WorldWideScience

Sample records for bed partial gasification

  1. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    Energy Technology Data Exchange (ETDEWEB)

    Archie Robertson

    2003-10-29

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the July 1--September 30, 2003 time period.

  2. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2003-01-30

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the October 1--December 31, 2002 time period.

  3. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    Energy Technology Data Exchange (ETDEWEB)

    Archie Robertson

    2003-07-23

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the April 1--June 30, 2003 time period.

  4. Development of Pressurized Circulating Fluidized Bed Partial Gasification Module (PGM)

    Energy Technology Data Exchange (ETDEWEB)

    A. Robertson

    2003-12-31

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the October 1 - December 31, 2003 time period.

  5. [Transformation of sulfur forms during coal pyrolysis and partial gasification in a fixed bed reactor].

    Science.gov (United States)

    Li, Bin; Cao, Yan; Zhang, Jianmin; Huang, Jiejie; Wang, Yang; Chen, Fuyan

    2003-03-01

    The development of various process to the pre-desulfurization of coal was drawn more attention. In present study, the transformation of sulfur forms of three different ranks high sulfur coals during coal pyrolysis and partial gasification were investigated in a fixed bed reactor. The sulfur and carbon content analysis of original coal and coal char produced were determined by LECO SC-444 and wet chemical analysis according to Sugawara's method. The results showed that half of inorganic sulfur and partial of organic sulfur were removed during coal pyrolysis. And the sulfur removal was much more than carbon during pyrolysis process; and the sulfur in the coal char, especially the sulfide sulfur was removed completely during partial gasification process for both Datong coal and Xishan coal, the degree of sulfide sulfur removal could be increased with increasing temperature. At the same time, the results of Yima coal showed that the effect of fixed-sulfur by alkaline metals increased when the temperature was higher than 700 degrees C, which attribute to the increase of the fixed sulfur reaction rate and the decrease of mass-transfer limitation.

  6. Fluidised-bed combustion of gasification residue

    Energy Technology Data Exchange (ETDEWEB)

    Korpela, T.; Kudjoi, A.; Hippinen, I.; Heinolainen, A.; Suominen, M.; Lu Yong [Helsinki Univ. of Technology (Finland). Lab of Energy Economics and Power Plant Engineering

    1996-12-01

    Partial gasification processes have been presented as possibilities for future power production. In the processes, the solid materials removed from a gasifier (i.e. fly ash and bed material) contain unburnt fuel and the fuel conversion is increased by burning this gasification residue either in an atmospheric or a pressurised fluidised-bed. In this project, which is a part of European JOULE 2 EXTENSION research programme, the main research objectives are the behaviour of calcium and sulphur compounds in solids and the emissions of sulphur dioxide and nitrogen oxides (NO{sub x} and N{sub 2}O) in pressurised fluidised-bed combustion of gasification residues. (author)

  7. DEVELOPMENT OF PRESSURIZED CIRCULATIONG FLUIDIZED BED PARTIAL GASIFICATION MODULE(PGM)

    Energy Technology Data Exchange (ETDEWEB)

    Archie Robertson

    2003-04-17

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building block that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the January 1--March 31, 2003 time period.

  8. Adiabatic Fixed-Bed Gasification of Colombian Coffee Husk Using Air-Steam Blends for Partial Oxidation

    Directory of Open Access Journals (Sweden)

    Javier Bonilla

    2017-01-01

    Full Text Available The increasing energy consumption, mostly supplied by fossil fuels, has motivated the research and development of alternative fuel technologies to decrease the humanity’s dependence on fossil fuels, which leads to pollution of natural sources. Small-scale biomass gasification, using air-steam blends for partial oxidation, is a good alternative since biomass is a neutral carbon feedstock for sustainable energy generation. This research presents results obtained from an experimental study on coffee husk (CH gasification, using air-steam blends for partial oxidation in a 10 kW fixed-bed gasifier. Parametric studies on equivalence ratio (ER (1.53 < ER < 6.11 and steam-fuel (SF ratio (0.23 < SF < 0.89 were carried out. The results show that increasing both SF and ER results in a syngas rich in CH4 and H2 but poor in CO. Also, decreased SF and ER decrease the peak temperature (Tpeak at the gasifier combustion zone. The syngas high heating value (HHV ranged from 3112 kJ/SATPm3 to 5085 kJ/SATPm3 and its maximum value was obtained at SF = 0.87 and ER = 4.09. The dry basis molar concentrations of the species, produced under those operating conditions (1.53 < ER < 6.11 and 0.23 < SF < 0.89, were between 1.12 and 4.1% for CH4, between 7.77 and 13.49% for CO, and between 7.54 and 19.07% for H2. Other species were in trace amount.

  9. Coal gasification fluidized bed (Winkler gasification) under pressure

    International Nuclear Information System (INIS)

    Anwer, J.; Boegner, F.

    1976-01-01

    Due to the 'oil crisis', the gasification of lignite and coal for the production of fuel and synthetic gas has reached increased importance. The present state of the Winkler gasification which has successfully operated for a long time is described. After the basic design of a Winkler gasification plant, the various chemical engineering problems are shown: the design characteristics of a fluidized bed, the reaction kinetics, the dependance of the products on the gasification pressure, and the economics of the process. Finally, the development trend in the USA and the future possibility of heating by nuclear heat is dealt with. (orig.) [de

  10. Partial gasification of coal in a fluidized bed reactor: Comparison of a laboratory and pilot scale reactors

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, R.; Shen, L.H.; Zhang, M.Y.; Jin, B.S.; Xiong, Y.Q.; Duan, Y.F.; Zhong, Z.P.; Zhou, H.C.; Chen, X.P.; Huang, Y.J. [Southeast University, Nanjing (China)

    2007-01-15

    A 0.1 MWth lab-scale and 2 MWth pilot-scale experimental rigs were constructed to demonstrate the technical feasibility of a new process. The aim of the lab-scale study is to optimize coal partial gasification reactions operating conditions, which were applied in the pilot-scale tests. A comparison between the laboratory and pilot scale experimental results is presented in this paper in order to provide valuable information for scaling-up of the PFB coal partial reactor to industrial applications. The results show that trends and phenomena obtained in the laboratory reactor are confirmed in a pilot plant operating at similar conditions. However, many differences are observed in the two reactors. The higher heat loss in the lab-scale reactor is responsible for higher equivalence ratio (ER) and lower gas heating value at the similar reactor temperature. With respect to the pilot-scale reactor, mass transfer limitation between bubbles and emulsion phase may become important. Hence, longer contact time is required to achieve the same conversions as in the lab-scale reactor. This difference is explained by a significant change of the hydrodynamic conditions due to the formation of larger bubbles.

  11. Fluidized bed combustion and gasification of corncobs

    Energy Technology Data Exchange (ETDEWEB)

    Butuk, N.; Morey, R.V.

    1987-01-01

    A 15.2 cm (6 in) diameter fluidized bed reactor was evaluated in combustion and gasification modes using hammer milled corncobs with average particle size of 0.2 cm (0.08 in). Combustion tests were run at 10 and 32% w.b. moisture contents and 710 degrees C and 815 degrees C bed temperatures. Heat output rates of 13.4 to 16.2 MJ/h were achieved. Gasification tests were run at 10 and 22% w.b. moisture contents and 710 degrees C bed temperature, and heat output rates of 84 to 133 MJ/h were achieved. Particulates in the exhaust gases were determined in both the combustion and gasification modes of operation. The measurements showed the inadequacy of the flame holder for flaring the gas in the gasification mode. A combustion model based on elemental balances and the first law of thermodynamics was developed and compared to experimental results. The model adequately predicted fuel-air ratios and exhaust gas mass fractions in the combustion mode.

  12. Fluidised bed gasification of low grade South African coals

    CSIR Research Space (South Africa)

    North, BC

    2006-09-01

    Full Text Available -going investigation into one potential Clean Coal Technology (CCT), namely fluidised bed gasification. Coal gasification holds the potential benefits of increased efficiency, reduced water consumption and co-production of liquid and gaseous fuels and chemicals...

  13. Modeling biomass gasification in circulating fluidized beds

    Science.gov (United States)

    Miao, Qi

    In this thesis, the modeling of biomass gasification in circulating fluidized beds was studied. The hydrodynamics of a circulating fluidized bed operating on biomass particles were first investigated, both experimentally and numerically. Then a comprehensive mathematical model was presented to predict the overall performance of a 1.2 MWe biomass gasification and power generation plant. A sensitivity analysis was conducted to test its response to several gasifier operating conditions. The model was validated using the experimental results obtained from the plant and two other circulating fluidized bed biomass gasifiers (CFBBGs). Finally, an ASPEN PLUS simulation model of biomass gasification was presented based on minimization of the Gibbs free energy of the reaction system at chemical equilibrium. Hydrodynamics plays a crucial role in defining the performance of gas-solid circulating fluidized beds (CFBs). A 2-dimensional mathematical model was developed considering the hydrodynamic behavior of CFB gasifiers. In the modeling, the CFB riser was divided into two regions: a dense region at the bottom and a dilute region at the top of the riser. Kunii and Levenspiel (1991)'s model was adopted to express the vertical solids distribution with some other assumptions. Radial distributions of bed voidage were taken into account in the upper zone by using Zhang et al. (1991)'s correlation. For model validation purposes, a cold model CFB was employed, in which sawdust was transported with air as the fluidizing agent. A comprehensive mathematical model was developed to predict the overall performance of a 1.2 MWe biomass gasification and power generation demonstration plant in China. Hydrodynamics as well as chemical reaction kinetics were considered. The fluidized bed riser was divided into two distinct sections: (a) a dense region at the bottom of the bed where biomass undergoes mainly heterogeneous reactions and (b) a dilute region at the top where most of homogeneous

  14. Biofluid process: fluidised-bed gasification of biomass

    Energy Technology Data Exchange (ETDEWEB)

    Dittrich, A. [ATEKO a.s., Hradec Kralove (Czech Republic)

    1996-12-31

    Fluidised-bed gasification of biomass was developed by ATEKO by using long-term experience from coal gasification. An experimental unit was built and a number of tests, first with sawdust gasification, were carried out. A gas combustion engine combined with a power generator was installed and operated in power production. (orig.)

  15. Fixed bed gasification of solid biomass fuels

    Energy Technology Data Exchange (ETDEWEB)

    Haavisto, I. [Condens Oy, Haemeenlinna (Finland)

    1996-12-31

    Fixed bed biomass gasifiers are feasible in the effect range of 100 kW -10 MW. Co-current gasification is available only up to 1 MW for technical reasons. Counter-current gasifiers have been used in Finland and Sweden for 10 years in gasification heating plants, which are a combination of a gasifier and an oil boiler. The plants have proved to have a wide control range, flexible and uncomplicated unmanned operation and an excellent reliability. Counter-current gasifiers can be applied for new heating plants or for converting existing oil and natural gas boilers into using solid fuels. There is a new process development underway, aiming at motor use of the producer gas. The development work involves a new, more flexible cocurrent gasifier and a cleaning step for the counter-current producer gas. (orig.)

  16. Gasification of wood in a fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, L.C. de; Marti, T.; Frankenhaeuser, M. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    A first series of gasification experiments with our fluidized bed gasifier was performed using clean sawdust as fuel. The installation and the analytical systems were tested in a parametric study in which gasification temperature and equivalence ratio were varied. The data acquired will serve to establish the differences between the gasification of clean wood and the gasification of Altholz (scrapwood) and wood/plastics mixtures. (author) 1 fig., 3 tabs., 5 refs.

  17. Fixed-bed gasification research using US coals. Volume 10. Gasification of Benton lignite

    Energy Technology Data Exchange (ETDEWEB)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the tenth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Benton lignite. The period of gasification test was November 1-8, 1983. 16 refs., 22 figs., 19 tabs.

  18. Fluidized bed gasification of select granular biomaterials.

    Science.gov (United States)

    Subramanian, P; Sampathrajan, A; Venkatachalam, P

    2011-01-01

    Biomaterials can be converted into solid, liquid and gaseous fuels through thermochemical or biochemical conversion processes. Thermochemical conversion of granular biomaterials is difficult because of its physical nature and one of the suitable processes is fluidized bed gasification. In this study, coir pith, rice husk and saw dust were selected and synthetic gas was generated using a fluidized bed gasifier. Gas compositions of product gas were analyzed and the percentage of carbon monoxide and carbon dioxide was in the range of 8.24-19.55 and 10.21-17.14, respectively. The effect of equivalence ratio (0.3, 0.4 and 0.5) and reaction time (at 10 min interval) on gas constituents was studied. The gas yield for coir pith, rice husk and sawdust were found to be in the range of 1.98-3.24, 1.79-2.81 and 2.18-3.70 Nm3 kg(-1), respectively. Models were developed to study the influence of biomaterial properties and operating conditions on molar concentration of gas constituents and energy output. Copyright © 2010 Elsevier Ltd. All rights reserved.

  19. Gasification of rice husk in a fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Mansaray, K.G.

    1998-12-31

    The development of two mathematical models which simulate the performance of a dual distributor fluidized bed gasifier was described. The gasification of rice husks in the gasifier using air as the sole gasifying agent was investigated. The four stages of the study were: (1) modification of the existing fluidized bed gasifier and data acquisition system, (2) preliminary experimentation to assess the suitability of rice husks for gasification to determine the feasible range of operating conditions for fluidized bed gasification of rice husks and to obtain data for proper design of thermochemical conversion systems, (3) development of mathematical models to predict the performance of the fluidized bed gasification system, and (4) experimentation to investigate the effects of various operating variables on the performance of the gasifier and provide data to evaluate the validity of the models.

  20. Fixed-bed gasification research using US coals. Volume 13. Gasification of Blind Canyon bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the thirteenth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Blind Canyon bituminous coal, from July 31, 1984 to August 11, 1984. 6 refs., 22 figs., 20 tabs.

  1. Lignite air-steam gasification in the fluidized bed of iron-containing slag catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Kuznetsov, B.N.; Shchipko, M.L.; Golovin, Yu. [Inst. of Chemistry of Natural Organic Materials, Academgorodok, Krasnoyarsk (Russian Federation)

    1995-12-01

    The influence of fluidized bed of iron-containing slag particles on air-steam gasification of powdered Kansk-Achinsk lignite in entrained flow was studied in pilot installation with productivity about 60 kg per hour. Slag of Martin process and boiler slag were used as catalytic active materials until their complete mechanical attrition. Two following methods of catalytic gasification of lignite were compared: the partial gasification in stationary fluidized bed of slag particles with degree of fuel conversion 40-70% and complete gasification in circulating bed of slag particles. In the first case only the most reactive part of fuel is gasified with the simultaneously formation of porous carbon residue with good sorption ability. It was found the catalytic fluidized bed improves heat transfer from combustion to reduction zone of gas-generator and increases the rate of fuel conversion at the temperature range 900-1000{degrees}C. At these temperatures the degree of conversion is depended considerably on the duration time of fuel particles in the catalytic fluidized bed. The influence of catalytic fluidized bed height and velocity of reaction mixture on the temperature profiles in the gas-generator was studied. The optimal relationship was found between the fluidized bed height and velocity of flow which makes possible to produce the gas with higher calorific value at maximum degree of fuel conversion.

  2. Gasification of sawdust in pressurised internally circulating fluidized bed

    Energy Technology Data Exchange (ETDEWEB)

    Maartensson, R.; Lindblom, M. [Lund Univ. (Sweden). Dept. of Chemical Engineering

    1996-12-31

    A test plant for pressurised gasification of biofuels in a internally circulating fluidized bed has been built at the department of Chemical Engineering II at the University of Lund. The design performance is set to maximum 20 bar and 1 050 deg C at a thermal input of 100 kW or a maximum fuel input of 18 kg/in. The primary task is to study pressurised gasification of biofuels in relation to process requirements of the IGCC concept (integrated gasification combined cycle processes), which includes studies in different areas of hot gas clean-up in reducing atmosphere for gas turbine applications. (orig.)

  3. Fixed-bed gasification research using US coals. Volume 4. Gasification of Leucite Hills subbituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-03-31

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the fourth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Leucite Hills subbituminous coal from Sweetwater County, Wyoming. The period of the gasification test was April 11-30, 1983. 4 refs., 23 figs., 27 tabs.

  4. Fixed-bed gasification research using US coals. Volume 9. Gasification of Elkhorn bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the ninth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Elkhorn bituminous coal. The period of gasificastion test was September 13 to October 12, 1983. 9 refs., 24 figs., 35 tabs.

  5. Gasification of Coal and PET in Fluidized Bed Reactor

    Czech Academy of Sciences Publication Activity Database

    Pohořelý, Michael; Vosecký, Martin; Kameníková, Petra; Punčochář, Miroslav; Skoblia, Sergej; Staf, M.; Vošta, J.; Koutský, B.; Svoboda, Karel

    2006-01-01

    Roč. 85, 17-18 (2006), s. 2458-2468 ISSN 0016-2361 R&D Projects: GA ČR(CZ) GA104/04/0829 Institutional research plan: CEZ:AV0Z40720504 Keywords : fludized bed * gasification * plastic waste Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.358, year: 2006

  6. Catalytic gasification in fluidized bed, of orange waste. Comparison with non catalytic gasification

    International Nuclear Information System (INIS)

    Aguiar Trujillo, Leonardo; Marquez Montesinos, Francisco; Ramos Robaina, Boris A.; Guerra Reyes, Yanet; Arauzo Perez, Jesus; Gonzalo Callejo, Alberto; Sanchez Cebrian, Jose L

    2011-01-01

    The industry processing of the orange, generates high volumes of solid waste. This waste has been used as complement in the animal feeding, in biochemical processes; but their energy use has not been valued by means of the gasification process. They were carried out gasification studies with air in catalytic fluidized bed (using dolomite and olivine as catalysts in a secondary reactor, also varying the temperature of the secondary reactor and the catalyst mass), of the solid waste of orange and the results are compared with those obtained in the gasification with non catalytic air. In the processes we use a design of complete factorial experiment of 2k, valuing the influence of the independent variables and their interactions in the answers, using the software Design-Expert version 7 and a grade of significance of 95 %. The results demonstrate the qualities of the solid waste of orange in the energy use by means of the gasification process for the treatment of these residuals, obtaining a gas of low caloric value. The use of catalysts also diminishes the yield of tars obtained in the gasification process, being more active the dolomite that the olivine in this process. (author)

  7. Attempts on cardoon gasification in two different circulating fluidized beds

    Directory of Open Access Journals (Sweden)

    Chr. Christodoulou

    2014-11-01

    Full Text Available Few tests have been carried out in order to evaluate the use of cardoon in gasification and combustion applications most of the researchers dealt with agglomeration problems. The aim of this work is to deal with the agglomeration problem and to present a solution for the utilization of this biofuel at a near industrial application scale. For this reason, two experiments were conducted, one in TU Delft and one in Centre for Research and Technology Hellas (CERTH, using fuel cardoon and 50% w/w cardoon blended with 50% w/w giant reed respectively. Both experimental campaigns were carried out in similar atmospheric circulating fluidized bed gasifiers. Apart from the feedstock, the other differences were the gasification medium and the bed material used in each trial. The oxidizing agent at TUD׳s run was O2/steam, whereas CERTH׳s tests used air. When experiments with the cardoon 50% w/w–giant reed 50% w/w blend were performed no agglomeration problems were presented. Consequently, gasification could be achieved in higher temperature than that of pure cardoon which led to the reduction of tar concentration.

  8. Mathematical modelling and optimization of biomass-plastic fixed-bed downdraft co-gasification process

    Science.gov (United States)

    Donskoy, Igor

    2017-10-01

    Co-gasification of woody biomass and polyethylene is studied using mathematical modeling. The gasification process is downdraft fixed-bed. Comparison of modeling results with some experimental data is made. Influence of biomass/plastic ratio and air equivalence ratio on gasification efficiency is investigated.

  9. Mathematical modelling and optimization of biomass-plastic fixed-bed downdraft co-gasification process

    Directory of Open Access Journals (Sweden)

    Donskoy Igor

    2017-01-01

    Full Text Available Co-gasification of woody biomass and polyethylene is studied using mathematical modeling. The gasification process is downdraft fixed-bed. Comparison of modeling results with some experimental data is made. Influence of biomass/plastic ratio and air equivalence ratio on gasification efficiency is investigated.

  10. Gasification of solid waste — potential and application of co-current moving bed gasifiers

    NARCIS (Netherlands)

    Groeneveld, M.J.; van Swaaij, Willibrordus Petrus Maria

    1979-01-01

    A review is given of gasification processes for solid fuels with special emphasis on waste gasification. Although the co-current moving bed gasifier has not been under consideration for a long time, it offers interesting possibilities for waste gasification. Some operational data are given. Two

  11. Waste-gasification efficiency of a two-stage fluidized-bed gasification system.

    Science.gov (United States)

    Liu, Zhen-Shu; Lin, Chiou-Liang; Chang, Tsung-Jen; Weng, Wang-Chang

    2016-02-01

    This study employed a two-stage fluidized-bed gasifier as a gasification reactor and two additives (CaO and activated carbon) as the Stage-II bed material to investigate the effects of the operating temperature (700°C, 800°C, and 900°C) on the syngas composition, total gas yield, and gas-heating value during simulated waste gasification. The results showed that when the operating temperature increased from 700 to 900°C, the molar percentage of H2 in the syngas produced by the two-stage gasification process increased from 19.4 to 29.7mol% and that the total gas yield and gas-heating value also increased. When CaO was used as the additive, the molar percentage of CO2 in the syngas decreased, and the molar percentage of H2 increased. When activated carbon was used, the molar percentage of CH4 in the syngas increased, and the total gas yield and gas-heating value increased. Overall, CaO had better effects on the production of H2, whereas activated carbon clearly enhanced the total gas yield and gas-heating value. Crown Copyright © 2015. Published by Elsevier Ltd. All rights reserved.

  12. Fixed-bed gasification research using US coals. Volume 11. Gasification of Minnesota peat. [Peat pellets and peat sods

    Energy Technology Data Exchange (ETDEWEB)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a coooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the eleventh volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of peat pellets and peat sods during 3 different test periods. 2 refs., 20 figs., 13 tabs.

  13. Characterisation of coal and chars in fluidised bed gasification

    CSIR Research Space (South Africa)

    Oboirien, BO

    2009-03-01

    Full Text Available gasification of high-ash Chinese coal in a pilot plant. The data also shows that the mean particle sizes of the various residual char were smaller than the feed coal and the particle size of the bed char were higher than the particle of the cyclone char... and ultimate analysis Results consisting of proximate and ultimate analyses together calorific value of the parent coals and chars are presented in Table 4. The ash content of the different coal samples ranges from 33.4- 40.4 wt %, the calorific value...

  14. Fixed bed gasification for production of industrial fuel gas

    Energy Technology Data Exchange (ETDEWEB)

    1977-10-01

    This report summarizes the results of technical and economic evaluations of six commercially available, fixed-bed coal gasification processes for the production of industrial fuel gas. The study was performed for DOE and is intended to assist industrial companies in exploring the feasibility of producing gaseous fuels for both retrofit and new industrial plant situations. The report includes a technical analysis of the physical configuration, performance capabilities, and commercial experiments to-date for both air-blown and oxygen-blown fixed bed gasifiers. The product gas from these gasifiers is analyzed economically for three different degrees of cleanliness: (1) hot raw gas, (2) dust-, tar-, and oil-free gas, and (3) dust-, tar-, oil-free and desulfurized gas. The evaluations indicate that low-Btu gases produced from fixed bed gasifiers constitute one of the most logical short-term solutions for helping ease the shortage of natural gas for industrial fuel applications because the technology is well-proven and has been utilized on a commercial scale for several decades both in this country and overseas; time from initiation of design to commercial operation is about two years; the technology is not complicated to construct, operate, or maintain; and a reliable supply of product gas can be generated on-site. The advantages and disadvantages of fixed bed gasification technology are listed. The cost of the low Btu gas is estimated at $2 to $4 per MM Btu depending on gas purity, cost of coal ($20 to $50 per ton) and a number of specified assumptions with respect to financing, reliability, etc. (LTN)

  15. Integrated Biomass Gasification with Catalytic Partial Oxidation for Selective Tar Conversion

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Lingzhi; Wei, Wei; Manke, Jeff; Vazquez, Arturo; Thompson, Jeff; Thompson, Mark

    2011-05-28

    requirement for commercial deployment of biomass-based power/heat co-generation and biofuels production. There are several commonly used syngas clean-up technologies: (1) Syngas cooling and water scrubbing has been commercially proven but efficiency is low and it is only effective at small scales. This route is accompanied with troublesome wastewater treatment. (2) The tar filtration method requires frequent filter replacement and solid residue treatment, leading to high operation and capital costs. (3) Thermal destruction typically operates at temperatures higher than 1000oC. It has slow kinetics and potential soot formation issues. The system is expensive and materials are not reliable at high temperatures. (4) In-bed cracking catalysts show rapid deactivation, with durability to be demonstrated. (5) External catalytic cracking or steam reforming has low thermal efficiency and is faced with problematic catalyst coking. Under this program, catalytic partial oxidation (CPO) is being evaluated for syngas tar clean-up in biomass gasification. The CPO reaction is exothermic, implying that no external heat is needed and the system is of high thermal efficiency. CPO is capable of processing large gas volume, indicating a very compact catalyst bed and a low reactor cost. Instead of traditional physical removal of tar, the CPO concept converts tar into useful light gases (eg. CO, H2, CH4). This eliminates waste treatment and disposal requirements. All those advantages make the CPO catalytic tar conversion system a viable solution for biomass gasification downstream gas clean-up. This program was conducted from October 1 2008 to February 28 2011 and divided into five major tasks. - Task A: Perform conceptual design and conduct preliminary system and economic analysis (Q1 2009 ~ Q2 2009) - Task B: Biomass gasification tests, product characterization, and CPO tar conversion catalyst preparation. This task will be conducted after completing process design and system economics analysis

  16. Fixed (slow moving) bed updraft gasification of agricultural residues

    Energy Technology Data Exchange (ETDEWEB)

    Vigouroux, Rolando Zanzi [Royal Institute of Technology (KTH), Stockholm (Sweden). Dept. of Chemical Engineering and Technology], E-mail: rolando@ket.kth.se; Escalona, Ronoldy Faxas [University of Oriente, Santiago de Cuba (Cuba). Fac. of Mechanical Engineering], E-mail: faxas@fim.uo.edu.cu

    2009-07-01

    Birch, in form of pellets has been gasified in updraft fixed-bed gasifier using air as oxidation agent. The main objectives were to study the effect of the treatment conditions on the distribution of the products and the composition of product gas. The influence of the air flow rates on the composition of the producer gas has been studied. The amount of the biomass used in the experiments was varied between 1 and 4 kg and the flow rate of the air was varied from 1.1 to 2.6 m3/h. Increased airflow rates favored higher temperatures. Excessively high airflow rates resulted in fast consumption of the biomass and it also favored combustion over gasification and thus formation of lower amounts of combustible products. High airflow rates caused also higher yields of tars, due to the shorter residence time of the tar-rich gas in the gasifier and thus unfavorable conditions for tar cracking. (author)

  17. Study on biomass pyrolysis and gasification in a fluidized bed

    Energy Technology Data Exchange (ETDEWEB)

    Su, X.; Wang, Z.; Cheng, C.; Tang, S.; Lu, Z.; Li, D. [Tsinghua University, Beijing (China). Thermal Engineering Department

    2000-08-01

    Experimental investigations of biomass pyrolysis and gasification were performed in a fluidized bed reactor with steam and nitrogen as fluid medium respectively. The size of the stainless steel reactor is 150mm ID and 1360mm in height. Five biomass samples including poplar sawdust, bagasse, cotton stem, eucalyptus globulus and pinus ratiata, have been tested on the facility at the temperatures ranging from 923K to 1073K. During each test run, biomass feedstock was fed into the reactor continuously for twelve minutes and without residue discharge, meanwhile seven gas samples were taken, five during the feeding process and two after the stop of feeding. The transient and accumulated gas yields were measured with a rotameter and a gas meter. The temperatures of the fluidized bed and freeboard were acquired by a system of thermocouples connected with a computer. The gas samples were analyzed on a gas chromatograph. On the basis of the experimental results, the variations of gas yield, gas composition, energy conversion efficiency and mass conversion efficiency with temperature are discussed for each biomass feedstock in both cases of steam and nitrogen fluidization. It has been revealed in this investigation that the presence of steam in the fluidized bed reactor stimulates tar cracking to form the gas species of C{sub 2}H{sub 4}and C{sub 2}H{sub 6}, etc. 8 ref., 15 figs., 6 tabs.

  18. Fluidized bed gasification of waste-derived fuels.

    Science.gov (United States)

    Arena, Umberto; Zaccariello, Lucio; Mastellone, Maria Laura

    2010-07-01

    Five alternative waste-derived fuels obtained from municipal solid waste and different post-consumer packaging were fed in a pilot-scale bubbling fluidized bed gasifier, having a maximum feeding capacity of 100 kg/h. The experimental runs utilized beds of natural olivine, quartz sand or dolomite, fluidized by air, and were carried out under various values of equivalence ratio. The process resulted technically feasible with all the materials tested. The olivine, a neo-silicate of Fe and Mg with an olive-green colour, has proven to be a good candidate to act as a bed catalyst for tar removal during gasification of polyolefin plastic wastes. Thanks to its catalytic activity it is possible to obtain very high fractions of hydrogen in the syngas (between 20% and 30%), even using air as the gasifying agent, i.e. in the most favourable economical conditions and with the simplest plant and reactor configuration. The catalytic activity of olivine was instead reduced or completely inhibited when waste-derived fuels from municipal solid wastes and aggregates of different post-consumer plastic packagings were fed. Anyhow, these materials have given acceptable performance, yielding a syngas of sufficient quality for energy applications after an adequate downstream cleaning. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  19. Thermodynamic analysis and conceptual design for partial coal gasification air preheating coal-fired combined cycle

    Science.gov (United States)

    Xu, Yue; Wu, Yining; Deng, Shimin; Wei, Shirang

    2004-02-01

    The partial coal gasification air pre-heating coal-fired combined cycle (PGACC) is a cleaning coal power system, which integrates the coal gasification technology, circulating fluidized bed technology, and combined cycle technology. It has high efficiency and simple construction, and is a new selection of the cleaning coal power systems. A thermodynamic analysis of the PGACC is carried out. The effects of coal gasifying rate, pre-heating air temperature, and coal gas temperature on the performances of the power system are studied. In order to repower the power plant rated 100 MW by using the PGACC, a conceptual design is suggested. The computational results show that the PGACC is feasible for modernizing the old steam power plants and building the new cleaning power plants.

  20. Fluidised bed gasification of high-ash South African coals: An experimental and modelling study

    CSIR Research Space (South Africa)

    Engelbrecht, AS

    2011-11-01

    Full Text Available The gasification of two high-ash coals were studied using a pilot scale fluidised bed gasifier using oxygen enrich air and steam as the gasification agents. The results of the tests show that the fixed carbon conversion and calorific value increases...

  1. Mathematical Modelling of the Fixed-Bed Biomass-Coal Co-Gasification Process

    Directory of Open Access Journals (Sweden)

    Donskoy Igor G.

    2016-01-01

    Full Text Available The paper considers mathematical modelling of downdraft fixed-bed gasification process of the mixtures of woody biomass and coal. Biomass/coal ratio, biomass moisture content and air equivalence ratio are varying parameters. Boundaries of the efficient gasification regimes are estimated.

  2. Fluidised bed gasification of South African coals – experimental results and process integration

    CSIR Research Space (South Africa)

    Engelbrecht, A

    2011-06-01

    Full Text Available high-ash coal from the Waterberg coalfield was tested in a bubbling fluidised bed gasifier at the CSIR using various gasification agents and operating conditions. The results of the tests show that when air and steam are used as the gasification agents...

  3. The influence of partial oxidation mechanisms on tar destruction in TwoStage biomass gasification

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Egsgaard, Helge; Stelte, Wolfgang

    2013-01-01

    and conversion. The study identifies the following major impact factors regarding tar content in the producer gas: oxidation temperature, excess air ratio and biomass moisture content. In a experimental setup, wood pellets were pyrolyzed and the resulting pyrolysis gas was transferred in a heated partial...... tar destruction and a high moisture content of the biomass enhances the decomposition of phenol and inhibits the formation of naphthalene. This enhances tar conversion and gasification in the char-bed, and thus contributes in-directly to the tar destruction....

  4. Artificial neural network models for biomass gasification in fluidized bed gasifiers

    DEFF Research Database (Denmark)

    Puig Arnavat, Maria; Hernández, J. Alfredo; Bruno, Joan Carles

    2013-01-01

    Artificial neural networks (ANNs) have been applied for modeling biomass gasification process in fluidized bed reactors. Two architectures of ANNs models are presented; one for circulating fluidized bed gasifiers (CFB) and the other for bubbling fluidized bed gasifiers (BFB). Both models determin...

  5. Performance analysis of RDF gasification in a two stage fluidized bed-plasma process.

    Science.gov (United States)

    Materazzi, M; Lettieri, P; Taylor, R; Chapman, C

    2016-01-01

    The major technical problems faced by stand-alone fluidized bed gasifiers (FBG) for waste-to gas applications are intrinsically related to the composition and physical properties of waste materials, such as RDF. The high quantity of ash and volatile material in RDF can provide a decrease in thermal output, create high ash clinkering, and increase emission of tars and CO2, thus affecting the operability for clean syngas generation at industrial scale. By contrast, a two-stage process which separates primary gasification and selective tar and ash conversion would be inherently more forgiving and stable. This can be achieved with the use of a separate plasma converter, which has been successfully used in conjunction with conventional thermal treatment units, for the ability to 'polish' the producer gas by organic contaminants and collect the inorganic fraction in a molten (and inert) state. This research focused on the performance analysis of a two-stage fluid bed gasification-plasma process to transform solid waste into clean syngas. Thermodynamic assessment using the two-stage equilibrium method was carried out to determine optimum conditions for the gasification of RDF and to understand the limitations and influence of the second stage on the process performance (gas heating value, cold gas efficiency, carbon conversion efficiency), along with other parameters. Comparison with a different thermal refining stage, i.e. thermal cracking (via partial oxidation) was also performed. The analysis is supported by experimental data from a pilot plant. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

  6. Research into Biomass and Waste Gasification in Atmospheric Fluidized Bed

    Energy Technology Data Exchange (ETDEWEB)

    Skala, Zdenek; Ochrana, Ladislav; Lisy, Martin; Balas, Marek; Kohout, Premysl; Skoblja, Sergej

    2007-07-01

    Considerable attention is paid in the Czech Republic to renewable energy sources. The largest potential, out of them all, have biomass and waste. The aim therefore is to use them in CHP in smaller units (up to 5MWel). These are the subject of the research summarized in our article. The paper presents results of experimental research into gasification in a 100 kW AFB gasifier situated in Energy Institute, Faculty of Mechanical Engineering, Brno University of Technology, and fitted with gas cleaning equipment. Within the research, study was carried out into gas cleaning taking primary measures in the fluidized bed and using hot filter, metal-based catalytic filter, and wet scrubber. Descriptions and diagrams are given of the gasifier and new ways of cleaning. Results include: Impact of various fuels (farming and forest wastes and fast-growing woods and culm plants) on fuel gas quality. Individual kinds of biomass have very different thermal and physical properties; Efficiency of a variety of cleaning methods on content of dust and tars and comparison of these methods; and, Impact of gasifier process parameters on resultant gas quality. (auth)

  7. Modeling Tar Recirculation in Biomass Fluidized Bed Gasification

    NARCIS (Netherlands)

    Heineken, Wolfram; De la Cuesta de Cal, Daniel; Zobel, Nico

    2016-01-01

    A biomass gasification model is proposed and applied to investigate the benefits of tar recirculation within a gasification plant. In the model, tar is represented by the four species phenol, toluene, naphthalene, and benzene. The model is spatially one-dimensional, assuming plug flow for the

  8. Biomass Gasification in Internal Circulating Fluidized Beds: a Thermodynamic Predictive Tool

    Czech Academy of Sciences Publication Activity Database

    Miccio, F.; Svoboda, Karel; Schosger, J.-P.; Baxter, D.

    2008-01-01

    Roč. 25, č. 4 (2008), s. 721-726 ISSN 0256-1115 Institutional research plan: CEZ:AV0Z40720504 Keywords : fluidized bed * gasification * fluidized bed Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 0.830, year: 2008

  9. Air gasification of rice husk in bubbling fluidized bed reactor with bed heating by conventional charcoal.

    Science.gov (United States)

    Makwana, J P; Joshi, Asim Kumar; Athawale, Gaurav; Singh, Dharminder; Mohanty, Pravakar

    2015-02-01

    An experimental study of air gasification of rice husk was conducted in a bench-scale fluidized bed gasifier (FBG) having 210 mm diameter and 1600 mm height. Heating of sand bed material was performed using conventional charcoal fuel. Different operating conditions like bed temperature, feeding rate and equivalence ratio (ER) varied in the range of 750-850 °C, 25-31.3 kg/h, and 0.3-0.38, respectively. Flow rate of air was kept constant (37 m(3)/h) during FBG experiments. The carbon conversion efficiencies (CCE), cold gas efficiency, and thermal efficiency were evaluated, where maximum CCE was found as 91%. By increasing ER, the carbon conversion efficiency was decreased. Drastic reduction in electric consumption for initial heating of gasifier bed with charcoal compared to ceramic heater was ∼45%. Hence rice husk is found as a potential candidate to use directly (without any processing) in FBG as an alternative renewable energy source from agricultural field. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. Gasification of a Dried Sewage Sludge in a Laboratory Scale Fixed Bed Reactor

    Directory of Open Access Journals (Sweden)

    Sebastian Werle

    2015-08-01

    Full Text Available This paper presents an investigation of sewage sludge gasification in a fixed bed gasifier. Experiments were conducted on a laboratory scale fixed bed gasifier. In the experiments, two types of dried sewage sludge were tested and their properties were analysed. Parameters such as air ratio λ = 0.12 to 0.27, gasification agent temperature t = 50 to 250 °C and gasification agent composition ( = 0.21 and  > 0.21 were found to influence on temperature distribution, syngas Lower Heating Value (LHV and syngas composition. The results indicate that the syngas LHV was found to decrease with increased air ratio for all analyzed cases: cold and preheated air and cold enriched air. The increase in the percentage of the main combustible components was accompanied by a decrease in the concentration of carbon dioxide. Increasing oxygen concentration increased the temperature, which tended to favor the formation of smaller molecules in the gas mixture. Thus, the enriched air medium produced a gas with a higher LHV. In contrast to conventional gasification, gasification process with gasification agent preheating causes that the flux of heat necessary to support endothermic gasification reactions is producing more effective. Air preheating causes increases hydrogen and carbon monoxide production.

  11. An Experimental and Numerical Investigation of Fluidized Bed Gasification of Solid Waste

    Directory of Open Access Journals (Sweden)

    Sharmina Begum

    2013-12-01

    Full Text Available Gasification is a thermo-chemical process to convert carbon-based products such as biomass and coal into a gas mixture known as synthetic gas or syngas. Various types of gasification methods exist, and fluidized bed gasification is one of them which is considered more efficient than others as fuel is fluidized in oxygen, steam or air. This paper presents an experimental and numerical investigation of fluidized bed gasification of solid waste (SW (wood. The experimental measurement of syngas composition was done using a pilot scale gasifier. A numerical model was developed using Advanced System for Process ENgineering (Aspen Plus software. Several Aspen Plus reactor blocks were used along with user defined FORTRAN and Excel code. The model was validated with experimental results. The study found very similar performance between simulation and experimental results, with a maximum variation of 3%. The validated model was used to study the effect of air-fuel and steam-fuel ratio on syngas composition. The model will be useful to predict the various operating parameters of a pilot scale SW gasification plant, such as temperature, pressure, air-fuel ratio and steam-fuel ratio. Therefore, the model can assist researchers, professionals and industries to identify optimized conditions for SW gasification.

  12. Temporal measurements and kinetics of selenium release during coal combustion and gasification in a fluidized bed

    International Nuclear Information System (INIS)

    Shen, Fenghua; Liu, Jing; Zhang, Zhen; Yang, Yingju

    2016-01-01

    Highlights: • The temporal release of Se from coal combustion and gasification was measured. • Kinetic laws for Se release from coal combustion and gasification were determined. • The influences of temperature and chemical composition of flue gas were clarified. • The interactions of Se species with mineral affect the release kinetics of Se. - Abstract: The temporal release of selenium from coal during combustion and gasification in a fluidized bed was measured in situ by an on-line analysis system of trace elements in flue gas. The on-line analysis system is based on an inductively coupled plasma optical emission spectroscopy (ICP-OES), and can measure concentrations of trace elements in flue gas quantitatively and continuously. The results of on-line analysis suggest that the concentration of selenium in flue gas during coal gasification is higher than that during coal combustion. Based on the results of on-line analysis, a second-order kinetic law r(x) = 0.94e −26.58/RT (−0.56 x 2 −0.51 x + 1.05) was determined for selenium release during coal combustion, and r(x) = 11.96e −45.03/RT (−0.53 x 2 −0.56 x + 1.09) for selenium release during coal gasification. These two kinetic laws can predict respectively the temporal release of selenium during coal combustion and gasification with an acceptable accuracy. Thermodynamic calculations were conducted to predict selenium species during coal combustion and gasification. The speciation of selenium in flue gas during coal combustion differs from that during coal gasification, indicating that selenium volatilization is different. The gaseous selenium species can react with CaO during coal combustion, but it is not likely to interact with mineral during coal gasification.

  13. Transient Catalytic Activity of Calcined Dolomitic Limestone in a Fluidized Bed during Gasification of Woody Biomass.

    Czech Academy of Sciences Publication Activity Database

    Pohořelý, Michael; Jeremiáš, Michal; Skoblia, S.; Beňo, Z.; Šyc, Michal; Svoboda, Karel

    2016-01-01

    Roč. 30, č. 5 (2016), s. 4065-4071 ISSN 0887-0624 R&D Projects: GA ČR GC14-09692J Institutional support: RVO:67985858 Keywords : fluidized- bed gasification * woody biomass * limestone Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 3.091, year: 2016

  14. Steam-air fluidized bed gasification of distillers grains: Effects of steam to biomass ratio, equivalence ratio and gasification temperature.

    Science.gov (United States)

    Kumar, Ajay; Eskridge, Kent; Jones, David D; Hanna, Milford A

    2009-03-01

    In this study, thermochemical biomass gasification was performed on a bench-scale fluidized-bed gasifier with steam and air as fluidizing and oxidizing agents. Distillers grains, a non-fermentable byproduct of ethanol production, were used as the biomass feedstock for the gasification. The goal was to investigate the effects of furnace temperature, steam to biomass ratio and equivalence ratio on gas composition, carbon conversion efficiency and energy conversion efficiency of the product gas. The experiments were conducted using a 3x3x3 full factorial design with temperatures of 650, 750 and 850 degrees C, steam to biomass ratios of 0, 7.30 and 14.29 and equivalence ratios of 0.07, 0.15 and 0.29. Gasification temperature was found to be the most influential factor. Increasing the temperature resulted in increases in hydrogen and methane contents, carbon conversion and energy efficiencies. Increasing equivalence ratio decreased the hydrogen content but increased carbon conversion and energy efficiencies. The steam to biomass ratio was optimal in the intermediate levels for maximal carbon conversion and energy efficiencies.

  15. Fluidized-Bed Gasification of Plastic Waste, Wood, and Their Blends with Coal

    Directory of Open Access Journals (Sweden)

    Lucio Zaccariello

    2015-08-01

    Full Text Available The effect of fuel composition on gasification process performance was investigated by performing mass and energy balances on a pre-pilot scale bubbling fluidized bed reactor fed with mixtures of plastic waste, wood, and coal. The fuels containing plastic waste produced less H2, CO, and CO2 and more light hydrocarbons than the fuels including biomass. The lower heating value (LHV progressively increased from 5.1 to 7.9 MJ/Nm3 when the plastic waste fraction was moved from 0% to 100%. Higher carbonaceous fines production was associated with the fuel containing a large fraction of coal (60%, producing 87.5 g/kgFuel compared to only 1.0 g/kgFuel obtained during the gasification test with just plastic waste. Conversely, plastic waste gasification produced the highest tar yield, 161.9 g/kgFuel, while woody biomass generated only 13.4 g/kgFuel. Wood gasification showed a carbon conversion efficiency (CCE of 0.93, while the tests with two fuels containing coal showed lowest CCE values (0.78 and 0.70, respectively. Plastic waste and wood gasification presented similar cold gas efficiency (CGE values (0.75 and 0.76, respectively, while that obtained during the co-gasification tests varied from 0.53 to 0.73.

  16. Experimental study of biomass gasification with oxygen-enriched air in fluidized bed gasifier.

    Science.gov (United States)

    Liu, Lingqin; Huang, Yaji; Cao, Jianhua; Liu, Changqi; Dong, Lu; Xu, Ligang; Zha, Jianrui

    2018-06-01

    Considering the universality, renewability and cleanness of biomass, an experimental research is carried out using rice straw in a two-stage fluidized bed. The experimental analysis identified the relevant parameters in the operation of the two-stage fluidized bed to investigate the properties of biomass enriched air gasification. Results show that higher gasification temperature is conducive to enhance the gasification performance. An increasing ER is shown to go against adding gas heat value. When oxygen concentration increases from 21% to 45%, the gas heating value increases from 4.00MJ/kg to 5.24MJ/kg and the gasification efficiency increases from 29.60% to 33.59%, which shows higher oxygen concentration is conducive to higher quality gas and higher gasification efficiency. A secondary oxygen injection leads to reduction of tar concentration from 15.78g/Nm 3 to 10.24g/Nm 3 . The optimal secondary oxygen ratio is about 33.00%. When the secondary oxygen ratio increased to 46.86%, monocyclic aromatics reduced from 28.17% to 19.65% and PAHs increased from 34.97% to 44.05%, leading to the increase aromatization of tar. Copyright © 2018 Elsevier B.V. All rights reserved.

  17. Treatment of Mixed Wastes via Fixed Bed Gasification

    Energy Technology Data Exchange (ETDEWEB)

    None

    1998-10-28

    This report outlines the details of research performed under USDOE Cooperative Agreement DE-FC21-96MC33258 to evaluate the ChemChar hazardous waste system for the destruction of mixed wastes, defined as those that contain both RCRA-regulated haz- ardous constituents and radionuclides. The ChemChar gasification system uses a granular carbonaceous char matrix to immobilize wastes and feed them into the gasifier. In the gasifier wastes are subjected to high temperature reducing conditions, which destroy the organic constituents and immobilize radionuclides on the regenerated char. Only about 10 percent of the char is consumed on each pass through the gasifier, and the regenerated char can be used to treat additional wastes. When tested on a 4-inch diameter scale with a continuous feed unit as part of this research, the ChemChar gasification system was found to be effective in destroying RCRA surrogate organic wastes (chlorobenzene, dichloroben- zene, and napht.halene) while retaining on the char RCRA heavy metals (chromium, nickel, lead, and cadmium) as well as a fission product surrogate (cesium) and a plutonium surrogate (cerium). No generation of harmful byproducts was observed. This report describes the design and testing of the ChemChar gasification system and gives the operating procedures to be followed in using the system safely and effectively for mixed waste treatment.

  18. Non-slag co-gasification of biomass and coal in entrained-bed furnace

    Science.gov (United States)

    Itaya, Yoshinori; Suami, Akira; Kobayashi, Nobusuke

    2018-02-01

    Gasification is a promising candidate of processes to upgrade biomass and to yield clean gaseous fuel for utilization of renewable energy resources. However, a sufficient amount of biomass is not always available to operate a large scale of the plant. Co-gasification of biomass with coal is proposed as a solution of the problem. Tar emission is another subject during operation in shaft or kiln type of gasifiers employed conventionally for biomass. The present authors proposed co-gasification of biomass and coal in entrained-bed furnace, which is a representative process without tar emission under high temperature, but operated so to collect dust as flyash without molten slag formation. This paper presents the works performed on co-gasification performance of biomass and pulverized coal to apply to entrained-bed type of furnaces. At first, co-gasification of woody powder and pulverized coal examined using the lab-scale test furnace of the down-flow entrained bed showed that the maximum temperatures in the furnace was over 1500 K and the carbon conversion to gas achieved at higher efficiency than 80-90 percent although the residence time in the furnace was as short as a few seconds. Non-slag co-gasification was carried out successfully without slag formation in the furnace if coal containing ash with high fusion temperature was employed. The trend suggesting the effect of reaction rate enhancement of co-gasification was also observed. Secondary, an innovative sewage sludge upgrading system consisting of self-energy recovery processes was proposed to yield bio-dried sludge and to sequentially produce char without adding auxiliary fuel. Carbonization behavior of bio-dried sludge was evaluated through pyrolysis examination in a lab-scale quartz tube reactor. The thermal treatment of pyrolysis of sludge contributed to decomposition and removal of contaminant components such as nitrogen and sulfur. The gasification kinetics of sludge and coal was also determined by a

  19. Gasification of biomass and coal in a pressurised fluidised bed gasifier

    Energy Technology Data Exchange (ETDEWEB)

    Andries, J.; Jong, W. de; Hein, K.R.G. [Technische Univ. Delft (Netherlands)

    1998-09-01

    During a 3 year (1996-1998) multinational JOULE project, partly funded by the EU, experimental and theoretical research is being done on co-gasification of biomass (pelletised straw and Miscanthus) and coal in a pressurised fluidised bed reactor. The influence of feedstock and operating conditions on gasification characteristics has been studied using a 1.5 MW{sub th} gasifier, which has been operated at a pressure of 5 bar and temperatures up to 900 C. The project and the test rig are described and results obtained in the first part of the project are presented and analysed. (orig.)

  20. Gasification of biomass in a fixed bed downdraft gasifier--a realistic model including tar.

    Science.gov (United States)

    Barman, Niladri Sekhar; Ghosh, Sudip; De, Sudipta

    2012-03-01

    This study presents a model for fixed bed downdraft biomass gasifiers considering tar also as one of the gasification products. A representative tar composition along with its mole fractions, as available in the literature was used as an input parameter within the model. The study used an equilibrium approach for the applicable gasification reactions and also considered possible deviations from equilibrium to further upgrade the equilibrium model to validate a range of reported experimental results. Heat balance was applied to predict the gasification temperature and the predicted values were compared with reported results in literature. A comparative study was made with some reference models available in the literature and also with experimental results reported in the literature. Finally a predicted variation of performance of the gasifier by this validated model for different air-fuel ratio and moisture content was also discussed. Copyright © 2011 Elsevier Ltd. All rights reserved.

  1. Air-steam gasification of biomass in a fluidised bed: Process optimisation by enriched air

    Energy Technology Data Exchange (ETDEWEB)

    Campoy, Manuel; Gomez-Barea, Alberto; Vidal, Fernando B.; Ollero, Pedro [Bioenergy Group, Chemical and Environmental Engineering Department, Escuela Superior de Ingenieros (University of Seville), Camino de los Descubrimientos s/n. 41092 - Seville (Spain)

    2009-05-15

    The effect of oxygen concentration in the gasification agent was studied by enriched-air-steam biomass gasification tests in a bubbling fluidised-bed gasification (FBG) plant. The oxygen content in the enriched air was varied from 21% (v/v, i.e. air) to 40% (v/v), aiming at simulating FBG where enriched air is produced by membranes. The stoichiometric ratio (ratio of actual to stoichiometric oxygen flow rates) and steam-to-biomass ratio (ratio of steam to biomass, dry and ash-free, flow rates) were varied from 0.24 to 0.38 and from 0 to 0.63, respectively. The tests were conducted under simulated adiabatic and autothermal conditions, to reproduce the behaviour of larger industrial FBG. The temperature of the inlet gasification mixture was fixed consistently at 400 C for all tests, a value that can be achieved by energy recovery from the off-gas in large FBG without tar condensation. It was shown that the enrichment of air from 21 to 40% v/v made it possible to increase the gasification efficiency from 54% to 68% and the lower heating value of the gas from 5 to 9.3 MJ/Nm{sup 3}, while reaching a maximum carbon conversion of 97%. The best conditions were found at intermediate values of steam-to-biomass ratio, specifically within the range 0.25-0.35. The enriched-air-steam gasification concept explored in this work seems to be an interesting option for the improvement of standalone direct air-blown FBG because it considerably improves the process efficiency while maintaining the costs relatively low as compared to oxygen-steam gasification. (author)

  2. Impact of feedstock properties and operating conditions on sewage sludge gasification in a fixed bed gasifier.

    Science.gov (United States)

    Werle, Sebastian

    2014-10-01

    This work presents results of experimental studies on the gasification process of granulated sewage sludge in a laboratory fixed bed gasifier. Nowadays, there is a large and pressing need for the development of thermal methods for sewage sludge disposal. Gasification is an example of thermal method that has several advantages over the traditional combustion. Gasification leads to a combustible gas, which can be used for the generation of useful forms of final energy. It can also be used in processes, such as the drying of sewage sludge directly in waste treatment plant. In the present work, the operating parameters were varied over a wide range. Parameters, such as air ratio λ = 0.12 to 0.27 and the temperature of air preheating t = 50 °C to 250 °C, were found to influence temperature distribution and syngas properties. The results indicate that the syngas heating value decreases with rising air ratio for all analysed cases: i.e. for both cold and preheated air. The increase in the concentration of the main combustible components was accompanied by a decrease in the concentration of carbon dioxide. Preheating of the gasification agent supports the endothermic gasification and increases hydrogen and carbon monoxide production. © The Author(s) 2014.

  3. Modeling of reaction kinetics in bubbling fluidized bed biomass gasification reactor

    Energy Technology Data Exchange (ETDEWEB)

    Thapa, R.K.; Halvorsen, B.M. [Telemark University College, Kjolnes ring 56, P.O. Box 203, 3901 Porsgrunn (Norway); Pfeifer, C. [University of Natural Resources and Life Sciences, Vienna (Austria)

    2013-07-01

    Bubbling fluidized beds are widely used as biomass gasification reactors as at the biomass gasification plant in Gussing, Austria. The reactor in the plant is a dual circulating bubbling fluidized bed gasification reactor. The plant produces 2MW electricity and 4.5MW heat from the gasification of biomass. Wood chips as biomass and olivine particles as hot bed materials are fluidized with high temperature steam in the reactor. As a result, biomass undergoes endothermic chemical reaction to produce a mixture of combustible gases in addition to some carbon-dioxide (CO2). The combustible gases are mainly hydrogen (H2), carbon monoxide (CO) and methane (CH4). The gas is used to produce electricity and heat via utilization in a gas engine. Alternatively, the gas is further processed for gaseous or liquid fuels, but still on the process of development level. Composition and quality of the gas determine the efficiency of the reactor. A computational model has been developed for the study of reaction kinetics in the gasification rector. The simulation is performed using commercial software Barracuda virtual reactor, VR15. Eulerian-Lagrangian approach in coupling of gas-solid flow has been implemented. Fluid phase is treated with an Eulerian formulation. Discrete phase is treated with a Lagrangian formulation. Particle-particle and particle-wall interactions and inter-phase heat and mass transfer have been taken into account. Series of simulations have been performed to study model prediction of the gas composition. The composition is compared with data from the gasifier at the CHP plant in Güssing, Austria. The model prediction of the composition of gases has good agreements with the result of the operating plant.

  4. Experimental and predicted approaches for biomass gasification with enriched air-steam in a fluidised bed.

    Science.gov (United States)

    Fu, Qirang; Huang, Yaji; Niu, Miaomiao; Yang, Gaoqiang; Shao, Zhiwei

    2014-10-01

    Thermo-chemical gasification of sawdust refuse-derived fuel was performed on a bench-scale fluidised bed gasifier with enriched air and steam as fluidising and oxidising agents. Dolomite as a natural mineral catalyst was used as bed material to reform tars and hydrocarbons. A series of experiments were carried out under typical operating conditions for gasification, as reported in the article. A modified equilibrium model, based on equilibrium constants, was developed to predict the gasification process. The sensitivity analysis of operating parameters, such as the fluidisation velocity, oxygen percentage of the enriched air and steam to biomass ratios on the produced gas composition, lower heating value, carbon conversion and cold gas efficiency was investigated. The results showed that the predicted syngas composition was in better agreement with the experimental data compared with the original equilibrium model. The higher fluidisation velocity enhanced gas-solid mixing, heat and mass transfers, and carbon fines elutriation, simultaneously. With the increase of oxygen percentage from 21% to 45%, the lower heating value of syngas increased from 5.52 MJ m(-3) to 7.75 MJ m(-3) and cold gas efficiency from 49.09% to 61.39%. The introduction of steam improved gas quality, but a higher steam to biomass ratio could decrease carbon conversion and gasification efficiency owing to a low steam temperature. The optimal value of steam to biomass ratio in this work was 1.0. © The Author(s) 2014.

  5. Thermal gasification of village rice husk and sawdust in fluidized bed : gasifier operation and thermal efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Gangavati, P.B. [Basaveshwar Engineering College, Bagalkot (India); Mishra, I.M.; Prasad, B. [Indian Inst. of Technology, Roorkee (India). Dept. of Chemical Engineering

    2006-07-01

    An air gasification process for converting rice husks into a renewable fuel was presented. The gasification process was conducted on a fluidized bed gasifier unit comprised of a fluidized bed reactor; an air supply unit; biomass-feeding unit; a high efficiency cyclone; and an after-burner. The performance of the gasifier was evaluated under a range of different operating conditions, fluidization velocities, and equivalence ratios. The aim of the study was to understand the gasification characteristics of the rice husk and compare it with the kinetic behaviour of sawdust. Temperature profiles were analyzed, as well as gas composition and heating values, as well as carbon conversion and thermal efficiencies. The results of the gasification experiments indicated that thermal efficiencies decreased as the fluidization velocity increased. The gas yield increased and the higher heating values decreased with increases in the equivalence ratio (ER) at all the tested velocities. A maximum efficiency of approximately 57 per cent was obtained for the village rice husk, while efficiencies of 72.3 per cent were obtained for the sawdust. 7 ref., 2 figs.

  6. Hydrogen production by biomass steam gasification in fluidized bed reactor with Co catalyst

    International Nuclear Information System (INIS)

    Kazuhiko Tasaka; Atsushi Tsutsumi; Takeshi Furusawa

    2006-01-01

    The catalytic performances of Co/MgO catalysts were investigated in steam gasification of cellulose and steam reforming of tar derived from cellulose gasification. For steam reforming of cellulose tar in a secondary fixed bed reactor, 12 wt.% Co/MgO catalyst attained more than 80% of tar reduction. The amount of produced H 2 and CO 2 increased with the presence of catalyst, and kept same level during 2 hr at 873 K. It is indicated that steam reforming of cellulose tar proceeds sufficiently over Co/MgO catalyst. For steam gasification of cellulose in a fluidized bed reactor, it was found that tar reduction increases with Co loading amount and 36 wt.% Co/MgO catalyst showed 84% of tar reduction. The amounts of produced gas kept for 2 hr indicating that 36 wt.% Co/MgO catalyst is stable during the reaction. It was concluded that these Co catalysts are promising systems for the steam gasification of cellulose and steam reforming of cellulose tar. (authors)

  7. Adiabatic Gasification and Pyrolysis of Coffee Husk Using Air-Steam for Partial Oxidation

    OpenAIRE

    Catalina Rodriguez; Gerardo Gordillo

    2011-01-01

    Colombian coffee industry produces about 0.6 million tons of husk (CH) per year which could serve as feedstock for thermal gasification to produce gaseous and liquid fuels. The current paper deals with: (i) CH adiabatic gasification modeling using air-steam blends for partial oxidation and (ii) experimental thermogravimetric analysis to determine the CH activation energy (E). The Chemical Equilibrium with Applications Program (CEA), developed by NASA, was used to estimate the effect of equiva...

  8. Design and simulation of a circulating fluidized bed to clean the products of biomass gasification

    Energy Technology Data Exchange (ETDEWEB)

    Uchoa Neto, Moises; Carvalho, Yuri de Araujo [Dept. de Engenharia Mecanica. Faculdade de Tecnologia. Universidade de Brasilia, DF (Brazil); Oliveira, Taygoara Felamingo de; Barcelos, Manuel [Faculdade do Gama. Universidade de Brasilia, Gama, DF (Brazil)], e-mail: taygoara@unb.br

    2010-07-01

    The main goal of this work is to design a workbench circulating fluidized bed to study the cracking of tar in gases from the processes of biomass gasification. For this, a design methodology based on analytical results and empirical correlations for fluidized beds was employed. In parallel, a numerical code of open source technology (MFIX) for the solution of the transport equations of the multiphase flow in the column of a fluidized bed was used to give support to the choice of the design elements. The whole project of the workbench fluidized bed was completely developed, whose operation parameters such as bed geometry, gas velocity, circulating ratio and void fraction characterize a fast fluidization process. A preliminary mesh convergence study was executed with the numerical tool, that was validated comparing with analytical results. Among the most important results, the code computed the predicted value for the minimum fluidization. (author)

  9. Simulation of biomass-steam gasification in fluidized bed reactors: Model setup, comparisons and preliminary predictions.

    Science.gov (United States)

    Yan, Linbo; Lim, C Jim; Yue, Guangxi; He, Boshu; Grace, John R

    2016-12-01

    A user-defined solver integrating the solid-gas surface reactions and the multi-phase particle-in-cell (MP-PIC) approach is built based on the OpenFOAM software. The solver is tested against experiments. Then, biomass-steam gasification in a dual fluidized bed (DFB) gasifier is preliminarily predicted. It is found that the predictions agree well with the experimental results. The bed material circulation loop in the DFB can form automatically and the bed height is about 1m. The voidage gradually increases along the height of the bed zone in the bubbling fluidized bed (BFB) of the DFB. The U-bend and cyclone can separate the syngas in the BFB and the flue gas in the circulating fluidized bed. The concentration of the gasification products is relatively higher in the conical transition section, and the dry and nitrogen-free syngas at the BFB outlet is predicted to be composed of 55% H 2 , 20% CO, 20% CO 2 and 5% CH 4 . Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Formation and removal of biomass-derived contaminants in fluidized-bed gasification processes

    Energy Technology Data Exchange (ETDEWEB)

    Kurkela, E. [VTT Energy, Espoo (Finland). Energy Production Technologies

    1996-12-31

    The objectives of this thesis were to examine the effects of the feedstock and the operating conditions of a fluidized-bed gasifier on the formation of tars and nitrogen-containing compounds and to study the effectiveness of the hot gas cleaning methods developed for the removal of particulates, alkali metals, tars and nitrogen-containing compounds. The most essential part of the work was carried out in the pressurized fluidized-bed gasification test facilities composed of an air-blown bubbling fluidized-bed gasifier and subsequent hot gas filter unit. The operation pressure of the test rig could be varied in the range 0.3 - 1.0 MPa and the maximum allowable gasification temperature was 1 050 deg C. The maximum capacity with biomass fuels was 80 kg/h. A wide range of feedstocks from hard coals, lignite and peat to different wood derived fuels and straw were used in the gasification tests. Two different types of ceramic filters were tested in the filter unit connected to the pressurized fluidized-bed gasifier. The filter unit was operated in a temperature range of 400 - 740 deg C. The particulate removal requirements set by the gas turbines were met by both types of filters and with product gases derived from all the feedstocks tested. In addition to the gasification and gas filtration tests, catalytic tar and ammonia decomposition was studied using both laboratory and bench-scale test facilities. Inexpensive calcium-based bulk materials, dolomites and limestones, were efficient tar decomposition catalysts in atmospheric-pressure tests

  11. Mathematical modeling of municipal solid waste plasma gasification in a fixed-bed melting reactor

    OpenAIRE

    Zhang, Qinglin

    2011-01-01

    The increasing yield of municipal solid waste (MSW) is one of the main by-products of modern society. Among various MSW treatment methods, plasma gasification in a fixed-bed melting reactor (PGM) is a new technology, which may provide an efficient and environmental friendly solution for problems related to MSW disposals. General objectives of this work are to develop mathematical models for the PGM process, and using these models to analyze the characteristics of this new technology. In this ...

  12. Gasification of Biomass with CO2 and H2O Mixtures in a Catalytic Fluidised Bed.

    Czech Academy of Sciences Publication Activity Database

    Jeremiáš, Michal; Pohořelý, Michael; Svoboda, Karel; Manovic, V.; Anthony, E.J.; Skoblia, S.; Beňo, Z.; Šyc, Michal

    2017-01-01

    Roč. 210, DEC 15 (2017), s. 605-610 ISSN 0016-2361 R&D Projects: GA ČR GC14-09692J Grant - others:NSC(TW) 103-2923-E-042A-001-MY3 Institutional support: RVO:67985858 Keywords : fluidised bed * gasification * catalyst Subject RIV: JE - Non-nuclear Energetics, Energy Consumption ; Use OBOR OECD: Energy and fuels Impact factor: 4.601, year: 2016

  13. International evaluation of the programme on fluid bed combustion and gasification

    Energy Technology Data Exchange (ETDEWEB)

    Kremer, H. [Ruhr Univ., Bochum (Germany); Magnusson, B.F. [Norwegian Univ. of Science and Technology, Trondheim (Norway); Reed, T. [Colorado School of Mines (United States)

    1996-12-31

    This report on the Swedish National Program on Fluid Bed Combustion and Gasification is part of the on-going evaluation process adopted by the funding organization NUTEK. This agency has invited the undersigned to act as members of an international panel responsible for evaluating the progress made in 9 projects initiated between 1993-1996. The output of this evaluation procedure is given in this report. The main aim of the Fluid Bed Combustion and Gasification Program is to develop industrially relevant knowledge and competence in experimental and computational techniques capable of characterizing the flow, heat transfer, combustion, gasification, ash formation and deposition and emissions in fluid bed gasifiers and combustors. To achieve this aim NUTEK is sponsoring research in a number of universities and encourages close cooperation between universities and industry. In the evaluation of the various sponsored research programs, the evaluation committee has considered the following key points: relevance of research to industrial needs; originality of research; program management; adequacy of resources; degree of collaboration between industry and academia; international standing of research. In this report comments and recommendations are made on individual projects as well as on the programme in general and they express the unanimous view of the panel members

  14. Theoretical and experimental studies of fixed-bed coal gasification reactors. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Joseph, B.; Bhattacharya, A.; Salam, L.; Dudukovic, M.P.

    1983-09-01

    A laboratory fixed-bed gasification reactor was designed and built with the objective of collecting operational data for model validation and parameter estimation. The reactor consists of a 4 inch stainless steel tube filled with coal or char. Air and steam is fed at one end of the reactor and the dynamic progress of gasification in the coal or char bed is observed through thermocouples mounted at various radial and axial locations. Product gas compositions are also monitored as a function of time. Results of gasification runs using Wyoming coal are included in this report. In parallel with the experimental study, a two-dimensional model of moving bed gasifiers was developed, coded into a computer program and tested. This model was used to study the laboratory gasifier by setting the coal feed rate equal to zero. The model is based on prior work on steady state and dynamic modeling done at Washington University and published elsewhere in the literature. Comparisons are made between model predictions and experimental results. These are also included in this report. 23 references, 18 figures, 6 tables.

  15. Tar removal during the fluidized bed gasification of plastic waste.

    Science.gov (United States)

    Arena, Umberto; Zaccariello, Lucio; Mastellone, Maria Laura

    2009-02-01

    A recycled polyethylene was fed in a pilot plant bubbling fluidized bed gasifier, having an internal diameter of 0.381 m and a maximum feeding capacity of 90 kg/h. The experimental runs were carried out under various operating conditions: the bed temperature was kept at about 850 degrees C, the equivalence ratio varied between 0.2 and 0.35, the amount of bed material was between 131 and 215 kg, the fluidizing velocity was between 0.5 and 0.7 m/s, quartz sand and olivine were used as bed material, and air and steam were used as fluidizing reactants. The results confirm that the tar removal treatments applied inside the gasifier (primary methods) can eliminate or strongly reduce the need for a further downstream cleanup of the syngas. In particular, the utilization of a natural olivine as an in situ tar reduction agent remarkably improves the quality of the product gas, in terms of both high hydrogen volumetric fraction and larger syngas yield.

