WorldWideScience

Sample records for bay potb methane

  1. Port of Tillamook Bay (POTB); Methane Energy Agriculture Development (MEAD); Dairy Digester Project

    Energy Technology Data Exchange (ETDEWEB)

    Jack Crider

    2004-12-31

    The Tillamook Digester is a fully operational demonstration project that will identify the components necessary to bring the concept to a financially viable alternative for handling waste manure from dairy operations in Tillamook County.

  2. Formation of methane fields in the Golubaya bay of the Black Sea

    Science.gov (United States)

    Kovaleva, Elena

    2014-05-01

    Study of formation of methane fields in water environments is essential for search of oil and gas in bottom sediments of the aquatories [Egorov et al., 2008]. Methane acts as a tracer of various biogeochemical processes in freshwater and marine waters as well. Moreover, in recent years estimation of methane emission is one of tasks of current climate research because of high contribution of methane in the greenhouse effect [Bazhin, 2000]. The Black Sea is the largest methane reservoir in the world [Lein, Ivanov, 2005]. The Golubaya Bay of the Black Sea acts as a peculiar model of formation and variability of methane fields in the marine environment. The main purpose of our study is to identify factors that influence the high methane saturation in the aerobic coastal waters. Data collection took place in the Golubaya and the Gelendzhikskaya bays and in the Ashamba River since 1999 to 2013. Water samples were analyzed by the head-space method with further gas chromatographic determination of methane concentrations [Bolshakov, Egorov, 1987]. Methane saturation in the Golubaya Bay waters exceeds the equilibrium with the atmosphere value 10-100 times. According to the simultaneous measurements of methane in two bays in different seasons, methane saturation in the Golubaya Bay is higher than in the Gelendzhikskaya Bay. The smaller bottom depth and accordingly the larger biological productivity in the Golubaya Bay may be the reason of it. Microbial production of methane in aerobic waters of the bay is associated with zone of zooplankton concentration and products of its vital activity [Lein, Ivanov, 2009]. It is known that formation of methane is intense in periodically flooded soils where anaerobic conditions are formed. That causes development of methanogenic bacteria [Alekseev et al., 1978]. Distribution of methane in marine and river waters illustrates that the river runoff and groundwater supply are some of the sources of high methane saturation in the Golubaya Bay

  3. Distribution of methane in the Lena Delta and Buor Khaya Bay, Russia

    Directory of Open Access Journals (Sweden)

    I. Bussmann

    2012-11-01

    Full Text Available The Lena River is one of the largest Russian rivers draining into the Laptev Sea. The permafrost areas surrounding the Lena are predicted to melt at increasing rates due to global temperature increases. With this melting, large amounts of carbon – either organic or as methane – will reach the waters of the Lena and the adjacent Buor Khaya Bay (Laptev Sea.

    Methane concentrations and the isotopic signal of methane in the waters of the Lena Delta and estuary were monitored from 2008 to 2010. Meltwater run-off of permafrost soils produced hotspots for methane input into the river system (median concentration 1500 nM compared with concentrations of around 100 nM observed in the main channels of the Lena. Within the river, especially at sites with meltwater input, microbiological experiments indicated strong in situ methane production but a very low methane oxidation potential. In the estuary of Buor Khaya Bay, methane concentrations decreased towards background levels of 20 nM. Here, the strong stratification of the water column permits the dilution of methane with seawater, and methane is released mainly by diffusion into the atmosphere.

  4. Carbon cycling fed by methane seepage at the shallow Cumberland Bay, South Georgia, sub-Antarctic

    Science.gov (United States)

    Geprägs, Patrizia; Torres, Marta E.; Mau, Susan; Kasten, Sabine; Römer, Miriam; Bohrmann, Gerhard

    2016-04-01

    Recent studies have suggested that the marine contribution of methane from shallow regions and melting marine-terminating glaciers may have been underestimated. Here we report on methane sources and potential sinks associated with methane seeps in Cumberland Bay, South Georgia's largest fjord system. The average organic carbon content in the upper 8 m of the sediment is around 0.65 wt %; this observation combined with Parasound data suggest that the methane gas accumulations probably originate from peat-bearing sediments currently located several tens of meters below the seafloor. Only one of our cores indicates upward advection; instead most of the methane is transported via diffusion. Sulfate and methane flux estimates indicate that a large fraction of methane is consumed by anaerobic oxidation of methane (AOM). Carbon cycling at the sulfate-methane transition (SMT) results in a marked fractionation of the δ13C-CH4 from an estimated source value of -65‰ to a value as low as -96‰ just below the SMT. Methane concentrations in sediments are high, especially close to the seepage sites (˜40 mM); however, concentrations in the water column are relatively low (max. 58 nM) and can be observed only close to the seafloor. Methane is trapped in the lowermost water mass; however, measured microbial oxidation rates reveal very low activity with an average turnover of 3.1 years. We therefore infer that methane must be transported out of the bay in the bottom water layer. A mean sea-air flux of only 0.005 nM/m2 s confirms that almost no methane reaches the atmosphere.

  5. Environmental control on anaerobic oxidation of methane in the gassy sediments of Eckernforde Bay (German Baltic)

    DEFF Research Database (Denmark)

    Treude, T.; Kruger, M.; Boetius, A.;

    2005-01-01

    AOM in Eckerntorde Bay. These archaea are known also from other marine methane-rich locations. However, they were not directly associated with sulfate-reducing bacteria. AOM is possibly mediated solely by these archaea that show a mesophilic physiology according to the seasonal temperature changes...

  6. Controls on subsurface methane fluxes and shallow gas formation in Baltic Sea sediment (Aarhus Bay, Denmark)

    Science.gov (United States)

    Flury, Sabine; Røy, Hans; Dale, Andrew W.; Fossing, Henrik; Tóth, Zsuzsanna; Spiess, Volkhard; Jensen, Jørn Bo; Jørgensen, Bo Barker

    2016-09-01

    Shallow gas accumulates in coastal marine sediments when the burial rate of reactive organic matter beneath the sulfate zone is sufficiently high and the methanogenic zone is sufficiently deep. We investigated the controls on methane production and free methane gas accumulation along a 400 m seismo-acoustic transect across a sharp transition from gas-free into gas-bearing sediment in Aarhus Bay (Denmark). Twelve gravity cores were taken, in which the pore water was analyzed for inorganic solutes while rates of organic carbon mineralization were measured experimentally by 35SO42- radiotracer method. The thickness of organic-rich Holocene mud increased from 5 to 10 m along the transect concomitant with a shallowing of the depth of the sulfate-methane transition from >4 m to 2.5 m. In spite of drastic differences in the distribution of methane and sulfate in the sediment along the transect, there were only small differences in total mineralization, and methanogenesis was only equivalent to about 1% of sulfate reduction. Shallow gas appeared where the mud thickness exceeded 8-9 m. Rates of methanogenesis increased along the transect as did the upward diffusive flux of methane. Interestingly, the increase in the sedimentation rate and Holocene mud thickness had only a modest direct effect on methanogenesis rates in deep sediments. This increase in methane flux, however, triggered a shallowing of the sulfate-methane transition which resulted in a large increase in methanogenesis at the top of the methanogenic zone. Thus, our results demonstrate a positive feedback mechanism that causes a strong enhancement of methanogenesis and explains the apparently abrupt appearance of gas when a threshold thickness of organic-rich mud is exceeded.

  7. Short-term variations of methane concentrations and methanotrophic activity in a coastal inlet (Eckernförde Bay, Germany)

    Science.gov (United States)

    Niemann, Helge; Richner, Dominik; Steinle, Lea; Schneider von Deimling, Jens; Urban, Peter; Hoffmann, Jasper; Schmidt, Mark; Treude, Tina; Lehmann, Moritz F.

    2015-04-01

    Large quantities of the greenhouse gas methane are produced in anoxic sediments of continental margins and may be liberated into the overlying water column and, potentially, into the atmosphere where it further contributes to global warming. However, a sequence of microbially mediated methane oxidation pathways in sediments and the water column mitigate the contribution of oceans to the atmospheric methane budget. In anoxic sediments, specialised archaea oxidise methane with sulphate in a process that has been termed the anaerobic oxidation of methane (AOM). In addition, aerobic bacteria at the sediment surface and the water column have the potential to consume methane (aerobic oxidation of methane; MOx) that has by passed the benthic, microbial filter. However methane cycling in (aerobic) marine waters is not well constrained. Particularly little is known about spatiotemporal aspects of MOx activity and the underlying key physical, chemical and biological factors. Here we show results from our investigations on methane dynamics on very short time scales of hours to days in the Eckernförde Bay (E-Bay), a costal inlet of the Baltic Sea in northern Germany featuring seasonal bottom water hypoxia/anoxia. In autumn 2014, we observed high spatiotemporal variations in water column methane contents and MOx activity: Anoxic bottom waters in a trough in the northern part of the bay contained extremely high methane concentrations of up to 800 nM, which sharply declined at the midwater redox interface (though methane remained supersaturated with respect to the atmospheric equilibrium throughout the water column at all times). The methane decrease at the redox interface was related to highly active MOx communities consuming methane under microoxic conditions at rates of up 40 nM/d. About 12 hours later, the methane content and the extent of bottom water anoxia was much lower and MOx activity was highly reduced in the northern part but strongly elevated in the southern part of

  8. Magnitude and seasonality of wetland methane emissions from the Hudson Bay Lowlands (Canada

    Directory of Open Access Journals (Sweden)

    C. A. Pickett-Heaps

    2011-04-01

    Full Text Available The Hudson Bay Lowlands (HBL is the second largest boreal wetland ecosystem in the world and an important natural source of global atmospheric methane. We quantify the HBL methane emissions by using the GEOS-Chem chemical transport model to simulate aircraft measurements over the HBL from the ARCTAS and pre-HIPPO campaigns in May–July 2008, together with continuous 2004–2008 surface observations at Fraserdale (southern edge of HBL and Alert (Arctic background. The difference in methane concentrations between Fraserdale and Alert is shown to be a good indicator of HBL emissions, and implies a sharp seasonal onset of emissions in late May (consistent with the aircraft data, a peak in July–August, and a seasonal shut-off in September. The model, in which seasonal variation of emission is mainly driven by surface temperature, reproduces well the observations in summer but its seasonal shoulders are too broad. We suggest that this reflects the suppression of emissions by snow cover and greatly improve the model simulation by accounting for this effect. Our resulting best estimate for HBL methane emissions is 2.3 Tg a−1, several-fold higher than previous estimates (Roulet et al., 1994; Worthy et al., 2000.

  9. Magnitude and seasonality of wetland methane emissions from the Hudson Bay Lowlands (Canada

    Directory of Open Access Journals (Sweden)

    C. A. Pickett-Heaps

    2010-09-01

    Full Text Available The Hudson Bay Lowlands (HBL is the second largest boreal wetland ecosystem in the world and an important natural source of global atmospheric methane. We quantify the HBL methane emissions by using the GEOS-Chem chemical transport model to simulate aircraft measurements over the HBL from the ARCTAS and pre-HIPPO campaigns in May–July 2008, together with continuous 2004–2008 surface observations at Fraserdale (southern edge of HBL and Alert (Arctic background. The difference in methane concentrations between Fraserdale and Alert is shown to be a good indicator of HBL emissions, and implies a sharp seasonal onset of emissions in June (consistent with the aircraft data and seasonal shut-off in September. The model, in which seasonal variation of emission is mainly driven by surface temperature, reproduces well the observations in summer but its seasonal shoulders are too broad. We suggest that this reflects the suppression of emissions by snow cover, and greatly improves the model simulation by accounting for this effect. Our resulting best estimate for HBL methane emissions is 2.3 Tg a−1, several-fold higher than previous estimates.

  10. Methane formation and consumption processes in Xiangxi Bay of the Three Gorges Reservoir

    Science.gov (United States)

    Wang, Chenghao; Xiao, Shangbin; Li, Yingchen; Zhong, Huayao; Li, Xuechen; Peng, Feng

    2014-03-01

    Indoor simulation experiment was carried out to evaluate the formation and consumption rates of methane (CH4) in Xiangxi Bay of the Three Gorges Reservoir (TGR), China. The results show that both the CH4 formation and consumption rates were significantly positively correlated with temperature. CH4 efflux decreased with rising temperature due to its potential increasing oxidation rate. CH4 oxidation in surface sediments accounted for 51.8% of the total production and it even reached to 77.4% at 35°C. The methane oxidation rate in water column ranged from 1.26 to 4.65 mg/(m2h), of which the average and greatest rate accounted for 46.7% and 73.9% of CH4 production respectively under the condition of 30 m water column and 35°C. The methane oxidation may increase by 41.04 mg/(m2h) under average water level of TGR (160 m), and most methane resulted from sediments can be oxidized in the water column.

  11. Methane Derived Authigenic Carbonates from the Upper Continental Margin of the Bay of Biscay (France)

    Science.gov (United States)

    Pierre, C.; Blanc-Valleron, M. M.; Dupré, S.

    2014-12-01

    Extensive seafloor carbonate pavements are present at water depth from 140 to 180 meters on the upper continental margin of the Bay of Biscay, 50 to 60 km away from the present-day coastline. They form at the seafloor meter-high sub-circular reliefs with a diameter from 10 m to 100 m that are surrounded by light brown silto-sandy unconsolidated sediments. All these structures are associated with active methane seeps that cover an area of 80km from N to S and up to 8km from W to E. These carbonates were sampled during the two cruises GAZCOGNE 1 (july-august 2013) and GAZCOGNE 2 (september 2013). The carbonate crusts are porous sandstones, dark brown to black by impregnation with Fe-Mn oxides/hydroxides. Subseafloor concretions are homogenous light to medium grey fine-grained sandstones. The bulk carbonate content varies in the range 36-42 weight %. The carbonate mineralogy is dominated by aragonite that cements the detrital grains whereas calcite comes from the biogenic carbonates. Dolomite occurs in significant amount in a few samples. Circular cavities of 5 to 10 µm of diameter in the carbonate cement represent traces of gas bubbles; smaller holes in the aragonite crystals are due to carbonate dissolution by CO2 issued from aerobic oxidation of methane. The oxygen isotopic compositions of the bulk carbonate (+1.7 to +4.5‰) and aragonite cement (-0.2 to +1.4‰) are lower than the values in equilibrium with the present-day temperature and salinity conditions. This indicates that the carbonate precipitated in mixtures of seawater and continental water, i.e. in a context of submarine groundwater discharge. The carbon isotopic compositions of the bulk carbonate (-51.9 to -38.2‰) and aragonite cement (-49.9 to -29.3‰) demonstrate that most carbon derived from methane oxidized as bicarbonate during microbial anaerobic oxidation of methane. The GAZCOGNE study is co-funded by TOTAL and IFREMER as part of the PAMELA (Passive Margin Exploration Laboratories

  12. Measuring Temporal Variability of Methylmercury and Methane in the Pore Waters of a Chesapeake Bay Tidal Marsh

    Science.gov (United States)

    Martin, K. R.; Oster, J.; Lapham, L.; Heyes, A.

    2015-12-01

    This study assesses the use of OsmoSampler technology to monitor methylmercury production in a tidal marsh and examines temporal variability of methylmercury in relation to controlling factors. We collected pore water samples in a Chesapeake Bay marsh using continuous pore-fluid sampling devices called OsmoSamplers. OsmoSampler technology has not previously been used to investigate mercury cycling. We designed systems using OsmoSamplers to collect pore water samples for methylmercury, methane, chloride, and sulfate analysis, sampling in a vegetated area and an area devegetated by clipping. Samples were collected over a 27 day period and stored in coils to create a temporal data set of in situ concentrations. This time series allows us to explore the methane-methylmercury connection and the effects of vegetation removal on methylmercury production. Some methanogens are known to methylate mercury, but the relative importance of the methane community in mercury methylation is not well understood. We hypothesized a positive correlation between methane and methylmercury production and a decrease in methylmercury production corresponding to vegetation removal. We also sought to demonstrate the feasibility of using OsmoSamplers to look at methylmercury flux in relation to these controls on mercury methylation. This study is a preliminary exploration of this technology in a marsh environment. Using our system we have successfully collected pore water samples. We present the temporal variability of measured concentrations with a discussion of adjustments for future long-term deployment.

  13. Impact of Sundarban mangrove biosphere on the carbon dioxide and methane mixing ratios at the NE Coast of Bay of Bengal, India

    International Nuclear Information System (INIS)

    Diurnal and seasonal variations in carbon dioxide and methane fluxes between Sundarban biosphere and atmosphere were measured using micrometeorological method during 1998-2000. Study of the diurnal variation of micrometeorological conditions in the atmosphere was found to be necessary to determine the duration of neutral stability when flux estimation was reliable. Neutral stability of the atmosphere occurred in the limited micrometeorological conditions, when friction velocity ranged between 0.360 and 0.383ms-1. The value of drag coefficient (1.62-20.6) x 103 obtained at variable wind speed could be deemed specific for this particular surface. 58.2% drop of carbon dioxide and 63.4% drop of methane in the atmosphere at 1m height were observed during day time, between dawn and early evening. Diurnal variations in methane and carbon dioxide mixing ratios showed a positive correlation with Richardson's number (Ri). This environment acted as a net source for carbon dioxide and methane. The mixing ratios of methane were found to vary between 1.42 and 2.07ppmv, and that of carbon dioxide, between 324.3 and 528.7ppmv during the study period. The biosphere-atmosphere flux of carbon dioxide ranged between -3.29 and 34.4mgm-2s-1, and that of methane, between -4.53 and 8.88μgm-2s-1. The overall annual estimate of carbon dioxide and methane fluxes from this ecosystem to atmosphere were estimated to be 694Tgyr-1 and 184Ggyr-1, respectively. Considerable variations in mixing ratios of carbon dioxide and methane at the NE coast of Bay of Bengal were observed due to the seasonal variations of their fluxes from the biosphere to the atmosphere. The composition was inferred by fitting model prediction to measurements. (Author)

  14. Seasonal dynamics of methane emissions from a subarctic fen in the Hudson Bay Lowlands

    Directory of Open Access Journals (Sweden)

    K. L. Hanis

    2013-03-01

    Full Text Available Ecosystem-scale methane (CH4 flux (FCH4 over a subarctic fen at Churchill, Manitoba, Canada was measured to understand the magnitude of emissions during spring and fall shoulder seasons, and the growing season in relation to physical and biological conditions. FCH4 was measured using eddy covariance with a closed-path analyzer in four years (2008–2011. Cumulative measured annual FCH4 (shoulder plus growing seasons ranged from 3.0 to 9.6 g CH4 m−2 yr−1 among the four study years, with a mean of 6.5 to 7.1 g CH4 m−2 yr−1 depending upon gap-filling method. Soil temperatures to depths of 50 cm and air temperature were highly correlated with FCH4, with near surface soil temperature at 5 cm most correlated across spring, fall, and the whole season. The response of FCH4 to soil temperature at the 5 cm depth and air temperature was more than double in spring to that of fall. Emission episodes were generally not observed during spring thaw. Growing season emissions also depended upon soil and air temperatures but water table also exerted influence with FCH4 highest when water was 2–13 cm below and least when it was at or above the mean peat surface.

  15. Seasonal dynamics of methane emissions from a subarctic fen in the Hudson Bay Lowlands

    Science.gov (United States)

    Hanis, K. L.; Tenuta, M.; Amiro, B. D.; Papakyriakou, T. N.

    2013-07-01

    Ecosystem-scale methane (CH4) flux (FCH4) over a subarctic fen at Churchill, Manitoba, Canada was measured to understand the magnitude of emissions during spring and fall shoulder seasons, and the growing season in relation to physical and biological conditions. FCH4 was measured using eddy covariance with a closed-path analyser in four years (2008-2011). Cumulative measured annual FCH4 (shoulder plus growing seasons) ranged from 3.0 to 9.6 g CH4 m-2 yr-1 among the four study years, with a mean of 6.5 to 7.1 g CH4 m-2 yr-1 depending upon gap-filling method. Soil temperatures to depths of 50 cm and air temperature were highly correlated with FCH4, with near-surface soil temperature at 5 cm most correlated across spring, fall, and the shoulder and growing seasons. The response of FCH4 to soil temperature at the 5 cm depth and air temperature was more than double in spring to that of fall. Emission episodes were generally not observed during spring thaw. Growing season emissions also depended upon soil and air temperatures but the water table also exerted influence, with FCH4 highest when water was 2-13 cm below and lowest when it was at or above the mean peat surface.

  16. Seasonal dynamics of methane emissions from a subarctic fen in the Hudson Bay Lowlands

    Directory of Open Access Journals (Sweden)

    K. L. Hanis

    2013-07-01

    Full Text Available Ecosystem-scale methane (CH4 flux (FCH4 over a subarctic fen at Churchill, Manitoba, Canada was measured to understand the magnitude of emissions during spring and fall shoulder seasons, and the growing season in relation to physical and biological conditions. FCH4 was measured using eddy covariance with a closed-path analyser in four years (2008–2011. Cumulative measured annual FCH4 (shoulder plus growing seasons ranged from 3.0 to 9.6 g CH4 m−2 yr−1 among the four study years, with a mean of 6.5 to 7.1 g CH4 m−2 yr−1 depending upon gap-filling method. Soil temperatures to depths of 50 cm and air temperature were highly correlated with FCH4, with near-surface soil temperature at 5 cm most correlated across spring, fall, and the shoulder and growing seasons. The response of FCH4 to soil temperature at the 5 cm depth and air temperature was more than double in spring to that of fall. Emission episodes were generally not observed during spring thaw. Growing season emissions also depended upon soil and air temperatures but the water table also exerted influence, with FCH4 highest when water was 2–13 cm below and lowest when it was at or above the mean peat surface.

  17. Relationships between the distribution and stable isotopic composition of living benthic foraminifera and cold methane seep biogeochemistry in Monterey Bay, California

    Science.gov (United States)

    Rathburn, Anthony E.; PéRez, M. Elena; Martin, Jonathan B.; Day, Shelley A.; Mahn, Chris; Gieskes, Joris; Ziebis, Wiebke; Williams, David; Bahls, Amanda

    2003-12-01

    As part of an ongoing effort to explore the use of foraminifera as a means to assess modern and ancient methane release, we compared ambient pore water chemistry with the distribution and stable isotopic composition of living (rose Bengal stained) foraminifera in MBARI ROV Ventana tube cores taken from modern seepage areas (about 1000 m water depth) in Monterey Bay, California. Benthic foraminiferal isotopic differences between sites clearly indicate that methane-influenced pore waters affect foraminiferal distributions and carbonate isotope geochemistry. Carbon isotope signatures of living benthic foraminifera did not conform to the very negative (-30 to -48‰), methane-influenced carbon isotope values of the pore waters they live in. Instead, the influence of methane seep pore waters was reflected in the greater range and carbon isotopic variability of living seep foraminifera compared with published δ13C values of foraminifera living in nonseep habitats. It is not clear what relative influences biological, ecological, and physical factors have on the carbon isotopic signatures observed in seep foraminifera. Substantial carbon isotope differences can exist between individuals of the same seep species. For instance, δ13C values of living Globobulimina pacifica varied by as much as 2.9‰ between seeps within 8 km of each other, whereas δ13C values of living Uvigerina peregrina varied by as much as 1.95‰ within the same seep. Provided there is no diagenetic alteration of the test carbonate, isotopic results of individual seep foraminifera support the hypothesis that foraminifera can be used to assess past and present methane seepage.

  18. Extensive occurrence and genesis of authigenic carbonates from Krishna-Godavari offshore basin (Bay of Bengal): Possible influence of methane hydrates occurrences.

    Digital Repository Service at National Institute of Oceanography (India)

    Kocherla, M.; Pillai, S.; Patil, D.J.

    that the carbon source for the formation of authigenic carbonates were gas hydrates below, and the carbonates were formed from the flow of methane-enriched fluids through fracture network formed because of shale diapirism. The detailed genetic framework is under...

  19. An investigation into the influence of methane seepage on calcium, calcium carbonate and other elemental concentrations in shallow water sediments in Dunmanus Bay, Ireland.

    OpenAIRE

    Coleman, Nigel

    2015-01-01

    peer-reviewed In the marine environment, hydrocarbon seeps are known to be common and recognisable features and occur in shallow water and in the deep ocean. These seeps tend to be located at distinctive geotectonic, geochemical and biological interfaces where gas-rich fluids (e.g. methane) migrate upwards to the seabed. Seep characteristics range from diffuse seafloor venting to more focused low emission gas escape and these characteristics can be associated with morphological features on...

  20. Pore-water chemistry of sediment cores off Mahanadi Basin, Bay of Bengal: Possible link to deep seated methane hydrate deposit

    Digital Repository Service at National Institute of Oceanography (India)

    Mazumdar, A.; Peketi, A.; Joao, H.M.; Dewangan, P.; Ramprasad, T.

    electrons via enzymatic pathways (Canfield, 2001). Sulfate reducing bacteria are most active close to the sediment water interface owing to high labile organic load and sulfate flux at the interface (Kasten and Jørgensen, 2000; Megonigal et al., 2003, Wall... from 70 to 80 ‰ VPDP indicate the microbial origin of methane in Mahanadi basin via CO2 reduction pathway. Other factors which may influence δ13CCH4 include methanogenic precursor, fractionation factor and temperature etc. (Alperin et al., 1992...

  1. Effect of sediment composition on methane concentration and production in the transition zone of a mangrove (Sepetiba Bay, Rio de Janeiro, Brazil).

    Science.gov (United States)

    Marinho, C C; Campos, E A; Guimarães, J R D; Esteves, F A

    2012-08-01

    The aim of this research was to evaluate the effect of sediment composition on methane (CH4) dynamics in sediments of different areas in the transition zone between a mangrove and the sea. This research was conducted in a mangrove at Coroa Grande, on the southern coast of Rio de Janeiro. Samples were collected at three stations: (1) region colonised by Rhizophora mangle L. on the edge of the mangrove, (2) region colonised by seagrasses and (3) infra-littoral region without vegetation. Samples were collected from the surface layer of the sediment to determine the concentrations of nutrients (C, N and P) and CH4 concentration and production. We observed that concentrations of CH4 and carbon (C) were significantly higher (p Rhizophora mangle vegetation. PMID:22990811

  2. Greigite as a marker of paleo sulphate methane transition zone (SMTZ) in cold seep environment of Krishna-Godavari (KG) Basin, Bay of Bengal, India.

    Science.gov (United States)

    B, F. K.; Dewangan, P.; Usapkar, A.; Mazumdar, A.; Kocherla, M.; Tammisetti, R.; Khalap, S. T.; Satelkar, N. P.; Mehrtens, T.; Rosenauer, A.

    2014-12-01

    Rockmagnetic results and electron microscopic observations on a sediment core retrieved from a proven cold seep environment of Krishna-Godavari (KG) Basin revealed an anomalously magnetically enhanced zone (17 - 23 mbsf) below the present-day SMTZ in the KG offshore basin. This zone is characterized by higher SIRM / k, kARM / SIRM and kfd % values indicating the presence of fine grained superparamagnetic (SP) sized ferrimagnetic iron sulphides minerals such as greigite formed due to anaerobic oxidation of methane (AOM). Identification of such mineral phases and understanding the mechanism of their formation and preservation is of vital importance which could provide better understanding of the geochemical processes on the paleo - SMTZ. Magnetic concentrates extracted from this zone were characterised by transmission electron microscopy and energy dispersive X- ray spectrometry. We observed two possible occurrences of magnetic phases within this sediment depths 17 - 23 mbsf. (a) authigenically formed SP sized ferrimagnetic inclusions of magnetite, pyrite and greigite within matrix of host siliceous grain, (b) poorly crystallized fine-grained magnetite with ill defined grain boundary possibily formed extracellulary by magnetotactic bacterias through biologically-induced mineralization. High methane fluxes as observed in this basin provides suitable environment for the formation of greigite in the vicinity of SMTZ. We hypothesize that due to availability of residual iron and low supply of hydrogen sulphide caused by downwards diffusion lead to preservation of greigite. The occurence of greigite as inclusion within the host silicate matrix might explain its preservation in this zone in spite of intense pyritization. The greigite would otherwise be converted to stable-form pyrite. It is challenging to explain the origin of biologically produced magnetite within 17 - 23 mbsf as it is expected to dissolve in this zone due to intense pyritization.

  3. Methane Flux

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Methane (CH4) flux is the net rate of methane exchange between an ecosystem and the atmosphere. Data of this variable were generated by the USGS LandCarbon project...

  4. Arctic methane

    NARCIS (Netherlands)

    Dyupina, E.; Amstel, van A.R.

    2013-01-01

    What are the risks of a runaway greenhouse effect from methane release from hydrates in the Arctic? In January 2013, a dramatic increase of methane concentration up to 2000 ppb has been measured over the Arctic north of Norway in the Barents Sea. The global average being 1750 ppb. It has been sugges

  5. Agricultural methanization

    International Nuclear Information System (INIS)

    After having briefly outlined the interest of the development of methanization of agricultural by-products in the context of struggle against climate change, and noticed that France is only now developing this sector as some other countries already did, this publication describes the methanization process also called anaerobic digestion, which produces a digestate and biogas. Advantages for the agriculture sector are outlined, as well as drawbacks and recommendations (required specific technical abilities, an attention to the use of energetic crops, an improved economic balance which still depends on public subsidies, competition in the field of waste processing). Actions undertaken by the ADEME are briefly evoked

  6. Seawater methane flux, methane oxidation rates, and methane sources on the Central US Beaufort Sea Continental Shelf

    Science.gov (United States)

    Pohlman, J.; Pack-Woo, M.; Xu, X.; Ruppel, C. D.; Casso, M.; Worley, C.

    2012-12-01

    -to-air methane fluxes from nearshore shallow water to the shelf break. By surveying across the geophysically-defined permafrost-no-permafrost transition in both 2011 (Harrison Bay) and 2012, we have been able to evaluate the extent to which the thawing of subsea permafrost corresponds to changes in methane emission patterns. Vertical profiles of LL 14C tracer methane oxidation rates at distinct locations along the transect provide the modern constraints on the role of water column aerobic methanotrophs in mitigating methane emitted at the seafloor before it reaches the atmosphere. The combination of techniques employed here provide novel first order constraints on the sources of methane escaping sediments of the Central US Beaufort Shelf, the magnitude of greenhouse gases transmitted to the atmosphere and the role that methane oxidation plays in regulating these fluxes.

  7. Methane and fertilizer production from seaweed biomass. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Betzer, P.R.; Humm, H.J.

    1984-01-01

    It was demonstrated that several varieties of abundant benthic algae indigenous to Tampa Bay (Gracilaria, Hypnea, and Ulva) were readily degradable via anaerobic digestion to methane. The energy yield per unit weight biomass degraded was higher than any previously reported. Given the large masses of readily degradable plants which are annually produced in and around Tampa Bay, the resource is estimated to be at least equivalent to several million gallons of gasoline.

  8. Methane release

    International Nuclear Information System (INIS)

    The Swiss Gas Industry has carried out a systematic, technical estimate of methane release from the complete supply chain from production to consumption for the years 1992/1993. The result of this survey provided a conservative value, amounting to 0.9% of the Swiss domestic output. A continuation of the study taking into account new findings with regard to emission factors and the effect of the climate is now available, which provides a value of 0.8% for the target year of 1996. These results show that the renovation of the network has brought about lower losses in the local gas supplies, particularly for the grey cast iron pipelines. (author)

  9. Environmental control on aerobic methane oxidation in coastal waters

    Science.gov (United States)

    Steinle, Lea; Maltby, Johanna; Engbersen, Nadine; Zopfi, Jakob; Bange, Hermann; Elvert, Marcus; Hinrichs, Kai-Uwe; Kock, Annette; Lehmann, Moritz; Treude, Tina; Niemann, Helge

    2016-04-01

    Large quantities of methane are produced in anoxic sediments of continental margins and may be liberated to the overlying water column, where some of it is consumed by aerobic methane oxidizing bacteria (MOB). Aerobic methane oxidation (MOx) in the water column is consequently the final sink for methane before its release to the atmosphere, where it acts as a potent greenhouse gas. In the context of the ocean's contribution to atmospheric methane, coastal seas are particularly important accounting >75% of global methane emission from marine systems. Coastal oceans are highly dynamic, in particular with regard to the variability of methane and oxygen concentrations as well as temperature and salinity, all of which are potential key environmental factors controlling MOx. To determine important environmental controls on the activity of MOBs in coastal seas, we conducted a two-year time-series study with measurements of physicochemical water column parameters, MOx activity and the composition of the MOB community in a coastal inlet in the Baltic Sea (Boknis Eck Time Series Station, Eckernförde Bay - E-Bay). In addition, we investigated the influence of temperature and oxygen on MOx during controlled laboratory experiments. In E-Bay, hypoxia developed in bottom waters towards the end of the stratification period. Constant methane liberation from sediments resulted in bottom water methane accumulations and supersaturation (with respect to the atmospheric equilibrium) in surface waters. Here, we will discuss the factors impacting MOx the most, which were (i) perturbations of the water column (ii) temperature and (iii) oxygen concentration. (i) Perturbations of the water column caused by storm events or seasonal mixing led to a decrease in MOx, probably caused by replacement of stagnant water with a high standing stock of MOB by 'new' waters with a lower abundance of methanotrophs. b) An increase in temperature generally led to higher MOx rates. c) Even though methane was

  10. Bayes and empirical Bayes: do they merge?

    CERN Document Server

    Petrone, Sonia; Scricciolo, Catia

    2012-01-01

    Bayesian inference is attractive for its coherence and good frequentist properties. However, it is a common experience that eliciting a honest prior may be difficult and, in practice, people often take an {\\em empirical Bayes} approach, plugging empirical estimates of the prior hyperparameters into the posterior distribution. Even if not rigorously justified, the underlying idea is that, when the sample size is large, empirical Bayes leads to "similar" inferential answers. Yet, precise mathematical results seem to be missing. In this work, we give a more rigorous justification in terms of merging of Bayes and empirical Bayes posterior distributions. We consider two notions of merging: Bayesian weak merging and frequentist merging in total variation. Since weak merging is related to consistency, we provide sufficient conditions for consistency of empirical Bayes posteriors. Also, we show that, under regularity conditions, the empirical Bayes procedure asymptotically selects the value of the hyperparameter for ...

  11. Large-scale environmental drivers of North American methane emissions

    Science.gov (United States)

    Miller, S. M.; Kort, E. A.; Worthy, D.; Havice, T. C.; Dlugokencky, E. J.; Andrews, A. E.; Wofsy, S. C.

    2011-12-01

    Uncertainties in environmental drivers have made it difficult for existing methane inventories to accurately assess the magnitude and seasonality of emissions. We characterize methane sources over northern North America and provide insight into the underlying environmental processes driving both anthropogenic and natural emissions. This study employs top-down inversion methods to examine driving emissions processes at continental scales. Tower measurements and a geostatistical inversion within a high resolution particle dispersion model (STILT) help constrain methane sources. We find a large methane source over the Hudson Bay Lowland in Canada, which exhibits a delayed, shorter seasonality than most existing inventories. Our analysis suggests a need to improve the treatment of soil temperature in many biogeochemical models of wetland sources.

  12. San Diego Bay Bibliography

    OpenAIRE

    Brueggeman, Peter

    1994-01-01

    The San Diego Bay Bibliography references the scientific & gray literature on the Bay up through 1994 and it is NOT current. Compiled from numerous resources (including Hubbs-Sea World Research Institute, Regional Water Quality Control Board, & local library catalogs), it is not comprehensive since so the Bay literature is elusive. In addition, there can be duplicate references varying in completeness. The San Diego Bay Bibliography is the outcome of discussion and networking within ...

  13. Investigations of Methane Production in Hypersaline Environments

    Science.gov (United States)

    Bebout, Brad M.

    2015-01-01

    The recent reports of methane in the atmosphere of Mars, as well as the findings of hypersaline paleo-environments on that planet, have underscored the need to evaluate the importance of biological (as opposed to geological) trace gas production and consumption. Methane in the atmosphere of Mars may be an indication of life but might also be a consequence of geologic activity and/or the thermal alteration of ancient organic matter. Hypersaline environments have now been reported to be extremely likely in several locations in our solar system, including: Mars, Europa, and Enceladus. Modern hypersaline microbial mat communities, (thought to be analogous to those present on the early Earth at a period of time when Mars was experiencing very similar environmental conditions), have been shown to produce methane. However, very little is known about the physical and/or biological controls imposed upon the rates at which methane, and other important trace gases, are produced and consumed in these environments. We describe here the results of our investigations of methane production in hypersaline environments, including field sites in Chile, Baja California Mexico, California, USA and the United Arab Emirates. We have measured high concentrations of methane in bubbles of gas produced both in the sediments underlying microbial mats, as well as in areas not colonized by microbial mats in the Guerrero Negro hypersaline ecosystem, Baja California Mexico, in Chile, and in salt ponds on the San Francisco Bay. The carbon isotopic (d13C) composition of the methane in the bubbles exhibited an extremely wide range of values, (ca. -75 per mille ca. -25 per mille). The hydrogen isotopic composition of the methane (d2H) ranged from -60 to -30per mille and -450 to -350per mille. These isotopic values are outside of the range of values normally considered to be biogenic, however incubations of the sediments in contact with these gas bubbles reveals that the methane is indeed being

  14. Methane emission from sewers.

    Science.gov (United States)

    Liu, Yiwen; Ni, Bing-Jie; Sharma, Keshab R; Yuan, Zhiguo

    2015-08-15

    Recent studies have shown that sewer systems produce and emit a significant amount of methane. Methanogens produce methane under anaerobic conditions in sewer biofilms and sediments, and the stratification of methanogens and sulfate-reducing bacteria may explain the simultaneous production of methane and sulfide in sewers. No significant methane sinks or methanotrophic activities have been identified in sewers to date. Therefore, most of the methane would be emitted at the interface between sewage and atmosphere in gravity sewers, pumping stations, and inlets of wastewater treatment plants, although oxidation of methane in the aeration basin of a wastewater treatment plant has been reported recently. Online measurements have also revealed highly dynamic temporal and spatial variations in methane production caused by factors such as hydraulic retention time, area-to-volume ratio, temperature, and concentration of organic matter in sewage. Both mechanistic and empirical models have been proposed to predict methane production in sewers. Due to the sensitivity of methanogens to environmental conditions, most of the chemicals effective in controlling sulfide in sewers also suppress or diminish methane production. In this paper, we review the recent studies on methane emission from sewers, including the production mechanisms, quantification, modeling, and mitigation. PMID:25889543

  15. Methane-Powered Vehicles

    Science.gov (United States)

    1982-01-01

    Liquid methane is beginning to become an energy alternative to expensive oil as a power source for automotive vehicles. Methane is the principal component of natural gas, costs less than half as much as gasoline, and its emissions are a lot cleaner than from gasoline or diesel engines. Beech Aircraft Corporation's Boulder Division has designed and is producing a system for converting cars and trucks to liquid methane operation. Liquid methane (LM) is a cryogenic fuel which must be stored at a temperature of 260 degrees below zero Fahrenheit. The LM system includes an 18 gallon fuel tank in the trunk and simple "under the hood" carburetor conversion equipment. Optional twin-fuel system allows operator to use either LM or gasoline fuel. Boulder Division has started deliveries for 25 vehicle conversions and is furnishing a liquid methane refueling station. Beech is providing instruction for Northwest Natural Gas, for conversion of methane to liquid state.

  16. Isotopic and chemical composition of submarine geothermal gases from the Bay of Plenty, New Zealand

    International Nuclear Information System (INIS)

    Gas samples collected from the ocean floor near Whale Island, Bay of Plenty, New Zealand, are composed of carbon dioxide, methane, hydrogen, and air. The methane has an isotopic composition of delta13C(PDB) = -280/00 and deltaD(SMOW) = -1250/00. The isotopic and chemical composition show that the gases are of geothermal origin and similar to gas evolved from Whale Island hot springs

  17. Tampa Bay: Chapter N

    Science.gov (United States)

    Handley, Larry; Spear, Kathryn; Cross, Lindsay; Baumstark, René; Moyer, Ryan; Thatcher, Cindy

    2013-01-01

    Tampa Bay is Florida’s largest open-water estuary and encompasses an area of approximately 1036 km2 (400 mi2) (Burgan and Engle, 2006; TBNEP, 2006). The Bay’s watershed drains 5,698 km2 (2,200 mi2) of land and includes freshwater from the Hillsborough River to the north east, the Alafia and Little Manatee rivers to the east, and the Manatee River to the south (Figure 1). Freshwater inflow also enters the bay from the Lake Tarpon Canal, from small tidal tributaries, and from watershed runoff. Outflow travels from the upper bay segments (Hillsborough Bay and Old Tampa Bay) into Middle and Lower Tampa Bay. Southwestern portions of the water shed flow through Boca Ciega Bay into the Intracoastal Waterway and through the Southwest Channel and Passage Key Inlet into the Gulf of Mexico. The average depth in most of Tampa Bay is only 3.4 m (11 ft); however, 129 km (80 mi) of shipping channels with a maximum depth of 13.1 m (43 ft) have been dredged over time and are regularly maintained. These channels help to support the three ports within the bay, as well as commercial and recreational boat traffic.

  18. Methanation assembly using multiple reactors

    Science.gov (United States)

    Jahnke, Fred C.; Parab, Sanjay C.

    2007-07-24

    A methanation assembly for use with a water supply and a gas supply containing gas to be methanated in which a reactor assembly has a plurality of methanation reactors each for methanating gas input to the assembly and a gas delivery and cooling assembly adapted to deliver gas from the gas supply to each of said methanation reactors and to combine water from the water supply with the output of each methanation reactor being conveyed to a next methanation reactor and carry the mixture to such next methanation reactor.

  19. Utilization of coalbed methane

    Energy Technology Data Exchange (ETDEWEB)

    Gustavson, J.B. [Gustavson Associates Inc., Boulder, CO (United States)

    1996-02-01

    Substantial progress has been made in capturing coalbed methane (CBM gas), which constitutes a valuable source of clean burning energy. It is of importance to study the various potential uses of coalbed methane and to understand the various technologies required, as well as their economics and any institutional constraints. In industrialised countries, the uses of coalbed methane are almost solely dependent on microeconomics; coalbed methane must compete for a market against natural gas and other energy sources - and frequently, coalbed methane is not competitive against other energy sources. In developing countries, on the other hand, particularly where other sources of energy are in short supply, coalbed methane economics yield positive results. Here, constraints to development of CBM utilization are mainly lack of technology and investment capital. Sociological aspects such as attitude and cultural habits, may also have a strong negative influence. This paper outlines the economics of coalbed methane utilization, particularly its competition with natural gas, and touches upon the many different uses to which coalbed methane may be applied. 24 refs., 4 figs.

  20. Methane and Climate Change

    NARCIS (Netherlands)

    Reay, D.; Smith, P.; Amstel, van A.R.

    2010-01-01

    Methane is a powerful greenhouse gas and is estimated to be responsible for approximately one-fifth of man-made global warming. Per kilogram, it is 25 times more powerful than carbon dioxide over a 100-year time horizon -- and global warming is likely to enhance methane release from a number of sour

  1. eBay.com

    DEFF Research Database (Denmark)

    Engholm, Ida

    2014-01-01

    Celebrated as one of the leading and most valuable brands in the world, eBay has acquired iconic status on par with century-old brands such as Coca-Cola and Disney. The eBay logo is now synonymous with the world’s leading online auction website, and its design is associated with the company’s...

  2. Methane flux from sediment into near-bottom water and its variability along the Hel Peninsula—Southern Baltic Sea

    Science.gov (United States)

    Reindl, Andrzej R.; Bolałek, Jerzy

    2014-02-01

    Methane in the sediments of the Bay of Puck occurs in the form of free gas bubbles and is released from the sediments into near-bottom water in the form of a flux. The sediments of the Bay of Puck also contain methanogens whose biological activity results in the production of methane. Research carried out in the coastal areas of the bay along the Hel Peninsula proved the existence of a methane flux ranging from 0.81 mmol m-2 d-1 to 33.41 mmol m-2 d-1 in 2011, while in 2010 ranged from 0.91 mmol m-2 d-1 to 49.15 mmol m-2 d-1. Seasonal and annual fluctuations were also observed. Other factors contributing to the change in methane flux are water temperature and other environmental factors. An increase in temperature causes an increase in the flux. Fluctuations of the flux within individual sampling sites were also observed. A test performed with specific methanogenic inhibitor—sodium dodecyl sulfate (SDS) unexpectedly revealed higher methane concentrations (10-13%) in samples to which SDS was added. We speculate that these higher methane concentration result from the lysis of methane-forming bacteria cells when exposed to SDS.

  3. Methane: A Neglected Greenhouse Gas

    OpenAIRE

    Claudia Kemfert; Wolf-Peter Schill

    2009-01-01

    Methane is a greenhouse gas that gets far less public attention than carbon dioxide. This is entirely unwarranted. Being 25 times more potent than carbon dioxide in trapping heat in the atmosphere, methane accounts for about one-sixth of all anthropogenic (i.e. human-induced) greenhouse gas emissions. Methane is also overlooked when it comes to taking concrete measures for climate protection, despite the fact that reducing methane emissions is potentially cheap. Major sources of methane emiss...

  4. Enzymatic Oxidation of Methane

    Energy Technology Data Exchange (ETDEWEB)

    Sirajuddin, S; Rosenzweig, AC

    2015-04-14

    Methane monooxygenases (MMOs) are enzymes that catalyze the oxidation of methane to methanol in methanotrophic bacteria. As potential targets for new gas-to-liquid methane bioconversion processes, MMOs have attracted intense attention in recent years. There are two distinct types of MMO, a soluble, cytoplasmic MMO (sMMO) and a membrane-bound, particulate MMO (pMMO). Both oxidize methane at metal centers within a complex, multisubunit scaffold, but the structures, active sites, and chemical mechanisms are completely different. This Current Topic review article focuses on the overall architectures, active site structures, substrate reactivities, proteinprotein interactions, and chemical mechanisms of both MMOs, with an emphasis on fundamental aspects. In addition, recent advances, including new details of interactions between the sMMO components, characterization of sMMO intermediates, and progress toward understanding the pMMO metal centers are highlighted. The work summarized here provides a guide for those interested in exploiting MMOs for biotechnological applications.

  5. Laser beam methane detector

    Science.gov (United States)

    Hinkley, E. D., Jr.

    1981-01-01

    Instrument uses infrared absorption to determine methane concentration in liquid natural gas vapor. Two sensors measure intensity of 3.39 mm laser beam after it passes through gas; absorption is proportional to concentration of methane. Instrument is used in modeling spread of LNG clouds and as leak detector on LNG carriers and installations. Unit includes wheels for mobility and is both vertically and horizontally operable.

  6. Hammond Bay Biological Station

    Data.gov (United States)

    Federal Laboratory Consortium — Hammond Bay Biological Station (HBBS), located near Millersburg, Michigan, is a field station of the USGS Great Lakes Science Center (GLSC). HBBS was established by...

  7. Humboldt Bay Orthoimages

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This data set consists of 0.5-meter pixel resolution, four band orthoimages covering the Humboldt Bay area. An orthoimage is remotely sensed image data in which...

  8. Bathymetry in Jobos Bay

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a 4x4 meter resolution bathymetric surface for Jobos Bay, Puerto Rico (in NAD83 UTM 19 North). The depth values are in meters referenced to...

  9. Logy Bay Fishing Settlement

    OpenAIRE

    S H Parsons and Sons

    2003-01-01

    202 x 151 mm. Showing the small inlet with moored rowing boats and rough wooden shacks built on the cliffside. Lying about seven miles from St. John's, Logy Bay was used as a summertime fishing station.

  10. Biscayne Bay Alongshore Epifauna

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Field studies to characterize the alongshore epifauna (shrimp, crabs, echinoderms, and small fishes) along the western shore of southern Biscayne Bay were started...

  11. Methane Emissions from Upland Forests

    Science.gov (United States)

    Megonigal, Patrick; Pitz, Scott; Wang, Zhi-Ping

    2016-04-01

    Global budgets ascribe 4-10% of atmospheric methane sinks to upland soils and assume that soils are the sole surface for methane exchange between upland forests and the atmosphere. The dogma that upland forests are uniformly atmospheric methane sinks was challenged a decade ago by the discovery of abiotic methane production from plant tissue. Subsequently a variety of relatively cryptic microbial and non-microbial methane sources have been proposed that have the potential to emit methane in upland forests. Despite the accumulating evidence of potential methane sources, there are few data demonstrating actual emissions of methane from a plant surface in an upland forest. We report direct observations of methane emissions from upland tree stems in two temperate forests. Stem methane emissions were observed from several tree species that dominate a forest located on the mid-Atlantic coast of North America (Maryland, USA). Stem emissions occurred throughout the growing season while soils adjacent to the trees simultaneously consumed methane. Scaling fluxes by stem surface area suggested the forest was a net methane source during a wet period in June, and that stem emissions offset 5% of the soil methane sink on an annual basis. High frequency measurements revealed diurnal cycles in stem methane emission rates, pointing to soils as the methane source and transpiration as the most likely pathway for gas transport. Similar observations were made in an upland forest in Beijing, China. However, in this case the evidence suggested the methane was not produced in soils, but in the heartwood by microbial or non-microbial processes. These data challenge the concept that forests are uniform sinks of methane, and suggest that upland forests are smaller methane sinks than previously estimated due to stem emissions. Tree emissions may be particularly important in upland tropical forests characterized by high rainfall and transpiration.

  12. The Nordic methane project

    International Nuclear Information System (INIS)

    The aim of NGC's 1992 methane project have been to compile a methane emission estimate with a higher accuracy and degree of documentation than before. Danish Gas Technology Centre has been engaged to draw up the project report and to assist with equipment for the emission measurements. The evaluation and analysis of data regarding the distribution sector have been carried out by Radian, the consultant of the Gas Research Institute (GRI)/environmental Protection Agency (EPA) - Methane Emission Project. Measurements have been made of the discharge rate from identified leaks. All measurement data has been systematized according to type and age of pipe. HNG is one of the distribution companies, which had carried out a measurement programme on the underground distribution network. The transmission companies' contributions to the Nordic project have been logging data for vented and flared gas in the context of operations and maintenance. The operator companies in Norway have finished an extensive environmental programme in which discharges of methane, among other substances, has been determined. Prime emission sources have been identified and reduction measures proposed. The relative natural gas leakage rate is calculated as the leakage rate of the total volume of natural gas in relation to production, transmission, and distribution, respectively. The accuracy of the methane emission estimates for the natural gas production and the distribution networks must be regarded as the best available. The estimated relative precision of the total leakage estimate for the distribution networks is ± 54 per cent based on a 90 per cent of confidence. The methane emission estimate for the transmission networks has some degree of uncertainty, but even a high degree of uncertainty would have a minor influence on the total methane emission estimate. (EG) (19 refs.)

  13. Module bay with directed flow

    Science.gov (United States)

    Torczynski, John R.

    2001-02-27

    A module bay requires less cleanroom airflow. A shaped gas inlet passage can allow cleanroom air into the module bay with flow velocity preferentially directed toward contaminant rich portions of a processing module in the module bay. Preferential gas flow direction can more efficiently purge contaminants from appropriate portions of the module bay, allowing a reduced cleanroom air flow rate for contaminant removal. A shelf extending from an air inlet slit in one wall of a module bay can direct air flowing therethrough toward contaminant-rich portions of the module bay, such as a junction between a lid and base of a processing module.

  14. 33 CFR 100.124 - Maggie Fischer Memorial Great South Bay Cross Bay Swim, Great South Bay, New York.

    Science.gov (United States)

    2010-07-01

    ... South Bay Cross Bay Swim, Great South Bay, New York. 100.124 Section 100.124 Navigation and Navigable... NAVIGABLE WATERS § 100.124 Maggie Fischer Memorial Great South Bay Cross Bay Swim, Great South Bay, New York... swimmer or safety craft on the swim event race course bounded by the following points: Starting Point...

  15. Direct Activation Of Methane

    KAUST Repository

    Basset, Jean-Marie

    2013-07-15

    Heteropolyacids (HPAs) can activate methane at ambient temperature (e.g., 20.degree. C.) and atmospheric pressure, and transform methane to acetic acid, in the absence of any noble metal such as Pd). The HPAs can be, for example, those with Keggin structure: H.sub.4SiW.sub.12O.sub.40, H.sub.3PW.sub.12O.sub.40, H.sub.4SiMo.sub.12O.sub.40, or H.sub.3PMo.sub.12O.sub.40, can be when supported on silica.

