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Sample records for based fuels nha

  1. Service station requirements for safe use of hydrogen based fuels: NHA work group update

    Energy Technology Data Exchange (ETDEWEB)

    Coutts, D.A. [Westinghouse Savannah River Co., Aiken, SC (United States)

    1997-12-31

    This paper consists of viewgraphs which summarize the results of the meeting of the working group on safety standards. A standard for an odorant for hydrogen leak detection is set forth. Recent activities with the National Fire Protection Association and the International Standard Organization are enumerated. The path forward is also summarized.

  2. Proceedings of NHA Annual Conferences

    Energy Technology Data Exchange (ETDEWEB)

    Debbi L. Smith

    2004-06-30

    The Proceedings of "Hydrogen: A Clean Energy Choice" and the 16th Annual U.S. Hydrogen Conference, "Partnering for the Global Hydrogen Future" include the presentations of high-level keynote speakers from the U.S. Department of Energy, the state government of California, Ambassadors and Executives of large corporations and emerging companies all presenting their vision on a future fueled by hydrogen. Parallel technical sessions informed attendees of developments in hydrogen technology R&D, commercial product development and market readiness. Persentations of the Student Design Competition Finalists are also included.

  3. Effect of overexpressing nhaA and nhaR on sodium tolerance and lactate production in Escherichia coli

    OpenAIRE

    Wu, Xianghao; Altman, Ronni; Eiteman, Mark A; Altman, Elliot

    2013-01-01

    Background Like other bacteria, Escherichia coli must carefully regulate the intracellular concentration of sodium ion (Na+). During the bacterial production of any organic acid, cations like Na+ invariably accumulate during a process which must maintain a near neutral pH. In this study, the E. coli nhaA gene encoding the Na+/H+ antiporter membrane protein and the nhaR gene encoding the NhaA regulatory protein were overexpressed in wild-type E. coli MG1655 and in MG1655 pflB (ALS1317) which l...

  4. Explaining tourists satisfaction and intention to revisit Nha Trang, Viet Nam

    OpenAIRE

    Tran, Thi Ai Cam

    2011-01-01

    The first purpose of the thesis is to find how visitors evaluate the quality of different facets or attributes of a destination image of Nha Trang, how satisfied they are with Nha Trang, loyalty intention to revisit and willingness to recommend Nha Trang to others. The second is to investigate what “image” is most important to explain global satisfaction with visiting Nha Trang. The third is to investigate how perceived quality, satisfaction and other motivational or dismotivational factors ...

  5. Carbon-based Fuel Cell

    Energy Technology Data Exchange (ETDEWEB)

    Steven S. C. Chuang

    2005-08-31

    The direct use of coal in the solid oxide fuel cell to generate electricity is an innovative concept for power generation. The C-fuel cell (carbon-based fuel cell) could offer significant advantages: (1) minimization of NOx emissions due to its operating temperature range of 700-1000 C, (2) high overall efficiency because of the direct conversion of coal to CO{sub 2}, and (3) the production of a nearly pure CO{sub 2} exhaust stream for the direct CO{sub 2} sequestration. The objective of this project is to determine the technical feasibility of using a highly active anode catalyst in a solid oxide fuel for the direct electrochemical oxidation of coal to produce electricity. Results of this study showed that the electric power generation from Ohio No 5 coal (Lower Kittanning) Seam, Mahoning County, is higher than those of coal gas and pure methane on a solid oxide fuel cell assembly with a promoted metal anode catalyst at 950 C. Further study is needed to test the long term activity, selectivity, and stability of anode catalysts.

  6. Loss of Sodium/Hydrogen Exchanger NHA2 Exacerbates Obesity- and Aging-Induced Glucose Intolerance in Mice

    Science.gov (United States)

    Deisl, Christine; Anderegg, Manuel; Albano, Giuseppe; Lüscher, Benjamin P.; Cerny, David; Soria, Rodrigo; Bouillet, Elisa; Rimoldi, Stefano; Scherrer, Urs

    2016-01-01

    We previously demonstrated that the sodium/hydrogen exchanger NHA2, also known as NHEDC2 or SLC9B2, is critical for insulin secretion by β–cells. To gain more insights into the role of NHA2 on systemic glucose homeostasis, we studied the impact of loss of NHA2 during the physiological aging process and in the setting of diet-induced obesity. While glucose tolerance was normal at 2 months of age, NHA2 KO mice displayed a significant glucose intolerance at 5 and 12 months of age, respectively. An obesogenic high fat diet further exacerbated the glucose intolerance of NHA2 KO mice. Insulin levels remained similar in NHA2 KO and WT mice during aging and high fat diet, but fasting insulin/glucose ratios were significantly lower in NHA2 KO mice. Peripheral insulin sensitivity, measured by insulin tolerance tests and hyperinsulinemic euglycemic clamps, was unaffected by loss of NHA2 during aging and high fat diet. High fat diet diminished insulin secretion capacity in both WT and NHA2 KO islets and reduced expression of NHA2 in WT islets. In contrast, aging was characterized by a gradual increase of NHA2 expression in islets, paralleled by an increasing difference in insulin secretion between WT and NHA2 KO islets. In summary, our results demonstrate that loss of the sodium/hydrogen exchanger NHA2 exacerbates obesity- and aging-induced glucose intolerance in mice. Furthermore, our data reveal a close link between NHA2 expression and insulin secretion capacity in islets. PMID:27685945

  7. EFFECTS OF LEACHING MEDIUM ON LEACHABILITY OF WOOD PRESERVING N'N-HYDROXYNAPTHALIMIDE (NHA

    Directory of Open Access Journals (Sweden)

    Evren Terzi,

    2012-02-01

    Full Text Available Laboratory leaching test procedures usually call for the use of distilled or deionized water; however, treated wood is generally exposed to different types of water, soil, and weather conditions. Thus, factors such as salinity, hardness, pH, temperature etc. might be important in the release of different amounts of biocide compounds. This study evaluates the release of the sodium salt of the calcium precipitating and wood preserving agent N’N-hydroxynapthalimide (NHA from treated wood specimens exposed to different types of leaching media. Scots pine wood specimens were treated with NHA at three different solution strengths. Treated specimens were then leached with distilled water, tap water, rain water, synthetic sea water, natural sparkling water, or 1% CaCO3 solutions for 2 weeks. Leaching with higher ion concentrations reduced NHA losses from the specimens in comparison with that of distilled water and rain water leaching trials. Microscopic evaluations were in good accordance with the results from leaching trials, revealing NHA precipitation onto the tori of pit elements and tracheids. In distilled water and rain water leaching trials, less NHA precipitation on to the tori of pit membranes and tracheid surfaces was observed, whilst the specimens leached with tap water, 1% CaCO3, sea water, and sparkling water showed higher NHA precipitations on the cell elements. We conclude that the leaching of NHA from treated wood can be decreased by precipitation with ions coming from tap water, sea water, sparkling water, and 1% CaCO3 solutions as leaching media rather than distilled water or rain water with no or much less ion composition.

  8. Molecular characterization of the Na+/H+-antiporter NhaA from Salmonella Typhimurium.

    Directory of Open Access Journals (Sweden)

    Christopher J Lentes

    Full Text Available Na+/H+ antiporters are integral membrane proteins that are present in almost every cell and in every kingdom of life. They are essential for the regulation of intracellular pH-value, Na+-concentration and cell volume. These secondary active transporters exchange sodium ions against protons via an alternating access mechanism, which is not understood in full detail. Na+/H+ antiporters show distinct species-specific transport characteristics and regulatory properties that correlate with respective physiological functions. Here we present the characterization of the Na+/H+ antiporter NhaA from Salmonella enterica serovar Thyphimurium LT2, the causing agent of food-born human gastroenteritis and typhoid like infections. The recombinant antiporter was functional in vivo and in vitro. Expression of its gene complemented the Na+-sensitive phenotype of an E. coli strain that lacks the main Na+/H+ antiporters. Purified to homogeneity, the antiporter was a dimer in solution as accurately determined by size-exclusion chromatography combined with multi-angle laser-light scattering and refractive index monitoring. The purified antiporter was fully capable of electrogenic Na+(Li+/H+-antiport when reconstituted in proteoliposomes and assayed by solid-supported membrane-based electrophysiological measurements. Transport activity was inhibited by 2-aminoperimidine. The recorded negative currents were in agreement with a 1Na+(Li+/2H+ stoichiometry. Transport activity was low at pH 7 and up-regulation above this pH value was accompanied by a nearly 10-fold decrease of KmNa (16 mM at pH 8.5 supporting a competitive substrate binding mechanism. K+ does not affect Na+ affinity or transport of substrate cations, indicating that selectivity of the antiport arises from the substrate binding step. In contrast to homologous E. coli NhaA, transport activity remains high at pH values above 8.5. The antiporter from S. Typhimurium is a promising candidate for combined

  9. NhaD type sodium/proton-antiporter of Halomonas elongata: a salt stress response mechanism in marine habitats?

    OpenAIRE

    Kurz, Matthias; Brünig, Anika NS; Galinski, Erwin A.

    2006-01-01

    Background Sodium/proton-antiporters (Nha) are known to play an important role in pH- and Na+-homeostasis. In microorganisms several types with different capacity, affinity and selectivity for Na+ and Li+ exist. The homeostasis system of E. coli, NhaA and NhaB, is well researched, but the function of other types of Na+/H+-antiporters like NhaD is yet to be fully understood. Since several antiporters play an important role at various points in the physiology of higher organisms, one can specul...

  10. Characterization and supply of coal based fuels

    Energy Technology Data Exchange (ETDEWEB)

    1992-06-01

    Studies and data applicable for fuel markets and coal resource assessments were reviewed and evaluated to provide both guidelines and specifications for premium quality coal-based fuels. The fuels supplied under this contract were provided for testing of advanced combustors being developed under Pittsburgh Energy Technology Center (PETC) sponsorship for use in the residential, commercial and light industrial (RCLI) market sectors. The requirements of the combustor development contractors were surveyed and periodically updated to satisfy the evolving needs based on design and test experience. Available coals were screened and candidate coals were selected for further detailed characterization and preparation for delivery. A team of participants was assembled to provide fuels in both coal-water fuel (CWF) and dry ultrafine coal (DUC) forms. Information about major US coal fields was correlated with market needs analysis. Coal fields with major reserves of low sulfur coal that could be potentially amenable to premium coal-based fuels specifications were identified. The fuels requirements were focused in terms of market, equipment and resource constraints. With this basis, the coals selected for developmental testing satisfy the most stringent fuel requirements and utilize available current deep-cleaning capabilities.

  11. Review of alternative fuels data bases

    Science.gov (United States)

    Harsha, P. T.; Edelman, R. B.

    1983-01-01

    Based on an analysis of the interaction of fuel physical and chemical properties with combustion characteristics and indicators, a ranking of the importance of various fuel properties with respect to the combustion process was established. This ranking was used to define a suite of specific experiments whose objective is the development of an alternative fuels design data base. Combustion characteristics and indicators examined include droplet and spray formation, droplet vaporization and burning, ignition and flame stabilization, flame temperature, laminar flame speed, combustion completion, soot emissions, NOx and SOx emissions, and the fuels' thermal and oxidative stability and fouling and corrosion characteristics. Key fuel property data is found to include composition, thermochemical data, chemical kinetic rate information, and certain physical properties.

  12. Solid polymer MEMS-based fuel cells

    Science.gov (United States)

    Jankowski, Alan F.; Morse, Jeffrey D.

    2008-04-22

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  13. Solid oxide MEMS-based fuel cells

    Science.gov (United States)

    Jankowksi, Alan F.; Morse, Jeffrey D.

    2007-03-13

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  14. NhaD type sodium/proton-antiporter of Halomonas elongata: a salt stress response mechanism in marine habitats?

    Science.gov (United States)

    Kurz, Matthias; Brünig, Anika NS; Galinski, Erwin A

    2006-01-01

    Background Sodium/proton-antiporters (Nha) are known to play an important role in pH- and Na+-homeostasis. In microorganisms several types with different capacity, affinity and selectivity for Na+ and Li+ exist. The homeostasis system of E. coli, NhaA and NhaB, is well researched, but the function of other types of Na+/H+-antiporters like NhaD is yet to be fully understood. Since several antiporters play an important role at various points in the physiology of higher organisms, one can speculate that the main functions of some of those procaryotic antiporters differ from pH- and Na+-homeostasis. Results This study investigates the function and regulation of a gene encoding for a NhaD type antiporter which was discovered in the halophilic eubacterium Halomonas elongata. The deduced primary amino acid sequence of the abovementioned gene showed more than 60% identity to known antiporters of the NhaD type from Alkalimonas amylolytica, Shewanella oneidensis and several other marine organisms of the γ-Proteobacteria. Evidence was found for a dual regulation of H. elongata NhaD expression. The gene was cloned and expressed in E. coli. Antiporter deficient NaCl and LiCl sensitive E. coli mutants EP432 and KNabc were partially complemented by a plasmid carrying the H. elongata nhaD gene. Surprisingly the LiCl sensitivity of E. coli strain DH5α having a complete homeostasis system was increased when NhaD was co-expressed. Conclusion Since NhaD is an antiporter known so far only from halophilic or haloalcaliphilic Proteobacteria one can speculate that this type of antiporter provides a special mechanism for adaptation to marine habitats. As was already speculated – though without supporting data – and substantiated in this study this might be active Na+-import for osmoregulatory purposes. PMID:16872527

  15. 40 CFR 79.55 - Base fuel specifications.

    Science.gov (United States)

    2010-07-01

    ... Base Fuels. (1) The methanol base fuels shall contain no elements other than carbon, hydrogen, oxygen... ethanol base fuel, E85, shall contain no elements other than carbon, hydrogen, oxygen, nitrogen, sulfur... no elements other than carbon, hydrogen, oxygen, nitrogen, and sulfur. The fuel shall contain...

  16. Novel Fuel Cells for Coal Based Systems

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Tao

    2011-12-31

    The goal of this project was to acquire experimental data required to assess the feasibility of a Direct Coal power plant based upon an Electrochemical Looping (ECL) of Liquid Tin Anode Solid Oxide Fuel Cell (LTA-SOFC). The objective of Phase 1 was to experimentally characterize the interaction between the tin anode, coal fuel and cell component electrolyte, the fate of coal contaminants in a molten tin reactor (via chemistry) and their impact upon the YSZ electrolyte (via electrochemistry). The results of this work will provided the basis for further study in Phase 2. The objective of Phase 2 was to extend the study of coal impurities impact on fuel cell components other than electrolyte, more specifically to the anode current collector which is made of an electrically conducting ceramic jacket and broad based coal tin reduction. This work provided a basic proof-of-concept feasibility demonstration of the direct coal concept.

  17. MEMS-based fuel cells with integrated catalytic fuel processor and method thereof

    Science.gov (United States)

    Jankowski, Alan F.; Morse, Jeffrey D.; Upadhye, Ravindra S.; Havstad, Mark A.

    2011-08-09

    Described herein is a means to incorporate catalytic materials into the fuel flow field structures of MEMS-based fuel cells, which enable catalytic reforming of a hydrocarbon based fuel, such as methane, methanol, or butane. Methods of fabrication are also disclosed.

  18. Nitrogen-Based Fuels: A Power-to-Fuel-to-Power Analysis.

    Science.gov (United States)

    Grinberg Dana, Alon; Elishav, Oren; Bardow, André; Shter, Gennady E; Grader, Gideon S

    2016-07-25

    What are the fuels of the future? Seven representative carbon- and nitrogen-based fuels are evaluated on an energy basis in a power-to-fuel-to-power analysis as possible future chemical hydrogen-storage media. It is intriguing to consider that a nitrogen economy, where hydrogen obtained from water splitting is chemically stored on abundant nitrogen in the form of a nontoxic and safe nitrogen-based alternative fuel, is energetically feasible.

  19. Jet Fuel Based High Pressure Solid Oxide Fuel Cell System

    Science.gov (United States)

    Gummalla, Mallika (Inventor); Yamanis, Jean (Inventor); Olsommer, Benoit (Inventor); Dardas, Zissis (Inventor); Bayt, Robert (Inventor); Srinivasan, Hari (Inventor); Dasgupta, Arindam (Inventor); Hardin, Larry (Inventor)

    2015-01-01

    A power system for an aircraft includes a solid oxide fuel cell system which generates electric power for the aircraft and an exhaust stream; and a heat exchanger for transferring heat from the exhaust stream of the solid oxide fuel cell to a heat requiring system or component of the aircraft. The heat can be transferred to fuel for the primary engine of the aircraft. Further, the same fuel can be used to power both the primary engine and the SOFC. A heat exchanger is positioned to cool reformate before feeding to the fuel cell. SOFC exhaust is treated and used as inerting gas. Finally, oxidant to the SOFC can be obtained from the aircraft cabin, or exterior, or both.

  20. An in vitro evaluation of novel NHA/zircon plasma coating on 316L stainless steel dental implant

    Directory of Open Access Journals (Sweden)

    Ebrahim Karamian

    2014-04-01

    Full Text Available The surface characteristics of an implant that influence the speed and strength of osseointegration include crystal structure and bioactivity. The aim of this study was to evaluate the bioactivity of a novel natural hydroxyapatite/zircon (NHA/zircon nanobiocomposite coating on 316L stainless steel (SS dental implants soaking in simulated body fluid. A novel NHA/zircon nanobiocomposite was fabricated with 0 (control, 5, 10, and 15 wt% of zircon in NHA using ball mill for 1 h. The composite mixture was coated on SS implants using a plasma spray method. Scanning electron microscopy (SEM was used to evaluate surface morphology, and X-ray diffraction (XRD was used to analyze phase composition and crystallinity (Xc. Further, calcium ion release was measured to evaluate the coated nanobiocomposite samples. The prepared NHA/zircon coating had a nanoscale morphological structure with a mean crystallite size of 30–40 nm in diameter and a bone-like composition, which is similar to that of the biological apatite of a bone. For the prepared NHA powder, high bioactivity was observed owing to the formation of apatite crystals on its surface. Both minimum crystallinity (Xc=41.1% and maximum bioactivity occurred in the sample containing 10 wt% of zircon because of minimum Xc and maximum biodegradation of the coating sample.

  1. An in vitro evaluation of novel NHA/zircon plasma coating on 316L stainless steel dental implant

    Institute of Scientific and Technical Information of China (English)

    Ebrahim Karamian; Mahmood Reza Kalantar Motamedi; Amirsalar Khandan; Parisa Soltani; Sahel Maghsoudi

    2014-01-01

    The surface characteristics of an implant that influence the speed and strength of osseointegration include crystal structure and bioactivity. The aim of this study was to evaluate the bioactivity of a novel natural hydroxyapatite/zircon (NHA/zircon) nanobiocomposite coating on 316L stainless steel (SS) dental implants soaking in simulated body fluid. A novel NHA/zircon nanobiocomposite was fabricated with 0 (control), 5, 10, and 15 wt%of zircon in NHA using ball mill for 1 h. The composite mixture was coated on SS implants using a plasma spray method. Scanning electron microscopy (SEM) was used to evaluate surface morphology, and X-ray diffraction (XRD) was used to analyze phase composition and crystallinity (Xc). Further, calcium ion release was measured to evaluate the coated nanobiocomposite samples. The prepared NHA/zircon coating had a nanoscale morphological structure with a mean crystallite size of 30-40 nm in diameter and a bone-like composition, which is similar to that of the biological apatite of a bone. For the prepared NHA powder, high bioactivity was observed owing to the formation of apatite crystals on its surface. Both minimum crystallinity (Xc = 41.1%) and maximum bioactivity occurred in the sample containing 10 wt%of zircon because of minimum Xc and maximum biodegradation of the coating sample.

  2. Mechanism of pH-dependent activation of the sodium-proton antiporter NhaA

    Science.gov (United States)

    Huang, Yandong; Chen, Wei; Dotson, David L.; Beckstein, Oliver; Shen, Jana

    2016-10-01

    Escherichia coli NhaA is a prototype sodium-proton antiporter, which has been extensively characterized by X-ray crystallography, biochemical and biophysical experiments. However, the identities of proton carriers and details of pH-regulated mechanism remain controversial. Here we report constant pH molecular dynamics data, which reveal that NhaA activation involves a net charge switch of a pH sensor at the entrance of the cytoplasmic funnel and opening of a hydrophobic gate at the end of the funnel. The latter is triggered by charging of Asp164, the first proton carrier. The second proton carrier Lys300 forms a salt bridge with Asp163 in the inactive state, and releases a proton when a sodium ion binds Asp163. These data reconcile current models and illustrate the power of state-of-the-art molecular dynamics simulations in providing atomic details of proton-coupled transport across membrane which is challenging to elucidate by experimental techniques.

  3. Fuel supply and distribution. Fixed base operation

    Science.gov (United States)

    Burian, L. C.

    1983-01-01

    Aviation gasoline versus other products, a changing marketplace, the Airline Deregulation Act of 1978, aviation fuel credit card purchases, strategic locations, storage, co-mingling of fuel, and transportation to/from central storage are discussed.

  4. Flexible fuel engine based on multi-combustion control technologies

    Institute of Scientific and Technical Information of China (English)

    LI Xiaolu; HUANG Zhen; QIAO Xinqi; SONG Jun; FANG Junhua; XIA Huimin

    2005-01-01

    A combustion control strategy is proposed for diesel engine to reduce PM and NOx emissions significantly, which adopts some technologies including internal exhaust gas recirculation (EGR), split spray, adjustable fuel delivery advance angle and the application of alternative fuels. Based on this strategy, a flexible fuel engine has been developed. The experimental results show that this engine can be fueled with diesel fuel, alcohol, dimethyl carbonate (DMC), etc. It works with extremely low levels of particulate matter (PM) and NOx, 2~3% higher effective thermal efficiency on moderate and high loads when alternative fuels are used. This engine not only has lower exhaust emissions, but also can be fueled with those alternative fuels, which are difficult to be ignited by compression.

  5. Crop production without fossil fuel: production systems for tractor fuel and mineral nitrogen based on biomass

    Energy Technology Data Exchange (ETDEWEB)

    Ahlgren, Serina

    2009-12-15

    With diminishing fossil fuel reserves and concerns about global warming, the agricultural sector needs to reduce its use of fossil fuels. The objective of this thesis was to evaluate different systems for biomass-based production of tractor fuel and mineral nitrogen fertilisers, which at present are the two largest fossil energy carriers in Swedish agriculture. The land use, energy input and environmental load of the systems were calculated using life cycle assessment methodology. Two categories of renewable tractor fuel were studied: first generation fuels and second generation fuels, the latter defined as fuels not yet produced on a commercial scale. An organic farm self-sufficient in tractor fuel was modelled. Raw material from the farm was assumed to be delivered to a large fuel production facility and fuel transported back to the farm, where it was utilised. In general, the second generation renewable fuels had higher energy balance and lower environmental impact than the first generation fuels. However all systems studied reduced the use of fossil fuels to a great extent and lowered the contribution to global warming. The land needed to be set aside for tractor fuel varied between 2% and 5% of the farm's available land. Two major routes for biomass-based production of mineral nitrogen for conventional agriculture were studied, one based on anaerobic digestion and one on thermochemical gasification of biomass. The crops studied were able to produce between 1.6 and 3.9 tonnes N per hectare in the form of ammonium nitrate. The use of fossil fuel for ammonium nitrate production was 35 MJ per kg N in the fossil reference scenario, but only 1-4 MJ per kg N in the biomass systems. The contribution to global warming can be greatly reduced by the biomass systems, but there is an increased risk of eutrophication and acidification. It is clear that the agricultural sector has great potential to reduce the use of fossil fuel and to lower the emissions of greenhouse

  6. Additive effects of the herbicide glyphosate and elevated temperature on the branched coral Acropora formosa in Nha Trang, Vietnam

    NARCIS (Netherlands)

    Amid, C.; Olstedt, M.; Gunnarsson, J.S.; Lan, Le H.; Tran Thi Minh, H.; Brink, van den P.J.; Hellström, M.; Tedengren, M.

    2017-01-01

    The combined effects of the herbicide glyphosate and elevated temperature were studied on the tropical staghorn coral Acropora formosa, in Nha Trang bay, Vietnam. The corals were collected from two different reefs, one close to a polluted fish farm and one in a marine-protected area (MPA). In the

  7. Gender, Alcohol Consumption Patterns, and Engagement in Sexually Intimate Behaviors among Adolescents and Young Adults in Nha Trang, Viet Nam

    Science.gov (United States)

    Kaljee, Linda M.; Green, Mackenzie S.; Zhan, Min; Riel, Rosemary; Lerdboon, Porntip; Lostutter, Ty W.; Tho, Le Huu; Luong, Vo Van; Minh, Truong Tan

    2011-01-01

    A randomly selected cross-sectional survey was conducted with 880 youth (16 to 24 years) in Nha Trang City to assess relationships between alcohol consumption and sexual behaviors. A timeline followback method was employed. Chi-square, generalized logit modeling and logistic regression analyses were performed. Of the sample, 78.2% male and 56.1%…

  8. Evaluation of thorium based nuclear fuel. Extended summary

    Energy Technology Data Exchange (ETDEWEB)

    Franken, W.M.P.; Bultman, J.H.; Konings, R.J.M.; Wichers, V.A.

    1995-04-01

    Application of thorium based nuclear fuels has been evaluated with emphasis on possible reduction of the actinide waste. As a result three ECN-reports are published, discussing in detail: - The reactor physics aspects, by comparing the operation characteristics of the cores of Pressurized Water Reactors and Heavy Water Reactors with different fuel types, including equilibrium thorium/uranium free, once-through uranium fuel and equilibrium uranium/plutonium fuel, - the chemical aspects of thorium based fuel cycles with emphasis on fuel (re)fabrication and fuel reprocessing, - the possible reduction in actinide waste as analysed for Heavy Water Reactors with various types of thorium based fuels in once-through operation and with reprocessing. These results are summarized in this report together with a short discussion on non-proliferation and uranium resource utilization. It has been concluded that a substantial reduction of actinide radiotoxicity of the disposed waste may be achieved by using thorium based fuels, if very efficient partitioning and multiple recycling of uranium and thorium can be realized. This will, however, require large efforts to develop the technology to the necessary industrial scale of operation. (orig.).

  9. The promise of fuel cell-based automobiles

    Indian Academy of Sciences (India)

    A K Shukla; C L Jackson; K Scott

    2003-02-01

    Fuel cell-based automobiles have gained attention in the last few years due to growing public concern about urban air pollution and consequent environmental problems. From an analysis of the power and energy requirements of a modern car, it is estimated that a base sustainable power of $ca$. 50 kW supplemented with short bursts up to 80 kW will suffice in most driving requirements. The energy demand depends greatly on driving characteristics but under normal usage is expected to be 200 Wh/km. The advantages and disadvantages of candidate fuel-cell systems and various fuels are considered together with the issue of whether the fuel should be converted directly in the fuel cell or should be reformed to hydrogen onboard the vehicle. For fuel cell vehicles to compete successfully with conventional internal-combustion engine vehicles, it appears that direct conversion fuel cells using probably hydrogen, but possibly methanol, are the only realistic contenders for road transportation applications. Among the available fuel cell technologies, polymer–electrolyte fuel cells directly fueled with hydrogen appear to be the best option for powering fuel cell vehicles as there is every prospect that these will exceed the performance of the internal-combustion engine vehicles but for their first cost. A target cost of $ 50/kW would be mandatory to make polymer–electrolyte fuel cells competitive with the internal combustion engines and can only be achieved with design changes that would substantially reduce the quantity of materials used. At present, prominent car manufacturers are deploying important research and development efforts to develop fuel cell vehicles and are projecting to start production by 2005.

  10. The choice of the fuel assembly for VVER-1000 in a closed fuel cycle based on REMIX-technology

    Directory of Open Access Journals (Sweden)

    Bobrov Evgenii

    2016-01-01

    Full Text Available This paper shows basic features of different fuel assembly (FA application for VVER-1000 in a closed fuel cycle based on REMIX-technology. This investigation shows how the change in the water–fuel ratio in the VVER FA affects on the fuel characteristics produced by REMIX technology during multiple recycling.

  11. Spent fuel data base: commercial light water reactors. [PWR; BWR

    Energy Technology Data Exchange (ETDEWEB)

    Hauf, M.J.; Kniazewycz, B.G.

    1979-12-01

    As a consequence of this country's non-proliferation policy, the reprocessing of spent nuclear fuel has been delayed indefinitely. This has resulted in spent light water reactor (LWR) fuel being considered as a potential waste form for disposal. Since the Nuclear Regulatory Commission (NRC) is currently developing methodologies for use in the regulation of the management and disposal of high-level and transuranic wastes, a comprehensive data base describing LWR fuel technology must be compiled. This document provides that technology baseline and, as such, will support the development of those evaluation standards and criteria applicable to spent nuclear fuel.

  12. Vegetable oil-based diesel fuels: Overview and current trends

    Science.gov (United States)

    Since the energy crises of the 1970's and early 1980's, feedstocks and fuels with the potential to reduce dependence on petroleum-based energy and fuels have found increasing interest. Materials with triacylglycerols (triglycerides; esters of glycerol with fatty acids) as major components, such as ...

  13. Fuel type characterization based on coarse resolution MODIS satellite data

    Directory of Open Access Journals (Sweden)

    Lanorte A

    2007-01-01

    Full Text Available Fuel types is one of the most important factors that should be taken into consideration for computing spatial fire hazard and risk and simulating fire growth and intensity across a landscape. In the present study, forest fuel mapping is considered from a remote sensing perspective. The purpose is to delineate forest types by exploring the use of coarse resolution satellite remote sensing MODIS imagery. In order to ascertain how well MODIS data can provide an exhaustive classification of fuel properties a sample area characterized by mixed vegetation covers and complex topography was analysed. The study area is located in the South of Italy. Fieldwork fuel type recognitions, performed before, after and during the acquisition of remote sensing MODIS data, were used as ground-truth dataset to assess the obtained results. The method comprised the following three steps: (I adaptation of Prometheus fuel types for obtaining a standardization system useful for remotely sensed classification of fuel types and properties in the considered Mediterranean ecosystems; (II model construction for the spectral characterization and mapping of fuel types based on two different approach, maximum likelihood (ML classification algorithm and spectral Mixture Analysis (MTMF; (III accuracy assessment for the performance evaluation based on the comparison of MODIS-based results with ground-truth. Results from our analyses showed that the use of remotely sensed MODIS data provided a valuable characterization and mapping of fuel types being that the achieved classification accuracy was higher than 73% for ML classifier and higher than 83% for MTMF.

  14. Silicon Based Direct Methanol Fuel Cells

    DEFF Research Database (Denmark)

    Larsen, Jackie Vincent

    The purpose of this project has been to investigate and fabricate small scale Micro Direct Methanol Fuel Cells (μDMFC). They are investigated as a possible alternative for Zinc-air batteries in small size consumer devices such as hearing aids. In such devices the conventional rechargeable batteries...... such as lithium-ion batteries have insufficiently low energy density. Methanol is a promising fuel for such devices due to the high energy density and ease of refueling compared to charging batteries, making μDMFC a suitable replacement energy source. In this Ph.D. dissertation, silicon micro fabrication...

  15. Tungsten based electrocatalyst for fuel cell applications

    Energy Technology Data Exchange (ETDEWEB)

    Christian, Joel B. [OSRAM SYLVANIA Inc., Global Tungsten and Powders R and D, Hawes Street, Towanda, PA 18848 (United States); Materials Science and Engineering, SUNY Binghamton, Binghamton, NY 13902 (United States); Smith, Sean P.E. [OSRAM SYLVANIA Inc., Global Tungsten and Powders R and D, Hawes Street, Towanda, PA 18848 (United States); Whittingham, M. Stanley [Materials Science and Engineering, SUNY Binghamton, Binghamton, NY 13902 (United States); Abruna, Hector D. [Cornell University, Department of Chemistry and Chemical Biology, Ithaca, NY 14653 (United States)

    2007-08-15

    A barrier to the widespread use of fuel cells is their reliance on expensive and scarce platinum and other precious metal catalysts. We present a catalyst for hydrogen oxidation, prepared electrochemically from high-purity aqueous tungstate salt precursors. The 24-electron reduction of ammonium metatungstate ((NH{sub 4}){sub 6}[H{sub 2}W{sub 12}O{sub 40}]) yields a material with electrocatalytic activity towards the oxidation of hydrogen in acid electrolyte which approaches 25% that of platinum. Moreover, the tungstate catalyst is unusually tolerant to CO and H{sub 2}S contaminants in the fuel stream. (author)

  16. Thorium-based fuel cycles: Reassessment of fuel economics and proliferation risk

    Energy Technology Data Exchange (ETDEWEB)

    Serfontein, Dawid E., E-mail: Dawid.Serfontein@nwu.ac.za [Senior Lecturer at the School of Mechanical and Nuclear Engineering, North West University (PUK-Campus), PRIVATE BAG X6001, Internal Post Box 360, Potchefstroom 2520 (South Africa); Mulder, Eben J. [Professor at the School of Mechanical and Nuclear Engineering, North West University (South Africa)

    2014-05-01

    At current consumption and current prices, the proven reserves for natural uranium will last only about 100 years. However, the more abundant thorium, burned in breeder reactors, such as large High Temperature Gas-Cooled Reactors, and followed by chemical reprocessing of the spent fuel, could stretch the 100 years for uranium supply to 15,000 years. Thorium-based fuel cycles are also viewed as more proliferation resistant compared to uranium. However, several barriers to entry caused all countries, except India and Russia, to abandon their short term plans for thorium reactor projects, in favour of uranium/plutonium fuel cycles. In this article, based on the theory of resonance integrals and original analysis of fast fission cross sections, the breeding potential of {sup 232}Th is compared to that of {sup 238}U. From a review of the literature, the fuel economy of thorium-based fuel cycles is compared to that of natural uranium-based cycles. This is combined with a technical assessment of the proliferation resistance of thorium-based fuel cycles, based on a review of the literature. Natural uranium is currently so cheap that it contributes only about 10% of the cost of nuclear electricity. Chemical reprocessing is also very expensive. Therefore conservation of natural uranium by means of the introduction of thorium into the fuel is not yet cost effective and will only break even once the price of natural uranium were to increase from the current level of about $70/pound yellow cake to above about $200/pound. However, since fuel costs constitutes only a small fraction of the total cost of nuclear electricity, employing reprocessing in a thorium cycle, for the sake of its strategic benefits, may still be a financially viable option. The most important source of the proliferation resistance of {sup 232}Th/{sup 233}U fuel cycles is denaturisation of the {sup 233}U in the spent fuel by {sup 232}U, for which the highly radioactive decay chain potentially poses a large

  17. Engine control system having fuel-based adjustment

    Science.gov (United States)

    Willi, Martin L.; Fiveland, Scott B.; Montgomery, David T.; Gong, Weidong

    2011-03-15

    A control system for an engine having a cylinder is disclosed having an engine valve configured to affect a fluid flow of the cylinder, an actuator configured to move the engine valve, and an in-cylinder sensor configured to generate a signal indicative of a characteristic of fuel entering the cylinder. The control system also has a controller in communication with the actuator and the sensor. The controller is configured to determine the characteristic of the fuel based on the signal and selectively regulate the actuator to adjust a timing of the engine valve based on the characteristic of the fuel.

  18. Monolithic fuel cell based power source for burst power generation

    Science.gov (United States)

    Fee, D. C.; Blackburn, P. E.; Busch, D. E.; Dees, D. W.; Dusek, J.; Easler, T. E.; Ellingson, W. A.; Flandermeyer, B. K.; Fousek, R. J.; Heiberger, J. J.

    A unique fuel cell coupled with a low power nuclear reactor presents an attractive approach for SDI burst power requirements. The monolithic fuel cell looks attractive for space applications and represents a quantum jump in fuel cell technology. Such a breakthrough in design is the enabling technology for lightweight, low volume power sources for space based pulse power systems. The monolith is unique among fuel cells in being an all solid state device. The capability for miniaturization, inherent in solid state devices, gives the low volume required for space missions. In addition, the solid oxide fuel cell technology employed in the monolith has high temperature reject heat and can be operated in either closed or open cycles. Both these features are attractive for integration into a burst power system.

  19. Pathway to fuel additives or designer fuels from bio-based alcohols

    Energy Technology Data Exchange (ETDEWEB)

    Breitkreuz, Klaas; Menne, Andreas [Fraunhofer-Institut fuer Umwelt-, Sicherheits- und Energietechnik UMSICHT, Oberhausen (Germany); Kraft, Axel

    2013-06-01

    A continuous heterogeneous-catalytic gas-phase process developed by Fraunhofer UMSICHT makes it possible to condense small alcohols and ketones to larger hydrocarbon molecules containing only one atom of oxygen per molecule. After an optional oxygen-removing step such as hydrotreatment, fuel-identical hydrocarbons are yielded. The overall conversion of feedstock to fuel additives or fuels is depicted below: Alcohol - Conversion to higher alcohols - Condensation with acetone - Hydrotreatment (Schematic process flow for the production of fuel-identical hydrocarbons and additives). Depending on raw materials and process conditions, a tailor-made product distribution is possible. The products can be used as fuel additives or as drop-in fuel, matching either diesel or kerosene specifications. The intermediates - secondary alcohols - are valuable as raw materials for several chemical applications, i.e. plasticizer, surfactants, solvents or lubricants. This process offers an attractive alternative to other competing processes producing long-chain hydrocarbons, like Fischer-Tropsch or hydrotreatment of fats and oils. Being based on economical, stable and commercially available catalysts as well as on a wide range of possible raw materials, this method 1s ready for scale up and related process development. (orig.)

  20. Investigation of Non-Petroleum Based Fuels

    Science.gov (United States)

    2005-09-01

    in-house HCCI engine and fuels program, and to develop a test plan for the 1.9-liter camless engine . Parties involved were Sturman Industries, VW...that Volkswagen’s previous HCCI research on the same engine would be used as a starting point for this work. Lawrence Livermore National Laboratory...was contacted about the capabilities of existing HCCI ignition and combustion models, for use in guiding the engine development work. 4 3.1

  1. Installation of Ohio's First Electrolysis-Based Hydrogen Fueling Station

    Science.gov (United States)

    Scheidegger, Brianne T.; Lively, Michael L.

    2012-01-01

    This paper describes progress made towards the installation of a hydrogen fueling station in Northeast Ohio. In collaboration with several entities in the Northeast Ohio area, the NASA Glenn Research Center is installing a hydrogen fueling station that uses electrolysis to generate hydrogen on-site. The installation of this station is scheduled for the spring of 2012 at the Greater Cleveland Regional Transit Authority s Hayden bus garage in East Cleveland. This will be the first electrolysis-based hydrogen fueling station in Ohio.

  2. Ectopic Expression of a Bacterium NhaD-type Na+/H+Antiporter Leads to Increased Tolerance to Combined Salt/Alkali Stresses

    Institute of Scientific and Technical Information of China (English)

    Nai-Qin Zhong; Li-Bo Han; Xiao-Min Wu; Li-Li Wang; Fang Wang; Yan-He Ma; Gui-Xian Xia

    2012-01-01

    AaNhaD,a gene isolated from the soda lake alkaliphile Alkalimonas amylolytica,encodes a Na+/H+antiporter crucial for the bacterium's resistance to salt/alkali stresses.However,it remains unknown whether this type of bacterial gene may be able to increase the tolerance of flowering plants to salt/alkali stresses.To investigate the use of extremophile genetic resources in higher plants,transgenic tobacco BY-2 cells and plants harboring AaNhaD were generated and their stress tolerance was evaluated.Ectopic expression of AaNhaD enhanced the salt tolerance of the transgenic BY-2 cells in a pH-dependent manner.Compared to wild-type controls,the transgenic cells exhibited increased Na+ concentrations and pH levels in the vacuoles.Subcellular localization analysis indicated that AaNhaD-GFP fusion proteins were primarily localized in the tonoplasts.Similar to the transgenic BY-2 cells,AaNhaD-overexpressing tobacco plants displayed enhanced stress tolerance when grown in saline-alkali soil.These results indicate that AaNhaD functions as a pH-dependent tonoplast Na+/H+ antiporter in plant cells,thus presenting a new avenue for the genetic improvement of salinity/alkalinity tolerance.

  3. Combustion characterization of beneficiated coal-based fuels

    Energy Technology Data Exchange (ETDEWEB)

    Chow, O.K.; Levasseur, A.A.

    1995-11-01

    The Pittsburgh Energy Technology Center (PETC) of the U.S. Department of Energy is sponsoring the development of advanced coal-cleaning technologies aimed at expanding the use of the nation`s vast coal reserves in an environmentally and economically acceptable manner. Because of the lack of practical experience with deeply beneficiated coal-based fuels, PETC has contracted Combustion Engineering, Inc. to perform a multi-year project on `Combustion Characterization of Beneficiated Coal-Based Fuels.` The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of Beneficiated Coal-Based Fuels (BCs) influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs.

  4. Recent Developments in Mems-Based Micro Fuel Cells

    CERN Document Server

    Pichonat, T

    2007-01-01

    Micro fuel cells ($\\mu$-FC) represent promising power sources for portable applications. Today, one of the technological ways to make $\\mu$-FC is to have recourse to standard microfabrication techniques used in the fabrication of micro electromechanical systems (MEMS). This paper shows an overview on the applications of MEMS techniques on miniature FC by presenting several solutions developed throughout the world. It also describes the latest developments of a new porous silicon-based miniature fuel cell. Using a silane grafted on an inorganic porous media as the proton-exchange membrane instead of a common ionomer such as Nafion, the fuel cell achieved a maximum power density of 58 mW cm-2 at room temperature with hydrogen as fuel.

  5. The conserved nhaAR operon is drastically divergent between B2 and non-B2 Escherichia coli and is involved in extra-intestinal virulence.

    Science.gov (United States)

    Lescat, Mathilde; Reibel, Florence; Pintard, Coralie; Dion, Sara; Glodt, Jérémy; Gateau, Cecile; Launay, Adrien; Ledda, Alice; Cruveiller, Stephane; Cruvellier, Stephane; Tourret, Jérôme; Tenaillon, Olivier

    2014-01-01

    The Escherichia coli species is divided in phylogenetic groups that differ in their virulence and commensal distribution. Strains belonging to the B2 group are involved in extra-intestinal pathologies but also appear to be more prevalent as commensals among human occidental populations. To investigate the genetic specificities of B2 sub-group, we used 128 sequenced genomes and identified genes of the core genome that showed marked difference between B2 and non-B2 genomes. We focused on the gene and its surrounding region with the strongest divergence between B2 and non-B2, the antiporter gene nhaA. This gene is part of the nhaAR operon, which is in the core genome but flanked by mobile regions, and is involved in growth at high pH and high sodium concentrations. Consistently, we found that a panel of non-B2 strains grew faster than B2 at high pH and high sodium concentrations. However, we could not identify differences in expression of the nhaAR operon using fluorescence reporter plasmids. Furthermore, the operon deletion had no differential impact between B2 and non-B2 strains, and did not result in a fitness modification in a murine model of gut colonization. Nevertheless, sequence analysis and experiments in a murine model of septicemia revealed that recombination in nhaA among B2 strains was observed in strains with low virulence. Finally, nhaA and nhaAR operon deletions drastically decreased virulence in one B2 strain. This effect of nhaAR deletion appeared to be stronger than deletion of all pathogenicity islands. Thus, a population genetic approach allowed us to identify an operon in the core genome without strong effect in commensalism but with an important role in extra-intestinal virulence, a landmark of the B2 strains.

  6. Polybenzimidazoles based on high temperature polymer electrolyte fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Linares Leon, Jose Joaquin; Camargo, Ana Paula M.; Ashino, Natalia M.; Morgado, Daniella L.; Frollini, Elisabeth; Paganin, Valdecir A.; Gonzalez, Ernesto Rafael [Universidade de Sao Paulo (IQSC/USP), Sao Carlos, SP (Brazil); Bajo, Justo Lobato [University of Castilla-La Mancha, Ciudad Real (Spain). Dept. of Chemical Engineering

    2010-07-01

    This work presents an interesting approach in order to enhance the performance of Polymer Electrolyte Membrane Fuel Cells (PEMFC) by means of an increase in the operational temperature. For this, two polymeric materials, Poly(2,5-bibenzimidazole) (ABPBI) and Poly[2,2'-(m-phenyl en)-5,5' bib enzimidazol] (PBI), impregnated with phosphoric acid have been utilized. These have shown excellent properties, such as thermal stability above 500 deg C, reasonably high conductivity when impregnated with H{sub 3}PO{sub 4} and a low permeability to alcohols compared to Nafion. Preliminary fuel cells measurements on hydrogen based Polymer Electrolyte Membrane Fuel Cell (PEMFC) displayed an interestingly reasonable good fuel cell performance, a quite reduced loss when the hydrogen stream was polluted with carbon monoxide, and finally, when the system was tested with an ethanol/water (E/W) fuel, it displayed quite promising results that allows placing this system as an attractive option in order to increase the cell performance and deal with the typical limitations of low temperature Nafion-based PEMFC. (author)

  7. Fabric-based alkaline direct formate microfluidic fuel cells.

    Science.gov (United States)

    Domalaon, Kryls; Tang, Catherine; Mendez, Alex; Bernal, Franky; Purohit, Krutarth; Pham, Linda; Haan, John; Gomez, Frank A

    2017-01-12

    Fabric-based microfluidic fuel cells (MFCs) serve as a novel, cost-efficient alternative to traditional FCs and batteries, since fluids naturally travel across fabric via capillary action, eliminating the need for an external pump and lowering production and operation costs. Building on previous research with Y-shaped paper-based MFCs, fabric-based MFCs mitigate fragility and durability issues caused by long periods of fuel immersion. In this study, we describe a microfluidic fabric-based direct formate fuel cell, with 5 M potassium formate and 30% hydrogen peroxide as the anode fuel and cathode oxidant, respectively. Using a two-strip, stacked design, the optimized parameters include the type of encasement, the barrier, and the fabric type. Surface contact of the fabric and laminate sheet expedited flow and respective chemical reactions. The maximum current (22.83 mA/cm(2) ) and power (4.40 mW/cm(2) ) densities achieved with a 65% cotton/35% polyester blend material are a respective 8.7% and 32% higher than previous studies with Y-shaped paper-based MFCs. In series configuration, the MFCs generate sufficient energy to power a handheld calculator, a thermometer, and a spectrum of light-emitting diodes.

  8. Microbial fuel cell based on Klebsiella pneumoniae biofilm

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Lixia [School of Chemistry and Environment, South China Normal University, Guangzhou 510006 (China); Guangdong Institute of Eco-Environmental and Soil Sciences, Guangzhou 510650 (China); Zhou, Shungui; Zhuang, Li; Zhang, Jintao; Lu, Na; Deng, Lifang [Guangdong Institute of Eco-Environmental and Soil Sciences, Guangzhou 510650 (China); Li, Weishan [School of Chemistry and Environment, South China Normal University, Guangzhou 510006 (China); Key Laboratory of Electrochemical Technology on Energy Storage and Power Generation in Guangdong Universities, Guangzhou 510006 (China)

    2008-10-15

    In this paper we reported a novel microbial fuel cell (MFC) based on Klebsiella pneumoniae (K. pneumoniae) strain L17 biofilm, which can utilize directly starch and glucose to generate electricity. The electrochemical activity of K. pneumoniae and the performance of the MFC were evaluated by cyclic voltammetry, scanning electron microscope (SEM) and polarization curve measurement. The results indicated that an established K. pneumoniae biofilm cells were responsible for the direct electron transfer from fuels to electrode during electricity production. The SEM observation proved the ability of K. pneumoniae to colonize on the electrode surface. This MFC generated power from the direct electrocatalysis by the K. pneumoniae strain L17 biofilm. (author)

  9. Graphene-Based Flexible Micrometer-Sized Microbial Fuel Cell

    KAUST Repository

    Mink, Justine E.

    2013-10-23

    Microbial fuel cells harvest electrical energy produced by bacteria during the natural decomposition of organic matter. We report a micrometer-sized microbial fuel cell that is able to generate nanowatt-scale power from microliters of liquids. The sustainable design is comprised of a graphene anode, an air cathode, and a polymer-based substrate platform for flexibility. The graphene layer was grown on a nickel thin film by using chemical vapor deposition at atmospheric pressure. Our demonstration provides a low-cost option to generate useful power for lab-on-chip applications and could be promising to rapidly screen and scale up microbial fuel cells for water purification without consuming excessive power (unlike other water treatment technologies).

  10. Plasma-membrane hyperpolarization diminishes the cation efflux via Nha1 antiporter and Ena ATPase under potassium-limiting conditions.

    Science.gov (United States)

    Zahrádka, Jaromír; Sychrová, Hana

    2012-06-01

    Saccharomyces cerevisiae extrudes K(+) cations even when potassium is only present in scarce amounts in the environment. Lost potassium is taken up by the Trk1 and Trk2 uptake systems. If the Trk transporters are absent or nonfunctional, the efflux of potassium is significantly diminished. A series of experiments with strains lacking various combinations of potassium efflux and uptake systems revealed that all three potassium-exporting systems the Nha1 antiporter, Ena ATPase and Tok1 channel contribute to potassium homeostasis and are active upon potassium limitation in wild-type cells. In trk1Δ trk2Δ mutants, the potassium efflux via potassium exporters Nha1 and Ena1 is diminished and can be restored either by the expression of TRK1 or deletion of TOK1. In both cases, the relative hyperpolarization of trk1Δ trk2Δ cells is decreased. Thus, it is the plasma-membrane potential which serves as the common mechanism regulating the activity of K(+) exporting systems. There is a continuous uptake and efflux of potassium in yeast cells to regulate their membrane potential and thereby other physiological parameters, and the cells are able to quickly and efficiently compensate for a malfunction of potassium transport in one direction by diminishing the transport in the other direction.

  11. Evaluation and Testing of the Suitability of a Coal-Based Jet Fuel

    Science.gov (United States)

    2008-06-01

    oxidative thermal stability was attributed to the lack of heteroatomic species, which contribute to deposition in petroleum -derived fuels...exists, petroleum -based fuels have more desirable low temperature properties, while at extremely low temperatures (<-50C) where solidification...production than the petroleum -derived fuel, but more than the coal-based fuel. In both the engine tests and the research combustor, the synthetic fuel

  12. Direct borohydride fuel cell using Ni-based composite anodes

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Jia; Sahai, Yogeshwar; Buchheit, Rudolph G. [Department of Materials Science and Engineering, The Ohio State University, 2041 College Rd., Columbus, OH 43210 (United States)

    2010-08-01

    In this study, nickel-based composite anode catalysts consisting of Ni with either Pd on carbon or Pt on carbon (the ratio of Ni:Pd or Ni:Pt being 25:1) were prepared for use in direct borohydride fuel cells (DBFCs). Cathode catalysts used were 1 mg cm{sup -2} Pt/C or Pd electrodeposited on activated carbon cloth. The oxidants were oxygen, oxygen in air, or acidified hydrogen peroxide. Alkaline solution of sodium borohydride was used as fuel in the cell. High power performance has been achieved by DBFC using non-precious metal, Ni-based composite anodes with relatively low anodic loading (e.g., 270 mW cm{sup -2} for NaBH{sub 4}/O{sub 2} fuel cell at 60 C, 665 mW cm{sup -2} for NaBH{sub 4}/H{sub 2}O{sub 2} fuel cell at 60 C). Effects of temperature, oxidant, and anode catalyst loading on the DBFC performance were investigated. The cell was operated for about 100 h and its performance stability was recorded. (author)

  13. Model-based fault diagnosis in PEM fuel cell systems

    Energy Technology Data Exchange (ETDEWEB)

    Escobet, T.; de Lira, S.; Puig, V.; Quevedo, J. [Automatic Control Department (ESAII), Universitat Politecnica de Catalunya (UPC), Rambla Sant Nebridi 10, 08222 Terrassa (Spain); Feroldi, D.; Riera, J.; Serra, M. [Institut de Robotica i Informatica Industrial (IRI), Consejo Superior de Investigaciones Cientificas (CSIC), Universitat Politecnica de Catalunya (UPC) Parc Tecnologic de Barcelona, Edifici U, Carrer Llorens i Artigas, 4-6, Planta 2, 08028 Barcelona (Spain)

    2009-07-01

    In this work, a model-based fault diagnosis methodology for PEM fuel cell systems is presented. The methodology is based on computing residuals, indicators that are obtained comparing measured inputs and outputs with analytical relationships, which are obtained by system modelling. The innovation of this methodology is based on the characterization of the relative residual fault sensitivity. To illustrate the results, a non-linear fuel cell simulator proposed in the literature is used, with modifications, to include a set of fault scenarios proposed in this work. Finally, it is presented the diagnosis results corresponding to these fault scenarios. It is remarkable that with this methodology it is possible to diagnose and isolate all the faults in the proposed set in contrast with other well known methodologies which use the binary signature matrix of analytical residuals and faults. (author)

  14. Novel Blend Membranes Based on Acid-Base Interactions for Fuel Cells

    Directory of Open Access Journals (Sweden)

    Yongzhu Fu

    2012-10-01

    Full Text Available Fuel cells hold great promise for wide applications in portable, residential, and large-scale power supplies. For low temperature fuel cells, such as the proton exchange membrane fuel cells (PEMFCs and direct methanol fuel cells (DMFCs, proton-exchange membranes (PEMs are a key component determining the fuel cells performance. PEMs with high proton conductivity under anhydrous conditions can allow PEMFCs to be operated above 100 °C, enabling use of hydrogen fuels with high-CO contents and improving the electrocatalytic activity. PEMs with high proton conductivity and low methanol crossover are critical for lowering catalyst loadings at the cathode and improving the performance and long-term stability of DMFCs. This review provides a summary of a number of novel acid-base blend membranes consisting of an acidic polymer and a basic compound containing N-heterocycle groups, which are promising for PEMFCs and DMFCs.

  15. Fuel-Cell Power Source Based on Onboard Rocket Propellants

    Science.gov (United States)

    Ganapathi, Gani; Narayan, Sri

    2010-01-01

    The use of onboard rocket propellants (dense liquids at room temperature) in place of conventional cryogenic fuel-cell reactants (hydrogen and oxygen) eliminates the mass penalties associated with cryocooling and boil-off. The high energy content and density of the rocket propellants will also require no additional chemical processing. For a 30-day mission on the Moon that requires a continuous 100 watts of power, the reactant mass and volume would be reduced by 15 and 50 percent, respectively, even without accounting for boiloff losses. The savings increase further with increasing transit times. A high-temperature, solid oxide, electrolyte-based fuel-cell configuration, that can rapidly combine rocket propellants - both monopropellant system with hydrazine and bi-propellant systems such as monomethyl hydrazine/ unsymmetrical dimethyl hydrazine (MMH/UDMH) and nitrogen tetroxide (NTO) to produce electrical energy - overcomes the severe drawbacks of earlier attempts in 1963-1967 of using fuel reforming and aqueous media. The electrical energy available from such a fuel cell operating at 60-percent efficiency is estimated to be 1,500 Wh/kg of reactants. The proposed use of zirconia-based oxide electrolyte at 800-1,000 C will permit continuous operation, very high power densities, and substantially increased efficiency of conversion over any of the earlier attempts. The solid oxide fuel cell is also tolerant to a wide range of environmental temperatures. Such a system is built for easy refueling for exploration missions and for the ability to turn on after several years of transit. Specific examples of future missions are in-situ landers on Europa and Titan that will face extreme radiation and temperature environments, flyby missions to Saturn, and landed missions on the Moon with 14 day/night cycles.

  16. Bifunctional Nanostructured Base Catalysts: Opportunities for BioFuels

    Energy Technology Data Exchange (ETDEWEB)

    Connor, William

    2010-12-30

    ABSTRACT This research studied and develop novel basic catalysts for production of renewable chemicals and fuels from biomass. We will focus on the development of unique porous structural-base catalysts formed by two techniques: from (mixed) metal-oxide bases and by nitrogen substitution for oxygen in zeolites. These catalysts will be compared to conventional solid base materials for aldol condensation, catalytic fast pyrolysis, and transesterification reactions. These reactions are important in processes that are currently being commercialized for production of fuels from biomass and will be pivotal in future biomass conversion to fuels and chemicals. Specifically, we have studied the aldol-condensation of acetone with furfural over oxides and zeolites, the conversion of sugars by rapid pyrolysis over zeolites and the trans-esterification of vegetable oil with methanol over mixed oxide catalysts. Our previous research has indicated that the base strength of framework nitrogen in nitrogen-substituted zeolites (NH-zeolites) is nearly twice as strong as in standard zeolites. Nitrogen substituted catalysts have been synthesized from several zeolites (including FAU, MFI, BEA, and LTL) using NH3 treatment.

  17. Study on Thermal Degradation Characteristics and Regression Rate Measurement of Paraffin-Based Fuel

    Directory of Open Access Journals (Sweden)

    Songqi Hu

    2015-09-01

    Full Text Available Paraffin fuel has been found to have a regression rate that is higher than conventional HTPB (hydroxyl-terminated polybutadiene fuel and, thus, presents itself as an ideal energy source for a hybrid rocket engine. The energy characteristics of paraffin-based fuel and HTPB fuel have been calculated by the method of minimum free energy. The thermal degradation characteristics were measured for paraffin, pretreated paraffin, HTPB and paraffin-based fuel in different working conditions by the using differential scanning calorimetry (DSC and a thermogravimetric analyzer (TGA. The regression rates of paraffin-based fuel and HTPB fuel were tested by a rectangular solid-gas hybrid engine. The research findings showed that: the specific impulse of paraffin-based fuel is almost the same as that of HTPB fuel; the decomposition temperature of pretreated paraffin is higher than that of the unprocessed paraffin, but lower than that of HTPB; with the increase of paraffin, the initial reaction exothermic peak of paraffin-based fuel is reached in advance, and the initial reaction heat release also increases; the regression rate of paraffin-based fuel is higher than the common HTPB fuel under the same conditions; with the increase of oxidizer mass flow rate, the regression rate of solid fuel increases accordingly for the same fuel formulation.

  18. Recapturing Graphite-Based Fuel Element Technology for Nuclear Thermal Propulsion

    Energy Technology Data Exchange (ETDEWEB)

    Trammell, Michael P [ORNL; Jolly, Brian C [ORNL; Miller, James Henry [ORNL; Qualls, A L [ORNL; Harrison, Thomas J [ORNL

    2013-01-01

    ORNL is currently recapturing graphite based fuel forms for Nuclear Thermal Propulsion (NTP). This effort involves research and development on materials selection, extrusion, and coating processes to produce fuel elements representative of historical ROVER and NERVA fuel. Initially, lab scale specimens were fabricated using surrogate oxides to develop processing parameters that could be applied to full length NTP fuel elements. Progress toward understanding the effect of these processing parameters on surrogate fuel microstructure is presented.

  19. Flexibility and dynamics of NhaA Na +/H +-antiporter of Escherichia coli studied by Fourier transform infrared spectroscopy

    Science.gov (United States)

    Džafić, E.; Klein, O.; Screpanti, E.; Hunte, C.; Mäntele, W.

    2009-02-01

    NhaA (41,355 Da) is a Na +/H + antiporter of Escherichia coli which plays a central role in regulation of intracellular pH, cellular Na + content, and cell volume [E. Padan, S. Schuldiner, J. Exp. Biol. 196 (1994) 443]. Its activity is strongly regulated by pH and increases over 3 orders of magnitude between pH 7 and 8 [A. Rothman, Y. Gerchman, E. Padan, S. Schuldiner, Biochemistry 36 (1997) 14572]. Protein dynamics and flexibility in the activated and inactivated state, respectively, was analysed by probing accessibility in 1H/ 2H exchange experiments for the wild type and the mutant G338S which is constitutively active independent of pH [A. Rimon, Y. Gerchman, Z. Kariv, E. Padan, J. Biol. Chem. 273 (1998) 26470]. This was studied by ATR-FTIR difference spectroscopy using a home built microvolume (protein is contained in a chamber with sample volumes of below 5 μl. It is in contact with the ATR crystal and separated from the flowing effector molecules by a dialysis membrane. The flow-ATR unit is characterised by high stability, fast response, and high sensitivity for the IR spectroscopic detection of binding-induced conformational changes and reactions. On the basis of 1H- 2H exchange of NhaA followed in the amide I and amide II region of the IR spectrum, it is concluded that the accessible fraction of the polypeptide chain of NhaA increases by more than 10% in the active state. For the mutant, no changes in accessibility were observed for different pH values. The increase of Na + concentration increases the extent of exchange. The stability of the wild type protein in the active and inactive form was analysed by measuring the temperature profiles of the IR spectra. A decrease of the structural stability of the protein with activation was observed. Together with the results from 1H/ 2H exchange, the inactive state represents a more compact form whereas activation induces a more open conformation of the protein.

  20. Ablation study of tungsten-based nuclear thermal rocket fuel

    Science.gov (United States)

    Smith, Tabitha Elizabeth Rose

    The research described in this thesis has been performed in order to support the materials research and development efforts of NASA Marshall Space Flight Center (MSFC), of Tungsten-based Nuclear Thermal Rocket (NTR) fuel. The NTR was developed to a point of flight readiness nearly six decades ago and has been undergoing gradual modification and upgrading since then. Due to the simplicity in design of the NTR, and also in the modernization of the materials fabrication processes of nuclear fuel since the 1960's, the fuel of the NTR has been upgraded continuously. Tungsten-based fuel is of great interest to the NTR community, seeking to determine its advantages over the Carbide-based fuel of the previous NTR programs. The materials development and fabrication process contains failure testing, which is currently being conducted at MSFC in the form of heating the material externally and internally to replicate operation within the nuclear reactor of the NTR, such as with hot gas and RF coils. In order to expand on these efforts, experiments and computational studies of Tungsten and a Tungsten Zirconium Oxide sample provided by NASA have been conducted for this dissertation within a plasma arc-jet, meant to induce ablation on the material. Mathematical analysis was also conducted, for purposes of verifying experiments and making predictions. The computational method utilizes Anisimov's kinetic method of plasma ablation, including a thermal conduction parameter from the Chapman Enskog expansion of the Maxwell Boltzmann equations, and has been modified to include a tangential velocity component. Experimental data matches that of the computational data, in which plasma ablation at an angle shows nearly half the ablation of plasma ablation at no angle. Fuel failure analysis of two NASA samples post-testing was conducted, and suggestions have been made for future materials fabrication processes. These studies, including the computational kinetic model at an angle and the

  1. Biogeochemical study of water and bottom sediments from the Khai river - Nha Trang Bay estuarine system, South China Sea

    Science.gov (United States)

    Shulga, Natalia; Lobys, Nikolay; Drozdova, Anastasia; Peresypkin, Valery

    2014-05-01

    The present study was carried out in Nha Trang Bay (Southern Vietnam, the South China Sea). The samples of water, suspended matter and bottom sediments were collected in summer 2010-2012 in section from the estuary of the Khai River to the marine part of the bay. The samples were analyzed in the stationary lab of IO RAS, Moscow, by TOC-V-CPH, GC/MS and pirolysis methods. We report here the novel data on sources, transformation and burial of OM coming from the Khai river waters. The investigation is focused on ontent and distribution of suspended matter (SM) in the estuary, dissolved organic carbon (DOC), particulated organic carbon (POC); molecular and group composition of hydrocarbons (n-alkanes, steranes, hopanes) and mercury content in water, SM and bottom sediments. It was found that concentration of POC and SM decrease in the Nha Trang Bay waters from estuary to the open part of the bay. However, major changes in the concentration of SM and POC belong to the zone of salinity gradient.DOC behavior is more stable throughout the study area. Organic-geochemical indicators estimation allowed recognition of genesis and transformation degree of organic matter in the study area. The estuary is characterized by mixed genesis of SM with a predominance of allochthonous organic matter whereas outlying parts of the Nha Trang bay are characterized by autochthonous OM. Composition of OM in sediments reflects regularities identified above, despite of the interannual and seasonal variability in the study area. The investigation reveals a predominance of terrestrial organic matter in the silt sediments of the estuary, transported by the Khai river. Distribution of OM in sediments of marine part of the bay is mosaic, with a predominance of planktonogenic, bacterial or terrestrial input at their complex combination. Local anthropogenic pollution as well as an impact of industrial city effluents are found in river- and seaport areas. According to obtained data sedimentation rate

  2. Emergy analysis of cassava-based fuel ethanol in China

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Hui; Chen, Li; Yan, Zongcheng; Wang, Honglin [School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510640 (China)

    2011-01-15

    Emergy analysis considers both energy quality and energy used in the past, and compensates for the inability of money to value non-market inputs in an objective manner. Its common unit allows all resources to be compared on a fair basis. As feedstock for fuel ethanol, cassava has some advantages over other feedstocks. The production system of cassava-based fuel ethanol (CFE) was evaluated by emergy analysis. The emergy indices for the system of cassava-based fuel ethanol (CFE) are as follows: transformity is 1.10 E + 5 sej/J, EYR is 1.07, ELR is 2.55, RER is 0.28, and ESI is 0.42. Compared with the emergy indices of wheat ethanol and corn ethanol, CFE is the most sustainable. CFE is a good alternative to substitute for oil in China. Non-renewable purchased emergy accounts for 71.15% of the whole input emergy. The dependence on non-renewable energy increases environmental degradation, making the system less sustainable relative to systems more dependent on renewable energies. For sustainable development, it is vital to reduce the consumption of non-renewable energy in the production of CFE. (author)

  3. Recent advances in Carbon Nanotube based Enzymatic Fuel Cells

    Directory of Open Access Journals (Sweden)

    Serge eCosnier

    2014-10-01

    Full Text Available This review summarizes recent trends in the field of enzymatic fuel cells. Thanks to the high specificity of enzymes, biofuel cells can generate electrical energy by oxidation of a targeted fuel (sugars, alcohols or hydrogen at the anode and reduction of oxidants (O2, H2O2 at the cathode in complex media. The combination of carbon nanotubes, enzymes and redox mediators was widely exploited to develop biofuel cells since the electrons, involved in the bio-electrocatalytic processes, can be efficiently transferred from or to an external circuit. Original approaches to construct electron transfer based CNT-bioelectrodes and impressive biofuel cell performances are reported as well as biomedical applications.

  4. Characterization and supply of coal based fuels. Quarterly report, August 1, 1987--October 31, 1987

    Energy Technology Data Exchange (ETDEWEB)

    1988-01-01

    Contract objectives are as follows: Develop fuel specifications to serve combustor requirements; Select coals having appropriate compositional and quality characteristics as well as an economically attractive reserve base; Provide quality assurance for both the parent coals and the fuel forms; and deliver premium coal-based fuels to combustor developers as needed for their contract work. Progress is discussed.

  5. 40 CFR 600.206-08 - Calculation and use of FTP-based and HFET-based fuel economy values for vehicle configurations.

    Science.gov (United States)

    2010-07-01

    ... natural gas test fuel. (b) If only one equivalent petroleum-based fuel economy value exists for an... petroleum-based fuel economy for that configuration. (c) If more than one equivalent petroleum-based fuel... HFET-based fuel economy values for vehicle configurations. 600.206-08 Section 600.206-08 Protection...

  6. SECA Coal-Based Systems - FuelCell Energy, Inc.

    Energy Technology Data Exchange (ETDEWEB)

    Ayagh, Hossein [Fuelcell Energy, Inc., Danbury, CT (United States)

    2014-01-31

    The overall goal of this U.S. Department of Energy (DOE) sponsored project is the development of solid oxide fuel cell (SOFC) cell and stack technology suitable for use in highly-efficient, economically-competitive central generation power plant facilities fueled by coal synthesis gas (syngas). This program incorporates the following supporting objectives: • Reduce SOFC-based electrical power generation system cost to $700 or less (2007 dollars) for a greater than 100 MW Integrated Gasification Fuel Cell (IGFC) power plant, exclusive of coal gasification and CO2 separation subsystem costs. • Achieve an overall IGFC power plant efficiency of at least 50%, from coal (higher heating value or HHV) to AC power (exclusive of CO2 compression power requirement). • Reduce the release of CO2 to the environment in an IGFC power plant to no more than 10% of the carbon in the syngas. • Increase SOFC stack reliability to achieve a design life of greater than 40,000 hours. At the inception of the project, the efforts were focused on research, design and testing of prototype planar SOFC power generators for stationary applications. FuelCell Energy, Inc. successfully completed the initial stage of the project by meeting the program metrics, culminating in delivery and testing of a 3 kW system at National Energy Technology Laboratory (NETL). Subsequently, the project was re-aligned into a three phase effort with the main goal to develop SOFC technology for application in coal-fueled power plants with >90% carbon capture. Phase I of the Coal-based efforts focused on cell and stack size scale-up with concurrent enhancement of performance, life, cost, and manufacturing characteristics. Also in Phase I, design and analysis of the baseline (greater than 100 MW) power plant system—including concept identification, system definition, and cost analysis—was conducted. Phase II efforts focused on development of a ≥25 kW SOFC stack tower incorporating

  7. SECA Coal-Based Systems - FuelCell Energy, Inc.

    Energy Technology Data Exchange (ETDEWEB)

    Ayagh, Hossein

    2014-01-31

    The overall goal of this U.S. Department of Energy (DOE) sponsored project is the development of solid oxide fuel cell (SOFC) cell and stack technology suitable for use in highly-efficient, economically-competitive central generation power plant facilities fueled by coal synthesis gas (syngas). This program incorporates the following supporting objectives: • Reduce SOFC-based electrical power generation system cost to $700 or less (2007 dollars) for a greater than 100 MW Integrated Gasification Fuel Cell (IGFC) power plant, exclusive of coal gasification and CO2 separation subsystem costs. • Achieve an overall IGFC power plant efficiency of at least 50%, from coal (higher heating value or HHV) to AC power (exclusive of CO2 compression power requirement). • Reduce the release of CO2 to the environment in an IGFC power plant to no more than 10% of the carbon in the syngas. • Increase SOFC stack reliability to achieve a design life of greater than 40,000 hours. At the inception of the project, the efforts were focused on research, design and testing of prototype planar SOFC power generators for stationary applications. FuelCell Energy, Inc. successfully completed the initial stage of the project by meeting the program metrics, culminating in delivery and testing of a 3 kW system at National Energy Technology Laboratory (NETL). Subsequently, the project was re-aligned into a three phase effort with the main goal to develop SOFC technology for application in coal-fueled power plants with >90% carbon capture. Phase I of the Coal-based efforts focused on cell and stack size scale-up with concurrent enhancement of performance, life, cost, and manufacturing characteristics. Also in Phase I, design and analysis of the baseline (greater than 100 MW) power plant system—including concept identification, system definition, and cost analysis—was conducted. Phase II efforts focused on development of a ≥25 kW SOFC stack tower incorporating multiple stack building

  8. Carbide-based fuel system for undersea vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Burke, A. Alan; Carreiro, Louis G.; Greene, Eric S. [Naval Undersea Warfare Center, Division Newport (NUWCDIVNPT), 1176 Howell Street, Building 1302/2, Newport, RI 02841 (United States)

    2008-01-21

    In underwater applications such as unmanned undersea vehicle (UUV) propulsion, mass and volume constraints often dictate system energy density and specific energy, which are targeted to exceed 300 Wh L{sup -1} and 300 Wh kg{sup -1}, respectively, in order to compete with state-of-the-art battery technologies. To address this need, a novel carbide-based fuel system (CFS) intended for use with a solid oxide fuel cell (SOFC) is under development that is capable of achieving these energy metrics as well as sequestering carbon dioxide. The proposed CFS uses calcium carbide and calcium hydride that react with water to generate acetylene and hydrogen as the fuel and calcium hydroxide as a carbon dioxide scrubber. The acetylene is hydrogenated to ethane and then reformed to syngas (carbon monoxide and hydrogen) before being utilized by the SOFC. Carbon dioxide effluent from the SOFC is reacted with the calcium hydroxide to produce a storable solid, calcium carbonate, thus eliminating gas evolution from the UUV. A system configuration is proposed and discussion follows concerning energy storage metrics, operational parameters and preliminary safety analysis. (author)

  9. Carbide-based fuel system for undersea vehicles

    Science.gov (United States)

    Burke, A. Alan; Carreiro, Louis G.; Greene, Eric S.