  16. Gas generation by co-gasification of biomass and coal in an autothermal fluidized bed gasifier

    International Nuclear Information System (INIS)

    Wang, Li-Qun; Chen, Zhao-Sheng

    2013-01-01

    In this study, thermochemical biomass and coal co-gasification were performed on an autothermal fluidized bed gasifier, with air and steam as oxidizing and gasifying media. The experiments were completed at reaction temperatures of 875 °C–975 °C, steam-to-biomass ratio of 1.2, and biomass-to-coal ratio of 4. This research aims to determine the effects of reaction temperature on gas composition, lower heating value (LHV), as well as energy and exergy efficiencies, of the product gas. Over the ranges of the test conditions used, the product gas LHV varies between 12 and 13.8 MJ/Nm 3 , and the exergy and energy efficiencies of the product gas are in the ranges of 50.7%–60.8% and 60.3%–85.1%, respectively. The results show that high reaction temperature leads to higher H 2 and CO contents, as well as higher exergy and energy efficiencies of the product gas. In addition, gas LHV decreases with temperature. The molar ratio of H 2 /CO is larger than 1 at temperatures above 925 °C. Our experimental analysis shows that co-gasification of biomass and coal in an autothermal fluidized bed gasifier for gas production is feasible and promising. -- Highlights: • An innovative steam co-gasification process for gas production was proposed. • Co-gasification of biomass and coal in an autothermal fluidized bed gasifier was tested. • High temperature favors H 2 production. • H 2 and CO contents increase, whereas CO 2 and CH 4 levels decrease with increase in T. • Exergy and energy efficiencies of gases increase with increase in T

  17. Low temperature circulating fluidized bed gasification and co-gasification of municipal sewage sludge. Part 1: Process performance and gas product characterization

    DEFF Research Database (Denmark)

    Thomsen, Tobias Pape; Sárossy, Zsuzsa; Gøbel, Benny

    2017-01-01

    Results from five experimental campaigns with Low Temperature Circulating Fluidized Bed (LT-CFB) gasification of straw and/or municipal sewage sludge (MSS) from three different Danish municipal waste water treatment plants in pilot and demonstration scale are analyzed and compared. The gasification...... process is characterized with respect to process stability, process performance and gas product characteristics. All experimental campaigns were conducted at maximum temperatures below 750°C, with air equivalence ratios around 0.12 and with pure silica sand as start-up bed material. A total of 8600kg...... particles in the system. Co-gasification of MSS with sufficient amounts of cereal straw was found to be an effective way to mitigate these issues as well as eliminate thermal MSS drying requirements. Characterization of gas products and process performance showed that even though gas composition varied...

  18. Gasification of bio char from empty fruit bunch in a fluidized bed

    International Nuclear Information System (INIS)

    Nsamba Hussein Kisiki; Amran Mohammad Salleh; Wan Azlina; Hamdan Yusof

    2010-01-01

    Full text: Bio char from empty fruit bunch was gasified in a fluidized bed reactor using compressed air as a gasifying agent. The experiment was conducted in the temperature ranges of 500-850 degree Celsius and the equivalence ratio, temperature and size of the feedstock was varied. A series of parameters such as gas yield, overall carbon conversion, gas quality, and composition, were measured as a function of temperature, equivalence ratio and temperature. Results obtained were compared to the actual values of coal and other gasification feedstock reveal that, bio char has the potential to replace coal as a gasification agent in power plants .Hydrogen gas from bio char was also optimized during the experiment. There is great potential of making Hydrogen from Bio char through thermo chemical gasification It was observed that it has a very great potential of being upgraded to Fischer Tropsh fuels. There is a great opportunity of using this char from empty fruit bunch as an alternative fuel in power plants and all the adverse effects of coal gasification can be counteracted. (author)

  19. Gasification of refuse derived fuel in a fixed bed reactor for syngas production.

    Science.gov (United States)

    Dalai, Ajay K; Batta, Nishant; Eswaramoorthi, I; Schoenau, Greg J

    2009-01-01

    Steam gasification of two different refuse derived fuels (RDFs), differing slightly in composition as well as thermal stability, was carried out in a fixed-bed reactor at atmospheric pressure. The proximate and ultimate analyses reveal that carbon and hydrogen are the major components in RDFs. The thermal analysis indicates the presence of cellulose and plastic based materials in RDFs. H2 and CO are found to be the major products, along with CO2 and hydrocarbons resulting from gasification of RDFs. The effect of gasification temperature on H2 and CO selectivities was studied, and the optimum temperature for better H2 and CO selectivity was determined to be 725 degrees C. The calorific value of product gas produced at lower gasification temperature is significantly higher than that of gas produced at higher process temperature. Also, the composition of RDF plays an important role in distribution of products gas. The RDF with more C and H content is found to produce more amounts of CO and H2 under similar experimental conditions. The steam/waste ratio showed a notable effect on the selectivity of syngas as well as calorific value of the resulting product gas. The flow rate of carrier gas did not show any significant effect on products yield or their distribution.

  20. Artificial neural network based modelling approach for municipal solid waste gasification in a fluidized bed reactor.

    Science.gov (United States)

    Pandey, Daya Shankar; Das, Saptarshi; Pan, Indranil; Leahy, James J; Kwapinski, Witold

    2016-12-01

    In this paper, multi-layer feed forward neural networks are used to predict the lower heating value of gas (LHV), lower heating value of gasification products including tars and entrained char (LHV p ) and syngas yield during gasification of municipal solid waste (MSW) during gasification in a fluidized bed reactor. These artificial neural networks (ANNs) with different architectures are trained using the Levenberg-Marquardt (LM) back-propagation algorithm and a cross validation is also performed to ensure that the results generalise to other unseen datasets. A rigorous study is carried out on optimally choosing the number of hidden layers, number of neurons in the hidden layer and activation function in a network using multiple Monte Carlo runs. Nine input and three output parameters are used to train and test various neural network architectures in both multiple output and single output prediction paradigms using the available experimental datasets. The model selection procedure is carried out to ascertain the best network architecture in terms of predictive accuracy. The simulation results show that the ANN based methodology is a viable alternative which can be used to predict the performance of a fluidized bed gasifier. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Generation of hydrogen rich gas through fluidized bed gasification of biomass.

    Science.gov (United States)

    Karmakar, M K; Datta, A B

    2011-01-01

    The objective of this study was to investigate the process of generating hydrogen rich syngas through thermo chemical fluidized bed gasification of biomass. The experiments were performed in a laboratory scale externally heated biomass gasifier. Rice husk had been taken as a representative biomass and, steam had been used as the fluidizing and gasifying media. A thermodynamic equilibrium model was used to predict the gasification process. The work included the parametric study of process parameters such as reactor temperature and steam biomass ratio which generally influence the percentage of hydrogen content in the product gas. Steam had been used here to generate nitrogen free product gas and also to increase the hydrogen concentration in syngas with a medium range heating value of around 12 MJ/Nm3. Copyright © 2010 Elsevier Ltd. All rights reserved.

  2. Co-gasification of Colombian coal and biomass in fluidized bed: An experimental study

    Energy Technology Data Exchange (ETDEWEB)

    Jhon F. Velez; Farid Chejne; Carlos F. Valdes; Eder J. Emery; Carlos A. Londono [Universidad Nacional de Colombia, Antioquia (Colombia). Grupo de Termodinamica Aplicada y Energias Alternativas

    2009-03-15

    The main results of an experimental work on co-gasification of Colombian biomass/coal blends in a fluidized bed working at atmospheric pressure are reported in this paper. Several samples of blends were prepared by mixing 6-15wt% biomass (sawdust, rice or coffee husk) with coal. Experimental assays were carried out by using mixtures of different steams/blends (Rvc) and air/blend (Rac) ratios showing the feasibility to implement co-gasification as energetic alternative to produce fuel gas to heat and to generate electricity and the possibility of converting clean and efficiently the refuse coal to a low-heating value gas. 29 refs., 5 figs., 4 tabs.

  3. Low temperature circulating fluidized bed gasification and co-gasification of municipal sewage sludge. Part 2: Evaluation of ash materials as phosphorus fertilizer.

    Science.gov (United States)

    Thomsen, Tobias Pape; Hauggaard-Nielsen, Henrik; Gøbel, Benny; Stoholm, Peder; Ahrenfeldt, Jesper; Henriksen, Ulrik B; Müller-Stöver, Dorette Sophie

    2017-08-01

    The study is part 2 of 2 in an investigation of gasification and co-gasification of municipal sewage sludge in low temperature gasifiers. In this work, solid residuals from thermal gasification and co-gasification of municipal sewage sludge were investigated for their potential use as fertilizer. Ashes from five different low temperature circulating fluidized bed (LT-CFB) gasification campaigns including two mono-sludge campaigns, two sludge/straw mixed fuels campaigns and a straw reference campaign were compared. Experiments were conducted on two different LT-CFBs with thermal capacities of 100kW and 6MW, respectively. The assessment included: (i) Elemental composition and recovery of key elements and heavy metals; (ii) content of total carbon (C) and total nitrogen (N); (iii) pH; (iv) water extractability of phosphorus after incubation in soil; and (v) plant phosphorus response measured in a pot experiment with the most promising ash material. Co-gasification of straw and sludge in LT-CFB gasifiers produced ashes with a high content of recalcitrant C, phosphorus (P) and potassium (K), a low content of heavy metals (especially cadmium) and an improved plant P availability compared to the mono-sludge ashes, thereby showing the best fertilizer qualities among all assessed materials. It was also found that bottom ashes from the char reactor contained even less heavy metals than cyclone ashes. It is concluded that LT-CFB gasification and co-gasification is a highly effective way to purify and sanitize sewage sludge for subsequent use in agricultural systems. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. H₂-rich syngas production by fluidized bed gasification of biomass and plastic fuel.

    Science.gov (United States)

    Ruoppolo, G; Ammendola, P; Chirone, R; Miccio, F

    2012-04-01

    This paper reports the results of gasification tests using a catalytic fluidized bed gasifier to obtain a H(2)-rich stream by feeding different pellets made of wood, biomass/plastic and olive husks to the gasifier. The effects of both the steam supply and an in-bed catalyst on gasifier performance have been investigated. In general, pelletization was an effective pre-treatment for improving the homogeneity of the fuel and the reliability of the feeding devices. The use of biomass/plastic pellets in a catalyst bed yielded good results in terms of the hydrogen concentration (up to 32%vol.), even if an increase in tar production and in the fine/carbon elutriation rate was observed in comparison with wood pellets. Copyright © 2011 Elsevier Ltd. All rights reserved.

  5. Energetic use of wood and biomass by circulating fluidized bed gasification. Final report

    International Nuclear Information System (INIS)

    Ising, M.; Balke, U.; Unger, C.

    1999-06-01

    The project's objective was the development and utilization of a biomass gasification process based on CFB-gasification with dry hot gas upgrading for IC-engine operation. Construction and operation of a test plant at pilot scale with 400 kW fuel input capacity. Development of a mathematical model for CFB-gasification. Reliable operation of CFB-gasifier, good results at partial load and good behaviour at changing the load. Air blown gasification of wood chips yielded lower heating values (LHV) up to 5500 kJ/m 3 (s.T.p., dry) for the gas. Main attention to measures for tar removal. Target value was 3 (s.T.p.) for napthalene + PAH. Average amount of tar after CBF-gasifier at 3000-5000 mg/m 3 (s.T.p.). Primary measures aiming at a decreased tar production were not suitable for achieving the target value. Several secondary measures were tested. Tars could almost completely be cracked or reformed by special catalysts. In continuous test runs of more than 100 h duration tar contents less than 50 mg/m 3 were achieved. A scale up for a catalytic gas cleaning system based on the results is planned. Estimations of economics show the process concept to be advantegous for plants up to 30 MW fuel input capacity. Profitable costs for combined heat and power production from biomass can be expected. (orig.) [de

  6. A new model for coal gasification on pressurized bubbling fluidized bed gasifiers

    International Nuclear Information System (INIS)

    Sánchez, Cristian; Arenas, Erika; Chejne, Farid; Londoño, Carlos A.; Cisneros, Sebastian; Quintana, Juan C.

    2016-01-01

    Highlights: • A new model was proposed for the simulation of fluidized bed reactors. • The model was validated against experimental data found in the literature. • The model was compared and found to be superior to other models reported in the literature. • Effects of pressure, temperature, steam/coal and air/coal ratios over gas composition were studied. - Abstract: Many industries have taken interest in the use of coal gasification for the production of chemicals and fuels. This gasification can be carried out inside a fluidized bed reactor. This non-ideal reactor is difficult to predict due to the complex physical phenomena and the different chemical changes that the feedstock undergoes. The lack of a good model to simulate the reactor’s behavior produces less efficient processes and plant designs. Various approaches to the proper simulation of such reactor have been proposed. In this paper, a new model is developed for the simulation of a pressurized bubbling fluidized bed (PBFB) gasifier that rigorously models the physical phenomena and the chemical changes of the feedstock inside the reactor. In the model, the reactor is divided into three sections; devolatilization, volatile reactions and combustion-gasification. The simulation is validated against experimental data reported in the literature and compared with other models proposed by different authors; once the model is validated, the dependence of the syngas composition on operational pressure, temperature, steam/coal and air/coal ratios are studied. The results of this article show how this model satisfactorily predicts the performance of PBFB gasifiers.

  7. Fluidized-Bed Gasification of Plastic Waste, Wood, and Their Blends with Coal

    OpenAIRE

    Lucio Zaccariello; Maria Laura Mastellone

    2015-01-01

    The effect of fuel composition on gasification process performance was investigated by performing mass and energy balances on a pre-pilot scale bubbling fluidized bed reactor fed with mixtures of plastic waste, wood, and coal. The fuels containing plastic waste produced less H 2 , CO, and CO 2 and more light hydrocarbons than the fuels including biomass. The lower heating value (LHV) progressively increased from 5.1 to 7.9 MJ/Nm 3 when the plastic waste fraction was moved from 0% to 100%. Hig...

  8. Equilibrium modeling of gasification: Gibbs free energy minimization approach and its application to spouted bed and spout-fluid bed gasifiers

    International Nuclear Information System (INIS)

    Jarungthammachote, S.; Dutta, A.

    2008-01-01

    Spouted beds have been found in many applications, one of which is gasification. In this paper, the gasification processes of conventional and modified spouted bed gasifiers were considered. The conventional spouted bed is a central jet spouted bed, while the modified spouted beds are circular split spouted bed and spout-fluid bed. The Gibbs free energy minimization method was used to predict the composition of the producer gas. The major six components, CO, CO 2 , CH 4 , H 2 O, H 2 and N 2 , were determined in the mixture of the producer gas. The results showed that the carbon conversion in the gasification process plays an important role in the model. A modified model was developed by considering the carbon conversion in the constraint equations and in the energy balance calculation. The results from the modified model showed improvements. The higher heating values (HHV) were also calculated and compared with the ones from experiments. The agreements of the calculated and experimental values of HHV, especially in the case of the circular split spouted bed and the spout-fluid bed were observed

  9. Performance of fluidized bed steam gasification of biomass - Modeling and experiment

    Energy Technology Data Exchange (ETDEWEB)

    Loha, Chanchal; Chatterjee, Pradip K. [Thermal Engineering Group, Central Mechanical Engineering Research Institute, CSIR, Durgapur 713 209 (India); Chattopadhyay, Himadri [Dept. of Mechanical Engineering, Jadavpur University, Kolkata 700 032 (India)

    2011-03-15

    This paper presents the investigation of the performance from different biomasses in a fluidized bed gasifier where steam has been used as gasifying as well as fluidizing agent. An experimental setup is fabricated to study the gasification performance of rice husk, which is of special relevance to rice-producing countries like China and India. An equilibrium modeling approach is deployed to predict the gas composition which has been compared with the experimental results. Calibration of the model with appropriate modeling coefficients was necessary to achieve close resemblance with the experimental values. Further, the model is used to predict the gas compositions from other biomass and benchmarked with the performance of coal. In this study, the gasification temperature is varied from 650 C to 800 C, whereas the steam-to-biomass ratio (S/B) is varied from 0.75 to 2.00. As the gasification temperature increases, the production of H{sub 2} and CO increases but the generation of CH{sub 4} and CO{sub 2} reduces. The steam-to-biomass ratio was again found to influence the production rates. With increasing steam input, H{sub 2}, CO{sub 2} and CH{sub 4} were found to increase while CO reduces. (author)

  10. Air gasification of biogas-derived digestate in a downdraft fixed bed gasifier.

    Science.gov (United States)

    Chen, Guanyi; Guo, Xiang; Cheng, Zhanjun; Yan, Beibei; Dan, Zeng; Ma, Wenchao

    2017-11-01

    Digestate is a byproduct from biomass anaerobic digestion process. Gasification of dried digestate to produce gasesous product might be a promising route. In this work, air gasification of digestate with high ash content was performed in a downdraft fixed bed gasifier at temperature varying from 600°C to 800°C and air equivalence ratio (ER) ranging from 0.25 to 0.30. The ash melting properties were firstly detected by the Intelligent Ash Melting Point Test, and the by-products (biochar and ash) were analyzed. The results showed that no ash slagging was observed and therefore it is feasible to operate digestate gasification under 800°C and ER ranging from 0.25 to 0.30. High temperature favored gas production, 800°C is proposed for digestate gasification in the present study. ER with a medium value improved gas quality and cold gas efficiency (CGE), and the optimal LHV of 4.78MJ/Nm 3 and CGE of 67.01% were obtained with ER of 0.28. High ER favored the increase of gas yield and decrease of tar concentration, and the optimal gas yield of 2.15 Nm 3 /kg and tar concentration of 1.61g/Nm 3 were achieved with ER of 0.30. Improved molar ratio of H 2 /CO varying from 1.03 to 1.08 was obtained at 800°C, indicating gaseous product has the potential for chemical synthesis processes (1

  11. Assessing the gasification potential of five woodchips species by employing a lab-scale fixed-bed downdraft reactor

    International Nuclear Information System (INIS)

    Sarker, Shiplu; Nielsen, Henrik Kofoed

    2015-01-01

    Highlights: • Fixed-bed downdraft lab scale gasification of 3 forest and 2 energy crops. • Gasification condition was varied in-terms of ER (0.19–0.80). • Energy crops gave mean bed temperature >750 °C and highest H 2 yield. • Spruce resulted inferior gasification performance than that of the other biomass. - Abstract: This paper is aimed to assess the performance of air blown fixed-bed downdraft gasification of local lignocellulosic biomasses which in perspective of Southern Norway are both available and sustainable. Long rotation forest crops birch, oak and spruce, coupled with energy crops poplar and willow were used as feedstocks. The gasification conditions undertaken were widely varied in-terms of air (∼3.20–4.20 N m 3 /h) and fuel flow (∼1.70–2.10 kg/h) so that the corresponding equivalence ratio (ER) differed (0.19–0.80) and ultimately reflected to other operational parameters such as bed temperature (∼550–760 °C maximum), producer gas yield (∼1.50–2.30 N m 3 /kg, wet base), cold gas efficiency (∼35–51%), carbon conversion efficiency (∼61–76%) and so on. An emphasis was also placed on evaluating material balance by accounting the by-products (such as tar, char) of gasification so that the system reliability is identified. Overall, the gasification performance of different woody biomass was found viable over a broad range of operating condition which is appealing in contributing this technology in the context of regional bioenergy and thus towards the renewable energy

  12. Study on biomass circulation and gasification performance in a clapboard-type internal circulating fluidized bed gasifier.

    Science.gov (United States)

    Zhou, Zhao-qiu; Ma, Long-long; Yin, Xiu-li; Wu, Chuang-zhi; Huang, Li-cheng; Wang, Chu

    2009-01-01

    We investigated the solid particle flow characteristics and biomass gasification in a clapboard-type internal circulating fluidized bed reactor. The effect of fluidization velocity on particle circulation rate and pressure distribution in the bed showed that fluidization velocities in the high and low velocity zones were the main operational parameters controlling particle circulation. The maximum internal circulation rates in the low velocity zone came almost within the range of velocities in the high velocity zone, when u(H)/u(mf)=2.2-2.4 for rice husk and u(H)/u(mf)=3.5-4.5 for quartz sand. In the gasification experiment, the air equivalence ratio (ER) was the main controlling parameter. Rice husk gasification gas had a maximum heating value of around 5000 kJ/m(3) when ER=0.22-0.26, and sawdust gasification gas reached around 6000-6500 kJ/m(3) when ER=0.175-0.24. The gasification efficiency of rice husk reached a maximum of 77% at ER=0.28, while the gasification efficiency of sawdust reached a maximum of 81% at ER=0.25.

  13. On partial fluidization in rotating fluidized beds

    International Nuclear Information System (INIS)

    Kao, J.; Pfeffer, R.; Tardos, G.I.

    1987-01-01

    In a rotating fluidized bed, unlike in a conventional fluidized bed, the granules are fluidized layer by layer from the (inner) free surface outward at increasing radius as the gas velocity is increased. This is a very significant and interesting phenomenon and is extremely important in the design of these fluidized beds. The phenomenon was first suggested in a theoretical analysis and recently verified experimentally in the authors' laboratory. However, in the first paper, the equations presented are too cumbersome and the influence of bed thickness is not clearly stated. In this note the authors present simplified equations, based on that paper, for the pressure drop and the minimum fluidizing velocities in a rotating fluidized bed. Experimental data are also shown and compared with the theoretical model, and the effect of bed thickness is shown. Furthermore, an explanation for the observation of a maximum in the pressure drop vs. velocity curve instead of the plateau derived by Chen is proposed

  14. The formation of impurities in fluidized-bed gasification of biomass, peat and coal; Epaepuhtauksien muodostuminen leijukerroskaasutuksessa

    Energy Technology Data Exchange (ETDEWEB)

    Kurkela, E.; Laatikainen-Luntama, J.; Kurkela, M.; Leppaelahti, J.; Koljonen, T.; Oesch, P. [VTT Energy, Espoo (Finland); Alen, R. [Jyvaeskylae Univ. (Finland)

    1996-12-01

    The objective of this three-year-long project was to study the effects of different process parameters and bed materials on the formation of impurities in pressurized fluidized-bed gasification. The main emphasis of the project was focused on the formation of tars and nitrogen compounds in wood, peat and coal gasification. The aims of the research were to find out such operating conditions, where the formation of problematic high-molecular-weight tars can be minimised and to create a better understanding on the fate of fuel nitrogen in fluidized-bed gasifiers. Main part of the research was carried out in a bench-scale pressurised fluidized-bed reactor (ID 30 mm), where the effects of pressure, temperature, gas atmosphere and bed material were studied with different feedstocks. Most of the test series were carried out using the same feedstocks as earlier used in the PDU-scale fluidized-bed gasification tests of VTT (pine wood, pine bark, wheat straw, two peats, Rhenish brown coal, Polish and Illinois No.6 bituminous coals). The effects of operating parameters on the product yields (gas components, tars, char) were first studied under inert nitrogen atmosphere. The conversion of fuel nitrogen into ammonia and HCN were also determined for the different feedstocks over the different operating conditions. These studies showed that ammonia is the main fixed nitrogen compound of fluidized-bed pyrolysis with all the feedstocks studied. The conversions of fuel nitrogen into ammonia and HCN was highest with the high volatile fuels and lowest with the two hard coals. Gas atmosphere had a dramatic effect on the conversion of fuel nitrogen; much higher ammonia yields were determined in real gasification gas atmosphere than in inert pyrolysis carried out in N{sub 2} or Argon atmosphere. In addition to the pressurised fluidized-bed pyrolysis tests, laboratory scale pyrolysis research was carried out in order to compare the pyrolysis behaviour of the different feedstocks

  15. Allothermal steam gasification of biomass in cyclic multi-compartment bubbling fluidized-bed gasifier/combustor - new reactor concept.

    Science.gov (United States)

    Iliuta, Ion; Leclerc, Arnaud; Larachi, Faïçal

    2010-05-01

    A new reactor concept of allothermal cyclic multi-compartment fluidized bed steam biomass gasification is proposed and analyzed numerically. The concept combines space and time delocalization to approach an ideal allothermal gasifier. Thermochemical conversion of biomass in periodic time and space sequences of steam biomass gasification and char/biomass combustion is simulated in which the exothermic combustion compartments provide heat into an array of interspersed endothermic steam gasification compartments. This should enhance unit heat integration and thermal efficiency and procure N(2)-free biosyngas with recourse neither to oxygen addition in steam gasification nor contact between flue and syngas. The dynamic, one-dimensional, multi-component, non-isothermal model developed for this concept accounts for detailed solid and gas flow dynamics whereupon gasification/combustion reaction kinetics, thermal effects and freeboard-zone reactions were tied. Simulations suggest that allothermal operation could be achieved with switch periods in the range of a minute supporting practical feasibility for portable small-scale gasification units. Copyright 2009 Elsevier Ltd. All rights reserved.

  16. The effect of Jatropha torrified biomass and coal preparation on steam co-gasification in a fixed bed reactor

    Science.gov (United States)

    Aloqaili, Mashal Mohammed

    Coal fired power stations produce vast amounts of harmful products that may affect our health and environment. Co-gasification of coal and biomass could be a solution to this issue as an emerging technology. Biomass may reduce emissions significantly and it may contribute to reducing capital operational cost while providing high gas yields. This research tests the co-gasification of coal and biomass blended chars. Coal and biomass were both prepared. Coal Illinois No #6 was prepared as coal semi-char and coal-char while Jatropha biomass was torrefied at six different temperatures ranging from [200-300] ºC. The co-gasification experiments was conducted in a fixed-bed reactor. A gasification temperature was 900 ºC and a constant flow rate of 100 mL/min. Carbon conversion, maximum char reactivity, products yield and amount of hydrogen produced were evaluated and studied based on data obtained from the G.C. Additionally, weight of bed material and ash leftover weight from gasification process were significantly contributed in calculating the carbon conversion percentages.

  17. Effect of Operating Conditions on Catalytic Gasification of Bamboo in a Fluidized Bed

    Directory of Open Access Journals (Sweden)

    Thanasit Wongsiriamnuay

    2013-01-01

    Full Text Available Catalytic gasification of bamboo in a laboratory-scale, fluidized bed reactor was investigated. Experiments were performed to determine the effects of reactor temperature (400, 500, and 600°C, gasifying medium (air and air/steam, and catalyst to biomass ratio (0 : 1, 1 : 1, and 1.5 : 1 on product gas composition, H2/CO ratio, carbon conversion efficiency, heating value, and tar conversion. From the results obtained, it was shown that at 400°C with air/steam gasification, maximum hydrogen content of 16.5% v/v, carbon conversion efficiency of 98.5%, and tar conversion of 80% were obtained. The presence of catalyst was found to promote the tar reforming reaction and resulted in improvement of heating value, carbon conversion efficiency, and gas yield due to increases in H2, CO, and CH4. The presence of steam and dolomite had an effect on the increasing of tar conversion.

  18. Improved steam gasification of lignocellulosic residues in a fluidized bed with commercial steam reforming catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Aznar, M.P.; Corella, J.; Delgado, J.; Lahoz, J. (Univ. of Zaragoza (Spain))

    1993-01-01

    The improved/two-stage steam gasification of biomass or lignocellulosic residues in fluidized bed with steam reforming catalysts placed in a downstream secondary reactor has been studied. Two commercial catalysts, R-67 and RKS-1 from Topsoee, were used at their incipient fluidization conditions. At 720-760 C and space-times of only 0.10-0.20 s, with catalyst sizes under 1.0 mm and with steam/biomass ratios of 1.2-1.6, tar conversions of 99.95% were achieved in the catalytic reactor. In this process, tar and methane in the flue gas can be easily lowered below 5 mg/m[sup 3](NTP) and 0.5 vol %, respectively, without using oxygen. The catalyst deactivation by coke from the tar cracking is the main problem of this process.

  19. Biomass gasification in a circulating fluidized bed; Vergasung von Biomasse in der zirkulierenden Wirbelschicht

    Energy Technology Data Exchange (ETDEWEB)

    Ising, M.; Hoelder, D.; Backhaus, C.; Althaus, W. [Fraunhofer Inst. fuer Umwelt-, Sicherheits- und Energietechnik UMSICHT, Oberhausen (Germany)

    1998-09-01

    Biomass gasification in a circulating fluidized bed, in combination with a gas engine or gas burner, is a promising option for energetic use of biomass. Economic efficiency analyses on the basis of the UMSICHT plant show that this technology for combined heat and power generation from biomass is promising also for the range below 10 MW. The economic situation of any plant must be considered for the specific boundary conditions imposed by the power supply industry. The feasibility of the process was tested in a demonstration plant at Oberhausen. The plant was optimized further in extensive test series, and a number of tar reduction processes were investigated and improved on. The authors now intend to prove that gasification in a circulating fluidized bed combined with a gas engine cogeneration plant is feasible in continuous operation. (orig./SR) [Deutsch] Die Vergasung von Biomasse in der zirkulierenden Wirbelschicht ist in Kombination mit einem Gasmotor oder einem Gasbrenner eine vielversprechende Option fuer die energetische Biomassenutzung. Wirtschaftlichkeitsbetrachtungen auf Basis der UMSICHT-Anlage zeigen, dass diese Technologie fuer die gekoppelte Strom- und Waermeerzeugung aus Biomasse auch im Leistungsbereich unter 10 MW grosse Chancen verspricht. Dabei ist die oekonomische Situation einer Anlage im Einzelfall unter Beachtung der energiewirtschaftlichen Randbedingungen zu beurteilen. Durch den Betrieb einer Demonstrationsanlage in Oberhausen konnte die Funktion des Verfahrens nachgewiesen werden. In weiteren umfangreichen Versuchsreihen werden die Anlage weiter optimiert und verschiedene Konzepte zur Teerminderung untersucht und weiterentwickelt. Angestrebt ist der Nachweis des Dauerbetriebs von ZWS-Vergasung zusammen mit dem Gasmotoren-BHKW. (orig./SR)

  20. Adiabatic Gasification and Pyrolysis of Coffee Husk Using Air-Steam for Partial Oxidation

    Directory of Open Access Journals (Sweden)

    Catalina Rodriguez

    2011-01-01

    Full Text Available Colombian coffee industry produces about 0.6 million tons of husk (CH per year which could serve as feedstock for thermal gasification to produce gaseous and liquid fuels. The current paper deals with: (i CH adiabatic gasification modeling using air-steam blends for partial oxidation and (ii experimental thermogravimetric analysis to determine the CH activation energy (E. The Chemical Equilibrium with Applications Program (CEA, developed by NASA, was used to estimate the effect of equivalence ratio (ER and steam to fuel ratio (S : F on equilibrium temperature and gas composition of ~150 species. Also, an atom balance model was developed for comparison purposes. The results showed that increased ER and (S : F ratios produce mixtures that are rich in H2 and CO2 but poor in CO. The value for the activation energy was estimated to be 221 kJ/kmol.

  1. Biomass gasification : The understanding of sulfur, tar, and char reaction in fluidized bed gasifiers

    NARCIS (Netherlands)

    Meng, X.

    2012-01-01

    As one of the currently available thermo-chemical conversion technologies, biomass gasification has received considerable interest since it increases options for combining with various power generation systems. The product gas or syngas produced from biomass gasification is environmental friendly

  2. Computational simulation of the biomass gasification process in a fluidized bed reactor

    International Nuclear Information System (INIS)

    Rojas Mazaira, Leorlen Y.; Gamez Rodriguez, Abel; Andrade Gregori, Maria Dolores; Armas Cardona, Raul

    2009-01-01

    In an agro-industrial country as Cuba many residues of cultivation like the rice and the cane of sugar take place, besides the forest residues in wooded extensions. Is an interesting application for all this biomass, the gasification technology, by its high efficiency and its positive environmental impact. The computer simulation appears like a useful tool in the researches of parameters of operation of a gas- emitting, because it reduces the number of experiments to realise and the cost of the researches. In the work the importance of the application of the computer simulation is emphasized to anticipate the hydrodynamic behavior of fluidized bed and of the process of combustion of the biomass for different residues and different conditions of operation. A model using CFD for the simulation of the process of combustion in a gas- emitting of biomass sets out of fluidized bed, the hydrodynamic parameters of the multiphasic flow from the elaboration of a computer simulator that allows to form and to vary the geometry of the reactor, as well as the influence of the variation of magnitudes are characterized such as: speed, diameter of the sand and equivalent reason. Experimental results in cylindrical channels appear, to complete the study of the computer simulation realised in 2D. (author)

  3. Biomass and fossil fuel conversion by pressurised fluidised bed gasification using hot gas ceramic filters as gas cleaning

    International Nuclear Information System (INIS)

    Jong, Wiebren de; Uenal, Oemer; Andries, Jans; Hein, K.R.G.; Spliethoff, Hartmut

    2003-01-01

    Gasification of biomass and fossil fuels, hot gas cleanup using a ceramic filter and combustion of LCV product gas in a combustor were performed using a 1.5 MWth test rig (pressurised bubbling fluidised bed gasifier) at Delft University and a 10-50 kWth system at Stuttgart University (DWSA) in the framework of experimental research on efficient, environmentally acceptable large-scale power generators based on fluidised bed gasification. The influence of operating conditions (pressure, temperature, stoichiometric ratio) on gasification (gas composition, conversion grades) was studied. The gasifiers were operated in a pressure range of 0.15-0.7 MPa and maximum temperatures of ca. 900 deg. C. The Delft gasifier has a 2 m high bed zone (diameter: 0.4 m) followed by a freeboard approximately 4 m high (diameter: 0.5 m). The IVD gasifier has a diameter of 0.1 m and a reactor length of 4 m. Carbon conversions during wood, miscanthus and brown coal gasification experiments were well above 80%. Fuel-nitrogen conversion to ammonia was above ca. 50% and the highest values were observed for biomass. The results are in line with other investigations with biomass bottom feeding. Deviation occurs compared with top feeding. Measurements are compared with simulation results of a reaction-kinetics-based model, using ASPEN PLUS, related to emission of components like fuel-nitrogen-derived species. Data from literature regarding initial biomass flash pyrolysis in the gasification process are used in the gasifier model and will be compared with simulation results from the FG-DVC model. Measurements and model predictions were in reasonably good agreement with each other

  4. Semi-continuous feeding and gasification of alfalfa and wheat straw pellets in a lab-scale fluidized bed reactor

    International Nuclear Information System (INIS)

    Sarker, Shiplu; Arauzo, Jesús; Nielsen, Henrik Kofoed

    2015-01-01

    Highlights: • Alfalfa and wheat straw pellets were gasified in a lab-scale fluid-bed reactor. • ER varied between 0.20 and 0.35 at which several parameters investigated. • ER = 0.35 was found optimum for alfalfa at which process performance improved. • ER = 0.30 revealed optimum for wheat straw at which gasification was effective. - Abstract: Small scale air-blown fluidized bed gasification of alfalfa and wheat straw pellets were conducted for semi-continuous solid feeding and range of operating conditions varied due to the modifications in equivalence ratio (ER) (0.20–0.35) achieved both by varying solid and air input. Alfalfa pellets displayed an improvement in several gasification variables such as gas lower heating value (∼4.1 MJ/Nm 3 ), specific gas yield (1.66 Nm 3 /kg), cold gas efficiency (∼42%) and carbon conversion efficiency (∼72%) as ER maximized to 0.35 which was found optimum for this feedstock for the present course of experiments. Gasification parameters of wheat straw pellets on the other hand were characterized by a great degree of variation as the ER progressively increased. The optimum performance of this biomass was likely to achieve at ER = 0.30 when gas lower heating value and cold gas efficiency maximized to ∼4 MJ/Nm 3 and ∼37% respectively. Moreover, a substantial drop in tar yield (58.7 g/Nm 3 ) at this ER was also indicative to the optimal thermal conversion at this point of operation. Overall, both the feedstocks presented promising alternatives for utilization into the small-scale fluidized bed gasification which is increasingly emerging as a sustainable solution towards processing lignocellulosic biomass

  5. Porous filtering media comparison through wet and dry sampling of fixed bed gasification products

    Science.gov (United States)

    Allesina, G.; Pedrazzi, S.; Montermini, L.; Giorgini, L.; Bortolani, G.; Tartarini, P.

    2014-11-01

    The syngas produced by fixed bed gasifiers contains high quantities of particulate and tars. This issue, together with its high temperature, avoids its direct exploitation without a proper cleaning and cooling process. In fact, when the syngas produced by gasification is used in an Internal Combustion engine (IC), the higher the content of tars and particulate, the higher the risk to damage the engine is. If these compounds are not properly removed, the engine may fail to run. A way to avoid engine fails is to intensify the maintenance schedule, but these stops will reduce the system profitability. From a clean syngas does not only follow higher performance of the generator, but also less pollutants in the atmosphere. When is not possible to work on the gasification reactions, the filter plays the most important role in the engine safeguard process. This work is aimed at developing and comparing different porous filters for biomass gasifiers power plants. A drum filter was developed and tested filling it with different filtering media available on the market. As a starting point, the filter was implemented in a Power Pallet 10 kW gasifier produced by the California-based company "ALL Power Labs". The original filter was replaced with different porous biomasses, such as woodchips and corn cobs. Finally, a synthetic zeolites medium was tested and compared with the biological media previously used. The Tar Sampling Protocol (TSP) and a modified "dry" method using the Silica Gel material were applied to evaluate the tars, particulate and water amount in the syngas after the filtration process. Advantages and disadvantages of every filtering media chosen were reported and discussed.

  6. Liquid transportation fuels via large-scale fluidised-bed gasification of lignocellulosic biomass

    Energy Technology Data Exchange (ETDEWEB)

    Hannula, I.; Kurkela, E.

    2013-04-15

    With the objective of gaining a better understanding of the system design trade-offs and economics that pertain to biomass-to-liquids processes, 20 individual BTL plant designs were evaluated based on their technical and economic performance. The investigation was focused on gasification-based processes that enable the conversion of biomass to methanol, dimethyl ether, Fischer-Tropsch liquids or synthetic gasoline at a large (300 MWth of biomass) scale. The biomass conversion technology was based on pressurised steam/O2-blown fluidised-bed gasification, followed by hot-gas filtration and catalytic conversion of hydrocarbons and tars. This technology has seen extensive development and demonstration activities in Finland during the recent years and newly generated experimental data has also been used in our simulation models. Our study included conceptual design issues, process descriptions, mass and energy balances and production cost estimates. Several studies exist that discuss the overall efficiency and economics of biomass conversion to transportation liquids, but very few studies have presented a detailed comparison between various syntheses using consistent process designs and uniform cost database. In addition, no studies exist that examine and compare BTL plant designs using the same front-end configuration as described in this work. Our analysis shows that it is possible to produce sustainable low-carbon fuels from lignocellulosic biomass with first-law efficiency in the range of 49.6-66.7% depending on the end-product and process conditions. Production cost estimates were calculated assuming Nth plant economics and without public investment support, CO2 credits or tax assumptions. They are 58-65 euro/MWh for methanol, 58-66 euro/MWh for DME, 64-75 euro/MWh for Fischer-Tropsch liquids and 68-78 euro/MWh for synthetic gasoline. (orig.)

  7. CO-PRODUCTION OF HYDROGEN AND ELECTRICITY USING PRESSURIZED CIRCULATING FLUIDIZED BED GASIFICATION TECHNOLOGY

    Energy Technology Data Exchange (ETDEWEB)

    Zhen Fan

    2006-05-30

    Foster Wheeler has completed work under a U.S. Department of Energy cooperative agreement to develop a gasification equipment module that can serve as a building block for a variety of advanced, coal-fueled plants. When linked with other equipment blocks also under development, studies have shown that Foster Wheeler's gasification module can enable an electric generating plant to operate with an efficiency exceeding 60 percent (coal higher heating value basis) while producing near zero emissions of traditional stack gas pollutants. The heart of the equipment module is a pressurized circulating fluidized bed (PCFB) that is used to gasify the coal; it can operate with either air or oxygen and produces a coal-derived syngas without the formation of corrosive slag or sticky ash that can reduce plant availabilities. Rather than fuel a gas turbine for combined cycle power generation, the syngas can alternatively be processed to produce clean fuels and or chemicals. As a result, the study described herein was conducted to determine the performance and economics of using the syngas to produce hydrogen for sale to a nearby refinery in a hydrogen-electricity co-production plant setting. The plant is fueled with Pittsburgh No. 8 coal, produces 99.95 percent pure hydrogen at a rate of 260 tons per day and generates 255 MWe of power for sale. Based on an electricity sell price of $45/MWhr, the hydrogen has a 10-year levelized production cost of $6.75 per million Btu; this price is competitive with hydrogen produced by steam methane reforming at a natural gas price of $4/MMBtu. Hence, coal-fueled, PCFB gasifier-based plants appear to be a viable means for either high efficiency power generation or co-production of hydrogen and electricity. This report describes the PCFB gasifier-based plant, presents its performance and economics, and compares it to other coal-based and natural gas based hydrogen production technologies.

  8. Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

    Energy Technology Data Exchange (ETDEWEB)

    Scott Sinquefield; Xiaoyan Zeng, Alan Ball

    2010-03-02

    Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. “syngas”) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950°C), but was limited to pressures below

  9. Fluidized bed gasification of high tonnage sorghum, cotton gin trash and beef cattle manure: Evaluation of synthesis gas production

    International Nuclear Information System (INIS)

    Maglinao, Amado L.; Capareda, Sergio C.; Nam, Hyungseok

    2015-01-01

    Highlights: • High tonnage sorghum, cotton gin trash and beef cattle manure were characterized and gasified in a fluidized bed reactor. • Biomass gasification at 730 °C and ER = 0.35 produced synthesis gas with an average energy content of 4.19 MJ Nm −3 . • Synthesis gas heating value and yield were relatively constant at reaction temperatures from 730 °C to 800 °C. • Optimum hydrogen production on HTS gasification was achieved at 780 °C temperature and ER of 0.4. - Abstract: Fluidized bed gasification using high-tonnage sorghum, cotton gin trash and beef cattle manure was performed in a pilot scale bubbling fluidized bed reactor equipped with the necessary feedback control system. Characterization of biomass showed that the high-tonnage sorghum had the highest energy and carbon content of 19.58 MJ kg −1 and 42.29% wt , respectively among the three feed stocks. At 730 °C reaction temperature and equivalence ratio of 0.35, comparable yields of methane, nitrogen and carbon dioxide (within ± 1.4% vol ) were observed in all three feed stocks. The gasification system produced synthesis gas with an average heating value of 4.19 ± 0.09 MJ Nm −3 and an average yield of 1.98 ± 0.1 Nm 3 kg −1 of biomass. Carbon conversion and gasification efficiencies indicated that most of the carbon was converted to gaseous products (85% average ) while 48% average of the energy from the biomass was converted into combustible gas. The production of hydrogen was significantly affected by the biomass used during gasification. The synthesis gas heating value and yield were relatively constant at reaction temperatures from 730 °C to 800 °C. Utilizing high-tonnage sorghum, the optimum hydrogen production during gasification was achieved at a reaction temperature of 780 °C and an equivalence ratio of 0.40.

  10. Biomass gasification with air in fluidized bed: hot gas cleanup and upgrading with steam-reforming catalysts of big size

    Energy Technology Data Exchange (ETDEWEB)

    Corella, J.; Caballero, M.A. [University Complutense, Madrid (Spain); Aznar, M.P.; Gil, J. [University of Saragossa (Spain)

    1999-07-01

    Several commercial steam reforming (nickel-based) catalysts were tested for tar elimination and gas upgrading in biomass gasification with air in fluidized bed. The characteristic or novelty of this work is that the catalysts are not crushed or ground but are used in their commercial size and shape. Catalysts were tested at pilot scale in two fixed beds located in a slip flow downstream from the gasifier. The equivalence ratio used in the upstream gasifier and steam content in the flue gas have an important effect on the kinetics of the tar removal reaction. (author)

  11. Dairy Biomass-Wyoming Coal Blends Fixed Gasification Using Air-Steam for Partial Oxidation

    Directory of Open Access Journals (Sweden)

    Gerardo Gordillo

    2012-01-01

    Full Text Available Concentrated animal feeding operations such as dairies produce a large amount of manure, termed as dairy biomass (DB, which could serve as renewable feedstock for thermal gasification. DB is a low-quality fuel compared to fossil fuels, and hence the product gases have lower heat content; however, the quality of gases can be improved by blending with coals. This paper deals with air-steam fixed-bed counterflow gasification of dairy biomass-Wyoming coal blend (DBWC. The effects of equivalence ratio (1.6<Φ<6.4 and steam-to-fuel ratio (0.4

  12. Air gasification of rice husk in a dual distributor type fluidized bed gasifier

    Energy Technology Data Exchange (ETDEWEB)

    Mansaray, K.G.; Ghaly, A.E. [Dalhousie University, Halifax, Nova Scotia (Canada). Biological Engineering Dept.; Al-Taweel, A.M. [Dalhousie University, Halifax, Nova Scotia (Canada). Chemical Engineering Dept.; Hamdullahpur, F.; Ugursal, V.I. [Dalhousie University, Halifax, Nova Scotia (Canada). Mechanical Engineering Dept.

    1999-10-01

    In this study, a dual distributor type fluidized bed gasifier was used for the air gasification of rice husk in view of producing fuel gas. The effects of varying fluidization velocity (0.22, 0.28 and 0.33 m s{sup -1}) and equivalence ratio (0.25, 0.30 and 0.35) on the gasifier performance were discussed. The steady state temperature varied between 665 and 830 degrees C. The fluidization velocity of 0.22 m s{sup -1} and equivalence ratio of 0.25 appeared to be the optimum conditions with respect to the quality of gas. The mole fractions of the combustible components reached their maximum values at these conditions with a typical gas composition of 4% H{sub 2}, 5% hydrocarbons (CH{sub 4}, C{sub 2}H{sub 2}, C{sub 2}H{sub 4} and C{sub 2}H{sub 6}), 15% CO{sub 2}, 20% CO and 57% N{sub 2}. The higher heating value of the gas obtained at these fluidization velocity and equivalence ratio (3.09 - 5.03 MJ Nm{sup -3}) compared very well with published data from air-blown biomass gasifiers of similar scale of operation. The gas yield and carbon conversion were in the range of 1.30 to 1.98 Nm{sup 3} kg{sup -1} and 55.0 to 81.0%, respectively.

  13. The O₂-enriched air gasification of coal, plastics and wood in a fluidized bed reactor.

    Science.gov (United States)

    Mastellone, Maria Laura; Zaccariello, Lucio; Santoro, Donato; Arena, Umberto

    2012-04-01

    The effect of oxygen-enriched air during fluidized bed co-gasification of a mixture of coal, plastics and wood has been investigated. The main components of the obtained syngas were measured by means of on-line analyzers and a gas chromatograph while those of the condensate phase were off-line analysed by means of a gas chromatography-mass spectrometer (GC-MS). The characterization of condensate phase as well as that of the water used as scrubbing medium completed the performed diagnostics. The experimental results were further elaborated in order to provide material and substances flow analyses inside the plant boundaries. These analyses allowed to obtain the main substance distribution between solid, gaseous and condensate phases and to estimate the conversion efficiency of carbon and hydrogen but also to easily visualise the waste streams produced by the process. The process performance was then evaluated on the basis of parameters related to the conversion efficiency of fuels into valuable products (i.e. by considering tar and particulate as process losses) as well as those related to the energy recovery. Copyright © 2011 Elsevier Ltd. All rights reserved.

  14. Numerical Simulation of Fluidized Bed Gasifier for Integrated Gasification Combined Cycle

    Directory of Open Access Journals (Sweden)

    CHEN Ju-hui

    2017-06-01

    Full Text Available The overall thermal efficiency of the integrated gasification combined cycle ( IGCC has not been sufficiently improved. In order to achieve higher power generation efficiency,the advanced technology of IGCC has been developed which is on the basis of the concept of exergy recovery. IGCC systems and devices from the overall structure of opinion,this technology will generate electricity for the integration of advanced technology together,the current utilization of power generation technology and by endothermic reaction of steam in the gasifier,a gas turbine exhaust heat recovery or the solid oxide fuel cell. It is estimated that such the use of exergy recycling has the advantage of being easy to use,separating,collecting fixed CO2,making it very attractive,and can increase the overall efficiency by 10% or more. The characteristics of fluidized bed gasifier,one of the core equipment of the IGCC system,and its effect on the whole system were studied.

  15. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system: Topical report, Process analysis, FY 1983

    Energy Technology Data Exchange (ETDEWEB)

    None

    1987-07-31

    KRW Energy Systems, Inc., is engaged in the continuing development of a pressurized, fluidized-bed gasification process at its Waltz Mill Site in Madison, Pennsylvania. The overall objective of the program is to demonstrate the viability of the KRW process for the environmentally-acceptable production of low- and medium-Btu fuel gas from a variety of fossilized carbonaceous feedstocks and industrial fuels. This report presents process analysis of the 24 ton-per-day Process Development Unit (PDU) operations and is a continuation of the process analysis work performed in 1980 and 1981. Included is work performed on PDU process data; gasification; char-ash separation; ash agglomeration; fines carryover, recycle, and consumption; deposit formation; materials; and environmental, health, and safety issues. 63 figs., 43 tabs.

  16. Multi-gene genetic programming based predictive models for municipal solid waste gasification in a fluidized bed gasifier.

    Science.gov (United States)

    Pandey, Daya Shankar; Pan, Indranil; Das, Saptarshi; Leahy, James J; Kwapinski, Witold

    2015-03-01

    A multi-gene genetic programming technique is proposed as a new method to predict syngas yield production and the lower heating value for municipal solid waste gasification in a fluidized bed gasifier. The study shows that the predicted outputs of the municipal solid waste gasification process are in good agreement with the experimental dataset and also generalise well to validation (untrained) data. Published experimental datasets are used for model training and validation purposes. The results show the effectiveness of the genetic programming technique for solving complex nonlinear regression problems. The multi-gene genetic programming are also compared with a single-gene genetic programming model to show the relative merits and demerits of the technique. This study demonstrates that the genetic programming based data-driven modelling strategy can be a good candidate for developing models for other types of fuels as well. Copyright © 2014 Elsevier Ltd. All rights reserved.

  17. Steam gasification of lignocellulosic residues in a fluidized bed at a small pilot scale; Effect of the type of feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Herguido, J.; Corella, J.; Gonzalez-Saiz, J. (Chemical and Environmental Engineering Dept., Univ. of Zaragoza, 50009 Zaragoza (ES))

    1992-05-01

    This paper discusses different biomass materials such as pine sawdust, pine wood chips, cereal straw, and thistles (Cynara cardunculus) from energetic crops gasified with steam in a 15-cm-i.d. fluidized bed reactor. The gas, tar, and char yields, the composition and heating value of the gas produced, and the conversion of carbon have been determined at temperatures between 650 and 780{degrees}C (923-1053 K) for each material. The product distribution varies with the biomass used and the gasification temperature. The differences are very marked for the H{sub 2}, CO, and CO{sub 2} contents in the gas product at low gasification temperatures. These differences decrease when the temperature increases to 780{degrees}C at which point a gas composition similar for all types of biomass tested is obtained by the achievement of equilibrium in the water-gas shift reaction.

  18. Soil application of ash produced by low-temperature fluidized bed gasification: effects on soil nutrient dynamics and crop response

    DEFF Research Database (Denmark)

    Müller-Stöver, Dorette Sophie; Ahrenfeldt, Jesper; Holm, Jens Kai

    2012-01-01

    on soil nutrient levels or on crop biomass. We conclude from the results of this study, that—depending on the feedstock used—ashes from LT-CFB gasification of plant biomass can be used to replace mineral fertilizers if they are applied according to their nutrient content, the crop demand, and soil......Recycling of residual products of bioenergy conversion processes is important for adding value to the technologies and as a potential beneficial soil fertility amendment. In this study, two different ash materials originating from low temperature circulating fluidized bed (LT-CFB) gasification...... of either wheat straw (SA) or residue fibers mainly from citrus peels (CP) were tested regarding their potential to be used as fertilizer on agricultural soils. A soil incubation study, a greenhouse experiment with barley and faba bean, and an accompanying outdoor experiment with maize were carried out...

  19. The effect of CO{sub 2} partial pressure on coal char gasification rates at high temperature and pressure

    Energy Technology Data Exchange (ETDEWEB)

    Elizabeth Hodge; Daniel Roberts; David Harris; John Stubington [CRC for Coal in Sustainable Development, Kenmore, Qld. (Australia)

    2007-07-01

    Deployment and optimisation of gasification-based technologies on a wider scale requires an improved understanding of the gasification process at high temperatures and pressures. The reactions of coal char with steam and CO{sub 2} (the gasification reactions) are the slowest steps in the gasification process; these reactions therefore limit the rate of coal conversion in the gasifier, making them key design and operating parameters for gasifier systems. As part of a wider study, this work investigates the char-CO{sub 2} reaction at high temperatures and pressures. New data are presented for reaction rates at temperatures of 1273-1673 K, pressures of 10-20 bar and CO{sub 2} partial pressures of 2.5-7.5 bar for a coal char in a pressurised entrained flow reactor. The data are used to investigate the effects of total pressure and CO{sub 2} partial pressure on the char-CO{sub 2} reaction rate at high temperature. The apparent reaction order was found to be 0.2-0.4, consistent with reaction in Regime 2 conditions. The effect of total pressure was found to be negligible, due to the dominance of Knudson diffusion in particles with small pore sizes. Ongoing work in this area is investigating further the links between char structure, intrinsic reactivity, and gasification rates at high temperatures. 20 refs., 4 figs., 1 tab.

  20. Simulation of Steam Gasification in a Fluidized Bed Reactor with Energy Self-Sufficient Condition

    Directory of Open Access Journals (Sweden)

    Ajaree Suwatthikul

    2017-03-01

    Full Text Available The biomass gasification process is widely accepted as a popular technology to produce fuel for the application in gas turbines and Organic Rankine Cycle (ORC. Chemical reactions of this process can be separated into three reaction zones: pyrolysis, combustion, and reduction. In this study, sensitivity analysis with respect to three input parameters (gasification temperature, equivalence ratio, and steam-to-biomass ratio has been carried out to achieve energy self-sufficient conditions in a steam gasification process under the criteria that the carbon conversion efficiency must be more than 70%, and carbon dioxide gas is lower than 20%. Simulation models of the steam gasification process have been carried out by ASPEN Plus and validated with both experimental data and simulation results from Nikoo & Mahinpey (2008. Gasification temperature of 911 °C, equivalence ratio of 0.18, and a steam-to-biomass ratio of 1.78, are considered as an optimal operation point to achieve energy self-sufficient condition. This operating point gives the maximum of carbon conversion efficiency at 91.03%, and carbon dioxide gas at 15.18 volumetric percentages. In this study, life cycle assessment (LCA is included to compare the environmental performance of conventional and energy self-sufficient gasification for steam biomass gasification.

  1. Thermodynamic analysis of a coal-based polygeneration system with partial gasification

    International Nuclear Information System (INIS)

    Li, Yuanyuan; Zhang, Guoqiang; Yang, Yongping; Zhai, Dailong; Zhang, Kai; Xu, Gang

    2014-01-01

    This study proposed a polygeneration system based on coal partial gasification, in which methanol and power were generated. This proposed system, comprising chemical and power islands, was designed and its characteristics are analyzed. The commercial software Aspen Plus was used to perform the system analysis. In the case study, the energy and exergy efficiency values of the proposed polygeneration system were 51.16% and 50.58%, which are 2.34% and 2.10%, respectively, higher than that of the reference system. Energy-Utilization Diagram analysis showed that removing composition adjustment and recycling 72.7% of the unreacted gas could reduce the exergy destruction during methanol synthesis by 46.85% and that the char utilized to preheat the compressed air could reduce the exergy destruction during combustion by 10.28%. Sensitivity analysis was also performed. At the same capacity ratio, the energy and exergy efficiency values of the proposed system were 1.30%–2.48% and 1.21%–2.30% higher than that of the reference system, respectively. The range of chemical-to-power capacity ratio in the proposed system was 0.41–1.40, which was narrower than that in the reference system. But the range of 1.04–1.4 was not recommended for the disappearance of energy saving potential in methanol synthesis. - Highlights: • A novel polygeneration system based on coal partial gasification is proposed. • The efficient conversion method for methanol and power is explored. • The exergy destruction in chemical energy conversion processes is decreased. • Thermodynamic performance and system characteristics are analyzed

  2. Partial oxidation of sewage sludge briquettes in a updraft fixed bed.

    Science.gov (United States)

    Kim, Minsu; Lee, Yongwoon; Park, Jinje; Ryu, Chankook; Ohm, Tae-In

    2016-03-01

    The fixed bed reaction of sewage sludge briquettes was investigated to evaluate the potential applications to gasification, combustion, or production of biochar as soil ameliorator. The reaction had two distinctive stages: ignition propagation and char oxidation. The ignition front of the sludge briquettes propagated at a lower speed, which significantly increased the stoichiometric ratio of overall combustion reaction and peak temperatures. The ignition front also had irregular shapes due to the channeling effects. During the char oxidation stage, the sludge ash agglomerated because of the slow reaction rate and increased CO2 formation. Because of low energy content in the product gas, the large briquettes were not favorable for syngas production. In addition, the low burning rates and ash agglomeration could cause problems in the operation of a grate-type furnace for combustion. However, the char accumulated above the ignition front had similar properties with that from pyrolysis under inert atmosphere. Therefore, the fixed bed reaction under partial oxidation conditions can be applied to produce biochar as soil ameliorator from the sludge briquettes without external heat supply. Copyright © 2016 Elsevier Ltd. All rights reserved.

  3. Biomass gasification: The understanding of sulfur, tar, and char reaction in fluidized bed gasifiers

    OpenAIRE

    Meng, X.

    2012-01-01

    As one of the currently available thermo-chemical conversion technologies, biomass gasification has received considerable interest since it increases options for combining with various power generation systems. The product gas or syngas produced from biomass gasification is environmental friendly alternatives to conventional petrochemical fuels for the production of electricity, hydrogen, synthetic transportation biofuels and other chemicals. The product gas normally contains the major compon...

  4. Biomass gasification with air in fluidized bed: Reforming of the gas composition with commercial steam reforming catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Corella, J.; Orio, A.; Aznar, P. [Univ. Complutense of Madrid (Spain). Dept. of Chemical Engineering

    1998-12-01

    Four commercial catalysts for steam reforming of higher hydrocarbons (naphthas) and three for steam reforming of light hydrocarbons are tested for hot gas clean up and upgrading in biomass gasification with air in fluidized bed. The catalysts used originate from four manufacturers: BASF, AG, ICI-Katalco, Haldor Topsoe a/s, and United Catalysts Inc. The work is performed in a small pilot plant (1--2 kg of biomass fed/h) with three reactors in series: gasifier, guard bed of dolomite, and full flow catalytic bed. Samples of gas are taken before and after the catalytic bed at different times-on-stream. It is shown how the H{sub 2}, CO, CO{sub 2}, CH{sub 4} and steam contents in the flue gas change because of the catalytic bed approaching contents near to the ones corresponding to the equilibrium state. Variations in the heating value of the gas and gas yield as a result of the catalytic bed are also reported.

  5. Biomass gasification in atmospheric and bubbling fluidized bed: effect of the type of gasifying agent on the product distribution

    Energy Technology Data Exchange (ETDEWEB)

    Gil, J.; Aznar, M.P.; Caballero, M.A. [University of Saragossa (Spain). Chemical and Environmental Engineering Dept.; Corella, J. [University ' ' Complutense' ' of Madrid (Spain). Chemical Engineering Dept.

    1999-07-01

    The effect of the type of gasifying agent used in biomass gasification on product distribution (gas, char and tar yields) and gas quality (Contents in H{sub 2}, CO, CO{sub 2}, CH{sub 4},..., tars) is analyzed. Gasifying agents taken into account are: air, pure steam, and steam-O{sub 2} mixtures. Process considered is biomass gasification in atmospheric and bubbling fluidized bed. Previous results by Herguido et al. (Ind. Eng. Chem. Res. 1992; 31(2): 1274-82), Gil et al. (Energy and Fuels 1997; 11(6): 1109-18) and Narvaez et al. (Ind. Eng. Chem. Res. 1996; 35(7): 2110-20) are compared. Such authors carried their research on biomass gasification under similar conditions but varying the gasifying agent. Three different gasifying agent-to-biomass ratios are needed and used to compare results. The relationships between the H{sub 2}, CO,..., tar contents in the flue gas and the type and amount of gasifying agent used are shown after a careful analysis. (author)

  6. Environmental assessment of the atlas bio-energy waste wood fluidized bed gasification power plant. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Holzman, M.I.

    1995-08-01

    The Atlas Bio-Energy Corporation is proposing to develop and operate a 3 MW power plant in Brooklyn, New York that will produce electricity by gasification of waste wood and combustion of the produced low-Btu gas in a conventional package steam boiler coupled to a steam-electric generator. The objectives of this project were to assist Atlas in addressing the environmental permit requirements for the proposed power plant and to evaluate the environmental and economic impacts of the project compared to more conventional small power plants. The project`s goal was to help promote the commercialization of biomass gasification as an environmentally acceptable and economically attractive alternative to conventional wood combustion. The specific components of this research included: (1) Development of a permitting strategy plan; (2) Characterization of New York City waste wood; (3) Characterization of fluidized bed gasifier/boiler emissions; (4) Performance of an environmental impact analysis; (5) Preparation of an economic evaluation; and (6) Discussion of operational and maintenance concerns. The project is being performed in two phases. Phase I, which is the subject of this report, involves the environmental permitting and environmental/economic assessment of the project. Pending NYSERDA participation, Phase II will include development and implementation of a demonstration program to evaluate the environmental and economic impacts of the full-scale gasification project.

  7. Biomass gasification and in-bed contaminants removal: performance of iron enriched olivine and bauxite in a process of steam/O2 gasification.

    Science.gov (United States)

    Barisano, D; Freda, C; Nanna, F; Fanelli, E; Villone, A

    2012-08-01

    A modified Olivine, enriched in iron content (10% Fe/Olivine), and a natural bauxite, were tested in the in-bed reduction of tar and alkali halides (NaCl and KCl) released in a process of biomass steam/O(2) gasification. The tests were carried out at an ICBFB bench scale reactor under the operating conditions of: 855-890 °C, atmospheric pressure, 0.5 steam/biomass and 0.33 ER ratios. From the use of the two materials, a reduction in the contaminant contents of the fuel gas produced was found. For the alkali halides, a decrease up to 70%(wt) was observed for the potassium concentration, while for sodium, the reduction was found to be quite poor. For the organic content, compared to unmodified Olivine, the chromatographically determined total tar quantity showed a removal efficiency of 38%(wt). Moreover, regarding the particulate content a rough doubling in the fuel gas revealed a certain brittleness of the new bed material. Copyright © 2012 Elsevier Ltd. All rights reserved.

  8. Storage capacity assessment of liquid fuels production by solar gasification in a packed bed reactor using a dynamic process model

    International Nuclear Information System (INIS)

    Kaniyal, Ashok A.; Eyk, Philip J. van; Nathan, Graham J.

    2016-01-01

    Highlights: • First analysis to assess storage requirements of a stand-alone packed bed, batch process solar gasifier. • 35 days of storage required for stand-alone solar system, whereas 8 h of storage required for hybrid system. • Sensitivity of storage requirement to reactor operation, solar region and solar multiple evaluated. - Abstract: The first multi-day performance analysis of the feasibility of integrating a packed bed, indirectly irradiated solar gasification reactor with a downstream FT liquids production facility is reported. Two fuel-loading scenarios were assessed. In one, the residual unconverted fuel at the end of a day is reused, while in the second, the residual fuel is discarded. To estimate a full year time-series of operation, a simplified statistical model was developed from short-period simulations of the 1-D heat transfer, devolatilisation and gasification chemistry model of a 150 kW th packed bed reactor (based on the authors’ earlier work). The short time-series cover a variety of solar conditions to represent seasonal, diurnal and cloud-induced solar transience. Also assessed was the influence of increasing the solar flux incident at the emitter plate of the packed bed reactor on syngas production. The combination of the annual time-series and daily model of syngas production was found to represent reasonably the seasonal transience in syngas production. It was then used to estimate the minimum syngas storage volume required to maintain a stable flow-rate and composition of syngas to a FT reactor over a full year of operation. This found that, for an assumed heliostat field collection area of 1000 m 2 , at least 64 days of storage is required, under both the Residual Fuel Re-Use and Discard scenarios. This figure was not sensitive to the two solar sites assessed, Farmington, New Mexico or Tonopah Airport, Nevada. Increasing the heliostat field collection area from 1000 to 1500 m 2 , led to an increase in the calculated daily rate

  9. Numerical simulations and correlations on the coal -conveying gas flow in pipe for fluidized -bed coal gasification facility

    International Nuclear Information System (INIS)

    Lee, Chan; Lee, Jin Wook; Kwon, Tae Wan; Kim, Gyoo Tae

    2014-01-01

    CFD modeling and simulation are made on the key flow elements, vertical, horizontal pipes and elbow pipes , used in the pneumatic coal -transport system of fluidized -bed gasification test facility. The coal- gas flow inside the flow elements are modeled by combining Reynolds -stress Averaged Navier- Stokes equations Solver (RANS), k- ε turbulence model and Discrete Phase Model (DPM) in the ANSYS Fluent code. Using the developed coal -gas flow analysis model, computations are carried out to investigate the gas flow path, the coal particle behavior and the pressure loss characteristics in flow element at various coal/ gas loading ratio and coal mass flux. The present prediction results show the coal -gas flow behavior of each flow element is changed from dilute -flow to dense -flow pattern at a specific coal/gas loading ratio where pressure loss is abruptly increased. From the numerical results, the present study also provides the limiting coal/gas loading conditions to secure stable coal feeding and the correlations for pressure losses in horizontal, vertical and elbow pipes, which can be suitable for the design guidelines of actual fluidized -bed coal gasification. Key words : Pneumatic Coal -Transport; Coal -Gas Flow, Dense Phase Flow; Dilute Phase Flow; Pressure Loss; Coal/Gas Loading Ratio; Correlation

  10. Fluidized bed gasification of the fuel fraction of municipal solid wastes; Gasificacion en lecho fluidizado de la fraccion combustible de los residuos solidos urbanos

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, J.; Baldasano, J. M.; Gasso, S. [Universidad Politecnica de Cataluna. Barcelona (Spain)

    1998-12-31

    In this paper, the results obtained in the application of the fluidized-bed gasification to the treatment of solid waste with high heating value. These wastes could be valuable materials in thermo conversion processes such as gasification. The combustible fraction of municipal solid waste (MSW) composed of paper, cardboard, plastics (PET,PVC), referred as refuse derived fuel (RDF), has been considered in this work. The experimental facility consists of an air-blown gasifier operating at atmospheric pressure with a capacity of 50 kg/h. The results obtained show that the gasification of RDF allows to produce a gas with a high heating value (HHV) of 7.8 Mj/Mn3 and recovering more than 80% of the initial HHV of the waste in the cold gas. Solid residue produced in the gasification process is lower than 10% of the initial waste. (Author)

  11. Biomass gasification in fixed bed type down draft: theoretical and experimental aspects; Gasificacao de biomassa em leito fixo tipo concorrente: aspectos teoricos e experimentais

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, Juan Daniel; Andrade, Rubenildo Vieira; Lora, Electo Eduardo Silva [Universidade Federal de Itajuba (UNIFEI), MG (Brazil). Inst. de Engenharia Mecanica. Nucleo de Excelencia em Geracao Termeletrica e Distribuida

    2008-07-01

    Actually are recognizing the advantages of biomass in reducing dependence on fossil fuels and significant reduction in emissions of greenhouse effect gases such as Co2. Also are known the different conversion of biomass routes for their use or exploitation, such as thermochemical process (gasification, pyrolysis and combustion), the biological process (fermentation and transesterification) and the physical process (densification, reducing grain and mechanical pressing). In this sense, the gasification is regarded as the most promising mechanism to obtain a homogeneous gaseous fuel with sufficient quality in the small scale distributed generation. This work presents some aspects of biomass gasification in fixed bed, as well as some preliminary results in the evaluation and operation of fixed bed down draft gasifier with double stage air supply of the NEST, identifying the adequate air supply quantity (equivalence ratio in the range of 0,35 to 0,45) for obtaining a fuel gas with lower heating value around 4 MJ/N m3. (author)

  12. Fixed-bed gasification for industrial appliances; Gaseificacao em leito fixo para aplicacoes industriais

    Energy Technology Data Exchange (ETDEWEB)

    Makray, Zsolt [Termoquip Energia Alternativa, Campinas, SP (Brazil)

    1988-12-31

    Wood gasification for industrial thermal processes as an alternative to fuel oil has economic, strategic and air pollution advantages. Since 1981, a Brazilian industry developed a line of down-draft gasifiers for industrial heating in the capacity of 0,3 to 3,0 MW thermal. (author) 3 figs.