  16. The Fermi's Bayes Theorem

    CERN Document Server

    D'Agostini, G

    2005-01-01

    It is curious to learn that Enrico Fermi knew how to base probabilistic inference on Bayes theorem, and that some influential notes on statistics for physicists stem from what the author calls elsewhere, but never in these notes, {\\it the Bayes Theorem of Fermi}. The fact is curious because the large majority of living physicists, educated in the second half of last century -- a kind of middle age in the statistical reasoning -- never heard of Bayes theorem during their studies, though they have been constantly using an intuitive reasoning quite Bayesian in spirit. This paper is based on recollections and notes by Jay Orear and on Gauss' ``Theoria motus corporum coelestium'', being the {\\it Princeps mathematicorum} remembered by Orear as source of Fermi's Bayesian reasoning.

  17. Direct Aromaization of Methane

    Energy Technology Data Exchange (ETDEWEB)

    George Marcelin

    1997-01-15

    The thermal decomposition of methane offers significant potential as a means of producing higher unsaturated and aromatic hydrocarbons when the extent of reaction is limited. Work in the literature previous to this project had shown that cooling the product and reacting gases as the reaction proceeds would significantly reduce or eliminate the formation of solid carbon or heavier (Clo+) materials. This project studied the effect and optimization of the quenching process as a means of increasing the amount of value added products during the pyrolysis of methane. A reactor was designed to rapidly quench the free-radical combustion reaction so as to maximize the yield of aromatics. The use of free-radical generators and catalysts were studied as a means of lowering the reaction temperature. A lower reaction temperature would have the benefits of more rapid quenching as well as a more feasible commercial process due to savings realized in energy and material of construction costs. It was the goal of the project to identify promising routes from methane to higher hydrocarbons based on the pyrolysis of methane.

  18. Methane emissions from grasslands.

    NARCIS (Netherlands)

    Pol-van Dasselaar, van den A.

    1998-01-01

    IntroductionMethane (CH 4 ) is an important greenhouse gas. The concentration of greenhouse gases in the atmosphere has been increasing since pre-industrial times, mainly due to human activities. This increase gives concern, because it may cause global warming due to an enhanced greenhous

  19. Enzymatic oxidation of methane.

    Science.gov (United States)

    Sirajuddin, Sarah; Rosenzweig, Amy C

    2015-04-14

    Methane monooxygenases (MMOs) are enzymes that catalyze the oxidation of methane to methanol in methanotrophic bacteria. As potential targets for new gas-to-liquid methane bioconversion processes, MMOs have attracted intense attention in recent years. There are two distinct types of MMO, a soluble, cytoplasmic MMO (sMMO) and a membrane-bound, particulate MMO (pMMO). Both oxidize methane at metal centers within a complex, multisubunit scaffold, but the structures, active sites, and chemical mechanisms are completely different. This Current Topic review article focuses on the overall architectures, active site structures, substrate reactivities, protein-protein interactions, and chemical mechanisms of both MMOs, with an emphasis on fundamental aspects. In addition, recent advances, including new details of interactions between the sMMO components, characterization of sMMO intermediates, and progress toward understanding the pMMO metal centers are highlighted. The work summarized here provides a guide for those interested in exploiting MMOs for biotechnological applications. PMID:25806595

  20. Impact of seasonal temperature and pressure changes on methane gas production, dissolution, and transport in unfractured sediments

    NARCIS (Netherlands)

    Mogollón, J.M.; Dale, A.W.; L'Heureux, I.; Regnier, P.

    2011-01-01

    A one‐dimensional reaction‐transport model is used to investigate the dynamics of methane gas in coastal sediments in response to intra‐annual variations in temperature and pressure. The model is applied to data from two shallow water sites in Eckernförde Bay (Germany) characterized by low and high

  1. Another Source of Atmospheric Methane

    Institute of Scientific and Technical Information of China (English)

    于心科

    1997-01-01

    The atmospheric concentration of methane is steadily increasin.Lacking of precise estimates of source and sink strengths for the atmospheric methane severely limits the current understanding of the global methane cycle.Agood budget of atmospheric methane can enhance our understanding of the global carbon cycle and global climate change,The known estimates of the main source and sink strengths are gresented in this paper,In terms of carbon isotopic studies,it is evidenced that the earth's primodial methane,which was trapped in the earth during its formation,may be another source of methane,with extensive,earth's degassing which is calleld the "breathing" process of the earth and played an important role in the formation of the promitive atmosphere,large amounts of methane were carried from the deep interior to the surface and then found its way into the atmosphere.

  2. Methane capture from livestock manure.

    Science.gov (United States)

    Tauseef, S M; Premalatha, M; Abbasi, Tasneem; Abbasi, S A

    2013-03-15

    It has been estimated that livestock manure contributes about 240 million metric tons of carbon dioxide equivalent of methane to the atmosphere and represents one of the biggest anthropogenic sources of methane. Considering that methane is the second biggest contributor to global warming after carbon dioxide, it is imperative that ways and means are developed to capture as much of the anthropogenic methane as possible. There is a major associated advantage of methane capture: its use as a source of energy which is comparable in 'cleanness' to natural gas. The present review dwells upon the traditional ways of methane capture used in India, China, and other developing countries for providing energy to the rural poor. It then reviews the present status of methane capture from livestock manure in developed countries and touches upon the prevalent trends.

  3. Yaquina Bay Topobathy DEM

    Science.gov (United States)

    The U.S.EPA contracted with the U.S.ACE to obtain intertidal and subtidal bathymetric soundings of Yaquina Bay between Poole Slough and the South Beach Marina in 2002. These data were compiled with U.S.ACE subtidal soundings from 1999, 1998, 2000 and National Ocean Service soundi...

  4. Observational constraints on the distribution, seasonality, and environmental predictors of North American boreal methane emissions

    Science.gov (United States)

    Miller, Scot M.; Worthy, Doug E. J.; Michalak, Anna M.; Wofsy, Steven C.; Kort, Eric A.; Havice, Talya C.; Andrews, Arlyn E.; Dlugokencky, Edward J.; Kaplan, Jed O.; Levi, Patricia J.; Tian, Hanqin; Zhang, Bowen

    2014-02-01

    Wetlands comprise the single largest global source of atmospheric methane, but current flux estimates disagree in both magnitude and distribution at the continental scale. This study uses atmospheric methane observations over North America from 2007 to 2008 and a geostatistical inverse model to improve understanding of Canadian methane fluxes and associated biogeochemical models. The results bridge an existing gap between traditional top-down, inversion studies, which typically emphasize total emission budgets, and biogeochemical models, which usually emphasize environmental processes. The conclusions of this study are threefold. First, the most complete process-based methane models do not always describe available atmospheric methane observations better than simple models. In this study, a relatively simple model of wetland distribution, soil moisture, and soil temperature outperformed more complex model formulations. Second, we find that wetland methane fluxes have a broader spatial distribution across western Canada and into the northern U.S. than represented in existing flux models. Finally, we calculate total methane budgets for Canada and for the Hudson Bay Lowlands, a large wetland region (50-60°N, 75-96°W). Over these lowlands, we find total methane fluxes of 1.8±0.24 Tg C yr-1, a number in the midrange of previous estimates. Our total Canadian methane budget of 16.0±1.2 Tg C yr-1 is larger than existing inventories, primarily due to high anthropogenic emissions in Alberta. However, methane observations are sparse in western Canada, and additional measurements over Alberta will constrain anthropogenic sources in that province with greater confidence.

  5. Project identification for methane reduction options

    Energy Technology Data Exchange (ETDEWEB)

    Kerr, T.

    1996-12-31

    This paper discusses efforts directed at reduction in emission of methane to the atmosphere. Methane is a potent greenhouse gas, which on a 20 year timeframe may present a similar problem to carbon dioxide. In addition, methane causes additional problems in the form of smog and its longer atmospheric lifetime. The author discusses strategies for reducing methane emission from several major sources. This includes landfill methane recovery, coalbed methane recovery, livestock methane reduction - in the form of ruminant methane reduction and manure methane recovery. The author presents examples of projects which have implemented these ideas, the economics of the projects, and additional gains which come from the projects.

  6. Coal Bed Methane Primer

    Energy Technology Data Exchange (ETDEWEB)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of

  7. Oxidation and Assimilation of Atmospheric Methane by Soil Methane Oxidizers

    OpenAIRE

    Roslev, P.; Iversen, N.; Henriksen, K.

    1997-01-01

    The metabolism of atmospheric methane in a forest soil was studied by radiotracer techniques. Maximum (sup14)CH(inf4) oxidation (163.5 pmol of C cm(sup-3) h(sup-1)) and (sup14)C assimilation (50.3 pmol of C cm(sup-3) h(sup-1)) occurred at the A(inf2) horizon located 15 to 18 cm below the soil surface. At this depth, 31 to 43% of the atmospheric methane oxidized was assimilated into microbial biomass; the remaining methane was recovered as (sup14)CO(inf2). Methane-derived carbon was incorporat...

  8. Methane ocean on Titan?

    Science.gov (United States)

    Bell, Peter M.

    There was an impressive list of names on a recent scientific communication that argues for the existence on Titan of an ocean of liquid methane (CH4) perhaps several hundred meters deep. C. Sagan and S. Dermott with helpful comments by S. Oter, S. Ostro, S. Peale, C. Yoder, W. Thompson, S. Squyres, G. Pettengill, P. Gierasch, and B. Khare speculate that such a methanic ocean, with its Saturnian tides and its tholinian floor, should exist all over Titan's surface; it should unless, they conclude, there is the ‘distracting coincidence [that] … the position of the surface of Titan [is] … near the liquidus in the CH4phase diagram [and, consequently, there is] …almost no methane ocean at all’ (Nature, 300, 731, 1982).We know very little about Titan and its surface; the way of checking into Sagan and Dermott's ideas appears to rest on the interpretation of radar reflectivity data. Preliminary attempts to obtain radar data were made in 1979 with the 305-m Arecibo telescope, but only broad limits resulted. The next opportunity for a measurement at Arecibo comes in the 1990's. Of course, the ideal circumstance would be to send spacecraft equipped with a radar reflectometer for a Titan flyby.

  9. Bayes and the Law

    Science.gov (United States)

    Fenton, Norman; Neil, Martin; Berger, Daniel

    2016-01-01

    Although the last forty years has seen considerable growth in the use of statistics in legal proceedings, it is primarily classical statistical methods rather than Bayesian methods that have been used. Yet the Bayesian approach avoids many of the problems of classical statistics and is also well suited to a broader range of problems. This paper reviews the potential and actual use of Bayes in the law and explains the main reasons for its lack of impact on legal practice. These include misconceptions by the legal community about Bayes’ theorem, over-reliance on the use of the likelihood ratio and the lack of adoption of modern computational methods. We argue that Bayesian Networks (BNs), which automatically produce the necessary Bayesian calculations, provide an opportunity to address most concerns about using Bayes in the law. PMID:27398389

  10. Methane Activation by Heterogeneous Catalysis

    OpenAIRE

    Horn, R.; Schlögl, R.

    2015-01-01

    Methane activation by heterogeneous catalysis will play a key role to secure the supply of energy, chemicals and fuels in the future. Methane is the main constituent of natural gas and biogas and it is also found in crystalline hydrates at the continental slopes of many oceans and in permafrost areas. In view of this vast reserves and resources, the use of methane as chemical feedstock has to be intensified. The present review presents recent results and developments in heterogeneous catalyti...

  11. Methanogens, Methane and Gastrointestinal Motility

    OpenAIRE

    Triantafyllou, Konstantinos; Chang, Christopher; Pimentel, Mark

    2013-01-01

    Anaerobic fermentation of the undigested polysaccharide fraction of carbohydrates produces hydrogen in the intestine which is the substrate for methane production by intestinal methanogens. Hydrogen and methane are excreted in the flatus and in breath giving the opportunity to indirectly measure their production using breath testing. Although methane is detected in 30%-50% of the healthy adult population worldwide, its production has been epidemiologically and clinically associated with const...

  12. Methane flux from wetlands areas

    OpenAIRE

    BAKER-BLOCKER, ANITA; Donahue, Thomas M.; MANCY, KHALIL H.

    2011-01-01

    Ebullient gases from Michigan wetlands have been collected and analyzed to deduce in situ methane fluxes. Methane flux has been found to be a function of mean air temperature. This relationship has been utilized to extrapolate observed methane fluxes to estimates of fluxes from the Pripet marshes, Sudd, Everglades, and Ugandan swamps. These four wetlands together provide a yearly source of 6.8 × 1013 g of methane to the atmosphere.DOI: 10.1111/j.2153-3490.1977.tb00731.x

  13. On methane pyrolysis special applications

    Science.gov (United States)

    Toncu, D. C.; Toncu, G.; Soleimani, S.

    2015-11-01

    Methane pyrolysis represents one of the most important processes in industrial use, with applications rising from the chemical and petrochemical industry, combustion, materials and protective coatings. Despite the intense research, experimental data lack kinetic aspects, and the thermodynamics involved often leads to inaccurate results when applied to various systems. Carrying out a comparative analysis of several available data on methane pyrolysis, the paper aims to study the phenomenon of methane pyrolysis under different environments (combustion and plasma), concluding on the most possible reaction pathways involved in many of its applications. Computer simulation using different database underlines the conclusion, helping to the understanding of methane pyrolysis importance in future technologies.

  14. 75 FR 11837 - Chesapeake Bay Watershed Initiative

    Science.gov (United States)

    2010-03-12

    ... Commodity Credit Corporation Chesapeake Bay Watershed Initiative AGENCY: Commodity Credit Corporation and... program funds for the Chesapeake Bay Watershed Initiative. SUMMARY: The Commodity Credit Corporation (CCC... Watershed Initiative for agricultural producers in the Chesapeake Bay watershed in the States of...

  15. BCDC Bay Trail Alignment 2009

    Data.gov (United States)

    California Department of Resources — The Bay Trail provides easily accessible recreational opportunities for outdoor enthusiasts, including hikers, joggers, bicyclists and skaters. It also offers a...

  16. Methane emissions from bald cypress tree trunks in a bottomland forest

    Science.gov (United States)

    Schile, L. M.; Pitz, S.; Megonigal, P.

    2013-12-01

    Studies on natural methane emissions predominantly have occurred on wetland soils with herbaceous plant species. Less attention, however, has been placed on the role of woody wetland plant species in the methane cycle. Recent studies on methane emissions from tree trunks document that they are a significant source of emissions that previously has been not accounted for. In this study, we examine methane emissions from trunks of mature bald cypress (Taxodium distichum), which is a dominant tree species in bottomland hardwood forests of the Southeastern United States. To date, little is known about soil methane emissions in these systems, and published tree emissions have been limited to a single study conducted on bald cypress knees. In May 2013, we established a plot in a monospecific bald cypress stand planted approximately 70 years ago on the Chesapeake Bay in Maryland and are monitoring methane emissions on 12 tree trunks, soil chambers, and pore-water over the course of a year. Custom-made 30 cm tall open face rectangular tree chambers were constructed out of white acrylic sheets and secured on each tree at a midpoint of 45 cm above the soil surface. Chambers were lined with neoprene along the tree surface and sealed with an epoxy. On three trees that varied in trunk diameter, chambers were placed at average heights of 95, 145, 195, and 345 cm from the soil surface in order to calculate a decay curve of methane emissions. Once a month, chambers were sealed with lids and head-space samples were collected over the course of an hour. Methane flux was calculated and compared to emissions from soil chambers. Average cypress trunk methane fluxes ranged from 17.7 μmole m-2 hr-1 in May to 49.5 and 116.5 μmole m-2 hr-1 in June and July, respectively. Soil fluxes averaged 28.5 μmole m-2 hr-1 in May and June, and decreased to 13.7 μmole m-2 hr-1 in July. Methane emissions decreased exponentially up the tree trunk, with fluxes of 2 μmole m-2 hr-1 and less calculated

  17. Methane from wood

    Energy Technology Data Exchange (ETDEWEB)

    Schulz, T. F.; Barreto, L.; Kypreos, S.; Stucki, S

    2005-07-15

    The role of wood-based energy technologies in the Swiss energy system in the long-term is examined using the energy-system Swiss MARKAL model. The Swiss MARKAL model is a 'bottom-up' energy-systems optimization model that allows a detailed representation of energy technologies. The model has been developed as a joint effort between the Energy Economics Group (EEG) at Paul Scherrer Institute PSI) and the University of Geneva and is currently used at PSI-EEG. Using the Swiss MARKAL model, this study examines the conditions under which wood-based energy technologies could play a role in the Swiss energy system, the most attractive pathways for their use and the policy measures that could support them. Given the involvement of PSI in the ECOGAS project, especial emphasis is put on the production of bio-SNG from wood via gasification and methanation of syngas and on hydrothermal gasification of woody biomass. Of specific interest as weIl is the fraction of fuel used in passenger cars that could be produced by locally harvested wood. The report is organized as follows: Section 2 presents a brief description of the MARKAL model. Section 3 describes the results of the base case scenario, which represents a plausible, 'middle-of-the-road' development of the Swiss energy system. Section 4 discusses results illustrating the conditions under which the wood-based methanation technology could become competitive in the Swiss energy market, the role of oil and gas prices, subsidies to methanation technologies and the introduction of a competing technology, namely the wood-based Fischer-Tropsch synthesis. FinaIly, section 5 outlines some conclusions from this analysis. (author)

  18. Methane from wood

    International Nuclear Information System (INIS)

    The role of wood-based energy technologies in the Swiss energy system in the long-term is examined using the energy-system Swiss MARKAL model. The Swiss MARKAL model is a 'bottom-up' energy-systems optimization model that allows a detailed representation of energy technologies. The model has been developed as a joint effort between the Energy Economics Group (EEG) at Paul Scherrer Institute PSI) and the University of Geneva and is currently used at PSI-EEG. Using the Swiss MARKAL model, this study examines the conditions under which wood-based energy technologies could play a role in the Swiss energy system, the most attractive pathways for their use and the policy measures that could support them. Given the involvement of PSI in the ECOGAS project, especial emphasis is put on the production of bio-SNG from wood via gasification and methanation of syngas and on hydrothermal gasification of woody biomass. Of specific interest as weIl is the fraction of fuel used in passenger cars that could be produced by locally harvested wood. The report is organized as follows: Section 2 presents a brief description of the MARKAL model. Section 3 describes the results of the base case scenario, which represents a plausible, 'middle-of-the-road' development of the Swiss energy system. Section 4 discusses results illustrating the conditions under which the wood-based methanation technology could become competitive in the Swiss energy market, the role of oil and gas prices, subsidies to methanation technologies and the introduction of a competing technology, namely the wood-based Fischer-Tropsch synthesis. FinaIly, section 5 outlines some conclusions from this analysis. (author)

  19. Making methane visible

    Science.gov (United States)

    Gålfalk, Magnus; Olofsson, Göran; Crill, Patrick; Bastviken, David

    2016-04-01

    Methane (CH4) is one of the most important greenhouse gases, and an important energy carrier in biogas and natural gas. Its large-scale emission patterns have been unpredictable and the source and sink distributions are poorly constrained. Remote assessment of CH4 with high sensitivity at a m2 spatial resolution would allow detailed mapping of the near-ground distribution and anthropogenic sources in landscapes but has hitherto not been possible. Here we show that CH4 gradients can be imaged on the sink attribution and scaling issues.

  20. Terrestrial plant methane production

    DEFF Research Database (Denmark)

    Mikkelsen, Teis Nørgaard; Bruhn, Dan; Møller, Ian M.;

    We evaluate all experimental work published on the phenomenon of aerobic methane (CH4) generation in terrestrial plants. We conclude that the phenomenon is true. Four stimulating factors have been observed to induce aerobic plant CH4 production, i.e. cutting injuries, increasing temperature...... into consideration other potential sources than pectin. Due to the large uncertainties related to effects of stimulating factors, genotypic responses and type of precursors, we conclude that current attempts for upscaling aerobic CH4 into a global budget is insufficient. Thus it is too early to draw the line under...

  1. A Methane Balloon Inflation Chamber

    Science.gov (United States)

    Czerwinski, Curtis J.; Cordes, Tanya J.; Franek, Joe

    2005-01-01

    The various equipments, procedure and hazards in constructing the device for inflating a methane balloon using a standard methane outlet in a laboratory are described. This device is fast, safe, inexpensive, and easy to use as compared to a hydrogen gas cylinder for inflating balloons.

  2. Instruments for Methane Gas Detection

    Directory of Open Access Journals (Sweden)

    Mr. Sibu Thomas

    2014-05-01

    Full Text Available This paper gives the explanation of different instruments for detecting methane gas in detail. This paper discusses their working principles. Methane gas detection is essentially required in the areas like in coal mines, power plant, Waste Water Treatment, Boiler Rooms etc. This paper also discusses their roles in various applications.

  3. Methane adsorption on activated carbon

    NARCIS (Netherlands)

    Perl, Andras; Koopman, Folkert; Jansen, Peter; Rooij, Marietta de; Gemert, Wim van

    2014-01-01

    Methane storage in adsorbed form is a promising way to effectively and safely store fuel for vehicular transportation or for any other potential application. In a solid adsorbent, nanometer wide pores can trap methane by van der Waals forces as high density fluid at low pressure and room temperature

  4. Instruments for Methane Gas Detection

    OpenAIRE

    Mr. Sibu Thomas; Ms. Nishi Shahnaj Haider

    2014-01-01

    This paper gives the explanation of different instruments for detecting methane gas in detail. This paper discusses their working principles. Methane gas detection is essentially required in the areas like in coal mines, power plant, Waste Water Treatment, Boiler Rooms etc. This paper also discusses their roles in various applications.

  5. Methane as a biomarker in the search for extraterrestrial life: Lessons learned from Mars analog hypersaline environments

    Science.gov (United States)

    Bebout, B.; Tazaz, A.; Kelley, C. A.; Poole, J. A.; Davila, A.; Chanton, J.

    2010-12-01

    Methane released from discrete regions on Mars, together with previous reports of methane determined with ground-based telescopes, has revived the possibility of past or even extant life near the surface on Mars, since 90% of the methane on Earth has a biological origin. This intriguing possibility is supported by the abundant evidence of large bodies of liquid water, and therefore of conditions conducive to the origin of life, early in the planet's history. The detection and analysis of methane is at the core of NASA’s strategies to search for life in the solar system, and on extrasolar planets. Because methane is also produced abiotically, it is important to generate criteria to unambiguously assess biogenicity. The stable carbon and hydrogen isotopic signature of methane, as well as its ratio to other low molecular weight hydrocarbons (the methane/(ethane + propane) ratio: C1/(C2 + C3)), has been suggested to be diagnostic for biogenic methane. We report measurements of the concentrations and stable isotopic signature of methane from hypersaline environments. We focus on hypersaline environments because spectrometers orbiting Mars have detected widespread chloride bearing deposits resembling salt flats. Other evaporitic minerals, e.g., sulfates, are also abundant in several regions, including those studied by the Mars Exploration Rovers. The presence of evaporitic minerals, together with the known evolution of the Martian climate, from warmer and wetter to cold and hyper-arid, suggest that evaporitic and hypersaline environments were common in the past. Hypersaline environments examined to date include salt ponds located in Baja California, the San Francisco Bay, and the Atacama Desert. Methane was found in gas produced both in the sediments, and in gypsum- and halite-hosted (endolithic) microbial communities. Maximum methane concentrations were as high as 40% by volume. The methane carbon isotopic (δ13C) composition showed a wide range of values, from about

  6. Microbial diversity in restored wetlands of San Francisco Bay

    Energy Technology Data Exchange (ETDEWEB)

    Theroux, Susanna [Lawrence Berkeley National Lab. (LBNL), Walnut Creek, CA (United States). Dept. of Energy Joint Genome Inst.; Hartman, Wyatt [Lawrence Berkeley National Lab. (LBNL), Walnut Creek, CA (United States). Dept. of Energy Joint Genome Inst.; He, Shaomei [Lawrence Berkeley National Lab. (LBNL), Walnut Creek, CA (United States). Dept. of Energy Joint Genome Inst.; Univ. of Wisconsin, Madison, WI (United States); Tringe, Susannah [Lawrence Berkeley National Lab. (LBNL), Walnut Creek, CA (United States). Dept. of Energy Joint Genome Inst.

    2013-12-09

    Wetland ecosystems may serve as either a source or a sink for atmospheric carbon and greenhouse gases. This delicate carbon balance is influenced by the activity of belowground microbial communities that return carbon dioxide and methane to the atmosphere. Wetland restoration efforts in the San Francisco Bay-Delta region may help to reverse land subsidence and possibly increase carbon storage in soils. However, the effects of wetland restoration on microbial communities, which mediate soil metabolic activity and carbon cycling, are poorly studied. In an effort to better understand the underlying factors which shape the balance of carbon flux in wetland soils, we targeted the microbial communities in a suite of restored and historic wetlands in the San Francisco Bay-Delta region. Using DNA and RNA sequencing, coupled with greenhouse gas monitoring, we profiled the diversity and metabolic potential of the wetland soil microbial communities along biogeochemical and wetland age gradients. Our results show relationships among geochemical gradients, availability of electron acceptors, and microbial community composition. Our study provides the first genomic glimpse into microbial populations in natural and restored wetlands of the San Francisco Bay-Delta region and provides a valuable benchmark for future studies.

  7. Hydroxylation of methane through component interactions in soluble methane monooxygenases.

    Science.gov (United States)

    Lee, Seung Jae

    2016-04-01

    Methane hydroxylation through methane monooxygenases (MMOs) is a key aspect due to their control of the carbon cycle in the ecology system and recent applications of methane gas in the field of bioenergy and bioremediation. Methanotropic bacteria perform a specific microbial conversion from methane, one of the most stable carbon compounds, to methanol through elaborate mechanisms. MMOs express particulate methane monooxygenase (pMMO) in most strains and soluble methane monooxygenase (sMMO) under copper-limited conditions. The mechanisms of MMO have been widely studied from sMMO belonging to the bacterial multicomponent monooxygenase (BMM) superfamily. This enzyme has diiron active sites where different types of hydrocarbons are oxidized through orchestrated hydroxylase, regulatory and reductase components for precise control of hydrocarbons, oxygen, protons, and electrons. Recent advances in biophysical studies, including structural and enzymatic achievements for sMMO, have explained component interactions, substrate pathways, and intermediates of sMMO. In this account, oxidation of methane in sMMO is discussed with recent progress that is critical for understanding the microbial applications of C-H activation in one-carbon substrates. PMID:27033202

  8. Methane production and methane consumption: a review of processes underlying wetland methane fluxes.

    NARCIS (Netherlands)

    Segers, R.

    1998-01-01

    Potential rates of both methane production and methane consumption vary over three orders of magnitude and their distribution is skew. These rates are weakly correlated with ecosystem type, incubation temperature, in situ aeration, latitude, depth and distance to oxic/anoxic interface. Anaerobic car

  9. 75 FR 29891 - Special Local Regulation; Maggie Fischer Memorial Great South Bay Cross Bay Swim, Great South Bay...

    Science.gov (United States)

    2010-05-28

    ... Swim, Great South Bay, NY, in the Federal Register (74 FR 32428). We did not receive any comments or... published at 74 FR 32428 on July 8, 2009, is adopted as a final rule with the following changes: PART 100... South Bay Cross Bay Swim, Great South Bay, NY AGENCY: Coast Guard, DHS. ACTION: Final rule. SUMMARY:...

  10. Bayes Multiple Decision Functions

    CERN Document Server

    Wu, Wensong

    2011-01-01

    This paper deals with the problem of simultaneously making many (M) binary decisions based on one realization of a random data matrix X. M is typically large and X will usually have M rows associated with each of the M decisions to make, but for each row the data may be low dimensional. A Bayesian decision-theoretic approach for this problem is implemented with the overall loss function being a cost-weighted linear combination of Type I and Type II loss functions. The class of loss functions considered allows for the use of the false discovery rate (FDR), false nondiscovery rate (FNR), and missed discovery rate (MDR) in assessing the decision. Through this Bayesian paradigm, the Bayes multiple decision function (BMDF) is derived and an efficient algorithm to obtain the optimal Bayes action is described. In contrast to many works in the literature where the rows of the matrix X are assumed to be stochastically independent, we allow in this paper a dependent data structure with the associations obtained through...

  11. Field Exploration of Methane Seep Near Atqasuk

    Energy Technology Data Exchange (ETDEWEB)

    Katey Walter, Dennis Witmer, Gwen Holdmann

    2008-12-31

    Methane (CH{sub 4}) in natural gas is a major energy source in the U.S., and is used extensively on Alaska's North Slope, including the oilfields in Prudhoe Bay, the community of Barrow, and the National Petroleum Reserve, Alaska (NPRA). Smaller villages, however, are dependent on imported diesel fuel for both power and heating, resulting in some of the highest energy costs in the U.S. and crippling local economies. Numerous CH{sub 4} gas seeps have been observed on wetlands near Atqasuk, Alaska (in the NPRA), and initial measurements have indicated flow rates of 3,000-5,000 ft{sup 3} day{sup -1} (60-100 kg CH{sub 4} day{sup -1}). Gas samples collected in 1996 indicated biogenic origin, although more recent sampling indicated a mixture of biogenic and thermogenic gas. In this study, we (1) quantified the amount of CH{sub 4} generated by several seeps and evaluated their potential use as an unconventional gas source for the village of Atqasuk; (2) collected gas and analyzed its composition from multiple seeps several miles apart to see if the source is the same, or if gas is being generated locally from isolated biogenic sources; and (3) assessed the potential magnitude of natural CH{sub 4} gas seeps for future use in climate change modeling.

  12. 75 FR 9886 - Methane Hydrate Advisory Committee

    Science.gov (United States)

    2010-03-04

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Methane... meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee. Federal... Methane Hydrate Advisory Committee is to provide advice on potential applications of methane hydrate...

  13. Methane emission from wetland rice fields.

    NARCIS (Netherlands)

    Denier van der Gon, H.A.C.

    1996-01-01

    Methane (CH 4 ) is an important greenhouse gas and plays a key role in tropospheric and stratospheric chemistry. Wetland rice fields are an important source of methane, accounting for approximately 20% of the global anthropogenic methane emission. Methane fluxes fro

  14. 76 FR 38020 - Safety Zone; Bay Point Fireworks, Bay Point Marina; Marblehead, OH

    Science.gov (United States)

    2011-06-29

    ... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA00 Safety Zone; Bay Point Fireworks, Bay Point Marina... transit or anchor in a portion of the Lake Erie, Bay Point Marina; Marblehead, OH between 10 p.m. and 10... Zone; Bay Point Fireworks, Bay Point Marina; Marblehead, OH. (a) Location. The following area is...

  15. Recent advances in methane activation

    Energy Technology Data Exchange (ETDEWEB)

    Huuska, M.; Kataja, K. [VTT Chemical Technology, Espoo (Finland)

    1996-12-31

    Considerable work has been done in the research and development of methane conversion technologies. Although some promising conversion processes have been demonstrated, further advances in engineering and also in the chemistry are needed before these technologies become commercial. High-temperature processes, e.g. the oxidative coupling of methane, studied thoroughly during the last 15 years, suffer from severe theoretical yield limits and poor economics. In the long term, the most promising approaches seem to be the organometallic and, especially, the biomimetic activation of methane. (author) (22 refs.)

  16. Global Methane Biogeochemistry

    Science.gov (United States)

    Reeburgh, W. S.

    2003-12-01

    Methane (CH4) has been studied as an atmospheric constituent for over 200 years. A 1776 letter from Alessandro Volta to Father Campi described the first experiments on flammable "air" released by shallow sediments in Lake Maggiore (Wolfe, 1996; King, 1992). The first quantitative measurements of CH4, both involving combustion and gravimetric determination of trapped oxidation products, were reported in French by Boussingault and Boussingault, 1864 and Gautier (1901), who reported CH4 concentrations of 10 ppmv and 0.28 ppmv (seashore) and 95 ppmv (Paris), respectively. The first modern measurements of atmospheric CH4 were the infrared absorption measurements of Migeotte (1948), who estimated an atmospheric concentration of 2.0 ppmv. Development of gas chromatography and the flame ionization detector in the 1950s led to observations of vertical CH4 distributions in the troposphere and stratosphere, and to establishment of time-series sampling programs in the late 1970s. Results from these sampling programs led to suggestions that the concentration of CH4, as that of CO2, was increasing in the atmosphere. The possible role of CH4 as a greenhouse gas stimulated further research on CH4 sources and sinks. Methane has also been of interest to microbiologists, but findings from microbiology have entered the larger context of the global CH4 budget only recently.Methane is the most abundant hydrocarbon in the atmosphere. It plays important roles in atmospheric chemistry and the radiative balance of the Earth. Stratospheric oxidation of CH4 provides a means of introducing water vapor above the tropopause. Methane reacts with atomic chlorine in the stratosphere, forming HCl, a reservoir species for chlorine. Some 90% of the CH4 entering the atmosphere is oxidized through reactions initiated by the OH radical. These reactions are discussed in more detail by Wofsy (1976) and Cicerone and Oremland (1988), and are important in controlling the oxidation state of the atmosphere

  17. Bayes multiple decision functions.

    Science.gov (United States)

    Wu, Wensong; Peña, Edsel A

    2013-01-01

    This paper deals with the problem of simultaneously making many (M) binary decisions based on one realization of a random data matrix X. M is typically large and X will usually have M rows associated with each of the M decisions to make, but for each row the data may be low dimensional. Such problems arise in many practical areas such as the biological and medical sciences, where the available dataset is from microarrays or other high-throughput technology and with the goal being to decide which among of many genes are relevant with respect to some phenotype of interest; in the engineering and reliability sciences; in astronomy; in education; and in business. A Bayesian decision-theoretic approach to this problem is implemented with the overall loss function being a cost-weighted linear combination of Type I and Type II loss functions. The class of loss functions considered allows for use of the false discovery rate (FDR), false nondiscovery rate (FNR), and missed discovery rate (MDR) in assessing the quality of decision. Through this Bayesian paradigm, the Bayes multiple decision function (BMDF) is derived and an efficient algorithm to obtain the optimal Bayes action is described. In contrast to many works in the literature where the rows of the matrix X are assumed to be stochastically independent, we allow a dependent data structure with the associations obtained through a class of frailty-induced Archimedean copulas. In particular, non-Gaussian dependent data structure, which is typical with failure-time data, can be entertained. The numerical implementation of the determination of the Bayes optimal action is facilitated through sequential Monte Carlo techniques. The theory developed could also be extended to the problem of multiple hypotheses testing, multiple classification and prediction, and high-dimensional variable selection. The proposed procedure is illustrated for the simple versus simple hypotheses setting and for the composite hypotheses setting

  18. Is methane a new therapeutic gas?

    OpenAIRE

    Liu Wenwu; Wang Dong; Tao Hengyi; Sun XueJun

    2012-01-01

    Abstract Background Methane is an attractive fuel. Biologically, methanogens in the colon can use carbon dioxide and hydrogen to produce methane as a by-product. It was previously considered that methane is not utilized by humans. However, in a recent study, results demonstrated that methane could exert anti-inflammatory effects in a dog small intestinal ischemia-reperfusion model. Point of view Actually, the bioactivity of methane has been investigated in gastrointestinal diseases, but the e...

  19. USGS Tampa Bay Pilot Study

    Science.gov (United States)

    Yates, K.K.; Cronin, T. M.; Crane, M.; Hansen, M.; Nayeghandi, A.; Swarzenski, P.; Edgar, T.; Brooks, G.R.; Suthard, B.; Hine, A.; Locker, S.; Willard, D.A.; Hastings, D.; Flower, B.; Hollander, D.; Larson, R.A.; Smith, K.

    2007-01-01

    Many of the nation's estuaries have been environmentally stressed since the turn of the 20th century and will continue to be impacted in the future. Tampa Bay, one the Gulf of Mexico's largest estuaries, exemplifies the threats that our estuaries face (EPA Report 2001, Tampa Bay Estuary Program-Comprehensive Conservation and Management Plan (TBEP-CCMP)). More than 2 million people live in the Tampa Bay watershed, and the population constitutes to grow. Demand for freshwater resources, conversion of undeveloped areas to resident and industrial uses, increases in storm-water runoff, and increased air pollution from urban and industrial sources are some of the known human activities that impact Tampa Bay. Beginning on 2001, additional anthropogenic modifications began in Tampa Bat including construction of an underwater gas pipeline and a desalinization plant, expansion of existing ports, and increased freshwater withdrawal from three major tributaries to the bay. In January of 2001, the Tampa Bay Estuary Program (TBEP) and its partners identifies a critical need for participation from the U.S. Geological Survey (USGS) in providing multidisciplinary expertise and a regional-scale, integrated science approach to address complex scientific research issue and critical scientific information gaps that are necessary for continued restoration and preservation of Tampa Bay. Tampa Bay stakeholders identified several critical science gaps for which USGS expertise was needed (Yates et al. 2001). These critical science gaps fall under four topical categories (or system components): 1) water and sediment quality, 2) hydrodynamics, 3) geology and geomorphology, and 4) ecosystem structure and function. Scientists and resource managers participating in Tampa Bay studies recognize that it is no longer sufficient to simply examine each of these estuarine system components individually, Rather, the interrelation among system components must be understood to develop conceptual and

  20. Methane LIDAR Laser Technology Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Fibertek proposes to develop laser technology intended to meet NASA's need for innovative lidar technologies for atmospheric measurements of methane. NASA and the...

  1. Miniature Airborne Methane Sensor Project

    Data.gov (United States)

    National Aeronautics and Space Administration — KalScott Engineering, and the subcontractor, Princeton University propose the development and demonstration of compact and robust methane sensor for small Unmanned...

  2. Methane Liquid Level Sensor Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Advanced Technologies Group, Inc. proposes the development of a Methane Liquid-Level Sensor, (MLS) for In-Space cryogenic storage capable of continuous monitoring...

  3. Oxygen-Methane Thruster Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Two main innovations will be developed in the Phase II effort that are fundamentally associated with our gaseous oxygen/gaseous methane RCS thruster. The first...

  4. Oxygen-Methane Thruster Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Orion Propulsion, Inc. proposes to develop an Oxygen and Methane RCS Thruster to advance the technology of alternate fuels. A successful Oxygen/CH4 RCS Thruster...

  5. Methane emissions from MBT landfills

    Energy Technology Data Exchange (ETDEWEB)

    Heyer, K.-U., E-mail: heyer@ifas-hamburg.de; Hupe, K.; Stegmann, R.

    2013-09-15

    Highlights: • Compilation of methane generation potential of mechanical biological treated (MBT) municipal solid waste. • Impacts and kinetics of landfill gas production of MBT landfills, approach with differentiated half-lives. • Methane oxidation in the waste itself and in soil covers. • Estimation of methane emissions from MBT landfills in Germany. - Abstract: Within the scope of an investigation for the German Federal Environment Agency (“Umweltbundesamt”), the basics for the estimation of the methane emissions from the landfilling of mechanically and biologically treated waste (MBT) were developed. For this purpose, topical research including monitoring results regarding the gas balance at MBT landfills was evaluated. For waste treated to the required German standards, a methane formation potential of approximately 18–24 m{sup 3} CH{sub 4}/t of total dry solids may be expected. Monitoring results from MBT landfills show that a three-phase model with differentiated half-lives describes the degradation kinetics in the best way. This is due to the fact that during the first years of disposal, the anaerobic degradation processes still proceed relatively intensively. In addition in the long term (decades), a residual gas production at a low level is still to be expected. Most of the soils used in recultivation layer systems at German landfills show a relatively high methane oxidation capacity up to 5 l CH{sub 4}/(m{sup 2} h). However, measurements at MBT disposal sites indicate that the majority of the landfill gas (in particular at non-covered areas), leaves the landfill body via preferred gas emission zones (hot spots) without significant methane oxidation. Therefore, rather low methane oxidation factors are recommended for open and temporarily covered MBT landfills. Higher methane oxidation rates can be achieved when the soil/recultivation layer is adequately designed and operated. Based on the elaborated default values, the First Order Decay (FOD

  6. A Survey of Methane Emissions from California's Natural Gas Infrastructure

    Science.gov (United States)

    Fischer, M. L.; Cui, X.; Jeong, S.; Conley, S. A.; Mehrotra, S.; Faloona, I. C.; Chen, T.; Blake, D. R.; Clements, C. B.; Lareau, N.; Lloyd, M.; Fairley, D.

    2015-12-01

    Methane emissions from natural gas infrastructure are estimated to contribute small but uncertain fractions of total natural gas consumed in California and of California's total GHG budget. Because natural gas (NG) methane is an energy resource, an economic commodity, a potential health hazard, and a potent greenhouse gas, it is important to identify and quantify and control both intentional venting, and un-intentional leakages. Here, we report results of an observational survey, measuring NG methane emissions across examples from subsectors of California's natural gas infrastructure, ranging from production and processing, to transmission and distribution, and notably including examples from the consumption subsector. At regional scales, a combination of tower and aircraft measurements are used to estimate emissions of NG methane for the San Francisco Bay Area. At facility scales, aircraft mass balance measurements are applied to estimate NG methane emissions from associated with individual petroleum production fields, NG storage facilities, and petroleum refineries. At local scales, ground-based roadway surveys are applied to place lower limits on NG emissions from aggregate leakage sources in selected urban and suburban areas, a sample of NG fueling stations, and a small number of capped gas wells. For a subset of the consumption subsector, mass balance and CH4:CO2 emission ratio measurements are used to estimate leakage from a sample of quiescent residential buildings and example operating gas appliances. In general, CH4 emissions are found to grow with the NG throughput in a given area or facility, though the observed ratio of leakage to throughput varies by more than an order of magnitude for some cases (e.g., urban areas), presumably in response to varied infrastructure type, vintage, and maintenance. Taken in sum, preliminary results of this initial survey are consistent with the commonly held assumption that total NG methane emissions from California NG

  7. Bayesian-inversion adjusted methane fluxes in Colombia and Panama

    Science.gov (United States)

    Guerrero, O. J.; Jimenez, R.; Lin, J. C.; Diskin, G. S.; Sachse, G. W.; Kort, E. A.; Kaplan, J. O.

    2011-12-01

    Methane is the second most important long lived greenhouse gas (GHG) in the Earth's atmosphere accounting for ~20% of the positive radiative forcing. The first step towards developing GHG mitigation strategies is to obtain sufficiently accurate and detailed source and sinks estimations. While ~2/3 of the global methane emissions are anthropogenic, the wetlands are the single largest source. Therefore, in many cases, wetland emissions must be included in inverse modeling calculations aimed at validating anthropogenic emission inventories from ambient air concentration measurements. High accuracy and precision methane measurements carried out in 2007 during NASA's TC4 mission revealed elevated enhancements over Colombia and Panama (up to ~500 ppbv CH4 over Uraba, Colombia). Aiming at identifying the origin of these enhancements and at validating the anthropogenic emission inventory, we used STILT to estimate methane mixing ratios based on surface fluxes at regional level over four regions of both Colombia and Panama. STILT was applied along with assimilated (GDAS and ECMWF) meteorological fields and a priori methane inventories for anthropogenic (EDGAR) and wetland emissions (Kaplan's and Matthews and Fung's). The modeled mixing ratios were compared to the TC4 mission measurements. A Bayesian inversion analysis allowed us to scale prior fluxes taking into account the uncertainty on modeled mixing ratios due to transport errors, which were calculated by comparison with meteorological observations. We obtained flux scaling factors for the whole domain of study and for each one of the four regions. Overall, the Bayesian inversion indicates that the prior anthropogenic inventory is reasonably accurate and the a priori wetland methane fluxes are overestimated almost by a factor 2. Although the posterior enhancements show a better agreement with measurements, the discrepancies cannot be reduced for 4 regions simultaneously, which points to the calculated meteorological

  8. Back Bay Wilderness area description

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This document is a description of the lands located within the Back Bay National Wildlife Refuge. Within these lands, it designates which area is suitable for...

  9. Annual report, Bristol Bay, 1955

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Commercial fishery management activities for Bristol Bay for 1955, including lists of operators, extensive statistics, descriptions of enforcement activities, and...

  10. FL BAY SPECTROUT-DIET

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Juvenile spotted seatrout and other sportfish are being monitored annually over a 6-mo period in Florida Bay to assess their abundance over time relative to...

  11. Lavaca Bay 1985-1987

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Samples were collected from October 15, 1985 through June 12, 1987 in emergent marsh and non-vegetated habitats throughout the Lavaca Bay system to characterize...

  12. Quantification of Methane Source Locations and Emissions in AN Urban Setting

    Science.gov (United States)

    Crosson, E.; Richardson, S.; Tan, S. M.; Whetstone, J.; Bova, T.; Prasad, K. R.; Davis, K. J.; Phillips, N. G.; Turnbull, J. C.; Shepson, P. B.; Cambaliza, M. L.

    2011-12-01

    The regulation of methane emissions from urban sources such as landfills and waste-water treatment facilities is currently a highly debated topic in the US and in Europe. This interest is fueled, in part, by recent measurements indicating that urban emissions are a significant source of Methane (CH4) and in fact may be substantially higher than current inventory estimates(1). As a result, developing methods for locating and quantifying emissions from urban methane sources is of great interest to industries such as landfill and wastewater treatment facility owners, watchdog groups, and the governmental agencies seeking to evaluate or enforce regulations. In an attempt to identify major methane source locations and emissions in Boston, Indianapolis, and the Bay Area, systematic measurements of CH4 concentrations and meteorology data were made at street level using a vehicle mounted cavity ringdown analyzer. A number of discrete sources were detected at concentration levels in excess of 15 times background levels. Using Gaussian plume models as well as tomographic techniques, methane source locations and emission rates will be presented. In addition, flux chamber measurements of discrete sources such as those found in natural gas leaks will also be presented. (1) Wunch, D., P.O. Wennberg, G.C. Toon, G. Keppel-Aleks, and Y.G. Yavin, Emissions of Greenhouse Gases from a North American Megacity, Geophysical Research Letters, Vol. 36, L15810, doi:10.1029/2009GL)39825, 2009.

  13. Is methane a new therapeutic gas?

    Directory of Open Access Journals (Sweden)

    Liu Wenwu

    2012-09-01

    Full Text Available Abstract Background Methane is an attractive fuel. Biologically, methanogens in the colon can use carbon dioxide and hydrogen to produce methane as a by-product. It was previously considered that methane is not utilized by humans. However, in a recent study, results demonstrated that methane could exert anti-inflammatory effects in a dog small intestinal ischemia-reperfusion model. Point of view Actually, the bioactivity of methane has been investigated in gastrointestinal diseases, but the exact mechanism underlying the anti-inflammatory effects is required to be further elucidated. Methane can cross the membrane and is easy to collect due to its abundance in natural gas. Although methane is flammable, saline rich in methane can be prepared for clinical use. These seem to be good news in application of methane as a therapeutic gas. Conclusion Several problems should be resolved before its wide application in clinical practice.

  14. Methane production from steam-exploded bamboo.

    Science.gov (United States)

    Kobayashi, Fumihisa; Take, Harumi; Asada, Chikako; Nakamura, Yoshitoshi

    2004-01-01

    To convert unutilized plant biomass into a useful energy source, methane production from bamboo was investigated using a steam explosion pretreatment. Methane could not be produced from raw bamboo but methane production was enhanced by steam explosion. The maximum amount of methane produced, i.e., about 215 ml, was obtained from 1 g of exploded bamboo at a steam pressure of 3.53 MPa and a steaming time of 5 min. A negative correlation between the amount of methane produced and the amount of Klason lignin was observed in the methane fermentation of steam-exploded bamboo.

  15. Characterization of Methane Degradation and Methane-Degrading Microbes in Alaska Coastal Water

    Energy Technology Data Exchange (ETDEWEB)

    Kirchman, David L. [Univ. of Delaware, Lewes, DE (United States)

    2012-03-29

    The net flux of methane from methane hydrates and other sources to the atmosphere depends on methane degradation as well as methane production and release from geological sources. The goal of this project was to examine methane-degrading archaea and organic carbon oxidizing bacteria in methane-rich and methane-poor sediments of the Beaufort Sea, Alaska. The Beaufort Sea system was sampled as part of a multi-disciplinary expedition (Methane in the Arctic Shelf or MIDAS) in September 2009. Microbial communities were examined by quantitative PCR analyses of 16S rRNA genes and key methane degradation genes (pmoA and mcrA involved in aerobic and anaerobic methane degradation, respectively), tag pyrosequencing of 16S rRNA genes to determine the taxonomic make up of microbes in these sediments, and sequencing of all microbial genes (metagenomes ). The taxonomic and functional make-up of the microbial communities varied with methane concentrations, with some data suggesting higher abundances of potential methane-oxidizing archaea in methane-rich sediments. Sequence analysis of PCR amplicons revealed that most of the mcrA genes were from the ANME-2 group of methane oxidizers. According to metagenomic data, genes involved in methane degradation and other degradation pathways changed with sediment depth along with sulfate and methane concentrations. Most importantly, sulfate reduction genes decreased with depth while the anaerobic methane degradation gene (mcrA) increased along with methane concentrations. The number of potential methane degradation genes (mcrA) was low and inconsistent with other data indicating the large impact of methane on these sediments. The data can be reconciled if a small number of potential methane-oxidizing archaea mediates a large flux of carbon in these sediments. Our study is the first to report metagenomic data from sediments dominated by ANME-2 archaea and is one of the few to examine the entire microbial assemblage potentially involved in

  16. Tsunami Inundation modeling for Tolaga Bay, Tokomaru Bay, Hicks Bay and Te Araroa communities

    Science.gov (United States)

    Barberopoulou, A.; Wang, X.; Power, W. L.

    2012-12-01

    We assess the tsunami hazard to four communities in Raukumara Peninsula (Northeastern region of North Island of New Zealand): Tokomaru Bay, Tolaga Bay, Hicks Bay and Te Araroa. Representative severe but realistic scenarios that could affect the Raukumara peninsula are earthquakes that rupture the interface between the Australian and Pacific plates, earthquakes that rupture faults within the overlying Australian plate or the subducting Pacific plate (location is not always well constrained). Earthquakes that rupture both the plate interface and simultaneously faults within the crust of the Australian plate are also a possibility. Tsunamis may also be caused by submarine landslides that occur near the edge of the continental shelf, but these are not considered here. For this study four scenario events were constructed, including a distant event from South America (offshore Peru), outer rise events and a thrust event in the Hikurangi region off the east coast of New Zealand. The sources are not exhaustive but representative of the types of significant events that could occur in the region and were either improved from earlier sources or derived from recent studies. Available high resolution LiDAR and RTK data were combined with topographic and LINZ data for the development of bathymetric/topographic grids. Our modelling results show that Tolaga Bay appears most vulnerable to tsunami inundation although Hicks Bay and Te Araroa are also significantly inundated in several of the scenarios. Tokomaru Bay is naturally well protected because the rapid change in elevation limits the range of inundation. The worst scenario for Tokomaru Bay was an earthquake in the Hikurangi subduction zone resulting in large flow depths, whereas for Tolaga Bay inundation is severe from most scenarios. Hicks Bay and Te Araroa get the most severe flooding from earthquakes in South America and on the Hikurangi subduction zone. Inundation extent is similar for Tolaga Bay during the Outer Rise and

  17. Methane as a climate gas

    Energy Technology Data Exchange (ETDEWEB)

    Karlsdottir, S.

    1996-03-01

    This paper was read at the workshop ``The Norwegian Climate and Ozone Research Programme`` held on 11-12 March 1996. Methane is a key component in the atmosphere where its concentration has increased rapidly since pre-industrial time. About 2/3 of it is caused by human activities. Changes in methane will affect the concentrations of other gases, and a model is a very important tool to study sensitivity due to changes in concentration of gases. The author used a three-dimensional global chemistry transport model to study the effect of changes in methane concentration on other trace gases. The model includes natural and anthropogenic emissions of NOx, CO, CH{sub 4} and non-methane hydrocarbons. Wet and dry deposition are also included. The chemical scheme in the model includes 49 compounds, 101 reactions, and 16 photolytic reactions. The trace gas concentrations are calculated every 30 min, using a quasi steady state approximation. Model calculations of three cases are reported and compared. Enhanced methane concentration will have strongest effect in remote regions. In polluted areas local chemistry will have remarked effect. The feedback was always positive. Average atmospheric lifetime calculated in the model was 7.6 years, which agrees with recent estimates based on observations. 8 refs.

  18. 77 FR 18739 - Safety Zone; Bay Swim V, Presque Isle Bay, Erie, PA

    Science.gov (United States)

    2012-03-28

    ... the January 17, 2008, issue of the Federal Register (73 FR 3316). Public Meeting We do not now plan to... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA00 Safety Zone; Bay Swim V, Presque Isle Bay, Erie, PA... is intended to restrict vessels from a portion of the Presque Island Bay during the Bay Swim...

