WorldWideScience

Sample records for au site pilote

  1. Strontium and caesium transport in unsaturated soil from Chernobyl Pilot Site under steady flow conditions; Transfert de radioelements en zone non saturee. Etude experimentale et modelisation appliquees au Site Pilote de Tchernobyl

    Energy Technology Data Exchange (ETDEWEB)

    Szenknect, St

    2003-10-15

    This work is devoted to the quantification and the identification of the predominant processes involved in strontium and caesium transport in unsaturated soil from Chernobyl Pilot Site under steady flow conditions. The transport and fate of radionuclides in the subsurface is affected by various physical and chemical processes including advective and diffusive transport as well as chemical and biological transformations. Laboratory experiments and the use of a multiple tracer approach allow to isolate the contributions of each elementary process and to control the physico-chemical conditions in the system. To be more representative of the field conditions, we decided to perform column miscible displacement experiments. We perform batch and flow-through reactor experiments to characterize the radionuclides sorption mechanisms. Miscible displacement experiments within homogeneous columns and modeling allow to characterize the hydrodynamic properties of the soil and to describe the radionuclides behaviour under dynamic conditions at different water contents. We show that the water content of porous media affect the transport behaviour of inert and strongly sorbing radionuclides. Our results demonstrate that a parametrized transport model that was calibrated under completely saturated conditions was not able to describe the advective-dispersive transport of reactive solutes under unsaturated steady state conditions. Under our experimental conditions, there is no effect of a decrease of the mean water content on the sorption model parameters, but the transport parameters are modified. We established for the studied soil the relation between hydrodynamic dispersion and water content and the relation between pore water velocity and water content. (author)

  2. Site characterization and site response in Port-au-Prince, Haiti

    Science.gov (United States)

    Hough, Susan E.; Yong, Alan K.; Altidor, Jean Robert; Anglade, Dieuseul; Given, Douglas D.; Mildor, Saint-Louis

    2011-01-01

    Waveform analysis of aftershocks of the Mw7.0 Haiti earthquake of 12 January 2010 reveals amplification of ground motions at sites within the Cul de Sac valley in which Port-au-Prince is situated. Relative to ground motions recorded at a hard-rock reference site, peak acceleration values are amplified by a factor of approximately 1.8 at sites on low-lying Mio-Pliocene deposits in central Port-au-Prince and by a factor of approximately 2.5–3 on a steep foothill ridge in the southern Port-au-Prince metropolitan region. The observed amplitude, predominant periods, variability, and polarization of amplification are consistent with predicted topographic amplification by a steep, narrow ridge. A swath of unusually high damage in this region corresponds with the extent of the ridge where high weak-motion amplifications are observed. We use ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) imagery to map local geomorphology, including characterization of both near-surface and of small-scale topographic structures that correspond to zones of inferred amplification.

  3. Projet pilote sur la stimulation du commerce des services au Moyen ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Projet pilote sur la stimulation du commerce des services au Moyen-Orient et en Afrique du Nord. Si certaines régions en développement ont réussi à s'intégrer aux chaînes de production mondiales, la région du Moyen-Orient et de l'Afrique du Nord ne participe encore à l'économie mondiale que par des activités simples et ...

  4. Site-specific growth of Au particles on ZnO nanopyramids under ultraviolet illumination

    KAUST Repository

    Yao, Kexin

    2011-01-01

    In this work, wurtzite ZnO nanocrystals with unique "pyramid" morphology were firstly prepared via solvothermal synthesis. It was determined that the ZnO nanopyramids are grown along the polar c-axis with the vertexes pointing to the [001] direction. When the mixture of ZnO nanopyramids and Au precursor (HAuCl4) was exposed to ultraviolet (UV) illumination, Au particles were site-specifically formed on the vertexes of ZnO nanopyramids. The obtained Au/ZnO nanocomposite showed significantly enhanced photocatalytic activity as compared to the bare ZnO nanopyramids. First-principles based calculations well explained the formation of ZnO nanopyramids as well as the site-specific growth of Au, and revealed that during the photocatalysis process the Au particles can accommodate photoelectrons and thus facilitate the charge separation. © 2011 The Royal Society of Chemistry.

  5. Site-specific growth of Au-Pd alloy horns on Au nanorods: A platform for highly sensitive monitoring of catalytic reactions by surface enhancement raman spectroscopy

    KAUST Repository

    Huang, Jianfeng

    2013-06-12

    Surface-enhanced Raman scattering (SERS) is a highly sensitive probe for molecular detection. The aim of this study was to develop an efficient platform for investigating the kinetics of catalytic reactions with SERS. To achieve this, we synthesized a novel Au-Pd bimetallic nanostructure (HIF-AuNR@AuPd) through site-specific epitaxial growth of Au-Pd alloy horns as catalytic sites at the ends of Au nanorods. Using high-resolution electron microscopy and tomography, we successfully reconstructed the complex three-dimensional morphology of HIF-AuNR@AuPd and identified that the horns are bound with high-index {11l} (0.25 < l < 0.43) facets. With an electron beam probe, we visualized the distribution of surface plasmon over the HIF-AuNR@AuPd nanorods, finding that strong longitudinal surface plasmon resonance concentrated at the rod ends. This unique crystal morphology led to the coupling of high catalytic activity with a strong SERS effect at the rod ends, making HIF-AuNR@AuPd an excellent bifunctional platform for in situ monitoring of surface catalytic reactions. Using the hydrogenation of 4-nitrothiophenol as a model reaction, we demonstrated that its first-order reaction kinetics could be accurately determined from this platform. Moreover, we clearly identified the superior catalytic activity of the rod ends relative to that of the rod bodies, owing to the different SERS activities at the two positions. In comparison with other reported Au-Pd bimetallic nanostructures, HIF-AuNR@AuPd offered both higher catalytic activity and greater detection sensitivity. © 2013 American Chemical Society.

  6. Waste Isolation Pilot Plant Annual Site Environmental Report for 2012

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-09-01

    The purpose of the Waste Isolation Pilot Plant (WIPP) Annual Site Environmental Report for 2012 (ASER) is to provide information required by U.S. Department of Energy (DOE) Order 231.1B, Environment, Safety, and Health Reporting. Specifically, the ASER presents summary environmental data to: Characterize site environmental management performance; Summarize environmental occurrences and responses reported during the calendar year; Confirm compliance with environmental standards and requirements; Highlight significant environmental accomplishments, including progress toward the DOE Environmental Sustainability Goals made through implementation of the WIPP Environmental Management System (EMS).

  7. SUPERFUND TREATABILITY CLEARINGHOUSE: SOIL STABILIZATION PILOT STUDY, UNITED CHROME NPL SITE PILOT STUDY AND HEALTH AND SAFETY PROGRAM, UNITED CHROME NPL SITE PILOT STUDY

    Science.gov (United States)

    This document is a project plan for a pilot study at the United Chrome NPL site, Corvallis, Oregon and includes the health and safety and quality assurance/quality control plans. The plan reports results of a bench-scale study of the treatment process as iieasured by the ...

  8. Waste Isolation Pilot Plant CY 2000 Site Environmental Report

    International Nuclear Information System (INIS)

    Westinghouse TRU Solutions, LLC; Environmental Science and Research Foundation, Inc.

    2001-01-01

    The U.S. Department of Energy's (DOE) Carlsbad Field Office and Westinghouse TRU Solutions, LLC (WTS) are dedicated to maintaining high quality management of Waste Isolation Pilot Plant (WIPP) environmental resources. DOE Order 5400.1, General Environmental Protection Program, and DOE Order 231.1, Environmental, Safety, and Health Reporting, require that the environment at and near DOE facilities be monitored to ensure the safety and health of the public and the environment. This Waste Isolation Pilot Plant 2000 Site Environmental Report summarizes environmental data from calendar year (CY) 2000 that characterize environmental management performance and demonstrate compliance with federal and state regulations. This report was prepared in accordance with DOE Order 5400.1, DOE Order 231.1, the Environmental Regulatory Guide for Radiological Effluent Monitoring and Environmental Surveillance (DOE/EH-0173T), and the Waste Isolation Pilot Plant Environmental Protect ion Implementation Plan (DOE/WIPP 96-2199). The above orders and guidance documents require that DOE facilities submit an Annual Site Environmental Report to DOE Headquarters, Office of the Assistant Secretary for Environment, Safety, and Health. The purpose of this report is to provide a comprehensive description of operational environmental monitoring activities, to provide an abstract of environmental activities conducted to characterize site environmental management performance to confirm compliance with environmental standards and requirements, and to highlight significant programs and efforts of environmental merit at WIPP during CY 2000. The format of this report follows guidance offered in a June 1, 2001 memo from DOE's Office of Policy and Guidance with the subject ''Guidance for the preparation of Department of Energy (DOE) Annual Site Environmental Reports (ASERs) for Calendar Year 2000.'' WIPP received its first shipment of waste on March 26, 1999. In 2000, no evidence was found of any adverse

  9. Waste Isolation Pilot Plant CY 2000 Site Environmental Report

    Energy Technology Data Exchange (ETDEWEB)

    Westinghouse TRU Solutions, LLC; Environmental Science and Research Foundation, Inc.

    2001-12-31

    The U.S. Department of Energy's (DOE) Carlsbad Field Office and Westinghouse TRU Solutions, LLC (WTS) are dedicated to maintaining high quality management of Waste Isolation Pilot Plant (WIPP) environmental resources. DOE Order 5400.1, General Environmental Protection Program, and DOE Order 231.1, Environmental, Safety, and Health Reporting, require that the environment at and near DOE facilities be monitored to ensure the safety and health of the public and the environment. This Waste Isolation Pilot Plant 2000 Site Environmental Report summarizes environmental data from calendar year (CY) 2000 that characterize environmental management performance and demonstrate compliance with federal and state regulations. This report was prepared in accordance with DOE Order 5400.1, DOE Order 231.1, the Environmental Regulatory Guide for Radiological Effluent Monitoring and Environmental Surveillance (DOE/EH-0173T), and the Waste Isolation Pilot Plant Environmental Protect ion Implementation Plan (DOE/WIPP 96-2199). The above orders and guidance documents require that DOE facilities submit an Annual Site Environmental Report to DOE Headquarters, Office of the Assistant Secretary for Environment, Safety, and Health. The purpose of this report is to provide a comprehensive description of operational environmental monitoring activities, to provide an abstract of environmental activities conducted to characterize site environmental management performance to confirm compliance with environmental standards and requirements, and to highlight significant programs and efforts of environmental merit at WIPP during CY 2000. The format of this report follows guidance offered in a June 1, 2001 memo from DOE's Office of Policy and Guidance with the subject ''Guidance for the preparation of Department of Energy (DOE) Annual Site Environmental Reports (ASERs) for Calendar Year 2000.'' WIPP received its first shipment of waste on March 26, 1999. In 2000, no

  10. Waste Isolation Pilot Plant Site Environmental Report Calendar Year 2002

    International Nuclear Information System (INIS)

    Washington Regulatory and Environmental Services

    2003-01-01

    The United States (U.S.) Department of Energy (DOE) Carlsbad Field Office (CBFO) and Washington TRU Solutions LLC (WTS) are dedicated to maintaining high quality management of Waste Isolation Pilot Plant (WIPP) environmental resources. DOE Order 5400.1, General Environmental Protection Program, and DOE Order 231.1, Environment, Safety, and Health Reporting, require that the environment at and near DOE facilities be monitored to ensure the safety and health of the public and the environment. This Waste Isolation Pilot Plant 2002 Site Environmental Report summarizes environmental data from calendar year 2002 that characterize environmental management performance and demonstrate compliance with federal and state regulations. This report was prepared in accordance with DOE Order 5400.1, DOE Order 231.1, and Guidance for the Preparation of DOE Annual Site Environmental Reports (ASERs) for Calendar Year 2002 (DOE Memorandum EH-41: Natoli:6-1336, April 4, 2003). These Orders and the guidance document require that DOE facilities submit an annual site environmental report to DOE Headquarters, Office of the Assistant Secretary for Environment, Safety, and Health; and the New Mexico Environment Department (NMED)

  11. Waste Isolation Pilot Plant Site Environmental Report Calendar Year 2002

    Energy Technology Data Exchange (ETDEWEB)

    Washington Regulatory and Environmental Services

    2003-09-17

    The United States (U.S.) Department of Energy (DOE) Carlsbad Field Office (CBFO) and Washington TRU Solutions LLC (WTS) are dedicated to maintaining high quality management of Waste Isolation Pilot Plant (WIPP) environmental resources. DOE Order 5400.1, General Environmental Protection Program, and DOE Order 231.1, Environment, Safety, and Health Reporting, require that the environment at and near DOE facilities be monitored to ensure the safety and health of the public and the environment. This Waste Isolation Pilot Plant 2002 Site Environmental Report summarizes environmental data from calendar year 2002 that characterize environmental management performance and demonstrate compliance with federal and state regulations. This report was prepared in accordance with DOE Order 5400.1, DOE Order 231.1, and Guidance for the Preparation of DOE Annual Site Environmental Reports (ASERs) for Calendar Year 2002 (DOE Memorandum EH-41: Natoli:6-1336, April 4, 2003). These Orders and the guidance document require that DOE facilities submit an annual site environmental report to DOE Headquarters, Office of the Assistant Secretary for Environment, Safety, and Health; and the New Mexico Environment Department (NMED).

  12. Waste Isolation Pilot Plant 2001 Site Environmental Report

    International Nuclear Information System (INIS)

    Westinghouse TRU Solutions, Inc.

    2002-01-01

    The United States (U.S.) Department of Energy's (DOE) Carlsbad Field Office (CBFO) and Westinghouse TRU Solutions LLC (WTS) are dedicated to maintaining high quality management of Waste Isolation Pilot Plant (WIPP) environmental resources. DOE Order 5400.1, General Environmental Protection Program, and DOE Order 231.1, Environmental, Safety, and Health Reporting, require that the environment at and near DOE facilities be monitored to ensure the safety and health of the public and the environment. This Waste Isolation Pilot Plant 2001 Site Environmental Report summarizes environmental data from calendar year (CY) 2001 that characterize environmental management performance and demonstrate compliance with federal and state regulations. This report was prepared in accordance with DOE Order 5400.1, DOE Order 231.1, the Environmental Regulatory Guide for Radiological Effluent Monitoring and Environmental Surveillance (DOE/EH- 0173T), and the Waste Isolation Pilot Plant Environmental Protection Implementation Plan (DOE/WIPP 96-2199). The above Orders and guidance documents require that DOE facilities submit an annual site environmental report to DOE Headquarters, Office of the Assistant Secretary for Environment, Safety, and Health; and the New Mexico Environment Department (NMED). The purpose of this report is to provide a comprehensive description of operational environmental monitoring activities, to provide an abstract of environmental activities conducted to characterize site environmental management performance to confirm compliance with environmental standards and requirements, and to highlight significant programs and efforts of environmental merit at WIPP during CY 2001. WIPP received its first shipment of waste on March 26, 1999. In 2001, no evidence was found of any adverse effects from WIPP on the surrounding environment

  13. Waste Isolation Pilot Plant 1999 Site Environmental Report

    Energy Technology Data Exchange (ETDEWEB)

    Evans, Roy B.; Adams, Amy; Martin, Don; Morris, Randall C.; Reynolds, Timothy D.; Warren, Ronald W.

    2000-09-30

    The U.S. Department of Energy's (DOE)Carlsbad Area Office and the Westinghouse Waste Isolation Division (WID) are dedicated to maintaining high quality management of Waste Isolation Pilot Plant (WIPP) environmental resources. DOE Order 5400.1, General Environmental Protection Program, and DOE Order 231.1, Environmental, Safety, and Health Reporting, require that the environment at and near DOE facilities be monitored to ensure the safety and health of the public and the environment. This Waste Isolation Pilot Plant 1999 Site Environmental Report summarizes environmental data from calendar year 1999 that characterize environmental management performance and demonstrate compliance with federal and state regulations. This report was prepared in accordance with DOE Order 5400.1, DOE Order 231.1, the Environmental Regulatory Guide for Radiological Effluent Monitoring and Environmental Surveillance (DOE/EH- 0173T), and the Waste Isolation Pilot Plant Environmental Protection Implementation Plan (DOE/WIPP 96-2199). The above orders and guidance documents require that DOE facilities submit an Annual Site Environmental Report to DOE Headquarters, Office of the Assistant Secretary for Environment, Safety, and Health. The purpose of this report is to provide a comprehensive description of operational environmental monitoring activities, to provide an abstract of environmental activities conducted to characterize site environmental management performance to confirm compliance with environmental standards and requirements, and to highlight significant programs and efforts of environmental merit at WIPP during calendar year 1999. WIPP received its first shipment of waste on March 26, 1999. In 1999, no evidence was found of any adverse effects from WIPP on the surrounding environment. Radionuclide concentrations in the environment surrounding WIPP were not statistically higher in 1999 than in 1998.

  14. Waste Isolation Pilot Plant 2001 Site Environmental Report

    Energy Technology Data Exchange (ETDEWEB)

    Westinghouse TRU Solutions, Inc.

    2002-09-20

    The United States (U.S.) Department of Energy's (DOE) Carlsbad Field Office (CBFO) and Westinghouse TRU Solutions LLC (WTS) are dedicated to maintaining high quality management of Waste Isolation Pilot Plant (WIPP) environmental resources. DOE Order 5400.1, General Environmental Protection Program, and DOE Order 231.1, Environmental, Safety, and Health Reporting, require that the environment at and near DOE facilities be monitored to ensure the safety and health of the public and the environment. This Waste Isolation Pilot Plant 2001 Site Environmental Report summarizes environmental data from calendar year (CY) 2001 that characterize environmental management performance and demonstrate compliance with federal and state regulations. This report was prepared in accordance with DOE Order 5400.1, DOE Order 231.1, the Environmental Regulatory Guide for Radiological Effluent Monitoring and Environmental Surveillance (DOE/EH- 0173T), and the Waste Isolation Pilot Plant Environmental Protection Implementation Plan (DOE/WIPP 96-2199). The above Orders and guidance documents require that DOE facilities submit an annual site environmental report to DOE Headquarters, Office of the Assistant Secretary for Environment, Safety, and Health; and the New Mexico Environment Department (NMED). The purpose of this report is to provide a comprehensive description of operational environmental monitoring activities, to provide an abstract of environmental activities conducted to characterize site environmental management performance to confirm compliance with environmental standards and requirements, and to highlight significant programs and efforts of environmental merit at WIPP during CY 2001. WIPP received its first shipment of waste on March 26, 1999. In 2001, no evidence was found of any adverse effects from WIPP on the surrounding environment.

  15. Site characterization and monitoring data from Area 5 Pilot Wells, Nevada Test Site, Nye County, Nevada

    International Nuclear Information System (INIS)

    1994-02-01

    The Special Projects Section (SPS) of Reynolds Electrical ampersand Engineering Co., Inc. (REECO) is responsible for characterizing the subsurface geology and hydrology of the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada Test Site (NTS) for the US Department of Energy, Nevada Operations Office (DOE/NV), Environmental Restoration and Waste Management Division, Waste Operations Branch. The three Pilot Wells that comprise the Pilot Well Project are an important part of the Area 5 Site Characterization Program designed to determine the suitability of the Area 5 RWMS for disposal of low-level waste (LLW), mixed waste (MW), and transuranic waste (TRU). The primary purpose of the Pilot Well Project is two-fold: first, to characterize important water quality and hydrologic properties of the uppermost aquifer; and second, to characterize the lithologic, stratigraphic, and hydrologic conditions which influence infiltration, redistribution, and percolation, and chemical transport through the thick vadose zone in the vicinity of the Area 5 RWMS. This report describes Pilot Well drilling and coring, geophysical logging, instrumentation and stemming, laboratory testing, and in situ testing and monitoring activities

  16. Active sites of ligand-protected Au25 nanoparticle catalysts for CO2 electroreduction to CO

    Science.gov (United States)

    Alfonso, Dominic R.; Kauffman, Douglas; Matranga, Christopher

    2016-05-01

    Recent experimental studies have reported the electrochemical reduction of carbon dioxide (CO2) into CO at atomically precise negatively charged Au25- nanoclusters. The studies showed CO2 conversion at remarkably low overpotentials, but the exact mechanisms and nature of the active sites remain unclear. We used first-principles density functional theory and continuum solvation models to examine the role of the cluster during electrochemical CO2 reduction and analyze the free energies of proposed intermediate species. Contrary to previous assumptions, our results show that the fully ligand protected cluster is not an active CO2 reduction catalyst because formation of the crucial carboxyl intermediate required very high electrochemical potentials. Instead, our calculations suggest that the reduction process likely occurs on a dethiolated gold site, and adsorbed carboxyl intermediate formation was significantly stabilized at dethiolated gold sites. These findings point to the crucial role of exposed metal sites during electrochemical CO2 reduction at gold nanocluster catalysts.

  17. The Pt site reactivity of the molecular graphs of Au6Pt isomers

    Science.gov (United States)

    Xu, Tianlv; Jenkins, Samantha; Xiao, Chen-Xia; Maza, Julio R.; Kirk, Steven R.

    2013-12-01

    Within the framework of the theory of atoms in molecules (QTAIM), in an exploratory study we propose a new measure of site reactivity equivalent to the atomic coordination number based purely on the electronic structure. It was found that the number of ring critical points (NNRCPs) positioned on the boundary of the atomic basin of the dopant (Pt) nucleus correlated very well with the relative zero point energy (ZPE) corrected energies. A weaker condition (i.e. than the number of associated bond paths) for the association of the dopant Pt nucleus with the Au6Pt molecular graph is found for NNRCP = 0.

  18. Waste Isolation Pilot Plant Annual Site Environmental Report for 2016

    Energy Technology Data Exchange (ETDEWEB)

    Ward, Anderson [Carlsbad Field Office (CBFO), NM (United States); Basabilvazo, George T. [Carlsbad Field Office (CBFO), NM (United States)

    2017-09-01

    The purpose of the Waste Isolation Pilot Plant (WIPP) Annual Site Environmental Report for 2016 (ASER) is to provide the information required by U.S. Department of Energy (DOE) Order 231.1B, Environment, Safety, and Health Reporting. The DOE Carlsbad Field Office (CBFO) and the management and operating contractor (MOC) maintain and preserve the environmental resources at the WIPP facility. DOE Order 231.1B; DOE Order 436.1, Departmental Sustainability; and DOE Order 458.1, Radiation Protection of the Public and the Environment, require that the affected environment at and near DOE facilities be monitored to ensure the safety and health of the public and workers, and preservation of the environment. This report was prepared in accordance with DOE Order 231.1B, which requires DOE facilities to submit an ASER to the DOE Headquarters Chief Health, Safety, and Security Officer.

  19. Waset Isolation Pilot Plant Annual Site Environmental Report for 2006

    International Nuclear Information System (INIS)

    2007-01-01

    The purpose of the Waste Isolation Pilot Plant Annual Site Environmental Report for 2006 (ASER) is to provide information required by U.S. Department of Energy (DOE) Order 231.1A, Environment, Safety, and Health Reporting. Specifically, the ASER presents summary environmental data that: (a) Characterize site environmental management performance; (b) Summarize environmental occurrences and responses reported during the calendar year; (c) Confirm compliance with environmental standards and requirements; and (d) Highlight significant facility programs and efforts. The DOE Carlsbad Field Office (CBFO) and Washington TRU Solutions LLC (WTS) maintain and preserve the environmental resources at the WIPP site. DOE Order 231.1A; DOE Order 450.1, Environmental Protection Program; and DOE Order 5400.5, Radiation Protection of the Public and Environment, require that the affected environment at and near DOE facilities be monitored to ensure the safety and health of the public and the environment. This report was prepared in accordance with DOE Order 231.1A. This order requires that DOE facilities submit an ASER to the DOE Headquarters Office of the Assistant Secretary for Environment, Safety, and Health. The WIPP Hazardous Waste Facility Permit (HWFP) (No. NM4890139088-TSDF [treatment, storage, and disposal facility]) further requires that the ASER be provided to the New Mexico Environment Department (NMED).

  20. Waset Isolation Pilot Plant Annual Site Environmental Report for 2006

    Energy Technology Data Exchange (ETDEWEB)

    Washington Regulatory and Environmental Services; Washington TRU Solutions LLC

    2007-09-26

    The purpose of the Waste Isolation Pilot Plant Annual Site Environmental Report for 2006 (ASER) is to provide information required by U.S. Department of Energy (DOE) Order 231.1A, Environment, Safety, and Health Reporting. Specifically, the ASER presents summary environmental data that: (a) Characterize site environmental management performance; (b) Summarize environmental occurrences and responses reported during the calendar year; (c) Confirm compliance with environmental standards and requirements; and (d) Highlight significant facility programs and efforts. The DOE Carlsbad Field Office (CBFO) and Washington TRU Solutions LLC (WTS) maintain and preserve the environmental resources at the WIPP site. DOE Order 231.1A; DOE Order 450.1, Environmental Protection Program; and DOE Order 5400.5, Radiation Protection of the Public and Environment, require that the affected environment at and near DOE facilities be monitored to ensure the safety and health of the public and the environment. This report was prepared in accordance with DOE Order 231.1A. This order requires that DOE facilities submit an ASER to the DOE Headquarters Office of the Assistant Secretary for Environment, Safety, and Health. The WIPP Hazardous Waste Facility Permit (HWFP) (No. NM4890139088-TSDF [treatment, storage, and disposal facility]) further requires that the ASER be provided to the New Mexico Environment Department (NMED).

  1. Sites of Au atoms in Sn crystals as determined by channeling

    International Nuclear Information System (INIS)

    Miller, J.W.; Gemmell, D.S.; Holland, R.E.; Poizat, J.C.; Worthington, J.N.; Loess, R.E.

    1974-01-01

    The position of Au atoms diffused into Sn monocrystals has been studied by channeling and backscattering of 2.5-MeV Ne ions. For equilibrium conditions at 217 0 C, Au atoms are found almost entirely in substitutional positions, so that the unusually fast diffusion of Au in Sn most likely arises from a small fraction of Au atoms migrating interstitially

  2. Waste Isolation Pilot Plant Annual Site Environmental Report for 2010

    International Nuclear Information System (INIS)

    2011-01-01

    The purpose of the Waste Isolation Pilot Plant (WIPP) Annual Site Environmental Report for 2010 (ASER) is to provide information required by U.S. Department of Energy (DOE) Order 231.1A, Environment, Safety, and Health Reporting. Specifically, the ASER presents summary environmental data to: (1) Characterize site environmental management performance. (2) Summarize environmental occurrences and responses reported during the calendar year. (3) Confirm compliance with environmental standards and requirements. (4) Highlight significant environmental accomplishments, including progress toward the DOE Environmental Sustainability Goals made through implementation of the WIPP Environmental Management System (EMS). The DOE Carlsbad Field Office (CBFO) and the management and operating contractor (MOC), Washington TRU Solutions LLC (WTS), maintain and preserve the environmental resources at the WIPP. DOE Order 231.1A; DOE Order 450.1A, Environmental Protection Program; and DOE Order 5400.5, Radiation Protection of the Public and the Environment, require that the affected environment at and near DOE facilities be monitored to ensure the safety and health of the public and workers, and preservation of the environment. This report was prepared in accordance with DOE Order 231.1A, which requires that DOE facilities submit an ASER to the DOE Headquarters Chief Health, Safety, and Security Officer. The WIPP Hazardous Waste Facility Permit Number NM4890139088-TSDF (Permit) further requires that the ASER be provided to the New Mexico Environment Department (NMED).

  3. Waste Isolation Pilot Plant Annual Site Environmental Report for 2010

    Energy Technology Data Exchange (ETDEWEB)

    None

    2011-09-01

    The purpose of the Waste Isolation Pilot Plant (WIPP) Annual Site Environmental Report for 2010 (ASER) is to provide information required by U.S. Department of Energy (DOE) Order 231.1A, Environment, Safety, and Health Reporting. Specifically, the ASER presents summary environmental data to: (1) Characterize site environmental management performance. (2) Summarize environmental occurrences and responses reported during the calendar year. (3) Confirm compliance with environmental standards and requirements. (4) Highlight significant environmental accomplishments, including progress toward the DOE Environmental Sustainability Goals made through implementation of the WIPP Environmental Management System (EMS). The DOE Carlsbad Field Office (CBFO) and the management and operating contractor (MOC), Washington TRU Solutions LLC (WTS), maintain and preserve the environmental resources at the WIPP. DOE Order 231.1A; DOE Order 450.1A, Environmental Protection Program; and DOE Order 5400.5, Radiation Protection of the Public and the Environment, require that the affected environment at and near DOE facilities be monitored to ensure the safety and health of the public and workers, and preservation of the environment. This report was prepared in accordance with DOE Order 231.1A, which requires that DOE facilities submit an ASER to the DOE Headquarters Chief Health, Safety, and Security Officer. The WIPP Hazardous Waste Facility Permit Number NM4890139088-TSDF (Permit) further requires that the ASER be provided to the New Mexico Environment Department (NMED).

  4. Waste Isolation Pilot Plant Annual Site Enviromental Report for 2008

    International Nuclear Information System (INIS)

    2009-01-01

    The purpose of the Waste Isolation Pilot Plant Annual Site Environmental Report for 2008 (ASER) is to provide information required by U.S. Department of Energy (DOE) Order 231.1A, Environment, Safety, and Health Reporting. Specifically, the ASER presents summary environmental data to characterize site environmental management performance; summarize environmental occurrences and responses reported during the calendar year; confirm compliance with environmental standards and requirements; highlight significant facility programs and efforts; and describe how compliance and environmental improvement is accomplished through the WIPP Environmental Management System (EMS). The DOE Carlsbad Field Office (CBFO) and the management and operating contractor (MOC), Washington TRU Solutions LLC (WTS), maintain and preserve the environmental resources at the Waste Isolation Pilot Plant (WIPP). DOE Order 231.1A; DOE Order 450.1A, Environmental Protection Program; and DOE Order 5400.5, Radiation Protection of the Public and the Environment, require that the affected environment at and near DOE facilities be monitored to ensure the safety and health of the public and workers, and preservation of the environment. This report was prepared in accordance with DOE Order 231.1A, which requires that DOE facilities submit an ASER to the DOE Headquarters Chief Health, Safety, and Security Officer. The WIPP Hazardous Waste Facility Permit (HWFP) Number NM4890139088-TSDF (treatment, storage, and disposal facility) further requires that the ASER be provided to the New Mexico Environment Department (NMED). The WIPP mission is to safely dispose of transuranic (TRU) radioactive waste generated by the production of nuclear weapons and other activities related to the national defense of the United States. In 2008, 5,265 cubic meters (m3) of TRU waste were disposed of at the WIPP facility, including 5,216 m3 of contact-handled (CH) TRU waste and 49 m3 of remote-handled (RH) TRU waste. From the first

  5. Waste Isolation Pilot Plant Annual Site Enviromental Report for 2008

    Energy Technology Data Exchange (ETDEWEB)

    Washington Regulatory and Enviromnetal Services

    2009-09-21

    The purpose of the Waste Isolation Pilot Plant Annual Site Environmental Report for 2008 (ASER) is to provide information required by U.S. Department of Energy (DOE) Order 231.1A, Environment, Safety, and Health Reporting. Specifically, the ASER presents summary environmental data to characterize site environmental management performance; summarize environmental occurrences and responses reported during the calendar year; confirm compliance with environmental standards and requirements; highlight significant facility programs and efforts; and describe how compliance and environmental improvement is accomplished through the WIPP Environmental Management System (EMS). The DOE Carlsbad Field Office (CBFO) and the management and operating contractor (MOC), Washington TRU Solutions LLC (WTS), maintain and preserve the environmental resources at the Waste Isolation Pilot Plant (WIPP). DOE Order 231.1A; DOE Order 450.1A, Environmental Protection Program; and DOE Order 5400.5, Radiation Protection of the Public and the Environment, require that the affected environment at and near DOE facilities be monitored to ensure the safety and health of the public and workers, and preservation of the environment. This report was prepared in accordance with DOE Order 231.1A, which requires that DOE facilities submit an ASER to the DOE Headquarters Chief Health, Safety, and Security Officer. The WIPP Hazardous Waste Facility Permit (HWFP) Number NM4890139088-TSDF (treatment, storage, and disposal facility) further requires that the ASER be provided to the New Mexico Environment Department (NMED). The WIPP mission is to safely dispose of transuranic (TRU) radioactive waste generated by the production of nuclear weapons and other activities related to the national defense of the United States. In 2008, 5,265 cubic meters (m3) of TRU waste were disposed of at the WIPP facility, including 5,216 m3 of contact-handled (CH) TRU waste and 49 m3 of remote-handled (RH) TRU waste. From the first

  6. Tenure Issues in REDD+ Pilot Project Sites in Tanzania

    Directory of Open Access Journals (Sweden)

    Therese Dokken

    2014-02-01

    Full Text Available REDD+ has been proposed as a viable option for addressing climate change in the near term, and at relatively low cost. There is a broad consensus that clearly defined tenure rights are important for the implementation and success of REDD+, both to manage forests effectively and to protect local communities’ livelihoods. We use primary data from 23 villages in six REDD+ pilot sites in Tanzania to identify causes of deforestation and forest degradation, and tenure rights issues, at the village level prior to project implementation. Further, interviews with project proponents and examination of project documents yields insights into how the proponents plan to address tenure issues. Most villages perceive their tenure as secure and have exclusion rights, while collective action challenges are prevalent in villages experiencing deforestation and forest degradation. These findings suggest that the main tenure issues are related to internal institutional arrangements. While we find that tenure is high on the agenda for all the project proponents, they are mainly focusing on formalization and securing tenure rights from state to community level. Though we do find this to be a precondition for reducing deforestation and degradation, some of their focus should be shifted to strengthening village institutions and enhancing internal compliance.

  7. Restoring of offshore wind farm sites. Lillgrund Pilot Project; Aaterstaellande av havsbaserad vindkraft. Lillgrund Pilot Projekt

    Energy Technology Data Exchange (ETDEWEB)

    Stumle Wikander, Jhenny (Vattenfall Vindkraft AB, Stockholm (Sweden))

    2009-02-15

    This report focuses on the legal aspects of decommissioning and restoring of offshore wind farm sites, as part of an extensive report on the Lillgrund Offshore Wind Farm Pilot Project. For this analysis, all permit conditions of the granted permits for the offshore wind parks in Sweden have been collected and studied. According to the Swedish Environmental code 'the validity of a permit, approval or exemption may be made subject to the requirement that the person who intends to pursue the activity must furnish a security for the costs of after-treatment and any other restoration measures that may be necessary as a result. The state, municipalities, county councils and associations of municipalities shall not be required to furnish a security. If there is cause to assume that the security furnished is no longer sufficient, the authority which is considering the application for a permit, approval or exemption may require an additional security to be furnished'. The permits show that different types of securities are being used, with bank warranties and securities being the most common. Securities are either fixed and furnished prior to start of construction or start of operations, or they are obtained gradually over the life of the project. Among the twelve permits studied, a gradual tendency to use a combination of the two alternatives can bee seen. The conditions governing when an offshore wind farm is to be discontinued and which parts need to be partly or fully removed from the site are obviously of future importance. The issue has been addressed to different degrees in the permits, some to a clear legal extent, while others are more general. The Lillgrund Offshore Wind Farm was secured for 60 million SEK. The extent to which the park is to be decommissioned and the site to be restored is decided by the county administrative board once production is terminated

  8. Using a Full Complex Site Transfer Function to Estimate Strong Ground Motion in Port-au-Prince (Haiti).

    Science.gov (United States)

    ST Fleur, S.; Courboulex, F.; Bertrand, E.; Mercier De Lepinay, B. F.; Hough, S. E.; Boisson, D.; Momplaisir, R.

    2017-12-01

    To assess the possible impact of a future earthquake in the urban area of Port-au-Prince (Haiti), we have implemented a simulation approach for complex ground motions produced by an earthquake. To this end, we have integrated local site effect in the prediction of strong ground motions in Port-au-Prince using the complex transfer functions method, which takes into account amplitude changes as well as phase changes. This technique is particularly suitable for basins where a conventional 1D digital approach proves inadequate, as is the case in Port-au-Prince. To do this, we use the results of the Standard Spectral Ratio (SSR) approach of St Fleur et al. (2016) to estimate the amplitude of the response of the site to a nearby rock site. Then, we determine the phase difference between sites, interpreted as changes in the phase of the signal related to local site conditions, using the signals of the 2010 earthquake aftershocks records. Finally, the accelerogram of the simulated earthquake is obtain using the technique of the inverse Fourier transform. The results of this study showed that the strongest soil motions are expected in neighborhoods of downtown Port-au-Prince and adjacent hills. In addition, this simulation method by complex transfer functions was validated by comparison with recorded actual data. Our simulated response spectra reproduce very well both the amplitude and the shape of the response spectra of recorded earthquakes. This new approach allowed to reproduce the lengthening of the signal that could be generated by surface waves at certain stations in the city of Port-au-Prince. However, two points of vigilance must be considered: (1) a good signal-to-noise ratio is necessary to obtain a robust estimate of the site-reference phase shift (ratio at least equal to 10); (2) unless the amplitude and phase changes are measured on strong motion records, this technique does not take non-linear effects into account.

  9. Bioventing Pilot Test Work Plan for Site ST200 (SA38), McClellan Air Force Base, California

    National Research Council Canada - National Science Library

    1997-01-01

    This Bioventing Pilot Test Work Plan presents the scope of an in situ bioventing pilot test and installation of a bioventing system for treatment of petroleum hydrocarbon-contaminated soils at Site...

  10. SHIRCO PILOT-SCALE INFRARED INCINERATION SYSTEM AT THE ROSE TOWNSHIP DEMODE ROAD SUPERFUND SITE

    Science.gov (United States)

    Under the Superfund Innovative Technology Evaluation or SITE Program, an evaluation was made of the Shirco Pilot-Scale Infrared Incineration System during 17 separate test runs under varying operating conditions. The tests were conducted at the Demode Road Superfund site in Ros...

  11. Hanford site as it relates to an alternative site for the Waste Isolation Pilot Plant: an environmental description

    Energy Technology Data Exchange (ETDEWEB)

    Fecht, K.R. (ed.)

    1978-12-01

    The use of basalt at Hanford as an alternative for the Waste Isolation Pilot Plant (WIPP) would require that the present Basalt Waste Isolation Program (BWIP) at Hanford be expanded to incorporate the planned WIPP functions, namely the permanent storage of transuranic (TRU) wastes. This report discusses: program costs, demography, ecology, climatology, physiography, hydrology, geology, seismology, and historical and archeological sites. (DLC)

  12. Hanford site as it relates to an alternative site for the Waste Isolation Pilot Plant: an environmental description

    International Nuclear Information System (INIS)

    Fecht, K.R.

    1978-12-01

    The use of basalt at Hanford as an alternative for the Waste Isolation Pilot Plant (WIPP) would require that the present Basalt Waste Isolation Program (BWIP) at Hanford be expanded to incorporate the planned WIPP functions, namely the permanent storage of transuranic (TRU) wastes. This report discusses: program costs, demography, ecology, climatology, physiography, hydrology, geology, seismology, and historical and archeological sites

  13. Site evaluation for the Waste Isolation Pilot Plant (WIPP)

    International Nuclear Information System (INIS)

    Hill, L.R.

    1979-01-01

    Preliminary site selection activities for the WIPP are complete now; these consisted primarily of national and regional studies over the past fifteen years, and resulted in selection of the WIPP study area for geological characterization. The work of geological characterization should be considered to have begun with the drilling of ERDA 9 at the center of the WIPP study area and the initiation of seismic reflection work on the site. That geological characterization, which is primarily oriented to provide specific data concerning the present geology of the site, was virtually complete in December, 1978, when the Geological Characterization Report was submitted to the Department of Energy; much basic information has been gathered indicating no major technical problems with the site as it is now understood. Studies of long-term processes which might affect a repository or have an effect on safety analyses will now be the major geotechnical activity for the WIPP site evaluation team, some of these activities are already underway. These studies will deal with the age of significant features and the rates and processes which produce those features. The information so gained will be useful in increasing the confidence in evaluation of the safety of a repository

  14. Interpreting sensor measurements in dikes - experiences from UrbanFlood pilot sites

    NARCIS (Netherlands)

    Simm, J.; Jordan, D.; Topple, A.; Mokhov, I.; Pyayt, A.; Abdoun, T.; Bennett, V.; Broekhuijsen, J.; Meijer, R.; Klijn, F.; Schweckendiek, T.

    2012-01-01

    The UrbanFlood project is creating an Early Warning System framework that can be used to link sensors via the Internet to predictive models and emergency warning systems. The project includes four pilot sites to apply and validate at full scale the technology being developed in the project:

  15. Hydraulic testing of Salado Formation evaporites at the Waste Isolation Pilot Plant site: Second interpretive report

    Energy Technology Data Exchange (ETDEWEB)

    Beauheim, R.L. [Sandia National Labs., Albuquerque, NM (United States); Roberts, R.M.; Dale, T.F.; Fort, M.D.; Stensrud, W.A. [INTERA, Inc., Austin, TX (United States)

    1993-12-01

    Pressure-pulse, constant-pressure flow, and pressure-buildup tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Transmissivities have been interpreted from six sequences of tests conducted on five stratigraphic intervals within 15 m of the WIPP underground excavations.

  16. Hydraulic testing of Salado Formation evaporites at the Waste Isolation Pilot Plant site: Second interpretive report

    International Nuclear Information System (INIS)

    Beauheim, R.L.; Roberts, R.M.; Dale, T.F.; Fort, M.D.; Stensrud, W.A.

    1993-12-01

    Pressure-pulse, constant-pressure flow, and pressure-buildup tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Transmissivities have been interpreted from six sequences of tests conducted on five stratigraphic intervals within 15 m of the WIPP underground excavations

  17. Waste Isolation Pilot Plant (WIPP) site gravity survey and interpretation

    International Nuclear Information System (INIS)

    Barrows, L.J.; Fett, J.D.

    1983-04-01

    A portion of the WIPP site has been extensively surveyed with high-precision gravity. The main survey (in T22S, R31E) covered a rectangular area 2 by 4-1/3 mi encompassing all of WIPP site Zone II and part of the disturbed zone to the north of the site. Stations were at 293-ft intervals along 13 north-south lines 880 ft apart. The data are considered accurate to within a few hundredths of a milligal. Long-wavelength gravity anomalies correlate well with seismic time structures on horizons below the Castile Formation. Both the gravity anomalies and the seismic time structures are interpreted as resulting from related density and velocity variations within the Ochoan Series. Shorter wavelength negative gravity anomalies are interpreted as resulting from bulk density alteration in the vicinity of karst conduits. The WIPP gravity survey was unable to resolve low-amplitude, long-wavelength anomalies that should result from the geologic structures within the disturbed zone. It did indicate the degree and character of karst development within the surveyed area

  18. Estimation of Wave Conditions at Svåheia SSG Pilot Site

    DEFF Research Database (Denmark)

    Kofoed, Jens Peter; Margheritini, Lucia; Stratigaki, V.

    The purpose of the project described in the present report is to estimate the local wave conditions at the proposed location for a SSG pilot at the Svåheia site in the south western part of Norway. Focus is put on estimating the everyday conditions to enable an evaluation of the power production...... potential for the SSG pilot at the proposed location. The work in the project has been performed in three parts: 1. Establishing the offshore wave conditions and bathymetry of the area. 2. Transformation of offshore waves to near shore, through numerical wave modeling. 3. Evaluation of the transformed...... (local) wave conditions and its implications....

  19. Ground Characterization Studies in Canakkale Pilot Site of LIQUEFACT Project

    Science.gov (United States)

    Ozcep, F.; Oztoprak, S.; Aysal, N.; Bozbey, I.; Tezel, O.; Ozer, C.; Sargin, S.; Bekin, E.; Almasraf, M.; Cengiz Cinku, M.; Ozdemir, K.

    2017-12-01

    The our aim is to outline the ground characterisation studies in Canakkale test site. Study is based on the EU H2020 LIQUEFACT project entitled "Liquefact: Assessment and mitigation of liquefaction potential across Europe: a holistic approach to protect structures / infrastructures for improved resilience to earthquake-induced liquefaction disasters". Objectives and extent of ground characterization for Canakkale test site includes pre-existing soil investigation studies and complementary field studies. There were several SPT and geophysical tests carried out in the study area. Within the context of the complementary tests, six (6) study areas in the test site were chosen and complementary tests were carried out in these areas. In these areas, additional boreholes were opened and SPT tests were performed. It was decided that additional CPT (CPTU and SCPT) and Marchetti Dilatometer (DMT) tests should be carried out within the scope of the complementary testing. Seismic refraction, MASW and micro tremor measurements had been carried out in pre-existing studies. Shear wave velocities obtained from MASW measurements were evaluated to the most rigorous level. These tests were downhole seismic, PS-logging, seismic refraction, 2D-ReMi, MASW, micro tremor (H/V Nakamura method), 2D resistivity and resonance acoustic profiling (RAP). RAP is a new technique which will be explained briefly in the relevant section. Dynamic soil properties had not been measured in pre-existing studies, therefore these properties were investigated within the scope of the complementary tests. Selection of specific experimental tests of the complementary campaign was based on cost-benefit considerations Within the context of complementary field studies, dynamic soil properties were measured using resonant column and cyclic direct shear tests. Several sieve analyses and Atterberg Limits tests which were documented in the pre-existing studies were evaluated. In the complementary study carried out

  20. Site-Selective Carving and Co-Deposition: Transformation of Ag Nanocubes into Concave Nanocrystals Encased by Au-Ag Alloy Frames.

    Science.gov (United States)

    Ahn, Jaewan; Wang, Daniel; Ding, Yong; Zhang, Jiawei; Qin, Dong

    2018-01-23

    We report a facile synthesis of Ag nanocubes with concave side faces and Au-Ag alloy frames, namely Ag@Au-Ag concave nanocrystals, by titrating HAuCl 4 solution into an aqueous mixture of Ag nanocubes, ascorbic acid (H 2 Asc), NaOH, and cetyltrimethylammonium chloride (CTAC) at an initial pH of 11.6 under ambient conditions. Different from all previous studies involving poly(vinylpyrrolidine), the use of CTAC at a sufficiently high concentration plays an essential role in carving away Ag atoms from the side faces through galvanic replacement. Concurrent co-deposition of Au and Ag atoms via chemical reduction at orthogonal sites on the surface of Ag nanocubes leads to the generation of Ag@Au-Ag concave nanocrystals with well-defined and controllable structures. Specifically, in the presence of CTAC-derived Cl - ions, the titrated HAuCl 4 is maintained in the AuCl 4 - species, enabling its galvanic replacement with the Ag atoms located on the side faces of nanocubes. The released Ag + ions can be retained in the soluble form of AgCl 2 - by complexing with the Cl - ions. Both the AuCl 4 - and AgCl 2 - in the solution are then reduced by ascorbate monoanion, a product of the neutralization reaction between H 2 Asc and NaOH, to Au and Ag atoms for their preferential co-deposition onto the edges and corners of the Ag nanocubes. Compared with Ag nanocubes, the Ag@Au-Ag concave nanocrystals exhibit much stronger SERS activity at an excitation of 785 nm, making it feasible to monitor the Au-catalyzed reduction of 4-nitrothiophenol by NaBH 4 in situ. When the Ag cores are removed, the concave nanocrystals evolve into Au-Ag nanoframes with controllable ridge thicknesses.

  1. Waste Isolation Pilot Plant Annual Site Environmental Report for 2014. Emended

    International Nuclear Information System (INIS)

    2015-01-01

    The purpose of the Waste Isolation Pilot Plant (WIPP) Annual Site Environmental Report for 2014 (ASER) is to provide information required by U.S. Department of Energy (DOE) Order 231.1B, Environment, Safety, and Health Reporting. Specifically, the ASER presents summary environmental data to: Characterize site environmental management performance; Summarize environmental occurrences and responses reported during the calendar year (CY); Confirm compliance with environmental standards and requirements; Highlight significant environmental accomplishments, including progress toward the DOE environmental sustainability goals made through implementation of the WIPP Environmental Management System (EMS).

  2. Waste Isolation Pilot Plant Annual Site Environmental Report for 2014. Emended

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2015-09-01

    The purpose of the Waste Isolation Pilot Plant (WIPP) Annual Site Environmental Report for 2014 (ASER) is to provide information required by U.S. Department of Energy (DOE) Order 231.1B, Environment, Safety, and Health Reporting. Specifically, the ASER presents summary environmental data to: Characterize site environmental management performance; Summarize environmental occurrences and responses reported during the calendar year (CY); Confirm compliance with environmental standards and requirements; Highlight significant environmental accomplishments, including progress toward the DOE environmental sustainability goals made through implementation of the WIPP Environmental Management System (EMS).

  3. Radioactive Waste Disposal Pilot Plant concept for a New Mexico site

    International Nuclear Information System (INIS)

    Weart, W.D.

    1976-01-01

    Twenty years of investigation have shown that disposal of nuclear wastes in deep salt formations is the surest means of isolating these wastes from the biosphere for the extremely long period of time required. A large scale demonstration of this capability will soon be provided by a Radioactive Waste Disposal Pilot Plant (RWDPP) to be developed in southeastern New Mexico. Initially, the pilot plant will accept only ERDA generated waste; high level waste from the commercial power reactor fuel cycle will eventually be accommodated in the pilot plant and the initial RWDPP design will be compatible with this waste form. Selection of a specific site and salt horizon will be completed in June 1976. Conceptual design of the RWDPP and assessment of its environmental impact will be completed by June 1977. Construction is expected to start in 1978 with first waste accepted in 1982. The present concept develops disposal areas for all nuclear waste types in a single salt horizon about 800 meters deep. This single level can accommodate all low level and high level waste generated in the United States through the year 2010. A major constraint on the RWDPP design is the ERDA requirement that all waste be ''readily'' retrievable during the duration of pilot plant operation

  4. Public outreach supports the entire life-cycle of the Ketzin pilot site, Germany

    Science.gov (United States)

    Martens, Sonja; Kollersberger, Tanja; Möller, Fabian; Liebscher, Axel

    2017-04-01

    Interdisciplinary research at the Ketzin pilot site in Germany contributes to the understanding of the geological CO2 storage since 2004. In addition to the research activities, public outreach has been a key element through the entire life-cycle of the project including site assessment, characterization, development as well as operation (2008-2013) and post-closure. From the very beginning of the project, the research activities were accompanied by an open dialogue with the general public including locals and interested people from all over Germany and the world. The visitor centre at the Ketzin site is run by GFZ and the most important contact point to inform about first-hand experiences from the project. Up to now, about 3,000 visitors came to the Ketzin site for guided tours and the annual open house days. In addition, project status and progress are disseminated in brochures and on the public website www.co2ketzin.de. The Ketzin project is also presented in short films, e.g. on monitoring, drilling and well closure. As the post-closure and pre-transfer phase started after the cease of CO2 injection in August 2013 and the injection facility was dismantled in December 2013, we were looking for a tool to further inform about the previous operation and site infrastructure. A virtual tour was set up for the Ketzin site which is accessible via the website. This tour includes several videos which virtually guide you on site and provide information on the (former) facilities. Public acceptance is a key issue for the Ketzin project as it is for any other CO2 storage project. For example, an open communication with the local residents helped to conduct large-scale seismic campaigns without severe restrictions. The experience from the Ketzin pilot site shows that honest communication and a diverse dissemination program is able to overcome critical public perception even for highly debated technologies.

  5. Waste Isolation Pilot Plant Site Environmental Report for calendar year 1989

    International Nuclear Information System (INIS)

    1989-01-01

    This is the 1989 Site Environmental Report (SER) for the Waste Isolation Pilot Plant (WIPP) in southeastern New Mexico. The WIPP is a government owned and contractor-operated facility. The WIPP project is operated by Westinghouse Electric Corporation for the US Department of Energy (DOE). The mission of the WIPP is to provide a research and development facility to demonstrate the safe disposal of transuranic (TRU) waste generated by the defense activities of the US Government. This report provides a comprehensive description of environmental activities at the WIPP during calendar year 1989. The WIPP facility will not receive waste until all concerns affecting opening the WIPP are addressed to the satisfaction of the Secretary of Energy. Therefore, this report describes the status of the preoperational activities of the Radiological Environmental Surveillance (RES) program, which are outlined in the Radiological Baseline Program for the Waste Isolation Pilot Plant (WTSD-TME-057). 72 refs., 13 figs., 20 tabs

  6. Awareness of households to the development of wind energy sites - Reporting on a survey; Receptivite des menages au developpement des sites eoliens. Rapport d'enquete

    Energy Technology Data Exchange (ETDEWEB)

    Voisard, M.

    2000-07-01

    This report for the Swiss Federal Office of Energy presents in tables and diagrams the results of a survey involving 421 households in Switzerland, about their awareness to energy issues and, in particular, to all what regards wind energy and wind power plants. Globally, 80% of the persons asked for their opinion believe that electric power demand will continue to increase. 66% of them are in favour of increased use of renewable energy sources and would consequently agree with a 10% more expensive end-user energy price. 89% of the persons taking part to the survey approve the installation of wind energy farms in Switzerland. Moreover, statistics indicates that the households living in regions already equipped with wind farms are significantly more favorable to the creation of new wind energy sites than those not living in these regions. By the end of the day, it turns out that the main reasons for accepting wind energy are environmental concerns as well as the fear of being obliged to use nuclear power. [French] Ce rapport presente par des graphiques et des tableaux le resultat d'un sondage d'opinion aupres de 421 menages en Suisse, sur la sensibilite du public aux problemes de l'energie et plus particulierement sur sa perception de tout ce qui concerne l'energie du vent et son exploitation par l'implantation d'eoliennes. Globalement, 80% des menages pensent que la demande d'energie electrique va poursuivre sa croissance. 66% d'entre eux sont favorables au developpement des energies renouvelables et prets a accepter en consequence une augmentation du prix de l'energie allant jusqu'a 10%. 89% des personnes interrogees sont favorables au developpement des eoliennes en Suisse. De plus, la statistique montre de maniere significative que les menages des regions dans lesquelles sont deja implantes des sites eoliens sont plus favorables au developpement des eoliennes que les autres. Finalement, le respect de l

  7. Awareness of households to the development of wind energy sites - Reporting on a survey; Receptivite des menages au developpement des sites eoliens. Rapport d'enquete

    Energy Technology Data Exchange (ETDEWEB)

    Voisard, M

    2000-07-01

    This report for the Swiss Federal Office of Energy presents in tables and diagrams the results of a survey involving 421 households in Switzerland, about their awareness to energy issues and, in particular, to all what regards wind energy and wind power plants. Globally, 80% of the persons asked for their opinion believe that electric power demand will continue to increase. 66% of them are in favour of increased use of renewable energy sources and would consequently agree with a 10% more expensive end-user energy price. 89% of the persons taking part to the survey approve the installation of wind energy farms in Switzerland. Moreover, statistics indicates that the households living in regions already equipped with wind farms are significantly more favorable to the creation of new wind energy sites than those not living in these regions. By the end of the day, it turns out that the main reasons for accepting wind energy are environmental concerns as well as the fear of being obliged to use nuclear power. [French] Ce rapport presente par des graphiques et des tableaux le resultat d'un sondage d'opinion aupres de 421 menages en Suisse, sur la sensibilite du public aux problemes de l'energie et plus particulierement sur sa perception de tout ce qui concerne l'energie du vent et son exploitation par l'implantation d'eoliennes. Globalement, 80% des menages pensent que la demande d'energie electrique va poursuivre sa croissance. 66% d'entre eux sont favorables au developpement des energies renouvelables et prets a accepter en consequence une augmentation du prix de l'energie allant jusqu'a 10%. 89% des personnes interrogees sont favorables au developpement des eoliennes en Suisse. De plus, la statistique montre de maniere significative que les menages des regions dans lesquelles sont deja implantes des sites eoliens sont plus favorables au developpement des eoliennes que les autres. Finalement, le respect de l'environnement et la crainte d'avoir a recourir a l

  8. TECHNOLOGY EVALUATION REPORT, SITE PROGRAM DEMONSTRATION TEST: SHIRCO PILOT-SCALE INFRARED INCINERATION SYSTEM ROSE TOWNSHIP DEMODE ROAD SUPERFUND SITE - VOLUME II

    Science.gov (United States)

    The performance of the Shirco pilot-scale infrared thermal destruction system has been evaluated at the Rose Township, Demode Road Superfund Site and is presented in the report. The waste tested consisted of solvents, organics and heavy metals in an illegal dump site. Volume I gi...

  9. PART I: Bioventing Pilot Test Work Plan for Fire Protection Training Area Site FY-03, Charleston AFB, South Carolina. PART II: Draft Interim Pilot Test Results Report for Fire Protection Training Area Site FT-03, Charleston AFB, South Carolina

    National Research Council Canada - National Science Library

    1993-01-01

    This site-specific work plan presents the scope of a bioventing pilot test for in situ treatment of fuel contaminated soils at the Fire Protection Training Area designated as Site FT-O3, Charleston Air Force Base (AFB), South Carolina...