  13. Coal gasification by indirect heating in a single moving bed reactor: Process development & simulation

    Directory of Open Access Journals (Sweden)

    Junaid Akhlas

    2015-10-01

    Full Text Available In this work, the development and simulation of a new coal gasification process with indirect heat supply is performed. In this way, the need of pure oxygen production as in a conventional gasification process is avoided. The feasibility and energetic self-sufficiency of the proposed processes are addressed. To avoid the need of Air Separation Unit, the heat required by gasification reactions is supplied by the combustion flue gases, and transferred to the reacting mixture through a bayonet heat exchanger installed inside the gasifier. Two alternatives for the flue gas generation have been investigated and compared. The proposed processes are modeled using chemical kinetics validated on experimental gasification data by means of a standard process simulator (Aspen PlusTM, integrated with a spreadsheet for the modeling of a special type of heat exchanger. Simulation results are presented and discussed for proposed integrated process schemes. It is shown that they do not need external energy supply and ensure overall efficiencies comparable to conventional processes while producing syngas with lower content of carbon dioxide.

  14. Method and system for controlling a gasification or partial oxidation process

    Science.gov (United States)

    Rozelle, Peter L; Der, Victor K

    2015-02-10

    A method and system for controlling a fuel gasification system includes optimizing a conversion of solid components in the fuel to gaseous fuel components, controlling the flux of solids entrained in the product gas through equipment downstream of the gasifier, and maximizing the overall efficiencies of processes utilizing gasification. A combination of models, when utilized together, can be integrated with existing plant control systems and operating procedures and employed to develop new control systems and operating procedures. Such an approach is further applicable to gasification systems that utilize both dry feed and slurry feed.

  15. Principles of a novel multistage circulating fluidized bed reactor for biomass gasification

    NARCIS (Netherlands)

    Kersten, Sascha R.A.; Prins, W.; van der Drift, Bram; van Swaaij, Willibrordus Petrus Maria

    2003-01-01

    In this paper a novel multistage circulating fluidized bed reactor has been introduced. The riser of this multistage circulating fluidized bed consists of several segments (seven in the base-case design) in series each built-up out of two opposite cones. Due to the specific shape, a fluidized bed

  16. Behavior of Heavy Metals in Steam Fluidized Bed Gasification of Contaminated Biomass

    Czech Academy of Sciences Publication Activity Database

    Šyc, Michal; Pohořelý, Michael; Jeremiáš, Michal; Vosecký, Martin; Kameníková, Petra; Skoblia, Sergej; Svoboda, Karel; Punčochář, Miroslav

    2011-01-01

    Roč. 25, č. 5 (2011), s. 2284-2291 ISSN 0887-0624 R&D Projects: GA ČR(CZ) GA104/07/0977; GA MŠk 2B08048 Institutional research plan: CEZ:AV0Z40720504 Keywords : gasification * heavy metals * contaminated biomass Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 2.721, year: 2011

  17. Dual catalyst bed concept for catalytic partial oxidation of methane to synthesis gas

    NARCIS (Netherlands)

    Zhu, J.J.; Mujeebur Rahuman, M.S.M.; van Ommen, J.G.; Lefferts, Leonardus

    2004-01-01

    A system with two catalyst beds instead of one single metal catalyst bed is proposed for catalytic partial oxidation of methane (CPOM) to synthesis gas. In this dual catalyst bed system, an irreducible stable oxide, such as yttrium-stabilized zirconia (YSZ), is used in the first catalyst bed to

  18. NH3 Abatement in Fluidized Bed Co-Gasification of RDF and Coal

    Science.gov (United States)

    Gulyurtlu, I.; Pinto, Filomena; Dias, Mário; Lopes, Helena; André, Rui Neto; Cabrita, I.

    Gasification of wastes may come out as an alternative technology to produce a gas with many potential applications, from direct burning in a boiler or motor to the production of synthetic chemicals and hydrogen. High tar production and high operational costs are preventing gasification wider dissemination. Besides these problems, the presence of NH3 in the syngas may have a negative impact as it can be converted into nitrogen oxides if the gas is further burnt. To reduce NH3 formation it is required a full understanding of how operational parameters contribute to the formation/reduction of this pollutant. A full studyon the effect of fuel composition, temperature and equivalence ratio on the formation of NH3 is given. Experimental results are compared to theoretical ones obtained with FactSage software. It is also analyzed the effect of feedstock mineral matterin NH3 release during gasification. Toaccomplish a significant decrease in the release of NH3, different catalysts and sorbents were tested with the aim of achieving high energy conversions and low environmental impact.

  19. Advanced and clean gasification of solid wastes by downstream hot flue gas cleaning with high temperature filters and catalytic beds

    Energy Technology Data Exchange (ETDEWEB)

    Corella, J.; Narvaez, I.; Orio, A. [Univ. Complutense of Madrid (Spain)

    1996-12-31

    Thermochemical gasification of solid wastes has two main advantages over their incineration: a lesser flow rate of exit /stack gas is produced, smaller gas cleaning devices are thus required, and no formation of dioxins/furans, because of the reducing gas atmosphere. Nevertheless, at least two other problems remain to be solved: the destruction or elimination of the halogenated tars produced, and the removal of the heavy metals from the flue gas. Two small pilot plants are being used at University of Madrid to study and solve these problems. They are based on a bubbling fluidized bed gasifier and on a riser type gasifier. They have a continuous feeding of waste (1-4 kg/h) and downstream vessels for high temperature gas cleaning with filters and catalysts. 2 refs., 2 figs.

  20. Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    Science.gov (United States)

    Grindley, Thomas

    1989-01-01

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

  1. Development of a bi-equilibrium model for biomass gasification in a downdraft bed reactor.

    Science.gov (United States)

    Biagini, Enrico; Barontini, Federica; Tognotti, Leonardo

    2016-02-01

    This work proposes a simple and accurate tool for predicting the main parameters of biomass gasification (syngas composition, heating value, flow rate), suitable for process study and system analysis. A multizonal model based on non-stoichiometric equilibrium models and a repartition factor, simulating the bypass of pyrolysis products through the oxidant zone, was developed. The results of tests with different feedstocks (corn cobs, wood pellets, rice husks and vine pruning) in a demonstrative downdraft gasifier (350kW) were used for validation. The average discrepancy between model and experimental results was up to 8 times less than the one with the simple equilibrium model. The repartition factor was successfully related to the operating conditions and characteristics of the biomass to simulate different conditions of the gasifier (variation in potentiality, densification and mixing of feedstock) and analyze the model sensitivity. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. Biomass gasification using nickel loaded brown coal char in fluidized bed gasifier at relatively low temperature

    Energy Technology Data Exchange (ETDEWEB)

    Le, D.D.; Xiao, X.B.; Morishita, K.; Takarada, T. [Gunma University, Gumma (Japan)

    2009-07-01

    Our work focuses on developing nickel loaded brown coal char as a new catalyst to decompose tar and to enhance quality of product gas delivered from woody biomass pyrolysis at relatively low temperatures of 823 K and 923 K. It is carried out in two-stage fixed-bed reactor and a lab scale fluidized bed gasifier (FBG) under various conditions. Inside of gasifier is constructed by two beds, the primary one is a fluidized bed with sand. and the second one is a catalyst bed. The catalyst bed is used to evaluate and to compare catalytic activity between the new catalyst and a conventional Ni/Al{sub 2}O{sub 3} catalyst. The new catalyst is prepared by ion exchange method, dried at 380 K in nitrogen for 24 h, and is then calcined at 923 K in nitrogen for 90 min. The temperature as a function of gas yield and the effect of catalysts on gas yield in presence and absence of steam are investigated in this study. The new catalyst has shown high catalytic activity and stable activity and given the high quality of product gas in presence of steam.

  3. Biomass gasification: Produced gas upgrading by in-bed use of dolomite

    Energy Technology Data Exchange (ETDEWEB)

    Olivares, A.; Aznar, M.P.; Caballero, M.A.; Gil, J.; Frances, E. [Univ. of Saragossa (Spain). Chemical and Environmental Engineering Dept.; Corella, J. [Univ. Complutense of Madrid (Spain). Chemical Engineering Dept.

    1997-12-01

    When some calcined dolomite (OCa{center_dot}OMg) is used in the bed of a biomass gasifier of fluidized bed type the raw gas produced is cleaner than when only silica sand is used in it as fluidizing medium. In-bed dolomite changes the product distribution at the gasifier exit because of in-situ catalytic reactions promoted by the calcined dolomite. Gasifying with steam-O{sub 2} mixtures causes the tar content in the exit gas to decrease from 12 to 2--3 g tar/m{sup 3}{sub n}, the H{sub 2} content to increase from 25--28 to 43 vol%, and the CO content to decrease from 45 to 27 vol% when the gas and char yields, heating value of the gas, and other main variables also undergo important changes because of the in-bed dolomite. The experimental work here reported is carried out at small pilot plant scale in a 15 cm i.d. atmospheric and bubbling fluidized bed gasifier fed by 10 kg biomass/h. Dolomite is continuously fed to the gasifier, mixed with the biomass in percentages of 2--3 wt% of the total mass flow fed. A 10 wt% of calcined dolomite in the gasifier bed is enough to significantly improve the product distribution and gas quality.

  4. Biomass gasification with air in an atmospheric bubbling fluidized bed. Effect of six operational variables on the quality of the produced raw gas

    Energy Technology Data Exchange (ETDEWEB)

    Narvaez, I.; Orio, A.; Corella, J. [Univ. Complutense of Madrid (Spain). Dept. of Chemical Engineering; Aznar, M.P. [Univ. of Saragossa (Spain). Dept. of Chemical Engineering

    1996-07-01

    Biomass gasification with air in a bubbling fluidized bed is studied in a small pilot plant. Variables analyzed are equivalence ratio (from 0.20 to 0.45), temperatures of the gasifier bed (750--850 C) and of its freeboard (500--600 C), H/C ratio in the feed, use of secondary air (10% of the overall) in the freeboard, and addition (2--5 wt %) of a calcined dolomite mixed with the biomass used as the feedstock. Using advanced tar and gas sampling and analysis methods, the gas composition and tar content in the gas are determined and their variation with the operation parameters is given. A statistical analysis of the effects of the gasification variables is also here presented.

  5. Biomass oxygen/steam gasification in a pressurized bubbling fluidized bed: Agglomeration behavior

    International Nuclear Information System (INIS)

    Zhou, Chunguang; Rosén, Christer; Engvall, Klas

    2016-01-01

    Highlights: • Dolomite is a superior material in preventing bed agglomeration. • Small molten ash particles deposited on magnesite at bed temperatures above 1000 °C. • The performance, when using magnesite, is sensitive to temperature disturbances. • The anti-agglomeration mechanisms of Ca- and Mg-bearing materials were discussed. - Abstract: In this study, the anti-agglomeration abilities of Ca- and Mg-containing bed materials, including dolomite and magnesite, in a pressurized bubbling fluidized bed gasifier using pine pellets and birch chips as feedstock, is investigated. The most typical bed material—silica sand—was also included as a reference for comparison. The sustainability of the operation was evaluated via analyzing the temperatures at different levels along the bed height. During the performances, the aim was to keep the temperature at the bottom zone of the reactor at around 870 °C. However, the success highly depends on the bed materials used in the bed and the temperature can vary significantly in case of agglomeration or bad mixing of bed materials and char particles. Both Glanshammar and Sala dolomites performed well with no observed agglomeration tendencies. In case of magnesite, the bed exhibited a high agglomeration tendency. Silica sand displayed the most severe agglomeration among all bed materials, even when birch chips with a low silica content was fed at a relatively low temperature. The solid samples of all the bed materials were inspected by light microscopy and Scanning Electron Microscopy (SEM). The Energy Dispersive Spectroscopy (EDS) detector was used to detect the elemental distribution in the surface. The crystal chemical structure was analyzed using X-ray Diffraction (XRD). Magnesite agglomerates glued together by big molten ash particles. There was no coating layer detected on magnesite particles at bed temperatures – below 870 °C. But when the temperature was above 1000 °C, a significant amount of small molten

  6. Potentials of Selected Malaysian Biomasses as Co-Gasification Fuels with Oil Palm Fronds in a Fixed-Bed Downdraft Gasifier

    Directory of Open Access Journals (Sweden)

    Moni Mohamad Nazmi Zaidi

    2014-07-01

    Full Text Available Oil palm frond (OPF has been successfully gasified to produce syngas and has since deemed as a potential source of biomass fuel in Malaysia. However, if OPF is to be utilized as a main fuel for industrial-scale firing/gasification plant, interruption in fuel supply may occur due to numerous reasons, for instance inefficient fuel processing and ineffective transportation. A secondary supporting solid fuel is therefore necessary as a partial component to the main fuel in such cases, where the secondary fuel is combusted with the main fuel to adhere to main fuel shortage. Gasification of two fuels together, known as co-gasification, is practiced worldwide, some in industrial scale. However, current practice utilizes biomass fuel as the secondary fuel to coal in co-gasification. This investigation explores into the feasibility of co-gasifying two biomass fuels together to produce syngas. OPF was chosen as the primary fuel and a selection of Malaysian biomasses were studied to discover their compatibility with OPF in co-gasification. Biomass selection was made using score-and-rank method and their selection criteria are concisely discussed.

  7. Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    Science.gov (United States)

    Grindley, T.

    1988-04-05

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

  8. Gasification of algal biomass (Cladophora glomerata L.) with CO2/H2O/O2in a circulating fluidized bed.

    Science.gov (United States)

    Ebadi, Abdol Ghaffar; Hisoriev, Hikmat

    2017-11-28

    Gasification is one of the most important thermochemical routes to produce both synthesis gas (syngas) and chars. The quality of produced syngas wieldy depends on the operating conditions (temperature, residence time, heating rate, and gasifying agent), hydrodynamic properties of gasifier (particle size, minimum fluidization velocity, and gasifier size), and type of feedstock (coal, biomass, oil, and municipal solid wastes). In the present study, simulation of syngas production via circulating fluidized bed (CFB) gasification of algal biomass (Cladophora glomerata L.) at different gasifying agents and particle sizes was carried out, using Aspen Plus simulator. The model which has been validated by using experimental data of the technical literature was used to evaluate the influence of operating conditions on gas composition and performance parameters. The results show that biomass gasification using pure oxygen as the gasification agent has great potential to improve the caloric value of produced gas and performance indicators. It was also found that the produced gas caloric value, syngas yield, and performance parameters (CCE and CGE) increase with reaction temperature but are inversely proportional to the biomass particle size.

  9. About the gasification of untreated scrap and waste wood in fluidized bed reactor for use in decentralized gas engine-cogeneration plants; Zur Vergasung von Rest- und Abfallholz in Wirbelschichtreaktoren fuer dezentrale Energieversorgungsanlagen

    Energy Technology Data Exchange (ETDEWEB)

    Tepper, H.

    2005-10-20

    This dissertation examines the thermochemical conversion (gasification) of untreated scrap and waste wood in combustible gases for use in decentralized gas engine-cogeneration plants of low output (1 to 10 MW fuel power). A general section goes into the basics of the energetic utilization of solid biomass, the subprocesses of thermochemical conversion being described in more detail. Special attention is given to the processes and state of the art of biomass gasification in decentralized plants. A theoretical section analyzes the gasification models for solid biomass presented in the literature. Based on this analysis, a simplified kinetic model is derived for the gasification of untreated scrap and waste wood with air in bubbling fluidized bed reactors. It includes a fluid mechanic analysis of the fluidized bed based on HILLIGARDT, an empirical pyrolysis model and a global kinetic approach to the main chemical reaction taken from the literature. An experimental section describes the tests of the gasification of forest scrap wood in a semi-industrial fluidized bed gasification test plant with 150 kW fuel power and presents the significant test results. The gasification model derived is applied to check the test plant's standard settings and compare them with measured values. Furthermore, the model is employed to explain basic reaction paths and zones and to perform concluding parameter simulations. (orig.)

  10. Gasification of Biomass with CO2 and H2O Mixtures in a Catalytic Fluidised Bed.

    Czech Academy of Sciences Publication Activity Database

    Jeremiáš, Michal; Pohořelý, Michael; Svoboda, Karel; Manovic, V.; Anthony, E.J.; Skoblia, S.; Beňo, Z.; Šyc, Michal

    2017-01-01

    Roč. 210, DEC 15 (2017), s. 605-610 ISSN 0016-2361 R&D Projects: GA ČR GC14-09692J Grant - others:NSC(TW) 103-2923-E-042A-001-MY3 Institutional support: RVO:67985858 Keywords : fluidised bed * gas ification * catalyst Subject RIV: JE - Non-nuclear Energetics, Energy Consumption ; Use OBOR OECD: Energy and fuels Impact factor: 4.601, year: 2016

  11. Gasification of rice straw in a fluidized-bed gasifier for syngas application in close-coupled boiler-gasifier systems.

    Science.gov (United States)

    Calvo, L F; Gil, M V; Otero, M; Morán, A; García, A I

    2012-04-01

    The feasibility and operation performance of the gasification of rice straw in an atmospheric fluidized-bed gasifier was studied. The gasification was carried out between 700 and 850 °C. The stoichiometric air-fuel ratio (A/F) for rice straw was 4.28 and air supplied was 7-25% of that necessary for stoichiometric combustion. Mass and power balances, tar concentration, produced gas composition, gas phase ammonia, chloride and potassium concentrations, agglomeration tendencies and gas efficiencies were assessed. Agglomeration was avoided by replacing the normal alumina-silicate bed by a mixture of alumina-silicate sand and MgO. It was shown that it is possible to produce high quality syngas from the gasification of rice straw. Under the experimental conditions used, the higher heating value (HHV) of the produced gas reached 5.1 MJ Nm(-3), the hot gas efficiency 61% and the cold gas efficiency 52%. The obtained results prove that rice straw may be used as fuel for close-coupled boiler-gasifier systems. Copyright © 2012 Elsevier Ltd. All rights reserved.

  12. Biomass gasification with air in fluidized bed. Hot gas cleanup with selected commercial and full-size nickel-based catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Caballero, M.A.; Corella, J.; Aznar, M.P.; Gil, J.

    2000-05-01

    Three selected commercial, full-size steam-reforming catalysts for naphthas, BASF G1-50, ICI 46-1, and Topsoee R-67, are tested at pilot-scale level for hot gas cleanup in biomass gasification in a fluidized bed. Gas composition and tar content in the flue gas are measured before and after the catalytic bed. Variations of the catalytic bed in H{sub 2}, CO, CO{sub 2}, CH{sub 4}, and H{sub 2}O contents are reported for different operating conditions. Tar conversions and an apparent first-order kinetics constant for the overall tar removal reaction are calculated. Tar contents at the exit of the catalytic reactor as low as 10 mg/m{sub n}{sup 3} are obtained in a test of 50 h-on-stream without noticeable catalyst deactivation. Important variations in tar conversion with space time in the catalytic bed, with H{sub 2}O/C* in the flue gas, and with the equivalence ratio in the upstream gasifier are observed. These results obtained at the pilot-scale level and with the use of full-sized commercial catalysts are an important forward step in demonstrating the technical feasibility of the overall biomass gasification process.

  13. Steam gasification of coal at low-medium (600-800{sup o}C) temperature with simultaneous CO{sub 2} capture in a bubbling fluidized bed at atmospheric pressure. 2. Results and recommendations for scaling up

    Energy Technology Data Exchange (ETDEWEB)

    Corella, J.; Toledo, J.M.; Molina, G. [Universidad Complutense de Madrid, Madrid (Spain). Dept. of Chemical Engineering

    2008-03-19

    A gasification gas with an H{sub 2} content as high as 80 vol %, dry basis has been obtained by gasification of coal with pure steam at 600-800{sup o}C. The gasifier used was an atmospheric and bubbling fluidized bed operating with CaO in the bed as the CO{sub 2} sorbent. The research was carried out at a small pilot plant scale with continuous feeding of coal and batch mode introduction of the CaO. The gas composition and gas quality (tar content) is given for the following variables of operation: (a) type of in-bed sorbent used, (b) the amount of CaO in the bed related to the amount of coal fed, (c) temperature in the gasifier bed, (d) weight hourly space velocity (h{sup -1}) of the coal in the gasifier, and (e) time(-on-stream). To capture CaO at atmospheric pressure, the gasification with in-bed CaO had to be carried out at low-medium (600-800{sup o}C) gasification temperatures. For this reason, the tar content in the gasification gas was high (up to 52 g/Nm{sup 3}), which lowered the value of the H{sub 2}-rich gasification raw gas. It is demonstrated that a gas rich in H{sub 2} (80 vol % H{sub 2}, dry basis), and with very low CO{sub 2} and tar contents, can be obtained only if the coal gasification, at atmospheric pressure and with pure steam, is carried out at (CaO/coal) ratios above 10-15.

  14. Sewage sludge gasification in fluidized bed: influence of temperature and the stoichiometric relation; Gasificacion de fangos de depuradora en lecho fluidizado: influencia de la temperatura y de la relacion estequiometrica

    Energy Technology Data Exchange (ETDEWEB)

    Manya, J.J.; Gonzalo, A.; Sanchez, J.L.; Arauzo, J. [Universidad de Zaragoza, Aragon (Spain). Inst. de Investigacion en Ingenieria. Grupo de Procesos Termoquimicos; Rocha, J.D. [Universidade Estadual de Campinas (UNICAMP), Campinas, SP (Brazil). Nucleo Interdisciplinar de Planejamento Energetico (NIPE); Mesa Perez, J.M. [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Fac. de Engenharia Agricola (FEAGRI)

    2004-07-01

    The gasification of a dry granular sewage sludge has been experimentally studied. The gasification was carried out in a bench scale BFB facility, operated at steady state. The attention was focused on the presence of tar in the produced gas which affect the process efficiency and give negative drawbacks in the utilization in motors. The influence of two operating variables (bed temperature and equivalence ratio) on the gasification performances has been explored. Results show that the composition of produced gas is quite dependent of the variables analyzed. However, the results of tar yield show an unexpected behaviour. (author)

  15. Hydrogen-rich gas production by steam gasification of char from biomass fast pyrolysis in a fixed-bed reactor: influence of temperature and steam on hydrogen yield and syngas composition.

    Science.gov (United States)

    Yan, Feng; Luo, Si-yi; Hu, Zhi-quan; Xiao, Bo; Cheng, Gong

    2010-07-01

    Steam gasification experiments of biomass char were carried out in a fixed-bed reactor. The experiments were completed at bed temperature of 600-850 degrees C, a steam flow rate of 0-0.357 g/min/g of biomass char, and a reaction time of 15min. The aim of this study is to determine the effects of bed temperature and steam flow rate on syngas yield and its compositions. The results showed that both high gasification temperature and introduction of proper steam led to higher yield of dry gas and higher carbon conversion efficiency. However, excessive steam reduced gas yield and carbon conversion efficiency. The maximum dry gas yield was obtained at the gasification temperature of 850 degrees C and steam flow rate of 0.165 g/min/g biomass char. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  16. The influence of bed roughness on partial alluviation in an experimental bedrock channel

    Science.gov (United States)

    Davis, J. R.; Sklar, L. S.; Demeter, G. I.; Johnson, J. P.; Whipple, K. X.

    2005-12-01

    The extent of alluvial cover on a bedrock channel bed strongly influences the efficiency of river incision, and can affect the quality of habitat for aquatic ecosystems. The extent of partial cover is commonly modeled as a simple function of sediment supply relative to the transport capacity of the stream, although other factors are likely to be important, particularly the roughness of the underlying bedrock surface. Here we report results of a set of laboratory experiments investigating the influence of bedrock channel bed topography on the dynamics of partial bed alluviation. The experiments were conducted in a tilting flume 8 m long and 0.3 m wide with an erodible bedrock bed made of a sand-cement mixture. The flume has a calibrated sediment feed and a double-basket sediment trap that provides a continuous record of sediment flux out of the downstream end. We used a uniform grain size of 5 mm, and varied the sediment supply rate from zero to that sufficient to create a fully alluviated bed. We created a variety of bedrock roughness conditions, from smooth, nearly planar surfaces to an egg-carton texture made with a plaster-coated foam mold. Intermediate roughness was achieved by chiseling into smooth beds and by allowing the bed topography to evolve by sustained bedload abrasion. We used a laser microtopography scanning device to make topographic maps of the bed surface, with a vertical resolution of 0.2 mm and a horizontal spacing of 5 mm. From these data we quantify bedrock bed roughness as the standard deviation of the distribution of bed elevations relative to a plane inclined at the mean bed slope. To guide our selection of bed roughness values we made topographic surveys of a number of bedrock channel beds, including partially alluviated channels where we dug trenches through alluvial deposits to expose the underlying bedrock surface. For each bed roughness condition we systematically varied the sediment supply rate and repeatedly mapped the extent of

  17. Conceptual design report -- Gasification Product Improvement Facility (GPIF)

    Energy Technology Data Exchange (ETDEWEB)

    Sadowski, R.S.; Skinner, W.H.; House, L.S.; Duck, R.R. [CRS Sirrine Engineers, Inc., Greenville, SC (United States); Lisauskas, R.A.; Dixit, V.J. [Riley Stoker Corp., Worcester, MA (United States); Morgan, M.E.; Johnson, S.A. [PSI Technology Co., Andover, MA (United States). PowerServe Div.; Boni, A.A. [PSI-Environmental Instruments Corp., Andover, MA (United States)

    1994-09-01

    The problems heretofore with coal gasification and IGCC concepts have been their high cost and historical poor performance of fixed-bed gasifiers, particularly on caking coals. The Gasification Product Improvement Facility (GPIF) project is being developed to solve these problems through the development of a novel coal gasification invention which incorporates pyrolysis (carbonization) with gasification (fixed-bed). It employs a pyrolyzer (carbonizer) to avoid sticky coal agglomeration caused in the conventional process of gradually heating coal through the 400 F to 900 F range. In so doing, the coal is rapidly heated sufficiently such that the coal tar exists in gaseous form rather than as a liquid. Gaseous tars are then thermally cracked prior to the completion of the gasification process. During the subsequent endothermic gasification reactions, volatilized alkali can become chemically bound to aluminosilicates in (or added to) the ash. To reduce NH{sub 3} and HCN from fuel born nitrogen, steam injection is minimized, and residual nitrogen compounds are partially chemically reduced in the cracking stage in the upper gasifier region. Assuming testing confirms successful deployment of all these integrated processes, future IGCC applications will be much simplified, require significantly less mechanical components, and will likely achieve the $1,000/kWe commercialized system cost goal of the GPIF project. This report describes the process and its operation, design of the plant and equipment, site requirements, and the cost and schedule. 23 refs., 45 figs., 23 tabs.

  18. Co-gasification of biosolids with biomass: Thermogravimetric analysis and pilot scale study in a bubbling fluidized bed reactor.

    Science.gov (United States)

    Yu, Ming Ming; Masnadi, Mohammad S; Grace, John R; Bi, Xiaotao T; Lim, C Jim; Li, Yonghua

    2015-01-01

    This work studied the feasibility of co-gasification of biosolids with biomass as a means of disposal with energy recovery. The kinetics study at 800°C showed that biomass, such as switchgrass, could catalyze the reactions because switchgrass ash contained a high proportion of potassium, an excellent catalyst for gasification. However, biosolids could also inhibit gasification due to interaction between biomass alkali/alkaline earth metals and biosolids clay minerals. In the pilot scale experiments, increasing the proportion of biosolids in the feedstock affected gasification performance negatively. Syngas yield and char conversion decreased from 1.38 to 0.47m(3)/kg and 82-36% respectively as the biosolids proportion in the fuel increased from 0% to 100%. Over the same range, the tar content increased from 10.3 to 200g/m(3), while the ammonia concentration increased from 1660 to 19,200ppmv. No more than 25% biosolids in the fuel feed is recommended to maintain a reasonable gasification. Copyright © 2014 Elsevier Ltd. All rights reserved.

  19. Cold test with a benchtop set-up for fluidized bed reactor using quartz sand to simulate gasification of coal cokes by concentrated solar radiation

    Science.gov (United States)

    Gokon, Nobuyuki; Tanabe, Tomoaki; Shimizu, Tadaaki; Kodama, Tatsuya

    2016-05-01

    The impacts of internal circulation of a mixture of coal-coke particles and quartz sand on the fluidization state in a fluidized bed reactor are investigated by a cold test with a benchtop set-up in order to design 10-30 kWth scale prototype windowed fluidized-bed reactor. Firstly, a basic relationship between pressure loss of inlet gas and gas velocity was experimentally examined using quartz sand with different particle sizes by a small-scale quartz tube with a distributor at ambient pressure and temperature. Based on the results, an appropriate particle range of quartz sand and layer height/layer diameter ratio (L/D ratio) was determined for a design of the fluidized bed reactor. Secondly, a windowed reactor mock-up was designed and fabricated for solar coke gasification using quartz sand as a bed material. The pressure loss between the inlet and outlet gases was examined, and descending cokes and sand particles on the sidewall of the reactor was observed in the reactor mock-up. The moving velocity and distance of descending particles/sands from the top to bottom of fluidized bed were measured by the visual observation of the colored tracer particles on outside wall of the reactor.

  20. Fiscal 1995 achievement report. Development of entrained bed coal gasification power plant (Part 5 - Surveys and studies of demonstration plant); 1995 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 5. Jissho plant ni kansuru chosa kenkyu hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Surveys and studies were conducted concerning a demonstration plant for establishing the technology of integrated coal gasification combined cycle, and the fiscal 1995 results are compiled. In this fiscal year, a demonstration plant conceptual design was prepared for assuring smooth transition from a pilot plant to a commercial plant. The design followed the system employed at the Nakoso pilot plant for its gasification power generation. It was decided that the gasification furnace be of the air-blown (oxygen enriched) 2-stage entrained bed type, that the desulfurization system be of the dry type 2-stage fluidized bed type, the dedusting system be of the dry type granular bed type (moving bed type), that the combined cycle power facility be derived from the commercialized gas turbine, and that the cycle of the steam system agree with the integrated coal gasification combined cycle system now under discussion. Studies were made, which covered heat efficiency (generating end/sending end), heat/matter balance, process flow, gas turbine/steam system optimization, comparison in performance with a pilot plant with its dimensions increased, estimation of the performance of each of the facilities, estimation of the construction cost, calculation of the generation cost, environmental friendliness, operating characteristics, acceptable coal types, and the like. (NEDO)

  1. Co-gasification of biomass and plastics: pyrolysis kinetics studies, experiments on 100 kW dual fluidized bed pilot plant and development of thermodynamic equilibrium model and balances.

    Science.gov (United States)

    Narobe, M; Golob, J; Klinar, D; Francetič, V; Likozar, B

    2014-06-01

    Thermo-gravimetric analysis (TGA) of volatilization reaction kinetics for 50 wt.% mixtures of plastics (PE) and biomass (wood pellets) as well as for 100 wt.% plastics was conducted to predict decomposition times at 850°C and 900°C using iso-conversional model method. For mixtures, agreement with residence time of dual fluidized bed (DFB) reactor, treated as continuous stirred-tank reactor (CSTR), was obtained at large conversions. Mono-gasification of plastics and its co-gasification with biomass were performed in DFB pilot plant, using olivine as heterogeneous catalyst and heat transfer agent. It was found that co-gasification led to successful thermochemical conversion of plastics as opposed to mono-gasification. Unknown flow rates were determined applying nonlinear regression to energy and mass balances acknowledging combustion fuel, air, steam, feedstock, but also exiting char, tar, steam and other components in DFB gasification unit. Water-gas shift equilibrium and methanol synthesis requirements were incorporated into gasification model, based on measurements. Copyright © 2014 Elsevier Ltd. All rights reserved.

  2. FY 1989 report on the results of the development of the entrained bed coal gasification power plant. Part 1. Element study; 1989 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 1. Yoso kenkyu hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-03-01

    For the purpose of establishing the technology of integrated coal gasification combined cycle power generation, element study was conducted of a 200t/d entrained bed coal gasification pilot plant, and the FY 1989 results were summarized. In the gasification test using 2t/d gasifier equipment, the following were carried out: test on gasification of the coal proposed for pilot plant, test on changes in coal feed ratio, analysis of trace gas elements in coal, study of the fixed bed gas refining system, etc. In the study of large gas turbine combustor for demonstration machine, development of combustor which makes stable combustion in the low load region possible, development of low NOx combustor which controls the conversion of nitrogen compounds such as ammonia in coal gasification gas to NOx, development of combustor which makes the optimum and effective cooling possible by combining film cooling, impingement cooling, etc. In the study of simulation of the combined power generation total system, verification tests on the control mode switching function of the general load pressure control system, movement to meet anomaly of the control system, integrated cooperation control system, etc. (NEDO)

  3. Fluidized Bed Gasification as a Mature And Reliable Technology for the Production of Bio-Syngas and Applied in the Production of Liquid Transportation Fuels—A Review

    Directory of Open Access Journals (Sweden)

    Adrian H.M. Verkooijen

    2011-03-01

    Full Text Available Biomass is one of the renewable and potentially sustainable energy sources and has many possible applications varying from heat generation to the production of advanced secondary energy carriers. The latter option would allow mobile services like the transportation sector to reduce its dependency on the fossil fuel supply. This article reviews the state-of-the-art of the fluidization technology applied for the gasification of biomass aimed at the production of gas for subsequent synthesis of the liquid energy carriers via, e.g., the Fischer-Tropsch process. It discusses the advantages of the gasification technology over combustion, considers the size of the conversion plant in view of the local biomass availability, assesses the pros and cons of different gasifier types in view of the application of the product gas. Subsequently the article focuses on the fluidized bed technology to discuss the main process parameters and their influence on the product composition and the operability of the gasifier. Finally a synthesis process (FT is introduced shortly to illustrate the necessary gas cleaning steps in view of the purity requirements for the FT feed gas.

  4. Steam gasification of wood biomass in a fluidized biocatalytic system bed gasifier: A model development and validation using experiment and Boubaker Polynomials Expansion Scheme BPES

    Directory of Open Access Journals (Sweden)

    Luigi Vecchione

    2015-07-01

    Full Text Available One of the most important issues in biomass biocatalytic gasification is the correct prediction of gasification products, with particular attention to the Topping Atmosphere Residues (TARs. In this work, performedwithin the European 7FP UNIfHY project, we develops and validate experimentally a model which is able of predicting the outputs,including TARs, of a steam-fluidized bed biomass gasifier. Pine wood was chosen as biomass feedstock: the products obtained in pyrolysis tests are the relevant model input. Hydrodynamics and chemical properties of the reacting system are considered: the hydrodynamic approach is based on the two phase theory of fluidization, meanwhile the chemical model is based on the kinetic equations for the heterogeneous and homogenous reactions. The derived differentials equations for the gasifier at steady state were implemented MATLAB. Solution was consecutively carried out using the Boubaker Polynomials Expansion Scheme by varying steam/biomass ratio (0.5-1 and operating temperature (750-850°C.The comparison between models and experimental results showed that the model is able of predicting gas mole fractions and production rate including most of the representative TARs compounds

  5. Fluidized-bed gasification of biomass: Conversion of fine carabon particles in the freeboard; Biomassevergasung in der Wirbelschicht: Umsatz von feinen Kohlenstoffpartikeln im Freeboard

    Energy Technology Data Exchange (ETDEWEB)

    Miccio, F. [Ist. Ricerche sulla Combustione-CNR, Napoli (Italy); Moersch, O.; Spliethoff, H.; Hein, K.R.G. [Stuttgart Univ. (Germany). Inst. fuer Verfahrenstechnik und Dampfkesselwesen

    1998-09-01

    The conversion of carbon particles in gasification processes was investigated in a fluidized-bed reactor of the Institute of Chemical Engineering and Steam Boiler Technology of Stuttgart University. This reactor is heated electrically to process temperature, and freeboard coal particles can be sampled using an isokinetic probe. The fuel used in the experiments consisted of beech wood chips. The temperature and air rating, i.e. the main parameters of the process, were varied in order to investigate their influence on product gas quality and carbon conversion. The conversion rate is influenced to a significant extent by grain disintegration and discharge of carbon particles. In gasification conditions, a further conversion process takes place in the freeboard. (orig.) [Deutsch] In dieser Arbeit wird die Umsetzung von Kohlenstoffpartikeln unter Vergasungsbedingungen untersucht. Die Versuche wurden an einem Wirbelschichtreaktor des Instituts fuer Verfahrenstechnik und Dampfkesselwesen der Universitaet Stuttgart durchgefuehrt. Dieser Reaktor wird elektrisch auf Prozesstemperatur beheizt. Mit Hilfe einer isokinetischen Sonde koennen Proben von Kohlenstoffpartikeln im Freeboard genommen werden. Als Brennstoff wurden zerkleinerte Buchenholz-Hackschnitzel eingesetzt. Variiert wurden als Hauptparameter des Prozesses Temperatur und Luftzahl. Untersucht wurde der Einfluss dieser Parameter auf die Qualitaet des Produktgases und die Umsetzung des Kohlenstoffes. Kornzersetzungs- und Austragsvorgaenge von Kohlenstoffpartikeln spielen eine wichtige Rolle fuer den Kohlenstoffumsatz. Unter Vergasungsbedingungen findet im Freeboard eine weitere Umsetzung der Partikel statt. (orig.)

  6. Gasification Product Improvement Facility (GPIF). Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    The gasifier selected for development under this contract is an innovative and patented hybrid technology which combines the best features of both fixed-bed and fluidized-bed types. PyGas{trademark}, meaning Pyrolysis Gasification, is well suited for integration into advanced power cycles such as IGCC. It is also well matched to hot gas clean-up technologies currently in development. Unlike other gasification technologies, PyGas can be designed into both large and small scale systems. It is expected that partial repowering with PyGas could be done at a cost of electricity of only 2.78 cents/kWh, more economical than natural gas repowering. It is extremely unfortunate that Government funding for such a noble cause is becoming reduced to the point where current contracts must be canceled. The Gasification Product Improvement Facility (GPIF) project was initiated to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology at a cost approaching $1,000 per kilowatt for electric power generation applications. The project was to include an innovative, advanced, air-blown, pressurized, fixed-bed, dry-bottom gasifier and a follow-on hot metal oxide gas desulfurization sub-system. To help defray the cost of testing materials, the facility was to be located at a nearby utility coal fired generating site. The patented PyGas{trademark} technology was selected via a competitive bidding process as the candidate which best fit overall DOE objectives. The paper describes the accomplishments to date.

  7. Fluidized Bed Gasification of Coal-Oil and Coal-Water-Oil Slurries by Oxygen –Steam and Oxygen-CO2 Mixtures

    Czech Academy of Sciences Publication Activity Database

    Svoboda, Karel; Pohořelý, Michael; Jeremiáš, Michal; Kameníková, Petra; Hartman, Miloslav; Skoblia, S.; Šyc, Michal

    2012-01-01

    Roč. 95, č. 1 (2012), s. 16-26 ISSN 0378-3820 R&D Projects: GA MŠk 2B08048; GA MŠk 7C08034 Grant - others:RFCR(XE) CT-2010-00009 Institutional research plan: CEZ:AV0Z40720504 Keywords : fluidized bed * gasification * coal slurries Subject RIV: JE - Non-nuclear Energetics, Energy Consumption ; Use Impact factor: 2.816, year: 2012 http://www.scopus.com/record/display.url?eid=2-s2.0-82455175439&origin=resultslist&sort=plf-f&src=s&st1=svoboda%2ck&sid=ikNGw6d45E-yyuMoDwlGiWn%3a420&sot=b&sdt=b&sl=22&s=AUTHOR-NAME%28svoboda%2ck%29&relpos=1&relpos=1&searchTerm=AUTHOR-NAME(svoboda,k)

  8. Biomass gasification with air in a fluidized bed: Effect of the in-bed use of dolomite under different operation conditions

    Energy Technology Data Exchange (ETDEWEB)

    Gil, J.; Caballero, M.A.; Martin, J.A.; Aznar, M.P.; Corella, J.

    1999-11-01

    The performance of a biomass gasifier, fluidized-bed type, is improved by in-bed use of calcined dolomite. Tar contents in the raw flue gas below 1 g/m{sub n}{sup 3} are obtained by using a bed with a percentage between 15 and 30 wt% of dolomite (the rest being silica sand). The work is carried out at small pilot-plant scale (10 kg of biomass/h) with equivalence ratios (ER) between 0.20 and 0.35 and temperatures of 800--840 C in the gasifier bed. To replace the eroded and elutriated dolomite (from the gasifier bed), an amount of dolomite (0.40--0.63 mm) is continuously fed, mixed with the biomass at 3 wt%. When the results obtained with in-bed dolomite are compared to the ones gained in a gasifier bed without dolomite, change of the following variables is reported: gas composition and its corresponding heating value, gas and char yields, apparent thermal efficiency, and tar contents. Once the usefulness of the in-bed use of dolomite is established, three main operation variables (ER and temperature of the gasifier bed and freeboard) are studied in the improved gasifier. Carryover of solids from the gasifier also increases when calcined dolomite is used because of its softness. Elutriation rate constants are calculated for several operational parameters.

  9. Simulation assessment of continuous simulating moving bed chromatography process with partial feed and new strategy with partial feed

    Directory of Open Access Journals (Sweden)

    H. Khan

    2009-09-01

    Full Text Available Partial Feed simulating moving bed (SMB has proved to be more efficient in binary separation performance (purity, recovery, productivity because of its two additional degrees of freedom, namely feed length and feed time, as compared to classical SMB process. The binary separation of dextran T6 and fructose with linear isotherm is modeled with Aspen Chromatography simulator in a four zone SMB with one column per zone for both normal-feed and Partial Feed. Increase in number of feed length and feed time in the cycle plays a very important role in the separation performance with Partial Feed. In addition, the effect of mode of operation (early or late introduction of increase in number of feed length in the cycle on product purity and recovery is also investigated. Furthermore, the binary separation system is designed with the safety margin method and the optimum operating parameters for simulation are calculated with triangle theory. Finally, a new strategy with Partial Feed is developed, showing improved separation performance relative to the basic four-zone SMB with regard to extract stream purity and recovery. The results of the proposed study can served as a useful summary of Partial Feed operation.

  10. Design, fabrication, operation and Aspen simulation of oil shale pyrolysis and biomass gasification process using a moving bed downdraft reactor

    Science.gov (United States)

    Golpour, Hassan

    Energy is the major facilitator of the modern life. Every developed and developing economy requires access to advanced sources of energy to support its growth and prosperity. Declining worldwide crude oil reserves and increasing energy needs has focused attention on developing existing unconventional fossil fuels like oil shale and renewable resources such as biomass. Sustainable, renewable and reliable resources of domestically produced biomass comparing to wind and solar energy is a sensible motivation to establish a small-scale power plant using biomass as feed to supply electricity demand and heat for rural development. The work in Paper I focuses on the possibility of water pollution from spent oil shale which should be studied before any significant commercial production is attempted. In Paper II, the proposed Aspen models for oil shale pyrolysis is to identify the key process parameters for the reactor and optimize the rate of production of syncrude from oil shale. The work in Paper III focuses on (1) Design and operation of a vertical downdraft reactor, (2) Establishing an optimum operating methodology and parameters to maximize syngas production through process testing. Finally in Paper IV, a proposed Aspen model for biomass gasification simulates a real biomass gasification system discussed in Paper III.

  11. Biomass gasification in fluidized bed at pilot-scale with steam-oxygen mixtures. Product distribution for very different operating conditions

    Energy Technology Data Exchange (ETDEWEB)

    Gil, J.; Aznar, M.P.; Caballero, M.A.; Frances, E.; Corella, J. [University of Zaragoza, Zaragoza (Spain). Chemical and Environmental Engineering Dept.

    1997-11-01

    Biomass gasification in a fluidized bed with steam-O{sub 2} mixtures has been studied in detail at pilot plant scale. The gasifier used was 15 cm i.d. and 3.2 m high, and it was fed with pine wood chips at flow rates of 5-20 kg/h. Main operating variables studied were gasifier bed temperature (780-890{degree}C), steam to oxygen in the feeding ratio (2-3 mol/mol), and gasifying agent (H{sub 2}O + O{sub 2}) to biomass feed ratio (0.6-1.6 kg/kg daf). Product distribution here shown includes gas, tar and char yields, gas composition (H{sub 2}, CO, CO{sub 2}, CH{sub 4} steam,...) and heating value, tar composition and content in the flue gas, gas heating value, apparent thermal efficiency, etc. Under good operating conditions the following gas is obtained: tar content of 5 g/Nm{sup 3}, 30 vol % H{sub 2}, heating value of 16.0 MJ/Nm{sub 3} (dry basis), gas yield of 1.2 Nm{sup 3} (dry basis)/kg biomass fed. 28 refs., 29 figs., 1 tab.

  12. Biomass gasification with steam in fluidized bed: Effectiveness of CaO, MgO, and CaO-MgO for hot raw gas cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Delgado, J.; Aznar, M.P. [Univ. of Saragossa (Spain). Dept. of Chemical and Environmental Engineering; Corella, J. [Univ. Complutense of Madrid (Spain). Dept. of Chemical Engineering

    1997-05-01

    The upgrading of the raw hot gas from a bubbling fluidized bed biomass gasifier is studied using cheap calcined minerals or rocks downstream from the gasifier. Biomass gasification is made with steam (not air) at 750--780 C and about 0.5--1.0 kg of biomass/h. Calcined solids used are dolomite (MgO-CaO), pure calcite (CaO), and pure magnesite (MgO). Variables studied have been temperature of the secondary bed (780--910 C), time of contact or space-time of the gas (0.08--0.32 kg{center_dot}h/m{sup 3}n), and particle diameter (1--4 mm) and type of mineral. Their effects on tar conversion, tar amount in the exit gas, product distribution, and gas composition are presented. Using a macrokinetic model for the tar disappearance network, the activities of the stones are expressed by their apparent kinetic constant. Apparent energies of activation for tar elimination (42--47 kJ/mol) and preexponential and effectiveness factors are given for all tested solids of which the most active is the calcined dolomite.

  13. Achievement report for fiscal 1993 on developing entrained bed coal gasification power plant. Part 4. Pilot plant operation edition; 1993 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 4. Pilot plant unten sosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-02-01

    Tests and researches have been carried out on operation of a 200-t/d entrained bed coal gasification pilot plant built with an objective of establishing the coal gasification composite power generation technology. This paper summarizes the operation achievements in fiscal 1993. The plant operation record in fiscal 1993 was as follows: 430 hours 27 minutes in the gasification furnace (ten gasification operations), 233 hours 51 minutes in the gas refining facility, 140 hours 31 minutes in the gas turbine facility (power generation amount of 746.8 MWh with nine actuations), 1,263 hours 09 minutes in the processing furnace in the safety environment facility, and 427 hours 22 minutes in the NOx removal equipment. Descriptions were given with detailed graphs on the actuation and shutdown record with respect to the run D2, the run D3 (1 and 2), the run D4, the run D5, the run D6, and the run D7 (1 through 4). The operation procedures were prepared for the plant startup and shutdown schedule, the generalization report, the gasification furnace facility, the gas refining facility (dry type desulfurizing facility), the gas refining facility (dry type dust removing facility), the gas turbine facility, the combustor testing facility with actual pressure and size, and the safety environment facilities. (NEDO)

  14. Development of a packed-bed combination gasification system. Opportunities for economical energy generation from waste and chip wood; Entwicklung eines kombinierten Festbettvergasungsverfahrens. Chancen fuer die wirtschaftliche energetische Nutzung von Alt- und Restholz

    Energy Technology Data Exchange (ETDEWEB)

    Senger, W. [Inst. fuer Umwelttechnologie und Umweltanalytik e.V., Duisburg (Germany). Abt. Abfallwirtschaft/Monobrennstoffe

    1998-01-01

    For environment-political reasons and with a view to saving fossil fuel resources, enhanced use of renewable feedstocks for energy generation, especially at decentral combustion or gasification plants, is called for. Thermal processing of, for instance, waste and chip wood by gasification has fundamental advantages over combustion: the lean gas produced generates electricity directly by means of a gas engine or gas turbine. For decentral uses, it is above all packed-bed gasification systems, and among these particularly downward and upward gasification systems, that are of interest. Both types have mutually exclusive advantages, which are to be harnessed in a combination gasification system developed by the IUTA. (orig.) [Deutsch] Aus umweltpolitischen Gruenden und vor dem Hintergrund des Zieles der Schonung fossiler Brennstoffe wird ein verstaerkter Einsatz nachwachsender Rohstoffe zur Energieerzeugung insbesondere auch durch dezentrale Verbrennungs- oder Vergasungsanlagen gefordert. Bei der thermischen Verwertung von zum Beispiel Alt- und Resthoelzern weist die Vergasungstechnik gegenueber der Verbrennung prinzipielle Vorteile auf, da aus dem produzierten Schwachgas mit einem Gasmotor oder einer Gasturbine direkt Strom erzeugt werden kann. Fuer den dezentralen Einsatz sind vor allem Festbettvergaser und bei diesen insbesondere Gleich- und Gegenstromvergaser interessant. Beide Typen weisen sich ausschliessende Vorteile auf, die in einem vom IUTA entwickelten kombinierten Festbettvergaser genutzt werden sollen. (orig.)

  15. Fiscal 1995 achievement report. Development of entrained bed coal gasification power plant (Part 4 - Pilot plant operation); 1995 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 4. Pilot plant unten sosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The 200 tons/day entrained bed coal gasification pilot plant constructed for establishing the technology of integrated coal gasification combined cycle was subjected to operational tests, and the fiscal 1995 results are compiled. In fiscal 1995, 1328 hours and 3 minutes (8 gasification operations) was recorded with gasification furnace facility, 899 hours and 53 minutes with the gas clean-up facility, 831 hours and 27 minutes with the gas turbine facility (11 startups for the generation of 6657 MWh), and 1958 hours and 2 minutes with the treatment furnace and 1331 hours and 10 minutes with the denitration unit of the safety/environment-related facility. The details of starts and stops were described in graphs which covered Runs D13, D14-1, D14-2, E1, D15, and A14. Operating procedures were studied and compiled for the plant start/stop schedule, general guidelines, gasification furnace facility, gas clean-up facility (dry type desulfurization facility), gas clean-up facility (dry type dedusting facility), gas turbine facility, real-pressure natural-size combustor test facility, and the safety/environment-related facility. (NEDO)

  16. FY 1990 report on the results of the development of the entrained bed coal gasification power plant. Part 1. Element study; 1990 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 1. Yoso kenkyu hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    For the purpose of establishing the technology of the integrated coal gasification combined cycle power generation, element study was made for a pilot plant of 200t/d entrained bed coal gasification power generation, and the FY 1990 results were summarized. In the study by the gasification test on 2t/d furnace, gasification test was conducted for the OM coal newly selected as a coal proposed for the expansion of coal kind. As a result, the pulverized coal/char of OM coal have almost good handling property and showed favorable gasification performance. In the study of large gas turbine combustor for demonstrative machine, with the aim of developing a combustor that makes stable combustion also in the low load region possible, fabrication of the accessory equipment of combustor (choke mechanism, measuring use duct and heat insulating plate) was made for the actual-pressure/actual-size combustion test. In the study by simulation of the total system of combined cycle power generation, etc., the following were conducted: verification of characteristics of the integrated control (state of the ordinary operation, state of the mock load control, etc.), load dump simulation (state of the bleed cooperation, state of the bleed separation (state of the air booster operation, etc.)), etc. (NEDO)

  17. Fiscal 1994 achievement report. Development of entrained bed coal gasification power plant (Part 4 - Pilot plant operation); 1994 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 4. Pilot plant unten sosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    The 200 tons/day entrained bed coal gasification pilot plant constructed for the establishment of the technology of integrated coal gasification combined cycle power generation was operated for testing, and the results are put together. Operating hours recorded were 1347 hours and 7 minutes for the gasification furnace facility (7 gasification operations), 752 hours and 22 minutes for the gas clean-up facilities, 425 hours and 20 minutes for the gas turbine facility (6 startups for generating 2616.1 MWh), and 1852 hours for the treatment furnace and 1304 hours and 32 minutes for the denitration system in the safety/environment-related facility. Detailed graphs were drawn for the description of starts and stops in Run D8, Run D9 (1-3), Run D10, Run D11, and in Run D12. Operating procedures were studied and then compiled for the plant start-stop schedule, general guidelines, gasification furnace facility, gas clean-up facility (dry type desulfurization facility), gas clean-up facility (dry type dedusting facility), gas turbine facility, real-pressure natural-size combustor test facility, and for the safety/environment related facility. (NEDO)

  18. Technical and economical optimization of wood gasification in a circulating fluidized bed. Final report; Technische und wirtschaftliche Optimierung der Vergasung von Holz in der zirkulierenden Wirbelschicht. Abschlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Ising, M.; Unger, C.; Heunemann, F.; Dinkelbach, L.

    2002-12-01

    The project's objective was the optimization of a novel process for high efficient combined heat and power production from solid biomass. The processed air blown wood gasification in a pilot scale circulating fluidized bed was added by a catalytic tar reformer which would yield a tar-free gas quality suitable for IC-engine operation. Major efforts were taken for technical improvement of the tar reformer, especially concerning temperature control and cleaning devices which is important for keeping constantly a high activity. Pure natural timber did not yield chemical deactivation at the catalyst whereas the gasification of waste wood yielded decreasing activity which could be partly reversed by special measures taken. Further optimization of the process considered a better automation and improvement of the engine's flue gas emissions. Also a detailed economic consideration and evaluation of the entire process has been carried out. As a result the novel process should have economic advantages compared with conventional technology. (orig.) [German] Gegenstand des Vorhabens war die Weiterentwicklung eines Verfahrens zur effizienteren Strom- und Waermegewinnung aus festen Biobrennstoffen. Durch luftgeblasene Vergasung von Holz im Pilotmassstab in einer zirkulierenden Wirbelschicht und anschliessender katalytischer Teerspaltung konnte ein niederkalorisches Brenngas erzeugt werden, welches zum Betrieb eines Motoren-Blockheizkraftwerks geeignet war. Im Rahmen der Verfahrensoptimierung wurde der katalytische Teer-Reformer, insbesondere in Bezug auf Temperaturfuehrung und die zum Aktivitaetserhalt wichtige Abreinigungsvorrichtung, verbessert. Bei der Vergasung von Naturholz wurde keine chemische Desaktivierung festgestellt. Beim Altholzeinsatz wurde ein ueberwiegend reversibler Aktivitaetsverlust verzeichnet und begruendet. Geeignete Gegenmassnahmen wurden untersucht und beschrieben. Weitere Optimierungen betrafen die Anlagensteuerungstechnik im Hinblick auf die

  19. Steam gasification of coal at low-medium (600-800{sup o}C) temperature with simultaneous CO{sub 2} capture in fluidized bed at atmospheric pressure: The effect of inorganic species. 1. Literature review and comments

    Energy Technology Data Exchange (ETDEWEB)

    Corella, J.; Toledo, J.M.; Molina, G. [Universidad Complutense de Madrid, Madrid (Spain). Dept. for Chemical Engineering

    2006-08-30

    This paper addresses the H{sub 2} production with simultaneous CO{sub 2} capture by steam gasification of coal in a fluidized bed, at low/medium temperatures (600-800{sup o}C) and atmospheric pressure. This work is mainly aimed at reviewing the effects of the inorganic species present in the matrix of the coal or added to the gasifier bed. The most promising species seems to be the calcined limestone (CaO), which intervenes in the overall gasification reaction network in at least five different types of reactions. The effectiveness of the CaO for CO{sub 2} capture in the coal gasifier is, therefore, affected/influenced by the other four simultaneous or competitive types of reactions in the gasifier. The effects of the temperature in the gasifier and of the (CaO/coal) ratio fed to the gasifier are finally reviewed and discussed in detail.

  20. Thermal decomposition and gasification of biomass pyrolysis gases using a hot bed of waste derived pyrolysis char.

    Science.gov (United States)

    Al-Rahbi, Amal S; Onwudili, Jude A; Williams, Paul T

    2016-03-01

    Chars produced from the pyrolysis of different waste materials have been investigated in terms of their use as a catalyst for the catalytic cracking of biomass pyrolysis gases during the two-stage pyrolysis-gasification of biomass. The chars were produced from the pyrolysis of waste tyres, refused derived fuel and biomass in the form of date stones. The results showed that the hydrocarbon tar yields decreased significantly with all the char materials used in comparison to the non-char catalytic experiments. For example, at a cracking temperature of 800°C, the total product hydrocarbon tar yield decreased by 70% with tyre char, 50% with RDF char and 9% with biomass date stones char compared to that without char. There was a consequent increase in total gas yield. Analysis of the tar composition showed that the content of phenolic compounds decreased and polycyclic aromatic hydrocarbons increased in the product tar at higher char temperatures. Copyright © 2015 Elsevier Ltd. All rights reserved.

  1. A thermo fluid dynamic model of wood particle gasification- and combustion processes

    Directory of Open Access Journals (Sweden)

    G Boiger

    2016-09-01

    Full Text Available In order to qualitatively understand and evaluate the thermo- fluid dynamic situation within a wood gasification reactor, a 1D particle model has been created. The presented tool accounts for the highly in- stationary, kinetic- and thermo chemical effects, leading to partial gasification and combustion of a wood particle embedded within a packed bed collective. It considers the fluid- dynamic situation within the changing porous bulk structure of the packed bed, its impact on species- and heat transition mechanisms, the energy- and mass balances of wood, coal, pyrolysis-gas, wood- gas and off- gas phases, the thermodynamics of locally developing gasification- and combustion reaction equilibria, as well as the presence of the chemical species hydrogen, water, carbon (di- oxide, methane, oxygen, solid carbon and gaseous, longer chain hydrocarbons from pyrolysis. Model results can be shown to yield very good, qualitative agreement with measurements, found in literature.

  2. On a clean power generation system with the co-gasification of biomass and coal in a quadruple fluidized bed gasifier.

    Science.gov (United States)

    Yan, Linbo; He, Boshu

    2017-07-01

    A clean power generation system was built based on the steam co-gasification of biomass and coal in a quadruple fluidized bed gasifier. The chemical looping with oxygen uncoupling technology was used to supply oxygen for the calciner. The solid oxide fuel cell and the steam turbine were combined to generate power. The calcium looping and mineral carbonation were used for CO 2 capture and sequestration. The aim of this work was to study the characteristics of this system. The effects of key operation parameters on the system total energy efficiency (ŋ ten ), total exergy efficiency (ŋ tex ) and carbon sequestration rate (R cs ) were detected. The energy and exergy balance calculations were implemented and the corresponding Sankey and Grassmann diagrams were drawn. It was found that the maximum energy and exergy losses occurred in the steam turbine. The system ŋ ten and ŋ tex could be ∼50% and ∼47%, and R cs could be over unit. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. Advanced treatment of biologically pretreated coal gasification wastewater using a novel anoxic moving bed biofilm reactor (ANMBBR)-biological aerated filter (BAF) system.

    Science.gov (United States)

    Zhuang, Haifeng; Han, Hongjun; Jia, Shengyong; Zhao, Qian; Hou, Baolin

    2014-04-01

    A novel system integrating anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) with short-cut biological nitrogen removal (SBNR) process was investigated as advanced treatment of real biologically pretreated coal gasification wastewater (CGW). The results showed the system had efficient capacity of degradation of pollutants especially nitrogen removal. The best performance was obtained at hydraulic residence times of 12h and nitrite recycling ratios of 200%. The removal efficiencies of COD, total organic carbon, NH4(+)-N, total phenols and total nitrogen (TN) were 74.6%, 70.0%, 85.0%, 92.7% and 72.3%, the corresponding effluent concentrations were 35.1, 18.0, 4.8, 2.2 and 13.6mg/L, respectively. Compared with traditional A(2)/O process, the system had high performance of NH4(+)-N and TN removal, especially under the high toxic loading. Moreover, ANMBBR played a key role in eliminating toxicity and degrading refractory compounds, which was beneficial to improve biodegradability of raw wastewater for SBNR process. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Fiscal 1996 achievement report. Development of entrained bed coal gasification power plant (Part 1 - Studies of dismantling and surveys of techniques); 1995 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 1. Kaitai kenkyu hen, gijutsu chosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-01-01

    For the establishment of technology of integrated coal gasification combined cycle, studies were made for the dismantling of the 200 tons/day entrained bed coal gasification pilot plant and surveys were conducted of overseas technologies. In the gasification furnace facility, 40 devices were selected, and dismantled, from the locations corresponding to the factors of damage expected to occur involving important equipment. Although no significant damage was detected in the gasification pressure vessel, peripheral walls, or the like, malfunctions due to corrosion or abrasion were discovered in some pipes and members. In the dry type gas clean-up facility (desulfurization facility), damage due to heat stress or corrosion was detected in the regeneration tower inner cyclone, regeneration tower filter flexible tubes, and in circulation gas cooler cooling tubes. In the dry type gas clean-up facility (dedusting facility), damage was found in the dust collector gas seal valve, dust collector filter materials cut valve, and in the separator A/B. In the gas turbine facility, no abnormality was discovered but for some damage in some initial stage static vanes. (NEDO)

  5. FY 1991 report on the results of the development of the entrained bed coal gasification power plant. Part 1. Element study/investigational study of technology/study of the integrated coal gasification combined cycle power system; 1991 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 1. Youso kenkyu hen, gijutsu chosa hen, sekitan gaska fukugo hatsuden system kento hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-01-01

    For the purpose of establishing the technology of integrated coal gasification combined cycle power generation, the following were conducted: element study of a 200t/d entrained bed coal gasification pilot plant, survey of technology of the coal gasification power generation, study of the practical scale IGCC, etc. The FY 1991 results were summarized. In the gasification test using 2t/d furnace equipment, evaluation test on the test coal for pilot plant was made. In the study of gas turbine combustor for demonstration machine use, measuring duct was fabricated for measurement of combustion gas temperature/pressure, etc. In the simulational study of the total system of combined cycle power generation, review/modification of part of the simulation model and detailing of the model were conducted by comparison with the data on pilot plant operation. In the technology study, joint technology conferences were held for discussions between Japan and Australia, Japan and the U.S., and Japan and Canada. As to the practical scale IGCC, the initially planned output capacity and thermal efficiency were studied based on the knowledge/information obtained through the R and D on the 200t/d pilot plant. (NEDO)

  6. Power partial-discard strategy to obtain improved performance for simulated moving bed chromatography.

    Science.gov (United States)

    Chung, Ji-Woo; Kim, Kyung-Min; Yoon, Tae-Ung; Kim, Seung-Ik; Jung, Tae-Sung; Han, Sang-Sup; Bae, Youn-Sang

    2017-12-22

    A novel power partial-discard (PPD) strategy was developed as a variant of the partial-discard (PD) operation to further improve the separation performance of the simulated moving bed (SMB) process. The PPD operation varied the flow rates of discard streams by introducing a new variable, the discard amount (DA) as well as varying the reported variable, discard length (DL), while the conventional PD used fixed discard flow rates. The PPD operations showed significantly improved purities in spite of losses in recoveries. Remarkably, the PPD operation could provide more enhanced purity for a given recovery or more enhanced recovery for a given purity than the PD operation. The two variables, DA and DL, in the PPD operation played a key role in achieving the desired purity and recovery. The PPD operations will be useful for attaining high-purity products with reasonable recoveries. Copyright © 2017 Elsevier B.V. All rights reserved.

  7. FY 1991 report on the results of the development of an entrained bed coal gasification power plant. Part 4. Operation of pilot plant; 1991 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 4. Pilot plant unten sosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-01-01

    A record was summarized of the operation of the 200 t/d entrained bed coal gasification pilot plant that was constructed with the aim of establishing technology of the integrated coal gasification combined cycle power generation. As to the actual results of operation hours, the paper summarized the records of gasifier facilities, gas refining facilities, gas turbine facilities and safety environment facilities which were collected from April 1991 to January 1993. Relating to the actual results of start-up/stop, the paper summarized the records of gasifier facilities, gas refining facilities (desulfurization), gas refining facilities (dedusting), gas turbine facilities and safety environment facilities. Further, operation manuals were made for the schedule of plant start-up/stop, generalization, gasifier facilities, gas refining facilities (desulfurization), gas refining facilities (dedusting), gas turbine facilities, actual pressure/actual size combustor testing facilities and safety environment facilities. (NEDO)

  8. Effect of Mass-Transport Limitations on the Performance of a Packed Bed Membrane Reactor for Partial Oxidations. Transport from the Membrane to the Packed Bed

    NARCIS (Netherlands)

    van Sint Annaland, M.; Kurten, U.; Kuipers, J.A.M.