  19. 77 FR 35860 - Safety Zone; Bay Swim V, Presque Isle Bay, Erie, PA

    Science.gov (United States)

    2012-06-15

    ..., Erie, PA in the Federal Register (77 FR 18739). We received no letters commenting on the proposed rule... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA00 Safety Zone; Bay Swim V, Presque Isle Bay, Erie, PA... restrict vessels from a portion of the Presque Island Bay during the Bay Swim V swimming event. The...

  20. 78 FR 34575 - Safety Zone; Bay Swim VI, Presque Isle Bay, Erie, PA

    Science.gov (United States)

    2013-06-10

    ... FR Federal Register NPRM Notice of Proposed Rulemaking TFR Temporary Final Rule A. Regulatory History... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA00 Safety Zone; Bay Swim VI, Presque Isle Bay, Erie, PA... portion of Presque Isle bay during the Bay Swim VI swimming event. This temporary safety zone is...

  1. Humboldt Bay, California Benthic Habitats 2009 Geoform

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Humboldt Bay is the largest estuary in California north of San Francisco Bay and represents a significant resource for the north coast region. Beginning in 2007 the...

  2. Humboldt Bay, California Benthic Habitats 2009 Biotic

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Humboldt Bay is the largest estuary in California north of San Francisco Bay and represents a significant resource for the north coast region. Beginning in 2007 the...

  3. Humboldt Bay, California Benthic Habitats 2009 Substrate

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Humboldt Bay is the largest estuary in California north of San Francisco Bay and represents a significant resource for the north coast region. Beginning in 2007 the...

  4. Humboldt Bay, California Benthic Habitats 2009 Geodatabase

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Humboldt Bay is the largest estuary in California north of San Francisco Bay and represents a significant resource for the north coast region. Beginning in 2007 the...

  5. Transformation of methane in peatland environments

    OpenAIRE

    Stępniewska, Zofia; Goraj, Weronika; Kuźniar, Agnieszka

    2014-01-01

    Wetlands and particularly peatlands are the main natural source of methane. Data indicate that 10–45% of methane emission comes from these sources. Methane emission from wetlands is the result of the balance between methanogenesis and methanotrophic processes and is actively affected by the wetland plant community composition. There are many factors affecting the balance of CH4: for instance, vegetation has a strong effect on CH4 emissions from wetland ecosystems by influencing methane ...

  6. [Advances in biomolecular machine: methane monooxygenases].

    Science.gov (United States)

    Lu, Jixue; Wang, Shizhen; Fang, Baishan

    2015-07-01

    Methane monooxygenases (MMO), regarded as "an amazing biomolecular machine", catalyze the oxidation of methane to methanol under aerobic conditions. MMO catalyze the oxidation of methane elaborately, which is a novel way to catalyze methane to methanol. Furthermore, MMO can inspire the biomolecular machine design. In this review, we introduced MMO including structure, gene and catalytic mechanism. The history and the taxonomy of MMO were also introduced. PMID:26647577

  7. Handbook methane potential; Handbok metanpotential

    Energy Technology Data Exchange (ETDEWEB)

    Carlsson, My (AnoxKaldnes AB (Sweden)); Schnurer, Anna (Swedish Univ. of Agricultural Sciences, Uppsala (Sweden))

    2011-07-15

    Before using a organic material for biogas production it is essential to evaluate the methane production potential. The methane potential is one important tool possible to use during planning of new plants but also when new materials are considered for already running biogas plants. The chemical composition of different organic material varies extensively and this will have an impact on both the degradability and the methane potential. Information about the methane potential of a specific material can sometimes be found in the literature or can be calculated after a chemical/ physical or biological characterization. Here, the BMP test (Biochemical Methane Potential) is a commonly used method. Today the BMP test is a commonly used method to determine the methane potential. Many national and international research groups, consultants as well as personal at biogas plants are using this method and there is a lot of data available in the literature from such tests. In addition there are several protocols giving guidelines on how to execute a BMP-test. The BMP-test is performed in many different ways, not always under optimized conditions, and there is a lack of information on how to interpret the obtained data. This report summarizes knowledge from the literature and the experience from a Swedish referee group, consisting of persons being active performers of BMP-tests. The report does not include a standardized protocol as the procedure can be performed in different ways depending on available equipment and on the type of material to be tested. Instead the report discusses different factors of great importance for a successful test giving reliable results. The report also summarizes important information concerning the interpretation and how to present results in order to allow comparison of data from different test.

  8. Bayes linear statistics, theory & methods

    CERN Document Server

    Goldstein, Michael

    2007-01-01

    Bayesian methods combine information available from data with any prior information available from expert knowledge. The Bayes linear approach follows this path, offering a quantitative structure for expressing beliefs, and systematic methods for adjusting these beliefs, given observational data. The methodology differs from the full Bayesian methodology in that it establishes simpler approaches to belief specification and analysis based around expectation judgements. Bayes Linear Statistics presents an authoritative account of this approach, explaining the foundations, theory, methodology, and practicalities of this important field. The text provides a thorough coverage of Bayes linear analysis, from the development of the basic language to the collection of algebraic results needed for efficient implementation, with detailed practical examples. The book covers:The importance of partial prior specifications for complex problems where it is difficult to supply a meaningful full prior probability specification...

  9. Nitrogen-fixing methane-utilizing bacteria

    NARCIS (Netherlands)

    Bont, de J.A.M.

    1976-01-01

    Methane occurs abundantly in nature. In the presence of oxygen this gas may be metabolized by bacteria that are able to use it as carbon and energy source. Several types of bacteria involved in the oxidation of methane have been described in literature. Methane-utilizing bacteria have in common that

  10. Are methane production and cattle performance related?

    Science.gov (United States)

    Methane is a product of fermentation of feed in ruminant animals. Approximately 2 -12% of the gross energy consumed by cattle is released through enteric methane production. There are three primary components that contribute to the enteric methane footprint of an animal. Those components are dry ...

  11. 40 CFR 721.4820 - Methane, bromodifluoro-.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Methane, bromodifluoro-. 721.4820... Substances § 721.4820 Methane, bromodifluoro-. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified as methane, bromodifluoro- is subject to reporting...

  12. 30 CFR 75.342 - Methane monitors.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Methane monitors. 75.342 Section 75.342 Mineral... SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.342 Methane monitors. (a)(1) MSHA approved methane monitors shall be installed on all face cutting machines, continuous miners, longwall...

  13. 78 FR 37536 - Methane Hydrate Advisory Committee

    Science.gov (United States)

    2013-06-21

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Methane... meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee. The Federal... of the Methane Hydrate Advisory Committee is to provide advice on potential applications of...

  14. 76 FR 59667 - Methane Hydrate Advisory Committee

    Science.gov (United States)

    2011-09-27

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Methane... Meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee. Federal... of the Committee: The purpose of the Methane Hydrate Advisory Committee is to provide advice...

  15. 78 FR 26337 - Methane Hydrate Advisory Committee

    Science.gov (United States)

    2013-05-06

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Methane... Meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee. The Federal... of the Methane Hydrate Advisory Committee is to provide advice on potential applications of...

  16. 77 FR 40032 - Methane Hydrate Advisory Committee

    Science.gov (United States)

    2012-07-06

    ... Methane Hydrate Advisory Committee AGENCY: Office of Fossil Energy, Department of Energy. ACTION: Notice of open meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee.... SUPPLEMENTARY INFORMATION: Purpose of the Committee: The purpose of the Methane Hydrate Advisory Committee is...

  17. 46 CFR 154.703 - Methane (LNG).

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Methane (LNG). 154.703 Section 154.703 Shipping COAST... and Temperature Control § 154.703 Methane (LNG). Unless a cargo tank carrying methane (LNG) can... system that meets § 154.702; (b) A waste heat or catalytic furnace that burns boil-off gas, and:...

  18. Microbial diversity and carbon cycling in San Francisco Bay wetlands

    Energy Technology Data Exchange (ETDEWEB)

    Theroux, Susanna [Lawrence Berkeley National Lab. (LBNL), Walnut Creek, CA (United States). Dept. of Energy Joint Genome Inst.; Hartman, Wyatt [Lawrence Berkeley National Lab. (LBNL), Walnut Creek, CA (United States). Dept. of Energy Joint Genome Inst.; He, Shaomei [Lawrence Berkeley National Lab. (LBNL), Walnut Creek, CA (United States). Dept. of Energy Joint Genome Inst.; Univ. of Wisconsin, Madison, WI (United States); Tringe, Susannah [Lawrence Berkeley National Lab. (LBNL), Walnut Creek, CA (United States). Dept. of Energy Joint Genome Inst.

    2014-03-21

    Wetland restoration efforts in San Francisco Bay aim to rebuild habitat for endangered species and provide an effective carbon storage solution, reversing land subsidence caused by a century of industrial and agricultural development. However, the benefits of carbon sequestration may be negated by increased methane production in newly constructed wetlands, making these wetlands net greenhouse gas (GHG) sources to the atmosphere. We investigated the effects of wetland restoration on below-ground microbial communities responsible for GHG cycling in a suite of historic and restored wetlands in SF Bay. Using DNA and RNA sequencing, coupled with real-time GHG monitoring, we profiled the diversity and metabolic potential of wetland soil microbial communities. The wetland soils harbor diverse communities of bacteria and archaea whose membership varies with sampling location, proximity to plant roots and sampling depth. Our results also highlight the dramatic differences in GHG production between historic and restored wetlands and allow us to link microbial community composition and GHG cycling with key environmental variables including salinity, soil carbon and plant species.

  19. Distribution and behavior of major and trace elements in Tokyo Bay, Mutsu Bay and Funka Bay marine sediments

    Energy Technology Data Exchange (ETDEWEB)

    Honda, Teruyuki [Musashi Inst. of Technology, Atomic Energy Research Laboratory, Kawasaki, Kanagawa (Japan); Kimura, Ken-ichiro [Musashi Inst. of Technology, Graduate School, Research Division in Engineering, Kawasaki, Kanagawa (Japan)

    2003-06-01

    Fourteen major and trace elements in marine sediment core samples collected from the coasts along eastern Japan, i.e. Tokyo Bay (II) (the recess), Tokyo Bay (IV) (the mouth), Mutsu Bay and Funka Bay and the Northwest Pacific basin as a comparative subject were determined by the instrumental neutron activation analysis (INAA). The sedimentation rates and sedimentary ages were calculated for the coastal sediment cores by the {sup 210}Pb method. The results obtained in this study are summarized as follows: (1) Lanthanoid abundance patterns suggested that the major origin of the sediments was terrigenous material. La*/Lu* and Ce*/La* ratios revealed that the sediments from Tokyo Bay (II) and Mutsu Bay more directly reflected the contribution from river than those of other regions. In addition, the Th/Sc ratio indicated that the coastal sediments mainly originated in the materials from the volcanic island-arcs, Japanese islands, whereas those from the Northwest Pacific mainly from the continent. (2) The correlation between the Ce/U and Th/U ratios with high correlation coefficients of 0.920 to 0.991 indicated that all the sediments from Tokyo Bay (II) and Funka Bay were in reducing conditions while at least the upper sediments from Tokyo Bay (IV) and Mutsu Bay were in oxidizing conditions. (3) It became quite obvious that the sedimentation mechanism and the sedimentation environment at Tokyo Bay (II) was different from those at Tokyo Bay (IV), since the sedimentation rate at Tokyo Bay (II) was approximately twice as large as that at Tokyo Bay (IV). The sedimentary age of the 5th layer (8{approx}10 cm in depth) from Funka Bay was calculated at approximately 1940{approx}50, which agreed with the time, 1943{approx}45 when Showa-shinzan was formed by the eruption of the Usu volcano. (author)

  20. 33 CFR 117.622 - West Bay

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false West Bay 117.622 Section 117.622 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES DRAWBRIDGE OPERATION REGULATIONS Specific Requirements Massachusetts § 117.622 West Bay The draw of the West Bay Bridge, mile...

  1. Cryptic Methane Emissions from Upland Forest Ecosystems

    Energy Technology Data Exchange (ETDEWEB)

    Megonigal, Patrick [Smithsonian Institution, Washington, DC (United States); Pitz, Scott [Johns Hopkins Univ., Baltimore, MD (United States); Smithsonian Institution, Washington, DC (United States)

    2016-04-19

    This exploratory research on Cryptic Methane Emissions from Upland Forest Ecosystems was motivated by evidence that upland ecosystems emit 36% as much methane to the atmosphere as global wetlands, yet we knew almost nothing about this source. The long-term objective was to refine Earth system models by quantifying methane emissions from upland forests, and elucidate the biogeochemical processes that govern upland methane emissions. The immediate objectives of the grant were to: (i) test the emerging paradigm that upland trees unexpectedly transpire methane, (ii) test the basic biogeochemical assumptions of an existing global model of upland methane emissions, and (iii) develop the suite of biogeochemical approaches that will be needed to advance research on upland methane emissions. We instrumented a temperate forest system in order to explore the processes that govern upland methane emissions. We demonstrated that methane is emitted from the stems of dominant tree species in temperate upland forests. Tree emissions occurred throughout the growing season, while soils adjacent to the trees consumed methane simultaneously, challenging the concept that forests are uniform sinks of methane. High frequency measurements revealed diurnal cycling in the rate of methane emissions, pointing to soils as the methane source and transpiration as the most likely pathway for methane transport. We propose the forests are smaller methane sinks than previously estimated due to stem emissions. Stem emissions may be particularly important in upland tropical forests characterized by high rainfall and transpiration, resolving differences between models and measurements. The methods we used can be effectively implemented in order to determine if the phenomenon is widespread.

  2. Coal Mine Methane in Russia

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    This paper discusses coal mine methane emissions (CMM) in the Russian Federation and the potential for their productive utilisation. It highlights specific opportunities for cost-effective reductions of CMM from oil and natural gas facilities, coal mines and landfills, with the aim of improving knowledge about effective policy approaches.

  3. Methane generation from waste materials

    Science.gov (United States)

    Samani, Zohrab A.; Hanson, Adrian T.; Macias-Corral, Maritza

    2010-03-23

    An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

  4. Methane emissions in the Netherlands

    International Nuclear Information System (INIS)

    Methane is the most important greenhouse gas after carbon dioxide. Detailed national emission estimates are needed to narrow the gap between world emission estimates and budget results from atmospheric chemistry. These estimates have to be based on sound emission factors and better extrapolation of methane measurement results. The article identifies the most important sources of methane in the Netherlands as landfills, ruminants, manure and the production, distribution and combustion of gas. It explains that emissions from landfills will decrease as a result of policies to reduce landfilling. The encouragement of increased internal use of otherwise vented gas on oil and gas production platforms and the planned extra maintenance of destribution networks should further decrease emissions. Policies to reduce milk and beef surplus and the introduction of new types of stabling and manure handling systems will reduce emissions in the agriculture sector. These measures should produce a total reduction of methane of 20% in 2000 with respect to 1990 levels. 5 refs., 3 figs., 2 tabs

  5. Methane Dynamics in Flooded Lands

    Science.gov (United States)

    Methane (CH4) is the second most important anthropogenic greenhouse gas with a heat trapping capacity 34 times greater than that of carbon dioxide on a100 year time scale. Known anthropogenic CH4 sources include livestock production, rice agriculture, landfills, and natural gas m...

  6. Insights into Methane Formation Temperatures, Biogenic Methanogenesis, and Natural Methane Emissions from Clumped Isotopes

    Science.gov (United States)

    Douglas, P. M.; Stolper, D. A.; Walter Anthony, K. M.; Dallimore, S.; Paull, C. K.; Wik, M.; Crill, P. M.; Winterdahl, M.; Smith, D. A.; Luhmann, A. J.; Ding, K.; Seyfried, W. E., Jr.; Eiler, J. M.; Ponton, C.; Sessions, A. L.

    2015-12-01

    Multiply substituted isotopologues of methane are a valuable new tool for characterizing and understanding the source of methane in different Earth environments. Here we present methane clumped isotope results from natural gas wells, hydrothermal vents, marine and lacustrine methane seeps, and culture experiments. We observe a wide range of formation temperatures for thermogenic methane. Methane samples from low-maturity reservoirs indicate formation temperatures between 102-144° C, high-maturity conventional and shale gasses indicate temperatures between 158-246 °C, and thermogenic coal gases indicate temperatures between 174-267 °C. Methane formation temperatures generally correlate positively with δ13C, and negatively with gas wetness indices. Methane samples from a set of marine hydrothermal vents indicate a formation temperature of 290-350 °C. Methane sampled from subsurface and marine biogenic sources typically indicate temperatures consistent with the formation environment (0-64° C). In contrast, freshwater biogenic methane samples, and cultures of hydrogenotrophic and methylotrophic methanogens, express low levels of isotopic clumping inconsistent with their formation temperature. These data and complementary models suggest that kinetic isotope effects, likely modulated by rates and pathways of methanogenesis, affect biogenic methane in cultures and freshwater environments. Alternatively, non-equilibrium signatures may result from mixing of methane with widely differing δD and δ13C values. Analyses of biogenic methane emissions from lakes indicate a correlation between methane flux and non-equilibrium clumped isotope fractionations in a given lake. Results from large methane seeps in Alaskan lakes confirm that some seeps emit thermogenic methane, but also indicate that other seeps emit subsurface biogenic methane or variable mixtures of biogenic and thermogenic methane. These results point to diverse sources for large Arctic methane seeps.

  7. Metagenomic evidence for reciprocal particle exchange between the mainstem estuary and lateral bay sediments of the lower Columbia River

    Directory of Open Access Journals (Sweden)

    Mariya W Smith

    2015-10-01

    Full Text Available Lateral bays of the lower Columbia River estuary are areas of enhanced water retention that influence net ecosystem metabolism through activities of their diverse microbial communities. Metagenomic characterization of sediment microbiota from three disparate sites in two brackish lateral bays (Baker and Youngs produced approximately 100 Gbp of DNA sequence data analyzed subsequently for predicted SSU rRNA and peptide-coding genes. The metagenomes were dominated by Bacteria. A large component of Eukaryota was present in Youngs Bay samples, i.e. the inner bay sediment was enriched with the invasive New Zealand mudsnail, Potamopyrgus antipodarum, known for high ammonia production. The metagenome was also highly enriched with an archaeal ammonia oxidizer closely related to Nitrosoarchaeum limnia. Combined analysis of sequences and continuous, high-resolution time series of biogeochemical data from fixed and mobile platforms revealed the importance of large-scale reciprocal particle exchanges between the mainstem estuarine water column and lateral bay sediments. Deposition of marine diatom particles in sediments near Youngs Bay mouth was associated with a dramatic enrichment of Bacteroidetes (58% of total Bacteria and corresponding genes involved in phytoplankton polysaccharide degradation. The Baker Bay sediment metagenome contained abundant Archaea, including diverse methanogens, as well as functional genes for methylotrophy and taxonomic markers for syntrophic bacteria, suggesting that active methane cycling occurs at this location. Our previous work showed enrichments of similar anaerobic taxa in particulate matter of the mainstem estuarine water column. In total, our results identify the lateral bays as both sources and sinks of biogenic particles significantly impacting microbial community composition and biogeochemical activities in the estuary.

  8. Atmospheric methane sources: Alaskan tundra bogs, an alpine fen, and a subarctic boreal marsh

    OpenAIRE

    Sebacher, Daniel I.; Harriss, Robert C.; Bartlett, Karen B.; Sebacher, Shirley M.; Grice, Shirley S.

    2011-01-01

    Methane (CH4) flux measurements from Alaskan tundra bogs, an alpine fen, and a subarctic boreal marsh were obtained at field sites ranging from Prudhoe Bay on the coast of the Arctic Ocean to the Alaskan Range south of Fairbanks during August 1984. In the tundra, average CH4 emission rates varied from 4.9 mg CH4 m-2 d-1 (moist tundra) to 119 mg CH4 m-2 d-1 (waterlogged tundra). Fluxes averaged 40 mg CH4 m-2 d-1 from wet tussock meadows in the Brooks Range and 289 mg CH4 m-2 d-1 from an alpine...

  9. Classification using Hierarchical Naive Bayes models

    DEFF Research Database (Denmark)

    Langseth, Helge; Dyhre Nielsen, Thomas

    2006-01-01

    Classification problems have a long history in the machine learning literature. One of the simplest, and yet most consistently well-performing set of classifiers is the Naïve Bayes models. However, an inherent problem with these classifiers is the assumption that all attributes used to describe......, termed Hierarchical Naïve Bayes models. Hierarchical Naïve Bayes models extend the modeling flexibility of Naïve Bayes models by introducing latent variables to relax some of the independence statements in these models. We propose a simple algorithm for learning Hierarchical Naïve Bayes models...

  10. Deep-ocean field test of methane hydrate formation from a remotely operated vehicle

    Science.gov (United States)

    Brewer, Peter G.; Orr, Franklin M., Jr.; Friederich, Gernot; Kvenvolden, Keith A.; Orange, Daniel L.; McFarlane, James; Kirkwood, William

    1997-05-01

    We have observed the process of formation of clathrate hydrates of methane in experiments conducted on the remotely operated vehicle (ROV) Ventana in the deep waters of Monterey Bay. A tank of methane gas, acrylic tubes containing seawater, and seawater plus various types of sediment were carried down on Ventana to a depth of 910 m where methane gas was injected at the base of the acrylic tubes by bubble stream. Prior calculations had shown that the local hydrographic conditions gave an upper limit of 525 m for the P-T boundary defining methane hydrate formation or dissociation at this site, and thus our experiment took place well within the stability range for this reaction to occur. Hydrate formation in free seawater occurred within minutes as a buoyant mass of translucent hydrate formed at the gas-water interface. In a coarse sand matrix the filling of the pore spaces with hydrate turned the sand column into a solidified block, which gas pressure soon lifted and ruptured. In a fine-grained black mud the gas flow carved out flow channels, the walls of which became coated and then filled with hydrate in larger discrete masses. Our experiment shows that hydrate formation is rapid in natural seawater, that sediment type strongly influences the patterns of hydrate formation, and that the use of ROV technologies permits the synthesis of large amounts of hydrate material in natural systems under a variety of conditions so that fundamental research on the stability and growth of these substances is possible.

  11. Coalbed methane reservoir boundaries and sealing mechanism

    Institute of Scientific and Technical Information of China (English)

    SU Xianbo; LIN Xiaoying; LIU Shaobo; SONG Yan

    2005-01-01

    It is important to investigate the coalbed methane reservoir boundaries for the classification, exploration, and development of the coalbed methane reservoir.Based on the investigation of the typical coalbed methane reservoirs in the world, the boundaries can be divided into four types: hydrodynamic boundary, air altered boundary,permeability boundary, and fault boundary. Hydrodynamic and air altered boundaries are ubiquitous boundaries for every coalbed methane reservoir. The four types of the fault sealing mechanism in the petroleum geological investigation (diagen- esis, clay smear, juxtaposition and cataclasis) are applied to the fault boundary of the coalbed methane reservoir. The sealing mechanism of the open fault boundary is the same with that of the hydrodynamic sealing boundary.The sealing mechanism of the permeability boundary is firstly classified into capillary pressure sealing and hydrocarbon concentration sealing. There are different controlling boundaries in coalbed methane reservoirs that are in different geological backgrounds. Therefore, the coalbed methane reservoir is diversiform.

  12. Methane clathrates in the Solar System

    CERN Document Server

    Mousis, Olivier; Holm, Nils G; Bouquet, Alexis; Waite, Jack Hunter; Geppert, Wolf Dietrich; Picaud, Sylvain; Aikawa, Yuri; Ali-Dib, Mohamad; Charlou, Jean-Luc; Rousselot, Philippe

    2015-01-01

    We review the reservoirs of methane clathrates that may exist in the different bodies of the Solar System. Methane was formed in the interstellar medium prior to having been embedded in the protosolar nebula gas phase. This molecule was subsequently trapped in clathrates that formed from crystalline water ice during the cooling of the disk and incorporated in this form in the building blocks of comets, icy bodies, and giant planets. Methane clathrates may play an important role in the evolution of planetary atmospheres. On Earth, the production of methane in clathrates is essentially biological, and these compounds are mostly found in permafrost regions or in the sediments of continental shelves. On Mars, methane would more likely derive from hydrothermal reactions with olivine-rich material. If they do exist, martian methane clathrates would be stable only at depth in the cryosphere and sporadically release some methane into the atmosphere via mechanisms that remain to be determined.

  13. Backscatter imagery in Jobos Bay

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a 1x1 meter resolution backscatter mosaic of Jobos Bay, Puerto Rico (in NAD83 UTM 19 North). The backscatter values are in relative 8-bit (0 –...

  14. Methane clathrates in the solar system.

    Science.gov (United States)

    Mousis, Olivier; Chassefière, Eric; Holm, Nils G; Bouquet, Alexis; Waite, Jack Hunter; Geppert, Wolf Dietrich; Picaud, Sylvain; Aikawa, Yuri; Ali-Dib, Mohamad; Charlou, Jean-Luc; Rousselot, Philippe

    2015-04-01

    We review the reservoirs of methane clathrates that may exist in the different bodies of the Solar System. Methane was formed in the interstellar medium prior to having been embedded in the protosolar nebula gas phase. This molecule was subsequently trapped in clathrates that formed from crystalline water ice during the cooling of the disk and incorporated in this form into the building blocks of comets, icy bodies, and giant planets. Methane clathrates may play an important role in the evolution of planetary atmospheres. On Earth, the production of methane in clathrates is essentially biological, and these compounds are mostly found in permafrost regions or in the sediments of continental shelves. On Mars, methane would more likely derive from hydrothermal reactions with olivine-rich material. If they do exist, martian methane clathrates would be stable only at depth in the cryosphere and sporadically release some methane into the atmosphere via mechanisms that remain to be determined. In the case of Titan, most of its methane probably originates from the protosolar nebula, where it would have been trapped in the clathrates agglomerated by the satellite's building blocks. Methane clathrates are still believed to play an important role in the present state of Titan. Their presence is invoked in the satellite's subsurface as a means of replenishing its atmosphere with methane via outgassing episodes. The internal oceans of Enceladus and Europa also provide appropriate thermodynamic conditions that allow formation of methane clathrates. In turn, these clathrates might influence the composition of these liquid reservoirs. Finally, comets and Kuiper Belt Objects might have formed from the agglomeration of clathrates and pure ices in the nebula. The methane observed in comets would then result from the destabilization of clathrate layers in the nuclei concurrent with their approach to perihelion. Thermodynamic equilibrium calculations show that methane-rich clathrate

  15. Methane clathrates in the solar system.

    Science.gov (United States)

    Mousis, Olivier; Chassefière, Eric; Holm, Nils G; Bouquet, Alexis; Waite, Jack Hunter; Geppert, Wolf Dietrich; Picaud, Sylvain; Aikawa, Yuri; Ali-Dib, Mohamad; Charlou, Jean-Luc; Rousselot, Philippe

    2015-04-01

    We review the reservoirs of methane clathrates that may exist in the different bodies of the Solar System. Methane was formed in the interstellar medium prior to having been embedded in the protosolar nebula gas phase. This molecule was subsequently trapped in clathrates that formed from crystalline water ice during the cooling of the disk and incorporated in this form into the building blocks of comets, icy bodies, and giant planets. Methane clathrates may play an important role in the evolution of planetary atmospheres. On Earth, the production of methane in clathrates is essentially biological, and these compounds are mostly found in permafrost regions or in the sediments of continental shelves. On Mars, methane would more likely derive from hydrothermal reactions with olivine-rich material. If they do exist, martian methane clathrates would be stable only at depth in the cryosphere and sporadically release some methane into the atmosphere via mechanisms that remain to be determined. In the case of Titan, most of its methane probably originates from the protosolar nebula, where it would have been trapped in the clathrates agglomerated by the satellite's building blocks. Methane clathrates are still believed to play an important role in the present state of Titan. Their presence is invoked in the satellite's subsurface as a means of replenishing its atmosphere with methane via outgassing episodes. The internal oceans of Enceladus and Europa also provide appropriate thermodynamic conditions that allow formation of methane clathrates. In turn, these clathrates might influence the composition of these liquid reservoirs. Finally, comets and Kuiper Belt Objects might have formed from the agglomeration of clathrates and pure ices in the nebula. The methane observed in comets would then result from the destabilization of clathrate layers in the nuclei concurrent with their approach to perihelion. Thermodynamic equilibrium calculations show that methane-rich clathrate

  16. Response of the Black Sea methane budget to massive short-term submarine inputs of methane

    DEFF Research Database (Denmark)

    Schmale, O.; Haeckel, M.; McGinnis, D. F.

    2011-01-01

    -water mud volcanoes or submarine landslides at intermediate water depths) on the water column methane distribution and the resulting methane emission to the atmosphere. Our non-steady state simulations predict that these inputs will be effectively buffered by intense microbial methane consumption...... and that the upward flux of methane is strongly hampered by the pronounced density stratification of the Black Sea water column. For instance, an assumed input of methane of 179 Tg CH(4) d(-1) (equivalent to the amount of methane released by 1000 mud volcano eruptions) at a water depth of 700m will only marginally...

  17. W.R. Grace: Plant Uses Six Sigma Methodology and Traditional Heat Balance Analysis to Identify Energy Conservation Opportunities at Curtis Bay Works

    Energy Technology Data Exchange (ETDEWEB)

    None

    2003-12-01

    The plant-wide energy assessment at W. R. Grace's Curtis Bay Works helped identify four projects with combined potential savings of $840,000 per year. A separate, unique project that would partner W. R. Grace with the City of Baltimore to recover and use landfill gas (methane) to cogenerate steam and electricity was also identified during the assessment. If implemented, the project would recover gas from the landfill to replace 40% of the electricity and 65% of the fuel currently required to produce steam at Curtis Bay Works. Annual savings are estimated at $900,000 to $1.2 million.

  18. Attributing Atmospheric Methane to Anthropogenic Emission Sources.

    Science.gov (United States)

    Allen, David

    2016-07-19

    Methane is a greenhouse gas, and increases in atmospheric methane concentration over the past 250 years have driven increased radiative forcing of the atmosphere. Increases in atmospheric methane concentration since 1750 account for approximately 17% of increases in radiative forcing of the atmosphere, and that percentage increases by approximately a factor of 2 if the effects of the greenhouse gases produced by the atmospheric reactions of methane are included in the assessment. Because of the role of methane emissions in radiative forcing of the atmosphere, the identification and quantification of sources of methane emissions is receiving increased scientific attention. Methane emission sources include biogenic, geogenic, and anthropogenic sources; the largest anthropogenic sources are natural gas and petroleum systems, enteric fermentation (livestock), landfills, coal mining, and manure management. While these source categories are well-known, there is significant uncertainty in the relative magnitudes of methane emissions from the various source categories. Further, the overall magnitude of methane emissions from all anthropogenic sources is actively debated, with estimates based on source sampling extrapolated to regional or national scale ("bottom-up analyses") differing from estimates that infer emissions based on ambient data ("top-down analyses") by 50% or more. To address the important problem of attribution of methane to specific sources, a variety of new analytical methods are being employed, including high time resolution and highly sensitive measurements of methane, methane isotopes, and other chemical species frequently associated with methane emissions, such as ethane. This Account describes the use of some of these emerging measurements, in both top-down and bottom-up methane emission studies. In addition, this Account describes how data from these new analytical methods can be used in conjunction with chemical mass balance (CMB) methods for source

  19. Attributing Atmospheric Methane to Anthropogenic Emission Sources.

    Science.gov (United States)

    Allen, David

    2016-07-19

    Methane is a greenhouse gas, and increases in atmospheric methane concentration over the past 250 years have driven increased radiative forcing of the atmosphere. Increases in atmospheric methane concentration since 1750 account for approximately 17% of increases in radiative forcing of the atmosphere, and that percentage increases by approximately a factor of 2 if the effects of the greenhouse gases produced by the atmospheric reactions of methane are included in the assessment. Because of the role of methane emissions in radiative forcing of the atmosphere, the identification and quantification of sources of methane emissions is receiving increased scientific attention. Methane emission sources include biogenic, geogenic, and anthropogenic sources; the largest anthropogenic sources are natural gas and petroleum systems, enteric fermentation (livestock), landfills, coal mining, and manure management. While these source categories are well-known, there is significant uncertainty in the relative magnitudes of methane emissions from the various source categories. Further, the overall magnitude of methane emissions from all anthropogenic sources is actively debated, with estimates based on source sampling extrapolated to regional or national scale ("bottom-up analyses") differing from estimates that infer emissions based on ambient data ("top-down analyses") by 50% or more. To address the important problem of attribution of methane to specific sources, a variety of new analytical methods are being employed, including high time resolution and highly sensitive measurements of methane, methane isotopes, and other chemical species frequently associated with methane emissions, such as ethane. This Account describes the use of some of these emerging measurements, in both top-down and bottom-up methane emission studies. In addition, this Account describes how data from these new analytical methods can be used in conjunction with chemical mass balance (CMB) methods for source

  20. Photocatalytic conversion of methane to methanol

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, C.E.; Noceti, R.P.; D`Este, J.R. [Pittsburgh Energy Technology Center, PA (United States)

    1995-12-31

    A long-term goal of our research group is the exploration of novel pathways for the direct oxidation of methane to liquid fuels, chemicals, and intermediates. The use of three relatively abundant and inexpensive reactants, light, water, and methane, to produce methanol is attractive. The products of reaction, methanol and hydrogen, are both commercially desirable, methanol being used as is or converted to a variety of other chemicals, and the hydrogen could be utilized in petroleum and/or chemical manufacturing. Methane is produced as a by-product of coal gasification. Depending upon reactor design and operating conditions, up to 18% of total gasifier product may be methane. In addition, there are vast proven reserves of geologic methane in the world. Unfortunately, a large fraction of these reserves are in regions where there is little local demand for methane and it is not economically feasible to transport it to a market. There is a global research effort under way in academia, industry, and government to find methods to convert methane to useful, more readily transportable and storable materials. Methanol, the initial product of methane oxidation, is a desirable product of conversion because it retains much of the original energy of the methane while satisfying transportation and storage requirements. Investigation of direct conversion of methane to transportation fuels has been an ongoing effort at PETC for over 10 years. One of the current areas of research is the conversion of methane to methanol, under mild conditions, using light, water, and a semiconductor photocatalyst. The use of three relatively abundant and inexpensive reactants, light, water, and methane, to produce methanol, is attractive. Research in the laboratory is directed toward applying the techniques developed for the photocatalytic splitting of the water and the photochemical conversion of methane.

  1. Enteric Methane Emission from Pigs

    DEFF Research Database (Denmark)

    Jørgensen, Henry; Theil, Peter Kappel; Knudsen, Knud Erik Bach

    2011-01-01

    per kg meat produced is increased (Fernández et al. 1983; Lekule et al. 1990). The present chapter will summarise our current knowledge concerning dietary and enteric fermentation that may influence the methane (CH4) emission in pigs. Enteric fermentation is the digestive process by which...... of the studies were specifically designed to investigate dietary or enteric pig factors that may influence the CH4 emission. The data used in the chapter is based on Danish pigs with reference to other European studies. In a global context Denmark’s 12 million pigs (FAOSTAT, 2009) contribute with 1.......3 % of the worlds pig population. The main number of pigs is in Asia (59.6 %) where the main pig population stay in China (47.8 % of the worlds pig population). The objective of the chapter is therefore: To obtain a general overview of the pigs’ contribution to methane emission. Where is the pigs’ enteric gas...

  2. Nelson River and Hudson Bay

    Science.gov (United States)

    2002-01-01

    Rivers that empty into large bodies of water can have a significant impact on the thawing of nearshore winter ice. This true-color Moderate Resolution Imaging Spectroradiometer (MODIS) image from May 18, 2001, shows the Nelson River emptying spring runoff from the Manitoba province to the south into the southwestern corner of Canada's Hudson Bay. The warmer waters from more southern latitudes hasten melting of ice near the shore, though some still remained, perhaps because in shallow coastal waters, the ice could have been anchored to the bottom. High volumes of sediment in the runoff turned the inflow brown, and the rim of the retreating ice has taken on a dirty appearance even far to the east of the river's entrance into the Bay. The sediment would have further hastened the melting of the ice because its darker color would have absorbed more solar radiation than cleaner, whiter ice. Image courtesy Jacques Descloitres, MODIS Land Rapid Response Team at NASA GSFC

  3. Factors Affecting Methane Emission from Rice Paddies

    Institute of Scientific and Technical Information of China (English)

    于心科; 王卫东; 等

    1995-01-01

    A comparative study of rice paddies and the uncovered water field in Taoyuan(Hunan) showed that methane emission from rice-vegetated paddy fields in 1993 was different from that in 1992(I,e,lower in rates and irregular in pattern).Climate has obvious influence on methane emission .And ebullition made a considerable contribution to the total flux of methane emission from rice paddies (45%).This implies that the intensification of paddy cultivation of rice might not be,as was proposed,the main con-tributor to the observed gradual increasing of atmospheric methane.24-hour automatic measurements of atmospheric temperature,air temperature and methane concentration in the static sampling boxes revealed that temperature,in addition to fertilization and irrigation style,is one of the most important factors that control the emission of methane from rice paddies.

  4. TOTAL COLUMN METHANE RETRIEVALS USING THE TROPOSPHERIC INFRARED MAPPING SPECTROMETER OVER SUNGLINT

    Directory of Open Access Journals (Sweden)

    N. Larsen

    2012-07-01

    Full Text Available Because it is a greenhouse gas, the detection of methane concentrations is a global issue. Additionally, the presence of methane is indicative of potential valuable petroleum and natural gas deposits. Therefore methane seep detection is useful for petroleum exploration around the world. The detection of methane, and other absorbing gases, over water is an issue for passive systems because one is seeking to detect an absorbing gas over an absorbing surface. The solution to this dilemma is to use the sun/sensor geometry for sun glint off of water to measure the absorbing gas over a reflecting surface, and therefore significantly increase the signal to noise of the measurement being taken. In September of 2010 Lockheed Martin performed a proof of concept by demonstrating from an airship over San Francisco Bay the capability of the Tropospheric Infrared Mapping Spectrometer's (TIMS hyper spectral sensor to passively measure methane, CO, and water vapor over sunglint water. The Lockheed Martin prototype TIMS sensor system is a hyper spectral grating spectrometer instrument that operates in the 2.3 micron spectral region at 0.25 cm-1 resolution. The Lockheed Martin retrieval algorithm developed applies the kCARTA (kCompressed Atmospheric Radiative Transfer Algorithm with Jacobians, with the HITRAN 2008 lineshape parameters, to retrieve the total column amount of atmospheric species along with the calibrated TIMS sensors radiometric input. A cell with known amount of methane was placed into the input to the TIMS to simulate atmospheric enhancements near the water surface. The amount in the cell was retrieved well within the uncertainty of 1% of the amount in the cell. Multi frame retrievals on data in which the cell was not placed into the input beam demonstrated 1% precision. In addition, in situ surface measurements were done over a landfill park, where measurements of methane were taken over known hotspots. This research allows for the future

  5. International opportunities to reduce coal mine methane

    International Nuclear Information System (INIS)

    This paper discusses opportunities to increase the recovery and use of methane from coal mines throughout the world. It presents information on resource estimates in Poland, Czechoslovakia, Russia, Ukraine and the People's Republic of China and discusses coalbed methane's role in helping these countries meet their energy and environmental goals. Existing barrier to expanded methane recovery and utilization at coal mines and some possible activities to overcome these barriers are also discussed

  6. Methane Pyrolysis and Disposing Off Resulting Carbon

    Science.gov (United States)

    Sharma, P. K.; Rapp, D.; Rahotgi, N. K.

    1999-01-01

    Sabatier/Electrolysis (S/E) is a leading process for producing methane and oxygen for application to Mars ISPP. One significant problem with this process is that it produces an excess of methane for combustion with the amount of oxygen that is produced. Therefore, one must discard roughly half of the methane to obtain the proper stoichiometric methane/oxygen mixture for ascent from Mars. This is wasteful of hydrogen, which must be brought from Earth and is difficult to transport to Mars and store on Mars. To reduced the problem of transporting hydrogen to Mars, the S/E process can be augmented by another process which reduces overall hydrogen requirement. Three conceptual approaches for doing this are (1) recover hydrogen from the excess methane produced by the S/E process, (2) convert the methane to a higher hydrocarbon or other organic with a lower H/C ratio than methane, and (3) use a separate process (such as zirconia or reverse water gas shift reaction) to produce additional oxygen, thus utilizing all the methane produced by the Sabatier process. We report our results here on recovering hydrogen from the excess methane using pyrolysis of methane. Pyrolysis has the advantage that it produces almost pure hydrogen, and any unreacted methane can pass through the S/E process reactor. It has the disadvantage that disposing of the carbon produced by pyrolysis presents difficulties. Hydrogen may be obtained from methane by pyrolysis in the temperature range 10000-12000C. The main reaction products are hydrogen and carbon, though very small amounts of higher hydrocarbons, including aromatic hydrocarbons are formed. The conversion efficiency is about 95% at 12000C. One needs to distinguish between thermodynamic equilibrium conversion and conversion limited by kinetics in a finite reactor.

  7. Formation temperatures of thermogenic and biogenic methane

    OpenAIRE

    Stolper, D. A.; Lawson, M.; Davis, C. L.; Ferreira, A. A.; Santos Neto, E. V.; Ellis, G.S.; Lewan, M.D.; Martini, A. M.; Tang, Y.; Schoell, M.; Sessions, A.L.; Eiler, J. M.

    2014-01-01

    Methane is an important greenhouse gas and energy resource generated dominantly by methanogens at low temperatures and through the breakdown of organic molecules at high temperatures. However, methane-formation temperatures in nature are often poorly constrained. We measured formation temperatures of thermogenic and biogenic methane using a “clumped isotope” technique. Thermogenic gases yield formation temperatures between 157° and 221°C, within the nominal gas window, and biogenic gases yiel...

  8. Methane storage in porous activated carbons

    OpenAIRE

    Perl, András; Gemert, Wim van

    2014-01-01

    Locally produced methane, - either as biomethane or power-to-gas product, has to be stored to provide a reliable gas source for the fluctuating demand of any local gas distribution network. Additionally, methane is a prominent transportation fuel but its suitability for vehicular application depends on the ability to store an adequate amount in the onboard fuel tank. Adsorption in porous materials could enable a simple, safe and cost-effective method for storing methane at ambient temperature...

  9. Dangerous effects of methane gas in atmosphere

    OpenAIRE

    Mohajan, Haradhan

    2011-01-01

    This paper discusses the effects of methane gas which causes sever global warming in the atmosphere. Global warming becomes main issue in economics in the 21st century. Because global climate change becomes more dangerous and every nation realized that this is due to greenhouse gas emissions. Methane is dangerous greenhouse gas, since it is 21 times more global warming potential than carbon dioxide. All the nations talk about the reduction of only carbon dioxide and no nation stress on methan...

  10. Acute Respiratory Distress Due to Methane Inhalation

    OpenAIRE

    Jo, Jun Yeon; Kwon, Yong Sik; Lee, Jin Wook; Park, Jae Seok; Rho, Byung Hak; Choi, Won-Il

    2013-01-01

    Inhalation of toxic gases can lead to pneumonitis. It has been known that methane gas intoxication causes loss of consciousness or asphyxia. There is, however, a paucity of information about acute pulmonary toxicity from methane gas inhalation. A 21-year-old man was presented with respiratory distress after an accidental exposure to methane gas for one minute. He came in with a drowsy mentality and hypoxemia. Mechanical ventilation was applied immediately. The patient's symptoms and chest rad...

  11. Simulation of Pollutant Transport in Marmaris Bay

    Institute of Scientific and Technical Information of China (English)

    Lale BALAS

    2001-01-01

    The circulation pattern and the pollutant transport in the Marmaris Bay are simulated by the developed three-dimensional baroclinic model. The Marmaris Bay is located at the Mediterranean Sea coast of Turkey. Since the sp ring tidal range is typically 20~30 cm, the dominant forcing for the circulation and water exchange is due to the wind action. In the Marmaris Bay, there is sea outfall discharging directly into the bay, and that threats the bay water quality significantly. The current patterns in the vicinity of the outfall have been observed by tracking drogues which are moved by currents at different water depths. In the simulations of pollutant transport, the coliforms-counts is used as the tracer.The model provides realistic predictions for the circulation and pollutant transport in the Marmaris Bay. The transport model component predictions well agree with the results of a laboratory model study.

  12. Lithospheric Architecture Beneath Hudson Bay

    Science.gov (United States)

    Porritt, R. W.; Miller, M. S.; Darbyshire, F. A.

    2015-12-01

    Hudson Bay overlies some of the thickest Precambrian lithosphere on Earth, whose internal structures contain important clues to the earliest workings of plate formation. The terminal collision, the Trans-Hudson Orogen, brought together the Western Churchill craton to the northwest and the Superior craton to the southeast. These two Archean cratons along with the Paleo-Proterozoic Trans-Hudson internides, form the core of the North American craton. We use S to P converted wave imaging and absolute shear velocity information from a joint inversion of P to S receiver functions, new ambient noise derived phase velocities, and teleseismic phase velocities to investigate this region and determine both the thickness of the lithosphere and the presence of internal discontinuities. The lithosphere under central Hudson Bay approaches 􏰂350 km thick but is thinner (􏰂200-250 km) around the periphery of the Bay. Furthermore, the amplitude of the lithosphere-asthenosphere boundary (LAB) conversion from the S receiver functions is unusually large for a craton, suggesting a large thermal contrast across the LAB, which we interpret as direct evidence of the thermal insulation effect of continents on the asthenosphere. Within the lithosphere, midlithospheric discontinuities, significantly shallower than the base of the lithosphere, are often imaged, suggesting the mechanisms that form these layers are common. Lacking time-history information, we infer that these discontinuities reflect reactivation of formation structures during deformation of the craton.

  13. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    Energy Technology Data Exchange (ETDEWEB)

    Donn McGuire; Steve Runyon; Richard Sigal; Bill Liddell; Thomas Williams; George Moridis

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. Hot Ice No. 1 was planned to test the Ugnu and West Sak sequences for gas hydrates and a concomitant free gas accumulation on Anadarko's 100% working interest acreage in section 30 of Township 9N, Range 8E of the Harrison Bay quadrangle of the North Slope of Alaska. The Ugnu and West Sak intervals are favorably positioned in the hydrate-stability zone over an area extending from Anadarko's acreage westward to the vicinity of the aforementioned gas-hydrate occurrences. This suggests that a large, north-to-south trending gas-hydrate accumulation may exist in that area. The presence of gas shows in the Ugnu and West Sak reservoirs in wells situated eastward and down dip of the Hot Ice location indicate that a free-gas accumulation may be trapped by gas hydrates. The Hot Ice No. 1 well was designed to core from the surface to the base of the West Sak interval using the

  14. MERLIN: a space-based methane monitor

    Science.gov (United States)

    Stephan, C.; Alpers, M.; Millet, B.; Ehret, G.; Flamant, P.; Deniel, C.

    2011-10-01

    Methane is a powerful greenhouse gas. The radiative forcing caused by methane contributes significantly to the warming of the atmosphere. To better understand the complex global Methane Cycle, it is necessary to apply space-based measurements techniques in order to obtain global coverage at high precision The Methane Remote Sensing Lidar Mission (MERLIN) is a joint French-German cooperation on a micro satellite mission for space-based measurement of spatial and temporal gradients of atmospheric methane columns on a global scale. MERLIN will be the first Integrated Path Differential Absorption LIDAR for methane monitoring from space. In contrast to passive methane missions, the LIDAR instrument allows to retrieve methane fluxes at all-latitudes, allseasons and during night as it is not relying on sunlight. First scientific studies show a substantial reduction of the prior methane flux uncertainties in key observational regions when using synthetic MERLIN observations in the flux inversion experiments. Furthermore, MERLIN observations can help to quantify and verify in scientific credible way national emission reduction scenarios as formulated in the Kyoto protocol. This paper reports on the present status of MERLIN and gives an overview on the joint mission concept with the German LIDAR on the French satellite platform MYRIADE.

  15. Microchannel Methanation Reactors Using Nanofabricated Catalysts Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Makel Engineering, Inc. (MEI) and the Pennsylvania State University (Penn State) propose to develop and demonstrate a microchannel methanation reactor based on...

  16. NOVEL SPECTRUM ABSORPTION OPTICAL FIBER METHANE SENSOR

    Institute of Scientific and Technical Information of China (English)

    Wang Shutao; Che Rensheng

    2005-01-01

    Based on spectrum principle and analyzing the infrared absorption spectrum of methane, a kind of optical fiber methane gas sensor and its system are developed. DFBLD(Distributed feedback laser diode) in 1 300 nm waveband is used as illuminant and phase-detecting technology is used to carry out harmonic wave detecting the concentration of methane. The sensitivity can arrive at 10-5.Experiments results show that the performance targets of the sensor such as sensitivity can basically satisfy the requests of methane detection.

  17. San Francisco and Bay Area, CA, USA

    Science.gov (United States)

    1991-01-01

    Although clouds obscure part of the city of San Francisco and the mouth of the Bay (37.5N, 122.0W), many cultural and natural features in the immediate vicinity are obvious. The Bay Bridge which was damaged in the 1989 earthquake, Candlestick Park, San Mateo and Dumbarton Bridges as well as the various colored settling ponds rimming the south end of the Bay, the San Andreas and Calaveras faults and many of the major highways can be seen.

  18. 33 CFR 80.1114 - San Pedro Bay-Anaheim Bay, CA.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false San Pedro Bay-Anaheim Bay, CA. 80.1114 Section 80.1114 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Coast § 80.1114 San Pedro Bay—Anaheim Bay, CA. (a) A line drawn across the...

  19. 77 FR 70891 - Safety Zone; Bay Bridge Construction, San Francisco Bay, San Francisco, CA

    Science.gov (United States)

    2012-11-28

    ... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA00 Safety Zone; Bay Bridge Construction, San Francisco Bay..., CA in support of the Bay Bridge Construction Safety Zone from November 1, 2012 through July 31, 2013...: Table of Acronyms DHS Department of Homeland Security FR Federal Register NPRM Notice of...

  20. Diel methane emission patterns from Scirpus lacustris and Phragmites australis

    NARCIS (Netherlands)

    Van der Nat, J.W.A.; Middelburg, J.J.; Van Meteren, D.; Wielemaker, A.

    1998-01-01

    In mature Phragmites australis and Scirpus lacustris vegetated sediment methane was emitted almost exclusively by plant- mediated transport, whereas in unvegetated, but otherwise identical sediment, methane was emitted almost exclusively by ebullition. Diel variations in methane emission, with highe

  1. Quantifying Low Temperature Production of Methane on Mars

    Science.gov (United States)

    Schwenzer, S. P.

    2011-03-01

    Potential anorganic production of methane from a range of martian rock compositions is quantified and compared to the concentration of methane observed on Mars. Impact-craters are suggested as potential sites of methane formation and storage.

  2. Chesapeake Bay Program Water Quality Database

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Chesapeake Information Management System (CIMS), designed in 1996, is an integrated, accessible information management system for the Chesapeake Bay Region....

  3. Polychlorinated biphenyls (PCBs) in San Francisco Bay.

    Science.gov (United States)

    Davis, J A; Hetzel, F; Oram, J J; McKee, L J

    2007-09-01

    San Francisco Bay is facing a legacy of polychlorinated biphenyls (PCBs) spread widely across the land surface of the watershed, mixed deep into the sediment of the Bay, and contaminating the Bay food web to a degree that poses health risks to humans and wildlife. In response to this persistent problem, water quality managers are establishing a PCB total maximum daily load (TMDL) and implementation plan to accelerate the recovery of the Bay from decades of PCB contamination. This article provides a review of progress made over the past 15 years in managing PCBs and understanding their sources, pathways, fate, and effects in the Bay, and highlights remaining information needs that should be addressed in the next 10 years. The phaseout of PCBs during the 1970s and the 1979 federal ban on sale and production led to gradual declines from the 1970s to the present. However, 25 years after the ban, PCB concentrations in some Bay sport fish today are still more than ten times higher than the threshold of concern for human health. Without further management action it appears that the general recovery of the Bay from PCB contamination will take many more decades. PCB concentrations in sport fish were, along with mercury, a primary cause of a consumption advisory for the Bay and the consequent classification of the Bay as an impaired water body. Several sources of information indicate that PCB concentrations in the Bay may also be high enough to adversely affect wildlife, including rare and endangered species. The greater than 90% reduction in food web contamination needed to meet the targets for protection of human health would likely also generally eliminate risks to wildlife. PCB contamination in the Bay is primarily associated with industrial areas along the shoreline and in local watersheds. Strong spatial gradients in PCB concentrations persist decades after the release of these chemicals to Bay Area waterways. Through the TMDL process, attention is being more sharply

  4. PHYSICAL SIMULATION AND ANALYSIS OF METHANE TRANSPORT IN COAL SEAM

    Institute of Scientific and Technical Information of China (English)

    罗新荣; 俞启香

    1994-01-01

    This paper studies the effect of ground stress, pore gas pressure and adsorbed methane on methane transport in coal seam, and researches into the applicability of Darcy's law to methane transport. The additional expansion stress of coal induced by adsorbed methane is measured. The paper establishes the constitutive equation of methane transport, taking ground stress, pore gas pressure and Klinkcnburg's effects into considcration, The features of methane transport under the condition of given stress or strain have been analyzed.

