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Sample records for basalt

  1. Why Hexagonal Basalt Columns?

    Science.gov (United States)

    Hofmann, Martin; Anderssohn, Robert; Bahr, Hans-Achim; Weiß, Hans-Jürgen; Nellesen, Jens

    2015-10-01

    Basalt columns with their preferably hexagonal cross sections are a fascinating example of pattern formation by crack propagation. Junctions of three propagating crack faces rearrange such that the initial right angles between them tend to approach 120°, which enables the cracks to form a pattern of regular hexagons. To promote understanding of the path on which the ideal configuration can be reached, two periodically repeatable models are presented here involving linear elastic fracture mechanics and applying the principle of maximum energy release rate. They describe the evolution of the crack pattern as a transition from rectangular start configuration to the hexagonal pattern. This is done analytically and by means of three-dimensional finite element simulation. The latter technique reproduces the curved crack path involved in this transition.

  2. Hanford basalt flow mineralogy

    International Nuclear Information System (INIS)

    Mineralogy of the core samples from five core wells was examined in some detail. The primary mineralogy study included an optical examination of polished mounts, photomicrographs, chemical analyses of feldspars, pyroxenes, metallic oxides and microcrystalline groundmasses and determination from the chemical analyses of the varieties of feldspars, pyroxenes and metallic oxides. From the primary mineralogy data, a firm understanding of the average Hanford basalt flow primary mineralogy emerged. The average primary feldspar was a laboradorite, the average pyroxene was an augite and the average metallic oxide was a solid solution of ilmenite and magnetite. Secondary mineralization consisted of vug filling and joint coating, chiefly with a nontronite-beidellite clay, several zeolites, quartz, calcite, and opal. Specific flow units also were examined to determine the possibility of using the mineralogy to trace flows between core wells. These included units of the Pomona, the Umatilla and a high chromium flow just below the Huntzinger. In the Umatilla, or high barium flow, the compositional variation of the feldspars was unique in range. The pyroxenes in the Pomona were relatively highly zoned and accumulated chromium. The high chromium flow contained chromium spinels that graded in chromium content into simple magnetites very low in chromium content. A study of the statistical relationships of flow unit chemical constituents showed that flow unit constituents could be roughly correlated between wells. The probable cause of the correlation was on-going physical-chemical changes in the source magma

  3. Bubble Growth in Lunar Basalts

    Science.gov (United States)

    Zhang, Y.

    2009-05-01

    Although Moon is usually said to be volatile-"free", lunar basalts are often vesicular with mm-size bubbles. The vesicular nature of the lunar basalts suggests that they contained some initial gas concentration. A recent publication estimated volatile concentrations in lunar basalts (Saal et al. 2008). This report investigates bubble growth on Moon and compares with that on Earth. Under conditions relevant to lunar basalts, bubble growth in a finite melt shell (i.e., growth of multiple regularly-spaced bubbles) is calculated following Proussevitch and Sahagian (1998) and Liu and Zhang (2000). Initial H2O content of 700 ppm (Saal et al. 2008) or lower is used and the effect of other volatiles (such as carbon dioxide, halogens, and sulfur) is ignored. H2O solubility at low pressures (Liu et al. 2005), concentration-dependent diffusivity in basalt (Zhang and Stolper 1991), and lunar basalt viscosity (Murase and McBirney 1970) are used. Because lunar atmospheric pressure is essentially zero, the confining pressure on bubbles is completely supplied by the overlying magma. Due to low H2O content in lunar basaltic melt (700 ppm H2O corresponds to a saturation pressure of 75 kPa), H2O bubbles only grow in the upper 16 m of a basalt flow or lake. A depth of 20 mm corresponds to a confining pressure of 100 Pa. Hence, vesicular lunar rocks come from very shallow depth. Some findings from the modeling are as follows. (a) Due to low confining pressure as well as low viscosity, even though volatile concentration is very low, bubble growth rate is extremely high, much higher than typical bubble growth rates in terrestrial melts. Hence, mm-size bubbles in lunar basalts are not strange. (b) Because the pertinent pressures are so low, bubble pressure due to surface tension plays a main role in lunar bubble growth, contrary to terrestrial cases. (c) Time scale to reach equilibrium bubble size increases as the confining pressure increases. References: (1) Liu Y, Zhang YX (2000) Earth

  4. Strength of Concrete Containing Basalt Fibre

    Directory of Open Access Journals (Sweden)

    Parvez Imraan Ansari

    2015-04-01

    Full Text Available This paper presents the comparative study of effect of basalt fibre on compressive and split tensile strength of M40 grade concrete. The basalt fibre was mixed in concrete by (0.5%, 1%, and 1.5% of its total weight of cement in concrete. Results indicated that the strength increases with increase of basalt fibre content up to 1.0% beyond that there is a reduction in strength on increasing basalt fibre. The results show that the concrete specimen with 1.0% of basalt fibre gives better performance when it compared with 0.5%and 1.5% basalt fibre mix in concrete specimens.

  5. Radiation shielding concrete made of Basalt aggregates.

    Science.gov (United States)

    Alhajali, S; Yousef, S; Kanbour, M; Naoum, B

    2013-04-01

    In spite of the fact that Basalt is a widespread type of rock, there is very little available information on using it as aggregates for concrete radiation shielding. This paper investigates the possibility of using Basalt for the aforementioned purpose. The results have shown that Basalt could be used successfully for preparing radiation shielding concrete, but some attention should be paid to the choice of the suitable types of Basalt and for the neutron activation problem that could arise in the concrete shield.

  6. Temperature dependence of basalt weathering

    Science.gov (United States)

    Li, Gaojun; Hartmann, Jens; Derry, Louis A.; West, A. Joshua; You, Chen-Feng; Long, Xiaoyong; Zhan, Tao; Li, Laifeng; Li, Gen; Qiu, Wenhong; Li, Tao; Liu, Lianwen; Chen, Yang; Ji, Junfeng; Zhao, Liang; Chen, Jun

    2016-06-01

    The homeostatic balance of Earth's long-term carbon cycle and the equable state of Earth's climate are maintained by negative feedbacks between the levels of atmospheric CO2 and the chemical weathering rate of silicate rocks. Though clearly demonstrated by well-controlled laboratory dissolution experiments, the temperature dependence of silicate weathering rates, hypothesized to play a central role in these weathering feedbacks, has been difficult to quantify clearly in natural settings at landscape scale. By compiling data from basaltic catchments worldwide and considering only inactive volcanic fields (IVFs), here we show that the rate of CO2 consumption associated with the weathering of basaltic rocks is strongly correlated with mean annual temperature (MAT) as predicted by chemical kinetics. Relations between temperature and CO2 consumption rate for active volcanic fields (AVFs) are complicated by other factors such as eruption age, hydrothermal activity, and hydrological complexities. On the basis of this updated data compilation we are not able to distinguish whether or not there is a significant runoff control on basalt weathering rates. Nonetheless, the simple temperature control as observed in this global dataset implies that basalt weathering could be an effective mechanism for Earth to modulate long-term carbon cycle perturbations.

  7. Characterization of reference Umtanum and Cohassett basalt

    Energy Technology Data Exchange (ETDEWEB)

    Allen, C.C.; Johnston, R.G.; Strope, M.B.

    1985-02-01

    The Basalt Waste Isolation Project (BWIP) Materials Testing Group (MTG) provides large quantities of reference basalt for testing waste package materials under repository conditions, site sorption characteristics and other experimental purposes. This document describes the reference rock materials currently used in testing, namely entablature and colonnade basalt from the Umtanum and Cohassett flows. The data include sampling locations, bulk chemical composition, modal percentages of major phases, and the chemical and mineralogical compositions of these phases. 8 refs., 17 figs., 15 tabs.

  8. The Use of Basalt, Basalt Fibers and Modified Graphite for Nuclear Waste Repository - 12150

    Energy Technology Data Exchange (ETDEWEB)

    Gulik, V.I. [Institute for Nuclear Research, pr. Nauky 47, Kyiv, 03680 (Ukraine); Biland, A.B. [HHK Technologies, 3535 Wilcreast Dr., Houston TX 77042 (United States)

    2012-07-01

    New materials enhancing the isolation of radioactive waste and spent nuclear fuel are continuously being developed.. Our research suggests that basalt-based materials, including basalt roving chopped basalt fiber strands, basalt composite rebar and materials based on modified graphite, could be used for enhancing radioactive waste isolation during the storage and disposal phases and maintaining it during a significant portion of the post-closure phase. The basalt vitrification process of nuclear waste is a viable alternative to glass vitrification. Basalt roving, chopped basalt fiber strands and basalt composite rebars can significantly increase the strength and safety characteristics of nuclear waste and spent nuclear fuel storages. Materials based on MG are optimal waterproofing materials for nuclear waste containers. (authors)

  9. Subseafloor basalts as fungal habitats

    Science.gov (United States)

    Ivarsson, M.; Bengtson, S.

    2013-12-01

    The oceanic crust makes up the largest potential habitat for life on Earth, yet next to nothing is known about the abundance, diversity and ecology of its biosphere. Our understanding of the deep biosphere of subseafloor crust is, with a few exceptions, based on a fossil record. Surprisingly, a majority of the fossilized microorganisms have been interpreted or recently re-interpreted as remnants of fungi rather than prokaryotes. Even though this might be due to a bias in fossilization the presence of fungi in these settings can not be neglected. We have examined fossilized microorganisms in drilled basalt samples collected at the Emperor Seamounts in the Pacific Ocean. Synchrotron-radiation X-ray tomography microscopy (SRXTM) studies has revealed a complex morphology and internal structure that corresponds to characteristic fungal morphology. Chitin was detected in the fossilized hyphae, which is another strong argument in favour of a fungal interpretation. Chitin is absent in prokaryotes but a substantial constituent in fungal cell walls. The fungal colonies consist of both hyphae and yeast-like growth states as well as resting structures and possible fruit bodies, thus, the fungi exist in vital colonies in subseafloor basalts. The fungi have also been involved in extensive weathering of secondary mineralisations. In terrestrial environments fungi are known as an important geobiological agent that promotes mineral weathering and decomposition of organic matter, and they occur in vital symbiosis with other microorganisms. It is probable to assume that fungi would play a similar role in subseafloor basalts and have great impact on the ecology and on biogeochemical cycles in such environments.

  10. Origin of the Grande Ronde Basalts, Columbia River Basalt Group

    Science.gov (United States)

    Durand, S. R.; Sen, G.; Reidel, S. P.

    2005-12-01

    The Columbia River basalts are generally thought to have formed by plume melting. Takahashi et al. (1998) suggested that the near-aphyric Grande Ronde Basalts (GR), which comprise ~63% of the CRBG, are essentially primary melts formed by nearly complete fusion of eclogite source rock in the plume and that such melting took place ~2.0 GPa. Durand and Sen (2002) examined phenocrysts and whole rock analyses and concluded that all the basalts are non-primary and, more importantly, that they underwent significant "processing" in shallow crustal magma chambers which erased their higher pressure geochemical signal, thus casting doubt on the validity of the eclogitic plume melting model. Here we report the results of our efforts to simulate the higher pressure histories of GR basalts using COMAGMAT and MELTS software. Our intent was to evaluate (1) whether such melts could be derived from primary melts formed by partial melting of a peridotite source as an alternative to the eclogite model, or if bulk melting of eclogite is required; and (2) at what pressure such primary melts could have been in equilibrium with the mantle. We carried out both forward and inverse modeling. In the forward models we chose different starting melt compositions, all produced in laboratory experiments, from peridotite vs. eclogitic sources. Our starting melts were produced by 6-17% partial melting of the peridotite KLB-1 (Hirose and Kushiro, 1993) and 18-40% melting of eclogites (77SL-582; CRB72-31; Keshav et al., 2004; Takahashi et al., 1998) at 1-3.0 GPa. In a second model, our starting melt composition was the most primitive GR lava with 6.5 wt. % MgO. We extrapolated a linear regression through the GR data to 8 wt. % MgO. We then assumed that such a melt was only olivine-equilibrated, and incrementally added olivine while maintaining equilibrium between olivine and melt using a Kd of 0.3, until a melt in equilibrium with the mantle olivine (Fo89) was found. This composition was fractionated

  11. Basaltic cannibalism at Thrihnukagigur volcano, Iceland

    Science.gov (United States)

    Hudak, M. R.; Feineman, M. D.; La Femina, P. C.; Geirsson, H.

    2014-12-01

    Magmatic assimilation of felsic continental crust is a well-documented, relatively common phenomenon. The extent to which basaltic crust is assimilated by magmas, on the other hand, is not well known. Basaltic cannibalism, or the wholesale incorporation of basaltic crustal material into a basaltic magma, is thought to be uncommon because basalt requires more energy than higher silica rocks to melt. Basaltic materials that are unconsolidated, poorly crystalline, or palagonitized may be more easily ingested than fully crystallized massive basalt, thus allowing basaltic cannibalism to occur. Thrihnukagigur volcano, SW Iceland, offers a unique exposure of a buried cinder cone within its evacuated conduit, 100 m below the main vent. The unconsolidated tephra is cross-cut by a NNE-trending dike, which runs across the ceiling of this cave to a vent that produced lava and tephra during the ~4 Ka fissure eruption. Preliminary petrographic and laser ablation inductively coupled mass spectrometry (LA-ICP-MS) analyses indicate that there are two populations of plagioclase present in the system - Population One is stubby (aspect ratio 2.1), subhedral to euhedral, and has much higher Ba/Sr ratios. Population One crystals are observed in the cinder cone, dike, and surface lavas, whereas Population Two crystals are observed only in the dike and surface lavas. This suggests that a magma crystallizing a single elongate population of plagioclase intruded the cinder cone and rapidly assimilated the tephra, incorporating the stubbier population of phenocrysts. This conceptual model for basaltic cannibalism is supported by field observations of large-scale erosion upward into the tephra, which is coated by magma flow-back indicating that magma was involved in the thermal etching. While the unique exposure at Thrihnukagigur makes it an exceptional place to investigate basaltic cannibalism, we suggest that it is not limited to this volcanic system. Rather it is a process that likely

  12. Hardness of basaltic glass-ceramics

    DEFF Research Database (Denmark)

    Jensen, Martin; Smedskjær, Morten Mattrup; Estrup, Maja;

    2009-01-01

    The dependence of the hardness of basaltic glass-ceramics on their degree of crystallisation has been explored by means of differential scanning calorimetry, optical microscopy, x-ray diffraction, and Vickers indentation. Different degrees of crystallisation in the basaltic glasses were achieved...

  13. Orthopyroxene fractionation in the Grande Ronde Basalt--Columbia River Basalt group

    International Nuclear Information System (INIS)

    Six orthopyroxenes were microprobed; five orthopyroxenes were from the Grande Ronde Basalt, and one was from the Buford flow of the Saddle Mountains Basalt. The orthopyroxenes are primarily bronzite in composition, but some analyses show that hypersthene is present. The reaction rims of all analyzed orthopyroxene crystals are pigeonite, while the groundmass pyroxene is both augite and pigeonite. Preliminary results from the least-squares linear modeling of the Grande Ronde Basalt indicate orthopyroxene is a necessary phase for mass balancing between flow compositions. Three models were tried in order to determine if selected mineral phases could be used to model the chemical compositions of the flows. These models suggest that orthopyroxene and plagioclase are phases common to the Grande Ronde Basalt. The similarity of orthopyroxene and plagioclase occurrences suggests that they are important intratelluric phases of the Grande Ronde Basalt which reacted out when the basaltic liquids were erupted at the surface

  14. Basaltic Soil of Gale Crater: Crystalline Component Compared to Martian Basalts and Meteorites

    Science.gov (United States)

    Treiman, A. H.; Bish, D. L.; Ming, D. W.; Morris, R. V.; Schmidt, M.; Downs, R. T.; Stolper, E. M.; Blake, D. F.; Vaniman, D. T.; Achilles, C. N.; Chipera, S. J.; Bristow, T. F.; Crisp, J. A.; Farmer, J. A.; Morookian, J. M.; Morrison, S. M.; Rampe, E. B.; Sarrazin, P.; Yen, A. S.; Anderosn, R. C.; DesMarais, D. J.; Spanovich, N.

    2013-01-01

    A significant portion of the soil of the Rocknest dune is crystalline and is consistent with derivation from unweathered basalt. Minerals and their compositions are identified by X-ray diffraction (XRD) data from the CheMin instrument on MSL Curiosity. Basalt minerals in the soil include plagioclase, olivine, low- and high-calcium pyroxenes, magnetite, ilmenite, and quartz. The only minerals unlikely to have formed in an unaltered basalt are hematite and anhydrite. The mineral proportions and compositions of the Rocknest soil are nearly identical to those of the Adirondack-class basalts of Gusev Crater, Mars, inferred from their bulk composition as analyzed by the MER Spirit rover.

  15. Noble Gases and Halogens in Icelandic Basalts

    OpenAIRE

    Weston, Bridget

    2013-01-01

    Noble gas and halogen data from a suite of Icelandic samples are presented. Iceland combines hotspot volcanism, a spreading ridge and abundant subglacially erupted samples. This combination allows for samples that erupted under high enough pressures to retain a measurable mantle volatile content, and also display signatures representing interaction between ocean island basalt (OIB) and mid-ocean ridge basalt (MORB) mantle sources.Erupted samples used to determine the mantle’s halogen and nobl...

  16. Hydrothermal evolution of repository groundwaters in basalt

    International Nuclear Information System (INIS)

    Groundwaters in the near field of a radioactive waste repository in basalt will change their chemical composition in response to reactions with the basalt. These reactions will be promoted by the heat generated by the decaying waste. It is important to predict both the rate and the extent of these reactions, and the secondary minerals produced, because the alteration process controls the chemical environment affecting the corrosion of the canister, the solubility and complexation of migrating radionuclides, the reactivity of the alteration products to radionuclides sorption, and the porosity and permeability of the host rock. A comprehensive review of the literature leads to the preliminary finding that hydrothermally altering basalts in geothermal regions such as Iceland lead to a secondary mineralogy and groundwater composition similar to that expected to surround a repository. Furthermore, laboratory experiments replicating the alteration conditions approximate those observed in the field and expected in a repository. Preliminary estimates were made of the rate of hydration and devitrification of basaltic glass and the zero-order dissolution rate of basaltic materials. The rates were compared with those for rhyolitic glasses and silicate minerals. Preliminary calculations made of mixed process alteration kinetics, involving pore diffusion and surface reaction suggest that at temperatures greater than 1500C, alteration proceeds so rapidly as to become pervasive in normally fractured basalt exposed to higher temperatures in the field. 70 references

  17. Radionuclide reactions with groundwater and basalts from Columbia River basalt formations

    International Nuclear Information System (INIS)

    Chemical reactions of radionuclides with geologic materials found in Columbia River basalt formations were studied. The objective was to determine the ability of these formations to retard radionuclide migration from a radioactive waste repository located in deep basalt. Reactions that can influence migration are precipitation, ion-exchange, complexation, and oxidation-reduction. These reactions were studied by measuring the effects of groundwater composition and redox potential (Eh) on radionuclide sorption on fresh basalt surfaces, a naturally altered basalt, and a sample of secondary minerals associated with a Columbia River basalt flow. In addition, radionuclide sorption isotherms were measured for these materials and reaction kinetics were determined. The radionuclides studied were 137Cs, 85Sr, 75Se, /sup 95m/Tc, 237Np, 241Am, 226Ra and 237Pu. The Freundlich equation accurately describes the isotherms when precipitation of radionuclides does not occur. In general, sorption increased in the order: basalt < altered basalt < secondary minerals. This increase in sorption corresponds to increasing surface area and cation exchange capacity. The Eh of the system had a large effect on technetium, plutonium, and neptunium sorption. Technetium(VII), Pu(VI), and Np(V) are reduced to Tc(IV), Pu(IV), and Np(IV), respectively, under Eh conditions expected in deep basalt formations. The kinetics of radionuclide sorption and basalt-groundwater reactions were observed over a period of 18 weeks. Most sorption reactions stabilized after about four weeks. Groundwater composition changed the least in contact with altered basalt. Contact with secondary minerals greatly increased Ca, K, and Mg concentrations in the groundwater

  18. Can we identify source lithology of basalt?

    Science.gov (United States)

    Yang, Zong-Feng; Zhou, Jun-Hong

    2013-01-01

    The nature of source rocks of basaltic magmas plays a fundamental role in understanding the composition, structure and evolution of the solid earth. However, identification of source lithology of basalts remains uncertainty. Using a parameterization of multi-decadal melting experiments on a variety of peridotite and pyroxenite, we show here that a parameter called FC3MS value (FeO/CaO-3*MgO/SiO2, all in wt%) can identify most pyroxenite-derived basalts. The continental oceanic island basalt-like volcanic rocks (MgO>7.5%) (C-OIB) in eastern China and Mongolia are too high in the FC3MS value to be derived from peridotite source. The majority of the C-OIB in phase diagrams are equilibrium with garnet and clinopyroxene, indicating that garnet pyroxenite is the dominant source lithology. Our results demonstrate that many reputed evolved low magnesian C-OIBs in fact represent primary pyroxenite melts, suggesting that many previous geological and petrological interpretations of basalts based on the single peridotite model need to be reconsidered.

  19. Study of crystallization of a basalt glass

    International Nuclear Information System (INIS)

    Basalt vitreous ceramics posses industrial importance by presenting high mechanical resistance to the abrasion. It was studied the obtention and the crystallization of a glass obtained from a basalt of Campinas, Sao Paulo, Brazil, aiming to develop a material with great abrasive resistance. Fusions were made at 1400 deg Celsius in electrical oven and in alumina crucible, of fine residues of basalt mining. The obtained glass was treated in a crystallization temperature of 880 deg Celsius, determined by DSC, by various time of treatment. The present main crystalline phases, detected by XRD, were the magnesium-ferrite (MgFe2O4) and the diopsid Ca(Mg,Fe,Al)(Si,Al)2O6. Analysing the density by the Archimedes methodology and the DRX it was possible to follow the crystallization kinetic up.

  20. Pressure grouting of fractured basalt flows

    International Nuclear Information System (INIS)

    This report describes a field trial of pressure grouting in basalt and presents the results of subsequent coring and permeability measurements. The trial shows that hydraulic conductivity of fractured basalt bedrock can be significantly reduced by pressure injection of cementitious materials. The effectiveness of the pressure grout procedure was evaluated by measuring the change in the hydraulic conductivity of the bedrock. The extent of grout penetration was determined by analyzing postgrout injection drilling chips for the presence of a tracer in the grout and also by examining cores of the treated basalt. Downhole radar mapping indicated major lava flow patterns and follow water movement during a surface infiltration test. A site called Box Canyon, which is northwest of the Idaho National Engineering Laboratory (INEL), was chosen for the study because its surface outcrop geology is similar to the underlying bedrock fracture system at the INEL's Radioactive Waste Management Complex (RWMC)

  1. CO2 sequestration in basalts: laboratory measurements

    Science.gov (United States)

    Otheim, L. T.; Adam, L.; van Wijk, K.; McLing, T. L.; Podgorney, R. K.

    2010-12-01

    Geologic sequestration of CO2 is proposed as the only promising large-scale method to help reduce CO2 gas emission by its capture at large point sources and subsequent long-term storage in deep geologic formations. Reliable and cost-effective monitoring will be important aspect of ensuring geological sequestration is a safe, effective, and acceptable method for CO2 emissions mitigation. Once CO2 injection starts, seismic methods can be used to monitor the migration of the carbon dioxide plume. To calibrate changes in rock properties from field observations, we propose to first analyze changes in elastic properties on basalt cores. Carbon dioxide sequestration in basalt rocks results in fluid substitution and mixing of CO2 with water and rock mineralizations. Carbon dioxide sequestration in mafic rocks creates reactions such as Mg2SiO 4 + CaMgSi2O 6 + 4CO2 = Mg 3Ca(CO 3) 4 + 3SiO2 whereby primary silicate minerals within the basalt react with carbonic acid laden water to creating secondary carbonate minerals and silicates. Using time-lapse laboratory scale experiments, such as laser generated ultrasonic wave propagation; it is possible to observe small changes in the physical properties of a rock. We will show velocity and modulus measurements on three basalt core samples for different saturation. The ultimate goal of the project is to track seismic changes due to fluid substitution and mineralization. The porosity of our basalts ranges from 8% to 12%, and the P-wave velocity increases by 20% to 40% from dry to water saturated conditions. Petrographic analysis (CT-scans, thin sections, XRF, XRf) will aid in the characterization of the mineral structure in these basalts and its correlation to seismic properties changes resulting from fluid substitution and mineralization.

  2. Increased corrosion resistance of basalt reinforced cement compositions with nanosilica

    Directory of Open Access Journals (Sweden)

    URKHANOVA Larisa Alekseevna

    2014-08-01

    Full Text Available Disperse fiber reinforcement is used to improve deformation and shrinkage characteristics, flexural strength of concrete. Basalt roving and thin staple fiber are often used as mineral fibers. The paper considers the problems of using thin basalt fiber produced by centrifugal-blow method. Evaluation of the corrosion resistance of basalt fiber as part of the cement matrix was performed. Nanodispersed silica produced by electron beam accelerator was used to increase corrosion resistance of basalt fiber.

  3. Structural relaxation in annealed hyperquenched basaltic glasses

    DEFF Research Database (Denmark)

    Guo, Xiaoju; Mauro, John C.; Potuzak, M.;

    2012-01-01

    The enthalpy relaxation behavior of hyperquenched (HQ) and annealed hyperquenched (AHQ) basaltic glass is investigated through calorimetric measurements. The results reveal a common onset temperature of the glass transition for all the HQ and AHQ glasses under study, indicating that the primary...

  4. The biological consequences of flood basalt volcanism

    Science.gov (United States)

    Clapham, M.

    2012-12-01

    Flood basalt eruptions are among the largest environmental perturbations of the Phanerozoic. The rapid release of CO2 from a large igneous province would have triggered a chain of events that can include climate warming, ocean acidification, reduced seawater carbonate saturation, and expanded oceanic anoxia. Those stressors have widely negative impacts on marine organisms, especially on calcified taxa, by affecting their respiratory physiology and reducing energy available for growth and reproduction. Many Phanerozoic extinctions, most notably the end-Permian and end-Triassic mass extinctions, coincided with flood basalt eruptions and shared distinctive patterns of taxonomic and ecological selectivity. In these extinctions, highly active organisms were more likely to survive because they possess physiological adaptations for maintaining internal pH during activity, which also proves useful when buffering pH against ocean acidification. In contrast, species that did not move and had low metabolic rates, such as brachiopods and sponges, suffered considerable losses during these extinctions. Heavily-calcified organisms, especially corals, were particularly vulnerable; as a result, ocean acidification and saturation state changes from flood basalt eruptions often triggered crises in reef ecosystems. This characteristic pattern of selectivity during "physiological" extinctions that closely coincided with flood basalts provides a template for assessing the causes of other extinction events. Because these crises also provide deep time analogues for the ongoing anthropogenic crisis of warming, ocean acidification, and expanded anoxia, the selectivity patterns can also help constrain "winners" and "losers" over upcoming decades.

  5. Site identification presentation: Basalt Waste Isolation Project

    International Nuclear Information System (INIS)

    The final step in the site identification process for the Basalt Waste Isolation Project is described. The candidate sites are identified. The site identification methodology is presented. The general objectives which must be met in selecting the final site are listed. Considerations used in the screening process are also listed. Summary tables of the guidelines used are included

  6. Thermal models for basaltic volcanism on Io

    Science.gov (United States)

    Keszthelyil, L.; McEwen, A.

    1997-01-01

    We present a new model for the thermal emissions from active basaltic eruptions on Io. While our methodology shares many similarities with previous work, it is significantly different in that (1) it uses a field tested cooling model and (2) the model is more applicable to pahoehoe flows and lava lakes than fountain-fed, channelized, 'a'a flows. This model demonstrates the large effect lava porosity has on the surface cooling rate (with denser flows cooling more slowly) and provides a preliminary tool for examining some of the hot spots on Io. The model infrared signature of a basaltic eruption is largely controlled by a single parameter, ??, the average survival time for a lava surface. During an active eruption surfaces are quickly covered or otherwise destroyed and typical values of ?? for a basaltic eruption are expected to be on the order of 10 seconds to 10 minutes. Our model suggests that the Galileo SSI eclipse data are consistent with moderately active to quiescent basaltic lava lakes but are not diagnostic of such activity. Copyright 1997 by the American Geophysical Union.

  7. Coatings on Atacama Desert Basalt: A Possible Analog for Coatings on Gusev Plains Basalt

    Science.gov (United States)

    Sutter, B.; Golden, D. C.; Amundson, R.; Chong-Diaz, G.; Ming, D. W.

    2007-01-01

    Surface coatings on Gusev Plains basalt have been observed and may contain hematite and nanophase Fe-oxides along with enrichments in P, S, Cl, and K relative to the underlying rock. The Gusev coatings may be derived from the dissolution of adhering soil and/or parent rock along with the addition of S and Cl from outside sources. Transient water for dissolution could be sourced from melting snow during periods of high obliquity, acid fog, and/or ground water (Haskin et al., 2005). Coatings on basalt in the hyper-arid (less than 2mm y(sup -1)) Atacama Desert may assist in understanding the chemistry, mineralogy and formation mechanisms of the Gusev basalt coatings. The Atacama Desert climate is proposed to be analogous to a paleo-Mars climate that was characterized by limited aqueous activity when the Gusev coatings could have formed. The objectives of this work are to (i) determine the chemical nature and extent of surface coatings on Atacama Desert basalt, and (ii) assess coating formation mechanisms in the Atacama Desert. Preliminary backscattered electron imaging of Atacama basalt thin-sections indicated that the coatings are as thick as 20 m. The boundary between the coating and the basalt labradorite, ilmenite, and augite grains was abrupt indicating that the basalt minerals underwent no chemical dissolution. The Atacama coatings have been added to the basalt instead of being derived from basalt chemical weathering. Semi-quantitative energy dispersive spectroscopy shows the coatings to be chemically homogeneous. The coating is depleted in Ca (0.9 wt% CaO) and enriched in K (1.3 wt.% K2O) and Si (69.1 wt.% SiO2) relative to the augite and labradorite grains. A dust source enriched in Si (e.g., poorly crystalline silica) and K and depleted in Ca appears to have been added to the basalt surface. Unlike the Gusev coatings, no P, S, and Cl enrichment was observed. However, Fe (3.2 wt.% FeO) was present in the Atacama coatings suggesting the present of Fe

  8. H 2O in basalt and basaltic andesite glass inclusions from four subduction-related volcanoes

    Science.gov (United States)

    Sisson, T. W.; Layne, G. D.

    1993-06-01

    Total dissolved H 2O and major element abundances were measured in basalt and basaltic andesite glass inclusions in olivine phenocrysts from Quaternary eruptions of four subduction-related volcanoes to test the hypothesis that low-MgO high-alumina basalts contain high H 2O at depth [1] and to reveal any petrogenetically significant correlations between arc basalt compositions and H 2O contents. Total dissolved H 2O (combined molecular H 2O and OH groups) measured by ion microprobe in mafic glass inclusions from the 1974 eruption of Fuego, Guatemala, reaches 6.2 wt.%. Dissolved H 2O contents decrease in more evolved Fuego glasses. Correlations of H 2O with MgO, Na 2O, K 2O, S and Cl indicate that aqueous fluid exsolution during magma ascent forced crystallization and differentiation of residual liquids. Low-K 2O magnesian high-alumina basalt glass inclusions from the 3 ka eruption of Black Crater (Medicine Lake volcano, California) have low H 2O contents, near 0.2 wt.%, which are consistent with the MORB-like character of these and other primitive lavas of the Medicine Lake region. Basalt and basaltic andesite glass inclusions from Copco Cone and Goosenest volcano on the Cascade volcanic front north of Mt. Shasta have H 2O contents of up to 3.3 wt.%. The range of H 2O contents in Cascade mafic magmas is too large to have resulted solely from enrichment by crystallization and indicates the participation of an H 2O-rich component in magma generation or crustal-level modification. Whereas fluid-absent melting of amphibole-bearing peridotite can account for the H 2O in most mafic arc liquids, the very high H 2O/alkali ratios of the 1974 Fuego eruptives suggest that an aqueous fluid was involved in the generation of Fuego basalts.

  9. Sulfur isotope homogeneity of lunar mare basalts

    Science.gov (United States)

    Wing, Boswell A.; Farquhar, James

    2015-12-01

    We present a new set of high precision measurements of relative 33S/32S, 34S/32S, and 36S/32S values in lunar mare basalts. The measurements are referenced to the Vienna-Canyon Diablo Troilite (V-CDT) scale, on which the international reference material, IAEA-S-1, is characterized by δ33S = -0.061‰, δ34S ≡ -0.3‰ and δ36S = -1.27‰. The present dataset confirms that lunar mare basalts are characterized by a remarkable degree of sulfur isotopic homogeneity, with most new and published SF6-based sulfur isotope measurements consistent with a single mass-dependent mean isotopic composition of δ34S = 0.58 ± 0.05‰, Δ33S = 0.008 ± 0.006‰, and Δ36S = 0.2 ± 0.2‰, relative to V-CDT, where the uncertainties are quoted as 99% confidence intervals on the mean. This homogeneity allows identification of a single sample (12022, 281) with an apparent 33S enrichment, possibly reflecting cosmic-ray-induced spallation reactions. It also reveals that some mare basalts have slightly lower δ34S values than the population mean, which is consistent with sulfur loss from a reduced basaltic melt prior to eruption at the lunar surface. Both the sulfur isotope homogeneity of the lunar mare basalts and the predicted sensitivity of sulfur isotopes to vaporization-driven fractionation suggest that less than ≈1-10% of lunar sulfur was lost after a potential moon-forming impact event.

  10. Geochemistry of apollo 15 basalt 15555 and soil 15531.

    Science.gov (United States)

    Schnetzler, C C; Philpotts, J A; Nava, D F; Schuhmann, S; Thomas, H H

    1972-01-28

    Major and trace element concentrations have been determined by atomic absorption spectrophotometry, colorimetry, and isotope dilution in Apollo 15 mare basalt 15555 from the Hadley Rille area; trace element concentrations have also been determined in plagioclase and pyroxene separates from basalt 15555 and in soil 15531 from the same area. Basalt 15555 most closely resembles in composition the Apollo 12 olivine-rich basalts. The concentrations of lithium, potassium, rubidium, barium, rare-earth elements, and zirconium in basalt 15555 are the lowest, and the negative europium anomaly is the smallest, reported for lunar basalts; this basalt might be the least differentiated material yet returned from the moon. Crystallization and removal of about 6 percent of plagioclase similar to that contained in the basalt would account for the observed europium anomaly; if plagioclase is not on the liquidus of this basalt, a multistage origin is indicated. Mineral data indicate that plagioclase and pyroxene approached quasi-equilibrium. Most of the chemical differences between basalt 15555 and soil 15531 would be accounted for if the soil were a mixture of 88 percent basalt, 6 percent KREEP (a component, identified in other Apollo soils, rich in potassium, rare-earth elements, and phosphorus) and 6 percent plagioclase (anorthosite?).

  11. Northwest Africa 5298: A Basaltic Shergottite

    Science.gov (United States)

    Hui, Hejiu; Peslier, Anne; Lapen, Thomas J.; Brandon, Alan; Shafer, John

    2009-01-01

    NWA 5298 is a single 445 g meteorite found near Bir Gandouz, Morocco in March 2008 [1]. This rock has a brown exterior weathered surface instead of a fusion crust and the interior is composed of green mineral grains with interstitial dark patches containing small vesicles and shock melts [1]. This meteorite is classified as a basaltic shergottite [2]. A petrologic study of this Martian meteorite is being carried out with electron microprobe analysis and soon trace element analyses by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Oxygen fugacity is calculated from Fe-Ti oxides pairs in the sample. The data from this study constrains the petrogenesis of basaltic shergottites.

  12. Technical program plan, Basalt Waste Isolation Project

    International Nuclear Information System (INIS)

    The Basalt Waste Isolation Project (BWIP) program as administered by the DOE's Richland Operations Office and Rockwell Hanford Operations is described. The objectives, scope and scientific technologies are discussed. The work breakdown structure of the project includes: project management and support, systems integration, geosciences, hydrology, engineered barriers, test facility design and construction, engineering testing, repository studies, and schedules. The budget of the program including operating and capital cost control is also included

  13. Nanoparticulate mineral matter from basalt dust wastes.

    Science.gov (United States)

    Dalmora, Adilson C; Ramos, Claudete G; Querol, Xavier; Kautzmann, Rubens M; Oliveira, Marcos L S; Taffarel, Silvio R; Moreno, Teresa; Silva, Luis F O

    2016-02-01

    Ultra-fine and nano-particles derived from basalt dust wastes (BDW) during "stonemeal" soil fertilizer application have been the subject of some concern recently around the world for their possible adverse effects on human health and environmental pollution. Samples of BDW utilized were obtained from companies in the mining district of Nova Prata in southern Brazil for chemical characterization and nano-mineralogy investigation, using an integrated application of advanced characterization techniques such as X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/(Energy Dispersive Spectroscopy) EDS/(selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM)/EDS and granulometric distribution analysis. The investigation has revealed that BDW materials are dominated by SiO2, Al2O3 and Fe2O3, with a complex micromineralogy including alkali feldspar, augite, barite, labradorite, hematite, heulandrite, gypsum, kaolinite, quartz, and smectite. In addition we have identified a number of trace metals such as Cd, Cu, Cr, Zn that are preferentially concentrated into the finer, inhalable, dust fraction and could so present a health hazard in the urban areas around the basalt mining zone. The implication of this observation is that use of these nanometric-sized particulates as soil fertilizer may present different health challenges to those of conventional fertilizers, inviting future work regarding the relative toxicities of these materials. Our investigation on the particle size distribution, nano-particle mineralogy and chemical composition in typical BDW samples highlights the need to develop cleaning procedures to minimise exposure to these natural fertilizing basalt dust wastes and is thus of direct relevance to both the industrial sector of basalt mining and to agriculture in the region.

  14. Technical program plan, Basalt Waste Isolation Project

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-12-01

    The Basalt Waste Isolation Project (BWIP) program as administered by the DOE's Richland Operations Office and Rockwell Hanford Operations is described. The objectives, scope and scientific technologies are discussed. The work breakdown structure of the project includes: project management and support, systems integration, geosciences, hydrology, engineered barriers, test facility design and construction, engineering testing, repository studies, and schedules. The budget of the program including operating and capital cost control is also included. (DC)

  15. Nanoparticulate mineral matter from basalt dust wastes.

    Science.gov (United States)

    Dalmora, Adilson C; Ramos, Claudete G; Querol, Xavier; Kautzmann, Rubens M; Oliveira, Marcos L S; Taffarel, Silvio R; Moreno, Teresa; Silva, Luis F O

    2016-02-01

    Ultra-fine and nano-particles derived from basalt dust wastes (BDW) during "stonemeal" soil fertilizer application have been the subject of some concern recently around the world for their possible adverse effects on human health and environmental pollution. Samples of BDW utilized were obtained from companies in the mining district of Nova Prata in southern Brazil for chemical characterization and nano-mineralogy investigation, using an integrated application of advanced characterization techniques such as X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/(Energy Dispersive Spectroscopy) EDS/(selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM)/EDS and granulometric distribution analysis. The investigation has revealed that BDW materials are dominated by SiO2, Al2O3 and Fe2O3, with a complex micromineralogy including alkali feldspar, augite, barite, labradorite, hematite, heulandrite, gypsum, kaolinite, quartz, and smectite. In addition we have identified a number of trace metals such as Cd, Cu, Cr, Zn that are preferentially concentrated into the finer, inhalable, dust fraction and could so present a health hazard in the urban areas around the basalt mining zone. The implication of this observation is that use of these nanometric-sized particulates as soil fertilizer may present different health challenges to those of conventional fertilizers, inviting future work regarding the relative toxicities of these materials. Our investigation on the particle size distribution, nano-particle mineralogy and chemical composition in typical BDW samples highlights the need to develop cleaning procedures to minimise exposure to these natural fertilizing basalt dust wastes and is thus of direct relevance to both the industrial sector of basalt mining and to agriculture in the region. PMID:26551199

  16. Making rhyolite in a basalt crucible

    Science.gov (United States)

    Eichelberger, John

    2016-04-01

    Iceland has long attracted the attention of those concerned with the origin of rhyolitic magmas and indeed of granitic continental crust, because it presents no alternative for such magmas other than deriving them from a basaltic source. Hydrothermally altered basalt has been identified as the progenitor. The fact that rhyolite erupts as pure liquid requires a process of melt-crustal separation that is highly efficient despite the high viscosity of rhyolite melt. Volcanoes in Iceland are foci of basaltic magma injection along the divergent plate boundary. Repeated injection produces remelting, digestion, and sometimes expulsion or lateral withdrawal of material resulting in a caldera, a "crucible" holding down-dropped and interlayered lava flows, tephras, and injected sills. Once melting of this charge begins, a great deal of heat is absorbed in the phase change. Just 1% change in crystallinity per degree gives a melt-present body an effective heat capacity >5 times the subsolidus case. Temperature is thus buffered at the solidus and melt composition at rhyolite. Basalt inputs are episodic ("fires") so likely the resulting generation of rhyolite by melting is too. If frequent enough to offset cooling between events, rhyolite melt extractions will accumulate as a rhyolite magma reservoir rather than as discrete crystallized sills. Evidently, such magma bodies can survive multiple firings without themselves erupting, as the 1875 eruption of Askja Caldera of 0.3 km3 of rhyolite equilibrated at 2-km depth without previous leakage over a ten-millennium period and the surprise discovery of rhyolite magma at 2-km depth in Krafla suggest. Water is required for melting; otherwise melting cannot begin at a temperature lower than that of the heat source. Because the solubility of water in melt is pressure-dependent and almost zero at surface pressure, there must be a minimum depth at which basalt-induced melting can occur and a rhyolite reservoir sustained. In practice, the

  17. FOAM CONCRETE REINFORCEMENT BY BASALT FIBRES

    Directory of Open Access Journals (Sweden)

    Zhukov Aleksey Dmitrievich

    2012-10-01

    Full Text Available The authors demonstrate that the foam concrete performance can be improved by dispersed reinforcement, including methods that involve basalt fibres. They address the results of the foam concrete modeling technology and assess the importance of technology-related parameters. Reinforcement efficiency criteria are also provided in the article. Dispersed reinforcement improves the plasticity of the concrete mix and reduces the settlement crack formation rate. Conventional reinforcement that involves metal laths and rods demonstrates its limited application in the production of concrete used for thermal insulation and structural purposes. Dispersed reinforcement is preferable. This technology contemplates the infusion of fibres into porous mixes. Metal, polymeric, basalt and glass fibres are used as reinforcing components. It has been identified that products reinforced by polypropylene fibres demonstrate substantial abradability and deformability rates even under the influence of minor tensile stresses due to the low adhesion strength of polypropylene in the cement matrix. The objective of the research was to develop the type of polypropylene of D500 grade that would demonstrate the operating properties similar to those of Hebel and Ytong polypropylenes. Dispersed reinforcement was performed by the basalt fibre. This project contemplates an autoclave-free technology to optimize the consumption of electricity. Dispersed reinforcement is aimed at the reduction of the block settlement in the course of hardening at early stages of their operation, the improvement of their strength and other operating properties. Reduction in the humidity rate of the mix is based on the plasticizing properties of fibres, as well as the application of the dry mineralization method. Selection of optimal parameters of the process-related technology was performed with the help of G-BAT-2011 Software, developed at Moscow State University of Civil Engineering. The authors also

  18. Quantifying glassy and crystalline basalt partitioning in the oceanic crust

    Science.gov (United States)

    Moore, Rachael; Ménez, Bénédicte

    2016-04-01

    The upper layers of the oceanic crust are predominately basaltic rock, some of which hosts microbial life. Current studies of microbial life within the ocean crust mainly focus on the sedimentary rock fraction, or those organisms found within glassy basalts while the potential habitability of crystalline basalts are poorly explored. Recently, there has been recognition that microbial life develops within fractures and grain boundaries of crystalline basalts, therefore estimations of total biomass within the oceanic crust may be largely under evaluated. A deeper understanding of the bulk composition and fractionation of rocks within the oceanic crust is required before more accurate estimations of biomass can be made. To augment our understanding of glassy and crystalline basalts within the oceanic crust we created two end-member models describing basalt fractionation: a pillow basalt with massive, or sheet, flows crust and a pillow basalt with sheeted dike crust. Using known measurements of massive flow thickness, dike thickness, chilled margin thickness, pillow lava size, and pillow lava glass thickness, we have calculated the percentage of glassy versus crystalline basalts within the oceanic crust for each model. These models aid our understanding of textural fractionation within the oceanic crust, and can be applied with bioenergetics models to better constrain deep biomass estimates.

  19. Microbial colonization and alteration of basaltic glass

    Directory of Open Access Journals (Sweden)

    J. Einen

    2006-03-01

    Full Text Available Microorganisms have been reported to be associated with the alteration of the glassy margin of seafloor pillow basalts (Thorseth et al., 2001, 2003; Lysnes et al., 2004. The amount of iron and other biological important elements present in basalts and the vast abundance of basaltic glass in the earth's crust, make glass alteration an important process in global element cycling. To gain further insight into microbial communities associated with glass alteration, five microcosm experiments mimicking seafloor conditions were inoculated with seafloor basalt and incubated for one year. Mineral precipitations, microbial attachment to the glass and glass alteration were visualized by scanning electron microscopy (SEM, and the bacterial community composition was fingerprinted by PCR and denaturing gradient gel electrophoresis (DGGE in combination with sequencing. SEM analysis revealed a microbial community with low morphological diversity of mainly biofilm associated and prosthecate microorganisms. Approximately 30 nm thick alteration rims developed on the glass in all microcosms after one year of incubation; this however was also seen in non inoculated controls. Calcium carbonate precipitates showed parallel, columnar and filamentous crystallization habits in the microcosms as well as in the sterile controls. DGGE analysis showed an alteration in bacterial community profiles in the five different microcosms, as a response to the different energy and redox regimes and time. In all microcosms a reduction in number of DGGE bands, in combination with an increase in cell abundance were recorded during the experiment. Sequence analysis showed that the microcosms were dominated by four groups of organisms with phylogenetic affiliation to four taxa: The Rhodospirillaceae, a family containing phototrophic marine organisms, in which some members are capable of heterotrophic growth in darkness and N2 fixation; the family Hyphomicrobiaceae, a group

  20. East Mariana Basin tholeiites: Cretaceous intraplate basalts or rift basalts related to the Ontong Java plume?

    Science.gov (United States)

    Castillo, P.R.; Pringle, M.S.; Carlson, R.W.

    1994-01-01

    Studies of seafloor magnetic anomaly patterns suggest the presence of Jurassic oceanic crust in a large area in the western Pacific that includes the East Mariana, Nauru and Pigafetta Basins. Sampling of the igneous crust in this area by the Deep Sea Drilling Program (DSDP) and the Ocean Drilling Program (ODP) allows direct evaluation of the age and petrogenesis of this crust. ODP Leg 129 drilled a 51 m sequence of basalt pillows and massive flows in the central East Mariana Basin. 40Ar 39Ar ages determined in this study for two Leg 129 basalts average 114.6 ?? 3.2 Ma. This age is in agreement with the Albian-late Aptian paleontologic age of the overlying sediments, but is distinctively younger than the Jurassic age predicted by magnetic anomaly patterns in the basin. Compositionally, the East Mariana Basin basalts are uniformly low-K tholeiites that are depleted in highly incompatible elements compared to moderately incompatible ones, which is typical of mid-ocean ridge basalts (MORB) erupted near hotspots. The Sr, Nd and Pb isotopic compositions of the tholeiites ( 87Sr 86Srinit = 0.70360-0.70374; 143Nd 144Ndinit = 0.512769-0.512790; 206Pb 204Pbmeas = 18.355-18.386) also overlap with some Indian Ocean Ridge MORB, although they are distinct from the isotopic compositions of Jurassic basalts drilled in the Pigafetta Basin, the oldest Pacific MORB. The isotopic compositions of the East Mariana Basin tholeiites are also similar to those of intraplate basalts, and in particular, to the isotopic signature of basalts from the nearby Ontong Java and Manihiki Plateaus. The East Mariana Basin tholeiites also share many petrologic and isotopic characteristics with the oceanic basement drilled in the Nauru Basin at DSDP Site 462. In addition, the new 110.8 ?? 1.0 Ma 40Ar 39Ar age for two flows from the bottom of Site 462 in the Nauru Basin is indistinguishable from the age of the East Mariana Basin flows. Thus, while magnetic anomaly patterns predict that the igneous

  1. Crystal Stratigraphy of Two Basalts from Apollo 16: Unique Crystallization of Picritic Basalt 606063,10-16 and Very-Low-Titanium Basalt 65703,9-13

    Science.gov (United States)

    Donohue, P. H.; Neal, C. R.; Stevens, R. E.; Zeigler, R. A.

    2014-01-01

    A geochemical survey of Apollo 16 regolith fragments found five basaltic samples from among hundreds of 2-4 mm regolith fragments of the Apollo 16 site. These included a high-Ti vitrophyric basalt (60603,10-16) and one very-low-titanium (VLT) crystalline basalt (65703,9-13). Apollo 16 was the only highlands sample return mission distant from the maria (approx. 200 km). Identification of basaltic samples at the site not from the ancient regolith breccia indicates input of material via lateral transport by post-basin impacts. The presence of basaltic rocklets and glass at the site is not unprecedented and is required to satisfy mass-balance constraints of regolith compositions. However, preliminary characterization of olivine and plagioclase crystal size distributions indicated the sample textures were distinct from other known mare basalts, and instead had affinities to impact melt textures. Impact melt textures can appear qualitatively similar to pristine basalts, and quantitative analysis is required to distinguish between the two in thin section. The crystal stratigraphy method is a powerful tool in studying of igneous systems, utilizing geochemical analyses across minerals and textural analyses of phases. In particular, trace element signatures can aid in determining the ultimate origin of these samples and variations document subtle changes occurring during their petrogenesis.

  2. Het Zevengebergte als supergroeve. Drachenfels, Stenzelberger, Wolkenburger en basalt

    NARCIS (Netherlands)

    Nijland, T.G.

    2015-01-01

    Vanuit Nederlands perspectief kan het Zevengebergte aan de Rijn tegenover Bonn als één grote groeve worden beschouwd. In de middeleeuwen leverde het gebied de bekende Drachenfels trachiet. In de 19e eeuw stichten Nederlanders de Basalt AG in Linz om aan de grote vraag naar basalt voor waterbouwkundi

  3. On Linear Relationships between Trace Elements in Oceanic Basalts

    Institute of Scientific and Technical Information of China (English)

    万渝生

    1991-01-01

    On the basis of the batch melting model*,the author explains the linear relationships between the elements which are often recognized in oceanic basalts,has established mathematic models,discusses some relevant questions,and finally gives an example to show how to apply the method to research on basalts.

  4. Quaternary basaltic volcanism in the Payenia volcanic province, Argentina

    DEFF Research Database (Denmark)

    Søager, Nina

    Pleistocene times. These basalts mark the end of a period of shallow subduction of the Nazca slab beneath the Payenia province and volcanism in the Nevado volcanic field apparently followed the downwarping slab in a north-northwest direction ending in the Northern Segment. The northern Payenia basalts...

  5. Vesicularity of basalt erupted at Reykjanes Ridge crest

    Science.gov (United States)

    Duffield, W.A.

    1978-01-01

    Average vesicularity of basalt drilled at three sites on the west flank of the Reykjanes Ridge increases with decreasing age. This change apparently records concomitant decrease in water depth at the ridge crest where the basalt was erupted and suggests substantial upward growth of the crest during the past 35 Myr. ?? 1978 Nature Publishing Group.

  6. Hydrothermal interaction of a ceramic waste form with basalt

    International Nuclear Information System (INIS)

    The behavior of crystalline supercalcine-ceramic in the presence of basalt was investigated under mild hydrothermal conditions at 100, 200, and 3000C with a pressure of 300 bars. Both the solid phases and solution concentrations of the interaction products of basalt and supercalcine-ceramic were characterized. At 1000C, no alteration products could be detected in experiments involving supercalcine-ceramic and basalt. The solution analyses for elements specific to the supercalcine-ceramic did not indicate any significant differences between the treatments with and without basalt, suggesting little or no interaction between basalt and supercalcine-ceramic at this temperature. At 3000C, several solid alteration/interaction products were identified. These products included two phases, pollucite and scheelite, originally incorporated into the ceramic formulation but which reformed with different bulk chemical compositions. In addition, isolated crystals of unidentified K (+-Ba) aluminosilicate phases were observed. Solution analyses of these runs did not indicate any significant differences between the treatments of supercalcine-ceramic with and without basalt, except that the Sr concentration decreased in the presence of basalt. Similar behavior was noted earlier, when basalt and SrZrO3 experiments were conducted. Alteration products and solution concentrations at 2000C lie intermediate between the 1000 and 3000C results

  7. Hydrogeology of the basalts in the Uruguayan NW

    International Nuclear Information System (INIS)

    This work is about the hydrogeological aspects in the NW Uruguayan basaltic area. The results of this research are the main geological, morphological and hydrogeological aspects of the area as well as the characteristics and the color of the basalt and sandstones

  8. [Determination of Total Iron and Fe2+ in Basalt].

    Science.gov (United States)

    Liu, Jian-xun; Chen, Mei-rong; Jian, Zheng-guo; Wu, Gang; Wu, Zhi-shen

    2015-08-01

    Basalt is the raw material of basalt fiber. The content of FeO and Fe2O3 has a great impact on the properties of basalt fibers. ICP-OES and dichromate method were used to test total Fe and Fe(2+) in basalt. Suitable instrument parameters and analysis lines of Fe were chosen for ICP-OES. The relative standard deviation (RSD) of ICP-OES is 2.2%, and the recovery is in the range of 98%~101%. The method shows simple, rapid and highly accurate for determination of total Fe and Fe(2+) in basalt. The RSD of ICP-OES and dichromate method is 0.42% and 1.4%, respectively.

  9. Origin of High-Alumina Basalt, Andesite, and Dacite Magmas.

    Science.gov (United States)

    Hamilton, W

    1964-10-30

    The typical volcanic rocks of most island arcs and eugeosynclines, and of some continental environments, are basalt, andesite, and dacite, of high alumina content. The high-alumina basalt differs from tholeiitic basalt primarily in having a greater content of the components of calcic plagioclase. Laboratory data indicate that in the upper mantle, below the level at which the basaltic component of mantle rock is transformed by pressure to eclogite or pyroxenite, the entire basaltic portion probably is melted within a narrow temperature range, but that above the level of that transformation plagioclase is melted selectively before pyroxene over a wide temperature range. The broad spectrum of high-alumina magmas may represent widely varying degrees of partial melting above the transformation level, whereas narrow-spectrum tholeiite magma may represent more complete melting beneath it.

  10. Control of oxidation potential for basalt repository simulation tests

    International Nuclear Information System (INIS)

    Borosilicate waste glass durability in simulated repository environments can be assessed by use of static tests in leach vessels fabricated of the representative geomedia. Control of the oxidation potential during the test simulates a basalt repository environment. Under very anoxic conditions (i.e. at negative Eh values), the interactions between basalt and SRP waste glass in silica-saturated basaltic groundwaters are the same as those of basalt and groundwater when no waste glass is present. The lack of significant leaching of ions from the waste glass and the lack of any significant changes in either the leached surfaces of glass or basalt under anoxic conditions suggests that the components of this system are at equilibrium when oxygen is absent. 11 refs., 4 figs

  11. Decompression-Induced Crystallization of Hydrous Basalt

    Science.gov (United States)

    Teasdale, R.; Brooker, R. A.

    2014-12-01

    Decompression-induced crystallization of hydrous basalt during magma ascent from 1.5 kb (150 MPa) is quantified using isothermal decompression TZM experiments. The starting composition is a synthetic glass based on the 1921 Kilauea basalt, with 1% H2O added. In all cases, the liquidus phase is aluminous spinel, followed by clinopyroxene, then plagioclase. The plagioclase liquidus temperatures for isobaric (equilibrium) experiments range from 1175°C (at 1.5 kb) to 1217°C (at 200b), which are 35-75°C hotter than predicted by MELTS (Ghiorso & Sack 1995). Experiments were decompressed at 1kb/hr and quenched at 800, 400, 200, or 100b for three temperatures (1160°, 1150°, and 1140°C). Plagioclase crystals formed during decompression have long axes that range from less than 1 micron to 20 microns. Increasing decompression yields larger plagioclase crystal sizes and aspect ratios for experiments at equal temperatures. However, the number of crystals does not vary systematically, indicating that crystallization is dominated by growth rather than nucleation during decompression. Plagioclase compositions for experiments were measured with University of Bristol's Electron Microprobe and the Hyperprobe with Field Emission Gun. Plagioclase compositions from equilibrium experiments (An60-An80) span the range of those from decompression experiments (An60-An73). Equilibrium experiments generated higher An compositions at lower pressures (500b) than at higher pressure (1.5kb) but do not systematically vary with temperature. Variations in plagioclase compositions are minimal above H2O saturation (100-200°C, based on Papale et al., 2006). Below H2O saturation, An content decreases slightly, by approximately 4% An. One application of this work is better characterization of groundmass crystallization in hydrous basalt as it traverses the conduit during eruption. This work also provides a means of distinguishing groundmass plagioclase related to decompression from crystals

  12. Heavy minerals in basalt maares and diatremes of South-Slovak alkali basaltic volcanic field

    International Nuclear Information System (INIS)

    A heavy mineral is one with a density that is greater than 2.8 g/cm3. Heavy mineral suites are usually used for determination of provenance and history of sedimentary and metamorphic rocks. The present study is focused on heavy minerals from pyroclastic rocks collected in maars and diatremes from the South Slovakian alkali basalt volcanic field. Practical part describes sampling strategy and methods of heavy mineral separation. Heavy minerals association from maar Hodejov and Filakovo as well as from diatremes Surice and Tachty were studied. The results indicates, that the samples are suitable for further research like geochronology, definition of possible heavy minerals source rocks and sedimentology analyses. This work will help us to get new information about alkali basalt volcanism in Southern Slovakia. (author)

  13. Study on lithogeochemistry of Middle Jurassic basalts from southern China represented by the Fankeng basalts from Yongding of Fujian Province

    Institute of Scientific and Technical Information of China (English)

    ZHOU Jincheng; JIANG Shaoyong; WANG Xiaolei; YANG Jinghong; ZHANG Mengqun

    2006-01-01

    There exists an E-W trending Middle Jurassic volcanic zone in southern China. The Fankeng basalts in the Yongding basin of Fujian Province are considered to be a typical example. The Fankeng basalts have TiO2 contents in the range of 1.92%-3.21%. They are classified as high-Ti basalts. They also have higher total Fe (averaging FeO*= 11.09%). The Middle Jurassic Fankeng basalts from southwestern Fujian have obvious distinctive lithogeochemical features from early Cretaceous basalts from southeastern coast of China. They have higher HFSE, such as Th, Nb, Ta, Zr and Ti. Their element ratios related with HFSE, such as Zr/Ba, La/Nb, La/Ta ,Zr/Y, Ti/Y, Ba/Nb, K/Ti and Rb/Zr are similar to those of OIB. The most samples have εNd(T) of -0.70-0.24, which are near chondrite. Some samples have higher εNd(T) of 1.87-3.55.Therefore, these basaltic magmas might be derived from depleted asthenospheric mantle. The lithogeochemical characteristics of the Fankeng basalts may be caused by interaction between asthenosphere and lithosphere at the time. The (Early-)Middle Jurassic basalts and gabbros from southeastern Hunan, southern Jiangxi and northern Guangdong provinces show similar geochemical features to those of the Fankeng basalts from the Yongding of Fujian. Occurrence of these OIB-type basalts in the area may be regarded as the petrological mark of upwelling of asthenosphere at the time. Upwelling of asthenosphere has led to tectonic extension and the formation of rifted basin in the area.

  14. Mineral chemistry of Pangidi basalt flows from Andhra Pradesh

    Indian Academy of Sciences (India)

    P V Nageswara Rao; P C Swaroop; Syed Karimulla

    2012-04-01

    This paper elucidates the compositional studies on clinopyroxene, plagioclase, titaniferous magnetite and ilmenite of basalts of Pangidi area to understand the geothermometry and oxybarometry conditions. Petrographic evidence and anorthite content (up to 85%) of plagioclase and temperature estimates of clinopyroxene indicate that the clinopyroxene is crystallized later than or together with plagioclase. The higher An content indicates that the parent magma is tholeiitic composition. The equilibration temperatures of clinopyroxene (1110–1190°C) and titaniferous magnetite and ilmenite coexisting mineral phases (1063–1103°C) are almost similar in lower basalt flow and it is higher for clinopyroxene (900–1110°C) when compared to titaniferous magnetite and ilmenite coexisting mineral phases (748–898°C) in middle and upper basalt flows. From this it can be inferred that the clinopyroxene is crystallized earlier than Fe–Ti oxide phases reequilibration, which indicates that the clinopyroxene temperature is the approximate eruption temperature of the present lava flows. The wide range of temperatures (900–1190°C) attained by clinopyroxene may point out that the equilibration of clinopyroxene crystals initiated from depth till closer to the surface before the melt erupted. Pangidi basalts follow the QFM buffer curve which indicates the more evolved tholeiitic composition. This suggests the parent tholeiitic magma suffered limited fractionation at high temperature under increasing oxygen fugacity in lower basalt flow and more fractionation at medium to lower temperatures under decreasing oxygen fugacity conditions during cooling of middle and upper basalt flows. The variation of oxygen fugacity indicates the oxidizing conditions for lower basalt flow (9.48–10.3) and extremely reducing conditions for middle (12.1–15.5) and upper basalt (12.4–15.54) flows prevailed at the time of cooling. Temperature vs. (FeO+Fe2O3)/(FeO+Fe2O3+MgO) data plots for present

  15. High water content in primitive continental flood basalts

    Science.gov (United States)

    Xia, Qun-Ke; Bi, Yao; Li, Pei; Tian, Wei; Wei, Xun; Chen, Han-Lin

    2016-01-01

    As the main constituent of large igneous provinces, the generation of continental flood basalts (CFB) that are characterized by huge eruption volume (>105 km3) within short time span (basaltic melts and the partition coefficient of H2O between cpx and basaltic melt. The arc-like H2O content (4.82 ± 1.00 wt.%) provides the first clear evidence that H2O plays an important role in the generation of CFB. PMID:27143196

  16. Basaltic volcanic episodes of the Yucca Mountain region

    International Nuclear Information System (INIS)

    The purpose of this paper is to summarize briefly the distribution and geologic characteristics of basaltic volcanism in the Yucca Mountain region during the last 10--12 Ma. This interval largely postdates the major period of silicic volcanism and coincides with and postdates the timing of major extensional faulting in the region. Field and geochronologic data for the basaltic rocks define two distinct episodes. The patterns in the volume and spatial distribution of these basaltic volcanic episodes in the central and southern part of the SNVF are used as a basis for forecasting potential future volcanic activity in vicinity of Yucca Mountain. 33 refs., 2 figs

  17. Pliocene Basaltic Volcanism in The East Anatolia Region (EAR), Turkey

    Science.gov (United States)

    Oyan, Vural; Özdemir, Yavuz; Keskin, Mehmet

    2016-04-01

    East Anatolia Region (EAR) is one of the high Plateau which is occurred with north-south compressional regime formed depending on continent-continent collision between Eurasia and Arabia plates (Şengör and Kidd, 1979). Recent studies have revealed that last oceanic lithosphere in the EAR have completely depleted to 20 million years ago based on fission track ages (Okay et al. 2010). Our initial studies suggest that extensively volcanic activity in the EAR peaked in the Pliocene and continued in the same productivity throughout Quaternary. Voluminous basaltic lava plateaus and basaltic lavas from local eruption centers occurred as a result of high production level of volcanism during the Pliocene time interval. In order to better understand the spatial and temporal variations in Pliocene basaltic volcanism and to reveal isotopic composition, age and petrologic evolution of the basaltic volcanism, we have started to study basaltic volcanism in the East Anatolia within the framework of a TUBITAK project (project number:113Y406). Petrologic and geochemical studies carried out on the Pliocene basaltic lavas indicate the presence of subduction component in the mantle source, changing the character of basaltic volcanism from alkaline to subalkaline and increasing the amount of spinel peridotitic melts (contributions of lithospheric mantle?) in the mantle source between 5.5-3.5 Ma. FC, AFC and EC-AFC modelings reveal that the while basaltic lavas were no or slightly influenced by crustal contamination and fractional crystallization, to more evolved lavas such as bazaltictrachyandesite, basalticandesite, trachybasalt might have been important processes. Results of our melting models and isotopic analysis data (Sr, Nd, Pb, Hf, 18O) indicate that the Pliocene basaltic rocks were derived from both shallow and deep mantle sources with different melting degrees ranging between 0.1 - 4 %. The percentage of spinel seems to have increased in the mantle source of the basaltic

  18. Spreading and collapse of big basaltic volcanoes

    Science.gov (United States)

    Puglisi, Giuseppe; Bonforte, Alessandro; Guglielmino, Francesco; Peltier, Aline; Poland, Michael

    2016-04-01

    Among the different types of volcanoes, basaltic ones usually form the most voluminous edifices. Because volcanoes are growing on a pre-existing landscape, the geologic and structural framework of the basement (and earlier volcanic landforms) influences the stress regime, seismicity, and volcanic activity. Conversely, the masses of these volcanoes introduce a morphological anomaly that affects neighboring areas. Growth of a volcano disturbs the tectonic framework of the region, clamps and unclamps existing faults (some of which may be reactivated by the new stress field), and deforms the substratum. A volcano's weight on its basement can trigger edifice spreading and collapse that can affect populated areas even at significant distance. Volcano instability can also be driven by slow tectonic deformation and magmatic intrusion. The manifestations of instability span a range of temporal and spatial scales, ranging from slow creep on individual faults to large earthquakes affecting a broad area. In the frame of MED-SVU project, our work aims to investigate the relation between basement setting and volcanic activity and stability at three Supersite volcanoes: Etna (Sicily, Italy), Kilauea (Island of Hawaii, USA) and Piton de la Fournaise (La Reunion Island, France). These volcanoes host frequent eruptive activity (effusive and explosive) and share common features indicating lateral spreading and collapse, yet they are characterized by different morphologies, dimensions, and tectonic frameworks. For instance, the basaltic ocean island volcanoes of Kilauea and Piton de la Fournaise are near the active ends of long hotspot chains while Mt. Etna has developed at junction along a convergent margin between the African and Eurasian plates and a passive margin separating the oceanic Ionian crust from the African continental crust. Magma supply and plate velocity also differ in the three settings, as to the sizes of the edifices and the extents of their rift zones. These

  19. Calcium Sulfate in Atacama Desert Basalt: A Possible Analog for Bright Material in Adirondack Basalt, Gusev Crater

    Science.gov (United States)

    Sutter, B.; Golden, D. C.; Amundson, R.; Chong-Diaz, G.; Ming, D. W.

    2007-01-01

    The Atacama Desert in northern Chile is one of the driest deserts on Earth (calcium sulfate (Ca-SO4) which was later confirmed by SEM/EDS analysis. This work examines the Ca-SO4 of Atacama basalt in an effort to provide insight into the possible nature of the bright material in the Adirondack basalt of Gusev Crater. The objectives of this work are to (i) discuss variations in Ca-SO4 crystal morphology in the vesicles and (ii) examine the Ca-SO4 interaction(s) with the basalt interior.

  20. A note on incipient spilitisation of central Indian basin basalts

    Digital Repository Service at National Institute of Oceanography (India)

    Karisiddaiah, S.M.; Iyer, S.D.

    Rocks dredged in the vicinity of the 79 degrees E fracture zone, in the Central Indian Basin, are sub-alkaline basalts, which are regarded as precursors to spilites. The minerals identified are mainly albitic plagioclase, augite, olivine, and less...

  1. Alteration of basaltic glasses from the Central Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.

    Textural, mineralogical and compositional characteristics of basaltic glasses from the Central Indian Ocean show them to be altered to varying extents through their interaction with the seawater, resulting in the formation of palagonite. The major...

  2. Two new basaltic asteroids in the Outer Main Belt

    CERN Document Server

    Duffard, R

    2007-01-01

    The identification of other basaltic objects in the asteroid belt is mandatory to explain the diversity in the collection of basaltic meteorites. This diversity requires more than one differentiated parent body, a fact that is consistent with the diversity of differentiated parent bodies implied by the iron meteorites. Based on a list of previously identified candidate basaltic (V-type) asteroids, two asteroids in the outer main belt, (7472) Kumakiri and (10537) 1991 RY16, were spectroscopically observed during an observational run in Calar Alto Observatory, Spain. We confirm the V-type character of these two asteroids that, together with (1459) Magnya, become the only known traces of basaltic found in the outer main belt up to now. We also demonstrate that the searching for candidate V-type asteroids using a photometric survey, like the Sloan Digital Sky Survey, produces reliable results.

  3. Petrology of the Apollo 12 pigeonite basalt suite

    International Nuclear Information System (INIS)

    A comparative petrologic study of the Apollo 12 pigeonite basalt suite has been undertaken to answer the following questions: (1) What are the textural and petrologic variations within the pigeonite suite. (2) Are these variations consistent with the hypothesis that the pigeonite basalts are related by crystal fractionation to the olivine basalts. Texturally, the pigeonite basalts range from porphyritic samples with a very fine-grained variolitic groundmass to coarse-grained microgabbro samples with ophitic to graphic textures. The abundances of olivine and Cr-spinel continuously decrease with increasing grain size, whereas the abundances of plagioclase and ilmenite steadily increase. Petrologically, increasing grain size is accompanied by increased Ca in plagioclase, increased Fe in pyroxene, olivine, and spinel, and less Al, Ti, and Cr in pyroxene. All of these changes, including the differences in bulk chemistry can be explained by near-surface fractionation of olivine, pigeonite, and Cr-spinel with the compositions of the observed phenocryst phases

  4. Petrography and chemistry of basalts from the Carlsberg ridge

    Digital Repository Service at National Institute of Oceanography (India)

    Banerjee, R.; Iyer, S.D

    The petrography of the basalts collected in dredge hauls from the Carlsberg Ridge (3 degrees 37'N and 64 degrees 07'E) show systematic variations in their textural and mineralogical assemblages, from an outermost vitreous glassy to a holocrystalline...

  5. Basaltic glass: alteration mechanisms and analogy with nuclear waste glasses

    International Nuclear Information System (INIS)

    A synthetic basaltic glass was dissolved experimentally at 90 deg. C under static conditions in initially pure water. The basaltic glass dissolution rates measured near and far from equilibrium were compared with those of SON 68 nuclear waste glass. Experimental and literature data notably suggested that the alteration mechanisms for the two glasses are initially similar. Under steady-state concentration conditions, the alteration rate decreased of four orders of magnitude below the initial rate (r0). The same alteration rate decrease was observed for basaltic and nuclear glass. These findings tend to corroborate the analogy of the two glasses alteration kinetics. The effect of dissolved silica in solution, observed through dynamic leach tests with silicon-rich solutions, cannot account for the significant drop in the basaltic glass kinetics. Hence, a protective effect of the glass alteration film was assumed and experimentally investigated. Moreover, modeling with LIXIVER argue for a significant effect of diffusion in the alteration gel

  6. Geochemical characterization of oceanic basalts using artificial neural network

    Digital Repository Service at National Institute of Oceanography (India)

    Das, P.; Iyer, S.D.

    method is specifically needed to identify the OFB as normal (N-MORB), enriched (E-MORB) and ocean island basalts (OIB). Artificial Neural Network (ANN) technique as a supervised Learning Vector Quantisation (LVQ) is applied to identify the inherent...

  7. Basalt waste isolation project institutional activities

    International Nuclear Information System (INIS)

    The Basalt Waste Isolation Project (BWIP) was established in 1976 as part of the National Waste Terminal Storage Program, and characterization studies to evaluate the Hanford Site have been ongoing since that time. In early 1983, the Nuclear Waste Policy Act (NWPA) became law and established the Office of Civilian Radioactive Waste Management, which includes the BWIP as part of that program. This paper describes the interaction process required by the NWPA and has been ongoing for the past 3 to 4 yr with the State of Washington, Yakima Indian Nation, Confederated Tribes of the Umatilla Indian Reservation, Nez Perce Tribe, other federal agencies, city and county governments, the public and news media, and many other organizations. It identifies the issues that the state and the US Department of Energy (DOE) have noted during the consultation and cooperation (C and C) process. In addition, this paper covers the site recommendation/nomination process for the first repository, including number of sites, location, and types of media being investigated. It covers the site recommendation/nomination process for the second repository, including types of media and where those investigations are being performed. Discussion covering the OCRWM program strategy, which includes documentation being prepared for site recommendation/nomination, site investigations required to determine site suitability, the licensing process for the first repository, etc., are provided

  8. Radiolytic Hydrogen Production in the Subseafloor Basaltic Aquifer.

    Science.gov (United States)

    Dzaugis, Mary E; Spivack, Arthur J; Dunlea, Ann G; Murray, Richard W; D'Hondt, Steven

    2016-01-01

    Hydrogen (H2) is produced in geological settings by dissociation of water due to radiation from radioactive decay of naturally occurring uranium ((238)U, (235)U), thorium ((232)Th) and potassium ((40)K). To quantify the potential significance of radiolytic H2 as an electron donor for microbes within the South Pacific subseafloor basaltic aquifer, we use radionuclide concentrations of 43 basalt samples from IODP Expedition 329 to calculate radiolytic H2 production rates in basement fractures. The samples are from three sites with very different basement ages and a wide range of alteration types. U, Th, and K concentrations vary by up to an order of magnitude from sample to sample at each site. Comparison of our samples to each other and to the results of previous studies of unaltered East Pacific Rise basalt suggests that significant variations in radionuclide concentrations are due to differences in initial (unaltered basalt) concentrations (which can vary between eruptive events) and post-emplacement alteration. However, there is no clear relationship between alteration type and calculated radiolytic yields. Local maxima in U, Th, and K produce hotspots of H2 production, causing calculated radiolytic rates to differ by up to a factor of 80 from sample to sample. Fracture width also greatly influences H2 production, where microfractures are hotspots for radiolytic H2 production. For example, H2 production rates normalized to water volume are 190 times higher in 1 μm wide fractures than in fractures that are 10 cm wide. To assess the importance of water radiolysis for microbial communities in subseafloor basaltic aquifers, we compare electron transfer rates from radiolysis to rates from iron oxidation in subseafloor basalt. Radiolysis appears likely to be a more important electron donor source than iron oxidation in old (>10 Ma) basement basalt. Radiolytic H2 production in the volume of water adjacent to a square cm of the most radioactive SPG basalt may support as

  9. Tensile tests of basalt FRP rebars using chemical anchorages

    OpenAIRE

    Neagoe, Catalin Andrei; Gil Espert, Lluís

    2013-01-01

    In the current report are analyzed the experimental results of initial tensile tests of Basalt FRP (BFRP) rebars provided by VSL. The investigation was conducted in the laboratory of CER LITEM. Objectives of the study: to determine the tensile strengths of 6 mm and 8 mm basalt FRP rebars, and to determine what type of test setup and anchorage system is best suited for future tensile tests of BFRP bars.

  10. Tensile tests of basalt FRP rebars using mechanical anchorages

    OpenAIRE

    Neagoe, Catalin Andrei; Gil Espert, Lluís

    2013-01-01

    In the current report are analyzed the experimental results of initial tensile tests of Basalt FRP (BFRP) rebars provided by VSL. The investigation was conducted on the 19th of February 2013, in the laboratory of CER LITEM. Objectives of the study: to determine the tensile strengths of 6 mm and 8 mm basalt FRP rebars, and to determine what type of test setup and anchorage system is best suited for future tensile tests of BFRP bars.

  11. Radiolytic hydrogen production in the subseafloor basaltic aquifer

    Directory of Open Access Journals (Sweden)

    Mary E Dzaugis

    2016-02-01

    Full Text Available Hydrogen (H2 is produced in geological settings by dissociation of water due to radiation from radioactive decay of naturally occurring uranium (238U, 235U, thorium (232Th and potassium (40K. To quantify the potential significance of radiolytic H2 as an electron donor for microbes within the South Pacific subseafloor basaltic aquifer, we use radionuclide concentrations of 43 basalt samples from IODP Expedition 329 to calculate radiolytic H2 production rates in basement fractures. The samples are from three sites with very different basement ages and a wide range of alteration types. U, Th and K concentrations vary by up to an order of magnitude from sample to sample at each site. Comparison of our samples to each other and to the results of previous studies of unaltered East Pacific Rise basalt suggests that significant variations in radionuclide concentrations are due to differences in initial (unaltered basalt concentrations (which can vary between eruptive events and post-emplacement alteration. In our samples, there is no clear relationship between alteration type and calculated radiolytic yields. Local maxima in U, Th, and K produce hotspots of H2 production, causing calculated radiolytic rates to differ by up to a factor of 80 from sample to sample. Fracture width also greatly influences H2 production, where microfractures are hotspots for radiolytic H2 production. For example, H2 production rates normalized to water volume are 190 times higher in 1 μm wide fractures than in fractures that are 10 cm wide. To assess the importance of water radiolysis for microbial communities in subseafloor basaltic aquifers, we compare electron transfer rates from radiolysis to rates from iron oxidation in subseafloor basalt. Radiolysis appears likely to be a more important electron donor source than iron oxidation in old (>10 Ma basement basalt. Radiolytic H2 production in the volume of water adjacent to a square cm of the most radioactive SPG basalt may

  12. Radiolytic Hydrogen Production in the Subseafloor Basaltic Aquifer

    Science.gov (United States)

    Dzaugis, Mary E.; Spivack, Arthur J.; Dunlea, Ann G.; Murray, Richard W.; D’Hondt, Steven

    2016-01-01

    Hydrogen (H2) is produced in geological settings by dissociation of water due to radiation from radioactive decay of naturally occurring uranium (238U, 235U), thorium (232Th) and potassium (40K). To quantify the potential significance of radiolytic H2 as an electron donor for microbes within the South Pacific subseafloor basaltic aquifer, we use radionuclide concentrations of 43 basalt samples from IODP Expedition 329 to calculate radiolytic H2 production rates in basement fractures. The samples are from three sites with very different basement ages and a wide range of alteration types. U, Th, and K concentrations vary by up to an order of magnitude from sample to sample at each site. Comparison of our samples to each other and to the results of previous studies of unaltered East Pacific Rise basalt suggests that significant variations in radionuclide concentrations are due to differences in initial (unaltered basalt) concentrations (which can vary between eruptive events) and post-emplacement alteration. However, there is no clear relationship between alteration type and calculated radiolytic yields. Local maxima in U, Th, and K produce hotspots of H2 production, causing calculated radiolytic rates to differ by up to a factor of 80 from sample to sample. Fracture width also greatly influences H2 production, where microfractures are hotspots for radiolytic H2 production. For example, H2 production rates normalized to water volume are 190 times higher in 1 μm wide fractures than in fractures that are 10 cm wide. To assess the importance of water radiolysis for microbial communities in subseafloor basaltic aquifers, we compare electron transfer rates from radiolysis to rates from iron oxidation in subseafloor basalt. Radiolysis appears likely to be a more important electron donor source than iron oxidation in old (>10 Ma) basement basalt. Radiolytic H2 production in the volume of water adjacent to a square cm of the most radioactive SPG basalt may support as many as

  13. Basalt: Biologic Analog Science Associated with Lava Terrains

    Science.gov (United States)

    Lim, D. S. S.; Abercromby, A.; Kobs-Nawotniak, S. E.; Kobayashi, L.; Hughes, S. S.; Chappell, S.; Bramall, N. E.; Deans, M. C.; Heldmann, J. L.; Downs, M.; Cockell, C. S.; Stevens, A. H.; Caldwell, B.; Hoffman, J.; Vadhavk, N.; Marquez, J.; Miller, M.; Squyres, S. W.; Lees, D. S.; Fong, T.; Cohen, T.; Smith, T.; Lee, G.; Frank, J.; Colaprete, A.