    2007-01-01

    With a packed bed membrane reactor, the product yield can be significantly enhanced for partial oxidation systems, via distributive addition of oxygen to the reaction mixture along the axial coordinate of the reactor, provided that the reaction order in oxygen of the formation rate of the target

  9. Gasificación con aire en lecho fluidizado de los residuos sólidos del proceso industrial de la naranja//Air gasification in fluidized bed of solid residue the orange industrial process

    Directory of Open Access Journals (Sweden)

    Leonardo Aguiar-Trujillo

    2012-12-01

    Full Text Available La industria procesadora de la naranja genera elevados volúmenes de residuos sólidos. Este residuo se ha utilizado en la alimentación animal y en procesos bioquímicos; pero no se ha aprovechado a través de la gasificación. El objetivo del trabajo fue determinar el aporte energético por medio del proceso de gasificación, realizándose estudios de los residuos sólidos de naranja, utilizando aire en reactor de lecho fluidizado burbujeante (variando la temperatura de gasificación, relación estequiométrica y altura del lecho. En el proceso se utilizó un diseño de experimento factorial completo de 2k, valorando la influencia de las variables independientes y sus interacciones en las respuestas, con un grado de significación del 95 %. Se obtuvieron los parámetros para efectuar el proceso de gasificación de los residuos sólidos de naranja, obteniendo un gas de bajo poder calórico, próximo a 5046 kJ/m3N, demostrando sus cualidades para su aprovechamiento energético.Palabras claves: gasificación con aire, lecho fluidizado, residuo de naranja._______________________________________________________________________________AbstractThe orange industrial process generates high volumes of solid residue. This residue has been used as complement in the animal feeding and biochemical processes; but it has not taken advantage through of the gasification process. The objective of the work was to determine the energy contribution by means ofthe gasification process, were carried out studies of the orange solid residue, using air in reactor of bubbling fluidized bed (varying the gasification temperature, air ratio and bed height. In the process a design of complete factorial experiment of 2k, was used, valuing the influence of the independent variables and its interactions in the answers, using a confidence level of 95 %. Were obtained the parameters to make the process of gasification of the orange solid residue, obtaining a gas of lower heating

  10. FY 1992 report on the results of the development of an entrained bed coal gasification power plant. Part 4. Operation of pilot plant; 1992 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 4. Pilot plant unten sosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-02-01

    A record was summarized of the operation test study in FY 1992 of the 200 t/d entrained bed coal gasification pilot plant that was constructed with the aim of establishing technology of the integrated coal gasification combined cycle power generation. The operating hour of gasifier facilities in FY 1992 was 635 hours 19 minutes, and the number of times of gasification operation was 9. The operating hour of letting gas through to gas refining facilities was 549 hours 14 minutes. The operating hour of gas turbine facilities was 310 hours 18 minutes, and the generated output was 1,366.2 MWh. The operating hour of treatment furnace of safety environment facilities was 1,401 hours 4 minutes, and that of the denitrification system was 621 hours 24 minutes. As to the actual results of the start-up/stop, the paper detailedly recorded those of RUNs 10, 11, 12, 13 and D1. Further, operation manuals were made for the schedule of plant start-up/stop, gasifier facilities, gas refining facilities (dry desulfurization facilities), gas refining facilities (dry dedusting facilities), actual pressure/actual size combustor testing facilities and safety environment facilities. (NEDO)

  11. A comparison of Rh/CeO2/SiO2 catalysts with steam reforming catalysts, dolomite and inert materials as bed materials in low throughput fluidized bed gasification systems

    International Nuclear Information System (INIS)

    Asadullah, Mohammad; Miyazawa, Tomohisa; Ito, Shin-ichi; Kunimori, Kimio; Koyama, Shuntarou; Tomishige, Keiichi

    2004-01-01

    The gasification of cedar wood in the presence of Rh/CeO 2 /SiO 2 has been conducted in the laboratory scale fluidized bed reactor using air as a gasifying agent at low temperatures (823-973 K) in order to produce high-quality fuel gas for gas turbine for power generation. The performance of the Rh/CeO 2 /SiO 2 catalyst has been compared with conventional catalysts such as commercial steam reforming catalyst G-91, dolomite and noncatalyst systems by measurements of the cold gas efficiency, tar concentration, carbon conversion to gas and gas composition. The tar concentration was completely negligible in the Rh/CeO 2 /SiO 2 -catalyzed product gas whereas it was about 30, 113, and 139 g/m 3 in G-91, dolomite and noncatalyzed product gas, respectively. Since the carbon conversion to useful gas such as CO, H 2 , and CH 4 are much higher on Rh/CeO 2 /SiO 2 catalyst than others at 873 K, the cold gas efficiency is much higher (71%) in this case than others. The hydrogen content in the product gas is much higher (>24 vol%) than the specified level (>10 vol%) for efficient combustion in the gas turbine engine. The char and coke formation is also very low on Rh/CeO 2 /SiO 2 catalyst than on the conventional catalysts. Although the catalyst surface area was slightly decreased after using the same catalyst in at least 20 experiments, the deactivation problem was not severe

  12. Bed and width oscillations form coherent patterns in a partially confined, regulated gravel-cobble-bedded river adjusting to anthropogenic disturbances

    Science.gov (United States)

    Brown, Rocko A.; Pasternack, Gregory B.

    2017-01-01

    Understanding the spatial organization of river systems in light of natural and anthropogenic change is extremely important because it can provide information to assess, manage, and restore them to ameliorate worldwide freshwater fauna declines. For gravel- and cobble-bedded alluvial rivers studies spanning analytical, empirical and numerical domains suggest that at channel-forming flows there is a tendency towards covarying bankfull bed and width undulations amongst morphologic units such as pools and riffles, whereby relatively wide areas have relatively higher minimum bed elevations and relatively narrow areas have relatively lower minimum bed elevations. The goal of this study was to determine whether minimum bed elevation and flow-dependent channel top width are organized in a partially confined, incising gravel-cobbled bed river with multiple spatial scales of anthropogenic and natural landform heterogeneity across a range of discharges. A key result is that the test river exhibited covarying oscillations of minimum bed elevation and channel top width across all flows analyzed. These covarying oscillations were found to be quasiperiodic at channel-forming flows, scaling with the length scales of bars, pools and riffles. Thus, it appears that alluvial rivers organize their topography to have quasiperiodic, shallow and wide or narrow and deep cross section geometry, even despite ongoing, centennial-scale incision. Presumably these covarying oscillations are linked to hydrogeomorphic mechanisms associated with alluvial river channel maintenance. The biggest conclusion from this study is that alluvial rivers are defined more so by variability in topography and flow than mean conditions. Broader impacts of this study are that the methods provide a framework for characterizing longitudinal and flow-dependent variability in rivers for assessing geomorphic structure and aquatic habitat in space, and if repeated, through time.

  13. Kinetics of gasification and combustion of residues, biomass and coal in a bubbling fluidized bed; Die Kinetik der Vergasung und Verbrennung unterschiedlicher Abfaelle, Biomassen und Kohlen in der blasenbildenden Wirbelschicht

    Energy Technology Data Exchange (ETDEWEB)

    Hamel, S.; Krumm, W. [Siegen Univ. (Gesamthochschule) (Germany). Lehrstuhl fuer Energie- und Umweltverfahrenstechnik

    1998-09-01

    The combustion and gasification characteristics of Rhenish brown coal, domestic waste, waste plastics, wood and sewage sludge were investigated in a bubbling atmospheric fluidized bed in the laboratory scale. The materials were pyrolyzed in the fluidized bed in a nitrogen atmosphere. The residual coke was combuted in the presence of oxygen with varying operating parameters or else gasified in the presence of carbon dioxide. The different materials were characterized by global combustion rates, and kinetic parameters were determined for residual coke combustion. (orig.) [Deutsch] Das Verbrennungs- und Vergasungsverhalten von Rheinischer Braunkohle, Hausmuell, Restkunststoff, Holz und Klaerschlamm wurde in einer blasenbildenden, atmosphaerischen Laborwirbelschicht untersucht. Die Einsatzstoffe wurden in der mit Stickstoff fluidisierten Wirbelschicht pyrolysiert. Der verbleibende Restkoks wurde anschliessend unter Variation der Betriebsparameter mit Sauerstoff verbrannt oder mit Kohlendioxid vergast. Die unterschiedlichen Einsatzstoffe wurden durch globale Vebrennungsraten charakterisiert. Fuer die Restkoksverbrennung wurden kinetische Parameter ermittelt. (orig.)

  14. Bio-syngas production from agro-industrial biomass residues by steam gasification.

    Science.gov (United States)

    Pacioni, Tatiana Ramos; Soares, Diniara; Domenico, Michele Di; Rosa, Maria Fernanda; Moreira, Regina de Fátima Peralta Muniz; José, Humberto Jorge

    2016-12-01

    This study evaluated the steam gasification potential of three residues from Brazilian agro-industry by assessing their reaction kinetics and syngas production at temperatures from 650 to 850°C and a steam partial pressure range of 0.05 to 0.3bar. The transition temperature between kinetic control and diffusion control regimes was identified. Prior to the gasification tests, the raw biomasses, namely apple pomace, spent coffee grounds and sawdust, were pyrolyzed in a fixed-bed quartz tubular reactor under controlled conditions. Gasification tests were performed isothermally in a magnetic suspension thermobalance and the reaction products were analyzed by a gas chromatograph with TCD/FID detectors. According to the characterization results, the samples presented higher carbon and lower volatile matter contents than the biomasses. Nevertheless, all of the materials had high calorific value. Syngas production was influenced by both temperature and steam partial pressure. Higher concentrations of H 2 and CO were found in the conversion range of 50-80% and higher concentrations of CO 2 in conversions around 10%, for all the gasified biochars. The H 2 /CO decreased with increasing temperature, mainly in kinetic control regime, in the lower temperature range. The results indicate the gasification potential of Brazilian biomass residues and are an initial and important step in the development of gasification processes in Brazil. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Development of a membrane-assisted fluidized bed reactor - 2 - Experimental demonstration and modeling for the partial oxidation of methanol

    NARCIS (Netherlands)

    Deshmukh, S.A.R.K.; Laverman, J.A.; van Sint Annaland, M.; Kuipers, J.A.M.

    2005-01-01

    A small laboratory-scale membrane-assisted fluidized bed reactor (MAFBR) was constructed in order to experimentally demonstrate the reactor concept for the partial oxidation of methanol to formaldehyde. Methanol conversion and product selectivities were measured at various overall fluidization

  16. Oxygen distribution in packed bed membrane reactors for partial oxidation systems and the effect on the product selectivity

    NARCIS (Netherlands)

    Kurten, U.; van Sint Annaland, M.; Kuipers, J.A.M.

    2004-01-01

    Packed bed membrane reactors (PBMRs) are currently considered for the distributive addition of oxygen in partial oxidation systems. Among other advantages the decreased oxygen concentrations in the PBMR can result in improved product selectivities for reaction systems in which the oxygen dependency

  17. Modeling and comparative assessment of bubbling fluidized bed gasification system for syngas production - a gateway for a cleaner future in Pakistan.

    Science.gov (United States)

    Shehzad, Areeb; Bashir, Mohammed J K; Horttanainen, Mika; Manttari, Mika; Havukainen, Jouni; Abbas, Ghulam

    2017-06-19

    The present study explores the potential of MSW gasification for exergy analysis and has been recently given a premier attention in a region like Pakistan where the urbanization is rapidly growing and resources are few. The plant capacity was set at 50 MW based on reference data available and the total exergetic efficiency was recorded to be 31.5 MW. The largest irreversibility distribution appears in the gasifier followed by methanation unit and CO 2 capture. The effect of process temperature, equivalence ratio and MSW moisture content was explored for inspecting the variations in syngas composition, lower heating value, carbon conversion efficiency and cold gas efficiency. Special attention of the paper is paid to the comparative assessment of MSW gasification products in four regions, namely Pakistan, USA, UAE and Thailand. This extended study gave an insight into the spectrum of socioeconomic conditions with varying MSW compositions in order to explain the effect of MSW composition variance on the gasification products.

  18. GASIFICATION FOR DISTRIBUTED GENERATION

    Energy Technology Data Exchange (ETDEWEB)

    Ronald C. Timpe; Michael D. Mann; Darren D. Schmidt

    2000-05-01

    evaluated through reactivity and product composition were carried out on thermogravimetric analysis (TGA) equipment. These tests were evaluated and then followed by bench-scale studies at 1123 K using an integrated bench-scale fluidized-bed gasifier (IBG) which can be operated in the semicontinuous batch mode. Products from tests were solid (ash), liquid (tar), and gas. Tar was separated on an open chromatographic column. Analysis of the gas product was carried out using on-line Fourier transform infrared spectroscopy (FT-IR). For selected tests, gas was collected periodically and analyzed using a refinery gas analyzer GC (gas chromatograph). The solid product was not extensively analyzed. This report is a part of a search into emerging gasification technologies that can provide power under 30 MW in a distributed generation setting. Larger-scale gasification has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries, and it is probable that scaled-down applications for use in remote areas will become viable. The appendix to this report contains a list, description, and sources of currently available gasification technologies that could be or are being commercially applied for distributed generation. This list was gathered from current sources and provides information about the supplier, the relative size range, and the status of the technology.

  19. Gasification of high ash, high ash fusion temperature bituminous coals

    Science.gov (United States)

    Liu, Guohai; Vimalchand, Pannalal; Peng, WanWang

    2015-11-13

    This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in 1150.degree. C. to 1500.degree. C. range as well as in excess of 1500.degree. C. In a preferred embodiment, such coals are dealt with a two stage gasification process--a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.

  20. Start-up and bacterial community compositions of partial nitrification in moving bed biofilm reactor.

    Science.gov (United States)

    Liu, Tao; Mao, Yan-Jun; Shi, Yan-Ping; Quan, Xie

    2017-03-01

    Partial nitrification (PN) has been considered as one of the promising processes for pretreatment of ammonium-rich wastewater. In this study, a kind of novel carriers with enhanced hydrophilicity and electrophilicity was implemented in a moving bed biofilm reactor (MBBR) to start up PN process. Results indicated that biofilm formation rate was higher on modified carriers. In comparison with the reactor filled with traditional carriers (start-up period of 21 days), it took only 14 days to start up PN successfully with ammonia removal efficiency and nitrite accumulation rate of 90 and 91%, respectively, in the reactor filled with modified carriers. Evident changes of spatial distributions and community structures had been detected during the start-up. Free-floating cells existed in planktonic sludge, while these microorganisms trended to form flocs in the biofilm. High-throughput pyrosequencing results indicated that Nitrosomonas was the predominant ammonia-oxidizing bacterium (AOB) in the PN system, while Comamonas might also play a vital role for nitrogen oxidation. Additionally, some other bacteria such as Ferruginibacter, Ottowia, Saprospiraceae, and Rhizobacter were selected to establish stable footholds. This study would be potentially significant for better understanding the microbial features and developing efficient strategies accordingly for MBBR-based PN operation.

  1. Second stage gasifier in staged gasification and integrated process

    Science.gov (United States)

    Liu, Guohai; Vimalchand, Pannalal; Peng, Wan Wang

    2015-10-06

    A second stage gasification unit in a staged gasification integrated process flow scheme and operating methods are disclosed to gasify a wide range of low reactivity fuels. The inclusion of second stage gasification unit operating at high temperatures closer to ash fusion temperatures in the bed provides sufficient flexibility in unit configurations, operating conditions and methods to achieve an overall carbon conversion of over 95% for low reactivity materials such as bituminous and anthracite coals, petroleum residues and coke. The second stage gasification unit includes a stationary fluidized bed gasifier operating with a sufficiently turbulent bed of predefined inert bed material with lean char carbon content. The second stage gasifier fluidized bed is operated at relatively high temperatures up to 1400.degree. C. Steam and oxidant mixture can be injected to further increase the freeboard region operating temperature in the range of approximately from 50 to 100.degree. C. above the bed temperature.

  2. FY 1992 report on the results of the development of an entrained bed coal gasification power plant. Part 1. Element study/Technical survey; 1992 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 1. Youso kenkyu hen, gijutsu chosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-02-01

    For the purpose of establishing the technology of the integrated coal gasification combined cycle power generation, element study of a 200 t/d entrained bed coal gasification pilot plant was made, and the FY 1992 results were summarized. In the gasification test using a 2 t/d furnace equipment, study was made of the extraction of subjects on the operation, performance of gasification, slagging characteristics and characteristics of flux addition. In the study of slag utilization technology, chemical analysis, test on fine aggregate and test on fine particle were carried out to study applicability of the slag discharged from the entrained bed coal gasification power plant to various materials. In the study of a large gas turbine combustor for the demonstrative machine, the demonstrative machine use large gas turbine combustor testing equipment was installed at actual pressure/actual size combustion testing facilities in the pilot plant and further the test use combustor was integrated into them. By using them, the real gas combustion test was made using the adjusted coal for evaluation of combustion performance of the test use combustor. In the simulation study of the total pilot plant system, the comparative study was made between the data on the test using the actual machine and the results of the simulation. (NEDO)

  3. Effect of partial replacement of diesel or biodiesel with gas from biomass gasification in a diesel engine

    International Nuclear Information System (INIS)

    Hernández, J.J.; Lapuerta, M.; Barba, J.

    2015-01-01

    The injected diesel fuel used in a diesel engine was partially replaced with biomass-derived gas through the intake port, and the effect on performance and pollutant emissions was studied. The experimental work was carried out in a supercharged, common-rail injection, single-cylinder diesel engine by replacing diesel fuel up to 20% (by energy), keeping constant the engine power. Three engine loads (60, 90, 105 Nm), three different EGR (exhaust gas recirculation) ratios (0, 7.5, 15%) and two intake temperatures (45, 60 °C) were tested. Finally, some of the tested conditions were selected to replace diesel injection fuel with biodiesel injection. Although the brake thermal efficiency was decreased and hydrocarbons and carbon monoxide emissions increased with increasing fuel replacement, particulate emissions decreased significantly and NO x emissions decreased slightly at all loads and EGR ratios. Thermodynamic diagnostic results showed higher premixed ratio and lower combustion duration for increasing diesel fuel replacement. High EGR ratios improved both engine performance and emissions, especially when intake temperature was increased, which suggest removing EGR cooling when diesel fuel is replaced. Finally, when biodiesel was used instead of diesel fuel, the gas replacement improved the efficiency and reduced the hydrocarbon, carbon monoxide and particulate emissions. - Highlights: • Replacing injected fuel with gas permits an efficient valorization of waste biomass. • Inlet gas was inefficiently burned after the end of liquid fuel injection. • Engine parameters were combined to simultaneously reduce particle and NO x emissions. • Hot EGR (exhaust gas recirculation) and biodiesel injection are proposed to improve efficiency and emissions

  4. FY 1996 report on the results of the development of an entrained bed coal gasification power plant. Part 2. Investigational study of verification plant; 1995 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 2. Jissho plant ni kansuru chosa kenkyu hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-01-01

    For the purpose of developing the technology of the integrated coal gasification combined cycle power generation, an investigational study of verification plant was made, and the FY 1996 results were summarized. In this fiscal year, the conceptual design was made of the Nakoso method based on the method of Nakoso pilot plant, the fixed bed method in which fixed bed gas refining facilities tested in Nakoso pilot plant were adopted, and the packed bed method. In the Nakoso method, 5 cases were studied using the air blown two-stage entrained bed for gasifier, dry two-stage fluidized bed for desulfurization and dry granular bed packed bed for dust removal. In the fixed bed method, 2 cases were studied using the air blown two-stage entrained bed for gasifier and dry fixed bed for gas refining. In the packed bed method, 2 cases were studied using the air blown two-stage entrained bed for gasifier and dry packed bed for gas refining. As to gas turbine facilities, 5 cases were studied in which GT output is 115MW - 215MW (output of combined cycle power generation: 220MW - 420MW). (NEDO)

  5. Catalytic gasification of automotive shredder residues with hydrogen generation

    Science.gov (United States)

    Lin, Kuen-Song; Chowdhury, Sujan; Wang, Ze-Ping

    Hydrogen is a clean and new energy carrier to generate power through the Proton exchange membrane fuel cell (PEMFC) system. Hydrogen can be effectively turned out through the catalytic gasification of organic material such as automotive shredder residues (ASR). The main objective of this manuscript is to present an analysis of the catalytic gasification of ASR for the generation of high-purity hydrogen in a lab-scale fixed-bed downdraft gasifier using 15 wt.% NiO/Al 2O 3 catalysts at 760-900 K. In the catalytic gasification process, reduction of Ni(II) catalyst into Ni(0) has been confirmed through XANES spectra and consequently EXAFS data shows that the central Ni atoms have Ni-O and Ni-Ni bonds with bond distances of 2.03 ± 0.05 and 2.46 ± 0.05 Å, respectively. ASR is partially oxidized and ultimately converts into hydrogen rich syngas (CO and H 2) and increases of the reaction temperature are favored the generation of hydrogen with decomposition of the CO. As well, approximately 220 kg h -1 of ASR would be catalytically gasified at 760-900 K and 46.2 atm with the reactor volume 0.27 m 3 to obtain approximately 3.42 × 10 5 kcal h -1 of thermal energy during over 87% syngas generation with the generation of 100 kW electric powers.

  6. Membrane assisted fluidized bed reactor: experimental demonstration for partial oxidation of methanol

    NARCIS (Netherlands)

    Deshmukh, S.A.R.K.

    2004-01-01

    In this thesis the reactor concept has been developed on the basis of an experimental study on the effect of fluidization conditions on the membrane permeation rate in a MAFBR, the extent of gas back mixing and the tube-to-bed heat transfer rates in the presence of membrane bundles with and without

  7. Effect of a Reactivation strategy based on partial bio catalyst replacement on the performance of a fungal fluidized bed bioreactor

    International Nuclear Information System (INIS)

    Ortega-Clemente, A.; Robledo-Narvaez, P.; Barrera-Cortes, J.; Poggi-Varaldo, H. M.

    2009-01-01

    The Mexican pulp and paper industry discharges approximately 12% of the annual industrial discharges and holds a second position in the ranking of main water industrial polluters in Mexico. Their wastewaters are characteristically recalcitrant and toxic. The objective of this work was to evaluate the effectiveness of two operational strategies on the performance of two fungal fluidized bed reactor (FBR) for the post-treatment of anaerobically weal black liquor systems (AP-WBL) without supplementation of soluble carbohydrates, i. e. Strategy 1 (continuous operation with the same original, fungal bio catalysts and eventual spikes of protease inhibitor and glucose), and Strategy 2 operation with partial exchange of bio catalysts. (Author)

  8. Techno Economic Analysis of Hydrogen Production by gasification of biomass

    Energy Technology Data Exchange (ETDEWEB)

    Francis Lau

    2002-12-01

    Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more

  9. Biomass gasification for energy production

    Energy Technology Data Exchange (ETDEWEB)

    Lundberg, H.; Morris, M.; Rensfelt, E. [TPS Termiska Prosesser Ab, Nykoeping (Sweden)

    1997-12-31

    Biomass and waste are becoming increasingly interesting as fuels for efficient and environmentally sound power generation. Circulating fluidized bed (CFB) gasification for biomass and waste has been developed and applied to kilns both in the pulp and paper industry and the cement industry. A demonstration plant in Greve-in- Chianti, Italy includes two 15 MW{sub t}h RDF-fuelled CFB gasifiers of TPS design, the product gas from which is used in a cement kiln or in steam boiler for power generation. For CFB gasification of biomass and waste to reach a wider market, the product gas has to be cleaned effectively so that higher fuel to power efficiencies can be achieved by utilizing power cycles based on engines or gas turbines. TPS has developed both CFB gasification technology and effective secondary stage tar cracking technology. The integrated gasification - gas-cleaning technology is demonstrated today at pilot plant scale. To commercialise the technology, the TPS`s strategy is to first demonstrate the process for relatively clean fuels such as woody biomass and then extend the application to residues from waste recycling. Several demonstration projects are underway to commercialise TPS`s gasification and gas cleaning technology. In UK the ARBRE project developed by ARBRE Energy will construct a gasification plant at Eggborough, North Yorkshire, which will provide gas to a gas turbine and steam turbine generation system, producing 10 MW and exporting 8 Mw of electricity. It has been included in the 1993 tranche of the UK`s Non Fossil Fuel Obligation (NFFO) and has gained financial support from EC`s THERMIE programme as a targeted BIGCC project. (author)

  10. First Partial Skeleton of a 1.34-Million-Year-Old Paranthropus boisei from Bed II, Olduvai Gorge, Tanzania

    Science.gov (United States)

    Domínguez-Rodrigo, Manuel; Pickering, Travis Rayne; Baquedano, Enrique; Mabulla, Audax; Mark, Darren F.; Musiba, Charles; Bunn, Henry T.; Uribelarrea, David; Smith, Victoria; Diez-Martin, Fernando; Pérez-González, Alfredo; Sánchez, Policarpo; Santonja, Manuel; Barboni, Doris; Gidna, Agness; Ashley, Gail; Yravedra, José; Heaton, Jason L.; Arriaza, Maria Carmen

    2013-01-01

    Recent excavations in Level 4 at BK (Bed II, Olduvai Gorge, Tanzania) have yielded nine hominin teeth, a distal humerus fragment, a proximal radius with much of its shaft, a femur shaft, and a tibia shaft fragment (cataloged collectively as OH 80). Those elements identified more specifically than to simply Hominidae gen. et sp. indet are attributed to Paranthropus boisei. Before this study, incontrovertible P. boisei partial skeletons, for which postcranial remains occurred in association with taxonomically diagnostic craniodental remains, were unknown. Thus, OH 80 stands as the first unambiguous, dentally associated Paranthropus partial skeleton from East Africa. The morphology and size of its constituent parts suggest that the fossils derived from an extremely robust individual who, at 1.338±0.024 Ma (1 sigma), represents one of the most recent occurrences of Paranthropus before its extinction in East Africa. PMID:24339873

  11. First partial skeleton of a 1.34-million-year-old Paranthropus boisei from Bed II, Olduvai Gorge, Tanzania.

    Directory of Open Access Journals (Sweden)

    Manuel Domínguez-Rodrigo

    Full Text Available Recent excavations in Level 4 at BK (Bed II, Olduvai Gorge, Tanzania have yielded nine hominin teeth, a distal humerus fragment, a proximal radius with much of its shaft, a femur shaft, and a tibia shaft fragment (cataloged collectively as OH 80. Those elements identified more specifically than to simply Hominidae gen. et sp. indet are attributed to Paranthropus boisei. Before this study, incontrovertible P. boisei partial skeletons, for which postcranial remains occurred in association with taxonomically diagnostic craniodental remains, were unknown. Thus, OH 80 stands as the first unambiguous, dentally associated Paranthropus partial skeleton from East Africa. The morphology and size of its constituent parts suggest that the fossils derived from an extremely robust individual who, at 1.338±0.024 Ma (1 sigma, represents one of the most recent occurrences of Paranthropus before its extinction in East Africa.

  12. First partial skeleton of a 1.34-million-year-old Paranthropus boisei from Bed II, Olduvai Gorge, Tanzania.

    Science.gov (United States)

    Domínguez-Rodrigo, Manuel; Pickering, Travis Rayne; Baquedano, Enrique; Mabulla, Audax; Mark, Darren F; Musiba, Charles; Bunn, Henry T; Uribelarrea, David; Smith, Victoria; Diez-Martin, Fernando; Pérez-González, Alfredo; Sánchez, Policarpo; Santonja, Manuel; Barboni, Doris; Gidna, Agness; Ashley, Gail; Yravedra, José; Heaton, Jason L; Arriaza, Maria Carmen

    2013-01-01

    Recent excavations in Level 4 at BK (Bed II, Olduvai Gorge, Tanzania) have yielded nine hominin teeth, a distal humerus fragment, a proximal radius with much of its shaft, a femur shaft, and a tibia shaft fragment (cataloged collectively as OH 80). Those elements identified more specifically than to simply Hominidae gen. et sp. indet are attributed to Paranthropus boisei. Before this study, incontrovertible P. boisei partial skeletons, for which postcranial remains occurred in association with taxonomically diagnostic craniodental remains, were unknown. Thus, OH 80 stands as the first unambiguous, dentally associated Paranthropus partial skeleton from East Africa. The morphology and size of its constituent parts suggest that the fossils derived from an extremely robust individual who, at 1.338±0.024 Ma (1 sigma), represents one of the most recent occurrences of Paranthropus before its extinction in East Africa.

  13. Co-gasification of sewage sludge and woody biomass in a fixed-bed downdraft gasifier: toxicity assessment of solid residues.

    Science.gov (United States)

    Rong, Le; Maneerung, Thawatchai; Ng, Jingwen Charmaine; Neoh, Koon Gee; Bay, Boon Huat; Tong, Yen Wah; Dai, Yanjun; Wang, Chi-Hwa

    2015-02-01

    As the demand for fossil fuels and biofuels increases, the volume of ash generated will correspondingly increase. Even though ash disposal is now strictly regulated in many countries, the increasing volume of ash puts pressure on landfill sites with regard to cost, capacity and maintenance. In addition, the probability of environmental pollution from leakage of bottom ash leachate also increases. The main aim of this research is to investigate the toxicity of bottom ash, which is an unavoidable solid residue arising from biomass gasification, on human cells in vitro. Two human cell lines i.e. HepG2 (liver cell) and MRC-5 (lung fibroblast) were used to study the toxicity of the bottom ash as the toxins in the bottom ash may enter blood circulation by drinking the contaminated water or eating the food grown in bottom ash-contaminated water/soil and the toxic compounds may be carried all over the human body including to important organs such as lung, liver, kidney, and heart. It was found that the bottom ash extract has a high basicity (pH = 9.8-12.2) and a high ionic strength, due to the presence of alkali and alkaline earth metals e.g. K, Na, Ca and Mg. Moreover, it also contains concentrations of heavy metals (e.g. Zn, Co, Cu, Fe, Mn, Ni and Mo) and non-toxic organic compounds. Although human beings require these trace elements, excessive levels can be damaging to the body. From the analyses of cell viability (using MTS assay) and morphology (using fluorescence microscope), the high toxicity of the gasification bottom ash extract could be related to effects of high ionic strength, heavy metals or a combination of these two effects. Therefore, our results suggest that the improper disposal of the bottom ash wastes arising from gasification can create potential risks to human health and, thus, it has become a matter of urgency to find alternative options for the disposal of bottom ash wastes. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. Coal gasification in Europe

    International Nuclear Information System (INIS)

    Furfari, S.

    1992-01-01

    This paper first analyzes European energy consumption and supply dynamics within the framework of the European Communities energy and environmental policies calling for the increased use of natural gas, reduced energy consumption, promotion of innovative renewable energy technologies, and the reduction of carbon dioxide emissions. This analysis evidences that, while, at present, the increased use of natural gas is an economically and environmentally advantageous policy, as well as, being strategically sound (in view of Middle East political instability), fuel interchangeability, in particular, the option to use coal, is vital to ensure stability of the currently favourable natural gas prices and offer a locally available energy alternative to foreign supplied sources. Citing the advantages to industry offered by the use of flexible, efficient and clean gaseous fuels, with interchangeability, the paper then illustrates the cost and environmental benefits to be had through the use of high efficiency, low polluting integrated gasification combined-cycle power plants equipped to run on a variety of fuels. In the assessment of technological innovations in this sector, a review is made of some of the commercially most promising gasification processes, e.g., the British Gas-Lurgi (BGL) slagging gasifier, the high-temperature Winkler (HTW) Rheinbraun, and the Krupp Koppers (PRENFLO) moving bed gasifier processes

  15. MHD power station with coal gasification

    International Nuclear Information System (INIS)

    Brzozowski, W.S.; Dul, J.; Pudlik, W.

    1976-01-01

    A description is given of the proposed operating method of a MHD-power station including a complete coal gasification into lean gas with a simultaneous partial gas production for the use of outside consumers. A comparison with coal gasification methods actually being used and full capabilities of power stations heated with coal-derived gas shows distinct advantages resulting from applying the method of coal gasification with waste heat from MHD generators working within the boundaries of the thermal-electric power station. (author)

  16. Report on the results of the R and D of a 200 t/d entrained bed coal gasification pilot plant. Summary - Part 2. Volume 3: Results of the study operation and the evaluation; 1986- 200t/nichi funryusho sekitan gaska hatsuden pilot plant no kenkyu seika hokokusho (Matome). Sono 2. Dai 3 hen kenkyu unten seika to sono hyoka

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-01-01

    A project was finished which had been carried out for 11 years since 1986 for technology of the entrained bed coal gasification power generation technology using a 200 t/d coal gasification combined cycle power generation pilot plant, and it was comprehensively summed up. In Volume 3: Results of the study operation and the evaluation, the following were summarized on gasifier: gasification performance of 200 t/d furnace, operation ability of the bituminous coal supply system, stability of char recovery, deposition of slag and char in furnace, discharge characteristics of molten slag, operation characteristics, etc. The following on gas refining facilities: dry desulfurizer, dust remover, new gas refining equipment (fixed bed dust removal/desulfurization system, packed bed desulfuriztion/dust removal system), etc. The following on gas turbine facilities: 12.5 MW gas turbine, large gas turbine, large gas turbine combustor, etc. Additionally, the paper summarized the control system and total function, operation characteristics of the whole pilot plant, relations of environmental preservation, study of the effective slag utilization, collection/study of unfavorable conditions/troubles and matters for the reflection, etc. (NEDO)

  17. Syngas yield during pyrolysis and steam gasification of paper

    International Nuclear Information System (INIS)

    Ahmed, I.; Gupta, A.K.

    2009-01-01

    Main characteristics of gaseous yield from steam gasification have been investigated experimentally. Results of steam gasification have been compared to that of pyrolysis. The temperature range investigated were 600-1000 °C in steps of 100 °C. Results have been obtained under pyrolysis conditions at same temperatures. For steam gasification runs, steam flow rate was kept constant at 8.0 g/min. Investigated characteristics were evolution of syngas flow rate with time, hydrogen flow rate and chemical composition of syngas, energy yield and apparent thermal efficiency. Residuals from both processes were quantified and compared as well. Material destruction, hydrogen yield and energy yield is better with gasification as compared to pyrolysis. This advantage of the gasification process is attributed mainly to char gasification process. Char gasification is found to be more sensitive to the reactor temperature than pyrolysis. Pyrolysis can start at low temperatures of 400 °C; however char gasification starts at 700 °C. A partial overlap between gasification and pyrolysis exists and is presented here. This partial overlap increases with increase in temperature. As an example, at reactor temperature 800 °C this overlap represents around 27% of the char gasification process and almost 95% at reactor temperature 1000 °C.

  18. Air-gasification of corncobs at fluidization

    Energy Technology Data Exchange (ETDEWEB)

    Hongming Jiang; Morey, R.V. (Minnesota Univ., St. Paul, MN (United States). Dept. of Agricultural Engineering)

    1992-01-01

    Self-sustained air gasification of corncobs was conducted using a gasifier-combustor system to provide data for validating a numerical gasifier model. The performance of the gasifier was analyzed with test results obtained at two bed temperatures (920 and 1050 K). (author).

  19. Estudio mecánico e hidrodinámico de un reactor de gasificación de lecho fluidizado. // Mechanic and hydrodynamic study of a fluidized bed gasification reactor.

    Directory of Open Access Journals (Sweden)

    W. Rosales

    2008-01-01

    Full Text Available Se realizó una simulación mediante Elementos Finitos y CFD de un prototipo de gasificador experimental a partir de unageometría propuesta. Se abordan aspectos termomecánicos, al calcularse las deformaciones originadas en el equipo,producto de su peso, en las condiciones de emplazamiento y la carga térmica a la que se somete. También se considera elflujo multifásico gas-sólido presente en el lecho fluidizado, se determina el rango de presiones y velocidades de trabajo deldispositivo, y se estudia la evolución del flujo. Para ello se utiliza el modelo de fuerza de arrastre y presión de sólido deGidaspow, así como los criterios de velocidad mínima de fluidización de Wen & Yu y Kunii & Levenspiel.Palabras claves: Gasificación, lecho fluidizado, CFD, FEM, flujo multifásico.______________________________________________________________________________Abstract.A Finite Element and CFD simulations were conducted to a prototype of experimental gasifier, starting from a proposedgeometry. Thermomechanic aspects are briefed, calculating the reactor deformation, due to its weight and the thermic load.The gas-solid multiphase flow, present on the fluidized bed was also considered, the working range for the pressure andvelocity fields were determined and the flow evolution was studied. The drag force and solid pressure models byGidaspow, and the minimum fluidization velocity criteria, by Wen & Yu and Kunii & Levenspiel were used.Key words: gasification, fluidized bed, CFD, Finite Element, Multiphase Flow.

  20. Mathematical Modelling of Coal Gasification Processes

    Science.gov (United States)

    Sundararajan, T.; Raghavan, V.; Ajilkumar, A.; Vijay Kumar, K.

    2017-07-01

    Coal is by far the most commonly employed fuel for electrical power generation around the world. While combustion could be the route for coal utilization for high grade coals, gasification becomes the preferred process for low grade coals having higher composition of volatiles or ash. Indian coals suffer from high ash content-nearly 50% by weight in some cases. Instead of transporting such high ash coals, it is more energy efficient to gasify the coal and transport the product syngas. Integrated Gasification Combined Cycle (IGCC) plants and Underground Gasification of coal have become attractive technologies for the best utilization of high ash coals. Gasification could be achieved in fixed beds, fluidized beds and entrained beds; faster rates of gasification are possible in fluidized beds and entrained flow systems, because of the small particle sizes and higher gas velocities. The media employed for gasification could involve air/oxygen and steam. Use of oxygen will yield relatively higher calorific value syngas because of the absence of nitrogen. Sequestration of the carbon dioxide after the combustion of the syngas is also easier, if oxygen is used for gasification. Addition of steam can increase hydrogen yield in the syngas and thereby increase the calorific value also. Gasification in the presence of suitable catalysts can increase the composition of methane in the product gas. Several competing heterogenous and homogenous reactions occur during coal major heterogenous reaction pathways, while interactions between carbon monoxide, oxygen, hydrogen, water vapour, methane and carbon dioxide result in several simultaneous gas-phase (homogenous) reactions. The overall product composition of the coal gasification process depends on the input reactant composition, particle size and type of gasifier, and pressure and temperature of the gasifier. The use of catalysts can also selectively change the product composition. At IIT Madras, over the last one decade, both

  1. Pyrolysis and Gasification

    DEFF Research Database (Denmark)

    Astrup, Thomas; Bilitewski, B.

    2011-01-01

    Pyrolysis and gasification include processes that thermally convert carbonaceous materials into products such as gas, char, coke, ash, and tar. Overall, pyrolysis generates products like gas, tar, and char, while gasification converts the carboncontaining materials (e.g. the outputs from pyrolysis...... may often be described as gasification only. Pyrolysis, however, can also be employed without proceeding with gasification. Gasification is by no means a novel process; in the 19th century so-called ‘town gas’ was produced by the gasification of coal and for example used for illumination purposes....... In Europe during World War II, wood-fueled gasifiers (or ‘gas generators’) were used to power cars during shortages of oil-based fuels. Sparked by oil price crises in 1970s and 1980s, further development in gasification technologies focused mainly on coal as a fuel to substitute for oil-based products...

  2. Effect of Mass-Transport Limitations on the Performance of a Packed Bed Membrane Reactor for Partial Oxidations. Intraparticle Mass Transport

    NARCIS (Netherlands)

    van Sint Annaland, M.; Kurten, U.; Kuipers, J.A.M.

    2007-01-01

    For partial oxidation systems, where the reaction order in oxygen of the formation rate of the target product is smaller than the reaction order in oxygen of the consecutive reaction rate toward the waste product, a packed bed membrane reactor can be applied to distributively dose oxygen along the

  3. Straw Gasification in a Two-Stage Gasifier

    DEFF Research Database (Denmark)

    Bentzen, Jens Dall; Hindsgaul, Claus; Henriksen, Ulrik Birk

    2002-01-01

    Additive-prepared straw pellets were gasified in the 100 kW two-stage gasifier at The Department of Mechanical Engineering of the Technical University of Denmark (DTU). The fixed bed temperature range was 800-1000°C. In order to avoid bed sintering, as observed earlier with straw gasification...

  4. Staged catalytic gasification/steam reforming of pyrolysis oil

    NARCIS (Netherlands)

    van Rossum, G.; Kersten, Sascha R.A.; van Swaaij, Willibrordus Petrus Maria

    2009-01-01

    Gasification/steam reforming of pyrolysis oil was studied in a staged reactor concept, which consisted of an inert fluidized bed and a catalytic fixed bed. Methane and C2−C3 free syngas is produced at a single temperature around 800 °C at atmospheric pressure. By lowering the temperature of the

  5. CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES; FINAL

    International Nuclear Information System (INIS)

    Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

    2001-01-01

    The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO(sub x)). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process

  6. CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

    2001-12-01

    The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

  7. Catalytic Gasification of Lignocellulosic Biomass

    NARCIS (Netherlands)

    Chodimella, Pramod; Seshan, Kulathuiyer; Schlaf, Marcel; Zhang, Z. Conrad

    2015-01-01

    Gasification of lignocellulosic biomass has attracted substantial current research interest. Various possible routes to convert biomass to fuels have been explored. In the present chapter, an overview of the gasification processes and their possible products are discussed. Gasification of solid

  8. International Seminar on Gasification 2008

    Energy Technology Data Exchange (ETDEWEB)

    Held, Joergen (ed.)

    2008-11-15

    results in a product gas free of nitrogen and hence suitable for production of biomethane. The concept has been proven at the Guessing plant using a slip-stream but still we are awaiting the first commercial plant that produce biomethane suitable as vehicle fuel or for grid injection. Several demonstration projects are related to air-blown gasification and CHP production. The two-stage Viking gasifier developed at Technical University of Denmark produces a gas with low tar content (<5 mg/Nm3) suitable for combined heat and power production where a gas engine is used for the electricity production. The 70 kW{sub th} pilot plant has an electric efficiency of 25 %. With a scale-up to 0.2-2 MW{sub e} and improved internal heat recovery an electric efficiency of >37 % is expected. In Skive, Denmark, biomass gasification in a 20 MW{sub th} gasifier based on technology developed at GTI, USA and commercialized by Carbona, Finland is demonstrated. The total investment cost is 30 million Euro. Expected pay-back time is approx. 10 years. The project is delayed and the official opening is planned to April 2009. The delay reflects the inherent uncertainty related to large-scale demonstration of new technology. There are several other demonstrations related to biomass gasification and gas cleaning on their way and the field of gasification seems to experience a renaissance. Gas engines utilizing gasified biomass are commercially available. GE Jenbacher has installed gas engines in many biomass gasification plants in Europe. The accumulated hours of operation for the gas engines well exceed 100,000 hours. The plants with installed gas engines span over different gasification technologies (e.g. fixed bed - updraft, fixed bed - down draft and indirect gasification) and different gas compositions with lower heating values ranging from 5.4 MJ/Nm3 to 10.5 MJ/Nm3. High CO content in the gas results in high CO emissions from the gas engine which calls for exhaust gas after-treatment. To avoid

  9. Gasification of secondary fuels in a circulating fluidized bed for energetic use in cement production; Vergasung von Sekundaerbrennstoffen in der zirkulierenden Wirbelschicht zur energetischen Nutzung fuer die Zementherstellung

    Energy Technology Data Exchange (ETDEWEB)

    Albrecht, J.; Gafron, B. [Lurgi Umwelt GmbH, Frankfurt am Main (Germany); Scur, P.; Wirthwein, R. [Ruedersdorfer Zement GmbH (Germany)

    1998-09-01

    Ruedersforf cement factory was commissioned a century ago as one of the first in Germany. After the plant was taken over by Readymix AG, a comprehensive sanitation concept was carried through. The plant has a production capacity of 8000 t/d of cement clinkers which are produced in a new kiln with a capacity of 6000 t/d and two modernized kilns each with a capacity of 1000 t/d. Reduction of energy consumption was the main goal of modernisation, with fuel gas generation in a circulating fluidized bed as a key element. The unit provides 40 % of the energy consumed by the clinker production process and is also used for selective ash production up to 25 t/h. The ash is used as a raw material for cement production. (orig./SR) [Deutsch] Bereits vor 100 Jahren wurde eine der ersten Zementfabriken in Deutschland am Standort Ruedersdorf in Betrieb genommen. Zum Erhalt der Wettbewerbsfaehigkeit wurde nach der Uebernahme des Werkes Ruedersdorf durch die Readymix AG ein umfangreiches Sanierungskonzept in die Wege geleitet. Bei einer Produktionskapazitaet von ca. 8 000 t Klinker pro Tag werden eine neue Ofenanlage mit einer Kapazitaet von 6 000 t/Tag sowie 2 sanierte kleine Anlagen zu je 1000 t/Tag betrieben. In der neuen Ofenanlage werden alle Moeglichkeiten genutzt, den Energiebedarf fuer die Klinkerproduktion zu senken. Eine wesentliche neue innovative Komponente ist dabei eine Brenngaserzeugung in einer Zirkulierenden Wirbelschicht, ueber die im folgenden berichtet werden soll. Die Anlage kann bis zu 40% des Energiebedarfes des Zementprozesses liefern. Weiterhin wird mit der ZWS eine gezielte Ascheproduktion, bis zu 25 t/h, betrieben. Diese Aschen sind Teil der Rohstoffrezeptur an der Rohmuehle. (orig./SR)

  10. Gasification of Woody Biomass.

    Science.gov (United States)

    Dai, Jianjun; Saayman, Jean; Grace, John R; Ellis, Naoko

    2015-01-01

    Interest in biomass to produce heat, power, liquid fuels, hydrogen, and value-added chemicals with reduced greenhouse gas emissions is increasing worldwide. Gasification is becoming a promising technology for biomass utilization with a positive environmental impact. This review focuses specifically on woody biomass gasification and recent advances in the field. The physical properties, chemical structure, and composition of biomass greatly affect gasification performance, pretreatment, and handling. Primary and secondary catalysts are of key importance to improve the conversion and cracking of tars, and lime-enhanced gasification advantageously combines CO2 capture with gasification. These topics are covered here, including the reaction mechanisms and biomass characterization. Experimental research and industrial experience are investigated to elucidate concepts, processes, and characteristics of woody biomass gasification and to identify challenges.

  11. Biomass utilization for the process of gasification

    Directory of Open Access Journals (Sweden)

    Josef Spěvák

    2008-01-01

    Full Text Available Biomass as one of the renewable resources of energy has bright future in utilization, especially in obtaining various forms of energy (heat, electrical energy, gas.According to the conception of energy policy of the Czech Republic and according to the fulfillment of the indicators of renewable resources using until the year 2010, the research of thermophysical characteristics of biofuels was realized.There were acquired considerable amount of results by combustion and gasification process on the basis of three-year project „Biomass energy parameters.” By means of combustion and gasification tests of various (biomass fuels were acquired the results which were not published so far.Acquired results are published in the fuel sheets, which are divided into four parts. They consist of information on fuel composition, ash composition, testing conditions and measurand overview. Measurements were realized for the process of combustion, fluidized-bed gasification and fixed-bed gasification. Following fuels were tested: Acacia, Pine, Birch, Beech, Spruce, Poplar, Willow, Rape, Amaranth, Corn, Flax, Wheat, Safflower, Mallow, and Sorrel.

  12. FY 1990 report on the results of the development of the entrained bed coal gasification power plant. Part 2. Fabrication/installation of pilot plant; 1990 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 2. Pilot plant seisaku suetsuke hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    For the purpose of establishing the technology of the integrated coal gasification combined cycle power generation, fabrication/installation work, etc. were made for a pilot plant of 200t/d entrained bed coal gasification power generation, and the FY 1990 results were summarized. Construction work of a pilot plant of coal gasification power generation was at its peak in April 1990, and installation/piping work for each facility/equipment was carried out. In May, transportation/installation of gas turbine and generator were started. In June, installation of equipment of the 66kV special high voltage switching station was conducted, and the initial power receiving of 6.9kV was conducted. In August, inspection before use was made of the main piping of the gasifier equipment, gas refining equipment and gas turbine equipment. In December, trial unit operation of each equipment and interlock test were carried out. 'The integrated plant protection interlock test' was made from January 21 to February 21, 1991, and the favorable results were obtained. On February 28, a ceremony to celebrate the completion of all facilities of pilot plant was made. In March, drying of gasifier and initial firing by light oil were conducted, and all the work was completed on March 25. (NEDO)

  13. Radiative Gasification Apparatus

    Data.gov (United States)

    Federal Laboratory Consortium — This apparatus, developed at EL, determines gasification rate (mass loss rate) of a horizontally oriented specimen exposed in a nitrogen environment to a controlled...

  14. Italian experience in gasification plants

    International Nuclear Information System (INIS)

    Rinaldi, N.U.

    1991-01-01

    After tracing the historical highlights representing the development of the Fauser (Montecatini) technology based gasification processes for the production of ammonia and methanol, this paper outlines the key design, operation and performance characteristics of the Montecatini (Italy) process plant for heavy liquid hydrocarbons gasification by means of partial auto-thermal combustion with oxygen. The outline makes evident the technical-economical validity of the Montecatini design solutions which include energy recovery (even the heat dispersed through the gasifier walls is recovered and utilized to produce low pressure steam to preheat the fuel oil); reduced oxygen consumption by the high temperature preheating of all reagents; the ecologically compatible elimination of gas black; as well as, desulfurization with materials recovery. The plant process descriptions come complete with flowsheets. While demonstrating that the Italian developed technology is historically well rooted, the Author stresses that the current design versions of Montecatini gasification plants are up to date with innovative solutions, especially, with regard to pollution abatement, and cites the need for a more concerted marketing effort on the part of local industry to help improve the competitiveness of the Italian made product

  15. On the gasification of biomass in a steam-oxygen blown CFB gasifier with the focus on gas quality upgrading : Technology background, experiments and mathematical modeling

    NARCIS (Netherlands)

    Siedlecki, M.

    2011-01-01

    This work presents and discusses the results of the research on the gasification of biomass in an atmospheric circulating fluidized bed, with a mixture of steam and oxygen as fluidization / gasification medium. The main objectives of this research were to investigate and improve the gasification

  16. Axial Changes of Catalyst Structure and Temperature in a Fixed-Bed Microreactor During Noble Metal Catalysed Partial Oxidation of Methane

    DEFF Research Database (Denmark)

    Hannemann, S.; Grunwaldt, Jan-Dierk; Kimmerle, B.

    2009-01-01

    The catalytic partial oxidation of methane (CPO) over flame-made 2.5%Rh-2.5%Pt/Al2O3 and 2.5%Rh/Al2O3 in 6%CH4/3%O-2/He shows the potential of in situ studies using miniaturized fixed-bed reactors, the importance of spatially resolved studies and its combination with infrared thermography and on......-line mass spectrometry. This experimental strategy allowed collecting data on the structure of the noble metal (oxidation state) and the temperature along the catalyst bed. The reaction was investigated in a fixed-bed quartz microreactor (1-1.5 mm diameter) following the catalytic performance by on-line gas...... mass spectrometry (MS). Above the ignition temperature of the catalytic partial oxidation of methane (310-330 A degrees C), a zone with oxidized noble metals was observed in the inlet region of the catalyst bed, accompanied by a characteristic hot spot (over-temperature up to 150 A degrees C), while...

  17. Investigation of Gas Solid Fluidized Bed Dynamics with Non-Spherical Particles

    Energy Technology Data Exchange (ETDEWEB)

    Choudhuri, Ahsan [Univ. of Texas, El Paso, TX (United States). Dept. of Mechanical Engineering

    2013-06-30

    One of the largest challenges for 21st century is to fulfill global energy demand while also reducing detrimental impacts of energy generation and use on the environment. Gasification is a promising technology to meet the requirement of reduced emissions without compromising performance. Coal gasification is not an incinerating process; rather than burning coal completely a partial combustion takes place in the presence of steam and limited amounts of oxygen. In this controlled environment, a chemical reaction takes place to produce a mixture of clean synthetic gas. Gas-solid fluidized bed is one such type of gasification technology. During gasification, the mixing behavior of solid (coal) and gas and their flow patterns can be very complicated to understand. Many attempts have taken place in laboratory scale to understand bed hydrodynamics with spherical particles though in actual applications with coal, the particles are non-spherical. This issue drove the documented attempt presented here to investigate fluidized bed behavior using different ranges of non-spherical particles, as well as spherical. For this investigation, various parameters are controlled that included particle size, bed height, bed diameter and particle shape. Particles ranged from 355 µm to 1180 µm, bed diameter varied from 2 cm to 7 cm, two fluidized beds with diameters of 3.4 cm and 12.4 cm, for the spherical and non-spherical shaped particles that were taken into consideration. Pressure drop was measured with increasing superficial gas velocity. The velocity required in order to start to fluidize the particle is called the minimum fluidization velocity, which is one of the most important parameters to design and optimize within a gas-solid fluidized bed. This minimum fluidization velocity was monitored during investigation while observing variables factors and their effect on this velocity. From our investigation, it has been found that minimum fluidization velocity is independent of bed

  18. Updraft gasification of salmon processing waste.

    Science.gov (United States)

    Rowland, Sarah; Bower, Cynthia K; Patil, Krushna N; DeWitt, Christina A Mireles

    2009-10-01

    The purpose of this study was to judge the feasibility of gasification for the disposal of waste streams generated through salmon harvesting. Gasification is the process of converting carbonaceous materials into combustible "syngas" in a high temperature (above 700 degrees C), oxygen deficient environment. Syngas can be combusted to generate power, which recycles energy from waste products. At 66% to 79% moisture, raw salmon waste streams are too wet to undergo pyrolysis and combustion. Ground raw or de-oiled salmon whole fish, heads, viscera, or frames were therefore "dried" by mixing with wood pellets to a final moisture content of 20%. Ground whole salmon with moisture reduced to 12% moisture was gasified without a drying agent. Gasification tests were performed in a small-scale, fixed-bed, updraft gasifer. After an initial start-up period, the gasifier was loaded with 1.5 kg of biomass. Temperature was recorded at 6 points in the gasifier. Syngas was collected during the short steady-state period during each gasifier run and analyzed. Percentages of each type of gas in the syngas were used to calculate syngas heating value. High heating value (HHV) ranged from 1.45 to 1.98 MJ/kg. Bomb calorimetry determined maximum heating value for the salmon by-products. Comparing heating values shows the efficiency of gasification. Cold gas efficiencies of 13.6% to 26% were obtained from the various samples gasified. Though research of gasification as a means of salmon waste disposal and energy production is ongoing, it can be concluded that pre-dried salmon or relatively low moisture content mixtures of waste with wood are gasifiable.

  19. Coal gasification and the power production market

    International Nuclear Information System (INIS)

    Howington, K.; Flandermeyer, G.

    1995-01-01

    The US electric power production market is experiencing significant changes sparking interest in the current and future alternatives for power production. Coal gasification technology is being marketed to satisfy the needs of the volatile power production industry. Coal gasification is a promising power production process in which solid coal is burned to produce a synthesis gas (syn gas). The syn gas may be used to fuel combustion integrated into a facility producing electric power. Advantages of this technology include efficient power production, low flue gas emissions, flexible fuel utilization, broad capability for facility integration, useful process byproducts, and decreased waste disposal. The primary disadvantages are relatively high capital costs and lack of proven long-term operating experience. Developers of coal gasification intend to improve on these disadvantages and lop a strong position in the power generation market. This paper is a marketing analysis of the partial oxidation coal gasification processes emerging in the US in response to the market factors of the power production industry. A brief history of these processes is presented, including the results of recent projects exploring the feasibility of integrated gasification combined cycle (IGCC) as a power production alternative. The current power generation market factors are discussed, and the status of current projects is presented including projected performance

  20. Application and Discussion of Dual Fluidized Bed Reactor in Biomass Energy Utilization

    Science.gov (United States)

    Guan, Haibin; Fan, Xiaoxu; Zhao, Baofeng; Yang, Liguo; Sun, Rongfeng

    2018-01-01

    As an important clean and renewable energy, biomass has a broad market prospect. The dual fluidized bed is widely used in biomass gasification technology, and has become an important way of biomass high-value utilization. This paper describes the basic principle of dual fluidized bed gasification, from the gas composition, tar content and thermal efficiency of the system point of view, analyzes and summarizes several typical dual fluidized bed biomass gasification technologies, points out the existence of gas mixing, the external heat source, catalyst development problems on gas. Finally, it is clear that the gasification of biomass in dual fluidized bed is of great industrial application and development prospect.

  1. Sensing underground coal gasification by ground penetrating radar

    Science.gov (United States)

    Kotyrba, Andrzej; Stańczyk, Krzysztof

    2017-12-01

    The paper describes the results of research on the applicability of the ground penetrating radar (GPR) method for remote sensing and monitoring of the underground coal gasification (UCG) processes. The gasification of coal in a bed entails various technological problems and poses risks to the environment. Therefore, in parallel with research on coal gasification technologies, it is necessary to develop techniques for remote sensing of the process environment. One such technique may be the radar method, which allows imaging of regions of mass loss (voids, fissures) in coal during and after carrying out a gasification process in the bed. The paper describes two research experiments. The first one was carried out on a large-scale model constructed on the surface. It simulated a coal seam in natural geological conditions. A second experiment was performed in a shallow coal deposit maintained in a disused mine and kept accessible for research purposes. Tests performed in the laboratory and in situ conditions showed that the method provides valuable data for assessing and monitoring gasification surfaces in the UCG processes. The advantage of the GPR method is its high resolution and the possibility of determining the spatial shape of various zones and forms created in the coal by the gasification process.

  2. Tumour bed delineation for partial breast/breast boost radiotherapy: What is the optimal number of implanted markers?

    International Nuclear Information System (INIS)

    Kirby, Anna NM.; Jena, Rajesh; Harris, Emma J.; Evans, Phil M.; Crowley, Clare; Gregory, Deborah L.; Coles, Charlotte E.

    2013-01-01

    Purpose: International consensus has not been reached regarding the optimal number of implanted tumour bed (TB) markers for partial breast/breast boost radiotherapy target volume delineation. Four common methods are: insertion of 6 clips (4 radial, 1 deep and 1 superficial), 5 clips (4 radial and 1 deep), 1 clip at the chest wall, and no clips. We compared TB volumes delineated using 6, 5, 1 and 0 clips in women who have undergone wide-local excision (WLE) of breast cancer (BC) with full-thickness closure of the excision cavity, in order to determine the additional margin required for breast boost or partial breast irradiation (PBI) when fewer than 6 clips are used. Methods: Ten patients with invasive ductal BC who had undergone WLE followed by implantation of six fiducial markers (titanium clips) each underwent CT imaging for radiotherapy planning purposes. Retrospective processing of the DICOM image datasets was performed to remove markers and associated imaging artefacts, using an in-house software algorithm. Four observers outlined TB volumes on four different datasets for each case: (1) all markers present (CT 6M ); (2) the superficial marker removed (CT 5M ); (3) all but the chest wall marker removed (CT CW ); (4) all markers removed (CT 0M ). For each observer, the additional margin required around each of TB 0M , TB CW , and TB 5M in order to encompass TB 6M was calculated. The conformity level index (CLI) and differences in centre-of-mass (COM) between observers were quantified for CT 0M , CT CW , CT 5M , CT 6M . Results: The overall median additional margins required to encompass TB 6M were 8 mm (range 0–28 mm) for TB 0M , 5 mm (range 1–13 mm) for TB CW , and 2 mm (range 0–7 mm) for TB 5M . CLI were higher for TB volumes delineated using CT 6M (0.31) CT 5M (0.32) than for CT CW (0.19) and CT 0M (0.15). Conclusions: In women who have undergone WLE of breast cancer with full-thickness closure of the excision cavity and who are proceeding to PBI or

  3. Gasification biochar as a valuable by-product for carbon sequestration and soil amendment

    DEFF Research Database (Denmark)

    Hansen, Veronika; Müller-Stöver, Dorette Sophie; Ahrenfeldt, Jesper

    2015-01-01

    Thermal gasification of various biomass residues is a promising technology for combining bioenergy production with soil fertility management through the application of the resulting biochar as soil amendment. In this study, we investigated gasification biochar (GB) materials originating from two...... major global biomass fuels: straw gasification biochar (SGB) and wood gasification biochar (WGB), produced by a Low Temperature Circulating Fluidized Bed gasifier (LT-CFB) and a TwoStage gasifier, respectively, optimized for energy conversion. Stability of carbon in GB against microbial degradation...

  4. Preparation and development of Ni/Olivine catalysts for hydrogen production by means of biomass gasification in fluidized bed; Elaboration et developpement d'un catalyseur Ni/Olivine pour la production d'hydrogene par gazeification de la biomasse en lit fluidise

    Energy Technology Data Exchange (ETDEWEB)

    Swierczynski, D

    2004-10-01

    Biomass gasification is one of the most interesting ways to valorize this widely accessible source of renewable energy. This process, realized in fluidized bed at high temperature (800-900 C), permits to obtain syngas (mainly H{sub 2}, and CO) which contains however the unwanted sub-products CH{sub 4} and tars. Their catalytic elimination is the key step of the process and permits to clean up the product gas as well as to increase the quantity of H{sub 2} produced. This work describes the development of a catalyst for steam gasification of biomass, designed for fluidized bed, and active for tar and methane reforming. For this we have integrated Ni with natural olivine (Mg{sub 0.9}Fe{sub 0.1})2SiO{sub 4}. Characterization by different techniques (XRD, TPR, SEM, TEM, Moessbauer) showed that during calcination in air, oxidation of olivine leads to a rejection of part of iron (II) from its structure with formation of iron (III) oxides.The catalysts Ni/olivine are obtained by wet impregnation of olivine with an aqueous solution of nickel salt, followed by calcination which leads to a reaction between NiO and olivine. This results in formation of a NiO-MgO solid solution grafted on the support surface and assuring attrition resistance. The catalytic activity was firstly studied in fixed bed in dry reforming of methane, then in steam reforming of tars with toluene as model compound. For both reactions the optimized system showed high activity and selectivity for syngas as well as an excellent stability explained by the presence of the NiO-MgO on the support surface and by formation of Ni-Fe alloys permitting to limit strongly carbon formation and providing long life for the catalyst. Finally the catalyst preparation was scaled-up to 100 kg and its efficacy was confirmed in biomass steam gasification in 100 kWth fluidized bed reactor permitting to envisage its industrial use. (author)

  5. Thermal and biological gasification

    Energy Technology Data Exchange (ETDEWEB)

    Overend, R.P.; Rivard, C.J. [National Renewable Energy Lab., Golden, CO (United States)

    1993-12-31

    Gasification is being developed to enable a diverse range of biomass resources to meet modern secondary energy uses, especially in the electrical utility sector. Biological or anaerobic gasification in US landfills has resulted in the installation of almost 500 MW(e) of capacity and represents the largest scale application of gasification technology today. The development of integrated gasification combined cycle generation for coal technologies is being paralleled by bagasse and wood thermal gasification systems in Hawaii and Scandinavia, and will lead to significant deployment in the next decade as the current scale-up activities are commercialized. The advantages of highly reactive biomass over coal in the design of process units are being realized as new thermal gasifiers are being scaled up to produce medium-energy-content gas for conversion to synthetic natural gas and transportation fuels and to hydrogen for use in fuel cells. The advent of high solids anaerobic digestion reactors is leading to commercialization of controlled municipal solid waste biological gasification rather than landfill application. In both thermal and biological gasification, high rate process reactors are a necessary development for economic applications that address waste and residue management and the production and use of new crops for energy. The environmental contribution of biomass in reducing greenhouse gas emission will also be improved.

  6. Integrated hot fuel gas cleaning for advanced gasification combined cycle process

    Energy Technology Data Exchange (ETDEWEB)

    Nieminen, M.; Kangasmaa, K.; Laatikainen, J.; Staahlberg, P.; Kurkela, E. [VTT Energy, Espoo (Finland). Gasification and Advanced Combustion

    1996-12-01

    The fate of halogens in pressurised fluidized-bed gasification and hot gas filtration is determined. Potential halogen removal sorbents, suitable for integrated hot gas cleaning, are screened and some selected sorbents are tested in bench scale. Finally, halogen removal results are verified using the PDU-scale pressurised fluidized-bed gasification and integrated hot gas cleaning facilities of VTT. The project is part of the JOULE II Extension programme of the European Union. (author)

  7. Effects of effluents of coal combustion and gasification upon lung structure and function. Annual report

    Energy Technology Data Exchange (ETDEWEB)

    Hinton, D.E.

    1980-01-01

    The overall objective of the proposed research is to correlate both structural and functional alterations in cells and tissues of the lung brought about by exposure to fluidized bed combustion and fixed bed gasification effluents and reagent grade oxides of metals known to be associated with coal combustion gasification. Projected milestones are described. Progress during the first year in setting up aerosol exposure facilities, intratracheal instillations, pulmonary mechanics, and morphometric examinations is reported. (DMC)

  8. Entrained flow gasification of coal/bio-oil slurries

    DEFF Research Database (Denmark)

    Feng, Ping; Lin, Weigang; Jensen, Peter Arendt

    2016-01-01

    Coal/bio-oil slurry (CBS) is a new partial green fuel for bio-oil utilization. CBS reacts with gasification agents at high temperatures and converts into hydrogen and carbon monoxide. This paper provides a feasibility study for the gasification of CBS in an atmospheric entrained flow reactor...... with steam/carbon ratio of 5, the syngas components are similar with that in equilibrium. A synergistic effect exists between coal and bio-oil in coal/bio-oil slurry gasification which might be caused by the catalysis effect of alkali metals and alkaline earth metals in bio-oil....

  9. High Pressure Biomass Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, Pradeep K [Georgia Tech Research Corporation, Atlanta, GA (United States)

    2016-07-29

    According to the Billion Ton Report, the U.S. has a large supply of biomass available that can supplement fossil fuels for producing chemicals and transportation fuels. Agricultural waste, forest residue, and energy crops offer potential benefits: renewable feedstock, zero to low CO2 emissions depending on the specific source, and domestic supply availability. Biomass can be converted into chemicals and fuels using one of several approaches: (i) biological platform converts corn into ethanol by using depolymerization of cellulose to form sugars followed by fermentation, (ii) low-temperature pyrolysis to obtain bio-oils which must be treated to reduce oxygen content via HDO hydrodeoxygenation), and (iii) high temperature pyrolysis to produce syngas (CO + H2). This last approach consists of producing syngas using the thermal platform which can be used to produce a variety of chemicals and fuels. The goal of this project was to develop an improved understanding of the gasification of biomass at high pressure conditions and how various gasification parameters might affect the gasification behavior. Since most downstream applications of synags conversion (e.g., alcohol synthesis, Fischer-Tropsch synthesis etc) involve utilizing high pressure catalytic processes, there is an interest in carrying out the biomass gasification at high pressure which can potentially reduce the gasifier size and subsequent downstream cleaning processes. It is traditionally accepted that high pressure should increase the gasification rates (kinetic effect). There is also precedence from coal gasification literature from the 1970s that high pressure gasification would be a beneficial route to consider. Traditional approach of using thermogravimetric analyzer (TGA) or high-pressure themogravimetric analyzer (PTGA) worked well in understanding the gasification kinetics of coal gasification which was useful in designing high pressure coal gasification processes. However

  10. Fiscal 1995 achievement report. Development of entrained bed coal gasification power plant (Part 1 - Studies of key elements and techniques); 1995 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 1. Youso kenkyu hen, gijutsu chosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Element techniques were studied and surveyed for establishing the technology of integrated coal gasification combined cycle. In fiscal 1995, E coal (coal of high ash fluid point) gasification was tested in the 2 tons/day furnace for the effect of its properties on furnace operation and for its properties relating to gasification and slagging and for changes in such properties due to flux admixed with the E coal. It was then found that the ash fluid point was so high as 1500 degrees C and that flux admixing, recovered oxygen reinjection, etc., would be necessary for the assurance of stable slag discharge. In a study using combined cycle system simulation, a comparison was made between results from tests conducted on a real system and results from the simulation, based on the detailed model completed by the preceding fiscal year. The model was reviewed and improved, and simulations were conducted in the respective operating states and operating modes. In the survey of element techniques, information was gathered at a Japan-U.S. joint technical conference held in Japan in October this year. Studies were also made about technical guidelines, or the like, involving coal gasification power generation. (NEDO)

  11. Development program to support industrial coal gasification. Quarterly report 1

    Energy Technology Data Exchange (ETDEWEB)

    None

    1982-01-15

    The Development Program to Support Industrial Coal Gasification is on schedule. The efforts have centered on collecting background information and data, planning, and getting the experimental program underway. The three principal objectives in Task I-A were accomplished. The technical literature was reviewed, the coals and binders to be employed were selected, and tests and testing equipment to be used in evaluating agglomerates were developed. The entire Erie Mining facility design was reviewed and a large portion of the fluidized-bed coal gasification plant design was completed. Much of the work in Task I will be experimental. Wafer-briquette and roll-briquette screening tests will be performed. In Task II, work on the fluidized-bed gasification plant design will be completed and work on a plant design involving entrained-flow gasifiers will be initiated.