  5. Off limits: sulfate below the sulfate-methane transition

    Science.gov (United States)

    Brunner, Benjamin; Arnold, Gail; Røy, Hans; Müller, Inigo; Jørgensen, Bo

    2016-07-01

    One of the most intriguing recent discoveries in biogeochemistry is the ubiquity of cryptic sulfur cycling. From subglacial lakes to marine oxygen minimum zones, and in marine sediments, cryptic sulfur cycling - the simultaneous sulfate consumption and production - has been observed. Though this process does not leave an imprint in the sulfur budget of the ambient environment - thus the term cryptic - it may have a massive impact on other element cycles and fundamentally change our understanding of biogeochemical processes in the subsurface. Classically, the sulfate-methane transition (SMT) in marine sediments is considered to be the boundary that delimits sulfate reduction from methanogenesis as the predominant terminal pathway of organic matter mineralization. Two sediment cores from Aarhus Bay, Denmark reveal the constant presence of sulfate (generally 0.1 to 0.2 mM) below the SMT. The sulfur and oxygen isotope signature of this deep sulfate (34S = 18.9‰, 18O = 7.7‰) was close to the isotope signature of bottom-seawater collected from the sampling site (34S = 19.8‰, 18O = 7.3‰). In one of the cores, oxygen isotope values of sulfate at the transition from the base of the SMT to the deep sulfate pool (18O = 4.5‰ to 6.8‰) were distinctly lighter than the deep sulfate pool. Our findings are consistent with a scenario where sulfate enriched in 34S and 18O is removed at the base of the SMT and replaced with isotopically light sulfate below. Here, we explore scenarios that explain this observation, ranging from sampling artifacts, such as contamination with seawater or auto-oxidation of sulfide - to the potential of sulfate generation in a section of the sediment column where sulfate is expected to be absent which enables reductive sulfur cycling, creating the conditions under which sulfate respiration can persist in the methanic zone.

  6. Plasma catalytic reforming of methane

    Energy Technology Data Exchange (ETDEWEB)

    Bromberg, L.; Cohn, D.R.; Rabinovich, A. [Massachusetts Inst. of Technology, Cambridge, MA (United States). Plasma Science and Fusion Center; Alexeev, N. [Russian Academy of Sciences, Moscow (Russian Federation). Baikov Inst. of Metallurgy

    1998-08-01

    Thermal plasma technology can be efficiently used in the production of hydrogen and hydrogen-rich gases from methane and a variety of fuels. This paper describes progress in plasma reforming experiments and calculations of high temperature conversion of methane using heterogeneous processes. The thermal plasma is a highly energetic state of matter that is characterized by extremely high temperatures (several thousand degrees Celsius) and high degree of dissociation and substantial degree of ionization. The high temperatures accelerate the reactions involved in the reforming process. Hydrogen-rich gas (50% H{sub 2}, 17% CO and 33% N{sub 2}, for partial oxidation/water shifting) can be efficiently made in compact plasma reformers. Experiments have been carried out in a small device (2--3 kW) and without the use of efficient heat regeneration. For partial oxidation/water shifting, it was determined that the specific energy consumption in the plasma reforming processes is 16 MJ/kg H{sub 2} with high conversion efficiencies. Larger plasmatrons, better reactor thermal insulation, efficient heat regeneration and improved plasma catalysis could also play a major role in specific energy consumption reduction and increasing the methane conversion. A system has been demonstrated for hydrogen production with low CO content ({approximately} 1.5%) with power densities of {approximately} 30 kW (H{sub 2} HHV)/liter of reactor, or {approximately} 10 m{sup 3}/hr H{sub 2} per liter of reactor. Power density should further increase with increased power and improved design.

  7. Two isozymes of particulate methane monooxygenase with different methane oxidation kinetics are found in Methylocystis sp. strain SC2

    OpenAIRE

    Baani, Mohamed; Liesack, Werner

    2008-01-01

    Methane-oxidizing bacteria (methanotrophs) attenuate methane emission from major sources, such as wetlands, rice paddies, and landfills, and constitute the only biological sink for atmospheric methane in upland soils. Their key enzyme is particulate methane monooxygenase (pMMO), which converts methane to methanol. It has long been believed that methane at the trace atmospheric mixing ratio of 1.75 parts per million by volume (ppmv) is not oxidized by the methanotrophs cultured to date, but ra...

  8. Light-Dependent Aerobic Methane Oxidation Reduces Methane Emissions from Seasonally Stratified Lakes.

    Directory of Open Access Journals (Sweden)

    Kirsten Oswald

    Full Text Available Lakes are a natural source of methane to the atmosphere and contribute significantly to total emissions compared to the oceans. Controls on methane emissions from lake surfaces, particularly biotic processes within anoxic hypolimnia, are only partially understood. Here we investigated biological methane oxidation in the water column of the seasonally stratified Lake Rotsee. A zone of methane oxidation extending from the oxic/anoxic interface into anoxic waters was identified by chemical profiling of oxygen, methane and δ13C of methane. Incubation experiments with 13C-methane yielded highest oxidation rates within the oxycline, and comparable rates were measured in anoxic waters. Despite predominantly anoxic conditions within the zone of methane oxidation, known groups of anaerobic methanotrophic archaea were conspicuously absent. Instead, aerobic gammaproteobacterial methanotrophs were identified as the active methane oxidizers. In addition, continuous oxidation and maximum rates always occurred under light conditions. These findings, along with the detection of chlorophyll a, suggest that aerobic methane oxidation is tightly coupled to light-dependent photosynthetic oxygen production both at the oxycline and in the anoxic bottom layer. It is likely that this interaction between oxygenic phototrophs and aerobic methanotrophs represents a widespread mechanism by which methane is oxidized in lake water, thus diminishing its release into the atmosphere.

  9. Sorption of methane and CO2 for enhanced coalbed methane recovery and carbon dioxide seauestration

    Institute of Scientific and Technical Information of China (English)

    Basanta Kumar Prusty

    2008-01-01

    Sequestration of CO2 in deep and unmineable coal seams is one of the attractive alternatives to reduce its atmospheric concentration. Injection of CO2 in coal seams may help in enhancing the recovery of coalbed methane. An experimental study has been carried out using coal samples from three different coal seams, to evaluate the enhanced gas recovery and sequestration potential of these coals. The coals were first saturated with methane and then by depressurization some of the adsorbed methane was desorbed. After partial desorption, CO2 was injected into the coals and subsequently they were depressurized again. Desorption of methane after the injections was studied, to investigate the ability of CO2 to displace and enhance the recovery of methane from the coals. The coals exhibited varying behavior of adsorption of CO2 and release of methane. For one coal, the release of methane was enhanced by injection of CO2, suggesting preferential adsorption of CO2 and desorption of methane. For the other two coals, CO2 injection did not produce incremental methane initially, as there was initial resistance to methane release. However with continued CO2 injection, most of the remaining methane was produced. The study suggested that preferential sorption behavior of coal and enhanced gas recovery pattern could not be generalized for all coals.

  10. Enteric methane emissions from German dairy cows

    DEFF Research Database (Denmark)

    Dammgen, U; Rosemann, C; Haenel, H D;

    2012-01-01

    Up to now, the German agricultural emission inventory used a model for the assessment of methane emissions from enteric fermentation that combined an estimate of the energy and feed requirements as a function of performance parameters and diet composition, with the constant methane conversion rate...

  11. Quantification of methane emissions from danish landfills

    DEFF Research Database (Denmark)

    Scheutz, Charlotte; Mønster, Jacob; Kjeldsen, Peter

    2013-01-01

    Whole-landfill methane emission was quantified using a tracer technique that combines controlled tracer gas release from the landfill with time-resolved concentration measurements downwind of the landfill using a mobile high-resolution analytical instrument. Methane emissions from 13 Danish...

  12. Thermophilic methane production and oxidation in compost.

    Science.gov (United States)

    Jäckel, Udo; Thummes, Kathrin; Kämpfer, Peter

    2005-04-01

    Methane cycling within compost heaps has not yet been investigated in detail. We show that thermophilic methane oxidation occurred after a lag phase of up to one day in 4-week old, 8-week old and mature (>10-week old) compost material. The potential rate of methane oxidation was between 2.6 and 4.1 micromol CH4(gdw)(-1)h(-1). Profiles of methane concentrations within heaps of different ages indicated that 46-98% of the methane produced was oxidised by methanotrophic bacteria. The population size of thermophilic methanotrophs was estimated at 10(9) cells (gdw)(-1), based on methane oxidation rates. A methanotroph (strain KTM-1) was isolated from the highest positive step of a serial dilution series. This strain belonged to the genus Methylocaldum, which contains thermotolerant and thermophilic methanotrophs. The closest relative organism on the basis of 16S rRNA gene sequence identity was M. szegediense (>99%), a species originally isolated from hot springs. The temperature optimum (45-55 degrees C) for methane oxidation within the compost material was identical to that of strain KTM-1, suggesting that this strain was well adapted to the conditions in the compost material. The temperatures measured in the upper layer (0-40 cm) of the compost heaps were also in this range, so we assume that these organisms are capable of effectively reducing the potential methane emissions from compost.

  13. Method for removing methane from gas mixtures

    NARCIS (Netherlands)

    Makkee, M.; Xu Xiao, D.

    2008-01-01

    The invention relates to a method for oxidizing methane, comprising passing a gaseous, methane containing mixture over a catalyst, comprising a carrier with a substrate surface which consists substantially of titanium dioxide with a combination of platinum and palladium thereon, in the presence of m

  14. Methane storage in porous activated carbons

    NARCIS (Netherlands)

    Perl, András; Gemert, Wim van

    2014-01-01

    Locally produced methane, - either as biomethane or power-to-gas product, has to be stored to provide a reliable gas source for the fluctuating demand of any local gas distribution network. Additionally, methane is a prominent transportation fuel but its suitability for vehicular application depends

  15. Raman Spectroscopic Studies of Methane Gas Hydrates

    DEFF Research Database (Denmark)

    Hansen, Susanne Brunsgaard; Berg, Rolf W.

    2009-01-01

    A brief review of the Raman spectroscopic studies of methane gas hydrates is given, supported by some new measurements done in our laboratory.......A brief review of the Raman spectroscopic studies of methane gas hydrates is given, supported by some new measurements done in our laboratory....

  16. Reducing methane emissions from ruminant animals

    Energy Technology Data Exchange (ETDEWEB)

    Mathison, G.W.; Okine, E.K.; McAllister, T.A.; Dong, Y.; Galbraith, J.; Dmytruk, O.I.N. [University of Alberta, Edmonton, AB (Canada). Dept. of Agriculture, Food and Nutrition Science

    1998-09-01

    In 1992 it was estimated that 30 x 10{sup 12}g more methane was emitted into the atmosphere than was removed, with animals being considered the largest single anthropogenic source. Ruminants produce 97% of the methane generated in enteric fermentation by animals. Estimates for methane emissions from animal wastes vary between 6 and 31% of that produced directly by the animal, with the most likely value being between 5 and 10% globally. Methane inhibitors can reduce methane emissions to zero in the short term but due to microbial adaptation the effects of these compounds are quickly neutralized and feed intake is often depressed. Methane emissions per unit of feed consumed from sheep and cattle fed hay diets appear to be quite similar but differences between other ruminants have been measured. The most practical way of influencing methane emissions per unit product is to increase productivity level since the proportion of feed energy required to just maintain the animal will be reduced, methane production falls with increased intake level, and the animal may go to market sooner. The most promising avenues for future research for reducing methanogenesis are the development of new products for reducing protozoal numbers in the rumen and the use of bacterocins or other compounds which specifically target methanogenic bacteria.

  17. Decarbonisation of fossil energy via methane pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Kreysa, G.; Agar, D.W.; Schultz, I. [Technische Univ. Dortmund (Germany)

    2010-12-30

    Despite the rising consumption of energy over the last few decades, the proven reserves of fossil fuels have steadily increased. Additionally, there are potentially tremendous reserves of methane hydrates available, which remain to be exploited. The use of fossil energy sources is thus increasingly being dictated less by supply than by the environmental concerns raised by climate change. In the context of the decarbonisation of the global energy system that this has stimulated, new means must be explored for using methane as energy source. Noncatalytic thermal pyrolysis of methane is proposed here as a promising concept for utilising methane with low to zero carbon dioxide emissions. Following cracking, only the energy content of the hydrogen is used, while the carbon can be stored safely and retrievably in disused coal mines. The thermodynamics and different process engineering concepts for the technical realisation of such a carbon moratorium technology are discussed. The possible contribution of methane pyrolysis to carbon negative geoengineering is also addressed. (orig.)

  18. Study on the hydrogenation coupling of methane

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    At atmospheric pressure and ambient temperature, the hydrogenation coupling of methane was studied by using pulse corona plasma and its synergism with catalyst. The results showed that (ⅰ) under pulse corona plasma, the coupling of methane could be fulfilled by the addition of hydrogen, and with the increase of the amount of hydrogen, the conversion of methane and the yield of C2 hydrocarbon increased, and the deposit of carbon decreased; (ⅱ) the conversion of methane was affected by pulse voltage and repeated frequency; (ⅲ) in the system, the addition of Ni/g-Al2O3 could improve the distribution of C2 hydrocarbon; (ⅳ) the activity of Ni/g-Al2O3 prepared by cold plasma was better than that by chemical methods. The experiment opened up a new technical route of the coupling of methane.

  19. Activated carbon monoliths for methane storage

    Science.gov (United States)

    Chada, Nagaraju; Romanos, Jimmy; Hilton, Ramsey; Suppes, Galen; Burress, Jacob; Pfeifer, Peter

    2012-02-01

    The use of adsorbent storage media for natural gas (methane) vehicles allows for the use of non-cylindrical tanks due to the decreased pressure at which the natural gas is stored. The use of carbon powder as a storage material allows for a high mass of methane stored for mass of sample, but at the cost of the tank volume. Densified carbon monoliths, however, allow for the mass of methane for volume of tank to be optimized. In this work, different activated carbon monoliths have been produced using a polymeric binder, with various synthesis parameters. The methane storage was studied using a home-built, dosing-type instrument. A monolith with optimal parameters has been fabricated. The gravimetric excess adsorption for the optimized monolith was found to be 161 g methane for kg carbon.

  20. Neutron cross section of methane hydrate

    Energy Technology Data Exchange (ETDEWEB)

    Kiyanagi, Y.; Date, S.; Horikawa, T.; Takamine, J.; Iwasa, H.; Kamiyama, T. [Graduate School of Eng., Hokkaido Univ., Sapporo (Japan); Uchida, T.; Ebinuma, T.; Narrita, H. [National Inst. of Advanced Industrial Science, Tsukisamu, Sapporo (Japan); Bennington, S.M. [ISIS Dept., Rutherford Appleton, Chilton, Didcot, Oxon (United Kingdom)

    2004-03-01

    To estimate the neutronic characteristics of methane hydrate and also to synthesize cross section data for simulation we need neutron scattering data ranging wide energy and momentum region. We performed inelastic neutron scattering experiments to get information about the neutron cross section on methane hydrate. It was found that at high momentum transfer region rotational mode as well as vibration mode showed recoil like behavior. On the other hand, at low momentum region, as well known, free rotation like energy levels were observed. The energy level of ice in methane hydrate was very similar to normal ice. The results suggest that the rough expression of the cross section of the methane hydrate is presented by linear combination of the methane and ice. (orig.)

  1. Investigation on Gas Storage in Methane Hydrate

    Institute of Scientific and Technical Information of China (English)

    Zhigao Sun; Rongsheng Ma; Shuanshi Fan; Kaihua Guo; Ruzhu Wang

    2004-01-01

    The effect of additives (anionic surfactant sodium dodecyl sulfate (SDS), nonionic surfactant alkyl polysaccharide glycoside (APG), and liquid hydrocarbon cyclopentane (CP)) on hydrate induction time and formation rate, and storage capacity was studied in this work. Micelle surfactant solutions were found to reduce hydrate induction time, increase methane hydrate formation rate and improve methane storage capacity in hydrates. In the presence of surfactant, hydrate could form quickly in a quiescent system and the energy costs of hydrate formation were reduced. The critical micelle concentrations of SDS and APG water solutions were found to be 300× 10-6 and 500× 10-6 for methane hydrate formation system respectively. The effect of anionic surfactant (SDS) on methane storage in hydrates is more pronounced compared to a nonionic surfactant (APG). CP also reduced hydrate induction time and improved hydrate formation rate, but could not improve methane storage in hydrates.

  2. Methane storage in advanced porous materials.

    Science.gov (United States)

    Makal, Trevor A; Li, Jian-Rong; Lu, Weigang; Zhou, Hong-Cai

    2012-12-01

    The need for alternative fuels is greater now than ever before. With considerable sources available and low pollution factor, methane is a natural choice as petroleum replacement in cars and other mobile applications. However, efficient storage methods are still lacking to implement the application of methane in the automotive industry. Advanced porous materials, metal-organic frameworks and porous organic polymers, have received considerable attention in sorptive storage applications owing to their exceptionally high surface areas and chemically-tunable structures. In this critical review we provide an overview of the current status of the application of these two types of advanced porous materials in the storage of methane. Examples of materials exhibiting high methane storage capacities are analyzed and methods for increasing the applicability of these advanced porous materials in methane storage technologies described. PMID:22990753

  3. High methane emission from Siberian river floodplains

    Science.gov (United States)

    Mi, Yanjiao; van Huissteden, Ko; Dolman, Han

    2013-04-01

    Methane contributes significantly to global warming. Methane emission is essentially the net result of a balance between CH4 production by methanogenic bacteria in anaerobic soil zones, and CH4 oxidation by methanotrophic bacteria in aerated soil zones and plants. Arctic and sub-arctic permafrost holds a large amount of climate vulnerable carbon. In particular river floodplains are carbon-rich soils. River floodplains in this area are periodically or permanently submerged. The occurrence of flooding decreases soil oxygen availability, providing an ideal anaerobic environment for methane generation. Here we compare the chamber measurements of the methane flux from tundra and floodplain of the Kytalyk site in Northeast Siberia. Model experiments on this site have also been carried out in order to better explain spatial and temporal variations in methane emissions from northern permafrost. This serves as a basis for further model development including modeling of the flooding regime on the floodplain.

  4. Quantum Annealing for Variational Bayes Inference

    OpenAIRE

    Sato, Issei; Kurihara, Kenichi; Tanaka, Shu; Nakagawa, Hiroshi; Miyashita, Seiji

    2014-01-01

    This paper presents studies on a deterministic annealing algorithm based on quantum annealing for variational Bayes (QAVB) inference, which can be seen as an extension of the simulated annealing for variational Bayes (SAVB) inference. QAVB is as easy as SAVB to implement. Experiments revealed QAVB finds a better local optimum than SAVB in terms of the variational free energy in latent Dirichlet allocation (LDA).

  5. Safety culture development at Daya Bay NPP

    International Nuclear Information System (INIS)

    From view on Organization Behavior theory, the concept, development and affecting factors of safety culture are introduced. The focuses are on the establishment, development and management practice for safety culture at Daya Bay NPP. A strong safety culture, also demonstrated, has contributed greatly to improving performance at Daya Bay

  6. Anthropization in Montevideo Bay during the Holocene

    International Nuclear Information System (INIS)

    This work is about the anthropogenic historic impacts in subtidal environments in Montevideo Bay. The studies carried out in the sediments enable to conclude that the increase of the industrial discharges (nutrients, heavy metals) are the cause of the chemical changes in the sediment of the Montevideo Bay

  7. Bayesian Posteriors Without Bayes' Theorem

    CERN Document Server

    Hill, Theodore P

    2012-01-01

    The classical Bayesian posterior arises naturally as the unique solution of several different optimization problems, without the necessity of interpreting data as conditional probabilities and then using Bayes' Theorem. For example, the classical Bayesian posterior is the unique posterior that minimizes the loss of Shannon information in combining the prior and the likelihood distributions. These results, direct corollaries of recent results about conflations of probability distributions, reinforce the use of Bayesian posteriors, and may help partially reconcile some of the differences between classical and Bayesian statistics.

  8. Biogeography and diversity of methane and sulfur-cycling ecotypes in deep subsurface sediments

    Science.gov (United States)

    Adams, M. M.; Biddle, J.; Girguis, P. R.

    2013-12-01

    The microbially mediated anaerobic oxidation of methane (AOM) is critical for regulating the flux of methane from the ocean. AOM is coupled to sulfate availability in many anoxic marine environments, which has been extensively studied at cold seeps, hydrothermal vents, and the sulfate-methane transition zone at the seafloor. The microbes known to catalyze AOM form phylogenetically distinct anaerobic methanotroph (ANME) clusters and sometimes live in concert with sulfate-reducing bacteria (SRB). Strikingly, certain ANME groups and subgroups have been shown to occupy different ecological niches in both hydrocarbon seep and hydrothermal vent sediments. However, the environmental parameters that select for certain phylogenetic variants or 'ecotypes' in a wide range of marine systems are still unknown. A marine environment that remains elusive to characterization of potential ANME and SRB ecotype diversity is methane hydrate formations in the deep subsurface. Current estimates indicate that seafloor hydrates may exceed 10,000 GtC at standard temperature and pressure conditions. However, only a handful of studies have investigated the potential for AOM in the deep subsurface associated with methane hydrates. To gain a better understanding of the distribution of methane- and sulfur- cycling ecotypes in biogeochemically distinct marine subsurface ecosystems, we generated a substantial library of 16S rRNA gene sequences for these uncultivable deep sea microorganisms using Illumina sequencing. Sediment strata were collected from the methane-hydrate associated deep subsurface of Hydrate Ridge (30 - 100 mbsf), hydrocarbon cold seeps of Monterey Bay, metalliferous sedimented hydrothermal vents of Juan de Fuca Ridge, and organic-rich hydrothermally influenced sediments of Guaymas Basin. We used the Illumina MiSeq sequencing platform to assess Archaeal and Bacterial richness in a total of 36 deep sea sediment samples followed by qPCR for quantification of ANME and SRB phylotype

  9. Biochemically enhanced methane production from coal

    Science.gov (United States)

    Opara, Aleksandra

    For many years, biogas was connected mostly with the organic matter decomposition in shallow sediments (e.g., wetlands, landfill gas, etc.). Recently, it has been realized that biogenic methane production is ongoing in many hydrocarbon reservoirs. This research examined microbial methane and carbon dioxide generation from coal. As original contributions methane production from various coal materials was examined in classical and electro-biochemical bench-scale reactors using unique, developed facultative microbial consortia that generate methane under anaerobic conditions. Facultative methanogenic populations are important as all known methanogens are strict anaerobes and their application outside laboratory would be problematic. Additional testing examined the influence of environmental conditions, such as pH, salinity, and nutrient amendments on methane and carbon dioxide generation. In 44-day ex-situ bench-scale batch bioreactor tests, up to 300,000 and 250,000 ppm methane was generated from bituminous coal and bituminous coal waste respectively, a significant improvement over 20-40 ppm methane generated from control samples. Chemical degradation of complex hydrocarbons using environmentally benign reagents, prior to microbial biodegradation and methanogenesis, resulted in dissolution of up to 5% bituminous coal and bituminous coal waste and up to 25% lignite in samples tested. Research results confirm that coal waste may be a significant underutilized resource that could be converted to useful fuel. Rapid acidification of lignite samples resulted in low pH (below 4.0), regardless of chemical pretreatment applied, and did not generate significant methane amounts. These results confirmed the importance of monitoring and adjusting in situ and ex situ environmental conditions during methane production. A patented Electro-Biochemical Reactor technology was used to supply electrons and electron acceptor environments, but appeared to influence methane generation in a

  10. Methane measurements manual; Handbok metanmaetningar

    Energy Technology Data Exchange (ETDEWEB)

    Holmgren, Magnus Andreas (SP Technical research institute of Sweden, Boraas (Sweden))

    2011-02-15

    Emissions to air in different parts of the system may arise in biogas plants, where there is biological treatment of organic matter by anaerobic degradation, and during upgrading of biogas to vehicle fuel. There are mainly four reasons why these emissions must be minimized. These are safety, greenhouse gas emissions, economy and smell. This manual gathers experience of several years of work with measurement of methane emissions from biogas and upgrading facilities. This work has been done mainly in the context of Swedish Waste Management's system of voluntary commitment. The purpose of this manual is to standardize methods and procedures when methane measurements are carried out so that the results are comparable between different providers. The main target group of the manual is measurement consultants performing such measurements. Calculation template in Excel is part of the manual, which further contributes to the measurements evaluated in a standardized way. The manual contains several examples which have been calculated in the accompanying Excel template. The handbook also contains a chapter mainly intended for facility staff, in which implementation of accurate leak detection is described, and where there are hints of a system of so-called intermediate inspections to detect leaks in time

  11. The direct aromatization of methane

    Energy Technology Data Exchange (ETDEWEB)

    Marcelin, G.; Oukaci, R.; Migone, R.A.; Kazi, A.M. [Altamira Instruments, Pittsburgh, PA (United States)

    1995-12-31

    The thermal decomposition of methane shows significant potential as a process for the production of higher unsaturated and aromatic hydrocarbons when the extent of the reaction is limited. Thermodynamic calculations have shown that when the reaction is limited to the formation of C{sub 2} to C{sub 10} products, yields of aromatics can exceed 40% at temperatures of 1200{degrees}C. Preliminary experiments have shown that when the reaction is limited to the formation of C{sub 2} to C{sub 10} products, yields of aromatics can exceed 40% at temperatures of 1200{degrees}C. Preliminary experiments have shown that cooling the product and reacting gases as the reaction proceeds can significantly reduce or eliminate the formation of solid carbon and heavier (C{sub 10+}) materials. Much work remains to be done in optimizing the quenching process and this is one of the goals of this program. Means to lower the temperature of the reaction are being studied as this result in a more feasible commercial process due to savings realized in energy and material of construction costs. The use of free-radical generators and catalysts will be investigated as a means of lowering the reaction temperature thus allowing faster quenching. It is highly likely that such studies will lead to a successful direct methane to higher hydrocarbon process.

  12. Radioactivity Levels in Kola Bay

    International Nuclear Information System (INIS)

    Sediment samples were collected in May 1995 from 16 locations in Kola Bay, North-west Russia, during an expedition starting from Murmansk and ending at Kildin Island in the Barents Sea. The purpose was to study the contamination level in an area with several potential sources of civilian and military radioactive pollution. 137Cs concentrations in the sediments, algae and benthic samples were low, but small particles containing 137Cs were separated from the sediment samples. All the sediments between the nuclear icebreaker base Atomflot and the open Barents Sea contained 60Co. Traces of 125Sb, 134Cs, 95Zr, 154Eu and 152Eu were also detected in some of the samples. Plutonium levels were low, but the increased 238Pu/239,240Pu ratio at Atomflot indicated a fresh release from the facility or from the waste storage vessels, Lepse and Imandra, lying in front of it. An increased 238Pu/239,240Pu ratio was also found in sediment collected in the outlet of Kola Bay in the Barents Sea. (author)

  13. Identification of Methanogens and Controls on Methane Production in Incubations of Natural Methane Seep Sediments

    Science.gov (United States)

    Kevorkian, R.; Lloyd, K. G.

    2014-12-01

    Methane, the most abundant hydrocarbon in Earth's atmosphere, is produced in large quantities in sediments underlying the world's oceans. Very little of this methane makes it to surface sediments as it is consumed by Anaerobic Methanotrophs (ANME's) in consortia with Sulfate Reducing Bacteria (SRB). Less is known about which organisms are responsible for methane production in marine sediments, and whether that production is under thermodynamic control based on hydrogen concentrations. Although ANMEs have been found to be active in methanogenic sediments and incubations, it is currently unknown whether they are able to grow in methanogenic conditions. We demonstrated with bottle incubations of methane seep sediment taken from Cape Lookout Bight, NC, that hydrogen controls methane production. While sulfate was present the hydrogen concentration was maintained at below 2 nM. Only after the depletion of sulfate allowed hydrogen concentrations to rise above 5 nM did we see production of methane. The same sediments when spiked with methane gas demonstrated its complete removal while sulfate reduction occurred. Quantitative PCR shows that ANME-2 and ANME-1 increase in 16S copy number as methane increases. Total direct cell counts demonstrate a decline in cells with the decrease of sulfate until a recovery corresponding with production of methane. Our results strongly suggest that hydrogen concentrations influence what metabolic processes can occur in marine sediments, and that ANME-1 and ANME-2 are able to grow on the energy provided from methane production.

  14. Methane seeps, methane hydrate destabilization, and the late Neoproterozoic postglacial cap carbonates

    Institute of Scientific and Technical Information of China (English)

    JIANG Ganqing; SHI Xiaoying; ZHANG Shihong

    2006-01-01

    Methane hydrates constitute the largest pool of readily exchangeable carbon at the Earth's sedimentary carapace and may destabilize, in some cases catastrophically, during times of global-scale warming and/or sea level changes. Given the extreme cold during Neoproterozoic ice ages, the aftermath of such events is perhaps amongst the most likely intervals in Earth history to witness a methane hydrate destabilization event. The coincidence of localized but widespread methane seep-like structures and textures, methane-derived isotopic signal,low sulfate concentration, marine barites, and a prominent, short-lived carbon isotope excursion (δ13C≤-5‰) from the post-Marinoan cap carbonates (~635 Ma) provides strong evidence for a methane hydrate destabilization event during the late Neoproterozoic postglacial warming and transgression. Methane release from hydrates could cause a positive feedback to global warming and oxidation of methane could result in ocean anoxia and fluctuation of atmospheric oxygen, providing an environmental force for the early animal evolution in the latest Neoproterozoic. The issues that remain to be clarified for this event include the trigger of methane hydrate destabilization, the time of initial methane release, the predicted ocean anoxia event and its relationship with the biological innovation, additional geochemical signals in response to methane release, and the regional and global synchrony of cap carbonate precipitation. The Doushantuo cap carbonate in South China provides one of the best examples of its age for a better understanding of these issues.

  15. Gas hydrate destabilization and methane release events in the Krishna-Godavari Basin, Bay of Bengal

    Digital Repository Service at National Institute of Oceanography (India)

    Joshi, R.K.; Mazumdar, A.; Peketi, A.; Ramamurty, P.B.; Naik, B.G.; Kocherla, M.; Carvalho, M.A.; Mahalakshmi, P.; Dewangan, P.; Ramana, M.V.

    13C excursions and earlier reports on the occurrence chemosynthetic bivalves and Mo concentration anomaly to the destabilization of the base of gas hydrate stability zone (BGHSZ). Sea level drop and shale tectonics induced focused fluid flow...

  16. Impact of seasonal temperature and pressure changes on methane gas production, dissolution, and transport in unfractured sediments

    OpenAIRE

    J. M. Mogollón; Dale, A.W.; L'Heureux, I.; Regnier, P.

    2011-01-01

    A one-dimensional reaction-transport model is used to investigate the dynamics of methane gas in coastal sediments in response to intra-annual variations in temperature and pressure. The model is applied to data from two shallow water sites in Eckernförde Bay (Germany) characterized by low and high rates of upward fluid advection. At both sites, organic matter is buried below the sulfate-reducing zone to the methanogenic zone at sufficiently high rates to allow supersaturation of the pore wat...

  17. 30 CFR 27.21 - Methane-monitoring system.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Methane-monitoring system. 27.21 Section 27.21... APPROVAL OF MINING PRODUCTS METHANE-MONITORING SYSTEMS Construction and Design Requirements § 27.21 Methane-monitoring system. (a) A methane-monitoring system shall be so designed that any machine or equipment,...

  18. 30 CFR 27.22 - Methane detector component.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Methane detector component. 27.22 Section 27.22... APPROVAL OF MINING PRODUCTS METHANE-MONITORING SYSTEMS Construction and Design Requirements § 27.22 Methane detector component. (a) A methane detector component shall be suitably constructed for incorporation in...

  19. 30 CFR 57.22308 - Methane monitors (III mines).

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Methane monitors (III mines). 57.22308 Section... Standards for Methane in Metal and Nonmetal Mines Equipment § 57.22308 Methane monitors (III mines). (a) Methane monitors shall be installed on continuous mining machines and longwall mining systems. (b)...

  20. 30 CFR 57.22226 - Testing for methane (IV mines).

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Testing for methane (IV mines). 57.22226... Standards for Methane in Metal and Nonmetal Mines Ventilation § 57.22226 Testing for methane (IV mines). Tests for methane shall be conducted in the mine atmosphere by a competent person— (a) At least...

  1. Resources of coal methane and problems in their development

    Institute of Scientific and Technical Information of China (English)

    A.V.Andreev

    2006-01-01

    @@ The coal deposits methane is one of the type ecological mineral-raw materials resources. The methane reasonable extract from coal-methane deposits at the same time with mining of coal. This is the most economical way of the coal methane mining.

  2. 30 CFR 75.1324 - Methane concentration and tests.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Methane concentration and tests. 75.1324... Methane concentration and tests. (a) No shot shall be fired in an area that contains 1.0 volume percent or more of methane. (b) Immediately before shots are fired, the methane concentration in a working...

  3. Methane on Mars: Measurements and Possible Origins

    Science.gov (United States)

    Mumma, Michael J.; Villanueva, Geronimo L.; Novak, Robert E.; Radeva, Yana L.; Kaufl, H. Ulrich; Tokunaga, Alan; Encrenaz, Therese; Hartogh, Paul

    2011-01-01

    The presence of abundant methane in Earth's atmosphere (1.6 parts per million) requires sources other than atmospheric chemistry. Living systems produce more than 90% of Earth's atmospheric methane; the balance is of geochemical origin. On Mars, methane has been sought for nearly 40 years because of its potential biological significance, but it was detected only recently [1-5]. Its distribution on the planet is found to be patchy and to vary with time [1,2,4,5], suggesting that methane is released recently from the subsurface in localized areas, and is then rapidly destroyed [1,6]. Before 2000, searchers obtained sensitive upper limits for methane by averaging over much of Mars' dayside hemisphere, using data acquired by Marsorbiting spacecraft (Mariner 9) and Earth-based observatories (Kitt Peak National Observatory, Canada- France-Hawaii Telescope, Infrared Space Observatory). These negative findings suggested that methane should be searched at higher spatial resolution since the local abundance could be significantly larger at active sites. Since 2001, searches for methane have emphasized spatial mapping from terrestrial observatories and from Mars orbit (Mars Express).

  4. Spatial distribution of microbial communities in the shallow submarine alkaline hydrothermal field of the Prony Bay, New Caledonia.

    Science.gov (United States)

    Quéméneur, Marianne; Bes, Méline; Postec, Anne; Mei, Nan; Hamelin, Jérôme; Monnin, Christophe; Chavagnac, Valérie; Payri, Claude; Pelletier, Bernard; Guentas-Dombrowsky, Linda; Gérard, Martine; Pisapia, Céline; Gérard, Emmanuelle; Ménez, Bénédicte; Ollivier, Bernard; Erauso, Gaël

    2014-12-01

    The shallow submarine hydrothermal field of the Prony Bay (New Caledonia) discharges hydrogen- and methane-rich fluids with low salinity, temperature (microbial community structure, abundance and diversity depending on the location, water depth, and structure of the carbonate chimneys. The low archaeal diversity was dominated by few uncultured Methanosarcinales similar to those found in other serpentinization-driven submarine and subterrestrial ecosystems (e.g. Lost City, The Cedars). The most abundant and diverse bacterial communities were mainly composed of Chloroflexi, Deinococcus-Thermus, Firmicutes and Proteobacteria. Functional gene analysis revealed similar abundance and diversity of both Methanosarcinales methanoarchaea, and Desulfovibrionales and Desulfobacterales sulfate-reducers in the studied sites. Molecular studies suggest that redox reactions involving hydrogen, methane and sulfur compounds (e.g. sulfate) are the energy driving forces of the microbial communities inhabiting the Prony hydrothermal system.

  5. Mars Methane highs unrelated to comets

    Science.gov (United States)

    Roos-Serote, Maarten; Atreya, Sushil K.; Webster, Chris; Mahaffy, Paul

    2016-10-01

    Until the Curiosity Rover arrived at Mars, all measurements of methane were done by remote sensing, either from Earth or from orbiting spacecraft, using a variety of different instruments and under different observing conditions. The Curiosity Rover's Sample Analysis at Mars (SAM) / Tunable Laser Spectrometer (TLS) has carried out systematic measurements of martian methane from Gale crater for two consecutive martian years (31 - 33, starting in October 2012). Meteoric material interacts with the martian atmosphere when Mars passes through a meteoroid stream left behind by cometary bodies orbiting the Sun. Predictions show that 33 such events are likely to occur during the martian year. It has been suggested that the organics present in this material trigger the formation of methane in the atmosphere, and thus these events could possibly be an explanation for the observed variations in the methane abundance. In a recent paper, Fries et al. [2016] argued that all measurements of high methane concentrations are within 16 days of a predicted meteor shower event, and that as such there is a correlation. We present a new analysis including seven new data points that were not available previously. All these new measurements show low methane values. Some of the new measurements were deliberately taken at the same Ls when high values of methane were measured in the previous martian year, showing that the high methane measurements are likely not seasonal, as would be expected if they were connected to meteor shower events. In our analysis we take into account all the predicted meteor events and search for any correlation drawn between these events and the level of methane in the atmosphere. We conclude that whether we consider individual data points, apply statistical analysis, or consider different time spans between measurements and the occurrence of meteor events, or possible supply of organic material from comets, there is no evidence for such a correlation in the

  6. Status of the methanization sector in France

    International Nuclear Information System (INIS)

    This report aims at describing the status of methanization installations, either operating or under construction, on the French national territory, all sectors included (industry, agriculture, sewage treatment, municipal wastes). In a first part, the authors propose a definition of methanization, a presentation of the various implementation techniques, a presentation of the different sectors using methanization (industry, agriculture and breeding, sewage treatment plants, household wastes), and a presentation of a survey. Then, they comment and discuss more precisely the different sectors, their history, their geographical distribution in France, their technologies, their effluents, their production, their economic data, their perspectives

  7. Enteric methane emissions from German pigs

    DEFF Research Database (Denmark)

    Dämmgen, Ulrich; Schulz, Joachim; Klausing, Heinrich Kleine;

    2012-01-01

    Methane emissions from enteric fermentation of pigs are object of emission reporting. Hitherto they were treated as part of the energy balance of pigs, in accordance with IPCC guidance documents. They were calculated from the gross energy intake rate and a constant methane conversion ratio....... Meanwhile numerous experimental data on methane emissions from enteric fermentation is available in Germany and abroad; the results are compiled in this work. These results also allow for a description of transformation processes in the hind gut and a subsequent establishment of models that relate emissions...

  8. China Accelerates Development of Coalbed Methane Industry

    Institute of Scientific and Technical Information of China (English)

    Wang Shenyan

    1997-01-01

    @@ Coalbed methane is a kind of natural gas self-accumulated in coalbed and adjacent strata. It was usually regarded hazardous in coal mine production and drained with an aim of coal mine safe production in the past time. Many countries have re-cently attached great importance to the development of coalbed methane since the United States developed the technique of extraction of coalbed methane through drilling a hole from the surface in the 1980s. It has rapidly become a new industrial sector, which provides both clean gas energy for residential and industrial purposes and raw material for chemical products such as fertilizer,carbon black and methanol.

  9. Tapping methane hydrates for unconventional natural gas

    Science.gov (United States)

    Ruppel, Carolyn

    2007-01-01

    Methane hydrate is an icelike form of concentrated methane and water found in the sediments of permafrost regions and marine continental margins at depths far shallower than conventional oil and gas. Despite their relative accessibility and widespread occurrence, methane hydrates have never been tapped to meet increasing global energy demands. With rising natural gas prices, production from these unconventional gas deposits is becoming economically viable, particularly in permafrost areas already being exploited for conventional oil and gas. This article provides an overview of gas hydrate occurrence, resource assessment, exploration, production technologies, renewability, and future challenges.

  10. Fiber Methane Gas Sensor and Its Application in Methane Outburst Prediction in Coal Mine

    Institute of Scientific and Technical Information of China (English)

    Jia-Sheng Ni; Jun Chang; Tong-Yu Liu; Yan-Fang Li; Yan-Jie Zhao; Qian Wang

    2008-01-01

    Fiber optic methane gas detecting system based on distributed feedback (DFB) laser wavelength scanning technique is demonstrated. Wavelength scan of methane absorption peak at 1665.9 nm is realized by saw tooth modulation of current which is injected to DFB laser. A reference methane gas cell is used to find the methane absorption peak around 1666 rim, and normalization is used to reduce the outside affection such as power drift, fiber loss. Concentration is got by arithmetic processing absorption coefficient of the methane gas. In-situ test is carried out in coal mine and long time precision of 0.05% is achieved. Some spot data of coal mine is introduced. By the system, methane outburst can be measured.

  11. 46 CFR 7.20 - Nantucket Sound, Vineyard Sound, Buzzards Bay, Narragansett Bay, MA, Block Island Sound and...

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Nantucket Sound, Vineyard Sound, Buzzards Bay, Narragansett Bay, MA, Block Island Sound and easterly entrance to Long Island Sound, NY. 7.20 Section 7.20... Atlantic Coast § 7.20 Nantucket Sound, Vineyard Sound, Buzzards Bay, Narragansett Bay, MA, Block...

  12. Deep-ocean field test of methane hydrate formation from a remotely operated vehicle

    Science.gov (United States)

    Brewer, P.G.; Orr, F.M.; Friederich, G.; Kvenvolden, K.A.; Orange, D.L.; McFarlane, J.; Kirkwood, W.

    1997-01-01

    We have observed the process of formation of clathrate hydrates of methane in experiments conducted on the remotely operated vehicle (ROY) Ventana in the deep waters of Monterey Bay. A tank of methane gas, acrylic tubes containing seawater, and seawater plus various types of sediment were carried down on Ventana to a depth of 910 m where methane gas was injected at the base of the acrylic tubes by bubble stream. Prior calculations had shown that the local hydrographic conditions gave an upper limit of 525 m for the P-T boundary defining methane hydrate formation or dissociation at this site, and thus our experiment took place well within the stability range for this reaction to occur. Hydrate formation in free sea-water occurred within minutes as a buoyant mass of translucent hydrate formed at the gas-water interface. In a coarse sand matrix the Filling of the pore spaces with hydrate turned the sand column into a solidified block, which gas pressure soon lifted and ruptured. In a fine-grained black mud the gas flow carved out flow channels, the walls of which became coated and then filled with hydrate in larger discrete masses. Our experiment shows that hydrate formation is rapid in natural seawater, that sediment type strongly influences the patterns of hydrate formation, and that the use of ROV technologies permits the synthesis of large amounts of hydrate material in natural systems under a variety of conditions so that fundamental research on the stability and growth of these substances is possible.

  13. Aquatic herbivores facilitate the emission of methane from wetlands

    OpenAIRE

    Dingemans, B.J.J.; Bakker, E.S.; Bodelier, P.L.E.

    2011-01-01

    Wetlands are significant sources of atmospheric methane. Methane produced by microbes enters roots and escapes to the atmosphere through the shoots of emergent wetland plants. Herbivorous birds graze on helophytes, but their effect on methane emission remains unknown. We hypothesized that grazing on shoots of wetland plants can modulate methane emission from wetlands. Diffusive methane emission was monitored inside and outside bird exclosures, using static flux chambers placed over whole vege...

  14. Termites Facilitate Methane Oxidation and Shape the Methanotrophic Community

    OpenAIRE

    Ho, Adrian; Erens, Hans; Mujinya, Basile Bazirake; Boeckx, Pascal; Baert, Geert; Schneider, Bellinda; Frenzel, Peter; Boon, Nico; Van Ranst, Eric

    2013-01-01

    Termite-derived methane contributes 3 to 4% to the total methane budget globally. Termites are not known to harbor methane-oxidizing microorganisms (methanotrophs). However, a considerable fraction of the methane produced can be consumed by methanotrophs that inhabit the mound material, yet the methanotroph ecology in these environments is virtually unknown. The potential for methane oxidation was determined using slurry incubations under conditions with high (12%) and in situ (∼0.004%) metha...

  15. Methane Conversion to C2 Hydrocarbons Using Glow Discharge Plasma

    Institute of Scientific and Technical Information of China (English)

    HU Miao; CHEN Jierong

    2007-01-01

    The infrared emission spectra of methane, H', CH and C2 hydrocarbons in natural gas were measured. The process of methane decomposition and C2 hydrocarbons formation was investigated. The experiment showed that the time and conditions of methane decomposition and C2 hydrocarbons formation were different. Methane conversion rate increased with the increase in the current and decrease in the amount of methane. Furthermore, an examination of the reaction mechanisms revealed that free radicals played an important role in the chain reaction.

  16. METHANE CONVERTERS WITH THE RAISED YIELD OF HYDROGEN

    OpenAIRE

    Mescherjakov, G.; Commissarov, Ju

    2011-01-01

    Has been created the hydrogen conversion index, that used for comparing the different type of methane conversions. Have been developed the tubular converter for steam reforming of methane using the flue gas and methane conversion shaft reactor with a hot bypass. Created the mathematical models of reforming methane reactors that adequately describe the processes and optimizated of oxidants flow (oxygen and water vapor). The designed reactors, that may produce more hydrogen per unit of methane ...

  17. Persistent whole-bay red tide of Noctiluca scintillans in Manila Bay, Philippines

    OpenAIRE

    Furuya, Ken; Saito, Haruna; Rujinard, Sriwoon; Anil K. Vijayan; Omura, Takuo; Elsa E. Furio; Valeriano M. Borja; Sopana, Boonyapiwat; Thaithaworn, Lirdwitayaprasit

    2006-01-01

    Noctiluca scintillans, which contains a photosynthetic endosymbiont, Pedinomonas noctilucae, formed perennial red tides in Manila Bay, Philippines, occasionally covering almost whole area since 2001. A whole-bay scale red tide of the green Noctiluca in Manila Bay is described as the first step to elucidate the formation mechanism of the large scale blooming of the organism. A field survey was conducted in March 2004, when greenish discoloration due to N. scintillans was observed in the whole ...

  18. Holy grail at Baglan Bay

    Energy Technology Data Exchange (ETDEWEB)

    Watson, Jim

    1999-09-01

    The UK government's consent for the construction of a gas-fired power plant at Baglan Bay in South Wales is reported, and the growing popularity of economic combined-cycle gas turbine (CCGT) power plants and the resulting environmental improvements are noted . The combining of gas and steam turbines, design developments, and the UK moratorium on planning consents for gas fired power plants are discussed. General Electric's H System technology which will lower the amount of energy lost in the conversion of natural gas to electricity is described, and details of the ten most problematic CCGTs in the UK are given. The domination of the CCGT global market by four manufacturers, and the pressure on manufacturers to develop their designs are considered. (UK)

  19. Bayes linear covariance matrix adjustment

    CERN Document Server

    Wilkinson, Darren J

    1995-01-01

    In this thesis, a Bayes linear methodology for the adjustment of covariance matrices is presented and discussed. A geometric framework for quantifying uncertainties about covariance matrices is set up, and an inner-product for spaces of random matrices is motivated and constructed. The inner-product on this space captures aspects of our beliefs about the relationship between covariance matrices of interest to us, providing a structure rich enough for us to adjust beliefs about unknown matrices in the light of data such as sample covariance matrices, exploiting second-order exchangeability and related specifications to obtain representations allowing analysis. Adjustment is associated with orthogonal projection, and illustrated with examples of adjustments for some common problems. The problem of adjusting the covariance matrices underlying exchangeable random vectors is tackled and discussed. Learning about the covariance matrices associated with multivariate time series dynamic linear models is shown to be a...

  20. The Liverpool Bay Coastal Observatory

    Science.gov (United States)

    Howarth, John; Palmer, Matthew

    2011-11-01

    A pilot Coastal Observatory has been established in Liverpool Bay which integrates (near) real-time measurements with coupled models and whose results are displayed on the web. The aim is to understand the functioning of coastal seas, their response to natural forcing and the consequences of human activity. The eastern Irish Sea is an apt test site, since it encompasses a comprehensive range of processes found in tidally dominated coastal seas, including near-shore physical and biogeochemical processes influenced by estuarine inflows, where both vertical and horizontal gradients are important. Applications include hypernutrification, since the region receives significantly elevated levels of nutrient inputs, shoreline management (coastal flooding and beach erosion/accretion), and understanding present conditions to predict the impact of climate change (for instance if the number and severity of storms, or of high or low river flows, change). The integrated measurement suite which started in August 2002 covers a range of space and time scales. It includes in situ time series, four to six weekly regional water column surveys, an instrumented ferry, a shore-based HF radar system measuring surface currents and waves, coastal tide gauges and visible and infra-red satellite data. The time series enable definition of the seasonal cycle, its inter-annual variability and provide a baseline from which the relative importance of events can be quantified. A suite of nested 3D hydrodynamic, wave and ecosystem models is run daily, focusing on the observatory area by covering the ocean/shelf of northwest Europe (at 12-km resolution) and the Irish Sea (at 1.8 km), and Liverpool Bay at the highest resolution of 200 m. The measurements test the models against events as they happen in a truly 3D context. All measurements and model outputs are displayed freely on the Coastal Observatory website (http://cobs.pol.ac.uk) for an audience of researchers, education, coastal managers and the

  1. Producing Hydrogen by Plasma Pyrolysis of Methane

    Science.gov (United States)

    Atwater, James; Akse, James; Wheeler, Richard

    2010-01-01

    Plasma pyrolysis of methane has been investigated for utility as a process for producing hydrogen. This process was conceived as a means of recovering hydrogen from methane produced as a byproduct of operation of a life-support system aboard a spacecraft. On Earth, this process, when fully developed, could be a means of producing hydrogen (for use as a fuel) from methane in natural gas. The most closely related prior competing process - catalytic pyrolysis of methane - has several disadvantages: a) The reactor used in the process is highly susceptible to fouling and deactivation of the catalyst by carbon deposits, necessitating frequent regeneration or replacement of the catalyst. b) The reactor is highly susceptible to plugging by deposition of carbon within fixed beds, with consequent channeling of flow, high pressure drops, and severe limitations on mass transfer, all contributing to reductions in reactor efficiency. c) Reaction rates are intrinsically low. d) The energy demand of the process is high.

  2. Methane Tracking and Mitigation Options - EPA CMOP

    Data.gov (United States)

    U.S. Environmental Protection Agency — This dataset contains the sub-model for EPA's MARKAL model, which tracks methane emissions from the energy system, and limited other sources (landfills and manure...

  3. Methane Detector With Plastic Fresnel Lens

    Science.gov (United States)

    Grant, W. B.

    1986-01-01

    Laser detector for natural gas leaks modified by substitution of molded plastic lens for spherical mirror. By measuring relative attenuation at two wavelengths, detector used to check for methane escaping from pipelines above or below ground and from landfill.

  4. Methane leakage in natural gas operations

    International Nuclear Information System (INIS)

    The world gas industry is efficient in conservation of natural gas within its systems. As the influence of methane as an infra-red absorbent gas has been more widely recognized, the considerations of methane's greenhouse effect has become vitally important to gas companies around the world. The industry is universally environmentally conscious. natural gas transmission and distribution companies want to maintain their image as suppliers of clean fuel. Further reductions in methane leakage --- particularly in older distribution systems --- can, should and will be pursued. Unfortunately, there has been little exchange of views on methane leakages between commentators on environmental matters and gas companies and organizations. There is absolutely no need for the industry to avoid the issue of greenhouse gases. Without industry involvement, the environmental debate concerning fossil fuels could lead to selective interpretation of scientific views and available evidence. Companies and authorities would be presented with confusing, contradictory evidence on which to base policy approaches and regulations

  5. Methane from the East Siberian Arctic shelf

    DEFF Research Database (Denmark)

    Petrenko...[], Vasilii V.; Etheridge, David M.

