WorldWideScience

Sample records for berliner-based bio pesticide

  1. Impact of pesticides on plant growth promotion of Vigna radiata and non-target microbes: comparison between chemical- and bio-pesticides.

    Science.gov (United States)

    Gupta, Sukriti; Gupta, Rashi; Sharma, Shilpi

    2014-08-01

    To compare the target and non-target effects of two chemical-pesticides (chlorpyrifos and endosulfan) with that of a bio-pesticide (azadirachtin), Vigna radiata (mung bean) was grown in a randomized pot experiment with recommended and higher application rates of pesticides. Colony counts enumerating specific microbial populations, viz. fungi, Pseudomonas, nitrogen-fixing bacteria, and phosphate-solubilizing microorganisms, were performed. In addition, several plant growth parameters such as root and shoot lengths were also monitored. It was observed that the pesticides exerted a suppressive effect on different microbial communities under study in the initial 30 days period. The bacterial and fungal populations in chlorpyrifos treated plants increased thereafter. Endosulfan resulted in enhancement of fungi and nitrogen-fixing bacteria, although phosphate-solubilizing microorganisms were suppressed at higher application rates. Azadirachtin, which is gaining popularity owing to its biological origin, did not result in enhancement of any microbial populations; on the other hand, it had a deleterious effect on phosphate-solubilizing bacteria. This study is the first to evaluate the non-target effects of pesticides with a comparison between chemical- and bio-pesticides, and also stresses the importance of critical investigation of bio-pesticides before their wide spread application in agriculture.

  2. Efficacy of bio and synthetic pesticides against the American ...

    African Journals Online (AJOL)

    Management for the bollworm complex in Uganda is largely synthetic chemical use with little or no biopesticide use which reduces natural enemies population and resistance development to continuous use of a single synthetic pesticide product. Therefore this study aimed at determining the efficacy of bio and synthetic ...

  3. Challenges and opportunities of the bio-pesticides production by solid-state fermentation: filamentous fungi as a model.

    Science.gov (United States)

    De la Cruz Quiroz, Reynaldo; Roussos, Sevastianos; Hernández, Daniel; Rodríguez, Raúl; Castillo, Francisco; Aguilar, Cristóbal N

    2015-01-01

    In recent years, production and use of bio-pesticides have increasing and replacing some synthetic chemical pesticides applied to food commodities. In this review, biological control is focused as an alternative, to some synthetic chemical treatments that cause environmental, human health, and food quality risks. In addition, several phytopathogenic microorganisms have developed resistance to some of these synthetic chemicals and become more difficult to control. Worldwide, the bio-pesticides market is growing annually at a rate of 44% in North America, 20% in Europe and Oceania, 10% in Latin and South American countries and 6% in Asia. Use of agro-industrial wastes and solid-state fermentation (SSF) technology offers an alternative to bio-pesticide production with advantages versus conventional submerged fermentations, as reduced cost and energy consumption, low production of residual water and high stability products. In this review, recent data about state of art regarding bio-pesticides production under SSF on agroindustrial wastes will be discussed. SSF can be defined as a microbial process that generally occurs on solid material in the absence of free water. This material has the ability to absorb water with or without soluble nutrients, since the substrate must have water to support the microorganism's growth and metabolism. Changes in water content are analyzed in order to select the conditions for a future process, where water stress can be combined with the best spore production conditions, obtaining in this way an inexpensive biotechnological option for modern agriculture in developing countries.

  4. potenti ls of two bio-pesticides in the control of some field insect

    African Journals Online (AJOL)

    USER

    2017-05-24

    May 24, 2017 ... Teaching and Research Farm, University of Ilorin, P.M.B. 1515 Ilorin, Nigeria ... effective of the bio-pesticides evaluated and can be used by ..... grasses: The genus Cymbopogon. ... Tropical Crop Science, Wageningen.

  5. Potentials of two bio-pesticides in the control of some field insect ...

    African Journals Online (AJOL)

    A field experiment was carried out to determine the predominate order of insects associated with Bambara groundnut and to compare the efficacy of aqueous leaf extracts of Jatropha (Jatropha curcas) and lemon grass (Cymbopogon citratus), used as bio-pesticides in controlling some field insect pests of Bambara ...

  6. Evaluation of Four Bio fertilizers for Bioremediation of Pesticide contaminated Soil

    International Nuclear Information System (INIS)

    El- Kabbany, S.

    1999-01-01

    Experiments were conducted to asses the ability of mixed populations of microorganisms which produced as a bio fertilizers by the General Organization of Agriculture Fund, Ministry of Agriculture, Egypt (phosphoren, microbien, cerealin and azospirillum) to degrade five selected pesticides representing different classes including organophosphate, carbamate and chlorinated organic compounds. There were differences in rates of biotransformation, suggesting the selective induction of certain metabolic enzymes. Inoculation of soil incorporated with malathion, fenamiphos, carbaryl, aldicarb and dieldrin, resulted in ca. 80-90% removal of malathion and fenamiphos within 8 days, carbaryl and aldicarb within 11-15 days respectively. Dieldrin removal occurred slowly within 2 months. These data suggest that bioremediate may act as potential candidates for soil inoculation to bioremediate pesticide contaminated soil. The production of Co2 (soil respiration ) was stimulated by some pesticides. In samples with microbien, an about 2 times higher Co2 production was measured

  7. Use of by-products rich in carbon and nitrogen as a nutrient source to produce Bacillus thuringiensis (Berliner)-based bio pesticide

    International Nuclear Information System (INIS)

    Valicente, Fernando H.; Mourao, Andre H.C.

    2008-01-01

    The amount and sources of carbon and nitrogen used to produce Bacillus thuringiensis (Berliner)-based biopesticide may influence the quality of the fi nal product. The objective of this research was to test different levels of carbon and nitrogen: medium 1 - 1.5% maize glucose + 0.5% soy fl our, medium 2 - 3.0% maize glucose + 1.0% soy flour, medium 3 - 1.0% maize glucose + 3.0% soy fl our and medium 4 - Luria Bertani (LB) + salts (FeSO 4 , ZnSO 4 , MnSO 4 , MgSO 4 ). The seed culture was produced in LB medium plus salt, under agitation (200 rpm) for 18h at 30 deg C. The strain 344 of Bt was used (B. thuringiensis var tolworthi - belonging to the EMBRAPA's Bt Bank). The pH was measured at regular intervals, and After culturing for 96h, the pH of the four tested media was basified (6.91 and 8.15), the number of spores yielded 4.39 x 10 9 spores/ml in medium 3, where the amount of protein is high. The dry biomass weight accumulated in media 3 was 39.3 g/l. Mortality of 2-day-old larvae Spodoptera frugiperda (J.E. Smith) was 100% when using Bt produced in media 3 and 4. CL 50 for medium 3 was 8.4 x 10 6 spores/ml. All tested media were satisfactory to Bt growth, and medium 3 was the most promising to be used on a large scale Bt-based biopesticide production. (author)

  8. Use of by-products rich in carbon and nitrogen as a nutrient source to produce Bacillus thuringiensis (Berliner)-based bio pesticide

    Energy Technology Data Exchange (ETDEWEB)

    Valicente, Fernando H. [EMBRAPA Milho e Sorgo, Sete Lagoas, MG (Brazil)]. E-mail: valicent@cnpms.embrapa.br; Mourao, Andre H.C. [Curso de Meio Ambiente, Sete Lagoas, MG (Brazil)

    2008-11-15

    The amount and sources of carbon and nitrogen used to produce Bacillus thuringiensis (Berliner)-based biopesticide may influence the quality of the fi nal product. The objective of this research was to test different levels of carbon and nitrogen: medium 1 - 1.5% maize glucose + 0.5% soy fl our, medium 2 - 3.0% maize glucose + 1.0% soy flour, medium 3 - 1.0% maize glucose + 3.0% soy fl our and medium 4 - Luria Bertani (LB) + salts (FeSO{sub 4}, ZnSO{sub 4}, MnSO{sub 4}, MgSO{sub 4}). The seed culture was produced in LB medium plus salt, under agitation (200 rpm) for 18h at 30 deg C. The strain 344 of Bt was used (B. thuringiensis var tolworthi - belonging to the EMBRAPA's Bt Bank). The pH was measured at regular intervals, and After culturing for 96h, the pH of the four tested media was basified (6.91 and 8.15), the number of spores yielded 4.39 x 10{sup 9} spores/ml in medium 3, where the amount of protein is high. The dry biomass weight accumulated in media 3 was 39.3 g/l. Mortality of 2-day-old larvae Spodoptera frugiperda (J.E. Smith) was 100% when using Bt produced in media 3 and 4. CL{sub 50} for medium 3 was 8.4 x 10{sup 6} spores/ml. All tested media were satisfactory to Bt growth, and medium 3 was the most promising to be used on a large scale Bt-based biopesticide production. (author)

  9. Indication of pesticide effects and recolonization in streams.

    Science.gov (United States)

    Knillmann, Saskia; Orlinskiy, Polina; Kaske, Oliver; Foit, Kaarina; Liess, Matthias

    2018-07-15

    The agricultural use of pesticides leads to environmentally relevant pesticide concentrations that cause adverse effects on stream ecosystems. These effects on invertebrate community composition can be identified by the bio-indicator SPEAR pesticides . However, refuge areas have been found to partly confound the indicator. On the basis of three monitoring campaigns of 41 sites in Central Germany, we identified 11 refuge taxa. The refuge taxa, mainly characterized by dispersal-based resilience, were observed only nearby uncontaminated stream sections and independent of the level of pesticide pressure. Through incorporation of this information into the revised SPEAR pesticides indicator, the community structure specifically identified the toxic pressure and no longer depended on the presence of refuge areas. With regard to ecosystem functions, leaf litter degradation was predicted by the revised SPEAR pesticides and the median water temperature at a site (R 2  = 0.38, P = 0.003). Furthermore, we designed the bio-indicator SPEAR refuge to quantify the magnitude of general recolonization at a given stream site. We conclude that the taxonomic composition of aquatic invertebrate communities enables a specific indication of anthropogenic stressors and resilience of ecosystems. Copyright © 2018 Elsevier B.V. All rights reserved.

  10. Distributed medical services within the ATM-based Berlin regional test bed

    Science.gov (United States)

    Thiel, Andreas; Bernarding, Johannes; Krauss, Manfred; Schulz, Sandra; Tolxdorff, Thomas

    1996-05-01

    The ATM-based Metropolitan Area Network (MAN) of Berlin connects two university hospitals (Benjamin Franklin University Hospital and Charite) with the computer resources of the Technical University of Berlin (TUB). Distributed new medical services have been implemented and will be evaluated within the highspeed MAN of Berlin. The network with its data transmission rates of up to 155 Mbit/s renders these medical services externally available to practicing physicians. Resource and application sharing is demonstrated by the use of two software systems. The first software system is an interactive 3D reconstruction tool (3D- Medbild), based on a client-server mechanism. This structure allows the use of high- performance computers at the TUB from the low-level workstations in the hospitals. A second software system, RAMSES, utilizes a tissue database of Magnetic Resonance Images. For the remote control of the software, the developed applications use standards such as DICOM 3.0 and features of the World Wide Web. Data security concepts are being tested and integrated for the needs of the sensitive medical data. The highspeed network is the necessary prerequisite for the clinical evaluation of data in a joint teleconference. The transmission of digitized real-time sequences such as video and ultrasound and the interactive manipulation of data are made possible by Multi Media tools.

  11. Isolation of ethyl acetic based AGF bio-nutrient and its application on the growth of Capsicum annum L. plants

    Science.gov (United States)

    Hendrawan, Sonjaya, Yaya; Khoerunnisa, Fitri; Musthapa, Iqbal; Nurmala, Astri Rizki

    2015-12-01

    The study aimed to obtain the bionutrient derived from extraction of AGF leafs in ethyl acetic solvents and to explore its application on the plant growth of capsicum annum L. (curly red chili). Particularly, the fraction of secondary metabolites groups composed bionutrient was intensively elucidated by liquid vacuum chromatography technique. The characterization of secondary metabolites groups was conducted through several methods, i.e. thin layer chromatography, phytochemical screening, and FTIR spectroscopy. The AGF extracts based bionutrient then was applied on capsicum annum L. plants with dosage of 2 and 10 mL/L. The ethyl acetic solvent and commercial nutrient of Phonska and pesticide of curacron (EC 500) were selected as a blank and a positive control to evaluate the growth pattern of capsicum annum L., respectively. The result showed that the CF 1 dan CF2 of AGF extract contained alkaloid and terpenoid of secondary metabolite group, the CF 3, and CF 4 of AGF extracts were dominated by alkaloid, flavonoid, and terpenoid, while the CF 5 of AGF extract contained alkaloid, tannin and terpenoid groups. The CF 2 of AGF extract has the highest growth rate constant of 0.1702 week-1 with the number and heaviest mass of the yield of 82 pieces and 186.60, respectively. It was also showed the significant bio-pesticide activity that should be useful to support plant growth, indicating that AGF extract can be applied as both bio-nutrient and bio-pesticide.

  12. Demonstrating an Approach for Including Pesticide Use in Life Cycle Assessment: Estimating Human and Ecosystem Toxicity of Pesticide Use in Midwest Corn Farming

    Science.gov (United States)

    Purpose This study demonstrates an approach to assess human health and ecotoxicity impacts of pesticide use by including multiple environmental pathways and various exposure routes using the case of corn grown for bio-based fuel or chemical production in US Midwestern states.Meth...

  13. Demonstrating an approach for including pesticide use in life-cycle assessment: Estimating human and ecosystem toxicity of pesticide use in Midwest corn farming

    Science.gov (United States)

    PurposeThis study demonstrates an approach to assess human health and ecotoxicity impacts of pesticide use by including multiple environmental pathways and various exposure routes using the case of corn grown for bio-based fuel or chemical production in US Midwestern states.Metho...

  14. Pesticides: chemicals for survival

    International Nuclear Information System (INIS)

    Lindquist, D.A.

    1981-01-01

    Pesticides are chemicals used to control pests such as insects, weeds, plant diseases, nematodes, and rodents. The increased use of pesticides since 1945 has greatly aided the increase in crop production, protected livestock from diseases such as trypanosomiasis, protected man from diseases such as malaria and filarisis, decreased losses of stored grain, and has generally improved man's welfare. Despite the enormous benefits derived from pesticides these chemicals are not problem-free. Many pesticides are toxic to living organisms and interfere with specific biochemical systems. To measure the very small quantities of a pesticide radiolabelled chemicals are frequently essential, particularly to measure changes in the chemical structure of the pesticide, movement of the pesticide in soil, plants, or animals, amounts of pesticide going through various steps in food processing, etc. The use of radiolabelled pesticides is shortly shown for metabolism of the pesticide in crop species, metabolism in ruminant, in chickens and eggs, in soil, and possibly leaching and sorption in soil, hydrolysis, bio-concentration, microbial and photodegradation, and toxicity studies

  15. Walter Benjamins Berlin

    DEFF Research Database (Denmark)

    Walter Benjamin (1892-1940). Tolkning af alle 33 kapitler i Benjamins bybarndomserindringer fra Berlin i begyndelsen af det 20. århundrede.......Walter Benjamin (1892-1940). Tolkning af alle 33 kapitler i Benjamins bybarndomserindringer fra Berlin i begyndelsen af det 20. århundrede....

  16. Acute toxicity assessment of Osthol content in bio-pesticides using two aquatic organisms

    Directory of Open Access Journals (Sweden)

    Eun-Chae Yim

    2014-12-01

    Full Text Available Objectives This study focused on the assessment of acute toxicity caused by Osthol, a major component of environment-friendly biological pesticides, by using two aquatic organisms. Methods The assessment of acute toxicity caused by Osthol was conducted in Daphnia magna and by examining the morphological abnormalities in Danio rerio embryos. Results The median effective concentration value of Osthol in D. magna 48 hours after inoculation was 19.3 μM. The median lethal concentration of D. rerio embryo at 96 hours was 30.6 μM. No observed effect concentration and predicted no effect concentration values of Osthol in D. magna and D. rerio were calculated as 5.4 and 0.19 μM, respectively. There was an increase in the morphological abnormalities in D. rerio embryo due to Osthol over time. Coagulation, delayed hatching, yolk sac edema, pericardial edema, and pigmentation were observed in embryos at 24–48 hours. Symptoms of scoliosis and head edema occurred after 72 hours. In addition, bent tails, ocular defects, and symptoms of collapse were observed in fertilized embryo tissue within 96 hours. Ocular defects and pigmentation were the additional symptoms observed in this study. Conclusions Because Osthol showed considerable toxicity levels continuous toxicity evaluation in agro-ecosystems is necessary when bio-pesticides containing Osthol are used.

  17. Mapping ground water vulnerability to pesticide leaching with a process-based metamodel of EuroPEARL.

    Science.gov (United States)

    Tiktak, A; Boesten, J J T I; van der Linden, A M A; Vanclooster, M

    2006-01-01

    To support EU policy, indicators of pesticide leaching at the European level are required. For this reason, a metamodel of the spatially distributed European pesticide leaching model EuroPEARL was developed. EuroPEARL considers transient flow and solute transport and assumes Freundlich adsorption, first-order degradation and passive plant uptake of pesticides. Physical parameters are depth dependent while (bio)-chemical parameters are depth, temperature, and moisture dependent. The metamodel is based on an analytical expression that describes the mass fraction of pesticide leached. The metamodel ignores vertical parameter variations and assumes steady flow. The calibration dataset was generated with EuroPEARL and consisted of approximately 60,000 simulations done for 56 pesticides with different half-lives and partitioning coefficients. The target variable was the 80th percentile of the annual average leaching concentration at 1-m depth from a time series of 20 yr. The metamodel explains over 90% of the variation of the original model with only four independent spatial attributes. These parameters are available in European soil and climate databases, so that the calibrated metamodel could be applied to generate maps of the predicted leaching concentration in the European Union. Maps generated with the metamodel showed a good similarity with the maps obtained with EuroPEARL, which was confirmed by means of quantitative performance indicators.

  18. Berlin: United Again.

    Science.gov (United States)

    Cogan, John J.

    1990-01-01

    Compares East and West Berlin before and after the fall of the Berlin Wall in November 1989. Offers divergent viewpoints on German reunification from interviews of two professors: one from East Germany, the other from West Germany. Recommends that social studies classes incorporate current events such as German reunification. (CH)

  19. (Non-Monumental Layers of Berlin

    Directory of Open Access Journals (Sweden)

    Juli Székely

    2016-09-01

    Full Text Available The two books reviewed in this article, Hsiu-Ling Kuos’s Monumentality and Modernity in Hitler’s Berlin (2013 and Janet Ward’s Post-Wall Berlin (2011, focus on the structural, political, social and aesthetic transformation of Berlin, from the first half of the twentieth century to the ‘post-wall’ era. Since both authors strongly emphasize the former and present status of monumental architecture and monumental memory, this book review pays particular attention to a critical discussion of the (non-monumental layers of Berlin.

  20. [Current status of bio-based materials industry in China].

    Science.gov (United States)

    Diao, Xiaoqian; Weng, Yunxuan; Huang, Zhigang; Yang, Nan; Wang, Xiyuan; Zhang, Min; Jin, Yujuan

    2016-06-25

    In recent years, bio-based materials are becoming a new dominant industry leading the scientific and technological innovation, and economic development of the world. We reviewed the new development of bio-based materials industry in China, analyzed the entire market of bio-based materials products comprehensively, and also stated the industry status of bio-based chemicals, such as lactic acid, 1,3-propanediol, and succinic acid; biodegradable bio-based polymers, such as co-polyester of diacid and diol, polylactic acid, carbon dioxide based copolymer, polyhydroxyalknoates, polycaprolactone, and thermoplastic bio-based plastics; non-biodegradable bio-based polymers, such as bio-based polyamide, polytrimethylene terephthalate, bio-based polyurethane, and bio-based fibers.

  1. Sexing Berlin?

    Science.gov (United States)

    Dahlke, Birgit

    2011-01-01

    Berlin has always been a literary space of extremely diverse political and cultural projections. This essay investigates why after the unification of East and West Berlin the city has been imagined as a play zone of sexual self-fulfilment by authors such as Inka Parei, Tanja Dückers, Kathrin Röggla, Judith Hermann and Julia Franck. Have such erotic adventures replaced political vision in our post-utopian decade? What is the purpose of the laboured allegorisation of the fall of the wall in Durs Grünbein's essays or in the novels of Katja Lange-Müller and Thomas Hettche? The sexification of historical and political processes recalls similar stereotypes in the East German literature of the 1980s: the metropolis as a whore in works by Heiner Müller or Wolf Biermann, but also by younger authors of the independent literary scene in Berlin like Uwe Kolbe or Frank-Wolf Matthies.

  2. Biosensor technology for pesticides--a review.

    Science.gov (United States)

    Verma, Neelam; Bhardwaj, Atul

    2015-03-01

    Pesticides, due to their lucrative outcomes, are majorly implicated in agricultural fields for crop production enhancement. Due to their pest removal properties, pesticides of various classes have been designed to persist in the environment over a longer duration after their application to achieve maximum effectiveness. Apart from their recalcitrant structure and agricultural benefits, pesticides also impose acute toxicological effects onto the other various life forms. Their accumulation in the living system may prove to be detrimental if established in higher concentrations. Thus, their prompt and accurate analysis is a crucial matter of concern. Conventional techniques like chromatographic techniques (HPLC, GC, etc.) used for pesticides detection are associated with various limitations like stumpy sensitivity and efficiency, time consumption, laboriousity, requirement of expensive equipments and highly trained technicians, and many more. So there is a need to recruit the methods which can detect these neurotoxic compounds sensitively, selectively, rapidly, and easily in the field. Present work is a brief review of the pesticide effects, their current usage scenario, permissible limits in various food stuffs and 21st century advancements of biosensor technology for pesticide detection. Due to their exceptional performance capabilities, easiness in operation and on-site working, numerous biosensors have been developed for bio-monitoring of various environmental samples for pesticide evaluation immensely throughout the globe. Till date, based on sensing element (enzyme based, antibody based, etc.) and type of detection method used (Electrochemical, optical, and piezoelectric, etc.), a number of biosensors have been developed for pesticide detection. In present communication, authors have summarized 21st century's approaches of biosensor technology for pesticide detection such as enzyme-based biosensors, immunosensors, aptamers, molecularly imprinted polymers, and

  3. Safety Aspects of Bio-Based Nanomaterials.

    Science.gov (United States)

    Catalán, Julia; Norppa, Hannu

    2017-12-01

    Moving towards a bio-based and circular economy implies a major focus on the responsible and sustainable utilization of bio-resources. The emergence of nanotechnology has opened multiple possibilities, not only in the existing industrial sectors, but also for completely novel applications of nanoscale bio-materials, the commercial exploitation of which has only begun during the last few years. Bio-based materials are often assumed not to be toxic. However, this pre-assumption is not necessarily true. Here, we provide a short overview on health and environmental aspects associated with bio-based nanomaterials, and on the relevant regulatory requirements. We also discuss testing strategies that may be used for screening purposes at pre-commercial stages. Although the tests presently used to reveal hazards are still evolving, regarding modifi-cations required for nanomaterials, their application is needed before the upscaling or commercialization of bio-based nanomaterials, to ensure the market potential of the nanomaterials is not delayed by uncertainties about safety issues.

  4. Safety Aspects of Bio-Based Nanomaterials

    Directory of Open Access Journals (Sweden)

    Julia Catalán

    2017-12-01

    Full Text Available Moving towards a bio-based and circular economy implies a major focus on the responsible and sustainable utilization of bio-resources. The emergence of nanotechnology has opened multiple possibilities, not only in the existing industrial sectors, but also for completely novel applications of nanoscale bio-materials, the commercial exploitation of which has only begun during the last few years. Bio-based materials are often assumed not to be toxic. However, this pre-assumption is not necessarily true. Here, we provide a short overview on health and environmental aspects associated with bio-based nanomaterials, and on the relevant regulatory requirements. We also discuss testing strategies that may be used for screening purposes at pre-commercial stages. Although the tests presently used to reveal hazards are still evolving, regarding modifi­cations required for nanomaterials, their application is needed before the upscaling or commercialization of bio-based nanomaterials, to ensure the market potential of the nanomaterials is not delayed by uncertainties about safety issues.

  5. Pesticide reducing instruments

    DEFF Research Database (Denmark)

    Jacobsen, Lars-Bo; Jensen, Jørgen Dejgård; Andersen, Martin

    2005-01-01

    -mentioned models and tools. All three scenarios are constructed such that they result in the same welfare implication (measured by national consumption in the CGE model). The scenarios are: 1) pesticide taxes resulting in a 25 percent overall reduction; 2) use of unsprayed field margins, resulting in the same...... for improving bio-diversity and securing drinking water. That is, combining economic modeling with physical biological modeling and geological evaluation allows us to select unsprayed field margins as the most effective instrument. Sensitivity analysis conducted on bio-diversity suggest that this result...

  6. Sustainable bio-based materials: opportunities and challenges

    NARCIS (Netherlands)

    van der Meer, Yvonne

    2017-01-01

    Research in the area of bio-based materials aims to achieve breakthroughs in bio-based materials development. A novel way is presented to organise bio-based materials research with a value chain approach in which sustainability research is integrated in the research program. This research approach

  7. Best Practices: Intercultural Integration of Arabic Refugees in Berlin

    Science.gov (United States)

    Kyuchukov, Hristo; New, William

    2017-01-01

    The paper presents the work of a Berlin-based NGO (ANE) in Germany, which works with migrants and Arab refugees. The organisation has a strong record publishing a Parents Newsletter and conducting family counselling for migrants and refugees in Berlin. One of the major activities of the organisation in 2016 was an international conference with…

  8. [Preface for special issue on bio-based materials (2016)].

    Science.gov (United States)

    Weng, Yunxuan

    2016-06-25

    Bio-based materials are new materials or chemicals with renewable biomass as raw materials such as grain, legume, straw, bamboo and wood powder. This class of materials includes bio-based polymer, biobased fiber, glycotechnology products, biobased rubber and plastics produced by biomass thermoplastic processing and basic biobased chemicals, for instance, bio-alcohols, organic acids, alkanes, and alkenes, obtained by bio-synthesis, bio-processing and bio-refinery. Owing to its environmental friendly and resource conservation, bio-based materials are becoming a new dominant industry taking the lead in the world scientific and technological innovation and economic development. An overview of bio-based materials development is reported in this special issue, and the industrial status and research progress of the following aspects, including biobased fiber, polyhydroxyalkanoates, biodegradable mulching film, bio-based polyamide, protein based biomedical materials, bio-based polyurethane, and modification and processing of poly(lactic acid), are introduced.

  9. Bio-Based Polymers with Potential for Biodegradability

    Directory of Open Access Journals (Sweden)

    Thomas F. Garrison

    2016-07-01

    Full Text Available A variety of renewable starting materials, such as sugars and polysaccharides, vegetable oils, lignin, pine resin derivatives, and proteins, have so far been investigated for the preparation of bio-based polymers. Among the various sources of bio-based feedstock, vegetable oils are one of the most widely used starting materials in the polymer industry due to their easy availability, low toxicity, and relative low cost. Another bio-based plastic of great interest is poly(lactic acid (PLA, widely used in multiple commercial applications nowadays. There is an intrinsic expectation that bio-based polymers are also biodegradable, but in reality there is no guarantee that polymers prepared from biorenewable feedstock exhibit significant or relevant biodegradability. Biodegradability studies are therefore crucial in order to assess the long-term environmental impact of such materials. This review presents a brief overview of the different classes of bio-based polymers, with a strong focus on vegetable oil-derived resins and PLA. An entire section is dedicated to a discussion of the literature addressing the biodegradability of bio-based polymers.

  10. Bio-based liquid crystalline polyesters

    Science.gov (United States)

    Wilsens, Carolus; Rastogi, Sanjay; Dutch Collaboration

    2013-03-01

    The reported thin-film polymerization has been used as a screening method in order to find bio-based liquid crystalline polyesters with convenient melting temperatures for melt-processing purposes. An in depth study of the structural, morphological and chemical changes occurring during the ongoing polycondensation reactions of these polymers have been performed. Structural and conformational changes during polymerization for different compositions have been followed by time resolved X-ray and Infrared spectroscopy. In this study, bio-based monomers such as vanillic acid and 2,5-furandicarboxylic acid are successfully incorporated in liquid crystalline polyesters and it is shown that bio-based liquid crystalline polymers with high aromatic content and convenient processing temperatures can be synthesized. Special thanks to the Dutch Polymer Institute for financial support

  11. Berlin in Television Drama Series: A Mediated Space

    Directory of Open Access Journals (Sweden)

    Susanne Eichner

    2017-07-01

    Full Text Available Since the early days of film Berlin and the film studios in its suburbs was an important site of production. Signature films for film historians such as Metropolis and The Blue Angel were shot at the UFA studios in Babelsberg. Throughout its history Berlin was and is a popular place for media productions with the city functioning as a text, full of meaning that turns into branded value. The article will investigate the complex relationship of historical and societal events and Berlin as a production site and an imaginary landscape respectively cityscape. Based on the analysis of national and international drama series we will argue that the increasing importance of Berlin as production site and location goes hand in hand with an increasing mediated imagination of the city as a cinematic respectively televisual space that is able to represent past events such as the Nazi regime and the cold war and actual events such as organised crime, counter terrorist activities, and an intercultural life in a modern metropolis.

  12. Vendor-based restrictions on pesticide sales to prevent pesticide self-poisoning - a pilot study

    Directory of Open Access Journals (Sweden)

    Manjula Weerasinghe

    2018-02-01

    Full Text Available Abstract Background In South Asia, up to 20% of people ingesting pesticides for self-poisoning purchase the pesticide from a shop with the sole intention of self-harm. Individuals who are intoxicated with alcohol and/or non-farmers represent 72% of such high-risk individuals. We aimed to test the feasibility and acceptability of vendor-based restrictions on pesticide sales for such high-risk individuals. Methods We conducted a pilot study in 14 (rural = 7, urban = 7 pesticide shops in Anuradhapura District of Sri Lanka. A two-hour training program was delivered to 28 pesticide vendors; the aim of the training was to help vendors recognize and respond to customers at high risk of pesticide self-poisoning. Knowledge and attitudes of vendors towards preventing access to pesticides for self-poisoning at baseline and in a three month follow-up was evaluated by questionnaire. Vendors were interviewed to explore the practice skills taught in the training and their assessment of the program. Results The scores of knowledge and attitudes of the vendors significantly increased by 23% (95% CI 15%–32%, p < 0.001 and by 16% (95% CI 9%–23%, p < 0.001 respectively in the follow-up. Fifteen (60% vendors reported refusing sell pesticides to a high-risk person (non-farmer or intoxicated person in the follow-up compared to three (12% at baseline. Vendors reported that they were aware from community feedback that they had prevented at least seven suicide attempts. On four identified occasions, vendors in urban shops had been unable to recognize the self-harming intention of customers who then ingested the pesticide. Only 2 (8% vendors were dissatisfied with the training and 23 (92% said they would recommend it to other vendors. Conclusions Our study suggests that vendor-based sales restriction in regions with high rates of self-poisoning has the potential to reduce access to pesticides for self-poisoning. A large-scale study of the effectiveness

  13. SERS-based pesticide detection by using nanofinger sensors

    Science.gov (United States)

    Kim, Ansoon; Barcelo, Steven J.; Li, Zhiyong

    2015-01-01

    Simple, sensitive, and rapid detection of trace levels of extensively used and highly toxic pesticides are in urgent demand for public health. Surface-enhanced Raman scattering (SERS)-based sensor was designed to achieve ultrasensitive and simple pesticide sensing. We developed a portable sensor system composed of high performance and reliable gold nanofinger sensor strips and a custom-built portable Raman spectrometer. Compared to the general procedure and previously reported studies that are limited to laboratory settings, our analytical method is simple, sensitive, rapid, and cost-effective. Based on the SERS results, the chemical interaction of two pesticides, chlorpyrifos (CPF) and thiabendazole (TBZ), with gold nanofingers was studied to determine a fingerprint for each pesticide. The portable SERS-sensor system was successfully demonstrated to detect CPF and TBZ pesticides within 15 min with a detection limit of 35 ppt in drinking water and 7 ppb on apple skin, respectively.

  14. Degradation of non-biodegradable pesticides in water by coupling photo catalysis and bio treatment; Eliminacion de plaguicidas no biodegrabables en aguas mediante acoplamiento de fotocatalisis solar y oxidacion biologica

    Energy Technology Data Exchange (ETDEWEB)

    Ballesteros Martin, M. M.; Sanchez Perez, J. A.; Malato Rodriguez, S.

    2008-07-01

    The influence of pesticide concentration, expressed as dissolved organic carbon (DOC), on combined solar photo-Fenton and biological oxidation treatment was studied using wastewater containing different pure and commercial pesticides (dimethoate, oxydemeton-methyl, carbaryl, oxamyl, methomyl, imidacloprid, dimethoate and pyrimethanil). Different initial concentrations were assayed. Variation in biodegradability with photo catalytic treatment intensity was tested using Pseudomonas putida. Biodegradation efficiencies after the photoreaction were found to be lower for the pesticide solution with the higher concentration, showing that to achieve sufficient biodegradability, the photo-Fenton treatment time must be increased with pesticide concentration. Bio treatment was carried out in different reactor including sequencing batch reactor (SBR) mode. As revealed by the biodegradation kinetics, intermediates generated at the higher pesticide concentration caused lower carbon removal rates in spite of the longer photo-Fenton treatment time applied. One strategy for treating water with high concentrations of pesticides and overcoming the low biodegradability of photo-Fenton intermediates is to mix it with a biodegradable carbon source (wastewater containing an easily biodegradable substrate, such as urban wastewater) before biological oxidation. This combination of photo-Fenton and acclimatized activated sludge in several SBR cycles led to complete biodegradation of a pesticide solutions up to of 500 mg/L of DOC. (Author)

  15. Prospects for a bio-based succinate industry.

    Science.gov (United States)

    McKinlay, James B; Vieille, C; Zeikus, J Gregory

    2007-09-01

    Bio-based succinate is receiving increasing attention as a potential intermediary feedstock for replacing a large petrochemical-based bulk chemical market. The prospective economical and environmental benefits of a bio-based succinate industry have motivated research and development of succinate-producing organisms. Bio-based succinate is still faced with the challenge of becoming cost competitive against petrochemical-based alternatives. High succinate concentrations must be produced at high rates, with little or no by-products to most efficiently use substrates and to simplify purification procedures. Herein are described the current prospects for a bio-based succinate industry, with emphasis on specific bacteria that show the greatest promise for industrial succinate production. The succinate-producing characteristics and the metabolic pathway used by each bacterial species are described, and the advantages and disadvantages of each bacterial system are discussed.

  16. Bio-based chemicals - green, but also sustainable?

    DEFF Research Database (Denmark)

    Ögmundarson, Ólafur; Herrgard, Markus; Förster, Jochen

    For almost two decades, the chemical industry has put great effort into developing bio-chemicals,among others to fight global warming caused by greenhouse gas emissions, one of the biggest threats that are faced by our society today. To facilitate a growing and versatile bio-based chemical...... production, the US Department of Energy proposed in 2004 a list of 12 building block chemicals which can either be converged through biological or chemical conversions. Moving toward more bio-based chemicals, the chemical industry does not only claim to reduce climate change impacts, but also...... that they are increasing overall sustainability in chemical production. Whether such claims are justifiable is unclear. When sustainability of bio-based polymer production is assessed, various environmental trade-offs occur that need to be considered. It is not enough to claim that a bio-chemical is sustainable...

  17. Inter-organizational collaboration in bio-based business

    NARCIS (Netherlands)

    Nuhoff-Isakhanyan, Gohar

    2016-01-01

    Globally, bio-based business is often perceived as sustainable, because its renewable production can potentially lower carbon and greenhouse emissions by substituting fossil-fuel-based production, reduce environmental sourcing problems, and create turnover and jobs. However, bio-based business

  18. The half-lives of biological activity of some pesticides in water

    OpenAIRE

    Kyaw Myint Oo,

    2001-01-01

    In the absence of analytical methods, the half-lives of biological activity of pesticides can be estimated by bioassays. To determine the half-lives of biological acivity of pesticides to fish, static bioassays were conducted in the laboratory with ten different formulations of pesticides using Labeo rohita as a bio-indicator. The half-lives of biological activity for ten different pesticides in soft water at pH 7.5 and 27░C, ranged from 4.6 days to 11.8 days. The half-life of biological acti...

  19. A consistent framework for modeling inorganic pesticides: Adaptation of life cycle inventory models to metal-base pesticides

    DEFF Research Database (Denmark)

    Peña, N.A.; Anton, A.; Fantke, Peter

    2016-01-01

    emission factors (percentages) or dynamic models base on specific application scenarios that describe only the behavior of organic pesticides. Currently fixed emission fractions for pesticides dearth to account for the influence of pesticide-specific function to crop type and application methods....... On the other hand the dynamic models need to account for the variability in this interactions in emissions of inorganic pesticides. This lack of appropriate models to estimate emission fractions of inorganic pesticides results in a lower accuracy when accounting for emissions in agriculture......, and it will influence the outcomes of the impact profile. The pesticide emission model PestLCI 2.0 is the most advanced currently available inventory model for LCA intended to provide an estimation of organic pesticide emission fractions to the environment. We use this model as starting point for quantifying emission...

  20. [Meta-analysis of association between organophosphorus pesticides and aplastic anemia].

    Science.gov (United States)

    Zhang, Ji; Yang, Tubao

    2015-09-01

    To evaluate the association between organophosphorus pesticides and aplastic anemia, and provide scientific evidence for the primary prevention of aplastic anemia. The published papers of case control studies on the association between organophosphorus pesticides and aplastic anemia from January 1990 to August 2014 were collected from Chinese BioMedical Literature Base (CBM), Chinese National Knowledge Infrastructure (CNKI), PubMed and EMBASE. The papers which met the inclusion criteria were evaluated. The pooled odds ratios (OR) and 95% confidence interval (CI) of organophosphorus pesticides were calculated with software Review Manager 5.0. Subgroup analysis were conducted for different population and different usage of organophosphorus pesticides. A total of 9 papers were selected, involving 5 833 subjects (1 404 cases and 4 429 controls). The results showed that organophosphorus pesticides could increase the risk of aplastic anemia (OR=1.97, 95% CI: 1.60-2.44) . Subgroup analysis showed that Asian (OR=2.01, 95% CI: 1.52-2.66) had higher risk of aplastic anemia than American or European (OR=1.93, 95% CI: 1.39-2.67) . Using pure organophosphorus pesticides (OR=2.15, 95% CI: 1.60-2.88) was more prone to cause aplastic anemia than using the mixture of organophosphorus pesticides (OR=1.82, 95% CI: 1.34-2.47). The analysis indicated that organophosphorus pesticides might be a risk factor for aplastic anemia. Reducing organophosphorus pesticides exposure in daily life and industrial or agricultural production could prevent the incidence of aplastic anemia.

  1. Risk of the research reactor BER II in Berlin; Risiken des Berliner Experimentierreaktors BER II

    Energy Technology Data Exchange (ETDEWEB)

    Paulitz, Henrik; Hoevener, Barbara; Rosen, Alex

    2015-04-20

    The research reactor BER II is sited at the periphery of Berlin in the neighborhood of residential areas. The operational license is limited until December 31, 2019. The reactor is funded by the Federal Government (90%) and the city of Berlin (10%). The stress test has shown that the reactor is not secured against an aircraft crash (airliner or fast flying military jet), meltdown with remarkable radiological consequences to the public would be the consequence. Further hazards result from the radioactive waste transport, explosions and fires. The emergency measures cannot be considered to be sufficient. The city of Berlin would not be able to fulfill the required measures in case of a radiation accident.

  2. Freizeit beim Feind. US-amerikanische Soldaten in Ost-Berlin

    Directory of Open Access Journals (Sweden)

    Stefanie Eisenhuth

    2018-04-01

    Full Text Available This article focuses on an almost forgotten type of ›border crosser‹ in the divided city of Berlin: the members of the American military community. To them (as well as to the members of the French and British forces, the Berlin Wall marked the front line of the Cold War. At the same time, though, they were allowed to cross the border and spend their free time in East Berlin. Especially in the 1970s and 1980s, when the dollar was tumbling, American families took advantage of the favourable exchange rate and crossed the border for cheap shopping, dining and entertainment. Due to Berlin’s status, the GDR government had to tolerate this kind of tourism, but nevertheless tried to prevent any personal contact between Americans and East Germans. The regime could also benefit financially from the Western tourists. This demonstrates the ambivalence of the Honecker era, the concurrence of an increased openness and internal erosion. The study is based on documents from the GDR’s Ministry for State Security, the West Berlin Senate Chancellery and the US Berlin Brigade as well as on contemporary newspaper articles. * * * Der Aufsatz widmet sich einer ungewöhnlichen Gruppe von Berliner Grenzgängern: den vor Ort stationierten US-Soldaten. Für sie (wie auch für die Soldaten der britischen und französischen Armee markierte die Mauer einerseits die Front des Kalten Krieges, andererseits durften sie diese ohne große Kontrollen passieren und ihre Freizeit in Ost-Berlin verbringen – was sie besonders in den 1970er- und 1980er-Jahren auch intensiv taten, denn in Zeiten der Dollarkrise versprach die östliche Stadthälfte viel Vergnügen, Restaurantbesuche und Einkaufsmöglichkeiten für wenig Geld. Die DDR-Regierung war genötigt, die Grenzgänge zu tolerieren. Von dieser Form des Tourismus konnte sie finanziell profitieren, versuchte konkrete Kontaktaufnahmen aber zu vermeiden. Der Umgang mit den Grenzgängen amerikanischer Soldaten und ihrer

  3. Formation and bio release of bound residues of [14 C]-lindane and [14 C]-parathion in two Brazilian soils

    International Nuclear Information System (INIS)

    Andrea, M.M. de.

    1992-01-01

    This work studied the extractable and bound residues formation of 14 C-lindane and 14 C-parathion immediately after application and after 3 months of interaction of the pesticides with the soils. Metabolism, bio release, and the possible bioavailability of bound residues were studied by employing bio meter flasks which allowed a relative comparison of the behaviour of the two different 14 C-pesticides, by a balance of the applied or present radiocarbon in the soils after the bio tests. (author)

  4. Challenges for bio-based products in sustainable value chains

    NARCIS (Netherlands)

    Cardon, L.; Lin, J.W.; De Groote, M.; Ragaert, K.; Kopecka, J.A.; Koster, R.P.

    2011-01-01

    This work concerns studies related to strategic development of products in which bio-based plastics are or will be applied, referred to as bio-based products. The studies cover (1) current and potential benefits of bio-based products in extended value chains including activities after end-of-life of

  5. Fatal accidents due to train surfing in Berlin.

    Science.gov (United States)

    Strauch, H; Wirth, I; Geserick, G

    1998-06-08

    This study was undertaken for the purpose of analysing under the aspect of legal medicine, fatal accidents due to train surfing in the local transport system of Berlin (S-Bahn and underground). The period of investigation was from 1989 through 1995, with 41 train surfing accidents, among them 18 with fatal outcome. Evaluation included those 14 deaths which were forensically autopsied. It was based on autopsy records of Berlin-based university institutes (Humboldt University and Free University) as well as the Brandenburg State Institute of Legal Medicine. Also used were data obtained from the Berlin Transport Police Record. The casualties were aged between 13 and 25 years, most of them between 16 and 20. The male-female gender ratio was 13:1. Accidents occurred above all in the warmer season of the year, most of them between 20:00 h and midnight. More than 50% of all cases were affected by alcohol, but centrally acting medicaments or other addictive drugs were not noticed at all. Most of the fatal accidents occurred to users of the Berlin S-Bahn network. Older train models were the preferred surfing objects due to their structural peculiarities. Collision with close-to-track obstacles and slipping from the train proved to be the major sources of danger. An analysis of injuries revealed polytraumatisation but for one exception, with craniocerebral injuries being the most common and severest events. The longest survival time amounted to 24 h. As the psychosocial causes of high-risk behaviour of adolescents will hardly be controllable, withdrawal of technical, that is structural design possibilities appears to be the most important approach to prevention of accidents in the future. This demand is met by the new series of the Berlin S-Bahn. The model of the old series, suitable for surfing, still accounts for about 10% of the rolling stock and is to be decommissioned in 1998.

  6. PCDDs/PCDFs, PCBs, and organochlorine pesticides in eggs of Eurasian sparrowhawks (Accipiter nisus), hobbies (Falco subbuteo), and northern goshawks (Accipiter gentilis) collected in the area of Berlin-Brandenburg, Germany.

    Science.gov (United States)

    Wiesmüller, T; Sömmer, P; Volland, M; Schlatterer, B

    2002-05-01

    Concentrations of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), polychlorinated biphenyls (PCBs), and organochlorine (OC) pesticides were measured in unsuccessfully hatched eggs of three different kinds of predatory birds: 3 eggs of sparrowhawks, 7 eggs of hobbies, and 16 eggs of goshawks collected in the German region of Berlin-Brandenburg. Using toxic equivalency factors for birds, eggs of hobbies contained mean concentrations of 478 pg TEQ/g fat and 551 pg TEQ/g fat contributed by PCDD/Fs and coplanar PCBs, respectively. For sparrowhawks the respective TCDD equivalents were 424 and 1278 pg/g fat; those for goshawks were 211 and 935 pg/g fat. The mean value of the summed concentrations of the PCB congeners 28, 52, 101, 138, 153, and 180 amounted to 11 microg/g fat in eggs of hobbies, 9.5 microg/g fat for sparrowhawks, and 16.1 microg/g fat for goshawks. Of the analyzed organochlorine pesticides the concentration of p,p'-DDE was highest (up to 273 microg/g); the concentration of the other OCs, with the exception of methoxychlor in eggs of goshawks (highest level of 10.6 microg/g fat), were negligible. In all cases the calculated toxicity of the coplanar PCBs surpassed the toxicity of the PCDD/Fs, at least by a factor of two. Due to the higher concentration of the coplanar PCB 77 compared to PCB 126 in eggs of hobbies, it is concluded that its metabolic excretion in this species is much lower than in sparrowhawks and goshawks.

  7. Comparison of questionnaire-based estimation of pesticide residue intake from fruits and vegetables with urinary concentrations of pesticide biomarkers.

    Science.gov (United States)

    Chiu, Yu-Han; Williams, Paige L; Mínguez-Alarcón, Lidia; Gillman, Matthew; Sun, Qi; Ospina, Maria; Calafat, Antonia M; Hauser, Russ; Chavarro, Jorge E

    2018-01-01

    We developed a pesticide residue burden score (PRBS) based on a food frequency questionnaire and surveillance data on food pesticide residues to characterize dietary exposure over the past year. In the present study, we evaluated the association of the PRBS with urinary concentrations of pesticide biomarkers. Fruit and vegetable (FV) intake was classified as having high (PRBS≥4) or low (PRBSEARTH study. Two urine samples per man were analyzed for seven biomarkers of organophosphate and pyrethroid insecticides, and the herbicide 2,4-dichlorophenoxyacetic acid. We used generalized estimating equations to analyze the association of the PRBS with urinary concentrations of pesticide biomarkers. Urinary concentrations of pesticide biomarkers were positively related to high pesticide FV intake but inversely related to low pesticide FV intake. The molar sum of urinary concentrations of pesticide biomarkers was 21% (95% confidence interval (CI): 2%, 44%) higher for each one serving/day increase in high pesticide FV intake, and 10% (95% CI: 1%, 18%) lower for each one serving/day increase in low pesticide FV intake. Furthermore, intake of high pesticide FVs positively related to most individual urinary biomarkers. Our findings support the usefulness of the PRBS approach to characterize dietary exposure to select pesticides.

  8. Experiencing memory museums in Berlin. The Otto Weidt Workshop for the Blind Museum and the Jewish Museum Berlin

    Directory of Open Access Journals (Sweden)

    Ana Souto

    2018-03-01

    Full Text Available This article explores memory studies from the audience’s perspective, focusing on the perception of Holocaust narratives in two museums in Berlin. This research builds on and contributes to a number of emerging issues on memory studies, tourism perception and museum design: the debate on experiential authenticity, Dark Tourism, as well as the analysis of memory studies from the perspective of the user. The main data facilitating the analysis is based on responses shared on TripAdvisor; the case studies being the Otto Weidt Workshop for the Blind Museum and the Jewish Museum Berlin. The analysis of these museums, focusing on their narratives, design features and comments from visitors, will highlight a potential shift from the traditional object-focused museum, to a phenomenological subject-focused one. It will be argued, then, that the understanding and consumption of authenticity encompasses a very flexible definition, not only based on the nature of the objects exhibited, but on the production of authentic experiences.

  9. Bio fertilizer Application in a Fertigation System

    International Nuclear Information System (INIS)

    Ahmad Nazrul Abd Wahid; Latiffah Noordin; Hoe, P.C.K.

    2011-01-01

    Bio fertilizers contain live beneficial microorganisms that provide nutrients and other benefits to crops. At present, bio fertilizers can be found in solid and liquid forms. Liquid bio fertilizer can be one of the alternatives to chemical fertilizers and pesticides. Liquid bio fertilizer is produced through culturing of microorganisms that are known to have specific capabilities in helping plant growth. However, application of bio fertilizers in the form of solution is more tedious than that of solid bio fertilizers, which can be applied directly to plants, whereas the liquid form requires several stages of preparation before it can be applied to crops. In Malaysian Nuclear Agency, a study on the distribution of liquid bio fertilizers to crops through the fertigation system has been conducted. In Malaysia, this study has not been conducted in depth, since the present fertigation system is associated to delivery of solubilised mineral fertilizers. This paper discusses the application of liquid bio fertilizers through a fertigation system. Discussions cover technical aspects of bio fertilizer preparation and its application via the said system. Tomato plant was used as test crop to determine the capability and efficiency of bio fertilizer application through the fertigation system. (author)

  10. Unraveling Dutch citizens' perceptions on the bio-based economy : The case of bioplastics, bio-jetfuels and small-scale bio-refineries

    NARCIS (Netherlands)

    Lynch, Durwin H J; Klaassen, Pim; Broerse, Jacqueline E W

    2017-01-01

    Little is known about how citizens perceive the transition towards a bio-based economy (BBE), despite the fact that they are one of the most important actors in this transition. Citizens' perceptions of bio-based innovations can support policy-makers to improve the quality of decision-making and the

  11. A brief review of extrusion-based tissue scaffold bio-printing.

    Science.gov (United States)

    Ning, Liqun; Chen, Xiongbiao

    2017-08-01

    Extrusion-based bio-printing has great potential as a technique for manipulating biomaterials and living cells to create three-dimensional (3D) scaffolds for damaged tissue repair and function restoration. Over the last two decades, advances in both engineering techniques and life sciences have evolved extrusion-based bio-printing from a simple technique to one able to create diverse tissue scaffolds from a wide range of biomaterials and cell types. However, the complexities associated with synthesis of materials for bio-printing and manipulation of multiple materials and cells in bio-printing pose many challenges for scaffold fabrication. This paper presents an overview of extrusion-based bio-printing for scaffold fabrication, focusing on the prior-printing considerations (such as scaffold design and materials/cell synthesis), working principles, comparison to other techniques, and to-date achievements. This paper also briefly reviews the recent development of strategies with regard to hydrogel synthesis, multi-materials/cells manipulation, and process-induced cell damage in extrusion-based bio-printing. The key issue and challenges for extrusion-based bio-printing are also identified and discussed along with recommendations for future, aimed at developing novel biomaterials and bio-printing systems, creating patterned vascular networks within scaffolds, and preserving the cell viability and functions in scaffold bio-printing. The address of these challenges will significantly enhance the capability of extrusion-based bio-printing. Copyright © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Microbial conversion of biomass into bio-based polymers.

    Science.gov (United States)

    Kawaguchi, Hideo; Ogino, Chiaki; Kondo, Akihiko

    2017-12-01

    The worldwide market for plastics is rapidly growing, and plastics polymers are typically produced from petroleum-based chemicals. The overdependence on petroleum-based chemicals for polymer production raises economic and environmental sustainability concerns. Recent progress in metabolic engineering has expanded fermentation products from existing aliphatic acids or alcohols to include aromatic compounds. This diversity provides an opportunity to expand the development and industrial uses of high-performance bio-based polymers. However, most of the biomonomers are produced from edible sugars or starches that compete directly with food and feed uses. The present review focuses on recent progress in the microbial conversion of biomass into bio-based polymers, in which fermentative products from renewable feedstocks serve as biomonomers for the synthesis of bio-based polymers. In particular, the production of biomonomers from inedible lignocellulosic feedstocks by metabolically engineered microorganisms and the synthesis of bio-based engineered plastics from the biological resources are discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Model-based computer-aided design for controlled release of pesticides

    DEFF Research Database (Denmark)

    Muro Sunè, Nuria; Gani, Rafiqul; Bell, G.

    2005-01-01

    In the field of controlled release technology for pesticides or active ingredients (AI), models that can predict its delivery during application are important for purposes of design and marketing of the pesticide product. Appropriate models for the controlled release of pesticides, if available, ...... extended models have been developed and implemented into a computer-aided system. The total model consisting of the property models embedded into the release models are then employed to study the release of different combinations of AIs and polymer-based microcapsules.......In the field of controlled release technology for pesticides or active ingredients (AI), models that can predict its delivery during application are important for purposes of design and marketing of the pesticide product. Appropriate models for the controlled release of pesticides, if available...

  14. Acute respiratory distress syndrome: the Berlin Definition.

    Science.gov (United States)

    Ranieri, V Marco; Rubenfeld, Gordon D; Thompson, B Taylor; Ferguson, Niall D; Caldwell, Ellen; Fan, Eddy; Camporota, Luigi; Slutsky, Arthur S

    2012-06-20

    The acute respiratory distress syndrome (ARDS) was defined in 1994 by the American-European Consensus Conference (AECC); since then, issues regarding the reliability and validity of this definition have emerged. Using a consensus process, a panel of experts convened in 2011 (an initiative of the European Society of Intensive Care Medicine endorsed by the American Thoracic Society and the Society of Critical Care Medicine) developed the Berlin Definition, focusing on feasibility, reliability, validity, and objective evaluation of its performance. A draft definition proposed 3 mutually exclusive categories of ARDS based on degree of hypoxemia: mild (200 mm Hg < PaO2/FIO2 ≤ 300 mm Hg), moderate (100 mm Hg < PaO2/FIO2 ≤ 200 mm Hg), and severe (PaO2/FIO2 ≤ 100 mm Hg) and 4 ancillary variables for severe ARDS: radiographic severity, respiratory system compliance (≤40 mL/cm H2O), positive end-expiratory pressure (≥10 cm H2O), and corrected expired volume per minute (≥10 L/min). The draft Berlin Definition was empirically evaluated using patient-level meta-analysis of 4188 patients with ARDS from 4 multicenter clinical data sets and 269 patients with ARDS from 3 single-center data sets containing physiologic information. The 4 ancillary variables did not contribute to the predictive validity of severe ARDS for mortality and were removed from the definition. Using the Berlin Definition, stages of mild, moderate, and severe ARDS were associated with increased mortality (27%; 95% CI, 24%-30%; 32%; 95% CI, 29%-34%; and 45%; 95% CI, 42%-48%, respectively; P < .001) and increased median duration of mechanical ventilation in survivors (5 days; interquartile [IQR], 2-11; 7 days; IQR, 4-14; and 9 days; IQR, 5-17, respectively; P < .001). Compared with the AECC definition, the final Berlin Definition had better predictive validity for mortality, with an area under the receiver operating curve of 0.577 (95% CI, 0.561-0.593) vs 0.536 (95% CI, 0.520-0.553; P

  15. Design and manufacturing of bio-based sandwich structures

    CSIR Research Space (South Africa)

    John, Maya J

    2017-03-01

    Full Text Available The aim of this chapter is to discuss the design and manufacturing of bio-based sandwich structures. As the economic advantages of weight reduction have become mandatory for many advanced industries, bio-based sandwich panels have emerged...

  16. [Effects of pesticides and plant bio-stimulants on the germination of chlamydospores and in vitro development of the nematophagous fungus Pochonia chlamydosporia].

    Science.gov (United States)

    Ceiro, Wilson G; Arévalo, Jersys; Hidalgo-Díaz, Leopoldo

    2015-01-01

    The effects of pesticides and plant bio-stimulants used in protected vegetable production systems on the fungus Pochonia chlamydosporia are unknown. The effectiveness of P. chlamydosporia against Meloidogyne spp. could be affected by products used in protected vegetable production systems. Two in vitro assays were carried out to evaluate any potential effect that pesticides and bio-stimulants often used in these systems could have on the fungus. The effect on chlamydospore germination was evaluated in a first assay, and mycelia growth and sporulation in a second. With these results, the compatibility of each product with the fungus was determined. Chlamydospores germination was over 50% with the control, FitoMas E, Biobras-16 and Amidor. Lower results were observed with other products, with some of them even inhibiting germination completely. Fungal growth was potentiated by Biobras-16 to 106.23%, promoted up to 50-100% by the control, FitoMas E and Cuproflow, and was below 50% with the rest of the products.Cipermetrina, Benomilo, Zineb, Mitigan, Karate, FitoMas E and Amidor promoted fungal sporulation, which was below 50% with Cuproflow and completely inhibited by the other products. Fifty-four percent of the products evaluated were compatible with P. chlamydosporia, while 8% were toxic and 38%, very toxic. Cipermetrina, Karate, Amidor, Benomilo, Zineb, Mitigan and FitoMas E were compatible with P. chlamydosporia. If it is necessary to use any of the other products for integrated pest management in protected vegetable production systems, it is recommended to avoid direct contact with P. chlamydosporia. Copyright © 2013 Revista Iberoamericana de Micología. Published by Elsevier Espana. All rights reserved.

  17. Recent Advances in the Sound Insulation Properties of Bio-based Materials

    Directory of Open Access Journals (Sweden)

    Xiaodong Zhu

    2013-12-01

    Full Text Available Many bio-based materials, which have lower environmental impact than traditional synthetic materials, show good sound absorbing and sound insulation performances. This review highlights progress in sound transmission properties of bio-based materials and provides a comprehensive account of various multiporous bio-based materials and multilayered structures used in sound absorption and insulation products. Furthermore, principal models of sound transmission are discussed in order to aid in an understanding of sound transmission properties of bio-based materials. In addition, the review presents discussions on the composite structure optimization and future research in using co-extruded wood plastic composite for sound insulation control. This review contributes to the body of knowledge on the sound transmission properties of bio-based materials, provides a better understanding of the models of some multiporous bio-based materials and multilayered structures, and contributes to the wider adoption of bio-based materials as sound absorbers.

  18. Bio-based Industries Joint Undertaking: The catalyst for sustainable bio-based economic growth in Europe.

    Science.gov (United States)

    Mengal, Philippe; Wubbolts, Marcel; Zika, Eleni; Ruiz, Ana; Brigitta, Dieter; Pieniadz, Agata; Black, Sarah

    2018-01-25

    This article discusses the preparation, structure and objectives of the Bio-based Industries Joint Undertaking (BBI JU). BBI JU is a public-private partnership (PPP) between the European Commission (EC) and the Bio-based Industries Consortium (BIC), the industry-led private not-for-profit organisation representing the private sectors across the bio-based industries. The model of the public-private partnership has been successful as a new approach to supporting research and innovation and de-risking investment in Europe. The BBI JU became a reality in 2014 and represents the largest industrial and economic cooperation endeavour financially ever undertaken in Europe in the area of industrial biotechnologies. It is considered to be one of the most forward-looking initiatives under Horizon 2020 and demonstrates the circular economy in action. The BBI JU will be the catalyst for this strategy to mobilise actors across Europe including large industry, small and medium-sized enterprises (SMEs), all types of research organisations, networks and universities. It will support regions and in doing so, the European Union Member States and associated countries in the implementation of their bioeconomy strategies. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. A comparative review of petroleum-based and bio-based acrolein production.

    Science.gov (United States)

    Liu, Lu; Ye, X Philip; Bozell, Joseph J

    2012-07-01

    Acrolein is an important chemical intermediate for many common industrial chemicals, leading to an array of useful end products. This paper reviews all the synthetic methods, including the former (aldol condensation) and contemporary (partial oxidation of propylene) manufacturing methods, the partial oxidation of propane, and most importantly, the bio-based glycerol-dehydration route. Emphasis is placed on the petroleum-based route from propylene and the bio-based route from glycerol, an abundantly available and relatively inexpensive raw material available from biodiesel production. This review provides technical details and incentives for industrial proyduction that justify a transition toward bio-based acrolein production. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Replacing fossil based plastic performance products by bio-based plastic products-Technical feasibility.

    Science.gov (United States)

    van den Oever, Martien; Molenveld, Karin

    2017-07-25

    Larger scale market introduction of new bio-based products requires a clear advantage regarding sustainability, as well as an adequate techno-economic positioning relative to fossil based products. In a previous paper [Broeren et al., 2016], LCA results per kg and per functionality equivalent of bio-based plastics were presented, together with economic considerations. The present paper discusses the mechanical and thermal properties of a range of commercially available bio-based plastics based on polylactic acid (PLA), cellulose esters, starch and polyamides, and the feasibility of replacing fossil-based counterparts based on performance. The evaluation is approached from an end user perspective. First, potentially suitable bio-based plastics are selected based on manufacturers' specifications in technical data sheets, then a first experimental evaluation is performed on injection moulded ISO specimens, and finally a further selection of plastics is tested on large 50×70cm panels. This technical feasibility study indicates that so far bio-based plastics do not completely match the properties of high performance materials like flame retardant V-0 PC/ABS blends used in electronic devices. The performance gap is being decreased by the development of stereocomplex PLA and hybrid PLA blends with polycarbonate, which offer clearly improved properties with respect to maximum usage temperature and toughness. In addition, several materials meet the V-0 flammability requirements needed in specific durable applications. On the other hand, improving these properties so far has negative consequences for the bio-based content. This study also shows that replacement of bulk polymers like PS is feasible using PLA compounds with a bio-based content as high as 85%. Copyright © 2016 Elsevier B.V. All rights reserved.

  1. Determining the bio-based content of bio-plastics used in Thailand by radiocarbon analysis

    Science.gov (United States)

    Ploykrathok, T.; Chanyotha, S.

    2017-06-01

    Presently, there is an increased interest in the development of bio-plastic products from agricultural materials which are biodegradable in order to reduce the problem of waste disposal. Since the amount of modern carbon in bio-plastics can indicate how much the amount of agricultural materials are contained in the bio-plastic products, this research aims to determine the modern carbon in bio-plastic using the carbon dioxide absorption method. The radioactivity of carbon-14 contained in the sample is measured by liquid scintillation counter (Tri-carb 3110 TR, PerkinElmer). The percentages of bio-based content in the samples were determined by comparing the observed modern carbon content with the values contained in agricultural raw materials. The experimental results show that only poly(lactic acid) samples have the modern carbon content of 97.4%, which is close to the agricultural materials while other bio-plastics types are found to have less than 50% of the modern carbon content. In other words, most of these bio-plastic samples were mixed with other materials which are not agriculturally originated.

  2. Determining the bio-based content of bio-plastics used in Thailand by radiocarbon analysis

    International Nuclear Information System (INIS)

    Ploykrathok, T; Chanyotha, S

    2017-01-01

    Presently, there is an increased interest in the development of bio-plastic products from agricultural materials which are biodegradable in order to reduce the problem of waste disposal. Since the amount of modern carbon in bio-plastics can indicate how much the amount of agricultural materials are contained in the bio-plastic products, this research aims to determine the modern carbon in bio-plastic using the carbon dioxide absorption method. The radioactivity of carbon-14 contained in the sample is measured by liquid scintillation counter (Tri-carb 3110 TR, PerkinElmer). The percentages of bio-based content in the samples were determined by comparing the observed modern carbon content with the values contained in agricultural raw materials. The experimental results show that only poly(lactic acid) samples have the modern carbon content of 97.4%, which is close to the agricultural materials while other bio-plastics types are found to have less than 50% of the modern carbon content. In other words, most of these bio-plastic samples were mixed with other materials which are not agriculturally originated. (paper)

  3. Development of bio-hybrid material based on Salmonella ...

    African Journals Online (AJOL)

    The immobilization of a whole microbial cell is an important process used in nanotechnology of biosensors and other related fields, especially the development of bio-hybrid materials based on live organisms and inorganic compounds. Here, we described an essay to develop a bio-hybrid material based on Salmonella ...

  4. Environmental indicators and bio monitoring: Costa Rica experience

    International Nuclear Information System (INIS)

    Ruiz Hidalgo, K.

    2012-01-01

    An experience carried out on rice, watermelon and melon crops were applied in Costa Rica. In sediment and water samples using bio monitoring techniques were found pesticides and pollution levels.The water bodies, sediments and ecological quality was determined by the BMWP- CR Index technique.

  5. Life cycle impact assessment of bio-based plastics from sugarcane ethanol

    NARCIS (Netherlands)

    Tsiropoulos, I.; Faaij, A. P C; Lundquist, L.; Schenker, U.; Briois, J. F.; Patel, M. K.

    2015-01-01

    The increasing production of bio-based plastics calls for thorough environmental assessments. Using life cycle assessment, this study compares European supply of fully bio-based high-density polyethylene and partially bio-based polyethylene terephthalate from Brazilian and Indian sugarcane ethanol

  6. A glyphosate-based pesticide impinges on transcription

    International Nuclear Information System (INIS)

    Marc, Julie; Le Breton, Magali; Cormier, Patrick; Morales, Julia; Belle, Robert; Mulner-Lorillon, Odile

    2005-01-01

    Widely spread chemicals used for human benefits may exert adverse effects on health or the environment, the identification of which are a major challenge. The early development of the sea urchin constitutes an appropriate model for the identification of undesirable cellular and molecular targets of pollutants. The widespread glyphosate-based pesticide affected sea urchin development by impeding the hatching process at millimolar range concentration of glyphosate. Glyphosate, the active herbicide ingredient of Roundup, by itself delayed hatching as judged from the comparable effect of different commercial glyphosate-based pesticides and from the effect of pure glyphosate addition to a threshold concentration of Roundup. The surfactant polyoxyethylene amine (POEA), the major component of commercial Roundup, was found to be highly toxic to the embryos when tested alone and therefore could contribute to the inhibition of hatching. Hatching, a landmark of early development, is a transcription-dependent process. Correlatively, the herbicide inhibited the global transcription, which follows fertilization at the 16-cell stage. Transcription inhibition was dose-dependent in the millimolar glyphosate range concentration. A 1257-bp fragment of the hatching enzyme transcript from Sphaerechinus granularis was cloned and sequenced; its transcription was delayed by 2 h in the pesticide-treated embryos. Because transcription is a fundamental basic biological process, the pesticide may be of health concern by inhalation near herbicide spraying at a concentration 25 times the adverse transcription concentration in the sprayed microdroplets

  7. Can bio-based attributes upgrade a brand? How partial and full use of bio-based materials affects the purchase intention of brands

    NARCIS (Netherlands)

    Reinders, Machiel J.; Onwezen, Marleen C.; Meeusen, Marieke J.G.