  12. Biowaste utilization in the process of co-gasification with bituminous coal and lignite

    International Nuclear Information System (INIS)

    Howaniec, Natalia; Smoliński, Adam

    2017-01-01

    Biowaste utilization in co-gasification with bituminous coal and lignite gives the benefits of stable supplies of a primary energy source – coal and utilization of a zero-emission, waste material (i.e. agriculture waste, sewage sludge, etc.) with higher process efficiency and lower negative environmental impact than biomass or coal gasification, respectively. The main focus of the study presented is co-gasification of bituminous coal or lignite with biowaste to hydrogen-rich gas. The experiments were performed in the laboratory scale fixed-bed reactor installation at 700 and 900 °C. The Hierarchical Clustering Analysis complemented with a color map of studied data were applied in the selection of the optimal operating parameters for biowaste utilization in the co-gasification process based on the experimental data of gasification/co-gasification process as well as physical and chemical properties of fuels tested. The experimental results showed that the carbon conversion rate in co-gasification increased with increasing biomass content in a fuel. The total gas volume and hydrogen volume in co-gasification were higher than the values expected based on the results of the gasification process of the fuels analyzed. - Highlights: • Biowaste co-gasification with bituminous coal/lignite to hydrogen-rich gas. • Steam co-gasification in laboratory scale fixed-bed reactor at 700 and 900 °C. • Hierarchical Clustering Analysis complemented with color map of experimental data. • Carbon conversion increase with increasing biomass content. • The highest total gas and hydrogen volume in co-gasification of C-B20 blend at 900C.

  13. Gasification - Status and technology

    Energy Technology Data Exchange (ETDEWEB)

    Held, Joergen

    2012-06-15

    In this report gasification and gas cleaning techniques for biomass are treated. The main reason for gasifying biomass is to refine the fuel to make it suitable for efficient CHP production, as vehicle fuel or in industrial processes. The focus is on production of synthesis gas that can be used for production of vehicle fuel and for CHP production. Depending on application different types of gasifiers, gasification techniques and process parameters are of interest. Two gasification techniques have been identified as suitable for syngas generation, mainly due to the fact that they allow the production of a nitrogen free gas out of the gasifier; Indirect gasification and pressurized oxygen-blown gasification For CHP production there are no restrictions on the gas composition in terms of nitrogen and here air-blown gasification is of interest as well. The main challenge when it comes to gas cleaning is related to sulphur and tars. There are different concepts and alternatives to handle sulphur and tars. Some of them are based on conventional techniques with well-proven components that are commercially available while others, more advantageous solutions, still need further development.

  14. FY 1991 report on the results of the development of an entrained bed coal gasification power plant. Part 3. Adjustment of the operation test of pilot plant (1/2); 1991 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 3. Pilot plant unten shiken chosei hen (1/2)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-01-01

    The adjustment was made of the operation test of the 200 t/d entrained bed coal gasification pilot plant that was constructed with the aim of establishing technology of the integrated coal gasification combined cycle power generation, and the results were reported. As to the adjustment of the operation test of gasifier facilities, the light-oil firing test and tests of RUN 1-9 were conducted, and the paper reported cases of 49-item troubles, the causes, measures against them, improvement of facilities, etc. For slagging, operation conditions, improvement of various facilities, etc. were studied. Relating to the adjustment of the operation test of gas refining facilities (dry desulfurization facilities), the following were carried out: test on empty column gas circulation, test on desulfurizer circulation characteristics, test on SO2 reduction tower, test on warming-up characteristics, tests 1-3 on initial performance, tests on change in gas turbine fuel and loads. And, 21 cases of troubles, the causes and measures against them were reported. Concerning the adjustment of the operation test of gas refining facilities (dry dedusting facilities), the following were conducted: test on non-load sequence, test on confirmation prior to letting gas through, tests 1-3 on initial performance, test on dedusting characteristics. And, 22 cases of troubles, the causes and measures against them were reported. (NEDO)

  15. FY 1991 report on the results of the development of an entrained bed coal gasification power plant. Part 3. Adjustment of the operation test of pilot plant (2/2); 1991 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 3. Pilot plant unten shiken chosei hen (2/2)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-01-01

    The adjustment was made of the operation test of the 200 t/d entrained bed coal gasification pilot plant that was constructed with the aim of establishing technology of the integrated coal gasification combined cycle power generation, and the results were reported. As to the adjustment of the operation test of gas turbine facilities, the following were conducted: tests 1 and 2 on light-oil firing characteristics, test on coal gas ignition, tests on fuel change/gas firing, test on fuel change. And, 12 cases of troubles, the causes and measures against them were reported. Relating to the adjustment of the operation test of actual pressure/actual size combustor testing facilities, tests on hot air device/air heating device and tests 1-3 on light-oil firing were carried out, and 7 cases of troubles, the causes and measures against them were reported. Concerning the adjustment of the operation test of safety environment facilities, tests were made of RUN 3-6, RUN 7 (1 and 2), RUN 8 (1-4) and RUN 9 (1-3), and 20 cases of troubles, the causes and measures against them were reported. As to the adjustment of the operation test of electric/control facilities, items of improvement were reported of gasifier facilities, gas refining facilities, gas turbine facilities, actual pressure/actual size combustor testing facilities, safety environment facilities and total control facilities. (NEDO)

  16. FY 1990 report on the results of the development of the entrained bed coal gasification power plant. Part 3. Fabrication/installation of pilot plant (Fabrication/installation drawings and fabrication/installation pictures - 1/2); 1990 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 3. Pilot plant seisaku suetsuke hen (Seisaku suetsukezu oyobi seisaku suetsuke shashin) (1/2)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    For the purpose of establishing the technology of the integrated coal gasification combined cycle power generation, the fabrication, installation work, etc. were conducted of a 200t/d entrained bed coal gasification pilot plant, and drawings of fabrication/installation in the FY 1990 were summarized. In fabrication/installation drawings, drawings of the following were included: layout of the total system and the yard, gasifier facilities (system diagram of the main pipe of gasifier, system diagram of gasifier air, system diagram of slag processing, system diagram of recycle gas, diagram of starting light oil pipe system, etc.), gas refining facilities (flow sheet of dry desulfurizer process, structural drawing of desulfurizing tower dust hopper, structural drawings of regeneration tower/rotary valve, etc.), gas refining facilities (flow sheet of dry dust removal system process, structural drawing of No.1 dust discharger, assembly drawing of protection filter, outline drawing of coarse powder discharger, etc.), gas turbine facilities (cross section of gas turbine, front view of gas turbine, structural drawing of air booster, flow sheet of process, system diagram of the main piping, scheme drawing of equipment layout, logic diagram of sequential control, block diagram of protection interlock, logic diagram of gas turbine control, etc.) (NEDO)

  17. FY 1989 report on the results of the development of the entrained bed coal gasification power plant. Part 3. Fabrication/installation of pilot plant (Fabrication/installation drawings and fabrication/installation pictures - 1/2); 1989 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 3. Pilot plant seisaku suetsuke hen (Seisaku suetsukezu oyobi seisaku suetsuke shashin) (1/2)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-03-01

    For the purpose of establishing the technology of the integrated coal gasification combined cycle power generation, the fabrication, installation work, etc. were conducted of a 200t/d entrained bed coal gasification pilot plant, and drawings of fabrication/installation in the FY 1989 were summarized. In fabrication/installation drawings, drawings of the following were included: layout of the total system and the yard, gasifier facilities (assembly drawing of the pressure part of gasifier, drawing of machinery arrangement of gasifier facilities, system diagram of raw coal receiving device, system diagram of pulverized coal feed equipment, system diagram of char feed equipment, etc.), gas refining facilities - dry desulfurizer (assembly drawing of desulfurizing agent carrying filter, assembly drawing of regeneration tower filter, structural drawing of SO{sub 2} reduction tower filter, assembly drawing of start-up heater, etc.), gas refining facilities - dry dust removal system (assembly drawing of No.1 dust separation filter, installation drawing of elevator, etc.), gas turbine facilities (cross section of gas turbine, front view of gas turbine, structural cross section of gas turbogenerator, etc.), actual-pressure/actual-size combustor test equipment (structural drawing of test stand, structural drawing of exhaust temperature reduction device, assembly/sectioned drawing of low-pressure air compressor, etc.) (NEDO)

  18. Underground gasification of coal - possibilities and trends

    International Nuclear Information System (INIS)

    Dushanov, D.; Minkova, V.

    1994-01-01

    A detailed historical review is given on the problem of underground coal gasification (UCG) with emphasis on its physical, chemical, technological and financial aspects. The experience of USA, Japan, former USSR, Belgium, UK and France is described. The feasibility of UCG in the Dobrudzhan Coal Bed in Bulgaria is discussed. The deposit has reserves of about 1.5 billion tones at relatively shallow depths. Almost the whole scale from long flame to dry coal is covered. According to its coalification degree the bed belongs to gas coal - V daf 35-40%; C daf 80-83%, eruption index = 1. Enriched samples has low sulfur content - 0.6-1.5% and low mineral content - 6-12%. Having in mind the lack of domestic natural gas and petroleum resources, the authors state that the utilisation of the bed will alleviate the energy problems in Bulgaria. 24 refs., 5 figs., 1 tab

  19. Analytic Hierarchy and Economic Analysis of a Plasma Gasification System for Naval Air Station Oceana-Dam Neck

    Science.gov (United States)

    2014-08-30

    fixed-bed gasification occur in the waste column, and finally produces a combustible gas mixture known as syngas . The main combustible species in...Old Dominion University Engineering Management and Systems Engineering Department ENMA 605 Program Capstone Final Project Analytic...Hierarchy and Economic Analysis of a Plasma Gasification System for Naval Air Station Oceana-Dam Neck Matthew R. Yost Report

  20. Interobserver variability in the delineation of the tumour bed using seroma and surgical clips based on 4DCT scan for external-beam partial breast irradiation

    International Nuclear Information System (INIS)

    Guo, Bing; Li, Jianbin; Wang, Wei; Xu, Min; Shao, Qian; Zhang, Yingjie; Liang, Chaoqian; Guo, Yanluan

    2015-01-01

    To explore the interobserver variability in the delineation of the tumour bed using seroma and surgical clips based on the four-dimensional computed tomography (4DCT) scan for external-beam partial breast irradiation (EB-PBI) during free breathing. Patients with a seroma clarity score (SCS) 3 ~ 5 and ≥5 surgical clips in the lumpectomy cavity after breast-conserving surgery who were recruited for EB-PBI underwent 4DCT simulation. Based on the ten sets of 4DCT images acquired, the tumour bed formed using the clips, the seroma, and both the clips and seroma (defined as TB C , TB S and TB C+S , respectively) were delineated by five radiation oncologists using specific guidelines. The following parameters were calculated to analyse interobserver variability: volume of the tumour bed (TB C , TB S , TB C+S ), coefficient of variation (COV C , COV S , COV C+S ), and matching degree (MD C , MD S , MD C+S ). The interobserver variability for TB C and TB C+S and for COV C and COV C+S were statistically significant (p = 0.021, 0.008, 0.002, 0.015). No significant difference was observed for TB S and COV S (p = 0.867, 0.061). Significant differences in interobserver variability were observed for MD C vs MD S , MD C vs MD C+S , MD S vs MD C+S (p = 0.000, 0.032, 0.008), the interobserver variability of MD S was smaller than that of MD C and MD C+S (MD S > MD C+S > MD C ). When the SCS was 3 ~ 5 points and the number of surgical clips was ≥5, interobserver variability was minimal for the delineation of the tumour bed based on seroma

  1. Gasification Plant Cost and Performance Optimization

    Energy Technology Data Exchange (ETDEWEB)

    Samuel Tam; Alan Nizamoff; Sheldon Kramer; Scott Olson; Francis Lau; Mike Roberts; David Stopek; Robert Zabransky; Jeffrey Hoffmann; Erik Shuster; Nelson Zhan

    2005-05-01

    As part of an ongoing effort of the U.S. Department of Energy (DOE) to investigate the feasibility of gasification on a broader level, Nexant, Inc. was contracted to perform a comprehensive study to provide a set of gasification alternatives for consideration by the DOE. Nexant completed the first two tasks (Tasks 1 and 2) of the ''Gasification Plant Cost and Performance Optimization Study'' for the DOE's National Energy Technology Laboratory (NETL) in 2003. These tasks evaluated the use of the E-GAS{trademark} gasification technology (now owned by ConocoPhillips) for the production of power either alone or with polygeneration of industrial grade steam, fuel gas, hydrocarbon liquids, or hydrogen. NETL expanded this effort in Task 3 to evaluate Gas Technology Institute's (GTI) fluidized bed U-GAS{reg_sign} gasifier. The Task 3 study had three main objectives. The first was to examine the application of the gasifier at an industrial application in upstate New York using a Southeastern Ohio coal. The second was to investigate the GTI gasifier in a stand-alone lignite-fueled IGCC power plant application, sited in North Dakota. The final goal was to train NETL personnel in the methods of process design and systems analysis. These objectives were divided into five subtasks. Subtasks 3.2 through 3.4 covered the technical analyses for the different design cases. Subtask 3.1 covered management activities, and Subtask 3.5 covered reporting. Conceptual designs were developed for several coal gasification facilities based on the fluidized bed U-GAS{reg_sign} gasifier. Subtask 3.2 developed two base case designs for industrial combined heat and power facilities using Southeastern Ohio coal that will be located at an upstate New York location. One base case design used an air-blown gasifier, and the other used an oxygen-blown gasifier in order to evaluate their relative economics. Subtask 3.3 developed an advanced design for an air

  2. Gasification from waste organic materials

    Directory of Open Access Journals (Sweden)

    Santiago Ramírez Rubio

    2011-09-01

    Full Text Available This article describes the fixed bed biomass gasifier operation designed and built by the Clean Development Mechanisms and Energy Management research group, the gasifier equipment and the measurement system. The experiment involved agro-industrial residues (biomass such wood chips, coconut shell, cocoa and coffee husk; some temperatures along the bed, its pressure, inlet air flow and the percentage of carbon monoxide and carbon dioxide in the syngas composition were measured. The test results showed that a fuel gas was being obtained which was suitable for use with an internal combustion engine for generating electricity because more carbon monoxide than carbon dioxide was being obtained during several parts of the operation. The gasification experimentation revealed that a gasifier having these characteristics should be ideal for bringing energy to areas where it is hard to obtain it (such as many rural sites in Latin-America or other places where large amounts of agro-industrial wastes are produced. Temperatures of around 1,000°C were obtained in the combustion zone, generating a syngas having more than 20% carbon monoxide in its composition, thereby leading to obtaining combustible gas.

  3. Partial oxidation of methane to synthesis gas in a dual catalyst bed system combining irreducible oxide and metallic catalysts

    NARCIS (Netherlands)

    Zhu, J.J.; Mujeebur Rahuman, M.S.M.; van Ommen, J.G.; Lefferts, Leonardus

    2004-01-01

    Operation of partial oxidation of methane to synthesis gas over yttrium-stabilized zirconia (YSZ) at very high temperatures (¿900°C) slightly improves the selectivity to synthesis gas, which is caused by some activity of YSZ for steam and dry reforming of methane. LaCoO3 perovskite is not active in

  4. WATER- AND COAL GASIFICATION

    Directory of Open Access Journals (Sweden)

    N. S. Nazarov

    2006-01-01

    Full Text Available According to the results of gas analysis it has been established that water- and coal gasification is rather satisfactorily described by three thermo-chemical equations. One of these equations is basic and independent and the other two equations depend on the first one.The proposed process scheme makes it possible to explain the known data and also permits to carry out the gasification process and obtain high-quality hydrogen carbon-monoxide which is applicable for practical use.

  5. Synergistic combination of biomass torrefaction and co-gasification: Reactivity studies.

    Science.gov (United States)

    Zhang, Yan; Geng, Ping; Liu, Rui

    2017-12-01

    Two typical biomass feedstocks obtained from woody wastes and agricultural residues were torrefied or mildly pyrolized in a fixed-bed reactor. Effects of the torrefaction conditions on product distributions, compositional and energetic properties of the solid products, char gasification reactivity, and co-gasification behavior between coal and torrefied solids were systematically investigated. Torrefaction pretreatment produced high quality bio-solids with not only increased energy density, but also concentrated alkali and alkaline earth metals (AAEM). As a consequence of greater retention of catalytic elements in the solid products, the chars derived from torrefied biomass exhibited a faster conversion than those derived from raw biomass during CO 2 gasification. Furthermore, co-gasification of coal/torrefied biomass blends exhibited stronger synergy compared to the coal/raw biomass blends. The results and insights provided by this study filled a gap in understanding synergy during co-gasification of coal and torrefied biomass. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Gas distributor for fluidized bed coal gasifier

    Science.gov (United States)

    Worley, Arthur C.; Zboray, James A.

    1980-01-01

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  7. Hydrogen-rich syngas production and tar removal from biomass gasification using sacrificial tyre pyrolysis char

    OpenAIRE

    Al-Rahbi, AS; Williams, PT

    2017-01-01

    Carbonaceous materials have been proven to have a high catalytic activity for tar removal from the syngas produced from biomass gasification. The simultaneous reforming and gasification of pyrolysis gases and char could have a significant role in increasing the gas yield and decreasing the tar in the product syngas. This study investigates the use of tyre char as a catalyst for H2-rich syngas production and tar reduction during the pyrolysis-reforming of biomass using a two stage fixed bed re...

  8. INVESTIGATION OF FUEL CHEMISTRY AND BED PERFORMANCE IN A FLUIDIZED BED BLACK LIQUOR STEAM REFORMER

    Energy Technology Data Exchange (ETDEWEB)

    Kevin Whitty

    2003-12-01

    The University of Utah project ''Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer'' (DOE award number DE-FC26-02NT41490) was developed in response to a solicitation for projects to provide technical support for black liquor and biomass gasification. The primary focus of the project is to provide support for a DOE-sponsored demonstration of MTCI's black liquor steam reforming technology at Georgia-Pacific's paper mill in Big Island, Virginia. A more overarching goal is to improve the understanding of phenomena that take place during low temperature black liquor gasification. This is achieved through five complementary technical tasks: (1) construction of a fluidized bed black liquor gasification test system, (2) investigation of bed performance, (3) evaluation of product gas quality, (4) black liquor conversion analysis and modeling and (5) computational modeling of the Big Island gasifier. Four experimental devices have been constructed under this project. The largest facility, which is the heart of the experimental effort, is a pressurized fluidized bed gasification test system. The system is designed to be able to reproduce conditions near the black liquor injectors in the Big Island steam reformer, so the behavior of black liquor pyrolysis and char gasification can be quantified in a representative environment. The gasification test system comprises five subsystems: steam generation and superheating, black liquor feed, fluidized bed reactor, afterburner for syngas combustion and a flue gas cooler/condenser. The three-story system is located at University of Utah's Industrial Combustion and Gasification Research Facility, and all resources there are available to support the research.

  9. Gasification-based energy production systems for different size classes - Potential and state of R and D

    International Nuclear Information System (INIS)

    Kurkela, E.

    1997-01-01

    (Conference paper). Different energy production systems based on biomass and waste gasification are being developed in Finland. In 1986-1995 the Finnish gasification research and development activities were almost fully devoted to the development of simplified IGCC power systems suitable to large-scale power production based on pressurized fluid-bed gasification, hot gas cleaning and a combined-cycle process. In the 1990's the atmospheric-pressure gasification activities aiming for small and medium size plants were restarted in Finland. Atmospheric-pressure fixed-bed gasification of wood and peat was commercialized for small-scale district heating applications already in the 1980's. Today research and development in this field aims at developing a combined heat and power plant based on the use of cleaned product gas in internal combustion engines. Another objective is to enlarge the feedstock basis of fixed-bed gasifiers, which at present are limited to the use of piece-shaped fuels such as sod peat and wood chips. Intensive research and development is at present in progress in atmospheric-pressure circulating fluidized-bed gasification of biomass residues and wastes. This gasification technology, earlier commercialized for lime-kiln applications, will lead to co-utilization of local residues and wastes in existing pulverized coal fired boilers. The first demonstration plant is under construction in Finland and there are several projects under planning or design phase in different parts of Europe. 48 refs., 1 fig., 1 tab

  10. Tar Management and Recycling in Biomass Gasification and Syngas Purification

    Science.gov (United States)

    McCaffrey, Zach

    Removal of tars is critical to the design and operation of biomass gasification systems as most syngas utilization processing equipment (e.g. internal combustion engines, gas turbines, fuel cells, and liquid fuel synthesis reactors) have a low tolerance for tar. Capturing and disposal of tar is expensive due to equipment costs, high hazardous waste disposal costs where direct uses cannot be found, and system energy losses incurred. Water scrubbing is an existing technique commonly used in gasification plants to remove contaminants and tar; however using water as the absorbent is non-ideal as tar compounds have low or no water solubility. Hydrophobic solvents can improve scrubber performance and this study evaluated tar solubility in selected solvents using slip-streams of untreated syngas from a laboratory fluidized bed reactor operated on almond composite feedstock using both air and steam gasification. Tar solubility was compared with Hansen's solubility theory to examine the extent to which the tar removal can be predicted. As collection of tar without utilization leads to a hazardous waste problem, the study investigated the effects of recycling tars back into the gasifier for destruction. Prior to experiments conducted on tar capture and recycle, characterizations of the air and steam gasification of the almond composite mix were made. This work aims to provide a better understanding of tar collection and solvent selection for wet scrubbers, and to provide information for designing improved tar management systems for biomass gasification.

  11. The technology of extracting gaseous fuel based on comprehensive in situ gasification and coalbed degassing

    Directory of Open Access Journals (Sweden)

    А. Н. Шабаров

    2016-08-01

    Full Text Available The study considers a comprehensive technology (designed and patented by the authors of developing coal and methane deposits which combines in situ gasification of lower coalbeds in the suite of rock bump hazardous gassy beds, extraction of coal methane and mechanized mining of coal. The first stage of the technology consists in mining gaseous fuel that enables one to extract up to 15-20 % of total energy from the suite of coalbeds. Geodynamic zoning is used to select positions for boring wells. Using the suggested technology makes it possible to solve a number of tasks simultaneously. First of all that is extracting gaseous fuel from the suite of coalbeds without running any mining works while retaining principal coalbeds in the suite and preparing them for future processing (unloading and degassing. During the first phase the methane-coal deposit works as a gas deposit only, the gas having two sources – extracted methane (which includes its locked forms, absorbed and adsorbed and the products of partial incineration of thin coalbeds, riders and seams from thee suite. The second stage consists in deep degassing and unloading of coal beds which sharply reduces the hazards of methane explosion and rock bumps, thus increasing the productivity of mechanized coal mining. During the second stage coal is mined in long poles with the account of degassing and unloading of coal beds, plus the data on gas dynamic structure of coal rock massif.

  12. Combustion, pyrolysis, gasification, and liquefaction of biomass

    Energy Technology Data Exchange (ETDEWEB)

    Reed, T.B.

    1980-09-01

    All the products now obtained from oil can be provided by thermal conversion of the solid fuels biomass and coal. As a feedstock, biomass has many advantages over coal and has the potential to supply up to 20% of US energy by the year 2000 and significant amounts of energy for other countries. However, it is imperative that in producing biomass for energy we practice careful land use. Combustion is the simplest method of producing heat from biomass, using either the traditional fixed-bed combustion on a grate or the fluidized-bed and suspended combustion techniques now being developed. Pyrolysis of biomass is a particularly attractive process if all three products - gas, wood tars, and charcoal - can be used. Gasification of biomass with air is perhaps the most flexible and best-developed process for conversion of biomass to fuel today, yielding a low energy gas that can be burned in existing gas/oil boilers or in engines. Oxygen gasification yields a gas with higher energy content that can be used in pipelines or to fire turbines. In addition, this gas can be used for producing methanol, ammonia, or gasoline by indirect liquefaction. Fast pyrolysis of biomass produces a gas rich in ethylene that can be used to make alcohols or gasoline. Finally, treatment of biomass with high pressure hydrogen can yield liquid fuels through direct liquefaction.

  13. Biomass Gasification Combined Cycle

    Energy Technology Data Exchange (ETDEWEB)

    Judith A. Kieffer

    2000-07-01

    Gasification combined cycle continues to represent an important defining technology area for the forest products industry. The ''Forest Products Gasification Initiative'', organized under the Industry's Agenda 2020 technology vision and supported by the DOE ''Industries of the Future'' program, is well positioned to guide these technologies to commercial success within a five-to ten-year timeframe given supportive federal budgets and public policy. Commercial success will result in significant environmental and renewable energy goals that are shared by the Industry and the Nation. The Battelle/FERCO LIVG technology, which is the technology of choice for the application reported here, remains of high interest due to characteristics that make it well suited for integration with the infrastructure of a pulp production facility. The capital cost, operating economics and long-term demonstration of this technology area key input to future economically sustainable projects and must be verified by the 200 BDT/day demonstration facility currently operating in Burlington, Vermont. The New Bern application that was the initial objective of this project is not currently economically viable and will not be implemented at this time due to several changes at and around the mill which have occurred since the inception of the project in 1995. The analysis shows that for this technology, and likely other gasification technologies as well, the first few installations will require unique circumstances, or supportive public policies, or both to attract host sites and investors.

  14. Operational characteristics of a 1.2-MW biomass gasification and power generation plant.

    Science.gov (United States)

    Wu, Chuang-zhi; Yin, Xiu-li; Ma, Long-long; Zhou, Zhao-qiu; Chen, Han-ping

    2009-01-01

    In this study, we analyzed the operational characteristics of a 1.2-MW rice husk gasification and power generation plant located in Changxing, Zhejiang province, China. The influences of gasification temperature, equivalence ratio (ER), feeding rate and rice husk water content on the gasification characteristics in a fluidized bed gasifier were investigated. The axial temperature profile in the dense phase of the gasifier showed that inadequate fluidization occurred inside the bed, and that the temperature was closely related to changes in ER and feeding rate. The bed temperature increased linearly with increasing ER when the feeding rate was kept constant, while a higher feeding rate corresponded to a lower bed temperature at fixed ER. The gas heating value decreased with increasing temperature, while the feeding rate had little effect. When the gasification temperature was 700-800 degrees C, the gas heating value ranged from 5450-6400 kJ/Nm(3). The water content of the rice husk had an obvious influence on the operation of the gasifier: increases in water content up to 15% resulted in increasing ER and gas yield, while water contents above 15% caused aberrant temperature fluctuations. The problems in this plant are discussed in the light of operational experience of MW-scale biomass gasification and power generation plants.

  15. Impact of long-term partial aeration on the removal of 2,4,6-trichlorophenol in an initially methanogenic fluidized bed bioreactor.

    Science.gov (United States)

    Garibay-Orijel, Claudio; Hoyo-Vadillo, Carlos; Ponce-Noyola, Teresa; García-Mena, Jaime; Poggi-Varaldo, Héctor Mario

    2006-08-05

    A fluidized bed bioreactor (FBBR) was operated for more than 1000 days under two regimes, Methanogenic (M) and Methanogenic-Aerobic (M-A), to remove 2,4,6-trichlorophenol (TCP) and phenol (Phe) from a synthetic wastewater, containing different amounts of TCP and Phe, using different aeration flow-rates (0, 2.13, and 1.06 NL O(2)/L.day). M conditions (80:20 mg/L of TCP:Phe, 0 NL O(2)/L.day) showed similar TCP and Phe removal (>95%). Nevertheless accumulation of 4-chlorophenol (4CP) up to 16 mg/L and Phe up to 4 mg/L was observed, while in M-A conditions (80:20 mg/L of TCP:Phe, 2.13 NL O(2)/L.day) TCP and Phe removal achieved 99.9(+)% and after 70 days no accumulation of intermediates were detected. The increase of TCP and Phe in the influent under M-A conditions from 80:20 to 120:30 mg/L of TCP:Phe did not negatively affect the removal of TCP, intermediates and Phe; in fact, they were similar to those in previous M-A conditions. The decrease in the oxygen flow rate from 2.13 to 1.06 NL O(2)/L.day had no negative effect on pollutant removals, which were as high as in previous two M-A conditions. The specific methanogenic activity of bioparticles of the fluidized bed decreased with long-term partial aeration, starting from 1.097 mmol CH(4)/h.g(TKN) in the M regime (day 60) to TCP and less chlorinated intermediates could be achieved in an initially methanogenic FBBR under conditions of partial aeration, although long-term operation seemed to negatively affect the methanogenic activity of biomass. It is also likely that after extended aeration the microbial community was finally enriched with strains with the ability to attack 2,4,6-TCP under aerobic conditions. This report represents the first evidence of a long exposure to oxygen of an anaerobic microbial consortium that efficiently remove TCP. (c) 2006 Wiley Periodicals, Inc.

  16. Inventory of future power and heat production technologies. Partial report Gasification with gas turbine/engine for power plants; Incl. English lang. appendix of 24 p. titled 'Status of large-scale biomass gasification for power production'; Inventering av framtidens el och vaermeproduktionstekniker. Delrapport Foergasning med gasturbin/motor foer kraftvaerk

    Energy Technology Data Exchange (ETDEWEB)

    Waldheim, Lars; Larsson, Eva K. (TPS Termiska Processer, Nykoeping (Sweden))

    2008-12-15

    This subproject is limited to applications with gas turbines or engines from approximately 1 MWe and firing of gas in a boiler either as indirect cofiring or as separate firing of gas from waste gasification. Gasification with gas engine, BIG-ICE (Biomass Integrated Gasification Internal-Combustion Engine) is realized in approximately 10 plants in Europe between 1 and 7 MWe. The gas needs to be cleaned from particles and tar before it is fed to the engine. A number of different gasifiers and gas cleaning technologies are applied in these prototypes, and in certain cases a second generation is being built. Gas engines from GE Jenbacher are most common, but there are also other producers with engines for low-calorific-value gas. The exhausts from engines must, unlike gas turbines, be cleaned catalytically, but emissions of hydrocarbons in particular are still higher than from gas turbines. It is possible to increase the electricity generation by applying a 'bottoming cycle' in the form of a steam or an ORC cycle. Such a plant with ORC has been started in Austria this year. During the 1990's expectations were high concerning the development of biomass gasification with gas turbine in a combined cycle BIG-CC (Biomass Integrated Gasification Combined Cycle) towards commercialisation. Two demonstration plants were built for the same gas turbine model, Siemens SGT 100 (earlier Typhoon); Vaernamo with pressurised gasification and ARBRE in Eggborough, England, with atmospheric gasification. The atmospheric technology has basically the same demands on gas cleaning as in the engine application, but downstream the gas is compressed to the pressure required by the gas turbine. In pressurised gasification, the gasifier pressure is set by the gas turbine. The gas is not cooled below 350-400 deg C and is cleaned in a high-temperature filter. Despite successful demonstration in Vaernamo, no more plants have been built. The ARBRE plant was never put into regular

  17. Guideline for safe and eco-friendly biomass gasification

    Energy Technology Data Exchange (ETDEWEB)

    Vos, J.; Knoef, H. (BTG biomass technology group, Enschede (Netherlands)); Hauth, M. (Graz Univ. of Technology. Institute of Thermal Engineering, Graz (Austria)) (and others)

    2009-11-15

    The objective of the Gasification Guide project is to accelerate the market penetration of small-scale biomass gasification systems (< 5 MW fuel power) by the development of a Guideline and Software Tool to facilitate risk assessment of HSE aspects. The Guideline may also be applied in retrofitting or converting old thermal plants in the Eastern European countries - with rich biomass recourses - to new gasification plants. The objective of this document is to guide key target groups identifying potential hazards and make a proper risk assessment. The software tool is an additional aid in the risk assessment. This guideline is intended to be a training tool and a resource for workers and employers to safely design, fabricate, construct, operate and maintain small-scale biomass gasification facilities. The Guideline is applicable with the following constraints: 1) The maximum scale of the gasification plant was agreed to be about 1 MW{sub e}. The reason is that large companies do have normally their safety rules in place; 2) This means in principle only fixed bed gasifier designs. However, most parts are also valid to other designs and even other thermal conversion processes; 3) The use of contaminated biomass is beyond the scope of this Guideline. The Guideline contains five major chapters; Chapter 2 briefly describes the gasification technology in general. Chapter 3 gives an overview of major legal framework issues on plant permission and operation. The legal frame is changing and the description is based on the situation by the end of 2007. Chapter 4 explains the theory behind the risk assessment method and risk reduction measures. Chapter 5 is the heart of the Guideline and gives practical examples of good design, operation and maintenance principles. The practical examples and feedback have been received throughout the project and the description is based on mid-2009. Chapter 6 describes the best techniques currently available for emission abatement which are

  18. Gasification with nuclear reactor heat

    International Nuclear Information System (INIS)

    Weisbrodt, I.A.

    1977-01-01

    The energy-political ultimate aims for the introduction of nuclear coal gasification and the present state of technology concerning the HTR reactor, concerning gasification and heat exchanging components are outlined. Presented on the plans a) for hydro-gasification of lignite and for steam gasification of pit coal for the production of synthetic natural gas, and b) for the introduction of a nuclear heat system. The safety and environmental problems to be expected are portrayed. The main points of development, the planned prototype plant and the schedule of the project Pototype plant Nuclear Process heat (PNP) are specified. In a market and economic viability study of nuclear coal gasification, the application potential of SNG, the possible construction programme for the FRG, as well as costs and rentability of SNG production are estimated. (GG) [de

  19. Biomass Gasification - A synthesis of technical barriers and current research issues for deployment at large scale

    Energy Technology Data Exchange (ETDEWEB)

    Heyne, Stefan [Chalmers Univ. of Technology, Gothenburg (Sweden); Liliedahl, Truls [KTH, Royal Inst. of Technology, Stockholm (Sweden); Marklund, Magnus [Energy Technology Centre, Piteaa (Sweden)

    2013-09-01

    Thermal gasification at large scale for cogeneration of power and heat and/or production of fuels and materials is a main pathway for a sustainable deployment of biomass resources. However, so far no such full scale production exists and biomass gasification projects remain at the pilot or demonstration scale. This report focuses on the key critical technology challenges for the large-scale deployment of the following biomass-based gasification concepts: Direct Fluidized Bed Gasification (FBG), Entrained Flow Gasification (EFG) and indirect Dual Fluidized Bed Gasification (DFBG). The main content in this report is based on responses from a number of experts in biomass gasification obtained from a questionnaire. The survey was composed of a number of more or less specific questions on technical barriers as to the three gasification concepts considered. For formalising the questionnaire, the concept of Technology Readiness Level (TRL 1-9) was used for grading the level of technical maturity of the different sub-processes within the three generic biomass gasification technologies. For direct fluidized bed gasification (FBG) it is mentioned that the technology is already available at commercial scale as air-blown technology and thus that air-blown FBG gasification may be reckoned a mature technology. The remaining technical challenge is the conversion to operation on oxygen with the final goal of producing chemicals or transport fuels. Tar reduction, in particular, and gas cleaning and upgrading in general are by far the most frequently named technical issues considered problematic. Other important aspects are problems that may occur when operating on low-grade fuels - i.e. low-cost fuels. These problems include bed agglomeration/ash sintering as well as alkali fouling. Even the preparation and feeding of these low-grade fuels tend to be problematic and require further development to be used on a commercial scale. Furthermore, efficient char conversion is mentioned by

  20. Achievement report for fiscal 1993 on developing entrained bed coal gasification power plant. Part 1. Element research and technology survey edition; 1993 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 1. Youso kenkyu hen, gijutsu chosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-02-01

    With an objective of establishing a coal gasification composite power generation technology, R and D works have been carried out on elementary technologies. This paper summarizes the achievements in fiscal 1993. In the research on the slag utilization technology, discussions were given on the applicability of slag discharged from a 200 t/d pilot plant to fine aggregate for concrete. In the research on a large gas turbine combustor for a demonstration plant, the test conditions were discussed and the reliability of the combustor was analyzed to conduct an actual gas combustion test using the coal D in continuation from the test in the previous fiscal year. In the research on the simulation of a composite power generation system, the simulation models were reviewed and corrected. Load variation simulations were carried out on every operation mode to have conducted comparison with and discussion on the actual plant data. In order to clarify the slagging phenomenon in the 200 t/d pilot plant, a characteristics test was performed by using a 2 t/d furnace. As a result, the combustor ash load and the dynamic pressure in the axial direction in the throat section were presumed to be the large factors for the occurrence of slagging. (NEDO)

  1. Achievement report for fiscal 1994 on developing entrained bed coal gasification power plant. Part 1. Element research edition and technology survey edition; 1994 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 1. Youso kenkyu hen, gijutsu chosa hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    With an objective of establishing the coal gasification composite power generation technology, R and D has been carried out on the elementary technologies. This paper summarizes the achievements in fiscal 1994. In the research on the large gas turbine combustor for the demonstration plant, combustion tests were carried out by using the actual gas from the designed coal (coal D). In addition, the minimum gas flow rate test, fuel calory change test, and fuel switching test were performed from the viewpoint of evaluating the low load stability. Furthermore, in order to evaluate the combustion performance of the tested combustor, such tests were conducted as the combustor pressure loss characteristics test, bypass valve flow rate characteristics test, light oil ignition and light oil combustion test, and tests on the characteristics to switch from light oil to coal gas and the coal gas combustion characteristics. Evaluations were given on the NOx conversion rate, CO, THC, combustion efficiency, metal temperatures, pattern factors, pressure loss, internal pressure variation, and vibration stress. In the simulation research of the composite power generation system, the simulation models were varied according to the actual plant requirements in association with the progress of the tests on the pilot plant. The results of the simulations were reflected to the general load pressure control equipment. (NEDO)

  2. Achievement report for fiscal 1993 on developing entrained bed coal gasification power plant. Part 5. Survey and research edition for demonstration plant; 1993 nendo seika hokokusho. Funryusho sekitan gaska hatsuden plant kaihatsu - Sono 5. Jissho plant ni kansuru chosa kenkyu hen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-02-01

    With an objective of developing the coal gasification composite power generation technology, surveys and researches have been carried out on a demonstration plant. This paper summarizes the achievements in fiscal 1993. Based on the achievements having been obtained by the previous fiscal year, the current fiscal year has discussed the method for evaluating the up-scaling, and performed a conceptual design of the demonstration plant. In discussing the demonstration plant in the current fiscal year, identification was made on the basic performance characteristics as the IGCC (atmospheric temperature characteristics, coal type change characteristics, partial load characteristics, methods for plant actuation and shutdown, and utility use amount), and selections were conducted on different systems to be adopted in the demonstration plant, both based on the approximate thermal material balance having been derived in the previous fiscal year. The results of the discussions were summarized as the steam cycle discussion, performance discussion by coal types, partial load characteristics, atmospheric temperature characteristics, secondary air temperature characteristics, discussions to enhance efficiency and reliability in association with the up-scaling, discussions on the utility facilities, discussions on the protection interlock, and forecast on the entire performance according to the approximate thermal material balance. (NEDO)

  3. Gasification of rice husks

    Energy Technology Data Exchange (ETDEWEB)

    Marzetti, P. (ENEA, Rome (Italy). Dipt. Fonti Alternative e Risparmio Energetico)

    The paper outlines the thermochemical processes and equipment involved in the gasification of rice husks. An assessment is made of the feasibility (availability, technology requirements, economics of production and marketing) of this renewable energy source. Results, reported here in tabular form, of experimental trials at an Italian pilot plant (producing, with the use of 165 kg/h of rice husks, 350,000 kcal/h of gas with a conversion yield of 70%) indicated good feasibility. More research is required to improve the combustion qualities of the final product.

  4. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    Energy Technology Data Exchange (ETDEWEB)

    Kevin Whitty

    2007-06-30

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  5. Reaction Mechanism of Tar Evolution in Biomass Steam Gasification for Hydrogen Production

    International Nuclear Information System (INIS)

    Shingo Katayama; Masahiro Suzuki; Atsushi Tsutsumi

    2006-01-01

    Reaction mechanism of tar evolution in steam gasification of biomass was investigated with a continuous cross-flow moving bed type differential reactor, in which tar and gases can be fractionated according to reaction time. We estimated that time profile of tar and gas evolution in the gasification of cellulose, xylan, and lignin, and compared it with experimental product time profile of real biomass gasification. The experimental tar evolution rate is different from estimated tar evolution rate. The estimated tar evolution rate has a peak at 20 s. On the other hand, the experimental tar evolution rate at 20 s is little, and tar at initial stage includes more water-soluble and water-insoluble compounds. It can be concluded that in the real biomass steam gasification the evolution of tar from cellulose and lignin component was found to be precipitated by that from hemi-cellulose component. (authors)

  6. Prevention of the ash deposits by means of process conditions in biomass gasification; Biomassapolttoaineiden tuhkan kuonaantumiskaeyttaeytymisen estaeminen prosessiolosuhteiden avulla

    Energy Technology Data Exchange (ETDEWEB)

    Moilanen, A.; Laatikainen-Luntama, J.; Nieminen, M.; Kurkela, E.; Korhonen, J. [VTT Energy, Espoo (Finland)

    1997-10-01

    In fluidised-bed gasification, various types of deposits and agglomerates may be formed by biomass ash in the bed, in upper zones of the reactor, for instance in cyclones. These may decisively hamper the operation of the process. The aim of the project was to obtain data on the detrimental fouling behaviour of the ash of different types of biomass in fluidised-bed gasification, and on the basis of these data to determine the process conditions and ways of preventing this kind of behaviour. Different types of biomass fuel relevant to energy production such as straw, wood residue were be used as samples. The project consisted of laboratory studies and fluidised-bed reactor tests including ash behaviour studied both in the bed and freeboard. In laboratory tests, the sample material was characterised as a function of different process parameters. In fluid-bed reactors, the most harmful biomasses were tested using process variables such as temperature, bed material and the gasification agents. Bubbling fluidised-bed gasification tests with wheat straw showed that agglomerates with different sizes and structures formed in the bed depending on the temperature, the feed gas composition and bed material. Agglomerates consisted of molten ash which sintered with bed material and other solids. In all BFB tests, freeboard walls were slicked by ash agglomerates (different amounts) which, however, were easily removable. The results of this project and the earlier pilot-scale gasification experience obtained with the same feedstocks showed that useful characteristic data about ash behaviour can be obtained using laboratory tests and small scale reactors. (orig.)

  7. The development of Coke Carried-Heat Gasification Coal-Fired Combined Cycle

    Science.gov (United States)

    Zhao, Li; Xu, Xiangdong

    1999-12-01

    Carried-Heat Partial Gasification Combined cycle is a novel combined cycle which was proposed by Thermal Engineering Department of Tsinghua University in 1992. The idea of the system comes from the situation that the efficiency of the power plants in China is much lower than that of the advanced countries, but the coal consumption is much higher, which brings about the waste of primary energy resources and the pollution of the environment. With the deep study of the gasification technology, Coke Carried-Heat Gasification Coal-Fired Combined Cycle, as the improved system, came into birth in 1996 based on the partial gasification one. At the end of 1997, a new cycle scheme similar to IGCC was created. This paper focuses on several classes combined cycle put forward by Tsinghua University, depending on the plant configuration and carbon conversion, making the solution a viable and attractive option for efficient coal utilization.

  8. Catalytic gasification of biomass (Miscanthus) enhanced by CO2 sorption.

    Science.gov (United States)

    Zamboni, I; Debal, M; Matt, M; Girods, P; Kiennemann, A; Rogaume, Y; Courson, C

    2016-11-01

    The main objective of this work concerns the coupling of biomass gasification reaction and CO 2 sorption. The study shows the feasibility to promote biomass steam gasification in a dense fluidized bed reactor with CO 2 sorption to enhance tar removal and hydrogen production. It also proves the efficiency of CaO-Ca 12 Al 14 O 33 /olivine bi-functional materials to reduce heavy tar production. Experiments have been carried out in a fluidized bed gasifier using steam as the fluidizing medium to improve hydrogen production. Bed materials consisting of CaO-based oxide for CO 2 sorption (CaO-Ca 12 Al 14 O 33 ) deposited on olivine for tar reduction were synthesized, their structural and textural properties were characterized by Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), and temperature-programmed reduction (TPR) methods, and the determination of their sorption capacity and stability analyzed by thermogravimetric analysis (TGA). It appears that this CaO-Ca 12 Al 14 O 33 /olivine sorbent/catalyst presents a good CO 2 sorption stability (for seven cycles of carbonation/decarbonation). Compared to olivine and Fe/olivine in a fixed bed reactor for steam reforming of toluene chosen as tar model compound, it shows a better hydrogen production rate and a lower CO 2 selectivity due to its sorption on the CaO phase. In the biomass steam gasification, the use of CaO-Ca 12 Al 14 O 33 /olivine as bed material at 700 °C leads to a higher H 2 production than olivine at 800 °C thanks to CO 2 sorption. Similar tar concentration and lighter tar production (analyzed by HPLC/UV) are observed. At 700 °C, sorbent addition allows to halve tar content and to eliminate the heaviest tars.

  9. Bio-syngas production from biomass catalytic gasification

    International Nuclear Information System (INIS)

    Lv, Pengmei; Yuan, Zhenhong; Wu, Chuangzhi; Ma, Longlong; Chen, Yong; Tsubaki, Noritatsu

    2007-01-01

    A promising application for biomass is liquid fuel synthesis, such as methanol or dimethyl ether (DME). Previous studies have studied syngas production from biomass-derived char, oil and gas. This study intends to explore the technology of syngas production from direct biomass gasification, which may be more economically viable. The ratio of H 2 /CO is an important factor that affects the performance of this process. In this study, the characteristics of biomass gasification gas, such as H 2 /CO and tar yield, as well as its potential for liquid fuel synthesis is explored. A fluidized bed gasifier and a downstream fixed bed are employed as the reactors. Two kinds of catalysts: dolomite and nickel based catalyst are applied, and they are used in the fluidized bed and fixed bed, respectively. The gasifying agent used is an air-steam mixture. The main variables studied are temperature and weight hourly space velocity in the fixed bed reactor. Over the ranges of operating conditions examined, the maximum H 2 content reaches 52.47 vol%, while the ratio of H 2 /CO varies between 1.87 and 4.45. The results indicate that an appropriate temperature (750 o C for the current study) and more catalyst are favorable for getting a higher H 2 /CO ratio. Using a simple first order kinetic model for the overall tar removal reaction, the apparent activation energies and pre-exponential factors are obtained for nickel based catalysts. The results indicate that biomass gasification gas has great potential for liquid fuel synthesis after further processing

  10. Gasification Performance of a Top-Lit Updraft Cook Stove

    Directory of Open Access Journals (Sweden)

    Yogesh Mehta

    2017-10-01

    Full Text Available This paper reports on an experimental study of a top-lit updraft cook stove with a focus on gasification. The reactor is operated with primary air only. The performance is studied for a variation in the primary airflow, as well as reactor geometry. Temperature in the reactor, air flow rate, fuel consumption rate, and producer gas composition were measured. From the measurements the superficial velocity, pyrolysis front velocity, peak bed temperature, air fuel ratio, heating value of the producer gas, and gasification rate were calculated. The results show that the producer gas energy content was maximized at a superficial velocity of 9 cm/s. The percent char remaining at the end of gasification decreased with increasing combustion chamber diameter. For a fixed superficial velocity, the gasification rate and producer gas energy content were found to scale linearly with diameter. The energy content of the producer gas was maximized at an air fuel (AF ratio of 1.8 regardless of the diameter.

  11. Hydrogen production from algal biomass via steam gasification.

    Science.gov (United States)

    Duman, Gozde; Uddin, Md Azhar; Yanik, Jale

    2014-08-01

    Algal biomasses were tested as feedstock for steam gasification in a dual-bed microreactor in a two-stage process. Gasification experiments were carried out in absence and presence of catalyst. The catalysts used were 10% Fe₂O₃-90% CeO₂ and red mud (activated and natural forms). Effects of catalysts on tar formation and gasification efficiencies were comparatively investigated. It was observed that the characteristic of algae gasification was dependent on its components and the catalysts used. The main role of the catalyst was reforming of the tar derived from algae pyrolysis, besides enhancing water gas shift reaction. The tar reduction levels were in the range of 80-100% for seaweeds and of 53-70% for microalgae. Fe₂O₃-CeO₂ was found to be the most effective catalyst. The maximum hydrogen yields obtained were 1036 cc/g algae for Fucus serratus, 937 cc/g algae for Laminaria digitata and 413 cc/g algae for Nannochloropsis oculata. Copyright © 2014 Elsevier Ltd. All rights reserved.

  12. Treatment of coal gasification wastewaters: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Donaldson, T.L.; Lee, D.D.; Singh, S.P.N.

    1987-03-01

    A bench-scale fluidized-bed bioreactor was operated for over 4 months to characterize the biooxidation of major organic pollutants in coal gasification wastewater obtained from the Morgantown Energy Technology Center. Monohydric phenol was degraded first, followed by more complex phenolics, including polycyclic aromatic hydrocarbons (PAHs). Organic components were assayed by methylene chloride extraction followed by gas chromatography. Genetic capability for degradation of naphthalene by the biofilm was identified by gene probe analysis. Further studies were conducted to determine if the existing biofilm could be enhanced for naphthalene degradation by supplemental inoculation with a microbial culture having good naphthalene-degrading capabilities. The biofilm response was monitored using gene probe techniques. An assessment of wastewater treatment technologies for coal conversion wastewaters was initiated. A bibliography was compiled, arrangements were initiated to collaborate with other investigators doing wastewater treatability studies, and a site visit was made to the Great Plains plant. 201 refs., 3 figs., 5 tabs.

  13. Fluid-bed combustion

    Energy Technology Data Exchange (ETDEWEB)

    Hunt, G.; Schoebotham, N.

    1981-02-01

    In Energy Equipment Company's two-stage fluidized bed system, partial combustion in a fluidized bed is followed by burn-off of the generated gases above the bed. The system can be retrofitted to existing boilers, and can burn small, high ash coal efficiently. It has advantages when used as a hot gas generator for process drying. Tests on a boiler at a Cadbury Schweppes plant are reported.

  14. Hydrogen production from biomass over steam gasification

    Energy Technology Data Exchange (ETDEWEB)

    Rauch, R.; Potetz, A.; Hofbauer, H. [Vienna Univ. of Technology (Austria). Inst. of Chemical Engineering; Weber, G. [Bioenergy 2020+, Guessing (Austria)

    2010-12-30

    Renewable hydrogen is one option for a clean energy carrier in the future. There were several research programs in the past, to produce hydrogen on a renewable basis by electrolysis, direct conversion of water or by gasification of biomass. None of these options were developed to a stage, that they could be used on a commercial basis. At the moment almost all hydrogen is produced from fossil fuels and one main consumer of hydrogen are refineries. So a good option to demonstrate the production of renewable hydrogen and bring it later into the market is over refineries. The most economic option to produce renewable hydrogen at the moment is over gasification of biomass. In Austria an indirect gasification system was developed and is demonstrated in Guessing, Austria. The biomass CHP Guessing uses the allothermal steam dual fluidised bed gasifier and produces a high grade product gas, which is used at the moment for the CHP in a gas engine. As there is no nitrogen in the product gas and high hydrogen content, this gas can be also used as synthesis gas or for production of hydrogen. The main aim of this paper is to present the experimental and simulation work to convert biomass into renewable hydrogen. The product gas of the indirect gasification system is mainly hydrogen, carbon monoxide, carbon dioxide and methane. Within the ERA-Net project ''OptiBtLGas'' the reforming of methane and the CO-shift reaction was investigated to convert all hydrocarbons and carbon monoxide to hydrogen. On basis of the experimental results the mass- and energy balances of a commercial 100 MW fuel input plant was done. Here 3 different cases of complexity of the overall plant were simulated. The first case was without reforming and CO-shift, only by hydrogen separation. The second case was by including steam - reforming and afterwards separation of hydrogen. The third case includes hydrocarbon reforming, CO-shift and hydrogen separation. In all cases the off-gases (CO

  15. Entrained Flow Gasification of Biomass

    DEFF Research Database (Denmark)

    Qin, Ke

    The present Ph. D. thesis describes experimental and modeling investigations on entrained flow gasification of biomass and an experimental investigation on entrained flow cogasification of biomass and coal. A review of the current knowledge of biomass entrained flow gasification is presented....... Biomass gasification experiments were performed in a laboratory-scale atmospheric pressure entrained flow reactor with the aim to investigate the effects of operating parameters and biomass types on syngas products. A wide range of operating parameters was involved: reactor temperature, steam/carbon ratio......, excess air ratio, oxygen concentration, feeder gas flow, and residence time. Wood, straw, and lignin were used as biomass fuels. In general, the carbon conversion was higher than 90 % in the biomass gasification experiments conducted at high temperatures (> 1200 °C). The biomass carbon...

  16. The development of solid fuel gasification systems for cost-effective power generation with low environmental impacts

    Energy Technology Data Exchange (ETDEWEB)

    Nieminen, M.; Kurkela, E.; Staahlberg, P.; Laatikainen-Luntama, J.; Ranta, J.; Hepola, J.; Kangasmaa, K. [VTT Energy, Espoo (Finland). Gasification and Advanced Combustion

    1997-10-01

    Relatively low carbon conversion is a disadvantage related to the air-blown fluidised-bed coal-biomass co-gasification process. Low carbon conversion is due to different reactivities and ash sintering behaviour of coal and biomass which leads to compromises in definition of gasification process conditions. In certain cases co-gasification may also lead to unexpected deposit formations or corrosion problems in downstream components especially when high alkali metal or chlorine containing biomass feedstocks are co-gasified with coal. During the reporting period, the work focused on co-gasification of coal and wood waste. The objectives of the present work were to find out the optimum conditions for improving the carbon conversion and to study the formation of different gas impurities. The results based on co-gasification tests with a pressurised fluidised-bed gasifies showed that in co-gasification even with only 15 % coal addition the heavy tar concentration was decreased significantly and, simultaneously, an almost total carbon conversion was achieved by optimising the gasification conditions. The study of filter fines recirculation and solid residues utilisation was started by characterizing filter dust. The work was carried out with an entrained-flow reactor in oxidising, inert and reducing gas conditions. The aim was to define the conditions required for achieving increased carbon conversion in different reactor conditions

  17. PHYSICO-CHEMICAL PROPERTIES OF THE SOLID AND LIQUID WASTE PRODUCTS FROM THE HEAVY METAL CONTAMINATED ENERGY CROPS GASIFICATION PROCESS

    Directory of Open Access Journals (Sweden)

    Sebastian Werle

    2017-02-01

    Full Text Available The paper presents the results of basic physico-chemical properties of solid (ash and liquid (tar waste products of the gasification process of the heavy metal contaminated energy crops. The gasification process has carried out in a laboratory fixed bed reactor. Three types of energy crops: Miscanthus x giganteus, Sida hermaphrodita and Spartina Pectinata were used. The experimental plots were established on heavy metal contaminated arable land located in Bytom (southern part of Poland, Silesian Voivodship.

  18. Catalytic hot gas cleaning of gasification gas

    Energy Technology Data Exchange (ETDEWEB)

    Simell, P. [VTT Energy, Espoo (Finland). Energy Production Technologies

    1997-12-31

    The aim of this work was to study the catalytic cleaning of gasification gas from tars and ammonia. In addition, factors influencing catalytic activity in industrial applications were studied, as well as the effects of different operation conditions and limits. Also the catalytic reactions of tar and ammonia with gasification gas components were studied. The activities of different catalyst materials were measured with laboratory-scale reactors fed by slip streams taken from updraft and fluid bed gasifiers. Carbonate rocks and nickel catalysts proved to be active tar decomposing catalysts. Ammonia decomposition was in turn facilitated by nickel catalysts and iron materials like iron sinter and iron dolomite. Temperatures over 850 deg C were required at 2000{sup -1} space velocity at ambient pressure to achieve almost complete conversions. During catalytic reactions H{sub 2} and CO were formed and H{sub 2}O was consumed in addition to decomposing hydrocarbons and ammonia. Equilibrium gas composition was almost achieved with nickel catalysts at 900 deg C. No deactivation by H{sub 2}S or carbon took place in these conditions. Catalyst blocking by particulates was avoided by using a monolith type of catalyst. The apparent first order kinetic parameters were determined for the most active materials. The activities of dolomite, nickel catalyst and reference materials were measured in different gas atmospheres using laboratory apparatus. This consisted of nitrogen carrier, toluene as tar model compound, ammonia and one of the components H{sub 2}, H{sub 2}O, CO, CO{sub 2}, CO{sub 2}+H{sub 2}O or CO+CO{sub 2}. Also synthetic gasification gas was used. With the dolomite and nickel catalyst the highest toluene decomposition rates were measured with CO{sub 2} and H{sub 2}O. In gasification gas, however, the rate was retarded due to inhibition by reaction products (CO, H{sub 2}, CO{sub 2}). Tar decomposition over dolomite was modelled by benzene reactions with CO{sub 2}, H

  19. On the feasibility of integrating thermochemical processes for the decomposition of water in coal gasification. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Preti, U.; Colussi, I.; Fermeglia, A.M.; Gallo, V.; Groppi, G.; Kikic, I.; Pomodoro, C.; Schmid, C.

    1984-01-01

    Two distinct parts from the study presented in this report: their common purpose is to increase hydrogen production in coal gasification processes with non traditional methods. In the first part it has been analysed to produce hydrogen by means of thermochemical cycles of water decomposition and taking advantage of gasification gas heat evolved in the entrained-bed reactor, which operates at high temperature (1700 to 1800 K). The second part deals with the analysis of recovering hydrogen from hydrogen sulphide, which forms in coal gasification, by utilizing processes derived from the 'Mark-13' thermochemical cycle of water decomposition conceived at the Joint Research Centre at Ispra.

  20. Centralized coke gasification study

    Energy Technology Data Exchange (ETDEWEB)

    du Plessis, Duke [Alberta Innovates (Canada); Pietrusik, Debbie [Alberta Finance and Enterprise (Canada)

    2011-07-01

    By the year 2020 Alberta will produce 3 million barrels of bitumen per day. Refining bitumen yields several by-products such as petroleum coke and off-gasses. These products can be further utilized as a low cost feedstock for additional applications to increase revenue. Alberta currently has the largest amount of coke stockpiled in the world. The presentation explores what is the most profitable way to use this coke and what future technologies would improve the economic and environmental impact of the process. The development of methane and hydrogen becomes competitive at intermediate gas and oil prices. The next generation of gasification technologies is going to be cheaper, efficient and much smaller. Pilot projects have shown positive results. Economies of scale can be reached simply by only 20-30% of annual coke production. The high cost of the current technology is creating the biggest challenge but new technologies and process innovations have the potential to drive down cost.

  1. Development of a chemical kinetic model for a biosolids fluidized-bed gasifier and the effects of operating parameters on syngas quality.

    Science.gov (United States)

    Champion, Wyatt M; Cooper, C David; Mackie, Kevin R; Cairney, Paul

    2014-02-01

    In an effort to decrease the land disposal of sewage sludge biosolids and to recover energy, gasification has become a viable option for the treatment of waste biosolids. The process of gasification involves the drying and devolatilization and partial oxidation of biosolids, followed closely by the reduction of the organic gases and char in a single vessel. The products of gasification include a gaseous fuel composed largely of N2, H2O, CO2, CO, H2, CH4, and tars, as well as ash and unburned solid carbon. A mathematical model was developed using published devolatilization, oxidation, and reduction reactions, and calibrated using data from three different experimental studies of laboratory-scale fluidized-bed sewage sludge gasifiers reported in the literature. The model predicts syngas production rate, composition, and temperature as functions of the biosolids composition and feed rate, the air input rate, and gasifier bottom temperature. Several data sets from the three independent literature sources were reserved for model validation, with a focus placed on five species of interest (CO, CO2, H2, CH4, and C6H6). The syngas composition predictions from the model compared well with experimental results from the literature. A sensitivity analysis on the most important operating parameters of a gasifier (bed temperature and equivalence ratio) was performed as well, with the results of the analysis offering insight into the operations of a biosolids gasifier.

  2. Materials of Gasification

    Energy Technology Data Exchange (ETDEWEB)

    None

    2005-09-15

    The objective of this project was to accumulate and establish a database of construction materials, coatings, refractory liners, and transitional materials that are appropriate for the hardware and scale-up facilities for atmospheric biomass and coal gasification processes. Cost, fabricability, survivability, contamination, modes of corrosion, failure modes, operational temperatures, strength, and compatibility are all areas of materials science for which relevant data would be appropriate. The goal will be an established expertise of materials for the fossil energy area within WRI. This would be an effort to narrow down the overwhelming array of materials information sources to the relevant set which provides current and accurate data for materials selection for fossil fuels processing plant. A significant amount of reference material on materials has been located, examined and compiled. The report that describes these resources is well under way. The reference material is in many forms including texts, periodicals, websites, software and expert systems. The most important part of the labor is to refine the vast array of available resources to information appropriate in content, size and reliability for the tasks conducted by WRI and its clients within the energy field. A significant has been made to collate and capture the best and most up to date references. The resources of the University of Wyoming have been used extensively as a local and assessable location of information. As such, the distribution of materials within the UW library has been added as a portion of the growing document. Literature from recent journals has been combed for all pertinent references to high temperature energy based applications. Several software packages have been examined for relevance and usefulness towards applications in coal gasification and coal fired plant. Collation of the many located resources has been ongoing. Some web-based resources have been examined.

  3. Co-combustion and gasification of various biomasses

    Energy Technology Data Exchange (ETDEWEB)

    Mutanen, K. [A. Ahlstrom Corporation, Varkaus (Finland). Ahlstrom Pyropower

    1996-12-31

    During the last twenty years the development of fluidized bed combustion and gasification technology has made it possible to increase significantly utilisation of various biomasses in power and heat generation. The forerunner was the pulp and paper industry that has an adequate biomass fuel supply and energy demand on site. Later on municipalities and even utilities have seen biomass as a potential fuel. The range of available biomasses includes wood-based fuels and wastes like bark, wood chips, and saw dust, agricultural wastes like straw, olive waste and rice husk, sludges from paper mills and de-inking plants, other wastes like municipal sludges, waste paper and RDF. Recently new environmental regulations and taxation of fossil fuels have further increased interest in the use of biomasses in energy generation. However, in many cases available quantities and/or qualities of biomasses are not adequate for only biomass-based energy generation in an economic sense. On the other hand plant owners want to maintain a high level of fuel flexibility and fuel supply security. In some cases disposing by burning is the only feasible way to handle certain wastes. In many cases the only way to fulfil these targets and utilize the energy is to apply co-combustion or gasification of different fuels and wastes. Due to the fact that fluidized bed combustion technology offers a very high fuel flexibility and high combustion efficiency with low emissions it has become the dominating technology in co-combustion applications. This presentation will present Alhstrom`s experiences in co-combustion of biomasses in bubbling beds and Ahlstrom Pyroflow circulating fluidized beds based on about 200 operating references worldwide. CFB gasification will also be discussed 9 refs.

  4. Power generation from biomass: Status report on catalytic-allothermal wood gasification. Papers; Energetische Nutzung von Biomasse: Stand der Realisierung der katalytisch-allothermen Holzvergasung. Vortraege

    Energy Technology Data Exchange (ETDEWEB)

    Spindler, H.; Bauermeister, U.; Kliche, H.; Seiffarth, K. (comps.)

    2001-12-01

    The topic of this event is bound up with the activities of FOeST in the field of gasification of biomass in decentralized small plants (< 2 MW{sub el}). The start project was a research work in 1993 to select a gasification process for using wood, sludge or plastic waste, continued 1995 by a research project with gasification tests of tar oil contaminated wood in a small gasification reactor with good results in environmental compatibility. But the following planning process of a demonstration plant for 500 kW{sub el} has shown, that the biomass gasification couldn't reach economic efficiency. Due to the development of an catalytic-partial allothermal gasification process of GNS ltd. it was clear, that the technical efficiency could be increased considerably. So, in 2000, a project started to test this catalytic-partial allothermal gasification in a pilot plant. Today the results of research, development and testing of biomass gasification with catalytic-partial allothermal processing as well as practically experience with a gasification plant, general conditions and further activities for energetically utilisation of biomass in Saxonia-Anhalt will be presented. (orig.)

  5. Experimental investigations of biomass gasification with carbon-dioxide

    Science.gov (United States)

    Sircar, Indraneel

    A sustainable energy cycle may include enhanced utilization of solar energy and atmospheric CO2 to produce biomass and enhanced utilization of exhaust CO2 from power plants for synthetic gas production. The reaction of carbon with CO2 is potentially one of the important processes in a future sustainable carbon cycle. Reactions involving carbon and CO2 are also relevant to the chemical process and metal industries. Biomass char has been recognized as a present and future alternative to fossil-fuels for energy production and fuel synthesis. Therefore, biomass char gasification with CO2 recycling is proposed as a sustainable and carbon-neutral energy technology. Biomass char is a complex porous solid and its gasification involves heat and mass transfer processes within pores of multiple sizes from nanometer to millimeter scales. These processes are coupled with heterogeneous chemistry at the internal and external surfaces. Rates for the heterogeneous carbon gasification reactions are affected by inorganic content of the char. Furthermore, pore structure of the char develops with conversion and influences apparent gasification rates. Effective modeling of the gasification reactions has relied on the best available understanding of diffusion processes and kinetic rate property constants from state of the art experiments. Improvement of the influences of inorganic composition, and process parameters, such as pressure and temperature on the gasification reaction rates has been a continuous process. Economic viability of gasification relies on use of optimum catalysts. These aspects of the current status of gasification technologies have motivated the work reported in this dissertation. The reactions between biomass chars and CO2 are investigated to determine the effects of temperature and pressure on the reaction rates for large char particles of relevance to practical gasification technologies. An experimental apparatus consisting of a high-pressure fixed-bed reactor

  6. Post-lumpectomy CT-guided tumor bed delineation for breast boost and partial breast irradiation: Can additional pre- and postoperative imaging reduce interobserver variability?

    Science.gov (United States)

    DEN Hartogh, Mariska D; Philippens, Marielle E P; VAN Dam, Iris E; Kleynen, Catharina E; Tersteeg, Robbert J H A; Kotte, Alexis N T J; VAN Vulpen, Marco; VAN Asselen, Bram; VAN DEN Bongard, Desirée H J G

    2015-11-01

    For breast boost radiotherapy or accelerated partial breast irradiation, the tumor bed (TB) is delineated by the radiation oncologist on a planning computed tomography (CT) scan. The aim of the present study was to investigate whether the interobserver variability (IOV) of the TB delineation is reduced by providing the radiation oncologist with additional magnetic resonance imaging (MRI) or CT scans. A total of 14 T1-T2 breast cancer patients underwent a standard planning CT in the supine treatment position following lumpectomy, as well as additional pre- and postoperative imaging in the same position. Post-lumpectomy TBs were independently delineated by four breast radiation oncologists on standard postoperative CT and on CT registered to an additional imaging modality. The additional imaging modalities used were postoperative MRI, preoperative contrast-enhanced (CE)-CT and preoperative CE-MRI. A cavity visualization score (CVS) was assigned to each standard postoperative CT by each observer. In addition, the conformity index (CI), volume and distance between centers of mass (dCOM) of the TB delineations were calculated. On CT, the median CI was 0.57, with a median volume of 22 cm 3 and dCOM of 5.1 mm. The addition of postoperative MRI increased the median TB volume significantly to 28 cm 3 (P<0.001), while the CI (P=0.176) and dCOM (P=0.110) were not affected. The addition of preoperative CT or MRI increased the TB volume to 26 and 25 cm 3 , respectively (both P<0.001), while the CI increased to 0.58 and 0.59 (both P<0.001) and the dCOM decreased to 4.7 mm (P=0.004) and 4.6 mm (P=0.001), respectively. In patients with CVS≤3, the median CI was 0.40 on CT, which was significantly increased by all additional imaging modalities, up to 0.52, and was accompanied by a median volume increase up to 6 cm 3 . In conclusion, the addition of postoperative MRI, preoperative CE-CT or preoperative CE-MRI did not result in a considerable reduction in the IOV in postoperative CT

  7. Wood biomass gasification in the world today

    International Nuclear Information System (INIS)

    Nikolikj, Ognjen; Perishikj, Radovan; Mikulikj, Jurica

    1999-01-01

    Today gasification technology of different kinds represents a more and more interesting option of the production of energy forms. The article describes a biomass gasification plant (waste wood) Sydkraft, Vernamo from Sweden. (Author)

  8. Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems

    Energy Technology Data Exchange (ETDEWEB)

    1990-12-01

    The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

  9. Survey of biomass gasification. Volume II. Principles of gasification

    Energy Technology Data Exchange (ETDEWEB)

    Reed, T.B. (comp.)