    2010-01-01

    In their Report “Extensive methane venting to the atmosphere from sediments of the East Siberian Arctic Shelf” (5 March, p. 1246), N. Shakhova et al. write that methane (CH4) release resulting from thawing Arctic permafrost “is a likely positive feedback to climate warming.” They add that the rel......In their Report “Extensive methane venting to the atmosphere from sediments of the East Siberian Arctic Shelf” (5 March, p. 1246), N. Shakhova et al. write that methane (CH4) release resulting from thawing Arctic permafrost “is a likely positive feedback to climate warming.” They add...... we conducted, suggests that a very large (~50%) increase in atmospheric CH4 concentration associated with an abrupt warming event ~11,600 years ago was driven mainly by wetlands, without distinguishing between high and low latitudes. Their reference 9 (3) was published in 1993 and is not relevant...

  6. Formation temperatures of thermogenic and biogenic methane

    Science.gov (United States)

    Stolper, D.A.; Lawson, M.; Davis, C.L.; Ferreira, A.A.; Santos Neto, E. V.; Ellis, G.S.; Lewan, M.D.; Martini, A.M.; Tang, Y.; Schoell, M.; Sessions, A.L.; Eiler, J.M.

    2014-01-01

    Methane is an important greenhouse gas and energy resource generated dominantly by methanogens at low temperatures and through the breakdown of organic molecules at high temperatures. However, methane-formation temperatures in nature are often poorly constrained. We measured formation temperatures of thermogenic and biogenic methane using a “clumped isotope” technique. Thermogenic gases yield formation temperatures between 157° and 221°C, within the nominal gas window, and biogenic gases yield formation temperatures consistent with their comparatively lower-temperature formational environments (<50°C). In systems where gases have migrated and other proxies for gas-generation temperature yield ambiguous results, methane clumped-isotope temperatures distinguish among and allow for independent tests of possible gas-formation models.

  7. Bio-methane. Challenges and technical solutions

    International Nuclear Information System (INIS)

    Among the new energy sectors in development, biogas has many benefits: several valorization possibilities (bio-methane, electricity and heat), continuous production, easy storage. In Europe, and particularly in France, the bio-methane market will be in the next years a driver for the improvement of the economic, environmental and social performance of the actors of the value chain of biogas. ENEA releases a report on the current state of the bio-methane market in Europe. This publication mainly describes: An outlook of the market evolution and the corresponding stakes for the actors of this sector, the technical and economic characteristics, maturity level and specificities of each biogas upgrading process, An analysis of the French regulatory framework for bio-methane injection into the grid

  8. High Performance Methane Thrust Chamber (HPMTC) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — ORBITEC proposes to develop a High-Performance Methane Thrust Chamber (HPMRE) to meet the demands of advanced chemical propulsion systems for deep-space mission...

  9. Carbon dioxide and methane emissions from estuaries

    OpenAIRE

    Abril, G.; Borges, Alberto

    2005-01-01

    Carbon dioxide and methane emissions from estuaries are reviewed in relationwith biogeochemical processes and carbon cycling. In estuaries, carbondioxide and methane emissions show a large spatial and temporalvariability, which results from a complex interaction of river carbon inputs,sedimentation and resuspension processes, microbial processes in watersand sediments, tidal exchanges with marshes and flats and gas exchangewith the atmosphere. The net mineralization of land-derived organic ca...

  10. Experimental analysis of direct thermal methane cracking

    OpenAIRE

    Abánades Velasco, Alberto; Martínez-Val Peñalosa, Jose Maria; Ruíz, E.; Ferruelo, E. M.; Hernández, F.; Cabanillas, A.; Rubio, J.A.; López, C.; Gavela, R.; G. Barrera; Rubbia, C.; Salmieri, D.; Rodilla, E.; Gutiérrez, D

    2011-01-01

    The analysis of the viability of Hydrogen production without CO2 emissions is one of the most challenging activities that have been initiated for a sustainable energy supply. As one of the tracks to fulfil such objective, direct methane cracking has been analysed experimentally to assess the scientific viability and reaction characterization in a broad temperature range, from 875 to 1700 ?C. The effect of temperature, sweeping/carrier gas fraction proposed in some concepts, methane flow ...

  11. A biomimetic methane-oxidising catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Dalton, H. [Warwick Univ., Coventry (United Kingdom). Dept. of Biological Sciences

    1996-12-31

    The diminishing resources of petroleum oil has meant that there has been considerable efforts in recent years to find a suitable substitute for gasoline as a transportation fuel. Methanol has been identified as a suitable substitute since it is a readily combustible fuel which can be manufactured from a number of different sources. Methane is commonly used as a starting material for the production of synthesis gas (CO + H{sub 2}) and hence methanol. It is well known that the cleavage of the C-H bond of methane is extremely difficult (bond energy is around 104 kcal/mol) and that fairly drastic conditions are required to convert methane into methanol. Temperatures around 1200 deg C and pressures of up to 100 atmospheres over metal catalysts in a series of reactions are required to effect this process. Efforts have been made to reduce the temperature and the number of steps by using lanthanide ruthenium oxide catalyst but such reactions are still thermodynamically endothermic. An energetically more efficient reaction would be the direct conversion of methane to methanol using oxygen as the oxidant: CH{sub 4} + 1/2O{sub 2} -> CH{sub 3}OH {Delta}H deg = - 30.7 kcal/mol. Such a direct oxidation route is manifest in the bacterially-mediated oxidation of methane by methanotrophic bacteria. These organisms effect the direct oxidation of methane to methanol by the enzyme methane monooxygenase (MMO) as part of the reaction sequences to oxidize methane to carbon dioxide. (14 refs.)

  12. The operational methane retrieval algorithm for TROPOMI

    OpenAIRE

    Hu, Haili; Hasekamp, Otto; Butz, André; Galli, André; Landgraf, Jochen; aan de Brugh, Joost; Borsdorff, Tobias; Scheepmaker, Remco; Aben, Ilse

    2016-01-01

    This work presents the operational methane retrieval algorithm for the Sentinel-5 Precursor (S5-P) satellite and its performance tested on realistic ensembles of simulated measurements. The target product is the column-averaged dry air volume mixing ratio of methane (XCH4), which will be retrieved simultaneously with scattering properties of the atmosphere. The algorithm attempts to fit spectra observed by the shortwave and near-infrared channels of the TROPOMI spectrometer aboard S5-P. ...

  13. Enhancement of methane production from barley waste

    OpenAIRE

    L. Neves; Ribeiro, R.; Oliveira, Rosário; Alves, M. M.

    2006-01-01

    Two different approaches were attempted to try and enhance methane production from an industrial waste composed of 100% barley, which results from production of instant coffee substitutes. In previous work, this waste was co-digested with an excess of activated sludge produced in the wastewater treatment plant located in same industrial unit, resulting in a very poor methane yield (25LCH4(STP)/ kgVSinitial), and low reductions in total solids (31%) and in volatile solids (40%). Wh...

  14. Prediction of enteric methane emissions from cattle.

    Science.gov (United States)

    Moraes, Luis E; Strathe, Anders B; Fadel, James G; Casper, David P; Kebreab, Ermias

    2014-07-01

    Agriculture has a key role in food production worldwide and it is a major component of the gross domestic product of several countries. Livestock production is essential for the generation of high quality protein foods and the delivery of foods in regions where animal products are the main food source. Environmental impacts of livestock production have been examined for decades, but recently emission of methane from enteric fermentation has been targeted as a substantial greenhouse gas source. The quantification of methane emissions from livestock on a global scale relies on prediction models because measurements require specialized equipment and may be expensive. The predictive ability of current methane emission models remains poor. Moreover, the availability of information on livestock production systems has increased substantially over the years enabling the development of more detailed methane prediction models. In this study, we have developed and evaluated prediction models based on a large database of enteric methane emissions from North American dairy and beef cattle. Most probable models of various complexity levels were identified using a Bayesian model selection procedure and were fitted under a hierarchical setting. Energy intake, dietary fiber and lipid proportions, animal body weight and milk fat proportion were identified as key explanatory variables for predicting emissions. Models here developed substantially outperformed models currently used in national greenhouse gas inventories. Additionally, estimates of repeatability of methane emissions were lower than the ones from the literature and multicollinearity diagnostics suggested that prediction models are stable. In this context, we propose various enteric methane prediction models which require different levels of information availability and can be readily implemented in national greenhouse gas inventories of different complexity levels. The utilization of such models may reduce errors

  15. Historical methyl mercury in San Francisco Bay

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — San Francisco Bay, California is considered a mercury-impaired watershed. Elevated concentrations of mercury are found in water and sediment as well as fish and...

  16. FL BAY SPECTROUT-POPULATION STATUS

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Juvenile spotted seatrout and other sportfish are being monitored annually over a 6-mo period in Florida Bay to assess their abundance over time relative to...

  17. South Bay Salt Ponds : Initial stewardship plan

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The California Department of Fish and Game and the U.S. Fish and Wildlife Service will operate and maintain the South Bay Salt Ponds under this Initial Stewardship...

  18. 2004 Saginaw Bay, Lake Huron, Michigan Lidar

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This metadata document describes the collection and processing of Light Detection and Ranging (LIDAR) data over an area along the coast of Saginaw Bay, Lake Huron,...

  19. Delaware River and Upper Bay Sediment Data

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The area of coverage consists of 192 square miles of benthic habitat mapped from 2005 to 2007 in the Delaware River and Upper Delaware Bay. The bottom sediment map...

  20. On Bayes' theorem for improper mixtures

    CERN Document Server

    McCullagh, Peter; 10.1214/11-AOS892

    2011-01-01

    Although Bayes's theorem demands a prior that is a probability distribution on the parameter space, the calculus associated with Bayes's theorem sometimes generates sensible procedures from improper priors, Pitman's estimator being a good example. However, improper priors may also lead to Bayes procedures that are paradoxical or otherwise unsatisfactory, prompting some authors to insist that all priors be proper. This paper begins with the observation that an improper measure on Theta satisfying Kingman's countability condition is in fact a probability distribution on the power set. We show how to extend a model in such a way that the extended parameter space is the power set. Under an additional finiteness condition, which is needed for the existence of a sampling region, the conditions for Bayes's theorem are satisfied by the extension. Lack of interference ensures that the posterior distribution in the extended space is compatible with the original parameter space. Provided that the key finiteness conditio...

  1. BENTHIC MACROFAUNAL ALIENS IN WILLAPA BAY

    Science.gov (United States)

    Benthic macrofaunal samples were collected at random stations in Willapa Bay, WA, in four habitats [eelgrass (Zostera marina), Atlantic cordgrass (Spartina alterniflora), mud shrimp (Upogebia pugettensis), ghost shrimp (Neotrypaea californiensis)] in 1996 and in seven habitats (Z...

  2. Underwater Video Transects in Jobos Bay

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Shallow-water (<30m) benthic habitat maps of the nearshore marine environment of Jobos Bay, Puerto Rico were mapped and characterized using visual interpretation...

  3. Underwater Video Sites in Jobos Bay

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Shallow-water (<30m) benthic habitat maps of the nearshore marine environment of Jobos Bay, Puerto Rico were mapped and characterized using visual interpretation...

  4. Hydrogeomorphic Regions in the Chesapeake Bay Watershed.

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Generalized lithology (rock type) and physiography based on geologic formations were used to characterize hydrgeomorphic regions (HGMR) within the Chesapeake Bay...

  5. Sediments of Buzzards Bay, MA (HOUGH40)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The modern sediments of Buzzards Bay are described principally by the use of quantitative data from mechanical analyses. The environment of the sediment and its...

  6. A Bayes but Not Classically Sufficient Statistic

    OpenAIRE

    Blackwell, D.; Ramamoorthi, R. V.

    1982-01-01

    In a Borel setting, every classically sufficient statistic is Bayes sufficient, but not vice versa. The example is a hypothesis testing problem in which Bayesians, but not classicists, can achieve zero error probabilities.

  7. Back Bay National Wildlife Refuge: Master Plan

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The Back Bay National Wildlife Refuge, located in the city of Virginia Beach, Virginia, comprises 4,608 acres of barrier beach, fresh and brackish marsh, small...

  8. Biscayne Bay Florida Bottlenose Dolphin Studies

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — These data sets include a compilation of small vessel based studies of bottlenose dolphins that reside within Biscayne Bay, Florida, adjacent estuaries and...

  9. Pb distribution and translocation in Jiaozhou Bay

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The trends of distribution, translocation and seasonal change of heavy metal Pb were studied based on the surface and bottom water sampling in Jiaozhou Bay in 1979, and compared with those in 1990's. The results showed that the source of Pb in the bay was from wastewater and sewage in the east of Jiaozhou Bay from ocean vessels. Pb concentration was higher in spring and lower in summer and autumn, and remained stable through sedimentation in the bottom layer. The overall water quality was good in 1970's. Compared with the environmental monitoring data of 1995-1999, Pb pollution had become serious. Therefore, more efforts should be made to protect the bay from Pb pollution.

  10. Back Bay Wilderness study : Public hearing analysis

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This document is an analysis of the public hearing that took place on May 15th, 1974 which discussed the Back Bay Wilderness. The analysis shows that there is...

  11. Back Bay Stormwater Monitoring Project Final Report

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The objective of this project was to assess the influx of nutrients and solid material into Back Bay and its tributaries during and immediately following such storm...

  12. Back Bay National Wildlife Refuge regulations

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This document is a collection of regulations pertaining to the Back Bay National Wildlife Refuge. Most of the regulations concern motor vehicle use on the refuge.

  13. Back Bay Wilderness study : Proposed recommendations

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This document is a list of recommendations for the proposed wilderness area on the Back Bay National Wildlife Refuge. The recommendations come as a result of the...

  14. Corpus ChristiEast Matagorda Bay 1986

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Patterns of habitat utilization were compared among transplanted and natural Spartina alterniflora marshes in the Halls Lake area of Chocolate Bay in the Galveston...

  15. How to Keep Bug Bites At Bay

    Science.gov (United States)

    ... gov/news/fullstory_160047.html How to Keep Bug Bites at Bay CDC offers advice on thwarting ... 23, 2016 SATURDAY, July 23, 2016 (HealthDay News) -- Bug bites can make you more than itchy. Ticks, ...

  16. Mercury distribution in the Jiaozhou Bay

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The Jiaozhou Bay is a semi-enclosed bay, Qingdao, China. More than 10 rivers enter the bay, of which most take wastes from industrial and household discharges. According to historical seasonal investigations in May, August, November 1979, the content,distribution, and development of heavy metal mercury are analyzed as a historical reference. Water samples were taken from the surface and bottom. The results revealed clear seasonal and regional changes in both horizontal and vertical directions, and close relation with major discharging rivers and plankton production. The seawater was polluted more seriously in spring than in any other seasons.However, it was the cleanest in winter during which least waste was input with low plankton production. According to historical data,the state of mercury pollution in seawater was worsening in the period, and has been improving in recent years. Terrestrial contamination was the main reason for mercury pollution in the bay.

  17. Habitat--Drakes Bay and Vicinity, California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This part of DS 781 presents data for the habitat map of the seafloor of the Drakes Bay and Vicinity map area, California. The vector data file is included in...

  18. Willapa Bay, Washington Benthic Habitats 1995 Substrate

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — In June 1995, the Columbia River Estuary Study Taskforce (CREST) acquired 295 true color aerial photographs (1:12,000) of Willapa Bay, Washington, from the State of...

  19. Willapa Bay, Washington Benthic Habitats 1995 Geodatabase

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — In June 1995, the Columbia River Estuary Study Taskforce (CREST) acquired 295 true color aerial photographs (1:12,000) of Willapa Bay, Washington, from the State of...

  20. Willapa Bay, Washington Benthic Habitats 1995 Geoform

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — In June 1995, the Columbia River Estuary Study Taskforce (CREST) acquired 295 true color aerial photographs (1:12,000) of Willapa Bay, Washington, from the State of...

  1. Willapa Bay, Washington Benthic Habitats 1995 Biotic

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — In June 1995, the Columbia River Estuary Study Taskforce (CREST) acquired 295 true color aerial photographs (1:12,000) of Willapa Bay, Washington, from the State of...

  2. San Antonio Bay 1986-1989

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The effect of salinity on utilization of shallow-water nursery habitats by aquatic fauna was assessed in San Antonio Bay, Texas. Overall, 272 samples were collected...

  3. Bayes Factors via Savage-Dickey Supermodels

    CERN Document Server

    Mootoovaloo, A; Kunz, M

    2016-01-01

    We outline a new method to compute the Bayes Factor for model selection which bypasses the Bayesian Evidence. Our method combines multiple models into a single, nested, Supermodel using one or more hyperparameters. Since the models are now nested the Bayes Factors between the models can be efficiently computed using the Savage-Dickey Density Ratio (SDDR). In this way model selection becomes a problem of parameter estimation. We consider two ways of constructing the supermodel in detail: one based on combined models, and a second based on combined likelihoods. We report on these two approaches for a Gaussian linear model for which the Bayesian evidence can be calculated analytically and a toy nonlinear problem. Unlike the combined model approach, where a standard Monte Carlo Markov Chain (MCMC) struggles, the combined-likelihood approach fares much better in providing a reliable estimate of the log-Bayes Factor. This scheme potentially opens the way to computationally efficient ways to compute Bayes Factors in...

  4. Methane Fingerprinting: Isotopic Methane and Ethane-to-Methane Ratio Analysis Using a Cavity Ring-Down Spectrometer

    Science.gov (United States)

    Saad, Nabil; Fleck, Derek; Hoffnagle, John

    2016-04-01

    Emissions of Natural gas, and methane (CH4) specifically, have come under increased scrutiny by virtue of methane's 28-36x greenhouse warming potential compared to carbon dioxide (CO2) while accounting for 10% of the total greenhouse gas emissions in the US. Large uncontrolled leaks, such as the recent Aliso Canyon leak, originating from uncapped wells, coal mines and storage facilities have increased the total global contribution of methane missions even further. Determining the specific fingerprint of methane sources, by quantifying δ13C values and C2:C1 ratios, provides the means to understand methane producing processes and allows for sources of methane to be mapped and classified through these processes; i.e. biogenic vs. thermogenic, wet vs dry. In this study we present a fully developed Cavity Ring-Down Spectrometer (CRDS) that precisely measures 12CH4 concentration and its 13CH4 isotope concentration, yielding δ13C measurements, C2H6 concentration, along with CO2 and H2O. This provides real-time continuous measurements without an upfront separation requirement or multiple analyses to derive the origin of the gas samples. The highly sensitive analyzer allows for measurements of scarce molecules down to sub-ppb 1-σ precision in 5 minutes of measurement: with CH4 <0.1ppb, δ13C <1‰ C2H6 <1ppb and CO2 <1ppm. To complement this work, we provide the analysis of different methane sources providing a 2-dimensional mapping of methane sources as functions of δ13C and C2:C1 ratios, which can be thought of as a modified Bernard Plot. This dual ratio mapping can be used to discriminate between naturally occurring biogenic methane sources, naturally occurring enriched thermogenic sources, and natural gas distribution sources. This also shows future promise in aiding gas and oil exploration, in distinguishing oil vs coal gases, as well as a valuable tool in the development of methane sequestration.

  5. Methane emission by adult ostriches (Struthio camelus).

    Science.gov (United States)

    Frei, Samuel; Dittmann, Marie T; Reutlinger, Christoph; Ortmann, Sylvia; Hatt, Jean-Michel; Kreuzer, Michael; Clauss, Marcus

    2015-02-01

    Ostriches (Struthio camelus) are herbivorous birds with a digestive physiology that shares several similarities with that of herbivorous mammals. Previous reports, however, claimed a very low methane emission from ostriches, which would be clearly different from mammals. If this could be confirmed, ostrich meat would represent a very attractive alternative to ruminant-and generally mammalian-meat by representing a particularly low-emission agricultural form of production. We individually measured, by chamber respirometry, the amount of oxygen consumed as well as carbon dioxide and methane emitted from six adult ostriches (body mass 108.3±8.3 kg) during a 24-hour period when fed a pelleted lucerne diet. While oxygen consumption was in the range of values previously reported for ostriches, supporting the validity of our experimental setup, methane production was, at 17.5±3.2 L d(-1), much higher than previously reported for this species, and was of the magnitude expected for similar-sized, nonruminant mammalian herbivores. These results suggest that methane emission is similar between ostriches and nonruminant mammalian herbivores and that the environmental burden of these animals is comparable. The findings furthermore indicate that it appears justified to use currently available scaling equations for methane production of nonruminant mammals in paleo-reconstructions of methane production of herbivorous dinosaurs. PMID:25446146

  6. Methane emission by adult ostriches (Struthio camelus).

    Science.gov (United States)

    Frei, Samuel; Dittmann, Marie T; Reutlinger, Christoph; Ortmann, Sylvia; Hatt, Jean-Michel; Kreuzer, Michael; Clauss, Marcus

    2015-02-01

    Ostriches (Struthio camelus) are herbivorous birds with a digestive physiology that shares several similarities with that of herbivorous mammals. Previous reports, however, claimed a very low methane emission from ostriches, which would be clearly different from mammals. If this could be confirmed, ostrich meat would represent a very attractive alternative to ruminant-and generally mammalian-meat by representing a particularly low-emission agricultural form of production. We individually measured, by chamber respirometry, the amount of oxygen consumed as well as carbon dioxide and methane emitted from six adult ostriches (body mass 108.3±8.3 kg) during a 24-hour period when fed a pelleted lucerne diet. While oxygen consumption was in the range of values previously reported for ostriches, supporting the validity of our experimental setup, methane production was, at 17.5±3.2 L d(-1), much higher than previously reported for this species, and was of the magnitude expected for similar-sized, nonruminant mammalian herbivores. These results suggest that methane emission is similar between ostriches and nonruminant mammalian herbivores and that the environmental burden of these animals is comparable. The findings furthermore indicate that it appears justified to use currently available scaling equations for methane production of nonruminant mammals in paleo-reconstructions of methane production of herbivorous dinosaurs.

  7. Biogeochemistry of Microbial Coal-Bed Methane

    Science.gov (United States)

    Strąpoć, Dariusz; Mastalerz, Maria; Dawson, Katherine; Macalady, Jennifer; Callaghan, Amy V.; Wawrik, Boris; Turich, Courtney; Ashby, Matthew

    2011-05-01

    Microbial methane accumulations have been discovered in multiple coal-bearing basins over the past two decades. Such discoveries were originally based on unique biogenic signatures in the stable isotopic composition of methane and carbon dioxide. Basins with microbial methane contain either low-maturity coals with predominantly microbial methane gas or uplifted coals containing older, thermogenic gas mixed with more recently produced microbial methane. Recent advances in genomics have allowed further evaluation of the source of microbial methane, through the use of high-throughput phylogenetic sequencing and fluorescent in situ hybridization, to describe the diversity and abundance of bacteria and methanogenic archaea in these subsurface formations. However, the anaerobic metabolism of the bacteria breaking coal down to methanogenic substrates, the likely rate-limiting step in biogenic gas production, is not fully understood. Coal molecules are more recalcitrant to biodegradation with increasing thermal maturity, and progress has been made in identifying some of the enzymes involved in the anaerobic degradation of these recalcitrant organic molecules using metagenomic studies and culture enrichments. In recent years, researchers have attempted lab and subsurface stimulation of the naturally slow process of methanogenic degradation of coal.

  8. A Glance at Bohai Bay Oil Province

    Institute of Scientific and Technical Information of China (English)

    Gao Shoubai

    1995-01-01

    @@ Chinese oil industry keeps on developing in 1994. The oil production of Bohai Bay Oil Province located in East China also keeps on growing. Geologically,the total area of Bohai Bay Basin is about 200 000 km2 and the main structural units are: Liaohe Depression, Huanghua Depression,Jizhong Depression, Linqing Depression, Jiyang Depression, Changwei Depression, Bozhong Depression,Chengning Uplift and Cangjing Uplift (see figure 1). Area of the main structural units is listed in following:

  9. The Daya Bay Reactor Neutrino Experiment

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    On Aug.15, 201l, a new large-scale scientific facility in China, Daya Bay Reactor Neutrino Experiment, started to operate. It is located in Daya Bay Nuclear Power Plant in Guangdong Province, around 50kin to both Hong Kong and Shenzhen City. The main scientific goal is to precisely determine the neutrino mixing angle 013 by detecting neutrinos from the reactors at different distances.

  10. Methane Fluxes from Subtropical Wetlands

    Science.gov (United States)

    DeLucia, N.; Gomez-Casanovas, N.; Bernacchi, C.

    2013-12-01

    It is well documented that green house gas concentrations have risen at unequivocal rates since the industrial revolution but the disparity between anthropogenic sources and natural sources is uncertain. Wetlands are one example of a natural ecosystem that can be a substantial source or sink for methane (CH4) depending on climate conditions. Due to strict anaerobic conditions required for CH4-generating microorganisms, natural wetlands are one of the main sources for biogenic CH4. Although wetlands occupy less than 5% of total land surface area, they contribute approximately 20% of total CH4 emissions to the atmosphere. The processes regulating CH4 emissions are sensitive to land use and management practices of areas surrounding wetlands. Variation in adjacent vegetation or grazing intensity by livestock can, for example, alter CH4 fluxes from wetland soils by altering nutrient balance, carbon inputs and hydrology. Therefore, understanding how these changes will affect wetland source strength is essential to understand the impact of wetland management practices on the global climate system. In this study we quantify wetland methane fluxes from subtropical wetlands on a working cattle ranch in central Florida near Okeechobee Lake (27o10'52.04'N, 81o21'8.56'W). To determine differences in CH4 fluxes associated with land use and management, a replicated (n = 4) full factorial experiment was designed for wetlands where the surrounding vegetation was (1) grazed or un-grazed and (2) composed of native vegetation or improved pasture. Net exchange of CH4 and CO2 between the land surface and the atmosphere were sampled with a LICOR Li-7700 open path CH4 analyzer and Li-7500A open path CO2/H20 analyzer mounted in a 1-m3 static gas-exchange chamber. Our results showed and verified that CH4 emissions from subtropical wetlands were larger when high soil moisture was coupled with high temperatures. The presence of cattle only amplified these results. These results help quantify

  11. Deriving Chesapeake Bay Water Quality Standards

    Science.gov (United States)

    Tango, Peter J.; Batiuk, Richard A.

    2013-01-01

    Achieving and maintaining the water quality conditions necessary to protect the aquatic living resources of the Chesapeake Bay and its tidal tributaries has required a foundation of quantifiable water quality criteria. Quantitative criteria serve as a critical basis for assessing the attainment of designated uses and measuring progress toward meeting water quality goals of the Chesapeake Bay Program partnership. In 1987, the Chesapeake Bay Program partnership committed to defining the water quality conditions necessary to protect aquatic living resources. Under section 303(c) of the Clean Water Act, States and authorized tribes have the primary responsibility for adopting water quality standards into law or regulation. The Chesapeake Bay Program partnership worked with U.S. Environmental Protection Agency to develop and publish a guidance framework of ambient water quality criteria with designated uses and assessment procedures for dissolved oxygen, water clarity, and chlorophyll a for Chesapeake Bay and its tidal tributaries in 2003. This article reviews the derivation of the water quality criteria, criteria assessment protocols, designated use boundaries, and their refinements published in six addendum documents since 2003 and successfully adopted into each jurisdiction's water quality standards used in developing the Chesapeake Bay Total Maximum Daily Load.

  12. Gradient Analysis and Classification of Carolina Bay Vegetation: A Framework for Bay Wetlands Conservation and Restoration

    Energy Technology Data Exchange (ETDEWEB)

    Diane De Steven,Ph.D.; Maureen Tone,PhD.

    1997-10-01

    This report address four project objectives: (1) Gradient model of Carolina bay vegetation on the SRS--The authors use ordination analyses to identify environmental and landscape factors that are correlated with vegetation composition. Significant factors can provide a framework for site-based conservation of existing diversity, and they may also be useful site predictors for potential vegetation in bay restorations. (2) Regional analysis of Carolina bay vegetation diversity--They expand the ordination analyses to assess the degree to which SRS bays encompass the range of vegetation diversity found in the regional landscape of South Carolina's western Upper Coastal Plain. Such comparisons can indicate floristic status relative to regional potentials and identify missing species or community elements that might be re-introduced or restored. (3) Classification of vegetation communities in Upper Coastal Plain bays--They use cluster analysis to identify plant community-types at the regional scale, and explore how this classification may be functional with respect to significant environmental and landscape factors. An environmentally-based classification at the whole-bay level can provide a system of templates for managing bays as individual units and for restoring bays to desired plant communities. (4) Qualitative model for bay vegetation dynamics--They analyze present-day vegetation in relation to historic land uses and disturbances. The distinctive history of SRS bays provides the possibility of assessing pathways of post-disturbance succession. They attempt to develop a coarse-scale model of vegetation shifts in response to changing site factors; such qualitative models can provide a basis for suggesting management interventions that may be needed to maintain desired vegetation in protected or restored bays.

  13. [Effect of temperature on methane production and oxidation in soils].

    Science.gov (United States)

    Ding, Weixin; Cai, Zucong

    2003-04-01

    The influence of temperature and its mechanism on methane production and oxidation in soils were reviewed in this paper. Temperature can alter the soil ability to produce methane through changing types of dominant methanogens in archaeal community. Dominant methanogen is Methanosarcinaceae at higher temperature which can utilize both H2/CO2 and acetate as the precursor to produce methane, while Methanosaetaceae at lower temperature which only use acetate as the precursor and produce far less methane than do Methanosarcinaceae. Increasing soil temperature apparently raises soil ability to produce methane, which is called temperature effectiveness and expressed as Q10 with a range from 1.5 to 28 and an average of 4.1. There is an obviously positive correlation between temperature effectiveness (Q10) on methane production and substrate content. As compared to methane production, effect of temperature on methane oxidation is lower, which may be related to the strong affinity of methanotrophs for methane.

  14. The Classification and Model of Coalbed Methane Reservoirs

    Institute of Scientific and Technical Information of China (English)

    SU Xianbo; LIN Xiaoying; SONG Yah; ZHAO Mengjun

    2004-01-01

    Coalbed methane has been explored in many basins worldwide for 30 years, and has been developed commercially in some of the basins. Many researchers have described the characteristics of coalbed methane geology and technology systematically. According to these investigations, a coalbed methane reservoir can be defined: "a coal seam that contains some coalbed methane and is isolated from other fluid units is called a coalbed methane reservoir".On the basis of anatomizafion, analysis, and comparison of the typical coalbed methane reservoirs, coalbed methane reservoirs can be divided into two classes: the hydrodynamic sealing coalbed methane reservoirs and the self-sealing coalbed methane reservoirs. The former can be further divided into two sub-classes: the hydrodynamic capping coalbed methane reservoirs, which can be divided into five types and the hydrodynamic driving coalbed methane reservoirs,which can be divided into three types. The latter can be divided into three types. Currently, hydrodynamic sealing reservoirs are the main target for coalbed methane exploration and development; self-sealing reservoirs are unsuitable for coalbed methane exploration and development, but they are closely related with coal mine gas hazards. Finally, a model for hydrodynamic sealing coalbed methane reservoirs is established.

  15. Atmospheric methane removal by methane-oxidizing bacteria immobilized on porous building materials.

    Science.gov (United States)

    Ganendra, Giovanni; De Muynck, Willem; Ho, Adrian; Hoefman, Sven; De Vos, Paul; Boeckx, Pascal; Boon, Nico

    2014-04-01

    Biological treatment using methane-oxidizing bacteria (MOB) immobilized on six porous carrier materials have been used to mitigate methane emission. Experiments were performed with different MOB inoculated in building materials at high (~20 % (v/v)) and low (~100 ppmv) methane mixing ratios. Methylocystis parvus in autoclaved aerated concrete (AAC) exhibited the highest methane removal rate at high (28.5 ± 3.8 μg CH₄ g⁻¹ building material h⁻¹) and low (1.7 ± 0.4 μg CH₄ g⁻¹ building material h⁻¹) methane mixing ratio. Due to the higher volume of pores with diameter >5 μm compared to other materials tested, AAC was able to adsorb more bacteria which might explain for the higher methane removal observed. The total methane and carbon dioxide-carbon in the headspace was decreased for 65.2 ± 10.9 % when M. parvus in Ytong was incubated for 100 h. This study showed that immobilized MOB on building materials could be used to remove methane from the air and also act as carbon sink. PMID:24337222

  16. High-pressure phase diagrams of methane + squalane and methane + hexatriacontane mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Marteau, P.; Tobaly, P. [CNRS, Villetaneuse (France). Lab. d`Ingenierie des Materiaux et des Hautes Pressions; Ruffier-Meray, V.; Hemptinne, J.C. de [Institut Francais du Petrole, Rueil-Malmaison (France)

    1998-05-01

    Thermodynamic properties of crude oils and natural gases are important for optimizing operating conditions. Equilibrium data on the methane + hexatriacontane mixture at (373, 398, 423, and 453) K and on the methane + squalane (2,6,10,15,19,23-hexamethyltetracosane) mixture at (323, 370, 420) K are reported. The apparatus and the near-infrared absorption method have been previously described.

  17. Methane, microbes and models: fundamental understanding of the soil methane cycle for future predictions.

    Science.gov (United States)

    Nazaries, Loïc; Murrell, J Colin; Millard, Pete; Baggs, Liz; Singh, Brajesh K

    2013-09-01

    Methane is an important greenhouse gas and microbes in the environment play major roles in both global methane emissions and terrestrial sinks. However, a full mechanistic understanding of the response of the methane cycle to global change is lacking. Recent studies suggest that a number of biological and environmental processes can influence the net flux of methane from soils to the atmosphere but the magnitude and direction of their impact are still debated. Here, we synthesize recent knowledge on soil microbial and biogeochemical process and the impacts of climate change factors on the soil methane cycle. We focus on (i) identification of the source and magnitude of methane flux and the global factors that may change the flux rate and magnitude in the future, (ii) the microbial communities responsible for methane production and terrestrial sinks, and (iii) how they will respond to future climatic scenarios and the consequences for feedback responses at a global scale. We also identify the research gaps in each of the topics identified above, provide evidence which can be used to demonstrate microbial regulation of methane cycle and suggest that incorporation of microbial data from emerging -omic technologies could be harnessed to increase the predictive power of simulation models. PMID:23718889

  18. 78 FR 45061 - Safety Zone; Sister Bay Marina Fest Fireworks and Ski Show, Sister Bay, WI

    Science.gov (United States)

    2013-07-26

    ... Department of Homeland Security FR Federal Register NPRM Notice of Proposed Rulemaking TFR Temporary Final... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA00 Safety Zone; Sister Bay Marina Fest Fireworks and Ski... intended to restrict vessels from a portion of Sister Bay due to a fireworks display and ski show....

  19. BOOK REVIEW OF "CHESAPEAKE BAY BLUES: SCIENCE, POLITICS, AND THE STRUGGLE TO SAVE THE BAY"

    Science.gov (United States)

    This is a book review of "Chesapeake Bay Blues: Science, Politics, and the Struggle to Save the Bay". This book is very well written and provides an easily understandable description of the political challenges faced by those proposing new or more stringent environmental regulat...

  20. 33 CFR 100.112 - Swim the Bay, Narragansett Bay, Narragansett, RI.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Swim the Bay, Narragansett Bay, Narragansett, RI. 100.112 Section 100.112 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY REGATTAS AND MARINE PARADES SAFETY OF LIFE ON NAVIGABLE WATERS § 100.112 Swim the...

  1. 75 FR 36292 - Safety Zone; Bay Swim III, Presque Isle Bay, Erie, PA

    Science.gov (United States)

    2010-06-25

    ... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA00 Safety Zone; Bay Swim III, Presque Isle Bay, Erie, PA... temporary safety zone for a swimming event in the Captain of the Port Buffalo zone. This rule is intended to... swimming event. DATES: This rule is effective from 9 a.m. to 11 a.m. on June 26, 2010. ADDRESSES:...

  2. 77 FR 39420 - Safety Zone; Bay Village Independence Day Fireworks, Lake Erie, Bay Village, OH

    Science.gov (United States)

    2012-07-03

    ...: Table of Acronyms DHS Department of Homeland Security FR Federal Register NPRM Notice of Proposed... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA00 Safety Zone; Bay Village Independence Day Fireworks... intended to restrict vessels from a portion of Lake Erie during the Bay Village Independence Day...

  3. 77 FR 35844 - Safety Zone; Olde Ellison Bay Days Fireworks Display, Ellison Bay, WI

    Science.gov (United States)

    2012-06-15

    ..., telephone 202-366-9826. SUPPLEMENTARY INFORMATION: Table of Acronyms DHS Department of Homeland Security FR..., Ellison Bay, WI AGENCY: Coast Guard, DHS. ACTION: Temporary final rule. SUMMARY: The Coast Guard is... held on Lake Michigan in Ellison Bay, WI. The Captain of the Port, Sector Lake Michigan has...

  4. 77 FR 44140 - Drawbridge Operation Regulation; Sturgeon Bay Ship Canal, Sturgeon Bay, WI

    Science.gov (United States)

    2012-07-27

    ...; Sturgeon Bay Ship Canal, Sturgeon Bay, WI, in the Federal Register (77 FR 21890). We did not receive any... final rule was published on October 24, 2005 in the Federal Register (70 FR 61380) to allow for one... published on June 5, 2009 in the Federal Register (74 FR 26954), effective from June 1, 2009 to November...

  5. Influence of headspace pressure on methane production in Biochemical Methane Potential (BMP) tests.

    Science.gov (United States)

    Valero, David; Montes, Jesús A; Rico, José Luis; Rico, Carlos

    2016-02-01

    The biochemical methane potential test is the most commonly applied method to determine methane production from organic wastes. One of the parameters measured is the volume of biogas produced which can be determined manometrically by keeping the volume constant and measuring increases in pressure. In the present study, the effect of pressure accumulation in the headspace of the reactors has been studied. Triplicate batch trials employing cocoa shell, waste coffee grounds and dairy manure as substrates have been performed under two headspace pressure conditions. The results obtained in the study showed that headspace overpressures higher than 600mbar affected methane production for waste coffee grounds. On the contrary, headspace overpressures within a range of 600-1000mbar did not affect methane production for cocoa shell and dairy manure. With the analyses performed in the present work it has not been possible to determine the reasons for the lower methane yield value obtained for the waste coffee grounds under high headspace pressures.

  6. Forest cockchafer larvae as methane production hotspots in soils and their importance for net soil methane fluxes

    Science.gov (United States)

    Görres, Carolyn-Monika; Kammann, Claudia; Murphy, Paul; Müller, Christoph

    2016-04-01

    Certain groups of soil invertebrates, namely scarab beetles and millipedes, are capable of emitting considerable amounts of methane due to methanogens inhabiting their gut system. It was already pointed out in the early 1990's, that these groups of invertebrates may represent a globally important source of methane. However, apart from termites, the importance of invertebrates for the soil methane budget is still unknown. Here, we present preliminary results of a laboratory soil incubation experiment elucidating the influence of forest cockchafer larvae (Melolontha hippocastani FABRICIUS) on soil methane cycling. In January/February 2016, two soils from two different management systems - one from a pine forest (extensive use) and one from a vegetable field (intensive use) - were incubated for 56 days either with or without beetle larvae. Net soil methane fluxes and larvae methane emissions together with their stable carbon isotope signatures were quantified at regular intervals to estimate gross methane production and gross methane oxidation in the soils. The results of this experiment will contribute to testing the hypothesis of whether methane production hotspots can significantly enhance the methane oxidation capacity of soils. Forest cockchafer larvae are only found in well-aerated sandy soils where one would usually not suspect relevant gross methane production. Thus, besides quantifying their contribution to net soil methane fluxes, they are also ideal organisms to study the effect of methane production hotspots on overall soil methane cycling. Funding support: Reintegration grant of the German Academic Exchange Service (DAAD) (#57185798).

  7. Methane converted to low emission energy

    International Nuclear Information System (INIS)

    A new project is underway at a major mine site in China to capture and use waste methane gas from coal mines. The three-year joint project will develop and demonstrate an innovative new Australian technology that captures harmful methane gas from coal mine ventilation air and uses it to produce low emission energy. The project will demonstrate that ventilation air from coal mines, which is largely untapped to date, can be safely captured to provide a source of electricity. An additional benefit of using ventilation air methane from coal mines is an increase in mine safety due to the reduced risk of gas explosions. The project is based on ventilation air methane catalytic combustion gas turbine (VAMCAT) technology. The project will fabricate a prototype demonstration unit and demonstrate the technology in a laboratory in Australia. Once tested in the laboratory the operational performance data and experience obtained will be used to design a 1% I methane turbine for demonstration at Huainan Mine, China. This project will develop technology that uses waste coal mine methane currently vented i into the atmosphere to create electricity and by doing so will reduce greenhouse gas emissions and improve mine safety. Development of this prototype will advance Australia's and China's capacity to reduce the potential greenhouse impact of coal through the development and deployment of VAMCAT technology as a practical solution for mitigating and utilising mine methane to generate power. The project will be implemented by the CSIRO with the Australian Government contributing a grant worth $350 000 to this $1.9 million project. Copyright (2006) Reed Business Information

  8. Spatially explicit methane inventory for Switzerland

    Science.gov (United States)

    Hiller, Rebecca; Bretscher, Daniel; DelSontro, Tonya; Eugster, Werner; Henne, Stephan; Henneberger, Ruth; Künzle, Thomas; Merbold, Lutz; Neininger, Bruno; Schellenberger, Andreas; Schroth, Martin; Buchmann, Nina; Brunner1, Dominik

    2013-04-01

    Spatially explicit greenhouse gas inventories are gaining in importance as a tool for policy makers to plan and control mitigation measures, and are a required input for atmospheric models used to relate atmospheric concentration measurements with upstream sources. In order to represent the high spatial heterogeneity in Switzerland, we compiled the national methane inventory into a 500 m x 500 m cadaster. In addition to the anthropogenic emissions reported to the United Nation Framework Convention on Climate Change (UNFCCC), we also included natural and semi-natural methane fluxes, i.e., emissions from lakes and reservoirs, wetlands, wild animals as well as forest uptake. Methane emissions were disaggregated according to geostatistical information about source location and extent. In Switzerland, highest methane emissions originate from the agricultural sector (152 Gg CH4 yr-1), followed by emissions from waste management (16 Gg CH4 yr-1) with highest contributions from landfills, and the energy sector (13 Gg CH4 yr-1) with highest contributions from the distribution of natural gas. Natural and semi-natural emissions only add a small amount (inventory was evaluated against methane concentrations measured from a small research aircraft (METAIR-DIMO) above the Swiss Plateau on 18 different days from May 2009 to August 2010 over. Source sensitivities of the air measured were determined by backward runs of the Lagrangian particle dispersion model FLEXPART-COSMO. Source sensitivities were multiplied with the methane inventory to derive simulated methane concentration time series. While the pattern of the variations can be reproduced well for some flight days (correlation coefficient up to 0.75), the amplitude of the variations for the simulated time series is underestimated by at least 20% suggesting an underestimation of CH4 emissions by the inventory, which is also concluded from inverse estimation using a Bayesian approach.

  9. Methane Hotspots in the Los Angeles Megacity

    Science.gov (United States)

    Hopkins, F. M.; Randerson, J. T.; Bush, S.; Ehleringer, J. R.; Lai, C.; Kort, E. A.; Blake, D. R.

    2013-12-01

    Airborne observations show that Los Angeles (LA) is a large source of methane to the atmosphere, yet the sources of excess methane from the urban area are poorly constrained. We used a mobile laboratory, a Ford Transit van equipped with cavity ring down spectrometers (Picarro, Inc.), to measure greenhouse gases (CH4, CO2, and CO) mole fractions in LA. On-road surveys across the LA Basin were conducted seasonally to determine patterns of CH4 enrichment in space and over time, with a focus on quantifying methane leaks from known sources. We found fugitive leaks and elevated CH4 concentrations throughout the LA Basin. Some were associated with known sources, such as landfills, wastewater treatment, and oil and gas infrastructure, while others had an unknown origin. Urban CH4 enrichment varied over the course of the year, largely due to seasonal changes in meteorological conditions. Nevertheless, our mobile surveys revealed CH4 hotspots (>200 ppb elevated with respect to background levels) that persisted among seasons. High CH4 concentrations were most easily predicted by proximity to methane sources, particularly near the coast, while elevated CH4 levels were more evenly dispersed in inland areas. CH4 hotspots had a disproportionate impact on excess methane relative to the area they accounted for, typically providing more than a quarter of excess methane measured on a transect. These data improve estimates of the relative roles of specific leaks and emission sectors to LA's excess methane. Depending on the cost of reducing these CH4 leaks, a focus on CH4 emissions may prove an effective way to reduce LA's greenhouse gas emissions in the near term.

  10. Upscaling methane emission hotspots in boreal peatlands

    Science.gov (United States)

    Cresto Aleina, Fabio; Runkle, Benjamin R. K.; Bruecher, Tim; Kleinen, Thomas; Brovkin, Victor

    2016-04-01

    Small-scale surface heterogeneities can influence land-atmosphere fluxes and therefore carbon, water and energy budgets on a larger scale. This effect is of particular relevance for high-latitude ecosystems, because of the great amount of carbon stored in their soils. Upscaling such small-scale surface heterogeneities and their effects to larger scales is a challenging issue in land surface modeling. We developed a novel approach to upscale local methane emissions in a boreal peatland from the micro-topographic scale to the landscape-scale. We based this parameterization on the analysis of the water table pattern generated by the Hummock-Hollow model (Cresto Aleina et al., 2015), a micro-topography resolving model for peatland hydrology and methane emissions. By computing the water table at the micro-topographic scale, the Hummock-Hollow model is able to describe the effects of micro-topography on hydrology and methane emissions in a typical boreal peatland. We introduce the new parameterization of methane hotspots in a global model-like version of the Hummock-Hollow model. This latter version underestimates methane emissions because of the lack of representation of micro-topographic controls on peatland hydrology. We tested the robustness of the parameterization by simulating methane emissions for the present day and for the next century, forcing the model with three different RCP scenarios. The Hotspot parameterization, despite being calibrated for the 1976-2005 climatology, mimics the output of the micro-topography resolving model for all the simulated scenarios. The new approach bridges the scale gap of methane emissions between this version of the model and the configuration explicitly resolving micro-topography.

  11. Bayes and empirical Bayes iteration estimators in two seemingly unrelated regression equations

    Institute of Scientific and Technical Information of China (English)

    WANG; Lichun

    2005-01-01

    For a system of two seemingly unrelated regression equations given by {y1=X1β+ε1,y2=X2γ+ε2, (y1 is an m × 1 vector and y2 is an n × 1 vector, m≠ n), employing the covariance adjusted technique, we propose the parametric Bayes and empirical Bayes iteration estimator sequences for regression coefficients. We prove that both the covariance matrices converge monotonically and the Bayes iteration estimator squence is consistent as well. Based on the mean square error (MSE) criterion, we elaborate the superiority of empirical Bayes iteration estimator over the Bayes estimator of single equation when the covariance matrix of errors is unknown. The results obtained in this paper further show the power of the covariance adjusted approach.

  12. Bayes and empirical-Bayes multiplicity adjustment in the variable-selection problem

    CERN Document Server

    Scott, James G; 10.1214/10-AOS792

    2010-01-01

    This paper studies the multiplicity-correction effect of standard Bayesian variable-selection priors in linear regression. Our first goal is to clarify when, and how, multiplicity correction happens automatically in Bayesian analysis, and to distinguish this correction from the Bayesian Ockham's-razor effect. Our second goal is to contrast empirical-Bayes and fully Bayesian approaches to variable selection through examples, theoretical results and simulations. Considerable differences between the two approaches are found. In particular, we prove a theorem that characterizes a surprising aymptotic discrepancy between fully Bayes and empirical Bayes. This discrepancy arises from a different source than the failure to account for hyperparameter uncertainty in the empirical-Bayes estimate. Indeed, even at the extreme, when the empirical-Bayes estimate converges asymptotically to the true variable-inclusion probability, the potential for a serious difference remains.

  13. Study on headland-bay sandy coast stability in South China coasts

    Science.gov (United States)

    Yu, Ji-Tao; Chen, Zi-Shen

    2011-03-01

    Headland-bay beach equilibrium planform has been a crucial problem abroad to long-term sandy beach evolution and stabilization, extensively applied to forecast long-term coastal erosion evolvement and the influences of coastal engineering as well as long-term coastal management and protection. However, little concern focuses on this in China. The parabolic relationship is the most widely used empirical relationship for determining the static equilibrium shape of headland-bay beaches. This paper utilizes the relation to predict and classify 31 headland-bay beaches and concludes that these bays cannot achieve the ultimate static equilibrium planform in South China. The empirical bay equation can morphologically estimate beach stabilization state, but it is just a referential predictable means and is difficult to evaluate headland-bay shoreline movements in years and decades. By using Digital Shoreline Analysis System suggested by USGS, the rates of shoreline recession and accretion of these different headland-bay beaches are quantitatively calculated from 1990 to 2000. The conclusions of this paper include that (a) most of these 31 bays maintain relatively stable and the rates of erosion and accretion are relatively large with the impact of man-made constructions on estuarine within these bays from 1990 to 2000; (b) two bays, Haimen Bay and Hailingshan Bay, originally in the quasi-static equilibrium planform determined by the parabolic bay shape equation, have been unstable by the influence of coastal engineering; and (c) these 31 bays have different recession and accretion characters occurring in some bays and some segments. On the one hand, some bays totally exhibit accretion, but some bays show erosion on the whole. Shanwei Bay, Houmen Bay, Pinghai Bay and Yazhou Bay have the similar planforms, characterized by less accretion on the sheltering segment and bigger accretion on the transitional and tangential segments. On the other hand, different segments of some

  14. Hierarchical Bayes Ensemble Kalman Filtering

    CERN Document Server

    Tsyrulnikov, Michael

    2015-01-01

    Ensemble Kalman filtering (EnKF), when applied to high-dimensional systems, suffers from an inevitably small affordable ensemble size, which results in poor estimates of the background error covariance matrix ${\\bf B}$. The common remedy is a kind of regularization, usually an ad-hoc spatial covariance localization (tapering) combined with artificial covariance inflation. Instead of using an ad-hoc regularization, we adopt the idea by Myrseth and Omre (2010) and explicitly admit that the ${\\bf B}$ matrix is unknown and random and estimate it along with the state (${\\bf x}$) in an optimal hierarchical Bayes analysis scheme. We separate forecast errors into predictability errors (i.e. forecast errors due to uncertainties in the initial data) and model errors (forecast errors due to imperfections in the forecast model) and include the two respective components ${\\bf P}$ and ${\\bf Q}$ of the ${\\bf B}$ matrix into the extended control vector $({\\bf x},{\\bf P},{\\bf Q})$. Similarly, we break the traditional backgrou...

  15. Physical processes in a coupled bay-estuary coastal system: Whitsand Bay and Plymouth Sound

    Science.gov (United States)

    Uncles, R. J.; Stephens, J. A.; Harris, C.

    2015-09-01

    Whitsand Bay and Plymouth Sound are located in the southwest of England. The Bay and Sound are separated by the ∼2-3 km-wide Rame Peninsula and connected by ∼10-20 m-deep English Channel waters. Results are presented from measurements of waves and currents, drogue tracking, surveys of salinity, temperature and turbidity during stratified and unstratified conditions, and bed sediment surveys. 2D and 3D hydrodynamic models are used to explore the generation of tidally- and wind-driven residual currents, flow separation and the formation of the Rame eddy, and the coupling between the Bay and the Sound. Tidal currents flow around the Rame Peninsula from the Sound to the Bay between approximately 3 h before to 2 h after low water and form a transport path between them that conveys lower salinity, higher turbidity waters from the Sound to the Bay. These waters are then transported into the Bay as part of the Bay-mouth limb of the Rame eddy and subsequently conveyed to the near-shore, east-going limb and re-circulated back towards Rame Head. The Simpson-Hunter stratification parameter indicates that much of the Sound and Bay are likely to stratify thermally during summer months. Temperature stratification in both is pronounced during summer and is largely determined by coastal, deeper-water stratification offshore. Small tidal stresses in the Bay are unable to move bed sediment of the observed sizes. However, the Bay and Sound are subjected to large waves that are capable of driving a substantial bed-load sediment transport. Measurements show relatively low levels of turbidity, but these respond rapidly to, and have a strong correlation with, wave height.