    2017-01-01

    To reduce human dependency on fossil fuels, increasing attempts are being made to substitute synthetic materials in products with bio-based materials. Global brands attempt to differentiate themselves by adding bio-based materials to their products. However, little is known about consumers'

  8. Safe water supply without disinfection in a large city case study: Berlin.

    Science.gov (United States)

    Grohmann, A; Petersohn, D

    2000-01-01

    Berlin's water supplies originate exclusively from groundwater. For sustainable water management, river water is treated by flocculation and filtration and used either for artificial groundwater recharge (rivers Spree and Havel) or for bank filtration (Nordgraben and Lake Tegel). Drinking water chlorination was abandoned in Berlin (West) in 1978, and in Berlin (East) in 1992, following German unification. Chlorine consumption for the purpose of weekly performance checks in the chlorination plants of Berlin's 11 waterworks and occasional chlorination within the pipe system following pipe burst events amounts to 2500 kg per year. Based on the annual water demand of 250 million cubic metres, this is equivalent to 0.01 mg of chlorine per litre. Microbiological monitoring at the 11 waterworks and at 383 sampling points within the pipe system shows CFU at less than 10/1 ml-1 and coliforms and E. coli invariably at 0/100 ml-1. In view of the low AOX content, a multiplication of bacteria within the pipe system can be expected to occur not at all or only to a small extent. Resource protection measures, filter backwashing and pipe system maintenance in observance of the relevant technical rules will continue to ensure that the quality of Berlin's drinking water meets stringent hygiene requirements without chlorination.

  9. Processing and characterization of bio-based composites

    Science.gov (United States)

    Lu, Hong

    Much research has focused on bio-based composites as a potential material to replace petroleum-based plastics. Considering the high price of Polyhydroxyalkanoates (PHAs), PHA/ Distiller's Dried Grains with Solubles (DDGS) composite is a promising economical and high-performance biodegradable material. In this paper, we discuss the effect of DDGS on PHA composites in balancing cost with material performance. Poly (lactic acid) PLA/DDGS composite is another excellent biodegradable composite, although as a bio-based polymer its degradation time is relatively long. The goal of this research is therefore to accelerate the degradation process for this material. Both bio-based composites were extruded through a twin-screw microcompounder, and the two materials were uniformly mixed. The morphology of the samples was examined using a Scanning Electron Microscope (SEM); thermal stability was determined with a Thermal Gravimetric Analyzer (TGA); other thermal properties were studied using Differential Scanning Calorimetry (DSC) and a Dynamic Mechanical Analyzer (DMA). Viscoelastic properties were also evaluated using a Rheometer.

  10. Electropolis Berlin. Power for a big city. Construction programmes and negotiations for electric power supply in the city of Berlin; Elektropolis Berlin. Die Energie der Grossstadt. Bauprogramme und Aushandlungsprozesse zur oeffentlichen Elektrizitaetsversorgung in Berlin

    Energy Technology Data Exchange (ETDEWEB)

    Dame, Thorsten

    2011-07-01

    The author presents a case study from the view of economic and architectural history, i.e. the history and development of the Berlin utility, Berliner Elektrizitaetswerke. It is shown that planning, design and construction were not the result of a dialogue between the architect and the utility but that economic, political and cultural goals of policy and public administration had to be integrated as well. The architecture of the industrial buildings therefore should be viewed as part of the community relations in general, i.e. as an element of the interaction between private, state and civilian society interests.

  11. Resource recovery from bio-based production processes: a future necessity?

    DEFF Research Database (Denmark)

    Mansouri, Seyed Soheil; S.B.A. Udugama, Isuru; Cignitti, Stefano

    2017-01-01

    The promise of transforming waste streams with small economic value into valuable products makes resource recovery technologies in bio-based production processes an attractive proposition. However, the use of resource recovery technologies in industrial applications is still minimal, despite its...... technologies to industrial bio-based production processes. The role and importance of economics, technology readiness and socio-environmental impacts of resource recovery in successfully implementing resource recovery technologies in industrial bio-based production processes is also discussed. Finally, based...... wide use in closely related processes such as dairy production. In this paper, a perspective on the role of resource recovery in bio-based production processes is provided through reviewing the past practice and identifying the benefits, opportunities and challenges of introducing resource recovery...

  12. High-speed train Oslo-Berlin

    DEFF Research Database (Denmark)

    Jespersen, Per Homann

    Indlæggets baggrund og formål I det såkaldte COINCO-projekt, et INTERREG-projekt støttet af regioner og byer mellem Oslo og Berlin, er der udviklet en strategi for et tættere samarbejde i korridoren (Jespersen et al. 2007). Udbygning af infrastrukturen for passagerer og gods er en væsentlig del h...... Oslo - Göteborg". Sluttrapport. Jespersen, P. H., Jensen, A., Stroschein, C., & Lundgren, A. 2007, COINCO - Corridor of Innovation and Cooperation - Strategy 2025. Landex, A. 2006, Railway Capacity Oslo-Berlin, Center for Trafik og Transport, Danmarks Tekniske Universitet, Lyngby.  ...

  13. Using serious games and virtual worlds in pesticides transport teaching

    Science.gov (United States)

    Payraudeau, Sylvain; Alvarez-Zaldivar, Pablo; van Dijk, Paul; Imfeld, Gwenaël

    2017-04-01

    Teaching environmental scenarios, such as the availability and transport of pesticides in catchments, may fail with traditional lectures and tutorials due to the complex and synergic interplay of soil, landuse, compounds properties, hydroclimatic forcing and biogeochemical processes. To tackle and pedagogically enter into this complexity, virtual worlds (i.e. computer-based simulated environment) and serious games (i.e. applied games with added pedagogical value) can efficiently improve knowledge and know-how of the future water management stakeholders and scientists. We have developed an e-learning teaching unit using virtual catchments and serious games by gradually adapting the level of complexity depending of the targeted public. The first targeted group is farmers in continuing education centers. We developed a distributed pesticide transport tool in a virtual agricultural catchment to highlight the specific risks of off-site pesticide transport along crop growing season. Students of this first group can interactively define and combine climatic, land-use and soil type scenarios with different pesticides to experiment the components of worst-case situations and to propose best-management practices depending of the involved environmental compartments, i.e. atmosphere, soil, surface water or groundwater. For Master's degree students, we added a level of complexity by adding a specific module focusing on pesticide degradation using cutting-edge approaches. With the compound-specific isotope analysis (CSIA) module students are able to link the 13C/12C signature of pesticides to the ongoing dissipation processes within the catchment. By using and interpreting CSIA data, students can thus efficiently understand the difference between non-destructive (e.g. sorption) and destructive (e.g. bio and abiotic degradation) processes occurring in a catchment. This CSIA tool applied to a virtual agricultural catchment will also allow to distinguish the dilution effect from

  14. Bio-based and biodegradable plastics for use in crop production.

    Science.gov (United States)

    Riggi, Ezio; Santagata, Gabriella; Malinconico, Mario

    2011-01-01

    The production and management of crops uses plastics for many applications (e.g., low tunnels, high tunnels, greenhouses, mulching, silage bags, hay bales, pheromone traps, coatings of fertilizers or pesticides or hormones or seeds, and nursery pots and containers for growing transplants). All these applications have led some authors to adopt the term "plasticulture" when discussing the use of plastic materials in agriculture and related industries. Unfortunately, the sustainability of this use of plastics is low, and renewability and degradability have become key words in the debate over sustainable production and utilization of plastic. Recently, researchers and the plastics industry have made strong efforts (i) to identify new biopolymers and natural additives from renewable sources that can be used in plastics production and (ii) to enhance the degradability (biological or physical) of the new ecologically sustainable materials. In the present review, we describe the main research results, current applications, patents that have been applied for in the last two decades, and future perspectives on sustainable use of plastics to support crop production. The article presents some promising patents on bio-based and biodegradable plastics for use in crop production.

  15. Bio-Based Coatings for Paper Applications

    Directory of Open Access Journals (Sweden)

    Vibhore Kumar Rastogi

    2015-11-01

    Full Text Available The barrier resistance and wettability of papers are commonly controlled by the application of petroleum-based derivatives such as polyethylene, waxes and/or fluor- derivatives as coating. While surface hydrophobicity is improved by employing these polymers, they have become disfavored due to limitations in fossil-oil resources, poor recyclability, and environmental concerns on generated waste with lack of biodegradation. Alternatively, biopolymers including polysaccharides, proteins, lipids and polyesters can be used to formulate new pathways for fully bio-based paper coatings. However, difficulties in processing of most biopolymers may arise due to hydrophilicity, crystallization behavior, brittleness or melt instabilities that hinder a full exploitation at industrial scale. Therefore, blending with other biopolymers, plasticizers and compatibilizers is advantageous to improve the coating performance. In this paper, an overview of barrier properties and processing of bio-based polymers and their composites as paper coating will be discussed. In particular, recent technical advances in nanotechnological routes for bio-based nano- composite coatings will be summarized, including the use of biopolymer nanoparticles, or nanofillers such as nanoclay and nanocellulose. The combination of biopolymers along with surface modification of nanofillers can be used to create hierarchical structures that enhance hydrophobicity, complete barrier protection and functionalities of coated papers.

  16. Bio-based Polymer Foam from Soyoil

    Science.gov (United States)

    Bonnaillie, Laetitia M.; Wool, Richard P.

    2006-03-01

    The growing bio-based polymeric foam industry is presently lead by plant oil-based polyols for polyurethanes and starch foams. We developed a new resilient, thermosetting foam system with a bio-based content higher than 80%. The acrylated epoxidized soybean oil and its fatty acid monomers is foamed with pressurized carbon dioxide and cured with free-radical initiators. The foam structure and pore dynamics are highly dependent on the temperature, viscosity and extent of reaction. Low-temperature cure hinds the destructive pore coalescence and the application of a controlled vacuum results in foams with lower densities ˜ 0.1 g/cc, but larger cells. We analyze the physics of foam formation and stability, as well as the structure and mechanical properties of the cured foam using rigidity percolation theory. The parameters studied include temperature, vacuum applied, and cross-link density. Additives bring additional improvements: nucleating agents and surfactants help produce foams with a high concentration of small cells and low bulk density. Hard and soft thermosetting foams with a bio content superior to 80% are successfully produced and tested. Potential applications include foam-core composites for hurricane-resistant housing, structural reinforcement for windmill blades, and tissue scaffolds.

  17. Comparative toxicity of two azadirachtin-based neem pesticides to Daphnia pulex.

    Science.gov (United States)

    Goktepe, Ipek; Plhak, Leslie C

    2002-01-01

    Azadirachtin (AZA)-based pesticides (Neemix and Bioneem) demonstrated toxicity in 48-h nonrenewal toxicity assays using Daphnia pulex at levels that were comparable with several organophosphate pesticides. The median lethal concentration (LC50) values for the two neem pesticides were found to be 0.028 and 0.033 microl/ml, respectively. The LC50 value for nonformulated (95% pure) AZA was determined to be 0.382 microg AZA/ml. Neemix and Bioneem were exposed to air and northern sky daylight in a light box at 24 and 37 degrees C for 1, 3, 6, and 9 d. Standard 48-h acute toxicity tests were used to determine the effect of aging in these dry environmental conditions. Neemix and Bioneem were also fractionated into volatile and nonvolatile fractions, and the toxicity of each was tested. Compared with Neemix, Bioneem remained toxic longer when exposed to light and air at 37 degrees C, indicating that this pesticide may be less prone to environmental degradation. When fractionated, the nonvolatile fractions for both pesticides exhibited significantly lower LC50 values than the full formulations. These results suggest that, depending on the application rate and environmental fate, AZA-based pesticides may have direct adverse effects on aquatic organisms and that the toxicity and stability of formulated pesticides depend on factors other than only the AZA concentration.

  18. SYNTHESIS AND CHARACTERIZATION OF BIO-BASED POLYESTER POLYOL

    Directory of Open Access Journals (Sweden)

    MİTHAT ÇELEBİ

    2016-11-01

    Full Text Available Polyurethanes are versatile polymeric materials and are usually synthesised by isocyanate reactions with polyols. Due to the variety of isocyanates and polyols, particularly polyols, polyurethanes can be easily tailored for wide applications, such as rigid and flexible foams, coatings, adhesives, and elastomers. Considerable efforts have been recently devoted to developing bio-based substitutes for petroleum-based polyuretahanes due to increasing concerns over the depletion of petroleum resources, environment, and sustainability. Polyester polyols based on aliphatic and aromatic dicarboxylic acids are one of the most important materials in polymer technologies. Large volume of plants oils are used as renewable resources to produce various chemicals which are industrially important to make soaps, cosmetic products, surfactants, lubricants, diluents, plasticizers, inks, agrochemicals, composite materials, food industry. This study introduces synthesis and properties of bio-based polyols from different renewable feedstocks including vegetable oils and derivatives. A comparison of bio-based polyol properties with their petroleum-based analogues were investigated.

  19. Opportunity and development of bio-based composites

    Science.gov (United States)

    Zhiyong Cai; Jerrold E. Winandy

    2005-01-01

    Our forests are a naturally renewable resource that has been used as a principal source of bio-energy and building materials for centuries. The rapid growth of world population has now resulted in substantial increases in demand and in consumption of all raw materials. This now provides a unique opportunity of developing new bio-based composites. The 100-year history...

  20. Exemplary design of climate-friendly waste management in the State of Berlin; Vorbildhafte Konzeption einer klimavertraeglichen Abfallentsorgung im Land Berlin

    Energy Technology Data Exchange (ETDEWEB)

    Vogt, Regine; Fehrenbach, Horst [ifeu - Institut fuer Energie- und Umweltforschung Heidelberg GmbH, Heidelberg (Germany); Wiegel, Ulrich; Ebert, Knud [ICU - Ingenieurconsulting Umwelt und Bau Berlin, Berlin (Germany); Schwilling, Thomas; Mehner, Heidelinde [SenStadtUm - Senatsverwaltung fuer Stadtentwicklung und Umwelt, Berlin (Germany). Referat Abfallwirtschaft

    2013-05-15

    On behalf of the Senate Department for Environment of the State of Berlin IFEU Heidelberg and ICU Berlin analysed a climate friendly waste treatment for the 36 most important waste types. The inventory for 2010 showed that the management of the 6.7 million tonnes of waste in the State of Berlin led to a remarkable prevention of greenhouse gas emissions of about -900,000 tonnes of CO{sub 2}-equivalents. Treatment optimisation for half of the waste types and increased source separation of dry recyclables and organics can lead to an additional mitigation of greenhouse gases of about -248,000 tonnes CO{sub 2}-equivalents. The impact of waste management on the global warming potential was determined using the standardised LCA method modified for waste management. A key element of the study was the intensive and constructive exchange with stakeholders. The results were integrated into an action plan based on the findings of the analysis of potentials and optimisation scenarios. For the relevant waste types of municipal origin property specifications were prepared. The specifications include distinct minimum criteria for an optimised treatment to reach the identified waste specific greenhouse gas reductions. The focus of the study was on climate change. A second study will be extended to further important environmental impacts like resource saving. (orig.)

  1. Rapid Detection Technology for Pesticides Residues Based on Microelectrodes Impedance Immunosensor

    Directory of Open Access Journals (Sweden)

    Wen Ping Zhao

    2014-09-01

    Full Text Available Compared with conventional methods, electrochemical immunosensors have many advantages, such as low cost, high sensitivity, and rapid detection, and has certain prospects for realizing real-time-monitoring. In this paper, a design of portable pesticide residues detection instrument was presented based on an electrochemical impedance immunosensor. Firstly, we studied on an impedance immunosensor based on interdigitated array microelectrode (IDAM coupled with magnetic nanobeads-antibody conjugates (MNAC for the pesticide detection. Magnetic nanobeads (diameter 150 nm coated with anti-carbofuran antibodies were used for further amplification of the binding reaction between antibody and hapten (carbofuran. Secondly, in order to develop a portable pesticide residue apparatus, we designed the impedance detection electric circuit. Main work included designing and constructing of the system circuit, designing and debugging of the system software and so on. Thirdly, the apparatus was used for the standard pesticides solutions testing combined with immunosensor to test the reliability and stability. The pesticide added standard recovery was more than 70 % and the impedance test error was less than 5 %. The results showed that the proposed instrument had a good consistence compared with the traditional analytical methods. Thus, it would be a promising rapid detection instrument for pesticide residues in agricultural products.

  2. Challenging a Home Country: A Preliminary Account of Indonesian Student Activism in Berlin, Germany

    Directory of Open Access Journals (Sweden)

    Syafiq Hasyim

    2014-12-01

    Full Text Available This article gives an overview on Indonesian student activism in Berlin, Germany. Based on documents (published and unpublished, interviews, and conversations with former and current student activists, the paper scrutinizes the trajectory of activism of Indonesian students in the capital of Germany since the 1960s and asks about the evolution of specific student organizations, the issues and topics they tackled, and their media and networking strategies. The article illustrates the activities of the PPI Berlin as a dominant example of Indonesian students’ political activism abroad and the activities of Indonesian Muslim students as a prominent example of religious-based activism which has gained significance since the fall of Suharto. These examples indicate the diversity of Indonesian student activists in Berlin that are nevertheless united in their aspirations to challenge politics back home.

  3. Dead Center: Berlin, the Postmodern Gothic, and Norman Ohler's Mitte

    Directory of Open Access Journals (Sweden)

    Steffen H. Hantke

    2006-06-01

    Full Text Available Cultural critics often frame present-day Berlin as a space of historical discontinuities, a nexus of modernity and postmodernity that, in its orientation toward the future, represents post-reunification Germany in all its complexity. However, this framing tends to suppress Gothic imagery, of which traces can be found in the critical discourse on the city. Recuperating such Gothic tropes from critical discourse, and then consciously and strategically re-deploying them, can be a valuable strategy for opening up new venues of thinking about the lingering presence of the past, the high cost of modernization, and the uncanny emotional and affective dimensions of urban space. While this project of recuperation has been taken on in some critical analyses of Berlin, most notably among them Brian Ladd's The Ghosts of Berlin (1997, it is the new German literature on Berlin that proceeds more boldly into the terrain of the Gothic. Among this new "Berlin literature," Norman Ohler's critically acclaimed Gothic novel Mitte (2001 stands out as a cogent analysis of the new Berlin and of the problems of inhabiting a decentralized urban space and reconnecting it to authentic historical experience.

  4. Zweiwegintegration durch zweisprachige Bildung? Ergebnisse aus der Staatlichen Europa-Schule Berlin

    Science.gov (United States)

    Meier, Gabriela

    2012-06-01

    While there is no simple recipe of how to respond to the multitude of languages present in many European schools, this article presents a promising alternative to monolingual education. The focus is on Staatliche Europa-Schule Berlin (SESB), a two-way immersion (TWI) model that unites children whose mother tongue is German with children whose mother tongue is another locally spoken language in one class and teaches them together in two languages. Thus in this model, offered by 17 primary schools and 13 secondary schools in Berlin, pupils learn in two languages from and with each other. Based on a largely quantitative, quasi-experimental study with 603 students, evidence is provided that there are a number of peace-linguistic benefits that can promote two-way social integration, besides fostering personal and societal multilingualism. This suggests that TWI education as practised in Berlin could serve as an educational model for other multilingual parts of Europe.

  5. Bio-Based Polyurethane Containing Isosorbide for Use in Composites and Coatings

    Science.gov (United States)

    2015-04-01

    ARL-TR-7259 ● APR 2015 US Army Research Laboratory Bio-Based Polyurethane Containing Isosorbide for Use in Composites and...copyright notation hereon. ARL-TR-7259 ● APR 2015 US Army Research Laboratory Bio-Based Polyurethane Containing Isosorbide for Use...4. TITLE AND SUBTITLE Bio-Based Polyurethane Containing Isosorbide for Use in Composites and Coatings 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c

  6. Evaluation of soil solarisation and bio-fumigation for the ...

    African Journals Online (AJOL)

    Soil-borne plant pathogens cause heavy losses to all major crops, leading to reductions in both yield and quality. Soil solarisation and bio-fumigation offer disease management options that are safe and reduce the use of pesticides for soil-borne plant pathogens. Mustard plant releases antimicrobial hydrolysis products, ...

  7. Bio-Based Adhesives and Evaluation for Wood Composites Application

    Directory of Open Access Journals (Sweden)

    Fatemeh Ferdosian

    2017-02-01

    Full Text Available There has been a rapid growth in research and innovation of bio-based adhesives in the engineered wood product industry. This article reviews the recent research published over the last few decades on the synthesis of bio-adhesives derived from such renewable resources as lignin, starch, and plant proteins. The chemical structure of these biopolymers is described and discussed to highlight the active functional groups that are used in the synthesis of bio-adhesives. The potentials and drawbacks of each biomass are then discussed in detail; some methods have been suggested to modify their chemical structures and to improve their properties including water resistance and bonding strength for their ultimate application as wood adhesives. Moreover, this article includes discussion of techniques commonly used for evaluating the petroleum-based wood adhesives in terms of mechanical properties and penetration behavior, which are expected to be more widely applied to bio-based wood adhesives to better evaluate their prospect for wood composites application.

  8. Touring Berlin

    OpenAIRE

    Farías, Ignacio

    2009-01-01

    Mittels einer Untersuchung von standardisierten Praktiken (Stadtrundgängen und Stadtrundfahrten) und Dispositiven (Stadtkarten, Reiseführer) fürs „Touren“ von Städten zeigt diese Dissertation, (1) wie die Stadt Berlin in ein virtuelles Objekt, nämlich, einen touristischen Zielort, transformiert wird, ( 2) wie diese Transformation nicht nur durch die Bewegung von Touristen im Raum und das Unterwegssein ermöglicht wird, sondern durch touristische Kommunikation über die Stadt, und (3) wie diese ...

  9. Landscape changes in East Berlin after 1989

    OpenAIRE

    Dellenbaugh, Mary Hartshorn

    2014-01-01

    Die Arbeit behandelt eine Reihe zusammenhängender Veränderungen, die nach dem Fall der Mauer im Ostteil von Berlin stattfanden. In drei Aufsätzen wird die Geschichte des unmittelbaren Wandels der Diskurse über Raumtypologien dargestellt, die symbolische Aneignung beschrieben, die in den Aushandlungsprozessen um die Schaffung einer vereinten Berliner Innenstadt stattfand und die Auswirkungen der Veränderungen in der diskursiven und symbolischen Neuausrichtung am Beispiel der Entwicklung zweie...

  10. Berlin Mitte: Alexanderplatz and Friedrichstaße: Urban and historical images

    Directory of Open Access Journals (Sweden)

    Aranđelović Biljana

    2014-01-01

    Full Text Available Berlin Mitte is one of the most interesting parts of the city, located in the core of Berlin where every corner and stone can tell a story. Mitte, the cultural center of Berlin is also known as the political and economic hub of Berlin. This paper explores the urban and historical image of two important parts of Berlin Mitte district: Alexanderplatz and Friedrichstaße. Friedrichstraße, as the main shopping and business street in this area, was planned with great attention by Prussian authorities, while the area around Alexanderplatz grew up randomly and its streets did not follow any special urban patterns. All potential international investors wanted to come to Friedrichstraße after the fall of the Wall, while Alexanderplatz was not so attractive to them. Many famous architects took part in numerous competitions regarding urban planning reconstructions of the famous Alex throughout the 20th century. These two areas of the Mitte district, Alexanderplatz and Friedrichstaße, are very important for contemporary Berlin and both areas have different problems.

  11. Evaluation of nematicidal action of some bio-agents and botanicals ...

    African Journals Online (AJOL)

    These biologically active factors exhibit the property to resist against M. incognita. Different concentrations for each treatments were used and analysis for the efficiency of bio pesticides was made effect of these concentrations were perceived on egg hatchability, gall formation, number of eggs, final nematode population, ...

  12. Predictive Methods for Dense Polymer Networks: Combating Bias with Bio-Based Structures

    Science.gov (United States)

    2016-03-16

    Combating bias with bio - based structures 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Andrew J. Guenthner...unlimited. PA Clearance 16152 Integrity  Service  Excellence Predictive methods for dense polymer networks: Combating bias with bio -based...Architectural Bias • Comparison of Petroleum-Based and Bio -Based Chemical Architectures • Continuing Research on Structure-Property Relationships using

  13. Risk-based prioritization method for the classification of groundwater pesticide pollution from agricultural regions.

    Science.gov (United States)

    Yang, Yu; Lian, Xin-Ying; Jiang, Yong-Hai; Xi, Bei-Dou; He, Xiao-Song

    2017-11-01

    Agricultural regions are a significant source of groundwater pesticide pollution. To ensure that agricultural regions with a significantly high risk of groundwater pesticide contamination are properly managed, a risk-based ranking method related to groundwater pesticide contamination is needed. In the present paper, a risk-based prioritization method for the classification of groundwater pesticide pollution from agricultural regions was established. The method encompasses 3 phases, including indicator selection, characterization, and classification. In the risk ranking index system employed here, 17 indicators involving the physicochemical properties, environmental behavior characteristics, pesticide application methods, and inherent vulnerability of groundwater in the agricultural region were selected. The boundary of each indicator was determined using K-means cluster analysis based on a survey of a typical agricultural region and the physical and chemical properties of 300 typical pesticides. The total risk characterization was calculated by multiplying the risk value of each indicator, which could effectively avoid the subjectivity of index weight calculation and identify the main factors associated with the risk. The results indicated that the risk for groundwater pesticide contamination from agriculture in a region could be ranked into 4 classes from low to high risk. This method was applied to an agricultural region in Jiangsu Province, China, and it showed that this region had a relatively high risk for groundwater contamination from pesticides, and that the pesticide application method was the primary factor contributing to the relatively high risk. The risk ranking method was determined to be feasible, valid, and able to provide reference data related to the risk management of groundwater pesticide pollution from agricultural regions. Integr Environ Assess Manag 2017;13:1052-1059. © 2017 SETAC. © 2017 SETAC.

  14. Acute pesticide poisoning and pesticide registration in Central America

    International Nuclear Information System (INIS)

    Wesseling, Catharina; Corriols, Marianela; Bravo, Viria

    2005-01-01

    The International Code of Conduct on the Distribution and Use of Pesticides of the Food and Agriculture Organization (FAO) of the United Nations has been for 20 years the most acknowledged international initiative for reducing negative impact from pesticide use in developing countries. We analyzed pesticide use and poisoning in Central America, particularly in Costa Rica and Nicaragua, and evaluated whether registration decisions are based on such data, in accordance with the FAO Code. Extensive use of very hazardous pesticides continues in Central America and so do poisonings with organophosphates, carbamates, endosulfan and paraquat as the main causative agents. Central American governments do not carry out or commission scientific risk assessments. Instead, guidelines from international agencies are followed for risk management through the registration process. Documentation of pesticide poisonings during several decades never induced any decision to ban or restrict a pesticide. However, based on the official surveillance systems, in 2000, the ministers of health of the seven Central American countries agreed to ban or restrict twelve of these pesticides. Now, almost 4 years later, restrictions have been implemented in El Salvador and in Nicaragua public debate is ongoing. Chemical and agricultural industries do not withdraw problematic pesticides voluntarily. In conclusion, the registration processes in Central America do not comply satisfactorily with the FAO Code. However, international regulatory guidelines are important in developing countries, and international agencies should strongly extend its scope and influence, limiting industry involvement. Profound changes in international and national agricultural policies, steering towards sustainable agriculture based on non-chemical pest management, are the only way to reduce poisonings

  15. Towards a carbon-negative sustainable bio-based economy.

    Science.gov (United States)

    Vanholme, Bartel; Desmet, Tom; Ronsse, Frederik; Rabaey, Korneel; Van Breusegem, Frank; De Mey, Marjan; Soetaert, Wim; Boerjan, Wout

    2013-01-01

    The bio-based economy relies on sustainable, plant-derived resources for fuels, chemicals, materials, food and feed rather than on the evanescent usage of fossil resources. The cornerstone of this economy is the biorefinery, in which renewable resources are intelligently converted to a plethora of products, maximizing the valorization of the feedstocks. Innovation is a prerequisite to move a fossil-based economy toward sustainable alternatives, and the viability of the bio-based economy depends on the integration between plant (green) and industrial (white) biotechnology. Green biotechnology deals with primary production through the improvement of biomass crops, while white biotechnology deals with the conversion of biomass into products and energy. Waste streams are minimized during these processes or partly converted to biogas, which can be used to power the processing pipeline. The sustainability of this economy is guaranteed by a third technology pillar that uses thermochemical conversion to valorize waste streams and fix residual carbon as biochar in the soil, hence creating a carbon-negative cycle. These three different multidisciplinary pillars interact through the value chain of the bio-based economy.

  16. Towards a carbon-negative sustainable bio-based economy

    Directory of Open Access Journals (Sweden)

    Bartel eVanholme

    2013-06-01

    Full Text Available The bio-based economy relies on sustainable, plant-derived resources for fuels, chemicals, materials, food and feed rather than on the evanescent usage of fossil resources. The cornerstone of this economy is the biorefinery, in which renewable resources are intelligently converted to a plethora of products, maximizing the valorization of the feedstocks. Innovation is a prerequisite to move a fossil-based economy towards sustainable alternatives, and the viability of the bio-based economy depends on the integration between plant (green and industrial (white biotechnology. Green biotechnology deals with primary production through the improvement of biomass crops, while white biotechnology deals with the conversion of biomass into products and energy. Waste streams are minimized during these processes or partly converted to biogas, which can be used to power the processing pipeline. The sustainability of this economy is guaranteed by a third technology pillar that uses thermochemical conversion to valorize waste streams and fix residual carbon as biochar in the soil, hence creating a carbon-negative cycle. These three different multidisciplinary pillars interact through the value chain of the bio-based economy.

  17. Towards a carbon-negative sustainable bio-based economy

    Science.gov (United States)

    Vanholme, Bartel; Desmet, Tom; Ronsse, Frederik; Rabaey, Korneel; Breusegem, Frank Van; Mey, Marjan De; Soetaert, Wim; Boerjan, Wout

    2013-01-01

    The bio-based economy relies on sustainable, plant-derived resources for fuels, chemicals, materials, food and feed rather than on the evanescent usage of fossil resources. The cornerstone of this economy is the biorefinery, in which renewable resources are intelligently converted to a plethora of products, maximizing the valorization of the feedstocks. Innovation is a prerequisite to move a fossil-based economy toward sustainable alternatives, and the viability of the bio-based economy depends on the integration between plant (green) and industrial (white) biotechnology. Green biotechnology deals with primary production through the improvement of biomass crops, while white biotechnology deals with the conversion of biomass into products and energy. Waste streams are minimized during these processes or partly converted to biogas, which can be used to power the processing pipeline. The sustainability of this economy is guaranteed by a third technology pillar that uses thermochemical conversion to valorize waste streams and fix residual carbon as biochar in the soil, hence creating a carbon-negative cycle. These three different multidisciplinary pillars interact through the value chain of the bio-based economy. PMID:23761802

  18. Experiencing memory museums in Berlin. The Otto Weidt Workshop for the Blind Museum and the Jewish Museum Berlin

    OpenAIRE

    Ana Souto

    2018-01-01

    This article explores memory studies from the audience’s perspective, focusing on the perception of Holocaust narratives in two museums in Berlin. This research builds on and contributes to a number of emerging issues on memory studies, tourism perception and museum design: the debate on experiential authenticity, Dark Tourism, as well as the analysis of memory studies from the perspective of the user. The main data facilitating the analysis is based on responses shared on TripAdvisor; the ca...

  19. German authors on Estonian minority rights : Selbstbestimmungsrecht und Minderheitenschutz in Estland, by Carmen Thiele. Berlin : Springer, 1999 ; Das Recht der nationalen Minderheiten in Osteuropa, edited by Georg Brunner and Boris Meissner. Berlin

    Index Scriptorium Estoniae

    Annus, Taavi, 1977-

    2004-01-01

    Arvustus: Thiele, Carmen. Selbstbestimmungsrecht und Minderheitenschutz in Estland. Berlin : Springer, 1999 ; Das Recht der nationalen Minderheiten in Osteuropa. Berlin : Berlin Verlag Arno Spitz, 1999

  20. Consumer perception of bio-based products-An exploratory study in 5 European countries

    NARCIS (Netherlands)

    Sijtsema, Siet J.; Onwezen, Marleen C.; Reinders, Machiel J.; Dagevos, Hans; Partanen, Asta; Meeusen-van Onna, Marieke

    2016-01-01

    This study explores people's perceptions (i.e., positive and negative associations, mixed feelings) regarding the concept of 'bio-based' in general and specific bio-based products. This exploratory study is one of the first consumer studies in the field of bio-based research. Three focus group

  1. Bio-based targeted chemical engineering education : Role and impact of bio-based energy and resourcedevelopment projects

    NARCIS (Netherlands)

    N.M. Márquez Luzardoa; Dr. ir. Jan Venselaar

    2012-01-01

    Avans University of Applied Sciences is redrafting its courses and curricula in view of sustainability. For chemical engineering in particular that implies a focus on 'green' and bio-based processes, products and energy. Avans is situated in the Southwest region of the Netherlands and specifically

  2. Bio-Mimetic Sensors Based on Molecularly Imprinted Membranes

    Directory of Open Access Journals (Sweden)

    Catia Algieri

    2014-07-01

    Full Text Available An important challenge for scientific research is the production of artificial systems able to mimic the recognition mechanisms occurring at the molecular level in living systems. A valid contribution in this direction resulted from the development of molecular imprinting. By means of this technology, selective molecular recognition sites are introduced in a polymer, thus conferring it bio-mimetic properties. The potential applications of these systems include affinity separations, medical diagnostics, drug delivery, catalysis, etc. Recently, bio-sensing systems using molecularly imprinted membranes, a special form of imprinted polymers, have received the attention of scientists in various fields. In these systems imprinted membranes are used as bio-mimetic recognition elements which are integrated with a transducer component. The direct and rapid determination of an interaction between the recognition element and the target analyte (template was an encouraging factor for the development of such systems as alternatives to traditional bio-assay methods. Due to their high stability, sensitivity and specificity, bio-mimetic sensors-based membranes are used for environmental, food, and clinical uses. This review deals with the development of molecularly imprinted polymers and their different preparation methods. Referring to the last decades, the application of these membranes as bio-mimetic sensor devices will be also reported.

  3. Bio-Mimetic Sensors Based on Molecularly Imprinted Membranes

    Science.gov (United States)

    Algieri, Catia; Drioli, Enrico; Guzzo, Laura; Donato, Laura

    2014-01-01

    An important challenge for scientific research is the production of artificial systems able to mimic the recognition mechanisms occurring at the molecular level in living systems. A valid contribution in this direction resulted from the development of molecular imprinting. By means of this technology, selective molecular recognition sites are introduced in a polymer, thus conferring it bio-mimetic properties. The potential applications of these systems include affinity separations, medical diagnostics, drug delivery, catalysis, etc. Recently, bio-sensing systems using molecularly imprinted membranes, a special form of imprinted polymers, have received the attention of scientists in various fields. In these systems imprinted membranes are used as bio-mimetic recognition elements which are integrated with a transducer component. The direct and rapid determination of an interaction between the recognition element and the target analyte (template) was an encouraging factor for the development of such systems as alternatives to traditional bio-assay methods. Due to their high stability, sensitivity and specificity, bio-mimetic sensors-based membranes are used for environmental, food, and clinical uses. This review deals with the development of molecularly imprinted polymers and their different preparation methods. Referring to the last decades, the application of these membranes as bio-mimetic sensor devices will be also reported. PMID:25196110

  4. Ranking system for national regulatory jurisdictions based on pesticide standard values in major exposures

    Directory of Open Access Journals (Sweden)

    Zijian Li

    2017-07-01

    Full Text Available To control the risk of human exposure to pesticides, about 50 nations have promulgated pesticide soil regulatory guidance values (RGVs, and 104 nations have provided pesticide drinking water maximum concentration levels (MCLs. In addition, 90 nations have regulated pesticide agricultural commodity maximum residue limits (MRLs. Pesticide standard values (PSVs for one single pesticide varied in a range of six, seven, or even eight orders of magnitude. Some PSVs are too large to prevent the impact of pesticides on human health. Many nations have not provided PSVs for some commonly used pesticides until now. This research has introduced several completeness values and numerical values methods to evaluate the national jurisdiction’s performance on PSVs on a nation base. The national jurisdiction ranking system developed by these methods will be beneficial to the environmental regulation makers in the management of PSVs. Results also indicate that European countries perform better in the regulation of pesticide soil RGVs, drinking water MCLs, and agricultural commodity MRLs.

  5. Rapid and sensitive suspension array for multiplex detection of organophosphorus pesticides and carbamate pesticides based on silica–hydrogel hybrid microbeads

    International Nuclear Information System (INIS)

    Wang, Xuan; Mu, Zhongde; Shangguan, Fengqi; Liu, Ran; Pu, Yuepu; Yin, Lihong

    2014-01-01

    Highlights: • Silica–hydrogel hybrid microbeads were used to develop suspension array. • The results in detecting pesticides agree well with those from LC–MS/MS. • The method showed the good capability for multiplex analysis of pesticides residues. - Abstract: A technique for multiplex detection of organophosphorus pesticides and carbamate pesticides has been developed using a suspension array based on silica–hydrogel hybrid microbeads (SHHMs). The main advantage of SHHMs, which consist of both silica and hydrogel materials, is that they not only could be distinguished by their characteristic reflection peak originating from the stop-band of the photonic crystal but also have low non-specific adsorption of proteins. Using fluorescent immunoassay, the LODs for fenitrothion, chlorpyrifos-methyl, fenthion, carbaryl and metolcarb were measured to be 0.02 ng/mL, 0.012 ng/mL, 0.04 ng/mL, 0.05 ng/mL and 0.1 ng/mL, respectively, all of which are much lower than the maximum residue limits, as reported in the European Union pesticides database. All the determination coefficients for these five pesticides were greater than 0.99, demonstrating excellent correlations. The suspension array was specific and had no significant cross-reactivity with other chemicals. The results for the detection of pesticide residues collected from agricultural samples using this method agree well with those from liquid chromatography–tandem mass spectrometry. Our results showed that this simple method is suitable for simultaneous detection of these five pesticides residues in fruits and vegetables

  6. Rapid and sensitive suspension array for multiplex detection of organophosphorus pesticides and carbamate pesticides based on silica–hydrogel hybrid microbeads

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xuan [Key Laboratory of Environmental Medicine Engineering, Ministry of Education, School of Public Health, Southeast University, Nanjing, Jiangsu (China); Mu, Zhongde; Shangguan, Fengqi [State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing, Jiangsu (China); Liu, Ran; Pu, Yuepu [Key Laboratory of Environmental Medicine Engineering, Ministry of Education, School of Public Health, Southeast University, Nanjing, Jiangsu (China); Yin, Lihong, E-mail: lhyin@seu.edu.cn [Key Laboratory of Environmental Medicine Engineering, Ministry of Education, School of Public Health, Southeast University, Nanjing, Jiangsu (China)

    2014-05-01

    Highlights: • Silica–hydrogel hybrid microbeads were used to develop suspension array. • The results in detecting pesticides agree well with those from LC–MS/MS. • The method showed the good capability for multiplex analysis of pesticides residues. - Abstract: A technique for multiplex detection of organophosphorus pesticides and carbamate pesticides has been developed using a suspension array based on silica–hydrogel hybrid microbeads (SHHMs). The main advantage of SHHMs, which consist of both silica and hydrogel materials, is that they not only could be distinguished by their characteristic reflection peak originating from the stop-band of the photonic crystal but also have low non-specific adsorption of proteins. Using fluorescent immunoassay, the LODs for fenitrothion, chlorpyrifos-methyl, fenthion, carbaryl and metolcarb were measured to be 0.02 ng/mL, 0.012 ng/mL, 0.04 ng/mL, 0.05 ng/mL and 0.1 ng/mL, respectively, all of which are much lower than the maximum residue limits, as reported in the European Union pesticides database. All the determination coefficients for these five pesticides were greater than 0.99, demonstrating excellent correlations. The suspension array was specific and had no significant cross-reactivity with other chemicals. The results for the detection of pesticide residues collected from agricultural samples using this method agree well with those from liquid chromatography–tandem mass spectrometry. Our results showed that this simple method is suitable for simultaneous detection of these five pesticides residues in fruits and vegetables.

  7. Developing a hybrid dictionary-based bio-entity recognition technique

    Science.gov (United States)

    2015-01-01

    Background Bio-entity extraction is a pivotal component for information extraction from biomedical literature. The dictionary-based bio-entity extraction is the first generation of Named Entity Recognition (NER) techniques. Methods This paper presents a hybrid dictionary-based bio-entity extraction technique. The approach expands the bio-entity dictionary by combining different data sources and improves the recall rate through the shortest path edit distance algorithm. In addition, the proposed technique adopts text mining techniques in the merging stage of similar entities such as Part of Speech (POS) expansion, stemming, and the exploitation of the contextual cues to further improve the performance. Results The experimental results show that the proposed technique achieves the best or at least equivalent performance among compared techniques, GENIA, MESH, UMLS, and combinations of these three resources in F-measure. Conclusions The results imply that the performance of dictionary-based extraction techniques is largely influenced by information resources used to build the dictionary. In addition, the edit distance algorithm shows steady performance with three different dictionaries in precision whereas the context-only technique achieves a high-end performance with three difference dictionaries in recall. PMID:26043907

  8. Developing a hybrid dictionary-based bio-entity recognition technique.

    Science.gov (United States)

    Song, Min; Yu, Hwanjo; Han, Wook-Shin

    2015-01-01

    Bio-entity extraction is a pivotal component for information extraction from biomedical literature. The dictionary-based bio-entity extraction is the first generation of Named Entity Recognition (NER) techniques. This paper presents a hybrid dictionary-based bio-entity extraction technique. The approach expands the bio-entity dictionary by combining different data sources and improves the recall rate through the shortest path edit distance algorithm. In addition, the proposed technique adopts text mining techniques in the merging stage of similar entities such as Part of Speech (POS) expansion, stemming, and the exploitation of the contextual cues to further improve the performance. The experimental results show that the proposed technique achieves the best or at least equivalent performance among compared techniques, GENIA, MESH, UMLS, and combinations of these three resources in F-measure. The results imply that the performance of dictionary-based extraction techniques is largely influenced by information resources used to build the dictionary. In addition, the edit distance algorithm shows steady performance with three different dictionaries in precision whereas the context-only technique achieves a high-end performance with three difference dictionaries in recall.

  9. Model methodology for estimating pesticide concentration extremes based on sparse monitoring data

    Science.gov (United States)

    Vecchia, Aldo V.

    2018-03-22

    This report describes a new methodology for using sparse (weekly or less frequent observations) and potentially highly censored pesticide monitoring data to simulate daily pesticide concentrations and associated quantities used for acute and chronic exposure assessments, such as the annual maximum daily concentration. The new methodology is based on a statistical model that expresses log-transformed daily pesticide concentration in terms of a seasonal wave, flow-related variability, long-term trend, and serially correlated errors. Methods are described for estimating the model parameters, generating conditional simulations of daily pesticide concentration given sparse (weekly or less frequent) and potentially highly censored observations, and estimating concentration extremes based on the conditional simulations. The model can be applied to datasets with as few as 3 years of record, as few as 30 total observations, and as few as 10 uncensored observations. The model was applied to atrazine, carbaryl, chlorpyrifos, and fipronil data for U.S. Geological Survey pesticide sampling sites with sufficient data for applying the model. A total of 112 sites were analyzed for atrazine, 38 for carbaryl, 34 for chlorpyrifos, and 33 for fipronil. The results are summarized in this report; and, R functions, described in this report and provided in an accompanying model archive, can be used to fit the model parameters and generate conditional simulations of daily concentrations for use in investigations involving pesticide exposure risk and uncertainty.

  10. Opportunities for a bio-based economy in the Netherlands

    International Nuclear Information System (INIS)

    Sanders, J.; Hoeven, D. van der

    2008-01-01

    The shift to a bio-based economy for the Netherlands is not only required because of climate change, but also for industrial strategy reasons. Traditional strongholds of the Dutch economy like the Rotterdam harbour, the agricultural sector (including the greenhouse sector, and food and feed industries) and the petrochemical industry will be affected by the new economic realities, and it is precisely to these sectors that a bio-based economy will offer new opportunities. (author)

  11. Nanomaterials-Based Optical Techniques for the Detection of Acetylcholinesterase and Pesticides

    Directory of Open Access Journals (Sweden)

    Ning Xia

    2014-12-01

    Full Text Available The large amount of pesticide residues in the environment is a threat to global health by inhibition of acetylcholinesterase (AChE. Biosensors for inhibition of AChE have been thus developed for the detection of pesticides. In line with the rapid development of nanotechnology, nanomaterials have attracted great attention and have been intensively studied in biological analysis due to their unique chemical, physical and size properties. The aim of this review is to provide insight into nanomaterial-based optical techniques for the determination of AChE and pesticides, including colorimetric and fluorescent assays and surface plasmon resonance.

  12. Evolved pesticide tolerance in amphibians: Predicting mechanisms based on pesticide novelty and mode of action

    International Nuclear Information System (INIS)

    Hua, Jessica; Jones, Devin K.; Mattes, Brian M.; Cothran, Rickey D.; Relyea, Rick A.; Hoverman, Jason T.

    2015-01-01

    We examined 10 wood frog populations distributed along an agricultural gradient for their tolerance to six pesticides (carbaryl, malathion, cypermethrin, permethrin, imidacloprid, and thiamethoxam) that differed in date of first registration (pesticide novelty) and mode-of-action (MOA). Our goals were to assess whether: 1) tolerance was correlated with distance to agriculture for each pesticide, 2) pesticide novelty predicted the likelihood of evolved tolerance, and 3) populations display cross-tolerance between pesticides that share and differ in MOA. Wood frog populations located close to agriculture were more tolerant to carbaryl and malathion than populations far from agriculture. Moreover, the strength of the relationship between distance to agriculture and tolerance was stronger for older pesticides compared to newer pesticides. Finally, we found evidence for cross-tolerance between carbaryl and malathion (two pesticides that share MOA). This study provides one of the most comprehensive approaches for understanding patterns of evolved tolerance in non-pest species. - Highlights: • We explored patterns of tolerance to six insecticides across 10 wood frog populations. • We found evidence that wood frogs have evolved tolerance to carbaryl and malathion. • The likelihood of evolved tolerance was stronger for older compared to newer pesticides. • We found evidence for cross-tolerance between carbaryl and malathion. • This is one of the most comprehensive approaches studying evolved tolerance in a non-pest species. - Using 10 wood frog populations, we detected evidence for evolved tolerance, found that the evolved tolerance depends on insecticide novelty, and found evidence for cross-tolerance.

  13. Center for BioBased Binders and Pollution Reduction Technology

    Energy Technology Data Exchange (ETDEWEB)

    Thiel, Jerry [Univ. of Northern Iowa, Cedar Falls, IA (United States)

    2013-07-01

    Funding will support the continuation of the Center for Advanced Bio-based Binders and Pollution Reduction Technology Center (CABB) in the development of bio-based polymers and emission reduction technologies for the metal casting industry. Since the formation of the center several new polymers based on agricultural materials have been developed. These new materials have show decreases in hazardous air pollutants, phenol and formaldehyde as much as 50 to 80% respectively. The polymers termed bio-polymers show a great potential to utilize current renewable agricultural resources to replace petroleum based products and reduce our dependence on importing of foreign oil. The agricultural technology has shown drastic reductions in the emission of hazardous air pollutants and volatile organic compounds and requires further development to maintain competitive costs and productivity. The project will also research new and improved inorganic binders that promise to eliminate hazardous emissions from foundry casting operations and allow for the beneficial reuse of the materials and avoiding the burdening of overcrowded landfills.

  14. Advanced biomass science and technology for bio-based products: proceedings

    Science.gov (United States)

    Chung Hse; Zehui Jiang; Mon-Lin Kuo

    2009-01-01

    This book was developed from the proceedings of the Advanced Biomass Science and Technology for Bio-Based Products Symposium held in Beijing, China, May 23-25, 2007. The symposium was designed to provide a forum for researchers, producers, and consumers of biomass and bio-based products; to exchange information and ideas; and to stimulate new research and...

  15. Risk of the research reactor BER II in Berlin

    International Nuclear Information System (INIS)

    Paulitz, Henrik; Hoevener, Barbara; Rosen, Alex

    2015-01-01

    The research reactor BER II is sited at the periphery of Berlin in the neighborhood of residential areas. The operational license is limited until December 31, 2019. The reactor is funded by the Federal Government (90%) and the city of Berlin (10%). The stress test has shown that the reactor is not secured against an aircraft crash (airliner or fast flying military jet), meltdown with remarkable radiological consequences to the public would be the consequence. Further hazards result from the radioactive waste transport, explosions and fires. The emergency measures cannot be considered to be sufficient. The city of Berlin would not be able to fulfill the required measures in case of a radiation accident.

  16. Berliner Philarmoniker ATLAS visit

    CERN Multimedia

    ATLAS Collaboration

    2017-01-01

    The Berliner Philarmoniker in on tour through Europe. They stopped on June 27th in Geneva, for a concert at the Victoria Hall. An ATLAS visit was organised the morning after, lead by the ATLAS spokesperson Karl Jakobs (welcome and overview talk) and two ATLAS guides (AVC visit and 3D movie).

  17. Engineering BioBrick vectors from BioBrick parts

    Directory of Open Access Journals (Sweden)

    Knight Thomas F

    2008-04-01

    Full Text Available Abstract Background The underlying goal of synthetic biology is to make the process of engineering biological systems easier. Recent work has focused on defining and developing standard biological parts. The technical standard that has gained the most traction in the synthetic biology community is the BioBrick standard for physical composition of genetic parts. Parts that conform to the BioBrick assembly standard are BioBrick standard biological parts. To date, over 2,000 BioBrick parts have been contributed to, and are available from, the Registry of Standard Biological Parts. Results Here we extended the same advantages of BioBrick standard biological parts to the plasmid-based vectors that are used to provide and propagate BioBrick parts. We developed a process for engineering BioBrick vectors from BioBrick parts. We designed a new set of BioBrick parts that encode many useful vector functions. We combined the new parts to make a BioBrick base vector that facilitates BioBrick vector construction. We demonstrated the utility of the process by constructing seven new BioBrick vectors. We also successfully used the resulting vectors to assemble and propagate other BioBrick standard biological parts. Conclusion We extended the principles of part reuse and standardization to BioBrick vectors. As a result, myriad new BioBrick vectors can be readily produced from all existing and newly designed BioBrick parts. We invite the synthetic biology community to (1 use the process to make and share new BioBrick vectors; (2 expand the current collection of BioBrick vector parts; and (3 characterize and improve the available collection of BioBrick vector parts.

  18. Mental constructs and the cognitive reconstruction of the Berlin wall.

    Science.gov (United States)

    Tijus, C A; Santolini, A

    1996-07-01

    In this study of how to change people's conceptions of certain facts (i.e., the position of the Berlin Wall), a surprising psychological phenomenon was discovered. In the trial test, instead of designing a wall to enclose West Berlin, most people described and drew a short and straight wall that divided the city from north to south. Two methods were created, based on two general information-processing components involved in problem solving, to study how people might repair their misconceptions by themselves. The do-it-yourself method consisted of providing people with the task of thinking about how to build the wall and then drawing it, instead of just asking them to draw it. The distance-to-goal evaluation method consisted of asking the participants how the wall they had drawn would actually prevent passage from East Germany to West Berlin. The results showed that both methods had important effects in repairing misconceptions, but improvement in performance with the distance-to-goal method was less significant for those participants who were first provided the task of thinking about how to build the wall. These findings are consistent with the hypothesis that awareness of functional properties plays an important role in structuring and restructuring mental constructs.

  19. A GIS-based method for household recruitment in a prospective pesticide exposure study

    Directory of Open Access Journals (Sweden)

    Phillips Michael J

    2008-04-01

    Full Text Available Abstract Background Recent advances in GIS technology and remote sensing have provided new opportunities to collect ecologic data on agricultural pesticide exposure. Many pesticide studies have used historical or records-based data on crops and their associated pesticide applications to estimate exposure by measuring residential proximity to agricultural fields. Very few of these studies collected environmental and biological samples from study participants. One of the reasons for this is the cost of identifying participants who reside near study fields and analyzing samples obtained from them. In this paper, we present a cost-effective, GIS-based method for crop field selection and household recruitment in a prospective pesticide exposure study in a remote location. For the most part, our multi-phased approach was carried out in a research facility, but involved two brief episodes of fieldwork for ground truthing purposes. This method was developed for a larger study designed to examine the validity of indirect pesticide exposure estimates by comparing measured exposures in household dust, water and urine with records-based estimates that use crop location, residential proximity and pesticide application data. The study focused on the pesticide atrazine, a broadleaf herbicide used in corn production and one of the most widely-used pesticides in the U.S. Results We successfully used a combination of remotely-sensed data, GIS-based methods and fieldwork to select study fields and recruit participants in Illinois, a state with high corn production and heavy atrazine use. Our several-step process consisted of the identification of potential study fields and residential areas using aerial photography; verification of crop patterns and land use via site visits; development of a GIS-based algorithm to define recruitment areas around crop fields; acquisition of geocoded household-level data within each recruitment area from a commercial vendor; and

  20. BioBoost. Biomass based energy intermediates boosting bio-fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Niebel, Andreas [Karlsruher Institut fuer Technologie (KIT), Karlsruhe (Germany). Institut fuer Katalyseforschung und -technologie (IKFT)

    2013-10-01

    To increase the share of biomass for renewable energy in Europe conversion pathways which are economic, flexible in feedstock and energy efficient are needed. The BioBoost project concentrates on dry and wet residual biomass and wastes as feedstock for de-central conversion by fast pyrolysis, catalytic pyrolysis and hydrothermal carbonization to the intermediate energy carriers oil, coal or slurry. Based on straw the energy density increases from 2 to 20-30 GJ/m{sup 3}, enabling central GW scale gasification plants for bio-fuel production. A logistic model for feedstock supply and connection of de-central with central conversion is set up and validated allowing the determination of costs, the number and location of de-central and central sites. Techno/economic and environmental assessment of the value chain supports the optimization of products and processes. The utilization of energy carriers is investigated in existing and coming applications of heat and power production and synthetic fuels and chemicals. (orig.)

  1. Pärt: Berliner Messe / Rob Cowan

    Index Scriptorium Estoniae

    Cowan, Rob

    1998-01-01

    Uuest heliplaadist "Pärt: Berliner Messe. The Beatitudes. Annum per Annum. Magnificat. Seven Magnificat Antiphons. De profundis. Polyphony / Steven Layton with Andrew Lucas" Hyperion CDA66960 (74 minutes:DDD)

  2. S-Layer Based Bio-Imprinting - Synthetic S-Layer Polymers

    Science.gov (United States)

    2015-07-09

    AFRL-OSR-VA-TR-2015-0161 S-Layer Based Bio- Imprinting - Synthetic S-Layer Polymers Dietmar Pum ZENTRUM FUER NANOBIOTECHNOLOGIE Final Report 07/09...COVERED (From - To)      01-06-2012 to 31-05-2015 4.  TITLE AND SUBTITLE S-Layer Based Bio- Imprinting - Synthetic S-Layer Polymers 5a.  CONTRACT...technology for the fabrication of nano patterned thin film imprints by using functional S-layer protein arrays as templates. The unique feature of

  3. Injection Molding and Mechanical Properties of Bio-Based Polymer Nanocomposites

    Directory of Open Access Journals (Sweden)

    Maria Chiara Mistretta

    2018-04-01

    Full Text Available The use of biodegradable/bio-based polymers is of great importance in addressing several issues related to environmental protection, public health, and new, stricter legislation. Yet some applications require improved properties (such as barrier or mechanical properties, suggesting the use of nanosized fillers in order to obtain bio-based polymer nanocomposites. In this work, bionanocomposites based on two different biodegradable polymers (coming from the Bioflex and MaterBi families and two different nanosized fillers (organo-modified clay and hydrophobic-coated precipitated calcium carbonate were prepared and compared with traditional nanocomposites with high-density polyethylene (HDPE as matrix. In particular, the injection molding processability, as well as the mechanical and rheological properties of the so-obtained bionanocomposites were investigated. It was found that the processability of the two biodegradable polymers and the related nanocomposites can be compared to that of the HDPE-based systems and that, in general, the bio-based systems can be taken into account as suitable alternatives.

  4. Built sustainability. The office building of the Federal Ministry for the Environment in Berlin; Gebaute Nachhaltigkeit. Der Berliner Dienstsitz des Bundesumweltministeriums

    Energy Technology Data Exchange (ETDEWEB)

    Mager, Hans; Schulz, Juergen; Weigand, Reinhold (comps.)

    2011-06-15

    With the move into the office building in the Stresemann Street in Berlin (Federal Republic of Germany), the Federal Ministry for the Environment, Nature Conservation and Nuclear Safety adopts a remarkable new building in the new centre of Berlin. It is the first Federal authority at all which works in a low-energy and passive house. This brochure under consideration reports on the history and architecture of the new office building as well as its sustainable energy management and life cycle assessments.

  5. Five years of proton therapy of tumours of the eye at Hahn-Meitner Institute, Berlin; Fuenf Jahre Protonentherapie von Augentumoren am Hahn-Meitner-Institut Berlin

    Energy Technology Data Exchange (ETDEWEB)

    Heufelder, J.; Cordini, D.; Heese, J.; Homeyer, H.; Kluge, H.; Morgenstern, H. [Hahn-Meitner-Inst. Berlin, Augentumortherapie (Germany); Fuchs, H. [Hahn-Meitner-Inst. Berlin, Augentumortherapie (Germany); Augenklinik, Charite - Universitaetsmedizin Berlin, Campus Benjamin Franklin (Germany); Hoecht, S.; Nausner, M.; Hinkelbein, W. [Klinik fuer Radioonkologie und Strahlentherapie, Charite - Universitaetsmedizin Berlin, Campus Benjamin Franklin (Germany); Bechrakis, N.E.; Foerster, M.H. [Augenklinik, Charite - Universitaetsmedizin Berlin, Campus Benjamin Franklin (Germany)

    2004-07-01

    Eye tumors (choroidal melanomas, iris melanomas, and choroidal hemangiomas) are being treated with 68 MeV protons since 1998 at the Ion Beam Laboratory of the Hahn-Meitner Institute of Berlin (Germany's first proton therapy center), in cooperation with the Charite University Hospital in Berlin, Campus Benjamin Franklin. The proton beam, generated via a combination of Van de Graaff accelerator and cyclotron, is prepared by passive shaping for conformal tumor irradiation. A digital X-ray verification of the tumor location with the patient in sitting position limits the position uncertainties to a maximum of 0,3 mm. The treatment planning is performed using the program EYEPLAN. OCTOPUS, a CT-based planning program developed in cooperation with the German Cancer Research Center of Heidelberg, is under pre-clinical testing. Thus far, more than 400 patients have been irradiated. The first results are comparable to those obtained in other proton therapy centers. At the end of 2002, the University Hospital of Essen has also become a cooperation partner of the Hahn-Meitner Institute. (orig.) [German] Seit 1998 werden am Ionenstrahllabor des Hahn-Meitner-Instituts Berlin (Deutschlands erster Einrichtung zur Protonentherapie) im Rahmen eines Kooperationsvertrages mit der Charite - Universitaetsmedizin Berlin, Campus Benjamin Franklin, Augentumoren (Aderhautmelanome, Irismelanome und Aderhauthaemangiome) mit 68-MeV-Protonen bestrahlt. Der mittels einer Kombination aus Van de Graaff-Beschleuniger und Zyklotron erzeugte Protonenstrahl wird passiv fuer eine konformale Bestrahlung des Tumors aufbereitet. Eine digitale Roentgenkontrolle der Lagerung des sitzenden Patienten beschraenkt die Lagerungsunsicherheit auf maximal 0,3 mm. Fuer die Bestrahlungsplanung wird das modellbasierte Planungsprogramm EYEPLAN verwendet. In vorklinischer Erprobung befindet sich das mit dem Deutschen Krebsforschungszentrum Heidelberg entwickelte CT-basierte Planungsprogramm OCTOPUS. Bisher wurden

  6. Pesticide Environmental Accounting: A method for assessing the external costs of individual pesticide applications

    International Nuclear Information System (INIS)

    Leach, A.W.; Mumford, J.D.

    2008-01-01

    The Pesticide Environmental Accounting (PEA) tool provides a monetary estimate of environmental and health impacts per hectare-application for any pesticide. The model combines the Environmental Impact Quotient method and a methodology for absolute estimates of external pesticide costs in UK, USA and Germany. For many countries resources are not available for intensive assessments of external pesticide costs. The model converts external costs of a pesticide in the UK, USA and Germany to Mediterranean countries. Economic and policy applications include estimating impacts of pesticide reduction policies or benefits from technologies replacing pesticides, such as sterile insect technique. The system integrates disparate data and approaches into a single logical method. The assumptions in the system provide transparency and consistency but at the cost of some specificity and precision, a reasonable trade-off for a method that provides both comparative estimates of pesticide impacts and area-based assessments of absolute impacts. - A method to estimate the external costs of a pesticide application based on the ecotoxicology, environmental behaviour and application rate of an active ingredient

  7. Berlin: Sustainability and Tour Guides in a Partial Dark Tourism Destination

    OpenAIRE

    Asaf Leshem

    2013-01-01

    When guiding in Berlin about the Holocaust or about the Cold War, tour guides often hear the phrase: “I didn’t come here for that, but I want to see that as well...” Many of Berlin’s 10 Million visitors per year claim to have an attraction towards both the morbid and the lighter side of the city. Following from that popular sentiment it is argued that Berlin can be defined as a Partial Dark Tourism Destination. As such, it is further argued that Berlin is prone to an increase of socio-econom...

  8. Radiotherapy of benign diseases in Berlin (West)

    International Nuclear Information System (INIS)

    Saller, A.

    1979-01-01

    1. In Berlin (West), X-ray therapy was applied during the year 1973 in 18 hospitals and by 33 practicing physicians. The 3rd quarter of the year 1973 was taken as basis for the frequency of therapeutic X-ray application. From a total of 15912 patients, 9432 were X-rayed on account of malignant diseases, 6480 because of benigne diseases. This number definitely surpasses the number of cases treated in Munich by X-ray therapy. In Berlin, this might be connected to the age structure. 2. Utilizing the quotations and calculations put down in the report about the effect of atomic radiation by the Scientific Committee of the United Nations, and the values quoted for gonadal doses in the literature, a total-GSD-value of 0.82 +- 0.2 mrem/a was calculated for hospitals and practicing physicians in Berlin. In spite of higher frequencies, this value is approximately of the same order of magnitude as the values calculated for Munich for the year 1971 by I. and H.P. Schmelz. 3. The total-GSD-value for the population of the Federal Republic of Germany resulting from artificial radiation exposure during 1976 is reported to be approximately 60 mrem. Thus, the GSD-value for the X-ray therapy of benign diseases lies approximately at 1.3% and should be of minor significance for radiation-hygienic reflections. 4. Of primary concern is still the radiation exposure to individual patients. Because of possible secondary effects, X-ray therapy for keloids and hemangiomas in infancy and youth are of particular significance. For this reason, its proportion to GSD is also in Berlin relatively large. (orig.) [de

  9. Social science studies accompanying the two Berlin research projects for energy-oriented modernisation of domestic buildings; Sozialwissenschaftliche Begleitung der beiden Berliner Forschungsvorhaben zur energiegerechten Sanierung von Wohngebaeuden

    Energy Technology Data Exchange (ETDEWEB)

    Gerth, H. [Weeber und Partner, Inst. fuer Stadtplanung und Sozialforschung, Berlin/Stuttgart (Germany)

    1997-12-31

    The initial and environment situations of the two apartment buildings in central Berlin and at Berlin-Marzahn are described including the structure of households. The procedure adopted in this social science project is also dealt with: participation and information of residents. The results of the survey among residents concerning satisfaction with redevelopment, thermal comfort prior to and after redevelopment, heating habits, and experience with automatic heating control are reported. (MSK) [Deutsch] Im Folgenden wird die Ausgangs-und Umgebungssituation der beiden Wohnhaeuser in Berlin-Mitte und Berlin-Marzahn geschildert. Dabei wird Auskunft ueber die Struktur der Haushalte gegeben. Ebenso wird die Vorgehensweise des sozialwissenschaftlichen Projekts beschrieben: Bewohnerbeteiligung und -information. Die Ergebnisse der Bewohnerbefragungen zu Zufriedenheit mit der Sanierung, zum Waermeempfinden vor und nach der Sanierung, zu Gewohnheiten in der Heizperiode, sowie zum Umgang mit der Heizungsregelungstechnik werden dargelegt.

  10. Sustainability benefits and challenges of inter-organizational collaboration in bio-based business

    NARCIS (Netherlands)

    Nuhoff-Isakhanyan, Gohar; Wubben, Emiel F.M.; Omta, S.W.F.

    2016-01-01

    Bio-based businesses are often considered to be sustainable. However, they are also linked to sustainability challenges such as deforestation and soil erosion. Encouraged to exploit innovative solutions and enhance sustainability, organizations engaged in bio-based activities extensively explore

  11. Bio-based composite pedestrian bridge. Part 2: materials and production process

    NARCIS (Netherlands)

    Lepelaar, Mark; Hoogendoorn, Alwin; Blok, Rijk; Teuffel, Patrick; Kawaguchi, K.; Ohsaki, M.; Takeuchi, T.