    1979-07-01

    Biomass can be converted by gasification into a clean-burning gaseous fuel that can be used to retrofit existing gas/oil boilers, to power engines, to generate electricity, and as a base for synthesis of methanol, gasoline, ammonia, or methane. This survey describes biomass gasification, associated technologies, and issues in three volumes. Volume I contains the synopsis and executive summary, giving highlights of the findings of the other volumes. In Volume II the technical background necessary for understanding the science, engineering, and commercialization of biomass is presented. In Volume III the present status of gasification processes is described in detail, followed by chapters on economics, gas conditioning, fuel synthesis, the institutional role to be played by the federal government, and recommendations for future research and development.

  10. Ash behaviour in fluidized bed gasification and combustion: release of harmful trace elements and the behavior of alkalis; Tuhkan muuntuminen leijukerroskaasutuksessa ja -poltossa: Haitallisten hivenmetallien vapautuminen ja alkalien kaeyttaeytyminen

    Energy Technology Data Exchange (ETDEWEB)

    Kauppinen, E.; Valmari, T. [VTT Chemical Technology, Espoo (Finland)

    1997-10-01

    During 1996 the behaviour of alkaline metals (K and Na) during circulating fluidized bed combustion of forest residue was studied in a real-scale plant using aerosol measurement instruments (filters, impactor, DMA). Prior to heat exchangers (850 deg C) the ash mass-concentration was 1.0 - 1.3 g/Nm{sup 3} with 1 % of ash forming constituents as vapours. At least 98 % of sulphur, over 90 % of sodium and over 80 % of potassium were found in particulate phase prior to heat exchangers. On the other hand, at least 80 % of the chlorine was in vapour phase. 98 % of the ash was in coarse (> 0.3 {mu}m) particles. Coarse ash particles had an irregular surface structure often consisting of fine primary particles. The remaining 2 % was observed in fine particles of about 0.1 {mu}m. Both rounded and cornered (suggesting crystal structure) fine particles were found. The fine particles were composed of alkali chlorides and sulphates, mainly of KCl. About 80 % of the ash on mass basis was deposited onto heat exchanger surfaces when soot-blowing was not carried out. Practically all of the particles larger than 10 {mu}m were deposited. The deposition was less significant for smaller particles. The fine particle concentration before and after the heat exchangers was the same within the experimental inaccuracy. The deposited fraction of potassium, sodium and sulphur was about the same than that of the total ash: However, the deposition of chlorine was much lower since the chlorine content was low in the coarse particles that were deposited most effectively. (orig.)

  11. The assessment of sewage sludge gasification by-products toxicity by ecotoxicologial test.

    Science.gov (United States)

    Werle, Sebastian; Dudziak, Mariusz

    2015-08-01

    The process of gasification of sewage sludge generates by-products, which may be contaminated with toxic and hazardous substances, both organic and inorganic. It is therefore important to assess the environmental risk associated with this type of waste. The feasibility of using an ecotoxicological tests for this purpose was determined in the presented study. The applied tests contained indicator organisms belonging to various biological groups (bacteria, crustaceans, plants). The subject of the study were solid (ash, char) and liquid (tar) by-products generated during gasification (in a fixed bed reactor) of dried sewage sludge from various wastewater treatment systems. The tested samples were classified based on their toxic effect. The sensitivity of the indicator organisms to the tested material was determined. In-house procedures for the preparation for toxicity analysis of both sewage sludge and by-products generated during the gasification were presented. The scope of work also included the determination of the effect of selected process parameters (temperature, amount of gasifying agent) on the toxicity of gasification by-products depending on the sewage sludge source. It was shown that both the type of sewage sludge and the parameters of the gasification process affects the toxicity of the by-products of gasification. However, the results of toxicity studies also depend on the type of ecotoxicological test used, which is associated with a different sensitivity of the indicator organisms. Nevertheless, it may be concluded that the by-products formed during the gasification of the low toxicity sewage sludge can be regarded as non-toxic or low toxic. However, the results analysis of the gasification of the toxic sludge were not conclusive, which leads to further research needs in this area. © The Author(s) 2015.

  12. The shell coal gasification process

    Energy Technology Data Exchange (ETDEWEB)

    Koenders, L.O.M.; Zuideveld, P.O. [Shell Internationale Petroleum Maatschappij B.V., The Hague (Netherlands)

    1995-12-01

    Future Integrated Coal Gasification Combined Cycle (ICGCC) power plants will have superior environmental performance and efficiency. The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an ICGCC plant. SCGP flexibility has been demonstrated for high-rank bituminous coals to low rank lignites and petroleum coke, and the process is well suited for combined cycle power generation, resulting in efficiencies of 42 to 46% (LHV), depending on choice of coal and gas turbine efficiency. In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology has been built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N.V. Sep). The construction of the unit was completed end 1993 and is now followed by start-up and a 3 year demonstration period, after that the plant will be part of the Dutch electricity generating system.

  13. Characteristics and utilisation of high-temperature (HTHP) filter dusts from pfb gasification of biomass

    Energy Technology Data Exchange (ETDEWEB)

    Ranta, J. [VTT Energy, Espoo (Finland)

    1996-12-31

    The aim of the study was to survey characteristics, utilisation and possible environmental impacts of solid wastes, i.e., in case of biomass, mainly high-temperature filter ash (HTHP) from pressurised fluidised-bed gasification (PFBG). The aim is to utilise solid wastes (slag, filter dust, additives) from biomass gasification instead of dumping. One alternative is recycling to the soil as liming material or fertiliser. It is expected that the ash recycled to forest soils changes the environment less than non-recycled ash. (orig.) 3 refs.

  14. Thermodynamic Analysis of an Integrated Gasification Solid Oxide Fuel Cell Plant with a Kalina Cycle

    DEFF Research Database (Denmark)

    Pierobon, Leonardo; Rokni, Masoud

    2015-01-01

    A hybrid plant that consists of a gasification system, Solid Oxide Fuel Cells (SOFC) and a Simple Kalina Cycle (SKC) is investigated. Woodchips are introduced into a fixed bed gasification plant to produce syngas, which is then fed into an integrated SOFC-SKC plant to produce electricity. The pre......-treated fuel then enters the anode side of the SOFC. Complete fuel oxidation is ensured in a burner by off-gases exiting the SOFC stacks. Off-gases are utilized as heat source for a SKC where a mixture of ammonia and water is expanded in a turbine to produce additional electric power. Thus, a triple novel...

  15. 3rd international conference on coal gasification and liquefaction, University of Pittsburgh

    Energy Technology Data Exchange (ETDEWEB)

    None

    1976-01-01

    The third annual international conference on ''Coal Gasification and Liquefaction: What Needs to be Done Now'' was held at the University of Pittsburgh, Pittsburgh, PA on August 3-5, 1976. The majority of the papers dealt with coal gasification and liquefaction (often on the basis of process pilot plant experience) and on flue gas desulfurization by a variety of processes; fewer papers involved fluidized bed combustion, combined cycle power plants, coal desulfurization, government policy on environmental effects and on synthetic fuels, etc. Twenty-eight papers have been entered individually into EDB and ERA. (LTN)

  16. Glas generator for the steam gasification of coal with nuclear generated heat

    International Nuclear Information System (INIS)

    Buchner, G.

    1980-01-01

    The use of heat from a High Temperature Reactor (HTR) for the steam gasification of coal saves coal, which otherwise is burnt to generate the necessary reaction heat. The gas generator for this process, a horizontal pressure vessel, contains a fluidized bed of coal and steam. An ''immersion-heater'' type of heat exchanger introduces the nuclear generated heat to the process. Some special design problems of this gasifier are presented. Reference is made to the present state of development of the steam gasification process with heat from high temperature reactors. (author)

  17. Leaching From Biomass Gasification Residues

    DEFF Research Database (Denmark)

    Allegrini, Elisa; Boldrin, Alessio; Polletini, A.

    2011-01-01

    The aim of the present work is to attain an overall characterization of solid residues from biomass gasification. Besides the determination of chemical and physical properties, the work was focused on the study of leaching behaviour. Compliance and pH-dependence leaching tests coupled with geoche......The aim of the present work is to attain an overall characterization of solid residues from biomass gasification. Besides the determination of chemical and physical properties, the work was focused on the study of leaching behaviour. Compliance and pH-dependence leaching tests coupled...

  18. Gasification of biomass for energy production. State of technology in Finland and global market perspectives

    International Nuclear Information System (INIS)

    Wilen, C.; Kurkela, E.

    1997-01-01

    This report reviews the development of the biomass gasification technology in Finland over the last two decades. Information on Finnish biomass resources and use, energy economy and national research policy is provided as background. Global biomass resources and potential energy from biomass markets are also assessed based on available literature, to put the development of the gasification technology into a wider perspective of global biomass utilization for energy production. The increasing use of biomass and other indigenous forms of energy has been part and parcel of the Finnish energy policy for some twenty years. Biomass and peat account for almost 20% of the production of primary energy in Finland. As the consumption of biofuels is significantly lower than the annual growth or renewal, the use of bioenergy is considered to be an important measure of reducing carbon dioxide emissions. Research and development on thermal gasification of solid fuels was initiated in the late 1970s in Finland. The principal aim was to decrease the dependence of Finnish energy economy on imported oil by increasing the utilization potential of indigenous fuels. Development in the early 1980s focused on simple atmospheric-pressure fuel gas applications including a gasification heating plant. Eight Bioneer updraft gasifiers (abt 5 MW th ) were constructed in 1982-1986, and a new Bioneer gasifier was commissioned in eastern Finland in 1996. A Pyroflow circulating fluidised-bed gasifies was also commercialized in the mid-1980s; four gasifiers (15-35 MW th ) were commissioned. In the late 1980s the interest in integrated gasification combined-cycle (IGCC) power plants, based on pressurised air gasification of biomass and hot gas cleanup, increased in Finland and in many other countries. The utilization potential for indigenous fuels is mainly in medium-scale combined heat and electricity production (20-150 MW,). Foster Wheeler Energia Oy, Carbona Inc. and Imatran Voima Oy are the main

  19. Gasification of biomass for energy production. State of technology in Finland and global market perspectives

    Energy Technology Data Exchange (ETDEWEB)

    Wilen, C.; Kurkela, E. [VTT Energy, Espoo (Finland). Energy Production Technologies

    1997-12-31

    This report reviews the development of the biomass gasification technology in Finland over the last two decades. Information on Finnish biomass resources and use, energy economy and national research policy is provided as background. Global biomass resources and potential energy from biomass markets are also assessed based on available literature, to put the development of the gasification technology into a wider perspective of global biomass utilization for energy production. The increasing use of biomass and other indigenous forms of energy has been part and parcel of the Finnish energy policy for some twenty years. Biomass and peat account for almost 20% of the production of primary energy in Finland. As the consumption of biofuels is significantly lower than the annual growth or renewal, the use of bioenergy is considered to be an important measure of reducing carbon dioxide emissions. Research and development on thermal gasification of solid fuels was initiated in the late 1970s in Finland. The principal aim was to decrease the dependence of Finnish energy economy on imported oil by increasing the utilization potential of indigenous fuels. Development in the early 1980s focused on simple atmospheric-pressure fuel gas applications including a gasification heating plant. Eight Bioneer updraft gasifiers (abt 5 MW{sub th}) were constructed in 1982-1986, and a new Bioneer gasifier was commissioned in eastern Finland in 1996. A Pyroflow circulating fluidised-bed gasifies was also commercialized in the mid-1980s; four gasifiers (15-35 MW{sub th}) were commissioned. In the late 1980s the interest in integrated gasification combined-cycle (IGCC) power plants, based on pressurised air gasification of biomass and hot gas cleanup, increased in Finland and in many other countries. The utilization potential for indigenous fuels is mainly in medium-scale combined heat and electricity production (20-150 MW,). Foster Wheeler Energia Oy, Carbona Inc. and Imatran Voima Oy are

  20. Biomass gasification hot gas cleanup for power generation

    Energy Technology Data Exchange (ETDEWEB)

    Wiant, B.C.; Bachovchin, D.M. [Westinghouse Electric Corp., Orlando, FL (United States); Carty, R.H.; Onischak, M. [Institute of Gas Technology, Chicago, IL (United States); Horazak, D.A. [Gilbert/Commonwealth, Reading, PA (United States); Ruel, R.H. [The Pacific International Center for High Technology Research, Honolulu, HI (United States)

    1993-12-31

    In support of the US Department of Energy`s Biomass Power Program, a Westinghouse Electric led team consisting of the Institute of Gas Technology (IGT), Gilbert/Commonwealth (G/C), and the Pacific International Center for High Technology Research (PICHTR), is conducting a 30 month research and development program. The program will provide validation of hot gas cleanup technology with a pressurized fluidized bed, air-blown, biomass gasifier for operation of a gas turbine. This paper discusses the gasification and hot gas cleanup processes, scope of work and approach, and the program`s status.

  1. The study of reactions influencing the biomass steam gasification process

    Energy Technology Data Exchange (ETDEWEB)

    C. Franco; F. Pinto; I. Gulyurtlu; I. Cabrita [INETI-DEECA, Lisbon (Portugal)

    2003-05-01

    Steam gasification studies were carried out in an atmospheric fluidised bed. The gasifier was operated over a temperature range of 700 900{sup o}C whilst varying a steam/biomass ratio from 0.4 to 0.85 w/w. Three types of forestry biomass were studied: Pinus pinaster (softwood), Eucalyptus globulus and holm-oak (hardwood). The energy conversion, gas composition, higher heating value and gas yields were determined and correlated with temperature, steam/biomass ratio, and species of biomass used. The results obtained seemed to suggest that the operating conditions were optimised for a gasification temperature around 830{sup o}C and a steam/biomass ratio of 0.6 0.7 w/w, because a gas richer in hydrogen and poorer in hydrocarbons and tars was produced. These conditions also favoured greater energy and carbon conversions, as well the gas yield. The main objective of the present work was to determine what reactions were dominant within the operation limits of experimental parameters studied and what was the effect of biomass type on the gasification process. As biomass wastes usually have a problem of availability because of seasonal variations, this work analysed the possibility of replacing one biomass species by another, without altering the gas quality obtained. 19 refs., 8 figs. 2 tabs.

  2. UTILIZATION OF LIGHTWEIGHT MATERIALS MADE FROM COAL GASIFICATION SLAGS

    Energy Technology Data Exchange (ETDEWEB)

    Vas Choudhry; Stephen Kwan; Steven R. Hadley

    2001-07-01

    The objective of the project entitled ''Utilization of Lightweight Materials Made from Coal Gasification Slags'' was to demonstrate the technical and economic viability of manufacturing low-unit-weight products from coal gasification slags which can be used as substitutes for conventional lightweight and ultra-lightweight aggregates. In Phase I, the technology developed by Praxis to produce lightweight aggregates from slag (termed SLA) was applied to produce a large batch (10 tons) of expanded slag using pilot direct-fired rotary kilns and a fluidized bed calciner. The expanded products were characterized using basic characterization and application-oriented tests. Phase II involved the demonstration and evaluation of the use of expanded slag aggregates to produce a number of end-use applications including lightweight roof tiles, lightweight precast products (e.g., masonry blocks), structural concrete, insulating concrete, loose fill insulation, and as a substitute for expanded perlite and vermiculite in horticultural applications. Prototypes of these end-use applications were made and tested with the assistance of commercial manufacturers. Finally, the economics of expanded slag production was determined and compared with the alternative of slag disposal. Production of value-added products from SLA has a significant potential to enhance the overall gasification process economics, especially when the avoided costs of disposal are considered.

  3. Diesel power plants based on biomass gasification; Biomassan ja turpeen kaasutukseen perustuvien dieselvoimalaitosten toteutettavuustutkimus

    Energy Technology Data Exchange (ETDEWEB)

    Kurkela, E.; Staahlberg, P.; Solantausta, Y.; Wilen, C.

    1995-12-31

    Different power production systems have been developed for biomass feedstocks. However, only few of these systems can meet the following three requirements: (a) suitability to small scale electricity production (< 5-10 MWe), (b) reliable operation with realistically available biomass feedstocks, and (c) potential for economical competitiveness. The fluidized-bed boilers have been successfully operated with wood waste and peat down to outputs of the order of 5 MWe and the investment costs have been successfully lowered to a reasonable level. However, this concept is most suitable for combined heat and electricity production and smaller plant sizes are not considered feasible. One of the most promising alternative for this commercially proven technology is the diesel power plant based on gasification. This concept has a potential for higher power to heat ratios in cogeneration or higher efficiency in separate electricity production. The objectives of this project were (a) to evaluate the technical and economical feasibility of diesel power plants based on biomass gasification and (b) to study the effects of operating conditions (temperature, bed material and air staging) on the performance of a circulating fluidized-bed gasifier. The experimental part of the project was carried out on a new PDU-scale Circulating Fluidized-Bed Gasification test facility of VTT. Wood residues were used as the feedstocks and the experiments were mainly focused on tar formation and gasifier performance. The results will be compared to earlier VTT data obtained for bubbling-bed reactors. The techno-economic feasibility studies are carried out using existing process modelling tools of VTT and the gasification based diesel plants will be compared to conventional fluidized-bed boilers

  4. Diesel power plants based on biomass gasification; Biomassan ja turpeen kaasutukseen perustuen dieselvoimalaitosten toteutettavuustutkimus

    Energy Technology Data Exchange (ETDEWEB)

    Kurkela, E.; Staahlberg, P.; Solantausta, Y. [VTT Energy, Espoo (Finland)

    1996-12-01

    Different power production systems have been developed for biomass feedstocks. However, only few of these systems can meet the following three requirements: (1) suitability to small scale electricity production (<5-10 MWe), (2) reliable operation with realistically available biomass feedstocks, and (3) potential for economical competitiveness. The fluidized-bed boilers have been successfully operated with wood waste and peat down to outputs of the order of 5 MWe and the investment costs have been successfully lowered to a reasonable level. However, this concept is most suitable for combined heat and electricity production and smaller plant sizes are not considered feasible. One of the most promising alternative for this commercially proven technology is the diesel power plant based on gasification. This concept has a potential for higher power to heat ratios in cogeneration or higher efficiency in separate electricity production. The objectives of this project were (1) to evaluate the technical and economical feasibility of diesel power plants based on biomass gasification and (2) to study the effects of operating conditions (temperature, bed material and air staging) on the performance of a circulating fluidized-bed gasifier. The experimental part of the project was carried out on a new PDU-scale Circulating Fluidized-Bed Gasification test facility of VTT. Wood residues were used as the feedstocks and the experiments were mainly focused on tar formation and gasifier performance. The results will be compared to earlier VTT data obtained for bubbling-bed reactors. The techno-economic feasibility studies are carried out using existing process modelling tools of VTT and the gasification based diesel plants will be compared to conventional fluidized-bed boilers. The studies are scheduled to be completed in March 1996. (author)

  5. The carbon dioxide gasification characteristics of biomass char samples and their effect on coal gasification reactivity during co-gasification.

    Science.gov (United States)

    Mafu, Lihle D; Neomagus, Hein W J P; Everson, Raymond C; Okolo, Gregory N; Strydom, Christien A; Bunt, John R

    2017-12-18

    The carbon dioxide gasification characteristics of three biomass char samples and bituminous coal char were investigated in a thermogravimetric analyser in the temperature range of 850-950 °C. Char SB exhibited higher reactivities (R i , R s , R f ) than chars SW and HW. Coal char gasification reactivities were observed to be lower than those of the three biomass chars. Correlations between the char reactivities and char characteristics were highlighted. The addition of 10% biomass had no significant impact on the coal char gasification reactivity. However, 20 and 30% biomass additions resulted in increased coal char gasification rate. During co-gasification, chars HW and SW caused increased coal char gasification reactivity at lower conversions, while char SB resulted in increased gasification rates throughout the entire conversion range. Experimental data from biomass char gasification and biomass-coal char co-gasification were well described by the MRPM, while coal char gasification was better described by the RPM. Copyright © 2018 Elsevier Ltd. All rights reserved.

  6. BIMOMASS GASIFICATION PILOT PLANT STUDY

    Science.gov (United States)

    The report gives results of a gasification pilot program using two biomass feedstocks: bagasse pellets and wood chips. he object of the program was to determine the properties of biomass product gas and its suitability as a fuel for gas-turbine-based power generation cycles. he f...

  7. Biomass gasification in the Netherlands

    Energy Technology Data Exchange (ETDEWEB)

    Van der Drift, A. [ECN Biomass and Energy Efficiency, Petten (Netherlands)

    2013-07-15

    This reports summarizes the activities, industries, and plants on biomass gasification in the Netherlands. Most of the initiatives somehow relate to waste streams, rather than clean biomass, which may seem logic for a densely populated country as the Netherlands. Furthermore, there is an increasing interest for the production of SNG (Substitute Natural Gas) from biomass, both from governments and industry.

  8. Catalytic gasification of oil-extracted residue biomass of Botryococcus braunii.

    Science.gov (United States)

    Watanabe, Hideo; Li, Dalin; Nakagawa, Yoshinao; Tomishige, Keiichi; Watanabe, Makoto M

    2015-09-01

    Catalytic gasification of the oil-extracted residue biomass of Botryococcus braunii was demonstrated in a laboratory-scale continuous feeding dual bed reactor. Steam gasification at 1023 K over Ni-Fe/Mg/Al catalyst can completely reform tar derived from pyrolysis of the residue biomass into C1 gases and hydrogen, and has achieved 91%-C conversion to gaseous product (CO+CO2+CH4). Composition of product gas has higher contents of CO and H2 with their ratio (H2/CO) of around 2.4 which is slightly H2-rich syngas. Maximum hydrogen yield of 74.7 mmol g-biomass(-1) obtained in this work is much higher than that from gasification of other algal biomass reported in literature. The residue biomass of B. braunii can be a superior renewable source of syngas or hydrogen. Copyright © 2015 Elsevier Ltd. All rights reserved.

  9. Effect of biomass containing zinc metal at different operating parameters on gasification efficiency.

    Science.gov (United States)

    Lin, Chiou-Liang; Chen, Hsien

    2015-01-01

    This paper describes the effect of Zn on the gas production of a fluidized-bed gasifier to determine the relationship between Zn and the gasification process. Different concentrations of Zn were used in the preparation of artificial waste to elucidate the effect on gas product composition, gas product heat value, gas production rate, and H2 yield in the gasification process. Zn served to increase H2 generation during the gasification process. The molar percentage of H2 with more than 0.1 wt% additional Zn increased by 33.02% and the H2 yield was increased by 11.34% compared to that without Zn. However, the gas heat value decreased, and no significant change in the gas production rate was noted.

  10. Pyrolysis and gasification-melting of automobile shredder residue.

    Science.gov (United States)

    Roh, Seon Ah; Kim, Woo Hyun; Yun, Jin Han; Min, Tae Jin; Kwak, Yeon Ho; Seo, Yong Chil

    2013-10-01

    Automobile shredder residue (ASR) from end-of-life vehicles (ELVs) in Korea has commonly been disposed of in landfills. Due to the growing number of scrapped cars and the decreasing availability of landfill space, effective technology for reducing ASR is needed. However ASR is a complex mixture, and finding an appropriate treatment is not easy on account of the harmful compounds in ASR. Therefore, research continues to seek an effective treatment technology. However most studies have thus far been performed in the laboratory, whereas few commercial and pilot studies have been performed. This paper studies the pyrolysis and gasification-melting of ASR. The pyrolyis characteristics have been analyzed in a thermogravimetric analyzer (TGA), a Lindberg furnace, and a fixed-bed pyrolyzer to study the fundamental characteristics of ASR thermal conversion. As a pilot study, shaft-type gasification-melting was performed. High-temperature gasification-melting was performed in a 5000 kg/day pilot system. The gas yield and syngas (H2 and CO) concentration increase when the reaction temperature increases. Gas with a high calorific value of more than 16,800 kJ/m3 was produced in the pyrolyzer. From the gasification-melting process, syngas of CO (30-40%) and H2(10-15%) was produced, with 5% CH4 produced as well. Slag generation was 17% of the initial ASR, with 5.8% metal content and 4% fly ash. The concentration of CO decreases, whereas the H2, CO2, and CH4 concentrations increase with an increase in the equivalence ratio (ER). The emission levels of dioxin and air pollution compounds except nitrogen oxides (NO(x)) were shown to satisfy Korean regulations.

  11. Multicriteria Optimization of Gasification Operational Parameters Using a Pareto Genetic Algorithm

    Directory of Open Access Journals (Sweden)

    Miguel Caldas

    2005-04-01

    Full Text Available Gasification is a well-known technology that allows for a combustible gas to be obtained from a carbonaceous fuel by a partial oxidation process (POX. The resulting gas (synthesis gas or syngas can be used either as a fuel or as a feedstock for chemical production. Recently, gasification has also received a great deal of attention concerning power production possibilities through IGCC process (Integrated Gasification Combined Cycle, which is currently the most environmentally friendly and efficient method for the production of electricity. Gasification allows for low grade fuels, or dirty fuels, to be used in an environmental acceptable way. Amongst these fuels are wastes from the petrochemical and other industries, which vary in composition from shipment to shipment, and from lot to lot. If operating conditions are kept constant this could result in lose of efficiency. This paper presents an application of Genetic Algorithms to optimize the operating parameters of a gasifier processing a given fuel, so that the system achieves maximum efficiency for each particular fuel composition. A Pareto multiobjective optimization method, combined with a Genetic Algorithm, is applied to the simultaneous maximization of two different objective functions: Cold Gas Efficiency and Hydrogen Contents of the syngas. Results show that the optimization method developed is fast and simple enough to be used for on-line adjustment of the gasification operating parameters for each fuel composition and aim of gasification, thus improving overall performance of the industrial process.

  12. Energetic recovery from LNG gasification plant : cold energy utilization in agro-alimentary industry

    International Nuclear Information System (INIS)

    Messineo, A.; Panno, D.

    2009-01-01

    It is known how the complete gasification of liquefied natural gas (LNG) can return about 230 kWh/t of energy. Nevertheless out of 51 gasification plants in the world, only 31 of them are equipped with systems for the partial recovery of the available energy. At the moment most of these plants mainly produce electric energy; however the employment of the cold energy results very interesting, in fact, it can be recovered for agrofood transformation and conservation as well as for some loops in the cold chain. Cold energy at low temperatures requires high amounts of mechanical energy and it unavoidably increases as the required temperature diminishes. Cold energy recovery from LNG gasification would allow considerable energy and economic savings to these applications, as well as environmental benefits due to the reduction of climate-changing gas emissions. The task of this work is to assess the possibility to create around a gasification plant an industrial site for firms working on the transformation and conservation of agrofood products locally grown. The cold recovered from gasification would be distributed to those firms through an opportune liquid Co 2 network distribution capable of supplying the cold to the different facilities. A LNG gasification plant in a highly agricultural zone in Sicily would increase the worth of the agrofood production, lower transformation and conservation costs when compared to the traditional systems and bring economic and environmental benefits to the interested areas. [it

  13. Biomass waste gasification - can be the two stage process suitable for tar reduction and power generation?

    Science.gov (United States)

    Sulc, Jindřich; Stojdl, Jiří; Richter, Miroslav; Popelka, Jan; Svoboda, Karel; Smetana, Jiří; Vacek, Jiří; Skoblja, Siarhei; Buryan, Petr

    2012-04-01

    A pilot scale gasification unit with novel co-current, updraft arrangement in the first stage and counter-current downdraft in the second stage was developed and exploited for studying effects of two stage gasification in comparison with one stage gasification of biomass (wood pellets) on fuel gas composition and attainable gas purity. Significant producer gas parameters (gas composition, heating value, content of tar compounds, content of inorganic gas impurities) were compared for the two stage and the one stage method of the gasification arrangement with only the upward moving bed (co-current updraft). The main novel features of the gasifier conception include grate-less reactor, upward moving bed of biomass particles (e.g. pellets) by means of a screw elevator with changeable rotational speed and gradual expanding diameter of the cylindrical reactor in the part above the upper end of the screw. The gasifier concept and arrangement are considered convenient for thermal power range 100-350 kW(th). The second stage of the gasifier served mainly for tar compounds destruction/reforming by increased temperature (around 950°C) and for gasification reaction of the fuel gas with char. The second stage used additional combustion of the fuel gas by preheated secondary air for attaining higher temperature and faster gasification of the remaining char from the first stage. The measurements of gas composition and tar compound contents confirmed superiority of the two stage gasification system, drastic decrease of aromatic compounds with two and higher number of benzene rings by 1-2 orders. On the other hand the two stage gasification (with overall ER=0.71) led to substantial reduction of gas heating value (LHV=3.15 MJ/Nm(3)), elevation of gas volume and increase of nitrogen content in fuel gas. The increased temperature (>950°C) at the entrance to the char bed caused also substantial decrease of ammonia content in fuel gas. The char with higher content of ash leaving the

  14. Single and multi-component adsorption of salicylic acid, clofibric acid, carbamazepine and caffeine from water onto transition metal modified and partially calcined inorganic-organic pillared clay fixed beds.

    Science.gov (United States)

    Cabrera-Lafaurie, Wilman A; Román, Félix R; Hernández-Maldonado, Arturo J

    2015-01-23

    Fixed-beds of transition metal (Co(2+), Ni(2+) or Cu(2+)) inorganic-organic pillared clays (IOCs) were prepared to study single- and multi-component non-equilibrium adsorption of a set of pharmaceutical and personal care products (PPCPs: salicylic acid, clofibric acid, carbamazepine and caffeine) from water. Adsorption capacities for single components revealed that the copper(II) IOCs have better affinity toward salicylic and clofibric acid. However, multi-component adsorption tests showed a considerable decrease in adsorption capacity for the acids and an unusual selectivity toward carbamazepine depending on the transition metal. This was attributed to a combination of competition between PPCPs for adsorption sites, adsorbate-adsorbate interactions, and plausible pore blocking caused by carbamazepine. The cobalt(II) IOC bed that was partially calcined to fractionate the surfactant moiety showcased the best selectivity toward caffeine, even during multi-component adsorption. This was due to a combination of a mildly hydrophobic surface and interaction between the PPCP and cobalt(II). In general, the tests suggest that these IOCs may be a potential solution for the removal of PPCPs if employed in a layered-bed configuration, to take care of families of adsorbates in a sequence that would produce sharpened concentration wavefronts. Copyright © 2014 Elsevier B.V. All rights reserved.

  15. Gasification biochar as a valuable by-product for carbon sequestration and soil amendment

    International Nuclear Information System (INIS)

    Hansen, Veronika; Müller-Stöver, Dorette; Ahrenfeldt, Jesper; Holm, Jens Kai; Henriksen, Ulrik Birk; Hauggaard-Nielsen, Henrik

    2015-01-01

    Thermal gasification of various biomass residues is a promising technology for combining bioenergy production with soil fertility management through the application of the resulting biochar as soil amendment. In this study, we investigated gasification biochar (GB) materials originating from two major global biomass fuels: straw gasification biochar (SGB) and wood gasification biochar (WGB), produced by a Low Temperature Circulating Fluidized Bed gasifier (LT-CFB) and a TwoStage gasifier, respectively, optimized for energy conversion. Stability of carbon in GB against microbial degradation was assessed in a short-term soil incubation study and compared to the traditional practice of direct incorporation of cereal straw. The GBs were chemically and physically characterized to evaluate their potential to improve soil quality parameters. After 110 days of incubation, about 3% of the added GB carbon was respired as CO 2 , compared to 80% of the straw carbon added. The stability of GB was also confirmed by low H/C and O/C atomic ratios with lowest values for WGB (H/C 0.12 and O/C 0.10). The soil application of GBs exhibited a liming effect increasing the soil pH from ca 8 to 9. Results from scanning electron microscopy and BET analyses showed high porosity and specific surface area of both GBs, indicating a high potential to increase important soil quality parameters such as soil structure, nutrient and water retention, especially for WGB. These results seem promising regarding the possibility to combine an efficient bioenergy production with various soil aspects such as carbon sequestration and soil quality improvements. - Highlights: • Biomass gasification can combine efficient bioenergy production with valuable biochar residuals for soil improvements. • The two investigated gasification biochars are recalcitrant indicating soil carbon sequestration potential. • Gasification biochars are potential soil improvers due to high specific surface area, liming effect

  16. Operating experiences with heat-exchanging components of a semi-technical pilot plant for steam gasification of coal using heat from HTR

    International Nuclear Information System (INIS)

    Kirchhoff, R.; Heek, K.H. van

    1984-01-01

    within the framework of the PNP- Project, a semi-technical plant for the development of a process of coal gasification by means of nuclear heat was operated. Here gasification is for the first time implemented in a fluidized bed using heat of an electrically heated helium cycle at pressure up to 40 bar and temperatures normal for HTR. The plant serves for testing and developing various components as immersion heater, insulations, dosing devices, and for compiling sound data for further planning

  17. Non-catalytic co-gasification of sub-bituminous coal and biomass

    Science.gov (United States)

    Nyendu, Guevara Che

    Fluidization characteristics and co-gasification of pulverized sub-bituminous coal, hybrid poplar wood, corn stover, switchgrass, and their mixtures were investigated. Co-gasification studies were performed over temperature range from 700°C to 900°C in different media (N2, CO2, steam) using a bubbling fluidized bed reactor. In fluidization experiments, pressure drop (Delta P) observed for coal-biomass mixtures was higher than those of single coal and biomass bed materials in the complete fluidization regime. There was no systematic trend observed for minimum fluidization velocity ( Umf) with increasing biomass content. However, porosity at minimum fluidization (εmf) increased with increasing biomass content. Channeling effects were observed in biomass bed materials and coal bed with 40 wt.% and 50 wt.% biomass content at low gas flowrates. The effect of coal pressure overshoot reduced with increasing biomass content. Co-gasification of coal and corn stover mixtures showed minor interactions. Synergetic effects were observed with 10 wt.% corn stover. Coal mixed with corn stover formed agglomerates during co-gasification experiments and the effect was severe with increase in corn stover content and at 900°C. Syngas (H2 + CO) concentrations obtained using CO2 as co-gasification medium were higher (~78 vol.% at 700°C, ~87 vol.% at 800°C, ~93 vol.% at 900°C) than those obtained with N2 medium (~60 vol.% at 700°C, ~65 vol.% at 800°C, ~75 vol.% at 900°C). Experiments involving co-gasification of coal with poplar showed no synergetic effects. Experimental yields were identical to predicted yields. However, synergetic effects were observed on H2 production when steam was used as the co-gasification medium. Additionally, the presence of steam increased H2/CO ratio up to 2.5 with 10 wt.% hybrid poplar content. Overall, char and tar yields decreased with increasing temperature and increasing biomass content, which led to increase in product gas.

  18. Hydrogen production from biomass gasification using biochar as a catalyst/support.

    Science.gov (United States)

    Yao, Dingding; Hu, Qiang; Wang, Daqian; Yang, Haiping; Wu, Chunfei; Wang, Xianhua; Chen, Hanping

    2016-09-01

    Biochar is a promising catalyst/support for biomass gasification. Hydrogen production from biomass steam gasification with biochar or Ni-based biochar has been investigated using a two stage fixed bed reactor. Commercial activated carbon was also studied as a comparison. Catalyst was prepared with an impregnation method and characterized by X-ray diffraction, specific surface and porosity analysis, X-ray fluorescence and scanning electron micrograph. The effects of gasification temperature, steam to biomass ratio, Ni loading and bio-char properties on catalyst activity in terms of hydrogen production were explored. The Ni/AC catalyst showed the best performance at gasification temperature of 800°C, S/B=4, Ni loading of 15wt.%. Texture and composition characterization of the catalysts suggested the interaction between volatiles and biochar promoted the reforming of pyrolysis volatiles. Cotton-char supported Ni exhibited the highest activity of H2 production (64.02vol.%, 92.08mgg(-1) biomass) from biomass gasification, while rice-char showed the lowest H2 production. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Co-gasification of coal and biomass: Synergy, characterization and reactivity of the residual char.

    Science.gov (United States)

    Hu, Junhao; Shao, Jingai; Yang, Haiping; Lin, Guiying; Chen, Yingquan; Wang, Xianhua; Zhang, Wennan; Chen, Hanping

    2017-11-01

    The synergy effect between coal and biomass in their co-gasification was studied in a vertical fixed bed reactor, and the physic-chemical structural characteristics and gasification reactivity of the residual char obtained from co-gasification were also investigated. The results shows that, conversion of the residual char and tar into gas is enhanced due to the synergy effect between coal and biomass. The physical structure of residual char shows more pore on coal char when more biomass is added in the co-gasification. The migration of inorganic elements between coal and biomass was found, the formation and competitive role of K 2 SiO 3 , KAlSiO 4 , and Ca 3 Al 2 (SiO 4 ) 3 is a mechanism behind the synergy. The graphization degree is enhanced but size of graphite crystallite in the residual char decreases with biomass blending ratio increasing. TGA results strongly suggest the big difference in the reactivity of chars derived from coal and biomass in spite of influence from co-gasification. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Comparative evaluation of kinetic, equilibrium and semi-equilibrium models for biomass gasification

    Energy Technology Data Exchange (ETDEWEB)

    Buragohain, Buljit [Center for Energy, Indian Institute of Technology Guwahati, Guwahati – 781 039, Assam (India); Chakma, Sankar; Kumar, Peeush [Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati – 781 039, Assam (India); Mahanta, Pinakeswar [Center for Energy, Indian Institute of Technology Guwahati, Guwahati – 781 039, Assam (India); Department of Mechanical Engineering, Indian Institute of Technology Guwahati, Guwahati – 781 039, Assam (India); Moholkar, Vijayanand S. [Center for Energy, Indian Institute of Technology Guwahati, Guwahati – 781 039, Assam (India); Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati – 781 039, Assam (India)

    2013-07-01

    Modeling of biomass gasification has been an active area of research for past two decades. In the published literature, three approaches have been adopted for the modeling of this process, viz. thermodynamic equilibrium, semi-equilibrium and kinetic. In this paper, we have attempted to present a comparative assessment of these three types of models for predicting outcome of the gasification process in a circulating fluidized bed gasifier. Two model biomass, viz. rice husk and wood particles, have been chosen for analysis, with gasification medium being air. Although the trends in molar composition, net yield and LHV of the producer gas predicted by three models are in concurrence, significant quantitative difference is seen in the results. Due to rather slow kinetics of char gasification and tar oxidation, carbon conversion achieved in single pass of biomass through the gasifier, calculated using kinetic model, is quite low, which adversely affects the yield and LHV of the producer gas. Although equilibrium and semi-equilibrium models reveal relative insensitivity of producer gas characteristics towards temperature, the kinetic model shows significant effect of temperature on LHV of the gas at low air ratios. Kinetic models also reveal volume of the gasifier to be an insignificant parameter, as the net yield and LHV of the gas resulting from 6 m and 10 m riser is same. On a whole, the analysis presented in this paper indicates that thermodynamic models are useful tools for quantitative assessment of the gasification process, while kinetic models provide physically more realistic picture.

  1. Texaco gasification power systems for clean energy

    International Nuclear Information System (INIS)

    Quintana, M.E.; Thone, P.W.

    1991-01-01

    The Texaco Gasification Power Systems integrate Texaco's proprietary gasification technology with proven power generation and energy recovery schemes for efficient and environmentally superior fuel utilization. Texaco's commercial experience on gasification spans a period of over 40 years. During this time, the Texaco Gasification Process has been used primarily to manufacture synthesis gas for chemical applications in one hundred commercial installations worldwide. Power generation using the Texaco Gasification Power Systems (TGPS) concept has been successfully demonstrated at the Texaco-sponsored Cool Water Coal Gasification Program in California. The environmental superiority of this technology was demonstrated by the consistent performance of Cool Water in exceeding the strict emission standards of the state of California. Currently, several TGPS projects are under evaluation worldwide for power generation in the range of 90MW to 1300MW

  2. Progress in biofuel production from gasification

    OpenAIRE

    Sikarwar, Vineet Singh; Zhao, Ming; Fennell, Paul S.; Shah, Nilay; Anthony, Edward J.

    2017-01-01

    Biofuels from biomass gasification are reviewed here, and demonstrated to be an attractive option. Recent progress in gasification techniques and key generation pathways for biofuels production, process design and integration and socio-environmental impacts of biofuel generation are discussed, with the goal of investigating gasification-to-biofuels’ credentials as a sustainable and eco-friendly technology. The synthesis of important biofuels such as bio-methanol, bio-ethanol and higher alcoho...

  3. Studies on biomass char gasification and dynamics

    Science.gov (United States)

    You, Zhanping; You, Shijun; Ma, Xiaoyan

    2018-01-01

    The gasification performances of two kinds of biomass char by experiment methods are studied, including conversion rate and gasification gas component with temperature and time. Experimental results show that gasification temperature has important effects on the conversion rate and gas component. In the range of experimental temperature, char conversion rates are no more than 30.0%. The apparent activation energies and apparent reaction frequency factors of two biomass chars are obtained through kinetic studies.

  4. Analysis of tars produced in biomass gasification

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, J.; Wang, Y.; Kinoshita, C.M. [Univ. of Hawaii, Honolulu, HI (United States)

    1993-12-31

    Parametric tests on tar formation, varying temperature, equivalence ratio, and residence time, are performed on a bench-scale, indirectly-heated fluidized bed gasifier. Prepared tar samples are analyzed in a gas chromatograph (GC) with a flame ionization detector, using a capillary column. Standards containing dominant tar species have been prepared for GC calibration. The identified peaks include single-ring hydrocarbons, such as benzene, to five-ring hydrocarbons, such as perylene; depending on the gasification conditions, the identified species represent about 70 to 90% (mass basis) of the tar constituents. Under all conditions tested, benzene and naphthalene were the most dominant species. Temperature and equivalence ratio have significant effect on tar yield and tar composition. Tar yield decreases with increasing temperature or equivalence ratio. The test results suggest that lower temperature favors the formation of more aromatic tar species with diversified substituent groups, while higher temperature favors the formation of fewer aromatic tar species without substituent groups. Higher temperature or equivalence ratio favors the formation of polyaromatic compounds. Oxygen-containing compounds exist in significant quantities only at temperature below 800{degrees}C and decrease with increasing temperature, equivalence ratio, or residence time.

  5. Co-gasification of pelletized wood residues

    Energy Technology Data Exchange (ETDEWEB)

    Carlos A. Alzate; Farid Chejne; Carlos F. Valdes; Arturo Berrio; Javier De La Cruz; Carlos A. Londono [Universidad Nacional de Colombia, Antioquia (Colombia). Grupo de Termodinamica Aplicada y Energias Alternativas

    2009-03-15

    A pelletization process was designed which produces cylindrical pellets 8 mm in length and 4 mm in diameter. These ones were manufactured using a blend of Pinus Patula and Cypress sawdust and coal in proportions of 0%, 5%, 10%, 20%, and 30% v/v of coal of rank sub-bituminous extracted from the Nech mine (Amaga-Antioquia). For this procedure, sodium carboxymethyl cellulose (CMC) was used as binder at three different concentrations. The co-gasification experiments were carried out with two kinds of mixtures, the first one was composed of granular coal and pellets of 100% wood and the second one was composed of pulverized wood and granular coal pellets. All samples were co-gasified with steam by using an electrical heated fluidized-bed reactor, operating in batches, at 850{sup o}C. The main components of the gaseous product were H{sub 2}, CO, CO{sub 2}, CH{sub 4}, and N{sub 2} with approximate quantities of 59%, 6.0%, 20%, 5.0%, and 9.0% v/v, respectively, and the higher heating values ranged from between 7.1 and 9.5 MJ/Nm{sup 3}.

  6. Experimental fact-finding in CFB biomass gasification for ECN's 500 kWth pilot-plant

    NARCIS (Netherlands)

    Kersten, Sascha R.A.; Prins, W.; van der Drift, A.; van Swaaij, Willibrordus Petrus Maria

    2003-01-01

    CFB biomass gasification has been studied by experimentation with ECN's pilot facility and a cold-flow model of this plant. Data obtained by normal operation of this plant and the results of some special experiments have provided new insight into the behavior of circulating fluidized bed reactors

  7. Simulation analysis of wastes gasification technologies

    Directory of Open Access Journals (Sweden)

    Stępień Leszek

    2017-01-01

    Full Text Available Each year a significant growth in the amount of wastes generated is observed. Due to this fact technologies enabling utilization of wastes are needed. One of the ways to utilizes wastes is thermal conversion. Most widely used technology for thermal conversion is gasification that enables to produce syngas that can be either combusted or directed to further synthesis to produce methanol or liquid fuels. There are several commercially available technologies that enable to gasify wastes. The first part of this study is subjected to general description of waste gasification process. Furthermore the analysis and comparison of commercially available gasification technologies is presented, including their process arrangement, limits and capabilities. Second part of the study is dedicated to the development of thermodynamic model for waste gasification. The model includes three zones of gasification reactors: drying, gasification and eventually ash melting. Modified Gibbs minimization method is used to simulate gasification process. The model is capable of predicting final gas composition as a function of temperature or equivalence ratio. Calculations are performed for a specified average wastes composition and different equivalence ratios of air to discuss its influence on the performance of gasification (temperature of the process and gas composition. Finally the model enables to calculate total energy balance of the process as well as gasification and final gas temperature.

  8. Fluidized bed gasification of selected South African coals

    CSIR Research Space (South Africa)

    Engelbrecht, AD

    2010-05-01

    Full Text Available are high in ash, rich in inertinites, very dense (low porosity), with low caking indices and high ash fusion temperatures. Reactivity measurements with a thermogravimetric analyser (TGA), under reaction rate controlling conditions with carbon dioxide...

  9. Engineering bed models for solid fuel conversion process in grate-fired boilers

    DEFF Research Database (Denmark)

    Costa, M.; Massarotti, N.; Indrizzi, V.

    2014-01-01

    A comparison between two numerical models describing the thermo-chemical conversion process of a solid fuel bed in a grate-fired boiler is presented. Both models consider the incoming biomass as subjected to drying, pyrolysis, gasification and combustion. In the first approach the biomass bed...

  10. Biomass ash-bed material interactions leading to agglomeration in FBC

    DEFF Research Database (Denmark)

    Visser, H.J.M.; van Lith, Simone Cornelia; Kiel, J.H.A.

    2008-01-01

    In (bubbling) fluidized-bed combustion and gasification of biomass, several potential problems are associated with the inorganic components of the fuel. A major problem area is defluidization due to bed agglomeration. The most common found process leading to defluidization in commercial-scale ins...

  11. Mathematical modelling of MSW incineration in a packed bed

    DEFF Research Database (Denmark)

    Chen, Guanyi; Gu, Tianbao; He, Xiao

    2017-01-01

    Grate-firing is the most commonly used technology for municipal solid waste (MSW) incineration for heat and power generation, in which MSW undergoes thermochemical conversion (e.g., drying, devolatilization, char gasification and oxidation) in the fuel bed on the grate while the combustible gases...

  12. Activated Carbon Prepared in a Novel Gas Fired Static Bed ...

    African Journals Online (AJOL)

    Activated Carbon Prepared in a Novel Gas Fired Static Bed Pyrolysis-Gasification Reactor for Gold Di-Cyanide Adsorption. ... The gold di-cyanide adsorption characteristics of the derived activated carbon compared very well with that of the commercial activated carbon, Norit RO 3515 used in most mines in Ghana.

  13. Gasification of peat and biomass in suspension flow 2; Turpeen ja biomassan suspensiokaasutus 2

    Energy Technology Data Exchange (ETDEWEB)

    Kurkela, E.; Hepola, J. [VTT Energy, Espoo (Finland); Haukka, P.; Vehmaan-Kreula, M.; Raiko, R. [Tampere Univ. of Technology (Finland)

    1996-12-01

    This project was an extension of the earlier Liekki-project 402 carried out in 1993-1994. The aims of the 1995 project were: (1) to study the formation of problematic tar/soot compounds and nitrogen pounds in the conditions of entrained flow gasification of biomass and peat, (2) study the product yields and kinetics of pyrolysis, and (3) to develop simulation methods for entrained flow pyrolysis and gasification. Pyrolysis and gasification tests were carried out at a new entrained flow reactor of the Gasification Research Group of VTT using mainly peat as the feedstock. The pyrolysis kinetics was studies using three particle size distributions of fuel peat (0.075-0.125 mm, 0.16-0.25 mm and 0.315-0.5 mm). The char yields were determined at two temperatures (900 and 1000 deg C) and the effects fuel to gas ratio (suspension density) as well as the effects of gas atmosphere were determined. Limited amount of tests were also carried out with pine wood and dried de-inking sludge. The formation of tars and nitrogen compounds was studied with peat as the feedstock. Based on the test results of this project and the on earlier fluidized-bed gasification data of VTT, the following conclusions can be made: (1) the char yields in rapid entrained flow pyrolysis of small particles of peat and biomass are considerably lower than derived in fluid-bed pyrolysis of more coarse feedstocks. Consequently, simple entrained flow reactors without any recycling of char could already give rather high carbon conversions. However, high carbon conversions can also be easily achieved in fluidized-bed gasifiers with biomass fuels due to the high gasification reactivity of the char, (2) more tars were formed in entrained flow pyrolysis of peat than in fluidized-bed experiments carried out at the same temperature, (3) the total conversion of peat nitrogen to NH{sub 3}+HCN was as high in the entrained flow pyrolysis as in the fluid-bed pyrolysis experiments. (Abstract Truncated)

  14. Mineral-char interaction during gasification of high-ash coals in fluidized-bed gasification

    CSIR Research Space (South Africa)

    Oboirien, BO

    2011-09-01

    Full Text Available on char reactivity, the molten ash also appeared to participate in a chemical reaction at the char-mineral interface, which seems to have involved the modification of the carbon properties. A structurally more ordered part formed at the interaction...

  15. Low temperature circulating fluidized bed gasification and co-gasification of municipal sewage sludge

    DEFF Research Database (Denmark)

    Thomsen, Tobias Pape; Hauggaard-Nielsen, Henrik; Gøbel, Benny

    2017-01-01

    kW and 6 MW, respectively. The assessment included: (i) Elemental composition and recovery of key elements and heavy metals; (ii) content of total carbon (C) and total nitrogen (N); (iii) pH; (iv) water extractability of phosphorus after incubation in soil; and (v) plant phosphorus response measured...... and sanitize sewage sludge for subsequent use in agricultural systems....

  16. Challenges for implementation of bioenergy in the Brazilian energy matrix and biomass gasification process for the production of electrical power; Desafios da bioenergia para sua implementacao na matriz energetica brasileira e o processo de gaseificacao da biomassa para a producao de energia eletrica

    Energy Technology Data Exchange (ETDEWEB)

    Figueiroa, E.O.; Moutinho-Junior, D.A.A.; Silva, J.D. [Universidade de Pernambuco (UPE), Recife, PE (Brazil)

    2010-07-01

    The gasification is the conversion of any solid or liquid fuel in fuel gas through the process of the partial oxidation at a high temperature. The gasification process of course occurs in four distinct physicochemical stages with different temperatures of reaction, as drying of the biomass, pyrolysis, reduction and combustion. The reorganization of the Brazilian electric sector foresees technological innovations in the system of electric generation for the country. The process of gasification integrated in a combined cycle (cycle of Brayton and cycle of Rankine) characterizes an innovative technology. It is with noting that this technology is still in improvement, it shows an excellent perspective of commercial viability and efficiency significantly higher than conventional technology. This work presents a study of the gases generated in the zone of combustion and its behavior in the zone of 'freeboard' of a gasifier of fluidized stream bed. For this study, we made the use of one hybrid technique (half-analytical) that is the transformed one of Fourier. (author)

  17. Hybrid Molten Bed Gasifier for High Hydrogen Syngas Production

    Energy Technology Data Exchange (ETDEWEB)

    Rue, David [Gas Technology Institute, Des Plaines, IL (United States)

    2017-05-23

    The techno-economic analyses of the hybrid molten bed gasification technology and laboratory testing of the HMB process were carried out in this project by the Gas Technology Institute and partner Nexant, Inc. under contract with the US Department of Energy’s National Energy Technology Laboratory. This report includes the results of two complete IGCC and Fischer-Tropsch TEA analyses comparing HMB gasification with the Shell slagging gasification process as a base case. Also included are the results of the laboratory simulation tests of the HMB process using Illinois #6 coal fed along with natural gas, two different syngases, and steam. Work in this 18-month project was carried out in three main Tasks. Task 2 was completed first and involved modeling, mass and energy balances, and gasification process design. The results of this work were provided to Nexant as input to the TEA IGCC and FT configurations studied in detail in Task 3. The results of Task 2 were also used to guide the design of the laboratory-scale testing of the HMB concept in the submerged combustion melting test facility in GTI’s industrial combustion laboratory. All project work was completed on time and budget. A project close-out meeting reviewing project results was conducted on April 1, 2015 at GTI in Des Plaines, IL. The hybrid molten bed gasification process techno-economic analyses found that the HMB process is both technically and economically attractive compared with the Shell entrained flow gasification process. In IGCC configuration, HMB gasification provides both efficiency and cost benefits. In Fischer-Tropsch configuration, HMB shows small benefits, primarily because even at current low natural gas prices, natural gas is more expensive than coal on an energy cost basis. HMB gasification was found in the TEA to improve the overall IGCC economics as compared to the coal only Shell gasification process. Operationally, the HMB process proved to be robust and easy to operate. The burner

  18. Combination of upflow anaerobic sludge blanket (UASB) reactor and partial nitritation/anammox moving bed biofilm reactor (MBBR) for municipal wastewater treatment.

    Science.gov (United States)

    Malovanyy, Andriy; Yang, Jingjing; Trela, Jozef; Plaza, Elzbieta

    2015-03-01

    In this study the combination of an upflow anaerobic sludge blanket (UASB) reactor and a deammonification moving bed biofilm reactor (MBBR) for mainstream wastewater treatment was tested. The competition between aerobic ammonium oxidizing bacteria (AOB) and nitrite oxidizing bacteria (NOB) was studied during a 5months period of transition from reject water to mainstream wastewater followed by a 16months period of mainstream wastewater treatment. The decrease of influent ammonium concentration led to a wash-out of suspended biomass which had a major contribution to nitrite production. Influence of a dissolved oxygen concentration and a transient anoxia mechanism of NOB suppression were studied. It was shown that anoxic phase duration has no effect on NOB metabolism recovery and oxygen diffusion rather than affinities of AOB and NOB to oxygen determine the rate of nitrogen conversion in a biofilm system. Anammox activity remained on the level comparable to reject water treatment systems. Copyright © 2014 Elsevier Ltd. All rights reserved.

  19. Gasification of seven coals in carbon dioxide at elevated temperatures and high heating rates: Unification approach of reactivity

    Energy Technology Data Exchange (ETDEWEB)

    Liu, H.; Kaneko, M.; Kato, S.; Kojima, T. [Seikei University, Tokyo (Japan). Dept. of Applied Chemistry

    2003-07-01

    Studies on coal gasification in CO{sub 2} at elevated temperatures and high heating rates are necessary to develop IGCC technology. Coal gasification is a very complicated phenomenon, which makes a generalized understanding and description of gasification reactivity of a coal highly important. With a unique fluidized bed, the reactivity of seven coals was investigated at elevated temperatures and high heating rates. A modified random pore model was proposed to unify the gasification reactivity of coals. It was identified that the coal reactivity can be unified with a master curve described by the new model for all the coals, temperatures and heating rates examined in this work. This model can also satisfactorily unify the experimental gasification data in literature. The modified random pore model can predict the experimental data with an error within about 5%. The error of the prediction by the modified random pore model is about one-third smaller than that of the prediction by the random pore model. It is recommended as a sub-model for simulation of coal gasification in practical gasifiers.

  20. The monitoring and control of underground coal gasification in laboratory conditions

    Directory of Open Access Journals (Sweden)

    Ján Kačúr

    2008-03-01

    Full Text Available A number of coal gasification technologies are currently available or under various stages of development. One technology “Underground coal gasification (UCG” is receiving renewed interest around the world. In this paper is provided the analysis of relevant processes during UCG. The laboratory equipment is described. Since experiments have long time response, partial automation has been realised. The structure of monitoring and control system is shown. Analysed are some results of measured data for oxidizing by air. Also, the influence of temperature on the structure of syngas is analysed. In light of the experimental results, potential performance of UCG in Slovak coal seam conditions is discussed.

  1. Chemical looping coal gasification with calcium ferrite and barium ferrite via solid–solid reactions

    International Nuclear Information System (INIS)

    Siriwardane, Ranjani; Riley, Jarrett; Tian, Hanjing; Richards, George

    2016-01-01

    Highlights: • BaFe 2 O 4 and CaFe 2 O 4 are excellent for chemical looping coal gasification. • BaFe 2 O 4 and CaFe 2 O 4 have minimal reactivity with synthesis gas. • Steam enhances the gasification process with these oxygen carriers. • Reaction rates of steam gasification of coal with CaFe 2 O 4 was better than with gaseous oxygen. • Coal gasification appears to be via solid–solid interaction with the oxygen carrier. - Abstract: Coal gasification to produce synthesis gas by chemical looping was investigated with two oxygen carriers, barium ferrite (BaFe 2 O 4 ) and calcium ferrite (CaFe 2 O 4 ). Thermo-gravimetric analysis (TGA) and fixed-bed flow reactor data indicated that a solid–solid interaction occurred between oxygen carriers and coal to produce synthesis gas. Both thermodynamic analysis and experimental data indicated that BaFe 2 O 4 and CaFe 2 O 4 have high reactivity with coal but have a low reactivity with synthesis gas, which makes them very attractive for the coal gasification process. Adding steam increased the production of hydrogen (H 2 ) and carbon monoxide (CO), but carbon dioxide (CO 2 ) remained low because these oxygen carriers have minimal reactivity with H 2 and CO. Therefore, the combined steam–oxygen carrier produced the highest quantity of synthesis gas. It appeared that neither the water–gas shift reaction nor the water splitting reaction promoted additional H 2 formation with the oxygen carriers when steam was present. Wyodak coal, which is a sub-bituminous coal, had the best gasification yield with oxygen carrier–steam while Illinois #6 coal had the lowest. The rate of gasification and selectivity for synthesis gas production was significantly higher when these oxygen carriers were present during steam gasification of coal. The rates and synthesis gas yields during the temperature ramps of coal–steam with oxygen carriers were better than with gaseous oxygen.

  2. TEXACO GASIFICATION PROCESS - INNOVATIVE TECHNOLOGY EVALUATION REPORT

    Science.gov (United States)

    This report summarizes the evaluation of the Texaco Gasification Process (TGP) conducted under the U.S. Environmental Protection Agency (EPA) Superfund Innovative Technology Evaluation (SITE) Program. The Texaco Gasification Process was developed by Texaco Inc. The TGP is a comm...

  3. Gasification — the process and the technology

    NARCIS (Netherlands)

    van Swaaij, Willibrordus Petrus Maria

    1981-01-01

    Thermochemical gasification of biomass can produce low, medium and high calorific value gases. The characteristics, applications and potential of the different processes and reactor types are discussed. The introduction of biomass gasification on a large or intermediate scale for the production of

  4. Modeling integrated biomass gasification business concepts

    Science.gov (United States)

    Peter J. Ince; Ted Bilek; Mark A. Dietenberger

    2011-01-01

    Biomass gasification is an approach to producing energy and/or biofuels that could be integrated into existing forest product production facilities, particularly at pulp mills. Existing process heat and power loads tend to favor integration at existing pulp mills. This paper describes a generic modeling system for evaluating integrated biomass gasification business...

  5. Circulating fluidized-bed technologies for the conversion of biomass into energy

    International Nuclear Information System (INIS)

    Greil, C.; Hirschfelder, H.

    1995-01-01

    The paper introduces circulating fluidized-bed (CFB) combustion and CFB gasification. CFB combustion units are state-of-the-art and have proven their ability to convert biomass into power and/or steam. The existing units and projects in developing countries are discussed as examples of conventional technology. To illustrate advanced technologies, CFB gasification is discussed. Important process parameters of plants already in operation or under construction in developed countries are shown, Criteria for the selection of CFB combustion or gasification based on available feedstocks and products required are discussed. Finally, a procedure for implementing Lurgi's CFB technology in developing countries is proposed. (author)

  6. Gasification of peat and biomass in suspension. Turpeen ja biomassan suspensiokaasutus

    Energy Technology Data Exchange (ETDEWEB)

    Haukka, P.; Raiko, R.

    1993-01-01

    Gasification of peat and biomass in dilute particle-gas suspension has not been studied significantly in Finland, even though these fuels require drying, which often produces dry pulverized fuel. This report has concentrated on studying suitability of so-called two-stage entrained-bed gasification for peat and biomass. The gasification system consists of a pyrolysis reactor (entrained flow) and an adiabatic char combustor. Dry or almost dry fuel is fed into the hot flue gas stream coming from the char combustor. Gasification is based on flash pyrolysis in the dilute suspension flow. Residual char is separated from pyrolyzer gases in a gas cleaning device and fed back to the adiabatic combustor. In the combustor char is burned at high temperature to supply the heat required to support endothermic reactions occurring in the pyrolyzer. To study entrained-bed gasification two types of computer models were developed: steady state simulation model and kinetic pyrolyzer model. With the help of these computer models mass and energy balances of the gasifier can be solved and the main dimensions of the gasifier can be determined. Lack of proper kinetic parameters for fast pyrolysis of peat and biomass makes it more difficult to apply the kinetic model in practice. Quantitative data concerning fast pyrolysis in dilute gas-particle suspension are needed to be able to evaluate the performance of the suspension gasifier in more detail. Gasifier operation has been studied using three different levels for amounts of pyrolysis pro- ducts, nine pressure levels between 15-23 bars and five temperature levels between 800-1200 deg C. Furthermore, normal pressure performance was simulated. In addition to simulation studies product gas heating value was optimized

  7. International Seminar on Gasification 2009 - Biomass Gasification, Gas Clean-up and Gas Treatment

    Energy Technology Data Exchange (ETDEWEB)

    2009-10-15

    During the seminar international and national experts gave presentations concerning Biomass gasification, Gas cleaning and gas treatment; and Strategy and policy issues. The presentations give an overview of the current status and what to be expected in terms of development, industrial interest and commercialization of different biomass gasification routes. The following PPT presentations are reproduced in the report: Black Liquor Gasification (Chemrec AB.); Gasification and Alternative Feedstocks for the Production of Synfuels and 2nd Generation Biofuels (Lurgi GmbH); Commercial Scale BtL Production on the Verge of Becoming Reality (Choren Industries GmbH.); Up-draft Biomass Gasification (Babcock and Wilcox Voelund A/S); Heterogeneous Biomass Residues and the Catalytic Synthesis of Alcohols (Enerkem); Status of the GoBiGas-project (Goeteborg Energi AB.); On-going Gasification Activities in Spain (University of Zaragoza,); Biomass Gasification Research in Italy (University of Perugia.); RDandD Needs and Recommendations for the Commercialization of High-efficient Bio-SNG (Energy Research Centre of the Netherlands.); Cleaning and Usage of Product Gas from Biomass Steam Gasification (Vienna University of Technology); Biomass Gasification and Catalytic Tar Cracking Process Development (Research Triangle Institute); Syngas Cleaning with Catalytic Tar Reforming (Franhofer UMSICHT); Biomass Gas Cleaning and Utilization - The Topsoee Perspective (Haldor Topsoee A/S); OLGA Tar Removal Technology (Dahlman); Bio-SNG - Strategy and Activities within E.ON (E.ON Ruhrgas AG); Strategy and Gasification Activities within Sweden (Swedish Energy Agency); 20 TWh/year Biomethane (Swedish Gas Association)

  8. PLASMA GASIFICATION OF WASTE PLASTICS

    Directory of Open Access Journals (Sweden)

    Tadeusz Mączka

    2013-01-01

    Full Text Available The article presents the process of obtaining liquid fuels and fuel gas in the process of plasma processing of organic materials, including waste plastics. The concept of plasma pyrolysis of plastics was presented and on its basis a prototype installation was developed. The article describes a general rule of operating the installation and its elements in the process and basic operation parameters determined during its start-up. Initial results of processing plastics and the directions further investigations are also discussed. The effect of the research is to be the design of effective technology of obtaining fuels from gasification/pyrolysis of organic waste and biomass.

  9. Calcium addition in straw gasification

    DEFF Research Database (Denmark)

    Risnes, H.; Fjellerup, Jan Søren; Henriksen, Ulrik Birk

    2003-01-01

    The present work focuses on the influence of calcium addition in gasification. The inorganic¿organic element interaction as well as the detailed inorganic¿inorganic elements interaction has been studied. The effect of calcium addition as calcium sugar/molasses solutions to straw significantly...... affected the ash chemistry and the ash sintering tendency but much less the char reactivity. Thermo balance test are made and high-temperature X-ray diffraction measurements are performed, the experimental results indicate that with calcium addition major inorganic¿inorganic reactions take place very late...