  16. Upscaling methane emission hotspots in boreal peatlands

    Directory of Open Access Journals (Sweden)

    F. Cresto Aleina

    2015-10-01

    Full Text Available Upscaling the properties and the effects of small-scale surface heterogeneities to larger scales is a challenging issue in land surface modeling. We developed a novel approach to upscale local methane emissions in a boreal peatland from the micro-topographic scale to the landscape-scale. We based this new parameterization on the analysis of the water table pattern generated by the Hummock–Hollow model, a micro-topography resolving model for peatland hydrology. We introduce this parameterization of methane hotspots in a global model-like version of the Hummock–Hollow model, that underestimates methane emissions. We tested the robustness of the parameterization by simulating methane emissions for the next century forcing the model with three different RCP scenarios. The Hotspot parameterization, despite being calibrated for the 1976–2005 climatology, mimics the output of the micro-topography resolving model for all the simulated scenarios. The new approach bridges the scale gap of methane emissions between this version of the model and the configuration explicitly resolving micro-topography.

  17. Changing Salinity Patterns in Biscayne Bay, Florida

    Science.gov (United States)

    ,

    2004-01-01

    Biscayne Bay, Fla., is a 428-square-mile (1,109-square-kilometer) subtropical estuarine ecosystem that includes Biscayne National Park, the largest marine park in the U.S. national park system (fig. 1). The bay began forming between 5,000 and 3,000 years ago as sea level rose and southern Florida was flooded. Throughout most of its history, the pristine waters of the bay supported abundant and diverse fauna and flora, and the bay was a nursery for the adjacent coral-reef and marine ecosystems. In the 20th century, urbanization of the Miami-Dade County area profoundly affected the environment of the bay. Construction of powerplants, water-treatment plants, and solid-waste sites and large-scale development along the shoreline stressed the ecosystem. Biscayne National Monument was established in 1968 to ?preserve and protect for the education, inspiration, recreation and enjoyment of present and future generations a rare combination of terrestrial, marine, and amphibious life in a tropical setting of great natural beauty? (Public Law 90?606). The monument was enlarged in 1980 and designated a national park.

  18. Hydrogen Recovery by ECR Plasma Pyrolysis of Methane Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Development of a microgravity and hypogravity compatible microwave plasma methane pyrolysis reactor is proposed to recover hydrogen which is lost as methane in the...

  19. [Research progress in microbial methane oxidation coupled to denitrification].

    Science.gov (United States)

    Zhu, Jing; Yuan, Meng-Dong; Liu, Jing-Jing; Huang, Xiao-Xiao; Wu, Wei-Xiang

    2013-12-01

    Methane oxidation coupled to denitrification is an essential bond to connect carbon- and nitrogen cycling. To deeply research this process will improve our understanding on the biochemical cycling of global carbon and nitrogen. As an exogenous gaseous carbon source of denitrification, methane can both regulate the balance of atmospheric methane to effectively mitigate the greenhouse effect caused by methane, and reduce the cost of exogenous carbon source input in traditional wastewater denitrification treatment process. As a result, great attention has being paid to the mechanical study of the process. This paper mainly discussed the two types of methane oxidation coupled to denitrification, i. e., aerobic methane oxidation coupled to denitrification (AME-D) and anaerobic methane oxidation coupled to denitrification (ANME-D), with the focus on the microbiological coupling mechanisms and related affecting factors. The existing problems in the engineering application of methane oxidation coupled to denitrification were pointed out, and the application prospects were approached. PMID:24697087

  20. The controls of methane emission from an Indian mangrove

    Science.gov (United States)

    Purvaja, R.; Ramesh, R.; Frenzel, P.

    2003-04-01

    Mangroves have been rated for a long time as a minor methane source, but recent reports have shown that polluted mangroves may emit substantial amounts of methane. In an Indian mangrove dominated by Avicennia marina we measured annual methane emission rates of 10 g methane/year, comparable to those from Northern wetlands. Methane emission from a freshwater-influenced area was higher, but lower from a stunted mangrove growing on a hypersaline soil, respectively. Methane emission was mediated by the pneumatophores of Avicennia. This was consistent with the methane concentration in the aerenchyma that decreased on average from 350 ppmv in the cable roots to 10 ppmv in the emergent part of the pneumatophores. The number of pneumatophores varied seasonally. During the monsoon floods less pneumatophores emerged from the water, reducing methane fluxes largely. Hence, CH4 emission was controlled via the pneumatophores by the water level.

  1. Methane emissions from enteric fermentation - effects of diet composition

    Energy Technology Data Exchange (ETDEWEB)

    Bertilsson, J. [Swedish Univ. of Agricultural Sciences, Dept. of Animal Nutrition and Management, Uppsala (Sweden)

    2002-10-01

    The formation of methane is an unavoidable result of the digestion of feeds by animals. Ruminants produce considerable amounts of methane. Cattle is the most important category of domestic ruminants in the Nordic countries. Feeding practice has considerable effect on the amount of methane produced, in general more concentrated feeds and a more intensive feeding will give less methane per kg of product (milk, beef). The separation between dairy and beef production might give a higher total methane production. Methane production can be determined experimentally using different methodologies. However, this is difficult and costly, and methane production is therefore most often calculated from knowledge about the animal production and the feeds used. Total amounts of methane produced can be decreased by manipulation of the feeding practice, but most of the methods have unacceptable consequences for environment or animal welfare. (au)

  2. Investigation on global warming gas methane; Ondanka gas methane ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    This paper summarizes the current status of research and development on generation of methane gas whose contribution to global warming is said to reach 18% as an atmospheric greenhouse effect gas. Systematization was made in the paper on the status of investigations and researches on different sources of methane gas. Measurement data are insufficient for swamplands, and amounts of methane generated in major swamplands in the world are being measured. Very few researches have been made on termites. Oceans were indicated that closed water areas are the sources of methane generation. Inland waters are in the stage of elucidating the methane generating mechanism. Methane hydrates are estimated being discharged from thawing of frozen soil. No measuring methods have yet been established for volcanic mountains. Discharge coefficient was sought for methane generation energies, and discharge amount in the global level was estimated from statistical data such as amount of production. With regard to agriculture, studies on mechanisms and measure technologies have been advanced on rumination of livestock. Data for paddy fields are being accumulated. Wastes have measurement data accumulated, and discussions are being made on discharge amount estimation and measure technologies. 30 refs., 32 figs., 28 tabs.

  3. Sediment grab data from October 1999 in Apalachicola Bay, Florida

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Apalachicola Bay National Estuarine Research Reserve and the NOAA Office for Coastal Management worked together to map benthic habitats within Apalachicola Bay,...

  4. Back Bay: Report on Salinity and Water Clarity in 1986

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Salinity, turbidity and various other water quality parameters were monitored monthly in 1986 at 24 stations on Back Bay. Results show Back Bay to be brackish (mean...

  5. Fishery Management Program Progress Report: Back Bay National Wildlife Refuge

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Memorandum containing summary of fishery biologist's visit to Back Bay to remove carp from impoundments at Back Bay National Wildlife Refuge.

  6. Biology and subsistence hunting of geese at Chagvan Bay

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Chagvan Bay and Nanvak Bay are known to be important staging and/or stopover areas for large numbers of Pacific Brant (Branta bernicola) and Emperor Geese (Chen...

  7. 33 CFR 110.127c - Trinidad Bay, Calif.

    Science.gov (United States)

    2010-07-01

    ... ANCHORAGE REGULATIONS Special Anchorage Areas § 110.127c Trinidad Bay, Calif. The waters of Trinidad Bay... floats and buoys for anchoring will be allowed in the area. Fixed moorings, piles or stakes...

  8. Benthic grab data from October 1999 in Apalachicola Bay, Florida

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Apalachicola Bay National Estuarine Research Reserve and the NOAA Office for Coastal Management worked together to map benthic habitats within Apalachicola Bay,...

  9. Parameter Identification by Bayes Decision and Neural Networks

    DEFF Research Database (Denmark)

    Kulczycki, P.; Schiøler, Henrik

    1994-01-01

    The problem of parameter identification by Bayes point estimation using neural networks is investigated.......The problem of parameter identification by Bayes point estimation using neural networks is investigated....

  10. Methane hydrates in nature - Current knowledge and challenges

    Science.gov (United States)

    Collett, Timothy S.

    2014-01-01

    Recognizing the importance of methane hydrate research and the need for a coordinated effort, the United States Congress enacted the Methane Hydrate Research and Development Act of 2000. At the same time, the Ministry of International Trade and Industry in Japan launched a research program to develop plans for a methane hydrate exploratory drilling project in the Nankai Trough. India, China, the Republic of Korea, and other nations also have established large methane hydrate research and development programs. Government-funded scientific research drilling expeditions and production test studies have provided a wealth of information on the occurrence of methane hydrates in nature. Numerous studies have shown that the amount of gas stored as methane hydrates in the world may exceed the volume of known organic carbon sources. However, methane hydrates represent both a scientific and technical challenge, and much remains to be learned about their characteristics and occurrence in nature. Methane hydrate research in recent years has mostly focused on: (1) documenting the geologic parameters that control the occurrence and stability of methane hydrates in nature, (2) assessing the volume of natural gas stored within various methane hydrate accumulations, (3) analyzing the production response and characteristics of methane hydrates, (4) identifying and predicting natural and induced environmental and climate impacts of natural methane hydrates, (5) analyzing the methane hydrate role as a geohazard, (6) establishing the means to detect and characterize methane hydrate accumulations using geologic and geophysical data, and (7) establishing the thermodynamic phase equilibrium properties of methane hydrates as a function of temperature, pressure, and gas composition. The U.S. Department of Energy (DOE) and the Consortium for Ocean Leadership (COL) combined their efforts in 2012 to assess the contributions that scientific drilling has made and could continue to make to advance

  11. Methanization of domestic and industrial wastes

    International Nuclear Information System (INIS)

    After having recalled that methanization helps meeting objectives of the Grenelle de l'Environnement regarding waste valorisation and production of renewable heat and electricity, this publication presents the methanization process which produces a humid product (digestate) and biogas by using various wastes (from agriculture, food industry, cities, households, sludge and so on). The numbers of existing and planned methanization units are evoked. The publication discusses the main benefits (production of renewable energy, efficient waste processing, and compact installations), drawbacks (costs, necessary specific abilities, impossibility to treat all organic materials) and associated recommendations. Actions undertaken by the ADEME are evoked. In conclusion, the publication outlines some priorities related to the development of this sector, its benefits, and the main strategic recommendations

  12. Methane production from marine microalgae Isochrysis galbana.

    Science.gov (United States)

    Santos, Nathalia O; Oliveira, Suzana M; Alves, Larissa C; Cammarota, Magali C

    2014-04-01

    Methane production from marine microalgae Isochrysis galbana was assessed before and after mechanical and chemical pretreatments. Mechanical pretreatment resulted in a 61.7% increase in soluble Chemical Oxygen Demand. Different hydrolysis conditions were evaluated by varying temperature - T, sulfuric acid concentration - AC and biomass suspension concentration (measured as particulate COD - CODp) using an experimental design. The most significant interaction occurred between AC and T and the hydrolysis condition that showed the best result in the anaerobic digestion step was the condition at 40°C with addition of 0.2% (v/v) acid for 16h (9.27LCH4/kgVS). The low methane yields were attributed to inhibitory sodium concentrations for anaerobic digestion. Eliminating inhibitory sodium in the anaerobic digestion by biomass prewashing, there was a 71.5% increase in methane yield for biomass after acid hydrolysis, demonstrating the need for pretreatment and reduction in sodium concentration in the anaerobic digestion.

  13. SCREENING TESTS FOR IMPROVED METHANE CRACKING MATERIALS

    Energy Technology Data Exchange (ETDEWEB)

    Klein, J; Jeffrey Holder, J

    2007-07-16

    Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{reg_sign} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 C, 101.3 kPa (760 torr) with a 10 sccm feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAES{reg_sign} getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas.

  14. Modelling Holocene carbon accumulation and methane emissions of boreal wetlands – an Earth system model approach

    Directory of Open Access Journals (Sweden)

    R. J. Schuldt

    2013-03-01

    Full Text Available Since the Last Glacial Maximum, boreal wetlands have accumulated substantial amounts of peat, estimated at 180–621 Pg of carbon. Wetlands have significantly affected the atmospheric greenhouse gas composition in the past and will play a significant role in future changes of atmospheric CO2 and CH4 concentrations. In order to investigate those changes with an Earth system model, biogeochemical processes in boreal wetlands need to be accounted for. Thus, a model of peat accumulation and decay was developed and included in the land surface model JSBACH of the Max Planck Institute Earth System Model (MPI-ESM. Here we present the evaluation of model results from 6000 yr BP to the pre-industrial period. Over this period of time, 240 Pg of peat carbon accumulated in the model in the areas north of 40° N. Simulated peat accumulation rates agree well with those reported for boreal wetlands. The model simulates CH4 emissions of 49.3 Tg CH4 yr−1 for 6000 yr BP and 51.5 Tg CH4 yr−1 for pre-industrial times. This is within the range of estimates in the literature, which range from 32 to 112 Tg CH4 yr−1 for boreal wetlands. The modelled methane emission for the West Siberian Lowlands and Hudson Bay Lowlands agree well with observations. The rising trend of methane emissions over the last 6000 yr is in agreement with measurements of Antarctic and Greenland ice cores.

  15. A four-helix bundle stores copper for methane oxidation

    OpenAIRE

    Vita, Nicholas; Platsaki, Semeli; Baslé, Arnaud; Allen, Stephen J; Paterson, Neil G.; Crombie, Andrew T.; Murrell, J Colin; Waldron, Kevin J.; Dennison, Christopher

    2015-01-01

    Methane-oxidising bacteria (methanotrophs) require large quantities of copper for the membrane-bound (particulate) methane monooxygenase (pMMO) 1,2 . Certain methanotrophs are also able to switch to using the iron-containing soluble MMO (sMMO) to catalyse methane oxidation, with this switchover regulated by copper 3,4 . MMOs are Nature’s primary biological mechanism for suppressing atmospheric levels of methane, a potent greenhouse gas. Furthermore, methanotrophs and MMOs have enormous potent...

  16. Analysis of methane biodegradation by Methylosinus trichosporium OB3b

    OpenAIRE

    Rodrigues, Andréa dos Santos; Salgado, Belkis Valdman e Andréa Medeiros

    2009-01-01

    The microbial oxidation of methane in the atmosphere is performed by methanotrophic bacteria that use methane as a unique source of carbon and energy. The objective of this work consisted of the investigation of the best conditions of methane biodegradation by methanotrophic bacteria Methylosinus trichosporium OB3b that oxidize it to carbon dioxide, and the use of these microorganisms in monitoring methods for methane. The results showed that M. trichosporium OB3b was capable to degrade metha...

  17. Methanol Improves Methane Uptake in Starved Methanotrophic Microorganisms

    OpenAIRE

    Jensen, Sigmund; Priemé, Anders; Bakken, Lars

    1998-01-01

    Methanotrophs in enrichment cultures grew and sustained atmospheric methane oxidation when supplied with methanol. If they were not supplied with methanol or formate, their atmospheric methane oxidation came to a halt, but it was restored within hours in response to methanol or formate. Indigenous forest soil methanotrophs were also dependent on a supply of methanol upon reduced methane access but only when exposed to a methane-free atmosphere. Their immediate response to each methanol additi...

  18. China's Development of Coalbed Methane Attracting World Attention

    Institute of Scientific and Technical Information of China (English)

    WANG Keyu

    1996-01-01

    @@ The worldwide environmental issue has been increasingly centered on the global warming climate because the ozone layer is devastated by emissions of carbon dioxide and other pollutants. Methane is the main element of the coalbed methane discharged in the process of coal exploitation. Methane is a high-effective and clean energy though the greenhouse effect of methane is 20 times larger than that of carbon dioxide.

  19. Preventing Coal and Gas Outburst Using Methane Hydration

    Institute of Scientific and Technical Information of China (English)

    吴强; 何学秋

    2003-01-01

    According to the characteristics of the methane hydrate condensing and accumulating methane, authors put forward a new technique thought way to prevent the accident of coal and gas outburst by urging the methane in the coal seams to form hydrate. The paper analyzes the feasibility of forming the methane hydrate in the coal seam from the several sides, such as, temperature,pressure, and gas components, and the primary trial results indicate the problems should be settled before the industrialization appliance realized.

  20. Tree-mediated methane emissions from tropical and temperate peatlands

    OpenAIRE

    S. R. Pangala; V. Gauci; E. R. C. Hornibrook; Gowing, D.J.

    2012-01-01

    Methane production and transport processes in peatlands are fairly well understood, but growing evidence for emission of methane through trees has highlighted the need to revisit methane transport processes. In wetland trees, morphological adaptations such as development of hypertrophied lenticels, aerenchyma and adventitious roots in response to soil anoxia mediates gas transport, transporting both oxygen from the atmosphere to oxygen-deprived roots and soil-produced methane from the root-zo...

  1. Origin of hydrogen in methane produced by Methanobacterium thermoautotrophicum.

    OpenAIRE

    Daniels, L; Fulton, G; Spencer, R W; Orme-Johnson, W H

    1980-01-01

    The production of deuterated methane by Methanobacterium thermoautotrophicum in H2O-D2O mixtures was examined by high-resolution mass spectrometry. The hydrogen in the methane arose solely from water and not from hydrogen gas. Hydrogen gas served only as an electron source in methanogenesis. A whole-cell product isotope discrimination of 1.5 favoring hydrogen over deuterium was observed in methane production in 81 atom% deuterated water. The distribution of deuterated methane species is descr...

  2. Printable enzyme-embedded materials for methane to methanol conversion

    OpenAIRE

    Craig D Blanchette; Knipe, Jennifer M.; Stolaroff, Joshuah K.; DeOtte, Joshua R.; Oakdale, James S.; Maiti, Amitesh; Lenhardt, Jeremy M.; Sirajuddin, Sarah; Rosenzweig, Amy C.; Baker, Sarah E.

    2016-01-01

    An industrial process for the selective activation of methane under mild conditions would be highly valuable for controlling emissions to the environment and for utilizing vast new sources of natural gas. The only selective catalysts for methane activation and conversion to methanol under mild conditions are methane monooxygenases (MMOs) found in methanotrophic bacteria; however, these enzymes are not amenable to standard enzyme immobilization approaches. Using particulate methane monooxygena...

  3. Bioconversion of methane to lactate by an obligate methanotrophic bacterium

    OpenAIRE

    Henard, Calvin A.; Holly Smith; Nancy Dowe; Marina G. Kalyuzhnaya; Philip T. Pienkos; Guarnieri, Michael T.

    2016-01-01

    Methane is the second most abundant greenhouse gas (GHG), with nearly 60% of emissions derived from anthropogenic sources. Microbial conversion of methane to fuels and value-added chemicals offers a means to reduce GHG emissions, while also valorizing this otherwise squandered high-volume, high-energy gas. However, to date, advances in methane biocatalysis have been constrained by the low-productivity and limited genetic tractability of natural methane-consuming microbes. Here, leveraging rec...

  4. Non-equilibrium Plasma Dehydrogenation Coupling of Methane

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A few factors effecting the reaction of plasma dehydrocoupling of methane have been investigated. The experiment shows that plasma power load, i.e. the ratio of methane flow to plasma power, is the most important factor effecting methane dehydrocoupling. The products of the reaction are mainly acetylene, ethylene, ethane and unreacted methane etc. If oxygen with a suitable molar ratio is introduced into plasma region at a reasonable position, the selectivity of C2 hydrocarbons can be increased greatly.

  5. Methane emissions from Earth’s degassing: Implications for Mars

    OpenAIRE

    Etiope, G.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Roma2, Roma, Italia; Oehler, D.Z.; Astromaterials ResearchandExplorationScience,NASA—Johnson SpaceCenter,2101NASAParkway,Houston,TX77058,USA; Allen, C.C.; Astromaterials ResearchandExplorationScience,NASA—Johnson SpaceCenter,2101NASAParkway,Houston,TX77058,USA

    2010-01-01

    The presence of methane on Mars is of great interest, since one possibility for its origin is that it derives from living microbes. However, CH4 in the martian atmosphere also could be attributable to geologic emissions released through pathways similar to those occurring on Earth. Using recent data on methane degassing of the Earth, we have estimated the relative terrestrial contributions of fossil geologic methane vs. modern methane from living methanogens, and have examined the significanc...

  6. Architecture and active site of particulate methane monooxygenase

    OpenAIRE

    Culpepper, Megen A.; Rosenzweig, Amy C.

    2012-01-01

    Particulate methane monooxygenase (pMMO) is an integral membrane metalloenzyme that oxidizes methane to methanol in methanotrophic bacteria, organisms that live on methane gas as their sole carbon source. Understanding pMMO function has important implications for bioremediation applications and for the development of new, environmentally friendly catalysts for the direct conversion of methane to methanol. Crystal structures of pMMOs from three different methanotrophs reveal a trimeric archite...

  7. Sulfide and methane production in sewer sediments.

    Science.gov (United States)

    Liu, Yiwen; Ni, Bing-Jie; Ganigué, Ramon; Werner, Ursula; Sharma, Keshab R; Yuan, Zhiguo

    2015-03-01

    Recent studies have demonstrated significant sulfide and methane production by sewer biofilms, particularly in rising mains. Sewer sediments in gravity sewers are also biologically active; however, their contribution to biological transformations in sewers is poorly understood at present. In this study, sediments collected from a gravity sewer were cultivated in a laboratory reactor fed with real wastewater for more than one year to obtain intact sediments. Batch test results show significant sulfide production with an average rate of 9.20 ± 0.39 g S/m(2)·d from the sediments, which is significantly higher than the areal rate of sewer biofilms. In contrast, the average methane production rate is 1.56 ± 0.14 g CH4/m(2)·d at 20 °C, which is comparable to the areal rate of sewer biofilms. These results clearly show that the contributions of sewer sediments to sulfide and methane production cannot be ignored when evaluating sewer emissions. Microsensor and pore water measurements of sulfide, sulfate and methane in the sediments, microbial profiling along the depth of the sediments and mathematical modelling reveal that sulfide production takes place near the sediment surface due to the limited penetration of sulfate. In comparison, methane production occurs in a much deeper zone below the surface likely due to the better penetration of soluble organic carbon. Modelling results illustrate the dependency of sulfide and methane productions on the bulk sulfate and soluble organic carbon concentrations can be well described with half-order kinetics.

  8. Numerical Simulation of Tidal Current in a Bay

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    -Based on the multilevel model, numerical calculations of tidal current affected by the M2 tide in the Tokyo Bay have been carried out. The results of calculation are compared with the data observed in the Tokyo Bay and the result calculated by an approximate formula as the Tokyo Bay is regarded as a rectangular bay, and good agreement is found. It is proved that the mathematical model and the calculation method are correct and useable

  9. Assessment of contamination in the Shuttle bay

    Science.gov (United States)

    Jeffery, J. A.; Maag, C. R.; Seastrom, J. W.; Weber, M. F.

    1982-01-01

    The results of an analytical study to determine the contamination potential of the Galileo probe instruments while in the STS bay are presented. The study covered conditions wherein the instruments weren't covered, covers were used with vent paths of varying sizes, and if the instruments were sealed and a nitrogen purge was employed. The contamination limits for each of the Galileo instruments are considered. Analytic approximations are devised for the diffusion of particles from surfaces and materials in the Shuttle bay during the ascent phase, using Fick's second law of diffusion. It is recommended that an instrument purge be implemented during the first 15 min of Shuttle flight in order to carry the contaminants from both the bay fixtures and from the instruments into space. Covers are suggested as necessary for the most sensitive instruments.

  10. Bayes' theorem: scientific assessment of experience

    Directory of Open Access Journals (Sweden)

    Lex Rutten

    2010-10-01

    Full Text Available Homeopathy is based on experience and this is a scientific procedure if we follow Bayes' theorem. Unfortunately this is not the case at the moment. Symptoms are added to our materia medica based on absolute occurrence, while Bayes theorem tells us that this should be based on relative occurrence. Bayes theorem can be applied on prospective research, but also on retrospective research and consensus based on a large number of cases. Confirmation bias is an important source of false data in experience based systems like homeopathy. Homeopathic doctors should become more aware of this and longer follow-up of cases could remedy this. The existing system of adding symptoms to our materia medica is obsolete.

  11. Endocrine disrupter - estradiol - in Chesapeake Bay tributaries

    Energy Technology Data Exchange (ETDEWEB)

    Dorabawila, Nelum [University of Maryland Eastern Shore, Princess Anne, MD 21853 (United States); Gupta, Gian [University of Maryland Eastern Shore, Princess Anne, MD 21853 (United States)]. E-mail: gcgupta@umes.edu

    2005-04-11

    Exogenous chemicals that interfere with natural hormonal functions are considered endocrine disrupting chemicals (EDCs). Estradiol (17{beta}-estradiol or E2) is the most potent of all xenoestrogens. Induction of vitellogenin (VTG) production in male fish occurs at E2 concentrations as low as 1 ng l{sup -1}. E2 reaches aquatic systems mainly through sewage and animal waste disposal. Surface water samples from ponds, rivers (Wicomico, Manokin and Pocomoke), sewage treatment plants (STPs), and coastal bays (Assawoman, Monie, Chincoteague, and Tangier Sound - Chesapeake Bay) on the Eastern Shore of Maryland were analyzed for E2 using enzyme linked immuno-sorbent assay (ELISA). E2 concentrations in river waters varied between 1.9 and 6.0 ng l{sup -1}. Highest E2 concentrations in river waters were observed immediately downstream of STPs. E2 concentrations in all the coastal bays tested were 2.3-3.2 ng l{sup -1}.

  12. Method for the production of methanation catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Hammer, H.; Hakim, I.

    1976-11-18

    A methanation catalyst is claimed which is produced by precipitation of nickel salts from alcoholic solutions. At the same time, these solutions contain aluminium or magnesium compounds and, in some cases, also a carrier medium. The precipitation agents are alkali boron hydride solutions and alkali carbonate solutions. The precipitate, which is preferably obtained at temperatures between -5 and +5/sup 0/C, consists of a fine mixture of nickel boride, oxide hydrates, and hydroxides of nickel, magnesium, or aluminium. In contrast to the known nickel catalyst masses, it may be processed in air without inert gas. Four examples of preparations with suitable methanation tests are given.

  13. Scattering of Slow Neutrons by Gaseous Methane

    International Nuclear Information System (INIS)

    Slow neutron scattering by molecular gases is discussed. The most detailed comparison between theoretical and experimental results has been on gaseous methane which shows conclusively that the quantum nature of the rotational levels must be explicitly taken into account to obtain agreement with the experimental results. It is also shown theoretically that interference scattering, that is interference scattering between two distinct atoms of the molecule, has an effect which can be observed. This effect has been observed experimentally in methane and apparently also for propane. It is pointed out that the theory makes quite definite predictions at smaller momentum transfers than has been measured. Thus experiments at smaller momentum transfers are needed. (author)

  14. Methane recovery from landfill in China

    Energy Technology Data Exchange (ETDEWEB)

    Gaolai, L.

    1996-12-31

    GEF has approved a special project for a demonstration project for Methane Recovery from the Urban Refuse Land Fill. This paper will introduce the possibility of GHG reduction from the landfill in China, describe the activities of the GEF project, and the priorities for international cooperation in this field. The Global Environment Facility (GEF) approved the project, China Promoting Methane Recovery and Unlization from Mixed Municipal Refuse, at its Council meeting in last April. This project is the first one supported by international organization in this field.

  15. Biochemical Methane Potential of Agro Wastes

    OpenAIRE

    Vidhya Prabhudessai; Anasuya Ganguly; Srikanth Mutnuri

    2013-01-01

    The focus of our work is on anaerobic digestion of locally available agro wastes like coconut oil cake, cashew apple waste, and grass from lawn cuttings. The most productive agro waste, in terms of methane yield, was coconut oil cake and grass. The results showed that the initial volatile solids concentration significantly affected the biogas production. The methane yield from coconut oil cake was found to be 383 ml CH4/g VS and 277 ml CH4/g VS added at 4 and 4.5 g VS/l. In case of grass the...

  16. Contribution of methane to aerosol carbon mass

    Science.gov (United States)

    Bianchi, F.; Barmet, P.; Stirnweis, L.; El Haddad, I.; Platt, S. M.; Saurer, M.; Lötscher, C.; Siegwolf, R.; Bigi, A.; Hoyle, C. R.; DeCarlo, P. F.; Slowik, J. G.; Prévôt, A. S. H.; Baltensperger, U.; Dommen, J.

    2016-09-01

    Small volatile organic compounds (VOC) such as methane (CH4) have long been considered non-relevant to aerosol formation due to the high volatility of their oxidation products. However, even low aerosol yields from CH4, the most abundant VOC in the atmosphere, would contribute significantly to the total particulate carbon budget. In this study, organic aerosol (OA) mass yields from CH4 oxidation were evaluated at the Paul Scherrer Institute (PSI) smog chamber in the presence of inorganic and organic seed aerosols. Using labeled 13C methane, we could detect its oxidation products in the aerosol phase, with yields up to 0.09

  17. Adiabatic Flame Temperature for Combustion of Methane

    Directory of Open Access Journals (Sweden)

    Rebeca Pupo

    2011-01-01

    Full Text Available This project calculated the adiabatic flame temperature of a combustion reaction of pure methane and oxygen, assuming that all of the heat liberated by the combustion reaction goes into heating the resulting mixture. Mole fractions of methane to oxygen were computed from 0.05 to 0.95, in increments of 0.05, and then an integral was computed was computed with respect to temperature using the moles of product produced or leftover moles of reactants from the starting mole fraction times the specific heat of each respective gas. The highest adiabatic flame temperature evaluated, occurred at a mole fraction of 0.35.

  18. Aquatic herbivores facilitate the emission of methane from wetlands

    NARCIS (Netherlands)

    Dingemans, B.J.J.; Bakker, E.S.; Bodelier, P.L.E.

    2011-01-01

    Wetlands are significant sources of atmospheric methane. Methane produced by microbes enters roots and escapes to the atmosphere through the shoots of emergent wetland plants. Herbivorous birds graze on helophytes, but their effect on methane emission remains unknown. We hypothesized that grazing on

  19. Methane oxidation coupled to oxygenic photosynthesis in anoxic waters.

    Science.gov (United States)

    Milucka, Jana; Kirf, Mathias; Lu, Lu; Krupke, Andreas; Lam, Phyllis; Littmann, Sten; Kuypers, Marcel M M; Schubert, Carsten J

    2015-09-01

    Freshwater lakes represent large methane sources that, in contrast to the Ocean, significantly contribute to non-anthropogenic methane emissions to the atmosphere. Particularly mixed lakes are major methane emitters, while permanently and seasonally stratified lakes with anoxic bottom waters are often characterized by strongly reduced methane emissions. The causes for this reduced methane flux from anoxic lake waters are not fully understood. Here we identified the microorganisms and processes responsible for the near complete consumption of methane in the anoxic waters of a permanently stratified lake, Lago di Cadagno. Interestingly, known anaerobic methanotrophs could not be detected in these waters. Instead, we found abundant gamma-proteobacterial aerobic methane-oxidizing bacteria active in the anoxic waters. In vitro incubations revealed that, among all the tested potential electron acceptors, only the addition of oxygen enhanced the rates of methane oxidation. An equally pronounced stimulation was also observed when the anoxic water samples were incubated in the light. Our combined results from molecular, biogeochemical and single-cell analyses indicate that methane removal at the anoxic chemocline of Lago di Cadagno is due to true aerobic oxidation of methane fuelled by in situ oxygen production by photosynthetic algae. A similar mechanism could be active in seasonally stratified lakes and marine basins such as the Black Sea, where light penetrates to the anoxic chemocline. Given the widespread occurrence of seasonally stratified anoxic lakes, aerobic methane oxidation coupled to oxygenic photosynthesis might have an important but so far neglected role in methane emissions from lakes. PMID:25679533

  20. Developments of coalbed methane development in the U.S.

    Institute of Scientific and Technical Information of China (English)

    渠祁; 赵俊; 郭华

    2001-01-01

    After decades of development and technology advancement, coalbed methane has become an important source for U.S. energy consumption. Especial in recent year, U.S. coalbed methane production continues its healthy growth rate of about 10% per year. The paper takes emphasis on the technology developments and the engineering approaches of coalbed methane in the U.S.

  1. Developments of coalbed methane development in the U.S.

    Institute of Scientific and Technical Information of China (English)

    QU Qi; ZHAO Jun; GUO Hua

    2001-01-01

    After decades of development and technology advancem ent, coalbed methane has become an important source for U.S. energy consumption . Especial in recent year, U.S. coalbed methane production continues its health y growth rate of about 10% per year. The paper takes emphasis on the technology developments and the engineering approaches of coalbed methane in the U.S.

  2. 40 CFR 86.1325-94 - Methane analyzer calibration.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Methane analyzer calibration. 86.1325... Procedures § 86.1325-94 Methane analyzer calibration. Prior to introduction into service and monthly thereafter, the methane analyzer shall be calibrated: (a) Follow the manufacturer's instructions...

  3. 30 CFR 75.1106-1 - Test for methane.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Test for methane. 75.1106-1 Section 75.1106-1... MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES Fire Protection § 75.1106-1 Test for methane. Until December 31, 1970, a permissible flame safety lamp may be used to make tests for methane required by...

  4. 40 CFR 86.125-94 - Methane analyzer calibration.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Methane analyzer calibration. 86.125... Complete Heavy-Duty Vehicles; Test Procedures § 86.125-94 Methane analyzer calibration. Prior to introduction into service and monthly thereafter, the methane analyzer shall be calibrated: (a) Follow...

  5. METHANE EMISSIONS FROM WETLAND RICE AREAS OF ASIA

    Science.gov (United States)

    Kahlil and Rasmussen (1990) reviewed eleven global methane budgets published between 1978 and 1988. hey found methane emissions from rice paddies ranged from 18 to 280 Tg year-1 which correspond to between 10 and 70% of the total anthropogenic methane emissions. or this paper, we...

  6. A marine microbial consortium apparently mediating anaerobic oxidation of methane

    DEFF Research Database (Denmark)

    Boetius, A.; Ravenschlag, K.; Schubert, CJ;

    2000-01-01

    A large fraction of globally produced methane is converted to CO2 by anaerobic oxidation in marine sediments(1). Strong geochemical evidence for net methane consumption in anoxic sediments is based on methane profiles(2), radiotracer experiments(3) and stable carbon isotope data(4). But the elusive...

  7. Methane biofiltration using Autoclaved Aerated Concrete as the carrier material

    NARCIS (Netherlands)

    Ganendra, Giovanni; Mercado-Garcia, Daniel; Hernandez-Sanabria, Emma; Boeckx, P.; Ho, Adrian; Boon, N.

    2015-01-01

    The methane removal capacity of mixed methane-oxidizing bacteria (MOB) culture in a biofilter setup using autoclaved aerated concrete (AAC) as a highly porous carrier material was tested. Batch experiment was performed to optimize MOB immobilization on AAC specimens where optimum methane removal was

  8. The Methanizer: A Small Scale Biogas Reactor for a Restaurant

    NARCIS (Netherlands)

    Vasudevan, R.; Karlsson, O.; Dhejne, K.; Derewonko, P.; Brezet, J.C.

    2010-01-01

    The purpose of this study is to determine the technical and economic feasibility of a smallscale bioreactor called the Methanizer for a restaurant. The bioreactor converts organic waste produced by the restaurant into methane. This methane can be used to power the restaurant’s cooking stoves. The sy

  9. 46 CFR 154.1854 - Methane (LNG) as fuel.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Methane (LNG) as fuel. 154.1854 Section 154.1854... STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Operations § 154.1854 Methane (LNG) as fuel. (a) If methane (LNG) vapors are used as fuel in the main propulsion system of a vessel,...

  10. Migratory birds and marine mammals of the Bristol Bay region: Wildlife narratives for the Bristol Bay Cooperative Management Plan

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This is a collection of reports on migratory birds and marine mammals of the Bristol Bay region for the purpose of facilitating the planning process in Bristol Bay....

  11. Empirical Bayes analysis of single nucleotide polymorphisms

    Directory of Open Access Journals (Sweden)

    Ickstadt Katja

    2008-03-01

    Full Text Available Abstract Background An important goal of whole-genome studies concerned with single nucleotide polymorphisms (SNPs is the identification of SNPs associated with a covariate of interest such as the case-control status or the type of cancer. Since these studies often comprise the genotypes of hundreds of thousands of SNPs, methods are required that can cope with the corresponding multiple testing problem. For the analysis of gene expression data, approaches such as the empirical Bayes analysis of microarrays have been developed particularly for the detection of genes associated with the response. However, the empirical Bayes analysis of microarrays has only been suggested for binary responses when considering expression values, i.e. continuous predictors. Results In this paper, we propose a modification of this empirical Bayes analysis that can be used to analyze high-dimensional categorical SNP data. This approach along with a generalized version of the original empirical Bayes method are available in the R package siggenes version 1.10.0 and later that can be downloaded from http://www.bioconductor.org. Conclusion As applications to two subsets of the HapMap data show, the empirical Bayes analysis of microarrays cannot only be used to analyze continuous gene expression data, but also be applied to categorical SNP data, where the response is not restricted to be binary. In association studies in which typically several ten to a few hundred SNPs are considered, our approach can furthermore be employed to test interactions of SNPs. Moreover, the posterior probabilities resulting from the empirical Bayes analysis of (prespecified interactions/genotypes can also be used to quantify the importance of these interactions.

  12. Lost lake - restoration of a Carolina bay

    Energy Technology Data Exchange (ETDEWEB)

    Hanlin, H.G.; McLendon, J.P. [Univ. of South Carolina, Aiken, SC (United States). Dept. of Biology and Geology; Wike, L.D. [Univ. of South Carolina, Aiken, SC (United States). Dept. of Biology and Geology]|[Westinghouse Savannah River Co., Aiken, SC (United States). Savannah River Technology Center; Dietsch, B.M. [Univ. of South Carolina, Aiken, SC (United States). Dept. of Biology and Geology]|[Univ. of Georgia, Aiken, SC (United States)

    1994-09-01

    Carolina bays are shallow wetland depressions found only on the Atlantic Coastal Plain. Although these isolated interstream wetlands support many types of communities, they share the common features of having a sandy margin, a fluctuating water level, an elliptical shape, and a northwest to southeast orientation. Lost Lake, an 11.3 hectare Carolina bay, was ditched and drained for agricultural production before establishment of the Savannah River Site in 1950. Later it received overflow from a seepage basin containing a variety of chemicals, primarily solvents and some heavy metals. In 1990 a plan was developed for the restoration of Lost Lake, and restoration activities were complete by mid-1991. Lost Lake is the first known project designed for the restoration and recovery of a Carolina bay. The bay was divided into eight soil treatment zones, allowing four treatments in duplicate. Each of the eight zones was planted with eight species of native wetland plants. Recolonization of the bay by amphibians and reptiles is being evaluated by using drift fences with pitfall traps and coverboard arrays in each of the treatment zones. Additional drift fences in five upland habitats were also established. Hoop turtle traps, funnel minnow traps, and dip nets were utilized for aquatic sampling. The presence of 43 species common to the region has been documented at Lost Lake. More than one-third of these species show evidence of breeding populations being established. Three species found prior to the restoration activity and a number of species common to undisturbed Carolina bays were not encountered. Colonization by additional species is anticipated as the wetland undergoes further succession.

  13. Mapping Oyster Reef Habitats in Mobile Bay

    Science.gov (United States)

    Bolte, Danielle

    2011-01-01

    Oyster reefs around the world are declining rapidly, and although they haven t received as much attention as coral reefs, they are just as important to their local ecosystems and economies. Oyster reefs provide habitats for many species of fish, invertebrates, and crustaceans, as well as the next generations of oysters. Oysters are also harvested from many of these reefs and are an important segment of many local economies, including that of Mobile Bay, where oysters rank in the top five commercial marine species both by landed weight and by dollar value. Although the remaining Mobile Bay oyster reefs are some of the least degraded in the world, projected climate change could have dramatic effects on the health of these important ecosystems. The viability of oyster reefs depends on water depth and temperature, appropriate pH and salinity levels, and the amount of dissolved oxygen in the water. Projected increases in sea level, changes in precipitation and runoff patterns, and changes in pH resulting from increases in the amount of carbon dioxide dissolved in the oceans could all affect the viability of oyster reefs in the future. Human activities such as dredging and unsustainable harvesting practices are also adversely impacting the oyster reefs. Fortunately, several projects are already under way to help rebuild or support existing or previously existing oyster reefs. The success of these projects will depend on the local effects of climate change on the current and potential habitats and man s ability to recognize and halt unsustainable harvesting practices. As the extent and health of the reefs changes, it will have impacts on the Mobile Bay ecosystem and economy, changing the resources available to the people who live there and to the rest of the country, since Mobile Bay is an important national source of seafood. This project identified potential climate change impacts on the oyster reefs of Mobile Bay, including the possible addition of newly viable

  14. Constraining Methane Abundance and Cloud Properties from the Reflected Light Spectra of Directly Imaged Exoplanets

    Science.gov (United States)

    Lupu, R.; Marley, M. S.; Lewis, N. K.

    2015-12-01

    We have assembled an atmospheric retrieval package for the reflected light spectra of gas- and ice- giants in order to inform the design and estimate the scientific return of future space-based coronagraph instruments. Such instruments will have a working bandpass of ~0.4-1 μm and a resolving power R~70, and will enable the characterization of tens of exoplanets in the Solar neighborhood. The targets will be chosen form known RV giants, with estimated effective temperatures of ~100-600 K and masses between 0.3 and 20 MJupiter. In this regime, both methane and clouds will have the largest effects on the observed spectra. Our retrieval code is the first to include cloud properties in the core set of parameters, along with methane abundance and surface gravity. We consider three possible cloud structure scenarios, with 0, 1 or 2 cloud layers, respectively. The best-fit parameters for a given model are determined using a Monte Carlo Markov Chain ensemble sampler, and the most favored cloud structure is chosen by calculating the Bayes factors between different models. We present the performance of our retrieval technique applied to a set of representative model spectra, covering a SNR range form 5 to 20 and including possible noise correlations over a 25 or 100 nanometer scale. Further, we apply the technique to more realistic cases, namely simulated observations of Jupiter, Saturn, Uranus, and the gas-giant HD99492c. In each case, we determine the confidence levels associated with the methane and cloud detections, as a function of SNR and noise properties.

  15. 33 CFR 80.1106 - Mission Bay, CA.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Mission Bay, CA. 80.1106 Section 80.1106 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Coast § 80.1106 Mission Bay, CA. A line drawn from Mission Bay South Jetty Light 2 to Mission...

  16. 33 CFR 80.1150 - Arcata-Humboldt Bay, CA.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Arcata-Humboldt Bay, CA. 80.1150 Section 80.1150 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Coast § 80.1150 Arcata-Humboldt Bay, CA. A line drawn from Humboldt Bay Entrance Light 4...

  17. 33 CFR 80.1112 - Newport Bay, CA.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Newport Bay, CA. 80.1112 Section 80.1112 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Coast § 80.1112 Newport Bay, CA. A line drawn from Newport Bay East Jetty Light 4 to Newport...

  18. 46 CFR 151.03-33 - Lakes, bays, and sounds.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Lakes, bays, and sounds. 151.03-33 Section 151.03-33... CARRYING BULK LIQUID HAZARDOUS MATERIAL CARGOES Definitions § 151.03-33 Lakes, bays, and sounds. A designation for all vessels navigating the waters of any of the lakes, bays, or sounds other than the...

  19. 46 CFR 188.10-39 - Lakes, bays, and sounds.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Lakes, bays, and sounds. 188.10-39 Section 188.10-39... PROVISIONS Definition of Terms Used in This Subchapter § 188.10-39 Lakes, bays, and sounds. Under this designation shall be included all vessels navigating the waters of any of the lakes, bays, or sounds,...

  20. 46 CFR 90.10-19 - Lakes, bays, and sounds.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Lakes, bays, and sounds. 90.10-19 Section 90.10-19... PROVISIONS Definition of Terms Used in This Subchapter § 90.10-19 Lakes, bays, and sounds. Under this designation shall be included all vessels navigating the waters of any of the lakes, bays, or sounds...

  1. THERMODYNAMIC STUDY OF HIGH-PRESSURE ADSORPTION OF METHANE AND HEATS OF METHANE ADSORPTION ON MICROPOROUS CARBONS

    Institute of Scientific and Technical Information of China (English)

    杨晓东; 林文胜; 郑青榕; 顾安忠; 鲁雪生; 宋燕

    2002-01-01

    The study was done for high-pressure adsorption of methane on microporous carbons, which has an ANG vehicular application background. Adsorption isotherm of methane on super activated carbon up to 6 MPa was measured and isosteric heats of methane adsorption on a number of microporous carbons were determined from adsorption isosteres by the Clausius-Clapeyron equation. The variation of the isosteric heats of adsorption with the amount of methane adsorbed was discussed.

  2. Coupled models of free methane gas and anaerobic oxidation of methane : from core to regional scales. Geologica Ultraiectina (339)

    OpenAIRE

    Mogollón, J.M.

    2011-01-01

    Methane is a potent greenhouse gas that is produced in marine sediments containing high amounts of degrading organic carbon. It is therefore not surprising that marine sediments contain vast amounts of methane (500-5000 gigatons) present in dissolved (aqueous), free gas (gaseous), and solid (clathrate) forms. Nevertheless, very little methane ultimately escapes into the atmosphere (circa 10 - 15 Tg/yr, or 2% of the total methane emissions into the atmosphere) due, for the most part, to the an...

  3. Anaerobic Oxidation of Methane at a Marine Methane Seep in a Forearc Sediment Basin off Sumatra, Indian Ocean

    OpenAIRE

    Siegert, Michael; Krüger, Martin; Teichert, Barbara; Wiedicke, Michael; Schippers, Axel

    2011-01-01

    A cold methane seep was discovered in a forearc sediment basin off the island Sumatra, exhibiting a methane-seep adapted microbial community. A defined seep center of activity, like in mud volcanoes, was not discovered. The seep area was rather characterized by a patchy distribution of active spots. The relevance of anaerobic oxidation of methane (AOM) was reflected by 13C-depleted isotopic signatures of dissolved inorganic carbon. The anaerobic conversion of methane to CO2 was confirmed in a...

  4. Roebuck Bay Invertebrate and bird Mapping 2006

    OpenAIRE

    Piersma, Theunis; Pearson, Grant B.; Hickey, Robert; Dittmann, Sabine; Rogers, Danny I.; Folmer, Eelke; Honkoop, Pieter; Drent, Jan; de Goeij, Petra; Marsh, Loisette

    2006-01-01

    1. This is a report on a survey of the benthic ecology of the intertidal flats along the northern shores of Roebuck Bay in June 2006. In the period 11-20 June we mapped both the invertebrate macrobenthic animals (those retained by a 1 mm sieve) over the whole of the northern intertidal area of Roebuck Bay and the shorebirds that depend on this food resource. The northern mudflats previously had been benthically mapped in 1997, 2000 and 2002. In addition to the mapping efforts, as a reach-out ...

  5. Abnormality of Development in Strongylocentrotus intermedius (A. Agassiz) Larvae from Polluted Habitat in Amursky Bay, Peter the Great Bay

    OpenAIRE

    Naidenko, Tamara

    1997-01-01

    Amursky Bay, Peter the Great Bay, Sea of Japan is very much prone to anthropogenic pollution by heavy metals, oils, phenols, pesticides, etc. To clarify the effect of pollution, tests of the embryonic and larval development of sea urchin Strongylocentrotus intermedius are conducted using material collected from polluted habitats in Amursky Bay. A population from an unpolluted site in Vityaz Bay is used as a control. Various abnormal patterns of development including failure to metamorphose ar...

  6. Anaerobic methane oxidation coupled to denitrification is the dominant methane sink in a deep lake

    DEFF Research Database (Denmark)

    Deutzmann, Joerg S.; Stief, Peter; Brandes, Josephin;

    2014-01-01

    Anaerobic methane oxidation coupled to denitrification, also known as “nitrate/nitrite-dependent anaerobic methane oxidation” (n-damo), was discovered in 2006. Since then, only a few studies have identified this process and the associated microorganisms in natural environments. In aquatic sediments......, the close proximity of oxygen- and nitrate-consumption zones can mask n-damo as aerobic methane oxidation. We therefore investigated the vertical distribution and the abundance of denitrifying methanotrophs related to Candidatus Methylomirabilis oxyfera with cultivation-independent molecular...... techniques in the sediments of Lake Constance. Additionally, the vertical distribution of methane oxidation and nitrate consumption zones was inferred from high-resolution microsensor profiles in undisturbed sediment cores. M. oxyfera-like bacteria were virtually absent at shallow-water sites (littoral...

  7. Simulations of atmospheric methane for Cape Grim, Tasmania, to constrain southeastern Australian methane emissions

    OpenAIRE

    Z. M. Loh; R. M. Law; Haynes, K. D.; P. B. Krummel; Steele, L. P.; P. J. Fraser; S. D. Chambers; Williams, A G

    2015-01-01

    This study uses two climate models and six scenarios of prescribed methane emissions to compare modelled and observed atmospheric methane between 1994 and 2007, for Cape Grim, Australia (40.7° S, 144.7° E). The model simulations follow the TransCom-CH4 protocol and use the Australian Community Climate and Earth System Simulator (ACCESS) and the CSIRO Conformal-Cubic Atmospheric Model (CCAM). Radon is also simulated and used to reduce the i...

  8. Simulations of atmospheric methane for Cape Grim, Tasmania, to constrain South East Australian methane emissions

    OpenAIRE

    Z. M. Loh; R. M. Law; Haynes, K. D.; P. B. Krummel; Steele, L. P.; P. J. Fraser; Chambers, S; Williams, A

    2014-01-01

    This study uses two climate models and six scenarios of prescribed methane emissions to compare modelled and observed atmospheric methane between 1994 and 2007, for Cape Grim, Australia (40.7° S, 144.7° E). The model simulations follow the TransCom-CH4 protocol and use the Australian Community Climate and Earth System Simulator (ACCESS) and the CSIRO Conformal-Cubic Atmospheric Model (CCAM). Radon is also simulated and used to reduce the i...

  9. South Bay Salt Pond initial stewardship plan & related Bay Area restoration projects

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The Initial Stewardship Plan for the South Bay Salt Pond Restoration Project outlines a process to reduce the salinity of the existing salt ponds and to manage the...

  10. Contaminants in redhead ducks wintering in Baffin Bay and Redfish Bay, Texas

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — A sample of 39 redhead ducks was collected from Redfish and Baffin Bays on the Texas Coast during the winter of 1988-1989 to obtain baseline information on...

  11. Geology and geomorphology--Drakes Bay and Vicinity Bay Map Area, California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This part of DS 781 presents data for the geologic and geomorphic map of the Drakes Bay and Vicinity map area, California. The polygon shapefile is included in...

  12. Methane: a new stake for negotiations on climate?

    International Nuclear Information System (INIS)

    After having outlined that the issue of methane emissions could be, after the reduction of emissions from deforestation and degradation and the reduction of greenhouse gas emissions, an additional matter of discussion for the struggle against climate change, this article comments some data concerning methane emissions in six African countries. Generally, the main source of methane is agriculture (often more than 90 per cent) except in Gambia where wastes represent 77.8 per cent of methane emissions. This high level of methane emissions by agriculture could be a problem for these countries, whereas perspectives of waste valuation already exist

  13. Recent Progress in Direct Partial Oxidation of Methane to Methanol

    Institute of Scientific and Technical Information of China (English)

    Qijian Zhang; Dehua He; Qiming Zhu

    2003-01-01

    The direct conversion of methane to methanol has attracted a great deal of attention for nearly a century since it was first found possible in 1902, and it is still a challenging task. This review article describes recent advancements in the direct partial oxidation of methane to methanol. The history of direct oxidation of methane and the difficulties encountered in the partial oxidation of methane to methanol are briefly summarized. Recently reported developments in gas-phase homogeneous oxidation, heterogeneous catalytic oxidation and liquid phase homogeneous catalytic oxidation of methane are reviewed.

  14. Market research on biogas valorizations and methanization. Final report

    International Nuclear Information System (INIS)

    This market research aims at giving an overview of the existing methanization installations and of their dynamics in France, at assessing biogas production and use, at analyzing the methanization market, and at defining development perspectives for this sector by 2020. Based on a survey of methanization installations, on interviews with many actors of this sector, and on a seminar organized on this topic, this report presents and comments market data for biogas valorization and methanization in different sectors: household, agricultural, and industrial and waste water processing plants. It comments evolution trends by 2020 for these sectors, and the role that the emerging sector of centralized methanization could have in the years to come

  15. Terrestrial plant methane production and emission

    DEFF Research Database (Denmark)

    Bruhn, Dan; Møller, Ian M.; Mikkelsen, Teis Nørgaard;

    2012-01-01

    In this minireview, we evaluate all experimental work published on the phenomenon of aerobic methane (CH4) generation in terrestrial plants and plant. Clearly, despite much uncertainty and skepticism, we conclude that the phenomenon is true. Four stimulating factors have been observed to induce a...