    In underwater applications such as unmanned undersea vehicle (UUV) propulsion, mass and volume constraints often dictate system energy density and specific energy, which are targeted to exceed 300 Wh L -1 and 300 Wh kg -1, respectively, in order to compete with state-of-the-art battery technologies. To address this need, a novel carbide-based fuel system (CFS) intended for use with a solid oxide fuel cell (SOFC) is under development that is capable of achieving these energy metrics as well as sequestering carbon dioxide. The proposed CFS uses calcium carbide and calcium hydride that react with water to generate acetylene and hydrogen as the fuel and calcium hydroxide as a carbon dioxide scrubber. The acetylene is hydrogenated to ethane and then reformed to syngas (carbon monoxide and hydrogen) before being utilized by the SOFC. Carbon dioxide effluent from the SOFC is reacted with the calcium hydroxide to produce a storable solid, calcium carbonate, thus eliminating gas evolution from the UUV. A system configuration is proposed and discussion follows concerning energy storage metrics, operational parameters and preliminary safety analysis.

  10. Coconut Oil Based Hybrid Fuels as Alternative Fuel for Diesel Engines

    Directory of Open Access Journals (Sweden)

    Pranil Singh

    2010-01-01

    Full Text Available Problem statement: The use of vegetable oils as a fuel in diesel engines causes some problems due to their high viscosity compared with diesel. Various techniques and methods are used to solve the problems resulting from high viscosity. Approach: One of the techniques is the preparation of a microemulsion fuel, called a hybrid fuel. In this study, hybrid fuels consisting of coconut oil, ethanol and octan-1-ol were prepared with an aim to test their suitability as a fuel for diesel engines. Density, viscosity and gross calorific values of these fuels were determined and the fuels were used to run a direct injection diesel engine. The engine performance and exhaust emissions were investigated and compared with that of diesel and coconut oil. Results: The experimental results show that the engine efficiency of the hybrid fuels is comparable to that of diesel. As the percentage of ethanol and/or octan-1-ol increased, the viscosity of the hybrid fuels decreased and the engine efficiency increased. The exhaust emissions were lower than those for diesel, except carbon monoxide, which increased. Conclusion/Recommendations: Hence, it is concluded that these hybrid fuels can be used successfully as an alternative fuel in diesel engines without any modifications. Their completely renewable nature ensures that they are environmentally friendly.

  11. Plate-Based Fuel Processing System Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Carlos Faz; Helen Liu; Jacques Nicole; David Yee

    2005-12-22

    took the initial steam reforming plate-reactor concept and advanced it towards an integrated fuel processing system. A substantial amount of modeling was performed to guide the catalyst development and prototype hardware design and fabrication efforts. The plate-reactor mechanical design was studied in detail to establish design guidelines which would help the plate reactor survive the stresses of repeated thermal cycles (from start-ups and shut-downs). Integrated system performance modeling was performed to predict system efficiencies and determine the parameters with the most significant impact on efficiency. In conjunction with the modeling effort, a significant effort was directed towards catalyst development. CESI developed a highly active, sulfur tolerant, coke resistant, precious metal based reforming catalyst. CESI also developed its own non-precious metal based water-gas shift catalyst and demonstrated the catalysts durability over several thousands of hours of testing. CESI also developed a unique preferential oxidation catalyst capable of reducing 1% CO to < 10 ppm CO over a 35 C operating window through a single pass plate-based reactor. Finally, CESI combined the modeling results and steam reforming catalyst development efforts into prototype hardware. The first generation 3kW(e) prototype was fabricated from existing heat-exchanger plates to expedite the fabrication process. This prototype demonstrated steady state operation ranging from 5 to 100% load conditions. The prototype also demonstrated a 20:1 turndown ratio, 10:1 load transient operation and rapid start-up capability.

  12. Modeling and control of fuel cell based distributed generation systems

    Science.gov (United States)

    Jung, Jin Woo

    This dissertation presents circuit models and control algorithms of fuel cell based distributed generation systems (DGS) for two DGS topologies. In the first topology, each DGS unit utilizes a battery in parallel to the fuel cell in a standalone AC power plant and a grid-interconnection. In the second topology, a Z-source converter, which employs both the L and C passive components and shoot-through zero vectors instead of the conventional DC/DC boost power converter in order to step up the DC-link voltage, is adopted for a standalone AC power supply. In Topology 1, two applications are studied: a standalone power generation (Single DGS Unit and Two DGS Units) and a grid-interconnection. First, dynamic model of the fuel cell is given based on electrochemical process. Second, two full-bridge DC to DC converters are adopted and their controllers are designed: an unidirectional full-bridge DC to DC boost converter for the fuel cell and a bidirectional full-bridge DC to DC buck/boost converter for the battery. Third, for a three-phase DC to AC inverter without or with a Delta/Y transformer, a discrete-time state space circuit model is given and two discrete-time feedback controllers are designed: voltage controller in the outer loop and current controller in the inner loop. And last, for load sharing of two DGS units and power flow control of two DGS units or the DGS connected to the grid, real and reactive power controllers are proposed. Particularly, for the grid-connected DGS application, a synchronization issue between an islanding mode and a paralleling mode to the grid is investigated, and two case studies are performed. To demonstrate the proposed circuit models and control strategies, simulation test-beds using Matlab/Simulink are constructed for each configuration of the fuel cell based DGS with a three-phase AC 120 V (L-N)/60 Hz/50 kVA and various simulation results are presented. In Topology 2, this dissertation presents system modeling, modified space

  13. Acute Dermal Irritation Study of Six Jet Fuels in New Zealand White Rabbits: Comparison of Four Bio-Based Jet Fuels with Two Petroleum JP-8 Fuels

    Science.gov (United States)

    2014-02-01

    irritation among airmen. 15. SUBJECT TERMS Dermal irritation, jet fuels, alternative fuels, synthetic paraffinic kerosene, JP-8, biobased /bio-based... plastic wrap to occlude the test site. The trunk of animals in both the occluded and semi-occluded groups was then wrapped with a gauze binder...secured with Dermiform® tape (Johnson and Johnson, New Brunswick NJ). Plastic restraint collars were applied to the animals to prevent ingestion of the

  14. Engine control system having fuel-based timing

    Science.gov (United States)

    Willi, Martin L [Dunlap, IL; Fiveland, Scott B [Metamora, IL; Montgomery, David T [Edelstein, IL; Gong, Weidong [Dunlap, IL

    2012-04-03

    A control system for an engine having a cylinder is disclosed having an engine valve movable to regulate a fluid flow of the cylinder and an actuator associated with the engine valve. The control system also has a sensor configured to generate a signal indicative of an amount of an air/fuel mixture remaining within the cylinder after completion of a first combustion event and a controller in communication with the actuator and the sensor. The controller may be configured to compare the amount with a desired amount, and to selectively regulate the actuator to adjust a timing of the engine valve associated with a subsequent combustion event based on the comparison.

  15. Fault Diagnosis for Fuel Cell Based on Naive Bayesian Classification

    Directory of Open Access Journals (Sweden)

    Liping Fan

    2013-07-01

    Full Text Available Many kinds of uncertain factors may exist in the process of fault diagnosis and affect diagnostic results. Bayesian network is one of the most effective theoretical models for uncertain knowledge expression and reasoning. The method of naive Bayesian classification is used in this paper in fault diagnosis of a proton exchange membrane fuel cell (PEMFC system. Based on the model of PEMFC, fault data are obtained through simulation experiment, learning and training of the naive Bayesian classification are finished, and some testing samples are selected to validate this method. Simulation results demonstrate that the method is feasible.    

  16. Natural Rubber Based Fuel Rich Propellant for Ramjet Rocket

    OpenAIRE

    Solomon Thomas; T. L. Varghese; Gupta, S. K.; T. S. Ram; V. N. Krishnamurthy

    1992-01-01

    Development of fuel rich propellants for air-breathing propulsion is one of the frontier areas of research. This carries less oxidiser than the normal propellants, uses ram air for complete combustion and is heavily metallised. Studies were conducted at VSSC for the development of hydroxyl-terminated natural rubber (HTNR)-based Mg and Mg-Al alloy-filled polyurethane systems. The HTNR prepolymer was modified to make it free of acid functionality so as to avoid reaction with the metals a...

  17. Simulation on reactor TRIGA Puspati core kinetics fueled with thorium (Th) based fuel element

    Science.gov (United States)

    Mohammed, Abdul Aziz; Pauzi, Anas Muhamad; Rahman, Shaik Mohmmed Haikhal Abdul; Zin, Muhamad Rawi Muhammad; Jamro, Rafhayudi; Idris, Faridah Mohamad

    2016-01-01

    In confronting global energy requirement and the search for better technologies, there is a real case for widening the range of potential variations in the design of nuclear power plants. Smaller and simpler reactors are attractive, provided they can meet safety and security standards and non-proliferation issues. On fuel cycle aspect, thorium fuel cycles produce much less plutonium and other radioactive transuranic elements than uranium fuel cycles. Although not fissile itself, Th-232 will absorb slow neutrons to produce uranium-233 (233U), which is fissile. By introducing Thorium, the numbers of highly enriched uranium fuel element can be reduced while maintaining the core neutronic performance. This paper describes the core kinetic of a small research reactor core like TRIGA fueled with a Th filled fuel element matrix using a general purpose Monte Carlo N-Particle (MCNP) code.

  18. Simulation on reactor TRIGA Puspati core kinetics fueled with thorium (Th) based fuel element

    Energy Technology Data Exchange (ETDEWEB)

    Mohammed, Abdul Aziz, E-mail: azizM@uniten.edu.my; Rahman, Shaik Mohmmed Haikhal Abdul [Universiti Tenaga Nasional. Jalan Ikram-UNITEN, 43000 Kajang, Selangor (Malaysia); Pauzi, Anas Muhamad, E-mail: anas@uniten.edu.my; Zin, Muhamad Rawi Muhammad; Jamro, Rafhayudi; Idris, Faridah Mohamad [Malaysian Nuclear Agency, Bangi, 43000 Kajang, Selangor (Malaysia)

    2016-01-22

    In confronting global energy requirement and the search for better technologies, there is a real case for widening the range of potential variations in the design of nuclear power plants. Smaller and simpler reactors are attractive, provided they can meet safety and security standards and non-proliferation issues. On fuel cycle aspect, thorium fuel cycles produce much less plutonium and other radioactive transuranic elements than uranium fuel cycles. Although not fissile itself, Th-232 will absorb slow neutrons to produce uranium-233 ({sup 233}U), which is fissile. By introducing Thorium, the numbers of highly enriched uranium fuel element can be reduced while maintaining the core neutronic performance. This paper describes the core kinetic of a small research reactor core like TRIGA fueled with a Th filled fuel element matrix using a general purpose Monte Carlo N-Particle (MCNP) code.

  19. Scratch Behaviors of Cr-Coated Zr-Based Fuel Claddings for Accident-Tolerant Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Young-Ho; Kim, Il-Hyun; Kim, Hyun-Gil; Kim, Hyung-Kyu; Koo, Yang-Hyun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    As the progression of Fukushima accident is worsened by the runaway reaction at a high temperature above 1200 .deg. C, it is essential to ensure the stabilities of coating layers on conventional Zr-based alloys during normal operations as well as severe accident conditions. This is because the failures of coating layer result in galvanic corrosion phenomenon by potential difference between coating layer and Zr alloy. Also, it is possible to damage the coating layer during handling and manufacturing process by contacting structural components of a fuel assembly. So, adhesion strength is one of the key factors determining the reliability of the coating layer on conventional Zr-based alloy. In this study, two kinds of Cr-coated Zr-based claddings were prepared using arc ion plating (AIP) and direct laser (DL) coating methods. The objective is to evaluate the scratch deformation behaviors of each coating layers on Zr alloys. Large area spallation below normal load of about 15 N appeared to be the predominant mode of failure in the AIP coating during scratch test. However, no tensile crack were found in entire stroke length. In DL coating, small plastic deformation and grooving behavior are more dominant scratching results. It was observed that the change of the slope of the COF curve did not coincide with the failure of coating layer.

  20. Fuel cells. Citations from the NTIS data base

    Science.gov (United States)

    Cavagnaro, D. M.

    1980-08-01

    Fuel cell applications, components, fabrication, design, catalysts, and chemistry are covered. The citations discuss different types of fuel cells such as hydrogen oxygen cells, hydrocarbon air cells, and biochemical cells.

  1. Robust Platinum-Based Electrocatalysts for Fuel Cell Applications

    Science.gov (United States)

    Coleman, Eric James

    Polymer electrolyte fuel cells (PEMFCs) are energy conversion devices that exploit the energetics of the reaction between hydrogen fuel and O 2 to generate electricity with water as the only byproduct. PEMFCs have attracted substantial attention due to their high conversion efficiency, high energy density, and low carbon footprint. However, PEMFC performance is hindered by the high activation barrier and slow reaction rates at the cathode where O2 undergoes an overall 4-electron reduction to water. The most efficient oxygen reduction reaction (ORR) catalyst materials to date are Pt group metals due to their high catalytic activity and stability in a wide range of operating conditions. Before fuel cells can become economically viable, efforts must be taken to decrease Pt content while maintaining a high level of ORR activity. This work describes the design and synthesis of a Pt-Cu electrocatalyst with ORR activity exceeding that of polycrystalline Pt. Production of this novel catalyst is quite simple and begins with synthesis of a porous Cu substrate, formed by etching Al from a Cu-Al alloy. The porous Cu substrate is then coated with a Pt layer via a spontaneous electrochemical process known as galvanic replacement. The Pt layer enhances the ORR activity (as measured by a rotating ring-disk electrode (RRDE)) and acts as a barrier towards corrosion of the Cu understructure. Growth of the Pt layer can be manipulated by time, temperature, concentration of Pt precursor, and convection rate during galvanic replacement. Data from analytical and electrochemical techniques confirm multiple Pt loadings have been achieved via the galvanic replacement process. The boost in ORR activity for the PtCu catalyst was determined to be a result of its lower affinity towards (site-blocking) OH adsorption. A unique catalyst degradation study explains the mechanism of initial catalyst ORR deactivation for both monometallic and bimetallic Pt-based catalysts. Finally, a rigorous and

  2. Science based integrated approach to advanced nuclear fuel development - vision, approach, and overview

    Energy Technology Data Exchange (ETDEWEB)

    Unal, Cetin [Los Alamos National Laboratory; Pasamehmetoglu, Kemal [IDAHO NATIONAL LAB; Carmack, Jon [IDAHO NATIONAL LAB

    2010-01-01

    Advancing the performance of Light Water Reactors, Advanced Nuclear Fuel Cycles, and Advanced Rcactors, such as the Next Generation Nuclear Power Plants, requires enhancing our fundamental understanding of fuel and materials behavior under irradiation. The capability to accurately model the nuclear fuel systems is critical. In order to understand specific aspects of the nuclear fuel, fully coupled fuel simulation codes are required to achieve licensing of specific nuclear fuel designs for operation. The backbone of these codes, models, and simulations is a fundamental understanding and predictive capability for simulating the phase and microstructural behavior of the nuclear fuel system materials and matrices. The purpose of this paper is to identify the modeling and simulation approach in order to deliver predictive tools for advanced fuels development. The coordination between experimental nuclear fuel design, development technical experts, and computational fuel modeling and simulation technical experts is a critical aspect of the approach and naturally leads to an integrated, goal-oriented science-based R & D approach and strengthens both the experimental and computational efforts. The Advanced Fuels Campaign (AFC) and Nuclear Energy Advanced Modeling and Simulation (NEAMS) Fuels Integrated Performance and Safety Code (IPSC) are working together to determine experimental data and modeling needs. The primary objective of the NEAMS fuels IPSC project is to deliver a coupled, three-dimensional, predictive computational platform for modeling the fabrication and both normal and abnormal operation of nuclear fuel pins and assemblies, applicable to both existing and future reactor fuel designs. The science based program is pursuing the development of an integrated multi-scale and multi-physics modeling and simulation platform for nuclear fuels. This overview paper discusses the vision, goals and approaches how to develop and implement the new approach.

  3. Laser-based analytical monitoring in nuclear-fuel processing plants

    Energy Technology Data Exchange (ETDEWEB)

    Hohimer, J.P.

    1978-09-01

    The use of laser-based analytical methods in nuclear-fuel processing plants is considered. The species and locations for accountability, process control, and effluent control measurements in the Coprocessing, Thorex, and reference Purex fuel processing operations are identified and the conventional analytical methods used for these measurements are summarized. The laser analytical methods based upon Raman, absorption, fluorescence, and nonlinear spectroscopy are reviewed and evaluated for their use in fuel processing plants. After a comparison of the capabilities of the laser-based and conventional analytical methods, the promising areas of application of the laser-based methods in fuel processing plants are identified.

  4. Laser-Based Characterization of Nuclear Fuel Plates

    Energy Technology Data Exchange (ETDEWEB)

    James A. Smith; David L. Cottle; Barry H. Rabin

    2013-07-01

    Ensuring the integrity of fuel-clad and clad-clad bonding in nuclear fuels is important for safe reactor operation and assessment of fuel performance, yet the measurement of bond strengths in actual fuels has proved challenging. The laser shockwave technique (LST) originally developed to characterize structural adhesion in composites is being employed to characterize interface strength in a new type of plate fuel being developed at Idaho National Laboratory (INL). LST is a non-contact method that uses lasers for the generation and detection of large-amplitude acoustic waves and is well suited for application to both fresh and irradiated nuclear-fuel plates. This paper will report on initial characterization results obtained from fresh fuel plates manufactured by different processes, including hot isostatic pressing, friction stir welding, and hot rolling.

  5. Laser-based characterization of nuclear fuel plates

    Science.gov (United States)

    Smith, James A.; Cottle, Dave L.; Rabin, Barry H.

    2014-02-01

    Ensuring the integrity of fuel-clad and clad-clad bonding in nuclear fuels is important for safe reactor operation and assessment of fuel performance, yet the measurement of bond strengths in actual fuels has proved challenging. The laser shockwave technique (LST) originally developed to characterize structural adhesion in composites is being employed to characterize interface strength in a new type of plate fuel being developed at Idaho National Laboratory (INL). LST is a non-contact method that uses lasers for the generation and detection of large-amplitude acoustic waves and is well suited for application to both fresh and irradiated nuclear-fuel plates. This paper will report on initial characterization results obtained from fresh fuel plates manufactured by different processes, including hot isostatic pressing, friction stir welding, and hot rolling.

  6. Fuel-Cell Electrolytes Based on Organosilica Hybrid Proton Conductors

    Science.gov (United States)

    Narayan, Sri R.; Yen, Shiao-Pin S.

    2008-01-01

    A new membrane composite material that combines an organosilica proton conductor with perfluorinated Nafion material to achieve good proton conductivity and high-temperature performance for membranes used for fuel cells in stationary, transportation, and portable applications has been developed. To achieve high proton conductivities of the order of 10(exp -1)S/cm over a wide range of temperatures, a composite membrane based on a new class of mesoporous, proton-conducting, hydrogen-bonded organosilica, used with Nafion, will allow for water retention and high proton conductivity over a wider range of temperatures than currently offered by Nafion alone. At the time of this reporting, this innovation is at the concept level. Some of the materials and processes investigated have shown good proton conductivity, but membranes have not yet been prepared and demonstrated.

  7. Photofragment Imaging of HNCO Decomposition at 210 nm: the Primary NH(a1Δ)+CO(X1Σ+) Channel

    Science.gov (United States)

    Wang, Hua; Liu, Shi-lin; Liu, Jie; Wang, Feng-yan; Jiang, Bo; Yang, Xue-ming

    2007-08-01

    The photodissociation of isocyanic acid (HNCO) on the first excited singlet state following the excitation at 210 nm was investigated with an ion velocity slice imaging technique by probing the CO fragment. It was found from the (2+1) resonance-enhanced multi-photon ionization (REMPI) spectrum that the CO fragments are rotationally hot with population up to Jmax=50. The velocity imagings of the CO fragments at JCO=30 and 35 indicate that formation of NH(a1Δ)+CO(X1Σ+, v=0) is the predominant dissociation channel at 210 nm. From analysis of the CO fragment translational energy distributions, the NH(a1Δ) fragment was observed to be rotationally cold, about half of the available energy was partitioned into the translational motion of fragments after dissociation, and the NH(a1Δ)+CO(X1Σ+) dissociation threshold was determined at 42738±30 cm-1. From analysis of the CO fragment angular distributions, the dissociation anisotropy parameter β was found to be negative, and increasing with the rotational quantum number of the NH fragment, i.e., from -0.75 at JNH=2-4 to -0.17 at JNH=11. Impulsive direct and vertical dissociation process of HNCO on the singlet state at 210 nm was confirmed experimentally. A classical impact dissociation model was employed to explain the dependence of the β value on the rotational excitation of the NH fragment.

  8. Desulfurization of jet fuel for fuel cell-based APU systems in aircraft

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Y.; Pasel, J.; Peters, R.; Stolten, D. [Forschungszentrum Juelich GmbH (Germany)

    2010-07-01

    To prevent the catalysts in fuel cell systems from poisoning by sulfur containing substances the fuel to be used must be desulfurized to a maximum of 10 ppmw of sulfur. Since the conventional hydrodesulfurization process employed in the refinery industry is not suitable for mobile fuel cell applications (e.g. auxiliary power units, APUs), the present study aims at developing an alternative process and determining its technical feasibility. A large number of processes were assessed with respect to their application in fuel cell APUs. The results revealed that a two-step process combining pervaporation and adsorption is a suitable process for the on-board desulfurization of jet fuel. The investigations to evaluate this process are presented in this paper. Seven different membrane materials and ten sorbent materials were screened to choose the most suitable candidates. Further laboratory experiments were conducted to optimize the operating conditions and to collect data for a pilot plant design. Different jet fuel qualities with up to 1650 ppmw of sulfur can be desulfurized to a level of 10 ppmw. (orig.)

  9. Method of forming a package for MEMS-based fuel cell

    Science.gov (United States)

    Morse, Jeffrey D; Jankowski, Alan F

    2013-05-21

    A MEMS-based fuel cell package and method thereof is disclosed. The fuel cell package comprises seven layers: (1) a sub-package fuel reservoir interface layer, (2) an anode manifold support layer, (3) a fuel/anode manifold and resistive heater layer, (4) a Thick Film Microporous Flow Host Structure layer containing a fuel cell, (5) an air manifold layer, (6) a cathode manifold support structure layer, and (7) a cap. Fuel cell packages with more than one fuel cell are formed by positioning stacks of these layers in series and/or parallel. The fuel cell package materials such as a molded plastic or a ceramic green tape material can be patterned, aligned and stacked to form three dimensional microfluidic channels that provide electrical feedthroughs from various layers which are bonded together and mechanically support a MEMS-based miniature fuel cell. The package incorporates resistive heating elements to control the temperature of the fuel cell stack. The package is fired to form a bond between the layers and one or more microporous flow host structures containing fuel cells are inserted within the Thick Film Microporous Flow Host Structure layer of the package.

  10. A review on the status of development in thorium-based nuclear fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Young Woo; Na, S. H.; Lee, Y. W.; Kim, H. S.; Kim, S. H.; Joung, C.Y

    2000-02-01

    Thorium as an alternative nuclear energy source had been widely investigated in the 1950s-1960s because it is more abundant than uranium, but the studies of thorium nuclear fuel cycle were discontinued by political and economic reasons in the 1970s. Recently, however, renewed interest was vested in thorium-based nuclear fuel cycle because it may generate less long-lived minor actinides and has a lower radiotoxicity of high level wastes after reprocessing compared with the thorium fuel cycle. In this state-of the art report, thorium-based nuclear cycle. In this state-of the art report, thorium-based nuclear fuel cycle and fuel fabrication processes developed so far with different reactor types are reviewed and analyzed to establish basic technologies of thorium fuel fabrication which could meet our situation. (author)

  11. Novel materials process for alcohol based fuel cells. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hyde, K.; Smith, R.

    2005-07-01

    At present, the unit cost of producing alcohol fuel cells, in particular the cost of the ion-exchange membrane and the platinum catalyst, is limiting the sales. Since the cost of platinum cannot be reduced, an effective means of making the cells more attractive would be to increase the power output per unit area of membrane other than by operating at elevated temperatures. To replace the expensive Nafion, ITM and Cranfield University have developed a new membrane based on ionic hydrophilic polymers. Both acidic and alkaline-based membranes have been produced, the latter may well avoid the use of platinum thus gaining a further cost bonus. Conductivity of the new styrene-sulphonic acid graft membranes is more than double that of Nafion. Similarly, in cross-over tests, the new cells outperformed the Nafion cells. Palladium was investigated as a cheaper alternative to platinum. Based on this study, ITM have applied for five new patents. The study was conducted by ITM Power Plc under contract to the DTI.

  12. 40 CFR 600.206-12 - Calculation and use of FTP-based and HFET-based fuel economy and carbon-related exhaust emission...

    Science.gov (United States)

    2010-07-01

    ... performed using alcohol or natural gas test fuel. (b) If only one equivalent petroleum-based fuel economy... per gallon, will comprise the petroleum-based fuel economy for that configuration. (c) If more than one equivalent petroleum-based fuel economy value exists for an electric vehicle configuration,...

  13. Experimental investigation of fuel regression rate in a HTPB based lab-scale hybrid rocket motor

    Science.gov (United States)

    Li, Xintian; Tian, Hui; Yu, Nanjia; Cai, Guobiao

    2014-12-01

    The fuel regression rate is an important parameter in the design process of the hybrid rocket motor. Additives in the solid fuel may have influences on the fuel regression rate, which will affect the internal ballistics of the motor. A series of firing experiments have been conducted on lab-scale hybrid rocket motors with 98% hydrogen peroxide (H2O2) oxidizer and hydroxyl terminated polybutadiene (HTPB) based fuels in this paper. An innovative fuel regression rate analysis method is established to diminish the errors caused by start and tailing stages in a short time firing test. The effects of the metal Mg, Al, aromatic hydrocarbon anthracene (C14H10), and carbon black (C) on the fuel regression rate are investigated. The fuel regression rate formulas of different fuel components are fitted according to the experiment data. The results indicate that the influence of C14H10 on the fuel regression rate of HTPB is not evident. However, the metal additives in the HTPB fuel can increase the fuel regression rate significantly.

  14. Fuel poverty in Scotland: refining spatial resolution in the Scottish Fuel Poverty Indicator using a GIS-based multiple risk index.

    Science.gov (United States)

    Morrison, Colin; Shortt, Niamh

    2008-12-01

    Fuel poverty describes a complex interaction between households with low income and energy inefficiency. The Scottish Executive has charged local Scottish authorities with the task of eradicating fuel poverty by 2016. In order to direct investment and tackle fuel poverty, a local authority must know which areas are more likely to contain fuel poor households. Currently, local area fuel poverty indicators, based on small area statistics, are used to identify target areas. This paper proposes an innovative methodology for refinement of the Scottish Fuel Poverty Indicator using GIS as a framework for integrating census data with georeferenced energy efficiency data on local housing stock. This allows a multi-scale mapping of fuel poverty risk at both a census output area level and an individual dwelling level. The proposed methodology highlights small areas, and households, possibly susceptible to fuel poverty previously masked by the aggregation of statistics to large geographic units.

  15. Biomass fuel based on wastes from the paper industry

    Directory of Open Access Journals (Sweden)

    Budzyń Stanisław

    2016-01-01

    Full Text Available Wastes from paper industry are mostly combustible. It is possible to recycle them with energy recovery. These wastes have a high moisture content (up to 60% and thus a small calorific value. An alternative to waste incineration is the production of solid recovered fuel. The benefits are: easy adjustment of the physical and chemical properties of the fuel (via the change of proportions of ingredients, low moisture and high calorific value. The study involved the following types of cellulose wastes: - Belmer - the rejects from recovered paper, Krofta - deinking sludge, sludge - wastewater treatment sludge, bark - the rejects from virgin pulps. The results of investigations of waste produced in one of the biggest Polish paper mill - are shown. Following aspects were investigated: energy properties, content of carbon, hydrogen, sulfur, chlorine and nitrogen, chemical composition of ash. Authors proposed two formulas of the biomass fuel. The properties of the fuel such as the content of carbon, hydrogen, sulfur, chlorine or nitrogen, the chemical composition of the ash were investigated. Due to the fact that the combustion of the biomass fuel is preferred in view of law regulations (zero CO2 emission, green certificates the content of biodegradable fraction was examined. It has been shown that the fuel is a biomass one. Fuel from waste can be a substitute for approx. 25% of primary fuel (coal used by the paper mill.

  16. Simulations of Lithium-Based Neutron Coincidence Counter for Gd-Loaded Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Cowles, Christian C.; Kouzes, Richard T.; Siciliano, Edward R.

    2014-10-31

    The Department of Energy Office of Nuclear Safeguards and Security (NA-241) is supporting the project Lithium-Based Alternative Neutron Detection Technology Coincidence Counting for Gd-loaded Fuels at Pacific Northwest National Laboratory for the development of a lithium-based neutron coincidence counter for nondestructively assaying Gd loaded nuclear fuel. This report provides results from MCNP simulations of a lithium-based coincidence counter for the possible measurement of Gd-loaded nuclear fuel. A comparison of lithium-based simulations and UNCL-II simulations with and without Gd loaded fuel is provided. A lithium-based model, referred to as PLNS3A-R1, showed strong promise for assaying Gd loaded fuel.

  17. Simulations of Lithium-Based Neutron Coincidence Counter for Gd-Loaded Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Cowles, Christian C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Kouzes, Richard T. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Siciliano, Edward R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-10-01

    The Department of Energy Office of Nuclear Safeguards and Security (NA-241) is supporting the project Lithium-Based Alternative Neutron Detection Technology Coincidence Counting for Gd-loaded Fuels at Pacific Northwest National Laboratory for the development of a lithium-based neutron coincidence counter for nondestructively assaying Gd loaded nuclear fuel. This report provides results from MCNP simulations of a lithium-based coincidence counter for the possible measurement of Gd-loaded nuclear fuel. A comparison of lithium-based simulations and UNCL-II simulations with and without Gd loaded fuel is provided. A lithium-based model, referred to as PLNS3A-R1, showed strong promise for assaying Gd loaded fuel.

  18. Model-based control of fuel cells (2): Optimal efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Golbert, Joshua; Lewin, Daniel R. [PSE Research Group, Wolfson Department of Chemical Engineering, Technion IIT, Haifa 32000 (Israel)

    2007-11-08

    A dynamic PEM fuel cell model has been developed, taking into account spatial dependencies of voltage, current, material flows, and temperatures. The voltage, current, and therefore, the efficiency are dependent on the temperature and other variables, which can be optimized on the fly to achieve optimal efficiency. In this paper, we demonstrate that a model predictive controller, relying on a reduced-order approximation of the dynamic PEM fuel cell model can satisfy setpoint changes in the power demand, while at the same time, minimize fuel consumption to maximize the efficiency. The main conclusion of the paper is that by appropriate formulation of the objective function, reliable optimization of the performance of a PEM fuel cell can be performed in which the main tunable parameter is the prediction and control horizons, V and U, respectively. We have demonstrated that increased fuel efficiency can be obtained at the expense of slower responses, by increasing the values of these parameters. (author)

  19. Trajectory Analysis of Fuel Injection into Supersonic Cross Flow Based on Schlieren Method

    Institute of Scientific and Technical Information of China (English)

    YANG Hui; LI Feng; SUN Baigang

    2012-01-01

    Trajectory analysis of fuel injection into supersonic cross flow is studied in this paper.A directly-connected wind tunnel is constructed to provide stable supersonic freestream.Based on the test rig,the schlieren system is established to reveal the fuel injection process visually.Subsequently,the method of quantitative schlieren is adopted to obtain data of both fuel/air interface and bow shock with the aid of Photoshop and Origin.Finally,the mechanism based on two influential factors of fuel injection angle and fuel injection driven pressure,is researched by vector analysis.A dimensionless model is deduced and analyzed.The curve fitting result is achieved.The relationship between the data and the two influential factors is established.The results provide not only the quantitative characteristics of the fuel injection in supersonic cross flow but also the valuable reference for the future computational simulation.

  20. Subtask 3.11 - Production of CBTL-Based Jet Fuels from Biomass-Based Feedstocks and Montana Coal

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Ramesh

    2014-06-01

    The Energy & Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from Exxon Mobil, undertook Subtask 3.11 to use a recently installed bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. The process involves liquefaction of Rosebud mine coal (Montana coal) coupled with an upgrading scheme to produce a naphthenic fuel. The upgrading comprises catalytic hydrotreating and saturation to produce naphthenic fuel. A synthetic jet fuel was prepared by blending equal volumes of naphthenic fuel with similar aliphatic fuel derived from biomass and 11 volume % of aromatic hydrocarbons. The synthetic fuel was tested using standard ASTM International techniques to determine compliance with JP-8 fuel. The composite fuel thus produced not only meets but exceeds the military aviation fuel-screening criteria. A 500-milliliter synthetic jet fuel sample which met internal screening criteria was submitted to the Air Force Research Laboratory (AFRL) at Wright–Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with U.S. Air Force-prescribed alternative aviation fuel initial screening criteria. The results show that this fuel meets or exceeds the key specification parameters for JP-8, a petroleum-based jet fuel widely used by the U.S. military. JP-8 specifications include parameters such as freeze point, density, flash point, and others; all of which were met by the EERC fuel sample. The fuel also exceeds the thermal stability specification of JP-8 fuel as determined by the quartz crystalline microbalance (QCM) test also performed at an independent laboratory as well as AFRL. This means that the EERC fuel looks and acts identically to petroleum-derived jet fuel and can be used

  1. Hydrocarbon Fuel Thermal Performance Modeling based on Systematic Measurement and Comprehensive Chromatographic Analysis

    Science.gov (United States)

    2016-07-27

    the Compositional Variability of RP-1 and RP-2 with the Advanced Distillation Curve Approach,” Energy & Fuels , Vol. 24 (2010), 5611-5623. 6 Fortin, T...Assessment of Variability in the Thermophysical Properties of Rocket Propellant RP-1,” Energy & Fuels , Vol. 26 (2012), 4383-4394. 7 Kehimkar, B...Conference Paper 3. DATES COVERED (From - To) 10 June 2016 - 27 July 2016 4. TITLE AND SUBTITLE Hydrocarbon Fuel Thermal Performance Modeling based on

  2. Natural Rubber Based Fuel Rich Propellant for Ramjet Rocket

    Directory of Open Access Journals (Sweden)

    Solomon Thomas

    1992-07-01

    Full Text Available Development of fuel rich propellants for air-breathing propulsion is one of the frontier areas of research. This carries less oxidiser than the normal propellants, uses ram air for complete combustion and is heavily metallised. Studies were conducted at VSSC for the development of hydroxyl-terminated natural rubber (HTNR-based Mg and Mg-Al alloy-filled polyurethane systems. The HTNR prepolymer was modified to make it free of acid functionality so as to avoid reaction with the metals and was then reacted with calculated amount of propylene oxide in the presence of tertiary amine catalyst at room temperature. Various levels of Mg and Mg-Al alloy were used in different compositions and the effect on propellant characteristics was studied. TMP and butane diol were used for higher crosslinking, chain extension, etc and their effects were evaluated. Propellant compositions using 30-35 per cent by weight of Mg/Mg-Al alloy with the modified prepolymer have been developed. They exhibit good processibility and mechanical properties. The feasibility of room temperature curing was attempted. Motors weighing 2 kg with 100 mm OD and 200 mm length were successfully static-tested in the primary mode for performance evaluation.

  3. Life-cycle analysis of bio-based aviation fuels.

    Science.gov (United States)

    Han, Jeongwoo; Elgowainy, Amgad; Cai, Hao; Wang, Michael Q

    2013-12-01

    Well-to-wake (WTWa) analysis of bio-based aviation fuels, including hydroprocessed renewable jet (HRJ) from various oil seeds, Fischer-Tropsch jet (FTJ) from corn-stover and co-feeding of coal and corn-stover, and pyrolysis jet from corn stover, is conducted and compared with petroleum jet. WTWa GHG emission reductions relative to petroleum jet can be 41-63% for HRJ, 68-76% for pyrolysis jet and 89% for FTJ from corn stover. The HRJ production stage dominates WTWa GHG emissions from HRJ pathways. The differences in GHG emissions from HRJ production stage among considered feedstocks are much smaller than those from fertilizer use and N2O emissions related to feedstock collection stage. Sensitivity analyses on FTJ production from coal and corn-stover are also conducted, showing the importance of biomass share in the feedstock, carbon capture and sequestration options, and overall efficiency. For both HRJ and FTJ, co-product handling methods have significant impacts on WTWa results.

  4. Lithium-ferrate-based cathodes for molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Lanagan, M.T.; Bloom, I.; Kaun, T.D. [Argonne National Lab., IL (United States)] [and others

    1996-12-31

    Argonne National Laboratory is developing advanced cathodes for pressurized operation of the molten carbonate fuel cell (MCFC) at {approximately}650{degrees}C. To be economically viable for stationary power generation, molten carbonate fuel cells must have lifetimes of more than 25,000 h while exhibiting superior cell performance. In the present technology, lithiated NiO is used as the cathode. Over the lifetime of the cell, however, N{sup 2+} ions tend to transport to the anode, where they are reduced to metallic Ni. With increased CO{sub 2} partial pressure, the transport of Ni increases because of the increased solubility of NiO in the carbonate electrolyte. Although this process is slow in MCFCs operated at 1 atm and a low CO{sub 2} partial pressure (about 0.1 atm), transport of nickel to the anode may be excessive at a higher pressure (e.g., 3 atm) and a high CO{sub 2} partial pressure (e.g., about 0.3 arm). This transport is expected to lead eventually to poor MCFC performance and/or short circuiting. Several alternative cathode compositions have been explored to reduce cathode solubility in the molten salt electrolyte. For example, LiCoO{sub 2} has been studied extensively as a potential cathode material. The LiCoO{sub 2} cathode has a low resistivity, about 10-cm, and can be used as a direct substitute for NiO. Argonne is developing advanced cathodes based on lithium ferrate (LiFeO{sub 2}), which is attractive because of its very low solubility in the molten (Li,K){sub 2}CO{sub 3} electrolyte. Because of its high resistivity (about 3000-cm), however, LiFeO{sub 2} cannot be used as a direct substitute for NiO. Cation substitution is, therefore, necessary to decrease resistivity. We determined the effect of cation substitution on the resistivity and deformation of LiFeO{sub 2}. The substituents were chosen because their respective oxides as well as LiFeO{sub 2} crystallize with the rock-salt structure.

  5. A quasi-direct methanol fuel cell system based on blend polymer membrane electrolytes

    DEFF Research Database (Denmark)

    Li, Qingfeng; Hjuler, Hans Aage; Hasiotis, C.

    2002-01-01

    , compared to less than 100 ppm CO for the Nafion-based technology at 80degrees C. The high CO tolerance makes it possible to use the reformed hydrogen directly from a simple methanol reformer without further CO removal. That both the fuel cell and the methanol reformer operate at temperatures around 200......On the basis of blend polymer electrolytes of polybenzimidazole and sulfonated polysulfone, a polymer electrolyte membrane fuel cell was developed with an operational temperature up to 200degrees C. Due to the high operational temperature, the fuel cell can tolerate 1.0-3.0 vol % CO in the fuel...

  6. Ohio's First Electrolysis-Based Hydrogen Fueling Station

    Science.gov (United States)

    Demattia, Brianne

    2014-01-01

    Presentation to the earth day coalition describing efforts with NASA GRC and Cleveland RTA on Ohio's hydrogen fueling station and bus demonstration. Project background and goals, challenges and successes, and current status.

  7. Technoeconomy of different solid oxide fuel cell based hybrid cycle

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2014-01-01

    Gas turbine, steam turbine and heat engine (Stirling engine) is used as bottoming cycle for a solid oxide fuel cell plant to compare different plants efficiencies, CO2 emissionsand plants cost in terms of $/kW. Each plant is then integrated with biomass gasification and finally six plants...... configurations are compared with each other. Technoeconomy is used when calculating the cost if the plants. It is found that when a solid oxide fuel cell plant is combined with a gas turbine cycle then the plant efficiency will be the highest one while if a biomass gasification plant is integrated...... with these hybrid cycles then integrated biomass gasification with solid oxide fuel cell and steam cycle will have the highest plant efficiency. The cost of solid oxide fuel cell with steam plant is found to be the lowest one with a value of about 1030$/kW....

  8. Performance Degradation Tests of Phosphoric Acid Doped PBI Membrane Based High Temperature PEM Fuel Cells

    DEFF Research Database (Denmark)

    Zhou, Fan; Araya, Samuel Simon; Grigoras, Ionela

    2014-01-01

    Degradation tests of two phosphoric acid (PA) doped PBI membrane based HT-PEM fuel cells were reported in this paper to investigate the effects of start/stop and the presence of methanol in the fuel to the performance degradation. Continuous tests with H2 and simulated reformate which was composed...... of H2, water steam and methanol as the fuel were performed on both single cells. 12-h-startup/12-h-shutdown dynamic tests were performed on the first single cell with pure dry H2 as the fuel and on the second single cell with simulated reformate as the fuel. Along with the tests electrochemical...... techniques such as polarization curves and electrochemical impedance spectroscopy (EIS) were employed to study the degradation mechanisms of the fuel cells. Both single cells showed an increase in the performance in the H2 continuous tests, because of a decrease in the ORR kinetic resistance probably due...

  9. Energy management strategy based on fuzzy logic for a fuel cell hybrid bus

    Science.gov (United States)

    Gao, Dawei; Jin, Zhenhua; Lu, Qingchun

    Fuel cell vehicles, as a substitute for internal-combustion-engine vehicles, have become a research hotspot for most automobile manufacturers all over the world. Fuel cell systems have disadvantages, such as high cost, slow response and no regenerative energy recovery during braking; hybridization can be a solution to these drawbacks. This paper presents a fuel cell hybrid bus which is equipped with a fuel cell system and two energy storage devices, i.e., a battery and an ultracapacitor. An energy management strategy based on fuzzy logic, which is employed to control the power flow of the vehicular power train, is described. This strategy is capable of determining the desired output power of the fuel cell system, battery and ultracapacitor according to the propulsion power and recuperated braking power. Some tests to verify the strategy were developed, and the results of the tests show the effectiveness of the proposed energy management strategy and the good performance of the fuel cell hybrid bus.

  10. Proton exchange membrane fuel cell system diagnosis based on the signed directed graph method

    Science.gov (United States)

    Hua, Jianfeng; Lu, Languang; Ouyang, Minggao; Li, Jianqiu; Xu, Liangfei

    The fuel-cell powered bus is becoming the favored choice for electric vehicles because of its extended driving range, zero emissions, and high energy conversion efficiency when compared with battery-operated electric vehicles. In China, a demonstration program for the fuel cell bus fleet operated at the Beijing Olympics in 2008 and the Shanghai Expo in 2010. It is necessary to develop comprehensive proton exchange membrane fuel cell (PEMFC) diagnostic tools to increase the reliability of these systems. It is especially critical for fuel-cell city buses serving large numbers of passengers using public transportation. This paper presents a diagnostic analysis and implementation study based on the signed directed graph (SDG) method for the fuel-cell system. This diagnostic system was successfully implemented in the fuel-cell bus fleet at the Shanghai Expo in 2010.

  11. Biomass fuel based on wastes from the paper industry

    OpenAIRE

    Budzyń Stanisław; Tora Barbara

    2016-01-01

    Wastes from paper industry are mostly combustible. It is possible to recycle them with energy recovery. These wastes have a high moisture content (up to 60%) and thus a small calorific value. An alternative to waste incineration is the production of solid recovered fuel. The benefits are: easy adjustment of the physical and chemical properties of the fuel (via the change of proportions of ingredients), low moisture and high calorific value. The study involved the following types of cellulose ...

  12. Hydrogen Research for Spaceport and Space-Based Applications: Fuel Cell Projects

    Science.gov (United States)

    Anderson, Tim; Balaban, Canan

    2008-01-01

    The activities presented are a broad based approach to advancing key hydrogen related technologies in areas such as fuel cells, hydrogen production, and distributed sensors for hydrogen-leak detection, laser instrumentation for hydrogen-leak detection, and cryogenic transport and storage. Presented are the results from research projects, education and outreach activities, system and trade studies. The work will aid in advancing the state-of-the-art for several critical technologies related to the implementation of a hydrogen infrastructure. Activities conducted are relevant to a number of propulsion and power systems for terrestrial, aeronautics and aerospace applications. Fuel cell research focused on proton exchange membranes (PEM), solid oxide fuel cells (SOFC). Specific technologies included aircraft fuel cell reformers, new and improved electrodes, electrolytes, interconnect, and seals, modeling of fuel cells including CFD coupled with impedance spectroscopy. Research was conducted on new materials and designs for fuel cells, along with using embedded sensors with power management electronics to improve the power density delivered by fuel cells. Fuel cell applications considered were in-space operations, aviation, and ground-based fuel cells such as; powering auxiliary power units (APUs) in aircraft; high power density, long duration power supplies for interplanetary missions (space science probes and planetary rovers); regenerative capabilities for high altitude aircraft; and power supplies for reusable launch vehicles.

  13. [Bioanode for a microbial fuel cell based on Gluconobacter oxydans inummobilized into a polymer matrix].

    Science.gov (United States)

    Alferov, S V; Minaĭcheva, P R; Arliapov, V A; Asulian, L D; Alferov, V A; Ponomareva, O N; Reshetilov, A N

    2014-01-01

    Acetic acid bacteria Gluconobacter oxydans subsp. industrius RKM V-1280 were immobilized into a synthetic matrix based on polyvinyl alcohol modified with N-vinylpyrrolidone and used as biocatalysts for the development ofbioanodes for microbial fuel cells. The immobilization method did not significantly affect bacterial substrate specificity. Bioanodes based on immobilized bacteria functioned stably for 7 days. The maximum voltage (fuel cell signal) was reached when 100-130 µM of an electron transport mediator, 2,6-dichlorophenolindophenol, was added into the anode compartment. The fuel cell signals reached a maximum at a glucose concentration higher than 6 mM. The power output of the laboratory model of a fuel cell based on the developed bioanode reached 7 mW/m2 with the use of fermentation industry wastes as fuel.

  14. Techno-Economic Analysis of Scalable Coal-Based Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Chuang, Steven S. C. [Univ. of Akron, OH (United States)

    2014-08-31

    Researchers at The University of Akron (UA) have demonstrated the technical feasibility of a laboratory coal fuel cell that can economically convert high sulfur coal into electricity with near zero negative environmental impact. Scaling up this coal fuel cell technology to the megawatt scale for the nation’s electric power supply requires two key elements: (i) developing the manufacturing technology for the components of the coal-based fuel cell, and (ii) long term testing of a kW scale fuel cell pilot plant. This project was expected to develop a scalable coal fuel cell manufacturing process through testing, demonstrating the feasibility of building a large-scale coal fuel cell power plant. We have developed a reproducible tape casting technique for the mass production of the planner fuel cells. Low cost interconnect and cathode current collector material was identified and current collection was improved. In addition, this study has demonstrated that electrochemical oxidation of carbon can take place on the Ni anode surface and the CO and CO2 product produced can further react with carbon to initiate the secondary reactions. One important secondary reaction is the reaction of carbon with CO2 to produce CO. We found CO and carbon can be electrochemically oxidized simultaneously inside of the anode porous structure and on the surface of anode for producing electricity. Since CH4 produced from coal during high temperature injection of coal into the anode chamber can cause severe deactivation of Ni-anode, we have studied how CH4 can interact with CO2 to produce in the anode chamber. CO produced was found able to inhibit coking and allow the rate of anode deactivation to be decreased. An injection system was developed to inject the solid carbon and coal fuels without bringing air into the anode chamber. Five planner fuel cells connected in a series configuration and tested. Extensive studies on the planner fuels

  15. Towards a reference architecture of fuel-based carbon management systems in the logistics industry

    NARCIS (Netherlands)

    Iacob, M.E.; Sinderen, van M.J.; Steenwijk, M.; Verkroost, P.

    2013-01-01

    The current practice in the logistics industry is to calculate the carbon footprint of transportation activities based on the distance covered, using long-term fuel consumption averages per kilometer. However, fuel consumption may actually vary over time, because of differences in road characteristi

  16. Systems Analysis of an Advanced Nuclear Fuel Cycle Based on a Modified UREX+3c Process

    Energy Technology Data Exchange (ETDEWEB)

    E. R. Johnson; R. E. Best

    2009-12-28

    The research described in this report was performed under a grant from the U.S. Department of Energy (DOE) to describe and compare the merits of two advanced alternative nuclear fuel cycles -- named by this study as the “UREX+3c fuel cycle” and the “Alternative Fuel Cycle” (AFC). Both fuel cycles were assumed to support 100 1,000 MWe light water reactor (LWR) nuclear power plants operating over the period 2020 through 2100, and the fast reactors (FRs) necessary to burn the plutonium and minor actinides generated by the LWRs. Reprocessing in both fuel cycles is assumed to be based on the UREX+3c process reported in earlier work by the DOE. Conceptually, the UREX+3c process provides nearly complete separation of the various components of spent nuclear fuel in order to enable recycle of reusable nuclear materials, and the storage, conversion, transmutation and/or disposal of other recovered components. Output of the process contains substantially all of the plutonium, which is recovered as a 5:1 uranium/plutonium mixture, in order to discourage plutonium diversion. Mixed oxide (MOX) fuel for recycle in LWRs is made using this 5:1 U/Pu mixture plus appropriate makeup uranium. A second process output contains all of the recovered uranium except the uranium in the 5:1 U/Pu mixture. The several other process outputs are various waste streams, including a stream of minor actinides that are stored until they are consumed in future FRs. For this study, the UREX+3c fuel cycle is assumed to recycle only the 5:1 U/Pu mixture to be used in LWR MOX fuel and to use depleted uranium (tails) for the makeup uranium. This fuel cycle is assumed not to use the recovered uranium output stream but to discard it instead. On the other hand, the AFC is assumed to recycle both the 5:1 U/Pu mixture and all of the recovered uranium. In this case, the recovered uranium is reenriched with the level of enrichment being determined by the amount of recovered plutonium and the combined amount

  17. Characterization and supply of coal based fuels. Volume 1, Final report and appendix A (Topical report)

    Energy Technology Data Exchange (ETDEWEB)

    1992-06-01

    Studies and data applicable for fuel markets and coal resource assessments were reviewed and evaluated to provide both guidelines and specifications for premium quality coal-based fuels. The fuels supplied under this contract were provided for testing of advanced combustors being developed under Pittsburgh Energy Technology Center (PETC) sponsorship for use in the residential, commercial and light industrial (RCLI) market sectors. The requirements of the combustor development contractors were surveyed and periodically updated to satisfy the evolving needs based on design and test experience. Available coals were screened and candidate coals were selected for further detailed characterization and preparation for delivery. A team of participants was assembled to provide fuels in both coal-water fuel (CWF) and dry ultrafine coal (DUC) forms. Information about major US coal fields was correlated with market needs analysis. Coal fields with major reserves of low sulfur coal that could be potentially amenable to premium coal-based fuels specifications were identified. The fuels requirements were focused in terms of market, equipment and resource constraints. With this basis, the coals selected for developmental testing satisfy the most stringent fuel requirements and utilize available current deep-cleaning capabilities.

  18. Thoria-based nuclear fuels thermophysical and thermodynamic properties, fabrication, reprocessing, and waste management

    CERN Document Server

    Bharadwaj, S R

    2013-01-01

    This book presents the state of the art on thermophysical and thermochemical properties, fabrication methodologies, irradiation behaviours, fuel reprocessing procedures, and aspects of waste management for oxide fuels in general and for thoria-based fuels in particular. The book covers all the essential features involved in the development of and working with nuclear technology. With the help of key databases, many of which were created by the authors, information is presented in the form of tables, figures, schematic diagrams and flow sheets, and photographs. This information will be useful for scientists and engineers working in the nuclear field, particularly for design and simulation, and for establishing the technology. One special feature is the inclusion of the latest information on thoria-based fuels, especially on the use of thorium in power generation, as it has less proliferation potential for nuclear weapons. Given its natural abundance, thorium offers a future alternative to uranium fuels in nuc...

  19. A review on phosphate based, solid state, protonic conductors for intermediate temperature fuel cells.

    Science.gov (United States)

    Paschos, O; Kunze, J; Stimming, U; Maglia, F

    2011-06-15

    The electrolytes currently used for proton exchange membrane fuel cells are mainly based on polymers such as Nafion which limits the operation regime of the cell to ∼80 °C. Solid oxide fuel cells operate at much elevated temperatures compared to proton exchange membrane fuel cells (∼1000 °C) and employ oxide electrolytes such as yttrium stabilized zirconia and gadolinium doped ceria. So far an intermediate temperature operation regime (300 °C) has not been widely explored which would open new pathways for novel fuel cell systems. In this review we summarize the potential use of phosphate compounds as electrolytes for intermediate temperature fuel cells. Various examples on ammonium polyphosphate, pyrophosphate, cesium phosphate and other phosphate based electrolytes are presented and their preparation methods, conduction mechanism and conductivity values are demonstrated.

  20. A review on phosphate based, solid state, protonic conductors for intermediate temperature fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Paschos, O; Kunze, J; Stimming, U [Department of Physics E19, Technische Universitaet Muenchen, James-Franck-Strasse 1, D-85748, Garching (Germany); Maglia, F, E-mail: odysseas.paschos@ph.tum.de [Dipartimento di Chimica Fisica ' M Rolla' , Universita di Pavia, Viale Taramelli 16, 27100 Pavia (Italy)

    2011-06-15

    The electrolytes currently used for proton exchange membrane fuel cells are mainly based on polymers such as Nafion which limits the operation regime of the cell to {approx} 80 {sup 0}C. Solid oxide fuel cells operate at much elevated temperatures compared to proton exchange membrane fuel cells ({approx}1000 {sup 0}C) and employ oxide electrolytes such as yttrium stabilized zirconia and gadolinium doped ceria. So far an intermediate temperature operation regime (300 {sup 0}C) has not been widely explored which would open new pathways for novel fuel cell systems. In this review we summarize the potential use of phosphate compounds as electrolytes for intermediate temperature fuel cells. Various examples on ammonium polyphosphate, pyrophosphate, cesium phosphate and other phosphate based electrolytes are presented and their preparation methods, conduction mechanism and conductivity values are demonstrated.

  1. Factoring-based method for the design of a nuclear fuel

    Energy Technology Data Exchange (ETDEWEB)

    Guzman-Arriaga, Rafael; Espinosa-Paredes, Gilberto [Division de Ciencias Basicas e Ingenieria, Universidad Autonoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186 Col. Vicentina, Mexico 09340, D. F. (Mexico)

    2010-05-15

    In this work a simple method for a fuel lattice design is presented. The method is focused on finding the radial distribution of the fuel rods having different fissile contents to obtain a prescribed neutron multiplication factor k{sub {infinity}} to a certain discharge burnup and to minimize the rod power peaking. This method is based on the factorization of the fissile content of each fuel bar and the performance of this novel method was demonstrated with a fuel design composed of enriched uranium for a typical boiling water reactor (BWR). The results show that the factoring-based method for the design of a nuclear fuel converges to a minimum rod power peaking and a prescribed k{sub {infinity}} in few iterations. A comparative analysis shows that the proposed method is more efficient than existing methods. (author)

  2. An operationally flexible fuel cell based on quaternary ammonium-biphosphate ion pairs

    Science.gov (United States)

    Lee, Kwan-Soo; Spendelow, Jacob S.; Choe, Yoong-Kee; Fujimoto, Cy; Kim, Yu Seung

    2016-09-01

    Fuel cells are promising devices for clean power generation in a variety of economically and environmentally significant applications. Low-temperature proton exchange membrane (PEM) fuel cells utilizing Nafion require a high level of hydration, which limits the operating temperature to less than 100 ∘C. In contrast, high-temperature PEM fuel cells utilizing phosphoric acid-doped polybenzimidazole can operate effectively up to 180 ∘C however, these devices degrade when exposed to water below 140 ∘C. Here we present a different class of PEM fuel cells based on quaternary ammonium-biphosphate ion pairs that can operate under conditions unattainable with existing fuel cell technologies. These fuel cells exhibit stable performance at 80-160 ∘C with a conductivity decay rate more than three orders of magnitude lower than that of a commercial high-temperature PEM fuel cell. By increasing the operational flexibility, this class of fuel cell can simplify the requirements for heat and water management, and potentially reduce the costs associated with the existing fully functional fuel cell systems.

  3. Satellite image based methods for fuels maps updating

    Science.gov (United States)

    Alonso-Benito, Alfonso; Hernandez-Leal, Pedro A.; Arbelo, Manuel; Gonzalez-Calvo, Alejandro; Moreno-Ruiz, Jose A.; Garcia-Lazaro, Jose R.

    2016-10-01

    Regular updating of fuels maps is important for forest fire management. Nevertheless complex and time consuming field work is usually necessary for this purpose, which prevents a more frequent update. That is why the assessment of the usefulness of satellite data and the development of remote sensing techniques that enable the automatic updating of these maps, is of vital interest. In this work, we have tested the use of the spectral bands of OLI (Operational Land Imager) sensor on board Landsat 8 satellite, for updating the fuels map of El Hierro Island (Spain). From previously digitized map, a set of 200 reference plots for different fuel types was created. A 50% of the plots were randomly used as a training set and the rest were considered for validation. Six supervised and 2 unsupervised classification methods were applied, considering two levels of detail. A first level with only 5 classes (Meadow, Brushwood, Undergrowth canopy cover >50%, Undergrowth canopy cover <15%, and Xeric formations), and the second one containing 19 fuel types. The level 1 classification methods yielded an overall accuracy ranging from 44% for Parellelepided to an 84% for Maximun Likelihood. Meanwhile, level 2 results showed at best, an unacceptable overall accuracy of 34%, which prevents the use of this data for such a detailed characterization. Anyway it has been demonstrated that in some conditions, images of medium spatial resolution, like Landsat 8-OLI, could be a valid tool for an automatic upgrade of fuels maps, minimizing costs and complementing traditional methodologies.

  4. Supply Chain-based Solution to Prevent Fuel Tax Evasion

    Energy Technology Data Exchange (ETDEWEB)

    Franzese, Oscar [ORNL; Capps, Gary J [ORNL; Daugherty, Michael [United States Department of Transportation (USDOT), Federal Highway Administration (FHWA); Siekmann, Adam [ORNL; Lascurain, Mary Beth [ORNL; Barker, Alan M [ORNL

    2016-01-01

    The primary source of funding for the United States transportation system is derived from motor fuel and other highway use taxes. Loss of revenue attributed to fuel-tax evasion has been assessed to be somewhere between $1 billion per year, or approximately 25% of the total tax collected. Any solution that addresses this problem needs to include not only the tax-collection agencies and auditors, but also the carriers transporting oil products and the carriers customers. This paper presents a system developed by the Oak Ridge National Laboratory for the Federal Highway Administration which has the potential to reduce or eliminate many fuel-tax evasion schemes. The solution balances the needs of tax-auditors and those of the fuel-hauling companies and their customers. The technology was deployed and successfully tested during an eight-month period on a real-world fuel-hauling fleet. Day-to-day operations of the fleet were minimally affected by their interaction with this system. The results of that test are discussed in this paper.

  5. Self-sustained cabinet based on fuel cell technology and solar energy

    Energy Technology Data Exchange (ETDEWEB)

    Correa, Rafael Augusto de Oliveira; Valentim, Rafael Bertier; Glir, Joao Raphael Zanlorensi; Stall, Alexandre; Sommer, Elise Meister; Sanches, Luciana Schimidilin; Dias, Fernando Gallego; Korndorfer, Heitor Medeiros de Albuquerque; Vargas, Jose Viriato Coelho [Universidade Federal do Parana (DEMEC/UFPR), Curitiba, PR (Brazil). Dept. de Engenharia Mecanica], Email: rafaelcorrea123@hotmail.com; Ordonez, Juan Carlos [Florida State University, Tallahasse, Florida (United States). Dept. of Mechanical Engineering. Center for Advanced Power Systems

    2010-07-01

    Along the past few years, there has been intensive research on clean and renewable energy production. Two main reasons have been pointed out: pollution caused by oil based fuels consumption and their availability diminution, which increases their production costs. Fuel Cells have shown to be a clean and renewable energy source, which reveals them as a promising solution, although their technology needs further development. Fuel Cells produce electricity, water and heat consuming hydrogen and oxygen, this provided pure or from a natural air source. Present research has combined different equipment to compose a self-sustaining fuel cells technology based cabinet for energy production, which is a Regenerative Fuel Cell System (RFC). This system contains: fuel cells stack, electrolyzer, photovoltaic panel, batteries, current inverter and a charge controller. Photovoltaic panel charges the batteries, while charge controller controls the batteries loading. Batteries are connected to an inverter which converts direct current into alternating current. Inverter is connected to an electrolyzer (Hogen GC 600) which splits the water molecule into hydrogen and oxygen molecules. Produced hydrogen supplies the fuel cell stack and the oxygen is released directly to the atmosphere. Fuel cell stacks power production is transformed into mechanical energy by a fan. Electrical power generated by Ballard stack is 5.124 W, with a voltage of 36.6 V and current of 0.14 A. The system proved to have a great efficiency and to be capable to assemble two renewable energy sources (solar and fuel cell technology) in a self-sustainable cabinet. It has also been shown that equipment such as Electrolyzer, Fuel Cell Stack and Photovoltaic panel can be fit together in the order to produce energy. Therefore, research on Fuel Cells Regenerative System reveals great importance for developing a new, clean, renewable and regenerative energy production system. (author)

  6. Algae-Based Jet Fuel: The Renewable Alternative to the Air Force’s Focus On Coal-To-Liquid Synthetic Fuel

    Science.gov (United States)

    2009-10-19

    with aircraft rubber seals causing them to expand. Without aromatics, aircraft seals don’t expand and aircraft fuel systems leak. 16 According to an...waste piles, mountain top removal, and coal dust pollution. 80 While increased coal mining has its own issues, FT CTL plants have additional...Compared to petroleum fuel, algae-based fuel emits fewer particulates, air toxins and carcinogens . 102 Additionally, algae cultivation can occur in

  7. Formulation and Testing of Paraffin-Based Solid Fuels Containing Energetic Additives for Hybrid Rockets

    Science.gov (United States)

    Larson, Daniel B.; Boyer, Eric; Wachs,Trevor; Kuo, Kenneth K.; Story, George

    2012-01-01

    Many approaches have been considered in an effort to improve the regression rate of solid fuels for hybrid rocket applications. One promising method is to use a fuel with a fast burning rate such as paraffin wax; however, additional performance increases to the fuel regression rate are necessary to make the fuel a viable candidate to replace current launch propulsion systems. The addition of energetic and/or nano-sized particles is one way to increase mass-burning rates of the solid fuels and increase the overall performance of the hybrid rocket motor.1,2 Several paraffin-based fuel grains with various energetic additives (e.g., lithium aluminum hydride (LiAlH4) have been cast in an attempt to improve regression rates. There are two major advantages to introducing LiAlH4 additive into the solid fuel matrix: 1) the increased characteristic velocity, 2) decreased dependency of Isp on oxidizer-to-fuel ratio. The testing and characterization of these solid-fuel grains have shown that continued work is necessary to eliminate unburned/unreacted fuel in downstream sections of the test apparatus.3 Changes to the fuel matrix include higher melting point wax and smaller energetic additive particles. The reduction in particle size through various methods can result in more homogeneous grain structure. The higher melting point wax can serve to reduce the melt-layer thickness, allowing the LiAlH4 particles to react closer to the burning surface, thus increasing the heat feedback rate and fuel regression rate. In addition to the formulation of LiAlH4 and paraffin wax solid-fuel grains, liquid additives of triethylaluminum and diisobutylaluminum hydride will be included in this study. Another promising fuel formulation consideration is to incorporate a small percentage of RDX as an additive to paraffin. A novel casting technique will be used by dissolving RDX in a solvent to crystallize the energetic additive. After dissolving the RDX in a solvent chosen for its compatibility

  8. Combustion characteristics of Methanol-base fuel(MBF)made by coal

    Institute of Scientific and Technical Information of China (English)

    ZHANG Quan; ZHAO Cong-cong; LIU Yang

    2011-01-01

    Profound experimental research was made on Methanol-base fuel(MBF)mainly consisting of methanol,and the results were compared with that of diesel oil.Their respective combustion characteristics of caloric value,combustion efficiency and components of smoke were synthetically analyzed by employing the electronic weighing devices,the rotor flow-meter,intelligent flue gas analyzer,advanced bomb calorimeter,etc.,referring to the feasibility of taking it as a fuel for general use.Experiment results show that Methanol-base fuel not only has superiorities on combustion characteristics but also bears energy saving and environmental protection advantages.

  9. Durability Issues and Status of PBI-Based Fuel Cells

    DEFF Research Database (Denmark)

    Jakobsen, Mark Tonny Dalsgaard; Jensen, Jens Oluf; Cleemann, Lars Nilausen;

    2016-01-01

    This chapter briefly reviews durability and stability issues with key materials and components for HT-PEMFCs, including the polymer membrane, the doping acid, the electrocatalyst, the catalyst support and bipolar plates. Degradation mechanisms and their dependence on fuel cell operating conditions...

  10. A Monte Carlo based spent fuel analysis safeguards strategy assessment

    Energy Technology Data Exchange (ETDEWEB)

    Fensin, Michael L [Los Alamos National Laboratory; Tobin, Stephen J [Los Alamos National Laboratory; Swinhoe, Martyn T [Los Alamos National Laboratory; Menlove, Howard O [Los Alamos National Laboratory; Sandoval, Nathan P [Los Alamos National Laboratory

    2009-01-01

    Safeguarding nuclear material involves the detection of diversions of significant quantities of nuclear materials, and the deterrence of such diversions by the risk of early detection. There are a variety of motivations for quantifying plutonium in spent fuel assemblies by means of nondestructive assay (NDA) including the following: strengthening the capabilities of the International Atomic Energy Agencies ability to safeguards nuclear facilities, shipper/receiver difference, input accountability at reprocessing facilities and burnup credit at repositories. Many NDA techniques exist for measuring signatures from spent fuel; however, no single NDA technique can, in isolation, quantify elemental plutonium and other actinides of interest in spent fuel. A study has been undertaken to determine the best integrated combination of cost effective techniques for quantifying plutonium mass in spent fuel for nuclear safeguards. A standardized assessment process was developed to compare the effective merits and faults of 12 different detection techniques in order to integrate a few techniques and to down-select among the techniques in preparation for experiments. The process involves generating a basis burnup/enrichment/cooling time dependent spent fuel assembly library, creating diversion scenarios, developing detector models and quantifying the capability of each NDA technique. Because hundreds of input and output files must be managed in the couplings of data transitions for the different facets of the assessment process, a graphical user interface (GUI) was development that automates the process. This GUI allows users to visually create diversion scenarios with varied replacement materials, and generate a MCNPX fixed source detector assessment input file. The end result of the assembly library assessment is to select a set of common source terms and diversion scenarios for quantifying the capability of each of the 12 NDA techniques. We present here the generalized

  11. Break-in and Performance Issues on a single cell PBI-based PEM Fuel Cell

    DEFF Research Database (Denmark)

    Kær, Søren Knudsen; Jespersen, Jesper Lebæk

    and the current drawn from the fuel cell are of great importance. One must therefore choose the point of operation carefully in order for the fuel cell to fulfil the requirements for lifetime perform-ance of the system. Break-in of fuel cells is often done in scientific experiments to improve the performance...... of the fuel cell, even though break-in of a fuel cell implemented in a commercial application would most likely not be feasible. In the present work a commercially available PBI-based high temperature MEA is subject to a break-in procedure, as specified by the manufacturer. The cell was operated at 160 °C...... at the active sites of the electrodes causing a more sluggish perform-ance. Moreover, preliminary data is given on a long term degradation study, using Electrochemical Im-pedance Spectroscopy (EIS) measurements to analyze the degradation at high current densities (0.8 A/cm2)....