    2015-12-01

    This presentation will provide an overview of the BASALT (Biologic Analog Science Associated with Lava Terrains) program. BASALT research addresses Science, Science Operations, and Technology. Specifically, BASALT is focused on the investigation of terrestrial volcanic terrains and their habitability as analog environments for early and present-day Mars. Our scientific fieldwork is conducted under simulated Mars mission constraints to evaluate strategically selected concepts of operations (ConOps) and capabilities with respect to their anticipated value for the joint human and robotic exploration of Mars. a) Science: The BASALT science program is focused on understanding habitability conditions of early and present-day Mars in two relevant Mars-analog locations (the Southwest Rift Zone (SWRZ) and the East Rift Zone (ERZ) flows on the Big Island of Hawai'i and the eastern Snake River Plain (ESRP) in Idaho) to characterize and compare the physical and geochemical conditions of life in these environments and to learn how to seek, identify, and characterize life and life-related chemistry in basaltic environments representing these two epochs of martian history. b) Science Operations: The BASALT team will conduct real (non-simulated) biological and geological science at two high-fidelity Mars analogs, all within simulated Mars mission conditions (including communication latencies and bandwidth constraints) that are based on current architectural assumptions for Mars exploration missions. We will identify which human-robotic ConOps and supporting capabilities enable science return and discovery. c) Technology: BASALT will incorporate and evaluate technologies in to our field operations that are directly relevant to conducting the scientific investigations regarding life and life-related chemistry in Mars-analogous terrestrial environments. BASALT technologies include the use of mobile science platforms, extravehicular informatics, display technologies, communication

  14. High water content in primitive continental flood basalts

    Science.gov (United States)

    Xia, Qun-Ke; Bi, Yao; Li, Pei; Tian, Wei; Wei, Xun; Chen, Han-Lin

    2016-05-01

    As the main constituent of large igneous provinces, the generation of continental flood basalts (CFB) that are characterized by huge eruption volume (>105 km3) within short time span (partition coefficient of H2O between cpx and basaltic melt. The arc-like H2O content (4.82 ± 1.00 wt.%) provides the first clear evidence that H2O plays an important role in the generation of CFB.

  15. Evaluation of basalt flows as a waste isolation medium

    International Nuclear Information System (INIS)

    The Basalt Waste Isolation Program within Rockwell Hanford Operations has the responsibility of conducting studies to determine the feasibility of using the basalt formations, which are in the Pacific Northwest and the Hanford Site, as a site for terminal storage of commercial nuclear waste. This program is divided into systems integration, geology, hydrology, engineered barrier studies, engineering testing, and the construction of a near-surface test facility. Brief descriptions of each task are presented

  16. Insulation from basaltic stamp sand. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Williams, F. D.

    1981-04-01

    A Midwest Appropriate Technology Grant was awarded to determine the technical and economic feasibility of producing mineral-fiber insulation directly from extensive deposits of basaltic sand produced during former mining and milling operations in the Keweenaw Peninsula region of Michigan's Upper Peninsula. The amounts of local basaltic sands available and representative chemical compositions were determined. The variation of viscosity with temperature and chemical composition was estimated. Samples were melted and either pulled or blown into fiber. In all cases fiber could be made with a reasonable tensile strength to ensure usefulness. It was concluded that it was technically feasible to produce fibers from basaltic stamp sands of the Upper Peninsula of Michigan. A technical feasibility study using published data, a cost and design analysis of a basalt fiber production plant, a market survey of fiber needs, and an economic analysis for investing in a basalt fiber venture was undertaken. These studies concluded that the local production of basaltic insulation was both feasible and economically reasonable. It was suggested that the plant be located in a region of greater population density with lower utility costs. A representative one-third of these studies is included as appendices A, B, C, and D.

  17. Geochemical characterization of oceanic basalts using Artificial Neural Network

    Directory of Open Access Journals (Sweden)

    Iyer Sridhar D

    2009-12-01

    Full Text Available Abstract The geochemical discriminate diagrams help to distinguish the volcanics recovered from different tectonic settings but these diagrams tend to group the ocean floor basalts (OFB under one class i.e., as mid-oceanic ridge basalts (MORB. Hence, a method is specifically needed to identify the OFB as normal (N-MORB, enriched (E-MORB and ocean island basalts (OIB. We have applied Artificial Neural Network (ANN technique as a supervised Learning Vector Quantisation (LVQ to identify the inherent geochemical signatures present in the Central Indian Ocean Basin (CIOB basalts. A range of N-MORB, E-MORB and OIB dataset was used for training and testing of the network. Although the identification of the characters as N-MORB, E-MORB and OIB is completely dependent upon the training data set for the LVQ, but to a significant extent this method is found to be successful in identifying the characters within the CIOB basalts. The study helped to geochemically delineate the CIOB basalts as N-MORB with perceptible imprints of E-MORB and OIB characteristics in the form of moderately enriched rare earth and incompatible elements. Apart from the fact that the magmatic processes are difficult to be deciphered, the architecture performs satisfactorily.

  18. Sensitivity of geochemical monitoring for CO2 sequestration in basalt

    Science.gov (United States)

    Zakharova, N. V.; Goldberg, D.; Herron, M.; Grau, J.

    2010-12-01

    Continental flood basalts is a promising target for carbon dioxide (CO2) storage due to high storage capacity, presence of seals, and potential for geochemical trapping which results in binding CO2 into stable carbonate minerals. The success of long-term CO2 storage in igneous rocks highly depends on our ability to monitor mineralization under in situ conditions. The direct chemistry measurements on cores are costly and typically do not provide continuous coverage. In this study we investigate the potential of borehole geochemical logging for monitoring of CO2 mineralization in basalt. Neutron-induced capture gamma ray spectroscopy tools allow obtaining in-situ concentration logs for up to 10 major elements which can be used to construct a quantitative mineralogical model. While this usually provides good bulk mineralogy estimates, detecting small-volume mineral alteration in volcanic rocks remains challenging, especially if borehole conditions are poor. We analyze Schlumberger Elemental Capture Spectroscopy logs and chemical core analysis from the pilot CO2 sequestration project in the Columbia River flood basalt. We use the geochemical spectroscopy logs and quantitative modeling to quantify their sensitivity to secondary mineralization in basalt. We apply statistical analysis to explain the variance in elemental concentrations (and other logs) and establish detection limits for various mineral alteration products in basalt. We use these results to evaluate monitoring capabilities and limitations of geochemical logging for CO2 mineralization after underground injection in basalt and suggest areas for future research.

  19. A basalt trigger for the 1991 eruptions of Pinatubo volcano?

    Science.gov (United States)

    Pallister, J.S.; Hoblitt, R.P.; Reyes, A.G.

    1992-01-01

    THE eruptive products of calc-alkaline volcanos often show evidence for the mixing of basaltic and acid magmas before eruption (see, for example, refs 1, 2). These observations have led to the suggestion3 that the injection of basaltic magma into the base of a magma chamber (or the catastrophic overturn of a stably stratified chamber containing basaltic magma at its base) might trigger an eruption. Here we report evidence for the mixing of basaltic and dacitic magmas shortly before the paroxysmal eruptions of Pinatubo volcano on 15 June 1991. Andesitic scoriae erupted on 12 June contain minerals and glass with disequilibrium compositions, and are considerably more mafic than the dacitic pumices erupted on 15 June. Differences in crystal abundance and glass composition among the pumices may arise from pre-heating of the dacite magma by the underlying basaltic liquid before mixing. Degassing of this basaltic magma may also have contributed to the climatologically important sulphur dioxide emissions that accompanied the Pinatubo eruptions.

  20. The Distribution of Basaltic Asteroids in the Main Belt

    CERN Document Server

    Moskovitz, Nicholas A; Gaidos, Eric; Willman, Mark; Nesvorny, David; Fevig, Ronald; Ivezic, Zeljko

    2008-01-01

    We present the observational results of a survey designed to target and detect asteroids whose colors are similar to those of Vesta family members and thus may be considered as candidates for having a basaltic composition. Fifty basaltic candidates were selected with orbital elements that lie outside of the Vesta dynamical family. Optical and near-infrared spectra were used to assign a taxonomic type to 11 of the 50 candidates. Ten of these were spectroscopically confirmed as V-type asteroids, suggesting that most of the candidates are basaltic and can be used to constrain the distribution of basaltic material in the Main Belt. Using our catalog of V-type candidates and the success rate of the survey, we calculate unbiased size-frequency and semi-major axis distributions of V-type asteroids. These distributions, in addition to an estimate for the total mass of basaltic material, suggest that Vesta was the predominant contributor to the basaltic asteroid inventory of the Main Belt, however scattered planetesim...

  1. Basaltic Lava Flow vs. Welded Basaltic Ignimbrite: Determining the Depositional Nature of a Volcanic Flow in the Akaroa Volcanic Complex

    Science.gov (United States)

    Sexton, E. A.; Hampton, S.

    2014-12-01

    Welded basaltic ignimbrites are one of the rarest forms of ignimbrites found on Earth and can often have characteristics that are indistinguishable from those of basaltic lava flows. This study evaluates a basaltic volcanic flow in a coastal cliff sequence in Raupo Bay, Akaroa Volcanic Complex, Banks Peninsula, New Zealand. The Raupo Bay coastal cliff sequence is comprised of 4 units, termed L1, L2, L3, and A, capped by loess. L1 and L2 are basaltic lavas, L3 proximal scoria deposits, which thin inland, and Unit A, a flow with unusual characteristics, which is the focus of this study. Field mapping, sampling, geochemical analysis and petrology were utilized to characterize units. Further detailed structural analysis of Unit A was completed, to determine the nature of the basal contact, variations in welding throughout the unit and the relationship of the layer to the underlying topography. From these analyses it was found: Unit A is thickest in a paleo-valley and thins and mantles higher topography, welding in the unit increases downwards forming topographic controlled columnar jointing, the top of the unit is brecciated and grades into the lower welded/jointed portion, the basal contact is sharp overlying a regional airfall deposit, the unit has a notably distinct geochemical composition from the underlying stratigraphic units, Unit A contains flattened and sheared scoria clasts, has aligned bubbles, and lava lithics. Further thin section analysis of Unit A identified flattened clast boundaries and microlite rimming around phenocrysts. In comparing these features to previous studies on basaltic lavas and ignimbrites it is hypothesized that Unit A is a welded basaltic ignimbrite that was channelized by paleo-topography on the outer flanks of the Akaroa Volcanic Complex. This study furthers the characterization of basaltic ignimbrites and is the first to recognize basaltic ignimbrites within the Akaroa Volcanic Complex.

  2. Vapor segregation and loss in basaltic melts

    Science.gov (United States)

    Edmonds, M.; Gerlach, T.M.

    2007-01-01

    Measurements of volcanic gases at Pu'u'O??'o??, Kilauea Volcano, Hawai'i, reveal distinct degassing regimes with respect to vapor segregation and loss during effusive activity in 2004-2005. Three styles of vapor loss are distinguished by the chemical character of the emitted volcanic gases, measured by open path Fourier transform infrared spectroscopy: 1 persistent continuous gas emission, 2 gas piston events, and 3 lava spattering. Persistent continuous gas emission is associated with magma ascent and degassing beneath the crater vents, then eruption of the degassed magma from flank vents. Gas piston events are the result of static gas accumulation at depths of 400-900 m beneath Pu'u'O??'o??. A CO2-rich gas slug travels up the conduit at a few meters per second, displacing magma as it expands. Lava spattering occurs due to dynamic bubble coalescence in a column of relatively stagnant magma. The Large gas bubbles are H2O rich and are generated by open-system degassing at depths of segregation in basaltic melts, but their implications differ. Accumulation and segregation of CO2-rich vapor at depth does not deplete the melt of H2O (required to drive lava fountains near to the surface) and therefore gas piston events can occur interspersed with lava fountaining activity. Lava spattering, however, efficiently strips H2O-rich vapor from magma beneath the crater vents; the magma must then erupt effusively from vents on the flank of the cone. ?? 2007 The Geological Society of America.

  3. Basalt Waste Isolation Project Reclamation Support Project:

    Energy Technology Data Exchange (ETDEWEB)

    Brandt, C.A.; Rickard, W.H. Jr.; Cadoret, N.A.

    1992-06-01

    The Basalt Waste Isolation Project (BWIP) Reclamation Support Project began in the spring of 1988 by categorizing sites distributed during operations of the BWIP into those requiring revegetation and those to be abandoned or transferred to other programs. The Pacific Northwest Laboratory's role in this project was to develop plans for reestablishing native vegetation on the first category of sites, to monitor the implementation of these plans, to evaluate the effectiveness of these efforts, and to identify remediation methods where necessary. The Reclamation Support Project focused on three major areas: geologic hydrologic boreholes, the Exploratory Shaft Facility (ESF), and the Near-Surface Test Facility (NSTF). A number of BWIP reclamation sites seeded between 1989 and 1990 were found to be far below reclamation objectives. These sites were remediated in 1991 using various seedbed treatments designed to rectify problems with water-holding capacity, herbicide activity, surficial crust formation, and nutrient imbalances. Remediation was conducted during November and early December 1991. Sites were examined on a monthly basis thereafter to evaluate plant growth responses to these treatments. At all remediation sites early plant growth responses to these treatments. At all remediation sites, early plant growth far exceeded any previously obtained using other methods and seedbed treatments. Seeded plants did best where amendments consisted of soil-plus-compost or fertilizer-only. Vegetation growth on Gable Mountain was less than that found on other areas nearby, but this difference is attributed primarily to the site's altitude and north-facing orientation.

  4. Space-Time-Isotopic Trends of Snake River Plain Basalts

    Science.gov (United States)

    Jean, M. M.; Hanan, B. B.; Shervais, J. W.

    2010-12-01

    The Snake River Plain (SRP) volcanic province is an 800 km track of basalt extending from the Owyhee Plateau to its current terminus, the Yellowstone Plateau. It is one of several late-Tertiary magmatic terranes that also include the Cascades magmatic arc, the Columbia River basalts, and the Oregon Plateau basalts; all of which are adjacent to the Basin and Range Province extensional system (Hughes and McCurry, 2002). This province represents the track of the Yellowstone plume and consists of basalt that is compositionally similar to ocean-island basalt. This basalt overlies a series of rhyolitic eruptive centers (overlapping caldera complexes, ignimbrites, and caldera-filling eruptions) that signal the arrival of the plume head (Christiansen, 2001) and herald the onset of plume-related rhyolitic and basaltic volcanism (Pierce et al., 2002). Observed within the SRP are two basalt types: the dominant low-K olivine tholeiites and less common high-K alkaline basalts. We report new Sr-, Nd-, and Pb-isotopic analyses of these two basalt types from all three SRP provinces: eastern, central, and western. Low-K tholeiites are enriched in 143Nd/144Nd and 86Sr/87Sr and forms a quasi-linear array in Pb-isotope space, along with Craters of the Moon and eastern SRP basalts. High-K lavas are found largely in the western plain, and have a uniquely different isotopic signature. They are depleted in 143Nd/144Nd and 86Sr/87Sr, relative to the low-K tholeiites, and plot closer to the BSE component of Zindler and Hart (1986). They also share the same Pb-isotopic space with high-K basalts from Smith Prairie (Boise River Group 2 of Vetter and Shervais, 1992). One low-K tholeiite - Eureka North, plots with these high alkali basalts. Mass balance models have demonstrated an increasing plume component from the Yellowstone caldera in the east to the craton edge in the west. The lavas analyzed in this study conform remarkably to this model. The mass fraction of plume component in western

  5. Surface oxidization-reduction reactions in Columbia Plateau basalts

    International Nuclear Information System (INIS)

    Results are presented which define principal oxidation-reduction reactions expected between ground water and iron in the Umtanum and Cohassett basalt flows of south central Washington. Data include kinetics of aqueous iron speciation, rates of O2 uptake and nature of oxyhydroxide precipitates. Such data are important in predicting behavior of radionuclides in basalt aquifers including determination of valence states, speciation, solubility, sorption, and coprecipitation on iron oxyhydroxide substrates and colloids. Analyses of the basalt by XPS indicates that ferrous iron is oxidized to ferric iron on the surface and that the total iron decreases as a function of pH during experimental weathering. Iron oxyhydroxide phases did not form surface coating on basalt surfaces but rather nucleated as separate plases in solution. No significant increases in Cs or Sr sorption were observed with increased weathering of the basalt. Concurrent increases in Fe(II) and decreases in Fe(III) in slightly to moderately acid solutions indicated continued oxidization of ferrous iron in the basalt. At neutral to basic pH, Fe(II) was strongly sorbed onto the basalt surface (Kd = 6.5 x 10-3 1 x m2) resulting in low dissolved concentrations even under anoxic conditions. The rate of O2 uptake increased with decreasing pH. Diffusion rates (-- 10-14 cm2 x s-1), calculated using a one-dimensional analytical model, indicate grain boundary diffusion. Comparisons of Eh values calculated by Pt electrode, dissolved O2 and Fe(II)/Fe(III) measurements showed considerable divergence, with the ferric-ferrous couple being the preferred method of estimating Eh

  6. Basalt here, basalt there: Constraining the basaltic nature of eight Vp-type asteroids in the inner and outer main asteroid belt

    Science.gov (United States)

    Hardersen, Paul Scott; Reddy, Vishnu

    2016-10-01

    The distribution and abundance of basaltic material in the main asteroid belt has multiple implications that impact our understanding of the physical and thermal conditions that existed in the inner solar system during the formation epoch about 4.6 Gyr ago. Subjects impacted by a more accurate basaltic asteroid inventory include the efficacy of current inner solar system heating model predictions (Al-26 and T Tauri induction heating), the existence of differentiated parent bodies other than (4) Vesta, the dispersion efficiency of Vestoids by YORP forces, and the predictive ability of the V-taxonomy in predicting a basaltic surface composition. This work reports on a continuation of an effort to better constrain the basaltic asteroid population in the main asteroid belt with the goal of observing about 650 Vp-type asteroids. This work focuses on two populations: a) those Vp-classified asteroids (Carvano et al., 2010) in the spatial vicinity of (4) Vesta (candidate Vestoids) in the inner main belt, and b) Vp-classified asteroids in the outer main belt beyond 2.5 AU. Thus far, 23 Vp-type asteroids and candidate Vestoids have been observed and analyzed, which are all strongly suggestive of a basaltic surface composition (Hardersen et al., 2014, 2015, 2016 (in preparation)). However, unpublished work is beginning to show that the Vp taxonomic class is less accurate in its ability to identify basaltic surface compositions in outer-belt Vp-type asteroids. We report here on an additional set of Vp-type asteroids that were observed at the NASA Infrared Telescope Facility (IRTF) in December 2015 and January 2016. All observations were obtained with the SpeX spectrograph in prism mode with spectral range from 0.7 to 2.5 microns. They include (4900) Maymelou, (7302) 1993 CQ, (9064) Johndavies, (9531) Jean-Luc, (11341) Babbage, (17480) 1991 PE10, (20171) 1996 WC2, and (25849) 2000 ET107. We present average near-infrared (NIR) reflectance spectra of each asteroid, determine the

  7. Effect of carbon nanotube addition on the wear behavior of basalt/epoxy woven composites.

    Science.gov (United States)

    Kim, M T; Rhee, K Y; Lee, B H; Kim, C J

    2013-08-01

    The effect of acid-treated carbon nanotube (CNT) addition on the wear and dynamic mechanical thermal properties of basalt/epoxy woven composites was investigated in this study. Basalt/CNT/epoxy composites were fabricated by impregnating woven basalt fibers into epoxy resin mixed with 1 wt% CNTs which were acid-treated. Wear and DMA (dynamic mechanical analyzer) tests were performed on basalt/epoxy composites and basalt/CNT/epoxy composites. The results showed that the addition of the acid-treated CNTs improved the wear properties of basalt/epoxy woven composites. Specifically, the friction coefficient of the basalt/epoxy composite was stabilized in the range of 0.5-0.6 while it fell in the range of 0.3-0.4 for basalt/CNT/epoxy composites. The wear volume loss of the basalt/CNT/epoxy composites was approximately 68% lower than that of the basalt/epoxy composites. The results also showed that the glass transition temperature of basalt/CNT/epoxy composites was higher than that of basalt/epoxy composites. The improvement of wear properties of basalt/epoxy composites by the addition of acid-treated CNTs was caused by the homogeneous load transfer between basalt fibers and epoxy matrix due to the reinforcement of CNTs.

  8. Preliminary Hydrogeologic Characterization Results from the Wallula Basalt Pilot Study

    Energy Technology Data Exchange (ETDEWEB)

    B.P. McGrail; E. C. Sullivan; F. A. Spane; D. H. Bacon; G. Hund; P. D. Thorne; C. J. Thompson; S. P. Reidel; F. S. Colwell

    2009-12-01

    The DOE's Big Sky Regional Carbon Sequestration Partnership has completed drilling the first continental flood basalt sequestration pilot borehole to a total depth (TD) of 4,110 feet on the Boise White Paper Mill property at Wallula, Washington. Site suitability was assessed prior to drilling by the 2007-2008 acquisition, processing and analysis of a four-mile, five-line three component seismic swath, which was processed as a single data-dense line. Analysis of the seismic survey data indicated a composite basalt formation thickness of {approx}8,000 feet and absence of major geologic structures (i.e., faults) along the line imaged by the seismic swath. Drilling of Wallula pilot borehole was initiated on January 13, 2009 and reached TD on April 6, 2009. Based on characterization results obtained during drilling, three basalt breccia zones were identified between the depth interval of 2,716 and 2,910 feet, as being suitable injection reservoir for a subsequent CO2 injection pilot study. The targeted injection reservoir lies stratigraphically below the massive Umtanum Member of the Grande Ronde Basalt, whose flow-interior section possesses regionally recognized low-permeability characteristics. The identified composite injection zone reservoir provides a unique and attractive opportunity to scientifically study the reservoir behavior of three inter-connected reservoir intervals below primary and secondary caprock confining zones. Drill cuttings, wireline geophysical logs, and 31one-inch diameter rotary sidewall cores provided geologic data for characterization of rock properties. XRF analyses of selected rock samples provided geochemical characterizations of the rocks and stratigraphic control for the basalt flows encountered by the Wallula pilot borehole. Based on the geochemical results, the pilot borehole was terminated in the Wapshilla Ridge 1 flow of the Grande Ronde Basalt Formation. Detailed hydrologic test characterizations of 12 basalt interflow

  9. An ancient recipe for flood-basalt genesis.

    Science.gov (United States)

    Jackson, Matthew G; Carlson, Richard W

    2011-07-27

    Large outpourings of basaltic lava have punctuated geological time, but the mechanisms responsible for the generation of such extraordinary volumes of melt are not well known. Recent geochemical evidence suggests that an early-formed reservoir may have survived in the Earth's mantle for about 4.5 billion years (ref. 2), and melts of this reservoir contributed to the flood basalt emplaced on Baffin Island about 60 million years ago. However, the volume of this ancient mantle domain and whether it has contributed to other flood basalts is not known. Here we show that basalts from the largest volcanic event in geologic history--the Ontong Java plateau--also exhibit the isotopic and trace element signatures proposed for the early-Earth reservoir. Together with the Ontong Java plateau, we suggest that six of the largest volcanic events that erupted in the past 250 million years derive from the oldest terrestrial mantle reservoir. The association of these large volcanic events with an ancient primitive mantle source suggests that its unique geochemical characteristics--it is both hotter (it has greater abundances of the radioactive heat-producing elements) and more fertile than depleted mantle reservoirs-may strongly affect the generation of flood basalts.

  10. Stratigraphy of Oceanus Procellarum basalts - Sources and styles of emplacement

    Science.gov (United States)

    Whitford-Stark, J. L.; Head, J. W., III

    1980-01-01

    The basaltic fill of Oceanus Procellarum has been formally subdivided into four lithostratigraphic formations: The Repsold Formation, the Telemann Formation, the Hermann Formation, and the Sharp Formation. The Repsold Formation is composed of high-Ti basalts and pyroclastic deposits with an estimated age of 3.75 + or - 0.05 b.y. and an estimated volume of about 2.1 x 10 to the 5th cu km. This is overlain by the Telemann Formation composed of very low-Ti basalts and pyroclastic deposits with an estimated age of 3.6 + or - 0.2 b.y. and a volume of 4.2 x 10 to the 5th cu km. The Hermann Formation, composed of intermediate basalts with an estimated age of 3.3 + or - 0.3 b.y., represents the next youngest unit with an estimated volume of 2.2 x 10 to the 5th cu km. The youngest materials in Procellarum are the medium-to-high-Ti basalts comprising the Sharp Formation with an estimated age of 2.7 + or - 0.7 b.y. and a volume of 1.8 x 10 to the 4th cu km.

  11. Emanation-thermal analysis of basalt fiber adsorbents

    International Nuclear Information System (INIS)

    Complex emanation-thermal analysis is used for investigating structural changes in basalt adsorbents taking place during thermal affects on material. Adsorbent is prepared by two-stage treatment of staple basalt fibers by hydrochloric acid. Isotherms of sorption of liquid nitrogen vapors by new sorbents are measured. Areas of the open surface, porosity and pores size spectra of leached fibers are calculated. It is determined by the method of thermostimulated gassing that adsorbed water is in two energetically different states in porous basalt fiber: basic part of water vapors is desorbed at 90-110 Deg C, remained part -at 300-320 Deg C. Full regeneration of sorbent requires warming up to 550 Deg C

  12. Evidence against hydrogen-based microbial ecosystems in basalt aquifers

    Science.gov (United States)

    Anderson; Chapelle; Lovley

    1998-08-14

    It has been proposed that hydrogen produced from basalt-ground-water interactions may serve as an energy source that supports the existence of microorganisms in the deep subsurface on Earth and possibly on other planets. However, experiments demonstrated that hydrogen is not produced from basalt at an environmentally relevant, alkaline pH. Small amounts of hydrogen were produced at a lower pH in laboratory incubations, but even this hydrogen production was transitory. Furthermore, geochemical considerations suggest that previously reported rates of hydrogen production cannot be sustained over geologically significant time frames. These findings indicate that hydrogen production from basalt-ground-water interactions may not support microbial metabolism in the subsurface.

  13. Investigation of basalt plastic reinforcement and its Adhesion with Concrete

    Directory of Open Access Journals (Sweden)

    Kustikova Yulia Olegovna

    2014-03-01

    Full Text Available The load-bearing capacity and durability of concrete structures with metal or other reinforcement depends on their physical and mechanical properties and adhesion values with concrete. In this regard, there is an urgent need in the definition of adhesion of basalt reinforcement and concrete of various compositions and classes. One of the main problems with the use of basalt rods in concrete structures is - providing a high degree of load-carrying capacity in different conditions of stress-strain state of the structure, and the related amount of its adhesion with concrete. Meeting these requirements can be achieved with load-bearing capacity of individual rods, adhesion value, in general, of basalt reinforcement with concrete.

  14. Petrogenesis of pillow basalts from Baolai in southwestern Taiwan

    Science.gov (United States)

    Liu, Chih-Chun; Yang, Huai-Jen

    2016-04-01

    The pillow basalts from Baolai in southwestern Taiwan have been inferred to bear Dupal signautres based on their Th/Ce ratio, linking the Baolai basalts to the South China Sea (SCS) seamounts that are characterized by Dupal Pb isotope signatures (Smith and Lewis, 2007). In this study, thirty-two Baolai basalt samples were analyzed for abundances of major and trace elements as well as Pb and Nd isotope ratios to verify their Dupal characters and to constrain their petrogenesis significance. The Baolai basalts contain 4-10 % L.O.I.. Three stages of alteration are inferred from plots of L.O.I. abundance versus concentrations major oxides as well as mineral textures and compositions. The first alteration stage was characterized by albitization that converted Ca-rich plagioclase to albite. The second alteration stage was dominated by chloritization of olivine and augite, resulting in increases in L.O.I. abundance. The last alteration stage is represented by formation of secondary calcite in vesicles and cracks. These alteration processes reflect interaction with seawater and apparently did not affect the magmatic Pb isotope composition for the low Pb concentration in seawater. Relative to the North Hemisphere Reference Line (NHRL), the Baolai pillow basalts have higher 208Pb/204Pb ratios at a given 206Pb/204Pb value, showing Dupal anomaly. For their relatively higher 208Pb/204Pb, 207Pb/204Pb, and 206Pb/204Pb ratios, the Baolai basalts are distinct from majority of the Cenozoic basalts in the Hainan-Leizhou peninsula, the Indochina peninsula, and the SCS seamounts, for which derivation from the Hainan mantle plume has been recently proposed (Wang et al., 2013). In contrast, the Baolai basalts and the Cenozoic basalts from eastern Guangdong at southeastern China have similar Pb and Nd isotope compositions, indicating derivation from similar mantle sources. However, the Baolai basalts have lower abundance ratios of Zr/Hf (40.3-45.6 versus 46.5-50.5), La/Yb (12

  15. Basalt fiber reinforced polymer composites: Processing and properties

    Science.gov (United States)

    Liu, Qiang

    A high efficiency rig was designed and built for in-plane permeability measurement of fabric materials. A new data derivation procedure to acquire the flow fluid pattern in the experiment was developed. The measurement results of the in-plane permeability for basalt twill 31 fabric material showed that a high correlation exists between the two principal permeability values for this fabric at 35% fiber volume fraction. This may be the most important scientific contribution made in this thesis. The results from radial measurements corresponded quite well with those from Unidirectional (UD) measurements, which is a well-established technique. No significant differences in mechanical properties were found between basalt fabric reinforced polymer composites and glass composites reinforced by a fabric of similar weave pattern. Aging results indicate that the interfacial region in basalt composites may be more vulnerable to environmental damage than that in glass composites. However, the basalt/epoxy interface may have been more durable than the glass/epoxy interface in tension-tension fatigue because the basalt composites have significantly longer fatigue life. In this thesis, chapter I reviews the literature on fiber reinforced polymer composites, with concentration on permeability measurement, mechanical properties and durability. Chapter II discusses the design of the new rig for in-plane permeability measurement, the new derivation procedure for monitoring of the fluid flow pattern, and the permeability measurement results. Chapter III compares the mechanical properties and durability between basalt fiber and glass fiber reinforced polymer composites. Lastly, chapter IV gives some suggestions and recommendations for future work.

  16. Seismic wave propagation through an extrusive basalt sequence

    Science.gov (United States)

    Sanford, Oliver; Hobbs, Richard; Brown, Richard; Schofield, Nick

    2016-04-01

    Layers of basalt flows within sedimentary successions (e.g. in the Faeroe-Shetland Basin) cause complex scattering and attenuation of seismic waves during seismic exploration surveys. Extrusive basaltic sequences are highly heterogeneous and contain strong impedance contrasts between higher velocity crystalline flow cores (˜6 km s-1) and the lower velocity fragmented and weathered flow crusts (3-4 km s-1). Typically, the refracted wave from the basaltic layer is used to build a velocity model by tomography. This velocity model is then used to aid processing of the reflection data where direct determination of velocity is ambiguous, or as a starting point for full waveform inversion, for example. The model may also be used as part of assessing drilling risk of potential wells, as it is believed to constrain the total thickness of the sequence. In heterogeneous media, where the scatter size is of the order of the seismic wavelength or larger, scattering preferentially traps the seismic energy in the low velocity regions. This causes a build-up of energy that is guided along the low velocity layers. This has implications for the interpretation of the observed first arrival of the seismic wave, which may be a biased towards the low velocity regions. This will then lead to an underestimate of the velocity structure and hence the thickness of the basalt, with implications for the drilling of wells hoping to penetrate through the base of the basalts in search of hydrocarbons. Using 2-D acoustic finite difference modelling of the guided wave through a simple layered basalt sequence, we consider the relative importance of different parameters of the basalt on the seismic energy propagating through the layers. These include the proportion of high to low velocity material, the number of layers, their thickness and the roughness of the interfaces between the layers. We observe a non-linear relationship between the ratio of high to low velocity layers and the apparent velocity

  17. Age of the youngest Palaeogene flood basalts in East Greenland

    DEFF Research Database (Denmark)

    Heilmann-Clausen, C.; Piasecki, Stefan; Abrahamsen, Niels;

    2008-01-01

    Intra-basaltic sediments 50 m below the top of the Paleogene lava succession at Kap Dalton, East Greenland, contain dinoflagellate cysts of late Ypresian-earliest Lutetian age, while sediments immediately above the lavas contain an assemblage of early Lutetian age. Combined with paleomagnetic...... results, this constrains the termination of the East Greenland Paleogene Igneous Province to the Early-Middle Eocene transition (nannoplankton chronozones NP13-NP14/earliest NP15). This is 6-8 Ma younger than according to previous biostratigraphic age assignments. The new data show that flood basalt...

  18. Friction Joint Between Basalt-Reinforced Composite and Aluminum

    DEFF Research Database (Denmark)

    Costache, Andrei; Glejbøl, Kristian; Sivebæk, Ion Marius;

    2015-01-01

    The purpose of this study was to anchor basalt-reinforced polymers in an aluminum grip using dry friction. Dry friction clamping is considered the optimal solution for post-mounting of load-bearing terminations on composite structures. A new test method is presented for characterizing the frictio......The purpose of this study was to anchor basalt-reinforced polymers in an aluminum grip using dry friction. Dry friction clamping is considered the optimal solution for post-mounting of load-bearing terminations on composite structures. A new test method is presented for characterizing...

  19. Basaltic rocks analyzed by the Spirit Rover in Gusev Crater

    Science.gov (United States)

    McSween, H. Y.; Arvidson, R. E.; Bell, J. F., III; Blaney, D.; Cabrol, N. A.; Christensen, P. R.; Clark, B. C.; Crisp, J. A.; Crumpler, L. S.; DesMarais, D. J.; Farmer, J. D.; Gellert, R.; Ghosh, A.; Gorevan, S.; Graff, T.; Grant, J.; Haskin, L. A.; Herkenhoff, K. E.; Johnson, J. R.; Jolliff, B. L.; Klingelhoefer, G.; Morris, R. V.; Yen, A.

    2004-01-01

    The Spirit landing site in Gusev Crater on Mars contains dark, fine-grained, vesicular rocks interpreted as lavas. Pancam and Mini-Thermal Emission Spectrometer (Mini-TES) spectra suggest that all of these rocks are similar but have variable coatings and dust mantles. Magnified images of brushed and abraded rock surfaces show alteration rinds and veins. Rock interiors contain Particle X-ray Spectrometer are consistent with picritic basalts, containing normative olivine, pyroxenes, plagioclase, and accessory FeTi oxides. Mossbauer, Pancam, and Mini-TES spectra confirm the presence of olivine, magnetite, and probably pyroxene. These basalts extend the known range of rock compositions composing the martian crust.

  20. Magmatic evolution of the fresh basalts from the Ridge axis near Egaria Fracture Zone, Central Indian Ridge

    Digital Repository Service at National Institute of Oceanography (India)

    Mudholkar, A.V.

    the basalts under study. These gradual changes in the olivines and plagioclase point to a simple evolution of the basaltic magma by differentiating mineral phases from the parental basalt The resorption features observed in high forsteritic olivines (~ 89...

  1. Glass and mineral chemistry of northern central Indian ridge basalts: Compositional diversity and petrogenetic significance

    Digital Repository Service at National Institute of Oceanography (India)

    Ray, Dwijesh; Banerjee, R.; Iyer, S.D.; Basavalingu, B.; Mukhopadhyay, S.

    The glass and mineral chemistry of basalts examined from the northern central Indian ridge (NCIR) provides an insight into magma genesis around the vicinity of two transform faults: Vityaz (VT) and Vema (VM). The studied mid-ocean ridge basalts...

  2. Preliminary feasibility study on storage of radioactive wastes in Columbia River basalts. Volume II

    Energy Technology Data Exchange (ETDEWEB)

    ,

    1976-11-01

    Volume II comprises four appendices: analytical data and sample locations for basalt flow type localities; Analytical data and sample locations for measured field sections in Yakima basalts; core hole lithology and analytical data; and geophysical logs. (LK)

  3. Notice of Release of NBR-1 Germplasm Basalt Milkvetch

    Science.gov (United States)

    Basalt milkvetch or threadstalk milkvetch (Astragalus filipes Torr. ex A. Gray) is a perennial legume that is widely distributed on rangelands in western North America and holds promise for rangeland revegetation and restoration programs. No germplasms or cultivars are commercially available for ba...

  4. Fire performance of basalt FRP mesh reinforced HPC thin plates

    DEFF Research Database (Denmark)

    Hulin, Thomas; Hodicky, Kamil; Schmidt, Jacob Wittrup;

    2013-01-01

    An experimental program was carried out to investigate the influence of basalt FRP (BFRP) reinforcing mesh on the fire behaviour of thin high performance concrete (HPC) plates applied to sandwich elements. Samples with BFRP mesh were compared to samples with no mesh, samples with steel mesh...

  5. Interpreting chemical compositions of small scale basaltic systems: A review

    Science.gov (United States)

    McGee, Lucy E.; Smith, Ian E. M.

    2016-10-01

    Small scale basaltic magmatic systems occur in all of the major tectonic environments of planet Earth and are characteristically expressed at the Earth's surface as fields of small monogenetic cones. The chemical compositions of the materials that make up these cones reflect processes of magma generation and differentiation that occur in their plumbing system. The volumes of magmas involved are very small and significantly their compositional ranges reveal remarkably complex processes which are overwhelmed or homogenized in larger scale systems. Commonly, compositions are basaltic, alkalic and enriched in light rare earth elements and large ion lithophile elements, although the spectrum extends from highly enriched nephelinites to subalkalic and tholeiitic basalts. Isotopic analyses of rocks from volcanic fields almost always display compositions which can only be explained by the interaction of two or more mantle sources. Ultimately their basaltic magmas originate by small scale melting of mantle sources. Compositional variety is testament to melting processes at different depths, a range of melting proportions, a heterogeneous source and fractionation, magma mixing and assimilation within the plumbing system that brings magmas to the surface. The fact that such a variety of compositions is preserved in a single field shows that isolation of individual melting events and their ascent is an important and possibly defining feature of monogenetic volcanism, as well as the window their chemical behavior provides into the complex process of melt generation and extraction in the Earth's upper mantle.

  6. [The dust factor in the manufacture of basalt fibers].

    Science.gov (United States)

    Gorban', L N; Riazanov, A V; Voloboeva, A A; Rybak, E A

    1996-01-01

    A study was made of the labour conditions of those workers engaged in the production of basalt fibre (BF). Morphological makeup is examined as is dispersity and cytotoxicity of the dust produced in the process of BF making. An issue is addressed of usefulness of setting special hygienic regulations for BF dust.

  7. Nuclear waste package materials testing report: basaltic and tuffaceous environments

    Energy Technology Data Exchange (ETDEWEB)

    Bradley, D.J.; Coles, D.G.; Hodges, F.N.; McVay, G.L.; Westerman, R.E.

    1983-03-01

    The disposal of high-level nuclear wastes in underground repositories in the continental United States requires the development of a waste package that will contain radionuclides for a time period commensurate with performance criteria, which may be up to 1000 years. This report addresses materials testing in support of a waste package for a basalt (Hanford, Washington) or a tuff (Nevada Test Site) repository. The materials investigated in this testing effort were: sodium and calcium bentonites and mixtures with sand or basalt as a backfill; iron and titanium-based alloys as structural barriers; and borosilicate waste glass PNL 76-68 as a waste form. The testing also incorporated site-specific rock media and ground waters: Reference Umtanum Entablature-1 basalt and reference basalt ground water, Bullfrog tuff and NTS J-13 well water. The results of the testing are discussed in four major categories: Backfill Materials: emphasizing water migration, radionuclide migration, physical property and long-term stability studies. Structural Barriers: emphasizing uniform corrosion, irradiation-corrosion, and environmental-mechanical testing. Waste Form Release Characteristics: emphasizing ground water, sample surface area/solution volume ratio, and gamma radiolysis effects. Component Compatibility: emphasizing solution/rock, glass/rock, glass/structural barrier, and glass/backfill interaction tests. This area also includes sensitivity testing to determine primary parameters to be studied, and the results of systems tests where more than two waste package components were combined during a single test.

  8. Nuclear waste package materials testing report: basaltic and tuffaceous environments

    International Nuclear Information System (INIS)

    The disposal of high-level nuclear wastes in underground repositories in the continental United States requires the development of a waste package that will contain radionuclides for a time period commensurate with performance criteria, which may be up to 1000 years. This report addresses materials testing in support of a waste package for a basalt (Hanford, Washington) or a tuff (Nevada Test Site) repository. The materials investigated in this testing effort were: sodium and calcium bentonites and mixtures with sand or basalt as a backfill; iron and titanium-based alloys as structural barriers; and borosilicate waste glass PNL 76-68 as a waste form. The testing also incorporated site-specific rock media and ground waters: Reference Umtanum Entablature-1 basalt and reference basalt ground water, Bullfrog tuff and NTS J-13 well water. The results of the testing are discussed in four major categories: Backfill Materials: emphasizing water migration, radionuclide migration, physical property and long-term stability studies. Structural Barriers: emphasizing uniform corrosion, irradiation-corrosion, and environmental-mechanical testing. Waste Form Release Characteristics: emphasizing ground water, sample surface area/solution volume ratio, and gamma radiolysis effects. Component Compatibility: emphasizing solution/rock, glass/rock, glass/structural barrier, and glass/backfill interaction tests. This area also includes sensitivity testing to determine primary parameters to be studied, and the results of systems tests where more than two waste package components were combined during a single test

  9. Assesment of Alkali Resistance of Basalt Used as Concrete Aggregates

    Directory of Open Access Journals (Sweden)

    al-Swaidani Aref M.

    2015-11-01

    Full Text Available The objective of this paper is to report a part of an ongoing research on the influence of using crushed basalt as aggregates on one of durability-related properties of concrete (i.e. alkali-silica reaction which is the most common form of Alkali-Aggregate Reaction. Alkali resistance has been assessed through several methods specified in the American Standards. Results of petrographic examination, chemical test (ASTM C289 and accelerated mortar bar test (ASTM C1260 have particularly been reported. In addition, the weight change and compressive strength of 28 days cured concrete containing basaltic aggregates were also reported after 90 days of exposure to 10% NaOH solution. Dolomite aggregate were used in the latter test for comparison. The experimental results revealed that basaltic rocks quarried from As-Swaida’a region were suitable for production of aggregates for concrete. According to the test results, the studied basalt aggregates can be classified as innocuous with regard to alkali-silica reaction. Further, the 10% sodium hydroxide attack did not affect the compressive strength of concrete.

  10. Basalt Waste Isolation Project. Annual report, fiscal year 1979

    International Nuclear Information System (INIS)

    This project is aimed at examining the feasibility and providing the technology to design and construct a radwaste repository in basalt formations beneath and within the Hanford Site. The project is divided into seven areas: systems integration, geosciences, hydrologic studies, engineered barriers, near-surface test facility, engineering testing, and repository engineering. This annual report summarizes key investigations in these seven areas

  11. Loading-unloading test analysis of anisotropic columnar jointed basalts

    Institute of Scientific and Technical Information of China (English)

    Zhi-gang SHAN; Sheng-jie DI

    2013-01-01

    To evaluate the columnar jointed basalts in the dam site of Baihetan hydropower station in southwest China,we developed a basic conceptual model of single jointed rock mass.Considering that the rock mass deformation consists of rock block deformation and joints deformation,the linear mechanical characteristics of the cell(including the elastic joints and the nonlinear mechanical behaviors of the cell)with a combined frictional-elastic interface were analyzed.We developed formulas to calculate the rock block deformation,which can be adapted for multiple jointed rock mass and columnar jointed basalts.The formulas are effective in calculating the equivalent modulus of multiple jointed rock mass,and precisely reveal the anisotropic properties of columnar jointed basalts.Furthermore,the in situ rigid bearing plate tests were analyzed and calculated,and the types of loading-unloading curves and the equivalent modulus along different directions of columnar jointed basalts were obtained.The analytical results are in close compliance with the test results.

  12. Basalt nuclear-waste repository remote sensing using electromagnetic techniques

    International Nuclear Information System (INIS)

    The electromagnetic permittivity and attenuation rate of basalt, from the Near Surface Test Facility of the Basalt Waste Isolation Project at Hanford, Washington, have been measured in the laboratory as a function of water content at frequencies from 25 MHz to 1000 MHz. Both the permittivity and the attenuation rate are strongly related to water content of basalt in this frequency range. Completely dehydrated, the rock has a frequency-independent relative permittivity of about 8 and attenuation rates (inverse skin depths) of 0.04 m-1 and 3.2 m-1 at 25 MHz and 1000 MHz, respectively. When completely saturated by tap water to 6% by volume, the relative permittivity ranges from 16.5 to 10.0 and the attenuation ranges from 0.3 m-1 to 5.5 m-1 between 25 MHz and 1000 MHz. The data indicate that high-frequency electromagnetic remote sensing techniques, such as those used in radar, cross-borehole tomography, and borehole logging, may be useful in characterizing proposed basalt repositories and monitoring established waste repositories. Electromagnetic methods are particularly suited to delineating water content of the rock and, when completely saturated, crack and pore porosity of the rock mass within a repository. 7 references, 3 figures

  13. Carbon fixation by basalt-hosted microbial communities

    Directory of Open Access Journals (Sweden)

    Beth N Orcutt

    2015-09-01

    Full Text Available Oceanic crust is a massive potential habitat for microbial life on Earth, yet our understanding of this ecosystem is limited due to difficulty in access. In particular, measurements of rates of microbial activity are sparse. We used stable carbon isotope incubations of crustal samples, coupled with functional gene analyses, to examine the potential for carbon fixation on oceanic crust. Both seafloor-exposed and subseafloor basalts were recovered from different mid-ocean ridge and hot spot environments (i.e., the Juan de Fuca Ridge, the Mid-Atlantic Ridge, and the Loihi Seamount and incubated with 13C-labeled bicarbonate. Seafloor-exposed basalts revealed incorporation of 13C-label into organic matter over time, though the degree of incorporation was heterogeneous. The incorporation of 13C into biomass was inconclusive in subseafloor basalts. Translating these measurements into potential rates of carbon fixation indicated that 0.1 – 10 nmol C g-1rock d-1 could be fixed by seafloor-exposed rocks. When scaled to the global production of oceanic crust, this suggests carbon fixation rates of 10^9 – 10^12 g C yr-1, which matches earlier predictions based on thermodynamic calculations. Functional gene analyses indicate that the Calvin cycle is likely the dominant biochemical mechanism for carbon fixation in basalt-hosted biofilms, although the reductive acetyl-CoA pathway and reverse TCA cycle likely play some role in net carbon fixation. These results provide empirical evidence for autotrophy in oceanic crust, suggesting that basalt-hosted autotrophy could be a significant contributor of organic matter in this remote and vast environment.

  14. Carbon fixation by basalt-hosted microbial communities.

    Science.gov (United States)

    Orcutt, Beth N; Sylvan, Jason B; Rogers, Daniel R; Delaney, Jennifer; Lee, Raymond W; Girguis, Peter R

    2015-01-01

    Oceanic crust is a massive potential habitat for microbial life on Earth, yet our understanding of this ecosystem is limited due to difficulty in access. In particular, measurements of rates of microbial activity are sparse. We used stable carbon isotope incubations of crustal samples, coupled with functional gene analyses, to examine the potential for carbon fixation on oceanic crust. Both seafloor-exposed and subseafloor basalts were recovered from different mid-ocean ridge and hot spot environments (i.e., the Juan de Fuca Ridge, the Mid-Atlantic Ridge, and the Loihi Seamount) and incubated with (13)C-labeled bicarbonate. Seafloor-exposed basalts revealed incorporation of (13)C-label into organic matter over time, though the degree of incorporation was heterogeneous. The incorporation of (13)C into biomass was inconclusive in subseafloor basalts. Translating these measurements into potential rates of carbon fixation indicated that 0.1-10 nmol C g(-1) rock d(-1) could be fixed by seafloor-exposed rocks. When scaled to the global production of oceanic crust, this suggests carbon fixation rates of 10(9)-10(12) g C year(-1), which matches earlier predictions based on thermodynamic calculations. Functional gene analyses indicate that the Calvin cycle is likely the dominant biochemical mechanism for carbon fixation in basalt-hosted biofilms, although the reductive acetyl-CoA pathway and reverse TCA cycle likely play some role in net carbon fixation. These results provide empirical evidence for autotrophy in oceanic crust, suggesting that basalt-hosted autotrophy could be a significant contributor of organic matter in this remote and vast environment.

  15. Geochemistry of Two Types of Basalts in the Emeishan Basaltic Province: Evidence for Mantle Plume-Lithosphere Interaction

    Institute of Scientific and Technical Information of China (English)

    张招崇; 王福生

    2002-01-01

    Based on the temporal-spatial distribution and geochemical characteristics, the Emeishan basalts can be divided into two types: high-P2O-TiO2 basalt (HPT) and low-P2O5-TiO2 basalt (LPT), which differ distinctly in geochemistry: the LPTs are characterized by relatively high abundances of MgO, total FeO and P2O5 and compatible elements (Cr, Ni, Sc), and relatively low contents of moderately compatible elements (V, Y, Yb, Co), LREE and other incompatible elements compared with the HPT. On the diagrams of trace element ratios, they are plotted on an approximately linear mixing line between depleted and enriched mantle sources, suggesting that these two types of basalts resulted from interactions of varying degrees between mantle plume and lithospheric mantle containing such volatile-rich minerals as amphibole and apatite. The source region of the LPT involves a smaller proportion of lithospheric components, while that of the HTP has a larger proportion of lithospheric components. Trachyte is generated by partial melting of the basic igneous rocks at the base of the lower continental crust. Both the two types of magmas underwent certain crystal fractionation and contamination of the lower crust at high-level magma chambers and en route to the surface.

  16. Eruption and emplacement of flood basalt. An example from the large-volume Teepee Butte Member, Columbia River Basalt Group

    Energy Technology Data Exchange (ETDEWEB)

    Reidel, S.P. (Washington State Univ., Pullman (United States)); Tolan, T.L. (Portland State Univ., OR (United States))

    1992-12-01

    Flows of the Teepee Butte Member, Grande Ronde Basalt, issued from a vent system in southeastern Washington, northeastern Oregon, and western Idaho. Three distinct basalt flows were erupted: the Limekiln Rapids flow, the Joseph Creek flow, and the Pruitt Draw flow. Together these mappable flows cover more than 52,000 km[sup 2] and have a volume exceeding 5,000 km[sup 3]. A portion of the vent system for the Joseph Creek flow is exposed in cross section in Joseph Canyon, Washington; it is one of the best preserved Columbia River Basalt Group vent complexes known. The vent complex is about 1 km in cross section, 30 m high, and composed of deposits characteristic of Hawaiian-type volcanism. The vent is asymmetrical; the eastern rampart consists of intercalated pyroclastic deposits and thin pahoehoe flows; the western rampart is composed wholly of pahoehoe flows. Flows of the Teepee Butte Member are compositionally homogeneous and were emplaced as sheet flows, each having several local flow units. Our study supports the importance of linear vent systems and the westward Palouse Slope, along with the large-volume lava flows, in controlling the distribution of Columbia River Basalt Group flows. Other factors, including the number of active fissure segments and topography, modified the shape of the flows and the number of flow units. 45 refs., 19 figs., 2 tabs.

  17. Zr and Nb partition coefficients - Implications for the genesis of mare basalts, KREEP, and sea floor basalts

    Science.gov (United States)

    Mccallum, I. S.; Charette, M. P.

    1978-01-01

    The distribution coefficients of Zr and Nb have been found between armalcolite, ilmenite, clinopyroxene, rutile, plagioclase, and a coexisting high-Ti mare basalt melt in the 1105-1128 C temperature range. Henry's Law is not broken over the compositional range evaluated. The distribution coefficients of clinopyroxene are strongly dependent on melt and crystal compositions. The Al2O3 activity in the melt is a strong controlling parameter. It is concluded that: (1) Apollo 11 (low K) and Apollo 17 high-Ti mare basalts may have been generated by the partial melting of an ilmenite-rich cumulate, (2) Apollo 11 (high K) basalts may have been generated by a small amount of partial melting of a more fractionated ilmenite-rich cumulate, (3) KREEP magmas may have been formed as residual melts produced by fractional crystallization of the lunar magma ocean, and (4) anomalous (type II) MOR basalts may have been generated by small degrees of partial melting of a relatively undepleted mantle with clinopyroxene remaining in the residium.

  18. Mechanical characteristics of fused cast basalt tube encased in steel pipe for protecting steel surface

    Institute of Scientific and Technical Information of China (English)

    Jee-Seok WANG; Jong-Do KIM; Hee-Jong YOON

    2009-01-01

    Because of the various excellent characteristics of cast basalt materials, such as, anti-corrosion, anti-wearing, good hardness, high chemical stability, of which steel may not possess, the steel-basalt composite pipes are used in severe environments for compensating the defects of steel. The limit of bending moment with which steel-basalt composite pipe may safely endure was calculated and the limit curvature of the composite pipe in the safe range was presented. The application temperature of steel-basalt pipe was examined due to a different coefficient among basalt, mortar and mild steel.

  19. Aqueous Alteration of Basalts: Earth, Moon, and Mars

    Science.gov (United States)

    Ming, Douglas W.

    2007-01-01

    The geologic processes responsible for aqueous alteration of basaltic materials on Mars are modeled beginning with our knowledge of analog processes on Earth, i.e., characterization of elemental and mineralogical compositions of terrestrial environments where the alteration and weathering pathways related to aqueous activity are better understood. A key ingredient to successful modeling of aqueous processes on Mars is identification of phases that have formed by those processes. The purpose of this paper is to describe what is known about the elemental and mineralogical composition of aqueous alteration products of basaltic materials on Mars and their implications for specific aqueous environments based upon our knowledge of terrestrial systems. Although aqueous alteration has not occurred on the Moon, it is crucial to understand the behaviors of basaltic materials exposed to aqueous environments in support of human exploration to the Moon over the next two decades. Several methods or indices have been used to evaluate the extent of basalt alteration/weathering based upon measurements made at Mars by the Mars Exploration Rover (MER) Moessbauer and Alpha Particle X-Ray Spectrometers. The Mineralogical Alteration Index (MAI) is based upon the percentage of total Fe (Fe(sub T)) present as Fe(3+) in alteration products (Morris et al., 2006). A second method is the evaluation of compositional trends to determine the extent to which elements have been removed from the host rock and the likely formation of secondary phases (Nesbitt and Young, 1992; Ming et al., 2007). Most of the basalts that have been altered by aqueous processes at the two MER landing sites in Gusev crater and on Meridiani Planum have not undergone extensive leaching in an open hydrolytic system with the exception of an outcrop in the Columbia Hills. The extent of aqueous alteration however ranges from relatively unaltered to pervasively altered materials. Several experimental studies have focused upon

  20. Investigation on mechanical properties of basalt composite fabrics (experiment study

    Directory of Open Access Journals (Sweden)

    Talebi Mazraehshahi H.

    2010-06-01

    Full Text Available To fully appreciate the role and application of composite materials to structures, correct understanding of mechanical behaviors required for selection of optimum material. Fabric reinforced composites are composed of a matrix that is reinforced with pliable fabric, glass fabric is most popular reinforcement for different application specially in aircraft structure, although other fabric material are also used. At this study new fabric material called basalt with epoxy resin introduced and mechanical behaviors of this material investigated from view point of testing. For this study two type of fabric with different thickness used. Comparison between this composite reinforcement with popular reinforcement as carbon, glass, kevlar performed. To determine mechanical properties of epoxy based basalt fabric following test procedure performed : 1. Tensile testing according to ASTM D3039 in 0° and 90° direction to find ultimate strength in tension and shear, modulus of elasticity, elangation and ultimate strain. 2. Compression testing according to EN 2850 ultimate compression strength and maximum deformation under compression loading. 3. Shear testing according to ASTM D3518-94 to find in plane shear response of polymer matrix composites materials. 4. Predict flexural properties of sandwich construction which manufactured from basalt facing with PVC foam core according to ASTM C393-94. Material strength properties must be based on enough tests of material to meet the test procedure specifications [1]. For this reason six specimens were manufactured for testing and the tests were performed on them using an INSTRON machine model 5582. In the study, the effect of percent of resin in basalt reinforced composite was investigated. Also the weights of the ballast based composites with different percent of resin were measured with conventional composites. As the weight is an important parameter in aerospace industry when the designer wants to replace one

  1. Investigation on mechanical properties of basalt composite fabrics (experiment study)

    Science.gov (United States)

    Talebi Mazraehshahi, H.; Zamani, H.

    2010-06-01

    To fully appreciate the role and application of composite materials to structures, correct understanding of mechanical behaviors required for selection of optimum material. Fabric reinforced composites are composed of a matrix that is reinforced with pliable fabric, glass fabric is most popular reinforcement for different application specially in aircraft structure, although other fabric material are also used. At this study new fabric material called basalt with epoxy resin introduced and mechanical behaviors of this material investigated from view point of testing. For this study two type of fabric with different thickness used. Comparison between this composite reinforcement with popular reinforcement as carbon, glass, kevlar performed. To determine mechanical properties of epoxy based basalt fabric following test procedure performed : 1). Tensile testing according to ASTM D3039 in 0° and 90° direction to find ultimate strength in tension and shear, modulus of elasticity, elangation and ultimate strain. 2). Compression testing according to EN 2850 ultimate compression strength and maximum deformation under compression loading. 3). Shear testing according to ASTM D3518-94 to find in plane shear response of polymer matrix composites materials. 4). Predict flexural properties of sandwich construction which manufactured from basalt facing with PVC foam core according to ASTM C393-94. Material strength properties must be based on enough tests of material to meet the test procedure specifications [1]. For this reason six specimens were manufactured for testing and the tests were performed on them using an INSTRON machine model 5582. In the study, the effect of percent of resin in basalt reinforced composite was investigated. Also the weights of the ballast based composites with different percent of resin were measured with conventional composites. As the weight is an important parameter in aerospace industry when the designer wants to replace one material with

  2. Similarities in basalt and rhyolite lava flow emplacement processes

    Science.gov (United States)

    Magnall, Nathan; James, Mike; Tuffen, Hugh; Vye-Brown, Charlotte

    2016-04-01

    Here we use field observations of rhyolite and basalt lava flows to show similarities in flow processes that span compositionally diverse lava flows. The eruption, and subsequent emplacement, of rhyolite lava flows is currently poorly understood due to the infrequency with which rhyolite eruptions occur. In contrast, the emplacement of basaltic lava flows are much better understood due to very frequent eruptions at locations such as Mt Etna and Hawaii. The 2011-2012 eruption of Cordón Caulle in Chile enabled the first scientific observations of the emplacement of an extensive rhyolite lava flow. The 30 to 100 m thick flow infilled a topographic depression with a negligible slope angle (0 - 7°). The flow split into two main channels; the southern flow advanced 4 km while the northern flow advanced 3 km before stalling. Once the flow stalled the channels inflated and secondary flows or breakouts formed from the flow front and margins. This cooling rather than volume-limited flow behaviour is common in basaltic lava flows but had never been observed in rhyolite lava flows. We draw on fieldwork conducted at Cordón Caulle and at Mt Etna to compare the emplacement of rhyolite and basaltic flows. The fieldwork identified emplacement features that are present in both lavas, such as inflation, breakouts from the flow font and margins, and squeeze-ups on the flow surfaces. In the case of Cordón Caulle, upon extrusion of a breakout it inflates due to a combination of continued lava supply and vesicle growth. This growth leads to fracturing and breakup of the breakout surface, and in some cases a large central fracture tens of metres deep forms. In contrast, breakouts from basaltic lava flows have a greater range of morphologies depending on the properties of the material in the flows core. In the case of Mt Etna, a range of breakout morphologies are observed including: toothpaste breakouts, flows topped with bladed lava as well as breakouts of pahoehoe or a'a lava. This

  3. Surface modification of basalt with silane coupling agent on asphalt mixture moisture damage

    Energy Technology Data Exchange (ETDEWEB)

    Min, Yahong; Fang, Ying; Huang, Xiaojun; Zhu, Yinhui; Li, Wensheng [College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 (China); Yuan, Jianmin [College of Materials Engineering, Hunan University, Changsha, 410082 (China); Tan, Ligang [College of Mechanical and Vehicle Engineering, Hunan University, Changsha, 410082 (China); Wang, Shuangyin [State Key Laboratory of Chem/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 (China); Wu, Zhenjun, E-mail: wooawt@163.com [College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 (China)

    2015-08-15

    Graphical abstract: - Highlights: • A new silane coupling agent was synthesized based on KH570. • Basalt surface was modified using the new silane coupling agent. • Chemical bond between basalt and the new silane coupling agent was formed. • Asphalt mixture which used modified basalt show superior water stability. - Abstract: A new silane coupling agent was synthesized based on γ-(methacryloyloxy) propyltrimethoxysilane (KH570). The surface of basalt rocks was modified by KH570 and the new silane coupling agent (NSCA), and the interfacial interaction between silane coupling agent and basalt was also studied. Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS) analysis showed that the silane coupling agent molecule bound strongly with basalt rocks. Scanning electronic microscopy (SEM) observation showed that a thin layer of coupling agent was formed on the surface of modified basalt. The boiling test and immersion Marshall test confirmed that the moisture sensitivity of basalt modified with the new silane coupling agent increased more significantly than that untreated and treated with KH570. The Retained Marshall Strength of basalt modified with the new coupling agent increased from 71.74% to 87.79% compared with untreated basalt. The results indicated that the new silane coupling agent played an important role in improving the interfacial performance between basalt and asphalt.

  4. Automated interpretation of nuclear and electrical well loggings for basalt characterization (case study from southern Syria).

    Science.gov (United States)

    Asfahani, J; Abdul Ghani, B

    2012-10-01

    Nuclear well logging, including natural gamma ray, density and neutron-porosity techniques are used with electrical well logging of long and short normal techniques in order to characterize the large extended basaltic areas in southern Syria. Four kinds of basalt have been identified: hard massive basalt, hard basalt, pyroclastic basalt and the alteration basalt products, clay, based on a statistical analysis approach with the threshold concept. The statistical conditions for such basalt characterization have been programmed in the present research to automatically interpret the well logging data for establishing and predicting the lithological cross-section of the studied well. A specific computer program has been written in Delphi for such purposes. The program is flexible and it can be used for other well logging applications by changing the statistical conditions and the well logging parameters. The program has been successfully tested on the Kodanah well logging data in southern Syria.

  5. Basalt characterization by means of nuclear and electrical well logging techniques. Case study from Southern Syria.

    Science.gov (United States)

    Asfahani, Jamal

    2011-03-01

    Nuclear well logging, including natural gamma ray, density, and neutron-porosity techniques are used with electrical well logging of long and short normal techniques to characterize the basaltic areas largely extended in Southern Syria. Statistical analysis approach with the threshold concept has been adapted for such characterization, where four kinds of basalt have been identified: very hard basalt, hard basalt, fractured basalt, and basalt alteration products. The spectrometric gamma technique has also been applied on the retrieved rock samples in order to determine the radioactive content (eU, eTh, and K%) of the basaltic section in the study area. No radioactive anomalies have been detected, the radioactive values are normal and in the expected range.

  6. Rapid solubility and mineral storage of CO2 in basalt

    DEFF Research Database (Denmark)

    Gislason, Sigurdur R.; Broecker, W.S.; Gunnlaugsson, E.;

    2014-01-01

    The long-term security of geologic carbon storage is critical to its success and public acceptance. Much of the security risk associated with geological carbon storage stems from its buoyancy. Gaseous and supercritical CO2 are less dense than formation waters, providing a driving force...... for it to escape back to the surface. This buoyancy can be eliminated by the dissolution of CO2 into water prior to, or during its injection into the subsurface. The dissolution makes it possible to inject into fractured rocks and further enhance mineral storage of CO2 especially if injected into silicate rocks...... rich in divalent metal cations such as basalts and ultra-mafic rocks. We have demonstrated the dissolution of CO2 into water during its injection into basalt leading to its geologic solubility storage in less than five minutes and potential geologic mineral storage within few years after injection [1...

  7. Flood basalt volcanism during the past 250 million years

    Science.gov (United States)

    Rampino, Michael R.; Stothers, Richard B.

    1988-01-01

    A chronology of the initiation dates of major continental flood basalt volcanism is established from published potassium-argon (K-Ar) and argon-argon (Ar-Ar) ages of basaltic rocks and related basic intrusions. The dating is therefore independent of the biostratigraphic and paleomagnetic time scales. Estimated errors of the initiation dates of the volcanic episodes determined from the distributions of the radiometric ages are, approximately, + or - 4 percent. There were 11 distinct episodes during the past 250 million years. Sometimes appearing in pairs, the episodes have occurred quasi-periodically with a mean cycle time of 32 + or - 1 (estimated error of the mean) million years. The initiation dates of the episodes are close to the estimated dates of mass extinctions of marine organisms. Showers of impacting comets may be the cause.

  8. A new basaltic glass microanalytical reference material for multiple techniques

    Science.gov (United States)

    Wilson, Steve; Koenig, Alan; Lowers, Heather

    2012-01-01

    The U.S. Geological Survey (USGS) has been producing reference materials since the 1950s. Over 50 materials have been developed to cover bulk rock, sediment, and soils for the geological community. These materials are used globally in geochemistry, environmental, and analytical laboratories that perform bulk chemistry and/or microanalysis for instrument calibration and quality assurance testing. To answer the growing demand for higher spatial resolution and sensitivity, there is a need to create a new generation of microanalytical reference materials suitable for a variety of techniques, such as scanning electron microscopy/X-ray spectrometry (SEM/EDS), electron probe microanalysis (EPMA), laser ablation inductively coupled mass spectrometry (LA-ICP-MS), and secondary ion mass spectrometry (SIMS). As such, the microanalytical reference material (MRM) needs to be stable under the beam, be homogeneous at scales of better than 10–25 micrometers for the major to ultra-trace element level, and contain all of the analytes (elements or isotopes) of interest. Previous development of basaltic glasses intended for LA-ICP-MS has resulted in a synthetic basaltic matrix series of glasses (USGS GS-series) and a natural basalt series of glasses (BCR-1G, BHVO-2G, and NKT-1G). These materials have been useful for the LA-ICP-MS community but were not originally intended for use by the electron or ion beam community. A material developed from start to finish with intended use in multiple microanalytical instruments would be useful for inter-laboratory and inter-instrument platform comparisons. This article summarizes the experiments undertaken to produce a basalt glass reference material suitable for distribution as a multiple-technique round robin material. The goal of the analytical work presented here is to demonstrate that the elemental homogeneity of the new glass is acceptable for its use as a reference material. Because the round robin exercise is still underway, only

  9. Investigation on mechanical properties of basalt composite fabrics (experiment study)

    OpenAIRE

    Talebi Mazraehshahi H.; Zamani H.

    2010-01-01

    To fully appreciate the role and application of composite materials to structures, correct understanding of mechanical behaviors required for selection of optimum material. Fabric reinforced composites are composed of a matrix that is reinforced with pliable fabric, glass fabric is most popular reinforcement for different application specially in aircraft structure, although other fabric material are also used. At this study new fabric material called basalt with epoxy resin introduced ...

  10. Initial effects of vegetation on Hawaiian basalt weathering rates

    Energy Technology Data Exchange (ETDEWEB)

    Cochran, M.F.; Berner, R.A. (Yale Univ., New Haven, CT (United States))

    1992-01-01

    Weathering of Ca and Mg silicates on land and ensuing precipitation and burial of Ca and Mg carbonates in marine sediments is the principal sink for carbon dioxide from the atmosphere/ocean system on geologic time scales. Model calculations of ancient atmospheric CO[sub 2] partial pressure depend strongly on the authors assumptions about the enhancement of silicate weathering rates first by primitive terrestrial biota, then by the appearance and evolution of the vascular plants. Aa and pahoehoe basalts were collected from Mauna Loa and Kilauea volcanoes on the island of Hawaii. Flows ranged in age (one year to several thousand years) and in ambient climate. Where possible, each flow was sampled beneath a suite of current plant covers: none, lichens, and higher plants. Rocks were embedded in epoxy to preserve the plant-rock interface, then sectioned and subjected to electron probe microanalysis. During initial weathering, vascular plants appeared to promote congruent dissolution of minerals (particularly olivine and Ca-rich plagioclase) and glass near the surfaces of underlying basalts. In the neighborhood of roots, primary cracks widened with time into networks of open channels. This effect was observed prior to the formation of measurable leached zones in exterior grains and prior to the appearance of secondary minerals. As a result, initial mass loss from young, plant-covered basalts appeared to be up to one or more orders of magnitude greater than from bare-rock controls. Despite earlier reports of substantial enhancement of Hawaiian basalt weathering rates by the lichen Stereocaulon vulcani, weathering observed beneath this lichen was comparable to that of unvegetated rocks.

  11. Putative cryptoendolithic life in Devonian pillow basalt, Rheinisches Schiefergebirge, Germany.

    Science.gov (United States)

    Peckmann, J; Bach, W; Behrens, K; Reitner, J

    2008-03-01

    Middle Devonian (Givetian) pillow basalt and inter-pillow breccia from the Rheinisches Schiefergebirge in Germany were found to contain putative biogenic filaments that indicate that life once proliferated within these volcanic rocks. Mineralized filaments are found in carbonate amygdules (vesicles filled by carbonate cement) in the volcanic rock, where they started to form on the internal surface of the once water-filled vesicles. Biogenicity of the filaments is indicated by (1) their size and shape resembling modern microorganisms including a constant diameter along the length of curved filaments, (2) their independence of crystal faces or cleavage planes, (3) branching patterns reminiscent of modern microorganisms, and (4) their spatial clustering and preferential occurrence close to the margin of pillows and in the inter-pillow breccias. A time lag between the deposition of pillow basalt and the activity of endoliths is revealed by the sequence of carbonate cements filling the amygdules. The putative filamentous microorganisms thrived after the formation of early fibrous rim cement, but before later equant calcite spar filled most of the remaining porosity. Microbial clay authigenesis analogous to the encrustation of prokaryotes in modern iron-rich environments led to the preservation of filaments. The filaments predominantly consist of the clay minerals chamosite and illite. Having dwelled in water-filled vesicles, the Devonian basalt-hosted filaments apparently represent cryptoendoliths. This finding suggests that a previously unrecognized niche for life exists within volcanic rock.

  12. Basalt Pb isotope analysis and the prehistoric settlement of Polynesia.

    Science.gov (United States)

    Weisler, M I; Woodhead, J D

    1995-03-14

    The prehistoric settlement of the Pacific Ocean has intrigued scholars and stimulated anthropological debate for the past two centuries. Colonized over a few millennia during the mid to late Holocene, the islands of the Pacific--displaying a wide diversity of geological and biotic variability--provided the stage for endless "natural experiments" in human adaptation. Crucial to understanding the evolution and transformation of island societies is documenting the relative degree of interisland contacts after island colonization. In the western Pacific, ideal materials for archaeologically documenting interisland contact--obsidian, pottery, and shell ornaments--are absent or of limited geographic distribution in Polynesia. Consequently, archaeologists have relied increasingly on fine-grained basalt artifacts as a means for documenting colonization routes and subsequent interisland contacts. Routinely used x-ray fluorescence characterization of oceanic island basalt has some problems for discriminating source rocks and artifacts in provenance studies. The variation in trace and major element abundances is largely controlled by near-surface magma-chamber processes and is broadly similar between most oceanic islands. We demonstrate that Pb isotope analysis accurately discriminates rock source and is an excellent technique for charting the scale, frequency, and temporal span of imported fine-grained basalt artifacts found throughout Polynesia. The technique adds another tool for addressing evolutionary models of interaction, isolation, and cultural divergence in the eastern Pacific.

  13. Carbon dioxide sequestration in deep-sea basalt.

    Science.gov (United States)

    Goldberg, David S; Takahashi, Taro; Slagle, Angela L

    2008-07-22

    Developing a method for secure sequestration of anthropogenic carbon dioxide in geological formations is one of our most pressing global scientific problems. Injection into deep-sea basalt formations provides unique and significant advantages over other potential geological storage options, including (i) vast reservoir capacities sufficient to accommodate centuries-long U.S. production of fossil fuel CO2 at locations within pipeline distances to populated areas and CO2 sources along the U.S. west coast; (ii) sufficiently closed water-rock circulation pathways for the chemical reaction of CO2 with basalt to produce stable and nontoxic (Ca(2+), Mg(2+), Fe(2+))CO(3) infilling minerals, and (iii) significant risk reduction for post-injection leakage by geological, gravitational, and hydrate-trapping mechanisms. CO2 sequestration in established sediment-covered basalt aquifers on the Juan de Fuca plate offer promising locations to securely accommodate more than a century of future U.S. emissions, warranting energized scientific research, technological assessment, and economic evaluation to establish a viable pilot injection program in the future.

  14. Interim reclamation report, Basalt Waste Isolation project: Boreholes, 1989

    Energy Technology Data Exchange (ETDEWEB)

    Brandt, C.A.; Rickard, W.H. Jr.; Hefty, M.G.

    1990-03-01

    In 1968, a program was started to assess the feasibility of storing Hanford Site defense waste in deep caverns constructed in basalt. This program was expanded in 1976 to include investigations of the Hanford Site as a potential location for a mined commercial nuclear waste repository. An extensive site characterization program was begun to determine the feasibility of using the basalts beneath the Hanford Site for the repository. Site research focused primarily on determining the direction and speed of groundwater movement, the uniformity of basalt layers, and tectonic stability. Some 98 boreholes were sited, drilled, deepened, or modified by BWIP between 1977 and 1988 to test the geologic properties of the Site. On December 22, 1987, President Reagan signed into law the Nuclear Waste Policy Amendments Act of 1987, which effectively stopped all repository-related activities except reclamation of disturbed lands at the Hanford Site. This report describes the development of the reclamation program for the BWIP boreholes, its implementation, and preliminary estimates of its success. The goal of the reclamation program is to return sites disturbed by the repository program as nearly as practicable to their original conditions using native plant species. 48 refs., 28 figs., 14 tabs.

  15. Interim reclamation report, Basalt Waste Isolation project: Boreholes, 1989

    International Nuclear Information System (INIS)

    In 1968, a program was started to assess the feasibility of storing Hanford Site defense waste in deep caverns constructed in basalt. This program was expanded in 1976 to include investigations of the Hanford Site as a potential location for a mined commercial nuclear waste repository. An extensive site characterization program was begun to determine the feasibility of using the basalts beneath the Hanford Site for the repository. Site research focused primarily on determining the direction and speed of groundwater movement, the uniformity of basalt layers, and tectonic stability. Some 98 boreholes were sited, drilled, deepened, or modified by BWIP between 1977 and 1988 to test the geologic properties of the Site. On December 22, 1987, President Reagan signed into law the Nuclear Waste Policy Amendments Act of 1987, which effectively stopped all repository-related activities except reclamation of disturbed lands at the Hanford Site. This report describes the development of the reclamation program for the BWIP boreholes, its implementation, and preliminary estimates of its success. The goal of the reclamation program is to return sites disturbed by the repository program as nearly as practicable to their original conditions using native plant species. 48 refs., 28 figs., 14 tabs

  16. Basalt Waste Isolation Project. Annual report, fiscal year 1980

    International Nuclear Information System (INIS)

    During this fiscal year the information available in the fields of geology and hydrology of the Columbia Plateau was consolidated and two reports were issued summarizing this information. In addition, the information on engineered barriers was consolidated and a report summarizing the research to date on waste package development and design of borehole seals was prepared. The waste package studies, when combined with the hydrologic integration, revealed that even under extreme disruptive conditions, a repository in basalt with appropriately designed waste packages can serve as an excellent barrier for containment of radionuclides for the long periods of time required for waste isolation. On July 1, 1980, the first two heater tests at the Near-Surface Test Facility were started and have been successfully operated to this date. The papers on the Near-Surface Test Facility section of this report present the results of the equipment installed and the preliminary results of the testing. In October 1979, the US Department of Energy selected the joint venture of Kaiser Engineers/Parsons Brinckerhoff Quade and Douglas, Inc., to be the architect-engineer to produce a conceptual design of a repository in basalt. During the year, this design has progressed and concept selection has now been completed. This annual report presents a summary of the highlights of the work completed during fiscal year 1980. It is intended to supplement and summarize the nearly 200 papers and reports that have been distributed to date as a part of the Basalt Waste Isolation Project studies

  17. Basalt Waste Isolation Project. Annual report, fiscal year 1980

    Energy Technology Data Exchange (ETDEWEB)

    1980-11-01

    During this fiscal year the information available in the fields of geology and hydrology of the Columbia Plateau was consolidated and two reports were issued summarizing this information. In addition, the information on engineered barriers was consolidated and a report summarizing the research to date on waste package development and design of borehole seals was prepared. The waste package studies, when combined with the hydrologic integration, revealed that even under extreme disruptive conditions, a repository in basalt with appropriately designed waste packages can serve as an excellent barrier for containment of radionuclides for the long periods of time required for waste isolation. On July 1, 1980, the first two heater tests at the Near-Surface Test Facility were started and have been successfully operated to this date. The papers on the Near-Surface Test Facility section of this report present the results of the equipment installed and the preliminary results of the testing. In October 1979, the US Department of Energy selected the joint venture of Kaiser Engineers/Parsons Brinckerhoff Quade and Douglas, Inc., to be the architect-engineer to produce a conceptual design of a repository in basalt. During the year, this design has progressed and concept selection has now been completed. This annual report presents a summary of the highlights of the work completed during fiscal year 1980. It is intended to supplement and summarize the nearly 200 papers and reports that have been distributed to date as a part of the Basalt Waste Isolation Project studies.

  18. Radiolytic Hydrogen Production in the South Pacific Subseafloor Basaltic Aquifer

    Science.gov (United States)

    Dzaugis, M. E.; Spivack, A. J.; Dunlea, A. G.; Murray, R. W.; D'Hondt, S.