  16. Methane production in simulated hybrid bioreactor landfill.

    Science.gov (United States)

    Xu, Qiyong; Jin, Xiao; Ma, Zeyu; Tao, Huchun; Ko, Jae Hac

    2014-09-01

    The aim of this work was to study a hybrid bioreactor landfill technology for landfill methane production from municipal solid waste. Two laboratory-scale columns were operated for about ten months to simulate an anaerobic and a hybrid landfill bioreactor, respectively. Leachate was recirculated into each column but aeration was conducted in the hybrid bioreactor during the first stage. Results showed that leachate pH in the anaerobic bioreactor maintained below 6.5, while in the hybrid bioreactor quickly increased from 5.6 to 7.0 due to the aeration. The temporary aeration resulted in lowering COD and BOD5 in the leachate. The volume of methane collected from the hybrid bioreactor was 400 times greater than that of the anaerobic bioreactor. Also, the methane production rate of the hybrid bioreactor was improved within a short period of time. After about 10 months' operation, the total methane production in the hybrid bioreactor was 212 L (16 L/kgwaste).

  17. Aerobic methane production from organic matter

    NARCIS (Netherlands)

    Vigano, I.

    2010-01-01

    Methane, together with H2O, CO2 and N2O, is an important greenhouse gas in the Earth’s atmosphere playing a key role in the radiative budget. It has been known for decades that the production of the reduced compound CH4 is possible almost exclusively in anoxic environments per opera of one of the mo

  18. Dense ceramic membranes for methane conversion

    NARCIS (Netherlands)

    Bouwmeester, Henny J.M.

    2003-01-01

    Dense ceramic membranes made from mixed oxygen-ionic and electronic conducting perovskite-related oxides allow separation of oxygen from an air supply at elevated temperatures (>700 °C). By combining air separation and catalytic partial oxidation of methane to syngas into a ceramic membrane reactor,

  19. Formation and retention of methane in coal

    Energy Technology Data Exchange (ETDEWEB)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  20. Methane conversion to hydrocarbons by double discharge

    OpenAIRE

    Ghorbanzadeh, A. M.; M. A. Khodagholi; N. S. Matin; S. Norouzi; M. T. Mohammadi

    2004-01-01

      Methane conversion to higher hydrocarbons by pulsed glow discharge at the atmospheric pressure was investigated. The energy efficiency up to 10 % was obtained which is higher than any value ever published for nonequilibrium plasma conversion of pure methame. This method has a potential for development and it is expected that the energy efficiency will be improved further if the plasma parameters are optimized.

  1. Methane Gas Emissions - is Older Infrastructure Leakier?

    Science.gov (United States)

    Wendt, L. P.; Caulton, D.; Zondlo, M. A.; Lane, H.; Lu, J.; Golston, L.; Pan, D.

    2015-12-01

    Large gains in natural gas production from hydraulic fracturing is reinvigorating the US energy economy. It is a clean burning fuel with lower emissions than that of coal or oil. Studies show that methane (CH4) leaks from natural gas infrastructure vary widely. A broader question is whether leak rates of methane might offset the benefits of combustion of natural gas. Excess methane (CH4) is a major greenhouse gas with a radiative forcing constant of 25 times that of CO2 when projected over a 100-year period. An extensive field study of 250 wells in the Marcellus Shale conducted in July 2015 examined the emission rates of this region and identifed super-emitters. Spud production data will provide information as to whether older infrastructure is responsible for more of the emissions. Quantifying the emission rate was determined by extrapolating methane releases at a distance from private well pads using an inverse Gaussian plume model. Wells studied were selected by prevailing winds, distance from public roads, and topographical information using commercial (ARCGIS and Google Earth), non-profit (drillinginfo), and government (State of PA) databases. Data were collected from the mobile sensing lab (CH4, CO2 and H2O sensors), as well as from a stationary tower. Emission rates from well pads will be compared to their original production (spud dates) to evaluate whether infrastructure age and total production correlates with the observed leak rates. Very preliminary results show no statistical correlation between well pad production rates and observed leak rates.

  2. Biomass gasification for the production of methane

    NARCIS (Netherlands)

    Nanou, P.

    2013-01-01

    Biomass is very promising as a sustainable alternative to fossil resources because it is a renewable source that contains carbon, an essential building block for gaseous and liquid fuels. Methane is the main component of natural gas, which is a fuel used for heating, power generation and transportat

  3. Methane: Signs of Progress along the Road

    Science.gov (United States)

    Recent findings of Simpson et al. (Geophysical Research Letters, 33:L22808, doi:10.1029/2006GL027330, 2006) have indicated that the growth in the concentration of atmospheric methane has leveled off based on air sampling conducted throughout the Pacific basin (71 deg N to 47 deg S) over the last sev...

  4. Red Tides in Nagasaki Bay during Summer Season of 1979

    OpenAIRE

    Dahril, Tengku; Iizuka, Shoji

    1981-01-01

    Almost every year during the summer season, red tides have occurred in Nagasaki Bay. Red tides are caused by various kind of phytoplankton and bay waters discolor like coffee by the exclusive growth of a single organism or mixed growth of two or three organisms. However, very little is known about red tide in this bay. In this paper the authors dealt with red tides in Nagasaki Bay during the summer season of 1979. The innermost part of this bay was divided into 3 areas. Five water sampling st...

  5. The land-sourced pollution in the Jiaozhou Bay

    Institute of Scientific and Technical Information of China (English)

    GAO Zhenhui; YANG Dongfang; QIN Jie; XIANG Lihong; ZHANG Ke

    2008-01-01

    In recent years,natural environment of the Jiaozhou Bay has been changed largely by fast developing industry and agriculture of the cities around,from which wastewaters were generated.The size of the bay has been continuously shrunk with reduced river flows,resulting in serious contamination to the marine lives in the bay.After analyzing the basic historical data,the authors put forward a suggestion of how to protect the bay ecology for sustaining the resources in the Jiaozhou Bay.

  6. Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water

    Energy Technology Data Exchange (ETDEWEB)

    Song Jin

    2007-05-31

    Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.

  7. Diurnal variation of oxygen and carbonate system parameters in Tampa Bay and Florida Bay

    Science.gov (United States)

    Yates, K.K.; Dufore, C.; Smiley, N.; Jackson, C.; Halley, R.B.

    2007-01-01

    Oxygen and carbonate system parameters were measured, in situ, over diurnal cycles in Tampa Bay and Florida Bay, Florida. All system parameters showed distinct diurnal trends in Tampa Bay with an average range of diurnal variation of 39.1 μmol kg− 1 for total alkalinity, 165.1 μmol kg− 1 for total CO2, 0.22 for pH, 0.093 mmol L− 1 for dissolved oxygen, and 218.1 μatm for pCO2. Average range of diurnal variation for system parameters in Tampa Bay was 73% to 93% of the seasonal range of variability for dissolved oxygen and pH. All system parameters measured in Florida Bay showed distinct variation over diurnal time-scales. However, clear diurnal trends were less evident. The average range of diurnal variability in Florida Bay was 62.8 μmol kg− 1 for total alkalinity, 130.4 μmol kg− 1 for total CO2, 0.13 for pH, 0.053 mmol L− 1 for dissolved oxygen, and 139.8 μatm for pCO2. The average range of diurnal variation was 14% to 102% of the seasonal ranges for these parameters. Diurnal variability in system parameters was most influenced by primary productivity and respiration of benthic communities in Tampa Bay, and by precipitation and dissolution of calcium carbonate in Florida Bay. Our data indicate that use of seasonal data sets without careful consideration of diurnal variability may impart significant error in calculations of annual carbon and oxygen budgets. These observations reinforce the need for higher temporal resolution measurements of oxygen and carbon system parameters in coastal ecosystems.

  8. Methane hydrate stability and anthropogenic climate change

    Directory of Open Access Journals (Sweden)

    D. Archer

    2007-04-01

    Full Text Available Methane frozen into hydrate makes up a large reservoir of potentially volatile carbon below the sea floor and associated with permafrost soils. This reservoir intuitively seems precarious, because hydrate ice floats in water, and melts at Earth surface conditions. The hydrate reservoir is so large that if 10% of the methane were released to the atmosphere within a few years, it would have an impact on the Earth's radiation budget equivalent to a factor of 10 increase in atmospheric CO2.

    Hydrates are releasing methane to the atmosphere today in response to anthropogenic warming, for example along the Arctic coastline of Siberia. However most of the hydrates are located at depths in soils and ocean sediments where anthropogenic warming and any possible methane release will take place over time scales of millennia. Individual catastrophic releases like landslides and pockmark explosions are too small to reach a sizable fraction of the hydrates. The carbon isotopic excursion at the end of the Paleocene has been interpreted as the release of thousands of Gton C, possibly from hydrates, but the time scale of the release appears to have been thousands of years, chronic rather than catastrophic.

    The potential climate impact in the coming century from hydrate methane release is speculative but could be comparable to climate feedbacks from the terrestrial biosphere and from peat, significant but not catastrophic. On geologic timescales, it is conceivable that hydrates could release much carbon to the atmosphere/ocean system as we do by fossil fuel combustion.

  9. Atmospheric Methane Contributions From Fractured Bedrock Aquifers

    Science.gov (United States)

    Marrin, D. L.

    2013-05-01

    Groundwater is not normally considered as an important contributor of atmospheric methane because the organic carbon content of aquifers is too low to sustain significant methanogenesis. Also, groundwater-generated methane partitions into the gas phase of the overlying soil, where it either dissolves in the pore water or is oxidized to carbon dioxide by methanotrophs. There are, however, localized conditions (related to human activities and hydrogeologic conditions) under which atmospheric contributions of groundwater-generated methane occur at the ground surface. Storing and transporting liquid petroleum products in the subsurface has resulted in the local introduction of high concentrations of degradable organic carbon and the creation of redox conditions that favor methanogenesis over more oxidative biodegradation pathways. Groundwater overlain by fractured bedrock, rather than by unconsolidated porous media, creates a situation where CH4 migrates through discrete fractures, thus limiting the soil volume and the surface area available for methanotrophic activity. The spatial distribution of methane in thin surface soils overlying bedrock suggests that CH4 migrates via fracture networks and that CH4 oxidation is a factor of about 50 less than that measured in typical unconsolidated soils. Atmospheric flux rates associated with contaminated bedrock aquifers were on the order of several grams of carbon (as CH4) per square meter, which is less than that reported for well documented sources (e.g., rice paddies) and probably represents a minor worldwide contribution. Nonetheless, these aquifers can represent an important localized source, can shift soils from a sink to a source of methane, and can permit petroleum products to load carbon (as biogenic CH4 and CO2) to the atmosphere without ever being combusted.

  10. Methane hydrate stability and anthropogenic climate change

    Directory of Open Access Journals (Sweden)

    D. Archer

    2007-07-01

    Full Text Available Methane frozen into hydrate makes up a large reservoir of potentially volatile carbon below the sea floor and associated with permafrost soils. This reservoir intuitively seems precarious, because hydrate ice floats in water, and melts at Earth surface conditions. The hydrate reservoir is so large that if 10% of the methane were released to the atmosphere within a few years, it would have an impact on the Earth's radiation budget equivalent to a factor of 10 increase in atmospheric CO2.

    Hydrates are releasing methane to the atmosphere today in response to anthropogenic warming, for example along the Arctic coastline of Siberia. However most of the hydrates are located at depths in soils and ocean sediments where anthropogenic warming and any possible methane release will take place over time scales of millennia. Individual catastrophic releases like landslides and pockmark explosions are too small to reach a sizable fraction of the hydrates. The carbon isotopic excursion at the end of the Paleocene has been interpreted as the release of thousands of Gton C, possibly from hydrates, but the time scale of the release appears to have been thousands of years, chronic rather than catastrophic.

    The potential climate impact in the coming century from hydrate methane release is speculative but could be comparable to climate feedbacks from the terrestrial biosphere and from peat, significant but not catastrophic. On geologic timescales, it is conceivable that hydrates could release as much carbon to the atmosphere/ocean system as we do by fossil fuel combustion.

  11. Bathymetry (2011) for Fish Bay, St. John

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution depth surface for Fish Bay, St. John in the U.S. Virgin Islands (USVI). The...

  12. Roebuck Bay Invertebrate and bird Mapping 2006

    NARCIS (Netherlands)

    Piersma, Theunis; Pearson, Grant B.; Hickey, Robert; Dittmann, Sabine; Rogers, Danny I.; Folmer, Eelke; Honkoop, Pieter; Drent, Jan; Goeij, Petra de; Marsh, Loisette

    2006-01-01

    1. This is a report on a survey of the benthic ecology of the intertidal flats along the northern shores of Roebuck Bay in June 2006. In the period 11-20 June we mapped both the invertebrate macrobenthic animals (those retained by a 1 mm sieve) over the whole of the northern intertidal area of Roebu

  13. Bathymetry (2011) for Coral Bay, St. John

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution depth surface for Coral Bay, St. John in the U.S. Virgin Islands (USVI). The...

  14. Empirical Bayes Estimation in Regression Model

    Institute of Scientific and Technical Information of China (English)

    Li-chun Wang

    2005-01-01

    This paper considers the empirical Bayes (EB) estimation problem for the parameterβ of the linear regression model y = Xβ + ε with ε~ N(0, σ2I) givenβ. Based on Pitman closeness (PC) criterion and mean square error matrix (MSEM) criterion, we prove the superiority of the EB estimator over the ordinary least square estimator (OLSE).

  15. Carolina bays of the Savannah River Plant

    Energy Technology Data Exchange (ETDEWEB)

    Schalles, J.F. (Creighton Univ., Omaha, NE (USA)); Sharitz, R.R.; Gibbons, J.W.; Leversee, G.J.; Knox, J.N. (Savannah River Ecology Lab., Aiken, SC (USA))

    1989-01-01

    Much of the research to date on the Carolina bays of the Savannah River Plant and elsewhere has focused on certain species or on environmental features. Different levels of detail exist for different groups of organisms and reflect the diverse interests of previous investigators. This report summarizes aspects of research to date and presents data from numerous studies. 70 refs., 14 figs., 12 tabs.

  16. ULF fluctuations at Terra Nova Bay (Antarctica

    Directory of Open Access Journals (Sweden)

    A. Meloni

    2000-06-01

    Full Text Available ULF geomagnetic field measurements in Antarctica are a very important tool for better understanding the dynamics of the Earth’s magnetosphere and its response to the variable solar wind conditions. We review the results obtained in the last few years at the Italian observatory at Terra Nova Bay

  17. Summary report on Bristol Bay murre mortality

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — At least 86,000 common murres died in Bristol Bay, Alaska during a brief period in late April of this year. Evidence suggests that it was a catastrophic event of...

  18. Estimating methane emissions from mangrove area in Ranong Province, Thailand

    Directory of Open Access Journals (Sweden)

    Suwanchai Nitisoravut

    2005-01-01

    Full Text Available This study aimed to estimate methane emissions from the mangrove area of Ranong Province andto explore the factors affecting the emissions, as part of an attempt to evaluate methane contribution to the global methane budget. Methane was measured by using a closed chamber technique and analyzed by a gas chromatograph equipped with a flame ionization detector (FID. The results showed that the annual estimated methane emission was released at approximately 157.32 mg/m2. The amount of methane emission from this mangrove area was lower than in other previously studied areas. Emission rates varied seasonally with the highest rate in the rainy season followed by summer and cold seasons, during which the values were 0.52, 0.27, and 0.19 mg/m2/day, respectively. Seasonal variations of methane emission was related to several factors depending upon field conditions such as water conductivity, soil temperature, and water level.

  19. Methane productivity of manure, straw and solid fractions of manure

    DEFF Research Database (Denmark)

    Møller, H.B.; Sommer, S.G.; Ahring, Birgitte Kiær

    2004-01-01

    The methane productivity of manure in terms of volatile solids (VS), volume and livestock production was determined. The theoretical methane productivity is higher in pig (516 1 kg(-1) VS) and sow (530 1 kg(-1) VS) manure than in dairy cattle manure (469 1 kg(-1) VS), while the ultimate methane...... yield in terms of VS is considerably higher in pig (356 1 kg(-1) VS) and sow manure (275 1 kg(-1) VS) than in dairy cattle manure (148 1 kg(-1) VS). Methane productivity based on livestock units (LU) shows the lowest methane productivity for sows (165 m(3) CH4 LU-1), while the other animal categories...... methane yield of straw was found to be higher than the yield from total manure and the solid fractions of manure, due to the higher VS content, and hence the use of straw as bedding material will increase the volumetric as well as the livestock-based methane productivity....

  20. Thermodynamic properties and diffusion of water + methane binary mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Shvab, I.; Sadus, Richard J., E-mail: rsadus@swin.edu.au [Centre for Molecular Simulation, Swinburne University of Technology, PO Box 218 Hawthorn, Victoria 3122 (Australia)

    2014-03-14

    Thermodynamic and diffusion properties of water + methane mixtures in a single liquid phase are studied using NVT molecular dynamics. An extensive comparison is reported for the thermal pressure coefficient, compressibilities, expansion coefficients, heat capacities, Joule-Thomson coefficient, zero frequency speed of sound, and diffusion coefficient at methane concentrations up to 15% in the temperature range of 298–650 K. The simulations reveal a complex concentration dependence of the thermodynamic properties of water + methane mixtures. The compressibilities, heat capacities, and diffusion coefficients decrease with increasing methane concentration, whereas values of the thermal expansion coefficients and speed of sound increase. Increasing methane concentration considerably retards the self-diffusion of both water and methane in the mixture. These effects are caused by changes in hydrogen bond network, solvation shell structure, and dynamics of water molecules induced by the solvation of methane at constant volume conditions.

  1. The Effects of Dissolved Methane upon Liquid Argon Scintillation Light

    CERN Document Server

    Jones, B J P; Back, H O; Collin, G; Conrad, J M; Greene, A; Katori, T; Pordes, S; Toups, M

    2013-01-01

    In this paper we report on measurements of the effects of dissolved methane upon argon scintillation light. We monitor the light yield from an alpha source held 20 cm from a cryogenic photomultiplier tube (PMT) assembly as methane is injected into a high-purity liquid argon volume. We observe significant suppression of the scintillation light yield by dissolved methane at the 10 part per billion (ppb) level. By examining the late scintillation light time constant, we determine that this loss is caused by an absorption process and also see some evidence of methane-induced scintillation quenching at higher concentrations (50-100 ppb). Using a second PMT assembly we look for visible re-emission features from the dissolved methane which have been reported in gas-phase argon methane mixtures, and we find no evidence of visible re-emission from liquid-phase argon methane mixtures at concentrations between 10 ppb and 0.1%.

  2. Methane biofiltration using autoclaved aerated concrete as the carrier material.

    Science.gov (United States)

    Ganendra, Giovanni; Mercado-Garcia, Daniel; Hernandez-Sanabria, Emma; Boeckx, Pascal; Ho, Adrian; Boon, Nico

    2015-09-01

    The methane removal capacity of mixed methane-oxidizing bacteria (MOB) culture in a biofilter setup using autoclaved aerated concrete (AAC) as a highly porous carrier material was tested. Batch experiment was performed to optimize MOB immobilization on AAC specimens where optimum methane removal was obtained when calcium chloride was not added during bacterial inoculation step and 10-mm-thick AAC specimens were used. The immobilized MOB could remove methane at low concentration (~1000 ppmv) in a biofilter setup for 127 days at average removal efficiency (RE) of 28.7 %. Unlike a plug flow reactor, increasing the total volume of the filter by adding a biofilter in series did not result in higher total RE. MOB also exhibited a higher abundance at the bottom of the filter, in proximity with the methane gas inlet where a high methane concentration was found. Overall, an efficient methane biofilter performance could be obtained using AAC as the carrier material. PMID:25967655

  3. Energy sector methane recovery and use: the importance of policy

    Energy Technology Data Exchange (ETDEWEB)

    Tom Kerr; Michelle Hershman

    2009-08-15

    To raise awareness about appropriate policy options to advance methane recovery and use in the energy sector, the IEA has conducted a series of analyses and studies over the past few years. This report continues IEA efforts by providing policy makers with examples and best practices in methane mitigation policy design and implementation. This report offers an overview of four types of methane mitigation projects that have the strongest links to the energy sector: oil and gas methane recovery and reduction of leaks and losses; coal mine methane; landfill methane; and manure methane recovery and use. It identifies successful policies that have been used to advance these important projects. This information is intended to guide policy makers as they search for low-cost, near-term solutions to climate change. 38 refs., 10 figs., 1 app.

  4. Chesapeake Bay Watershed - Protecting the Chesapeake Bay and its rivers through science, restoration, and partnership

    Science.gov (United States)

    U.S. Geological Survey

    2012-01-01

    The Chesapeake Bay, the Nation's largest estuary, has been degraded due to the impact of human-population increase, which has doubled since 1950, resulting in degraded water quality, loss of habitat, and declines in populations of biological communities. Since the mid-1980s, the Chesapeake Bay Program (CBP), a multi-agency partnership which includes the Department of Interior (DOI), has worked to restore the Bay ecosystem. The U.S. Geological Survey (USGS) has the critical role of providing unbiased scientific information that is utilized to document and understand ecosystem change to help assess the effectiveness of restoration strategies in the Bay and its watershed. The USGS revised its Chesapeake Bay science plan for 2006-2011 to address the collective needs of the CBP, DOI, and USGS with a mission to provide integrated science for improved understanding and management of the Bay ecosystem. The USGS science themes for this mission are: Causes and consequences of land-use change; Impact of climate change and associated hazards; Factors affecting water quality and quantity; Ability of habitat to support fish and bird populations; and Synthesis and forecasting to improve ecosystem assessment, conservation, and restoration.

  5. Responses of upland herpetofauna to the restoration of Carolina Bays and thinning of forested Bay Margins.

    Energy Technology Data Exchange (ETDEWEB)

    Ledvina, Joseph A.

    2008-05-01

    Research on the effects of wetland restoration on reptiles and amphibians is becoming more common, but almost all of these studies have observed the colonization of recently disturbed habitats that were completely dry at the time of restoration. In a similar manner, investigations herpetofaunal responses to forest management have focused on clearcuts, and less intensive stand manipulations are not as well studied. To evaluate community and population responses of reptiles and amphibians to hydrology restoration and canopy removal in the interior of previously degraded Carolina bays, I monitored herpetofauna in the uplands adjacent to six historically degraded Carolina bays at the Savannah River Site (SRS) in South Carolina for four years after restoration. To evaluate the effects of forest thinning on upland herpetofauna, forests were thinned in the margins of three of these bays. I used repeated measures ANOVA to compare species richness and diversity and the abundance of selected species and guilds between these bays and with those at three reference bays that were not historically drained and three control bays that remained degraded. I also used Non-metric Multidimensional Scaling (NMDS) to look for community-level patterns based treatments.

  6. Atmospheric distribution of methane on Mars: A model study

    Science.gov (United States)

    Viscardy, Sébastien; Daerden, Frank; Neary, Lori

    2016-10-01

    In the past decade, the detection of methane (CH4) in the atmosphere of Mars has been reported several times. These observations have strongly drawn the attention of the scientific community and triggered a renewed interest in Mars as their implications for the geochemical or biological activities are remarkable. However, given that methane is expected to have a photochemical lifetime of several centuries, the relatively fast loss rates of methane estimated from Earth-based measurements remain unexplained. Although this gave rise to objections against the validity of those observations, recent in situ measurements confirmed that methane is being occasionally released into the atmosphere from an unknown source (possibly from the ground). Additionally, ExoMars/TGO was launched to Mars in March 2016. NOMAD, one of the instruments onboard TGO, will provide the first global detailed observations of methane on Mars. It is in this context that we present a model study of the behavior of methane plumes.A general circulation model for the atmosphere of Mars is applied to simulate surface emission of methane and to investigate its vertical distribution during the first weeks after the release. Such surface emissions were suggested to explain observations of methane. Previous GCM simulations focused on the horizontal evolution of the methane, but the present study focuses on the three-dimensional dispersion of methane throughout the atmosphere after the surface release. It is found that a highly nonuniform vertical distribution, including distinct vertical layers, can appear throughout the atmosphere during the first weeks after the emission. This is explained by the global circulation patterns in the atmosphere at the time of the emission. Large Hadley cells transport the methane rapidly to other locations over the planet, and methane will be stretched out in layers along the general circulation streamlines at heights corresponding to strong zonal jets.This result changes

  7. Effects of salinity on methane gas hydrate system

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Using an approximately analytical formation,we extend the steady state model of the pure methane hydrate system to include the salinity based on the dynamic model of the methane hydrate system.The top and bottom boundaries of the methane hydrate stability zone (MHSZ) and the actual methane hydrate zone (MHZ),and the top of free gas occurrence are determined by using numerical methods and the new steady state model developed in this paper.Numerical results show that the MHZ thickness becomes thinner with increasing the salinity,and the stability is lowered and the base of the MHSZ is shifted toward the seafloor in the presence of salts.As a result,the thickness of actual hydrate occurrence becomes thinner compared with that of the pure water case.On the other hand,since lower solubility reduces the amount of gas needed to form methane hydrate,the existence of salts in seawater can actually promote methane gas hydrate formation in the hydrate stability zone.Numerical modeling also demonstrates that for the salt-water case the presence of methane within the field of methane hydrate stability is not sufficient to ensure the occurrence of gas hydrate,which can only form when the methane concentration dissolved in solution with salts exceeds the local methane solubility in salt water and if the methane flux exceeds a critical value corresponding to the rate of diffusive methane transport.In order to maintain gas hydrate or to form methane gas hydrate in marine sediments,a persistent supplied methane probably from biogenic or thermogenic processes,is required to overcome losses due to diffusion and advection.

  8. Biogenic silicate accumulation in sediments, Jiaozhou Bay

    Institute of Scientific and Technical Information of China (English)

    LI Xuegang; SONG Jinming; DAI Jicui; YUAN Huamao; LI Ning; LI Fengye; SUN Song

    2006-01-01

    It has been widely recognized that low silicate content in seawater is a major limiting factor to phytoplankton primary production in Jiaozhou Bay. However the reason of Si-limitation remains poorly understood. In the present study we measured the biogenic silicate content and discussed the accumulation of silicate in Jiaozhou Bay sediment. The results show that the biogenic silica content in the sediment of the Jiaozhou Bay is obviously much higher than those in the Yellow Sea and the Bohai Sea. The BSi:TN ratios and BSi:16P ratios in the sediment are > 1 and the OC:BSi ratio in sediment is lower than these of Redfield ratio (106:16), indicating that the decomposition rate of OC is much higher than that for BSi in similar conditions. Therefore, the majority of the biogenic silicate was buried and thus did not participate in silicate recycling. Silicate accumulation in sediment may explain why Si limits the phytoplankton growth in the Jiaozhou Bay. Comparing the flux of biogenic silicate from sediments with primary production rate, it can be concluded that only 15.5% of biogenic silicate is hydrolyzed during the journey from surface to bottom in seawater, thus approximate 84.5% of biogenic silicate could reach the bottom. The silicate releasing rate from the sediment to seawater is considerably lower than that of sedimentation of biogenic silicate, indicating silicate accumulation in sediment too. In a word, the silicate accumulation in sediment is the key reason of silicate limiting to phytoplankton growth in Jiaozhou Bay.

  9. Biological baseline data Youngs Bay, Oregon, 1974

    Energy Technology Data Exchange (ETDEWEB)

    McMechan, K.J. (ed.); Higley, D.L.; Holton, R.L.

    1975-04-01

    This report presents biological baseline information gathered during the research project, Physical, Chemical and Biological Studies on Youngs Bay.'' Youngs Bay is a shallow embayment located on the south shore of the Columbia River, near Astoria, Oregon. Research on Youngs Bay was motivated by the proposed construction by Alumax Pacific Aluminum Corporation of an aluminum reduction plant at Warrenton, Oregon. The research was designed to provide biological baseline information on Youngs Bay in anticipation of potential harmful effects from plant effluents. The information collected concerns the kinds of animals found in the Youngs Bay area, and their distribution and seasonal patterns of abundance. In addition, information was collected on the feeding habits of selected fish species, and on the life history and behavioral characteristics of the most abundant benthic amphipod, Corophium salmonis. Sampling was conducted at approximately three-week intervals, using commonly accepted methods of animal collection. Relatively few stations were sampled for fish, because of the need to standardize conditions of capture. Data on fish capture are reported in terms of catch-per-unit effort by a particular sampling gear at a specific station. Methods used in sampling invertebrates were generally more quantitative, and allowed sampling at a greater variety of places, as well as a valid basis for the computation of densities. Checklists of invertebrate species and fish species were developed from these samples, and are referred to throughout the report. The invertebrate checklist is more specific taxonomically than are tables reporting invertebrate densities. This is because the methods employed in identification were more precise than those used in counts. 9 refs., 27 figs., 25 tabs.

  10. The role of endophytic methane-oxidizing bacteria in submerged Sphagnum in determining methane emissions of Northeastern Siberian tundra

    Directory of Open Access Journals (Sweden)

    T. C. Maximov

    2011-05-01

    Full Text Available The role of the microbial processes governing methane emissions from tundra ecosystems is receiving increasing attention. Recently, cooperation between methanotrophic bacteria and submerged Sphagnum was shown to reduce methane emissions but also to supply CO2 for photosynthesis for the plant. Although this process was shown to be important in the laboratory, the differences that exist in methane emissions from inundated vegetation types with or without Sphagnum in the field have not been linked to these bacteria before. In this study, chamber flux measurements, an incubation study and a process model were used to investigate the drivers and controls on the relative difference in methane emissions between a submerged Sphagnum/sedge vegetation type and an inundated sedge vegetation type without Sphagnum. It was found that methane emissions in the Sphagnum-dominated vegetation type were 50 % lower than in the vegetation type without Sphagnum. A model sensitivity analysis showed that these differences could not sufficiently be explained by differences in methane production and plant transport. The model, combined with an incubation study, indicated that methane oxidation by endophytic bacteria, living in cooperation with submerged Sphagnum, plays a significant role in methane cycling at this site. This result is important for spatial upscaling as oxidation by these bacteria is likely involved in 15 % of the net methane emissions at this tundra site. Our findings support the notion that methane-oxidizing bacteria are an important factor in understanding the processes behind methane emissions in tundra.

  11. Short-term changes in anaerobic oxidation of methane in response to varying methane and sulfate fluxes

    Directory of Open Access Journals (Sweden)

    G. Wegener

    2008-08-01

    Full Text Available A major role in global methane fluxes has been attributed to the process of anaerobic oxidation of methane, which is performed by consortia of methanotrophic archaea and sulfate reducing bacteria. An important question remains how these very slow growing microorganisms with generation times of 3–7 months respond to natural variations in methane fluxes at cold seeps. Here, we used an experimental flow-through column system filled with cold seep sediments naturally enriched in methanotrophic communities, to test their response to short-term variations in methane and sulfate fluxes. At stable methane and sulfate concentrations of ~2 mM and 28 mM, respectively, we measured constant rates of anaerobic oxidation of methane (AOM and sulfide production (SR for up to 160 days of incubation. When percolated with methane-free medium, the anaerobic methanotrophs ceased to oxidize methane and to produce sulfide. After a starvation phase of 40 days, the addition of methane restored former AOM and SR rates immediately. At methane concentrations between 0–2.3 mM we measured a linear correlation between methane availability, AOM and SR. At constant fluid flow rates of 30 m yr−1, ca. 50% of the methane was consumed by the ANME population at all concentrations tested. Reducing the sulfate concentration from 28 to 1 mM, a decrease in AOM and SR by 35% was observed. Hence, the marine anaerobic methanotrophs (ANME are capable to consume substantial amounts of methane rising from the subsurface seabed to the hydrosphere over a wide range of fluxes of methane and sulfate.

  12. Topobathymetric model of Mobile Bay, Alabama

    Science.gov (United States)

    Danielson, Jeffrey J.; Brock, John C.; Howard, Daniel M.; Gesch, Dean B.; Bonisteel-Cormier, Jamie M.; Travers, Laurinda J.

    2013-01-01

    Topobathymetric Digital Elevation Models (DEMs) are a merged rendering of both topography (land elevation) and bathymetry (water depth) that provides a seamless elevation product useful for inundation mapping, as well as for other earth science applications, such as the development of sediment-transport, sea-level rise, and storm-surge models. This 1/9-arc-second (approximately 3 meters) resolution model of Mobile Bay, Alabama was developed using multiple topographic and bathymetric datasets, collected on different dates. The topographic data were obtained primarily from the U.S. Geological Survey (USGS) National Elevation Dataset (NED) (http://ned.usgs.gov/) at 1/9-arc-second resolution; USGS Experimental Advanced Airborne Research Lidar (EAARL) data (2 meters) (http://pubs.usgs.gov/ds/400/); and topographic lidar data (2 meters) and Compact Hydrographic Airborne Rapid Total Survey (CHARTS) lidar data (2 meters) from the U.S. Army Corps of Engineers (USACE) (http://www.csc.noaa.gov/digitalcoast/data/coastallidar/). Bathymetry was derived from digital soundings obtained from the National Oceanic and Atmospheric Administration’s (NOAA) National Geophysical Data Center (NGDC) (http://www.ngdc.noaa.gov/mgg/geodas/geodas.html) and from water-penetrating lidar sources, such as EAARL and CHARTS. Mobile Bay is ecologically important as it is the fourth largest estuary in the United States. The Mobile and Tensaw Rivers drain into the bay at the northern end with the bay emptying into the Gulf of Mexico at the southern end. Dauphin Island (a barrier island) and the Fort Morgan Peninsula form the mouth of Mobile Bay. Mobile Bay is 31 miles (50 kilometers) long by a maximum width of 24 miles (39 kilometers) with a total area of 413 square miles (1,070 square kilometers). The vertical datum of the Mobile Bay topobathymetric model is the North American Vertical Datum of 1988 (NAVD 88). All the topographic datasets were originally referenced to NAVD 88 and no transformations

  13. Corpus Christi, Nueces, and Aransas Bays

    Science.gov (United States)

    Handley, Lawrence R.; Spear, Kathryn A.; Eleonor Taylor,; Thatcher, Cindy

    2015-01-01

    Corpus Christi Bay and Nueces Bay comprise the middle estuarine portion of Texas’ Coastal Bend region (Figure 1; Burgan and Engle, 2006). Aransas Bay is part of the upper estuarine portion of the region. These bays make up part of the Coastal Bend Bays and Estuaries Program, one of the many estuarine areas in the U.S. Environmental Protection Agency’s National Estuary Program (Holt, 1998). The Coastal Bend region is sub-humid and sub-tropical. Summers are long, hot, and humid, and winters are short and mild. The landscape around the estuaries is dominated by row crops, pastures, and brushy rangeland (Handley and others, 2007). The Nueces River, along with other smaller rivers and creeks, provides freshwater inflow—along with essential nutrients and sediment— into Nueces Bay, which feeds into Corpus Christi Bay (Holt, 1998). Freshwater inflow into the Aransas Bay comes from Mission River, Aransas River, and Copano Creek. The region is relatively dry otherwise and prone to droughts. Corpus Christi receives an average of 76.2 cm (30 in) of rain annually; evaporation usually exceeds 177.8 cm (70 in) (Holt, 1998; Handley and others, 2007). The San Antonio-Nueces Coastal Basin drains into Aransas Bay. The Nueces River basin covers 43,253 km2 (16,700 miles2 ), from northwest of San Antonio, flowing southeast to where it drains into Nueces and Corpus Christi Bays (Holt, 1998). The Nueces-Rio Grande basin covers approximately 18,648 1 U.S. Geological Survey National Wetlands Research Center, 700 Cajundome Blvd., Lafayette, LA 70506 2 Harte Research Institute for Gulf of Mexico Studies, Texas A&M University - Corpus Christi, 6300 Ocean Drive, Unit 5869, Corpus Christi, Texas 78412 2 km2 (7,200 miles2 ) and flows partially into Corpus Christi Bay (as well as the upper Laguna Madre). The inflow from Nueces River has declined by approximately 20 percent over the past several decades, partly due to construction of lakes and reservoirs, particularly Lake Corpus Christi

  14. Technical Note: Methionine, a precursor of methane in living plants

    Science.gov (United States)

    Lenhart, K.; Althoff, F.; Greule, M.; Keppler, F.

    2015-03-01

    When terrestrial plants were identified as producers of the greenhouse gas methane, much discussion and debate ensued not only about their contribution to the global methane budget but also with regard to the validity of the observation itself. Although the phenomenon has now become more accepted for both living and dead plants, the mechanism of methane formation in living plants remains to be elucidated and its precursor compounds to be identified. We made use of stable isotope techniques to verify the in vivo formation of methane, and, in order to identify the carbon precursor, 13C positionally labeled organic compounds were employed. Here we show that the amino acid L-methionine acts as a methane precursor in living plants. Employing 13C-labeled methionine clearly identified the sulfur-bound methyl group of methionine as a carbon precursor of methane released from lavender (Lavandula angustifolia). Furthermore, when lavender plants were stressed physically, methane release rates and the stable carbon isotope values of the emitted methane greatly increased. Our results provide additional support that plants possess a mechanism for methane production and suggest that methionine might play an important role in the formation of methane in living plants, particularly under stress conditions.

  15. A conduit dilation model of methane venting from lake sediments

    Science.gov (United States)

    Scandella, B.P.; Varadharajan, C.; Hemond, Harold F.; Ruppel, C.; Juanes, R.

    2011-01-01

    Methane is a potent greenhouse gas, but its effects on Earth's climate remain poorly constrained, in part due to uncertainties in global methane fluxes to the atmosphere. An important source of atmospheric methane is the methane generated in organic-rich sediments underlying surface water bodies, including lakes, wetlands, and the ocean. The fraction of the methane that reaches the atmosphere depends critically on the mode and spatiotemporal characteristics of free-gas venting from the underlying sediments. Here we propose that methane transport in lake sediments is controlled by dynamic conduits, which dilate and release gas as the falling hydrostatic pressure reduces the effective stress below the tensile strength of the sediments. We test our model against a four-month record of hydrostatic load and methane flux in Upper Mystic Lake, Mass., USA, and show that it captures the complex episodicity of methane ebullition. Our quantitative conceptualization opens the door to integrated modeling of methane transport to constrain global methane release from lakes and other shallow-water, organic-rich sediment systems, and to assess its climate feedbacks.

  16. A four-helix bundle stores copper for methane oxidation.

    Science.gov (United States)

    Vita, Nicolas; Platsaki, Semeli; Baslé, Arnaud; Allen, Stephen J; Paterson, Neil G; Crombie, Andrew T; Murrell, J Colin; Waldron, Kevin J; Dennison, Christopher

    2015-09-01

    Methane-oxidizing bacteria (methanotrophs) require large quantities of copper for the membrane-bound (particulate) methane monooxygenase. Certain methanotrophs are also able to switch to using the iron-containing soluble methane monooxygenase to catalyse methane oxidation, with this switchover regulated by copper. Methane monooxygenases are nature's primary biological mechanism for suppressing atmospheric levels of methane, a potent greenhouse gas. Furthermore, methanotrophs and methane monooxygenases have enormous potential in bioremediation and for biotransformations producing bulk and fine chemicals, and in bioenergy, particularly considering increased methane availability from renewable sources and hydraulic fracturing of shale rock. Here we discover and characterize a novel copper storage protein (Csp1) from the methanotroph Methylosinus trichosporium OB3b that is exported from the cytosol, and stores copper for particulate methane monooxygenase. Csp1 is a tetramer of four-helix bundles with each monomer binding up to 13 Cu(I) ions in a previously unseen manner via mainly Cys residues that point into the core of the bundle. Csp1 is the first example of a protein that stores a metal within an established protein-folding motif. This work provides a detailed insight into how methanotrophs accumulate copper for the oxidation of methane. Understanding this process is essential if the wide-ranging biotechnological applications of methanotrophs are to be realized. Cytosolic homologues of Csp1 are present in diverse bacteria, thus challenging the dogma that such organisms do not use copper in this location. PMID:26308900

  17. Technical note: Methionine, a precursor of methane in living plants

    Directory of Open Access Journals (Sweden)

    K. Lenhart

    2014-11-01

    Full Text Available When terrestrial plants were identified as producers of the greenhouse gas methane, much discussion and debate ensued, not only about their contribution to the global methane budget, but also with regard to the validity of the observation itself. Although the phenomenon has now become more accepted for both living and dead plants, the mechanism of methane formation in living plants remains to be elucidated and its precursor compounds identified. We made use of stable isotope techniques to verify in vivo formation of methane and, in order to identify the carbon precursor, 13C-positionally labelled organic compounds were employed. Here we show that the amino acid L-methionine acts as a methane precursor in living plants. Employing 13C-labelled methionine clearly identified the sulphur-bound methyl group of methionine as a carbon precursor of methane released from lavender (Lavandula angustifolia. Furthermore, when lavender plants were stressed physically, methane release rates and the stable carbon isotope values of the emitted methane greatly increased. Our results provide additional support that plants possess a mechanism for methane production and suggest that methionine might play an important role in the formation of methane in living plants, particularly under stress conditions.

  18. Feasibility of atmospheric methane removal using methanotrophic biotrickling filters

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Sukhwan; Carey, Jeffrey N.; Semrau, Jeremy D. [Michigan Univ., Ann Arbor, MI (United States). Dept. of Civil and Environmental Engineering

    2009-07-15

    Methane is a potent greenhouse gas with a global warming potential {proportional_to}23 times that of carbon dioxide. Here, we describe the modeling of a biotrickling filtration system composed of methane-consuming bacteria, i.e., methanotrophs, to assess the utility of these systems in removing methane from the atmosphere. Model results indicate that assuming the global average atmospheric concentration of methane, 1.7 ppmv, methane removal is ineffective using these methanotrophic biofilters as the methane concentration is too low to enable cell survival. If the concentration is increased to 500-6,000 ppmv, however, similar to that found above landfills and in concentrated animal feeding operations (factory farms), 4.98-35.7 tons of methane can be removed per biofilter per year assuming biotrickling filters of typical size (3.66 m in diameter and 11.5 m in height). Using reported ranges of capital, operational, and maintenance costs, the cost of the equivalent ton of CO{sub 2} removal using these systems is $90-$910 ($2,070-$20,900 per ton of methane), depending on the influent concentration of methane and if heating is required. The use of methanotrophic biofilters for controlling methane emissions is technically feasible and, provided that either the costs of biofilter construction and operation are reduced or the value of CO{sub 2} credits is increased, can also be economically attractive. (orig.)

  19. Temporal Dynamics of Methane Fluxes in Temperate Urban Wetlands

    Science.gov (United States)

    Schafer, K. V.; Bohrer, G.; Naor, L.; Mouser, P. J.; Mitsch, W. J.; Wu, M.

    2011-12-01

    Recent concerns about wetland restoration have highlighted the potential conflict of the hydrological and ecological benefits of wetlands and greenhouse gas emissions particularly methane. Therefore it is pivotal to quantify emission rates and effects of meteorological, hydrological and ecological drivers of methane fluxes in wetlands. Novel fast methane (CH4) gas analyzers are now enabling continuous ecosystem scale measurements and assessment. We have set up two eddy flux stations - one in a constructed freshwater wetland in the Olentangy River Wetland Research Park (ORWRP) Ohio and one in a restored tidal salt marsh in the Meadowlands of New Jersey (MNJ). Continuous methane fluxes were measured with the LI7700 over one growing season and additional measurements with chambers were conducted at several locations in each site. Methane emissions were highly variable in space and time. The mean daily dynamics of methane emission are related to major drivers of methane production. In ORWRP a late afternoon peak of methane emission is correlated to soil temperature and no other meteorological or hydrological driver seem to explain the pattern observed. In MNJ a correlation of methane fluxes to night time CO2 fluxes was observed. At both sites methane production and emission is increasing at the beginning of the growing season.

  20. Mapping methane from marine and terrestrial hydrocarbon seepage using AVIRIS

    Science.gov (United States)

    Thorpe, A. K.; Bradley, E. S.; Funk, C.; Roberts, D. A.; Leifer, I.; Dennison, P. E.; Margolis, J.

    2010-12-01

    Concentrations of atmospheric methane (CH4), a greenhouse gas at least 20 times more potent per molecule than carbon dioxide (CO2), have more than doubled in the last two centuries. Due to a lack of direct measurements of sources and sinks, the global methane budget is poorly constrained and emissions of this important greenhouse gas are often underestimated in climate models. The Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) recently mapped methane emissions from the Coal Oil Point (COP) marine seep fields, a concentrated geologic methane source (0.015 Tg yr-1 from ~3 km2) located offshore from Santa Barbara, CA using a residual-based approach (Roberts et al. 2010) and short-wave infrared band ratios (Bradley et al. submitted). In this study, an additional cluster-tuned matched filter technique adapted from Funk et al. 2001 detected methane anomalies for COP that closely matched previous results and were in agreement with sonar-based seep surveys and flux buoy data. This technique was also applied to AVIRIS data acquired over the La Brea Tar Pits in Los Angeles, CA, a region known for natural oil and methane seepage. Significant anomalies were identified for known methane sources close to the tar pits where pipes have been established to prevent dangerous methane buildup. Therefore, imaging spectrometry using sensors like AVIRIS and planned satellite sensors like HyspIRI has the potential to greatly improve high spatial resolution mapping of methane emissions, thereby better constraining regional methane sources.

  1. Martian zeolites as a source of atmospheric methane

    Science.gov (United States)

    Mousis, Olivier; Simon, Jean-Marc; Bellat, Jean-Pierre; Schmidt, Frédéric; Bouley, Sylvain; Chassefière, Eric; Sautter, Violaine; Quesnel, Yoann; Picaud, Sylvain; Lectez, Sébastien

    2016-11-01

    The origin of the martian methane is still poorly understood. A plausible explanation is that methane could have been produced either by hydrothermal alteration of basaltic crust or by serpentinization of ultramafic rocks producing hydrogen and reducing crustal carbon into methane. Once formed, methane storage on Mars is commonly associated with the presence of hidden clathrate reservoirs. Here, we alternatively suggest that chabazite and clinoptilolite, which belong to the family of zeolites, may form a plausible storage reservoir of methane in the martian subsurface. Because of the existence of many volcanic terrains, zeolites are expected to be widespread on Mars and their Global Equivalent Layer may range up to more than ∼1 km, according to the most optimistic estimates. If the martian methane present in chabazite and clinoptilolite is directly sourced from an abiotic source in the subsurface, the destabilization of a localized layer of a few millimeters per year may be sufficient to explain the current observations. The sporadic release of methane from these zeolites requires that they also remained isolated from the atmosphere during its evolution. The methane release over the ages could be due to several mechanisms such as impacts, seismic activity or erosion. If the methane outgassing from excavated chabazite and/or clinoptilolite prevails on Mars, then the presence of these zeolites around Gale Crater could explain the variation of methane level observed by Mars Science Laboratory.

  2. Removal of methane from compressed natural gas fueled vehicle exhaust

    International Nuclear Information System (INIS)

    The objective of this paper is to investigate the modes of methane (CH4) removal from simulated compressed natural gas (CNG) fueled vehicle exhaust under net oxidizing, net reducing, and stoichiometric conditions. Model reaction studies were conducted. The results suggest that the oxidation of methane with oxygen contributes to the removal of methane under net oxidizing conditions. In contrast, the oxidation of methane with oxygen as well as nitric oxide contributes to its removal under net reducing conditions. The steam reforming reaction does not significantly contribute to the removal of methane. The methane conversions under net reducing conditions are higher than those observed under net oxidizing conditions. The study shows that the presence of carbon monoxide in the feed gas leads to a gradual decrease in the methane conversion with increasing redox ratio, under net oxidizing conditions. a minimum in methane conversion is observed at a redox ratio of 0. 8. The higher activity for the methane-oxygen reaction resulting from a lowering in the overall oxidation state of palladium and the contribution of the methane-nitric oxide reaction toward the removal of CH4 appear to account for the higher CH4 conversions observed under net reducing conditions

  3. Methane emission from flooded soils - from microorganisms to the atmosphere

    Science.gov (United States)

    Conrad, Ralf

    2016-04-01

    Methane is an important greenhouse gas that is affected by anthropogenic activity. The annual budget of atmospheric methane, which is about 600 million tons, is by more than 75% produced by methanogenic archaea. These archaea are the end-members of a microbial community that degrades organic matter under anaerobic conditions. Flooded rice fields constitute a major source (about 10%) of atmospheric methane. After flooding of soil, anaerobic processes are initiated, finally resulting in the disproportionation of organic matter to carbon dioxide and methane. This process occurs in the bulk soil, on decaying organic debris and in the rhizosphere. The produced methane is mostly ventilated through the plant vascular system into the atmosphere. This system also allows the diffusion of oxygen into the rizosphere, where part of the produced methane is oxidized by aerobic methanotrophic bacteria. More than 50% of the methane production is derived from plant photosynthetic products and is formed on the root surface. Methanocellales are an important group of methanogenic archaea colonizing rice roots. Soils lacking this group seem to result in reduced root colonization and methane production. In rice soil methane is produced by two major paths of methanogenesis, the hydrogenotrophic one reducing carbon dioxide to methane, and the aceticlastic one disproportionating acetate to methane and carbon dioxide. Theoretically, at least two third of the methane should be produced by aceticlastic and the rest by hydrogenotrophic methanogenesis. In nature, however, the exact contribution of the two paths can vary from zero to 100%. Several environmental factors, such as temperature and quality of organic matter affect the path of methane production. The impact of these factors on the composition and activity of the environmental methanogenic microbial community will be discussed.

  4. CYANOBACTERIA FOR MITIGATING METHANE EMISSION FROM SUBMERGED PADDY FIELDS

    Energy Technology Data Exchange (ETDEWEB)

    Upasana Mishra; Shalini Anand [Department of Environmental Studies, Inderprastha Engineering College, Sahibabad, Ghaziabad (India)

    2008-09-30

    Atmospheric methane, a potent greenhouse gas with high absorption potential for infrared radiation, is responsible for one forth of the total anticipated warming. It is forming a major part of green house gases, next after carbon dioxide. Its concentration has been increasing alarmingly on an average at the rate of one percent per year. Atmospheric methane, originating mainly from biogenic sources such as paddy fields, natural wetlands and landfills, accounts for 15-20% of the world's total anthropogenic methane emission. With intensification of rice cultivation in coming future, methane emissions from paddy fields are anticipated to increase. India's share in world's rice production is next after to China and likewise total methane emission from paddy fields also. Methane oxidation through planktophytes, particularly microalgae which are autotrophic and abundant in rice rhizospheres, hold promise in controlling methane emission from submerged paddy fields. The present study is focused on the role of nitrogen fixing, heterocystous cyanobacteria and Azolla (a water fern harboring a cyanobacterium Anabaena azollae) as biological sink for headspace concentration of methane in flooded soils. In this laboratory study, soil samples containing five potent nitrogen fixer cyanobacterial strains from paddy fields, were examined for their methane reducing potential. Soil sample without cyanobacterial strain was tested and taken as control. Anabaena sp. was found most effective in inhibiting methane concentration by 5-6 folds over the control. Moist soil cores treated with chemical nitrogen, urea, in combination with cyanobacteria mixture, Azolla microphylla or cyanobacteria mixture plus Azolla microphylla exhibited significance reduction in the headspace concentration of methane than the soil cores treated with urea alone. Contrary to other reports, this study also demonstrates that methane oxidation in soil core samples from paddy fields was stimulated by

  5. Cryolava flow destabilization of crustal methane clathrate hydrate on Titan

    Science.gov (United States)

    Davies, Ashley Gerard; Sotin, Christophe; Choukroun, Mathieu; Matson, Dennis L.; Johnson, Torrence V.

    2016-08-01

    To date, there has been no conclusive observation of ongoing endogenous volcanic activity on Saturn's moon Titan. However, with time, Titan's atmospheric methane is lost and must be replenished. We have modeled one possible mechanism for the replenishment of Titan's methane loss. Cryolavas can supply enough heat to release large amounts of methane from methane clathrate hydrates (MCH). The volume of methane released is controlled by the flow thickness and its areal extent. The depth of the destabilisation layer is typically ≈30% of the thickness of the lava flow (≈3 m for a 10-m thick flow). For this flow example, a maximum of 372 kg of methane is released per m2 of flow area. Such an event would release methane for nearly a year. One or two events per year covering ∼20 km2 would be sufficient to resupply atmospheric methane. A much larger effusive event covering an area of ≈9000 km2 with flows 200 m thick would release enough methane to sustain current methane concentrations for 10,000 years. The minimum size of "cryo-flows" sufficient to maintain the current atmospheric methane is small enough that their detection with current instruments (e.g., Cassini) could be challenging. We do not suggest that Titan's original atmosphere was generated by this mechanism. It is unlikely that small-scale surface MCH destabilisation is solely responsible for long-term (> a few Myr) sustenance of Titan's atmospheric methane, but rather we present it as a possible contributor to Titan's past and current atmospheric methane.