  10. Probing properties of the interfacial perimeter sites in TiO x /Au/SiO 2 with 2-propanol decomposition

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Yi Y.; Kung, Harold H. (NWU)

    2017-11-01

    The decomposition of 2-propanol was studied over SiO2, SiO2 with an overlayer of TiO2 (Ti/SiO2), Au/SiO2, and Au/SiO2 with an overlayer of TiO2 (Ti/[Au/SiO2]) at 170–190 °C. There was no reaction on SiO2. Propene was the only product on Ti/SiO2, and its rate of formation increased proportionally with the Ti content. Acetone was the major product (selectivity 65–99%) on all Au-containing catalysts. Its rate of formation also increased with Ti loading. In addition, small amounts of propene were also formed on Ti/[Au/SiO2] the rate of which increased with Ti loading. Characterization of the catalysts with N2 adsorption, STEM, DR-UV-vis spectroscopy, XPS, XANES and EXAFS suggested that the Ti formed an amorphous TiO2 overlayer on the catalyst. At high Ti loadings (4–5 wt.%), there were patches of thick porous TiO2 layer, and some microdomains of crystalline TiO2 could be detected. Au was present as 1–3 nm nanoparticles on all catalysts, before and after used in reaction. Only Lewis acid sites were detected based on results from pyridine adsorption, and their quantities increased with Ti loading. Based on the comparison of reaction rates, the dependence of the kinetics on 2-propanol partial pressure, the apparent activation energies, and the effect of co-feeding O2 among different catalysts, it was concluded that propene was formed on the TiO2 overlayer, acetone was formed primarily at the Au-TiO2 interfacial perimeter sites, and α-C-H bond breaking preceding acetone formation was more facile on Au at the interfacial site than other surface Au atoms. Implication of these results to the selective acetone formation in the oxidation of propane in the presence of a O2/H2 mixture was discussed.

  11. Observation of Au + AuAu + Au + ρ0 and Au + AuAu* + Au* + ρ0 with STAR

    International Nuclear Information System (INIS)

    Spencer, K.

    2002-01-01

    First observation of the reactions Au + AuAu + Au + ρ 0 and Au + AuAu* + Au* + ρ 0 with the STAR detector are reported. The ρ are produced at small perpendicular momentum, as expected if they couple coherently to both nuclei. Models of vector meson production and the correlation with nuclear breakup are discussed, as well as a fundamental test of quantum mechanics that is possible with the system. (author)

  12. Surface complexation modeling of uranyl adsorption on corrensite from the Waste Isolation Pilot Plant Site

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sang-Won; Leckie, J.O. [Stanford Univ., CA (United States); Siegel, M.D. [Sandia National Labs., Albuquerque, NM (United States)

    1995-09-01

    Corrensite is the dominant clay mineral in the Culebra Dolomite at the Waste Isolation Pilot Plant. The surface characteristics of corrensite, a mixed chlorite/smectite clay mineral, have been studied. Zeta potential measurements and titration experiments suggest that the corrensite surface contains a mixture of permanent charge sites on the basal plane and SiOH and AlOH sites with a net pH-dependent charge at the edge of the clay platelets. Triple-layer model parameters were determined by the double extrapolation technique for use in chemical speciation calculations of adsorption reactions using the computer program HYDRAQL. Batch adsorption studies showed that corrensite is an effective adsorbent for uranyl. The pH-dependent adsorption behavior indicates that adsorption occurs at the edge sites. Adsorption studies were also conducted in the presence of competing cations and complexing ligands. The cations did not affect uranyl adsorption in the range studied. This observation lends support to the hypothesis that uranyl adsorption occurs at the edge sites. Uranyl adsorption was significantly hindered by carbonate. It is proposed that the formation of carbonate uranyl complexes inhibits uranyl adsorption and that only the carbonate-free species adsorb to the corrensite surface. The presence of the organic complexing agents EDTA and oxine also inhibits uranyl sorption.

  13. Surface complexation modeling of uranyl adsorption on corrensite from the Waste Isolation Pilot Plant Site

    International Nuclear Information System (INIS)

    Park, Sang-Won; Leckie, J.O.; Siegel, M.D.

    1995-09-01

    Corrensite is the dominant clay mineral in the Culebra Dolomite at the Waste Isolation Pilot Plant. The surface characteristics of corrensite, a mixed chlorite/smectite clay mineral, have been studied. Zeta potential measurements and titration experiments suggest that the corrensite surface contains a mixture of permanent charge sites on the basal plane and SiOH and AlOH sites with a net pH-dependent charge at the edge of the clay platelets. Triple-layer model parameters were determined by the double extrapolation technique for use in chemical speciation calculations of adsorption reactions using the computer program HYDRAQL. Batch adsorption studies showed that corrensite is an effective adsorbent for uranyl. The pH-dependent adsorption behavior indicates that adsorption occurs at the edge sites. Adsorption studies were also conducted in the presence of competing cations and complexing ligands. The cations did not affect uranyl adsorption in the range studied. This observation lends support to the hypothesis that uranyl adsorption occurs at the edge sites. Uranyl adsorption was significantly hindered by carbonate. It is proposed that the formation of carbonate uranyl complexes inhibits uranyl adsorption and that only the carbonate-free species adsorb to the corrensite surface. The presence of the organic complexing agents EDTA and oxine also inhibits uranyl sorption

  14. Superfund Technology Evaluation Report: SITE Program Demonstration Test Shirco Pilot-Scale Infrared Incineration System at the Rose Township Demode Road Superfund Site Volume I

    Science.gov (United States)

    The Shirco Pilot-Scale Infrared Incineration System was evaluated during a series of seventeen test runs under varied operating conditions at the Demode Road Superfund Site located in Rose Township, Michigan. The tests sought to demonstrate the effectiveness of the unit and the t...

  15. Hydraulic Testing of Salado Formation Evaporites at the Waste Isolation Pilot Plant Site: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Beauheim, Richard L.; Domski, Paul S.; Roberts, Randall M.

    1999-07-01

    This report presents interpretations of hydraulic tests conducted in bedded evaporates of the Salado Formation from May 1992 through May 1995 at the Waste Isolation Pilot Plant (WIPP) site in southeastern New Mexico. The WIPP is a US Department of Energy research and development facility designed to demonstrate safe disposal of transuranic wastes from the nation's defense programs. The WIPP disposal horizon is located in the lower portion of the Permian Salado Formation. The hydraulic tests discussed in this report were performed in the WIPP underground facility by INTERA inc. (now Duke Engineering and Services, Inc.), Austin, Texas, following the Field Operations Plan and Addendum prepared by Saulnier (1988, 1991 ) under the technical direction of Sandia National Laboratories, Albuquerque, New Mexico.

  16. Waste Isolation Pilot Plant site environmental report for calendar year 1990

    International Nuclear Information System (INIS)

    1990-01-01

    The US Department of Energy (DOE) Waste Isolation Pilot Plant (WIPP) Operational Environmental Monitoring Plan (OEMP) monitors a comprehensive set of parameters in order to detect any potential environmental impacts and establish baselines for future quantitative environmental impact evaluations. Surface water and groundwater, soil, and biotics are measured for background radiation. Nonradiological environmental monitoring activities include meteorological, air quality, soil properties, and the status of the local biological community. Ecological studies focus on the immediate area surrounding the site with emphasis on the salt storage pile, whereas baseline radiological surveillance covers a broader geographic area including nearby ranches, villages, and cities. Since the WIPP is still in a preoperational state, no waste has been received; therefore, certain elements required by Order DOE 5400.1 are not presented in this report. 15 figs. 19 tabs

  17. Hydraulic Testing of Salado Formation Evaporites at the Waste Isolation Pilot Plant Site: Final Report

    International Nuclear Information System (INIS)

    Beauheim, Richard L.; Domski, Paul S.; Roberts, Randall M.

    1999-01-01

    This report presents interpretations of hydraulic tests conducted in bedded evaporates of the Salado Formation from May 1992 through May 1995 at the Waste Isolation Pilot Plant (WIPP) site in southeastern New Mexico. The WIPP is a US Department of Energy research and development facility designed to demonstrate safe disposal of transuranic wastes from the nation's defense programs. The WIPP disposal horizon is located in the lower portion of the Permian Salado Formation. The hydraulic tests discussed in this report were performed in the WIPP underground facility by INTERA inc. (now Duke Engineering and Services, Inc.), Austin, Texas, following the Field Operations Plan and Addendum prepared by Saulnier (1988, 1991 ) under the technical direction of Sandia National Laboratories, Albuquerque, New Mexico

  18. Waste Isolation Pilot Plant site environmental report for calendar year 1990

    Energy Technology Data Exchange (ETDEWEB)

    1990-01-01

    The US Department of Energy (DOE) Waste Isolation Pilot Plant (WIPP) Operational Environmental Monitoring Plan (OEMP) monitors a comprehensive set of parameters in order to detect any potential environmental impacts and establish baselines for future quantitative environmental impact evaluations. Surface water and groundwater, soil, and biotics are measured for background radiation. Nonradiological environmental monitoring activities include meteorological, air quality, soil properties, and the status of the local biological community. Ecological studies focus on the immediate area surrounding the site with emphasis on the salt storage pile, whereas baseline radiological surveillance covers a broader geographic area including nearby ranches, villages, and cities. Since the WIPP is still in a preoperational state, no waste has been received; therefore, certain elements required by Order DOE 5400.1 are not presented in this report. 15 figs. 19 tabs.

  19. Pilot-scale incineration of comtaminated soils from the drake chemical superfund site. Final report

    International Nuclear Information System (INIS)

    King, C.; Lee, J.W.; Waterland, L.R.

    1993-03-01

    A series of pilot-scale incineration tests were performed at the U.S. Environmental Protection Agency's (EPA's) Incineration Research Facility to evaluate the potential of incineration as an option to treat contaminated soils from the Drake Chemical Superfund site in Lock Haven, Pennsylvania. The soils at the Drake site are reported to be contaminated to varying degrees with various organic constituents and several hazardous constituent trace metals. The purpose of the test program was to evaluate the incinerability of selected site soils in terms of the destruction of contaminant organic constituents and the fate of contaminant trace metals. All tests were conducted in the rotary kiln incineration system at the IRF. Test results show that greater than 99.995 percent principal organic hazardous constituent (POHC) destruction and removal efficiencies (DRE) can be achieved at kiln exit gas temperatures of nominally 816 C (1,500 F) and 538 C (1,000 F). Complete soil decontamination of semivolatile organics was achieved; however, kiln ash levels of three volatile organic constituents remained comparable to soil levels

  20. Waste Isolation Pilot Plant site environmental report, for calendar year 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-09-01

    The U.S. Department of Energy (DOE) Order 5400.1 General Environmental Protection Program, requires DOE facilities, that conduct environmental protection programs, to annually prepare a Site Environmental Report (SER). The purpose of the SER is to provide an abstract of environmental assessments conducted in order to characterize site environmental management performance, to confirm compliance with environmental standards and requirements, and to highlight significant programs and efforts of environmental merit. The content of this SER is not restricted to a synopsis of the required data, in addition, information pertaining to new and continued monitoring and compliance activities during the 1995 calendar year are also included. Data contained in this report are derived from those monitoring programs directed by the Waste Isolation Pilot Plant (WIPP) Environmental Monitoring Plan (EMP). The EMP provides inclusive guidelines implemented to detect potential impacts to the environment and to establish baseline measurements for future environmental evaluations. Surface water, groundwater. air, soil, and biotic matrices are monitored for an array of radiological and nonradiological factors. The baseline radiological surveillance program encompasses a broader geographic area that includes nearby ranches, villages, and cities. Most elements of nonradiological assessments are conducted within the geographic vicinity of the WIPP site.

  1. Waste Isolation Pilot Plant site environmental report for calendar year 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-01

    US Department of Energy (DOE) Order 5400.1 General Environmental Protection Program, requires each DOE facility that conducts significant environmental protection programs to prepare an Annual Site Environmental Report (ASER). The purpose of the ASER is to summarize environmental data in order to characterize site environmental management performance, to confirm compliance with environmental standards and requirements, and to highlight significant programs and efforts. This ASER not only documents the required data, it also documents new and continued monitoring and compliance activities during the 1994 calendar year. Data contained in this report are derived from those monitoring programs directed by the Waste Isolation Pilot Plant (WIPP) Environmental Monitoring Plan (EMP) (DOE/WIPP 94-024). The EMP defines a comprehensive set of parameters that must be monitored to detect potential impacts to the environment and to establish baseline measurements for future environmental evaluations. Surface water, groundwater, air, soil, and biotics are monitored for radiological and nonradiological activity levels. The baseline radiological surveillance program covers the broader geographic area that encompasses nearby ranches, villages, and cities. Nonradiological studies focus on the area immediately surrounding the WIPP site.

  2. Waste Isolation Pilot Plant site environmental report for calendar year 1994

    International Nuclear Information System (INIS)

    1995-06-01

    US Department of Energy (DOE) Order 5400.1 General Environmental Protection Program, requires each DOE facility that conducts significant environmental protection programs to prepare an Annual Site Environmental Report (ASER). The purpose of the ASER is to summarize environmental data in order to characterize site environmental management performance, to confirm compliance with environmental standards and requirements, and to highlight significant programs and efforts. This ASER not only documents the required data, it also documents new and continued monitoring and compliance activities during the 1994 calendar year. Data contained in this report are derived from those monitoring programs directed by the Waste Isolation Pilot Plant (WIPP) Environmental Monitoring Plan (EMP) (DOE/WIPP 94-024). The EMP defines a comprehensive set of parameters that must be monitored to detect potential impacts to the environment and to establish baseline measurements for future environmental evaluations. Surface water, groundwater, air, soil, and biotics are monitored for radiological and nonradiological activity levels. The baseline radiological surveillance program covers the broader geographic area that encompasses nearby ranches, villages, and cities. Nonradiological studies focus on the area immediately surrounding the WIPP site

  3. Waste Isolation Pilot Plant site environmental report, for calendar year 1995

    International Nuclear Information System (INIS)

    1996-01-01

    The U.S. Department of Energy (DOE) Order 5400.1 General Environmental Protection Program, requires DOE facilities, that conduct environmental protection programs, to annually prepare a Site Environmental Report (SER). The purpose of the SER is to provide an abstract of environmental assessments conducted in order to characterize site environmental management performance, to confirm compliance with environmental standards and requirements, and to highlight significant programs and efforts of environmental merit. The content of this SER is not restricted to a synopsis of the required data, in addition, information pertaining to new and continued monitoring and compliance activities during the 1995 calendar year are also included. Data contained in this report are derived from those monitoring programs directed by the Waste Isolation Pilot Plant (WIPP) Environmental Monitoring Plan (EMP). The EMP provides inclusive guidelines implemented to detect potential impacts to the environment and to establish baseline measurements for future environmental evaluations. Surface water, groundwater. air, soil, and biotic matrices are monitored for an array of radiological and nonradiological factors. The baseline radiological surveillance program encompasses a broader geographic area that includes nearby ranches, villages, and cities. Most elements of nonradiological assessments are conducted within the geographic vicinity of the WIPP site

  4. Impaired bone healing at tooth extraction sites in CD24-deficient mice: A pilot study.

    Science.gov (United States)

    Avivi-Arber, Limor; Avivi, Doran; Perez, Marilena; Arber, Nadir; Shapira, Shiran

    2018-01-01

    To use a micro-computed tomography (micro-CT) to quantify bone healing at maxillary first molar extraction sites, and test the hypothesis that bone healing is impaired in CD24-knockout mice as compared with wild-type C57BL/6J mice. Under ketamine-xylazine general anaesthesia, mice had either extraction of the right maxillary first molar tooth or sham operation. Mice were sacrificed 1 (n = 12/group), 2 (n = 6/group) or 4 (n = 6/group) weeks postoperatively. The right maxillae was disected. Micro-CT was used to quantify differences in bone microstructural features at extrction sites, between CD24-knockout mice and wild-type mice. CD24-Knockout mice displayed impaired bone healing at extraction sites that was manifested as decreased trabecular bone density, and decreased number and thickness of trabeculae. This pilot study suggests that CD24 plays an important role in extraction socket bone healing and may be used as a novel biomarker of bone quality and potential therapeutic target to improve bone healing and density following alveolar bone injury.

  5. Seismic reflection data report: Waste Isolation Pilot Plant (WIPP) site, Southeastern New Mexico

    International Nuclear Information System (INIS)

    Hern, J.L.; Powers, D.W.; Barrows, L.J.

    1978-12-01

    Three seismic reflection (Vibroseis) surveys conducted from 1976 through 1978 by Sandia Laboratories to support investigations for the Waste Isolation Pilot Plant (WIPP) are described. Volume I describes the purpose, field parameters, and data processing parameters. Volume II contains uninterpreted processed lines and shotpoint maps. Data interpretations will be the subject of the subsequent reports. The data collected during these three surveys total 77 line miles; 72 line miles of this are on or very near the WIPP site. The first of the surveys (1976 SAN) covered 25 line miles and was conducted similarly to previous petroleum industry surveys in the area. 1976 SAN supplemented existing petroleum industry data. The two subsequent surveys (1977 X and 1978 Y) used shorter geophone spacings (110'), higher signal frequencies (up to 100 Hz), and higher data sampling rates (2 ms.) to better define the shallow zone (less than 4000') of primary interest. 1977 X contained 47 line miles on or near the WIPP site and over several structural features northwest of the site. 1978 Y contains 5 line miles over a one square mile area near the center of the WIPP site. These data show increasing discrimination of shallow reflectors as data collection parameters were modified. Data tables of recording and processing parameters are included. A fourth Vibroseis survey was conducted at the WIPP site in 1978 by Grant Geophysical Company for Bechtel; the data are not in final form and are not included. Petroleum industry data and an inconclusive weight-drop survey, conducted in 1976, are also not included in this report

  6. The Construction And Instrumentation Of A Pilot Treatment System At The Standard Mine Superfund Site, Crested Butte, CO

    Science.gov (United States)

    A pilot biochemical reactor (BCR) was designed and constructed to treat mine-influenced water emanating from an adit at a remote site in southern Colorado which receives an average of 400 inches (10.2 meters) of snowfall each season. The objective of the study is to operate and ...

  7. The Construction And Instrumentation Of A Pilot Treatment System At The Standard Mine Superfund Site, Crested Butte, CO - (Presentation)

    Science.gov (United States)

    A pilot biochemical reactor (BCR) was designed and constructed to treat mine-influenced water emanating from an adit at a remote site in southern Colorado which receives an average of 400 inches (10.2 meters) of snowfall each season. The objective of the study is to operate and ...

  8. Verification of geomechanical integrity and prediction of long-term mineral trapping for the Ketzin CO2 storage pilot site

    Science.gov (United States)

    Kempka, Thomas; De Lucia, Marco; Kühn, Michael

    2014-05-01

    Static and dynamic numerical modelling generally accompany the entire CO2 storage site life cycle. Thereto, it is required to match the employed models with field observations on a regular basis in order to predict future site behaviour. We investigated the coupled processes at the Ketzin CO2 storage pilot site [1] using a model coupling concept focusing on the temporal relevance of processes involved (hydraulic, chemical and mechanical) at given time-scales (site operation, abandonment and long-term stabilization). For that purpose, long-term dynamic multi-phase flow simulations [2], [3] established the basis for all simulations discussed in the following. Hereby, pressure changes resulting in geomechanical effects are largest during site operation, whereas geochemical reactions are governed by slow kinetics resulting in a long-term stabilization. To account for mechanical integrity, which may be mainly affected during site operation, we incorporated a regional-scale coupled hydro-mechanical model. Our simulation results show maximum ground surface displacements of about 4 mm, whereas shear and tensile failure are not observed. Consequently, the CO2 storage operation at the Ketzin pilot site does not compromise reservoir, caprock and fault integrity. Chemical processes responsible for mineral trapping are expected to mainly occur during long-term stabilization at the Ketzin pilot site [4]. Hence, our previous assessment [3] was extended by integrating two long-term mineral trapping scenarios. Thereby, mineral trapping contributes to the trapping mechanisms with 11.7 % after 16,000 years of simulation in our conservative and with 30.9 % in our maximum reactivity scenarios. Dynamic flow simulations indicate that only 0.2 % of the CO2 injected (about 67,270 t CO2 in total) is in gaseous state, but structurally trapped after 16,000 years. Depending on the studied long-term scenario, CO2 dissolution is the dominating trapping mechanism with 68.9 % and 88

  9. Annual site environmental monitoring report for the Waste Isolation Pilot Plant, Calendar year 1985

    International Nuclear Information System (INIS)

    Reith, C.; Prince, K.; Fischer, T.; Rodriguez, A.; Uhland, D.; Winstanley, D.

    1986-04-01

    This is the first Annual Site Environmental Monitoring Report for the Waste Isolation Pilot Plant (WIPP) in southeastern New Mexico. The WIPP project is operated by the US Department of Energy (DOE) for the purpose of providing a research and development facility to demonstrate the safe disposal of radioactive wastes generated by the defense activities of the U.S. Government. The report provides a comprehensive description of environmental activities at WIPP during Calendar Year 1985, including: a description of the WIPP project and its mission; a description of the local environment, including demographics; a summary of environmental program information, including an update on the status of environmental permits and compliance activities; a presentation of the findings of the Radiological Baseline Program (RBP), which is a program to characterize radionuclide activities in the environment around the WIPP site; and a summary of findings of the Ecological Monitoring Program (EMP), which examines non-radiological impacts of WIPP construction on the surrounding ecosystem. The WIPP facility is under construction, and will not receive radioactive wastes before October 1988. Therefore, this report describes the status of preoperational (as opposed to operational) environmental activities. 29 refs., 17 figs., 22 tabs

  10. SITE CHARACTERIZATION AND MONITORING DATA FROM THE AREA 5 PILOT WELLS

    International Nuclear Information System (INIS)

    2005-01-01

    Three exploratory boreholes were drilled and completed to the uppermost alluvial aquifer in Area 5 of the Nevada Test Site, Nye County, Nevada, in 1992. The boreholes and associated investigations were part of the Area 5 Site Characterization Program developed to meet data needs associated with regulatory requirements applicable to the disposal of low-level, mixed, and high-specific-activity waste at this site. This series of boreholes was specifically designed to characterize the hydrogeology of the thick vadose zone and to help define the water quality and hydraulic properties of the uppermost aquifer. Wells UE5PW-1, UE5PW-2, and UE5PW-3 are located in a triangular array near the southeast, northeast, and northwest corners, respectively, of the approximately 2.6-square-kilometer Area 5 Radioactive Waste Management Site to give reasonable spatial coverage for sampling and characterization, and to help define the nearly horizontal water table. Two of the wells, UE5PW-1 and UE5PW-2, penetrated only unconsolidated alluvial materials. The third well, located closer to the margin of the basin, penetrated both alluvium and underlying ash-flow and bedded tuff units. The watertable was encountered at the elevation of approximately 734 meters. The results of laboratory testing of core and drill cuttings samples indicate that the mineralogical, material, and hydrologic properties of the alluvium are very similar within and between boreholes. Additional tests on the same core and drill cuttings samples indicate that hydrologic conditions within the alluvium are also similar between pilot wells. Both core and drill cuttings samples are dry (less than 10 percent water content by weight) throughout the entire unsaturated section of alluvium, and water content increases slightly with depth in each borehole. Water potential measurements on core samples show a large positive potential gradient (water tends to move upward, rather than downward) to a depth of approximately 30

  11. Waste Isolation Pilot Plant annual site environmental report for calendar year 1992

    International Nuclear Information System (INIS)

    1993-01-01

    The US Department of Energy (DOE) Waste Isolation Pilot Plant (WIPP) Operational Environmental Monitoring Plan (OEMP) defined a comprehensive set of parameters which are monitored to detect potential environmental impacts and establish baselines for future environmental evaluations. Surface water and groundwater, air, soil, and biotics are monitored for radioactivity levels. Nonradiological environmental monitoring activities include air, water quality, soil properties, meteorological measurements and determination of the status of the local biological community. Ecological studies focus on the immediate area surrounding the WIPP site with emphasis on the salt storage pile. The baseline radiological surveillance covers a broader geographic area including nearby ranches, villages, and cities. Since the WIPP is still in its preoperational phase (i.e., no waste has been received) certain operational requirements of DOE Orders 5400.1, 5400.5, and the Environmental Regulatory Guide for Radiological Effluent Monitoring and Environmental Surveillance (DOE/EH-0173T) are not relevant. Therefore, this report does not discuss items such as radionuclide emissions and effluents and subsequent doses to the public

  12. Waste Isolation Pilot Plant: Site environmental report for calendar year 1991

    International Nuclear Information System (INIS)

    1991-01-01

    The US Department of Energy (DOE) Waste Isolation Pilot Plant (WIPP) Operational Environmental Monitoring Plan (OEMP) monitors a comprehensive set of parameters in order to detect any potential environmental Impacts and establish baselines for future quantitative environmental Impact evaluations. Surface water and groundwater, air, soil, and biotics are measured for background radiation. Nonradiological environmental monitoring activities include air quality, water quality, soil properties, meteorological, and the status of the local biological community. Ecological studies focus on the immediate area surrounding the site with emphasis on the salt storage pile, whereas baseline radiological surveillance covers a broader geographic area Including nearby ranches, villages, and cities. Since the WIPP is still in a preoperational state, and no waste has been received; certain elements required by DOE Order 5400.1 are not presented In this report. The most significant addition to the 1991 report is the inclusion of the first four appendices, the Radiological Baseline Program (DOE/WIPP 92-037), the Salt Impact Studies (DOE/WIPP 92-038), the Disturbed Land Reclamation Techniques (DOE/WIPP 92-039), and the Background Water Characterization for the WIPP (DOE/WIPP 92-013). These appendices are independently published and available to interested parties by the DOE reference number. These summaries will not be published in future ASER'S. They will, however, be referenced as a basis for evaluating similar data collected during the Test and subsequent Operational phases of the WIPP

  13. Waste Isolation Pilot Plant annual site environmental report for calendar year 1992

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    The US Department of Energy (DOE) Waste Isolation Pilot Plant (WIPP) Operational Environmental Monitoring Plan (OEMP) defined a comprehensive set of parameters which are monitored to detect potential environmental impacts and establish baselines for future environmental evaluations. Surface water and groundwater, air, soil, and biotics are monitored for radioactivity levels. Nonradiological environmental monitoring activities include air, water quality, soil properties, meteorological measurements and determination of the status of the local biological community. Ecological studies focus on the immediate area surrounding the WIPP site with emphasis on the salt storage pile. The baseline radiological surveillance covers a broader geographic area including nearby ranches, villages, and cities. Since the WIPP is still in its preoperational phase (i.e., no waste has been received) certain operational requirements of DOE Orders 5400.1, 5400.5, and the Environmental Regulatory Guide for Radiological Effluent Monitoring and Environmental Surveillance (DOE/EH-0173T) are not relevant. Therefore, this report does not discuss items such as radionuclide emissions and effluents and subsequent doses to the public.

  14. Background radiation measurements at the Waste Isolation Pilot Plant (WIPP) Site, Carlsbad, New Mexico

    International Nuclear Information System (INIS)

    Minnema, D.M.; Brewer, L.W.

    1983-09-01

    A series of background radiation measurements was performed at the Waste Isolation Pilot Plant (WIPP) Site, Carlsbad, New Mexico. The survey consisted of gross gamma and gamma spectral measurements of the radiation fields, soil and salt grab sample gamma analysis, and radon and working level measurements. The survey included locations at the surface and also within the mine itself. Background radiation levels on the surface were measured to average 7.65 microR/hour, and 0.7 microR/hour within the mine. Radon and working levels were at or below detection levels at all locations, and the radon concentration was estimated to be about 0.01 pCi/liter on the surface based on spectral measurements. The spectral measurements were performed using an intrinsic germanium spectrometer, and calculations from the spectra indicated that potassium-40 contributed about 28% to the surface level dose rates, natural uranium daughters contributed about 64%, and cesium-137 from weapons testing fallout contributed about 8%. In the mine potassium-40 was the only identifiable contributor to the dose rate

  15. Geohydrology of the proposed Waste Isolation Pilot Plant site in southeastern New Mexico

    International Nuclear Information System (INIS)

    Mercer, J.W.; Gonzalez, D.D.

    1981-01-01

    The proposed site for the U.S. Department of Energy's Waste Isolation Pilot Plant (WIPP) is in the Los Medanos area located about 40 km east of Carlsbad, in eastern Eddy County, NM. Geohydrologic data have been collected from this area since 1972, and the data will be used as part of a study evaluating the feasibility of storing defense-associated transuranic wastes in bedded salt at a depth of 655 m. The salt beds are within the Salado Formation of Permian age. The study presented includes the determination of ground-water flow boundaries; potentiometric heads; ground-water chemistry; and hydraulic properties through pump, slug, pressure-pulse, and tracer tests. Data collected during drilling and testing 30 hydrologic holes have indicated three zones above the Salado Formation that could potentially transport wastes to the biosphere if the proposed facility is breached. These zones include the Magenta and Culebra Dolomite members of the Rustler Formation and the contact zone between the Rustler and Salado formations

  16. Strontium and caesium transport in unsaturated soil from Chernobyl Pilot Site under steady flow conditions

    International Nuclear Information System (INIS)

    Szenknect, St.

    2003-10-01

    This work is devoted to the quantification and the identification of the predominant processes involved in strontium and caesium transport in unsaturated soil from Chernobyl Pilot Site under steady flow conditions. The transport and fate of radionuclides in the subsurface is affected by various physical and chemical processes including advective and diffusive transport as well as chemical and biological transformations. Laboratory experiments and the use of a multiple tracer approach allow to isolate the contributions of each elementary process and to control the physico-chemical conditions in the system. To be more representative of the field conditions, we decided to perform column miscible displacement experiments. We perform batch and flow-through reactor experiments to characterize the radionuclides sorption mechanisms. Miscible displacement experiments within homogeneous columns and modeling allow to characterize the hydrodynamic properties of the soil and to describe the radionuclides behaviour under dynamic conditions at different water contents. We show that the water content of porous media affect the transport behaviour of inert and strongly sorbing radionuclides. Our results demonstrate that a parametrized transport model that was calibrated under completely saturated conditions was not able to describe the advective-dispersive transport of reactive solutes under unsaturated steady state conditions. Under our experimental conditions, there is no effect of a decrease of the mean water content on the sorption model parameters, but the transport parameters are modified. We established for the studied soil the relation between hydrodynamic dispersion and water content and the relation between pore water velocity and water content. (author)

  17. A pilot study for the extraction and treatment of groundwater from a manufactured gas plant site. Final report

    International Nuclear Information System (INIS)

    1997-12-01

    This report describes a pilot study involving treatment of contaminated groundwater at a former manufactured gas plant site on the eastern seaboard of the US. The work was performed in order to provide the design basis for a full-scale groundwater extraction and treatment system at the site, as well as to develop a generic approach to selection of groundwater treatment sequences at other MGP sites. It included three main components: hydrogeologic investigations, bench-scale treatability studies, and pilot-scale treatability studies. Technologies evaluated in bench-scale work included gravity settling, filtration, and dissolved air flotation (DAF) for primary treatment of nonaqueous phase materials; biological degradation, air stripping, and carbon adsorption for secondary treatment of dissolved organics; and carbon adsorption as tertiary treatment of remaining dissolved contaminants. Pilot-scale studies focused on collecting system performance data fore three distinct levels of contamination. Two treatment trains were evaluated. One consisted of DAF, fluidized-bed biotreatment, and filtration plus carbon adsorption; the other used the same steps except to substitute air stripping for fluidized bed treatment. The final effluents produced by both treatment sequences were similar and demonstrated complete treatment of the groundwater. Besides detailing system design and performance for the treatability studies, the report includes an analysis of groundwater treatment applications to MGP sites in general, including a discussion of capital and operating costs

  18. Site Effect Assessment of the Gros-Morne Hill Area in Port-au-Prince, Haiti, Part A: Geophysical-Seismological Survey Results

    Directory of Open Access Journals (Sweden)

    Sophia Ulysse

    2018-04-01

    Full Text Available After the M = 7.0 Haiti earthquake in 2010, many teams completed seismic risk studies in Port-au-Prince to better understand why this not extraordinarily strong event had induced one of the most severe earthquake disasters in history (at least in the Western World. Most highlighted the low construction quality as the main cause for the disaster, but some also pointed to possible soil and topographic amplification effects, especially in the lower and central parts of Port-au-Prince (e.g., close to the harbor. However, very detailed local studies of such site effects have not been completed yet. A Belgian-Haitian collaboration project was established in order to develop a detailed local seismic hazard study for Gros-Morne hill located in the district of Pétion-Ville, southeast of Port-au-Prince. In order to have a better understanding of the amplification on the Gros-Morne hill, in the southeastern part of Port-au-Prince, site effects were investigated by using near surface geophysical methods. The horizontal to vertical spectral ratio technique was applied to ambient vibrations and earthquake data, and multichannel analysis of surface waves and P-wave refraction tomography calculation were applied to seismic data. Standard spectral ratios were computed for the S-wave windows of the earthquake data recorded by a small temporary seismic network. Electrical resistivity tomography profiles were also performed in order to image the structure of the subsurface and detect the presence of water, if any. The spectral ratio results generally show low to medium (1.5–6 resonance amplitudes at one or several different resonance frequencies (for the same site, between 0.5 and 25 Hz. At most of the investigated sites, the fundamental resonance frequency varies between 7 and 10 Hz. By using the multichannel surface wave analyses of the seismic data, we were able to determine shear wave velocities ranging between 200 and 850 m/s, up to a depth of about 15–20

  19. Caustic Recycling Pilot Unit to Separate Sodium from LLW at Hanford Site - 12279

    Energy Technology Data Exchange (ETDEWEB)

    Pendleton, Justin; Bhavaraju, Sai; Priday, George; Desai, Aditya; Duffey, Kean; Balagopal, Shekar [Ceramatec Inc., Salt Lake City, UT 84119 (United States)

    2012-07-01

    As part of the Department of Energy (DOE) sponsored Advanced Remediation Technologies initiative, a scheme was developed to combine Continuous Sludge Leaching (CSL), Near-Tank Cesium Removal (NTCR), and Caustic Recycling Unit (CRU) using Ceramatec technology, into a single system known as the Pilot Near-Tank Treatment System (PNTTS). The Cesium (Cs) decontaminated effluent from the NTCR process will be sent to the caustic recycle process for recovery of the caustic which will be reused in another cycle of caustic leaching in the CSL process. Such an integrated mobile technology demonstration will give DOE the option to insert this process for sodium management at various sites in Hanford, and will minimize the addition of further sodium into the waste tanks. This allows for recycling of the caustic used to remove aluminum during sludge washing as a pretreatment step in the vitrification of radioactive waste which will decrease the Low Level Waste (LLW) volume by as much as 39%. The CRU pilot process was designed to recycle sodium in the form of pure sodium hydroxide. The basis for the design of the 1/4 scale pilot caustic recycling unit was to demonstrate the efficient operation of a larger scale system to recycle caustic from the NTCR effluent stream from the Parsons process. The CRU was designed to process 0.28 liter/minute of NTCR effluent, and generate 10 M concentration of 'usable' sodium hydroxide. The proposed process operates at 40 deg. C to provide additional aluminum solubility and then recover the sodium hydroxide to the point where the aluminum is saturated at 40 deg. C. A system was developed to safely separate and vent the gases generated during operation of the CRU with the production of 10 M sodium hydroxide. Caustic was produced at a rate between 1.9 to 9.3 kg/hr. The CRU was located inside an ISO container to allow for moving of the unit close to tank locations to process the LLW stream. Actual tests were conducted with the NTCR effluent

  20. Interpretations of Tracer Tests Performed in the Culebra Dolomite at the Waste Isolation Pilot Plant Site

    International Nuclear Information System (INIS)

    MEIGS, LUCY C.; BEAUHEIM, RICHARD L.; JONES, TOYA L.

    2000-01-01

    This report provides (1) an overview of all tracer testing conducted in the Culebra Dolomite Member of the Rustler Formation at the Waste Isolation Pilot Plant (WPP) site, (2) a detailed description of the important information about the 1995-96 tracer tests and the current interpretations of the data, and (3) a summary of the knowledge gained to date through tracer testing in the Culebra. Tracer tests have been used to identify transport processes occurring within the Culebra and quantify relevant parameters for use in performance assessment of the WIPP. The data, especially those from the tests performed in 1995-96, provide valuable insight into transport processes within the Culebra. Interpretations of the tracer tests in combination with geologic information, hydraulic-test information, and laboratory studies have resulted in a greatly improved conceptual model of transport processes within the Culebra. At locations where the transmissivity of the Culebra is low ( -6 m 2 /s), we conceptualize the Culebra as a single-porosity medium in which advection occurs largely through the primary porosity of the dolomite matrix. At locations where the transmissivity of the Culebra is high (> 4 x 10 -6 m 2 /s), we conceptualize the Culebra as a heterogeneous, layered, fractured medium in which advection occurs largely through fractures and solutes diffuse between fractures and matrix at multiple rates. The variations in diffusion rate can be attributed to both variations in fracture spacing (or the spacing of advective pathways) and matrix heterogeneity. Flow and transport appear to be concentrated in the lower Culebra. At all locations, diffusion is the dominant transport process in the portions of the matrix that tracer does not access by flow

  1. Interpretations of Tracer Tests Performed in the Culebra Dolomite at the Waste Isolation Pilot Plant Site

    Energy Technology Data Exchange (ETDEWEB)

    MEIGS,LUCY C.; BEAUHEIM,RICHARD L.; JONES,TOYA L.

    2000-08-01

    This report provides (1) an overview of all tracer testing conducted in the Culebra Dolomite Member of the Rustler Formation at the Waste Isolation Pilot Plant (WPP) site, (2) a detailed description of the important information about the 1995-96 tracer tests and the current interpretations of the data, and (3) a summary of the knowledge gained to date through tracer testing in the Culebra. Tracer tests have been used to identify transport processes occurring within the Culebra and quantify relevant parameters for use in performance assessment of the WIPP. The data, especially those from the tests performed in 1995-96, provide valuable insight into transport processes within the Culebra. Interpretations of the tracer tests in combination with geologic information, hydraulic-test information, and laboratory studies have resulted in a greatly improved conceptual model of transport processes within the Culebra. At locations where the transmissivity of the Culebra is low (< 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a single-porosity medium in which advection occurs largely through the primary porosity of the dolomite matrix. At locations where the transmissivity of the Culebra is high (> 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a heterogeneous, layered, fractured medium in which advection occurs largely through fractures and solutes diffuse between fractures and matrix at multiple rates. The variations in diffusion rate can be attributed to both variations in fracture spacing (or the spacing of advective pathways) and matrix heterogeneity. Flow and transport appear to be concentrated in the lower Culebra. At all locations, diffusion is the dominant transport process in the portions of the matrix that tracer does not access by flow.

  2. Seismic reflection data report: Waste Isolation Pilot Plant (WIPP) site, Southeastern New Mexico

    International Nuclear Information System (INIS)

    Hern, J.L.; Powers, D.W.; Barrows, L.J.

    1978-12-01

    Volume II contains uninterpreted processed lines and shotpoint maps from three seismic reflection surveys conducted from 1976 through 1978 by Sandia Laboratories to support investigations for the Waste Isolation Pilot Plant. Data interpretations will be the subject of subsequent reports

  3. Catalytic activity of Au nanoparticles

    DEFF Research Database (Denmark)

    Larsen, Britt Hvolbæk; Janssens, Ton V.W.; Clausen, Bjerne

    2007-01-01

    Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change with par......Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change...... with particle size. We find that the fraction of low-coordinated Au atoms scales approximately with the catalytic activity, suggesting that atoms on the corners and edges of Au nanoparticles are the active sites. This effect is explained using density functional calculations....

  4. Summary of site-characterization studies conducted from 1983 through 1987 at the Waste Isolation Pilot Plant (WIPP) site, southeastern New Mexico

    International Nuclear Information System (INIS)

    Lappin, A.R.

    1988-01-01

    The Waste Isolation Pilot Plant (WIPP) is being excavated at a depth of approximately 655 m in bedded halites. Site-characterization activities at the WIPP site began in 1976. Characterization activities since 1983 have had the objective of updating the conceptual model for the geologic and hydrologic behavior of the WIPP site and vicinity. This paper discusses aspects of the general conceptual model significant to both site characterization and performance assessment. The geological and hydrologic behavior of the WIPP site and vicinity is transient, and has been transient since at least deposition of the Permian Salado Formation containing the underground workings of the WIPP facility. The Salado Formation deforms regionally in response to gravity, but is very low in permeability, except within approximately two meters of the WIPP facility. The Culebra Dolomite Member of the Rustler Formation dominates the hydrology at the WIPP site. Hydrologic measurements, geologic studies, major-element and minor-element distributions in Culebra fluids, and the results of isotopic studies (stable-isotope, radiocarbon, uranium-disequilibrium, and 87 Sr/ 86 Sr) are consistent with the interpretations that, although the Culebra dominates flow within the Rustler at the WIPP site and Rustler karst is not present, there has been limited vertical fluid movement within the Rustler and between the Rustler and the overlying Dewey Lake Red Beds

  5. Leveraging Social Networking Sites for an Autoimmune Hepatitis Genetic Repository: Pilot Study to Evaluate Feasibility.

    Science.gov (United States)

    Comerford, Megan; Fogel, Rachel; Bailey, James Robert; Chilukuri, Prianka; Chalasani, Naga; Lammert, Craig Steven

    2018-01-18

    Conventional approaches to participant recruitment are often inadequate in rare disease investigation. Social networking sites such as Facebook may provide a vehicle to circumvent common research limitations and pitfalls. We report our preliminary experience with Facebook-based methodology for participant recruitment and participation into an ongoing study of autoimmune hepatitis (AIH). The goal of our research was to conduct a pilot study to assess whether a Facebook-based methodology is capable of recruiting geographically widespread participants into AIH patient-oriented research and obtaining quality phenotypic data. We established a Facebook community, the Autoimmune Hepatitis Research Network (AHRN), in 2014 to provide a secure and reputable distillation of current literature and AIH research opportunities. Quarterly advertisements for our ongoing observational AIH study were posted on the AHRN over 2 years. Interested and self-reported AIH participants were subsequently enrolled after review of study materials and completion of an informed consent by our study coordinator. Participants returned completed study materials, including epidemiologic questionnaires and genetic material, to our facility via mail. Outside medical records were obtained and reviewed by a study physician. We successfully obtained all study materials from 29 participants with self-reported AIH within 2 years from 20 different states. Liver biopsy results were available for 90% (26/29) of participants, of which 81% (21/29) had findings consistent with AIH, 15% (4/29) were suggestive of AIH with features of primary biliary cholangitis (PBC), and 4% (1/29) had PBC alone. A total of 83% (24/29) had at least 2 of 3 proposed criteria: positive autoimmune markers, consistent histologic findings of AIH on liver biopsy, and reported treatment with immunosuppressant medications. Self-reported and physician records were discrepant for immunosuppressant medications or for AIH/PBC diagnoses in 4

  6. Electrokinetic remediation of plutonium-contaminated nuclear site wastes: Results from a pilot-scale on-site trial

    International Nuclear Information System (INIS)

    Agnew, Kieran; Cundy, Andrew B.; Hopkinson, Laurence; Croudace, Ian W.; Warwick, Phillip E.; Purdie, Philip

    2011-01-01

    This paper examines the field-scale application of a novel low-energy electrokinetic technique for the remediation of plutonium-contaminated nuclear site soils, using soil wastes from the Atomic Weapons Establishment (AWE) Aldermaston site, Berkshire, UK as a test medium. Soils and sediments with varying composition, contaminated with Pu through historical site operations, were electrokinetically treated at laboratory-scale with and without various soil pre-conditioning agents. Results from these bench-scale trials were used to inform a larger on-site remediation trial, using an adapted containment pack with battery power supply. 2.4 m 3 (ca. 4 tonnes) of Pu-contaminated soil was treated for 60 days at a power consumption of 33 kW h/m 3 , and then destructively sampled. Radiochemical data indicate mobilisation of Pu in the treated soil, and migration (probably as a negatively charged Pu-citrate complex) towards the anodic compartment of the treatment cell. Soil in the cathodic zone of the treatment unit was remediated to a level below free-release disposal thresholds (1.7 Bq/g, or <0.4 Bq/g above background activities). The data show the potential of this method as a low-cost, on-site tool for remediation of radioactively contaminated soils and wastes which can be operated remotely on working sites, with minimal disruption to site infrastructure or operations.

  7. Surfing for thinness: a pilot study of pro-eating disorder Web site usage in adolescents with eating disorders.

    Science.gov (United States)

    Wilson, Jenny L; Peebles, Rebecka; Hardy, Kristina K; Litt, Iris F

    2006-12-01

    Pro-eating disorder Web sites are communities of individuals who engage in disordered eating and use the Internet to discuss their activities. Pro-recovery sites, which are less numerous, express a recovery-oriented perspective. This pilot study investigated the awareness and usage of pro-eating disorder Web sites among adolescents with eating disorders and their parents and explored associations with health and quality of life. This was a cross-sectional study of 698 families of patients (aged 10-22 years) diagnosed with an eating disorder at Stanford between 1997 and 2004. Anonymous surveys were mailed and offered in clinic. Survey content included questions about disease severity, health outcomes, Web site usage, and parental knowledge of eating disorder Web site usage. Surveys were returned by 182 individuals: 76 patients and 106 parents. Parents frequently (52.8%) were aware of pro-eating disorder sites, but an equal number did not know whether their child visited these sites, and only 27.6% had discussed them with their child. Most (62.5%) parents, however, did not know about pro-recovery sites. Forty-one percent of patients visited pro-recovery sites, 35.5% visited pro-eating disorder sites, 25.0% visited both, and 48.7% visited neither. While visiting pro-eating disorder sites, 96.0% reported learning new weight loss or purging techniques. However, 46.4% of pro-recovery site visitors also learned new techniques. Pro-eating disorder site users did not differ from nonusers in health outcomes but reported spending less time on school or schoolwork and had a longer duration of illness. Users of both pro-eating disorder and pro-recovery sites were hospitalized more than users of neither site. Pro-eating disorder site usage was prevalent among adolescents with eating disorders, yet parents had little knowledge of this. Although use of these sites was not associated with other health outcomes, usage may have a negative impact on quality of life and result in

  8. Major Practicum as a Learning Site for Exercise Science Professionals: A Pilot Study

    Science.gov (United States)

    Tinning, Richard; Jenkins, David; Collins, Jessie; Rossi, Tony; Brancato, Tania

    2012-01-01

    Exercise science is now an integral part of the allied health framework in Australia and graduates from accredited programmes are equipped with skills recognised as being important in the prevention and management of lifestyle-related diseases. This pilot study sought to determine the experiences of 11 final-year exercise science students in their…

  9. Field evaluation of a horizontal well recirculation system for groundwater treatment: Pilot test at the Clean Test Site Portsmouth Gaseous Diffusion Plant, Piketon, Ohio

    International Nuclear Information System (INIS)

    Muck, M.T.; Kearl, P.M.; Siegrist, R.L.

    1998-01-01

    This report presents the results of field testing a horizontal well recirculation system at the Portsmouth Gaseous Diffusion Plant (PORTS). The recirculation system uses a pair of horizontal wells, one for groundwater extraction and treatment and the other for reinjection of treated groundwater, to set up a recirculation flow field. The induced flow field from the injection well to the extraction well establishes a sweeping action for the removal and treatment of groundwater contaminants. The overall purpose of this project is to study treatment of mixed groundwater contaminants that occur in a thin water-bearing zone not easily targeted by traditional vertical wells. The project involves several research elements, including treatment-process evaluation, hydrodynamic flow and transport modeling, pilot testing at an uncontaminated site, and pilot testing at a contaminated site. The results of the pilot test at an uncontaminated site, the Clean Test Site (CTS), are presented in this report

  10. Site effects in Port-au-Prince (Haiti) from the analysis of spectral ratio and numerical simulations.

    Science.gov (United States)

    St. Fleur, Sadrac; Bertrand, Etienne; Courboulex, Francoise; Mercier de Lépinay, Bernard; Deschamps, Anne; Hough, Susan E.; Cultrera, Giovanna; Boisson, Dominique; Prepetit, Claude

    2016-01-01

    To provide better insight into seismic ground motion in the Port‐au‐Prince metropolitan area, we investigate site effects at 12 seismological stations by analyzing 78 earthquakes with magnitude smaller than 5 that occurred between 2010 and 2013. Horizontal‐to‐vertical spectral ratio on earthquake recordings and a standard spectral ratio were applied to the seismic data. We also propose a simplified lithostratigraphic map and use available geotechnical and geophysical data to construct representative soil columns in the vicinity of each station that allow us to compute numerical transfer functions using 1D simulations. At most of the studied sites, spectral ratios are characterized by weak‐motion amplification at frequencies above 5 Hz, in good agreement with the numerical transfer functions. A mismatch between the observed amplifications and simulated response at lower frequencies shows that the considered soil columns could be missing a deeper velocity contrast. Furthermore, strong amplification between 2 and 10 Hz linked to local topographic features is found at one station located in the south of the city, and substantial amplification below 5 Hz is detected near the coastline, which we attribute to deep and soft sediments as well as the presence of surface waves. We conclude that for most investigated sites in Port‐au‐Prince, seismic amplifications due to site effects are highly variable but seem not to be important at high frequencies. At some specific locations, however, they could strongly enhance the low‐frequency content of the seismic ground shaking. Although our analysis does not consider nonlinear effects, we thus conclude that, apart from sites close to the coast, sediment‐induced amplification probably had only a minor impact on the level of strong ground motion, and was not the main reason for the high level of damage in Port‐au‐Prince.

  11. Routine implementation of isoniazid preventive therapy in HIV-infected patients in seven pilot sites in Zimbabwe

    Science.gov (United States)

    Choto, R. C.; Harries, A. D.; Mutasa-Apollo, T.; Chakanyuka-Musanhu, C.

    2017-01-01

    Setting: Seven pilot sites in Zimbabwe implementing 6 months of isoniazid preventive therapy (IPT) for people living with the human immunodeficiency virus (PLHIV). Objectives: To determine, among PLHIV started on IPT, the completion rates for a 6-month course of IPT and factors associated with non-adherence. Design: A retrospective cohort study. Results: Of 578 patients, 466 (81%) completed IPT. Of the 112 patients who failed to complete IPT, 69 (60%) were lost to follow-up, 30 (27%) stopped treatment with no documented reasons, 8 (7%) developed toxicity/adverse reactions, 5 (5%) were documented as having drug stock-outs and the remainder transferred out or refused to continue treatment. Currently being on antiretroviral therapy (ART) (aOR 0.09, 95%CI 0.03–0.28) and receiving a ⩾2 month supply of isoniazid at the start of treatment were associated with a lower risk of not completing IPT, while missing clinic visits prior to starting IPT (aOR 5.25, 95%CI 2.10–13.14) was associated with a higher risk of non-completion. Conclusion: IPT completion rates in seven pilot sites of Zimbabwe were comparatively high, showing that IPT roll-out in public health facilities is feasible. Enhanced adherence counselling or active tracing among pre-ART patients and those with a history of loss to follow-up may improve IPT completion rates, along with synchronising IPT and ART resupplies. PMID:28775944

  12. Pratiques sacrificielles et funéraires au site Moche de la Huaca de La Luna, côte nord du Pérou

    Directory of Open Access Journals (Sweden)

    1998-01-01

    Full Text Available De récentes recherches archéologiques au site Moche de la Huaca de la Luna ont conduit à la découverte d’un important site sacrificiel et d’une plate-forme funéraire. Dans une enceinte située vers l’arrière du temple et jointe à la plate-forme principale, plusieurs individus auraient été sacrifiés lors de pluies torrentielles (phénomène de El Niño. Dans une structure attenante au site sacrificiel, des tombes ont également été localisées dont celles de deux officiants religieux. Des artefacts retrouvés dans ces sépultures semblent indiquer que ceux-ci étaient des spécialistes du sacrifice. Certains résultats préliminaires seront présentés ici. Il appert d’ores et déjà que ce site exceptionnel permettra de mieux comprendre les dimensions funéraires et sacrificielles du système idéologique et religieux Moche. PRÁCTICAS SACRIFICIALES Y FUNERARIAS EN EL SITIO MOCHE DE LA HUACA DE LA LUNA, COSTA NORTE DEL PERÚ. Investigaciones arqueológicas realizadas en el sitio Moche de la Huaca de la Luna han conducido al descubrimiento de un importante sitio sacrificial y de una plataforma funeraria. En primer lugar, en una plaza de la Huaca, numerosos individuos habrían sido sacrificados durante lluvias torrenciales (fenómeno de El Niño. En segundo lugar, en una plataforma asociada a la plaza, cuatro tumbas elaboradas han sido localizadas. Algunos elementos descubiertos en dos de estas tumbas parecen indicar que serían las de dos especialistas de los sacrificios. Solamente los resultados preliminares estarán presentados aquí, pero parece que este sitio excepcional permitirá comprender mejor las dimensiones funerarias y sacrificiales del sistema ideológico y religioso Moche. SACRIFICIAL AND FUNERARY PRACTICES AT THE MOCHE SITE HUACA DE LA LUNA, NORTH COAST OF PERU. Archaeological research carried out at the Moche site of Huaca de la Luna has led to the discovery of a sacrificial site and a funerary platform. A number

  13. Pilot scale processing of simulated Savannah River Site high level radioactive waste

    International Nuclear Information System (INIS)

    Hutson, N.D.; Zamecnik, J.R.; Ritter, J.A.; Carter, J.T.

    1991-01-01

    The Savannah River Laboratory operates the Integrated DWPF Melter System (IDMS), which is a pilot-scale test facility used in support of the start-up and operation of the US Department of Energy's Defense Waste Processing Facility (DWPF). Specifically, the IDMS is used in the evaluation of the DWPF melter and its associated feed preparation and offgass treatment systems. This article provides a general overview of some of the test work which has been conducted in the IDMS facility. The chemistry associated with the chemical treatment of the sludge (via formic acid adjustment) is discussed. Operating experiences with simulated sludge containing high levels of nitrite, mercury, and noble metals are summarized

  14. Pilot plant experiences using physical and biological treatment steps for the remediation of groundwater from a former MGP site

    Energy Technology Data Exchange (ETDEWEB)

    Wirthensohn, T. [University of Natural Resources and Applied Life Sciences-Vienna, Department of IFA-Tulln, Institute for Environmental Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln (Austria)], E-mail: thomas.wirthensohn@boku.ac.at; Schoeberl, P. [Wienenergie Gasnetz GmbH, Referat 17-Altlasten, Josefstaedterstrasse 10-12, 1080 Vienna (Austria); Ghosh, U. [Department of Civil and Environmental Engineering, University of Maryland Baltimore County, Baltimore, MD 21250 (United States); Fuchs, W. [University of Natural Resources and Applied Life Sciences-Vienna, Department of IFA-Tulln, Institute for Environmental Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln (Austria)

    2009-04-15

    The production of manufactured gas at a site in Vienna, Austria led to the contamination of soil and groundwater with various pollutants including PAHs, hydrocarbons, phenols, BTEX, and cyanide. The site needs to be remediated to alleviate potential impacts to the environment. The chosen remediation concept includes the excavation of the core contaminated site and the setup of a hydraulic barrier to protect the surrounding aquifer. The extracted groundwater will be treated on-site. To design the foreseen pump-and-treat system, a pilot-scale plant was built and operated for 6 months. The scope of the present study was to test the effectiveness of different process steps, which included an aerated sedimentation basin, a submerged fixed film reactor (SFFR), a multi-media filter, and an activated carbon filter. The hydraulic retention time (HRT) was 7.0 h during normal flow conditions and 3.5 h during high flow conditions. The treatment system was effective in reducing the various organic and inorganic pollutants in the pumped groundwater. However, it was also demonstrated that appropriate pre-treatment was essential to overcome problems with clogging due to precipitation of tar and sulfur compounds. The reduction of the typical contaminants, PAHs and BTEX, was more than 99.8%. All water quality parameters after treatment were below the Austrian legal requirements for discharge into public water bodies.

  15. Pilot plant experiences using physical and biological treatment steps for the remediation of groundwater from a former MGP site.

    Science.gov (United States)

    Wirthensohn, T; Schoeberl, P; Ghosh, U; Fuchs, W

    2009-04-15

    The production of manufactured gas at a site in Vienna, Austria led to the contamination of soil and groundwater with various pollutants including PAHs, hydrocarbons, phenols, BTEX, and cyanide. The site needs to be remediated to alleviate potential impacts to the environment. The chosen remediation concept includes the excavation of the core contaminated site and the setup of a hydraulic barrier to protect the surrounding aquifer. The extracted groundwater will be treated on-site. To design the foreseen pump-and-treat system, a pilot-scale plant was built and operated for 6 months. The scope of the present study was to test the effectiveness of different process steps, which included an aerated sedimentation basin, a submerged fixed film reactor (SFFR), a multi-media filter, and an activated carbon filter. The hydraulic retention time (HRT) was 7.0 h during normal flow conditions and 3.5h during high flow conditions. The treatment system was effective in reducing the various organic and inorganic pollutants in the pumped groundwater. However, it was also demonstrated that appropriate pre-treatment was essential to overcome problems with clogging due to precipitation of tar and sulfur compounds. The reduction of the typical contaminants, PAHs and BTEX, was more than 99.8%. All water quality parameters after treatment were below the Austrian legal requirements for discharge into public water bodies.

  16. Pilot plant experiences using physical and biological treatment steps for the remediation of groundwater from a former MGP site

    International Nuclear Information System (INIS)

    Wirthensohn, T.; Schoeberl, P.; Ghosh, U.; Fuchs, W.