    2015-12-01

    Hydrogen (H2) is produced in geological settings by dissociation of water due to radiation from natural radioactive decay of uranium (238U, 235U), thorium (232Th) and potassium (40K). To quantify the potential significance of radiolytic H2 as an electron donor for microbes within the South Pacific subseafloor basaltic aquifer, we calculate radiolytic H2 production rates in basement fractures utilizing measured radionuclide concentrations in 42 basalt samples from IODP Expedition 329. The samples are from three sites with very different basement ages and a wide range of alteration types. Major and trace element concentrations vary by up to an order of magnitude from sample to sample. Comparison of our samples to each other and to previous studies of fresh East Pacific Rise basalt suggests that between-sample variation in radionuclide concentrations is primarily due to differences in initial (pre-alteration) concentrations (which can vary between eruptive events), rather than to alteration type or extent. Local maxima in radionuclide (U, Th, and K) concentrations produce 'hotspots' of radiolytic H2 production; calculated radiolytic rates differ by up to a factor of 80 from sample to sample. Fracture width also greatly influences H2 production. Due to the low penetration distance of alpha radiation, microfractures are 'hotpots' for radiolytic H2 production. For example, radiolytic H2 production rates normalized to water volume are 170 times higher in 1μm-wide fractures than in 10cm-wide fractures.

  19. The consanguinity of the oldest Apollo 11 mare basalts

    Science.gov (United States)

    Gamble, R. P.; Coish, R. A.; Taylor, L. A.

    1978-01-01

    The textural, mineralogical, and chemical relationships between three of the oldest dates lunar mare basalt samples returned by Apollo 11 (10003, 10029 and 10062) were investigated. Very strong resemblances were noted between the modal minerologies of 10003 and 10029. Significantly more modal olivine and cristobalite was observed in 10062 than in the other basalt samples. A detailed examination of mineral-chemical relationships among the samples revealed similarities between 10003 and 10062 and differences between these two rocks and 10029, the most significant of which is the presence of akaganeite in 10029, implying that lawrencite was present in the pristine sample of 10029 but not in 10003 and 10062. Results of a Wright-Doherty mixing program used to test various fractional crystallization schemes show that 10062 can be derived from a liquid with the composition of either 10003 or 10029 by removing 2-5% ilmenite and 5% olivine. By removing about 6% plagioclase, 10003 can be derived from a liquid with the bulk composition of 10062. It is concluded that 10003 and 10029 may have come from different basaltic flows, whereas it is possible that 10003 and 10062 were derived from the same parental magma by near-surface fractionation of olivine plus ilmenite or of plagioclase plus or minus olivine.

  20. Differentiation mechanism of frontal-arc basalt magmas

    Science.gov (United States)

    Kuritani, T.; Yoshida, T.; Kimura, J.; Hirahara, Y.; Takahashi, T.

    2012-04-01

    In a cooling magma chamber, magmatic differentiation can proceed both by fractionation of crystals from the main molten part of the magma body (homogeneous fractionation) and by mixing of the main magma with fractionated melt derived from low-temperature mush zones (boundary layer fractionation) (Jaupart and Tait, 1995, and references therein). The geochemical path caused by boundary layer fractionation can be fairly different from a path resulting from homogeneous fractionation (e.g., Langmuir, 1989). Therefore, it is important to understand the relative contributions of these fractionation mechanisms in magma chambers. Kuritani (2009) examined the relative roles of the two fractionation mechanisms in cooling basaltic magma chambers using a thermodynamics-based mass balance model. However, the basaltic magmas examined in the work were alkali-rich (Na2O+K2O > 4 wt.%). In this study, to explore differentiation mechanisms of frontal-arc basalt magmas that are volumetrically much more important than rear-arc alkali basalt magmas, the relative roles of the two fractionation mechanisms are examined for low-K tholetiitic basalt magma from Iwate Volcano, NE Japan arc, using the same mass balance model. First, the water content and the temperature of the Iwate magma were estimated. The Iwate lavas are moderately porphyritic, consisting of ~8 vol.% olivine and ~20 vol.% plagioclase phenocrysts. The olivine and plagioclase phenocrysts show significant compositional variations, and the Mg# of olivine phenocrysts (Mg#78-81) correlates positively with the An content of coexisting plagioclase phenocrysts (An85-92). The olivine phenocrysts with Mg# > ~82 do not form crystal aggregates with plagioclase. It is inferred from these observations that the phenocrysts with variable compositions were derived from a common magma with variable temperature in a magma chamber, and the plagioclase phenocrysts were all derived from mushy boundary layers along the walls of the magma chamber. By

  1. Preliminary Study on the PGE Geochemistry of the Permian Basalts in the Jinping Area

    Institute of Scientific and Technical Information of China (English)

    Nian Hong; Shen Wei; Zhang Xueshu

    2006-01-01

    To disclose and study the magma genesis of the Permian basalts in the Jinping (金平)area, the PGE and Au contents of the Permian basalts in the Jinping area were assayed by use of the ICP-MS method. The PGE data show relatively strong differentiation of basaltic magma in comparison with the primitive mantle. The primitive mantle-normalized pattern is a left-dipping curve of the Pd-Pt enriched type. The Pd/Ir ratios of the PGE of the Permian basalts in the Jinping area are higher than those of the primitive mantle and the upper primitive mantle and the chondrite meteorite. The Pd/Ir ramaterial source. It is concluded that they are derived from the basaltic magma of the upper mantle source with a lower melting degree, which shares the similar magma material source with the Emeishan Permian basalts as a whole.

  2. Recycled dehydrated lithosphere observed in plume-influenced mid-ocean-ridge basalt.

    Science.gov (United States)

    Dixon, Jacqueline Eaby; Leist, Loretta; Langmuir, Charles; Schilling, Jean-Guy

    2002-11-28

    A substantial uncertainty in the Earth's global geochemical water cycle is the amount of water that enters the deep mantle through the subduction and recycling of hydrated oceanic lithosphere. Here we address the question of recycling of water into the deep mantle by characterizing the volatile contents of different mantle components as sampled by ocean island basalts and mid-ocean-ridge basalts. Although all mantle plume (ocean island) basalts seem to contain more water than mid-ocean-ridge basalts, we demonstrate that basalts associated with mantle plume components containing subducted lithosphere--'enriched-mantle' or 'EM-type' basalts--contain less water than those associated with a common mantle source. We interpret this depletion as indicating that water is extracted from the lithosphere during the subduction process, with greater than 92 per cent efficiency.

  3. Petrographical indicators of petrogenesis: Examples from Central Indian Ocean Basin basalts

    Digital Repository Service at National Institute of Oceanography (India)

    Mislankar, P.G.; Iyer, S.D.

    glassy rims 8 . Generally, chemical compositions, obtained through various analytical techniques, are utilised to arrive at the genesis of the basalts. But the morphotypes of plagioclases and olivines occurring in the basalts can also be used... be considered as liquid drops of the magma 16 . This indicates that the plagioclase phenocrysts might have either crystallized contemporaneously with or later than the basaltic groundmass and thus, show the effects of magmatic corrosion. The flow texture...

  4. Engineered barrier development for a nuclear waste repository in basalt: an integration of current knowledge

    Energy Technology Data Exchange (ETDEWEB)

    Smith, M.J.

    1980-05-01

    This document represents a compilation of data and interpretive studies conducted as part of the engineered barriers program of the Basalt Waste Isolation Project. The overall objective of these studies is to provide information on barrier system designs, emplacement and isolation techniques, and chemical reactions expected in a nuclear waste repository located in the basalts underlying the Hanford Site within the state of Washington. Backfills, waste-basalt interactions, sorption, borehole plugging, etc., are among the topics discussed.

  5. Experimental petrology of ancient lunar mare basalt Asuka-881757: Spinel crystallization as a petrologic indicator

    OpenAIRE

    Arai,Tomoko/Takeda,Hiroshi /Miyamoto,Masamichi

    2006-01-01

    The paucity of titanian chromites in lunar-meteorite basalt Asuka (A)-881757 is unusual compared to the general occurrence of co-existing chromites and ulvospinels in the Apollo and Luna mare basalts. The unique spinel crystallization of A-881757 is expected to hold a key to elucidate the crystallization and cooling episodes of the basalt. In this study, we investigated the possible reason for the missing chromite by conducting isothermal and cooling experiments on the bulk-rock composition o...

  6. Engineered barrier development for a nuclear waste repository in basalt: an integration of current knowledge

    International Nuclear Information System (INIS)

    This document represents a compilation of data and interpretive studies conducted as part of the engineered barriers program of the Basalt Waste Isolation Project. The overall objective of these studies is to provide information on barrier system designs, emplacement and isolation techniques, and chemical reactions expected in a nuclear waste repository located in the basalts underlying the Hanford Site within the state of Washington. Backfills, waste-basalt interactions, sorption, borehole plugging, etc., are among the topics discussed

  7. A Metasomatic Origin for the Enriched Walvis Ridge Basalts

    Science.gov (United States)

    Salters, V. J.

    2008-12-01

    he isotopic composition of the EMI and HIMU are consistent with them containing a component of recycled crust. For HIMU it is suggested that subducted oceanic crust plays an important role and for EMI it is argued that pelagic sediments is present in small but important amounts. One of the "type localities" of the EMI source is the Walvis Ridge, and the most enriched basalts from this locality define the EMI endmember. Models that explain the isotopic composition of the Walvis Ridge basalts need in addition to subducted oceanic crust with sediment a component of subcontinental lithosphere (SCL) [1, 2]. New and more complete data on Walvis Ridge basalts allows a better constrain on its source evolution. The approach has been to explain both the isotopic composition as well as the trace element composition with an as-simple-as possible model. The parent-daughter ratios of the U-Th-Pb, Lu-Hf, Sm-Nd and Rb-Sr system provide a large part of the incompatible trace element pattern. Starting with a bulk silicate Earth composition the isotopic composition can be modeled by a three stage evolution: first as Bulk Silicate Earth which ended by an 4.2 Ga old addition of 1.5% of a low degree garnet melt (1%). This enrichment raised the μ of the system to 10 during the second stage of the sources' history. This enrichment was followed by a 3.9 Ga old depletion equivalent to the extraction of 0.5% melt, again in the garnet stability field. This source then melts to 10% partly in the garnet and partly in the spinel stability field to generate the trace element pattern of the basalts. Because the nuclides represent a large range in half-lives the age constraints are surprisingly strong and especially the early fractionation cannot be younger then 4.1 Ga. Similarly the duration of the second stage is constrained to plus or minus 0.1 Ga. This purely metasomatic origin explains the enriched Walvis ridge basalt source evolution from "cradle to grave" with garden variety processes

  8. Nuclear waste repository in basalt: preconceptual design guidelines

    International Nuclear Information System (INIS)

    The development of the basalt waste isolation program parallels the growing need for permanent, environmentally safe, and secure means to store nuclear wastes. The repository will be located within the Columbia Plateau basalt formations where these ends can be met and radiological waste can be stored. These wastes will be stored such that the wastes may be retrieved from storage for a period after placement. After the retrieval period, the storage locations will be prepared for terminal storage. The terminal storage requirements will include decommissioning provisions. The facility boundaries will encompass no more than several square miles of land which will be above a subsurface area where the geologic makeup is primarily deep basaltic rock. The repository will receive, from an encapsulation site(s), nuclear waste in the form of canisters (not more than 18.5 feet x 16 inches in diameter) and containers (55-gallon drums). Canisters will contain spent fuel (after an interim 5-year storage period), solidified high-level wastes (HLW), or intermediate-level wastes (ILW). The containers (drums) will package the low-level transuranic wastes (LL-TRU). The storage capacity of the repository will be expanded in a time-phased program which will require that subsurface development (repository expansion) be conducted concurrently with waste storage operations. The repository will be designed to store the nuclear waste generated within the predictable future and to allow for reasonable expansion. The development and assurance of safe waste isolation is of paramount importance. All activities will be dedicated to the protection of public health and the environment. The repository will be licensed by the US Nuclear Regulatory Commission (NRC). Extensive efforts will be made to assure selection of a suitable site which will provide adequate isolation

  9. 3D Finite Difference Modelling of Basaltic Region

    Science.gov (United States)

    Engell-Sørensen, L.

    2003-04-01

    The main purpose of the work was to generate realistic data to be applied for testing of processing and migration tools for basaltic regions. The project is based on the three - dimensional finite difference code (FD), TIGER, made by Sintef. The FD code was optimized (parallelized) by the author, to run on parallel computers. The parallel code enables us to model large-scale realistic geological models and to apply traditional seismic and micro seismic sources. The parallel code uses multiple processors in order to manipulate subsets of large amounts of data simultaneously. The general anisotropic code uses 21 elastic coefficients. Eight independent coefficients are needed as input parameters for the general TI medium. In the FD code, the elastic wave field computation is implemented by a higher order FD solution to the elastic wave equation and the wave fields are computed on a staggered grid, shifted half a node in one or two directions. The geological model is a gridded basalt model, which covers from 24 km to 37 km of a real shot line in horizontal direction and from the water surface to the depth of 3.5 km. The 2frac {1}{2}D model has been constructed using the compound modeling software from Norsk Hydro. The vertical parameter distribution is obtained from observations in two wells. At The depth of between 1100 m to 1500 m, a basalt horizon covers the whole sub surface layers. We have shown that it is possible to simulate a line survey in realistic (3D) geological models in reasonable time by using high performance computers. The author would like to thank Norsk Hydro, Statoil, GEUS, and SINTEF for very helpful discussions and Parallab for being helpful with the new IBM, p690 Regatta system.

  10. Diffusive fractionation of trace elements in basaltic melt

    Science.gov (United States)

    Holycross, Megan E.; Bruce Watson, E.

    2016-10-01

    The chemical diffusivities of 25 trace elements (Sc, V, Rb, Sr, Y, Zr, Nb, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, Lu, Hf, Ta, Th, and U) in basaltic melt were measured in diffusion couple experiments performed at 1 GPa pressure and temperatures from 1250 to 1500 °C. Trace element concentration gradients developed in the glasses were simultaneously characterized using laser ablation ICP/MS to create an internally consistent data set. A ratio-fitting technique was employed to accurately determine the relative diffusivities of the rare earth elements (REE). All diffusion coefficients conform to the expected Arrhenius relation D = D 0exp(- E a /RT), where the constant log( D 0, m2/s) ranges from -3.81 to -5.11 and E a ranges from 161.73 to 223.81 kJ/mol. The slowest diffusivities are obtained for the high-field-strength elements; the fastest diffusivities are obtained for the low-field-strength elements. Trace element diffusion in MORB follows the compensation law, where log D 0 is linearly correlated with E a. Arrhenius parameters for diffusion of trivalent REE monotonically increase from La to Lu and are near-linear functions of bond strength (the variation in Arrhenius parameters means that the diffusivities decrease monotonically from La to Lu at a given T). The new data for trace element diffusion in basaltic melt can be used to explore the potential for diffusive fractionation of trace elements using kinetic models. Concentrations of the slower-diffusing heavy REE may be altered relative to those of the faster-diffusing light REE as a diffusive boundary layer develops in melt-melt and crystal-melt systems. The results indicate that diffusion in basalt can be an effective mechanism to fractionate trace elements from one another.

  11. A Study on the Forming Conditions of Basalts in Seamounts of the South China Sea

    Institute of Scientific and Technical Information of China (English)

    李兆麟; 梁德华; 等

    1994-01-01

    Volcanic rocks in seamounts of the South China Sea consist mainly of alkali basalt, tholeiitic basalt, trachyandesitic pumice, dacite, etc.Inclusions in the minerals of the volcanic rocks are main-ly amorphors melt inclusions, which reflects that the volcanic rocks are characterized by submarine eruption and rapid cooling on the seafloor .Furthermore, fluid-melt inclusions have been discovered for the first time in alkali basalts and mantle-derived xenoliths,indicating a process of differentiation between magma and fluid in the course of mantle partial melting .Alkali basalts and inclusions may have been formed in this nonhomogeneous system.Rock-forming temperatures of four seamouns estimated as follows:the Z hongnan seamount alkali basalt 1155-1185℃; the Xianbei seamount alkali basalt 960-1200℃; tholeiitic basalt 1040-1230℃; the Daimao seamount tholeiitic basalt 1245-1280℃; and the Jianfeng seamount trachandestic prmice 880-1140℃. Equilibrium pressures of alkali basalts in the Zhongnan and Xianbei seamounts are 13.57 and 8.8×108 Pa ,respectively. Pyroxene equilibrium tem-peratures of mantle xenoliths from the Xianbei seamount were estimated at 1073-1121℃, and pres-sures ar (15.58-22.47)×108Pa, suggesting a deep-source (e.g.the asthenosphere )for the alkalibasalts.

  12. Flood basalt hosted palaeosols:Potential palaeoclimatic indicators of global climate change

    Institute of Scientific and Technical Information of China (English)

    M.R.G. Sayyed

    2014-01-01

    Since continental sediments (in addition to the marine geological record) offer important means of deciphering environmental changes, the sediments hosted by the successive flows of the continental flood basalt provinces of the world should be treasure houses in gathering the palaeoclimatic data. Palaeosols developed on top of basalt flows are potentially ideal for palaeoenvironmental reconstructions because it is easy to determine their protolith geochemistry and also they define a definite time interval. The present paper summarizes the nature of the basalt-hosted palaeosols formed on the flood basalts provinces from different parts of the globe having different ages.

  13. Radiation shielding properties of a novel cement–basalt mixture for nuclear energy applications

    Energy Technology Data Exchange (ETDEWEB)

    Ipbüker, Cagatay; Nulk, Helena; Gulik, Volodymyr [University of Tartu, Institute of Physics (Estonia); Biland, Alex [HHK Technologies, Houston (United States); Tkaczyk, Alan Henry, E-mail: alan@ut.ee [University of Tartu, Institute of Physics (Estonia)

    2015-04-01

    Highlights: • Basalt fiber is a relatively cheap material that can be used as reinforcement. • Gamma-ray attenuation remains relatively stable with addition of basalt fiber. • Neutron attenuation remains relatively stable with addition of basalt fiber. • Cement–basalt mixture has a good potential for use in nuclear energy applications. - Abstract: The radiation shielding properties of a new proposed building material, a novel cement–basalt fiber mixture (CBM), are investigated. The authors analyze the possibility of this material to be a viable substitute to outgoing materials in nuclear energy applications, which will lead to a further sustained development of nuclear energy in the future. This computational study involves four types of concrete with various amounts of basalt fiber in them. The gamma-ray shielding characteristics of proposed CBM material are investigated with the help of WinXCom program, whereas the neutron shielding characteristics are computed by the Serpent code. For gamma-ray shielding, we find that the attenuation coefficients of concretes with basalt fibers are not notably influenced by the addition of fibers. For neutron shielding, additional basalt fiber in mixture presents negligible effect on neutron radiation shielding. With respect to radiation shielding, it can be concluded that basalt fibers have good potential as an addition to heavyweight concrete for nuclear energy applications.

  14. Trace Element Geochemistry of Hannuoba Ultramafic Inclusion—bearing Alkali Basalts

    Institute of Scientific and Technical Information of China (English)

    支霞臣

    1990-01-01

    Presented in this paper are the trace element abundances of 16 samples of Hannuoba ultramafic inclusion-bearing aldali basalts,which were determined by instrumental neutron activation analysis and X-ray fluorescence spectrometry.The Petrogenesis of the alkali basalt suite has been modeled by batch partial melting and and Rayleigh fractional crystallization processes,The geochemical characteristics of the mantle source from where alkali basalts were derived are described in terms of variations in trace element abundances of the alkali basalt suite.

  15. Basalt fiber manufacturing technology and the possibility of its use in dentistry

    Science.gov (United States)

    Karavaeva, E.; Rogozhnikov, A.; Nikitin, V.; Cherepennikov, Yu; Lysakov, A.

    2015-11-01

    The article touches upon the technology of basalt fiber manufacturing and prospects of its use in dental practice. Two kinds of construction using basalt fiber have been proposed. The first one is a splinting construction for mobile teeth and the second one is the reinforced base for removable plate-denture. The work presents the results of the investigation of physical and mechanical properties of the constructions based on basalt fiber. It also describes the aspects of biomechanical modeling of such constructions in the ANSYS software package. The results of the investigation have proved that applying constructions using basalt fiber is highly promising for prosthetic dentistry practice.

  16. Geology of the Sabie River Basalt Formation in the Southern Kruger National Park

    Directory of Open Access Journals (Sweden)

    R.J. Sweeney

    1986-12-01

    Full Text Available The Sabie River Basalt Formation (SRBF in the central Lebombo is a virtually continuous sequence of basaltic lavas some 2 500 m thick that was erupted 200 - 179 Ma ago. Flows are dominantly pahoehoe in character and vary from 2 m to 20 m in thickness. Dolerite dykes cross-cutting the basalt sequence probably represent feeders to this considerable volcanic event. Volcanological features observed within the SRBF are described. Two chemically distinct basaltic magma types are recognised, the simultaneous eruption of which presents an intriguing geochemical problem as to their origins.

  17. Basalt Waste Isolation Project exploratory shaft site: Final reclamation report

    International Nuclear Information System (INIS)

    The restoration of areas disturbed by activities of the Basalt Waste Isolation Project (BWIP) constitutes a unique operation at the US Department of Energy's (DOE) Hanford Site, both from the standpoint of restoration objectives and the time frame for accomplishing these objectives. The BWIP reclamation program comprises three separate projects: borehole reclamation, Near Surface Test Facility (NSTF) reclamation, and Exploratory Shaft Facility (ESF) reclamation. The main focus of this report is on determining the success of the revegetation effort 1 year after work was completed. This report also provides a brief overview of the ESF reclamation program. 21 refs., 7 figs., 14 tabs

  18. Reclamation report, Basalt Waste Isolation Project, boreholes 1990

    Energy Technology Data Exchange (ETDEWEB)

    Brandt, C.A.; Rickard, W.H. Jr.; Cadoret, N.A.

    1991-01-01

    The restoration of areas disturbed activities of the Basalt Waste Isolation Project (BWIP) has been undertaken by the US Department of Energy (DOE) in fulfillment of obligations and commitments made under the National Environmental Policy Act and the Nuclear Waste Policy Act. This restoration program comprises three separate projects: borehole reclamation, Near Surface Test Facility reclamation, and Exploratory Shaft Facility reclamation. Detailed descriptions of these reclamation projects may be found in a number of previous reports. This report describes the second phase of the reclamation program for the BWIP boreholes and analyzes its success relative to the reclamation objective. 6 refs., 14 figs., 13 tabs.

  19. Final Reclamation Report: Basalt Waste Isolation Project exploratory shaft site

    Energy Technology Data Exchange (ETDEWEB)

    Brandt, C.A.; Rickard, W.H. Jr.

    1990-06-01

    The restoration of areas disturbed by activities of the Basalt Waste Isolation Project (BWIP) constitutes a unique operation at the US Department of Energy's (DOE) Hanford Site, both from the standpoint of restoration objectives and the time frame for accomplishing these objectives. The BWIP reclamation program comprises three separate projects: borehole reclamation, Near Surface Test Facility (NSTF) reclamation, and Exploratory Shaft Facility (ESF) reclamation. The main focus of this report is on determining the success of the revegetation effort 1 year after work was completed. This report also provides a brief overview of the ESF reclamation program. 21 refs., 7 figs., 14 tabs.

  20. Geochemical characterization of tubular alteration features in subseafloor basalt glass

    Science.gov (United States)

    Knowles, Emily; Staudigel, Hubert; Templeton, Alexis

    2013-07-01

    There are numerous indications that subseafloor basalts may currently host a huge quantity of active microbial cells and contain biosignatures of ancient life in the form of physical and chemical basalt glass alteration. Unfortunately, technological challenges prevent us from observing the formation and mineralization of these alteration features in situ, or reproducing tubular basalt alteration processes in the laboratory. Therefore, comprehensive analysis of the physical and chemical traces retained in mineralized tubules is currently the best approach for deciphering a record of glass alteration. We have used a number of high-resolution spectroscopic and microscopic methods to probe the geochemical and mineralogical characteristics of tubular alteration features in basalt glasses obtained from a suite of subseafloor drill cores that covers a range of different collection locations and ages. By combining three different synchrotron-based X-ray measurements - X-ray fluorescence microprobe mapping, XANES spectroscopy, and μ-XRD - with focused ion beam milling and transmission electron microscopy, we have spatially resolved the major and trace element distributions, as well as the oxidation state of Fe, determined the coordination chemistry of Fe, Mn and Ti at the micron-scale, and constrained the secondary minerals within these features. The tubular alteration features are characterized by strong losses of Fe2+, Mn2+, and Ca2+ compared to fresh glass, oxidation of the residual Fe, and the accumulation of Ti and Cu. The predominant phases infilling the alteration regions are Fe3+-bearing silicates dominated by 2:1 clays, with secondary Fe- and Ti-oxides, and a partially oxidized Mn-silicate phase. These geochemical patterns observed within the tubular alteration features are comparable across a diverse suite of samples formed over the past 5-100 Ma, which shows that the microscale mineralization processes are common and consistent throughout the ocean basins and

  1. Basalt weathering in an Arctic Mars-analog site

    Science.gov (United States)

    Yesavage, Tiffany; Thompson, Aaron; Hausrath, Elisabeth M.; Brantley, Susan L.

    2015-07-01

    The martian surface has undergone chemical and physical weathering in the past, and these processes may continue intermittently today. To explore whether martian rocks are likely to retain features indicative of weathering, we investigated how basaltic material weathers on Earth. Specifically, we investigated weathering of a Quaternary-aged basaltic flow at the Sverrefjell volcano in Svalbard, above the Arctic Circle. This flow weathered since deglaciation under cold, dry (characterized the mineralogical and morphological properties using electron microscopy (EM), X-ray diffraction (XRD), infrared (IR) spectroscopy and selective chemical dissolution. In addition, we ran colloidal dispersion, wetting/drying, and freeze/thaw experiments. In the regolith, we observed concentrations of short-range ordered (SRO) phases similar to those observed in warmer, wetter volcanic ash soils. IR and EM analyses of the clay-sized fraction were consistent with allophane as the predominant secondary phase. Selective chemical extractions targeting SRO phases indicated lower Al/Si ratios than those observed in volcanic soils reported in warmer localities, which we attribute to Si-rich allophane and/or abundant Si-rich rock coatings. The oxic circumneutral-pH colloidal dispersion experiments mobilized Al, Fe and Ti primarily as 260-415 nm particles and Ca, Mg and Na as solutes. Si was lost both in the colloidal and dissolved forms. Dispersed colloids likely contain allophane and ferrihydrite. Under anoxic conditions, dissolution of Fe oxide cements also released fines. The experiments help to explain elemental loss from the clay-sized regolith fraction at Svalbard: observed depletions in Ca, K, Mg and Na were likely due to solute loss, while particle-reactive Al, Fe, Si and Ti were mostly retained. Wetting/drying was observed to be as effective as freeze/thaw in driving material loss. It is thus possible that cyclic adsorption of water onto basaltic rocks in this dry climate may result

  2. Structural Analysis of Basalt Fiber Reinforced Plastic Wind Turbine Blade

    Directory of Open Access Journals (Sweden)

    Mengal Ali Nawaz

    2014-07-01

    Full Text Available In this study, Basalt fiber reinforced plastic (BFRP wind turbine blade was analyzed and compared with Glass fiber reinforced plastic blade (GFRP. Finite element analysis (FEA of blade was carried out using ANSYS. Data for FEA was obtained by using rule of mixture. The shell element in ANSYS was used to simulate the wind turbine blade and to conduct its strength analysis. The structural analysis and comparison of blade deformations proved that BFRP wind turbine blade has better strength compared to GFRP wind turbine blade.

  3. Basalt features observed in outcrops, cores, borehole video imagery and geophysical logs, and basalt hydrogeologic study at the Idaho National Engineering Laboratory, Eastern Idaho

    International Nuclear Information System (INIS)

    A study was undertaken to examine permeable zones identified in boreholes open to the underlying basalt and to describe the vertical cross flows present in the boreholes. To understand the permeable zones in the boreholes detailed descriptions and measurements of three outcrops in the Snake River Plain, three cores at the Idaho Chemical Processing Plant (ICPP) at the INEL, and over fifty borehole TV logs from the INEL were carried out. Based on the observations made on the three outcrops an idealized basalt lava flow model was generated that used a set of nomenclature that would be standard for the basalt lava flows studied. An upper vesicular zone, a sometimes absent columnar zone, central zone, and lower vesicular zone make up the basalt lava flow model. The overall distinction between the different zones are based on the vesicle shape size, vesicularity, and fractures present. The results of the studies also indicated that the basalt lava flows at the INEL are distal to medial facies pahoehoe lava flows with close fitting contacts. The most permeable zones identified in these basalts are fractured vesiculated portions of the top of the lava flow, the columnar areas, and basalt-flow contacts in order of importance. This was determined from impeller flowmeter logging at the INEL. Having this information a detailed stratigraphy of individual basalt lava flows and the corresponding permeable units were generated. From this it was concluded that groundwater flow at the ICPP prefers to travel along thin basalt lava flows or flow-units. Flow direction and velocity of intrawell flows detected by flowmeter is controlled by a nearby pumping well

  4. Basalt features observed in outcrops, cores, borehole video imagery and geophysical logs, and basalt hydrogeologic study at the Idaho National Engineering Laboratory, Eastern Idaho

    Energy Technology Data Exchange (ETDEWEB)

    Bennecke, W.M.

    1996-10-01

    A study was undertaken to examine permeable zones identified in boreholes open to the underlying basalt and to describe the vertical cross flows present in the boreholes. To understand the permeable zones in the boreholes detailed descriptions and measurements of three outcrops in the Snake River Plain, three cores at the Idaho Chemical Processing Plant (ICPP) at the INEL, and over fifty borehole TV logs from the INEL were carried out. Based on the observations made on the three outcrops an idealized basalt lava flow model was generated that used a set of nomenclature that would be standard for the basalt lava flows studied. An upper vesicular zone, a sometimes absent columnar zone, central zone, and lower vesicular zone make up the basalt lava flow model. The overall distinction between the different zones are based on the vesicle shape size, vesicularity, and fractures present. The results of the studies also indicated that the basalt lava flows at the INEL are distal to medial facies pahoehoe lava flows with close fitting contacts. The most permeable zones identified in these basalts are fractured vesiculated portions of the top of the lava flow, the columnar areas, and basalt-flow contacts in order of importance. This was determined from impeller flowmeter logging at the INEL. Having this information a detailed stratigraphy of individual basalt lava flows and the corresponding permeable units were generated. From this it was concluded that groundwater flow at the ICPP prefers to travel along thin basalt lava flows or flow-units. Flow direction and velocity of intrawell flows detected by flowmeter is controlled by a nearby pumping well.

  5. Lead isotopes and the sources of the Columbia River Basalt Group

    Science.gov (United States)

    Chamberlain, V. E.; Lambert, R. St. J.

    1994-06-01

    A detailed study of Pb-208/Pb-204, Pb-207/Pb-204, and Pb-206/Pb-204 ratios suggests that the number of Pb isotopic reservoirs required for the Columbia River Basalt Group (CRBG) (as currently defined) must be increased from the presently accepted four to at least six. The identities of the six reservoirs are two of mid-ocean ridge basalt (MORB) slightly contaminated with sediment (R1 and R2, R1 being 'Cascades' PB); one a probable plume component (R3); two of unspecified mantle material but probably of R1 type, contaminated with local crustal Pb (R4 and R5); and the sixth a complex enriched reservoir of 2150 Ma age (R6). R1 is an end-member for all CRBG, except the Saddle Mountains Basalts. R2 is a second end-member for the Picture Gorge Basalt and CRBG, except the Saddle Mountains Basalts. R2 is a second end-member for the Picture Gorge Basalt and appears to be unique to it. R3 is the principal source for most of the Wanapum Basalt, as well as for most of the chemically evolved portions of the Grande Ronde Basalt. Volumetric and tectonic considerations require that one source of the CRBG be a plume or, at least, a nonlocal crustal or uppermost mantle source, and R3 is the ideal candidate for that role. R4 is the second source for the Imnaha Basalt, and R5 is the source for the (206)Pb-rich varieties of the Grande Ronde Basalt. R4 and R5 are identified with contamination by local Phanerozoic crust because of their similarity to local crustal Pb and because the rocks which contain them also have Cu contents correlated with their Pb isotopic compositions. R6 is the parent for Pb in all the Saddle Mountain Basalts. This last source appears to have been homogeneous 2150 m.y. ago but has since split into a number of separate, discrete pockets, each with its own characteristic Pb isotopic signature. Some of these appear in individual Saddle Mountain Basalt flows, while other sources have mixed with R4 to produce individual Saddle Mountain Basalt flows of the Ice Harbor

  6. Radiometric dating of bioalteration textures in Archean basaltic metaglasses

    International Nuclear Information System (INIS)

    Full text: Direct in-situ U-Pb dating of titanite which infills tubular bioalteration textures in pillow basalt rims from the ∼ 3.35 Ga Euro basalt of the Pilbara craton, W. Australia (PWA) confirms their Archean age. A novel in situ laser ablation multi-collector-ICP-MS technique is here reported that has enabled the first radiometric age determination of an Archean biosignature. Multiple lines of evidence suggest that these tubular bioalteration textures formed by microbial etching of formerly glassy Archean lavas that were subsequently mineralized by titanite. Firstly, there are striking morphological similarities between tubular structures from both the Pilbara and Barberton (BGB) cratons and bioalteration textures in modern glasses. Secondly, x-ray mapping indicates C enriched along the margins of the tubular structures from both the BGB and PWA. Thirdly, disseminated carbonates in the BGB pillow rims have C-isotopes depleted by as much as -16 %o, which is consistent with microbial oxidation of organic matter. A pre-metamorphic age for these microtubes is indicated by their segmentation caused by metamorphic chlorite overgrowths. A laser ablation spot size of ∼ 40 μm was used to analyze titanite in the 'root zones' at the centre of microtube clusters. Thirteen analyzes upon three thin sections gave a weighted average 206Pb/238U age of 2921 ± 110 Ma. This corresponds to the oldest metamorphic episode that has affected the PWA rocks and gives a minimum, late Archean age estimate for the bioalteration. (author)

  7. Solubilities of nitrogen and noble gases in basalt melt

    Science.gov (United States)

    Miyazaki, A.; Hiyagon, H.; Sugiura, N.

    1994-01-01

    Nitrogen and noble gases are important tracers in geochemistry and chosmochemistry. Compared to noble gases, however, physicochemical properties of nitrogen, such as solubility in melt or melt/silicate partition, are not well known. Solubility of nitrogen in basalt melt depends on redox condition of the atmosphere. For example, solubility of nitrogen in E chondrite melt under reducing conditions is as high as 2 mol percent at 1500 C, suggesting that nitrogen is chemically dissolved in silicate melts, i.e., being dissolved as free anions or replacing oxygen sites in silicate network. However, the solubility and the dissolution mechanism of nitrogen under oxidizing conditions are not well investigated. To obtain nitrogen solubility in silicate melts under various redox conditions and to understand its mechanism, we are conducting experiments by using (15)N(15)N-labeled nitrogen gas. This makes it easy to distinguish dissolved nitrogen from later contamination of atmospheric nitrogen, and hence enables us to measure the nitrogen solubility accurately. As a preliminary experiment, we have measured solubility of nitrogen in basalt melt under the atmospheric oxygen pressure.

  8. Seismic wave propagation through surface basalts - implications for coal seismic surveys

    Science.gov (United States)

    Sun, Weijia; Zhou, Binzhong; Hatherly, Peter; Fu, Li-Yun

    2010-02-01

    Seismic reflection surveying is one of the most widely used and effective techniques for coal seam structure delineation and risk mitigation for underground longwall mining. However, the ability of the method can be compromised by the presence of volcanic cover. This problem arises within parts of the Bowen and Sydney Basins of Australia and seismic surveying can be unsuccessful. As a consequence, such areas are less attractive for coal mining. Techniques to improve the success of seismic surveying over basalt flows are needed. In this paper, we use elastic wave-equation-based forward modelling techniques to investigate the effects and characteristics of seismic wave propagation under different settings involving changes in basalt properties, its thickness, lateral extent, relative position to the shot position and various forms of inhomogeneity. The modelling results suggests that: 1) basalts with high impedance contrasts and multiple flows generate strong multiples and weak reflectors; 2) thin basalts have less effect than thick basalts; 3) partial basalt cover has less effect than full basalt cover; 4) low frequency seismic waves (especially at large offsets) have better penetration through the basalt than high frequency waves; and 5) the deeper the coal seams are below basalts of limited extent, the less influence the basalts will have on the wave propagation. In addition to providing insights into the issues that arise when seismic surveying under basalts, these observations suggest that careful management of seismic noise and the acquisition of long-offset seismic data with low-frequency geophones have the potential to improve the seismic results.

  9. Intracanyon basalt lavas of the Debed River (northern Armenia), part of a Pliocene-Pleistocene continental flood basalt province in the South Caucasus

    Science.gov (United States)

    Sheth, Hetu; Meliksetian, Khachatur; Gevorgyan, Hripsime; Israyelyan, Arsen; Navasardyan, Gevorg

    2015-03-01

    Late Pliocene to Early Pleistocene (~ 3.25-2.05 Ma), 200-400 m thick basalt lavas outcrop in the South Caucasus region, including the Kars-Erzurum Plateau (northeastern Turkey), the Javakheti Plateau (Georgia-Armenia), and the Lori Plateau (northern Armenia). These fissure-fed, rapidly erupted fluid lavas filled pre-existing river valleys over many tens of kilometres. The basalts exposed in the Debed River canyon, northern Armenia, are ~ 200 m thick and of three morphological types: (1) basal pillow basalts and hyaloclastites, overlain by (2) columnar-jointed pahoehoe sheet flows, in turn overlain by (3) slabby pahoehoe and rubbly pahoehoe flows. The lower and middle lavas show evidence for damming of river drainage, like many lavas of the Columbia River flood basalt province, Scotland, Ireland, and Iceland. There is also evidence for syn-volcanic faulting of the early lavas. Related basalts also outcrop in the Gegham Uplands and the Hrazdan River basin in Armenia. This 3.25-2.05 Ma South Caucasus basalt province, covering parts of Turkey, Georgia and Armenia, has an estimated areal extent of ~ 15,000 km2 and volume of ~ 2250 km3. Because its main geological features are remarkably like those of many continental flood basalt (CFB) provinces, we consider it a true, albeit small, CFB province. It is the smallest and youngest CFB in the world. An analogue closely similar in major features is the Late Miocene Altos de Jalisco CFB province in the western Trans-Mexican Volcanic Belt. Both provinces formed during lithospheric pull-apart and transtensional faulting. Their broader significance is in showing flood basalt size distribution to be a continuum without natural breaks, with implications for geodynamic models.

  10. Conceptual model for regional radionuclide transport from a basalt repository site. Final draft, technical memorandum

    International Nuclear Information System (INIS)

    This technical memorandum was prepared to: (1) describe a typical basalt radionuclide repository site, (2) describe geologic and hydrologic processes associated with regional radionuclide transport in basalts, (3) define the parameters required to model regional radionuclide transport from a basalt repository site, and (4) develop a ''conceptual model'' of radionuclide transport from a basalt repository site. In a general hydrological sense, basalts may be described as layered sequences of aquifers and aquitards. The Columbia River Basalt, centered near the semi-arid Pasco Basin, is considered by many to be typical basalt repository host rock. Detailed description of the flow system including flow velocities with high-low hydraulic conductivity sequences are not possible with existing data. However, according to theory, waste-transport routes are ultimately towards the Columbia River and the lengths of flow paths from the repository to the biosphere may be relatively short. There are many physical, chemical, thermal, and nuclear processes with associated parameters that together determine the possible pattern of radionuclide migration in basalts and surrounding formations. Brief process descriptions and associated parameter lists are provided. Emphasis has been placed on the use of the distribution coefficient in simulating ion exchange. The use of the distribution coefficient approach is limited because it takes into account only relatively fast mass transfer processes. In general, knowledge of hydrogeochemical processes is primitive

  11. Effect of Crystallisation Degree on Hardness of Basaltic Glass-Ceramics

    DEFF Research Database (Denmark)

    Jensen, Martin; Smedskjær, Morten Mattrup; Yue, Yuanzheng

    The dependence of hardness of basaltic glass-ceramics on their crystallisation degree has been explored by means of differential scanning calorimetry, optical microscopy, X-ray diffraction, and Vickers indentation. Different degrees of crystallisation in the basaltic glasses have been obtained...

  12. Spectral evidence for weathered basalt as an alternative to andesite in the northern lowlands of Mars.

    Science.gov (United States)

    Wyatt, Michael B; McSween, Harry Y

    2002-05-16

    Mineral abundances derived from the analysis of remotely sensed thermal emission data from Mars have been interpreted to indicate that the surface is composed of basalt (Surface Type 1) and andesite (Surface Type 2). The global distribution of these rock types is divided roughly along the planetary dichotomy which separates ancient, heavily cratered crust in the southern hemisphere (basalt) from younger lowland plains in the north (andesite). But the existence of such a large volume of andesite is difficult to reconcile with our present understanding of the geological evolution of Mars. Here we reinterpret martian surface rock lithologies using mineral abundances from previous work and new mineralogies derived from a spectral end-member set representing minerals common in unaltered and low-temperature aqueously altered basalts. Our results continue to indicate the dominance of unaltered basalt in the southern highlands, but reveal that the northern lowlands can be interpreted as weathered basalt as an alternative to andesite. The coincidence between locations of such altered basalt and a suggested northern ocean basin implies that lowland plains material may be composed of basalts weathered under submarine conditions or weathered basaltic sediments transported into this depocentre.

  13. Transition from platemargin to intraplate environment: Geochemistry of basalts in Paleogene Liaohe basin, northeastern China

    Institute of Scientific and Technical Information of China (English)

    WU; Changzhi; GU; Lianxing; REN; Zuowei; ZHANG; Zunzhong

    2005-01-01

    Paleogene basalts from the Liaohe basin, northeastern China, are dominated by alkaline olivine basalts and olivine basalts. These basalts are generally enriched in high field strength elements (HFSE), depleted in large ion lithophile elements (LILE) and comparable to those of typical ocean island basalts (OIB). Positive anomalies of Ba, Sr and Zr with high Nb/U, U/Pb, Ce/Pb and Zr/Hf ratios imply that materials from an oceanic crust had been added to the mantle sources of the basalts. In addition, the basalts are generally depleted in Sr, Nd and Pb isotopes, indicating that an enriched mantle (EMI) and a depleted mantle (DM) sources were added to the OIB-like resource.Comprehensive research on lithosphere evolution and tectonic setting of the Liaohe basin and surrounding areas suggests that these basalts were derived by variable degrees of partial melting from an upwelling asthenosphere mantle. Materials from an oceanic lithosphere were added to the source in company with Paleogene tectonic transition from platemargin to intraplate environment. Retreating and steepening of the subducting Pacific oceanic plate could be the main cause for the tectonic environment transition.

  14. Signatures of the source for the Emeishan flood basalts in the Ertan area: Pb isotope evidence

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The Emeishan flood basalts can be divided into high-Ti (HT) basalt (Ti/Y>500) and low-Ti (LT) basalt (Ti/Y<500). Sr, Nd isotopic characteristics of the lavas indicate that the LT- and the HT-type magmas originated from distinct mantle sources and parental magmas. The LT-type magma was derived from a shallower lithospheric mantle, whereas the HT-type magma was derived from a deeper mantle source that may be possibly a mantle plume. However, few studies on the Emeishan flood basalts involved their Pb isotopes, especially the Ertan basalts. In this paper, the authors investigated basalt samples from the Ertan area in terms of Pb isotopes, in order to constrain the source of the Emeishan flood basalts. The ratios of 206Pb/204Pb (18.31-18.41), 207Pb/204Pb (15.55-15.56) and 208Pb/204Pb (38.81-38.94) are significantly higher than those of the depleted mantle, just lying between EM I and EM II. This indicates that the Emeishan HT basalts (in the Ertan area) are the result of mixing of EMI end-member and EMII end-member.

  15. Geochemical constraints on the petrogenesis of basalts from eastern Jiangnan orogen, South China

    Institute of Scientific and Technical Information of China (English)

    唐红峰; 周新民

    1997-01-01

    The basalts crop out widely in the eastern part of late Proterozoic Jiangnan orogen. In terms of their petrographical and geochemical characteristics, they can be divided into two distinct types: low- and high-Ti basalts. They crystallized from the magmas derived from the depleted upper mantle differing in partial melting degree.

  16. Conceptual model for regional radionuclide transport from a basalt repository site. Final draft, technical memorandum

    Energy Technology Data Exchange (ETDEWEB)

    Walton, W.C.; Voorhees, M.L.; Prickett, T.A.

    1980-05-23

    This technical memorandum was prepared to: (1) describe a typical basalt radionuclide repository site, (2) describe geologic and hydrologic processes associated with regional radionuclide transport in basalts, (3) define the parameters required to model regional radionuclide transport from a basalt repository site, and (4) develop a ''conceptual model'' of radionuclide transport from a basalt repository site. In a general hydrological sense, basalts may be described as layered sequences of aquifers and aquitards. The Columbia River Basalt, centered near the semi-arid Pasco Basin, is considered by many to be typical basalt repository host rock. Detailed description of the flow system including flow velocities with high-low hydraulic conductivity sequences are not possible with existing data. However, according to theory, waste-transport routes are ultimately towards the Columbia River and the lengths of flow paths from the repository to the biosphere may be relatively short. There are many physical, chemical, thermal, and nuclear processes with associated parameters that together determine the possible pattern of radionuclide migration in basalts and surrounding formations. Brief process descriptions and associated parameter lists are provided. Emphasis has been placed on the use of the distribution coefficient in simulating ion exchange. The use of the distribution coefficient approach is limited because it takes into account only relatively fast mass transfer processes. In general, knowledge of hydrogeochemical processes is primitive.

  17. Surface modification of basalt with silane coupling agent on asphalt mixture moisture damage

    Science.gov (United States)

    Min, Yahong; Fang, Ying; Huang, Xiaojun; Zhu, Yinhui; Li, Wensheng; Yuan, Jianmin; Tan, Ligang; Wang, Shuangyin; Wu, Zhenjun

    2015-08-01

    A new silane coupling agent was synthesized based on γ-(methacryloyloxy) propyltrimethoxysilane (KH570). The surface of basalt rocks was modified by KH570 and the new silane coupling agent (NSCA), and the interfacial interaction between silane coupling agent and basalt was also studied. Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS) analysis showed that the silane coupling agent molecule bound strongly with basalt rocks. Scanning electronic microscopy (SEM) observation showed that a thin layer of coupling agent was formed on the surface of modified basalt. The boiling test and immersion Marshall test confirmed that the moisture sensitivity of basalt modified with the new silane coupling agent increased more significantly than that untreated and treated with KH570. The Retained Marshall Strength of basalt modified with the new coupling agent increased from 71.74% to 87.79% compared with untreated basalt. The results indicated that the new silane coupling agent played an important role in improving the interfacial performance between basalt and asphalt.

  18. Searching for neuKREEP: An EMP study of Apollo 11 Group A basalts

    Science.gov (United States)

    Jerde, Eric A.; Taylor, Lawrence A.

    1993-01-01

    The Apollo 11 and 17 landing sites are characterized by the presence of high-Ti basalts (TiO2 greater than 6 percent). The Group A basalts of Apollo 11 have elevated K compositions (greater than 2000 ppm); and are enriched in incompatible trace elements relative to the other types of high-Ti basalt found in the region. These unique basalts also are the youngest of all high-Ti basalts, with an age of 3.56 +/- 0.02 Ga. Recent modelling of the Apollo 11 Group A basalts by Jerde et al. has demonstrated that this unique variety of high-Ti basalt may have formed through fractionation of a liquid with the composition of the Apollo 11 orange glass, coupled with assimilation of evolved material (dubbed neuKREEP and having similarities to lunar quartz monzodiorite). Assimilation of this material would impart its REE signature on the liquid, resulting in the elevated REE abundances observed. Minerals such as whitlockite which contain a large portion of the REE budget can be expected to reflect the REE characteristics of the assimilant. To this end, an examination of the whitlockite present in the Apollo 11 Group A basalts was undertaken to search for evidence of the neuKREEP material assimilated.

  19. Post-Columbia River Basalt Group stratigraphy and map compilation of the Columbia Plateau, Oregon

    International Nuclear Information System (INIS)

    This report presents the results of reconnaissance mapping of sedimentary deposits and volcanic rocks overlying the Columbia River Basalt. The project area covers parts of the Dalles, Pendleton, Grangeville, Baker, Canyon City, and Bend. The mapping was done to provide stratigraphic data on the sedimentary deposits and volcanic rocks overlying the Columbia River Basalt Group. 160 refs., 16 figs., 1 tab

  20. Spinel from Apollo 12 Olivine Mare Basalts: Chemical Systematics of Selected Major, Minor, and Trace Elements

    Science.gov (United States)

    Papike, J. J.; Karner, J. M.; Shearer, C. K.; Spilde, M. N.

    2002-01-01

    Spinels from Apollo 12 Olivine basalts have been studied by Electron and Ion microprobe techniques. The zoning trends of major, minor and trace elements provide new insights into the conditions under which planetary basalts form. Additional information is contained in the original extended abstract.

  1. Prokaryotic diversity, distribution, and insights into their role in biogeochemical cycling in marine basalts

    Energy Technology Data Exchange (ETDEWEB)

    Mason, Olivia U.; Di Meo-Savoie, Carol A.; Van Nostrand, Joy D.; Zhou, Jizhong; Fisk, Martin R.; Giovannoni, Stephen J.

    2008-09-30

    We used molecular techniques to analyze basalts of varying ages that were collected from the East Pacific Rise, 9 oN, from the rift axis of the Juan de Fuca Ridge, and from neighboring seamounts. Cluster analysis of 16S rDNA Terminal Restriction Fragment Polymorphism data revealed that basalt endoliths are distinct from seawater and that communities clustered, to some degree, based on the age of the host rock. This age-based clustering suggests that alteration processes may affect community structure. Cloning and sequencing of bacterial and archaeal 16S rRNA genes revealed twelve different phyla and sub-phyla associated with basalts. These include the Gemmatimonadetes, Nitrospirae, the candidate phylum SBR1093 in the c, andin the Archaea Marine Benthic Group B, none of which have been previously reported in basalts. We delineated novel ocean crust clades in the gamma-Proteobacteria, Planctomycetes, and Actinobacteria that are composed entirely of basalt associated microflora, and may represent basalt ecotypes. Finally, microarray analysis of functional genes in basalt revealed that genes coding for previously unreported processes such as carbon fixation, methane-oxidation, methanogenesis, and nitrogen fixation are present, suggesting that basalts harbor previously unrecognized metabolic diversity. These novel processes could exert a profound influence on ocean chemistry.

  2. /sup 87/Sr//sup 86/Sr ratios for basalt from Loihi Seamount, Hawaii

    Energy Technology Data Exchange (ETDEWEB)

    Lanphere, M. (Geological Survey, Menlo Park, CA (USA))

    1983-12-01

    /sup 87/Sr//sup 86/Sr ratios of 15 samples of basalt dredged from Loihi Seamount range from 0.70334 to 0.70368. The basalt types range from tholeiite to basanite in composition and can be divided into six groups on the basis of abundances of K/sub 2/O, Na/sub 2/O, Rb and Sr and /sup 87/Sr//sup 86/Sr ratio. The isotopic data require that the various basalt types be derived from source regions differing in Sr isotopic composition. The Loihi basalts may be produced by mixing of isotopically distinct sources, but the tholeiites and alkalic basalts from Loihi do not show a well-developed inverse trend between Rb/Sr and /sup 87/Sr//sup 86/Sr that is characteristic of the later stages of Hawaiian volcanoes such as Haleakala and Koolau.

  3. Petrogenetic significance of high Fe/Mn ratios of the Cenozoic basalts from Eastern China

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The Cenozoic basalts from eastern China show commonly high Fe/Mn ratios (average = 68.6 ± 11.5) coupled with OIB-type trace element signature. The Cenozoic basalts form the northern margin and the southern margin of the North China Craton are studied in detail. Model calculations point out that the coupling feature of high Fe/Mn ratio with OIB-type trace element signature of these basalts cannot be produced by neither pyroxene/olivine crystallization nor remelting of previously melted mantle, but require partial melting of a garnet pyroxenite-rich mantle source. Combining these features of the Cenozoic basalts with the Phanerozoic lithospheric evolution of the eastern China, we suggest that the Cenozoic basalts were derived from a garnet pyroxenite-rich mantle source associated with continental crust delamination or oceanic crust subduction.

  4. Experimental alteration of basalt glass applied to the alteration of nuclear waste glass

    International Nuclear Information System (INIS)

    The main objective of the experiments was to produce in the laboratory an altered basalt glass similar to basalt glass altered in a natural environment. This objective has been accomplished with a very good correlation between the observed alteration of basalt glass in a natural environment with that in the laboratory. The formation of the amorphous hydration layer, smectite, analcime, calcium carbonate, and thomsonite all have been observed in natural glass samples that have undergone palagonitization. The SRL 165 glass reacts to a greater extent than the synthetic basalt glass under the same conditions. The alteration of SRL 165 glass produced a smectite clay, analcime, and gyrolite similar to that produced by the synthetic basalt glass

  5. Reference waste form, basalts, and ground water systems for waste interaction studies

    Energy Technology Data Exchange (ETDEWEB)

    Deju, R.A.; Ledgerwood, R.K.; Long, P.E.

    1978-09-01

    This report summarizes the type of waste form, basalt, and ground water compositions to be used in theoretical and experimental models of the geochemical environment to be simulated in studying a typical basalt repository. Waste forms to be used in the experiments include, and are limited to, glass, supercalcine, and spent unreprocessed fuel. Reference basalts selected for study include the Pomona member and the Umtanum Unit, Shwana Member, of the Columbia River Basalt Group. In addition, a sample of the Basalt International Geochemical Standard (BCR-1) will be used for cross-comparison purposes. The representative water to be used is of a sodium bicarbonate composition as determined from results of analyses of deep ground waters underlying the Hanford Site. 12 figures, 13 tables.

  6. A preliminary analysis of lunar extra-mare basalts - Distribution, compositions, ages, volumes, and eruption styles

    Science.gov (United States)

    Whitford-Stark, J. L.

    1982-01-01

    Extra-mare basalts occupy 8.5% of the lunar basalt area and comprise 1% of the total mare basalt volume. They are preferentially located where the crust is thin and topographically low. In terms of age, eruption style, and composition they are as variable as the mare basalts. In some instances extrusion in extra-mare craters was preceded by floor-fracturing whereas in other cases it apparently was not. The volume of lava erupted may have been controlled more by the volume of magma produced than by hydrostatic effects. A minimum of nearly 1300 separate basalt eruptions is indicated; the true value could be nearer 30,000 separate eruptions.

  7. Effect of Moisture Absorption Behavior on Mechanical Properties of Basalt Fibre Reinforced Polymer Matrix Composites

    Directory of Open Access Journals (Sweden)

    Amuthakkannan Pandian

    2014-01-01

    Full Text Available The study of mechanical properties of fibre reinforced polymeric materials under different environmental conditions is much important. This is because materials with superior ageing resistance can be satisfactorily durable. Moisture effects in fibre reinforced plastic composites have been widely studied. Basalt fibre reinforced unsaturated polyester resin composites were subjected to water immersion tests using both sea and normal water in order to study the effects of water absorption behavior on mechanical properties. Composites specimens containing woven basalt, short basalt, and alkaline and acid treated basalt fibres were prepared. Water absorption tests were conducted by immersing specimens in water at room temperature for different time periods till they reached their saturation state. The tensile, flexural, and impact properties of water immersed specimens were conducted and compared with dry specimens as per the ASTM standard. It is concluded that the water uptake of basalt fibre is considerable loss in the mechanical properties of the composites.

  8. Constitutive equations of basalt filament tows under quasi-static and high strain rate tension

    International Nuclear Information System (INIS)

    The tensile properties of basalt filament tows were tested at quasi-static (0.001 s-1) and high strain rates (up to 3000 s-1) with MTS materials tester (MTS 810.23) and split Hopkinson tension bar (SHTB), respectively. Experimental results showed that the mechanical properties of the basalt filament tows were rather sensitive to strain rate. Specifically, the stiffness and failure stress of the basalt filament tows increased distinctly as the strain rate increased, while the failure strain decreased. From scanning electronic microscope (SEM) photographs of the fracture surface, it is indicated that the basalt filament tows failed in a more brittle mode and the fracture surface got more regular as the strain rate increases. The strength distributions of the basalt filament tows have been evaluated by a single Weibull distribution function. The curve predicted from the single Weibull distribution function was in good agreement with the experimental data points.

  9. Glass and Mineral Chemistry of Northern Central Indian Ridge Basalts: Compositional Diversity and Petrogenetic Significance

    Institute of Scientific and Technical Information of China (English)

    Dwijesh RAY; Ranadip BANERJEE; Sridhar D IYER; Basavaraju BASAVALINGU; Subir MUKHOPADHYAY

    2009-01-01

    The glass and mineral chemistry of basalts examined from the northern central Indian ridge (NCIR) provides an insight into magma genesis around the vicinity of two transform faults: Vityaz (VT) and Vema (VM). The studied mid-ocean ridge basalts (MORBs) from the outer ridge flank (VT area) and a near-ridge seamount (VM area) reveal that they are moderately phyric plagioclase basalts composed of plagioclase (phenocryst [An_(60-90)] and groundmass [An_(35-79)]), olivine (FO_(81-88)), diopside (Wo_(45-51), En_(25-37), Fs_(14-24)), and titanomagnetite (FeO_t~63.75 wt% and TiO_2 ~22.69 wt%). The whole-rock composition of these basalts has similar Mg# [mole Mg/mole(Mg+Fe~(2+)] (VT basalt: ~0.56-0.58; VM basalt: ~0.57), but differ in their total alkali content (VT basalt: ~2.65; VM basalt: ~3.24). The bulk composition of the magma was gradually depleted in MgO and enriched in FeO_t, TiO_2, P_2O_5, and Na_2O with progressive fractionation, the basalts were gradually enriched in Y and Zr and depleted in Ni and Cr. In addition, the ΣREE of magma also increased with fractionation, without any change in the (La/ Yb)_N value. Glass from the VM seamount shows more fractionated characters (Mg#: 0.56-0.57) compared to the outer ridge flank lava of the VT area (Mg#: 0.63-0.65). This study concludes that present basalts experienced low-pressure crystallization at a relatively shallow depth. The geochemical changes in the NCIR magmas resulted from fractional crystallization at a shallow depth. As a consequence, spinel was the first mineral to crystallize at a pressure 10 kbar, followed by Fe-rich olivine at <10 kbar pressure.

  10. Voluminous Icelandic Basaltic Eruptions Appear To Cause Abrupt Global Warming

    Science.gov (United States)

    Ward, P. L.

    2011-12-01

    Beginning on June 21, 1783, Laki volcano in southern Iceland erupted 14.7 km3 basalt, ejecting 24 Mt SO_{2} into the stratosphere where it was blown eastward and northward and 98 Mt into the troposphere where the jet stream transported it southeastward to Europe. The "dry fog" observed in Europe with an estimated mean concentration of 60 ppbv SO2, raised daytime temperatures as much as 3.3^{o}C, causing the warmest July in England from 1659 when measurements began until 1983. SO2, tropospheric O_{3}, NO2, and fine ash absorb ultraviolet energy from the sun that causes the bonds between and within their atoms to oscillate at 47 times higher frequency than the bonds in CO_{2} absorbing infrared radiation. Temperature is proportional to the kinetic energy of these oscillations, i.e. the frequency squared. Thus these gases are raised to much higher temperatures than greenhouse gases. The Stefan-Boltzmann law says that radiation from these molecules is a constant times temperature raised to the fourth power. As a result, SO2 and ash radiate far more energy back to earth than CO_{2}, causing warming. Another way to look at the energy involved shows that 15 ppbv SO2 in the 0.3-0.42 μm wavelength band absorbs as much solar energy per unit volume as 388,000 ppbv CO_{2} absorbs infrared energy in the 12.7-17.5 μm band. Basaltic volcanoes such as Laki emit 10 to 100 times more SO2 than more evolved magmas and are less explosive, leaving most of the SO_{2} in the troposphere. All 14 Dansgaard-Oeschger (DO) sudden warmings between 46 and 11 ka are contemporaneous with the highest levels of sulfate in the GISP2 drill hole near Summit Greenland. These DO events typically warmed the northern hemisphere out of the ice age within decades, but as volcanism waned, ocean temperatures cooled the world back into an ice age within centuries. The world finally exited the ice age when voluminous volcanism continued from 11.6 to 9.6 ka. Basaltic table mountains or tuyas in Iceland document

  11. Basalt fiber reinforced porous aggregates-geopolymer based cellular material

    Science.gov (United States)

    Luo, Xin; Xu, Jin-Yu; Li, Weimin

    2015-09-01

    Basalt fiber reinforced porous aggregates-geopolymer based cellular material (BFRPGCM) was prepared. The stress-strain curve has been worked out. The ideal energy-absorbing efficiency has been analyzed and the application prospect has been explored. The results show the following: fiber reinforced cellular material has successively sized pore structures; the stress-strain curve has two stages: elastic stage and yielding plateau stage; the greatest value of the ideal energy-absorbing efficiency of BFRPGCM is 89.11%, which suggests BFRPGCM has excellent energy-absorbing property. Thus, it can be seen that BFRPGCM is easy and simple to make, has high plasticity, low density and excellent energy-absorbing features. So, BFRPGCM is a promising energy-absorbing material used especially in civil defense engineering.

  12. Melting of subducted basalt at the core-mantle boundary.

    Science.gov (United States)

    Andrault, Denis; Pesce, Giacomo; Bouhifd, Mohamed Ali; Bolfan-Casanova, Nathalie; Hénot, Jean-Marc; Mezouar, Mohamed

    2014-05-23

    The geological materials in Earth's lowermost mantle control the characteristics and interpretation of seismic ultra-low velocity zones at the base of the core-mantle boundary. Partial melting of the bulk lower mantle is often advocated as the cause, but this does not explain the nonubiquitous character of these regional seismic features. We explored the melting properties of mid-oceanic ridge basalt (MORB), which can reach the lowermost mantle after subduction of oceanic crust. At a pressure representative of the core-mantle boundary (135 gigapascals), the onset of melting occurs at ~3800 kelvin, which is ~350 kelvin below the mantle solidus. The SiO2-rich liquid generated either remains trapped in the MORB material or solidifies after reacting with the surrounding MgO-rich mantle, remixing subducted MORB with the lowermost mantle.

  13. Interim reclamation report: Basalt Waste Isolation Project exploration shaft site

    Energy Technology Data Exchange (ETDEWEB)

    Brandt, C.A.; Rickard, W.H. Jr.; Hefty, M.G.

    1990-02-01

    In 1968, a program was started to assess the feasibility of storing Hanford Site defense waste in deep caverns constructed in basalt. This program was expanded in 1976 to include investigations of the Hanford Site as a potential location for a mined commercial nuclear waste repository. Extensive studies of the geotechnical aspects of the site were undertaken, including preparations for drilling a large diameter Exploratory Shaft. This report describes the development of the reclamation program for the Exploratory Shaft Facility, its implementation, and preliminary estimates of its success. The goal of the reclamation program is to return sites disturbed by the repository program as nearly as practicable to their original conditions using native plant species. 43 refs., 19 figs., 9 tabs.

  14. Geoscience parameter data base handbook: granites and basalts

    Energy Technology Data Exchange (ETDEWEB)

    1979-12-01

    The Department of Energy has the responsibility for selecting and constructing Federal repositories for radioactive waste. The Nuclear Regulatory Commission must license such repositories prior to construction. The basic requirement in the geologic disposal of radioactive waste is stated as: placement in a geologic host whereby the radioactive waste is not in mechanical, thermal or chemical equilibrium with the object of preventing physical or chemical migration of radionuclides into the biosphere or hydrosphere in hazardous concentration (USGS, 1977). The object of this report is to document the known geologic parameters of large granite and basalt occurrences in the coterminous United States, for future evaluation in the selection and licensing of radioactive waste repositories. The description of the characteristics of certain potential igneous hosts has been limited to existing data pertaining to the general geologic character, geomechanics, and hydrology of identified occurrences. A description of the geochemistry is the subject of a separate report.

  15. Interim reclamation report: Basalt Waste Isolation Project exploration shaft site

    International Nuclear Information System (INIS)

    In 1968, a program was started to assess the feasibility of storing Hanford Site defense waste in deep caverns constructed in basalt. This program was expanded in 1976 to include investigations of the Hanford Site as a potential location for a mined commercial nuclear waste repository. Extensive studies of the geotechnical aspects of the site were undertaken, including preparations for drilling a large diameter Exploratory Shaft. This report describes the development of the reclamation program for the Exploratory Shaft Facility, its implementation, and preliminary estimates of its success. The goal of the reclamation program is to return sites disturbed by the repository program as nearly as practicable to their original conditions using native plant species. 43 refs., 19 figs., 9 tabs

  16. Geoscience parameter data base handbook: granites and basalts

    International Nuclear Information System (INIS)

    The Department of Energy has the responsibility for selecting and constructing Federal repositories for radioactive waste. The Nuclear Regulatory Commission must license such repositories prior to construction. The basic requirement in the geologic disposal of radioactive waste is stated as: placement in a geologic host whereby the radioactive waste is not in mechanical, thermal or chemical equilibrium with the object of preventing physical or chemical migration of radionuclides into the biosphere or hydrosphere in hazardous concentration (USGS, 1977). The object of this report is to document the known geologic parameters of large granite and basalt occurrences in the coterminous United States, for future evaluation in the selection and licensing of radioactive waste repositories. The description of the characteristics of certain potential igneous hosts has been limited to existing data pertaining to the general geologic character, geomechanics, and hydrology of identified occurrences. A description of the geochemistry is the subject of a separate report

  17. Continental crustal formation and recycling: Evidence from oceanic basalts

    Science.gov (United States)

    Saunders, A. D.; Tarney, J.; Norry, M. J.

    1988-01-01

    Despite the wealth of geochemical data for subduction-related magma types, and the clear importance of such magmas in the creation of continental crust, there is still no concensus about the relative magnitudes of crustal creation versus crustal destruction (i.e., recycling of crust into the mantle). The role of subducted sediment in the formation of the arc magmas is now well documented; but what proportion of sediment is taken into the deeper mantle? Integrated isotopic and trace element studies of magmas erupted far from presently active subduction zones, in particular basaltic rocks erupted in the ocean basins, are providing important information about the role of crustal recycling. By identifying potential chemical tracers, it is impossible to monitor the effects of crustal recycling, and produce models predicting the mass of material recycled into the mantle throughout long periods of geological time.

  18. Nuclear waste repository in basalt: a design description

    International Nuclear Information System (INIS)

    The conceptual design of a nuclear waste repository in basalt is described. Nuclear waste packages are placed in holes drilled into the floor of tunnels at a depth of 3700 ft. About 100 miles of tunnels are required to receive 35,000 packages. Five shafts bring waste packages, ventilation air, excavated rock, personnel, material, and services to and from the subsurface. The most important surface facility is the waste handling building, located over the waste handling shaft, where waste is received and packaged for storage. Two independent ventilation systems are provided to avoid potential contamination of spaces that do not contain nuclear waste. Because of the high temperatures at depth, an elaborate air chilling system is provided. Because the waste packages deliver a considerable amount of heat energy to the rock mass, particular attention is paid to heat transfer and thermal stress studies. 3 references, 31 figures, 3 tables

  19. Hydrothermal waste package interactions with methane-containing basalt groundwater

    International Nuclear Information System (INIS)

    Hydrothermal waste package interaction tests with methane-containing synthetic basalt groundwater have shown that in the absence of gamma radiolysis, methane has little influence on the glass dissolution rate. Gamma radiolysis tests at fluxes of 5.5 x 105 and 4.4 x 104 R/hr showed that methane-saturated groundwater was more reducing than identical experiments where Ar was substituted for CH4. Dissolved methane, therefore, may be beneficial to the waste package in limiting the solubility of redox sensitive radionuclides such a 99Tc. Hydrocarbon polymers known to form under the irradiation conditions of these tests were not produced. The presence of the waste package constituents apparently inhibited the formation of the polymers, however, the mechanism which prevented their formation was not determined

  20. Aeromagnetic Expression of Buried Basaltic Volcanoes Near Yucca Mountain, Nevada

    Science.gov (United States)

    O'Leary, D. W.; Mankinen, E.A.; Blakely, R.J.; Langenheim, V.E.; Ponce, D.A.

    2002-01-01

    A high-resolution aeromagnetic survey has defined a number of small dipolar anomalies indicating the presence of magnetic bodies buried beneath the surface of Crater Flat and the Amargosa Desert. Results of potential-field modeling indicate that isolated, small-volume, highly magnetic bodies embedded within the alluvial deposits of both areas produce the anomalies. Their physical characteristics and the fact that they tend to be aligned along major structural trends provide strong support for the hypothesis that the anomalies reflect buried basaltic volcanic centers. Other, similar anomalies are identified as possible targets for further investigation. High-resolution gravity and ground-magnetic surveys, perhaps along with drilling sources of selected anomalies and radiometric age determinations, can provide valuable constraints in estimating potential volcanic hazard to the potential nuclear waste repository at Yucca Mountain.

  1. Repository site definition in basalt: Pasco Basin, Washington

    International Nuclear Information System (INIS)

    Discussion of the regional setting, geology, hydrology, and geochemistry of the Pasco Basin are included in this report. Pasco basin is a structural and topographic basin of approximately 2000 mi2 (5180 km2) located within the Yakima Fold Belt Subprovince of the Columbia Plateau. The stratigraphic sequence within the basin consists of an undetermined thickness of lower Miocene and younger flood basalts with interbedded and overlying sedimentary units. This sequence rests upon a basement of probably diverse rock types that may range in age from precambrian through early Tertiary. Although a large amount of information is available on the hydrology of the unconfined aquifer system, ground-water flow within the basin is, in general, poorly understood. Recharge areas for the Mabton interbed and the Saddle Mountains Formation are the highlands surrounding the basin with the flow for these units toward Gable Butte - Gable Mountain and Lake Wallula. Gable Butte - Gable Mountain probably is a ground-water sink, although the vertical flow direction in this zone is uncertain. The amount of upward vertical leakage from the Saddle Mountains Formation into the overlying sediments or to the Columbia River is unknown. Units underlying the Mabton interbed may have a flow scheme similar to those higher units or a flow scheme dominated by interbasin flow. Upward vertical leakage either throughout the basin, dominantly to the Columbia River, or dominantly to Lake Wallula has been proposed for the discharge of the lower units. None of these proposals is verified. The lateral and vertical distribution of major and minor ions in solution, Eh and pH, and ion exchange between basalt and ground-water are not well defined for the basin. Changes in the redox potential from the level of the subsurface facility to the higher stratigraphic levels along with the numerous other factors influencing K/sub d/, result in a poor understanding of the retardation process

  2. Repository site definition in basalt: Pasco Basin, Washington

    Energy Technology Data Exchange (ETDEWEB)

    Guzowski, R.V.; Nimick, F.B.; Muller, A.B.

    1982-03-01

    Discussion of the regional setting, geology, hydrology, and geochemistry of the Pasco Basin are included in this report. Pasco basin is a structural and topographic basin of approximately 2000 mi/sup 2/ (5180 km/sup 2/) located within the Yakima Fold Belt Subprovince of the Columbia Plateau. The stratigraphic sequence within the basin consists of an undetermined thickness of lower Miocene and younger flood basalts with interbedded and overlying sedimentary units. This sequence rests upon a basement of probably diverse rock types that may range in age from precambrian through early Tertiary. Although a large amount of information is available on the hydrology of the unconfined aquifer system, ground-water flow within the basin is, in general, poorly understood. Recharge areas for the Mabton interbed and the Saddle Mountains Formation are the highlands surrounding the basin with the flow for these units toward Gable Butte - Gable Mountain and Lake Wallula. Gable Butte - Gable Mountain probably is a ground-water sink, although the vertical flow direction in this zone is uncertain. The amount of upward vertical leakage from the Saddle Mountains Formation into the overlying sediments or to the Columbia River is unknown. Units underlying the Mabton interbed may have a flow scheme similar to those higher units or a flow scheme dominated by interbasin flow. Upward vertical leakage either throughout the basin, dominantly to the Columbia River, or dominantly to Lake Wallula has been proposed for the discharge of the lower units. None of these proposals is verified. The lateral and vertical distribution of major and minor ions in solution, Eh and pH, and ion exchange between basalt and ground-water are not well defined for the basin. Changes in the redox potential from the level of the subsurface facility to the higher stratigraphic levels along with the numerous other factors influencing K/sub d/, result in a poor understanding of the retardation process.

  3. High-Ti type N-MORB parentage of basalts from the south Andaman ophiolite suite, India

    Indian Academy of Sciences (India)

    Rajesh K Srivastava; R Chandra; Anant Shastry

    2004-12-01

    A complete dismembered sequence of ophiolite is well exposed in the south Andaman region that mainly comprises ultramafic cumulates, serpentinite mafic plutonic and dyke rocks, pillow lava, radiolarian chert, and plagiogranite. Pillow lavas of basaltic composition occupy a major part of the Andaman ophiolite suite (AOS). These basalts are well exposed all along the east coast of southern part of the south AOS. Although these basalts are altered due to low-grade metamorphism and late hydrothermal processes, their igneous textures are still preserved. These basalts are mostly either aphyric or phyric in nature. Aphyric type exhibits intersertal or variolitic textures, whereas phyric variety shows porphyritic or sub-ophitic textures. The content of alkalies and silica classify these basalts as sub-alkaline basalts and alkaline basalts. A few samples show basaltic andesite, trachybasalt, or basanitic chemical composition. High-field strength element (HFSE) geochemistry suggests that studied basalt samples are probably derived from similar parental magmas. Al2O3/TiO2 and CaO/TiO2 ratios classify these basalts as high-Ti type basalt. On the basis of these ratios and many discriminant functions and diagrams, it is suggested that the studied basalts, associated with Andaman ophiolite suite, were derived from magma similar to N-MORB and emplaced in the mid-oceanic ridge tectonic setting.

  4. The mode of emplacement of Neogene flood basalts in eastern Iceland: Facies architecture and structure of simple aphyric basalt groups

    Science.gov (United States)

    Óskarsson, Birgir V.; Riishuus, Morten S.

    2014-12-01

    Simple flows (tabular) in the Neogene flood basalt sections of Iceland are described and their mode of emplacement assessed. The flows belong to three aphyric basalt groups: the Kumlafell group, the Hólmatindur group and the Hjálmadalur group. The groups can be traced over 50 km and originate in the Breiðdalur-Thingmuli volcanic zone. The groups have flow fields that display mixed volcanic facies architecture and can be classified after dominating type morphology. The Kumlafell and the Hólmatindur groups have predominantly simple flows of pāhoehoe and rubbly pāhoehoe morphologies with minor compound or lobate pāhoehoe flows. The Hjálmadalur group has simple flows of rubbly pāhoehoe, but also includes minor compound or lobate flows of rubble and 'a'ā. Simple flows are most common in the distal and medial areas from the vents, while more lobate flows in proximal areas. The simple flows are formed by extensive sheet lobes that are several kilometers long with plane-parallel contacts, some reaching thicknesses of ~ 40 m (aspect ratios inflation structures. Their internal structure consists generally of a simple upper vesicular crust, a dense core and a thin basal vesicular zone. The brecciated flow-top is formed by clinker and crustal rubble, the clinker often welded or agglutinated. The simple flows erupted from seemingly short-lived fissures and have the characteristics of cooling-limited flows. We estimate the effusion rates to be ~ 105 m3/s for the simple flows of the Kumlafell and Hólmatindur groups and ~ 104 m3/s for the Hjálmadalur group. The longest flows advanced 15-20 km from the fissures, with lava streams of fast propagating flows inducing tearing and brecciation of the chilled crust. Compound or lobate areas appear to reflect areas of low effusion rates or the interaction of the lava with topographic barriers or wetlands, resulting in chaotic flowage. Slowing lobes with brecciated flow-tops developed into 'a'ā flows. The groups interdigitated

  5. Probability encoding of hydrologic parameters for basalt. Elicitation of expert opinions from a panel of three basalt waste isolation project staff hydrologists

    International Nuclear Information System (INIS)

    The present study implemented a probability encoding method to estimate the probability distributions of selected hydrologic variables for the Cohassett basalt flow top and flow interior, and the anisotropy ratio of the interior of the Cohassett basalt flow beneath the Hanford Site. Site-speciic data for these hydrologic parameters are currently inadequate for the purpose of preliminary assessment of candidate repository performance. However, this information is required to complete preliminary performance assessment studies. Rockwell chose a probability encoding method developed by SRI International to generate credible and auditable estimates of the probability distributions of effective porosity and hydraulic conductivity anisotropy. The results indicate significant differences of opinion among the experts. This was especially true of the values of the effective porosity of the Cohassett basalt flow interior for which estimates differ by more than five orders of magnitude. The experts are in greater agreement about the values of effective porosity of the Cohassett basalt flow top; their estimates for this variable are generally within one to two orders of magnitiude of each other. For anisotropy ratio, the expert estimates are generally within two or three orders of magnitude of each other. Based on this study, the Rockwell hydrologists estimate the effective porosity of the Cohassett basalt flow top to be generally higher than do the independent experts. For the effective porosity of the Cohassett basalt flow top, the estimates of the Rockwell hydrologists indicate a smaller uncertainty than do the estimates of the independent experts. On the other hand, for the effective porosity and anisotropy ratio of the Cohassett basalt flow interior, the estimates of the Rockwell hydrologists indicate a larger uncertainty than do the estimates of the independent experts

  6. Tracing volatile loss during the eruption of individual flood basalt flows in the Columbia River Flood Basalt Province

    Science.gov (United States)

    Burton, K. W.; Vye, C.; Gannoun, A.; Self, S.