    2016-01-01

    The Bio-based composite bridge is a 3TU project which aims to design and realize a 14m span pedestrian bridge made from fibre-reinforced polymers (FRP) and which is introduced in part 1 of this paper. Part 2 will focus on various studies about bio-based materials, which are suitable for structural

  12. BioCreative V BioC track overview: collaborative biocurator assistant task for BioGRID.

    Science.gov (United States)

    Kim, Sun; Islamaj Doğan, Rezarta; Chatr-Aryamontri, Andrew; Chang, Christie S; Oughtred, Rose; Rust, Jennifer; Batista-Navarro, Riza; Carter, Jacob; Ananiadou, Sophia; Matos, Sérgio; Santos, André; Campos, David; Oliveira, José Luís; Singh, Onkar; Jonnagaddala, Jitendra; Dai, Hong-Jie; Su, Emily Chia-Yu; Chang, Yung-Chun; Su, Yu-Chen; Chu, Chun-Han; Chen, Chien Chin; Hsu, Wen-Lian; Peng, Yifan; Arighi, Cecilia; Wu, Cathy H; Vijay-Shanker, K; Aydın, Ferhat; Hüsünbeyi, Zehra Melce; Özgür, Arzucan; Shin, Soo-Yong; Kwon, Dongseop; Dolinski, Kara; Tyers, Mike; Wilbur, W John; Comeau, Donald C

    2016-01-01

    BioC is a simple XML format for text, annotations and relations, and was developed to achieve interoperability for biomedical text processing. Following the success of BioC in BioCreative IV, the BioCreative V BioC track addressed a collaborative task to build an assistant system for BioGRID curation. In this paper, we describe the framework of the collaborative BioC task and discuss our findings based on the user survey. This track consisted of eight subtasks including gene/protein/organism named entity recognition, protein-protein/genetic interaction passage identification and annotation visualization. Using BioC as their data-sharing and communication medium, nine teams, world-wide, participated and contributed either new methods or improvements of existing tools to address different subtasks of the BioC track. Results from different teams were shared in BioC and made available to other teams as they addressed different subtasks of the track. In the end, all submitted runs were merged using a machine learning classifier to produce an optimized output. The biocurator assistant system was evaluated by four BioGRID curators in terms of practical usability. The curators' feedback was overall positive and highlighted the user-friendly design and the convenient gene/protein curation tool based on text mining.Database URL: http://www.biocreative.org/tasks/biocreative-v/track-1-bioc/. Published by Oxford University Press 2016. This work is written by US Government employees and is in the public domain in the US.

  13. Genetic research at a fivefold children's burial from medieval Berlin.

    Science.gov (United States)

    Rothe, Jessica; Melisch, Claudia; Powers, Natasha; Geppert, Maria; Zander, Judith; Purps, Josephine; Spors, Birgit; Nagy, Marion

    2015-03-01

    Berlin originated from the two twin cities Berlin and Cölln, which both were founded at the beginning of the 13th century. However the real date of their foundation as well as the origin of the first settlers is still unknown. On the Berlin site the historic city center is still visible in the Nikolaiviertel, but the medieval origin of Cölln disappeared almost completely. In 2007 a large scale excavation, which comprised an area of about 1700m(2) of the historical center of the St. Peters church, recovers the remains of Cölln's first citizens and span a period of 500 years of medieval population. Here we present the first genetic analysis of a fivefold children's burial from excavations in Berlin. The genetic data unveiled next to ancestry and eye color data also the kinship and the gender of the five individuals. Together with the archeological context the new gained information help to shed more light on the possible reasons for this burial. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

  14. Evolution of a Structure-Searchable Database into a Prototype for a High-Fidelity SmartPhone App for 62 Common Pesticides Used in Delaware.

    Science.gov (United States)

    D'Souza, Malcolm J; Barile, Benjamin; Givens, Aaron F

    2015-05-01

    Synthetic pesticides are widely used in the modern world for human benefit. They are usually classified according to their intended pest target. In Delaware (DE), approximately 42 percent of the arable land is used for agriculture. In order to manage insectivorous and herbaceous pests (such as insects, weeds, nematodes, and rodents), pesticides are used profusely to biologically control the normal pest's life stage. In this undergraduate project, we first created a usable relational database containing 62 agricultural pesticides that are common in Delaware. Chemically pertinent quantitative and qualitative information was first stored in Bio-Rad's KnowItAll® Informatics System. Next, we extracted the data out of the KnowItAll® system and created additional sections on a Microsoft® Excel spreadsheet detailing pesticide use(s) and safety and handling information. Finally, in an effort to promote good agricultural practices, to increase efficiency in business decisions, and to make pesticide data globally accessible, we developed a mobile application for smartphones that displayed the pesticide database using Appery.io™; a cloud-based HyperText Markup Language (HTML5), jQuery Mobile and Hybrid Mobile app builder.

  15. Impact of Bio-Based Plastics on Current Recycling of Plastics

    Directory of Open Access Journals (Sweden)

    Luc Alaerts

    2018-05-01

    Full Text Available Bio-based plastics are increasingly appearing in a range of consumption products, and after use they often end up in technical recycling chains. Bio-based plastics are different from fossil-based ones and could disturb the current recycling of plastics and hence inhibit the closure of plastic cycles, which is undesirable given the current focus on a transition towards a circular economy. In this paper, this risk has been assessed via three elaborated case studies using data and information retrieved through an extended literature search. No overall risks were revealed for bio-based plastics as a group; rather, every bio-based plastic is to be considered as a potential separate source of contamination in current recycling practices. For PLA (polylactic acid, a severe incompatibility with PET (polyethylene terephthalate recycling is known; hence, future risks are assessed by measuring amounts of PLA ending up in PET waste streams. For PHA (polyhydroxy alkanoate there is no risk currently, but it will be crucial to monitor future application development. For PEF (polyethylene furanoate, a particular approach for contamination-related issues has been included in the upcoming market introduction. With respect to developing policy, it is important that any introduction of novel plastics is well guided from a system perspective and with a particular eye on incompatibilities with current and upcoming practices in the recycling of plastics.

  16. Application of 1D and 2D MFR reactor technology for the isolation of insecticidal and anti-microbial properties from pyrolysis bio-oils.

    Science.gov (United States)

    Hossain, Mohammad M; Scott, Ian M; Berruti, Franco; Briens, Cedric

    2016-12-01

    Valuable chemicals can be separated from agricultural residues by chemical or thermochemical processes. The application of pyrolysis has already been demonstrated as an efficient means to produce a liquid with a high concentration of desired product. The objective of this study was to apply an insect and microorganism bioassay-guided approach to separate and isolate pesticidal compounds from bio-oil produced through biomass pyrolysis. Tobacco leaf (Nicotianata bacum), tomato plant (Solanum lycopersicum), and spent coffee (Coffea arabica) grounds were pyrolyzed at 10°C/min from ambient to 565°C using the mechanically fluidized reactor (MFR). With one-dimensional (1D) MFR pyrolysis, the composition of the product vapors varied as the reactor temperature was raised allowing for the selection of the temperature range that corresponds to vapors with a high concentration of pesticidal properties. Further product separation was performed in a fractional condensation train, or 2D MFR pyrolysis, thus allowing for the separation of vapor components according to their condensation temperature. The 300-400°C tobacco and tomato bio-oil cuts from the 1D MFR showed the highest insecticidal and anti-microbial activity compared to the other bio-oil cuts. The 300-350 and 350-400°C bio-oil cuts produced by 2D MFR had the highest insecticidal activity when the bio-oil was collected from the 210°C condenser. The tobacco and tomato bio-oil had similar insecticidal activity (LC 50 of 2.1 and 2.2 mg/mL) when the bio-oil was collected in the 210°C condenser from the 300-350°C reactor temperature gases. The 2D MFR does concentrate the pesticidal products compared to the 1D MFR and thus can reduce the need for further separation steps such as solvent extraction.

  17. Education through music--the model of the Musikkindergarten Berlin.

    Science.gov (United States)

    Uibel, Stefanie

    2012-04-01

    In 2005, the pianist and conductor Daniel Barenboim initiated the Musikkindergarten Berlin as the first kindergarten in which music is not only used as an occasional add-on but as the central education medium for the child every day. The skills of specially trained kindergarten teachers combined with regular visits by professional musicians of the Staatskapelle Berlin (the Berlin State Opera orchestra) form the basis of a new educational concept, in which children experience music in all its different aspects and in its unique capability as a transfer medium into all the other educational areas. In this context, the method, the aim, and the experimental ground is not only education in or with music, but through music. This paper provides information and examples about first-hand experiences over the last six years. © 2012 New York Academy of Sciences.

  18. A Design of Portable Pesticide Residue Detection System Based on the Enzyme Electrode

    Directory of Open Access Journals (Sweden)

    Xia SUN

    2013-03-01

    Full Text Available In this paper, a portable detection system was designed based on amperometric acetylcholinesterase biosensor for rapidly detecting pesticide residues in fruits and vegetables. There were potentiostat, three electrode system, differential amplification circuit and double integral analog to digital (A/D circuit modules in this system. The measurement principle of this system was depended on the weak current from enzyme catalyzing substrate in acetylcholinesterase biosensor for detecting pesticide residues. The weak current generated by the enzyme biosensor was changed into 0-5 V standard voltage signal by this system as an output signal. The proposed system was investigated with eight kinds of standard pesticide of different concentrations, the results showed that the detection limits were all lower than 10 ng/kg. Thus, a new effective home-made system of detecting pesticide residues with portable, easy-to-use, fast response was developed. The pesticide residues rapid detection system can collect the weak current signal generated by electrochemical reaction and on-site detect the concentration of pesticide residues in real fruits and vegetables samples.

  19. Bio-based fillers for environmentally friendly composites

    CSIR Research Space (South Africa)

    Mokhothu, Thabang H

    2017-03-01

    Full Text Available The use of bio-based fillers as alternative replacement for synthetic fillers has been dictated by increasing ecological concerns as well as depleting petroleum resources. The other aspect is a growing need for eco-friendly, renewable...

  20. Influence of pesticide applications on degradation of the herbicide 14C - 2,4-D in different soils

    International Nuclear Information System (INIS)

    Marcondes, Marcilio Amaral

    2001-01-01

    Despite the importance of pesticide usage for the food production, its indiscriminate use may cause changes in the soil fertility, because pesticides influence soil microorganisms which are important for the biogeochemical cycles. The influence of applications of several pesticides, as recommended for cotton culture, was studied on the bioactivity of different soils (from Sao Paulo and Tatui, SP) by using radiometric techniques and a closed system for detection of bio mineralization of ''1 4 C-2,4-D ( 14 C-2,4-dichlorophenoxyacetic acid) and production of 14 C-volatile compounds. The 14 C-2,4-D dissipation under influence of other pesticide applications was also studied by determination of 14 C-extractable residues, 14 C-bound residues and qualitative and quantitative analysis of the 14 C-extractable residues by high pressure liquid chromatography (HPLC) and thin layer chromatography (TLC). 14 C-volatile compounds were never detected but increases and decreases of bio mineralization were detected in both soils after different treatments. The mixture of deltamethrin + methyl parathion increased significantly the bioactivity in both soils; nevertheless, monocrotophos did not have any influence. The applications of different pesticides have also influenced the 14 C-2,4-D dissipation, because the radiocarbon recovered as 14 C-extractable residues differed between the treated and untreated samples of both soils. On the other hand, the pesticide applications did not influence the production of 14 C-bound residues. This 14 C-residue was produced in larger amounts by the richest in organic matter soil (Sao Paulo). Although radiocarbon had been detected not only as 14 'C-2,4-D but also as a 14 C-metabolite, in both soils and treatments, results indicate that the ' 14 C-2,4-D dissipation varied in the two studied soils and was influenced by treatments with others pesticides. (author)

  1. Pesticides and children

    International Nuclear Information System (INIS)

    Garry, Vincent F.

    2004-01-01

    Prevention and control of damage to health, crops, and property by insects, fungi, and noxious weeds are the major goals of pesticide applications. As with use of any biologically active agent, pesticides have unwanted side-effects. In this review, we will examine the thesis that adverse pesticide effects are more likely to occur in children who are at special developmental and behavioral risk. Children's exposures to pesticides in the rural and urban settings and differences in their exposure patterns are discussed. The relative frequency of pesticide poisoning in children is examined. In this connection, most reported acute pesticide poisonings occur in children younger than age 5. The possible epidemiological relationships between parental pesticide use or exposure and the risk of adverse reproductive outcomes and childhood cancer are discussed. The level of consensus among these studies is examined. Current concerns regarding neurobehavioral toxicity and endocrine disruption in juxtaposition to the relative paucity of toxicant mechanism-based studies of children are explored

  2. Understanding intentions to purchase bio-based products

    NARCIS (Netherlands)

    Onwezen, Marleen C.; Reinders, Machiel J.; Sijtsema, Siet J.

    2017-01-01

    This article aims to explore whether subjective ambivalence increases the understanding of consumers' intentions to buy bio-based products. Subjective ambivalence is the aversive feeling that accompanies evaluations containing both negative and positive elements. Two studies (N = 1851) in six

  3. Preparation of the soil for the energy policy turnaround. With bio-energy for more climate protection and sustainability. Collection of essays with contributions from science, practice and policy; Den Boden bereiten fuer die Energiewende. Mit Bioenergie fuer mehr Klimaschutz und Nachhaltigkeit. Aufsatzsammlung mit Beitraegen aus Wissenschaft, Praxis und Politik

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-02-15

    In order to create acceptance by understanding and in order to support the energy policy turnaround, the Agency for Renewable Energies (Berlin, Federal Republic of Germany) supplies several contributions to the following topics: (1) Bio-energy and the energy policy turnaround; (2) Sustainability by means of bio-energy, but how?; (3) How can energy crops modify the region?; (4) Bio-Energy and the landscape of the future; (5) Isles with green energy: Bio-Energy for decentralized solutions; (6) Bio-energy and organic agriculture; (7) Forest and field in the climate protection.

  4. Projections for the Production of Bulk Volume Bio-Based Polymers in Europe and Environmental Implications

    NARCIS (Netherlands)

    Patel, M.K.; Crank, M.

    2007-01-01

    In this paper we provide an overview of the most important emerging groups of bio-based polymers for bulk volume applications and we discuss market projections for these types of bio-based polymers in the EU, thereby distinguishing between three scenarios. Bio-based polymers are projected to reach a

  5. Phytotoxicity of pesticides mancozeb and chlorpyrifos: correlation with the antioxidative defence system in Allium cepa.

    Science.gov (United States)

    Fatma, Firdos; Verma, Sonam; Kamal, Aisha; Srivastava, Alka

    2018-02-01

    Pesticides are a group of chemical substances which are widely used to improve agricultural production. However, these substances could be persistent in soil and water, accumulative in sediment or bio-accumulative in biota depending on their solubility, leading to different types of environmental pollution. The present study was done to assess the impact of pesticides-mancozeb and chlorpyrifos, via morphological and physiological parameters using Allium cepa test system. Phytotoxic effects of pesticides were examined via germination percentage, survival percentage, root and shoot length, root shoot length ratio, seedling vigor index, percentage of phytotoxicity and tolerance index. Oxidative stress on Allium seedlings caused by pesticides was also assessed by investigating the activity of antioxidative enzymes viz. catalase, peroxidase and superoxide dismutase. Correlation was worked out between morphological parameters and antioxidative enzymes to bring out the alliance between them. Mancozeb and chlorpyrifos concentrations were significantly and positively correlated with the activity of antioxidative enzymes and negatively correlated with morphological parameters. Significant positive correlation between various morphological parameters showed their interdependency. However, negative correlation was obtained between activity of antioxidative enzymes and morphological parameters. The enzymes however, showed positive correlation with each other. Based on our result we can conclude that all morphological parameters were adversely affected by the two pesticides as reflected by phytotoxicity in Allium . Their negative correlation with activity of antioxidative enzymes indicates that upregulation of antioxidative enzymes is not sufficient to overcome the toxic effect, thereby signifying the threat being caused by the regular use of these pesticides.

  6. Opportunities for using bio-based fibers for value-added composites

    Science.gov (United States)

    Zhiyong Cai; Jerrold E. Winandy

    2006-01-01

    Efficient and economical utilization of various bio-based materials is an effective way to improve forest management, promote long-term sustainability, and restore native ecosystems. However, the dilemma is how to deal with lesser used, undervalued or no-value bio-resources such as small diameter trees, agricultural residues (wheat straw, rice straw, and corn stalk),...

  7. The Berlin Wall: A Simulation for the Social Studies Classroom

    Science.gov (United States)

    Russell, William B., III

    2010-01-01

    November 9, 2009, marked the twentieth anniversary of the opening of the Berlin Wall. The Wall, a symbol of the Cold War, separated the German people for 28 years (1961-1989), keeping those on the East side isolated. Although the construction and dismantling of the Berlin Wall is a significant part of history, the topic is little covered in the…

  8. BIOS Security Analysis and a Kind of Trusted BIOS

    Science.gov (United States)

    Zhou, Zhenliu; Xu, Rongsheng

    The BIOS's security threats to computer system are analyzed and security requirements for firmware BIOS are summarized in this paper. Through discussion about TCG's trust transitivity, a new approach about CRTM implementation based on BIOS is developed. In this paper, we also put forward a new trusted BIOS architecture-UTBIOS which is built on Intel Framework for EFI/UEFI. The trustworthiness of UTBIOS is based on trusted hardware TPM. In UTBIOS, trust encapsulation and trust measurement are used to construct pre-OS trust chain. Performance of trust measurement is also analyzed in the end.

  9. “Modeling and Measuring Competencies” Conference, Berlin, 24-25 February 2011

    NARCIS (Netherlands)

    Gulikers, J.T.M.; Mulder, M.

    2013-01-01

    In February 2011, I visited Berlin in order to attend a special conference on “Modeling and Measuring Competencies in Higher Education”, organized by the Humboldt University of Berlin and the Johannes Gutenberg University of Mainz. It was a special conference as it addressed this topic only over a

  10. The Rebirth of Waste Cooking Oil to Novel Bio-based Surfactants

    Science.gov (United States)

    Zhang, Qi-Qi; Cai, Bang-Xin; Xu, Wen-Jie; Gang, Hong-Ze; Liu, Jin-Feng; Yang, Shi-Zhong; Mu, Bo-Zhong

    2015-05-01

    Waste cooking oil (WCO) is a kind of non-edible oil with enormous quantities and its unreasonable dispose may generate negative impact on human life and environment. However, WCO is certainly a renewable feedstock of bio-based materials. To get the rebirth of WCO, we have established a facile and high-yield method to convert WCO to bio-based zwitterionic surfactants with excellent surface and interfacial properties. The interfacial tension between crude oil and water could reach ultra-low value as 0.0016 mN m-1 at a low dosage as 0.100 g L-1 of this bio-based surfactant without the aid of extra alkali, which shows a strong interfacial activity and the great potential application in many industrial fields, in particular, the application in enhanced oil recovery in oilfields in place of petroleum-based surfactants.

  11. Rhythmanalysing Berlin Marathon

    DEFF Research Database (Denmark)

    Edensor, Tim; Larsen, Jonas

    2017-01-01

    This paper draws on Lefebvre’s rhythmanalysis to investigate the multiple rhythms of the Berlin Marathon, exemplifying and expanding understandings about the rhythms of places and mobilities. First, we discuss how isorhythmic order is imposed on the city and event by race organizers. Secondly, we...... show that a marathon depends upon the preparatory training or ‘dressage’ performed by the thousands who have made themselves ‘race-ready’. Thirdly, we explore the changing individual and collective rhythms that continuously emerge according to contingencies and stages of the race to compose...

  12. Viscous Flow Behaviour of Karanja Oil Based Bio-lubricant Base Oil.

    Science.gov (United States)

    Sharma, Umesh Chandra; Sachan, Sadhana; Trivedi, Rakesh Kumar

    2018-01-01

    Karanja oil (KO) is widely used for synthesis of bio-fuel karanja oil methyl ester (KOME) due to its competitive price, good energy values and environmentally friendly combustion properties. Bio-lubricant is another value added product that can be synthesized from KO via chemical modification. In this work karanja oil trimethylolpropane ester (KOTMPE) bio-lubricant was synthesized and evaluated for its viscous flow behaviour. A comparison of viscous flow behaviours of natural KO and synthesized bio-fuel KOME and bio-lubricant KOTMPE was also made. The aim of this comparison was to validate the superiority of KOTMPE bio-lubricant over its precursors KO and KOME in terms of stable viscous flow at high temperature and high shear rate conditions usually encountered in engine operations and industrial processes. The free fatty acid (FFA) content of KO was 5.76%. KOME was synthesized from KO in a two-step, acid catalyzed esterification followed by base catalyzed transesterification, process at 65°C for 5 hours with oil-methanol ratio 1:6, catalysts H 2 SO 4 and KOH (1 and 1.25% w/w KO, respectively). In the final step, KOTMPE was prepared from KOME via transesterification with trimethylolpropane (TMP) at 150°C for 3 hours with KOME-TMP ratio 4:1 and H 2 SO 4 (2% w/w KOME) as catalyst. The viscosity versus temperature studies were made at 0-80°C temperatures in shear rate ranges of 10-1000 s -1 using a Discovery Hybrid Rheometer, model HR-3 (TA instruments, USA). The study found that viscosities of all three samples decreased with increase in temperature, though KOTMPE was able to maintain a good enough viscosity at elevated temperatures due to chemical modifications in its molecular structure. The viscosity index (VI) value for KOTMPE was 206.72. The study confirmed that the synthesized bio-lubricant KOTMPE can be used at high temperatures as a good lubricant, though some additives may be required to improve properties other than viscosity.

  13. Bridge in Berlin Fragments of a journey between Necropolis and Elysium

    DEFF Research Database (Denmark)

    Pihl, Ole Verner

    ”Bridge in Berlin" af Ole Pihl Bogen ”Bridge in Berlin" er en ”Graphic Novel” og fænomenologisk poetisk rejse i tid og rum, der undersøger broens betydning i byen og i vores bevidsthed, eksemplificeret og fortalt fra en bestemt bro i Berlin, nemlig Friedrichsbrücke på Museums Insel. I fortællingen...... bliver broen fortolket på flere måder både som konkret forbindelse mellem to steder, to tilstande, arkitektur og kultur historie og som poetisk metafor for forandring og transformation. En af hovedpersonerne i bogen er den store tyske neoklassicistiske arkitekt Carl Friedrich Schinkel. Han fortæller...

  14. Climate to measure. Facility management for Universal Music at Berlin; Klima nach Mass. TGA-Planung fuer Universal Music in Berlin

    Energy Technology Data Exchange (ETDEWEB)

    McLead, E.A.

    2002-07-01

    Designing and constructing the technical facilities for a historical building like the 'Spreespeicher' in Berlin is a difficult but interesting task. The building is owned by Universal Music. Each department has its own office structure, and all offices and structures were integrated in a functional overall concept by the planners of Happold Ingenieure. [German] Klima, Lueftung und Elektroinstallation fuer ein historisches Gebaeude wie den Berliner Spreespeicher zu entwickeln, ist eine schwierige, aber reizvolle Aufgabe. Besonders, wenn der Nutzer Universal Music heisst: Jede Abteilung besitzt ihre eigene Buerostruktur, und alle mussten die TGA-Planer von Happold Ingenieure in ein funktionierendes Gesamtkonzept integrieren. (orig.)

  15. Bio methane in the cogeneration market and heating market. Status quo, potentials and recommendations for an accelerated market penetration; Biomethan im KWK- und Waermemarkt. Status Quo, Potenziale und Handlungsempfehlungen fuer eine beschleunigte Marktdurchdringung

    Energy Technology Data Exchange (ETDEWEB)

    Herr, Michael; Rostek, Sandra [comps.

    2010-07-15

    The current contribution of the German Energy Agency (Berlin, Federal Republic of Germany) reports on the present sale situation of bio methane on the coupled and uncoupled heating market. The contribution clarifies, why the existing support measures do not stimulate the demand for bio methane in the necessary order of magnitude. Without adjustment of the legal framework neither the considerable sales potentials can be established, nor the targets for the development of the biogas feeding can be achieved approximately. The low demand on bio methane led to a planning stop on the producer side. Direct need for action is required.

  16. Bio-based supply chains : risks and institutional arrangements

    NARCIS (Netherlands)

    Peerlings, J.H.M.; Ge, L.; Galen, van M.A.

    2012-01-01

    One of the challenges for the bio-based economy is to achieve production efficiency that can compete with fossil-based products. New scale-efficient product supply chains have to be created, or current supply chains have to be amended to incorporate the biomass supply chain. These new supply chains

  17. Pesticides: Benefaction or Pandora's Box? A synopsis of the environmental aspects of 243 pesticides

    NARCIS (Netherlands)

    Linders JBHJ; Jansma JW; Mensink BJWG; Otermann K; ACT

    1994-01-01

    The report provides an overview of physical, chemical and environmental data of 243 pesticides. The data mentioned are based on confidential information supplied by the manufacturers of the pesticides. For all pesticides mentioned a Final Environmental File, which is public, is derived. Tables with

  18. Bio-based products from solar energy and carbon dioxide.

    Science.gov (United States)

    Yu, Jian

    2014-01-01

    Producing bio-based products directly from CO₂ and solar energy is a desirable alternative to the conventional biorefining that relies on biomass feedstocks. The production paradigm is based on an artificial photosynthetic system that converts sunlight to electricity and H₂ via water electrolysis. An autotrophic H₂-oxidizing bacterium fixes CO₂ in dark conditions. The assimilated CO₂ is stored in bacterial cells as polyhydroxybutyrate (PHB), from which a range of products can be derived. Compared with natural photosynthesis of a fast-growing cyanobacterium, the artificial photosynthetic system has much higher energy efficiency and productivity of bio-based products. The new technology looks promising because of possible cost reduction in feedstock, equipment, and operation. Copyright © 2013 Elsevier Ltd. All rights reserved.

  19. Comparing life cycle energy and GHG emissions of bio-based PET, recycled PET, PLA and man-made cellulosics

    NARCIS (Netherlands)

    Shen, L.; Worrell, E.; Patel, M.K.

    2012-01-01

    The purpose of this paper is to review the environmental profiles of petrochemical PET, (partially) bio-based PET, recycled PET, and recycled (partially) bio-based PET, and compare them with other bio-based materials, namely PLA (polylactic acid, a bio-based polyester) and man-made cellulose

  20. Pesticide exposure and risk of Parkinson's disease: A family-based case-control study

    Directory of Open Access Journals (Sweden)

    Scott Burton L

    2008-03-01

    Full Text Available Abstract Background Pesticides and correlated lifestyle factors (e.g., exposure to well-water and farming are repeatedly reported risk factors for Parkinson's disease (PD, but few family-based studies have examined these relationships. Methods Using 319 cases and 296 relative and other controls, associations of direct pesticide application, well-water consumption, and farming residences/occupations with PD were examined using generalized estimating equations while controlling for age-at-examination, sex, cigarette smoking, and caffeine consumption. Results Overall, individuals with PD were significantly more likely to report direct pesticide application than their unaffected relatives (odds ratio = 1.61; 95% confidence interval, 1.13–2.29. Frequency, duration, and cumulative exposure were also significantly associated with PD in a dose-response pattern (p ≤ 0.013. Associations of direct pesticide application did not vary by sex but were modified by family history of PD, as significant associations were restricted to individuals with no family history. When classifying pesticides by functional type, both insecticides and herbicides were found to significantly increase risk of PD. Two specific insecticide classes, organochlorines and organophosphorus compounds, were significantly associated with PD. Consuming well-water and living/working on a farm were not associated with PD. Conclusion These data corroborate positive associations of broadly defined pesticide exposure with PD in families, particularly for sporadic PD. These data also implicate a few specific classes of pesticides in PD and thus emphasize the need to consider a more narrow definition of pesticides in future studies.

  1. Bazaar Pagodas – Transnational Religion, Postsocialist Marketplaces and Vietnamese Migrant Women in Berlin

    Directory of Open Access Journals (Sweden)

    Gertrud Huwelmeier

    2013-04-01

    Full Text Available After the fall of the Berlin Wall and the breakdown of the East German Socialistgovernment, thousands of former contract workers from Vietnam stayedin the then reunified Germany. Due to their resulting precarious economicsituation, a large number of these migrants became engaged in small businessand petty trade. Some of them, women in particular, have become successfulentrepreneurs and wholesalers in recently built bazaars in the eastern parts ofBerlin. Most interestingly, parts of these urban spaces, former industrial areason the periphery of Germany’s capital, have been transformed into religiousplaces. This article explores the formation of female Vietnamese Buddhistnetworks on the grounds of Asian wholesale markets. It argues that transnationalmobilities in a post-socialist setting encourage border-crossing religious activities,linking people and places to various former socialist countries as well as to theSocialist Republic of Vietnam. Further, by considering political tensions betweenVietnamese in the eastern and western part of Berlin, this contribution illustratesthe negotiation of political sensitivities among diasporic Vietnamese in reunitedGermany. Based on ethnographic fieldwork among female lay Buddhists, itfocuses on entrepreneurship and investigates the relationship between business,migration and religious practices.

  2. The acceleration of the masculine in early-twentieth-century Berlin.

    Science.gov (United States)

    Prickett, David James

    2012-01-01

    In early-twentieth-century Berlin, agents of speed and industrialisation, such as the railway, contributed to the seemingly unbridled velocity of urban life. Doctors and cultural critics took an ambivalent stance toward the impact of speed and technology on the human body. Critics argued that these factors, in conjunction with sexual excess and prostitution, accelerated the sexual maturation of young men, thereby endangering ‘healthy’ male sexuality. This comparison of Hans Ostwald's socio-literary study Dunkle Winkel in Berlin (1904) with Georg Buschan's sexual education primer Vom Jüngling zum Mann (1911) queries the extent to which speed shaped the understanding of ‘the masculine’ in pre-World-War-I Germany. The essay thus examines Ostwald's and Buschan's arguments and postulates that speed in the city (Berlin) can be seen as a feminised, sexualised force that determined sex in the city. According to this reading, the homosexual urban dandy resisted the accelerated modernist urban tempo, whereas the heterosexual man and hegemonic, heteronormative masculinity yielded to speed. ‘“Das Verhältnis”’ became a fleeting, momentary alternative to stable marital relationships, which in turn contributed to the general ‘crisis’ of – and in– masculinity in early-twentieth-century Berlin.

  3. Dietary intakes of pesticides based on community duplicate diet samples.

    Science.gov (United States)

    Melnyk, Lisa Jo; Xue, Jianping; Brown, G Gordon; McCombs, Michelle; Nishioka, Marcia; Michael, Larry C

    2014-01-15

    The calculation of dietary intake of selected pesticides was accomplished using food samples collected from individual representatives of a defined demographic community using a community duplicate diet approach. A community of nine participants was identified in Apopka, FL from which intake assessments of organophosphate (OP) and pyrethroid pesticides were made. From these nine participants, sixty-seven individual samples were collected and subsequently analyzed by gas chromatography/mass spectrometry. Measured concentrations were used to estimate dietary intakes for individuals and for the community. Individual intakes of total OP and pyrethroid pesticides ranged from 6.7 to 996 ng and 1.2 to 16,000 ng, respectively. The community intake was 256 ng for OPs and 3430 ng for pyrethroid pesticides. The most commonly detected pesticide was permethrin, but the highest overall intake was of bifenthrin followed by esfenvalerate. These data indicate that the community in Apopka, FL, as represented by the nine individuals, was potentially exposed to both OP and pyrethroid pesticides at levels consistent with a dietary model and other field studies in which standard duplicate diet samples were collected. Higher levels of pyrethroid pesticides were measured than OPs, which is consistent with decreased usage of OPs. The diversity of pyrethroid pesticides detected in food samples was greater than expected. Continually changing pesticide usage patterns need to be considered when determining analytes of interest for large scale epidemiology studies. The Community Duplicate Diet Methodology is a tool for researchers to meet emerging exposure measurement needs that will lead to more accurate assessments of intake which may enhance decisions for chemical regulation. Successfully determining the intake of pesticides through the dietary route will allow for accurate assessments of pesticide exposures to a community of individuals, thereby significantly enhancing the research benefit

  4. Principles of Developing Multi-Pesticide Methods Based on HPLC Determination

    Energy Technology Data Exchange (ETDEWEB)

    Dudar, E. [Plant Protection & Soil Conservation Service of Budapest, Budapest (Hungary)

    2009-07-15

    Principles for the development of multi-pesticide methods based on HPLC determination are outlined. Flow charts and block diagrams give guidance on how to proceed stepwise in the set-up of respective analytical methods. Detailed information is provided on what to take into consideration for setting up a pesticide formulation analysis method. HPLC variables like the types of column, solvents and their strength, pH value, eluent modifiers, column temperature, etc, and the influence on the separation and resolution of chromatographic peaks are discussed as well as the necessity and benefits of internal standardization. Examples of system suitability testing experiments are given for illustration. (author)

  5. Pesticide-contaminated feeds in integrated grass carp aquaculture: toxicology and bioaccumulation.

    Science.gov (United States)

    Pucher, J; Gut, T; Mayrhofer, R; El-Matbouli, M; Viet, P H; Ngoc, N T; Lamers, M; Streck, T; Focken, U

    2014-02-19

    Effects of dissolved pesticides on fish are widely described, but little is known about effects of pesticide-contaminated feeds taken up orally by fish. In integrated farms, pesticides used on crops may affect grass carp that feed on plants from these fields. In northern Vietnam, grass carp suffer seasonal mass mortalities which may be caused by pesticide-contaminated plants. To test effects of pesticide-contaminated feeds on health and bioaccumulation in grass carp, a net-cage trial was conducted with 5 differently contaminated grasses. Grass was spiked with 2 levels of trichlorfon/fenitrothion and fenobucarb. Unspiked grass was used as a control. Fish were fed at a daily rate of 20% of body mass for 10 d. The concentrations of fenitrothion and fenobucarb in pond water increased over time. Effects on fish mortality were not found. Fenobucarb in feed showed the strongest effects on fish by lowering feed uptake, deforming the liver, increasing blood glucose and reducing cholinesterase activity in blood serum, depending on feed uptake. Fenobucarb showed increased levels in flesh in all treatments, suggesting bio-concentration. Trichlorfon and fenitrothion did not significantly affect feed uptake but showed concentration-dependent reduction of cholinesterase activity and liver changes. Fenitrothion showed bioaccumulation in flesh which was dependant on feed uptake, whereas trichlorfon was only detected in very low concentrations in all treatments. Pesticide levels were all detected below the maximum residue levels in food. The pesticide-contaminated feeds tested did not cause mortality in grass carp but were associated with negative physiological responses and may increase susceptibility to diseases.

  6. Thermoset coatings from epoxidized sucrose soyate and blocked, bio-based dicarboxylic acids.

    Science.gov (United States)

    Kovash, Curtiss S; Pavlacky, Erin; Selvakumar, Sermadurai; Sibi, Mukund P; Webster, Dean C

    2014-08-01

    A new 100% bio-based thermosetting coating system was developed from epoxidized sucrose soyate crosslinked with blocked bio-based dicarboxylic acids. A solvent-free, green method was used to block the carboxylic acid groups and render the acids miscible with the epoxy resin. The thermal reversibility of this blocking allowed for the formulation of epoxy-acid thermoset coatings that are 100% bio-based. This was possible due to the volatility of the vinyl ethers under curing conditions. These systems have good adhesion to metal substrates and perform well under chemical and physical stress. Additionally, the hardness of the coating system is dependent on the chain length of the diacid used, making it tunable. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Pesticide Environmental Accounting: a method for assessing the external costs of individual pesticide applications.

    Science.gov (United States)

    Leach, A W; Mumford, J D

    2008-01-01

    The Pesticide Environmental Accounting (PEA) tool provides a monetary estimate of environmental and health impacts per hectare-application for any pesticide. The model combines the Environmental Impact Quotient method and a methodology for absolute estimates of external pesticide costs in UK, USA and Germany. For many countries resources are not available for intensive assessments of external pesticide costs. The model converts external costs of a pesticide in the UK, USA and Germany to Mediterranean countries. Economic and policy applications include estimating impacts of pesticide reduction policies or benefits from technologies replacing pesticides, such as sterile insect technique. The system integrates disparate data and approaches into a single logical method. The assumptions in the system provide transparency and consistency but at the cost of some specificity and precision, a reasonable trade-off for a method that provides both comparative estimates of pesticide impacts and area-based assessments of absolute impacts.

  8. BioPig: a Hadoop-based analytic toolkit for large-scale sequence data.

    Science.gov (United States)

    Nordberg, Henrik; Bhatia, Karan; Wang, Kai; Wang, Zhong

    2013-12-01

    The recent revolution in sequencing technologies has led to an exponential growth of sequence data. As a result, most of the current bioinformatics tools become obsolete as they fail to scale with data. To tackle this 'data deluge', here we introduce the BioPig sequence analysis toolkit as one of the solutions that scale to data and computation. We built BioPig on the Apache's Hadoop MapReduce system and the Pig data flow language. Compared with traditional serial and MPI-based algorithms, BioPig has three major advantages: first, BioPig's programmability greatly reduces development time for parallel bioinformatics applications; second, testing BioPig with up to 500 Gb sequences demonstrates that it scales automatically with size of data; and finally, BioPig can be ported without modification on many Hadoop infrastructures, as tested with Magellan system at National Energy Research Scientific Computing Center and the Amazon Elastic Compute Cloud. In summary, BioPig represents a novel program framework with the potential to greatly accelerate data-intensive bioinformatics analysis.

  9. The BioHub Knowledge Base: Ontology and Repository for Sustainable Biosourcing.

    Science.gov (United States)

    Read, Warren J; Demetriou, George; Nenadic, Goran; Ruddock, Noel; Stevens, Robert; Winter, Jerry

    2016-06-01

    The motivation for the BioHub project is to create an Integrated Knowledge Management System (IKMS) that will enable chemists to source ingredients from bio-renewables, rather than from non-sustainable sources such as fossil oil and its derivatives. The BioHubKB is the data repository of the IKMS; it employs Semantic Web technologies, especially OWL, to host data about chemical transformations, bio-renewable feedstocks, co-product streams and their chemical components. Access to this knowledge base is provided to other modules within the IKMS through a set of RESTful web services, driven by SPARQL queries to a Sesame back-end. The BioHubKB re-uses several bio-ontologies and bespoke extensions, primarily for chemical feedstocks and products, to form its knowledge organisation schema. Parts of plants form feedstocks, while various processes generate co-product streams that contain certain chemicals. Both chemicals and transformations are associated with certain qualities, which the BioHubKB also attempts to capture. Of immediate commercial and industrial importance is to estimate the cost of particular sets of chemical transformations (leading to candidate surfactants) performed in sequence, and these costs too are captured. Data are sourced from companies' internal knowledge and document stores, and from the publicly available literature. Both text analytics and manual curation play their part in populating the ontology. We describe the prototype IKMS, the BioHubKB and the services that it supports for the IKMS. The BioHubKB can be found via http://biohub.cs.manchester.ac.uk/ontology/biohub-kb.owl .

  10. Six recommendations for a bio-based economy in the Netherlands

    International Nuclear Information System (INIS)

    Van der Hoeven, D.

    2009-03-01

    The Bio-based Raw Materials Platform (PGG), part of the Energy Transition in The Netherlands, commissioned the Agricultural Economics Research Institute (LEI) and the Copernicus Institute of Utrecht University to conduct research on the macro-economic impact of large scale deployment of biomass for energy and materials in the Netherlands. Two model approaches were applied based on a consistent set of scenario assumptions: a bottom-up study including technoeconomic projections of fossil and bio-based conversion technologies and a topdown study including macro-economic modelling of (global) trade of biomass and fossil resources. The results of the top-down and bottom-up modelling work are reported separately. Based on the results of the studies the platform formulated six recommendations [nl

  11. From Berlin to Brussels

    OpenAIRE

    Chukwuma Charles Soludo

    2012-01-01

    The paper evaluates the economic partnership agreement (EPA) which the European Union is forging with African, Caribbean and Pacific (ACP) countries and concludes that it is a raw deal for these developing countries. Particularly for Africa, the author likens the EPA to the Berlin conference of 1884–1885 that divided Africa among the European powers. EPA as the second scramble for Africa would merely turn Africa into a dumping ground for European goods and severely undermine its nascent dev...

  12. Berlin: Sustainability and Tour Guides in a Partial Dark Tourism Destination

    Directory of Open Access Journals (Sweden)

    Asaf Leshem

    2013-10-01

    Full Text Available When guiding in Berlin about the Holocaust or about the Cold War, tour guides often hear the phrase: “I didn’t come here for that, but I want to see that as well...” Many of Berlin’s 10 Million visitors per year claim to have an attraction towards both the morbid and the lighter side of the city. Following from that popular sentiment it is argued that Berlin can be defined as a Partial Dark Tourism Destination. As such, it is further argued that Berlin is prone to an increase of socio-economic and socio-cultural negative impacts. The premise of the research is that Berlin’s tour guides function as a link between the residents of the city and the visitors. The thesis, then, is that tour guides play a role and can contribute to development of social, cultural and economic urban tourism sustainability. An analysis of tourism impacts and tourists-residents relations is presented, in which the tour guide plays a role in influencing the visitor’s behaviour. I conclude that tour guides have greater influence on social, cultural and economic behaviour of the tourist than previously considered, and therefore a potential to enhance sustainable tourism development in Berlin. The significance of this research is in the way it points out to the roles Berlin tour guides play in facilitation of sustainable tourism development in the city. Furthermore, the research shows the ways in which tour guides contribute to increasing responsible tourist behaviour.

  13. Summary of the BioLINK SIG 2013 meeting at ISMB/ECCB 2013.

    Science.gov (United States)

    Verspoor, Karin; Shatkay, Hagit; Hirschman, Lynette; Blaschke, Christian; Valencia, Alfonso

    2015-01-15

    The ISMB Special Interest Group on Linking Literature, Information and Knowledge for Biology (BioLINK) organized a one-day workshop at ISMB/ECCB 2013 in Berlin, Germany. The theme of the workshop was 'Roles for text mining in biomedical knowledge discovery and translational medicine'. This summary reviews the outcomes of the workshop. Meeting themes included concept annotation methods and applications, extraction of biological relationships and the use of text-mined data for biological data analysis. All articles are available at http://biolinksig.org/proceedings-online/. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

  14. Technological change of the energy innovation system: From oil-based to bio-based energy

    International Nuclear Information System (INIS)

    Wonglimpiyarat, Jarunee

    2010-01-01

    This paper concerns the structural developments and the direction of technological change of the energy innovation system, based on the studies of Kuhn's model of scientific change and Schumpeter's model of technological change. The paper uses the case study of Thai government agencies for understanding the way governments can facilitate technological innovation. The analyses are based on a pre-foresight exercise to examine the potential of the bio-based energy and investigate a set of development policies necessary for the direction of energy system development. The results have shown that bio-based energy is seen as the next new wave for future businesses and one of the solutions to the problem of high oil prices to improve the world's economic security and sustainable development. (author)

  15. Hydrotreatment of bio-oil over Ni-based catalyst.

    Science.gov (United States)

    Zhang, Xinghua; Wang, Tiejun; Ma, Longlong; Zhang, Qi; Jiang, Ting

    2013-01-01

    Inexpensive non-sulfided Ni-based catalysts were evaluated for hydrotreatments using phenol as model compound. HZSM-5, a zeolite with different ratio of Si/Al and γ-Al(2)O(3) were impregnated with Ni(NO(3))(2) · 6H(2)O and calcined at 450 °C. Conversion rates and product distribution for treatment of phenol at 160-240 °C in the presence of catalysts with nickel loads of 6, 10, 14 and 17 wt.% were determined. Phenol conversion was highest (91.8%) at 240 °C in the presence of HZSM-5(Si/Al = 38) loaded with 10% Ni. When hydrotreatment was carried out with bio-oil obtained from pyrolysis of pine sawdust under the optimal conditions determined for phenol, the pH of bio-oil increased from 2.27 to 4.07, and the hydrogen content increased from 6.28 to 7.01 wt.%. The decrease in acidity is desirable for the use of upgraded bio-oil. Copyright © 2012. Published by Elsevier Ltd.

  16. Was ist so Berlin? Eine kritische Rezension aktueller Linien und Fragestellungen der Stadtforschung in der deutschen Hauptstadt

    Directory of Open Access Journals (Sweden)

    Samuel Merrill

    2014-10-01

    Full Text Available Ende 2012 hat das Zitty Magazin des Tagesspiegels seine Werbekampagne „Das ist so Berlin“ gestartet. Seither sind kleine rot-weiße Aufkleber mit dieser Aussage überall in der Stadt aufgetaucht, auf Mülleimern, U-Bahn-Schildern und Bushaltestellen. Zum Teil als Reaktion auf diese Kampagne, fragt diese kritische, bilinguale Rezension Was ist so Berlin? um die aktuellen Linien und Fragestellungen der Stadtforschung in Berlin zu diskutieren. Dazu werden die Berlin-Sitzungen zweier internationaler Tagungen des Jahres 2013 rezensiert, die Sitzungen der Jahreskonferenz der Association of American Geographers (Los Angeles 9-13 April und es Jahrestreffen des Research Committee 21 (Berlin 29-31, sowie der Sammelband – The Berlin Reader: A Compendium on Urban Change and Activism (Transcript, 2013, herausgegeben von Matthias Bernt, Britta Grell und Andrej Holm. Im Anschluss betont die Rezension die Notwendigkeit die Vorstellungen zu Berlin und Berlins exceptionalism, die in der Stadtforschung entwickelt werden, fortlaufend so zu beleuchten, dass eine pluralistische Rhetorik, die Position und Verantwortung von Forscher_innen und wissenschaftliche Forschungslücken, berücksichtigt werden.

  17. 78 FR 41398 - City of Berlin, Berlin Water Works; Notice of Preliminary Permit Application Accepted for Filing...

    Science.gov (United States)

    2013-07-10

    ...) to be located on a water supply conduit at the City of Berlin's municipal water treatment plant (WTP... diameter cement-transite water main leading to the City's WTP; (2) piping, valves, control panels, and.... The WTP will use the power produced by the proposed project to run process equipment, lighting, and...

  18. The role of studies and analysis in the Berlin crisis

    International Nuclear Information System (INIS)

    Schake, K.

    1994-01-01

    The question posed for this conference was whether military exercises, studies and analysis have made an appreciable difference in the policies associated with tactical nuclear forces (TNF) in the North Atlantic Treaty Organization (NATO). Some of the papers leave the impression that studies, analysis and military exercises have very little impact on the strategy, policy decisions and force posture of NATO tactical nuclear forces. The studies and analyses undertaken during the 1961 Berlin crisis suggest a very different conclusion: that studies and analyses, when specific in scope and carrying some sense of immediacy, can be enormously influential. Whether one considers the changes to be positive or negative, the experience of the 1961 Berlin crisis suggests that studies and analyses had a tangible and direct impact both on contingency planning for the Berlin crisis specifically and on discussions of the role of tactical nuclear forces more broadly. The results of these studies and analyses are discussed

  19. A techno-economic evaluation of two non-edible vegetable oil based bio diesel in Pakistan

    International Nuclear Information System (INIS)

    Chakrabarti, M.H.; Ali, M.

    2010-01-01

    Technical evaluation of Bio diesel, produced from various non-edible oils, was carried out on the basis of emission profile, torque, engine brake power and exhaust temperatures at 10% blend ratio (by volume) with mineral diesel. The performance of engine parameters showed that the castor oil based bio diesel gave the best results. Economic feasibility for bio diesel production was carried out based on available data on cultivation of necessary plants on marginal lands. This economic analysis also included the value of by-products which would be available during the chemical process for the production of bio diesel. It was found that jatropha bio diesel could be produced at a comparable cost to mineral diesel, however, castor bio diesel required substantial subsidies or mass cultivation of plants on marginal lands to enable it to compete economically with mineral diesel. (author)

  20. An optical sensor for pesticide determination based on the autoindicating optical properties of peroxidase.

    Science.gov (United States)

    de Marcos, Susana; Callizo, Esther; Mateos, Elena; Galbán, Javier

    2014-05-01

    During the enzymatic reaction of the heme-protein Horseradish peroxidase (HRP) with hydrogen peroxide there are changes in the molecular absorption spectra of HRP and its different oxidation states which can be used for quantitative determination of the substrate. One of these intermediate oxidation states is the HRPII, with iron as an oxyferryl. This compound is assumed to be responsible for the organophosphate pesticide degradation in the Fenton reaction. In this work, the enzymatic HRP-H₂O₂ reaction has been studied, based on the effect of different pesticides on the mechanism reaction; these modifications have been used for the quantitative determination of pesticides. A mathematical model has been developed relating to the analytical signal with the pesticide concentration. Three organophosphate pesticides (diazinon, trichlorfon and tetrachlorvinphos) and one sulfamide (dichlofluanid) have been used to demonstrate the viability of the methodology and the accomplishment fulfillment of the model. Tetrachlorvinphos was chosen as the pesticide model to develop the optical sensor film for continuous pesticide determination, consisting of HRP immobilized in a polyacrylamide gel. The sensor can be used for at least 15 days and responds linearly to tetrachlorvinphos concentrations in the range from 4.0 × 10(-7) to 4.0 × 10(-6)mol L(-1). The main advantage of the methodology is its reversibility in contrast to the irreversible Fenton reaction. The HRP-H2O2 methodology has been used to measure the pesticides in a waste water sample spiked with tetrachlorvinphos. Copyright © 2014 Elsevier B.V. All rights reserved.

  1. A label-free silicon quantum dots-based photoluminescence sensor for ultrasensitive detection of pesticides.

    Science.gov (United States)

    Yi, Yinhui; Zhu, Gangbing; Liu, Chang; Huang, Yan; Zhang, Youyu; Li, Haitao; Zhao, Jiangna; Yao, Shouzhuo

    2013-12-03

    Sensitive, rapid, and simple detection methods for the screening of extensively used organophosphorus pesticides and highly toxic nerve agents are in urgent demand. A novel label-free silicon quantum dots (SiQDs)-based sensor was designed for ultrasensitive detection of pesticides. This sensing strategy involves the reaction of acetylcholine chloride (ACh) with acetylcholinesterase (AChE) to form choline that is in turn catalytically oxidized by choline oxidase (ChOx) to produce betaine and H2O2 which can quench the photoluminescence (PL) of SiQDs. Upon the addition of pesticides, the activity of AChE is inhibited, leading to the decrease of the generated H2O2, and hence the PL of SiQDs increases. By measuring the increase in SiQDs PL, the inhibition efficiency of pesticide to AChE activity was evaluated. It was found that the inhibition efficiency was linearly dependent on the logarithm of the pesticides concentration. Consequently, pesticides, such as carbaryl, parathion, diazinon, and phorate, were determined with the SiQDs PL sensing method. The lowest detectable concentrations for carbaryl, parathion, diazinon, and phorate reached 7.25 × 10(-9), 3.25 × 10(-8), 6.76 × 10(-8), and 1.9 × 10(-7) g/L, respectively, which were much lower than those previously reported. The detecting results of pesticide residues in food samples via this method agree well with those from high-performance liquid chromatography. The simple strategy reported here should be suitable for on-site pesticides detection, especially in combination with other portable platforms.

  2. Gasoline from biomass through refinery-friendly carbohydrate-based bio-oil produced by ketalization.

    Science.gov (United States)

    Batalha, Nuno; da Silva, Alessandra V; de Souza, Matheus O; da Costa, Bruna M C; Gomes, Elisa S; Silva, Thiago C; Barros, Thalita G; Gonçalves, Maria L A; Caramão, Elina B; dos Santos, Luciana R M; Almeida, Marlon B B; de Souza, Rodrigo O M A; Lam, Yiu L; Carvalho, Nakédia M F; Miranda, Leandro S M; Pereira, Marcelo M

    2014-06-01

    The introduction of biomass-derived compounds as an alternative feed into the refinery structure that already exists can potentially converge energy uses with ecological sustainability. Herein, we present an approach to produce a bio-oil based on carbohydrate-derived isopropylidene ketals obtained by reaction with acetone under acidic conditions directly from second-generation biomass. The obtained bio-oil showed a greater chemical inertness and miscibility with gasoil than typical bio-oil from fast pyrolysis. Catalytic upgrading of the bio-oil over zeolites (USY and Beta) yielded gasoline with a high octane number. Moreover, the co-processing of gasoil and bio-oil improved the gasoline yield and quality compared to pure gasoil and also reduced the amount of oxygenated compounds and coke compared with pure bio-oil, which demonstrates a synergistic effect. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. REACHing out to the bio-based economy : Perspectives and challenges of EU chemicals legislation

    NARCIS (Netherlands)

    Luit RJ; Waaijers-van der Loop SL; Heugens EHW; ICH; VSP

    2017-01-01

    The Dutch National Institute for Public Health and the Environment (hereafter: RIVM) recently investigated how the bio-based economy, more specifically the bio-based chemistry sector, relates to the EU REACH Regulation on chemicals. From this investigation, RIVM learnt that REACH may actually be an

  4. Microvalve-based bioprinting - process, bio-inks and applications.

    Science.gov (United States)

    Ng, Wei Long; Lee, Jia Min; Yeong, Wai Yee; Win Naing, May

    2017-03-28

    Bioprinting is an emerging research field that has attracted tremendous attention for various applications; it offers a highly automated, advanced manufacturing platform for the fabrication of complex bioengineered constructs. Different bio-inks comprising multiple types of printable biomaterials and cells are utilized during the bioprinting process to improve the homology to native tissues and/or organs in a highly reproducible manner. This paper, presenting a first-time comprehensive yet succinct review of microvalve-based bioprinting, provides an in-depth analysis and comparison of different drop-on-demand bioprinting systems and highlights the important considerations for microvalve-based bioprinting systems. This review paper reports a detailed analysis of its printing process, bio-ink properties and cellular components on the printing outcomes. Lastly, this review highlights the significance of drop-on-demand bioprinting for various applications such as high-throughput screening, fundamental cell biology research, in situ bioprinting and fabrication of in vitro tissue constructs and also presents future directions to transform the microvalve-based bioprinting technology into imperative tools for tissue engineering and regenerative medicine.

  5. The S-Bahn Challenge in Berlin

    NARCIS (Netherlands)

    Beckenbach, Isabel; Borndörfer, Ralf; Knoben, Loes; Kretz, David; Uetz, Marc Jochen

    Traveling an entire subway or S-Bahn network as fast as possible has become a kind of sport in many major cities, with increasing popularity. The Guinness Book of Records already has several entries in this category, all quite recent. Of course, the S-Bahn network of Berlin had been a blatant gap in

  6. Perspectives on Resource Recovery from Bio-Based Production Processes: From Concept to Implementation

    DEFF Research Database (Denmark)

    S.B.A. Udugama, Isuru; Mansouri, Seyed Soheil; Mitic, Aleksandar

    2017-01-01

    Recovering valuable compounds from waste streams of bio-based production processes is in line with the circular economy paradigm, and is achievable by implementing “simple-to-use” and well-established process separation technologies. Such solutions are acceptable from industrial, economic...... and environmental points of view, implying relatively easy future implementation on pilot- and full-scale levels in the bio-based industry. Reviewing such technologies is therefore the focus here. Considerations about technology readiness level (TRL) and Net Present Value (NPV) are included in the review, since TRL...... and NPV contribute significantly to the techno-economic evaluation of future and promising process solutions. Based on the present review, a qualitative guideline for resource recovery from bio-based production processes is proposed. Finally, future approaches and perspectives toward identification...

  7. A comparison of municipal solid waste management in Berlin and Singapore

    International Nuclear Information System (INIS)

    Zhang Dongqing; Keat, Tan Soon; Gersberg, Richard M.

    2010-01-01

    A comparative analysis of municipal solid waste management (MSWM) in Singapore and Berlin was carried out in order to identify its current status, and highlight the prevailing conditions of MSWM. An overview of the various aspects of MSWM in these two cities is provided, with emphasis on comparing the legal, technical, and managerial aspects of MSW. Collection systems and recycling practiced with respect to the involvement of the government and the private sector, are also presented. Over last two decades, the city of Berlin has made impressive progress with respect to its waste management. The amounts of waste have declined significantly, and at the same time the proportion that could be recovered and recycled has increased. In contrast, although Singapore's recycling rate has been increasing over the past few years, rapid economic and population growth as well as change in consumption patterns in this city-state has caused waste generation to continue to increase. Landfilling of MSW plays minor role in both cities, one due to geography (Singapore) and the other due to legislative prohibition (Berlin). Consequently, both in Singapore and Berlin, waste is increasingly being used as a valuable resource and great efforts have been made for the development of incineration technology and energy recovery, as well as climate protection.

  8. The Berlin tradition in Chicago: Franz Alexander and the Chicago Institute for Psychoanalysis.

    Science.gov (United States)

    Schmidt, Erika S

    2010-01-01

    Freud considered Franz Alexander, the first graduate of the Berlin Psychoanalytic Institute and an assistant in the Berlin Polyclinic, to be "one of our strongest hopes for the future." Alexander went on to become the first director of the Chicago Institute for Psychoanalysis in 1932 and modeled some of the Chicago Institute's mission on his Berlin experiences. He was also a researcher in psychosomatic medicine, a prolific writer about psychoanalysis and prominent in psychoanalytic organizations. As he proposed modifications in psychoanalytic technique, he became a controversial figure, especially in the elaboration of his ideas about brief therapy and the corrective emotional experience. This paper puts Alexander's achievements in historical context, draws connections between the Berlin and Chicago Institutes and suggests that, despite his quarrels with traditional psychoanalysis, Alexander's legacy may be in his attitude towards psychoanalysis, characterized by a commitment to scientific study, a willingness to experiment, and a conviction about the role of psychoanalysis within the larger culture.

  9. Bio-based renewable additives for anti-icing applications (phase one).

    Science.gov (United States)

    2016-09-04

    The performance and impacts of several bio-based anti-icers along with a traditional chloride-based anti-icer (salt brine) were evaluated. : A statistical design of experiments (uniform design) was employed for developing anti-icing liquids consistin...

  10. ITB Berlin: The world's leading tourism fair

    Directory of Open Access Journals (Sweden)

    Đeri Lukrecija

    2010-01-01

    Full Text Available MICE is a significant segment of tourism industry. It is of great interest for exhibitors and visitors, as well as for host cities and organizers. ITB Berlin represents the world's leading travel trade show. This paper analyses the key trends of this event in the last five year period (from 2004 until 2008. Analyzed data was annually gathered by Gelzus Messe-Marktforschung GmbH. This research focused on exhibitors', trade visitors and private visitors' origin, age distribution of private visitors, exhibiting companies, exhibiting branches, interest for travel according to type and overall impression and outlook that was gathered through surveys at ITB Berlin. Data was collected in the period 2004-2008 and placed together to make a five year overview. The goal is to present a development of above mentioned values and to discover potential patterns and predict future trends for this tourism fair. .

  11. Replacing fossil based plastic performance products by bio-based plastic products-Technical feasibility

    NARCIS (Netherlands)

    Oever, van den Martien; Molenveld, Karin

    2017-01-01

    Larger scale market introduction of new bio-based products requires a clear advantage regarding sustainability, as well as an adequate techno-economic positioning relative to fossil based products. In a previous paper [Broeren et al., 2016], LCA results per kg and per functionality equivalent of

  12. Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts

    Directory of Open Access Journals (Sweden)

    X. Q. Liu

    2012-04-01

    Full Text Available In this paper a bio-based epoxy with outstanding thermal and mechanical properties was synthesized using a rosin-based epoxy monomer and a rosin-based curing agent. The chemical structures of rosin based epoxy monomer and curing agent were confirmed by Nuclear Magnetic Resonance (NMR and Fourier Transform Infrared (FT-IR spectra. The flexural mechanical and dynamic mechanical properties as well as thermal stability of the cured epoxy were investigated. The results showed that the cured epoxy exhibited a glass transition temperature (Tg of 164°C and its flexural strength and modulus were as high as 70 and 2200 MPa, respectively. This indicated that a wholly bio-based epoxy resin possessing high performance was successfully obtained.

  13. [Some impressions of child and adolescent psychiatric management in Berlin after the fall of the wall].

    Science.gov (United States)

    Fegert, J M; Geiken, G; Lenz, K

    1992-12-01

    The fall of the Berlin wall caused a sudden increase in migration from East-Germany to West-Berlin. In our sample we compared 155 Berlin elementary school children to 17 children from East-Germany now living in Berlin and 25 immigrant children most oft them coming from Turkey and Poland. Although many authors expected short-term disorders of adaptation, we found a constancy of psychiatric diagnosis in the migration group. We noticed important differences particularly in the new psychosocial situation of the former East German mothers, with many single-mother-families, where the mothers now were often unemployed.

  14. Fast-Responding Bio-Based Shape Memory Thermoplastic Polyurethanes.

    Science.gov (United States)

    Petrović, Zoran S; Milić, Jelena; Zhang, Fan; Ilavsky, Jan

    2017-07-14

    Novel fast response shape-memory polyurethanes were prepared from bio-based polyols, diphenyl methane diisocyanate and butane diol for the first time. The bio-based polyester polyols were synthesized from 9-hydroxynonanoic acid, a product obtained by ozonolysis of fatty acids extracted from soy oil and castor oil. The morphology of polyurethanes was investigated by synchrotron ultra-small angle X-ray scattering, which revealed the inter-domain spacing between the hard and soft phases, the degree of phase separation, and the level of intermixing between the hard and soft phases. We also conducted thorough investigations of the thermal, mechanical, and dielectric properties of the polyurethanes, and found that high crystallization rate of the soft segment gives these polyurethanes unique properties suitable for shape-memory applications, such as adjustable transition temperatures, high degree of elastic elongations, and good mechanical strength. These materials are also potentially biodegradable and biocompatible, therefore suitable for biomedical and environmental applications.

  15. Dynamics of Sub-urbanisation - The Growing Periphery of the Metropolis. Berlin 1890 - 2000

    NARCIS (Netherlands)

    H. Reif (Heinz)

    2003-01-01

    textabstractWhat controls the secular process of sub-urbanisation of Berlin to garden and satellite cities and what were the effects? Through the massive retreat of its wealthy and academic bourgeoisie from the centre, Berlin became a bipolar city. On this side of the "railway ring", stood the

  16. Methodology for Designing and Developing a New Ultra-Wideband Antenna Based on Bio-Inspired Optimization Techniques

    Science.gov (United States)

    2017-11-01

    on Bio -Inspired Optimization Techniques by Canh Ly, Nghia Tran, and Ozlem Kilic Approved for public release; distribution is...Research Laboratory Methodology for Designing and Developing a New Ultra-Wideband Antenna Based on Bio -Inspired Optimization Techniques by...SUBTITLE Methodology for Designing and Developing a New Ultra-Wideband Antenna Based on Bio -Inspired Optimization Techniques 5a. CONTRACT NUMBER

  17. More chemistry between green and growth. The opportunities and dilemmas of a bio-based economy

    International Nuclear Information System (INIS)

    2010-12-01

    A bio-based economy is one in which enterprises manufacture non-food products from biomass. Such products include fuel for the transport industry, chemicals, materials, and energy. Biomass is the biological material of living or recently living organisms, either animal or vegetable. With technology becoming more sophisticated, it is growing easier to turn plants, trees, crops, and residual animal waste into biomass. Waste and waste streams are increasingly being used as input in production processes, thereby gaining an economic value of their own. They are giving rise to new, sustainable products with considerable added value that replace products based on non-renewable materials. New bio-based products may offer the Netherlands new economic opportunities. The Dutch can already boast a number of distinct advantages in that respect, thanks to the sophistication of their industrial sector, agro-industry, chemicals and energy industries, and transport and logistics sector - all key sectors in a bio-based economy. However, the growing world population and increasing level of prosperity worldwide, and the environmental and climate problems associated with such growth, are adding to the complexity of policy-making aimed at developing a bio-based economy. The shift from fossil-based to bio-based materials must be part of a comprehensive policy aimed at achieving a sustainable economy. [nl

  18. Bio-robots automatic navigation with graded electric reward stimulation based on Reinforcement Learning.

    Science.gov (United States)

    Zhang, Chen; Sun, Chao; Gao, Liqiang; Zheng, Nenggan; Chen, Weidong; Zheng, Xiaoxiang

    2013-01-01

    Bio-robots based on brain computer interface (BCI) suffer from the lack of considering the characteristic of the animals in navigation. This paper proposed a new method for bio-robots' automatic navigation combining the reward generating algorithm base on Reinforcement Learning (RL) with the learning intelligence of animals together. Given the graded electrical reward, the animal e.g. the rat, intends to seek the maximum reward while exploring an unknown environment. Since the rat has excellent spatial recognition, the rat-robot and the RL algorithm can convergent to an optimal route by co-learning. This work has significant inspiration for the practical development of bio-robots' navigation with hybrid intelligence.

  19. Computational Methods to Assess the Production Potential of Bio-Based Chemicals.

    Science.gov (United States)

    Campodonico, Miguel A; Sukumara, Sumesh; Feist, Adam M; Herrgård, Markus J

    2018-01-01

    Elevated costs and long implementation times of bio-based processes for producing chemicals represent a bottleneck for moving to a bio-based economy. A prospective analysis able to elucidate economically and technically feasible product targets at early research phases is mandatory. Computational tools can be implemented to explore the biological and technical spectrum of feasibility, while constraining the operational space for desired chemicals. In this chapter, two different computational tools for assessing potential for bio-based production of chemicals from different perspectives are described in detail. The first tool is GEM-Path: an algorithm to compute all structurally possible pathways from one target molecule to the host metabolome. The second tool is a framework for Modeling Sustainable Industrial Chemicals production (MuSIC), which integrates modeling approaches for cellular metabolism, bioreactor design, upstream/downstream processes, and economic impact assessment. Integrating GEM-Path and MuSIC will play a vital role in supporting early phases of research efforts and guide the policy makers with decisions, as we progress toward planning a sustainable chemical industry.

  20. Development of bio-hybrid material based on Salmonella ...

    African Journals Online (AJOL)

    Teodoro

    2016-07-13

    Jul 13, 2016 ... Full Length Research Paper. Development of bio-hybrid material based on. Salmonella Typhimurium and layered double hydroxides. Slah Hidouri .... the LDH with co-precipitation synthesis method was successfully done according the study given by Hidouri et al. (2011), Abdelkader et al. (2011), Hidouri et ...