  6. Methane, where does it come from and what is its impact on climate?

    International Nuclear Information System (INIS)

    This report proposes a detailed presentation of knowledge on methane and on its role in the atmosphere. The first part addresses methane and the greenhouse effect: general considerations on methane in the atmosphere, radiative properties and importance with respect to the greenhouse effect, methane and future climate change. The second part proposes a presentation of methane sources and sinks. The third part addresses the study of methane fluxes: possible approaches to assess methane fluxes, measurement of atmospheric methane, the issue of atmospheric inversion (an approach to convert atmospheric observations into methane fluxes, lessons learned from atmospheric inversions, perspectives to improve knowledge on methane fluxes). The next chapters discuss the past, present and future evolution of methane in the atmosphere, discuss the carbon equivalence of methane (Kyoto protocol, policies of climate change, global warming power, role of methane, metrics, emission reduction), and comment the current perceivable evolutions, propose some methodological recommendations and actions to be implemented on the short term with no regret

  7. Metagenomics in methane seep detection and studies of the microbial methane sediment filter

    Science.gov (United States)

    Gunn Rike, Anne; Håvelsrud, Othilde Elise; Haverkamp, Thomas; Kristensen, Tom; Jakobsen, Kjetill

    2013-04-01

    Metanotrophic prokaryotes with their capacity to oxidize methane to biomass and CO2 contribute considerably in reduction of the global methane emission from oceans. Metagenomic studies of seabed sediments represent a new approach to detect marine methane seeps and to study whether the inhabiting microbial consortium represent a microbial methane filter. We have used next generation high throughput DNA sequencing technology to study microbial consortia and their potential metabolic processes in marine sediment samples from the Håkon Mosby mud volcano (HMMV) in the Barents Sea, the Tonya Seep in the Coal Oil Point area in California and from the pockmarked area at the Troll oil and gas field in the North Sea. Annotation of archaeal reads from the HMMV metagenome resulted in hits to all enzymes supposed to be involved in the anaerobic oxidation of methane (AOM) carried out by anaerobic methanotrophic archaea (ANME). The presence of several ANME taxa at HMMV has previously been well described (1). The stratification analysis of the Tonya seep sediment showed that both aerobic and anaerobic methanotrophs were present at both layers investigated, although total archaea, ANME-1, ANME-2 and ANME-3 were overabundant in the deepest layer. Several sulphate reducing taxa (possibly syntrophic ANME partners) were detected. The Tonya Seep sediment represent a robust methane filter where presently dominating methanotrophic taxa could be replaced by less abundant methanotrophs should the environmental conditions change (2). In the Troll pockmarked sediments several methanotrophic taxa including ANME-1, ANME-2 and candidate division NC10 were detected although there was an overabundance of autotrophic nitrifiers (e.g. Nitrosopumilis, Nitrococcus, Nitrospira) using CO2 as the carbon source. Methane migrating upwards through the sediments is probably oxidized to CO2 in AOM resulting in an upward CO2 flux. The CO2 entering the seafloor may contribute to maintain the pockmark structure

  8. Methane production from acid hydrolysates of Agave tequilana bagasse: evaluation of hydrolysis conditions and methane yield.

    Science.gov (United States)

    Arreola-Vargas, Jorge; Ojeda-Castillo, Valeria; Snell-Castro, Raúl; Corona-González, Rosa Isela; Alatriste-Mondragón, Felipe; Méndez-Acosta, Hugo O

    2015-04-01

    Evaluation of diluted acid hydrolysis for sugar extraction from cooked and uncooked Agave tequilana bagasse and feasibility of using the hydrolysates as substrate for methane production, with and without nutrient addition, in anaerobic sequencing batch reactors (AnSBR) were studied. Results showed that the hydrolysis over the cooked bagasse was more effective for sugar extraction at the studied conditions. Total sugars concentration in the cooked and uncooked bagasse hydrolysates were 27.9 g/L and 18.7 g/L, respectively. However, 5-hydroxymethylfurfural was detected in the cooked bagasse hydrolysate, and therefore, the uncooked bagasse hydrolysate was selected as substrate for methane production. Interestingly, results showed that the AnSBR operated without nutrient addition obtained a constant methane production (0.26 L CH4/g COD), whereas the AnSBR operated with nutrient addition presented a gradual methane suppression. Molecular analyses suggested that methane suppression in the experiment with nutrient addition was due to a negative effect over the archaeal/bacterial ratio.

  9. Methane bubble ascent within muddy aquatic sediments under different ambient methane source strengths

    Science.gov (United States)

    Tarboush Sirhan, Shahrazad; Katsman, Regina; Ten Brink, Uri

    2016-04-01

    Methane (CH4) is the simplest and, the most common hydrocarbon in nature. It is considered as one of the most adverse greenhouse gases, at least 25 times more potent than carbon dioxide. When concentration of the dissolved methane in pore waters exceeds the solubility of the gas (affected in turn by temperature, pressure, salinity and by other factors) methane bubbles nucleate. Gas migration in fine-grained cohesive muddy aquatic sediments is accompanied by sediment fracturing. When gas pressure is high enough to overcome compression, friction, and cohesion at grain contacts, gas migrates by pushing the grains apart. These sub-vertical fractures provide lowered-resistance conduits for migration of other bubbles that can destabilize sediment structure resulting even in slope failure. Therefore, understanding the processes governing bubble propagation within fine-grained aquatic sediment is important. Previous models showed that bubbles propagation within fine-grained muddy aquatic sediments can be modeled using principles of linear elastic fracture mechanics. Mass transfer between the bubble rising with high velocity and the surrounding sediments was mostly ignored. We use a coupled macroscopic mechanical/reaction-transport numerical model under a variable source strength profile associated with bio-chemical processes of methane production and consumption within the sediment, as it occurs in nature. The model shows that changes in the dissolved methane concentrations strongly affect bubble ascent velocity, sometimes leading to its retardation below the sediment-water interface

  10. New insights into the transport processes controlling the sulfate-methane-transition-zone near methane vents

    Science.gov (United States)

    Sultan, Nabil; Garziglia, Sébastien; Ruffine, Livio

    2016-05-01

    Over the past years, several studies have raised concerns about the possible interactions between methane hydrate decomposition and external change. To carry out such an investigation, it is essential to characterize the baseline dynamics of gas hydrate systems related to natural geological and sedimentary processes. This is usually treated through the analysis of sulfate-reduction coupled to anaerobic oxidation of methane (AOM). Here, we model sulfate reduction coupled with AOM as a two-dimensional (2D) problem including, advective and diffusive transport. This is applied to a case study from a deep-water site off Nigeria’s coast where lateral methane advection through turbidite layers was suspected. We show by analyzing the acquired data in combination with computational modeling that a two-dimensional approach is able to accurately describe the recent past dynamics of such a complex natural system. Our results show that the sulfate-methane-transition-zone (SMTZ) is not a vertical barrier for dissolved sulfate and methane. We also show that such a modeling is able to assess short timescale variations in the order of decades to centuries.

  11. Methane production from acid hydrolysates of Agave tequilana bagasse: evaluation of hydrolysis conditions and methane yield.

    Science.gov (United States)

    Arreola-Vargas, Jorge; Ojeda-Castillo, Valeria; Snell-Castro, Raúl; Corona-González, Rosa Isela; Alatriste-Mondragón, Felipe; Méndez-Acosta, Hugo O

    2015-04-01

    Evaluation of diluted acid hydrolysis for sugar extraction from cooked and uncooked Agave tequilana bagasse and feasibility of using the hydrolysates as substrate for methane production, with and without nutrient addition, in anaerobic sequencing batch reactors (AnSBR) were studied. Results showed that the hydrolysis over the cooked bagasse was more effective for sugar extraction at the studied conditions. Total sugars concentration in the cooked and uncooked bagasse hydrolysates were 27.9 g/L and 18.7 g/L, respectively. However, 5-hydroxymethylfurfural was detected in the cooked bagasse hydrolysate, and therefore, the uncooked bagasse hydrolysate was selected as substrate for methane production. Interestingly, results showed that the AnSBR operated without nutrient addition obtained a constant methane production (0.26 L CH4/g COD), whereas the AnSBR operated with nutrient addition presented a gradual methane suppression. Molecular analyses suggested that methane suppression in the experiment with nutrient addition was due to a negative effect over the archaeal/bacterial ratio. PMID:25647030

  12. Titan's transport-driven methane cycle

    CERN Document Server

    Mitchell, Jonathan L

    2012-01-01

    The strength of Titan's methane cycle, as measured by precipitation and evaporation, is key to interpreting fluvial erosion and other indicators of the surface-atmosphere exchange of liquids. But the mechanisms behind the occurrence of large cloud outbursts and precipitation on Titan have been disputed. A gobal- and annual-mean estimate of surface fluxes indicated only 1% of the insolation, or $\\sim$0.04 W/m$^2$, is exchanged as sensible and/or latent fluxes. Since these fluxes are responsible for driving atmospheric convection, it has been argued that moist convection should be quite rare and precipitation even rarer, even if evaporation globally dominates the surface-atmosphere energy exchange. In contrast, climate simulations that allow atmospheric motion indicate a robust methane cycle with substantial cloud formation and/or precipitation. We argue the top-of-atmosphere radiative imbalance -- a readily observable quantity -- is diagnostic of horizontal heat transport by Titan's atmosphere, and thus constr...

  13. Regulation of methane genes and genome expression

    Energy Technology Data Exchange (ETDEWEB)

    John N. Reeve

    2009-09-09

    At the start of this project, it was known that methanogens were Archaeabacteria (now Archaea) and were therefore predicted to have gene expression and regulatory systems different from Bacteria, but few of the molecular biology details were established. The goals were then to establish the structures and organizations of genes in methanogens, and to develop the genetic technologies needed to investigate and dissect methanogen gene expression and regulation in vivo. By cloning and sequencing, we established the gene and operon structures of all of the “methane” genes that encode the enzymes that catalyze methane biosynthesis from carbon dioxide and hydrogen. This work identified unique sequences in the methane gene that we designated mcrA, that encodes the largest subunit of methyl-coenzyme M reductase, that could be used to identify methanogen DNA and establish methanogen phylogenetic relationships. McrA sequences are now the accepted standard and used extensively as hybridization probes to identify and quantify methanogens in environmental research. With the methane genes in hand, we used northern blot and then later whole-genome microarray hybridization analyses to establish how growth phase and substrate availability regulated methane gene expression in Methanobacterium thermautotrophicus ΔH (now Methanothermobacter thermautotrophicus). Isoenzymes or pairs of functionally equivalent enzymes catalyze several steps in the hydrogen-dependent reduction of carbon dioxide to methane. We established that hydrogen availability determine which of these pairs of methane genes is expressed and therefore which of the alternative enzymes is employed to catalyze methane biosynthesis under different environmental conditions. As were unable to establish a reliable genetic system for M. thermautotrophicus, we developed in vitro transcription as an alternative system to investigate methanogen gene expression and regulation. This led to the discovery that an archaeal protein

  14. An innovative membrane bioreactor for methane biohydroxylation.

    Science.gov (United States)

    Pen, N; Soussan, L; Belleville, M-P; Sanchez, J; Charmette, C; Paolucci-Jeanjean, D

    2014-12-01

    In this study, a membrane bioreactor (MBR) was developed for efficient, safe microbial methane hydroxylation with Methylosinus trichosporium OB3b. This innovative MBR, which couples a bioreactor with two gas/liquid macroporous membrane contactors supplying the two gaseous substrates (methane and oxygen) was operated in fed-batch mode. The feasibility and the reproducibility of this new biohydroxylation process were first demonstrated. The mass transfer within this MBR was twice that observed in a batch reactor in similar conditions. The productivity reached with this MBR was 75±25mgmethanol(gdrycell)(-1)h(-1). Compared to the literature, this value is 35times higher than that obtained with the only other fed-batch membrane bioreactor reported, which was run with dense membranes, and is comparable to those obtained with bioreactors fed by bubble-spargers. However, in the latter case, an explosive gas mixture can be formed, a problem that is avoided with the MBR.

  15. SYNTHETIC APPROACHES FOR BIS (INDOLYL METHANES

    Directory of Open Access Journals (Sweden)

    Partha Pratim Kaishap* and Chandrajit Dohutia

    2013-04-01

    Full Text Available ABSTRACT: Indole ring system is the most important heterocycle available in natural compounds. Owing to great structural diversity, the indole ring system has become an important structural requirement in many pharmaceutical agents. Indole has been widely identified as a privileged structure or pharmacophore, with its presence in over 3000 natural isolates which are known to possess broad spectrum of biological activities and pharmaceutical applications. The bis (indolyl methane derivatives are found to be very active compounds in pharmacy field. They are found in cruciferous plants and are known to promote beneficial oestrogen metabolism and induce apoptosis in human cancer cells. In recent years, a lots of bis (indolyl methane derivatives have been synthesized and found to possess promising biological activities including anticancer, antimicrobial, antifungal, analgesic, anti-inflammatory, anthelmintic, cardiovascular activities. In the present review several synthetic schemes of these compounds are discussed involving non-toxic catalyst and providing high yields.

  16. Aqueous solvation of methane from first principles

    CERN Document Server

    Rossato, Lorenzo; Silvestrelli, Pier Luigi

    2012-01-01

    Structural, dynamical, bonding, and electronic properties of water molecules around a soluted methane molecule are studied from first principles. The results are compatible with experiments and qualitatively support the conclusions of recent classical Molecular Dynamics simulations concerning the controversial issue on the presence of "immobilized" water molecules around hydrophobic groups: the hydrophobic solute slightly reduces (by a less than 2 factor) the mobility of many surrounding water molecules rather than immobilizing just the few ones which are closest to methane, similarly to what obtained by previous first-principles simulations of soluted methanol. Moreover, the rotational slowing down is compatible with that one predicted on the basis of the excluded volume fraction, which leads to a slower Hydrogen bond-exchange rate. The analysis of simulations performed at different temperatures suggests that the target temperature of the soluted system must be carefully chosen, in order to avoid artificial ...

  17. Nitrogen as a regulatory factor of methane oxidation in soils and sediments

    NARCIS (Netherlands)

    Bodelier, P.L.E.; Laanbroek, H.J.

    2004-01-01

    The oxidation of methane by methane-oxidising microorganisms is an important link in the global methane budget. Oxic soils are a net sink while wetland soils are a net source of atmospheric methane. It has generally been accepted that the consumption of methane in upland as well as lowland systems i

  18. Can rapeseed lower methane emission from heifers?

    DEFF Research Database (Denmark)

    Hellwing, Anne Louise Frydendahl; Sørensen, Martin Tang; Weisbjerg, Martin Riis;

    2013-01-01

    Twelve heifers were assigned to either a control diet (CON) with 26 g fat per kg dry matter (DM) or a supplemented diet (FAT) with crushed rapeseed with 53 g fat per kg DM. Methane (CH4) emission was measured by open-circuit indirect calorimetry for four days when the heifers weighed approximately.......08). It is concluded that the FAT may have potential to reduce CH4 emission from heifers, but further studies are warranted to document this effect....

  19. Methane conversion to hydrocarbons by double discharge

    Directory of Open Access Journals (Sweden)

    A. M. Ghorbanzadeh

    2004-12-01

    Full Text Available   Methane conversion to higher hydrocarbons by pulsed glow discharge at the atmospheric pressure was investigated. The energy efficiency up to 10 % was obtained which is higher than any value ever published for nonequilibrium plasma conversion of pure methame. This method has a potential for development and it is expected that the energy efficiency will be improved further if the plasma parameters are optimized.

  20. Cross Sections for Electron Collisions with Methane

    Energy Technology Data Exchange (ETDEWEB)

    Song, Mi-Young, E-mail: mysong@nfri.re.kr; Yoon, Jung-Sik [Plasma Technology Research Center, National Fusion Research Institute, 814-2 Osikdo-dong, Gunsan, Jeollabuk-do 573-540 (Korea, Republic of); Cho, Hyuck [Department of Physics, Chungnam National University, Daejeon 305-764 (Korea, Republic of); Itikawa, Yukikazu [Institute of Space and Astronautical Science, Sagamihara 252-5210 (Japan); Karwasz, Grzegorz P. [Faculty of Physics, Astronomy and Applied Informatics, University Nicolaus Copernicus, Grudziadzka 5, 87100 Toruń (Poland); Kokoouline, Viatcheslav [Department of Physics, University of Central Florida, Orlando, Florida 32816 (United States); Nakamura, Yoshiharu [6-1-5-201 Miyazaki, Miyamae, Kawasaki 216-0033 (Japan); Tennyson, Jonathan [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom)

    2015-06-15

    Cross section data are compiled from the literature for electron collisions with methane (CH{sub 4}) molecules. Cross sections are collected and reviewed for total scattering, elastic scattering, momentum transfer, excitations of rotational and vibrational states, dissociation, ionization, and dissociative attachment. The data derived from swarm experiments are also considered. For each of these processes, the recommended values of the cross sections are presented. The literature has been surveyed through early 2014.

  1. TITAN'S TRANSPORT-DRIVEN METHANE CYCLE

    International Nuclear Information System (INIS)

    The mechanisms behind the occurrence of large cloud outbursts and precipitation on Titan have been disputed. A global- and annual-mean estimate of surface fluxes indicated only 1% of the insolation, or ∼0.04 W m–2, is exchanged as sensible and/or latent fluxes. Since these fluxes are responsible for driving atmospheric convection, it has been argued that moist convection should be quite rare and precipitation even rarer, even if evaporation globally dominates the surface-atmosphere energy exchange. In contrast, climate simulations indicate substantial cloud formation and/or precipitation. We argue that the top-of-atmosphere (TOA) radiative imbalance is diagnostic of horizontal heat transport by Titan's atmosphere, and thus constrains the strength of the methane cycle. Simple calculations show the TOA radiative imbalance is ∼0.5-1 W m–2 in Titan's equatorial region, which implies 2-3 MW of latitudinal heat transport by the atmosphere. Our simulation of Titan's climate suggests this transport may occur primarily as latent heat, with net evaporation at the equator and net accumulation at higher latitudes. Thus, the methane cycle could be 10-20 times previous estimates. Opposing seasonal transport at solstices, compensation by sensible heat transport, and focusing of precipitation by large-scale dynamics could further enhance the local, instantaneous strength of Titan's methane cycle by a factor of several. A limited supply of surface liquids in regions of large surface radiative imbalance may throttle the methane cycle, and if so, we predict more frequent large storms over the lakes district during Titan's northern summer.

  2. Experimental Dissociation of Methane Hydrates Through Depressurization

    Science.gov (United States)

    Borgfeldt, T.; Flemings, P. B.; Meyer, D.; You, K.

    2015-12-01

    We dissociated methane hydrates by stepwise depressurization. The initial hydrates were formed by injecting gas into a cylindrical sample of brine-saturated, coarse-grained sand at hydrate-stable conditions with the intention of reaching three-phase equilibrium. The sample was initially at 1°C with a pore pressure of 1775 psi and a salinity of 7 wt. % NaBr. The depressurization setup consisted of one pump filled with tap water attached to the confining fluid port and a second pump attached to the inlet port where the methane was injected. Depressurization was conducted over sixteen hours at a constant temperature of 1°C. The pore pressure was stepwise reduced from 1775 psi to atmospheric pressure by pulling known volumes of gas from the sample. After each extraction, we recorded the instantaneous and equilibrium pore pressure. 0.503 moles of methane were removed from the sample. The pore pressure decreased smoothly and nonlinearly with the cumulative gas withdrawn from the sample. We interpret that hydrate began to dissociate immediately with depressurization, and it continued to dissociate when the pressure decreased below the three-phase pressure for 1°C and 0 wt. % salinity. Two breaks in slope in the pressure vs. mass extracted data are bounded by smooth, nonlinear curves with differing slopes on either side. We attribute the breaks to dissociation of three zones of hydrate concentration. We created a box model to simulate the experimental behavior. For a 10% initial gas saturation (estimated from the hydrate formation experiment and based on mass conservation), an initial hydrate saturation of 55% is required to match the total methane extracted from the sample. Future experiments will be conducted over a longer timespan while monitoring hydrate dissociation with CT imaging throughout the process.

  3. Selective Catalytic Reduction of NO with Methane

    Institute of Scientific and Technical Information of China (English)

    Xiang Gao; Qi Yu; Limin Chen

    2003-01-01

    The removal of nitrogen oxides from exhaust gases has attracted great attention in recent years, and many approaches have been developed depending on the application. Methane, the main component of natural gas, has great potential as a NO reductant. In this paper, a number of catalysts previous reported for this catalytic reduction of NO have been reviewed, including a direct comparison of the relative activities and effective factors of the catalysts. Reaction mechanisms have also been explored preliminarily.

  4. Energy gases: The methane age and beyond

    OpenAIRE

    Nakicenovic, N.

    1994-01-01

    The combustion of fossil fuels results in the emissions of gases and pollutants that produce adverse ecological effects. Evidence is also accumulating that suggest they may also cause global climate change. The combustion gases that are connected with global climate change are primarily carbon dioxide (CO2) and to a lesser degree methane (CH4). All of these gases already occur in low concentrations in the atmosphere and, in fact, together with other greenhouse gases, such as water vapor, have...

  5. Biomass gasification for the production of methane

    OpenAIRE

    Nanou, P.

    2013-01-01

    Biomass is very promising as a sustainable alternative to fossil resources because it is a renewable source that contains carbon, an essential building block for gaseous and liquid fuels. Methane is the main component of natural gas, which is a fuel used for heating, power generation and transportation. In The Netherlands, the contribution of natural gas to the primary energy consumption is almost 50% (Source: Energy Research Centre of The Netherlands [ECN]) and it is a fuel with a well-devel...

  6. Prediction of enteric methane emissions from cattle

    OpenAIRE

    Moraes, LE; Strathe, AB; Fadel, JG; Casper, DP; Kebreab, E.

    2014-01-01

    Agriculture has a key role in food production worldwide and it is a major component of the gross domestic product of several countries. Livestock production is essential for the generation of high quality protein foods and the delivery of foods in regions where animal products are the main food source. Environmental impacts of livestock production have been examined for decades, but recently emission of methane from enteric fermentation has been targeted as a substantial greenhouse gas source...

  7. Coalbed methane resource of Jingcheng mining area

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Y.; Zhang, Z.; Wang, H. [Shanxi Coal Field Research Institute, Taiyuan (China)

    2001-06-01

    Through researching a large quantity of data on the coalbed methane (CBM) resource in Jingcheng mining area, a scheme of CBM resource statistical division is put forward, which comprises 4 sections and 3 grades. According to this division scheme, the CBM resources in Daning district No.2 mine, Panzhuang district No.1 mine, and Panzhung district No.2 mine are calculated in detail. 4 tabs.

  8. Importance of methane-oxidizing bacteria in the methane budget as revealed by the use of a specific inhibitor

    Science.gov (United States)

    Oremland, R.S.; Culbertson, C.W.

    1992-01-01

    METHANE is a greenhouse gas whose concentration in the atmosphere is increasing1-3 Much of this methane is derived from the metabolism of methane-generating (methanogenic) bacteria4,5, and over the past two decades much has been learned about the ecology of methanogens; specific inhibitors of methanogenesis, such as 2-bromoethanesulphonic acid, have proved useful in this regard6. In contrast, although much is known about the biochemistry of methane-oxidizing (methanotrophic) bacteria7, ecological investigations have been hampered by the lack of an analogous specific inhibitor6. Methanotrophs limit the flux of methane to the atmosphere from sediments8,9 and consume atmospheric methane10, but the quantitative importance of methanotrophy in the global methane budget is not well known5. Methylfluoride (CH3F) is known to inhibit oxygen consumption by Methylococcus capsulatus11, and to inhibit the oxidation of 14CH4 to 14CO2 by endosymbionts in mussel gill tissues12. Here we report that methylfluoride (MF) inhibits the oxidation of methane by methane monooxygenase, and by using methylfluoride in field investigations, we find that methanotrophic bacteria can consume more than 90% of the methane potentially available.

  9. The Application of Methane Clumped Isotope Measurements to Determine the Source of Large Methane Seeps in Alaskan Lakes

    Science.gov (United States)

    Douglas, P. M.; Stolper, D. A.; Eiler, J. M.; Sessions, A. L.; Walter Anthony, K. M.

    2014-12-01

    Natural methane emissions from the Arctic present an important potential feedback to global warming. Arctic methane emissions may come from either active microbial sources or from deep fossil reservoirs released by the thawing of permafrost and melting of glaciers. It is often difficult to distinguish between and quantify contributions from these methane sources based on stable isotope data. Analyses of methane clumped isotopes (isotopologues with two or more rare isotopes such as 13CH3D) can complement traditional stable isotope-based classifications of methane sources. This is because clumped isotope abundances (for isotopically equilibrated systems) are a function of temperature and can be used to identify pathways of methane generation. Additionally, distinctive effects of mixing on clumped isotope abundances make this analysis valuable for determining the origins of mixed gasses. We find large variability in clumped isotope compositions of methane from seeps in several lakes, including thermokarst lakes, across Alaska. At Lake Sukok in northern Alaska we observe the emission of dominantly thermogenic methane, with a formation temperature of at least 100° C. At several other lakes we find evidence for mixing between thermogenic methane and biogenic methane that forms in low-temperature isotopic equilibrium. For example, at Eyak Lake in southeastern Alaska, analysis of three methane samples results in a distinctive isotopic mixing line between a high-temperature end-member that formed between 100-170° C, and a biogenic end-member that formed in isotopic equilibrium between 0-20° C. In this respect, biogenic methane in these lakes resembles observations from marine gas seeps, oil degradation, and sub-surface aquifers. Interestingly, at Goldstream Lake in interior Alaska, methane with strongly depleted clumped-isotope abundances, indicative of disequilibrium gas formation, is found, similar to observations from methanogen culture experiments.

  10. TAMARIND SEEDS CARBON: PREPRARTION AND METHANE UPTAKE

    Directory of Open Access Journals (Sweden)

    K. Munusamy

    2011-02-01

    Full Text Available Tamarind seeds carbon (TSC from tamarind (Tamarindus indica seeds, an agro-byproduct and waste that is available abundantly in the southern states of India, was prepared by chemical activation with KOH. The influence of tamarind seeds char to KOH weight ratio (1:1 to 1:4 and activation temperature (400 to 800 °C were investigated. TSC having micro-pore volume as high as 1.0 cm3/g with surface area 2673 m2/g was obtained. TSC was characterized by scanning electron microscopy, powder X-ray diffraction analysis, thermogravimetric analysis, and FT-IR spectroscopy. The potential of TSC to be used as a methane storage material was tested and compared with a commercial activated carbon. The highest methane adsorption capacity obtained for TSC was ca. 32.5 cm3/g at 30 °C and 1 bar. The maximum methane storage capacity achieved was 180 cm3/g at 30 °C and 35 bars.

  11. Hydrogen bonds in methane-water clusters.

    Science.gov (United States)

    Salazar-Cano, Juan-Ramón; Guevara-García, Alfredo; Vargas, Rubicelia; Restrepo, Albeiro; Garza, Jorge

    2016-08-24

    Characterization of hydrogen bonds in CH4-(H2O)12 clusters was carried out by using several quantum chemistry tools. An initial stochastic search provided around 2 500 000 candidate structures, then, using a convex-hull polygon criterion followed by gradient based optimization under the Kohn-Sham scheme, a total of 54 well defined local minima were located in the Potential Energy Surface. These structures were further analyzed through second-order many-body perturbation theory with an extended basis set at the MP2/6-311++G(d,p) level. Our analysis of Gibbs energies at several temperatures clearly suggests a structural preference toward compact water clusters interacting with the external methane molecule, instead of the more commonly known clathrate-like structures. This study shows that CH4-(H2O)12 clusters may be detected at temperatures up to 179 K, this finding provides strong support to a recently postulated hypothesis that suggests that methane-water clusters could be present in Mars at these conditions. Interestingly, we found that water to water hydrogen bonding is strengthened in the mixed clusters when compared to the isolated water dimer, which in turn leads to a weakening of the methane to water hydrogen bonding when compared to the CH4-(H2O) dimer. Finally, our evidence places a stern warning about the abilities of popular geometrical criteria to determine the existence of hydrogen bonds. PMID:27492605

  12. Determination of Methane Sourcex Globally by Sciamachy

    Science.gov (United States)

    Park, J. G.; Park, S. Y.

    2016-06-01

    Since the beginning of the industrial revolution, the atmospheric concentration of carbon dioxide (CO2) has increased by nearly 30%, and the Methane (CH4) concentration has more than doubled. CH4 is the second most important greenhouse gas, after CO2. Emissions, extrapolated from measurements of actual gas flux from wetlands, vary from place to place, even within the same wetland. This high variability makes large-scale estimates difficult and means that average emissions levels include a large degree of estimated uncertainty. The SCIAMACHY instrument on the European Space Agency satellite ENVISAT measured greenhouse gases in the troposphere and stratosphere. In this study, the CH4 source area is extracted by estimating the concentrations of methane emissions from time-series satellite data. Contamination of the data by cloud is interpolated both spatially and temporally. It is assumed that methane emission is negligible over ocean and that the concentration in the ocean area is due to advection from land. Background CH4 concentration on land was defined as the ocean CH4 concentration at the same latitude. Land CH4 emission concentrations show that areas of concentrated high CH4 emission are not in paddy fields only but also in broadleaf evergreen areas in South America and Central Africa.

  13. Aerobic methane production from organic matter

    Science.gov (United States)

    Vigano, I.

    2010-01-01

    Methane, together with H2O, CO2 and N2O, is an important greenhouse gas in th e Earth’s atmosphere playing a key role in the radiative budget. It has be en known for decades that the production of the reduced compound CH4 is possible almost exclusively in anoxic environments per opera of one of the most importan t class of microorganisms which form the Archaea reign. Methane can be produced also from incomplete combustion of organic material. The generation of CH4 in an oxygenated environment under near-ambient conditions is a new discovery made in 2006 by Keppler et. al where surprisingly they measured emissions of this green house gas from plants incubated in chambers with air containing 20% of oxygen. A lthough the estimates on a global scale are still object of an intensive debate, the results presented in this thesis clearly show the existence of methane prod uction under oxic conditions for non living plant material. Temperature and UV l ight are key factors that drive the generation of CH4 from plant matter in a wel l oxygenated environment.

  14. Thermodynamic analysis of nonoxidative dehydroaromatization of methane

    Energy Technology Data Exchange (ETDEWEB)

    Moghimpour Bijani, P.; Sohrabi, M. [Amirkabir University of Technology, Chemical Engineering Department, Tehran (Iran, Islamic Republic of); Sahebdelfar, S. [Petrochemical Research and Technology Company, National Petrochemical Company, Catalyst Research Group, Tehran (Iran, Islamic Republic of)

    2012-10-15

    The thermodynamics of methane dehydroaromatization in the absence and presence of coke-removing agents was studied using the Gibbs free energy minimization approach. Numerical results indicated that higher temperatures and lower pressures increase methane conversion as well as formation of olefins and aromatics but suppress that of paraffins. Higher H{sub 2}/CH{sub 4} ratios enhance the selectivity of light hydrocarbons but reduce that of naphthalene. Benzene selectivity has a maximum at an H{sub 2}/CH{sub 4} molar ratio of 0.26. Methane conversion exhibits a minimum at an H{sub 2}O/CH{sub 4} molar ratio of 0.07. As the H{sub 2}O/CH{sub 4} ratio increases, formations of heavier hydrocarbons decrease at the expense of CO, CO{sub 2}, and hydrogen. These results may provide guidelines to improve the process performance. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  15. Thatcher Bay, Washington, Nearshore Restoration Assessment

    Science.gov (United States)

    Breems, Joel; Wyllie-Echeverria, Sandy; Grossman, Eric E.; Elliott, Joel

    2009-01-01

    The San Juan Archipelago, located at the confluence of the Puget Sound, the Straits of Juan de Fuca in Washington State, and the Straits of Georgia, British Columbia, Canada, provides essential nearshore habitat for diverse salmonid, forage fish, and bird populations. With 408 miles of coastline, the San Juan Islands provide a significant portion of the available nearshore habitat for the greater Puget Sound and are an essential part of the regional efforts to restore Puget Sound (Puget Sound Shared Strategy 2005). The nearshore areas of the San Juan Islands provide a critical link between the terrestrial and marine environments. For this reason the focus on restoration and conservation of nearshore habitat in the San Juan Islands is of paramount importance. Wood-waste was a common by-product of historical lumber-milling operations. To date, relatively little attention has been given to the impact of historical lumber-milling operations in the San Juan Archipelago. Thatcher Bay, on Blakely Island, located near the east edge of the archipelago, is presented here as a case study on the restoration potential for a wood-waste contaminated nearshore area. Case study components include (1) a brief discussion of the history of milling operations. (2) an estimate of the location and amount of the current distribution of wood-waste at the site, (3) a preliminary examination of the impacts of wood-waste on benthic flora and fauna at the site, and (4) the presentation of several restoration alternatives for the site. The history of milling activity in Thatcher Bay began in 1879 with the construction of a mill in the southeastern part of the bay. Milling activity continued for more than 60 years, until the mill closed in 1942. Currently, the primary evidence of the historical milling operations is the presence of approximately 5,000 yd3 of wood-waste contaminated sediments. The distribution and thickness of residual wood-waste at the site was determined by using sediment

  16. Daya Bay Antineutrino Detector Gas System

    CERN Document Server

    Band, H R; Chu, M-C; Heeger, K M; Kwok, M W; Shih, K; Wise, T; Xiao, Q

    2012-01-01

    The Daya Bay Antineutrino Detector gas system is designed to protect the liquid scintillator targets of the antineutrino detectors against degradation and contamination from exposure to ambient laboratory air. The gas system is also used to monitor the leak tightness of the antineutrino detector assembly. The cover gas system constantly flushes the gas volumes above the liquid scintillator with dry nitrogen to minimize oxidation of the scintillator over the five year lifetime of the experiment. This constant flush also prevents the infiltration of radon or other contaminants into these detecting liquids keeping the internal backgrounds low. Since the Daya Bay antineutrino detectors are immersed in the large water pools of the muon veto system, other gas volumes are needed to protect vital detector cables or gas lines. These volumes are also purged with dry gas. Return gas is monitored for oxygen content and humidity to provide early warning of potentially damaging leaks. The design and performance of the Daya...

  17. The Bay of Pigs: Revisiting Two Museums

    Directory of Open Access Journals (Sweden)

    Peter Read

    2007-08-01

    Full Text Available The Museum of Playa Giron (the Bay of Pigs in the region of Cienega De Zapata, Cuba, celebrates the repulse of Brigade 2506 as the first reverse of US imperialism on the American continents. The equivalent Brigade 2506 Museum in Miami, dedicated to and maintained by the members of Brigade 2506, celebrates defeat at the Bay of Pigs as moral victory for the Cuban exiles. The forces were indeed implacable foes. Yet between the museums can be detected some curious similarities. Both present the common theme of the confrontation between forces of good and evil. Both celebrate the philosophy that dying for one’s country is the greatest good a citizen may achieve. Both museums fly the common Cuban flag. Both museums identify a common enemy: the United States of America. This article, by comparing the displays in the two museums, analyses some cultural elements of what, despite decades of separation, in some ways remains a common Cuban culture.

  18. Process for separating nitrogen from methane using microchannel process technology

    Science.gov (United States)

    Tonkovich, Anna Lee; Qiu, Dongming; Dritz, Terence Andrew; Neagle, Paul; Litt, Robert Dwayne; Arora, Ravi; Lamont, Michael Jay; Pagnotto, Kristina M.

    2007-07-31

    The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

  19. Martian zeolites as a source of atmospheric methane

    CERN Document Server

    Mousis, Olivier; Bellat, Jean-Pierre; Schmidt, Frédéric; Bouley, Sylvain; Chassefière, Eric; Sautter, Violaine; Quesnel, Yoann; Picaud, Sylvain; Lectez, Sébastien

    2016-01-01

    The origin of the martian methane is still poorly understood. A plausible explanation is that methane could have been produced either by hydrothermal alteration of basaltic crust or by serpentinization of ultramafic rocks producing hydrogen and reducing crustal carbon into methane. Once formed, methane storage on Mars is commonly associated with the presence of hidden clathrate reservoirs. Here, we alternatively suggest that chabazite and clinoptilolite, which belong to the family of zeolites, may form a plausible storage reservoir of methane in the martian subsurface. Because of the existence of many volcanic terrains, zeolites are expected to be widespread on Mars and their Global Equivalent Layer may range up to more than $\\sim$1 km, according to the most optimistic estimates. If the martian methane present in chabazite and clinoptilolite is directly sourced from an abiotic source in the subsurface, the destabilization of a localized layer of a few millimeters per year may be sufficient to explain the curr...

  20. Kinetics of methane oxidation in selected mineral soils

    Science.gov (United States)

    Walkiewicz, A.; Bulak, P.; Brzeziñska, M.; Włodarczyk, T.; Polakowski, C.

    2012-10-01

    The kinetic parameters of methane oxidation in three mineral soils were measured under laboratory conditions. Incubationswere preceded by a 24-day preincubationwith 10%vol. of methane. All soils showed potential to the consumption of added methane. None of the soils, however, consumed atmospheric CH4. Methane oxidation followed the Michaelis-Menten kinetics, with relatively low values of parameters for Eutric Cambisol, while high values for Haplic Podzol, and especially for Mollic Gleysol which showed the highest methanotrophic activity and much lower affinity to methane. The high values of parameters for methane oxidation are typical for organic soils and mineral soils from landfill cover. The possibility of the involvement of nitrifying microorganisms, which inhabit the ammonia-fertilized agricultural soils should be verified.

  1. Methane from domestic animals: Possibilities for reduction by methane inhibitors; Methan fra husdyr: Muligheder for reduktion ved brug af metanhaemmende stoffer

    Energy Technology Data Exchange (ETDEWEB)

    Weisbjerg, M.R. [Danmarks JordbrugsForskning. Afd. for Husdyrsundhed, Velfaerd og Ernaering, Tjele (Denmark)

    2005-01-01

    Ruminant's enteric fermentation implies production of methane. A number of substances might have an impact on the production of methane, either through influence on the composition of rumen microbes or through hydrogen consumption. Changing the rumen micro-flora composition through biological methods might also influence the methane production. Several chemical methane inhibitors will not be acceptable for use in cattle farming, and the use of biological methods is technological immature. The most promising methods acceptable for general use are the use of bacteriocines, e.g. Nisin, and application of hydrogen consuming substances as fumarat or malat to the fodder. Furthermore, serums with the ability to further antibody production against methanogen bacteria are being developed, which would reduce the methane production. (BA)

  2. Bayes linear variance adjustment for time series

    CERN Document Server

    Wilkinson, Darren J

    2008-01-01

    This paper exhibits quadratic products of linear combinations of observables which identify the covariance structure underlying the univariate locally linear time series dynamic linear model. The first- and second-order moments for the joint distribution over these observables are given, allowing Bayes linear learning for the underlying covariance structure for the time series model. An example is given which illustrates the methodology and highlights the practical implications of the theory.

  3. Whose Bay Street? Competing Narratives of Nassau's City Centre

    Directory of Open Access Journals (Sweden)

    Nona Patara Martin

    2009-05-01

    Full Text Available Bay Street has always been at the centre of commercial, cultural and political life in the Bahama Islands. It also acts as a gateway for millions of tourists who come to Nassau, the Bahamian capital, via cruise ships every year. Not surprisingly, Bahamians and non-Bahamians have widely divergent impressions of Bay Street. The need to accommodate the tourists who are critical to the Bahamian economy has meant that Bay Street, despite its deep social significance for Bahamians, has increasingly become a tourist space. With reference to the ‘sense of place’ and place attachment literature, this paper traces the transformation of Bay Street and attempts to tease out the most obvious tensions between the Bay Street that Bahamians experience and Bay Street as a port of call.

  4. An overview of San Francisco Bay PORTS

    Science.gov (United States)

    Cheng, Ralph T.; McKinnie, David; English, Chad; Smith, Richard E.

    1998-01-01

    The Physical Oceanographic Real-Time System (PORTS) provides observations of tides, tidal currents, and meteorological conditions in real-time. The San Francisco Bay PORTS (SFPORTS) is a decision support system to facilitate safe and efficient maritime commerce. In addition to real-time observations, SFPORTS includes a nowcast numerical model forming a San Francisco Bay marine nowcast system. SFPORTS data and nowcast numerical model results are made available to users through the World Wide Web (WWW). A brief overview of SFPORTS is presented, from the data flow originated at instrument sensors to final results delivered to end users on the WWW. A user-friendly interface for SFPORTS has been designed and implemented. Appropriate field data analysis, nowcast procedures, design and generation of graphics for WWW display of field data and nowcast results are presented and discussed. Furthermore, SFPORTS is designed to support hazardous materials spill prevention and response, and to serve as resources to scientists studying the health of San Francisco Bay ecosystem. The success (or failure) of the SFPORTS to serve the intended user community is determined by the effectiveness of the user interface.

  5. Characteristics of the energy metabolism of the White Sea herring Clupea pallasii marisalbi Berg (Clupeiformes, Clupeidae) of Onega Bay, Dvina Bay, and Kandalaksha Bay of the White Sea.

    Science.gov (United States)

    Nemova, N N; Meshcheryakova, O V; Churova, M V; Murzina, S A

    2016-07-01

    The activity of the enzymes of the energy and carbohydrate metabolisms (cytochrome-c oxidase, L-lactate dehydrogenase, aldolase, and glycerol-1-phosphate dehydrogenase) have been studied in White Sea herring (the 1+, 2+, and 3+ age groups) sampled in Onega Bay, Dvina Bay, and Kandalaksha Bay of the White Sea. The bays differ in the hydrological regime, ecological and feeding conditions. The individual variability of the enzyme activity was the largest in the herring of the age 1+. The flexibility of the intensity and vector of the basic metabolic reactions probably supports the energy homeostasis, preconditions the switching to the most effective way of using the resources, and regulates the synthesis of the structural and storage molecules, as well as vectors the adaptation strategy of herring specimens of each age group to the hydrological regime, environment, and feeding conditions of the particular bay, corresponding to their age-related characteristics. PMID:27595825

  6. Technical note: Methionine, a precursor of methane in living plants

    OpenAIRE

    Lenhart, K.; F. Althoff; Greule, M.; F. Keppler

    2014-01-01

    When terrestrial plants were identified as producers of the greenhouse gas methane, much discussion and debate ensued, not only about their contribution to the global methane budget, but also with regard to the validity of the observation itself. Although the phenomenon has now become more accepted for both living and dead plants, the mechanism of methane formation in living plants remains to be elucidated and its precursor compounds identified. We made use of stable isoto...

  7. Variability of methane fluxes over high latitude permafrost wetlands

    OpenAIRE

    Andrei Serafimovich; Hartmann, J.; Eric Larmanou; Torsten Sachs

    2013-01-01

    Atmospheric methane plays an important role in the global climate system. Due to significant amounts of organic material stored in the upper layers of high latitude permafrost wetlands and a strong Arctic warming trend, there is concern about potentially large methane emissions from Arctic and sub-Arctic areas. The quantification of methane fluxes and their variability from these regions therefore plays an important role in understanding the Arctic carbon cycle and changes in atmo...

  8. Upscaling methane emissions from rice paddies: problems and possibilities

    OpenAIRE

    Bodegom, van, P.M.; P. H. Verburg; Denier Van Der Gon, H.A.C.

    2002-01-01

    Global methane emission estimates depend highly on the models, techniques, and databases used. Since emissions cannot be measured directly at large scales, it is impossible to judge which estimate is more realistic. In this paper, different aspects of uncertainty in upscaling methane emissions from rice paddies are discussed. These aspects are visualized by a case study on the spatial upscaling of methane emissions from the island of Java, Indonesia. The first aspect concerns process informat...

  9. Technical Note: Methionine, a precursor of methane in living plants

    OpenAIRE

    Lenhart, K.; F. Althoff; Greule, M.; F. Keppler

    2015-01-01

    When terrestrial plants were identified as producers of the greenhouse gas methane, much discussion and debate ensued not only about their contribution to the global methane budget but also with regard to the validity of the observation itself. Although the phenomenon has now become more accepted for both living and dead plants, the mechanism of methane formation in living plants remains to be elucidated and its precursor compounds to be identified. We made use of stable iso...

  10. Isolation and characterization of organisms growing with methane only

    International Nuclear Information System (INIS)

    More than 20 obligate methane utilizing bacteria were isolated from local soil following shake flask enrichment and continuous subculture technique isolation of methanotrophs proved to the difficult and slow. All isolates were gram negative, strictly aerobic, use methane as their sole carbon and energy source, unable to grow on nutrient media and can use nitrate as N source. Some isolates were motile. Few were able to utilize methanol. All the tested soil samples contained methane utilizing organisms. (author)

  11. INFLUENCE OF PLANT COMPOSITION ON METHANE EMISION FROM MOSZNE PEATLAND

    OpenAIRE

    Weronika Goraj; Agnieszka Kuźniar; Danuta Urban; Karolina Pietrzykowska; Zofia Stępniewska

    2013-01-01

    Methane is the second most important man-made greenhouse gas after carbon dioxide. For more than the last 20 years the increase of the rate of CH4 emission has been varying dramatically each year. This trend is common worldwide, though in different parts of the world unevenly intense, conditioned by the amount of emissions from natural and anthropogenic sources. Peatland ecosystems are one of the natural methane emitters, responsible for about 24% of the total CH4 emissions. Methane emission ...

  12. Effects of Environmental Conditions on an Urban Wetland's Methane Fluxes

    Science.gov (United States)

    Naor Azrieli, L.; Morin, T. H.; Bohrer, G.; Schafer, K. V.; Brooker, M.; Mitsch, W. J.

    2013-12-01

    Methane emissions from wetlands are the largest natural source of uncertainty in the global methane (CH4) budget. Wetlands are highly productive ecosystems with a large carbon sequestration potential. While wetlands are a net sink for carbon dioxide, they also release methane, a potent greenhouse gas. To effectively develop wetland management techniques, it is important to properly calculate the carbon budget of wetlands by understand the driving factors of methane fluxes. We constructed an eddy flux covariance system in the Olentangy River Wetland Research Park, a series of created and restored wetland in Columbus Ohio. Through the use of high frequency open path infrared gas analyzer (IRGA) sensors, we have continuously monitored the methane fluxes associated with the wetland since May 2011. To account for the heterogeneous landscape surrounding the tower, a footprint analysis was used to isolate data originating from within the wetland. Continuous measurements of the meteorological and environmental conditions at the wetlands coinciding with the flux measurements allow the interactions between methane fluxes and the climate and ecological forcing to be studied. The wintertime daily cycle of methane peaks around midday indicating a typical diurnal pattern in cold months. In the summer, the peak shifts to earlier in the day and also includes a daily peak occurring at approximately 10 AM. We believe this peak is associated with the onset of photosynthesis in Typha latifolia flushing methane from the plant's air filled tissue. Correlations with methane fluxes include latent heat flux, soil temperature, and incoming radiation. The connection to radiation may be further evidence of plant activity as a driver of methane fluxes. Higher methane fluxes corresponding with higher soil temperature indicates that warmer days stimulate the methanogenic consortium. Further analysis will focus on separating the methane fluxes into emissions from different terrain types within

  13. Anthropogenic emissions of methane in the United States

    OpenAIRE

    Miller, Scot M.; WOFSY Steven C.; Michalak, Anna M; Kort, Eric A.; Andrews, Arlyn E.; Biraud, Sebastien C.; Dlugokencky, Edward J.; Eluszkiewicz, Janusz; Fischer, Marc L.; Janssens-Maenhout, Greet; Miller, Ben R.; Miller, John B.; Montzka, Stephen A.; Nehrkorn, Thomas; Sweeney, Colm

    2013-01-01

    Successful regulation of greenhouse gas emissions requires knowledge of current methane emission sources. Existing state regulations in California and Massachusetts require ∼15% greenhouse gas emissions reductions from current levels by 2020. However, government estimates for total US methane emissions may be biased by 50%, and estimates of individual source sectors are even more uncertain. This study uses atmospheric methane observations to reduce this level of uncertainty. We find greenhous...

  14. Methane production through anaerobic digestion of dedicated energy crops

    OpenAIRE

    Di Girolamo, Giuseppe

    2014-01-01

    Methane yield of ligno-cellulosic substrates (i.e. dedicated energy crops and agricultural residues) may be limited by their composition and structural features. Hence, biomass pre-treatments are envisaged to overcome this constraint. This thesis aimed at: i) assessing biomass and methane yield of dedicated energy crops; ii) evaluating the effects of hydrothermal pre-treatments on methane yield of Arundo; iii) investigating the effects of NaOH pre-treatments and iv) acid pre-treatments on che...

  15. Methane-to-acetic acid synthesis matriculates at Penn State

    Energy Technology Data Exchange (ETDEWEB)

    Rotman, D.

    1994-04-20

    Direct conversion of methane to commercially valuable chemicals remains one of the grails of industrial chemistry. But scientists at Pennsylvania State University (University Park) appear to have made a significant step forward, reporting the direct catalytic conversion of methane into acetic acid under relatively mild conditions. Commercial acetic production involves a three-step process, including steam reforming of methane to synthesis gas (syngas) and the carbonylation of methanol of acetic acid.

  16. Kinetic Study of Nonequilibrium Plasma-Assisted Methane Steam Reforming

    OpenAIRE

    Hongtao Zheng; Qian Liu

    2014-01-01

    To develop a detailed reaction mechanism for plasma-assisted methane steam reforming, a comprehensive numerical and experimental study of effect laws on methane conversion and products yield is performed at different steam to methane molar ratio (S/C), residence time s, and reaction temperatures. A CHEMKIN-PRO software with sensitivity analysis module and path flux analysis module was used for simulations. A set of comparisons show that the developed reaction mechanism can accurately predict ...

  17. Methane dehydroaromatisation and methanol activation over zeolite catalysts: an overview

    OpenAIRE

    J.S.J. Hargreaves

    2016-01-01

    A brief overview of methane dehydroaromatisation over MoO3/H-ZSM-5 derived catalysts, the deposition of carbonaceous residues from methanol over H-mordenite and the role of binders in zeolite catalysed reactions is presented. The selective poisoning of methane cracking catalysts is proposed as a potential strategy for the development of methane dehydroaromatisation catalysts. In the case of methanol conversion over H-mordenite, evidence is presented for the formation of larger alkylated aroma...

  18. Reducing Methane Emissions from Cattle Production in Central Queensland

    OpenAIRE

    Rolfe, John

    2002-01-01

    Beef cattle contribute about 7% of national greenhouse gas emissions through the release of methane into the atmosphere. Cattle in northern Australia produce more methane per unit of beef produced because of tropical (C4) grasses and slower average growth rates. In this paper the level of emissions from different herds and some strategies to reduce emissions are modelled. The results indicate that few options exist to reduce methane emissions without reducing beef production. The opportunity ...

  19. Oxidation of methane by a biological dicopper center

    OpenAIRE

    Balasubramanian, Ramakrishnan; Smith, Stephen M.; Rawat, Swati; Yatsunyk, Liliya A.; Stemmler, Timothy L.; Rosenzweig, Amy C.

    2010-01-01

    Vast world reserves of methane gas are underutilized as a feedstock for production of liquid fuels and chemicals due to the lack of economical and sustainable strategies for selective oxidation to methanol1. Current processes to activate the strong C–H bond (104 kcal/mol) in methane require high temperatures, are costly and inefficient, and produce waste2. In nature, methanotrophic bacteria perform this reaction under ambient conditions using metalloenzymes called methane monooxygenases (MMOs...

  20. Selective methane oxidation on zeolite stabilized copper oxide clusters

    OpenAIRE

    Grundner, Sebastian

    2016-01-01

    Copper oxide clusters stabilized in the micropores of zeolites have been found to selectively oxidize methane to methanol. The synthesis of a catalyst with homotopic trinuclear copper oxide clusters was achieved via ion exchange and oxidation. The steric and chemical environments of these clusters characterized by combinations of physicochemical measurement were critical to activate and convert methane. While the absence of water was critical for methane oxidation, the presence of water was r...