    2009-01-01

    The production of manufactured gas at a site in Vienna, Austria led to the contamination of soil and groundwater with various pollutants including PAHs, hydrocarbons, phenols, BTEX, and cyanide. The site needs to be remediated to alleviate potential impacts to the environment. The chosen remediation concept includes the excavation of the core contaminated site and the setup of a hydraulic barrier to protect the surrounding aquifer. The extracted groundwater will be treated on-site. To design the foreseen pump-and-treat system, a pilot-scale plant was built and operated for 6 months. The scope of the present study was to test the effectiveness of different process steps, which included an aerated sedimentation basin, a submerged fixed film reactor (SFFR), a multi-media filter, and an activated carbon filter. The hydraulic retention time (HRT) was 7.0 h during normal flow conditions and 3.5 h during high flow conditions. The treatment system was effective in reducing the various organic and inorganic pollutants in the pumped groundwater. However, it was also demonstrated that appropriate pre-treatment was essential to overcome problems with clogging due to precipitation of tar and sulfur compounds. The reduction of the typical contaminants, PAHs and BTEX, was more than 99.8%. All water quality parameters after treatment were below the Austrian legal requirements for discharge into public water bodies

  17. Pilot-Scale Demonstration of In-Situ Chemical Oxidation Involving Chlorinated Volatile Organic Compounds - Design and Deployment Guidelines (Parris Island, SC, U.S. Marine Corp Recruit Depot, Site 45 Pilot Study)

    Science.gov (United States)

    A pilot-scale in situ chemical oxidation (ISCO) demonstration, involving subsurface injections of sodium permanganate (NaMnO4), was performed at the US Marine Corp Recruit Depot (MCRD), site 45 (Parris Island (PI), SC). The ground water was originally contaminated with perchloroe...

  18. Selection and Characterization of Geological Sites able to Host a Pilot-Scale CO2 Storage in the Paris Basin (GéoCarbone-PICOREF Choix et caractérisation de sites géologiques propices à l’installation d’un pilote pour le stockage de CO2 dans le bassin de Paris (GéoCarbone-PICOREF

    Directory of Open Access Journals (Sweden)

    Brosse É.

    2010-06-01

    Full Text Available The objective of the GéoCarbone-PICOREF project was to select and characterize geological sites where CO2 storage in permeable reservoir could be tested at the pilot scale. Both options of storage in deep saline aquifer and in depleted hydrocarbon field were considered. The typical size envisioned for the pilot was 100 kt CO2 per year. GéoCarbone-PICOREF initially focused on a “Regional Domain”, ca. 200 × 150 km, in the Paris Basin. It was attractive for the following reasons: detailed geological data is available, due to 50 years of petroleum exploration; basin-scale deep saline aquifers are present, with a preliminary estimate of storage capacity which is at the Gt CO2 level, namely the carbonate Oolithe Blanche Formation, of Middle Jurassic age, generally located between 1500 and 1800 m depths in the studied area, and several sandstone formations of Triassic age, located between 2000 and 3000 m; several depleted oil fields exist: although offering storage capacities at a much lower level, they do represent very well constrained geological environments, with proven sealing properties; several sources of pure CO2 were identified in the area, at a flow rate compatible with the pilot size, that would avoid capture costs. 750 km of seismic lines were reprocessed and organized in six sections fitted on well logs. This first dataset provided improved representations of: the gross features of the considered aquifers in the Regional Domain; the structural scheme; lateral continuity of the sealing cap rocks. An inventory of the environmental characteristics was also made, including human occupancy, protected areas, water resource, natural hazards, potential conflicts of use with other resources of the subsurface, etc. From all these criteria, a more restricted geographical domain named the “Sector”, ca. 70 × 70 km, was chosen, the most appropriate for further selection of storage site(s. The geological characterization of the Sector has

  19. Health Promotion at the Construction Work Site: The Lunch Truck Pilot Study.

    Science.gov (United States)

    Caban-Martinez, Alberto J; Moore, Kevin J; Clarke, Tainya C; Davila, Evelyn P; Clark, John D; Lee, David J; Fleming, Lora E

    2018-04-01

    The transient nature of construction work makes it difficult to conduct longitudinal worksite-based health promotion activities. As part of a workplace health assessment pilot study, we worked with a commercial lunch truck company to disseminate four types of health education materials including cancer screening, workplace injury prevention, fruit and vegetable consumption, and smoking cessation to construction workers purchasing food items from the truck during their job breaks. Two weeks following the worksite assessment, we followed up with these workers to ascertain their use of the health promotion materials. Of the 54 workers surveyed, 83% reported reviewing and sharing the cancer screening materials with their families, whereas 44% discussed the cancer screening materials with coworkers. Similar proportions of workers reviewed, shared, and discussed the other health promotion materials with their family. Lunch trucks may be an effective strategy and delivery method for educating construction workers on healthy behaviors and injury prevention practices.

  20. Identification of spatial variability and heterogeneity of the Culebra dolomite at the waste isolation pilot plant site

    International Nuclear Information System (INIS)

    Beauheim, R.L.

    1991-01-01

    The Culebra dolomite is an heterogeneous, locally fractured medium whose transmissivity varies over seven orders of magnitude in the vicinity of the Waste isolation Pilot Plant (WIPP) site in southeastern New Mexico, USA. The spatial distribution of hydraulic properties within the Culebra has been defined by performing 150 hydraulic tests at 41 well locations. Different scales of tests are performed to provide data for different purposes. Small-scale tests such as drillstem tests and slug tests, and intermediate-scale pumping tests provide point data useful in developing initial parameters for numerical modeling. Large-scale pumping tests provide information on the distribution of fractures between widely spaced wells, and also provide data for model calibration. Tracer tests provide data on transport mechanisms needed for transport modeling. 7 figs.; 16 refs

  1. Identification of spatial variability and heterogeneity of the Culebra dolomite at the Waste Isolation Pilot Plant site

    International Nuclear Information System (INIS)

    Beauheim, R.L.

    1990-01-01

    The Culebra dolomite is a heterogeneous, locally fractured medium whose transmissivity varies over seven orders of magnitude in the vicinity of the Waste Isolation Pilot Plant site in southeastern New Mexico, USA. The spatial distribution of hydraulic properties within the Culebra has been defined by performing 150 hydraulic tests at 41 well locations. Different scales of tests are performing 150 hydraulic tests at 41 well locations. Different scales of tests are performed to provide data for different purposes. Small-scale tests such as drillstem tests and slug tests, and short, intermediate-scale pumping tests provide point data useful in developing initial parameters for numerical modeling. Large-scale pumping tests provide information on the distribution of fractures between widely spaced wells, and also provide data for model calibration. Tracer tests provide data on transport mechanisms needed for transport modeling. 16 refs., 7 figs

  2. Environmental assessment for the reuse of TNX as a multi-purpose pilot plant campus at the Savannah River Site

    International Nuclear Information System (INIS)

    1998-07-01

    The Department of Energy (DOE) prepared this environmental assessment (EA) to analyze the potential environmental and safety impacts of DOE planning to allow asset reuse of the TNX Area at the Savannah River Site (SRS) located near Aiken, South Carolina. The proposed action would include providing for a location for the Centers of Excellence at or adjacent to SRS and entering into a cooperative agreement with a non-profit management and operations (management firm) contractor to operate and market the TNX facilities and equipment. The area (formerly TNX) would be called a Multi-Purpose Pilot Plant Campus (MPPC) and would be used: (1) as location for technology research, development, demonstration, and commercial operations; (2) to establish partnerships with industry to develop applied technologies for commercialization; and (3) serve as administrative headquarters for Centers of Excellence in the program areas of soil remediation, radioecology, groundwater contamination, and municipal solid waste minimization

  3. Site selection and evaluation studies of the Waste Isolation Pilot Plant (WIPP), Los Medanos, Eddy County, NM

    International Nuclear Information System (INIS)

    Griswold, G.B.

    1977-12-01

    Bedded-salt deposits of the Salado Formation have been selected for evaluation for a proposed Waste Isolation Pilot Plant (WIPP) to be located in Eddy County, NM, approximately 26 mi east of Carlsbad. Site selection and evaluation studies that included geologic mapping, geophysical surveys, drilling, and resource appraisal were conducted over and under the prospective location. The lower portion of the Salado meets essential criteria for waste isolation. Beds chosen for waste storage lie 2074 to 2730 ft below the surface. High-purity salt exists at these depths, and the geologic structure revealed by geophysical surveys indicates that these beds are essentially flat. Additional geophysical surveys are now under way. The initial interpretation of the new data indicates that more structure may exist in the salt beds in the northern portion of the site area. Full evaluation of potentially commercial deposits of potash and natural gas within the WIPP site will be reported by separate studies, as will be the hydrologic details of the region

  4. On-Site Pilot Study - Removal of Uranium, Radium-226 and Arsenic from Impacted Leachate by Reverse Osmosis - 13155

    Energy Technology Data Exchange (ETDEWEB)

    McMurray, Allan; Everest, Chris; Rilling, Ken [Conestoga-Rovers and Associates, 651 Colby Dr, Waterloo, ON (Canada); Vandergaast, Gary [Atomic Energy of Canada Ltd, 115 Toronto Road, Port Hope, ON (Canada); LaMonica, David [RoChem Membrane Systems Inc., 430 30th Street, Hermosa Beach, CA (United States)

    2013-07-01

    Conestoga-Rovers and Associates (CRA-LTD) performed an on-site pilot study at the Welcome Waste Management Facility in Port Hope, Ontario, Canada, to evaluate the effectiveness of a unique leachate treatment process for the removal of radioactive contaminants from leachate impacted by low-level radioactive waste. Results from the study also provided the parameters needed for the design of the CRA-LTD full scale leachate treatment process design. The final effluent water quality discharged from the process to meet the local surface water discharge criteria. A statistical software package was utilized to obtain the analysis of variance (ANOVA) for the results from design of experiment applied to determine the effect of the evaluated factors on the measured responses. The factors considered in the study were: percent of reverse osmosis permeate water recovery, influent coagulant dosage, and influent total dissolved solids (TDS) dosage. The measured responses evaluated were: operating time, average specific flux, and rejection of radioactive contaminants along with other elements. The ANOVA for the design of experiment results revealed that the operating time is affected by the percent water recovery to be achieved and the flocculant dosage over the range studied. The average specific flux and rejection for the radioactive contaminants were not affected by the factors evaluated over the range studied. The 3 month long on-site pilot testing on the impacted leachate revealed that the CRA-LTD leachate treatment process was robust and produced an effluent water quality that met the surface water discharge criteria mandated by the Canadian Nuclear Safety Commission and the local municipality. (authors)

  5. On-Site Pilot Study - Removal of Uranium, Radium-226 and Arsenic from Impacted Leachate by Reverse Osmosis - 13155

    International Nuclear Information System (INIS)

    McMurray, Allan; Everest, Chris; Rilling, Ken; Vandergaast, Gary; LaMonica, David

    2013-01-01

    Conestoga-Rovers and Associates (CRA-LTD) performed an on-site pilot study at the Welcome Waste Management Facility in Port Hope, Ontario, Canada, to evaluate the effectiveness of a unique leachate treatment process for the removal of radioactive contaminants from leachate impacted by low-level radioactive waste. Results from the study also provided the parameters needed for the design of the CRA-LTD full scale leachate treatment process design. The final effluent water quality discharged from the process to meet the local surface water discharge criteria. A statistical software package was utilized to obtain the analysis of variance (ANOVA) for the results from design of experiment applied to determine the effect of the evaluated factors on the measured responses. The factors considered in the study were: percent of reverse osmosis permeate water recovery, influent coagulant dosage, and influent total dissolved solids (TDS) dosage. The measured responses evaluated were: operating time, average specific flux, and rejection of radioactive contaminants along with other elements. The ANOVA for the design of experiment results revealed that the operating time is affected by the percent water recovery to be achieved and the flocculant dosage over the range studied. The average specific flux and rejection for the radioactive contaminants were not affected by the factors evaluated over the range studied. The 3 month long on-site pilot testing on the impacted leachate revealed that the CRA-LTD leachate treatment process was robust and produced an effluent water quality that met the surface water discharge criteria mandated by the Canadian Nuclear Safety Commission and the local municipality. (authors)

  6. Pedestrian and motorists' actions at pedestrian hybrid beacon sites: findings from a pilot study.

    Science.gov (United States)

    Pulugurtha, Srinivas S; Self, Debbie R

    2015-01-01

    This paper focuses on an analysis of pedestrian and motorists' actions at sites with pedestrian hybrid beacons and assesses their effectiveness in improving the safety of pedestrians. Descriptive and statistical analyses (one-tail two-sample T-test and two-proportion Z-test) were conducted using field data collected during morning and evening peak hours at three study sites in the city of Charlotte, NC, before and after the installation of pedestrian hybrid beacons. Further, an analysis was conducted to assess the change in pedestrian and motorists' actions over time (before the installation; 1 month, 3 months, 6 months, and 12 months after the installation). Results showed an increase in average traffic speed at one of the pedestrian hybrid beacon sites while no specific trends were observed at the other two pedestrian hybrid beacon sites. A decrease in the number of motorists not yielding to pedestrians, pedestrians trapped in the middle of the street, and pedestrian-vehicle conflicts were observed at all the three pedestrian hybrid beacon sites. The installation of pedestrian hybrid beacons did not have a negative effect on pedestrian actions at two out of the three sites. Improvements seem to be relatively more consistent 3 months after the installation of the pedestrian hybrid beacon.

  7. Fabrication of efficient TiO2-RGO heterojunction composites for hydrogen generation via water-splitting: Comparison between RGO, Au and Pt reduction sites

    Science.gov (United States)

    El-Bery, Haitham M.; Matsushita, Yoshihisa; Abdel-moneim, Ahmed

    2017-11-01

    A facile one-step synthesis approach of M/TiO2/RGO (M = Au or Pt) ternary composite by hydrothermal treatment for hydrogen generation via water-splitting was investigated. Photocurrent response measurements revealed that TiO2 (P25) nanoparticles anchored on the reduced graphene oxide (RGO) surface exhibited a p-n heterojunction interface by changing the photocurrent direction with the applied bias from reverse to forward potential. H2 evolution rate of TiO2/RGO (5 wt.%) composite was substantially enhanced by 12-fold in comparison to bare TiO2 under simulated solar light irradiation. Cyclic volatmmetry measurements manifested, that the optimized 0.3 wt.% of platinum metal loaded on TiO2/RGO composite was the most active catalytic reduction sites for hydrogen generation reaction with an initial hydrogen rate of 670 μmol h-1. This study sheds the light on the tunable semiconductor type of TiO2/RGO composite fabricated by solution mixing pathway and its merits to improve the photocatalytic activity.

  8. Evaluation of soil bioassays for use at Washington state hazardous waste sites: A pilot study

    International Nuclear Information System (INIS)

    Blakley, N.; Norton, D.; Stinson, M.; Boyer, R.

    1994-01-01

    The Washington State Department of Ecology (Ecology) is developing guidelines to assess soil toxicity at hazardous waste sites being investigated under the Washington Model Toxics Control Act Cleanup Regulation. To evaluate soil toxicity, Ecology selected five bioassay protocols -- Daphnia, Earthworm, Seedling, Fathead Minnow, and Frog Embryo Teratogenesis Assay Xenopus (FETAX) -- for use as screening level assessment tools at six State hazardous waste sites. Sites contained a variety of contaminants including metals, creosote, pesticides, and petroleum products (leaking underground storage tanks). Three locations, representing high, medium, and low levels of contamination, were samples at each site. In general, the high contaminant samples resulted in the highest toxic response in all bioassays. The order of site toxicity, as assessed by overall toxic response, is creosote, petroleum products, metals, and pesticides. Results indicate that human health standards, especially for metals, may not adequately protect some of the species tested. The FETAX bioassay had the greatest overall number of toxic responses and lowest variance. The seedling and Daphnia bioassays had lower and similar overall toxic response results, followed by the earthworm and fathead minnow. Variability was markedly highest for the seedling. The Daphnia and fathead minnow variability were similar to the FETAX level, while the earthworm variability was slightly higher

  9. Chemical analyses of potash-bearing horizons from 21 exploratory holes drilled at a tentative site for the Waste Isolation Pilot Plant, Eddy County, New Mexico

    International Nuclear Information System (INIS)

    Griswold, G.B.

    1977-09-01

    Sandia Laboratories drilled 21 potash drill holes over an 18,960-acre site in east-central Eddy County, New Mexico, to evaluate potash resources as part of their Waste Isolation Pilot Plant (WIPP) project. This report furnishes assay information on samples obtained from the drilling program

  10. Impacts of Residual Surfactant on Tetrachloroethene (PCE) Degradation Following Pilot-Scale SEAR Treatment at a Chloroethene-Impacted Site

    Science.gov (United States)

    Ramsburg, C. A.; Abriola, L. M.; Pennell, K. D.; Löffler, F. E.; Gamache, M.; Petrovskis, E. A.

    2003-04-01

    A pilot-scale surfactant-enhanced aquifer remediation (SEAR) demonstration was completed during the summer of 2000 at the Bachman Road site (Oscoda, MI USA). For this test, an aqueous solution of 60 g/L Tween 80 (polyoxyethylene (20) sorbitan monooleate) was used to recover tetrachloroethene (PCE) from a suspected source zone, located underneath a former dry-cleaning facility. Tween 80 was selected for use based upon its demonstrated capacity to solubilize PCE, “food-grade” status, and biodegradative potential. Hydraulic control was maintained throughout the test, with 95% of the injected surfactant mass recovered by a single extraction well. Source-zone monitoring conducted 15 months after SEAR treatment revealed the presence of previously undetected volatile fatty acids (acetate and formate) and PCE degradation products (trichloroethene, cis-1,2-dichloroethene, trans-1,2-dichlorethene, and vinyl chloride), in conjunction with PCE concentration reductions of approximately two orders-of-magnitude. The detection of volatile fatty acids is relevant, as they are likely fermentation products of residual Tween 80. Microbial reductive dechlorination is limited by available electron donors, and microcosm studies demonstrated that both acetate and formate support reductively dechlorinating populations present at the oligotrophic Bachman Road site aquifer. Surfactant transport simulations, using a regional flow model developed for the site, were employed to determine appropriate down-gradient monitoring locations. Drive point samples taken 15 months post-treatment in the vicinity of the simulated residual surfactant plume, contained elevated concentrations of acetate and PCE daughter products. Ongoing efforts include continued site-monitoring, and microcosm studies to corroborate a causal relationship between Tween 80 fermentation and PCE dechlorination.

  11. Pilot study risk assessment for selected problems at the Nevada Test Site (NTS)

    International Nuclear Information System (INIS)

    Daniels, J.I.; Andricevic, R.; Jacobson, R.L.

    1993-06-01

    The Nevada Test Site (NTS) is located in southwestern Nevada, about 105 km (65 mi) northwest of the city of Las Vegas. A series of tests was conducted in the late 1950s and early 1960s at or near the NTS to study issues involving plutonium-bearing devices. These tests resulted in the dispersal of about 5 TBq of 239,24O Pu on the surficial soils at the test locations. Additionally, underground tests of nuclear weapons devices have been conducted at the NTS since late 1962; ground water beneath the NTS has been contaminated with radionuclides produced by these tests. These two important problems have been selected for assessment. Regarding the plutonium contamination, because the residual 239 Pu decays slowly (half-life of 24,110 y), these sites could represent a long-term hazard if they are not remediated and if institutional controls are lost. To investigate the magnitude of the potential health risks for this no-remediation case, three basic exposure scenarios were defined that could bring individuals in contact with 239,24O Pu at the sites: (1) a resident living in a subdivision, (2) a resident farmer, and (3) a worker at a commercial facility -- all located at a test site. The predicted cancer risks for the resident farmer were more than a factor of three times higher than the suburban resident at the median risk level, and about a factor of ten greater than the reference worker at a commercial facility. At 100 y from the present, the 5, 50, and 95th percentile risks for the resident farmer at the most contaminated site were 4 x 10 -6 , 6 x 10 -5 , and 5 x 10 -4 , respectively. For the assessment of Pu in surface soil, the principal sources of uncertainty in the estimated risks were population mobility, the relationship between indoor and outdoor contaminant levels, and the dose and risk factors for bone, liver, and lung

  12. A Geochemical Approach for Monitoring a CO2 Pilot Site: Rousse, France. A Major gases, CO2-Carbon Isotopes and Noble Gases Combined Approach Une méthode géochimique pour la surveillance d’un site pilote de stockage de CO2 : Rousse, France. Approche combinant les gaz majeurs, l’isotopie du carbone du CO2 et les gaz rares

    Directory of Open Access Journals (Sweden)

    Garcia B.

    2012-02-01

    storage pilot suggest that noble gas compositions produced by oxyfuel process are sufficiently exotic compared to compositions found in nature (reservoir, aquifer and air to be directly used as tracers of the injected CO2, and to detect and quantify leaks at soil and aquifer levels. Ce papier presente la caracterisation geochimique des differents gaz, naturels et anthropogeniques, impliques dans un pilote de stockage de CO2 en champ de gaz naturel appauvri (Rousse, France. Dans ce pilote, le CO2 est produit par oxycombustion d’un gaz naturel transforme en gaz domestique a l’usine de Lacq. Ce CO2 est transporte dans un pipeline de 30 km de longueur jusqu’au reservoir de gaz appauvri de Rousse. Les gaz produits a Rousse avant injection de CO2, le gaz commercial de Lacq et le CO2 resultant de l’oxycombustion ont ete echantillonnes, ainsi que les gaz situes dans un puits de surveillance (a une profondeur de 45 m et les gaz du sol situes au voisinage de Rousse. Pour tous ces echantillons, la composition en gaz majeurs, la signature isotopique du carbone ainsi que l’abondance et signature isotopique des gaz rares ont ete determinees. Les compositions gazeuses du gaz naturel de Rousse sont comparables a celle du gaz domestique de Lacq avec le methane comme compose principal et la fraction C2-C5 et CO2 comme gaz residuels. Les gaz des sols refletent typiquement des melanges entre l’air (pole pur et le CO2 d’origine biogenique (avec des teneurs maximales de l’ordre de 9-10 %, tandis que les gaz presents dans le puits de monitoring refletent typiquement la composition de l’air sans exces de CO2. Le gaz de Rousse et le gaz domestique du site de Lacq ont une composition isotopique δ13CCH4 egale a –41,0 ‰ et –43,0 ‰ respectivement. Le CO2 injecte sur Rousse a une composition isotopique δ13CCO2 egale a –40,0 ‰ a la sortie de la chambre d’oxycombustion, tandis que la composition isotopique δ13CCO2 des gaz des sols est comprise entre –15 et –25

  13. Thermal conductivity of rocksalt and other geologic materials from the site of the proposed waste isolation pilot plant

    International Nuclear Information System (INIS)

    Sweet, J.N.; McCreight, J.E.

    1979-01-01

    The measurements first reported by Acton on the thermal conductivity of samples taken from a borehole at the site of the proposed nuclear waste isolation pilot plant (WIPP) near Carlsbad, NM, have been extended to include additional samples and higher temperature measurements. Samples for our measurements were taken from several depths of three wells, including the well AEC 8 from which Acton obtained his samples. These samples ranged from relatively pure rocksalt (NaCl) with small amounts of interstitial anhydrite to essentially nonsalt samples composed of gypsum or clay. The measurements in this latest series were conducted at Sandia using the longitudinal heat flow apparatus described by Acton, at the Los Alamos Scientific Laboratory (LASL) using a transient line source technique, and at Dynatech Corp., Cambridge, MA using a linear heat flow comparative technique. On the basis of these experiments, we have concluded that the thermal conductivity of materials found at the site can be predicted to an accuracy approx. +- 30% from knowledge of the composition and grain size of these materials

  14. Thermal conductivity of rocksalt and other geologic materials from the site of the proposed waste isolation pilot plant

    International Nuclear Information System (INIS)

    Sweet, J.N.; McCreight, J.E.

    1980-01-01

    The measurements first reported by Acton on the thermal conductivity of samples taken from a borehole at the site of the proposed nuclear waste isolation pilot plant (WIPP) near Carlsbad, NM, have been extended to include additional samples and higher temperature measurements. Samples for measurements were taken from several depths of three wells, including the well AEC 8 from which Acton obtained his samples. These samples ranged from relatively pure rocksalt (NaCl) with small amounts of interstitial anhydrite to essentially nonsalt samples composed of gypsum or clay. The measurements in this latest series were conducted at Sandia, the Los Alamos Scientific Laboratory (LASL), and at Dynatech Corp. In general, the data from the three laboratories agreed reasonably well for similar coarse grained translucent rock salt samples, with the LASL and Sandia results typically being about 20% higher than those of Dynatceh. On the basis of these experiments, it is concluded that the thermal conductivity of materials found at the site can be predicted to an accuracy +-30% from knowledge of the composition and grain size of these materials

  15. Geochemistry of the Waste Isolation Pilot Plant (WIPP) site, southeastern New Mexico, U.S.A

    International Nuclear Information System (INIS)

    Lambert, S.J.

    1992-01-01

    An extensive geochemical data base, including analyses of major and minor solutes, mineralogical studies of core samples, and isotopic studies of waters, carbonates and sulfates, has been assembled for evaporites and related rocks in the northern Delaware Basin of southeastern New Mexico. These data were compiled for the geological and hydrological characterization of the Waste Isolation Pilot Plant (WIPP), which is excavated in the evaporites of the Salado Formation. These data were evaluated in order:(1) to determine the stability of the evaporite mineralogy over geological time; (2) to compare the aqueous geochemistry with host rock mineralogy; (3) to delineate the nature and timing of water-rock interactions, such as dissolution and recrystallization; and (4) to determine the geological and climatic conditions that have governed groundwater recharge. The resulting synthesis of data and current hypotheses concerning the origin, composition and history of waters in the evaporite rocks and related units of the Delaware Basin provides a tentative conceptual model for the behavior of the water-rock system since the deposition of the evaporites in the Permian. Essential components of this model include: (1) widespread Late Triassic/Early Jurassic evaporite recrystallization; (2) accumulation of deep-basin brines isolated from meteoric recharge; (3) evaporite dissolution by meteoric waters flowing in carbonates and sulfates interbedded in the uppermost Permian section and at the basin margin; (4) lateral rather than vertical infiltration of pre-Holocene meteoric waters in the uppermost Permian section; and (5) climatic conditions presently less conductive to recharge than in the Late Pleistocene. (author)

  16. Cross-prediction of the groundwater chemistry at the SKB sites in Sweden. Pilot study

    International Nuclear Information System (INIS)

    Skaarman, C.; Laaksoharju, M.

    1997-08-01

    The possibility to perform a large scale prediction throughout Sweden was tested. The aim of the work was: to collect data and create a groundwater database for current and future use; to see if there is any correlation between data at different sites; to perform a modelling where the groundwater composition at different regions in Sweden is predicted. The outcome of the predictions were compared with the measured data at different sites. The results show that it is possible but more work needs to be done to improve the prediction models. More measurements at depth are needed to enable the use of 3D models. It is also important to include hydrogeological parameters in the groundwater chemical prediction models that are used

  17. An Intraoperative Site-specific Bone Density Device: A Pilot Test Case.

    Science.gov (United States)

    Arosio, Paolo; Moschioni, Monica; Banfi, Luca Maria; Di Stefano, Anilo Alessio

    2015-08-01

    This paper reports a case of all-on-four rehabilitation where bone density at implant sites was assessed both through preoperative computed tomographic (CT) scans and using a micromotor working as an intraoperative bone density measurement device. Implant-supported rehabilitation is a predictable treatment option for tooth replacement whose success depends on the clinician's experience, the implant characteristics and location and patient-related factors. Among the latter, bone density is a determinant for the achievement of primary implant stability and, eventually, for implant success. The ability to measure bone density at the placement site before implant insertion could be important in the clinical setting. A patient complaining of masticatory impairment was presented with a plan calling for extraction of all her compromised teeth, followed by implant rehabilitation. A week before surgery, she underwent CT examination, and the bone density on the CT scans was measured. When the implant osteotomies were created, the bone density was again measured with a micromotor endowed with an instantaneous torque-measuring system. The implant placement protocols were adapted for each implant, according to the intraoperative measurements, and the patient was rehabilitated following an all-on-four immediate loading protocol. The bone density device provided valuable information beyond that obtained from CT scans, allowing for site-specific, intraoperative assessment of bone density immediately before implant placement and an estimation of primary stability just after implant insertion. Measuring jaw-bone density could help clinicians to select implant-placement protocols and loading strategies based on site-specific bone features.

  18. Pilot study risk assessment for selected problems at the Nevada Test Site (NTS)

    Energy Technology Data Exchange (ETDEWEB)

    Daniels, J.I. [ed.; Anspaugh, L.R.; Bogen, K.T.; Daniels, J.I.; Layton, D.W.; Straume, T. [Lawrence Livermore National Lab., CA (United States); Andricevic, R.; Jacobson, R.L. [Nevada Univ., Las Vegas, NV (United States). Water Resources Center; Meinhold, A.F.; Holtzman, S.; Morris, S.C.; Hamilton, L.D. [Brookhaven National Lab., Upton, NY (United States)

    1993-06-01

    The Nevada Test Site (NTS) is located in southwestern Nevada, about 105 km (65 mi) northwest of the city of Las Vegas. A series of tests was conducted in the late 1950s and early 1960s at or near the NTS to study issues involving plutonium-bearing devices. These tests resulted in the dispersal of about 5 TBq of {sup 239,24O}Pu on the surficial soils at the test locations. Additionally, underground tests of nuclear weapons devices have been conducted at the NTS since late 1962; ground water beneath the NTS has been contaminated with radionuclides produced by these tests. These two important problems have been selected for assessment. Regarding the plutonium contamination, because the residual {sup 239}Pu decays slowly (half-life of 24,110 y), these sites could represent a long-term hazard if they are not remediated and if institutional controls are lost. To investigate the magnitude of the potential health risks for this no-remediation case, three basic exposure scenarios were defined that could bring individuals in contact with {sup 239,24O}Pu at the sites: (1) a resident living in a subdivision, (2) a resident farmer, and (3) a worker at a commercial facility -- all located at a test site. The predicted cancer risks for the resident farmer were more than a factor of three times higher than the suburban resident at the median risk level, and about a factor of ten greater than the reference worker at a commercial facility. At 100 y from the present, the 5, 50, and 95th percentile risks for the resident farmer at the most contaminated site were 4 x 10{sup {minus}6}, 6 x 10{sup {minus}5}, and 5 x 10{sup {minus}4}, respectively. For the assessment of Pu in surface soil, the principal sources of uncertainty in the estimated risks were population mobility, the relationship between indoor and outdoor contaminant levels, and the dose and risk factors for bone, liver, and lung.

  19. Pilot study risk assessment for selected problems at the Nevada Test Site (NTS)

    Energy Technology Data Exchange (ETDEWEB)

    Daniels, J.I. (ed.)

    1993-06-01

    The Nevada Test Site (NTS) is located in southwestern Nevada, about 105 km (65 mi) northwest of the city of Las Vegas. A series of tests was conducted in the late 1950s and early 1960s at or near the NTS to study issues involving plutonium-bearing devices. These tests resulted in the dispersal of about 5 TBq of [sup 239,24O]Pu on the surficial soils at the test locations. Additionally, underground tests of nuclear weapons devices have been conducted at the NTS since late 1962; ground water beneath the NTS has been contaminated with radionuclides produced by these tests. These two important problems have been selected for assessment. Regarding the plutonium contamination, because the residual [sup 239]Pu decays slowly (half-life of 24,110 y), these sites could represent a long-term hazard if they are not remediated and if institutional controls are lost. To investigate the magnitude of the potential health risks for this no-remediation case, three basic exposure scenarios were defined that could bring individuals in contact with [sup 239,24O]Pu at the sites: (1) a resident living in a subdivision, (2) a resident farmer, and (3) a worker at a commercial facility -- all located at a test site. The predicted cancer risks for the resident farmer were more than a factor of three times higher than the suburban resident at the median risk level, and about a factor of ten greater than the reference worker at a commercial facility. At 100 y from the present, the 5, 50, and 95th percentile risks for the resident farmer at the most contaminated site were 4 x 10[sup [minus]6], 6 x 10[sup [minus]5], and 5 x 10[sup [minus]4], respectively. For the assessment of Pu in surface soil, the principal sources of uncertainty in the estimated risks were population mobility, the relationship between indoor and outdoor contaminant levels, and the dose and risk factors for bone, liver, and lung.

  20. Pilot-scale bioremediation of a petroleum hydrocarbon-contaminated clayey soil from a sub-Arctic site

    Energy Technology Data Exchange (ETDEWEB)

    Akbari, Ali; Ghoshal, Subhasis, E-mail: subhasis.ghoshal@mcgill.ca

    2014-09-15

    Highlights: • Aeration and moisture addition alone caused extensive hydrocarbon biodegradation. • 30-day slurry reactor remediation endpoints attained in 385 days in biopiles. • High nitrogen concentrations inhibited hydrocarbon degradation. • Inhibition of biodegradation linked to lack of shifts in soil microbial community. - Abstract: Bioremediation is a potentially cost-effective solution for petroleum contamination in cold region sites. This study investigates the extent of biodegradation of petroleum hydrocarbons (C16–C34) in a pilot-scale biopile experiment conducted at 15 °C for periods up to 385 days, with a clayey soil, from a crude oil-impacted site in northern Canada. Although several studies on bioremediation of petroleum hydrocarbon-contaminated soils from cold region sites have been reported for coarse-textured, sandy soils, there are limited studies of bioremediation of petroleum contamination in fine-textured, clayey soils. Our results indicate that aeration and moisture addition was sufficient for achieving 47% biodegradation and an endpoint of 530 mg/kg for non-volatile (C16–C34) petroleum hydrocarbons. Nutrient amendment with 95 mg-N/kg showed no significant effect on biodegradation compared to a control system without nutrient but similar moisture content. In contrast, in a biopile amended with 1340 mg-N/kg, no statistically significant biodegradation of non-volatile fraction was detected. Terminal Restriction Fragment Length Polymorphism (T-RFLP) analyses of alkB and 16S rRNA genes revealed that inhibition of hydrocarbon biodegradation was associated with a lack of change in microbial community composition. Overall, our data suggests that biopiles are feasible for attaining the bioremediation endpoint in clayey soils. Despite the significantly lower biodegradation rate of 0.009 day{sup −1} in biopile tank compared to 0.11 day{sup −1} in slurry bioreactors for C16–C34 hydrocarbons, the biodegradation extents for this fraction

  1. Pilot-scale bioremediation of a petroleum hydrocarbon-contaminated clayey soil from a sub-Arctic site

    International Nuclear Information System (INIS)

    Akbari, Ali; Ghoshal, Subhasis

    2014-01-01

    Highlights: • Aeration and moisture addition alone caused extensive hydrocarbon biodegradation. • 30-day slurry reactor remediation endpoints attained in 385 days in biopiles. • High nitrogen concentrations inhibited hydrocarbon degradation. • Inhibition of biodegradation linked to lack of shifts in soil microbial community. - Abstract: Bioremediation is a potentially cost-effective solution for petroleum contamination in cold region sites. This study investigates the extent of biodegradation of petroleum hydrocarbons (C16–C34) in a pilot-scale biopile experiment conducted at 15 °C for periods up to 385 days, with a clayey soil, from a crude oil-impacted site in northern Canada. Although several studies on bioremediation of petroleum hydrocarbon-contaminated soils from cold region sites have been reported for coarse-textured, sandy soils, there are limited studies of bioremediation of petroleum contamination in fine-textured, clayey soils. Our results indicate that aeration and moisture addition was sufficient for achieving 47% biodegradation and an endpoint of 530 mg/kg for non-volatile (C16–C34) petroleum hydrocarbons. Nutrient amendment with 95 mg-N/kg showed no significant effect on biodegradation compared to a control system without nutrient but similar moisture content. In contrast, in a biopile amended with 1340 mg-N/kg, no statistically significant biodegradation of non-volatile fraction was detected. Terminal Restriction Fragment Length Polymorphism (T-RFLP) analyses of alkB and 16S rRNA genes revealed that inhibition of hydrocarbon biodegradation was associated with a lack of change in microbial community composition. Overall, our data suggests that biopiles are feasible for attaining the bioremediation endpoint in clayey soils. Despite the significantly lower biodegradation rate of 0.009 day −1 in biopile tank compared to 0.11 day −1 in slurry bioreactors for C16–C34 hydrocarbons, the biodegradation extents for this fraction were

  2. Pilot-scale bioremediation of a petroleum hydrocarbon-contaminated clayey soil from a sub-Arctic site.

    Science.gov (United States)

    Akbari, Ali; Ghoshal, Subhasis

    2014-09-15

    Bioremediation is a potentially cost-effective solution for petroleum contamination in cold region sites. This study investigates the extent of biodegradation of petroleum hydrocarbons (C16-C34) in a pilot-scale biopile experiment conducted at 15°C for periods up to 385 days, with a clayey soil, from a crude oil-impacted site in northern Canada. Although several studies on bioremediation of petroleum hydrocarbon-contaminated soils from cold region sites have been reported for coarse-textured, sandy soils, there are limited studies of bioremediation of petroleum contamination in fine-textured, clayey soils. Our results indicate that aeration and moisture addition was sufficient for achieving 47% biodegradation and an endpoint of 530 mg/kg for non-volatile (C16-C34) petroleum hydrocarbons. Nutrient amendment with 95 mg-N/kg showed no significant effect on biodegradation compared to a control system without nutrient but similar moisture content. In contrast, in a biopile amended with 1340 mg-N/kg, no statistically significant biodegradation of non-volatile fraction was detected. Terminal Restriction Fragment Length Polymorphism (T-RFLP) analyses of alkB and 16S rRNA genes revealed that inhibition of hydrocarbon biodegradation was associated with a lack of change in microbial community composition. Overall, our data suggests that biopiles are feasible for attaining the bioremediation endpoint in clayey soils. Despite the significantly lower biodegradation rate of 0.009 day(-1) in biopile tank compared to 0.11 day(-1) in slurry bioreactors for C16-C34 hydrocarbons, the biodegradation extents for this fraction were comparable in these two systems. Copyright © 2014 Elsevier B.V. All rights reserved.

  3. Mise au point d'un pilote micro-ondes multifonction en vue d'un séchage d'algues alimentaires

    OpenAIRE

    Mikula, Stéphane

    1992-01-01

    Le séchage ou dessiccation consiste à évacuer l'eau d'un matériau humide vers le milieu ambiant dans le but d'en assurer la stabilité. Actuellement, le séchage à l'air chaud est le mode de déshydratation le plus employé dans le monde pour le traitement des denrées alimentaires. Cependant, cette technique présente quelques inconvénients. Au cours du séchage, il se produit généralement un gradient de déshydratation aboutissant à un dessèchement superficiel caractérisé par un croûtage et u...

  4. Pilot study risk assessment for selected problems at the Savannah River Site (SRS)

    International Nuclear Information System (INIS)

    Hamilton, L.D.; Holtzman, S.; Meinhold, A.; Morris, S.C.; Pardi, R.; Sun, C.; Daniels, J.I.; Layton, D.; McKone, T.E.; Straume, T.; Anspaugh, L.

    1993-03-01

    An assessment of the health risks was made for releases of tritium and 137 Cs from the Savannah River Site (SRS) at water-receptor locations downriver. Although reactor operations were shut down at the SRS in 1989, liquid wastes continue to be released to the Savannah River either by direct discharges into onsite surface waters or by groundwater transport into surface waters from waste facilities. Existing state mandates will cause the liquid waste streams from future operations to go directly into surface waters. Two drinking water processing plants take water from the river approximately 129 km downriver from the SRS. Potential incremental risks of cancer fatality to individuals and each population were analyzed for either no further reactor operations or resumption of operation of one specific reactor

  5. Pilot study risk assessment for selected problems at the Savannah River Site (SRS)

    Energy Technology Data Exchange (ETDEWEB)

    Hamilton, L.D.; Holtzman, S.; Meinhold, A.; Morris, S.C.; Pardi, R.; Sun, C. [Brookhaven National Lab., Upton, NY (United States); Daniels, J.I.; Layton, D.; McKone, T.E.; Straume, T.; Anspaugh, L. [Lawrence Livermore National Lab., CA (United States)

    1993-03-01

    An assessment of the health risks was made for releases of tritium and {sup 137}Cs from the Savannah River Site (SRS) at water-receptor locations downriver. Although reactor operations were shut down at the SRS in 1989, liquid wastes continue to be released to the Savannah River either by direct discharges into onsite surface waters or by groundwater transport into surface waters from waste facilities. Existing state mandates will cause the liquid waste streams from future operations to go directly into surface waters. Two drinking water processing plants take water from the river approximately 129 km downriver from the SRS. Potential incremental risks of cancer fatality to individuals and each population were analyzed for either no further reactor operations or resumption of operation of one specific reactor.

  6. Pilot study risk assessment for selected problems at the Savannah River Site (SRS)

    Energy Technology Data Exchange (ETDEWEB)

    Hamilton, L.D.; Holtzman, S.; Meinhold, A.; Morris, S.C.; Pardi, R.; Sun, C. (Brookhaven National Lab., Upton, NY (United States)); Daniels, J.I.; Layton, D.; McKone, T.E.; Straume, T.; Anspaugh, L. (Lawrence Livermore National Lab., CA (United States))

    1993-03-01

    An assessment of the health risks was made for releases of tritium and [sup 137]Cs from the Savannah River Site (SRS) at water-receptor locations downriver. Although reactor operations were shut down at the SRS in 1989, liquid wastes continue to be released to the Savannah River either by direct discharges into onsite surface waters or by groundwater transport into surface waters from waste facilities. Existing state mandates will cause the liquid waste streams from future operations to go directly into surface waters. Two drinking water processing plants take water from the river approximately 129 km downriver from the SRS. Potential incremental risks of cancer fatality to individuals and each population were analyzed for either no further reactor operations or resumption of operation of one specific reactor.

  7. Regional water balance for the Waste Isolation Pilot Plant (WIPP) site and surrounding area

    International Nuclear Information System (INIS)

    Hunter, R.L.

    1985-12-01

    The WIPP water-balance study area defined here comprises approx.2000 mi 2 in Eddy and Lea Counties, southeastern New Mexico. Inflows to the study area are precipitation (roughly 1.47 x 10 6 ac-ft/y), surface water (roughly 1.1 x 10 5 ac-ft/y), water imported by municipalities and industries (roughly 3 x 10 4 ac-ft/y), and ground water (volume not estimated). Outflows from the area are evapotranspiration (roughly 1.5 x 10 6 ac-ft/y), surface water (roughly 1.2 x 10 5 ac-ft/y), and possibly some ground water. The volume of surface and ground water in storage in Nash Draw has increased since the beginning of potash refining. Regional ground-water flow in aquifers above the Salado Formation is from the northeast to the southwest, although this pattern is interrupted by Clayton Basin, Nash Draw, and San Simon Swale. The Pecos River is the only important perennial stream. Most of the area has no integrated surface-water drainage. The available data suggest that approx.1600 mi 2 of the study area are hydrologically separate from Nash Draw and the WIPP site. Ground water north of Highway 180 apparently discharges into Clayton Basin and evaporates. Water in San Simon Swale apparently percolates downward and flows to the southeast. Data are inadequate to create a water budget for the Nash Draw-WIPP site hydrologic system alone, although an attempt to do so can provide guidance for further study

  8. Interaction of radionuclides with geomedia associated with the Waste Isolation Pilot Plant (WIPP) site in New Mexico

    International Nuclear Information System (INIS)

    Dosch, R.G.; Lynch, A.W.

    1978-06-01

    A survey of the potential of geological media from the vicinity of the Waste Isolation Pilot Plant site in Southeastern New Mexico for retardation of radionuclide migration in an aqueous carrier was conducted. The survey included the measurement of sorption coefficients (Kd) for twelve radionuclides between three natural water simulants and ten samples from various geological strata. The nuclides included 137 Cs, 85 Sr, 131 I, 99 Tc, 125 Sb, 144 Ce, 152 Eu, 153 Gd, 106 Ru, 243 Am, 244 Cm, and 238 Pu. The compositions of the simulant solutions were those expected of water in contact with potash minerals or halite deposits in the area and in a typical groundwater found in the Delaware Basin. The geological samples were obtained from potential aquifers above and below the proposed repository horizons and from bedded salt deposits in the repository horizons. In brine solutions, Tc and I were not significantly adsorbed by any of the minerals and Cs and Sr showed minimal adsorption (Kd's 10 3 and Ru and Sb Kd's varied in the range of 25 to > 10 3 . In the groundwater simulant, Tc and I showed the same behavior, but the Kd's of the other nuclides were generally higher. Some initial parametric studies involving pH, trace organic constituents in the simulant solutions, and radionuclide concentrations were carried out. Significant differences in the observed Kd's can result from varying one or more of these solution parameters

  9. Analysis of solutes in groundwaters from the Rustler Formation at and near the Waste Isolation Pilot Plant site

    International Nuclear Information System (INIS)

    Robinson, K.L.

    1997-09-01

    Between 1976 and 1986, groundwater samples from more than 60 locations in the vicinity of the Waste Isolation Pilot Plant site were collected and analyzed for a variety of major, minor, and trace solutes. Most of the samples were from the Rustler Formation (the Culebra Dolomite, the Magenta Dolomite, or the zone at the contact between the Rustler and underlying Salado Formations) or the Dewey Lake Red Beds. The analytical data from the laboratories are presented here with accompanying discussions of sample collection methods, supporting field measurements, and laboratory analytical methods. A comparison of four data sets and a preliminary evaluation of the data for the major solutes (Cl - , SO 4 -2 , Na, K, Ca, and Mg) shows that the data for samples analyzed by UNC/Bendix for SNL seem to be the most reliable, but that at some locations, samples representative of the native, unperturbed groundwater have not been collected. At other locations, the water chemistry has apparently changed between sampling episodes

  10. Novel implant design improves implant survival in multirooted extraction sites: a preclinical pilot study.

    Science.gov (United States)

    Sivan-Gildor, Adi; Machtei, Eli E; Gabay, Eran; Frankenthal, Shai; Levin, Liran; Suzuki, Marcelo; Coelho, Paulo G; Zigdon-Giladi, Hadar

    2014-10-01

    The primary aim is to evaluate clinical, radiographic, and histologic parameters of novel implants with "three roots" design that were inserted into fresh multirooted extraction sockets. A secondary aim is to compare this new implant to standard root-form dental implants. Immediate implantation of novel or standard design 6 × 6-mm implants was performed bilaterally into multirooted sockets in mandibles of mini-pigs. Twelve weeks later, clinical, radiographic, stability, histomorphometric, and microcomputed tomography (micro-CT) analyses were performed. Survival rates were significantly higher in the test implants compared with control (92.8% versus 33.3%, respectively; P micro-CT analyses demonstrated bone fill in the inner part of the test implants. Moreover, bone-to-implant contact was higher in the test implants (55.50% ± 3.68% versus 42.47% ± 9.89%). Contrary to the clinical, radiographic, and histomorphometric results, resonance frequency analysis measurements were greater in the control group (77.74 ± 3.21 implant stability quotient [ISQ]) compared with the test group (31.09 ± 0.28 ISQ), P = 0.008. The novel design implants resulted in significantly greater survival rate in multirooted extraction sites. Further studies will be required to validate these findings.

  11. Monitoring of well integrity by magnetic imaging defectoscopy (MID) at the Ketzin pilot site, Germany

    Science.gov (United States)

    Zemke, Kornelia; Liebscher, Axel; Möller, Fabian

    2017-04-01

    One of the key requirements for safe CO2 storage operation is to ensure wellbore integrity. The CO2 triggered acid in-well environment may lead to pitting and/or surface corrosion and eventually to fatigue of well casings and cementation by this giving raise to wellbore leakage. Corrosion effects are conventionally monitored by measurement of inner casing surface, internal diameter and wall thickness. Caliper logging provides inner surface and internal diameter data while ultrasonic tools measure both the internal diameter and casing thickness as well as the bonding between casing and cement. However, both tools can only monitor and characterize the most inner casing and ultrasonic tools in addition can only be applied in fluid filled wells. At the Ketzin CO2 storage test site, Germany, about 67 kt of CO2 were injected between June 2008 and August 2013 and an interdisciplinary monitoring concept was developed with focus on the storage complex, the overburden, the surface and the wellbores. Four deep wells penetrate the reservoir and their integrity has been monitored by a combination of video inspection, pulsed neutron gamma logging PNG and magnetic imaging defectoscopy MID. MID is an advanced logging method for non-destructive testing and has the great advantages that it can be operated in gas filled boreholes and that it provides information also for outer casings. The MID tool generates electromagnetic pulsed transient eddy currents and records the response of the surrounding media. The distribution and strength of the eddy-currents is then converted into averaged, depth-resolved thicknesses of the individual casings. Run in time-lapse mode, MID provides a measure to detect changes in casing thickness and therefore hints to corrosion. At Ketzin, the four deep wells haven been monitored by repeat MID logging on a roughly annual basis in cooperation with VNG Gasspeicher GmbH (VGS) and GAZPROMENERGODIAGNOSTIKA, applying their in-house MID tool. The MID based depth

  12. Interpretation of brine-permeability tests of the Salado Formation at the Waste Isolation Pilot Plant site: First interim report

    International Nuclear Information System (INIS)

    Beauheim, R.L.; Saulnier, G.J. Jr.; Avis, J.D.

    1991-08-01

    Pressure-pulse tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Hydraulic conductivities ranging from about 10 -14 to 10 -11 m/s (permeabilities of about 10 -21 to 10 -18 m 2 ) have been interpreted from nine tests conducted on five stratigraphic intervals within eleven meters of the WIPP underground excavations. Tests of a pure halite layer showed no measurable permeability. Pore pressures in the stratigraphic intervals range from about 0.5 to 9.3 MPa. An anhydrite interbed (Marker Bed 139) appears to be one or more orders of magnitude more permeable than the surrounding halite. Hydraulic conductivities appear to increase, and pore pressures decrease, with increasing proximity to the excavations. These effects are particularly evident within two to three meters of the excavations. Two tests indicated the presence of apparent zero-flow boundaries about two to three meters from the boreholes. The other tests revealed no apparent boundaries within the radii of influence of the tests, which were calculated to range from about four to thirty-five meters from the test holes. The data are insufficient to determine if brine flow through evaporites results from Darcy-like flow driven by pressure gradients within naturally interconnected porosity or from shear deformation around excavations connecting previously isolated pores, thereby providing pathways for fluids at or near lithostatic pressure to be driven towards the low-pressure excavations. Future testing will be performed at greater distances from the excavations to evaluate hydraulic properties and processes beyond the range of excavation effects

  13. The potential of subterranean microbes in facilitating actinide migration at the Grimsel test site and waste isolation pilot plant

    International Nuclear Information System (INIS)

    Gillow, J.B.; Dunn, M.; Francis, A.J.; Lucero, D.A.; Papenguth, H.W.

    2000-01-01

    Microorganisms may affect the long-term stability and mobility of radionuclides disposed of in deep geological formations. Of particular concern is the association of radionuclides with subterranean microbial cells and their subsequent transport as biocolloids. We characterized the total microbial populations in two groundwater samples: one from the Culebra dolomite member of the Rustler formation at the waste isolation pilot plant (WIPP), NM, and the other from the granitic formation at the Grimsel test site (GTS), Switzerland. Culebra groundwater (ionic strength 2.8 M, pH 7) contained 1.51 ± 1.08 x 10 5 cells ml -1 , with a mean cell length of 0.75 ± 0.04 μm and width of 0.58 ± 0.02 μm. In contrast, low ionic-strength GTS groundwater (0.001 M, pH 10) contained 3.97 ± 0.37 x 10 3 cells ml -1 , with a mean cell length of 1.50 ± 0.14 μm and width of 0.37 ± 0.01 μm. Adding appropriate electron donors and acceptors to the groundwaters facilitated the growth of aerobic, denitrifying, fermentative, and acetogenic microorganisms. Uranium biosorption was studied in two isolates from these groundwaters, as well as several pure cultures from saline and non-saline environments. Halophilic and non-halophilic bacteria exhibited differences in the amount of U associated with the cells. Plutonium uptake by Acetobacterium sp. isolated from GTS varied from 30-145 pg of Pu mg -1 dry weight of cells. (orig.)

  14. Performance of statistical process control methods for regional surgical site infection surveillance: a 10-year multicentre pilot study.

    Science.gov (United States)

    Baker, Arthur W; Haridy, Salah; Salem, Joseph; Ilieş, Iulian; Ergai, Awatef O; Samareh, Aven; Andrianas, Nicholas; Benneyan, James C; Sexton, Daniel J; Anderson, Deverick J

    2017-11-24

    Traditional strategies for surveillance of surgical site infections (SSI) have multiple limitations, including delayed and incomplete outbreak detection. Statistical process control (SPC) methods address these deficiencies by combining longitudinal analysis with graphical presentation of data. We performed a pilot study within a large network of community hospitals to evaluate performance of SPC methods for detecting SSI outbreaks. We applied conventional Shewhart and exponentially weighted moving average (EWMA) SPC charts to 10 previously investigated SSI outbreaks that occurred from 2003 to 2013. We compared the results of SPC surveillance to the results of traditional SSI surveillance methods. Then, we analysed the performance of modified SPC charts constructed with different outbreak detection rules, EWMA smoothing factors and baseline SSI rate calculations. Conventional Shewhart and EWMA SPC charts both detected 8 of the 10 SSI outbreaks analysed, in each case prior to the date of traditional detection. Among detected outbreaks, conventional Shewhart chart detection occurred a median of 12 months prior to outbreak onset and 22 months prior to traditional detection. Conventional EWMA chart detection occurred a median of 7 months prior to outbreak onset and 14 months prior to traditional detection. Modified Shewhart and EWMA charts additionally detected several outbreaks earlier than conventional SPC charts. Shewhart and SPC charts had low false-positive rates when used to analyse separate control hospital SSI data. Our findings illustrate the potential usefulness and feasibility of real-time SPC surveillance of SSI to rapidly identify outbreaks and improve patient safety. Further study is needed to optimise SPC chart selection and calculation, statistical outbreak detection rules and the process for reacting to signals of potential outbreaks. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2017. All rights

  15. Interpretation of brine-permeability tests of the Salado Formation at the Waste Isolation Pilot Plant site: First interim report

    Energy Technology Data Exchange (ETDEWEB)

    Beauheim, R.L. (Sandia National Labs., Albuquerque, NM (United States)); Saulnier, G.J. Jr.; Avis, J.D. (INTERA, Inc., Austin, TX (United States))

    1991-08-01

    Pressure-pulse tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Hydraulic conductivities ranging from about 10{sup {minus}14} to 10{sup {minus}11} m/s (permeabilities of about 10{sup {minus}21} to 10{sup {minus}18} m{sup 2}) have been interpreted from nine tests conducted on five stratigraphic intervals within eleven meters of the WIPP underground excavations. Tests of a pure halite layer showed no measurable permeability. Pore pressures in the stratigraphic intervals range from about 0.5 to 9.3 MPa. An anhydrite interbed (Marker Bed 139) appears to be one or more orders of magnitude more permeable than the surrounding halite. Hydraulic conductivities appear to increase, and pore pressures decrease, with increasing proximity to the excavations. These effects are particularly evident within two to three meters of the excavations. Two tests indicated the presence of apparent zero-flow boundaries about two to three meters from the boreholes. The other tests revealed no apparent boundaries within the radii of influence of the tests, which were calculated to range from about four to thirty-five meters from the test holes. The data are insufficient to determine if brine flow through evaporites results from Darcy-like flow driven by pressure gradients within naturally interconnected porosity or from shear deformation around excavations connecting previously isolated pores, thereby providing pathways for fluids at or near lithostatic pressure to be driven towards the low-pressure excavations. Future testing will be performed at greater distances from the excavations to evaluate hydraulic properties and processes beyond the range of excavation effects.

  16. Enlisted or Officer Drone Pilots

    Science.gov (United States)

    2010-04-01

    the property of the United States government. AU/ACSC/Rafnson, Gary B/AY10 3 Abstract This paper compares remotely piloted aircraft— drones ...operations in both the US Army and US Air Force. It argues that officers should continue to pilot Air Force drones because of the increased risks and

  17. From Site Characterization through Safe and Successful CO2 Injection Operation to Post-injection Monitoring and Site Closure - Closing the Full Life Cycle Research at the Ketzin Pilot Site, Germany

    Science.gov (United States)

    Liebscher, Axel

    2017-04-01

    Initiated in 2004, the Ketzin pilot site near Berlin, Germany, was the first European onshore storage project for research and development on geological CO2 storage. After comprehensive site characterization the site infrastructure was build comprising three deep wells and the injection facility including pumps and storage tanks. The operational CO2 injection period started in June 2008 and ended in August 2013 when the site entered the post-injection closure period. During these five years, a total amount of 67 kt of CO2 was safely injected into an Upper Triassic saline sandstone aquifer at a depth of 630 m - 650 m. In fall 2013, the first observation well was partially plugged in the reservoir section with CO2 resistant cement; full abandonment of this well finished in 2015 after roughly 2 years of cement plug monitoring. Abandonment of the remaining wells will be finished by summer 2017 and hand-over of liability to the competent authority is scheduled for end of 2017. The CO2 injected was mainly of food grade quality (purity > 99.9%). In addition, 1.5 kt of CO2 from the oxyfuel pilot capture facility "Schwarze Pumpe" (purity > 99.7%) was injected in 2011. The injection period terminated with a CO2-N2 co-injection experiment of 650 t of a 95% CO2/5% N2 mixture in summer 2013 to study the effects of impurities in the CO2 stream on the injection operation. During regular operation, the CO2 was pre-heated on-site to 40°C prior to injection to ensure a single-phase injection process and avoid any phase transition or transient states within the injection facility or the reservoir. Between March and July 2013, just prior to the CO2-N2 co-injection experiment, the injection temperature was stepwise decreased down to 10°C within a "cold-injection" experiment to study the effects of two-phase injection conditions. During injection operation, the combination of different geochemical and geophysical monitoring methods enabled detection and mapping of the spatial and

  18. Comparative Study of Surface-lattice-site Resolved Neutralization of Slow Multicharged Ions during Large-angle Quasi-binary Collisions with Au(110): Simulation and Experiment

    International Nuclear Information System (INIS)

    Meyer, F.W.