  1. Trends in Flow-based Biosensing Systems for Pesticide Assessment

    Directory of Open Access Journals (Sweden)

    Jean-Louis Marty

    2006-10-01

    Full Text Available This review gives a survey on the state of the art of pesticide detection usingflow-based biosensing systems for sample screening. Although immunosensor systems havebeen proposed as powerful pesticide monitoring tools, this review is mainly focused onenzyme-based biosensors, as they are the most commonly employed when using a flowsystem. Among the different detection methods able to be integrated into flow-injectionanalysis (FIA systems, the electrochemical ones will be treated in more detail, due to theirhigh sensitivity, simple sample pretreatment, easy operational procedures and real-timedetection. During the last decade, new trends have been emerging in order to increase theenzyme stability, the sensitivity and selectivity of the measurements, and to lower thedetection limits. These approaches are based on (i the design of novel matrices for enzymeimmobilisation, (ii new manifold configurations of the FIA system, sometimes includingminiaturisation or lab-on-chip protocols thanks to micromachining technology, (iii the useof cholinesterase enzymes either from various commercial sources or genetically modifiedwith the aim of being more sensitive, (iv the incorporation of other highly specificenzymes, such as organophosphate hydrolase (OPH or parathion hydrolase (PH and (v thecombination of different electrochemical methods of detection. This article discusses thesenovel strategies and their advantages and limitations.

  2. Polymeric Nanoparticles as a Metolachlor Carrier: Water-Based Formulation for Hydrophobic Pesticides and Absorption by Plants.

    Science.gov (United States)

    Tong, Yujia; Wu, Yan; Zhao, Caiyan; Xu, Yong; Lu, Jianqing; Xiang, Sheng; Zong, Fulin; Wu, Xuemin

    2017-08-30

    Pesticide formulation is highly desirable for effective utilization of pesticide and environmental pollution reduction. Studies of pesticide delivery system such as microcapsules are developing prosperously. In this work, we chose polymeric nanoparticles as a pesticide delivery system and metolachlor was used as a hydrophobic pesticide model to study water-based mPEG-PLGA nanoparticle formulation. Preparation, characterization results showed that the resulting nanoparticles enhanced "water solubility" of hydrophobic metolachlor and contained no organic solvent or surfactant, which represent one of the most important sources of pesticide pollution. After the release study, absorption of Cy5-labeled nanoparticles into rice roots suggested a possible transmitting pathway of this metolachlor formulation and increased utilization of metolachlor. Furthermore, the bioassay test demonstrated that this nanoparticle showed higher effect than non-nano forms under relatively low concentrations on Oryza sativa, Digitaria sanguinalis. In addition, a simple cytotoxicity test involving metolachlor and metolachlor-loaded nanoparticles was performed, indicating toxicity reduction of the latter to the preosteoblast cell line. All of these results showed that those polymeric nanoparticles could serve as a pesticide carrier with lower environmental impact, comparable effect, and effective delivery.

  3. Evaluation of FOCUS surface water pesticide concentration predictions and risk assessment of field-measured pesticide mixtures-a crop-based approach under Mediterranean conditions.

    Science.gov (United States)

    Pereira, Ana Santos; Daam, Michiel A; Cerejeira, Maria José

    2017-07-01

    FOCUS models are used in the European regulatory risk assessment (RA) to predict individual pesticide concentrations in edge-of-field surface waters. The scenarios used in higher tier FOCUS simulations were mainly based on Central/North European, and work is needed to underpin the validity of simulated exposure profiles for Mediterranean agroecosystems. In addition, the RA of chemicals are traditionally evaluated on the basis of single substances although freshwater life is generally exposed to a multitude of pesticides. In the present study, we monitored 19 pesticides in surface waters of five locations in the Portuguese 'Lezíria do Tejo' agricultural area. FOCUS step 3 simulations were performed for the South European scenarios to estimate predicted environmental concentrations (PECs). We verified that 44% of the PECs underestimated the measured environmental concentrations (MEC) of the pesticides, showing a non-compliance with the field data. Risk was assessed by comparing the environmental quality standards (EQS) and regulatory acceptable concentrations with their respective MECs. Risk of mixtures was demonstrated in 100% of the samples with insecticides accounting for 60% of the total risk identified. The overall link between the RA and the actual situation in the field must be considerably strengthened, and field studies on pesticide exposure and effects should be carried out to assist the improvement of predictive approaches used for regulatory purposes.

  4. PESTICIDES: BENEFITS AND HAZARDS

    Directory of Open Access Journals (Sweden)

    Ivan Maksymiv

    2015-05-01

    Full Text Available Pesticides are an integral part of modern life used to prevent growth of unwanted living  organisms. Despite the fact that scientific statements coming from many toxicological works provide indication on the low risk of the pesticides and their residues, the community especially last years is deeply concerned about massive application of pesticides in diverse fields. Therefore evaluation of hazard risks particularly in long term perspective is very important. In the fact there are at least two clearly different approaches for evaluation of pesticide using: the first one is defined as an objective or probabilistic risk assessment, while the second one is the potential economic and agriculture benefits. Therefore, in this review the author has considered scientifically based assessment of positive and negative effects of pesticide application and discusses possible approaches to find balance between them.

  5. Nanomaterials in electrochemical biosensors for pesticide detection: advances and challenges in food analysis

    International Nuclear Information System (INIS)

    Arduini, Fabiana; Moscone, Danila; Cinti, Stefano; Scognamiglio, Viviana

    2016-01-01

    This overview (with 114 refs.) covers the progress made between 2010 and 2015 in the field of nanomaterial based electrochemical biosensors for pesticides in food. Its main focus is on strategies to analyze real samples. The review first gives a short introduction into the most often used bio recognition elements. These include (a) enzymes (resulting in inhibition-based and direct catalytic biosensors), (b) antibodies (resulting in immunosensors), and (c) aptamers (resulting in aptasensors). The next main section covers the various kinds of nanomaterials for use in biosensors and includes carbonaceous species (carbon nanotubes, graphene, carbon black and others), and non-carbonaceous species in the form of nanoparticles, rods, or porous materials. Aspects of sample treatment and real sample analysis are treated next before discussing vanguard technologies in tailor-made food analysis. (author)

  6. Ecological monitoring for Berlin and its back country

    International Nuclear Information System (INIS)

    Meyer, G.

    1992-01-01

    In 1991, the city of Berlin started the implementation of the 'monitoring program natural budget'. The aim of this program is the assessment of biological and ecological effects of atmospheric pollution as well as the analysis and evaluation of the functioning of the natural balance in pine forest ecosystems in the city area of Berlin and in the close vicinity. The investigations should make temporal and regional statements possible. Techniques of active and passive monitoring are applied (effect cadastre) as well as extensive investigations in long-term observation areas (at present pine forest systems). The ecosystem itself is in the foreground as a sensitive indicator for an existing atmospheric pollution load. The results should enable forecasts of the development of the related organisms and the ecosystems under the effect of anthropogenic load factors. (orig.) [de

  7. Wastewater-based epidemiology to assess pan-European pesticide exposure

    DEFF Research Database (Denmark)

    Rousis, Nikolaos I.; Gracia-Lor, Emma; Zuccato, Ettore

    2017-01-01

    human exposure to pesticides in eight cities across Europe. 24 h-composite wastewater samples were collected from the main wastewater treatment plants and analyzed for urinary metabolites of three classes of pesticides, namely triazines, organophosphates and pyrethroids, by liquid chromatography...

  8. Bio-based self-healing coatings based on thermo-reversible Diels-Alder reaction

    NARCIS (Netherlands)

    Turkenburg, D.H.; Durant, Y.; Fischer, H.R.

    2017-01-01

    Stimulated by the growing demand for greener and more sustainable polymer systems we have studied thermoreversible polymer networks composed largely (> 83% w/w) of diethylitaconate of bio-based origin. A series of coating materials has been synthesized consisting of linear chains of diethylitaconate

  9. Individuality and modernity in Berlin: self and society from Weimar to the Wall

    NARCIS (Netherlands)

    Föllmer, M.

    2013-01-01

    Moritz Föllmer traces the history of individuality in Berlin from the late 1920s to the construction of the Berlin Wall in August 1961. The demand to be recognised as an individual was central to metropolitan society, as were the spectres of risk, isolation and loss of agency. This was true under

  10. Multifamily determination of pesticide residues in soya-based nutraceutical products by GC/MS-MS.

    Science.gov (United States)

    Páleníková, Agneša; Martínez-Domínguez, Gerardo; Arrebola, Francisco Javier; Romero-González, Roberto; Hrouzková, Svetlana; Frenich, Antonia Garrido

    2015-04-15

    An analytical method based on a modified QuEChERS extraction coupled with gas chromatography-tandem mass spectrometry (GC-MS/MS) was evaluated for the determination of 177 pesticides in soya-based nutraceutical products. The QuEChERS method was optimised and different extraction solvents and clean-up approaches were tested, obtaining the most efficient conditions with a mixture of sorbents (PSA, C18, GBC and Zr-Sep(+)). Recoveries were evaluated at 10, 50 and 100 μg/kg and ranged between 70% and 120%. Precision was expressed as relative standard deviation (RSD), and it was evaluated for more than 160 pesticides as intra and inter-day precision, with values always below 20% and 25%, respectively. Limits of detection (LODs) ranged from 0.1 to 10 μg/kg, whereas limits of quantification (LOQs) from 0.5 to 20 μg/kg. The applicability of the method was proved by analysing soya-based nutraceuticals. Two pesticides were found in these samples, malathion and pyriproxyfen, at 11.1 and 1.5 μg/kg respectively. Copyright © 2014 Elsevier Ltd. All rights reserved.

  11. A comparison of municipal solid waste management in Berlin and Singapore.

    Science.gov (United States)

    Zhang, Dongqing; Keat, Tan Soon; Gersberg, Richard M

    2010-05-01

    A comparative analysis of municipal solid waste management (MSWM) in Singapore and Berlin was carried out in order to identify its current status, and highlight the prevailing conditions of MSWM. An overview of the various aspects of MSWM in these two cities is provided, with emphasis on comparing the legal, technical, and managerial aspects of MSW. Collection systems and recycling practiced with respect to the involvement of the government and the private sector, are also presented. Over last two decades, the city of Berlin has made impressive progress with respect to its waste management. The amounts of waste have declined significantly, and at the same time the proportion that could be recovered and recycled has increased. In contrast, although Singapore's recycling rate has been increasing over the past few years, rapid economic and population growth as well as change in consumption patterns in this city-state has caused waste generation to continue to increase. Landfilling of MSW plays minor role in both cities, one due to geography (Singapore) and the other due to legislative prohibition (Berlin). Consequently, both in Singapore and Berlin, waste is increasingly being used as a valuable resource and great efforts have been made for the development of incineration technology and energy recovery, as well as climate protection. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  12. Choosing organic pesticides over synthetic pesticides may not effectively mitigate environmental risk in soybeans.

    Directory of Open Access Journals (Sweden)

    Christine A Bahlai

    Full Text Available BACKGROUND: Selection of pesticides with small ecological footprints is a key factor in developing sustainable agricultural systems. Policy guiding the selection of pesticides often emphasizes natural products and organic-certified pesticides to increase sustainability, because of the prevailing public opinion that natural products are uniformly safer, and thus more environmentally friendly, than synthetic chemicals. METHODOLOGY/PRINCIPAL FINDINGS: We report the results of a study examining the environmental impact of several new synthetic and certified organic insecticides under consideration as reduced-risk insecticides for soybean aphid (Aphis glycines control, using established and novel methodologies to directly quantify pesticide impact in terms of biocontrol services. We found that in addition to reduced efficacy against aphids compared to novel synthetic insecticides, organic approved insecticides had a similar or even greater negative impact on several natural enemy species in lab studies, were more detrimental to biological control organisms in field experiments, and had higher Environmental Impact Quotients at field use rates. CONCLUSIONS/SIGNIFICANCE: These data bring into caution the widely held assumption that organic pesticides are more environmentally benign than synthetic ones. All pesticides must be evaluated using an empirically-based risk assessment, because generalizations based on chemical origin do not hold true in all cases.

  13. Recirculation: A New Concept to Drive Innovation in Sustainable Product Design for Bio-Based Products.

    Science.gov (United States)

    Sherwood, James; Clark, James H; Farmer, Thomas J; Herrero-Davila, Lorenzo; Moity, Laurianne

    2016-12-29

    Bio-based products are made from renewable materials, offering a promising basis for the production of sustainable chemicals, materials, and more complex articles. However, biomass is not a limitless resource or one without environmental and social impacts. Therefore, while it is important to use biomass and grow a bio-based economy, displacing the unsustainable petroleum basis of energy and chemical production, any resource must be used effectively to reduce waste. Standards have been developed to support the bio-based product market in order to achieve this aim. However, the design of bio-based products has not received the same level of attention. Reported here are the first steps towards the development of a framework of understanding which connects product design to resource efficiency. Research and development scientists and engineers are encouraged to think beyond simple functionality and associate value to the potential of materials in their primary use and beyond.

  14. The incidence of ARDS and associated mortality in severe TBI using the Berlin definition.

    Science.gov (United States)

    Aisiku, Imoigele P; Yamal, Jose-Miguel; Doshi, Pratik; Rubin, Maria Laura; Benoit, Julia S; Hannay, Julia; Tilley, Barbara C; Gopinath, Shankar; Robertson, Claudia S

    2016-02-01

    The incidence of adult respiratory distress syndrome (ARDS) in severe traumatic brain injury (TBI) is poorly reported. Recently, a new definition for ARDS was proposed, the Berlin definition. The percentage of patients represented by TBI in the Berlin criteria study is limited. This study describes the incidence and associated mortality of ARDS in TBI patients. The study was an analysis of the safety of erythropoietin administration and transfusion threshold on the incidence of ARDS in severe TBI patients. Three reviewers independently assessed all patients enrolled in the study for acute lung injury/ARDS using the Berlin and the American-European Consensus Conference (AECC) definitions. A Cox proportional hazards model was used to assess the relationship between ARDS and mortality and 6-month Glasgow Outcome Scale (GOS) score. Two hundred patients were enrolled in the study. Of the patients, 21% (41 of 200) and 26% (52 of 200) developed ARDS using the AECC and Berlin definitions, respectively, with a median time of 3 days (interquartile range, 3) after injury. ARDS by either definition was associated with increased mortality (p = 0.04) but not with differences in functional outcome as measured by the GOS score at 6 months. Adjusted analysis using the Berlin criteria showed an increased mortality associated with ADS (p = 0.01). Severe TBI is associated with an incidence of ARDS ranging from 20% to 25%. The incidence is comparable between the Berlin and AECC definitions. ARDS is associated with increased mortality in severe TBI patients, but further studies are needed to validate these findings. Epidemiologic study, level II.

  15. Understanding bio-economics

    NARCIS (Netherlands)

    Patel, M.K.|info:eu-repo/dai/nl/18988097X

    2008-01-01

    New plants for production of bio-based fuels, chemicals or plastics are being set up at an accelerating pace. However, this transition towards bio-based fuels, feedstocks and chemicals has not come without consequences. Increased demand has pushed up prices of key agricultural products such as maize

  16. Effects of Pesticides on the Growth and Reproduction of Earthworm: A Review

    International Nuclear Information System (INIS)

    Yasmin, S.; Doris D'Souza, D.

    2010-01-01

    Scientific literature addressing the influence of pesticides on the growth and reproduction of earthworm is reviewed. Earthworms are considered as important bio indicators of chemical toxicity in the soil ecosystem. Studies on this aspect are important because earthworms are the common prey of many terrestrial vertebrate species such as birds and small mammals, and thus they play a key role in the bio magnification process of several soil pollutants. Majority of the studies have used mortality as an endpoint rather than subtler endpoints such as reproductive output. It is now emphasized that, whereas higher concentrations of a pollutant can easily be assessed with the acute (mortality) test, contaminated soils with lower (sublethal) pollutant concentrations require more sensitive test methods such as reproduction test in their risk assessment.

  17. Techno-economic performance analysis of bio-oil based Fischer-Tropsch and CHP synthesis platform

    International Nuclear Information System (INIS)

    Ng, Kok Siew; Sadhukhan, Jhuma

    2011-01-01

    The techno-economic potential of the UK poplar wood and imported oil palm empty fruit bunch derived bio-oil integrated gasification and Fischer-Tropsch (BOIG-FT) systems for the generation of transportation fuels and combined heat and power (CHP) was investigated. The bio-oil was represented in terms of main chemical constituents, i.e. acetic acid, acetol and guaiacol. The compositional model of bio-oil was validated based on its performance through a gasification process. Given the availability of large scale gasification and FT technologies and logistic constraints in transporting biomass in large quantities, distributed bio-oil generations using biomass pyrolysis and centralised bio-oil processing in BOIG-FT system are technically more feasible. Heat integration heuristics and composite curve analysis were employed for once-through and full conversion configurations, and for a range of economies of scale, 1 MW, 675 MW and 1350 MW LHV of bio-oil. The economic competitiveness increases with increasing scale. A cost of production of FT liquids of 78.7 Euro/MWh was obtained based on 80.12 Euro/MWh of electricity, 75 Euro/t of bio-oil and 116.3 million Euro/y of annualised capital cost. -- Highlights: → Biomass to liquid process and gas to liquid process synthesis. → Biorefinery economic analysis. → Pyrolysis oil to biofuel. → Gasification and Fischer-Tropsch. → Process integration, pinch analysis and energy efficiency.

  18. Symbolic Uses of the Berlin Wall, 1961-1989.

    Science.gov (United States)

    Bruner, Michael S.

    1989-01-01

    Examines samples from public discourse during the period 1961-1989, which reveal several different symbolic uses of the Berlin Wall. Suggests these differences reflect the never-completed struggle between the United States and the Soviet Union. (KEH)

  19. Exposure to pesticide as a risk factor for depression: A population-based longitudinal study in Korea.

    Science.gov (United States)

    Koh, Sang-Baek; Kim, Tae Hui; Min, Seongho; Lee, Kyungsuk; Kang, Dae Ryong; Choi, Jung Ran

    2017-09-01

    Exposure to pesticides is associated with mental disorders, including depression, especially among occupationally exposed populations, such as farmers. The results of experimental studies ascribed the negative effects of pesticides on mental health to their neurotoxic and endocrine-disrupting activities. This study aimed to investigate the association between the risk of depression and high- or low-level exposure to pesticides in a rural population. This longitudinal study was performed in 2005-2008 (baseline) and 2008-2012 (follow-up) to evaluate the risk of depression among 2151 Korean adults. A standardized questionnaire was used to obtain information on depression upon self-reported exposure to pesticide based on the Center for Epidemiologic Studies Depression Scale. Logistic regression analysis was performed to evaluate the association between pesticide exposure and depression. We adjusted the data for age, cigarette smoking status, current alcohol use, monthly income, educational level, marriage status, and religion. Among the individuals who reported depression, the number of participants who used pesticides was significantly higher than that who did not (N=61 [7.2%] vs. N=54 [4.2%], P=0.003). A positive association was noted between >20-year period of pesticide use and depression (odds ratio [OR], 2.35; 95% confidence interval [CI], 1.41-3.88). Individuals who reported depression showed greater odds of being exposed to higher pesticide concentrations (OR, 2.33; 95% CI, 1.40-3.88) and experiencing pesticide poisoning (OR, 5.83; 95% CI, 1.80-18.86) than those who did not. Exposure to pesticides at a high concentration was found to be associated with depressive symptoms among Korean adults. Copyright © 2017 Elsevier B.V. All rights reserved.

  20. Wastewater engineering applications of BioIronTech process based on the biogeochemical cycle of iron bioreduction and (biooxidation

    Directory of Open Access Journals (Sweden)

    Volodymyr Ivanov

    2014-12-01

    Full Text Available Bioreduction of Fe(III and biooxidation of Fe(II can be used in wastewater engineering as an innovative biotechnology BioIronTech, which is protected for commercial applications by US patent 7393452 and Singapore patent 106658 “Compositions and methods for the treatment of wastewater and other waste”. The BioIronTech process comprises the following steps: 1 anoxic bacterial reduction of Fe(III, for example in iron ore powder; 2 surface renovation of iron ore particles due to the formation of dissolved Fe2+ ions; 3 precipitation of insoluble ferrous salts of inorganic anions (phosphate or organic anions (phenols and organic acids; 4 (biooxidation of ferrous compunds with the formation of negatively, positively, or neutrally charged ferric hydroxides, which are good adsorbents of many pollutants; 5 disposal or thermal regeration of ferric (hydroxide. Different organic substances can be used as electron donors in bioreduction of Fe(III. Ferrous ions and fresh ferrous or ferric hydroxides that are produced after iron bioreduction and (biooxidation adsorb and precipitate diferent negatively charged molecules, for example chlorinated compounds of sucralose production wastewater or other halogenated organics, as well as phenols, organic acids, phosphate, and sulphide. Reject water (return liquor from the stage of sewage sludge dewatering on municipal wastewater treatment plants represents from 10 to 50% of phosphorus load when being recycled to the aeration tank. BioIronTech process can remove/recover more than 90% of phosphorous from this reject water thus replacing the conventional process of phosphate precipitation by ferric/ferrous salts, which are 20–100 times more expensive than iron ore, which is used in BioIronTech process. BioIronTech process can remarkably improve the aerobic and anaerobic treatments of municipal and industrial wastewaters, especially anaerobic digestion of lipid- and sulphate-containing food-processing wastewater. It

  1. To be, or not to be biodegradable… that is the question for the bio-based plastics

    OpenAIRE

    Prieto, Auxiliadora

    2016-01-01

    Summary Global warming, market and production capacity are being the key drivers for selecting the main players for the next decades in the market of bio?based plastics. The drop?in bio?based polymers such as the bio?based polyethylene terephtalate (PET) or polyethylene (PE), chemically identical to their petrochemical counterparts but having a component of biological origin, are in the top of the list. They are followed by new polymers such as PHA and PLA with a significant market growth rat...

  2. Opportunities for Bio-Based Solvents Created as Petrochemical and Fuel Products Transition towards Renewable Resources.

    Science.gov (United States)

    Clark, James H; Farmer, Thomas J; Hunt, Andrew J; Sherwood, James

    2015-07-28

    The global bio-based chemical market is growing in size and importance. Bio-based solvents such as glycerol and 2-methyltetrahydrofuran are often discussed as important introductions to the conventional repertoire of solvents. However adoption of new innovations by industry is typically slow. Therefore it might be anticipated that neoteric solvent systems (e.g., ionic liquids) will remain niche, while renewable routes to historically established solvents will continue to grow in importance. This review discusses bio-based solvents from the perspective of their production, identifying suitable feedstocks, platform molecules, and relevant product streams for the sustainable manufacturing of conventional solvents.

  3. Opportunities for Bio-Based Solvents Created as Petrochemical and Fuel Products Transition towards Renewable Resources

    Science.gov (United States)

    Clark, James H.; Farmer, Thomas J.; Hunt, Andrew J.; Sherwood, James

    2015-01-01

    The global bio-based chemical market is growing in size and importance. Bio-based solvents such as glycerol and 2-methyltetrahydrofuran are often discussed as important introductions to the conventional repertoire of solvents. However adoption of new innovations by industry is typically slow. Therefore it might be anticipated that neoteric solvent systems (e.g., ionic liquids) will remain niche, while renewable routes to historically established solvents will continue to grow in importance. This review discusses bio-based solvents from the perspective of their production, identifying suitable feedstocks, platform molecules, and relevant product streams for the sustainable manufacturing of conventional solvents. PMID:26225963

  4. Development of Bio-Based Paint by using Methyl Esters from Palm Oil for Corrosion Inhibitor

    International Nuclear Information System (INIS)

    Mohibah Musa; Miradatul Najwa Muhd Rodhi; Najmiddin Yaakob; Ku Halim Ku Hamid; Juferi Idris

    2013-01-01

    Paint is used as a means of protection to prevent surfaces from being corroded over time. This research is focused on the development of a Bio-based paint made from palm oil methyl ester (POME) which originated from crude palm oil (CPO). New formulation paint has been developed to protect the pipeline from corrosion thus reducing the cost of the operation. Bio-based paint is made up of four components which are solvent, binder, additives, and pigment. The solvent in the bio-based paint is POME. The additives used are wetting and dispersing agent. The pigment used in the bio-based paint is TiO 2 . The formulation was developed by using a constant amount of additives and binder but varying the amount of POME at 10 ml, 15 ml, 20 ml, 25 ml and 30 ml with addition of water. The Standard Testing Methods for measuring the corrosion rate (ASTM G5-94(2011)) was carried out for each sample. In conclusion, it is proven that in the making of bio-based paint formulation for better corrosion inhibitor; the best amount of binder, additives and de-foam that should be used is 20 ml, 10 ml and 10 ml, respectively. (author)

  5. Gold nanoparticle-based fluorescent sensor for the analysis of dithiocarbamate pesticides in water

    DEFF Research Database (Denmark)

    Senkbeil, Silja; Lafleur, Josiane P.; Jensen, Thomas Glasdam

    2012-01-01

    Pesticides play a key role in the high yields achieved in modern agricultural food production. Besides their positive effect on increasing productivity they are intentionally toxic, often towards non-target organisms and contaminated food products can have a serious impact on human...... and environmental health. This paper demonstrates the potential of a gold nanoparticle-based microfluidic sensor for in field detection of dithiocarbamate pesticides at remote locations. Combining the attractive optical properties of gold nanoparticles with on chip mixing and detection, using a simple digital...

  6. [From traditional to modern hospital--from Paris to Berlin].

    Science.gov (United States)

    Murken, Axel Hinrich

    Discussions about the modernisation and reform of the Hôtel Dieu in Paris concerning the catastrophic fire of 1772 there were followed very closely in Prussia and other German countries, though for a long time this had only slight consequences for modernising developments in the hospitals of Berlin or other administrative capitals of Germany. In contrast to this, the Hôpital Lariboisière was praised as a model example in Germany soon after its completion in 1854 after the pre-revolutionary Parisian plans, was imitated in Berlin twenty years later. It must be added that in Prussia great importance was attached to stricter requirements for hygiene and ventilation than in Paris. This was clearly demonstrated barely in the construction of the pavilionhospital in Berlin-Friedrichshain (1868-1874) with an extremely decentralized layout. It was not until two generations later with the completion of the municipal hospital Westend in Charlottenburg (1904-1907), a suburb of Berlin, that a slightly modified "Lariboisière" in the Wilheminian brick Baroque style was built. Similarily the acceptance of high-rise construction was, compared with Paris, considerably delayed on the German hospital scene. Whereas in the USA and France plans had been made for high-rise hospitals from the 1920s on and realized by 1935, as with the Hôpital Beaujon in Paris (1932-1935), there were fundamental reservations about them in Germany. As a result, this conception of the structure, with an effective concentration of inpatient care in towers together with separate low-rise buildings for functions such as treatment and diagnosis, only gradually gained acceptance in Germany at the end of the 1960s. On the other hand, German architects such as Hermann Distel (1875-1946) or Ernst Kopp (1890-1962), had already, indeed before the Second World War, promoted the high-rise type for inpatient care on theoretical grounds. In addition, two hospitals providing medical care within in Berlin, Martin

  7. Work characteristics and pesticide exposures among migrant agricultural families: a community-based research approach.

    OpenAIRE

    McCauley, L A; Lasarev, M R; Higgins, G; Rothlein, J; Muniz, J; Ebbert, C; Phillips, J

    2001-01-01

    There are few data on pesticide exposures of migrant Latino farmworker children, and access to this vulnerable population is often difficult. In this paper we describe a community-based approach to implement culturally appropriate research methods with a migrant Latino farmworker community in Oregon. Assessments were conducted in 96 farmworker homes and 24 grower homes in two agricultural communities in Oregon. Measurements included surveys of pesticide use and work protection practices and a...

  8. Biotechnological Perspectives of Pyrolysis Oil for a Bio-Based Economy.

    Science.gov (United States)

    Arnold, Stefanie; Moss, Karin; Henkel, Marius; Hausmann, Rudolf

    2017-10-01

    Lignocellulosic biomass is an important feedstock for a potential future bio-based economy. Owing to its compact structure, suitable decomposition technologies will be necessary to make it accessible for biotechnological conversion. While chemical and enzymatic hydrolysis are currently established methods, a promising alternative is provided by fast pyrolysis. The main resulting product thereof, referred to as pyrolysis oil, is an energy-rich and easily transportable liquid. Many of the identified constituents of pyrolysis oil, however, have previously been reported to display adverse effects on microbial growth. In this Opinion we discuss relevant biological, biotechnological, and technological challenges that need to be addressed to establish pyrolysis oil as a reliable microbial feedstock for a bio-based economy of the future. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Isosorbide as the structural component of bio-based unsaturated polyesters for use as thermosetting resins.

    Science.gov (United States)

    Sadler, Joshua M; Toulan, Faye R; Nguyen, Anh-Phuong T; Kayea, Ronald V; Ziaee, Saeed; Palmese, Giuseppe R; La Scala, John J

    2014-01-16

    In recent years, the development of renewable bio-based resins has gained interest as potential replacements for petroleum based resins. Modified carbohydrate-based derivatives have favorable structural features such as fused bicyclic rings that offer promising candidates for the development of novel renewable polymers with improved thermomechanical properties when compared to early bio-based resins. Isosorbide is one such compound and has been utilized as the stiffness component for the synthesis of novel unsaturated polyesters (UPE) resins. Resin blends of BioUPE systems with styrene were shown to possess viscosities (120-2200 cP) amenable to a variety of liquid molding techniques, and after cure had Tgs (53-107 °C) and storage moduli (430-1650 MPa) that are in the desired range for composite materials. These investigations show that BioUPEs containing isosorbide can be tailored during synthesis of the prepolymer to meet the needs of different property profiles. Copyright © 2013 Elsevier Ltd. All rights reserved.

  10. Fabrication, modification and application of (BiO)_2CO_3-based photocatalysts: A review

    International Nuclear Information System (INIS)

    Ni, Zilin; Sun, Yanjuan; Zhang, Yuxin; Dong, Fan

    2016-01-01

    Graphical abstract: - Highlights: • The (BiO)_2CO_3 with Aurivillius structure y is an emergent material. • Synthesis of (BiO)_2CO_3 micro/nano structures was reviewed. • The mechanisms of (BiO)_2CO_3 based nanocomposites were discussed. • Doping (BiO)_2CO_3 with nonmetals for enhanced activity was highlighted. • Multi-functional applications of (BiO)_2CO_3 based derivatives was demonstrated. - Abstract: (BiO)_2CO_3 (BOC), a fascinating material, belongs to the Aurivillius-related oxide family with an intergrowth texture in which Bi_2O_2"2"+ layers and CO_3"2"− layers are orthogonal to each other. BOC is a suitable candidate for various fields, such as healthcare, photocatalysis, humidity sensor, nonlinear optical application and supercapacitors. Recently, the photocatalysis properties of (BiO)_2CO_3 have been gained increased attention. BOC has a wide band gap (3.1–3.5 eV), which constrains its visible light absorption and utilization. In order to enhance the visible light driven photocatalytic performance of BOC, many modification strategies have been developed. According to the discrepancies of different coupling mechanisms, six primary systems of BOC-based nanocomposites can be classified and summarized: namely, metal/BOC heterojunction, single metal oxides (metal sulfides)/BOC heterostructure, bismuth-based metallic acid salts (Bi_xMO_y)/BOC, bismuth oxyhalides (BiOX)/BOC, metal-free semiconductor/BOC and the BOC-based complex heterojunction. Doping BOC with nonmetals (C, N and oxygen vacancy) is unique strategy and warrants a separate categorization. In this review, we first give a detailed description of the strategies to fabricate various BOC micro/nano structures. Next, the mechanisms of photocatalytic activity enhancement are elaborated in three parts, including BOC-based nanocomposites, nonmetal doping and formation of oxygen vacancy. The enhanced photocatalytic activity of BOC-based systems can be attributed to the unique interaction of

  11. Identification and quantification of pesticide residues in water samples of Dhamrai Upazila, Bangladesh

    Science.gov (United States)

    Hasanuzzaman, M.; Rahman, M. A.; Salam, M. A.

    2017-10-01

    Being agricultural country, different types of pesticides are widely used in Bangladesh to prevent the crop losses due to pest attack which are ultimately drain to the water bodies. The present study was conducted to identify and quantify the organochlorine (DDT, DDE and DDD), organophosphorus (malathion, diazinon and chloropyrifos) and carbamate (carbaryl) residues in water samples of different sources from Dhamrai upazila of Bangladesh using high performance liquid chromatography (HPLC) equipped with ultra violate (UV) detector. Thirty water samples from fish pond, cultivated land and tube-well were collected in winter season to analyze the pesticide residues. Among the organophosphorus pesticides, malathion was present in seven water samples ranging from 42.58 to 922.8 μg/L, whereas diazinon was detected in water sample-8 (WS-8) and the concentration was 31.5 μg/L. None of the tested water samples was found to be contaminated with chlorpyrifos, carbaryl or DDT and its metabolites (DDE and DDD). Except for a tube-well water sample, concentrations of the detected residues are above the acceptable limit for human body as assigned by different organizations. To avoid the possible health hazards, the indiscriminate application of pesticides should be restricted and various substitute products like bio-pesticide should be introduced in a broad scale as soon as possible.

  12. Ultra-sensitive bio-sensor based on GMR in self-suspended-membrane-type germanium grating

    International Nuclear Information System (INIS)

    Ma, Jianyong; Zhang, Dawei

    2012-01-01

    In this paper, an ultra-sensitive bio-sensor based on the GMR effect in self-suspended-membrane-type gratings (SSGs) is proposed using multilayer plane waveguide theory. It is demonstrated from our calculations that the sensitivity of our bio-sensor is near the theoretical limit compared with a conventional GMR sensor. Based on the normalized eigenfunction of a single-layer homogeneous grating, the resonance curves with respect to different refractive indices of surrounding media are calculated, which confirm the estimated sensitivity. In addition, we design a highly sensitive bio-sensor in the near- and mid-IR wavelength region for liquid and gas detection respectively, the sensor can deliver a resolution over 1 × 10 −5 in the near-IR region in a large refractive index (1.3–1.7) range and provide better than 1 × 10 −6 in the mid-IR region, which is enough for various bio-material detections. Therefore, the bio-sensor we proposed is one or two orders more sensitive than conventional GMR sensors. (paper)

  13. WebBio, a web-based management and analysis system for patient data of biological products in hospital.

    Science.gov (United States)

    Lu, Ying-Hao; Kuo, Chen-Chun; Huang, Yaw-Bin

    2011-08-01

    We selected HTML, PHP and JavaScript as the programming languages to build "WebBio", a web-based system for patient data of biological products and used MySQL as database. WebBio is based on the PHP-MySQL suite and is run by Apache server on Linux machine. WebBio provides the functions of data management, searching function and data analysis for 20 kinds of biological products (plasma expanders, human immunoglobulin and hematological products). There are two particular features in WebBio: (1) pharmacists can rapidly find out whose patients used contaminated products for medication safety, and (2) the statistics charts for a specific product can be automatically generated to reduce pharmacist's work loading. WebBio has successfully turned traditional paper work into web-based data management.

  14. Work characteristics and pesticide exposures among migrant agricultural families: a community-based research approach.

    Science.gov (United States)

    McCauley, L A; Lasarev, M R; Higgins, G; Rothlein, J; Muniz, J; Ebbert, C; Phillips, J

    2001-05-01

    There are few data on pesticide exposures of migrant Latino farmworker children, and access to this vulnerable population is often difficult. In this paper we describe a community-based approach to implement culturally appropriate research methods with a migrant Latino farmworker community in Oregon. Assessments were conducted in 96 farmworker homes and 24 grower homes in two agricultural communities in Oregon. Measurements included surveys of pesticide use and work protection practices and analyses of home-dust samples for pesticide residues of major organophosphates used in area crops. Results indicate that migrant farmworker housing is diverse, and the amounts and types of pesticide residues found in homes differ. Azinphos-methyl (AZM) was the pesticide residue found most often in both farmworker and grower homes. The median level of AZM in farmworker homes was 1.45 ppm compared to 1.64 ppm in the entry area of grower homes. The median level of AZM in the play areas of grower homes was 0.71 ppm. The levels of AZM in migrant farmworker homes were most associated with the distance from fields and the number of agricultural workers in the home. Although the levels of AZM in growers and farmworker homes were comparable in certain areas, potential for disproportionate exposures occur in areas of the homes where children are most likely to play. The relationship between home resident density, levels of pesticide residues, and play behaviors of children merit further attention.

  15. Enhanced biodegradation of lindane using oil-in-water bio-microemulsion stabilized by biosurfactant produced by a new yeast strain, Pseudozyma VITJzN01.

    Science.gov (United States)

    Abdul Salam, Jaseetha; Das, Nilanjana

    2013-11-28

    Organochlorine pesticide residues continue to remain as a major environmental threat worldwide. Lindane is an organochlorine pesticide widely used as an acaricide in medicine and agriculture. In the present study, a new lindane-degrading yeast strain, Pseudozyma VITJzN01, was identified as a copious producer of glycolipid biosurfactant. The glycolipid structure and type were elucidated by FTIR, NMR spectroscopy, and GC-MS analysis. The surface activity and stability of the glycolipid was analyzed. The glycolipids, characterized as mannosylerythritol lipids (MELs), exhibited excellent surface active properties and the surface tension of water was reduced to 29 mN/m. The glycolipid was stable over a wide range of pH, temperature, and salinity, showing a very low CMC of 25 mg/l. Bio-microemulsion of olive oil-in-water (O/W) was prepared using the purified biosurfactant without addition of any synthetic cosurfactants, for lindane solubilization and enhanced degradation assay in liquid and soil slurry. The O/W bio-microemulsions enhanced the solubility of lindane up to 40-folds. Degradation of lindane (700 mg/l) by VITJzN01 in liquid medium amended with bio-microemulsions was found to be enhanced by 36% in 2 days, compared with degradation in 12 days in the absence of bio-microemulsions. Lindane-spiked soil slurry incubated with bio-microemulsions also showed 20-40% enhanced degradation compared with the treatment with glycolipids or yeast alone. This is the first report on lindane degradation by Pseudozyma sp., and application of bio-microemulsions for enhanced lindane degradation. MEL-stabilized bio-microemulsions can serve as a potential tool for enhanced remediation of diverse lindanecontaminated environments.

  16. The Berlin International Consensus Meeting on Concussion in Sport.

    Science.gov (United States)

    Davis, Gavin A; Ellenbogen, Richard G; Bailes, Julian; Cantu, Robert C; Johnston, Karen M; Manley, Geoffrey T; Nagahiro, Shinji; Sills, Allen; Tator, Charles H; McCrory, Paul

    2018-02-01

    The Fifth International Conference on Concussion in Sport was held in Berlin in October 2016. A series of 12 questions and subquestions was developed and the expert panel members were required to perform a systematic review to answer each question. Following presentation at the Berlin meeting of the systematic review, poster abstracts and audience discussion, the summary Consensus Statement was produced. Further, a series of tools for the management of sport-related concussion was developed, including the Sport Concussion Assessment Tool Fifth edition (SCAT5), the Child SCAT5, and the Concussion Recognition Tool Fifth edition. This paper elaborates on this process, the outcomes, and explores the implications for neurosurgeons in the management of sport-related concussion. Copyright © 2017 by the Congress of Neurological Surgeons.

  17. Opportunities for a Bio-based Economy in the Netherlands

    NARCIS (Netherlands)

    Sanders, J.P.M.; Hoeven, van der D.A.

    2008-01-01

    The shift to a bio-based economy for the Netherlands is not only required because of climate change, but also for industrial strategy reasons. Traditional strongholds of the Dutch economy like the Rotterdam harbour, the agricultural sector (including the greenhouse sector, and food and feed

  18. Polypyrrole Additional functions to bio-based façades

    NARCIS (Netherlands)

    Sailer, M.F. (Michael); Oostra, M.A.R. (Mieke); Eversdijk, J. (Jacco)

    2015-01-01

    AbstractDue to the crisis of 2008 the construction and real estate market became more demand-driven. Architects, builders and developers are looking for high-quality solutions for the realization of sustainable buildings. Supplying SMEs experience an increasing demand for bio-based materials with

  19. A bio-based fibre-reinforced plastic pedestrian bridge for Schiphol

    NARCIS (Netherlands)

    Smits, J.E.P.; Gkaidatzis, R.

    2015-01-01

    The present paper investigates Bio-based fibre-reinforced plastics, used as a load-bearing element of a bridge. We aim to increase the renewable content and decreasing the embodied energy of FRP. To achieve that, the consisting raw materials of these plastics which are based on non-renewable

  20. Software as a Service: Herausforderungen bei der Einführung des Bibliothekssystems Alma in der Freien Universität Berlin

    Directory of Open Access Journals (Sweden)

    Jiri Kende

    2015-12-01

    Full Text Available Moderne Bibliothekssysteme werden zunehmend als Software as a Service (SaaS angeboten. Die Berliner Bibliotheken der Freien Universität Berlin, der Humboldt Universität, der Technischen Universität und der Universität der Künste haben für 2016 gemeinsam den Umstieg auf das cloudbasierte Bibliothekssystem Alma beschlossen. Der Aufsatz berichtet über die Herausforderungen während der zweijährigen Vertragsverhandlungen mit besonderem Augenmerk auf den Datenschutz.  Modern library management systems are increasingly offered as Software as a Service (SaaS.The libraries of the Free University Berlin, the Humboldt university, the Technical university and the University of Arts decided concertedly to move in 2016 to the cloud based next generation library management system Alma. The article reviews the challenges during the contract negotiations with a special focus on data protection.

  1. Nannochloropsis algae pyrolysis with ceria-based catalysts for production of high-quality bio-oils.

    Science.gov (United States)

    Aysu, Tevfik; Sanna, Aimaro

    2015-10-01

    Pyrolysis of Nannochloropsis was carried out in a fixed-bed reactor with newly prepared ceria based catalysts. The effects of pyrolysis parameters such as temperature and catalysts on product yields were investigated. The amount of bio-char, bio-oil and gas products, as well as the compositions of the resulting bio-oils was determined. The results showed that both temperature and catalyst had significant effects on conversion of Nannochloropsis into solid, liquid and gas products. The highest bio-oil yield (23.28 wt%) and deoxygenation effect was obtained in the presence of Ni-Ce/Al2O3 as catalyst at 500°C. Ni-Ce/Al2O3 was able to retain 59% of the alga starting energy in the bio-oil, compared to only 41% in absence of catalyst. Lower content of acids and oxygen in the bio-oil, higher aliphatics (62%), combined with HHV show promise for production of high-quality bio-oil from Nannochloropsis via Ni-Ce/Al2O3 catalytic pyrolysis. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. Nature reserve Pfaueninsel in Berlin-Wannsee. V. The Lichen Flora

    Energy Technology Data Exchange (ETDEWEB)

    Grummann, V J; Poelt, J

    1972-01-01

    During the years 1965-1971 about 95 species of lichens were identified within the district of West Berlin. A few of them were growing on trees; corticolous foliaceous species are present in very reduced numbers, and the surviving individuals do not appear healthy. The majority of the species are found on walls and large rocks or on the ground in pine woods. Even these species are showing signs of diminution. Several species seem to have disappeared since the beginning of the observations. Air pollution is singled out as the cause of the decline of the lichens. Berlin today must be considered a lichen desert. 29 references, 2 figures.

  3. The Improvement of Screening the Significant Factors of Oil Blends as Bio lubricant Base Stock

    International Nuclear Information System (INIS)

    Noor Hajarul Ashikin Shamsuddin; Rozaini Abdullah; Zainab Hamzah; Siti Jamilah Hanim Mohd Yusof

    2015-01-01

    A new formulation bio lubricant base stock was developed by blending of waste cooking oil (WCO) with Jatropha curcas oil (JCO). The objective of this research is to evaluate significant factors contributing to the production of oil blends for bio lubricant application. The significant factors used in this study were oil ratio (WCO:JCO), agitation times (min) and agitation speed (rpm). The blended oil bio based lubricant was used to determine the saponification, acid, peroxide and iodine values. The experimental design used in this study was the 2 level-factorial design. In this experiment, it was found that the effect of oil ratio and interaction of oil ratio and agitation speed gave the most significant effect in oil blends as bio lubricant base stock. The highest ratio of oil blend 80 %:20 % WCO:JCO, with low agitation speed of 300 rpm and low agitation time of 30 minutes gave the optimum results. The acid, saponification, peroxide and iodine values obtained were 0.517±0.08 mg KOH/ g, 126.23±1.62 mg/ g, 7.5±2.0 m eq/ kg and 50.42±2.85 mg/ g respectively. A higher ratio of waste cooking oil blends was found to be favourable as bio lubricant base stock. (author)

  4. Bio-based C-3 Platform Chemical: Biotechnological Production and -Conversion of 3-Hydroxypropionaldehyde

    OpenAIRE

    Rezaei, Roya

    2013-01-01

    Demands for efficient, greener, economical and sustainable production of chemicals, materials and energy have led to development of industrial biotechnology as a key technology area to provide such products from bio-based raw materials from agricultural-, forestry- and related industrial residues and by-products. For the bio-based industry, it is essential to develop a number of building blocks or platform chemicals for C2-C6 chemicals and even aromatic chemicals. 3-hydroxypropionaldehyde (3H...

  5. Urban and rural mortality rates during heat waves in Berlin and Brandenburg, Germany

    International Nuclear Information System (INIS)

    Gabriel, Katharina M.A.; Endlicher, Wilfried R.

    2011-01-01

    In large cities such as Berlin, human mortality rates increase during intense heat waves. Analysis of relevant data from north-eastern Germany revealed that, during the heat waves that occurred between 1990 and 2006, health risks were higher for older people in both rural and urban areas, but that, during the two main heat waves within that 17-year period of time, the highest mortality rates were from the city of Berlin, and in particular from its most densely built-up districts. Adaptation measures will need to be developed, particularly within urban areas, in order to cope with the expected future intensification of heat waves due to global climate change. - Highlights: → Periods of heat stress enhance mortality rates in Berlin and Brandenburg. → Heat-related mortality is an urban as well as a rural problem. → During extreme events highest mortality rates can be found in the city centre. → Mortality rates correlate well with the distribution of sealed surfaces. → Health risks are higher for older than for younger people. - During periods of severe heat stress the pattern of mortality rates in Berlin and Brandenburg was found to correlate well with the distribution of sealed surfaces.

  6. 10. ročník „Berlin 10“ konference v Jihoafrické republice

    Czech Academy of Sciences Publication Activity Database

    Burešová, Iva

    -, č. 4 (2012) E-ISSN 1805-2800. [Berlin10. Stellenbosch, 06.11.2012-08.11.2012] Keywords : conferences * Berlin Open Access Conference * open access http://www.lib.cas.cz/casopis-informace/10-rocnik-%E2%80%9Eberlin-10-konference-v-jihoafricke-republice/

  7. Berlin, Maryland - How One Small City is Using Science to Change its World

    Science.gov (United States)

    Allen, L.; Silbergeld, E.

    2016-12-01

    Small cities are uniquely challenged to mitigate environmental issues in their communities because they usually lack the financial resources and technical expertise to address them. The Town of Berlin, population 4,500, recently purchased approximately 60 acres of private property located at 9943 Old Ocean City Boulevard. The property was previously owned by Tyson Chicken, Inc. and contains a chicken processing plant which has not been in use for over 10 years. Historically the plant emitted significant odors which limited the Town's ability to diversify its economic base. The plant closure provided an opportunity to convert the property to another use, but the downturn in the economy delayed that change. The Town intends to establish recreation oriented uses on the property with the following goals in mind: Create a common ground for the people of Berlin that will unite various neighborhoods. Create synergy between ecological sustainability and community resilience Upgrade the ponds on the property to make them the design focal point Through the Thriving Earth Exchange, the Town of Berlin connected with Dr. Ellen Silbergeld to resolve the question of how to remediate the ponds. Dr. Silbergeld is trained as an environmental engineer and public health researcher, with substantial experience in environmental issues in the poultry industry. This case study will show how one small city is working with a volunteer scientist to convert a blighted piece of property into a multi-use public space for the benefit of its residents and guests.

  8. Parenteral exposure to pesticides and occurence of congenital malformations: hospital-based case-control study.

    Science.gov (United States)

    Ueker, Marly Eliane; Silva, Vivianne Monteiro; Moi, Gisele Pedroso; Pignati, Wanderley Antonio; Mattos, Ines Echenique; Silva, Ageo Mário Cândido

    2016-08-12

    Most fetal defects are associated with genetic and environmental causes, among them, exposure of pregnant women to intensive pesticide use. Agribusiness is the economic basis of the state of Mato Grosso, the largest consumer of pesticides of all Brazilian states. The objective of this study was to investigate the association between past parental exposure to pesticides and the occurrence of congenital malformations in children in Mato Grosso, Brazil. This hospital-based case-control study was conducted in Cuiabá, the capital of Mato Grosso, from March to October 2011. Data was collected in all public, private, and health plan referral hospitals that provide care for pregnant women in the state of Mato Grosso and were situated in Cuiabá. Cases were children under 5 years of age with congenital malformations classified in Chapter XVIII of the International Classification of Diseases-10 and controls were children within the same age range, without congenital malformations, treated at the same hospitals. Malformation-related data was obtained from the patients' medical records. Socioeconomic data and information about parental exposure to pesticides were obtained in an interview with the mother using a standardized questionnaire. We conducted multivariate logistic regression to assess the relation between parent report of past pesticide use and congenital malformations. We also assessed effect modification to verify whether low maternal education level modified the association between exposure and our outcome. We observed positive effect modification of the association of paternal past exposure to pesticide and congenital malformation in the offspring by maternal education for mothers with low educational level (OR = 8.40, 95 % CI 2.17-32.52), father's work related to farming (OR = 4.65, 95 % CI 1.03-20.98) and paternal past exposure to pesticides (OR = 4.15, 95 % CI 1.24-13.66). These findings provide further evidence that paternal exposure to

  9. Bio-patch design and implementation based on a low-power system-on-chip and paper-based inkjet printing technology.

    Science.gov (United States)

    Yang, Geng; Xie, Li; Mantysalo, Matti; Chen, Jian; Tenhunen, Hannu; Zheng, L R

    2012-11-01

    This paper presents the prototype implementation of a Bio-Patch using fully integrated low-power System-on-Chip (SoC) sensor and paper-based inkjet printing technology. The SoC sensor is featured with programmable gain and bandwidth to accommodate a variety of bio-signals. It is fabricated in a 0.18-ìm standard CMOS technology, with a total power consumption of 20 ìW from a 1.2 V supply. Both the electrodes and interconnections are implemented by printing conductive nano-particle inks on a flexible photo paper substrate using inkjet printing technology. A Bio-Patch prototype is developed by integrating the SoC sensor, a soft battery, printed electrodes and interconnections on a photo paper substrate. The Bio-Patch can work alone or operate along with other patches to establish a wired network for synchronous multiple-channel bio-signals recording. The measurement results show that electrocardiogram and electromyogram are successfully measured in in-vivo tests using the implemented Bio-Patch prototype.

  10. An Overview of Pesticide Monitoring at Environmental Samples Using Carbon Nanotubes-Based Electrochemical Sensors

    Directory of Open Access Journals (Sweden)

    Ademar Wong

    2017-03-01

    Full Text Available Carbon nanotubes have received enormous attention in the development of electrochemical sensors by promoting electron transfer reactions, decreasing the work overpotential within great surface areas. The growing concerns about environmental health emphasized the necessity of continuous monitoring of pollutants. Pesticides have been successfully used to control agricultural and public health pests; however, intense use can cause a number of damages for biodiversity and human health. In this sense, carbon nanotubes-based electrochemical sensors have been proposed for pesticide monitoring combining different electrode modification strategies and electroanalytical techniques. In this paper, we provide a review of the recent advances in the use of carbon nanotubes for the construction of electrochemical sensors dedicated to the environmental monitoring of pesticides. Future directions, perspectives, and challenges are also commented.

  11. Collapsing (New Buildings: Town Planning, History and Music in Hubertus Siegert's Berlin Babylon (2001

    Directory of Open Access Journals (Sweden)

    Andrew Hurley

    2011-09-01

    Full Text Available Hubertus Siegert’s impressionistic documentary, Berlin Babylon, illuminates the demolition and urban renewal of Berlin during the mid-late 1990s. This was a critical phase in the city’s history, as it prepared, amidst a flurry of excitement and anticipation, to become the united Germany's seat of power. Siegert's film seeks to give pause for thought, but deliberately eschews a “voice of god” voiceover, opting instead for a poetic audiovisual montage. This includes shots of the cityscape (and its lacunae, archival footage documenting the wartime devastation and subsequent dynamiting of buildings, observational cinema of the city’s busy building sites, and of verbal snippets from various architects, developers and politicians––following the film title’s cue, the agents in a rerun of the construction of the Tower of Babel––as well as epigraphs from the Bible and Walter Benjamin, and a prominent soundscape and musical score. As this article will demonstrate, the film’s (mostly sombre soundtrack plays a critical role here, commenting on the footage, and beyond that on the whole project of the new ‘Berlin Republic’ and its attitude to architectural heritage and twentieth century history. Re-figuring the theme of this volume, Berlin Babylon’s music is a form of writing about (collapsing, old architecture and history. And yet, the soundtrack is not as unambiguous as a voiceover might have been, and thereby allows creative space for the audience’s interpretation, a matter that was very important to the film’s director. This article will focus, in particular, on three elements: the use (and treatment of historical recordings in the film; the use of silence; and finally the way in which tracks from the Berlin band Einstürzende Neubauten use music, noise and text to comment on the project of the new Berlin.

  12. Quality control of pesticide products

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-15

    In light of an established need for more efficient analytical procedures, this publication, which documents the findings of an IAEA coordinated research project (CRP) on “Quality Control of Pesticide Products”, simplifies the existing protocol for pesticide analysis while simultaneously upholding existing standards of quality. This publication includes both a report on the development work done in the CRP and a training manual for use by pesticide analysis laboratories. Based on peer reviewed and internationally recognized methods published by the Association of Analytical Communities (AOAC) and the Collaborative International Pesticides Analytical Council (CIPAC), this report provides laboratories with versatile tools to enhance the analysis of pesticide chemicals and to extend the scope of available analytical repertoires. Adoption of the proposed analytical methodologies promises to reduce laboratories’ use of solvents and the time spent on reconfiguration and set-up of analytical equipment.

  13. Quality control of pesticide products

    International Nuclear Information System (INIS)

    2009-07-01

    In light of an established need for more efficient analytical procedures, this publication, which documents the findings of an IAEA coordinated research project (CRP) on “Quality Control of Pesticide Products”, simplifies the existing protocol for pesticide analysis while simultaneously upholding existing standards of quality. This publication includes both a report on the development work done in the CRP and a training manual for use by pesticide analysis laboratories. Based on peer reviewed and internationally recognized methods published by the Association of Analytical Communities (AOAC) and the Collaborative International Pesticides Analytical Council (CIPAC), this report provides laboratories with versatile tools to enhance the analysis of pesticide chemicals and to extend the scope of available analytical repertoires. Adoption of the proposed analytical methodologies promises to reduce laboratories’ use of solvents and the time spent on reconfiguration and set-up of analytical equipment

  14. Predictive acute toxicity tests with pesticides.

    Science.gov (United States)

    Brown, V K

    1983-01-01

    By definition pesticides are biocidal products and this implies a probability that pesticides may be acutely toxic to species other than the designated target species. The ways in which pesticides are manufactured, formulated, packaged, distributed and used necessitates a potential for the exposure of non-target species although the technology exists to minimize adventitious exposure. The occurrence of deliberate exposure of non-target species due to the misuse of pesticides is known to happen. The array of predictive acute toxicity tests carried out on pesticides and involving the use of laboratory animals can be justified as providing data on which hazard assessment can be based. This paper addresses the justification and rationale of this statement.

  15. Community air monitoring for pesticides. Part 3: using health-based screening levels to evaluate results collected for a year.

    Science.gov (United States)

    Wofford, Pamela; Segawa, Randy; Schreider, Jay; Federighi, Veda; Neal, Rosemary; Brattesani, Madeline

    2014-03-01

    The CA Department of Pesticide Regulation (CDPR) and the CA Air Resources Board monitored 40 pesticides, including five degradation products, in Parlier, CA, to determine if its residents were exposed to any of these pesticides and, if so, in what amounts. They included 1,3-dichloropropene, acrolein, arsenic, azinphos-methyl, carbon disulfide, chlorpyrifos and its degradation product, chlorthalonil, copper, cypermethrin, diazinon and its degradation product, dichlorvos, dicofol, dimethoate and its degradation product, diuron, endosulfan and its degradation product, S-ethyl dipropylcarbamothioate (EPTC), formaldehyde, malathion and its degradation product, methyl isothiocyanate (MITC), methyl bromide, metolachlor, molinate, norflurazon, oryzalin, oxyfluorfen, permethrin, phosmet, propanil, propargite, simazine, SSS-tributylphosphorotrithioate, sulfur, thiobencarb, trifluralin, and xylene. Monitoring was conducted 3 days per week for a year. Twenty-three pesticides and degradation products were detected. Acrolein, arsenic, carbon disulfide, chlorpyrifos, copper, formaldehyde, methyl bromide, MITC, and sulfur were detected in more than half the samples. Since no regulatory ambient air standards exist for these pesticides, CDPR developed advisory, health-based non-cancer screening levels (SLs) to assess acute, subchronic, and chronic exposures. For carcinogenic pesticides, CDPR assessed risk using cancer potency values. Amongst non-carcinogenic agricultural use pesticides, only diazinon exceeded its SL. For carcinogens, 1,3-dichloropropene concentrations exceeded its cancer potency value. Based on these findings, CDPR has undertaken a more comprehensive evaluation of 1,3-dichloropropene, diazinon, and the closely related chlorpyrifos that was frequently detected. Four chemicals-acrolein, arsenic, carbon disulfide, and formaldehyde-sometimes used as pesticides were detected, although no pesticidal use was reported in the area during this study. Their presence was most

  16. Pesticide Use and Self-Reported Symptoms of Acute Pesticide Poisoning among Aquatic Farmers in Phnom Penh, Cambodia

    Directory of Open Access Journals (Sweden)

    Hanne Klith Jensen

    2011-01-01

    Full Text Available Organophosphates and carbamates (OPs/CMs are known for their acetylcholinesterase inhibiting character. A cross-sectional study of pesticide handling practices and self-perceived symptoms of acute pesticide poisoning was conducted using questionnaire-based interviews with 89 pesticide sprayers in Boeung Cheung Ek (BCE Lake, Phnom Penh, Cambodia. The study showed that 50% of the pesticides used belonged to WHO class I + II and personal protection among the farmers were inadequate. A majority of the farmers (88% had experienced symptoms of acute pesticide poisoning, and this was significantly associated with the number of hours spent spraying with OPs/CMs (OR = 1.14, CI 95%: 1.02–1.28. The higher educated farmers reduced their risk of poisoning by 55% for each extra personal protective measure they adapted (OR = 0.45, CI 95%: 0.22–0.91. These findings suggest that improving safe pesticide management practices among the farmers and enforcing the effective banning of the most toxic pesticides will considerably reduce the number of acute pesticide poisoning episodes.

  17. Risk factors associated with purchasing pesticide from shops for self-poisoning: a protocol for a population-based case-control study.

    Science.gov (United States)

    Weerasinghe, Manjula; Konradsen, Flemming; Eddleston, Michael; Pearson, Melissa; Gunnell, David; Hawton, Keith; Jayamanne, Shaluka; Pabasara, Chathurani; Jayathilaka, Tharidu; Dissanayaka, Kalpani; Rajapaksha, Sandamali; Thilakarathna, Prasanna; Agampodi, Suneth

    2015-05-20

    Pesticide self-poisoning is one of the most frequently used methods of suicide worldwide, killing over 300,000 people annually. Around 15-20% of pesticide self-poisonings occur soon after the person has bought the pesticide from a shop. We aim to determine the characteristics of individuals who purchase pesticides directly from shops and how they differ from individuals who access pesticides from other sources such as home, home garden or farmland. This information will help inform possible vendor/shop-based intervention strategies aimed at reducing access to pesticides used for self-harm. This study will investigate risk factors associated with purchasing pesticides for acts of self-poisoning from pesticide shops, including cases identified over a 9-month period using a population-based case-control group approach. Four interviewer-administered data collection tools will be used for this study: a semistructured questionnaire, Beck Suicidal Intent Scale (SIS), Clinical Interview Schedule-Sinhalese version (CIS-Sn) and Alcohol Use Disorders Identification Test (AUDIT). Each case (expected n=33) will be compared with two groups of individuals: (1) those who have self-poisoned using pesticides from the home, home garden or farmland and (2) those who bought pesticides from the same shops as the above cases, but not did not self-poison. Logistic regression models will be used to identify risk factors of purchasing pesticides for self-poisoning from shops. The study has received ethical approval from the Ethical Review Committee of the Faculty of Medicine and Allied Sciences, Rajarata University of Sri Lanka. A sensitive data collection technique will be used and ethical issues will be considered throughout the study. Results will be disseminated in scientific peer-reviewed articles. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

  18. Determination of pesticide residues in cereal grains

    International Nuclear Information System (INIS)

    Fuzesi, I.; Susan, M.

    2005-01-01

    The applicability of the TLC for determination of pesticide residues in cereal grains was studied using corn, rice and wheat as representative commodities and atrazine, captan, chlorpyrifos, chlortoluron, diazinon, diuron, fenitrothion, metoxuron, prochloraz, triforine as representative compounds. Following the extraction with ethyl acetate the efficiency of extraction was tested with Bio-Rad SX-3 gel, GPC, silica gel, florisil and RP-18 reverse phase silica cartridge. The GPC alone or in combination with silica or florisil cleanup were the most suitable for cleanup of the extracts. The TLC elution characteristics of 131 pesticide active ingredients were tested with eight elution systems. The detectability of the selected compounds was determined with six detection methods including two chemical and four bioassay procedures. In addition to the basic methods, the non-toxic Penicillium cyclopium fungi spore inhibition was introduced and it was found very sensitive for some fungicide compounds. The minimum detectable quantities of the tested compounds ranged from 1 ng to 100 ng. The average recoveries from rice and wheat ranged from 78% to 89%, and the limits of quantitation, LOQ, were between 0.01 and 0.2 mg/kg for the selected ten compounds. (author)

  19. Berlin Reflectance Spectral Library (BRSL)

    Science.gov (United States)

    Henckel, D.; Arnold, G.; Kappel, D.; Moroz, L. V.; Markus, K.

    2017-09-01

    The Berlin Reflectance Spectral Library (BRSL) provides a collection of reflectance spectra between 0.3 and 17 µm. It was originally dedicated to support space missions to small solar system bodies. Meanwhile the library includes selections of biconical reflectance spectra for spectral data analysis of other planetary bodies as well. The library provides reference spectra of well-characterized terrestrial analogue materials and meteorites for interpretation of remote sensing reflectance spectra of planetary surfaces. We introduce the BRSL, summarize the data available, and access to use them for further relevant applications.

  20. Microfilming of the Bach Manuscripts in the Staatsbibliothek Berlin.

    Science.gov (United States)

    Penzold, Leonhard

    1998-01-01

    Describes a microfilming project to preserve music manuscripts of Johann Sebastian Bach at the Staatsbibliothek Berlin (Germany), highlighting project goals, problems and peculiarities encountered filming the collection, color micrography, and black-and-white filming. (PEN)

  1. Controlled Pesticide Release from Porous Composite Hydrogels Based on Lignin and Polyacrylic Acid

    Directory of Open Access Journals (Sweden)

    Yajie Sun

    2016-01-01

    Full Text Available For the controlled release of pesticides, a novel composite porous hydrogel (LBPAA was prepared based on lignin and polyacrylic acid for use as the support frame of a pore structure for water delivery. The LBPAA was analyzed to determine its water-swelling and slow release properties. The controlled release properties of LBPAA were evaluated through experiments in relation to the cumulative release of pesticides, with particular emphasis on environmental effects and release models. The porous LBPAA hydrogel showed improved properties compared to polyacrylic acid, and could therefore be considered an efficient material for application in controlled release systems in agriculture.

  2. The research reactor BER II at the Helmholtz-Center Berlin

    Energy Technology Data Exchange (ETDEWEB)

    Krohn, Herbert [Helmholtz-Zentrum Berlin (HZB), Berlin (Germany)

    2012-10-15

    For basic and application-oriented research assignments the Helmholtz-Center Berlin (Helmholtz Zentrum Berlin - HZB) runs a research reactor that operates as a source of neutron beams for a wide range of scientific investigations. At the end of the 1980{sup th} the BER II was completed renewed and fitted with new experimental facilities. The BER II is a light water cooled and moderated swimming pool type reactor to be operated at 10 MW thermal power. Six neutron guides deliver cold neutrons from the cold moderator cell to a neutron guide hall adjacent to the experiment hall. With its 24 experimental stations, experimenters at HZB have practically all neutron scattering or neutron radiography techniques at their disposal. (orig.)

  3. Investigations on medical film processing in the city of Berlin

    International Nuclear Information System (INIS)

    Pape, U.

    1986-01-01

    An investigation on the methods of film processing in diagnostic radialogy departments can for instance be understood as a mere statistical representation of number and type of processing apparatus and film types, chemical methods and processing time, or it can be done as an attempt to objectively compare the film processing methods by means of a densitometric evaluation of equally exposed films of current usage within a given department. Such a comparative evaluation has been suggested by the diagnostics experts of the Berlin association of medical physicists, who presented their proposals within the course of project planning talks for a planned field test with a phantom for X-ray diagnostics, to be carried out in Berlin. (orig.) [de

  4. The research reactor BER II at the Helmholtz-Center Berlin

    International Nuclear Information System (INIS)

    Krohn, Herbert

    2012-01-01

    For basic and application-oriented research assignments the Helmholtz-Center Berlin (Helmholtz Zentrum Berlin - HZB) runs a research reactor that operates as a source of neutron beams for a wide range of scientific investigations. At the end of the 1980 th the BER II was completed renewed and fitted with new experimental facilities. The BER II is a light water cooled and moderated swimming pool type reactor to be operated at 10 MW thermal power. Six neutron guides deliver cold neutrons from the cold moderator cell to a neutron guide hall adjacent to the experiment hall. With its 24 experimental stations, experimenters at HZB have practically all neutron scattering or neutron radiography techniques at their disposal. (orig.)

  5. Diagnosing acute respiratory distress syndrome in resource limited settings: the Kigali modification of the Berlin definition.