  12. Uncertainty in life cycle economical analysis of cassava-based ethanol fuel

    Institute of Scientific and Technical Information of China (English)

    LENG Ru-bo; DAI Du; CHEN Xiao-jun; WANG Cheng-tao

    2005-01-01

    Biomass ethanol fuel is not only renewable but also environmental-friendly. Guangxi Zhuang Autonomous Region is developing the cassava-based ethanol fuel. Economical performance of the project is the key issue.The traditional life cycle economical analysis is just a static calculation process. Uncertainty is the character of cassava yield, cost of cassava plant, cassava price, tax rate and gasoline price, and the economical performance of the project is determined by these aspects. This study proposes an economical model of cassava-based ethanol fuel. The method of Monte Carol is used to simulate the economical performance. This method conquers the shortage of the traditional way. The results show that cassava-based ethanol fuel can get survived when the tax is exempted. Finally, the study also evaluates the potential of the economical performance.

  13. Dynamic Analysis of Nuclear Waste Generation Based on Nuclear Fuel Cycle Transition Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, S. R. [University of Science and Technology, Daejeon (Korea, Republic of); Ko, W. I. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    According to the recommendations submitted by the Public Engagement Commission on Spent Nuclear Fuel Management (PECOS), the government was advised to pick the site for an underground laboratory and interim storage facilities before the end of 2020 followed by the related research for permanent and underground disposal of spent fuel after 10 years. In the middle of the main issues, the factors of environmentally friendly and safe way to handle nuclear waste are inextricable from nuclear power generating nation to ensure the sustainability of nuclear power. For this purposes, the closed nuclear fuel cycle has been developed regarding deep geological disposal, pyroprocessing, and burner type sodium-cooled fast reactors (SFRs) in Korea. Among two methods of an equilibrium model and a dynamic model generally used for screening nuclear fuel cycle system, the dynamic model is more appropriate to envisage country-specific environment with the transition phase in the long term and significant to estimate meaningful impacts based on the timedependent behavior of harmful wastes. This study aims at analyzing the spent nuclear fuel generation based on the long-term nuclear fuel cycle transition scenarios considered at up-to-date country specific conditions and comparing long term advantages of the developed nuclear fuel cycle option between once-through cycle and Pyro-SFR cycle. In this study, a dynamic analysis was carried out to estimate the long-term projection of nuclear electricity generation, installed capacity, spent nuclear fuel arising in different fuel cycle scenarios based on the up-to-date national energy plans.

  14. A Bio-Based Fuel Cell for Distributed Energy Generation

    Energy Technology Data Exchange (ETDEWEB)

    Anthony Terrinoni; Sean Gifford

    2008-06-30

    The technology we propose consists primarily of an improved design for increasing the energy density of a certain class of bio-fuel cell (BFC). The BFCs we consider are those which harvest electrons produced by microorganisms during their metabolism of organic substrates (e.g. glucose, acetate). We estimate that our technology will significantly enhance power production (per unit volume) of these BFCs, to the point where they could be employed as stand-alone systems for distributed energy generation.

  15. New Membranes Based on Polybenzimidazole for Polymer Fuel Cells

    Institute of Scientific and Technical Information of China (English)

    P.Mustarelli; E.Quartarone; S; Grandi; A.Carollo; S.Leonardi; A.Magistris

    2007-01-01

    1 Results Acid-doped polybenzimidazoles[1] are particularly appealing because of high proton conductivity with no or low humidification and promising fuel cells performances. PBI, in fact, contains basic functional groups which can easily interact with strong oxo-acids, such as H3PO4 and H2SO4. The acid partially protonates the polymer and partially is freely dispersed in the polymer backbone, so allowing proton migration via Grotthuss mechanism along the anionic chains[2]. Anyway, a technological limit...

  16. Advanced Thermally Stable Coal-Based Jet Fuels

    Science.gov (United States)

    2009-09-30

    hydrotreating to remove sulfur and then by hydrogenation for partial or complete ring saturation. Although this approach leads to a fuel of excellent quality...contributed by this coal were mainly two- and three-ring compounds. With hydrotreating to reduce sulfur and nitrogen and saturation of the aromatics...it could be a useful solvent for process configurations that couple coal conversion upstream with standard downstream hydrotreating , aromatics

  17. Improved Accelerated Stress Tests Based on Fuel Cell Vehicle Data

    Energy Technology Data Exchange (ETDEWEB)

    Patterson, Timothy [Research Engineer; Motupally, Sathya [Research Engineer

    2012-06-01

    UTC will led a top-tier team of industry and national laboratory participants to update and improve DOE’s Accelerated Stress Tests (AST’s) for hydrogen fuel cells. This in-depth investigation will focused on critical fuel cell components (e.g. membrane electrode assemblies - MEA) whose durability represented barriers for widespread commercialization of hydrogen fuel cell technology. UTC had access to MEA materials that had accrued significant load time under real-world conditions in PureMotion® 120 power plant used in transit buses. These materials are referred to as end-of-life (EOL) components in the rest of this document. Advanced characterization techniques were used to evaluate degradation mode progress using these critical cell components extracted from both bus power plants and corresponding materials tested using the DOE AST’s. These techniques were applied to samples at beginning-of-life (BOL) to serve as a baseline. These comparisons advised the progress of the various failure modes that these critical components were subjected to, such as membrane degradation, catalyst support corrosion, platinum group metal dissolution, and others. Gaps in the existing ASTs predicted the degradation observed in the field in terms of these modes were outlined. Using the gaps, new AST’s were recommended and tested to better reflect the degradation modes seen in field operation. Also, BOL components were degraded in a test vehicle at UTC designed to accelerate the bus field operation.

  18. Systems Analysis of an Advanced Nuclear Fuel Cycle Based on a Modified UREX+3c Process

    Energy Technology Data Exchange (ETDEWEB)

    E. R. Johnson; R. E. Best

    2009-12-28

    The research described in this report was performed under a grant from the U.S. Department of Energy (DOE) to describe and compare the merits of two advanced alternative nuclear fuel cycles -- named by this study as the “UREX+3c fuel cycle” and the “Alternative Fuel Cycle” (AFC). Both fuel cycles were assumed to support 100 1,000 MWe light water reactor (LWR) nuclear power plants operating over the period 2020 through 2100, and the fast reactors (FRs) necessary to burn the plutonium and minor actinides generated by the LWRs. Reprocessing in both fuel cycles is assumed to be based on the UREX+3c process reported in earlier work by the DOE. Conceptually, the UREX+3c process provides nearly complete separation of the various components of spent nuclear fuel in order to enable recycle of reusable nuclear materials, and the storage, conversion, transmutation and/or disposal of other recovered components. Output of the process contains substantially all of the plutonium, which is recovered as a 5:1 uranium/plutonium mixture, in order to discourage plutonium diversion. Mixed oxide (MOX) fuel for recycle in LWRs is made using this 5:1 U/Pu mixture plus appropriate makeup uranium. A second process output contains all of the recovered uranium except the uranium in the 5:1 U/Pu mixture. The several other process outputs are various waste streams, including a stream of minor actinides that are stored until they are consumed in future FRs. For this study, the UREX+3c fuel cycle is assumed to recycle only the 5:1 U/Pu mixture to be used in LWR MOX fuel and to use depleted uranium (tails) for the makeup uranium. This fuel cycle is assumed not to use the recovered uranium output stream but to discard it instead. On the other hand, the AFC is assumed to recycle both the 5:1 U/Pu mixture and all of the recovered uranium. In this case, the recovered uranium is reenriched with the level of enrichment being determined by the amount of recovered plutonium and the combined amount

  19. Thorium-based mixed oxide fuel in a pressurized water reactor: A feasibility analysis with MCNP

    Science.gov (United States)

    Tucker, Lucas Powelson

    This dissertation investigates techniques for spent fuel monitoring, and assesses the feasibility of using a thorium-based mixed oxide fuel in a conventional pressurized water reactor for plutonium disposition. Both non-paralyzing and paralyzing dead-time calculations were performed for the Portable Spectroscopic Fast Neutron Probe (N-Probe), which can be used for spent fuel interrogation. Also, a Canberra 3He neutron detector's dead-time was estimated using a combination of subcritical assembly measurements and MCNP simulations. Next, a multitude of fission products were identified as candidates for burnup and spent fuel analysis of irradiated mixed oxide fuel. The best isotopes for these applications were identified by investigating half-life, photon energy, fission yield, branching ratios, production modes, thermal neutron absorption cross section and fuel matrix diffusivity. 132I and 97Nb were identified as good candidates for MOX fuel on-line burnup analysis. In the second, and most important, part of this work, the feasibility of utilizing ThMOX fuel in a pressurized water reactor (PWR) was first examined under steady-state, beginning of life conditions. Using a three-dimensional MCNP model of a Westinghouse-type 17x17 PWR, several fuel compositions and configurations of a one-third ThMOX core were compared to a 100% UO2 core. A blanket-type arrangement of 5.5 wt% PuO2 was determined to be the best candidate for further analysis. Next, the safety of the ThMOX configuration was evaluated through three cycles of burnup at several using the following metrics: axial and radial nuclear hot channel factors, moderator and fuel temperature coefficients, delayed neutron fraction, and shutdown margin. Additionally, the performance of the ThMOX configuration was assessed by tracking cycle length, plutonium destroyed, and fission product poison concentration.

  20. Canopy Fuel Load Mapping of Mediterranean Pine Sites Based on Individual Tree-Crown Delineation

    Directory of Open Access Journals (Sweden)

    Giorgos Mallinis

    2013-12-01

    Full Text Available This study presents an individual tree-crown-based approach for canopy fuel load estimation and mapping in two Mediterranean pine stands. Based on destructive sampling, an allometric equation was developed for the estimation of crown fuel weight considering only pine crown width, a tree characteristic that can be estimated from passive imagery. Two high resolution images were used originally for discriminating Aleppo and Calabrian pines crown regions through a geographic object based image analysis approach. Subsequently, the crown region images were segmented using a watershed segmentation algorithm and crown width was extracted. The overall accuracy of the tree crown isolation expressed through a perfect match between the reference and the delineated crowns was 34.00% for the Kassandra site and 48.11% for the Thessaloniki site, while the coefficient of determination between the ground measured and the satellite extracted crown width was 0.5. Canopy fuel load values estimated in the current study presented mean values from 1.29 ± 0.6 to 1.65 ± 0.7 kg/m2 similar to other conifers worldwide. Despite the modest accuracies attained in this first study of individual tree crown fuel load mapping, the combination of the allometric equations with satellite-based extracted crown width information, can contribute to the spatially explicit mapping of canopy fuel load in Mediterranean areas. These maps can be used among others in fire behavior prediction, in fuel reduction treatments prioritization and during active fire suppression.

  1. Cluster Analysis of Indonesian Province Based on Household Primary Cooking Fuel Using K-Means

    Science.gov (United States)

    Huda, S. N.

    2017-03-01

    Each household definitely provides installations for cooking. Kerosene, which is refined from petroleum products once dominated types of primary fuel for cooking in Indonesia, whereas kerosene has an expensive cost and small efficiency. Other household use LPG as their primary cooking fuel. However, LPG supply is also limited. In addition, with a very diverse environments and cultures in Indonesia led to diversity of the installation type of cooking, such as wood-burning stove brazier. The government is also promoting alternative fuels, such as charcoal briquettes, and fuel from biomass. The use of other fuels is part of the diversification of energy that is expected to reduce community dependence on petroleum-based fuels. The use of various fuels in cooking that vary from one region to another reflects the distribution of fuel basic use by household. By knowing the characteristics of each province, the government can take appropriate policies to each province according each character. Therefore, it would be very good if there exist a cluster analysis of all provinces in Indonesia based on the type of primary cooking fuel in household. Cluster analysis is done using K-Means method with K ranging from 2-5. Cluster results are validated using Silhouette Coefficient (SC). The results show that the highest SC achieved from K = 2 with SC value 0.39135818388151. Two clusters reflect provinces in Indonesia, one is a cluster of more traditional provinces and the other is a cluster of more modern provinces. The cluster results are then shown in a map using Google Map API.

  2. NEUTRONICS STUDIES OF URANIUM-BASED FULLY CERAMIC MICRO-ENCAPSULATED FUEL FOR PWRs

    Energy Technology Data Exchange (ETDEWEB)

    George, Nathan M [ORNL; Maldonado, G Ivan [ORNL; Terrani, Kurt A [ORNL; Gehin, Jess C [ORNL; Godfrey, Andrew T [ORNL

    2012-01-01

    This study evaluates the core neutronics and fuel cycle characteristics that result from employing uranium-based fully ceramic micro-encapsulated (FCM) fuel in a pressurized water reactor (PWR). Specific PWR bundle designs with FCM fuel have been developed, which by virtue of their TRISO particle based elements, are expected to safely reach higher fuel burnups while also increasing the tolerance to fuel failures. The SCALE 6.1 code package, developed and maintained at ORNL, was the primary software employed to model these designs. Analysis was performed using the SCALE double-heterogeneous (DH) fuel modeling capabilities. For cases evaluated with the NESTLE full-core three-dimensional nodal simulator, because the feature to perform DH lattice physics branches with the SCALE/TRITON sequence is not yet available, the Reactivity-Equivalent Physical Transformation (RPT) method was used as workaround to support the full core analyses. As part of the fuel assembly design evaluations, fresh feed lattices were modeled to analyze the within-assembly pin power peaking. Also, a color-set array of assemblies was constructed to evaluate power peaking and power sharing between a once-burned and a fresh feed assembly. In addition, a parametric study was performed by varying the various TRISO particle design features; such as kernel diameter, coating layer thicknesses, and packing fractions. Also, other features such as the selection of matrix material (SiC, Zirconium) and fuel rod dimensions were perturbed. After evaluating different uranium-based fuels, the higher physical density of uranium mononitride (UN) proved to be favorable, as the parametric studies showed that the FCM particle fuel design will need roughly 12% additional fissile material in comparison to that of a standard UO2 rod in order to match the lifetime of an 18-month PWR cycle. Neutronically, the FCM fuel designs evaluated maintain acceptable design features in the areas of fuel lifetime, temperature

  3. Life Cycle GHG of NG-Based Fuel and Electric Vehicle in China

    Directory of Open Access Journals (Sweden)

    Qian Zhang

    2013-05-01

    Full Text Available This paper compares the greenhouse gas (GHG emissions of natural gas (NG- based fuels to the GHG emissions of electric vehicles (EVs powered with NG-to-electricity in China. A life-cycle model is used to account for full fuel cycle and use-phase emissions, as well as vehicle cycle and battery manufacturing. The reduction of life-cycle GHG emissions of EVs charged by electricity generated from NG, without utilizing carbon dioxide capture and storage (CCS technology can be 36%–47% when compared to gasoline vehicles. The large range change in emissions reduction potential is driven by the different generation technologies that could in the future be used to generate electricity in China. When CCS is employed in power plants, the GHG emission reductions increase to about 71%–73% compared to gasoline vehicles. It is found that compressed NG (CNG and liquefied NG (LNG fuels can save about 10% of carbon as compared to gasoline vehicles. However, gas-to-liquid (GTL fuel made through the Fischer-Tropsch method will likely lead to a life-cycle GHG emissions increase, potentially 3%–15% higher than gasoline, but roughly equal to petroleum-based diesel. When CCS is utilized, the GTL fueled vehicles emit roughly equal GHG emissions to petroleum-based diesel fuel high-efficient hybrid electric vehicle from the life-cycle perspective.

  4. Allocation of Energy Use in the Biomass-based Fuel Ethanol System and Its Use in Decision Making

    Institute of Scientific and Technical Information of China (English)

    LENG Ru-bo; YU Sui-ran; FANG Fang; DAI Du; WANG Cheng-tao

    2005-01-01

    The Chinese government is developing biomass ethanol as one of its automobile fuels for energy security and environmental improvement reasons. The energy efficiency of the biomass-based fuel ethanol is critical issue. To investigate the energy use in the three biomass-base ethanol fuel systems, energy content approach, Market value approach and Product displacement approach methods were used to allocate the energy use based on life cycle energy assessment. The results shows that the net energy of corn based, wheat based, and cassava-based ethanol fuel are 12543MJ, 10299MJ and 13112MJ when get one ton biomassbased ethanol, respectively, and they do produce positive net energy.

  5. Numerical modeling of oxides of nitrogen based on density of biodiesel fuels

    Directory of Open Access Journals (Sweden)

    A. Gopinath, Sukumar Puhan, G. Nagarajan

    2010-03-01

    Full Text Available Biodiesel is an alternative fuel derived from vegetable oils or animal fats. Research has shown that biodiesel fueled engines produce lesser carbon monoxide, unburned hydrocarbon, and particulate emissions compared to mineral based diesel fuel but emit higher oxides of nitrogen (NOx emissions. NOx could be strongly correlated with density or cetane number of a fuel. The objective of the present work is to predict the NOx concentration of a neat biodiesel fueled compression ignition engine from the density of biodiesel fuels using regression model. Experiments were conducted at different engine loads and the results were given as inputs to develop the regression model. A single cylinder, four stroke, constant speed, air cooled, direct injection diesel engine was used for the experiments. Five different biodiesel fuels were used and NOx were measured at different engine loads. The NOx concentration was taken as response (dependent variable and the density values were taken as explanatory (independent variables. The regression model has yielded R2 values between 0.918 and 0.995. The maximum prediction error was found to be 3.01 %.

  6. Fuel lattice design in a boiling water reactor using a knowledge-based automation system

    Energy Technology Data Exchange (ETDEWEB)

    Tung, Wu-Hsiung, E-mail: wstong@iner.gov.tw; Lee, Tien-Tso; Kuo, Weng-Sheng; Yaur, Shung-Jung

    2015-11-15

    Highlights: • An automation system was developed for the fuel lattice radial design of BWRs. • An enrichment group peaking equalizing method is applied to optimize the design. • Several heuristic rules and restrictions are incorporated to facilitate the design. • The CPU time for the system to design a 10x10 lattice was less than 1.2 h. • The beginning-of-life LPF was improved from 1.319 to 1.272 for one of the cases. - Abstract: A knowledge-based fuel lattice design automation system for BWRs is developed and applied to the design of 10 × 10 fuel lattices. The knowledge implemented in this fuel lattice design automation system includes the determination of gadolinium fuel pin location, the determination of fuel pin enrichment and enrichment distribution. The optimization process starts by determining the gadolinium distribution based on the pin power distribution of a flat enrichment lattice and some heuristic rules. Next, a pin power distribution flattening and an enrichment grouping process are introduced to determine the enrichment of each fuel pin enrichment type and the initial enrichment distribution of a fuel lattice design. Finally, enrichment group peaking equalizing processes are performed to achieve lower lattice peaking. Several fuel lattice design constraints are also incorporated in the automation system such that the system can accomplish a design which meets the requirements of practical use. Depending on the axial position of the lattice, a different method is applied in the design of the fuel lattice. Two typical fuel lattices with U{sup 235} enrichment of 4.471% and 4.386% were taken as references. Application of the method demonstrates that improved lattice designs can be achieved through the enrichment grouping and the enrichment group peaking equalizing method. It takes about 11 min and 1 h 11 min of CPU time for the automation system to accomplish two design cases on an HP-8000 workstation, including the execution of CASMO-4

  7. Fuel level sensor based on polymer optical fiber Bragg gratings for aircraft applications

    Science.gov (United States)

    Marques, C. A. F.; Pospori, A.; Sáez-Rodríguez, D.; Nielsen, K.; Bang, O.; Webb, D. J.

    2016-04-01

    Safety in civil aviation is increasingly important due to the increase in flight routes and their more challenging nature. Like other important systems in aircraft, fuel level monitoring is always a technical challenge. The most frequently used level sensors in aircraft fuel systems are based on capacitive, ultrasonic and electric techniques, however they suffer from intrinsic safety concerns in explosive environments combined with issues relating to reliability and maintainability. In the last few years, optical fiber liquid level sensors (OFLLSs) have been reported to be safe and reliable and present many advantages for aircraft fuel measurement. Different OFLLSs have been developed, such as the pressure type, float type, optical radar type, TIR type and side-leaking type. Amongst these, many types of OFLLSs based on fiber gratings have been demonstrated. However, these sensors have not been commercialized because they exhibit some drawbacks: low sensitivity, limited range, long-term instability, or limited resolution. In addition, any sensors that involve direct interaction of the optical field with the fuel (either by launching light into the fuel tank or via the evanescent field of a fiber-guided mode) must be able to cope with the potential build up of contamination - often bacterial - on the optical surface. In this paper, a fuel level sensor based on microstructured polymer optical fiber Bragg gratings (mPOFBGs), including poly (methyl methacrylate) (PMMA) and TOPAS fibers, embedded in diaphragms is investigated in detail. The mPOFBGs are embedded in two different types of diaphragms and their performance is investigated with aviation fuel for the first time, in contrast to our previous works, where water was used. Our new system exhibits a high performance when compared with other previously published in the literature, making it a potentially useful tool for aircraft fuel monitoring.

  8. Smart Energy Management and Control for Fuel Cell Based Micro-Grid Connected Neighborhoods

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Mohammad S. Alam

    2006-03-15

    Fuel cell power generation promises to be an efficient, pollution-free, reliable power source in both large scale and small scale, remote applications. DOE formed the Solid State Energy Conversion Alliance with the intention of breaking one of the last barriers remaining for cost effective fuel cell power generation. The Alliance’s goal is to produce a core solid-state fuel cell module at a cost of no more than $400 per kilowatt and ready for commercial application by 2010. With their inherently high, 60-70% conversion efficiencies, significantly reduced carbon dioxide emissions, and negligible emissions of other pollutants, fuel cells will be the obvious choice for a broad variety of commercial and residential applications when their cost effectiveness is improved. In a research program funded by the Department of Energy, the research team has been investigating smart fuel cell-operated residential micro-grid communities. This research has focused on using smart control systems in conjunction with fuel cell power plants, with the goal to reduce energy consumption, reduce demand peaks and still meet the energy requirements of any household in a micro-grid community environment. In Phases I and II, a SEMaC was developed and extended to a micro-grid community. In addition, an optimal configuration was determined for a single fuel cell power plant supplying power to a ten-home micro-grid community. In Phase III, the plan is to expand this work to fuel cell based micro-grid connected neighborhoods (mini-grid). The economic implications of hydrogen cogeneration will be investigated. These efforts are consistent with DOE’s mission to decentralize domestic electric power generation and to accelerate the onset of the hydrogen economy. A major challenge facing the routine implementation and use of a fuel cell based mini-grid is the varying electrical demand of the individual micro-grids, and, therefore, analyzing these issues is vital. Efforts are needed to determine

  9. A fuel cell operating between room temperature and 250 C based on a new phosphoric acid based composite electrolyte

    Energy Technology Data Exchange (ETDEWEB)

    Lan, Rong [Department of Chemistry, Heriot-Watt University, Edinburgh EH14 4AS (United Kingdom); Xu, Xiaoxiang; Irvine, John T.S. [School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST (United Kingdom); Tao, Shanwen [Department of Chemistry, Heriot-Watt University, Edinburgh EH14 4AS (United Kingdom); School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST (United Kingdom)

    2010-10-15

    A phosphoric acid based composite material with core-shell microstructure has been developed to be used as a new electrolyte for fuel cells. A fuel cell based on this electrolyte can operate at room temperature indicating leaching of H{sub 3}PO{sub 4} with liquid water is insignificant at room temperature. This will help to improve the thermal cyclability of phosphoric acid based electrolyte to make it easier for practical use. The conductivity of this H{sub 3}PO{sub 4}-based electrolyte is stable at 250 C with addition of the hydrophilic inorganic compound BPO{sub 4} forming a core-shell microstructure which makes it possible to run a PAFC at a temperature above 200 C. The core-shell microstructure retains after the fuel cell measurements. A power density of 350 mW/cm{sup 2} for a H{sub 2}/O{sub 2} fuel cell has been achieved at 200 C. The increase in operating temperature does not have significant benefit to the performance of a H{sub 2}/O{sub 2} fuel cell. For the first time, a composite electrolyte material for phosphoric acid fuel cells which can operate in a wide range of temperature has been evaluated but certainly further investigation is required. (author)

  10. Model-Based Design of Energy Efficient Palladium Membrane Water Gas Shift Fuel Processors for PEM Fuel Cell Power Plants

    Science.gov (United States)

    Gummalla, Mallika; Vanderspurt, Thomas Henry; Emerson, Sean; She, Ying; Dardas, Zissis; Olsommer, Benoît

    An integrated, palladium alloy membrane Water-Gas Shift (WGS) reactor can significantly reduce the size, cost and complexity of a fuel processor for a Polymer Electrolyte Membrane fuel cell power system.

  11. The Hardware Implementation of Demonstrator Air Independent Electric Supply System Based on Pem Fuel Cell

    Directory of Open Access Journals (Sweden)

    Grzeczka G.

    2016-12-01

    Full Text Available The paper presents results of the research project whose the main goal was to build a technology demonstrator of an electric supply system based on the PEM fuel cell. The electric supply system is dedicated to operation on a board of a submarine during emergency situations. The underwater conditions influence on a specific architecture of supply subsystems of the PEM fuel cell system. In this case the fuel cell stack is supplied by both clean hydrogen and clean oxygen stored in pressurized tanks. The hydrogen has to be delivered in a closed loop, while the oxygen can be delivered in a closed or an open loop. In the technology demonstrator, the supply of the fuel cell stack by the hydrogen in the closed loop and the oxygen in the open loop with a precise control of its flow were used.

  12. Concept of development of nuclear power based on LMFBR operation in open nuclear fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Toshinsky, G.I. [Inst. of Physics and Power Engineering, Obninsk (Russian Federation)

    1996-08-01

    The preliminary assessments performed show that it is reasonable to investigate in the future the possibilities of FBR efficient operation with the open NFC. To improve its safety it is expedient to use the lead-bismuth alloy as a coolant. In order to operate with depleted uranium make-up it is necessary to meet a number of requirements providing the reactor criticality due to plutonium build-up and BR > 1. These requirements are as follows: a large core (20--25 m{sup 3}); a high fuel volume fraction (> 60%); utilization of dense metallic fuel; a high fuel burn-up--at a level of 20% of h.a. Making use of these reactors should allow the NP fuel base to be extended more than 10 times without making NFC closed. It provides improving NP safety during a sufficiently long stage of its development.

  13. A comprehensive review of PBI-based high temperature PEM fuel cells

    DEFF Research Database (Denmark)

    Simon Araya, Samuel; Zhou, Fan; Liso, Vincenzo;

    2016-01-01

    The current status on the understanding of the various operational aspects of high temperature proton exchange membrane fuel cells (HT-PEMFC) has been summarized. The paper focuses on phosphoric acid-doped polybenzimidazole (PBI)-based HT-PEMFCs and an overview of the common practices...... are outlined. Catalyst degradation and electrolyte loss take place at higher rates in the beginning of life of the fuel cell. This is due to the smaller size of Pt particles and the presence of excess phosphoric acid in the beginning of life that favor the respective degradation. Therefore, the redistribution...... of phosphoric acid in the membrane and the electrodes is crucial for the proper activation of the fuel cell, and a startup procedure should take this into account in order to avoid beginning of life degradation. On-line monitoring of the fuel cell system's state of health using diagnostic tools can help detect...

  14. The development of agro-residue densified fuel in China based on energetics analysis.

    Science.gov (United States)

    Chen, Longjian; Xing, Li; Han, Lujia

    2010-05-01

    Agro-residue is one of the important biomass resources in China and its efficient utilization is crucial for providing bio-energy, releasing risk of environmental pollution, and enhancing rural incomes. Densification is one of the important utilization routes of agro-residues. The objective of this paper is to explore the development of agro-residue densified fuel in China based on energetics analysis. The energetical property and energy potential of main agro-residues in China were firstly analyzed and then the development of agro-residue densified fuel in every region was evaluated based on energetics analysis. The results show that the main agro-residues in China are good feedstocks as densified fuel and they constitute enormous energy potential for developing densified fuel. However, the situation of every region should be considered for the development of agro-residue densified fuel. The primary energy embodied per unit of useful energy indicates that most of the regions in China are suitable for developing agro-residue densified fuel as it is energetically advantageous compared with coal, whereas only about 25% of regions near coal production locations are not suitable as they are less energetically advantageous.

  15. Experimental investigation of paraffin-based fuels for hybrid rocket propulsion

    Science.gov (United States)

    Galfetti, L.; Merotto, L.; Boiocchi, M.; Maggi, F.; DeLuca, L. T.

    2013-03-01

    Solid fuels for hybrid rockets were characterized in the framework of a research project aimed to develop a new generation of solid fuels, combining at the same time good mechanical and ballistic properties. Original techniques were implemented in order to improve paraffin-based fuels. The first strengthening technique involves the use of a polyurethane foam (PUF); a second technique is based on thermoplastic polymers mixed at molecular level with the paraffin binder. A ballistic characterization of paraffin-based hybrid rocket solid fuels was performed, considering pure wax-based fuels and fuels doped with suitable metal additives. Nano-Al powders and metal hydrides (magnesium hydride (MgH2), lithium aluminum hydride (LiAlH4 )) were used as fillers in paraffin matrices. The results of this investigation show a strong correlation between the measured viscosity of the melted paraffin layer and the regression rate: a decrease of viscosity increases the regression rate. This trend is due to the increasing development of entrainment phenomena, which strongly increase the regression rate. Addition of LiAlH4 (mass fraction 10%) can further increase the regression rate up to 378% with respect to the pure HTPB regression rate, taken as baseline reference fuel. The highest regression rates were found for the Solid Wax (SW) composition, added with 5% MgH2 mass fraction; at 350 kg/(m2s) oxygen mass flux, the measured regression rate, averaged in space and time, was 2.5 mm/s, which is approximately five times higher than that of the pure HTPB composition. Compositions added with nanosized aluminum powders were compared with those added with MgH2, using gel or solid wax.

  16. 40 CFR 600.207-08 - Calculation and use of vehicle-specific 5-cycle-based fuel economy values for vehicle...

    Science.gov (United States)

    2010-07-01

    .... (b) If only one equivalent petroleum-based fuel economy value exists for an electric configuration...-cycle fuel economy for that configuration. (c) If more than one equivalent petroleum-based 5-cycle fuel...-specific 5-cycle-based fuel economy values for vehicle configurations. 600.207-08 Section...

  17. Performance Analyses of Renewable and Fuel Power Supply Systems for Different Base Station Sites

    Directory of Open Access Journals (Sweden)

    Josip Lorincz

    2014-11-01

    Full Text Available Base station sites (BSSs powered with renewable energy sources have gained the attention of cellular operators during the last few years. This is because such “green” BSSs impose significant reductions in the operational expenditures (OPEX of telecom operators due to the possibility of on-site renewable energy harvesting. In this paper, the green BSSs power supply system parameters detected through remote and centralized real time sensing are presented. An implemented sensing system based on a wireless sensor network enables reliable collection and post-processing analyses of many parameters, such as: total charging/discharging current of power supply system, battery voltage and temperature, wind speed, etc. As an example, yearly sensing results for three different BSS configurations powered by solar and/or wind energy are discussed in terms of renewable energy supply (RES system performance. In the case of powering those BSS with standalone systems based on a fuel generator, the fuel consumption models expressing interdependence among the generator load and fuel consumption are proposed. This has allowed energy-efficiency comparison of the fuel powered and RES systems, which is presented in terms of the OPEX and carbon dioxide (CO2 reductions. Additionally, approaches based on different BSS air-conditioning systems and the on/off regulation of a daily fuel generator activity are proposed and validated in terms of energy and capital expenditure (CAPEX savings.

  18. Advanced Materials for PEM-Based Fuel Cell Systems

    Energy Technology Data Exchange (ETDEWEB)

    James E. McGrath

    2005-10-26

    Proton exchange membrane fuel cells (PEMFCs) are quickly becoming attractive alternative energy sources for transportation, stationary power, and small electronics due to the increasing cost and environmental hazards of traditional fossil fuels. Two main classes of PEMFCs include hydrogen/air or hydrogen/oxygen fuel cells and direct methanol fuel cells (DMFCs). The current benchmark membrane for both types of PEMFCs is Nafion, a perfluorinated sulfonated copolymer made by DuPont. Nafion copolymers exhibit good thermal and chemical stability, as well as very high proton conductivity under hydrated conditions at temperatures below 80 °C. However, application of these membranes is limited due to their high methanol permeability and loss of conductivity at high temperatures and low relative humidities. These deficiencies have led to the search for improved materials for proton exchange membranes. Potential PEMs should have good thermal, hydrolytic, and oxidative stability, high proton conductivity, selective permeability, and mechanical durability over long periods of time. Poly(arylene ether)s, polyimides, polybenzimidazoles, and polyphenylenes are among the most widely investigated candidates for PEMs. Poly(arylene ether)s are a promising class of proton exchange membranes due to their excellent thermal and chemical stability and high glass transition temperatures. High proton conductivity can be achieved through post-sulfonation of poly(arylene ether) materials, but this most often results in very high water sorption or even water solubility. Our research has shown that directly polymerized poly(arylene ether) copolymers show important advantages over traditional post-sulfonated systems and also address the concerns with Nafion membranes. These properties were evaluated and correlated with morphology, structure-property relationships, and

  19. Advanced Materials for PEM-Based Fuel Cell Systems

    Energy Technology Data Exchange (ETDEWEB)

    James E. McGrath; Donald G. Baird; Michael von Spakovsky

    2005-10-26

    Proton exchange membrane fuel cells (PEMFCs) are quickly becoming attractive alternative energy sources for transportation, stationary power, and small electronics due to the increasing cost and environmental hazards of traditional fossil fuels. Two main classes of PEMFCs include hydrogen/air or hydrogen/oxygen fuel cells and direct methanol fuel cells (DMFCs). The current benchmark membrane for both types of PEMFCs is Nafion, a perfluorinated sulfonated copolymer made by DuPont. Nafion copolymers exhibit good thermal and chemical stability, as well as very high proton conductivity under hydrated conditions at temperatures below 80 degrees C. However, application of these membranes is limited due to their high methanol permeability and loss of conductivity at high temperatures and low relative humidities. These deficiencies have led to the search for improved materials for proton exchange membranes. Potential PEMs should have good thermal, hydrolytic, and oxidative stability, high proton conductivity, selective permeability, and mechanical durability over long periods of time. Poly(arylene ether)s, polyimides, polybenzimidazoles, and polyphenylenes are among the most widely investigated candidates for PEMs. Poly(arylene ether)s are a promising class of proton exchange membranes due to their excellent thermal and chemical stability and high glass transition temperatures. High proton conductivity can be achieved through post-sulfonation of poly(arylene ether) materials, but this most often results in very high water sorption or even water solubility. Our research has shown that directly polymerized poly(arylene ether) copolymers show important advantages over traditional post-sulfonated systems and also address the concerns with Nafion membranes. These properties were evaluated and correlated with morphology, structure-property relationships, and states of water in the membranes. Further improvements in properties were achieved through incorporation of inorganic

  20. High power fuel cell simulator based on artificial neural network

    Energy Technology Data Exchange (ETDEWEB)

    Chavez-Ramirez, Abraham U.; Munoz-Guerrero, Roberto [Departamento de Ingenieria Electrica, CINVESTAV-IPN. Av. Instituto Politecnico Nacional No. 2508, D.F. CP 07360 (Mexico); Duron-Torres, S.M. [Unidad Academica de Ciencias Quimicas, Universidad Autonoma de Zacatecas, Campus Siglo XXI, Edif. 6 (Mexico); Ferraro, M.; Brunaccini, G.; Sergi, F.; Antonucci, V. [CNR-ITAE, Via Salita S. Lucia sopra Contesse 5-98126 Messina (Italy); Arriaga, L.G. [Centro de Investigacion y Desarrollo Tecnologico en Electroquimica S.C., Parque Tecnologico Queretaro, Sanfandila, Pedro Escobedo, Queretaro (Mexico)

    2010-11-15

    Artificial Neural Network (ANN) has become a powerful modeling tool for predicting the performance of complex systems with no well-known variable relationships due to the inherent properties. A commercial Polymeric Electrolyte Membrane fuel cell (PEMFC) stack (5 kW) was modeled successfully using this tool, increasing the number of test into the 7 inputs - 2 outputs-dimensional spaces in the shortest time, acquiring only a small amount of experimental data. Some parameters could not be measured easily on the real system in experimental tests; however, by receiving the data from PEMFC, the ANN could be trained to learn the internal relationships that govern this system, and predict its behavior without any physical equations. Confident accuracy was achieved in this work making possible to import this tool to complex systems and applications. (author)

  1. Performance of the Salt Bridge Based Microbial Fuel Cell

    Directory of Open Access Journals (Sweden)

    Maksudur R. Khan

    2012-04-01

    Full Text Available Electricity generation from readily biodegradable organic substrates accompanied by decolorization of azo dye was investigated using a Microbial fuel cell (MFC. Biodegradation was the dominant mechanism of the dye removal, and glucose was the optimal substrate for Red Cibacron-2G (RC decolorization. Batch experiments were conducted to evaluate the performance of the MFC.  As compared to traditional anaerobic technology higher decolorization efficiency was achieved by MFC. Effect of initial dye concentration and external resistance on power generation were studied. Polarization experiments were also directed to find the maximum power density. Maximum Power density of 100mW/m2 (1.04A/m2 was recorded at optimum operating conditions.

  2. Substrates and pathway of electricity generation in a nitrification-based microbial fuel cell.

    Science.gov (United States)

    Chen, Hui; Zheng, Ping; Zhang, Jiqiang; Xie, Zuofu; Ji, Junyuan; Ghulam, Abbas

    2014-06-01

    Nitrification-based microbial fuel cell (N-MFC) is a novel inorganic microbial fuel cell based on nitrification in the anode compartment. So far, little information is available on the substrates and pathway of N-MFC. The results of this study indicated that apart from the primary nitrification substrate (ammonium), the intermediates (hydroxylamine and nitrite) could also serve as anodic fuel to generate current, and the end product nitrate showed an inhibitory effect on electricity generation. Based on the research, a pathway of electricity generation was proposed for N-MFC: ammonium was oxidized first to nitrite by ammonia-oxidizing bacteria (AOB), then the nitrite in anolyte and the potassium permanganate in catholyte constituted a chemical cell to generate current. In other words, the electricity generation in N-MFC was not only supported by microbial reaction as we expected, but both biological and electrochemical reactions contributed.

  3. Decision-making of biomass ethanol fuel policy based on life cycle 3E assessment

    Institute of Scientific and Technical Information of China (English)

    LENG Ru-bo; DAI Du; CHEN Xiao-jun; WANG Cheng-tao

    2005-01-01

    To evaluate the environmental, economic, energy performance of biomass ethanol fuel in China and tosupport the decision-making of biomass ethanol energy policy, an assessment method of life cycle 3E (economy, en vironment, energy) was applied to the three biomass ethanol fuel cycle alternatives, which includes cassava-based, corn-based and wheat-based ethanol fuel. The assessments provide a comparison of the economical performance, energy efficiency and environmental impacts of the three alternatives. And the development potential of the three alternatives in China was examined. The results are very useful for the Chinese government to make decisions on the biomass ethanol energy policy, and some advises for the decision-making of Chinese government were given.

  4. The combustion properties analysis of various liquid fuels based on crude oil and renewables

    Science.gov (United States)

    Grab-Rogalinski, K.; Szwaja, S.

    2016-09-01

    The paper presents results of investigation on combustion properties analysis of hydrocarbon based liquid fuels commonly used in the CI engine. The analysis was performed with aid of the CRU (Combustion Research Unit). CRU is the machine consisted of a constant volume combustion chamber equipped with one or two fuel injectors and a pressure sensor. Fuel can be injected under various both injection pressure and injection duration, also with two injector versions two stage combustion with pilot injection can be simulated, that makes it possible to introduce and modify additional parameter which is injection delay (defined as the time between pilot and main injection). On a basis of this investigation such combustion parameters as pressure increase, rate of heat release, ignition delay and combustion duration can be determined. The research was performed for the four fuels as follows: LFO, HFO, Biofuel from rape seeds and Glycerol under various injection parameters as well as combustion chamber thermodynamic conditions. Under these tests the change in such injection parameters as injection pressure, use of pilot injection, injection delay and injection duration, for main injection, were made. Moreover, fuels were tested under different conditions of load, what was determined by initial conditions (pressure and temperature) in the combustion chamber. Stored data from research allows to compare combustion parameters for fuels applied to tests and show this comparison in diagrams.

  5. Continuous energy Monte Carlo calculations for randomly distributed spherical fuels based on statistical geometry model

    Energy Technology Data Exchange (ETDEWEB)

    Murata, Isao [Osaka Univ., Suita (Japan); Mori, Takamasa; Nakagawa, Masayuki; Itakura, Hirofumi

    1996-03-01

    The method to calculate neutronics parameters of a core composed of randomly distributed spherical fuels has been developed based on a statistical geometry model with a continuous energy Monte Carlo method. This method was implemented in a general purpose Monte Carlo code MCNP, and a new code MCNP-CFP had been developed. This paper describes the model and method how to use it and the validation results. In the Monte Carlo calculation, the location of a spherical fuel is sampled probabilistically along the particle flight path from the spatial probability distribution of spherical fuels, called nearest neighbor distribution (NND). This sampling method was validated through the following two comparisons: (1) Calculations of inventory of coated fuel particles (CFPs) in a fuel compact by both track length estimator and direct evaluation method, and (2) Criticality calculations for ordered packed geometries. This method was also confined by applying to an analysis of the critical assembly experiment at VHTRC. The method established in the present study is quite unique so as to a probabilistic model of the geometry with a great number of spherical fuels distributed randomly. Realizing the speed-up by vector or parallel computations in future, it is expected to be widely used in calculation of a nuclear reactor core, especially HTGR cores. (author).

  6. Upward revision of global fossil fuel methane emissions based on isotope database

    Science.gov (United States)

    Schwietzke, Stefan; Sherwood, Owen A.; Bruhwiler, Lori M. P.; Miller, John B.; Etiope, Giuseppe; Dlugokencky, Edward J.; Michel, Sylvia Englund; Arling, Victoria A.; Vaughn, Bruce H.; White, James W. C.; Tans, Pieter P.

    2016-10-01

    Methane has the second-largest global radiative forcing impact of anthropogenic greenhouse gases after carbon dioxide, but our understanding of the global atmospheric methane budget is incomplete. The global fossil fuel industry (production and usage of natural gas, oil and coal) is thought to contribute 15 to 22 per cent of methane emissions to the total atmospheric methane budget. However, questions remain regarding methane emission trends as a result of fossil fuel industrial activity and the contribution to total methane emissions of sources from the fossil fuel industry and from natural geological seepage, which are often co-located. Here we re-evaluate the global methane budget and the contribution of the fossil fuel industry to methane emissions based on long-term global methane and methane carbon isotope records. We compile the largest isotopic methane source signature database so far, including fossil fuel, microbial and biomass-burning methane emission sources. We find that total fossil fuel methane emissions (fossil fuel industry plus natural geological seepage) are not increasing over time, but are 60 to 110 per cent greater than current estimates owing to large revisions in isotope source signatures. We show that this is consistent with the observed global latitudinal methane gradient. After accounting for natural geological methane seepage, we find that methane emissions from natural gas, oil and coal production and their usage are 20 to 60 per cent greater than inventories. Our findings imply a greater potential for the fossil fuel industry to mitigate anthropogenic climate forcing, but we also find that methane emissions from natural gas as a fraction of production have declined from approximately 8 per cent to approximately 2 per cent over the past three decades.

  7. Upward revision of global fossil fuel methane emissions based on isotope database.

    Science.gov (United States)

    Schwietzke, Stefan; Sherwood, Owen A; Bruhwiler, Lori M P; Miller, John B; Etiope, Giuseppe; Dlugokencky, Edward J; Michel, Sylvia Englund; Arling, Victoria A; Vaughn, Bruce H; White, James W C; Tans, Pieter P

    2016-10-06

    Methane has the second-largest global radiative forcing impact of anthropogenic greenhouse gases after carbon dioxide, but our understanding of the global atmospheric methane budget is incomplete. The global fossil fuel industry (production and usage of natural gas, oil and coal) is thought to contribute 15 to 22 per cent of methane emissions to the total atmospheric methane budget. However, questions remain regarding methane emission trends as a result of fossil fuel industrial activity and the contribution to total methane emissions of sources from the fossil fuel industry and from natural geological seepage, which are often co-located. Here we re-evaluate the global methane budget and the contribution of the fossil fuel industry to methane emissions based on long-term global methane and methane carbon isotope records. We compile the largest isotopic methane source signature database so far, including fossil fuel, microbial and biomass-burning methane emission sources. We find that total fossil fuel methane emissions (fossil fuel industry plus natural geological seepage) are not increasing over time, but are 60 to 110 per cent greater than current estimates owing to large revisions in isotope source signatures. We show that this is consistent with the observed global latitudinal methane gradient. After accounting for natural geological methane seepage, we find that methane emissions from natural gas, oil and coal production and their usage are 20 to 60 per cent greater than inventories. Our findings imply a greater potential for the fossil fuel industry to mitigate anthropogenic climate forcing, but we also find that methane emissions from natural gas as a fraction of production have declined from approximately 8 per cent to approximately 2 per cent over the past three decades.

  8. Fuel Cell Power Model Version 2: Startup Guide, System Designs, and Case Studies. Modeling Electricity, Heat, and Hydrogen Generation from Fuel Cell-Based Distributed Energy Systems

    Energy Technology Data Exchange (ETDEWEB)

    Steward, D.; Penev, M.; Saur, G.; Becker, W.; Zuboy, J.

    2013-06-01

    This guide helps users get started with the U.S. Department of Energy/National Renewable Energy Laboratory Fuel Cell Power (FCPower) Model Version 2, which is a Microsoft Excel workbook that analyzes the technical and economic aspects of high-temperature fuel cell-based distributed energy systems with the aim of providing consistent, transparent, comparable results. This type of energy system would provide onsite-generated heat and electricity to large end users such as hospitals and office complexes. The hydrogen produced could be used for fueling vehicles or stored for later conversion to electricity.

  9. Statistical model for combustion of high-metal magnesium-based hydro-reactive fuel

    Institute of Scientific and Technical Information of China (English)

    Hu Jian-Xin; Han Chao; Xia Zhi-Xun; Huang Li-Ya; Huang Xu

    2012-01-01

    We investigate experimentally and analytically the combustion behavior of a high-metal magnesium-based hydro-reactive fuel under high temperature gaseous atmosphere.The fuel studied in this paper contains 73% magnesium powders.An experimental system is designed and experimeuts are carried out in both argon and water vapor atmospheres.It is found that the burning surface temperature of the fuel is higher in water vapor than that in argon and both of them are higher than the melting point of magnesium,which indicates the molten state of magnesium particles in the burning surface of the fuel.Based on physical considerations and experimental results,a mathematical one-dimensional model is formulated to describe the combustion behavior of the high-metal magnesium-based hydro-reactive fuel.The model enables the evaluation of the burning surface temperature,the burning rate and the flame standoff distance each as a function of chamber pressure and water vapor concentration.The results predicted by the model show that the burning rate and the surface temperature increase when the chamber pressure and the water vapor concentration increase,which are in agreement with the observed experimental trends.

  10. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 17, April--June 1993

    Energy Technology Data Exchange (ETDEWEB)

    Chow, O.K.; Nsakala, N.Y.

    1993-08-01

    Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. During the third quarter of 1993, the following technical progress was made: Completed modeling calculations of coal mineral matter transformations, deposition behavior, and heat transfer impacts of six test fuels; and ran pilot-scale tests of Upper Freeport feed coal, microagglomerate product, and mulled product.

  11. Feasibility of Producing and Using Biomass-Based Diesel and Jet Fuel in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Milbrandt, A. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Kinchin, C. [National Renewable Energy Lab. (NREL), Golden, CO (United States); McCormick, R. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2013-12-01

    The study summarizes the best available public data on the production, capacity, cost, market demand, and feedstock availability for the production of biomass-based diesel and jet fuel. It includes an overview of the current conversion processes and current state-of-development for the production of biomass-based jet and diesel fuel, as well as the key companies pursuing this effort. Thediscussion analyzes all this information in the context of meeting the RFS mandate, highlights uncertainties for the future industry development, and key business opportunities.

  12. Development of nuclear fuel cycle technologies - bases of long-term provision of fuel and environmental safety of nuclear power

    Energy Technology Data Exchange (ETDEWEB)

    Solonin, M.I.; Polyakov, A.S.; Zakharkin, B.S.; Smelov, V.S.; Nenarokomov, E.A.; Mukhin, I.V. [SSC, RF, A.A. Bochvar ALL-Russia Research Institute of Inorganic Materials, Moscow (Russian Federation)

    2000-07-01

    To-day nuclear power is one of the options, however, to-morrow it may become the main source of the energy, thus, providing for the stable economic development for the long time to come. The availability of the large-scale nuclear power in the foreseeable future is governed by not only the safe operation of nuclear power plants (NPP) but also by the environmentally safe management of spent nuclear fuel, radioactive waste conditioning and long-term storage. More emphasis is to be placed to the closing of the fuel cycle in view of substantial quantities of spent nuclear fuel arisings. The once-through fuel cycle that is cost effective at the moment cannot be considered to be environmentally safe even for the middle term since the substantial build-up of spent nuclear fuel containing thousands of tons Pu will require the resolution of the safe management problem in the nearest future and is absolutely unjustified in terms of moral ethics as a transfer of the responsibility to future generations. The minimization of radioactive waste arisings and its radioactivity is only feasible with the closed fuel cycle put into practice and some actinides and long-lived fission radionuclides burnt out. The key issues in providing the environmentally safe fuel cycle are efficient processes of producing fuel for NPP, radionuclide after-burning included, a long-term spent nuclear fuel storage and reprocessing as well as radioactive waste management. The paper deals with the problems inherent in producing fuel for NPP with a view for the closed fuel cycle. Also discussed are options of the fuel cycle, its effectiveness and environmental safety with improvements in technologies of spent nuclear fuel reprocessing and long-lived radionuclide partitioning. (authors)

  13. Direct methane solid oxide fuel cells based on catalytic partial oxidation enabling complete coking tolerance of Ni-based anodes

    Science.gov (United States)

    Lee, Daehee; Myung, Jaeha; Tan, Jeiwan; Hyun, Sang-Hoon; Irvine, John T. S.; Kim, Joosun; Moon, Jooho

    2017-03-01

    Solid oxide fuel cells (SOFCs) can oxidize diverse fuels by harnessing oxygen ions. Benefited by this feature, direct utilization of hydrocarbon fuels without external reformers allows for cost-effective realization of SOFC systems. Superior hydrocarbon reforming catalysts such as nickel are required for this application. However, carbon coking on nickel-based anodes and the low efficiency associated with hydrocarbon fueling relegate these systems to immature technologies. Herein, we present methane-fueled SOFCs operated under conditions of catalytic partial oxidation (CPOX). Utilizing CPOX eliminates carbon coking on Ni and facilitates the oxidation of methane. Ni-gadolinium-doped ceria (GDC) anode-based cells exhibit exceptional power densities of 1.35 W cm-2 at 650 °C and 0.74 W cm-2 at 550 °C, with stable operation over 500 h, while the similarly prepared Ni-yttria stabilized zirconia anode-based cells exhibit a power density of 0.27 W cm-2 at 650 °C, showing gradual degradation. Chemical analyses suggest that combining GDC with the Ni anode prevents the oxidation of Ni due to the oxygen exchange ability of GDC. In addition, CPOX operation allows the usage of stainless steel current collectors. Our results demonstrate that high-performance SOFCs utilizing methane CPOX can be realized without deterioration of Ni-based anodes using cost-effective current collectors.

  14. Iron-based perovskite cathodes for solid oxide fuel cells

    Science.gov (United States)

    Ralph, James M.; Rossignol, Cecile C.R.; Vaughey, John T.

    2007-01-02

    An A and/or A' site deficient perovskite of general formula of (A.sub.1-xA'.sub.x).sub.1-yFeO.sub.3-.delta. or of general formula A.sub.1-x-yA'.sub.xFeO.sub.3-67, wherein A is La alone or with one or more of the rare earth metals or a rare earth metal other than Ce alone or a combination of rare earth metals and X is in the range of from 0 to about 1; A' is Sr or Ca or mixtures thereof and Y is in the range of from about 0.01 to about 0.3; .delta. represents the amount of compensating oxygen loss. If either A or A' is zero the remaining A or A' is deficient. A fuel cell incorporating the inventive perovskite as a cathode is disclosed as well as an oxygen separation membrane. The inventive perovskite is preferably single phase.

  15. Reprocessability of molybdenum and magnesia based inert matrix fuels

    Directory of Open Access Journals (Sweden)

    Ebert Elena L.

    2015-12-01

    Full Text Available This work focuses on the reprocessability of metallic 92Mo and ceramic MgO, which is under investigation for (Pu,MA-oxide (MA = minor actinide fuel within a metallic 92Mo matrix (CERMET and a ceramic MgO matrix (CERCER. Magnesium oxide and molybdenum reference samples have been fabricated by powder metallurgy. The dissolution of the matrices was studied as a function of HNO3 concentration (1-7 mol/L and temperature (25-90°C. The rate of dissolution of magnesium oxide and metallic molybdenum increased with temperature. While the MgO rate was independent of the acid concentration (1-7 mol/L, the rate of dissolution of Mo increased with acid concentration. However, the dissolution of Mo at high temperatures and nitric acid concentrations was accompanied by precipitation of MoO3. The extraction of uranium, americium, and europium in the presence of macro amounts of Mo and Mg was studied by three different extraction agents: tri-n-butylphosphate (TBP, N,Nʹ-dimethyl-N,Nʹ-dioctylhexylethoxymalonamide (DMDOHEMA, and N,N,N’,N’- -tetraoctyldiglycolamide (TODGA. With TBP no extraction of Mo and Mg occurred. Both matrix materials are partly extracted by DMDOHEMA. Magnesium is not extracted by TODGA (D < 0.1, but a weak extraction of Mo is observed at low Mo concentration.

  16. Fuel level sensor based on polymer optical fiber Bragg gratings for aircraft applications

    DEFF Research Database (Denmark)

    Marques, C. A. F.; Pospori, A.; Sáez-Rodríguez, D.

    2016-01-01

    Safety in civil aviation is increasingly important due to the increase in flight routes and their more challenging nature. Like other important systems in aircraft, fuel level monitoring is always a technical challenge. The most frequently used level sensors in aircraft fuel systems are based...... on capacitive, ultrasonic and electric techniques, however they suffer from intrinsic safety concerns in explosive environments combined with issues relating to reliability and maintainability. In the last few years, optical fiber liquid level sensors (OFLLSs) have been reported to be safe and reliable...... and present many advantages for aircraft fuel measurement. Different OFLLSs have been developed, such as the pressure type, float type, optical radar type, TIR type and side-leaking type. Amongst these, many types of OFLLSs based on fiber gratings have been demonstrated. However, these sensors have not been...

  17. Metal hydride and pyrophoric fuel additives for dicyclopentadiene based hybrid propellants

    Science.gov (United States)

    Shark, Steven C.

    The purpose of this study is to investigate the use of reactive energetic fuel additives that have the potential to increase the combustion performance of hybrid rocket propellants in terms of solid fuel regression rate and combustion efficiency. Additives that can augment the combustion flame zone in a hybrid rocket motor by means of increased energy feedback to the fuel grain surface are of great interest. Metal hydrides have large volumetric hydrogen densities, which gives these materials high performance potential as fuel additives in terms of specifc impulse. The excess hydrogen and corresponding base metal may also cause an increase in the hybrid rocket solid fuel regression rate. Pyrophoric additives also have potential to increase the solid fuel regression rate by reacting more readily near the burning fuel surface providing rapid energy feedback. An experimental performance evaluation of metal hydride fuel additives for hybrid rocket motor propulsion systems is examined in this study. Hypergolic ignition droplet tests and an accelerated aging study revealed the protection capabilities of Dicyclopentadiene (DCPD) as a fuel binder, and the ability for unaided ignition. Static hybrid rocket motor experiments were conducted using DCPD as the fuel. Sodium borohydride (NabH4) and aluminum hydride (AlH3) were examined as fuel additives. Ninety percent rocket grade hydrogen peroxide (RGHP) was used as the oxidizer. In this study, the sensitivity of solid fuel regression rate and characteristic velocity (C*) efficiency to total fuel grain port mass flux and particle loading is examined. These results were compared to HTPB combustion performance as a baseline. Chamber pressure histories revealed steady motor operation in most tests, with reduced ignition delays when using NabH4 as a fuel additive. The addition of NabH4 and AlH3 produced up to a 47% and 85% increase in regression rate over neat DCPD, respectively. For all test conditions examined C* efficiency ranges

  18. Irradiation Performance of U-Mo Alloy Based ‘Monolithic’ Plate-Type Fuel – Design Selection

    Energy Technology Data Exchange (ETDEWEB)

    A. B. Robinson; G. S. Chang; D. D. Keiser, Jr.; D. M. Wachs; D. L. Porter

    2009-08-01

    A down-selection process has been applied to the U-Mo fuel alloy based monolithic plate fuel design, supported by irradiation testing of small fuel plates containing various design parameters. The irradiation testing provided data on fuel performance issues such as swelling, fuel-cladding interaction (interdiffusion), blister formation at elevated temperatures, and fuel/cladding bond quality and effectiveness. U-10Mo (wt%) was selected as the fuel alloy of choice, accepting a somewhat lower uranium density for the benefits of phase stability. U-7Mo could be used, with a barrier, where the trade-off for uranium density is critical to nuclear performance. A zirconium foil barrier between fuel and cladding was chosen to provide a predictable, well-bonded, fuel-cladding interface, allowing little or no fuel-cladding interaction. The fuel plate testing conducted to inform this selection was based on the use of U-10Mo foils fabricated by hot co-rolling with a Zr foil. The foils were subsequently bonded to Al-6061 cladding by hot isostatic pressing or friction stir bonding.

  19. Experimental evaluation of a Pt based heat exchanger methanol reformer for a HTPEM fuel cell

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Nielsen, Mads Pagh; Kær, Søren Knudsen

    2007-01-01

    .g. methanol. A hydrocarbon as methanol can be derived from e.g. biomass and be used directly in a PEM fuel cell, but with a poor performance and often complicated water management system. Another way of using methanol in a fuel cell is by steam reforming it over a catalyst to hydrogen : CH3OH+H2O CO2 + 3H......2. Included in this reaction is the decomposition of methanol, which produces CO : CH3OH CO + 2H2 , The CO can be removed by adding extra water to the gas by a water-gas-shift: CO + H2O CO2 + H2. The hydrogen can then be used in a fuel cell with a much better performance than the DMFC. Many...... Nafion based low temperature PEM fuel cells are intolerant to CO in the anode gas, and require very pure hydrogen with only up to 100 ppm CO or even lower. Another type of PEM fuel cells, the PBI based high temperature PEM operates at high temperatures (160-180oC), and has a much higher tolerance of CO...

  20. Radiation induced dissolution of UO 2 based nuclear fuel - A critical review of predictive modelling approaches

    Science.gov (United States)

    Eriksen, Trygve E.; Shoesmith, David W.; Jonsson, Mats

    2012-01-01

    Radiation induced dissolution of uranium dioxide (UO 2) nuclear fuel and the consequent release of radionuclides to intruding groundwater are key-processes in the safety analysis of future deep geological repositories for spent nuclear fuel. For several decades, these processes have been studied experimentally using both spent fuel and various types of simulated spent fuels. The latter have been employed since it is difficult to draw mechanistic conclusions from real spent nuclear fuel experiments. Several predictive modelling approaches have been developed over the last two decades. These models are largely based on experimental observations. In this work we have performed a critical review of the modelling approaches developed based on the large body of chemical and electrochemical experimental data. The main conclusions are: (1) the use of measured interfacial rate constants give results in generally good agreement with experimental results compared to simulations where homogeneous rate constants are used; (2) the use of spatial dose rate distributions is particularly important when simulating the behaviour over short time periods; and (3) the steady-state approach (the rate of oxidant consumption is equal to the rate of oxidant production) provides a simple but fairly accurate alternative, but errors in the reaction mechanism and in the kinetic parameters used may not be revealed by simple benchmarking. It is essential to use experimentally determined rate constants and verified reaction mechanisms, irrespective of whether the approach is chemical or electrochemical.

  1. Study of visualized simulation and analysis of nuclear fuel cycle system based on multilevel flow model

    Institute of Scientific and Technical Information of China (English)

    LIU Jing-Quan; YOSHIKAWA Hidekazu; ZHOU Yang-Ping

    2005-01-01

    Complex energy and environment system, especially nuclear fuel cycle system recently raised social concerns about the issues of economic competitiveness, environmental effect and nuclear proliferation. Only under the condition that those conflicting issues are gotten a consensus between stakeholders with different knowledge background, can nuclear power industry be continuingly developed. In this paper, a new analysis platform has been developed to help stakeholders to recognize and analyze various socio-technical issues in the nuclear fuel cycle system based on the functional modeling method named Multilevel Flow Models (MFM) according to the cognition theory of human being. Its character is that MFM models define a set of mass, energy and information flow structures on multiple levels of abstraction to describe the functional structure of a process system and its graphical symbol representation and the means-end and part-whole hierarchical flow structure to make the represented process easy to be understood. Based upon this methodology, a micro-process and a macro-process of nuclear fuel cycle system were selected to be simulated and some analysis processes such as economics analysis, environmental analysis and energy balance analysis related to those flows were also integrated to help stakeholders to understand the process of decision-making with the introduction of some new functions for the improved Multilevel Flow Models Studio, and finally the simple simulation such as spent fuel management process simulation and money flow of nuclear fuel cycle and its levelised cost analysis will be represented as feasible examples.

  2. Feasibility of Technologies to Produce Coal-Based Fuels with Equal or Lower Greenhouse Gas Emissions than Petroleum Fuels

    Science.gov (United States)

    2014-12-22

    Figure 6. Costs of alternative liquid fuels produced from coal, biomass , or coal and biomass with zero carbon price [reproduced from [6...Terms bpd Barrels per day BTL Biomass -to-liquids CBTL Coal-and- Biomass -to-Liquids CCS Carbon capture and storage CCUS Carbon capture... carbon footprint”) of a CTL process— partially narrowing the gap in well (or mine)-to-tank GHG emissions between CTL fuels and petroleum fuels

  3. Lanthanum manganate based cathodes for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Juhl Joergensen, M.

    2001-07-01

    Composite cathodes for solid oxide fuel cells were investigated using electrochemical impedance spectroscopy and scanning electron microscopy. The aim was to study the oxygen reduction process in the electrode in order to minimise the voltage drop in the cathode. The electrodes contained a composite layer made from lanthanum strontium manganate (LSM) and yttria stabilised zirconia (YSZ) and a layer of pure LSM aimed for current collection. The performance of the composite electrodes was sensitive to microstructure and thickness. Further, the interface between the composite and the current collecting layer proved to affect the performance. In a durability study severe deg-radation of the composite electrodes was found when passing current through the electrode for 2000 hours at 1000 deg. C. This was ascribed to pore formation along the composite interfaces and densification of the composite and current collector microstructure. An evaluation of the measurement approach indicated that impedance spectroscopy is a very sensitive method. This affects the reproducibility, as small undesirable variations in for instance the microstructure from electrode to electrode may change the impedance. At least five processes were found to affect the impedance of LSM/YSZ composite electrodes. Two high frequency processes were ascribed to transport of oxide ions/oxygen intermediates across LSM/YSZ interfaces and through YSZ in the composite. Several competitive elementary reaction steps, which appear as one medium frequency process in the impedance spectra, were observed. A low frequency arc related to gas diffusion limitation in a stagnant gas layer above the composite structure was detected. Finally, an inductive process, assumed to be connected to an activation process involving segregates at the triple phase boundary between electrode, electrolyte and gas phase, was found. (au)

  4. Performance Degradation Tests of Phosphoric Acid Doped Polybenzimidazole Membrane Based High Temperature Polymer Electrolyte Membrane Fuel Cells

    DEFF Research Database (Denmark)

    Zhou, Fan; Araya, Samuel Simon; Grigoras, Ionela

    2015-01-01

    Degradation tests of two phosphoric acid (PA) doped PBI membrane based HT-PEM fuel cells were reported in this paper to investigate the effects of start/stop and the presence of methanol in the fuel to the performance degradation of the HT-PEM fuel cell. Continuous tests with pure dry H2...... and methanol containing H2 which was composed of H2, steam and methanol as the fuel were performed on both single cells. After the continuous tests, 12-h-startup/12-h-shutdown dynamic tests were performed on the first single cell with H2 as the fuel and on the second single cell with methanol containing H2...... as the fuel. Along with the degradation tests, electrochemical techniques such as polarization curves and electrochemical impedance spectroscopy (EIS) were employed to study the degradation mechanisms of the fuel cells. The results of the tests showed that both single cells experienced an increase...

  5. Imidazolium-Based Polymeric Materials as Alkaline Anion-Exchange Fuel Cell Membranes

    Science.gov (United States)

    Narayan, Sri R.; Yen, Shiao-Ping S.; Reddy, Prakash V.; Nair, Nanditha

    2012-01-01

    Polymer electrolyte membranes that conduct hydroxide ions have potential use in fuel cells. A variety of polystyrene-based quaternary ammonium hydroxides have been reported as anion exchange fuel cell membranes. However, the hydrolytic stability and conductivity of the commercially available membranes are not adequate to meet the requirements of fuel cell applications. When compared with commercially available membranes, polystyrene-imidazolium alkaline membrane electrolytes are more stable and more highly conducting. At the time of this reporting, this has been the first such usage for imidazolium-based polymeric materials for fuel cells. Imidazolium salts are known to be electrochemically stable over wide potential ranges. By controlling the relative ratio of imidazolium groups in polystyrene-imidazolium salts, their physiochemical properties could be modulated. Alkaline anion exchange membranes based on polystyrene-imidazolium hydroxide materials have been developed. The first step was to synthesize the poly(styrene-co-(1-((4-vinyl)methyl)-3- methylimidazolium) chloride through a free-radical polymerization. Casting of this material followed by in situ treatment of the membranes with sodium hydroxide solutions provided the corresponding hydroxide salts. Various ratios of the monomers 4-chloromoethylvinylbenzine (CMVB) and vinylbenzine (VB) provided various compositions of the polymer. The preferred material, due to the relative ease of casting the film, and its relatively low hygroscopic nature, was a 2:1 ratio of CMVB to VB. Testing confirmed that at room temperature, the new membranes outperformed commercially available membranes by a large margin. With fuel cells now in use at NASA and in transportation, and with defense potential, any improvement to fuel cell efficiency is a significant development.

  6. Environmental Assessment. Increase Fuel Storage Capacity, Dover Air Force Base, Delaware

    Science.gov (United States)

    2012-06-01

    in 1998. Grasshopper Sparrow 2 Observed on Bergold Farm 16 July 2003 and in 1998. Great blue heron 2 Observed many times foraging along both Pipe...ENVIRONMENTAL CONSEQUENCES Increase Fuels Capacity Dover Air Force Base, Delaware 28 calculations were derived from the same EPA software utilized to

  7. Microbial Communities and Electrochemical Performance of Titanium-Based Anodic Electrodes in a Microbial Fuel Cell

    NARCIS (Netherlands)

    Michaelidou, U.; Heijne, ter A.; Euverink, G.J.W.; Hamelers, H.V.M.; Stams, A.J.M.; Geelhoed, J.S.

    2011-01-01

    Four types of titanium (Ti)-based electrodes were tested in the same microbial fuel cell (MFC) anodic compartment. Their electrochemical performances and the dominant microbial communities of the electrode biofilms were compared. The electrodes were identical in shape, macroscopic surface area, and

  8. Assessment of full ceramic solid oxide fuel cells based on modified strontium titanates

    DEFF Research Database (Denmark)

    Holtappels, Peter; Ramos, Tania; Sudireddy, Bhaskar Reddy;

    2014-01-01

    stimulated the development for full ceramic anodes based on strontium titanates. Furthermore, the Ni-cermet is primarily a hydrogen oxidation electrode and efficiency losses might occur when operating on carbon containing fuels. In the European project SCOTAS-SOFC full ceramic cells comprising CGO...

  9. A spatially resolved fuel-based inventory of Utah and Colorado oil and natural gas emissions

    Science.gov (United States)

    Gorchov Negron, A.; McDonald, B. C.; De Gouw, J. A.; Frost, G. J.

    2015-12-01

    A fuel-based approach is presented for estimating emissions from US oil and natural gas production that utilizes state-level fuel surveys of oil and gas engine activity, well-level production data, and emission factors for oil and gas equipment. Emissions of carbon dioxide (CO2) and nitrogen oxides (NOx) are mapped on a 4 km x 4 km horizontal grid for 2013-14 in Utah and Colorado. Emission sources include combustion from exploration (e.g., drilling), production (e.g., heaters, dehydrators, and compressor engines), and natural gas processing plants, which comprise a large fraction of the local combustion activity in oil and gas basins. Fuel-based emission factors of NOx are from the U.S. Environmental Protection Agency, and applied to spatially-resolved maps of CO2 emissions. Preliminary NOx emissions from this study are estimated for the Uintah Basin, Utah, to be ~5300 metric tons of NO2-equivalent in 2013. Our result compares well with an observations-based top-down emissions estimate of NOx derived from a previous study, ~4200 metric tons of NO2-equivalent. By contrast, the 2011 National Emissions Inventory estimates oil and gas emissions of NOx to be ~3 times higher than our study in the Uintah Basin. We intend to expand our fuel-based approach to map combustion-related emissions in other U.S. oil and natural gas basins and compare with additional observational datasets.

  10. Determining Fuel Losses in Storage Tanks Based on Factual Saturation Pressures

    Science.gov (United States)

    Levitin, R. E.; Tryascin, R. A.

    2016-10-01

    At present, evaluation of fuel evaporative losses is based on a number of indirect parameters. Accuracy of such methods leaves much to be desired. The paper presents a method developed following the author's laboratory tests. An effective operation range of pressure vent valves in various tanks is provided, as well as low A92 gasoline losses for horizontal steel tanks at all operation temperatures.