    2001-01-01

    In this article we extend our earlier studies of the azimuthal dependences of low energy projectiles scattered in large angle quasi-binary collisions from Au(110). Measurements are presented for 20 keV Ar 9+ at normal incidence, which are compared with our earlier measurements for this ion at 5 keV and 10 0 incidence angle. A deconvolution procedure based on MARLOWE simulation results carried out at both energies provides information about the energy dependence of projectile neutralization during interactions just with the atoms along the top ridge of the reconstructed Au(110) surface corrugation, in comparison to, e.g., interactions with atoms lying on the sidewalls. To test the sensitivity of the agreement between the MARLOWE results and the experimental measurements, we show simulation results obtained for a non-reconstructed Au(110) surface with 20 keV Ar projectiles, and for different scattering potentials that are intended to simulate the effects on scattering trajectory of a projectile inner shell vacancy surviving the binary collision, In addition, simulation results are shown for a number of different total scattering angles, to illustrate their utility in finding optimum values for this parameter prior to the actual measurements

  19. Central Au on Au collisions

    Energy Technology Data Exchange (ETDEWEB)

    Alard, J.P.; Amouroux, V. [Labo de Phys. Corp., IN2P3-CRNS, Univ. Blaise Pascal, Clermont-Fd. (France); Basrak, Z. [Rudjer Boskovic Institute, Zagreb (Croatia)] [and others; FOPI-Collaboration

    1995-02-06

    In nucleus-nucleus collisions the initial relative kinetic energy of target and projectile is available for internal excitation of the interacting system; it is however still not well established to what extent local equilibrium and thermalisation occur. Local equilibrium is of interest to derive, within the formalism of transport equations and of the equation of state, (EOS), general properties of compressed and excited nuclear matter. Such approach describes in relatively simple terms the complex many body interactions occuring within extended baryonic and hadronic (or quark) matter. For a basic microscopic understanding it is highly desirable to investigate the elementary in-medium interactions in relation to the free elementary processes. Excitation function measurements of central collisions between the heaviest available nuclei (like Au on Au), supply the best ground for such studies: the highest degree of thermalisation and compression is expected for such reactions. The consideration presented here of energy thermalisation and of an expanding system clusterizing at freeze-out in a situation close to the liquid gas phase transition can be of interest to astrophysics as well as to the quark gluon plasma deconfinement studied in nucleus-nucleus collisions at the higher energy regime of CERN and Brookhaven. (orig.).

  20. Pilot studies for the North American Soil Geochemical Landscapes Project - Site selection, sampling protocols, analytical methods, and quality control protocols

    Science.gov (United States)

    Smith, D.B.; Woodruff, L.G.; O'Leary, R. M.; Cannon, W.F.; Garrett, R.G.; Kilburn, J.E.; Goldhaber, M.B.

    2009-01-01

    In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada sampled and chemically analyzed soils along two transects across Canada and the USA in preparation for a planned soil geochemical survey of North America. This effort was a pilot study to test and refine sampling protocols, analytical methods, quality control protocols, and field logistics for the continental survey. A total of 220 sample sites were selected at approximately 40-km intervals along the two transects. The ideal sampling protocol at each site called for a sample from a depth of 0-5 cm and a composite of each of the O, A, and C horizons. The Ca, Fe, K, Mg, Na, S, Ti, Ag, As, Ba, Be, Bi, Cd, Ce, Co, Cr, Cs, Cu, Ga, In, La, Li, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Sn, Sr, Te, Th, Tl, U, V, W, Y, and Zn by inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry following a near-total digestion in a mixture of HCl, HNO3, HClO4, and HF. Separate methods were used for Hg, Se, total C, and carbonate-C on this same size fraction. Only Ag, In, and Te had a large percentage of concentrations below the detection limit. Quality control (QC) of the analyses was monitored at three levels: the laboratory performing the analysis, the USGS QC officer, and the principal investigator for the study. This level of review resulted in an average of one QC sample for every 20 field samples, which proved to be minimally adequate for such a large-scale survey. Additional QC samples should be added to monitor within-batch quality to the extent that no more than 10 samples are analyzed between a QC sample. Only Cr (77%), Y (82%), and Sb (80%) fell outside the acceptable limits of accuracy (% recovery between 85 and 115%) because of likely residence in mineral phases resistant to the acid digestion. A separate sample of 0-5-cm material was collected at each site for determination of organic compounds. A subset of 73 of these samples was analyzed for a suite of

  1. Tracer-level radioactive pilot-scale test of in situ vitrification technology for the stabilization of contaminated soil sites at ORNL

    International Nuclear Information System (INIS)

    Jacobs, G.K.; Spalding, B.P.

    1991-11-01

    This plan summarizes the activities to be performed during FY 1990 and FY 1991 for the tracer-level radioactive pilot-scale in situ vitrification (ISV) test. This test is the second step in evaluating ISV as a remedial action for the pits and trenches at Oak Ridge National Laboratory (ORNL). A previous test used nonradioactive tracers for cesium and strontium. This new test will again use a one-half-scale model of trench 7 and the pilot-scale ISV equipment of Pacific Northwest Laboratory (PNL). A small and precisely known amount of waste from a liquid waste disposal pit will be used for the test. An actually contaminated waste site cannot be used for this test because of the necessity to use an exactly known inventory of radionuclides so that a precise measurement of the volatilization of various constituents to the off-gas can be determined

  2. Community health workers and smartphones for the detection of surgical site infections in rural Haiti: a pilot study.

    Science.gov (United States)

    Matousek, Alexi; Paik, Ken; Winkler, Eric; Denike, Jennifer; Addington, Stephen R; Exe, Chauvet; Louis, Rodolphe R E Jean; Riviello, Robert

    2015-04-27

    Absence of outcome data is a barrier to quality improvement in resource poor settings. To address this challenge, we set out to determine whether follow up for surgical site infections (SSIs) using community health workers (CHWs) and smartphones is feasible in rural Haiti. In this pilot study, all patients from a specific mountain region who received an operation between March 10, and July 1, 2014, at Hôpital Albert Schweitzer in rural Haiti were eligible for inclusion. Patients or guardians of minors were approached for consent. We designed a smartphone application to enable CHWs to screen for SSIs during home visits by administering a questionnaire, obtaining GPS data, and submitting a photograph of an incision. We selected and trained CHWs to use the smartphone application and compensated them based on performance. CHWs completed home visits for 30 days after an operation for all participants. Surgeons examined all participants within 24 h after the second CHW home visit. Primary outcomes included the number of participants completing 30-day follow-up and home visits made on time. Secondary outcomes included the quality of the photographs and the agreement between surgeons and CHWs on the diagnosis of SSI. The Partners Healthcare institutional review board and the Ethics Committee at Hôpital Albert Schweitzer approved the study protocol. Five CHWs completed 30-day follow up for 37 of 39 participants (94·9%) and completed 107 of 117 home visits on time (91·5%). High quality photographs were submitted for 101 of 117 visits (86·3%). Surgeons and CHWs agreed on the diagnosis of SSI in 28 of 33 cases (84·8%). Outpatient follow up for SSIs with CHWs and smartphones is feasible in rural Haiti. Further validation of the programme needs to be done before widespread adoption or advocating for task shifting post-operative follow up to CHWs. Partners Healthcare, Children's Hospital Boston, and Swiss Bündner Partnerschaft Hôpital Albert Schweitzer Haiti. Copyright

  3. Au pairs on Facebook

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2016-01-01

    Ethnographers are increasingly making use of Facebook to acquire access and general acquaintance with their field of study. However, little has been written on how Facebook is used methodologically in research that does not have social media sites as the main focus of interest. This article argues...... the au pairs resist and embrace such dominant representations, and on how such representations are ascribed different meanings in the transnational social fields of which the migrant are a part. The article is based on ethnographic fieldwork conducted between 2010 and 2014 in Denmark, the Philippines...

  4. Summary of computational support and general documentation for computer code (GENTREE) used in Office of Nuclear Waste Isolation Pilot Salt Site Selection Project

    International Nuclear Information System (INIS)

    Beatty, J.A.; Younker, J.L.; Rousseau, W.F.; Elayat, H.A.

    1983-01-01

    A Decision Tree Computer Model was adapted for the purposes of a Pilot Salt Site Selection Project conducted by the Office of Nuclear Waste Isolation (ONWI). A deterministic computer model was developed to structure the site selection problem with submodels reflecting the five major outcome categories (Cost, Safety, Delay, Environment, Community Impact) to be evaluated in the decision process. Time-saving modifications were made in the tree code as part of the effort. In addition, format changes allowed retention of information items which are valuable in directing future research and in isolation of key variabilities in the Site Selection Decision Model. The deterministic code was linked to the modified tree code and the entire program was transferred to the ONWI-VAX computer for future use by the ONWI project

  5. Contribution Economique et Sociale de la pêche artisanale au Sénégal

    OpenAIRE

    Dione, D.; Sy, A.B.; Ndiaye, M.S.

    2005-01-01

    Programme pour des Moyens d'Existence Durables dans la Pêche en Afrique de l'Ouest. Projet Pilote 1 "Moyens d'Existence améliorés dans le secteur post-capture de la pêche artisanale" au Cameroun, en Gambie, au Sénégal et au Tchad.

  6. SUPERFUND TREATABILITY CLEARINGHOUSE: FINAL REPORT: ON-SITE INCINERATION OF SHIRCO INFRARED SYSTEMS PORTABLE PILOT TEST UNIT, TIMES BEACH, MISSOURI

    Science.gov (United States)

    During the period of July 8 - July 12, 1985, the Shirco Infrared Systems Portable Pilot Test Unit was in operation at the Times Beach Dioxin Research Facility to demonstrate the capability of Shirco's infrared technology to decontaminate silty soil laden with 2,3,7,8-tetrachlorod...

  7. Advanced and Integrated Petrophysical Characterization for CO2 Storage: Application to the Ketzin Site Caractérisation pétrophysique intégrée pour le stockage de CO2 : application au site de Ketzin

    Directory of Open Access Journals (Sweden)

    Fleury M.

    2013-06-01

    perméabilité. La pression d’entrée a également été évaluée. Les diagraphies RMN et de résistivité ont également été utilisées pour estimer de manière continue la saturation irréductible et juger de la représentativité des échantillons analysés au laboratoire. Pour le site de Ketzin, la zone de stockage est un grès argileux d’origine fluviatile localement très cimenté d’une porosité d’environ 30 % et d’une perméabilité variant de 100 à 300 mD. Deux zones se distinguent par des saturations irréductibles variant de 15 à 35 %. La courbe de perméabilité relative à l’eau présente une forte pente et suggère qu’une saturation inférieure à 50 % n’est pas atteignable en pratique. L’exposant de saturation de l’indice de résistivité est de 1,7, plus faible que la valeur standard de 2. La couverture a une perméabilité de 27 nD, une porosité de 15 % et une diffusivité de 0,8 x 10-9 m2/s.

  8. Soil-biological, soil-chemical and soil-physical parameters along a pollutant gradient on grassland sites in the vicinity o Brixlegg (Tyrol) - a pilot project

    International Nuclear Information System (INIS)

    Pohla, H.; Palzenberger, M.; Krassnigg, F.; Kandeler, E.; Schwarz, S.; Kasperowski, E.

    1992-01-01

    It was the main aim of this pilot project to check the indicator value of soil organisms by means of distinct pollutant gradients - heavy metals, organic compounds (PCB, dioxins) -. On the basis of available results (1/2/3/), 4 grassland sites at increasing distances from a local emission source (copper production from scrap metal) were selected. Physical and chemical analyses as well as the quantification of habitat structures were used for the characterization of the sites. The following analyses were carried out accompanyingly: The performances of soil microorganisms under pollutant load, the accumulation of pollutants, and the structures of plants and animal communities (macro, meso and microfauna). The investigation area and the examined parameters are introduced, as well as first result on soil chemistry and enzymatics as well as for the accumulation of heavy metals in an earthworm species are introduced. (orig.) [de

  9. Geologic and well-construction data for the H-10 borehole complex near the proposed Waste Isolation Pilot Plant site, southeastern New Mexico

    International Nuclear Information System (INIS)

    Wells, J.G.; Drellack, S.L. Jr.

    1983-01-01

    The H-10 borehole complex, a group of three closely spaced boreholes, is located 4 miles southeast of the proposed Waste Isolation Pilot Plant site in west-central Lea County, New Mexico. The holes were drilled during August and October 1979 to obtain geologic and hydrologic data to better define the regional ground-water-flow system. The geologic data presented in this report are part of a site-characterization study for the possible storage of defense-associated radioactive wastes within salt beds of the Salado Formation of Permian age. The geologic data include detailed descriptions of cores, cuttings, and geophysical logs. Each borehole was designed to penetrate a distinct water-bearing zone: H-10a (total depth 1318 feet) was completed just below the Magenta Dolomite Member of the Rustler Formation of Permian age; H-10b (total depth 1398 feet) was completed just below the Culebra Dolomite Member of the Rustler Formation; and H-10c (total depth 1538 feet) was completed below the Rustler Formation-Salado Formation contact. The geologic units penetrated in borehole H-10c are surficial alluvium and eolian sand of Holocene age (0 to 5 feet); the Mescalero caliche (5 to 9 feet) and the Gatuna Formation (9 to 90 feet) of Pleistocene age: formations in the Dockum Group (Chinle Formation, 90 to 482 feet and Santa Rosa Sandstone, 482 to 658 feet) of Late Triassic age; and the Dewey Lake Red Beds (658 to 1204 feet), the Rustler Formation (1204 to 1501 feet), and part of the Salado Formation (1501 to 1538 feet), all of Permian age. The sections of the Rustler and Salado Formations penetrated by borehole H-10c are complete and contain little or no evidence of dissolution of halite and associated rocks, indicating that the eastward-moving dissolution within the Rustler or on top of the Salado, found west of the Waste Isolation Pilot Plant site, has not reached the H-10 site

  10. Supporting Regional Aged Care Nursing Staff to Manage Residents' Behavioural and Psychological Symptoms of Dementia, in Real Time, Using the Nurses' Behavioural Assistant (NBA): A Pilot Site 'End-User Attitudes' Trial.

    Science.gov (United States)

    Klein, Britt; Clinnick, Lisa; Chesler, Jessica; Stranieri, Andrew; Bignold, Adam; Dazeley, Richard; McLaren, Suzanne; Lauder, Sue; Balasubramanian, Venki

    2018-01-01

    This regional pilot site 'end-user attitudes' study explored nurses' experiences and impressions of using the Nurses' Behavioural Assistant (NBA) (a knowledge-based, interactive ehealth system) to assist them to better respond to behavioural and psychological symptoms of dementia (BPSD) and will be reported here. Focus groups were conducted, followed by a four-week pilot site 'end-user attitudes' trial of the NBA at a regional aged care residential facility (ACRF). Brief interviews were conducted with consenting nursing staff. Focus group feedback (N = 10) required only minor cosmetic changes to the NBA prototype. Post pilot site end-user interview data (N = 10) indicated that the regional ACRF nurses were positive and enthusiastic about the NBA, however several issues were also identified. Overall the results supported the utility of the NBA to promote a person centred care approach to managing BPSD. Slight modifications may be required to maximise its uptake across all ACRF nursing staff.

  11. Numerical simulation of ground-water flow in the Culebra dolomite at the Waste Isolation Pilot Plant (WIPP) site: Second interim report

    International Nuclear Information System (INIS)

    LaVenue, A.M.; Haug, A.; Kelley, V.A.

    1988-03-01

    This hydrogeologic modeling study has been performed as part of the regional hydrologic characterization of the Waste Isolation Pilot Plant (WIPP) Site in southeastern New Mexico. The study resulted in an estimation of the transmissivity distrubution, hydraulic potentials, flow field, and fluid densities in the Culebra Dolomite Member of the Permian Rustler Formation at the WIPP site. The three-dimensional finite-difference code SWIFT-II was employed for the numerical modeling, using variable-fluid-density and a single-porosity formulation. The modeled area includes and extends beyond the WIPP controlled zone (Zone 3). The work performed consisted of modeling the hydrogeology of the Culebra using two approaches: (1) steady-state modeling to develop the best estimate of the undisturbed head distribution, i.e., of the situation before sinking if the WIPP shafts, which began in 1981; and (2) superimposed transient modeling of local hydrologic responses to excavation of the three WIPP shafts at the center of the WIPP site, as well as to various well tests. Boundary conditions (prescribed constant fluid pressures and densities) were estimated using hydraulic-head and fluid-density data obtained from about 40 wells at and near the WIPP site. The transient modeling used the calculated steady-state freshwater heads as initial conditions. 107 refs., 112 figs., 22 tabs

  12. Numerical simulation of ground-water flow in the Culebra dolomite at the Waste Isolation Pilot Plant (WIPP) site: Second interim report

    Energy Technology Data Exchange (ETDEWEB)

    LaVenue, A.M.; Haug, A.; Kelley, V.A.

    1988-03-01

    This hydrogeologic modeling study has been performed as part of the regional hydrologic characterization of the Waste Isolation Pilot Plant (WIPP) Site in southeastern New Mexico. The study resulted in an estimation of the transmissivity distrubution, hydraulic potentials, flow field, and fluid densities in the Culebra Dolomite Member of the Permian Rustler Formation at the WIPP site. The three-dimensional finite-difference code SWIFT-II was employed for the numerical modeling, using variable-fluid-density and a single-porosity formulation. The modeled area includes and extends beyond the WIPP controlled zone (Zone 3). The work performed consisted of modeling the hydrogeology of the Culebra using two approaches: (1) steady-state modeling to develop the best estimate of the undisturbed head distribution, i.e., of the situation before sinking if the WIPP shafts, which began in 1981; and (2) superimposed transient modeling of local hydrologic responses to excavation of the three WIPP shafts at the center of the WIPP site, as well as to various well tests. Boundary conditions (prescribed constant fluid pressures and densities) were estimated using hydraulic-head and fluid-density data obtained from about 40 wells at and near the WIPP site. The transient modeling used the calculated steady-state freshwater heads as initial conditions. 107 refs., 112 figs., 22 tabs.

  13. Soil Fertility in relation to Landscape Position and Land Use/Cover Types: A Case Study of the Lake Kivu Pilot Learning Site

    Directory of Open Access Journals (Sweden)

    Majaliwa Mwanjalolo Jackson-Gilbert

    2015-01-01

    Full Text Available This study determined the change and distribution of land-uses/covers along the landscape, and evaluated the nutrient status of the top soil layer in the Lake Kivu Pilot Learning Site (LKPLS benchmarked micro-catchments. Soil physical and chemical properties were quantified using triplicate soil samples collected from each land-use/cover at two depths (0–15 and 15–30 cm in three LK PLS Learning Innovation Platform (IP sites (Bufundi in Uganda, Mupfuni-Shanga in D.R. Congo, Gataraga in Rwanda. Small scale agriculture has increased in all the benchmarked micro-catchments at the expense of other land-uses/covers. In the settlement areas land-use/cover distribution along the landscape varied across sites and countries; the major one being eucalyptus woodlots, wetland, and perennials and annuals crops in Bufundi; annuals and perennials crops in Mupfuni-Shanga; and annuals crops in Gataraga. Perennial crops tended to occur at the footslope and valley bottoms, while the annuals occurred at the upper backslopes and summits. Available P and K were relatively higher and C/N ratio (7.28 was the lowest in Mupfuni Shanga. Annual crops had the lowest available P and N across site (P<0.05. The key nutrients N, P and K were below the critical values for plant growth for Bufundi.

  14. Synthesis and crystal structure of a new Cu3Au-type ternary phase in the Au-In-Pd system: distribution of atoms over crystallographic positions.

    Science.gov (United States)

    Ptashkina, Evgeniya A; Kabanova, Elizaveta G; Tursina, Anna I; Yatsenko, Alexandr V; Kuznetsov, Victor N

    2018-03-01

    A new Cu 3 Au-type ternary phase (τ phase) is found in the AuPd-rich part of the Au-In-Pd system. It has a broad homogeneity range based on extensive (Pd,Au) and (In,Au) replacement, with the composition varying between Au 17.7 In 25.3 Pd 57.0 and Au 50.8 In 16.2 Pd 33.0 . The occupancies of the crystallographic positions were studied by single-crystal X-ray diffraction for three samples of different composition. The sites with m-3m symmetry are occupied by atoms with a smaller scattering power than the atoms located on 4/mmm sites. Two extreme structure models were refined. Within the first, the occupation type changes from (Au,In,Pd) 3 (Pd,In) to (Au,Pd) 3 (In,Pd,Au) with an increase in the Au gross content. For the second model, the occupation type (Au,In,Pd) 3 (Pd,Au) remains essentially unchanged for all Au concentrations. Although the diffraction data do not allow the choice of one of these models, the latter model, where Au substitutes In on 4/mmm sites, seems to be preferable, since it agrees with the fact that the homogeneity range of the τ phase is inclined to the Au corner and provides the same occupation type for all the studied samples of different compositions.

  15. Influence of bathymetry in manganese nodule pilot mine site selection: A case study from the Central Indian Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Kodagali, V.N.

    Although manganese nodules are observed in all world oceans, known reserves cannot be only criterion in future mine sites selection and sizing. Detailed and accurate depth data is another major prerequisite. With the advent of multibeam swath...

  16. Demosite - Demonstration of the integration of photovoltaic elements in buildings; DEMOSITE. Site de demonstration d'elements de construction photovoltaiques integres au batiment

    Energy Technology Data Exchange (ETDEWEB)

    Roecker, C.; Affolter, P.; Muller, A.N.; Ould-Yenia, A.

    2003-07-01

    This final report for the Swiss Federal Office of Energy summarises Phase 4 of the DEMOSITE project and concludes 10 years of DEMOSITE activities. The DEMOSITE project, started in 1992, demonstrates various ways of integrating photovoltaic elements in buildings by providing stands, pavilions and monitoring facilities at its site in Lausanne, Switzerland. Here, at the Swiss Federal Institute of Technology, roof-mounted installations can be found as well as mock-ups of buildings and roofing systems that also serve as covered parking facilities. The DEMOSITE web site and graphical presentations are also reviewed. Furthermore, the six newest pavilions are presented in detail. The report also presents several sets of data from measurements made on the installations and discusses the dissemination of information and results obtained from the project. A comprehensive annex provides illustrations of examples of building-integrated photovoltaics from around the world.

  17. The Pilot Staffing Conundrum: A Delphi Study

    Science.gov (United States)

    2009-06-01

    Project, AFIT/ GMO /LAL/98J-2. School of Logistics and Acquisition Management, Air Force Institute of Technology (AU), Wright Patterson AFB, OH, June...Kafer, John H. Relationship of Airline Pilot Demand and Air Force Pilot Retention. Graduate Research Project, AFIT/ GMO /LAL/98J-11. School of Logistics

  18. Assessment of technologies for hazardous waste site remediation: Non-treatment technologies and pilot scale facility implementation -- monitoring technology

    International Nuclear Information System (INIS)

    Johnson, H.R.; Overbey, W.K. Jr.; Molnar, D.L.

    1994-02-01

    The objective of this study was to investigate and evaluate existing proven technologies for the monitoring of hazardous waste sites during remediation activities and to protect the health and safety of all related entities while complying with government regulations. The study began with a literature search to determine manufacturers and related instrumentation which would be applicable to the most complex (in terms of toxicity and mediums affected) sites. Criteria for monitoring and analyses were established and a functional analysis was performed to select the most appropriate instrumentation available. Gas Chromatography/Mass Spectrometry is the most widely accepted method for generating quantitative data given the characterization of the Winfield site. Fourier Transform Infrared Spectroscopy, while not a new technology, has the distinct advantage of measuring simultaneously hundreds of gaseous pollutants which can also be sparged from water and this technology received the highest score as per the functional analysis. To protect workers and the public surrounding remediation sites which are known to contain VOCs, on site monitoring prior to, and during the excavation operations, is recommended until enough data are obtained to assess the health risks to workers. The conclusion of this study is to recommend evaluation of both the mobile GC/MS and FTIR systems simultaneously in identical operating conditions

  19. Maintenir la continuité des collections à l'heure d'Internet : du catalogue de vente au site web de maison de vente

    OpenAIRE

    Jacquet , Françoise

    2014-01-01

    International audience; La Bibliothèque nationale de France conserve depuis des siècles une importante collection de catalogues de vente sur support papier. Cependant avec l’apparition d’Internet on assiste à une dématérialisation des données documentaires en art. Aujourd’hui les sites des maisons de vente offrent en ligne les adjudications des ventes, récentes ou archivées et certaines ventes sont désormais annoncées uniquement sur Internet. Ces informations qui ne se trouvent pas sur les ca...

  20. Compilation and comparison of test-hole location surveys in the vicinity of the Waste Isolation Pilot Plant site

    International Nuclear Information System (INIS)

    Gonzales, M.M.

    1989-02-01

    Between 1976 and 1988, many surveys were performed related to the Waste Isolation Pilot Plant and its geologic and hydrologic test holes, which are part of the hydrogeologic-characterization program. Among these surveys were two First-Order, Class I vertical surveys, a satellite survey, and a number of township-range surveys. An overview of the basic function, history, and methodology of each survey type is provided in this report along with a review and comparison of the two major test-hole surveys. Elevation and location data for 96 test holes and 4 shafts are also included. The comparison of the satellite survey to the township-range surveys showed that the latter have the following advantages: their data are more complete; their elevation data are more accurate; and their techniques can be used for surveying new wells, keeping the data set consistent. Therefore, the final township-range surveys were selected as the best source of elevation and location data to use in the WIPP hydrology program. 17 refs., 5 figs., 10 tabs

  1. Geologic and well-construction data for the H-8 borehole complex near the proposed Waste Isolation Pilot Plant site, southeastern New Mexico

    Science.gov (United States)

    Wells, J.G.; Drellack, S.L.

    1982-01-01

    The H-8 complex, a group of three closely-spaced boreholes, is located 9 miles south of the proposed Waste Isolation Pilot Plant site in southeastern Eddy County, New Mexico. The holes were drilled during July, August, and September of 1979 to obtain geologic and hydrologic data to better define the regional ground-water-flow system. The geologic data presented in this report are part of a site-characterization study for the possible disposal of defense-associated radioactive wastes within salt beds of the Salado Formation of Permian age. The geologic data include detailed descriptions of cores, cuttings, and geophysical logs. Each borehole was designed to penetrate a distinct water-bearing zone: H-8a (total depth 505 feet) was completed just below the Magenta Dolomite Member of the Rustler Formation of Permian Age; H-8b (total depth 624 feet) was completed just belows the Culebra Dolomite Member of the Rustler Formation; and H-8c (total depth 808 feet) was completed just below the Rustler Formation-Salado Formation contact. The geologic units penetrated in borehole H-8c are surficial alluvium and eolian sand of Holocene age (0-4 feet); the Mescalero caliche (4-10 feet) and Gatuna Formation (10-153 feet) , both of Pleistocene age; and the Dewey Lake Red Beds (153-399 feet), the Rustler Formation (399-733 feet), and part of the Salado Formation penetrated by borehole H-8c is composed of residue from dissolution of halite and associated rocks, and the hydration of anhydrite to gypsum, indicating that the eastward-moving dissolution front on top of the Salado, found just to the west of the WIPP site, has reached the H-8 site. (USGS)

  2. Geologic and well-construction data for the H-9 borehole complex near the proposed Waste Isolation Pilot Plant site, southeastern New Mexico

    Science.gov (United States)

    Drellack, S.L.; Wells, J.G.

    1982-01-01

    The H-9 complex, a group of three closely spaced boreholes, is located 5.5 miles south of the proposed Waste Isolation Pilot Plant (WIPP) site in east-central Eddy County, New Mexico. The holes were drilled during July, August, and September 1979 to obtain geologic and hydrologic data to better define the regional ground-water-flow system. The geologic data presented in this report are part of a site-characterization study for the possible storage of defense-associated radioactive wastes within salt beds of the Salado Formation of Permian age. The geologic data include detailed descriptions of cores, cuttings, and geophysical logs. Each borehole was designed to penetrate a distinct water-bearing zone: H-9a (total depth 559 feet) was completed just below the Magenta Dolomite Member of the Rustler Formation; H-9b (total depth 708 feet) was completed just below the Culebra Dolomite Member of the Rustler Formation; H-9c (total depth 816 feet) was completed below the Rustler Formation-Salado Formation contact. The geologic units penetrated in borehole H-9c are eolian sand of Holocene age (0-5 feet); the Gatuna Formation of Pleistocene age; (5-25 feet); and the Dewey Lake Red Beds (25-455 feet), the Rustler Formation (455.791 feet), and part of the Salado Formation (791-816 feet), all of Permian age. Three sections (494-501 feet, 615-625 feet, 692-712 feet) in the Rustler Formation penetrated by borehole H-9c are composed of remnant anhydrite (locally altered to gypsum) and clay and silt residue from the dissolution of much thicker seams of argillaceous and silty halite. This indicates that the eastward-moving dissolution within the Rustler Formation, found just to the west of the WIPP site, is present at the H-9 site. (USGS)

  3. Geologic and well-construction data for the H-10 borehole complex near the proposed Waste Isolation Pilot Plant site, southeastern New Mexico

    Science.gov (United States)

    Wells, J.G.; Drellack, S.L.

    1983-01-01

    The H-10 borehole complex, a group of three closely spaced boreholes, is located 3 1/2 miles southeast of the proposed Waste Isolation Pilot Plant site in west-central Lea County, New Mexico. The geological data presented in this report are part of a site-characterization study for the possible storage of defense-associated radioactive wastes within salt beds of the Salado Formation of Permian age. Each borehole was designated to penetrate a distinct water-bearing zone: H-10a (total depth 1 ,318 feet) was completed just below the Magenta Dolomite Member of the Rustler Formation of Permian age; H-10b (total depth 1 ,398 feet) was completed just below the Culebra Dolomite Member of the Rustler Formation; and H-10c (total depth 1,538 feet) was completed below the Rustler Formation-Salado Formation contact. The geologic units penetrated in borehole H-10c are surficial alluvium and eolian sand of Holocene age (0-5 feet); the Mescalero caliche (5-9 feet) and the Gatuna Formation (9-90 feet) of Pleistocene age; formation in the Dockum Group (Chinle Formation, 90-482 feet and Santa Rosa Sandstone, 482-658 feet) of Late Triassic age; and the Dewey Lake Red Beds (658-1,204 feet), the Rustler Formation (1,204-1,501 feet), and part of the Salado Formation (1,501-1,538 feet), all of Permian age. The sections of the Rustler and Salado Formations penetrated by borehole H-10c are complete and contain little or no evidence of dissolution of halite and associated rocks, indicating that the eastward-moving dissolution on top of the Salado, found just to the west of the WIPP site, has not reached the H-10 site. (USGS)

  4. Application of open-path Fourier transform infrared spectroscopy for atmospheric monitoring of a CO2 back-production experiment at the Ketzin pilot site (Germany).

    Science.gov (United States)

    Sauer, Uta; Borsdorf, H; Dietrich, P; Liebscher, A; Möller, I; Martens, S; Möller, F; Schlömer, S; Schütze, C

    2018-02-03

    During a controlled "back-production experiment" in October 2014 at the Ketzin pilot site, formerly injected CO 2 was retrieved from the storage formation and directly released to the atmosphere via a vent-off stack. Open-path Fourier transform infrared (OP FTIR) spectrometers, on-site meteorological parameter acquisition systems, and distributed CO 2 point sensors monitored gas dispersion processes in the near-surface part of the atmospheric boundary layer. The test site provides a complex and challenging mosaic-like surface setting for atmospheric monitoring which can also be found at other storage sites. The main aims of the atmospheric monitoring of this experiment were (1) to quantify temporal and spatial variations in atmospheric CO 2 concentrations around the emitting vent-off stack and (2) to test if and how atmospheric monitoring can cope with typical environmental and operational challenges. A low environmental risk was encountered during the whole CO 2 back-production experiment. The study confirms that turbulent wind conditions favor atmospheric mixing processes and are responsible for rapid dilution of the released CO 2 leading to decreased detectability at all sensors. In contrast, calm and extremely stable wind conditions (especially occurring during the night) caused an accumulation of gases in the near-ground atmospheric layer with the highest amplitudes in measured gas concentration. As an important benefit of OP FTIR spectroscopic measurements and their ability to detect multiple gas species simultaneously, emission sources could be identified to a much higher certainty. Moreover, even simulation models using simplified assumptions help to find suitable monitoring network designs and support data analysis for certain wind conditions in such a complex environment.

  5. The temporal course of mucoperiosteal flap revascularization at guided bone regeneration treated implant sites: a pilot study

    NARCIS (Netherlands)

    Milstein, D.M.J.; Mathura, K.R.; Lindeboom, J.A.H.; Ramsoekh, D.; Lindeboom, R.; Ince, C.

    2009-01-01

    Aims: To investigate post-operative capillary density regeneration in healing mucoperiosteal flaps at guided bone regeneration-treated implant sites. Material and Methods: A non-invasive post-operative investigation was performed in 10 patients using orthogonal polarization spectral (OPS) imaging

  6. The temporal course of mucoperiosteal flap revascularization at guided bone regeneration-treated implant sites: a pilot study

    NARCIS (Netherlands)

    Milstein, Dan M. J.; Mathura, Keshen R.; Lindeboom, Jerôme A. H.; Ramsoekh, Dewkoemar; Lindeboom, Robert; Ince, Can

    2009-01-01

    P>Aims To investigate post-operative capillary density regeneration in healing mucoperiosteal flaps at guided bone regeneration-treated implant sites. Material and Methods A non-invasive post-operative investigation was performed in 10 patients using orthogonal polarization spectral (OPS) imaging

  7. Recommandations essentielles de sécurité relatives au travail du personnel des laboratoires géologiques de chantier Essential Safety Recommendations Concerning Work by Personnel in Well Site Mud Logging Units

    Directory of Open Access Journals (Sweden)

    Chambre Syndicale du Pétrole

    2006-11-01

    Full Text Available Le personnel travaillant dans les cabines géologiques sur chantiers de forage doit respecter des règles de sécurité pour la prévention des accidents et doit connaître nécessairement les consignes à suivre en cas de danger. Ces recommandations sont relatives à l'installation des cabines géologiques et aux problèmes créés par leur équipement très diversifié, comprenant notamment de nombreux capteurs dispersés sur le chantier et leur réseau de câbles de liaison. Huit annexes rappellent les risques inhérents à la présence d'hydrogène sulfuré et les conditions d'utilisation des appareils de protection, les problèmes liés aux fours à micro-ondes éventuellement installés, ceux liés à la présence de sources radioactives. Une large part de ces recommandations est consacrée au stockage, à la manipulation et à l'élimination des produits chimiques couramment présents dans les cabines. Dix-neuf fiches de prévention simplifiées rappellent les risques que ces produits chimiques font courir au personnel et précisent les premiers soins à appliquer. Les deux dernières annexes traitent de la définition des zones classées pour les forages à terre et les forages en mer. The personnel working in mud logging units at well sites must respect safety rules for the prevention of accidents and must know the instructions to be followed in case of danger. These recommendations concern the installation of logging units and the problems created by the highly diversified equipment in such units, including in particular numerous sensors scattered around the site and the network of cables linking the sensors to the unit. Eight appendixes review the risks inherent in the presence of hydrogen sulfide and the conditions for using protective equipment, the problems linked to any microwave ovens that may be installed, and the problems linked to the presence of radioactive sources. A large portion of these recommen-dations is devoted to

  8. CERN pilot greenhouse

    CERN Multimedia

    1983-01-01

    This pilot installation was situated near Bld. BA6 opposite to the main entrance of the Meyrin site, with respect to Route de Meyrin. See Weekly Bulletin 3/83, and also photo 8305594X, 8505898X, 8302200.

  9. Distribution of Trauma Care Facilities in Oman in Relation to High-Incidence Road Traffic Injury Sites: Pilot study.

    Science.gov (United States)

    Al-Kindi, Sara M; Naiem, Ahmed A; Taqi, Kadhim M; Al-Gheiti, Najla M; Al-Toobi, Ikhtiyar S; Al-Busaidi, Nasra Q; Al-Harthy, Ahmed Z; Taqi, Alaa M; Ba-Alawi, Sharif A; Al-Qadhi, Hani A

    2017-11-01

    Road traffic injuries (RTIs) are considered a major public health problem worldwide. In Oman, high numbers of RTIs and RTI-related deaths are frequently registered. This study aimed to evaluate the distribution of trauma care facilities in Oman with regards to their proximity to RTI-prevalent areas. This descriptive pilot study analysed RTI data recorded in the national Royal Oman Police registry from January to December 2014. The distribution of trauma care facilities was analysed by calculating distances between areas of peak RTI incidence and the closest trauma centre using Google Earth and Google Maps software (Google Inc., Googleplex, Mountain View, California, USA). A total of 32 trauma care facilities were identified. Four facilities (12.5%) were categorised as class V trauma centres. Of the facilities in Muscat, 42.9% were ranked as class IV or V. There were no class IV or V facilities in Musandam, Al-Wusta or Al-Buraimi. General surgery, orthopaedic surgery and neurosurgery services were available in 68.8%, 59.3% and 12.5% of the centres, respectively. Emergency services were available in 75.0% of the facilities. Intensive care units were available in 11 facilities, with four located in Muscat. The mean distance between a RTI hotspot and the nearest trauma care facility was 34.7 km; however, the mean distance to the nearest class IV or V facility was 83.3 km. The distribution and quality of trauma care facilities in Oman needs modification. It is recommended that certain centres upgrade their levels of trauma care in order to reduce RTI-associated morbidity and mortality in Oman.

  10. Ultra-relativistic Au+Au and d+Au collisions:

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Chai, Z.; Decowski, M. P.; García, E.; Gburek, T.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Hauer, M.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Seals, H.; Sedykh, I.; Skulski, W.; Smith, C. E.; Stankiewicz, M. A.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tang, J.-L.; Tonjes, M. B.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Vaurynovich, S. S.; Verdier, R.; Veres, G. I.; Wenger, E.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    In this talk I will review PHOBOS data on charged particle multiplicities, obtained in Au+Au and d+Au collisions at RHIC. The general features of the Au+Au pseudorapidity distributions results will be discussed and compared to those of /line{p}p collisions. The total charged particle multiplicity, scaled by the number of participant pairs, is observed to be about 40% higher in Au+Au collisions than in /line{p}p and d+Au systems, but, surprisingly at the same level of e+e- collisions. Limiting fragmentation scaling is seen to be obeyed in Au+Au collisions.

  11. A pilot study on health risk assessment based on body loadings of PCBs of lactating mothers at Taizhou, China, the world's major site for recycling transformers.

    Science.gov (United States)

    Man, Yu Bon; Chow, Ka Lai; Xing, Guan Hua; Chan, Janet Kit Yan; Wu, Sheng Chun; Wong, Ming Hung

    2017-08-01

    Our early study reported an extraordinarily high Estimated Daily Intake (EDI) of PCBs of lactating mothers from Taizhou, Zhejiang Province, China (based on a food consumption survey and food basket analysis). The EDI well exceeded the intake limit stipulated by FAO/WHO 70 pg TEQ/kg body weight (bw)/month. The present pilot study provided further information on PCBs body burden in lactating mothers of Taizhou. The total PCBs detected in human milk, placenta and hair samples of these lactating mothers were 363 ng/g lipid, 224 ng/g lipid, and 386 ng/g dry wt. Respectively, three times higher than those samples collected from the reference site (Lin'an). Compared with the previous reported values in the 3rd WHO coordinated study, Taizhou topped the list of 32 countries/regions with regards to WHO-PCB-TEQ values of milk samples, which could be attributed to the relatively higher level of PCB-126 derived from electronic waste. In addition, the corresponding EDI of PCBs of Taizhou mothers (12.9 pg WHO-PCB-TEQ/kg bw/day) and infants (438 pg WHO-PCB-TEQ/kg) were derived from individual congener levels in human milk. The results were also higher than the tolerable daily intakes recommended by WHO (1-4 pg WHO-TEQ/kg bw/day) by 3 and 110 times, for mothers and infants, respectively. A more intensive epidemiological study on the potential health effects of e-waste recycling activities affecting both workers and residents seems to be of top priority, based on findings of this pilot study. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. In situ pilot test for bioremediation of energetic compound-contaminated soil at a former military demolition range site.

    Science.gov (United States)

    Jugnia, Louis B; Manno, Dominic; Drouin, Karine; Hendry, Meghan

    2018-05-04

    Bioremediation was performed in situ at a former military range site to assess the performance of native bacteria in degrading hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) and 2,4-dinitrotoluene (2,4-DNT). The fate of these pollutants in soil and soil pore water was investigated as influenced by waste glycerol amendment to the soil. Following waste glycerol application, there was an accumulation of organic carbon that promoted microbial activity, converting organic carbon into acetate and propionate, which are intermediate compounds in anaerobic processes. This augmentation of anaerobic activity strongly correlated to a noticeable reduction in RDX concentrations in the amended soil. Changes in concentrations of RDX in pore water were similar to those observed in the soil suggesting that RDX leaching from the soil matrix, and treatment with waste glycerol, contributed to the enhanced removal of RDX from the water and soil. This was not the case with 2,4-DNT, which was neither found in pore water nor affected by the waste glycerol treatment. Results from saturated conditions and Synthetic Precipitation Leaching Procedure testing, to investigate the environmental fate of 2,4-DNT, indicated that 2,4-DNT found on site was relatively inert and was likely to remain in its current state on the site.

  13. Decision support for the definition of wind turbine systems adequacy to site specificities and weak electrical networks; Aide a la decision pour la definition d'un systeme eolien, adequation au site et a un reseau faible

    Energy Technology Data Exchange (ETDEWEB)

    Arbaoui, A

    2006-10-15

    A decision support system for the definition of wind turbine systems is developed by taking into account the wind and site characteristics, the wind turbine components and the electrical network properties close to the site. The approach is based on functional analysis, on the investigation of the functional fluxes and on the definition of a model suitable for supporting decision at the preliminary stages of wind turbine design. The complete set of solutions derived from the model is determined using a Constraint Satisfaction Problem solver. The intrinsic capability of the model to support decision is derived from the investigation of the model parsimony, precision, exactness and specialization. The model takes into account performance criteria resulting from knowledge of manufacturers, distributors and investors. These criteria are used to discriminate design alternatives. Design alternatives correspond to choices of site (wind, electric network) and wind turbine architectures (related to 7 design variables). Performance criteria are the cost of electric kWh, the amount of energy being produced and the discounted total cost of the project. Electric network connection to wind turbines is taken into account through slow variations of the voltage and Flickers phenomenon. First, the maximal rate of penetration of the wind turbine energy production is determined. Next, two design alternatives have been investigated to improve wind turbine system integration in electric distribution networks. These alternatives are a reactive power control system and an inertial energy storage system. Inertial storage systems seem to be more expensive than reactive power control systems for this type of application. The influence of site specificities on decision making process has been established through three different sites (a Mediterranean site and two sites located in northern Europe). Profits relative to the cost of kWh appear to be high for Mediterranean sites. Most of the

  14. Decision support for the definition of wind turbine systems adequacy to site specificities and weak electrical networks; Aide a la decision pour la definition d'un systeme eolien, adequation au site et a un reseau faible

    Energy Technology Data Exchange (ETDEWEB)

    Arbaoui, A

    2006-10-15

    A decision support system for the definition of wind turbine systems is developed by taking into account the wind and site characteristics, the wind turbine components and the electrical network properties close to the site. The approach is based on functional analysis, on the investigation of the functional fluxes and on the definition of a model suitable for supporting decision at the preliminary stages of wind turbine design. The complete set of solutions derived from the model is determined using a Constraint Satisfaction Problem solver. The intrinsic capability of the model to support decision is derived from the investigation of the model parsimony, precision, exactness and specialization. The model takes into account performance criteria resulting from knowledge of manufacturers, distributors and investors. These criteria are used to discriminate design alternatives. Design alternatives correspond to choices of site (wind, electric network) and wind turbine architectures (related to 7 design variables). Performance criteria are the cost of electric kWh, the amount of energy being produced and the discounted total cost of the project. Electric network connection to wind turbines is taken into account through slow variations of the voltage and Flickers phenomenon. First, the maximal rate of penetration of the wind turbine energy production is determined. Next, two design alternatives have been investigated to improve wind turbine system integration in electric distribution networks. These alternatives are a reactive power control system and an inertial energy storage system. Inertial storage systems seem to be more expensive than reactive power control systems for this type of application. The influence of site specificities on decision making process has been established through three different sites (a Mediterranean site and two sites located in northern Europe). Profits relative to the cost of kWh appear to be high for Mediterranean sites. Most of the

  15. Rustler Formation in the waste handling and exhaust shafts, Waste Isolation Pilot Plant (WIPP) site, southeastern New Mexico

    International Nuclear Information System (INIS)

    Holt, R.M.; Powers, D.W.

    1987-01-01

    The Permian Rustler Formation was recently examined in detail in two shafts at the WIPP site: the waste handling shaft (waste shaft) and the exhaust shaft. Fresh exposures of the Rustler in the shafts exhibited abundant primary sedimentary structures. The abundance of primary sedimentary structures observed in the shafts is unequaled in previously described sections. Data are reported here in their stratigraphic context as an initial basis for evaluation of depositional environments of the Rustler and reevaluating the role of dissolution in the formation of the Rustler. 10 refs

  16. Well-based stable carbon isotope leakage monitoring of an aquifer overlying the CO2 storage reservoir at the Ketzin pilot site, Germany

    Science.gov (United States)

    Nowak, Martin; Myrttinen, Anssi; Zimmer, Martin; van Geldern, Robert; Barth, Johannes A. C.

    2014-05-01

    At the pilot site for CO2 storage in Ketzin, a new well-based leakage-monitoring concept was established, comprising geochemical and hydraulic observations of the aquifer directly above the CO2 reservoir (Wiese et al., 2013, Nowak et al. 2013). Its purpose was to allow early detection of un-trapped CO2. Within this monitoring concept, we established a stable carbon isotope monitoring of dissolved inorganic carbon (DIC). If baseline isotope values of aquifer DIC (δ13CDIC) and reservoir CO2 (δ13CCO2) are known and distinct from each other, the δ13CDIC has the potential to serve as an an early indicator for an impact of leaked CO2 on the aquifer brine. The observation well of the overlying aquifer was equipped with an U-tube sampling system that allowed sampling of unaltered brine. The high alkaline drilling mud that was used during well drilling masked δ13CDIC values at the beginning of the monitoring campaign. However, subsequent monitoring allowed observing on-going re-equilibration of the brine, indicated by changing δ13CDIC and other geochemical values, until values ranging around -23 ‰ were reached. The latter were close to baseline values before drilling. Baselineδ13CDIC and δ13CCO2 values were used to derive a geochemical and isotope model that predicts evolution of δ13CDIC, if CO2 from the reservoir would leak into the aquifer. The model shows that equilibrium isotope fractionation would have to be considered if CO2 dissolves in the brine. The model suggests that stable carbon isotope monitoring is a suitable tool to assess the impact of injected CO2 in overlying groundwater aquifers. However, more data are required to close gaps of knowledge about fractionation behaviour within the CO2(g) - DIC system under elevated pressures and temperatures. Nowak, M., Myrttinen, A., Zimmer, M., Wiese, B., van Geldern, R., Barth, J.A.C., 2013. Well-based, Geochemical Leakage Monitoring of an Aquifer Immediately Above a CO2 Storage Reservoir by Stable Carbon

  17. Characterization of Sediments from the Soil Desiccation Pilot Test (SDPT) Site in the BC Cribs and Trenches Area

    Energy Technology Data Exchange (ETDEWEB)

    Um, Wooyong; Truex, Michael J.; Valenta, Michelle M.; Iovin, Cristian; Kutnyakov, Igor V.; Chang, Hyun-shik; Clayton, Ray E.; Serne, R. Jeffrey; Ward, Anderson L.; Brown, Christopher F.; Geiszler, Keith N.; Clayton, Eric T.; Baum, Steven R.; Smith, David M.

    2009-09-25

    This technical report documents the results of laboratory geochemical and hydrologic measurements of sediments collected from new borehole 299-E13-65 (C7047) and comparison of the results with those of nearby borehole 299-13E-62 (C5923) both drilled in the BC Cribs and Trenches Area. The total and water-leachable concentrations of key contaminants will be used to update contaminant-distribution conceptual models and to provide more data for improving baseline risk predictions and remedial alternative selections. Improved understanding of subsurface conditions and methods to remediate these principal contaminants can be also used to evaluate the application of specific technologies to other contaminants across the Hanford Site.

  18. WIPP: Waste Isolation Pilot Plant

    International Nuclear Information System (INIS)

    1984-01-01

    The following aspects of the Waste Isolation Pilot Plant are discussed briefly: history and site selection; salt as a disposal medium; transporting waste materials; early key events; impacts on New Mexico; project organization; and site certification profile

  19. Mise au point

    African Journals Online (AJOL)

    31 mai 2013 ... traités au service de chirurgie maxillo-faciale et chirurgie plastique de l'hôpital ... qui est la fracture simple isolée du corps, on a inclut ce type de fracture ... sion latérale au niveau de la queue du sourcil. La voie vestibulaire ...

  20. Transport characteristics in Au/pentacene/Au diodes

    Science.gov (United States)

    Hayashi, Toshiaki; Naka, Akiyoshi; Hiroki, Masanobu; Yokota, Tomoyuki; Someya, Takao; Fujiwara, Akira

    2018-03-01

    We have used scanning and transmission electron microscopes (SEM and TEM) to study the structure of a pentacene thin film grown on a Au layer with and shown that it consists of randomly oriented amorphous pentacene clusters. We have also investigated the transport properties of amorphous pentacene in a metal-semiconductor-metal (MSM) diode structure and shown that the current is logarithmically proportional to the square root of the applied voltage, which indicates that transport occurs as the result of hopping between localized sites randomly distributed in space and energy.

  1. Au pair trajectories

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2015-01-01

    pair-sending families in the Philippines, this dissertation examines the long-term trajectories of these young Filipinas. It shows how the au pairs’ local and transnational family relations develop over time and greatly influence their life trajectories. A focal point of the study is how au pairs...... that Filipina au pairs see their stay abroad as an avenue of personal development and social recognition, I examine how the au pairs re-position themselves within their families at home through migration, and how they navigate between the often conflicting expectations of participation in the sociality......Since 2000, thousands of young Filipino migrants have come to Denmark as au pairs. Officially, they are there to “broaden their cultural horizons” by living temporarily with a Danish host family, but they also conduct domestic labor in exchange for food and money, which allows them to send...

  2. Pilot-Scale Test Results Of A Thin Film Evaporator System For Management Of Liquid High-Level Wastes At The Hanford Site Washington USA -11364

    International Nuclear Information System (INIS)

    Corbett, J.E.; Tedesch, A.R.; Wilson, R.A.; Beck, T.H.; Larkin, J.

    2011-01-01

    A modular, transportable evaporator system, using thin film evaporative technology, is planned for deployment at the Hanford radioactive waste storage tank complex. This technology, herein referred to as a wiped film evaporator (WFE), will be located at grade level above an underground storage tank to receive pumped liquids, concentrate the liquid stream from 1.1 specific gravity to approximately 1.4 and then return the concentrated solution back into the tank. Water is removed by evaporation at an internal heated drum surface exposed to high vacuum. The condensed water stream will be shipped to the site effluent treatment facility for final disposal. This operation provides significant risk mitigation to failure of the aging 242-A Evaporator facility; the only operating evaporative system at Hanford maximizing waste storage. This technology is being implemented through a development and deployment project by the tank farm operating contractor, Washington River Protection Solutions (WRPS), for the Office of River Protection/Department of Energy (ORPIDOE), through Columbia Energy and Environmental Services, Inc. (Columbia Energy). The project will finalize technology maturity and install a system at one of the double-shell tank farms. This paper summarizes results of a pilot-scale test program conducted during calendar year 2010 as part of the ongoing technology maturation development scope for the WFE.

  3. Process performance of the pilot-scale in situ vitrification of a simulated waste disposal site at the Oak Ridge National Laboratory

    International Nuclear Information System (INIS)

    Carter, J.G.; Koegler, S.S.; Bates, S.O.

    1988-06-01

    Process feasibility studies have been successfully performed on three developmental scales to determine the potential for applying in situ vitrification to intermediate-level (low-level) waste placed in seepage pits and trenches at Oak Ridge National Laboratory (ORNL). In the laboratory, testing was performed in crucibles containing a mixture of 50% ORNL soil and 50% limestone. In an engineering-scale test at Pacific Northwest Laboratory a /1/12/-scale simulation of an ORNL waste trench was constructed and vitrified, resulting in a waste product containing soil and limestone concentrations of 68 wt % and 32 wt %, respectively. In the pilot-scale test a /3/8/-scale simulation of the same trench was constructed and vitrified at ORNL, resulting in soil and limestone concentrations of 80% and 20%, respectively, in the waste product. Results of the three scales of testing indicate that the ORNL intermediate-level (low-level) waste sites can be successfully processed by in situ vitrification; the waste form will retain significant quantities of the cesium and strontium. Because cesium-137 and strontium-90 are the major components of the radionuclide inventory in the ORNL seepage pits and trenches, final field process decontamination factors (i.e., losses to the off-gas system relative to the waste inventory) of 1.0 E + 4 are desired to minimize activity buildup in the off-gas system. 17 refs., 34 figs., 13 tabs

  4. Self-collected cervicovaginal sampling for site-of-care primary HPV-based cervical cancer screening: a pilot study in a rural underserved Greek population.

    Science.gov (United States)

    Chatzistamatiou, Kimon; Chatzaki, Εkaterini; Constantinidis, Τheocharis; Nena, Evangelia; Tsertanidou, Athena; Agorastos, Theodoros

    2017-11-01

    In the present pilot study, the feasibility of a site-of-care cervicovaginal self-sampling methodology for HPV-based screening was tested in 346 women residing in underserved rural areas of Northern Greece. These women provided self-collected cervicovaginal sample along with a study questionnaire. Following molecular testing, using the cobas ® HPV Test, Roche ® , HPV positive women, were referred to colposcopy and upon abnormal findings, to biopsy and treatment. Participation rate was 100%. Regular pap-test examination was reported for 17.1%. Among hrHPV testing, 11.9% were positive and colposcopy/biopsy revealed 2 CIN3 cases. Non-compliance was the most prevalent reason for no previous attendance. Most women reported non-difficulty and non-discomfort in self-sampling (77.6% and 82.4%, respectively). They would choose self-sampling over clinician-sampling (86.2%), and should self-sampling being available, they would test themselves more regularly (92.3%). In conclusion, self-sampling is feasible and well-accepted for HPV-based screening, and could increase population coverage in underserved areas, helping towards successful prevention.

  5. PILOT-SCALE TEST RESULTS OF A THIN FILM EVAPORATOR SYSTEM FOR MANAGEMENT OF LIQUID HIGH-LEVEL WASTES AT THE HANFORD SITE WASHINGTON USA -11364

    Energy Technology Data Exchange (ETDEWEB)

    CORBETT JE; TEDESCH AR; WILSON RA; BECK TH; LARKIN J

    2011-02-14

    A modular, transportable evaporator system, using thin film evaporative technology, is planned for deployment at the Hanford radioactive waste storage tank complex. This technology, herein referred to as a wiped film evaporator (WFE), will be located at grade level above an underground storage tank to receive pumped liquids, concentrate the liquid stream from 1.1 specific gravity to approximately 1.4 and then return the concentrated solution back into the tank. Water is removed by evaporation at an internal heated drum surface exposed to high vacuum. The condensed water stream will be shipped to the site effluent treatment facility for final disposal. This operation provides significant risk mitigation to failure of the aging 242-A Evaporator facility; the only operating evaporative system at Hanford maximizing waste storage. This technology is being implemented through a development and deployment project by the tank farm operating contractor, Washington River Protection Solutions (WRPS), for the Office of River Protection/Department of Energy (ORPIDOE), through Columbia Energy and Environmental Services, Inc. (Columbia Energy). The project will finalize technology maturity and install a system at one of the double-shell tank farms. This paper summarizes results of a pilot-scale test program conducted during calendar year 2010 as part of the ongoing technology maturation development scope for the WFE.

  6. A comparison of geostatistically based inverse techniques for use in performance assessment analysis at the Waste Isolation Pilot Plant Site: Results from Test Case No. 1

    International Nuclear Information System (INIS)

    Zimmerman, D.A.; Gallegos, D.P.

    1993-10-01

    The groundwater flow pathway in the Culebra Dolomite aquifer at the Waste Isolation Pilot Plant (WIPP) has been identified as a potentially important pathway for radionuclide migration to the accessible environment. Consequently, uncertainties in the models used to describe flow and transport in the Culebra need to be addressed. A ''Geostatistics Test Problem'' is being developed to evaluate a number of inverse techniques that may be used for flow calculations in the WIPP performance assessment (PA). The Test Problem is actually a series of test cases, each being developed as a highly complex synthetic data set; the intent is for the ensemble of these data sets to span the range of possible conceptual models of groundwater flow at the WIPP site. The Test Problem analysis approach is to use a comparison of the probabilistic groundwater travel time (GWTT) estimates produced by each technique as the basis for the evaluation. Participants are given observations of head and transmissivity (possibly including measurement error) or other information such as drawdowns from pumping wells, and are asked to develop stochastic models of groundwater flow for the synthetic system. Cumulative distribution functions (CDFs) of groundwater flow (computed via particle tracking) are constructed using the head and transmissivity data generated through the application of each technique; one semi-analytical method generates the CDFs of groundwater flow directly. This paper describes the results from Test Case No. 1

  7. Detection of Turner syndrome using X-chromosome inactivation specific differentially methylated CpG sites: A pilot study.