    2010-12-01

    Continental flood basalt (CFB) volcanism is characterised by the repeated eruption of huge batches of magma, producing enormous basalt provinces (105-106 km3) over relatively brief intervals of time, and delivering large masses of volcanic gas to the atmosphere. The release of gases and aerosols during CFB volcanism is thought to have had a significant impact on the atmosphere, ocean chemistry and climate [1-3]. The key factors influencing atmospheric chemistry and the environmental impact of CFB eruptions are the timing, mechanism and duration of volatile release during individual eruptions, but for the most part such information remains poorly known. The 187Re-187Os isotope system offers a highly sensitive tracer of the evolution of melt chemistry, and of the timing and mechanism of volatile release. This is partly because the contrasting behaviour of Re and Os during melting results in the extreme fractionation of parent/daughter (Re/Os) isotope ratios, thus magmatic phases can yield precise chronological information, and crustal rocks develop highly radiogenic isotope compositions that can be readily traced if assimilated [4]. Partly also because Re behaves as a highly volatile element during sub-aerial volcanism [5]. This study presents 187Re-187Os isotope data for rocks and minerals from two flows in the Columbia River Flood Basalt Group, one of the youngest flood basalt provinces that formed over a 2 million year interval in the Mid-Miocene. The 2,660 km3 Sand Hollow flow field displays small major and trace element variations, both laterally and vertically across the flow, indicative of fractional crystallisation, but the elemental data cannot be used to distinguish source variations and/or crustal contamination. However, Os isotopes indicate systematic crustal contamination over the timescale of an individual eruption, where the earliest formed lavas show the greatest degree of contamination. Isotope and elemental data for phenocryst phases from the 40

  7. Extreme Mantle Heterogeneity beneath the Jingpohu Area, Northeastern China-Geochemical Evidence of Holocene Basaltic Rock

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Holocene basaltic rocks of the Jingpohu area are located in the "Crater Forest" and Hamatang districts to the northwest of the Jingpohu Lake. Although there is only a distance of 15 km between the two districts, their petrological characteristics are very different: alkaline olivine basalt without any megacrysts in the former, and leucite tephrite with Ti-amphibole, phlogopite and anorthoclasite megacrysts in the latter. On the basis of their geochemical characteristics, the two types of basaltic rocks should belong to weakly sodian alkaline basalts. But leucite tephrite is characterized by higher Al2O3, Na2O and K2O, higher enrichment in light rare earth elements (LREE) and large ion lithophile elements (LILE), lower MgO and CaO, compatible elements and moderately compatible elements and lower Mg# values and Na/K ratios in comparison with alkaline olivine basalt. However, the two types of basaltic rocks have similar Sr, Nd, Pb isotopic compositions, which suggests that the mantle beneath the Jingpohu area was homogeneous before undergoing some geological processes about 3490 years ago. As the activity of the mantle plume led to different degrees of metasomatism, extreme mantle source heterogeneities occurred beneath the Jingpohu area. In comparison with alkaline olivine basalt, the leucite tephrite was derived from the more enriched mantle source region and resulted from strong metasomatism.

  8. Explosive eruption of coal and basalt and the end-Permian mass extinction.

    Science.gov (United States)

    Ogden, Darcy E; Sleep, Norman H

    2012-01-01

    The end-Permian extinction decimated up to 95% of carbonate shell-bearing marine species and 80% of land animals. Isotopic excursions, dissolution of shallow marine carbonates, and the demise of carbonate shell-bearing organisms suggest global warming and ocean acidification. The temporal association of the extinction with the Siberia flood basalts at approximately 250 Ma is well known, and recent evidence suggests these flood basalts may have mobilized carbon in thick deposits of organic-rich sediments. Large isotopic excursions recorded in this period are potentially explained by rapid venting of coal-derived methane, which has primarily been attributed to metamorphism of coal by basaltic intrusion. However, recently discovered contemporaneous deposits of fly ash in northern Canada suggest large-scale combustion of coal as an additional mechanism for rapid release of carbon. This massive coal combustion may have resulted from explosive interaction with basalt sills of the Siberian Traps. Here we present physical analysis of explosive eruption of coal and basalt, demonstrating that it is a viable mechanism for global extinction. We describe and constrain the physics of this process including necessary magnitudes of basaltic intrusion, mixing and mobilization of coal and basalt, ascent to the surface, explosive combustion, and the atmospheric rise necessary for global distribution.

  9. Geochemical Characteristics and New Eruption Ages of Ruby-Related Basalts from Southeast Kenya

    Institute of Scientific and Technical Information of China (English)

    Tawatchai Chualaowanich; Chakkaphan Sutthirat; Visut Pisuttha-Arnond; Christoph Hauzenberger; Chinghua Lo; Tongyi Lee; Punya Charusiri

    2014-01-01

    Two ruby-related basaltic fields were recently discovered in the southeast region of Kenya, exposed in the Nguu and Ngulai Hills vicinities. These fields host abundant deep-seated xeno-liths, including corundum-bearing granulites. The basalts are alkaline affinity having compositions from foidrite to basanite. The Ngulai basalts have a wider range of SiO2 (38.2 wt.%-44.8 wt.%) cov-ering those of the Nguu basalts (38.7 wt.%-42.3 wt.%). This overlapping behavior also holds for other major oxides and trace elements, e.g., Al2O3, Na2O, K2O, Cr, Ni, Rb and Ga. The overall OIB-like in-compatible patterns with strong K depletion and slight spike of Ti enrichment signatures imply low degrees of partial melting of the upper mantle region source induced under a mantle plume-related process. The K-depletion signature indicates a residual K-bearing phase still retained in the source domain. Chondrite-normalized REE patterns exhibiting strong LREE enrichment without Eu anoma-lies suggest that plagioclase fractionation is insignificant. New40Ar/39Ar ages indicate eruption events occurred during the Pleistocene times, which are around 2 Ma for the Ngulai basalts and 0.9 to 1.6 Ma for the Nguu basalts. Clinopyroxene-basalt thermobarometric calculations yield the equilibriumP-T ranges of ~8-29 kbar and 1 200-1 450 oC.

  10. Petrochemistry and origin of basalt breccia from Ban Sap Sawat area, Wichian Buri, Phetchabun, central Thailand

    Directory of Open Access Journals (Sweden)

    Phisit Limtrakun

    2013-08-01

    Full Text Available Thailand is usually considered to be controlled by escape tectonics associated with India-Asia collision during theLate Cenozoic, and basaltic volcanism took place in this extensional period. This volcanism generated both subaqueous andsubaerial lava flows with tholeiitic to alkalic basaltic magma. The subaqueous eruptions represented by the studied WichianBuri basalts, Ban Sap Sawat in particular, are constituted by two main types of volcanic lithofacies, including lava flows andbasalt breccias. The lava flows are commonly porphyritic with olivine and plagioclase phenocrysts and microphenocrysts,and are uncommonly seriate textured. The basalt breccias are strongly vitrophyric texture with olivine and plagioclasephenocrysts and microphenocrysts. Chemical analyses indicate that both lava flows and basalt breccias have similar geochemical compositions, signifying that they were solidified from the same magma. Their chondrite normalized REE patternsand N-MORB normalized patterns are closely analogous to the Early to Middle Miocene tholeiites from central Sinkhote-Alinand Sakhalin, northeastern margin of the Eurasian continent which were erupted in a continental rift environment. The originfor the Wichian Buri basalts show similarity of lava flows and basalt breccias, in terms of petrography and chemical compositions, signifying that they have been formed from the same continental within-plate, transitional tholeiitic magma.

  11. Measurement of the Dielectric Properties of Volcanic Scoria and Basalt at 9370 MHz

    Institute of Scientific and Technical Information of China (English)

    ZHENG Yongchun; WANG Shijie; OUYANG Ziyuan; LI Xiongyao

    2005-01-01

    Dielectric data for volcanic scoria and basalt on the earth at microwave frequency are extremely sparse, and also crucial for volcanic terrains imaging, and development. In consideration of their similarity to lunar regolith (soils and rocks) in chemical and mineral composition, the dielectric data is significative for passive and active microwave remote sensing on the Moon. This study provides the data about the dielectric properties of three kinds of scoria and two kinds of basalt in China. The method put forward in this paper is also applicable for measuring the dielectric properties of dry rocks and other granular ground materials with low complex dielectric constants. Firstly, the authors measured the ε' and tanδvalues of strip specimens prepared from the mixture of scoria or basalt powder and polythene with the resonant cavity perturbation method at 9370 MHz. Secondly, from the ε' and tanδ values of the mixture, the ε's and ranδs values of solid scoria and basalt were calculated using Lichtenecker's mixture formulae. Finally, the effective complex dielectric constants, ε'e and tanδe, of scoria at different bulk densities were calculated. The results have shown that the ε's and tancδs values of all solid basaltic materials measured (both solid basaltic scoria or basalt) are approximately 7 and 0.05, respectively. With increasing bulk density of scoria, the ε'e and tanδe values of scoria increase significantly.

  12. Basalt generation at the Apollo 12 site. Part 2: Source heterogeneity, multiple melts, and crustal contamination

    Science.gov (United States)

    Neal, Clive R.; Hacker, Matthew D.; Snyder, Gregory A.; Taylor, Lawrence A.; Liu, Yun-Gang; Schmitt, Roman A.

    1994-01-01

    The petrogenesis of Apollo 12 mare basalts has been examined with emphasis on trace-element ratios and abundances. Vitrophyric basalts were used as parental compositions for the modeling, and proportions of fractionating phases were determined using the MAGFOX prograqm of Longhi (1991). Crystal fractionation processes within crustal and sub-crustal magma chambers are evaluated as a function of pressure. Knowledge of the fractionating phases allows trace-element variations to be considered as either source related or as a product of post-magma-generation processes. For the ilmenite and olivine basalts, trace-element variations are inherited from the source, but the pigeonite basalt data have been interpreted with open-system evolution processes through crustal assimilation. Three groups of basalts have been examined: (1) Pigeonite basalts-produced by the assimilation of lunar crustal material by a parental melt (up to 3% assimilation and 10% crystal fractionation, with an 'r' value of 0.3). (2) Ilmenite basalts-produced by variable degrees of partial melting (4-8%) of a source of olivine, pigeonite, augite, and plagioclase, brought together by overturn of the Lunar Magma Ocean (LMO) cumulate pile. After generation, which did not exhaust any of the minerals in the source, these melts experienced closed-system crystal fractionation/accumulation. (3) Olivine basalts-produced by variable degrees of partial melting (5-10%) of a source of olivine, pigeonite, and augite. After generation, again without exhausting any of the minerals in the source, these melts evolved through crystal accumulation. The evolved liquid counterparts of these cumulates have not been sampled. The source compositions for the ilmenite and olivine basalts were calculated by assuming that the vitrophyric compositions were primary and the magmas were produced by non-modal batch melting. Although the magnitude is unclear, evaluation of these source regions indicates that both be composed of early- and

  13. Evolution of the basalts from three back-arc basins of southwest Pacific

    Digital Repository Service at National Institute of Oceanography (India)

    Mudholkar, A.V.; Paropkari, A.L.

    in NiO (&0.3%) and MgO (&17%) but are depleted in TiO 2 (0.5%). These aluminous spinels are indicative of very high pressures, similar to that in the mantle (Dick and Bullen, 1984). The other type of spinel is rich in iron}chromium (Fe}Cr). It has a Fe... (Fig. 5). The bulk composition of this basalt (2186) is similar to that of a primitive basaltic melt in terms of high MgO (11%), and high Ni and Cr concentrations (600 and 300 ppm). The mineralogical data show that olivines in this basalt are highly...

  14. Immiscible iron- and silica-rich melt in basalt petrogenesis documented in the Skaergaard intrusion

    DEFF Research Database (Denmark)

    Jakobsen, Jakob Kløve; Veksler, Ilya; Tegner, Christian;

    2005-01-01

    Silicate liquid immiscibility in basalt petrogenesis is a contentious issue. Immiscible iron and silica-rich liquids were reported in melt inclusions of lunar basalt and in groundmass glasses of terrestrial volcanics. In fully crystallized plutonic rocks, however, silicate liquid immiscibility has...... emulsion of silica and iron-rich liquids. On the outcrop scale, silica-rich (melanogranophyre) pods and layers in iron-rich ferrodiorite of the Upper Zone of the Skaergaard intrusion witness segregation of the two liquids. These findings demand that silicate immiscibility is considered in basalt...

  15. Petrological Characteristics and Genesis of the Central Indian Ocean Basin Basalts

    Digital Repository Service at National Institute of Oceanography (India)

    Das, P.; Iyer, S.D.; Hazra, S.

    " August 19 - 24, Cologne, Germany, A202. Das, P., Iyer, S. D., 2009. Geochemical characterization of oceanic basalts using Artificial Neural Network. Geochemical Transactions, 10:13 doi: 10.1186/1467-4866-10-13. Das, P., Iyer, S. D., Kodagali, V. N... neural network study of the CIOB also helped to geochemically delineate the CIOB basalts to be largely N-MORB but instances of enriched-MORB and ocean island basalt were noticed (Das and Iyer, 2009). The K/Nd ratio (≈ 172 to 752) reflects...

  16. Circumventing shallow air contamination in Mid Ocean Ridge Basalts

    Science.gov (United States)

    Mukhopadhyay, Sujoy; Parai, Rita; Tucker, Jonathan; Middleton, Jennifer; Langmuir, Charles

    2016-04-01

    Noble gases in mantle-derived basalts provide a rich portrait of mantle degassing and surface-interior volatile exchange. However, the ubiquity of shallow-level air contamination frequently obscures the mantle noble gas signal. In a majority of samples, shallow air contamination dominates the noble gas budget. As a result, reconstructing the variability in heavy noble gas mantle source compositions and inferring the history of deep recycling of atmospheric noble gases is difficult. For example, in the gas-rich popping rock 2ΠD43, 129Xe/130Xe ratios reach 7.7±0.23 in individual step-crushes, but the bulk composition of the sample is close to air (129Xe/130Xe of 6.7). Here, we present results from experiments designed to elucidate the source of shallow air contamination in MORBs. Step-crushes were carried out to measure He, Ne, Ar and Xe isotopic compositions on two aliquots of a depleted popping glass that was dredged from between the Kane and Atlantis Fracture Zones of the Mid-Atlantic Ridge in May 2012. One aliquot was sealed in ultrapure N2 after dredge retrieval, while the other aliquot was left exposed to air for 3.5 years. The bulk 20Ne/22Ne and 129Xe/130Xe ratios measured in the aliquot bottled in ultrapure N2 are 12.3 and 7.6, respectively, and are nearly identical to the estimated mantle source values. On the other hand, step crushes in the aliquot left exposed to air for several years show Ne isotopic compositions that are shifted towards air, with a bulk 20Ne/22Ne of 11.5; the bulk 129Xe/130Xe, however, was close to 7.6. These results indicate that lighter noble gases exchange more efficiently between the bubbles trapped in basalt glass and air, suggesting a diffusive or kinetic mechanism for the incorporation of the shallow air contamination. Importantly, in Ne-Ar or Ar-Xe space, step-crushes from the bottled aliquot display a trend that can be easily fit with a simple two-component hyperbolic mixing between mantle and atmosphere noble gases. Step

  17. Ar-Ar and U-Pb geochronology of Late Paleozoic basalts in western Guangxi and its constraints on the eruption age of Emeishan basalt magmatism

    Institute of Scientific and Technical Information of China (English)

    FAN Weiming; WANG Yuejun; PENG Touping; MIAO Laicheng; GUO Feng

    2004-01-01

    The Late Paleozoic layered or stratoid-layered basalts in western Guangxi have similar elemental and isotopic compositions to Emeishan high-Ti basalts. Whole-rock 40Ar/39Ar and SHRIMP zircon U-Pb dating were carried out for the representative basalt samples in three typical profiles in the area. Three basalts from the upper segment of Yangxu profile and lower segment of Yufeng and Min'an profiles yield the 40Ar/39Ar plateau ages of 253.6±0.4 Ma (20BS-71),255.4±0.4 Ma (20BS-99) and 256.2±0.8 Ma (20BS-119), respectively. Twenty-three analyses on 23 zircons of the basalt from the upper segment of Yangxu profile give a weighted mean 206pb/238U age of 253.7±6.1 Ma with an MSWD = 2.8.These new and published geochronological data for Emeishan large igneous province (LIP) indicate that the Emeishan LIP was initiated at ~260 Ma, voluminously erupted between 253 and 256 Ma, and possibly ended at ~251-253Ma' The age (251-260 Ma) is generally consistent with that of the associated environmental deterioration and mass extinction events at the end-Guadalupian and Permo-Triassic boundary. These precise geochronological data provide important constraints on the dominantly eruptive time of the Emeishan LIP and understanding of the distribution of Emeishan high-Ti basalts and its mantle plume dynamics.

  18. Depleted basaltic lavas from the proto-Iceland plume, Central East Greenland

    DEFF Research Database (Denmark)

    Waight, Tod Earle; Baker, Joel A.

    2012-01-01

    New geochemical and isotopic data are presented for volumetrically minor, depleted low-Ti basalts that occur in the Plateau Basalt succession of central East Greenland (CEG), formed during the initial stages of opening of the North Atlantic at 55 Ma. The basalts have MORB-like geochemistry (e...... contamination (isotopic composition (ca. 1% lower for 206Pb/204Pb and 0.1% higher for 87Sr/86Sr depending on the contaminant). Negative ¿Nb suggests a MORB affinity for the low-Ti magmas, however they are distinguished from.......g. depleted LREE) and are distinct from the high-Ti lavas that dominate the sequence. REE geochemistry implies derivation from a source more depleted than the typical MORB source, and suggests polybaric melting and contributions from both spinel and garnet facies mantle. The low-Ti basalts have Sr...

  19. Fluid Composititon and Carbon & Oxygen Isotope Geochemistry of Cenozoic Alkali Basalts in Eastern China

    Institute of Scientific and Technical Information of China (English)

    张铭杰; 王先彬; 等

    1999-01-01

    The fluid compositions of Cenozoic alkali basalts in eastern China have been determined by the pyrolysis-MS method,meanwhile the carbon and oxygen isotopic compositions of CO2 released from these samples at different heating temperatures have been analyzed by the vacuum step-heating method.The data show the volatiole heterogeneity in upper-mantle sources and different evolution trends of alkali basaltic magmas in eastern China,and these alkali basaltic magmas may be generated in the oxidizing milieu,as compared with mantle-derived xenoliths in these alkali basalts,and exotic volatile components were mixed into these magmas in the process of their formation and development.

  20. INVESTIGATION OF SOFTENING AGENT PREPARATION AND PERFORMANCE OF HANDMADE ECOCOMPOSITES WITH CONIFEROUS WOOD AND BASALT FIBERS

    Institute of Scientific and Technical Information of China (English)

    GuangjianWang; DekuShang; KailiangZhang; LinnaHu; ZhenhuaGuo

    2004-01-01

    In this investigation, basalt mineral fiber softening agent was prepared in order to obtain desirable flexible performance. Stability and physical chemistry natures of softening agent were evaluated by particle size distribution, dilution, storage and folding endurance etc. Constitutes of basalt and wood fibers were determined by energy dispersion analysis X-ray which served as an accessory of scanning electron microscopy (SEM-EDAX). Naturally degradable ecocomposite was prepared by basalt and wood fibers. The results of SEM observation illustrated that the wood and basalt fibers were blended uniformly. The impact factors of beating degree, content of wood fibers and adhesive etc. were discussed. The structure of the naturally degradable ecocomposite was contrasted with that of pure wood fibers and the cause of excellent filtration performance was analyzed. Compared with traditional methods, it was of saving wood resource, a large amount of water and reducing second pollution. As a consequence, the ecocomposite harmonized with environment and accorded with requirement of benignly friendly environment.

  1. Melt migration in basalt columns driven by crystallization-induced pressure gradients.

    Science.gov (United States)

    Mattsson, Hannes B; Caricchi, Luca; Almqvist, Bjarne S G; Caddick, Mark J; Bosshard, Sonja A; Hetényi, György; Hirt, Ann M

    2011-01-01

    The structure of columnar-jointed lava flows and intrusions has fascinated people for centuries and numerous hypotheses on the mechanisms of formation of columnar jointing have been proposed. In cross-section, weakly developed semicircular internal structures are a near ubiquitous feature of basalt columns. Here we propose a melt-migration model, driven by crystallization and a coeval specific volume decrease inside cooling and solidifying columns, which can explain the observed macroscopic features in columnar-jointed basalts. We study basalts from Hrepphólar (Iceland), combining macroscopic observations, detailed petrography, thermodynamic and rheological modelling of crystallization sequences, and Anisotropy of Magnetic Susceptibility (AMS) of late crystallizing phases (that is, titanomagnetite). These are all consistent with our proposed model, which also suggests that melt-migration features are more likely to develop in certain evolved basaltic lava flows (with early saturation of titanomagnetite), and that the redistribution of melt within individual columns can modify cooling processes.

  2. Combined Thickness of the Modeled Saddle Mountains Basalt and Mabton Interbed Geomodel Units (smthk_f)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The smthk_f grid represents the modeled combined thickness of the Saddle Mountains Basalt and Mabton interbed geomodel units at a 500 foot resolution. It is one...

  3. Age and petrology of the Kalaupapa Basalt, Molokai, Hawaii ( geochemistry, Sr isotopes).

    Science.gov (United States)

    Clague, D.A.

    1982-01-01

    The post-erosional Kalaupapa Basalt on East Molokai, Hawaii, erupted between 0.34 and 0.57 million years ago to form the Kalaupapa Peninsula. The Kalaupapa Basalt ranges in composition from basanite to lava transitional between alkalic and tholeiitic basalt. Rare-earth and other trace-element abundances suggest that the Kalaupapa Basalt could be generated by 11-17% partial melting of a light-REE-enriched source like that from which the post-erosional lavas of the Honolulu Group on Oahu were generated by 2-11% melting. The 87Sr/86Sr ratios of the lavas range from 0.70320 to 0.70332, suggesting that the variation in composition mainly reflects variation in the melting process rather than heterogeneity of sources. The length of the period of volcanic quiescence that preceded eruption of post-erosional lavas in the Hawaiian Islands decreased as volcanism progressed from Kauai toward Kilauea. - Authors

  4. Mineral chemistry of Carlsberg Ridge basalts at 3 degrees 35'- 3 degrees 41' N

    Digital Repository Service at National Institute of Oceanography (India)

    Iyer, S.D.; Banerjee, R.

    Mineral chemical analyses of transitional basalts from the Carlsberg Ridge show plagioclase (An approximately 87 mole %), phenocrysts, and microphenocrysts have a K sub(2)O depletion as compared to the laths (approximately 79 mole %). Olivine...

  5. Mechanical Properties of Wood Flour Reinforced High Density Polyethylene Composites with Basalt Fibers

    Directory of Open Access Journals (Sweden)

    Guojun LU

    2014-12-01

    Full Text Available Basalt fibers (BFs were surface-treated with a vinyl triethoxy silane coupling agent to improve the mechanical properties of wood fiber-reinforced high density polyethylene (HDPE composites. Basalt fibers were characterized with SEM and FT-IR. The effects of the basalt fiber content and apparent morphology on the mechanical properties of the hybrid composites were investigated in this paper. The results show that the BF coated with the vinyl triethoxy silane coupling agent resulted in an improvement in mechanical properties due to the increased interfacial compatibility between the BF and HDPE. The flexural strength and impact properties significantly increased with 4 wt.% modified basalt fibers. DOI: http://dx.doi.org/10.5755/j01.ms.20.4.6441

  6. Complex Formation History of Highly Evolved Basaltic Shergottite, Zagami

    Science.gov (United States)

    Niihara, T.; Misawa, K.; Mikouchi, T.; Nyquist, L. E.; Park, J.; Hirata, D.

    2012-01-01

    Zagami, a basaltic shergottite, contains several kinds of lithologies such as Normal Zagami consisting of Fine-grained (FG) and Coarse-grained (CG), Dark Mottled lithology (DML), and Olivine-rich late-stage melt pocket (DN). Treiman and Sutton concluded that Zagami (Normal Zagami) is a fractional crystallization product from a single magma. It has been suggested that there were two igneous stages (deep magma chamber and shallow magma chamber or surface lava flow) on the basis of chemical zoning features of pyroxenes which have homogeneous Mg-rich cores and FeO, CaO zoning at the rims. Nyquist et al. reported that FG has a different initial Sr isotopic ratio than CG and DML, and suggested the possibility of magma mixing on Mars. Here we report new results of petrology and mineralogy for DML and the Olivine-rich lithology (we do not use DN here), the most evolved lithology in this rock, to understand the relationship among lithologies and reveal Zagami s formation history

  7. Possible solar noble-gas component in Hawaiian basalts

    Energy Technology Data Exchange (ETDEWEB)

    Honda, Masahiko; McDougall, I.; Patterson, D.B.; Doulgeris, A. (Australian National Univ., Canberra (Australia). Research School of Earth Sciences); Clague, D.A. (Geological Survey, Menlo Park, CA (USA))

    1991-01-10

    The noble-gas elemental and isotopic composition in the Earth is significantly different from that of the present atmosphere, and provides an important clue to the origin and history of the Earth and its atmosphere. Possible candidates for the noble-gas composition of the primordial Earth include a solar-like component, a planetary-like component (as observed in primitive meteorites) and a component similar in composition to the present atmosphere. In an attempt to identify the contributions of such components, we have measured isotope ratios of helium and neon in fresh basaltic glasses dredged from Loihi seamount and the East Rift Zone of Kilauea. We find a systematic enrichment in {sup 20}Ne and {sup 21}Ne relative to {sup 22}Ne, compared with atmospheric neon. The helium and neon isotope signatures observed in our samples can be explained by mixing of solar, present atmospheric, radiogenic and nucleogenic components. These data suggest that the noble-gas isotopic composition of the mantle source of the Hawaiian plume is different from that of the present atmosphere, and that it includes a significant solar-like component. We infer that this component was acquired during the formation of the Earth. (author).

  8. On the puzzle of space weathering alteration of basaltic asteroids

    CERN Document Server

    Marchi, S; Lazzarin, M; Magrin, S

    2010-01-01

    The majority of basaltic asteroids are found in the inner main belt, although a few have also been observed in the outer main belt and near-Earth space. These asteroids -referred to as V-types- have surface compositions that resemble that of the 530km sized asteroid Vesta. Besides the compositional similarity, dynamical evidence also links many V-type asteroids to Vesta. Moreover, Vesta is one of the few asteroids to have been identified as source of specific classes of meteorites, the howardite, eucrite, diogenite achondrites (HEDs). Despite the general consensus on the outlined scenario, several questions remain unresolved. In particular, it is not clear if the observed spectral diversity among Vesta, V-types and HEDs is due to space weathering, as is thought to be the case for S-type asteroids. In this paper, SDSS photometry is used to address the question of whether the spectral diversity among candidate V-types and HEDs can be explained by space weathering. We show that visible spectral slopes of V-types...

  9. Structural change in molten basalt at deep mantle conditions.

    Science.gov (United States)

    Sanloup, Chrystèle; Drewitt, James W E; Konôpková, Zuzana; Dalladay-Simpson, Philip; Morton, Donna M; Rai, Nachiketa; van Westrenen, Wim; Morgenroth, Wolfgang

    2013-11-01

    Silicate liquids play a key part at all stages of deep Earth evolution, ranging from core and crust formation billions of years ago to present-day volcanic activity. Quantitative models of these processes require knowledge of the structural changes and compression mechanisms that take place in liquid silicates at the high pressures and temperatures in the Earth's interior. However, obtaining such knowledge has long been impeded by the challenging nature of the experiments. In recent years, structural and density information for silica glass was obtained at record pressures of up to 100 GPa (ref. 1), a major step towards obtaining data on the molten state. Here we report the structure of molten basalt up to 60 GPa by means of in situ X-ray diffraction. The coordination of silicon increases from four under ambient conditions to six at 35 GPa, similar to what has been reported in silica glass. The compressibility of the melt after the completion of the coordination change is lower than at lower pressure, implying that only a high-order equation of state can accurately describe the density evolution of silicate melts over the pressure range of the whole mantle. The transition pressure coincides with a marked change in the pressure-evolution of nickel partitioning between molten iron and molten silicates, indicating that melt compressibility controls siderophile-element partitioning.

  10. Glass-ceramics obtained by the crystallization of basalt

    Directory of Open Access Journals (Sweden)

    Cocić M.

    2010-01-01

    Full Text Available The possibility to obtain glass-ceramics from basalt from the locality on Vrelo (Kopaonik mt. is shown in this paper. The parent rock was ground to fraction -0.4 +0.1 mm, and then melted at 1250 - 1300°C. The crystallization melted bazaltic glass at 950°C during the time interval of 3 hours caused synthesis of a glass-ceramic material with a microstructure that has excellent mechanical properties according to the determined dynamic modulus of elasticity and uniaxial compresive strength. The phase composition of the obtained glass ceramic material was determined by XRPD using Rietveld refinement and SEM. Two phases were found: pyroxene which corresponds to omphacite of the composition (Na0.199 K0.180 Ca0.471 Mg0.2491.1(Mg0.271Fe0.299Al0.4301.0(Si1.704Ti0.046Al0.2502.0O6 and glass with an approximate relationship 69:31.

  11. Assessing the potential for luminescence dating of basalts

    Science.gov (United States)

    Tsukamoto, S.; Duller, G.A.T.; Wintle, A.G.; Muhs, D.

    2011-01-01

    The possibility of dating basalt using luminescence was tested on four samples with independent age control from Cima volcanic field, California, with the ultimate aim of assessing whether the technique could be used to date sediments on the surface of Mars. Previous analysis of these samples had demonstrated that the infrared stimulated luminescence (IRSL) signal is most suitable for dating as it showed the lowest fading rate among various luminescence signals. In this study, changes in equivalent dose as a function of preheat are described. The ages for the two youngest Cima samples agree with the independent ages based on cosmogenic nuclide measurements (12.0 ?? 0.8 ka). In the two older samples (dated to 320 and 580 ka by K-Ar), the luminescence behaviour is more complex and the form of the IRSL decay curve is seen to vary with dose. Mathematical fitting is used to isolate two components and their intensities are used to produce dose response curves. The slower component yields a larger equivalent dose. However, even using this component and after correction for fading, the ages obtained for the older samples are younger than the K-Ar ages. ?? 2010 Elsevier B.V.

  12. Possible solar noble-gas component in Hawaiian basalts

    Science.gov (United States)

    Honda, M.; McDougall, I.; Patterson, D.B.; Doulgeris, A.; Clague, D.A.

    1991-01-01

    THE noble-gas elemental and isotopic composition in the Earth is significantly different from that of the present atmosphere, and provides an important clue to the origin and history of the Earth and its atmosphere. Possible candidates for the noble-gas composition of the primordial Earth include a solar-like component, a planetary-like component (as observed in primitive meteorites) and a component similar in composition to the present atmosphere. In an attempt to identify the contributions of such components, we have measured isotope ratios of helium and neon in fresh basaltic glasses dredged from Loihi seamount and the East Rift Zone of Kilauea1-3. We find a systematic enrichment in 20Ne and 21Ne relative to 22Ne, compared with atmospheric neon. The helium and neon isotope signatures observed in our samples can be explained by mixing of solar, present atmospheric, radiogenic and nucleogenic components. These data suggest that the noble-gas isotopic composition of the mantle source of the Hawaiian plume is different from that of the present atmosphere, and that it includes a significant solar-like component. We infer that this component was acquired during the formation of the Earth.

  13. Underground engineering at the Basalt Waste Isolation Project

    International Nuclear Information System (INIS)

    A special task group was organized by the US National Committee for Rock Mechanics and the Board on Radioactive Waste Management of the National Research Council to address issues relating to the geotechnical site characterization program for an underground facility to house high-level radioactive waste of the Basalt Waste Isolation Project (BWIP). Intended to provide an overview of the geotechnical program, the study was carried out by a task group consisting of ten members with expertise in the many disciplines required to successfully complete such a project. The task group recognized from the outset that the short time frame of this study would limit its ability to address all geotechnical issues in detail. Geotechnical issues were considered to range from specific technical aspects such as in-situ testing for rock mass permeability; rock hardness testing in the laboratory; or geologic characterizations and quantification of joints, to broader aspects of design philosophy, data collection, and treatment of uncertainty. The task group chose to focus on the broader aspects of underground design and construction, recognizing that the BWIP program utilizes a peer review group on a regular basis which reviews the specific technical questions related to geotechnical engineering. In this way, it was hoped that the review provided by the task group would complement those prepared by the BWIP peer review group

  14. Highly siderophile element abundances in Eoarchean komatiite and basalt protoliths

    Science.gov (United States)

    Frank, Elizabeth A.; Maier, Wolfgang D.; Mojzsis, Stephen J.

    2016-03-01

    Plume-derived, Mg-rich, volcanic rocks (komatiites, high-Mg basalts, and their metamorphic equivalents) can record secular changes in the highly siderophile element (HSE) abundances of mantle sources. An apparent secular time-dependent enrichment trend in HSE abundances from Paleoarchean to Paleoproterozoic mantle-derived rocks could represent the protracted homogenization of a Late Veneer chondritic contaminant into the pre-Late Veneer komatiite source. To search for a possible time dependence of a late accretion signature in the Eoarchean mantle, we report new data from rare >3700 Myr-old mafic and ultramafic schists locked in supracrustal belts from the Inukjuak domain (Québec, Canada) and the Akilia association (West Greenland). Our analysis shows that some of these experienced HSE mobility and/or include a cumulate component (Touboul et al. in Chem Geol 383:63-75, 2014), whereas several of the oldest samples show some of the most depleted HSE abundances measured for rocks of this composition. We consider these new data for the oldest documented rocks of komatiite protolith in light of the Late Veneer hypothesis.

  15. Differential weathering of basaltic and granitic catchments from concentration-discharge relationships

    Science.gov (United States)

    Ibarra, Daniel E.; Caves, Jeremy K.; Moon, Seulgi; Thomas, Dana L.; Hartmann, Jens; Chamberlain, C. Page; Maher, Kate

    2016-10-01

    A negative feedback between silicate weathering rates and climate is hypothesized to play a central role in moderating atmospheric CO2 concentrations on geologic timescales. However, uncertainty regarding the processes that regulate the operation of the negative feedback limits our ability to interpret past variations in the ocean-atmosphere carbon cycle. In particular, the mechanisms that determine the flux of weathered material for a given climatic state are still poorly understood. Here, we quantify the processes that determine catchment-scale solute fluxes for two lithologic end-members-basalt and granite-by applying a recently developed solute production model that links weathering fluxes to both discharge and the reactivity of the weathering material. We evaluate the model against long-term monitoring of concentration-discharge relationships from basaltic and granitic catchments to determine the parameters associated with solute production in each catchment. Higher weathering rates in basaltic catchments relative to granitic catchments are driven by differing responses to increases in runoff, with basaltic catchments showing less dilution with increasing runoff. In addition, results from the solute production model suggest that thermodynamic constraints on weathering reactions could explain higher concentrations in basaltic catchments at lower runoff compared to granitic catchments. To understand how the response to changing discharge controls weathering fluxes under different climatic states, we define basalt/granite weatherability as the ratio of the basalt catchment flux to the granite catchment flux. This weatherability is runoff-dependent and increases with increasing runoff. For HCO3- and SiO2(aq) fluxes, for modern global runoff, the derived mean basalt/granite weatherability is 2.2 (1.3-3.7, 2σ) and 1.7 (1.6-2.1, 2σ), respectively. Although we cannot determine the array of individual processes resulting in differences among catchments, the relative

  16. Episodic entrainment of deep primordial mantle material into ocean island basalts

    OpenAIRE

    Williams, Curtis D.; Li, Mingming; McNamara, Allen K.; Garnero, Edward J.; van Soest, Matthijs C.

    2015-01-01

    Chemical differences between mid-ocean ridge basalts (MORBs) and ocean island basalts (OIBs) provide critical evidence that the Earth's mantle is compositionally heterogeneous. MORBs generally exhibit a relatively low and narrow range of 3He/4He ratios on a global scale, whereas OIBs display larger variability in both time and space. The primordial origin of 3He in OIBs has motivated hypotheses that high 3He/4He ratios are the product of mantle plumes sampling chemically distinct material, bu...

  17. Fracture Analysis of the Ribeirao Preto Basalts, SP: Application for Developing a Conceptual Hydrogeological Model

    Directory of Open Access Journals (Sweden)

    Amélia João Fernandes

    2011-12-01

    Full Text Available The study of the physical geology and geochemistry of the Ribeirão Preto basalts was part of a hydrogeologicalresearch, which aimed to investigate the recharge of the Guarani Aquifer System (SAG through the basalts of the SerraGeral Aquifer (ASG, a project shortly named FRATASG. In addition to the hydrogeological research, a detailed geologicalinvestigation was conducted to develop a conceptual model of groundwater fl ow in complex aquifers, as is the case ofthe fractured basalts of the ASG. Therefore, this study included a thorough structural survey and analysis of horizontaland subvertical fractures, which resulted in the identifi cation of four tectonic events. It was concluded that the verticalgroundwater flow is important up to 10 m in depth and, secondarily, up to 25 m. Horizontal fl ow, more evident up to thedepth of 50 m, predominates and occurs along sub-horizontal fractures, which occur mainly at the contact between basalts2 and 3 and in its vicinity. Because the great majority of subvertical fractures do not propagate into the vesicular layers,which occur at the basalt contacts, it is suggested that these layers act as regional hydraulic barriers, and greatly hamperthe recharge of the SAG through the ASG. As a consequence, groundwater flow in the basalt stack is of stratabound type,as it occurs mainly along the basalt contacts. Based on diagnostic features of the fl ow, it is proposed in this study that the vertical flow,which crosses the basalt stack reaching the SAG, is local and probably occurs along NE structures.

  18. Growing magma chambers control the distribution of small-scale flood basalts.

    Science.gov (United States)

    Yu, Xun; Chen, Li-Hui; Zeng, Gang

    2015-01-01

    Small-scale continental flood basalts are a global phenomenon characterized by regular spatio-temporal distributions. However, no genetic mechanism has been proposed to explain the visible but overlooked distribution patterns of these continental basaltic volcanism. Here we present a case study from eastern China, combining major and trace element analyses with Ar-Ar and K-Ar dating to show that the spatio-temporal distribution of small-scale flood basalts is controlled by the growth of long-lived magma chambers. Evolved basalts (SiO2 > 47.5 wt.%) from Xinchang-Shengzhou, a small-scale Cenozoic flood basalt field in Zhejiang province, eastern China, show a northward younging trend over the period 9.4-3.0 Ma. With northward migration, the magmas evolved only slightly ((Na2O + K2O)/MgO = 0.40-0.66; TiO2/MgO = 0.23-0.35) during about 6 Myr (9.4-3.3 Ma). When the flood basalts reached the northern end of the province, the magmas evolved rapidly (3.3-3.0 Ma) through a broad range of compositions ((Na2O + K2O)/MgO = 0.60-1.28; TiO2/MgO = 0.30-0.57). The distribution and two-stage compositional evolution of the migrating flood basalts record continuous magma replenishment that buffered against magmatic evolution and induced magma chamber growth. Our results demonstrate that the magma replenishment-magma chamber growth model explains the spatio-temporal distribution of small-scale flood basalts. PMID:26581905

  19. Hydrothermal alteration and diagenesis of terrestrial lacustrine pillow basalts: Coordination of hyperspectral imaging with laboratory measurements

    Science.gov (United States)

    Greenberger, Rebecca N; Mustard, John F; Cloutis, Edward A; Mann, Paul; Wilson, Janette H.; Flemming, Roberta L; Robertson, Kevin; Salvatore, Mark R; Edwards, Christopher

    2015-01-01

    We investigate an outcrop of ∼187 Ma lacustrine pillow basalts of the Talcott Formation exposed in Meriden, Connecticut, USA, focusing on coordinated analyses of one pillow lava to characterize the aqueous history of these basalts in the Hartford Basin. This work uses a suite of multidisciplinary measurements, including hyperspectral imaging, other spectroscopic techniques, and chemical and mineralogical analyses, from the microscopic scale up to the scale of an outcrop.

  20. Single and Multi-Date Landsat Classifications of Basalt to Support Soil Survey Efforts

    Directory of Open Access Journals (Sweden)

    Jessica J. Mitchell

    2013-10-01

    Full Text Available Basalt outcrops are significant features in the Western United States and consistently present challenges to Natural Resources Conservation Service (NRCS soil mapping efforts. Current soil survey methods to estimate basalt outcrops involve field transects and are impractical for mapping regionally extensive areas. The purpose of this research was to investigate remote sensing methods to effectively determine the presence of basalt rock outcrops. Five Landsat 5 TM scenes (path 39, row 29 over the year 2007 growing season were processed and analyzed to detect and quantify basalt outcrops across the Clark Area Soil Survey, ID, USA (4,570 km2. The Robust Classification Method (RCM using the Spectral Angle Mapper (SAM method and Random Forest (RF classifications was applied to individual scenes and to a multitemporal stack of the five images. The highest performing RCM basalt classification was obtained using the 18 July scene, which yielded an overall accuracy of 60.45%. The RF classifications applied to the same datasets yielded slightly better overall classification rates when using the multitemporal stack (72.35% than when using the 18 July scene (71.13% and the same rate of successfully predicting basalt (61.76% using out-of-bag sampling. For optimal RCM and RF classifications, uncertainty tended to be lowest in irrigated areas; however, the RCM uncertainty map included more extensive areas of low uncertainty that also encompassed forested hillslopes and riparian areas. RCM uncertainty was sensitive to the influence of bright soil reflectance, while RF uncertainty was sensitive to the influence of shadows. Quantification of basalt requires continued investigation to reduce the influence of vegetation, lichen and loess on basalt detection. With further development, remote sensing tools have the potential to support soil survey mapping of lava fields covering expansive areas in the Western United States and other regions of the world with similar

  1. Geochemical Characteristics and Tectonic Setting of the Laohushan Basalts, North Qilian Mountains

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The Ordovician Laohushan ophiolite, located in the eastern partof the North Qilian Mountains, is mainly composed of meta-peridotites, gabbros and basalts alternating with sediments. The sediments are mainly turbidites, in cluding sandstones, siltstones, cherts etc. Major elements show that the basalts are subalkaline tholeiites and may be analogous to ocean-floor basalts. Except a few N-MORBs, most of the basalts are E-MORBs as indicated by incompatible element ratios such as (La/Ce)N, La/Sm, Ce/Zr, Zr/Y and Zr/Nb. Negative Nb anomaly is common but negative Zr, Hf and Ti anomalies are quite rare. Based on the geochemical characteristics, it is suggested that the Laohushan basalts were formed in a back-arc basin. eNd (t) of the basalts ranges between +3.0 and +8.9 and (87Sr/86Sr)i ranges between 0.7030 and 0.7060, indicating a depleted mantle source which was mixed with more or less enriched mantle components. Further more, the petrography of the sandstones and geochemistry of the cherts suggest that the sediments were deposited near a continental margin.

  2. Depth of volcanic basalt degassing forecasted from CO2 fluid inclusions

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Fluid inclusions have recorded the history of degassing in basalt. Some fluid inclusions in olivine and pyroxene phenocrysts of basalt were analyzed by micro-thermometry and Raman spectroscopy in this paper. The experimental results showed that many inclusions are present almost in a pure CO2 system. The densities of some CO2 inclusions were computed in terms of Raman spectroscopic characteristics of CO2 Fermi resonance at room temperature. Their densities change over a wide range, but mainly between 0.044 g/cm3 and 0.289 g/cm3. Their micro-thermometric measurements showed that the CO2 inclusions examined reached homogenization between 1145.5℃ and 1265℃. The mean value of homogenization temperatures of CO2 inclusions in basalts is near 1210℃. The trap pressures (depths) of inclusions were computed with the equation of state and computer program. Distribution of the trap depths makes it know that the degassing of magma can happen over a wide pressure (depth) range, but mainly at the depth of 0.48 km to 3.85 km. This implicates that basalt magma experienced intensive degassing and the CO2 gas reservoir from the basalt magma also may be formed in this range of depths. The results of this study showed that the depth of basalt magma degassing can be forecasted from CO2 fluid inclusions, and it is meaningful for understanding the process of magma degassing and constraining the inorganogenic CO2 gas reservoir.

  3. Preliminary feasibility study on storage of radioactive wastes in Columbia River basalts. Volume I

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Messrs. D. J.; Isaacson, R. E.; Ledgerwood, R. K.; Taylor, T. W.; Deju, R. A.; Klingsberg, C.; Myers, C. W.

    1976-11-01

    Geologic, hydrologic, heat transfer and rock-waste compatibility studies conducted by the Atlantic Richfield Hanford Company to evaluate the feasibility of storing nuclear wastes in caverns mined out into the Columbia River basalts are discussed. The succession of Columbia River Plateau flood basalts was sampled at various outcrops and in core holes and the samples were analyzed to develop a stratigraphic correlation of the various basalt units and sedimentary interbeds. Hydrologic tests were made in one bore hole to assess the degree of isolation in the various deep aquifers separated by thick basalt accumulations. Earthquake and tectonic studies were conducted to assess the tectonic stability of the Columbia River Plateau. Studies were made to evaluate the extent of heat dissipation from stored radioactive wastes. Geochemical studies were aimed at evaluating the compatibility between the radioactive wastes and the basalt host rocks. Data obtained to-date have allowed development of a hydrostratigraphic framework for the Columbia River Plateau and a preliminary understanding of the deep aquifer systems. Finally, the compilation of this information has served as a basis for planning the studies necessary to define the effectiveness of the Columbia River basalts for permanently isolating nuclear wastes from the biosphere.

  4. Primitive and contaminated basalts from the Southern Rocky Mountains, U.S.A

    Science.gov (United States)

    Doe, B.R.; Lipman, P.W.; Hedge, C.E.; Kurasawa, H.

    1969-01-01

    Basalts in the Southern Rocky Mountains province have been analyzed to determine if any of them are primitive. Alkali plagioclase xenocrysts armored with calcic plagioclase seem to be the best petrographic indicator of contamination. The next best indicator of contamination is quartz xenocrysts armored with clinopyroxene. On the rocks and the region studied, K2O apparently is the only major element with promise of separating primitive basalt from contaminated basalt inasmuch as it constitutes more than 1 % in all the obviously contaminated basalts. K2O: lead (> 4 ppm) and thorium (> 2 ppm) contents and Rb/Sr (> 0.035) are the most indicative of the trace elements studied. Using these criteria, three basalt samples are primitive (although one contains 1.7% K2O) and are similar in traceelement contents to Hawaiian and Eastern Honshu, Japan, primitive basalts. Contamination causes lead isotope ratios, 206Pb/204Pb and 208Pb/204Pb, to become less radiogenic, but it has little or no effect on 87Sr/86Sr. We interpret the effect on lead isotopes to be due to assimilation either of lower crustal granitic rocks, which contain 5-10 times as much lead as basalt and which have been low in U/Pb and Th/Pb since Precambrian times, or of upper crustal Precambrian or Paleozoic rocks, which have lost much of their radiogenic lead because of heating prior to assimilation. The lack of definite effects on strontium isotopes may be due to the lesser strontium contents of granitic crustal rocks relative to basaltic rocks coupled with lack of a large radiogenic enrichment in the crustal rocks. Lead isotope ratios were found to be less radiogenic in plagioclase separates from an obviously contaminated basalt than in the primitive basalts. The feldspar separate that is rich in sodic plagioclase xenocrysts was found to be similar to the whole-rock composition for 206Pb/204Pb and 208Pb/204Pb whereas a more dense fraction probably enriched in more calcic plagioclase phenocrysts is more similar

  5. Fractionation of yttrium and holmium during basaltic soil weathering

    Science.gov (United States)

    Thompson, Aaron; Amistadi, Mary Kay; Chadwick, Oliver A.; Chorover, Jon

    2013-10-01

    The anomalously low affinity of yttrium (Y) for iron (Fe) (oxyhydr)oxides relative to lanthanides with similar ionic radius (e.g., Ho) has been demonstrated in experiments with isolated Fe minerals and in a variety of marine systems that contain high concentrations of solid phase Fe. However, it has not previously been demonstrated to occur during soil genesis, despite the common observation that many soils become enriched in Fe over time. We hypothesized that Y would become progressively depleted in soils relative to Ho with increased weathering. Since, trivalent Y has an anomalously low Misono softness relative to other trivalent ions included in the rare earth element and yttrium group (REY3+), we also investigated whether soil REY fractionation reflects variation in Misono softness. To test this, we measured trends in total REY concentrations for Hawaiian soils derived from basaltic parent materials aged 0.3-4100 ky, and measured REYs released from the same samples during short-time (3 h) dissolution experiments conducted as part of a previous investigation linking dissolution with surface charge properties (Chorover et al., 2004). The chondrite-normalized Y/Ho ratios in the parent Hawaiian basalt (Chond[Y/Ho] = 0.998) and continental dust (Chond[Y/Ho] = 0.994) inputs are remarkably similar, and thus we can interpret deviations from Chond[Y/Ho] ∼ 1.0 to result from soil biogeochemical processes and not source mixing. Between 0.3 and 20 ky, the Chond[Y/Ho] ratio of the subsurface soils decreased from 0.96 ± 0.07(2σ) to 0.71 ± 0.05, and then remained unchanged across the rest of the weathering sequence. In contrast, the Chond[Y/Ho] ratio of the surface soils decreased from 0.99 ± 0.07 to 0.76 ± 0.05 at 150 ky and then, most likely due to continued dust inputs, increased to 1.04 ± 0.07 in the oldest soils. Analysis of the short-time dissolution experiments revealed preferential release of Y relative to Ho (and also La relative Pr) at intermediate pH where

  6. Glass structure and petrogenesis of high-titanium lunar basalts

    Science.gov (United States)

    Finnila, Aleta Berk

    Chapters 1 and 2 use characteristics of the lunar volcanic glass suites to elucidate their petrogenesis and the mineralogy of the lunar mantle. Chapter 1 discusses techniques for calculating the amount of crustal assimilation possible in lunar magma chambers and dikes based on thermal energy balances, kinetic rates, and simple fluid mechanical constraints. The discussion leads to the conclusion that only a small part of the total major element chemical variation in the mare basalt and volcanic glass collection is due to assimilation/fractional crystallization processes near the lunar surface. Chapter 2 analyses a series of piston-cylinder experiments conducted at pressures of 1.0 and 1.5 GPa where ilmenite was dissolved into a lunar red glass composition. The calculated ilmenite saturation surface and experimentally determined ilmenite-olivine cotectic are used to create a TiOsb2-(FeO+MgO)-SiOsb2 pseudo-ternary diagram at 1.0 and 1.5 GPa. These phase diagrams are used to constrain the origin of the high-titanium lunar basalt suite. The projection of the suite of pristine lunar glasses onto the olivine-orthopyroxene cotectic supports having a common deep source of orthopyroxene-olivine-ilmenite±diopside with every mineral except olivine or orthopyroxene being consumed during melt generation. The position and temperature of the ilmenite-olivine-orthopyroxene eutectic constrain melt compositions to having a maximum of approximately 17 wt.% TiOsb2. Chapters 3 and 4 use computer simulations to predict glass structure at the atomic level. Chapter 3 demonstrates the utility of the Monte Carlo simulation method called quantum annealing (QA). Because QA is a relatively new technique, the theory and implementation are described in detail. The QA results compare favorably to molecular dynamics (MD) simulations using the same boundary conditions. While the QA code is not very efficient on a serial architecture, the algorithm is almost perfectly parallel. Using the Cray-T3D

  7. The Mantle and Basalt-Crust Interaction Below the Mount Taylor Volcanic Field, New Mexico

    Science.gov (United States)

    Schrader, Christian M.; Crumpler, Larry S.; Schmidt, Marick E.

    2010-01-01

    The Mount Taylor Volcanic Field (MTVF) lies on the Jemez Lineament on the southeastern margin of the Colorado Plateau. The field is centered on the Mt. Taylor composite volcano and includes Mesa Chivato to the NE and Grants Ridge to the WSW. MTVF magmatism spans approximately 3.8-1.5 Ma (K-Ar). Magmas are dominantly alkaline with mafic compositions ranging from basanite to hy-basalt and felsic compositions ranging from ne-trachyte to rhyolite. We are investigating the state of the mantle and the spatial and temporal variation in basalt-crustal interaction below the MTVF by examining mantle xenoliths and basalts in the context of new mapping and future Ar-Ar dating. The earliest dated magmatism in the field is a basanite flow south of Mt. Taylor. Mantle xenolith-bearing alkali basalts and basanites occur on Mesa Chivato and in the region of Mt. Taylor, though most basalts are peripheral to the main cone. Xenolith-bearing magmatism persists at least into the early stages of conebuilding. Preliminary examination of the mantle xenolith suite suggests it is dominantly lherzolitic but contains likely examples of both melt-depleted (harzburgitic) and melt-enriched (clinopyroxenitic) mantle. There are aphyric and crystal-poor hawaiites, some of which are hy-normative, on and near Mt. Taylor, but many of the more evolved MTVF basalts show evidence of complex histories. Mt. Taylor basalts higher in the cone-building sequence contain >40% zoned plagioclase pheno- and megacrysts. Other basalts peripheral to Mt. Taylor and at Grants Ridge contain clinopyroxene and plagioclase megacrysts and cumulate-textured xenoliths, suggesting they interacted with lower crustal cumulates. Among the questions we are addressing: What was the chemical and thermal state of the mantle recorded by the basaltic suites and xenoliths and how did it change with time? Are multiple parental basalts (Si-saturated vs. undersaturated) represented and, if so, what changes in the mantle or in the tectonic

  8. The variation of magma discharge during basaltic eruptions

    Science.gov (United States)

    Wadge, G.

    1981-12-01

    The rate at which basaltic magma is discharged varies substantially during many eruptions. An individual eruption has an eruption rate ( Qe), the volumetric rate of discharge averaged over the whole or a major part of an eruption, and an effusion rate ( Qf), the volumetric flux rate at any given time. In many examples Qf soon reaches a maximum value after a short period of waxing flow, partly because of magmatic expansion, and then falls more slowly in the later parts of the eruption. The release of elastic strain energy from stored magma and the sub-volcanic reservoir during eruption can produce an exponential form of such waning flow. Comparison of the eruption rates of the historic eruptions of Mauna Loa, Kilauea and Etna shows that for each volcano there is a trend of decreasing Qe with increasing duration of eruption. This relationship is not predicted by a simple elastic model of magma release. Two additional processes are invoked to explain the eruptive histories of these volcanoes: modification of the eruptive conduits, and the continued supply of magma from depth during eruption. Conduits evolving from dikes to plugs by wall-rock erosion or freezing of magma can result in increased early values of Qf and the maintenance of very low values of Qf values for long periods later in the eruption. Discharge variations during three specific eruptions are discussed in detail. Paricutin (1943-1952) had exponentially waning flow, with a time constant of about three years, that is consistent with a deep reservoir. The waning flow of Hekla's 1947-1948 eruption showed some of the characteristics of conduit modification, whilst the 1959 Kilauea Iki eruption is interpreted in terms of a closed system with varying magma rheology.

  9. Spectral characterization of acid weathering products on Martian basaltic glass

    Science.gov (United States)

    Yant, Marcella; Rogers, A. Deanne; Nekvasil, Hanna; Zhao, Yu-Yan Sara; Bristow, Tom

    2016-03-01

    For the first time, direct infrared spectral analyses of glasses with Martian compositions, altered under controlled conditions, are presented in order to assess surface weathering and regolith development on Mars. Basaltic glasses of Irvine and Backstay composition were synthesized and altered using H2SO4-HCl acid solutions (pH 0-4). Scanning electron microscopy/energy dispersive spectroscopy, X-ray diffraction, Raman, and infrared spectral measurements were acquired for each reaction product. Infrared spectra were also acquired from previously synthesized and altered glasses with Pathfinder-measured compositions. Acid alteration on particles in the most acidic solutions (pH ≤ 1) yielded sulfate-dominated visible near infrared (VNIR) and thermal infrared (TIR) spectra with some silica influence. Spectral differences between alteration products from each starting material were present, reflecting strong sensitivity to changes in mineral assemblage. In the TIR, alteration features were preserved after reworking and consolidation. In the VNIR, hydrated sulfate features were present along with strong negative spectral slopes. Although such signatures are found in a few isolated locations on Mars with high-resolution spectrometers, much of the Martian surface lacks these characteristics, suggesting the following: acid alteration occurred at pH ≥ 2; small amounts of sulfates were reworked with unaltered material; there is a prevalence of intermediate-to-high silica glass in Martian starting materials (more resistant to acid alteration); primary or added sulfur were lacking; alteration features are obscured by dust; and/or large-scale, pervasive, acid sulfate weathering of the Martian surface did not occur. These results highlight the need to better understand the spectral properties of altered Martian surface material in order to enhance the interpretation of remote spectra for altered terrains.

  10. Experimental constraints on the outgassing dynamics of basaltic magmas

    Science.gov (United States)

    Pioli, L.; Bonadonna, C.; Azzopardi, B. J.; Phillips, J. C.; Ripepe, M.

    2012-03-01

    The dynamics of separated two-phase flow of basaltic magmas in cylindrical conduits has been explored combining large-scale experiments and theoretical studies. Experiments consisted of the continuous injection of air into water or glucose syrup in a 0.24 m diameter, 6.5 m long bubble column. The model calculates vesicularity and pressure gradient for a range of gas superficial velocities (volume flow rates/pipe area, 10-2-102 m/s), conduit diameters (100-2 m), and magma viscosities (3-300 Pa s). The model is calibrated with the experimental results to extrapolate key flow parameters such as Co (distribution parameter) and Froude number, which control the maximum vesicularity of the magma in the column, and the gas rise speed of gas slugs. It predicts that magma vesicularity increases with increasing gas volume flow rate and decreases with increasing conduit diameter, until a threshold value (45 vol.%), which characterizes churn and annular flow regimes. Transition to annular flow regimes is expected to occur at minimum gas volume flow rates of 103-104 m3/s. The vertical pressure gradient decreases with increasing gas flow rates and is controlled by magma vesicularity (in bubbly flows) or the length and spacing of gas slugs. This study also shows that until conditions for separated flow are met, increases in magma viscosity favor stability of slug flow over bubbly flow but suggests coexistence between gas slugs and small bubbles, which contribute to a small fraction of the total gas outflux. Gas flow promotes effective convection of the liquid, favoring magma homogeneity and stable conditions.

  11. Morphology and dynamics of inflated subaqueous basaltic lava flows

    Science.gov (United States)

    Deschamps, Anne; Grigné, Cécile; Le Saout, Morgane; Soule, Samuel Adam; Allemand, Pascal; Van Vliet-Lanoe, Brigitte; Floc'h, France

    2014-06-01

    eruptions onto low slopes, basaltic Pahoehoe lava can form thin lobes that progressively coalesce and inflate to many times their original thickness, due to a steady injection of magma beneath brittle and viscoelastic layers of cooled lava that develop sufficient strength to retain the flow. Inflated lava flows forming tumuli and pressure ridges have been reported in different kinds of environments, such as at contemporary subaerial Hawaiian-type volcanoes in Hawaii, La Réunion and Iceland, in continental environments (states of Oregon, Idaho, Washington), and in the deep sea at Juan de Fuca Ridge, the Galapagos spreading center, and at the East Pacific Rise (this study). These lava have all undergone inflation processes, yet they display highly contrasting morphologies that correlate with their depositional environment, the most striking difference being the presence of water. Lava that have inflated in subaerial environments display inflation structures with morphologies that significantly differ from subaqueous lava emplaced in the deep sea, lakes, and rivers. Their height is 2-3 times smaller and their length being 10-15 times shorter. Based on heat diffusion equation, we demonstrate that more efficient cooling of a lava flow in water leads to the rapid development of thicker (by 25%) cooled layer at the flow surface, which has greater yield strength to counteract its internal hydrostatic pressure than in subaerial environments, thus limiting lava breakouts to form new lobes, hence promoting inflation. Buoyancy also increases the ability of a lava to inflate by 60%. Together, these differences can account for the observed variations in the thickness and extent of subaerial and subaqueous inflated lava flows.

  12. A brief comparison of lava flows from the Deccan Volcanic Province and the Columbia-Oregon Plateau Flood Basalts: Implications for models of flood basalt emplacement

    Indian Academy of Sciences (India)

    Ninad Bondre; Raymond A Duraiswami; Gauri Dole

    2004-12-01

    The nature and style of emplacement of Continental Flood Basalt (CFB) lava flows has been a atter of great interest as well as considerable controversy in the recent past. However, even a cursory review of published literature reveals that the Columbia River Basalt Group (CRBG) and Hawaiian volcanoes provide most of the data relevant to this topic. It is interesting to note, however, that the CRBG lava flows and their palaeotopographic control is atypical of other CFB provinces in the world. In this paper, we first present a short overview of important studies pertaining to the emplacement of flood basalt flows. We then briefly review the morphology of lava flows from the Deccan Volcanic Province (DVP) and the Columbia-Oregon Plateau flood basalts. The review underscores the existence of significant variations in lava flow morphology between different provinces, and even within the same province. It is quite likely that there were more than one way of emplacing the voluminous and extensive CFB lava flows. We argue that the establishment of general models of emplacement must be based on a comprehensive documentation of lava flow morphology from all CFB provinces.

  13. Statistical factor analysis technique for characterizing basalt through interpreting nuclear and electrical well logging data (case study from Southern Syria).

    Science.gov (United States)

    Asfahani, Jamal

    2014-02-01

    Factor analysis technique is proposed in this research for interpreting the combination of nuclear well logging, including natural gamma ray, density and neutron-porosity, and the electrical well logging of long and short normal, in order to characterize the large extended basaltic areas in southern Syria. Kodana well logging data are used for testing and applying the proposed technique. The four resulting score logs enable to establish the lithological score cross-section of the studied well. The established cross-section clearly shows the distribution and the identification of four kinds of basalt which are hard massive basalt, hard basalt, pyroclastic basalt and the alteration basalt products, clay. The factor analysis technique is successfully applied on the Kodana well logging data in southern Syria, and can be used efficiently when several wells and huge well logging data with high number of variables are required to be interpreted.

  14. Basalt identification by interpreting nuclear and electrical well logging measurements using fuzzy technique (case study from southern Syria).

    Science.gov (United States)

    Asfahani, J; Abdul Ghani, B; Ahmad, Z

    2015-11-01

    Fuzzy analysis technique is proposed in this research for interpreting the combination of nuclear and electrical well logging data, which include natural gamma ray, density and neutron-porosity, while the electrical well logging include long and short normal. The main objective of this work is to describe, characterize and establish the lithology of the large extended basaltic areas in southern Syria. Kodana well logging measurements have been used and interpreted for testing and applying the proposed technique. The established lithological cross section shows the distribution and the identification of four kinds of basalt, which are hard massive basalt, hard basalt, pyroclastic basalt and the alteration basalt products, clay. The fuzzy analysis technique is successfully applied on the Kodana well logging data, and can be therefore utilized as a powerful tool for interpreting huge well logging data with higher number of variables required for lithological estimations.

  15. Alkali basalts and enclosed ultramafic xenoliths near Ushuaia, Tierra Del Fuego, Argentina.

    Science.gov (United States)

    Acevedo, Rogelio Daniel

    2016-01-01

    At the southernmost part of Tierra del Fuego a few outcrops and erratic boulders of alkali basaltic rocks with ultramafic enclaves have been studied. Alkali basalt plugs or pipes hitherto identified are scarce, and host rocks are constituted by slates that belong to Mesozoic deposition. The petrography, texture and composition of the basalt and xenoliths were investigated by petrographic microscope and electron microprobe analysis. Xenocrysts of amphibole and alkali feldspar, phenocrysts of nepheline, olivine, spinel, phlogopite and Fe-Ti minerals (10 %) and a diversity of xenoliths, mainly lherzolitic, pyroxenite and wehrlitic nodules (15 %), but also from metamorphic rocks provenance, are contained in the basalt groundmass (75 %). This finer-grained material is made up of laths or needles of plagioclase, pyroxene, opaque minerals, apatite and glass, with intersertal, hyalopilitic and pilotaxitic. Locally, rock has an even granoblastic texture. Former amygdules are filled by analcite, zeolites, sodalite and calcite. The normative classification, based on nepheline content, conclude that this rock is an alkali basalt. The chemical classification, considering immobile elements as Zr/TiO2 versus Nb/Y indicate an alkali basalt too and plots over the TAS diagram fall in the foidite (Na-rich or nephelinite) and basanite fields. The REE patterns are fractionated (La/Yb primitive mantle normalized is approximately 30). The K-Ar isotopic technique on individual macrocrysts gave ages of 146 ± 5 Ma (amphibole) and 127 ± 4 Ma (alkali feldspar); and K-Ar whole rock datum reported 8.3 ± 0.3 Ma. Nevertheless, fertile samples show geochemical features typical of deep derived material thus, based on the position in the actual tectonic setting, indicate that the basalt is older than its isotopic age.

  16. Interactions between basalts and oil source rocks in rift basins: CO2 generation

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Basalts interbedded with oil source rocks are discovered frequently in rift basins of eastern China, where CO2 is found in reservoirs around or within basalts, for example in the Binnan reservoir of the Dongying Depression. In the reservoirs, CO2 with heavy carbon isotopic composition (δ13C>-10‰ PDB) is in most cases accounts for 40% of the total gas reserve, and is believed to have resulted from degassing of basaltic magma from the mantle. In their investigations of the Binnan reservoir, the authors suggested that the CO2 would result from interactions between the source rocks and basalts. As the source rocks around basalts are rich in carbonate minerals, volcanic minerals, transition metals and organic matter, during their burial history some of the transition metals were catalyzed on the thermal degradation of organic matter into hydrocarbons and on the decomposition of carbonate minerals into CO2, which was reproduced in thermal simulations of the source rocks with the transition metals (Ni and Co). This kind of CO2 accounts for 55%-85% of the total gas reserve generated in the process of thermal simulation, and its δ13C values range from -11‰- -7.2‰ PDB, which are very similar to those of CO2 found in the Binnan reservoir. The co-generation of CO2 and hydrocarbon gases makes it possible their accumulation together in one trap. In other words, if the CO2 resulted directly from degassing of basaltic magma or was derived from the mantle, it could not be accumulated with hydrocarbon gases because it came into the basin much earlier than hydrocarbon generation and much earlier than trap formation. Therefore, the source rocks around basalts generated hydrocarbons and CO2 simultaneously through catalysis of Co and Ni transition metals, which is useful for the explanation of co-accumulation of hydrocarbon gases and CO2 in rift basins in eastern China.

  17. Movement of coliform bacteria and nutrients in ground water flowing through basalt and sand aquifers.

    Science.gov (United States)

    Entry, J A; Farmer, N

    2001-01-01

    Large-scale deposition of animal manure can result in contamination of surface and ground water and in potential transfer of disease-causing enteric bacteria to animals or humans. We measured total coliform bacteria (TC), fecal coliform bacteria (FC), NO3, NH4, total P, and PO4 in ground water flowing from basalt and sand aquifers, in wells into basalt and sand aquifers, in irrigation water, and in river water. Samples were collected monthly for 1 yr. Total coliform and FC numbers were always higher in irrigation water than in ground water, indicating that soil and sediment filtered most of these bacteria before they entered the aquifers. Total coliform and FC numbers in ground water were generally higher in the faster flowing basalt aquifer than in the sand aquifer, indicating that the slower flow and finer grain size may filter more TC and FC bacteria from water. At least one coliform bacterium/100 mL of water was found in ground water from both basalt and sand aquifers, indicating that ground water pumped from these aquifers is not necessarily safe for human consumption according to the American Public Health Association and the USEPA. The NO3 concentrations were usually higher in water flowing from the sand aquifer than in water flowing from the basalt aquifer or in perched water tables in the basalt aquifer. The PO4 concentrations were usually higher in water flowing from the basalt aquifer than in water flowing from the sand aquifer. The main concern is fecal contamination of these aquifers and health consequences that may arise from human consumption.

  18. Geochemical characteristics and petrogenesis of Mesozoic basalts from the North China Craton: A case study in Fuxin, Liaoning Province

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Occurrence of Cretaceous basalts in Fuxin County, Liaoning Province provides us an opportunity to understand Mesozoic mantle processes beneath the northern margin of the North China Craton (NNCC). Fuxin Jianguo basalts occur as volcanic channel phases with well-developed columnar jointings and contain few spinel lherzolite and pyroxenite xenoliths. They are poor in silica and rich in alkalis, Ti and Al, belonging to alkaline basalts. In trace element compositions, Jianguo basalts are moderately enriched in LREE and LILE, but not depleted in HFSE. They have low Sr and high Nd and Pb isotopic ratios. These geochemical characteristics suggest that Jianguo basalts originated from the depleted asthenosphere, representing an undifferentiated and uncontaminated primitive magma. Presence of these basalts indicates that the lithosphere beneath the region had thickness less than 65 km at the time of basalt eruption and was mainly composed of fertile pargasite-bearing spinel lherzolite and plagioclase pyroxenite. The voluminous basaltic-andesitic magmatism during the early Jurassic-late Cretaceous time indicates that the commencement and accomplishment of lithosphere thinning in the NNCC was much earlier than that in the southern margin, since the mafic-intermediate volcanism only occurred at the Cretaceous time in the southern margin and the basalts with an asthenosphere isotopic signature at the Tertiary. This shows that highly spatial and temporal heterogeneity existed in the Mesozoic lithosphere evolution.

  19. Technical support for GEIS: radioactive waste isolation in geologic formations. Volume 7. Baseline rock properties-basalt

    International Nuclear Information System (INIS)

    This volume, Y/OWI/TM-36/7 Baseline Rock Properties--Basalt, is one of a 23-volume series, ''Technical Support for GEIS: Radioactive Waste Isolation in Geologic Formations, Y/OWI/TM-36'' which supplements a ''Contribution to Draft Generic Environmental Impact Statement on Commercial Waste Management: Radioactive Waste Isolation in Geologic Formations, Y/OWI/TM-44.'' The series provides a more complete technical basis for the preconceptual designs, resource requirements, and environmental source terms associated with isolating commercial LWR wastes in underground repositories in salt, granite, shale and basalt. Wastes are considered from three fuel cycles: uranium and plutonium recycling, no recycling of spent fuel and uranium-only recycling. This report contains an evaluation of the results of a literature survey to define the rock mass properties of a generic basalt, which could be considered as a geological medium for storing radioactive waste. The general formation and structure of basaltic rocks is described. This is followed by specific descriptions and rock property data for the Dresser Basalt, the Amchitka Island Basalt, the Nevada Test Site Basalt and the Columbia River Group Basalt. Engineering judgment has been used to derive the rock mass properties of a typical basalt from the relevant intact rock property data and the geological information pertaining to structural defects, such as joints and faults

  20. Technical support for GEIS: radioactive waste isolation in geologic formations. Volume 7. Baseline rock properties-basalt

    Energy Technology Data Exchange (ETDEWEB)

    1978-04-01

    This volume, Y/OWI/TM-36/7 Baseline Rock Properties--Basalt, is one of a 23-volume series, ''Technical Support for GEIS: Radioactive Waste Isolation in Geologic Formations, Y/OWI/TM-36'' which supplements a ''Contribution to Draft Generic Environmental Impact Statement on Commercial Waste Management: Radioactive Waste Isolation in Geologic Formations, Y/OWI/TM-44.'' The series provides a more complete technical basis for the preconceptual designs, resource requirements, and environmental source terms associated with isolating commercial LWR wastes in underground repositories in salt, granite, shale and basalt. Wastes are considered from three fuel cycles: uranium and plutonium recycling, no recycling of spent fuel and uranium-only recycling. This report contains an evaluation of the results of a literature survey to define the rock mass properties of a generic basalt, which could be considered as a geological medium for storing radioactive waste. The general formation and structure of basaltic rocks is described. This is followed by specific descriptions and rock property data for the Dresser Basalt, the Amchitka Island Basalt, the Nevada Test Site Basalt and the Columbia River Group Basalt. Engineering judgment has been used to derive the rock mass properties of a typical basalt from the relevant intact rock property data and the geological information pertaining to structural defects, such as joints and faults.

  1. A chemical model for generating the sources of mare basalts - Combined equilibrium and fractional crystallization of the lunar magmasphere

    Science.gov (United States)

    Snyder, Gregory A.; Taylor, Lawrence A.; Neal, Clive R.

    1992-01-01

    A chemical model for simulating the sources of the lunar mare basalts was developed by considering a modified mafic cumulate source formed during the combined equilibrium and fractional crystallization of a lunar magma ocean (LMO). The parameters which influence the initial LMO and its subsequent crystallization are examined, and both trace and major elements are modeled. It is shown that major elements tightly constrain the composition of mare basalt sources and the pathways to their creation. The ability of this LMO model to generate viable mare basalt source regions was tested through a case study involving the high-Ti basalts.

  2. The Giant Lavas of Kalkarindji: rubbly pāhoehoe lava in an ancient continental flood basalt province

    OpenAIRE

    Marshall, Peter E.; Widdowson, Mike; Murphy, David T.

    2016-01-01

    The Kalkarindji continental flood basalt province of northern Australia erupted in the mid Cambrian (c. 511-505 Ma). It now consists of scattered basaltic lava fields, the most extensive being the Antrim Plateau Volcanics (APV) - a semi-continuous outcrop (c. 50,000 km2) reaching a maximum thickness of 1.1 km. Cropping out predominately in the SW of the APV, close to the top of the basalt succession, lies the Blackfella Rockhole Member (BRM). Originally described as ‘basaltic agglomerate’ the...

  3. Experimental Evidence for Polybaric Intracrustal Differentiation of Primitive Arc Basalt beneath St. Vincent, Lesser Antilles

    Science.gov (United States)

    Blundy, Jon; Melekhova, Lena; Robertson, Richard

    2014-05-01

    We present experimental phase equilibria for a primitive, high-Mg basalt from St. Vincent, Lesser Antilles. Experimental details were presented in Melekhova et al (Nature Geosci, 2013); the objective here is to compare experimental phase compositions to those of erupted lavas and cumulates from St. Vincent. Starting material with 4.5 wt% H2O is multiply-saturated with a lherzolite assemblage at 1.3 GPa and 1180 ° C, consistent with mantle wedge derivation. Experimental glasses from our study, in addition to those of Pichavant et al (GCA, 2002) and Pichavant & Macdonald (CMP 2007) on a similar high-Mg basalt, encompass a compositional range from high-magnesian basalt to dacite, with a systematic dependence on H2O content, temperature and pressure. We are able to match the glasses from individual experiments to different lava types, so as to constrain the differentiation depths at which these magmas could be generated from a high-Mg parent, as follows: Composition wt% H2OP (GPa) T (° C) High-Mg basalt 3.9-4.8 1.45-1.751180-1200 Low-Mg basalt 2.3-4.5 1.0-1.3 1065-1150 High alumina basalt 3.0-4.5 0.4 1050-1080 Basaltic andesite 0.6-4.5 0.7-1.0 1050-1130 Andesite 0.6 1.0 1060-1080 The fact that St. Vincent andesites (and some basaltic andesites) appear to derive from a low-H2O (0.6 wt%) parent suggest that they are products of partial melting of older, high-Mg gabbroic rocks, as 0.6 wt% H2O is approximately the amount that can be stored in amphibole-bearing gabbros. The higher H2O contents of parents for the other lava compositions is consistent with derivation by crystallization of basalts with H2O contents that accord with those of olivine-hosted melt inclusions from St. Vincent (Bouvier et al, J Petrol, 2008). The generation of evolved melts both by basalt crystallization and gabbro melting is consistent with the hot zone concept of Annen et al (J Petrol, 2006) wherein repeated intrusion of mantle-derived basalt simultaneously crystallize by cooling and melt

  4. Viscous flow behavior of tholeiitic and alkaline Fe-rich martian basalts

    Science.gov (United States)

    Chevrel, Magdalena Oryaëlle; Baratoux, David; Hess, Kai-Uwe; Dingwell, Donald B.

    2014-01-01

    The chemical compositions of martian basalts are enriched in iron with respect to terrestrial basalts. Their rheology is poorly known and liquids of this chemical composition have not been experimentally investigated. Here, we determine the viscosity of five synthetic silicate liquids having compositions representative of the diversity of martian volcanic rocks including primary martian mantle melts and alkali basalts. The concentric cylinder method has been employed between 1500 °C and the respective liquidus temperatures of these liquids. The viscosity near the glass transition has been derived from calorimetric measurements of the glass transition. Although some glass heterogeneity limits the accuracy of the data near the glass transition, it was nevertheless possible to determine the parameters of the non-Arrhenian temperature-dependence of viscosity over a wide temperature range (1500 °C to the glass transition temperature). At superliquidus conditions, the martian basalt viscosities are as low as those of the Fe-Ti-rich lunar basalts, similar to the lowest viscosities recorded for terrestrial ferrobasalts, and 0.5 to 1 order of magnitude lower than terrestrial tholeiitic basalts. Comparison with empirical models reveals that Giordano et al. (2008) offers the best approximation, whereas the model proposed by Hui and Zhang (2007) is inappropriate for the compositions considered. The slightly lower viscosities exhibited by the melts produced by low degree of mantle partial melting versus melts produced at high degree of mantle partial melting (likely corresponding to the early history of Mars), is not deemed sufficient to lead to viscosity variations large enough to produce an overall shift of martian lava flow morphologies over time. Rather, the details of the crystallization sequence (and in particular the ability of some of these magmas to form spinifex texture) is proposed to be a dominant effect on the viscosity during martian lava flow emplacement and

  5. Siderophile and chalcophile metal variations in Tertiary picrites and basalts from West Greenland with implications for the sulphide saturation history of continental flood basalt magmas

    Science.gov (United States)

    Keays, Reid R.; Lightfoot, Peter C.

    2007-04-01

    Sixty-five million year old continental flood basalts crop out on Qeqertarssuaq Island and the Nuussuaq Peninsula in West Greenland, and they include ˜1,000 m of picritic lavas and discrete 10- to 50-m-thick members of highly contaminated basalts. On Qeqertarssuaq, the lavas are allocated to the Vaîgat and Maligât Formations of which the former includes the Naujánguit member, which consists of picrites with 7-29 wt% MgO, 80-1,400 ppm Ni, 5.7-9.4 ppb Pt and 4.2-12.9 ppb Pd. The Naujánguit member contains two horizons of contaminated basalts, the Asûk and Kûgánguaq, which have elevated SiO2 (52-58 wt%) and low to moderate MgO (7.5-12.8 wt%). These lavas are broadly characterized by low Cu and Ni abundances (average, 40 ppm Ni and 45 ppm Cu) and very low Pt (0.16-0.63 ppb) and Pd (0.13-0.68 ppb) abundances, and in the case of the Asûk, they contain shale xenoliths and droplets of native iron and troilite. The contaminated basalts from Nuussuaq, the B0 to B4 members, are also usually Ni-, Cu-, and platinum-group elements (PGE)-depleted. The geochemical signatures (especially the ratios of incompatible trace elements such as Th/Nb) of all of the contaminated basalts from Qeqertarssuaq and some of those from Nuussuaq record what appears to be a chemical contribution from deltaic shales that lie immediately below the lavas. This suggests that the contamination of the magmas occurred during the migration of the magmas through plumbing systems developed in sedimentary rocks, and hence, at a high crustal level. Nickel, Cu, and PGE depletion together with geochemical signatures produced by crustal contamination are also a feature of Siberian Trap basalts from the Noril’sk region. These basalts belong to the 0- to 500-m thick, ˜5,000- to 10,000-km3 Nadezhdinsky Formation, which is centered in the Noril’sk Region. A major difference between Siberia and West Greenland is that PGE depletion in the Nadezhdinsky Formation samples with the lowest Cu and Ni contents is

  6. Characteristics of platinum-group elements in basalts from spreading axis of Mariana Trough

    Institute of Scientific and Technical Information of China (English)

    CAO Zhimin; ZHENG Jianbin; ZHOU Meifu; AN Wei; QI Liang

    2007-01-01

    Total platinum-group elements (PGEs) abundances in basalts from the spreading axis of Mariana Trough ranged from 0.418 × 10-9 to 1.022 × 10-9, and primitive mantle-normalized PGE patterns are of positive slope showing the relative enrichment of PPGE (platinum, palladium, rhodium) and gold relative to IPGE. Compared with other mantle-originated rocks, these basalts have lower PGE contents and wider ranges of primitive mantle-normalized ratios of palladium content to iridium one, palladium content to platinum one and palladium content to gold one exhibiting relative platinum and iridium depletion. Characteristics of PGE patterns indicated that the studied Mariana Trough basalts originated from low partial melting, and the MORB mantle beneath the spreading center had been contaminated by the arc-island mantle. In the aspect of trace elements, Mariana Trough basalts showed the enrichment of LILE, lead and LREE, indicating that they had been influenced by subduction compositions. All these demonstrated that Mariana Trough basalts are products of partial melting from a mixed mantle ( the contamination of MORB mantle by arc-island mantle).