  11. Particle Swarm Optimization based predictive control of Proton Exchange Membrane Fuel Cell (PEMFC)

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Proton Exchange Membrane Fuel Cells (PEMFCs) are the main focus of their current development as power sources because they are capable of higher power density and faster start-up than other fuel cells. The humidification system and output performance of PEMFC stack are briefly analyzed. Predictive control of PEMFC based on Support Vector Regression Machine (SVRM) is presented and the SVRM is constructed. The processing plant is modelled on SVRM and the predictive control law is obtained by using Particle Swarm Optimization (PSO). The simulation and the results showed that the SVRM and the PSO receding optimization applied to the PEMFC predictive control yielded good performance.

  12. Soot modeling of counterflow diffusion flames of ethylene-based binary mixture fuels

    KAUST Repository

    Wang, Yu

    2015-03-01

    A soot model was developed based on the recently proposed PAH growth mechanism for C1-C4 gaseous fuels (KAUST PAH Mechanism 2, KM2) that included molecular growth up to coronene (A7) to simulate soot formation in counterflow diffusion flames of ethylene and its binary mixtures with methane, ethane and propane based on the method of moments. The soot model has 36 soot nucleation reactions from 8 PAH molecules including pyrene and larger PAHs. Soot surface growth reactions were based on a modified hydrogen-abstraction-acetylene-addition (HACA) mechanism in which CH3, C3H3 and C2H radicals were included in the hydrogen abstraction reactions in addition to H atoms. PAH condensation on soot particles was also considered. The experimentally measured profiles of soot volume fraction, number density, and particle size were well captured by the model for the baseline case of ethylene along with the cases involving mixtures of fuels. The simulation results, which were in qualitative agreement with the experimental data in the effects of binary fuel mixing on the sooting structures of the measured flames, showed in particular that 5% addition of propane (ethane) led to an increase in the soot volume fraction of the ethylene flame by 32% (6%), despite the fact that propane and ethane are less sooting fuels than is ethylene, which is in reasonable agreement with experiments of 37% (14%). The model revealed that with 5% addition of methane, there was an increase of 6% in the soot volume fraction. The average soot particle sizes were only minimally influenced while the soot number densities were increased by the fuel mixing. Further analysis of the numerical data indicated that the chemical cross-linking effect between ethylene and the dopant fuels resulted in an increase in PAH formation, which led to higher soot nucleation rates and therefore higher soot number densities. On the other hand, the rates of soot surface growth per unit surface area through the HACA mechanism were

  13. Innovative Household Systems Based on Solid Oxide Fuel Cells for a Northern European climate

    DEFF Research Database (Denmark)

    Rokni, Masoud; Vialetto, Giulio

    2015-01-01

    Energy saving is an open point in most European countries where energy policies are oriented to reduce the use of fossil fuels, greenhouses emissions and energy independence and to increase the use of renewable energies. In the last several years, new technologies have been developed, and some...... of them received subsidies to increase installation and reduce cost.This article presents an innovative cogeneration system based on a solid oxide fuel cell (SOFC) systemand heat pump for household applications with a focus on primary energy and economic savings using electric equivalent load parameter...

  14. A wide characterization of paraffin-based fuels mixed with styrene-based thermoplastic polymers for hybrid propulsion

    Science.gov (United States)

    Boiocchi, M.; Milova, P.; Galfetti, L.; Di Landro, L.; Golovko, A. K.

    2016-07-01

    In the framework of a long-term research activity focused on the development of high-performance solid fuels for hybrid rockets, paraffin-based fuels were investigated and characterized using two different pure paraffinic waxes and a styrene-based thermoplastic elastomer as strengthening material. The fuels were studied using differential scanning calorimetry (DSC) and thermogravimetric analysis / differential thermal analysis (TGA-DTA). The viscosity of the melt layer, responsible for the entrainment effect, was investigated using a Couette viscosimeter. The storage modulus (G') was analyzed using a parallel-plate rheometer. The chemical composition of the pure paraffinic materials was studied using gas chromatography / mass spectrometry (GC-MS), while mechanical properties were investigated through uniaxial tensile tests.

  15. Characterizing Gaseous Fuels for Their Knock Resistance based on the Chemical and Physical Properties of the Fuel

    NARCIS (Netherlands)

    Levinsky, Howard; Gersen, Sander; van Essen, Martijn; van Dijk, Gerco

    2016-01-01

    A method is described to characterize the effects of changes in the composition of gaseous fuels on engine knock by computing the autoignition process during the compression and burn periods of the engine cycle. To account for the effects of fuel composition on the in-cylinder pressure and temperatu

  16. Fuel economy improvement based on a many-gear shifting strategy

    Energy Technology Data Exchange (ETDEWEB)

    Mashadi, B. [School of Automotive Engineering, Iran University of Science and Technology, Tehran (Iran, Islamic Republic of); Baghaei Lakeh, R. [Department of Mechanical Engineering, Southern Illinois University, Edwardsville (United States)

    2012-07-01

    Considering the engine operating condition in terms of engine load and engine speed, a fuzzy decision making system has been developed. The objective was to controlling the engine operating point in the engine torque-rpm map, in order to enhance fuel economy. The main idea stems from the approach of tracking the defined target curve in the engine map similar to the CVT control criteria. To provide resemblance between a traditional geared transmission and a CVT, a many-gear transmission concept was introduced. A Fuzzy control was utilized by defining proper membership functions for the inputs and output. The efficient fuel consumption curve in the engine map was taken as the target of controller. The effect of engine output power on fuel consumption has also been taken into consideration. Making use of ADVISOR software, vehicle simulations was performed for the many-gear base case and a very good consistency was found with the CVT case. As a result the fuel consumption was found to become considerably less than existing values. The developed strategy was then applied to other cases including conventional manual and automatic transmissions and improvements in the fuel economy was observed.

  17. Performance enhancement of phosphoric acid fuel cell using phosphosilicate gel based electrolyte

    Institute of Scientific and Technical Information of China (English)

    Kajari Kargupta; Swati Saha; Dipali Banerjee; Mrinal Seal; Saibal Ganguly

    2012-01-01

    Replacement of phosphoric acid electrolyte by phosphosilicate gel based electrolytes is proposed for performance enhancement of phosphoric acid fuel cell (PAFG).Phosphosilicate gel in paste form and in powder form is synthesized from tetraethoxysilane and orthophosphoric acid using sol-gel method for two different P/Si ratio of 5 and 1.5 respectively.Replacement of phosphoric acid electrolyte by phosphosilicate gel paste enhances the peak power generation of the fuel cell by 133% at 120 ℃ cell temperature; increases the voltage generation in the ohmic regime and extends the maximum possible load current.Polyinyl alcohol (PVA) is used to bind the phosphosilicate gel powder and to form the hybrid crosslinked gel polymer electrolyte membrane.Soaking the membrane with phosphoric acid solution,instead of that with water improves the proton conductivity of the membrane,enhances the voltage and power generation by the fuel cell and extends the maximum possible operating temperature.At lower operating temperature of 70 ℃,peak power produced by phosphosilicate gel polymer electrolyte membrane fuel cell ( PGMFC ) is increased by 40% compared to that generated by phosphoric acid fuel cell ( PAFC ).However,the performance of composite membrane diminishes as the cell temperature increases.Thus phosphosilicate gel in paste form is found to be a good alternative of phosphoric acid electrolyte at medium operating temperature range while phosphosilicate gel-PVA composite offers performance enhancement at low operating temperatures.

  18. Fuel economy improvement based on a many-gear shifting strategy

    Directory of Open Access Journals (Sweden)

    B. Mashadi, R. Baghaei Lakeh

    2012-01-01

    Full Text Available Considering the engine operating condition in terms of engine load and engine speed, a fuzzy decision making system has been developed. The objective was to controlling the engine operating point in the engine torque-rpm map, in order to enhance fuel economy. The main idea stems from the approach of tracking the defined target curve in the engine map similar to the CVT control criteria. To provide resemblance between a traditional geared transmission and a CVT, a many-gear transmission concept was introduced. A Fuzzy control was utilized by defining proper membership functions for the inputs and output. The efficient fuel consumption curve in the engine map was taken as the target of controller. The effect of engine output power on fuel consumption has also been taken into consideration. Making use of ADVISOR software, vehicle simulations was performed for the many-gear base case and a very good consistency was found with the CVT case. As a result the fuel consumption was found to become considerably less than existing values. The developed strategy was then applied to other cases including conventional manual and automatic transmissions and improvements in the fuel economy was observed.

  19. Membrane-less micro fuel cell based on two-phase flow

    Science.gov (United States)

    Hashemi, S. M. H.; Neuenschwander, M.; Hadikhani, P.; Modestino, M. A.; Psaltis, D.

    2017-04-01

    Most microfluidic fuel cells use highly soluble fuels and oxidants in streams of liquid electrolytes to overcome the mass transport limitations that result from the low solubility of gaseous reactants such as hydrogen and oxygen. In this work, we address these limitations by implementing controlled two-phase flows of these gases in a set of microchannels electrolytically connected through a narrow gap. Annular flows of the gases reshape the concentration boundary layer over the surface of electrodes and increase the mass-transport limited current density in the system. Our results show that the power density of a two-phase system with hydrogen and oxygen streams is an order of magnitude higher than that of single phase system consisting of liquid electrolytes saturated with the same reactants. The reactor design described here can be employed to boost the performance of MFFCs and put them in a more competitive position compared to membrane based fuel cells.

  20. Experimental investigation of nitrogen based emissions from an ammonia fueled SI-engine

    DEFF Research Database (Denmark)

    Westlye, Fredrik Ree; Ivarsson, Anders; Schramm, Jesper

    2013-01-01

    This study concerns nitrogen based emissions from a hydrogen enriched ammonia fueled SI engine. These emissions deserve special attention as their formation may differ from conventional HC combustion due to the nitrogen content in the fuel. A range of experiments are conducted with a single cylin...... by the compression ratio. However, levels are lower than required in order to eliminate all NOx emissions with a SCR catalyst. © 2013 Elsevier Ltd. All rights reserved....... cylinder 0.612 l CFR engine with a compression ratio varying from 7 to 15 using a fuel composition of 80 vol% NH3 and 20 vol% H2. Wet exhaust samples are analysed with an FT-IR. Emission measurements reveal that nitric oxide stem from other reaction paths than the dissociation of molecular nitrogen...

  1. Durability Issues of High Temperature Proton Exchange Membrane Fuel Cells Based on Acid Doped Polybenzimidazole Membranes

    DEFF Research Database (Denmark)

    To achieve high temperature operation of proton exchange membrane fuel cells (PEMFC), preferably under ambient pressure, phosphoric acid doped polybenzimidazole (PBI) membrane represents an effective approach, which in recent years has motivated extensive research activities with great progress....... As a critical concern, issues of long term durability of PBI based fuel cells are addressed in this talk, including oxidative degradation of the polymer, mechanical failures of the membrane, acid leaching out, corrosion of carbon support and sintering of catalysts particles. Excellent polymer durability has...... observed under continuous operation with hydrogen and air at 150-160oC, with a fuel cell performance degradation rate of 5-10 µV/h. Improvement of the membrane performance such as mechanical strength, swelling and oxidative stability has achieved by exploring the polymer chemistry, i.e. covalently...

  2. Silica based composite membranes for methanol fuel cells operating at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez, A.; Guzman, C.; Peza-Ledesma, C.; Godinez, Luis A.; Nava, R.; Duron-Torres, S.M.; Ledesma-Garcia, J.; Arriaga, L.G.

    2011-01-15

    Direct methanol fuel cells (DMFCs) are seen as an alternative energy source for several applications, particularly portable power sources. Nafion membranes constitute a well known proton exchange system for DMFC systems due to their convenient electrochemical, mechanical and thermal stability and high proton conductivity properties. But there are problems currently associated with the direct methanol fuel cell technology. Intensive efforts to decrease the methanol crossover are focused mainly on the development of new polymer electrolyte membranes. In this study, Nafion polymer was modified by means of the incorporation of inorganic oxides with different structural properties (SBA-15 and SiO2), both prepared by sol-gel method in order to increase the proton conductivity at high temperature of fuel cell and to contribute decrementing the methanol crossover effect. Composite membranes based in inorganic fillers showed a significant decrease in the concentration of methanol permeation.

  3. Time-resolved fuel injector flow characterisation based on 3D laser Doppler vibrometry

    CERN Document Server

    Crua, Cyril

    2015-01-01

    In order to enable investigations of the fuel flow inside unmodified injectors, we have developed a new experimental approach to measure time-resolved vibration spectra of diesel nozzles using a three dimensional laser vibrometer. The technique we propose is based on the triangulation of the vibrometer and fuel pressure transducer signals, and enables the quantitative characterisation of quasi-cyclic internal flows without requiring modifications to the injector, the working fluid, or limiting the fuel injection pressure. The vibrometer, which uses the Doppler effect to measure the velocity of a vibrating object, was used to scan injector nozzle tips during the injection event. The data were processed using a discrete Fourier transform to provide time-resolved spectra for valve-closed-orifice, minisac and microsac nozzle geometries, and injection pressures ranging from 60 to 160MPa, hence offering unprecedented insight into cyclic cavitation and internal mechanical dynamic processes. A peak was consistently f...

  4. Designing and optimization of a micro CHP system based on Solid Oxide Fuel Cell with different fuel processing technologies

    DEFF Research Database (Denmark)

    Liso, Vincenzo; Nielsen, Mads Pagh; Kær, Søren Knudsen

    2009-01-01

    (SMR) and partial oxidation (CPO) will be investigated for each configuration. The internal reforming will be also considered for its ability to reduce the stack temperature and decrease the need of cooling air. Finally, optimization criteria for SOFC systems applied to single-family detached dwellings...... are the possibility to partially reform hydrocarbon in the fuel cell anode compartment and the possibility to use high quality heat for cogeneration. In this work, different configurations of solid oxide fuel cell system for decentralized electricity production are examined. The Balance of Plant (BoP) components...... of the Micro Combined Heat and Power plant (mCHP) will be identified including fuel and air supply, fuel management anode re-circulation, exhaust gas heat management, power conditioning and control system. Using mass and energy balance, different types of fuel reforming including steam reforming...

  5. Waste Classification based on Waste Form Heat Generation in Advanced Nuclear Fuel Cycles Using the Fuel-Cycle Integration and Tradeoffs (FIT) Model

    Energy Technology Data Exchange (ETDEWEB)

    Denia Djokic; Steven J. Piet; Layne F. Pincock; Nick R. Soelberg

    2013-02-01

    This study explores the impact of wastes generated from potential future fuel cycles and the issues presented by classifying these under current classification criteria, and discusses the possibility of a comprehensive and consistent characteristics-based classification framework based on new waste streams created from advanced fuel cycles. A static mass flow model, Fuel-Cycle Integration and Tradeoffs (FIT), was used to calculate the composition of waste streams resulting from different nuclear fuel cycle choices. This analysis focuses on the impact of waste form heat load on waste classification practices, although classifying by metrics of radiotoxicity, mass, and volume is also possible. The value of separation of heat-generating fission products and actinides in different fuel cycles is discussed. It was shown that the benefits of reducing the short-term fission-product heat load of waste destined for geologic disposal are neglected under the current source-based radioactive waste classification system , and that it is useful to classify waste streams based on how favorable the impact of interim storage is in increasing repository capacity.

  6. Integrated data base report - 1994: US spent nuclear fuel and radioactive waste inventories, projections, and characteristics

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    The Integrated Data Base Program has compiled historic data on inventories and characteristics of both commercial and U.S. Department of Energy (DOE) spent nuclear fuel and commercial and U.S. government-owned radioactive wastes. Except for transuranic wastes, inventories of these materials are reported as of December 31, 1994. Transuranic waste inventories are reported as of December 31, 1993. All spent nuclear fuel and radioactive waste data reported are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecasted is consistent with the latest DOE/Energy Information Administration (EIA) projections of U.S. commercial nuclear power growth and the expected DOE-related and private industrial and institutional activities. The radioactive materials considered, on a chapter-by-chapter basis, are spent nuclear fuel, high-level waste, transuranic waste, low-level waste, commercial uranium mill tailings, DOE Environmental Restoration Program contaminated environmental media, commercial reactor and fuel-cycle facility decommissioning wastes, and mixed (hazardous and radioactive) low-level waste. For most of these categories, current and projected inventories are given through the calendar-year 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions.

  7. An Agent-Based Modeling Framework and Application for the Generic Nuclear Fuel Cycle

    Science.gov (United States)

    Gidden, Matthew J.

    Key components of a novel methodology and implementation of an agent-based, dynamic nuclear fuel cycle simulator, Cyclus , are presented. The nuclear fuel cycle is a complex, physics-dependent supply chain. To date, existing dynamic simulators have not treated constrained fuel supply, time-dependent, isotopic-quality based demand, or fuel fungibility particularly well. Utilizing an agent-based methodology that incorporates sophisticated graph theory and operations research techniques can overcome these deficiencies. This work describes a simulation kernel and agents that interact with it, highlighting the Dynamic Resource Exchange (DRE), the supply-demand framework at the heart of the kernel. The key agent-DRE interaction mechanisms are described, which enable complex entity interaction through the use of physics and socio-economic models. The translation of an exchange instance to a variant of the Multicommodity Transportation Problem, which can be solved feasibly or optimally, follows. An extensive investigation of solution performance and fidelity is then presented. Finally, recommendations for future users of Cyclus and the DRE are provided.

  8. Use of non-petroleum fuels to reduce military energy vulnerabilities: self-sufficient bases and new weapon propulsion systems

    Energy Technology Data Exchange (ETDEWEB)

    Freiwald, D.A.

    1980-01-01

    The US fossil synfuels program may not have significant impact on domestic fuel supplies until near the year 2000, resulting in a continuing mobility fuels vulnerability for the US military until then. But there are other mobility fuel options for both propulsion systems and stationary base-energy sources, for which the base technology is commercially available or at least demonstrated. For example, for surface propulsion systems, hydrogen-fuel-cell/battery-electric hybrids may be considered; for weapons systems these may offer some new flexibilities, standardization possibilities, and multiple military-controlled fuel-supply options. Hydrogen-fueled aircraft may provide interesting longer-term possibilities in terms of military energy self-sufficiency and multiple supply options, as well as performance specifications. These scenarios will be discussed, along with possibilities for demonstrations in the MX-system ground vehicles.

  9. Nanowire-based three-dimensional hierarchical core/shell heterostructured electrodes for high performance proton exchange membrane fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Saha, Madhu Sudan; Li, Ruying; Sun, Xueliang [Department of Mechanical and Materials Engineering, The University of Western Ontario, London, Ontario N6A 5B9 (Canada); Cai, Mei [General Motors Research and Development Center, Warren, MI 48090-9055 (United States)

    2008-12-01

    In order to effectively utilize expensive Pt in fuel cell electrocatalyst and improve the durability of PEM fuel cells, new catalyst supports with three-dimensional (3D) open structure are highly desirable. Here, we report the fabrication of a 3D core/shell heterostructure consisting tin nanowire core and carbon nanotube shell (SnC) grown directly onto fuel cell backing (here carbon paper) as Pt catalyst support for PEM fuel cells. Compared with the conventional Pt/C membrane electrode assembly (MEA), SnC nanowire-based MEA shows significantly higher oxygen reaction performance and better CO tolerance as well as excellent stability in PEM fuel cells. The results demonstrate that the core/shell nanowire-based composites are very promising supports in making cost effective and electrocatalysts for fuel cell applications. (author)

  10. Fuel cell membrane preparation: effects of base polymer

    Energy Technology Data Exchange (ETDEWEB)

    Brack, H.P.; Scherer, G.G. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    Radiation grafted films and membranes prepared from the partially fluorinated base copolymer poly(ethylene-alt-tetrafluoroethylene) or ETFE have better mechanical properties than those prepared from poly(tetrafluoroethylene-co-hexafluoropropylene) or FEP. The influence of the base copolymer film type on the grafting rate and yields is reported in the present investigation. An understanding of the effects of these parameters is important so that the grafting process can be carried out reproducibly in as short a time as possible. The grafting rate and yield as a function of the irradiation dose has been found to be much higher for the partially fluorinated base copolymer ETFE. (author) 2 figs., 1 tab., 5 refs.

  11. Observer-Based Fuel Control Using Oxygen Measurement

    DEFF Research Database (Denmark)

    Andersen, Palle; Bendtsen, Jan Dimon; Mortensen, Jan Henrik

    is constructed and validated against data obtained at the plant. A Kalman filter based on measurements of combustion air flow led into the furnace and oxygen concentration in the flue gas is designed to estimate the actual coal flow. With this estimate, it becomes possible to close an inner loop around the coal......This report describes an attempt to improve the existing control af coal mills used at the Danish power plant Nordjyllandsværket Unit 3. The coal mills are not equipped with coal flow sensors; thus an observer-based approach is investigated. A nonlinear differential equation model of the boiler...

  12. Comparison of Coal-Based Dimethyl Ether and Diesel as Vehicle Fuels from Well to Wheel in China

    Institute of Scientific and Technical Information of China (English)

    ZHANG Liang; HUANG Zhen

    2009-01-01

    With life cycle assessment (LCA) methodology, a life cycle model of coal-based vehicle fuels (CBVFs) including coal-based dimethyl ether (CBDME) and coal-based diesel (CBD) is established. Their primary energy consumption (PEC) and global warming potential (GWP) from well to wheel including feedstock extraction, fuel production, fuel consumption in vehicle and energy transportation are calculated and compared. Results show that the life cycle PEC and GWP of CBD pathway are 1.17 and 1.34 times as CBDME pathway. Based on the above results, CBDME will become a choice with great potential to replace conventional petroleum-based diesel (CPBD) in China.

  13. The emergence of new technology-based industries: the case of fuel cells and its technological relatedness to regional knowledge bases

    DEFF Research Database (Denmark)

    Tanner, Anne Nygaard

    2016-01-01

    to emerging radical technologies that create the foundation for new industries. The article develops a new measure for technological relatedness between the knowledge base of a region and that of a radical technology based on patent classes. It demonstrates that emerging fuel cell technology develops where...... the regional knowledge base is technologically related to that of fuel cells and consequently confirms the evolutionary thesis....

  14. Impact of thorium based molten salt reactor on the closure of the nuclear fuel cycle

    Science.gov (United States)

    Jaradat, Safwan Qasim Mohammad

    Molten salt reactor (MSR) is one of six reactors selected by the Generation IV International Forum (GIF). The liquid fluoride thorium reactor (LFTR) is a MSR concept based on thorium fuel cycle. LFTR uses liquid fluoride salts as a nuclear fuel. It uses 232Th and 233U as the fertile and fissile materials, respectively. Fluoride salt of these nuclides is dissolved in a mixed carrier salt of lithium and beryllium (FLiBe). The objective of this research was to complete feasibility studies of a small commercial thermal LFTR. The focus was on neutronic calculations in order to prescribe core design parameter such as core size, fuel block pitch (p), fuel channel radius, fuel path, reflector thickness, fuel salt composition, and power. In order to achieve this objective, the applicability of Monte Carlo N-Particle Transport Code (MCNP) to MSR modeling was verified. Then, a prescription for conceptual small thermal reactor LFTR and relevant calculations were performed using MCNP to determine the main neutronic parameters of the core reactor. The MCNP code was used to study the reactor physics characteristics for the FUJI-U3 reactor. The results were then compared with the results obtained from the original FUJI-U3 using the reactor physics code SRAC95 and the burnup analysis code ORIPHY2. The results were comparable with each other. Based on the results, MCNP was found to be a reliable code to model a small thermal LFTR and study all the related reactor physics characteristics. The results of this study were promising and successful in demonstrating a prefatory small commercial LFTR design. The outcome of using a small core reactor with a diameter/height of 280/260 cm that would operate for more than five years at a power level of 150 MWth was studied. The fuel system 7LiF - BeF2 - ThF4 - UF4 with a (233U/ 232Th) = 2.01 % was the candidate fuel for this reactor core.

  15. Hardware-Based Simulation of a Fuel Cell Turbine Hybrid Response to Imposed Fuel Cell Load Transients

    Energy Technology Data Exchange (ETDEWEB)

    Smith, T.P. (Georgia Inst. of Technology); Tucker, D.A.; Haynes, C.L. (Georgia Inst. of Technology); Liese, E.A.; Wepfer, W.J. (Georgia Inst. of Technology)

    2006-11-01

    Electrical load transients imposed on the cell stack of a solid oxide fuel cell/gas turbine hybrid power system are studied using the Hybrid Performance (HyPer) project. The hardware simulation facility is located at the U.S. Department of Energy, National Energy Technology Laboratory (NETL). A computational fuel cell model capable of operating in real time is integrated with operating gas turbine hardware. The thermal output of a modeled 350 kW solid oxide fuel cell stack is replicated in the facility by a natural gas fired burner in a direct fired hybrid configuration. Pressure vessels are used to represent a fuel cell stack's cathode flow and post combustion volume and flow impedance. This hardware is used to simulate the fuel cell stack and is incorporated with a modified turbine, compressor, and 120 kW generator on a single shaft. For this study, a simulation was started with a simulated current demand of 307 A on the fuel cell at approximately 0.75 V and an actual 45 kW electrical load on the gas turbine. An open loop response, allowing the turbine rotational speed to respond to thermal transients, was successfully evaluated for a 5% current reduction on the fuel cell followed by a 5% current increase. The impact of the fuel cell load change on system process variables is presented. The test results demonstrate the capabilities of the hardware-in-the-loop simulation approach in evaluating hybrid fuel cell turbine dynamics and performance.

  16. ISRU Reactant, Fuel Cell Based Power Plant for Robotic and Human Mobile Exploration Applications

    Science.gov (United States)

    Baird, Russell S.; Sanders, Gerald; Simon, Thomas; McCurdy, Kerri

    2003-01-01

    Three basic power generation system concepts are generally considered for lander, rover, and Extra-Vehicular Activity (EVA) assistant applications for robotic and human Moon and Mars exploration missions. The most common power system considered is the solar array and battery system. While relatively simple and successful, solar array/battery systems have some serious limitations for mobile applications. For typical rover applications, these limitations include relatively low total energy storage capabilities, daylight only operating times (6 to 8 hours on Mars), relatively short operating lives depending on the operating environment, and rover/lander size and surface use constraints. Radioisotope power systems are being reconsidered for long-range science missions. Unfortunately, the high cost, political controversy, and launch difficulties that are associated with nuclear-based power systems suggests that the use of radioisotope powered landers, rovers, and EVA assistants will be limited. The third power system concept now being considered are fuel cell based systems. Fuel cell power systems overcome many of the performance and surface exploration limitations of solar array/battery power systems and the prohibitive cost and other difficulties associated with nuclear power systems for mobile applications. In an effort to better understand the capabilities and limitations of fuel cell power systems for Moon and Mars exploration applications. NASA is investigating the use of In-Situ Resource Utilization (ISRU) produced reactant, fuel cell based power plants to power robotic outpost rovers, science equipment, and future human spacecraft, surface-excursion rovers, and EVA assistant rovers. This paper will briefly compare the capabilities and limitations of fuel cell power systems relative to solar array/battery and nuclear systems, discuss the unique and enhanced missions that fuel cell power systems enable, and discuss the common technology and system attributes

  17. Energy Management Strategies based on efficiency map for Fuel Cell Hybrid Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Feroldi, Diego; Serra, Maria; Riera, Jordi [Institut de Robotica i Informatica Industrial (CSIC-UPC), C. Llorens i Artigas 4, 08028 Barcelona (Spain)

    2009-05-15

    The addition of a fast auxiliary power source like a supercapacitor bank in fuel cell-based vehicles has a great potential because permits a significant reduction of the hydrogen consumption and an improvement of the vehicle efficiency. The Energy Management Strategies, commanding the power split between the power sources in the hybrid arrangement to fulfil the power requirement, perform a fundamental role to achieve this objective. In this work, three strategies based on the knowledge of the fuel cell efficiency map are proposed. These strategies are attractive due to the relative simplicity of the real time implementation and the good performance. The strategies are tested both in a simulation environment and in an experimental setup using a 1.2-kW PEM fuel cell. The results, in terms of hydrogen consumption, are compared with an optimal case, which is assessed trough an advantageous technique also introduced in this work and with a pure fuel cell vehicle as well. This comparative reveals high efficiency and good performance, allowing to save up to 26% of hydrogen in urban scenarios. (author)

  18. Single-use paper-based hydrogen fuel cells for point-of-care diagnostic applications

    Science.gov (United States)

    Esquivel, J. P.; Buser, J. R.; Lim, C. W.; Domínguez, C.; Rojas, S.; Yager, P.; Sabaté, N.

    2017-02-01

    This work demonstrates a stand-alone power source that integrates a paper-based hydrogen fuel cell with a customized chemical heater that produces hydrogen in-situ upon the addition of a liquid. The presented approach operates by capillary action and takes advantage of the hydrogen released as a by-product of an exothermic reaction used in point-of-care diagnostics. The paper-based fuel cell produces a maximum power of 25.8 mW (103.2 mW cm-2), which is suitable for powering a diversity of electrical devices such as commercially available digital pregnancy tests and glucometers. While device shape and dimensions can be customized, here it is shown that the fuel cell can be designed in a compact form factor and footprint comparable to a lateral flow test while providing a remarkable power output. This approach holds great promise for powering portable diagnostics, as the generated electric power could enable device functionalities required for advanced assays, such as device timing, actuation, and signal quantification. Part of the same liquid sample that is to be analyzed (urine, saliva, water, etc) could be used to trigger the hydrogen generation and start the fuel cell operation.

  19. Greenhouse gas emissions and land use change from Jatropha curcas-based jet fuel in Brazil.

    Science.gov (United States)

    Bailis, Robert E; Baka, Jennifer E

    2010-11-15

    This analysis presents a comparison of life-cycle GHG emissions from synthetic paraffinic kerosene (SPK) produced as jet fuel substitute from jatropha curcas feedstock cultivated in Brazil against a reference scenario of conventional jet fuel. Life cycle inventory data are derived from surveys of actual Jatropha growers and processors. Results indicate that a baseline scenario, which assumes a medium yield of 4 tons of dry fruit per hectare under drip irrigation with existing logistical conditions using energy-based coproduct allocation methodology, and assumes a 20-year plantation lifetime with no direct land use change (dLUC), results in the emissions of 40 kg CO₂e per GJ of fuel produced, a 55% reduction relative to conventional jet fuel. However, dLUC based on observations of land-use transitions leads to widely varying changes in carbon stocks ranging from losses in excess of 50 tons of carbon per hectare when Jatropha is planted in native cerrado woodlands to gains of 10-15 tons of carbon per hectare when Jatropha is planted in former agro-pastoral land. Thus, aggregate emissions vary from a low of 13 kg CO₂e per GJ when Jatropha is planted in former agro-pastoral lands, an 85% decrease from the reference scenario, to 141 kg CO₂e per GJ when Jatropha is planted in cerrado woodlands, a 60% increase over the reference scenario. Additional sensitivities are also explored, including changes in yield, exclusion of irrigation, shortened supply chains, and alternative allocation methodologies.

  20. Dynamic fuel cell stack model for real-time simulation based on system identification

    Science.gov (United States)

    Meiler, M.; Schmid, O.; Schudy, M.; Hofer, E. P.

    The authors have been developing an empirical mathematical model to predict the dynamic behaviour of a polymer electrolyte membrane fuel cell (PEMFC) stack. Today there is a great number of models, describing steady-state behaviour of fuel cells by estimating the equilibrium voltage for a certain set of operating parameters, but models capable of predicting the transient process between two steady-state points are rare. However, in automotive applications round about 80% of operating situations are dynamic. To improve the reliability of fuel cell systems by model-based control for real-time simulation dynamic fuel cell stack model is needed. Physical motivated models, described by differential equations, usually are complex and need a lot of computing time. To meet the real-time capability the focus is set on empirical models. Fuel cells are highly nonlinear systems, so often used auto-regressive (AR), output-error (OE) or Box-Jenkins (BJ) models do not accomplish satisfying accuracy. Best results are achieved by splitting the behaviour into a nonlinear static and a linear dynamic subsystem, a so-called Uryson-Model. For system identification and model validation load steps with different amplitudes are applied to the fuel cell stack at various operation points and the voltage response is recorded. The presented model is implemented in MATLAB environment and has a computing time of less than 1 ms per step on a standard desktop computer with a 2.8 MHz CPU and 504 MB RAM. Lab tests are carried out at DaimlerChrysler R&D Centre with DaimlerChrysler PEMFC hardware and a good agreement is found between model simulations and lab tests.

  1. Dynamic fuel cell stack model for real-time simulation based on system identification

    Energy Technology Data Exchange (ETDEWEB)

    Meiler, M.; Schmid, O.; Schudy, M. [Department of MEA and Stack Technology, DaimlerChrysler AG, Neue Str. 95, D-73230 Kirchheim/Teck (Germany); Hofer, E.P. [Department of Measurement, Control and Microtechnology, University of Ulm, Albert-Einstein-Allee 41, D-89081 Ulm (Germany)

    2008-02-01

    The authors have been developing an empirical mathematical model to predict the dynamic behaviour of a polymer electrolyte membrane fuel cell (PEMFC) stack. Today there is a great number of models, describing steady-state behaviour of fuel cells by estimating the equilibrium voltage for a certain set of operating parameters, but models capable of predicting the transient process between two steady-state points are rare. However, in automotive applications round about 80% of operating situations are dynamic. To improve the reliability of fuel cell systems by model-based control for real-time simulation dynamic fuel cell stack model is needed. Physical motivated models, described by differential equations, usually are complex and need a lot of computing time. To meet the real-time capability the focus is set on empirical models. Fuel cells are highly nonlinear systems, so often used auto-regressive (AR), output-error (OE) or Box-Jenkins (BJ) models do not accomplish satisfying accuracy. Best results are achieved by splitting the behaviour into a nonlinear static and a linear dynamic subsystem, a so-called Uryson-Model. For system identification and model validation load steps with different amplitudes are applied to the fuel cell stack at various operation points and the voltage response is recorded. The presented model is implemented in MATLAB environment and has a computing time of less than 1 ms per step on a standard desktop computer with a 2.8 MHz CPU and 504 MB RAM. Lab tests are carried out at DaimlerChrysler R and D Centre with DaimlerChrysler PEMFC hardware and a good agreement is found between model simulations and lab tests. (author)

  2. Thermal Property Simulation of Zr{sub O}2-based Nanocomposites for Inert Matrix Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Raj, Vivek Raj [Indian Institute of Technology-Kanpur, Kalyanpur (India); Mistarihi, Qusai M.; Ryu, Ho Jin [KAIST, Daejeon (Korea, Republic of)

    2015-05-15

    Inert matrix fuel (IMF) is a promising concept to incinerate TRU without further producing plutonium from U-238 which is a main host material for current nuclear fuels containing fissile isotopes such as U-235 or Pu-239. ZrO{sub 2} is one of the suitable materials for a matrix of IMF because it has an excellent chemical stability and an irradiation resistance. However, ZrO{sub 2} has a very low thermal conductivity around 3 W/mK at 1000 .deg. C which is not beneficial for the in-reactor fuel performances, and the low thermal conductivity might result in a high fission gas release and high fuel swelling. Therefore, enhancing the thermal conductivity of ZrO{sub 2} might be very effective in improving the fuel performance of ZrO{sub 2} based IMF. Metallic wires with a high thermal conductivity can be used as reinforcement for ZrO{sub 2}. In this study, Mo wire has been selected for the modeling and characterization of ZrO{sub 2}-based nanocomposites because Mo has a high thermal conductivity approximately 138 W/mK and a relatively low neutron absorption cross section. The experimental results and computational simulations presented a good agreement in estimating the effects of the reinforcement on the thermal conductivities of Mo reinforced ZrO{sub 2} nanocomposites. It is found that one of the most contributing factors to the enhancement of the thermal conductivity of ZrO{sub 2}-based nanocomposites is the interconnection of Mo wire.

  3. A PEM fuel cell based on electrocatalyst and membrane materials modified by PANAM dendrimers

    Energy Technology Data Exchange (ETDEWEB)

    Ledesma-Garcia, J.; Chapman, T.W.; Godinez, L.A. [Centro de Investigacion y Desarrollo Tecnologico en Electroquimica, Queretaro (Mexico)

    2008-10-15

    Due to its high energy conversion efficiency and low emission of pollutants, fuel-cell technology has been generally recognized as a key twenty-first century energy source. For polymer electrolyte membrane fuel cells (PEMFC), it has been found that platinum and its alloys exhibit the best electrocatalytic activity for oxygen reduction. The highest electrocatalytic activity of platinum and its alloys can be achieved when the particles are produced in the nanometer range. In this context, organic molecules have been adopted as templates to control the size of metal nanoparticles. Dendrimers, in particular, have shown promising properties for this application, and strategies that include direct adsorption, electrostatic attachment and covalent bonding have been developed for connecting metal-bearing dendrimers to conducting substrates. This paper reported on the preliminary results of a study that involved the construction and testing of a hydrogen-oxygen PEM fuel cell based on carbon-fiber-paper electrodes coated with hydroxyl-terminated dendrimers that encapsulated nanoparticles of platinum. This prototype cell also employed an ion exchange membrane comprising a cellulose acetate filter functionalized with proton-exchanging dendrimers. A proton-exchange membrane was prepared by binding duplex amine-carboxylate dendrimers to a cellulose-acetate support. With these dendrimer-based materials, a hydrogen-oxygen fuel cell was assembled and the performance compared with cells prepared with Nafion-based membranes. The voltage-current profiles and the power-density curves from the new cell provide encouragement to continue work with these dendrimer-modified materials. The paper discussed the experimental methods, with particular reference to materials; electrode preparation and characterization; proton-exchange membrane preparation; and PEM fuel-cell assembly and testing. It was concluded that the use of the dendritic macromolecules as supports for the nanoparticulate

  4. Nanostructure-based proton exchange membrane for fuel cell applications at high temperature.

    Science.gov (United States)

    Li, Junsheng; Wang, Zhengbang; Li, Junrui; Pan, Mu; Tang, Haolin

    2014-02-01

    As a clean and highly efficient energy source, the proton exchange membrane fuel cell (PEMFC) has been considered an ideal alternative to traditional fossil energy sources. Great efforts have been devoted to realizing the commercialization of the PEMFC in the past decade. To eliminate some technical problems that are associated with the low-temperature operation (such as catalyst poisoning and poor water management), PEMFCs are usually operated at elevated temperatures (e.g., > 100 degrees C). However, traditional proton exchange membrane (PEM) shows poor performance at elevated temperature. To achieve a high-performance PEM for high temperature fuel cell applications, novel PEMs, which are based on nanostructures, have been developed recently. In this review, we discuss and summarize the methods for fabricating the nanostructure-based PEMs for PEMFC operated at elevated temperatures and the high temperature performance of these PEMs. We also give an outlook on the rational design and development of the nanostructure-based PEMs.

  5. Non-Petroleum-Based Fuels: Report on the Relationship Between Molecular Structure and Compression Ignition Fuels, Both Conventional and HCCI

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, Joshua [National Renewable Energy Lab. (NREL), Golden, CO (United States); McCormick, Robert [National Renewable Energy Lab. (NREL), Golden, CO (United States); Clark, Wendy [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2004-08-01

    The U.S. Department of Energy (DOE) is committed to increasing our nation’s energy security by decreasing our dependence on imported petroleum. The Fuels Technologies Subprogram within DOE’s Office of Freedom Car and Vehicle Technology (OFCVT) supports research that allows the United States to develop advanced fuels that enable efficient engines with low emissions. This document reports the completion of NREL FY 2004 Annual Operating Plan milestone 10.2: “Report on the relationship between molecular structure and compression ignition fuels, both conventional and HCCI.” This work is an incremental step toward the OFCVT Multi-Year Program Plan APBF/NPBF Milestone No. 3: “Establish fuel and lubricant constituents that are required for advanced combustion regime engines.”

  6. Desulfurization of fuels with calcium-based sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Abbasian, J.; Rehmat, A.; Leppin, D.; Banerjee, D.D. (Institute of Gas Technology, Chicago, IL (USA))

    1990-04-01

    Calcium-based sorbents, such as limestone and dolomite, are viable candidates for sulphur-capturing agents in an in-situ coal gasification/desulfurization process. The effect of limestone addition on the hydrodynamics of a fluidized-bed gasifier, desulfurization of the product gas, and stabilization of the solid wastes have been studied. The hydrodynamic characteristics of coal char/limestone mixtures, such as mixing and fines retention, have been studied in a 0.2 m diameter fluidization column. Kinetic data pertaining to the reaction between calcium oxide (which is obtained by calcination of limestone and dolomite) and hydrogen sulfide have been obtained by a gravimetric technique in the temperature range of 650 to 1050{degree}C. Kinetic data relating to the reaction between calcium sulfide (which is obtained by sulfidation of calcium-based sorbents) and oxygen have been obtained in the temperature range of 800 to 1050{degree}C and in the pressure range of 2 to 3.1 MPa. The operating conditions for these reactions have been chosen to be within the application range of a commercial coal gasification process that is accompanied by in situ desulfurization. 14 refs., 8 figs., 7 tabs.

  7. Potential of thorium-based fuel cycle for PWR core to reduce plutonium and long-term toxicity

    Energy Technology Data Exchange (ETDEWEB)

    Joo, Hyung Kook; Kim, Taek Kyum; Kim, Young Jin [Korea Atomic Energy Research Institute, Taejon (Korea)

    1999-01-01

    The cross section libraries and calculation methods of the participants were inter-compared through the first stage benchmark calculation. The multiplication factor of unit cell benchmark are in good agreement, but there is significant discrepancies of 2.3 to 3.5 %k at BOC and at EOC between the calculated infinite multiplication factors of each participants for the assembly benchmark. Our results with HELIOS show a reasonable agreement with the others except the MTC value at EOC. To verify the potential of the thorium-based fuel to consume the plutonium and to reduce the radioactivity from the spent fuel, the conceptual core with ThO{sub 2}-PuO{sub 2} or MOX fuel were constructed. The composition and quantity of plutonium isotopes and the radioactivity level of spent fuel for conceptual cores were analyzed, and the neutronic characteristics of conceptual cores were also calculated. The nuclear characteristics for ThO{sub 2}-PuO{sub 2} thorium fueled core was similar to MOX fueled core, mainly due to the same seed fuel material, plutonium. For the capability of plutonium consumption, ThO{sub 2}-PuO{sub 2} thorium fuel can consume plutonium 2.1-2.4 times MOX fuel. The fraction of fissile plutonium in the spent ThO{sub 2}-PuO{sub 2} thorium fuel is more favorable in view of plutonium consumption and non-proliferation than MOX fuel. The radioactivity of spent ThO{sub 2}-PuO{sub 2} thorium and MOX fuel batches were calculated. Since plutonium isotopes are dominant for the long-term radioactivity, ThO{sub 2}-PuO{sub 2} thorium has almost the same level of radioactivity as in MOX fuel for a long-term perspective. (author). 22 figs., 11 tabs.

  8. Evaluation of improved materials for stationary diesel engines operating on residual and coal based fuels. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1980-01-01

    Experimental results to date from an on-going research program on improved materials for stationary diesel engines using residual or coal-based fuels are presented with little discussion of conclusions about these results. Information is included on ring and liner wear, fuel oil qualities, ceramic materials, coatings, test procedures and equipment, and tribology test results. (LCL)

  9. ASSESSMENT OF POSSIBLE CYCLE LENGTHS FOR FULLY-CERAMIC MICRO-ENCAPSULATED FUEL-BASED LIGHT WATER REACTOR CONCEPTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Sonat Sen; Michael A. Pope; Abderrafi M. Ougouag; Kemal Pasamehmetoglu; Francesco Venneri

    2012-04-01

    The use of TRISO-particle-based dispersion fuel within SiC matrix and cladding materials has the potential to allow the design of extremely safe LWRs with failure-proof fuel. This paper examines the feasibility of LWR-like cycle length for such a low enriched uranium fuel with the imposed constraint of strictly retaining the original geometry of the fuel pins and assemblies. The motivation for retaining the original geometry is to provide the ability to incorporate the fuel 'as-is' into existing LWRs while retaining their thermal-hydraulic characteristics. The feasibility of using this fuel is assessed by looking at cycle lengths and fuel failure rates. Other considerations (e.g., safety parameters, etc.) were not considered at this stage of the study. The study includes the examination of different TRISO kernel diameters without changing the coating layer thicknesses. The study shows that a naive use of UO{sub 2} results in cycle lengths too short to be practical for existing LWR designs and operational demands. Increasing fissile inventory within the fuel compacts shows that acceptable cycle lengths can be achieved. In this study, starting with the recognized highest packing fraction practically achievable (44%), higher enrichment, larger fuel kernel sizes, and the use of higher density fuels have been evaluated. The models demonstrate cycle lengths comparable to those of ordinary LWRs. As expected, TRISO particles with extremely large kernels are shown to fail under all considered scenarios. In contrast, the designs that do not depart too drastically from those of the nominal NGNP HTR fuel TRISO particles are shown to perform satisfactorily and display a high rates of survival under all considered scenarios. Finally, it is recognized that relaxing the geometry constraint will result in satisfactory cycle lengths even using UO{sub 2}-loaded TRISO particles-based fuel with enrichment at or below 20 w/o.

  10. Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells.

    Science.gov (United States)

    Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel; Larouche, Nicholas; Tian, Juan; Herranz, Juan; Dodelet, Jean-Pol

    2011-08-02

    H(2)-air polymer-electrolyte-membrane fuel cells are electrochemical power generators with potential vehicle propulsion applications. To help reduce their cost and encourage widespread use, research has focused on replacing the expensive Pt-based electrocatalysts in polymer-electrolyte-membrane fuel cells with a lower-cost alternative. Fe-based cathode catalysts are promising contenders, but their power density has been low compared with Pt-based cathodes, largely due to poor mass-transport properties. Here we report an iron-acetate/phenanthroline/zeolitic-imidazolate-framework-derived electrocatalyst with increased volumetric activity and enhanced mass-transport properties. The zeolitic-imidazolate-framework serves as a microporous host for phenanthroline and ferrous acetate to form a catalyst precursor that is subsequently heat treated. A cathode made with the best electrocatalyst from this work, tested in H(2)-O(2,) has a power density of 0.75 W cm(-2) at 0.6 V, a meaningful voltage for polymer-electrolyte-membrane fuel cells operation, comparable with that of a commercial Pt-based cathode tested under identical conditions.

  11. Testing of Paraffin-based Hybrid Rocket Fuel using Gaseous Oxygen Oxidiser

    Directory of Open Access Journals (Sweden)

    Yash Pal

    2012-09-01

    Full Text Available A series of paraffin-based hybrid rocket fuel has been studied experimentally in a laboratory-scale motor. To enhance the regression rate of paraffin solid fuel, three types of grain configurations: Cylindrical, star, and helical grain configurations of paraffin wax have been developed and tested with gaseous oxygen. The helical fuel grain presented best performance among all the test ports. About 40.2 per cent and 20.6 per cent regression rates are increased by burning paraffin fuel with helical and star grain configuration respectively, as compared to cylindrical grain configuration at Gox=0.0191 g/mm2s. The regression rates were significantly influenced by the oxygen injection pressure varied between 344.7 kPa and 620.5 kPa. Furthermore, the experimentally obtained exponents of oxidizer mass flux for all three grain configurations have been found to be significantly different from those of the classical hybrid system. Finally, thrust-time traces for all three grain configurations were also studied. The result shown no significant increase or decrease in the amplitude of the thrust oscillations.Defence Science Journal, 2012, 62(5, pp.277-283, DOI:http://dx.doi.org/10.14429/dsj.62.2346

  12. Testing of Paraffin-based Hybrid Rocket Fuel using Gaseous Oxygen Oxidiser

    Directory of Open Access Journals (Sweden)

    Yash Pal

    2012-07-01

    Full Text Available A series of paraffin-based hybrid rocket fuel has been studied experimentally in a laboratory-scale motor. To enhance the regression rate of paraffin solid fuel, three types of grain configurations: Cylindrical, star, and helical grain configurations of paraffin wax have been developed and tested with gaseous oxygen. The helical fuel grain presented best performance among all the test ports. About 40.2 per cent and 20.6 per cent regression rates are increased by burning paraffin fuel with helical and star grain configuration respectively, as compared to cylindrical grain configuration at Gox=0.0191 g/mm2s. The regression rates were significantly influenced by the oxygen injection pressure varied between 344.7 kPa and 620.5 kPa. Furthermore, the experimentally obtained exponents of oxidizer mass flux for all three grain configurations have been found to be significantly different from those of the classical hybrid system. Finally, thrust-time traces for all three grain configurations were also studied. The result shown no significant increase or decrease in the amplitude of the thrust oscillations.

  13. An Electrical Energy Storage System Based on Solid Oxide Fuel Cells

    Science.gov (United States)

    Luo, T.; Shao, L.; Qian, J. Q.; Wang, S. R.; Zhan, Z. L.

    2013-07-01

    This work studies a proof-of-concept integrated electrical energy storage system of solid oxide fuel cell (SOFC) by using Fe as original fuel and Ca(OH)2 as additive. The design and operation of this cell are based on a conventional anode-supported tubular SOFC, with Ni-SSZ, SSZ, and SSZ-LSM as anode, electrolyte and cathode, respectively. In this design, Fe reacts with H2O generated from the decomposition of Ca(OH)2 at high temperature, as a result, H2 is produced in situ as SOFC fuel. The charging process is realized by electrolysis of water in the SOEC mode along with the reduction of Fe3O4 by the generated H2. It is demonstrated that the open circuit voltage (OCV) for the Fe-Fe3O4 system is above 1.0V at 1073K. By using such fuel, the maximum power density of 124 mW cm-2 has been achieved. Two stable charge/discharge cycles have been tested. Combined with the advantages of environmental friendliness, sustainability promise and excellent performance, the novel SOFC system will be a new choice of grid-scale energy storage.

  14. Prognostics of Proton Exchange Membrane Fuel Cells stack using an ensemble of constraints based connectionist networks

    Science.gov (United States)

    Javed, Kamran; Gouriveau, Rafael; Zerhouni, Noureddine; Hissel, Daniel

    2016-08-01

    Proton Exchange Membrane Fuel Cell (PEMFC) is considered the most versatile among available fuel cell technologies, which qualify for diverse applications. However, the large-scale industrial deployment of PEMFCs is limited due to their short life span and high exploitation costs. Therefore, ensuring fuel cell service for a long duration is of vital importance, which has led to Prognostics and Health Management of fuel cells. More precisely, prognostics of PEMFC is major area of focus nowadays, which aims at identifying degradation of PEMFC stack at early stages and estimating its Remaining Useful Life (RUL) for life cycle management. This paper presents a data-driven approach for prognostics of PEMFC stack using an ensemble of constraint based Summation Wavelet- Extreme Learning Machine (SW-ELM) models. This development aim at improving the robustness and applicability of prognostics of PEMFC for an online application, with limited learning data. The proposed approach is applied to real data from two different PEMFC stacks and compared with ensembles of well known connectionist algorithms. The results comparison on long-term prognostics of both PEMFC stacks validates our proposition.

  15. Novel Processing of Unique Ceramic-Based Nuclear Materials and Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Hui Zhang; Raman P. Singh

    2008-11-30

    Advances in nuclear reactor technology and the use of gas-cooled fast reactors require the development of new materials that can operate at the higher temperatures expected in these systems. These include refractory alloys base on Nb, Zr, Ta, Mo, W, and Re; ceramics and composites such as those based on silicon carbide (SiCf-SiC); carbon-carbon composites; and advanced coatings. Besides the ability to handle higher expected temperatures, effective heat transfer between reactor componets is necessary for improved efficiency. Improving thermal conductivity of the materials used in nuclear fuels and other temperature critical components can lower the center-line fuel temperature and thereby enhance durability and reduce the risk of premature failure.

  16. Solid oxide fuel cell anode image segmentation based on a novel quantum-inspired fuzzy clustering

    Science.gov (United States)

    Fu, Xiaowei; Xiang, Yuhan; Chen, Li; Xu, Xin; Li, Xi

    2015-12-01

    High quality microstructure modeling can optimize the design of fuel cells. For three-phase accurate identification of Solid Oxide Fuel Cell (SOFC) microstructure, this paper proposes a novel image segmentation method on YSZ/Ni anode Optical Microscopic (OM) images. According to Quantum Signal Processing (QSP), the proposed approach exploits a quantum-inspired adaptive fuzziness factor to adaptively estimate the energy function in the fuzzy system based on Markov Random Filed (MRF). Before defuzzification, a quantum-inspired probability distribution based on distance and gray correction is proposed, which can adaptively adjust the inaccurate probability estimation of uncertain points caused by noises and edge points. In this study, the proposed method improves accuracy and effectiveness of three-phase identification on the micro-investigation. It provides firm foundation to investigate the microstructural evolution and its related properties.

  17. Terminology used for renewable liquid and gaseous fuels based on the conversion of electricity: a review

    DEFF Research Database (Denmark)

    Ridjan, Iva; Mathiesen, Brian Vad; Connolly, David

    2016-01-01

    As the transport sector transitions away from fossil fuels and renewable fuels shift into focus, it is important that the terminology around renewable fuels is clarified. A number of terms such as synthetic fuel and electrofuel are used to describe both renewable and alternative fuels. The aim of...

  18. Graphene oxide based nanohybrid proton exchange membranes for fuel cell applications: An overview.

    Science.gov (United States)

    Pandey, Ravi P; Shukla, Geetanjali; Manohar, Murli; Shahi, Vinod K

    2017-02-01

    In the context of many applications, such as polymer composites, energy-related materials, sensors, 'paper'-like materials, field-effect transistors (FET), and biomedical applications, chemically modified graphene was broadly studied during the last decade, due to its excellent electrical, mechanical, and thermal properties. The presence of reactive oxygen functional groups in the grapheme oxide (GO) responsible for chemical functionalization makes it a good candidate for diversified applications. The main objectives for developing a GO based nanohybrid proton exchange membrane (PEM) include: improved self-humidification (water retention ability), reduced fuel crossover (electro-osmotic drag), improved stabilities (mechanical, thermal, and chemical), enhanced proton conductivity, and processability for the preparation of membrane-electrode assembly. Research carried on this topic may be divided into protocols for covalent grafting of functional groups on GO matrix, preparation of free-standing PEM or choice of suitable polymer matrix, covalent or hydrogen bonding between GO and polymer matrix etc. Herein, we present a brief literature survey on GO based nano-hybrid PEM for fuel cell applications. Different protocols were adopted to produce functionalized GO based materials and prepare their free-standing film or disperse these materials in various polymer matrices with suitable interactions. This review article critically discussed the suitability of these PEMs for fuel cell applications in terms of the dependency of the intrinsic properties of nanohybrid PEMs. Potential applications of these nanohybrid PEMs, and current challenges are also provided along with future guidelines for developing GO based nanohybrid PEMs as promising materials for fuel cell applications.

  19. Fuel Cell Power Plant Initiative. Volume 2; Preliminary Design of a Fixed-Base LFP/SOFC Power System

    Science.gov (United States)

    Veyo, S.E.

    1997-01-01

    This report documents the preliminary design for a military fixed-base power system of 3 MWe nominal capacity using Westinghouse's tubular Solid Oxide Fuel Cell [SOFC] and Haldor Topsoe's logistic fuels processor [LFP]. The LFP provides to the fuel cell a methane rich sulfur free fuel stream derived from either DF-2 diesel fuel, or JP-8 turbine fuel. Fuel cells are electrochemical devices that directly convert the chemical energy contained in fuels such as hydrogen, natural gas, or coal gas into electricity at high efficiency with no intermediate heat engine or dynamo. The SOFC is distinguished from other fuel cell types by its solid state ceramic structure and its high operating temperature, nominally 1000'C. The SOFC pioneered by Westinghouse has a tubular geometry closed at one end. A power generation stack is formed by aggregating many cells in an ordered array. The Westinghouse stack design is distinguished from other fuel cell stacks by the complete absence of high integrity seals between cell elements, cells, and between stack and manifolds. Further, the reformer for natural gas [predominantly methane] and the stack are thermally and hydraulically integrated with no requirement for process water. The technical viability of combining the tubular SOFC and a logistic fuels processor was demonstrated at 27 kWe scale in a test program sponsored by the Advanced Research Projects Agency [ARPA) and carried out at the Southern California Edison's [SCE] Highgrove generating station near San Bernardino, California in 1994/95. The LFP was a breadboard design supplied by Haldor Topsoe, Inc. under subcontract to Westinghouse. The test program was completely successful. The LFP fueled the SOFC for 766 hours on JP-8 and 1555 hours of DF-2. In addition, the fuel cell operated for 3261 hours on pipeline natural gas. Over the 5582 hours of operation, the SOFC generated 118 MVVH of electricity with no perceptible degradation in performance. The LFP processed military

  20. Modeling Ozone in the Eastern United States Using a Fuel-Based Mobile Source Emissions Inventory

    Science.gov (United States)

    Mcdonald, B. C.; Ahmadov, R.; McKeen, S. A.; Kim, S. W.; Frost, G. J.; Trainer, M.

    2015-12-01

    A fuel-based mobile source emissions inventory of nitrogen oxides (NOx) and carbon monoxide (CO) is developed for the continental US. Emissions are mapped for the year 2013, including emissions from on-road gasoline and diesel vehicles, and off-road engines. We find that mobile source emissions of NOx in the National Emissions Inventory 2011 (NEI11) are 50-60% higher than results from this study; mobile sources contribute around half of total US anthropogenic NOx emissions. We model chemistry and transport of emissions from the NEI11 and our fuel-based inventory during the Southeast Nexus (SENEX) Study period in the summer of 2013, using the Weather Research and Forecasting with Chemistry (WRF-Chem) model. In the Eastern US, there is a consistent over-prediction of tropospheric ozone (O3) levels when simulating emissions from the NEI11, with the largest biases located in the Southeastern US. Using our fuel-based inventory, we test O3 sensitivity to lower NOx emissions. We highlight results in the Southeast, a region with significant interactions between anthropogenic and biogenic emissions of ozone precursors. Model results of NOy, CO, and O3 are compared with aircraft measurements made during SENEX.

  1. Metal based gas diffusion layers for enhanced fuel cell performance at high current densities

    Science.gov (United States)

    Hussain, Nabeel; Van Steen, Eric; Tanaka, Shiro; Levecque, Pieter

    2017-01-01

    The gas diffusion layer strongly influences the performance and durability of polymer electrolyte fuel cells. A major drawback of current carbon fiber based GDLs is the non-controlled variation in porosity resulting in a random micro-structure. Moreover, when subjected to compression these materials show significant reduction in porosity and permeability leading to water management problems and mass transfer losses within the fuel cell. This study investigated the use of uniform perforated metal sheets as GDLs in conjunction with microchannel flowfields. A metal sheet design with a pitch of 110 μm and a hole diameter of 60 μm in combination with an MPL showed superior performance in the high current density region compared to a commercially available carbon paper based GDL in a single cell environment. Fuel cell testing with different oxidants (air, heliox and oxygen) indicate that the metal sheet offers both superior diffusion and reduced flooding in comparison to the carbon based GDL. The presence of the MPL has been found to be critical to the functionality of the metal sheet suggesting that the MPL design may represent an important optimisation parameter for further improvements in performance.

  2. Energy, Environment, Economic Life Cycle Assessment of Cassava-based Ethanol Used as Automotive Fuel in Guangxi Province, China

    Institute of Scientific and Technical Information of China (English)

    HU Zhi-yuan; ZHANG Cheng; PU Geng-qiang; WANG Cheng-tao

    2005-01-01

    A life-cycle assessment (LCA) was carried out to compare the energy, environmental and economic impacts of converting cassava to fuel ethanol in Guangxi Province, China. The entire life cycle is a system that includes stages from cassava farming to ethanol fuel combustion. A computer-based model was developed to assess energy, environmental, and economic (EEE) life cycle implication of cassava-based ethanol fuel. The LCA results for fuel ethanol were compared to conventional gasoline (CG) as a base-line case. On the life-cycle bases, the use of cassava-based ethanol fuel in Guangxi may consume more energy but reduce greenhouse gas, VOC, and CO emissions. Life cycle cost results indicate that although fuel ethanol currently is not competitive compared to conventional gasoline, it has great potentials when there are subsidies and/or yields of cassava planting are improved. In terms of balancing the energy, environmental and economical, the introduction form of cassavabased ethanol fuel would be E10. The assessment results generated from this study provide an important reference for Guangxi policy makers to better understand the trade-offs among energy, environmental effects, and economics for the most effective using of regional energy resources.

  3. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 15, October--December 1992

    Energy Technology Data Exchange (ETDEWEB)

    Chow, O.K.; Nsakala, N.Y.

    1993-03-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. During the third quarter of 1992, the following technical progress was made: Continued analyses of drop tube furnace samples to determine devolatilization kinetics; re-analyzed the samples from the pilot-scale ash deposition tests of the first nine feed coals and BCFs using a modified CCSEM technique; updated the topical summary report; and prepared for upcoming tests of new BCFs being produced.

  4. Fuel cycle analysis based evaluation of the fuel and emissions reduction potential of adapting the hybrid technology to tricycles

    Energy Technology Data Exchange (ETDEWEB)

    Biona, J.B.M. [Don Bosco Technical College, Mandaluyong City (Philippines); De La Salle University, Center for Engineering and Sustainable Development Research, Manila (Philippines); Culaba, A.B. [De La Salle University, Center for Engineering and Sustainable Development Research, Manila (Philippines); Purvis, M.R.I. [University of Portsmouth, Department of Mechanical Design and Engineering, Portsmouth (United Kingdom)

    2008-02-15

    A preliminary analysis has been conducted to investigate the fuel use and emissions reduction potential of incorporating hybrid systems to two stroke powered tricycles in Metro Manila. Carbureted and direct injection two stroke engine hybrid systems were investigated and compared with the impact of shifting to four stroke engines. Results showed that hybridized direct injection retrofitted two stroke powered systems would be able to provide far better environmental and fuel reduction benefits than the shift to new four strokes tricycles. It is thus recommended that the development of such technology specifically for tricycles be seriously pursued. (orig.)

  5. Characterization of spent fuel elements stored at IEA-R1 research reactor based on visual inspections and sipping tests

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Jose Eduardo Rosa da; Terremoto, Luis Antonio Albiac; Teodoro, Celso Antonio; Castanheira, Myrthes; Lucki, Georgi; Damy, Margaret de Almeida; Silva, Antonio Teixeira e [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)]. E-mail: jersilva@ipen.br

    2005-07-01

    Aluminum spent nuclear fuels are susceptible to corrosion attack, or mechanical damage from improper handling, while in pool reactor storage. Storage practices have been modified to reduce the potential for damage, based on recommendations presented at second WS on Spent Fuel Characterization, promoted by IAEA. In this work, we present the inspection program proposed to the IEA-R1 stored spent fuel elements, in order to provide information on the physical condition during the interim storage time under wet condition at the reactor pool. The inspection program is based on non-destructive tests results (visual inspection and sipping tests) already periodically performed to exam the IEA-R1 stored spent fuel and fuel elements from the core reactor. To record the available information and examination results it was elaborated a document in the format of a catalogue containing the proposed inspection program for the IEA-R1 stored spent fuel, the description of the visual inspection and sipping tests systems, a compilation of information and images result from the tests performed for all stored standard spent fuel element and, in annexes, copies of the reference documents. That document constitutes an important step of the effective implementation of the referred IEA-R1 spent fuel inspection program and can be used to address regulatory and operational needs for the demonstration, for example, of safe storage throughout the pool storage period. (author)

  6. Fuel lattice design in a boiling water reactor using an ant-colony-based system

    Energy Technology Data Exchange (ETDEWEB)

    Montes, Jose Luis, E-mail: joseluis.montes@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Carr. Mexico-Toluca S/N, La Marquesa, Ocoyoacac, Estado de Mexico, CP 52750 (Mexico); Facultad de Ciencias, Universidad Autonoma del Estado de Mexico (Mexico); Francois, Juan-Luis, E-mail: juan.luis.francois@gmail.com [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532, Jiutepec, Mor., CP 62550 (Mexico); Ortiz, Juan Jose, E-mail: juanjose.ortiz@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Carr. Mexico-Toluca S/N, La Marquesa, Ocoyoacac, Estado de Mexico, CP 52750 (Mexico); Martin-del-Campo, Cecilia, E-mail: cecilia.martin.del.campo@gmail.com [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532, Jiutepec, Mor., CP 62550 (Mexico); Perusquia, Raul, E-mail: raul.perusquia@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Carr. Mexico-Toluca S/N, La Marquesa, Ocoyoacac, Estado de Mexico, CP 52750 (Mexico)

    2011-06-15

    Research highlights: > We present an ant-colony-based system for BWR fuel lattice design and optimization. > Assessment of candidate solutions at 0.0 MWd/kg {sup 235}U seems to have a limited scope. > Suitable heuristic rules enable more realistic fuel lattice designs. > The election of the objective has a large impact in CPU time. > ACS enables an important decrease of the initial average U-235 enrichment. - Abstract: This paper presents a new approach to deal with the boiling water reactor radial fuel lattice design. The goal is to optimize the distribution of both, the fissionable material, and the reactivity control poison material inside the fuel lattice at the beginning of its life. An ant-colony-based system was used to search for either: the optimum location of the poisoned pin inside the lattice, or the U{sup 235} enrichment and Gd{sub 2}O{sub 3} concentrations. In the optimization process, in order to know the parameters of the candidate solutions, the neutronic simulator CASMO-4 transport code was used. A typical 10 x 10 BWR fuel lattice with an initial average U{sup 235} enrichment of 4.1%, used in the current operation of Laguna Verde Nuclear Power Plant was taken as a reference. With respect to that reference lattice, it was possible to decrease the average U{sup 235} enrichment up to 3.949%, this obtained value represents a decrease of 3.84% with respect to the reference U{sup 235} enrichment; whereas, the k-infinity was inside the {+-}100 pcm's range, and there was a difference of 0.94% between the local power peaking factor and the lattice reference value. Particular emphasis was made on defining the objective function which is used for making the assessment of candidate solutions. In a typical desktop personal computer, about four hours of CPU time were necessary for the algorithm to fulfill the goals of the optimization process. The results obtained with the application of the implemented system showed that the proposed approach represents a

  7. Thorium-Based Fuel Cycles in the Modular High Temperature Reactor

    Institute of Scientific and Technical Information of China (English)

    CHANG Hong; YANG Yongwei; JING Xingqing; XU Yunlin

    2006-01-01

    Large stockpiles of civil-grade as well as weapons-grade plutonium have been accumulated in the world from nuclear power or other programs of different countries. One alternative for the management of the plutonium is to incinerate it in the high temperature reactor (HTR). The thorium-based fuel cycle was studied in the modular HTR to reduce weapons-grade plutonium stockpiles, while producing no additional plutonium or other transuranic elements. Three thorium-uranium fuel cycles were also investigated. The thorium absorption cross sections of the resolved and unresolved resonances were generated using the ZUT-DGL code based on existing resonance data. The equilibrium core of the modular HTR was calculated and analyzed by means of the code VSOP'94. The results show that the modular HTR can incinerate most of the initially loaded plutonium amounting to about 95.3% net 239Pu for weapons-grade plutonium and can effectively utilize the uranium and thorium in the thorium-uranium fuel cycles.

  8. Vacuum extraction based response equipment for recovery of fresh fuel spills from soil.

    Science.gov (United States)

    Halmemies, Sakari; Gröndahl, Siri; Arffman, Mika; Nenonen, Keijo; Tuhkanen, Tuula

    2003-02-28

    Accidental overturns of fuel tankers can have, depending on soil types, severe consequences. This applies, particularly in areas of shallow soils where the groundwater is located 2-4m below the ground surface. By rapid, vacuum extraction based recovery emergency services, which would normally be the first to arrive on the scene, could minimize consequences of fresh fuel spills and even prevent groundwater contamination, the primary purpose of emergency response. Powerful vacuum extraction-based response (PER), equipment has been developed to recover freshly spilt volatile fuels from the soil, primary by emergency services, but also by other trained responders. The main components of mobile PER-equipment are perforated extraction pipes, a recovery vacuum tank, a vacuum pump and an incinerator. The PER-equipment has been tested in summer and sub-zero winter conditions, and in both cases 50-80% of fresh gasoline spilled into sandy soil was recovered during the first 2h of operation. Gasoline was recovered in both liquid and vapor form, and hydrocarbon vapors were destroyed by controlled incineration at a safe distance from the spill. Recovery of less volatile diesel oil is not so effective from the sandy soil, but about 30% of it could be pumped from a fresh pool directly after a seepage time of 15 min.

  9. STEAM AND SOFC BASED REFORMING OPTIONS OF PEM FUEL CELLS FOR MARINE APPLICATIONS

    Directory of Open Access Journals (Sweden)

    Mohamed M. El Gohary

    2015-06-01

    Full Text Available The need for green energy sources without or with low emissions in addition to improve the using efficiency of current fossil fuels in the marine field makes it important to replace or improve current fossil-fuelled engines. The replacement process should work on narrowing the gap between the most scientific innovative clean energy technologies and the concepts of feasibility and cost-effective solutions. Early expectations of very low emissions and relatively high efficiencies have been met in marine power plants using fuel cell. In this study, steam and SOFC based reforming options of natural gas for PEM fuel cells are proposed as an attractive option to limit the environmental impact of the marine sector. The benefits of these two different reforming options can be assessed using computer predictions incorporating chemical flow sheeting software. It is found that a high overall efficiency approaching 60% may be achieved using SOFC based reforming systems which are significantly better than a reformed PEM system or an SOFC only system.