  10. Properties of gasification-derived char and its utilization for catalytic tar reforming

    Science.gov (United States)

    Qian, Kezhen

    Char is a low-value byproduct of biomass gasification and pyrolysis with many potential applications, such as soil amendment and the synthesis of activated carbon. The overall goal of the proposed research was to develop novel methods to use char derived from gasification for high-value applications in syngas conditioning. The first objective was to investigate effects of gasification condition and feedstock on properties of char derived from fluidized bed gasification. Results show that the surface areas of most of the char were 1--10 m 2/g and increased as the equivalence ratio increased. Char moisture and fixed carbon contents decreased while ash content increased as equivalence ratio increased. The next objective was to study the properties of sorghum and red cedar char derived from downdraft gasifier. Red cedar char contained more aliphatic carbon and o-alkyl carbon than sorghum char. Char derived from downdraft gasification had higher heating values and lower ash contents than char derived from fluidized bed gasification. The gasification reactivity of red cedar char was higher than that of sorghum char. Then, red cedar char based catalysts were developed with different preparation method to reform toluene and naphthalene as model tars. The catalyst prepared with nickel nitrate was found to be better than that with nickel acetate. The nickel particle size of catalyst impregnated with nickel nitrate was smaller than that of catalyst impregnated with nickel acetate. The particle size of catalyst impregnated with nickel acetate decreased by hydrazine reduction. The catalyst impregnated with nickel nitrate had the highest toluene removal efficiency, which was 70%--100% at 600--800 °C. The presence of naphthalene in tar reduced the catalyst efficiency. The toluene conversion was 36--99% and the naphthalene conversion was 37%--93% at 700--900 °C. Finally, effects of atmosphere and pressure on catalytic reforming of lignin-derived tars over the developed catalyst

  11. Brown coal gasification made easy

    International Nuclear Information System (INIS)

    Hamilton, Chris

    2006-01-01

    Few Victorians will be aware that gas derived from coal was first used in 1849 to provide lighting in a baker's shop in Swanston Street, long before electric lighting came to the State. The first commercial 'gas works' came on stream in 1856 and Melbourne then had street lighting run on gas. By 1892 there were 50 such gas works across the State. Virtually all were fed with black coal imported from New South Wales. Brown coal was first discovered west of Melbourne in 1857, and the Latrobe Valley deposits were identified in the early 1870s. Unfortunately, such wet brown coal did not suit the gas works. Various attempts to commercialise Victorian brown coal met with mixed success as it struggled to compete with imported New South Wales black coal. In June 1924 Yallourn A transmitted the first electric power to Melbourne, and thus began the Latrobe Valley's long association with generating electric power from brown coal. Around 1950, the Metropolitan Gas Company applied for financial assistance to build a towns gas plant using imported German gasification technology which had been originally designed for a brown coal briquette feed. The State Government promptly acquired the company and formed the Gas and Fuel Corporation. The Morwell Gasification Plant was opened on 9 December 1956 and began supplying Melbourne with medium heating value towns gas

  12. Macauba gasification; Gaseificacao da macauba

    Energy Technology Data Exchange (ETDEWEB)

    Santos Filho, Jaime dos; Oliveira, Eron Sardinha de [Instituto Federal de Educacao, Ciencia e Tecnologia da Bahia (IFBA), Vitoria da Conquista, BA (Brazil)], E-mail: jaime@ifba.edu.br; Silva, Jadir Nogueira da; Galvarro, Svetlana Fialho Soria [Universidade Federal de Vicosa (UFV), MG (Brazil); Chaves, Modesto Antonio [Universidade Estadual do Sudoeste da Bahia (UESB), Itapetinga, BA (Brazil). Dept. de Engenharia de Alimentos

    2009-07-01

    For development of a productive activity, with reduced environmental degradation, the use of renewable energy sources as an important option. The gasification has been increasing among the ways of obtaining energy from biomass, and consists of a process where the necessary oxygen to the complete combustion of a fuel it is restricts and, in high temperatures it generates fuel gas of high-quality. In this direction, this work is justified and has its importance as the study of a renewable energy source, macauba coconut (Acrocomia aculeata [Jacq] Lodd), with the gasification process. The objective of this study is to build a biomass concurrent gasifier and evaluate the viability to provide heating for dehydration of fruits, using the macauba coconut as fuel. It was measured the temperature in five points distributed in both gasifier and combustor chamber, being the input area of primary combustor air and also the speed of rotation of the electric motor, using a factorial 3X3 experimental design with three repetitions and interval of measurements of five minutes. The analytical results take to infer that the macauba coconut have potential to be gasified and used for the dehydration of fruits. (author)

  13. Review and analysis of biomass gasification models

    DEFF Research Database (Denmark)

    Puig Arnavat, Maria; Bruno, Joan Carles; Coronas, Alberto

    2010-01-01

    The use of biomass as a source of energy has been further enhanced in recent years and special attention has been paid to biomass gasification. Due to the increasing interest in biomass gasification, several models have been proposed in order to explain and understand this complex process......, and the design, simulation, optimisation and process analysis of gasifiers have been carried out. This paper presents and analyses several gasification models based on thermodynamic equilibrium, kinetics and artificial neural networks. The thermodynamic models are found to be a useful tool for preliminary...

  14. Water pollution control for underground coal gasification

    International Nuclear Information System (INIS)

    Humenick, M.J.

    1984-01-01

    Water pollution arising from underground gasification of coal is one of the important considerations in the eventual commercialization of the process. Because many coal seams which are amenable to in situ gasification are also ground-water aquifers, contaminants may be released to these ground waters during and after gasification. Also, when product gas is processed above ground for use, wastewater streams are generated which are too polluted to be discharged. The purpose of this paper is to characterize the nature of the groundwater and above-ground pollutants, discuss the potential long and short-term effects on ground water, propose control and restoration strategies, and to identify potential wastewater treatment schemes

  15. Thermodynamic analysis of an integrated gasification solid oxide fuel cell plant combined with an organic Rankine cycle

    DEFF Research Database (Denmark)

    Pierobon, Leonardo; Rokni, Masoud; Larsen, Ulrik

    2013-01-01

    A 100 kWe hybrid plant consisting of gasification system, solid oxide fuel cells and organic Rankine cycle is presented. The nominal power is selected based on cultivation area requirement. For the considered output a land of around 0.5 km2 needs to be utilized. Woodchips are introduced...... into a fixed bed gasification plant to produce syngas which fuels the combined solid oxide fuel cells e organic Rankine cycle system to produce electricity. More than a hundred fluids are considered as possible alternative for the organic cycle using non-ideal equations of state (or state-of-the-art equations...... achieved by simple and double stage organic Rankine cycle plants and around the same efficiency of a combined gasification, solid oxide fuel cells and micro gas turbine plant. © 2013 Elsevier Ltd. All rights reserved....

  16. High Performance Gasification with the Two-Stage Gasifier

    DEFF Research Database (Denmark)

    Gøbel, Benny; Hindsgaul, Claus; Henriksen, Ulrik Birk

    2002-01-01

    , air preheating and pyrolysis, hereby very high energy efficiencies can be achieved. Encouraging results are obtained at a 100 kWth laboratory facility. The tar content in the raw gas is measured to be below 25 mg/Nm3 and around 5 mg/Nm3 after gas cleaning with traditional baghouse filter. Furthermore...... a cold gas efficiency exceeding 90% is obtained. In the original design of the two-stage gasification process, the pyrolysis unit consists of a screw conveyor with external heating, and the char unit is a fixed bed gasifier. This design is well proven during more than 1000 hours of testing with various...... fuels, and is a suitable design for medium size gasifiers....

  17. Characteristics of Malaysian coals with their pyrolysis and gasification behaviour

    International Nuclear Information System (INIS)

    Nor Fadzilah Othman; Mohd Hariffin Bosrooh; Kamsani Abdul Majid

    2010-01-01

    This study was conducted since comprehensive study on the gasification behaviour of Malaysian coals is still lacking. Coals were characterised using heating value determination, proximate analysis, ultimate analysis and ash analysis. Pyrolysis process was investigated using thermogravimetric analyser. While, atmospheric bubbling fluidized bed gasifier was used to investigate the gasification behaviour. Three Malaysian coals, Merit Pila, Mukah Balingian, Silantek; and Australian coal, Hunter Valley coals were used in this study. Thermal degradation of four coal samples were performed, which involved weight loss profile and derivative thermogravimetric (DTG) curves. The kinetic parameters, such as maximum reactivity value, R max , Activation Energy, E a and Arrhenius constant, ln R o for each coal were determined using Arrhenius Equation. Merit Pila coal shows the highest maximum reactivity among other Malaysian coals. E a is the highest for Merit Pila coal (166.81kJmol -1 ) followed with Mukah Balingian (101.15 kJmol -1 ), Hunter Valley (96.45 kJmol -1 ) and Silantek (75.23 kJmol -1 ) coals. This finding indicates direct correlation of lower rank coal with higher E a . Merit Pila coal was studied in detail using atmospheric bubbling fluidized bed gasifier. Different variables such as equivalence ratio (ER) and gasifying agents were used. The highest H 2 proportion (38.3 mol.%) in the producer gas was reached at 715 degree Celsius and ER=0.277 where the maximization of LHV pg (5.56 MJ/Nm 3 ) was also detected. ER and addition of steam had shown significant contributions to the producer gas compositions and LHV pg . (author)

  18. Biomass gasification for production of 'green energy'

    International Nuclear Information System (INIS)

    Mambre, V.

    2008-01-01

    This paper presents the differences between biomass gasification and biomass methanation, two ways of using biomass for decentralized production of energy. The stakes of biomass and biomass gasification for meeting the European and national energy goals and environmental targets are summarized. The gasification principle is described and in particular the FICFB optimized process from Repotec for the production of concentrated syngas. The four different ways of syngas valorization (combined heat and power (CHP), 'green methane' (SNG), 'green hydrogen' (gas shift) and liquid biofuels of 2. generation (Fisher-Tropsch)) are recalled and compared with each other. Finally, the economical and environmental key issues of the global chain are summarized with their technological and scientific key locks. The GAYA R and D project of Gaz de France Suez group, which aims at developing gasification and methanation demonstration plants through different programs with European partners, is briefly presented. (J.S.)

  19. Advancement of High Temperature Black Liquor Gasification Technology

    Energy Technology Data Exchange (ETDEWEB)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the

  20. BIOMASS GASIFICATION AND POWER GENERATION USING ADVANCED GAS TURBINE SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    David Liscinsky

    2002-10-20

    A multidisciplined team led by the United Technologies Research Center (UTRC) and consisting of Pratt & Whitney Power Systems (PWPS), the University of North Dakota Energy & Environmental Research Center (EERC), KraftWork Systems, Inc. (kWS), and the Connecticut Resource Recovery Authority (CRRA) has evaluated a variety of gasified biomass fuels, integrated into advanced gas turbine-based power systems. The team has concluded that a biomass integrated gasification combined-cycle (BIGCC) plant with an overall integrated system efficiency of 45% (HHV) at emission levels of less than half of New Source Performance Standards (NSPS) is technically and economically feasible. The higher process efficiency in itself reduces consumption of premium fuels currently used for power generation including those from foreign sources. In addition, the advanced gasification process can be used to generate fuels and chemicals, such as low-cost hydrogen and syngas for chemical synthesis, as well as baseload power. The conceptual design of the plant consists of an air-blown circulating fluidized-bed Advanced Transport Gasifier and a PWPS FT8 TwinPac{trademark} aeroderivative gas turbine operated in combined cycle to produce {approx}80 MWe. This system uses advanced technology commercial products in combination with components in advanced development or demonstration stages, thereby maximizing the opportunity for early implementation. The biofueled power system was found to have a levelized cost of electricity competitive with other new power system alternatives including larger scale natural gas combined cycles. The key elements are: (1) An Advanced Transport Gasifier (ATG) circulating fluid-bed gasifier having wide fuel flexibility and high gasification efficiency; (2) An FT8 TwinPac{trademark}-based combined cycle of approximately 80 MWe; (3) Sustainable biomass primary fuel source at low cost and potentially widespread availability-refuse-derived fuel (RDF); (4) An overall integrated

  1. Ab initio calculations and kinetic modeling of thermal conversion of methyl chloride: implications for gasification of biomass.

    Science.gov (United States)

    Singla, Mallika; Rasmussen, Morten Lund; Hashemi, Hamid; Wu, Hao; Glarborg, Peter; Pelucchi, Matteo; Faravelli, Tiziano; Marshall, Paul

    2018-01-24

    Limitations in current hot gas cleaning methods for chlorine species from biomass gasification may be a challenge for end use such as gas turbines, engines, and fuel cells, all requiring very low levels of chlorine. During devolatilization of biomass, chlorine is released partly as methyl chloride. In the present work, the thermal conversion of CH 3 Cl under gasification conditions was investigated. A detailed chemical kinetic model for pyrolysis and oxidation of methyl chloride was developed and validated against selected experimental data from the literature. Key reactions of CH 2 Cl with O 2 and C 2 H 4 for which data are scarce were studied by ab initio methods. The model was used to analyze the fate of methyl chloride in gasification processes. The results indicate that CH 3 Cl emissions will be negligible for most gasification technologies, but could be a concern for fluidized bed gasifiers, in particular in low-temperature gasification. The present work illustrates how ab initio theory and chemical kinetic modeling can help to resolve emission issues for thermal processes in industrial scale.

  2. Analysis of Organic and Inorganic Contaminants in Dried Sewage Sludge and By-Products of Dried Sewage Sludge Gasification

    Directory of Open Access Journals (Sweden)

    Sebastian Werle

    2014-01-01

    Full Text Available Organic and inorganic contaminants in sewage sludge may cause their presence also in the by-products formed during gasification processes. Thus, this paper presents multidirectional chemical instrumental activation analyses of dried sewage sludge as well as both solid (ash, char coal and liquid (tar by-products formed during sewage gasification in a fixed bed reactor which was carried out to assess the extent of that phenomenon. Significant differences were observed in the type of contaminants present in the solid and liquid by-products from the dried sewage sludge gasification. Except for heavy metals, the characteristics of the contaminants in the by-products, irrespective of their form (solid and liquid, were different from those initially determined in the sewage sludge. It has been found that gasification promotes the migration of certain valuable inorganic compounds from sewage sludge into solid by-products which might be recovered. On the other hand, the liquid by-products resulting from sewage sludge gasification require a separate process for their treatment or disposal due to their considerable loading with toxic and hazardous organic compounds (phenols and their derivatives.

  3. Calcium addition in straw gasification

    DEFF Research Database (Denmark)

    Risnes, H.; Fjellerup, Jan Søren; Henriksen, Ulrik Birk

    2003-01-01

    The present work focuses on the influence of calcium addition in gasification. The inorganic¿organic element interaction as well as the detailed inorganic¿inorganic elements interaction has been studied. The effect of calcium addition as calcium sugar/molasses solutions to straw significantly...... affected the ash chemistry and the ash sintering tendency but much less the char reactivity. Thermo balance test are made and high-temperature X-ray diffraction measurements are performed, the experimental results indicate that with calcium addition major inorganic¿inorganic reactions take place very late...... in the char conversion process. Comprehensive global equilibrium calculations predicted important characteristics of the inorganic ash residue. Equilibrium calculations predict the formation of liquid salt if sufficient amounts of Ca are added and according to experiments as well as calculations calcium binds...

  4. Groundwater and underground coal gasification in Alberta

    International Nuclear Information System (INIS)

    Haluszka, A.; MacMillan, G.; Maev, S.

    2010-01-01

    Underground coal gasification has potential in Alberta. This presentation provided background information on underground coal gasification and discussed groundwater and the Laurus Energy demonstration project. A multi-disciplined approach to project assessment was described with particular reference to geologic and hydrogeologic setting; geologic mapping; and a hydrogeologic numerical model. Underground coal gasification involves the conversion of coal into synthesis gas or syngas. It can be applied to mined coal at the surface or applied to non-mined coal seams using injection and production wells. Underground coal gasification can effect groundwater as the rate of water influx into the coal seams influences the quality and composition of the syngas. Byproducts created include heat as well as water with dissolved concentrations of ammonia, phenols, salts, polyaromatic hydrocarbons, and liquid organic products from the pyrolysis of coal. A process overview of underground coal gasification was also illustrated. It was concluded that underground coal gasification has the potential in Alberta and risks to groundwater could be minimized by a properly designed project. refs., figs.

  5. Advances in fluidized bed technologies

    International Nuclear Information System (INIS)

    Mutanen, K.

    1992-01-01

    Atmospheric fluidized bed combustion (AFBC) has advanced into industrial cogeneration and utility-scale electric generation. During the 1980's AFBC became the dominant technology in the United States for power generation systems fired with solid fuels. Development of pressurized fluidized bed combustion/gasification (PFB/G) has grown rapidly from small bench-scale rigs to large pilot and demonstration plants. AFBC as large as 160 MWe in capacity are now in operation, while pressurized combustion systems generating 80 MWe have started up two years ago. The major driving forces behind development of fluidized bed technologies are all the time strictening emission control regulations, need for fuel flexibility, repowering of older power plants and need for higher efficiency in electricity generation. Independent power producers (IPP) and cogenerators were the first ones in the United States who accepted AFBC for wide commercial use. Their role will be dominant in the markets of the 1990's also. Developers of AFBC systems are working on designs that reduce investment costs, decrease emissions and offer even higher reliability and availability in utility-scale applications while developers of PFBC/G work on designs that increase plant efficiencies, allow modular construction, decrease emissions further and reduce the cost of generating power. This paper presents technological background, commercial status, boiler performance, emissions and future developments for both AFBC and PFBC/G systems

  6. Allothermal gasification of biomass using micron size biomass as external heat source.

    Science.gov (United States)

    Cheng, Gong; Li, Qian; Qi, Fangjie; Xiao, Bo; Liu, Shiming; Hu, Zhiquan; He, Piwen

    2012-03-01

    An allothermal biomass gasification system using biomass micron fuel (BMF) as external heat source was developed. In this system, heat supplied to gasifier was generated from combustion of BMF. Biomass feedstock was gasified with steam and then tar in the produced gas was decomposed in a catalytic bed with NiO/γ-Al(2)O(3) catalyst. Finally the production gas was employed as a substitute for civil fuel gas. An overall energy analysis of the system was also investigated. The results showed that the lower heating value of the product gas reached more than 12 MJ/Nm(3). The combusted BMF accounted for 26.8% of the total energy input. Allothermal gasification based on the substituted BMF for conventional energy was an efficient and economical technology to obtain bioenergy. Copyright © 2011 Elsevier Ltd. All rights reserved.

  7. Release characteristics of alkali and alkaline earth metallic species during biomass pyrolysis and steam gasification process.

    Science.gov (United States)

    Long, Jiang; Song, Hu; Jun, Xiang; Sheng, Su; Lun-Shi, Sun; Kai, Xu; Yao, Yao

    2012-07-01

    Investigating the release characteristics of alkali and alkaline earth metallic species (AAEMs) is of potential interest because of AAEM's possible useful service as catalysts in biomass thermal conversion. In this study, three kinds of typical Chinese biomass were selected to pyrolyse and their chars were subsequently steam gasified in a designed quartz fixed-bed reactor to investigate the release characteristics of alkali and alkaline earth metallic species (AAEMs). The results indicate that 53-76% of alkali metal and 27-40% of alkaline earth metal release in pyrolysis process, as well as 12-34% of alkali metal and 12-16% of alkaline earth metal evaporate in char gasification process, and temperature is not the only factor to impact AAEMs emission. The releasing characteristics of AAEMs during pyrolysis and char gasification process of three kinds of biomass were discussed in this paper. Copyright © 2012 Elsevier Ltd. All rights reserved.

  8. WABASH RIVER COAL GASIFICATION REPOWERING PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2000-09-01

    The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas{trademark} technology (E-Gas{trademark} is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas{trademark} process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation.

  9. WABASH RIVER COAL GASIFICATION REPOWERING PROJECT; FINAL

    International Nuclear Information System (INIS)

    Unknown

    2000-01-01

    The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas(trademark) technology (E-Gas(trademark) is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas(trademark) process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation

  10. The influence of chlorine on the gasification of wood

    Energy Technology Data Exchange (ETDEWEB)

    Scala, C. von; Struis, R.; Stucki, S. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    Chlorides of the heavy metals copper, lead and zinc inhibit the CO{sub 2}-gasification reaction of charcoal. This is observed either by impregnation the wood with the salts before pyrolysis or by mechanically mixing the salts with the charcoal before gasification. Charcoal impregnated or mixed with ammonium chloride reacts more slowly than untreated charcoal. Treating the charcoal with HCl also influences negatively the gasification reactivity, indicating that chlorine plays an important role in the gasification. (author) 2 figs., 4 refs.

  11. Japan`s Sunshine Project. 1991 annual summary of coal liquefaction and gasification; 1991 nendo sunshine keikaku seika hokokusho gaiyoshu. Sekitan no ekika gas ka

    Energy Technology Data Exchange (ETDEWEB)

    1992-07-01

    Out of the research and development on the 1991 Sunshine Project, the results of coal liquefaction/gasification are reported. The basic research of coal liquefaction/gasification is conducted. The research plan for a 150 ton/day scale pilot plant (PP) is worked out for the development of bituminous coal liquefaction technology by NEDOL process. Data of PSU (Process Support Units) operation, especially, are studied. Concerning the data obtained through dismantling of the 50 ton/day PP in Australia which uses Australian Victoria coal due to completion of its operation and also obtained from its support research, they are reflected in the design of a demonstration plant, and the results are arranged for study. Research and development on refining technology of coal-derived liquid such as Illinois coal liquid and on application technology of its products are made. For the development of coal-use hydrogen production technology, conducted is the research of a high temperature gasification PP by entrained flow bed process which is the core of the coal gasification technology. Elementary study with a 2 ton/day furnace is made for the development of the entrained flow bed coal gasification combined cycle power generation system. Also conducted are PP construction, adjusting operation and the overall research operation.

  12. Gasification of peat and biomass in suspension flow; Turpeen ja biomassan suspensiokaasutus

    Energy Technology Data Exchange (ETDEWEB)

    Raiko, R.; Haukka, P. [Tampere Univ. of Technology (Finland). Thermal Engineering

    1995-11-01

    This is the second phase of a project that started with examination of a gasification process for fuels containing high amounts of volatiles such as biomass. In the earlier phase of the project the gasification process was studied with the aid of computer models. Gas production with this gasification method is based mainly on rapid pyrolysis in dilute suspension flow enabling high solid to gas conversion. The two-stage approach eliminates char gasification as a limiting process step, and consequently, allows product temperature to be controlled by the kinetics of volatile reactions. A greater amount of enthalpy is made available for rapid pyrolysis through the total combustion of the residual char than is possible by partial oxidation. The main goal in the second year (1994) was to get experimental information on peat reactivity, main pyrolysis products and formation of nitrogen compounds in the early stages of peat pyrolysis in dilute pressurized flow conditions. These experiments were conducted using pressurized entrained flow reactor at VTT Energy (Jyvaeskylae). Preliminary experiments gave the result that pressure increase accelerates pyrolysis of peat at first (residence time < 100 ms), but this difference disappears gradually. The total amount of volatile matter does not seem to depend on pressure level. (author)

  13. A numerical model of a fluidized bed biomass gasifier

    Energy Technology Data Exchange (ETDEWEB)

    Hongming Jiang; Morey, R.V. (Minnesota Univ., St. Paul, MN (United States). Dept. of Agricultural Engineering)

    1992-01-01

    A one-dimensional, steady state, numerical model was developed for a fluidized bed biomass gasifier. The gasifier model consists of a fuel pyrolysis model, an oxidation model, a gasification model and a freeboard model. Given the bed temperature, ambient air flow rate and humidity ratio, fuel moisture content and reactor parameters, the model predicts the fuel feed rate for steady state operation, composition of the producer gas and fuel energy conversion. The gasifier model was validated with experimental results. The effects of major mechanisms (fuel pyrolysis and the chemical and the physical rate processes) were assessed in a sensitivity study of the gasification model. A parametric study was also conducted for the gasifier model. It is concluded that the model can be used for gasifier performance analysis. (author)

  14. CFD analysis of the fluidised bed hydrodynamic behaviour inside an isothermal gasifier with different perforated plate distributors

    OpenAIRE

    Al-Akaishi, Ahmed; Valera Medina, Agustin; Chong, C. T.; Marsh, Richard

    2017-01-01

    The hydrodynamic behaviour of gas-solid mixtures inside Bed Fluidised Beds (BFB) gasifiers has a major impact on the gasification process due to particles - gas and particle - particle contact mechanisms. The Discrete Phase Model DPM with Multiphase Particle-in-Cell method MPPIC was used as a CFD approach to study the hydrodynamic behaviour of an 800 height x 83 mm φ prototype fluidised bed gasifier with 4 different perforated plate distributors. In terms of bubble forming, pressure drop and ...

  15. Biomass gasification: a strategy for energy recovery and disposal of ...

    African Journals Online (AJOL)

    Gasification is a process that devoltalizes solid or liquid hydrocarbons, and converts them into a producer gas. There are more than 100 waste gasification facilities operating or under construction around the world. Some plants have been operating commercially for more than five years. Gasification has several advantages ...

  16. Hydrothermal Gasification for Waste to Energy

    Science.gov (United States)

    Epps, Brenden; Laser, Mark; Choo, Yeunun

    2014-11-01

    Hydrothermal gasification is a promising technology for harvesting energy from waste streams. Applications range from straightforward waste-to-energy conversion (e.g. municipal waste processing, industrial waste processing), to water purification (e.g. oil spill cleanup, wastewater treatment), to biofuel energy systems (e.g. using algae as feedstock). Products of the gasification process are electricity, bottled syngas (H2 + CO), sequestered CO2, clean water, and inorganic solids; further chemical reactions can be used to create biofuels such as ethanol and biodiesel. We present a comparison of gasification system architectures, focusing on efficiency and economic performance metrics. Various system architectures are modeled computationally, using a model developed by the coauthors. The physical model tracks the mass of each chemical species, as well as energy conversions and transfers throughout the gasification process. The generic system model includes the feedstock, gasification reactor, heat recovery system, pressure reducing mechanical expanders, and electricity generation system. Sensitivity analysis of system performance to various process parameters is presented. A discussion of the key technological barriers and necessary innovations is also presented.

  17. A critical review on biomass gasification, co-gasification, and their environmental assessments

    Directory of Open Access Journals (Sweden)

    Somayeh Farzad

    2016-12-01

    Full Text Available Gasification is an efficient process to obtain valuable products from biomass with several potential applications, which has received increasing attention over the last decades. Further development of gasification technology requires innovative and economical gasification methods with high efficiencies. Various conventional mechanisms of biomass gasification as well as new technologies are discussed in this paper. Furthermore, co-gasification of biomass and coal as an efficient method to protect the environment by reduction of greenhouse gas (GHG emissions has been comparatively discussed. In fact, the increasing attention to renewable resources is driven by the climate change due to GHG emissions caused by the widespread utilization of conventional fossil fuels, while biomass gasification is considered as a potentially sustainable and environmentally-friendly technology. Nevertheless, social and environmental aspects should also be taken into account when designing such facilities, to guarantee the sustainable use of biomass. This paper also reviews the life cycle assessment (LCA studies conducted on biomass gasification, considering different technologies and various feedstocks.

  18. The formation of nitrogen compounds at gasification/pyrolysis condition

    Energy Technology Data Exchange (ETDEWEB)

    Bjoerkman, E.; Nilsson, Torbjoern; Stroemberg, B. [TPS Termiska Processer AB, Nykoeping (Sweden)

    1998-08-01

    A kinetic model by which it is possible to determine reactions constants for the formation/destruction of hydrogen cyanide and ammonia from fuel-N during pyrolysis/gasification conditions in presence of an internal catalyst is here presented, together with the possibilities to experimentally support the model with data. The experiments were performed in a small fixed bed quarts reactor, the bed materials were CaO and iron doped CaO. The fuel used was a liquid mixture of pyridine, ethylene glycol and formic acid (25 mole-% C, 49 mole-% H, 24 mole-% 0 and 1.8 mole-% of N). The product gas was analysed for NH{sub 3}, HCN, NO, CO, CO{sub 2}, CH{sub 4} and C{sub 2}H{sub 4} with an FTIR. For some of the experiments a gas chromatograph with double thermal conductivity detectors (TCD) was used to measure the nitrogen gas formation. Changing the contact time with the iron doped CaO gave significant changes in mainly ammonia and nitrogen monoxide concentrations. The decomposition of hydrogen cyanide has also been studied, showing that no ammonia was formed from HCN during the experimental conditions used 26 refs, 8 figs, 1 appendix

  19. Plasma Treatments and Biomass Gasification

    Science.gov (United States)

    Luche, J.; Falcoz, Q.; Bastien, T.; Leninger, J. P.; Arabi, K.; Aubry, O.; Khacef, A.; Cormier, J. M.; Lédé, J.

    2012-02-01

    Exploitation of forest resources for energy production includes various methods of biomass processing. Gasification is one of the ways to recover energy from biomass. Syngas produced from biomass can be used to power internal combustion engines or, after purification, to supply fuel cells. Recent studies have shown the potential to improve conventional biomass processing by coupling a plasma reactor to a pyrolysis cyclone reactor. The role of the plasma is twofold: it acts as a purification stage by reducing production of tars and aerosols, and simultaneously produces a rich hydrogen syngas. In a first part of the paper we present results obtained from plasma treatment of pyrolysis oils. The outlet gas composition is given for various types of oils obtained at different experimental conditions with a pyrolysis reactor. Given the complexity of the mixtures from processing of biomass, we present a study with methanol considered as a model molecule. This experimental method allows a first modeling approach based on a combustion kinetic model suitable to validate the coupling of plasma with conventional biomass process. The second part of the paper is summarizing results obtained through a plasma-pyrolysis reactor arrangement. The goal is to show the feasibility of this plasma-pyrolysis coupling and emphasize more fundamental studies to understand the role of the plasma in the biomass treatment processes.

  20. MICRO AUTO GASIFICATION SYSTEM: EMISSIONS ...

    Science.gov (United States)

    A compact, CONEX-housed waste to energy unit, Micro Auto Gasification System (MAGS), was characterized for air emissions from burning of military waste types. The MAGS unit is a dual chamber gasifier with a secondary diesel-fired combustor. Eight tests were conducted with multiple waste types in a 7-day period at the Kilauea Military Camp in Hawai’i. The emissions characterized were chosen based on regulatory emissions limits as well as their ability to cause adverse health effects on humans: particulate matter (PM), mercury, heavy metals, volatile organic compounds (VOCs), polyaromatic hydrocarbons (PAHs), and polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). Three military waste feedstock compositions reflecting the variety of wastes to be encountered in theatre were investigated: standard waste (SW), standard waste with increased plastic content (HP), standard waste without SW food components but added first strike ration (FSR) food and packaging material (termed FSR). A fourth waste was collected from the Kilauea dumpster that served the dining facility and room lodging (KMC). Limited scrubber water and solid ash residue samples were collected to obtain a preliminary characterization of these effluents/residues.Gasifying SW, HP, and KMC resulted in similar PCDD/PCDF stack concentrations, 0.26-0.27 ng TEQ/m3 at 7% O2, while FSR waste generated a notably higher stack concentration of 0.68 ng TEQ/m3 at 7% O2. The PM emission

  1. Potential application of gasification to recycle food waste and rehabilitate acidic soil from secondary forests on degraded land in Southeast Asia.

    Science.gov (United States)

    Yang, Zhanyu; Koh, Shun Kai; Ng, Wei Cheng; Lim, Reuben C J; Tan, Hugh T W; Tong, Yen Wah; Dai, Yanjun; Chong, Clive; Wang, Chi-Hwa

    2016-05-01

    Gasification is recognized as a green technology as it can harness energy from biomass in the form of syngas without causing severe environmental impacts, yet producing valuable solid residues that can be utilized in other applications. In this study, the feasibility of co-gasification of woody biomass and food waste in different proportions was investigated using a fixed-bed downdraft gasifier. Subsequently, the capability of biochar derived from gasification of woody biomass in the rehabilitation of soil from tropical secondary forests on degraded land (adinandra belukar) was also explored through a water spinach cultivation study using soil-biochar mixtures of different ratios. Gasification of a 60:40 wood waste-food waste mixture (w/w) produced syngas with the highest lower heating value (LHV) 5.29 MJ/m(3)-approximately 0.4-4.0% higher than gasification of 70:30 or 80:20 mixtures, or pure wood waste. Meanwhile, water spinach cultivated in a 2:1 soil-biochar mixture exhibited the best growth performance in terms of height (a 4-fold increment), weight (a 10-fold increment) and leaf surface area (a 5-fold increment) after 8 weeks of cultivation, owing to the high porosity, surface area, nutrient content and alkalinity of biochar. It is concluded that gasification may be an alternative technology to food waste disposal through co-gasification with woody biomass, and that gasification derived biochar is suitable for use as an amendment for the nutrient-poor, acidic soil of adinandra belukar. Copyright © 2016 Elsevier Ltd. All rights reserved.

  2. Dynamic models of staged gasification processes. Documentation of gasification simulator; Dynamiske modeller a f trinopdelte forgasningsprocesser. Dokumentation til forgasser simulator

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-02-15

    In connection with the ERP project 'Dynamic modelling of staged gasification processes' a gasification simulator has been constructed. The simulator consists of: a mathematical model of the gasification process developed at Technical University of Denmark, a user interface programme, IGSS, and a communication interface between the two programmes. (BA)

  3. Biomass Gasification Technology Assessment: Consolidated Report

    Energy Technology Data Exchange (ETDEWEB)

    Worley, M.; Yale, J.

    2012-11-01

    Harris Group Inc. (HGI) was commissioned by the National Renewable Energy Laboratory to assess gasification and tar reforming technologies. Specifically, the assessments focused on gasification and tar reforming technologies that are capable of producing a syngas suitable for further treatment and conversion to liquid fuels. HGI gathered sufficient information to analyze three gasification and tar reforming systems. This report summarizes the equipment, general arrangement of the equipment, operating characteristics, and operating severity for each technology. The order of magnitude capital cost estimates are supported by a basis-of-estimate write-up, which is also included in this report. The report also includes Microsoft Excel workbook models, which can be used to design and price the systems. The models can be used to analyze various operating capacities and pressures. Each model produces a material balance, equipment list, capital cost estimate, equipment drawings and preliminary general arrangement drawings. Example outputs of each model are included in the Appendices.

  4. Pressurized pyrolysis and gasification behaviour of black liquor and biofuels

    Energy Technology Data Exchange (ETDEWEB)

    Whitty, K.; Backman, R.; Hupa, M. [Aabo Akademi, Turku (Finland)

    1996-12-01

    The objective of this project is to obtain basic experimental data on pyrolysis and gasification of various black liquors and biofuels at elevated pressures, and to model these processes. Liquor-to-liquor differences in conversion behavior of single liquor droplets during gasification at atmospheric pressure were investigated. The applicability of a rate equation developed for catalyzed gasification of carbon was investigated with regard to pressurized black liquor gasification. A neural network was developed to simulate the progression of char conversion during pressurized black liquor gasification. Pyrolysis of black liquor in a pressurized drop-tube furnace was investigated in collaboration with KTH in Stockholm. (author)

  5. Numerical simulation of waste tyres gasification.

    Science.gov (United States)

    Janajreh, Isam; Raza, Syed Shabbar

    2015-05-01

    Gasification is a thermochemical pathway used to convert carbonaceous feedstock into syngas (CO and H2) in a deprived oxygen environment. The process can accommodate conventional feedstock such as coal, discarded waste including plastics, rubber, and mixed waste owing to the high reactor temperature (1000 °C-1600 °C). Pyrolysis is another conversion pathway, yet it is more selective to the feedstock owing to the low process temperature (350 °C-550 °C). Discarded tyres can be subjected to pyrolysis, however, the yield involves the formation of intermediate radicals additional to unconverted char. Gasification, however, owing to the higher temperature and shorter residence time, is more opted to follow quasi-equilibrium and being predictive. In this work, tyre crumbs are subjected to two levels of gasification modelling, i.e. equilibrium zero dimension and reactive multi-dimensional flow. The objective is to investigate the effect of the amount of oxidising agent on the conversion of tyre granules and syngas composition in a small 20 kW cylindrical gasifier. Initially the chemical compositions of several tyre samples are measured following the ASTM procedures for proximate and ultimate analysis as well as the heating value. The measured data are used to carry out equilibrium-based and reactive flow gasification. The result shows that both models are reasonably predictive averaging 50% gasification efficiency, the devolatilisation is less sensitive than the char conversion to the equivalence ratio as devolatilisation is always complete. In view of the high attained efficiency, it is suggested that the investigated tyre gasification system is economically viable. © The Author(s) 2015.

  6. High-Btu coal gasification processes

    Energy Technology Data Exchange (ETDEWEB)

    Blazek, C.F.; Baker, N.R.; Tison, R.R.

    1979-01-01

    This evaluation provides estimates of performance and cost data for advanced technology, high-Btu, coal gasification facilities. The six processes discussed reflect the current state-of-the-art development. Because no large commercial gasification plants have yet been built in the United States, the information presented here is based only on pilot-plant experience. Performance characteristics that were investigated include unit efficiencies, product output, and pollution aspects. Total installed plant costs and operating costs are tabulated for the various processes. The information supplied here will assist in selecting energy conversion units for an Integrated Community Energy System (ICES).

  7. Catalytic gasification of oil-shales

    Energy Technology Data Exchange (ETDEWEB)

    Lapidus, A.; Avakyan, T. [I.M. Gubkin Russian State Univ. of Oil and Gas, Moscow (Russian Federation); Strizhakova, Yu. [Samara State Univ. (Russian Federation)

    2012-07-01

    Nowadays, the problem of complex usage of solid fossil fuels as raw materials for obtaining of motor fuels and chemical products is becoming increasingly important. A one of possible solutions of the problem is their gasification with further processing of gaseous and liquid products. In this work we have investigated the process of thermal and catalytic gasification of Baltic and Kashpir oil-shales. We have shown that, as compared with non-catalytic process, using of nickel catalyst in the reaction increases the yield of gas, as well as hydrogen content in it, and decreases the amount of liquid products. (orig.)

  8. Microwave-assisted synthesis of geopolymers from fluidised bed gasifier bottom ash

    CSIR Research Space (South Africa)

    Oboirien, BO

    2013-09-01

    Full Text Available -1 International Conference of Coal Science and Technology, State College, Pennysylvania, USA, 29 September- 3 October 2013 Microwave-assisted synthesis of geopolymers from fluidised bed gasifier bottom ash B.O. Oboirien1, B.C. North1 and E. R. Sadiku2... 1CSIR Materials Science and Manufacturing, PO Box, 395, Pretoria 0001, South Africa boboiriencsir.co.za 2Tshwane University of Technology, Department of Polymer Technology, Pretoria South Africa Abstract Fluidised bed gasification (FBG...

  9. Biomass gasification with steam and oxygen mixtures at pilot scale and with catalytic gas upgrading. Pt. 1: performance of the gasifier

    Energy Technology Data Exchange (ETDEWEB)

    Aznar, M.P.; Gil, J.; Martin, M.A.; Caballero, M.A.; Olivares, A.; Perez, P.; Frances, E. [University of Zaragoza (Spain). Dept. of Chemical and Environmental Engineering; Corella, J. [University `Complutense` of Madrid (Spain). Dept. of Chemical Engineering

    1997-12-31

    Biomass gasification with steam + O{sub 2} mixtures is studied at small pilot plant (10-20 kg/h) scale. The gasifier used is a turbulent fluidised bed of 15 cm. i.d. and 3.3 m high. The pilot plant has a downstream slip flow to study the catalytic upgrading of the raw gas. A guard bed with dolomite and a catalytic bed with a steam reforming catalyst are used and eight different commercial catalysts have been tested to date. Product distribution from the gasifier, including gas proposition and tar content in the gas, are here shown in detail at different (steam + oxygen)/biomass and (H{sub 2}O/O{sub 2}) ratios and gasification temperatures (800-880{sup o}C). (author)

  10. Recent advances in AFB biomass gasification pilot plant with catalytic reactors in a downstream slip flow

    Energy Technology Data Exchange (ETDEWEB)

    Aznar, M.P.; Gil, J.; Martin, J.A.; Frances, E.; Olivares, A.; Caballero, M.A.; Perez, P. [Saragossa Univ. (Spain). Dept. of Chemistry and Environment; Corella, J. [Madrid Univ. (Spain)

    1996-12-31

    A new 3rd generation pilot plant is being used for hot catalytic raw gas cleaning. It is based on a 15 cm. i.d. fluidized bed with biomass throughputs of 400-650 kg/h.m{sup 2}. Gasification is performed using mixtures of steam and oxygen. The produced gas is passed in a slip flow by two reactors in series containing a calcined dolomite and a commercial reforming catalyst. Tars are periodically sampled and analysed after the three reactors. Tar conversions of 99.99 % and a 300 % increase of the hydrogen content in the gas are obtained. (author) (2 refs.)

  11. The characteristics of bed agglomeration during fluidized bed combustion of eucalyptus bark

    International Nuclear Information System (INIS)

    Chaivatamaset, Pawin; Tia, Suvit

    2015-01-01

    The bed agglomeration behaviors were investigated experimentally when eucalyptus bark was burning tested in a laboratory scale fluidized bed reactor. The focuses of this work were the influences of operating conditions and bed materials on the bed agglomeration tendency and the elucidation in the behaviors of fuel inorganic elements and the governing mode of the agglomeration. It was found that the defluidization caused by the bed agglomeration was clearly detectable from the decrease in measured bed pressure. The growth of bed particle and accumulation of agglomerates during combustion provided the partial to complete defluidization. The defluidization was promoted by the increase of bed temperature and bed particle size, and the decrease of fluidizing air velocity. The SEM-EDS analyses revealed that the bed agglomeration was mainly attributed to the formation of potassium silicate compounds as liquid phase during the combustion. This was initiated by the chemical reaction between the bed particle and the released ash constituents. In this study, the inorganic migration from fuel particle to bed particle was likely dominated by the condensation/reaction. The thermodynamic examination by ternary phase diagram analysis corroborated that the liquid phase formation of the ash derived materials controlled the agglomeration. The alumina sand prevented the bed agglomeration since it was inactive in the formation of viscous molten substances during combustion at the observed temperatures. - Highlights: • The behaviors of bed agglomeration were studied during the fluidized bed combustion of eucalyptus bark. • The increase in bed temperature and sand size, and the decrease of air velocity promoted bed defluidization. • The formation of molten potassium silicate compounds conduced to the bed agglomeration. • Condensation/reaction was the dominant inorganic migration mechanism from fuel particle to bed particle. • The alumina sand prevented effectively the bed

  12. Commercialization Development of Crop Straw Gasification Technologies in China

    Directory of Open Access Journals (Sweden)

    Zhengfeng Zhang

    2014-12-01

    Full Text Available Crop straw gasification technologies are the most promising biomass gasification technologies and have great potential to be further developed in China. However, the commercialization development of gasification technology in China is slow. In this paper, the technical reliability and practicability of crop straw gasification technologies, the economic feasibility of gas supply stations, the economic feasibility of crop straw gasification equipment manufacture enterprises and the social acceptability of crop straw gasification technologies are analyzed. The results show that presently both the atmospheric oxidation gasification technology and the carbonization pyrolysis gasification technology in China are mature and practical, and can provide fuel gas for households. However, there are still a series of problems associated with these technologies that need to be solved for the commercialization development, such as the high tar and CO content of the fuel gas. The economic feasibility of the gas supply stations is different in China. Parts of gas supply stations are unprofitable due to high initial investment, the low fuel gas price and the small numbers of consumers. In addition, the commercialization development of crop straw gasification equipment manufacture enterprises is hindered for the low market demand for gasification equipment which is related to the fund support from the government. The acceptance of the crop straw gasification technologies from both the government and the farmers in China may be a driving force of further commercialization development of the gasification technologies. Then, the crop straw gasification technologies in China have reached at the stage of pre-commercialization. At this stage, the gasification technologies are basically mature and have met many requirements of commercialization, however, some incentives are needed to encourage their further development.

  13. Fast microwave-assisted catalytic gasification of biomass for syngas production and tar removal.

    Science.gov (United States)

    Xie, Qinglong; Borges, Fernanda Cabral; Cheng, Yanling; Wan, Yiqin; Li, Yun; Lin, Xiangyang; Liu, Yuhuan; Hussain, Fida; Chen, Paul; Ruan, Roger

    2014-03-01

    In the present study, a microwave-assisted biomass gasification system was developed for syngas production. Three catalysts including Fe, Co and Ni with Al2O3 support were examined and compared for their effects on syngas production and tar removal. Experimental results showed that microwave is an effective heating method for biomass gasification. Ni/Al2O3 was found to be the most effective catalyst for syngas production and tar removal. The gas yield reached above 80% and the composition of tar was the simplest when Ni/Al2O3 catalyst was used. The optimal ratio of catalyst to biomass was determined to be 1:5-1:3. The addition of steam was found to be able to improve the gas production and syngas quality. Results of XRD analyses demonstrated that Ni/Al2O3 catalyst has good stability during gasification process. Finally, a new concept of microwave-assisted dual fluidized bed gasifier was put forward for the first time in this study. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. A comparative experimental study of biomass, lignite and hard coal steam gasification

    Energy Technology Data Exchange (ETDEWEB)

    Smolinski, A.; Howaniec, N.; Stanczyk, K. [Central Mining Institute, Katowice (Poland)

    2011-06-15

    In the paper the results of experimental comparative study on steam gasification of lignite, hard coal and energy crops, such as Spartina pectinata, Helianthus tuberosus L, Sida hermaphrodita R. and Miscanthus X Giganteus in a laboratory-scale fixed bed reactor at the temperature of 700 {sup o}C were presented. The effectiveness of steam gasification in terms of gas flows, composition and carbon conversion was tested. The ability of coal and biomass to undergo thermochemical transformations was determined based on their chars reactivities. The tested biomass samples were relatively more reactive but produced less synthesis gas and of lower calorific value. Comparison of the reactivities and other physical and chemical properties of coals and biomass, selected based on the gasification process requirements, with a use of the principal component analysis showed that biomass samples differ from the remaining samples due to the highest content of volatiles, oxygen and hydrogen in a sample and the highest amount of carbon dioxide in produced synthesis gas. Hard coals were characterized by the lowest carbon conversion and reactivities R{sub 50} and R{sub max}. Moreover, the negative correlation between the reactivity and the heat of combustion, calorific value, carbon content in a sample and total gas yield produced in the process as well as a positive correlation between R{sub 50} and R{sub max} and volatiles, oxygen content in a sample and carbon dioxide concentration in produced gas were observed.

  15. Study on Tar Generated from Downdraft Gasification of Oil Palm Fronds

    Science.gov (United States)

    Atnaw, Samson Mekbib; Kueh, Soo Chuan; Sulaiman, Shaharin Anwar

    2014-01-01

    One of the most challenging issues concerning the gasification of oil palm fronds (OPF) is the presence of tar and particulates formed during the process considering its high volatile matter content. In this study, a tar sampling train custom built based on standard tar sampling protocols was used to quantify the gravimetric concentration of tar (g/Nm3) in syngas produced from downdraft gasification of OPF. The amount of char, ash, and solid tar produced from the gasification process was measured in order to account for the mass and carbon conversion efficiency. Elemental analysis of the char and solid tar samples was done using ultimate analysis machine, while the relative concentration of the different compounds in the liquid tar was determined making use of a liquid gas chromatography (GC) unit. Average tar concentration of 4.928 g/Nm3 and 1.923 g/Nm3 was obtained for raw gas and cleaned gas samples, respectively. Tar concentration in the raw gas sample was found to be higher compared to results for other biomass materials, which could be attributed to the higher volatile matter percentage of OPF. Average cleaning efficiency of 61% which is comparable to that of sand bed filter and venturi scrubber cleaning systems reported in the literature was obtained for the cleaning system proposed in the current study. PMID:24526899

  16. Characterization of ash melting behaviour at high temperatures under conditions simulating combustible solid waste gasification.

    Science.gov (United States)

    Niu, Miaomiao; Dong, Qing; Huang, Yaji; Jin, Baosheng; Wang, Hongyan; Gu, Haiming

    2018-03-01

    To achieve high-temperature gasification-melting of combustible solid waste, ash melting behaviour under conditions simulating high-temperature gasification were studied. Raw ash (RA) and gasified ash (GA) were prepared respectively by waste ashing and fluidized bed gasification. Results of microstructure and composition of the two-ash indicated that GA showed a more porous structure and higher content of alkali and alkali earth metals among metallic elements. Higher temperature promoted GA melting and could reach a complete flowing state at about 1250°C. The order of melting rate of GA under different atmospheres was reducing condition > inert condition > oxidizing condition, which might be related to different existing forms of iron during melting and different flux content with atmosphere. Compared to RA, GA showed lower melting activity at the same condition due to the existence of an unconverted carbon and hollow structure. The melting temperature for sufficient melting and separation of GA should be at least 1250°C in this work.

  17. Biomass Integrated Gasification Combined Cycle for heat and power at ethanol plants

    Energy Technology Data Exchange (ETDEWEB)

    De Kam, Matthew J.; Vance Morey, R. [Department of Bioproducts and Biosystems Engineering, University of Minnesota, 1390 Eckles Ave, St. Paul, MN 55108 (United States); Tiffany, Douglas G. [Department of Applied Economics, University of Minnesota, 1994 Buford Avenue St. Paul, MN 55108 (United States)

    2009-07-15

    Biomass Integrated Gasification Combined Cycle (BIGCC) technology can be used to generate process heat and significant amounts of electricity at dry-grind ethanol facilities by utilizing the ethanol process co-products and other biomass sources. These systems can reduce fuel costs for ethanol plants, improve the renewable energy balance of dry-grind ethanol production, and provide reliable renewable electricity for process use and for sale to the local utility. An Aspen Plus model of the dry-grind ethanol process is used as the basis for a subsequent gasification system model. A twin fluidized bed steam gasification configuration based on the SilvaGas process is used to generate synthesis gas. The results show that a dry-grind ethanol facility with a capacity of 190 million liters per year could produce 30.4 MW{sub e} of power while supplying all its process heat needs using ethanol co-products and corn cobs. This configuration results in a three fold improvement in the amount of renewable energy produced per unit of fossil energy used compared to a conventional ethanol production process using natural gas. (author)

  18. Coal bed sequestration of carbon dioxide

    Science.gov (United States)

    Stanton, Robert; Flores, Romeo M.; Warwick, Peter D.; Gluskoter, Harold J.; Stricker, Gary D.

    2001-01-01

    Geologic sequestration of CO2 generated from fossil fuel combustion may be an environmentally attractive method to reduce the amount of greenhouse gas emissions. Of the geologic options, sequestering CO2 in coal beds has several advantages. For example, CO2 injection can enhance methane production from coal beds; coal can trap CO2 for long periods of time; and potential major coal basins that contain ideal beds for sequestration are near many emitting sources of CO2.One mission of the Energy Resources Program of the U.S. Geological Survey is to maintain assessment information of the Nation’s resources of coal, oil, and gas. The National Coal Resources Assessment Project is currently completing a periodic assessment of 5 major coal-producing regions of the US. These regions include the Powder River and Williston and other Northern Rocky Mountain basins (Fort Union Coal Assessment Team, 1999), Colorado Plateau area (Kirschbaum and others, 2000), Gulf Coast Region, Appalachian Basin, and Illinois Basin. The major objective of this assessment is to estimate available coal resources and quality for the major producing coal beds of the next 25 years and produce digital databases and maps. Although the focus of this work has been on coal beds with the greatest potential for mining, it serves as a basis for future assessments of the coal beds for other uses such as coal bed methane resources, in situ gasification, and sites for sequestration of CO2. Coal bed methane production combined with CO2 injection and storage expands the use of a coal resource and can provide multiple benefits including increased methane recovery, methane drainage of a resource area, and the long-term storage of CO2.

  19. Gasification under CO2–Steam Mixture: Kinetic Model Study Based on Shared Active Sites

    Directory of Open Access Journals (Sweden)

    Xia Liu

    2017-11-01

    Full Text Available In this work, char gasification of two coals (i.e., Shenfu bituminous coal and Zunyi anthracite and a petroleum coke under a steam and CO2 mixture (steam/CO2 partial pressures, 0.025–0.075 MPa; total pressures, 0.100 MPa and CO2/steam chemisorption of char samples were conducted in a Thermogravimetric Analyzer (TGA. Two conventional kinetic models exhibited difficulties in exactly fitting the experimental data of char–steam–CO2 gasification. Hence, a modified model based on Langmuir–Hinshelwood model and assuming that char–CO2 and char–steam reactions partially shared active sites was proposed and had indicated high accuracy for estimating the interactions in char–steam–CO2 reaction. Moreover, it was found that two new model parameters (respectively characterized as the amount ratio of shared active sites to total active sites in char–CO2 and char–steam reactions in the modified model hardly varied with gasification conditions, and the results of chemisorption indicate that these two new model parameters mainly depended on the carbon active sites in char samples.

  20. Environmental impact assessment for steeply dipping coal beds: North Knobs site

    Energy Technology Data Exchange (ETDEWEB)

    1978-11-08

    The US Department of Energy is funding an underground coal gasification (UCG) project in steeply dipping coal beds (SDB), at North Knobs, about 8 miles west of Rawlins, Carbon County, Wyoming. The project is being conducted to determine the technical, economic and environmental viability of such a technology. The development of SDB is an interesting target for UCG since such beds contain coals not normally mineable economically by ordinary techniques. Although the underground gasification of SDB has not been attempted in the US, Soviet experience and theoretical work indicate that the gasification of SDB in place offers all the advantages of underground gasification of horizontal coal seams plus some unique characteristics. The steep angle of dip helps to channel the produced gases up dip to offtake holes and permits the ash and rubble to fall away from the reaction zone helping to mitigate the blocking of the reaction zone in swelling coals. The intersection of SDB with the surface makes the seam accessible for drilling and other preparation. The tests at the North Knobs site will consist of three tests, lasting 20, 80 and 80 days, respectively. A total of 9590 tons of coal is expected to be gasified, with surface facilities utilizing 15 acres of the total section of land. The environmental effects of the experiment are expected to be very small. The key environmental impact is potential groundwater contamination by reaction products from coal gasification. There is good evidence that the surrounding coal effectively blocks the migration of these contaminants.

  1. DEMONSTRATION BULLETIN: TEXACO GASIFICATION PROCESS TEXACO, INC.

    Science.gov (United States)

    The Texaco Gasification Process (TGP) has operated commercially for nearly 45 years on feeds such as natural gas, liquid petroleum fractions, coal, and petroleum coke. More than 45 plants are either operational or under development in the United States and abroad. Texaco has dev...

  2. Catalytic gasification of dry and wet biomass

    NARCIS (Netherlands)

    van Rossum, G.; Potic, B.; Kersten, Sascha R.A.; van Swaaij, Willibrordus Petrus Maria

    2009-01-01

    Catalytic gasification of dry biomass and of wet biomass streams in hot compressed water are reviewed and discussed as potential technologies for the production of synthesis gas, hydrogen- and methane-rich gas. Next to literature data also new experimental results from our laboratory on catalytic

  3. MICRO AUTO GASIFICATION SYSTEM: EMISSIONS CHARACTERIZATION

    Science.gov (United States)

    A compact, CONEX-housed waste to energy unit, Micro Auto Gasification System (MAGS), was characterized for air emissions from burning of military waste types. The MAGS unit is a dual chamber gasifier with a secondary diesel-fired combustor. Eight tests were conducted with multipl...

  4. Hydrogen-Rich Syngas Production from Gasification and Pyrolysis of Solar Dried Sewage Sludge: Experimental and Modeling Investigations

    Directory of Open Access Journals (Sweden)

    Aïda Ben Hassen Trabelsi

    2017-01-01

    Full Text Available Solar dried sewage sludge (SS conversion by pyrolysis and gasification processes has been performed, separately, using two laboratory-scale reactors, a fixed-bed pyrolyzer and a downdraft gasifier, to produce mainly hydrogen-rich syngas. Prior to SS conversion, solar drying has been conducted in order to reduce moisture content (up to 10%. SS characterization reveals that these biosolids could be appropriate materials for gaseous products production. The released gases from SS pyrolysis and gasification present relatively high heating values (up to 9.96 MJ/kg for pyrolysis and 8.02  9.96 MJ/kg for gasification due to their high contents of H2 (up to 11 and 7 wt%, resp. and CH4 (up to 17 and 5 wt%, resp.. The yields of combustible gases (H2 and CH4 show further increase with pyrolysis. Stoichiometric models of both pyrolysis and gasification reactions were determined based on the global biomass formula, CαHβOγNδSε, in order to assist in the products yields optimization.

  5. Hydrogen-Rich Syngas Production from Gasification and Pyrolysis of Solar Dried Sewage Sludge: Experimental and Modeling Investigations

    Science.gov (United States)

    Ghrib, Amina; Friaa, Athar; Ouerghi, Aymen; Naoui, Slim; Belayouni, Habib

    2017-01-01

    Solar dried sewage sludge (SS) conversion by pyrolysis and gasification processes has been performed, separately, using two laboratory-scale reactors, a fixed-bed pyrolyzer and a downdraft gasifier, to produce mainly hydrogen-rich syngas. Prior to SS conversion, solar drying has been conducted in order to reduce moisture content (up to 10%). SS characterization reveals that these biosolids could be appropriate materials for gaseous products production. The released gases from SS pyrolysis and gasification present relatively high heating values (up to 9.96 MJ/kg for pyrolysis and 8.02  9.96 MJ/kg for gasification) due to their high contents of H2 (up to 11 and 7 wt%, resp.) and CH4 (up to 17 and 5 wt%, resp.). The yields of combustible gases (H2 and CH4) show further increase with pyrolysis. Stoichiometric models of both pyrolysis and gasification reactions were determined based on the global biomass formula, CαHβOγNδSε, in order to assist in the products yields optimization. PMID:28856162

  6. Economic viability of the construction and operation of a biomass gasificator for poultry houses heating

    Energy Technology Data Exchange (ETDEWEB)

    Zanatta, Fabio Luiz; Silva, Jadir Nogueira da; Tinoco, Ilda de Fatima Ferreira; Martin, Samuel; Melo, Lucas D.; Bueno, Mateus [Universidade Federal de Vicosa (DEA/UFV), MG (Brazil). Dept. de Engenharia Agricola], E-mail: fzanatta@vicosa.ufv.br

    2008-07-01

    In all poultry farms, at least in the first days of life of the chicken, it is necessary to heat the environment to obtain a good development of the chicken and good economics results. However, this additional heat generation is sometimes neglected or not well executed, because of the costs that this practice could bring. This research has the objective of analyze the costs of construction and operation of a Biomass Gasificator for Poultry Houses Heating in comparison with a direct furnace system. The fuel used in both systems was firewood of eucalyptus. For so much, economic analyzes was make considering the costs of the gasification systems implementation in substitution of the traditional system used in the company (direct furnace system). For the viability the adopted method was the partial budget and the complementary investments were analyzed through the cash flow elaboration and of determination of indicator of economic feasibility. (author)

  7. Co-gasification of different rank coals with biomass and petroleum coke in a high-pressure reactor for H(2)-rich gas production.

    Science.gov (United States)

    Fermoso, J; Arias, B; Gil, M V; Plaza, M G; Pevida, C; Pis, J J; Rubiera, F

    2010-05-01

    Four coals of different rank were gasified, using a steam/oxygen mixture as gasifying agent, at atmospheric and elevated pressure in a fixed bed reactor fitted with a solids feeding system in continuous mode. Independently of coal rank, an increase in gasification pressure led to a decrease in H(2) + CO production and carbon conversion. Gasification of the different rank coals revealed that the higher the carbon content and reactivity, the greater the hydrogen production. Co-gasification experiments of binary (coal-biomass) and ternary blends (coal-petcoke-biomass) were conducted at high pressure to study possible synergetic effects. Interactions between the blend components were found to modify the gas production. An improvement in hydrogen production and cold gas efficiency was achieved when the coal was gasified with biomass. Copyright 2009 Elsevier Ltd. All rights reserved.

  8. Preliminary experimental studies of waste coal gasification

    Energy Technology Data Exchange (ETDEWEB)

    Su, S.; Jin, Y.G.; Yu, X.X.; Worrall, R. [CSIRO, Brisbane, QLD (Australia). Advanced Coal Technology

    2013-07-01

    Coal mining is one of Australia's most important industries. It was estimated that coal washery rejects from black coal mining was approximately 1.82 billion tonnes from 1960 to 2009 in Australia, and is projected to produce another one billion tonnes by 2018 at the current production rate. To ensure sustainability of the Australian coal industry, we have explored a new potential pathway to create value from the coal waste through production of liquid fuels or power generation using produced syngas from waste coal gasification. Consequently, environmental and community impacts of the solid waste could be minimized. However, the development of an effective waste coal gasification process is a key to the new pathway. An Australian mine site with a large reserve of waste coal was selected for the study, where raw waste coal samples including coarse rejects and tailings were collected. After investigating the initial raw waste coal samples, float/sink testing was conducted to achieve a desired ash target for laboratory-scale steam gasification testing and performance evaluation. The preliminary gasification test results show that carbon conversions of waste coal gradually increase as the reaction proceeds, which indicates that waste coal can be gasified by a steam gasification process. However, the carbon conversion rates are relatively low, only reaching to 20-30%. Furthermore, the reactivity of waste coal samples with a variety of ash contents under N{sub 2}/air atmosphere have been studied by a home-made thermogravimetric analysis (TGA) apparatus that can make the sample reach the reaction temperature instantly.

  9. Testing of downstream catalysts for tar destruction with a guard bed in a fluidised bed biomass gasifier at pilot plant scale

    Energy Technology Data Exchange (ETDEWEB)

    Aznar, M.P.; Frances, E.; Campos, I.J.; Martin, J.A.; Gil, J. [Saragossa Univ. (Spain). Dept. of Chemistry and Environment Engineering; Corella, J. [Complutense Univ. of Madrid (Spain). Dept. of Chemical Engineering

    1996-12-31

    A new pilot plant for advanced gasification of biomass in a fast fluidised bed is now fully operative at University of Saragossa, Spain. It is a `3rd generation` pilot plant. It has been built up after having used two previous pilot plants for biomass gasification. The main characteristic of this pilot plant is that it has two catalytic reactors connected in series, downstream the biomass gasifier. Such reactors, of 4 cm i.d., are placed in a slip stream in a by-pass from the main gasifier exit gas. The gasification is made at atmospheric pressure, with flow rates of 3-50 kg/in, using steam + O{sub 2} mixtures as the gasifying agent. Several commercial Ni steam-reforming catalyst are being tested under a realistic raw gas composition. Tar eliminations or destructions higher than 99 % are easily achieved. (orig.) 2 refs.

  10. Operation of a semi-technical pilot plant for nuclear aided steam gasification of coal

    International Nuclear Information System (INIS)

    Kirchhoff, R.; Heek, K.H. van; Juentgen, H.; Peters, W.

    1984-01-01

    After intensive investigations on a small scale, the principle of the process has been tested in a semi-technical pilot plant. In its gasifier a fluidized bed of approx. 1 m 2 cross-section and of up to 4 m height is operated at 40 bar. Heat is supplied to the bed from an immersed heat exchanger with helium flowing through it, which is heated electrically. The plant was commissioned in 1976 and has been in hot operation for approx. 23000 h, over 13000 h whereof account for coal gasification. Roughly 1600 t of coal have been put through. During recent years the processing of German caking long-flame gas coal and the marked improvement of the process by the use of catalysts have been demonstrated successfully. (orig.)

  11. Optimisation of Experimental Conditions for Ex-Bed Desulfurization

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez, J. M.; Ruiz, E.; Otero, J.

    2010-12-22

    This report compiles the results of the work conducted by CIEMAT for Task 6.3 Sulfur and Nitrogen Compounds Abatement of the FLEXGAS project Near Zero Emission Advanced Fluidized Bed Gasification, which has been carried out with financial support from the Research Fund for Coal and Steel, RFCR-CT-2007-00005. The assignment of CIEMAT in Task 6.3 has dealt with the experimental study of ex-bed desulfurization at high temperature and high pressure. Based on a review of the state of the art, a zinc oxide sorbent was chosen as a promising candidate for bulk sulfur removal in highly reducing gases such as those from coal and waste oxygen gasification or for a polishing stage in low sulfur content gases, which is typically the case in biomass gasification gases. The work accomplished has included the study of the sulfidation and regeneration stages in order to determine successful operating conditions and the assessment of the long term performance of the sorbent over subsequent sulfidation and regeneration cycles. (Author) 36 refs.

  12. Process aspects in combustion and gasification Waste-to-Energy (WtE) units.

    Science.gov (United States)

    Leckner, Bo

    2015-03-01

    The utilisation of energy in waste, Waste to Energy (WtE), has become increasingly important. Waste is a wide concept, and to focus, the feedstock dealt with here is mostly municipal solid waste. It is found that combustion in grate-fired furnaces is by far the most common mode of fuel conversion compared to fluidized beds and rotary furnaces. Combinations of pyrolysis in rotary furnace or gasification in fluidized or fixed bed with high-temperature combustion are applied particularly in Japan in systems whose purpose is to melt ashes and destroy dioxins. Recently, also in Japan more emphasis is put on WtE. In countries with high heat demand, WtE in the form of heat and power can be quite efficient even in simple grate-fired systems, whereas in warm regions only electricity is generated, and for this product the efficiency of boilers (the steam data) is limited by corrosion from the flue gas. However, combination of cleaned gas from gasification with combustion provides a means to enhance the efficiency of electricity production considerably. Finally, the impact of sorting on the properties of the waste to be fed to boilers or gasifiers is discussed. The description intends to be general, but examples are mostly taken from Europe. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. Commercial steam reforming catalysts to improve biomass gasification with steam-oxygen mixtures. 2: Catalytic tar removal

    Energy Technology Data Exchange (ETDEWEB)

    Aznar, M.P.; Caballero, M.A.; Gil, J.; Martin, J.A. [Univ. of Saragossa (Spain). Chemical and Environmental Engineering Dept.; Corella, J. [Univ. Complutense of Madrid (Spain). Chemical Engineering Dept.

    1998-07-01

    Eight different commercial catalysts, nickel based, for steam reforming of naphthas and of natural gas are tested in biomass gasification for hot gas cleanup and conditioning. They were manufactured by BASF AG, ICI-Katalco, UCI, and Haldor Topsoee a/s. The catalysts were tested in a slip flow after a biomass gasifier of fluidized bed type at small pilot-plant scale (10--20 kg of biomass/h). The gasifying agent used is steam-oxygen mixtures. A guard bed containing a calcined dolomite is used to decrease the tar content in the gas at the inlet of the catalytic bed. Main variables studied are catalyst type, bed temperature, H{sub 2}O + O{sub 2} to biomass feed ratio, and time-on-stream. All catalysts for reforming of naphthas show to be very active and useful for tar removal and gas conditioning (in biomass gasification). 98% tar removal is easily obtained with space velocities of 14,000 h{sup {minus}1} (n.c.). No catalysts deactivation is found in 48 h-on-stream tests when the catalyst temperature is relatively high (780--830 C). Using a simple first-order kinetic model for the overall tar removal reaction, apparent energies of activation (of around 58 kJ/mol) and preexponential factors are obtained for the most active catalysts.

  14. Selected Environmental Aspects of Gasification and Co-Gasification of Various Types of Waste

    Directory of Open Access Journals (Sweden)

    Natalia Kamińska-Pietrzak

    2013-01-01

    Full Text Available The process of gasification of carbonaceous fuels is a technology with a long-standing practice. In recent years, the technology has been extensively developing to produce energy or chemicals on the basis of obtained gas. Studies focused on the improvement of the gasification process aims at developing the process by increasing environmental safety, the efficiency and the possibilities to utilize various types of alternative fuels (post-consumer waste, various types of biomass waste, by-products and post-process residues, sewage sludge independently or by co-gasification with coal. The choice of the gas purification system, the process operating parameters and introducing the necessary modifications to the existing technologies are essential steps while processing these kinds of feedstock, with regard to their individual characteristics. This paper discusses selected environmental aspects of the gasification and co-gasification of municipal solid waste, sewage sludge, various types of biomass waste and post-process residues. Selected alternative fuels are also characterized, focusing on the influence of their presence in the feedstock in terms of production and the emission of polychlorinated organic compounds, tars, heavy metals and toxic elements.

  15. Drilling in Underground Coal Gasification with Coiled Tubing Technologies

    Directory of Open Access Journals (Sweden)

    Monika Blišťanová

    2006-04-01

    Full Text Available Underground coal gasification is the potential to provide a clean, efficient and convenient source of energy from coal seams where traditional mining methods are either impossible or uneconomical. The latest drilling technology – drilling directional injection well with down well assembly. The is used world- wide from 1990 injection well is transmitting the coal seam along its location. The coil – tubing equipment transport the gasification agents (oxygen and water into the coal cavity, where give out gasification.

  16. Techno-Economic Analysis of Biofuels Production Based on Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Swanson, R. M.; Platon, A.; Satrio, J. A.; Brown, R. C.; Hsu, D. D.

    2010-11-01

    This study compares capital and production costs of two biomass-to-liquid production plants based on gasification. The first biorefinery scenario is an oxygen-fed, low-temperature (870?C), non-slagging, fluidized bed gasifier. The second scenario is an oxygen-fed, high-temperature (1,300?C), slagging, entrained flow gasifier. Both are followed by catalytic Fischer-Tropsch synthesis and hydroprocessing to naphtha-range (gasoline blend stock) and distillate-range (diesel blend stock) liquid fractions. Process modeling software (Aspen Plus) is utilized to organize the mass and energy streams and cost estimation software is used to generate equipment costs. Economic analysis is performed to estimate the capital investment and operating costs. Results show that the total capital investment required for nth plant scenarios is $610 million and $500 million for high-temperature and low-temperature scenarios, respectively. Product value (PV) for the high-temperature and low-temperature scenarios is estimated to be $4.30 and $4.80 per gallon of gasoline equivalent (GGE), respectively, based on a feedstock cost of $75 per dry short ton. Sensitivity analysis is also performed on process and economic parameters. This analysis shows that total capital investment and feedstock cost are among the most influential parameters affecting the PV.