    Science.gov (United States)

    Zhang, Qiang; Guo, Xiaohong; Tian, Tian; Wang, Teng; Li, Qiaoli; Wang, Lei; Liu, Yun; Xing, Qinghe; He, Lin; Zhao, Xinzhi

    2017-05-01

    Early diagnosis of Turner syndrome (TS) may improve preventive measures and treatment. X-chromosome inactivation specific differentially methylated CpG sites (XIDMSs) that are high methylated in inactive X chromosomes (Xi) and unmethylated in active X chromosomes (Xa) may be potential makers for TS detection. The candidate XIDMSs were screened from 9 male and 12 female DNA samples with normal karyotypes using the Illumina 450k array and validated by bisulfite sequencing PCR and pyrosequencing assay. X chromosome dosage was calculated according to the methylation level of multiple XIDMSs. Overall, 108 candidate XIDMSs were screened by the 450k array. Validations indicated that XIDMSs gathered and formed the X-chromosome inactivation specific differentially methylated regions (XIDMRs). Using 3 XIDMRs at SAT1, UXT and UTP14A loci, 36 TS, 22 normal female and 6 male samples were analyzed. Methylation levels of the 20 XIDMSs in the XIDMRs could distinguish between TS and normal female DNA samples, the X chromosome dosage was consistent with karyotyping data. Analyzing samples of 2 triple X syndrome and 3 Klinefelter syndrome patients suggested that this method could be used to detect X chromosome aneuploids other than TS. XIDMSs are widely spread along the X chromosome and might be effective markers for detection of TS and other X chromosome aneuploids. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Geochemical study of evaporite and clay mineral-oxyhydroxide samples from the Waste Isolation Pilot Plant site

    International Nuclear Information System (INIS)

    Brookins, D.G.

    1993-06-01

    Samples of clay minerals, insoluble oxyhydroxides, and their host evaporites from the WIPP site have been studied for their major and minor elements abundances, x-ray diffraction characteristics, K-Ar ages, and Rb-Sr ages. This study was undertaken to determine their overall geochemical characteristics and to investigate possible interactions between evaporates and insoluble constituents. The evaporite host material is water-soluble, having Cl/Br ratios typical of marine evaporites, although the Br content is low. Insoluble material (usually a mixture of clay minerals and oxyhydroxide phases) yields very high Cl/Br ratios, possibly because of Cl from admixed halide minerals. This same material yields K/Rb and Th/U ratios in the normal range for shales; suggesting little, if any, effect of evaporite-induced remobilization of U, K, or Rb in the insoluble material. The rare-earth element (REE) data also show normal REE/chondrite (REE/CHON) distribution patterns, supporting the K/Rb and Th/U data. Clay minerals yield K-Ar dates in the range 365 to 390 Ma and a Rb-Sr isochron age of 428 ± 7 Ma. These ages are well in excess of the 220- to 230-Ma formational age of the evaporites, and confirm the detrital origin of the clays. The ages also show that any evaporite or clay mineral reactions that might have occurred at or near the time of sedimentation and diagenesis were not sufficient to reset the K-Ar and Rb-Sr systematics of the clay minerals. Further, x-ray data indicate a normal evaporitic assemblage of clay minerals and Fe-rich oxyhydroxide phases. The clay minerals and other insoluble material appear to be resistant to the destructive effects of their entrapment in the evaporites, which suggests that these insoluble materials would be good getters for any radionuclides (hypothetically) released from the storage of radioactive wastes in the area

  9. Repetitive transcranial magnetic stimulation in cervical dystonia: effect of site and repetition in a randomized pilot trial.

    Directory of Open Access Journals (Sweden)

    Sarah Pirio Richardson

    Full Text Available Dystonia is characterized by abnormal posturing due to sustained muscle contraction, which leads to pain and significant disability. New therapeutic targets are needed in this disorder. The objective of this randomized, sham-controlled, blinded exploratory study is to identify a specific motor system target for non-invasive neuromodulation and to evaluate this target in terms of safety and tolerability in the cervical dystonia (CD population. Eight CD subjects were given 15-minute sessions of low-frequency (0.2 Hz repetitive transcranial magnetic stimulation (rTMS over the primary motor cortex (MC, dorsal premotor cortex (dPM, supplementary motor area (SMA, anterior cingulate cortex (ACC and a sham condition with each session separated by at least two days. The Toronto Western Spasmodic Torticollis Rating Scale (TWSTRS score was rated in a blinded fashion immediately pre- and post-intervention. Secondary outcomes included physiology and tolerability ratings. The mean change in TWSTRS severity score by site was 0.25 ± 1.7 (ACC, -2.9 ± 3.4 (dPM, -3.0 ± 4.8 (MC, -0.5 ± 1.1 (SHAM, and -1.5 ± 3.2 (SMA with negative numbers indicating improvement in symptom control. TWSTRS scores decreased from Session 1 (15.1 ± 5.1 to Session 5 (11.0 ± 7.6. The treatment was tolerable and safe. Physiology data were acquired on 6 of 8 subjects and showed no change over time. These results suggest rTMS can modulate CD symptoms. Both dPM and MC are areas to be targeted in further rTMS studies. The improvement in TWSTRS scores over time with multiple rTMS sessions deserves further evaluation.

  10. Groundwater residence time downgradient of Trench No. 22 at the Chernobyl Pilot Site: Constraints on hydrogeological aquifer functioning

    International Nuclear Information System (INIS)

    Le Gal La Salle, C.; Aquilina, L.; Fourre, E.; Jean-Baptiste, P.; Michelot, J.-L.; Roux, C.; Bugai, D.; Labasque, T.; Simonucci, C.; Van Meir, N.; Noret, A.; Bassot, S.; Dapoigny, A.; Baumier, D.

    2012-01-01

    Following the explosion of reactor 4 at the Chernobyl power plant in northern Ukraine in 1986, contaminated soil and vegetation were buried in shallow trenches dug directly on-site in an Aeolian sand deposit. These trenches are sources of radionuclide (RN) pollution. The objective of the present study is to provide constraints for the Chernobyl flow and RN transport models by characterising groundwater residence time. A radiochronometer 3 H/ 3 He method (t 1/2 = 12.3 a) and anthropogenic tracers including CFC and SF 6 are investigated along with the water mass natural tracers Na, Cl, 18 O and 2 H. The groundwater is stratified, as evidenced by Na and Cl concentrations and stable isotopes ( 18 O, 2 H). In the upper aeolian layer, the Na–Cl relationship corresponds to evapotranspiration of precipitation, while in the underlying alluvial layer, an increase in Na and Cl with depth suggests both water–rock interactions and mixing processes. The 3 H/ 3 He and CFC apparent groundwater ages increase with depth, ranging from ‘recent’ (1–3 a) at a 2 m depth below the groundwater table to much higher apparent ages of 50–60 a at 27 m depth below the groundwater table. Discrepancies in 3 H/ 3 He and CFC apparent ages (20–25 a and 3–10 a, respectively) were observed during the 2008 campaign at an intermediate depth immediately below the aeolian/alluvial sand limit, which were attributed to the complex water transfer processes. Extremely high SF 6 concentrations, well above equilibrium with the atmosphere and up to 1112 pptv, are attributed to significant contamination of the soils following the nuclear reactor explosion in 1986. The SF 6 concentration vs. the apparent groundwater ages agrees with this interpretation, as the high SF 6 concentrations are all more recent than 1985. The persistence of the SF 6 concentration suggests that SF 6 was introduced in the soil atmosphere and slowly integrated in the groundwater moving along the hydraulic gradient. The

  11. The thermodynamic approach of the pilot-scale purification of refractory metals; Application de la thermodynamique a la mise au point des methodes de purification industrielle des metaux et semi-metaux refractaires

    Energy Technology Data Exchange (ETDEWEB)

    Accary, A [Commissariat a l' Energie Atomique, Dir. des Piles Atomiques, Saclay (France). Centre d' Etudes Nucleaires

    1967-06-15

    The author shows how the thermodynamic can be applied to the prediction of the evolution of impurities from a metal or an alloy being melted and cast at the pilot-scale using electron bombardment and continuous casting in a water cooled copper. He studies this possibility on two examples: - the melting vanadium, - the melting of the uranium monocarbide. He shows using only the constants available in the literature and a few special runs in the pilot-equipment itself it is possible to determine: - the possibility of elimination of anyone impurity by keeping the material in the melting state under vacuum as well as the limit of purification which is achievable under given technological conditions, - the proportion of an impure metal which should be vaporized in order to bring the level of a given impurity down to a predetermined level and the necessary duration of heating. (author) [French] L'auteur montre comment la thermodynamique peut etre appliquee a la prevision de l'evolution d'un metal ou d'un alliage fondu a l'echelle pilote par bombardement d'electrons et coule en continu dans un creuset de cuivre refroidi. Il etudie cette possibilite sur deux cas particuliers: - la fusion de vanadium, - la fusion du monocarbure d'uranium. Il montre que, grace aux constantes disponibles dans la litterature et a des essais simples faits a l'aide de l'appareillage pilote lui-meme, on peut determiner: - la possibilite d'eliminer une impurete par maintien a l'etat fondu ainsi que la limite de purification dans des conditions technologiques donnees, - la proportion d'un metal brut qu'il faut evaporer pour amener sa teneur en une impurete a un niveau donne ainsi que la duree de chauffage necessaire, - la nature des additions propres a favoriser le depart d'une impurete et l'efficacite comparee des additions possibles. (auteur)

  12. Structure of eutectic alloys of Au with Si and Ge

    Energy Technology Data Exchange (ETDEWEB)

    Takeda, S. [Faculty of Sciences, Kyushu University, 4-2-1, Ropponmatsu, Fukuoka 810-8560 (Japan)], E-mail: takeda@rc.kyushu-u.ac.jp; Fujii, H. [Graduate School of Sciences, Kyushu University, 4-2-1, Ropponmatsu, Fukuoka 810-8560 (Japan); Kawakita, Y. [Faculty of Sciences, Kyushu University, 4-2-1, Ropponmatsu, Fukuoka 810-8560 (Japan); Tahara, S.; Nakashima, S. [Graduate School of Sciences, Kyushu University, 4-2-1, Ropponmatsu, Fukuoka 810-8560 (Japan); Kohara, S.; Itou, M. [Japan Synchrotron Radiation Research Institute, 1-1-1 Koto Sayo-cho, Sayo Hyogo 679-5198 (Japan)

    2008-03-06

    Au-Si and Au-Ge alloy systems have a deep eutectic point in the Au-rich concentration region where the melting point falls down to 633 K. In order to investigate the liquid structure in relation to the glass-forming tendency of these alloys, high-energy X-ray diffraction measurements have been carried out at the eutectic composition and at compositions with excess amounts of Au or IVb element. The nearest neighbor correlations in the eutectic liquids are intense and sharp in the pair distribution function and exhibit a rather small temperature dependence in comparison with those alloys of other than the eutectic composition. Structural models for these liquid alloys are proposed with the aid of reverse Monte Carlo simulation. The reproduced atomic arrangements around the eutectic region exhibit a substitutional-type structure where the dense random packing of Au atoms is preserved and Si or Ge atoms occupy the Au-sites at random.

  13. An experimental study of the thermal conductivity: application of EST 205 borehole of Meuse/Haute Marne site (ANDRA); Etude experimentale de la conductivite thermique: application au forage EST 205 du site de Meuse/Haute Marne (ANDRA)

    Energy Technology Data Exchange (ETDEWEB)

    Jorand, R

    2006-10-15

    The determination of the thermal properties of clayey rocks is fundamental for predicting the behaviour a radioactive waste geological repository, and geothermal and oil reservoirs. The main objectives of this thesis work were to 1) better understand the effects of the parameters controlling the thermal conductivity, 2) study to which extent the laboratory measurements can be extrapolated to the field, and 3) find relationships between the thermal conductivity and other quantities easier to measure on the field, e.g. the P- and S- wave velocities. The study was conducted on 24 cores of marls carbonates and argillites coming from the EST205 borehole of the M/HM site (ANDRA). After a complete characterisation of the samples, their thermal conductivities were measured using a stationary method. The borehole was drilled with a special oil-based mud to avoid damaging the argillites, and many logs were available. Hence, it is ideal to study the properties of clayey rocks and compare them with field data. The results show the major effect of the microstructure (mainly the particles orientation), which causes the important anisotropy of the thermal conductivity in the marls and argillites. For all lithologies, linear relationships between the conductivity and the P- and S- wave velocities were obtained. The application of this experimental law to the sonic log helped building a synthetic log of thermal conductivity. Finally, we developed a heat probe, which allows measurements in function of temperature and saturation. We showed with this method that the thermal conductivity increases quasi-linearly with the saturation in a sandstone and a carbonate samples. (author)

  14. Analysis of pumping tests of the Culebra dolomite conducted at the H-11 hydropad at the Waste Isolation Pilot Plant (WIPP) site

    International Nuclear Information System (INIS)

    Saulnier, G.J. Jr.

    1987-01-01

    The Culebra Dolomite Member of the Permian Rustler Formation was hydrologically evaluated in a series of pumping tests conducted at the H-11 hydropad at the Waste Isolation Pilot Plant (WIPP) site. At H-11, the Culebra dolomite is a 25-ft thick argillaceous dolomite with 0.1- to 0.5-foot thick layers with a high density of vugs. The vugs range in size from 0.1 to 0.5 inches in diameter; most are 0.1 to 0.2 inches in diameter. The thin vuggy layers alternate with thicker, more competent layers which have few vugs, but which do contain high-angle fractures. Some of the vugs and fractures are gypsum-filled. Three pumping tests consisted of 12- to 21-hour pumping periods at each of the three wells, while using the other two wells at the hydropad as observation wells. An additional pumping test was conducted at H-11b3 with H-11b1 and H-11b2 as observation wells. The test was a 32-day multirate test with four pumping and recovery periods. The original tests were conducted by lowering a submersible pump and pressure transducers in the boreholes. The additional test added a downhole packer with feed-through assembly designed to isolate the test interval and reduce or minimize the effect of wellbore storage. The data from all tests were recorded and stored on floppy disks. The pumping tests at the H-11 hydropad were analyzed with the INTERPRET reservoir-analysis software. 46 refs., 46 figs., 12 tabs

  15. Preferential Au precipitation at deformation-induced defects in Fe–Au and Fe–Au–B–N alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, S., E-mail: S.Zhang-1@tudelft.nl [Fundamental Aspects of Materials and Energy, Faculty of Applied Sciences, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Langelaan, G. [Fundamental Aspects of Materials and Energy, Faculty of Applied Sciences, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Brouwer, J.C.; Sloof, W.G. [Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft (Netherlands); Brück, E. [Fundamental Aspects of Materials and Energy, Faculty of Applied Sciences, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Zwaag, S. van der [Novel Aerospace Materials Group, Faculty of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, 2629 HS Delft (Netherlands); Dijk, N.H. van [Fundamental Aspects of Materials and Energy, Faculty of Applied Sciences, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands)

    2014-01-25

    Highlights: • Fe–Au–B–N forms a good model alloy system for self healing of deformation damage. • Solute Au atoms exclusively precipitate at grain boundaries, cracks and cavities. • XPS indicates a strong tendency for Au segregation on free surfaces at 550 °C. • Interstitial B and N form hexagonal BN on free surfaces at 550 °C. • Selective Au precipitation at open volume defects can cause autonomous repair. -- Abstract: The influence of deformation-induced defects on the isothermal precipitation of Au was studied in high-purity Fe–Au and Fe–Au–B–N alloys. Preferential Au precipitation upon annealing at 550 °C is observed at local plastic indentations. In fractured Fe–Au–B–N, solute Au atoms were found to heterogeneously precipitate at grain boundaries and local micro-cracks. This is supported by in-situ creep tests that showed a strong tendency for Au precipitation at cracks and cavities also formed during creep loading at 550 °C. Complementary X-ray photoelectron spectroscopy experiments indicate a strong tendency of Au, B and N segregation onto free surface during aging. The observed site-specific precipitation of Au holds interesting opportunities for defect healing in steels subjected to creep deformation.

  16. Flow in the unsaturated zone around a shallow subsurface radioactive waste trench: Interpretation of an infiltration–drainage test at the Chernobyl Pilot Site

    International Nuclear Information System (INIS)

    Van Meir, N.; Gaudet, J.P.; Phrommavanh, V.; Laurent, J.P.; Bugai, D.; Biron, R.

    2012-01-01

    This article describes an infiltration–drainage test carried out in the unsaturated zone (UZ) at the Chernobyl Pilot Site during October 2008; this is an international radioecology study site and is the subject of several papers in this special issue. The test has to be seen in the larger context of radionuclide transport from a waste trench. The conducted experiment consisted of infiltrating a layer of 9.5 cm of water in a circular area of 5.51 m 2 over 5 h. Its main objective was to create a larger range of water content values (and hence suction pressure values), not only at the top of the soil profile but also at greater depths, in this case up to 1.50 m. Observations of water content and suction pressure were carried out continuously at seven different depths during infiltration, drainage and during the return to natural conditions over a period of several months. This allowed deriving UZ parameter values with greater confidence than those derived from monitoring small natural water content changes over periods of years. The experiment also shows that a 1D model was incapable of correctly reproducing the observed water balance established on the central axis. A 2D axi-symmetric model was needed showing that lateral boundary effects have to be accounted for. This implies that small scale infiltrometer tests should be analysed in more than one dimension. It further became clear from the drainage curves that soil layering played a significant role and that in the present case hysteresis did not play a major role; i.e. the infiltration and drainage event can be reproduced with the same set of parameters and subsequent natural rain events can be reproduced well enough with two numerical models used for test interpretation, one is module oriented for reactive transfer, and the second with an automatic optimisation procedure. The robustness of the estimated parameter values, of the model discretisation and layer identification was tested over a 2-month period with

  17. Poisson's ratio model derived from P- and S-wave reflection seismic data at the CO2CRC Otway Project pilot site, Australia

    Science.gov (United States)

    Beilecke, Thies; Krawczyk, Charlotte M.; Tanner, David C.; Ziesch, Jennifer; Research Group Protect

    2014-05-01

    Compressional wave (P-wave) reflection seismic field measurements are a standard tool for subsurface exploration. 2-D seismic measurements are often used for overview measurements, but also as near-surface supplement to fill gaps that often exist in 3-D seismic data sets. Such supplementing 2-D measurements are typically simple with respect to field layout. This is an opportunity for the use of shear waves (S-waves). Within the last years, S-waves have become more and more important. One reason is that P- and S-waves are differently sensitive to fluids and pore fill so that the additional S-wave information can be used to enhance lithological studies. Another reason is that S-waves have the advantage of higher spatial resolution. Within the same signal bandwidth they typically have about half the wavelength of P-waves. In near-surface unconsolidated sediments they can even enhance the structural resolution by one order of magnitude. We make use of these capabilities within the PROTECT project. In addition to already existing 2-D P-wave data, we carried out a near surface 2-D S-wave field survey at the CO2CRC Otway Project pilot site, close to Warrnambool, Australia in November 2013. The combined analysis of P-wave and S-wave data is used to construct a Poisson's Ratio 2-D model down to roughly 600 m depth. The Poisson's ratio values along a 1 km long profile at the site are surprisingly high, ranging from 0.47 in the carbonate-dominated near surface to 0.4 at depth. In the literature, average lab measurements of 0.22 for unfissured carbonates and 0.37 for fissured examples have been reported. The high values that we found may indicate areas of rather unconsolidated or fractured material, or enhanced fluid contents, and will be subject of further studies. This work is integrated in a larger workflow towards prediction of CO2 leakage and monitoring strategies for subsurface storage in general. Acknowledgement: This work was sponsored in part by the Australian

  18. Tuning the chemical activity through PtAu nanoalloying: a first principles study

    KAUST Repository

    Mokkath, Junais Habeeb

    2013-06-21

    The electronic structure and adsorption properties of 1.5 nm sized Pt, Au, and PtAu nanoclusters are studied by density functional theory. We explain the recent experimental finding that 20% Au content in PtAu nanoparticles is optimal to induce a dramatically different catalytic behavior. Our results show that the d-band center together with the density of states at the Fermi energy can be used as an indicator of the chemical activity of PtAu nanoclusters. The most favorable adsorption sites on the cluster surfaces as a function of the Pt/Au ratio are identified using atomic H as a probe.

  19. Tuning the chemical activity through PtAu nanoalloying: a first principles study

    KAUST Repository

    Mokkath, Junais Habeeb; Schwingenschlö gl, Udo

    2013-01-01

    The electronic structure and adsorption properties of 1.5 nm sized Pt, Au, and PtAu nanoclusters are studied by density functional theory. We explain the recent experimental finding that 20% Au content in PtAu nanoparticles is optimal to induce a dramatically different catalytic behavior. Our results show that the d-band center together with the density of states at the Fermi energy can be used as an indicator of the chemical activity of PtAu nanoclusters. The most favorable adsorption sites on the cluster surfaces as a function of the Pt/Au ratio are identified using atomic H as a probe.

  20. Imprinting of molecular recognition sites combined with π-donor-acceptor interactions using bis-aniline-crosslinked Au-CdSe/ZnS nanoparticles array on electrodes: Development of electrochemiluminescence sensor for the ultrasensitive and selective detection of 2-methyl-4-chlorophenoxyacetic acid.

    Science.gov (United States)

    Yang, Yukun; Fang, Guozhen; Wang, Xiaomin; Liu, Guiyang; Wang, Shuo

    2016-03-15

    A novel strategy is reported for the fabrication of bis-aniline-crosslinked Au nanoparticles (NPs)-CdSe/ZnS quantum dots (QDs) array composite by facil one-step co-electropolymerization of thioaniline-functionalized AuNPs and thioaniline-functionalized CdSe/ZnS QDs onto thioaniline-functionalized Au elctrodes (AuE). Stable and enhanced cathodic electrochemiluminescence (ECL) of CdSe/ZnS QDs is observed on the modified electrode in neutral solution, suggesting promising applications in ECL sensing. An advanced ECL sensor is explored for detection of 2-methyl-4-chlorophenoxyacetic acid (MCPA) which quenches the ECL signal through electron-transfer pathway. The sensitive determination of MCPA with limit of detection (LOD) of 2.2 nmolL(-1) (S/N=3) is achieved by π-donor-acceptor interactions between MCPA and the bis-aniline bridging units. Impressively, the imprinting of molecular recognition sites into the bis-aniline-crosslinked AuNPs-CdSe/ZnS QDs array yields a functionalized electrode with an extremely sensitive response to MCPA in a linear range of 10 pmolL(-1)-50 μmolL(-1) with a LOD of 4.3 pmolL(-1 ()S/N=3). The proposed ECL sensor with high sensitivity, good selectivity, reproducibility and stability has been successfully applied for the determination of MCPA in real samples with satisfactory recoveries. In this study, ECL sensor combined the merits of QDs-ECL and molecularly imprinting technology is reported for the first time. The developed ECL sensor holds great promise for the fabrication of QDs-based ECL sensors with improved sensitivity and furthermore opens the door to wide applications of QDs-based ECL in food safety and environmental monitoring. Copyright © 2015 Elsevier B.V. All rights reserved.

  1. Efficient Photocatalytic H2 Evolution: Controlled Dewetting-Dealloying to Fabricate Site-Selective High-Activity Nanoporous Au Particles on Highly Ordered TiO2 Nanotube Arrays.

    Science.gov (United States)

    Nguyen, Nhat Truong; Altomare, Marco; Yoo, JeongEun; Schmuki, Patrik

    2015-05-27

    Anodic self-organized TiO2 nanostumps are formed and exploited for self-ordering dewetting of Au-Ag sputtered films. This forms ordered particle configurations at the tube top (crown position) or bottom (ground position). By dealloying from a minimal amount of noble metal, porous Au nanoparticles are then formed, which, when in the crown position, allow for a drastically improved photocatalytic H2 production compared with nanoparticles produced by conventional dewetting processes. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Stability, structural and electronic properties of benzene molecule adsorbed on free standing Au layer

    Energy Technology Data Exchange (ETDEWEB)

    Katoch, Neha, E-mail: nehakatoch2@gmail.com; Kapoor, Pooja; Sharma, Munish; Ahluwalia, P. K. [Physics Department, Himachal Pradesh University, Shimla, Himachal Pradesh, India 171005 (India); Kumar, Ashok [Center for Physical Sciences, School of Basic and Applied Sciences, Central University of Punjab, Bathinda, India, 151001 (India)

    2016-05-23

    We report stability and electronic properties of benzene molecule adsorbed on the Au atomic layer within the framework of density function theory (DFT). Horizontal configuration of benzene on the top site of Au monolayer prefers energetically over other studied configurations. On the adsorption of benzene, the ballistic conductance of Au monolayer is found to decrease from 4G{sub 0} to 2G{sub 0} suggesting its applications for the fabrications of organic sensor devices based on the Au atomic layers.

  3. Comparison of long-term numerical simulations at the Ketzin pilot site using the Schlumberger ECLIPSE and LBNL TOUGH2 simulators

    Science.gov (United States)

    Kempka, T.; Norden, B.; Tillner, E.; Nakaten, B.; Kühn, M.

    2012-04-01

    Geological modelling and dynamic flow simulations were conducted at the Ketzin pilot site showing a good agreement of history matched geological models with CO2 arrival times in both observation wells and timely development of reservoir pressure determined in the injection well. Recently, a re-evaluation of the seismic 3D data enabled a refinement of the structural site model and the implementation of the fault system present at the top of the Ketzin anticline. The updated geological model (model size: 5 km x 5 km) shows a horizontal discretization of 5 x 5 m and consists of three vertical zones, with the finest discretization at the top (0.5 m). According to the revised seismic analysis, the facies modelling to simulate the channel and floodplain facies distribution at Ketzin was updated. Using a sequential Gaussian simulator for the distribution of total and effective porosities and an empiric porosity-permeability relationship based on site and literature data available, the structural model was parameterized. Based on this revised reservoir model of the Stuttgart formation, numerical simulations using the TOUGH2-MP/ECO2N and Schlumberger Information Services (SIS) ECLIPSE 100 black-oil simulators were undertaken in order to evaluate the long-term (up to 10,000 years) migration of the injected CO2 (about 57,000 t at the end of 2011) and the development of reservoir pressure over time. The simulation results enabled us to quantitatively compare both reservoir simulators based on current operational data considering the long-term effects of CO2 storage including CO2 dissolution in the formation fluid. While the integration of the static geological model developed in the SIS Petrel modelling package into the ECLIPSE simulator is relatively flawless, a work-flow allowing for the export of Petrel models into the TOUGH2-MP input file format had to be implemented within the scope of this study. The challenge in this task was mainly determined by the presence of a

  4. Pilot Implementations

    DEFF Research Database (Denmark)

    Manikas, Maria Ie

    by conducting a literature review. The concept of pilot implementation, although commonly used in practice, is rather disregarded in research. In the literature, pilot implementations are mainly treated as secondary to the learning outcomes and are presented as merely a means to acquire knowledge about a given...... objective. The prevalent understanding is that pilot implementations are an ISD technique that extends prototyping from the lab and into test during real use. Another perception is that pilot implementations are a project multiple of co-existing enactments of the pilot implementation. From this perspective......This PhD dissertation engages in the study of pilot (system) implementation. In the field of information systems, pilot implementations are commissioned as a way to learn from real use of a pilot system with real data, by real users during an information systems development (ISD) project and before...

  5. WIPP site and vicinity geological field trip. A report of a field trip to the proposed Waste Isolation Pilot Plant project in Southeastern New Mexico, June 16 to 18, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Chaturvedi, L

    1980-10-01

    The Environmental Evaluation Group is conducting an assessment of the radiological health risks to people from the Waste Isolation Pilot Plant. As a part of this work, EEG is making an effort to improve the understanding of those geological issues concerning the WIPP site which may affect the radiological consequences of the proposed repository. One of the important geological issues to be resolved is the timing and the nature of the dissolution processes which may have affected the WIPP site. EEG organized a two-day conference of geological scientists, on January 17-18, 1980. On the basis of the January conference and the June field trip, EEG has formed the following conclusions: (1) it has not been clearly established that the site or the surrounding area has been attacked by deep dissolution to render it unsuitable for the nuclear waste pilot repository; (2) the existence of an isolated breccia pipe at the site unaccompanied by a deep dissolution wedge, is a very remote possibility; (3) more specific information about the origin and the nature of the brine reservoirs is needed. An important question that should be resolved is whether each encounter with artesian brine represents a separate pocket or whether these occurrences are interconnected; (4) Anderson has postulated a major tectonic fault or a fracture system at the Basin margin along the San Simon Swale; (5) the area in the northern part of the WIPP site, identified from geophysical and bore hole data as the disturbed zone, should be further investigated to cleary understand the nature and significance of this structural anomaly; and (6) a major drawback encountered during the discussions of geological issues related to the WIPP site is the absence of published material that brings together all the known information related to a particular issue.

  6. Magnetic susceptibilities of liquid Cr-Au, Mn-Au and Fe-Au alloys

    Energy Technology Data Exchange (ETDEWEB)

    Ohno, S.; Shimakura, H. [Niigata University of Pharmacy and Applied Life Sciences, Higashijima, Akiha-ku, Niigata 956-8603 (Japan); Tahara, S. [Faculty of Science, University of the Ryukyus, Nishihara-cho, Okinawa 903-0213 (Japan); Okada, T. [Niigata College of Technology, Kamishin’eicho, Nishi-ku, Niigata 950-2076 (Japan)

    2015-08-17

    The magnetic susceptibility of liquid Cr-Au, Mn-Au, Fe-Au and Cu-Au alloys was investigated as a function of temperature and composition. Liquid Cr{sub 1-c}Au{sub c} with 0.5 ≤ c and Mn{sub 1-c}Au{sub c} with 0.3≤c obeyed the Curie-Weiss law with regard to their dependence of χ on temperature. The magnetic susceptibilities of liquid Fe-Au alloys also exhibited Curie-Weiss behavior with a reasonable value for the effective number of Bohr magneton. On the Au-rich side, the composition dependence of χ for liquid TM-Au (TM=Cr, Mn, Fe) alloys increased rapidly with increasing TM content, respectively. Additionally, the composition dependences of χ for liquid Cr-Au, Mn-Au, and Fe-Au alloys had maxima at compositions of 50 at% Cr, 70 at% Mn, and 85 at% Fe, respectively. We compared the composition dependences of χ{sub 3d} due to 3d electrons for liquid binary TM-M (M=Au, Al, Si, Sb), and investigated the relationship between χ{sub 3d} and E{sub F} in liquid binary TM-M alloys at a composition of 50 at% TM.

  7. Marine Biological Investigations at the Eniwetok Test Site; Recherches de Biologie Marine au Centre d'Essais d'Eniwetok; 0411 0414 ; Investigaciones sobre Biologia Marina en la Zona de Ensayo de Eniwetok

    Energy Technology Data Exchange (ETDEWEB)

    Lowman, Frank G. [Laboratory of Radiation Biology, University of Washington (United States)

    1960-07-01

    The results of marine biological investigations conducted at the Eniwetok Test Site since 1952 are summarized. Radioisotopes introduced into the sea from the tests at various times since then include fission products and other radioisotopes (U{sup 237}, Np{sup 239}, Mn{sup 54}, Fe{sup 55,59}, Co{sup 57,58,60}, Zn{sup 65} and W{sup 185}). The levels of radioisotopes in plankton samples taken 4 days to 6 weeks after contamination are reported and the distribution of the radioactivity between plankton and water is given. Grazing fishes contained Zn{sup 65}, Fe{sup 55}, Co{sup 57,58,60} and Mn{sup 54}. Carnivorous fishes contained mostly Fe{sup 55} and Zn{sup 65}. (author) [French] L'auteur fait le bilan des recherches de biologie marine effectuees depuis 1952 au Centre d'essais d'Eniwetok. Les radioisotopes qui se sont repandus dans la mer a la suite des essais auxquels on a procede a plusieurs reprises depuis cette date comprennent des produits de fission et d'autres isotopes ({sup 237}U, {sup 239}Np, {sup 54}Mn, {sup 55,59}Fe, {sup 57,58,60}Co, {sup 65}Zn et {sup 185}W). L'auteur indique les quantites des radioisotopes presents dans des echantillons de plancton preleves de quatre jours a six semaines apres ia contamination, et la repartition de la radioactivite entre le plancton et l'eau. Les poissons herbivores contenaient du zinc-65, du fer-55, du cobalt-57, 58, 60 et du manganese-54. Les poissons carnassiers contenaient surtout du fer-55 et du zinc-65. (author) [Spanish] En la memoria se resumen los resultados de las investigaciones sobre biologia marina que se vienen realizando desde 1952 en la zona de ensayo de Eniwetok. A consecuencia de los diversos ensayos nucleares efectuados desde esa fecha se han introducido en el mar una serie de productos de fision y otros radioisotopos ({sup 237}U, {sup 239}Np, {sup 54}Mn, {sup 55,59}Fe, {sup 57,58,60}Co, {sup 65}Zn y {sup 185}W). El autor indica la concentracion de los radioisotopos en las muestras de plancton tomadas

  8. Comparative study of surface-lattice-site resolved neutralization of slow multicharged ions during large-angle quasi-binary collisions with Au(1 1 0): Simulation and experiment

    International Nuclear Information System (INIS)

    Meyer, F.W.; Morozov, V.A.

    2002-01-01

    In this article we extend our earlier studies of the azimuthal dependences of low energy projectiles scattered in large angle quasi-binary collisions (BCs) from Au(1 1 0). Measurements are presented for 20 keV Ar 9+ at normal incidence, which are compared with our earlier measurements for this ion at 5 keV and 10 deg. incidence angle. A deconvolution procedure based on MARLOWE simulation results carried out at both energies provides information about the energy dependence of projectile neutralization during interactions just with the atoms along the top ridge of the reconstructed Au(1 1 0) surface corrugation, in comparison to, e.g. interactions with atoms lying on the sidewalls. To test the sensitivity of the agreement between the MARLOWE results and the experimental measurements, we show simulation results obtained for a non-reconstructed Au(1 1 0) surface with 20 keV Ar projectiles, and for different scattering potentials that are intended to simulate the effects on scattering trajectory of a projectile inner shell vacancy surviving the BC. In addition, simulation results are shown for a number of different total scattering angles, to illustrate their utility in finding optimum values for this parameter prior to the actual measurements

  9. Reports on 1977 result of research. Investigation for selecting site location of pilot plant for 7,000Nm{sup 3}/day class high calorie gasification; 1977 nendo sunshine keikaku ni kakawaru plant kenkyu kaihatsu seika hokoku. 7,000Nm{sup 3}/nichi kyu kokarori gas ka pilot plant yochi no ricchi sentei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1978-03-20

    A report was made on the result of investigation for selecting a suitable site for a coal gasification pilot plant. The high calorie gasification plant under the Sunshine Project is scheduled to have a parallel operation of two methods. It could be decided on one only method depending on the future studies. One is the 'water gasification method' using coal only as the raw material, with hydrogen gas added to contrive methanization. The other is the 'hybrid gasification method' using mixed slurry of powdered coal and heavy oil as the raw material, with oxygen supplied to it to form a clean gas. The sites proposed for the pilot plant are the cities of Yubari, Iwaki, Kita-Ibaraki, Tagawa, Iizuka and Imari. The items for assessment of cost effectiveness are the expenses of development of a site, road construction, removal of existing obstacles, plant construction, power receiving equipment construction, irrigation supply facilities construction, wastewater treatment system construction, ash discharging system construction, transportation, and supply/processing-related maintenance. As a result of the assessment, Iwaki city was picked up as the area almost free from drawbacks to cost effectiveness. (NEDO)

  10. Reports on 1977 result of research. Investigation for selecting site location of pilot plant for 7,000Nm{sup 3}/day class high calorie gasification; 1977 nendo sunshine keikaku ni kakawaru plant kenkyu kaihatsu seika hokoku. 7,000Nm{sup 3}/nichi kyu kokarori gas ka pilot plant yochi no ricchi sentei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1978-03-20

    A report was made on the result of investigation for selecting a suitable site for a coal gasification pilot plant. The high calorie gasification plant under the Sunshine Project is scheduled to have a parallel operation of two methods. It could be decided on one only method depending on the future studies. One is the 'water gasification method' using coal only as the raw material, with hydrogen gas added to contrive methanization. The other is the 'hybrid gasification method' using mixed slurry of powdered coal and heavy oil as the raw material, with oxygen supplied to it to form a clean gas. The sites proposed for the pilot plant are the cities of Yubari, Iwaki, Kita-Ibaraki, Tagawa, Iizuka and Imari. The items for assessment of cost effectiveness are the expenses of development of a site, road construction, removal of existing obstacles, plant construction, power receiving equipment construction, irrigation supply facilities construction, wastewater treatment system construction, ash discharging system construction, transportation, and supply/processing-related maintenance. As a result of the assessment, Iwaki city was picked up as the area almost free from drawbacks to cost effectiveness. (NEDO)

  11. Le CRDI au Ghana

    International Development Research Centre (IDRC) Digital Library (Canada)

    pour prévenir le paludisme, des études ayant démontré que leur utilisation pouvait réduire considérablement la mortalité infantile. Les chercheurs ont également suggéré aux gouvernements différents moyens pour inciter les gens à acheter les moustiquaires et à les utiliser correctement. Les TI au service de la démocratie.

  12. Mise au point

    African Journals Online (AJOL)

    et traité à temps, le risque de complications et de morbidité peut être écarté. Les auteurs rapportent 2 cas de kystes de la vallécule. La tomodensitométrie a confirmé la présence d'une formation kystique prenant origine au niveau de la val- lécule. Une laryngoscopie directe a été faite pour les 2 patients sous anesthésie ...

  13. Diastereoselective Au-Catalyzed Allene Cycloisomerizations to Highly Substituted Cyclopentenes.

    Science.gov (United States)

    Reeves, Ryan D; Phelps, Alicia M; Raimbach, William A T; Schomaker, Jennifer M

    2017-07-07

    Site- and regiocontrolled Au-catalyzed allene carbocyclizations furnish highly substituted cyclopentenes in >1:1 dr. Significant substitution on the substrate is tolerated, with potential to install five contiguous stereocenters after alkene functionalization. Major challenges include identifying a Au/Cu catalyst that controls both the relative rates of allene epimerization/cyclization and the facial selectivity in addition of a metal enolate to the allene. Experiments to achieve stereodivergent cyclizations and transform key cyclopentenes into useful synthetic building blocks are described.

  14. Impact of Surgihoney Reactive Oxygen on surgical site infection (SSI after complex abdominal wall reconstruction (AWR of grade 3 and 4 ventral Hernias: A single arm pilot study

    Directory of Open Access Journals (Sweden)

    Sam Parker

    2017-01-01

    Conclusions: This study will provide an assessment of methods and feasibility of recruiting and following up patients who are treated with SHRO. On the basis of this pilot trial, a full trial may be proposed in the future which will provide additional, robust evidence on the clinical and cost effectiveness of SHRO in wound management following AWR. This may act as a model for the management of wounds in complex patients undergoing AWR.

  15. Mise au point

    African Journals Online (AJOL)

    tomie est replacé et fixé par des fils d'acier, krönlein lais- sait ce fragment pédiculé au fascia temporalis afin d'évi- ter la dépression de la fosse temporale due à la désinser- tion du muscle temporal [20] ; dans notre série, après reconstitution du cadre, le muscle temporal est suturé à son point d'insertion. pour les tumeurs ...

  16. Antibacterial Au nanostructured surfaces

    Science.gov (United States)

    Wu, Songmei; Zuber, Flavia; Brugger, Juergen; Maniura-Weber, Katharina; Ren, Qun

    2016-01-01

    We present here a technological platform for engineering Au nanotopographies by templated electrodeposition on antibacterial surfaces. Three different types of nanostructures were fabricated: nanopillars, nanorings and nanonuggets. The nanopillars are the basic structures and are 50 nm in diameter and 100 nm in height. Particular arrangement of the nanopillars in various geometries formed nanorings and nanonuggets. Flat surfaces, rough substrate surfaces, and various nanostructured surfaces were compared for their abilities to attach and kill bacterial cells. Methicillin-resistant Staphylococcus aureus, a Gram-positive bacterial strain responsible for many infections in health care system, was used as the model bacterial strain. It was found that all the Au nanostructures, regardless their shapes, exhibited similar excellent antibacterial properties. A comparison of live cells attached to nanotopographic surfaces showed that the number of live S. aureus cells was flat and rough reference surfaces. Our micro/nanofabrication process is a scalable approach based on cost-efficient self-organization and provides potential for further developing functional surfaces to study the behavior of microbes on nanoscale topographies.We present here a technological platform for engineering Au nanotopographies by templated electrodeposition on antibacterial surfaces. Three different types of nanostructures were fabricated: nanopillars, nanorings and nanonuggets. The nanopillars are the basic structures and are 50 nm in diameter and 100 nm in height. Particular arrangement of the nanopillars in various geometries formed nanorings and nanonuggets. Flat surfaces, rough substrate surfaces, and various nanostructured surfaces were compared for their abilities to attach and kill bacterial cells. Methicillin-resistant Staphylococcus aureus, a Gram-positive bacterial strain responsible for many infections in health care system, was used as the model bacterial strain. It was found that all

  17. Au@AuPt nanoparticles embedded in B-doped graphene: A superior electrocatalyst for determination of rutin

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Xianlan; Yang, Guangming; Feng, Shaoping; Shi, Ling; Huang, Zhaolong [School of Science, Honghe University (China); Key Laboratory of Natural Pharamaceutical & Chemical Biology of Yunnan Province Mengzi, Yunnan 661100 (China); Pan, Haibo [Fujian Key Lab of Medical Instrument & Pharmaceutical Technology, Yishan Campus, Fuzhou University, Fuzhou, Fujian 350002 (China); Liu, Wei, E-mail: liuwei4728@126.com [School of Science, Honghe University (China); Key Laboratory of Natural Pharamaceutical & Chemical Biology of Yunnan Province Mengzi, Yunnan 661100 (China)

    2017-04-30

    Highlights: • The formation of B-doped graphene (BG) with high content of a total B species use hydrothermal method with B{sub 2}O{sub 3} as reducing agent and boron source. • BG was exfoliated into monolayer nanosheet impregnated by Au@AuPt NPs because B atom creates a net positive charge to facilitate NPs adsorption. • The dispersed carboxyl units of BG can form hydrogen bonding with the phenolic hydroxyl groups of rutin, making more rutin participate in reaction. • Au@AuPt NPs can form charge accumulation or valence change on prominent part of the surface, improving the catalytic effect to rutin. • More electroactive sites were generated by doping B atoms into graphene structures, which act as multidimensional electron transport pathways. - Abstract: A hydrothermal approach was used to prepare B-doped graphene with B{sub 2}O{sub 3} as reductant and boron source. Results reveal that the boron atoms have been successfully embedded into graphene with a high content of a total B species (2.85 at.%). Then, B-doped graphene was exfoliated further into monolayer nanosheet by impregnating Au@AuPt core-shell nanoparticles (Au@AuPt NPs) because boron atom creates a net positive charge, which facilitates Au@AuPt NPs adsorption to form Au@AuPt NPs/B-doped graphene hybrid nanocatalysts. After that, the Au@AuPt NPs/B-doped hybrid suspension was dropped on glassy carbon electrode for sensing rutin. In this way, the dispersed carboxyl units of B-doped graphene can form hydrogen bonding with the phenolic hydroxyl groups of rutin, making rutin enrich easily on modified electrode surface to enhance the electrochemical response. At the same time, its electrochemical mechanism on the modified electrode was elucidated using cyclic voltammetry. It was found that its electrochemical behavior on modified electrode surface was a surface-controlled quasi-reversible process, and the charge transfer coefficient (α) and electron transfer number (n) were 0.296 and 2, respectively

  18. Pilot implementation

    DEFF Research Database (Denmark)

    Hertzum, Morten; Bansler, Jørgen P.; Havn, Erling C.

    2012-01-01

    A recurrent problem in information-systems development (ISD) is that many design shortcomings are not detected during development, but first after the system has been delivered and implemented in its intended environment. Pilot implementations appear to promise a way to extend prototyping from...... the laboratory to the field, thereby allowing users to experience a system design under realistic conditions and developers to get feedback from realistic use while the design is still malleable. We characterize pilot implementation, contrast it with prototyping, propose a iveelement model of pilot...... implementation and provide three empirical illustrations of our model. We conclude that pilot implementation has much merit as an ISD technique when system performance is contingent on context. But we also warn developers that, despite their seductive conceptual simplicity, pilot implementations can be difficult...

  19. NSTAR Smart Grid Pilot

    Energy Technology Data Exchange (ETDEWEB)

    Rabari, Anil [NSTAR Electric, Manchester, NH (United States); Fadipe, Oloruntomi [NSTAR Electric, Manchester, NH (United States)

    2014-03-31

    NSTAR Electric & Gas Corporation (“the Company”, or “NSTAR”) developed and implemented a Smart Grid pilot program beginning in 2010 to demonstrate the viability of leveraging existing automated meter reading (“AMR”) deployments to provide much of the Smart Grid functionality of advanced metering infrastructure (“AMI”), but without the large capital investment that AMI rollouts typically entail. In particular, a central objective of the Smart Energy Pilot was to enable residential dynamic pricing (time-of-use “TOU” and critical peak rates and rebates) and two-way direct load control (“DLC”) by continually capturing AMR meter data transmissions and communicating through customer-sited broadband connections in conjunction with a standardsbased home area network (“HAN”). The pilot was supported by the U.S. Department of Energy’s (“DOE”) through the Smart Grid Demonstration program. NSTAR was very pleased to not only receive the funding support from DOE, but the guidance and support of the DOE throughout the pilot. NSTAR is also pleased to report to the DOE that it was able to execute and deliver a successful pilot on time and on budget. NSTAR looks for future opportunities to work with the DOE and others in future smart grid projects.

  20. Antibacterial Au nanostructured surfaces.

    Science.gov (United States)

    Wu, Songmei; Zuber, Flavia; Brugger, Juergen; Maniura-Weber, Katharina; Ren, Qun

    2016-02-07

    We present here a technological platform for engineering Au nanotopographies by templated electrodeposition on antibacterial surfaces. Three different types of nanostructures were fabricated: nanopillars, nanorings and nanonuggets. The nanopillars are the basic structures and are 50 nm in diameter and 100 nm in height. Particular arrangement of the nanopillars in various geometries formed nanorings and nanonuggets. Flat surfaces, rough substrate surfaces, and various nanostructured surfaces were compared for their abilities to attach and kill bacterial cells. Methicillin-resistant Staphylococcus aureus, a Gram-positive bacterial strain responsible for many infections in health care system, was used as the model bacterial strain. It was found that all the Au nanostructures, regardless their shapes, exhibited similar excellent antibacterial properties. A comparison of live cells attached to nanotopographic surfaces showed that the number of live S. aureus cells was flat and rough reference surfaces. Our micro/nanofabrication process is a scalable approach based on cost-efficient self-organization and provides potential for further developing functional surfaces to study the behavior of microbes on nanoscale topographies.

  1. Cluster-to-cluster transformation among Au6, Au8 and Au11 nanoclusters.

    Science.gov (United States)

    Ren, Xiuqing; Fu, Junhong; Lin, Xinzhang; Fu, Xuemei; Yan, Jinghui; Wu, Ren'an; Liu, Chao; Huang, Jiahui

    2018-05-22

    We present the cluster-to-cluster transformations among three gold nanoclusters, [Au6(dppp)4]2+ (Au6), [Au8(dppp)4Cl2]2+ (Au8) and [Au11(dppp)5]3+ (Au11). The conversion process follows a rule that states that the transformation of a small cluster to a large cluster is achieved through an oxidation process with an oxidizing agent (H2O2) or with heating, while the conversion of a large cluster to a small one occurs through a reduction process with a reducing agent (NaBH4). All the reactions were monitored using UV-Vis spectroscopy and ESI-MS. This work may provide an alternative approach to the synthesis of novel gold nanoclusters and a further understanding of the structural transformation relationship of gold nanoclusters.

  2. Proposal of organisation and ALARA procedures for maintenance site: application to replacement of steam generator; Propositions d'organisation et procedures ALARA pour la preparation des chantiers de maintenance: application au RGV

    Energy Technology Data Exchange (ETDEWEB)

    Lochard, J; Lefaure, C

    1989-08-01

    This report proposes generic organization and ALARA procedures for preparing a maintenance site at a NPP. After a short description of the ALARA principle, it describes the proposition for French sites. They are grouped according to the following: motivation, organisation, means. They are illustrated by the example of steam generator replacement. Three special points concerning preparation of the site are developed: education; training of operators; review of the project.

  3. Charged particle density distributions in Au + Au collisions at ...

    Indian Academy of Sciences (India)

    Charged particle pseudorapidity distributions have been measured in Au + Au collisions using the BRAHMS detector at RHIC. The results are presented as a function of the collision centrality and the center of mass energy. They are compared to the predictions of different parton scattering models and the important role of ...

  4. Analysis of empty ATLAS pilot jobs

    Science.gov (United States)

    Love, P. A.; Alef, M.; Dal Pra, S.; Di Girolamo, A.; Forti, A.; Templon, J.; Vamvakopoulos, E.; ATLAS Collaboration

    2017-10-01

    In this analysis we quantify the wallclock time used by short empty pilot jobs on a number of WLCG compute resources. Pilot factory logs and site batch logs are used to provide independent accounts of the usage. Results show a wide variation of wallclock time used by short jobs depending on the site and queue, and changing with time. For a reference dataset of all jobs in August 2016, the fraction of wallclock time used by empty jobs per studied site ranged from 0.1% to 0.8%. Aside from the wall time used by empty pilots, we also looked at how many pilots were empty as a fraction of all pilots sent. Binning the August dataset into days, empty fractions between 2% and 90% were observed. The higher fractions correlate well with periods of few actual payloads being sent to the site.

  5. Analysis of hydraulic tests of the Culebra and Magenta Dolomites and Dewey Lake Redbeds conducted at the Waste Isolation Pilot Plant Site

    Energy Technology Data Exchange (ETDEWEB)

    Beauheim, R.L. [Sandia National Labs., Albuquerque, NM (United States). Geohydrology Dept.; Ruskauff, G.J. [Duke Engineering and Services, Inc., Albuquerque, NM (United States)

    1998-09-01

    This report presents interpretations of hydraulic tests conducted at 15 well locations in the vicinity of the Waste Isolation Pilot Plant (WIPP) in southeastern New Mexico between 1980 and 1996. The WIPP is a US Department of Energy (DOE) facility to demonstrate safe disposal of transuranic wastes arising form the nation`s defense programs. The WIPP repository lies within bedded halite of the Salado Formation, 2,155 ft below ground surface. The tests reported herein were, with two exceptions, conducted in the Culebra Dolomite member of the Rustler Formation, which overlies the Salado Formation. The remaining tests were conducted in the Magenta Member of the Rustler and in the overlying formation, the Dewey Lake Redbeds. This report completes the documentation of hydraulic-test interpretations used as input to the WIPP Compliance Certification Application (US DOE, 1996).

  6. Analysis of hydraulic tests of the Culebra and Magenta Dolomites and Dewey Lake Redbeds conducted at the Waste Isolation Pilot Plant Site

    International Nuclear Information System (INIS)

    Beauheim, R.L.

    1998-09-01

    This report presents interpretations of hydraulic tests conducted at 15 well locations in the vicinity of the Waste Isolation Pilot Plant (WIPP) in southeastern New Mexico between 1980 and 1996. The WIPP is a US Department of Energy (DOE) facility to demonstrate safe disposal of transuranic wastes arising form the nation's defense programs. The WIPP repository lies within bedded halite of the Salado Formation, 2,155 ft below ground surface. The tests reported herein were, with two exceptions, conducted in the Culebra Dolomite member of the Rustler Formation, which overlies the Salado Formation. The remaining tests were conducted in the Magenta Member of the Rustler and in the overlying formation, the Dewey Lake Redbeds. This report completes the documentation of hydraulic-test interpretations used as input to the WIPP Compliance Certification Application (US DOE, 1996)

  7. Faciliter l'échange de connaissances et tisser des liens au sein du ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Institution. Fundación Acción Social, Educación y Tiempo Libre, ESPLAI. Pays d' institution. Espagne. Site internet. http://www.fundacionesplai.org. Contenus connexes. Appui au réseautage et au renforcement des télécentres communautaires au Mali. En Afrique de l'Ouest francophone, les télécentres luttent pour atteindre ...

  8. Structure and Mobility of Metal Clusters in MOFs: Au, Pd, and AuPd Clusters in MOF-74

    DEFF Research Database (Denmark)

    Vilhelmsen, Lasse; Walton, Krista S.; Sholl, David S.

    2012-01-01

    is just as important for nanocluster adsorption as open Zn or Mg metal sites. Using the large number of clusters generated by the GA, we developed a systematic method for predicting the mobility of adsorbed clusters. Through the investigation of diffusion paths a relationship between the cluster......Understanding the adsorption and mobility of metal–organic framework (MOF)-supported metal nanoclusters is critical to the development of these catalytic materials. We present the first theoretical investigation of Au-, Pd-, and AuPd-supported clusters in a MOF, namely MOF-74. We combine density...... functional theory (DFT) calculations with a genetic algorithm (GA) to reliably predict the structure of the adsorbed clusters. This approach allows comparison of hundreds of adsorbed configurations for each cluster. From the investigation of Au8, Pd8, and Au4Pd4 we find that the organic part of the MOF...

  9. Rapid point-of-care CD4 testing at mobile HIV testing sites to increase linkage to care: an evaluation of a pilot program in South Africa.

    Science.gov (United States)

    Larson, Bruce A; Schnippel, Kathryn; Ndibongo, Buyiswa; Xulu, Thembisile; Brennan, Alana; Long, Lawrence; Fox, Matthew P; Rosen, Sydney

    2012-10-01

    A mobile HIV counseling and testing (HCT) program around Johannesburg piloted the integration of point-of-care (POC) CD4 testing, using the Pima analyzer, to improve linkages to HIV care. We report results from this pilot program for patients testing positive (n = 508) from May to October 2010. We analyzed 3 primary outcomes: assignment to testing group (offered POC CD4 or not), successful follow-up (by telephone), and completed the referral visit for HIV care within 8 weeks after HIV testing if successfully followed up. Proportions for each outcome were calculated, and relative risks were estimated using a modified Poisson approach. Three hundred eleven patients were offered the POC CD4 test, and 197 patients were not offered the test. No differences in patient characteristics were observed between the 2 groups. Approximately 62.7% of patients were successfully followed up 8 weeks after HIV testing, with no differences observed between testing groups. Among those followed up, 54.4% reported completing their referral visit. Patients offered the POC CD4 test were more likely to complete the referral visit for further HIV care (relative risk 1.25, 95% confidence interval: 1.00 to 1.57). In this mobile HCT setting, patients offered POC CD4 testing as part of the HCT services were more likely to visit a referral clinic after testing, suggesting that rapid CD4 testing technology may improve linkage to HIV care. Future research can evaluate options for adjusting HCT services if POC CD4 testing was included permanently and the cost-effectiveness of the POC CD4 testing compared with other approaches for improving linkage of care.

  10. Analysis of empty ATLAS pilot jobs

    CERN Document Server

    Love, Peter; The ATLAS collaboration

    2016-01-01

    The pilot model used by the ATLAS production system has been in use for many years. The model has proven to be a success with many advantages over push models. However one of the negative side-effects of using a pilot model is the presence of 'empty pilots' running on sites which consume a small amount of walltime and not running a useful payload job. The impact on a site can be significant with previous studies showing a total 0.5% walltime usage with no benefit to either the site or to ATLAS. Another impact is the number of empty pilots being processed by a site's Compute Element and batch system which can be 5% of the total number of pilots being handled. In this paper we review the latest statistics using both ATLAS and site data and highlight edge cases where the number of empty pilots dominate. We also study the effect of tuning the pilot factories to reduce the number of empty pilots.

  11. Hydrogen evolution on Au(111) covered with submonolayers of Pd

    DEFF Research Database (Denmark)

    Björketun, Mårten; Karlberg, Gustav; Rossmeisl, Jan

    2011-01-01

    A theoretical investigation of electrochemical hydrogen evolution on Au(111) covered with submonolayers of Pd is presented. The size and shape of monoatomically high Pd islands formed on the Au(111) surface are determined using Monte Carlo simulations, for Pd coverages varying from 0.02 to 0.95 ML....... The energetics of adsorption and desorption of hydrogen on/from different types of sites on the Pd-Au(111) surface are assessed by means of density functional theory calculations combined with thermodynamic modeling. Based on the density functional and Monte Carlo data, the hydrogen evolution activity...... is evaluated with a micro-kinetic model. The analysis reproduces measured Pd-coverage-dependent activities for Pd submonolayers exceeding similar to 0.15 ML and enables the relative contributions from different types of electrocatalytically active sites to be determined. Finally, the implications of surface...