  10. Small Scale SOFC Demonstration Using Bio-Based and Fossil Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Petrik, Michael [Technology Management Inc., Cleveland, OH (United States); Ruhl, Robert [Technology Management Inc., Cleveland, OH (United States)

    2012-05-01

    Technology Management, Inc. (TMI) of Cleveland, Ohio, has completed the project entitled Small Scale SOFC Demonstration using Bio-based and Fossil Fuels. Under this program, two 1-kW systems were engineered as technology demonstrators of an advanced technology that can operate on either traditional hydrocarbon fuels or renewable biofuels. The systems were demonstrated at Patterson's Fruit Farm of Chesterland, OH and were open to the public during the first quarter of 2012. As a result of the demonstration, TMI received quantitative feedback on operation of the systems as well as qualitative assessments from customers. Based on the test results, TMI believes that > 30% net electrical efficiency at 1 kW on both traditional and renewable fuels with a reasonable entry price is obtainable. The demonstration and analysis provide the confidence that a 1 kW entry-level system offers a viable value proposition, but additional modifications are warranted to reduce sound and increase reliability before full commercial acceptance.

  11. Co-generation of acetylene and hydrogen for a carbide-based fuel system

    Energy Technology Data Exchange (ETDEWEB)

    Carreiro, Louis G.; Burke, A. Alan [Naval Undersea Warfare Center Division Newport, Code 8231, 1176 Howell Street, Newport, RI 02841 (United States); Dubois, Lily [Stonehill College, Department of Chemistry, 320 Washington Street, Easton, MA 02357 (United States)

    2010-09-15

    The co-generation of acetylene and hydrogen from the hydrolysis of calcium carbide and calcium hydride was investigated as part of a unique carbide-based fuel system intended for high-temperature fuel cells. To gain better control of this highly energetic reaction, glycerin was used to coat the reactant particles to form slurry prior to their reaction with water. This process was shown to moderate the rate of gas production, as well as to provide a means for preparing slurry that could be pumped into the reactor vessel. It was also observed that the presence of calcium hydroxide, a by-product of hydrolysis, lowered the solubility of acetylene resulting in a higher initial flow rate due to less acetylene being dissolved in solution. However, the buildup of calcium hydroxide with time inhibited the hydrolysis of both calcium carbide and calcium hydride causing the acetylene and hydrogen flow rates to decrease. (author)

  12. Innovative Household Systems Based on Solid Oxide Fuel Cells for a Northern European climate

    DEFF Research Database (Denmark)

    Rokni, Masoud; Vialetto, Giulio

    2015-01-01

    Energy saving is an open point in most European countries where energy policies are oriented to reduce the use of fossil fuels, greenhouses emissions and energy independence and to increase the use of renewable energies. In the last several years, new technologies have been developed, and some...... of them received subsidies to increase installation and reduce cost.This article presents an innovative cogeneration system based on a solid oxide fuel cell (SOFC) systemand heat pump for household applications with a focus on primary energy and economic savings using electric equivalent load parameter...... which is a function of the electricity and heat demand of the user, and allows different operation strategies to be considered. The proposal is to maximize the efficiency of the system and to make it profitable, even though technologies with a high purchase cost are considered.Simulations of the system...

  13. Catalyst Degradation in High Temperature Proton Exchange Membrane Fuel Cells Based on Acid Doped Polybenzimidazole Membranes

    DEFF Research Database (Denmark)

    Cleemann, Lars Nilausen; Buazar, F.; Li, Qingfeng;

    2013-01-01

    Degradation of carbon supported platinum catalysts is a major failure mode for the long term durability of high temperature proton exchange membrane fuel cells based on phosphoric acid doped polybenzimidazole membranes. With Vulcan carbon black as a reference, thermally treated carbon black...... and multi‐walled carbon nanotubes were used as supports for electrode catalysts and evaluated in accelerated durability tests under potential cycling at 150 °C. Measurements of open circuit voltage, area specific resistance and hydrogen permeation through the membrane were carried out, indicating little...... contribution of the membrane degradation to the performance losses during the potential cycling tests. As the major mechanism of the fuel cell performance degradation, the electrochemical active area of the cathodic catalysts showed a steady decrease in the cyclic voltammetric measurements, which was also...

  14. Prediction Study on PCI Failure of Reactor Fuel Based on a Radial Basis Function Neural Network

    Directory of Open Access Journals (Sweden)

    Xinyu Wei

    2016-01-01

    Full Text Available Pellet-clad interaction (PCI is one of the major issues in fuel rod design and reactor core operation in water cooled reactors. The prediction of fuel rod failure by PCI is studied in this paper by the method of radial basis function neural network (RBFNN. The neural network is built through the analysis of the existing experimental data. It is concluded that it is a suitable way to reduce the calculation complexity. A self-organized RBFNN is used in our study, which can vary its structure dynamically in order to maintain the prediction accuracy. For the purpose of the appropriate network complexity and overall computational efficiency, the hidden neurons in the RBFNN can be changed online based on the neuron activity and mutual information. The presented method is tested by the experimental data from the reference, and the results demonstrate its effectiveness.

  15. High temperature proton exchange membranes based on polybenzimidazoles for fuel cells

    DEFF Research Database (Denmark)

    Li, Qingfeng; Jensen, Jens Oluf; Savinell, Robert F

    2009-01-01

    To achieve high temperature operation of proton exchange membrane fuel cells (PEMFC), preferably under ambient pressure, acid–base polymer membranes represent an effective approach. The phosphoric acid-doped polybenzimidazole membrane seems so far the most successful system in the field. It has...... in recent years motivated extensive research activities with great progress. This treatise is devoted to updating the development, covering polymer synthesis, membrane casting, physicochemical characterizations and fuel cell technologies. To optimize the membrane properties, high molecular weight polymers...... with synthetically modified or N-substituted structures have been synthesized. Techniques for membrane casting from organic solutions and directly from acid solutions have been developed. Ionic and covalent cross-linking as well as inorganic–organic composites has been explored. Membrane characterizations...

  16. Coal-Based Oxy-Fuel System Evaluation and Combustor Development; Oxy-Fuel Turbomachinery Development for Energy Intensive Industrial Applications

    Energy Technology Data Exchange (ETDEWEB)

    Hollis, Rebecca

    2013-03-31

    Clean Energy Systems, Inc. (CES) partnered with the U.S. Department of Energy’s National Energy Technology Laboratory in 2005 to study and develop a competing technology for use in future fossil-fueled power generation facilities that could operate with near zero emissions. CES’s background in oxy-fuel (O-F) rocket technology lead to the award of Cooperative Agreement DE-FC26-05NT42645, “Coal-Based Oxy-Fuel System Evaluation and Combustor Development,” where CES was to first evaluate the potential of these O-F power cycles, then develop the detailed design of a commercial-scale O-F combustor for use in these clean burning fossil-fueled plants. Throughout the studies, CES found that in order to operate at competitive cycle efficiencies a high-temperature intermediate pressure turbine was required. This led to an extension of the Agreement for, “Oxy-Fuel Turbomachinery Development for Energy Intensive Industrial Applications” where CES was to also develop an intermediate-pressure O-F turbine (OFT) that could be deployed in O-F industrial plants that capture and sequester >99% of produced CO2, at competitive cycle efficiencies using diverse fuels. The following report details CES’ activities from October 2005 through March 2013, to evaluate O-F power cycles, develop and validate detailed designs of O-F combustors (main and reheat), and to design, manufacture, and test a commercial-scale OFT, under the three-phase Cooperative Agreement.

  17. Unregulated emissions from diesel engine with particulate filter using Fe-based fuel borne catalyst.

    Science.gov (United States)

    Zhao, Hong; Ge, Yunshan; Zhang, Tiezhu; Zhang, Jipeng; Tan, Jianwei; Zhang, Hongxin

    2014-10-01

    The alteration and formation of toxic compounds and potential changes in the toxicity of emissions when using after-treatment technologies have gained wide attention. Volatile organic compound (VOC), carbonyl compound and particle-phase polycyclic aromatic hydrocarbon (PAH) emissions were tested at European Steady State Cycle (ESC) to study unregulated emissions from a diesel engine with a fuel-borne catalyst and diesel particulate filter (FBC-DPF). An Fe-based fuel-borne catalyst was used for this study. According to the results, brake specific emissions of total VOCs without and with DPF were 4.7 and 4.9mg/kWh, respectively, showing a 4.3% increase. Benzene and n-undecane emissions increased and toluene emission decreased, while other individual VOC emissions basically had no change. When retrofitted with the FBC-DPF, total carbonyl compound emission decreased 15.7%, from 25.8 to 21.8mg/kWh. The two highest carbonyls, formaldehyde and acetaldehyde, were reduced from 20.0 and 3.7 to 16.5 and 3.3mg/kWh respectively. The specific reactivity (SR) with DPF was reduced from 6.68 to 6.64mg/kWh. Total particle-phase PAH emissions decreased 66.4% with DPF compared to that without DPF. However, the Benzo[a]pyrene equivalent (BaPeq) with DPF had increased from 0.016 to 0.030mg/kWh. Fluoranthene and Pyrene had the greatest decrease, 91.1% and 88.4% respectively. The increase of two- and three-ring PAHs with DPF indicates that the fuel-borne catalyst caused some gas-phase PAHs to adsorb on particles. The results of this study expand the knowledge of the effects of using a particulate filter and a Fe-based fuel-borne catalyst on diesel engine unregulated emissions.

  18. Graphene-based electrochemical energy conversion and storage: fuel cells, supercapacitors and lithium ion batteries.

    Science.gov (United States)

    Hou, Junbo; Shao, Yuyan; Ellis, Michael W; Moore, Robert B; Yi, Baolian

    2011-09-14

    Graphene has attracted extensive research interest due to its strictly 2-dimensional (2D) structure, which results in its unique electronic, thermal, mechanical, and chemical properties and potential technical applications. These remarkable characteristics of graphene, along with the inherent benefits of a carbon material, make it a promising candidate for application in electrochemical energy devices. This article reviews the methods of graphene preparation, introduces the unique electrochemical behavior of graphene, and summarizes the recent research and development on graphene-based fuel cells, supercapacitors and lithium ion batteries. In addition, promising areas are identified for the future development of graphene-based materials in electrochemical energy conversion and storage systems.

  19. Proton exchange membrane fuel cells modeling based on artificial neural networks

    Institute of Scientific and Technical Information of China (English)

    Yudong Tian; Xinjian Zhu; Guangyi Cao

    2005-01-01

    To understand the complexity of the mathematical models of a proton exchange membrane fuel cell (PEMFC) and their shortage of practical PEMFC control, the PEMFC complex mechanism and the existing PEMFC models are analyzed, and artificial neural networks based PEMFC modeling is advanced. The structure, algorithm, training and simulation of PEMFC modeling based on improved BP networks are given out in detail. The computer simulation and conducted experiment verify that this model is fast and accurate, and can be used as a suitable operational model for PEMFC real-time control.

  20. Technical Report Cellulosic Based Black Liquor Gasification and Fuels Plant Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Fornetti, Micheal [Escanaba Paper Company, MI (United States); Freeman, Douglas [Escanaba Paper Company, MI (United States)

    2012-10-31

    The Cellulosic Based Black Liquor Gasification and Fuels Plant Project was developed to construct a black liquor to Methanol biorefinery in Escanaba, Michigan. The biorefinery was to be co-located at the existing pulp and paper mill, NewPage’s Escanaba Paper Mill and when in full operation would: • Generate renewable energy for Escanaba Paper Mill • Produce Methanol for transportation fuel of further refinement to Dimethyl Ether • Convert black liquor to white liquor for pulping. Black liquor is a byproduct of the pulping process and as such is generated from abundant and renewable lignocellulosic biomass. The biorefinery would serve to validate the thermochemical pathway and economic models for black liquor gasification. It was a project goal to create a compelling new business model for the pulp and paper industry, and support the nation’s goal for increasing renewable fuels production and reducing its dependence on foreign oil. NewPage Corporation planned to replicate this facility at other NewPage Corporation mills after this first demonstration scale plant was operational and had proven technical and economic feasibility. An overview of the process begins with black liquor being generated in a traditional Kraft pulping process. The black liquor would then be gasified to produce synthesis gas, sodium carbonate and hydrogen sulfide. The synthesis gas is then cleaned with hydrogen sulfide and carbon dioxide removed, and fed into a Methanol reactor where the liquid product is made. The hydrogen sulfide is converted into polysulfide for use in the Kraft pulping process. Polysulfide is a known additive to the Kraft process that increases pulp yield. The sodium carbonate salts are converted to caustic soda in a traditional recausticizing process. The caustic soda is then part of the white liquor that is used in the Kraft pulping process. Cellulosic Based Black Liquor Gasification and Fuels Plant project set out to prove that black liquor gasification could

  1. EXPERIMENTAL STUDY OF THE NEW BIOCATALYST METHOD FOR BIODIESEL-FUEL BASED ON THE LIPASE PRODUCTION FUNGUS

    Science.gov (United States)

    Hata, Toshiro; Shimada, Miki; Toida, Jinichi

    This paper describes how to develop and evaluate a new biocatalyst method for biodiesel fuel based on the lipase production fungus. This method can convert waste vegetable oil into biodiesel fuel without alkaline waste fluid and byproducts (gly cerine). The main outcomes of this research were: (1) The biodiesel fuel can be manufactured from lipase production fungus (Rhizupus oryzae NBRC 9364). (2) The lipase activity can be enhanced by adding glucose and oil. (3) Phased addition of the methanol enhances the conversion rate of the biodiesel fuel (Maximum conversion rate is 85%). (4) The proposed method can improve vehicle exhaust emission and reduce byproducts (glycerine). We concluded that our proposed methods are effective for the production of biodiesel fuel from waste vegetable oil.

  2. Nickel-based anodic electrocatalysts for fuel cells and water splitting

    Science.gov (United States)

    Chen, Dayi

    Our world is facing an energy crisis, so people are trying to harvest and utilize energy more efficiently. One of the promising ways to harvest energy is via solar water splitting to convert solar energy to chemical energy stored in hydrogen. Another of the options to utilize energy more efficiently is to use fuel cells as power sources instead of combustion engines. Catalysts are needed to reduce the energy barriers of the reactions happening at the electrode surfaces of the water-splitting cells and fuel cells. Nickel-based catalysts happen to be important nonprecious electrocatalysts for both of the anodic reactions in alkaline media. In alcohol fuel cells, nickel-based catalysts catalyze alcohol oxidation. In water splitting cells, they catalyze water oxidation, i.e., oxygen evolution. The two reactions occur in a similar potential range when catalyzed by nickel-based catalysts. Higher output current density, lower oxidation potential, and complete substrate oxidation are preferred for the anode in the applications. In this dissertation, the catalytic properties of nickel-based electrocatalysts in alkaline medium for fuel oxidation and oxygen evolution are explored. By changing the nickel precursor solubility, nickel complex nanoparticles with tunable sizes on electrode surfaces were synthesized. Higher methanol oxidation current density is achieved with smaller nickel complex nanoparticles. DNA aggregates were used as a polymer scaffold to load nickel ion centers and thus can oxidize methanol completely at a potential about 0.1 V lower than simple nickel electrodes, and the methanol oxidation pathway is changed. Nickel-based catalysts also have electrocatalytic activity towards a wide range of substrates. Experiments show that methanol, ethanol, glycerol and glucose can be deeply oxidized and carbon-carbon bonds can be broken during the oxidation. However, when comparing methanol oxidation reaction to oxygen evolution reaction catalyzed by current nickel-based

  3. Characterization of the relocated and dispersed fuel in the Halden reactor project LOCA tests based on gamma scan data

    Energy Technology Data Exchange (ETDEWEB)

    Brankov, Vladimir, E-mail: vladimir.brankov@psi.ch [Paul Scherrer Institut, 5232 Villigen PSI (Switzerland); École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne (Switzerland); Khvostov, Grigori; Mikityuk, Konstantin [Paul Scherrer Institut, 5232 Villigen PSI (Switzerland); Pautz, Andreas [Paul Scherrer Institut, 5232 Villigen PSI (Switzerland); École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne (Switzerland); Wiesenack, Wolfgang [Institutt For Energiteknikk OECD Halden Reactor Project, P.O. Box 173, Halden 1751 (Norway)

    2016-04-15

    Highlights: • We propose method to estimate dispersed fuel based on gamma scan data. • Analysis to determine the origin of relocated and dispersed fuel in Halden LOCA tests. • Useful data is gathered for code validation. • Suggestions are discussed to improve the quality of gamma scan data at Halden. • Dispersed and relocated material is a mixture of fuel from pellet periphery and bulk. - Abstract: The on-going Loss-of-Coolant Accident (LOCA) test program at the OECD Halden Reactor Project (HRP) conducts in-house gamma scanning as standard post-irradiation examination (PIE) procedure on Light Water Reactor (LWR) fuel rods. One of the primary objectives of the program is to investigate fuel relocation into the balloon region and fuel dispersal through the cladding rupture opening after burst. A simple model called Gamma Transport Model was formulated for the purpose of interpretation of fuel relocation based on the gamma scan data. Fuel relocation may have a strong effect on the linear heat generation rate at the balloon due to, firstly, increase in linear fuel density, and secondly due to differences in burn-up and local heat generation rate at the periphery and bulk of the pellet. For this analysis, a pair of short-lived isotopes with very different fission product yields for {sup 235}U and {sup 239}Pu is selected from the gamma scan spectrum. The intention is to use the difference in the ratio of their concentrations in the balloon region to qualitatively make conclusion on the fuel relocation. As a separate outcome, the same analysis can be applied to the dispersed fuel region and to draw conclusion on its origin (pellet rim or bulk). The Gamma Transport Model is validated against a special (non-destructive) case from the Halden LOCA test program and then applied for the analysis of selected tests. In addition, a methodology is presented for estimation of the amount of dispersed fuel from the LOCA tests based on the gamma scan data. Currently, at

  4. A stackable, two-chambered, paper-based microbial fuel cell.

    Science.gov (United States)

    Fraiwan, Arwa; Choi, Seokheun

    2016-09-15

    We developed a stackable and integrable paper-based microbial fuel cell (MFC) for potentially powering on-chip paper-based devices. Four MFCs were prepared on a T-shaped filter paper which was eventually folded three times to connect these MFCs in series. Each MFC was fabricated by sandwiching multifunctional paper layers for two-chambered fuel cell configuration. One drop of bacteria-containing anolyte into the anodic inlet and another drop of potassium ferricyanide for cathodic reaction flowed through patterned fluidic pathways within the paper matrix, both vertically and horizontally, reaching each of the four MFCs and filling the reservoir of each device. Bacterial respiration then transferred electrons to the anode, which traveled across an external load to the cathode where they combined with protons. The MFC stack connected in series generated a high power density (1.2μW/cm(2)), which is two orders of magnitude higher than the previous report on the paper-based MFC stack. This work will represent the fusion of the art of origami and paper-based MFC technology, which could provide a paradigm shift for the architecture and design of paper-based batteries.

  5. Physical characterization of biomass-based pyrolysis liquids. Application of standard fuel oil analyses

    Energy Technology Data Exchange (ETDEWEB)

    Oasmaa, A.; Leppaemaeki, E.; Koponen, P.; Levander, J.; Tapola, E. [VTT Energy, Espoo (Finland). Energy Production Technologies

    1997-12-31

    The main purpose of the study was to test the applicability of standard fuel oil methods developed for petroleum-based fuels to pyrolysis liquids. In addition, research on sampling, homogeneity, stability, miscibility and corrosivity was carried out. The standard methods have been tested for several different pyrolysis liquids. Recommendations on sampling, sample size and small modifications of standard methods are presented. In general, most of the methods can be used as such but the accuracy of the analysis can be improved by minor modifications. Fuel oil analyses not suitable for pyrolysis liquids have been identified. Homogeneity of the liquids is the most critical factor in accurate analysis. The presence of air bubbles may disturb in several analyses. Sample preheating and prefiltration should be avoided when possible. The former may cause changes in the composition and structure of the pyrolysis liquid. The latter may remove part of organic material with particles. The size of the sample should be determined on the basis of the homogeneity and the water content of the liquid. The basic analyses of the Technical Research Centre of Finland (VTT) include water, pH, solids, ash, Conradson carbon residue, heating value, CHN, density, viscosity, pourpoint, flash point, and stability. Additional analyses are carried out when needed. (orig.) 53 refs.

  6. A Continuous Liquid-Level Sensor for Fuel Tanks Based on Surface Plasmon Resonance

    Science.gov (United States)

    Pozo, Antonio M.; Pérez-Ocón, Francisco; Rabaza, Ovidio

    2016-01-01

    A standard problem in large tanks at oil refineries and petrol stations is that water and fuel usually occupy the same tank. This is undesirable and causes problems such as corrosion in the tanks. Normally, the water level in tanks is unknown, with the problems that this entails. We propose herein a method based on surface plasmon resonance (SPR) to detect in real time the interfaces in a tank which can simultaneously contain water, gasoline (or diesel) and air. The plasmonic sensor is composed of a hemispherical glass prism, a magnesium fluoride layer, and a gold layer. We have optimized the structural parameters of the sensor from the theoretical modeling of the reflectance curve. The sensor detects water-fuel and fuel-air interfaces and measures the level of each liquid in real time. This sensor is recommended for inflammable liquids because inside the tank there are no electrical or electronic signals which could cause explosions. The sensor proposed has a sensitivity of between 1.2 and 3.5 RIU−1 and a resolution of between 5.7 × 10−4 and 16.5 × 10−4 RIU. PMID:27213388

  7. A Continuous Liquid-Level Sensor for Fuel Tanks Based on Surface Plasmon Resonance

    Directory of Open Access Journals (Sweden)

    Antonio M. Pozo

    2016-05-01

    Full Text Available A standard problem in large tanks at oil refineries and petrol stations is that water and fuel usually occupy the same tank. This is undesirable and causes problems such as corrosion in the tanks. Normally, the water level in tanks is unknown, with the problems that this entails. We propose herein a method based on surface plasmon resonance (SPR to detect in real time the interfaces in a tank which can simultaneously contain water, gasoline (or diesel and air. The plasmonic sensor is composed of a hemispherical glass prism, a magnesium fluoride layer, and a gold layer. We have optimized the structural parameters of the sensor from the theoretical modeling of the reflectance curve. The sensor detects water-fuel and fuel-air interfaces and measures the level of each liquid in real time. This sensor is recommended for inflammable liquids because inside the tank there are no electrical or electronic signals which could cause explosions. The sensor proposed has a sensitivity of between 1.2 and 3.5 RIU−1 and a resolution of between 5.7 × 10−4 and 16.5 × 10−4 RIU.

  8. Homo- and heterofermentative lactobacilli differently affect sugarcane-based fuel ethanol fermentation.

    Science.gov (United States)

    Basso, Thiago Olitta; Gomes, Fernanda Sgarbosa; Lopes, Mario Lucio; de Amorim, Henrique Vianna; Eggleston, Gillian; Basso, Luiz Carlos

    2014-01-01

    Bacterial contamination during industrial yeast fermentation has serious economic consequences for fuel ethanol producers. In addition to deviating carbon away from ethanol formation, bacterial cells and their metabolites often have a detrimental effect on yeast fermentative performance. The bacterial contaminants are commonly lactic acid bacteria (LAB), comprising both homo- and heterofermentative strains. We have studied the effects of these two different types of bacteria upon yeast fermentative performance, particularly in connection with sugarcane-based fuel ethanol fermentation process. Homofermentative Lactobacillus plantarum was found to be more detrimental to an industrial yeast strain (Saccharomyces cerevisiae CAT-1), when compared with heterofermentative Lactobacillus fermentum, in terms of reduced yeast viability and ethanol formation, presumably due to the higher titres of lactic acid in the growth medium. These effects were only noticed when bacteria and yeast were inoculated in equal cell numbers. However, when simulating industrial fuel ethanol conditions, as conducted in Brazil where high yeast cell densities and short fermentation time prevail, the heterofermentative strain was more deleterious than the homofermentative type, causing lower ethanol yield and out competing yeast cells during cell recycle. Yeast overproduction of glycerol was noticed only in the presence of the heterofermentative bacterium. Since the heterofermentative bacterium was shown to be more deleterious to yeast cells than the homofermentative strain, we believe our findings could stimulate the search for more strain-specific antimicrobial agents to treat bacterial contaminations during industrial ethanol fermentation.

  9. Fuel cell-based instrumentation for ethanol determination in alcoholic beverages, fermentations, and biofluids

    Energy Technology Data Exchange (ETDEWEB)

    Parry, K.W.

    1988-01-01

    The main aim of this project was to devise an alternative method for ethanol assay, employing an electrochemical fuel cell sensor. Thus, the early part of this thesis describes the work carried out in the development of a new analytical technique for this purpose. This work resulted in the production of a successful prototype unit which has led to the development of a commercial instrument, vis., the Lion Drinks Alcolmeter (DA-1) available from Lion Laboratories Ltd. The problem of determining the ethanol content of a fermenting liquor at any point during a fermentation process was also broached and a novel technique combining a flow dilution system, dynamic headspace analysis and a fuel cell sensor was developed. This procedure, suitably automated, will enable the ethanolic content of a fermenting beverage to be determined at any stage during a fermentation, the results obtained in this manner being in excellent agreement with those obtained gas chromatographically. Methods of extending the linear working range of a fuel cell-based sampling system are reported in the hope that the encouraging results obtained may initiate further progress in this field. Finally, the sensing system used in this work has also been utilized with an alternative sampling procedure for the determination of ethanol in biological fluids, mainly for clinical and forensic applications. This work has also led to the production of a commercial instrument, viz. the Lion AE-D3 Alcolmeter.

  10. Can Hawaii Meet Its Renewable Fuel Target? Case Study of Banagrass-Based Cellulosic Ethanol

    Directory of Open Access Journals (Sweden)

    Chinh Tran

    2016-08-01

    Full Text Available Banagrass is a biomass crop candidate for ethanol production in the State of Hawaii. This study examines: (i whether enough banagrass can be produced to meet Hawaii’s renewable fuel target of 20% highway fuel demand produced with renewable sources by 2020 and (ii at what cost. This study proposes to locate suitable land areas for banagrass production and ethanol processing, focusing on the two largest islands in the state of Hawaii—Hawaii and Maui. The results suggest that the 20% target is not achievable by using all suitable land resources for banagrass production on both Hawaii and Maui. A total of about 74,224,160 gallons, accounting for 16.04% of the state’s highway fuel demand, can be potentially produced at a cost of $6.28/gallon. Lower ethanol cost is found when using a smaller production scale. The lowest cost of $3.31/gallon is found at a production processing capacity of about 9 million gallons per year (MGY, which meets about 2% of state demand. This cost is still higher than the average imported ethanol price of $3/gallon. Sensitivity analysis finds that it is possible to produce banagrass-based ethanol on Hawaii Island at a cost below the average imported ethanol price if banagrass yield increases of at least 35.56%.

  11. Monolithic solid oxide fuel cell technology advancement for coal-based power generation

    Science.gov (United States)

    1994-05-01

    This project has successfully advanced the technology for MSOFC's for coal-based power generation. Major advances include: tape-calendering processing technology, leading to 3X improved performance at 1000 C; stack materials formulations and designs with sufficiently close thermal expansion match for no stack damage after repeated thermal cycling in air; electrically conducting bonding with excellent structural robustness; and sealants that form good mechanical seals for forming manifold structures. A stack testing facility was built for high-spower MSOFC stacks. Comprehensive models were developed for fuel cell performance and for analyzing structural stresses in multicell stacks and electrical resistance of various stack configurations. Mechanical and chemical compatibility properties of fuel cell components were measured; they show that the baseline Ca-, Co-doped interconnect expands and weakens in hydrogen fuel. This and the failure to develop adequate sealants were the reason for performance shortfalls in large stacks. Small (1-in. footprint) two-cell stacks were fabricated which achieved good performance (average area-specific-resistance 1.0 ohm-sq cm per cell); however, larger stacks had stress-induced structural defects causing poor performance.

  12. Testing a vapour-fed PBI-based direct ethanol fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Lobato, J.; Canizares, P.; Rodrigo, M.A.; Linares, J.J. [Chemical Engineering Department, University of Castilla-La Mancha, Ciudad Real (Spain)

    2009-10-15

    This work is focused on the application and performance of a high temperature PBI-based direct ethanol fuel cell, studying the influence of some operating variables such as the temperature, ethanol concentration and oxygen partial pressure. An increase in the temperature resulted in an improvement of the cell performance due to the enhanced electrodic kinetic and electrolyte conductivity. An ethanol/water weight ratio between 0.25 and 0.5 was found to be suitable for providing both enough water and fuel availability to make the ethanol oxidation possible. Measurements of the ethanol crossover at different temperatures and concentrations were carried out. An intermittent lifetime test showed that the cell, after several hours, was able to reach stability. Moreover, its performance was completely reversible with no perceptible losses for 7 days. Finally, tests using bio-ethanol as fuel were performed, with no significant power losses. This final feature is of special interest from a practical 'green' point of view. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  13. A Continuous Liquid-Level Sensor for Fuel Tanks Based on Surface Plasmon Resonance.

    Science.gov (United States)

    Pozo, Antonio M; Pérez-Ocón, Francisco; Rabaza, Ovidio

    2016-05-19

    A standard problem in large tanks at oil refineries and petrol stations is that water and fuel usually occupy the same tank. This is undesirable and causes problems such as corrosion in the tanks. Normally, the water level in tanks is unknown, with the problems that this entails. We propose herein a method based on surface plasmon resonance (SPR) to detect in real time the interfaces in a tank which can simultaneously contain water, gasoline (or diesel) and air. The plasmonic sensor is composed of a hemispherical glass prism, a magnesium fluoride layer, and a gold layer. We have optimized the structural parameters of the sensor from the theoretical modeling of the reflectance curve. The sensor detects water-fuel and fuel-air interfaces and measures the level of each liquid in real time. This sensor is recommended for inflammable liquids because inside the tank there are no electrical or electronic signals which could cause explosions. The sensor proposed has a sensitivity of between 1.2 and 3.5 RIU(-1) and a resolution of between 5.7 × 10(-4) and 16.5 × 10(-4) RIU.

  14. Corrosion of aluminium, stainless steels and AISI 680 nickel alloy in nitrogen-based fuels

    Energy Technology Data Exchange (ETDEWEB)

    Kap, I.; Starostin, M.; Shter, G.E.; Grader, G.S. [Department of Chemical Engineering, Technion-Israel Institute of Technology, Haifa (Israel)

    2012-07-15

    Nitrogen-based compounds can potentially be used as alternative non-carbon or low-carbon fuels. Nevertheless, the corrosion of construction materials at high temperatures and pressures in the presence of such fuel has not been reported yet. This work is focused on the corrosion of AISI Al 6061, 1005 carbon steel (CS), 304, 316L, 310 austenitic stainless steels (SS) and 680 nickel alloy in highly concentrated water solution of ammonium nitrate and urea (ANU). The corrosion at 50 C and ambient pressure and at 350 C and 20 bar was investigated to simulate storage and working conditions. Sodium chloride was added to the fuel (0-5 wt%) to simulate industrial fertilizers and accelerated corrosion environment. Heavy corrosion of CS was observed in ANU solution at 50 C, while Al 6061, 304 and 316L SS showed high resistance both to uniform and pitting corrosion in ANU containing 1% of sodium chloride. Addition of 5% sodium chloride caused pitting of Al 6061 but had no influence on the corrosion of SS. Tests in ANU at 350 C and 20 bar showed pitting on SS 304 and 316L and 680 nickel alloy. The highest corrosion resistance was found for SS 310 due to formation of stable oxide film on its surface. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  15. Fuel-Cell Power Systems Incorporating Mg-Based H2 Generators

    Science.gov (United States)

    Kindler, Andrew; Narayan, Sri R.

    2009-01-01

    Two hydrogen generators based on reactions involving magnesium and steam have been proposed as means for generating the fuel (hydrogen gas) for such fuel-cell power systems as those to be used in the drive systems of advanced motor vehicles. The hydrogen generators would make it unnecessary to rely on any of the hydrogen storage systems developed thus far that are, variously, too expensive, too heavy, too bulky, and/or too unsafe to be practical. The two proposed hydrogen generators are denoted basic and advanced, respectively. In the basic hydrogen generator (see figure), steam at a temperature greater than or equals 330 C would be fed into a reactor charged with magnesium, wherein hydrogen would be released in the exothermic reaction Mg + H2O yields MgO + H2. The steam would be made in a flash boiler. To initiate the reaction, the boiler could be heated electrically by energy borrowed from a storage battery that would be recharged during normal operation of the associated fuel-cell subsystem. Once the reaction was underway, heat from the reaction would be fed to the boiler. If the boiler were made an integral part of the hydrogen-generator reactor vessel, then the problem of transfer of heat from the reactor to the boiler would be greatly simplified. A pump would be used to feed water from a storage tank to the boiler.

  16. Scientific bases of biomass processing into basic component of aviation fuel

    Science.gov (United States)

    Kachalov, V. V.; Lavrenov, V. A.; Lishchiner, I. I.; Malova, O. V.; Tarasov, A. L.; Zaichenko, V. M.

    2016-11-01

    A combination of feedstock pyrolysis and the cracking of the volatile pyrolysis products on the charcoal at 1000 °C allows to obtain a tarless synthesis gas which contains 90 vol% or more of carbon monoxide and hydrogen in approximately equal proportions. Basic component of aviation fuel was synthesized in a two-stage process from gas obtained by pyrolytic processing of biomass. Methanol and dimethyl ether can be efficiently produced in a two-layer loading of methanolic catalyst and γ-Al2O3. The total conversion of CO per pass was 38.2% using for the synthesis of oxygenates a synthesis gas with adverse ratio of H2/CO = 0.96. Conversion of CO to CH3OH was 15.3% and the conversion of CO to dimethyl ether was 20.9%. A high yield of basic component per oxygenates mass (44.6%) was obtained during conversion. The high selectivity of the synthesis process for liquid hydrocarbons was observed. An optimal recipe of aviation fuel B-92 based on a synthesized basic component was developed. The prototype of aviation fuel meets the requirements for B-92 when straight fractions of 50-100 °C (up to 35 wt%), isooctane (up to 10 wt%) and ethyl fluid (2.0 g/kg calculated as tetraethyl lead) is added to the basic component.

  17. Strata-based forest fuel classification for wild fire hazard assessment using terrestrial LiDAR

    Science.gov (United States)

    Chen, Yang; Zhu, Xuan; Yebra, Marta; Harris, Sarah; Tapper, Nigel

    2016-10-01

    Fuel structural characteristics affect fire behavior including fire intensity, spread rate, flame structure, and duration, therefore, quantifying forest fuel structure has significance in understanding fire behavior as well as providing information for fire management activities (e.g., planned burns, suppression, fuel hazard assessment, and fuel treatment). This paper presents a method of forest fuel strata classification with an integration between terrestrial light detection and ranging (LiDAR) data and geographic information system for automatically assessing forest fuel structural characteristics (e.g., fuel horizontal continuity and vertical arrangement). The accuracy of fuel description derived from terrestrial LiDAR scanning (TLS) data was assessed by field measured surface fuel depth and fuel percentage covers at distinct vertical layers. The comparison of TLS-derived depth and percentage cover at surface fuel layer with the field measurements produced root mean square error values of 1.1 cm and 5.4%, respectively. TLS-derived percentage cover explained 92% of the variation in percentage cover at all fuel layers of the entire dataset. The outcome indicated TLS-derived fuel characteristics are strongly consistent with field measured values. TLS can be used to efficiently and consistently classify forest vertical layers to provide more precise information for forest fuel hazard assessment and surface fuel load estimation in order to assist forest fuels management and fire-related operational activities. It can also be beneficial for mapping forest habitat, wildlife conservation, and ecosystem management.

  18. Dynamical analysis of an accelerator-based fluid-fueled subcritical radioactive waste burning system

    Science.gov (United States)

    Woosley, Michael Louis, Jr.

    The recent revival of interest in accelerator-driven subcritical fluid-fueled systems is documented. Several important applications of these systems are mentioned. In particular, new applications have focused on the destruction of high-level radioactive waste. Systems can be designed to quickly destroy the actinides and long-lived fission products from light water reactor fuel, weapons plutonium, and other high-level defense wastes. The proposed development of these systems is used to motivate the need for the development of dynamic analysis methods for their nuclear kinetics. A physical description of the Los Alamos Accelerator-Based Conversion (ABC) concept is provided. This system is used as the basis for the kinetics study in this research. The current approach to the dynamic simulation of an accelerator-driven subcritical fluid-fueled system includes three elements: A discrete ordinates model is used to calculate the flux distribution for the source-driven system; A nodal convection model is used to calculate time-dependent isotope and temperature distributions which impact reactivity; A nodal importance weighting model is used to calculate the reactivity impact of temperature and isotope distributions and to feed this information back to the time-dependent nodal convection model. Specific transients which have been analyzed with the current modeling system are discussed. These transients include loss-of-flow and loss-of-cooling accidents, xenon and samarium transients, and cold-plug and overfueling events. The results of various transients have uncovered unpredictable behavior, unresolved design issues, and the need for active control. Modest initiating events can cause significant swings in system temperature and power. The circulation of the fluid fuel can lead to oscillations on the relatively short scale of the loop circulation time. The system responds quickly to reactivity changes because the large neutron source overwhelms the damping effect of delayed

  19. Mechanisms for enhanced performance of platinum-based electrocatalysts in proton exchange membrane fuel cells.

    Science.gov (United States)

    Su, Liang; Jia, Wenzhao; Li, Chang-Ming; Lei, Yu

    2014-02-01

    As a new generation of power sources, fuel cells have shown great promise for application in transportation. However, the expensive catalyst materials, especially the cathode catalysts for oxygen reduction reaction (ORR), severely limit the widespread commercialization of fuel cells. Therefore, this review article focuses on platinum (Pt)-based electrocatalysts for ORR with better catalytic performance and lower cost. Major breakthroughs in the improvement of activity and durability of electrocatalysts are discussed. Specifically, on one hand, the enhanced activity of Pt has been achieved through crystallographic control, ligand effect, or geometric effect; on the other hand, improved durability of Pt-based cathode catalysts has been realized by means of the incorporation of another noble metal or the morphological control of nanostructures. Furthermore, based on these improvement mechanisms, rationally designed Pt-based nanoparticles are summarized in terms of different synthetic strategies such as wet-chemical synthesis, Pt-skin catalysts, electrochemically dealloyed nanomaterials, and Pt-monolayer deposition. These nanoparticulate electrocatalysts show greatly enhanced catalytic performance towards ORR, aiming not only to outperform the commercial Pt/C, but also to exceed the US Department of Energy 2015 technical target ($30/kW and 5000 h).

  20. Life-cycle assessment of corn-based butanol as a potential transportation fuel.

    Energy Technology Data Exchange (ETDEWEB)

    Wu, M.; Wang, M.; Liu, J.; Huo, H.; Energy Systems

    2007-12-31

    Butanol produced from bio-sources (such as corn) could have attractive properties as a transportation fuel. Production of butanol through a fermentation process called acetone-butanol-ethanol (ABE) has been the focus of increasing research and development efforts. Advances in ABE process development in recent years have led to drastic increases in ABE productivity and yields, making butanol production worthy of evaluation for use in motor vehicles. Consequently, chemical/fuel industries have announced their intention to produce butanol from bio-based materials. The purpose of this study is to estimate the potential life-cycle energy and emission effects associated with using bio-butanol as a transportation fuel. The study employs a well-to-wheels analysis tool--the Greenhouse Gases, Regulated Emissions and Energy Use in Transportation (GREET) model developed at Argonne National Laboratory--and the Aspen Plus{reg_sign} model developed by AspenTech. The study describes the butanol production from corn, including grain processing, fermentation, gas stripping, distillation, and adsorption for products separation. The Aspen{reg_sign} results that we obtained for the corn-to-butanol production process provide the basis for GREET modeling to estimate life-cycle energy use and greenhouse gas emissions. The GREET model was expanded to simulate the bio-butanol life cycle, from agricultural chemical production to butanol use in motor vehicles. We then compared the results for bio-butanol with those of conventional gasoline. We also analyzed the bio-acetone that is coproduced with bio-butanol as an alternative to petroleum-based acetone. Our study shows that, while the use of corn-based butanol achieves energy benefits and reduces greenhouse gas emissions, the results are affected by the methods used to treat the acetone that is co-produced in butanol plants.

  1. Influence of tall oil biodiesel with Mg and Mo based fuel additives on diesel engine performance and emission.

    Science.gov (United States)

    Keskin, Ali; Gürü, Metin; Altiparmak, Duran

    2008-09-01

    The purpose of this study is to investigate influences of tall oil biodiesel with Mg and Mo based fuel additives on diesel engine performance and emission. Tall oil resinic acids were reacted with MgO and MoO(2) stoichiometrically for the production of metal-based fuel additives (combustion catalysts). The metal-based additives were added into tall oil biodiesel (B60) at the rate of 4 micromol/l, 8 micromol/l and 12 micromol/l for preparing test fuels. In general, both of the metal-based additives improved flash point, pour point and viscosity of the biodiesel fuel, depending on the rate of additives. A single cylinder DI diesel engine was used in the tests. Engine performance values did not change significantly with biodiesel fuels, but exhaust emission profile was improved. CO emissions and smoke opacity decreased by 56.42% and by 30.43%, respectively. In general, low NO(x) and CO(2) emissions were measured with the biodiesel fuels.

  2. Trigeneration System Based on Municipal Waste Gasification, Fuel Cell and an Absorption Chiller

    DEFF Research Database (Denmark)

    Katsaros, Giannis; Nguyen, Tuong-Van; Rokni, Masoud

    2016-01-01

    for electricity, heating and cooling. The system is modelled in Aspen Plus and the influence of different operating parameters on the system performance is studied. The findings suggest that low air equivalent ratios enhance the overall system performance. The possibility of covering the demand profiles......The present work focuses on the design of a novel tri-generation system based on municipal solid wastes gasification, solid oxide fuel cell and an ammonia-water absorption chiller. Trigeneration systems can be implemented in buildings such as hospitals, where there is a continuous and large demand...

  3. Integrated data base report--1995: US spent nuclear fuel and radioactive waste inventories, projections, and characteristics

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-01

    The information in this report summarizes the U.S. Department of Energy (DOE) data base for inventories, projections, and characteristics of domestic spent nuclear fuel and radioactive waste. This report is updated annually to keep abreast of continual waste inventory and projection changes in both the government and commercial sectors. Baseline information is provided for DOE program planning purposes and to support DOE program decisions. Although the primary purpose of this document is to provide background information for program planning within the DOE community, it has also been found useful by state and local governments, the academic community, and some private citizens.

  4. Monolithic solid oxide fuel cell technology advancement for coal-based power generation

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-14

    The program is conducted by a team consisting of AiResearch Los Angeles Division of Allied-Signal Aerospace Company and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

  5. UPS Project for GSM base stations with a fuel cell (PEM fuel cell back-up system) - Final report; Projekt USV fuer GSM-Basisstationen mit BZ (PEM fuel cell back-up system) - Abschlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Trachte, U.

    2007-07-01

    The University of applied sciences HTA Lucerne designed a prototype of an uninterruptible power supply (UPS) with Fuel Cell technology instead of lead-acid batteries and put it into operation. The delayed start-up of the Fuel Cell was bridged with ultra capacitor technology. In a first project stage the system was designed, assembled and tested in laboratory. In a second stage the installation was connected to a real base station of a telecommunication antenna and put to field tests for one year. The field test included monthly simulations of power failure with antenna load of about 2.4 kW as well as tests with external load up to 8.5 kW to establish the characteristic diagram. Hydrogen was provided by two 50 l pressure tanks. The full quantity of hydrogen secured a stand-alone operation of the Fuel Cell system for about 6 hours under antenna load. The results of the 101 grid-failure simulations demonstrate a very reliable start-up behaviour of the Fuel Cell System. Also during a real power failure due to a thunderstorm the installation provided the demanded power without any problem. The total duration of operation of the Fuel Cell during the field tests was 39 hours. No degradation could be noticed. The project takes place in collaboration with the industrial partners APC Industrial Systems, as a producer and market leader of UPS-Systems, and Swisscom Mobile AG, as a user of UPS-systems in telecommunications. Following the good results and in order to get more experience in long-term operation of the Fuel Cell system the tests will go on for two more years. (author)

  6. Life cycle analysis and choice of natural gas-based automotive alternative fuels in Chongqing Municipality,China

    Institute of Scientific and Technical Information of China (English)

    WU Rui; LI Guangyi; ZHANG Zongyi; REN Yulong; HAN Weijian

    2007-01-01

    Road transport produces significant amounts of emissions by using crude oil as the primary energy source.A reduction of emissions can be achieved by implementing alternative fuel chains.The objective of this study is to carry out an economic,environmental and energy (EEE) life cycle study on natural gas-based automotive fuels with conventional gasoline in an abundant region of China.A set of indices of four fuels/vehicle systems on the basis of life cycle are assessed in terms of impact of EEE,in which natural gas produces compressed natural gas (CNG),methanol,dimethylether (DME) and Fischer Tropsch diesel (FTD).The study included fuel production,vehicle production,vehicle operation,infrastructure and vehicle end of life as a system for each fuel/vehicle system.A generic gasoline fueled car is used as a baseline.Data have been reviewed and modified based on the best knowledge available to Chongqing local sources.Results indicated that when we could not change electric and hydrogen fuel cell vehicles into commercial vehicles on a large scale,direct use of CNG in a dedicated or bi-fuel vehicle is an economical choice for the region which is most energy efficient and more environmental friendly.The study can be used to support decisions on how natural gas resources can best be utilized as a fuel/energy resource for automobiles,and what issues need to be resolved in Chongqing.The models and approaches for this study can be applied to other regions of China as long as all the assumptions are well defined and modified to find a substitute automotive energy source and establish an energy policy in a specific region.

  7. Storage study with waste fuels based on municipal solid wastes; Lagringsfoersoek med avfallsbraenslen baserade paa hushaallsavfall

    Energy Technology Data Exchange (ETDEWEB)

    Aakesson, M.; Bramryd, T.; Hogland, W. [Lund Univ. (Sweden). Waste Management and Recovery

    1991-12-31

    A storage study with waste fuels based on Municipal Solid Waste (MSW) has been carried out. Four different types of waste fuels have been examined; pelletized RDF (BRINI), reject RDF from a separation/composting plant, the dry fraction of the source separation trials with `Wet and Dry`, and household waste from a row house area where a source separation program with kitchen garbage grinder is in progress. Three different types of storage have been tested, well ventilated wood boxes with approx. size of 20 m{sup 3} which were covered with plastic coated paper, compartments in a tent with approx. size of 50 m{sup 3} and finally 100 m{sup 3} piles covered with wood chips. Continuous monitoring of the biological activities including temperatures and concentrations of the gas components O{sub 2}, CO{sub 2} and CH{sub 4} has been carried out. The material analyses consist of moisture and ash content, substance losses, material compositions, heating values and fungi spore concentration. An investigation concerning how the heating value on a dry and ash free basis of a waste fuel is changed during a microbiological degradation has been carried out. A water balance over the pile of pelletized RDF has been formulated. The results of our study show that the materials can be placed in order of rank from the most to the least biological active in the following way: RDF, pelletized RDF, household waste, and dry fraction. This shows that the substance losses is considerable in the two mechanically separated materials (RDFs), while losses in the other two source separated materials are not detectable. Heat generation in the two most biologically active waste fuels seems to be considerable that a pronounced drying effect takes place. This leads to the fact that the heating value on a as-received-basis is increasing. This phenomena does not occur in the other two biologically more stable waste fuels. Any concentrations that show a risk of allergic alveolitis has not been observed.

  8. Nonproliferation impacts assessment for the management of the Savannah River Site aluminum-based spent nuclear fuel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-01

    On May 13, 1996, the US established a new, 10-year policy to accept and manage foreign research reactor spent nuclear fuel containing uranium enriched in the US. The goal of this policy is to reduce civilian commerce in weapons-usable highly enriched uranium (HEU), thereby reducing the risk of nuclear weapons proliferation. Two key disposition options under consideration for managing this fuel include conventional reprocessing and new treatment and packaging technologies. The Record of Decision specified that, while evaluating the reprocessing option, ``DOE will commission or conduct an independent study of the nonproliferation and other (e.g., cost and timing) implications of chemical separation of spent nuclear fuel from foreign research reactors.`` DOE`s Office of Arms Control and Nonproliferation conducted this study consistent with the aforementioned Record of Decision. This report addresses the nonproliferation implications of the technologies under consideration for managing aluminum-based spent nuclear fuel at the Savannah River Site. Because the same technology options are being considered for the foreign research reactor and the other aluminum-based spent nuclear fuels discussed in Section ES.1, this report addresses the nonproliferation implications of managing all the Savannah River Site aluminum-based spent nuclear fuel, not just the foreign research reactor spent nuclear fuel. The combination of the environmental impact information contained in the draft EIS, public comment in response to the draft EIS, and the nonproliferation information contained in this report will enable the Department to make a sound decision regarding how to manage all aluminum-based spent nuclear fuel at the Savannah River Site.

  9. Scale-up of a high temperature polymer electrolyte membrane fuel cell based on polybenzimidazole

    Science.gov (United States)

    Pinar, F. Javier; Cañizares, Pablo; Rodrigo, Manuel A.; Úbeda, Diego; Lobato, Justo

    A high temperature PEM fuel cell stack with a total active area 150 cm 2 has been studied. The PEM technology is based on a polybenzimidazole (PBI) membrane. Cast from a PBI polymer synthesised in our lab, the performance of a three-cell stack was analysed in static and dynamic modes. In static mode, operating at high constant oxygen flow rate (QO2 > 1105 ml O2 / min) produces a small decrease on the stack performance. High constant oxygen stoichiometry (λO2 > 3) does not produce a decrease on the performance of the stack. There are not differences between operating at constant flow rate of oxygen and constant stoichiometry of oxygen in the stack performance. The effect of operating at high temperature with a pressurization system and operating at higher temperatures are beneficial since the performance of the fuel cell is enhanced. A large shut-down stage produces important performance losses due to the loss of catalyst activity and the loss of membrane conductivity. After 150 h of operation at 0.2 A cm -2, it is observed a very high voltage drop. The phosphoric acid leached from the stack was also evaluated and did not exceed 2% (w/w). This fact suggests that the main degradation mechanism of a fuel cell stack based on polybenzimidazole is not the electrolyte loss. In dynamic test mode, it was observed a rapid response of power and current output even at the lower step-time (10 s). In the static mode at 125 °C and 1 atm, the stack reached a power density peak of 0.29 W cm -2 (43.5 W) at 1 V.

  10. Controlling fuel crossover and hydration in ultrathin proton exchange membrane-based fuel cells using Pt-nanosheet catalysts

    DEFF Research Database (Denmark)

    Wang, Rujie; Zhang, Wenjing (Angela); He, Gaohong

    2014-01-01

    An ultra-thin proton exchange membrane with Pt-nanosheet catalysts was designed for a self-humidifying fuel cell running on H2 and O2. In this design, an ultra-thin Nafion membrane was used to reduce ohmic resistance. Pt nanocatalysts were uniformly anchored on exfoliated, layered double hydroxide...... (LDH) nanosheets by chemical vapor deposition. After embedding Pt-LDH nanocatalysts in 9 mm-thick Nafion membranes, exfoliated LDH nanosheets effectively captured crossovered H2 and O2 through the membranes. Meanwhile, Pt nanocatalysts on LDH nanosheets catalyzed reactions between captured H2 and O2...

  11. A NMR-Based Carbon-Type Analysis of Diesel Fuel Blends From Various Sources

    Energy Technology Data Exchange (ETDEWEB)

    Bays, J. Timothy; King, David L.

    2013-05-10

    In collaboration with participants of the Coordinating Research Council (CRC) Advanced Vehicle/Fuels/Lubricants (AVFL) Committee, and project AVFL-19, the characteristics of fuels from advanced and renewable sources were compared to commercial diesel fuels. The main objective of this study was to highlight similarities and differences among the fuel types, i.e. ULSD, renewables, and alternative fuels, and among fuels within the different fuel types. This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of 14 diesel fuel samples. The diesel fuel samples come from diverse sources and include four commercial ultra-low sulfur diesel fuels (ULSD), one gas-to-liquid diesel fuel (GTL), six renewable diesel fuels (RD), two shale oil-derived diesel fuels, and one oil sands-derived diesel fuel. Overall, the fuels examined fall into two groups. The two shale oil-derived samples and the oil-sand-derived sample closely resemble the four commercial ultra-low sulfur diesels, with SO1 and SO2 most closely matched with ULSD1, ULSD2, and ULSD4, and OS1 most closely matched with ULSD3. As might be expected, the renewable diesel fuels, with the exception of RD3, do not resemble the ULSD fuels because of their very low aromatic content, but more closely resemble the gas-to-liquid sample (GTL) in this respect. RD3 is significantly different from the other renewable diesel fuels in that the aromatic content more closely resembles the ULSD fuels. Fused-ring aromatics are readily observable in the ULSD, SO, and OS samples, as well as RD3, and are noticeably absent in the remaining RD and GTL fuels. Finally, ULSD3 differs from the other ULSD fuels by having a significantly lower aromatic carbon content and higher cycloparaffinic carbon content. In addition to providing important comparative compositional information regarding the various diesel fuels, this report also provides important information about the capabilities of NMR

  12. Hydrocarbon raw emission characterization of a direct-injection spark ignition engine operated with alcohol and furan-based bio fuels

    Energy Technology Data Exchange (ETDEWEB)

    Thewes, Matthias [FEV GmbH, Aachen (Germany); Mauermann, Peter; Pischinger, Stefan [RWTH Aachen Univ. (Germany). Inst. for Combustion Engines; Bluhm, Kerstin; Hollert, Henner [RWTH Aachen Univ. (Germany). Inst. for Environmental Research, Dept. of Ecosystem Analysis

    2013-06-01

    Within the Cluster of Excellence ''Tailor-Made Fuels from Biomass'' the impact of various potential bio fuels on engine combustion is studied. Besides alcohols, furan-based bio fuels have come into the focus with novel production routes to transform biomass into 2-Methylfuran or 2,5-Dimethylfuran. In the present study, the influence of these and other bio fuels on the hydrocarbon raw emission spectrum of a direct-injection spark-ignition single cylinder engine is studied experimentally by means of gas chromatographic and mass spectroscopic analysis of exhaust gas samples. The results obtained are compared to operation with conventional EN 228 gasoline fuel. This fuel showed slip of partially carcinogenic aromatic fuel molecule(s) in warm and in cold engine conditions. For the bio fuels, slip was found to be significant for the alcohol fuels. The carcinogenic molecule 1,3-Butadiene was present in the exhaust gas of all fuels. Furan as another possibly carcinogenic molecule was found at significantly higher concentrations in the exhaust gas of the furan-based bio fuels compared to conventional gasoline fuel but not in the exhaust gas of the alcohol fuels. (orig.)

  13. A paper-based microbial fuel cell: instant battery for disposable diagnostic devices.

    Science.gov (United States)

    Fraiwan, Arwa; Mukherjee, Sayantika; Sundermier, Steven; Lee, Hyung-Sool; Choi, Seokheun

    2013-11-15

    We present a microfabricated paper-based microbial fuel cell (MFC) generating a maximum power of 5.5 μW/cm(2). The MFC features (1) a paper-based proton exchange membrane by infiltrating sulfonated sodium polystyrene sulfonate and (2) micro-fabricated paper chambers by patterning hydrophobic barriers of photoresist. Once inoculum and catholyte were added to the MFC, a current of 74 μA was generated immediately. This paper-based MFC has the advantages of ease of use, low production cost, and high portability. The voltage produced was increased by 1.9 × when two MFC devices were stacked in series, while operating lifetime was significantly enhanced in parallel.

  14. Fuel gas desulfurization at elevated temperatures with copper-based sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Abbasian, J.; Hill, A.H.; Lau, F.S. [Inst. of Gas Technology, Des Plaines, IL (United States); Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States); Honea, F.I. [Illinois Clean Coal Inst., Carbondale, IL (United States)

    1995-12-31

    Zinc-based sorbents, the leading candidates for hot gas cleanup, have been shown to suffer from zinc volatilization at elevated temperatures, leading to sorbent deterioration, increasing sorbent replacement costs. Copper-based sorbents, because of the high melting point of the metal, do not suffer from this problem. However, bulk copper oxide is generally reduced to metallic copper in reducing fuel gas environments leading to thermodynamic limitations, resulting in insufficient level of desulfurization. The reduction stability and therefore the desulfurization performance of copper oxide sorbents can be significantly improved by combining copper oxide with other oxides in a supported form or as bulk mixed metal oxides. This paper addresses the results of a systematic study of several novel copper-based sorbents for hot gas cleanup application. The evaluation criteria included reduction stability, sulfidation reactivity and regenerability at elevated temperatures. The performance of the most promising sorbent in long duration cycle sulfidation-regeneration tests is also presented.

  15. PEALD YSZ-based bilayer electrolyte for thin film-solid oxide fuel cells

    Science.gov (United States)

    Yu, Wonjong; Cho, Gu Young; Hong, Soonwook; Lee, Yeageun; Kim, Young Beom; An, Jihwan; Cha, Suk Won

    2016-10-01

    Yttria-stabilized zirconia (YSZ) thin film electrolyte deposited by plasma enhanced atomic layer deposition (PEALD) was investigated. PEALD YSZ-based bi-layered thin film electrolyte was employed for thin film solid oxide fuel cells on nanoporous anodic aluminum oxide substrates, whose electrochemical performance was compared to the cell with sputtered YSZ-based electrolyte. The cell with PEALD YSZ electrolyte showed higher open circuit voltage (OCV) of 1.0 V and peak power density of 182 mW cm-2 at 450 °C compared to the one with sputtered YSZ electrolyte(0.88 V(OCV), 70 mW cm-2(peak power density)). High OCV and high power density of the cell with PEALD YSZ-based electrolyte is due to the reduction in ohmic and activation losses as well as the gas and electrical current tightness.

  16. Fuzzy Pattern Classification Based Detection of Faulty Electronic Fuel Control (EFC Valves Used in Diesel Engines

    Directory of Open Access Journals (Sweden)

    Umut Tugsal

    2014-05-01

    Full Text Available In this paper, we develop mathematical models of a rotary Electronic Fuel Control (EFC valve used in a Diesel engine based on dynamic performance test data and system identification methodology in order to detect the faulty EFC valves. The model takes into account the dynamics of the electrical and mechanical portions of the EFC valves. A recursive least squares (RLS type system identification methodology has been utilized to determine the transfer functions of the different types of EFC valves that were investigated in this study. Both in frequency domain and time domain methods have been utilized for this purpose. Based on the characteristic patterns exhibited by the EFC valves, a fuzzy logic based pattern classification method was utilized to evaluate the residuals and identify faulty EFC valves from good ones. The developed methodology has been shown to provide robust diagnostics for a wide range of EFC valves.

  17. Zirconium-based alloys, nuclear fuel rods and nuclear reactors including such alloys, and related methods

    Science.gov (United States)

    Mariani, Robert Dominick

    2014-09-09

    Zirconium-based metal alloy compositions comprise zirconium, a first additive in which the permeability of hydrogen decreases with increasing temperatures at least over a temperature range extending from 350.degree. C. to 750.degree. C., and a second additive having a solubility in zirconium over the temperature range extending from 350.degree. C. to 750.degree. C. At least one of a solubility of the first additive in the second additive over the temperature range extending from 350.degree. C. to 750.degree. C. and a solubility of the second additive in the first additive over the temperature range extending from 350.degree. C. to 750.degree. C. is higher than the solubility of the second additive in zirconium over the temperature range extending from 350.degree. C. to 750.degree. C. Nuclear fuel rods include a cladding material comprising such metal alloy compositions, and nuclear reactors include such fuel rods. Methods are used to fabricate such zirconium-based metal alloy compositions.

  18. In situ microbial fuel cell-based biosensor for organic carbon

    DEFF Research Database (Denmark)

    de Jesus dos Santos Peixoto, Luciana; Min, Booki; Martins, Gilberto

    2011-01-01

    The biological oxygen demand (BOD) may be the most used test to assess the amount of pollutant organic matter in water; however, it is time and labor consuming, and is done ex-situ. A BOD biosensor based on the microbial fuel cell principle was tested for online and in situ monitoring of biodegra......The biological oxygen demand (BOD) may be the most used test to assess the amount of pollutant organic matter in water; however, it is time and labor consuming, and is done ex-situ. A BOD biosensor based on the microbial fuel cell principle was tested for online and in situ monitoring...... to 78±7.6mg O2/L. The current generation from the BOD biosensor was dependent on the measurement conditions such as temperature, conductivity, and pH. Thus, a correction factor should be applied to measurements done under different environmental conditions from the ones used in the calibration....... These results provide useful information for the development of a biosensor for real-time in situ monitoring of wastewater quality....

  19. Synthesis of Petroleum-Based Fuel from Waste Plastics and Performance Analysis in a CI Engine

    Directory of Open Access Journals (Sweden)

    Christine Cleetus

    2013-01-01

    Full Text Available The present work involves the synthesis of a petroleum-based fuel by the catalytic pyrolysis of waste plastics. Catalytic pyrolysis involves the degradation of the polymeric materials by heating them in the absence of oxygen and in the presence of a catalyst. In the present study different oil samples are produced using different catalysts under different reaction conditions from waste plastics. The synthesized oil samples are subjected to a parametric study based on the oil yield, selectivity of the oil, fuel properties, and reaction temperature. Depending on the results from the above study, an optimization of the catalyst and reaction conditions was done. Gas chromatography-mass spectrometry of the selected optimized sample was done to find out its chemical composition. Finally, performance analysis of the selected oil sample was carried out on a compression ignition (CI engine. Polythene bags are selected as the source of waste plastics. The catalysts used for the study include silica, alumina, Y zeolite, barium carbonate, zeolite, and their combinations. The pyrolysis reaction was carried at polymer to catalyst ratio of 10 : 1. The reaction temperature ranges between 400°C and 550°C. The inert atmosphere for the pyrolysis was provided by using nitrogen as a carrier gas.

  20. Preparation, characterisation, engine performance and emission characteristics of coconut oil based hybrid fuels

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Pranil J.; Singh, Anirudh [Division of Physics, School of Engineering and Physics, Faculty of Science, Technology and Environment, University of the South Pacific, 325 Fletcher Road, Suva (Fiji); Khurma, Jagjit [Division of Chemistry, School of Biological, Chemical and Environmental Sciences, Faculty of Science, Technology and Environment, University of the South Pacific, Suva (Fiji)

    2010-09-15

    In this study, hybrid fuels consisting of coconut oil, aqueous ethanol and a surfactant (butan-1-ol) were prepared and tested as a fuel in a direct injection diesel engine. After determining fuel properties such as the density, viscosity and gross calorific values of these fuels, they were used to run a diesel engine. The engine performance and exhaust emissions were investigated and compared with that of diesel. The experimental results show that the efficiency of the hybrid fuels is comparable to that of diesel. As the viscosity of the hybrid fuels decreased and approached that of diesel, the efficiency increased progressively towards that of diesel. The exhaust emissions were lower than those for diesel, except carbon monoxide emissions, which increased. Hence, it is concluded that these hybrid fuels can be used successfully as an alternative fuel in diesel engines without any modifications. Their completely renewable nature ensures that they are environmentally friendly with regard to their emissions characteristics. (author)

  1. A Comparison of Materials Issues for Cermet and Graphite-Based NTP Fuels

    Science.gov (United States)

    Stewart, Mark E.; Schnitzler, Bruce G.

    2013-01-01

    This paper compares material issues for cermet and graphite fuel elements. In particular, two issues in NTP fuel element performance are considered here: ductile to brittle transition in relation to crack propagation, and orificing individual coolant channels in fuel elements. Their relevance to fuel element performance is supported by considering material properties, experimental data, and results from multidisciplinary fluid/thermal/structural simulations. Ductile to brittle transition results in a fuel element region prone to brittle fracture under stress, while outside this region, stresses lead to deformation and resilience under stress. Poor coolant distribution between fuel element channels can increase stresses in certain channels. NERVA fuel element experimental results are consistent with this interpretation. An understanding of these mechanisms will help interpret fuel element testing results.

  2. Boundary model-based reference control of blower cooled high temperature polymer electrolyte membrane fuel cells

    DEFF Research Database (Denmark)

    Jensen, Hans-Christian Becker; Kær, Søren Knudsen

    2011-01-01

    Fuel cells have, by design, a limited effective life time, which depends on how they are operated. The general consent is that operation of the fuel cell at the extreme of the operational range, or operation of the fuel cell without sufficient reactants (a.k.a. starvation), will lower the effective...... life time of a fuel cell significantly. On air cooled HTPEMFCs, the blower, which supplies the fuel cell with oxygen for the chemical process, also functions as the cooling system. This makes the blower bi-functional and as a result a higher supply of oxygen is often available, hence changes...... in the fuel cell output can be optimised by the knowledge of how much oxygen is supplied to the fuel cell at any given time, without reducing the effective life time of a fuel cell by starvation....

  3. Oxygen reduction and methanol oxidation behaviour of SiC based Pt nanocatalysts for proton exchange membrane fuel cells

    DEFF Research Database (Denmark)

    Dhiman, Rajnish; Stamatin, Serban Nicolae; Andersen, Shuang Ma

    2013-01-01

    Research with proton exchange membrane fuel cells has demonstrated their important potential as providers of clean energy. The commercialization of this type of fuel cell needs a breakthrough in electrocatalyst technology to reduce the relatively large amount of noble metal platinum used...... with the present carbon based substrates. We have recently examined suitably sized silicon carbide (SiC) particles as catalyst supports for fuel cells based on the stable chemical and mechanical properties of this material. In the present study, we have continued our work with studies of the oxygen reduction...... and methanol oxidation reactions of SiC supported catalysts and measured them against commercially available carbon based catalysts. The deconvolution of the hydrogen desorption signals in CV cycles shows a higher contribution of Pt (110) & Pt (111) peaks compared to Pt (100) for SiC based supports than...

  4. [Multi-objectives optimization on life cycle pollutants emission of cassava-based ethanol blended gasoline fuels].

    Science.gov (United States)

    Pu, Geng-qiang; Hu, Zhi-yuan; Wang, Cheng-tao

    2004-09-01

    An optimization model on life cycle pollutants emission of cassava-based ethanol blended gasoline fuels, including single and multi-objectives, was carried out in this paper. And, the single and multi-objectives optimization of cassava-based ethanol blended gasoline fuels were done, using the life cycle CO, NOx, PM, HC, SOx, CO2 emissions as objectives. Moreover, sensitivity analysis of design variables was done. The multi-objectives results shown that the blend ratio between cassava-based ethanol and gasoline was 63%. Compare with the initial value, multi-objective optimization of cassava-based ethanol blended gasoline fuels achieved a little more life cycle CO, NOx and PM emissions, about 1%, 15% and 19% respectively, and reduced life cycle HC, SOx and CO2 emissions, 8%, 50%, and 21% respectively.

  5. Sulphation of calcium-based sorbents in circulating fluidised beds under oxy-fuel combustion conditions

    Energy Technology Data Exchange (ETDEWEB)

    Francisco Garcia-Labiano; Luis F. de Diego; Alberto Abad; Pilar Gayan; Margarita de las Obras-Loscertales; Aranzazu Rufas; Juan Adanez [Instituto de Carboquimica (CSIC), Zaragoza (Spain). Dept. Energy and Environment

    2009-07-01

    Sulphur Retention (SR) by calcium-based sorbents is a process highly dependent on the temperature and CO{sub 2} concentration. In circulating fluidised beds combustors (CFBC's) operating under oxy-fuel conditions, the sulphation process takes place in atmospheres enriched in CO{sub 2} with bed concentrations that can vary from 40 to 95%. Under so high CO{sub 2} concentrations, very different from that in conventional coal combustion atmosphere with air, the calcination and sulphation behaviour of the sorbent must be defined to optimise the SR process in the combustor. The objective of this work was to determine the SO{sub 2} retention capacity of a Spanish limestone at typical oxy-fuel conditions in CFBC's. Long term duration tests of sulphation (up to 24 h), to simulate the residence time of sorbents in CFBC's, were carried out by thermogravimetric analysis (TGA). Clear behaviour differences were found under calcining and non-calcining conditions. Especially relevant was the result obtained at calcining conditions but close to the thermodynamic temperature given for sorbent calcination. This situation must be avoided in CFBC's because the CO{sub 2} produced inside the particle during calcination can destroy the particles if a non-porous sulphate product layer has been formed around the particle. The effect of the main variables on the sorbent sulphation such as SO{sub 2} concentration, temperature, and particle size were analysed in the long term TGA tests. These data were also used to determine the kinetic parameters for the sulphation under oxy-fuel combustion conditions, which were able to adequately predict the sulphation conversion values in a wide range of operating conditions. 20 refs., 5 figs., 2 tabs.