    Science.gov (United States)

    Riviello, Elisabeth D; Buregeya, Egide; Twagirumugabe, Theogene

    2017-02-01

    The acute respiratory distress syndrome (ARDS) was re-defined by a panel of experts in Berlin in 2012. Although the Berlin criteria improved upon the validity and reliability of the definition, it did not make diagnosis of ARDS in resource limited settings possible. Mechanical ventilation, arterial blood gas measurements, and chest radiographs are not feasible in many regions of the world. In 2014, we proposed and applied the Kigali modification of the Berlin definition in a hospital in Rwanda. This review synthesizes literature from the last 18 months relevant to the Kigali modification. In the last 18 months, the need for a universally applicable ARDS definition was reinforced by advances in supportive care that can be implemented in resource poor settings. Research demonstrating the variable impact of positive end expiratory pressure on hypoxemia, the validity of using pulse oximetry rather than arterial blood gas to categorize hypoxemia, and the accuracy of lung ultrasound support the use of the Kigali modification of the Berlin definition. Studies directly comparing the Berlin definition to the Kigali modification are needed. Ongoing clinical research on ARDS needs to include low-income countries.

  6. Acute Respiratory Distress Syndrome in Burn Patients: A Comparison of the Berlin and American-European Definitions.

    Science.gov (United States)

    Sine, Christy R; Belenkiy, Slava M; Buel, Allison R; Waters, J Alan; Lundy, Jonathan B; Henderson, Jonathan L; Stewart, Ian J; Aden, James K; Liu, Nehemiah T; Batchinsky, Andriy; Cannon, Jeremy W; Cancio, Leopoldo C; Chung, Kevin K

    2016-01-01

    The purpose of this study was to compare the Berlin definition to the American-European Consensus Conference (AECC) definition in determining the prevalence of acute respiratory distress syndrome (ARDS) and associated mortality in the critically ill burn population. Consecutive patients admitted to our institution with burn injury that required mechanical ventilation for more than 24 hours were included for analysis. Included patients (N = 891) were classified by both definitions. The median age, % TBSA burn, and injury severity score (interquartile ranges) were 35 (24-51), 25 (11-45), and 18 (9-26), respectively. Inhalation injury was present in 35.5%. The prevalence of ARDS was 34% using the Berlin definition and 30.5% using the AECC definition (combined acute lung injury and ARDS), with associated mortality rates of 40.9 and 42.9%, respectively. Under the Berlin definition, mortality rose with increased ARDS severity (14.6% no ARDS; 16.7% mild; 44% moderate; and 59.7% severe, P Berlin definition was not different from patients without ARDS (P = .91). The Berlin definition better stratifies ARDS in terms of severity and correctly excludes those with minimal disease previously captured by the AECC.

  7. Pesticide use and self-reported symptoms of acute pesticide poisoning among aquatic farmers in Phnom Penh, Cambodia

    DEFF Research Database (Denmark)

    Jensen, Hanne Klith; Konradsen, Flemming; Jørs, Erik

    2011-01-01

    Organophosphates and carbamates (OPs/CMs) are known for their acetylcholinesterase inhibiting character. A cross-sectional study of pesticide handling practices and self-perceived symptoms of acute pesticide poisoning was conducted using questionnaire-based interviews with 89 pesticide sprayers...... in Boeung Cheung Ek (BCE) Lake, Phnom Penh, Cambodia. The study showed that 50% of the pesticides used belonged to WHO class I + II and personal protection among the farmers were inadequate. A majority of the farmers (88%) had experienced symptoms of acute pesticide poisoning, and this was significantly...... associated with the number of hours spent spraying with OPs/CMs (OR = 1.14, CI 95%: 1.02-1.28). The higher educated farmers reduced their risk of poisoning by 55% for each extra personal protective measure they adapted (OR = 0.45, CI 95%: 0.22-0.91). These findings suggest that improving safe pesticide...

  8. Evaluation of Traffic Accident Risk in In-City Bus Drivers: The Use of Berlin Questionnaire

    Science.gov (United States)

    Ekren, Pervin Korkmaz; Uysal, Funda Elmas; Başoğlu, Özen K.

    2018-01-01

    OBJECTIVES Traffic accidents associated with high mortality rate may produce serious problems especially in highways. Obstructive sleep apnea (OSA) has been associated with a high risk for traffic accidents due to excessive daytime sleepiness even in in-city drivers. In the present study, it was aimed to evaluate the rate of OSA symptoms and to identify risk factors associated with traffic accidents in in-city bus drivers. MATERIAL AND METHODS A self-administered questionnaire including demographic and anthropometric features, sleep and work schedules, Berlin questionnaire, Epworth sleepiness score (ESS), and history of traffic accidents was used. RESULTS The questionnaire was conducted for 1400 male bus drivers (mean age, 38.0±6.4 y, body mass index, 27.8±3.9 kg/m2). A total of 1058 (75.6%) drivers had one or more accidents while driving bus. According to the Berlin questionnaire, 176 (12.6%) drivers were found to have high OSA risk and the accident rate was 83.0% in high-risk group, whereas 74.5% of low-risk drivers had accidents (p=0.043). The drivers with a history of traffic accident were older (p=0.030), had higher ESS (p=0.019), and were more in the high-risk OSA group according to the Berlin questionnaire (p=0.015). In multivariate linear regression analysis, traffic accident was associated with only Berlin questionnaire (p=0.015). CONCLUSION The present results support that city bus drivers with high OSA risk according to Berlin questionnaire have increased accident rates. Therefore, we suggest using Berlin questionnaire for screening sleep apnea not only in highway drivers but also in in-city bus drivers. PMID:29755810

  9. The impact of public employment on private sector activity: Evidence from Berlin

    OpenAIRE

    Faggio, G.; Schluter, T.; vom Berge, P.

    2016-01-01

    We use the move of the seat of the German government from Bonn to Berlin in 1999 to test competing views about the impact of public employment on private sector activity in a local labor market. Using employment data from a 50% sample of establishments across 190 Berlin postcodes, we apply a treatment intensity approach which takes the possibility of spillovers into account. Results indicate that the arrival of 100 public sector jobs into an area generates 55 additional jobs in the private se...

  10. BioPortal: An Open-Source Community-Based Ontology Repository

    Science.gov (United States)

    Noy, N.; NCBO Team

    2011-12-01

    Advances in computing power and new computational techniques have changed the way researchers approach science. In many fields, one of the most fruitful approaches has been to use semantically aware software to break down the barriers among disparate domains, systems, data sources, and technologies. Such software facilitates data aggregation, improves search, and ultimately allows the detection of new associations that were previously not detectable. Achieving these analyses requires software systems that take advantage of the semantics and that can intelligently negotiate domains and knowledge sources, identifying commonality across systems that use different and conflicting vocabularies, while understanding apparent differences that may be concealed by the use of superficially similar terms. An ontology, a semantically rich vocabulary for a domain of interest, is the cornerstone of software for bridging systems, domains, and resources. However, as ontologies become the foundation of all semantic technologies in e-science, we must develop an infrastructure for sharing ontologies, finding and evaluating them, integrating and mapping among them, and using ontologies in applications that help scientists process their data. BioPortal [1] is an open-source on-line community-based ontology repository that has been used as a critical component of semantic infrastructure in several domains, including biomedicine and bio-geochemical data. BioPortal, uses the social approaches in the Web 2.0 style to bring structure and order to the collection of biomedical ontologies. It enables users to provide and discuss a wide array of knowledge components, from submitting the ontologies themselves, to commenting on and discussing classes in the ontologies, to reviewing ontologies in the context of their own ontology-based projects, to creating mappings between overlapping ontologies and discussing and critiquing the mappings. Critically, it provides web-service access to all its

  11. Battling Creaticide: An Interview with David C. Berliner

    Science.gov (United States)

    Ambrose, Don

    2012-01-01

    This article presents an interview with David C. Berliner, a Regents' Professor in the College of Education at Arizona State University. His books include "Educational Psychology," "The Manufactured Crisis," and "The Handbook of Educational Psychology." He has served as president of the American Educational Research Association and of the…

  12. From marine bio-corrosion to new bio-processes

    International Nuclear Information System (INIS)

    Bergel, A.; Dasilva, S.; Basseguy, R.; Feron, D.; Mollica, A.

    2004-01-01

    Full text of publication follows: From the middle of the last century it has been observed that the development of marine bio-films on the surface of stainless steels and different metallic materials induces the ennoblement of their free corrosion potential. A main step in deciphering the mechanisms of aerobic marine bio-corrosion has been achieved around 1976 with the demonstration that the potential ennoblement was due to the modification of the cathodic process. Since this date, the catalysis of oxygen reduction by marine bio-films has been the topic of numerous controversies, but it is now commonly agreed as a basic phenomena in aerobic corrosion. Several hypotheses have been proposed to explain the fine mechanisms of the bio-film-catalysed reduction of oxygen: intermediate formation of hydrogen peroxide, modification of the oxide layer on the stainless steel surface, involvement of manganese species and manganese oxidising bacteria, catalysis by proteins produced by the micro-organisms... Recent results may confirm the possible involvement of hemic enzymes or proteins. Whatever the mechanisms, very promising results have been obtained with the possible application of bio-film-catalysed oxygen reduction to conceive innovative biofuel cells with stainless steel electrodes. Actually, the catalysis of oxygen reduction is a key step that still drastically hinders the development of economically efficient hydrogen/oxygen fuel cells. The current technology requires high amounts of platinum or platinum-based materials to catalyze oxygen reduction on the cathode of these cells. The prohibitive cost of platinum is a main obstacle to the commercialization of low-cost fuel cells. Unpublished results recently showed that adapting the enzyme-catalysed reaction that was assumed for bio-corrosion on the cathode of hydrogen/oxygen fuel cells may lead to a significant decrease in the charge of platinum. Moreover, it was demonstrated on a laboratory-scale fuel cell pilot that

  13. Bazaar Pagodas – Transnational Religion, Postsocialist Marketplaces and Vietnamese Migrant Women in Berlin

    OpenAIRE

    Gertrud Huwelmeier

    2013-01-01

    After the fall of the Berlin Wall and the breakdown of the East German Socialistgovernment, thousands of former contract workers from Vietnam stayedin the then reunified Germany. Due to their resulting precarious economicsituation, a large number of these migrants became engaged in small businessand petty trade. Some of them, women in particular, have become successfulentrepreneurs and wholesalers in recently built bazaars in the eastern parts ofBerlin. Most interestingly, parts of these urba...

  14. Fate of para-toluenesulfonamide (p-TSA) in groundwater under anoxic conditions: modelling results from a field site in Berlin (Germany).

    Science.gov (United States)

    Meffe, Raffaella; Kohfahl, Claus; Hamann, Enrico; Greskowiak, Janek; Massmann, Gudrun; Dünnbier, Uwe; Pekdeger, Asaf

    2014-01-01

    This article reports on a field modelling study to investigate the processes controlling the plume evolution of para-toluenesulfonamide (p-TSA) in anoxic groundwater in Berlin, Germany. The organic contaminant p-TSA originates from the industrial production process of plasticisers, pesticides, antiseptics and drugs and is of general environmental concern for urban water management. Previous laboratory studies revealed that p-TSA is degradable under oxic conditions, whereas it appears to behave conservatively in the absence of oxygen (O2). p-TSA is ubiquitous in the aquatic environment of Berlin and present in high concentrations (up to 38 μg L(-1)) in an anoxic aquifer downgradient of a former sewage farm, where groundwater is partly used for drinking water production. To obtain refined knowledge of p-TSA transport and degradation in an aquifer at field scale, measurements of p-TSA were carried out at 11 locations (at different depths) between 2005 and 2010. Comparison of chloride (Cl(-)) and p-TSA field data showed that p-TSA has been retarded in the same manner as Cl(-). To verify the transport behaviour under field conditions, a two-dimensional transport model was setup, applying the dual-domain mass transfer approach in the model sector corresponding to an area of high aquifer heterogeneity. The distribution of Cl(-) and p-TSA concentrations from the site was reproduced well, confirming that both compounds behave conservatively and are subjected to retardation due to back diffusion from water stagnant zones. Predictive simulations showed that without any remediation measures, the groundwater quality near the drinking water well galleries will be affected by high p-TSA loads for about a hundred years.

  15. Transfer of tracers and pesticides in lab scale wetland systems: the role of vegetation

    Science.gov (United States)

    Durst, R.; Imfeld, G.; Lange, J.

    2012-04-01

    Surface wetlands can collect contaminated runoff from urban or agricultural catchments and have intrinsic physical, chemical and biological retention and removal processes useful for mitigating contaminants, including pesticides, and thus limiting the contamination of aquatic ecosystems. Yet little is known about the transfer of pesticides between wetlands collecting pesticides runoff and groundwater, and the subsequent threat of groundwater contamination. In particular, the influence of wetland vegetation and related processes during pesticide transfer is largely unknown. Here we evaluate the transfer of the widely used herbicide Isoproturon (IPU) and the fungicide Metalaxyl (MTX) with that of Uranine (UR) and Sulphorhodamine (SRB) in a vegetated and a non-vegetated lab-scale wetland. UR and SRB had successfully served as a reference for pesticides in surface wetlands. We filled two 65 cm long and 15 cm diameter borosilicate columns with sediment cores from a wetland, one without and one with vegetation (Phragmites australis, Cav.). When a constant flow-through rate of 0.33 ml min-1 was reached, tracers and pesticides were injected simultaneously and continuously. The hydrological mass balance and tracer concentrations were measured daily at the outlet of the lab-scale wetland. Samples for pesticides and hydrochemical analyses were collected biweekly. The lab-scale wetlands were covered to limit evaporation and light decay of injected compounds. The reactive transfer of compounds in the vegetated and non-vegetated lab-scale wetland was compared based on breakthrough curves (BTC's) and model parameters of the lumped parameter model CXTFIT. The hydrologic balance revealed that the intensity of transpiration and hence plant activity in the lab-scale wetlands progressively decreased and then apparently ceased after about eight days following continuous pesticide injection. In this first phase, no significant difference in the hydrologic balances could be observed

  16. To be, or not to be biodegradable… that is the question for the bio-based plastics.

    Science.gov (United States)

    Prieto, Auxiliadora

    2016-09-01

    Global warming, market and production capacity are being the key drivers for selecting the main players for the next decades in the market of bio-based plastics. The drop-in bio-based polymers such as the bio-based polyethylene terephtalate (PET) or polyethylene (PE), chemically identical to their petrochemical counterparts but having a component of biological origin, are in the top of the list. They are followed by new polymers such as PHA and PLA with a significant market growth rate since 2014 with projections to 2020. Research will provide improved strains designed through synthetic and systems biology approaches; furthermore, the use of low-cost substrates will contribute to the widespread application of these bio- based polymers. The durability of plastics is not considered anymore as a virtue, and interesting bioprospecting strategies to isolate microorganisms for assimilating the recalcitrant plastics will pave the way for in vivo strategies for plastic mineralization. In this context, waste management of bio-based plastic will be one of the most important issues in the near future in terms of the circular economy. There is a clear need for standardized labelling and sorting instructions, which should be regulated in a coordinated way by policymakers and material producers. © 2016 The Author. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

  17. Diffraction-based BioCD biosensor for point-of-care diagnostics

    Science.gov (United States)

    Choi, H.; Chang, C.; Savran, C.; Nolte, D.

    2018-02-01

    The BioCD platform technology uses spinning-disk interferometry to detect molecular binding to target molecular probes in biological samples. Interferometric configurations have included differential phase contrast and in-line quadrature detection. For the detection of extremely low analyte concentrations, nano- or microparticles can enhance the signal through background-free diffraction detection. Diffraction signal measurements on BioCD biosensors are achieved by forming gratings on a disc surface. The grating pattern was printed with biotinylated bovine serum albumin (BSA) and streptavidin coated beads were deployed. The diameter of the beads was 1 micron and strong protein bonding occurs between BSA and streptavidin-coated beads at the printed location. The wavelength for the protein binding detection was 635 nm. The periodic pattern on the disc amplified scattered light into the first-order diffraction position. The diffracted signal contains Mie scattering and a randomly-distributed-bead noise contributions. Variation of the grating pattern periodicity modulates the diffraction efficiency. To test multiple spatial frequencies within a single scan, we designed a fan-shaped grating to perform frequency filter multiplexing on a diffraction-based BioCD.

  18. Emil Fahrenkamp : Bauten und Projekte für Berlin

    NARCIS (Netherlands)

    Jacob, B.

    2006-01-01

    Thema der vorliegenden Arbeit ist die umfassende Aufarbeitung und Dokumentation der Bauten und Projekte Emil Fahrenkamps (*1885, 1966) in Berlin und Potsdam-Babelsberg sowie die kritische Einordnung seiner Arbeiten in den Kontext der Baugeschichte des 20. Jahrhunderts. Den zentralen

  19. Unexpected nitrile formation in bio-based mesoporous materials (Starbons®).

    Science.gov (United States)

    Attard, Jennifer; Milescu, Roxana; Budarin, Vitaliy; Matharu, Avtar S; Clark, James H

    2018-01-16

    The bio-based mesoporous materials made from polysaccharides, Starbons® can be modified by two different routes to give high levels of N-content, unexpectedly including significant quantities of nitrile groups which can improve the materials performance in applications including metal capture.

  20. Types of pesticides and determination of their residues

    International Nuclear Information System (INIS)

    Kassem, A.R.

    2010-01-01

    The pesticide is any material or component used to protect from pests. Its toxic effect is related to the chemical structure, which can be divided into 3 types : 1- Metal pesticides : Sulphur, cupper, zinc, mercury; 2- Vegetal pesticides : advanced and less toxic to the general health; 3- Synthetic organo pesticides : organo chlorine, organophosphorous, carbamate and pyrethroids. Pesticides in the soil undergo biological dissociation according to their concentration and chemical structure. High concentration of the pesticides in the soil may lead to fertility decrease due to destruction of micro-organisms by the pesticides. Many methods are used to analyze the residues of pesticides in plant or soil : 1- Chromatographic methods : Gas chromatography, gas liquid chromatography and high performance liquid chromatography; 2- Spectroscopy methods : spectrophotometer and mass spectrometer; 3- Isotopic methods : based on tracers technique which is the most sensitive and accurate method and can estimate minor amounts of the pesticides. (author)

  1. pH measurements of FET-based (bio)chemical sensors using portable measurement system.

    Science.gov (United States)

    Voitsekhivska, T; Zorgiebel, F; Suthau, E; Wolter, K-J; Bock, K; Cuniberti, G

    2015-01-01

    In this study we demonstrate the sensing capabilities of a portable multiplex measurement system for FET-based (bio)chemical sensors with an integrated microfluidic interface. We therefore conducted pH measurements with Silicon Nanoribbon FET-based Sensors using different measurement procedures that are suitable for various applications. We have shown multiplexed measurements in aqueous medium for three different modes that are mutually specialized in fast data acquisition (constant drain current), calibration-less sensing (constant gate voltage) and in providing full information content (sweeping mode). Our system therefore allows surface charge sensing for a wide range of applications and is easily adaptable for multiplexed sensing with novel FET-based (bio)chemical sensors.

  2. Ecology in a walled city: researching urban wildlife in post-war Berlin.

    Science.gov (United States)

    Lachmund, Jens

    2007-06-01

    The division of Berlin in the aftermath of World War II and the erection of the Wall in 1961 were not only of tremendous political, social and cultural significance, but also had implications for the way in which science was undertaken in this city. For ecologists living and working in the enclosed city part of West Berlin, the lack of accessible countryside motivated them to focus their fieldwork increasingly on urban sites and, thereby, to engage themselves in one of the most significant attempts to develop an ecology of the city.

  3. Intumescent formulations based on lignin and phosphinates for the bio-based textiles

    Science.gov (United States)

    Mandlekar, N.; Cayla, A.; Rault, F.; Giraud, S.; Salaün, F.; Malucelli, G.; Guan, J.

    2017-10-01

    This study investigates new intumescent formulations based on lignin and phosphinates to improve the flame retardant properties of Polyamide 11, while preserving the bio-based characteristics of this latter. Lignin has the advantage of being a bio-based compound and can be effectively used as carbon source for the design of intumescent systems in combination with other flame retardant additives. Metal phosphinates belong to a novel class of phosphorus flame retardants. Despite their increasing use, there is lack of scientific understanding as far as their fire retardancy mechanism is considered, especially in char forming polymeric materials. In this context, Polyamide 11 was melt blended with lignin and metal phosphinates. The possibility of melt spinning the prepared blends were assessed through melt flow index (MFI) tests; thermogravimetric (TG) analyses and cone calorimetry tests were exploited for investigating the thermal stability and the combustion behaviour of the obtained products, respectively. MFI results indicate that some formulations are suitable for melt spinning processes to generate flame retardant multifilament. Furthermore, the combination of lignin and phosphinates provides charring properties to polyamide 11. Finally, cone calorimetry data confirmed that the designed intumescent formulations could remarkably reduce PHRR through formation of protective char layer, hence slowing down the combustion process.

  4. Identification of Mycobacterium tuberculosis BioA inhibitors by using structure-based virtual screening

    Science.gov (United States)

    Singh, Swati; Khare, Garima; Bahal, Ritika Kar; Ghosh, Prahlad C; Tyagi, Anil K

    2018-01-01

    Background 7,8-Diaminopelargonic acid synthase (BioA), an enzyme of biotin biosynthesis pathway, is a well-known promising target for anti-tubercular drug development. Methods In this study, structure-based virtual screening was employed against the active site of BioA to identify new chemical entities for BioA inhibition and top ranking compounds were evaluated for their ability to inhibit BioA enzymatic activity. Results Seven compounds inhibited BioA enzymatic activity by greater than 60% at 100 μg/mL with most potent compounds being A36, A35 and A65, displaying IC50 values of 10.48 μg/mL (28.94 μM), 33.36 μg/mL (88.16 μM) and 39.17 μg/mL (114.42 μM), respectively. Compounds A65 and A35 inhibited Mycobacterium tuberculosis (M. tuberculosis) growth with MIC90 of 20 μg/mL and 80 μg/mL, respectively, whereas compound A36 exhibited relatively weak inhibition of M. tuberculosis growth (83% inhibition at 200 μg/mL). Compound A65 emerged as the most potent compound identified in our study that inhibited BioA enzymatic activity and growth of the pathogen and possessed drug-like properties. Conclusion Our study has identified a few hit molecules against M. tuberculosis BioA that can act as potential candidates for further development of potent anti-tubercular therapeutic agents. PMID:29750019

  5. Estimation of pyrethroid pesticide intake using regression modeling of food groups based on composite dietary samples

    Data.gov (United States)

    U.S. Environmental Protection Agency — Population-based estimates of pesticide intake are needed to characterize exposure for particular demographic groups based on their dietary behaviors. Regression...

  6. Antimicrobial Pesticides

    Science.gov (United States)

    EPA regulates pesticides under the statutory authority of the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA). The registration requirements for antimicrobial pesticides differ somewhat from those of other pesticides. Find out more.

  7. Bio-based materials with novel characteristics for tissue engineering applications - A review.

    Science.gov (United States)

    Bedian, Luis; Villalba-Rodríguez, Angel M; Hernández-Vargas, Gustavo; Parra-Saldivar, Roberto; Iqbal, Hafiz M N

    2017-05-01

    Recently, a wider spectrum of bio-based materials and materials-based novel constructs and systems has been engineered with high interests. The key objective is to help for an enhanced/better quality of life in a secure way by avoiding/limiting various adverse effects of some in practice traditional therapies. In this context, different methodological approaches including in vitro, in vivo, and ex vivo techniques have been exploited, so far. Among them, bio-based therapeutic constructs are of supreme interests for an enhanced and efficient delivery in the current biomedical sector of the modern world. The development of new types of novel, effective and highly reliable materials-based novel constructs for multipurpose applications is essential and a core demand to tackle many human health related diseases. Bio-based materials possess several complementary functionalities, e.g. unique chemical structure, bioactivity, non-toxicity, biocompatibility, biodegradability, recyclability, etc. that position them well in the modern world's materials sector. In this context, the utilization of biomaterials provides extensive opportunities for experimentation in the field of interdisciplinary and multidisciplinary scientific research. With an aim to address the global dependence on petroleum-based polymers, researchers have been redirecting their interests to the engineering of biological materials for targeted applications in different industries including cosmetics, pharmaceuticals, and other biotechnological or biomedical applications. Herein, we reviewed biotechnological advancements at large and tissue engineering from a biomaterials perspective in particular and envision directions of future developments. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Patterns of presence and concentration of pesticides in fish and waters of the Júcar River (Eastern Spain).

    Science.gov (United States)

    Belenguer, Vicent; Martinez-Capel, Francisco; Masiá, Ana; Picó, Yolanda

    2014-01-30

    The Júcar River, in a typical Mediterranean Basin, is expected to suffer a decline in water quality and quantity as a consequence of the climate change. This study is focused on the presence and distribution of pesticides in water and fish, using the first extensive optimization and application of the QuEChERS method to determine pesticides in freshwater fish. Majority pesticides in water - in terms of presence and concentration - were dichlofenthion, chlorfenvinphos, imazalil, pyriproxyfen and prochloraz (associated with a frequent use in farming activities), as well as buprofezin, chlorpyriphos and hexythiazox. In fish, the main compounds were azinphos-ethyl, chlorpyriphos, diazinon, dimethoate and ethion. The analysis of bio-concentration in fish indicated differences by species. The maximum average concentration was detected in European eel (a critically endangered fish species). The wide presence of pesticides in water and fish suggests potential severe effects on fish populations and other biota in future scenarios of climate change, in a river basin with several endemic and endangered fish species. The potential effects of pesticides in combination with multiple stressors require further research to prioritize the management of specific chemicals and suggest effective restoration actions at the basin scale. Copyright © 2013 Elsevier B.V. All rights reserved.

  9. Der Umlauf der spanischen Handschriften aus dem Antiquariat Leo Liepmannssohns in Paris und Berlin

    Directory of Open Access Journals (Sweden)

    Romero Naranjo, Francisco Javier

    2004-12-01

    Full Text Available One of the antique libraries most representative of the second half of the 19th century was that of Leo Liepmannssohn, with branches in Paris and Berlin. Its importance grew over time due to its auctions of many manuscripts by J. S. Bach, Handel, Mozart, Beethoven and other composers, a fact that explains how the author came across it during his investigation into the referred manuscripts. The object of this investigation is a collection of more than 300 folders that can be consulted in the Music Department in the Staatsbibliothek Preußischer Kulturbesitz in Berlin. The folders contain the annual catalogues from the antique library of Liepmannssohn (Berlin comprising the years 1866 to 1923. Each catalogue consists of a list of all the sales from the corresponding year in alphabetical order and contains, besides manuscripts, literature, musical treatises and the portraits of several composers. There are many Spanish manuscripts included in these catalogues whose distribution was so important that in 1900 Liepmannssohn published an exclusive catalogue for Spanish and Portuguese manuscripts, 291 of which the librarian had sold during that year. During the celebration of those auctions many documents, musical treatises and manuscripts, both known and unknown, were brought to light. The investigation earned out contributes to our knowledge about the works of different Spanish composers from the 16th to the 19th centuries and their distribution abroad, especially in Berlin.

    [de] Eines der repräsentativsten Antiquariate der zweiten Hälfte des XIX Jh. und des Anfangs des XX Jh. wurde von Leo Liepmannssohn in den Städten Paris und Berlin verwaltet. Durch die Versteigerung vieler Handschriften von J.S. Bach, Händel, Mozart, Beethoven und anderer Komponisten gewann das Antiquariat zusatzlich an Bedeutung. Deswegen ist es verstandlich, dass der Autor auf das Antiquariat stieß, als er Nachforschungen über den

  10. Pesticide Labels

    Science.gov (United States)

    Pesticide labels translate results of our extensive evaluations of pesticide products into conditions, directions and precautions that define parameters for use of a pesticide with the goal of ensuring protection of human health and the environment.

  11. Pesticides in Brazilian freshwaters: a critical review.

    Science.gov (United States)

    Albuquerque, A F; Ribeiro, J S; Kummrow, F; Nogueira, A J A; Montagner, C C; Umbuzeiro, G A

    2016-07-13

    The widespread use of pesticides in agriculture can lead to water contamination and cause adverse effects on non-target organisms. Brazil has been the world's top pesticide market consumer since 2008, with 381 approved pesticides for crop use. This study provides a comprehensive literature review on the occurrence of pesticide residues in Brazilian freshwaters. We searched for information in official agency records and peer-reviewed scientific literature. Risk quotients were calculated to assess the potential risk posed to aquatic life by the individual pesticides based on their levels of water contamination. Studies about the occurrence of pesticides in freshwaters in Brazil are scarce and concentrated in few sampling sites in 5 of the 27 states. Herbicides (21) accounted for the majority of the substances investigated, followed by fungicides (11), insecticides (10) and plant growth regulators (1). Insecticides are the class of major concern. Brazil would benefit from the implementation of a nationwide pesticide freshwater monitoring program to support preventive, remediation and enforcement actions.

  12. Applying distance-to-target weighing methodology to evaluate the environmental performance of bio-based energy, fuels, and materials

    International Nuclear Information System (INIS)

    Weiss, Martin; Patel, Martin; Heilmeier, Hermann; Bringezu, Stefan

    2007-01-01

    The enhanced use of biomass for the production of energy, fuels, and materials is one of the key strategies towards sustainable production and consumption. Various life cycle assessment (LCA) studies demonstrate the great potential of bio-based products to reduce both the consumption of non-renewable energy resources and greenhouse gas emissions. However, the production of biomass requires agricultural land and is often associated with adverse environmental effects such as eutrophication of surface and ground water. Decision making in favor of or against bio-based and conventional fossil product alternatives therefore often requires weighing of environmental impacts. In this article, we apply distance-to-target weighing methodology to aggregate LCA results obtained in four different environmental impact categories (i.e., non-renewable energy consumption, global warming potential, eutrophication potential, and acidification potential) to one environmental index. We include 45 bio- and fossil-based product pairs in our analysis, which we conduct for Germany. The resulting environmental indices for all product pairs analyzed range from -19.7 to +0.2 with negative values indicating overall environmental benefits of bio-based products. Except for three options of packaging materials made from wheat and cornstarch, all bio-based products (including energy, fuels, and materials) score better than their fossil counterparts. Comparing the median values for the three options of biomass utilization reveals that bio-energy (-1.2) and bio-materials (-1.0) offer significantly higher environmental benefits than bio-fuels (-0.3). The results of this study reflect, however, subjective value judgments due to the weighing methodology applied. Given the uncertainties and controversies associated not only with distance-to-target methodologies in particular but also with weighing approaches in general, the authors strongly recommend using weighing for decision finding only as a

  13. Two types of health care systems and their influence on the introduction of perinatal care: an epidemiological twin model in Berlin from 1950 to 1990.

    Science.gov (United States)

    Arabin, B; Raum, E; Mohnhaupt, A; Schwartz, F W

    1999-06-01

    When perinatal medicine emerged as a new medical discipline in the 1960s, Berlin was as one of the world's leading centers. During that time, the city was separated into two parts, each fostering its own health care system. After the destruction of the Berlin Wall, it was possible to speak with the citizens of East Berlin and to access their database systems. This created the singular opportunity to objectively compare the development of perinatal care in both parts of Berlin. Rates of maternal, perinatal, and infant mortality as well as the rate of preterm deliveries were evaluated over time and between East and West Berlin. The timing of introduction of 20 specific perinatal interventions was evaluated across 18 hospitals with more than 500 deliveries (11 in West Berlin and 7 in East Berlin). Interviews were conducted with 100 gynecologists, 100 midwives, and 100 women who had recently delivered their first child from each side of the city regarding their opinions of the importance of these interventions for the quality of perinatal medicine and how they would distribute a budget to improve maternity care. Maternal, perinatal, and infant mortality decreased in both parts of Berlin until 1990 (p Berlin, though the preterm delivery rate was slightly lower in East Berlin compared with West Berlin (p Berlin. In contrast, certain public health measures--such as maternal transport, screening programs for diabetes, and support of breastfeeding--were introduced much earlier in East Berlin. There were significant differences between the beliefs of gynecologists, midwives, and mothers in East and West Berlin. In general, citizens of East Berlin were more enthusiastic about technological medical advances, whereas citizens of West Berlin were more supportive of public health and alternative methods. In addition, there were significant differences between female and male physicians in their beliefs about how to improve health care, regardless of whether they resided in East

  14. Cross-Linked Amylose Bio-Plastic: A Transgenic-Based Compostable Plastic Alternative

    Directory of Open Access Journals (Sweden)

    Domenico Sagnelli

    2017-09-01

    Full Text Available Bio-plastics and bio-materials are composed of natural or biomass derived polymers, offering solutions to solve immediate environmental issues. Polysaccharide-based bio-plastics represent important alternatives to conventional plastic because of their intrinsic biodegradable nature. Amylose-only (AO, an engineered barley starch with 99% amylose, was tested to produce cross-linked all-natural bioplastic using normal barley starch as a control. Glycerol was used as plasticizer and citrate cross-linking was used to improve the mechanical properties of cross-linked AO starch extrudates. Extrusion converted the control starch from A-type to Vh- and B-type crystals, showing a complete melting of the starch crystals in the raw starch granules. The cross-linked AO and control starch specimens displayed an additional wide-angle diffraction reflection. Phospholipids complexed with Vh-type single helices constituted an integrated part of the AO starch specimens. Gas permeability tests of selected starch-based prototypes demonstrated properties comparable to that of commercial Mater-Bi© plastic. The cross-linked AO prototypes had composting characteristics not different from the control, indicating that the modified starch behaves the same as normal starch. The data shows the feasibility of producing all-natural bioplastic using designer starch as raw material.

  15. Cross-Linked Amylose Bio-Plastic: A Transgenic-Based Compostable Plastic Alternative

    Science.gov (United States)

    Sagnelli, Domenico; Kemmer, Gerdi Christine; Holse, Mette; Hebelstrup, Kim H.; Bao, Jinsong; Stelte, Wolfgang; Bjerre, Anne-Belinda; Blennow, Andreas

    2017-01-01

    Bio-plastics and bio-materials are composed of natural or biomass derived polymers, offering solutions to solve immediate environmental issues. Polysaccharide-based bio-plastics represent important alternatives to conventional plastic because of their intrinsic biodegradable nature. Amylose-only (AO), an engineered barley starch with 99% amylose, was tested to produce cross-linked all-natural bioplastic using normal barley starch as a control. Glycerol was used as plasticizer and citrate cross-linking was used to improve the mechanical properties of cross-linked AO starch extrudates. Extrusion converted the control starch from A-type to Vh- and B-type crystals, showing a complete melting of the starch crystals in the raw starch granules. The cross-linked AO and control starch specimens displayed an additional wide-angle diffraction reflection. Phospholipids complexed with Vh-type single helices constituted an integrated part of the AO starch specimens. Gas permeability tests of selected starch-based prototypes demonstrated properties comparable to that of commercial Mater-Bi© plastic. The cross-linked AO prototypes had composting characteristics not different from the control, indicating that the modified starch behaves the same as normal starch. The data shows the feasibility of producing all-natural bioplastic using designer starch as raw material. PMID:28973963

  16. Cross-Linked Amylose Bio-Plastic: A Transgenic-Based Compostable Plastic Alternative.

    Science.gov (United States)

    Sagnelli, Domenico; Hooshmand, Kourosh; Kemmer, Gerdi Christine; Kirkensgaard, Jacob J K; Mortensen, Kell; Giosafatto, Concetta Valeria L; Holse, Mette; Hebelstrup, Kim H; Bao, Jinsong; Stelte, Wolfgang; Bjerre, Anne-Belinda; Blennow, Andreas

    2017-09-30

    Bio-plastics and bio-materials are composed of natural or biomass derived polymers, offering solutions to solve immediate environmental issues. Polysaccharide-based bio-plastics represent important alternatives to conventional plastic because of their intrinsic biodegradable nature. Amylose-only (AO), an engineered barley starch with 99% amylose, was tested to produce cross-linked all-natural bioplastic using normal barley starch as a control. Glycerol was used as plasticizer and citrate cross-linking was used to improve the mechanical properties of cross-linked AO starch extrudates. Extrusion converted the control starch from A-type to Vh- and B-type crystals, showing a complete melting of the starch crystals in the raw starch granules. The cross-linked AO and control starch specimens displayed an additional wide-angle diffraction reflection. Phospholipids complexed with Vh-type single helices constituted an integrated part of the AO starch specimens. Gas permeability tests of selected starch-based prototypes demonstrated properties comparable to that of commercial Mater-Bi © plastic. The cross-linked AO prototypes had composting characteristics not different from the control, indicating that the modified starch behaves the same as normal starch. The data shows the feasibility of producing all-natural bioplastic using designer starch as raw material.

  17. Bio energy: Bio fuel - Properties and Production

    International Nuclear Information System (INIS)

    Wilhelmsen, Gunnar; Martinsen, Arnold Kyrre; Sandberg, Eiliv; Fladset, Per Olav; Kjerschow, Einar; Teslo, Einar

    2001-01-01

    This is Chapter 3 of the book ''Bio energy - Environment, technique and market''. Its main sections are: (1) Definitions and properties, (2) Bio fuel from the forest, (3) Processed bio fuel - briquettes, pellets and powder, (4) Bio fuel from agriculture, (5) Bio fuel from agro industry, (6) Bio fuel from lakes and sea, (7) Bio fuel from aquaculture, (8) Bio fuel from wastes and (9) Hydrogen as a fuel. The exposition largely describes the conditions in Norway. The chapter on energy from the forest includes products from the timber and sawmill industry, the pulp and paper industry, furniture factories etc. Among agricultural sources are straw, energy forests, vegetable oil, bio ethanol, manure

  18. Bio based cogeneration plants in Sweden; Biobaserte kraftvarmeverk i Sverige

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    Cogeneration plants using bio fuel need a certificate in the Swedish electricity certificate system. Since the initiation of the system in 2003 the plants have taken advantage of the possibility of switching from fossil, to bio fuel. However, there is a potential for additional bio power production, provided that there is a market for the produced heating. The certificate system may contribute to an acceleration of investments in new capacities, and the facilitation of increased bio power production.

  19. Identification of Mycobacterium tuberculosis BioA inhibitors by using structure-based virtual screening

    Directory of Open Access Journals (Sweden)

    Singh S

    2018-05-01

    Full Text Available Swati Singh,1 Garima Khare,1 Ritika Kar Bahal,1 Prahlad C Ghosh,1 Anil K Tyagi1,2 1Department of Biochemistry, University of Delhi South Campus, New Delhi, India; 2Guru Gobind Singh Indraprastha University, New Delhi, India Background: 7,8-Diaminopelargonic acid synthase (BioA, an enzyme of biotin biosynthesis pathway, is a well-known promising target for anti-tubercular drug development. Methods: In this study, structure-based virtual screening was employed against the active site of BioA to identify new chemical entities for BioA inhibition and top ranking compounds were evaluated for their ability to inhibit BioA enzymatic activity. Results: Seven compounds inhibited BioA enzymatic activity by greater than 60% at 100 µg/mL with most potent compounds being A36, A35 and A65, displaying IC50 values of 10.48 µg/mL (28.94 µM, 33.36 µg/mL (88.16 µM and 39.17 µg/mL (114.42 µM, respectively. Compounds A65 and A35 inhibited Mycobacterium tuberculosis (M. tuberculosis growth with MIC90 of 20 µg/mL and 80 µg/mL, respectively, whereas compound A36 exhibited relatively weak inhibition of M. tuberculosis growth (83% inhibition at 200 µg/mL. Compound A65 emerged as the most potent compound identified in our study that inhibited BioA enzymatic activity and growth of the pathogen and possessed drug-like properties. Conclusion: Our study has identified a few hit molecules against M. tuberculosis BioA that can act as potential candidates for further development of potent anti-tubercular therapeutic agents. Keywords: Mycobacterium tuberculosis, BioA, virtual screening, drug discovery

  20. Reactions to Receiving a Gift-Maternal Scaffolding and Cultural Learning in Berlin and Delhi.

    Science.gov (United States)

    Kärtner, Joscha; Crafa, Daina; Chaudhary, Nandita; Keller, Heidi

    2016-05-01

    This study shows how Berlin (n = 35) and Delhi (n = 28) mothers scaffold a common and highly scripted social situation, namely gift giving, and enable cultural learning in 19-month-olds. Using modeling and prompting to encourage appropriate responses, mothers took culture-specific directions during scaffolding that were in line with the broader cultural model as assessed by maternal socialization goals (SGs). Whereas Berlin mothers prioritized autonomous SGs, Delhi mothers emphasized autonomous and relational SGs to similar degrees. During scaffolding, Berlin mothers focused on maximizing positive affect and acknowledging the gift, whereas Delhi mothers prompted toddlers to acknowledge the giver more often. Furthermore, there were differences in toddlers' behavior in line with these culture-specific scripts guiding gift giving. © 2016 The Authors. Child Development © 2016 Society for Research in Child Development, Inc.

  1. On quiet wheels through Berlin's underground

    OpenAIRE

    Hohwieler, Eckard

    2011-01-01

    Many Berliners still have clear memories from last winter of the massive technical problems experienced by the city's S-Bahn - the municipal rail system operated by the German national railroad the Deutsche Bahn. At times only half the trains were running; the rest had to be taken out of service for safety reasons. For operators of railway vehicles in particular, it is important to know the condition of their trains so as to be able to plan their maintenance and repair in advance. In the inno...

  2. Sustainable Bio-Aggregate-Based Composites Containing Hemp Hurds and Alternative Binder

    Directory of Open Access Journals (Sweden)

    Nadezda Stevulova

    2018-02-01

    Full Text Available This experimental study was focused on the application of a surface-modified hemp- hurds aggregate into composites using an alternative binder of MgO-cement. This paper presents the results of the comparative study of the parameters (chemical and physico-chemical modification, and hardening time affecting the physical (density, thermal conductivity coefficient and water-absorption behavior and mechanical properties (compressive strength of the bio-aggregate-based composite. A test of the parameters of the bio-composite samples showed some differences, which were determined by the chemical and surface properties of the modified filler, and which affected the mechanisms of hardening. The bulk density values of the hemp hurd composites hardened for 28 days place this material in the lightweight category of composites. The values of water absorption and the thermal conductivity coefficient of bio-composites decreased, and the strength parameter increased with an increase in the hardening time. The lower values of compressive strength, water absorption, and thermal conductivity coefficient (except for the ethylenediaminetetraacetic-acid-treated filler were observed in composites based on fillers chemically treated with NaOH and Ca(OH2 compared to referential composites (based on original hemp hurds. This is related to changes in the chemical composition of hemp hurds after chemical modification. The composites with ultrasound-treated hemp hurds had the greatest strengths at each hardening time. This is related to pulping the bundles of fibers and forming a larger surface area for bonding in the matrix.

  3. Training Manual Occupational Pesticide Exposure & Health and Safe & Responsible Handling of Pesticides

    NARCIS (Netherlands)

    Maden, van der E.C.L.J.; Koomen, I.

    2016-01-01

    Pesticides are commonly used in the horticulture sector. While emphasis is often on the correct and efficient application of pesticides, the risk associated with application of pesticides receives less attention. Those working with pesticides need to know about occupational pesticide exposure and

  4. Adjustments of the Pesticide Risk Index Used in Environmental Policy in Flanders.

    Science.gov (United States)

    Fevery, Davina; Peeters, Bob; Lenders, Sonia; Spanoghe, Pieter

    2015-01-01

    Indicators are used to quantify the pressure of pesticides on the environment. Pesticide risk indicators typically require weighting environmental exposure by a no effect concentration. An indicator based on spread equivalents (ΣSeq) is used in environmental policy in Flanders (Belgium). The pesticide risk for aquatic life is estimated by weighting active ingredient usage by the ratio of their maximum allowable concentration and their soil halflife. Accurate estimates of total pesticide usage in the region are essential in such calculations. Up to 2012, the environmental impact of pesticides was estimated on sales figures provided by the Federal Government. Since 2013, pesticide use is calculated based on results from the Farm Accountancy Data Network (FADN). The estimation of pesticide use was supplemented with data for non-agricultural use based on sales figures of amateur use provided by industry and data obtained from public services. The Seq-indicator was modified to better reflect reality. This method was applied for the period 2009-2012 and showed differences between estimated use and sales figures of pesticides. The estimated use of pesticides based on accountancy data is more accurate compared to sales figures. This approach resulted in a better view on pesticide use and its respective environmental impact in Flanders.

  5. Adjustments of the Pesticide Risk Index Used in Environmental Policy in Flanders.

    Directory of Open Access Journals (Sweden)

    Davina Fevery

    Full Text Available Indicators are used to quantify the pressure of pesticides on the environment. Pesticide risk indicators typically require weighting environmental exposure by a no effect concentration. An indicator based on spread equivalents (ΣSeq is used in environmental policy in Flanders (Belgium. The pesticide risk for aquatic life is estimated by weighting active ingredient usage by the ratio of their maximum allowable concentration and their soil halflife. Accurate estimates of total pesticide usage in the region are essential in such calculations. Up to 2012, the environmental impact of pesticides was estimated on sales figures provided by the Federal Government. Since 2013, pesticide use is calculated based on results from the Farm Accountancy Data Network (FADN. The estimation of pesticide use was supplemented with data for non-agricultural use based on sales figures of amateur use provided by industry and data obtained from public services. The Seq-indicator was modified to better reflect reality. This method was applied for the period 2009-2012 and showed differences between estimated use and sales figures of pesticides. The estimated use of pesticides based on accountancy data is more accurate compared to sales figures. This approach resulted in a better view on pesticide use and its respective environmental impact in Flanders.

  6. Understanding bio-economics

    OpenAIRE

    Patel, M.K.

    2008-01-01

    New plants for production of bio-based fuels, chemicals or plastics are being set up at an accelerating pace. However, this transition towards bio-based fuels, feedstocks and chemicals has not come without consequences. Increased demand has pushed up prices of key agricultural products such as maize and corn with the result that consumers - especially those in low income areas - have reacted with concern and protest. At the same time, environmental research institutes and lobby groups - and n...

  7. Water and Pesticides

    Science.gov (United States)

    ; Environment Human Health Animal Health Safe Use Practices Food Safety Environment Air Water Soil Wildlife Home Page Pesticides and the Environment Water and Pesticides Related Topics: What Happens to Pesticides Released into the Environment? Water Solubility Drinking Water and Pesticides Fact Sheet

  8. Risk factors associated with purchasing pesticide from shops for self-poisoning

    DEFF Research Database (Denmark)

    Weerasinghe, Manjula; Konradsen, Flemming; Eddleston, Michael

    2015-01-01

    of individuals who purchase pesticides directly from shops and how they differ from individuals who access pesticides from other sources such as home, home garden or farmland. This information will help inform possible vendor/shop-based intervention strategies aimed at reducing access to pesticides used for self-harm......INTRODUCTION: Pesticide self-poisoning is one of the most frequently used methods of suicide worldwide, killing over 300,000 people annually. Around 15-20% of pesticide self-poisonings occur soon after the person has bought the pesticide from a shop. We aim to determine the characteristics....... METHODS AND ANALYSIS: This study will investigate risk factors associated with purchasing pesticides for acts of self-poisoning from pesticide shops, including cases identified over a 9-month period using a population-based case-control group approach. Four interviewer-administered data collection tools...

  9. BioFET-SIM

    DEFF Research Database (Denmark)

    Hediger, M. R.; Martinez, K. L.; Nygård, J.

    2013-01-01

    Biosensors based on nanowire field effect transistor (FET) have received much attention in recent years as a way to achieve ultra-sensitive and label-free sensing of molecules of biological interest. The BioFET-SIM computer model permits the analysis and interpretation of experimental sensor...... signals through its web-based interface www.biofetsim.org. The model also allows for predictions of the effects of changes in the experimental setup on the sensor signal. After an introduction to nanowire-based FET biosensors, this chapter reviews the theoretical basis of BioFET-SIM models describing both...... single and multiple charges on the analyte. Afterwards the usage of the interface and its relative command line version is briefly shown. Finally, possible applications of the BioFET-SIM model are presented. Among the possible uses of the interface, the effects on the predicted signal of pH, buffer ionic...

  10. Sustainable coatings from bio-based, enzymatically synthesized polyesters with enhanced functionalities

    NARCIS (Netherlands)

    Gustini, L.; Lavilla, C.; Finzel, L.; Noordover, B.A.J.; Hendrix, M.M.R.M.; Koning, C.E.

    2016-01-01

    Bio-based sorbitol-containing polyester polyols were synthesized via enzymatic polycondensation. The selectivity of the biocatalyst for primary vs. secondary hydroxyl groups allowed for the preparation of close to linear renewable polyester polyols with enhanced hydroxyl functionalities, both as

  11. Thermoplastic poly(urethane urea)s from novel, bio-based amorphous polyester diols

    NARCIS (Netherlands)

    Tang, D.; Noordover, B.A.J.; Sablong, R.J.; Koning, C.E.

    2012-01-01

    In this study, two novel, bio-based, amorphous polyester diols, namely poly(1,2-dimethylethylene adipate) (PDMEA) and poly(1,2-dimethylethylene succinate) (PDMES) are used to prepare thermoplastic poly(urethane urea)s (TPUUs). Interestingly, the TPUUs based on PDMEA show similar thermal and

  12. Novel two-tiered approach of ecological risk assessment for pesticide mixtures based on joint effects.

    Science.gov (United States)

    Tian, Dayong; Mao, Haichen; Lv, Huichao; Zheng, Yong; Peng, Conghu; Hou, Shaogang

    2018-02-01

    Ecological risk assessments for mixtures have attracted considerable attention. In this study, 38 pesticides in the real environment were taken as objects and their toxicities to different organisms from three trophic levels were employed to assess the ecological risk of the mixture. The first tier assessment was based on the CA effect and the obtained sum of risk quotients (SRQ species-CA ) were 3.06-9.22. The second tier assessment was based on non-CA effects and the calculated SRQ species-TU are 5.37-9.29 using joint effects (TU sum ) as modified coefficients, which is higher than SRQ species-CA and indicates that ignoring joint effects might run the risk of underestimating the actual impact of pesticide mixtures. Due to the influences of synergistic and antagonistic effects, risk contribution of components to mixture risks based on non-CA effects are different from those based on the CA effect. Moreover, it was found that the top 8 dominating components explained 95.5%-99.8% of mixture risks in this study. The dominating components are similar in the two tiers for a given species. Accordingly, a novel two-tiered approach was proposed to assess the ecological risks of mixtures based on joint effects. This study provides new insights for ecological risk assessments with the consideration of joint effects of components in the pesticide mixtures. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. The Closure of the Cycle: Enzymatic Synthesis and Functionalization of Bio-Based Polyesters.

    Science.gov (United States)

    Pellis, Alessandro; Herrero Acero, Enrique; Ferrario, Valerio; Ribitsch, Doris; Guebitz, Georg M; Gardossi, Lucia

    2016-04-01

    The polymer industry is under pressure to mitigate the environmental cost of petrol-based plastics. Biotechnologies contribute to the gradual replacement of petrol-based chemistry and the development of new renewable products, leading to the closure of carbon circle. An array of bio-based building blocks is already available on an industrial scale and is boosting the development of new generations of sustainable and functionally competitive polymers, such as polylactic acid (PLA). Biocatalysts add higher value to bio-based polymers by catalyzing not only their selective modification, but also their synthesis under mild and controlled conditions. The ultimate aim is the introduction of chemical functionalities on the surface of the polymer while retaining its bulk properties, thus enlarging the spectrum of advanced applications. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. Bio-oil based biorefinery strategy for the production of succinic acid

    Science.gov (United States)

    2013-01-01

    Background Succinic acid is one of the key platform chemicals which can be produced via biotechnology process instead of petrochemical process. Biomass derived bio-oil have been investigated intensively as an alternative of diesel and gasoline fuels. Bio-oil could be fractionized into organic phase and aqueous phase parts. The organic phase bio-oil can be easily upgraded to transport fuel. The aqueous phase bio-oil (AP-bio-oil) is of low value. There is no report for its usage or upgrading via biological methods. In this paper, the use of AP-bio-oil for the production of succinic acid was investigated. Results The transgenic E. coli strain could grow in modified M9 medium containing 20 v/v% AP-bio-oil with an increase in OD from 0.25 to 1.09. And 0.38 g/L succinic acid was produced. With the presence of 4 g/L glucose in the medium, succinic acid concentration increased from 1.4 to 2.4 g/L by addition of 20 v/v% AP-bio-oil. When enzymatic hydrolysate of corn stover was used as carbon source, 10.3 g/L succinic acid was produced. The obtained succinic acid concentration increased to 11.5 g/L when 12.5 v/v% AP-bio-oil was added. However, it decreased to 8 g/L when 50 v/v% AP-bio-oil was added. GC-MS analysis revealed that some low molecular carbon compounds in the AP-bio-oil were utilized by E. coli. Conclusions The results indicate that AP-bio-oil can be used by E. coli for cell growth and succinic acid production. PMID:23657107

  15. Long-Term Persistence of Pesticides and TPs in Archived Agricultural Soil Samples and Comparison with Pesticide Application.

    Science.gov (United States)

    Chiaia-Hernandez, Aurea C; Keller, Armin; Wächter, Daniel; Steinlin, Christine; Camenzuli, Louise; Hollender, Juliane; Krauss, Martin

    2017-09-19

    For polar and more degradable pesticides, not many data on long-term persistence in soil under field conditions and real application practices exist. To assess the persistence of pesticides in soil, a multiple-compound screening method (log K ow 1.7-5.5) was developed based on pressurized liquid extraction, QuEChERS and LC-HRMS. The method was applied to study 80 polar pesticides and >90 transformation products (TPs) in archived topsoil samples from the Swiss Soil Monitoring Network (NABO) from 1995 to 2008 with known pesticide application patterns. The results reveal large variations between crop type and field sites. For the majority of the sites 10-15 pesticides were identified with a detection rate of 45% at concentrations between 1 and 330 μg/kg dw in soil. Furthermore, TPs were detected in 47% of the cases where the "parent-compound" was applied. Overall, residues of about 80% of all applied pesticides could be detected with half of these found as TPs with a persistence of more than a decade.

  16. Zero-Acreage Farming in the City of Berlin: An Aggregated Stakeholder Perspective on Potential Benefits and Challenges

    Directory of Open Access Journals (Sweden)

    Kathrin Specht

    2015-04-01

    Full Text Available How can buildings be combined with agricultural production and what are the major potential benefits and challenges for the introduction of zero-acreage farming (ZFarming in Berlin from the relevant stakeholders’ perspectives? These questions were explored through a series of interviews and stakeholder workshops held between 2011 and 2013. The aim was to identify the most suitable building-integrated farming model for the Berlin metropolitan area and to develop guidelines for the model’s successful and sustainable implementation through a stakeholder-driven approach. This paper provides an aggregated synthesis of the outcomes derived from the qualitative interviews and stakeholder workshops. As the results reveal, the stakeholders perceive potential benefits and challenges related to the issue of ZFarming in all dimensions (economic, social, environmental and political. They largely agreed on the importance of focusing on local resources, using energy-efficient production—including social and educational aspects—and developing new market structures when introducing ZFarming to the city of Berlin. The stakeholders identified urban rooftop greenhouses (RTG as the most promising farming model for Berlin. In a joint collaboration of all stakeholders, a manual for RTG was developed within the participatory innovation process that addresses the identified problems and challenges associated with future implementation and governance of RTG in Berlin and beyond.

  17. Sustainability Benefits and Challenges of Inter-Organizational Collaboration in Bio-Based Business: A Systematic Literature Review

    Directory of Open Access Journals (Sweden)

    Gohar Nuhoff-Isakhanyan

    2016-03-01

    Full Text Available Bio-based businesses are often considered to be sustainable. However, they are also linked to sustainability challenges such as deforestation and soil erosion. Encouraged to exploit innovative solutions and enhance sustainability, organizations engaged in bio-based activities extensively explore collaboration possibilities with external partners. The objective of this paper is to integrate the available knowledge on sustainability of inter-organisational collaborations in bio-based businesses, while considering the three aspects of sustainability: environmental, economic, and social. We collected data from three academic sources—Web of Science, Scopus, and EconLit—and conducted a systematic literature review. The results show the importance of geographical proximity and complementarity in creating sustainability benefits such as reduced emissions, reduced waste, economic synergies, and socio-economic activities. Based on the findings, we have developed a framework that illustrates sustainability benefits and challenges. Interestingly, the studies emphasize sustainability benefits more in emerging than in industrialised economies, especially relating to the social aspects of sustainability. In conclusion, although the scholars have not discussed mitigation of several sustainability challenges in bio-based businesses, such as land use conflicts, they have found evidence of vital sustainability benefits, such as energy availability, lower emissions, improved socio-economic life, and poverty reduction, which are essential in emerging economies.

  18. Vom Geschäftsgang zum Prozess: Prozessmanagement in Bibliotheken am Beispiel der Staatsbibliothek zu Berlin

    Directory of Open Access Journals (Sweden)

    Cornelia Vonhof

    2015-12-01

    Full Text Available Der Beitrag skizziert den Weg der Staatsbibliothek zu Berlin bei der Implementierung eines systematischen Prozessmanagements. Basierend auf den Erfahrungen aus einem Pilotprojekt werden Vorgehensweisen und Methoden reflektiert und weiterentwickelt, die sich eignen, in einer großen, arbeitsteiligen Organisation eingesetzt zu werden. Beleuchtet werden Motivationsfaktoren für Prozessmanagement sowie neue Ansätze wie Service Blueprint und Adaptiv Case Management, die das klassische Verständnis von Prozessmanagement erweitern. The article outlines the path of the Berlin State Library working towards the implementation of a systematic process management. Based on the experience of a pilot project procedures and methods are reflected and further developed to be suitable for a large, work-sharing organization. Motivating factors for process management as well as new approaches such as Service Blueprint and Adaptive Case Management, that expand the classical understanding of process management, are covered.

  19. Pesticides

    Science.gov (United States)

    ... stores. Exposure to pesticides can happen in the workplace, through foods that are eaten, and in the ... or place bait in areas where children or pets have access. DO NOT stock up on pesticides, ...

  20. The first conference of Signatory States to the UN Global Climate Convention: Results of the Berlin summit conference

    International Nuclear Information System (INIS)

    Ehrmann, M.

    1996-01-01

    The article briefly explains the background of the Berlin summit conference as well as some results, as for instance the ''Berlin mandate'', or agreements concerning organisational structures or procedures like those termed ''joint implementation''. (Orig./CB) [de

  1. The 2nd Guards Tank Army in the Berlin Strategic Offensive Operation

    Directory of Open Access Journals (Sweden)

    Vladimir Ottovich Daynes

    2015-01-01

    Full Text Available One of the greatest battles of the Great Patriotic and also the World War II took place on the outskirts of the capital of Nazi Germany on April 16, 1945. Three magor fronts - 1st Belorussian, 2nd Byelorussian, 1st Ukrainian - and four tank armies were involved. They were not used as highly mobile groups to enter Berlin from the north and north-west, they were sent first to break powerful enemy defenses, and then to wage battles on the streets. The Supreme Command and the commanders of the 1st Byelorussian and 1st Ukrainian fronts understood the inevitability of heavy losses in tanks and troops, but deliberately took this step. The aim was not only a speedy capture of the German capital and the end of the war, but also to be ahead of allies on their way to Berlin. The article deals with the planning and preparation for the Berlin Strategic Offensive Operation, the use of 2nd Guards Tank Army, who played along with other tank divisions a magor role in the success of this operation.

  2. Soil and Pesticides

    Science.gov (United States)

    ; Environment Human Health Animal Health Safe Use Practices Food Safety Environment Air Water Soil Wildlife Home Page Pesticides and the Environment Soil and Pesticides Related Topics: What Happens to Pesticides español Soil and Pesticides Soil can be degraded and the community of organisms living in the soil can

  3. Comparative techno-economic analysis of biohydrogen production via bio-oil gasification and bio-oil reforming

    International Nuclear Information System (INIS)

    Zhang, Yanan; Brown, Tristan R.; Hu, Guiping; Brown, Robert C.

    2013-01-01

    This paper evaluates the economic feasibility of biohydrogen production via two bio-oil processing pathways: bio-oil gasification and bio-oil reforming. Both pathways employ fast pyrolysis to produce bio-oil from biomass stock. The two pathways are modeled using Aspen Plus ® for a 2000 t d −1 facility. Equipment sizing and cost calculations are based on Aspen Economic Evaluation® software. Biohydrogen production capacity at the facility is 147 t d −1 for the bio-oil gasification pathway and 160 t d −1 for the bio-oil reforming pathway. The biomass-to-fuel energy efficiencies are 47% and 84% for the bio-oil gasification and bio-oil reforming pathways, respectively. Total capital investment (TCI) is 435 million dollars for the bio-oil gasification pathway and is 333 million dollars for the bio-oil reforming pathway. Internal rates of return (IRR) are 8.4% and 18.6% for facilities employing the bio-oil gasification and bio-oil reforming pathways, respectively. Sensitivity analysis demonstrates that biohydrogen price, biohydrogen yield, fixed capital investment (FCI), bio-oil yield, and biomass cost have the greatest impacts on facility IRR. Monte-Carlo analysis shows that bio-oil reforming is more economically attractive than bio-oil gasification for biohydrogen production. -- Highlights: ► Biohydrogen production via bio-oil reforming has higher energy efficiency compared to gasification. ► Hydrogen price, fixed capital cost, and feedstock cost most strongly affect IRR. ► Lower risk investment is biohydrogen production via bio-oil reforming

  4. Using Machine learning method to estimate Air Temperature from MODIS over Berlin

    Science.gov (United States)

    Marzban, F.; Preusker, R.; Sodoudi, S.; Taheri, H.; Allahbakhshi, M.

    2015-12-01

    Land Surface Temperature (LST) is defined as the temperature of the interface between the Earth's surface and its atmosphere and thus it is a critical variable to understand land-atmosphere interactions and a key parameter in meteorological and hydrological studies, which is involved in energy fluxes. Air temperature (Tair) is one of the most important input variables in different spatially distributed hydrological, ecological models. The estimation of near surface air temperature is useful for a wide range of applications. Some applications from traffic or energy management, require Tair data in high spatial and temporal resolution at two meters height above the ground (T2m), sometimes in near-real-time. Thus, a parameterization based on boundary layer physical principles was developed that determines the air temperature from remote sensing data (MODIS). Tair is commonly obtained from synoptic measurements in weather stations. However, the derivation of near surface air temperature from the LST derived from satellite is far from straight forward. T2m is not driven directly by the sun, but indirectly by LST, thus T2m can be parameterized from the LST and other variables such as Albedo, NDVI, Water vapor and etc. Most of the previous studies have focused on estimating T2m based on simple and advanced statistical approaches, Temperature-Vegetation index and energy-balance approaches but the main objective of this research is to explore the relationships between T2m and LST in Berlin by using Artificial intelligence method with the aim of studying key variables to allow us establishing suitable techniques to obtain Tair from satellite Products and ground data. Secondly, an attempt was explored to identify an individual mix of attributes that reveals a particular pattern to better understanding variation of T2m during day and nighttime over the different area of Berlin. For this reason, a three layer Feedforward neural networks is considered with LMA algorithm

  5. A benchmark report on MVA Berlin, the key element of waste management in Berlin; MVA Berlin als Herzstueck der Berliner Entsorgung im Vergleich mit der Wettbewerbs-Benchmark

    Energy Technology Data Exchange (ETDEWEB)

    Kempin, T. [Berliner Stadtreinigungsbetrieb, Berlin (Germany)

    2004-07-01

    The MVA Ruhleben incinerator has state-of-the-art technology, volume-dependent prime costs of 100-130 EUR/t, an acceptance payment of 63.70 EUR/t, employees covered by collective agreement system, disposal capacities of 500,000 tpa of residues, ecological sustainability, and customer-friendliness. Its importance will increase in the future as more than half of the expected waste volume of 983,000 tpa will be processed from 2005. (orig.) [German] Die MVA Ruhleben gewaehrleistet derzeit den Stand der Technik, mengenabhaengige Selbstkosten zwischen 100 EUR/t und 130 EUR/t, ein Annahmeentgelt von 63,70 EUR/t, soziale tarifgebundene Arbeitsplaetze, Entsorgungssicherheit, derzeit fuer 500.000 Tonnen Abfall pro Jahr, oekologische Nachhaltigkeit, Kundenfreundlichkeit. Die MVA Ruhleben wird zukuenftig fuer die Abfallentsorgung in Berlin eine noch groessere Bedeutung haben. Mit etwa 520.000 t/a Abfallentsorgungskapazitaet wird sie mehr als die Haelfte des erwarteten ueberlassungspflichtigen Restabfallaufkommens von 983.000 t/a ab 2005 verarbeiten. (orig.)

  6. Pre-study on the Berlin-Budapest high-speed rail link; Hochgeschwindigkeitsverkehr: Vorstudie zur Strecke Berlin-Budapest

    Energy Technology Data Exchange (ETDEWEB)

    Fengler, W.; Stehle, J. [TU Dresden (Germany). Fakultaet Verkehrswissenschaften ' ' Friedrich List' ' ; Schach, R. [TU Dresden (Germany). Fakultaet Bauingenieurwesen; Stephan, A. [Inst. fuer Bahntechnik GmbH, Dresden/Berlin (Germany)

    2008-07-01

    In a pre-study, the Government of the State of Saxony commissioned a comparison between wheel/rail and maglev technology for high-speed operations on the northern section of the pan-European Corridor IV. From the holistic perspective of the business evaluation and the expected economic impact, it can be concluded that there is a case for establishing a guided high-speed link between Berlin and Budapest and that the plan should be pursued further. Teh pre-study showed that, taking a comprehensive view of investment and operational aspects, the Transrapid technology already stands comparison with wheel/rail technology. (orig.)

  7. A statistical downscaling approach for roadside NO2 concentrations: Application to a WRF-Chem study for Berlin

    Science.gov (United States)

    Kuik, Friderike; Lauer, Axel; von Schneidemesser, Erika; Butler, Tim

    2017-04-01

    Many European cities continue to struggle with meeting the European air quality limits for NO2. In Berlin, Germany, most of the exceedances in NO2 recorded at monitoring sites near busy roads can be largely attributed to emissions from traffic. In order to assess the impact of changes in traffic emissions on air quality at policy relevant scales, we combine the regional atmosphere-chemistry transport model WRF-Chem at a resolution of 1kmx1km with a statistical downscaling approach. Here, we build on the recently published study evaluating the performance of a WRF-Chem setup in representing observed urban background NO2 concentrations from Kuik et al. (2016) and extend this setup by developing and testing an approach to statistically downscale simulated urban background NO2 concentrations to street level. The approach uses a multilinear regression model to relate roadside NO2 concentrations observed with the municipal monitoring network with observed NO2 concentrations at urban background sites and observed traffic counts. For this, the urban background NO2 concentrations are decomposed into a long term, a synoptic and a diurnal component using the Kolmogorov-Zurbenko filtering method. We estimate the coefficients of the regression model for five different roadside stations in Berlin representing different street types. In a next step we combine the coefficients with simulated urban background concentrations and observed traffic counts, in order to estimate roadside NO2 concentrations based on the results obtained with WRF-Chem at the five selected stations. In a third step, we extrapolate the NO2 concentrations to all major roads in Berlin. The latter is based on available data for Berlin of daily mean traffic counts, diurnal and weekly cycles of traffic as well as simulated urban background NO2 concentrations. We evaluate the NO2 concentrations estimated with this method at street level for Berlin with additional observational data from stationary measurements and

  8. Design and Fabrication of Piezoresistive Based Encapsulated Poly-Si Cantilevers for Bio/chemical Sensing

    Science.gov (United States)

    Krishna, N. P. Vamsi; Murthy, T. R. Srinivasa; Reddy, K. Jayaprakash; Sangeeth, K.; Hegde, G. M.