  12. Different expression of MIB1 in primary site of non-Hodgkin lymphoma and its bone marrow deposits, a pilot study

    Directory of Open Access Journals (Sweden)

    Malysz J

    2017-02-01

    Full Text Available Jozef Malysz,1 Juanita J Evans,2 Malcolm Acon-Laws,3 Michael G Bayerl,1 Michael H Creer1 1Department of Pathology, Penn State Milton S Hershey Medical Center, Hershey, PA, 2Department of Pathology, St. John Heath – Providence, Southfield, MI, USA; 3Laboratorio de Patologia Hospital Cima, San Jose, Costa Rica Abstract: Evaluation of mindbomb E3 ubiquitin protein ligase 1 (MIB1 (Ki67 proliferation index (PI in B-cell non-Hodgkin lymphomas is increasingly a common addition to classification of lymphoma and staging procedures. Clinicians relay on PI as a surrogate marker of biologic activity; however, no established guidelines have been published whether PI at the primary site of the tumor gives the same answer as evaluation of tumor in staging marrow. In our study, dual immunohistochemical staining for MIB1 and CD20 was performed on tissue from primary site and bone marrow involved by B-cell non-Hodgkin lymphoma to compare PI for each individual patient. For all patients, MIB1 expression was higher at primary tumor site as compared to staging marrow. Additional analysis was performed to investigate the degree of difference depending on lymphoma morphology. Patients with large cell lymphoma at the primary site and large cell morphology in the marrow (LCL-L, those with large cell morphology at the primary site and small cell morphology in the marrow (LCL-S, and those with small cell morphology at the primary site and small cells in the marrow (SCL-S were compared. As expected, LCL cases had a higher mean PI at the primary site when compared to SCL cases (28.5% vs 2.8%, P=0.0001. In addition, the most significant difference between medullary and extramedullary PI was observed in cases with discordant morphology (LCL-S (21% vs 1.1%, P=0.009. Our results indicate that PI of lymphoma within the bone marrow should not be used as a surrogate prognostic indicator of lymphoma biology in its primary site. Keywords: proliferation index, biologic behavior

  13. Preparation of Au nanosheets supported on Ni foam and its electrocatalytic performance towards NaBH4 oxidation

    International Nuclear Information System (INIS)

    Yang, Fan; Cheng, Kui; Wang, Guiling; Cao, Dianxue

    2015-01-01

    Highlights: • The unique Au nanosheets are electrodeposited uniformly on Ni foam substrate. • Au NSs/Ni foam electrode shows high catalytic activity for NaBH 4 electrooxidation. • The surface of a single Au sheet is consisted of many nano-scale corrugations. - Abstract: The unique Au nanosheets (Au NSs) are electrodeposited uniformly on Ni foam substrate via a one-step potentiostatic electrodeposition technique. The electrode is characterized by scanning electron microscopy equipped with energy dispersive X-ray spectrometer and X-ray diffractometer. It shows a unique open structure allowing the full utilization of Au surface active sites. NaBH 4 electrooxidation in KOH solution on the Au NSs/Ni foam electrode are studied by linear sweep voltammetry and chronoamperometry. The electrode exhibits a high catalytic performance outperforming the Au particles made by the same method. At the oxidation potential of 0 V, the current density of 827 mA cm −2 can be achieved on Au NSs/Ni foam electrode, and only 219 mA cm −2 was obtained on Au NPs/Ni foam electrode, indicating that the catalytic activity is increased by 278%, which is attributed to the porous 3D structure, ensuring the full utilization of Au surfaces. Besides, H 2 generated by NaBH 4 hydrolysis can quickly diffuse away from the electrode, preventing surface active sites of Au from blocking by adsorbed gas bubbles

  14. Recruitment methods and costs for a randomized, placebo-controlled trial of chiropractic care for lumbar spinal stenosis: a single-site pilot study.

    Science.gov (United States)

    Cambron, Jerrilyn A; Dexheimer, Jennifer M; Chang, Mabel; Cramer, Gregory D

    2010-01-01

    The purpose of this article is to describe the methods for recruitment in a clinical trial on chiropractic care for lumbar spinal stenosis. This randomized, placebo-controlled pilot study investigated the efficacy of different amounts of total treatment dosage over 6 weeks in 60 volunteer subjects with lumbar spinal stenosis. Subjects were recruited for this study through several media venues, focusing on successful and cost-effective strategies. Included in our efforts were radio advertising, newspaper advertising, direct mail, and various other low-cost initiatives. Of the 1211 telephone screens, 60 responders (5.0%) were randomized into the study. The most successful recruitment method was radio advertising, generating more than 64% of the calls (776 subjects). Newspaper and magazine advertising generated approximately 9% of all calls (108 subjects), and direct mail generated less than 7% (79 subjects). The total direct cost for recruitment was $40 740 or $679 per randomized patient. The costs per randomization were highest for direct mail ($995 per randomization) and lowest for newspaper/magazine advertising ($558 per randomization). Success of recruitment methods may vary based on target population and location. Planning of recruitment efforts is essential to the success of any clinical trial. Copyright 2010 National University of Health Sciences. Published by Mosby, Inc. All rights reserved.

  15. Multifragmentation in Au + Au collisions studied with AMD-V

    Energy Technology Data Exchange (ETDEWEB)

    Ono, Akira [Tohoku Univ., Sendai (Japan). Faculty of Science

    1998-07-01

    AMD-V is an optimum model for calculation of multifragmentation in Au + Au collisions. AMD-V consider anti-symmetry of incident nucleus, target nucleus and fragments, furthermore, it treat the quantum effect to exist many channels in the intermediate and final state. 150 and 250 MeV/nucleon incident energy were used in the experiments. The data of multifragment atom in {sup 197}Au + {sup 197}Au collisions was reproduced by AMD-V calculation using Gognny force, corresponding to the imcompressibility of nuclear substance K = 228 MeV and its mean field depend on momentum. When other interaction (SKG 2 force, corresponding to K = 373 KeV) was used an mean field does not depend on momentum, the calculation results could not reproduce the experimental values, because nucleus and deuteron were estimated too large and {alpha}-particle and intermediate fragments estimated too small. (S.Y.)

  16. Transverse expansion in 197 Au + 197 Au collisions at RHIC

    International Nuclear Information System (INIS)

    Cheng, Y.; Liu, F.; Liu, K.; Schweda, K.; Xu, N.

    2003-01-01

    Using the RQMD model, transverse momentum distributions and particle ratios are studied for 197 Au + 197 Au collisions at √s NN = 200 GeV. In particular, they present results on the mean transverse momentum of charged pions, charged kaons, protons and anti-protons and compare with experimental measurements. They discuss an approach to study early partonic collectivity in high energy nuclear collisions

  17. Face au risque

    CERN Document Server

    Grosse, Christian; November, Valérie

    2007-01-01

    Ce volume collectif sur le risque inaugure la collection L'ÉQUINOXE. Ancré dans l'histoire pour mesurer les continuités et les ruptures, il illustre la manière dont les sciences humaines évaluent et mesurent les enjeux collectifs du risque sur les plans politiques, scientifiques, énergétiques, juridiques et éthiques. Puisse-t-il nourrir la réflexion sur la culture et la prévention du risque. Ses formes épidémiques, écologiques, sociales, terroristes et militaires nourrissent les peurs actuelles, structurent les projets sécuritaires et constituent - sans doute - les défis majeurs à notre modernité. Dans la foulée de la richesse scientifique d'Equinoxe, L'ÉQUINOXE hérite de son esprit en prenant à son tour le pari de contribuer - non sans risque - à enrichir en Suisse romande et ailleurs le champ éditorial des sciences humaines dont notre société a besoin pour forger ses repères. Après Face au risque suivra cet automne Du sens des Lumières. (MICHEL PORRET Professeur Ordinaire à la F...

  18. Amperometric Immunosensor for Carbofuran Detection Based on MWCNTs/GS-PEI-Au and AuNPs-Antibody Conjugate

    Directory of Open Access Journals (Sweden)

    Xiangyou Wang

    2013-04-01

    Full Text Available In this paper, an amperometric immunosensor for the detection of carbofuran was developed. Firstly, multiwall carbon nanotubes (MWCNTs and graphene sheets-ethyleneimine polymer-Au (GS-PEI-Au nanocomposites were modified onto the surface of a glass carbon electrode (GCE via self-assembly. The nanocomposites can increase the surface area of the GCE to capture a large amount of antibody, as well as produce a synergistic effect in the electrochemical performance. Then the modified electrode was coated with gold nanoparticles-antibody conjugate (AuNPs-Ab and blocked with BSA. The monoclonal antibody against carbofuran was covalently immobilized on the AuNPs with glutathione as a spacer arm. The morphologies of the GS-PEI-Au nanocomposites and the fabrication process of the immunosensor were characterized by X-ray diffraction (XRD, ultraviolet and visible absorption spectroscopy (UV-vis and scanning electron microscopy (SEM, respectively. Under optimal conditions, the immunosensor showed a wide linear range, from 0.5 to 500 ng/mL, with a detection limit of 0.03 ng/mL (S/N = 3. The as-constructed immunosensor exhibited notable performance features such as high specificity, good reproducibility, acceptable stability and regeneration performance. The results are mainly due to the excellent properties of MWCNTs, GS-PEI-Au nanocomposites and the covalent immobilization of Ab with free hapten binding sites for further immunoreaction. It provides a new avenue for amperometric immunosensor fabrication.

  19. INTRAVAL Phase 2 WIPP 1 test case report: Modeling of brine flow through halite at the Waste Isolation Pilot Plant site

    International Nuclear Information System (INIS)

    Beauheim, R.L.

    1997-05-01

    This report describes the WIPP 1 test case studied as part of INTRAVAL, an international project to study validation of geosphere transport models. The WIPP 1 test case involved simulation of measured brine-inflow rates to boreholes drilled into the halite strata surrounding the Waste Isolation Pilot Plant repository. The goal of the test case was to evaluate the use of Darcy's law to describe brine flow through halite. The general approach taken was to try to obtain values of permeability and specific capacitance that would be: (1) consistent with other available data and (2) able to provide reasonable simulations of all of the brine-inflow experiments performed in the Salado Formation. All of the teams concluded that the average permeability of the halite strata penetrated by the holes was between approximately 10 -22 and 10 -21 m 2 . Specific capacitances greater than 10 -10 Pa -1 are inconsistent with the known constitutive properties of halite and are attributed to deformation, possibly ongoing, of the halite around the WIPP excavations. All project teams found that Darcy-flow models could replicate the experimental data in a consistent and reasonable manner. Discrepancies between the data and simulations are attributed to inadequate representation in the models of processes modifying the pore-pressure field in addition to the experiments themselves, such as ongoing deformation of the rock around the excavations. Therefore, the conclusion from the test case is that Darcy-flow models can reliably be used to predict brine flow to WIPP excavations, provided that the flow modeling is coupled with measurement and realistic modeling of the pore-pressure field around the excavations. This realistic modeling of the pore-pressure field would probably require coupling to a geomechanical model of the stress evolution around the repository

  20. Assessment of technologies for hazardous waste site remediation: Non-treatment technologies and pilot scale facility implementation -- excavation -- storage technology -- safety analysis and review statement. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, H.R.; Overbey, W.K. Jr.; Koperna, G.J. Jr.

    1994-02-01

    The purpose of this study is to assess the state-of-the-art of excavation technology as related to environmental remediation applications. A further purpose is to determine which of the excavation technologies reviewed could be used by the US Corp of Engineers in remediating contaminated soil to be excavated in the near future for construction of a new Lock and Dam at Winfield, WV. The study is designed to identify excavation methodologies and equipment which can be used at any environmental remediation site but more specifically at the Winfield site on the Kanawha River in Putnam County, West Virginia. A technical approach was determined whereby a functional analysis was prepared to determine the functions to be conducted during the excavation phase of the remediation operations. A number of excavation technologies were identified from the literature. A set of screening criteria was developed that would examine the utility and ranking of the technologies with respect to the operations that needed to be conducted at the Winfield site. These criteria were performance, reliability, implementability, environmental safety, public health, and legal and regulatory compliance. The Loose Bulk excavation technology was ranked as the best technology applicable to the Winfield site. The literature was also examined to determine the success of various methods of controlling fugitive dust. Depending upon any changes in the results of chemical analyses, or prior remediation of the VOCs from the vadose zone, consideration should be given to testing a new ``Pneumatic Excavator`` which removes the VOCs liberated during the excavation process as they outgas from the soil. This equipment however would not be needed on locations with low levels of VOC emissions.

  1. Improving the Quality of Voluntary Medical Male Circumcision through Use of the Continuous Quality Improvement Approach: A Pilot in 30 PEPFAR-Supported Sites in Uganda

    Science.gov (United States)

    Opio, Alex; Calnan, Jacqueline; Njeuhmeli, Emmanuel

    2015-01-01

    Background Uganda adopted voluntary medical male circumcision (VMMC) (also called Safe Male Circumcision in Uganda), as part of its HIV prevention strategy in 2010. Since then, the Ministry of Health (MOH) has implemented VMMC mostly with support from the United States President’s Emergency Plan for AIDS Relief (PEPFAR) through its partners. In 2012, two PEPFAR-led external quality assessments evaluated compliance of service delivery sites with minimum quality standards. Quality gaps were identified, including lack of standardized forms or registers, lack of documentation of client consent, poor preparedness for emergencies and use of untrained service providers. In response, PEPFAR, through a USAID-supported technical assistance project, provided support in quality improvement to the MOH and implementing partners to improve quality and safety in VMMC services and build capacity of MOH staff to continuously improve VMMC service quality. Methods and Findings Sites were supported to identify barriers in achieving national standards, identify possible solutions to overcome the barriers and carry out improvement plans to test these changes, while collecting performance data to objectively measure whether they had bridged gaps. A 53-indicator quality assessment tool was used by teams as a management tool to measure progress; teams also measured client-level indicators through self-assessment of client records. At baseline (February-March 2013), less than 20 percent of sites scored in the “good” range (>80%) for supplies and equipment, patient counseling and surgical procedure; by November 2013, the proportion of sites scoring “good” rose to 67 percent, 93 percent and 90 percent, respectively. Significant improvement was noted in post-operative follow-up at 48 hours, sexually transmitted infection assessment, informed consent and use of local anesthesia but not rate of adverse events. Conclusion Public sector providers can be engaged to address the quality of

  2. Assessment of technologies for hazardous waste site remediation: Non-treatment technologies and pilot scale facility implementation -- excavation -- storage technology -- safety analysis and review statement

    International Nuclear Information System (INIS)

    Johnson, H.R.; Overbey, W.K. Jr.; Koperna, G.J. Jr.

    1994-02-01

    The purpose of this study is to assess the state-of-the-art of excavation technology as related to environmental remediation applications. A further purpose is to determine which of the excavation technologies reviewed could be used by the US Corp of Engineers in remediating contaminated soil to be excavated in the near future for construction of a new Lock and Dam at Winfield, WV. The study is designed to identify excavation methodologies and equipment which can be used at any environmental remediation site but more specifically at the Winfield site on the Kanawha River in Putnam County, West Virginia. A technical approach was determined whereby a functional analysis was prepared to determine the functions to be conducted during the excavation phase of the remediation operations. A number of excavation technologies were identified from the literature. A set of screening criteria was developed that would examine the utility and ranking of the technologies with respect to the operations that needed to be conducted at the Winfield site. These criteria were performance, reliability, implementability, environmental safety, public health, and legal and regulatory compliance. The Loose Bulk excavation technology was ranked as the best technology applicable to the Winfield site. The literature was also examined to determine the success of various methods of controlling fugitive dust. Depending upon any changes in the results of chemical analyses, or prior remediation of the VOCs from the vadose zone, consideration should be given to testing a new ''Pneumatic Excavator'' which removes the VOCs liberated during the excavation process as they outgas from the soil. This equipment however would not be needed on locations with low levels of VOC emissions

  3. Improving the Quality of Voluntary Medical Male Circumcision through Use of the Continuous Quality Improvement Approach: A Pilot in 30 PEPFAR-Supported Sites in Uganda.

    Science.gov (United States)

    Byabagambi, John; Marks, Pamela; Megere, Humphrey; Karamagi, Esther; Byakika, Sarah; Opio, Alex; Calnan, Jacqueline; Njeuhmeli, Emmanuel

    2015-01-01

    Uganda adopted voluntary medical male circumcision (VMMC) (also called Safe Male Circumcision in Uganda), as part of its HIV prevention strategy in 2010. Since then, the Ministry of Health (MOH) has implemented VMMC mostly with support from the United States President's Emergency Plan for AIDS Relief (PEPFAR) through its partners. In 2012, two PEPFAR-led external quality assessments evaluated compliance of service delivery sites with minimum quality standards. Quality gaps were identified, including lack of standardized forms or registers, lack of documentation of client consent, poor preparedness for emergencies and use of untrained service providers. In response, PEPFAR, through a USAID-supported technical assistance project, provided support in quality improvement to the MOH and implementing partners to improve quality and safety in VMMC services and build capacity of MOH staff to continuously improve VMMC service quality. Sites were supported to identify barriers in achieving national standards, identify possible solutions to overcome the barriers and carry out improvement plans to test these changes, while collecting performance data to objectively measure whether they had bridged gaps. A 53-indicator quality assessment tool was used by teams as a management tool to measure progress; teams also measured client-level indicators through self-assessment of client records. At baseline (February-March 2013), less than 20 percent of sites scored in the "good" range (>80%) for supplies and equipment, patient counseling and surgical procedure; by November 2013, the proportion of sites scoring "good" rose to 67 percent, 93 percent and 90 percent, respectively. Significant improvement was noted in post-operative follow-up at 48 hours, sexually transmitted infection assessment, informed consent and use of local anesthesia but not rate of adverse events. Public sector providers can be engaged to address the quality of VMMC using a continuous quality improvement approach.

  4. Au/ZnO nanocomposites: Facile fabrication and enhanced photocatalytic activity for degradation of benzene

    International Nuclear Information System (INIS)

    Yu, Hang; Ming, Hai; Zhang, Hengchao; Li, Haitao; Pan, Keming; Liu, Yang; Wang, Fang; Gong, Jingjing; Kang, Zhenhui

    2012-01-01

    Au nanoparticles supported on highly uniform one-dimensional ZnO nanowires (Au/ZnO hybrids) have been successfully fabricated through a simple wet chemical method, which were first used for photodegradation of gas-phase benzene. Compared with bare ZnO nanowires, the as-prepared Au/ZnO hybrids were found to possess higher photocatalytic activity for degradation of benzene under UV and visible light (degradation efficiencies reach about 56.0% and 33.7% after 24 h under UV and visible light irradiation, respectively). Depending on excitation happening on ZnO semiconductor or on the surface plasmon band of Au, the efficiency and operating mechanism are different. Under UV light irradiation, Au nanoparticles serve as an electron buffer and ZnO nanowires act as the reactive sites for benzene degradation. When visible light is used as the light irradiation source, Au nanoparticles act as the light harvesters and photocatalytic sites alongside of charge-transfer process, simultaneously. -- Graphical abstract: Under visible light irradiation, Au nanoparticles, which are supported on ZnO nanowires, dominate their catalytic properties in gas-phase degradation benzene reaction. Highlights: ► The composites that Au nanoparticles supported on ZnO nanowires were synthesized. ► Au/ZnO composites were firstly used as effective photocatalysts for benzene degradation. ► Two operating mechanisms were proposed depending on excitation wavelength.

  5. Alginate dressing and polyurethane film versus paraffin gauze in the treatment of split-thickness skin graft donor sites: a randomized controlled pilot study.

    Science.gov (United States)

    Kaiser, Dominik; Hafner, Jürg; Mayer, Dieter; French, Lars E; Läuchli, Severin

    2013-02-01

    To compare postoperative healing of split-thickness skin graft (STSG) donor sites using traditional dressings (paraffin gauze) or modern wound dressings (alginate dressing and polyurethane film) in a randomized controlled trial. Thirty patients were randomly assigned to treatment of an STSG donor site with an alginate dressing and a polyurethane film or nonadherent paraffin gauze. Outcome variables were pain (measured with a visual analog scale), amount of dressing changes, healing time, cosmetic outcome, treatment costs, and overall satisfaction with the procedure. There was no significant difference in pain (postoperative day 1: 2.1 vs 1.2, P = .26; postoperative days 5-7: 1.0 vs 0.9, P = .47; final removal: 1.9 vs 1.0, P = .19) and time to healing (18.1 vs 15.4 days, P = .29) between alginate/polyurethane film dressing and nonadherent paraffin gauze. The semiocclusive dressings with polyurethane film required multiple dressing changes, whereas the nonadherent paraffin gauze could be left in place until complete epithelialization. Treatment costs were substantially lower for paraffin gauze. Semiocclusive dressings with alginate dressings and polyurethane film showed no advantages over treatment with paraffin gauze. With lower costs and better patient acceptance, paraffin gauze dressings were the preferred treatment for STSG donor sites.

  6. Film thickness degradation of Au/GaN Schottky contact characteristics

    International Nuclear Information System (INIS)

    Wang, K.; Wang, R.X.; Fung, S.; Beling, C.D.; Chen, X.D.; Huang, Y.; Li, S.; Xu, S.J.; Gong, M.

    2005-01-01

    Electrical characteristics of Au/n-GaN Schottky contacts with different Au film thicknesses up to 1300 A, have been investigated using current-voltage (I-V) and capacitance-voltage (C-V) techniques. Results show a steady decrease in the quality of the Schottky diodes for increasing Au film thickness. I-V measurements indicate that thin ( 500 A). Depth profiling Auger electron spectroscopy (AES) shows that the width of the Au/GaN junction interface increases with increasing Au thickness, suggesting considerable inter-mixing of Au, Ga and N. The results have been interpreted in terms of Ga out-diffusion from the GaN giving rise to gallium vacancies that in turn act as sites for electron-hole pair generation within the depletion region. The study supports the recent suggestion that gallium vacancies associated with threaded dislocations are playing an important role in junction breakdown

  7. Photoluminescence enhancement in few-layer WS2 films via Au nanoparticles

    Directory of Open Access Journals (Sweden)

    Sin Yuk Choi

    2015-06-01

    Full Text Available Nano-composites of two-dimensional atomic layered WS2 and Au nanoparticles (AuNPs have been fabricated by sulfurization of sputtered W films followed by immersing into HAuCl4 aqueous solution. The morphology, structure and AuNPs distribution have been characterized by electron microscopy. The decorated AuNPs can be more densely formed on the edge and defective sites of triangle WS2. We have compared the optical absorption and photoluminescence of bare WS2 and Au-decorated WS2 layers. Enhancement in the photoluminescence is observed in the Au-WS2 nano-composites, attributed to localized surface plasmonic effect. This work provides the possibility to develop photonic application in two-dimensional materials.

  8. Spin-polarized ballistic conduction through correlated Au-NiMnSb-Au heterostructures

    KAUST Repository

    Morari, C.

    2017-11-20

    We examine the ballistic conduction through Au-NiMnSb-Au heterostructures consisting of up to four units of the half-metallic NiMnSb in the scattering region, using density functional theory (DFT) methods. For a single NiMnSb unit the transmission function displays a spin polarization of around 50% in a window of 1eV centered around the Fermi level. By increasing the number of layers, an almost complete spin polarization of the transmission is obtained in this energy range. Supplementing the DFT calculations with local electronic interactions, of Hubbard-type on the Mn sites, leads to a hybridization between the interface and many-body states. The significant reduction of the spin polarization seen in the density of states is not apparent in the spin polarization of the conduction electron transmission, which suggests that the hybridized interface and many-body induced states are localized.

  9. 4D Joint Stratigraphic Inversion of Prestack Seismic Data: Application to the CO2 Storage Reservoir (Utsira Sand Formation at Sleipner Site Inversion stratigraphique jointe 4D de données sismiques avant sommation : application au réservoir de stockage de CO2 (Formation Utsira du site de Sleipner

    Directory of Open Access Journals (Sweden)

    Labat K.

    2012-04-01

    éservoirs au cours de leur production. Nous présentons ici une méthodologie d'inversion stratigraphique 4D qui fournit une estimation des variations d'impédances des ondes P et S dans le réservoir, par inversion de données de sismiques répétées avant-sommation. L'inversion 4D est implémentée dans le domaine temps et nécessite une loi de mise à l'échelle des temps de trajets pour chaque jeu de données de sismique répétée (aussi appelé "millésime" afin de mettre en correspondance les temps d'arrivée d'événements homologues observés sur les jeux de données appelés référence et monitors. Cette opération est souvent appelée "warping". L'inversion 4D est une méthodologie qui comporte trois étapes : la première étape consiste à inverser chaque millésime sismique séparément, pour produire autant de distributions en impédances P et S que de jeux de données considérés. La seconde étape utilise l'information des impédances P disponibles pour résoudre le problème du warping, qui est un point clé pour la troisième et dernière étape : l'inversion jointe de tous les millésimes sismiques disponibles. Cette séquence d'inversion 4D a été appliquée aux jeux de données enregistrés sur le réservoir de stockage de CO2 du site norvégien de Sleipner (Mer du Nord. Ce dernier est devenu un site industriel de référence pour le stockage à long terme du dioxyde de carbone (CO2 dans un aquifère salin, la formation des sables de l'Utsira. Nous avons focalisé notre étude sur l'inversion 4D des millésimes 1994 et 2006, acquise respectivement avant et dix ans après le début de l'injection de CO2. Le warping a fourni une loi de mise à l'échelle des temps de propagation avec un retard maximum d'environ 45 ms à la base de l'aquifère Utsira. L'inversion 4D jointe a donné des résultats plus cohérents que les inversions 3D : l'inversion 4D fournit en particulier des impédances P pour les grès saturés en CO2 qui sont très proches des

  10. Effect of tautomerism on Au-6-mercaptopurine nanocluster stability

    Science.gov (United States)

    Rashidpour, Neda; Kashid, Vikas; Shah, Vaishali

    2013-02-01

    We have investigated the stability of conjugated nanoparticles of Au-6-Mercaptopurine (6-MP) using ab initio density functional theory. We have studied the conjugation of the 6 tautomers of 6-MP via the different atomic sites with the gold nanoparticles. Our results show that the least stable tautomer has the strongest adsorption with the Au nanoparticles whereas the most stable tautomer has the weakest adsorption. We will discuss our results to explain the experimentally observed increased plasma half life time of the conjugated drug in vitro.

  11. Green synthesis and characterization of Au@Pt core-shell bimetallic nanoparticles using gallic acid

    Science.gov (United States)

    Zhang, Guojun; Zheng, Hongmei; Shen, Ming; Wang, Lei; Wang, Xiaosan

    2015-06-01

    In this study, we developed a facile and benign green synthesis approach for the successful fabrication of well-dispersed urchin-like Au@Pt core-shell nanoparticles (NPs) using gallic acid (GA) as both a reducing and protecting agent. The proposed one-step synthesis exploits the differences in the reduction potentials of AuCl4- and PtCl62-, where the AuCl4- ions are preferentially reduced to Au cores and the PtCl62- ions are then deposited continuously onto the Au core surface as a Pt shell. The as-prepared Au@Pt NPs were characterized by transmission electron microscope (TEM); high-resolution transmission electron microscope (HR-TEM); scanning electron microscope (SEM); UV-vis absorption spectra (UV-vis); X-ray diffraction (XRD); Fourier transmission infrared spectra (FT-IR). We systematically investigated the effects of some experimental parameters on the formation of the Au@Pt NPs, i.e., the reaction temperature, the molar ratios of HAuCl4/H2PtCl6, and the amount of GA. When polyvinylpyrrolidone K-30 (PVP) was used as a protecting agent, the Au@Pt core-shell NPs obtained using this green synthesis method were better dispersed and smaller in size. The as-prepared Au@Pt NPs exhibited better catalytic activity in the reaction where NaBH4 reduced p-nitrophenol to p-aminophenol. However, the results showed that the Au@Pt bimetallic NPs had a lower catalytic activity than the pure Au NPs obtained by the same method, which confirmed the formation of Au@Pt core-shell nanostructures because the active sites on the surfaces of the Au NPs were covered with a Pt shell.

  12. A pilot study on health risk assessment based on body loadings of PCBs of lactating mothers at Taizhou, China, the world's major site for recycling transformers

    International Nuclear Information System (INIS)

    Man, Yu Bon; Chow, Ka Lai; Xing, Guan Hua; Chan, Janet Kit Yan; Wu, Sheng Chun; Wong, Ming Hung

    2017-01-01

    Our early study reported an extraordinarily high Estimated Daily Intake (EDI) of PCBs of lactating mothers from Taizhou, Zhejiang Province, China (based on a food consumption survey and food basket analysis). The EDI well exceeded the intake limit stipulated by FAO/WHO 70 pg TEQ/kg body weight (bw)/month. The present pilot study provided further information on PCBs body burden in lactating mothers of Taizhou. The total PCBs detected in human milk, placenta and hair samples of these lactating mothers were 363 ng/g lipid, 224 ng/g lipid, and 386 ng/g dry wt. Respectively, three times higher than those samples collected from the reference site (Lin'an). Compared with the previous reported values in the 3rd WHO coordinated study, Taizhou topped the list of 32 countries/regions with regards to WHO-PCB-TEQ values of milk samples, which could be attributed to the relatively higher level of PCB-126 derived from electronic waste. In addition, the corresponding EDI of PCBs of Taizhou mothers (12.9 pg WHO-PCB-TEQ/kg bw/day) and infants (438 pg WHO-PCB-TEQ/kg) were derived from individual congener levels in human milk. The results were also higher than the tolerable daily intakes recommended by WHO (1–4 pg WHO-TEQ/kg bw/day) by 3 and 110 times, for mothers and infants, respectively. A more intensive epidemiological study on the potential health effects of e-waste recycling activities affecting both workers and residents seems to be of top priority, based on findings of this pilot study. - Highlights: • Highest TEQ detected in human milk (Taizhou) amongst other countries or cities. • Highest PCB detected in placenta/hair samples (Taizhou & Li'an) amongst worldwide. • E-waste workers/residents in Taizhou had high levels of PCBs in body tissues. - The present results showed that human exposure to high levels of PCBs in this intensive e-waste processing site is of high public health concern, especially workers and residents living in the vicinity.

  13. Pilot Greenhouse

    CERN Multimedia

    1983-01-01

    This pilot greenhouse was built in collaboration with the "Association des Maraichers" of Geneva in the frame of the study for making use of the heat rejected as warm water by CERN accelerators and experiments. Among other improvements, more automated and precise regulation systems for heating and ventilation were developed. See also 8305598X.

  14. Cost-effectiveness analysis alongside a pilot study of prophylactic negative pressure wound therapy.

    Science.gov (United States)

    Heard, Christopher; Chaboyer, Wendy; Anderson, Vinah; Gillespie, Brigid M; Whitty, Jennifer A

    2017-02-01

    Negative pressure wound therapy (NPWT) is increasingly used prophylactically following surgery despite limited evidence of clinical or cost-effectiveness. To evaluate whether NPWT is cost-effective compared to standard care, for the prevention of surgical site infection (SSI) in obese women undergoing elective caesarean section, and inform development of a larger trial. An economic evaluation was conducted alongside a pilot randomised controlled trial at one Australian hospital, in which women were randomised to NPWT (n = 44) or standard care (n = 43). A public health care provider perspective and time horizon to four weeks post-discharge was adopted. Cost-effectiveness assessment was based on incremental cost per SSI prevented and per quality-adjusted life year (QALY) gained. Patients receiving NPWT each received health care costing AU$5887 (±1038) and reported 0.069 (±0.010) QALYs compared to AU$5754 (±1484) and 0.066 (±0.010) QALYs for patients receiving standard care. NPWT may be slightly more costly and more effective than standard care, with estimated incremental cost-effectiveness ratios (ICERs) of AU$1347 (95%CI dominant- $41,873) per SSI prevented and AU$42,340 (95%CI dominant- $884,019) per QALY gained. However, there was considerable uncertainty around these estimates. NPWT may be cost-effective in the prophylactic treatment of surgical wounds following elective caesarean section in obese women. Larger trials could clarify the cost-effectiveness of NPWT as a prophylactic treatment for SSI. Sensitive capture of QALYs and cost offsets will be important given the high level of uncertainty around the point estimate cost-effectiveness ratio which was close to conventional thresholds. ACTRN12612000171819. Copyright © 2016 Tissue Viability Society. Published by Elsevier Ltd. All rights reserved.

  15. Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL

    International Nuclear Information System (INIS)

    Spalding, B.P.; Jacobs, G.K.; Naney, M.T.; Dunbar, N.W.; Tixier, J.S.; Powell, T.D.

    1992-11-01

    A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were 137 Cs and 90 Sr, with lesser amounts of 6O Co, 241 Am, and 239,240 Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the 137 Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of 90 Sr, 241 Am, or 239,240 Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500 degrees C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms

  16. Bienvenue au CERN !

    CERN Multimedia

    CERN Press Office. Geneva

    1998-01-01

    CERN, the Laboratory which invented the World-Wide Web has re-invented its public Web site. The new face of CERN has gone live at http://www.cern.ch/ Public . CERN's new Web pages have been designed to give visitors an informative introduction to the fascinating world of particle physics. For those whose whirl around the Web only allows a short stop, there's the 'CERN in two minutes' page.

  17. Growth model of Au films on Ru(001)

    International Nuclear Information System (INIS)

    Canessa, E.; Calmetta, A.

    1992-06-01

    In an attempt to find generic features on the fractal growth of Au films deposited on Ru(001), a simple simulation model based on irreversible diffusion-limited aggregation (DLA) is discussed. Highly irregular two-dimensional dentritic islands of Au particles that gradually grow on a larger host lattice of Ru particles and have fractal dimension d f approx. 1.70 each, are generated via a multiple had-hoc version of the DLA algorithm for single aggregates. Annealing effects on the islands morphology are reproduced assuming different sticking probabilities at nearest-neighbour lattice sites of Au films on Ru(001). Using simulation data, islands growth are described in analogy to diffusion-limited, precipitate growth with soft impingement of precipities. This leads to analyse thin film island growth kinetics in such fractal systems and to predict a main peak in scattering intensity patterns due to interisland interference. (author). 12 refs, 4 figs

  18. L’apprentissage au cern

    CERN Multimedia

    2007-01-01

    pour les professions d’électronicien(ne) et de laborantin(e) en physique L’apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le canton de Genève. En cas de réussite à l’examen de fin d’apprentissage, les apprentis obtiennent le Certificat fédéral de capacité suisse (CFC). 6 places au total sont ouvertes au recrutement pour les deux professions. L’apprentissage dure 4 ans. Minima requis pour faire acte de candidature : avoir au moins 15 ans et moins de 21 ans à la date de début de l’apprentissage ; avoir terminé la scolarité obligatoire, au minimum 9e du Cycle d’orientation genevois (3e en France) ; être ressortissant d’un pays membre du CERN (Allemagne, Autriche, Belgique, Bulgarie, Danemark, Espagne, Finlande, France, Grèce, Hongrie, Italie, Norvège, Pays-Bas, Pologne, Portugal, Royaume-Uni, République tchèque, République slovaque , Suède, Suisse) ; pour les résidents en Suisse : être ressortissant su...

  19. Transverse velocity scaling in 197Au+197Au fragmentation

    International Nuclear Information System (INIS)

    Lukasik, J.; Hudan, S.; Lavaud, F.

    2002-07-01

    Invariant transverse-velocity spectra of intermediate-mass fragments were measured with the 4π multi-detector system INDRA for collisions of 197 Au on 197 Au at incident energies between 40 and 150 MeV per nucleon. Their scaling properties as a function of incident energy and atomic number Z are used to distinguish and characterize the emissions in (i) peripheral collisions at the projectile and target rapidities, and in (ii) central and (iii) peripheral collisions near mid-rapidity. The importance of dynamical effects is evident in all three cases and their origin is discussed. (orig.)

  20. Flow in Au+Au collisions at RHIC

    Science.gov (United States)

    Belt Tonjes, Marguerite; the PHOBOS Collaboration; Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tang, J.-L.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wolfs, F. L. H.; Wosiek, B.; Wozniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2004-08-01

    The study of flow can provide information on the initial state dynamics and the degree of equilibration attained in heavy-ion collisions. This contribution presents results for both elliptic and directed flow as determined from data recorded by the PHOBOS experiment in Au+Au runs at RHIC at \\sqrt{sNN} = 19.6, 130 and 200 GeV. The PHOBOS detector provides a unique coverage in pseudorapidity for measuring flow at RHIC. The systematic dependence of flow on pseudorapidity, transverse momentum, centrality and energy is discussed.

  1. Bimetallic Au-decorated Pd catalyst for the liquid phase hydrodechlorination of 2,4-dichlorophenol

    International Nuclear Information System (INIS)

    Zhou, Juan; Chen, Huan; Chen, Quanyuan; Huang, Zhaolu

    2016-01-01

    Graphical abstract: 2,4-Dichlorophenol can be converted to phenol via the catalytic HDC method over Pd-Au/CNTs and the catalytic activity first increased and then decreased with Au content. - Highlights: • Bimetallic catalysts had smaller metal particles and larger number of exposed active site than the monometallic catalysts. • The cationization of Pd particles increased with Au content in the bimetallic catalysts. • The bimetallic catalysts exhibited higher catalytic activities for HDC of 2,4-DCP than the monometallic counterparts. • The concerted pathway for HDC of 2,4-DCP was more predominant with increasing Au content in the bimetallic catalyst. - Abstract: Monometallic and bimetallic Pd-Au catalysts supported on multi-walled carbon nanotubes (CNTs) with varied Au cooperation amounts were prepared using the complexing-reduction method in the presence of tetrahydrofuran (THF). The liquid phase catalytic hydrodechlorination (HDC) of 2,4-dichlorophenol (2,4-DCP) was investigated over these bimetallic catalysts. The catalysts were characterized by N 2 adsorption-desorption isotherms, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and H 2 chemisorption. Characterization results showed that the co-reduction of Pd and Au mainly formed alloy-like structure. The bimetallic catalysts had smaller metal particles and larger numbers of exposed active site than that of monometallic catalysts. In addition, compared with Pd(1.7)/CNTs and Au(0.4)/CNTs, the binding energies of Pd 3d 5/2 shifted to higher positions while that of Au 4f 7/2 had negative shifts in the Pd-Au bimetallic catalysts, which can be ascribed to the electrons transferred from metal Pd to Au and the cationization of Pd particles was enhanced. Accordingly, the bimetallic Pd-Au particles with different Au contents in the catalysts exhibited varied synergistic effects for the catalytic HDC of 2,4-DCP, with Pd(1.8)Au(0.4)/CNTs having the highest catalytic activity

  2. Bimetallic Au-decorated Pd catalyst for the liquid phase hydrodechlorination of 2,4-dichlorophenol

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Juan [School of the Environment, Donghua University, Shanghai 201620 (China); Chen, Huan, E-mail: hchen404@njust.edu.cn [Key Laboratory of Jiangsu Province for Chemical Pollution Control and Resources Reuse, School of Environmental & Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094 (China); Chen, Quanyuan; Huang, Zhaolu [School of the Environment, Donghua University, Shanghai 201620 (China)

    2016-11-30

    Graphical abstract: 2,4-Dichlorophenol can be converted to phenol via the catalytic HDC method over Pd-Au/CNTs and the catalytic activity first increased and then decreased with Au content. - Highlights: • Bimetallic catalysts had smaller metal particles and larger number of exposed active site than the monometallic catalysts. • The cationization of Pd particles increased with Au content in the bimetallic catalysts. • The bimetallic catalysts exhibited higher catalytic activities for HDC of 2,4-DCP than the monometallic counterparts. • The concerted pathway for HDC of 2,4-DCP was more predominant with increasing Au content in the bimetallic catalyst. - Abstract: Monometallic and bimetallic Pd-Au catalysts supported on multi-walled carbon nanotubes (CNTs) with varied Au cooperation amounts were prepared using the complexing-reduction method in the presence of tetrahydrofuran (THF). The liquid phase catalytic hydrodechlorination (HDC) of 2,4-dichlorophenol (2,4-DCP) was investigated over these bimetallic catalysts. The catalysts were characterized by N{sub 2} adsorption-desorption isotherms, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and H{sub 2} chemisorption. Characterization results showed that the co-reduction of Pd and Au mainly formed alloy-like structure. The bimetallic catalysts had smaller metal particles and larger numbers of exposed active site than that of monometallic catalysts. In addition, compared with Pd(1.7)/CNTs and Au(0.4)/CNTs, the binding energies of Pd 3d{sub 5/2} shifted to higher positions while that of Au 4f{sub 7/2} had negative shifts in the Pd-Au bimetallic catalysts, which can be ascribed to the electrons transferred from metal Pd to Au and the cationization of Pd particles was enhanced. Accordingly, the bimetallic Pd-Au particles with different Au contents in the catalysts exhibited varied synergistic effects for the catalytic HDC of 2,4-DCP, with Pd(1.8)Au(0.4)/CNTs having the highest

  3. Volatility and entrainment of feed components and product glass characteristics during pilot-scale vitrification of simulated Hanford site low-level waste

    International Nuclear Information System (INIS)

    Shade, J.W.

    1996-01-01

    Commercially available melter technologies were tested for application to vitrification of Hanford site low-level waste (LLW). Testing was conducted at vendor facilities using a non-radioactive LLW simulant. Technologies tested included four Joule-heated melter types, a carbon electrode melter, a cyclone combustion melter, and a plasma torch-fired melter. A variety of samples were collected during the vendor tests and analyzed to provide data to support evaluation of the technologies. This paper describes the evaluation of melter feed component volatility and entrainment losses and product glass samples produced during the vendor tests. All vendors produced glasses that met minimum leach criteria established for the test glass formulations, although in many cases the waste oxide loading was less than intended. Entrainment was much lower in Joule-heated systems than in the combustion or plasma torch-fired systems. Volatility of alkali metals, halogens, B, Mo, and P were severe for non-Joule-heated systems. While losses of sulfur were significant for all systems, the volatility of other components was greatly reduced for some configurations of Joule-heated melters. Data on approaches to reduce NO x generation, resulting from high nitrate and nitrite content in the double-shell slurry feed, are also presented

  4. Au nanoinjectors for electrotriggered gene delivery into the cell nucleus.

    Science.gov (United States)

    Kang, Mijeong; Kim, Bongsoo

    2015-01-01

    Intracellular delivery of exogenous materials is an essential technique required for many fundamental biological researches and medical treatments. As our understanding of cell structure and function has been improved and diverse therapeutic agents with a subcellular site of action have been continuously developed, there is a demand to enhance the performance of delivering devices. Ideal intracellular delivery devices should convey various kinds of exogenous materials without deteriorating cell viability regardless of cell type and, furthermore, precisely control the location and the timing of delivery as well as the amount of delivered materials for advanced researches.In this chapter the development of a new intracellular delivery device, a nanoinjector made of a Au (gold) nanowire (a Au nanoinjector) is described in which delivery is triggered by external application of an electric pulse. As a model study, a gene was delivered directly into the nucleus of a neuroblastoma cell, and successful delivery without cell damage was confirmed by the expression of the delivered gene. The insertion of a Au nanoinjector directly into a cell can be generally applied to any kind of cell, and a high degree of surface modification of Au allows attachment of diverse materials such as proteins, small molecules, or nanoparticles as well as genes on Au nanoinjectors. This expands their applicability, and it is expected that they will provide important information on the effects of delivered exogenous materials and consequently contribute to the development of related therapeutic or clinical technologies.

  5. Exotic high activity surface patterns in PtAu nanoclusters

    KAUST Repository

    Mokkath, Junais Habeeb

    2013-05-09

    The structure and chemical ordering of PtAu nanoclusters of 79, 135, and 201 atoms are studied via a combination of a basin hopping atom-exchange technique (to locate the lowest energy homotops at fixed composition), a symmetry orbit technique (to find the high symmetry isomers), and density functional theory local reoptimization (for determining the most stable homotop). The interatomic interactions between Pt and Au are derived from the empirical Gupta potential. The lowest energy structures show a marked tendency toward PtcoreAushell chemical ordering by enrichment of the more cohesive Pt in the core region and of Au in the shell region. We observe a preferential segregation of Pt atoms to (111) facets and Au atoms to (100) facets of the truncated octahedron cluster motif. Exotic surface patterns are obtained particularly for Pt-rich compositions, where Pt atoms are being surrounded by Au atoms. These surface arrangements boost the catalytic activity by creating a large number of active sites. © 2013 American Chemical Society.

  6. Incendie au CERN

    CERN Multimedia

    CERN Press Office. Geneva

    1999-01-01

    At 9.15 a.m. on 26 January a fire broke out when part of a particle detector was being dismantled. This apparatus comprised 80 plates of depleted uranium which is used for its strong particle absorption power. Depleted uranium is only very slightly radioactive. The work was being done by two people from a specialist company inside a sealed tent with an entrance lock. The tent itself was located in the large North Experimental Hall on the Prévessin site.

  7. Pilot study

    International Nuclear Information System (INIS)

    Hofmeester, G.H.; Swart, A.; Dijk, E. van

    1984-01-01

    In May 1980 it was decided to organize an intercomparison of personal dosimeters for photon radiations. The Commission of the European Communities initiated the intercomparison by starting a pilot study in which three laboratories NPL (United Kingdom), PTB (Germany) and RIV (The Netherlands) were asked to irradiate a series of personal dosemeters from institutes, GSF (Muenchen), CEA (Fontenay-aux-Roses), CNEN (Bologna) and CEGB (Berkeley). The latter institutes are secondary standard laboratories and have a radiation protection service as well. A new aspect of this pilot study is the fact that the irradiations also take place in front of a phantom. Irradiations took place in July and August 1980. The results of 4 institutes show that the personal dosemeters are quite capable of measuring the backscattered photon components

  8. Site-specific 13C content by quantitative isotopic 13C Nuclear Magnetic Resonance spectrometry: A pilot inter-laboratory study

    International Nuclear Information System (INIS)

    Chaintreau, Alain; Fieber, Wolfgang; Sommer, Horst; Gilbert, Alexis; Yamada, Keita; Yoshida, Naohiro; Pagelot, Alain; Moskau, Detlef; Moreno, Aitor; Schleucher, Jürgen; Reniero, Fabiano; Holland, Margaret; Guillou, Claude; Silvestre, Virginie; Akoka, Serge; Remaud, Gérald S.

    2013-01-01

    Graphical abstract: -- Highlights: •First ring test on isotopic 13 C NMR spectrometry. •Evaluation of the intra- and inter-variability of the NMR spectrometers used. •Definition of a protocol for qualification of the performance of the spectrometer. -- Abstract: Isotopic 13 C NMR spectrometry, which is able to measure intra-molecular 13 C composition, is of emerging demand because of the new information provided by the 13 C site-specific content of a given molecule. A systematic evaluation of instrumental behaviour is of importance to envisage isotopic 13 C NMR as a routine tool. This paper describes the first collaborative study of intra-molecular 13 C composition by NMR. The main goals of the ring test were to establish intra- and inter-variability of the spectrometer response. Eight instruments with different configuration were retained for the exercise on the basis of a qualification test. Reproducibility at the natural abundance of isotopic 13 C NMR was then assessed on vanillin from three different origins associated with specific δ 13 C i profiles. The standard deviation was, on average, between 0.9 and 1.2‰ for intra-variability. The highest standard deviation for inter-variability was 2.1‰. This is significantly higher than the internal precision but could be considered good in respect of a first ring test on a new analytical method. The standard deviation of δ 13 C i in vanillin was not homogeneous over the eight carbons, with no trend either for the carbon position or for the configuration of the spectrometer. However, since the repeatability for each instrument was satisfactory, correction factors for each carbon in vanillin could be calculated to harmonize the results

  9. Site-specific {sup 13}C content by quantitative isotopic {sup 13}C Nuclear Magnetic Resonance spectrometry: A pilot inter-laboratory study

    Energy Technology Data Exchange (ETDEWEB)

    Chaintreau, Alain; Fieber, Wolfgang; Sommer, Horst [Firmenich SA, Corporate R and D Division, P.O. Box 239, 1211 Geneva 8 (Switzerland); Gilbert, Alexis; Yamada, Keita [Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8503 (Japan); Yoshida, Naohiro [Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8503 (Japan); Earth-Life Science Institute, Tokyo Institute of Technology, Meguro, Tokyo 152-8551 (Japan); Pagelot, Alain [Bruker Biospin SAS, 34 rue de l‘Industrie, 67166 Wissembourg Cedex (France); Moskau, Detlef; Moreno, Aitor [Bruker Biospin AG, Industriestrasse 26, 8117 Fällanden (Switzerland); Schleucher, Jürgen [Department of Medical Biochemistry and Biophysics, Umeå University, S-90187 Umeå (Sweden); Reniero, Fabiano; Holland, Margaret; Guillou, Claude [European Commission, Joint Research Centre – Institute for Health and Consumer Protection, via E. Fermi 2749, I-21027 Ispra (Italy); Silvestre, Virginie; Akoka, Serge [EBSI team, Interdisciplinary Chemistry: Synthesis, Analysis, Modelling (CEISAM), University of Nantes-CNRS UMR 6230, 2 rue de la Houssinière, BP 92208, F-44322 Nantes cedex 3 (France); Remaud, Gérald S., E-mail: gerald.remaud@univ-nantes.fr [EBSI team, Interdisciplinary Chemistry: Synthesis, Analysis, Modelling (CEISAM), University of Nantes-CNRS UMR 6230, 2 rue de la Houssinière, BP 92208, F-44322 Nantes cedex 3 (France)

    2013-07-25

    Graphical abstract: -- Highlights: •First ring test on isotopic {sup 13}C NMR spectrometry. •Evaluation of the intra- and inter-variability of the NMR spectrometers used. •Definition of a protocol for qualification of the performance of the spectrometer. -- Abstract: Isotopic {sup 13}C NMR spectrometry, which is able to measure intra-molecular {sup 13}C composition, is of emerging demand because of the new information provided by the {sup 13}C site-specific content of a given molecule. A systematic evaluation of instrumental behaviour is of importance to envisage isotopic {sup 13}C NMR as a routine tool. This paper describes the first collaborative study of intra-molecular {sup 13}C composition by NMR. The main goals of the ring test were to establish intra- and inter-variability of the spectrometer response. Eight instruments with different configuration were retained for the exercise on the basis of a qualification test. Reproducibility at the natural abundance of isotopic {sup 13}C NMR was then assessed on vanillin from three different origins associated with specific δ{sup 13}C{sub i} profiles. The standard deviation was, on average, between 0.9 and 1.2‰ for intra-variability. The highest standard deviation for inter-variability was 2.1‰. This is significantly higher than the internal precision but could be considered good in respect of a first ring test on a new analytical method. The standard deviation of δ{sup 13}C{sub i} in vanillin was not homogeneous over the eight carbons, with no trend either for the carbon position or for the configuration of the spectrometer. However, since the repeatability for each instrument was satisfactory, correction factors for each carbon in vanillin could be calculated to harmonize the results.

  10. Laparo-Endoscopic Single-Site Surgery for Radical and Cytoreductive Nephrectomy, Renal Vein Thrombectomy, and Partial Nephrectomy: A Prospective Pilot Evaluation

    Directory of Open Access Journals (Sweden)

    Ithaar H. Derweesh

    2010-01-01

    Full Text Available Introduction. Laparo-endoscopic single-site surgery (LESS may diminish morbidity of laparoscopic surgery. We prospectively evaluated feasibility and outcomes of LESS-Radical Nephrectomy (LESS-RN and Partial Nephrectomy (LESS-PN. Methods. 10 patients underwent LESS-RN (6 and LESS-PN (4 between 2/2009-5/2009. LESS-RN included 2 with renal vein thrombectomy, one of which was also cytoreductive. Transperitoneal LESS access was obtained by periumbilical incision. Patient/tumor characteristics, oncologic, and quality of life (QoL outcomes were analyzed. Results. 3 Men/7 Women (mean age 58.7 years, median follow-up 9.8 months underwent LESS. 9/10 cases were completed successfully. All had negative margins. Mean operative time was 161 minutes, estimated blood loss was 125 mL, and incision size was 4.4 cm. Median tumor size for LESS-RN and -PN was 5.0 and 1.7 cm (=.045. Median LESS-PN ischemia time was 24 minutes; mean preoperative/postoperative creatinine were 0.7/0.8 mg/dL (=.19. Mean pain score at discharge was 1.3. Mean preoperative, 3-, and 6-month postoperative SF-36 QoL Score was 73.8, 74.4 and 77.1 (=.222. All patients are currently alive. Conclusions. LESS-RN, renal vein thrombectomy, and PN are technically feasible and safe while maintaining adherence to oncologic principles, with excellent QoL preservation and low discharge pain scores. Further study is requisite.

  11. Recruitment Strategies and Costs Associated With Enrolling People With Insomnia and High Blood Pressure Into an Online Behavioral Sleep Intervention: A Single-Site Pilot Study.

    Science.gov (United States)

    Routledge, Faye S; Davis, Tara D; Dunbar, Sandra B

    Recruitment in clinical research is a common challenge and source of study failure. The reporting of recruitment methods and costs in hypertension trials is limited especially for smaller, single-site trials, online intervention trials, and trials using newer online recruitment strategies. The aims of this study are to describe and examine the feasibility of newer online-e-mail recruitment strategies and traditional recruitment strategies used to enroll participants with insomnia and high blood pressure into an online behavioral sleep intervention study (Sleeping for Heart Health). The 16 online-e-mail-based and traditional recruitment strategies used are described. Recruitment strategy feasibility was examined by study interest and enrollee yields, conversion rates, and costs (direct, remuneration, labor, and cost per enrollee). From August 2014 to October 2015, 183 people were screened and 58 (31.7%) enrolled in the study (51.1 ± 12.9 years, 63.8% female, 72.4% African American, 136 ± 12/88 ± 7 mm Hg, 87.9% self-reported hypertension, 67.2% self-reported antihypertensive medication use). The recruitment strategies yielding the highest enrollees were the university hospital phone waiting message system (25.4%), Craigslist (22.4%), and flyers (20.3%) at a per enrollee cost of $42.84, $98.90, and $128.27, respectively. The university hospital phone waiting message system (55.6%) and flyers (54.5%) had the highest interested participant to enrolled participant conversion rate of all recruitment strategies. Approximately 70% of all enrolled participants were recruited from the university hospital phone waiting message system, Craigslist, or flyers. Given the recruitment challenges that most researchers face, we encourage the documenting, assessing, and reporting of detailed recruitment strategies and associated recruitment costs so that other researchers may benefit.

  12. Chiral magnetic effect search in p+Au, d+Au and Au+Au collisions at RHIC

    Science.gov (United States)

    Zhao, Jie

    2018-01-01

    Metastable domains of fluctuating topological charges can change the chirality of quarks and induce local parity violation in quantum chromodynamics. This can lead to observable charge separation along the direction of the strong magnetic field produced by spectator protons in relativistic heavy-ion collisions, a phenomenon called the chiral magnetic effect (CME). A major background source for CME measurements using the charge-dependent azimuthal correlator (Δϒ) is the intrinsic particle correlations (such as resonance decays) coupled with the azimuthal elliptical anisotropy (v2). In heavy-ion collisions, the magnetic field direction and event plane angle are correlated, thus the CME and the v2-induced background are entangled. In this report, we present two studies from STAR to shed further lights on the background issue. (1) The Δϒ should be all background in small system p+Au and d+Au collisions, because the event plane angles are dominated by geometry fluctuations uncorrelated to the magnetic field direction. However, significant Δϒ is observed, comparable to the peripheral Au+Au data, suggesting a background dominance in the latter, and likely also in the mid-central Au+Au collisions where the multiplicity and v2 scaled correlator is similar. (2) A new approach is devised to study Δϒ as a function of the particle pair invariant mass (minv) to identify the resonance backgrounds and hence to extract the possible CME signal. Signal is consistent with zero within uncertainties at high minv. Signal at low minv, extracted from a two-component model assuming smooth mass dependence, is consistent with zero within uncertainties.

  13. Filipino au pairs on the move

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2016-01-01

    Most Filipina au pairs in Denmark send remittances back home, and for many, au pairing forms part of longer-term migration trajectories. This article explores how Filipina au pairs try to carve out a future for themselves abroad. It shows that they navigate within tight webs of financial interdep......Most Filipina au pairs in Denmark send remittances back home, and for many, au pairing forms part of longer-term migration trajectories. This article explores how Filipina au pairs try to carve out a future for themselves abroad. It shows that they navigate within tight webs of financial...

  14. Level lifetimes of Au52+ in Au plasma

    International Nuclear Information System (INIS)

    Liu Bo; Zhu Zhiyan; Jiang Gang; Zhu Zhenghe

    2003-01-01

    Based on the extended relativistic multiconfiguration Dirac-Fock theory, the level lifetimes, level widths and wavelengths of Au 52+ have been calculated using the General-purpose Relativistic Atomic Structure Program. The wavelengths obtained are in good agreement with the experimental data available. The relationship between the level lifetimes and the level widths satisfies the Heisenberg uncertainty principle

  15. La course au logement social

    OpenAIRE

    Bourgeois, Marine

    2013-01-01

    Ce billet a été publié dans le cadre de l'opération Têtes Chercheuses, qui permet à des étudiants ou chercheurs de grandes écoles, d'universités ou de centres de recherche partenaires de promouvoir des projets innovants en les rendant accessibles, et ainsi participer au débat public.

  16. Synthesis of Au nanotubes with SiOx nanowires as sacrificial templates

    International Nuclear Information System (INIS)

    Lu, M.Y.; Chang, Y.C.; Chen, L.J.

    2006-01-01

    Gold nanotubes with SiO x nanowires as sacrificial templates have been synthesized. SiO x nanowires were functionalized by 3-aminopropyl trimethoxysilane that generates a charged surface. The attachment of negatively charged Au nanoparticles was followed. The coverage of Au nanoparticles was initially less than 30%. Further coverage was achieved by the reduction of gold hydroxide to grow the continuous nanoshell on Au nanoparticles, which serve as nucleation sites. The final coverage of Au nanoshells on SiO x nanowires depends strongly on the relative amount of SiO x nanowires in gold hydroxide solution. Both transmission electron microscope and scanning electron microscope images revealed the formation of Au nanotubes with the removal of SiO x nanowires by etching in a dilute HF solution

  17. Some recent results in Au+Au collisions at AGS

    International Nuclear Information System (INIS)

    Chen, Z.