  6. Artificial Neural Network-Based Monitoring of the Fuel Assembly Temperature Sensor and FPGA Implementation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2015-07-01

    Numerous methods have been developed around the world to model the dynamic behavior and detect a faulty operating mode of a temperature sensor. In this context, we present in this study a new method based on the dependence between the fuel assembly temperature profile on control rods positions, and the coolant flow rate in a nuclear reactor. This seems to be possible since the insertion of control rods at different axial positions and variations in flow rate of the reactor coolant results in different produced thermal power in the reactor. This is closely linked to the instant fuel rod temperature profile. In a first step, we selected parameters to be used and confirmed the adequate correlation between the chosen parameters and those to be estimated by the proposed monitoring system. In the next step, we acquired and de-noised the data of corresponding parameters, the qualified data is then used to design and train the artificial neural network. The effective data denoising was done by using the wavelet transform to remove a various kind of artifacts such as inherent noise. With the suitable choice of wavelet level and smoothing method, it was possible for us to remove all the non-required artifacts with a view to verify and analyze the considered signal. In our work, several potential mother wavelet functions (Haar, Daubechies, Bi-orthogonal, Reverse Bi-orthogonal, Discrete Meyer and Symlets) were investigated to find the most similar function with the being processed signals. To implement the proposed monitoring system for the fuel rod temperature sensor (03 wire RTD sensor), we used the Bayesian artificial neural network 'BNN' technique to model the dynamic behavior of the considered sensor, the system correlate the estimated values with the measured for the concretization of the proposed system we propose an FPGA (field programmable gate array) implementation. The monitoring system use the correlation. (authors)

  7. Adsorptive Desulfurization of JP-8 Fuel Using Ag+/Silica Based Adsorbents at Room Temperature

    Science.gov (United States)

    2012-09-01

    cell-quality hydrogen is liquid phase desulfurization (figure 1). Any organic sulfur compounds in the fuel are converted into hydrogen sulfide in...the fuel processing reformer, resulting in poisoning the reformation catalysts as well as poisoning downstream operations. Therefore, it is essential...the reformation catalysts from potential poisoning (1). Figure 1. Schematic diagram of logistic fuel processing. Adsorbents with a high

  8. Scale formation on Ni-based alloys in simulated solid oxide fuel cell interconnect environments

    Energy Technology Data Exchange (ETDEWEB)

    Ziomek-Moroz, Margaret; Cramer, Stephen D.; Holcomb, Gordon R.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Singh, P. (PNNL); Windisch, C.F. (PNNL); Johnson, C.D. (NETL); Schaeffer, C. (National Energy Research Laboratory, Morgantown, WV)

    2004-11-01

    Recent publications suggest that the environment on the fuel side of the bi-polar stainless steel SOFC interconnects changes the oxidation behavior and morphology of the scale formed on the air side. The U.S. Department of Energy Albany Research Center (ARC), has examined the role of such exposure conditions on advanced nickel base alloys. Alloy formulations developed at ARC and commercial alloys were studied using X-ray diffraction (XRD) and Raman spectroscopy. The electrical property of oxide scales formed on selected alloys was determined in terms of areaspecific resistance (ASR). The corrosion behavior of ARC nickel-based alloys exposed to a dual environment of air/ H2 were compared to those of Crofer 22APU and Haynes 230.

  9. Wave-Based Attitude Control of Spacecraft with Fuel Sloshing Dynamics

    Directory of Open Access Journals (Sweden)

    Thompson Joseph William

    2016-06-01

    Full Text Available Wave-Based Control has been previously applied successfully to simple under-actuated flexible mechanical systems. Spacecraft and rockets with structural flexibility and sloshing are examples of such systems but have added difficulties due to non-uniform structure, external disturbing forces and non-ideal actuators and sensors. The aim of this paper is to extend the application of WBC to spacecraft systems, to compare the performance of WBC to other popular controllers and to carry out experimental validation of the designed control laws. A mathematical model is developed for an upper stage accelerating rocket moving in a single plane. Fuel sloshing is represented by an equivalent mechanical pendulum model. A wave-based controller is designed for the upper stage AVUM of the European launcher Vega. In numerical simulations the controller successfully suppresses the sloshing motion. A major advantage of the strategy is that no measurement of the pendulum states (sloshing motion is required.

  10. Iron-based alloy and nitridation treatment for PEM fuel cell bipolar plates

    Science.gov (United States)

    Brady, Michael P [Oak Ridge, TN; Yang, Bing [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN

    2010-11-09

    A corrosion resistant electrically conductive component that can be used as a bipolar plate in a PEM fuel cell application is composed of an alloy substrate which has 10-30 wt. % Cr, 0.5 to 7 wt. % V, and base metal being Fe, and a continuous surface layer of chromium nitride and vanadium nitride essentially free of base metal. A oxide layer of chromium vanadium oxide can be disposed between the alloy substrate and the continuous surface nitride layer. A method to prepare the corrosion resistant electrically conductive component involves a two-step nitridization sequence by exposing the alloy to a oxygen containing gas at an elevated temperature, and subsequently exposing the alloy to an oxygen free nitrogen containing gas at an elevated temperature to yield a component where a continuous chromium nitride layer free of iron has formed at the surface.

  11. Enhancement of the fuel cell performance of a high temperature proton exchange membrane fuel cell running with titanium composite polybenzimidazole-based membranes

    Science.gov (United States)

    Lobato, Justo; Cañizares, Pablo; Rodrigo, Manuel A.; Úbeda, Diego; Pinar, F. Javier

    2011-10-01

    The fuel cell performance of a composite PBI-based membrane with TiO2 has been studied. The behaviour of the membrane has been evaluated by comparison with the fuel cell performance of other PBI-based membranes, all of which were cast from the same polymer with the same molecular weight. The PBI composite membrane incorporating TiO2 showed the best performance and reached 1000 mW cm-2 at 175 °C. Moreover, this new titanium composite PBI-based membrane also showed the best stability during the preliminary long-term test under our operation conditions. Thus, the slope of the increase in the ohmic resistance of the composite membrane was 0.041 mΩ cm2 h-1 and this is five times lower than that of the standard PBI membrane. The increased stability was due to the high phosphoric acid retention capacity - as confirmed during leaching tests, in which the Ti-based composite PBI membrane retained 5 mol of H3PO4/PBI r.u. whereas the PBI standard membrane only retained 1 mol H3PO4/PBI r.u. Taking into account the results obtained in this study, the TiO2-PBI based membranes are good candidates as electrolytes for high temperature PEMFCs.

  12. A comparison of high-speed flywheels, batteries, and ultracapacitors on the bases of cost and fuel economy as the energy storage system in a fuel cell based hybrid electric vehicle

    Science.gov (United States)

    Doucette, Reed T.; McCulloch, Malcolm D.

    Fuel cells aboard hybrid electric vehicles (HEVs) are often hybridized with an energy storage system (ESS). Batteries and ultracapacitors are the most common technologies used in ESSs aboard HEVs. High-speed flywheels are an emerging technology with traits that have the potential to make them competitive with more established battery and ultracapacitor technologies in certain vehicular applications. This study compares high-speed flywheels, ultracapacitors, and batteries functioning as the ESS in a fuel cell based HEV on the bases of cost and fuel economy. In this study, computer models were built to simulate the powertrain of a fuel cell based HEV where high-speed flywheels, batteries, and ultracapacitors of a range of sizes were used as the ESS. A simulated vehicle with a powertrain using each of these technologies was run over two different drive cycles in order to see how the different ESSs performed under different driving patterns. The results showed that when cost and fuel economy were both considered, high-speed flywheels were competitive with batteries and ultracapacitors.

  13. Approach for Emissions Compliance in the Fossil-Fuel Based Energy Sector

    Energy Technology Data Exchange (ETDEWEB)

    Alain, Bill; Bitran, Guillaume; Basler, Benno; Hess, Stephan

    2007-07-01

    Most of today's air pollution legislation varies from country to country depending on factors such as the economy, fuel supply, fuel dependency and specific local pollution problems. At the same time, in a growing number of countries, the energy sector is going through privatisation, deregulation and globalisation process which is affecting energy demand and fuel selection, driving gradual integration of energy markets and requiring new solutions. Today it is also well recognized that pollution is often not a localized problem and that gaseous air pollutants can cross great distances. This has led to the cooperation between countries to control transboundary pollution, under bilateral or multilateral agreements. Similarly as for the energy sector, countries are not only becoming increasingly linked to each other in political, economic and social terms but also in environmental terms. Power generators and equipment manufacturers have been developing technologies and business agreements in countries with respective legislation constraints over many years and take this trend of interdependence into account. The equipment manufacturers and global solution providers such as Alstom have become the focal point driving the development of new environmental compliance products and solutions within the fossil fuel based energy sector. Technological progress achieved in many fields over recent years in different areas of the world according to the different legislations allows the power generators to meet these increasingly stringent emissions reduction requirements while extending the plant lifetime of existing power plants, and keeping them competitive. This paper gives an overview and outlook of environmental regulations, air pollution control technologies and some experience in pioneering environmental long-term service agreements. Obviously, the most immediately effective way to ensure emissions compliance of existing power plant is to professionally maintain and

  14. Forecasting Fossil Fuel Energy Consumption for Power Generation Using QHSA-Based LSSVM Model

    Directory of Open Access Journals (Sweden)

    Wei Sun

    2015-01-01

    Full Text Available Accurate forecasting of fossil fuel energy consumption for power generation is important and fundamental for rational power energy planning in the electricity industry. The least squares support vector machine (LSSVM is a powerful methodology for solving nonlinear forecasting issues with small samples. The key point is how to determine the appropriate parameters which have great effect on the performance of LSSVM model. In this paper, a novel hybrid quantum harmony search algorithm-based LSSVM (QHSA-LSSVM energy forecasting model is proposed. The QHSA which combines the quantum computation theory and harmony search algorithm is applied to searching the optimal values of and C in LSSVM model to enhance the learning and generalization ability. The case study on annual fossil fuel energy consumption for power generation in China shows that the proposed model outperforms other four comparative models, namely regression, grey model (1, 1 (GM (1, 1, back propagation (BP and LSSVM, in terms of prediction accuracy and forecasting risk.

  15. Micro-tubular solid oxide fuel cell based on a porous yttria-stabilized zirconia support.

    Science.gov (United States)

    Panthi, Dhruba; Tsutsumi, Atsushi

    2014-08-29

    Solid oxide fuel cells (SOFCs) are promising electrochemical energy conversion devices owing to their high power generation efficiency and environmentally benign operation. Micro-tubular SOFCs, which have diameters ranging from a few millimeters to the sub-millimeter scale, offer several advantages over competing SOFCs such as high volumetric power density, good endurance against thermal cycling, and flexible sealing between fuel and oxidant streams. Herein, we successfully realized a novel micro-tubular SOFC design based on a porous yttria-stabilized zirconia (YSZ) support using multi-step dip coating and co-sintering methods. The micro-tubular SOFC consisted of Ni-YSZ, YSZ, and strontium-doped lanthanum manganite (LSM)-YSZ as the anode, electrolyte, and cathode, respectively. In addition, to facilitate current collection from the anode and cathode, Ni and LSM were applied as an anode current collector and cathode current collector, respectively. Micro-crystalline cellulose was selected as a pore former to achieve better shrinkage behavior of the YSZ support so that the electrolyte layer could be densified at a co-sintering temperature of 1300 °C. The developed micro-tubular design showed a promising electrochemical performance with maximum power densities of 525, 442, and 354 mW cm(-2) at 850, 800, and 750 °C, respectively.

  16. Study of fuel control strategy based on an fuel behavior model for starting conditions; Nenryo kyodo model ni motozuita shidoji no nenryo hosei hosho ni tsuite no kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Nakajima, Y.; Uchida, M.; Iwano, H.; Oba, H. [Nissan Motor Co. Ltd., Tokyo (Japan)

    1997-10-01

    We have applied a fuel behavior model to a fuel injection system which we call SOFIS (Sophisticated and Optimized Fuel Injection System) so that we get air/fuel ratio control accuracy and good driveability. However the fuel behavior under starting conditions is still not clear. To meet low emission rules and to get better driveability under starting conditions, better air/fuel ratio control is necessary. Now we have understood the ignition timing, injection timing, and injection pulse width required in such conditions. In former days, we analyzed the state of the air/fuel mixture under cold conditions and made a new fuel behavior model which considered fuel loss such as hydrocarbons and dissolution into oil and so on. Al this time, we have applied this idea to starting. We confirm this new model offers improved air/fuel ratio control. 6 refs., 9 figs., 3 tabs.

  17. Production of planar copper-based anode supported intermediate temperature solid oxide fuel cells cosintered at 950 °C

    Science.gov (United States)

    De Marco, Vincenzo; Grazioli, Alberto; Sglavo, Vincenzo M.

    2016-10-01

    Copper-based anode supported planar Intermediate Temperature Solid Oxide Fuel Cells are produced and characterized in the present work. The most important advancement is related to the use of copper within the anodic layer, this giving promising results for feeding Intermediate Temperature Solid Oxide Fuel Cells with carbon and sulphur containing fuels. Both anode and Li2O containing-Gadolinia Doped Ceria based electrolyte are produced by water based tape casting process. The supporting anode is coupled to the electrolyte by thermopressing, the cathode being obtained by screen printing. A 3 h isotherm at 950 °C allows to obtain the cosintering of the three layers. The electrochemical test performed on such cells reveals a 0.8 V open circuit voltage and a power density higher than 26 mW cm-2 at 650 °C.

  18. A fuel cell operating between room temperature and 250 °C based on a new phosphoric acid based composite electrolyte

    Science.gov (United States)

    Lan, Rong; Xu, Xiaoxiang; Tao, Shanwen; Irvine, John T. S.

    A phosphoric acid based composite material with core-shell microstructure has been developed to be used as a new electrolyte for fuel cells. A fuel cell based on this electrolyte can operate at room temperature indicating leaching of H 3PO 4 with liquid water is insignificant at room temperature. This will help to improve the thermal cyclability of phosphoric acid based electrolyte to make it easier for practical use. The conductivity of this H 3PO 4-based electrolyte is stable at 250 °C with addition of the hydrophilic inorganic compound BPO 4 forming a core-shell microstructure which makes it possible to run a PAFC at a temperature above 200 °C. The core-shell microstructure retains after the fuel cell measurements. A power density of 350 mW/cm 2 for a H 2/O 2 fuel cell has been achieved at 200 °C. The increase in operating temperature does not have significant benefit to the performance of a H 2/O 2 fuel cell. For the first time, a composite electrolyte material for phosphoric acid fuel cells which can operate in a wide range of temperature has been evaluated but certainly further investigation is required.

  19. Gas/Water and Heat Management of PEM-Based Fuel Cell and Electrolyzer Systems for Space Applications

    Science.gov (United States)

    Guo, Qing; Ye, Fang; Guo, Hang; Ma, Chong Fang

    2017-02-01

    Hydrogen/oxygen fuel cells were successfully utilized in the field of space applications to provide electric energy and potable water in human-rated space mission since the 1960s. Proton exchange membrane (PEM) based fuel cells, which provide high power/energy densities, were reconsidered as a promising space power equipment for future space exploration. PEM-based water electrolyzers were employed to provide life support for crews or as major components of regenerative fuel cells for energy storage. Gas/water and heat are some of the key challenges in PEM-based fuel cells and electrolytic cells, especially when applied to space scenarios. In the past decades, efforts related to gas/water and thermal control have been reported to effectively improve cell performance, stability lifespan, and reduce mass, volume and costs of those space cell systems. This study aimed to present a primary review of research on gas/water and waste thermal management for PEM-based electrochemical cell systems applied to future space explorations. In the fuel cell system, technologies related to reactant supplement, gas humidification, water removal and active/passive water separation were summarized in detail. Experimental studies were discussed to provide a direct understanding of the effect of the gas-liquid two-phase flow on product removal and mass transfer for PEM-based fuel cell operating in a short-term microgravity environment. In the electrolyzer system, several active and static passive phaseseparation methods based on diverse water supplement approaches were discussed. A summary of two advanced passive thermal management approaches, which are available for various sizes of space cell stacks, was specifically provided

  20. Gas/Water and Heat Management of PEM-Based Fuel Cell and Electrolyzer Systems for Space Applications

    Science.gov (United States)

    Guo, Qing; Ye, Fang; Guo, Hang; Ma, Chong Fang

    2016-11-01

    Hydrogen/oxygen fuel cells were successfully utilized in the field of space applications to provide electric energy and potable water in human-rated space mission since the 1960s. Proton exchange membrane (PEM) based fuel cells, which provide high power/energy densities, were reconsidered as a promising space power equipment for future space exploration. PEM-based water electrolyzers were employed to provide life support for crews or as major components of regenerative fuel cells for energy storage. Gas/water and heat are some of the key challenges in PEM-based fuel cells and electrolytic cells, especially when applied to space scenarios. In the past decades, efforts related to gas/water and thermal control have been reported to effectively improve cell performance, stability lifespan, and reduce mass, volume and costs of those space cell systems. This study aimed to present a primary review of research on gas/water and waste thermal management for PEM-based electrochemical cell systems applied to future space explorations. In the fuel cell system, technologies related to reactant supplement, gas humidification, water removal and active/passive water separation were summarized in detail. Experimental studies were discussed to provide a direct understanding of the effect of the gas-liquid two-phase flow on product removal and mass transfer for PEM-based fuel cell operating in a short-term microgravity environment. In the electrolyzer system, several active and static passive phaseseparation methods based on diverse water supplement approaches were discussed. A summary of two advanced passive thermal management approaches, which are available for various sizes of space cell stacks, was specifically provided

  1. Economic feasibility analysis of distributed electric power generation based upon the natural gas-fired fuel cell

    Science.gov (United States)

    1994-03-01

    The final report provides a summary of results of the Cost of Ownership Model and the circumstances under which a distributed fuel cell is economically viable. The analysis is based on a series of micro computer models estimates of the capital and operations cost of a fuel cell central utility plant configuration. Using a survey of thermal and electrical demand profiles, the study defines a series of energy user classes. The energy user class demand requirements are entered into the central utility plant model to define the required size the fuel cell capacity and all supporting equipment. The central plant model includes provisions that enables the analyst to select optional plant features that are most appropriate to a fuel cell application, and that are cost effective. The model permits the choice of system features that would be suitable for a large condominium complex or a residential institution such as a hotel, boarding school or prison. Other applications are also practical; however, such applications have a higher relative demand for thermal energy, a characteristic that is well-suited to a fuel cell application with its free source of hot water or steam. The analysis combines the capital and operation from the preceding models into a Cost of Ownership Model to compute the plant capital and operating costs as a function of capacity and principal features and compares these estimates to the estimated operating cost of the same central plant configuration without a fuel cell.

  2. Azcaxalli: A system based on Ant Colony Optimization algorithms, applied to fuel reloads design in a Boiling Water Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Esquivel-Estrada, Jaime, E-mail: jaime.esquivel@fi.uaemex.m [Facultad de Ingenieria, Universidad Autonoma del Estado de Mexico, Cerro de Coatepec S/N, Toluca de Lerdo, Estado de Mexico 50000 (Mexico); Instituto Nacional de Investigaciones Nucleares, Carr. Mexico Toluca S/N, Ocoyoacac, Estado de Mexico 52750 (Mexico); Ortiz-Servin, Juan Jose, E-mail: juanjose.ortiz@inin.gob.m [Instituto Nacional de Investigaciones Nucleares, Carr. Mexico Toluca S/N, Ocoyoacac, Estado de Mexico 52750 (Mexico); Castillo, Jose Alejandro; Perusquia, Raul [Instituto Nacional de Investigaciones Nucleares, Carr. Mexico Toluca S/N, Ocoyoacac, Estado de Mexico 52750 (Mexico)

    2011-01-15

    This paper presents some results of the implementation of several optimization algorithms based on ant colonies, applied to the fuel reload design in a Boiling Water Reactor. The system called Azcaxalli is constructed with the following algorithms: Ant Colony System, Ant System, Best-Worst Ant System and MAX-MIN Ant System. Azcaxalli starts with a random fuel reload. Ants move into reactor core channels according to the State Transition Rule in order to select two fuel assemblies into a 1/8 part of the reactor core and change positions between them. This rule takes into account pheromone trails and acquired knowledge. Acquired knowledge is obtained from load cycle values of fuel assemblies. Azcaxalli claim is to work in order to maximize the cycle length taking into account several safety parameters. Azcaxalli's objective function involves thermal limits at the end of the cycle, cold shutdown margin at the beginning of the cycle and the neutron effective multiplication factor for a given cycle exposure. Those parameters are calculated by CM-PRESTO code. Through the Haling Principle is possible to calculate the end of the cycle. This system was applied to an equilibrium cycle of 18 months of Laguna Verde Nuclear Power Plant in Mexico. The results show that the system obtains fuel reloads with higher cycle lengths than the original fuel reload. Azcaxalli results are compared with genetic algorithms, tabu search and neural networks results.

  3. Assessment of RANS Based CFD Methodology using JAEA Experiment with a Wire-wrapped 127-pin Fuel Assembly

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, J. H.; Yoo, J.; Lee, K. L.; Ha, K. S. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    In this paper, we assess the RANS based CFD methodology with JAEA experimental data. The JAEA experiment study with the 127-pin wire-wrapped fuel assembly was implemented using water for validating pressure drop formulas in ASFRE code. Complicated and vortical flow phenomena in the wire-wrapped fuel bundles were captured by vortex structure identification technique based on the critical point theory. The SFR system is one of the nuclear reactors in which a recycling of transuranics (TRUs) by reusing spent nuclear fuel sustains the fission chain reaction. This situation strongly motivated the Korea Atomic Energy Research Institute (KAERI) to start a prototype Gen-4 Sodium-cooled Fast Reactor (PGSFR) design project under the national nuclear R and D program. Generally, the SFR system has a tight package of the fuel bundle and a high power density. The sodium material has a high thermal conductivity and boiling temperature than the water. That can make core design to be more compact than Light Water Reactor (LWR) through narrower sub-channels. The fuel assembly of the SFR system consists of long and thin wire-wrapped fuel bundles and a hexagonal duct, in which wire-wrapped fuel bundles in the hexagonal tube has triangular loose array. The main purpose of a wire spacer is to avoid collisions between adjacent rods. Furthermore, a wire spacer can mitigate a vortex induced vibration, and enhance convective heat transfer due to the secondary flow by helical type wire spacers. Most of numerical studies in the nuclear fields was widely conducted based on the simplified sub-channel analysis codes such as COBRA (Rowe), SABRE (Macdougall and Lillington), ASFRE (Ninokata), and MATRA-LMR (Kim et al.). The relationship between complex flow phenomena and helically wrapped-wire spacers will be discussed. The RANS based CFD methodology is evaluated with JAEA experimental data of the 127-pin wirewrapped fuel assembly. Complicated and vortical flow phenomena in the wire-wrapped fuel

  4. Energy recovery from waste streams with microbial fuel cell (MFC)-based technologies

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Y.

    2012-09-15

    Microbial fuel cell (MFC)-based technologies are promising technologies for direct energy production from various wastewaters and waste streams. Beside electrical power production, more emphasis is recently devoted to alternative applications such as hydrogen production, bioremediation, seawater desalination, and biosensors. Although the technologies are promising, a number of hurdles need to be overcome before that field applications are economically feasible. The main purpose of this work was to improve the performance, reduce the construction cost, and expand the application scopes of MFC-based bio-electrochemical systems. To reduce the energy cost in nitrogen removal and during the same process achieve phosphorus elimination, a sediment-type photomicrobial fuel cell was developed based on the cooperation between microalgae (Chlorella vulgaris) and electrochemically active bacteria. The main removal mechanism of nitrogen and phosphorus was algae biomass uptake, while nitrification and denitrification process contributed to part of nitrogen removal. The key factors such as algae concentration, COD/N ratios and photoperiod were systemically studied. A self-powered submersible microbial electrolysis cell was developed for in situ biohydrogen production from anaerobic reactors. The hydrogen production increased along with acetate and buffer concentration. The hydrogen production rate of 32.2 mL/L/d and yield of 1.43 mol-H2/mol-acetate were achieved. Alternate exchanging the function between the two cell units was found to be an effective approach to inhibit methanogens. A sensor, based on a submersible microbial fuel cell, was developed for in situ monitoring of microbial activity and biochemical oxygen demand in groundwater. Presence or absence of a biofilm on the anode was a decisive factor for the applicability of the sensor. Temperature, pH, conductivity and inorganic solid content were significantly affecting the sensitivity of the sensor. The sensor showed

  5. Modelling a Combined Heat and Power Plant based on Gasification, Micro Gas Turbine and Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Bang-Møller, Christian; Rokni, Masoud

    2009-01-01

    A system level modelling study on two combined heat and power (CHP) systems both based on biomass gasification. One system converts the product gas in a micro gas turbine (MGT) and the other in a combined solid oxide fuel cell (SOFC) and MGT arrangement. An electrochemical model of the SOFC has...... been developed and calibrated against published data from Topsoe Fuel Cells A/S (TOFC) and Risø National Laboratory, and the modelled gasifier is based on an up scaled version of the demonstrated low tar gasifier, Viking, situated at the Technical University of Denmark. The SOFC converts the syngas...

  6. Temperature modeling and control of Direct Methanol Fuel Cell based on adaptive neural fuzzy technology

    Institute of Scientific and Technical Information of China (English)

    Qi Zhidong; Zhu Xinjian; Cao Guangyi

    2006-01-01

    Aiming at on-line controlling of Direct Methanol Fuel Cell (DMFC) stack, an adaptive neural fuzzy inference technology is adopted in the modeling and control of DMFC temperature system. In the modeling process, an Adaptive Neural Fuzzy Inference System (ANFIS) identification model of DMFC stack temperature is developed based on the input-output sampled data, which can avoid the internal complexity of DMFC stack. In the controlling process, with the network model trained well as the reference model of the DMFC control system, a novel fuzzy genetic algorithm is used to regulate the parameters and fuzzy rules of a neural fuzzy controller. In the simulation, compared with the nonlinear Proportional Integral Derivative (PID) and traditional fuzzy algorithm, the improved neural fuzzy controller designed in this paper gets better performance, as demonstrated by the simulation results.

  7. Study on Model Based Combustion Control of Diesel Engine with Multi Fuel Injection

    Science.gov (United States)

    Ikemura, R.; Yamasaki, Y.; Kaneko, S.

    2016-09-01

    A controller for model-based control of diesel engine with triple injection were developed with a combustion model. In the combustion model, an engine cycle is discretized into several representative points in order to improve calculation speed, while physical equations are employed to expand the versatility. The combustion model can predict in-cylinder pressure and temperature in these discrete points. Prediction accuracy of the combustion model was evaluated by comparison with experimental result. A controller was designed with the combustion model in order to calculate optimal fuel injection pattern for controlling in-cylinder pressure peak timing. The controller's performance was evaluated through simulation in which the combustion model was used as a plant model.

  8. Micromechanical Modeling of Solid Oxide Fuel Cell Anode Supports based on Three-dimensional Reconstructions

    DEFF Research Database (Denmark)

    Kwok, Kawai; Jørgensen, Peter Stanley; Frandsen, Henrik Lund

    2014-01-01

    The efficiency and lifetime of solid oxide fuel cells (SOFCs) is compromised by mechanical failure of cells in the system. Improving the mechanical reliability is a major step in ensuring feasibility of the technology. To quantify the stress in a cell, mechanical properties of the different layers...... need to be accurately known. Since the mechanical properties are heavily dependent on the microstructures of the materials, it is highly advantageous to understand the impact of microstructures and to be able to determine accurate effective mechanical properties for cell or stack scale analyses...... are computed by the finite element method. The macroscopic creep response of the porous anode support is determined based on homogenization theory. It is shown that micromechanical modeling provides an effective tool to study the effect of microstructures on the macroscopic properties....

  9. Residential Systems Based on Solid Oxide Fuel Cells for Scandinavian Climate

    DEFF Research Database (Denmark)

    Rokni, Masoud; Vialetto, Giulio

    2015-01-01

    are performed under different strategies at a resort located in a northern European climate (Denmark) to cover electricity, space heating and domestic hot water (DHW) demands. The results of these simulations are analyzed with thermodynamic and techno-economic benchmarks, considering different economic...... of them received subsidies to increase installation and reduce cost. This article presents an innovative cogeneration system based on a solid oxide fuel cell (SOFC) system and heat pump for household applications with a focus on primary energy and economic savings using electric equivalent load parameter...... which is a function of the electricity and heat demand of the user, and allows different operation strategies to be considered. The proposal is to maximize the efficiency of the system and to make it profitable, even though technologies with a high purchase cost are considered. Simulations of the system...

  10. A New Cogeneration Residential System Based on Solid Oxide Fuel Cells for a Northern European Climate

    DEFF Research Database (Denmark)

    Vialetto, Giulio; Rokni, Masoud

    2015-01-01

    are performed under different strategies at a resort located in a northern European climate (Denmark) to cover electricity, space heating and domestic hot water (DHW) demands. The results of these simulations are analyzed with thermodynamic and techno-economic benchmarks, considering different economic...... of them received subsidies to increase installation and reduce cost. This article presents an innovative cogeneration system based on a solid oxide fuel cell (SOFC) system and heat pump for household applications with a focus on primary energy and economic savings using electric equivalent load parameter...... which is a function of the electricity and heat demand of the user, and allows different operation strategies to be considered. The proposal is to maximize the efficiency of the system and to make it profitable, even though technologies with a high purchase cost are considered. Simulations of the system...

  11. A one-compartment fructose/air biological fuel cell based on direct electron transfer.

    Science.gov (United States)

    Wu, Xuee; Zhao, Feng; Varcoe, John R; Thumser, Alfred E; Avignone-Rossa, Claudio; Slade, Robert C T

    2009-10-15

    The construction and characterization of a one-compartment fructose/air biological fuel cell (BFC) based on direct electron transfer is reported. The BFC employs bilirubin oxidase and d-fructose dehydrogenase adsorbed on a cellulose-multiwall carbon nanotube (MWCNT) matrix, reconstituted with an ionic liquid, as the biocathode and the bioanode for oxygen reduction and fructose oxidation reactions, respectively. The performance of the bioelectrode was investigated by chronoamperometric and cyclic voltammetric techniques in a standard three-electrode cell, and the polarization and long-term stability of the BFC was tested by potentiostatic discharge. An open circuit voltage of 663 mV and a maximum power density of 126 microWcm(-2) were obtained in buffer at pH 5.0. Using this regenerated cellulose-MWCNT matrix as the immobilization platform, this BFC has shown a relatively high performance and long-term stability compared with previous studies.

  12. Numerical Modeling of Microbial Fuel Cell Based on Redox Electron Mediator

    Institute of Scientific and Technical Information of China (English)

    Nanqi Ren

    2015-01-01

    To investigate the behavior of redox electron mediator and its impact to power generation of microbial fuel cell ( MFC ) , this study carries out the numerical modeling of a typical two⁃chamber MFC based on assumption of interfacial electron transfer via redox electron mediator and acetate as sole electron donor. The model simulates the development of cell voltage, current, substrate concentration, redox electron mediator concentration, polarization and power density output under defined conditions. The results demonstrate that the developed models can fit the experimental results well on a qualitative basis, and concentration of electron reduced mediator plays a dominant role in electron transfer process, and the mass transfer may constitute the limiting step when its concentration is at a relatively low level. This study not only provides a better understanding of electron redox mediator behavior during power generation, but also suggests a strategy to improve electron transfer in the anode of MFC.

  13. Effect of temperature fluctuation on hydrate-based CO2 separation from fuel gas

    Institute of Scientific and Technical Information of China (English)

    Xiaosen Li; Chungang Xu; Zhaoyang Chen; Huijie Wu; Jing Cai

    2011-01-01

    A new method of temperature fluctuation is proposed to promote the process of hydrate-based CO2 separation from fuel gas in this work according to the dual nature of CO2 solubility in hydrate forming and non-hydrate forming regions [1].The temperature fluctuation operated in the process of hydrate formation improves the formation of gas hydrate observably.The amount of the gas consumed with temperature fluctuation is approximately 35% more than that without temperature fluctuation.It is found that only the temperature fluctuation operated in the period of forming hydrate leads to a good effect on CO2 separation.Meanwhile,with the proceeding of hydrate formation,the effect of temperature fluctuation on the gas hydrate gradually reduces,and little effect is left in the completion term.The CO2 separation efficiencies in the separation processes with the effective temperature fluctuations are improved remarkably.

  14. Microbial fuel cell based biosensor for in situ monitoring of anaerobic digestion process.

    Science.gov (United States)

    Liu, Zhidan; Liu, Jing; Zhang, Songping; Xing, Xin-Hui; Su, Zhiguo

    2011-11-01

    A wall-jet microbial fuel cell (MFC) was developed for the monitoring of anaerobic digestion (AD). This biofilm based MFC biosensor had a character of being portable, short hydraulic retention time (HRT) for sample flow through and convenient for continuous operation. The MFC was installed in the recirculation loop of an upflow anaerobic fixed-bed (UAFB) reactor in bench-scale where pH of the fermentation broth and biogas flow were monitored in real time. External disturbances to the AD were added on purpose by changing feedstock concentration, as well as process configuration. MFC signals had good correlations with online measurements (i.e. pH, gas flow rate) and offline analysis (i.e. COD) over 6-month operation. These results suggest that the MFC signal can reflect the dynamic variation of AD and can potentially be a valuable tool for monitoring and control of bioprocess.

  15. Nano-structured noble metal catalysts based on hexametallate architecture for the reforming of hydrocarbon fuels

    Energy Technology Data Exchange (ETDEWEB)

    Gardner, Todd H.

    2015-09-15

    Nano-structured noble metal catalysts based on hexametallate lattices, of a spinel block type, and which are resistant to carbon deposition and metal sulfide formation are provided. The catalysts are designed for the reforming of hydrocarbon fuels to synthesis gas. The hexametallate lattices are doped with noble metals (Au, Pt, Rh, Ru) which are atomically dispersed as isolated sites throughout the lattice and take the place of hexametallate metal ions such as Cr, Ga, In, and/or Nb. Mirror cations in the crystal lattice are selected from alkali metals, alkaline earth metals, and the lanthanide metals, so as to reduce the acidity of the catalyst crystal lattice and enhance the desorption of carbon deposit forming moieties such as aromatics. The catalysts can be used at temperatures as high as 1000.degree. C. and pressures up to 30 atmospheres. A method for producing these catalysts and applications of their use also is provided.

  16. Auxiliary power unit based on a solid oxide fuel cell and fuelled with diesel

    Science.gov (United States)

    Lawrence, Jeremy; Boltze, Matthias

    An auxiliary power unit (APU) is presented that is fuelled with diesel, thermally self-sustaining, and based on a solid oxide fuel cell (SOFC). The APU is rated at 1 kW electrical, and can generate electrical power after a 3 h warm-up phase. System features include a "dry" catalytic partial oxidation (CPOX) diesel reformer, a 30 cell SOFC stack with an open cathode, and a porous-media afterburner. The APU does not require a supply of external water. The SOFC stack is an outcome of a development partnership with H.C. Starck GmbH and Fraunhofer IKTS, and is discussed in detail in an accompanying paper.

  17. A Sustainable Nuclear Fuel Cycle Based on Laser Inertial Fusion Energy

    Energy Technology Data Exchange (ETDEWEB)

    Moses, E; Diaz de la Rubia, T; Storm, E; Latkowski, J; Farmer, J; Abbott, R; Kramer, K; Peterson, P; Shaw, H; Lehman II, R

    2009-05-22

    The National Ignition Facility (NIF), a laser-based Inertial Confinement Fusion (ICF) experiment designed to achieve thermonuclear fusion ignition and burn in the laboratory, will soon be completed at the Lawrence Livermore National Laboratory. Experiments designed to accomplish the NIF's goal will commence in 2010, using laser energies of 1 to 1.3 MJ. Fusion yields of the order of 10 to 35 MJ are expected soon thereafter. They propose that a laser system capable of generating fusion yields of 35 to 75 MJ at 10 to 15 Hz (i.e., {approx} 350- to 1000-MW fusion and {approx} 1.3 to 3.6 x 10{sup 20} n/s), coupled to a compact subdritical fission blanket, could be used to generate several GW of thermal power (GWth) while avoiding carbon dioxide emissions, mitigating nuclear proliferation concerns and minimizing the concerns associated with nuclear safety and long-term nuclear waste disposition. this Laser Inertial Fusion Energy (LIFE) based system is a logical extension of the NIF laser and the yields expec ted from the early ignition experiments on NIF. The LIFE concept is a once-through,s elf-contained closed fuel cycle and would have the following characteristics: (1) eliminate the need for spent fuel chemical separation facilities; (4) maintain the fission blanket subcritical at all times (k{sub eff} < 0.90); and (5) minimize future requirements for deep underground geological waste repositories and minimize actinide content in the end-of-life nuclear waste below the Department of Energy's (DOE's) attractiveness Level E (the lowest). Options to burn natural or depleted U, Th, U/Th mixtures, Spent Nuclear Fuel (SNF) without chemical separations of weapons-attractive actinide streams, and excess weapons Pu or highly enriched U (HEU) are possible and under consideration. Because the fission blanket is always subcritical and decay heat removal is possible via passive mechanisms, the technology is inherently safe. Many technical challenges must be met, but

  18. Blister Threshold Based Thermal Limits for the U-Mo Monolithic Fuel System

    Energy Technology Data Exchange (ETDEWEB)

    D. M. Wachs; I. Glagolenko; F. J. Rice; A. B. Robinson; B. H. Rabin; M. K. Meyer

    2012-10-01

    Fuel failure is most commonly induced in research and test reactor fuel elements by exposure to an under-cooled or over-power condition that results in the fuel temperature exceeding a critical threshold above which blisters form on the plate. These conditions can be triggered by normal operational transients (i.e. temperature overshoots that may occur during reactor startup or power shifts) or mild upset events (e.g., pump coastdown, small blockages, mis-loading of fuel elements into higher-than-planned power positions, etc.). The rise in temperature has a number of general impacts on the state of a fuel plate that include, for example, stress relaxation in the cladding (due to differential thermal expansion), softening of the cladding, increased mobility of fission gases, and increased fission-gas pressure in pores, all of which can encourage the formation of blisters on the fuel-plate surface. These blisters consist of raised regions on the surface of fuel plates that occur when the cladding plastically deforms in response to fission-gas pressure in large pores in the fuel meat and/or mechanical buckling of the cladding over damaged regions in the fuel meat. The blister temperature threshold decreases with irradiation because the mechanical properties of the fuel plate degrade while under irradiation (due to irradiation damage and fission-product accumulation) and because the fission-gas inventory progressively increases (and, thus, so does the gas pressure in pores).

  19. Support schemes and ownership structures - the policy context for fuel cell based micro-combined heat and power

    DEFF Research Database (Denmark)

    Schröder, Sascha Thorsten; Costa, Ana; Obé, Elisabeth

    2011-01-01

    In recent years, fuel cell based micro-combined heat and power (mCHP) has received increasing attention due to its potential contribution to European energy policy goals, i.e., sustainability, competitiveness and security of supply. Besides technical advances, regulatory framework and ownership s...... for fuel cell mCHP. This can be used for improved analysis of operational strategies. The interaction of this plethora of elements necessitates careful balancing from a private- and socio-economic point of view.......In recent years, fuel cell based micro-combined heat and power (mCHP) has received increasing attention due to its potential contribution to European energy policy goals, i.e., sustainability, competitiveness and security of supply. Besides technical advances, regulatory framework and ownership...

  20. Comparative Performance of Direct Injection Diesel Engines Fueled Using Compressed Natural Gas and Diesel Fuel Based on GT-POWER Simulation

    Directory of Open Access Journals (Sweden)

    Semin

    2008-01-01

    Full Text Available The paper is investigated the application of compressed natural gas (CNG as an alternative fuel and its performance effect in the diesel engines using GT-POWER computational simulation. The CNG as an alternative fuel for four stroke diesel engine modeling was developed from the real diesel engine using GT-POWER computational model with measure all of engine components size. The computational model will be running on mono CNG fuel and mono diesel fuel to simulate and investigate the engine performance effect on the difference fuel. Output of the model simulation shown the effect of diesel engine fueled by CNG performance effect were simulated in any engine speeds parameters.

  1. Palladium-Based Catalysts as Electrodes for Direct Methanol Fuel Cells: A Last Ten Years Review

    Directory of Open Access Journals (Sweden)

    Juan Carlos Calderón Gómez

    2016-08-01

    Full Text Available Platinum-based materials are accepted as the suitable electrocatalysts for anodes and cathodes in direct methanol fuel cells (DMFCs. Nonetheless, the increased demand and scarce world reserves of Pt, as well as some technical problems associated with its use, have motivated a wide research focused to design Pd-based catalysts, considering the similar properties between this metal and Pt. In this review, we present the most recent advancements about Pd-based catalysts, considering Pd, Pd alloys with different transition metals and non-carbon supported nanoparticles, as possible electrodes in DMFCs. In the case of the anode, different reported works have highlighted the capacity of these new materials for overcoming the CO poisoning and promote the oxidation of other intermediates generated during the methanol oxidation. Regarding the cathode, the studies have showed more positive onset potentials, as fundamental parameter for determining the mechanism of the oxygen reduction reaction (ORR and thus, making them able for achieving high efficiencies, with less production of hydrogen peroxide as collateral product. This revision suggests that it is possible to replace the conventional Pt catalysts by Pd-based materials, although several efforts must be made in order to improve their performance in DMFCs.

  2. Performance study of direct borohydride fuel cells employing polyvinyl alcohol hydrogel membrane and nickel-based anode

    Energy Technology Data Exchange (ETDEWEB)

    Ma, J.; Choudhury, N.A.; Sahai, Y.; Buchheit, R.G. [Department of Materials Science and Engineering, Ohio State University, Columbus, OH 43210 (United States)

    2011-10-15

    A direct borohydride fuel cell (DBFC) employing a polyvinyl alcohol (PVA) hydrogel membrane and a nickel-based composite anode is reported. Carbon-supported platinum and sputtered gold have been employed as cathode catalysts. Oxygen, air and acidified hydrogen peroxide have been used as oxidants in the DBFC. Performance of the PVA hydrogel membrane-based DBFC was tested at different temperatures and compared with similar DBFCs employing Nafion registered membrane electrolytes under identical conditions. The borohydride-oxygen fuel cell employing PVA hydrogel membrane yielded a maximum peak power density of 242 mW cm{sup -2} at 60 C. The peak power densities of the PVA hydrogel membrane-based DBFCs were comparable or a little higher than those using Nafion registered 212 membranes at 60 C. The fuel efficiency of borohydride-oxygen fuel cell based on PVA hydrogel membrane and Ni-based composite anode was found to be between 32 and 41%. The cell was operated for more than 100 h and its performance stability was recorded. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  3. A new formulation of physical surrogates of FACE A gasoline fuel based on heating and evaporation characteristics

    KAUST Repository

    Elwardani, Ahmed Elsaid

    2016-02-19

    The US Department of Energy has formulated various sets of gasoline fuels, called fuels for advanced combustion engines (FACE), which are consistent in composition and properties. The analysis of heating and evaporation of FACE A gasoline fuel (paraffin-rich) is studied by replacing the 66 components with 19 components to represent this fuel. The reduction in the number of components is based on merging components from the same chemical groups and having the same chemical formula, which have very close thermophysical properties; the components with the highest initial compositions are chosen to be the representative components. Modelling of heating and evaporation of FACE A gasoline fuel and various surrogates is carried out based on the effective thermal conductivity/effective diffusivity model (ETC/ED). The model takes into account the effect of finite liquid thermal conductivity, finite liquid mass diffusivity and recirculation inside the droplets due to their non-zero velocities relative to the ambient air. Four surrogates of FACE A found in the literature are used in the analysis. These surrogates include the five component surrogate chosen for its ability to match the ignition delay time of the FACE A gasoline fuel (Surr1), the primary reference fuel surrogate (PRF84) that matches the research octane number (RON) of FACE A, the one that matches hydrogen-to-carbon ratio (H/C), RON, density and distillation curve with FACE A (Surr2), and the one that matches the RON based on mole fraction linear blending (Surr3). It is shown that these surrogates cannot predict adequately the time evolution of surface temperatures and radii of FACE A droplets. New \\'physical\\' surrogates with 8, 7 and 6 components (Surr4, Surr5, and Surr6) are introduced to match the evaporation characteristics of FACE A. It is found that Surr5 (7 components surrogate) can predict droplet lifetime and time evolution of surface temperature of a FACE A droplet with errors of up to 5% and 0

  4. Fuzzy Logic Based Control of Power of PEM Fuel Cell System for Residential Application

    Directory of Open Access Journals (Sweden)

    Khaled MAMMAR

    2009-07-01

    Full Text Available This paper presents a dynamic model of Fuel cell system for residential power generation. The models proposed include a fuel cell stack model, reformer model and DC/AC inverter model. Furthermore a fuzzy logic (FLC controller is used to control active power of PEM fuel cell system. The controller modifies the hydrogen flow feedback from the terminal load. Simulation results confirmed the high performance capability of the fuzzy logic controller to control power generation.

  5. Fuzzy Logic Based Control of Power of PEM Fuel Cell System for Residential Application

    OpenAIRE

    Khaled MAMMAR; CHAKER, Abdelkader

    2009-01-01

    This paper presents a dynamic model of Fuel cell system for residential power generation. The models proposed include a fuel cell stack model, reformer model and DC/AC inverter model. Furthermore a fuzzy logic (FLC) controller is used to control active power of PEM fuel cell system. The controller modifies the hydrogen flow feedback from the terminal load. Simulation results confirmed the high performance capability of the fuzzy logic controller to control power generation.

  6. Research of power fuel low-temperature vortex combustion in industrial boiler based on numerical modelling

    Directory of Open Access Journals (Sweden)

    Orlova K.Y.

    2017-01-01

    Full Text Available The goal of the presented research is to perform numerical modelling of fuel low-temperature vortex combustion in once-through industrial steam boiler. Full size and scaled-down furnace model created with FIRE 3D software and was used for the research. All geometrical features were observed. The baseline information for the low-temperature vortex furnace process are velocity and temperature of low, upper and burner blast, air-fuel ratio, fuel consumption, coal dust size range. The obtained results are: temperature and velocity three dimensional fields, furnace gases and solid fuel ash particles concentration.

  7. Supply Chain Based Solution to Prevent Fuel Tax Evasion: Proof of Concept Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Capps, Gary J [ORNL; Lascurain, Mary Beth [ORNL; Franzese, Oscar [ORNL; Earl, Dennis Duncan [ORNL; West, David L [ORNL; McIntyre, Timothy J [ORNL; Chin, Shih-Miao [ORNL; Hwang, Ho-Ling [ORNL; Connatser, Raynella M [ORNL; Lewis Sr, Samuel Arthur [ORNL; Moore, Sheila A [ORNL

    2011-12-01

    The goal of this research was to provide a proof-of-concept (POC) system for preventing non-taxable (non-highway diesel use) or low-taxable (jet fuel) petrochemical products from being blended with taxable fuel products and preventing taxable fuel products from cross-jurisdiction evasion. The research worked to fill the need to validate the legitimacy of individual loads, offloads, and movements by integrating and validating, on a near-real-time basis, information from global positioning system (GPS), valve sensors, level sensors, and fuel-marker sensors.

  8. UP-report. Fuel-based energy systems. Basis of the Development platform. Fuel to the Swedish Energy Agency's strategy work FOKUS; UP-rapport. Braenslebaserade energisystem. Underlag fraan Utvecklingsplattformen. Braensle till Energimyndighetens strategiarbete FOKUS

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-11-01

    The report serves as input to the Swedish Energy Agency's strategies and priorities for research and innovation in the fuel-based energy system for the period 2011 - 2016. The report has been compiled by members of the development platform Fuel. This report provides background and conditions for the fuel based energy system, and proposed priorities and activities for future efforts in this area. The development platform has contributed with valuable experience and knowledge which enabled the Swedish Energy Agency to then develop a strategy that meets the needs of the society and business.

  9. The emergence of new technology-based industries: the case of fuel cells and its technological relatedness to regional knowledge bases

    DEFF Research Database (Denmark)

    Tanner, Anne Nygaard

    2016-01-01

    Evolutionary economic geographers propose that regional diversification is a path-dependent process whereby industries grow out of pre-existing industrial structures through technologically related localised knowledge spillovers and learning. This article examines whether this also applies...... to emerging radical technologies that create the foundation for new industries. The article develops a new measure for technological relatedness between the knowledge base of a region and that of a radical technology based on patent classes. It demonstrates that emerging fuel cell technology develops where...... the regional knowledge base is technologically related to that of fuel cells and consequently confirms the evolutionary thesis....

  10. Integrated data base report--1996: US spent nuclear fuel and radioactive waste inventories, projections, and characteristics

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-01

    The Integrated Data Base Program has compiled historic data on inventories and characteristics of both commercial and U.S. Department of Energy (DOE) spent nuclear fuel (SNF) and commercial and U.S. government-owned radioactive wastes. Inventories of most of these materials are reported as of the end of fiscal year (FY) 1996, which is September 30, 1996. Commercial SNF and commercial uranium mill tailings inventories are reported on an end-of-calendar year (CY) basis. All SNF and radioactive waste data reported are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecasted is consistent with the latest DOE/Energy Information Administration (EIA) projections of U.S. commercial nuclear power growth and the expected DOE-related and private industrial and institutional activities. The radioactive materials considered, on a chapter-by-chapter basis, are SNF, high-level waste, transuranic waste, low-level waste, uranium mill tailings, DOE Environmental Restoration Program contaminated environmental media, naturally occurring and accelerator-produced radioactive material, and mixed (hazardous and radioactive) low-level waste. For most of these categories, current and projected inventories are given through FY 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions.

  11. Fe3C-based oxygen reduction catalysts: synthesis, hollow spherical structures and applications in fuel cells

    DEFF Research Database (Denmark)

    Hu, Yang; Jensen, Jens Oluf; Zhang, Wei

    2015-01-01

    We present a detailed study of a novel Fe3C-based spherical catalyst with respect to synthetic parameters, nanostructure formation, ORR active sites and fuel cell demonstration. The catalyst is synthesized by high temperature autoclave pyrolysis using decomposing precursors. Below 500 °C, melamine...

  12. Effect of chloride impurities on the performance and durability of polybenzimidazole-based high temperature proton exchange membrane fuel cells

    DEFF Research Database (Denmark)

    Ali, Syed Talat; Li, Qingfeng; Pan, Chao;

    2011-01-01

    The effect of chloride as an air impurity and as a catalyst contaminant on the performance and durability of polybenzimidazole (PBI)-based high temperature proton exchange membrane fuel cell (HT-PEMFC) was studied. The ion chromatographic analysis reveals the existence of chloride contaminations...

  13. Influence of reaction products of K-getter fuel additives on commercial vanadia-based SCR catalysts

    DEFF Research Database (Denmark)

    Castellino, Francesco; Jensen, Anker Degn; Johnsson, Jan Erik

    2009-01-01

    Commercial vanadia-based full-length monoliths have been exposed to aerosols formed by injection of K3PO4 (dissolved in water) in a hot flue gas (T > 850 °C) from a natural gas burner. Such aerosols may form when burning fuels with high K- and P-content, or when P-compounds are mixed with biomass...

  14. Applying distance-to-target weighing methodology to evaluate the environmental performance of bio-based energy, fuels, and materials

    NARCIS (Netherlands)

    Weiss, M.; Patel, M.K.; Heilmeier, H.; Bringezu, S.

    2007-01-01

    The enhanced use of biomass for the production of energy, fuels, and materials is one of the key strategies towards sustainable production and consumption. Various life cycle assessment (LCA) studies demonstrate the great potential of bio-based products to reduce both the consumption of non-renewabl

  15. Modelling a Combined Heat and Power Plant based on Gasification, Micro Gas Turbine and Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Bang-Møller, Christian; Rokni, Masoud

    2009-01-01

    A system level modelling study on two combined heat and power (CHP) systems both based on biomass gasification. One system converts the product gas in a micro gas turbine (MGT) and the other in a combined solid oxide fuel cell (SOFC) and MGT arrangement. An electrochemical model of the SOFC has...

  16. Innovation processes of knowledge-based technologies. Example of PEM fuel cell; Innovationsprozesse wissensbasierter Technologien. Beispiel der PEM-Brennstoffzelle

    Energy Technology Data Exchange (ETDEWEB)

    Bertram, Bjoern

    2011-07-01

    Knowledge as distinguished from increasingly crucial factor of production and forms the basis for development of knowledge-based technologies. This study analyzed the example of the PEM fuel cell technology, this innovation process, drawing upon the heuristic of the innovation system. At the same time a detailed picture of the PEM technology as part of the electric mobility is drawn. (orig.)

  17. Impedance Analysis of the Conditioning of PBI–Based Electrode Membrane Assemblies for High Temperature PEM Fuel Cells

    DEFF Research Database (Denmark)

    Araya, Samuel Simon; Vang, Jakob Rabjerg; Andreasen, Søren Juhl;

    2013-01-01

    This work analyses the conditioning of single fuel cell assemblies based on different membrane electrode assembly (MEA) types, produced by different methods. The analysis was done by means of electrochemical impedance spectroscopy, and the changes in the fitted resistances of the all the tested...

  18. The Fossil Fueled Metropolis: Los Angeles and the Emergence of Oil-Based Energy in North America, 1865--1930

    Science.gov (United States)

    Cooke, Jason Arthur

    Beginning with coal in the nineteenth century, the mass production and intensive consumption of fossil fuel energy fundamentally changed patterns of urban and industrial development in North America. Focusing on the metropolitan development of Los Angeles, this dissertation examines how the emergence of oil-based capitalism in the first three decades of the twentieth century was sustained and made increasingly resilient through the production of urban and industrial space. In a region where coal was scarce, the development of oil-based energy was predicated on long-term investments into conversion technologies, storage systems and distribution networks that facilitated the efficient and economical flow of liquefied fossil fuel. In this dissertation, I argue that the historical and geographical significance of the Southern California petroleum industry is derived from how its distinctive market expansion in the first three decades of the twentieth century helped establish the dominance of oil-based energy as the primary fuel for transportation in capitalist society. In North America, the origins of oil-based capitalism can be traced to the turn of the twentieth century when California was the largest oil-producing economy in the United States and Los Angeles was the fastest growing metropolitan region. This dissertation traces how Los Angeles became the first city in North America where oil became a formative element of urban and industrial development: not only as fuel for transportation, but also in the infrastructures, landscapes and networks that sustain a critical dependence on oil-based energy. With a distinctive metropolitan geography, decentralized and automobile-dependent, Los Angeles became the first oil-based city in North America and thus provides an ideal case study for examining the regional dynamics of energy transition, establishment and dependence. Interwoven with the production of urban and industrial space, oil remains the primary fuel that

  19. Comparative Performance of Direct Injection Diesel Engines Fueled Using Compressed Natural Gas and Diesel Fuel Based on GT-POWER Simulation

    OpenAIRE

    Semin; Abdul R. Ismail; Rosli A. Bakar

    2008-01-01

    The paper is investigated the application of compressed natural gas (CNG) as an alternative fuel and its performance effect in the diesel engines using GT-POWER computational simulation. The CNG as an alternative fuel for four stroke diesel engine modeling was developed from the real diesel engine using GT-POWER computational model with measure all of engine components size. The computational model will be running on mono CNG fuel and mono diesel fuel to simulate and investigate the engine pe...

  20. The Tasse concept (thorium based accelerator driven system with simplified fuel cycle for long term energy production)

    Energy Technology Data Exchange (ETDEWEB)

    Berthou, V. [CEA Cadarache, 13 - Saint Paul lez Durance (France); Slessarev, I.; Salvatores, M. [IRI, TU Delft (Netherlands)

    2001-07-01

    Within the framework of the nuclear waste management studies, the ''one-component''. concept has to be considered as an attractive option in the long-term perspective. This paper proposes a new system called TASSE (''Thorium based Accelerator driven System with Simplified fuel cycle for long term Energy production''.), destined to the current French park renewal. The main idea of the TASSE concept is to simplify both the front and the back end of the fuel cycle, and his major goals are to provide electricity with low waste production, and with an economical competitiveness. (author)

  1. Methyl phosphate formation as a major degradation mode of direct methanol fuel cells with phosphoric acid based electrolytes

    DEFF Research Database (Denmark)

    Aili, David; Vassiliev, Anton; Jensen, Jens Oluf

    2015-01-01

    Phosphoric acid and phosphoric acid doped polymer membranes are widely used as electrolytes in hydrogen based fuel cells operating at elevated temperatures. Such electrolytes have been explored for direct oxidation of methanol to further increase the versatility of the systems, however......, with demonstrated lifetimes of only a few days to weeks. In this work the methyl phosphate formation from the acid and methanol is identified and proposed to be a major mechanism for the cell degradation. Proton conductivity and fuel cell durability tests validate the mechanism at high methanol contents....

  2. Life-Cycle Analyses of Energy Consumption and GHG Emissions of Natural Gas-Based Alternative Vehicle Fuels in China

    Directory of Open Access Journals (Sweden)

    Xunmin Ou

    2013-01-01

    Full Text Available Tsinghua life-cycle analysis model (TLCAM has been used to examine the primary fossil energy consumption and greenhouse gas (GHG emissions for natural gas- (NG- based alternative vehicle fuels in China. The results show that (1 compress NG- and liquid NG-powered vehicles have similar well-to-wheels (WTW fossil energy uses to conventional gasoline- and diesel-fueled vehicles, but differences emerge with the distance of NG transportation. Additionally, thanks to NG having a lower carbon content than petroleum, CNG- and LNG-powered vehicles emit 10–20% and 5–10% less GHGs than gasoline- and diesel-fueled vehicles, respectively; (2 gas-to-liquid- (GTL- powered vehicles involve approximately 50% more WTW fossil energy uses than conventional gasoline- and diesel-fueled vehicles, primarily because of the low efficiency of GTL production. Nevertheless, since NG has a lower carbon content than petroleum, GTL-powered vehicles emit approximately 30% more GHGs than conventional-fuel vehicles; (3 The carbon emission intensity of the LNG energy chain is highly sensitive to the efficiency of NG liquefaction and the form of energy used in that process.

  3. Synthesis and characterization of palm oil fuel ash (POFA) and metakaolin based geopolymer for possible application in nanocoating

    Science.gov (United States)

    Khan, Ihsan Ullah; Bhat, A. H.; Masset, Patrick J.; Khan, Farman Ullah; Rehman, Wajid Ur

    2016-11-01

    The main aim of this study was to synthesize and characterize highly amorphous geopolymer from palm oil fuel ash (POFA) and metakaolin, to be used as nanocoating. Geopolymers are man-made aluminosilicate materials that are amorphous analogues of zeolites. The geopolymers were made by condensing a mixture of raw materials metakaolin and palm oil fuel ash (POFA) with alkaline activator at a fixed ratio at room temperature. The kaolin type clay was calcined at 700 °C for 4hrs to transform it into amorphous metakaolin which is more reactive precursor for geopolymer formation. The characteristics of metakaolin and geopolymers (metakaolin and palm oil fuel ash based geopolymers) were analyzed by using x-ray fluorescence (XRF), Fourier transform infra-red spectrometry (FTIR), Thermogravimetric analysis (TG/DTA) and scanning electron microscopy with energy dispersive x-ray analysis (SEM-EDX). FTIR revealed the presence of Al-O and Si-O stretching vibrations of amorphous alumino-silicate structure for metakaolin, palm oil fuel ash and geopolymers. SEM-EDX images showed the presence of reaction product complementary to NASH (N = Na2O, A = Al2O3, S = SiO2, H = H2O) solid. The resulting geopolymers that were synthesized with NaOH/Na2SiO3 solution cured at 60 °C for 3 days. The results demonstrated the suitability of metakaolin and palm oil fuel ash (POFA) for synthesis of geopolymer at room temperatures.

  4. Model-based optimal control of a hybrid power generation system consisting of photovoltaic arrays and fuel cells

    Science.gov (United States)

    Zervas, P. L.; Sarimveis, H.; Palyvos, J. A.; Markatos, N. C. G.

    Hybrid renewable energy systems are expected to become competitive to conventional power generation systems in the near future and, thus, optimization of their operation is of particular interest. In this work, a hybrid power generation system is studied consisting of the following main components: photovoltaic array (PV), electrolyser, metal hydride tanks, and proton exchange membrane fuel cells (PEMFC). The key advantage of the hybrid system compared to stand-alone photovoltaic systems is that it can store efficiently solar energy by transforming it to hydrogen, which is the fuel supplied to the fuel cell. However, decision making regarding the operation of this system is a rather complicated task. A complete framework is proposed for managing such systems that is based on a rolling time horizon philosophy.

  5. Influence of current collectors design on the performance of a silicon-based passive micro direct methanol fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Esquivel, J.P.; Sabate, N.; Santander, J.; Torres-Herrero, N.; Gracia, I.; Ivanov, P.; Fonseca, L.; Cane, C. [Instituto de Microelectronica de Barcelona, IMB-CNM (CSIC), Campus UAB, 08193 Bellaterra, Barcelona (Spain)

    2009-10-20

    In this paper, the influence of current collector open ratio on the performance of a passive micro direct methanol fuel cell is evaluated. The device is based on a hybrid approach consisting of two microfabricated silicon current collectors assembled together with a commercial membrane electrode assembly. The characterization was performed by measuring polarization curves of the fuel cell using current collectors with different open ratios on anode and cathode. Results show that the way in which the open ratio of current collectors is combined has an effect not only on the output power but also on the repeatability of polarization curves. This study allows the setting of some general design rules for current collectors of passive micro direct methanol fuel cells. (author)

  6. New co-products from grain-based fuel ethanol production and their drying performance

    Science.gov (United States)

    Fuel ethanol production in the U.S. and elsewhere is an important and growing industry. In the U.S, about 40% of annual corn production is now converted into fuel ethanol. During co-product recovery, condensed distillers solubles (CDS) has to be mixed with distillers wet grains before drying due to ...

  7. Nuclear fuel cycle system simulation tool based on high-fidelity component modeling

    Energy Technology Data Exchange (ETDEWEB)

    Ames, David E.,

    2014-02-01

    The DOE is currently directing extensive research into developing fuel cycle technologies that will enable the safe, secure, economic, and sustainable expansion of nuclear energy. The task is formidable considering the numerous fuel cycle options, the large dynamic systems that each represent, and the necessity to accurately predict their behavior. The path to successfully develop and implement an advanced fuel cycle is highly dependent on the modeling capabilities and simulation tools available for performing useful relevant analysis to assist stakeholders in decision making. Therefore a high-fidelity fuel cycle simulation tool that performs system analysis, including uncertainty quantification and optimization was developed. The resulting simulator also includes the capability to calculate environmental impact measures for individual components and the system. An integrated system method and analysis approach that provides consistent and comprehensive evaluations of advanced fuel cycles was developed. A general approach was utilized allowing for the system to be modified in order to provide analysis for other systems with similar attributes. By utilizing this approach, the framework for simulating many different fuel cycle options is provided. Two example fuel cycle configurations were developed to take advantage of used fuel recycling and transmutation capabilities in waste management scenarios leading to minimized waste inventories.

  8. Strontium Titanate-based Composite Anodes for Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Blennow Tullmar, Peter; Kammer Hansen, Kent; Wallenberg, L.R.;

    2008-01-01

    Surfactant-assisted infiltration of Gd-doped ceria (CGO) in Nb-doped SrTiO3 (STN) was investigated as a potential fuel electrode for solid oxide fuel cells (SOFC). An electronically conductive backbone structure of STN was first fabricated at high temperatures and then combined with the mixed con...

  9. Analysis of DC/DC Converter Efficiency for Energy Storage System Based on Bidirectional Fuel Cells

    DEFF Research Database (Denmark)

    Pittini, Riccardo; Zhang, Zhe; Andersen, Michael A. E.

    2013-01-01

    Renewable energy sources are fluctuating depending on the availability of the energy source. For this reason, energy storage is becoming more important and bidirectional fuel cells represent an attractive technology. Fuel cells require highcurrent low-voltage dc-dc or dc-ac converters as power...

  10. Water free proton conducting membranes based on poly-4-vinylpyridinebisulfate for fuel cells

    Science.gov (United States)

    Narayanan, Sekharipuram R. (Inventor); Yen, Shiao-Pin S. (Inventor)

    2007-01-01

    Disclosed are methods for forming a water-free electrolyte membrane useful in fuel cells. Also provided is a water-free electrolyte membrane comprising a quaternized amine salt including poly-4-vinylpyridinebisulfate, a poly-4-vinylpyridinebisulfate silica composite, and a combination thereof and a fuel cell comprising the membrane.

  11. Composite fuel based on residue from tyre and secondary polymer pyrolysis

    Science.gov (United States)

    Popov, V.; Papin, A.; Ignatova, A.; Makarovskikh, A.

    2016-09-01

    The article presents the analysis of obtaining high-quality molded solid fuel from waste that is a carbonaceous residue obtained by pyrolysis of automobile tyres and secondary polymers. Preliminary waste preparing, blending and briquetting have been carried out; fuel samples have been obtained; their strength characteristics have been studied; technical analysis has been carried out.

  12. Transport fuel

    DEFF Research Database (Denmark)

    Ronsse, Frederik; Jørgensen, Henning; Schüßler, Ingmar

    2014-01-01

    Worldwide, the use of transport fuel derived from biomass increased four-fold between 2003 and 2012. Mainly based on food resources, these conventional biofuels did not achieve the expected emission savings and contributed to higher prices for food commod - ities, especially maize and oilseeds...

  13. Dip-in Indicators for Visual Differentiation of Fuel Mixtures Based on Wettability of Fluoroalkylchlorosilane-Coated Inverse Opal Films.

    Science.gov (United States)

    Sedighi, Abootaleb; Qiu, Shuang; Wong, Michael C K; Li, Paul C H

    2015-12-30

    We have developed the dip-in indicator based on the inverse opal film (IOF) for visual differentiation of organic liquid mixtures, such as oil/gasoline or ethanol/gasoline fuel mixtures. The IOF consists of a three-dimensional porous structure with a highly ordered periodic arrangement of nanopores. The specularly reflected light at the interface of the nanopores and silica walls contributes to the structural color of the IOF film. This color disappears when the nanopores are infiltrated by a liquid with a similar refractive index to silica. The disappearance of the structural color provides a means to differentiate various liquid fuel mixtures based on their wettability of the nanopores in the IOF-based indicators. For differentiation of various liquid mixtures, we tune the wettability threshold of the indicator in such a way that it is wetted (color disappears) by one liquid but is not wetted by the other (color remains). Although colorimetric differentiation of liquids based on IOF wettability has been reported, differentiation of highly similar liquid mixtures require complicated readout approaches. It is known that the IOF wettability is controlled by multiple surface properties (e.g., oleophobicity) and structural properties (e.g., neck angle and film thickness) of the nanostructure. Therefore, we aim to exploit the combined tuning of these properties for differentiation of fuel mixtures with close compositions. In this study, we have demonstrated that, for the first time, the IOF-based dip-in indicator is able to detect a slight difference in the fuel mixture composition (i.e., 0.4% of oil content). Moreover, the color/no-color differentiation platform is simple, powerful, and easy-to-read. This platform makes the dip-in indicator a promising tool for authentication and determination of fuel composition at the point-of-purchase or point-of-use.

  14. Silicon Based Solid Oxide Fuel Cell Chip for Portable Consumer Electronics -- Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Alan Ludwiszewski

    2009-06-29

    LSI’s fuel cell uses efficient Solid Oxide Fuel Cell (“SOFC”) technology, is manufactured using Micro Electrical Mechanical System (“MEMS”) fabrication methods, and runs on high energy fuels, such as butane and ethanol. The company’s Fuel Cell on a Chip™ technology enables a form-factor battery replacement for portable electronic devices that has the potential to provide an order-of-magnitude run-time improvement over current batteries. Further, the technology is clean and environmentally-friendly. This Department of Energy funded project focused on accelerating the commercialization and market introduction of this technology through improvements in fuel cell chip power output, lifetime, and manufacturability.

  15. Power level effects on thorium-based fuels in pressure-tube heavy water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Bromley, B.P.; Edwards, G.W.R., E-mail: blair.bromley@cnl.ca [Canadian Nuclear Laboratories, Chalk River, Ontario (Canada); Sambavalingam, P. [Univ. of Ontario Inst. of Technology, Oshawa, Ontario (Canada)

    2016-06-15

    Lattice and core physics modeling and calculations have been performed to quantify the impact of power/flux levels on the reactivity and achievable burnup for 35-element fuel bundles made with Pu/Th or U-233/Th. The fissile content in these bundles has been adjusted to produce on the order of 20 MWd/kg burnup in homogeneous cores in a 700 MWe-class pressure-tube heavy water reactor, operating on a once-through thorium cycle. Results demonstrate that the impact of the power/flux level is modest for Pu/Th fuels but significant for U-233/Th fuels. In particular, high power/flux reduces the breeding and burnup potential of U-233/Th fuels. Thus, there may be an incentive to operate reactors with U-233/Th fuels at a lower power density or to develop alternative refueling schemes that will lower the time-average specific power, thereby increasing burnup.(author)

  16. A hybrid microbial fuel cell stack based on single and double chamber microbial fuel cells for self-sustaining pH control

    Science.gov (United States)

    Yang, Wei; Li, Jun; Ye, Dingding; Zhang, Liang; Zhu, Xun; Liao, Qiang

    2016-02-01

    Proton accumulation in the anode chamber is the major problem that affects the operational stability and electricity generation performance of double chamber microbial fuel cells (MFCs). In this study, a hybrid microbial fuel cell stack (DS-DS stack) based on single (SCMFCs) and double chamber MFCs (DCMFCs) is proposed for self-sustaining pH control in the MFC stack. It is found that the aerobic microbial oxidation of acetate by the biofilm that is attached to the air cathode of SCMFCs is responsible for the self-sustaining removal of accumulated H+ in the effluent of DCMFCs. Compared with the stack that solely consists of SCMFCs (SS-SS stack) or DCMFCs (DD-DD stack), the hybrid stack exhibits the highest electricity output performance and the most effective conversion of acetate into electricity at high power levels. Furthermore, the hybrid stack demonstrates the operation time of 15.7 ± 1.1 h when the operating voltage is above 0.8 V. This value is much higher than that of the DD-DD (8.5 ± 2.4 h) and SS-SS (8.1 ± 1.4 h) stacks, which suggests that the hybrid stack had a good operational stability.