  7. A novel basalt fiber-reinforced polylactic acid composite for hard tissue repair.

    Science.gov (United States)

    Chen, Xi; Li, Yan; Gu, Ning

    2010-08-01

    A basalt fiber (BF) was, for the first time, introduced into a poly(l-lactic acid) (PLLA) matrix as innovative reinforcement to fabricate composite materials for hard tissue repair. Firstly, BF/PLLA composites and pure PLLA were produced by the methods of solution blending and freeze drying. The results showed that basalt fibers can be uniformly dispersed in the PLLA matrix and significantly improve the mechanical properties and hydrophilicity of the PLLA matrix. The presence of basalt fibers may retard the polymer degradation rate and neutralize the acid degradation from PLLA. Osteoblasts were cultured in vitro to evaluate the cytocompatibility of the composite. An MTT assay revealed that osteoblasts proliferated well for 7 days and there was little difference found in their viability on both PLLA and BF/PLLA films, which was consistent with the alkaline phosphatase (ALP) activity results. A fluorescent staining observation showed that osteoblasts grew well on the composites. SEM images displayed that osteoblasts tended to grow along the fiber axis. The formation of mineralized nodules was observed on the films by Alizarin red S staining. These results suggest that the presence of basalt fibers does not noticeably affect osteoblastic behavior and the designed composites are osteoblast compatible. It is concluded that basalt fibers, as reinforcing fibers, may have promising applications in hard tissue repair.

  8. The Composition of the Fluids in Alkali Basalts and Mantle-Derived Xenoliths in Eastern China

    Institute of Scientific and Technical Information of China (English)

    ZHANG Minjie; WANG Xianbin; LIU Gang; LI Liwu

    2001-01-01

    The components of the fluids released from alkali basalts and mantle-derived Iherzolite xenoliths in eastern China have been determined by the vacuum pyrolysis-mass spectrometric (MS) method in the present study. The results show that mantle-derived lherzolites formed in fluids composed mainly of reducing gases such as H2 and CO, and their fluid composition is characterized by a higher H2 content and a lower total content of volatiles. The fluids in alkali basalts are composed mainly of oxidizing gases, such as CO2 an SO2 and characterized by higher contents of SO2 and volatiles,implying that the extraneous oxidized fluids which are composed mainly of SO2 mixed with primary alkali basaltic magmas during their formation and evolution. The fluid compositions of alkali basalts and Iherzolite xenoliths show high nonhomogeneity in the upper mantle source region and difference in alkali basaltic magma evolution in different districts. It can be deduced that the region with higher PH2 could exist in the upper mantle beneath eastern China.

  9. Preconceptual systems and equipment for plugging of man-made accesses to a repository in basalt

    International Nuclear Information System (INIS)

    This report presents results of a study leading to preconceptual designs for plugging boreholes, shafts, and tunnels to a nuclear waste repository in basalt. Beginning design criteria include a list of preferred plug materials and plugging machines that were selected to suit the environmental conditions, and depths, diameters, and orientations of the accesses to a nuclear waste repository in the Columbia River basalts located in eastern Washington State. The environmental conditions are described. The fiscal year 1979-1980 Task II work is presented in two parts: preliminary testing of materials for plugging of man-made accesses to a repository in basalt (described in a separate report); and preconceptual systems and equipment for plugging of man-made accesses to a repository in basalt (described in this report). To fulfill the scope of the Task II work, Woodward-Clyde Consultants (WCC) was requested to: provide preconceptual systems for plugging boreholes, tunnels, and shafts in basalt; describe preconceptual borehole plugging equipment for placing the selected materials in man-made accesses; utilize the quality assurance program, program plan and schedule, and work plans previously developed for Task II; and prepare a preliminary report

  10. A deterministic methodology for prediction of fracture distribution in basaltic multiflows

    Science.gov (United States)

    Lore, Jason; Aydin, Atilla; Goodson, Kenneth

    2001-04-01

    The fracture distribution in basalt flows is a direct result of thermal processes. Thus basalt flows present a unique opportunity to characterize a nearly perfect deterministic system with its fundamental physical parameters. Fracture distribution data collected on cliff exposures of basalt flows near the Idaho National Engineering and Environmental Laboratory (INEEL) are combined with calculations of cooling rate and temperature distribution from a finite element model to construct a predictive methodology for fracture spacing. The methodology is based on an empirical power law relationship between inverse cooling rate and fracture spacing. The methodology may be applied to unexposed basalt flows of approximately elliptical cross section whose thickness and width are constrained only by geophysical or borehole data if sufficient fracture data on nearby exposed flows are available. The methodology aids waste remediation efforts at sites involving contaminant transport through fractured basalt, such as the INEEL and the Hanford site in Washington, as well as involving transport and fluid flow through volcanic or intrusive rocks where thermal processes are responsible for fracturing.

  11. Evidence for pressure-release melting beneath magmatic arcs from basalt at Galunggung, Indonesia

    Science.gov (United States)

    Sisson, T.W.; Bronto, S.

    1998-01-01

    The melting of peridotite in the mantle wedge above subduction zones is generally believed to involve hydrous fluids derived from the subducting slab. But if mantle peridotite is upwelling within the wedge, melting due to pressure release could also contribute to magma production. Here we present measurements of the volatile content of primitive magmas from Galunggung volcano in the Indonesian are which indicate that these magmas were derived from the pressure-release melting of hot mantle peridotite. The samples that we have analysed consist of mafic glass inclusions in high-magnesium basalts. The inclusions contain uniformly low H2O concentrations (0.21-0.38 wt%), yet relatively high levels of CO2 (up to 750 p.p.m.) indicating that the low H2O concentrations are primary and not due to degassing of the magma. Results from previous anhydrous melting experiments on a chemically similar Aleutian basalts indicate that the Galunggung high-magnesium basalts were last in equilibrium with peridotite at ~1,320 ??C and 1.2 GPa. These high temperatures at shallow sub-crustal levels (about 300-600 ??C hotter than predicted by geodynamic models), combined with the production of nearly H2O- free basaltic melts, provide strong evidence that pressure-release melting due to upwelling in the sub-are mantle has taken place. Regional low- potassium and low-H2O (ref. 5) basalts found in the Cascade are indicate that such upwelling-induced melting can be widespread.

  12. Preconceptual systems and equipment for plugging of man-made accesses to a repository in basalt

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, C.L.; O' Rourke, J.E.; Allirot, D.; O' Connor, K.

    1980-09-01

    This report presents results of a study leading to preconceptual designs for plugging boreholes, shafts, and tunnels to a nuclear waste repository in basalt. Beginning design criteria include a list of preferred plug materials and plugging machines that were selected to suit the environmental conditions, and depths, diameters, and orientations of the accesses to a nuclear waste repository in the Columbia River basalts located in eastern Washington State. The environmental conditions are described. The fiscal year 1979-1980 Task II work is presented in two parts: preliminary testing of materials for plugging of man-made accesses to a repository in basalt (described in a separate report); and preconceptual systems and equipment for plugging of man-made accesses to a repository in basalt (described in this report). To fulfill the scope of the Task II work, Woodward-Clyde Consultants (WCC) was requested to: provide preconceptual systems for plugging boreholes, tunnels, and shafts in basalt; describe preconceptual borehole plugging equipment for placing the selected materials in man-made accesses; utilize the quality assurance program, program plan and schedule, and work plans previously developed for Task II; and prepare a preliminary report.

  13. Source, evolution and emplacement of Permian Tarim Basalts: Evidence from U-Pb dating, Sr-Nd-Pb-Hf isotope systematics and whole rock geochemistry of basalts from the Keping area, Xinjiang Uygur Autonomous region, northwest China

    Science.gov (United States)

    Zhang, Dayu; Zhou, Taofa; Yuan, Feng; Jowitt, Simon M.; Fan, Yu; Liu, Shuai

    2012-04-01

    Permian basalts distribute at least 250,000 km2, and underlie the southwest Tarim Basin in Xinjiang Uygur Autonomous region, northwest China. This vast accumulation of basalt is the main part of the Tarim Large Igneous Province (LIP). The basaltic units in the Lower Permian Kupukuziman and Kaipaizileike Formations in the Keping area, Tarim Basin; were the best exposure of the Permian basalt sequence in the basin. LA-ICP-MS U-Pb dating of zircon from the basal basaltic unit in the section gives an age of 291.9 ± 2.2 Ma (MSWD = 0.30, n = 17); this age, combined with previously published geochronological data, indicates that the basalts in the Tarim Basin were emplaced between 292 Ma and 272 Ma, with about 90% of the basalts being emplaced between 292 and 287 Ma. Basalts from the Keping area have high FeOT (10.8-18.6 wt.%), low Mg#s (0.26-0.60), and exhibit primitive mantle normalized patterns with positive Pb, P and Ti but negative Zr, Y and Ta anomalies. The basalts from both formations have similar 206Pb/204Pb (18.192-18.934), 207Pb/204Pb (15.555-15.598) and 208Pb/204Pb (38.643-38.793) ratios. The basalts also have high ɛSr(t) (45.7-62.1), low ɛNd(t) (-3.6 to -2.2) and low zircon ɛHf(t) (-4.84 to -0.65) values. These characteristics are typical of alkali basalts and suggest that the basalts within the Tarim Basin were derived from an OIB-type mantle source and interacted with enriched mantle (EMI-type) before emplacement. Rare earth element systematics indicate that the parental melts for the basalts were high-degree partial melts derived from garnet lherzolite mantle at the base of the lithosphere. Prior to emplacement, the Tarim Permian Basalts (TPB) underwent fractional crystallization and assimilated crustal material; the basalts were finally emplaced during crustal extension in an intra-plate setting. The wide distribution, deep source and high degree partial melting of the TPB was consistent with a mantle plume origin. The TPB and other coeval igneous

  14. Strategy for determination of geochemical reactivity in the Hanford basalts, southeastern Washington

    International Nuclear Information System (INIS)

    The geochemical reactivity of radionuclides or their analogues will be determined in basalt groundwater systems at the Hanford Site to assess its suitability for permanent disposal of high level radioactive waste. A combination of field and laboratory experiments are being designed to determine radionuclide sorption, kinetics of redox reactions, and retardation factors in basalt from a repository. Field testing requires that both single and paired borehole reactive tracer tests be carried out in basalt flow tops at a depth of about 1,000 meters. Special precautions are required to prevent atmospheric contamination of the borehole fluids which could affect the validity of results. Laboratory batch and column sorption testing on core materials collected before and after field tracer testing will be conducted to determine scale factors between laboratory and field sorption data obtained for a variety of key radionuclides

  15. Preliminary K/Ar geochronology of the Crater Basalt volcanic field (CBVF, northern Patagonia

    Directory of Open Access Journals (Sweden)

    Z. Pécskay

    2007-03-01

    Full Text Available The Crater Basalt volcanic field is one of the Quaternary intraplate basaltic fields in northern Patagonia. A systematic geological, volcanological and geochronological study of CBVF indicates a multistage history of eruptions of basaltic volcanoes. K/Ar dating, using whole rock samples shows that the measured analytical ages are fully consistent with the available stratigraphic control. The radiometric ages fall into three distinct, internally consistent age groups, which give evidence that there were at least three major episodes of volcanic activity, at about 1.0 Ma, 0.6 Ma and 0.3 Ma ago. The age differences appear to be just significant, even although less than 10 % radiogenic argon was found in the isotope analysis of whole rock samples.

  16. Two—Dimensional Mathematical Model and Numerical Simulation Describing the Melting Process of Cylindrical Basalt Bed

    Institute of Scientific and Technical Information of China (English)

    YanQuanying; ShangDeku; 等

    1999-01-01

    A two-dimensional mathematical model was built to describe the melting process of cylindrical basalt particle bed in a crucible.The melting processes with respect to the factors of thermal boundary conditions and particle sizes of basalt were simulated by using the numerical method (FDM).The governing equations were discretized in tridiagonal matrix form and were solved by using the tridiagonal matrix algorithm (TDMA) as well as the alternative direction implicit(ADI) solver.The temperature distribution,the moving law of the two dimensional phase-change boundaries the thermal current distribution were given through the numerical simulation.The results provided a theoretical basis for deciding heating procedure,for evaluating power import and controlling furnace temperature and for predicting basalt melting states etc.In the experiment,an electrical furnace was designed based on the computations.It has been proved that the simulation results are reasonably coincident with the experimental data.

  17. Bimodal basalt-rhyolite magmatism in the central and western Snake River Plain, Idaho and Oregon

    Science.gov (United States)

    McCurry, M.; Bonnichsen, B.; White, C.; Godchaux, M.M.; Hughes, S.S.

    1997-01-01

    The purpose of this trip is to examine Miocene to Pleistocene basalt and rhyolite flows, ignimbrites and hypabyssal intrusions in a transect from the western Snake River Plain graben across the older part of the Snake River Plain "hot-spot-track." The earlier, dominantly explosive rhyolitic phase of volcanism will be examined primarily in the Cassia Mountains, near Twin Falls, Idaho. The second day of the field trip will focus on the Graveyard Point intrusion, a strongly differentiated diabase sill in easternmost Oregon. This late Tertiary sill is well exposed from floor to roof in sections up to 150 m thick, and is an example of the type of solidified shallow magma chamber that may be present beneath some Snake River Plain basalt volcanoes. The field trip will conclude with an examination of the diverse styles of effusive and explosive basaltic volcanism in the central and western Snake River Plain.

  18. The petrology and chemistry of basaltic fragments from the Apollo 11 soil - I

    Science.gov (United States)

    Beaty, D. W.; Hill, S. M. R.; Albee, A. L.; Ma, M.-S.; Schmitt, R. A.

    1979-01-01

    A study of basaltic fragments from the Apollo 11 bulk sample using instrumental neutron activation analysis, the petrographic microscope, and the electron microprobe is presented. The fragments include Group A, B2, and B3 basalts, of which two of the Group A samples are vitrophyres with bulk compositions similar to the crystalline high-K rocks which crystallized under different physical conditions and represent a second high-K cooling unit. The B2 samples relate to each other through ilmenite fractionation, and the B3 samples relate through olivine fractionation; it is concluded that the B2 samples have an anomalously high La/K ratio and may have generated in the same source region as the Group D basalts.

  19. Modeling of the Sedimentary Interbedded Basalt Stratigraphy for the Idaho National Laboratory Probabilistic Seismic Hazard Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Suzette Payne

    2007-08-01

    This report summarizes how the effects of the sedimentary interbedded basalt stratigraphy were modeled in the probabilistic seismic hazard analysis (PSHA) of the Idaho National Laboratory (INL). Drill holes indicate the bedrock beneath INL facilities is composed of about 1.1 km of alternating layers of basalt rock and loosely consolidated sediments. Alternating layers of hard rock and “soft” loose sediments tend to attenuate seismic energy greater than uniform rock due to scattering and damping. The INL PSHA incorporated the effects of the sedimentary interbedded basalt stratigraphy by developing site-specific shear (S) wave velocity profiles. The profiles were used in the PSHA to model the near-surface site response by developing site-specific stochastic attenuation relationships.

  20. Modeling of the Sedimentary Interbedded Basalt Stratigraphy for the Idaho National Laboratory Probabilistic Seismic Hazard Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Suzette Payne

    2006-04-01

    This report summarizes how the effects of the sedimentary interbedded basalt stratigraphy were modeled in the probabilistic seismic hazard analysis (PSHA) of the Idaho National Laboratory (INL). Drill holes indicate the bedrock beneath INL facilities is composed of about 1.1 km of alternating layers of basalt rock and loosely consolidated sediments. Alternating layers of hard rock and “soft” loose sediments tend to attenuate seismic energy greater than uniform rock due to scattering and damping. The INL PSHA incorporated the effects of the sedimentary interbedded basalt stratigraphy by developing site-specific shear (S) wave velocity profiles. The profiles were used in the PSHA to model the near-surface site response by developing site-specific stochastic attenuation relationships.

  1. Thermal control of low-pressure fractionation processes. [in basaltic magma solidification

    Science.gov (United States)

    Usselman, T. M.; Hodge, D. S.

    1978-01-01

    Thermal models detailing the solidification paths for shallow basaltic magma chambers (both open and closed systems) were calculated using finite-difference techniques. The total solidification time for closed chambers are comparable to previously published calculations; however, the temperature-time paths are not. These paths are dependent on the phase relations and the crystallinity of the system, because both affect the manner in which the latent heat of crystallization is distributed. In open systems, where a chamber would be periodically replenished with additional parental liquid, calculations indicate that the possibility is strong that a steady-state temperature interval is achieved near a major phase boundary. In these cases it is straightforward to analyze fractionation models of the basaltic liquid evolution and their corresponding cumulate sequences. This steady thermal fractionating state can be invoked to explain large amounts of erupted basalts of similar composition over long time periods from the same volcanic center and some rhythmically layered basic cumulate sequences.

  2. The Bowen-Fenner Debate Revisited: A Review of Basalt Crystal Fractionation and the Generation of Andesite

    Science.gov (United States)

    Conrey, R. M.

    2002-12-01

    The Bowen-Fenner debate over the nature of basalt crystal fractionation is still unresolved. Bowen's classic 1928 book detailed his basalt-andesite-rhyolite fractionation scheme, whereas Fenner emphasized the evidence for Fe-enrichment during most basalt crystallization, thus anticipating discovery of the Skaergaard. In the 1940's Bowen suggested only wet basalt generates common andesite. To address this debate MELTS simulations were performed with near-constant parents but varied water contents from 0-4 wt per cent. For comparison, data were compiled from mid-ocean ridge (MORB), back-arc basin (BABB), and arc basalts. There is a strong correlation between empirical fractionation patterns and the simulations. Dry basaltic magma exemplified by MORB shows fractionation patterns controlled by early plagioclase crystallization, whereas nearly all wet arc basaltic magmas have patterns controlled by crystallization of mafic minerals, with the later onset of highly calcic plagioclase. BABB have fractionation patterns between those two extremes. The fundamental antithetic behavior of Al and Fe during basalt crystal fractionation due to the sensitive control over plagioclase crystallization by water is completely obscured by the use of Harker and AFM diagrams. Mafic arc basalts which show evidence for significant crystallization of magnetite are largely lacking - most arc basalt fractionation patterns are consistent with 2-3 per cent H2O in the primitive melt and oxygen fugacity near the NNO buffer. A few mafic arc volcanoes have steep increases in Al content or slightly declining Fe content with only slight increases in FeO*/MgO suggestive of significant magnetite crystallization. Magma at these centers must be somewhat more hydrous and/or oxidized than is the normal case. Arc basalt clinopyroxene compositions support the inference that common high-alumina basalt (HAB) is a derivative magma, as empirical and experimental data, and MELTS simulations, all show coupled

  3. Hydrochemistry and hydrogeologic conditions within the Hanford Site upper basalt confined aquifer system

    International Nuclear Information System (INIS)

    As part of the Hanford Site Ground-Water Surveillance Project, Flow System Characterization Task. Pacific Northwest Laboratory examines the potential for offsite migration of contamination within the upper basalt confined aquifer system for the US Department of Energy (DOE). As part of this activity, groundwater samples were collected over the past 2 years from selected wells completed in the upper Saddle Mountains Basalt. The hydrochemical and isotopic information obtained from these groundwater samples provides hydrologic information concerning the aquifer-flow system. Ideally, when combined with other hydrologic property information, hydrochemical and isotopic data can be used to evaluate the origin and source of groundwater, areal groundwater-flow patterns, residence and groundwater travel time, rock/groundwater reactions, and aquifer intercommunication for the upper basalt confined aquifer system. This report presents the first comprehensive Hanford Site-wide summary of hydrochemical properties for the upper basalt confined aquifer system. This report provides the hydrogeologic characteristics (Section 2.0) and hydrochemical properties (Section 3.0) for groundwater within this system. A detailed description of the range of the identified hydrochemical parameter subgroups for groundwater in the upper basalt confined aquifer system is also presented in Section 3.0. Evidence that is indicative of aquifer contamination/aquifer intercommunication and an assessment of the potential for offsite migration of contaminants in groundwater within the upper basalt aquifer is provided in Section 4.0. The references cited throughout the report are given in Section 5.0. Tables that summarize groundwater sample analysis results for individual test interval/well sites are included in the Appendix

  4. [Dynamic studies of the leukocyte phagocytic activity after exposure of rats to asbestos and basalt fibers].

    Science.gov (United States)

    Hurbánková, M

    1993-05-01

    The paper presents the results of the dynamic one-year follow-up of the phagocytic activity of Wistar-rats peripheral blood leukocytes following intraperitoneal administration of asbestos and basalt fibres (Man-Made Mineral Fibres--MMMF). We investigated the phagocytic activity of leukocytes in peripheral blood following intraperitoneal administration of asbestos and basalt fibres to rats 2, 24, 48 h as well as 1, 2, 4, 8 weeks and 6 and 12 months after dosing. We investigated the time dependent of the changes of relative granulocytes count, percentage of phagocytizing cells from leukocytes, percentage of phagocytizing granulocytes and percentage of phagocytizing monocytes. The results of our experiment showed that asbestos and basalt fibres differed in their effects on the parameters studied. Granulocyte count as well as the phagocytic activity of leukocytes during the one-year dynamic follow-up in both dust--exposed groups of animals were found to change in two phases, characterised by the initial stimulation of the acute phase (I), followed by the suppression of the parameters in the chronic phase (II). Exposure to asbestos and basalt fibres led, in phase II, to impairment of the phagocytic activity of granulocytes. Asbestos fibres at the same time significantly decreased also the phagocytic activity of monocytes. Exposure to basalt fibres did not affect the phagocytic activity of monocytes in phase II. It follows from the results of the experiment, that the monocytic component of leukocytes probably plays an important role in the development of diseases caused by exposure to fibrous dusts and basalt fibres have smaller biological effects compared with asbestos fibres.

  5. High-level waste-basalt interactions. Annual progress report, February 1, 1977--September 30, 1977

    International Nuclear Information System (INIS)

    Commercial radioactive waste can be placed under ground in a basalt repository to contain significant amounts of radioactive decay heat for the first hundred or so years, which constitutes the ''thermal period'' of waste isolation, if the feasibility is determined that a basalt geology is a suitable medium for storage of radioactive wastes. Several physical-chemical changes analogous to natural geochemical processes can occur in and around this repository during the thermal period. The waste canister can act as a heat source and cause changes in the mineralogy and properties of the surrounding basalts. Geochemically, this is ''contact metamorphism.'' This phenomenon needs to be investigated because it could affect the behavior of the basalt with regard to migration of long-lived radionuclides away from the immediate repository. It is well known that even the relatively low-grade hydrothermal conditions possible in the repository (temperatures up to 400 degrees Centigrade; pressures up to 300 bars) can cause extensive modifications in rocks and minerals. At the end of the thermal period, the residue of the original waste plus the waste-basalt interaction products would constitute the actual waste form (or ''source term'') subject to the low-temperature leaching and migration processes under investigation in other laboratories. During the last eight months of fiscal year 1977, a program was initiated at The Pennsylvania State University which had as its objective the determination of the nature and implication of any chemical or mineralogical changes in, or interactions between, each candidate radioactive waste form and representative Columbia River Basalt under the various relevant repository conditions during the thermal period. Results of these investigations are given

  6. Bacterial Diversity of Young Seafloor Basalts: A Potential Role for Microorganisms in Ocean Crust Weathering

    Science.gov (United States)

    Santelli, C. M.; Edgcomb, V.; Bach, W.; Edwards, K.

    2005-12-01

    A growing number of studies indicate that microbial communities exist within the oceanic crust on mid-ocean ridge flanks. Young ocean crust that is exposed at the seafloor or in the shallow subseafloor interacts directly with low-temperature, oxygenated fluids and undergoes alteration. The free energy associated with oxidation of reduced species in the basalt could potentially be used by microbial communities for growth. Basaltic rock habitats at and below the seafloor, however, remain poorly studied with respect to the physiological and phylogenetic diversity of microbial communities that may be supported by oxidative weathering reactions. In this study, we have investigated the diversity of microorganisms living on or within basaltic crust at the seafloor, and the changes in these microbial communities with increasing oxidative rock alteration. Seafloor lavas representing various flow morphologies, alteration states, and ages (up to 20 kyrs) were collected from the East Pacific Rise between 9°28'N and 9°50'N. Total community DNA was extracted and bacterial 16S rRNA was amplified by PCR. Clone libraries were constructed and sequenced for phylogenetic analyses. To assess the overall extent of basalt alteration and quantify cell abundance in relation to surfacial weathering products, a combination of confocal laser scanning microscopy and scanning electron microscopy was used on natural, unprocessed samples. Phylogenetic and microscopic analyses indicate that diverse, yet distinct populations of bacteria inhabit different lavas, and these microbial communities shift with changes in basalt alteration state. A general trend from metal and sulfur-oxidizing autotrophic communities towards metal- and sulfur-reducing populations correlates with apparent increasing accumulation of weathering products (oxides, clays, etc.). These results provide insight into phylogenetic population trends among bacterial communities harbored in basalt during ocean crust weathering.

  7. Olivine Major and Trace Element Compositions in Southern Payenia Basalts, Argentina

    DEFF Research Database (Denmark)

    Søager, Nina; Portnyagin, Maxim; Hoernle, Kaj;

    2015-01-01

    Olivine major and trace element compositions from 12 basalts from the southern Payenia volcanic province in Argentina have been analyzed by electron microprobe and laser ablation inductively coupled plasma mass spectrometry. The olivines have high Fe/Mn and low Ca/Fe and many fall at the end...... by subduction-zone fluids and/or melts. The increasing contributions from the pyroxene-rich source in the southern Payenia basalts are correlated with an increasing Fe-enrichment, which caused the olivines to have lower forsterite contents at a given Ni content. Al-in-olivine crystallization temperatures...

  8. Evidence for a basalt-free surface on Mercury and implications for internal heat.

    Science.gov (United States)

    Jeanloz, R; Mitchell, D L; Sprague, A L; de Pater, I

    1995-06-01

    Microwave and mid-infrared observations reveal that Mercury's surface contains less FeO + TiO2 and at least as much feldspar as the lunar highlands. The results are compatible with the high albedo (brightness) of Mercury's surface at visible wavelengths in suggesting a rock and soil composition that is devoid of basalt, the primary differentiate of terrestrial mantles. The occurrence of a basalt-free, highly differentiated crust is in accord with recent models of the planet's thermal evolution and suggests that Mercury has retained a hot interior as a result of a combination of inefficient mantle convection and minimal volcanic heat loss.

  9. Strengthening of reinforced concrete beams with basalt-based FRP sheets: An analytical assessment

    Science.gov (United States)

    Nerilli, Francesca; Vairo, Giuseppe

    2016-06-01

    In this paper the effectiveness of the flexural strengthening of RC beams through basalt fiber-reinforced sheets is investigated. The non-linear flexural response of RC beams strengthened with FRP composites applied at the traction side is described via an analytical formulation. Validation results and some comparative analyses confirm soundness and consistency of the proposed approach, and highlight the good mechanical performances (in terms of strength and ductility enhancement of the beam) produced by basalt-based reinforcements in comparison with traditional glass or carbon FRPs.

  10. Extreme magnesium isotope fractionation during bauxite formation on the Columbia River Basalts

    Science.gov (United States)

    Liu, X.; Teng, F.; Rudnick, R. L.; McDonough, W. F.; Cummings, M. L.

    2012-12-01

    The behavior of magnesium isotopes during intense weathering of continental basalt is investigated by analyses of two ~10 m deep drill cores through bauxite developed on Columbia River Basalts (CRBs) in western Oregon and Washington, United States. XRD analyses reveal that these cores consist of gibbsite, hematite, +/- halloysite, kaolinite, goethite and maghemite; quartz, which is not present in fresh basalt, occurs only at the top of the cores and its abundance decreases progressively with depth; no quartz is observed below 5 m depth in either core. Both profiles display strong Mg depletion (up to 99%) relative to fresh basalt and one profile shows re-enrichment of Mg near the surface. δ26Mg values in bauxites are extremely high (up to +1.7) relative to the fresh basalts, which have mantle-like δ26Mg of -0.24 ± 0.07. The Mg isotopic fractionation in these bauxites is unlikely to be caused by kinetic fractionation via chemical diffusion (as suggested for lithium isotopes for a different weathering profile by Teng et al. (1)) because Richter et al. (2) found no measureable Mg isotopic fractionation associated with Mg diffusion in water. Moreover, due to the intense weathering, Mg isotopic fractionation in these drill cores should not be influenced by dissolution of basalts. Therefore, it is likely that the observed extreme Mg isotopic fractionation is associated with secondary mineral formation. However, δ26Mg tends to lower values towards the surface in both cores, opposite the trend that is expected to be produced by progressive leaching of the basalt accompanied by secondary mineral formation. Both the presence of quartz and less radiogenic Nd isotopic compositions at the tops of the profiles suggest that eolian material has been added to the top few meters of these weathering profiles, causing the Mg isotopic composition to be lighter at the surface. Moreover, both Mg concentration and δ26Mg in bauxites influenced by eolian addition show correlations with

  11. Review of the upper Cenozoic stratigraphy overlying the Columbia River Basalt Group in western Idaho

    International Nuclear Information System (INIS)

    This report is a synthesis of information currently available on the rocks that stratigraphically overlie the Columbia River Basalt Group in Idaho. The primary objective is to furnish a brief but comprehensive review of the literature available on upper Cenozoic rocks in western Idaho and to discuss their general stratigraphic relationships. This study also reviews the derivation of the present stratigraphy and notes weaknesses in our present understanding of the geology and the stratigraphy. This report was prepared in support of a study to evaluate the feasibility of nuclear waste storage in the Columbia River Basalt Group of the Pasco Basin, Washington

  12. Microbial communities in recent and 10 - 28 Ma ocean floor basalt (ODP Leg 187)

    Science.gov (United States)

    Lysnes, K.; Steinsbu, B. O.; Einen, J.; Thorseth, I. H.; Pedersen, R. B.; Torsvik, T.

    2003-04-01

    Previous studies have shown that microbial communities are harboring ocean crust basalt (e.g., Thorseth et al. 1995). The non-hydrothermal regions of ocean ridges are largely unstudied with respect to microbial diversity and physiology. In the present study, the microbial communities resident in samples of recent (microbial diversity and to compare the endolithic microbial communities in seafloor samples (Arctic Ridges) with subsurface samples (ODP Leg 187) by molecular biology techniques. To monitor possible contamination samples of sediment and seawater, treated in the same manner as the basalt samples, served as controls. Polymerase chain reaction -- denaturing gradient gel electrophoresis (PCR -- DGGE) were used to amplify fragments of 16S rRNA genes and to separate individual DNA sequences, corresponding to different species and strains of Bacteria and Archaea in the samples. Relative similarity indices were calculated from DGGE banding patterns using Jaccard's algorithm, and species richness was estimated using Shannon's index. Furthermore, individual DNA bands were excised from the gel and sequenced to evaluate the phylogenetic affiliation of the endolithic microbes. Shannon indices show that the species richness of microbial communities in basalt is higher for seafloor samples (Arctic Ridges) than for subsurface samples (Southeast Indian Ridge). The microbial population in the Arctic Ridge basalt samples affiliates with ten major lineages of the domain Bacteria and 1 major lineage of Archaea. Bacteria in the ODP Leg 187 basalt samples affiliate with six major lineages of the domain Bacteria, whereas no archaeal sequences were retrieved from these samples. Many sequences from both areas appear to be unaffiliated with any previously isolated microbes. The uncultured green nonsulfur bacterium Chloroflexales Arctic 96BD-6, and the three gamma proteobacteria Acinetobacter junii, Pseudoalteromonas sp., and Shewanella frigidimarina affiliate with sequences from

  13. Hydrologic bibliography of the Columbia River basalts in Washington with selected annotations

    International Nuclear Information System (INIS)

    The objective of this compilation is to present a comprehensive listing of the published, unpublished, and open file references pertaining to the surface and subsurface hydrology of the Columbia River basalts within the State of Washington and is presented in support of Rockwell's hydrologic data compilation effort for the Basalt Waste Isolation Program. A comprehensive, annotated bibliography of the Pasco Basin (including the Hanford Site) hydrology has been prepared for Rockwell as part of the Pasco Basin hydrology studies. In order to avoid unnecessary duplication, no effort was made to include a complete list of bibliographic references on Hanford in this volume

  14. Age discrimination among basalt flows using digitally enhanced LANDSAT imagery. [Saudi Arabia

    Science.gov (United States)

    Blodget, H. W.; Brown, G. F.

    1984-01-01

    Digitally enhanced LANDSAT MSS data were used to discriminate among basalt flows of historical to Tertiary age, at a test site in Northwestern Saudi Arabia. Spectral signatures compared favorably with a field-defined classification that permits discrimination among five groups of basalt flows on the basis of geomorphic criteria. Characteristics that contributed to age definition include: surface texture, weathering, color, drainage evolution, and khabrah development. The inherent gradation in the evolution of geomorphic parameters, however, makes visual extrapolation between areas subjective. Therefore, incorporation of spectrally-derived volcanic units into the mapping process should produce more quantitatively consistent age groupings.

  15. Sr Isotopic Evidence on the Spilitic Degradation of the Deccan Basalt

    Indian Academy of Sciences (India)

    K V Subbarao

    2000-03-01

    Similar Sr isotopic ratios (∼0.7055) for the tholeiite-spilite flow unit and the associated mineral phases, of Bombay (Deccan Traps) provide a direct evidence for the spilitic degradation of tholeiite. In contrast, a dramatic increase in the rare earth elements (REE) from basalt to spilite is rather puzzling as rare earths are considered to be relatively immobile. The geochemistry thus suggests that the process of spilitization is due to the reaction with a complex fluid having identical Sr-isotopic composition as that of the basaltic magma - thereby masking the details of the mixing process.

  16. Origin of arc-like continental basalts: Implications for deep-Earth fluid cycling and tectonic discrimination

    Science.gov (United States)

    Wang, Xuan-Ce; Wilde, Simon A.; Xu, Bei; Pang, Chong-Jin

    2016-09-01

    Continental basalts generally display enrichment of fluid-mobile elements and depletion of high-field-strength elements, similar to those that evolved in the subduction environment, but different from oceanic basalts. Based on the continental flood basalt database for six large igneous provinces, together with rift-related basalt data from the Basin and Range Province, this study aimed to test the validity of geochemical tectonic discrimination diagrams in distinguishing arc-like intra-continental basalts from arc basalts and to further investigate the role of deep-Earth water cycling in producing arc-like signatures in large-scale intra-continental basalts. Our evaluation shows that arc-like intra-continental basalts can be distinguished from arc basalts by integrating the following factors: (1) the FeO, MgO, and Al2O3 concentrations of the primary melt; (2) Tisbnd V, Zrsbnd Zr/Y, Zrsbnd Ti, and Ti/Vsbnd Zr/Smsbnd Sr/Nd discrimination diagrams; (3) the coexistence of arc-like and OIB-like subtype basalts within the same province; (4) primitive mantle-normalized trace element distribution patterns. The similarity of enrichment in fluid-mobile elements (Ba, Rb, Sr, U, and K) between arc-like and true arc basalts suggests the importance of water flux melting in producing arc-like signatures in continental basalts. Experimentally determined liquid lines of descent (LLD) imply high magma water concentrations for continental flood basalts (CFBs) and the Basin and Range basalts. Furthermore, estimates based on the Al2O3-LLD method indicates 4.0-5.0 wt% pre-eruptive magma H2O concentration for CFBs and the Basin and Range basalts. The tight relationships between H2O/Ce and Ba/La, Ba/Nb and Rb/Nb based on global arc basalt data were further used to estimate the primary H2O concentrations. With the exception of the Emeishan CFBs (mainly containing 4.0-5.6 wt% H2O), all other CFBs investigated have similar estimated primary H2O contents, with values ranging from 1.0 to 2

  17. Local Environmental Effects from Deposition of Basaltic Tephra

    Science.gov (United States)

    Ort, M. H.; Sheppard, P. R.; Anderson, K. C.; Elson, M. D.

    2012-12-01

    Basaltic tephra is produced by scoria cones and by composite and stratovolcanoes, which may cover 1000s-10,000's km2 with tephra to depths greater than 1 cm. This tephra changes the abiotic and biotic environment. The thickness of the tephra affects whether plants can send their seeds and roots to the soil underneath or grow through the tephra to reach the surface. More than 20 cm of tephra greatly inhibits most plant growth, as shown by agricultural experiments and observations of natural landscapes. At Sunset Crater in northern Arizona, incipient soil formation (after ~925 years) consists of eolian grains having sifted down to a depth of 10-20 cm, forming a finer grained layer that retains water. Plant roots concentrate at this level, helping to trap more fine grains and adding organic material to the layer. This then provides a more hospitable environment for further plant growth and the development of soil ecosystems. Fresh tephra, especially if coarse, allows water to pass through it to the underlying soil, reducing runoff, and slows subsequent evaporation. At Sunset Crater, increased water infiltration led to better plant growth in semiarid grasslands and forest and possibly to new springs and increased surface water. At Parícutin in Michoacán, México, flooding caused by abundant rain that saturated the tephra led to stream shifts and erosion. Tephra has available ions on the surface of grains and the volcanic glass may be easily altered. This, combined with increased water retention in the soil, can lead to changes in soil and groundwater chemistry underlying the tephra. Adhering sulfur, as well as HCl- and HNO3-rich rainfall, can lower pH in the water, dissolving soil ions as mineralogical phase changes occur in response to the lower pH. At three scoria cones (Sunset Crater, Paricutin, and Cinder Cone, which is in northeast California), tree-ring chemistry reflects changes in the soil-water composition. P and S increase for a few years to decades after

  18. Thermobarometry for spinel lherzolite xenoliths in alkali basalts

    Science.gov (United States)

    Ozawa, Kazuhito; Youbi, Nasrrddine; Boumehdi, Moulay Ahmed; Nagahara, Hiroko

    2016-04-01

    geothermobarometry based on reactions with large and distinct volume changes, is necessary. Specification of mineral domains and their components representing the thermal state of the mantle just before xenolith extraction is one of the major tasks for the establishment of reliable geothermobarometry for spinel lherzolite xenoliths. Systematic variations of such mineralogical information among xenoliths transported by a single volcanic eruption guarantees proper estimation of a mantle geotherm. For the development of such geobarometry, it is important to choose appropriate xenolith locality, where previous studies provide enough information and where many xenolith samples are available for extending a range of derivation depth. Spinel lherzolite xenoliths in alkali basalts from Bou Ibalhatene maars in the Middle Atlas in Morocco are suitable study target. Geochemical, geochronological, petrological, and rheological aspects of the spinel lherzolite xenoliths have been studied (Raffone et al. 2009; El Messbahi et al., 2015; Witting et al., 2010; El Azzouzi et al., 2010), which show that they represent fragments of the lithospheric mantle formed and modified since 1.7Ga before their extraction from Miocene to recent. We have pinpointed portions of minerals in the xenolith samples and their components representing condition just before their entrapment in magmas, on which appropriate geothermobarometers are applied and detected ~0.5GPa pressure difference (1.5-2.0GPa) for ~100°C variation in temperatures (950-1050°C).

  19. Geochemistry of Paraná-Etendeka basalts from Misiones, Argentina: Some new insights into the petrogenesis of high-Ti continental flood basalts

    Science.gov (United States)

    Rämö, O. Tapani; Heikkilä, Pasi A.; Pulkkinen, Arto H.

    2016-04-01

    The Early Cretaceous (˜135-131 Ma) Paraná-Etendeka continental flood basalts, preserved in bulk in the Paraná basin of southern Brazil and vicinity, have been divided into low-Ti and high-Ti types that govern the southern and northern halves of the basin, respectively. We have examined a new sample set from the southern margin of the northern high-Ti segment of Paraná basalts in Misiones, northeastern Argentina. These basalts are strongly to moderately enriched in TiO2 (2-4 wt.%), have relatively high Ti/Y (300-500), low MgO (3.5-6.5 wt.%), and high Fe (FeO(tot) 12-14 wt.%) and belong to the Pitanga and Paranapanema magma types of Peate et al. (1992). Nd and Sr isotope compositions are quite unvarying with ɛNd (at 133 Ma) values of -4.6 to -3.6 and initial 87Sr/86Sr of 0.7054-0.7059 and show no variation with fractionation. Compared to high-Ti lavas in the central and northern parts of the Paraná high-Ti basalt segment, the lavas from Misiones are similar to those in the northeastern magin of the basin but less radiogenic in initial Nd isotope composition than those in the central part. This variation probably reflects mixed EM1-EM2 source components in the sublithospheric mantle. A polybaric melt model of a sublithospheric mantle source at the garnet lherzolite-spinel lherzolite transition is compatible with the observed Ti budget of the Pitanga and Paranapanema lavas, regardless of the Nd isotope composition of their purported source.

  20. Chromium Oxidation State in Planetary Basalts: Oxygen Fugacity Indicator and Critical Variable for Cr-Spinel Stability

    Science.gov (United States)

    Bell, A. S.; Burger, P. V.; Le, Loan; Papike, J. J.; Jone, J.; Shearer, C. K.

    2014-01-01

    Cr is a ubiquitous and relatively abundant minor element in basaltic, planetary magmas. At the reduced oxidation states (Cr2+. We have applied these results to modeling Cr spinel stability and Cr redox ratios in a primitive, iron-rich martian basalt.

  1. Geochemistry and stratigraphic correlation of basalt lavas beneath the Idaho Chemical Processing Plant, Idaho National Engineering Laboratory

    Science.gov (United States)

    Reed, M.F.; Bartholomay, R.C.; Hughes, S.S.

    1997-01-01

    Thirty-nine samples of basaltic core were collected from wells 121 and 123, located approximately 1.8 km apart north and south of the Idaho Chemical Processing Plant at the Idaho National Engineering Laboratory. Samples were collected from depths ranging from 15 to 221 m below land surface for the purpose of establishing stratigraphic correlations between these two wells. Elemental analyses indicate that the basalts consist of three principal chemical types. Two of these types are each represented by a single basalt flow in each well. The third chemical type is represented by many basalt flows and includes a broad range of chemical compositions that is distinguished from the other two types. Basalt flows within the third type were identified by hierarchical K-cluster analysis of 14 representative elements: Fe, Ca, K, Na, Sc, Co, La, Ce, Sm, Eu, Yb, Hf, Ta, and Th. Cluster analyses indicate correlations of basalt flows between wells 121 and 123 at depths of approximately 38-40 m, 125-128 m, 131-137 m, 149-158 m, and 183-198 m. Probable correlations also are indicated for at least seven other depth intervals. Basalt flows in several depth intervals do not correlate on the basis of chemical compositions, thus reflecting possible flow margins in the sequence between the wells. Multi-element chemical data provide a useful method for determining stratigraphic correlations of basalt in the upper 1-2 km of the eastern Snake River Plain.

  2. Does the presence of bacteria effect basaltic glass dissolution rates? 1: Dead Pseudomonas reactants

    Science.gov (United States)

    Stockmann, Gabrielle J.; Shirokova, Liudmila S.; Pokrovsky, Oleg S.; Oelkers, Eric H.; Benezeth, Pascale

    2010-05-01

    Basaltic glass and crystalline basalt formations in Iceland have been suggested for industrial CO2 storage due to their porous and permeable properties and high reactivity. Acid CO2-saturated waters in contact with basaltic glass will lead to rapid dissolution of the glass and release of divalent cations, (Ca2+, Mg2+, Fe2+) that can react to form stable carbonates and thereby trap the CO2. However, the basalt formations in Iceland not only contains glass and mineral assemblages, but also host microbiological communities that either by their presence or by active involvement in chemical reactions could affect the amount of basaltic glass being dissolved and CO2 being trapped. Samples of natural bacteria communities from the CO2 storage grounds in Iceland were collected, separated, and purified using agar plate technique and cultured under laboratory conditions in nutrient broth-rich media. Heterotrophic aerobic Gram-negative strain of Pseudomonas reactants was selected for a series of flow-through experiments aimed at evaluation of basaltic glass dissolution rate in the presense of increasing amounts of dead bacteria and their lysis products. The experiments were carried out using mixed-flow reactors at pH 4, 6, 8 and 10 at 25 °C. Each of the four reactors contained 1 gram of basaltic glass of the size fraction 45-125 μm. This glass was dissolved in ~ 0.01 M buffer solutions (acetate, MES, bicarbonate and carbonate+bicarbonate mixture) of the desired pH. All experiments ran 2 months, keeping the flowrate and temperature stable and only changing the concentration of dead bacteria in the inlet solutions (from 0 to 430 mg/L). Experiments were performed in sterile conditions, and bacterial growth was prevented by adding NaN3 to the inlet solutions. Routine culturing of bacteria on the agar plates confirmed the sterility of experiments. Samples of outlet solutions were analyzed for major cations and trace elements by ICP-MS. Results demonstrate a slight decrease in the

  3. Characterization of lunar mare basalt types. I - A remote sensing study using reflection spectroscopy of surface soils

    Science.gov (United States)

    Pieters, C.; Mccord, T. B.

    1976-01-01

    Telescopic reflection spectra of mature mare surfaces are used to identify and characterize major basalt types on the frontside of the moon. The spectra are classified according to (1) continuum slope and (2) near-infrared features. This study indicates that there are major lunar basalt types that are unlikely to have been sampled during the landing missions. Regions of basalt exist in the western maria with a TiO2 content comparable to that of Apollo 11 but with infrared characteristics that indicate a distinctly different composition. Samples from two landing sites, Apollo 12 and Luna 16, may contain fragments of a nearby basalt unit compositionally different from the dominant basalt type of the landing area.

  4. Performance allocation traceable to regulatory criteria as applied to site characterization work at the Basalt Waste Isolation Project

    International Nuclear Information System (INIS)

    The Basalt Waste Isolation Project has developed a method for defining in detail the work required to demonstrate the feasibility of emplacing and providing for the safe isolation of nuclear wastes in a repository in the deep basalts at the Hanford Site near Richland, Washington. Criteria analysis allows the identification of areas of significant technical uncertainty or controversy that can be highlighted as issues. A preliminary analysis has been conducted, which, by identifying key radionuclides and allocating performance among the multiple barriers in a repository constructed in a basalt, allows the design and development testing activities at the Basalt Waste Isolation Project to be put into perspective. Application of sophisticated uncertainty analysis techniques will allow refinements in the analysis to be made and to further guide characterization and testing activities. Preliminary results suggest that a repository constructed in basalt will provide for the safe isolation of nuclear wastes in a cost-effective and reliable manner with a high degree of confidence

  5. Geochemical discrimination of the geotectonic environment of basaltic-andesitic volcanic rocks associated with the Laochang polymetallic ore deposit at Lancang, Yunnan

    Institute of Scientific and Technical Information of China (English)

    GAO Jianguo

    2006-01-01

    The Laochang polymetallic ore deposit at Lancang is one of the well known ancient ore deposits associated with volcanic rocks in the Sanjiang (Tri-river) region of Southwest China. Volcanic rocks are dominated by alkali basalt and trachyte basalt. There has long been a controversy on the environment of formation of basalts. Some scholars hold that the basalts were formed in a continental environment, some thought they were formed in an oceanic environment and others considered that the basalts were emplaced in a back-arc basin. This study focuses on the geochemical characteristics of the basalts on the basis of their major elements, REEs and trace elements. At the same time, strongly incompatible elements such as Ta, Th and Hf and their ratios were used to differentiate the geotectonic settings of basalts. The results showed that the basalts in the region studied were formed in a continental rift environment.

  6. A Plagioclase Ultraphyric Basalt group in the Neogene flood basalt piles of eastern Iceland: Volcanic architecture and mode of emplacement

    Science.gov (United States)

    Oskarsson, B. V.; Riishuus, M. S.

    2013-12-01

    3D photogrammetry in conjunction with ground mapping was applied in order to assess the architecture of a Plagioclase Ultraphyric Basalt (PUB) group in eastern Iceland, namely the Grænavatn group. The ~10 Myr old group is exposed in steep glacially carved fjords and can be traced over 60 km along strike. Two feeder dikes have been found and show that the group erupted along the trend of the dike swarm associated with the Breiddalur central volcano. The group has 9--14 flows where thickest, and thins to about 3--4 flows up-dip to the east within the distance of 15-20 km from the source. We have estimated the volume of the group to exceed 40 km3. The flows have mixed architecture of simple and compound morphology. The flow lobes have thicknesses from 1--24 m and many reach lengths over 1000 m. The surface morphology varies from rubbly to scoriaceous, but is dominantly of pahoehoe style. The internal structure of the lava flows is well preserved and the flows display abundant vesicle cylinders. The modal percentage of An-rich plagioclase macrocrysts varies from 25--50 % and they are in the range of 5--30 mm. The aspect ratio of the group and the nature of the flows indicate fissure-fed eruptions. A thick flow found at the base of the group in various locations seems to record the largest eruption episode in the formation of the group. This phase is also the most abundant in macrocryst. An asymmetric buildup is seen in one location and may have characterized the general buildup of the group. The general morphology of the lava flows suggests low viscous behavior, at odds with the high crystal content. Petrographic observations and mineral chemistry shows that the plagioclase macrocrysts are very calcic (An80-85) and in disequilibrium with the groundmass and plagioclases therein (An50-70). Thus the apparent lava rheology and emplacement of the PUBs was likely achieved due to fast ascent of the magma through the crust and transfer of heat from the primitive macrocrysts

  7. Late Carboniferous N-MORB-type basalts in central Inner Mongolia, China: Products of hydrous melting in an intraplate setting?

    Science.gov (United States)

    Pang, Chong-Jin; Wang, Xuan-Ce; Xu, Bei; Zhao, Jian-Xin; Feng, Yue-Xing; Wang, Yan-Yang; Luo, Zhi-Wen; Liao, Wen

    2016-09-01

    Petrogenesis of the ca. 310 Ma Benbatu basalts in central Inner Mongolia is crucial for constraining the evolution of the Xing'an Mongolia Orogenic Belt (XMOB), eastern segment of the Central Asian Orogenic Belt. The Benbatu basalts have low initial 87Sr/86Sr ratios (0.7042-0.7048), positive εNd(t) (+ 8.99 to + 9.24) and εHf(t) values (+ 15.38 to + 15.65), and are characterized by relatively flat rare earth element patterns and enrichment of Rb, U, Pb, Zr and Hf, but depletion of Nb, Ta, Sr and Ti, resembling those of the normal Mid-Ocean-Ridge Basalt (N-MORB). Variations of trace element ratios (e.g., Sm/Yb and La/Sm) suggest that the basalts were derived from spinel peridotites, with a melting depth of basalts from typical arc basalts and back arc basin basalts. The arc-like geochemical signatures (i.e., enrichment of large ion lithophile elements and depletion of Nb and Ta) are attributed to hydrated mantle source that may be caused by fluids released from stagnant oceanic slabs in the mantle transition zone. Integrating geological evidences with geochemical and isotopic features of the Benbatu basalts, we proposed that these basalts were produced under an intraplate extensional setting during the Late Carboniferous. The genesis of the Benbatu basalts therefore argues for the pre-Carboniferous accretion of the XMOB and highlights the importance of the deep-Earth recycling water in the generation of the Late Carboniferous magmatism in this region.

  8. Petrology, geochemistry, and age of low-Ti mare-basalt meteorite Northeast Africa 003-A: A possible member of the Apollo 15 mare basaltic suite

    Science.gov (United States)

    Haloda, Jakub; Týcová, Patricie; Korotev, Randy L.; Fernandes, Vera A.; Burgess, Ray; Thöni, Martin; Jelenc, Monika; Jakeš, Petr; Gabzdyl, Pavel; Košler, Jan

    2009-06-01

    Northeast Africa 003 (NEA 003) is a lunar meteorite found as a two paired stones (6 and 118 g) in Libya, 2000 and 2001. The main portion (˜75 vol%) of the 118 g meteorite, used for this study, (NEA 003-A) consists of mare-basalt and a smaller adjacent portion (˜25 vol%) is a basaltic breccia (NEA 003-B). NEA 003-A has a coarse-grained magmatic texture consisting mainly of olivine, pyroxene and plagioclase. The late-stage mineral association is composed mainly of elongated plagioclase, ilmenite, troilite, fayalite, Si-K-rich glass, apatite, and a rare SiO 2 phase. Other accessory minerals include ulvöspinel, chromite, and trace Fe-Ni metal. Olivine and pyroxene contain shock-induced fractures, and plagioclase is completely converted into maskelynite. The Fe/Mn values of the whole rock, olivines and pyroxenes, and the bulk-rock oxygen isotopic composition provide evidence for the lunar origin of NEA 003-A meteorite. This is further supported by the presence of Fe-Ni metal and the anhydrous mineral association. NEA 003-A is geochemically and petrographically distinct from previously described mare-basalt meteorites and is not paired with any of them. The petrography and major element composition of NEA 003-A is similar to the composition of low-Ti olivine mare basalts from Apollo 12 and olivine-normative basalts from Apollo 15. The NEA 003-A meteorite shows obvious geochemical similarities in trace elements contents with Apollo 15 olivine-normative basalts and could represent a yet unknown geochemically primitive member of the olivine-normative basalt series. The meteorite is depleted in rare earth elements (REE) and incompatible trace elements indicating a primitive character of the parental magma. The bulk-rock chemical composition demonstrates that the parent melt of NEA 003-A was not contaminated with KREEP components as a result of magma mixing or assimilation processes. Results of crystallization modelling and low minimum cooling rate estimates (˜0.07

  9. Pb isotope evidence for contributions from different Iceland mantle components to Palaeogene East Greenland flood basalts

    DEFF Research Database (Denmark)

    Peate, David; Stecher, Ole

    2003-01-01

    We present new Pb isotope data on 21 samples of break-up-related flood basalts (56–54 Ma) from the Blosseville Kyst region of East Greenland. These samples show a considerable range in isotopic composition (206Pb/204Pb 17.6 to 19.3) that broadly correlates with compositional type. The ‘low-Ti’ type...

  10. Early J2 basalts in SE China: Incipience of large-scale late Mesozoic magmatism

    Institute of Scientific and Technical Information of China (English)

    XIE; Xin; XU; Xisheng; ZOU; Haibo; JIANG; Shaoyong; ZHANG; Ming

    2006-01-01

    Magmatism in SE China was dormant during 204-180 Ma, but was reactivated in 180-170 Ma (early J2), and then became more and more intensive towards the end of early Cretaceous. The small-scale early J2 magmatism is the incipience to long-term and large-scale magmatism in this region. A near east-west (EW) trend volcanic belt was distributed across south Hunan, south Jiangxi and southwest Fujian was formed during early J2 time. Along this belt from the inland toward the coast, the lithology of basalts changes from alkali into tholeiite, and the amount of erupted volcanic rocks and the proportions of rhyolites coexisting with the basalts increase. On the basis of geochemical characteristics of these basalts, we infer that the melting degree of source rocks and the extent of fractional crystallization and crustal contamination all increased whereas the depth of mantle source decreased from the inland to the coast, which led to the variations of geological characteristics of the volcanic belt. In early J2, the western spreading Pacific plate began to subduct underneath SE China continental block, reactivating near EW trend deep fault that was originally formed during the Indosinian event. The stress of the western spreading Pacific plate and the extent of asthenosphere upwelling increased from the inland to the coast, which is consistent with the generation and evolution of early J2 basalts.

  11. Upper Basalt-Confined Aquifer System in the Southern Hanford Site

    International Nuclear Information System (INIS)

    The 1990 DOE Tiger Team Finding GW/CF-202 found that the hydrogeologic regime at the Hanford Site was inadequately characterized. This finding also identified the need for completing a study of the confined aquifer in the central and southern portions of the Hanford Site. The southern portion of the site is of particular interest because hydraulic-head patterns in the upper basalt-confined aquifer system indicate that groundwater from the Hanford central plateau area, where contaminants have been found in the aquifer, flows southeast toward the southern site boundary. This results in a potential for offsite migration of contaminants through the upper basalt-confined aquifer system. Based on the review presented in this report, available hydrogeologic characterization information for the upper basalt-confined aquifer system in this area is considered adequate to close the action item. Recently drilled offsite wells have provided additional information on the structure of the aquifer system in and near the southern part of the Hanford Site. Information on hydraulic properties, hydrochemistry, hydraulic heads and flow directions for the upper basalt-confined aquifer system has been re-examined and compiled in recent reports including Spane and Raymond (1993), Spane and Vermeul ( 1994), and Spane and Webber (1995)

  12. Modeled Top of the Saddle Mountains Basalt Geomodel Unit (smtop_f)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The smtop_f grid represents the modeled elevation of the top of the Saddle Mountains Basalt geomodlel unit at a 500 foot resolution. It is one grid of a geomodel...

  13. An Experimental Melting—crystallization Study on Basalt at High Pressures

    Institute of Scientific and Technical Information of China (English)

    任国浩; 谢鸿森; 等

    1991-01-01

    A series of melting-crystallization experiments on alkali basalt samples from Minqing,Fujian Prov-ince was carried out in dry and water-bearing systems at high pressures.A high-pressure melting curve was obtained.The results indicate that clinopyroxene crystallized from basalt melt at 13.5-23.7kbar,spinel at 23.7-28.6kbar and garnet at>28.6kbar.With increasing pressure,the CaSiO3 contents of clinopyroxenes increase;and the FeSiO3 decreases,but the chemical composition of garnet does not show any significant difference.The minerals are larger and euhedral in the wa-ter-bearing system.Therefore,we consider that natural megacrysts of the basalt can crystallize from the water-bearing basalt magma at high pressure.So the megacysts may be derived from the upper mantle as a result of magmatic crystallization-fractionation under high pressure.

  14. INVESTIGATION OF SOFTENING AGENT PREPARATION AND PERFORMANCE OF HANDMADE ECOCOMPOSITES WITH CONIFEROUS WOOD AND BASALT FIBERS

    Institute of Scientific and Technical Information of China (English)

    Guangjian Wang; Deku Shang; Kailiang Zhang; Linna Hu; Zhenhua Guo

    2004-01-01

    In this investigation, basalt mineral fiber softening agent was prepared in order to obtain desirable flexible performance. Stability and physical chemistry natures of softening agent were evaluated by particle size distribution, dilution, storage and folding endurance etc. Constitutes of basalt and wood fibers were determined by energy dispersion analysis X-ray which served as an accessory of scanning electron microscopy (SEM-EDAX). Naturally degradable ecocomposite was prepared by basalt and wood fibers. The results of SEM observation illustrated that the wood and basalt fibers were blended uniformly. The impact factors of beating degree, content of wood fibers and adhesive etc. were discussed. The structure of the naturally degradable ecocomposite was contrasted with that of pure wood fibers and the cause of excellent filtration performance was analyzed. Compared with traditional methods, it was of saving wood resource,a large amount of water and reducing second pollution. As a consequence, the ecocomposite harmonized with environment and accorded with requirement of benignly friendly environment.

  15. Physiological and Morphological Characteristics Among Ecotypes of Basalt Milkvetch (Astragalus Filipes)

    Science.gov (United States)

    Astragalus filipes Torr. ex A. Gray (basalt milkvetch or threadstalk milkvetch) is a legume that is widely distributed in western North America and holds promise for revegetation and restoration programs in the western U.S.A. Seed of 67 accessions was collected in 2003 from Utah, Nevada, Idaho, Ore...

  16. Mossbauer spectroscopy of magnetic minerals in basalt on Earth and Mars

    DEFF Research Database (Denmark)

    Gunnlaugsson, H. P.; Rasmussen, H.; Kristjansson, L.;

    2008-01-01

    Mossbauer spectroscopy of iron-titanium containing spinel phases is reviewed. New techniques are presented for determination of their composition using room-temperature Mossbauer spectroscopy. An example of thermal alteration processes is described. The speciality of olivine-containing basalt...

  17. Modeled Thickness of the Grande Ronde Basalt Geomodel Unit (grthk_f)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The grthk_f grid represents the modeled thickness of the Gronde Ronde Basalt geomodel unit at a 500 foot resolution. It is one grid of a geomodel that consists of...

  18. Modeled Combined Extent of All Columbia River Basalt Units (CRB_extent4xconnections)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This shapefile was created as a boundary for the Columbia River Basalt extent and a buffered version was used to clip the geomodel unit grids. As part of a U.S....

  19. STUDY ON THE BIODEGRADATION OF CELLULOSE FIBER/BASALTIC FIBER COMPOSITE PAPERBOARD

    Institute of Scientific and Technical Information of China (English)

    Linna Hu; Fushan Chen; Mingxing Ai; Deku Shang; Junqing Cai; Jilin Cao

    2004-01-01

    Influence factors on the biodegradation of cellulose fiber composite paperboard were studied experimentally and explained theoretically. The results show that the inorganic salts as nutriment added in the soil lixivium, the ratio of C/N, the temperature for biodegradation and content of basaltic fibers in the composite paperboard are the main influence factors.

  20. Derivation of Apollo 14 High-Al Basalts at Discrete Times: Rb-Sr Isotopic Constraints

    Science.gov (United States)

    Hui, H.; Neal, C. R.; Shih, C.-Y.; Nyquist, L. E.

    2012-03-01

    Four eruption episodes were identified for A-14 high-Al basalts. Rb-Sr isotopic data and ITE ratios show that their parental melt compositions of are correlated through mixing of evolved components with a relatively primitive magma ocean cumulate.

  1. Petrochemistry and tectonic significance of Lower Cretaceous Barros Arana Formation basalts, southernmost Chilean Andes

    Science.gov (United States)

    Stern, C. R.; Mohseni, P. P.; Fuenzalida, P. R.

    The Lower Cretaceous Barros Arana Formation (Albian, hornblende KAr age of 104 Ma), in the Magallanes region of Chile, consists of a sequence of spilitized clinopyroxene- and amphibole-bearing mafic dikes and lavas, and volcaniclastic breccias, occurring within the sedimentary infill of the Rocas Verdes marginal basin and its eastward extension onto the Cretaceous continental platform. Although the original alkali and alkaline earth element concentrations of the basaltic lavas and dikes have been altered by spilitization, the presence of relict pargasitic amphibole phenocrysts, the absence of orthopyroxene, and high LREE contents and LREE/HREE ratios imply mildly alkaline affinities for these basalts. Their low TiO 2 and HFSE (Zr, Nb, Ta, and Hf) contents and high LREE/HFSE ratios suggest affinities with convergent plate boundary arc magmas. The Barros Arana basalts are interpreted as mafic members of the mildly alkaline shoshonitic rock suite of subduction-related arcs. They may have formed as subduction geometry began to undergo the changes (flattening) that ultimately led to the initiation of the closure, deformation, and uplift of the Rocas Verdes basin by the late or post-Albian. The low initial 87Sr/ 86Sr (0.7031) and high initial 143Nd/ 144Nd (0.51277) of the basalts indicate that a generally extensional tectonic regime east of the main calc-alkaline arc allowed eruption of these mafic shoshonites without interaction with continental crust (in contrast to the contemporaneous plutons of the Patagonian batholith).

  2. Influences of chemical aging on the surface morphology and crystallization behavior of basaltic glass fibers

    DEFF Research Database (Denmark)

    Lund, Majbritt Deichgræber; Yue, Yuanzheng

    2008-01-01

    The impact of aging in high humidity and water on the surface morphology and crystallization behavior of basaltic glass fibers has been studied using scanning electron microscopy, transmission electron microscopy, calorimetry and X-ray diffraction. The results show that interaction between the...

  3. Modeled Top of the Grande Ronde Basalt Geomodel Unit (grtop_f)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The grtop_f grid represents the modeled elevation of the top of the Grande Ronde Basalt geomodel unit at a 500 foot resolution. It is one grid of a geomodel that...

  4. Modeled Top of the Wanapum Basalt Geomodel Unit (wntop_f)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The wntop_f grid represents the modeled elevation of the top of the Wanapum Basalt geomodel unit at a 500 foot resolution. It is one grid of a geomodel that...

  5. Mantle potential temperature estimates of basalt from the surface of Venus

    Science.gov (United States)

    Shellnutt, J. Gregory

    2016-10-01

    The crater density and distribution of Venus indicates the average surface age is younger (≤1 Ga) than most terrestrial planets and satellites in the Solar System. The type and rate (i.e. equilibrium, catastrophic or differential) of volcanism associated with the stagnant lid tectonic system of Venus is a first order problem that has yet to be resolved but is directly related to the thermal conditions of the mantle. The calculated primary melt composition of basalt at the Venera 14 landing site is high-Mg basalt to picrite with a mantle potential temperature estimate similar to terrestrial ambient mantle (1370 ± 70 °C). The calculated accumulated fractional melting curves indicate the olivine compositions from the melt have Mg# of 89-91. The results show that the thermal regime required to generate the primary melt composition of the Venera 14 basalt was not anomalously high (i.e. mantle-plume system) but rather consistent with a lithospheric tensional rift system. The juxtaposition of high thermal regime structures (e.g. Beta Regio) and 'ambient' mantle potential temperature estimates of the Venera 14 basalt suggests that the relatively young surface of Venus is the result of volcanism from a combination of thermal systems that resurfaced the planet at variable rates.

  6. Basalt Waste Isolation Project. Quarterly report, July 1, 1979-September 30, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Deju, R.A.

    1979-10-01

    Progress in various areas of the Basalt Waste Isolation Project during the last quarter is reported. Systems integration, licensing, geologic activities, hydrology, borehole studies, geophysical logging, engineered barriers, test facilities, testing of canisters, and selection process for architect-engineer services for repository conceptual design are discussed. (DC)

  7. Chromium isotope fractionation during oxidative weathering of a modern basaltic weathering profile

    DEFF Research Database (Denmark)

    D'Arcy, Joan Mary; Døssing, Lasse Nørbye; Frei, Robert

    contrasting climates; 1) Northern Ireland, a marine temperate climate, and 2) Uruguay, a sub-tropical climate. The oxidation of Cr in soils can be broken down into two important stages, (i) The breaking down of Cr-bearing minerals in the basalt, which make Cr (III) accessible to oxidizing processes. Cr3+ + 2H...

  8. Processing and Characterization of Basalt Fiber Reinforced Ceramic Composites for High Temperature Applications Using Polymer Precursors

    Science.gov (United States)

    Cox, Sarah B.; Lui, Donovan; Gou, Jihua

    2014-01-01

    The development of high temperature structural composite materials has been very limited due to the high cost of the materials and the processing needed. Ceramics can take much higher temperatures, but they are difficult to produce and form in bulk volumes. Polymer Derived Ceramics (PDCs) begin as a polymer matrix, allowing a shape to be formed and cured and then to be pyrolized in order to obtain a ceramic with the associated thermal and mechanical properties. The two PDCs used in this development are polysiloxane and polycarbosilane. Polysiloxanes contain a silicon oxycarbide backbone when pyrolized up to 1000C. Polycarbosilane, an organosilicon polymer, contain a silicon-carbon backbone; around 1200C, beta-SiC begins to crystallize. The use of basalt in structural and high temperature applications has been under development for over 50 years, yet there has been little published research on the incorporation of basalt fibers as a reinforcement in composites. Basalt is a naturally occurring material found in volcanic rock. Continuous basalt fiber reinforced PDCs have been fabricated and tested for the applicability of this composite system as a high temperature structural composite material. Thermal and mechanical testing includes oxyacetylene torch testing and three point bend testing.

  9. Investigating the explosivity of shallow sub-aqueous basaltic eruptions

    Science.gov (United States)

    Murtagh, R.; White, J. D. L.

    2009-04-01

    Volcanic eruptions produce pyroclasts containing vesicles, clearly implying exsolution of volatiles from the magma has occurred. Our aim is to understand the textural characteristics of vesiculated clasts as a quantitative indicator of the eruptive behaviour of a volcano. Assessing water's role in volatile degassing and outgassing has been and is being well documented for terrestrial eruptions; the same cannot be said, however, for their shallow subaqueous counterparts. The eruptive behaviour of Surtseyan volcanoes, which include both subaqueous and subaerial phases (for example, the type-location Surtsey, Iceland in 1963) is under investigation here and for good reason. Volcanic eruptions during which water and basaltic magma come into contact appear to ignite violent eruptions of many of the small "monogenetic" volcanoes so abundant on Earth. A key problem remains that detailed conditions of water-magma interactions are not yet fully understood. Field samples obtained from exposed sequences deposited originally in a subaqueous environment allow for the necessary analysis of lapilli. With the aid of experimental data, mathematical modelling and terrestrial analogues the ambition is to unravel volatile degassing, ascent histories and fragmentation processes, allowing us ultimately to identify both the role water plays in the explosivity of shallow subaqueous eruptions, and the rise history of magma to the point of interaction. The first site, Pahvant Butte is located in southwest Utah, U.S. It is a well preserved tuff cone overlying a subaqueously deposited mound of glassy ash composed of sideromelane and tachylite. It was erupted under ~85m of water into Lake Bonneville approximately 15,300 years ago. Our focus is on samples collected from a well-bedded, broadly scoured coarse ash and lapilli lithofacies on the eastern flank of the edifice. Vesicularity indices span from 52.6% - 60.8%, with very broad vesicularity ranges, 20.6% - 81.0% for one extreme sample. The

  10. Compositional Variations of Primary Basalts in the Poison Lake Chain, Lassen Region of Northern California

    Science.gov (United States)

    Lewis, G. T.; Teasdale, R.; Wenner, J. M.

    2015-12-01

    Multiple compositional mantle domains are represented by primitive basalts of the Poison Lake chain (PLC), located east of the Lassen Volcanic Center in the southern Cascades and on the western margin of the Basin and Range. Four of the nine compositional groups of PLC basalts include primary basalt samples that represent distinct mantle compositions from which other samples are likely derived. Primitive basalts from two of the groups, the old railroad grade (bg; 102.1 +/- 11.4 ka) and the basalts of Poison Butte (bp; 105.0 +/- 6.0 ka), spatially and chronologically overlap. Both groups are primitive basalts that have phenocrysts of olivine, plagioclase and clinopyroxene. However, bg has larger, more euhedral olivine while bp has fewer, smaller, anhedral and embayed olivine phenocrysts. Compositionally, bg has higher whole-rock MgO (9.2-12.2 %) and Ni (189-238 ppm) and lower Zr (57-89 ppm) than bp (MgO = 5.3-7.8 %; Ni = 35-89 ppm; Zr = 98-153 ppm), suggesting bp has undergone more fractionation than bg. MELTS and REE models predict that the most primitive unit of bg (bg3) could have fractionated to produce the other three bg units. Similarly, MELTS and REE models suggest that four of the six units of bp can be derived by fractional crystallization from bg3. However, those models require that bg3 would need to fractionate between 40-50% in order to generate the bp compositions. Unreasonably high % fractionation suggests that the relationship between bg and bp groups is more complex than simple fractionation allows, but their similar Cr spinel compositions (bg Cr# =32.9-50.9 and bp Cr# = 44.0-56.3) suggest bg and bp are likely derived from a common mantle source. Additional petrogenetic modeling and isotope analyses will help clarify the relationship between PLC primitive basalt groups. The combination of small scale mantle heterogeneities along with detailed examination of magma processing are only recognized in the PLC with high density sampling, which may be

  11. The effect of a thin weak layer covering a basalt block on the impact cratering process

    Science.gov (United States)

    Dohi, Koji; Arakawa, Masahiko; Okamoto, Chisato; Hasegawa, Sunao; Yasui, Minami

    2012-04-01

    To clarify the effect of a surface regolith layer on the formation of craters in bedrock, we conducted impact-cratering experiments on two-layered targets composed of a basalt block covered with a mortar layer. A nylon projectile was impacted on the targets at velocities of 2 and 4 km s-1, and we investigated the crater size formed on the basalt. The crater size decreased with increased mortar thickness and decreased projectile mass and impact velocity. The normalized crater volume, πV, of all the data was successfully scaled by the following exponential equation with a reduction length λ0: π=b0πY-b1exp(-λ/λ0), where λ is the normalized thickness T/Lp, T and Lp are the mortar thickness and the projectile length, respectively, b0 and b1 are fitted parameters obtained for a homogeneous basalt target, 10-2.7±0.7 and -1.4 ± 0.3, respectively, and λ0 is obtained to be 0.38 ± 0.03. This empirical equation showing the effect of the mortar layer was physically explained by an improved non-dimensional scaling parameter, πY∗, defined by πY∗=Y/(ρup2), where up was the particle velocity of the mortar layer at the boundary between the mortar and the basalt. We performed the impact experiments to obtain the attenuation rate of the particle velocity in the mortar layer and derived the empirical equation of {u}/{v}=0.50exp-{λ}/{1.03}, where vi is the impact velocity of the projectile. We propose a simple model for the crater formation on the basalt block that the surface mortar layer with the impact velocity of up collides on the surface of the basalt block, and we confirmed that this model could reproduce our empirical equation showing the effect of the surface layer on the crater volume of basalt.

  12. Effect of Miocene basaltic volcanism in Shanwang (Shandong Province, China) on environmental changes

    Institute of Scientific and Technical Information of China (English)

    GUO; ZhengFu; LIU; JiaQi; CHEN; XiaoYu

    2007-01-01

    Miocene (16-10 Ma) basalts, together with significantly well-preserved fossils (including animal and plant fossils) in the contemporaneously tephra-rich Maar sediments, are located in Shanwang volcanic region, Shandong Province, China. Distribution area of the basaltic eruption products is about 240 km2. Detailed field observations indicate that most of basaltic rocks are fissure eruptive products and some are central eruptives constrained by linear faults. The well-preserved fossils in the lacustrine deposits have been considered to be a result of mass mortalities. Based on physically volcanologic modeling results, eruption column of the basaltic fissure activities in the Shanwang volcanic region is estimated to have entered the stratosphere. Petrographic observations indicate that the basalts have porphyritic textures with phenocrysts of olivine, pyroxene, plagioclase feldspar and alkali feldspar setting in groundmass of plagioclase feldspar, alkali feldspar, quartz, apatite and glass. Based on observations of tephra, tuff and tuffites collected in the Maar sediments of the Shanwang area, we determined major element oxide concentrations and volatile composition of melt inclusions in phenocrysts and matrix glasses by electron microprobe analysis. Volatile (including S, Cl, F and H2O) concentrations erupted into the stratosphere were estimated by comparing pre- and post-eruptive volatile concentrations. Our determination results show that contents of S, Cl, F and H2O emitted into the stratosphere were 0.18%-0.24%, 0.03%-0.05%, 0.03%-0.05% and 0.4%-0.6%, respectively, which was characterized by high-S contents erupted. Amounts of volatiles emitted in the Shanwang volcanic region are much higher than those in eruptions which had a substantial effect on climate and environment. According to the compositions and amounts of the volatiles erupted from the Miocene basaltic volcanism in Shanwang, we propose a hypothesis that volatile-rich basaltic volcanism could result in

  13. Partial crystallization of picritic melt and its applications for the genesis of high-Ti and low-Ti basalts

    Science.gov (United States)

    Yang, J.; WANG, C.; Jin, Z.; Jin, S.; Yan, S.

    2015-12-01

    Geochemical and petrological studies have revealed the existence of high-Ti and low-Ti basalts in large igneous provinces (LIPs). However the originate of these high-Ti and low-Ti magmas are still under debate. Several different mechanisms have been proposed: (1) the high-Ti basalts are formed by the melting of mantle plume containing recycled oceanic crust (Spandler et al., 2008) while low-Ti basalts are formed by the melting of subcontinental lithospheric mantle (Xiao et al., 2004); (2) both high-Ti and low-Ti basalts are from mantle plume source, but the production of high-Ti basalts are associated with the thick lithosphere while the low-Ti basalts are controlled by the thin lithosphere (Arndt et al., 1993); (3) they are derived from the different degrees of melting, with high-Ti basalts representing low degree of partial melting of mantle plume (Xu et al., 2004). The low Mg# (below 0.7) of high-Ti and low-Ti basalts provides that they are far away from direct melting of mantle peridotite. In addition, seismic data indicate unusually high seismic velocities bodies beneath the LIPs which explained by the fractionated cumulates from picritic magmas (Farnetani et al., 1996). Therefore, we believed that the crystallization differentiation process might play a more significant role in the genesis of high-Ti and low-Ti basalts.In order to investigate the generation of high-Ti and low-Ti basalts, a series of high pressure and high temperature partial crystallization experiments were performed at pressures of 1.5, 3.0 and 5.0 GPa and a temperature range of 1200-1700℃. The starting material is picrate glass with relative high TiO2 (2.7 wt %), which is synthesized according to the chemical composition of primary magmas of Emeishan LIP (Xu et al., 2001). The experimental results show that: (1) At a given pressure, the TiO2 content is decreased with increasing melt fraction; (2) At a given melt fraction, the TiO2 content of melts is increased with increasing pressure. On

  14. Petrogenesis of Late Cenozoic basalts from North Hainan Island: Constraints from melt inclusions and their host olivines

    Science.gov (United States)

    Liu, Jian-Qiang; Ren, Zhong-Yuan; Nichols, Alexander R. L.; Song, Mao-Shuang; Qian, Sheng-Ping; Zhang, Yan; Zhao, Pei-Pei

    2015-03-01

    Melt inclusions and their host olivines in basaltic lavas provide important information about the nature of their mantle source. We present the first analyzed chemical data of olivine-hosted melt inclusions in Cenozoic basalts from the North Hainan Island and report the discovery of both tholeiitic and alkalic melt inclusions in a single rock sample. Cenozoic basalts from the Hainan Island are predominantly tholeiites with only small amounts of alkali basalts. There is a much broader compositional variation in melt inclusions than whole rocks. Compared to partial melts of mantle peridotite, the Hainan basalts have lower CaO, Na2O/TiO2, CaO/Al2O3 and Co/Fe, and higher TiO2, FeO∗, Fe/Mn, Zn/Fe and Zn/Mn. The olivine phenocrysts from the Hainan basalts contain lower Ca and Mn, and higher Ni and Fe/Mn than those of olivines crystallized from partial melts of peridotite. Projections from or towards olivine into the plane CS-MS-A for melt inclusions and whole rocks with MgO >7.5 wt% imply that the residual minerals in the source of the tholeiites are mainly clinopyroxene and garnet, possibly with some orthopyroxene, while in the source of the alkali basalts they are dominated by clinopyroxene and garnet. This indicates that a pyroxenite component could serve as the source lithology of the Hainan basalts. The OIB-like trace element compositions, with Ba, Sr, Nb and Ta positive anomalies, and Th and U negative anomalies, of the Hainan basalts suggest that a recycled oceanic crust component was involved in the source of the Hainan basalts. Based on a CMAS projection of primary magma compositions of the whole rocks and melt inclusions, we infer that a stage-2 silica-deficient pyroxenite derived from melt-peridotite reaction or mechanical mixing between recycled oceanic crust and peridotite can serve as the source lithology. Partial melts derived from such a source can match the overall compositions of the Hainan basalts better than those of MORB-eclogite and fertile

  15. Petrophysical and geochemical properties of Columbia River flood basalt: Implications for carbon sequestration

    Science.gov (United States)

    Zakharova, Natalia V.; Goldberg, David S.; Sullivan, E. Charlotte; Herron, Michael M.; Grau, James A.