    1996-01-01

    Many interesting results have been obtained for Au + Au reactions at AGS. The basic information about the reaction dynamics comes from the hadronic distribution. and this article reviews the recent progress of these distributions in details. The proton rapidity distribution shows significantly increased stopping compared to lighter systems, implying the formation of a state of high baryon density. Unlike reactions at this energy induced by lighter heavy ions, at low m t - m 0 the proton invariant spectra deviate from a single exponential shape and become fear,. while pion spectra are found to rise in this region, with the π - spectra rising faster than the π + spectra. The inverse slope parameter increases faster for particles of larger mass as the number of participants in the reaction increases, an indication of increased effect of radial expansion in central collision. Anti-proton Needs have been measured recently, and unfortunately a comparison among current results from different experiments indicates discrepancy

  18. 75 FR 69049 - Expansion and Extension of the Green Technology Pilot Program

    Science.gov (United States)

    2010-11-10

    ... under the Green Technology Pilot Program is available on the USPTO's Internet Web site at http://www... Extension of the Green Technology Pilot Program AGENCY: United States Patent and Trademark Office, Commerce...) implemented the Green [[Page 69050

  19. Nuclear spin of 185Au and hyperfine structure of 188Au

    International Nuclear Information System (INIS)

    Ekstroem, C.; Ingelman, S.; Wannberg, G.

    1977-03-01

    The nuclear spin of 185 Au, I = 5/2, and the hyperfine separation of 188 Au, Δγ = +- 2992(30) MHz, have been measured with the atomic-beam magnetic resonance method. The spin of 185 Au indicates a deformed nuclear shape in the ground state. The small magnetic moment of 188 Au is close in value to those of the heavier I = 1 gold isotopes 190 192 194 Au, being located in a typical transition region. (Auth.)

  20. On ternary intermetallic aurides. CaAu{sub 2}Al{sub 2}, SrAu{sub 2-x}Al{sub 2+x} and Ba{sub 3}Au{sub 5+x}Al{sub 6-x}

    Energy Technology Data Exchange (ETDEWEB)

    Stegemann, Frank [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster (Germany); Benndorf, Christopher [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster (Germany); Institut fuer Physikalische Chemie, Westfaelische Wilhelms-Universitaet Muenster (Germany); Institut fuer Mineralogie, Kristallographie und Materialwissenschaften, Universitaet Leipzig (Germany); Zhang, Yuemei; Fokwa, Boniface P.T. [Department of Chemistry, University of California, Riverside, CA (United States); Bartsch, Manfred; Zacharias, Helmut [Physikalisches Institut, Westfaelische Wilhelms-Universitaet Muenster (Germany); Eckert, Hellmut [Institut fuer Physikalische Chemie, Westfaelische Wilhelms-Universitaet Muenster (Germany); Instituto de Fisica de Sao Carlos, Universidade de Sao Paulo, Sao Carlos, SP (Brazil); Janka, Oliver [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster (Germany); Institut fuer Chemie, Carl von Ossietzky Universitaet Oldenburg (Germany)

    2017-11-17

    The intermetallic compound CaAu{sub 2}Al{sub 2}, and the members of the solid solutions SrAu{sub 2-x}Al{sub 2+x} (0 ≤ x ≤ 0.33) and Ba{sub 3}Au{sub 5+x}Al{sub 6-x} (x = 0, 0.14, 0.49) were synthesized from the elements in sealed tantalum ampoules. The Ca compound crystallizes with the orthorhombic ThRu{sub 2}P{sub 2} type structure, whereas the targeted SrAu{sub 2}Al{sub 2} was found to form a solid solution according to SrAu{sub 2-x}Al{sub 2+x}. For the Ba system no ''BaAu{sub 2}Al{sub 2}'' was found, however, Ba{sub 3}Au{sub 5+x}Al{sub 6-x} was discovered to crystallize in the monoclinic space group C2/c with its own structure type. The samples were investigated by powder X-ray diffraction and their crystal structures were refined on the basis of single-crystal X-ray diffraction data. All compounds were characterized furthermore by susceptibility measurements. The crystallographic aluminum sites of CaAu{sub 2}Al{sub 2} and Ba{sub 3}Au{sub 5}Al{sub 6} can be differentiated by {sup 27}Al solid state NMR spectra on the basis of their different electric field gradients, in agreement with theoretical calculations. The electron transfer from the alkaline earth metals and the aluminum atoms onto the gold atoms was investigated by X-ray photoelectron spectroscopy (XPS) classifying these intermetallics as aurides, in full agreement with the calculated Bader charges. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  1. Spectroscopic characterization of Au 3+ biosorption by waste biomass of Saccharomyces cerevisiae

    Science.gov (United States)

    Lin, Zhongyu; Wu, Jianming; Xue, Ru; Yang, Yong

    2005-02-01

    Some spectroscopic characteristics of Au 3+ biosorption by waste biomass of Saccharomyces cerevisiae have been reported in this paper. The effect of temperature on the correlation parameters of chemical kinetics and thermodynamics of the binding reaction was investigated by using AAS. XRD diffraction pattern of gold-loaded biomass revealed that the Au 3+ bound on the cell wall of the biomass had been reduced into gold particle. FTIR spectrophotometry on blank and gold-loaded biomass demonstrated that active groups such as the hydroxyl group of saccharides, and the carboxylate anion of amino-acid residues, from the peptidoglycan layer on the cell wall seem to be the sites for the Au 3+ binding, and the free aldehyde group of the hemiacetalic hydroxyl group from reducing sugars, i.e. the hydrolysates of the polysaccharides on the peptidoglycan layer, serving as the electron donor, in situ reduced the Au 3+ to Au 0. XPS and IR characterizations of the interaction between glucose and Au 3+ further supported that the reduction of Au 3+ to Au 0 can directly occur at the aldehyde group of the reducing sugars.

  2. Venus project : experimentation at ENEA's pilot site

    International Nuclear Information System (INIS)

    Bargellini, M.L.; Fontana, F.; Niccolai, L.; Scavino, G.; Mancini, R.; Levialdi, S.

    1996-12-01

    The document describes the ENEA's (Italian Agency for New Technologies, Energy and the Environment) experience in the Venus Project (Esprit III 6398). Venus is an advanced visual interface based on icon representation that permits to end-user to inquiry databases. VENUS interfaces to ENEA's databases: cometa materials Module, Cometa Laboratories Module and European Programs. This report contents the results of the experimentation and of the validation carried out in ENEA's related to the Venus generations. Moreover, the description of the architecture, the user requirements syntesis and the validation methodology of the VENUS systems have been included

  3. L’apprentissage au CERN

    CERN Multimedia

    Staff Association

    2016-01-01

    En 1961, sur la base du constat que l’évolution du marché du travail nécessitait un besoin croissant de personnel qualifié, le 1er accord entre la République et canton de Genève et le CERN fut signé. Cet accord avait notamment pour objet la formation professionnelle de jeunes électroniciens et techniciens de laboratoires en physique. Le CERN, acteur local économique d’importance, soulignait par cet accord sa volonté de participer au développement économique et social local. Le 1er apprenti arriva au CERN en 1965. En 1971, le centre d’apprentissage fut créé ; il accueille aujourd’hui plus d’une vingtaine d’apprentis au total, à raison d’environ six nouveaux apprentis chaque année. Cet apprentissage est dédié aux jeunes âgés e...

  4. How Does Amino Acid Ligand Modulate Au Core Structure and Characteristics in Peptide Coated Au Nanocluster?

    Science.gov (United States)

    Li, Nan; Li, Xu; Zhao, Hongkang; Zhao, Lina

    2018-03-01

    The atomic structures and the corresponding physicochemical properties of peptide coated Au nanoclusters determine their distinctive biological targeting applications. To learn the modulation of amino acid ligand on the atomic structure and electronic characteristics of coated Au core is the fundamental knowledge for peptide coated Au nanocluster design and construction. Based on our recent coated Au nanocluster configuration study (Nanoscale, 2016, 8, 11454), we built the typically simplified Au13(Cys-Au-Cys) system to more clearly learn the basic modulation information of amino acid ligand on Au core by the density functional theory (DFT) calculations. There are two isomers as ligand adjacent bonding (Iso1) and diagonal bonding (Iso2) to Au13 cores. The geometry optimizations indicate the adjacent bonding Iso1 is more stable than Iso2. More important, the Au13 core of Iso1 distorts much more significantly than that of Iso2 by Cys-Au-Cys bonding through the root-mean-square deviation (RMSD) analysis, which modulate their electronic characteristics in different ways. In addition, the frontier molecular orbital results of Au13(Cys-Au-Cys) isomers confirm that the Au cores mainly determine the blue shifts of Au13(Cys-Au-Cys) systems versus the original Au13 core in their UV-visible absorption spectrum studies. The configuration of Au13 core performs deformation under Cys-Au-Cys ligand modulation to reach new stability with distinct atomic structure and electronic properties, which could be the theory basis for peptide coated AuNCs design and construction.

  5. Using Dawn to Observe SEP Events Past 2 AU

    Science.gov (United States)

    Villarreal, M. N.; Russell, C. T.; Prettyman, T. H.

    2017-12-01

    The launch of the STEREO spacecraft provided much insight into the longitudinal and radial distribution of solar energetic particles (SEPs) relative to their origin site. However, almost all of the observations of SEP events have been made exclusively near 1 AU. The Dawn mission, which orbited around Vesta before arriving at Ceres, provides an opportunity to analyze these events at much further distances. Although Dawn's Gamma Ray and Neutron Detector (GRaND) is not optimized for SEP characterization, it is sensitive to protons greater than 4 MeV, making it capable of detecting a solar energetic particle event in its vicinity. Solar energetic particles in this area of the solar system are important as they are believed to cause sputtering at bodies such as Ceres and comets (Villarreal et al., 2017; Wurz et al., 2015). In this study, we use Dawn's GRaND data from 2011-2015 when Dawn was at distances between 2-3 AU. We compare the SEP events seen by Dawn with particle measurements at 1 AU using STEREO, Wind, and ACE to understand how the SEP events evolved past 1 AU.References: Villarreal, M. N., et al. (2017), The dependence of the Cerean exosphere on solar energetic particle events, Astrophys. J. Lett., 838, L8.Wurz, P. et al. (2015), Solar wind sputtering of dust on the surface of 67P/Churyumov-Gerasimenko, A&A, 583, A22.

  6. Regional energy facility siting analysis

    International Nuclear Information System (INIS)

    Eberhart, R.C.; Eagles, T.W.

    1976-01-01

    Results of the energy facility siting analysis portion of a regional pilot study performed for the anticipated National Energy Siting and Facility Report are presented. The question of cell analysis versus site-specific analysis is explored, including an evaluation of the difference in depth between the two approaches. A discussion of the possible accomplishments of regional analysis is presented. It is concluded that regional sitting analysis could be of use in a national siting study, if its inherent limits are recognized

  7. Role of Au-C Interactions on the Catalytic Activity of Au Nanoparticles Supported on TiC(001) toward Molecular Oxygen Dissociation

    International Nuclear Information System (INIS)

    Rodriguez, J.; Feria, L.; Jirsak, T.; Takahashi, Y.; Nakamura, K.; Illas, F.

    2010-01-01

    High-resolution photoemission and density functional calculations on realistic slab surface models were used to study the interaction and subsequent dissociation of O 2 with Au nanoparticles supported on TiC(001). The photoemission results indicate that at 150 K O 2 adsorbs molecularly on the supported gold nanoparticles, and upon heating to temperatures above 200 K the O 2 → 2O reaction takes place with migration of atomic oxygen to the TiC(001) substrate. The addition of Au to TiC(001) substantially enhances the rate of O 2 dissociation at room temperature. The reactivity of Au nanoparticles supported on TiC(001) toward O 2 dissociation is much larger than that of similar nanoparticles supported either on TiO 2 (110) or MgO(001) surfaces, where the cleavage of O-O bonds is very difficult. Density functional calculations carried out on large supercells show that the contact of Au with TiC(001) is essential for charge polarization and an enhancement in the chemical activity of Au. Small two-dimensional particles which expose Au atoms in contact with TiC(001) are the most reactive. While O 2 prefers binding to Au sites, the O atoms interact more strongly with the TiC(001) surface. The oxygen species active during the low-temperature ( 2 . Once atomic O binds to TiC(001), the chemisorption bond is so strong that temperatures well above 400 K are necessary to remove the O adatoms from the TiC(001) substrate by direct reaction with CO. The high reactivity of Au/TiC(001) toward O 2 at low-temperature opens the route for the transformation of alcohols and amines on the supported Au nanoparticles.

  8. Fabricating a Homogeneously Alloyed AuAg Shell on Au Nanorods to Achieve Strong, Stable, and Tunable Surface Plasmon Resonances

    KAUST Repository

    Huang, Jianfeng

    2015-08-13

    Colloidal metal nanocrystals with strong, stable, and tunable localized surface plasmon resonances (SPRs) can be useful in a corrosive environment for many applications including field-enhanced spectroscopies, plasmon-mediated catalysis, etc. Here, a new synthetic strategy is reported that enables the epitaxial growth of a homogeneously alloyed AuAg shell on Au nanorod seeds, circumventing the phase segregation of Au and Ag encountered in conventional synthesis. The resulting core–shell structured bimetallic nanorods (AuNR@AuAg) have well-mixed Au and Ag atoms in their shell without discernible domains. This degree of mixing allows AuNR@AuAg to combine the high stability of Au with the superior plasmonic activity of Ag, thus outperforming seemingly similar nanostructures with monometallic shells (e.g., Ag-coated Au NRs (AuNR@Ag) and Au-coated Au NRs (AuNR@Au)). AuNR@AuAg is comparable to AuNR@Ag in plasmonic activity, but that it is markedly more stable toward oxidative treatment. Specifically, AuNR@AuAg and AuNR@Ag exhibit similarly strong signals in surface-enhanced Raman spectroscopy that are some 30-fold higher than that of AuNR@Au. When incubated with a H2O2 solution (0.5 m), the plasmonic activity of AuNR@Ag immediately and severely decayed, whereas AuNR@AuAg retained its activity intact. Moreover, the longitudinal SPR frequency of AuNR@AuAg can be tuned throughout the red wavelengths (≈620–690 nm) by controlling the thickness of the AuAg alloy shell. The synthetic strategy is versatile to fabricate AuAg alloyed shells on different shaped Au, with prospects for new possibilities in the synthesis and application of plasmonic nanocrystals.

  9. The growth of sulfur adlayers on Au(100)

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Yue; Ren, Shendong; Chen, Chi-Lu [Department of Physics, National Central University, Taoyuan 32001, Taiwan (China); Liang, Xihui [Department of Physics, National Central University, Taoyuan 32001, Taiwan (China); Guangzhou Research Institute of Optics-Mechanics-Electricity Technology, Guangzhou 510663 (China); Fan, Liang-Jen; Yang, Yaw-Wen [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China); Tang, Jian-Ming [Department of Physics, University of New Hampshire, Durham, New Hampshire 03824 (United States); Luh, Dah-An, E-mail: luh.dah.an@gmail.com [Department of Physics, National Central University, Taoyuan 32001, Taiwan (China); National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China)

    2015-02-14

    We have studied the growth of S layers adsorbed on Au(100) with low-energy electron diffraction (LEED), X-ray photoemission spectra (XPS), and scanning tunneling microscope (STM). Three phases of S/Au(100)—(2 × 2), trimer, and c(2 × 4)—are identified; the latter two are not previously reported. A dose of S{sub 2} at 300 K transformed Au(100)-(5 × 20) initially into the (2 × 2) phase and formed the c(2 × 4) phase at a saturation coverage. The STM results show that monolayer Au islands formed during the initial S dose and remained throughout the growth, resulting in a rough c(2 × 4) surface. We show that a highly ordered c(2 × 4) phase can be obtained with a flat (2 × 2) phase as an intermediate step during growth. Based on the evolution of XPS and STM images with varied S{sub 2} dose, the components of S 2p are assigned and structural models for the various S/Au(100) phases are proposed. In the (2 × 2) phase, one S atom resides on a four-fold hollow site in each (2 × 2) unit cell, corresponding to a S coverage of 0.25 ML; in the trimer phase, three S atoms form a trimer residing on a four-fold hollow site in each (2 × 2) unit cell, corresponding to a S coverage of 0.75 ML; in the c(2 × 4) phase, there are five S atoms in each primitive unit cell of c(2 × 4); three of them form a trimer residing on a four-fold hollow site, and the other two form a dimer located on the top of the trimer, corresponding to a nominal S coverage of 1.25 ML. With the proposed structural models, the growth of S on Au(100) at 300 K is described in detail.

  10. The National Conversion Pilot Project

    International Nuclear Information System (INIS)

    Roberts, A.V.

    1995-01-01

    The National Conversion Pilot Project (NCPP) is a recycling project under way at the U.S. Department of Energy (DOE) Rocky Flats Environmental Technology Site (RFETS) in Colorado. The recycling aim of the project is threefold: to reuse existing nuclear weapon component production facilities for the production of commercially marketable products, to reuse existing material (uranium, beryllium, and radioactively contaminated scrap metals) for the production of these products, and to reemploy former Rocky Flats workers in this process

  11. High-p$_{T}$ Tomography of d+Au and Au+Au at SPS, RHIC, and LHC

    CERN Document Server

    Vitev, I; Vitev, Ivan; Gyulassy, Miklos

    2002-01-01

    The interplay of nuclear effects on the p_T > 2 GeV inclusive hadron spectra in d+Au and Au+Au reactions at root(s) = 17, 200, 5500 GeV is compared to leading order perturbative QCD calculations for elementary p+p (p-bar+p) collisions. The competition between nuclear shadowing, Cronin effect, and jet energy loss due to medium-induced gluon radiation is predicted to lead to a striking energy dependence of the nuclear suppression/enhancement pattern in A+A reactions. We show that future d+Au data can used to disentangle the initial and final state effects.

  12. Analysis of empty ATLAS pilot jobs

    CERN Document Server

    AUTHOR|(INSPIRE)INSPIRE-00006364; The ATLAS collaboration; Dal Pra, S.; Di Girolamo, A.; Forti, A.; Templon, J.; Vamvakopoulos, E.

    2017-01-01

    In this analysis we quantify the wallclock time used by short empty pilot jobs on a number of WLCG compute resources. Pilot factory logs and site batch logs are used to provide independent accounts of the usage. Results show a wide variation of wallclock time used by short jobs depending on the site and queue, and changing with time. For a reference dataset of all jobs in August 2016, the fraction of wallclock time used by empty jobs per studied site ranged from 0.1% to 0.8%. The variation in wallclock usage may be explained by different workloads for each resource with a greater fraction when the workload is low. Aside from the wall time used by empty pilots, we also looked at how many pilots were empty as a fraction of all pilots sent. Binning the August dataset into days, empty fractions between 2% and 90% were observed.  The higher fractions correlate well with periods of few actual payloads being sent to the site.

  13. Le site paléo-indien de Piedra Museo (Patagonie). Sa contribution au débat sur le premier peuplement du continent américainThe palaeo-indian site of Piedra Museo (Patagonia). Its contribution to the debate on the peopling of the Americas.

    Science.gov (United States)

    Ramirez Rozzi, Fernando V.; d'Errico, Francesco; Zarate, Marcelo

    2000-08-01

    The Piedra Museo site (Santa Cruz, Argentina), excavated over the past nine years has yielded a rich archaeological record, which contributes to the discussion on the first peopling of the Americas. We present here a new study of the site, based on an analysis of the stratigraphy, spatial distribution of archaeological remains, bone taphonomy, and discussion of new AMS- 14C dates. We conclude that remains of extinct species with cut-marks from the lower levels are contemporaneous of stone tools and cores from the same levels. This demonstrates that humans were present in the southern part of Patagonia around 10 300 and 11 100 years BP and suggests that hunting of large mammals was a part of their subsistence strategies.

  14. Configuration dependent deformation in 183Au

    International Nuclear Information System (INIS)

    Joshi, P.; Kumar, A.; Govil, I.M.; Mukherjee, G.; Singh, R.P.; Muralithar, S.; Bhowmik, R.K.

    1998-01-01

    The lifetime measurements in 183 Au nucleus were carried in order to probe the deformation properties of the band built on the i 3/2 and h 9/2 configurations. The nucleus of 183 Au was populated using a reaction 28 Si( 159 Tb,4n) 183 Au at a beam energy of 140 MeV. Lifetime measurements were carried out using Recoil Distance Measurements (RDM) method

  15. Hydrogen adsorption on bimetallic PdAu(111) surface alloys

    DEFF Research Database (Denmark)

    Takehiro, Naoki; Liu, Ping; Bergbreiter, Andreas

    2014-01-01

    The adsorption of hydrogen on structurally well defined PdAu-Pd(111) monolayer surface alloys was investigated in a combined experimental and theoretical study, aiming at a quantitative understanding of the adsorption and desorption properties of individual PdAu nanostructures. Combining...... the structural information obtained by high resolution scanning tunneling microscopy (STM), in particular on the abundance of specific adsorption ensembles at different Pd surface concentrations, with information on the adsorption properties derived from temperature programmed desorption (TPD) spectroscopy...... and high resolution electron energy loss spectroscopy (HREELS) provides conclusions on the minimum ensemble size for dissociative adsorption of hydrogen and on the adsorption energies on different sites active for adsorption. Density functional theory (DFT) based calculations give detailed insight...

  16. 75 FR 56857 - Pilot, Flight Instructor, and Pilot School Certification

    Science.gov (United States)

    2010-09-17

    ...-2006-26661; Amendment No., 141-14] RIN 2120-AI86 Pilot, Flight Instructor, and Pilot School..., certification, and operating requirements for pilots, flight instructors, ground instructors, and pilot schools...: Background On August 21, 2009, the FAA published the ``Pilot, Flight Instructor, and Pilot School...

  17. Predicted Habitat Suitability for Montipora Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Montipora in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  18. Predicted Habitat Suitability for Porites in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Porites in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  19. Predicted Habitat Suitability for Leptoseris Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Leptoseris in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  20. Predicted Habitat Suitability for Leptoseris in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Leptoseris in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  1. Predicted Habitat Suitability for All Mesophotic Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for all mesophotic corals in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to...

  2. Synthesis of nir-sensitive Au-Au{sub 2}S nanocolloids for drug delivery

    Energy Technology Data Exchange (ETDEWEB)

    Ren, L.; Chow, G.M

    2003-01-15

    Near IR (NIR) sensitive Au-Au{sub 2}S nanocolloids were prepared by mixing HAuCl{sub 4} and Na{sub 2}S in aqueous solutions. An anti-tumor drug, cis-platin, was adsorbed onto Au-Au{sub 2}S nanoparticle surface via the 11-mercaptoundecanoic acid (MUA) layers. The results show that the degree of adsorption of cis-platin onto Au-Au{sub 2}S nanoparticles was controlled by the solution pH value, and the drug release was sensitive to near-infrared irradiation. The cis-platin-loaded Au-Au{sub 2}S nanocolloids can be potentially applied as NIR activated drug delivery carrier.

  3. Successful synthesis and thermal stability of immiscible metal Au-Rh, Au-Ir andAu-Ir-Rh nanoalloys

    Science.gov (United States)

    Shubin, Yury; Plyusnin, Pavel; Sharafutdinov, Marat; Makotchenko, Evgenia; Korenev, Sergey

    2017-05-01

    We successfully prepared face-centred cubic nanoalloys in systems of Au-Ir, Au-Rh and Au-Ir-Rh, with large bulk miscibility gaps, in one-run reactions under thermal decomposition of specially synthesised single-source precursors, namely, [AuEn2][Ir(NO2)6], [AuEn2][Ir(NO2)6] х [Rh(NO2)6]1-х and [AuEn2][Rh(NO2)6]. The precursors employed contain all desired metals ‘mixed’ at the atomic level, thus providing significant advantages for obtaining alloys. The observations using high-resolution transmission electron microscopy show that the nanoalloy structures are composed of well-dispersed aggregates of crystalline domains with a mean size of 5 ± 3 nm. Еnergy dispersive x-ray spectroscopy and x-ray powder diffraction (XRD) measurements confirm the formation of AuIr, AuRh, AuIr0.75Rh0.25, AuIr0.50Rh0.50 and AuIr0.25Rh0.75 metastable solid solutions. In situ high-temperature synchrotron XRD (HTXRD) was used to study the formation mechanism of nanoalloys. The observed transformations are described by the ‘conversion chemistry’ mechanism characterised by the primary development of particles comprising atoms of only one type, followed by a chemical reaction resulting in the final formation of a nanoalloy. The obtained metastable nanoalloys exhibit essential thermal stability. Exposure to 180 °C for 30 h does not cause any dealloying process.

  4. Spontaneous decoration of Au nanoparticles on micro-patterned reduced graphene oxide shaped by focused laser beam

    International Nuclear Information System (INIS)

    Wan, Y. C.; Tok, E. S.; Teoh, H. F.; Sow, C. H.

    2015-01-01

    We report a facile, two-step method for the micro-landscaping of Au nanoparticles(NPs) on reduced graphene oxide (rGO) film en route to micro-patterned Au(NPs)-rGO hybrid functional materials. This method employs a focused laser beam to first locally convert GO to rGO before immersing the micro-patterned GO-rGO film into HAuCl 4 solution. The rGO micro-pattern, shaped by the focused laser beam, serves as nucleation sites for the reduction of Au ions. The reduction mechanism that governs the decoration of Au NPs on rGO films is akin to electroless deposition process. In this instance, surface charges that are formed during laser reduction of GO to rGO provide active nucleation sites for Au 3+ ions to form Au NPs when HAuCl 4 solution is introduced. The number density, the size, and size distribution of the Au NPs can thus be directly tuned and preferentially anchored onto the rGO micro-pattern by varying the incident laser power, the scanning speed of the laser, or the concentration of HAuCl 4 . The resulting hybrid materials can be used as a substrate for Surface Enhanced Raman Spectroscopy (SERS). Using Rhodamine 6G as the test subject, we found an improvement of SERS enhancement over bare rGO of up to four times, depending on the size of the Au NPs

  5. Spontaneous decoration of Au nanoparticles on micro-patterned reduced graphene oxide shaped by focused laser beam

    Energy Technology Data Exchange (ETDEWEB)

    Wan, Y. C.; Tok, E. S. [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Teoh, H. F. [Graduate School of Integrative Sciences and Engineering, National University of Singapore, 28 Medical Drive, Singapore 117456 (Singapore); Sow, C. H. [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Graduate School of Integrative Sciences and Engineering, National University of Singapore, 28 Medical Drive, Singapore 117456 (Singapore)

    2015-02-07

    We report a facile, two-step method for the micro-landscaping of Au nanoparticles(NPs) on reduced graphene oxide (rGO) film en route to micro-patterned Au(NPs)-rGO hybrid functional materials. This method employs a focused laser beam to first locally convert GO to rGO before immersing the micro-patterned GO-rGO film into HAuCl{sub 4} solution. The rGO micro-pattern, shaped by the focused laser beam, serves as nucleation sites for the reduction of Au ions. The reduction mechanism that governs the decoration of Au NPs on rGO films is akin to electroless deposition process. In this instance, surface charges that are formed during laser reduction of GO to rGO provide active nucleation sites for Au{sup 3+} ions to form Au NPs when HAuCl{sub 4} solution is introduced. The number density, the size, and size distribution of the Au NPs can thus be directly tuned and preferentially anchored onto the rGO micro-pattern by varying the incident laser power, the scanning speed of the laser, or the concentration of HAuCl{sub 4}. The resulting hybrid materials can be used as a substrate for Surface Enhanced Raman Spectroscopy (SERS). Using Rhodamine 6G as the test subject, we found an improvement of SERS enhancement over bare rGO of up to four times, depending on the size of the Au NPs.

  6. The Electronic Properties and L3 XANES of Au and Nano-Au

    International Nuclear Information System (INIS)

    Yiu, Y.M.; Zhang, P.; Sham, T.K.

    2004-01-01

    The electronic properties of Au crystal and nano Au have been investigated by theory and experiment. Molecularly capped nano-Au was synthesized using the two-phase method. Au nano-particles have been characterized by X-Ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). They retain the fcc crystal structure. Their sizes have been determined to be in a range from 5.5 nm to 1.7 nm. The L3 X-ray Absorption Near Edge Structure (XANES) of nano-Au and Au foil have been recorded using synchrotron radiation, and examined by theoretical calculation based on the first principles. Both theory and experiment show that the nano-Au particles have essentially all the Au L3 XANES features of bulk Au in the near edge region with less pronounced resonance peaks. It is also shown that nano Au exhibits lower 4f binding energy than bulk Au in good agreement with quantum confined Au systems reported previously.

  7. Pilot Boarding Areas

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Pilot boarding areas are locations at sea where pilots familiar with local waters board incoming vessels to navigate their passage to a destination port. Pilotage is...

  8. Controlling the Local Electronic Properties of Si(553)-Au through Hydrogen Doping

    Science.gov (United States)

    Hogan, C.; Speiser, E.; Chandola, S.; Suchkova, S.; Aulbach, J.; Schäfer, J.; Meyer, S.; Claessen, R.; Esser, N.

    2018-04-01

    We propose a quantitative and reversible method for tuning the charge localization of Au-stabilized stepped Si surfaces by site-specific hydrogenation. This is demonstrated for Si(553)-Au as a model system by combining density functional theory simulations and reflectance anisotropy spectroscopy experiments. We find that controlled H passivation is a two-step process: step-edge adsorption drives excess charge into the conducting metal chain "reservoir" and renders it insulating, while surplus H recovers metallic behavior. Our approach illustrates a route towards microscopic manipulation of the local surface charge distribution and establishes a reversible switch of site-specific chemical reactivity and magnetic properties on vicinal surfaces.

  9. L’olivier au Maroc

    Directory of Open Access Journals (Sweden)

    El Mouhtadi Issam

    2014-03-01

    Full Text Available L’olivier est une culture traditionnelle sur le pourtour de la Méditerranée. Il est donc naturel de trouver cet arbre au Maroc où il est présent depuis des siècles. Cultivé surtout traditionnellement jusqu’à ses dernières années, il fait l’objet maintenant d’un plan de valorisation très ambitieux pour non seulement garder le Royaume à son niveau actuel (2e producteur mondial pour l’olive de conserve et 6e pour l’huile d’olive mais pour conquérir de nouveaux marchés au niveau mondial et profiter ainsi de l’engouement que connaît cette huile reconnue pour ses bienfaits. Le plan national « Maroc Vert » permet ainsi, grâce à des subventions conséquentes, non seulement de renouveler les vergers existant avec la variété traditionnelle picholine du Maroc, mais également la plantation de nouvelles variétés en super-intensif dans le but d’industrialiser au maximum de nouveaux vergers. Il en est de même pour la transformation des olives en huile de bonne qualité avec la mise en place d’unités de trituration modernes qui doivent supplanter à terme la multitude de « maâsra » et réduire ainsi l’impact environnemental dû aux margines. L’olive ne sera plus dans l’avenir que représentée par son huile et ses formes comestibles, mais les résidus de son extraction seront valorisés soit sous forme de combustible élaboré pour le grignon, soit sous forme d’une base de chimie verte pour les sous-produits du raffinage. D’autres applications sont actuellement à l’étude, car le Maroc à compris, comme tous les autres grands pays producteurs, que l’olive était un nouveau gisement de richesses.

  10. Travailler avec Windows 7 au CERN (FR)

    CERN Multimedia

    CERN. Geneva

    2010-01-01

    Vue d'ensemble des nouveaux concepts et des changements dans l'interface utilisateur survenus dans Windows 7 depuis les versions antérieures de Windows (XP ou Vista). La mise à disposition de Windows 7 au CERN et son intégration dans l’infrastructure de Windows au CERN seront présentées.

  11. Becoming independent through au pair migration

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2015-01-01

    . This article argues that, despite this critique, au pairing does play an important formative role for young Filipinas because it opens up for experiences abroad that enable them to be recognised as independent adults in Philippine society. Rather than autonomy, however, au pairs define their independence...

  12. Study of Au+Au relativistic collisions with the Fopi-Phase I detector; Etude des collisions relativistes Au+Au avec le detecteur Fopi-Phase I

    Energy Technology Data Exchange (ETDEWEB)

    Dupieux, P

    1995-01-01

    Au+Au relativistic collisions, in a 100-1000 MeV energy domain per nucleon, are described. Experiments have been carried out with the SIS accelerator at GSI/Darmstadt. Data are analysed with the FOPI-phase I detector. These data are compared with IQMD model (Isospin Quantum Molecular Dynamics) Predictions. (S.G). 80 refs., 77 figs., 5 tabs.

  13. Fire at a dry material burial site in Pierrefonds : atmospheric emissions of pollutants and health impacts; Incendie au site d'enfouissement de materiaux secs de Pierrefonds : emissions de polluants a l'atmosphere et impacts sur la sante

    Energy Technology Data Exchange (ETDEWEB)

    Beausoleil, M.

    2005-05-01

    The Quebec Health Agency for the City of Montreal was asked to evaluate the health risk associated with the atmospheric emissions associated with a fire that occurred at a dry material burial site in Pierrefonds in December 2004. The fire lasted several weeks, resulting in a release of pollutants into the ambient air of a residential district located near the site. Air emission concentration measurements were taken at 3 intervals in order to evaluate the health risks that the chemical substances posed to the residents in the area. During the few hours when the fire was out of control and while flames were visible, the concentrations of aldehydes, acids, polycyclic aromatic hydrocarbons and particulates in the plume of smoke were very high, causing residents to experience respiratory problems and irritations to eyes, nose and throat. However, as soon as the fire was controlled, the concentrations of these pollutants decreased quickly. Fire extinction efforts continued for several weeks. Although the concentrations of pollutants measured in the ambient air of the residential district were higher than those generally measured in this district and elsewhere on the island of Montreal, they were in the same order of magnitude as those measured occasionally in certain districts under similar circumstances. The fire was extinguished in February 2005 at which time the measured concentrations were very similar to those generally measured in the urban environment. However, the strong and unpleasant odours that persist, particularly in the evening, correspond to the high values of hydrogen sulphide (H{sub 2}S). The Health Agency has reassured the residents that these values do not present long term health risks, but recognizes that the situation constitutes a reduction in the quality of life for the residents that can have psychosocial impacts of which the long-term repercussions are difficult to measure. refs., tabs., figs.

  14. English for au pairs the au pair's guide to learning English

    CERN Document Server

    Curtis, Lucy

    2014-01-01

    English for Au Pairs has interlinked stories about a group of au pairs new to England. Marta, an 18-year-old from Poland arrives in the UK to work as an au pair. Throughout her year-long stay she has many different experiences - some bad, some good - but with the support of her host family she finds new friends and improves her English. English for Au Pairs offers insight into the joys and difficulties of being an au pair while at the same time reinforcing English language learning through grammar explanations and exercises.

  15. Plan for the civil reprocessing pilot plant of China

    International Nuclear Information System (INIS)

    Wang, D.Y.; Chen, M.

    1987-01-01

    Based on the R and D work, experience on plant operation and site situation, the necessity and feasibility of building a pilot plant for civil reprocessing in China are discussed. The capacity of 100 kg HM/day (LWR) and 3 kg HM/day (MTR) has been proposed. The plant consists of cold testing facility and hot pilot facility. It is expected to complete the pilot plant in 1990's. This paper also describes the purpose, scale, process and equipment of the pilot plant

  16. Theoretical prediction of the noble gas complexes HeAuF and NeAuF

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Ab initio calculations were carried out to investigate the structures and the stability of the noble gas complexes HeAuF and NeAuF through MP2 and CCSD(T) methods.The HeAuF was predicted to have a linear structure with weak He-Au covalent bonding,the distance of which is closer to the covalent limit in comparison with the corresponding van der Waals limit.The dissociation energy with respect to He + AuF was found to be 24 and 26 kJ·mol-1 at the CCSD(T)/basis set B and B’ levels,respectively.However,similar calculations for NeAuF indicate that NeAuF is not a stable species.

  17. Au, Ag and Au:Ag colloidal nanoparticles synthesized by pulsed laser ablation as SERS substrates

    Directory of Open Access Journals (Sweden)

    M. Vinod

    2014-12-01

    Full Text Available Chemically pure colloidal suspensions of gold and silver nanoparticles were synthesized using pulsed laser ablation. The dependence of laser fluence on the surface plasmon characteristics of the nanoparticles was investigated. Au:Ag colloidal suspensions were prepared by mixing highly monodisperse Au and Ag nanocolloids. The plasmon band of these mixtures was found to be highly sensitive to Au:Ag concentration ratio and wavelength of the laser beam used in the ablation process. The Au:Ag mixture consists of almost spherical shaped nanostructures with a tendency to join with adjacent ones. The surface enhanced Raman scattering activity of the Au, Ag and Au:Ag colloidal suspensions was tested using crystal violet as probe molecules. Enhancement in Raman signal obtained with Au:Ag substrates was found to be promising and strongly depends on its plasmon characteristics.

  18. A further insight into the biosorption mechanism of Au(III by infrared spectrometry

    Directory of Open Access Journals (Sweden)

    Lin Zhongyu

    2011-10-01

    Full Text Available Abstract Background The interactions of microbes with metal ions form an important basis for our study of biotechnological applications. Despite the recent progress in studying some properties of Au(III adsorption and reduction by Bacillus megatherium D01 biomass, there is still a need for additional data on the molecular mechanisms of biosorbents responsible for their interactions with Au(III to have a further insight and to make a better exposition. Results The biosorption mechanism of Au(III onto the resting cell of Bacillus megatherium D01 biomass on a molecular level has been further studied here. The infrared (IR spectroscopy on D01 biomass and that binding Au(III demonstrates that the molecular recognition of and binding to Au(III appear to occur mostly with oxygenous- and nitrogenous-active groups of polysaccharides and proteins in cell wall biopolymers, such as hydroxyl of saccharides, carboxylate anion of amino-acid residues (side-chains of polypeptide backbone, peptide bond (amide I and amide II bands, etc.; and that the active groups must serve as nucleation sites for Au(0 nuclei growth. A further investigation on the interactions of each of the soluble hydrolysates of D01, Bacillus licheniformis R08, Lactobacillus sp. strain A09 and waste Saccharomyces cerevisiae biomasses with Au(III by IR spectrometry clearly reveals an essential biomacromolecule-characteristic that seems the binding of Au(III to the oxygen of the peptide bond has caused a significant, molecular conformation-rearrangement in polypeptide backbones from β-pleated sheet to α-helices and/or β-turns of protein secondary structure; and that this changing appears to be accompanied by the occurrence, in the peptide bond, of much unbound -C=O and H-N- groups, being freed from the inter-molecular hydrogen-bonding of the β-pleated sheet and carried on the helical forms, as well as by the alternation in side chain steric positions of protein primary structure. This might

  19. Substrate-dependent Au{sub x} cluster: A new insight into Au{sub x}/CeO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Kong-Jie; Yang, Yan-Ju [School of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004 (China); Lang, Jia-Jian [School of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004 (China); Engineering Laboratory of Specialty Fibers and Nuclear Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China); Teng, Bo-Tao, E-mail: tbt@zjnu.cn [School of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004 (China); Wu, Feng-Min [School of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004 (China); Du, Shi-Yu [Engineering Laboratory of Specialty Fibers and Nuclear Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China); Wen, Xiao-Dong, E-mail: wxd@sxicc.ac.cn [State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001 (China)

    2016-11-30

    Graphical abstract: 2D Au{sub x} (x < 10) on CeO{sub 2}(110) are more stable than 3D ones, while the stability trend changes for x ≥ 10; Au{sub x} (x ≤ 4) prefer to monatomically disperse on CeO{sub 2}(100) and aggregate to 3D clusters for x > 4. - Highlights: • The stable structures of Au{sub x}/CeO{sub 2} are dependent of index surfaces of CeO{sub 2}. • Au{sub x} prefers to monatomically disperse on CeO{sub 2}(100) at low coverage. • Au{sub x} aggregates to 3D clusters on CeO{sub 2}(100) at high coverage. • 2D Au{sub x} (x < 10) are more stable than the 3D ones on CeO{sub 2}(110). • The effects on the stability of Au{sub x}/CeO{sub 2} are systematically discussed. - Abstract: To theoretically study the structures of metal clusters on oxides is very important and becomes one of the most challenging works in computational heterogeneous catalysis since many factors affect their structures and lead to various possibilities. In this work, it is very interesting to find that the stable structures and stability evolution of Au{sub x} clusters on ceria are varied with different index surfaces of CeO{sub 2}. The corresponding reasons in chemical, geometric and electronic properties are systematically explored. Au{sub x} (x = 1–4) clusters prefer to separately disperse at the O-O bridge sites on CeO{sub 2}(100) due to the low coordination number of surface O; while aggregate due to the strong Au–Au attractions when x is larger than 4. Owing to the uniform distribution of O-O bridge sites on CeO{sub 2}(111) and (100), the most stable configurations of Au{sub x} are 3D structures with bottom atoms more than top ones when x is larger than 4. However, 2D configurations of Au{sub x}/CeO{sub 2}(110) (x < 10) are more stable than the corresponding 3D structures due to the particular O-O arrangement on CeO{sub 2}(110). 3D Au{sub x} clusters across O-O-Y lines are suggested as the most stable configurations for Au{sub x}/CeO{sub 2}(110) (x ≥ 10). The present

  20. The ATLAS PanDA Pilot in Operation

    International Nuclear Information System (INIS)

    Nilsson, P; De, K; Stradling, A; Caballero, J; Maeno, T; Wenaus, T

    2011-01-01

    The Production and Distributed Analysis system (PanDA) was designed to meet ATLAS requirements for a data-driven workload management system capable of operating at LHC data processing scale. Submitted jobs are executed on worker nodes by pilot jobs sent to the grid sites by pilot factories. This paper provides an overview of the PanDA pilot system and presents major features added in light of recent operational experience, including multi-job processing, advanced job recovery for jobs with output storage failures, gLExec based identity switching from the generic pilot to the actual user, and other security measures. The PanDA system serves all ATLAS distributed processing and is the primary system for distributed analysis; it is currently used at over 100 sites worldwide. We analyze the performance of the pilot system in processing real LHC data on the OSG, EGI and Nordugrid infrastructures used by ATLAS, and describe plans for its evolution.

  1. La-doped Al2O3 supported Au nanoparticles: highly active and selective catalysts for PROX under PEMFC operation conditions.

    Science.gov (United States)

    Lin, Qingquan; Qiao, Botao; Huang, Yanqiang; Li, Lin; Lin, Jian; Liu, Xiao Yan; Wang, Aiqin; Li, Wen-Cui; Zhang, Tao

    2014-03-14

    La-doped γ-Al2O3 supported Au catalysts show high activity and selectivity for the PROX reaction under PEMFC operation conditions. The superior performance is attributed to the formation of LaAlO3, which suppresses H2 oxidation and strengthens CO adsorption on Au sites, thereby improving competitive oxidation of CO at elevated temperature.

  2. Controlled Synthesis of Au@AgAu Yolk-Shell Cuboctahedra with Well-Defined Facets.

    Science.gov (United States)

    Londono-Calderon, Alejandra; Bahena, Daniel; Yacaman, Miguel J

    2016-08-02

    The synthesis of Au@AgAu yolk-shell cuboctahedra nanoparticles formed by galvanic replacement in a seed-mediated method is described. Initially, single-crystal Au seeds are used for the formation of Au@Ag core-shell nanocubes, which serve as the template material for the deposition of an external Au layer. The well-controlled synthesis yields the formation of cuboctahedra nanoparticles with smooth inner and outer Au/Ag surfaces. The deposition/oxidation process is described to understand the formation of cuboctahedra and octahedra nanoparticles. The Au core maintains the initial morphology of the seed and remains static at the center of the yolk-shell because of residual Ag. Structural analysis of the shell indicates intrinsic stacking faults (SFs) near the surface. Energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) compositional analysis show an Au-Ag nonordered alloy forming the shell. The three-dimensional structure of the nanoparticles presented open facets on the [111] as observed by electron tomography SIRT reconstruction over a stack of high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) images. The geometrical model was validated by analyzing the direction of streaks in coherent nanobeam diffraction (NBD). The catalytic activity was evaluated using a model reaction based on the reduction of 4-nitrophenol (4-NTP) by NaBH4 in the presence of Au@AgAu yolk-shell nanoparticles.

  3. Au nanoparticles on tryptophan-functionalized graphene for sensitive detection of dopamine

    International Nuclear Information System (INIS)

    Lian, Qianwen; Luo, Ai; An, Zhenzhen; Li, Zhuang; Guo, Yongyang; Zhang, Dongxia; Xue, Zhonghua; Zhou, Xibin; Lu, Xiaoquan

    2015-01-01

    Graphical abstract: - Highlights: • A novel AuNPs/Trp-GR composite was fabricated by directly electrochemical deposition. • The composite exhibited excellent electrocatalytic activity towards DA. • The proposed method was applied to real samples. - Abstract: A novel and uniform gold nanoparticles/tryptophan-functionalized graphene nanocomposite (AuNPs/Trp-GR) has been successfully fabricated by directly electrochemical depositing gold onto the surface of tryptophan-functionalized graphene (Trp-GR). The nanostructure of AuNPs/Trp-GR was characterized by using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). It was demonstrated that Au nanoparticles were well dispersed on the surface of Trp-GR which might attribute to the more binding sites provided by Trp-GR for the formation of Au nanoparticles. The electrocatalytic activity of the AuNPs/Trp-GR towards the dopamine (DA) was systematically investigated using cyclic voltammetry (CV) and differential pulse voltammetry (DPV). Under optimum conditions, a wide and valuable linear range (0.5–411 μM), a low detection limit (0.056 μM, S/N = 3), good repeatability and stability were obtained for the determination of DA. Furthermore, the modified electrode was successfully applied to real samples analysis

  4. Au nanoparticles on tryptophan-functionalized graphene for sensitive detection of dopamine

    Energy Technology Data Exchange (ETDEWEB)

    Lian, Qianwen; Luo, Ai; An, Zhenzhen; Li, Zhuang; Guo, Yongyang; Zhang, Dongxia [Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Geography and Environment Science, Northwest Normal University, 730070, Lanzhou (China); Xue, Zhonghua [College of Chemistry and Chemical Engineering, Northwest Normal University, 730070, Lanzhou (China); Zhou, Xibin, E-mail: zhouxb@nwnu.edu.cn [Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Geography and Environment Science, Northwest Normal University, 730070, Lanzhou (China); Lu, Xiaoquan, E-mail: Luxq@nwnu.edu.cn [College of Chemistry and Chemical Engineering, Northwest Normal University, 730070, Lanzhou (China)

    2015-09-15

    Graphical abstract: - Highlights: • A novel AuNPs/Trp-GR composite was fabricated by directly electrochemical deposition. • The composite exhibited excellent electrocatalytic activity towards DA. • The proposed method was applied to real samples. - Abstract: A novel and uniform gold nanoparticles/tryptophan-functionalized graphene nanocomposite (AuNPs/Trp-GR) has been successfully fabricated by directly electrochemical depositing gold onto the surface of tryptophan-functionalized graphene (Trp-GR). The nanostructure of AuNPs/Trp-GR was characterized by using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). It was demonstrated that Au nanoparticles were well dispersed on the surface of Trp-GR which might attribute to the more binding sites provided by Trp-GR for the formation of Au nanoparticles. The electrocatalytic activity of the AuNPs/Trp-GR towards the dopamine (DA) was systematically investigated using cyclic voltammetry (CV) and differential pulse voltammetry (DPV). Under optimum conditions, a wide and valuable linear range (0.5–411 μM), a low detection limit (0.056 μM, S/N = 3), good repeatability and stability were obtained for the determination of DA. Furthermore, the modified electrode was successfully applied to real samples analysis.

  5. Fabrication of catalytically active Au/Pt/Pd trimetallic nanoparticles by rapid injection of NaBH{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Haijun, E-mail: zhanghaijun@wust.edu.cn [College of Materials and Metallurgy, Wuhan University of Science and Technology, Wuhan, Hubei Province 430081 (China); State Key Laboratory Breeding Base of Refractories and Ceramics, Wuhan University of Science and Technology, Wuhan 430081 (China); Lu, Lilin [College of Chemical Engineering and Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Cao, Yingnan; Du, Shuang [College of Materials and Metallurgy, Wuhan University of Science and Technology, Wuhan, Hubei Province 430081 (China); State Key Laboratory Breeding Base of Refractories and Ceramics, Wuhan University of Science and Technology, Wuhan 430081 (China); Cheng, Zhong [College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072 (China); Zhang, Shaowei [State Key Laboratory Breeding Base of Refractories and Ceramics, Wuhan University of Science and Technology, Wuhan 430081 (China)

    2014-01-01

    Graphical abstract: The synthesis and characterization of 2.0 nm-diameter Au/Pt/Pd nanoparticles are reported. The catalytic activity for glucose oxidation of the nanoparticles is several times higher than that of Au nanoparticles with nearly same size. - Highlights: • PVP-protected Au/Pt/Pd trimetallic nanoparticles (TNPs) of 2.0 nm in diameter were prepared. • The catalytic activity of TNPs is several times higher than that of Au nanoparticles. • Negatively charged Au atoms in the TNPs were confirmed by DFT calculation. - Abstract: Au/Pt/Pd trimetallic nanoparticles (TNPs) with an alloyed structure and an average diameter of about 2.0 nm were prepared via reducing the corresponding ions with rapidly injected NaBH{sub 4}, and characterized by UV–vis, TEM and HR-TEM. The catalytic activity of as-prepared TNPs for the aerobic glucose oxidation is several times higher than that of Au monometallic nanoparticles with about the same average size, which could be attributed to the catalytically active sites provided by the negatively charged Au atoms as a result of the electron donation from the neighboring Pd atoms. This was well supported by the electron density calculations based on the density functional theory.

  6. Au@TiO2 yolk-shell nanostructures for enhanced performance in both photoelectric and photocatalytic solar conversion

    Science.gov (United States)

    He, Qinrong; Sun, Hang; Shang, Yinxing; Tang, Yanan; She, Ping; Zeng, Shan; Xu, Kongliang; Lu, Guolong; Liang, Song; Yin, Shengyan; Liu, Zhenning

    2018-05-01

    Solar energy conversion is an important field gaining increasing interest. Herein, bio-inspired Au@TiO2 yolk-shell nanoparticles (NPs) have been prepared via a facial one-pot hydrothermal approach. The Au@TiO2 yolk-shell NPs can self-assemble into 3D-structure to form photoelectrode for photoelectric conversion. The obtained photoelectrode demonstrates a swift and stable photocurrent of 3.5 μA/cm2, which is 4.2 and 1.6 times higher than those of the photocurrents generated by the counterparts of commercial TiO2 and Au@TiO2 core-shell NPs, respectively. Moreover, compared to the commercial TiO2 and Au@TiO2 core-shell NPs, the Au@TiO2 yolk-shell NPs also exhibit superior photocatalytic activity, delivering a H2 evolution rate of 4.92 mmol/g h. The performance improvement observed for the Au@TiO2 yolk-shell NPs is likely contributed by two synergistic factors, i.e. the incorporation of AuNPs and the unique hollow structure, which benefit the activity by simultaneously enhancing light utilization, charge separation and reaction site accessibility. The rational design and fabrication of Au@TiO2 yolk-shell NPs hold great promise for future application in efficient solar energy conversion.

  7. Fabrication of catalytically active Au/Pt/Pd trimetallic nanoparticles by rapid injection of NaBH4

    International Nuclear Information System (INIS)

    Zhang, Haijun; Lu, Lilin; Cao, Yingnan; Du, Shuang; Cheng, Zhong; Zhang, Shaowei

    2014-01-01

    Graphical abstract: The synthesis and characterization of 2.0 nm-diameter Au/Pt/Pd nanoparticles are reported. The catalytic activity for glucose oxidation of the nanoparticles is several times higher than that of Au nanoparticles with nearly same size. - Highlights: • PVP-protected Au/Pt/Pd trimetallic nanoparticles (TNPs) of 2.0 nm in diameter were prepared. • The catalytic activity of TNPs is several times higher than that of Au nanoparticles. • Negatively charged Au atoms in the TNPs were confirmed by DFT calculation. - Abstract: Au/Pt/Pd trimetallic nanoparticles (TNPs) with an alloyed structure and an average diameter of about 2.0 nm were prepared via reducing the corresponding ions with rapidly injected NaBH 4 , and characterized by UV–vis, TEM and HR-TEM. The catalytic activity of as-prepared TNPs for the aerobic glucose oxidation is several times higher than that of Au monometallic nanoparticles with about the same average size, which could be attributed to the catalytically active sites provided by the negatively charged Au atoms as a result of the electron donation from the neighboring Pd atoms. This was well supported by the electron density calculations based on the density functional theory

  8. AU-EU “Strategic Partnership”

    DEFF Research Database (Denmark)

    Rodt, Annemarie Peen; Okeke, Jide

    2013-01-01

    This article appraises strategic partnership between the African Union (AU) and European Union (EU). It examines the context and nature of AU and EU security relations and explores the conditions under which partnership has a positive impact in this regard. This includes an evaluation...... of convergence between the two organizations and its effect or lack thereof on African security. The article concludes that events leading up to and initiatives following the 2007 Joint Africa–European Union Strategy have produced a degree of AU and EU convergence, which has had limited impact on the efficacy...... of the African security regime, the level of which remains mediocre at best....

  9. Synthesis of ultrathin face-centered-cubic Au@Pt and Au@Pd core-shell nanoplates from hexagonal-close-packed Au square sheets

    KAUST Repository

    Fan, Zhanxi

    2015-03-17

    The synthesis of ultrathin face-centered-cubic (fcc) Au@Pt rhombic nanoplates is reported through the epitaxial growth of Pt on hexagonal-close-packed (hcp) Au square sheets (AuSSs). The Pt-layer growth results in a hcp-to-fcc phase transformation of the AuSSs under ambient conditions. Interestingly, the obtained fcc Au@Pt rhombic nanoplates demonstrate a unique (101)f orientation with the same atomic arrangement extending from the Au core to the Pt shell. Importantly, this method can be extended to the epitaxial growth of Pd on hcp AuSSs, resulting in the unprecedented formation of fcc Au@Pd rhombic nanoplates with (101)f orientation. Additionally, a small amount of fcc (100)f-oriented Au@Pt and Au@Pd square nanoplates are obtained with the Au@Pt and Au@Pd rhombic nanoplates, respectively. We believe that these findings will shed new light on the synthesis of novel noble bimetallic nanostructures. Phase change: Ultrathin Au@Pt and Au@Pd core-shell nanoplates were prepared from Au square sheets. A phase transformation from hexagonal close-packed (hcp) to face-centered cubic (fcc) is observed upon coating the hcp Au square sheets with Pt or Pd under ambient conditions. The prepared fcc Au@Pt and Au@Pd rhombic nanoplates demonstrate unique (101)f orientation (picture shows a typical fcc Au@Pt rhombic nanoplate). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Et pourquoi pas au CERN ?

    CERN Multimedia

    Staff Association

    2015-01-01

    Télétravail ou travail à distance, aménagement des horaires de travail et autres évolutions favorables à un meilleur équilibre vie privée et vie professionnelle sont adoptés par nombre d’entreprises et d’organisations !   Rendu possible grâce au développement de nouvelles technologies dont Internet, le travail à distance séduit de plus en plus de personnels, ainsi que de plus en plus de sociétés qui y trouvent des avantages en matière de gestion de l’espace, de sécurité (moins de trajets domicile-entreprise), de développement durable (moins de pollution), de motivation et de bien-être de leurs personnels. Les horaires aménagés, voire les « core-hours1 », sont également des pratiques de plus e...

  11. Facile synthesis of Au/ZnO nanoparticles and their enhanced ...

    Indian Academy of Sciences (India)

    Au nanoparticles act as electron buffer due to irradiation by UV light and ZnO nanoparticles as reactive sites for ... et al 2009). Doping with metals (Akyol et al 2004; Kabra et al 2004 ..... of benzene as that under visible light irradiation were ca-.

  12. Pilot solid-waste incinerator

    International Nuclear Information System (INIS)

    Farber, M.G.; Hootman, H.E.; Trapp, D.J.

    1982-01-01

    An experimental program to develop and confirm technology for incinerating solid radioactive waste is in progress at the Savannah River Laboratory (SRL) in support of the short-term and long-term waste management objectives of the Savannah River Plant (SRP). This report reviews the experience of a pilot incinerator with a capacity of 1.0 lb/hr. The facility was tested with nonradioactive materials similar to the radioactive waste generated at the Savannah River site. The experimental program included determining operating parameters, testing wet and dry off-gas treatment systems, and evaluating materials of construction

  13. Local structure of disordered Au-Cu and Au-Ag alloys

    International Nuclear Information System (INIS)

    Frenkel, A. I.; Machavariani, V. Sh.; Rubshtein, A.; Rosenberg, Yu.; Voronel, A.; Stern, E. A.

    2000-01-01

    X-ray-absorption fine structure (XAFS) and x-ray-diffraction (XRD) measurements of disordered alloys Au x Cu 1-x and Au 0.5 Ag 0.5 prepared by melt spinning were performed. In the Au 0.5 Ag 0.5 alloy, no significant local deviations of the atoms from the average fcc lattice were detected while in Au x Cu 1-x alloys, significant deviations of atoms from the average fcc lattice were found. Mean-square vibrations of the Cu-Cu distances revealed by the XAFS in Au x Cu 1-x alloys indicate the weakening of contact between Cu atoms in the dilute limit. Our computer simulation for Au x Cu 1-x clusters of 10 5 atoms reproduces the main features of both the XAFS and XRD data

  14. Charged hadron transverse momentum distributions in Au+Au collisions at S=200 GeV

    Science.gov (United States)

    Roland, Christof; PHOBOS Collaboration; Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Ballintijn, M.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Michałowski, J.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S. F.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wadsworth, B.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2003-03-01

    We present transverse momentum distributions of charged hadrons produced in Au+Au collisions at sqrt(s_NN) = 200 GeV. The evolution of the spectra for transverse momenta p_T from 0.25 to 5GeV/c is studied as a function of collision centrality over a range from 65 to 344 participating nucleons. We find a significant change of the spectral shape between proton-antiproton and peripheral Au+Au collisions. Comparing peripheral to central Au+Au collisions, we find that the yields at the highest p_T exhibit approximate scaling with the number of participating nucleons, rather than scaling with the number of binary collisions.