  17. A proposal of benchmark calculation on reactor physics for metallic fueled and MOX fueled LMFBR based upon mack-up experiment at FCA

    Energy Technology Data Exchange (ETDEWEB)

    Oigawa, Hiroyuki; Iijima, Susumu; Sakurai, Takeshi; Okajima, Shigeaki; Andoh, Masaki; Nemoto, Tatsuo; Kato, Yuichi; Osugi, Toshitaka [Dept. of Nuclear Energy System, Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan)

    2000-02-01

    In order to assess the validity of the cross section library for fast reactor physics, a set of benchmark calculation is proposed. The benchmark calculation is based upon mock-up experiments at three FCA cores with various compositions of central test regions, two of which were mock-ups of metallic fueled LMFBR's, and the other was a mock-up of a mixed oxide fueled LMFBR. One of the metallic cores included enriched uranium in the test region, while the others did not. Physics parameters to be calculated are criticality, reaction rate ratios, plutonium and B{sub 4}C sample worth, sodium void reactivity worth, and Doppler reactivity worth of {sup 238}U. Homogenized atomic number densities and various correction factors are given so that anyone can easily perform diffusion calculation in two-dimensional RZ-model and compare the results with the experiments. The validity of the correction factors are proved by changing the calculation method and used nuclear data file. (author)

  18. A miniature microbial fuel cell with conducting nanofibers-based 3D porous biofilm

    Science.gov (United States)

    Jiang, Huawei; Halverson, Larry J.; Dong, Liang

    2015-12-01

    Miniature microbial fuel cell (MFC) technology has received growing interest due to its potential applications in high-throughput screening of bacteria and mutants to elucidate mechanisms of electricity generation. This paper reports a novel miniature MFC with an improved output power density and short startup time, utilizing electrospun conducting poly(3,4-ethylenedioxythiophene) (PEDOT) nanofibers as a 3D porous anode within a 12 μl anolyte chamber. This device results in 423 μW cm-3 power density based on the volume of the anolyte chamber, using Shewanella oneidensis MR-1 as a model biocatalyst without any optimization of bacterial culture. The device also excels in a startup time of only 1hr. The high conductivity of the electrospun nanofibers makes them suitable for efficient electron transfer. The mean pore size of the conducting nanofibers is several micrometers, which is favorable for bacterial penetration and colonization of surfaces of the nanofibers. We demonstrate that S. oneidensis can fully colonize the interior region of this nanofibers-based porous anode. This work represents a new attempt to explore the use of electrospun PEDOT nanofibers as a 3D anode material for MFCs. The presented miniature MFC potentially will provide a high-sensitivity, high-throughput tool to screen suitable bacterial species and mutant strains for use in large-size MFCs.

  19. Corrosion Performance of Fe-Based Alloys in Simulated Oxy-Fuel Environment

    Science.gov (United States)

    Zeng, Zuotao; Natesan, Ken; Cai, Zhonghou; Rink, David L.

    2017-02-01

    The long-term corrosion of Fe-based alloys in simulated oxy-fuel environment at 1023 K (750 °C) was studied. Detailed results are presented on weight change, scale thickness, internal penetration, microstructural characteristics of the corrosion products, and the cracking of scales for the alloys after exposure at 1023 K (750 °C) for up to 3600 hours. An incubation period during which the corrosion rate was low was observed for the alloys. After the incubation period, the corrosion accelerated, and the corrosion process followed linear kinetics. Effects of alloy, CaO-containing ash, and gas composition on the corrosion rate were also studied. In addition, synchrotron nanobeam X-ray analysis was employed to determine the phase and chemical composition of the oxide layers on the alloy surface. Results from these studies are being used to address the long-term corrosion performance of Fe-based alloys in various coal-ash combustion environments and to develop methods to mitigate high-temperature ash corrosion.

  20. Structural integrity evaluation of the components of the UO{sub 2} based SMART fuel

    Energy Technology Data Exchange (ETDEWEB)

    Song, Kee Nam; Kang, Heung Seok; Yoon, Kyong Ho; Kim, Hyung Kyu; Kim, Dae Hwan

    1999-03-01

    Using an 8 node brick element of ANSYS, finite element models for the top/bottom end piece have been established. And the structural integrity evaluation of the top/bottom end piece has been carried out through finite element stress analyses under the 4g design load. A spring characteristic test on the specimens of various kinds of hold down spring assemblies has been carried out. An elastic stiffness formula for the hold down spring assembly has been analytically derived, based on the Euler beam theory and the strain energy method. In addition, finite element models with a solid element using a contact element on the interface between the leaf springs and with a shell element of ANSYS have been developed to estimate the elastic stiffness. The structural integrity of the top/bottom end piece for the UO{sub 2} based SMART fuel were maintained under the 4g design load. The elastic stiffness formula and the finite element models were able to estimate the elastic stiffness of the leaf type hold down spring assembly. (Author). 12 refs., 4 tabs., 38 figs.

  1. Fuel reforming and electrical performance studies in intermediate temperature ceria - gadolinia-based SOFCs

    Energy Technology Data Exchange (ETDEWEB)

    Livermore, S.J.A. [CERAM Research, Stoke-on-Trent (United Kingdom); Birchall Centre for Inorganic Chemistry and Materials Science, Department of Chemistry, Keele Univ. (United Kingdom); Cotton, J.W. [CERAM Research, Stoke-on-Trent (United Kingdom); Ormerod, R.M. [Birchall Centre for Inorganic Chemistry and Materials Science, Department of Chemistry, Keele Univ. (United Kingdom)

    2000-03-01

    The methane reforming and carbon deposition characteristics of two nickel/ceria-gadolinia cermet anodes have been studied over the temperature range 550-700 C, for use in intermediate temperature ceria-gadolinia (CGO)-based solid oxide fuel cells (SOFCs), using conventional catalytic methods and temperature-programmed spectroscopy. The electrical performance and durability of planar CGO-based SOFCs with a 280-{mu}m-thick CGO electrolyte, screen printed cathode and different screen printed nickel/CGO cermet anodes have been studied over the temperature range 500-650 C. Temperature-programmed reduction has been used to study the reduction characteristics of the anodes, and indicates the presence of 'bulk' NiO particles and smaller NiO particles in intimate contact with the ceria. Both anodes show good activity towards methane steam reforming with methane activation occurring at temperatures as low as 210 C; steady-state steam reforming of methane was observed using a methane-rich mixture at 650 C, with 20% methane conversion. Post-reaction temperature-programmed oxidation has been used to determine the amount of carbon deposited during reforming and the strength of its interaction with the anode. (orig.)

  2. A new composite cathode for intermediate temperature solid oxide fuel cells with zirconia-based electrolytes

    Science.gov (United States)

    Zhang, Cuijuan; Huang, Kevin

    2017-02-01

    Improving the electrocatalytic activity of electrode materials is vitally important to achieve practically meaningful performance for intermediate temperature solid oxide fuel cells (IT-SOFCs). The present work develops a composite cathode consisting of an electronic conductor Sr-doped LaMnO3 (LSM) and an ionic conductor Y- and Ce- co-doped Bi2O3 (BYC7). BYC7 is an excellent oxide-ion conductor, exhibiting a high and stable ionic conductivity of 0.008 S cm-1 at 500 °C. The polarization resistance of LSM-BYC7 cathode in a symmetrical cell with doped ZrO2 as electrolyte varies from 5.76 at 500 °C to 0.25 Ω cm2 at 650 °C. The surface diffusion and charge transfer at the triple phase boundaries are the rate determining steps based on the dependence of polarization resistance on partial pressure of oxygen. The maximum power density of a ZrO2-based anode-supported cell with LSM-BYC7 composite cathode is 56.4, 154.6, 327.9, and 451.0 mW cm-2 at 500, 550, 600, and 650 °C respectively. AC impedance analysis reveals that the performance of IT-SOFC prepared in this study is actually limited by the anode, not by LSM-BYC7 cathode.

  3. High throughput evaluation of perovskite-based anode catalysts for direct methanol fuel cells

    Science.gov (United States)

    Deshpande, Kishori; Mukasyan, Alexander; Varma, Arvind

    Liquid feed direct methanol fuel cells (DMFC) are promising candidates for portable power applications. However, owing to the problems associated with expensive Pt-based catalysts, viz., CO poisoning, a promising approach is to use complex oxides of the type ABO 3 (A = Sr, Ce, La, etc. and B = Co, Fe, Ni, Pt, Ru, etc.). In the current work, a variety of ABO 3 and A 2BO 4 type non-noble and partially substituted noble metal high surface area compounds were synthesized by an effective and rapid aqueous combustion synthesis (CS). Their catalytic activity was evaluated by using "High Throughput Screening Unit"-NuVant System, which compares up to 25 compositions simultaneously under DMFC conditions. It was found that the Sr-based perovskites showed performance comparable with the standard Pt-Ru catalyst. Further, it was observed that the method of doping SrRuO 3 with Pt influenced the activity. Specifically, platinum added during aqueous CS yielded better catalyst than when added externally at the ink preparation stage. Finally, it was also demonstrated that the presence of SrRuO 3 significantly enhanced the catalytic properties of Pt, leading to superior performance even at lower noble metal loadings.

  4. Corrosion Performance of Fe-Based Alloys in Simulated Oxy-Fuel Environment

    Science.gov (United States)

    Zeng, Zuotao; Natesan, Ken; Cai, Zhonghou; Rink, David L.

    2016-09-01

    The long-term corrosion of Fe-based alloys in simulated oxy-fuel environment at 1023 K (750 °C) was studied. Detailed results are presented on weight change, scale thickness, internal penetration, microstructural characteristics of the corrosion products, and the cracking of scales for the alloys after exposure at 1023 K (750 °C) for up to 3600 hours. An incubation period during which the corrosion rate was low was observed for the alloys. After the incubation period, the corrosion accelerated, and the corrosion process followed linear kinetics. Effects of alloy, CaO-containing ash, and gas composition on the corrosion rate were also studied. In addition, synchrotron nanobeam X-ray analysis was employed to determine the phase and chemical composition of the oxide layers on the alloy surface. Results from these studies are being used to address the long-term corrosion performance of Fe-based alloys in various coal-ash combustion environments and to develop methods to mitigate high-temperature ash corrosion.

  5. Ceria based inverse opals for thermochemical fuel production: Quantification and prediction of high temperature behavior

    Science.gov (United States)

    Casillas, Danielle Courtney

    Solar energy has the potential to supply more than enough energy to meet humanity's energy demands. Here, a method for thermochemical solar energy storage through fuel production is presented. A porous non-stoichiometric oxide, ceria, undergoes partial thermal reduction and oxidation with concentrated solar energy as a heat source, and water as an oxidant. The resulting yields for hydrogen fuel and oxygen are produced in two discrete steps, while the starting material maintains its original phase. Ordered porosity has been shown superior to random porosity for thermochemical fuel production applications, but stability limits for these structures are currently undefined. Ceria-based inverse opals are currently being investigated to assess the architectural influence on thermochemical hydrogen production. Low tortuosity and continuous interconnected pore network allow for facile gas transport and improved reaction kinetics. Ceria-based ordered materials have recently been shown to increase maximum hydrogen production over non-ordered porous ceria. Thermal stability of ordered porosity was quantified using quantitative image analysis. Fourier analysis was applied to SEM images of the material. The algorithm results in an order parameter gamma that describes the degree of long range order maintained by these structures, where gamma>4 signifies ordered porosity. According to this metric, a minimum zirconium content of 20 atomic percent (at%) is necessary for these architectures to survive aggressive annealing up to 1000°C. Zirconium substituted ceria (ZSC) with Zr loadings in excess of 20at% developed undesired tetragonal phases. Through gamma, we were able to find a balance between the benefit of zirconium additions on structural stability and its negative impact on phase. This work demonstrates the stability of seemingly delicate architectures, and the operational limit for ceria based inverse opals to be 1000°C for 1microm pore size. Inverse opals having sub

  6. New composite membranes based on modified Nafion or Flemion for PEM fuel cell application

    Science.gov (United States)

    Tian, Huimin

    Nafion and Flemion during the procedure of casting composite membrane and there was the interaction between the sulphonic acid group and STA. X-ray photoelectron spectroscopy shows the existence of W-S and W-C bonds in composite membrane. This can be used to explain the previous experimental observation that the composite membrane with STA has higher conductivity and water uptake than the composite membrane without STA. The above studies allowed us to conclude that the improvements in ionic conductivity and water uptake are due to the change of the chemical composition of the composite membranes by the addition of silicotungstic acid. The current-potential polarization characterization of composite Nafion/STA and Flemion/STA membranes was measured using H2/O2 single polymer electrolyte membrane (PEM) fuel cell system. The performance based on composite Nafion/STA and Flemion/STA membranes is always better than that based on cast Nafion or cast Flemion without STA membranes. The improvement in the fuel cell characteristics for the composite Nafion/STA and Flemion/STAmembrane is due to a combined effect of the polymer and STA. The existence of STA improves the fuel cell performance and make this operation feasible under high temperature.

  7. An Economic Basis for Littoral Land-Based Production of Low Carbon Fuel from Renewable Electrical Energy and Seawater for Naval Use: Diego Garcia Evaluation

    Science.gov (United States)

    2015-08-13

    Based Production of Low Carbon Fuel from Renewable Electrical Energy and Seawater for Naval Use: Diego Garcia Evaluation Heather D. Willauer, Dennis R...difficult challenges to the U.S. Navy for the future production of low carbon fuel from renewable electrical energy from photovoltaic (PV) arrays and...gallons of fuel delivered annually to Diego Garcia. Using published capital cost estimates and a range of solar and wind renewable electrical energy

  8. Evaluation of a Passive Heat Exchanger Based Cooling System for Fuel Cell Applications

    Science.gov (United States)

    Colozza, Anthony J.; Burke, Kenneth A.

    2011-01-01

    Fuel cell cooling is conventionally performed with an actively controlled, dedicated coolant loop that exchanges heat with a separate external cooling loop. To simplify this system the concept of directly cooling a fuel cell utilizing a coolant loop with a regenerative heat exchanger to preheat the coolant entering the fuel cell with the coolant exiting the fuel cell was analyzed. The preheating is necessary to minimize the temperature difference across the fuel cell stack. This type of coolant system would minimize the controls needed on the coolant loop and provide a mostly passive means of cooling the fuel cell. The results indicate that an operating temperature of near or greater than 70 C is achievable with a heat exchanger effectiveness of around 90 percent. Of the heat exchanger types evaluated with the same type of fluid on the hot and cold side, a counter flow type heat exchanger would be required which has the possibility of achieving the required effectiveness. The number of heat transfer units required by the heat exchanger would be around 9 or greater. Although the analysis indicates the concept is feasible, the heat exchanger design would need to be developed and optimized for a specific fuel cell operation in order to achieve the high effectiveness value required.

  9. Fuel Injection Pressure Effect on Performance of Direct Injection Diesel Engines Based on Experiment

    Directory of Open Access Journals (Sweden)

    Rosli A. Bakar

    2008-01-01

    Full Text Available Fuel injection pressures in diesel engine plays an important role for engine performance obtaining treatment of combustion. The present diesel engines such as fuel direct injection, the pressures can be increased about 100 – 200 Mpa bar in fuel pump injection system. The experimental investigated effects of fuel injection pressure on engine performance. Experiments have been performed on a diesel engine with four-cylinder, two-stroke, direct injection. Engine performance values such as indicated pressure, indicated horse power, shaft horse power, brake horse power, break mean effective pressure and fuel consumption have been investigated both of variation engine speeds - fixed load and fixed engine speed – variation loads by changing the fuel injection pressure from 180 to 220 bar. According to the results, the best performance of the pressure injection has been obtained at 220 bar, specific fuel consumption has been obtained at 200 bar for fixed load – variation speeds and at 180 bar for variation loads – fixed speed. The results of the experiment have given as graphics in this paper.

  10. Technology and productivity in fuel distribution bases; Tecnologia e produtividade em bases de distribuicao de combustiveis

    Energy Technology Data Exchange (ETDEWEB)

    Silberman, Luis; Barros, Miguel Monteiro de; Correa Junior, Sebastiao Muniz; Gryner, Flavio [Companhia Brasileira de Petroleo Ipiranga, Rio de Janeiro, RJ (Brazil)

    1998-12-31

    The Companhia Brasileira de Petroleo Ipiranga (CBPI), in continuity to operational plan of increase of productivity with reduction of costs, implanted the system of industrial automation AUTOBASI-NT in 7 bases. This work will go to present the equipment and systems implanted in the terminals of Duque de Caxias and Sao Caetano aiming at to describe the gotten benefits. System AUTOBASI-NT is composite basically for a supervisory software for the management of the process and some intelligent instruments of field. Also some variable measured will be presented before and after the automation of the terminal. (author) 5 figs., 1 tab.

  11. Performance Enhancement Of Mems-Based Microbial Fuel Cells (μMFC) For Microscale Power Generation

    Science.gov (United States)

    Şen Doğan, Begüm; Afşar Erkal, Nilüfer; Özgür, Ebru; Zorlu, Özge; Külah, Haluk

    2016-11-01

    This paper reports the design, fabrication, and testing of a microliter scale Microbial Fuel Cell (μMFC) based on silicon MEMS fabrication technology. μMFC systems are operated under different loads or open circuit to compare the effect of different acclimatization conditions on start-up time. Shewanella oneidensis MR-1 is preferred to be the biocatalyst. The internal resistance is calculated as 20 kΩ under these conditions. Acclimatization of μMFC under a finite load resulted in shorter start-up time (30 hours) when compared to the open load case. Power and current densities normalized to anode area are 2 μW/cm2 and 12 μA/cm2 respectively. When the load resistance value is closer to the internal resistance of the μMFC, higher power and current densities are achieved as expected, and it resulted in a shorter start-up time. Further studies focusing on the different acclimatization techniques for μMFC could pave the way to use μMFCs as fast and efficient portable power sources.

  12. Development of gas diffusion layer using water based carbon slurry for proton exchange membrane fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Lin, J.F.; Liu, X.; Adame, A.; Villacorta, R. [Fuel Cell Research Laboratory, Engineering Technology Department, Arizona State University, Mesa, AZ 85212 (United States); Wertz, J. [Hollingsworth and Vose Co., A.K. Nicholson Research Lab, 219 Townsend Road, West Groton, MA 01472 (United States); Ahmad, R.; Thommes, M. [Quantachrome Instruments, 1900 Corporate Drive, Boynton Beach, FL 33426 (United States); Kannan, A.M., E-mail: amk@asu.ed [Fuel Cell Research Laboratory, Engineering Technology Department, Arizona State University, Mesa, AZ 85212 (United States)

    2011-01-01

    The micro-porous layer of gas diffusion layers (GDLs) was fabricated with the carbon slurry dispersed in water containing sodium dodecyl sulfate (SDS), by wire rod coating process. The aqueous carbon slurry with micelle-encapsulation was highly consistent and stable without losing any homogeneity even after adding polytetrafluoroethylene (PTFE) binder for hundreds of hours. The surface morphology, contact angle and pore size distribution of the GDLs were examined using SEM, Goniometer and Hg Porosimeter, respectively. GDLs fabricated with various SDS concentrations were assembled into MEAs and evaluated in a single cell PEMFC under diverse operating relative humidity (RH) conditions using H{sub 2}/O{sub 2} and H{sub 2}/air as reactants. The peak power density of the single cell using the GDLs with optimum SDS concentration was 1400 and 500 mW cm{sup -2} with H{sub 2}/O{sub 2} and H{sub 2}/air at 90% RH, respectively. GDLs were also fabricated with isopropyl alcohol (IPA) based carbon slurry for fuel cell performance comparison. It was found that the composition of the carbon slurry, specifically SDS concentration played a critical role in controlling the pore diameter as well as the corresponding pore volumes of the GDLs.

  13. [Mechanisms of bioelectricity generation in Enterobacter aerogenes-based microbial fuel cells].

    Science.gov (United States)

    Zhang, Jin-Tao; Zhou, Shun-Gui; Zhang, Li-Xia; Lu, Na; Deng, Li-Fang; Ni, Jin-Ren

    2009-04-15

    Microbial fuel cells (MFCs) using hydrogen-producing bacteria (HPB) could utilize a large number of substrates to generate power. However, the coulombic efficiency is limited by the fact that only suspended cells are used as biocatalyst in anodic medium. MFCs using Fe (III)-reducing bacteria have high energy recovery efficiency, but can only utilize some simple organic matters. In this study, Enterobacter aerogenes XM02, a hydrogen-producing strain with Fe(III)-reducing activity, was selected as biocatalyst for MFCs, which could produce electricity by digesting lots of carbohydrates even starch. Graphite felt, a material with high specific surface area and hydrogen catalysis, instead of carbon paper supported platinum, was used as anode material. The coulombic efficiency had been substantially improved from 1.68% to 42.49%, higher than other HPB-based MFCs previously reported. The SEM image proved the ability of XM02 strain to colonize on the anode surface. Power generation of MFCs could restore quickly when anodic medium was completely replaced with non-growth medium containing glucose. This suggested that the attached cells contributed to electricity production because planktonic cells had been removed during the medium replacement. This study proposed the mechanism of power generated from in situ oxidation of hydrogen produced by the XM02 strain biofilm.

  14. Promising aquivion composite membranes based on fluoroalkyl zirconium phosphate for fuel cell applications.

    Science.gov (United States)

    Donnadio, Anna; Pica, Monica; Subianto, Surya; Jones, Deborah J; Cojocaru, Paula; Casciola, Mario

    2014-08-01

    Layered zirconium phosphate (ZP) that bears fluorinated alkyl chains bonded covalently to the layers (ZPR) was used as a nanofiller in membranes based on a short-side-chain perfluorosulfonic acid (PFSA) to mechanically reinforce the PFSA hydrophobic component. Compared to the pristine PFSA, membranes with a ZPR loading up to 30 wt% show enhanced mechanical properties, and the largest improvement of elastic modulus (E) and yield stress (σY ) are observed for the 10 wt% ZPR membrane: ΔE/E up to 90% and ΔσY /σY up 70% at 70°C and 80% relative humidity (RH). In the RH range 50-95%, the in-plane conductivity of the composite membranes reaches 0.43 S cm(-1) for 10 wt% ZPR at 110°C and is on average 30% higher than the conductivity of the pristine PFSA. The 10 wt % ZPR membrane is as hydrated as the neat PFSA membrane at 50% RH but becomes progressively less hydrated with increasing RH both at 80 and 110°C. The fuel cell performance of this membrane, at 80°C and 30% RH, is better than that of the unmodified PFSA.

  15. Electro-osmotic-based catholyte production by Microbial Fuel Cells for carbon capture.

    Science.gov (United States)

    Gajda, Iwona; Greenman, John; Melhuish, Chris; Santoro, Carlo; Li, Baikun; Cristiani, Pierangela; Ieropoulos, Ioannis

    2015-12-01

    In Microbial Fuel Cells (MFCs), the recovery of water can be achieved with the help of both active (electro-osmosis), and passive (osmosis) transport pathways of electrolyte through the semi-permeable selective separator. The electrical current-dependent transport, results in cations and electro-osmotically dragged water molecules reaching the cathode. The present study reports on the production of catholyte on the surface of the cathode, which was achieved as a direct result of electricity generation using MFCs fed with wastewater, and employing Pt-free carbon based cathode electrodes. The highest pH levels (>13) of produced liquid were achieved by the MFCs with the activated carbon cathodes producing the highest power (309 μW). Caustic catholyte formation is presented in the context of beneficial cathode flooding and transport mechanisms, in an attempt to understand the effects of active and passive diffusion. Active transport was dominant under closed circuit conditions and showed a linear correlation with power performance, whereas osmotic (passive) transport was governing the passive flux of liquid in open circuit conditions. Caustic catholyte was mineralised to a mixture of carbonate and bicarbonate salts (trona) thus demonstrating an active carbon capture mechanism as a result of the MFC energy-generating performance. Carbon capture would be valuable for establishing a carbon negative economy and environmental sustainability of the wastewater treatment process.

  16. A novel Ni/ceria-based anode for metal-supported solid oxide fuel cells

    Science.gov (United States)

    Rojek-Wöckner, Veronika A.; Opitz, Alexander K.; Brandner, Marco; Mathé, Jörg; Bram, Martin

    2016-10-01

    For optimization of ageing behavior, electrochemical performance, and sulfur tolerance of metal-supported solid oxide fuel cells a new anode concept is introduced, which is based on a Ni/GDC cermet replacing the established Ni/YSZ anodes. In the present work optimized processing parameters compatible with MSC substrates are specified by doing sintering studies on pressed bulk specimen and on real porous anode structures. The electrochemical performance of the Ni/GDC anodes was characterized by means of symmetrical electrolyte supported model-type cells. In this study, three main objectives are pursued. Firstly, the effective technical realization of the Ni/GDC concept is demonstrated. Secondly, the electrochemical behavior of Ni/GDC porous anodes is characterized by impedance spectroscopy and compared with the current standard Ni/YSZ anode. Further, a qualitative comparison of the sulfur poisoning behavior of both anode types is presented. Thirdly, preliminary results of a successful implementation of the Ni/GDC cermet into a metal-supported single cell are presented.

  17. Application of a Decomposition Strategy to the Optimal Synthesis/Design and Operation of a Fuel Cell Based Total Energy System

    OpenAIRE

    2002-01-01

    A decomposition methodology based on the concept of â thermoeconomic isolationâ applied to the synthesis/design and operational optimization of a stationary cogeneration proton exchange membrane fuel cell (PEMFC) based total energy system (TES) for residential/commercial applications is the focus of this work. A number of different configurations for the fuel cell based TES were considered. The most promising set based on an energy integration analysis of candidate configurations was devel...

  18. Resolving the H 2 effect on radiation induced dissolution of UO 2-based spent nuclear fuel

    Science.gov (United States)

    Trummer, Martin; Jonsson, Mats

    2010-01-01

    In recent years, the impact of H2 on α-radiation induced dissolution of UO2-based spent nuclear fuel has been studied and debated extensively. Experimental results on the effect of H2 on the concentration of H2O2 during α-radiolysis have been shown to disagree with numerical simulations. For this reason, the reaction scheme used in simulations of aqueous radiation chemistry has sometimes been questioned. In this work, we have studied the impact of H2 on the H2O2 concentration in α-irradiated aqueous solution using numerical simulations. The effects of H2 pressure, α-dose rate and HCO3- concentration were investigated by performing systematic variations in these parameters. The simulations show that the discrepancy between the previously published experimental result and numerical simulations is due to the use of a homogeneous dose rate (the energy is assumed to be equally distributed in the whole volume). Taking the actual dose rate of the α-irradiated volume into account, the simulation is in perfect agreement with the experimental results. This shows that the H2 effect is strongly α-dose rate dependent, and proves the reliability of the reaction scheme used in the simulations. The simulations also show that H2 influences the H2O2 concentration under α-radiolysis. The magnitude of the effect depends on the dose rate and the H2 pressure as well as on the concentration of HCO 3-. The impact of the radiolytic H2 effect on the rate of α-radiation induced dissolution of spent nuclear fuel is discussed along with other (α- and γ-) radiation induced processes capable of reducing the concentration of uranium in solution. The radiolytic H2 effect is quantitatively compared to the previously presented noble metal catalyzed H2 effect. This comparison shows that the noble metal catalyzed H2 effect is far more efficient than the radiolytic H2 effect. Reduction of U(VI) in solution due to low dose rate γ-radiolysis in the presence of H2 is proposed to be the cause of

  19. Ceria-Based Anodes for Next Generation Solid Oxide Fuel Cells

    Science.gov (United States)

    Mirfakhraei, Behzad

    Mixed ionic and electronic conducting materials (MIECs) have been suggested to represent the next generation of solid oxide fuel cell (SOFC) anodes, primarily due to their significantly enhanced active surface area and their tolerance to fuel components. In this thesis, the main focus has been on determining and tuning the physicochemical and electrochemical properties of ceria-based MIECs in the versatile perovskite or fluorite crystal structures. In one direction, BaZr0.1Ce0.7Y0.1 M0.1O3-delta (M = Fe, Ni, Co and Yb) (BZCY-M) perovskites were synthesized using solid-state or wet citric acid combustion methods and the effect of various transition metal dopants on the sintering behavior, crystal structure, chemical stability under CO2 and H 2S, and electrical conductivity, was investigated. BZCY-Ni, synthesized using the wet combustion method, was the best performing anode, giving a polarization resistance (RP) of 0.4 O.cm2 at 800 °C. Scanning electron microscopy and X-ray diffraction analysis showed that this was due to the exsolution of catalytic Ni nanoparticles onto the oxide surface. Evolving from this promising result, the effect of Mo-doped CeO 2 (nCMO) or Ni nanoparticle infiltration into a porous Gd-doped CeO 2 (GDC) anode (in the fluorite structure) was studied. While 3 wt. % Ni infiltration lowered RP by up to 90 %, giving 0.09 O.cm2 at 800 °C and exhibiting a ca. 5 times higher tolerance towards 10 ppm H2, nCMO infiltration enhanced the H2 stability by ca. 3 times, but had no influence on RP. In parallel work, a first-time study of the Ce3+ and Ce 4+ redox process (pseudocapacitance) within GDC anode materials was carried out using cyclic voltammetry (CV) in wet H2 at high temperatures. It was concluded that, at 500-600 °C, the Ce3+/Ce 4+ reaction is diffusion controlled, probably due to O2- transport limitations in the outer 5-10 layers of the GDC particles, giving a very high capacitance of ca. 70 F/g. Increasing the temperature ultimately

  20. Successful elimination of non-neural cells and unachievable elimination of glial cells by means of commonly used cell culture manipulations during differentiation of GFAP and SOX2 positive neural progenitors (NHA to neuronal cells

    Directory of Open Access Journals (Sweden)

    Krynska Barbara

    2008-07-01

    Full Text Available Abstract Background Although extensive research has been performed to control differentiation of neural stem cells – still, the response of those cells to diverse cell culture conditions often appears to be random and difficult to predict. To this end, we strived to obtain stabilized protocol of NHA cells differentiation – allowing for an increase in percentage yield of neuronal cells. Results Uncommitted GFAP and SOX2 positive neural progenitors – so-called, Normal Human Astrocytes (NHA were differentiated in different environmental conditions to: only neural cells consisted of neuronal [MAP2+, GFAP-] and glial [GFAP+, MAP2-] population, non-neural cells [CD44+, VIMENTIN+, FIBRONECTIN+, MAP2-, GFAP-, S100β-, SOX2-], or mixture of neural and non-neural cells. In spite of successfully increasing the percentage yield of glial and neuronal vs. non-neural cells by means of environmental changes, we were not able to increase significantly the percentage of neuronal (GABA-ergic and catecholaminergic over glial cells under several different cell culture testing conditions. Supplementing serum-free medium with several growth factors (SHH, bFGF, GDNF did not radically change the ratio between neuronal and glial cells – i.e., 1,1:1 in medium without growth factors and 1,4:1 in medium with GDNF, respectively. Conclusion We suggest that biotechnologists attempting to enrich in vitro neural cell cultures in one type of cells – such as that required for transplantology purposes, should consider the strong limiting influence of intrinsic factors upon extracellular factors commonly tested in cell culture conditions.

  1. Study of A Multi-criteria Evaluation Methodology for Nuclear Fuel Cycle System Based on Sustainability

    Institute of Scientific and Technical Information of China (English)

    Liu Jingquan; Hidekazu Yoshikawa; OuYang Jun; Zhou Yangping

    2006-01-01

    This paper presents a multi-criteria evaluation methodology for nuclear fuel cycle options in terms of energy sustainability. Starting from the general sustainability concept and the public acceptance questionnaire, a set of indicators reflecting specific criteria for the evaluation of nuclear fuel cycle options are defined.Particular attention is devoted to the resource utility efficiency, environmental effect, human health hazard and economic effect, which represent the different concerns of different stakeholders. This methodology also integrated a special mathematic processing approach, namely the Extentics Evaluation Method, which quantifies the human being subjective perception to provide the intuitionistic judgement and comparison for different options. The once-through option and reprocessing option of nuclear fuel cycle are examined by using the proposed methodology. The assessment process and result can give us some guidance in nuclear fuel cycle evaluation under the constraint of limited data.

  2. Closing the carbon cycle through rational use of carbon-based fuels.

    Science.gov (United States)

    MacElroy, J M Don

    2016-01-01

    In this paper, a brief overview is presented of natural gas as a fuel resource with subsequent carbon capture and re-use as a means to facilitate reduction and eventual elimination of man-made carbon emissions. A particular focus is shale gas and, to a lesser extent, methane hydrates, with the former believed to provide the most reasonable alternative as a transitional fuel toward a low-carbon future. An emphasis is placed on the gradual elimination of fossil resource usage as a fuel over the coming 35 to 85 years and its eventual replacement with renewable resources and nuclear power. Furthermore, it is proposed that synthesis of chemical feedstocks from recycled carbon dioxide and hydrogen-rich materials should be undertaken for specific applications in the transport sector which require access to high energy density fuels. To achieve the latter, carbon dioxide capture is imperative and possible synthetic routes for chemical feedstock production are briefly reviewed.

  3. Identification and analysis based on genetic algorithm for proton exchange membrane fuel cell stack

    Institute of Scientific and Technical Information of China (English)

    LI Xi; CAO Guang-yi; ZHU Xin-jian; WEI Dong

    2006-01-01

    The temperature of proton exchange membrane fuel cell stack and the stoichiometric oxygen in cathode have relationship with the performance and life span of fuel cells closely. The thermal coefficients were taken as important factors affecting the temperature distribution of fuel cells and components. According to the experimental analysis, when the stoichiometric oxygen in cathode is greater than or equal to 1.8, the stack voltage loss is the least. A novel genetic algorithm was developed to identify and optimize the variables in dynamic thermal model of proton exchange membrane fuel cell stack, making the outputs of temperature model approximate to the actual temperature, and ensuring that the maximal error is less than 1℃. At the same time, the optimum region of stoichiometric oxygen is obtained, which is in the range of 1.8 -2.2 and accords with the experimental analysis results. The simulation and experimental results show the effectiveness of the proposed algorithm.

  4. Comparative study on ammonia oxidation over Ni-based cermet anodes for solid oxide fuel cells

    Science.gov (United States)

    Molouk, Ahmed Fathi Salem; Yang, Jun; Okanishi, Takeou; Muroyama, Hiroki; Matsui, Toshiaki; Eguchi, Koichi

    2016-02-01

    In the current work, we investigate the performance of solid oxide fuel cells (SOFCs) with Ni‒yttria-stabilized zirconia (Ni-YSZ) and Ni‒gadolinia-dope ceria (Ni-GDC) cermet anodes fueled with H2 or NH3 in terms of the catalytic activity of ammonia decomposition. The cermet of Ni-GDC shows higher catalytic activity for ammonia decomposition than Ni-YSZ. In response to this, the performance of direct NH3-fueled SOFC improved by using Ni-GDC anode. Moreover, we observe further enhancement in the cell performance and the catalytic activity for ammonia decomposition with applying Ni-GDC anode synthesised by the glycine-nitrate combustion process. These results reveal that the high performance of Ni-GDC anode for the direct NH3-fueled SOFC results from its mixed ionic-electronic conductivity as well as high catalytic activity for ammonia decomposition.

  5. High temperature proton exchange membranes based on polybenzimidazoles for fuel cells

    DEFF Research Database (Denmark)

    Li, Qingfeng; Jensen, Jens Oluf; Savinell, Robert F;

    2009-01-01

    in recent years motivated extensive research activities with great progress. This treatise is devoted to updating the development, covering polymer synthesis, membrane casting, physicochemical characterizations and fuel cell technologies. To optimize the membrane properties, high molecular weight polymers...... havebeenmadeincluding spectroscopy,wateruptake and acid doping, thermal and oxidative stability, conductivity, electro-osmoticwater drag, methanol crossover, solubility and permeability of gases, and oxygen reduction kinetics. Related fuel cell technologies such as electrode and MEA fabrication have been developed...

  6. Improving Catalyst Efficiency in Bio-Based Hydrocarbon Fuels; NREL (National Renewable Energy Laboratory)

    Energy Technology Data Exchange (ETDEWEB)

    None

    2015-06-01

    This article investigates upgrading biomass pyrolysis vapors to form hydrocarbon fuels and chemicals using catalysts with different concentrations of acid sites. It shows that greater separation of acid sites makes catalysts more efficient at producing hydrocarbon fuels and chemicals. The conversion of biomass into liquid transportation fuels has attracted significant attention because of depleting fossil fuel reserves and environmental concerns resulting from the use of fossil fuels. Biomass is a renewable resource, which is abundant worldwide and can potentially be exploited to produce transportation fuels that are less damaging to the environment. This renewable resource consists of cellulose (40–50%), hemicellulose (25–35%), and lignin (16–33%) biopolymers in addition to smaller quantities of inorganic materials such as silica and alkali and alkaline earth metals (calcium and potassium). Fast pyrolysis is an attractive thermochemical technology for converting biomass into precursors for hydrocarbon fuels because it produces up to 75 wt% bio-oil,1 which can be upgraded to feedstocks and/or blendstocks for further refining to finished fuels. Bio-oil that has not been upgraded has limited applications because of the presence of oxygen-containing functional groups, derived from cellulose, hemicellulose and lignin, which gives rise to high acidity, high viscosity, low heating value, immiscibility with hydrocarbons and aging during storage. Ex situ catalytic vapor phase upgrading is a promising approach for improving the properties of bio-oil. The goal of this process is to reject oxygen and produce a bio-oil with improved properties for subsequent downstream conversion to hydrocarbons.

  7. Development & optimization of a rule-based energy management strategy for fuel economy improvement in hybrid electric vehicles

    Science.gov (United States)

    Asfoor, Mostafa

    The gradual decline of oil reserves and the increasing demand for energy over the past decades has resulted in automotive manufacturers seeking alternative solutions to reduce the dependency on fossil-based fuels for transportation. A viable technology that enables significant improvements in the overall energy conversion efficiencies is the hybridization of conventional vehicle drive systems. This dissertation builds on prior hybrid powertrain development at the University of Idaho. Advanced vehicle models of a passenger car with a conventional powertrain and three different hybrid powertrain layouts were created using GT-Suite. These different powertrain models were validated against a variety of standard driving cycles. The overall fuel economy, energy consumption, and losses were monitored, and a comprehensive energy analysis was performed to compare energy sources and sinks. The GT-Suite model was then used to predict the formula hybrid SAE vehicle performance. Inputs to this model were a numerically predicted engine performance map, an electric motor torque curve, vehicle geometry, and road load parameters derived from a roll-down test. In this case study, the vehicle had a supervisory controller that followed a rule-based energy management strategy to insure a proper power split during hybrid mode operation. The supervisory controller parameters were optimized using discrete grid optimization method that minimized the total amount of fuel consumed during a specific urban driving cycle with an average speed of approximately 30 [mph]. More than a 15% increase in fuel economy was achieved by adding supervisory control and managing power split. The vehicle configuration without the supervisory controller displayed a fuel economy of 25 [mpg]. With the supervisory controller this rose to 29 [mpg]. Wider applications of this research include hybrid vehicle controller designs that can extend the range and survivability of military combat platforms. Furthermore, the

  8. Structural Path Analysis of Fossil Fuel Based CO2 Emissions: A Case Study for China.

    Directory of Open Access Journals (Sweden)

    Zhiyong Yang

    Full Text Available Environmentally extended input-output analysis (EEIOA has long been used to quantify global and regional environmental impacts and to clarify emission transfers. Structural path analysis (SPA, a technique based on EEIOA, is especially useful for measuring significant flows in this environmental-economic system. This paper constructs an imports-adjusted single-region input-output (SRIO model considering only domestic final use elements, and it uses the SPA technique to highlight crucial routes along the production chain in both final use and sectoral perspectives. The results indicate that future mitigation policies on household consumption should change direct energy use structures in rural areas, cut unreasonable demand for power and chemical products, and focus on urban areas due to their consistently higher magnitudes than rural areas in the structural routes. Impacts originating from government spending should be tackled by managing onsite energy use in 3 major service sectors and promoting cleaner fuels and energy-saving techniques in the transport sector. Policies on investment should concentrate on sectoral interrelationships along the production chain by setting up standards to regulate upstream industries, especially for the services, construction and equipment manufacturing sectors, which have high demand pulling effects. Apart from the similar methods above, mitigating policies in exports should also consider improving embodied technology and quality in manufactured products to achieve sustainable development. Additionally, detailed sectoral results in the coal extraction industry highlight the onsite energy use management in large domestic companies, emphasize energy structure rearrangement, and indicate resources and energy safety issues. Conclusions based on the construction and public administration sectors reveal that future mitigation in secondary and tertiary industries should be combined with upstream emission intensive

  9. Carbon-Based Air-Breathing Cathodes for Microbial Fuel Cells

    Directory of Open Access Journals (Sweden)

    Irene Merino-Jimenez

    2016-08-01

    Full Text Available A comparison between different carbon-based gas-diffusion air-breathing cathodes for microbial fuel cells (MFCs is presented in this work. A micro-porous layer (MPL based on carbon black (CB and an activated carbon (AC layer were used as catalysts and applied on different supporting materials, including carbon cloth (CC, carbon felt (CF, and stainless steel (SS forming cathode electrodes for MFCs treating urine. Rotating ring disk electrode (RRDE analyses were done on CB and AC to: (i understand the kinetics of the carbonaceous catalysts; (ii evaluate the hydrogen peroxide production; and (iii estimate the electron transfer. CB and AC were then used to fabricate electrodes. Half-cell electrochemical analysis, as well as MFCs continuous power performance, have been monitored. Generally, the current generated was higher from the MFCs with AC electrodes compared to the MPL electrodes, showing an increase between 34% and 61% in power with the AC layer comparing to the MPL. When the MPL was used, the supporting material showed a slight effect in the power performance, being that the CF is more powerful than the CC and the SS. These differences also agree with the electrochemical analysis performed. However, the different supporting materials showed a bigger effect in the power density when the AC layer was used, being the SS the most efficient, with a power generation of 65.6 mW·m−2, followed by the CC (54 mW·m−2 and the CF (44 mW·m−2.

  10. Structural Path Analysis of Fossil Fuel Based CO2 Emissions: A Case Study for China.

    Science.gov (United States)

    Yang, Zhiyong; Dong, Wenjie; Xiu, Jinfeng; Dai, Rufeng; Chou, Jieming

    2015-01-01

    Environmentally extended input-output analysis (EEIOA) has long been used to quantify global and regional environmental impacts and to clarify emission transfers. Structural path analysis (SPA), a technique based on EEIOA, is especially useful for measuring significant flows in this environmental-economic system. This paper constructs an imports-adjusted single-region input-output (SRIO) model considering only domestic final use elements, and it uses the SPA technique to highlight crucial routes along the production chain in both final use and sectoral perspectives. The results indicate that future mitigation policies on household consumption should change direct energy use structures in rural areas, cut unreasonable demand for power and chemical products, and focus on urban areas due to their consistently higher magnitudes than rural areas in the structural routes. Impacts originating from government spending should be tackled by managing onsite energy use in 3 major service sectors and promoting cleaner fuels and energy-saving techniques in the transport sector. Policies on investment should concentrate on sectoral interrelationships along the production chain by setting up standards to regulate upstream industries, especially for the services, construction and equipment manufacturing sectors, which have high demand pulling effects. Apart from the similar methods above, mitigating policies in exports should also consider improving embodied technology and quality in manufactured products to achieve sustainable development. Additionally, detailed sectoral results in the coal extraction industry highlight the onsite energy use management in large domestic companies, emphasize energy structure rearrangement, and indicate resources and energy safety issues. Conclusions based on the construction and public administration sectors reveal that future mitigation in secondary and tertiary industries should be combined with upstream emission intensive industries in a

  11. Graphene-Supported Platinum Catalyst-Based Membrane Electrode Assembly for PEM Fuel Cell

    Science.gov (United States)

    Devrim, Yilser; Albostan, Ayhan

    2016-08-01

    The aim of this study is the preparation and characterization of a graphene-supported platinum (Pt) catalyst for proton exchange membrane fuel cell (PEMFC) applications. The graphene-supported Pt catalysts were prepared by chemical reduction of graphene and chloroplatinic acid (H2PtCl6) in ethylene glycol. X-ray powder diffraction, thermogravimetric analysis (TGA) and scanning electron microscopy have been used to analyze structure and surface morphology of the graphene-supported catalyst. The TGA results showed that the Pt loading of the graphene-supported catalyst was 31%. The proof of the Pt particles on the support surfaces was also verified by energy-dispersive x-ray spectroscopy analysis. The commercial carbon-supported catalyst and prepared Pt/graphene catalysts were used as both anode and cathode electrodes for PEMFC at ambient pressure and 70°C. The maximum power density was obtained for the Pt/graphene-based membrane electrode assembly (MEA) with H2/O2 reactant gases as 0.925 W cm2. The maximum current density of the Pt/graphene-based MEA can reach 1.267 and 0.43 A/cm2 at 0.6 V with H2/O2 and H2/air, respectively. The MEA prepared by the Pt/graphene catalyst shows good stability in long-term PEMFC durability tests. The PEMFC cell voltage was maintained at 0.6 V without apparent voltage drop when operated at 0.43 A/cm2 constant current density and 70°C for 400 h. As a result, PEMFC performance was found to be superlative for the graphene-supported Pt catalyst compared with the Pt/C commercial catalyst. The results indicate the graphene-supported Pt catalyst could be utilized as the electrocatalyst for PEMFC applications.

  12. Ionic-liquid-based proton conducting membranes for anhydrous H2/Cl2 fuel-cell applications.

    Science.gov (United States)

    Liu, Sa; Zhou, Li; Wang, Pengjie; Zhang, Fangfang; Yu, Shuchun; Shao, Zhigang; Yi, Baolian

    2014-03-12

    An ionic-liquid-doped poly(benzimidazole) (PBI) proton-conducting membrane for an anhydrous H2/Cl2 fuel cell has been proposed. Compared with other ionic liquids, such as imidazole-type ionic liquids, diethylmethylammonium trifluoromethanesulfonate ([dema][TfO]) showed better electrode reaction kinetics (H2 oxidation and Cl2 reduction reaction at platinum) and was more suitable for a H2/Cl2 fuel cell. PBI polymer and [dema][TfO] were compatible with each other, and the hybrid membranes exhibited high stability and good ionic conductivity, reaching 20.73 mS cm(-1) at 160 °C. We also analyzed the proton-transfer mechanism in this ionic-liquid-based membrane and considered that both proton-hopping and diffusion mechanisms existed. In addition, this composite electrolyte worked well in a H2/Cl2 fuel cell under non-water conditions. This work would give a good path to study the novel membranes for anhydrous H2/Cl2 fuel-cell application.

  13. Determination of the Operating Envelope for a Direct Fired Fuel Cell Turbine Hybrid Using Hardware Based Simulation

    Energy Technology Data Exchange (ETDEWEB)

    David Tucker; Eric Liese; Randall Gemmen

    2009-02-10

    The operating range of a direct fired solid oxide fuel cell gas turbine (SOFC/GT) hybrid with bypass control of cathode airflow was determined using a hardware-based simulation facility designed and built by the U.S. Department of Energy, National Energy Technology Laboratory (NETL). Three methods of cathode airflow management using bypass valves in a hybrid power system were evaluated over the maximum range of operation. The cathode air flow was varied independently over the full range of operation of each bypass valve. Each operating point was taken at a steady state condition and was matched to the thermal, pressure and flow output of a corresponding fuel cell operation condition. Turbine electric load was also varied so that the maximum range of fuel cell operation could be studied, and a preliminary operating map could be made. Results are presented to show operating envelopes in terms of cathode air flow, fuel cell and turbine load, and compressor surge margin to be substantial.

  14. Reactor-based management of used nuclear fuel: assessment of major options.

    Science.gov (United States)

    Finck, Phillip J; Wigeland, Roald A; Hill, Robert N

    2011-01-01

    This paper discusses the current status of the ongoing Advanced Fuel Cycle Initiative (AFCI) program in the U.S. Department of Energy that is investigating the potential for using the processing and recycling of used nuclear fuel to improve radioactive waste management, including used fuel. A key element of the strategies is to use nuclear reactors for further irradiation of recovered chemical elements to transmute certain long-lived highly-radioactive isotopes into less hazardous isotopes. Both thermal and fast neutron spectrum reactors are being studied as part of integrated nuclear energy systems where separations, transmutation, and disposal are considered. Radiotoxicity is being used as one of the metrics for estimating the hazard of used fuel and the processing of wastes resulting from separations and recycle-fuel fabrication. Decay heat from the used fuel and/or wastes destined for disposal is used as a metric for use of a geologic repository. Results to date indicate that the most promising options appear to be those using fast reactors in a repeated recycle mode to limit buildup of higher actinides, since the transuranic elements are a key contributor to the radiotoxicity and decay heat. Using such an approach, there could be much lower environmental impact from the high-level waste as compared to direct disposal of the used fuel, but there would likely be greater generation of low-level wastes that will also require disposal. An additional potential waste management benefit is having the ability to tailor waste forms and contents to one or more targeted disposal environments (i.e., to be able to put waste in environments best-suited for the waste contents and forms).

  15. Estimating Impacts of Diesel Fuel Reformulation with Vector-based Blending

    Energy Technology Data Exchange (ETDEWEB)

    Hadder, G.R.

    2003-01-23

    The Oak Ridge National Laboratory Refinery Yield Model has been used to study the refining cost, investment, and operating impacts of specifications for reformulated diesel fuel (RFD) produced in refineries of the U.S. Midwest in summer of year 2010. The study evaluates different diesel fuel reformulation investment pathways. The study also determines whether there are refinery economic benefits for producing an emissions reduction RFD (with flexibility for individual property values) compared to a vehicle performance RFD (with inflexible recipe values for individual properties). Results show that refining costs are lower with early notice of requirements for RFD. While advanced desulfurization technologies (with low hydrogen consumption and little effect on cetane quality and aromatics content) reduce the cost of ultra low sulfur diesel fuel, these technologies contribute to the increased costs of a delayed notice investment pathway compared to an early notice investment pathway for diesel fuel reformulation. With challenging RFD specifications, there is little refining benefit from producing emissions reduction RFD compared to vehicle performance RFD. As specifications become tighter, processing becomes more difficult, blendstock choices become more limited, and refinery benefits vanish for emissions reduction relative to vehicle performance specifications. Conversely, the emissions reduction specifications show increasing refinery benefits over vehicle performance specifications as specifications are relaxed, and alternative processing routes and blendstocks become available. In sensitivity cases, the refinery model is also used to examine the impact of RFD specifications on the economics of using Canadian synthetic crude oil. There is a sizeable increase in synthetic crude demand as ultra low sulfur diesel fuel displaces low sulfur diesel fuel, but this demand increase would be reversed by requirements for diesel fuel reformulation.

  16. 基于喷油脉宽测试法的汽车油耗智能测试技术%Automobile fuel consumption intelligent testing technology based on fuel injection pulse-width test method

    Institute of Scientific and Technical Information of China (English)

    付百学; 胡胜海

    2014-01-01

    injections is detected by the single-chip microcomputer, the fuel injection pulse width is obtained, and the relationship between the quality of engine fuel consumption and the injection pulse width is determined. According to EFI controller principles, we determined the testing method for automobile fuel consumption. Based on fuel consumption testing principles, we built a mathematical model of an automobile fuel-consumption testing system, and corrected the mathematical model in standard conditions. According to the function requirements of the fuel-consumption testing system, we determined the single chip microcomputer model and modules function of automobile fuel consumption test controlling system, and designed the injection pulse signal acquisition system and the main program for the automobile fuel-consumption test system. We structured the trial system on a testing prototype using the automotive fuel consumption prototype and the automotive dynamometer test bench. Through analyzing and processing the trial data, the testing precision of the automobile fuel consumption prototype is up to 0.46%. Engine speed has an important impact on injector characteristics parameters, and it will influence automobile fuel consumption testing accuracy. Injector characteristics parameters under different engine speed conditions were amended using a linear regression method that will further improve automobile fuel-consumption testing accuracy. The research will provide the reference to develop high-precision, intelligent automobile fuel-consumption test equipment.%针对汽车油耗测试存在的问题,采用单片机控制技术,通过直接测试喷油器喷油脉宽测试汽车油耗,研制汽车油耗智能测试仪器。根据汽车发动机喷油器喷油控制原理,确定汽车油耗测试方法。基于油耗测试原理构建汽车油耗测试系统的数学计算模型,并在标准状态下对该数学模型进行修正。根据油耗测试系统的功能要求

  17. New Polymer Electrolyte Membranes Based on Acid Doped PBI For Fuel Cells Operating above 100°C

    DEFF Research Database (Denmark)

    Li, Qingfeng

    2003-01-01

    The technical achievement and challenges for the PEMFC technology based on perfluorosulfonic acid (PFSA) polymer membranes (e.g. Nafion®) are briefly discussed. The newest development for alternative polymer electrolytes for operation above 100°C. As one of the successful approaches to high...... operational temperatures, the development and evaluation of acid doped PBI membranes are reviewed, covering polymer synthesis, membrane casting, acid doping, physiochemical characterization and fuel cell tests....

  18. Applying distance-to-target weighing methodology to evaluate the environmental performance of bio-based energy, fuels, and materials

    OpenAIRE

    Weiss, M.; Patel, M.K.; H. Heilmeier; Bringezu, S.

    2007-01-01

    The enhanced use of biomass for the production of energy, fuels, and materials is one of the key strategies towards sustainable production and consumption. Various life cycle assessment (LCA) studies demonstrate the great potential of bio-based products to reduce both the consumption of non-renewable energy resources and greenhouse gas emissions. However, the production of biomass requires agricultural land and is often associated with adverse environmental effects such as eutrophication of s...

  19. Integrated Data Base report--1993: U.S. spent nuclear fuel and radioactive waste inventories, projections, and characteristics. Revision 10

    Energy Technology Data Exchange (ETDEWEB)

    1994-12-01

    The Integrated Data Base Program has compiled historic data on inventories and characteristics of both commercial and DOE spent nuclear fuel; also, commercial and US government-owned radioactive wastes through December 31, 1993. These data are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecasted is consistent with the latest US Department of Energy/Energy Information Administration projections of US commercial nuclear power growth and the expected DOE-related and private industrial and institutional activities. The radioactive materials considered, on a chapter-by-chapter basis, are spent nuclear fuel, high-level waste, transuranic waste, low-level waste, commercial uranium mill tailings, DOE Environmental Restoration Program wastes, commercial reactor and fuel-cycle facility decommissioning wastes, and mixed (hazardous and radioactive) low-level waste. For most of these categories, current and projected inventories are given the calendar-year 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions. In addition, characteristics and current inventories are reported for miscellaneous radioactive materials that may require geologic disposal. 256 refs., 38 figs., 141 tabs.

  20. Integrated data base for 1993: US spent fuel and radioactive waste inventories, projections, and characteristics. Revision 9

    Energy Technology Data Exchange (ETDEWEB)

    Klein, J.A.; Storch, S.N.; Ashline, R.C. [and others

    1994-03-01

    The Integrated Data Base (IDB) Program has compiled historic data on inventories and characteristics of both commercial and DOE spent fuel; also, commercial and U.S. government-owned radioactive wastes through December 31, 1992. These data are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecasted is consistent with the latest U.S. Department of Energy/Energy Information Administration (DOE/EIA) projections of U.S. commercial nuclear power growth and the expected DOE-related and private industrial and institutional (I/I) activities. The radioactive materials considered, on a chapter-by-chapter basis, are spent nuclear fuel, high-level waste (HLW), transuranic (TRU), waste, low-level waste (LLW), commercial uranium mill tailings, environmental restoration wastes, commercial reactor and fuel-cycle facility decommissioning wastes, and mixed (hazardous and radioactive) LLW. For most of these categories, current and projected inventories are given through the calendar-year (CY) 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions. In addition, characteristics and current inventories are reported for miscellaneous radioactive materials that may require geologic disposal.

  1. Integrated Data Base for 1992: US spent fuel and radioactive waste inventories, projections, and characteristics. Revision 8

    Energy Technology Data Exchange (ETDEWEB)

    Payton, M. L.; Williams, J. T.; Tolbert-Smith, M.; Klein, J. A.

    1992-10-01

    The Integrated Data Base (IDB) Program has compiled current data on inventories and characteristics of commercial spent fuel and both commercial and US government-owned radioactive wastes through December 31, 1991. These data are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecasted is consistent with the latest US Department of Energy/Energy Information Administration (DOE/EIA) projections of US commercial nuclear power growth and the expected DOE-related and private industrial and institutional (I/I) activities. The radioactive materials considered, on a chapter-by-chapter basis, are spent nuclear fuel, high-level waste, transuranic waste, low-level waste, commercial uranium mill tailings, environmental restoration wastes, commercial reactor and fuel cycle facility decommissioning wastes, and mixed (hazardous and radioactive) low-level waste. For most of these categories, current and projected inventories are given through the year 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions. In addition, characteristics and current inventories are reported for miscellaneous radioactive materials that may require geologic disposal.

  2. Characterization of Thermal and Mechanical Properties of Polypropylene-Based Composites for Fuel Cell Bipolar Plates and Development of Educational Tools in Hydrogen and Fuel Cell Technologies

    Science.gov (United States)

    Lopez Gaxiola, Daniel

    2011-01-01

    In this project we developed conductive thermoplastic resins by adding varying amounts of three different carbon fillers: carbon black (CB), synthetic graphite (SG) and multi-walled carbon nanotubes (CNT) to a polypropylene matrix for application as fuel cell bipolar plates. This component of fuel cells provides mechanical support to the stack,…

  3. Feasibility study of boiling water reactor core based on thorium-uranium fuel concept

    Energy Technology Data Exchange (ETDEWEB)

    Nunez-Carrera, Alejandro [Comision Nacional de Seguridad Nuclear y Salvaguardias, Dr. Barragan 779, Col Narvarte, 03020 Mexico D.F. (Mexico); Francois Lacouture, Juan Luis; Martin del Campo, Cecilia [Universidad Nacional Autonoma de Mexico, Facultad de Ingenieria, Paseo Cuauhnahuac 8532, Jiutepec, Mor. (Mexico); Espinosa-Paredes, Gilberto [Area de Ingenieria en Recursos Energeticos, Universidad Autonoma Metropolitana Iztapalapa, Apartado Postal 55-534, Mexico D.F. 09340 (Mexico)], E-mail: gepe@xanum.uam.mx

    2008-01-15

    The design of a boiling water reactor (BWR) equilibrium core using the thorium-uranium (blanket-seed) concept in the same integrated fuel assembly is presented in this paper. The lattice design uses the thorium conversion capability to {sup 233}U in a BWR spectrum. A core design was developed to achieve an equilibrium cycle of one effective full power year in a standard BWR with a reload of 104 fuel assemblies designed with an average {sup 235}U enrichment of 7.5 w/o in the seed sub-lattice. The main core operating parameters were obtained. It was observed that the analyzed parameters behave like those obtained in a standard BWR. The economic analysis shows that the fuel cycle cost of the proposed core design can be competitive with a standard uranium core design. Finally, a comparison of the toxicity of the spent fuel showed that the toxicity is lower in the thorium cycle than in other fuel cycles (UO{sub 2} and MOX uranium and plutonium) in the case of the once through cycle for light water reactors (LWR)

  4. Life Cycle Assesment (LCA Based Environmental Impact Minimization of Solid Fuel Boilers in Lithuanian Industry

    Directory of Open Access Journals (Sweden)

    Marius Šulga

    2011-12-01

    Full Text Available Today Europe is facing unprecedented energy problems related to the EU dependence on energy imports, concerns about global supplies of fossil fuel and obvious climate change. However, despite all these problems Europe wastes at least 20 percent of energy due to its inefficient use.The EU energy efficiency policy states that one of the biggest saving potentials lies in heating of the buildings whose current consumption is ~ 1725 Mt. The EU building sector is the largest final energy consumer.This research deals with domestic solid fuel boilers that are used in buildings and their efficiency increase by applying life-cycle tools. This article analyzes the situation of manufacturing solid fuel boilers in Lithuania, the EU EuP policy, the main environmental issues of boilers production (their production and use phases. The impact of two different fuels (wood and coal on the environment is also estimated, propositions of an ecological design of boilers are presented and a new solid fuel boiler is described.

  5. Characterizing model uncertainties in the life cycle of lignocellulose-based ethanol fuels.

    Science.gov (United States)

    Spatari, Sabrina; MacLean, Heather L

    2010-11-15

    Renewable and low carbon fuel standards being developed at federal and state levels require an estimation of the life cycle carbon intensity (LCCI) of candidate fuels that can substitute for gasoline, such as second generation bioethanol. Estimating the LCCI of such fuels with a high degree of confidence requires the use of probabilistic methods to account for known sources of uncertainty. We construct life cycle models for the bioconversion of agricultural residue (corn stover) and energy crops (switchgrass) and explicitly examine uncertainty using Monte Carlo simulation. Using statistical methods to identify significant model variables from public data sets and Aspen Plus chemical process models,we estimate stochastic life cycle greenhouse gas (GHG) emissions for the two feedstocks combined with two promising fuel conversion technologies. The approach can be generalized to other biofuel systems. Our results show potentially high and uncertain GHG emissions for switchgrass-ethanol due to uncertain CO₂ flux from land use change and N₂O flux from N fertilizer. However, corn stover-ethanol,with its low-in-magnitude, tight-in-spread LCCI distribution, shows considerable promise for reducing life cycle GHG emissions relative to gasoline and corn-ethanol. Coproducts are important for reducing the LCCI of all ethanol fuels we examine.

  6. Formulation, Casting, and Evaluation of Paraffin-Based Solid Fuels Containing Energetic and Novel Additives for Hybrid Rockets

    Science.gov (United States)

    Larson, Daniel B.; Desain, John D.; Boyer, Eric; Wachs, Trevor; Kuo, Kenneth K.; Borduin, Russell; Koo, Joseph H.; Brady, Brian B.; Curtiss, Thomas J.; Story, George

    2012-01-01

    This investigation studied the inclusion of various additives to paraffin wax for use in a hybrid rocket motor. Some of the paraffin-based fuels were doped with various percentages of LiAlH4 (up to 10%). Addition of LiAlH4 at 10% was found to increase regression rates between 7 - 10% over baseline paraffin through tests in a gaseous oxygen hybrid rocket motor. Mass burn rates for paraffin grains with 10% LiAlH4 were also higher than those of the baseline paraffin. RDX was also cast into a paraffin sample via a novel casting process which involved dissolving RDX into dimethylformamide (DMF) solvent and then drawing a vacuum on the mixture of paraffin and RDX/DMF in order to evaporate out the DMF. It was found that although all DMF was removed, the process was not conducive to generating small RDX particles. The slow boiling generated an inhomogeneous mixture of paraffin and RDX. It is likely that superheating the DMF to cause rapid boiling would likely reduce RDX particle sizes. In addition to paraffin/LiAlH4 grains, multi-walled carbon nanotubes (MWNT) were cast in paraffin for testing in a hybrid rocket motor, and assorted samples containing a range of MWNT percentages in paraffin were imaged using SEM. The fuel samples showed good distribution of MWNT in the paraffin matrix, but the MWNT were often agglomerated, indicating that a change to the sonication and mixing processes were required to achieve better uniformity and debundled MWNT. Fuel grains with MWNT fuel grains had slightly lower regression rate, likely due to the increased thermal conductivity to the fuel subsurface, reducing the burning surface temperature.

  7. Metallic fuels for advanced reactors

    Science.gov (United States)

    Carmack, W. J.; Porter, D. L.; Chang, Y. I.; Hayes, S. L.; Meyer, M. K.; Burkes, D. E.; Lee, C. B.; Mizuno, T.; Delage, F.; Somers, J.

    2009-07-01

    In the framework of the Generation IV Sodium Fast Reactor Program, the Advanced Fuel Project has conducted an evaluation of the available fuel systems supporting future sodium cooled fast reactors. This paper presents an evaluation of metallic alloy fuels. Early US fast reactor developers originally favored metal alloy fuel due to its high fissile density and compatibility with sodium. The goal of fast reactor fuel development programs is to develop and qualify a nuclear fuel system that performs all of the functions of a conventional fast spectrum nuclear fuel while destroying recycled actinides. This will provide a mechanism for closure of the nuclear fuel cycle. Metal fuels are candidates for this application, based on documented performance of metallic fast reactor fuels and the early results of tests currently being conducted in US and international transmutation fuel development programs.

  8. A Rechargeable Li-Air Fuel Cell Battery Based on Garnet Solid Electrolytes

    Science.gov (United States)

    Sun, Jiyang; Zhao, Ning; Li, Yiqiu; Guo, Xiangxin; Feng, Xuefei; Liu, Xiaosong; Liu, Zhi; Cui, Guanglei; Zheng, Hao; Gu, Lin; Li, Hong

    2017-01-01

    Non-aqueous Li-air batteries have been intensively studied in the past few years for their theoretically super-high energy density. However, they cannot operate properly in real air because they contain highly unstable and volatile electrolytes. Here, we report the fabrication of solid-state Li-air batteries using garnet (i.e., Li6.4La3Zr1.4Ta0.6O12, LLZTO) ceramic disks with high density and ionic conductivity as the electrolytes and composite cathodes consisting of garnet powder, Li salts (LiTFSI) and active carbon. These batteries run in real air based on the formation and decomposition at least partially of Li2CO3. Batteries with LiTFSI mixed with polyimide (PI:LiTFSI) as a binder show rechargeability at 200 °C with a specific capacity of 2184 mAh g−1carbon at 20 μA cm−2. Replacement of PI:LiTFSI with LiTFSI dissolved in polypropylene carbonate (PPC:LiTFSI) reduces interfacial resistance, and the resulting batteries show a greatly increased discharge capacity of approximately 20300 mAh g−1carbon and cycle 50 times while maintaining a cutoff capacity of 1000 mAh g−1carbon at 20 μA cm−2 and 80 °C. These results demonstrate that the use of LLZTO ceramic electrolytes enables operation of the Li-air battery in real air at medium temperatures, leading to a novel type of Li-air fuel cell battery for energy storage. PMID:28117359

  9. Critical analysis of the Hanford spent nuclear fuel project activity based cost estimate

    Energy Technology Data Exchange (ETDEWEB)

    Warren, R.N.

    1998-09-29

    In 1997, the SNFP developed a baseline change request (BCR) and submitted it to DOE-RL for approval. The schedule was formally evaluated to have a 19% probability of success [Williams, 1998]. In December 1997, DOE-RL Manager John Wagoner approved the BCR contingent upon a subsequent independent review of the new baseline. The SNFP took several actions during the first quarter of 1998 to prepare for the independent review. The project developed the Estimating Requirements and Implementation Guide [DESH, 1998] and trained cost account managers (CAMS) and other personnel involved in the estimating process in activity-based cost (ABC) estimating techniques. The SNFP then applied ABC estimating techniques to develop the basis for the December Baseline (DB) and documented that basis in Basis of Estimate (BOE) books. These BOEs were provided to DOE in April 1998. DOE commissioned Professional Analysis, Inc. (PAI) to perform a critical analysis (CA) of the DB. PAI`s review formally began on April 13. PAI performed the CA, provided three sets of findings to the SNFP contractor, and initiated reconciliation meetings. During the course of PAI`s review, DOE directed the SNFP to develop a new baseline with a higher probability of success. The contractor transmitted the new baseline, which is referred to as the High Probability Baseline (HPB), to DOE on April 15, 1998 [Williams, 1998]. The HPB was estimated to approach a 90% confidence level on the start of fuel movement [Williams, 1998]. This high probability resulted in an increased cost and a schedule extension. To implement the new baseline, the contractor initiated 26 BCRs with supporting BOES. PAI`s scope was revised on April 28 to add reviewing the HPB and the associated BCRs and BOES.

  10. A Rechargeable Li-Air Fuel Cell Battery Based on Garnet Solid Electrolytes

    Science.gov (United States)

    Sun, Jiyang; Zhao, Ning; Li, Yiqiu; Guo, Xiangxin; Feng, Xuefei; Liu, Xiaosong; Liu, Zhi; Cui, Guanglei; Zheng, Hao; Gu, Lin; Li, Hong

    2017-01-01

    Non-aqueous Li-air batteries have been intensively studied in the past few years for their theoretically super-high energy density. However, they cannot operate properly in real air because they contain highly unstable and volatile electrolytes. Here, we report the fabrication of solid-state Li-air batteries using garnet (i.e., Li6.4La3Zr1.4Ta0.6O12, LLZTO) ceramic disks with high density and ionic conductivity as the electrolytes and composite cathodes consisting of garnet powder, Li salts (LiTFSI) and active carbon. These batteries run in real air based on the formation and decomposition at least partially of Li2CO3. Batteries with LiTFSI mixed with polyimide (PI:LiTFSI) as a binder show rechargeability at 200 °C with a specific capacity of 2184 mAh g‑1carbon at 20 μA cm‑2. Replacement of PI:LiTFSI with LiTFSI dissolved in polypropylene carbonate (PPC:LiTFSI) reduces interfacial resistance, and the resulting batteries show a greatly increased discharge capacity of approximately 20300 mAh g‑1carbon and cycle 50 times while maintaining a cutoff capacity of 1000 mAh g‑1carbon at 20 μA cm‑2 and 80 °C. These results demonstrate that the use of LLZTO ceramic electrolytes enables operation of the Li-air battery in real air at medium temperatures, leading to a novel type of Li-air fuel cell battery for energy storage.

  11. Modeling Heavy/Medium-Duty Fuel Consumption Based on Drive Cycle Properties

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Lijuan; Duran, Adam; Gonder, Jeffrey; Kelly, Kenneth

    2015-10-13

    This paper presents multiple methods for predicting heavy/medium-duty vehicle fuel consumption based on driving cycle information. A polynomial model, a black box artificial neural net model, a polynomial neural network model, and a multivariate adaptive regression splines (MARS) model were developed and verified using data collected from chassis testing performed on a parcel delivery diesel truck operating over the Heavy Heavy-Duty Diesel Truck (HHDDT), City Suburban Heavy Vehicle Cycle (CSHVC), New York Composite Cycle (NYCC), and hydraulic hybrid vehicle (HHV) drive cycles. Each model was trained using one of four drive cycles as a training cycle and the other three as testing cycles. By comparing the training and testing results, a representative training cycle was chosen and used to further tune each method. HHDDT as the training cycle gave the best predictive results, because HHDDT contains a variety of drive characteristics, such as high speed, acceleration, idling, and deceleration. Among the four model approaches, MARS gave the best predictive performance, with an average absolute percent error of -1.84% over the four chassis dynamometer drive cycles. To further evaluate the accuracy of the predictive models, the approaches were first applied to real-world data. MARS outperformed the other three approaches, providing an average absolute percent error of -2.2% of four real-world road segments. The MARS model performance was then compared to HHDDT, CSHVC, NYCC, and HHV drive cycles with the performance from Future Automotive System Technology Simulator (FASTSim). The results indicated that the MARS method achieved a comparative predictive performance with FASTSim.