    2012-11-01

    This study presents borehole geophysical data and sidewall core chemistry from the Wallula Pilot Sequestration Project in the Columbia River flood basalt. The wireline logging data were reprocessed, core-calibrated and interpreted in the framework of reservoir and seal characterization for carbon dioxide storage. Particular attention is paid to the capabilities and limitations of borehole spectroscopy for chemical characterization of basalt. Neutron capture spectroscopy logging is shown to provide accurate concentrations for up to 8 major and minor elements but has limited sensitivity to natural alteration in fresh-water basaltic reservoirs. The Wallula borehole intersected 26 flows from 7 members of the Grande Ronde formation. The logging data demonstrate a cyclic pattern of sequential basalt flows with alternating porous flow tops (potential reservoirs) and massive flow interiors (potential caprock). The log-derived apparent porosity is extremely high in the flow tops (20-45%), and considerably overestimates effective porosity obtained from hydraulic testing. The flow interiors are characterized by low apparent porosity (0-8%) but appear pervasively fractured in borehole images. Electrical resistivity images show diverse volcanic textures and provide an excellent tool for fracture analysis, but neither fracture density nor log-derived porosity uniquely correlate with hydraulic properties of the Grande Ronde formation. While porous flow tops in these deep flood basalts may offer reservoirs with high mineralization rates, long leakage migration paths, and thick sections of caprock for CO2 storage, a more extensive multiwell characterization would be necessary to assess lateral variations and establish sequestration capacity in this reservoir.

  16. Petrophysical and Geochemical Properties of Columbia River Flood Basalt: Implications for Carbon Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Zakharova, Natalia V.; Goldberg, David S.; Sullivan, E. C.; Herron, Michael M.; Grau, Jim A.

    2012-11-02

    Abstract This study presents borehole geophysical data and sidewall core chemistry from the Wallula Pilot Sequestration Project in the Columbia River flood basalt. The wireline logging data were reprocessed, core-calibrated and interpreted in the framework of reservoir and seal characterization for carbon dioxide storage. Particular attention is paid to the capabilities and limitations of borehole spectroscopy for chemical characterization of basalt. Neutron capture spectroscopy logging is shown to provide accurate concentrations for up to 8 major and minor elements but has limited sensitivity to natural alteration in fresh-water basaltic reservoirs. The Wallula borehole intersected 26 flows from 7 members of the Grande Ronde formation. The logging data demonstrate a cyclic pattern of sequential basalt flows with alternating porous flow tops (potential reservoirs) and massive flow interiors (potential caprock). The log-derived apparent porosity is extremely high in the flow tops (20%-45%), and considerably overestimates effective porosity obtained from hydraulic testing. The flow interiors are characterized by low apparent porosity (0-8%) but appear pervasively fractured in borehole images. Electrical resistivity images show diverse volcanic textures and provide an excellent tool for fracture analysis, but neither fracture density nor log-derived porosity uniquely correlate with hydraulic properties of the Grande Ronde formation. While porous flow tops in these deep flood basalts may offer reservoirs with high mineralization rates, long leakage migration paths, and thick sections of caprock for CO2 storage, a more extensive multi- well characterization would be necessary to assess lateral variations and establish sequestration capacity in this reservoir.

  17. Continental flood basalt weathering as a trigger for Neoproterozoic Snowball Earth

    Science.gov (United States)

    Cox, Grant M.; Halverson, Galen P.; Stevenson, Ross K.; Vokaty, Michelle; Poirier, André; Kunzmann, Marcus; Li, Zheng-Xiang; Denyszyn, Steven W.; Strauss, Justin V.; Macdonald, Francis A.

    2016-07-01

    Atmospheric CO2 levels and global climate are regulated on geological timescales by the silicate weathering feedback. However, this thermostat has failed multiple times in Earth's history, most spectacularly during the Cryogenian (c. 720-635 Ma) Snowball Earth episodes. The unique middle Neoproterozoic paleogeography of a rifting, low-latitude, supercontinent likely favored a globally cool climate due to the influence of the silicate weathering feedback and planetary albedo. Under these primed conditions, the emplacement and weathering of extensive continental flood basalt provinces may have provided the final trigger for runaway global glaciation. Weathering of continental flood basalts may have also contributed to the characteristically high carbon isotope ratios (δ13 C) of Neoproterozoic seawater due to their elevated P contents. In order to test these hypotheses, we have compiled new and previously published Neoproterozoic Nd isotope data from mudstones in northern Rodinia (North America, Australia, Svalbard, and South China) and Sr isotope data from carbonate rocks. The Nd isotope data are used to model the mafic detrital input into sedimentary basins in northern Rodinia. The results reveal a dominant contribution from continental flood basalt weathering during the ca. 130 m.y. preceding the onset of Cryogenian glaciation, followed by a precipitous decline afterwards. These data are mirrored by the Sr isotope record, which reflects the importance of chemical weathering of continental flood basalts on solute fluxes to the early-middle Neoproterozoic ocean, including a pulse of unradiogenic Sr input into the oceans just prior to the onset of Cyrogenian glaciation. Hence, our new data support the hypotheses that elevated rates of flood basalt weathering contributed to both the high average δ13 C of seawater in the Neoproterozoic and to the initiation of the first (Sturtian) Snowball Earth.

  18. Shallow Miocene basaltic magma reservoirs in the Bahia de Los Angeles basin, Baja California, Mexico

    Science.gov (United States)

    Delgado-Argote, Luis A.; García-Abdeslem, Juan

    1999-01-01

    The basement in the Bahı´a de Los Angeles basin consists of Paleozoic metamorphic rocks and Cretaceous granitoids. The Neogene stratigraphy overlying the basement is formed, from the base to the top, by andesitic lava flows and plugs, sandstone and conglomeratic horizons, and Miocene pyroclastic flow units and basaltic flows. Basaltic dikes also intrude the whole section. To further define its structure, a detailed gravimetric survey was conducted across the basin about 1 km north of the Sierra Las Flores. In spite of the rough and lineal topography along the foothills of the Sierra La Libertad, we found no evidence for large-scale faulting. Gravity data indicates that the basin has a maximum depth of 120 m in the Valle Las Tinajas and averages 75 m along the gravimetric profile. High density bodies below the northern part of the Sierra Las Flores and Valle Las Tinajas are interpreted to be part of basaltic dikes. The intrusive body located north of the Sierra Las Flores is 2.5 km wide and its top is about 500 m deep. The lava flows of the top of the Sierra Las Flores, together with the distribution of basaltic activity north of this sierra, suggests that this intrusive body continues for 20 km along a NNW-trending strike. Between the sierras Las Flores and Las Animas, a 0.5-km-wide, 300-m-thick intrusive body is interpreted at a depth of about 100 m. This dike could be part of the basaltic activity of the Cerro Las Tinajas and the small mounds along the foothills of western Sierra Las Animas. The observed local normal faulting in the basin is inferred to be mostly associated with the emplacement of the shallow magma reservoirs below Las Flores and Las Tinajas.

  19. The Oxidation State of Terrestrial Basalts and its Link with the Mantle

    Science.gov (United States)

    Mallmann, G.; O'Neill, H. S.; Berry, A. J.; Norman, M. D.; Eggins, S. M.; Kamenetsky, V.; Turner, S.; Smith, I. E.; Ballhaus, C.

    2011-12-01

    The prevailing paradigm is that the Earth's mantle is both laterally and vertically heterogeneous in regards to its oxidation state. This view has been motivated by the observation that, on average, primitive island arc basalts (IAB) preserve Fe3+/Fe2+ higher than ocean island (OIB) and, particularly, mid-ocean ridge basalts (MORB), and reinforced by the higher oxygen fugacities (fO2) determined in lithospheric (mantle wedge) arc peridotites. fO2 measurements in peridotites equilibrated over a range of pressures have also led to the notion that the mantle becomes more reduced with depth. V and Sc behave very similarly during partial melting of the mantle, but while V is redox-sensitive Sc is not. Their ratio in basalts has therefore a memory of the redox conditions during partial melting. Within the many assumptions involved in forward trace-element modeling, the bulk-rock V/Sc of MORBs, OIBs and IABs indicate that the partial melting events responsible for their genesis occurred at a relatively narrow range of fO2s between QFM and QFM-1. V olivine-liquid partition coefficients are also sensitive to oxidation state (normalization to Sc is useful to minimize the effect of variables other than fO2), and the values determined between olivine phenocrysts (Fo76-90) and quenched basaltic melts suggest that, at the time of olivine crystallization, terrestrial basalts have already oxidized about 1 log fO2 unit (IABs even more so, approximately 2 log fO2 units). The results reveal no statistically significant distinction between the oxidation states of MORBs and OIBs. This has been confirmed by Fe3+/Fe2+ determined by XANES.

  20. Petrography and geochemistry of the enriched basaltic shergottite Northwest Africa 2975

    Science.gov (United States)

    He, Qi; Xiao, Long; Balta, J. Brian; Baziotis, Ioannis P.; Hsu, Weibiao; Guan, Yunbin

    2015-11-01

    We present a study of the petrology and geochemistry of basaltic shergottite Northwest Africa 2975 (NWA 2975). NWA 2975 is a medium-grained basalt with subophitic to granular texture. Electron microprobe (EMP) analyses show two distinct pyroxene compositional trends and patchy compositional zoning patterns distinct from those observed in other meteorites such as Shergotty or QUE 94201. As no bulk sample was available to us for whole rock measurements, we characterized the fusion crust and its variability by secondary ion mass spectrometer (SIMS) measurements and laser ablation inductively coupled plasma spectroscopy (LA-ICP-MS) analyses as a best-available proxy for the bulk rock composition. The fusion crust major element composition is comparable to the bulk composition of other enriched basaltic shergottites, placing NWA 2975 within that sample group. The CI-normalized REE (rare earth element) patterns are flat and also parallel to those of other enriched basaltic shergottites. Merrillite is the major REE carrier and has a flat REE pattern with slight depletion of Eu, parallel to REE patterns of merrillites from other basaltic shergottites. The oxidation state of NWA 2975 calculated from Fe-Ti oxide pairs is NNO-1.86, close to the QFM buffer. NWA 2975 represents a sample from the oxidized and enriched shergottite group, and our measurements and constraints on its origin are consistent with the hypothesis of two distinct Martian mantle reservoirs: a reduced, LREE-depleted reservoir and an oxidized, LREE-enriched reservoir. Stishovite, possibly seifertite, and dense SiO2 glass were also identified in the meteorite, allowing us to infer that NWA 2975 experienced a realistic shock pressure of ~30 GPa.

  1. Appraisal and evolution of hydrochemical processes from proximity basalt and granite areas of Deccan Volcanic Province (DVP) in India

    Science.gov (United States)

    Sonkamble, Sahebrao; Sahya, Ashalata; Mondal, N. C.; Harikumar, P.

    2012-05-01

    SummaryThis paper deals with a systematic hydrochemical study carried out at proximity basalt and granite areas of Deccan Volcanic Province (DVP) in India to assess groundwater quality and evaluate the hydrochemical processes. A total of 40 groundwater samples were collected equally from these areas and analyzed. Results showed that the groundwaters rich in alkaline earth in the basalt and alkali rich element in the granite. The dominancy of cations was observed as Ca2+ > Mg2+ > Na+ > K+ in the basalt and Na+ > Mg2+ > K+ > Ca2+ in the granite, whereas anions as HCO3->Cl>SO42- and Cl>HCO3->SO42-, respectively. Hydrochemical processes were identified with the helps of ion exchange, carbonate weathering and dissolution, multiple ionic ratios, and silicate weathering, which shown the predominance of carbonate, dolomite, calcite and silicate (anorthite) weathering in basalt, but in granite, silicate (alkali feldspar) weathering was dominated. Factor analysis also showed that there were multiple processes acting on groundwaters, were separated from the main cluster. Salinity, Sodium Absorption Ratio (SAR), Soluble Sodium Percentage (SSP), Residual Sodium Carbonate (RSC), Kelley's Ratio (KR) and Permeability Index (PI) in well samples showed that groundwater in basalt was more suitable for irrigation purposes. Further, a digital elevation model (DEM) was generated using Global mapper (8.0 version) software, which aided to decipher the thickness of basalt trap, and vertical transition zone of basaltic (trap) and granitic (basement) aquifer at this DVP comprising with the well depths and groundwater chemistry.

  2. Mapping and compositional analysis of mare basalts in the Aristarchus region of the Moon using Clementine data

    International Nuclear Information System (INIS)

    The process of accurately defining and outlining mare basalt units is necessary for constraining the stratigraphy and ages of basalt units, which are used to determine the duration and the flux of lunar volcanism. We use a combination of Clementine's five-band ultraviolet/visible data and TiO2 and FeO abundance distribution maps to define homogenous mare basalt units and characterize their compositional variations (with maturity) in the Aristarchus region. With 20 groups of distinct mare basaltic soils identified using the method in this paper, six additional spectrally defined areas and five basaltic units are constructed, and their mineralogic quantization values provide new constraints on their temporal and spatial evolution. Our results indicate that the Aristarchus region has diverse basalt units and a complex history of volcanic evolution. We also demonstrate that the techniques, from which spectrally distinct mare basalts can be mapped, performed well in this study and can be confidently expanded to other mare regions of the Moon. (research papers)

  3. Dissolution-precipitation reactions and permeability evolution from reactions of CO2-rich aqueous solutions with fractured basalt

    Science.gov (United States)

    Wells, R. K.; Xiong, W.; Bae, Y.; Sesti, E.; Skemer, P. A.; Giammar, D.; Conradi, M.; Ellis, B. R.; Hayes, S. E.

    2015-12-01

    The injection of CO2 into fractured basalts is one of several possible solutions to mitigate global climate change; however, research on carbonation in natural basalts in relation to carbon sequestration is limited, which impedes our understanding of the processes that may influence the viability of this strategy. We are conducting bench-scale experiments to characterize the mineral dissolution and precipitation and the evolution of permeability in synthetic and natural basalts exposed to CO2-rich fluids. Analytical methods include optical and electron microscopy, electron microprobe, Raman spectroscopy, nuclear magnetic resonance (NMR), and micro X-ray computed tomography (μCT) with variable flow rates. Reactive rock and mineral samples consist of 1) packed powders of olivine or natural basalt, and 2) sintered cores of olivine or a synthetic basalt mixture. Each sample was reacted in a batch reactor at 100 °C, and 100 bars CO2. Magnesite is detected within one day in olivine packed beds, and within 15 days in olivine sintered cores. Forsterite and synthetic basalt sinters were also reacted in an NMR apparatus at 102 °C and 65 bars CO2. Carbonate signatures are observed within 72 days of reaction. Longer reaction times are needed for carbonate precipitation in natural basalt samples. Cores from the Columbia River flood basalt flows that contain Mg-rich olivine and a serpentinized basalt from Colorado were cut lengthwise, the interface mechanically roughened or milled, and edges sealed with epoxy to simulate a fractured interface. The cores were reacted in a batch reactor at 50-150 °C and 100 bars CO2. At lower temperatures, calcite precipitation is rare within the fracture after 4 weeks. At higher temperatures, numerous calcite and aragonite crystals are observed within 1 mm of the fracture entrance along the roughened fracture surface. In flow-through experiments, permeability decreased along the fracture paths within a few hours to several days of flow.

  4. MARIUS HILLS REGION, MOON: Stratigraphy of low shields and mare basalts

    Science.gov (United States)

    Gebhart, Jennifer; Hiesinger, Harry; van der Bogert, Carolyn; Hendrik Pasckert, Jan; Weinauer, Julia; Lawrence, Samuel; Stopar, Julie; Robinson, Mark

    2016-04-01

    The Marius Hills region consists of more than 250 individual basaltic low shields (usually referred to as "domes") and cones, located on a broad topographic rise. The bases of numerous low shields have slope angles of ~2-3° whereas the upper portions have slopes of ~6-7° [1], interpreted to reflect changes in composition over time [1]. However, the absence of spectral differences between the two dome morphologies and the surrounding mare basalts suggests that the observed morphologies are more plausibly explained by changes in effusion rates, temperature (viscosity), and/or crystallization over time [e.g., 2]. Previous studies indicate that volcanism in this region occurred in the Upper Imbrian (3.2-3.8 Ga) [3], although several other authors reported ages ranging from the Imbrian (~3.3 Ga) to the Eratosthenian (~2.5 Ga) [e.g., 1,2,4]. [2,5] reported that all low shields are embayed by younger mare units, indicating that they formed during an older stage of volcanic activity. Mare basalts surrounding the Marius Hills exhibit absolute model ages of 1.2-3.7 Ga [6]. We used 36 LRO NAC images to perform crater size-frequency distribution (CSFD) measurements. The images were calibrated and map-projected with ISIS 3 and imported into ArcGIS. Within ArcGIS, we used CraterTools [7] to perform our CSFD measurements. The crater size-frequency distributions were then plotted with CraterStats [8], using the production and chronology functions of [9]. We conducted CSFD measurements for 50 Marius Hills low shields. Our count area sizes ranged from 1.06 x 101 to 8.75 x 101 km2; those for adjacent basalts varied between 6.17 x 100 and 8.01 x 101 km2. We determined absolute model ages (AMAs) of 1.03 to 3.65 Ga for the low shields and did not find a spatial correlation of ages versus their locations. CSFD measurements for 27 adjacent basalts show AMAs of 1.20-3.69 Ga. Of those basalts, 24 exhibit AMAs of 3-3.5 Ga; there is no correlation of AMAs and the geographic position of the

  5. Quickly erupted volcanic sections of the Steens Basalt, Columbia River Basalt Group: Secular variation, tectonic rotation, and the Steens Mountain reversal

    Science.gov (United States)

    Jarboe, N.A.; Coe, R.S.; Renne, P.R.; Glen, J.M.G.; Mankinen, E.A.

    2008-01-01

    The Steens Basalt, now considered part of the Columbia River Basalt Group (CRBG), contains the earliest eruptions of this magmatic episode. Lava flows of the Steens Basalt cover about 50,000 km2 of the Oregon Plateau in sections up to 1000 m thick. The large number of continuously exposed, quickly erupted lava flows (some sections contain over 200 flows) allows for small loops in the magnetic field direction paths to be detected. For volcanic rocks, this detail and fidelity are rarely found outside of the Holocene and yield estimates of eruption durations at our four sections of ??2.5 ka for 260 m at Pueblo Mountains, 0.5 to 1.5 ka for 190 m at Summit Springs, 1-3 ka for 170 m at North Mickey, and ??3 ka for 160 m at Guano Rim. That only one reversal of the geomagnetic field occurred during the eruption of the Steens Basalt (the Steens reversal at approximately 16.6 Ma) is supported by comparing 40Ar/39Ar ages and magnetic polarities to the geomagnetic polarity timescale. At Summit Springs two 40Ar/39Ar ages from normal polarity flows (16.72 ?? ?? 0.29 Ma (16.61) and 16.92 ?? ?? 0.52 Ma (16.82); ?? ?? equals 2s error) place their eruptions after the Steens reversal, while at Pueblo Mountains an 40Ar/39Ar age of 16.72 ?? ?? 0.21 Ma (16.61) from a reverse polarity flow places its eruption before the Steens reversal. Paleomagnetic field directions yielded 50 nontransitional directional-group poles which, combined with 26 from Steens Mountain, provide a paleomagnetic pole for the Oregon Plateau of 85.7??N, 318.4??E, K = 15.1, A95 = 4.3. Comparison of this new pole with a reference pole derived from CRBG flows from eastern Washington and a synthetic reference pole for North America derived from global data implies relative clockwise rotation of the Oregon Plateau of 7.4 ?? 5.0?? or 14.5 ?? 5.4??, respectively, probably due to northward decreasing extension of the basin and range. ?? 2008 by the American Geophysical Union.

  6. A petrogenetic model of basalts from the Northern Central Indian Ridge: 3-11°S

    Digital Repository Service at National Institute of Oceanography (India)

    Ray, Dwijesh; Iyer, S.D.; Banerjee, R.; Misra, S.; Widdowson, M.

    ) and Y (~25 ppm) (Fig. 6). The nearly flat REE pattern [(Ce/Yb)N= 0.67?1.37] of the NCIR basalts (Fig. 7) suggest that these trace elements did not suffer any major fractionation during fractional crystallization of NCIR parent magma, except for a... progressive enrichment during fractionation (Figs. 7 d,e,f). 3. 5. Composition of parental magma of NCIR basalts It has been noted that the NCIR basalts show mixed incompatible trace element characters. Incompatible element ratios are highly variable...

  7. Preliminary geochemical and physical testing of materials for plugging of man-made accesses to a repository in basalt

    International Nuclear Information System (INIS)

    The available data on environmental conditions (both natural and man-made) at the Hanford Site are sufficient for preconceptual plug system design. Results of the geochemical testing program indicate that preferred candidate plug materials are chemically nonreactive during laboratory tests that simulated some of the expected environmental conditions. Agitated, crushed-basalt samples and mixtures containing basalt were found to be self-cementing under the hydrothermal conditions. Materials considered most suitable for consideration in future test programs and preconceptual plug design are mixtures of natural materials (basalt, clay, glaciofluvial sand, gravel, and zeolite) and processed natural materials

  8. Near field chemical speciation: the reaction of uranium and thorium with Hanford basalt and elevated pH

    International Nuclear Information System (INIS)

    The hydrolysis of radionuclides such as thorium and uranium and their subsequent chemisorption on Hanford basalt have been studied using a variety of techniques, including x-ray photoelectron and infrared spectroscopy. Data obtained to date indicate mixed complexes of uranium and thorium to be on the basalt surface, the complexes being radionuclide oxides, hydrated oxides (hydroxides), and carbonates. These findings are discussed with respect to their importance for input for models describing speciation and dissolution processes involving nuclear waste repository materials such as Hanford basalt. 5 figures, 2 tables

  9. Preliminary geochemical and physical testing of materials for plugging of man-made accesses to a repository in basalt

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, C.L.; Anttonen, G.J.; O' Rourke, J.E.; Allirot, D.

    1980-04-01

    The available data on environmental conditions (both natural and man-made) at the Hanford Site are sufficient for preconceptual plug system design. Results of the geochemical testing program indicate that preferred candidate plug materials are chemically nonreactive during laboratory tests that simulated some of the expected environmental conditions. Agitated, crushed-basalt samples and mixtures containing basalt were found to be self-cementing under the hydrothermal conditions. Materials considered most suitable for consideration in future test programs and preconceptual plug design are mixtures of natural materials (basalt, clay, glaciofluvial sand, gravel, and zeolite) and processed natural materials (portland cement Type V and grouts plus additives).

  10. Chemical characterization, nano-particle mineralogy and particle size distribution of basalt dust wastes.

    Science.gov (United States)

    Dalmora, Adilson C; Ramos, Claudete G; Oliveira, Marcos L S; Teixeira, Elba C; Kautzmann, Rubens M; Taffarel, Silvio R; de Brum, Irineu A S; Silva, Luis F O

    2016-01-01

    Understanding the geochemistry of basalt alteration is central to the study of agriculture systems. Various nano-minerals play an important role in the mobilization of contaminants and their subsequent uptake by plants. We present a new analytical experimental approach in combination with an integrated analytical protocol designed to study basalt alteration processes. Recently, throughout the world, ultra-fine and nano-particles derived from basalt dust wastes (BDW) during "stonemeal" soil fertilizer application have been of great concern for their possible adverse effects on human health and environmental pollution. Samples of BDW utilized were obtained from companies in the Nova Prata mining district in southern Brazil for chemical characterization and nano-mineralogy investigation, using an integrated application of advanced characterization techniques such as X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/Energy Dispersive Spectroscopy (EDS)/(selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM/EDS), and granulometric distribution analysis. The investigation has revealed that BDW materials are dominated by SiO2, Al2O3, and Fe2O3, with a complex micromineralogy including alkali feldspar, augite, barite, labradorite, hematite, heulandrite, gypsum, kaolinite, quartz, and smectite. In addition, we have identified a number of trace metals such as Cd, Cu, Cr, and Zn, that are preferentially concentrated into the finer, inhalable, dust fraction and, thus, could present a health hazard in the urban areas around the basalt mining zone. The implication of this observation is that use of these nanometric-sized particulates as soil fertilizer may present different health challenges to those of conventional fertilizers, inviting future work regarding the relative toxicities of these materials. Our investigation on the particle size distribution, nano-particle mineralogy and chemical composition in

  11. Controls on melting at spreading ridges from correlated abyssal peridotite - mid-ocean ridge basalt compositions

    Science.gov (United States)

    Regelous, Marcel; Weinzierl, Christoph G.; Haase, Karsten M.

    2016-09-01

    Variations in the volume and major element composition of basalt erupted along the global mid-ocean ridge system have been attributed to differences in mantle potential temperature, mantle composition, or plate spreading rate and lithosphere thickness. Abyssal peridotites, the residues of mantle melting beneath mid-ocean ridges, provide additional information on the melting process, which could be used to test these hypotheses. We compiled a global database of abyssal peridotite compositions averaged over the same ridge segments defined by Gale et al. (2013). In addition, we calculated the distance of each ridge segment to the nearest hotspots. We show that Cr# in spinel in abyssal peridotites is negatively correlated with Na90 in basalts from the same ridge segments on a global scale. Ridge segments that erupt basalts apparently produced by larger degrees of mantle melting are thus underlain by peridotites from which large amounts of melt have been extracted. We find that near-ridge hotspots have a more widespread influence on mid-ocean ridge basalt (MORB) composition and ridge depth than previously thought. However, when these hotspot-influenced ridge segments are excluded, the remaining segments show clear relationships between MORB composition, peridotite composition, and ridge depth with spreading rate. Very slow-spreading ridges (<20 mm/yr) are deeper, erupt basalts with higher Na90, Al90, K90/Ti90, and lower Fe90, Ca90/Al90, and expose peridotites with lower Cr# than intermediate and fast-spreading ridges. We show that away from hotspots, the spreading-rate dependence of the maximum degree of mantle melting inferred from Cr# in peridotites (FM) and the bulk degree of melting inferred from Na90 in basalts (FB) from the same ridge segments is unlikely to be due to variations in mantle composition. Nor can the effects of dynamic mantle upwelling or incomplete melt extraction at low spreading rates satisfactorily explain the observed compositions of abyssal

  12. Chemical characterization, nano-particle mineralogy and particle size distribution of basalt dust wastes.

    Science.gov (United States)

    Dalmora, Adilson C; Ramos, Claudete G; Oliveira, Marcos L S; Teixeira, Elba C; Kautzmann, Rubens M; Taffarel, Silvio R; de Brum, Irineu A S; Silva, Luis F O

    2016-01-01

    Understanding the geochemistry of basalt alteration is central to the study of agriculture systems. Various nano-minerals play an important role in the mobilization of contaminants and their subsequent uptake by plants. We present a new analytical experimental approach in combination with an integrated analytical protocol designed to study basalt alteration processes. Recently, throughout the world, ultra-fine and nano-particles derived from basalt dust wastes (BDW) during "stonemeal" soil fertilizer application have been of great concern for their possible adverse effects on human health and environmental pollution. Samples of BDW utilized were obtained from companies in the Nova Prata mining district in southern Brazil for chemical characterization and nano-mineralogy investigation, using an integrated application of advanced characterization techniques such as X-ray diffraction (XRD), High Resolution-Transmission Electron microscopy (HR-TEM)/Energy Dispersive Spectroscopy (EDS)/(selected-area diffraction pattern) SAED, Field Emission-Scanning Electron Microscopy (FE-SEM/EDS), and granulometric distribution analysis. The investigation has revealed that BDW materials are dominated by SiO2, Al2O3, and Fe2O3, with a complex micromineralogy including alkali feldspar, augite, barite, labradorite, hematite, heulandrite, gypsum, kaolinite, quartz, and smectite. In addition, we have identified a number of trace metals such as Cd, Cu, Cr, and Zn, that are preferentially concentrated into the finer, inhalable, dust fraction and, thus, could present a health hazard in the urban areas around the basalt mining zone. The implication of this observation is that use of these nanometric-sized particulates as soil fertilizer may present different health challenges to those of conventional fertilizers, inviting future work regarding the relative toxicities of these materials. Our investigation on the particle size distribution, nano-particle mineralogy and chemical composition in

  13. Denitrification in a deep basalt aquifer: implications for aquifer storage and recovery.

    Science.gov (United States)

    Nelson, Dennis; Melady, Jason

    2014-01-01

    Aquifer storage and recovery (ASR) can provide a means of storing water for irrigation in agricultural areas where water availability is limited. A concern, however, is that the injected water may lead to a degradation of groundwater quality. In many agricultural areas, nitrate is a limiting factor. In the Umatilla Basin in north central Oregon, shallow alluvial groundwater with elevated nitrate-nitrogen of 9 mg/L is injected into the Columbia River Basalt Group (CRBG), a transmissive confined aquifer(s) with low natural recharge rates. Once recovery of the injected water begins, however, NO3 -N in the recovered water decreases quickly to  +50, and correlate inversely with NO3 -N concentrations. This variation occurs in basalt aquifer, averaging 3.0 mg/L. Similar to nitrate concentrations, TOC drops in the recovered water, consistent with this component contributing to the denitrification of nitrate during storage.

  14. Strength and Deformability of Fiber Reinforced Cement Paste on the Basis of Basalt Fiber

    Directory of Open Access Journals (Sweden)

    Yury Barabanshchikov

    2016-01-01

    Full Text Available The research object of the paper is cement paste with the particulate reinforcement of basalt fiber. Regardless of fibers’ length at the same fiber cement mix workability and cement consumption equality compressive solidity of the specimens is reduced with increasing fiber content. This is due to the necessity to increase the water-cement ratio to obtain a given workability. The flexural stability of the specimens with increasing fiber content increments in the same conditions. There is an optimum value of the fibers’ dosage. That is why stability has a maximum when crooking. The basaltic fiber particulate reinforcement usage can abruptly increase the cement paste level limiting extensibility, which is extremely important in terms of crack resistance.

  15. Evidence for microbial carbon and sulfur cycling in deeply buried ridge flank basalt.

    Science.gov (United States)

    Lever, Mark A; Rouxel, Olivier; Alt, Jeffrey C; Shimizu, Nobumichi; Ono, Shuhei; Coggon, Rosalind M; Shanks, Wayne C; Lapham, Laura; Elvert, Marcus; Prieto-Mollar, Xavier; Hinrichs, Kai-Uwe; Inagaki, Fumio; Teske, Andreas

    2013-03-15

    Sediment-covered basalt on the flanks of mid-ocean ridges constitutes most of Earth's oceanic crust, but the composition and metabolic function of its microbial ecosystem are largely unknown. By drilling into 3.5-million-year-old subseafloor basalt, we demonstrated the presence of methane- and sulfur-cycling microbes on the eastern flank of the Juan de Fuca Ridge. Depth horizons with functional genes indicative of methane-cycling and sulfate-reducing microorganisms are enriched in solid-phase sulfur and total organic carbon, host δ(13)C- and δ(34)S-isotopic values with a biological imprint, and show clear signs of microbial activity when incubated in the laboratory. Downcore changes in carbon and sulfur cycling show discrete geochemical intervals with chemoautotrophic δ(13)C signatures locally attenuated by heterotrophic metabolism.

  16. Bimodal magmatism, basaltic volcanic styles, tectonics, and geomorphic processes of the eastern Snake River Plain, Idaho

    Science.gov (United States)

    Hughes, S.S.; Smith, R.P.; Hackett, W.R.; McCurry, M.; Anderson, S.R.; Ferdock, G.C.

    1997-01-01

    Geology presented in this field guide covers a wide spectrum of internal and surficial processes of the eastern Snake River Plain, one of the largest components of the combined late Cenozoic igneous provinces of the western United States. Focus is on widespread Quaternary basaltic plains volcanism that produced coalescent shields and complex eruptive centers that yielded compositionally evolved magmas. The guide is constructed in several parts beginning with discussion sections that provide an overview of the geology followed by road directions, with explanations, for specific locations. The geology overview briefly summarizes the collective knowledge gained, and petrologic implications made, over the past few decades. The field guide covers plains volcanism, lava flow emplacement, basaltic shield growth, phreatomagmatic eruptions, and complex and evolved eruptive centers. Locations and explanations are also provided for the hydrogeology, groundwater contamination, and environmental issues such as range fires and cataclysmic floods associated with the region.

  17. Post-impact mechanical characterisation of E-glass/basalt woven fabric interply hybrid laminates

    Directory of Open Access Journals (Sweden)

    2011-05-01

    Full Text Available Post-impact properties of different configurations (symmetrical and non-symmetrical of hybrid laminates including E-glass and basalt fibre composites, all with volume fraction of fibres equal to 0.38±0.02 and manufactured by RTM, have been studied. With this aim, interlaminar shear strength tests and four-point flexural tests of laminates impacted with different energies (0, 7.5, 15 and 22.5 J have been performed. Acoustic emission (AE localisation and AE evolution with applied flexural stress was studied to support impact damage characterisation, provided by SEM and transient thermography. The results indicate that a symmetrical configuration including E-glass fibre laminate as a core for basalt fibre laminate skins presents the most favourable degradation pattern, whilst intercalation of layers may bring to further improvement of the laminate properties, but also to more extended and complex damage patterns.

  18. Melt contribution to partitioning of trace element between plagioclase and basaltic magma of Fuji volcano, Japan

    Energy Technology Data Exchange (ETDEWEB)

    Togashi, S.; Kita, N.T.; Tomiya, A.; Morishita, Y.; Imai, N

    2003-01-15

    Ion microprobe analyses of trace elements in plagioclase crystals apply to partitioning between plagioclase phenocrysts and basaltic magma of Fuji volcano. The partitioning of trace elements of plagioclase is governed not only by the site preference of ions in the crystal as it is widely accepted, but also by the components of melt. The observed logarithmic count ratios of the ion microprobe analyses between trace and host elements in plagioclase, is linear with X{sub An} (anorthite composition of plagioclase), in the range of X{sub An} (0.55-0.85). The observed ratio is proportional with K'-value (apparent exchange partition coefficient) because of nearly constant composition of the basalt. We separate the K'-value into two terms: plagioclase component controlled term and non-plagioclase component controlled term. The second term mainly characterizes the pattern of the Onuma PC-IR-diagram in a magmatic system.

  19. Evidence of magma activation beneath the Lunayyir basaltic field (Saudi Arabia from attenuation tomography

    Directory of Open Access Journals (Sweden)

    I. Koulakov

    2014-06-01

    Full Text Available We present a seismic attenuation model for the crust beneath the Cenozoic basaltic field of Lunayyir (western Saudi Arabia, where a strong seismic swarm occurred in 2009. The tomography inversion uses the envelope shape of the S wave seismograms from over 300 strong events (M > 3.5. The resulting attenuation structures appear to be consistent with the distribution of seismic velocities. The obtained 3-D attenuation model distinguishes the low-attenuation zones down to 5 km depth corresponding to the rigid basaltic cover. At greater depths, we detect a high-attenuation anomaly coinciding with the main seismicity cluster. We propose that this zone corresponds to the upper part of the conduit area ascending from deeper magma sources. According to the distributions of local events, fluids and melts from this conduit appear to reach a depth of ~2 km, but were not able to reach the surface and cause the eruption in 2009.

  20. Energy and Carbon Flow: Comparing ultramafic- and basalt-hosted vents

    Science.gov (United States)

    Perner, M.; Bach, W.; Seifert, R.; Strauss, H.; Laroche, J.

    2010-12-01

    In deep-sea vent habitats hydrothermal fluids provide the grounds for life by supplying reduced inorganic compounds (e.g. H2, sulfide). Chemolithoautotrophs can oxidize these substrates hereby yielding energy, which can then be used to fuel autotrophic CO2 fixation. Depending on the type of host rocks (and the degree of admixed ambient seawater) the availability of inorganic electron donors can vary considerably. While in ultramafic-hosted vents H2 levels are high and H2-oxidizing metabolisms are thought to dominate, in basalt-hosted vents, H2 is much lower and microbial sulfide oxidation is considered to prevail [1, 2]. We have investigated the effect of H2 and sulfide availability on the microbial community of distinct H2-rich and H2-poor vent sites along the Mid-Atlantic Ridge. Hydrothermally influenced samples were collected from the H2-rich ultramafic-hosted Logatchev field (15°N) and the comparatively H2-poor basalt-hosted vents from 5°S and 9°S. We conducted catabolic energy calculations to estimate the potential of various electron donors to function as microbial energy sources. We performed incubation experiments with hydrothermal fluids amended with H2 or sulfide and radioactively labelled bicarbonate and determined H2 and sulfide consumption and carbon incorporation rates. We constructed metagenomic libraries for sequence-based screening of genes encoding key enzymes for H2 uptake (NiFe uptake hydrogenases, group 1), sulfide oxidation (sulfide quinone oxidoreductase, sqr) and CO2 fixation pathways (RubisCOs of the Calvin cycle [CBB] and beta-subunit of the ATP citrate lyase of the reductive tricarboxylic acid cycle [rTCA]). We evaluated parts of the metagenomes from basalt-hosted sites by pyrosequencing. Based on our incubation experiments - under the conditions applied - we could not confirm that generally H2 consumption rates and biomass syntheses in fluids derived from ultramafic-hosted locations are significantly enhanced over those from basalt

  1. Scenarios constructed for basaltic igneous activity at Yucca Mountain and vicinity

    International Nuclear Information System (INIS)

    Basaltic volcanism has been identified as a possible future event initiating a release of radionuclides from a potential repository at the proposed Yucca Mountain high-level waste repository site. The performance assessment method set forth in the Site Characterization Plan (DOE, 1988) requires that a set of scenarios encompassing all significant radionuclide release paths to the accessible environment be described. This report attempts to catalogue the details of the interactions between the features and processes produced by basaltic volcanism in the presence of the presumed groundwater flow system and a repository structure, the engineered barrier system (EBS), and waste. This catalogue is developed in the form of scenarios. We define a scenario as a well-posed problem, starting from an initiating event or process and proceeding through a logically connected and physically possible combination or sequence of features, events, and processes (FEPs) to the release of contaminants

  2. Inverse modeling for field-scale hydrologic and transport parameters of fractured basalt

    International Nuclear Information System (INIS)

    A large-scale test of infiltration into a thick sequence Of fractured Snake River Plain basalts was performed during the summer of 1994 on the Idaho National Engineering Laboratory. Monitoring of moisture and tracer movement during this test provided a set of quantitative measurements from which to obtain a field-scale hydrologic description of the fractured basalts. An inverse modeling study using these quantitative measurements was performed to obtain the representative hydrologic description. This report describes the results of the inverse modeling study and includes the background and motivation for conducting the infiltration test; a brief overview of the infiltration test; descriptions of the calibration targets chosen for the simulation study, the simulation model, and the model implementation; and the simulation results with comparisons to hydrologic and tracer breakthrough data obtained from the infiltration test

  3. Intermediate-scale sodium-concrete reaction tests with basalt and limestone concrete

    International Nuclear Information System (INIS)

    Ten tests were performed to investigate the chemical reactions and rate and extent of attack between sodium and basalt and limestone concretes. Test temperatures ranged from 510 to 8700C (950 to 16000F) and test times from 2 to 24 hours. Sodium hydroxide was added to some of the tests to assess the impact of a sodium hydroxide-aided reaction on the overall penetration characteristics. Data suggest that the sodium penetration of concrete surfaces is limited. Penetration of basalt concrete in the presence of sodium hydroxide is shown to be less severe than attack by the metallic sodium alone. Presence of sodium hydroxide changes the characteristics of sodium penetration of limestone concrete, but no major differences in bulk penetration were observed as compared to penetration by metallic sodium

  4. The Basalt Waste Isolation Project technical program evaluation process: A criteria-based method

    International Nuclear Information System (INIS)

    The need to objectively evaluate the progress being made by the Basalt Waste Isolation Project (BWIP) toward establishing the feasibility of siting a nuclear waste repository in basalt (NWRB) mandates a process for evaluating the technical work of the project. To assist BWIP management in the evaluation process, the Systems Department staff has developed a BWIP Technical Program Evaluation Process (TPEP). The basic process relates progress on project technical work to the BWIP Functional and System Performance Criteria as defined in National Waste Terminal Storage (NWTS) Criteria Documents. The benefits of the TPEP to BWIP and future plans for TPEP are discussed. During fiscal year (FY) 1982, TPEP will be further formalized and further applied to the review of BWIP technical activities

  5. Use and modification of the Universal Distinct Element Code (UDEC) for basalt block test analysis

    International Nuclear Information System (INIS)

    This report represents the final phase of the ongoing analysis program which sought to use discrete element numerical modeling methods to assess the basic deformational mechanisms of closely jointed basalt based on the results from the Near-Surface Test Facility (NSTF) Block Test. The current work involved the development and use of a three-dimensional version of the Universal Distinct Element Code (UDEC) to verify the results inferred from the previous two-dimensional modeling effort. Generally, the results of this work were in agreement with and thus did verify the previous analyses. The characterization of the basalt deformational mechanisms provided by this program will enable results from the Block Test and other small-scale tests to be extrapolated to the overall rock mass behavior to support repository design activities. 90 figs., 12 tabs

  6. BASALTIC ASTEROIDS: A NEW LOOK ON THE DIFFERENTIATION PROCESS IN THE MAIN BELT

    Directory of Open Access Journals (Sweden)

    D. Lazzaro

    2009-01-01

    Full Text Available Although asteroid (4 Vesta is the only large object in the Main Belt which shows an almost intact basaltic crust, an increasingly large number of small asteroids with a similar surface composition have been discovered in the last years. All these objects, classi ed as V-type in the diverse taxonomies, have a surface composition similar to that of the Howardites, Eucrites, and Diogenites meteorites, known as HED. In this paper we review the new ndings on basaltic asteroids, and on the HED meteorites, and discuss how these reinforce the idea that di erentiation was quite common in the Main Belt early stages of formation, in contrast to the classical scenario which considers the formation of just one large di erentiated body, (4 Vesta.

  7. Trace element abundances in megacrysts and their host basalts - Constraints on partition coefficients and megacryst genesis

    Science.gov (United States)

    Irving, A. J.; Frey, F. A.

    1984-01-01

    Rare earth and other trace element abundances are determined in megacrysts of clinopyroxene, orthopyroxene, amphibole, mica, anorthoclase, apatite and zircon, as well as their host basalts, in an effort to gather data on mineral/melt trace element partitioning during the high pressure petrogenesis of basic rocks. Phase equilibria, major element partitioning and isotopic ratio considerations indicate that while most of the pyroxene and amphibole megacrysts may have been in equilibrium with their host magmas at high pressures, mica, anorthoclase, apatite, and zircon megacrysts are unlikely to have formed in equilibrium with their host basalts. It is instead concluded that they were precipitated from more evolved magmas, and have been mixed into their present hosts.

  8. A new type of rare earth elements deposit in weathering crust of Permian basalt in western Guizhou, NW China

    Institute of Scientific and Technical Information of China (English)

    YANG Ruidong; WANG Wei; ZHANG Xiaodong; LIU Ling; WEI Huairui; BAO Miao; WANG Jingxin

    2008-01-01

    A new type of rare earth elements (REEs) deposit was discovered from the gaolinite mudstone in the weathering crust of Permian basalt, Bijie region, western Guizhou, China. It contained ∑-RE2O3 0.065%-1.086%. This type of REEs deposit was widely distributed with steady horizon and thickness of 3-4 m. The ore-bearing weathering crust (kaolinite) of the three discovered REEs deposits belonged to the third episode of the Emeishan basalt eruption. The new type of REEs deposit was suggested that basalt (tuff) weathering could lead to the en- richment of the rare earth elements. Therefore, it is of important economic significance to explore REEs deposits in the weathering crust of basalt (tufts) in Yunnan, Guizhou, and Sichuan Provinces.

  9. Combined Thickness of the Modeled Wanapum Basalt and Vantage-Latah Interbed Geomodel Units (wnthk_f)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The wnthk_f grid represents the modeled combined thickness of the Wanapum Basalt and the Vantage/Latah interbed geomodel units at a 500 foot resolution. It is one...

  10. Petrologic insights into basaltic volcanism at historically active Hawaiian volcanoes: Chapter 6 in Characteristics of Hawaiian volcanoes

    Science.gov (United States)

    Helz, Rosalind L.; Clague, David A.; Sisson, Thomas W.; Thornber, Carl R.; Poland, Michael P.; Takahashi, T. Jane; Landowski, Claire M.

    2014-01-01

    Study of the petrology of Hawaiian volcanoes, in particular the historically active volcanoes on the Island of Hawai‘i, has long been of worldwide scientific interest. When Dr. Thomas A. Jaggar, Jr., established the Hawaiian Volcano Observatory (HVO) in 1912, detailed observations on basaltic activity at Kīlauea and Mauna Loa volcanoes increased dramatically. The period from 1912 to 1958 saw a gradual increase in the collection and analysis of samples from the historical eruptions of Kīlauea and Mauna Loa and development of the concepts needed to evaluate them. In a classic 1955 paper, Howard Powers introduced the concepts of magnesia variation diagrams, to display basaltic compositions, and olivine-control lines, to distinguish between possibly comagmatic and clearly distinct basaltic lineages. In particular, he and others recognized that Kīlauea and Mauna Loa basalts must have different sources.

  11. Aqueous Alteration Rinds in Basalt: Mineralogic Characterization from Hand Sample to Outcrop with Hyperspectral Imaging and Implications for Mars 2020

    Science.gov (United States)

    Greenberger, R. N.; Mustard, J. F.; Cloutis, E. A.; Mann, P.; Wilson, J. H.

    2014-07-01

    Hydrothermally altered lacustrine pillow basalts show strong gradients in mineralogy, chemistry, and redox state from interior to exterior at thick section, hand sample, and outcrop scales identified with hyperspectral imaging and elemental mapping.

  12. Determination of properties of Proterozoic continental flood basalts of western part from North Qilian Mountains

    Institute of Scientific and Technical Information of China (English)

    夏林圻; 夏祖春; 赵江天; 徐学义; 杨合群; 赵东宏

    1999-01-01

    Proterozoic volcanic rocks of the western part from the North Qilian Mountains are the products of continental rift volcanism, belonging to continental flood basalts, the petrogeochemistry of which apears to suggest that they are derived from sub-lithospheric mantle plume sources, but that they also show evidence of continental lithosphere components involvement. Their formation is the consequences of plume-lithosphere interactions and is precursive to the opening of the North Qilian Early-Paleozoic ocean basin.

  13. Lunar basalt chronology, mantle differentiation and implications for determining the age of the Moon

    Science.gov (United States)

    Snape, Joshua F.; Nemchin, Alexander A.; Bellucci, Jeremy J.; Whitehouse, Martin J.; Tartèse, Romain; Barnes, Jessica J.; Anand, Mahesh; Crawford, Ian A.; Joy, Katherine H.

    2016-10-01

    Despite more than 40 years of studying Apollo samples, the age and early evolution of the Moon remain contentious. Following the formation of the Moon in the aftermath of a giant impact, the resulting Lunar Magma Ocean (LMO) is predicted to have generated major geochemically distinct silicate reservoirs, including the sources of lunar basalts. Samples of these basalts, therefore, provide a unique opportunity to characterize these reservoirs. However, the precise timing and extent of geochemical fractionation is poorly constrained, not least due to the difficulty in determining accurate ages and initial Pb isotopic compositions of lunar basalts. Application of an in situ ion microprobe approach to Pb isotope analysis has allowed us to obtain precise crystallization ages from six lunar basalts, typically with an uncertainty of about ± 10 Ma, as well as constrain their initial Pb-isotopic compositions. This has enabled construction of a two-stage model for the Pb-isotopic evolution of lunar silicate reservoirs, which necessitates the prolonged existence of high-μ reservoirs in order to explain the very radiogenic compositions of the samples. Further, once firm constraints on U and Pb partitioning behaviour are established, this model has the potential to help distinguish between conflicting estimates for the age of the Moon. Nonetheless, we are able to constrain the timing of a lunar mantle reservoir differentiation event at 4376 ± 18 Ma, which is consistent with that derived from the Sm-Nd and Lu-Hf isotopic systems, and is interpreted as an average estimate of the time at which the high-μ urKREEP reservoir was established and the Ferroan Anorthosite (FAN) suite was formed.

  14. Potential fossil endoliths in vesicular pillow basalt, Coral Patch Seamount, eastern North Atlantic Ocean.

    Science.gov (United States)

    Cavalazzi, Barbara; Westall, Frances; Cady, Sherry L; Barbieri, Roberto; Foucher, Frédéric

    2011-09-01

    The chilled rinds of pillow basalt from the Ampère-Coral Patch Seamounts in the eastern North Atlantic were studied as a potential habitat of microbial life. A variety of putative biogenic structures, which include filamentous and spherical microfossil-like structures, were detected in K-phillipsite-filled amygdules within the chilled rinds. The filamentous structures (∼2.5 μm in diameter) occur as K-phillipsite tubules surrounded by an Fe-oxyhydroxide (lepidocrocite) rich membranous structure, whereas the spherical structures (from 4 to 2 μm in diameter) are associated with Ti oxide (anatase) and carbonaceous matter. Several lines of evidence indicate that the microfossil-like structures in the pillow basalt are the fossilized remains of microorganisms. Possible biosignatures include the carbonaceous nature of the spherical structures, their size distributions and morphology, the presence and distribution of native fluorescence, mineralogical and chemical composition, and environmental context. When taken together, the suite of possible biosignatures supports the hypothesis that the fossil-like structures are of biological origin. The vesicular microhabitat of the rock matrix is likely to have hosted a cryptoendolithic microbial community. This study documents a variety of evidence for past microbial life in a hitherto poorly investigated and underestimated microenvironment, as represented by the amygdules in the chilled pillow basalt rinds. This kind of endolithic volcanic habitat would have been common on the early rocky planets in our Solar System, such as Earth and Mars. This study provides a framework for evaluating traces of past life in vesicular pillow basalts, regardless of whether they occur on early Earth or Mars.

  15. Permeability measurements and precipitation sealing of basalt in an ancient exhumed subduction-zone fault

    OpenAIRE

    Kato, Aitaro; Sakaguchi, Arito; Yoshida, Shingo; Mochizuki, Hiromine; Kaneda, Yoshiyuki

    2003-01-01

    We conducted permeability measurements of basalt sampled from an exhumed ancient fault zone in the Cretaceous Shimanto accretionary complex in Japan, in order to investigate permeability structure and evolution following shear failure. Permeability showed a strong reduction with increase in the effective confining pressure and temperature. Rapid sealing at elevated temperatures was observed during hold experiments following shear failure. The results indicate that the permeability of a subduc...

  16. Evolution of porosity and diffusivity associated with chemical weathering of a basalt clast

    Energy Technology Data Exchange (ETDEWEB)

    Navarre-Sitchler, A.; Steefel, C.I.; Yang, L.; Tomutsa, L.; Brantley, S.L.

    2009-02-15

    Weathering of rocks as a result of exposure to water and the atmosphere can cause significant changes in their chemistry and porosity. In low-porosity rocks, such as basalts, changes in porosity, resulting from chemical weathering, are likely to modify the rock's effective diffusivity and permeability, affecting the rate of solute transport and thus potentially the rate of overall weathering to the extent that transport is the rate limiting step. Changes in total porosity as a result of mineral dissolution and precipitation have typically been used to calculate effective diffusion coefficients through Archie's law for reactive transport simulations of chemical weathering, but this approach fails to account for unconnected porosity that does not contribute to transport. In this study, we combine synchrotron X-ray microcomputed tomography ({mu}CT) and laboratory and numerical diffusion experiments to examine changes in both total and effective porosity and effective diffusion coefficients across a weathering interface in a weathered basalt clast from Costa Rica. The {mu}CT data indicate that below a critical value of {approx}9%, the porosity is largely unconnected in the basalt clast. The {mu}CT data were further used to construct a numerical pore network model to determine upscaled, effective diffusivities as a function of total porosity (ranging from 3 to 30%) for comparison with diffusivities determined in laboratory tracer experiments. By using effective porosity as the scaling parameter and accounting for critical porosity, a model is developed that accurately predicts continuum-scale effective diffusivities across the weathering interface of the basalt clast.

  17. Melt extraction in the Earth's mantle: Constraints from U Th Pa Ra studies in oceanic basalts

    Science.gov (United States)

    Stracke, Andreas; Bourdon, Bernard; McKenzie, Dan

    2006-04-01

    U-series studies in oceanic basalts are critical for understanding melting and melt extraction in the Earth's mantle. The combined results of a detailed geochemical study of melting and melt extraction at Theistareykir, northern Iceland, provide a strong case for melt extraction via channeled melt flow at an active spreading ridge. It has often been argued, however, that widely used melting and melt extraction models, which simulate channeled melt extraction (i.e. fractional and/or dynamic melting), can only partially explain the global U-series systematics in oceanic basalts. As a consequence, more complicated models have been invoked, which suggest different styles of melt extraction at different depths/pressures in the mantle, so-called "two-porosity models". Alternatively, diffusion-controlled mechanisms have been proposed. Here we show that U-Th-Pa-Ra systematics in oceanic basalts can indeed be explained by models where melt transport occurs without chemical equilibrium between melt and solid when variations in all three critical melting parameters (residual porosity, upwelling rate of the solid mantle and melt velocity) are taken into account. Melting at ridges requires systematic variation of at least two critical melting parameters, most likely upwelling and melt extraction rate. Melts generated with increasing lateral distance to the ridge axis are generated with slower upwelling rates and are extracted with lower velocities than melts created closer to the ridge axis. Melting at ocean islands, on the other hand, can successfully be explained by variations in upwelling rate only. Global U-series systematics in OIB originate from superimposed global variations in upwelling velocity due to different buoyancy fluxes and from local variation in upwelling velocity as a function of radial distance to the plume center. The model proposed here is consistent with other geochemical data for oceanic basalts and strongly supports melt extraction via high

  18. Potential fossil endoliths in vesicular pillow basalt, Coral Patch Seamount, eastern North Atlantic Ocean.

    Science.gov (United States)

    Cavalazzi, Barbara; Westall, Frances; Cady, Sherry L; Barbieri, Roberto; Foucher, Frédéric

    2011-09-01

    The chilled rinds of pillow basalt from the Ampère-Coral Patch Seamounts in the eastern North Atlantic were studied as a potential habitat of microbial life. A variety of putative biogenic structures, which include filamentous and spherical microfossil-like structures, were detected in K-phillipsite-filled amygdules within the chilled rinds. The filamentous structures (∼2.5 μm in diameter) occur as K-phillipsite tubules surrounded by an Fe-oxyhydroxide (lepidocrocite) rich membranous structure, whereas the spherical structures (from 4 to 2 μm in diameter) are associated with Ti oxide (anatase) and carbonaceous matter. Several lines of evidence indicate that the microfossil-like structures in the pillow basalt are the fossilized remains of microorganisms. Possible biosignatures include the carbonaceous nature of the spherical structures, their size distributions and morphology, the presence and distribution of native fluorescence, mineralogical and chemical composition, and environmental context. When taken together, the suite of possible biosignatures supports the hypothesis that the fossil-like structures are of biological origin. The vesicular microhabitat of the rock matrix is likely to have hosted a cryptoendolithic microbial community. This study documents a variety of evidence for past microbial life in a hitherto poorly investigated and underestimated microenvironment, as represented by the amygdules in the chilled pillow basalt rinds. This kind of endolithic volcanic habitat would have been common on the early rocky planets in our Solar System, such as Earth and Mars. This study provides a framework for evaluating traces of past life in vesicular pillow basalts, regardless of whether they occur on early Earth or Mars. PMID:21875356

  19. A Fungal-Prokaryotic Consortium at the Basalt-Zeolite Interface in Subseafloor Igneous Crust.

    Directory of Open Access Journals (Sweden)

    Magnus Ivarsson

    Full Text Available We have after half a century of coordinated scientific drilling gained insight into Earth´s largest microbial habitat, the subseafloor igneous crust, but still lack substantial understanding regarding its abundance, diversity and ecology. Here we describe a fossilized microbial consortium of prokaryotes and fungi at the basalt-zeolite interface of fractured subseafloor basalts from a depth of 240 m below seafloor (mbsf. The microbial consortium and its relationship with the surrounding physical environment are revealed by synchrotron-based X-ray tomographic microscopy (SRXTM, environmental scanning electron microscopy (ESEM, and Raman spectroscopy. The base of the consortium is represented by microstromatolites-remains of bacterial communities that oxidized reduced iron directly from the basalt. The microstromatolites and the surrounding basalt were overlaid by fungal cells and hyphae. The consortium was overgrown by hydrothermally formed zeolites but remained alive and active during this event. After its formation, fungal hyphae bored in the zeolite, producing millimetre-long tunnels through the mineral substrate. The dissolution could either serve to extract metals like Ca, Na and K essential for fungal growth and metabolism, or be a response to environmental stress owing to the mineral overgrowth. Our results show how microbial life may be maintained in a nutrient-poor and extreme environment by close ecological interplay and reveal an effective strategy for nutrient extraction from minerals. The prokaryotic portion of the consortium served as a carbon source for the eukaryotic portion. Such an approach may be a prerequisite for prokaryotic-eukaryotic colonisation of, and persistence in, subseafloor igneous crust.

  20. A Fungal-Prokaryotic Consortium at the Basalt-Zeolite Interface in Subseafloor Igneous Crust.

    Science.gov (United States)

    Ivarsson, Magnus; Bengtson, Stefan; Skogby, Henrik; Lazor, Peter; Broman, Curt; Belivanova, Veneta; Marone, Federica

    2015-01-01

    We have after half a century of coordinated scientific drilling gained insight into Earth´s largest microbial habitat, the subseafloor igneous crust, but still lack substantial understanding regarding its abundance, diversity and ecology. Here we describe a fossilized microbial consortium of prokaryotes and fungi at the basalt-zeolite interface of fractured subseafloor basalts from a depth of 240 m below seafloor (mbsf). The microbial consortium and its relationship with the surrounding physical environment are revealed by synchrotron-based X-ray tomographic microscopy (SRXTM), environmental scanning electron microscopy (ESEM), and Raman spectroscopy. The base of the consortium is represented by microstromatolites-remains of bacterial communities that oxidized reduced iron directly from the basalt. The microstromatolites and the surrounding basalt were overlaid by fungal cells and hyphae. The consortium was overgrown by hydrothermally formed zeolites but remained alive and active during this event. After its formation, fungal hyphae bored in the zeolite, producing millimetre-long tunnels through the mineral substrate. The dissolution could either serve to extract metals like Ca, Na and K essential for fungal growth and metabolism, or be a response to environmental stress owing to the mineral overgrowth. Our results show how microbial life may be maintained in a nutrient-poor and extreme environment by close ecological interplay and reveal an effective strategy for nutrient extraction from minerals. The prokaryotic portion of the consortium served as a carbon source for the eukaryotic portion. Such an approach may be a prerequisite for prokaryotic-eukaryotic colonisation of, and persistence in, subseafloor igneous crust.

  1. Indigenous nitrogen in the Moon: Constraints from coupled nitrogen-noble gas analyses of mare basalts

    Science.gov (United States)

    Füri, Evelyn; Barry, Peter H.; Taylor, Lawrence A.; Marty, Bernard

    2015-12-01

    Nitrogen and noble gas (Ne-Ar) abundances and isotope ratios, determined by step-wise CO2 laser-extraction, static-mass spectrometry analysis, are reported for bulk fragments and mineral separates of ten lunar mare basalts (10020, 10057, 12008, 14053, 15555, 70255, 71557, 71576, 74255, 74275), one highland breccia (14321), and one ferroan anorthosite (15414). The mare basalt sub-samples 10057,183 and 71576,12 contain a large amount of solar noble gases, whereas neon and argon in all other samples are purely cosmogenic, as shown by their 21Ne/22Ne ratios of ≈0.85 and 36Ar/38Ar ratios of ≈0.65. The solar-gas-free basalts contain a two-component mixture of cosmogenic 15N and indigenous nitrogen (Earth's primordial mantle or an enstatite chondrite-like impactor. While the lowest δ15 N values allow for nitrogen trapped in the Moon's interior to be inherited from the proto-Earth and/or the impactor, the more 15N-enriched compositions require that carbonaceous chondrites provided nitrogen to the lunar magma ocean prior to the solidification of the crust. Since nitrogen can efficiently be incorporated into mafic minerals (olivine, pyroxene) under oxygen fugacities close to or below the iron-wustite buffer (Li et al., 2013), the mare basalt source region is likely characterized by a high nitrogen storage capacity. In contrast, anorthosite 15414 shows no traces of indigenous nitrogen, suggesting that nitrogen was not efficiently incorporated into the lunar crust during magma ocean differentiation.

  2. Revisiting the Jurassic Geomagnetic Reversal recorded in the Lesotho Basalt (Southern Africa)

    OpenAIRE

    Prévot, Michel; Roberts, Neil; Thompson, John; Faynot, Liliane; Perrin, Mireille; Camps, Pierre

    2003-01-01

    Post-print, as published. We carried out a detailed and continuous paleomagnetic sampling of the reversed to normal geomagnetic transition recorded by some 60 consecutive flow units near the base of the Lesotho Basalt (182-184Ma). After alternating field or thermal cleaning the directions of remanence are generally well clustered within flow units. In contrast, the thermal instability of the samples did not allow to obtain reliable paleointensity determinations. The geomagnetic transition ...

  3. Basalt fiber insulating material with a mineral binding agent for industrial use

    Science.gov (United States)

    Drozdyuk, T.; Aizenshtadt, A.; Tutygin, A.; Frolova, M.

    2016-04-01

    The paper considers a possibility of using mining industry waste as a binding agent for heat insulating material on the basis of basalt fiber. The main objective of the research is to produce a heat-insulating material to be applied in machine building in high-temperature environments. After synthetic binder having been replaced by a mineral one, an environmentally sound thermal insulating material having desirable heat-protecting ability and not failing when exposed to high temperatures was obtained.

  4. Pb-, Sr- and Nd-Isotopic systematics and chemical characteristics of cenozoic basalts, Eastern China

    Science.gov (United States)

    Peng, Z.C.; Zartman, R.E.; Futa, K.; Chen, D.G.

    1986-01-01

    Forty-eight Paleogene, Neogene and Quaternary basaltic rocks from northeastern and east-central China have been analyzed for major-element composition, selected trace-element contents, and Pb, Sr and Nd isotopic systematics. The study area lies entirely within the marginal Pacific tectonic domain. Proceeding east to west from the continental margin to the interior, the basalts reveal an isotopic transition in mantle source material and/or degree of crustal interaction. In the east, many of the rocks are found to merge both chemically and isotopically with those previously reported from the Japanese and Taiwan island-arc terrains. In the west, clear evidence exists for component(s) of Late Archean continental lithosphere to be present in some samples. A major crustal structure, the Tan-Lu fault, marks the approximate boundary between continental margin and interior isotopic behaviors. Although the isotopic signature of the western basalts has characteristics of lower-crustal contamination, a subcrustal lithosphere, i.e. an attached mantle keel, is probably more likely to be the major contributor of their continental "flavor". The transition from continental margin to interior is very pronounced for Pb isotopes, although Sr and Nd isotopes also combine to yield correlated patterns that deviate strikingly from the mid-ocean ridge basalt (MORB) and oceanic-island trends. The most distinctive chemical attribute of this continental lithosphere component is its diminished U Pb as reflected in the Pb isotopic composition when compared to sources of MORB, oceanic-island and island-arc volcanic rocks. Somewhat diminished Sm Nd and elevated Rb Sr, especially in comparison to the depleted asthenospheric mantle, are also apparent from the Nd- and Sr-isotopic ratios. ?? 1986.

  5. Petrology of rift-related basalts at Bombay High waters, Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Karisiddaiah, S.M.; Iyer, S.D.

    Tholeiitic basalts obtained in 6 cores from Bombay High Region (Maharashtra, India), at depths of 860-2550 m below the seabed, are of low K and high Fe types. SiO sub(2) varies from 45.68 to 50.72%, K sub(2)O 0.09 to 0.69%, TiO sub(2) 1.06 to 2...

  6. Pore water chemistry reveals gradients in mineral transformation across a model basaltic hillslope

    Science.gov (United States)

    Pohlmann, Michael; Dontsova, Katerina; Root, Robert; Ruiz, Joaquin; Troch, Peter; Chorover, Jon

    2016-06-01

    The extent of weathering incongruency during soil formation from rock controls local carbon and nutrient cycling in ecosystems, as well as the evolution of hydrologic flow paths. Prior studies of basalt weathering, including those that have quantified the dynamics of well-mixed, bench-scale laboratory reactors or characterized the structure and integrated response of field systems, indicate a strong influence of system scale on weathering rate and trajectory. For example, integrated catchment response tends to produce lower weathering rates than do well mixed reactors, but the mechanisms underlying these disparities remain unclear. Here we present pore water geochemistry and physical sensor data gathered during two controlled rainfall-runoff events on a large-scale convergent model hillslope mantled with 1 m uniform depth of granular basaltic porous media. The dense sampler and sensor array (1488 samplers and sensors embedded in 330 m3 of basalt) showed that rainfall-induced dissolution of basaltic glass produced supersaturation of pore waters with respect to multiple secondary solids including allophane, gibbsite, ferrihydrite, birnessite and calcite. The spatial distribution of saturation state was heterogeneous, suggesting an accumulation of solutes leading to precipitation of secondary solids along hydrologic flow paths. Rapid dissolution of primary silicates was widespread throughout the entire hillslope, irrespective of up-gradient flowpath length. However, coherent spatial variations in solution chemistry and saturation indices were observed in depth profiles and between distinct topographic regions of the hillslope. Colloids (110-2000 nm) enriched in iron (Fe), aluminum (Al), and phosphorus (P) were mobile in soil pore waters.

  7. GEOCHEMISTRY OF BASALT AND XENOLITHS AND ITS DEEP PROCESS IN DAOXIAN COUNTY,HUNAN PROVINCE

    Institute of Scientific and Technical Information of China (English)

    KONG Hua; XI Xiao-shuang; JIN Zhen-min; HUANG De-zhi

    2001-01-01

    @@ Deep xenolith are important samples for us to know composition and nature of the deep crust.There are many new volcanos which can all kinds of xenoliths such as a lower crustal graulite,and upper mantle-derived peridolite and lherzolite.In eastern China,there occured many deep xenoliths in Mesozoic-Cenzoic alkaline basalt.Besides these,some small volcanos eruptions were founded in southern Hunan province,which age is about 132-151 Ma.

  8. Detection of sub-basaltic sediments by a multi-parametric joint inversion approach

    Indian Academy of Sciences (India)

    Ajay Manglik; Saurabh K Verma; K H Singh

    2009-10-01

    In many parts of the world sedimentary horizons with potential for hydrocarbon are located below flood basalt provinces.However,the presence of high velocity basaltic overburden makes delineation of sediments difficult due to the low velocity layer problem.Electrical and electromagnetic methods have been used in such scenarios because of the good electrical conductivity contrast between basalts and underlying sediments.However,mapping of the target sediments becomes difficult when the layer is thin as the data errors due to inherent noise lead to equivalent solutions.To tackle such difficult situations,a joint inversion scheme incorporating seismic reflection and refraction, magnetotelluric and deep electrical resistivity datasets is presented. Efficacy of the scheme is tested for a model comprising a thin sedimentary layer sandwiched between a thick basalt cover and a granitic basement.The results indicate that the parameters of the target sedimentary layer are either poorly resolved or equivalent solutions are obtained by the inversion of individual datasets. Joint inversions of seismic reflection (RFLS)and refraction (RFRS),or DC and MT dataset pairs provide improved results and the range of equivalent solutions is narrowed down.Combination of any three of the above datasets leads to further narrowing of this range and improvements in mean model estimates.Joint inversion incorporating all the datasets is found to yield good estimates of the structure.Resolution analysis is carried out to appraise estimates of various model parameters obtained by jointly inverting different combinations of datasets.

  9. Stability investigation of road cut slope in basaltic rockmass, Mahabaleshwar, India

    Institute of Scientific and Technical Information of China (English)

    Ashutosh Kainthola; P.K. Singh; T.N. Singh

    2015-01-01

    Slope failures along hill cut road slopes are the major nuisance for commuters and highway planners as they put the human lives at huge risk, coupled with immense monetary losses. Analysis of these vulnerable cut slopes entails the assessment and estimation of the suitable material strength input parameters to be used in the numerical models to accomplish a holistic stability examination. For the present study a 60 m high, basaltic and lateritic road cut hill slope in Mahabaleshwar, India, has been considered. A number of samples of both basalt and laterite, in their natural state were tested in the laboratory and the evaluated maximum, minimum and mean strength parameters were employed for the three cases in a distinct element numerical model. The Mohr-Coulomb failure criterion has been incorporated in the numerical model for the material as well as the joints. The numerical investigation offered the factor of safety and insights into the probable deformational mechanism for the three cases. Beside, several critical parameters have also been judged from the study viz., mode of failure, factor of safety, shear strain rate, displacement magnitudes etc. The result of this analysis shows that the studied section is prone to recurrent failures due to the capping of a substantially thick layer of weaker lateritic material above the high strength basaltic rock mass. External triggering mechanisms like heavy pre-cipitation and earthquake may also accelerate the slope failure in this area. The study also suggests employing instant preventive measures to avert the further risk of damage.

  10. Ambient changes in tracer concentrations from a multilevel monitoring system in Basalt

    Science.gov (United States)

    Bartholomay, Roy C.; Twining, Brian V.; Rose, Peter E.

    2014-01-01

    Starting in 2008, a 4-year tracer study was conducted to evaluate ambient changes in groundwater concentrations of a 1,3,6-naphthalene trisulfonate tracer that was added to drill water. Samples were collected under open borehole conditions and after installing a multilevel groundwater monitoring system completed with 11 discrete monitoring zones within dense and fractured basalt and sediment layers in the eastern Snake River aquifer. The study was done in cooperation with the U.S. Department of Energy to test whether ambient fracture flow conditions were sufficient to remove the effects of injected drill water prior to sample collection. Results from thief samples indicated that the tracer was present in minor concentrations 28 days after coring, but was not present 6 months after coring or 7 days after reaming the borehole. Results from sampling the multilevel monitoring system indicated that small concentrations of the tracer remained in 5 of 10 zones during some period after installation. All concentrations were several orders of magnitude lower than the initial concentrations in the drill water. The ports that had remnant concentrations of the tracer were either located near sediment layers or were located in dense basalt, which suggests limited groundwater flow near these ports. The ports completed in well-fractured and vesicular basalt had no detectable concentrations.

  11. Epithermal neutron activation analysis of Cr(VI)-reducer basalt-inhabiting bacteria.

    Science.gov (United States)

    Tsibakhashvili, Nelly Yasonovna; Frontasyeva, Marina Vladimirovna; Kirkesali, Elena Ivanovna; Aksenova, Nadezhda Gennadievna; Kalabegishvili, Tamaz Levanovich; Murusidze, Ivana Georgievich; Mosulishvili, Ligury Mikhailovich; Holman, Hoi-Ying N

    2006-09-15

    Epithermal neutron activation analysis (ENAA) has been applied to study elemental composition of Cr(VI)-reducer bacteria isolated from polluted basalts from the Republic of Georgia. Cr(VI)-reducing ability of the bacteria was examined by electron spin resonance, demonstrating that the bacteria differ in their rates of Cr(VI) reduction. A well-pronounced correlation between the ability of the bacteria to accumulate Cr(V) and their ability to reduce Cr(V) to Cr(III) observed in our experiments is discussed. Elemental analysis of these bacteria also revealed that basalt-inhabiting bacteria are distinguished by relative contents of essential elements such as K, Na, Mg, Fe, Mn, Zn, and Co. A high rate of Cr(III) formation correlates with a high concentration of Co in the bacterium. ENAA detected some similarity in the elemental composition of the bacteria. The relatively high contents of Fe detected in the bacteria (140-340 microg/g of dry weight) indicate bacterial adaptation to the environmental conditions typical of the basalts. The concentrations of at least 12-19 different elements were determined in each type of bacteria simultaneously starting with the major to ultratrace elements. The range of concentrations spans over 8 orders of magnitude.

  12. Novel microbial assemblages inhabiting crustal fluids within mid-ocean ridge flank subsurface basalt.

    Science.gov (United States)

    Jungbluth, Sean P; Bowers, Robert M; Lin, Huei-Ting; Cowen, James P; Rappé, Michael S

    2016-08-01

    Although little is known regarding microbial life within our planet's rock-hosted deep subseafloor biosphere, boreholes drilled through deep ocean sediment and into the underlying basaltic crust provide invaluable windows of access that have been used previously to document the presence of microorganisms within fluids percolating through the deep ocean crust. In this study, the analysis of 1.7 million small subunit ribosomal RNA genes amplified and sequenced from marine sediment, bottom seawater and basalt-hosted deep subseafloor fluids that span multiple years and locations on the Juan de Fuca Ridge flank was used to quantitatively delineate a subseafloor microbiome comprised of distinct bacteria and archaea. Hot, anoxic crustal fluids tapped by newly installed seafloor sampling observatories at boreholes U1362A and U1362B contained abundant bacterial lineages of phylogenetically unique Nitrospirae, Aminicenantes, Calescamantes and Chloroflexi. Although less abundant, the domain Archaea was dominated by unique, uncultivated lineages of marine benthic group E, the Terrestrial Hot Spring Crenarchaeotic Group, the Bathyarchaeota and relatives of cultivated, sulfate-reducing Archaeoglobi. Consistent with recent geochemical measurements and bioenergetic predictions, the potential importance of methane cycling and sulfate reduction were imprinted within the basalt-hosted deep subseafloor crustal fluid microbial community. This unique window of access to the deep ocean subsurface basement reveals a microbial landscape that exhibits previously undetected spatial heterogeneity.

  13. Microbial characterization of basalt formation waters targeted for geological carbon sequestration.

    Science.gov (United States)

    Lavalleur, Heather J; Colwell, Frederick S

    2013-07-01

    Geological carbon sequestration in basalts is a promising solution to mitigate carbon emissions into the Earth's atmosphere. The Wallula pilot well in Eastern Washington State, USA provides an opportunity to investigate how native microbial communities in basalts are affected by the injection of supercritical carbon dioxide into deep, alkaline formation waters of the Columbia River Basalt Group. Our objective was to characterize the microbial communities at five depth intervals in the Wallula pilot well prior to CO2 injection to establish a baseline community for comparison after the CO2 is injected. Microbial communities were examined using quantitative polymerase chain reaction to enumerate bacterial cells and 454 pyrosequencing to compare and contrast the diversity of the native microbial communities. The deepest depth sampled contained the greatest amount of bacterial biomass, as well as the highest bacterial diversity. The shallowest depth sampled harbored the greatest archaeal diversity. Pyrosequencing revealed the well to be dominated by the Proteobacteria, Firmicutes, and Actinobacteria, with microorganisms related to hydrogen oxidizers (Hydrogenophaga), methylotrophs (Methylotenera), methanotrophs (Methylomonas), iron reducers (Geoalkalibacter), sulfur oxidizers (Thiovirga), and methanogens (Methermicocccus). Thus, the Wallula pilot well is composed of a unique microbial community in which hydrogen and single-carbon compounds may play a significant role in sustaining the deep biosphere.

  14. Development and characterization of basalt-glass ceramics for the immobilization of transuranic wastes

    International Nuclear Information System (INIS)

    Basalt-based waste forms were developed for the immobilization of transuranic (TRU) contaminated wastes. The specific waste studied is a 3:1 blend of process sludge and incinerator ash. Various amounts of TRU blended waste were melted with Pomona basalt powder. The vitreous products were subjected to a variety of heat treatment conditions to form glass ceramics. The total crystallinity of the glass ceramic, ranging from 20 to 45 wt %, was moderately dependent on composition and heat treatment conditions. Three parent glasses and four glass ceramics with varied composition and heat treatment were produced for detailed phase characterization and leaching. Both parent glasses and glass ceramics were mainly composed of a continuous, glassy matrix phase. This glass matrix entered into solution during leaching in both types of materials. The Fe-Ti rich dispersed glass phase was not significantly degraded by leaching. The glass ceramics, however, exhibited four to ten times less elemental releases during leaching than the parent glasses. The glass ceramic matrix probably contains higher Fe and Na and lower Ca and Mg relative to the parent glass matrix. The crystallization of augite in the glass ceramics is believed to contribute to the improved leach rates. Leach rates of the basalt glass ceramic are compared to those of other TRU nuclear waste forms containing 239Pu

  15. Characteristics of terrestrial basaltic rock populations: Implications for Mars lander and rover science and safety

    Science.gov (United States)

    Craddock, Robert A.; Golombek, Matthew P.

    2016-08-01

    We analyzed the morphometry of basaltic rock populations that have been emplaced or affected by a variety of geologic processes, including explosive volcanic eruptions (as a proxy for impact cratering), catastrophic flooding, frost shattering, salt weathering, alluvial deposition, and chemical weathering. Morphometric indices for these rock populations were compared to an unmodified population of rocks that had broken off a solidified lava flow to understand how different geologic processes change rock shape. We found that a majority of rocks have an sphericity described as either a disc or sphere in the Zingg classification system and posit that this is a function of cooling fractures in the basalt (Zingg [1935] Schweiz. Miner. Petrogr. Mitt., 15, 39-140). Angularity (roundness) is the most diagnostic morphometric index, but the Corey Shape Factor (CSF), Oblate-Prolate Index (OPI) and deviation from compactness (D) also sometimes distinguished weathering processes. Comparison of our results to prior analyses of rock populations found at the Mars Pathfinder, Spirit, and Curiosity landing sites support previous conclusions. The observation that the size-frequency distribution of terrestrial rock populations follow exponential functions similar to lander and orbital measurements of rocks on Mars, which is expected from fracture and fragmentation theory, indicates that these distributions are being dominantly controlled by the initial fracture and fragmentation of the basalt.

  16. The effect of oxygen fugacity on the solubility of carbon-oxygen fluids in basaltic melt

    Science.gov (United States)

    Pawley, Alison R.; Holloway, John R.; Mcmillan, Paul F.