  17. Mathematic modelling of a fixed-bed gasifier as component of a plant for decentral biomass utilisation; Mathematische Modellierung eines Festbettvergasers als Bestandteil einer Anlage zur dezentralen Nutzung von Biomasse

    Energy Technology Data Exchange (ETDEWEB)

    Funk, G.; Krumm, W. [Siegen Univ. (Gesamthochschule) (Germany). Lehrstuhl fuer Energie- und Umweltverfahrenstechnik

    2000-07-01

    This paper presents a two-dimensional nonstationary model that describes processes taking place during gasification in a fixed bed. For didactic purposes the process is split up into and described in terms of the partial models ''chemical reaction'', ''drying'', ''heat transfer'' and ''mass flow''. [German] Es wird ein zweidimensionales, instationaeres Modell zur Beschreibung der Vorgaenge bei der Vergasung im Festbett vorgestellt. Dabei werden zylinderfoermige Reaktoren betrachtet. Zur Beschreibung wird der Gesamtvorgang in die Teilmodelle 'chemische Reaktion', 'Trocknung', 'Waermeuebertragung' und 'Massefluss' unterteilt. Die einzelnen Teilmodelle werden vorgestellt. (orig.)

  18. Kinetic study of coals gasification into carbon dioxide atmosphere

    Directory of Open Access Journals (Sweden)

    Korotkikh A.G.

    2015-01-01

    Full Text Available The solid fuel gasification process was investigated to define chemical reactions rate and activation energy for a gas-generator designing and regime optimizing. An experimental procedure includes coal char samples of Kuznetskiy and Kansko-Achinskiy deposits consequent argon pyrolysis into argon and oxidating into carbon dioxide with different temperatures. The thermogravimetric analysis data of coal char gasification into carbon dioxide was obtained in the temperature range 900–1200 ºC. The mass loss and gasification time dependencies from temperature were defined to calculate chemical reaction frequency factor and activation energy. Two coal char gasification physico-mathematical models were proposed and recommendations for them were formed.

  19. Wood biomass gasification: Technology assessment and prospects in developing countries

    International Nuclear Information System (INIS)

    Salvadego, C.

    1992-05-01

    This investigation of the technical-economic feasibility of the development and use of wood biomass gasification plants to help meet the energy requirements of developing countries covers the following aspects: resource availability and production; gasification technologies and biomass gasification plant typology; plant operating, maintenance and safety requirements; the use of the biomass derived gas in internal combustion engines and boilers; and the nature of energy requirements in developing countries. The paper concludes with a progress report on biomass gasification research programs being carried out in developing countries world-wide

  20. A review of biomass gasification technologies in Denmark and Sweden

    DEFF Research Database (Denmark)

    Ridjan, Iva; Mathiesen, Brian Vad; Connolly, David

    This report provides an overview of existing technologies and projects in Denmark and Sweden with a focus on the Öresund region. Furthermore it presents the research and development of biomass gasification in the region and these two countries. The list of existing gasification plants from...... laboratory scale projects to big scale plants is given. The report ends with an overview of future gasification projects as well as potential experience exchanges that could occur between the countries. We regard biomass gasification as one of the key technologies in future renewable energy systems....

  1. Kinetics of gasification of black liquor char by steam

    International Nuclear Information System (INIS)

    Li, J.; van Heiningen, A.R.P.

    1991-01-01

    This paper reports on the steam gasification kinetics of kraft black liquor char that were studied in a thermogravimetric analysis reactor. The effect of steam and hydrogen concentration on gasification rate can be described by Langmuir-Hinshelwood type kinetics. An activation energy of 210 kJ/mol was obtained. Methane formation was negligible, and H 2 S was the major gaseous sulfur-containing product obtained over the temperature range studied, 873-973 K. The CO 2 concentration was higher than calculated for the water-shift reaction at equilibrium. A gasification mechanism is proposed whereby CO 2 is one of the primary gasification products

  2. Thermodynamic analysis of gasification-driven direct carbon fuel cells

    Science.gov (United States)

    Lee, Andrew C.; Mitchell, Reginald E.; Gür, Turgut M.

    The gasification-driven direct carbon fuel cell (GD-DCFC) system is compared with systems using separate gasification steps prior to work extraction, under autothermal or indirect constraints. Using simple system exergy analysis, the maximum work output of the indirect gasification scheme is 4-7% lower than the unconstrained direct approach, while the work output of the autothermal gasification approach is 12-13% lower than the unconstrained case. A more detailed calculation for the DCFC and indirect gasification plants, using common solid fuel compositions, gives conversion efficiencies in the range of 51-58% at an operating voltage of 0.7 V selected for both systems in this study. In contrast, the conversion efficiency of the autothermal gasification approach is estimated to be 33-35% at 0.7 V. DCFC efficiencies can be increased to over 60% by an increase in operating voltage and/or inclusion of a bottoming cycle. The thermodynamic model also indicates that steam gasification yields similar work output and thermal efficiency as for CO 2 gasification. Open circuit potential measurements agree with equilibrium calculations both for the C-O and C-H-O gasification systems, confirming the governing mechanism and feasibility of the GD-DCFC. Current-voltage measurements on an un-optimized system demonstrate power densities of 220 mW cm -2 at 0.68 V during operation at 1178 K.

  3. Thermodynamic analysis of gasification-driven direct carbon fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Andrew C.; Mitchell, Reginald E. [Department of Mechanical Engineering, Stanford University, 452 Escondido Mall, Building 520, Stanford, CA 94305 (United States); Guer, Turgut M. [Department of Materials Science and Engineering, Stanford University, 496 Lomita Mall, Durand Building, Stanford, CA 94305 (United States); Direct Carbon Technologies, LLC, Palo Alto, CA 94301 USA

    2009-12-01

    The gasification-driven direct carbon fuel cell (GD-DCFC) system is compared with systems using separate gasification steps prior to work extraction, under autothermal or indirect constraints. Using simple system exergy analysis, the maximum work output of the indirect gasification scheme is 4-7% lower than the unconstrained direct approach, while the work output of the autothermal gasification approach is 12-13% lower than the unconstrained case. A more detailed calculation for the DCFC and indirect gasification plants, using common solid fuel compositions, gives conversion efficiencies in the range of 51-58% at an operating voltage of 0.7 V selected for both systems in this study. In contrast, the conversion efficiency of the autothermal gasification approach is estimated to be 33-35% at 0.7 V. DCFC efficiencies can be increased to over 60% by an increase in operating voltage and/or inclusion of a bottoming cycle. The thermodynamic model also indicates that steam gasification yields similar work output and thermal efficiency as for CO{sub 2} gasification. Open circuit potential measurements agree with equilibrium calculations both for the C-O and C-H-O gasification systems, confirming the governing mechanism and feasibility of the GD-DCFC. Current-voltage measurements on an un-optimized system demonstrate power densities of 220 mW cm{sup -2} at 0.68 V during operation at 1178 K. (author)

  4. Roadmap for the commercialisation of biomass gasification. A critical evaluation, tips, questions and pitfalls

    International Nuclear Information System (INIS)

    Huisman, G.H.

    2000-10-01

    Biomass has the potential to be a major replacement of fossil fuels. The world wide availability of biomass is considerable but it is not always in balance with the anticipated consumption. Biomass (wood) has the disadvantage that it has a low energy density and transport costs are, therefore, relatively high. Combustion, being a well-developed technology with many references, is the obvious choice for conversion technology. On the scale that biomass plants are usually constructed, however, the overall efficiency of the combustion system is low. Gasification has the advantage that solid fuel is converted into gaseous fuel which can be used in IC (internal combustion) engines or combined (gas and steam turbine) cycles with high efficiency. Even on a very small scale (several hundred kWe) a biomass-driven IC engine can have an efficiency of around 25%. Gasification has not yet advanced to the stage that it can serve as a reliable conversion technology for supplying electric power to industry or to the national grid. This may be possible on paper but in practice the market needs to be convinced by the success of plants in full operation. The first generation of plants, now under construction, or in operation, have to demonstrate the technology and provide confidence for future developments. Fixed bed gasification in combination with IC engines is more appropriate for small units. The development in micropower units is of particular interest. This development has been initiated for natural gas-fuelled units supplying power and heat to households, apartment blocks or offices. Once the fuel handling problems have been overcome and the units are more reliable and easier to operate, this could be a market with ample cost savings on the basis of mass production. Fluidised bed gasification, integrated with a combined cycle, is probably better suited to larger units, above 10 MWe. After experience has been obtained with units at an atmospheric pressure, the increase of the

  5. Effect of reactions in small eddies on biomass gasification with eddy dissipation concept - Sub-grid scale reaction model.

    Science.gov (United States)

    Chen, Juhui; Yin, Weijie; Wang, Shuai; Meng, Cheng; Li, Jiuru; Qin, Bai; Yu, Guangbin

    2016-07-01

    Large-eddy simulation (LES) approach is used for gas turbulence, and eddy dissipation concept (EDC)-sub-grid scale (SGS) reaction model is employed for reactions in small eddies. The simulated gas molar fractions are in better agreement with experimental data with EDC-SGS reaction model. The effect of reactions in small eddies on biomass gasification is emphatically analyzed with EDC-SGS reaction model. The distributions of the SGS reaction rates which represent the reactions in small eddies with particles concentration and temperature are analyzed. The distributions of SGS reaction rates have the similar trend with those of total reactions rates and the values account for about 15% of the total reactions rates. The heterogeneous reaction rates with EDC-SGS reaction model are also improved during the biomass gasification process in bubbling fluidized bed. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. PFB air gasification of biomass. Investigation of product formation and problematic issues related to ammonia, tar and alkali

    Energy Technology Data Exchange (ETDEWEB)

    Padban, Nader

    2000-09-01

    Fluidised bed thermal gasification of biomass is an effective route that results in 100 % conversion of the fuel. In contrast to chemical, enzymatic or anaerobic methods of biomass treatment, the thermal conversion leaves no contaminated residue after the process. The product gas evolved within thermal conversion can be used in several applications such as: fuel for gas turbines, combustion engines and fuel cells, and raw material for production of chemicals and synthetic liquid fuels. This thesis treats a part of the experimental data from two different gasifiers: a 90 kW{sub th} pressurised fluidised bubbling bed gasifier at Lund University and a 18 MW{sub th} circulating fluidised bed gasifier integrated with gas turbine (IGCC) in Vaernamo. A series of parallel and consecutive chemical reactions is involved in thermal gasification, giving origin to formation of a variety of products. These products can be classified within three major groups: gases, tars and oils, and char. The proportion of these categories of species in the final product is a matter of the gasifier design and the process parameters. The thesis addresses the technical and theoretical aspects of the biomass thermochemical conversion and presents a new approach in describing the gasification reactions. There is an evidence of fuel effect on the characteristics of the final products: a mixture of plastic waste (polyethylene) and biomass results in higher concentration of linear hydrocarbons in the gas than gasification of pure biomass. Mixing the biomass with textile waste (containing aromatic structure) results in a high degree of formation of aromatic compounds and light tars. Three topic questions within biomass gasification, namely: tar, NO{sub x} and alkali are discussed in the thesis. The experimental results show that gasification at high ER or high temperature decreases the total amount of the tars and simultaneously reduces the contents of the oxygenated and alkyl-substituted poly

  7. Gasification characteristics of auto shredder residue

    International Nuclear Information System (INIS)

    Navee, S.; Ramzan, N.

    2011-01-01

    Given the large volume of used tyre waste generated each year it is imperative that suitable re-use and disposal techniques are developed for dealing with this problem; presently these include rethreading, reprocessing for use as safe playground and sports surfaces, use as noise reduction barriers and utilisation as a fuel source. This paper reports on pilot scale studies designed to investigate the suitability of automotive waste for energy recovery via gasification. The study was carried out into auto shredder residue, which is a mixture of three distinct waste streams: tyres, rubber/plastic and general automotive waste. The tests included proximate, ultimate and elemental analysis, TGA, as well as calorific value determinations. In addition, the waste was tested in a desktop gasifier, and analysis was carried out to determine the presence and type of combustible gases. It was concluded that tyre waste and rubber/plastic waste are quite suitable fuels for gasification. (author)

  8. Down-flow moving-bed gasifier with catalyst recycle

    Science.gov (United States)

    Halow, John S.

    1999-01-01

    The gasification of coal and other carbonaceous materials by an endothermic gasification reaction is achieved in the presence of a catalyst in a down-flow, moving-bed gasifier. Catalyst is removed along with ash from the gasifier and is then sufficiently heated in a riser/burner by the combustion of residual carbon in the ash to volatilize the catalyst. This volatilized catalyst is returned to the gasifier where it uniformly contacts and condenses on the carbonaceous material. Also, the hot gaseous combustion products resulting from the combustion of the carbon in the ash along with excess air are introduced into the gasifier for providing heat energy used in the endothermic reaction.

  9. Development of catalytic gas cleaning in gasification

    Energy Technology Data Exchange (ETDEWEB)

    Simell, P.; Kurkela, E.; Staahlberg, P.; Hepola, J. [VTT Energy, Espoo (Finland)

    1996-12-31

    Gasification gas containing dust can be efficiently purified from tars and ammonia with a nickel monolith catalyst. Temperatures of >900 deg C and a residence time of about 1 s (SV 2 500 1/h) were needed at 5 bar pressure to achieve complete tar decomposition and 80 % ammonia conversion. Catalyst deactivation was not observed during test runs of 100 h. At lower pressures dolomites and limestones can also be applied for tar removal at about 900 deg C temperatures. (orig.) 12 refs.

  10. Pilot-scale gasification of woody biomass

    Science.gov (United States)

    Thomas Elder; Leslie H. Groom

    2011-01-01

    The gasification of pine and mixed-hardwood chips has been carried out in a pilot-scale system at a range of gas flow rates. Consuming ~17-30 kgh-1 of feedstock, the producer gas was composed of ~200 dm3 m-3 carbon monoxide, 12 dm3 m-3 carbon dioxide, 30 dm3 m-3 methane and 190 dm3 m-3 hydrogen, with an energy content of ~6 MJ m-3 for both feedstocks. It was found that...

  11. EXPERIMENT OF PEAT GASIFICATION IN PLASMA REACTOR

    OpenAIRE

    Lázár, Marián; Lengyelová, Marta; Kurilla, Peter

    2012-01-01

    Gasification of solid and low quality fuel from the economic point is not a new idea or a new technology. Industrial applications for the production of energo gas from coal dates back to the beginning of the nineteenth century, whilst the construction of several large industrial plants for producing the electricity from coal and heavy oil fractions have been launched in the United States and Europe in the last 40 years. The aim of this contribution is to verify the assessment of u...

  12. Development of coal hydro gasification technology

    International Nuclear Information System (INIS)

    Itoh, Kazuo; Nomura, Kazuo; Asaoka, Yoshikiyo; Kato, Shojiro; Seo, Tomoyuki

    1997-01-01

    Taking a potential future decrease in natural gas supply into consideration, we are looking for a way to secure a stable supply of high quality substitute natural gas made from coal (which occurs abundantly throughout the world) in large volumes at low cost. We are working towards our goal of commercializing coal hydro gasification technology in the 2010's and have started developing elemental technology from FY, 1996 as a part of the governmental new energy program. (au)

  13. Minimum rate of spouting and peak pressure-drop in a spouted bed

    International Nuclear Information System (INIS)

    Ogino, Fumiaru; Zhang, Laiying; Maehashi, Yasuo

    1993-01-01

    Spouted beds are a type of fluidized bed, but one which has certain advantages, viz., (1) the capability of handling coarse particles; (2) the capability of handling particles with complicated shapes; (3) the absence of the need to have a high flow-rate; and (4) a small pressure drop. The first and second of these advantages, in particular, are responsible for spouted beds having found use in industry in the drying of powdered materials, in granulation apparatus, in the roasting of mineral ores, and in waste incinerators, while their application in coal gasification and shale pyrolysis is, also, examined

  14. Bed models for solid fuel conversion process in grate-fired boilers

    DEFF Research Database (Denmark)

    Costa, M.; Massarotti, N.; Indrizzi, V.

    2013-01-01

    Because of the complexity to describe and solve thermo-chemical processes occurring in a fuel bed in grate-fired boiler, it is often necessary to simplify the process and use modeling techniques based on overall mass, energy and species conservation. A comparison between two numerical models...... to describe the thermo-chemical conversion process of a solid fuel bed in a grate-fired boiler is presented. In this work both models consider the incoming solid fuel as subjected to drying, pyrolysis, gasification and combustion. In the first approach the biomass bed is treated as a 0D system, but the thermo...

  15. GASIFICATION TEST RUN TC06

    Energy Technology Data Exchange (ETDEWEB)

    Southern Company Services, Inc.

    2003-08-01

    This report discusses test campaign TC06 of the Kellogg Brown & Root, Inc. (KBR) Transport Reactor train with a Siemens Westinghouse Power Corporation (Siemens Westinghouse) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Reactor is an advanced circulating fluidized-bed reactor designed to operate as either a combustor or a gasifier using a particulate control device (PCD). The Transport Reactor was operated as a pressurized gasifier during TC06. Test run TC06 was started on July 4, 2001, and completed on September 24, 2001, with an interruption in service between July 25, 2001, and August 19, 2001, due to a filter element failure in the PCD caused by abnormal operating conditions while tuning the main air compressor. The reactor temperature was varied between 1,725 and 1,825 F at pressures from 190 to 230 psig. In TC06, 1,214 hours of solid circulation and 1,025 hours of coal feed were attained with 797 hours of coal feed after the filter element failure. Both reactor and PCD operations were stable during the test run with a stable baseline pressure drop. Due to its length and stability, the TC06 test run provided valuable data necessary to analyze long-term reactor operations and to identify necessary modifications to improve equipment and process performance as well as progressing the goal of many thousands of hours of filter element exposure.

  16. A utilização da gaseificação de pneus usados em leito fluidizado para a produção de energéticos Gasification of used tires in fluidized bed reactor to produce energy sources

    Directory of Open Access Journals (Sweden)

    Eduardo A. Goulart

    1999-12-01

    proposal of a reactor which uses scrap tires to fuel oil using the gasification process.

  17. Sugarcane bagasse gasification: Global reaction mechanism of syngas evolution

    International Nuclear Information System (INIS)

    Ahmed, I.I.; Gupta, A.K.

    2012-01-01

    Highlights: ► Gasification of sugarcane bagasse has been investigated using a semi batch reactor. ► Global reaction mechanism combining pyrolysis and gasification reactions is presented. ► High flow rates of syngas supported fragmentation and secondary reactions. ► CO flow rate increased at higher heating rates at the expense of CO 2 production. ► At high temperatures merger between pyrolysis and char gasification occurs. -- Abstract: Steam gasification of sugarcane bagasse has been investigated. A semi batch reactor with a fixed amount of sugarcane bagasse sample placed in steady flow of high temperature steam at atmospheric pressure has been used. The gasification of bagasse was examined at reactor and steam temperatures of 800, 900 and 1000 °C. The evolution of syngas flow rate and chemical composition has been monitored. The evolution of chemical composition and total flow rate of the syngas has been used to formulate a global reaction mechanism. The mechanism combines pyrolysis reaction mechanisms from the literature and steam gasification/reforming reactions. Steam gasification steps include steam–hydrocarbons reforming, char gasification and water gas shift reactions. Evidence of fragmentation, secondary ring opening reactions and tertiary reactions resulting in formation of gaseous hydrocarbons is supported by higher flow rates of syngas and hydrogen at high heating rates and high reactor temperatures. Increase in carbon monoxide flow rate at the expense of carbon dioxide flow rate with the increase in reactor temperature has been observed. This increase in the ratio of CO/CO 2 flow rate confirms the production of CO and CO 2 from the competing reaction routes. At 1000 °C gasification a total merging between the pyrolysis step and the char gasification step has been observed. This is attributed to acceleration of char gasification reactions and acceleration of steam–hydrocarbons reforming reactions. These hydrocarbons are the precursors to

  18. Study on the structure and gasification characteristics of selected South African bituminous coal in fluidised bed gasification

    CSIR Research Space (South Africa)

    Oboirien, BO

    2009-10-01

    Full Text Available . The microstructural characteristics of the parent coals and their resultant chars were determined using XRD, FTIR, Raman and petrographic analysis. The microstructural changes that occurred in the organic (maceral) and the inorganic (mineral) fractions of the selected...

  19. Study on the structure and gasification characteristics of selected South African bituminous coals in fluidised bed gasification

    CSIR Research Space (South Africa)

    Oboirien, BO

    2011-04-01

    Full Text Available . The microstructural characteristics of the parent coals and their resultant chars were determined using XRD, FT-IR, Raman and petrographic analysis. The microstructural changes that occurred in the organic (maceral) and the inorganic (mineral) fractions...

  20. System studies on Biofuel production via Integrated Biomass Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, Jim; Lundgren, Joakim [Luleaa Univ. of Technology Bio4Energy, Luleaa (Sweden); Malek, Laura; Hulteberg, Christian [Lund Univ., Lund (Sweden); Pettersson, Karin [Chalmers Univ. of Technology, Goeteborg (Sweden); Wetterlund, Elisabeth [Linkoeping Univ. Linkoeping (Sweden)

    2013-09-01

    A large number of national and international techno-economic studies on industrially integrated gasifiers for production of biofuels have been published during the recent years. These studies comprise different types of gasifiers (fluidized bed, indirect and entrained flow) integrated in different industries for the production of various types of chemicals and transportation fuels (SNG, FT-products, methanol, DME etc.) The results are often used for techno-economic comparisons between different biorefinery concepts. One relatively common observation is that even if the applied technology and the produced biofuel are the same, the results of the techno-economic studies may differ significantly. The main objective of this project has been to perform a comprehensive review of publications regarding industrially integrated biomass gasifiers for motor fuel production. The purposes have been to identify and highlight the main reasons why similar studies differ considerably and to prepare a basis for fair techno-economic comparisons. Another objective has been to identify possible lack of industrial integration studies that may be of interest to carry out in a second phase of the project. Around 40 national and international reports and articles have been analysed and reviewed. The majority of the studies concern gasifiers installed in chemical pulp and paper mills where black liquor gasification is the dominating technology. District heating systems are also well represented. Only a few studies have been found with mechanical pulp and paper mills, steel industries and the oil refineries as case basis. Other industries have rarely, or not at all, been considered for industrial integration studies. Surprisingly, no studies regarding integration of biomass gasification neither in saw mills nor in wood pellet production industry have been found. In the published economic evaluations, it has been found that there is a large number of studies containing both integration and

  1. Hydrogen-rich syngas production and tar removal from biomass gasification using sacrificial tyre pyrolysis char

    International Nuclear Information System (INIS)

    Al-Rahbi, Amal S.; Williams, Paul T.

    2017-01-01

    Highlights: • Tyre char is used as catalyst and syngas source in pyrolysis-reforming of biomass. • Metals in tyre char catalyse tar decomposition. • Increased steam and higher temperature promotes H 2 production. • Syngas H 2 /CO ratio varied between 1.3 to 2. • A waste derived catalyst degrades tar and is also sacrificed for char gasification. - Abstract: Carbonaceous materials have been proven to have a high catalytic activity for tar removal from the syngas produced from biomass gasification. The simultaneous reforming and gasification of pyrolysis gases and char could have a significant role in increasing the gas yield and decreasing the tar in the product syngas. This study investigates the use of tyre char as a catalyst for H 2 -rich syngas production and tar reduction during the pyrolysis-reforming of biomass using a two stage fixed bed reactor. The biomass sample was pyrolysed under nitrogen at a pyrolysis temperature of 500 °C, the evolved pyrolysis volatiles were passed to a second stage with steam and the gases were reformed in the presence of tyre char as catalyst. The influence of catalyst bed temperature, steam to biomass ratio, reaction time and tyre ash metals were investigated. The influence of the catalytic activity of tyre ash minerals on composition of syngas and tar decomposition during the steam reforming of biomass was significant as the removal of minerals led to a decrease in the H 2 yield. Raising the steam injection rate and reforming temperature resulted in an increase in H 2 production as steam reforming and char gasification reactions were enhanced. The maximum H 2 content in the product syngas of 56 vol.% was obtained at a reforming temperature of 900 °C and with a steam to biomass mass ratio of 6 (g/g). Further investigation of the influence of the biomass:steam ratio on syngas quality showed that the H 2 :CO molar ratio was increased from 1.8 (steam: biomass ratio; 1.82 g g −1 ) to 3 (steam: biomass ratio; 6 g g −1 ).

  2. Feasibility of Biomass Biodrying for Gasification Process

    Science.gov (United States)

    Hamidian, Arash

    An important challenge of biomass gasification is the limitation of feedstock quality especially the moisture content, which plays a significant role on the performance of gasification process. Gasification requires low moisture levels (20% and less) and several reports have emphasized on the moisture as a typical problem while gasifying biomass. Moisture affects overall reaction rates in the gasifiers as a result of temperature drop and ultimately increases tar content, decreases gas yield, changes the composition of produced gas and affects the efficiency. Therefore, it is mandatory to pre-treat the biomass before gasification and reduce the moisture content to the suitable and economic level. The well-known solutions are either natural drying (not practical for commercial plants) or conventional drying technologies (have high operating costs). Biodrying is an alternative process, which uses both convective air and heat of biological reactions as a source of energy, to reduce the moisture. In the biodrying reactor heat is generated from exothermic decomposition of organic fraction of biomass and that is why the process is called "self-heating process". Employing such technology for drying biomass at pre-treatment units of gasification process returns several economic and environmental advantages to mills. In Europe, municipal waste treatment (MSW) plants use the biodrying at commercial scale to degrade a part of the biodegradable fraction of waste to generate heat and reduce the moisture content for high quality SRF (Solid Recovered Fuel) production. In Italy, wine industry is seeking to develop biodrying for energy recovery of grape wastes after fermentation and distillation, which returns economic benefits to the industry. In Canada, the development of biodrying technology for pulp and paper industry was started at Ecole polytechnique de Montreal as an option for sludge management solution. Therefore, batch biodrying reactor was successfully developed in 2004

  3. Performance Analysis of an Integrated Fixed Bed Gasifier Model for Different Biomass Feedstocks

    Directory of Open Access Journals (Sweden)

    Sharmina Begum

    2013-12-01

    Full Text Available Energy recovery from biomass by gasification technology has attracted significant interest because it satisfies a key requirement of environmental sustainability by producing near zero emissions. Though it is not a new technology, studies on its integrated process simulation and analysis are limited, in particular for municipal solid waste (MSW gasification. This paper develops an integrated fixed bed gasifier model of biomass gasification using the Advanced System for Process ENngineering (Aspen Plus software for its performance analysis. A computational model was developed on the basis of Gibbs free energy minimization. The model is validated with experimental data of MSW and food waste gasification available in the literature. A reasonable agreement between measured and predicted syngas composition was found. Using the validated model, the effects of operating conditions, namely air-fuel ratio and gasifier temperature, on syngas production are studied. Performance analyses have been done for four different feedstocks, namely wood, coffee bean husks, green wastes and MSWs. The ultimate and proximate analysis data for each feedstock was used for model development. It was found that operating parameters have a significant influence on syngas composition. An air-fuel ratio of 0.3 and gasifier temperature of 700 °C provides optimum performance for a fixed bed gasifier for MSWs, wood wastes, green wastes and coffee bean husks. The developed model can be useful for gasification of other biomasses (e.g., food wastes, rice husks, poultry wastes and sugarcane bagasse to predict the syngas composition. Therefore, the study provides an integrated gasification model which can be used for different biomass feedstocks.

  4. Supercritical Water Gasification of Biomass : A Literature and Technology Overview

    NARCIS (Netherlands)

    Yakaboylu, O.; Harinck, J.; Smit, K.G.; De Jong, W.

    2014-01-01

    The supercritical water gasification process is an alternative to both conventional gasification as well as anaerobic digestion as it does not require drying and the process takes place at much shorter residence times; a few minutes at most. The drastic changes in the thermo-physical properties of

  5. Methods for sequestering carbon dioxide into alcohols via gasification fermentation

    Science.gov (United States)

    Gaddy, James L; Ko, Ching-Whan; Phillips, J. Randy; Slape, M. Sean

    2013-11-26

    The present invention is directed to improvements in gasification for use with synthesis gas fermentation. Further, the present invention is directed to improvements in gasification for the production of alcohols from a gaseous substrate containing at least one reducing gas containing at least one microorganism.

  6. BIOMASS REACTIVITY IN GASIFICATION BY THE HYNOL PROCESS

    Science.gov (United States)

    A thermobalance reactor was used to evaluate the reactivity of poplar wood in gasification under the operating conditions specific for the Hynol process where biomass is gasified at 30 atm and 800E C with a hydrogen-rich gas recycled from methane synthesis. The gasification invol...

  7. Robustness studies on coal gasification process variables | Coetzer ...

    African Journals Online (AJOL)

    Optimisation of the Sasol-Lurgi gasification process was carried out by utilising the method of Factorial Experimental Design on the process variables of interest from a specifically equipped full-scale test gasifier. The process variables that govern gasification are not always fully controllable during normal operation.

  8. Analysis of Operation Parameters in a Dual Fluidized Bed Biomass Gasifier Integrated with a Biomass Rotary Dryer: Development and Application of a System Model

    Directory of Open Access Journals (Sweden)

    Nargess Puadian

    2014-07-01

    Full Text Available An integrated system model was developed in UniSim Design for a dual fluidized bed (DFB biomass gasifier and a rotary biomass dryer using a combination of user-defined and built-in unit operations. A quasi-equilibrium model was used for modelling biomass steam gasification in the DFB gasifier. The biomass drying was simulated with consideration of mass and energy balances, heat transfer, and dryer’s configuration. After validation using experimental data, the developed system model was applied to investigate: (1 the effects of gasification temperature and steam to biomass (S/B ratio on the gasification performance; (2 the effect of air supplied to the fast fluidized bed (FFB reactor and feed biomass moisture content on the integrated system performance, energy and exergy efficiencies. It was found that gasification temperature and S/B ratio have positive effects on the gasification yields; a H2/CO ratio of 1.9 can be achieved at the gasification temperature of 850 °C with a S/B ratio of 1.2. Consumption of excessive fuel in the system at higher biomass feed moisture content can be compensated by the heat recovery such as steam generation while it has adverse impact on exergy efficiency of the system.

  9. Pyrolysis and gasification behavior of black liquor under pressurized conditions

    Energy Technology Data Exchange (ETDEWEB)

    Whitty, K.

    1997-11-01

    The purpose of this study has been to enhance the understanding of the processes involved in pressurized black liquor gasification. Gasification is known to occur in three stages: drying, pyrolysis and char gasification. The work presented here focuses on the pyrolysis and gasification stages. Experiments were carried out primarily in two laboratory-scale reactors. A pressurized grid heater was used to study black liquor pyrolysis under pressurized conditions. Char yields and the fate of elements in the liquor, as well as the degree of liquor swelling, were measured in this device. A pressurized thermogravimetric reactor was used to measure the rate of the char gasification process under different temperatures and pressures and in various gas atmospheres. Pyrolysis experiments were also carried out in this device, and data on swelling behavior, char yields and component release were obtained 317 refs.

  10. An overview of world history of underground coal gasification

    Science.gov (United States)

    Konovšek, Damjan; Nadvežnik, Jakob; Medved, Milan

    2017-07-01

    We will give an overview of the activities in the field of underground coal gasification in the world through history. Also we will have a detailed presentation of the most successful and the most recent research and development projects. The currency and scope of the study of coal gasification processes are linked through recent history to the price of crude oil. We will show how by changing oil prices always changes the interest for investment in research in the field of coal gasification. Most coal-producing countries have developed comprehensive programs that include a variety of studies of suitable coal fields, to assess the feasibility and design pilot and commercial projects of underground coal gasification. The latest technologies of drilling in oil and gas industry now enable easier, simpler and more economically viable process underground coal gasification. The trend of increasing research in this area will continue forward until the implementation of commercial projects.

  11. Clean Coal and Gasification Technology: How it Works?

    Directory of Open Access Journals (Sweden)

    Marina Sidorová

    2006-10-01

    Full Text Available Gasification of coal is the oldest method for the production of hydrogen. Coal gasification is a process that converts coal from a solid to a gaseous state. The gas that is created is very similar to natural gas and can be used to produce chemicals, fertilizers, and/or the electric power [1]. Cleanest of all coal-based electric power technologies, gasification has significantly lower levels of air emissions (including volatile mercury, solid wastes, and wastewater.Due to its high efficiencies, gasification also uses less coal to produce the same amount of energy, resulting in lower carbon dioxide (CO2 emissions. Some scientists believe that CO2 in the atmosphere contributes to a "greenhouse effect" that will lead to the global warming. Coal gasification has a proven technology for capturing CO2 at a fraction of the cost required for coal combustion technologies.

  12. Hybrid Combustion-Gasification Chemical Looping

    Energy Technology Data Exchange (ETDEWEB)

    Herbert Andrus; Gregory Burns; John Chiu; Gregory Lijedahl; Peter Stromberg; Paul Thibeault

    2009-01-07

    For the past several years Alstom Power Inc. (Alstom), a leading world-wide power system manufacturer and supplier, has been in the initial stages of developing an entirely new, ultra-clean, low cost, high efficiency power plant for the global power market. This new power plant concept is based on a hybrid combustion-gasification process utilizing high temperature chemical and thermal looping technology The process consists of the oxidation, reduction, carbonation, and calcination of calcium-based compounds, which chemically react with coal, biomass, or opportunity fuels in two chemical loops and one thermal loop. The chemical and thermal looping technology can be alternatively configured as (i) a combustion-based steam power plant with CO{sub 2} capture, (ii) a hybrid combustion-gasification process producing a syngas for gas turbines or fuel cells, or (iii) an integrated hybrid combustion-gasification process producing hydrogen for gas turbines, fuel cells or other hydrogen based applications while also producing a separate stream of CO{sub 2} for use or sequestration. In its most advanced configuration, this new concept offers the promise to become the technology link from today's Rankine cycle steam power plants to tomorrow's advanced energy plants. The objective of this work is to develop and verify the high temperature chemical and thermal looping process concept at a small-scale pilot facility in order to enable AL to design, construct and demonstrate a pre-commercial, prototype version of this advanced system. In support of this objective, Alstom and DOE started a multi-year program, under this contract. Before the contract started, in a preliminary phase (Phase 0) Alstom funded and built the required small-scale pilot facility (Process Development Unit, PDU) at its Power Plant Laboratories in Windsor, Connecticut. Construction was completed in calendar year 2003. The objective for Phase I was to develop the indirect combustion loop with CO{sub 2

  13. Combustion and gasification rates of lignocellulosic chars

    Energy Technology Data Exchange (ETDEWEB)

    Di Blasi, Colomba [Dipartimento di Ingegneria Chimica, Universita degli Studi di Napoli ' Federico II' , P.le V. Tecchio, 80125 Napoli (Italy)

    2009-04-15

    This review critically examines the state of the art of rate laws and kinetic constants for the gasification, with carbon dioxide and steam, and the combustion of chars produced from lignocellulosic fuels, including a brief outline about yields and composition of pyrolysis products. The analysis also gives space to the role played by various factors, such as heating rate, temperature and pressure of the pyrolysis stage, feedstock and content/composition of the inorganic matter, on char reactivity. Finally, directions for future research are suggested. (author)

  14. Nordic seminar on biomass gasification and combustion

    International Nuclear Information System (INIS)

    1993-01-01

    The report comprises a collection of papers from a seminar arranged as a part of the Nordic Energy Research Program. The aim of this program is to strengthen the basic competence in the energy field at universities and research organizations in the Nordic countries. In the program 1991-1994 six areas are selected for cooperation such as energy and society, solid fuels, district heating, petroleum technology, bioenergy and environment, and fuel cells. The topics deal both with biomass combustion and gasification, and combustion of municipal solid waste (MSW) and refuse derived fuel (RDF). A number of 11 papers are prepared. 97 refs., 91 figs., 11 tabs

  15. Nordic seminar on biomass gasification and combustion

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-12-31

    The report comprises a collection of papers from a seminar arranged as a part of the Nordic Energy Research Program. The aim of this program is to strengthen the basic competence in the energy field at universities and research organizations in the Nordic countries. In the program 1991-1994 six areas are selected for cooperation such as energy and society, solid fuels, district heating, petroleum technology, bioenergy and environment, and fuel cells. The topics deal both with biomass combustion and gasification, and combustion of municipal solid waste (MSW) and refuse derived fuel (RDF). A number of 11 papers are prepared. 97 refs., 91 figs., 11 tabs.

  16. Incineration, pyrolysis and gasification of electronic waste

    Directory of Open Access Journals (Sweden)

    Gurgul Agnieszka

    2017-01-01

    Full Text Available Three high temperature processes of the electronic waste processing: smelting/incineration, pyrolysis and gasification were shortly discussed. The most distinctive feature of electronic waste is complexity of components and their integration. This type of waste consists of polymeric materials and has high content of valuable metals that could be recovered. The purpose of thermal treatment of electronic waste is elimination of plastic components (especially epoxy resins while leaving non-volatile mineral and metallic phases in more or less original forms. Additionally, the gaseous product of the process after cleaning may be used for energy recovery or as syngas.

  17. Incineration, pyrolysis and gasification of electronic waste

    Science.gov (United States)

    Gurgul, Agnieszka; Szczepaniak, Włodzimierz; Zabłocka-Malicka, Monika

    2017-11-01

    Three high temperature processes of the electronic waste processing: smelting/incineration, pyrolysis and gasification were shortly discussed. The most distinctive feature of electronic waste is complexity of components and their integration. This type of waste consists of polymeric materials and has high content of valuable metals that could be recovered. The purpose of thermal treatment of electronic waste is elimination of plastic components (especially epoxy resins) while leaving non-volatile mineral and metallic phases in more or less original forms. Additionally, the gaseous product of the process after cleaning may be used for energy recovery or as syngas.

  18. Chemicals Derived from Biomass Thermolysis and Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Schaidle, Joshua A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Talmadge, Michael S [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Biddy, Mary J [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Nimlos, Mark R [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Bratis, Adam D [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-07-14

    The United States has the potential to sustainably produce over 1 billion dry tons of nonfood biomass per year by 2030. While conversion of this biomass into fuels has garnished significant attention, these renewable feedstocks can also be converted into valuable chemicals. Analogous to petroleum refining, the coproduction of fuels and chemicals from biomass enables more complete utilization of the feedstock and supports the growth of a bio-economy by improving biorefinery economics. This chapter provides an overview of biomass thermolysis and gasification technologies, highlights existing and future chemical production opportunities, and elaborates on specific challenges associated with product separation and purification.

  19. Study of the equilibrium of air-blown gasification of biomass to coal evolution fuels

    International Nuclear Information System (INIS)

    Biagini, Enrico

    2016-01-01

    Highlights: • Equilibrium model validated for coals, torrefied/green biomasses, in different gasifiers. • Maps of syngas composition, LHV and CGE for ER = 0–0.6, T = 500–2000 K, EBP = 0.004–0.158. • Effect of unconverted carbon, fuel moisture and overoxidation quantified. • Parameters for the maximum efficiency determined as functions of EBP. • EBP proven to be a good parameter for the quantitative comparison of different fuels. - Abstract: A non-stoichiometric equilibrium model based on the minimization of the Gibbs free energy was used to study the isothermal and adiabatic air-blown gasification of solid fuels on a carbonization curve from fossil (hard/brown coals, peat) to renewable (green biomasses and cellulose) fuels, including torrefied biofuels. The maps of syngas composition, heating value and process efficiency were provided as functions of equivalent ratio (oxygen-to-fuel ratio) in the range 0–0.6, temperature in 500–2000 K, and a fuel parameter, which allowed different cases to be quantitatively compared. The effect of fuel moisture, unconverted carbon and conditions to limit the tar formation was also studied. Cold gas efficiency >0.75 can be achieved for coals at high temperature, using entrained beds (which give low unconverted carbon), and improved by moisture/added steam. The bigger efficiency of green biomasses is only potential, as the practical limits (high temperature required to limit tar formation, moisture content and unconverted carbon in small gasifiers) strongly reduce the gasification performance. Torrefied biomasses (and plastics having an intermediate fuel parameter between coals and green biomasses) can attain high efficiency also in real conditions. The results shown in this work can be useful to evaluate the most promising feedstock (depending on its composition and possible pre-treatment/upgrading), define the operating conditions for maximizing the syngas heating value or the global efficiency, assess the

  20. The role of char and tar in determining the gas-phase partitioning of nitrogen during biomass gasification

    International Nuclear Information System (INIS)

    Broer, Karl M.; Brown, Robert C.

    2015-01-01

    Highlights: • Switchgrass was gasified at an equivalence ratio of zero and 650–850 °C. • Short residence times were employed to minimize secondary reactions. • Char- and tar-bound nitrogen, NH 3 , HCN, and N 2 were all significant products. • Increasing temperature leads to increased release of gaseous nitrogen compounds. • Kinetic models of gasification should include nitrogen release from char and tar. - Abstract: Gasification is an attractive option for converting biomass into fuels and chemicals. Most biomass contains significant amounts of fuel-bound nitrogen (FBN), which partially converts into ammonia (NH 3 ) and hydrogen cyanide (HCN) during gasification. These nitrogen compounds are problematic as they can lead to NO X emissions or catalyst poisoning in downstream applications of syngas. FBN can convert to other products as well, including diatomic nitrogen (N 2 ), char-bound nitrogen (char-N), and tar-bound nitrogen (tar-N). Efforts to predict concentrations of NH 3 and HCN have been hindered by a lack of accurate, comprehensive measurements of nitrogen partitioning among gasification products. The present study gasified switchgrass under allothermal, short residence time conditions and measured NH 3 , HCN, char-N, and tar-N as a function of temperature in the range of 650–850 °C with diatomic nitrogen determined by difference. It was found that a major portion of FBN was retained in the char and tar products. As temperature was increased, char and tar were consumed, releasing nitrogen as gaseous NH 3 and HCN. This increase in undesirable nitrogen compounds is contrary to the predictions of most gasification models, which overlook the presence of significant nitrogen in char and tar even if they include tar cracking and char gasification reactions. The results of this study demonstrate that gas-phase reactions alone are not sufficient to predict the fate of nitrogen during gasification. In order for modeling efforts to obtain more accurate

  1. Reduction of H{sub 2} S during the mineral coal gasification by using dolomite addition in a fluidized bed reactor; Diminuicao de H{sub 2} S na gaseificacao de carvao mineral mediante adicao de dolomita em reator de leito fluidizado

    Energy Technology Data Exchange (ETDEWEB)

    Behanie, John Jairo Ramirez [Universidad Pontificia Bolivariana, Medellin (Colombia). Centro de Investigaciones para el Desarrollo Integral. Grupo de Investigaciones Ambientales]. E-mail: jbehaine@logos.upb.edu.co; Sanches, Caio Glauco [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Engenharia Termica e de Fluidos]. E-mail: caio@fem.unicamp.br

    2000-07-01

    Brazilian mineral coal from Candiota mine (Rio Grande do Sul State) was gasified with air in a atmospheric fluidized bed reactor at laboratory scale. Experimental essays carried out in a 0.2 m internal diameter reactor permitted both, to evaluate the gasifier operation at different air factors without dolomite particles addition, and to study the effect adsorbent on the capture hydrogen sulfide (H2 S), contained in the generated gas. Test were done with and without the use of dolomite. Without using dolomite, the maximum gas lower heating value was 2.2 MJ/N m3 and the cold gas thermal efficiency was close to 43%, operating at an air factor between 0.45 and 0.60. During the experimental test with dolomite , a maximum reduction of 58% for H2 S was attained using a molar ratio of Ca/S equal to 4. Literature review showed higher capture efficiencies, even at lower molar ratio (Ca/S). Variances were probably caused by low residence times in the gas-solid interaction, considering the used bubble fluidization regime. (author)

  2. Kinetics of Pyrolysis and Gasification Using Thermogravimetric and Thermovolumetric Analyses

    Directory of Open Access Journals (Sweden)

    Czerski Grzegorz

    2016-03-01

    Full Text Available The carbon dioxide gasification process of Miscanthus giganteus biomass was examined using two methods. First an isothermal thermovolumetric method was applied. The measurement was conducted at 950°C and pressure of 0.1 MPa. Based on the continuous analysis of different kinds of gases formed during the gasification process, the thermovolumetric method allowed the determination of yields and composition of the resulting gas as well as the rate constant of CO formation. Then a non-isothermal thermogravimetric method was applied, during which the loss of weight of a sample as a function of temperature was recorded. In the course of the measurement, the temperature was raised from ambient to 950°C and the pressure was 0.1 MPa. As a result, a change in the carbon conversion degree was obtained. Moreover, TGA methods allow distinguishing various stages of the gasification process such as primary pyrolysis, secondary pyrolysis and gasification, and determining kinetic parameters for each stage. The presented methods differs from each other as they are based either on the analysis of changes in the resulting product or on the analysis of changes in the supplied feedstock, but both can be successfully used to the effective examination of kinetics of the gasification process. In addition, an important advantage of both methods is the possibility to carry out the gasification process for different solid fuels as coal, biomass, or solid waste in the atmosphere of a variety of gasification agents.

  3. From coal to biomass gasification: Comparison of thermodynamic efficiency

    International Nuclear Information System (INIS)

    Prins, Mark J.; Ptasinski, Krzysztof J.; Janssen, Frans J.J.G.

    2007-01-01

    The effect of fuel composition on the thermodynamic efficiency of gasifiers and gasification systems is studied. A chemical equilibrium model is used to describe the gasifier. It is shown that the equilibrium model presents the highest gasification efficiency that can be possibly attained for a given fuel. Gasification of fuels with varying composition of organic matter, in terms of O/C and H/C ratio as illustrated in a Van Krevelen diagram, is compared. It was found that exergy losses in gasifying wood (O/C ratio around 0.6) are larger than those for coal (O/C ratio around 0.2). At a gasification temperature of 927 deg. C, a fuel with O/C ratio below 0.4 is recommended, which corresponds to a lower heating value above 23 MJ/kg. For gasification at 1227 deg. C, a fuel with O/C ratio below 0.3 and lower heating value above 26 MJ/kg is preferred. It could thus be attractive to modify the properties of highly oxygenated biofuels prior to gasification, e.g. by separation of wood into its components and gasification of the lignin component, thermal pre-treatment, and/or mixing with coal in order to enhance the heating value of the gasifier fuel

  4. Gasification of various types of tertiary coals: A sustainability approach

    International Nuclear Information System (INIS)

    Öztürk, Murat; Özek, Nuri; Yüksel, Yunus Emre

    2012-01-01

    Highlights: ► Production energy by burning of coals including high rate of ash and sulfur is harmful to environment. ► Energy production via coal gasification instead of burning is proposed for sustainable approach. ► We calculate exergy and environmental destruction factor of gasification of some tertiary coals. ► Sustainability index, improvement potential of gasification are evaluated for exergy-based approach. - Abstract: The utilization of coal to produce a syngas via gasification processes is becoming a sustainability option because of the availability and the economic relevance of this fossil source in the present world energy scenario. Reserves of coal are abundant and more geographically spread over the world than crude oil and natural gas. This paper focuses on sustainability of the process of coal gasification; where the synthesis gas may subsequently be used for the production of electricity, fuels and chemicals. The coal gasifier unit is one of the least efficient step in the whole coal gasification process and sustainability analysis of the coal gasifier alone can substantially contribute to the efficiency improvement of this process. In order to evaluate sustainability of the coal gasification process energy efficiency, exergy based efficiency, exergy destruction factor, environmental destruction factor, sustainability index and improvement potential are proposed in this paper.

  5. Wabash River coal gasification repowering project: Public design report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    The Wabash River Coal Gasification Repowering Project (the Project), conceived in October of 1990 and selected by the US Department of Energy as a Clean Coal IV demonstration project in September 1991, is expected to begin commercial operations in August of 1995. The Participants, Destec Energy, Inc., (Destec) of Houston, Texas and PSI Energy, Inc., (PSI) of Plainfield, Indiana, formed the Wabash River Coal Gasification Repowering Project Joint Venture (the JV) to participate in the DOE`s Clean Coal Technology (CCT) program by demonstrating the coal gasification repowering of an existing 1950`s vintage generating unit affected by the Clean Air Act Amendments (CAAA). The Participants, acting through the JV, signed the Cooperative Agreement with the DOE in July 1992. The Participants jointly developed, and separately designed, constructed, own, and will operate an integrated coal gasification combined cycle (CGCC) power plant using Destec`s coal gasification technology to repower Unit {number_sign}1 at PSI`s Wabash River Generating Station located in Terre Haute, Indiana. PSI is responsible for the new power generation facilities and modification of the existing unit, while Destec is responsible for the coal gasification plant. The Project demonstrates integration of the pre-existing steam turbine generator, auxiliaries, and coal handling facilities with a new combustion turbine generator/heat recovery steam generator tandem and the coal gasification facilities.

  6. Development of a pressurized fluidized-bed biomass gsifier to produce substitute fuels

    Science.gov (United States)

    Babu, S. P.; Onischak, M.; Kosowski, G.

    The Institute of Gas technology (IGT) is conducting a program to convert forest and crop residues to substitute fuel in a pressurized fluidized-bed biomass gasifier. The process is designed for operation at pressures up to 2.17 MPa (315 psia) and temperatures up to 1255 K (1800 F). Various goals for synthesis or fuel gas processes are being pursued to develop an efficient process. Some of these goals are to maximize the throughput, the amount, and the quality of the gas, while minimizing both the amount of the feedstock preparation needed and the formation of condensible compounds that require by-product disposal and process wastewater treatment. The process development results obtained from fluidization biomass devolatilization, and char gasification studies were used to design a 30/5-cm (12-inch) ID adiabatic fluidized-bed gasification process development unit (PDU), capable of handling up to 455 kg (1000 lb) of biomass per hour.

  7. Power Systems Development Facility Gasification Test Run TC08

    Energy Technology Data Exchange (ETDEWEB)

    Southern Company Services

    2002-06-30

    This report discusses Test Campaign TC08 of the Kellogg Brown & Root, Inc. (KBR) Transport Gasifier train with a Siemens Westinghouse Power Corporation (Siemens Westinghouse) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Gasifier is an advanced circulating fluidized-bed gasifier designed to operate as either a combustor or a gasifier in air- or oxygen-blown mode using a particulate control device (PCD). The Transport Gasifier was operated as a pressurized gasifier in air- and oxygen-blown modes during TC08. Test Run TC08 was started on June 9, 2002 and completed on June 29. Both gasifier and PCD operations were stable during the test run with a stable baseline pressure drop. The oxygen feed supply system worked well and the transition from air to oxygen blown was smooth. The gasifier temperature was varied between 1,710 and 1,770 F at pressures from 125 to 240 psig. The gasifier operates at lower pressure during oxygen-blown mode due to the supply pressure of the oxygen system. In TC08, 476 hours of solid circulation and 364 hours of coal feed were attained with 153 hours of pure oxygen feed. The gasifier and PCD operations were stable in both enriched air and 100 percent oxygen blown modes. The oxygen concentration was slowly increased during the first transition to full oxygen-blown operations. Subsequent transitions from air to oxygen blown could be completed in less than 15 minutes. Oxygen-blown operations produced the highest synthesis gas heating value to date, with a projected synthesis gas heating value averaging 175 Btu/scf. Carbon conversions averaged 93 percent, slightly lower than carbon conversions achieved during air-blown gasification.

  8. DOE Coal Gasification Multi-Test Facility: fossil fuel processing technical/professional services

    Energy Technology Data Exchange (ETDEWEB)

    Hefferan, J.K.; Lee, G.Y.; Boesch, L.P.; James, R.B.; Rode, R.R.; Walters, A.B.

    1979-07-13

    A conceptual design, including process descriptions, heat and material balances, process flow diagrams, utility requirements, schedule, capital and operating cost estimate, and alternative design considerations, is presented for the DOE Coal Gasification Multi-Test Facility (GMTF). The GMTF, an engineering scale facility, is to provide a complete plant into which different types of gasifiers and conversion/synthesis equipment can be readily integrated for testing in an operational environment at relatively low cost. The design allows for operation of several gasifiers simultaneously at a total coal throughput of 2500 tons/day; individual gasifiers operate at up to 1200 tons/day and 600 psig using air or oxygen. Ten different test gasifiers can be in place at the facility, but only three can be operated at one time. The GMTF can produce a spectrum of saleable products, including low Btu, synthesis and pipeline gases, hydrogen (for fuel cells or hydrogasification), methanol, gasoline, diesel and fuel oils, organic chemicals, and electrical power (potentially). In 1979 dollars, the base facility requires a $288 million capital investment for common-use units, $193 million for four gasification units and four synthesis units, and $305 million for six years of operation. Critical reviews of detailed vendor designs are appended for a methanol synthesis unit, three entrained flow gasifiers, a fluidized bed gasifier, and a hydrogasifier/slag-bath gasifier.

  9. Design and operation of a CFB gasification and power generation system for rice husk

    Energy Technology Data Exchange (ETDEWEB)

    Xiu Li Yin; Chuang Zhi Wu; Shun Peng Zheng; Yong Chen [Chinese Academy of Sciences, Guangzhou (China). Guangzhou Institute of Energy Conversion

    2002-09-01

    A circulating fluidized bed (CFB) biomass gasification and power generation system (BGPG) for rice husk was designed and installed to provide power for a rice mill with a capacity of 150 td{sup -1}. The project has been operating in Putian Huaguang Miye Ltd., located in Fujian Province of China since August 1998. The system consists of a CFB gasifier, a gas cleaner (including an inertial separator, a cyclone separator, a venturi and two water scrubbers), and power generation subsystem (containing five parallel gas engines rated 200 kW each), in addition to a wastewater treatment system. It is found that the system can be operated stably within the temperature from 700{sup o}C to 850{sup o}C, and its optimal condition was reached when the workload is increased above 800 kW. The main performance indices are: capacity: 1500 kgh{sup -1}, gasification efficiency: 65%, rice husk consumption: 1.7-1.9 kgkWh-1, total efficiency: about 17%. The reliability of the BGPG system has been proven through two years of operation (about 10,000 h). The total investment is 510000 US dollars, the unit investment is 370 US dollars kW{sup -1}, the operation cost is 0.032 US dollars kW{sup -1}, and the payback period is not more than two years. (author)

  10. Biomass-Ash-Induced Agglomeration in a Fluidized Bed. Part 1: Experimental Study on the Effects of a Gas Atmosphere

    DEFF Research Database (Denmark)

    Ma, Teng; Fan, Chuigang; Hao, Lifang

    2016-01-01

    Fluidized beds have been widely applied to gasification and combustion of biomass. During gasification, a high temperature is preferable to increase the carbon conversion and to reduce the undesirable tar. However, the high temperature may lead to a severe agglomeration problem in a fluidized bed....... Understanding of the agglomeration in various atmospheres is crucial to optimize the design and operation conditions. This study focuses on the effects of gases on agglomeration tendency with different types of biomass, including corn straw, rice straw, and wheat straw. The biomass ash samples are mixed...... with quartz sand and fluidized by the gas mixtures of N2/CO2, N2/H2, and N2/steam or by air. At 550 °C, the bed temperature is increased at the rate of 3 °C/min until defluidization occurs. In this way, the defluidization temperature can be determined, which represents the agglomeration tendency...

  11. High temperature steam gasification of solid wastes: Characteristics and kinetics

    Science.gov (United States)

    Gomaa, Islam Ahmed

    Greater use of renewable energy sources is of pinnacle importance especially with the limited reserves of fossil fuels. It is expected that future energy use will have increased utilization of different energy sources, including biomass, municipal solid wastes, industrial wastes, agricultural wastes and other low grade fuels. Gasification is a good practical solution to solve the growing problem of landfills, with simultaneous energy extraction and nonleachable minimum residue. Gasification also provides good solution to the problem of plastics and rubber in to useful fuel. The characteristics and kinetics of syngas evolution from the gasification of different samples is examined here. The characteristics of syngas based on its quality, distribution of chemical species, carbon conversion efficiency, thermal efficiency and hydrogen concentration has been examined. Modeling the kinetics of syngas evolution from the process is also examined. Models are compared with the experimental results. Experimental results on the gasification and pyrolysis of several solid wastes, such as, biomass, plastics and mixture of char based and plastic fuels have been provided. Differences and similarities in the behavior of char based fuel and a plastic sample has been discussed. Global reaction mechanisms of char based fuel as well polystyrene gasification are presented based on the characteristic of syngas evolution. The mixture of polyethylene and woodchips gasification provided superior results in terms of syngas yield, hydrogen yield, total hydrocarbons yield, energy yield and apparent thermal efficiency from polyethylene-woodchips blends as compared to expected weighed average yields from gasification of the individual components. A possible interaction mechanism has been established to explain the synergetic effect of co-gasification of woodchips and polyethylene. Kinetics of char gasification is presented with special consideration of sample temperature, catalytic effect of ash

  12. Methane rich gasification of wood pellets

    Directory of Open Access Journals (Sweden)

    Joka Magdalena

    2016-01-01

    Full Text Available In the work there are shown the results of experimental studies on methane rich gasification of pinewood pellets in Bio-CONOx technology. The experiment was carried out on a laboratory scale gasifier (5 kW, which design features allow producing a high quality gas with a high methane content. In the results there was identified the impact of the quantity of Bio-CONOx on the amount of flammable gas compounds (methane, hydrogen and carbon monoxide in the synthesis gas and the gas calorific value. The additive was added in 10,20,30 and 50% concentrations to the gasifier chamber. It has been shown that increasing the amount of the additive has a positive effect on the calorific value of the synthesis gas (Fig.1,2. Gas with a high content of methane (and high calorific value was obtained from gasification of biomass with a 50% addition of Bio-CONOx. There was also examined the proportion of blowing air (gasifying medium for which the properties of obtained syngas were the best.

  13. Tenth annual underground coal gasification symposium: proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Burwell, E.; Docktor, L.; Martin, J.W. (eds.)

    1984-12-01

    The Tenth Annual Underground Coal Gasification Symposium was cosponsored by the Fossil Energy Division of the US Department of Energy and the Morgantown Energy Technology Center's Laramie Projects Office. The purpose of the symposium was to provide a forum for presenting research results and for determining additional research needs in underground coal gasification. This years' meeting was held in Williamsburg, Virginia, during the week of August 12 through 15, 1984. Approximately 120 attendees representing industry, academia, national laboratories, Government, and eight foreign countries participated in the exchange of ideas, results, and future research plans. International representatives included participants from Belgium, Brazil, France, the Netherlands, New Zealand, Spain, West Germany, and Yugoslavia. During the three-day symposium, sixty papers were presented and discussed in four formal presentation sessions and two informal poster sessions. The papers describe interpretation of field test data, results of environmental research, and evaluations of laboratory, modeling, and economic studies. All papers in this Proceedings have been processed for inclusion in the Energy Data Base.

  14. Investigations on catalyzed steam gasification of biomass

    Energy Technology Data Exchange (ETDEWEB)

    Mudge, L.K.; Weber, S.L.; Mitchell, D.H.; Sealock, L.J. Jr.; Robertus, R.J.

    1981-01-01

    The purpose of the study is to evaluate the technical and economic feasibility of producing specific gas products via the catalytic gasification of biomass. This report presents the results of research conducted from December 1977 to October 1980. The study was comprised of laboratory studies, process development, and economic analyses. The laboratory studies were conducted to develop operating conditions and catalyst systems for generating methane-rich gas, synthesis gases, hydrogen, and carbon monoxide; these studies also developed techniques for catalyst recovery, regeneration, and recycling. A process development unit (PDU) was designed and constructed to evaluate laboratory systems at conditions approximating commercial operations. The economic analyses, performed by Davy McKee, Inc. for PNL, evaluated the feasibility of adapting the wood-to-methane and wood-to-methanol processes to full-scale commercial operations. Plants were designed in the economic analyses to produce fuel-grade methanol from wood and substitute natural gas (SNG) from wood via catalytic gasification with steam.

  15. GASIFICATION PLANT COST AND PERFORMANCE OPTIMIZATION

    Energy Technology Data Exchange (ETDEWEB)

    Samuel S. Tam

    2002-05-01

    The goal of this series of design and estimating efforts was to start from the as-built design and actual operating data from the DOE sponsored Wabash River Coal Gasification Repowering Project and to develop optimized designs for several coal and petroleum coke IGCC power and coproduction projects. First, the team developed a design for a grass-roots plant equivalent to the Wabash River Coal Gasification Repowering Project to provide a starting point and a detailed mid-year 2000 cost estimate based on the actual as-built plant design and subsequent modifications (Subtask 1.1). This unoptimized plant has a thermal efficiency of 38.3% (HHV) and a mid-year 2000 EPC cost of 1,681 $/kW. This design was enlarged and modified to become a Petroleum Coke IGCC Coproduction Plant (Subtask 1.2) that produces hydrogen, industrial grade steam, and fuel gas for an adjacent Gulf Coast petroleum refinery in addition to export power. A structured Value Improving Practices (VIP) approach was applied to reduce costs and improve performance. The base case (Subtask 1.3) Optimized Petroleum Coke IGCC Coproduction Plant increased the power output by 16% and reduced the plant cost by 23%. The study looked at several options for gasifier sparing to enhance availability. Subtask 1.9 produced a detailed report on this availability analyses study. The Subtask 1.3 Next Plant, which retains the preferred spare gasification train approach, only reduced the cost by about 21%, but it has the highest availability (94.6%) and produces power at 30 $/MW-hr (at a 12% ROI). Thus, such a coke-fueled IGCC coproduction plant could fill a near term niche market. In all cases, the emissions performance of these plants is superior to the Wabash River project. Subtasks 1.5A and B developed designs for single-train coal and coke-fueled power plants. This side-by-side comparison of these plants, which contain the Subtask 1.3 VIP enhancements, showed their similarity both in design and cost (1,318 $/kW for the

  16. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Michael L. Swanson

    2005-08-30

    50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

  17. Refuse Derived Fuel (RDF) production and gasification in a pilot plant integrated with an Otto cycle ICE through Aspen plus™ modelling: Thermodynamic and economic viability.

    Science.gov (United States)

    Násner, Albany Milena Lozano; Lora, Electo Eduardo Silva; Palacio, José Carlos Escobar; Rocha, Mateus Henrique; Restrepo, Julian Camilo; Venturini, Osvaldo José; Ratner, Albert

    2017-11-01

    This work deals with the development of a Refuse Derived Fuel (RDF) gasification pilot plant using air as a gasification agent. A downdraft fixed bed reactor is integrated with an Otto cycle Internal Combustion Engine (ICE). Modelling was carried out using the Aspen Plus™ software to predict the ideal operational conditions for maximum efficiency. Thermodynamics package used in the simulation comprised the Non-Random Two-Liquid (NRTL) model and the Hayden-O'Connell (HOC) equation of state. As expected, the results indicated that the Equivalence Ratio (ER) has a direct influence over the gasification temperature and the composition of the Raw Produced Gas (RPG), and effects of ER over the Lower Heating Value (LHV) and Cold Gasification Efficiency (CGE) of the RPG are also discussed. A maximum CGE efficiency of 57-60% was reached for ER values between 0.25 and 0.3, also an average reactor temperature values in the range of 680-700°C, with a peak LHV of 5.8MJ/Nm 3 . RPG was burned in an ICE, reaching an electrical power of 50kW el . The economic assessment of the pilot plant implementation was also performed, showing the project is feasible, with power above 120kW el with an initial investment of approximately US$ 300,000. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Pilot scale testing of biomass feedstocks for use in gasification/gas turbine based power generation systems

    Energy Technology Data Exchange (ETDEWEB)

    Najewicz, D.J.; Furman, A.H. [General Electric Corporate Research and Development Center, Schenectady, NY (United States)

    1993-12-31

    A biomass gasification pilot program was performed at the GE Corporate Research and Development Center using two types of biomass feedstock. The object of the testing was to determine the properties of biomass product gas and its` suitability as a fuel for gas turbine based power generation cycles. The test program was sponsored by the State of Vermont, the US Environmental Protection Agency, the US Department of Energy and Winrock International/US Agency for International Development. Gasification of bagasse and wood chip feedstock was performed at a feed rate of approximately one ton per hour, using the Ge pressurized fixed bed gasifier and a single stage of cyclone particulate removal, operating at a temperature of 1,000 F. Both biomass feedstocks were found to gasify easily, and gasification capacity was limited by volumetric capacity of the fuel feed equipment. The biomass product gas was analyzed for chemical composition, particulate loading, fuel bound nitrogen levels, sulfur and alkali metal content. The results of the testing indicated the combustion characteristics of the biomass product gas are compatible with gas turbine combustor requirements. However, the particulate removal performance of the pilot facility single stage cyclone was found to be inadequate to meet turbine particulate contamination specifications. In addition, alkali metals found in biomass based fuels, which are known to cause corrosion of high temperature gas turbine components, were found to exceed allowable levels in the fuel gas. These alkali metal compounds are found in the particulate matter (at 1000 F) carried over from the gasifier, thus improved particulate removal technology, designed specifically for biomass particulate characteristics could meet the turbine requirements for both particulate and alkali loading. The paper will present the results of the biomass gasification testing and discuss the development needs in the area of gas clean-up and turbine combustion.

  19. Evaluation of advanced coal gasification combined-cycle systems under uncertainty

    International Nuclear Information System (INIS)

    Frey, H.C.; Rubin, E.S.

    1992-01-01

    Advanced integrated gasification combined cycle (IGCC) systems have not been commercially demonstrated, and uncertainties remain regarding their commercial-scale performance and cost. Therefore, a probabilistic evaluation method has been developed and applied to explicitly consider these uncertainties. The insights afforded by this method are illustrated for an IGCC design featuring a fixed-bed gasifier and a hot gas cleanup system. Detailed case studies are conducted to characterize uncertainties in key measures of process performance and cost, evaluate design trade-offs under uncertainty, identify research priorities, evaluate the potential benefits of additional research, compare results for different uncertainty assumptions, and compare the advanced IGCC system to a conventional system under uncertainty. The implications of probabilistic results for research planning and technology selection are discussed in this paper

  20. Performance of different dolomites on hot raw gas cleaning from biomass gasification with air

    Energy Technology Data Exchange (ETDEWEB)

    Orio, A.; Corella, J.; Narvaez, I. [Univ. Complutense, Madrid (Spain). Dept. of Chemical Engineering

    1997-09-01

    Calcined dolomites (CaO-MgO) from four different quarries have been tested for the upgrading of the hot raw gas from a fluidized bed gasifier of biomass with air. These calcined dolomites have big macropores (900--4,000 {angstrom}) and low (3.8--12 m{sup 2}/g) BET surface areas. They have been tested in a fixed bed of 6 cm i.d. downstream from the air-blown biomass gasifier. The change in gas composition (contents in H{sub 2}, CO, CO{sub 2}, CH{sub 4}, {hor_ellipsis}), tar content, gas heating value, etc., has been studied in different temperatures (780--920 C) as well as space-times for the gas in the bed (0.03--0.10 kg{center_dot}h/m{sup 3}) and the type of dolomite. Increasing the equivalence ratio used in the gasifier and decreasing the H/C ratio of the gas increases the refractoriness of the tars to be eliminated by the calcined dolomite. Activation energies (100 {+-} 20 kJ/mol) and preexponential factors for the overall tar elimination reaction have been calculated for the different dolomites under realistic conditions. The activity of the dolomite for tar elimination can increase by 20% on increasing its pore diameter or its Fe{sub 2}O{sub 3} content. Comparison of results with similar ones obtained in biomass gasification with steam is also presented.