    Cantilever-based sensing is a growing research field not only within micro regime but also in nano technology. The technology offers a method for rapid, on-line and in-situ monitoring of specific bio/chemical substances by detecting the nanomechanical responses of a cantilever sensor. Cantilever with piezoresistive based detection scheme is more attractive because of its electronics compatibility. Majority of commercially available micromachined piezoresistive sensors are bulk micromachined devices and are fabricated using single crystal silicon wafers. As substrate properties are not important in surface micromachining, the expensive silicon wafers can be replaced by cheaper substrates, such as poly-silicon, glass or plastic. Here we have designed SU-8 based bio/chemical compatible micro electro mechanical device that includes an encapsulated polysilicon piezoresistor for bio/chemical sensing. In this paper we report the design, fabrication and analysis of the encapsulated poly-Si cantilevers. Design and theoretical analysis are carried out using Finite Element Analysis software. For fabrication of poly-silicon piezoresistive cantilevers we followed the surface micromachining process steps. Preliminary characterization of the cantilevers is presented.

  9. Limits—Urban Density and Mobility Networks in West Berlin during the Period of Containment

    Directory of Open Access Journals (Sweden)

    Vanessa Miriam Carlow

    2014-10-01

    Full Text Available If space may be conceptualized as a natural resource, much like gas, oil, or minerals, then its production and use can also be thought of as something to be properly managed, taken care of, and not wasted. Limiting the expansion of the footprint of built-up land in urban areas forces this particular resource (space to be used more efficiently—in a sense, compelling it to be more creative and productive. These spatial constraints on urban areas generate different kinds of densification processes within the existing city, propagating densification, and with it new patterns and uses in urban development, as well as novel approaches to mitigating the hazards of dense urban environments. This paper examines the case of how spatial containment in West Berlin during the period of the Berlin Wall (1961–1989 produced such outcomes. West Berlin during this period can be considered a unique case of spatial containment, where a relatively large and vibrant modern city had to work around a clear and indelible limit to its physical expansion. This paper will discuss ways in which the containment influenced patterns of development in West Berlin toward densification and connectivity, focusing on the expansion of its infrastructural networks, and discuss the development of a new building culture around transformation and densification, including hybrid architectures and mitigation devices to deal with difficult sites produced by the densification.

  10. Ontology-Based Querying with Bio2RDF's Linked Open Data.

    Science.gov (United States)

    Callahan, Alison; Cruz-Toledo, José; Dumontier, Michel

    2013-04-15

    A key activity for life scientists in this post "-omics" age involves searching for and integrating biological data from a multitude of independent databases. However, our ability to find relevant data is hampered by non-standard web and database interfaces backed by an enormous variety of data formats. This heterogeneity presents an overwhelming barrier to the discovery and reuse of resources which have been developed at great public expense.To address this issue, the open-source Bio2RDF project promotes a simple convention to integrate diverse biological data using Semantic Web technologies. However, querying Bio2RDF remains difficult due to the lack of uniformity in the representation of Bio2RDF datasets. We describe an update to Bio2RDF that includes tighter integration across 19 new and updated RDF datasets. All available open-source scripts were first consolidated to a single GitHub repository and then redeveloped using a common API that generates normalized IRIs using a centralized dataset registry. We then mapped dataset specific types and relations to the Semanticscience Integrated Ontology (SIO) and demonstrate simplified federated queries across multiple Bio2RDF endpoints. This coordinated release marks an important milestone for the Bio2RDF open source linked data framework. Principally, it improves the quality of linked data in the Bio2RDF network and makes it easier to access or recreate the linked data locally. We hope to continue improving the Bio2RDF network of linked data by identifying priority databases and increasing the vocabulary coverage to additional dataset vocabularies beyond SIO.

  11. A screening framework for pesticide substitution in agriculture

    DEFF Research Database (Denmark)

    Steingrímsdóttir, María Magnea; Petersen, Annette; Fantke, Peter

    2018-01-01

    Farmers lack science-based tools to flexibly and rapidly identify more sustainable pesticides. To address this gap, we present a screening-level substitution framework to compare and rank pesticides using a consistent set of indicators including registration, pest resistance, human toxicity...... substitution list, performed worst. Total costs across considered pesticides range from 23 to 302 €/ha. Our framework constitutes an operational starting point for identifying sustainable pesticides by farmers and other stakeholders and highlights (a) the need to consider various relevant aspects influencing...... and aquatic ecotoxicity impact potentials, and market price. Toxicity-related damage costs and application costs were combined with application dosages to yield total costs per pesticide. We applied and tested our framework in a case study on pesticides applied to lettuce in Denmark. Our results indicate...

  12. Pesticides and the Environment

    Science.gov (United States)

    ; Environment Human Health Animal Health Safe Use Practices Food Safety Environment Air Water Soil Wildlife Home Page Pesticides and the Environment Related Topics: What Happens to Pesticides Released into the Environment? Pesticide Storage Pesticide Disposal Pesticide Products Integrated Pest Management (IPM) How Safe

  13. Pattern of pesticide storage before pesticide self-poisoning in rural Sri Lanka

    Science.gov (United States)

    Mohamed, Fahim; Manuweera, Gamini; Gunnell, David; Azher, Shifa; Eddleston, Michael; Dawson, Andrew; Konradsen, Flemming

    2009-01-01

    Background Deliberate self-poisoning with agricultural pesticides is the commonest means of suicide in rural Asia. It is mostly impulsive and facilitated by easy access to pesticides. The aim of this large observational study was to investigate the immediate source of pesticides used for self-harm to help inform suicide prevention strategies such as reducing domestic access to pesticides. Methods The study was conducted in a district hospital serving an agricultural region of Sri Lanka. Patients who had self-poisoned with pesticides and were admitted to the adult medical wards were interviewed by study doctors following initial resuscitation to identify the source of pesticides they have ingested. Results Of the 669 patients included in the analysis, 425 (63.5%) were male; the median age was 26 (IQR 20-36). In 511 (76%) cases, the pesticides had been stored either inside or immediately outside the house; among this group only eight patients obtained pesticides that were kept in a locked container. Ten percent (n = 67) of the patients used pesticides stored in the field while 14% (n = 91) purchased pesticides from shops within a few hours of the episode. The most common reasons for choosing the particular pesticide for self-harm were its easy accessibility (n = 311, 46%) or its popularity as a suicide agent in their village (n = 290, 43%). Conclusion Three quarters of people who ingested pesticides in acts of self-harm used products that were available within the home or in close proximity; relatively few patients purchased the pesticide for the act. The study highlights the importance of reducing the accessibility of toxic pesticides in the domestic environment. PMID:19889236

  14. Für Forschung und Kultur - Öffentlichkeitswirksame Darstellung bibliothekarischer Weltschätze und bibliothekarischer Wissenschaftsservices am Beispiel der Staatsbibliothek zu Berlin

    Directory of Open Access Journals (Sweden)

    Barbara Schneider-Kempf

    2014-12-01

    Full Text Available Die Öffentlichkeitsarbeit der Staatsbibliothek zu Berlin zielt auf eine wirksame Darstellung ihrer bibliothekarischen Weltschätze und ihrer Serviceangebote für die Wissenschaft ab. Sie ruht auf drei Säulen: kulturelle Breitenbildung für wenig bibliotheksaffine Kreise, allgemeine und breit gefächerte Öffentlichkeitsarbeit sowie Aktionen, die sich an spezielle communities in der Wissenschaft richten. Der Beitrag informiert auch über die erfolgreiche Umsetzung dieser Strategie anhand zahlreicher Beispiele. Er zeigt, wie es der Staatsbibliothek in der Hauptstadt Berlin, in der viele Gedächtnisinstitutionen tätig sind, gelingt, öffentlich präsent zu bleiben und ihr Profil zu vermitteln. The public relations work of the Berlin State Library – Prussian Cultural Heritage aims at effectively presenting its globally significant treasures as well as its services for the scientific world. It is based on three pillars: cultural education for the general public, especially for people who are not naturally close to libraries; a general and wide variety of public relations work; and events which target special communities in science. The paper also presents many examples for the effectual implementation of this strategy. It shows how the State Library, in the capital city of Berlin with its many memory institutions, succeeds in keeping a strong presence and communicating its profile to the public.

  15. Large-proportional shrunken bio-replication of shark skin based on UV-curing shrinkage

    International Nuclear Information System (INIS)

    Chen, Huawei; Che, Da; Zhang, Xin; Yue, Yue; Zhang, Deyuan

    2015-01-01

    The shark skin effect has attracted worldwide attention because of its superior drag reduction. As the product of natural selection, the maximum drag reduction of shark skin is found in its normal living environment. Large-proportional shrinkage of shark skin morphology is greatly anticipated for its adaptation to faster fluid flow. One novel approach, large-proportional shrunken bio-replication, is proposed as a method to adjust the optimal drag reduction region of shark skin based on the shrinkage of UV-cured material. The shark skin is taken as a replica template to allow large-proportional shrinking in the drag reduction morphology by taking advantage of the shrinkage of UV-curable material. The accuracy of the large-proportional shrunken bio-replication approach is verified by a comparison between original and shrunken bio-replicated shark skin, which shows that the shrinking ratio can reach 23% and the bio-replication accuracy is higher than 95%. In addition, the translation of the optimum drag reduction peak of natural surface function to various applications and environments is proved by drag reduction experiments. (technical note)

  16. Synthesis and Characterization of Bio-Oil Phenol Formaldehyde Resin Used to Fabricate Phenolic Based Materials.

    Science.gov (United States)

    Cui, Yong; Hou, Xiaopeng; Wang, Wenliang; Chang, Jianmin

    2017-06-18

    In this study, bio-oil from the fast pyrolysis of renewable biomass was used as the raw material to synthesize bio-oil phenol formaldehyde (BPF) resin-a desirable resin for fabricating phenolic-based material. During the synthesis process, paraformaldehyde was used to achieve the requirement of high solid content and low viscosity. The properties of BPF resins were tested. Results indicated that BPF resin with the bio-oil addition of 20% had good performance on oxygen index and bending strength, indicating that adding bio-oil could modify the fire resistance and brittleness of PF resin. The thermal curing behavior and heat resistance of BPF resins were investigated by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). Results showed that adding bio-oil had an impact on curing characteristics and thermal degradation process of PF resin, but the influence was insignificant when the addition was relatively low. The chemical structure and surface characteristics of BPF resins were determined by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). The analysis demonstrated that adding bio-oil in the amount of 20% was able to improve the crosslinking degree and form more hydrocarbon chains in PF resin.

  17. Synthesis and Characterization of Bio-Oil Phenol Formaldehyde Resin Used to Fabricate Phenolic Based Materials

    Directory of Open Access Journals (Sweden)

    Yong Cui

    2017-06-01

    Full Text Available In this study, bio-oil from the fast pyrolysis of renewable biomass was used as the raw material to synthesize bio-oil phenol formaldehyde (BPF resin—a desirable resin for fabricating phenolic-based material. During the synthesis process, paraformaldehyde was used to achieve the requirement of high solid content and low viscosity. The properties of BPF resins were tested. Results indicated that BPF resin with the bio-oil addition of 20% had good performance on oxygen index and bending strength, indicating that adding bio-oil could modify the fire resistance and brittleness of PF resin. The thermal curing behavior and heat resistance of BPF resins were investigated by differential scanning calorimetry (DSC and thermal gravimetric analysis (TGA. Results showed that adding bio-oil had an impact on curing characteristics and thermal degradation process of PF resin, but the influence was insignificant when the addition was relatively low. The chemical structure and surface characteristics of BPF resins were determined by Fourier transform infrared (FTIR spectroscopy and scanning electron microscopy (SEM. The analysis demonstrated that adding bio-oil in the amount of 20% was able to improve the crosslinking degree and form more hydrocarbon chains in PF resin.

  18. End-of-life care for immigrants in Germany. An epidemiological appraisal of Berlin.

    Science.gov (United States)

    Henke, Antje; Thuss-Patience, Peter; Behzadi, Asita; Henke, Oliver

    2017-01-01

    Since the late 1950's, a steadily increasing immigrant population in Germany is resulting in a subpopulation of aging immigrants. The German health care system needs to adjust its services-linguistically, culturally, and medically-for this subpopulation of patients. Immigrants make up over 20% of the population in Germany, yet the majority receive inadequate medical care. As many of the labor immigrants of the 1960s and 1970s are in need of hospice and palliative care (HPC), little is known about this specialized care for immigrants. This epidemiological study presents utilization of HPC facilities in Berlin with a focus on different immigrant groups. A validated questionnaire was used to collect data from patients at 34 HPC institutions in Berlin over 20 months. All newly admitted patients were recruited. Anonymized data were coded and analyzed by using SPSS and compared with the population statistics of Berlin. 4118 questionnaires were completed and included in the analysis. At 11.4% the proportion of immigrants accessing HPC was significantly (pimmigrants in Berlin population, 17.7% immigrants in HPC population) and 61-70 years (16,9% vs. 13,1%). The largest ethnic groups are Turks, Russians, and Poles, with a different weighting than in the general population: Turkish immigrants were 24% of all Berlin immigrants, but only 13.6% of the study immigrant population (OR: 0.23, 95%CI: 0.18-0.29, pimmigrants account for 5.6% and 9.2% in the population, but 11.5% and 24.8% in the study population respectively (Russian: OR 0.88, 95%CI: 0.66-1.16; Polish: OR 1.17, 95%CI: 0.97-1.42). Palliative care wards (PC) were used most often (16.7% immigrants of all PC patients); outpatient hospice services were used least often by immigrants (11.4%). Median age at first admission to HPC was younger in immigrants than non-immigrants: 61-70 vs. 71-80, p = 0.03. Immigrants are underrepresented in Berlin´s HPC and immigrants on average make use of care at a younger age than non

  19. [Leaking: Frequency and correlates of announcements and threats of homicidal violence reported by Berlin schools between 1996 and 2007].

    Science.gov (United States)

    Leuschner, Vincenz; Bondü, Rebecca; Allroggen, Marc; Scheithauer, Herbert

    2016-01-01

    Threats and announcements of homicidal violence at schools may have massive consequences like evacuations, police searches, criminal investigations, or loss of the sense of security by students, teachers, and parents. However, there is a lack of systematic studies about that phenomenon. The present article would like to contribute to closing the research gap. It presents results about the frequency and structure of threats and announcements of homicidal violence in schools in Berlin. The study is based on an official dataset from school administration reports of violent acts in Berlin schools which has been studied within the Berlin Leaking-Projekt. The sample consists of 427 threats and announcements of homicidal violence between 1996 and 2007. The study is an exceptional analysis of the phenomenon: it presents crosscutting results about frequency and characteristics of threats and the threatening students as well as results of a longitudinal analysis about the development of threats and announcements. Results show a rate of 0,3 threats and announcements per 1 000 student and year. During the observation time span a steady increase of threats and announcements – year by year, influenced by imitation effects after school shootings – has been observed.

  20. Bio-Based Nano Composites from Plant Oil and Nano Clay

    Science.gov (United States)

    Lu, Jue; Hong, Chang K.; Wool, Richard P.

    2003-03-01

    We explored the combination of nanoclay with new chemically functionalized, amphiphilic, plant oil resins to form bio-based nanocomposites with improved physical and mechanical properties. These can be used in many new applications, including the development of self-healing nanocomposites through controlled reversible exfoliation/intercalation, and self-assembled nano-structures. Several chemically modified triglyceride monomers of varying polarity, combined with styrene (ca 30include acrylated epoxidized soybean oil (AESO), maleated acrylated epoxidized soybean oil (MAESO) and soybean oil pentaerythritol glyceride maleates (SOPERMA), containing either hydroxyl group or acid functionality or both. The clay used is a natural montmorillonite modified with methyl tallow bis-2-hydroxyethyl quaternary ammonium chloride, which has hydroxyl groups. Both XRD and TEM showed a completely exfoliated structure at 3 wtwhen the clay content is above 5 wtconsidered a mix of intercalated and partially exfoliated structure. The controlled polarity of the monomer has a major effect on the reversible dispersion of clay in the polymer matrix. The bio-based nanocomposites showed a significant increase in flexural modulus and strength. Supported by EPA and DoE

  1. Efektifitas Penginduksi Resistensi dan Biopestisida terhadap Penyakit Bercak Daun Cercospora dan Antraknosa pada Cabai (Capsicum annuum L.

    Directory of Open Access Journals (Sweden)

    Bambang Heri Isnawan

    2014-08-01

    Full Text Available A research to confirm potential natural resources as an induced systemic resistance agent and bio- pesticide and it combination against Cercospora leaf spot and anthracnose on pepper. The research method was conducted by experiment on field, arranged in factorial design 3 x 5, arranged Randomized Completely Block Design with three replications as blocks. The First factor was inducer of resistance, consist of 3 levels i.e. non-inducer of resistance, inducer of resistance by Mirabilis jalapa and inducer of resistance by Amaranthus spinosus. The Second factor was bio-pesticide consist of 5 level i.e. non-bio-pesticide, bio-pesticide Amp, bio-pesticide Pfm001, bio-pesticide Amp+Pfm001 and chemical fungicide. The result of this research showed that inducer of resistance could suppressing damage fruit by anthracnose but could not influencing in Cercospora leafspot. Inducer of resistance could not be influencing growth of plant but could suppressing damage fruit volume and total damage fruit. Inducer of resistance i.e. Mirabilis jalapa and Amaranthus spinosus could suppressing damage fruit by anthracnose. Bio-pesticide could not be influencing in Cercospora leafspot but could suppressing anthracnose on pepper. Bio-pesticide could not be influencing the growth of pepper but could suppressing total damage fruit and damage fruit volume also increasing up the yield. There is no interaction between inducer of resistance and bio-pesticide through every parameter except for the area under diseases progress curve (AUDPC.

  2. Pesticide poisoning in Chitwan, Nepal: a descriptive epidemiological study

    Directory of Open Access Journals (Sweden)

    Deepak Gyenwali

    2017-07-01

    Full Text Available Abstract Background Globally, there is a growing concern over pesticides use, which has been linked to self-harm and suicide. However, there is paucity of research on the epidemiology of pesticides poisoning in Nepal. This study is aimed at assessing epidemiological features of pesticides poisoning among hospital-admitted cases in selected hospitals of Chitwan District of Nepal. Methods A hospital-based quantitative study was carried out in four major hospitals of Chitwan District. Information on all pesticides poisoning cases between April 1 and December 31, 2015, was recorded by using a Pesticides Exposure Record (PER form. Results A total of 439 acute pesticides poisoning cases from 12 districts including Chitwan and adjoining districts attended the hospitals during the 9-month-long study period. A majority of the poisoned subjects deliberately used pesticides (89.5% for attempted suicide. The total incidence rate was 62.67/100000 population per year. Higher annual incidence rates were found among young adults (111.66/100000 population, women (77.53/100000 population and individuals from Dalit ethnic groups (98.22/100000 population. Pesticides responsible for poisoning were mostly insecticides (58.0% and rodenticides (20.8%. The most used chemicals were organophosphates (37.3% and pyrethroids (36.7%. Of the total cases, 98.6% were hospitalized, with intensive care required for 41.3%. The case fatality rate among admitted cases was 3.8%. Conclusions This study has indicated that young adults, females and socially disadvantaged ethnic groups are at a higher risk of pesticides poisoning. Pesticides are mostly misused intentionally as an easy means for committing suicide. It is recommended that the supply of pesticides be properly regulated to prevent easy accessibility and misuse. A population-based study is warranted to reveal the actual problem of pesticides exposure and intoxication in the community.

  3. Review: Holger Stoecker: Afrikawissenschaften in Berlin von 1919 bis 1945. Zur Geschichte und Topographie eines wissenschaftlichen Netzwerkes (2008 Buchbesprechung: Holger Stoecker: Afrikawissenschaften in Berlin von 1919 bis 1945. Zur Geschichte und Topographie eines wissenschaftlichen Netzwerkes

    Directory of Open Access Journals (Sweden)

    Katrin Bromber

    2009-05-01

    Full Text Available Review of the monograph: Holger Stoecker: Afrikawissenschaften in Berlin von 1919 bis 1945. Zur Geschichte und Topographie eines wissenschaftlichen Netzwerkes, Stuttgart: Franz Steiner Verlag 2008, ISBN 978-3-515-09161-9, 359 pages. Besprechung der Monographie: Holger Stoecker: Afrikawissenschaften in Berlin von 1919 bis 1945. Zur Geschichte und Topographie eines wissenschaftlichen Netzwerkes, Stuttgart: Franz Steiner Verlag 2008, ISBN 978-3-515-09161-9, 359 Seiten.

  4. Nanotechnology-based polymeric bio(muco)adhesive platforms for controlling drug delivery - properties, methodologies and applications

    International Nuclear Information System (INIS)

    Carvalho, Flavia Chiva; Chorilli, Marlus; Gremiao, Maria Palmira Daflon

    2014-01-01

    Studies using bio(muco)adhesive drug delivery systems have recently gained great interest, which can promote drug targeting and more specific contact of the drug delivery system with the various absorptive membranes of the body. This technological platform associated with nanotechnology offers potential for controlling drug delivery; therefore, they are excellent strategies to increase the bioavailability of drugs. The objective of this work was to study nanotechnology-based polymeric bio(muco)adhesive platforms for controlling drug delivery, highlighting their properties, how the bio(muco)adhesion can be measured and their potential applications for different routes of administration. (author)

  5. Pesticide exposure - Indian scene

    International Nuclear Information System (INIS)

    Gupta, P.K.

    2004-01-01

    Use of pesticides in India began in 1948 when DDT was imported for malaria control and BHC for locust control. India started pesticide production with manufacturing plant for DDT and benzene hexachloride (BHC) (HCH) in the year 1952. In 1958, India was producing over 5000 metric tonnes of pesticides. Currently, there are approximately 145 pesticides registered for use, and production has increased to approximately 85,000 metric tonnes. Rampant use of these chemicals has given rise to several short-term and long-term adverse effects of these chemicals. The first report of poisoning due to pesticides in India came from Kerala in 1958 where, over 100 people died after consuming wheat flour contaminated with parathion. Subsequently several cases of pesticide-poisoning including the Bhopal disaster have been reported. Despite the fact that the consumption of pesticides in India is still very low, about 0.5 kg/ha of pesticides against 6.60 and 12.0 kg/ha in Korea and Japan, respectively, there has been a widespread contamination of food commodities with pesticide residues, basically due to non-judicious use of pesticides. In India, 51% of food commodities are contaminated with pesticide residues and out of these, 20% have pesticides residues above the maximum residue level values on a worldwide basis. It has been observed that their long-term, low-dose exposure are increasingly linked to human health effects such as immune-suppression, hormone disruption, diminished intelligence, reproductive abnormalities, and cancer. In this light, problems of pesticide safety, regulation of pesticide use, use of biotechnology, and biopesticides, and use of pesticides obtained from natural plant sources such as neem extracts are some of the future strategies for minimizing human exposure to pesticides

  6. Highly Branched Bio-Based Unsaturated Polyesters by Enzymatic Polymerization

    DEFF Research Database (Denmark)

    Nguyen, Hiep Dinh; Löf, David; Hvilsted, Søren

    2016-01-01

    A one-pot, enzyme-catalyzed bulk polymerization method for direct production of highly branched polyesters has been developed as an alternative to currently used industrial procedures. Bio-based feed components in the form of glycerol, pentaerythritol, azelaic acid, and tall oil fatty acid (TOFA)...... stability, very high water contact angles of up to 141° and a glass transition temperature that could be controlled through the feed composition....

  7. Increased incidence of cervical intraepithelial neoplasia in young women in the Mitte district, Berlin, Germany.

    Science.gov (United States)

    Blohmer, J U; Schmalisch, G; Klette, I; Grineisen, Y; Kohls, A; Guski, H; Lichtenegger, W

    1999-01-01

    To investigate whether the incidence of cervical intraepithelial neoplasia (CIN), in particular of high grade CIN, increased in Berlin during the period 1970-1989 and whether the ages of women with CIN had decreased. In the former German Democratic Republic, which had a highly centralized public health system, all gynecologic operations performed on women living in the Mitte district of Berlin were carried out during the period 1970-1989 (when the Berlin Wall fell) in the gynecologic clinic of the Charité Hospital. The incidence of all CIN increased from year to year over the observation period: 0.04% (1970-1971), 0.10% (1980-1981), 0.39% (1988-1989). There was a particularly high increase in the incidence of high grade intraepithelial neoplasms (CIN 3): 0.016% (1970-1971), 0.056% (1980-1981), 0.25% (1988-1989). With a virtually unchanged age distribution for women in the Mitte district of Berlin, the median age of women with CIN 3 decreased significantly from 1970 to 1989, from 39.5 (1970) to 33 (1989) (P < .001). The increase in the incidence of CIN, especially of high grade CIN, as well as the reduction in age for onset of the disease, makes high participation in screening necessary, above all among young women.

  8. Cascade use indicators for selected biopolymers: Are we aiming for the right solutions in the design for recycling of bio-based polymers?

    Science.gov (United States)

    Hildebrandt, Jakob; Bezama, Alberto; Thrän, Daniela

    2017-04-01

    When surveying the trends and criteria for the design for recycling (DfR) of bio-based polymers, priorities appear to lie in energy recovery at the end of the product life of durable products, such as bio-based thermosets. Non-durable products made of thermoplastic polymers exhibit good properties for material recycling. The latter commonly enjoy growing material recycling quotas in countries that enforce a landfill ban. Quantitative and qualitative indicators are needed for characterizing progress in the development towards more recycling friendly bio-based polymers. This would enable the deficits in recycling bio-based plastics to be tracked and improved. The aim of this paper is to analyse the trends in the DfR of bio-based polymers and the constraints posed by the recycling infrastructure on plastic polymers from a systems perspective. This analysis produces recommendations on how life cycle assessment indicators can be introduced into the dialogue between designers and recyclers in order to promote DfR principles to enhance the cascading use of bio-based polymers within the bioeconomy, and to meet circular economy goals.

  9. Cascade use indicators for selected biopolymers: Are we aiming for the right solutions in the design for recycling of bio-based polymers?

    Science.gov (United States)

    Hildebrandt, Jakob; Bezama, Alberto; Thrän, Daniela

    2017-01-01

    When surveying the trends and criteria for the design for recycling (DfR) of bio-based polymers, priorities appear to lie in energy recovery at the end of the product life of durable products, such as bio-based thermosets. Non-durable products made of thermoplastic polymers exhibit good properties for material recycling. The latter commonly enjoy growing material recycling quotas in countries that enforce a landfill ban. Quantitative and qualitative indicators are needed for characterizing progress in the development towards more recycling friendly bio-based polymers. This would enable the deficits in recycling bio-based plastics to be tracked and improved. The aim of this paper is to analyse the trends in the DfR of bio-based polymers and the constraints posed by the recycling infrastructure on plastic polymers from a systems perspective. This analysis produces recommendations on how life cycle assessment indicators can be introduced into the dialogue between designers and recyclers in order to promote DfR principles to enhance the cascading use of bio-based polymers within the bioeconomy, and to meet circular economy goals. PMID:28097922

  10. By bus and by train into the past. Berlin and its legacy in Annett Gröschner’s writing

    Directory of Open Access Journals (Sweden)

    Ewa Pytel-Bartnik

    2015-12-01

    Full Text Available This paper concentrates on the strategies of reconstructing the past as  inscribed into the urban space of Berlin and discussed within the literary field. Developed by the German writer Annett Gröschner, they have been used to reexamine the history of the city – only dimly reflected in the present urban landscape. Her perspective emphasizes the distinctive spatial and architectural organization of the city, particularly after the fall of the Berlin Wall. In order to harness her dialec-tical composition of the spacing of-the-past, Gröschner uses the map of various routes on the Berlin public transport network, some inner-city artefacts set along those lines, and also the city map with its constant modifications to create appropriate landmarks through which she [re]constructs Berlin's past-present.

  11. Cytotoxicity and mechanical behavior of chitin-bentonite clay based polyurethane bio-nanocomposites.

    Science.gov (United States)

    Zia, Khalid Mahmood; Zuber, Mohammad; Barikani, Mehdi; Hussain, Rizwan; Jamil, Tahir; Anjum, Sohail

    2011-12-01

    Chitin based polyurethane bio-nanocomposites (PUBNC) were prepared using chitin, Delite HPS bentonite nanoclay enriched in montmorillonite (MMT), 4,4'-diphenylmethane diisocyanate (MDI) and polycaprolactone polyol CAPA 231 (3000 g/mol(-1)). The prepolymers having different concentration of Delite HPS bentonite nanoclay were extended with 2 moles of chitin. The structures of the resulted polymers were determined by FT-IR technique. The effect of nanoclay contents on mechanical properties and in vitro biocompatibility was investigated. The mechanical properties of the synthesized materials were improved with increase in the Delite HPS bentonite nanoclay contents. Optimum mechanical properties were obtained from the PU bio-nanocomposite samples having 4% Delite HPS bentonite nanoclay. The results revealed that the final PU bio-nanocomposite having 2% Delite HPS bentonite nanoclay contents is ideal contenders for surgical threads with on going investigations into their in vitro biocompatibility, non-toxicity, and mechanical properties. Copyright © 2011 Elsevier B.V. All rights reserved.

  12. Berlin: A Model for the Teaching of Contemporary German Culture.

    Science.gov (United States)

    Jankowsky, Karen; Remmler, Karyn

    1987-01-01

    Presents the goals, procedures, visual aids, instructional materials used in a German conversation and culture class taught in English. The courses are intended to realistically portray the way of life and the environment of the people of East and West Berlin. (LMO)

  13. Polyvinylpyrrolidone-Based Bio-Ink Improves Cell Viability and Homogeneity during Drop-On-Demand Printing

    Directory of Open Access Journals (Sweden)

    Wei Long Ng

    2017-02-01

    Full Text Available Drop-on-demand (DOD bioprinting has attracted huge attention for numerous biological applications due to its precise control over material volume and deposition pattern in a contactless printing approach. 3D bioprinting is still an emerging field and more work is required to improve the viability and homogeneity of printed cells during the printing process. Here, a general purpose bio-ink was developed using polyvinylpyrrolidone (PVP macromolecules. Different PVP-based bio-inks (0%–3% w/v were prepared and evaluated for their printability; the short-term and long-term viability of the printed cells were first investigated. The Z value of a bio-ink determines its printability; it is the inverse of the Ohnesorge number (Oh, which is the ratio between the Reynolds number and a square root of the Weber number, and is independent of the bio-ink velocity. The viability of printed cells is dependent on the Z values of the bio-inks; the results indicated that the cells can be printed without any significant impairment using a bio-ink with a threshold Z value of ≤9.30 (2% and 2.5% w/v. Next, the cell output was evaluated over a period of 30 min. The results indicated that PVP molecules mitigate the cell adhesion and sedimentation during the printing process; the 2.5% w/v PVP bio-ink demonstrated the most consistent cell output over a period of 30 min. Hence, PVP macromolecules can play a critical role in improving the cell viability and homogeneity during the bioprinting process.

  14. BioGPS descriptors for rational engineering of enzyme promiscuity and structure based bioinformatic analysis.

    Directory of Open Access Journals (Sweden)

    Valerio Ferrario

    Full Text Available A new bioinformatic methodology was developed founded on the Unsupervised Pattern Cognition Analysis of GRID-based BioGPS descriptors (Global Positioning System in Biological Space. The procedure relies entirely on three-dimensional structure analysis of enzymes and does not stem from sequence or structure alignment. The BioGPS descriptors account for chemical, geometrical and physical-chemical features of enzymes and are able to describe comprehensively the active site of enzymes in terms of "pre-organized environment" able to stabilize the transition state of a given reaction. The efficiency of this new bioinformatic strategy was demonstrated by the consistent clustering of four different Ser hydrolases classes, which are characterized by the same active site organization but able to catalyze different reactions. The method was validated by considering, as a case study, the engineering of amidase activity into the scaffold of a lipase. The BioGPS tool predicted correctly the properties of lipase variants, as demonstrated by the projection of mutants inside the BioGPS "roadmap".

  15. Life cycle human health impacts of 875 pesticides

    DEFF Research Database (Denmark)

    Fantke, Peter; Jolliet, Oliver

    2016-01-01

    present a consistent framework for characterizing human toxicological impacts associated with pesticides applied to agricultural crops in the frame of life cycle impact assessment based on state-of-the-art data and methods. Methods We combine a dynamic multicrop plant uptake model designed for evaluating......-crop combinations of 10 orders of magnitude. Conclusions Our framework is operational for use in current life cycle impact assessment models, is made available for USEtox, and closes an important gap in the assessment of human exposure to pesticides. For ready use in life cycle assessment studies, we present...... pesticide-crop combination-specific characterization factors normalized to pesticide mass applied and provide default data for application times and loss due to post-harvest food processing. When using our data, we emphasize the need to consult current pesticide regulation, since each pesticide...

  16. [Acute respiratory distress syndrome: a review of the Berlin definition].

    Science.gov (United States)

    de Luis Cabezón, N; Sánchez Castro, I; Bengoetxea Uriarte, U X; Rodrigo Casanova, M P; García Peña, J M; Aguilera Celorrio, L

    2014-01-01

    Acute Respiratory Distress Syndrome (ARDS) is due to many causes. The absence of a universal definition up until now has led to a series of practical problems for a definitive diagnosis. The incidences of ARDS and Acute Lung Injury (ALI) vary widely in the current literature. The American-European Consensus Conference definition has been applied since its publication in 1994 and has helped to improve knowledge about ARDS. However, 18 years later, in 2011, the European Intensive Medicine Society, requested a team of international experts to meet in Berlin to review the ARDS definition. The purpose of the Berlin definition is not to use it as a prognostic tool, but to improve coherence between research and clinical practice. Copyright © 2013 Sociedad Española de Anestesiología, Reanimación y Terapéutica del Dolor. Published by Elsevier España. All rights reserved.

  17. Bio-based polyurethane composite foams with inorganic fillers studied by thermogravimetry

    International Nuclear Information System (INIS)

    Hatakeyema, Hyoe; Tanamachi, Noriko; Matsumura, Hiroshi; Hirose, Shigeo; Hatakeyama, Tatsuko

    2005-01-01

    Bio-based polyurethane (PU) composite foams filled with various inorganic fillers, such as barium sulfate (BaSO 4 ), calcium carbonate (CaCO 3 ) and talc were prepared using polyols, such as diethylene glycol, triethylene glycol and polyethylene glycol (molecular weight ca. 200) containing molasses and lignin. Reactive hydroxyl groups in plant components and above polyols were used as reaction sites. Morphological observation of fracture surface of composites was carried out by scanning electron microscopy. Thermal properties of bio-based PU composites were examined by thermogravimetry. It was found that the above composites decompose in two stages reflecting decomposition of organic components. Decomposition temperature increased with increasing filler content, when plant components were homogenously mixed with inorganic fillers. Activation energy calculated by Ozawa-Wall-Flynn method was ca. 150 kJ mol -1 . The durability of composites was predicted using kinetic data. Calculated values indicate that composites with fillers are more durable than that of those without fillers at a moderate temperature region

  18. Bio-fuel production potential in Romania

    International Nuclear Information System (INIS)

    Laurentiu, F.; Silvian, F.; Dumitru, F.

    2006-01-01

    The paper is based on the ESTO Study: Techno- Economic Feasibility of Large-Scale Production of Bio-Fuels in EU-Candidate Countries. Bio-fuel production has not been taken into account significantly until now in Romania, being limited to small- scale productions of ethanol, used mostly for various industrial purposes. However the climatic conditions and the quality of the soil are very suitable in the country for development of the main crops (wheat, sugar-beet, sunflower and rape-seed) used in bio-ethanol and bio-diesel production. The paper intended to consider a pertinent discussion of the present situation in Romania's agriculture stressing on the following essential items in the estimation of bio-fuels production potential: availability of feed-stock for bio-fuel production; actual productions of bio-fuels; fuel consumption; cost assessment; SWOT approach; expected trends. Our analysis was based on specific agricultural data for the period 1996-2000. An important ethanol potential (due to wheat, sugar-beet and maize cultures), as well as bio-diesel one (due to sun-flower and rape-seed) were predicted for the period 2005-2010 which could be exploited with the support of an important financial and technological effort, mainly from EU countries

  19. Die Berliner Schule der Ethnologie Ethnografie und Selbst-Ethnografie der Jahre 1978-1986 - The Berlin School of Ethnology. Ethnography and Self-Ethnography between 1978 and 1986

    Directory of Open Access Journals (Sweden)

    Antonio Luigi Palmisano

    2012-12-01

    Full Text Available Can we speak of a Berlin School of Anthropology? During the XXth century the Institut für Ethnologie of the Freien Universität had an intense research activity and a significant plurality of theoretical approaches. Particularly, at the end of the 70’s a wide group of researchers gathered in Berlin around the IfE. These scholars not only focused their attention on specific geographical areas (above all Northeast Africa and Central Asia but also developed common themes which led to the debate on the methodology and epistemology of Anthropology. Research activities catalysed around charismatic figures of German and European Anthropology and this led to the promotion of the idea of long-term fieldwork and to a particular attention to the critical definition of the qualities of ethnological knowledge. With the development and the application of the notion of imaginäre Ethnografie and with the theorization of the modified states of consciousness, the relationship between der Wissenschaftler und das Irrationale – to recall the title of a book published during those years – could finally be reconsidered in a continuous dialogue with researchers such as Hans Peter Duerr and Paul Feyerabend. This is how what I would like to define as “the Berlin stream of Anthropology” was born; and many scholars who later left the IfE for the wide world may or may not recognize themselves in it.

  20. Potsdamer Platz, Berlin - Autographic Experiences, cultural heritage and branded environments

    DEFF Research Database (Denmark)

    Allingham, Peter

    2009-01-01

    One of the main attractions found at Potsdamer Platz in Berlin is Sony Center, a "brandscape" that appeals and communicates to experientially and culturally minded audiences of citizens and tourists. Apart from commercial and cultural venues Sony Center contains apartments, numerous cafés...

  1. Hazard-ranking of agricultural pesticides for chronic health effects in Yuma County, Arizona.

    Science.gov (United States)

    Sugeng, Anastasia J; Beamer, Paloma I; Lutz, Eric A; Rosales, Cecilia B

    2013-10-01

    With thousands of pesticides registered by the United States Environmental Protection Agency, it not feasible to sample for all pesticides applied in agricultural communities. Hazard-ranking pesticides based on use, toxicity, and exposure potential can help prioritize community-specific pesticide hazards. This study applied hazard-ranking schemes for cancer, endocrine disruption, and reproductive/developmental toxicity in Yuma County, Arizona. An existing cancer hazard-ranking scheme was modified, and novel schemes for endocrine disruption and reproductive/developmental toxicity were developed to rank pesticide hazards. The hazard-ranking schemes accounted for pesticide use, toxicity, and exposure potential based on chemical properties of each pesticide. Pesticides were ranked as hazards with respect to each health effect, as well as overall chronic health effects. The highest hazard-ranked pesticides for overall chronic health effects were maneb, metam-sodium, trifluralin, pronamide, and bifenthrin. The relative pesticide rankings were unique for each health effect. The highest hazard-ranked pesticides differed from those most heavily applied, as well as from those previously detected in Yuma homes over a decade ago. The most hazardous pesticides for cancer in Yuma County, Arizona were also different from a previous hazard-ranking applied in California. Hazard-ranking schemes that take into account pesticide use, toxicity, and exposure potential can help prioritize pesticides of greatest health risk in agricultural communities. This study is the first to provide pesticide hazard-rankings for endocrine disruption and reproductive/developmental toxicity based on use, toxicity, and exposure potential. These hazard-ranking schemes can be applied to other agricultural communities for prioritizing community-specific pesticide hazards to target decreasing health risk. Copyright © 2013 Elsevier B.V. All rights reserved.

  2. Hazard-Ranking of Agricultural Pesticides for Chronic Health Effects in Yuma County, Arizona

    Science.gov (United States)

    Sugeng, Anastasia J.; Beamer, Paloma I.; Lutz, Eric A.; Rosales, Cecilia B.

    2013-01-01

    With thousands of pesticides registered by the United States Environmental Protection Agency, it not feasible to sample for all pesticides applied in agricultural communities. Hazard-ranking pesticides based on use, toxicity, and exposure potential can help prioritize community-specific pesticide hazards. This study applied hazard-ranking schemes for cancer, endocrine disruption, and reproductive/developmental toxicity in Yuma County, Arizona. An existing cancer hazard-ranking scheme was modified, and novel schemes for endocrine disruption and reproductive/developmental toxicity were developed to rank pesticide hazards. The hazard-ranking schemes accounted for pesticide use, toxicity, and exposure potential based on chemical properties of each pesticide. Pesticides were ranked as hazards with respect to each health effect, as well as overall chronic health effects. The highest hazard-ranked pesticides for overall chronic health effects were maneb, metam sodium, trifluralin, pronamide, and bifenthrin. The relative pesticide rankings were unique for each health effect. The highest hazard-ranked pesticides differed from those most heavily applied, as well as from those previously detected in Yuma homes over a decade ago. The most hazardous pesticides for cancer in Yuma County, Arizona were also different from a previous hazard-ranking applied in California. Hazard-ranking schemes that take into account pesticide use, toxicity, and exposure potential can help prioritize pesticides of greatest health risk in agricultural communities. This study is the first to provide pesticide hazard-rankings for endocrine disruption and reproductive/developmental toxicity based on use, toxicity, and exposure potential. These hazard-ranking schemes can be applied to other agricultural communities for prioritizing community-specific pesticide hazards to target decreasing health risk. PMID:23783270

  3. Editorial: from plant biotechnology to bio-based products.

    Science.gov (United States)

    Stöger, Eva

    2013-10-01

    From plant biotechnology to bio-based products - this Special Issue of Biotechnology Journal is dedicated to plant biotechnology and is edited by Prof. Eva Stöger (University of Natural Resources and Life Sciences, Vienna, Austria). The Special Issue covers a wide range of topics in plant biotechnology, including metabolic engineering of biosynthesis pathways in plants; taking advantage of the scalability of the plant system for the production of innovative materials; as well as the regulatory challenges and society acceptance of plant biotechnology. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Pesticide Program Dialogue Committee: Public Health Working Group

    Science.gov (United States)

    EPA formed this workgroup to assist in meeting its long-term goal of creating a publically-available framework that improves the reporting, quality and efficient use of pesticide incident data to ensure high-quality, science-based pesticide decisions.

  5. Functional and Morphological Evaluation of Traumatized Eyes With Berlin's Edema Affecting the Macula Using mfERG, Microperimetry, and SD-OCT.

    Science.gov (United States)

    Boss, Joseph Daniel; Tosi, Joaquin; Glybina, Inna; Tewari, Asheesh; Abrams, Gary W

    2017-02-01

    To describe the structural and functional changes that occur in traumatic Berlin's edema involving the macula through assessment with multifocal electroretinogram (mfERG), microperimetry, fundus photography, and spectral-domain optical coherence tomography (SD-OCT). Retrospective case series of five eyes from four patients with macular traumatic Berlin's edema. Patients underwent baseline mfERG (three eyes), MP1 microperimetry (three eyes), fundus photography (five eyes), and SD-OCT (five eyes). All eyes with Berlin's edema showed abnormal findings on baseline SD-OCT, including disruption and fragmentation of the inner segment/ outer segment layer. In two patients with unilateral blunt ocular trauma who underwent mfERG, there was complete loss of the foveal peak in affected eyes. All three eyes that underwent microperimetry showed depressed retinal sensitivity in the area of Berlin's edema. SD-OCT, microperimetry, and mfERG can be used to help diagnose, stratify traumatic severity, and follow structural and functional progression over time in patients with Berlin's edema. [Ophthalmic Surg Lasers Imaging Retina. 2017;48:114-121.]. Copyright 2017, SLACK Incorporated.

  6. Recovery based on plot experiments is a poor predictor of landscape-level population impacts of agricultural pesticides.

    Science.gov (United States)

    Topping, Christopher John; Kjaer, Lene Jung; Hommen, Udo; Høye, Toke Thomas; Preuss, Thomas G; Sibly, Richard M; van Vliet, Peter

    2014-07-01

    Current European Union regulatory risk assessment allows application of pesticides provided that recovery of nontarget arthropods in-crop occurs within a year. Despite the long-established theory of source-sink dynamics, risk assessment ignores depletion of surrounding populations and typical field trials are restricted to plot-scale experiments. In the present study, the authors used agent-based modeling of 2 contrasting invertebrates, a spider and a beetle, to assess how the area of pesticide application and environmental half-life affect the assessment of recovery at the plot scale and impact the population at the landscape scale. Small-scale plot experiments were simulated for pesticides with different application rates and environmental half-lives. The same pesticides were then evaluated at the landscape scale (10 km × 10 km) assuming continuous year-on-year usage. The authors' results show that recovery time estimated from plot experiments is a poor indicator of long-term population impact at the landscape level and that the spatial scale of pesticide application strongly determines population-level impact. This raises serious doubts as to the utility of plot-recovery experiments in pesticide regulatory risk assessment for population-level protection. Predictions from the model are supported by empirical evidence from a series of studies carried out in the decade starting in 1988. The issues raised then can now be addressed using simulation. Prediction of impacts at landscape scales should be more widely used in assessing the risks posed by environmental stressors. © 2014 SETAC.

  7. Prediction of climate impacts on pesticide leaching to the aquatic environments

    Energy Technology Data Exchange (ETDEWEB)

    Henriksen, Hans Joergen; Rosenbom, A.; van der Keur, P.; Kjaer, J.; Sonnenborg, T. [GEUS Danmark, Copenhagen (Denmark); Olesen, J.E. [Aarhus Univ., Tjele (Denmark); Nistrup Joergensen, L. [Aarhus Unv., Slagelse (Denmark); Boessing Christensen, O. [Danmarks Meteorologiske Institut (DMI), Copenhagen (Denmark)

    2013-10-01

    The report evaluates direct (precipitation, actual evapotranspiration and temperature) and indirect (crop rotations, crop management, and pesticide use) climatic change effects on pesticide-leaching to groundwater and the aquatic environment by use of MACRO and MIKE SHE model. The analysis is based on five model pesticides: low-dose herbicides, ordinary herbicides, strongly sorbing herbicides, fungicides and insecticides, and selected farm types (arable and dairy) for the variable saturated sandy soil (Jyndevad) and loamy soil (Faardrup). The evaluation has the aim at describing the implications of future climatic factors on pesticide leaching to groundwater as realistic as possible, based on realistic doses and parameters from MACRO setups from the Danish Pesticide Leaching Assessment Programme. (Author)

  8. An integrated (nano-bio) technique for degradation of γ-HCH contaminated soil

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Ritu [Ecotoxicology Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India); Analytical Chemistry Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India); Manickam, Natesan [Environmental Biotechnology Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India); Mudiam, Mohana Krishna Reddy [Analytical Chemistry Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India); Murthy, Ramesh Chandra, E-mail: murthyrc729@gmail.com [Analytical Chemistry Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India); Misra, Virendra, E-mail: virendra_misra2001@yahoo.co.in [Ecotoxicology Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India)

    2013-08-15

    Highlights: • An integrated (nano-bio) technique is employed to degrade γ-HCH in soil. • Degradation efficiency of γ-HCH in integrated and individual systems is compared. • Synergistic effect was noticed on γ-HCH degradation in integrated system. • Integrated system was found 1.7–2.1 times more efficient than individual methods. • This technique could be exploited for other chlorinated pesticides as well. -- Abstract: We have evaluated the effect of an integrated (nano-bio) technique involving the use of stabilized Pd/Fe{sup 0} bimetallic nanoparticles (CMC-Pd/nFe{sup 0}) and a Sphingomonas sp. strain NM05, on the degradation of γ-HCH in soil. Factors affecting degradation such as pH, incubation temperature and γ-HCH initial concentration were also studied. The results revealed that γ-HCH degradation efficiency is ∼ 1.7–2.1 times greater in integrated system as compared to system containing either NM05 or CMC-Pd/nFe{sup 0} alone. The integration showed synergistic effect on γ-HCH degradation. Further, cell growth studies indicated that NM05 gets well acclimatized to nanoparticles, showing potential growth in the presence of CMC-Pd/nFe{sup 0} with respect to control system. This study signifies the potential efficacy of integrated technique to become an effective alternative remedial tool for γ-HCH contaminated soil. Further research in this direction could lead to the development of effective remediation strategies for other isomers of HCH and other chlorinated pesticides as well.

  9. Pattern of pesticide storage before pesticide self-poisoning in rural Sri Lanka

    DEFF Research Database (Denmark)

    Mohamed, Fahim; Manuweera, Gamini; Gunnell, David

    2009-01-01

    BACKGROUND: Deliberate self-poisoning with agricultural pesticides is the commonest means of suicide in rural Asia. It is mostly impulsive and facilitated by easy access to pesticides. The aim of this large observational study was to investigate the immediate source of pesticides used for self......-harm to help inform suicide prevention strategies such as reducing domestic access to pesticides. METHODS: The study was conducted in a district hospital serving an agricultural region of Sri Lanka. Patients who had self-poisoned with pesticides and were admitted to the adult medical wards were interviewed...... the particular pesticide for self-harm were its easy accessibility (n = 311, 46%) or its popularity as a suicide agent in their village (n = 290, 43%). CONCLUSION: Three quarters of people who ingested pesticides in acts of self-harm used products that were available within the home or in close proximity...

  10. Cell Deformation in Cancer Metastasis: a BioMEMS Based Approach

    Energy Technology Data Exchange (ETDEWEB)

    Manimaran, M [Department of Medical Devices, Institute of Bioengineering and Nanotechnology (IBN) - A-STAR, 31 Biopolis Way, Nanos 04-01, Singapore 138669 (Singapore); Tay, Francis E H [Department of Medical Devices, Institute of Bioengineering and Nanotechnology (IBN) - A-STAR, 31 Biopolis Way, Nanos 04-01, Singapore 138669 (Singapore); NUS - Department of Mechanical Engineering, Singapore 117576., Department of Medical Devices, Institute of Bioengineering and Nanotechnology, 31 Biopolis way, 04-01 Nanos, Singapore 138669 (Singapore); Chaw, K C [Department of Medical Devices, Institute of Bioengineering and Nanotechnology (IBN) - A-STAR, 31 Biopolis Way, Nanos 04-01, Singapore 138669 (Singapore)

    2006-04-01

    Here we report a BioMEMS based microfluidic device as a deformation assay to study the deformability and growth capability of cells through microgaps. The micro-gaps are ranging from 3{mu}m to 30{mu}m with three microchannels parallel to each other to mimic the blood vessel bio-microenvironment. Flow conditions in the device can be controlled to have an environment as similar to that in vivo as possible. We used osteoblast cells with approximate size of 30 {mu}m as a model cell to study the deformation ability of this cell to migrate through the 3 {mu}m gap. Such a device enabled us, for the first time to measure the cell deformation with ease. More importantly, we are able to observe the cellular responses to gaps present in the device and understand the mechanics behind the morphological change of the cells.

  11. Five years of proton therapy of tumours of the eye at Hahn-Meitner Institute, Berlin

    International Nuclear Information System (INIS)

    Heufelder, J.; Cordini, D.; Heese, J.; Homeyer, H.; Kluge, H.; Morgenstern, H.; Fuchs, H.; Hoecht, S.; Nausner, M.; Hinkelbein, W.; Bechrakis, N.E.; Foerster, M.H.

    2004-01-01

    Eye tumors (choroidal melanomas, iris melanomas, and choroidal hemangiomas) are being treated with 68 MeV protons since 1998 at the Ion Beam Laboratory of the Hahn-Meitner Institute of Berlin (Germany's first proton therapy center), in cooperation with the Charite University Hospital in Berlin, Campus Benjamin Franklin. The proton beam, generated via a combination of Van de Graaff accelerator and cyclotron, is prepared by passive shaping for conformal tumor irradiation. A digital X-ray verification of the tumor location with the patient in sitting position limits the position uncertainties to a maximum of 0,3 mm. The treatment planning is performed using the program EYEPLAN. OCTOPUS, a CT-based planning program developed in cooperation with the German Cancer Research Center of Heidelberg, is under pre-clinical testing. Thus far, more than 400 patients have been irradiated. The first results are comparable to those obtained in other proton therapy centers. At the end of 2002, the University Hospital of Essen has also become a cooperation partner of the Hahn-Meitner Institute. (orig.) [de

  12. Maxillary sinus floor augmentation with Bio-Oss or Bio-Oss mixed with autogenous bone as graft in animals

    DEFF Research Database (Denmark)

    Jensen, T; Schou, S; Stavropoulos, Andreas

    2012-01-01

    The objective of the present systematic review was to test the hypothesis of no differences between the use of Bio-Oss or Bio-Oss mixed with autogenous bone as graft for maxillary sinus floor augmentation (MSFA) applying the lateral window technique, as evaluated in animals. A MEDLINE (Pub...... of the graft improved significantly with increased proportion of Bio-Oss. Bone regeneration, bone-to-implant contact (BIC), biomechanical implant test values, and biodegradation of Bio-Oss after MSFA with Bio-Oss or Bio-Oss mixed with autogenous bone have never been compared within the same study in animals....... Thus, the hypothesis of no differences between the use of Bio-Oss and Bio-Oss mixed with autogenous bone as graft for MSFA could neither be confirmed nor rejected based on existing animal studies....

  13. Sustainability of biomass in a bio-based economy. A quick-scan analysis of the biomass demand of a bio-based economy in 2030 compared to the sustainable supply

    Energy Technology Data Exchange (ETDEWEB)

    Ros, J.; Olivier, J.; Notenboom, J. [Netherlands Environmental Assessment Agency PBL, Bilthoven (Netherlands); Croezen, H.; Bergsma, G. [CE Delft, Delft (Netherlands)

    2012-02-15

    The conversion of a fossil fuel-based economy into a bio-based economy will probably be restricted in the European Union (EU) by the limited supply of ecologically sustainable biomass. It appears realistic that, for the EU, the sustainable biomass supply will be enough to meet about 10% of the final energy and feedstock consumption in 2030. Under optimistic assumptions, this supply might increase to 20%. EU Member States, in their Renewable Energy Action Plans for 2020, already aim to apply an amount of biomass that already approaches this 10%. Therefore, from a sustainability perspective, there is an urgent need to guarantee ecologically sustainable biomass production. In considering sustainable biomass production, land use is the most critical issue, especially the indirect land-use impacts on greenhouse gas emissions and biodiversity. The use of waste resources and agricultural and forestry residues, that does not involve additional land use, therefore, would be a sustainable option. Technically, it is possible to use these types of resources for most applications in a bio-based economy. However, it seems unlikely that, by 2030, waste and residue resources will contribute more than three to four per cent to the final energy and feedstock consumption in Europe. Moreover, many waste and residue resources currently already have useful applications; for instance, as feed or soil improvers. These are the main findings of a quick-scan analysis carried out by the PBL Netherlands Environmental Assessment Agency and CE Delft on the sustainability of a bio-based economy. Three priorities can be distinguished in the transition to an ecologically sustainable bio-based economy that aims to reduce the consumption of fossil fuels: (1) develop new technologies, procedures and infrastructure to collect or to produce more biomass without using directly or indirectly valuable natural land; (2) develop technologies to produce hydrocarbons from types of biomass that have potentially

  14. "We Learned What Democracy Really Meant": The Berlin Student Parliament and Postwar School Reform in the 1950s

    Science.gov (United States)

    Puaca, Brian M.

    2005-01-01

    In this paper, the author highlights the Berlin Student Parliament and assesses educational innovations of the postwar era. The Berlin Student Parliament is but one example of the postwar pedagogical and curricular initiatives that sought to prepare West German pupils for their responsibilities in the new democracy. The organization believe that…

  15. Social Life Cycle Approach as a Tool for Promoting the Market Uptake of Bio-Based Products from a Consumer Perspective

    Directory of Open Access Journals (Sweden)

    Pasquale Marcello Falcone

    2018-03-01

    Full Text Available The sustainability of bio-based products, especially when compared with fossil based products, must be assured. The life cycle approach has proven to be a promising way to analyze the social, economic and environmental impacts of bio-based products along the whole value chain. Until now, however, the social aspects have been under-investigated in comparison to environmental and economic aspects. In this context, the present paper aims to identify the main social impact categories and indicators that should be included in a social sustainability assessment of bio-based products, with a focus on the consumers’ category. To identify which social categories and indicators are most relevant, we carry out a literature review on existing social life cycle studies; this is followed by a focus group with industrial experts and academics. Afterwards, we conduct semi-structured interviews with some consumer representatives to understand which social indicators pertaining to consumers are perceived as relevant. Our findings highlight the necessity for the development and dissemination of improved frameworks capable of exploiting the consumers’ role in the ongoing process of market uptake of bio-based products. More specifically, this need regards the effective inclusion of some social indicators (i.e., end users’ health and safety, feedback mechanisms, transparency, and end-of-life responsibility in the social life cycle assessment scheme for bio-based products. This would allow consumers, where properly communicated, to make more informed and aware purchasing choices, therefore having a flywheel effect on the market diffusion of a bio-based product.

  16. Photobiology of Symbiodinium revisited: bio-physical and bio-optical signatures

    Science.gov (United States)

    Hennige, S. J.; Suggett, D. J.; Warner, M. E.; McDougall, K. E.; Smith, D. J.

    2009-03-01

    Light is often the most abundant resource within the nutrient-poor waters surrounding coral reefs. Consequently, zooxanthellae ( Symbiodinium spp.) must continually photoacclimate to optimise productivity and ensure coral success. In situ coral photobiology is becoming dominated by routine assessments using state-of-the-art non-invasive bio-optical or chlorophyll a fluorescence (bio-physical) techniques. Multiple genetic types of Symbiodinium are now known to exist; however, little focus has been given as to how these types differ in terms of characteristics that are observable using these techniques. Therefore, this investigation aimed to revisit and expand upon a pivotal study by Iglesias-Prieto and Trench (1994) by comparing the photoacclimation characteristics of different Symbiodinium types based on their bio-physical (chlorophyll a fluorescence, reaction centre counts) and bio-optical (optical absorption, pigment concentrations) ‘signatures’. Signatures described here are unique to Symbiodinium type and describe phenotypic responses to set conditions, and hence are not suitable to describe taxonomic structure of in hospite Symbiodinium communities. In this study, eight Symbiodinium types from clades and sub-clades (A-B, F) were grown under two PFDs (Photon Flux Density) and examined. The photoacclimation response by Symbiodinium was highly variable between algal types for all bio-physical and for many bio-optical measurements; however, a general preference to modifying reaction centre content over effective antennae-absorption was observed. Certain bio-optically derived patterns, such as light absorption, were independent of algal type and, when considered per photosystem, were matched by reaction centre stoichiometry. Only by better understanding genotypic and phenotypic variability between Symbiodinium types can future studies account for the relative taxonomic and physiological contribution by Symbiodinium to coral acclimation.

  17. Measuring Rice Farmer’s Pesticide Overuse Practice and the Determinants: A Statistical Analysis Based on Data Collected in Jiangsu and Anhui Provinces of China

    Directory of Open Access Journals (Sweden)

    Jianhua Wang

    2018-03-01

    Full Text Available Understanding the extent of pesticide overuse and what drives rice farmers to overuse pesticide in agricultural production theoretically and empirically is imperative to increase farmers’ income, promote agricultural transformation and agricultural sustainable development. In this paper, we examined the phenomenon and pattern of pesticides overuse based on the data collected from 861 rice farmers in Jiangsu and Anhui, two provinces in China. By applying the Cobb-Douglas production function (C-D production function and the damage control model, we estimated the marginal productivity of pesticides. We also adopted the Binary Probit model to further explore factors leading to overuse of pesticide among farmers. Our findings suggested that the marginal productivity of pesticides is close to zero, indicating that there is an excessive use of pesticides in the surveyed areas. According to the Binary Probit model, we also discovered that female farmers, farmers with knowledge about pesticide toxicity, pesticide residue and farmers who hold the view that massive use of pesticide is inimical to the environment, and farmers who participate in pesticide training organized by the government, are more likely to overuse pesticide. On the contrary, experienced farmers have a lower chance of overusing pesticides. Possible explanations to the above findings may be that applying pesticides in accordance with the instructions causes overusing and farmers who are loss-averse, in order to avoid the risk of income loss that may be caused by disease and insect pests, and keep its own income stable, will still increase the amount of pesticide application. It also indicates that farmers are insensitive to increased pesticide overuse.

  18. Progress on Azadirachta indica Based Biopesticides in Replacing Synthetic Toxic Pesticides.

    Science.gov (United States)

    Chaudhary, Suman; Kanwar, Rupinder K; Sehgal, Alka; Cahill, David M; Barrow, Colin J; Sehgal, Rakesh; Kanwar, Jagat R

    2017-01-01

    Over the years, extensive use of commercially available synthetic pesticides against phytophagous insects has led to their bioaccumulation in the environment causing increased resistance and reduction in soil biodiversity. Further, 90% of the applied pesticides enter the various environmental resources as a result of run-off, exposing the farmers as well as consumers of the agricultural produce to severe health issues. Therefore, growing attention has been given toward the development of alternate environmentally friendly pesticides/insecticides that would aid an efficient pest management system and also prevent chronic exposures leading to diseases. One such strategy is, the use of neem plant's (Binomial name: Azadirachta indica ) active ingredients which exhibit agro-medicinal properties conferring insecticidal as well as immunomodulatory and anti-cancer properties. The most prominent constituent of neem is azadirachtin, which has been established as a pivotal insecticidal ingredient. It acts as an antifeedant, repellent, and repugnant agent and induces sterility in insects by preventing oviposition and interrupting sperm production in males. This review discusses, key neem pesticidal components, their active functional ingredients along with recent strategies on employing nanocarriers, to provide controlled release of the active ingredients and to improve their stability and sustainability.

  19. Comparative Probabilistic Assessment of Occupational Pesticide Exposures Based on Regulatory Assessments

    Science.gov (United States)

    Pouzou, Jane G.; Cullen, Alison C.; Yost, Michael G.; Kissel, John C.; Fenske, Richard A.

    2018-01-01

    Implementation of probabilistic analyses in exposure assessment can provide valuable insight into the risks of those at the extremes of population distributions, including more vulnerable or sensitive subgroups. Incorporation of these analyses into current regulatory methods for occupational pesticide exposure is enabled by the exposure data sets and associated data currently used in the risk assessment approach of the Environmental Protection Agency (EPA). Monte Carlo simulations were performed on exposure measurements from the Agricultural Handler Exposure Database and the Pesticide Handler Exposure Database along with data from the Exposure Factors Handbook and other sources to calculate exposure rates for three different neurotoxic compounds (azinphos methyl, acetamiprid, emamectin benzoate) across four pesticide-handling scenarios. Probabilistic estimates of doses were compared with the no observable effect levels used in the EPA occupational risk assessments. Some percentage of workers were predicted to exceed the level of concern for all three compounds: 54% for azinphos methyl, 5% for acetamiprid, and 20% for emamectin benzoate. This finding has implications for pesticide risk assessment and offers an alternative procedure that may be more protective of those at the extremes of exposure than the current approach. PMID:29105804

  20. Comparative Probabilistic Assessment of Occupational Pesticide Exposures Based on Regulatory Assessments.

    Science.gov (United States)

    Pouzou, Jane G; Cullen, Alison C; Yost, Michael G; Kissel, John C; Fenske, Richard A

    2017-11-06

    Implementation of probabilistic analyses in exposure assessment can provide valuable insight into the risks of those at the extremes of population distributions, including more vulnerable or sensitive subgroups. Incorporation of these analyses into current regulatory methods for occupational pesticide exposure is enabled by the exposure data sets and associated data currently used in the risk assessment approach of the Environmental Protection Agency (EPA). Monte Carlo simulations were performed on exposure measurements from the Agricultural Handler Exposure Database and the Pesticide Handler Exposure Database along with data from the Exposure Factors Handbook and other sources to calculate exposure rates for three different neurotoxic compounds (azinphos methyl, acetamiprid, emamectin benzoate) across four pesticide-handling scenarios. Probabilistic estimates of doses were compared with the no observable effect levels used in the EPA occupational risk assessments. Some percentage of workers were predicted to exceed the level of concern for all three compounds: 54% for azinphos methyl, 5% for acetamiprid, and 20% for emamectin benzoate. This finding has implications for pesticide risk assessment and offers an alternative procedure that may be more protective of those at the extremes of exposure than the current approach. © 2017 Society for Risk Analysis.

  1. Progress on Azadirachta indica Based Biopesticides in Replacing Synthetic Toxic Pesticides

    Directory of Open Access Journals (Sweden)

    Suman Chaudhary

    2017-05-01

    Full Text Available Over the years, extensive use of commercially available synthetic pesticides against phytophagous insects has led to their bioaccumulation in the environment causing increased resistance and reduction in soil biodiversity. Further, 90% of the applied pesticides enter the various environmental resources as a result of run-off, exposing the farmers as well as consumers of the agricultural produce to severe health issues. Therefore, growing attention has been given toward the development of alternate environmentally friendly pesticides/insecticides that would aid an efficient pest management system and also prevent chronic exposures leading to diseases. One such strategy is, the use of neem plant's (Binomial name: Azadirachta indica active ingredients which exhibit agro-medicinal properties conferring insecticidal as well as immunomodulatory and anti-cancer properties. The most prominent constituent of neem is azadirachtin, which has been established as a pivotal insecticidal ingredient. It acts as an antifeedant, repellent, and repugnant agent and induces sterility in insects by preventing oviposition and interrupting sperm production in males. This review discusses, key neem pesticidal components, their active functional ingredients along with recent strategies on employing nanocarriers, to provide controlled release of the active ingredients and to improve their stability and sustainability.