    1992-01-01

    The solubility of CO2-CO fluids in a midocean ridge basalt have been measured at 1200 C, 500-1500 bar, and oxygen fugacities between NNO and NNO-4. In agreement with results of previous studies, the results reported here imply that, at least at low pressures, CO2 dissolves in basaltic melt only in the form of carbonate groups. The dissolution reaction is heterogeneous, with CO2 molecules in the fluid reacting directly with reactive oxygens in the melt to produce CO3(2-). CO, on the other hand, is insoluble, dissolving neither as carbon, molecular CO, nor CO3(2-). It is shown that, for a given pressure and temperature, the concentration of dissolved carbon-bearing species in basaltic melt in equilibrium with a carbon-oxygen fluid is proportional to the mole fraction of CO2 in the fluid, which is a function of fO2. At low pressures CO2 solubility is a linear function of CO2 fugacity at constant temperatures.

  17. The Efficiency of Basalt Fibres in Strengthening the Reinforced Concrete Beams

    Directory of Open Access Journals (Sweden)

    Andreea Şerbescu

    2006-01-01

    Full Text Available The technique of externally bonding fibre reinforced polymer (FRP composite laminates on the tension side of reinforced concrete (RC beams is already widely accepted as an easy to apply, corrosion resistant and effective solution due to the high strength as well as the low weight of the composite material. The basalt fibres are produced from volcano rocks by a simple process; their applicability as reinforcing material composites utilized for plate bonding of RC beams was not enough researched up to now but it seems to be a cost-effective, durable and fire resistant alternative to traditional fibres. High basalt fiber’s advantages, related to physical-mechanical characteristics and cost, stipulate a new high efficient structural composite materials, which can replace asbestos, metal, timber, plastic materials, etc. The paper investigates the applicability of externally bonded Basalt Fibre Reinforced Polymer (BFRP laminates in strengthening of rectangular reinforced section of a RC beam. The influence of the cross-sectional BFRP area on service and ultimate bending moments and also on service deflection, are analysed. The procedure is based on section analysis, equilibrium of forces and compatibility of strains, considered appropriate for any type of fibres, in case of rectangular RC beams.

  18. Processing and Material Characterization of Continuous Basalt Fiber Reinforced Ceramic Matrix Composites Using Polymer Derived Ceramics.

    Science.gov (United States)

    Cox, Sarah B.

    2014-01-01

    The need for high performance vehicles in the aerospace industry requires materials which can withstand high loads and high temperatures. New developments in launch pads and infrastructure must also be made to handle this intense environment with lightweight, reusable, structural materials. By using more functional materials, better performance can be seen in the launch environment, and launch vehicle designs which have not been previously used can be considered. The development of high temperature structural composite materials has been very limited due to the high cost of the materials and the processing needed. Polymer matrix composites can be used for temperatures up to 260C. Ceramics can take much higher temperatures, but they are difficult to produce and form in bulk volumes. Polymer Derived Ceramics (PDCs) begin as a polymer matrix, allowing a shape to be formed and cured and then to be pyrolized in order to obtain a ceramic with the associated thermal and mechanical properties. The use of basalt in structural and high temperature applications has been under development for over 50 years, yet there has been little published research on the incorporation of basalt fibers as a reinforcement in the composites. In this study, continuous basalt fiber reinforced PDCs have been fabricated and tested for the applicability of this composite system as a high temperature structural composite material. The oxyacetylene torch testing and three point bend testing have been performed on test panels and the test results are presented.

  19. K/Ar radiometric dating of basaltic rocks in Transdanubia, Hungary

    International Nuclear Information System (INIS)

    K/Ar datings were made on 39 types of Pliocene-Pleistocene basaltic rocks from Transdanubia, Hungary. The isotopic tracer technique and the isochron method for dating are presented. The radiometric data were evaluated in view of the geological position and petrographic type and character of the samples. In addition to the conventional K/Ar dates, the 40Ar/36Ar-K/36Ar isochron dates were also calculated for presumably cogenetic samples. According to the present determinations, the age of basalts erupted near Pula at the end of the middle part of the Upper Pannonian Formation is 4.15+-0.17 m.y. The basalts of some hills in the area could be assigned to the upper part of the Upper Pannonian Formation. The average K/Ar age of the Pleistocene basic volcanic rock at village Bar is 2.02+-0.14 m.y., and its isochron age is 2.11+-0.17 m.y. (author)

  20. Basaltic glass alteration in confined media: analogy with nuclear glass in geological disposal conditions

    International Nuclear Information System (INIS)

    This dissertation concerns basaltic glass alteration mechanisms and rates. Through a better understanding of the processes controlling the basaltic glass durability, this thesis attempts to establish a link between laboratory studies and volcanic glass alteration in natural environment. The methodology used here is similar to the one used for nuclear glasses. Thus, we measured for the first time the residual alteration rate of basaltic glasses. Protective effect of the alteration film is clearly established. Moreover, synthetic glass representativeness is evaluated through a study focused on the effect of iron oxidation degree on the glass structure and leaching properties. A minor effect of Fe II on the forward rate and a negligible effect on the residual rate are shown. The residual rate is extrapolated at 5 C and compared to the mean alteration rate of natural samples of ages ranging from 1900 to 107 years. Non-zeolitized natural glasses follow this linear tendency, suggesting a control of the long-term rate by clayey secondary phase precipitation. Natural environments are open environments: a parametric study was performed in order to quantify the water flow rate effect on chemical composition of the alteration layer. When applied to two natural samples, the obtained laws provide coherent results. It seems possible to unify the descriptive approach from the study of natural environments to the mechanistic approach developed at the laboratory. The next step will consist in developing a model to transpose these results to nuclear glasses. (author)

  1. Isotopic composition of strontium in three basalt-andesite centers along the Lesser Antilles arc

    Science.gov (United States)

    Hedge, C.E.; Lewis, J.F.

    1971-01-01

    Si87/Sr86 ratios have been determined for lavas and py lastic rocks from three basalt-andesite centers along the Lesser Antilles arc-Mt. Misery on the island of St. Kitts, Soufriere on the island of St. Vincent, and Carriacou, an island of The Grenadines. The average Si87/Sr86 content of these rocks is 0.7038 for Mt. Misery, 0.7041 for Soufriere, and 0.7053 for Carriacou. All the Sr87/Sr86 values from each center are the same within analytical uncertainty (??0.0002). The constancy of strontium isotopic data within each center supports the hypothesis that basalts and andesites for each specific center investigated are generated from the same source - in agreement with petrographic and major- and minor-element data. Strontium isotopic compositions and elemental concentrations, particularly of strontium and nickel, indicate that this source was mantle peridotite and that the relationship between the respective basalts and andesites is probably fractional crystallization. ?? 1971 Springer-Verlag.

  2. Phase Equilibria Constraints on Relations of Ore-bearing Intrusionswith Flood Basalts in the Panxi Region, Southwestern China

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zhaochong; HAO Yanli; AI Yu; LI Ying; ZHAO Li

    2009-01-01

    There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province (LIP); namely, small uitramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element (PGE)-bearing sulfide deposits and large mafic layered intrusions that host giant Ti-V magnetite deposits in the Panxi region. However, except for their coeval ages, the genetic relations between the ore-bearing intrusions and extrusive rocks are poorly understood. Phase equilibria analysis (Q-PI-OI-Opx-Cpx system) has been carried out to elucidate whether ore-bearing Panzhihua, Xinjie and Limahe intrusions are co-magmatic with the picrites and flood basalts (including high-Ti, low-Ti and alkali basalts), respectively. In this system, the parental magma can be classified as silica-undersaturated olivine basalt and silica-saturated tholeiite. The equivalents of the parental magma of the Xinjie and Limahe peridotites and picrites and iow-Ti basalts are silica-undersaturated, whereas the Limahe gabbro-diorites and high-Ti basalts are silica-saturated. In contrast, the Panzhihua intrusion appears to be alkali character. Phase equilibria relations clearly show that the magmas that formed the Panzhihua intrusion and high-Ti basalts cannot be co-magmatic as there is no way to derive one liquid from another by fractional crystallization. On the other hand, the Panzhihua intrusion appears to be related to Permian alkali intrusions in the region, but does not appear to be related to the alkali basalts recognized in the Longzhoushan lava stratigraphy. Comparably, the Limabe intrusion appears to be a genetic relation to the picrites, whereas the Xinjie intrusion may be genetically related to be low-Ti basaits. Additionally, the gabbro-diorites and peridotites of the Limahe intrusion are not co-magmatic, and the former appears to be derived liquid from high-Ti basalts.

  3. Multiphase Alkaline Basalts of Central Al-Haruj Al-Abyad of Libya: Petrological and Geochemical Aspects

    Directory of Open Access Journals (Sweden)

    Abdel-Aal M. Abdel-Karim

    2013-01-01

    Full Text Available Al-Haruj basalts that represent the largest volcanic province in Libya consist of four lava flow phases of varying thicknesses, extensions, and dating. Their eruption is generally controlled by the larger Afro-Arabian rift system. The flow phases range from olivine rich and/or olivine dolerites to olivine and/or normal basalts that consist mainly of variable olivine, clinopyroxene, plagioclase, and glass. Olivine, plagioclase, and clinopyroxene form abundant porphyritic crystals. In olivine-rich basalt and olivine basalt, these minerals occur as glomerophyric or seriate clusters of an individual mineral or group of minerals. Groundmass textures are variably intergranular, intersertal, vitrophyric, and flow. The pyroclastic, clastogenic flows and/or ejecta of the volcanic cones show porphyritic, vitrophric, pilotaxitic, and vesicular textures. They are classified into tholeiite, alkaline, and olivine basalts. Three main groups are recorded. Basalts of phase 1 are generated from tholeiitic to alkaline magma, while those of phases 3 and 4 are derived from alkaline magma. It is proposed that the tholeiitic basalts represent prerift stage magma generated by higher degree of partial melting (2.0–3.5% of garnet-peridotite asthenospheric mantle source, at shallow depth, whereas the dominant alkaline basalts may represent the rift stage magma formed by low degree of partial melting (0.7–1.5% and high fractionation of the same source, at greater depth in an intra-continental plate with OIB affinity. The melt generation could be also attributed to lithosphere extension associated with passive rise of variable enriched mantle.

  4. Summary and evaluation of hydraulic property data available for the Hanford Site upper basalt confined aquifer system

    Energy Technology Data Exchange (ETDEWEB)

    Spane, F.A. Jr.; Vermeul, V.R.

    1994-09-01

    Pacific Northwest Laboratory, as part of the Hanford Site Ground-Water Surveillance Project, examines the potential for offsite migration of contamination within the upper basalt confined aquifer system. For the past 40 years, hydrologic testing of the upper basalt confined aquifer has been conducted by a number of Hanford Site programs. Hydraulic property estimates are important for evaluating aquifer flow characteristics (i.e., ground-water flow patterns, flow velocity, transport travel time). Presented are the first comprehensive Hanford Site-wide summary of hydraulic properties for the upper basalt confined aquifer system (i.e., the upper Saddle Mountains Basalt). Available hydrologic test data were reevaluated using recently developed diagnostic test analysis methods. A comparison of calculated transmissivity estimates indicates that, for most test results, a general correspondence within a factor of two between reanalysis and previously reported test values was obtained. For a majority of the tests, previously reported values are greater than reanalysis estimates. This overestimation is attributed to a number of factors, including, in many cases, a misapplication of nonleaky confined aquifer analysis methods in previous analysis reports to tests that exhibit leaky confined aquifer response behavior. Results of the test analyses indicate a similar range for transmissivity values for the various hydro-geologic units making up the upper basalt confined aquifer. Approximately 90% of the calculated transmissivity values for upper basalt confined aquifer hydrogeologic units occur within the range of 10{sup 0} to 10{sup 2} m{sup 2}/d, with 65% of the calculated estimate values occurring between 10{sup 1} to 10{sup 2} m{sup 2}d. These summary findings are consistent with the general range of values previously reported for basalt interflow contact zones and sedimentary interbeds within the Saddle Mountains Basalt.

  5. Numerical simulation of basaltic lava flows in the Auckland Volcanic Field, New Zealand—implication for volcanic hazard assessment

    OpenAIRE

    Kereszturi, G.; Volcanic Risk Solutions, Institute of Agriculture and Environment, Massey University, New Zealand; Cappello, A.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Catania, Catania, Italia; Ganci, G.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Catania, Catania, Italia; Procter, J.; Volcanic Risk Solutions, Institute of Agriculture and Environment, Massey University, New Zealand; Németh, K.; Volcanic Risk Solutions, Institute of Agriculture and Environment, Massey University, New Zealand; Del Negro, C.; Istituto Nazionale di Geofisica e Vulcanologia, Sezione Catania, Catania, Italia; Cronin, S. J.; Volcanic Risk Solutions, Institute of Agriculture and Environment, Massey University, New Zealand

    2014-01-01

    Monogenetic volcanic fields, such as the Auckland Volcanic Field (AVF), New Zealand, are common on the Earth’s surface and are typically dominated by basaltic lava flows up to 10 s of km long. In monogenetic volcanic fields located in close proximity to human population and infrastructure, lava flows are a significant threat. In this study, lava flow emplacement conditions for some basaltic eruptions of the AVF were reconstructed using the thermo-rheological MAGFLOW model. Eight existi...

  6. Geochemical and Sr-Nd isotope variations within Cretaceous continental flood-basalt suites of the Canadian High Arctic, with a focus on the Hassel Formation basalts of northeast Ellesmere Island

    Science.gov (United States)

    Estrada, Solveig

    2015-11-01

    Early- to mid-Cretaceous flood-basalt suites of the northeast Canadian High Arctic assigned to a High Arctic Large Igneous Province (HALIP) were studied for their whole-rock geochemistry and Sr-Nd isotopes. Data from basalt flows within the upper Albian to lower Cenomanian Hassel Formation of northeast Ellesmere Island are compared with former published data and new inductively coupled plasma mass spectrometry data of the stratigraphic equivalent Strand Fiord basalts and the older, late Hauterivian to Aptian Isachsen basalts from Axel Heiberg Island. The transitional to mildly alkaline aphyric Hassel basalts, with ocean island basalt (OIB)-like geochemical signatures in parts, have an Ar-Ar whole-rock age of on average 96.4 ± 1.6 Ma. They represent two geochemically different flow units without a fractional crystallization relationship: the high-phosphorous (HP) and low-phosphorous (LP) basalts. The Hassel HP basalts differ from the LP basalts by additionally higher Ba, K, Rb, Th and LREE contents, a pronounced positive Eu anomaly (Eu/Eu* = 1.74-1.76), as well as lower Ta, Nb, Zr and Hf concentrations. The Nd and Sr isotope ratios of the Hassel HP basalts [ ɛ Nd( t) of -1.3 to -1.4, 87Sr/86Sr( t) of 0.70706-0.70707] and the LP basalts [ ɛ Nd( t) of 4.5-4.9, 87Sr/86Sr( t) of 0.7038-0.7040] indicate an origin from different mantle sources. The geochemically similar tholeiitic Isachsen (ca. 130-113 Ma) and Strand Fiord basalts (ca. 105-95 Ma) are also incompatible element enriched relative to the primitive mantle, however, with negative Sr-P anomalies as well as partially negative K, Ta and Nb anomalies. In terms of incompatible element ratios (Zr/Nb, Nb/Th), several mantle components are involved in the formation of the flood-basalt suites: a component with primitive mantle composition, an OIB-like component (probably subducted and recycled oceanic crust) and an enriched lithospheric component. The latter component, probably metasomatized subcontinental

  7. Linking geology, fluid chemistry, and microbial activity of basalt- and ultramafic-hosted deep-sea hydrothermal vent environments.

    Science.gov (United States)

    Perner, M; Hansen, M; Seifert, R; Strauss, H; Koschinsky, A; Petersen, S

    2013-07-01

    Hydrothermal fluids passing through basaltic rocks along mid-ocean ridges are known to be enriched in sulfide, while those circulating through ultramafic mantle rocks are typically elevated in hydrogen. Therefore, it has been estimated that the maximum energy in basalt-hosted systems is available through sulfide oxidation and in ultramafic-hosted systems through hydrogen oxidation. Furthermore, thermodynamic models suggest that the greatest biomass potential arises from sulfide oxidation in basalt-hosted and from hydrogen oxidation in ultramafic-hosted systems. We tested these predictions by measuring biological sulfide and hydrogen removal and subsequent autotrophic CO2 fixation in chemically distinct hydrothermal fluids from basalt-hosted and ultramafic-hosted vents. We found a large potential of microbial hydrogen oxidation in naturally hydrogen-rich (ultramafic-hosted) but also in naturally hydrogen-poor (basalt-hosted) hydrothermal fluids. Moreover, hydrogen oxidation-based primary production proved to be highly attractive under our incubation conditions regardless whether hydrothermal fluids from ultramafic-hosted or basalt-hosted sites were used. Site-specific hydrogen and sulfide availability alone did not appear to determine whether hydrogen or sulfide oxidation provides the energy for primary production by the free-living microbes in the tested hydrothermal fluids. This suggests that more complex features (e.g., a combination of oxygen, temperature, biological interactions) may play a role for determining which energy source is preferably used in chemically distinct hydrothermal vent biotopes.

  8. Clinopyroxene-melt Equilibrium of Cenozoic Basalts in Kuandian,Hannuoba and Mingxi areas, Eastern China and Its Importance

    Institute of Scientific and Technical Information of China (English)

    LI Tianfu; MA Hongwen

    2001-01-01

    Based on clinopyroxene (cpx)-melt equilibrium thermobarometer, this paper deals with the calculation of the elinopyroxene-melt equilibrium temperature and pressure of basalts in Kuandian,Hannuoba and Mingxi areas, eastern China. These basalts all bear mantle xenoliths. The results indicate that the crystallizing temperature and pressure of clinopyroxene phenocrysts in alkaline basalts are commonly higher than those in subalkaline basalts and the crystallizing temperature and pressure of cpx megacrysts are higher than those of phenocrysts, which further confirms that the cpx megaerysts crystallized at higher pressure than cpx porphyritic crystals. The cpx phenocrysts at various pressures indicates that the cpx can crystallize continually along the way the magma moves up.Regression analysis shows, although the basalts bearing mantle xenoliths moved up very rapidly, heat diffusion rather than adiabatic process still occurred. The comparison of temperatures and pressures between the cpx phenocrysts and megacrysts crystallization and xenolith in alkali basalts demonstrates that host magma came deeper than the mantle xenoliths in terms of pressure and the xenoliths are therefore the upper mantle fragments captured by magma along the way up but not the source residues of the host magma as considered previously.

  9. Linking geology, fluid chemistry, and microbial activity of basalt- and ultramafic-hosted deep-sea hydrothermal vent environments.

    Science.gov (United States)

    Perner, M; Hansen, M; Seifert, R; Strauss, H; Koschinsky, A; Petersen, S

    2013-07-01

    Hydrothermal fluids passing through basaltic rocks along mid-ocean ridges are known to be enriched in sulfide, while those circulating through ultramafic mantle rocks are typically elevated in hydrogen. Therefore, it has been estimated that the maximum energy in basalt-hosted systems is available through sulfide oxidation and in ultramafic-hosted systems through hydrogen oxidation. Furthermore, thermodynamic models suggest that the greatest biomass potential arises from sulfide oxidation in basalt-hosted and from hydrogen oxidation in ultramafic-hosted systems. We tested these predictions by measuring biological sulfide and hydrogen removal and subsequent autotrophic CO2 fixation in chemically distinct hydrothermal fluids from basalt-hosted and ultramafic-hosted vents. We found a large potential of microbial hydrogen oxidation in naturally hydrogen-rich (ultramafic-hosted) but also in naturally hydrogen-poor (basalt-hosted) hydrothermal fluids. Moreover, hydrogen oxidation-based primary production proved to be highly attractive under our incubation conditions regardless whether hydrothermal fluids from ultramafic-hosted or basalt-hosted sites were used. Site-specific hydrogen and sulfide availability alone did not appear to determine whether hydrogen or sulfide oxidation provides the energy for primary production by the free-living microbes in the tested hydrothermal fluids. This suggests that more complex features (e.g., a combination of oxygen, temperature, biological interactions) may play a role for determining which energy source is preferably used in chemically distinct hydrothermal vent biotopes. PMID:23647923

  10. The First Paleomagnetic data from the Cambrian basalts of Henrietta Island (De Long Archipelago, Arctic Ocean)

    Science.gov (United States)

    Metelkin, D. V.; Zhdanova, A.; Vernikovskiy, V. A.; Matushkin, N. Y.

    2015-12-01

    Henrietta Island in De Long archipelago (East-Siberian sea) still remains poorly studied geologically but last investigations show that its volcano-sedimentary sequences can help reconstruct tectonic evolution of East Russian Arctic in Early Paleozoic stage. The deposits lying on Precambrian basements are deformed to varying degrees and intruded by mafic dykes.The study was carried out on two basaltic lava flows whose 40Ar/39Ar age is 520.6±9.5 Ma. Previously the age of these basalts was assumed Cretaceous. According to available data the underlaying sediments contain zircons with Cambrian and Ordovician ages but all boundaries between these basalts and other strata are tectonic. So we suppose the age of basalts as Middle Cambrian but more precise geochronological data are required. All magnetic measurements were performed at the Laboratory of Geodynamics and Paleomagnetism of Institute of Petroleum Geology and Geophysics (Novosibirsk). Basalt samples has relatively high magnetic susceptibility values varying from 5x10-4 to 180x10-4SI units. NRM values range is from 3 to 170 mA/m. Petromagnetic parameters including also coercive characteristics point at the good potentially preserving primary magnetization. Stepwise thermal demagnetization permits to isolate characteristic components of magnetization and calculate mean directions in two lava flows: 1. Ds=294.3°, Is=29.1°, K=81.1, α95=5.1; 2. Ds=301.0°, Is=28.3°, K=34.4, α95=7.9). The mean paleomagnetic pole has coordinates: Plat=20.9°, Plong = 42.6°, dp/dm=14.3/7.9. Paleolatitude was defined as 15.3° but the question of the hemisphere for De Long Islands is open yet. In case of south hemisphere in Middle Cambrian according to available paleomagnetic data De Long islands could be placed close to Taimyr margin of Siberia and in case of northern hemisphere they may be located near south (in present-day coordinates) margin of Siberia. The work was supported by grant RFBR 14-05-31399 and Russian Research Fund

  11. Geochemistry and Petrology of Emeishan Basalts and Subcontinental Mantle Evolution in Southwestern China

    Institute of Scientific and Technical Information of China (English)

    汪云亮; S.S.HUGHES; 等

    1989-01-01

    Three major volcanic rock sequences in the P2β formation(Emeishan basalts)were sampled dur-ing a comprehensive study of the Late Permian volcanics associated with the Panxi paleorift in southwestern China .Two of the three sections-Emei and Tangfang are composed of continental flood basalts(CFB) while the third-Ertan is an alkalic center.Multi-element chemical analyses indi-cate a predominance of low MgO transitional quartz tholeiites at Emei and Tangfang,whereas the Ertan suite ranges from high-MgO alkaline olivine basalts to rhombic porphyry trachytes and quartz-bearing aegerine-augite syenites.Consanguineity of the rocks from the three sections is sug-gested by consistently high TiO2 ,K2O,incompatible trace elements and uniformly fractionated REE patterns typical of alkalic compositions,but antypical of CFB.Sr isotope data for ten Emei basalt samples(87Sr/86Sr=0.7066-0.7082)which show no correla-tion with Rb/Sr ratios (0.02-0.12) and Nd isotopes for two of the samples(143Nd/144Nd=0.51171-0.51174)are interpreted as being related to the mantle evolution.The primary magmas re-sponsible for all the three sequences have been modeled in terms of a uniformly metasomatized man-tle source.Trace element models support the derivation of the Emei and Tangfang primary magmas from 10-15 percent partial melting of spinel lherzolite,followed by fractional crystallization of olivive and clinopyroxene.The primary alkaline olivine basalts at Ertan are generated by 7-10 percent par-tial melting of a chemically equivalent source in the garnet-peridodite stability region.The assumed mantle composition is characterixzed by Rb=3.8-5.5 ppm,Sr=62-83ppm,Ba=45-64 ppm,La=3.8-5.6ppm,and Yb=0.46-0.57ppm.The proposed mechanism of regional mantle enrichment requires metasomatic stabilization of phlogopite which becomes depleted later during par-tial melting.Such enrichment is consistent with the models proposed for alkalic systems in which a large mantle diaper acts as the agent for upward

  12. Bald Friar Metabasalt and Kennett Square Amphibolite: Two Iapetan Ocean Floor Basalts

    Science.gov (United States)

    Smith, R.C., II

    2006-01-01

    The Bald Friar Metabasalt (BFM) and Kennett Square Amphibolite (KSA) are basaltic units found in the Piedmont of southeastern Pennsylvania. The BFM is also recognized in northern Maryland. Both are believed to represent fragments of the floor of the Iapetus Ocean, but are not known occur in direct association with one another. The BFM typically occurs as small fragments having typical stratigraphic thicknesses of 2.5 m, and composed of greenish, fine-grained chlorite-epidote-actinolite-albite metabasalt in ophiolite me??lange. One bed of pillow basalt has been found at the type locality, Bald Friar, Cecil County, Maryland. Even though outcrops of BFM are highly discontinuous, they have a remarkable chemical uniformity over a strike length of 143 km and appear to be equivalent to the Caldwell Group 1b metabasalt of the Thetford, Quebec, area. The BFM is typically associated with ultramafic fragments and may be affiliated with the Baltimore Mafic Complex (BMC), from which a baddeleyite date of 442 +/- 7 Ma (Silurian) has been obtained. The BFM is probably a back arc basin basalt (BABB). Pod and schlieren chromite compositions suggest an island arc environment for the BMC itself. The poorly defined, informal "Conowingo Creek metabasalt" of Lancaster County, Pennsylvania, occurs on the north margin of the BMC and appears to be a fore arc boninite. The BFM and associated ultramafic fragments serve as a field-mappable marker for the structural equivalent of the Baie Verte-Brompton line in southeastern Pennsylvania and northern Maryland. Steatization of the associated ultramafic fragments has produced zones of extremely low competence that facilitated and localized thrusts of presumed Silurian age and later Alleghanian folding. The KSA typically occurs as much larger bodies having lengths of 3 km and composed of dark, medium-grained hornblende-plagioclase-clinopyroxene gneiss. No ultramafic rocks or me??lange have been recognized with the KSA. In Pennsylvania, the KSA

  13. Impact of organic carbon on weathering and chemical denudation of granular basalt

    Science.gov (United States)

    Dontsova, Katerina; Zaharescu, Dragos; Henderson, Whitney; Verghese, Sarah; Perdrial, Nicolas; Hunt, Edward; Chorover, Jon

    2014-08-01

    Bench-scale experiments were conducted to determine rates and patterns of coupled organic matter infusion and weathering in a San Francisco volcanic field (Flagstaff, AZ) basalt sample under experimentally-modeled biotic and abiotic condition and to inform larger-scale collaborative studies at the landscape evolution observatory (LEO), Biosphere 2 (Tucson, AZ), where the same basaltic media is being used in a synthetic hillslope experiment. We postulated that mineral transformations depend significantly on the presence of organic carbon compounds including dissolved natural organic matter (DOM), with organic C simultaneously imprinting the chemical and mineralogical properties of primary and secondary solids undergoing incongruent dissolution. The present work reports on solute releases from Flagstaff basalt (FB) along laboratory-controlled gradients in DOM type and concentration. Loamy sand textured FB was subjected to flow-through, saturated column dissolution experiments using influent solutions with and without DOM compounds. Solutions included Ponderosa pine forest soil O-horizon extracts at three target concentrations: 7, 35, and 70 mg L-1 C, malic acid (MA) solutions at 7, 35, 70, and 140 mg L-1 C, and a control without DOM but having comparable inorganic solution composition. Chemical denudation rates for FB dissolution products were calculated from the concentration difference between outflow and inflow solutions. In addition, changes in the composition of the solid phase over the course of the experiment were determined using X-ray diffraction (XRD), X-ray fluorescence (XRF), and selective dissolution (SE). Column experiments supported dissolution rates derived from the literature and indicated a potentially strong effect of plant-derived organic ligands on mineral dissolution congruency and secondary phase precipitation. Both malic acid and DOM enhanced basalt dissolution, with malic acid having larger effect on per unit C basis. The largest relative

  14. Reactive transport models for mineral CO2 storage in basaltic rocks

    Science.gov (United States)

    Aradottir, E. S.; Sonnenthal, E. L.; Bjornsson, G.; Jonsson, H.

    2010-12-01

    CO2 mineral storage in basalts may provide a long lasting, thermodynamically stable and environmentally benign solution to reduce anthropogenic CO2 in the atmosphere. We present here development of reactive transport models of this process with focus on the CarbFix experiment at Hellisheidi geothermal power plant in Iceland. There, up to 2.2 tons/year of purified CO2 of volcanic origin will be dissolved in water and injected at intermediate depths (400-800 m) into relatively fresh basaltic lava. Plans call for a full-scale injection if the experiment is successful. Reactive transport modeling is an important factor in the CarbFix project, providing tools to predict and optimize long-term management of the injection site as well as to quantify the amount of CO2 that has the potential of being mineralized. TOUGHREACT and iTOUGH2 are used to develop reactive fluid flow models that simulate hydrology and mineral alteration associated with injecting dissolved CO2 into basalts. The mineral reactions database in TOUGHREACT has been revised and extended, providing an internally consistent database suitable for mineral reactions of interest for this study. A multiple interacting continua (MINC) dissolution model was developed to simulate the long and short-term dissolution of basaltic glass taking into account dissolution kinetics, leached layer formation and diffusion-limited dissolution rates. Our main focus has been on developing a three dimensional field model of the injection site at Hellisheidi. Hydrological parameters of the model were calibrated using iTOUGH2 to simulate tracer tests that have been ongoing since 2007. Modeling results indicate groundwater velocity in the reservoir to be significantly lower than expected. The slow groundwater velocity may necessitate increasing groundwater flow by producing downstream wells at low rates after CO2 injection has started. The three dimensional numerical model has proven to be a valuable tool in simulating different

  15. Stratigraphical framework of basaltic lavas in Torres Syncline main valley, southern Parana-Etendeka Volcanic Province

    Science.gov (United States)

    Rossetti, Lucas M.; Lima, Evandro F.; Waichel, Breno L.; Scherer, Claiton M.; Barreto, Carla J.

    2014-12-01

    The Paraná-Etendeka Volcanic Province records the volcanism of the Early Cretaceous that precedes the fragmentation of the South-Gondwana supercontinent. Traditionally, investigations of these rocks prioritized the acquisition of geochemical and isotopic data, considering the volcanic stack as a monotonous succession of tabular flows. Torres Syncline is a tectonic structure located in southern Brazil and where the Parana-Etendeka basalts are well preserved. This work provides a detailed analysis of lithofacies and facies architecture, integrated to petrographic and geochemical data. We identified seven distinct lithofacies grouped into four facies associations related to different flow morphologies. The basaltic lava flows in the area can be divided into two contrasting units: Unit I - pahoehoe flow fields; and Unit II - simple rubbly flows. The first unit is build up by innumerous pahoehoe lava flows that cover the sandstones of Botucatu Formation. These flows occur as sheet pahoehoe, compound pahoehoe, and ponded lavas morphologies. Compound lavas are olivine-phyric basalts with intergranular pyroxenes. In ponded lavas and cores of sheet flows coarse plagioclase-phyric basalts are common. The first pahoehoe lavas are more primitive with higher contents of MgO. The emplacement of compound pahoehoe flows is related to low volume eruptions, while sheet lavas were emplaced during sustained eruptions. In contrast, Unit II is formed by thick simple rubbly lavas, characterized by a massive core and a brecciated/rubbly top. Petrographically these flows are characterized by plagioclase-phyric to aphyric basalts with high density of plagioclase crystals in the matrix. Chemically they are more differentiated lavas, and the emplacement is related to sustained high effusion rate eruptions. Both units are low TiO2 and have geochemical characteristics of Gramado magma type. The Torres Syncline main valley has a similar evolution when compared to other Large Igneous Provinces

  16. New Petrologic and Geochemical Insights into Differentiation Processes Required to Produce the Lower Steens Basalt, Columbia River Basalt Province, SE Oregon

    Science.gov (United States)

    Moore, N. E.; Lytle, K.; Bohrson, W. A.; Grunder, A.

    2015-12-01

    The Steens Basalt (~16.7 Ma) of SE Oregon is the oldest member and contains the most mafic compositions of the Columbia River Flood Basalt (CRB) event. The lower Steens lavas are more mafic and incompatible element poor than upper Steens flows, which are less magnesian, mildly alkalic, richer in incompatible elements, and mainly basaltic andesites, much like the CRB proper. At Steens Mountain, the lower Steens are thickest and comprise 35-40 mainly compound flows with modest soil development between, suggesting a period of slower effusion rate transitioning to high effusion rates as represented by stratigraphically higher flows that make up the prominent cliffs of the range. Stronger soil development between the uppermost flows implies a waning effusion rate. Whole rock major element data define two distinct trends in the lower Steens; the first has increasing Al2O3 with decreasing MgO at relatively low FeO, whereas the second exhibits increasing Al2O3 with decreasing MgO until an inflection point (~8 wt.% MgO), at which both Al2O3 and MgO decrease. Plagioclase mode is not coupled with Al2O3. MELTS closed system fractionation models across a range of pressures cannot reproduce these trends, suggesting open-system processes were at work. Olivine is homogeneous in some flows (~Fo80-78), but heterogeneous in others (~Fo84-62). Fo range does not correlate with whole rock MgO; two different flows with >10 wt.% MgO have Fo85-70 and Fo84-82. Plagioclase composition is restricted within and between flows (~An75-60). All these data suggest lower Steens magmas underwent large amounts of crystal fractionation and recharge with modest assimilation. Some assimilation requires an aluminous contaminant other than simple plagioclase accumulation. During other periods, magma mixing must have been efficient. Magma Chamber Simulator modeling will provide quantitative estimates for the roles of fractionation, recharge and assimilation in the lower Steens magma system.

  17. Geochemical characteristics of Cretaceous basaltic rocks in South China and constraints on Pacific plate subduction

    Institute of Scientific and Technical Information of China (English)

    CHEN Weifeng; CHEN Peirong; XU Xisheng; ZHANG Min

    2005-01-01

    Middle-Late Cretaceous Basaltic rocks (85―110 Ma) are distributed in the contemporaneous downfaulted red basins and volcanic-sedimentary basins in South China (including Hunan, Jiangxi, Guangdong, Fujian, Zhejiang provinces). They are geographically divided into two groups delimited by Wuyishan Range, namely the west area basaltic rocks (WABs) distributing over the west of Wuyishan Range and the east area basaltic rocks (EABs) distributing over the east of Wuyishan Range, and observed having distinct geochemical and isotopic characters.WABs are characterized by relatively low in K2O (0.44%―3.17%), alkalis (K2O+Na2O= 3.27%―6.80%) and Al2O3 (13.08%―16.75%) contents, but high in MgO (5.13%―8.78%) and TiO2 (1.12%―3.35%) contents. WABs are similar to ocean-island basalts (OIB) or intraplate basalts on trace elements and isotopes: no negative Nb and Ta anomalies, relatively low (REE (74.66 μg/g―287.72 μg/g) and LaN/YbN (4.49―22.10), low (87Sr/86Sr)I (average ratio is 0.704679), high εNd(t) (-1.81―8.00). In contrast, EABs display relatively high in K2O (0.55%―4.86%), alkalis (K2O+Na2O=2.95%―7.55%) and Al2O3 (15.80%―21.10%) contents, but low in MgO (2.63%―6.28%) and TiO2 (1.19%―1.86%) contents, strong negative Nb and Ta anomalies, enrichment in LILE (K, Rb, Ba and Th), relatively high ∑REE (79.68 μg/g―327.61 μg/g) and LaN/YbN (5.25―26.37), high (87Sr/86Sr)I (average ratio is 0.707658) and negative εNd(t) (-8.50― -1.22), similar to that of IAB (island arc basalts) or CAB (continental arc basalts). Accordingly, WABs were probably generated under continental rifting tectonic setting related to asthenosphere upwelling, and hence their source was characterized by mixing between EMⅡ with DM. Source of EABs may be enriched lithoshperic mantle which had ever undergone the metasomatism of fluid/melt derived from the subducted Pacific plate.This indicates that subduction of a paleo-Pacific plate (Kula) beneath the Eurasian continent had

  18. Using chalcophile elements to constrain crustal contamination and xenolith-magma interaction in Cenozoic basalts of eastern China

    Science.gov (United States)

    Zeng, Gang; Huang, Xiao-Wen; Zhou, Mei-Fu; Chen, Li-Hui; Xu, Xi-Sheng

    2016-08-01

    Continental basalts have complicated petrogenetic processes, and their chemical compositions can be affected by multi-staged geological evolution. Compared to lithophile elements, chalcophile elements including Ni, platinum-group elements (PGEs) and Cu are sensitive to sulfide segregation and fractional crystallization during the evolution of mantle-derived magmas and can provide constraints on the genesis of continental basalts. Cenozoic intra-continental alkaline basalts in the Nanjing basaltic field, eastern China, include high-Ca and low-Ca varieties. All these basalts have poor PGE contents with Ir ranging from 0.016 ppb to 0.288 ppb and high Cu/Pd ratios from 0.7 × 105 to 4.7 × 105 (5.7 × 103 for DMM), indicating that they were derived from sulfide-saturated mantle sources with variable amounts of residual sulfide during melting or might undergo an early-sulfide segregation in the mantle. Relatively high Cu/Pd ratios along with high Pd concentrations for the high-Ca alkaline basalts indicate an additional removal of sulfide during magma ascent. Because these basalts have high, variable Pd/Ir ratios (2.8-16.8) with low Ce/Pb (9.9-19.7) ratios and εNd values (+ 3.6-+6.4), crustal contamination is proposed to be a potential process to induce the sulfide saturation and removal. Significantly increased Pd/Ir ratios for few high-Ca basalts can be explained by the fractionation of laurite or Ru-Os-Ir alloys with olivine or chromite. For low-Ca alkaline basalts, their PGE contents are well correlated with the MgO, Sc contents, incompatible element ratios (Lu/Hf, Na/Ti and Ca/Al) and Hf isotopes. Good correlations are also observed between Pd/Ir (or Rh/Ir) and Na/Ti (or Ca/Al) ratios. Variations of these elemental ratios and Hf isotopes is previously documented to be induced by the mixing of peridotite xenolith-released melts during ascent. Therefore, we suggest that such xenolith-magma interaction are also responsible for the variable PGE compositions of low

  19. Water content of primitive low-K tholeiitic basalt magma from Iwate Volcano, NE Japan arc: implications for differentiation mechanism of frontal-arc basalt magmas

    Science.gov (United States)

    Kuritani, Takeshi; Yoshida, Takeyoshi; Kimura, Jun-Ichi; Hirahara, Yuka; Takahashi, Toshiro

    2014-02-01

    The water content of low-K tholeiitic basalt magma from Iwate volcano, which is located on the volcanic front of the NE Japan arc, was estimated using multi-component thermodynamic models. The Iwate lavas are moderately porphyritic, consisting of ~8 vol.% olivine and ~20 vol.% plagioclase phenocrysts. The olivine and plagioclase phenocrysts show significant compositional variations, and the Mg# of olivine phenocrysts (Mg#78-85) correlates positively with the An content of coexisting plagioclase phenocrysts (An85-92). The olivine phenocrysts with Mg# > ~82 do not form crystal aggregates with plagioclase phenocrysts. It is inferred from these observations that the phenocrysts with variable compositions were primarily derived from mushy boundary layers along the walls of a magma chamber. By using thermodynamic calculations with the observed petrological features of the lavas, the water content of the Iwate magma was estimated to be 4-5 wt.%. The high water content of the magma supports the recent consensus that frontal-arc magmas are remarkably hydrous. Using the estimated water content of the Iwate magma, the water content and temperature of the source mantle were estimated. Given that the Iwate magma was derived from a primary magma solely by olivine fractionation, the water content and temperature were estimated to be ~0.7 wt.% and ~1,310 °C, respectively. Differentiation mechanisms of low-K frontal-arc basalt magmas were also examined by application of a thermodynamics-based mass balance model to the Iwate magma. It is suggested that magmatic differentiation proceeds primarily through fractionation of crystals from the main molten part of a magma chamber when it is located at ~200 MPa.

  20. Palaeoweathering characteristics of an intrabasaltic red bole of the Deccan Flood Basalts near Shrivardhan of western coast of India

    Indian Academy of Sciences (India)

    M R G Sayyed; R G Pardeshi; R Islam

    2014-10-01

    An intrabasaltic red bole horizon is studied for its weathering characteristics with respect to the underlying and overlying basalts. The study indicates that all the three units have been considerably weathered; the red bole unit, however shows some distinctive characteristics. The red boles show a higher cation exchange capacity (CEC) and lower sodium adsorption ratio (SAR) and organic carbon (OC) as compared to the weathered basalts. The lower values of Al2O3, TiO2 and Fe2O3(T) in red boles indicate their lesser weathering than the underlying and overlying basalts, which is further corroborated by the weathering intensity measured by the indices like chemical index of alteration (CIA) and statistical empirical index of chemical weathering (W). It is also evident that the red bole samples show more retention of original mafic and felsic components. While K2O exhibits an erratic behaviour, the MgO and CaO do not show much leaching in red boles. Lesser leaching and salinity in the red boles is indicated by the higher values of calcification and lower values of salinization. The SiO2-Al2O3-Fe2O3 plot indicates that red bole samples are close to the basalt field, while the weathered upper basalt is more kaolinized than the weathered lower basalt. These observations reveal that the post-formational weathering processes have least affected the original palaeoweathering characters of the red bole horizon and hence the intrabasaltic palaeosols (weathering horizons) can effectively be used to constrain the palaeoweathering and palaeoclimates during the continental flood basalt episodes in the geologic past.

  1. Results of USGS Workshop on CO2 Storage in Coals, Shales, Basalts, and Ultramafic Rocks

    Science.gov (United States)

    Jones, K.; Corum, M.; Blondes, M. S.

    2012-12-01

    Geologic storage of anthropogenic CO2 is one possible approach to help mitigate global climate change. The U.S. Geological Survey (USGS) is currently estimating the potential CO2 storage capacity of sandstones, limestones, and dolostones in major domestic sedimentary basins. Other "unconventional" lithologies—coals, organic-rich shales, basalts, and ultramafic rocks—are not currently included in the assessment, but could store significant additional CO2 by sorption and mineralization. In March 2012, the USGS held a workshop to support a possible future assessment of the capacity of unconventional rocks. Thirty-six participants from academia, industry, and government discussed 1) pilot projects, laboratory studies, and modeling of CO2 storage in unconventional rocks; 2) the feasibility of CO2 storage in these rocks; and 3) recommendations that could help build a USGS methodology to assess the CO2 storage capacity of these rocks, if such storage is feasible, and if this methodology is a USGS priority. Workshop participants recommended that the USGS proceed with developing separate methodologies to assess the storage potentials of coals and organic-rich shales. Other recommendations were 1) to assess all coals rather than only "unminable" coals, because minability depends on changeable economics and technology; 2) to require sealing formations above storage formations, thus reducing risk of leakage, even though sorbed CO2 is immobile; 3) to assess only formations deep enough for CO2 to be supercritical, allowing much greater storage efficiency; 4) to assess storage potential in tiers (3-10 and >10 g/L total dissolved solids in groundwater) based on CO2 injection restrictions from the U.S. Environmental Protection Agency; and 5) to establish vitrinite reflectance (0.5%) and total organic content (1%) minima for assessment of shales. Workshop participants recommended that the USGS also proceed with developing a methodology to assess potential CO2 storage in basalts

  2. Density and structure of basaltic magma under high pressure and high temperature

    Science.gov (United States)

    Sakamaki, T.; Ohtani, E.; Suzuki, A.; Terasaki, H.; Urakawa, S.; Katayama, Y.; Funakoshi, K.

    2008-12-01

    The density of magma is one of the important properties for discussing evolution of magma ocean at the early history of the planets and magmatic activity in the planetary mantle. We have measured the density of basaltic melt at high temperature and high pressure by X-ray absorption method. The experiments were carried out using a DIA-type cubic press at BL22XU of the SPring-8. X-ray absorption method is accurate method for the density measurement under desired pressure and temperature compared to the other methods. This method for density measurements was originally developed by Katayama et al. (1993). It is based on the Lambert-Beer"fs law. The sample was placed in a diamond capsule to calibrate the sample thickness and the X-ray absorption profile of the sample was measured by ion chambers. We succeeded in measuring the density of basaltic melt up to 4.6 GPa and up to 2000 K. We obtained the compression curve of basaltic melt by using the Birch-Murnaghan equation of state with a negative pressure derivative of bulk modulus (dK/dP). A negative dK/dP might be caused by the structural change of the silicate melts, although it is unlikely in crystals. The structure of magma is based on continuous three-dimensional networks of corner-sharing SiO4 and AlO4 tetrahedra, as being derived from a network of tetrahedrally coordinated Si and Al atoms each linked to four others through a shared O atom. The principal mechanisms of compression for silicate melts involve continuous changes in T-O-T bond angles and bond lengths. Silicate melts might undergo continuous and gradual changes in topology and cation coordinations. In order to further understand these changes and how they are affected by the microscopic structure, we have conducted the energy-dispersive X-ray diffraction to determine the structure of the basaltic melt up to 5 GPa. High pressure and high temperature X-ray diffraction experiments on basaltic melts were carried out by the energy dispersive method using

  3. Basaltic Magma-Water Interaction on Earth: Recognition Criteria To Aid Planetary Mapping on Mars (Invited)

    Science.gov (United States)

    Skilling, I. P.; Graettinger, A. H.; Mercurio, E.; McGarvie, D.; Edwards, B. R.

    2013-12-01

    The interaction of basaltic magma with frozen/liquid water or wet sediment is a very common process on Earth, resulting in a wide array of explosively and non-explosively generated products at the micron to kilometre scale. A variety of products and edifices on Mars have also been interpreted as having formed by such interaction, but with the exception of rootless cones, such interpretations are rarely unequivocal. This talk focuses on terrestrial process recognition criteria at a scale, orientation (vertical) and erosion level that is relevant to Mars geological mapping. In this context, we emphasise intrusions with peperite margins and wide hydrothermal haloes, steep margins of ice-contact lava flows, subaerial-subaqueous lava delta transitions, lava domains with distinctive water-cooled jointing, edifices that are dominated by slumped and rotated beds, and the presence of surrounding fluvial deposits and erosion. The most common products of magma-water interaction on Earth are subaqueously emplaced lava flows, which are dominated by pillow lavas. Though pillows are not easy to distinguish from subaerial pahoehoe toes at the resolution of most remote imagery, they are commonly associated with distinctively jointed lava domains, which are usually on a larger scale, including areas of water-cooled jointing (curvicolumnar, blocky etc), lava-filled tubes, which often display radial jointing, and steep talus deposits of joint-block breccia. Subaqueous basaltic lavas emplaced in an ice-confined environment may also display near-vertical ice-contact margins, draped by curtains of elongate pillows or cavities formed from melting of included ice-blocks. Subaerial lava flows that transition into water also develop large-scale foreset-bedding close to the angle of repose, which should be easily visible, at least in oblique imagery. As the majority of the Martian surface is more deeply eroded than most areas of terrestrial basaltic volcanism, it is important to discuss

  4. Alteration of oceanic basalts leading to self-reversal. A XMCD study

    International Nuclear Information System (INIS)

    Complete text of publication follows. In oceanic basalts, self-reversal can be produced during extreme low-temperature oxidation of titanomagnetite (Fe3-xTixO4) by ionic reordering. This is an important question to investigate, because paleomagnetism rests on the fact that the TRM acquired by a rock when cooled through its Curie temperature in the Earth's magnetic field is oriented in a direction parallel to that of the field, but this alteration causes the thermoremanent magnetization (TRM) to orient antiparallel to the external field. Ionic reordering leads to Neel N-type magnetism, which occurs in single-phase ferrimagnetic minerals where the sign of the total magnetization can change because of changes in the ionic distributions of the two antiparallel sublattices with temperature or as a result of chemical transformations. Titanomaghemites showing N-type reversal were found in submarine basalts recovered during ODP Leg 192 (Doubrovine and Tarduno, EPSL, 2004; Carvallo et al., GJI, 2004). In order to better understand the mechanism of self-reversal, we carried out X-ray magnetic circular dichroism (XMCD) at Fe K-edge at room temperature and low-temperature for oceanic basalts displaying N-type behavior. XMCD is an element-, site-, and symmetry-selective technique and allows determining the site occupancies of Fe in several iron oxides and the magnetization associated with these ions. The N-type reversal was evidenced by the fact that the XMCD spectrum at 30 K is a mirror image of the XMCD spectrum at room temperature. For comparison, we also measured XMCD spectra on pure magnetite, maghemite and titanomagnetite. Preliminary work has shown that ligand-field multiplet calculations of XMCD at Fe K-edge can be carried out on iron oxides and help identify the contributions of the different elements in our measured XMCD spectra.

  5. Origin of Columbia River flood basalt controlled by propagating rupture of the Farallon slab.

    Science.gov (United States)

    Liu, Lijun; Stegman, Dave R

    2012-02-15

    The origin of the Steens-Columbia River (SCR) flood basalts, which is presumed to be the onset of Yellowstone volcanism, has remained controversial, with the proposed conceptual models involving either a mantle plume or back-arc processes. Recent tomographic inversions based on the USArray data reveal unprecedented detail of upper-mantle structures of the western USA and tightly constrain geodynamic models simulating Farallon subduction, which has been proposed to influence the Yellowstone volcanism. Here we show that the best-fitting geodynamic model depicts an episode of slab tearing about 17 million years ago under eastern Oregon, where an associated sub-slab asthenospheric upwelling thermally erodes the Farallon slab, leading to formation of a slab gap at shallow depth. Driven by a gradient of dynamic pressure, the tear ruptured quickly north and south and within about two million years covering a distance of around 900 kilometres along all of eastern Oregon and northern Nevada. This tear would be consistent with the occurrence of major volcanic dikes during the SCR-Northern Nevada Rift flood basalt event both in space and time. The model predicts a petrogenetic sequence for the flood basalt with sources of melt starting from the base of the slab, at first remelting oceanic lithosphere and then evolving upwards, ending with remelting of oceanic crust. Such a progression helps to reconcile the existing controversies on the interpretation of SCR geochemistry and the involvement of the putative Yellowstone plume. Our study suggests a new mechanism for the formation of large igneous provinces.

  6. Using conservative and reactive tracers to monitor and verify permanent carbon dioxide storage in basalt

    Science.gov (United States)

    Hall, J. L.; Matter, J. M.; Stute, M.; Bausch, A.

    2012-12-01

    Carbon capture and storage methods can assist in reducing greenhouse gas emissions and tackling global warming. Long term, thermodynamically stable storage of carbon dioxide through mineral carbonation is one such method, in which divalent cations released from rocks such as basalt react with CO2 to form carbonates. [1] Currently used monitoring techniques for geologic CO2 storage fail to detect dissolved or chemically transformed CO2. We use conservative and reactive tracers in an ongoing pilot CO2 injection project in Iceland to characterize subsurface CO2 transport and in situ CO2-water-rock reactions. The Carbfix project in Iceland is a field scale pilot project where CO2 and H2S emissions from the Hellisheidi geothermal power plant are dissolved in groundwater and injected into a permeable basalt formation at ~500 m depth below surface. Trifluormethylsulphur pentafluoride (SF5CF3) and sulfurhexafluoride (SF6) are added as conservative tracers to the injected CO2 for the purpose of characterizing the migration of the injected CO2 in the basaltic storage reservoir. Furthermore, the injected CO2 is labeled with radiocarbon (14C) to monitor the extent of CO2-water-rock reactions and mineral carbonation. Initial results from the monitoring wells show a fast dispersion and reaction of the injected CO2. Breakthrough curves of SF6, SF5CF3 and 14C can be observed in nearby monitoring wells from samples collected and analyzed by gas chromatography or accelerator mass spectrometry, respectively. Changes in the ratios between reactive and conservative tracers demonstrate that mixing and CO2-water-rock reactions are occurring. The use of conservative and reactive tracers contributes to the monitoring, verification and accounting information needed to establish the extent and security of carbon storage and be helpful in furthering the public acceptance of geological CO2 storage via mineral carbonation as a contribution to reducing carbon dioxide emissions. [1] Oelkers, et

  7. Re-Os Isotopes Distinguish Crust vs. Slab Inputs to Northern Cascade Arc Basalts

    Science.gov (United States)

    Mullen, E.; Gannoun, A.; Nauret, F.; Schiano, P.; Weis, D.

    2015-12-01

    Delineating the relative contributions of mantle, slab, and crust to arc magmas is particularly challenging in the Cascades where the continental crust is juvenile and contrasts little with magmas in traditional radiogenic isotope systems (Sr-Nd-Hf-Pb). The Re-Os isotope system offers a sensitive technique for evaluating these contributions because even young crust has significantly higher Os ratios than the mantle. We analyzed Re-Os isotope ratios in 33 primitive basalts from 9 volcanic centers of the northern Cascade Arc (Garibaldi Volcanic Belt, GVB). Although GVB basalts have mantle-like Sr-Pb-Nd-Hf ratios (Mullen & Weis, 2015, EPSL), the range in 187Os/188Os is very large (0.13-0.99) with [Os] of Cinder Cone/Mt. Garibaldi, Salal Glacier, Mt. Meager, Indian Pass/Glacier Peak) has low Os isotopic ratios (0.13-0.19), only slightly elevated relative to global mantle wedge peridotites (≤0.16), indicating minimal crustal contamination. Group 1 samples lie on Os-Sr isotope mixing curves indicating variable sediment input to the mantle. Os ratios of Group 2 basalts (Silverthrone, Bridge River, Elaho, Cheakamus, Mt. Baker, Glacier Peak) extend to extremely high values, up to 0.99, and lie on different Os-Sr mixing curves indicating addition of a crustal contaminant. Sr-Nd-Hf-Pb isotopic ratios cannot be used to identify this crustal input because Groups 1 and 2 are identical in these isotope systems. Interaction with a mafic underplate from older Cenozoic or accreted Mesozoic arcs is likely, and Re-Os analyses of basement samples (in progress) will provide a test of this hypothesis. This study reveals that most primitive magmas in the Cascades have suffered variable crustal contamination, but only the Re-Os isotope system has the potential to delineate the extent of this involvement.

  8. Basalt of Summit Creek: Eocene Magmatism Associated with Farallon Slab Break Off

    Science.gov (United States)

    Kant, L. B.; Tepper, J. H.; Eddy, M. P.

    2015-12-01

    In the Pacific Northwest the Early-Middle Eocene was a time of widespread magmatism and tectonic reorganization that included accretion of the Siletzia terrane, Challis volcanism, and establishment of the modern Cascade arc. Although individual events are well documented our knowledge of the underlying tectonic framework is incomplete. To better understand the tectonic changes that occurred during this interval we studied the ~48 Ma Basalt of Summit Creek (BSC), a 1500m section of lavas located south of Mt. Rainier that erupted during the critical time period between the docking of Siletzia and the initiation of the modern Cascade arc. The BSC consists mainly of tholeiitic basalts (wt. % SiO2 = 45.54-63.45, Mg# = 0.68-0.30) with EMORB traits (La/YbN = 1.2-5.9; 206Pb/204Pb = 19.005-19.102; 207Pb/204Pb = 15.538-15.593; 208Pb/204Pb = 38.560-38.714). These lavas lack arc signatures (e.g., HFSE depletions) but overlap in elemental and isotopic composition with oceanic basalts of the Crescent Formation (part of Siletzia) located ~100 km to the west. We suggest that emplacement of lavas that lack arc traits in what was the forearc was a response to break off of the Farallon slab, which occurred as a result of the accretion of Siletzia at ~49 Ma (Wells et al., 2014). Break off opened a gap in the subducted slab, allowing upwelling and subsequent decompression melting. BSC lavas are consistent in age, location and composition with this model. After break off subduction resumed outboard of Siletzia, initiating the Cascade arc. Thus, BSC provides evidence of Farallon slab break off and furthers our understanding of the tectonic transition from widespread magmatism of the Early-Middle Eocene to the Cascade arc.

  9. Preliminary K/Ar geochronology of the Crater Basalt volcanic field (CBVF, northern Patagonia

    Directory of Open Access Journals (Sweden)

    Z. Pécskay

    2007-11-01

    Full Text Available The Crater Basalt volcanic field is one of the Quaternary intraplate basaltic fields in northern Patagonia. A systematic geological, volcanological and geochronological study of CBVF indicates a multistage history of eruptions of basaltic volcanoes. K/Ar dating, using whole rock samples shows that the measured analytical ages are fully consistent with the available stratigraphic control. The radiometric ages fall into three distinct, internally consistent age groups, which give evidence that there were at least three major episodes of volcanic activity, at about 1.0 Ma, 0.6 Ma and 0.3 Ma ago. The age differences appear to be just significant, even although less than 10 % radiogenic argon was found in the isotope analysis of whole rock samples.El campo volcánico del Basalto Cráter (CVBC constituye uno de los campos basálticos cuaternarios de intraplaca de la Patagonia septentrional. El estudio sistemático de la geología, volcanología y geocronología del CVBC muestra una historia eruptiva multiepisódica de volcanes basálticos. Las dataciones K-Ar realizadas sobre roca total son coherentes con el control estratigráfico. Las edades obtenidas para el Basalto Cráter permiten distinguir tres episodios diferentes, pero individualmente coherentes, de actividad volcánica, ocurridos hace ~1,0 Ma; 0,6 Ma y 0,3 Ma. Las diferencias de edad parecen ser significativas, aún cuando el contenido de argón radiogénico determinado en los análisis de roca total resultó menor al 10 %.

  10. Magmatic inclusions in rhyolites, contaminated basalts, and compositional zonation beneath the Coso volcanic field, California

    Science.gov (United States)

    Bacon, C.R.; Metz, J.

    1984-01-01

    Basaltic lava flows and high-silica rhyolite domes form the Pleistocene part of the Coso volcanic field in southeastern California. The distribution of vents maps the areal zonation inferred for the upper parts of the Coso magmatic system. Subalkalic basalts (Coso volcanic field contain sparse andesitic inclusions (55-61% SiO2). Pillow-like forms, intricate commingling and local diffusive mixing of andesite and rhyolite at contacts, concentric vesicle distribution, and crystal morphologies indicative of undercooling show that inclusions were incorporated in their rhyolitic hosts as blobs of magma. Inclusions were probably dispersed throughout small volumes of rhyolitic magma by convective (mechanical) mixing. Inclusion magma was formed by mixing (hybridization) at the interface between basaltic and rhyolitic magmas that coexisted in vertically zoned igneous systems. Relict phenocrysts and the bulk compositions of inclusions suggest that silicic endmembers were less differentiated than erupted high-silica rhyolite. Changes in inferred endmembers of magma mixtures with time suggest that the steepness of chemical gradients near the silicic/mafic interface in the zoned reservoir may have decreased as the system matured, although a high-silica rhyolitic cap persisted. The Coso example is an extreme case of large thermal and compositional contrast between inclusion and host magmas; lesser differences between intermediate composition magmas and inclusions lead to undercooling phenomena that suggest smaller ??T. Vertical compositional zonation in magma chambers has been documented through study of products of voluminous pyroclastic eruptions. Magmatic inclusions in volcanic rocks provide evidence for compositional zonation and mixing processes in igneous systems when only lava is erupted. ?? 1984 Springer-Verlag.

  11. Microbial colonization of basaltic glasses in hydrothermal organic-rich sediments at Guaymas Basin

    Directory of Open Access Journals (Sweden)

    Nolwenn eCallac

    2013-08-01

    Full Text Available Oceanic basalts host diverse microbial communities with various metabolisms involved in C, N, S and Fe biogeochemical cycles which may contribute to mineral and glass alteration processes at, and below the seafloor. In order to study the microbial colonization on basaltic glasses and their potential biotic/abiotic weathering products, two colonization modules called AISICS (Autonomous In Situ Instrumented Colonization System were deployed in hydrothermal deep-sea sediments at the Guaymas Basin for 8 days and 22 days. Each AISICS module contained 18 colonizers (including sterile controls filled with basaltic glasses of contrasting composition. Chemical analyses of ambient fluids sampled through the colonizers showed a greater contribution of hydrothermal fluids (maximum temperature 57.6°C for the module deployed during the longer time period. For each colonizer, the phylogenetic diversity and metabolic function of bacterial and archaeal communities were explored using a molecular approach by cloning and sequencing. Results showed large microbial diversity in all colonizers. The bacterial distribution is primarily linked to the deployment duration, as well as the depth for the short deployment time module. Some 16s rRNA sequences form a new cluster of Epsilonproteobacteria. Within the Archaea the retrieved diversity could not be linked to either duration, depth or substrata. However, mcrA gene sequences belonging to the ANME-1 mcrA-guaymas cluster were found sometimes associated with their putative sulfate-reducers syntrophs depending on the colonizers. Although no specific glass alteration texture was identified, nano-crystals of barite and pyrite were observed in close association with organic matter, suggesting a possible biological mediation. This study gives new insights into the colonization steps of volcanic rock substrates and the capability of microbial communities to exploit new environmental conditions.

  12. Physical response of backfill materials to mineralogical changes in a basalt environment

    International Nuclear Information System (INIS)

    Backfill materials surrounding waste canisters in a high-level nuclear waste repository are capable of ensuring very slow flow of groundwater past the canisters, and thereby increase the safety of the repository. However, in the design of a repository it will be necessary to allow for possible changes in the backfill. In this experimental program, changes in permeability, swelling behavior, and plastic behavior of the backfill at the temperatures, pressures, and radiation levels expected in a repository are investigated. The emphasis is on investigation of relevant phenomena and evaluation of experimental procedures for use in licensing procedures. The permeability of a slightly compacted sand-clay mixture containing 25% bentonite, with a dry bulk density of 1.59 g/cm3, was determined to be 0.9 x 10-18 m2 in liquid water at 25 and 2000C, respectively. This is sufficiently low to demonstrate the potential effectiveness of proposed materials. In practice, fractures in the host rock may form short circuits around the backfill, so an even lower flow rate is probable. However, alteration by any of several mechanisms is expected to change the properties of the backfill. Crushed basalt plus bentonite is a leading candidate backfill for a basalt repository. Experiments show that basalt reacts with groundwater vapor or with liquid groundwater producing smectites, zeolites, silica, and other products that may be either beneficial or detrimental to the long-term performance of the backfill. Concentration of groundwater salts in the backfill by evaporation would cause immediate, but possibly reversible, reduction of the swelling abaility of bentonite. Moreover, under some circumstances, gamma radiolysis of moist air in the backfill could produce up to 0.5 mole of nitric acid or ammonia per liter of pore space. 27 references, 7 figures, 4 tables

  13. Study on stacking sequence on the flexural properties of basalt/carbon/epoxy hybrid composites using test and finite element analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kim, S. H.; Lee, J. I.; Rhee, K. Y. [Kyung Hee University, Yongin (Korea, Republic of); Choi, C. R. [ELSOLTEC Inc., Yongin (Korea, Republic of)

    2015-05-15

    Basalt fiber is widely used in various industries and several studies have been carried out to understand the mechanical behavior of basalt fiber reinforced composites. However, few studies have been made to specifically investigate the mechanical properties of basalt/carbon hybrid composites. In this study, the effect of stacking sequence on the flexural properties of carbon/basalt/epoxy hybrid composites was investigated in order to verify the reliability of this composite model. Two types of carbon/basalt/epoxy hybrid composites with a sandwich form were fabricated: basalt skin-carbon core (BSCC) composites and carbon skin-basalt core (CSBC) composites. After fabrication flexural tests and finite element method (FEM) were conducted. FEM results of flexural analysis are compared with experimental results. A FEA analysis model has been successfully developed in order to predict flexural behavior of basalt/carbon/epoxy hybrid composites. The simulation using the FEA model produces a similar flexural strength to that obtained from the experiment. Therefore, the developed FEA model in general will be highly useful for the prediction of stacking sequence of basalt/carbon/ epoxy hybrid composites for several industrial applications.

  14. Age and Geochemical Features of Dredged Basalts from Offshore SW Taiwan: The Coincidence of Intra-Plate Magmatism with the Spreading South China Sea

    Directory of Open Access Journals (Sweden)

    Kuo-Lung Wang

    2012-01-01

    Full Text Available This study reports age and geochemical analyses of basaltic rocks dredged from volcanic seamounts offshore SW Taiwan. 40Ar/39Ar dating results of these rocks show them to be of the early Miocene age of ~22 - 21 Ma. They are evolved alkali basalts that show OIB-type geochemical features similar to post-spreading seamount basalts (14 - 3.5 Ma in the South China Sea (SCS and Miocene intraplate basalts on the Penghu Islands (16 - 8 Ma and NW Taiwan (23 - 9 Ma. Their Sr-Nd-Pb isotope data plot within the range of the SCS seamount basalts that show an EM2-like component in the mantle source. The age and overall geochemical characteristics of the dredged basalts are comparable to those of the Kungkuan basalts, NW Taiwan and Baolai basalts, SW Taiwan, suggesting an extensive alkali basaltic volcanism along the southeastern Eurasian continental margin during the early Miocene that resulted from regional lithospheric extension in association with seafloor spreading in the South China Sea.

  15. Chopped basalt fibres: A new perspective in reinforcing poly(lactic acid to produce injection moulded engineering composites from renewable and natural resources

    Directory of Open Access Journals (Sweden)

    P. Tamas

    2013-02-01

    Full Text Available This paper focuses on the reinforcing of Poly(lactic acid with chopped basalt fibres by using silane treated and untreated basalt fibres. Composite materials with 5–10–15–20–30–40 wt% basalt fibre contents were prepared from silane sized basalt fibres using extrusion, and injection moulding, while composites with 5–10–15 wt% basalt fibre contents were also prepared by using untreated basalt fibres as control. The properties of the injection moulded composites were extensively examined by using quasi-static (tensile, three-point bending and dynamic mechanical tests (notched and unnotched Charpy impact tests, dynamic mechanical analysis (DMA, differential scanning calorimetry (DSC, heat deflection temperature (HDT analysis, dimensional stability test, as well as melt flow index (MFI analysis and scanning electron microscopic (SEM observations. It was found that silane treated chopped basalt fibres are much more effective in reinforcing Poly(lactic acid than natural fibres; although basalt fibres are not biodegradable but they are still considered as natural (can be found in nature in the form of volcanic rocks and biologically inert. It is demonstrated in this paper that by using basalt fibre reinforcement, a renewable and natural resource based composite can be produced by injection moulding with excellent mechanical properties suitable even for engineering applications. Finally it was shown that by using adequate drying of the materials, composites with higher mechanical properties can be achieved compared to literature data.

  16. The interactions of the bacterium Cupriavidus metallidurans CH34 with basalt rock, on Earth and in Space

    Science.gov (United States)

    Byloos, Bo; Van Houdt, Rob; Leys, Natalie; Ilyin, Vyacheslav; Nicholson, Natasha; Childers, Delma; Cockell, Charles; Boon, Nico

    2016-07-01

    Microbe-mineral interactions have become of interest for space exploration as microorganisms can biomine elements from extra-terrestrial materials, which could be used as nutrients in a life support system. This research is aimed at identifying the molecular mechanisms behind the interaction of Cupriavidus metallidurans CH34 with basalt, a lunar-type rock, and determining the influence of space flight conditions on this interaction. Survival and physiology of CH34 was monitored, with and without basalt, in mineral water over several months by flow cytometry, plate counts, ICP-MS, microscopy and proteomics. To study the influence of space conditions, a flight experiment on board the Russian FOTON-M4 capsule was performed. The results obtained from from water survival experiments on ground showed that CH34 was able to survive in mineral water, in the absence and presence of basalt, for several months. The total cell concentration remained stable but the cultivable fraction dropped to 10%, indicating a transition to a more dormant state. In the presence of basalt, this transition was less pronounced and cultivability was enhanced. In addition, with basalt, CH34 attached to the rock surface and formed a biofilm. The space flight experiment indicated more viable and cultivable cells compared to the ground experiment, both in the absence and presence of basalt, indicating a positive effect of space flight on survival. Chemical analysis indicated that basalt leaches out elements which may contribute to a positive effect of basalt on survival. Basalt may thus enhance survival and viability of CH34 both in ground and space flight experimental conditions. This study hopefully can contribute to a better understanding of microbe-mineral interactions, opening the door to future applications, in space, and on Earth. Acknowledgments: This work is supported by the European Space Agency (ESA-PRODEX) and the Belgian Science Policy (Belspo) through the BIOROCK project. We thank Kai

  17. Rare-earth element geochemistry and the origin of andesites and basalts of the Taupo Volcanic Zone, New Zealand

    Science.gov (United States)

    Cole, J.W.; Cashman, K.V.; Rankin, P.C.

    1983-01-01

    Two types of basalt (a high-Al basalt associated with the rhyolitic centres north of Taupo and a "low-Al" basalt erupted from Red Crater, Tongariro Volcanic Centre) and five types of andesite (labradorite andesite, labradorite-pyroxene andesite, hornblende andesite, pyroxene low-Si andesite and olivine andesite/low-Si andesite) occur in the Taupo Volcanic Zone (TVZ), North Island, New Zealand. Rare-earth abundances for both basalts and andesites are particularly enriched in light rare-earth elements. High-Al basalts are more enriched than the "low-Al" basalt and have values comparable to the andesites. Labradorite and labradorite-pyroxene andesites all have negative Eu anomalies and hornblende andesites all have negative Ce anomalies. The former is probably due to changing plagioclase composition during fractionation and the latter to late-stage hydration of the magma. Least-squares mixing models indicate that neither high-Al nor "low-Al" basalts are likely sources for labradorite/labradorite-pyroxene andesites. High-Al basalts are considered to result from fractionation of olivine and clinopyroxene from a garnet-free peridotite at the top of the mantle wedge. Labradorite/labradorite-pyroxene andesites are mainly associated with an older NW-trending arc. The source is likely to be garnet-free but it is not certain whether the andesites result from partial melting of the top of the subducting plate or a hydrated lower portion of the mantle wedge. Pyroxene low-Si andesites probably result from cumulation of pyroxene and calcic plagioclase within labradorite-pyroxene andesites, and hornblende andesites by late-stage hydration of labradorite-pyroxene andesite magma. Olivine andesites, low-Si andesites and "low-Al" basalts are related to the NNE-trending Taupo-Hikurangi arc structure. Although the initial source material is different for these lavas they have probably undergone a similar history to the labradorite/labradorite-pyroxene andesites. All lavas show evidence

  18. Petrogenesis and origin of modern Ethiopian rift basalts: Constraints from isotope and trace element geochemistry

    Science.gov (United States)

    Ayalew, D.; Jung, S.; Romer, R. L.; Kersten, F.; Pfänder, J. A.; Garbe-Schönberg, D.

    2016-08-01

    The source of continental rift-related basalts and their relation to rifting processes is a continuous matter of debate. We present major and trace element and Sr, Nd, Hf and Pb isotope data for axial rift basalts from eight volcanic centres (Ayelu, Hertali, Dofan, Fantale, Kone, Bosetti and Gedemsa, from NE to SW) in Afar and Main Ethiopian Rift (MER) to assess their source regions and their genetic relationships. These lavas have geochemical characteristics, i.e., a peak at Ba, Nb and troughs at K and Rb in primitive mantle-normalised multielement diagrams, which are consistent with predominant melting of an amphibole-bearing lithospheric mantle. However, the isotopic compositions for these lavas are heterogeneous (87Sr/86Sr = 0.70354-0.70431, 143Nd/144Nd = 0.51280-0.51294, 176Hf/177Hf = 0.28301-0.28315, 206Pb/204Pb = 18.48-19.31, 207Pb/204Pb = 15.53-15.62, 208Pb/204Pb = 38.61-39.06) and require various mantle reservoirs with distinctive isotopic signatures. The range of isotopic compositions requires the involvement of three distinct source components from the asthenospheric and veined lithospheric mantle. Progressive rifting leads to lithosperic thinning and upwelling of hot asthenospheric mantle, which induces melting of the veined lithospheric mantle. The trace element characteristics of the lavas are dominated by the vein material, which has a higher trace element content than the surrounding mantle. The isotopic composition of the vein material, however, is not very different from the ambient mantle, giving rise of apparent uncoupling of trace element and isotope constraints for the melt source. The uprising basaltic liquids in part inherit a lithospheric trace element signature, while their isotopic compositions are mostly unaffected due to short residence times within the lithosphere in context with progressive rifting and lithospheric thinning. Thus, the geochemical and isotope data are consistent with a multi-component source prevailing beneath the Afar

  19. CarbFix I: Rapid CO2 mineralization in basalt for permanent carbon storage

    Science.gov (United States)

    Matter, J. M.; Stute, M.; Snæbjörnsdóttir, S.; Gíslason, S. R.; Oelkers, E. H.; Sigfússon, B.; Gunnarsson, I.; Aradottir, E. S.; Gunnlaugsson, E.; Broecker, W. S.

    2015-12-01

    Carbon dioxide mineralization via CO2-fluid-rock reactions provides the most permanent solution for geologic CO2 storage. Basalts, onshore or offshore, have the potential to store million metric tons of CO2 as (Ca, Mg, Fe) carbonates [1, 2]. However, as of today it was unclear how fast CO2 is converted to carbonate minerals in-situ in a basalt storage reservoir. The CarbFix I project in Iceland was designed to verify in-situ CO2 mineralization in basaltic rocks. Two injection tests were performed at the CarbFix I pilot injection site near the Hellisheidi geothermal power plant in 2012. 175 tons of pure CO2 and 73 tons of a CO2+H2S mixture were injection from January to March 2012 and in June 2013, respectively. The gases were injected fully dissolved in groundwater into a permeable basalt formation between 400 and 800 m depth using a novel CO2 injection system. Using conservative (SF6, SF5CF3) and reactive (14C) tracers, we quantitatively monitor and detect dissolved and chemically transformed CO2. Tracer breakthrough curves obtained from the first monitoring well indicate that the injected solution arrived in a fast short pulse and a late broad peak. Ratios of 14C/SF6, 14C/SF5CF3 or DIC/SF6 and DIC/SF5CF3 are significantly lower in the monitoring well compared to the injection well, indicating that the injected dissolved CO2 reacted. Mass balance calculations using the tracer data reveal that >95% of the injected CO2 has been mineralized over a period of two years. Evidence of carbonate precipitation has been found in core samples that were collected from the storage reservoir using wireline core drilling as well as in and on the submersible pump in the monitoring well. Results from the core analysis will be presented with emphasis on the CO2 mineralization. [1] McGrail et al. (2006) JGR 111, B12201; [2] Goldberg et al. (2008) PNAS 105(29), 9920-9925.

  20. (21238) 1995 WV7: A New Basaltic Asteroid Outside the 3:1 Mean Motion Resonance

    CERN Document Server

    Hammergren, M; Puckett, A; Hammergren, Mark; Gyuk, Geza; Puckett, Andrew

    2006-01-01

    We report visible to near-infrared spectroscopy and spectrophotometry of asteroid (21238) 1995 WV7 that reveal the presence of deep absorption bands indicating a V taxonomic type with an apparently basaltic surface composition. Since this asteroid is on the other side of the 3:1 mean motion resonance from Vesta, and because the required ejection velocity from Vesta is in excess of 1.6 km s-1, we conclude that 21238 represents a sample of a differentiated body dynamically unrelated to Vesta.

  1. Mobilization of manganese by basalt associated Mn(II)-oxidizing bacteria from the Indian Ridge System.

    Science.gov (United States)

    Sujith, P P; Mourya, B S; Krishnamurthi, S; Meena, R M; Loka Bharathi, P A

    2014-01-01

    The Indian Ridge System basalt bearing Mn-oxide coatings had todorokite as the major and birnesite as the minor mineral. We posit that microorganisms associated with these basalts participate in the oxidation of Mn and contribute to mineral deposition. We also hypothesized that, the Mn-oxidizing microbes may respond reversibly to pulses of fresh organic carbon introduced into the water column by mobilizing the Mn in Mn-oxides. To test these two hypotheses, we enumerated the number of Mn-oxidizers and -reducers and carried out studies on the mobilization of Mn by microbial communities associated with basalt. In medium containing 100 μM Mn(2+), 10(3) colony forming units (CFU) were recovered with undetectable number of reducers on Mn-oxide amended medium, suggesting that the community was more oxidative. Experiments were then conducted with basalt fragments at 4±2 °C in the presence 'G(+)' and absence 'G(-)' of glucose (0.1%). Controls included set-ups, some of which were poisoned with 15 mM azide and the others of which were heat-killed. The mobilization of Mn in the presence of glucose was 1.76 μg g(-1) d(-1) and in the absence, it was 0.17 μg g(-1) d(-1) after 150 d. Mn mobilization with and without added glucose was 13 and 4 times greater than the corresponding azide treated controls. However, rates in 'G(+)' were 16 times and 'G(-)' 24 times more than the respective heat killed controls. The corresponding total counts in the presence of added glucose increased from 1.63×10(6) to 6.71×10(7) cells g(-1) and from 1.41×10(7) to 3.52×10(7) cells g(-1) in its absence. Thus, the addition of glucose as a proxy for organic carbon changed the community's response from Mn(II)-oxidizing to Mn(IV)-reducing activity. The results confirm the participation of Mn oxidizing bacteria in the mobilization of Mn. Identification of culturable bacteria by 16S rRNA gene analysis showed taxonomic affiliations to Bacillus, Exiguobacterium, Staphylococcus, Brevibacterium and

  2. Mobilization of manganese by basalt associated Mn(II)-oxidizing bacteria from the Indian Ridge System.

    Science.gov (United States)

    Sujith, P P; Mourya, B S; Krishnamurthi, S; Meena, R M; Loka Bharathi, P A

    2014-01-01

    The Indian Ridge System basalt bearing Mn-oxide coatings had todorokite as the major and birnesite as the minor mineral. We posit that microorganisms associated with these basalts participate in the oxidation of Mn and contribute to mineral deposition. We also hypothesized that, the Mn-oxidizing microbes may respond reversibly to pulses of fresh organic carbon introduced into the water column by mobilizing the Mn in Mn-oxides. To test these two hypotheses, we enumerated the number of Mn-oxidizers and -reducers and carried out studies on the mobilization of Mn by microbial communities associated with basalt. In medium containing 100 μM Mn(2+), 10(3) colony forming units (CFU) were recovered with undetectable number of reducers on Mn-oxide amended medium, suggesting that the community was more oxidative. Experiments were then conducted with basalt fragments at 4±2 °C in the presence 'G(+)' and absence 'G(-)' of glucose (0.1%). Controls included set-ups, some of which were poisoned with 15 mM azide and the others of which were heat-killed. The mobilization of Mn in the presence of glucose was 1.76 μg g(-1) d(-1) and in the absence, it was 0.17 μg g(-1) d(-1) after 150 d. Mn mobilization with and without added glucose was 13 and 4 times greater than the corresponding azide treated controls. However, rates in 'G(+)' were 16 times and 'G(-)' 24 times more than the respective heat killed controls. The corresponding total counts in the presence of added glucose increased from 1.63×10(6) to 6.71×10(7) cells g(-1) and from 1.41×10(7) to 3.52×10(7) cells g(-1) in its absence. Thus, the addition of glucose as a proxy for organic carbon changed the community's response from Mn(II)-oxidizing to Mn(IV)-reducing activity. The results confirm the participation of Mn oxidizing bacteria in the mobilization of Mn. Identification of culturable bacteria by 16S rRNA gene analysis showed taxonomic affiliations to Bacillus, Exiguobacterium, Staphylococcus, Brevibacterium and

  3. Bacterial mineralization patterns in basaltic aquifers: implications for possible life in martian meteorite ALH84001

    Science.gov (United States)

    Thomas-Keprta, K. L.; McKay, D. S.; Wentworth, S. J.; Stevens, T. O.; Taunton, A. E.; Allen, C. C.; Coleman, A.; Gibson, E. K. Jr; Romanek, C. S.