  12. PBI-based polymer electrolyte membranes fuel cells. Temperature effects on cell performance and catalyst stability

    Energy Technology Data Exchange (ETDEWEB)

    Lobato, Justo; Canizares, Pablo; Rodrigo, Manuel A.; Linares, Jose J. [Chemical Engineering Department, University of Castilla-La Mancha, Campus Universitario s/n, 13004 Ciudad Real (Spain)

    2007-03-10

    In this work, it has been shown that the temperature (ranging from 100 to 175 C) greatly influences the performance of H{sub 3}PO{sub 4}-doped polybenzimidazole-based high-temperature polymer electrolyte membrane fuel cells by several and complex processes. The temperature, by itself, increases H{sub 3}PO{sub 4}-doped PBI conductivity and enhances the electrodic reactions as it rises. Nevertheless, high temperatures reduce the level of hydration of the membrane, above 130-140 C accelerate the self-dehydration of H{sub 3}PO{sub 4}, and they may boost the process of catalyst particle agglomeration that takes place in strongly acidic H{sub 3}PO{sub 4} medium (as checked by multi-cycling sweep voltammetry), reducing the overall electrochemical active surface. The first process seems to have a rapid response to changes in the temperature and controls the cell performance immediately after them. The second process seems to develop slower, and influences the cell performance in the 'long-term'. The predominant processes, at each moment and temperature, determine the effect of the temperature on the cell performance, as potentiostatic curves display. 'Long-term' polarization curves grow up to 150 C and decrease at 175 C. 'Short-term' ones continuously increase as the temperature does after 'conditioning' the cell at 125 C. On the contrary, when compared the polarization curves at 175 C a continuous decrease is observed with the 'conditioning' temperature. A discussion of the observed trends is proposed in this work. (author)

  13. Electricity Generation from Organic Matters in Biocatalyst-Based Microbial Fuel Cells (MFCs)

    DEFF Research Database (Denmark)

    Min, Booki; Zhang, Yifeng; Angelidaki, Irini

    Microbial fuel cells (MFCs) are a novel technology for converting organic matter directly to electricity via biocatalytic reactions by microorganisms. MFCs can also be used for wastewater treatment by the oxidations of organic pollutants during the electricity generation. Several factors...... for optimum power generation in MFC have been investigated at previous studies. A submersible microbial fuel cell (SMFC), which is a novel configuration, was developed by immersing an anode electrode and a cathode chamber in an anaerobic reactor. Domestic wastewater without any amendments was used...... generation showed a saturation-type relationship as a function of wastewater strength, with a maximum power density (Pmax) of 218mWm−2 and a saturation constant (Ks) of 244 mg L−1.We also achieved a successful power generation (123 mW/m2) from wheat straw hydrolysate in a two chamber microbial fuel cells...

  14. More efficiency in fuel consumption using gearbox optimization based on Taguchi method

    Science.gov (United States)

    Goharimanesh, Masoud; Akbari, Aliakbar; Akbarzadeh Tootoonchi, Alireza

    2014-05-01

    Automotive emission is becoming a critical threat to today's human health. Many researchers are studying engine designs leading to less fuel consumption. Gearbox selection plays a key role in an engine design. In this study, Taguchi quality engineering method is employed, and optimum gear ratios in a five speed gear box is obtained. A table of various gear ratios is suggested by design of experiment techniques. Fuel consumption is calculated through simulating the corresponding combustion dynamics model. Using a 95 % confidence level, optimal parameter combinations are determined using the Taguchi method. The level of importance of the parameters on the fuel efficiency is resolved using the analysis of signal-to-noise ratio as well as analysis of variance.

  15. Advanced chemical hydride-based hydrogen generation/storage system for fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Breault, R.W.; Rolfe, J. [Thermo Power Corp., Waltham, MA (United States)

    1998-08-01

    Because of the inherent advantages of high efficiency, environmental acceptability, and high modularity, fuel cells are potentially attractive power supplies. Worldwide concerns over clean environments have revitalized research efforts on developing fuel cell vehicles (FCV). As a result of intensive research efforts, most of the subsystem technology for FCV`s are currently well established. These include: high power density PEM fuel cells, control systems, thermal management technology, and secondary power sources for hybrid operation. For mobile applications, however, supply of hydrogen or fuel for fuel cell operation poses a significant logistic problem. To supply high purity hydrogen for FCV operation, Thermo Power`s Advanced Technology Group is developing an advanced hydrogen storage technology. In this approach, a metal hydride/organic slurry is used as the hydrogen carrier and storage media. At the point of use, high purity hydrogen will be produced by reacting the metal hydride/organic slurry with water. In addition, Thermo Power has conceived the paths for recovery and regeneration of the spent hydride (practically metal hydroxide). The fluid-like nature of the spent hydride/organic slurry will provide a unique opportunity for pumping, transporting, and storing these materials. The final product of the program will be a user-friendly and relatively high energy storage density hydrogen supply system for fuel cell operation. In addition, the spent hydride can relatively easily be collected at the pumping station and regenerated utilizing renewable sources, such as biomass, natural, or coal, at the central processing plants. Therefore, the entire process will be economically favorable and environmentally friendly.

  16. Sensor system for fuel transport vehicle

    Science.gov (United States)

    Earl, Dennis Duncan; McIntyre, Timothy J.; West, David L.

    2016-03-22

    An exemplary sensor system for a fuel transport vehicle can comprise a fuel marker sensor positioned between a fuel storage chamber of the vehicle and an access valve for the fuel storage chamber of the vehicle. The fuel marker sensor can be configured to measure one or more characteristics of one or more fuel markers present in the fuel adjacent the sensor, such as when the marked fuel is unloaded at a retail station. The one or more characteristics can comprise concentration and/or identity of the one or more fuel markers in the fuel. Based on the measured characteristics of the one or more fuel markers, the sensor system can identify the fuel and/or can determine whether the fuel has been adulterated after the marked fuel was last measured, such as when the marked fuel was loaded into the vehicle.

  17. Advanced reactors and novel reactions for the conversion of triglyceride based oils into high quality renewable transportation fuels

    Science.gov (United States)

    Linnen, Michael James

    Sustainable energy continues to grow more important to all societies, leading to the research and development of a variety of alternative and renewable energy technologies. Of these, renewable liquid transportation fuels may be the most visible to consumers, and this visibility is further magnified by the long-term trend of increasingly expensive petroleum fuels that the public consumes. While first-generation biofuels such as biodiesel and fuel ethanol have been integrated into the existing fuel infrastructures of several countries, the chemical differences between them and their petroleum counterparts reduce their effectiveness. This gives rise to the development and commercialization of second generation biofuels, many of which are intended to have equivalent properties to those of their petroleum counterparts. In this dissertation, the primary reactions for a second-generation biofuel process, known herein as the University of North Dakota noncatalytic cracking process (NCP), have been studied at the fundamental level and improved. The NCP is capable of producing renewable fuels and chemicals that are virtually the same as their petroleum counterparts in performance and quality (i.e., petroleum-equivalent). In addition, a novel analytical method, FIMSDIST was developed which, within certain limitations, can increase the elution capabilities of GC analysis and decrease sample processing times compared to other high resolution methods. These advances are particularly useful for studies of highly heterogeneous fuel and/or organic chemical intermediates, such as those studied for the NCP. However the data from FIMSDIST must be supplemented with data from other methods such as for certain carboxylic acid, to provide accurate, comprehensive results, From a series of TAG cracking experiments that were performed, it was found that coke formation during cracking is most likely the result of excessive temperature and/or residence time in a cracking reactor. Based on this

  18. The modeling and simulation of thermal based modified solid oxide fuel cell (SOFC for grid-connected systems

    Directory of Open Access Journals (Sweden)

    Ayetül Gelen

    2015-05-01

    Full Text Available This paper presents a thermal based modified dynamic model of a Solid Oxide Fuel Cell (SOFC for grid-connected systems. The proposed fuel cell model involves ohmic, activation and concentration voltage losses, thermal dynamics, methanol reformer, fuel utilization factor and power limiting module. A power conditioning unit (PCU, which consists of a DC-DC boost converter and a DC-AC voltage-source inverter (VSI, their controller, transformer and filter, is designed for grid-connected systems. The voltage-source inverter with six Insulated Gate Bipolar Transistor (IGBT switches inverts the DC voltage that comes from the converter into a sinusoidal voltage synchronized with the grid. The simulations and modeling of the system are developed on Matlab/Simulink environment. The performance of SOFC with converter is examined under step and random load conditions. The simulation results show that the designed boost converter for the proposed thermal based modified SOFC model has fairly followed different DC load variations. Finally, the AC bus of 400 Volt and 50 Hz is connected to a single-machine infinite bus (SMIB through a transmission line. The real and reactive power managements of the inverter are analyzed by an infinite bus system. Thus, the desired nominal values are properly obtained by means of the inverter controller.

  19. Methodology and a preliminary data base for examining the health risks of electricity generation from uranium and coal fuels

    Energy Technology Data Exchange (ETDEWEB)

    El-Bassioni, A.A.

    1980-08-01

    An analytical model was developed to assess and examine the health effects associated with the production of electricity from uranium and coal fuels. The model is based on a systematic methodology that is both simple and easy to check, and provides details about the various components of health risk. A preliminary set of data that is needed to calculate the health risks was gathered, normalized to the model facilities, and presented in a concise manner. Additional data will become available as a result of other evaluations of both fuel cycles, and they should be included in the data base. An iterative approach involving only a few steps is recommended for validating the model. After each validation step, the model is improved in the areas where new information or increased interest justifies such upgrading. Sensitivity analysis is proposed as the best method of using the model to its full potential. Detailed quantification of the risks associated with the two fuel cycles is not presented in this report. The evaluation of risks from producing electricity by these two methods can be completed only after several steps that address difficult social and technical questions. Preliminary quantitative assessment showed that several factors not considered in detail in previous studies are potentially important. 255 refs., 21 figs., 179 tabs.

  20. Exploring Sustainable Rocket Fuels: [Imidazolyl-Amine-BH2](+)-Cation-Based Ionic Liquids as Replacements for Toxic Hydrazine Derivatives.

    Science.gov (United States)

    Huang, Shi; Qi, Xiujuan; Zhang, Wenquan; Liu, Tianlin; Zhang, Qinghua

    2015-12-01

    The application of hypergolic ionic liquids as propellant fuels is a newly emerging area in the fields of chemistry and propulsion science. Herein, a new class of [imidazolyl-amine-BH2](+)-cation-based ionic liquids, which included fuel-rich anions, such as dicyanamide (N(CN)2(-)) and cyanoborohydride (BH3CN(-)) anions, were synthesized and characterized. As expected, all of the ionic liquids exhibited spontaneous combustion upon contact with the oxidizer 100 % HNO3. The densities of these ionic liquids varied from 0.99-1.12 g cm(-3), and the heats of formation, predicted based on Gaussian 09 calculations, were between -707.7 and 241.8 kJ mol(-1). Among them, the salt of compound 5, that is, (1-allyl-1H-imidazole-3-yl)-(trimethylamine)-dihydroboronium dicyanamide, exhibited the lowest viscosity (168 MPa s), good thermal properties (Tg 130 °C), and the shortest ignition-delay time (18 ms) with 100 % HNO3. These ionic fuels, as "green" replacements for toxic hydrazine-derivatives, may have potential applications as bipropellant formulations.

  1. Life cycle assessment of microalgae-based aviation fuel: Influence of lipid content with specific productivity and nitrogen nutrient effects.

    Science.gov (United States)

    Guo, Fang; Zhao, Jing; A, Lusi; Yang, Xiaoyi

    2016-12-01

    The aim of this work is to compare the life cycle assessments of low-N and normal culture conditions for a balance between the lipid content and specific productivity. In order to achieve the potential contribution of lipid content to the life cycle assessment, this study established relationships between lipid content (nitrogen effect) and specific productivity based on three microalgae strains including Chlorella, Isochrysis and Nannochloropsis. For microalgae-based aviation fuel, the effects of the lipid content on fossil fuel consumption and greenhouse gas (GHG) emissions are similar. The fossil fuel consumption (0.32-0.68MJ·MJ(-1)MBAF) and GHG emissions (17.23-51.04gCO2e·MJ(-1)MBAF) increase (59.70-192.22%) with the increased lipid content. The total energy input decreases (2.13-3.08MJ·MJ(-1)MBAF, 14.91-27.95%) with the increased lipid content. The LCA indicators increased (0-47.10%) with the decreased nitrogen recovery efficiency (75-50%).

  2. SARAPAN—A Simulated-Annealing-Based Tool to Generate Random Patterned-Channel-Age in CANDU Fuel Management Analyses

    Directory of Open Access Journals (Sweden)

    Doddy Kastanya

    2017-02-01

    Full Text Available In any reactor physics analysis, the instantaneous power distribution in the core can be calculated when the actual bundle-wise burnup distribution is known. Considering the fact that CANDU (Canada Deuterium Uranium utilizes on-power refueling to compensate for the reduction of reactivity due to fuel burnup, in the CANDU fuel management analysis, snapshots of power and burnup distributions can be obtained by simulating and tracking the reactor operation over an extended period using various tools such as the *SIMULATE module of the Reactor Fueling Simulation Program (RFSP code. However, for some studies, such as an evaluation of a conceptual design of a next-generation CANDU reactor, the preferred approach to obtain a snapshot of the power distribution in the core is based on the patterned-channel-age model implemented in the *INSTANTAN module of the RFSP code. The objective of this approach is to obtain a representative snapshot of core conditions quickly. At present, such patterns could be generated by using a program called RANDIS, which is implemented within the *INSTANTAN module. In this work, we present an alternative approach to derive the patterned-channel-age model where a simulated-annealing-based algorithm is used to find such patterns, which produce reasonable power distributions.

  3. Ferrite-based perovskites as cathode materials for anode-supported solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Mai, Andreas; Haanappel, Vincent A.C.; Uhlenbruck, Sven; Tietz, Frank; Stoever, Detlev [Institute for Materials and Processes in Energy Systems, Forschungszentrum Juelich, IWV-1, D-52425 Juelich (Germany)

    2005-05-12

    The properties and the applicability of iron- and cobalt-containing perovskites were evaluated as cathodes for solid oxide fuel cells (SOFCs) in comparison to state-of-the-art manganite-based perovskites. The materials examined were La{sub 1-x-y}Sr{sub x}Co{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (x=0.2 and 0.4; y=0-0.05), La{sub 0.8}Sr{sub 0.2}FeO{sub 3-{delta}}, La{sub 0.7}Ba{sub 0.3}Co{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} and Ce{sub 0.05}Sr{sub 0.95}Co{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}}. The main emphasis was placed on the electrochemical properties of the materials, which were investigated on planar anode-supported SOFCs with 8 mol% yttria-stabilised zirconia (8YSZ) electrolytes. An interlayer of the composition Ce{sub 0.8}Gd{sub 0.2}O{sub 2-{delta}} was placed between the electrolyte and the cathode to prevent undesired chemical reactions between the materials. The sintering temperatures of the cathodes were adapted for each of the materials to obtain similar microstructures. In comparison to the SOFCs with state-of-the-art manganite-based cathodes, SOFCs with La{sub 1-x-y}Sr{sub x}Co{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} cathodes achieved much higher current densities. Small A-site deficiency and high strontium content had a particularly positive effect on cell performance. The measured current densities of cells with these cathodes were as high as 1.76 A/cm{sup 2} at 800 {sup o}C and 0.7 V, which is about twice the current density of cells with LSM/YSZ cathodes. SOFCs with La{sub 0.58}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} cathodes have been operated for more than 5000 h in endurance tests with a degradation of 1.0-1.5% per 1000 h.

  4. Supply Chain-Based Solution to Prevent Fuel Tax Evasion: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Capps, Gary J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Franzese, Oscar [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Lascurain, Mary Beth [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Siekmann, Adam [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Barker, Alan M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Electrical and Electronics Systems Research Division

    2016-07-28

    The primary source of funding for the United States transportation system is derived from motor fuel and other highway use taxes. Loss of revenue attributed to fuel-tax evasion has been assessed to be somewhere between 1 billion and 3 billion per year. Any solution that addresses this problem needs to include not only the tax-collection agencies and auditors, but also the carriers transporting oil products and the carriers customers. This report presents a system developed by the Oak Ridge National Laboratory (ORNL) for the Federal Highway Administration which has the potential to reduce or eliminate many fuel-tax evasion schemes. The solution balances the needs of tax-auditors and those of the fuel-hauling companies and their customers. The system has three main components. The on-board subsystem combined sensors, tracking and communication devices, and software (the on-board Evidential Reasoning System, or obERS) to detect, monitor, and geo-locate the transfer of fuel among different locations. The back office sub-system (boERS) used self-learning algorithms to determine the legitimacy of the fuel loading and offloading (important for tax auditors) and detect potential illicit operations such as fuel theft (important for carriers and their customers, and may justify the deployment costs). The third sub-system, the Fuel Distribution and Auditing System or FDAS, is a centralized database, which together with a user interface allows tax auditors to query the data submitted by the fuel-hauling companies and correlate different parameters to quickly identify any anomalies. Industry partners included Barger Transport of Weber City, Virginia (fleet); Air-Weigh, of Eugene, Oregon (and their wires and harnesses); Liquid Bulk Tank (LBT) of Omaha, Nebraska (three five-compartment trailers); and Innovative Software Engineering (ISE) of Coralville, Iowa(on-board telematics device and back-office system). ORNL conducted a pilot test with the three instrumented vehicles

  5. Supply Chain-Based Solution to Prevent Fuel Tax Evasion: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Capps, Gary J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Franzese, Oscar [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Lascurain, Mary Beth [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Siekmann, Adam [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Barker, Alan M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Electrical and Electronics Systems Research Division

    2016-07-28

    The primary source of funding for the United States transportation system is derived from motor fuel and other highway use taxes. Loss of revenue attributed to fuel-tax evasion has been assessed to be somewhere between 1 billion and 3 billion per year. Any solution that addresses this problem needs to include not only the tax-collection agencies and auditors, but also the carriers transporting oil products and the carriers customers. This report presents a system developed by the Oak Ridge National Laboratory (ORNL) for the Federal Highway Administration which has the potential to reduce or eliminate many fuel-tax evasion schemes. The solution balances the needs of tax-auditors and those of the fuel-hauling companies and their customers. The system has three main components. The on-board subsystem combined sensors, tracking and communication devices, and software (the on-board Evidential Reasoning System, or obERS) to detect, monitor, and geo-locate the transfer of fuel among different locations. The back office sub-system (boERS) used self-learning algorithms to determine the legitimacy of the fuel loading and offloading (important for tax auditors) and detect potential illicit operations such as fuel theft (important for carriers and their customers, and may justify the deployment costs). The third sub-system, the Fuel Distribution and Auditing System or FDAS, is a centralized database, which together with a user interface allows tax auditors to query the data submitted by the fuel-hauling companies and correlate different parameters to quickly identify any anomalies. Industry partners included Barger Transport of Weber City, Virginia (fleet); Air-Weigh, of Eugene, Oregon (and their wires and harnesses); Liquid Bulk Tank (LBT) of Omaha, Nebraska (three five-compartment trailers); and Innovative Software Engineering (ISE) of Coralville, Iowa(on-board telematics device and back-office system). ORNL conducted a pilot test with the three instrumented vehicles

  6. A novel power generation system based on combination of hydrogen and direct carbon fuel cells for decentralized applications

    Energy Technology Data Exchange (ETDEWEB)

    Muradov, Nazim; Smith, Franklyn; Choi, Pyoungho; Bokerman, Gary [Central Florida Univ., FL (United States)

    2010-07-01

    Fuel cell (FC) based power generation systems are characterized by highest chemical-toelectrical (CTE) energy conversion efficiency compared to conventional power generators (e.g., internal combustion and diesel engines, turbines). Most efforts in this area relate to hydrogen-FC coupled with hydrocarbon fuel reformers (HFR). However, the overall CTE efficiency of the combined HFR-FC systems is relatively low (about 30-35%). The objective of this work is to develop a highly-efficient power generation system integrating a hydrocarbon decomposition reactor (HDR) with both hydrogen and direct-carbon FC. A unique feature of direct carbon FC is that its theoretical CTE efficiency is close to 100% and the practical efficiency could rich 80-90%. The concept of the integrated hydrogen and direct carbon FC system is discussed and the experimental data on the performance testing of a HDR coupled with PEM FC are presented in this paper. (orig.)

  7. State participation in the creation of fuel-cell-based power plants to meet civilian demand in Russia

    Energy Technology Data Exchange (ETDEWEB)

    Pekhota, F.N.

    1996-04-01

    At present, up to 70% of Russian territory is not covered by central electrical distribution systems. In the field of fuel cell power plants, Russia is at parity with the leading foreign countries with respect to both technical and economic performance and the level of research being conducted. Civilian use of these generating systems on a broad scale, however, demands that a number of problems be solved, particularly those relating to the need for longer plant service life, lower unit cost of electricity, etc. The Ministry of Science and technical Policy of the Russian Federation issued a decree creating a new are of concentration, `Fuel Cell Based Power Plants for Civilian Needs,` in the GNTPR `Environmentally Clean Power Industry,` which will form the basis for financial support in this area out of the federal budget.

  8. Investigation of the Start-up Strategy for a Solid Oxide Fuel Cell Based Auxiliary Power Unit under Transient Conditions

    Directory of Open Access Journals (Sweden)

    Michael R. von Spakovsky

    2005-06-01

    Full Text Available

    A typical approach to the synthesis/design optimization of energy systems is to only use steady state operation and high efficiency (or low total life cycle cost at full load as the basis for the synthesis/design. Transient operation as reflected by changes in power demand, shut-down, and start-up are left as secondary tasks to be solved by system and control engineers once the synthesis/design is fixed. However, start-up and shut-down may be events that happen quite often and, thus, may be quite important in the creative process of developing the system. This is especially true for small power units used in transportation applications or for domestic energy supplies, where the load demand changes frequently and peaks in load of short duration are common. The duration of start-up is, of course, a major factor which must be considered since rapid system response is an important factor in determining the feasibility of solid oxide fuel cell (SOFC based auxiliary power units (APUs. Start-up and shut-down may also significantly affect the life span of the system due to thermal stresses on all system components. Therefore, a proper balance must be struck between a fast response and the costs of owning and operating the system so that start-up or any other transient process can be accomplished in as short a time as possible yet with a minimum in fuel consumption.

    In this research work we have been studying the effects of control laws and strategies and transients on system performance. The results presented in this paper are based on a set of transient models developed and implemented for the components of a 5 kWe net power SOFC based APU and for the high-fidelity system which results from their integration. The simulation results given below are for two different start-up approaches: one with steam recirculation and component pre-heating and the second without either. These start-up simulations were performed for fixed values of a number of

  9. Fracture properties of nickel-based anodes for solid oxide fuel cells

    DEFF Research Database (Denmark)

    Goutianos, Stergios; Frandsen, Henrik Lund; Sørensen, Bent F.

    2010-01-01

    such as the anode material (NiO–YSZ) in a fuel cell. The approach involves a new specimen geometry which consists of a thin ceramic glued onto thick steel beams to form a double cantilever beam (DCB) specimen. The fracture toughness values, measured from truly sharp cracks, are obtained over a range of applied...

  10. Issues for Storing Plant-Based Alternative Fuels in Marine Environments

    Science.gov (United States)

    2014-05-09

    anaerobic biodegradation of hydrocarbons were detected in fuel layers by GC-MS prior to incuba- tion. At the end of the incubation, several putative...contention that hydrocarbon removal was due at least in part to biodegradation by seawater microorganisms. Benzoate. cresols and alkanoic acids...oligotrophic and eutrophic environments, respectively) were used to evaluate potential biodegradation and corrosion problems during exposure to

  11. A microbial fuel cell-based biosensor for the detection of toxic components in water

    NARCIS (Netherlands)

    Stein, N.E.

    2011-01-01

    In a microbial fuel cell bacteria produce electricity. When water with a constant quality is lead passed the bacteria, a constant current will be measured. When toxic components enter the cell with the water, the bacteria are affected a

  12. Analyzing Carbohydrate-Based Regenerative Fuel Cells as a Power Source for Unmanned Aerial Vehicles

    Science.gov (United States)

    2008-03-01

    different researchers. As an example, one fuel cell was reported to have a 95% efficiency [ Weibel and Dodge, 1975] however, upon closer inspection...implants, in 19th IEEE International Conference on Mi- cro Electro Mechanical Systems, vol. 2006, pp. 934–937. Weibel , M. K., and C. Dodge (1975

  13. Homo- and heterofermentative lactobacilli differently affect sugarcane-based fuel ethanol fermentation

    Science.gov (United States)

    The antagonism between by yeast and lactobacilli is largely dependent on the initial population of each organism. While homo-fermentative lactobacillus present higher inhibitory effect upon yeast when in equal cell number, in industrial fuel ethanol conditions where high yeast cell densities prevail...

  14. Comparison of renewable fuels based on their land use using energy densities

    NARCIS (Netherlands)

    Dijkman, T. J.; Benders, R. M. J.

    2010-01-01

    In this article energy densities of selected renewable fuels are determined. Energy density is defined here as the annual energy production per hectare, taking energy inputs into account. Using 5 scenarios, consisting of 1 set focusing on technical differences and 1 set focusing on geographical vari

  15. Experimental hydrogen-fueled automotive engine design data-base project. Volume 2. Main technical report

    Energy Technology Data Exchange (ETDEWEB)

    Swain, M.R.; Adt, R.R. Jr.; Pappas, J.M.

    1983-05-01

    Operational performance and emissions characteristics of hydrogen-fueled engines are reviewed. The project activities are reviewed including descriptions of the test engine and its components, the test apparatus, experimental techniques, experiments performed and the results obtained. Analyses of other hydrogen engine project data are also presented and compared with the results of the present effort.

  16. Superheater fouling in a BFB boiler firing wood-based fuel blends

    NARCIS (Netherlands)

    Stam, A.F.; Haasnoot, K.; Brem, G.

    2014-01-01

    Four different fuel blends have been fired in a 28 MWel BFB. Wood pellets (test 0) were not problematic for about ten years, contrary to a mixture of demolition wood, wood cuttings, compost overflow, paper sludge and roadside grass (test 1) which caused excessive fouling at a superheater bundle afte

  17. Benchmarking Pt-based electrocatalysts for low temperature fuel cell reactions with the rotating disk electrode

    DEFF Research Database (Denmark)

    Pedersen, Christoffer Mølleskov; Escribano, Maria Escudero; Velazquez-Palenzuela, Amado Andres

    2015-01-01

    We present up-to-date benchmarking methods for testing electrocatalysts for polymer exchange membrane fuel cells (PEMFC), using the rotating disk electrode (RDE) method. We focus on the oxygen reduction reaction (ORR) and the hydrogen oxidation reaction (HOR) in the presence of CO. We have chosen...

  18. LIFE CYCLE BASED STUDIES ON BIOETHANOL FUEL FOR SUSTAINABLE TRANSPORTATION: A LITERATURE REVIEW

    Science.gov (United States)

    A literature search was conducted and revealed 45 publications (1996-2005) that compare bio-ethanol systems to conventional fuel on a life-cycle basis, or using life cycle assessment. Feedstocks, such as sugar beets, wheat, potato, sugar cane, and corn, have been investigated in...

  19. Biomass & Natural Gas Based Hydrogen Fuel For Gas Turbine (Power Generation)

    Science.gov (United States)

    Significant progress has been made by major power generation equipment manufacturers in the development of market applications for hydrogen fuel use in gas turbines in recent years. Development of a new application using gas turbines for significant reduction of power plant CO2 e...

  20. Low-temperature plasma synthesis of carbon nanotubes and graphene based materials and their fuel cell applications.

    Science.gov (United States)

    Wang, Qi; Wang, Xiangke; Chai, Zhifang; Hu, Wenping

    2013-12-07

    Carbon nanotubes (CNTs) and graphene, and materials based on these, are largely used in multidisciplinary fields. Many techniques have been put forward to synthesize them. Among all kinds of approaches, the low-temperature plasma approach is widely used due to its numerous advantages, such as highly distributed active species, reduced energy requirements, enhanced catalyst activation, shortened operation time and decreased environmental pollution. This tutorial review focuses on the recent development of plasma synthesis of CNTs and graphene based materials and their electrochemical application in fuel cells.

  1. Exceptional durability enhancement of PA/PBI based polymer electrolyte membrane fuel cells for high temperature operation at 200°C

    DEFF Research Database (Denmark)

    Aili, David; Zhang, Jin; Jakobsen, Mark Tonny Dalsgaard

    2016-01-01

    The incorporation of phosphotungstic acid functionalized mesoporous silica in phosphoric acid doped polybenzimidazole (PA/PBI) substantially enhances the durability of PA/PBI based polymer electrolyte membrane fuel cells for high temperature operation at 200°C.......The incorporation of phosphotungstic acid functionalized mesoporous silica in phosphoric acid doped polybenzimidazole (PA/PBI) substantially enhances the durability of PA/PBI based polymer electrolyte membrane fuel cells for high temperature operation at 200°C....

  2. 1986 fuel cell seminar: Program and abstracts

    Energy Technology Data Exchange (ETDEWEB)

    None

    1986-10-01

    Ninety nine brief papers are arranged under the following session headings: gas industry's 40 kw program, solid oxide fuel cell technology, phosphoric acid fuel cell technology, molten carbonate fuel cell technology, phosphoric acid fuel cell systems, power plants technology, fuel cell power plant designs, unconventional fuels, fuel cell application and economic assessments, and plans for commerical development. The papers are processed separately for the data base. (DLC)

  3. Performance of a microbial fuel cell-based biosensor for online monitoring in an integrated system combining microbial fuel cell and upflow anaerobic sludge bed reactor.

    Science.gov (United States)

    Jia, Hui; Yang, Guang; Wang, Jie; Ngo, Huu Hao; Guo, Wenshan; Zhang, Hongwei; Zhang, Xinbo

    2016-10-01

    A hybrid system integrating a microbial fuel cell (MFC)-based biosensor with upflow anaerobic sludge blanket (UASB) was investigated for real-time online monitoring of the internal operation of the UASB reactor. The features concerned were its rapidity and steadiness with a constant operation condition. In addition, the signal feedback mechanism was examined by the relationship between voltage and time point of changed COD concentration. The sensitivity of different concentrations was explored by comparing the signal feedback time point between the voltage and pH. Results showed that the electrical signal feedback was more sensitive than pH and the thresholds of sensitivity were S=3×10(-5)V/(mg/L) and S=8×10(-5)V/(mg/L) in different concentration ranges, respectively. Although only 0.94% of the influent COD was translated into electricity and applied for biosensing, this integrated system indicated great potential without additional COD consumption for real-time monitoring.

  4. Critical Analysis of Dry Storage Temperature Limits for Zircaloy-Clad Spent Nuclear Fuel Based on Diffusion Controlled Cavity Growth

    Energy Technology Data Exchange (ETDEWEB)

    Hayes, T.A.; Rosen, R.S.; Kassner, M.E.

    1999-12-01

    Interim dry storage of spent nuclear fuel (SNF) rods is of critical concern because a shortage of existing SNF wet storage capacity combined with delays in the availability of a permanent disposal repository has led to an increasing number of SNF rods being placed into interim dry storage. Safe interim dry storage must be maintained for a minimum of twenty years according to the Standard Review Plan for Dry Cask Storage Systems [1] and the Code of Federal Regulations, 10 CFR Part 72 [2]. Interim dry storage licensees must meet certain safety conditions when storing SNF rods to ensure that there is a ''very low probability (e.g. 0.5%) of cladding breach during long-term storage'' [1]. Commercial SNF typically consists of uranium oxide pellets surrounded by a thin cladding. The cladding is usually an {alpha}-zirconium based alloy know as ''Zircaloy''. In dry storage, the SNF rods are confined in one of several types of cask systems approved by the Nuclear Regulatory Commission (NRC). ''The cask system must be designed to prevent degradation of fuel cladding that results in a type of cladding breach, such as axial-splits or ductile fracture, where irradiated UO{sub 2} particles may be released. In addition, the fuel cladding should not degrade to the point where more than one percent of the fuel rods suffer pinhole or hairline crack type failure under normal storage conditions [1].'' The NRC has approved two models [3,4] for use by proposed dry storage licensees to determine the maximum initial temperature limit for nuclear fuel rods in dry storage that supposedly meet the above criteria and yield consistent temperature limits. Though these two models are based on the same fundamental failure theory, different assumptions have been made including the choice of values for material constants in the failure equation. This report will examine and compare the similarities and inconsistencies of these two models

  5. Visual examinations of K east fuel elements

    Energy Technology Data Exchange (ETDEWEB)

    Pitner, A.L., Fluor Daniel Hanford

    1997-02-03

    Selected fuel elements stored in both ``good fuel`` and ``bad fuel`` canisters in K East Basin were extracted and visually examined full length for damage. Lower end damage in the ``bad fuel`` canisters was found to be more severe than expected based on top end appearances. Lower end damage for the ``good fuel`` canisters, however, was less than expected based on top end observations. Since about half of the fuel in K East Basin is contained in ``good fuel`` canisters based on top end assessments, the fraction of fuel projected to be intact with respect to IPS processing considerations remains at 50% based on these examination results.

  6. Powered by technology or powering technology?---Belief-based decision-making in nuclear power and synthetic fuel

    Science.gov (United States)

    Yang, Chi-Jen

    The overarching question in this study is how and why technical-fixes in energy policy failed. In the post-WWII era, civilian nuclear power and synthetic fuel had both been top priorities on the U.S. national policy agenda during certain periods of time. Nuclear power was promoted and pursued persistently with great urgency for over two decades. In contrast, synthetic fuel policy suffered from boom-and-bust cycles. The juxtaposition of policy histories of nuclear power and synthetic fuel highlights many peculiarities in policymaking. The U.S. government forcefully and consistently endorsed the development of civilian nuclear power for two decades. It adopted policies to establish the competitiveness of civilian nuclear power far beyond what would have occurred under free-market conditions. Even though synthetic fuel was characterized by a similar level of economic potential and technical feasibility, the policy approach toward synthetic fuel was almost the opposite of nuclear power. Political support usually stopped when the development of synthetic fuel technology encountered economic difficulties. The contrast between the unfaltering faith in nuclear power and the indeterminate attitude toward synthetic fuel raises many important questions. I argue that these diverging paths of development can be explained by exploring the dominant government ideology of the time or "ideology of the state" as the sociology literature describes it. The price-determining approach was a result of government preoccupied with fighting the Cold War. The U.S. intentionally idealized and deified nuclear power to serve its Cold War psychological strategy. These psychological maneuverings attached important symbolic meaning to nuclear power. The society-wide enthusiasm and resulting bandwagon market are better understood by taking the role of symbolism in the political arena into account. On the other hand, a "welfare state" ideology that stood behind synthetic fuel was confused

  7. Fuel cells, batteries and super-capacitors stand-alone power systems management using optimal/flatness based-control

    Science.gov (United States)

    Benaouadj, M.; Aboubou, A.; Ayad, M. Y.; Bahri, M.; Boucetta, A.

    2016-07-01

    In this work, an optimal control (under constraints) based on the Pontryagin's maximum principle is used to optimally manage energy flows in a basic PEM (Proton Exchange Membrane) fuel cells system associated to lithium-ion batteries and supercapacitors through a common DC bus having a voltage to stabilize using the differential flatness approach. The adaptation of voltage levels between different sources and load is ensured by use of three DC-DC converters, one boost connected to the PEM fuel cells, while the two others are buck/boost and connected to the lithiumion batteries and supercapacitors. The aim of this paper is to develop an energy management strategy that is able to satisfy the following objectives: - Impose the power requested by a habitat (representing the load) according to a proposed daily consumption profile, - Keep fuel cells working at optimal power delivery conditions, - Maintain constant voltage across the common DC bus, - Stabilize the batteries voltage and stored quantity of charge at desired values given by the optimal control.Results obtained under MATLAB/Simulink environment prove that the cited objectives are satisfied, validating then, effectiveness and complementarity between the optimal and flatness concepts proposed for energy management. Note that this study is currently in experimentally validation within MSE Laboratory.

  8. Optimal/flatness based-control of stand-alone power systems using fuel cells, batteries and supercapacitors

    Directory of Open Access Journals (Sweden)

    Mahdi Benaouadj

    2017-03-01

    Full Text Available In this work, an optimal control (under constraints based on the Pontryagin’s maximum principle is used to optimally manage energy flows in a basic PEM (Proton Exchange Membrane fuel cells system associated to lithium-ion batteries and supercapacitors through a common DC bus having a voltage to stabilize using the differential flatness approach. The adaptation of voltage levels between different sources and load is ensured by use of three DCDC converters, one boost connected to the PEM fuel cells, while the two others are buck/boost and connected to the lithium-ion batteries and supercapacitors. The aim of this paper is to develop an energy management strategy that is able to satisfy the following objectives: - Impose the power requested by a habitat (representing the load according to a proposed daily consumption profile, - Keep fuel cells working at optimal power delivery conditions, - Maintain constant voltage across the common DC bus, - Stabilize the batteries voltage and stored quantity of charge at desired values given by the optimal control. Results obtained under MATLAB/Simulink environment prove that the cited objectives are satisfied, validating then effectiveness and complementarity between the optimal and flatness concepts proposed for energy management.

  9. A Silicon-Based Nanothin Film Solid Oxide Fuel Cell Array with Edge Reinforced Support for Enhanced Thermal Mechanical Stability.

    Science.gov (United States)

    Baek, Jong Dae; Yu, Chen-Chiang; Su, Pei-Chen

    2016-04-13

    A silicon-based micro-solid oxide fuel cell (μ-SOFC) with electrolyte membrane array embedded in a thin silicon supporting membrane, featuring a unique edge reinforcement structure, was demonstrated by utilizing simple silicon micromachining processes. The square silicon supporting membrane, fabricated by combining deep reactive ion etching and through-wafer wet etching processes, has thicker edges and corners than the center portion of the membrane, which effectively improved the mechanical stability of the entire fuel cell array during cell fabrication and cell operation. The 20 μm thick single crystalline silicon membrane supports a large number of 80 nm thick free-standing yttria-stabilized zirconia (YSZ) electrolytes. The fuel cell array was stably maintained at the open circuit voltage (OCV) of 1.04 V for more than 30 h of operation at 350 °C. A high peak power density of 317 mW/cm(2) was obtained at 400 °C. During a rigorous in situ thermal cycling between 150 and 400 °C at a fast cooling and heating rate of 25 °C/min, the OCV of the μ-SOFC recovered to its high value of 1.07 V without any drop caused by membrane failure, which justifies the superior thermal stability of this novel cell architecture.

  10. Development of advanced catalytic layer based on vertically aligned conductive polymer arrays for thin-film fuel cell electrodes

    Science.gov (United States)

    Jiang, Shangfeng; Yi, Baolian; Cao, Longsheng; Song, Wei; Zhao, Qing; Yu, Hongmei; Shao, Zhigang

    2016-10-01

    The degradation of carbon supports significantly influences the performance of proton exchange membrane fuel cells (PEMFCs), particularly in the cathode, which must be overcome for the wide application of fuel cells. In this study, advanced catalytic layer with electronic conductive polymer-polypyrrole (PPy) nanowire as ordered catalyst supports for PEMFCs is prepared. A platinum-palladium (PtPd) catalyst thin layer with whiskerette shapes forms along the long axis of the PPy nanowires. The resulting arrays are hot-pressed on both sides of a Nafion® membrane to construct a membrane electrode assembly (without additional ionomer). The ordered thin catalyst layer (approximately 1.1 μm) is applied in a single cell as the anode and the cathode without additional Nafion® ionomer. The single cell yields a maximum performance of 762.1 mW cm-2 with a low Pt loading (0.241 mg Pt cm-2, anode + cathode). The advanced catalyst layer indicates better mass transfer in high current density than that of commercial Pt/C-based electrode. The mass activity is 1.08-fold greater than that of DOE 2017 target. Thus, the as-prepared electrodes have the potential for application in fuel cells.

  11. EPRI fuel cladding integrity program

    Energy Technology Data Exchange (ETDEWEB)

    Yang, R. [Electric Power Research Institute, Palo Alto, CA (United States)

    1997-01-01

    The objectives of the EPRI fuel program is to supplement the fuel vendor research to assure that utility economic and operational interests are met. To accomplish such objectives, EPRI has conducted research and development efforts to (1) reduce fuel failure rates and mitigate the impact of fuel failures on plant operation, (2) provide technology to extend burnup and reduce fuel cycle cost. The scope of R&D includes fuel and cladding. In this paper, only R&D related to cladding integrity will be covered. Specific areas aimed at improving fuel cladding integrity include: (1) Fuel Reliability Data Base; (2) Operational Guidance for Defective Fuel; (3) Impact of Water Chemistry on Cladding Integrity; (4) Cladding Corrosion Data and Model; (5) Cladding Mechanical Properties; and (6) Transient Fuel Cladding Response.

  12. HTPEM Fuel Cell Impedance

    DEFF Research Database (Denmark)

    Vang, Jakob Rabjerg

    As part of the process to create a fossil free Denmark by 2050, there is a need for the development of new energy technologies with higher efficiencies than the current technologies. Fuel cells, that can generate electricity at higher efficiencies than conventional combustion engines, can...... potentially play an important role in the energy system of the future. One of the fuel cell technologies, that receives much attention from the Danish scientific community is high temperature proton exchange membrane (HTPEM) fuel cells based on polybenzimidazole (PBI) with phosphoric acid as proton conductor....... This type of fuel cell operates at higher temperature than comparable fuel cell types and they distinguish themselves by high CO tolerance. Platinum based catalysts have their efficiency reduced by CO and the effect is more pronounced at low temperature. This Ph.D. Thesis investigates this type of fuel...

  13. A Range-Based Vehicle Life Cycle Assessment Incorporating Variability in the Environmental Assessment of Different Vehicle Technologies and Fuels

    Directory of Open Access Journals (Sweden)

    Maarten Messagie

    2014-03-01

    Full Text Available How to compare the environmental performance of different vehicle technologies? Vehicles with lower tailpipe emissions are perceived as cleaner. However, does it make sense to look only to tailpipe emissions? Limiting the comparison only to these emissions denies the fact that there are emissions involved during the production of a fuel and this approach gives too much advantage to zero-tailpipe vehicles like battery electric vehicles (BEV and fuel cell electric vehicle (FCEV. Would it be enough to combine fuel production and tailpipe emissions? Especially when comparing the environmental performance of alternative vehicle technologies, the emissions during production of the specific components and their appropriate end-of-life treatment processes should also be taken into account. Therefore, the complete life cycle of the vehicle should be included in order to avoid problem shifting from one life stage to another. In this article, a full life cycle assessment (LCA of petrol, diesel, fuel cell electric (FCEV, compressed natural gas (CNG, liquefied petroleum gas (LPG, hybrid electric, battery electric (BEV, bio-diesel and bio-ethanol vehicles has been performed. The aim of the manuscript is to investigate the impact of the different vehicle technologies on the environment and to develop a range-based modeling system that enables a more robust interpretation of the LCA results for a group of vehicles. Results are shown for climate change, respiratory effects, acidification and mineral extraction damage of the different vehicle technologies. A broad range of results is obtained due to the variability within the car market. It is concluded that it is essential to take into account the influence of all the vehicle parameters on the LCA results.

  14. Spray combustion of biomass-based renewable diesel fuel using multiple injection strategy in a constant volume combustion chamber

    KAUST Repository

    Jing, Wei

    2016-05-26

    Effect of a two-injection strategy associated with a pilot injection on the spray combustion process was investigated under conventional diesel combustion conditions (1000 K and 21% O2 concentration) for a biomass-based renewable diesel fuel, i.e., biomass to liquid (BTL), and a regular No. 2 diesel in a constant volume combustion chamber using multiband flame measurement and two-color pyrometry. The spray combustion flame structure was visualized by using multiband flame measurement to show features of soot formation, high temperature and low temperature reactions, which can be characterized by the narrow-band emissions of radicals or intermediate species such as OH, HCHO, and CH. The objective of this study was to identify the details of multiple injection combustion, including a pilot and a main injection, and to provide further insights on how the two injections interact. For comparison, three injection strategies were considered for both fuels including a two-injection strategy (Case TI), single injection strategy A (Case SA), and single injection strategy B (Case SB). Multiband flame results show a strong interaction, indicated by OH emissions between the pilot injection and the main injection for Case TI while very weak connection is found for the narrow-band emissions acquired through filters with centerlines of 430 nm and 470 nm. A faster flame development is found for the main injection of Case TI compared to Cases SA and SB, which could be due to the high temperature environment and large air entrainment from the pilot injection. A lower soot level is observed for the BTL flame compared to the diesel flame for all three injection types. Case TI has a lower soot level compared to Cases SA and SB for the BTL fuel, while the diesel fuel maintains a similar soot level among all three injection strategies. Soot temperature of Case TI is lower for both fuels, especially for diesel. Based on these results, it is expected that the two-injection strategy could be

  15. Fuel cell based micro-combined heat and power under different policy frameworks - An economic analysis

    DEFF Research Database (Denmark)

    Hansen, Lise-Lotte Pade; Schröder, Sascha Thorsten

    2013-01-01

    political objectives on the design of the future energy system. This article takes the point of departure in the existing support schemes, most common ownership structures, energy prices, electricity demand and heating demand in Denmark, France and Portugal. For the three countries, we analyse different...... constellations of operational strategies, ownership structures and promotion schemes and assess the necessary support levels for residential fuel cells under these constellations. We find that the necessary support levels are not excessively high compared to the initial support levels for e.g. photovoltaic...... systems in Germany. Especially net metering in Denmark and price premiums for fuel cells functioning as a virtual power plant in France and Portugal seems promising. The annual number of operation hours depends strongly on the operational scheme. For thermal-led units, cold start and modulation capacity...

  16. An Equivalent Electrical Circuit Model of Proton Exchange Membrane Fuel Cells Based on Mathematical Modelling

    Directory of Open Access Journals (Sweden)

    Dinh An Nguyen

    2012-07-01

    Full Text Available Many of the Proton Exchange Membrane Fuel Cell (PEMFC models proposed in the literature consist of mathematical equations. However, they are not adequately practical for simulating power systems. The proposed model takes into account phenomena such as activation polarization, ohmic polarization, double layer capacitance and mass transport effects present in a PEM fuel cell. Using electrical analogies and a mathematical modeling of PEMFC, the circuit model is established. To evaluate the effectiveness of the circuit model, its static and dynamic performances under load step changes are simulated and compared to the numerical results obtained by solving the mathematical model. Finally, the applicability of our model is demonstrated by simulating a practical system.

  17. Social impact theory based modeling for security analysis in the nuclear fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Woo, Tae Ho [Systemix Global Co. Ltd., Seoul (Korea, Republic of)

    2015-03-15

    The nuclear fuel cycle is investigated for the perspective of the nuclear non-proliferation. The random number generation of the Monte-Carlo method is utilized for the analysis. Five cases are quantified by the random number generations. These values are summed by the described equations. The higher values are shown in 52{sup nd} and 73{sup rd} months. This way could be a useful obligation in the license of the plant construction. The security of the nuclear fuel cycle incorporated with nuclear power plants (NPPs) is investigated using social impact theory. The dynamic quantification of the theory shows the non-secured time for act of terrorism which is considered for the non-secured condition against the risk of theft in nuclear material. For a realistic consideration, the meta-theoretical framework for modeling is performed for situations where beliefs, attributes or behaviors of an individual are influenced by those of others.

  18. Microbial Fuel Cells Applied to the Metabolically-Based Detection of Extraterrestrial Life

    CERN Document Server

    Abrevaya, Ximena C; Cortón, Eduardo

    2010-01-01

    Since the 1970's, when the Viking spacecrafts carried out experiments aimed to the detection of microbial metabolism on the surface of Mars, the search for nonspecific methods to detect life in situ has been one of the goals of astrobiology. It is usually required that the methodology can detect life independently from its composition or form, and that the chosen biological signature points to a feature common to all living systems, as the presence of metabolism. In this paper we evaluate the use of Microbial Fuel Cells (MFCs) for the detection of microbial life in situ. MFCs are electrochemical devices originally developed as power electrical sources, and can be described as fuel cells in which the anode is submerged in a medium that contains microorganisms. These microorganisms, as part of their metabolic process, oxidize organic material releasing electrons that contribute to the electric current, which is therefore proportional to metabolic and other redox processes. We show that power and current density...

  19. Nanocomposite Membranes based on Perlfuorosulfonic Acid/Ceramic for Proton Exchange Membrane Fuel Cells

    Institute of Scientific and Technical Information of China (English)

    LI Qiong; WANG Guangjin; YE Hong; YAN Shilin

    2015-01-01

    Perlfuorosulfonic acid/ceramic nanocomposite membranes were investigated as electrolytes for polymer electrolyte membrane fuel cell applications under low relative humidity. Different nanosized ceramics (SiO2, ZrO2, TiO2) with diameters in the range of 2-6 nm were synthesized in situ in Nafion solution through a sol-gel process and the formed nanosized ceramics were well-dispersed in the solution. The nanocomposite membranes were formed through a casting process. The nanocomposite membrane showes enhanced water retention ability and improved proton conductivity compared to those of pure Naifon membrane. The mechanical strength of the formed nanocomposite membranes is slightly less than that of pure Naifon membrane. The experimental results demonstrate that the polymer ceramic nanocompsite membranes are potential electrolyte for fuel cells operating at elevated temperature.

  20. Continuous Fuel Level Sensor Based on Spiral Side-Emitting Optical Fiber

    Directory of Open Access Journals (Sweden)

    Chengrui Zhao

    2012-01-01

    Full Text Available A continuous fuel level sensor using a side-emitting optical fiber is introduced in this paper. This sensor operates on the modulation of the light intensity in fiber, which is caused by the cladding’s acceptance angle change when it is immersed in fuel. The fiber is bent as a spiral shape to increase the sensor’s sensitivity by increasing the attenuation coefficient and fiber’s submerged length compared to liquid level. The attenuation coefficients of fiber with different bent radiuses in the air and water are acquired through experiments. The fiber is designed as a spiral shape with a steadily changing slope, and its response to water level is simulated. The experimental results taken in water and aviation kerosene demonstrate a performance of 0.9 m range and 10 mm resolution.

  1. Exergy Analysis of Gas Turbine – Fuel cell based combined Cycle Power Plant

    Directory of Open Access Journals (Sweden)

    M.Sreeramulu,

    2011-06-01

    Full Text Available The increase in demand for electrical energy leads to the newer power generation systems. Though it is not new, fuel cell technology is one of the promising systems for cleaner and competitive alternate power generation system. When the fuel cells are integrated with the Gas Turbines, the total thermal efficiency of the combined cycle is obtained greater than 60%. In this paper, thermodynamic analysis of SOFC-GT combined system (2.898MW has been carried out, exergy efficiency and exergy destruction of each component are calculated.The effect of compression ratio (rp, turbine inlet temperature (TIT and ambient temperature of air, on the performance of the system has been analyzed. Outcome of the system modeling reveals that SOFC andcombustion chamber are the main sources of exergy destruction. At the optimum compression ratio 9, the total thermal efficiency and exergy efficiency are found to be 63.3% and 60.85% respectively.

  2. Polymer electrolyte membrane fuel cells based on Nafion and acid-doped PBI:state-of-the-art and recent progress

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Based on perfluorosulfonic acid polymer membranes (PFSA,e.g.Nafion),polymer electrolyte membrane fuel cells (PEMFC) operate with hydrogen or purified reformate gas due to the strong poisoning effect of fuel impurities.Consequently,a complicated fuel storage or fuel processing system is needed.Direct methanol fuel cells,on the other hand,suffer from slow anodic kinetics and therefore low power density.The newest technology in the field is the development of temperature-resistant polymer membranes for operation at temperatures higher than 100°C.The high temperature PEMFC exhibits performance compatible with PFSA-based PEM fuel cell but can tolerate up to 3 %(volume fraction) carbon monoxide.The high CO tolerance makes it possible to use the reformed hydrogen directly from a simple methanol reformer without further CO removal.This opens possibility for an integrated reformer-fuel cell system,which is expected to exhibit high power density and simple construction as well as efficient capital and operational cost.

  3. Intermediate temperature fuel cells based on proton conducting electrolytes. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Duval, S.; Holtappels, P.

    2006-03-15

    Solid oxide proton conductors can offer a new intermediate temperature fuel cell technology combining the advantages of polymeric fuel cells and solid oxide fuel cells. Among potential proton conductor materials, Y-doped barium zirconate (BZY) was found to be a promising candidate. This material was synthesised and characterised at EMPA. The synthesis study shows the possibility to use up scalable methods to produce BZY. It was demonstrated that BZY can take up protons and that the protons are the mobile charge carriers that dominate the conductivity. The conductivity of the grain interior (log {sigma} {approx} -3 S.cm{sup -1} at 300 {sup o}C) competes with the conductivity of the best proton conductors. A correlation between the bulk conductivity and the cubic lattice parameter was observed. It was found that controlling the lattice parameter during the synthesis enable to tune the conductivity. The total conductivity of the test material was found to be dominated by the large resistive grain boundary contribution. Neither a clear microstructure/conductivity relationship could be identified nor could be found a blocking secondary phase. Only an exceptional thermal treatment (annealing up to 2200 {sup o}C) showed an improvement of the grain boundary conductivity. A first interpretation presumes an electronic effect arising from the shearing of crystallographic planes that depresses either the proton concentration or the proton mobility in the vicinity of the grain boundaries (i.e. in the so-called 'space charge region'). Consequences for the further development of BZY for fuel cell application are discussed. (author)

  4. The Department of Defense: Reducing Its Reliance on Fossil-Based Aviation Fuel - Issues for Congress

    Science.gov (United States)

    2007-06-15

    19 Figure 2. KC-135 Winglet Flight Tests at Dryden Flight Research Center . . . . 23 List of Tables Table 1...involving two or more opposing forces using rules, data, and procedures designed to depict an actual or assumed real life situation.” 19 Winglets , for...applying winglets to DOD aircraft. See page 24 of this report for further information. reflect the DOD’s true fuel costs, masks energy efficiency

  5. Economic potential of biomass based fuels for greenhouse gas emission mitigation

    OpenAIRE

    U. Schneider; McCarl, Bruce A.

    2003-01-01

    Use of biofuels diminishes fossil fuel combustion, thereby also reducing net greenhouse gas emissions. However, subsidies are needed to make agricultural biofuel production economically feasible. To explore the economic potential of biofuels in a greenhouse gas mitigation market, the authors incorporate data on production and biofuel processing for the designated energy crops--switchgrass, hybrid poplar, and willow--in a U.S. Agricultural Sector Model, along with data on traditional crop-live...

  6. A Literature Survey and Data Base Assessment: Microbial Fate of Diesel Fuel and Fog Oils,

    Science.gov (United States)

    1986-04-01

    were mostly aerobic NocardLa species and fungi. Cladosporum resinae , which has been repeatedly found as a contaminant of jet fuels and has been...1,13 2 Glucose metabolism is subject to inhibition or repression by hydrocarbon in a Candida strain 1 3 3 and Cladosporium resinae .1 3 ,1 5 Microbial...microorganisms isolated from soil. Can. J. Microbiol. 14:403. 93. Cooney, J.J. and J.D. Walker. 1973. Hydrocarbon utilization by Cladosporium resinae

  7. Proton Exchange Membrane Fuel Cell Modeling Based on Seeker Optimization Algorithm

    Institute of Scientific and Technical Information of China (English)

    LI Qi; DAI Chao-hua; Chen Wei-rong; JIA Jun-bo; HAN Ming

    2008-01-01

    Seeker optimization algorithm (SOA) has applications in continuous space of swarm intelligence. In the fields of proton ex-change membrane fuel cell (PEMFC) modeling, SOA was proposed to research a set of optimized parameters in PEMFC polariza-tion curve model. Experimental result showed that the mean square error of the optimization modeling strategy was only 6.9 × 10-23. Hence, the optimization model could fit the experiment data with high precision.

  8. The Effects of Amine Based Missile Fuels on the Activated Sludge Process.

    Science.gov (United States)

    1979-10-01

    the 347 mg/i measured COD can be attributed to the fuel itself. Using semibatch reactor kinetics, it is possible to calculate the effluent COD given the...Specific Substrate Utilization as a Function of Substrate Concentration, 140nod Plot .. ............ 3 2 Completely Mixed Reactor with Cellular...Residence Time .. ........... 13 5 Laboratory Schematic......................16 6 Mixing Chamber Used to Achieve C1 in Reactors 1 to 4, C2 in Reactors 9 to

  9. Hybrid microfluidic fuel cell based on Laccase/C and AuAg/C electrodes.

    Science.gov (United States)

    López-González, B; Dector, A; Cuevas-Muñiz, F M; Arjona, N; Cruz-Madrid, C; Arana-Cuenca, A; Guerra-Balcázar, M; Arriaga, L G; Ledesma-García, J

    2014-12-15

    A hybrid glucose microfluidic fuel cell composed of an enzymatic cathode (Laccase/ABTS/C) and an inorganic anode (AuAg/C) was developed and tested. The enzymatic cathode was prepared by adsorption of 2,2'-Azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) and Laccase on Vulcan XC-72, which act as a redox mediator, enzymatic catalyst and support, respectively. The Laccase/ABTS/C composite was characterised by Fourier Transform Infrared (FTIR) Spectroscopy, streaming current measurements (Zeta potential) and cyclic voltammetry. The AuAg/C anode catalyst was characterised by Transmission electron microscopy (TEM) and cyclic voltammetry. The hybrid microfluidic fuel cell exhibited excellent performance with a maximum power density value (i.e., 0.45 mW cm(-2)) that is the highest reported to date. The cell also exhibited acceptable stability over the course of several days. In addition, a Mexican endemic Laccase was used as the biocathode electrode and evaluated in the hybrid microfluidic fuel cell generating 0.5 mW cm(-2) of maximum power density.

  10. Extractive Deep Desulfurization of Liquid Fuels Using Lewis-Based Ionic Liquids

    Directory of Open Access Journals (Sweden)

    Swapnil A. Dharaskar

    2013-01-01

    Full Text Available A new class of green solvents, known as ionic liquids (ILs, has recently been the subject of intensive research on the extractive desulfurization of liquid fuels because of the limitation of traditional hydrodesulfurization method. In present work, eleven Lewis acid ionic liquids were synthesized and employed as promising extractants for deep desulfurization of the liquid fuel containing dibenzothiophene (DBT to test the desulfurization efficiency. [Bmim]Cl/FeCl3 was the most promising ionic liquid and performed the best among studied ionic liquids under the same operating conditions. It can remove dibenzothiophene from the model liquid fuel in the single-stage extraction process with the maximum desulfurization efficiency of 75.6%. It was also found that [Bmim]Cl/FeCl3 may be reused without regeneration with considerable extraction efficiency of 47.3%. Huge saving on energy can be achieved if we make use of this ionic liquids behavior in process design, instead of regenerating ionic liquids after every time of extraction.

  11. Evaluation of single and stack membraneless enzymatic fuel cells based on ethanol in simulated body fluids.

    Science.gov (United States)

    Galindo-de-la-Rosa, J; Arjona, N; Moreno-Zuria, A; Ortiz-Ortega, E; Guerra-Balcázar, M; Ledesma-García, J; Arriaga, L G

    2017-02-08

    The purpose of this work is to evaluate single and double-cell membraneless microfluidic fuel cells (MMFCs) that operate in the presence of simulated body fluids SBF, human serum and blood enriched with ethanol as fuels. The study was performed using the alcohol dehydrogenase enzyme immobilised by covalent binding through an array composed of carbon Toray paper as support and a layer of poly(methylene blue)/tetrabutylammonium bromide/Nafion and glutaraldehyde (3D bioanode electrode). The single MMFC was tested in a hybrid microfluidic fuel cell using Pt/C as the cathode. A cell voltage of 1.035V and power density of 3.154mWcm(-2) were observed, which is the highest performance reported to date. The stability and durability were tested through chronoamperometry and polarisation/performance curves obtained at different days, which demonstrated a slow decrease in the power density on day 10 (14%) and day 20 (26%). Additionally, the cell was tested for ethanol oxidation in simulated body fluid (SBF) with ionic composition similar to human blood plasma. Those tests resulted in 0.93V of cell voltage and a power density close to 1.237mWcm(-2). The double cell MMFC (Stack) was tested using serum and human blood enriched with ethanol. The stack operated with blood in a serial connection showed an excellent cell performance (0.716mWcm(-2)), demonstrating the feasibility of employing human blood as energy source.

  12. Effect of Fuel Content and Particle Size Distribution of Oxidiser on Ignition of Metal-Based Pyrotechnic Compositions

    Directory of Open Access Journals (Sweden)

    A. G. Dugam

    1999-07-01

    Full Text Available Influence of boron content in boron-based pyrotechnic composition and particle size distribution of oxidiser, i.e., KNO3 in boron-based pyrotechnic composition is examined by subjecting these to various tests. Study on boron-based pyrotechnic compositions reveals that compositions with 20, 25 and 30 parts by weight of boron are promising igniter compositions wrt their calorimetric values, pressure maximum, ignition delay, etc. However, from sensitivity point of view, the composition with 30 parts of boron is more safe to handle, manufacture and use. From the study of particle size distribution of KNO3 in Mg- based pyrotechnic compositions, it is observed that the composition with wider particle size distribution of oxidiser gives better packing density for their binary miJQ with metal fuel, which in turn gives lower ignition delay and ignition temperature.

  13. Adaptive Passivity-Based Control of PEM Fuel Cell/Battery Hybrid Power Source for Stand-Alone Applications

    Directory of Open Access Journals (Sweden)

    KALANTAR, A.

    2010-11-01

    Full Text Available In this paper, a DC hybrid power source composed of PEM fuel cell as main source, Li-ion battery storage as transient power source and their power electronic interfacing is modelled based on Euler-Lagrange framework. Subsequently, adaptive passivity-based controllers are synthesized using the energy shaping and damping injection technique. Local asymptotic stability is insured as well. In addition, the power management system is designed in order to manage power flow between components. Evaluation of the proposed system and simulation of the hybrid system are accomplished using MATLAB/Simulink. Afterwards, linear PI controllers are provided for the purpose of comparison with proposed controllers responses. The results show that the outputs of hybrid system based on adaptive passivity-based controllers have a good tracking response, low overshoot, short settling time and zero steady-state error. The comparison of results demonstrates the robustness of the proposed controllers for reference DC voltage and resistive load changes.

  14. Support schemes and ownership structures - The policy context for fuel cell based micro-combined heat and power

    Energy Technology Data Exchange (ETDEWEB)

    Ropenus, S.; Thorsten Schroeder, S.; Costa, A.; Obe, E.

    2010-05-15

    In recent years, fuel cell based micro-combined heat and power has received increasing attention due to its potential contribution to energy savings, efficiency gains, customer proximity and flexibility in operation and capacity size. The FC4Home project assesses technical and economic aspects of the ongoing fuel cell based micro-combined heat and power (mCHP) demonstration projects by addressing the socio-economic and systems analyses perspectives of a large-scale promotion scheme of fuel cells. This document constitutes the deliverable of Work Package 1 of the FC4Home project and provides an introduction to the policy context for mCHP. Section 1 describes the rationale for the promotion of mCHP by explaining its potential contribution to European energy policy goals. Section 2 addresses the policy context at the supranational European level by outlining relevant EU Directives on support schemes for promoting combined heat and power and energy from renewable sources. These Directives are to be implemented at the national level by the Member States. Section 3 conceptually presents the spectrum of national support schemes, ranging from investment support to market-based operational support. The choice of support scheme simultaneously affects risk and technological development, which is the focus of Section 4. Subsequent to this conceptual overview, Section 5 takes a glance at the national application of support schemes for mCHP in practice, notably in the three country cases of the FC4Home project, Denmark, France and Portugal. Another crucial aspect for the diffusion of the mCHP technology is possible ownership structures. These may range from full consumer ownership to ownership by utilities and energy service companies, which is discussed in Section 6. Finally, a conclusion (Section 7) wraps up previous findings and provides a short 'preview' of the quantitative analyses in subsequent Work Packages by giving some food for thought on the way. (author)

  15. PEM Fuel Cells - Fundamentals, Modeling and Applications

    Directory of Open Access Journals (Sweden)

    Maher A.R. Sadiq Al-Baghdadi

    2013-01-01

    Full Text Available Part I: Fundamentals Chapter 1: Introduction. Chapter 2: PEM fuel cell thermodynamics, electrochemistry, and performance. Chapter 3: PEM fuel cell components. Chapter 4: PEM fuel cell failure modes. Part II: Modeling and Simulation Chapter 5: PEM fuel cell models based on semi-empirical simulation. Chapter 6: PEM fuel cell models based on computational fluid dynamics. Part III: Applications Chapter 7: PEM fuel cell system design and applications.

  16. Computer model for refinery operations with emphasis on jet fuel production. Volume 2: Data and technical bases

    Science.gov (United States)

    Dunbar, D. N.; Tunnah, B. G.

    1978-01-01

    The FORTRAN computing program predicts the flow streams and material, energy, and economic balances of a typical petroleum refinery, with particular emphasis on production of aviation turbine fuel of varying end point and hydrogen content specifications. The program has provision for shale oil and coal oil in addition to petroleum crudes. A case study feature permits dependent cases to be run for parametric or optimization studies by input of only the variables which are changed from the base case. The report has sufficient detail for the information of most readers.

  17. Microstructure and Wear Properties of Fe-based Amorphous Coatings Deposited by High-velocity Oxygen Fuel Spraying

    Institute of Scientific and Technical Information of China (English)

    Gang WANG; Ping XIAO; Zhong-jia HUANG; Ru-jie HE

    2016-01-01

    Fe-based powder with a composition of Fe42·87 Cr15·98 Mo16·33 C15·94 B8·88 (at·%)was used to fabricate coatings by high-velocity oxygen fuel spraying.The effects of the spraying parameters on the microstructure and the wear properties of the Fe-based alloy coatings were systematically studied.The results showed that the obtained Fe-based coatings with a thickness of about 400μm consisted of a large-volume amorphous phase and some nanocrystals.With increasing the fuel and oxygen flow rates,the porosity of the obtained coatings decreased.The coating deposited un-der optimized parameters exhibited the lowest porosity of 2·8%.The excellent wear resistance of this coating was at-tributed to the properties of the amorphous matrix and the presence of nanocrystals homogeneously distributed with-in the matrix.The wear mechanism of the coatings was discussed on the basis of observations of the worn surfaces.

  18. Emissions from a Diesel Engine using Fe-based Fuel Additives and a Sintered Metal Filtration System.

    Science.gov (United States)

    Bugarski, Aleksandar D; Hummer, Jon A; Stachulak, Jozef S; Miller, Arthur; Patts, Larry D; Cauda, Emanuele G

    2016-03-01

    A series of laboratory tests were conducted to assess the effects of Fe-containing fuel additives on aerosols emitted by a diesel engine retrofitted with a sintered metal filter (SMF) system. Emission measurements performed upstream and downstream of the SMF system were compared, for cases when the engine was fueled with neat ultralow sulfur diesel (ULSD) and with ULSD treated with two formulations of additives containing Fe-based catalysts. The effects were assessed for four steady-state engine operating conditions and one transient cycle. The results showed that the SMF system reduced the average total number and surface area concentrations of aerosols by more than 100-fold. The total mass and elemental carbon results confirmed that the SMF system was indeed very effective in the removal of diesel aerosols. When added at the recommended concentrations (30 p.p.m. of iron), the tested additives had minor adverse impacts on the number, surface area, and mass concentrations of filter-out (FOut) aerosols. For one of the test cases, the additives may have contributed to measurable concentrations of engine-out (EOut) nucleation mode aerosols. The additives had only a minor impact on the concentration and size distribution of volatile and semi-volatile FOut aerosols. Metal analysis showed that the introduction of Fe with the additives substantially increased Fe concentration in the EOut, but the SMF system was effective in removal of Fe-containing aerosols. The FOut Fe concentrations for all three tested fuels were found to be much lower than the corresponding EOut Fe concentrations for the case of untreated ULSD fuel. The results support recommendations that these additives should not be used in diesel engines unless they are equipped with exhaust filtration systems. Since the tested SMF system was found to be very efficient in removing Fe introduced by the additives, the use of these additives should not result in a measurable increase in emissions of de novo generated

  19. A PHYSIOLOGICALLY BASED PHARMACOKINETIC/PHARMACODYNAMIC (PBPK/PD) MODEL FOR ESTIMATION OF CUMULATIVE RISK FROM EXPOSURE TO THREE N-METHYL CARBAMATES: CARBARYL, ALDICARB, AND CARBOFURAN

    Science.gov (United States)

    A physiologically-based pharmacokinetic (PBPK) model for a mixture of N-methyl carbamate pesticides was developed based on single chemical models. The model was used to compare urinary metabolite concentrations to levels from National Health and Nutrition Examination Survey (NHA...

  20. Combustion Simulation and Quick-freeze Observation of a Cupola-furnace Process Using a Bio-coke Fuel Based on Tea Scum

    Science.gov (United States)

    Ishii, Kazuyoshi; Murata, Hirotoshi; Kuwana, Kazunori; Mizuno, Satoru; Morita, Akihiro; Ida, Tamio

    Global environment problems have become more and more serious in recent years, and reduction of greenhouse gas emission based on Kyoto Protocol adopted at the 3rd conference of the parties of the United nations Framework Convention on Climate Change (COP3); securement of primary energy source and development of clean and renewable energy sources have been pressingly needed in consideration of the predicted depletion of fossil fuel in the future. In this study, we explore the use of a solidified biomass-derived fuel, having the maximum compressive strength of 100MPa and calorific value of 21MJ/kg, in iron-casting or iron-making processes as an alternative fuel to be mixed with coal coke. This study, carried out for internal observation using a quick-freeze technique, observed an actual working cupola furnace under the 20% alternative coal coke operation condition. After quick freeze of the cupola furnace, the solidified biomass fuel was found to inhabit near the iron-melting zone. Especially, this solidified biomass fuel smoothly changes carbonized fuel through high-density state during the operating process. On the other hand, this study tried to simulate gasification combustion under a high temperature environment instead of actual internal combustion of solidified biomass fuel. These combustion mechanisms were confirmed to be similar to diffusion-flame phenomena in general.