  2. Progress on Azadirachta indica Based Biopesticides in Replacing Synthetic Toxic Pesticides

    Science.gov (United States)

    Chaudhary, Suman; Kanwar, Rupinder K.; Sehgal, Alka; Cahill, David M.; Barrow, Colin J.; Sehgal, Rakesh; Kanwar, Jagat R.

    2017-01-01

    Over the years, extensive use of commercially available synthetic pesticides against phytophagous insects has led to their bioaccumulation in the environment causing increased resistance and reduction in soil biodiversity. Further, 90% of the applied pesticides enter the various environmental resources as a result of run-off, exposing the farmers as well as consumers of the agricultural produce to severe health issues. Therefore, growing attention has been given toward the development of alternate environmentally friendly pesticides/insecticides that would aid an efficient pest management system and also prevent chronic exposures leading to diseases. One such strategy is, the use of neem plant's (Binomial name: Azadirachta indica) active ingredients which exhibit agro-medicinal properties conferring insecticidal as well as immunomodulatory and anti-cancer properties. The most prominent constituent of neem is azadirachtin, which has been established as a pivotal insecticidal ingredient. It acts as an antifeedant, repellent, and repugnant agent and induces sterility in insects by preventing oviposition and interrupting sperm production in males. This review discusses, key neem pesticidal components, their active functional ingredients along with recent strategies on employing nanocarriers, to provide controlled release of the active ingredients and to improve their stability and sustainability. PMID:28533783

  3. Pesticide poisoning in the developing world--a minimum pesticides list

    DEFF Research Database (Denmark)

    Eddleston, Michael; Karalliedde, Lakshman; Buckley, Nick

    2002-01-01

    In parts of the developing world, pesticide poisoning causes more deaths than infectious diseases. Use of pesticides is poorly regulated and often dangerous; their easy availability also makes them a popular method of self-harm. In 1985, the UN Food and Agriculture Organisation (FAO) produced...... a voluntary code of conduct for the pesticide industry in an attempt to limit the harmful effects of pesticides. Unfortunately, a lack of adequate government resources in the developing world makes this code ineffective, and thousands of deaths continue today. WHO has recommended that access to highly toxic...... to do specific tasks within an integrated pest management system. Use of safer pesticides should result in fewer deaths, just as the change from barbiturates to benzodiazepines has reduced the number of deaths from pharmaceutical self-poisoning....

  4. BioMeeT. Planning of biomass based methanol energy combine - Trollhaettan region. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Brandberg, Aake; Hjortsberg, Hans; Saevbark, Bengt [Ecotraffic R and D AB, Stockholm (Sweden); Ekbom, Tomas; Hjerpe, Carl-Johan; Landaelv, Ingvar [Nykomb Synergetics AB, Stockholm (Sweden)

    2000-04-01

    The conversion of biomass in an energy combine based on primary gasification yields a gas that can be used as fuels gas, for synthesis of motor fuels (methanol or other) or for electric power production. The study gives examples of alternative product mixes. The conclusions of the study are: (1) Potential of new, not yet utilised biomass is available, and new areas of applications, where oil is presently used, are needed to develop the potential. Motor fuel production (methanol, DME) is a presumption in the BioMeeT-study. (2) Yield figures in the energy combine are comparable to those of now used bio-systems for power and co-generation. (3) Which one of the cases in the BioMeeT-project is the most favourable cannot be decided on a plant-to-plant basis alone but the entire system for supply energy carriers in the region has to be considered, as the all plants within the system may change. This would require further investigations. Moreover, the results will be different in various regions in Sweden and Europe due to the markets for all energy carriers. (4) At today's conditions in the Trollhaettan region it must be stated that there is only room for dedicated bio-methanol/DME production (provided such a market will come) with moderate addition to the district heating system as in the BAL-project. (5) In the longer term the future supply of all energy carriers, including new electric power and new bio-fuels, has to be considered for new plants and at renewals. In such a case an energy combine as in the BioMeeT-project may be a central conversion plant with gas deliveries to satellites such as local co-generation, district heat and industries in a regional system within a 50 - 100 km radius. This should be included in regional planning for the future. (6) Estimated investment costs per kW feedstock input is higher for the energy combine compared to present technologies (mature technologies for power and heat) but have to be judged for all plants taken together in

  5. BioMeeT. Planning of biomass based methanol energy combine - Trollhaettan region. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Brandberg, Aake; Hjortsberg, Hans; Saevbark, Bengt [Ecotraffic R and D AB, Stockholm (Sweden); Ekbom, Tomas; Hjerpe, Carl-Johan; Landaelv, Ingvar [Nykomb Synergetics AB, Stockholm (Sweden)

    2000-04-01

    The conversion of biomass in an energy combine based on primary gasification yields a gas that can be used as fuels gas, for synthesis of motor fuels (methanol or other) or for electric power production. The study gives examples of alternative product mixes. The conclusions of the study are: (1) Potential of new, not yet utilised biomass is available, and new areas of applications, where oil is presently used, are needed to develop the potential. Motor fuel production (methanol, DME) is a presumption in the BioMeeT-study. (2) Yield figures in the energy combine are comparable to those of now used bio-systems for power and co-generation. (3) Which one of the cases in the BioMeeT-project is the most favourable cannot be decided on a plant-to-plant basis alone but the entire system for supply energy carriers in the region has to be considered, as the all plants within the system may change. This would require further investigations. Moreover, the results will be different in various regions in Sweden and Europe due to the markets for all energy carriers. (4) At today's conditions in the Trollhaettan region it must be stated that there is only room for dedicated bio-methanol/DME production (provided such a market will come) with moderate addition to the district heating system as in the BAL-project. (5) In the longer term the future supply of all energy carriers, including new electric power and new bio-fuels, has to be considered for new plants and at renewals. In such a case an energy combine as in the BioMeeT-project may be a central conversion plant with gas deliveries to satellites such as local co-generation, district heat and industries in a regional system within a 50 - 100 km radius. This should be included in regional planning for the future. (6) Estimated investment costs per kW feedstock input is higher for the energy combine compared to present technologies (mature technologies for power and heat) but have to be judged for all plants taken together in the

  6. Bio-inspired networking

    CERN Document Server

    Câmara, Daniel

    2015-01-01

    Bio-inspired techniques are based on principles, or models, of biological systems. In general, natural systems present remarkable capabilities of resilience and adaptability. In this book, we explore how bio-inspired methods can solve different problems linked to computer networks. Future networks are expected to be autonomous, scalable and adaptive. During millions of years of evolution, nature has developed a number of different systems that present these and other characteristics required for the next generation networks. Indeed, a series of bio-inspired methods have been successfully used to solve the most diverse problems linked to computer networks. This book presents some of these techniques from a theoretical and practical point of view. Discusses the key concepts of bio-inspired networking to aid you in finding efficient networking solutions Delivers examples of techniques both in theoretical concepts and practical applications Helps you apply nature's dynamic resource and task management to your co...

  7. A systems-level approach for investigating organophosphorus pesticide toxicity.

    Science.gov (United States)

    Zhu, Jingbo; Wang, Jing; Ding, Yan; Liu, Baoyue; Xiao, Wei

    2018-03-01

    The full understanding of the single and joint toxicity of a variety of organophosphorus (OP) pesticides is still unavailable, because of the extreme complex mechanism of action. This study established a systems-level approach based on systems toxicology to investigate OP pesticide toxicity by incorporating ADME/T properties, protein prediction, and network and pathway analysis. The results showed that most OP pesticides are highly toxic according to the ADME/T parameters, and can interact with significant receptor proteins to cooperatively lead to various diseases by the established OP pesticide -protein and protein-disease networks. Furthermore, the studies that multiple OP pesticides potentially act on the same receptor proteins and/or the functionally diverse proteins explained that multiple OP pesticides could mutually enhance toxicological synergy or additive on a molecular/systematic level. To the end, the integrated pathways revealed the mechanism of toxicity of the interaction of OP pesticides and elucidated the pathogenesis induced by OP pesticides. This study demonstrates a systems-level approach for investigating OP pesticide toxicity that can be further applied to risk assessments of various toxins, which is of significant interest to food security and environmental protection. Copyright © 2017 Elsevier Inc. All rights reserved.

  8. Temperature effect on the physico-chemical properties of silica based bio-hybrid composite for uranium uptake

    International Nuclear Information System (INIS)

    Mishra, Archana; Melo, Jose Savio

    2013-01-01

    In the present work, silica based bio-hybrid composite has been prepared using Streptococcus lactis cells and silica nanoparticles through one step single process of spray drying. Bio-hybrids have many desired characteristics, and are thus used in a wide range of applications for example environmental cleanup which is of increasing importance. Thermogravimetric and thermodynamic analysis have been employed to understand the binding of uranium to the synthesized bio-hybrid material. Analysis of the thermodynamic parameters (ΔG 0 , ΔS 0 and ΔH 0 ) provides information regarding the inherent energy and feasibility of the sorption process. (author)

  9. Acoustic performance and microstructural analysis of bio-based lightweight concrete containing miscanthus

    NARCIS (Netherlands)

    Chen, Yuxuan; Yu, Q. L.; Brouwers, H. J.H.

    2017-01-01

    Miscanthus Giganteus (i.e. Elephant Grass) is a cost-effective and extensively available ecological resource in many agricultural regions. This article aims at a fundamental research on a bio-based lightweight concrete using miscanthus as aggregate, i.e. miscanthus lightweight concrete (MLC), with

  10. “Turn-off” fluorescent data array sensor based on double quantum dots coupled with chemometrics for highly sensitive and selective detection of multicomponent pesticides

    Energy Technology Data Exchange (ETDEWEB)

    Fan, Yao; Liu, Li; Sun, Donglei; Lan, Hanyue [The Modernization Engineering Technology Research Center of Ethnic Minority Medicine of Hubei Province, College of Pharmacy, South-Central University for Nationalities, Wuhan 430074 (China); Fu, Haiyan, E-mail: fuhaiyan@mail.scuec.edu.cn [The Modernization Engineering Technology Research Center of Ethnic Minority Medicine of Hubei Province, College of Pharmacy, South-Central University for Nationalities, Wuhan 430074 (China); Yang, Tianming, E-mail: tmyang@mail.scuec.edu.cn [The Modernization Engineering Technology Research Center of Ethnic Minority Medicine of Hubei Province, College of Pharmacy, South-Central University for Nationalities, Wuhan 430074 (China); She, Yuanbin, E-mail: sheyb@zjut.edu.cn [State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310032 (China); Ni, Chuang [The Modernization Engineering Technology Research Center of Ethnic Minority Medicine of Hubei Province, College of Pharmacy, South-Central University for Nationalities, Wuhan 430074 (China)

    2016-04-15

    As a popular detection model, the fluorescence “turn-off” sensor based on quantum dots (QDs) has already been successfully employed in the detections of many materials, especially in the researches on the interactions between pesticides. However, the previous studies are mainly focused on simple single track or the comparison based on similar concentration of drugs. In this work, a new detection method based on the fluorescence “turn-off” model with water-soluble ZnCdSe and CdSe QDs simultaneously as the fluorescent probes is established to detect various pesticides. The fluorescence of the two QDs can be quenched by different pesticides with varying degrees, which leads to the differences in positions and intensities of two peaks. By combining with chemometrics methods, all the pesticides can be qualitative and quantitative respectively even in real samples with the limit of detection was 2 × 10{sup −8} mol L{sup −1} and a recognition rate of 100%. This work is, to the best of our knowledge, the first report on the detection of pesticides based on the fluorescence quenching phenomenon of double quantum dots combined with chemometrics methods. What's more, the excellent selectivity of the system has been verified in different mediums such as mixed ion disruption, waste water, tea and water extraction liquid drugs. - Highlights: • A new model based on double QDs is established for pesticide residues detection. • The fluorescent data array sensor is coupled with chmometrics methods. • The sensor can be highly sensitive and selective detection in actual samples.

  11. “Turn-off” fluorescent data array sensor based on double quantum dots coupled with chemometrics for highly sensitive and selective detection of multicomponent pesticides

    International Nuclear Information System (INIS)

    Fan, Yao; Liu, Li; Sun, Donglei; Lan, Hanyue; Fu, Haiyan; Yang, Tianming; She, Yuanbin; Ni, Chuang

    2016-01-01

    As a popular detection model, the fluorescence “turn-off” sensor based on quantum dots (QDs) has already been successfully employed in the detections of many materials, especially in the researches on the interactions between pesticides. However, the previous studies are mainly focused on simple single track or the comparison based on similar concentration of drugs. In this work, a new detection method based on the fluorescence “turn-off” model with water-soluble ZnCdSe and CdSe QDs simultaneously as the fluorescent probes is established to detect various pesticides. The fluorescence of the two QDs can be quenched by different pesticides with varying degrees, which leads to the differences in positions and intensities of two peaks. By combining with chemometrics methods, all the pesticides can be qualitative and quantitative respectively even in real samples with the limit of detection was 2 × 10"−"8 mol L"−"1 and a recognition rate of 100%. This work is, to the best of our knowledge, the first report on the detection of pesticides based on the fluorescence quenching phenomenon of double quantum dots combined with chemometrics methods. What's more, the excellent selectivity of the system has been verified in different mediums such as mixed ion disruption, waste water, tea and water extraction liquid drugs. - Highlights: • A new model based on double QDs is established for pesticide residues detection. • The fluorescent data array sensor is coupled with chmometrics methods. • The sensor can be highly sensitive and selective detection in actual samples.

  12. The influence of geopolitical change on the well-being of a population: the Berlin Wall.

    Science.gov (United States)

    Héon-Klin, V; Sieber, E; Huebner, J; Fullilove, M T

    2001-03-01

    Social cohesion is recognized as a fundamental condition for healthy populations, but social cohesion itself arises from political unity. The history of the Berlin Wall provides a unique opportunity to examine the effects of partition on social cohesion and, by inference, on health. This ethnographic study consisted of examination of the territory formerly occupied by the Wall, formal and informal interviews with Berlin residents, and collection of cultural documents related to the Wall. Transcripts, field notes, and documents were examined by means of a keyword-in-context analysis. The separation of Berlin into 2 parts was a traumatic experience for the city's residents. After partition, East and West Germany had divergent social, cultural, and political experiences and gradually grew apart. The demolition of the Wall--the symbol and the instrument of partition--makes possible but does not ensure the reintegration of 2 populations that were separated for 40 years. The evolution of a new common culture might be accelerated by active attempts at cultural and social exchange.

  13. Bio politics - The bio-environment - bio-culture of the Danube

    International Nuclear Information System (INIS)

    Vlavianos-Arvanitis, A.

    1997-01-01

    The bio-environment has been the single most important correlation in human history and can successfully promote international co-operational co-operation and understanding. With the construction of a network for collaboration, the 'Danube Countries' can come together in celebration of their culture and heritage. As the Danube flows from the Black Forest to the Black Sea, it carries messages of peace, hope and co-operation. Applying these messages to every endeavour can improve our quality of life and lead to a brighter future. Since its inception in 1985, the Bio politics International Organization (B.I.O.) has been labouring to raise awareness of the urgent need to instate a new system of norms and principles, compatible with sound environmental management and with the most important task of ensuring global literacy on environmental issues. Along with critically re-assessing the concept of profit, the goal is to adopt a system of bio centric values, where respect for the bio-environment will govern our every action and thought

  14. Treatability study of pesticide-based industrial wastewater.

    Science.gov (United States)

    Shah, Kinnari; Chauhan, L I; Galgale, A D

    2012-10-01

    This paper finds out appropriate treatment methods for wastewater of an Organophosphorus viz, chloropyrifos pesticide manufacturing industry. The characterization of wastewater generated during trial production of chloropyrifos was carried out. Based on the characterization of wastewater, various treatability studies were conducted. The most desirable results were obtained with treatment scheme employing acidification, chlorination with NaOCl, suspended growth biological treatment, chemical precipitation for phosphorous removal and activated carbon treatment. Acidification of wastewater helps in by-product recovery as well as reduction in COD upto 36.26%. Chlorination followed by biological treatment was found to be effective to reduce the COD level by 62.06%. To comply with permissible limits prescribed by Effluent Channel Project Ltd.(ECPL)* and Gujarat Pollution Control Board (GPCB) for discharge of industrial effluent into channel, further treatment in the form of chemical precipitation (for phosphorous removal) and granular activated carbon is suggested.

  15. Bio-based polyurethane foams toward applications beyond thermal insulation

    International Nuclear Information System (INIS)

    Gama, Nuno V.; Soares, Belinda; Freire, Carmen S.R.; Silva, Rui; Neto, Carlos P.; Barros-Timmons, Ana; Ferreira, Artur

    2015-01-01

    Highlights: • Coffee grounds wastes were successfully liquefied yielding a bio-based polyol. • Coffee grounds derived foams formulations were optimized by tuning reagents’ contents. • The viscoelastic properties of these foams are promising to expand their applications. - Abstract: In this work the preparation of viscoelastic bio-based polyurethane foams (PUFs) using polyols obtained via acid liquefaction of coffee grounds wastes has been optimized. In a first stage, the effect of different ratios of isocyanate content to hydroxyl number (0.6, 0.7 and 0.8) and of three distinct percentages of catalyst (3%, 5% and 7%) on the extent of the polymerization reaction was studied by infrared spectroscopy. Next, different percentages of surfactant (14%, 16% and 18%) and blowing agent (12%, 14% and 16%) were used to assess their effect on the density, thermal conductivity and mechanical properties of the foams, including their recovery time. The mechanical properties of the ensuing foams proved to be very interesting due to their viscoelastic behavior. PUFs were also characterized by scanning electron microscopy (SEM) revealing a typical cellular structure and by thermogravimetric analysis (TGA) which proved that these materials are thermally stable up to 190 °C. These results suggest other potential applications for these materials beyond heat insulation in areas where damping properties can be an added value

  16. Dynamik, Schadstoffbelastung und Ökotoxizität der Sedimente in der Rummelsburger Bucht – Berliner Spree

    OpenAIRE

    Bölscher, Jens; Dumm, Michaela; Suthfeldt, René; Vogt, Benjamin; Bölscher, Judith; Terytze, Konstantin; Schulte, Achim

    2017-01-01

    Der vorliegende Bericht behandelt die Ergebnisse des Forschungsprojektes RUBUS, welches im Zeitraum November 2013 bis November 2015 von der Freien Universität Berlin durchgeführt wurde. Gegenstand des Projektes ist die Untersuchung der aktuellen Belastungssituation und der Dynamik der Sedimente in der Rummelsburger Bucht als Teil der urbanen Spree in Berlin. Das Projekt hat die Klärung der räumlichen Verteilung, Quantifizierung und Bewertung der Schadstoffbelastung in den Sedimenten der Ru...

  17. Prevalence of pesticides in postconsumer agrochemical polymeric packaging.

    Science.gov (United States)

    Eras, J; Costa, J; Vilaró, F; Pelacho, A M; Canela-Garayoa, R; Martin-Closas, L

    2017-02-15

    Pesticide remains contained in agrochemical packaging waste are a source of uncontrolled risk for human health; they are also a quality feedstock for the plastic recycling industry. Many governments have recently started to establish laws and regulations to develop systems for recovering and recycling the polymeric packages used for pesticides. There is also a demand in having a procedure to control the suitability of the pesticide packages to be reused. We have developed a two-step operation process to assess the pesticide residues in agricultural containers made of a variety of polymeric matrices. The procedure is based on an extraction with a solvent mixture followed by UPLC-MS/MS determination. Solvents for neutral pesticides were selected considering the Hildebrand solubility (δ) of solvents and polymers together with those estimated for the pesticides. The proposed technique is effective in recovering imbibed pesticides in polymeric matrices. Also, a simplified extraction procedure has been tested to become a routine method for these wastes. We have found that in many cases a significant amount of pesticides remain into the polymeric matrix, even after a standardized cleaning; the impact of releasing these hazardous compounds into the environment is to be of further consideration. Copyright © 2016 Elsevier B.V. All rights reserved.

  18. Hydrodeoxygenation of prairie cordgrass bio-oil over Ni based activated carbon synergistic catalysts combined with different metals.

    Science.gov (United States)

    Cheng, Shouyun; Wei, Lin; Zhao, Xianhui; Kadis, Ethan; Cao, Yuhe; Julson, James; Gu, Zhengrong

    2016-06-25

    Bio-oil can be upgraded through hydrodeoxygenation (HDO). Low-cost and effective catalysts are crucial for the HDO process. In this study, four inexpensive combinations of Ni based activated carbon synergistic catalysts including Ni/AC, Ni-Fe/AC, Ni-Mo/AC and Ni-Cu/AC were evaluated for HDO of prairie cordgrass (PCG) bio-oil. The tests were carried out in the autoclave under mild operating conditions with 500psig of H2 pressure and 350°C temperature. The catalysts were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) and transmission electron microscope (TEM). The results show that all synergistic catalysts had significant improvements on the physicochemical properties (water content, pH, oxygen content, higher heating value and chemical compositions) of the upgraded PCG bio-oil. The higher heating value of the upgraded bio-oil (ranging from 29.65MJ/kg to 31.61MJ/kg) improved significantly in comparison with the raw bio-oil (11.33MJ/kg), while the oxygen content reduced to only 21.70-25.88% from 68.81% of the raw bio-oil. Compared to raw bio-oil (8.78% hydrocarbons and no alkyl-phenols), the Ni/AC catalysts produced the highest content of gasoline range hydrocarbons (C6-C12) at 32.63% in the upgraded bio-oil, while Ni-Mo/AC generated the upgraded bio-oil with the highest content of gasoline blending alkyl-phenols at 38.41%. Copyright © 2016 Elsevier B.V. All rights reserved.

  19. Obstetric care quality indicators and outcomes based on the degree of acculturation of immigrants-results from a cross-sectional study in Berlin.

    Science.gov (United States)

    David, Matthias; Borde, Theda; Brenne, Silke; Ramsauer, Babett; Hinkson, Larry; Henrich, Wolfgang; Razum, Oliver; Breckenkamp, Jürgen

    2018-02-01

    Acculturation is a complex, multidimensional process involving the integration of the traditional norms, values, and lifestyles of a new cultural environment. It is, however, unclear what impact the degree of acculturation has on obstetric outcomes. Data collection was performed in 2011 and 2012 at three obstetric tertiary centers in Berlin, Germany. Standardized interviews (20-30 min.) were performed with support of evaluated questionnaires. The primary collected data were then linked to the perinatal data recorded at the individual clinics provided from the obstetric centers which correspond with the routinely centralized data collected for quality assurance throughout Germany. The questionnaire included questions on sociodemographic, health care, and migrant-related aspects. Migrant women and women with a migration background were assessed using the Frankfurt Acculturation Scale, a one-dimensional measurement tool to assess the degree of acculturation (15 items on language and media usage as well as integration into social networks). In summary, 7100 women were available for the survey (response rate of 89.6%) of which 3765 (53%) had a migration background. The probability of low acculturation is significantly (p relationships between the degree of acculturation and obstetric parameters show no significant differences for prematurity, 5 min.-Apgar values > 7, arterial umbilical cord pH values > 7.00 and admissions to the neonatal unit. In Berlin, among migrant women a low degree of acculturation may have an unfavorable effect on the utilization of pregnancy care provision. However, there were no relevant differences in obstetric outcome parameters in relation to the degree of acculturation within the migrant population of Berlin.

  20. CO{sub 2} reduction cost for bio-diesel, Danish produced bio-diesel based on rape seed; CO{sub 2} reduktionsomkostninger ved biodiesel. Dansk produceret biodiesel pae raps

    Energy Technology Data Exchange (ETDEWEB)

    Carlsen, Kirsten; Kjellingbro, M; Mogensen, Martin Frank; Kohl, M

    2006-12-15

    Bio-diesel based on rape seed (RME, Rape Methyl Esther), often referred to as first generation bio-diesel, is a renewable fuel with CO{sub 2} reduction potential. Mixed with conventional diesel it can be used directly in existing diesel engines. The EU target for the use of bio-fuels in the transport sector was 2 % by 2005 and is 5.75 % by 2010. In Denmark, the use of bio-fuels in the transport sector is not viewed as a cost-effective CO{sub 2} reduction measure. This conclusion concerning the cost-effectiveness of bio-fuels was partly based on calculations of the CO2 reduction cost for Danish-produced RME made by the Danish Energy Authority in 2003. At that time the cost was estimated at 360 DKK/tonne CO{sub 2}. Since then some of the assumptions behind the calculations have changed. The overall objective of this report is to update the Danish Energy Authority's study from 2003, taking into account revised assumptions. The report also attempts to examine the uncertainties associated with the calculations by including extended sensitivity analyses. The report draws the following conclusions: 1) The CO{sub 2} reduction cost for Danish produced RME is estimated at 860 DKK/tonne CO{sub 2}, which is significantly higher than the result obtained by the Danish Energy Authority in 2003. 2) The difference from the Danish Energy Authority's original calculations is principally due to a higher rape seed price based on the market price on rape seed. 3) The uncertainty in both estimates is substantial, and there is about 15 % probability of the reduction costs being lower than the target of 180 DKK/tonne CO2 set by the government. (au)

  1. CO{sub 2} reduction cost for bio-diesel, Danish produced bio-diesel based on rape seed; CO{sub 2} reduktionsomkostninger ved biodiesel. Dansk produceret biodiesel pae raps

    Energy Technology Data Exchange (ETDEWEB)

    Carlsen, Kirsten; Kjellingbro, M.; Mogensen, Martin Frank; Kohl, M.

    2006-12-15

    Bio-diesel based on rape seed (RME, Rape Methyl Esther), often referred to as first generation bio-diesel, is a renewable fuel with CO{sub 2} reduction potential. Mixed with conventional diesel it can be used directly in existing diesel engines. The EU target for the use of bio-fuels in the transport sector was 2 % by 2005 and is 5.75 % by 2010. In Denmark, the use of bio-fuels in the transport sector is not viewed as a cost-effective CO{sub 2} reduction measure. This conclusion concerning the cost-effectiveness of bio-fuels was partly based on calculations of the CO2 reduction cost for Danish-produced RME made by the Danish Energy Authority in 2003. At that time the cost was estimated at 360 DKK/tonne CO{sub 2}. Since then some of the assumptions behind the calculations have changed. The overall objective of this report is to update the Danish Energy Authority's study from 2003, taking into account revised assumptions. The report also attempts to examine the uncertainties associated with the calculations by including extended sensitivity analyses. The report draws the following conclusions: 1) The CO{sub 2} reduction cost for Danish produced RME is estimated at 860 DKK/tonne CO{sub 2}, which is significantly higher than the result obtained by the Danish Energy Authority in 2003. 2) The difference from the Danish Energy Authority's original calculations is principally due to a higher rape seed price based on the market price on rape seed. 3) The uncertainty in both estimates is substantial, and there is about 15 % probability of the reduction costs being lower than the target of 180 DKK/tonne CO2 set by the government. (au)

  2. Recovery evaluation of organophosphorus pesticides from bee pollen by matrix solid-phase dispersion extraction using sorbents based on silica and titania

    International Nuclear Information System (INIS)

    Torres-Perea, C; Muñoz-Rodríguez, D; Carrera-Figueiras, C; Medina-Peralta, S; Moguel-Ordóñez, Y B

    2013-01-01

    This work focused on the evaluation of the recovery of organophosphorus pesticides from bee pollen after matrix solid phase-dispersion extraction (MSPD). Materials based on silica, titania and titania modified with polivylnylimidazole or polyestirene were used as adsorbents for the extraction of pesticides. Small amounts of fortified pollen (0.1 g, at 1 micro-g/g of pesticides), adsorbent (0.4 g) and solvent elution (1 mL de acetonitrile – ACN) were used in the extractions. For recovery evaluation, pollen extracts were analyzed by gas chromatography coupled with mass spectrometry.

  3. Bio-inspired computation in telecommunications

    CERN Document Server

    Yang, Xin-She; Ting, TO

    2015-01-01

    Bio-inspired computation, especially those based on swarm intelligence, has become increasingly popular in the last decade. Bio-Inspired Computation in Telecommunications reviews the latest developments in bio-inspired computation from both theory and application as they relate to telecommunications and image processing, providing a complete resource that analyzes and discusses the latest and future trends in research directions. Written by recognized experts, this is a must-have guide for researchers, telecommunication engineers, computer scientists and PhD students.

  4. "Turn-off" fluorescent data array sensor based on double quantum dots coupled with chemometrics for highly sensitive and selective detection of multicomponent pesticides.

    Science.gov (United States)

    Fan, Yao; Liu, Li; Sun, Donglei; Lan, Hanyue; Fu, Haiyan; Yang, Tianming; She, Yuanbin; Ni, Chuang

    2016-04-15

    As a popular detection model, the fluorescence "turn-off" sensor based on quantum dots (QDs) has already been successfully employed in the detections of many materials, especially in the researches on the interactions between pesticides. However, the previous studies are mainly focused on simple single track or the comparison based on similar concentration of drugs. In this work, a new detection method based on the fluorescence "turn-off" model with water-soluble ZnCdSe and CdSe QDs simultaneously as the fluorescent probes is established to detect various pesticides. The fluorescence of the two QDs can be quenched by different pesticides with varying degrees, which leads to the differences in positions and intensities of two peaks. By combining with chemometrics methods, all the pesticides can be qualitative and quantitative respectively even in real samples with the limit of detection was 2 × 10(-8) mol L(-1) and a recognition rate of 100%. This work is, to the best of our knowledge, the first report on the detection of pesticides based on the fluorescence quenching phenomenon of double quantum dots combined with chemometrics methods. What's more, the excellent selectivity of the system has been verified in different mediums such as mixed ion disruption, waste water, tea and water extraction liquid drugs. Copyright © 2016 Elsevier B.V. All rights reserved.

  5. Estimating pesticide emissions for LCA of agricultural products

    DEFF Research Database (Denmark)

    Hauschild, Michael Zwicky

    2000-01-01

    Emission data for pesticides from agricultural product systems may be based on national and international pesticide usage statistics, but these only provide information on the applied dose. When the field is considered as part of the technosphere, the emissions from the system are those quantitie...

  6. First pediatric transatlantic air ambulance transportation on a Berlin Heart EXCOR left ventricular assist device as a bridge to transplantation.

    Science.gov (United States)

    Tissot, Cecile; Buchholz, Holger; Mitchell, Max B; da Cruz, Eduardo; Miyamoto, Shelley D; Pietra, Bill A; Charpentier, Arnaud; Ghez, Olivier

    2010-03-01

    Mechanical circulatory devices are indicated in patients with refractory cardiac failure as a bridge to recovery or to transplantation. Whenever required, transportation while on mechanical support is a challenge and still limited by technical restrictions or distance. We report the first pediatric case of transatlantic air transportation on a Berlin Heart EXCOR ventricular assist device (Berlin Heart, Berlin, Germany) of a 13-yr-old American female who presented in cardiogenic shock with severe systolic dysfunction while vacationing in France. Rapid hemodynamic deterioration occurred despite maximal medical treatment, and she was supported initially with extracorporeal membrane oxygenation converted to a Berlin Heart EXCOR left ventricular assist device. Long-distance air transportation of the patient was accomplished 3 wks after implantation from Marseille, France, to Denver, Colorado. No adverse hemodynamic effects were encountered during the 13.5-hr flight (8770 km). The patient did not recover sufficient cardiac function and underwent successful orthotopic heart transplantation 3 months after the initial event. Our experience suggests that long-distance air transportation of pediatric patients using the Berlin Heart EXCOR mobile unit as a bridge to recovery or transplantation is feasible and appears safe.

  7. Twisting biomaterials around your little finger: Environmental impacts of bio-based wrappings

    NARCIS (Netherlands)

    Hermann, B.G.; Blok, K.; Patel, M.K.

    2010-01-01

    Background, aim, and scope Packaging uses nearly 40% of all polymers, a substantial share of which is used for sensitive merchandise such as moisture-sensitive food. To find out if bio-based materials are environmentally advantageous for this demanding application, we compared laminated, printed

  8. Enzymatic polymerization of bio-based monomers for applications in hydrogels and coatings

    DEFF Research Database (Denmark)

    Hoffmann, Christian; Nguyen, Hiep Dinh; Storgaard, Thomas

    of the enzymatic catalysts that can provide control over polymer structure in functional polymers. Lipase catalyzed polymerizations (specifically CALB) has been applied to prepare functional polyesters and to evaluate the possibilities of using less stable bio-based monomers such as itaconic acid or its...

  9. Secure and Usable Bio-Passwords based on Confidence Interval

    OpenAIRE

    Aeyoung Kim; Geunshik Han; Seung-Hyun Seo

    2017-01-01

    The most popular user-authentication method is the password. Many authentication systems try to enhance their security by enforcing a strong password policy, and by using the password as the first factor, something you know, with the second factor being something you have. However, a strong password policy and a multi-factor authentication system can make it harder for a user to remember the password and login in. In this paper a bio-password-based scheme is proposed as a unique authenticatio...

  10. 75 FR 62323 - Pesticide Management and Disposal; Standards for Pesticide Containers and Containment; Change to...

    Science.gov (United States)

    2010-10-08

    ... Pesticide Management and Disposal; Standards for Pesticide Containers and Containment; Change to Labeling... the pesticide container and containment regulations to provide an 8-month extension of the labeling... titled ``Pesticide Management and Disposal; Standards for Pesticide Containers and Containment'' (71 FR...

  11. A bare-eye-based lateral flow immunoassay based on the use of gold nanoparticles for simultaneous detection of three pesticides

    International Nuclear Information System (INIS)

    Wang, Limin; Cai, Jia; Wang, Yulong; Fang, Qingkui; Wang, Suyan; Cheng, Qi; Liu, Fengquan; Du, Dan; Lin, Yuehe

    2014-01-01

    We present a novel lateral flow immunoassay (LFIA) for the simultaneous detection of the pesticides imidacloprid, chlorpyrifos-methyl and isocarbophos based on three competitive immunoreactions. In contrast to previously reported LFIAs, the method is based on the use of four strips. Each has three red channels (three test lines dispensed with different capture reagent) to detect imidacloprid, chlorpyrifos-methyl and isocarbophos respectively. Different channels on each strip are the key to multi-detection, and four strips of LFIA are needed for visual and semi-quantitative read-outs. Under optimized conditions, the LFIA was applied to the determination of three pesticides. The detection time is within 7 min and the detection limits are 50, 100, and 100 μg L −1 , respectively. Furthermore, the LFIA was applied to the analysis of spiked Chinese cabbage and soil samples and results were validated by HPLC. (author)

  12. Characterization of the extent of Mercury Contamination in the Androscoggin River from a former Chlor-alkali Facility, Berlin, New Hampshire

    Science.gov (United States)

    Chalmers, A.; Marvin-Dipasquale, M. C.; Rosiu, C.; Luce, D.; Coles, J.; Zimmerman, M.; Smith, T.

    2010-12-01

    From the late 1800s to the 1960s a chlor-alkali plant was used to produce chlorine gas for the papermaking industry in Berlin, New Hampshire. During operation of the chlor-alkali facility, elemental mercury (Hg) was released to the environment, contaminating soils and the underlying fractured rock. Investigations have revealed that elemental Hg continues to seep through bedrock fractures into the adjacent Androscoggin River. This study evaluates the extent and transformation of Hg contamination in the Androscoggin River by comparing a reference site 17 kilometers above the former chlor-alkali facility to 5 sites ranging from 1 to 16 km downstream from the facility. Total and methyl Hg (THg and MeHg, respectively), among other analytes, were characterized in surface water, pore water, sediment and biological tissue samples at each site. Bed sediment was also assessed for bio-available (tin-reducible) inorganic Hg (II) and microbial MeHg production potential rates. Acid extractable ferrous iron, crystalline and amorphous (poorly crystalline) ferric iron, total reduced sulfur, particle size, and organic content in bed sediment was analyzed to help explain spatial differences in MeHg production rates and bio-available Hg (II) among sites. The information provided by this study will help evaluate the extent of Hg contamination in the Androscoggin River, will improve our understanding of the controls on MeHg production in the Androscoggin River system, and will be used by the U.S. Environmental Protection Agency to support remediation of the chlor-alkali facility site.

  13. Bio-electrospraying and droplet-based microfluidics: control of cell numbers within living residues

    Energy Technology Data Exchange (ETDEWEB)

    Hong Jongin; DeMello, Andrew J [Nanostructured Materials and Devices Group, Department of Chemistry, Imperial College London, Exhibition Road, London SW7 2AZ (United Kingdom); Jayasinghe, Suwan N, E-mail: a.demello@imperial.ac.u, E-mail: s.jayasinghe@ucl.ac.u [BioPhysics Group, Department of Mechanical Engineering, University College London, Torrington Place, London WC1E 7JE (United Kingdom)

    2010-04-15

    Bio-electrospraying (BES) has demonstrated great promise as a rapidly evolving strategy for tissue engineering and regenerative biology/medicine. Since its discovery in 2005, many studies have confirmed that cells (immortalized, primary and stem cells) and whole organisms (Danio rerio, Xenopus tropicalis, Caenorhabditis elegans to Drosophila) remain viable post-bio-electrospraying. Although this bio-protocol has achieved much, it suffers from one crucial problem, namely the ability to precisely control the number of cells within droplets and or encapsulations. If overcome, BES has the potential to become a high-efficiency biotechnique for controlled cell encapsulation, a technique most useful for a wide range of applications in biology and medicine ranging from the forming of three-dimensional cultures to an approach for treating diseases such as type I diabetes. In this communication, we address this issue by demonstrating the coupling of BES with droplet-based microfluidics for controlling live cell numbers within droplets and residues. (communication)

  14. Bio-electrospraying and droplet-based microfluidics: control of cell numbers within living residues

    International Nuclear Information System (INIS)

    Hong Jongin; DeMello, Andrew J; Jayasinghe, Suwan N

    2010-01-01

    Bio-electrospraying (BES) has demonstrated great promise as a rapidly evolving strategy for tissue engineering and regenerative biology/medicine. Since its discovery in 2005, many studies have confirmed that cells (immortalized, primary and stem cells) and whole organisms (Danio rerio, Xenopus tropicalis, Caenorhabditis elegans to Drosophila) remain viable post-bio-electrospraying. Although this bio-protocol has achieved much, it suffers from one crucial problem, namely the ability to precisely control the number of cells within droplets and or encapsulations. If overcome, BES has the potential to become a high-efficiency biotechnique for controlled cell encapsulation, a technique most useful for a wide range of applications in biology and medicine ranging from the forming of three-dimensional cultures to an approach for treating diseases such as type I diabetes. In this communication, we address this issue by demonstrating the coupling of BES with droplet-based microfluidics for controlling live cell numbers within droplets and residues. (communication)

  15. Star polymer-based unimolecular micelles and their application in bio-imaging and diagnosis.

    Science.gov (United States)

    Jin, Xin; Sun, Pei; Tong, Gangsheng; Zhu, Xinyuan

    2018-02-03

    As a novel kind of polymer with covalently linked core-shell structure, star polymers behave in nanostructure in aqueous medium at all concentration range, as unimolecular micelles at high dilution condition and multi-micelle aggregates in other situations. The unique morphologies endow star polymers with excellent stability and functions, making them a promising platform for bio-application. A variety of functions including imaging and therapeutics can be achieved through rational structure design of star polymers, and the existence of plentiful end-groups on shell offers the opportunity for further modification. In the last decades, star polymers have become an attracting platform on fabrication of novel nano-systems for bio-imaging and diagnosis. Focusing on the specific topology and physicochemical properties of star polymers, we have reviewed recent development of star polymer-based unimolecular micelles and their bio-application in imaging and diagnosis. The main content of this review summarizes the synthesis of integrated architecture of star polymers and their self-assembly behavior in aqueous medium, focusing especially on the recent advances on their bio-imaging application and diagnosis use. Finally, we conclude with remarks and give some outlooks for further exploration in this field. Copyright © 2018 Elsevier Ltd. All rights reserved.

  16. Pesticide residue quantification analysis by hyperspectral imaging sensors

    Science.gov (United States)

    Liao, Yuan-Hsun; Lo, Wei-Sheng; Guo, Horng-Yuh; Kao, Ching-Hua; Chou, Tau-Meu; Chen, Junne-Jih; Wen, Chia-Hsien; Lin, Chinsu; Chen, Hsian-Min; Ouyang, Yen-Chieh; Wu, Chao-Cheng; Chen, Shih-Yu; Chang, Chein-I.

    2015-05-01

    Pesticide residue detection in agriculture crops is a challenging issue and is even more difficult to quantify pesticide residue resident in agriculture produces and fruits. This paper conducts a series of base-line experiments which are particularly designed for three specific pesticides commonly used in Taiwan. The materials used for experiments are single leaves of vegetable produces which are being contaminated by various amount of concentration of pesticides. Two sensors are used to collected data. One is Fourier Transform Infrared (FTIR) spectroscopy. The other is a hyperspectral sensor, called Geophysical and Environmental Research (GER) 2600 spectroradiometer which is a batteryoperated field portable spectroradiometer with full real-time data acquisition from 350 nm to 2500 nm. In order to quantify data with different levels of pesticide residue concentration, several measures for spectral discrimination are developed. Mores specifically, new measures for calculating relative power between two sensors are particularly designed to be able to evaluate effectiveness of each of sensors in quantifying the used pesticide residues. The experimental results show that the GER is a better sensor than FTIR in the sense of pesticide residue quantification.

  17. Determination of pesticides and pesticide degradates in filtered water by direct aqueous-injection liquid chromatography-tandem mass spectrometry

    Science.gov (United States)

    Sandstrom, Mark W.; Kanagy, Leslie K.; Anderson, Cyrissa A.; Kanagy, Christopher J.

    2016-01-11

    A liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was developed for determination of 229 pesticides compounds (113 pesticides and 116 pesticide degradates) in filtered water samples from stream and groundwater sites. The pesticides represent a broad range of chemical classes and were selected based on criteria such as current-use intensity, probability of occurrence in streams and groundwater, and toxicity to humans or aquatic organisms. More than half of the analytes are pesticide degradates. The method involves direct injection of a 100-microliter (μL) sample onto the LC-MS/MS without any sample preparation other than filtration. Samples are analyzed with two injections, one in electrospray ionization (ESI) positive mode and one in ESI negative mode, using dynamic multiple reaction monitoring (MRM) conditions, with two MRM transitions for each analyte. The LC-MS/MS instrument parameters were optimized for highest sensitivity for the most analytes. This report describes the analytical method and presents characteristics of the method validation including bias and variability, detection levels, and holding-time studies.

  18. Study on thermal properties of synthetic and bio-based polyurethane

    Directory of Open Access Journals (Sweden)

    Šercer Mladen

    2015-01-01

    Full Text Available Polymers that are created by the chemical polymerization of naturally occurring monomers are attracting considerable commercial interest in the last few years because of their non-toxicity, biodegradability and biocompatibility and use of feedstock that is renewable. The development of specialized lignin compounds, such as electrically conducting polymers, engineering plastics and polyurethane, is an area of highest interest and growth. The paper will present the comparison of the mechanical and thermal properties of conventional polyurethane and bio-based polyurethane, i.e. polyurethane based on polyols produced by liquefaction of waste wood biomass.

  19. Risk Factors for Non-communicable Diseases in Vietnam: A Focus on Pesticides

    Directory of Open Access Journals (Sweden)

    Hoang V. Dang

    2017-09-01

    Full Text Available Agent Orange, which was used in southern Vietnam, is confirmed the main source of dioxin exposure in Vietnam. Since early 1990s, agriculture of Vietnam has attained advances under intensive cultivation. Both production and yields per crop have increased significantly at the farm level, but the quantity of pesticides used in agriculture also increased in the absence of regulations and good practices. Illegal business of pesticides with false labels, as well as marketing of expired or poor quality products in stores without license are popular in Vietnam. Misuse and improper use in agriculture in Vietnam has led to a variety of problems, such as environmental pollution (including food producing animals and adverse health impact on animals and humans. Open dumpsites worsen the general scenario. Similar to the environmental exposure, human exposure to DDT in Vietnam was ranked among the highest worldwide, with recognized effects. Exposed communities have to face birth defects, health disorders and non-communicable diseases (NCDs, from metabolic syndrome, asthma, infertility and other reproductive disorders through to diabetes, obesity, cardiovascular and neurodegenerative diseases, and cancer. A common feature of many chronic disorders and NCDs is metabolic disruption: environmental chemical factors disturb cellular homeostasis, thus affecting the ability of the body to restore a functional internal environment. Among these, endocrine disrupting pesticides can interfere with the action of hormones including metabolic hormones, and are likely to represent the main concern for developmentally-induced NCDs. Since pesticides are often persistent and bio-accumulate in the food chain through the living environment of food-producing organisms, this paper discusses relevant aspects of risk assessment, risk communication and risk management.

  20. Trends of pesticide exposure and related cases in the Philippines.

    Science.gov (United States)

    Lu, Jinky Leilanie; Cosca, Katherine Z; Del Mundo, Jocelyn

    2010-01-01

    The study aims to provide a comprehensive trend of pesticide poisoning cases in the Philippines as well as pesticide exposures, and risk factors related to the adverse effects of pesticide. Records were gathered from the National Poison Control and Management Center (NPCMC), the Philippine General Hospital, De La Salle Medical Center, and other hospitals, and reviewed research studies conducted in the Philippines. Based on hospital surveys, the number of pesticide cases as well as mortality trends have been increasing. Studies from 2006 to 2010 showed that human health especially those of the farmers is at risk due to pesticide exposure. Illnesses and symptoms such as headache, skin abnormalities, fatigue, fever, and weaknesses were the common health complaints experienced by the farmers as reported in the research studies. Moreover, the studies showed risk factors to pesticide exposure, work practices, and pesticide residues in environmental media that could be contributory to pesticide poisoning cases. Government agencies should intensify their surveillance and regulation on both household and agricultural pesticides. The state of pesticide-related illnesses mirrors the poor safety practices among farmers as well as lack of necessary supervision from the government agencies.

  1. TU Berlin Rover Family for Terrestrial Testing of Complex Planetary Mission Scenarios

    Science.gov (United States)

    Kryza, L.; Brieß, K.

    2018-04-01

    The TU Berlin has developed a family of planetary rovers for educational use and research activities. The paper will introduce these cost-effective systems, which can be used for analogue mission demonstration on Earth.

  2. Pesticide regulations and farm worker safety: the need to improve pesticide regulations in Viet Nam.

    Science.gov (United States)

    Phung, Dung Tri; Connell, Des; Miller, Greg; Rutherford, Shannon; Chu, Cordia

    2012-06-01

    Agricultural pesticide use in Viet Nam has more than tripled since 1990. However, pesticide legislation and regulations have not been developed in response to this large increase in usage, as a result of which pesticides pose a serious threat to human health and the environment. This paper identifies the need to improve pesticide regulations in Viet Nam through a comparative analysis of pesticide regulations in Viet Nam and the United States of America, where the rate of acute poisoning among agricultural workers is much lower than in Viet Nam and where information pertaining to pesticide regulations is made accessible to the public. The analysis identified several measures that would help to improve Viet Nam's pesticide regulations. These include enhancing pesticide legislation, clarifying the specific roles and active involvement of both the environmental and health sectors; performing a comprehensive risk-benefit evaluation of pesticide registration and management practices; improving regulations on pesticide suspension and cancellation, transport, storage and disposal; developing import and export policies and enhancing pesticide-related occupational safety programmes.

  3. Tours de Babel et lettres de feu : motifs bibliques dans le Berlin de Vladimir Nabokov

    OpenAIRE

    Manolescu-Oancea, Monica

    2017-01-01

    When examining the critical responses to Vladimir Nabokov’s representations of Berlin in his Russian fiction, it is quite surprising to notice that two antithetical positions have been formulated, one which stresses the absence of Berlin as a city in Nabokov’s texts, and a more recent position emphasizing, on the contrary, the substantial presence of the city in terms of references, landmarks and recognizable sites. This article adopts a different stance, focusing on two Old Testament motifs ...

  4. A community-based cluster randomised trial of safe storage to reduce pesticide self-poisoning in rural Sri Lanka

    DEFF Research Database (Denmark)

    Pearson, Melissa; Konradsen, Flemming; Gunnell, David

    2011-01-01

    . One approach to reducing access to pesticides is for households to store pesticides in lockable "safe-storage" containers. However, before this approach can be promoted, evidence is required on its effectiveness and safety. Methods/Design A community-based cluster randomised controlled trial has been...... at the 5% significance level. Secondary outcomes will include the incidence of all pesticide poisoning and total self-harm. Discussion This paper describes a large effectiveness study of a community intervention to reduce the burden of intentional poisoning in rural Sri Lanka. The study builds on a strong...... partnership between provincial health services, local and international researchers, and local communities. We discuss issues in relation to randomisation and contamination, engaging control villages, the intervention, and strategies to improve adherence. Trial Registritation The trial is registered...

  5. Progress on Azadirachta indica Based Biopesticides in Replacing Synthetic Toxic Pesticides

    OpenAIRE

    Chaudhary, Suman; Kanwar, Rupinder K.; Sehgal, Alka; Cahill, David M.; Barrow, Colin J.; Sehgal, Rakesh; Kanwar, Jagat R.

    2017-01-01

    Over the years, extensive use of commercially available synthetic pesticides against phytophagous insects has led to their bioaccumulation in the environment causing increased resistance and reduction in soil biodiversity. Further, 90% of the applied pesticides enter the various environmental resources as a result of run-off, exposing the farmers as well as consumers of the agricultural produce to severe health issues. Therefore, growing attention has been given toward the development of alte...

  6. Diamond bio electronics.

    Science.gov (United States)

    Linares, Robert; Doering, Patrick; Linares, Bryant

    2009-01-01

    The use of diamond for advanced applications has been the dream of mankind for centuries. Until recently this dream has been realized only in the use of diamond for gemstones and abrasive applications where tons of diamonds are used on an annual basis. Diamond is the material system of choice for many applications, but its use has historically been limited due to the small size, high cost, and inconsistent (and typically poor) quality of available diamond materials until recently. The recent development of high quality, single crystal diamond crystal growth via the Chemical Vapor Deposition (CVD) process has allowed physcists and increasingly scientists in the life science area to think beyond these limitations and envision how diamond may be used in advanced applications ranging from quantum computing, to power generation and molecular imaging, and eventually even diamond nano-bots. Because of diamond's unique properties as a bio-compatible material, better understanding of diamond's quantum effects and a convergence of mass production, semiconductor-like fabrication process, diamond now promises a unique and powerful key to the realization of the bio-electronic devices being envisioned for the new era of medical science. The combination of robust in-the-body diamond based sensors, coupled with smart bio-functionalized diamond devices may lead to diamond being the platform of choice for bio-electronics. This generation of diamond based bio-electronic devices would contribute substantially to ushering in a paradigm shift for medical science, leading to vastly improved patient diagnosis, decrease of drug development costs and risks, and improved effectiveness of drug delivery and gene therapy programs through better timed and more customized solutions.

  7. Investigation of curing rates of bio-based thiol-ene films from diallyl 2,5-furandicaboxylate

    DEFF Research Database (Denmark)

    Larsen, Daniel Bo; Sønderbæk-Jørgensen, Rene; Duus, Jens Ø.

    2018-01-01

    The bio-based monomer, 2,5-furandicarboxylic acid, has been adapted to classic thiol-ene chemistry by derivatization of the acid with allyl alcohol. This new monomer has allowed for the synthesis of new thermoset systems, capable of forming green, sustainable materials through UV-crosslinking. In......The bio-based monomer, 2,5-furandicarboxylic acid, has been adapted to classic thiol-ene chemistry by derivatization of the acid with allyl alcohol. This new monomer has allowed for the synthesis of new thermoset systems, capable of forming green, sustainable materials through UV......-crosslinking. In this study, the synthesis of the new monomer along with thorough kinetic studies of the new thermoset systems are presented. In order to determine kinetic values for the systems, all reactions have been followed by real-time FT-IR. Initially, a study of three different photoinitiators is performed...... on a classic TEMPIC-TATATO system, in order to determine the superior initiator for the new systems. The new monomer is crosslinked with five different thiol compounds in both stoichiometric and off-stoichiometric ratios, yielding an array of bio-based thermosets. The properties of these systems are determined...

  8. Evaluation System for Pesticides (ESPE). 1. Agricultural pesticides

    NARCIS (Netherlands)

    Emans HJB; Beek MA; Linders JBHJ

    1992-01-01

    In this report a risk assessment or evaluation system for agricultural pesticides is presented, which estimates the hazards for man and environment resulting from the use of these pesticides. The evaluation system has also been placed within the context of the Uniform System for the Evaluation of

  9. Feasibility Study for the Use of Green, Bio-Based, Efficient Reactive Sorbent Material to Neutralize Chemical Warfare Agents

    Science.gov (United States)

    2012-08-02

    REPORT Feasibility study for the use of green, bio-based, efficient reactive sorbent material to neutralize chemical warfare agents 14. ABSTRACT 16...way cellulose, lignin and hemicelluloses interact as well as whole wood dissolution occurs in ILs. The present project was conducted to 1. REPORT...Feasibility study for the use of green, bio-based, efficient reactive sorbent material to neutralize chemical warfare agents Report Title ABSTRACT Over the

  10. Application of XAD-2 resin-based passive samplers and SPME–GC–MS/MS analysis for the monitoring of spatial and temporal variations of atmospheric pesticides in Luxembourg

    International Nuclear Information System (INIS)

    Schummer, Claude; Tuduri, Ludovic; Briand, Olivier; Appenzeller, Brice M.; Millet, Maurice

    2012-01-01

    Passive air sampling has been shown to be a very interesting alternative to high-volume sampling by overcoming its disadvantages (size, weight, expensiveness). However, to date, only limited data is available about passive air sampling of current-use pesticides. In order to test if passive samplers allow monitoring of spatial and temporal variations of atmospheric pesticide concentrations, five XAD-2-resin based passive air samplers were deployed at five locations in Luxembourg. Samplers were analyzed using accelerated solvent extraction coupled to solid-phase microextraction and gas chromatography with tandem mass spectrometry. Collected data was used to study the spatial and temporal variations of the concentrations of the compounds. Twenty two pesticides were detected between March and October, while no pesticides were detected from November to February. Highest concentrations were measured on the rural sites, suggesting that the used XAD-2 resin-based passive samplers allow the simultaneous monitoring of multiple current-use pesticides and identifying spatial and temporal variations. - Highlights: ► XAD-2 passive sampling of current-used pesticides. ► Coupling of ASE and SPME–GC–MS/MS for the analysis of pesticides in XAD-2 passive sampling. ► XAD-2 passive samplers suitable for current-used pesticides atmospheric sampling. ► XAD-2 passive samplers suitable for spatial and temporal atmospheric concentrations variations. - XAD-2 passive sampling of current-use pesticides in the atmosphere.

  11. Bio-films and processes of bio-corrosion and bio-deterioration in oil-and gas-processing industry

    Energy Technology Data Exchange (ETDEWEB)

    Kholodenko, V.P.; Irkhina, I.A.; Chugunov, V.A.; Rodin, V.B.; Zhigletsova, S.K.; Yermolenko, Z.M.; Rudavin, V.V. [State Research Center for Applied Microbiology, Obolensk, Moscow region (Russian Federation)

    2004-07-01

    As a rule, oil- and gas-processing equipment and pipelines are attacked by different microorganisms. Their vital ability determines processes of bio-deterioration and bio-corrosion that lead often to technological accidents and severe environmental contamination. Bio-films presenting a complex association of different microorganisms and their metabolites are responsible for most of damages. In this context, to study the role bio-films may play in processes of bio-damages and in efficacy of protective measures is important. We have developed method of culturing bio-films on the surface of metal coupons by using a natural microbial association isolated from oil-processing sites. Simple and informative methods of determining microbiological parameters of bio-films required to study bio-corrosion processes are also developed. In addition, a method of electron microscopic analysis of bio-films and pitting corrosion is offered. Using these methods, we conducted model experiments to determine the dynamics of corrosion processes depending on qualitative and quantitative composition of bio-films, aeration conditions and duration of the experiment. A harmful effect of soil bacteria and micro-mycetes on different pipeline coatings was also investigated. Experiments were conducted within 3-6 months and revealed degrading action of microorganisms. This was confirmed by axial tension testing of coatings. All these approaches will be used for further development of measures to protect gas- and oil-processing equipment and pipelines against bio-corrosion and bio-damages (first of all biocides). (authors)

  12. WCP-RNN : a novel RNN-based approach for Bio-NER in Chinese EMRs: Paper ID: FC_17_25

    NARCIS (Netherlands)

    Li, Jianqiang; Zhao, Shenhe; Yang, Jijiang; Huang, Zhisheng; Liu, Bo; Chen, Shi; Pan, Hui; Wang, Qing

    2018-01-01

    Deep learning has achieved remarkable success in a wide range of domains. However, it has not been comprehensively evaluated as a solution for the task of Chinese biomedical named entity recognition (Bio-NER). The traditional deep-learning approach for the Bio-NER task is usually based on the

  13. Degradation kinetics of seven organophosphorus pesticides in milk during yoghurt processing

    Directory of Open Access Journals (Sweden)

    LI-YING BO

    2011-03-01

    Full Text Available Bovine milk spiked with seven organophosphorus pesticides, i.e., dimethoate, fenthion, malathion, methyl parathion, monocrotophos, phorate and trichlorphon, was fermented at 42 °C with commercial directed vat set (DVS starters to investigate the degradation kinetics of the pesticides during yoghurt processing. The spiked pesticides were extracted from the prepared samples with an organic solvent and analyzed by gas chromatography after purification. Based on published results that the degradation kinetics of pesticides is first order, the rate constant of degradation and the half live period of the pesticides were calculated. The results indicated that degradation of the pesticides in milk during yoghurt processing were enhanced by one or both starters, except for malathion, and the two commercial DVS starters had different influences on the degradation kinetics of the pesticides.

  14. Treatment of pesticide wastewater by moving-bed biofilm reactor combined with Fenton-coagulation pretreatment

    Energy Technology Data Exchange (ETDEWEB)

    Chen Sheng [School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090 (China)]. E-mail: hitchensheng@126.com; Sun Dezhi [School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090 (China); Chung, J.-S. [School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090 (China); Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784 (Korea, Republic of)

    2007-06-01

    In order to treat pesticide wastewater having high chemical oxygen demand (COD) value and poor biodegradability, Fenton-coagulation process was first used to reduce COD and improve biodegradability and then was followed by biological treatment. Optimal experimental conditions for the Fenton process were determined to be Fe{sup 2+} concentration of 40 mmol/L and H{sub 2}O{sub 2} dose of 97 mmol/L at initial pH 3. The interaction mechanism of organophosphorous pesticide and hydroxyl radicals was suggested to be the breakage of the P=S double bond and formation of sulfate ions and various organic intermediates, followed by formation of phosphate and consequent oxidation of intermediates. For the subsequent biological treatment, 3.2 g/L Ca(OH){sub 2} was added to adjust the pH and further coagulate the pollutants. The COD value could be evidently decreased from 33,700 to 9300 mg/L and the ratio of biological oxygen demand (BOD{sub 5}) to COD of the wastewater was enhanced to over 0.47 by Fenton oxidation and coagulation. The pre-treated wastewater was then subjected to biological oxidation by using moving-bed biofilm reactor (MBBR) inside which tube chip type bio-carriers were fluidized upon air bubbling. Higher than 85% of COD removal efficiency could be achieved when the bio-carrier volume fraction was kept more than 20% by feeding the pretreated wastewater containing 3000 mg/L of inlet COD at one day of hydraulic retention time (HRT), but a noticeable decrease in the COD removal efficiency when the carrier volume was decreased down to 10%, only 72% was observed. With the improvement of biodegradability by using Fenton pretreatment, also due to the high concentration of biomass and high biofilm activity using the fluidizing bio-carriers, high removal efficiency and stable operation could be achieved in the biological process even at a high COD loading of 37.5 gCOD/(m{sup 2} carrier day)

  15. Treatment of pesticide wastewater by moving-bed biofilm reactor combined with Fenton-coagulation pretreatment

    International Nuclear Information System (INIS)

    Chen Sheng; Sun Dezhi; Chung, J.-S.

    2007-01-01

    In order to treat pesticide wastewater having high chemical oxygen demand (COD) value and poor biodegradability, Fenton-coagulation process was first used to reduce COD and improve biodegradability and then was followed by biological treatment. Optimal experimental conditions for the Fenton process were determined to be Fe 2+ concentration of 40 mmol/L and H 2 O 2 dose of 97 mmol/L at initial pH 3. The interaction mechanism of organophosphorous pesticide and hydroxyl radicals was suggested to be the breakage of the P=S double bond and formation of sulfate ions and various organic intermediates, followed by formation of phosphate and consequent oxidation of intermediates. For the subsequent biological treatment, 3.2 g/L Ca(OH) 2 was added to adjust the pH and further coagulate the pollutants. The COD value could be evidently decreased from 33,700 to 9300 mg/L and the ratio of biological oxygen demand (BOD 5 ) to COD of the wastewater was enhanced to over 0.47 by Fenton oxidation and coagulation. The pre-treated wastewater was then subjected to biological oxidation by using moving-bed biofilm reactor (MBBR) inside which tube chip type bio-carriers were fluidized upon air bubbling. Higher than 85% of COD removal efficiency could be achieved when the bio-carrier volume fraction was kept more than 20% by feeding the pretreated wastewater containing 3000 mg/L of inlet COD at one day of hydraulic retention time (HRT), but a noticeable decrease in the COD removal efficiency when the carrier volume was decreased down to 10%, only 72% was observed. With the improvement of biodegradability by using Fenton pretreatment, also due to the high concentration of biomass and high biofilm activity using the fluidizing bio-carriers, high removal efficiency and stable operation could be achieved in the biological process even at a high COD loading of 37.5 gCOD/(m 2 carrier day)

  16. Composting plant conversion for the production of bio based products; Konversion eines Kompostwerkes zur Herstellung biobasierter Produkte

    Energy Technology Data Exchange (ETDEWEB)

    Hoffmann, Marc [Universitaetsklinikum Jena (Germany). Stabsstelle Umweltschutz

    2013-03-15

    The intention behind this paper is to explore the potential of extracting bio based products such as lactic acid and further organic acid compounds during a successful composting process, by inserting an additional pre-treatment level into the existing process. The fundamental idea of extracting bio based products and biogas is based on the extension of a composting plant with an anaerobic intermediate level of maceration and a bypass reactor as a potential bio-refinery. For the extraction of carboxylic acid out of the macerated substance the principle of electrodialysis on a laboratory scale can be successfully verified by means of concentration of free acids. The concluding assessment of the composting plant Darmstadt-Kranichstein with regards to its potential shows that further examination on a large scale for the extraction of biobased products using biowaste is deemed to be appropriate on material and energetic consideration. The study demonstrates the potential for a combined aerobic/anaerobic plant with composting, renewable energy and secondary raw materials generation. (orig.)

  17. Extraction of medium chain fatty acids from organic municipal waste and subsequent production of bio-based fuels.

    Science.gov (United States)

    Kannengiesser, Jan; Sakaguchi-Söder, Kaori; Mrukwia, Timo; Jager, Johannes; Schebek, Liselotte

    2016-01-01

    This paper provides an overview on investigations for a new technology to generate bio-based fuel additives from bio-waste. The investigations are taking place at the composting plant in Darmstadt-Kranichstein (Germany). The aim is to explore the potential of bio-waste as feedstock in producing different bio-based products (or bio-based fuels). For this investigation, a facultative anaerobic process is to be integrated into the normal aerobic waste treatment process for composting. The bio-waste is to be treated in four steps to produce biofuels. The first step is the facultative anaerobic treatment of the waste in a rotting box namely percolate to generate a fatty-acid rich liquid fraction. The Hydrolysis takes place in the rotting box during the waste treatment. The organic compounds are then dissolved and transferred into the waste liquid phase. Browne et al. (2013) describes the hydrolysis as an enzymatically degradation of high solid substrates to soluble products which are further degraded to volatile fatty acids (VFA). This is confirmed by analytical tests done on the liquid fraction. After the percolation, volatile and medium chain fatty acids are found in the liquid phase. Concentrations of fatty acids between 8.0 and 31.5 were detected depending on the nature of the input material. In the second step, a fermentation process will be initiated to produce additional fatty acids. Existing microorganism mass is activated to degrade the organic components that are still remaining in the percolate. After fermentation the quantity of fatty acids in four investigated reactors increased 3-5 times. While fermentation mainly non-polar fatty acids (pentanoic to octanoic acid) are build. Next to the fermentation process, a chain-elongation step is arranged by adding ethanol to the fatty acid rich percolate. While these investigations a chain-elongation of mainly fatty acids with pair numbers of carbon atoms (acetate, butanoic and hexanoic acid) are demonstrated. After

  18. Safe Disposal of Pesticides

    Science.gov (United States)

    ... Toxics Environmental Information by Location Greener Living Health Land, Waste, and Cleanup Lead Mold Pesticides Radon Science ... or www.earth911.com . Think before disposing of extra pesticides and containers: Never reuse empty pesticide containers. ...

  19. A multi-scale, multi-disciplinary approach for assessing the technological, economic and environmental performance of bio-based chemicals.

    Science.gov (United States)

    Herrgård, Markus; Sukumara, Sumesh; Campodonico, Miguel; Zhuang, Kai

    2015-12-01

    In recent years, bio-based chemicals have gained interest as a renewable alternative to petrochemicals. However, there is a significant need to assess the technological, biological, economic and environmental feasibility of bio-based chemicals, particularly during the early research phase. Recently, the Multi-scale framework for Sustainable Industrial Chemicals (MuSIC) was introduced to address this issue by integrating modelling approaches at different scales ranging from cellular to ecological scales. This framework can be further extended by incorporating modelling of the petrochemical value chain and the de novo prediction of metabolic pathways connecting existing host metabolism to desirable chemical products. This multi-scale, multi-disciplinary framework for quantitative assessment of bio-based chemicals will play a vital role in supporting engineering, strategy and policy decisions as we progress towards a sustainable chemical industry. © 2015 Authors; published by Portland Press Limited.

  20. The first international leprosy conference, Berlin, 1897: the politics of segregation.

    Science.gov (United States)

    Pandya, S S

    2004-01-01

    The present paper examines the first attempts to internationalise the problem of leprosy, a subject hitherto overlooked by historians of imperialism and disease. The last decade of the nineteenth century saw many in the civilised countries of the imperialist West gripped by a paranoia about an invasion of leprosy via germ-laden immigrants and returning expatriates who had acquired the infection in leprosy endemic colonial possessions. Such alarmists clamoured for the adoption of vigorous leper segregation policies in such colonies. But the contagiousness of leprosy did not go unquestioned by other westerners. The convocation in Berlin of the first international meeting on leprosy revealed the interplay of differing and sometimes incompatible views about the containment of leprosy by segregation. The roles of officials from several countries, as well as the roles of five protagonists (Albert Ashmead, Jules Goldschmidt, Edvard Ehlers. Armauer Hansen, and Phineas Abraham) in the shaping of the Berlin Conference are here examined.