    1998-01-01

    To explore the formation and preservation of biogenic features in igneous rocks, we have examined the organisms in experimental basaltic microcosms using scanning and transmission electron microscopy. Four types of microorganisms were recognized on the basis of size, morphology, and chemical composition. Some of the organisms mineralized rapidly, whereas others show no evidence of mineralization. Many mineralized cells are hollow and do not contain evidence of microstructure. Filaments, either attached or no longer attached to organisms, are common. Unattached filaments are mineralized and are most likely bacterial appendages (e.g., prosthecae). Features similar in size and morphology to unattached, mineralized filaments are recognized in martian meteorite ALH84001.

  4. Volatiles in Submarine HIMU Basalts from the Austral Islands, South Pacific

    Science.gov (United States)

    Nichols, A. R.; Hanyu, T.; Shimizu, K.; Dosso, L.

    2014-12-01

    Submarine basalts have been collected from the slopes of Rurutu and Tubuai in the Austral Islands, South Pacific with the manned submersible Shinkai 6500. Previous work on the bulk radiogenic isotope and trace element chemistry of these samples suggests that the basalts were generated from a HIMU reservoir derived from an ancient subducted slab that was entrained and mixed with the depleted asthenospheric mantle. Olivines and glasses from the submarine basalts show lower 3He/4He than MORB, similar to subaerial basalts from these islands. Sixteen glass chips from the same submarine samples have now undergone in-situ analysis for major elements (including S and Cl) by EPMA, trace elements by LA-ICP-MS, H2O and CO2 by FTIR, and bulk volatile analysis (S, Cl, F) by ion chromatography combined with pyrohydrolysis. H2O ranges from 0.62-2.44 wt%, while CO2 is below detection (<20 ppm). S measured by EPMA ranges from 612-1889 ppm and by bulk analysis from 582-1301 ppm and, with the exception of one sample, concentrations agree well. Cl measured by EPMA ranges from 151-538 ppm, and by bulk analysis from 188-980 ppm. The higher values suggest that the bulk samples may be contaminated by seawater; otherwise Cl correlates strongly with incompatible elements. F measured in the bulk samples ranges from 221-1243 ppm. S correlates positively with FeO and Cu, but not with incompatible elements, suggesting sulfide saturation. While the highest H2O contents may reflect late-stage hydration and are oversaturated at the depth of collection, the low H2O contents (11 samples with 0.62-0.96 wt%) are undersaturated, and there is a positive correlation between the H2O contents of all chips and their incompatible element concentrations. This suggests that H2O/Ce and Cl/Ce filtered for shallow level processes may reflect source compositions, providing constraints on volatiles in the sources of Rurutu and Tubuai, and indications about the efficiency of subduction-related volatile-loss in the

  5. Identification of a basaltic component on the Martian surface from Thermal Emission Spectrometer data

    Science.gov (United States)

    Christensen, Philip R.; Bandfield, Joshua L.; Smith, Michael D.; Hamilton, Victoria E.; Clark, Roger N.

    2000-04-01

    The Mars Global Surveyor Thermal Emission Spectrometer (TES) instrument collected 4.8×106 spectra of Mars during the initial aerobraking and science-phasing periods of the mission (September 14, 1997, through April 29, 1998). Two previously developed atmosphere-removal models were applied to data from Cimmeria Terra (25°S, 213°W). The surface spectra derived for these two models agree well, indicating that the surface and atmosphere emission can be separated and that the exact atmosphere-removal model used has little effect on the derived surface composition. The Cimmeria spectra do not match terrestrial high-silica igneous rocks (granite and rhyolite), ultramafic igneous rocks, limestone, or quartz- and clay-rich sandstone and siltstone. A particulate (sand-sized) sample of terrestrial flood basalt does provide an excellent match in both spectral shape and band depth to the Cimmeria spectrum over the entire TES spectral range. No unusual particle size effects are required to account for the observed spectral shape and depth. The implied grain size is consistent with the thermal inertia and albedo of this region, which indicate a sand-sized surface with little dust. The identification of basalt is consistent with previous indications of pyroxene and basalt-like compositions from visible/near-infrared and thermal-infrared spectral measurements. A linear spectral deconvolution model was applied to both surface-only Cimmeria spectra using a library of 60 minerals to determine the composition and abundance of the component minerals. Plagioclase feldspar (45; 53%) and clinopyroxene (26; 19%) were positively identified above an estimated detection threshold of 10-15% for these minerals. The TES observations provide the first identification of feldspars on Mars. The best fit to the Mars data includes only clinopyroxene compositions; no orthopyroxene compositions are required to match the Cimmeria spectra. Olivine (12% 12%) and sheet silicate (15% 11%) were identified

  6. Uranium Series Chronology of the Late Pleistocene Basalt from the Longgang Volcanoes, Jilin Province

    Institute of Scientific and Technical Information of China (English)

    YU Fusheng; HAN Song; MA Zhibang; XIE Ruijie

    2005-01-01

    The Longgang volcanic cluster located in Jilin Province belongs to one of the active volcanic regions in northeast China, and has been active in modem times. In view of the multiple eruptions in history, it is very important to determine the age of each eruption for evaluating the volcanic hazards. Two alkaline basalt samples taken from Dayizishan and Diaoshuihu were analyzed with the U-series component dating after magnetic separation. The ages of the two samples are (71±9) ka and (106±13) ka B.P., respectively. These data indicate that there existed intensive eruption activities during the late Pleistocene.

  7. Investigating lava-substrate interactions through flow experiments with syrup, wax, and molten basalt

    Science.gov (United States)

    Rumpf, M. E.; Lev, E.

    2015-12-01

    Among the many factors influencing the complex process of lava flow emplacement, the interaction with the substrate onto which flow is emplaced plays a central role. Lava flows are rarely emplaced onto smooth or regular surfaces. For example, at Kīlauea Volcano, Hawai'i, lava flows regularly flow over solid rock, vegetation, basaltic or silica sand, and man-made materials, including asphalt and concrete. In situ studies of lava-substrate interactions are inherently difficult, and often dangerous, to carry-out, requiring the design of controllable laboratory experiments. We investigate the effects of substrate grain size, cohesion, and roughness on flow mobility and morphology through a series of flow experiments using analog materials and molten basalt. We have developed a series of experiments that allow for adjustable substrate parameters and analyze their effects on lava flow emplacement. The first set of experiments are performed at the Fluids Mechanics Laboratory at the Lamont-Doherty Earth Observatory and focus on two analog materials: polyethylene glycol (PEG), a commercially available wax, and corn syrup. The fluids were each extruded onto a series of scaled substrate beds to replicate the emplacement of lava in a natural environment. Preliminary experiments demonstrated that irregular topography, particularly topography with a height amplitude similar to that of the flow itself, can affect flow morphology, width, and velocity by acting as local barriers or culverts to the fluid. This is expected from observations of fluid flow in natural environments. A follow-up set of experiments will be conducted in Fall 2015 at the Syracuse University (SU) Lava Project Lab. In this set, we will pour molten basalt directly onto a series of substrates representing natural environments found on the Earth and other rocky bodies in the Solar System. These experiments will allow for analysis of the effects of basaltic composition and high temperatures on lava-substrate heat

  8. Geochemical evolution of Pliocene-Recent post-subduction alkalic basalts from Seal Nunataks, Antarctic Peninsula

    International Nuclear Information System (INIS)

    Following more than 200 Ma of subduction of Pacific oceanic crust beneath the west coast of the Antarctic Peninsula, subduction ceased by a series of ridge crest-trench collisions. However, magmatism continued after the cessation of subduction with basaltic rocks of the intraplate alkalic association being erupted from centres scattered along the whole length of the peninsula. In the northeast, at Seal Nunataks, a suite of intraplate basalts ranging in composition from tholeiite to alkali basalt was erupted less than 4 Ma ago, almost synchronously with the cessation of subduction in that area (4-6 Ma). LREE-enrichment [(La/Yb)n 4.7-11.5] but consistency of HREE abundances for all the basalts suggest they were generated by partial melting in the garnet stability field of the mantle. A number of trace-element ratios [e.g. Zr/Nb (4.9-8.4), Hf/Ta (1.5-3.3), Sr/Nb (15-26), Ti/Nb (390-800)] are likely to have been fractionated during partial melting/melt extraction, although they do exhibit some correlation with isotope ratios, suggesting variations in these ratios may have been controlled by both partial melting and source heterogeneity. However, Th/Ta (0.87-2.31), La/Th (5.4-10.5) and K/Rb (275-1330) ratios also exhibit considerable variations within the suite and show strong correlations with 87Sr/86Sr ratios (0.7028-0.7033). These trace-element-isotope covariations are explained by a model involving mixing of a LILE-, 87Sr-depleted end-member, broadly similar to the source for non-Dupal OIB and N-type MORB, and upper-mantle material with high LILE/HFSE and 87Sr/86Sr ratios. This high-LILE/HFSE, high-87Sr component may represent mantle material which was enriched during the previous 200 Ma of subduction-related magmatism within the Antarctic Peninsula. Post-subduction high-Mg andesites (''bajaites''), which are associated with the cessation of subduction long other continental margins, are apparently absent within the Antarctic Peninsula. (orig./WB)

  9. Age and Duration of the Paraná-Etendeka Flood Basalts and Related Plumbing System

    Science.gov (United States)

    Renne, P. R.

    2015-12-01

    The Paraná-Etendeka Igneous Province (PEIP) comprises a large volume sequence of continental flood basalts presently distributed assymetrically between South America (mainly southern Brazil but also parts of Uruguay, Paraguay and Argentina) and southwestern Africa (Namibia, Angola), following opening of the South Atlantic ocean. The PEIP is dominated by tholeiitic basalts to basaltic andesites, with subordinate silicic rocks spanning the dacite-trachyte-rhyolite fields, which occur as lava flows, sills and dike swarms as well as intrusive complexes closely related to the eruptive rocks. The PEIP has long been subject of 40Ar/39Ar geochronologic and paleomagnetic studies which led to conclude its rapid formation near the Hauterivian stage (~133 Ma) with onward progression to Barremian from the intrusive equivalents exposed northwards. Two decades after publication of the first 40Ar/39Ar ages for the Paraná flood basalts (Renne et al., 1992) we report here an updated study of the age and duration of this magmatic event. We calibrated a set of sixty published and new results to the calibration of Renne et al. (2011), which indicates an inception age of the volcanism now estimated at 135 ± 1 Ma, before the initiation of sea floor spreading. Lava extrusion progressed over ~2 Ma from south to north. A protracted duration of ~10 Ma inferred by Stewart et al. (1996) for PEIP volcanism is clearly incorrect, as also concluded by Thiede and Vasconcelos (2010). Low-Ti mafic magmas prevailed during the earlier stages followed over time by enhanced dominance of their silicic equivalents. Eruption of the high-Ti (mafic and silicic) magmas initiated simultaneously ~0.5 m.y. later, continuing up to ~133 Ma with injection of the Ponta Grossa dyke swarm. Despite several paleomagnetic polarity intervals recorded by the lava piles in the southern (> 27°S) and central (latitudes of ~24-27°S) domains of the Brazilian PEIP, the paleomagnetic data show small dispersion in agreement

  10. GEOCHEMISTRY OF BASALT AND XENOLITHS AND ITS DEEP PROCESS IN DAOXIAN COUNTY,HUNAN PROVINCE

    Institute of Scientific and Technical Information of China (English)

    KONG; Hua; XI; Xiao-shuang; JIN; Zhen-min; HUANG; De-zhi

    2001-01-01

    Deep xenolith are important samples for us to know composition and nature of the deep crust.There are many new volcanos which can all kinds of xenoliths such as a lower crustal graulite,and upper mantle-derived peridolite and lherzolite.In eastern China,there occured many deep xenoliths in Mesozoic-Cenzoic alkaline basalt.Besides these,some small volcanos eruptions were founded in southern Hunan province,which age is about 132-151 Ma.……

  11. Thorium and uranium variations in Apollo 17 basalts, and K-U systematics

    Science.gov (United States)

    Laul, J. C.; Fruchter, J. S.

    1976-01-01

    It is found that Apollo 11 low-K and in particular Apollo 17 mare basalts show a wide range of Th/U ratios unlike other rocks; such variations cannot be explained by near surface crystal fractionation. A two-stage fractional crystallization-partial melting model involving a clinopyroxene cumulate as the major phase can explain the variations in Th/U ratios. Due to the Sm-Nd systematics constraint, several source cumulates are invoked to explain the observed Th/U continuum.

  12. Extracting accurate temperatures of molten basalts from non-contact thermal infrared radiance data

    Science.gov (United States)

    Fontanella, N. R.; Ramsey, M. S.; Lee, R.

    2013-12-01

    The eruptive and emplacement temperature of a lava flow relates important information on parameters such as the composition, rheology, and emplacement processes. It can also serve as a critical input into flow cooling and propagation models used for hazard prediction. One of the most common ways to determine temperatures of active lava flows is to use non-contact thermal infrared (TIR) measurements, either from ground-based radiometers and cameras or air and space-based remote sensing instruments. These temperature measurements assume a fixed value for the lava emissivity in order to solve the Planck Equation for temperature. The research presented here examines the possibility of variable emissivity in a material's molten state and the effect it has on deriving accurate surface temperature. Emplacement of a pahoehoe lava lobe at Kilauea volcano, Hawaii was captured with high spatial resolution/high frame rate TIR video in order to study this phenomenon. The data show the appearance of molten lava at a breakout point until it cools to form a glassy crust that begins to fold. Emissivity was adjusted sequentially along linear transects from a starting value of 1.0 to lower values until the TIR temperature matched the known temperature measured with a thermocouple. Below an emissivity of ~0.89, temperatures of the molten lava rose above the known lava temperature. This value suggests a decrease in emissivity with a change of state and is likely due to changes in the atomic bond structure of the melt. We have also recently completed the first ever calibrated laboratory-based emissivity measurements of molten basalts, and these high spectral resolution data confirm the field-based estimates. In contrast to rhyolites, basalts appear to display a less dramatic change between their glassy and molten spectra due to their higher melting and glass transition temperatures and the quick formation time of the crust. Therefore, the change in emissivity for molten rhyolite could

  13. Annotated bibliography of the geology of the Columbia Plateau (Columbia River Basalt) and adjacent areas of Oregon

    International Nuclear Information System (INIS)

    This bibliography containing approximately 2000 entries was prepared by the Oregon Department of Geology and Mineral Industries under Subcontract SA-913 with Rockwell Hanford Operations' Basalt Waste Isolation Program. The objective of the Basalt Waste Isolation Program is to determine the feasibility of storing nuclear waste within the Columbia River Basalt Group. Under the geologic portion of this program, the stratigraphic, structural, tectonic, seismic, and hydrologic aspects of the Columbia Plateau are being examined. Other aspects of the Basalt Waste Isolation Program are concerned with systems integration, engineered barriers, engineering testing, and construction of a near-surface test facility. The area covered in this bibliography comprises that area north of 43030' latitude and east of the Willamette Meridian, which is located just west of Portland. The bibliographic entries are presented in two forms. The first is an alphabetized listing of all articles dealing with the geology of the Columbia Plateau (Columbia River Basalt) and adjacent areas of Oregon. The second form consists of an alphabetized listing of the entries subdivided under fourteen categories

  14. Isotope systematics of a juvenile intraplate volcano: Pb, Nd, and srisotope ratios of basalts from Loihi Seamount, Hawaii

    Energy Technology Data Exchange (ETDEWEB)

    Staudigel, H. (Columbia Univ., Palisades, NY (USA). Lamont-Doherty Geological Observatory; Scripps Institution of Oceanography, La Jolla, CA (USA)); Zindler, A.; Leslie, T. (Columbia Univ., Palisades, NY (USA). Lamont-Doherty Geological Observatory); Hart, S.R.; Chen, C.Y. (Massachusetts Inst. of Tech., Cambridge (USA). Dept. of Earth and Planetary Sciences); Clague, D. (Geological Survey, Menlo Park, CA (USA))

    1984-07-01

    Sr, Nd, and Pb isotope ratios for a representative suite of 15 basanites, alkali basalts, transitional basalts and tholeiites from Loihi Seamount, Hawaii, display unusually large variations for a single volcano, but lie within known ranges for Hawaiian basalts. Nd isotope ratios in alkali basalts show the largest relative variation (0.51291 - 0.51305), and include the nearly constant tholeiite value (approx.= 0.51297). Pb isotope ratios show similarly large ranges for tholeiites and alkali basalts and continue Tatsumoto's (31) 'Loa' trend towards higher /sup 206/Pb//sup 204/Pb, ratios, resulting in a substantial overlap with the 'Kea' trend. /sup 206/Pb//sup 204/Pb ratios for Loihi and other volcanoes along the Loa and Kea trends (31) are observed to correlate with the age of the underlying lithosphere suggesting lithosphere involvement in the formation of Hawaiian tholeiites. Loihi lavas display no correlation of Nd, Sr, or Pb isotope ratios with major element compositions or eruptive age, in contrast with observations of some other Hawaiian volcanoes. Isotope data for Loihi, as well as average values for Hawaiian volcanoes, are not adequately explained by previously proposed two-end-member models; new models for the origin and the development of Hawaiian volcanoes must include mixing of at least three geochemically distinct source regions and allow for the involvement of heterogeneous oceanic lithosphere.

  15. Annotated bibliography of the geology of the Columbia Plateau (Columbia River Basalt) and adjacent areas of Oregon

    Energy Technology Data Exchange (ETDEWEB)

    Bela, J.

    1979-01-01

    This bibliography containing approximately 2000 entries was prepared by the Oregon Department of Geology and Mineral Industries under Subcontract SA-913 with Rockwell Hanford Operations' Basalt Waste Isolation Program. The objective of the Basalt Waste Isolation Program is to determine the feasibility of storing nuclear waste within the Columbia River Basalt Group. Under the geologic portion of this program, the stratigraphic, structural, tectonic, seismic, and hydrologic aspects of the Columbia Plateau are being examined. Other aspects of the Basalt Waste Isolation Program are concerned with systems integration, engineered barriers, engineering testing, and construction of a near-surface test facility. The area covered in this bibliography comprises that area north of 43/sup 0/30' latitude and east of the Willamette Meridian, which is located just west of Portland. The bibliographic entries are presented in two forms. The first is an alphabetized listing of all articles dealing with the geology of the Columbia Plateau (Columbia River Basalt) and adjacent areas of Oregon. The second form consists of an alphabetized listing of the entries subdivided under fourteen categories. (RWR)

  16. Effective Carbon Dioxide Photoreduction over Metals (Fe-, Co-, Ni-, and Cu- Incorporated TiO2/Basalt Fiber Films

    Directory of Open Access Journals (Sweden)

    Jeong Yeon Do

    2016-01-01

    Full Text Available Mineralogical basalt fibers as a complementary adsorbent were introduced to improve the adsorption of CO2 over the surfaces of photocatalysts. TiO2 photocatalysts (M-TiO2 incorporated with 5.0 mol.% 3d-transition metals (Fe, Co, Ni, and Cu were prepared using a solvothermal method and mixed with basalt fibers for applications to CO2 photoreduction. The resulting 5.0 mol.% M-TiO2 powders were characterized by X-ray diffraction, scanning electron microscopy, ultraviolet-visible spectroscopy, photoluminescence, Brunauer, Emmett, and Teller surface area, and CO2-temperature-programmed desorption. A paste composed of two materials was coated and fixed on a Pyrex plate by a thermal treatment. The 5.0 mol.% M-TiO2/basalt fiber films increased the adsorption of CO2 significantly, indicating superior photocatalytic behavior compared to pure TiO2 and basalt fiber films, and produced 158~360 μmol gcat-1 L−1 CH4 gases after an 8 h reaction. In particular, the best performance was observed over the 5.0 mol.% Co-TiO2/basalt fiber film. These results were attributed to the effective CO2 gas adsorption and inhibition of photogenerated electron-hole pair recombination.

  17. STUDIES ON SURFACE CHARACTERIZATION AND ECOMATERIAL SHEET DEGRADATION OF BASALT FIBERS BY PLASMA TREATMENTS AND WOOD FIBERS

    Institute of Scientific and Technical Information of China (English)

    GuangjianWang; YajieGuo; DekuShang; linnaHu; ZhenhuaGuo; KailiangZhang

    2004-01-01

    plasma surtace modification (Argon: Hydrogen=0.6:0.4) of basalt fibers was mvestigated and the element contents of basalt and wood fibers were determined by X-ray energy dispersion spectroscope (EDS). configuration of basalt fibers was described by means of confocal Laser Raman microRaman spectrometer and Fourier transform infrared spectroscopy. And the morphology of fiber surface was studied with scanning electron microscope (SEM). The modified samples were characterized by X-ray photoelectron spectra (XPS). The results showed that the roughness of basalt fibers was increased with the increase of exposure time of plasma. At the same time the wettability and surface characteristics such as active groups of NH2, OH were improved as well. Basalt fibers were of good chemical stability, better mechanism intension and thermo-stability etc. They mainly consist of [SiO4]4-, [Si2O6]4-,[Si2O5]2-. Further experiments demostrated that they were degraded into edaphic matrix after use. Therefore, they were environmentally friendly.

  18. Geochemical Characteristics and Genesis of Late Cretaceous to Paleogene Basalts in the Tuyon Basin, South Tianshan Mountains

    Institute of Scientific and Technical Information of China (English)

    WANG Yanbin; WANG Yong; LIU Xun; FU Derong; XIAO Xuchang; QI Longshui

    2001-01-01

    The Tianshan Mountains is believed to be a typical intercontinental mountain belt, which is formed during the tectonic amalgamation of the Tarim and Tianshan blocks and the Siberian carton in Late Carboniferous-Permian period. A series of basaltic extrusive and intrusive units emplaced primarily into the Late Cretaceous-Paleogene sedimentary rocks in the Tuyon basin and its adjacent area, the South Tianshan Mountains. Geochemical data of the basalts show low Sr and Pb isotopic values and relative high Nd values (87Sr/86Sr = 0.703554 ~ 0.703884; 143Nd/144Nd = 0.512838 ~ 0.512904;206pb/204pb = 18.0063 ~ 18.4720; 207pb/204pb = 15.5060; 208Pb/204P b= 37.8072~37.9290). The data of major elements, trace elements and rare earth elements of the basalts indicate that these basaltic rocks are similar to those beneath the Hawaiian Islands. In the Tuyon basin and its adjacent areas, some Cenozoic alkaline basaltic magmatism may be related to the Cenozoic activity of mantle plume.

  19. Secondary Sulfate Mineralization and Basaltic Chemistry of Craters of the Moon National Monument, Idaho: Potential Martian Analog

    Energy Technology Data Exchange (ETDEWEB)

    C. Doc Richardson; Nancy W. Hinman; Lindsay J. McHenry; J. Michelle Kotler; Jill R. Scott

    2012-05-01

    Secondary deposits associated with the basaltic caves of Craters of the Moon National Monument (COM) in southern Idaho were examined using X-ray powder diffraction, X-ray fluorescence spectrometry, Fourier transform infrared spectrometry, and Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS). The secondary mineral assemblages are dominated by Na-sulfate minerals (thenardite, mirabilite) with a small fraction of the deposits containing minor concentrations of Na-carbonate minerals. The assemblages are found as white, efflorescent deposits in small cavities along the cave walls and ceilings and as localized mounds on the cave floors. Formation of the deposits is likely due to direct and indirect physiochemical leaching of meteoritic water through the overlying basalts. Whole rock data from the overlying basaltic flows are characterized by their extremely high iron concentrations, making them good analogs for martian basalts. Understanding the physiochemical pathways leading to secondary mineralization at COM is also important because lava tubes and basaltic caves are present on Mars. The ability of FTICR-MS to consistently and accurately identify mineral species within these heterogeneous mineral assemblages proves its validity as a valuable technique for the direct fingerprinting of mineral species by deductive reasoning or by comparison with reference spectra.

  20. Effect of Chopped Basalt Fibers on the Mechanical Properties and Microstructure of High Performance Fiber Reinforced Concrete

    Directory of Open Access Journals (Sweden)

    Tehmina Ayub

    2014-01-01

    Full Text Available This paper presents the mechanical properties and the microstructure of the high performance fiber reinforced concrete (HPFRC containing up to 3% volume fraction of chopped Basalt fibers. Three types of the concrete were prepared, out of which, the first type was prepared by utilizing 100% cement content. The other two types of the concrete were prepared by replacing 10% cement content with silica fume and the locally produced metakaolin. Using each concrete type, four mixes were prepared in which Basalt fibers were added in the range of 0–3%; that is, total twelve mixes of the HPFRC concrete were prepared. From each of the twelve concrete mixes, total twelve specimens were cast to determine the mechanical properties of the HPFRC including compressive strength (cube and cylinder, splitting tensile strength, and the flexural strength. In this way, a total of 108 specimens were cast and tested in this study. Test results showed that the addition of the Basalt fibers significantly increased the tensile splitting strength and the flexural strength of the HPFRC, while there was slight improvement in the compressive strength with the addition of Basalt fibers. The microstructure of HPFRC was examined to determine the interfacial transition zone (ITZ between the aggregates and the paste by using field emission scanning electron microscope (FESEM, which showed the improvement of the ITZ due to the addition of the Basalt fibers.

  1. Nitrogen stimulates the growth of subsurface basalt-associated microorganisms at the western flank of the Mid-Atlantic Ridge

    Directory of Open Access Journals (Sweden)

    Xinxu eZhang

    2016-05-01

    Full Text Available Oceanic crust constitutes the largest aquifer system on Earth, and microbial activity in this environment has been inferred from various geochemical analyses. However, empirical documentation of microbial activity from subsurface basalts is still lacking, particularly in the cool (<25 °C regions of the crust, where are assumed to harbor active iron-oxidizing microbial communities. To test this hypothesis, we report the enrichment and isolation of crust-associated microorganisms from North Pond, a site of relatively young and cold basaltic basement on the western flank of the Mid-Atlantic Ridge that was sampled during Expedition 336 of the Integrated Ocean Drilling Program. Enrichment experiments with different carbon (bicarbonate, acetate, methane and nitrogen (nitrate and ammonium sources revealed significant cell growth (one magnitude higher cell abundance, higher intracellular DNA content, and increased Fe3+/ΣFe ratios only when nitrogen substrates were added. Furthermore, a Marinobacter strain with neutrophilic iron-oxidizing capabilities was isolated from the basalt. This work reveals that basalt-associated microorganisms at North Pond had the potential for activity and that microbial growth could be stimulated by in vitro nitrogen addition. Furthermore, iron oxidation is supported as an important process for microbial communities in subsurface basalts from young and cool ridge flank basement.

  2. Nitrogen Stimulates the Growth of Subsurface Basalt-associated Microorganisms at the Western Flank of the Mid-Atlantic Ridge.

    Science.gov (United States)

    Zhang, Xinxu; Fang, Jing; Bach, Wolfgang; Edwards, Katrina J; Orcutt, Beth N; Wang, Fengping

    2016-01-01

    Oceanic crust constitutes the largest aquifer system on Earth, and microbial activity in this environment has been inferred from various geochemical analyses. However, empirical documentation of microbial activity from subsurface basalts is still lacking, particularly in the cool (crust, where are assumed to harbor active iron-oxidizing microbial communities. To test this hypothesis, we report the enrichment and isolation of crust-associated microorganisms from North Pond, a site of relatively young and cold basaltic basement on the western flank of the Mid-Atlantic Ridge that was sampled during Expedition 336 of the Integrated Ocean Drilling Program. Enrichment experiments with different carbon (bicarbonate, acetate, methane) and nitrogen (nitrate and ammonium) sources revealed significant cell growth (one magnitude higher cell abundance), higher intracellular DNA content, and increased Fe(3+)/ΣFe ratios only when nitrogen substrates were added. Furthermore, a Marinobacter strain with neutrophilic iron-oxidizing capabilities was isolated from the basalt. This work reveals that basalt-associated microorganisms at North Pond had the potential for activity and that microbial growth could be stimulated by in vitro nitrogen addition. Furthermore, iron oxidation is supported as an important process for microbial communities in subsurface basalts from young and cool ridge flank basement.

  3. Identification of Columbia River basalt flows from deep cores in the Pasco Basin based on trace element abundances

    Energy Technology Data Exchange (ETDEWEB)

    Fruchter, J.S.; Rancitelli, L.A.

    1976-03-31

    Samples of basalt from three deep core holes drilled in the Pasco Basin, Washington (DDH-3, DH-4, DH-5) were analyzed by instrumental neutron activation (INAA) for up to fifteen trace and major elements. These analyses were used to assign each basalt flow to one of a series of previously defined chemical types of the Columbia River Basalt Group. All of the flows except the two flows at the bottom of well DDH-3 were clearly assignable to one of the defined chemical types. These two flows apparently represent new, as yet undefined chemical types. Average values and standard deviations for compositions of each of the chemical types found in the three wells are presented along with two-element variation diagrams for the geochemically important pair La-Cr, La-Fe, La-Th and La-Sc. The assignment of the flows to known chemical types accomplished in this study was very helpful in relating the basalts in the core holes to stratigraphically defined basalt flows in surface sections. A correlation diagram relating the flows in the core holes to one another on the basis of chemical type is presented.

  4. Geographical Tendencies of Trace Element Contents in Soils Derived from Gramite,Basalt and Limestone of Eastern China

    Institute of Scientific and Technical Information of China (English)

    CHENJING-SHENG; PANMAO; 等

    1993-01-01

    92 soil samples were collected from granite,basalt and limestone areas of eastern China and determined for 13 trace element contents.The geographical tendencies of and factors affecting trace element contents in soils were studied.The sequences of soil trace element contents (especially the transitional elements in the 4period) were:basalt soils> limestone soils> granite soils.The contents of trace elements in soils of granite areas and basalt areas showed great inheritance of trace element contents from the relevant parent rocks.The contents of trace elements in limestones were very low,but they became very high in limestone soils.Trace element contents of soils derived from limestone and basalt increased significantly from north to south,these tendencies were similar to the tendency of ferric oxide contents in soils.There were differences of contents of trace elements bound to ferric oxide in different kinds of parent material and in different types of soil.The correlations between the contents of trace elements and the contents of ferric oxide were better in basalt soils than in granite soils.

  5. Fractionation products of basaltic komatiite magmas at lower crustal pressures: implications for genesis of silicic magmas in the Archean

    Science.gov (United States)

    Mandler, B. E.; Grove, T. L.

    2015-12-01

    Hypotheses for the origin of crustal silicic magmas include both partial melting of basalts and fractional crystallization of mantle-derived melts[1]. Both are recognized as important processes in modern environments. When it comes to Archean rocks, however, partial melting hypotheses dominate the literature. Tonalite-trondhjemite-granodiorite (TTG)-type silicic magmas, ubiquitous in the Archean, are widely thought to be produced by partial melting of subducted, delaminated or otherwise deeply buried hydrated basalts[2]. The potential for a fractional crystallization origin for TTG-type magmas remains largely unexplored. To rectify this asymmetry in approaches to modern vs. ancient rocks, we have performed experiments at high pressures and temperatures to closely simulate fractional crystallization of a basaltic komatiite magma in the lowermost crust. These represent the first experimental determinations of the fractionation products of komatiite-type magmas at elevated pressures. The aim is to test the possibility of a genetic link between basaltic komatiites and TTGs, which are both magmas found predominantly in Archean terranes and less so in modern environments. We will present the 12-kbar fractionation paths of both Al-depleted and Al-undepleted basaltic komatiite magmas, and discuss their implications for the relative importance of magmatic fractionation vs. partial melting in producing more evolved, silicic magmas in the Archean. [1] Annen et al., J. Petrol., 47, 505-539, 2006. [2] Moyen J-F. & Martin H., Lithos, 148, 312-336, 2012.

  6. Trace Element Geochemistry of Tertiary Continental Alkali Basalts from the Liuhe—Yizheng Area,Jiangsu Province,China

    Institute of Scientific and Technical Information of China (English)

    支霞臣

    1991-01-01

    Reported in this paper are the chemical compositions and trace element (REE,Ba,Rb,Sr,Nb,Zr,Ni,Cr,V,Ga,Y,Sc,Zn,Cu,etc)abundances of Tertiary continental alkali basalts from the Liube-yizheng area,Jiangsu Province,China.The olivine basalt,alkali olivine basalt and basanite are all derived from evolved melts which were once af-fected by different degrees of fractional crystallization of olivine and clinopyroxene(1:2)under high pres-sures.The initial melts were derived from the garnet lherzolite-type mantle source through low-degree par-tial melting.The mantle source has been affected by recent mantle-enrichment events(e.g.mantle metasomatism),resulting in incompatible trace element enrichment and long-term depletion of radiogenic isotopic compositions of Sr and Nd.

  7. Noble gases in submarine pillow basalt glasses from Loihi and Kilauea, Hawaii: A solar component in the Earth

    Science.gov (United States)

    Honda, M.; McDougall, I.; Patterson, D.B.; Doulgeris, A.; Clague, D.A.

    1993-01-01

    Noble gas elemental and isotopic abundances have been analysed in twenty-two samples of basaltic glass dredged from the submarine flanks of two currently active Hawaiian volcanoes, Loihi Seamount and Kilauea. Neon isotopic ratios are enriched in 20Ne and 21Ne by as much as 16% with respect to atmospheric ratios. All the Hawaiian basalt glass samples show relatively high 3He 4He ratios. The high 20Ne 22Ne values in some of the Hawaiian samples, together with correlations between neon and helium systematics, suggest the presence of a solar component in the source regions of the Hawaiian mantle plume. The solar hypothesis for the Earth's primordial noble gas composition can account for helium and neon isotopic ratios observed in basaltic glasses from both plume and spreading systems, in fluids in continental hydrothermal systems, in CO2 well gases, and in ancient diamonds. These results provide new insights into the origin and evolution of the Earth's atmosphere. ?? 1993.

  8. Petrography and geochemistry of basaltic rocks from the Conrad fracture zone on the America-Antarctica Ridge

    Science.gov (United States)

    le Roex, Anton P.; Dick, Henry J. B.

    1981-06-01

    Intrusive and extrusive basaltic rocks have been dredged from the Conrad fracture zone (transecting the slow-spreading America-Antarctica Ridge). The majority of rocks recovered are holocrystalline with the dominant mineral assemblage being plagioclase plus clinopyroxene with or without minor Fe-Ti oxides (olivine occurs in only three samples) and many of the samples show evidence of extensive alteration. Secondary minerals include chlorite, actinolite, K- and Na-feldspar, analcite and epidote. In terms of bulk chemistry the rocks are characterized by their generally evolved and highly variable compositions (e.g. Mg *=0.65-0.35;TiO 2=0.7-3.6%;Zr=31-374ppm;Nb=differentiation observed in the Conrad fracture zone basalts implies some additional constraint other than spreading rate on the formation of ferrobasalt and reaffirms the importance of extensive crustal differentiation during the production of this basalt type.

  9. Episodic entrainment of deep primordial mantle material into ocean island basalts.

    Science.gov (United States)

    Williams, Curtis D; Li, Mingming; McNamara, Allen K; Garnero, Edward J; van Soest, Matthijs C

    2015-01-01

    Chemical differences between mid-ocean ridge basalts (MORBs) and ocean island basalts (OIBs) provide critical evidence that the Earth's mantle is compositionally heterogeneous. MORBs generally exhibit a relatively low and narrow range of (3)He/(4)He ratios on a global scale, whereas OIBs display larger variability in both time and space. The primordial origin of (3)He in OIBs has motivated hypotheses that high (3)He/(4)He ratios are the product of mantle plumes sampling chemically distinct material, but do not account for lower MORB-like (3)He/(4)He ratios in OIBs, nor their observed spatial and temporal variability. Here we perform thermochemical convection calculations which show the variable (3)He/(4)He signature of OIBs can be reproduced by deep isolated mantle reservoirs of primordial material that are viscously entrained by thermal plumes. Entrainment is highly time-dependent, producing a wide range of (3)He/(4)He ratios similar to that observed in OIBs worldwide and indicate MORB-like (3)He/(4)He ratios in OIBs cannot be used to preclude deep mantle-sourced hotspots. PMID:26596781

  10. Borehole plugging of man-made accesses to a basalt repository: a preliminary study

    International Nuclear Information System (INIS)

    This report describes the status of work currently in progress for the Basalt Borehole Plugging Program (BBPP). The primary objectives of the BBPP outlined in this report have been met during this first phase of work. These objectives included: (1) the preparation of a preliminary list of candidate plug materials; (2) a description of available machinery capable of placing candidate plug materials; and (3) the development of physical and geochemical testing programs to help evaluate the chemical stability and physical properties of candidate plug materials. The most significant finding from work to date is that given reasonable regulatory criteria, nothing has been identified which would prevent design of a plug system to seal manmade openings leading to a nuclear waste repository in Columbia River basalt for significantly long periods of time (on the order of thousands of years). Work accomplished to date indicates that this plug system can be designed using both natural and manufactured materials and can be emplaced with existing placement machinery and modifications of that machinery. The objectives of Task II are to conduct laboratory tests to evaluate the suitability of preferred candidate materials for plugging boreholes in the proposed repository, select plug system(s), initiate preconceptual machinery design for the placement of materials in plug system(s), and prepare a preliminary Task II report. As with Task I project organization, Task II is divided into subtasks that are identified by written subtask work summaries

  11. Bunburra Rockhole: Exploring the Geology of a New Differentiated Basaltic Asteroid

    Science.gov (United States)

    Benedix, G.K.; Bland, P. A.; Friedrich, J. M.; Mittlefehldt, D.; Sanborn, M. E.; Yin, Q.-Z.; Greenwood, R. C; Franchi, L. A.; Bevan, A. W. R.; Towner, M. C.; Perotta, Grace C.

    2014-01-01

    Bunburra Rockhole (BR) is the first recovered meteorite of the Desert Fireball Network. It was initially classified as a basaltic eucrite, based on texture, mineralogy, and mineral chemistry but subsequent O isotopic analyses showed that BR's composition lies significantly far away from the HED group of meteorites. This suggested that BR was not a piece of the HED parent body (4 Vesta), but other explanations could also account for the observed oxygen signatures. Possible scenarios include contamination by components from other bodies (chondrites or other achondrites) or that 4 Vesta may not be as equilibrated as hypothesized. After examining multiple pieces with different instruments (CT scans and x-ray maps), no obvious evidence of contamination was found. If BR is not from Vesta, a conundrum exists as no unusual features were found in mineral and bulk trace element chemistry as exist for other anomalous basaltic achondrites such as Ibitira or Asuka 881394. These meteorites have distinct petrological and geochemical characteristics, in addition to their anomalous O isotope compositions, that set them apart from eucrites. Thus, early results provided a somewhat ambiguous picture of BR's petrogenesis and parentage. To clarify the nature of the relationship, if any, between BR and eucrites, we have performed a correlated stable isotope and bulk chemical study of several lithologic fragments.

  12. Epithermal Neutron Activation Analysis (ENAA) of Cr(VI)-reducer Basalt-inhabiting Bacteria

    CERN Document Server

    Tsibakhashvili, N Ya; Kirkesali, E I; Aksenova, N G; Kalabegishvili, T L; Murusidze, I G; Mosulishvili, L M; Holman, H Y N

    2005-01-01

    Epithermal neutron activation analysis (ENAA) has been applied to studying elemental composition of Cr(VI)-reducer bacteria isolated from polluted basalts from the Republic of Georgia. Cr(VI)-reducing ability of the bacteria was examined by electron spin resonance (ESR) demonstrating that the bacteria differ in the rates of Cr(VI) reduction. A well-pronounced correlation between the ability of the bacteria to accumulate Cr(V) and their ability to reduce Cr(V) to Cr(III) observed in our experiments is discussed. Elemental analysis of these bacteria also revealed that basalt-inhabiting bacteria are distinguished by relative contents of essential elements such as K, Na, Mg, Fe, Mn, Zn, and Co. A high rate of Cr(III) formation correlates with a high concentration of Co in the bacterium. ENAA detected some similarity in the elemental composition of the bacteria. The relatively high contents of Fe detected in the bacteria (140-340 $\\mu $g/g of dry weight) indicate bacterial adaptation to the environmental condition...

  13. Solubility of chrysotile asbestos and basalt fibers in relation to their fibrogenic and carcinogenic action.

    Science.gov (United States)

    Kogan, F M; Nikitina, O V

    1994-10-01

    Fiber length and persistence are thought to be determinants for the development of toxic, fibrogenic, and carcinogenic effects of fibrous dusts. When the solubilities of chrysotile asbestos (CA) and basalt fibers (BF) were compared by measuring the loss of silica and magnesium in Leineweber's solution, CA was shown to be the more soluble. In a 6-month inhalation experiment, chrysotile at a mean concentration of 25 mg/m3 had a higher clearance rate than other comparable dusts. In acute toxicity studies, chrysotile and basalt fibers were administered intraperitoneally. At a dose of 1.7 g/kg body weight of CA, one third of the animals died. A dose of 2.7 g/kg body weight killed all the animals. With BF, even at a dose of 10 g/kg body weight all the animals survived. When the two fibers were administered over a 6-month period, either intratracheally or by inhalation, fibrotic lesions were more common in the group that received CA. Intraperitoneal administration of CA led to three times as many deaths from peritoneal mesothelioma as administration of BF. It appears, therefore, that in spite of its higher solubility and lower persistence, CA was the more toxic, fibrogenic and carcinogenic fiber, which gives rise to the hypothesis that the surface chemistry of the fibers is the determinant for biological activity.

  14. Manufacture of Green-Composite Sandwich Structures with Basalt Fiber and Bioepoxy Resin

    Directory of Open Access Journals (Sweden)

    J. P. Torres

    2013-01-01

    Full Text Available Nowadays, there is a growing interest for the use and development of materials synthesized from renewable sources in the polymer composites manufacturing industry; this applies for both matrix and reinforcement components. In the present research, a novel basalt fibre reinforced (BFR bioepoxy green composite is proposed as an environmentally friendly alternative to traditional petroleum-derived composites. In addition, this material system was combined with cork as core material for the fabrication of fibre composite sandwich structures. Mechanical properties of both skin and core materials were assessed through flexural and tensile tests. Finite element (FEM simulations for the mechanical stress analysis of the sandwich material were carried out, and a maximum allowable shear stress for material failure under bending loads was established. Permeability measurements of the basalt fabrics were carried out in order to perform numerical simulations of liquid composite moulding (LCM processes on the PAM-RTM software. The proposed green-composite sandwich material was used for the fabrication of a longboard as a case study for a sports equipment application. Numerical simulations of the mould filling stage allowed the determination of an optimal mould filling strategy. Finally, the load-bearing capacity of the board was studied by means of FEM simulations, and the presented design proved to be acceptable for service.

  15. Imprint of a dissolved cobalt basaltic source on the Kerguelen Plateau

    Directory of Open Access Journals (Sweden)

    J. Bown

    2012-06-01

    Full Text Available Processes of cobalt (Co entrainment from shelf sediments over the Kerguelen Plateau were studied during the KEOPS (Kerguelen Ocean Plateau compared Study in order to explain the exceptionally high dissolved cobalt concentrations that have been measured in the surface waters above the Kerguelen Plateau, and in intermediate and deep waters above its eastern slope. Lateral advection and dissolution of Co contained in basalt sediments around Heard Island, a main source of lithogenic Co in the study area, were shown to imprint the process of surface enrichment over the plateau. Dissolved Co enrichment was strongest at the intercept of the eastern slope with intermediate and deep waters, probably due to more efficient mobilisation of the sediments in the slope current, in addition to advection of Co-enriched and low oxygenated ocean water-masses.

    In surface waters, strong sedimentary Co inputs were estimated to be much higher than biological Co uptake in phytoplankton blooms, underlining the potential role of cobalt as lithogenic tracer. Based on a simple, steady state balance equation of the external input of dissolved iron over the plateau, the fertilization of iron inferred by using Co as a tracer of basalt sources is estimated to be 28 × 102 ± 21 × 102 ton yr−1 in surface waters of the Kerguelen Plateau. This estimate is consistent with preceding ones and the required iron supply matching the phytoplankton demand.

  16. An innovative artificial recharge system to enhance groundwater storage in basaltic terrain: example from Maharashtra, India

    Science.gov (United States)

    Bhusari, Vijay; Katpatal, Y. B.; Kundal, Pradeep

    2016-08-01

    The management of groundwater poses challenges in basaltic terrain as its availability is not uniform due to the absence of primary porosity. Indiscriminate excessive withdrawal from shallow as well as deep aquifers for meeting increased demand can be higher than natural recharge, causing imbalance in demand and supply and leading to a scarcity condition. An innovative artificial recharge system has been conceived and implemented to augment the groundwater sources at the villages of Saoli and Sastabad in Wardha district of Maharashtra, India. The scheme involves resectioning of a stream bed to achieve a reverse gradient, building a subsurface dam to arrest subsurface flow, and installation of recharge shafts to recharge the deeper aquifers. The paper focuses on analysis of hydrogeological parameters like porosity, specific yield and transmissivity, and on temporal groundwater status. Results indicate that after the construction of the artificial recharge system, a rise of 0.8-2.8 m was recorded in the pre- and post-monsoon groundwater levels in 12 dug wells in the study area; an increase in the yield was also noticed which solved the drinking water and irrigation problems. Spatial analysis was performed using a geographic information system to demarcate the area of influence of the recharge system due to increase in yields of the wells. The study demonstrates efficacy, technical viability and applicability of an innovative artificial recharge system constructed in an area of basaltic terrain prone to water scarcity.

  17. Functions of an engineered barrier system for a nuclear waste repository in basalt

    International Nuclear Information System (INIS)

    Defined in this document are the functions of components selected for an engineered barrier system for a nuclear waste repository in basalt. The definitions provide a focal point for barrier material research and development by delineating the purpose and operative lifetime of each component of the engineered system. A five-component system (comprised of waste form, canister, buffer, overpack, and tailored backfill) is discussed in terms of effective operation throughout the course of repository history, recognizing that the emplacement environment changes with time. While components of the system are mutually supporting, redundancy is provided by subsystems of physical and chemical barriers which act in concert with the geology to provide a formidable barrier to transport of hazardous materials to the biosphere. The operating philosophy of the conceptual engineered barrier system is clarified by examples pertinent to storage in basalt, and a technical approach to barrier design and material selection is proposed. A method for system validation and qualification is also included which considers performance criteria proposed by external agencies in conjunction with site-specific models and risk assessment to define acceptable levels of system performance

  18. Glass melt inclusion in clinopyroxene from Linqu Cenozoic basalt, Shandong Province, China

    Institute of Scientific and Technical Information of China (English)

    ZHANG Hongfu; Eizo Nakamura; ZHANG Jin; Ishikawa Akira

    2006-01-01

    Cenozoic basalts from the Linqu County, Shandong Province, China entrain some clinopyroxene crystals, of which many contain abundant glass melt inclusions. These melt inclusions are extremely irregular in shape with most grain sizes in a range of 10-50 μm and coexist with low-Mg# olivines, labradorites and Ca-rich potassium feldspars. In-situ major and trace element analyses show that the glass melt inclusions are high in alkalis (Na2O+K2O > 10 wt%), SiO2 (>54 wt%), CaO and FeO (>4 wt%), but low in MgO (Mg# < 20), and have LREE enrichments ((Ce/Yb)cn = 11.6-16.4) and apparently positive Eu anomalies (Eu/Eu*>2), thus having phonolitic compositions. The compositional features of clinopyroxene crystals, glass melt inclusions and their coexistent minerals suggest that these melt inclusions were exotic melts in clinopyroxenes trapped prior to their entrainment in the host basalt. The discovery of these melt inclusions provides a new approach to further investigating the evolution of Meso- zoic lithospheric mantle beneath the southeastern North China Craton.

  19. Time-lapse characterization of hydrothermal seawater and microbial interactions with basaltic tephra at Surtsey Volcano

    Science.gov (United States)

    Jackson, M. D.; Gudmundsson, M. T.; Bach, W.; Cappelletti, P.; Coleman, N. J.; Ivarsson, M.; Jónasson, K.; Jørgensen, S. L.; Marteinsson, V.; McPhie, J.; Moore, J. G.; Nielson, D.; Rhodes, J. M.; Rispoli, C.; Schiffman, P.; Stefánsson, A.; Türke, A.; Vanorio, T.; Weisenberger, T. B.; White, J. D. L.; Zierenberg, R.; Zimanowski, B.

    2015-12-01

    A new International Continental Drilling Program (ICDP) project will drill through the 50-year-old edifice of Surtsey Volcano, the youngest of the Vestmannaeyjar Islands along the south coast of Iceland, to perform interdisciplinary time-lapse investigations of hydrothermal and microbial interactions with basaltic tephra. The volcano, created in 1963-1967 by submarine and subaerial basaltic eruptions, was first drilled in 1979. In October 2014, a workshop funded by the ICDP convened 24 scientists from 10 countries for 3 and a half days on Heimaey Island to develop scientific objectives, site the drill holes, and organize logistical support. Representatives of the Surtsey Research Society and Environment Agency of Iceland also participated. Scientific themes focus on further determinations of the structure and eruptive processes of the type locality of Surtseyan volcanism, descriptions of changes in fluid geochemistry and microbial colonization of the subterrestrial deposits since drilling 35 years ago, and monitoring the evolution of hydrothermal and biological processes within the tephra deposits far into the future through the installation of a Surtsey subsurface observatory. The tephra deposits provide a geologic analog for developing specialty concretes with pyroclastic rock and evaluating their long-term performance under diverse hydrothermal conditions. Abstracts of research projects are posted at http://surtsey.icdp-online.org.

  20. Comparative experimental study of dynamic compressive strength of mortar with glass and basalt fibres

    Directory of Open Access Journals (Sweden)

    Kruszka Leopold

    2015-01-01

    Full Text Available Specimen reinforced with glass and basalt fibers were prepared using Standard Portland cement (CEM I, 52.5 R as prescribed by EN 197-1 and standard sand, in accordance with EN 196-1. From this cementitious mixture, a reference cement mortar without fibers was first prepared. Compressive strength, modulus of elasticity, and mod of fracture were determined for all specimens. Static and dynamic properties were investigated using Instron testing machine and split Hopkinson pressure bar, respectively. Content of the glass fibers in the mortar does not influence the fracture stress at static loading conditions in a clearly observed way. Moreover at dynamic range 5% content of the fiber results in a significant drop of fracture stress. Analysis of the basalt fibers influence on the fracture stress shows that optimal content of this reinforcement is equal to 3% for both static and dynamic loading conditions. Further increase of the fiber share gives the opposite effect, i.e. drop of the fracture stress.

  1. Basalt Waste Isolation Program. Quarterly report, April 1, 1979-June 30, 1979

    International Nuclear Information System (INIS)

    During the quarter, progress was made in all areas of the Basalt Waste Isolation Program. In the Geosciences, Hydrology, and Engineered Barriers areas, work continued on schedule aimed at being able to make a site selection decision in 1981, as scheduled. Emphasis continued to be placed on geologic mapping studies, on hydrologic data gathering, and on definition of waste/basalt interactions and needed engineered barriers. Progress at the end of the quarter on the Near-Surface Test Facility was approximately on schedule and the rate of work was accelerating to better than scheduled due to some equipment improvements and tunnel design modifications. In the Engineering Testing area, design work, test planning, and fabrication of heaters and auxiliary equipment continued on schedule. In the Repository area, an Architect/Engineer Evaluation Board was formally designed by the US Department of Energy-Headquarters during October 1978. The evaluation board will select an architect/engineer for repository conceptual design with an option for follow-on Title I, Title II, and Title III engineering services. Selection will be completed by October 1979. Questionnaire information was received from a number of interested architect/engineer firms by the US Department of Energy-Richland Operations Office and has been evaluated. Onsite visits with the qualified firms were completed during April 1979. In addition, repository preconceptual design studies continued on schedule with emphasis on compilation of repository functional design criteria by July 1979, and the repository preconceptual design report in September 1979

  2. Basalt Waste Isolation Program. Quarterly report, April 1, 1979-June 30, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Deju, R.A.

    1979-07-01

    During the quarter, progress was made in all areas of the Basalt Waste Isolation Program. In the Geosciences, Hydrology, and Engineered Barriers areas, work continued on schedule aimed at being able to make a site selection decision in 1981, as scheduled. Emphasis continued to be placed on geologic mapping studies, on hydrologic data gathering, and on definition of waste/basalt interactions and needed engineered barriers. Progress at the end of the quarter on the Near-Surface Test Facility was approximately on schedule and the rate of work was accelerating to better than scheduled due to some equipment improvements and tunnel design modifications. In the Engineering Testing area, design work, test planning, and fabrication of heaters and auxiliary equipment continued on schedule. In the Repository area, an Architect/Engineer Evaluation Board was formally designed by the US Department of Energy-Headquarters during October 1978. The evaluation board will select an architect/engineer for repository conceptual design with an option for follow-on Title I, Title II, and Title III engineering services. Selection will be completed by October 1979. Questionnaire information was received from a number of interested architect/engineer firms by the US Department of Energy-Richland Operations Office and has been evaluated. Onsite visits with the qualified firms were completed during April 1979. In addition, repository preconceptual design studies continued on schedule with emphasis on compilation of repository functional design criteria by July 1979, and the repository preconceptual design report in September 1979.

  3. Effect of Dissolved Organic Matter on Basalt Weathering Rates under Flow Conditions

    Science.gov (United States)

    Dontsova, K.; Steefel, C. I.; Chorover, J. D.

    2009-12-01

    Rock weathering is an important aspect of soil formation that is tightly coupled to the progressive colonization of grain surfaces by microorganisms and plant tissue, both of which are associated with the exudation of complexing ligands and reducing equivalents that are incorporated into dissolved organic matter. As part of a larger hillslope experimental study being designed for Biosphere 2 (Oracle, AZ), we seek to determine how the presence and concentration of dissolved organic matter affects the incongruent dissolution rates of basaltic tuff. Saturated flow column experiments are being conducted using plant-derived soluble organic matter solutions of variable concentrations, and comparisons are being made to experiments conducted with malic acid, a low-molecular weight organic acid commonly exuded into the rhizosphere. Dissolved organic matter was extracted from Ponderosa Pine forest floor and was characterized for aqueous geochemical parameters (pH, EC, ion balance, DOC/TN) and also for DOC composition (UV-Vis, FTIR spectroscopy). Column effluents are being analyzed for major and trace cations, anions, silica and organic solutes. Dissolution rates of primary minerals and precipitation rates of secondary phases will be estimated by fitting the data to a numerical reactive transport model, CrunchFlow2007. At the end of the fluid flow experiment, column materials will be analyzed for biogeochemical composition to detect preferential dissolution of specific phases, the precipitation of new ones, and to monitor the associated formation of biofilms. The influence of organic solutions on weathering patterns of basalt will be discussed.

  4. Magnetic mineralogy of a weathered tropical basalt, Hainan Island, South China

    Science.gov (United States)

    Ouyang, Tingping; Tang, Zhihua; Zhao, Xiang; Tian, Chengjing; Ma, Jinlong; Wei, Gangjian; Huang, Ningsheng; Li, Mingkun; Bian, Yong

    2015-03-01

    Numerous studies have shown that mineral magnetic properties are sensitive indicators of weathering and soil formation (pedogenesis). However, the formation pathways and subsequent alteration mechanisms of specific weathering products are poorly constrained. We report a detailed magnetic investigation through a basalt profile that has been weathered under tropical conditions in South China. The rock magnetic analyses show that hot and humid conditions led to the neoformation of fine-grained magnetite and promoted mineral transformations in the form of maghemitization and hematization. Thus, although the basaltic parent material is rich in titanomagnetite, the final products of the weathering process are maghemite and hematite. Magnetic grain-size varies through the profile, with a combination of pseudo-single domain and single-domain particles at the base, with fining to single-domain in the middle and a mixture of superparamagnetic and single-domain particles in the uppermost profile. Importantly, the magnetic mineral assemblage through the profile is influenced by the mobilization and migration of iron through the sequence. This process is illustrated by concentration-dependent magnetic parameters, which reach maxima at the assembly depth of major and trace elements and minima at the oxic front where Fe content is its lowest.

  5. Volcanological aspects of the northwest region of Paraná continental flood basalts (Brazil)

    Science.gov (United States)

    Braz Machado, F.; Reis Viana Rocha-Júnior, E.; Soares Marques, L.; Ranalli Nardy, A. J.

    2015-02-01

    There has been little research on volcanological aspects of Paraná continental flood basalts (PCFBs), and all investigations have mainly been concentrated on the internal portions of the lava flows. Thus, this study describes for the first time morphological aspects of lava flows and structural characteristics caused by lava-sediment interaction in the northwestern PCFB province (NW-PCFB). Early Cretaceous (134 to 132 Ma) tholeiitic rocks of the PCFB were emplaced on a large intracratonic Paleozoic sedimentary basin (Paraná Basin), mainly covering dry eolian sandstones (Botucatu Formation). As this sedimentary unit is overlain by the basic lava flows of the PCFB, the interaction of lavas and unconsolidated sediments resulted in the generation of fluidal peperites. This aspect is significant because it shows that restricted wet environments should have existed in the Botucatu desert. The peperite zones of the NW-PCFB are associated with compound pahoehoe-type (P-type) flows and are always related to the first volcanic pulses. These flows have dispersed vesicles and sand-filled cracks in their base and top borders, as well as the presence of interlayered sandstones with irregular contacts and varied thicknesses. It is remarkable that, to the best of current knowledge, only in this area of the whole PCFB did the volcanic activity start with low-Ti basalt flows of Ribeira type (TiO2 < 2.3 wt%), which are scarce in the province.

  6. Combined effect of permeability and crystallization on the explosive eruption of basaltic magma

    Science.gov (United States)

    Moitra, P.; Gonnermann, H. M.; Houghton, B. F.; Crozier, J.

    2015-12-01

    Plinian eruptions are the most dangerous style of eruptive activity of basaltic magma. In this study, we focus on the two best studied Plinian eruptions of basaltic magma at Mt. Tarawera, New Zealand (1886 CE) and Mt. Etna, Italy (122 BCE). We measured and analyzed the porosity-permeability relationships of the pyroclasts from both eruptions. We then used numerical modeling to assess the relative importance of two competing processes during eruptive magma ascent, which are the syneruptive crystallization that increases viscosity, potentially increasing bubble overpressure, and the open-system degassing of the permeable magma that allows the pressurized gas to escape, potentially reducing bubble overpressure. We find that the onset of crystallization is likely to have occurred prior to the onset of magma percolation. The orders of magnitude increase in magma viscosity due to the nucleation and growth of microlites had the combined effect of rapidly increasing the decompression rate, due to viscous pressure losses associated with magma flow within the volcanic conduit, and decreasing the rates of bubble growth, thus building up large overpressures inside bubbles. Although measured permeabilities of the studied pyroclasts are 1-2 orders of magnitude higher than their silicic counterpart, our model results show that crystallization and subsequent increase in viscosity are likely to surpass the effect of open-system gas loss, thus increasing bubble overpressure, required for explosive magma fragmentation.

  7. The relative roles of boundary layer fractionation and homogeneous fractionation in cooling basaltic magma chambers

    Science.gov (United States)

    Kuritani, Takeshi

    2009-06-01

    In a cooling magma chamber, magmatic differentiation can proceed both by fractionation of crystals from the main molten part of the magma body (homogeneous fractionation) and by mixing of the main magma with fractionated melt derived from low-temperature mush zones (boundary layer fractionation). In this study, the relative roles of boundary layer fractionation and homogeneous fractionation in basaltic magma bodies were examined using a thermodynamics-based mass balance model. Model calculations show that boundary layer fractionation cannot be a dominant fractionation mechanism when magma chambers are located at low pressures (magmatic evolution. On the other hand, boundary layer fractionation can occur effectively when magmas are hydrous (> ~ 2 wt.%), such as arc basalt, and the magma chambers are located at depth (> ~ 100 MPa). Because the melt derived from mush zones is enriched in alkalis and H 2O, crystallization from the main magma is suppressed by mixing with the mush melt as a consequence of depression of the liquidus temperature. Therefore, homogeneous fractionation is more effectively suppressed in magma chambers in which boundary layer fractionation is more active. If magmatic differentiation proceeds primarily by boundary layer fractionation, magmas can remain free of crystals for long periods during magmatic evolution.

  8. Ocean Basalt Simulator version 1 (OBS1): Trace element mass balance in adiabatic melting of a pyroxenite-bearing peridotite

    Science.gov (United States)

    Kimura, Jun-Ichi; Kawabata, Hiroshi

    2015-01-01

    present a new numerical trace element mass balance model for adiabatic melting of a pyroxenite-bearing peridotite for estimating mantle potential temperature, depth of melting column, and pyroxenite fraction in the source mantle for a primary ocean basalt/picrite. The Ocean Basalt Simulator version 1 (OBS1) uses a thermodynamic model of adiabatic melting of a pyroxenite-bearing peridotite with experimentally/thermodynamically parameterized liquidus-solidus intervals and source mineralogy. OBS1 can be used to calculate a sequence of adiabatic melting with two melting models, including (1) melting of peridotite and pyroxenite sources with simple mixing of their fractional melts (melt-melt mixing model), and (2) pyroxenite melting, melt metasomatism in the host peridotite, and melting of the metasomatized peridotite (source-metasomatism model). OBS1 can be used to explore (1) the fractions of peridotite and pyroxenite, (2) mantle potential temperature, (3) pressure of termination of melting, (4) degree of melting, and (5) residual mode of the sources. In order to constrain these parameters, the model calculates a mass balance for 26 incompatible trace elements in the sources and in the generated basalt/picrite. OBS1 is coded in an Excel spreadsheet and runs with VBA macros. Using OBS1, we examine the source compositions and conditions of the mid-oceanic ridge basalts, Loihi-Koolau basalts in the Hawaiian hot spot, and Jurassic Shatsky Rise and Mikabu oceanic plateau basalts and picrites. The OBS1 model shows the physical conditions, chemical mass balance, and amount of pyroxenite in the source peridotite, which are keys to global mantle recycling.

  9. Subduction—Modified Subcontinental Mantle in South China:Trace Element and Isotope Evidence in Basalts from Hainan Island

    Institute of Scientific and Technical Information of China (English)

    张明; 解广轰; 等

    1996-01-01

    Cenozoic lavas from Hainan Island,South China,comprise quartz tholeiite,olivine tholeiite,alkali basalt,and basanite and form a continuous,tholeiite-dominated,compositional spectrum.Highly incompatible elements and their relationships with isotopes in these lavas are shown to be useful in evaluating mantle-source composition,whereas modeling suggests that ratios of elements with bulk partition coefficients significantly larger than those of Nb and Ta may be sensitive to partial melting.Th/Ta and La/Nb ratios of alkali basalts are lower than those of tholeiites,and they are all lower than those of the primitive mantle,These ratios correlate positively with 207Pb/204Pb and 87Sr/86Sr ratios.Such relationships can be explained by mixing of depleted and enriched source components.A depleted component is indicated by alkali basalt compositions and is similar to some depleted OIB (PREMA).The enriched component,similar to sediment compositions,is indicated by tholeiites with high LILE/HFSE,207Pb/204Pb,and 87Sr/86Sr ratios.In general,basalts from Hainan and the South China Basin(SCB)share common geochemical characters.e.g.high Rb/Sr,Th/Ta,207Pb/206Pb,and low Ba/Th ratios.Such a geochemical trend is comparable to that of EMII-type OIB and best explained as the result of subduction.Occurrence of these characteristics in both continental Hainan basalts and SCB seamout basalts indicates the presence of a South China geochemical domain that exists in the mantle region below the lithosphere.

  10. Technical support for GEIS: radioactive waste isolation in geologic formations. Volume 14. Repository preconceptual design studies: basalt

    Energy Technology Data Exchange (ETDEWEB)

    1978-04-01

    This document describes a preconceptual design for a nuclear waste storage facility in basalt. The facility design consists of several chambers excavated deep within a geologic formation together with access shafts and supportive surface structures. The facility design provides for: receiving and unloading waste containers; lowering them down shafts to the mine level; transporting them to the proper storage area and emplacing them in mined storage rooms. Drawings of the facility design are contained in TM-36/15, ''Drawings for Repository Preconceptual Design Studies: Basalt.''

  11. Technical support for GEIS: radioactive waste isolation in geologic formations. Volume 14. Repository preconceptual design studies: basalt

    International Nuclear Information System (INIS)

    This document describes a preconceptual design for a nuclear waste storage facility in basalt. The facility design consists of several chambers excavated deep within a geologic formation together with access shafts and supportive surface structures. The facility design provides for: receiving and unloading waste containers; lowering them down shafts to the mine level; transporting them to the proper storage area and emplacing them in mined storage rooms. Drawings of the facility design are contained in TM-36/15, ''Drawings for Repository Preconceptual Design Studies: Basalt.''

  12. Maskelynite in asteroidal, lunar and planetary basaltic meteorites: An indicator of shock pressure during impact ejection from their parent bodies

    Science.gov (United States)

    Rubin, Alan E.

    2015-09-01

    Maskelynite is a diaplectic glass that forms from plagioclase at shock pressures of ∼20-30 GPa, depending on the Ca concentration. The proportion of maskelynite-rich samples in a basaltic meteorite group correlates with the parent-body escape velocity and serves as a shock indicator of launching conditions. For eucrites (basalts widely presumed to be from Vesta; vesc = 0.36 km s-1), ∼5% of the samples are maskelynite rich. For the Moon (vesc = 2.38 km s-1), ∼30% of basaltic meteorites are maskelynite rich. For Mars (vesc = 5.03 km s-1), ∼93% of basaltic meteorites are maskelynite rich. In contrast, literature data show that maskelynite is rare (∼1%) among mare basalts and basaltic fragments in Apollo 11, 12, 15 and 17 soils (which were never ejected from the Moon). Angrites are unbrecciated basaltic meteorites that are maskelynite free; they were ejected at low-to-moderate shock pressures from an asteroid smaller than Vesta. Because most impacts that eject materials from a large (⩾100 km) parent body are barely energetic enough to do that, a collision that has little more than the threshold energy required to eject a sample from Vesta will not be able to eject identical samples from the Moon or Mars. There must have been relatively few impacts, if any, that launched eucrites off their parent body that also imparted shock pressures of ∼20-30 GPa in the ejected rocks. More-energetic impacts were required to launch basalts off the Moon and Mars. On average, Vesta ejecta were subjected to lower shock pressures than lunar ejecta, and lunar ejecta were subjected to lower shock pressures than martian ejecta. H and LL ordinary chondrites have low percentages of shock-stage S5 maskelynite-bearing samples (∼1% and ∼4%, respectively), probably reflecting shock processes experienced by these rocks on their parent asteroids. In contrast, L chondrites have a relatively high proportion of samples containing maskelynite (∼11%), most likely a result of

  13. Near-UV Transmittance of Basalt Dust as an Analog of the Martian Regolith: Implications for Sensor Calibration and Astrobiology

    OpenAIRE

    J. Martínez-Frías; E. Mateo-Martí; G. M. Muñoz Caro

    2006-01-01

    The Martian regolith is exposed to solar irradiation in the near-UV (200-390 nm). Basalt is one of the main components of the dust on Mars surface. The near-UV irradiation of basalt dust on Mars is simulated experimentally in order to determine the transmittance as a function of the mass and thickness of the dust. This data can serve to quantify the absorption of dust deposited on sensors aiming to measure the UV intensity on Mars surface. The minimum thickness of the dust that corresponds to...

  14. Flood-basalt magmatism of the Vodlozero Block of the Karelian Craton: relations between high- and low-Cr Varieties

    Science.gov (United States)

    Bogina, Maria; Zlobin, Valeriy; Sharkov, Evgenii; Chistyakov, Alexii

    2016-04-01

    The early Paleoproterozoic (2.5-2.3 Ga) volcanic rocks of the Karelian Craton are ascribed to the large igneous province of the eastern Fennoscandian Shield. They are mainly represented by calc-alkaline low-Ti basalts and basaltic andesites with relatively high SiO2 and clearly pronounced continental trace element signatures. The compositions of the rocks vary in the different domains of the Karelian craton. In particular, basalts developed in the Central Domain are represented by strongly fractionated varieties (Mg # parental melts of continental flood basalts and their crustal evolution. In the spidergrams they demonstrate weak positive Ti anomaly at positive or absent Zr anomaly and negative Nb anomaly. The rocks of the second group are also characterized (with rare exception) by LREE enriched but less fractionated patterns than the first group: ((La/Yb)n up to 7.5, (La/Sm)n = up to 2.8, (Gd/Yb)n = up to 2.0). High Cr and low Y contents are indicative of relatively high degree of partial melting of a depleted mantle source. These rocks are simulated by sequential fractionation of uncontaminated continental flood basalts leaving Ol residue and lower crustal contamination (rocks with low values of eNd). The percentage of crustal contamination is controlled by Nb/Th ratio. Examination of Nd isotope data revealed that both these types have negative eNd, but high-Cr rocks have slightly more radiogenic Nd isotope composition. A high positive correlation of eNd with Cr and Mg# in combination with similar trace element signatures of these rocks indicates that the rocks were derived from a single magmatic system: low-Cr basalts were derived from high-Cr basalts via fractionation and insignificant upper crustal contamination. A considerable decrease of Cr and Ni with decrease of Mg#, at practically unchangeable Al2O3, TiO2, CaO, and Na2O suggests that the process was controlled by fractional crystallization of olivine and Cr-spinel. Absence of distinctive increase in V

  15. Groundwater recharge in Pleistocene sediments overlying basalt aquifers in the Palouse Basin, USA: modeling of distributed recharge potential and identification of water pathways

    NARCIS (Netherlands)

    Dijksma, R.; Brooks, E.S.; Boll, J.

    2011-01-01

    Groundwater levels in basalt aquifers around the world have been declining for many years. Understanding water pathways is needed for solutions like artificial drainage. Water supply in the Palouse Basin, Washington and Idaho, USA, primarily relies on basalt aquifers. This study presents a combinati

  16. Bimodal TiO2 Contents of Mare Basalts at Apollo and Luna Sites and Implications for TiO2 Derived from Clementine Spectral Reflectance

    Science.gov (United States)

    Gillis, J. J.; Jolliff, B. L.

    2001-01-01

    A revised algorithm to estimate Ti contents of mare regions centered on Apollo and Luna sites shows a bimodal distribution, consistent with mare-basalt sample data. A global TiO2 map shows abundant intermediate TiO2 basalts in western Procellarum. Additional information is contained in the original extended abstract.

  17. Extreme incompatibility of helium during mantle melting: Evidence from undegassed mid-ocean ridge basalts

    Science.gov (United States)

    Graham, David W.; Michael, Peter J.; Shea, Thomas

    2016-11-01

    We report total helium concentrations (vesicles + glass) for a suite of thirteen ultradepleted mid-ocean ridge basalts (UD-MORBs) that were previously studied for volatile contents (CO2, H2O) plus major and trace elements. The selected basalts are undersaturated in CO2 + H2O at their depths of eruption and represent rare cases of undegassed MORBs. Sample localities from the Atlantic (2), Indian (1) and Pacific (7) Oceans collectively show excellent linear correlations (r2 = 0.75- 0.92) between the concentrations of helium and the highly incompatible elements C, K, Rb, Ba, Nb, Th and U. Three basalts from Gakkel Ridge in the Arctic were also studied but show anomalous behavior marked by excess lithophile trace element abundances. In the Atlantic-Pacific-Indian suite, incompatible element concentrations vary by factors of 3-4.3, while helium concentration varies by a factor of 13. The strong correlations between the concentrations of helium and incompatible elements are explained by helium behavior as the most incompatible element during mantle melting. Partial melting of an ultradepleted mantle source, formed as a residue of earlier melt extraction, accounts for the observed concentrations. The earlier melting event involved removal of a small degree melt (∼1%) at low but non-zero porosity (0.01-0.5%), leading to a small amount of melt retention that strongly leveraged the incompatible element budget of the ultradepleted mantle source. Equilibrium melting models that produce the range of trace element and helium concentrations from this source require a bulk solid/melt distribution coefficient for helium that is lower than that for other incompatible elements by about a factor of ten. Alternatively, the bulk solid/melt distribution coefficient for helium could be similar to or even larger than that for other incompatible elements, but the much larger diffusivity of helium in peridotite leads to its more effective incompatibility and efficient extraction from a

  18. Estimates of olivine-basaltic melt electrical conductivity using a digital rock physics approach

    Science.gov (United States)

    Miller, Kevin J.; Montési, Laurent G. J.; Zhu, Wen-lu

    2015-12-01

    Estimates of melt content beneath fast-spreading mid-ocean ridges inferred from magnetotelluric tomography (MT) vary between 0.01 and 0.10. Much of this variation may stem from a lack of understanding of how the grain-scale melt geometry influences the bulk electrical conductivity of a partially molten rock, especially at low melt fraction. We compute bulk electrical conductivity of olivine-basalt aggregates over 0.02 to 0.20 melt fraction by simulating electric current in experimentally obtained partially molten geometries. Olivine-basalt aggregates were synthesized by hot-pressing San Carlos olivine and high-alumina basalt in a solid-medium piston-cylinder apparatus. Run conditions for experimental charges were 1.5 GPa and 1350 °C. Upon completion, charges were quenched and cored. Samples were imaged using synchrotron X-ray micro-computed tomography (μ-CT). The resulting high-resolution, 3-dimensional (3-D) image of the melt distribution constitutes a digital rock sample, on which numerical simulations were conducted to estimate material properties. To compute bulk electrical conductivity, we simulated a direct current measurement by solving the current continuity equation, assuming electrical conductivities for olivine and melt. An application of Ohm's Law yields the bulk electrical conductivity of the partially molten region. The bulk electrical conductivity values for nominally dry materials follow a power-law relationship σbulk = Cσmeltϕm with fit parameters m = 1.3 ± 0.3 and C = 0.66 ± 0.06. Laminar fluid flow simulations were conducted on the same partially molten geometries to obtain permeability, and the respective pathways for electrical current and fluid flow over the same melt geometry were compared. Our results indicate that the pathways for flow fluid are different from those for electric current. Electrical tortuosity is lower than fluid flow tortuosity. The simulation results are compared to existing experimental data, and the potential

  19. Uptaking of plagioclase xenocryst into H2O-rich rear-arc basaltic magma

    Science.gov (United States)

    Hamada, M.

    2015-12-01

    Kuritani et al. (2013, Mineral. Petrol.) and Kuritani et al. (2014, Contrib. Mineral. Petrol.) estimated genetic conditions of primary arc magmas beneath the Iwate volcano (a frontal arc volcano in the northeast Japan arc) and the Sannome-gata volcano (a rear-arc volcano in the northeast Japan arc) based on analyses of volcanic rocks and numerical simulation. They estimated that H2O concentrations of primary melts are 4-5 wt.% beneath the Iwate volcano and 6-7 wt.% beneath the Sannnome-gata volcano, respectively. Their arguments mean that primary melts beneath frontal-arc volcanoes and rear-arc volcanoes are both H2O-rich, yet there has been no direct evidence to support their arguments at the Sannnome-gata volcano because volcanic rocks are either almost aphyric and/or almost no melt inclusions were found. Hydrogen concentration in nominally anhydrous minerals serves as a hygrometer of arc basaltic melts (e.g., Hamada et al. 2013, Earth Planet. Sci. Lett.). In this study, hydrogen concentration of plagioclase as a crustal xenocryst was analyzed to estimate H2O concentration of basaltic melt coexisted with plagioclase before the eruption. Plagioclase xenocrists were separated from crushed scoria which erupted from the Sannome-gata volcano 20,000-24,000 years ago. Composition of the plagioclase core is homogeneous and ranges from An30 through An35. The rim is 150 to 200-μm-thick dusty zone whose composition is around An60, suggesting that the rim crystallized rapidly from degassed basaltic melt. The profiles of infrared absorption area per unit thickness across the plagioclase core were obtained using Fourier Transform InfraRed spectrometer (FTIR). The inner core contains hydrogen of about 60 wt. ppm H2O, and hydrogen concentration elevates at outer core. Hydrogen concentration at the outermost core of plagioclase is >200 wt. ppm H2O, suggesting that plagioclase xenocrists were taken by hydrous melt (H2O>5 wt.%; Hamada et al. 2014, Earth Planet. Sci. Lett.) and

  20. The effect of rock composition on cyanobacterial weathering of crystalline basalt and rhyolite.

    Science.gov (United States)

    Olsson-Francis, K; Simpson, A E; Wolff-Boenisch, D; Cockell, C S

    2012-09-01

    The weathering of volcanic rocks contributes significantly to the global silicate weathering budget, effecting carbon dioxide drawdown and long-term climate control. The rate of chemical weathering is influenced by the composition of the rock. Rock-dwelling micro-organisms are known to play a role in changing the rate of weathering reactions; however, the influence of rock composition on bio-weathering is unknown. Cyanobacteria are known to be a ubiquitous surface taxon in volcanic rocks. In this study, we used a selection of fast and slow growing cyanobacterial species to compare microbial-mediated weathering of bulk crystalline rocks of basaltic and rhyolitic composition, under batch conditions. Cyanobacterial growth caused an increase in the pH of the medium and an acceleration of rock dissolution compared to the abiotic controls. For example, Anabaena cylindrica increased the linear release rate (R(i)(l)) of Ca, Mg, Si and K from the basalt by more than fivefold (5.21-12.48) and increased the pH of the medium by 1.9 units. Although A. cylindrica enhanced rhyolite weathering, the increase in R(i)(l) was less than threefold (2.04-2.97) and the pH increase was only 0.83 units. The R(i)(l) values obtained with A. cylindrica were at least ninefold greater with the basalt than the rhyolite, whereas in the abiotic controls, the difference was less than fivefold. Factors accounting for the slower rate of rhyolite weathering and lower biomass achieved are likely to include the higher content of quartz, which has a low rate of weathering and lower concentrations of bio-essential elements, such as, Ca, Fe and Mg, which are known to be important in controlling cyanobacterial growth. We show that at conditions where weathering is favoured, biota can enhance the difference between low and high Si-rock weathering. Our data show that cyanobacteria can play a significant role in enhancing rock weathering and likely have done since they evolved on the early Earth.