  1. Understanding Pesticide Risks: Toxicity and Formulation

    OpenAIRE

    Muntz, Helen; Miller, Rhonda; Alston, Diane

    2016-01-01

    This fact sheet provides information about pesticide risks to human health, primary means of pesticide exposure, standardized measures of pesticide toxicity, pesticide signal words and type of pesticide formulations.

  2. Pesticide Environmental Stewardship Program (PESP)

    Science.gov (United States)

    PESP is an EPA partnership program that works with the nation's pesticide-user community to promote IPM practices. Pesticide users can reduce the risks from pests and pesticides. Members include organizations and companies in the pesticide-user community.

  3. To Save a City: The Berlin Airlift, 1948-1949

    Science.gov (United States)

    1998-01-01

    Berliners gainfully employed , the blockade threw some 10 percent out of work. Since the unemployed received a ration card, this factor had little effect...Organization, these units employed large numbers of German laborers. Similarly, the Forward Airfield Supply Organization accomplished all cargo handling in...use as coal sacks. Additionally, EUCOM pro- cured jute bags in England and in Switzerland , although these would last only from three to five trips

  4. A sensitive acetylcholinesterase biosensor based on gold nanorods modified electrode for detection of organophosphate pesticide.

    Science.gov (United States)

    Lang, Qiaolin; Han, Lei; Hou, Chuantao; Wang, Fei; Liu, Aihua

    2016-08-15

    A sensitive amperometric acetylcholinesterase (AChE) biosensor, based on gold nanorods (AuNRs), was developed for the detection of organophosphate pesticide. Compared with Au@Ag heterogeneous NRs, AuNRs exhibited excellent electrocatalytic properties, which can electrocatalytically oxidize thiocholine, the hydrolysate of acetylthiocholine chloride (ATCl) by AChE at +0.55V (vs. SCE). The AChE/AuNRs/GCE biosensor was fabricated on basis of the inhibition of AChE activity by organophosphate pesticide. The biosensor could detect paraoxon in the linear range from 1nM to 5μM and dimethoate in the linear range from 5nM to 1μM, respectively. The detection limits of paraoxon and dimethoate were 0.7nM and 3.9nM, which were lower than the reported AChE biosensor. The proposed biosensor could restore to over 95% of its original current, which demonstrated the good reactivation. Moreover, the biosensor can be applicable to real water sample measurement. Thus, the biosensor exhibited low applied potential, high sensitivity and good stability, providing a promising tool for analysis of pesticides. Copyright © 2016 Elsevier B.V. All rights reserved.

  5. Endangered Species: Pesticide Restrictions

    Science.gov (United States)

    Our goal is to protect threatened and endangered species and their habitats, without placing unnecessary burden on agriculture and pesticide users. Pesticide limitations are developed to ensure safe use of pesticides in order to meet this goal.

  6. Bio-composites : opportunities for value-added biobased materials

    Energy Technology Data Exchange (ETDEWEB)

    Drzal, L.T. [Michigan State Univ., East Lansing, MI (United States). Dept. of Chemical Engineering and Materials Science]|[Michigan State Univ., East Lansing, MI (United States). Composite Materials and Structures Center

    2003-07-01

    In order to reduce dependency on foreign oil, there is a growing need to develop and commercialize new bio-based green materials and technologies that can produce bio-based structural materials that are competitive with current synthetic products. The use of bio-based products would also improve the environment and create new opportunities for the agricultural economy. This paper described ongoing research into bio-based materials and products that replace petroleum-based products. In particular, it examined the use of biocomposites made by embedding natural/biofibers such as kenaf, hemp, flax, jute, henequen, pineapple leaf fiber, corn stalk fibers and native Michigan grasses into petroleum-derived traditional plastics such as polypropylene, unsaturated polyesters and epoxies. It also examines the use of green biocomposites developed by embedding these bio-fibers into renewable resource-based bioplastics such as cellulosic plastics and soy-based plastics. New processing methods that combine biofibers with plastics were needed to produce the biocomposites with desirable mechanical properties. The study showed that biofiber reinforced petroleum-based plastic biocomposites can produce a structural material that offers a balance between ecology, economy and technology. The potential for using these materials for automotive and building materials was also presented. 1 tab., 28 figs.

  7. Multi-scale cellulose based new bio-aerogel composites with thermal super-insulating and tunable mechanical properties.

    Science.gov (United States)

    Seantier, Bastien; Bendahou, Dounia; Bendahou, Abdelkader; Grohens, Yves; Kaddami, Hamid

    2016-03-15

    Bio-composite aerogels based on bleached cellulose fibers (BCF) and cellulose nanoparticles having various morphological and physico-chemical characteristics are prepared by a freeze-drying technique and characterized. The various composite aerogels obtained were compared to a BCF aerogel used as the reference. Severe changes in the material morphology were observed by SEM and AFM due to a variation of the cellulose nanoparticle properties such as the aspect ratio, the crystalline index and the surface charge density. BCF fibers form a 3D network and they are surrounded by the cellulose nanoparticle thin films inducing a significant reduction of the size of the pores in comparison with a neat BCF based aerogel. BET analyses confirm the appearance of a new organization structure with pores of nanometric sizes. As a consequence, a decrease of the thermal conductivities is observed from 28mWm(-1)K(-1) (BCF aerogel) to 23mWm(-1)K(-1) (bio-composite aerogel), which is below the air conductivity (25mWm(-1)K(-1)). This improvement of the insulation properties for composite materials is more pronounced for aerogels based on cellulose nanoparticles having a low crystalline index and high surface charge (NFC-2h). The significant improvement of their insulation properties allows the bio-composite aerogels to enter the super-insulating materials family. The characteristics of cellulose nanoparticles also influence the mechanical properties of the bio-composite aerogels. A significant improvement of the mechanical properties under compression is obtained by self-organization, yielding a multi-scale architecture of the cellulose nanoparticles in the bio-composite aerogels. In this case, the mechanical property is more dependent on the morphology of the composite aerogel rather than the intrinsic characteristics of the cellulose nanoparticles. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Pesticide tolerant and phosphorus solubilizing Pseudomonas sp. strain SGRAJ09 isolated from pesticides treated Achillea clavennae rhizosphere soil.

    Science.gov (United States)

    Rajasankar, R; Manju Gayathry, G; Sathiavelu, A; Ramalingam, C; Saravanan, V S

    2013-05-01

    In this study, an attempt was made to identify an effective phosphate solubilizing bacteria from pesticide polluted field soil. Based on the formation of solubilization halo on Pikovskaya's agar, six isolates were selected and screened for pesticide tolerance and phosphate (P) solubilization ability through liquid assay. The results showed that only one strain (SGRAJ09) obtained from Achillea clavennae was found to tolerate maximum level of the pesticides tested and it was phylogenetically identified as Pseudomonas sp. It possessed a wide range of pesticide tolerance, ranging from 117 μg mL(-1) for alphamethrin to 2,600 μg mL(-1) for endosulfan. The available P concentrations increased with the maximum and double the maximum dose of monocrotophos and imidacloprid, respectively. On subjected to FT-IR and HPLC analysis, the presence of organic acids functional group in the culture broth and the production of gluconic acid as dominant acid aiding the P solubilization were identified. On comparison with control broth, monocrotophos and imidacloprid added culture broth showed quantitatively high organic acids production. In addition to gluconic acid production, citric and acetic acids were also observed in the pesticide amended broth. Furthermore, the Pseudomonas sp. strain SGRAJ09 possessed all the plant growth promoting traits tested. In presence of monocrotophos and imidacloprid, its plant growth promoting activities were lower than that of the pesticides unamended treatment.

  9. Fabrication of fluorescence-based biosensors from functionalized CdSe and CdTe quantum dots for pesticide detection

    International Nuclear Information System (INIS)

    Chi Tran, Thi Kim; Vu, Duc Chinh; Thuy Ung, Thi Dieu; Nguyen, Hai Yen; Nguyen, Ngoc Hai; Dao, Tran Cao; Pham, Thu Nga; Nguyen, Quang Liem

    2012-01-01

    This paper presents the results on the fabrication of highly sensitive fluorescence biosensors for pesticide detection. The biosensors are actually constructed from the complex of quantum dots (QDs), acetylcholinesterase (AChE) and acetylthiocholine (ATCh). The biosensor activity is based on the change of luminescence from CdSe and CdTe QDs with pH, while the pH is changed with the hydrolysis rate of ATCh catalyzed by the enzyme AChE, whose activity is specifically inhibited by pesticides. Two kinds of QDs were used to fabricate our biosensors: (i) CdSe QDs synthesized in high-boiling non-polar organic solvent and then functionalized by shelling with two monolayers (2-ML) of ZnSe and eight monolayers (8-ML) of ZnS and finally capped with 3-mercaptopropionic acid (MPA) to become water soluble; and (ii) CdTe QDs synthesized in aqueous phase then shelled with CdS. For normal checks the fabricated biosensors could detect parathion methyl (PM) pesticide at very low contents of ppm with the threshold as low as 0.05 ppm. The dynamic range from 0.05 ppm to 1 ppm for the pesticide detection could be expandable by increasing the AChE amount in the biosensor. (paper)

  10. Bio-prospecting of distillery yeasts as bio-control and bio-remediation agents.

    Science.gov (United States)

    Ubeda, Juan F; Maldonado, María; Briones, Ana I; Francisco, J Fernández; González, Francisco J

    2014-05-01

    This work constitutes a preliminary study in which the capacity of non-Saccharomyces yeasts isolated from ancient distilleries as bio-control agents against moulds and in the treatment of waste waters contaminated by heavy metals-i.e. bio-remediation-is shown. In the first control assays, antagonist effect between non-Saccharomyces yeasts, their extracts and supernatants against some moulds, analysing the plausible (not exhaustive) involved factors were qualitatively verified. In addition, two enzymatic degrading properties of cell wall plant polymers, quitinolitic and pectinolitic, were screened. Finally, their use as agents of bio-remediation of three heavy metals (cadmium, chromium and lead) was analysed semi-quantitatively. The results showed that all isolates belonging to Pichia species effectively inhibited all moulds assayed. Moreover, P. kudriavzevii is a good candidate for both bio-control and bio-remediation because it inhibited moulds and accumulated the major proportion of the three tested metals.

  11. SPEAR indicates pesticide effects in streams - Comparative use of species- and family-level biomonitoring data

    International Nuclear Information System (INIS)

    Beketov, M.A.; Foit, K.; Schaefer, R.B.; Schriever, C.A.; Sacchi, A.; Capri, E.; Biggs, J.; Wells, C.; Liess, M.

    2009-01-01

    To detect effects of pesticides on non-target freshwater organisms the Species at risk (SPEAR pesticides ) bioindicator based on biological traits was previously developed and successfully validated over different biogeographical regions of Europe using species-level data on stream invertebrates. Since many freshwater biomonitoring programmes have family-level taxonomic resolution we tested the applicability of SPEAR pesticides with family-level biomonitoring data to indicate pesticide effects in streams (i.e. insecticide toxicity of pesticides). The study showed that the explanatory power of the family-level SPEAR(fm) pesticides is not significantly lower than the species-level index. The results suggest that the family-level SPEAR(fm) pesticides is a sensitive, cost-effective, and potentially European-wide bioindicator of pesticide contamination in flowing waters. Class boundaries for SPEAR pesticides according to EU Water Framework Directive are defined to contribute to the assessment of ecological status of water bodies. - We show that SPEAR pesticides can be based on family-level biomonitoring data and is applicable for large-scale monitoring programmes to detect and quantify pesticide contamination.

  12. SPEAR indicates pesticide effects in streams - Comparative use of species- and family-level biomonitoring data

    Energy Technology Data Exchange (ETDEWEB)

    Beketov, M.A., E-mail: mikhail.beketov@ufz.d [UFZ - Helmholtz Centre for Environmental Research, Department System Ecotoxicology, Permoserstrasse 15, D-04318 Leipzig (Germany); Foit, K.; Schaefer, R.B.; Schriever, C.A. [UFZ - Helmholtz Centre for Environmental Research, Department System Ecotoxicology, Permoserstrasse 15, D-04318 Leipzig (Germany); Sacchi, A.; Capri, E. [Universita Cattolica del Sacro Cuore, Istituto di Chimica Agraria ed Ambientale, Piacenza (Italy); Biggs, J. [Pond Conservation, c/o Oxford Brookes University, Headington (United Kingdom); Wells, C. [Environment Agency of England and Wales, Science Department, Bristol (United Kingdom); Liess, M. [UFZ - Helmholtz Centre for Environmental Research, Department System Ecotoxicology, Permoserstrasse 15, D-04318 Leipzig (Germany)

    2009-06-15

    To detect effects of pesticides on non-target freshwater organisms the Species at risk (SPEAR{sub pesticides}) bioindicator based on biological traits was previously developed and successfully validated over different biogeographical regions of Europe using species-level data on stream invertebrates. Since many freshwater biomonitoring programmes have family-level taxonomic resolution we tested the applicability of SPEAR{sub pesticides} with family-level biomonitoring data to indicate pesticide effects in streams (i.e. insecticide toxicity of pesticides). The study showed that the explanatory power of the family-level SPEAR(fm){sub pesticides} is not significantly lower than the species-level index. The results suggest that the family-level SPEAR(fm){sub pesticides} is a sensitive, cost-effective, and potentially European-wide bioindicator of pesticide contamination in flowing waters. Class boundaries for SPEAR{sub pesticides} according to EU Water Framework Directive are defined to contribute to the assessment of ecological status of water bodies. - We show that SPEAR{sub pesticides} can be based on family-level biomonitoring data and is applicable for large-scale monitoring programmes to detect and quantify pesticide contamination.

  13. Enlightening City Childhoods: Walter Benjamin's Berlin and Erich Kästner's Dresden

    Science.gov (United States)

    Lathey, Gillian

    2016-01-01

    Walter Benjamin, cultural critic and philosopher, compiled "Berlin childhood around 1900" (trans. Howard Eiland, 2006) while in exile from Germany in the early 1930s, filtering impressions of a privileged childhood through a politicised adult consciousness. Erich Kästner, journalist, poet, satirist and author of the children's classic…

  14. Comments on the art and research project ‘The division of the earth: tableaux on the legal synopses of the Berlin Africa conference’

    Directory of Open Access Journals (Sweden)

    Dierk Schmidt

    2014-10-01

    Full Text Available Is pictorial language able to convey a juridical abstraction? This co-authored text addresses that question in the context of the geo-political division of Africa after the Berlin Africa Conference (Congo Conference, as a means to conceptualise colonial rule in 1884/85 – and its manifold grave consequences – as a historical by-product of Europe’s political and aesthetic modernity. Is there any value in representing the image of genocide, (while acknowledging the ‘impossibility’ of its representation? With these issues in mind, lawyer Malte Jaguttis and artist Dierk Schmidt offer a commentary based on their project, ‘The division of the earth — Tableaux on the legal synopses of the Berlin Africa Conference’.

  15. Computing Pathways in Bio-Models Derived from Bio-Science Text Sources

    DEFF Research Database (Denmark)

    Andreasen, Troels; Bulskov, Henrik; Nilsson, Jørgen Fischer

    2015-01-01

    This paper outlines a system, OntoScape, serving to accomplish complex inference tasks on knowledge bases and bio-models derived from life-science text corpora. The system applies so-called natural logic, a form of logic which is readable for humans. This logic affords ontological representations...... of complex terms appearing in the text sources. Along with logical propositions, the system applies a semantic graph representation facilitating calculation of bio-pathways. More generally, the system aords means of query answering appealing to general and domain specic inference rules....

  16. Personal exposure to pesticide among workers engaged in pesticide container recycling operations.

    Science.gov (United States)

    Guidotti, T L; Yoshida, K; Clough, V

    1994-12-01

    Pesticide container handling operations in western Canada were examined to determine the exposure of workers to residual pesticide in sorting, metal-container crushing, metal-container shredding, plastic-container shredding, metal washing, and metal melting. Environmental exposure monitoring and biological monitoring were applied, including measurement of pesticide deposition density on outer clothing (test coveralls and other protective wear), deposition on fabric and gauze patches under the outer clothing, inhalation of airborne pesticide residues, dislodgement of pesticide residues by hand washing, and pre- and postexposure urinary excretion of pesticide (2,4-D). Exposure levels were highly variable; some variability was accounted for by work practices or lapses in protection. The highest levels of exposure were observed for metal washing, metal crushing, and metal shredding; sorting and plastic shredding were intermediate, and metal melting was associated with very little exposure. Urinary 2,4-D excretion, as an indicator of internal dose, correlated most closely with exposure by the inhalation route, and both were highest for metal washing and shredding. Deposition of pesticide on garments was highest for metal crushing. Melting of washed metal does not appear to present a significant hazard of exposure. Recommendations are proposed for the protection of workers emphasizing health and safety guidelines, worker education, personal hygiene, exposure and health monitoring, and record-keeping, and specific recommendations for each process. These recommendations apply to all pesticide container recycling operations except melting of washed metal containers.

  17. Comparison of the Berlin definition with the American European consensus definition for acute respiratory distress syndrome in burn patients.

    Science.gov (United States)

    Bordes, Julien; Lacroix, Guillaume; Esnault, Pierre; Goutorbe, Philippe; Cotte, Jean; Dantzer, Eric; Meaudre, Eric

    2014-06-01

    Acute respiratory distress syndrome (ARDS) is a leading cause of mortality in burn patients. Smoke inhalation, pneumonia and inflammation process are the major causes of ARDS in burn patients. The American European Consensus Conference (AECC) definition proposed in 1994 has recently been revised by the Berlin definition. Our objective was to describe the epidemiology of ARDS comparing the Berlin definition with the AECC definition in a retrospective cohort of burn patients. We reviewed admitted burn adult patients for a two year period, and investigated patient who received mechanical ventilation for more than 48 h and in whom pneumonia was diagnosed. 40 patients were analyzed. According to the AECC definition, 11 patients met criteria for ALI (27.5%), and 29 patients for ARDS (72.5%). According to the Berlin definition, all patients met criteria for ARDS: 4 (10%) for a severe ARDS, 25 (62.5%) for a moderate ARDS, 11 (27.5%) for a mild ARDS. Inhalation injury was diagnosed in 10 patients (25%). Categorizing patients with the Berlin definition showed statistically significative difference of mortality within the three groups, but not with the AECC definition. The Berlin definition seems to be more accurate than the AECC definition to assess the severity of ARDS in term of outcome in burn patients. This definition may facilitate prompt recognition of ARDS in burn patients, and promote protective ventilation strategy to a larger number of patients. Copyright © 2014 Elsevier Ltd and ISBI. All rights reserved.

  18. Impacts of pesticides in a Central California estuary.

    Science.gov (United States)

    Anderson, Brian; Phillips, Bryn; Hunt, John; Siegler, Katie; Voorhees, Jennifer; Smalling, Kelly; Kuivila, Kathy; Hamilton, Mary; Ranasinghe, J Ananda; Tjeerdema, Ron

    2014-03-01

    Recent and past studies have documented the prevalence of pyrethroid and organophosphate pesticides in urban and agricultural watersheds in California. While toxic concentrations of these pesticides have been found in freshwater systems, there has been little research into their impacts in marine receiving waters. Our study investigated pesticide impacts in the Santa Maria River estuary, which provides critical habitat to numerous aquatic, terrestrial, and avian species on the central California coast. Runoff from irrigated agriculture constitutes a significant portion of Santa Maria River flow during most of the year, and a number of studies have documented pesticide occurrence and biological impacts in this watershed. Our study extended into the Santa Maria watershed coastal zone and measured pesticide concentrations throughout the estuary, including the water column and sediments. Biological effects were measured at the organism and community levels. Results of this study suggest the Santa Maria River estuary is impacted by current-use pesticides. The majority of water samples were highly toxic to invertebrates (Ceriodaphnia dubia and Hyalella azteca), and chemistry evidence suggests toxicity was associated with the organophosphate pesticide chlorpyrifos, pyrethroid pesticides, or mixtures of both classes of pesticides. A high percentage of sediment samples were also toxic in this estuary, and sediment toxicity occurred when mixtures of chlorpyrifos and pyrethroid pesticides exceeded established toxicity thresholds. Based on a Relative Benthic Index, Santa Maria estuary stations where benthic macroinvertebrate communities were assessed were degraded. Impacts in the Santa Maria River estuary were likely due to the proximity of this system to Orcutt Creek, the tributary which accounts for most of the flow to the lower Santa Maria River. Water and sediment samples from Orcutt Creek were highly toxic to invertebrates due to mixtures of the same pesticides measured

  19. Preparation and Properties of Novel Thermoplastic Vulcanizate Based on Bio-Based Polyester/Polylactic Acid, and Its Application in 3D Printing

    Directory of Open Access Journals (Sweden)

    Yu Gao

    2017-12-01

    Full Text Available Thermoplastic vulcanizate (TPV combines the high elasticity of elastomers and excellent processability of thermoplastics. Novel bio-based TPV based on poly (lactide (PLA and poly (1,4-butanediol/2,3-butanediol/succinate/itaconic acid (PBBSI were prepared in this research. PBBSI copolyesters were synthesized by melting polycondensation, and the molecular weights, chemical structures and compositions of the copolyesters were characterized by GPC, NMR and FTIR. Bio-based 2,3-butanediol was successfully incorporated to depress the crystallization behavior of the PBBSI copolyester. With an increase of 2,3-butanediol content, the PBBSI copolyester transformed from a rigid plastic to a soft elastomer. Furthermore, the obtained TPV has good elasticity and rheological properties, which means it can be applied as a 3D-printing material.

  20. Pesticide Program Dialogue Committee and Pesticide Regulatory Reform Meetings

    Science.gov (United States)

    EPA’s Office of Pesticide Programs will hold a public meeting of the Pesticide Program Dialogue Committee (PPDC) on Wednesday, May 3, from 9:00 a.m. to 4:45 p.m., and on Thursday, May 4, from 8:30 a.m. to noon.

  1. Pesticide Exposure in Children

    Science.gov (United States)

    Roberts, James R.; Karr, Catherine J.

    2018-01-01

    Pesticides are a collective term for a wide array of chemicals intended to kill unwanted insects, plants, molds, and rodents. Food, water, and treatment in the home, yard, and school are all potential sources of children’s exposure. Exposures to pesticides may be overt or subacute, and effects range from acute to chronic toxicity. In 2008, pesticides were the ninth most common substance reported to poison control centers, and approximately 45% of all reports of pesticide poisoning were for children. Organophosphate and carbamate poisoning are perhaps the most widely known acute poisoning syndromes, can be diagnosed by depressed red blood cell cholinesterase levels, and have available antidotal therapy. However, numerous other pesticides that may cause acute toxicity, such as pyrethroid and neonicotinoid insecticides, herbicides, fungicides, and rodenticides, also have specific toxic effects; recognition of these effects may help identify acute exposures. Evidence is increasingly emerging about chronic health implications from both acute and chronic exposure. A growing body of epidemiological evidence demonstrates associations between parental use of pesticides, particularly insecticides, with acute lymphocytic leukemia and brain tumors. Prenatal, household, and occupational exposures (maternal and paternal) appear to be the largest risks. Prospective cohort studies link early-life exposure to organophosphates and organochlorine pesticides (primarily DDT) with adverse effects on neurodevelopment and behavior. Among the findings associated with increased pesticide levels are poorer mental development by using the Bayley index and increased scores on measures assessing pervasive developmental disorder, inattention, and attention-deficit/hyperactivity disorder. Related animal toxicology studies provide supportive biological plausibility for these findings. Additional data suggest that there may also be an association between parental pesticide use and adverse birth

  2. Succinic acid production derived from carbohydrates: An energy and greenhouse gas assessment of a platform chemical toward a bio-based economy

    NARCIS (Netherlands)

    Cok, B.|info:eu-repo/dai/nl/371750679; Tsiropoulos, I.; Roes, A.L.|info:eu-repo/dai/nl/303022388; Patel, M.K.|info:eu-repo/dai/nl/18988097X

    2014-01-01

    Bio-based succinic acid has the potential to become a platform chemical, i.e. a key building block for deriving both commodity and high-value chemicals, which makes it an attractive compound in a bio-based economy. A few companies and industrial consortia have begun to develop its industrial

  3. Establishment of a cervical cancer bio-bank for the Chinese population: from project-based sample collection to routine management.

    Science.gov (United States)

    Yang, Ru; Li, Xiong; Zhou, Hang; Jia, Yao; Zhou, Jin; Huang, Kecheng; Tang, Fangxu; Hu, Ting; Shen, Jian; Chen, Zhilan; Wang, Shaoshuai; Sun, Haiying; Guo, Lili; Wang, Lin; Wang, Hui; Ma, Ding; Li, Shuang

    2015-08-01

    There is an increasing need for the establishment of a cervical cancer bio-bank that will facilitate both clinical and basic research. The cervical cancer bio-bank was first established in January 1999 and included two stages. First, a GWAS-based sample collection was conducted with special emphasis on the diagnosis and the retrieval of the corresponding bio-specimens, especially blood samples. Second, clinical data and their corresponding bio-specimens were routinely collected and handled. Notably, these bio-specimens also included samples from Wufeng Tujia Autonomous County, which has the highest incidence of cervical cancer in China. The specimens were collected from patients with cervical cancer and those with cervical intraepithelial neoplasia, while the control samples were collected from normal individuals. With special emphasis on clinical data and blood samples for the GWAS analysis, the collection of other bio-specimens was slow, and the pairing of specimens and clinical data was poor during the first stage. However, in the second stage, the pairing of the clinical data and its corresponding bio-specimens improved. At present, the samples procured and preserved in the bio-bank cover most regions of China and different ethnic groups for both the normal controls and cervical cancer patients of different pathological categories. This bio-bank of cervical cancer specimens from the Chinese population will greatly promote the studies of cervical cancer in China.

  4. Quercetin as natural stabilizing agent for bio-polymer

    Energy Technology Data Exchange (ETDEWEB)

    Morici, Elisabetta [Dipartimento di Ingegneria Chimica, Gestionale, Informatica, Meccanica, Università di Palermo, 90128 Palermo (Italy); Arrigo, Rossella; Dintcheva, Nadka Tzankova [Dipartimento di Ingegneria Civile, Ambientale, Aerospaziale, dei Materiali, Università di Palermo, 90128 Palermo (Italy)

    2014-05-15

    The introduction of antioxidants in polymers is the main way to prevent or delay the degradation process. In particular natural antioxidants receive attention in the food industry also because of their presumed safety. In this work bio-polymers, i.e. a commercial starch-based polymer (Mater-Bi®) and a bio-polyester (PLA), and a bio-polyether (PEO) were additivated with quercetin, a natural flavonoid antioxidants, in order to formulate bio-based films for ecosustainable packaging and outdoor applications. The photo-oxidation behavior of unstabilized and quercetin stabilized films was analyzed and compared with the behavior of films additivated with a commercial synthetic light stabilizer. The quercetin is able to slow down the photo-degradation rate of all bio-polymeric films investigated in similar way to the synthetic stabilizer.

  5. Quercetin as natural stabilizing agent for bio-polymer

    Science.gov (United States)

    Morici, Elisabetta; Arrigo, Rossella; Dintcheva, Nadka Tzankova

    2014-05-01

    The introduction of antioxidants in polymers is the main way to prevent or delay the degradation process. In particular natural antioxidants receive attention in the food industry also because of their presumed safety. In this work bio-polymers, i.e. a commercial starch-based polymer (Mater-Bi®) and a bio-polyester (PLA), and a bio-polyether (PEO) were additivated with quercetin, a natural flavonoid antioxidants, in order to formulate bio-based films for ecosustainable packaging and outdoor applications. The photo-oxidation behavior of unstabilized and quercetin stabilized films was analyzed and compared with the behavior of films additivated with a commercial synthetic light stabilizer. The quercetin is able to slow down the photo-degradation rate of all bio-polymeric films investigated in similar way to the synthetic stabilizer.

  6. Quercetin as natural stabilizing agent for bio-polymer

    International Nuclear Information System (INIS)

    Morici, Elisabetta; Arrigo, Rossella; Dintcheva, Nadka Tzankova

    2014-01-01

    The introduction of antioxidants in polymers is the main way to prevent or delay the degradation process. In particular natural antioxidants receive attention in the food industry also because of their presumed safety. In this work bio-polymers, i.e. a commercial starch-based polymer (Mater-Bi®) and a bio-polyester (PLA), and a bio-polyether (PEO) were additivated with quercetin, a natural flavonoid antioxidants, in order to formulate bio-based films for ecosustainable packaging and outdoor applications. The photo-oxidation behavior of unstabilized and quercetin stabilized films was analyzed and compared with the behavior of films additivated with a commercial synthetic light stabilizer. The quercetin is able to slow down the photo-degradation rate of all bio-polymeric films investigated in similar way to the synthetic stabilizer

  7. 76 FR 41246 - Pesticide Program Dialogue Committee, Pesticide Registration Improvement Act Process Improvement...

    Science.gov (United States)

    2011-07-13

    ... Committee, Pesticide Registration Improvement Act Process Improvement Workgroup; Notice of Public Meeting...) Process Improvement Work Group. EPA plans to meet its ESA consultation obligations through the pesticide... a pesticide during the registration review process. This meeting of the PRIA Process Improvement...

  8. 75 FR 33705 - Pesticide Management and Disposal; Standards for Pesticide Containers and Containment; Change to...

    Science.gov (United States)

    2010-06-15

    ... Pesticide Management and Disposal; Standards for Pesticide Containers and Containment; Change to Labeling... the pesticide container and containment regulations to provide a 4-month extension of the 40 CFR 156... pesticide labels to comply with the label requirements in the container and containment regulations. DATES...

  9. An overview on cellulose-based material in tailoring bio-hybrid nanostructured photocatalysts for water treatment and renewable energy applications.

    Science.gov (United States)

    Mohamed, Mohamad Azuwa; Abd Mutalib, Muhazri; Mohd Hir, Zul Adlan; M Zain, M F; Mohamad, Abu Bakar; Jeffery Minggu, Lorna; Awang, Nor Asikin; W Salleh, W N

    2017-10-01

    A combination between the nanostructured photocatalyst and cellulose-based materials promotes a new functionality of cellulose towards the development of new bio-hybrid materials for various applications especially in water treatment and renewable energy. The excellent compatibility and association between nanostructured photocatalyst and cellulose-based materials was induced by bio-combability and high hydrophilicity of the cellulose components. The electron rich hydroxyl group of celluloses helps to promote superior interaction with photocatalyst. The formation of bio-hybrid nanostructured are attaining huge interest nowadays due to the synergistic properties of individual cellulose-based material and photocatalyst nanoparticles. Therefore, in this review we introduce some cellulose-based material and discusses its compatibility with nanostructured photocatalyst in terms of physical and chemical properties. In addition, we gather information and evidence on the fabrication techniques of cellulose-based hybrid nanostructured photocatalyst and its recent application in the field of water treatment and renewable energy. Copyright © 2017 Elsevier B.V. All rights reserved.

  10. Bio-fuels for the gas turbine: A review

    International Nuclear Information System (INIS)

    Gupta, K.K.; Rehman, A.; Sarviya, R.M.

    2010-01-01

    Due to depletion of fossil fuel, bio-fuels have generated a significant interest as an alternative fuel for the future. The use of bio-fuels to fuel gas turbine seems a viable solution for the problems of decreasing fossil-fuel reserves and environmental concerns. Bio-fuels are alternative fuels, made from renewable sources and having environmental benefit. In recent years, the desire for energy independence, foreseen depletion of nonrenewable fuel resources, fluctuating petroleum fuel costs, the necessity of stimulating agriculture based economy, and the reality of climate change have created an interest in the development of bio-fuels. The application of bio-fuels in automobiles and heating applications is increasing day by day. Therefore the use of these fuels in gas turbines would extend this application to aviation field. The impact of costly petroleum-based aviation fuel on the environment is harmful. So the development of alternative fuels in aviation is important and useful. The use of liquid and gaseous fuels from biomass will help to fulfill the Kyoto targets concerning global warming emissions. In addition, to reduce exhaust emission waste gases and syngas, etc., could be used as a potential gas turbine fuel. The term bio-fuel is referred to alternative fuel which is produced from biomass. Such fuels include bio-diesel, bio-ethanol, bio-methanol, pyrolysis oil, biogas, synthetic gas (dimethyl ether), hydrogen, etc. The bio-ethanol and bio-methanol are petrol additive/substitute. Bio-diesel is an environment friendly alternative liquid fuel for the diesel/aviation fuel. The gas turbine develops steady flame during its combustion; this feature gives a flexibility to use alternative fuels. Therefore so the use of different bio-fuels in gas turbine has been investigated by a good number of researchers. The suitability and modifications in the existing systems are also recommended. (author)

  11. Bio-Based Polyols from Seed Oils for Water-Blown Rigid Polyurethane Foam Preparation

    Directory of Open Access Journals (Sweden)

    Paweena Ekkaphan

    2016-01-01

    Full Text Available The preparation of water-blown rigid polyurethane (RPUR foams using bio-based polyols from sesame seed oil and pumpkin seed oil has been reported. Polyols synthesis involved two steps, namely, hydroxylation and alcoholysis reaction. FTIR, NMR, and ESI-MS were used to monitor the process of the synthesized polyols and their physicochemical properties were determined. The resulting polyols have OH number in the range of 340–351 mg KOH/g. RPUR foams blown with water were produced from the reaction of biopolyols with commercial polymeric methylene diphenyl diisocyanate (PMDI. The proper PUR formulations can be manipulated to produce the desired material applications. These seed oil-based RPUR foams exhibited relatively high compressive strength (237.7–240.2 kPa with the density in the range of 40–45 kg/m3. Additionally, the cell foam morphology investigated by scanning electron microscope indicated that their cellular structure presented mostly polygonal closed cells. The experimental results demonstrate that these bio-based polyols can be used as an alternative starting material for RPUR production.

  12. Chitosan: An undisputed bio-fabrication material for tissue engineering and bio-sensing applications.

    Science.gov (United States)

    Baranwal, Anupriya; Kumar, Ashutosh; Priyadharshini, A; Oggu, Gopi Suresh; Bhatnagar, Ira; Srivastava, Ananya; Chandra, Pranjal

    2018-04-15

    Biopolymers have been serving the mankind in various ways since long. Over the last few years, these polymers have found great demand in various domains which includes bio medicine, tissue engineering, bio sensor fabrications etc. because of their excellent bio compatibility. In this context, chitosan has found global attention due to its environmentally benign nature, biocompatibility, biodegradability, and ease of availability. In last one decade or so, extensive research in active biomaterials, like chitosan has led to the development of novel delivery systems for drugs, genes, and biomolecules; and regenerative medicine. Additionally, chitosan has also witnessed its usage in functionalization of biocompatible materials, nanoparticle (NP) synthesis, and immobilization of various bio-recognition elements (BREs) to form active bio-surfaces with great ease. Keeping these aspects in mind, we have written a comprehensive review which aims to acquaint its readers with the exceptional properties of chitosan and its usage in the domain of biomedicine, tissue engineering, and biosensor fabrication. Herein, we have briefly explained various aspects of direct utilization of chitosan and then presented vivid strategies towards formulation of chitosan based nanocomposites for biomedicine, tissue engineering, and biosensing applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  13. [Contribution of Berlin clinics and especially the Charité to the development of modern anesthesia in Germany].

    Science.gov (United States)

    Wauer, H J; Kühne, H; Kox, W J

    2000-01-01

    Soon after announcement of the first American ether anesthesias in 1846 one started to anesthetize with ether in Europe. The first ether anesthesia in Germany took place on January 24th, 1947, and was given by Johann Ferdinand Heyfelder in Erlangen. Two weeks later the first ether anesthesia in Berlin was given on February 6th, 1847, by the orthopaedic surgeon Heimann-Wolff Berend. On February 12th, 1847, the surgeon Johann Friedrich Dieffenbach used ether to anesthetize a patient in the Berlin university hospital. Still in 1847 he published his book "The Ether against Pain" which used to be the standard textbook of anesthesia in Germany for many years to come. On February 15th, 1847, Johann Christian Jüngken operated his first patient under ether anesthesia in the surgical department of the Charité hospital assisted by Rudolf Virchow. Since then several famous Berlin surgeons influenced the development of modern anesthesia until the middle of the 20th century. The nitrous oxide bottle was introduced into practice by the Barth company in cooperation with the dentist Carl Sauer and Kurt Schimmelbusch introduced his mask for ether anesthesia. Carl Ludwig Schleich reported at the German congress of surgery in 1894 about his first experience with infiltration anesthesia. Spinal anesthesia developed by August Bier in Kiel was improved during his time in Berlin.

  14. Different conditions and strategies to utilize forensic radiology in the cities of Melbourne, Australia and Berlin, Germany.

    Science.gov (United States)

    Bedford, Paul J; Oesterhelweg, Lars

    2013-09-01

    Forensic radiology has become a common modality in many forensic practices around the world. Here, we report and compare the usage patterns in the cities of Melbourne, Australia, and Berlin, Germany, using 16 multislice scanners in two large forensic facilities with both machines integrated in the mortuary. While in Melbourne all bodies receive a full body computed tomography (CT) scan resulting in nearly 5,000 scans per year, the situation differs in Berlin where approximately 250 state prosecutor sanctioned cases are scanned per year. While in Melbourne the CT scanner is an integral element of the process of determining whether further examinations will follow, in contrast in Berlin all cases proceed to autopsy irrespective of the findings from the CT scan. While pathologists in Berlin receive on site training to use the CT scanner by a highly experienced forensic pathologist who has previously been involved in the Virtopsy(®) program in Switzerland, training of pathologists in Melbourne is multifaceted. A radiologist with extensive experience in the forensic environment is employed part time at the institute in Melbourne and provides radiology lectures including topics such as postmortem artifacts, regional anatomy, and neuroradiology. CT is gaining acceptance as a useful modality for presenting information to the courts and juries, as well as providing an easily accessible platform to review cases and initiated research projects.

  15. When Iron Crumbles: Berlin and the Wall. A Social Studies Unit Recommended for Grades 9-12 and Community College.

    Science.gov (United States)

    Chan, Adrian; And Others

    This unit, designed for use with high school and community college students, uses primary materials, literature, and interactive lesson plans to present the city of Berlin (Germany) as a case study of some of the 20th century's most significant events. In lesson 1, students take a pre-test, view a video about the Berlin Wall, and discuss the kinds…

  16. New development thoughts on the bio-inspired intelligence based control for unmanned combat aerial vehicle

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Bio-inspired intelligence is in the spotlight in the field of international artificial intelligence,and unmanned combat aerial vehicle(UCAV),owing to its potential to perform dangerous,repetitive tasks in remote and hazardous,is very promising for the technological leadership of the nation and essential for improving the security of society.On the basis of introduction of bioinspired intelligence and UCAV,a series of new development thoughts on UCAV control are proposed,including artificial brain based high-level autonomous control for UCAV,swarm intelligence based cooperative control for multiple UCAVs,hy-brid swarm intelligence and Bayesian network based situation assessment under complicated combating environments, bio-inspired hardware based high-level autonomous control for UCAV,and meta-heuristic intelligence based heterogeneous cooperative control for multiple UCAVs and unmanned combat ground vehicles(UCGVs).The exact realization of the proposed new development thoughts can enhance the effectiveness of combat,while provide a series of novel breakthroughs for the intelligence,integration and advancement of future UCAV systems.

  17. Bio-fuels

    International Nuclear Information System (INIS)

    2008-01-01

    This report presents an overview of the technologies which are currently used or presently developed for the production of bio-fuels in Europe and more particularly in France. After a brief history of this production since the beginning of the 20. century, the authors describe the support to agriculture and the influence of the Common Agricultural Policy, outline the influence of the present context of struggle against the greenhouse effect, and present the European legislative context. Data on the bio-fuels consumption in the European Union in 2006 are discussed. An overview of the evolution of the activity related to bio-fuels in France, indicating the locations of ethanol and bio-diesel production facilities, and the evolution of bio-fuel consumption, is given. The German situation is briefly presented. Production of ethanol by fermentation, the manufacturing of ETBE, the bio-diesel production from vegetable oils are discussed. Second generation bio-fuels are then presented (cellulose enzymatic processing), together with studies on thermochemical processes and available biomass resources

  18. The power of poison: pesticide poisoning of Africa's wildlife.

    Science.gov (United States)

    Ogada, Darcy L

    2014-08-01

    Poisons have long been used to kill wildlife throughout the world. An evolution has occurred from the use of plant- and animal-based toxins to synthetic pesticides to kill wildlife, a method that is silent, cheap, easy, and effective. The use of pesticides to poison wildlife began in southern Africa, and predator populations were widely targeted and eliminated. A steep increase has recently been observed in the intensity of wildlife poisonings, with corresponding population declines. However, the majority of poisonings go unreported. Under national laws, it is illegal to hunt wildlife using poisons in 83% of African countries. Pesticide regulations are inadequate, and enforcement of existing legislation is poor. Few countries have forensic field protocols, and most lack storage and testing facilities. Methods used to poison wildlife include baiting carcasses, soaking grains in pesticide solution, mixing pesticides to form salt licks, and tainting waterholes. Carbofuran is the most widely abused pesticide in Africa. Common reasons for poisoning are control of damage-causing animals, harvesting fish and bushmeat, harvesting animals for traditional medicine, poaching for wildlife products, and killing wildlife sentinels (e.g., vultures because their aerial circling alerts authorities to poachers' activities). Populations of scavengers, particularly vultures, have been decimated by poisoning. Recommendations include banning pesticides, improving pesticide regulations and controlling distribution, better enforcement and stiffer penalties for offenders, increasing international support and awareness, and developing regional pesticide centers. © 2014 New York Academy of Sciences.

  19. Pesticide authorization in the EU-environment unprotected?

    Science.gov (United States)

    Stehle, Sebastian; Schulz, Ralf

    2015-12-01

    Pesticides constitute an integral part of high-intensity European agriculture. Prior to their authorization, a highly elaborated environmental risk assessment is mandatory according to EU pesticide legislation, i.e., Regulation (EC) No. 1107/2009. However, no field data-based evaluation of the risk assessment outcome, i.e., the regulatory acceptable concentrations (RACs), and therefore of the overall protectiveness of EU pesticide regulations exists. We conducted here a comprehensive meta-analysis using peer-reviewed literature on agricultural insecticide concentrations in EU surface waters and evaluated associated risks using the RACs derived from official European pesticide registration documents. As a result, 44.7 % of the 1566 cases of measured insecticide concentrations (MICs) in EU surface waters exceeded their respective RACs. It follows that current EU pesticide regulations do not protect the aquatic environment and that insecticides threaten aquatic biodiversity. RAC exceedances were significantly higher for insecticides authorized using conservative tier-I RACs and for more recently developed insecticide classes, i.e., pyrethroids. In addition, we identified higher risks, e.g., for smaller surface waters that are specifically considered in the regulatory risk assessment schemes. We illustrate the shortcomings of the EU regulatory risk assessment using two case studies that contextualize the respective risk assessment outcomes to field exposure. Overall, our meta-analysis challenges the field relevance and protectiveness of the regulatory environmental risk assessment conducted for pesticide authorization in the EU and indicates that critical revisions of related pesticide regulations and effective mitigation measures are urgently needed to substantially reduce the environmental risks arising from agricultural insecticide use.

  20. Comparison of Prevalence and Outcomes of Pediatric Acute Respiratory Distress Syndrome Using Pediatric Acute Lung Injury Consensus Conference Criteria and Berlin Definition.

    Science.gov (United States)

    Gupta, Samriti; Sankar, Jhuma; Lodha, Rakesh; Kabra, Sushil K

    2018-01-01

    Our objective was to compare the prevalence and outcomes of pediatric acute respiratory distress syndrome using the Pediatric Acute Lung Injury Consensus Conference (PALICC) criteria and Berlin definitions. We screened case records of all children aged 1 month to 17 years of age admitted to the Pediatric Intensive Care Unit (PICU) over a 3-year period (2015-2017) for presence of any respiratory difficulty at admission or during PICU stay. We applied both PALICC and Berlin criteria to these patients. Data collection included definition and outcome related variables. Data were compared between the "PALICC only group" and the "Berlin with or without PALICC" group using Stata 11. Of a total of 615 admissions, 246 were identified as having respiratory difficulty at admission or during PICU stay. A total of 61 children (prevalence 9.9%; 95% CI: 7.8-12.4) fulfilled the definition of acute respiratory distress syndrome (ARDS) with either of the two criteria. While 60 children (98%) fulfilled PALICC criteria, only 26 children (43%) fulfilled Berlin definition. There was moderate agreement between the two definitions (Kappa: 0.51; 95% CI: 0.40-0.62; observed agreement 85%). Greater proportion of patients had severe ARDS in the "Berlin with or without PALICC group" as compared to the "PALICC only" group (50 vs. 19%). There was no difference between the groups with regard to key clinical outcomes such as duration of ventilation (7 vs. 8 days) or mortality [51.4 vs. 57.7%: RR (95% CI): 0.99 (0.64-1.5)]. In comparison to Berlin definition, the PALICC criteria identified more number of patients with ARDS. Proportion with severe ARDS and complications was greater in the "Berlin with or without PALICC" group as compared to the "PALICC only" group. There were no differences in clinical outcomes between the groups.

  1. Enormously varying utilization as a demand. An underfloor heating system for the fashion hotspot 'label Berlin 2'; Stark variierende Auslastung als Herausforderung. Ein Flaechentemperiersystem fuer den Mode-Hotspot ''Labels Berlin 2''

    Energy Technology Data Exchange (ETDEWEB)

    Buchner, Peter [Viega GmbH und Co. KG, Attendorn (Germany). Flaechentemperiersysteme

    2011-07-01

    Hugo Boss, Esprit, Brax, Puma, Comma or more s.Oliver - 'the labels Berlin 1 and 2 ' became a hotspot of the international world of fashion in Berlin (Federal Republic of Germany) within a few years. However, the concept to combine high-quality brands and their large showrooms under one roof was a challenge not only for architects. Also in the building services and especially in keeping rooms with their strongly varying extent of utilization at a moderate temperature all the stops had to be pulled out.

  2. Application study of Bio-FGD based on environmental safety during the coal combustion

    Science.gov (United States)

    Zhang, Pin

    2018-05-01

    Coal combustion produces a large amount of acidic gas, which is the main cause of acid rain and other natural disasters. Flue Gas Desulfurization (FGD) is a necessary requirement for clean coal combustion. Compared with the traditional chemical desulfurization technology, biological desulfurization has the advantages of low operating cost, without secondary pollution, low carbon emission and the additional economic benefits. The process and structure of BioDeSOx which as one of Bio-FGD technology is introduced. The major factors that influent BioDeSOx Bio- FGD system is the pH, oxidation reduction potential (-300 MV to -400MV), electrical conductivity, the adding amount of nutrient and temperature (30°C-40°C). Taking the Bio- FGD project of Yixing xielian thermal power plant as an example, the BioDeSOx technology was applied in this project. The environmental and economic benefits of the project were greater than the traditional desulfurization technology. With the continuous improvement of environmental safety standards, Bio- FGD technology will have broad application prospects.

  3. Bio-objects and the media: the role of communication in bio-objectification processes.

    Science.gov (United States)

    Maeseele, Pieter; Allgaier, Joachim; Martinelli, Lucia

    2013-06-01

    The representation of biological innovations in and through communication and media practices is vital for understanding the nature of "bio-objects" and the process we call "bio-objectification." This paper discusses two ideal-typical analytical approaches based on different underlying communication models, ie, the traditional (science- and media-centered) and media sociological (a multi-layered process involving various social actors in defining the meanings of scientific and technological developments) approach. In this analysis, the latter is not only found to be the most promising approach for understanding the circulation, (re)production, and (re)configuration of meanings of bio-objects, but also to interpret the relationship between media and science. On the basis of a few selected examples, this paper highlights how media function as a primary arena for the (re)production and (re)configuration of scientific and biomedical information with regards to bio-objects in the public sphere in general, and toward decision-makers, interest groups, and the public in specific.

  4. Pesticides and their effects on wildlife

    Energy Technology Data Exchange (ETDEWEB)

    Driver, C.J.

    1994-07-01

    About 560 active ingredients are currently used as pesticides. Applications of these pesticides are made to agricultural lands and other areas inhabited by wildlife. Unfortunately, many agricultural-use pesticides also entail some measure of risk to organisms other than the pest species. Because testing of pesticides prior to registration cannot evaluate all the potential environmental-pesticide-wildlife/fish interactions, current methods of risk assessment do not always provide sufficient safety to nontarget organisms. This is evidenced by die-offs of fish and wildlife from applications of pesticides at environmentally {open_quotes}safe{close_quotes} rates, the linking of population declines of some species with agrochemical use, and observations of survival-threatening behavioral changes in laboratory and field animals exposed to typical field levels of pesticides. It is important to note, however, that the majority of pesticides, when properly applied, have not caused significant injury to wildlife. A brief summary of pesticide effects on wildlife and fish are presented for the common classes of pesticides in use today.

  5. Environmental exposure to pesticides and the risk of Parkinson's disease in the Netherlands.

    Science.gov (United States)

    Brouwer, Maartje; Huss, Anke; van der Mark, Marianne; Nijssen, Peter C G; Mulleners, Wim M; Sas, Antonetta M G; van Laar, Teus; de Snoo, Geert R; Kromhout, Hans; Vermeulen, Roel C H

    2017-10-01

    Exposure to pesticides has been linked to Parkinson's disease (PD), although associations between specific pesticides and PD have not been well studied. Residents of rural areas can be exposed through environmental drift and volatilization of agricultural pesticides. Our aim was to investigate the association between lifetime environmental exposure to individual pesticides and the risk of PD, in a national case-control study. Environmental exposure to pesticides was estimated using a spatio-temporal model, based on agricultural crops around the residential address. Distance up to 100m from the residence was considered most relevant, considering pesticide drift potential of application methods used in the Netherlands. Exposure estimates were generated for 157 pesticides, used during the study period, of which four (i.e. paraquat, maneb, lindane, benomyl) were considered a priori relevant for PD. A total of 352 PD cases and 607 hospital-based controls were included. No significant associations with PD were found for the a priori pesticides. In a hypothesis generating analysis, including 153 pesticides, increased risk of PD was found for 21 pesticides, mainly used on cereals and potatoes. Results were suggestive for an association between bulb cultivation and PD. For paraquat, risk estimates for the highest cumulative exposure tertile were in line with previously reported elevated risks. Increased risk of PD was observed for exposure to (a cluster of) pesticides used on rotating crops. High correlations limited our ability to identify individual pesticides responsible for this association. This study provides some evidence for an association between environmental exposure to specific pesticides and the risk of PD, and generates new leads for further epidemiological and mechanistic research. Copyright © 2017. Published by Elsevier Ltd.

  6. Green bio-oil extraction for oil crops

    Science.gov (United States)

    Zainab, H.; Nurfatirah, N.; Norfaezah, A.; Othman, H.

    2016-06-01

    The move towards a green bio-oil extraction technique is highlighted in this paper. The commonly practised organic solvent oil extraction technique could be replaced with a modified microwave extraction. Jatropha seeds (Jatropha curcas) were used to extract bio-oil. Clean samples were heated in an oven at 110 ° C for 24 hours to remove moisture content and ground to obtain particle size smaller than 500μm. Extraction was carried out at different extraction times 15 min, 30 min, 45 min, 60 min and 120 min to determine oil yield. The biooil yield obtained from microwave assisted extraction system at 90 minutes was 36% while that from soxhlet extraction for 6 hours was 42%. Bio-oil extracted using the microwave assisted extraction (MAE) system could enhance yield of bio-oil compared to soxhlet extraction. The MAE extraction system is rapid using only water as solvent which is a nonhazardous, environment-friendly technique compared to soxhlet extraction (SE) method using hexane as solvent. Thus, this is a green technique of bio-oil extraction using only water as extractant. Bio-oil extraction from the pyrolysis of empty fruit bunch (EFB), a biomass waste from oil palm crop, was enhanced using a biocatalyst derived from seashell waste. Oil yield for non-catalytic extraction was 43.8% while addition of seashell based biocatalyst was 44.6%. Oil yield for non-catalytic extraction was 43.8% while with addition of seashell-based biocatalyst was 44.6%. The pH of bio-oil increased from 3.5 to 4.3. The viscosity of bio-oil obtained by catalytic means increased from 20.5 to 37.8 cP. A rapid and environment friendly extraction technique is preferable to enhance bio-oil yield. The microwave assisted approach is a green, rapid and environmental friendly extraction technique for the production of bio-oil bearing crops.

  7. Techno-economic assessment of the production of bio-based chemicals from glutamic acid

    NARCIS (Netherlands)

    Lammens, T.M.; Gangarapu, S.; Franssen, M.C.R.; Scott, E.L.; Sanders, J.P.M.

    2012-01-01

    In this review, possible process steps for the production of bio-based industrial chemicals from glutamic acid are described, including a techno-economic assessment of all processes. The products under investigation were those that were shown to be synthesized from glutamic acid on lab-scale, namely

  8. Securing renewable resource supplies for changing market demands in a bio-based economy

    NARCIS (Netherlands)

    Dam, van J.E.G.; Klerk-Engels, de B.; Struik, P.C.; Rabbinge, R.

    2005-01-01

    Establishment of a bio-based economy has been recognised as one of the key issues for sustainable development For future developments renewable resources will play a key role as CO2 neutral raw material for sustainable industrial production to curb depletion of fossil resources. Options to fully

  9. Use-exposure relationships of pesticides for aquatic risk assessment.

    Directory of Open Access Journals (Sweden)

    Yuzhou Luo

    2011-04-01

    Full Text Available Field-scale environmental models have been widely used in aquatic exposure assessments of pesticides. Those models usually require a large set of input parameters and separate simulations for each pesticide in evaluation. In this study, a simple use-exposure relationship is developed based on regression analysis of stochastic simulation results generated from the Pesticide Root-Zone Model (PRZM. The developed mathematical relationship estimates edge-of-field peak concentrations of pesticides from aerobic soil metabolism half-life (AERO, organic carbon-normalized soil sorption coefficient (KOC, and application rate (RATE. In a case study of California crop scenarios, the relationships explained 90-95% of the variances in the peak concentrations of dissolved pesticides as predicted by PRZM simulations for a 30-year period. KOC was identified as the governing parameter in determining the relative magnitudes of pesticide exposures in a given crop scenario. The results of model application also indicated that the effects of chemical fate processes such as partitioning and degradation on pesticide exposure were similar among crop scenarios, while the cross-scenario variations were mainly associated with the landscape characteristics, such as organic carbon contents and curve numbers. With a minimum set of input data, the use-exposure relationships proposed in this study could be used in screening procedures for potential water quality impacts from the off-site movement of pesticides.

  10. Review of Berliner & Biddle "The Manufactured Crisis"

    Directory of Open Access Journals (Sweden)

    Lawrence C. Stedman

    1996-01-01

    Full Text Available In a provocative new book, The Manufactured Crisis, David Berliner and Bruce Biddle make four sweeping claims about U.S. achievement: there never was a test score decline, today's students are "out-achieving their parents substantially" (p. 33, U.S. students "stack up very well" in international assessments (p. 63, and the general education crisis is a right-wing fabrication. As a progressive, I'm sympathetic to their concerns, but as a scholar who specializes in this material, I find their analysis deeply flawed and misleading. They mischaracterize the test score decline data, mishandle the international findings, and fail to acknowledge students' continuing low levels of academic achievement.

  11. Eugenol-loaded chitosan nanoparticles: II. Application in bio-based plastics for active packaging.

    Science.gov (United States)

    Woranuch, Sarekha; Yoksan, Rangrong

    2013-07-25

    The aim of the present research was to study the possibility of using eugenol-loaded chitosan nanoparticles as antioxidants for active bio-based packaging material. Eugenol-loaded chitosan nanoparticles were incorporated into thermoplastic flour (TPF) - a model bio-based plastic - through an extrusion process at temperatures above 150°C. The influences of eugenol-loaded chitosan nanoparticles on crystallinity, morphology, thermal properties, radical scavenging activity, reducing power, tensile properties and barrier properties of TPF were investigated. Although the incorporation of 3% (w/w) of eugenol-loaded chitosan nanoparticles significantly reduced the extensibility and the oxygen barrier property of TPF, it provided antioxidant activity and improved the water vapor barrier property. In addition, TPF containing eugenol-loaded chitosan nanoparticles exhibited superior radical scavenging activity and stronger reducing power compared with TPF containing naked eugenol. The results suggest the applicability of TPF containing eugenol-loaded chitosan nanoparticles as an antioxidant active packaging material. Copyright © 2012 Elsevier Ltd. All rights reserved.

  12. The Future of Polar Organometallic Chemistry Written in Bio-Based Solvents and Water.

    Science.gov (United States)

    García-Álvarez, Joaquín; Hevia, Eva; Capriati, Vito

    2018-06-19

    There is a strong imperative to reduce the release of volatile organic compounds (VOCs) into the environment, and many efforts are currently being made to replace conventional hazardous VOCs in favour of safe, green and bio-renewable reaction media that are not based on crude petroleum. Recent ground-breaking studies from a few laboratories worldwide have shown that both Grignard and (functionalised) organolithium reagents, traditionally handled under strict exclusion of air and humidity and in anhydrous VOCs, can smoothly promote both nucleophilic additions to unsaturated substrates and nucleophilic substitutions in water and other bio-based solvents (glycerol, deep eutectic solvents), competitively with protonolysis, at room temperature and under air. The chemistry of polar organometallics in the above protic media is a complex phenomenon influenced by several factors, and understanding its foundational character is surely stimulating in the perspective of the development of a sustainable organometallic chemistry. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. BioSig - An application of Octave

    OpenAIRE

    Schlögl, Alois

    2006-01-01

    BioSig is an open source software library for biomedical signal processing. Most users in the field are using Matlab; however, significant effort was undertaken to provide compatibility to Octave, too. This effort has been widely successful, only some non-critical components relying on a graphical user interface are missing. Now, installing BioSig on Octave is as easy as on Matlab. Moreover, a benchmark test based on BioSig has been developed and the benchmark results of several platforms are...

  14. Effect of harsh or mild extraction of soil on pesticide leaching to groundwater

    NARCIS (Netherlands)

    Boesten, Jos J.T.I.

    2016-01-01

    Assessment of leaching to groundwater is an important aspect of pesticide risk assessment. The first leaching tier usually consists of simulations with leaching scenarios based on pesticide- soil properties derived from laboratory studies. Because the extractability of pesticide residues in such

  15. Synthesis and Characterization of Bio-based Nanomaterials from Jabon (Anthocephalus cadamba (Roxb. Miq Wood Bark: an Organic Waste Material from Community Forest

    Directory of Open Access Journals (Sweden)

    Sutrisno

    2015-06-01

    Full Text Available The application of nanotechnology to produce nanomaterials from renewable bio-based materials, like wood bark, has great potential to benefit the wood processing industry. To support this issue, we investigated the production of bio-based nanomaterials using conventional balls milling. Jabon (Anthocephalus cadamba(Roxb. Miq wood bark (JWB, an organic waste material from a community forest was subjected to conventional balls milling for 96 h and was converted into bio-based nanomaterial. The morphology and particle size, chemical components, functional groups and crystallinity of the bio-based nanomaterial were evaluated using scanning electron microscopy (SEM, scanning electron microscopy extended with energy dispersive X-ray spectroscopy (SEM-EDS, Fourier transform infrared spectroscopy (FTIR, and X-ray diffraction (XRD. The particle-sizes obtained for the JWB bio-based nanomaterial were between 43 nm to 469 nm and the functional groups were detected as cellulose. The chemical components found were carbon, oxygen, chloride, potassium and calcium, except for the sample produced from sieve type T14, which did not contain chloride. The crystalline structure was calcium oxalate hydrate (C2CaO4.H2O with crystalline sizes 21 nm and 15 nm, produced from sieve types T14 and T200 respectively.

  16. Estegomiias em conserva e micróbios de vinha-d'alhos: o Brasil triunfa em Berlim Preserved Stegomyia and vinegared microbes: Brazil's triumph in Berlin

    Directory of Open Access Journals (Sweden)

    Henrique Luiz Cukierman

    2001-02-01

    Full Text Available O artigo investiga as circunstâncias que levaram o Brasil a alcançar o primeiro prêmio na XIV Exposição de Higiene e Demografia, em Berlim, em 1907. A partir da inédita correspondência trocada entre Henrique da Rocha Lima e Oswaldo Cruz às vésperas da exposição, é possível observar as agruras do empreendimento à brasileira, onde aquilo que se parecia a uma cuidadosa estratégia revela-se como um turbilhão de acontecimentos, no qual a sorte da participação brasileira dependeu de situações pouco ou nada delineadas por planejamento meticuloso e previdente. A correspondência revela ainda que, se assumidas as narrativas glorificadoras de méritos pessoais, a vitória em Berlim foi muito mais de Rocha Lima que de Oswaldo Cruz. À luz de Raízes do Brasil, de Sérgio Buarque de Holanda, outra questão abordada diz respeito ao embate entre os mundos ibérico e anglo-saxônico na construção e no reconhecimento da vitória brasileira.This article investigates the circumstances leading to Brazil being awarded the first prize at the XIV International Conference on Demography and Hygiene, held in Berlin in 1907. An examination of the unpublished correspondence between Henrique da Rocha Lima and Oswaldo Cruz prior to the conference/exhibition reveals the peculiarities of a Brazilian-style event, where the outcome seems to be determined by haphazard incidents rather than by meticulously planned strategies. Their letters can also be read as a narrative celebrating individual qualities, as they attribute the victory in Berlin much more to Rocha Lima's than Oswaldo Cruz's personal merits. In the light of Raízes do Brasil, a classic by Sérgio Buarque de Holanda, this article also addresses the issue regarding the dispute between the Iberian and Anglo-Saxon worlds over the Brazilian victory.

  17. Biodegradable and bio-based polymers: future prospects of eco-friendly plastics.

    Science.gov (United States)

    Iwata, Tadahisa

    2015-03-09

    Currently used plastics are mostly produced from petrochemical products, but there is a growing demand for eco-friendly plastics. The use of bio-based plastics, which are produced from renewable resources, and biodegradable plastics, which are degraded in the environment, will lead to a more sustainable society and help us solve global environmental and waste management problems. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Combining Bio-inspired Sensing with Bio-inspired Locomotion

    DEFF Research Database (Denmark)

    Shaikh, Danish; Hallam, John; Christensen-Dalsgaard, Jakob

    In this paper we present a preliminary Braitenberg vehicle–like approach to combine bio-inspired audition with bio-inspired quadruped locomotion in simulation. Locomotion gaits of the salamander–like robot Salamandra robotica are modified by a lizard’s peripheral auditory system model that modula......In this paper we present a preliminary Braitenberg vehicle–like approach to combine bio-inspired audition with bio-inspired quadruped locomotion in simulation. Locomotion gaits of the salamander–like robot Salamandra robotica are modified by a lizard’s peripheral auditory system model...

  19. From zero to hero - production of bio-based nylon from renewable resources using engineered Corynebacterium glutamicum.

    Science.gov (United States)

    Kind, Stefanie; Neubauer, Steffi; Becker, Judith; Yamamoto, Motonori; Völkert, Martin; Abendroth, Gregory von; Zelder, Oskar; Wittmann, Christoph

    2014-09-01

    Polyamides are important industrial polymers. Currently, they are produced exclusively from petrochemical monomers. Herein, we report the production of a novel bio-nylon, PA5.10 through an integration of biological and chemical approaches. First, systems metabolic engineering of Corynebacterium glutamicum was used to create an effective microbial cell factory for the production of diaminopentane as the polymer building block. In this way, a hyper-producer, with a high diaminopentane yield of 41% in shake flask culture, was generated. Subsequent fed-batch production of C. glutamicum DAP-16 allowed a molar yield of 50%, a productivity of 2.2gL(-1)h(-1), and a final titer of 88gL(-1). The streamlined producer accumulated diaminopentane without generating any by-products. Solvent extraction from alkalized broth and two-step distillation provided highly pure diaminopentane (99.8%), which was then directly accessible for poly-condensation. Chemical polymerization with sebacic acid, a ten-carbon dicarboxylic acid derived from castor plant oil, yielded the bio-nylon, PA5.10. In pure form and reinforced with glass fibers, the novel 100% bio-polyamide achieved an excellent melting temperature and the mechanical strength of the well-established petrochemical polymers, PA6 and PA6.6. It even outperformed the oil-based products in terms of having a 6% lower density. It thus holds high promise for applications in energy-friendly transportation. The demonstration of a novel route for generation of bio-based nylon from renewable sources opens the way to production of sustainable bio-polymers with enhanced material properties and represents a milestone in industrial production. Copyright © 2014 The Authors. Published by Elsevier Inc. All rights reserved.

  20. Marble Deterioration and Climate: Examples from the Schlossbrücke Berlin

    Science.gov (United States)

    Pirskawetz, S.; Siegesmund, S.; Weise, F.; Rieffel, Y.; Plagge, R.

    2012-04-01

    Protective structures for works of art or antique artefacts have a long architectural tradition and have been known in Germany since the 19th century. The effect of such covers on the microclimate around artworks of natural stone, and hence, their protective capability are insufficiently documented and understood. In 2007, an inter-disciplinary model project and part of a pilot study coordinated by the Berlin State Office for the Protection of Monuments was planned with the aim of developing an innovative winter covering system for marble statuaries located on the Schlossbrücke in Berlin. Such a system would need to fulfil the various requirements for structural stability, aesthetics, climate and practical use. This applied research represents the first complex scientific study of the sustainability of a winter covering system. A climate monitoring system was designed to create a dense database for the numerical prediction of the effect of protective systems, and to compare the given climate conditions to the known factors influencing the marble deterioration. Based on these findings a prototype of an innovative shelter was designed and tested. The project shows, that beside a temporary covering regular inspection and maintenance combined with regular cleaning ensures an effective and sustainable protection of marble sculptures. Such a maintenance program is the precondition for preserving the sculptures of the Schlossbrücke as a historical ensemble. Important scientific results of the project are transferable to similar objects of Carrara marble. The results throw a new light on the conventional protection of such objects and leads to a discussion on the necessity of an all-season protection.