  15. Comparative efficiencies of photothermal destruction of malignant cells using antibody-coated silica-Au nanoshells, hollow Au/Ag nanospheres and Au nanorods

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Fong-Yu; Chen, Chen-Tai; Yeh, Chen-Sheng, E-mail: csyeh@mail.ncku.edu.t [Department of Chemistry, National Cheng Kung University, Tainan 701, Taiwan (China)

    2009-10-21

    Three Au-based nanomaterials (silica-Au nanoshells, hollow Au/Ag nanospheres and Au nanorods) were evaluated for their comparative photothermal efficiencies at killing three types of malignant cells (A549 lung cancer cells, HeLa cervix cancer cells and TCC bladder cancer cells) using a CW NIR laser. Photodestructive efficiency was evaluated as a function of the number of nanoparticles required to destroy the cancer cells under 808 nm laser wavelength at fixed laser power. Of the three nanomaterials, silica/Au nanoshells needed the minimum number of particles to produce effective photodestruction, whereas Au nanorods needed the largest number of particles. Together with the calculated photothermal conversion efficiency, the photothermal efficiency rankings are silica-Au nanoshells > hollow Au/Ag nanospheres > Au nanorods. Additionally, we found that HeLa cells seem to present better heat tolerance than the other two cancer cell lines.

  16. Intense fluorescence of Au 20

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Chongqi; Harbich, Wolfgang; Sementa, Luca; Ghiringhelli, Luca; Apra, Edoardo; Stener, Mauro; Fortunelli, Alessandro; Brune, Harald

    2017-08-21

    Ligand-protected Au clusters are non-bleaching fluorescence markers in bio- and medical applications. We show that their fluorescence is an intrinsic property of the Au cluster itself. We find a very intense and sharp fluorescence peak located at λ =739.2 nm (1.68 eV) for Au20 clusters in a Ne matrix held at 6 K. The fluorescence reflects the HOMO-LUMO diabatic bandgap of the cluster. The cluster shows a very rich absorption fine structure reminiscent of well defined molecule-like quantum levels. These levels are resolved since Au20 has only one stable isomer (tetrahedral), therefore our sample is mono-disperse in cluster size and conformation. Density-functional theory (DFT) and time-dependent DFT calculations clarify the nature of optical absorptionand predict both main absorption peaks and intrinsic fluorescence in good agreement with experiment.

  17. Interplanetary shock phenomena beyond 1 AU

    International Nuclear Information System (INIS)

    Smith, E.J.

    1985-01-01

    Attention is given to spatial dependences exhibited by spacecraft measurements obtained between 1 and 30 AU, together with temporal variations occurring between solar activity cycle maxima and minima. At 1-3 AU radial distances, shocks develop in association with the corotating solar wind streams characterizing solar minimum and accelerate solar wind evolution with distance while heating the solar wind and generating waves and turbulence. At solar maximum, shocks are observed more frequently at 1 AU but still in association with transient solar events; acceleration leading to energetic storm particles is observed both within and beyond 1 AU. The superimposed effect of large numbers of intense shocks may be responsible for the solar cycle modulation of galactic cosmic rays. 77 references

  18. Amélioration de la nutrition au Cambodge au moyen de l ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Amélioration de la nutrition au Cambodge au moyen de l'aquaculture et des jardins potagers domestiques (FCRSAI). Si l'on produit au Cambodge suffisamment de riz pour nourrir la population, la sous-alimentation maternelle et infantile y demeure quand même élevée en raison de la faible diversification des cultures et du ...

  19. Proton channeling in Au at low energies

    International Nuclear Information System (INIS)

    Valdes, J.E.; Vargas, P.

    1996-01-01

    The electronic energy loss for low velocity protons channeled in the direction single crystal Au is calculated. The spatial distribution of valence electronic density in Au is calculated using Tight Binding Linear Muffin Tin Method. The proton trajectories are determined by numerical integration of the classical motion equation, and the energy loss is evaluated using the calculated valence electronic density in the friction term. The results allow to describe qualitatively the non linear behavior of energy loss with ion velocity observed experimentally. (author)

  20. Unravelling Thiol’s Role in Directing Asymmetric Growth of Au Nanorod–Au Nanoparticle Dimers

    KAUST Repository

    Huang, Jianfeng

    2015-12-15

    Asymmetric nanocrystals have practical significance in nanotechnologies but present fundamental synthetic challenges. Thiol ligands have proven effective in breaking the symmetric growth of metallic nanocrystals but their exact roles in the synthesis remain elusive. Here, we synthesized an unprecedented Au nanorod-Au nanoparticle (AuNR-AuNP) dimer structure with the assistance of a thiol ligand. On the basis of our experimental observations, we unraveled for the first time that the thiol could cause an inhomogeneous distribution of surface strains on the seed crystals as well as a modulated reduction rate of metal precursors, which jointly induced the asymmetric growth of monometallic dimers. © 2015 American Chemical Society.

  1. Carbon dioxide cleaning pilot project

    International Nuclear Information System (INIS)

    Knight, L.; Blackman, T.E.

    1994-01-01

    In 1989, radioactive-contaminated metal at the Rocky Flats Plant (RFP) was cleaned using a solvent paint stripper (Methylene chloride). One-third of the radioactive material was able to be recycled; two-thirds went to the scrap pile as low-level mixed waste. In addition, waste solvent solutions also required disposal. Not only was this an inefficient process, it was later prohibited by the Resource Conservation and Recovery Act (RCRA), 40 CFR 268. A better way of doing business was needed. In the search for a solution to this situation, it was decided to study the advantages of using a new technology - pelletized carbon dioxide cleaning. A proof of principle demonstration occurred in December 1990 to test whether such a system could clean radioactive-contaminated metal. The proof of principle demonstration was expanded in June 1992 with a pilot project. The purpose of the pilot project was three fold: (1) to clean metal so that it can satisfy free release criteria for residual radioactive contamination at the Rocky Flats Plant (RFP); (2) to compare two different carbon dioxide cleaning systems; and (3) to determine the cost-effectiveness of decontamination process in a production situation and compare the cost of shipping the metal off site for waste disposal. The pilot project was completed in August 1993. The results of the pilot project were: (1) 90% of those items which were decontaminated, successfully met the free release criteria , (2) the Alpheus Model 250 was selected to be used on plantsite and (3) the break even cost of decontaminating the metal vs shipping the contaminated material offsite for disposal was a cleaning rate of 90 pounds per hour, which was easily achieved

  2. India: From SITE to INSAT.

    Science.gov (United States)

    Chaudhri, M. M.

    1986-01-01

    Identifies core of India's illiteracy problem and describes use of educational technology to educate rural children. Highlights include descriptions of the Satellite Instructional Television Experiment (SITE) project; motivation behind low-cost educational aids development in rural areas; an educational radio pilot project; and development and…

  3. Apprentissages techniques : L'apprentissage au CERN

    CERN Multimedia

    2004-01-01

    APPRENTISSAGES TECHNIQUES GESTION ET DEVELOPPEMENT DU PERSONNEL HR/PMD L'APPRENTISSAGE AU CERN pour les professions d'électronicien(ne) et de laborantin(e) en physique L'apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le Canton de Genève. En cas de réussite à l'examen de fin d'apprentissage, les apprentis obtiennent le Certificat Fédéral de Capacité Suisse (CFC). 7 places au total sont ouvertes au recrutement pour les deux professions. L'apprentissage dure 4 ans. Minima requis pour faire acte de candidature : • avoir au moins 15 ans et moins de 21 ans à la date de début de l'apprentissage • avoir terminé la scolarité obligatoire, au minimum 9ème du Cycle d'orientation genevois (3ème en France) • être ressortissant d'un pays membre du CERN (Allemagne, Autriche, Belgiqu...

  4. Electric field changes on Au nanoparticles on semiconductor supports--the molecular voltmeter and other methods to observe adsorbate-induced charge-transfer effects in Au/TiO2 nanocatalysts.

    Science.gov (United States)

    McEntee, Monica; Stevanovic, Ana; Tang, Wenjie; Neurock, Matthew; Yates, John T

    2015-02-11

    Infrared (IR) studies of Au/TiO2 catalyst particles indicate that charge transfer from van der Waals-bound donor or acceptor molecules on TiO2 to or from Au occurs via transport of charge carriers in the semiconductor TiO2 support. The ΔνCO on Au is shown to be proportional to the polarizability of the TiO2 support fully covered with donor or acceptor molecules, producing a proportional frequency shift in νCO. Charge transfer through TiO2 is associated with the population of electron trap sites in the bandgap of TiO2 and can be independently followed by changes in photoluminescence intensity and by shifts in the broad IR absorbance region for electron trap sites, which is also proportional to the polarizability of donors by IR excitation. Density functional theory calculations show that electron transfer from the donor molecules to TiO2 and to supported Au particles produces a negative charge on the Au, whereas the transfer from the Au particles to the TiO2 support into acceptor molecules results in a positive charge on the Au. These changes along with the magnitudes of the shifts are consistent with the Stark effect. A number of experiments show that the ∼3 nm Au particles act as "molecular voltmeters" in influencing ΔνCO. Insulator particles, such as SiO2, do not display electron-transfer effects to Au particles on their surface. These studies are preliminary to doping studies of semiconductor-oxide particles by metal ions which modify Lewis acid/base oxide properties and possibly strongly modify the electron-transfer and catalytic activity of supported metal catalyst particles.

  5. Pilot unit for cesium-137 separation; Unite pilote de separation du cesium-137

    Energy Technology Data Exchange (ETDEWEB)

    Raggenbass, A; Quesney, M; Fradin, J; Dufrene, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Users of radiation are becoming increasingly interested in cesium-137. At the same time the starting up of the industrial plant at Marcoule will make available in the near future large stocks of fission products which should be made use of as quickly as possible. The installation described is a pilot plant for cesium-137 production which should make it possible: - to verify the chemical method on actual solutions of fission products, by treating about 100 curies of {sup 137}Cs by operation, - to obtain technical information on the chemical equipment (tele-commands, corrosion, maintenance, etc...), - to obtain {sup 137}Cs in sufficient quantity to perfect the technique of the manufacture of sealed sources. (author)Fren. [French] L'interet des utilisateurs de rayonnement se porte de plus en plus vers le caesium-137. Parallelement, la mise en oeuvre de l'ensemble industriel de Marcoule nous permettra de disposer dans un avenir proche de stocks importants de produits de fission qu'il sera interessant de valoriser au plus vite. L'installation que nous decrivons est un pilote de production de caesium-137 qui doit nous permettre: - de verifier la methode chimique sur des solutions de produits de fission reelles en traitant environ 100 curies de {sup 137}Cs par operation; - d'obtenir des renseignements techniques sur l'appareillage chimique (telecommandes, corrosion, entretien, etc...); - d'obtenir du {sup 137}Cs en quantite suffisante pour mettre au point la technique de fabrication des sources scellees. (auteur)

  6. Evidence of final-state suppression of high-p{_ T} hadrons in Au + Au collisions using d + Au measurements at RHIC

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Becker, B.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; Gburek, T.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Harrington, A. S.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Khan, N.; Kulinich, P.; Kuo, C. M.; Lee, J. W.; Lin, W. T.; Manly, S.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Roland, C.; Roland, G.; Sagerer, J.; Sarin, P.; Sedykh, I.; Skulski, W.; Smith, C. E.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tonjes, M. B.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Veres, G. I.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wysłouch, B.; Zhang, J.

    Transverse momentum spectra of charged hadrons with pT 2 GeV/c). In contrast, the d + Au nuclear modification factor exhibits no suppression of the high-pT yields. These measurements suggest a large energy loss of the high-pT particles in the highly interacting medium created in the central Au + Au collisions. The lack of suppression in d + Au collisions suggests that it is unlikely that initial state effects can explain the suppression in the central Au + Au collisions. PACS: 25.75.-q

  7. Draft environmental assessment: Ocean Thermal Energy Conversion (OTEC) Pilot Plants

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, S.M.; Sands, M.D.; Donat, J.R.; Jepsen, P.; Smookler, M.; Villa, J.F.

    1981-02-01

    This Environmental Assessment (EA) has been prepared, in accordance with the National Environmental Policy Act of 1969, for the deployment and operation of a commercial 40-Megawatt (MW) Ocean Thermal Energy Conversion (OTEC) Pilot Plant (hereafter called the Pilot Plant). A description of the proposed action is presented, and a generic environment typical of the candidate Pilot Plant siting regions is described. An assessment of the potential environmental impacts associated with the proposed action is given, and the risk of credible accidents and mitigating measures to reduce these risks are considered. The Federal and State plans and policies the proposed action will encompass are described. Alternatives to the proposed action are presented. Appendix A presents the navigation and environmental information contained in the US Coast Pilot for each of the candidate sites; Appendix B provides a brief description of the methods and calculations used in the EA. It is concluded that environmental disturbances associated with Pilot Plant activities could potentially cause significant environmental impacts; however, the magnitude of these potential impacts cannot presently be assessed, due to insufficient engineering and environmental information. A site- and design-specific OTEC Pilot Plant Environmental Impact Statement (EIS) is required to resolve the potentially significant environmental effects associated with Pilot Plant deployment and operation. (WHK)

  8. 100-MeV proton beam intensity measurement by Au activation analysis using {sup 197}Au(p, pn){sup 196}Au and {sup 197}Au(p, p3n){sup 194}Au reactions

    Energy Technology Data Exchange (ETDEWEB)

    Mokhtari Oranj, Leila [Division of Advanced Nuclear Engineering, POSTECH, Pohang 37673 (Korea, Republic of); Jung, Nam-Suk; Oh, Joo-Hee [Pohang Accelerator Laboratory, POSTECH, Pohang 37673 (Korea, Republic of); Lee, Hee-Seock, E-mail: lee@postech.ac.kr [Pohang Accelerator Laboratory, POSTECH, Pohang 37673 (Korea, Republic of)

    2016-05-15

    The proton beam intensity of a 100-MeV proton linac at the Korea Multi-purpose Accelerator Complex (KOMAC) was measured by an Au activation analysis using {sup 197}Au(p, pn){sup 196}Au and {sup 197}Au(p, p3n){sup 194}Au reactions to determine the accuracy and precision of beam intensity measurement using Gafchromic film dosimetry method. The target, irradiated by 100-MeV protons, was arranged in a stack consisting of Au, Al foils and Pb plates. The yields of produced radio-nuclei in Au foils were obtained by gamma-ray spectroscopy. The FLUKA code was employed to calculate the energy spectrum of protons onto the front surface of Au foils located at three different depth points of the target and also to investigate the condition of incident beam on the target. A good agreement was found between the beam intensity measurements using the activation analysis method at three different depth points of the target. An excellent agreement was also observed between the beam intensity measurements using the Au activation analysis method and the dosimetry method using Gafchromic film.

  9. Effect of Au Precursor and Support on the Catalytic Activity of the Nano-Au-Catalysts for Propane Complete Oxidation

    Directory of Open Access Journals (Sweden)

    Arshid M. Ali

    2015-01-01

    Full Text Available Catalytic activity of nano-Au-catalyst(s for the complete propane oxidation was investigated. The results showed that the nature of both Au precursor and support strongly influences catalytic activity of the Au-catalyst(s for the propane oxidation. Oxidation state, size, and dispersion of Au nanoparticles in the Au-catalysts, surface area, crystallinity, phase structure, and redox property of the support are the key aspects for the complete propane oxidation. Among the studied Au-catalysts, the AuHAuCl4-Ce catalyst is found to be the most active catalyst.

  10. Carbon monoxide oxidation on a Au(111 surface modified by spontaneously deposited Ru

    Directory of Open Access Journals (Sweden)

    ROLF-JÜRGEN BEHM

    2001-04-01

    Full Text Available The spontaneous deposition of Ru on Au(111 was performed in 10-3 M RuCl3 + 0.5 M H2SO4 solution. The obtained surface was characterized by STM under potential control in 0.5 M H2SO4 solution. The coverage of the Au(111 terraces by deposited Ru was estimated by STM to be 0.02 ML. Step decoration could be noticed in the STM images, which indicates that the steps, as lined defects, are active sites for the nucleation of Ru monolayer islands, while the random distribution of Ru nuclei, observed on the terraces indicates point defects as active sites. The electrocatalytic activity of Au(111 surface modified by spontaneously deposited Ru was studied towards CO oxidation. The significant enhancement in the reaction rate compared to CO oxidation on a pure Au(111 surface, indicated that the edges of the deposited Ru islands were the active sites for the reaction.

  11. A pilot eduroam service at CERN

    CERN Multimedia

    2013-01-01

    Eduroam is a secure, worldwide roaming Wi-Fi access service developed for the international research and education community. It allows people from participating institutions to obtain an Internet connection when visiting other participating institutions by simply opening their laptop.   A pilot eduroam service has been available in IT for some months. Now this pilot service will be extended to most parts of the CERN site from early January. Introduction of this pilot service brings two advantages: CERN users who register with the eduroam service here at CERN will have easy and quick access to Wi-Fi services at many other academic institutions across Europe and beyond;   People visiting CERN from other eduroam institutes will be able to connect to the Wi-Fi network at CERN without waiting for a network connection request to be approved. Being a eduroam user obviously has advantages but, like many computing services, eduroam provides a way for malicious people to steal passwords...

  12. A pilot eduroam service at CERN

    CERN Multimedia

    2014-01-01

    Eduroam is a secure, worldwide roaming Wi-Fi access service developed for the international research and education community. It allows people from participating institutions to obtain an Internet connection when visiting other participating institutions by simply opening their laptop.   A pilot eduroam service has been available in IT for some months. Now this pilot service will be extended to most parts of the CERN site from early January. Introduction of this pilot service brings two advantages: CERN users who register with the eduroam service here at CERN will have easy and quick access to Wi-Fi services at many other academic institutions across Europe and beyond;   People visiting CERN from other eduroam institutes will be able to connect to the Wi-Fi network at CERN without waiting for a network connection request to be approved. Being a eduroam user obviously has advantages but, like many computing services, eduroam provides a way for malicious people to steal passwords...

  13. Toward hybrid Au nanorods @ M (Au, Ag, Pd and Pt) core-shell heterostructures for ultrasensitive SERS probes

    Science.gov (United States)

    Xie, Xiaobin; Gao, Guanhui; Kang, Shendong; Lei, Yanhua; Pan, Zhengyin; Shibayama, Tamaki; Cai, Lintao

    2017-06-01

    Being able to precisely control the morphologies of noble metallic nanostructures is of essential significance for promoting the surface-enhanced Raman scattering (SERS) effect. Herein, we demonstrate an overgrowth strategy for synthesizing Au @ M (M = Au, Ag, Pd, Pt) core-shell heterogeneous nanocrystals with an orientated structural evolution and highly improved properties by using Au nanorods as seeds. With the same reaction condition system applied, we obtain four well-designed heterostructures with diverse shapes, including Au concave nanocuboids (Au CNs), Au @ Ag crystalizing face central cube nanopeanuts, Au @ Pd porous nanocuboids and Au @ Pt nanotrepangs. Subsequently, the exact overgrowth mechanism of the above heterostructural building blocks is further analysed via the systematic optimiziation of a series of fabrications. Remarkably, the well-defined Au CNs and Au @ Ag nanopeanuts both exhibit highly promoted SERS activity. We expect to be able to supply a facile strategy for the fabrication of multimetallic heterogeneous nanostructures, exploring the high SERS effect and catalytic activities.

  14. INDRA at GSI; INDRA au GSI

    Energy Technology Data Exchange (ETDEWEB)

    Bougault, R.; Bocage, F.; Durand, D.; Lopez, O.; Steckmeyer, J.C.; Tamain, B.; Vient, E. [Lab. de Physique Corpusculaire, Caen Univ., 14 (France); Collaboration INDRA: IPN-Orsay, DAPNIA-Saclay, SUBATECH-Nantes, IPN- Lyon, GANIL-Caen

    1997-12-31

    In connection to the decision of installing the INDRA detector by the SIS synchrocyclotron at GSI (Darmstadt, Germany) the report presents the tasks taken into account by the LPC-Caen. These refer to the detector displacement and (mechanical) installation at GSI, the tests before beam (i.e. electronics acquisition software, detectors, etc.) as well as the data acquisition and processing. The physical pro-arguments mention the possibility of disposing of heavy ion beams in a range from 50 MeV to several GeV/nucleon so extending the study of multifragmentation done at GANIL between 30 and 90 MeV/nucleon. More specific, the scientific program of INDRA at GSI inserts studies between those done at around Fermi energy, were the reaction mechanisms are of type of deep inelastic scattering/incomplete fusion, and the studies in the relativistic energy domain where the individual properties of nucleons and transparency of nuclear matter implies mechanisms of the participant-spectator type (fire-ball creation). Also mentioned as fields of extensive studies are: the multifragmentation and its fundamental relation with the nuclear matter equation of state, the role of reaction dynamics in the appearance of collective effects of the radial flow type and its relations with the nuclear compressibility and phase transitions and the thermodynamics of nuclear matter. It appeared that the heavy systems Xe + Sn and Au + Au are the best compromise for the different topics to be approached. The bombarding energies extend from 50 to 150 MeV/nucleon. The report ends with the table giving for six heavy systems (Xe + Sn, Au + Au, C + Au, Ar + Au and P + Au) the required bombarding energies 15 refs.

  15. Preparing Pilots for Takeoff

    Science.gov (United States)

    Ravage, Barbara

    2012-01-01

    Why would schools consider partnering with a vendor to operate a pilot? Why not just wait until the final product is released? For starters, pilots provide schools with a golden opportunity to get an early look at the software, take it for a test flight, and ask for changes tailored to their operating environment and business needs. In some cases,…

  16. Au Kenya, des oiseaux nuisent à une culture adaptée au climat ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    23 août 2013 ... Selon Evans Kituyi, spécialiste de programme principal au Centre de ... principal au Gadam Sorghum Production and Marketing Project. Si les graines occupent une place de premier plan dans l'alimentation des oiseaux, ...

  17. The extraction characteristic of Au-Ag from Au concentrate by thiourea solution

    Science.gov (United States)

    Kim, Bongju; Cho, Kanghee; On, Hyunsung; Choi, Nagchoul; Park, Cheonyoung

    2013-04-01

    The cyanidation process has been used commercially for the past 100 years, there are ores that are not amenable to treatment by cyanide. Interest in alternative lixiviants, such as thiourea, halogens, thiosulfate and malononitrile, has been revived as a result of a major increase in gold price, which has stimulated new developments in extraction technology, combined with environmental concern. The Au extraction process using the thiourea solvent has many advantages over the cyanidation process, including higher leaching rates, faster extraction time and less than toxicity. The purpose of this study was investigated to the extraction characteristic of Au-Ag from two different Au concentrate (sulfuric acid washing and roasting) under various experiment conditions (thiourea concentration, pH of solvent, temperature) by thiourea solvent. The result of extraction experiment showed that the Au-Ag extraction was a fast extraction process, reaching equilibrium (maximum extraction rate) within 30 min. The Au-Ag extraction rate was higher in the roasted concentrate than in the sulfuric acid washing. The higher the Au-Ag extraction rate (Au - 70.87%, Ag - 98.12%) from roasted concentrate was found when the more concentration of thiourea increased, pH decreased and extraction temperature increased. This study informs extraction method basic knowledge when thiourea was a possibility to eco-/economic resources of Au-Ag utilization studies including the hydrometallurgy.

  18. Search for hyperheavy toroidal nuclear structures formed in Au + Au collisions

    International Nuclear Information System (INIS)

    Sochocka, A.; Planeta, R.; Starypan, Z.; Benisz, A.; Hachaj, P.; Nicolis, N.G.

    2008-01-01

    We study the feasibility of an experimental observation of toroidal breakup configurations in Au+Au collisions using the CHIMERA multidetector system. BUU simulations indicate that the threshold energy for toroidal configuration is around 23 MeV/nucleon. The simulations of decay process using the ETNA code indicate the sensitivity of some observables to different studied break-up geometries. (author)

  19. Au/ZnO nanoarchitectures with Au as both supporter and antenna of visible-light

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Tianyu; Chen, Wei; Hua, Yuxiang; Liu, Xiaoheng, E-mail: xhliu@mail.njust.edu.cn

    2017-01-15

    Highlights: • An inversed Au/ZnO nanostructure was fabricated with ZnO loaded onto Au. • The Au/ZnO nanocomposites showed enhanced properties in visible-light photocatalysis. • The SPR effect of Au was considered important for visible-light photocatalysis. - Abstract: In this paper, we fabricate Au/ZnO nanostructure with smaller ZnO nanoparticles loaded onto bigger gold nanoparticles via combining seed-mediated method and sol-gel method. The obtained Au/ZnO nanocomposites exhibit excellent properties in photocatalysis process like methyl orange (MO) degradation and oxidative conversion of methanol into formaldehyde under visible light irradiation. The enhanced properties were ascribed to the surface plasmon resonance (SPR) effect of Au nanoparticles, which could contribute to the separation of photo-excited electrons and holes and facilitate the process of absorbing visible light. This paper contributes to the emergence of multi-functional nanocomposites with possible applications in visible-light driven photocatalysts and makes the Au/ZnO photocatalyst an exceptional choice for practical applications such as environmental purification of organic pollutants in aqueous solution and the synthesis of fine chemicals and intermediates.

  20. Identified particles in Au+Au collisions at S=200 GeV

    Science.gov (United States)

    Phobos Collaboration; Wosiek, Barbara; Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Ballintijn, M.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Manly, S.; McLeod, D.; Michałowski, J.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S. F.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wadsworth, B.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2003-03-01

    The yields of identified particles have been measured at RHIC for Au+Au collisions at S=200 GeV using the PHOBOS spectrometer. The ratios of antiparticle to particle yields near mid-rapidity are presented. The first measurements of the invariant yields of charged pions, kaons and protons at very low transverse momenta are also shown.

  1. Au/ZnO nanoarchitectures with Au as both supporter and antenna of visible-light

    International Nuclear Information System (INIS)

    Liu, Tianyu; Chen, Wei; Hua, Yuxiang; Liu, Xiaoheng

    2017-01-01

    Highlights: • An inversed Au/ZnO nanostructure was fabricated with ZnO loaded onto Au. • The Au/ZnO nanocomposites showed enhanced properties in visible-light photocatalysis. • The SPR effect of Au was considered important for visible-light photocatalysis. - Abstract: In this paper, we fabricate Au/ZnO nanostructure with smaller ZnO nanoparticles loaded onto bigger gold nanoparticles via combining seed-mediated method and sol-gel method. The obtained Au/ZnO nanocomposites exhibit excellent properties in photocatalysis process like methyl orange (MO) degradation and oxidative conversion of methanol into formaldehyde under visible light irradiation. The enhanced properties were ascribed to the surface plasmon resonance (SPR) effect of Au nanoparticles, which could contribute to the separation of photo-excited electrons and holes and facilitate the process of absorbing visible light. This paper contributes to the emergence of multi-functional nanocomposites with possible applications in visible-light driven photocatalysts and makes the Au/ZnO photocatalyst an exceptional choice for practical applications such as environmental purification of organic pollutants in aqueous solution and the synthesis of fine chemicals and intermediates.

  2. Influence of Au Nanoparticle Shape on Au@Cu2O Heterostructures

    Directory of Open Access Journals (Sweden)

    Jie Zhu

    2015-01-01

    Full Text Available Synthesis of metal-semiconductor heterostructures may allow the combination of function of the corresponding components and/or the enhanced performance resulting from the interactions between all the components. In this paper, Au@Cu2O core-shell heterostructures are prepared by a seed-growth method, using different-shaped Au nanocrystals as the seeds such as nanorods, octahedra, decahedra, dots, and nanocubes. The results revealed that the final structure of Au@Cu2O was greatly influenced by the shape of the seeds used. Exposure of Cu2O{111} and Cu2O{001} favored when the overgrowth happened on Au{111} and Au{001} surface, respectively. The size of the product can also be tuned by the amount of the seeds. The results reported here provide a thinking clue to modulate the shape and size of core-shell nanocrystals, which is useful in developing new materials with desired performance.

  3. Fabrication of Te@Au core-shell hybrids for efficient ethanol oxidation

    Science.gov (United States)

    Jin, Huile; Wang, Demeng; Zhao, Yuewu; Zhou, Huan; Wang, Shun; Wang, Jichang

    2012-10-01

    Using Au nanoparticles to catalyze the oxidation of alcohols has garnered increasing attention due to its potential application in direct alcohol fuel cells. In this research Te@Au core-shell hybrids were fabricated for the catalytic oxidation of ethanol, where the preparation procedure involved the initial production of Te crystals with different microstructures and the subsequent utilization of the Te crystal as a template and reducing agent for the production of Te@Au hybrids. The as-prepared core-shell hybrids were characterized by scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction techniques. Electrochemical measurements illustrate that the hybrids have great electrocatalytic activity and stability toward ethanol oxidation in alkaline media. The enhanced electrocatalytic property may be attributed to the cooperative effects between the metal and semiconductor and the presence of a large number of active sites on the hybrids surface.

  4. Oxygen-induced restructuring with release of gold atoms from Au(111)

    International Nuclear Information System (INIS)

    Min, B.K.; Deng, X.; Schalek, R.; Pinnaduwage, D.; Friend, C.M.

    2005-01-01

    Adsorption of oxygen atoms, achieved via electron-induced dissociation of nitrogen dioxide, induces restructuring of the 'herringbone' to a striped, soliton-wall structure accompanied by release of gold from the 'elbows' in the herringbone structure. The number density of 'elbows' (dislocations corresponding to a change in direction of the reconstruction) decreases as a function of increasing atomic oxygen coverage while the long range order observed in low energy electron diffraction (LEED) changes from (√(3)x22)-rec. to (1x22) in the limit of saturation coverage. Small islands and serrated step edges were formed due to the release of gold atoms from elbow sites of Au(111). The overall structural change of the Au(111) surface may result from the reduction of anisotropy related to the tensile stress relief of the Au(111) surface by oxygen atoms

  5. Recent Improvements in the ATLAS PanDA Pilot

    International Nuclear Information System (INIS)

    Nilsson, P; De, K; Bejar, J Caballero; Maeno, T; Potekhin, M; Wenaus, T; Compostella, G; Contreras, C; Dos Santos, T

    2012-01-01

    The Production and Distributed Analysis system (PanDA) in the ATLAS experiment uses pilots to execute submitted jobs on the worker nodes. The pilots are designed to deal with different runtime conditions and failure scenarios, and support many storage systems. This talk will give a brief overview of the PanDA pilot system and will present major features and recent improvements including CernVM File System integration, the job retry mechanism, advanced job monitoring including JEM technology, and validation of new pilot code using the HammerCloud stress-testing system. PanDA is used for all ATLAS distributed production and is the primary system for distributed analysis. It is currently used at over 130 sites worldwide. We analyze the performance of the pilot system in processing LHC data on the OSG, EGI and Nordugrid infrastructures used by ATLAS, and describe plans for its further evolution.

  6. Synthesis of ultrathin face-centered-cubic Au@Pt and Au@Pd core-shell nanoplates from hexagonal-close-packed Au square sheets

    KAUST Repository

    Fan, Zhanxi; Zhu, Yihan; Huang, Xiao; Han, Yu; Wang, Qingxiao; Liu, Qing; Huang, Ying; Gan, Chee Lip; Zhang, Hua

    2015-01-01

    @Pd rhombic nanoplates, respectively. We believe that these findings will shed new light on the synthesis of novel noble bimetallic nanostructures. Phase change: Ultrathin Au@Pt and Au@Pd core-shell nanoplates were prepared from Au square sheets. A phase

  7. Kinetic Investigation of Homogeneous H(2)-D(2) Equilibration Catalyzed by Pt-Au Cluster Compounds. Characterization of the Cluster [(H)Pt(AuPPh(3))(9)](NO(3))(2).

    Science.gov (United States)

    Rubinstein, Leon I.; Pignolet, Louis H.

    1996-11-06

    The new Pt-Au hydrido cluster compound [(H)Pt(AuPPh(3))(9)](NO(3))(2) (3) has been synthesized and characterized by NMR, FABMS, and single-crystal X-ray diffraction [triclinic, P&onemacr;, a = 17.0452(1) Å, b = 17.4045(2) Å, c = 55.2353(1) Å, alpha = 89.891(1) degrees, beta = 85.287(1) degrees, gamma = 75.173(1) degrees, V = 15784.0(2) Å(3), Z = 4 (two molecules in asymmetric unit), residual R = 0.089 for 45 929 observed reflections and 3367 variables, Mo Kalpha radiation]. The Pt(AuP)(9) core geometry is a distorted icosahedron with three vertices vacant. The Pt-Au, Au-Au, and Au-P distances are within the normal ranges observed in other Pt-Au clusters. This cluster is a catalyst for H(2)-D(2) equilibration in homogeneous solution phase and has been used in a general mechanistic study of this reaction catalyzed by Pt-Au clusters. We previously proposed that a key step in the mechanism for catalytic H(2)-D(2) equilibration is the dissociation of a PPh(3) ligand to give a cluster with an open Au site for bonding of H(2) or D(2). This was based on qualitative observations that PPh(3) inhibited the rate of HD production with [Pt(AuPPh(3))(8)](NO(3))(2) (1) as catalyst. In order to test this hypothesis, phosphine inhibition (on the rate of HD production) and phosphine ligand exchange kinetic experiments were carried out with [(H)(PPh(3))Pt(AuPPh(3))(7)](NO(3))(2) (2) and 3. In this paper we show that the rate constant for phosphine dissociation determined from the PPh(3) inhibition rate study of H(2)-D(2) equilibration with cluster 2 is nearly identical to the rate constant for dissociative phosphine ligand exchange. The slower rate for H(2)-D(2) equilibration observed with 3 compared with 2 (5.5 x 10(-3) vs 7.7 x 10(-2) turnover s(-1)) is explained by its smaller rate constant for phosphine dissociation (2.8 x 10(-5) vs 2.9 x 10(-4) s(-1)). The fact that clusters 2 and 3 show similar kinetic behaviors suggests that the PPh(3) dissociation step in the catalytic H(2

  8. Excitation functions for 197Au (d, p)198Au, 197Au(d, 2n)197mHg, 197Au(d, 2n)197Hg and 197Au(d, p2n)196Au

    International Nuclear Information System (INIS)

    Long Xianguan; Peng Xiufeng; He Fuqing

    1987-01-01

    By using activation method and stack-foil technique, the excitation functions for d + 197 Au reaction in 6.6-13.1 MeV energy range are measured. The measured values are compared with previous results and theoretical calculations

  9. Direct atomic imaging and density functional theory study of the Au24Pd1 cluster catalyst.

    Science.gov (United States)

    Bruma, A; Negreiros, F R; Xie, S; Tsukuda, T; Johnston, R L; Fortunelli, A; Li, Z Y

    2013-10-21

    In this study we report a direct, atomic-resolution imaging of calcined Au24Pd1 clusters supported on multiwall carbon nanotubes by employing aberration-corrected scanning transmission electron microscopy. Using gold atoms as mass standards, we confirm the cluster size to be 25 ± 2, in agreement with the Au24Pd1(SR)18 precursor used in the synthesis. Concurrently, a Density-Functional/Basin-Hopping computational algorithm is employed to locate the low-energy configurations of free Au24Pd1 cluster. Cage structures surrounding a single core atom are found to be favored, with a slight preference for Pd to occupy the core site. The cluster shows a tendency toward elongated arrangements, consistent with experimental data. The degree of electron transfer from the Pd dopant to Au is quantified through a Löwdin charge analysis, suggesting that Pd may act as an electron promoter to the surrounding Au atoms when they are involved in catalytic reactions.

  10. Synthesis and characterization in AuCu–Si nanostructures

    International Nuclear Information System (INIS)

    Novelo, T.E.; Amézaga-Madrid, P.; Maldonado, R.D.; Oliva, A.I.; Alonzo-Medina, G.M.

    2015-01-01

    Au/Cu bilayers with different Au:Cu concentrations (25:75, 50:50 and 75:25 at.%) were deposited on Si(100) substrates by thermal evaporation. The thicknesses of all Au/Cu bilayers were 150 nm. The alloys were prepared by thermal diffusion into a vacuum oven with argon atmosphere at 690 K during 1 h. X-ray diffraction analysis revealed different phases of AuCu and CuSi alloys in the samples after annealing process. CuSi alloys were mainly obtained for 25:75 at.% samples, meanwhile the AuCuII phase dominates for samples prepared with 50:50 at.%. Additionally, the Au:Cu alloys with 75:25 at.%, produce Au 2 Cu 3 and Au 3 Cu phases. The formed alloys were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) to study the morphology and the elemental concentration of the formed alloys. - Highlights: • AuCu/Si alloy thin films were prepared by thermal diffusion. • Alloys prepared with 50 at.% of Au produce the AuCuII phase. • Alloys prepared with 75 at.% of Au produce Au 3 Cu and Au 2 Cu 3 phases. • All alloys present diffusion of Si and Cu through the CuSi alloy formation

  11. Au nanoparticles films used in biological sensing

    International Nuclear Information System (INIS)

    Rosales Perez, M; Delgado Macuil, R; Rojas Lopez, M; Gayou, V L; Sanchez Ramirez, J F

    2009-01-01

    Lactobacillus para paracasei are used commonly as functional food and probiotic substances. In this work Au nanoparticles self-assembled films were used for Lactobacillus para paracasei determination at five different concentrations. Functionalized substrates were immersed in a colloidal solution for one and a half hour at room temperature and dried at room temperature during four hours. After that, drops of Lactobacillus para paracasei in aqueous solution were put into the Au nanoparticles film and let dry at room temperature for another two hours. Infrared spectroscopy in attenuated total reflectance sampling mode was used to observe generation peaks due to substrate silanization, enhancement of Si-O band intensity due to the Au colloids added to silanized substrate and also to observe the enhancement of Lactobacillus para paracasei infrared intensity of the characteristic frequencies at 1650, 1534 and 1450 cm -1 due to surface enhancement infrared absorption.

  12. Au nanoparticles films used in biological sensing

    Energy Technology Data Exchange (ETDEWEB)

    Rosales Perez, M; Delgado Macuil, R; Rojas Lopez, M; Gayou, V L [Centro de Investigacion en BiotecnologIa Aplicada del IPN, Tepetitla Tlaxcala Mexico C.P. 90700 (Mexico); Sanchez Ramirez, J F, E-mail: mrosalespe@ipn.m [CICATA Legaria Instituto Politecnico Nacional, Mexico Distrito Federal (Mexico)

    2009-05-01

    Lactobacillus para paracasei are used commonly as functional food and probiotic substances. In this work Au nanoparticles self-assembled films were used for Lactobacillus para paracasei determination at five different concentrations. Functionalized substrates were immersed in a colloidal solution for one and a half hour at room temperature and dried at room temperature during four hours. After that, drops of Lactobacillus para paracasei in aqueous solution were put into the Au nanoparticles film and let dry at room temperature for another two hours. Infrared spectroscopy in attenuated total reflectance sampling mode was used to observe generation peaks due to substrate silanization, enhancement of Si-O band intensity due to the Au colloids added to silanized substrate and also to observe the enhancement of Lactobacillus para paracasei infrared intensity of the characteristic frequencies at 1650, 1534 and 1450 cm{sup -1} due to surface enhancement infrared absorption.

  13. A DFT-based genetic algorithm search for AuCu nanoalloy electrocatalysts for CO2 reduction

    DEFF Research Database (Denmark)

    Lysgaard, Steen; Mýrdal, Jón Steinar Garðarsson; Hansen, Heine Anton

    2015-01-01

    Using a DFT-based genetic algorithm (GA) approach, we have determined the most stable structure and stoichiometry of a 309-atom icosahedral AuCu nanoalloy, for potential use as an electrocatalyst for CO2 reduction. The identified core–shell nano-particle consists of a copper core interspersed....... This shows that the mixed Cu135@Au174 core–shell nanoalloy has a similar adsorption energy, for the most favorable site, as a pure gold nano-particle. Cu, however, has the effect of stabilizing the icosahedral structure because Au particles are easily distorted when adding adsorbates....... that it is possible to use the LCAO mode to obtain a realistic estimate of the molecular chemisorption energy for systems where the computation in normal grid mode is not computationally feasible. These corrections are employed when calculating adsorption energies on the Cu, Au and most stable mixed particles...

  14. Nitrogen treatment from digestat of biogas plants in a moving bed biofilm reactor; Projet de recherche pilote. Traitement de l'azote des digestats issus d'installations de biogaz au moyen d'un reacteur a biofilm sur support mobile - Rapport final

    Energy Technology Data Exchange (ETDEWEB)

    Roches, S.; Bakx, T.; Membrez, Y. [EREP SA, Aclens (Switzerland); Baggenstos, M.; Chappaz, A. [Wabag Water Technology Ltd, Winterthur (Switzerland); Holliger, Ch. [Swiss Federal Institute of Technology, EPFL, Laboratory for Environmental Biotechnology, Lausanne (Switzerland)

    2010-11-15

    Ammonia emissions are a source for polluting ecosystems, causing in particular acidification and eutrophication of the affected areas. In Switzerland 90% of the atmospheric ammonia emissions are due to agriculture, mostly during storage and use of animal manures and slurries. Anaerobic digestion of these manures and slurries produces renewable energy and stabilises the agricultural effluents. However, it does not solve the ammonia problem; on the contrary, it releases an additional amount of ammonium while mineralizing a large part of the organic nitrogen. A previous study dealing with the biological removal of ammonia from digested manures was conducted at the Laboratory of Environmental Biotechnology, EPFL. It has shown that it is possible to obtain simultaneously a conversion of ammonium and nitrogen removal in a same continuously aerated aerobic reactor, using a mobile support for fixing the biomass. The obtained efficiencies were high, with 90% of the ammonium being converted of which 80% as N{sub 2}-gas. This current study proposed to test the process at pilot scale, to evaluate the transferability of the technique to a full-scale application and to determine the operating parameter. The results are as follows: (i) It is possible to obtain high nitrification and denitrification rates without pre-treating the digestat or adding a carbon source; (ii) Biochemical reactions are extremely sensitive to the oxygenation rate, which in turn is very sensitive to the liquid characteristics in the reactor, such as the dry matter content. It fairly complicates maintaining simultaneous nitrification and denitrification; (iii) At a minimum hydraulic residence time of 4 days, over 90% of the ammonium is converted and 85% of it is removed. These results provide the basic design parameters for a full-scale installation. Depending on the performance desired, it would have a volume going from 30 to 60 m{sup 3} for a 400 m{sup 3} digester. The aeration rate would be between 300

  15. Au nanorice assemble electrolytically into mesostars.

    Science.gov (United States)

    Bardhan, Rizia; Neumann, Oara; Mirin, Nikolay; Wang, Hui; Halas, Naomi J

    2009-02-24

    Star-shaped mesotructures are formed when an aqueous suspension of Au nanorice particles, which consist of prolate hematite cores and a thin Au shell, is subjected to an electric current. The nanorice particles assemble to form hyperbranched micrometer-scale mesostars. To our knowledge, this is the first reported observation of nanoparticle assembly into larger ordered structures under the influence of an electrochemical process (H(2)O electrolysis). The assembly is accompanied by significant modifications in the morphology, dimensions, chemical composition, crystallographic structure, and optical properties of the constituent nanoparticles.

  16. Development of 1000kW-class MCFC pilot plant

    Energy Technology Data Exchange (ETDEWEB)

    Ooue, M.; Yasue, H. [MCFC Research Association, Mie (Japan); Takasu, K.; Tsuchitori, T.

    1996-12-31

    This pilot plant is a part of the New Sunshine Program which has proceeded by the Agency of Industrial Science and Technology of the Ministry of International Trade and Industry. MCFC Research Association is entrusted with the development of the pilot plant, and constructing it at Kawagoe site. Following items will be verified by this pilot plant operation. (a) Development of 250kW class stack and confirmation of stack performance and decay rate. (b) System verification such as basic process, control system and operation characteristics, toward commercialization. (c) To get design data for demonstration plant.

  17. La Nuit des Chercheurs au CERN / Researchers' Night at CERN

    CERN Multimedia

    CERN. Geneva; Pohl, Martin; Paniccia, Mercedes

    2017-01-01

    Vendredi 29 septembre 2017 de 17h à 23h Entrée libre - pas d'inscription nécessaire. Depuis maintenant 8 ans, le Laboratoire ouvre ses portes en soirée au grand public, à l’occasion de cette fête scientifique. C’est un plaisir d’accueillir tous ces curieux et de partager les découvertes de la science, toutes plus étonnantes les unes que les autres. L’invention du Web en est une particulièrement intégrée au quotidien, mais il y en a tellement d’autres ! Venez découvrir cette science insoupçonnée et en prendre plein les yeux ! Le programme est prêt ! Nous sommes ravis de vous présenter toutes les activités que nous avons prévues pour vous, scientifiques en herbe, novices ou aficionados de tout âge . Il y aura même une surprise pour les 400 premiers visiteurs ! Activités sur le site du CERN Activités en ligne (Facebook Live) Nous avons hâte de vous accueillir !     ...

  18. First-principles investigations of O2 dissociation on low-coordinated Pd ensembles over stepped Au surfaces

    International Nuclear Information System (INIS)

    Yuan, D.W.; Liu, Z.R.; Xu, Y.

    2012-01-01

    The adsorption and dissociation of O 2 on Pd monomer or trimer incorporated into Au(322) and Au(321) surfaces are systematically investigated by first-principles calculations and nudged-elastic-band simulations. We found that the contiguous low-coordinated Pd ensembles alloyed into step edges of Au surfaces are required for O 2 dissociation with an enhanced adsorption energy (∼−1.00 eV). The dissociative barrier of O 2 is mainly related to the size of Pd ensembles, and the activation energy is about 1.00 eV on Pd trimers. However, the Pd monomer is less active for the adsorption and dissociation of O 2 . Additionally, the O spillover from Pd to Au sites only occurs at elevated temperature, and the diffusion processes are highly endothermic. The calculated results indicate that the Pd-modified Au step edge with a contiguous Pd ensemble is the reactive center for supplying atomic oxygen on Pd-doped Au catalysts. -- Highlights: ► Our results reveal the mechanism of O 2 dissociation on Pd-decorated stepped Au surfaces. ► The adsorption energy of O 2 is related to both coordination numbers and geometrical arrangements of Pd atoms alloyed into Au surface. ► The Pd-modified Au step with a contiguous Pd ensemble is the reactive center for O 2 dissociation. ► Our results are important for understanding the catalytic properties of Pd-modified nanoporous gold, especially for those catalytic reactions related to O 2 activation.

  19. Influence of Au Nanoparticle Shape on Au@Cu2O Heterostructures

    OpenAIRE

    Zhu, Jie; Lu, Na; Chen, Wei; Kong, Lina; Yang, Yun; Ma, Dekun; Huang, Shaoming

    2015-01-01

    Synthesis of metal-semiconductor heterostructures may allow the combination of function of the corresponding components and/or the enhanced performance resulting from the interactions between all the components. In this paper, Au@Cu2O core-shell heterostructures are prepared by a seed-growth method, using different-shaped Au nanocrystals as the seeds such as nanorods, octahedra, decahedra, dots, and nanocubes. The results revealed that the final structure of Au@Cu2O was greatly influenced by ...

  20. Surface chemistry of 2-butanol and furfural on Cu, Au and Cu/Au single crystals

    OpenAIRE

    Megginson, Rory

    2016-01-01

    In this study, the adsorption of 2-butanol and furfural was investigated on Au (111), Cu (111) and Cu/Au (111) surfaces. It was hoped that by studying how these species adsorbed on these surfaces , insight would be provided into the roles of Cu and Au in the “hydrogen free” hydrogenation of furfural to furfuryl alcohol. This is a valuable process as currently furfuryl alcohol is derived from crude oil but it is possible to derive furfural from corn husk making it a greener process...

  1. Pilot Weather Reports

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Aviation weather reports relayed from pilots to FAA air traffic controllers or National Weather Service personnel. Elements include sky cover, turbulence, wind...

  2. Agile Web Pilot Program

    National Research Council Canada - National Science Library

    Lang, Mark

    1997-01-01

    ... in an increasingly competitive global marketplace. The pilot program allowed 18 small and medium sized enterprises to experiment with new agile business practices in competitive manufacturing environments by forming virtual organizations within...

  3. Radioactive-waste isolation pilot plant

    International Nuclear Information System (INIS)

    Weart, W.D.

    1977-01-01

    The objective of the Waste Isolation Pilot Plant (WIPP) program is to demonstrate the suitability of bedded salt, specifically, the bedded salt deposits in the Los Medanos area of southeastern New Mexico, as a disposal medium for radioactive wastes. Our program responsibilities include site selection considerations, all aspects of design and development, technical guidance of facility operation, environmental impact assessment, and technical support to ERDA for developing public understanding of the facility

  4. The effect of CNTs on structures and catalytic properties of AuPd clusters for H2O2 synthesis.

    Science.gov (United States)

    Yang, Hua-feng; Xie, Peng-yang; Yu, Hui-you; Li, Xiao-nian; Wang, Jian-guo

    2012-12-28

    The structures and catalytic properties of AuPd clusters supported on carbon nanotubes (CNTs) for H(2)O(2) synthesis have been investigated by means of density functional theory calculations. Firstly, the structures of AuPd clusters are strongly influenced by CNTs, in which the bottom layers are mainly composed of Pd and the top layers are a mix of Au and Pd due to the stronger binding of Pd than Au on CNTs. Especially, it is found that O(2) adsorption on the Pd/CNTs interfacial sites is much weaker than that on the only Pd sites, which is in contrast to transition metal oxide (for example TiO(2), Al(2)O(3), CeO(2)) supported metal clusters. Furthermore, Pd ensembles on the interfacial sites have far superior catalytic properties for H(2)O(2) formation than those away from CNT supports due to the changes in electronic structures caused by the CNTs. Therefore, our study provides a physical insight into the enhanced role of carbon supports in H(2)O(2) synthesis over supported AuPd catalysts.

  5. Tin-phthalocyanine adsorption and diffusion on Cu and Au (111) surfaces: A density functional theory study

    Science.gov (United States)

    Qin, Dan; Ge, Xu-Jin; Lü, Jing-Tao

    2018-05-01

    Through density functional theory based calculations, we study the adsorption and diffusion of tin phthalocyanine (SnPc) molecule on Au(111) and Cu(111) surfaces. SnPc has two conformers with Sn pointing to the vacuum (Sn-up) and substrate (Sn-down), respectively. The binding energies of the two conformers with different adsorption sites on the two surfaces, including top, bridge, fcc, hcp, are calculated and compared. It is found that the SnPc molecule binds stronger on Cu(111) surface, with binding energy about 1 eV larger than that on Au(111). Only the bridge and top adsorption sites are stable on Cu(111), while all the four adsorption sites are stable on Au(111), with small diffusion barriers between them. Moreover, the flipping barrier from Sn-up to Sn-down conformer is of the same magnitude on the two metal surfaces. These results are consistent with a recent experiment [Zhang, et al., Angew. Chem., 56, 11769 (2017)], which shows that conformation change from Sn-up to Sn-down on Cu(111) surface can be induced by a C60-functionalized STM tip, while similar change is difficult to realize on Au(111), due to smaller diffusion barrier on Au(111).

  6. (DEEE) au Sénégal

    African Journals Online (AJOL)

    utilisateurs professionnels ont moins de 40 ans; 65,9% des réparateurs sont âgés au plus de 36 ans. Les acteurs de sexe ..... conséquences négatives des DEEE sur la santé ..... Chine où un réseau de coopération entre les institutions ...

  7. 370 emplois auraient ete supprimes au CERN

    CERN Multimedia

    Benoit-Godet, S

    2002-01-01

    "La FTMH demande un plan social pour les salaries des sous-traitants.  Environ 370 postes ont ete supprimes au CERN ces douze derniers mois.» Alain Perrat, secretaire de la FTMH, tire la sonnette d'alarme" (1 page).

  8. Surface structure of AU3Cu(001)

    DEFF Research Database (Denmark)

    Eckstein, G.A.; Maupai, S.; Dakkouri, A.S.

    1999-01-01

    The surface morphology, composition, and structure of Au3Cu(001) as determined by scanning tunneling microscopy and surface x-ray diffraction are presented. Atomic resolution STM images reveal distinctive geometric features. The analysis of the surface x-ray diffraction data provides clear evidence...... for the surface structure. [S0163-1829(99)04535-X]....

  9. Nanoporous Au: an unsupported pure gold catalyst?

    Energy Technology Data Exchange (ETDEWEB)

    Wittstock, A; Neumann, B; Schaefer, A; Dumbuya, K; Kuebel, C; Biener, M; Zielasek, V; Steinrueck, H; Gottfried, M; Biener, J; Hamza, A; B?umer, M

    2008-09-04

    The unique properties of gold especially in low temperature CO oxidation have been ascribed to a combination of various effects. In particular, particle sizes below a few nm and specific particle-support interactions have been shown to play important roles. On the contrary, recent reports revealed that monolithic nanoporous gold (npAu) prepared by leaching a less noble metal, such as Ag, out of the corresponding alloy can also exhibit remarkably high catalytic activity for CO oxidation, even though no support is present. Therefore, it was claimed to be a pure and unsupported gold catalyst. We investigated npAu with respect to its morphology, surface composition and catalytic properties. In particular, we studied the reaction kinetics for low temperature CO oxidation in detail taking mass transport limitation due to the porous structure of the material into account. Our results reveal that Ag, even if removed almost completely from the bulk, segregates to the surface resulting in surface concentrations of up to 10 at%. Our data suggest that this Ag plays a significant role in activation of molecular oxygen. Therefore, npAu should be considered as a bimetallic catalyst rather than a pure Au catalyst.

  10. HYPERTENSION AU COURS DE LA GROSSESSE: Aspects ...

    African Journals Online (AJOL)

    hypertension soit une prévalence de 8,2%. Cette pathologie survient dans notre .... consultations prénatales ou le post-partum. Sur le plan clinique, la ... des patientes étaient au terme de leur grossesse alors que 22.11%, avaient un âge ...

  11. A reagentless amperometric immunosensor based on nano-au and ...

    African Journals Online (AJOL)

    Jane

    2011-08-01

    Aug 1, 2011 ... which was then mixed with AU nanoparticles (nano-Au) and multi-walled carbon nanotubes (MWCNTs) ..... Kaminishi D, Ozaki H, Ohno Y, Maehashi K, Inoue K, Matsumoto K, Seri ... nanoparticle doped chitosan film. Anal.

  12. Molecules on vicinal Au surfaces studied by scanning tunnelling microscopy

    International Nuclear Information System (INIS)

    Kroeger, J; Neel, N; Jensen, H; Berndt, R; Rurali, R; Lorente, N

    2006-01-01

    Using low-temperature scanning tunnelling microscopy and spectroscopy we investigated the adsorption characteristics of 3,4,9,10-perylenetetracarboxylic-dianhydride and fullerenes on Au(788), Au(433), and Au(778). On Au(788) and Au(778), 3,4,9,10-perylenetetracarboxylic-dianhydride exhibits three coexisting superstructures, which do not reflect the periodicity of the hosting substrate. The adsorption on Au(433) leads to the formation of molecule chains along the step edges after annealing the sample. Fullerene molecules on Au(788) arrange in a mesh of islands, which extends over several hundreds of nanometres with an extraordinarily high periodicity. A combination of fullerene adsorption and annealing leads to facetting of Au(433) and the formation of extraordinarily long fullerene stripes

  13. Pilot demonstrations of arsenic removal technologies.

    Energy Technology Data Exchange (ETDEWEB)

    Siegal Malcolm D.

    2004-09-01

    The Arsenic Water Technology Partnership (AWTP) program is a multi-year program funded by a congressional appropriation through the Department of Energy to develop and test innovative technologies that have the potential to reduce the costs of arsenic removal from drinking water. The AWTP members include Sandia National Laboratories, the American Water Works Association (Awwa) Research Foundation and WERC (A Consortium for Environmental Education and Technology Development). The program is designed to move technologies from bench-scale tests to field demonstrations. The Awwa Research Foundation is managing bench-scale research programs; Sandia National Laboratories is conducting the pilot demonstration program and WERC will evaluate the economic feasibility of the technologies investigated and conduct technology transfer activities. The objective of the Sandia Arsenic Treatment Technology Demonstration project (SATTD) is the field demonstration testing of both commercial and innovative technologies. The scope for this work includes: (1) Identification of sites for pilot demonstrations; (2) Accelerated identification of candidate technologies through Vendor Forums, proof-of-principle laboratory and local pilot-scale studies, collaboration with the Awwa Research Foundation bench-scale research program and consultation with relevant advisory panels; and (3) Pilot testing multiple technologies at several sites throughout the country, gathering information on: (a) Performance, as measured by arsenic removal; (b) Costs, including capital and Operation and Maintenance (O&M) costs; (c) O&M requirements, including personnel requirements, and level of operator training; and (d) Waste residuals generation. The New Mexico Environment Department has identified over 90 public water systems that currently exceed the 10 {micro}g/L MCL for arsenic. The Sandia Arsenic Treatment Technology Demonstration project is currently operating pilots at three sites in New Mexico. The cities of

  14. Three-particle correlations from parton cascades in Au+Au collisions

    International Nuclear Information System (INIS)

    Ma, G.L.; Ma, Y.G.; Zhang, S.; Cai, X.Z.; Chen, J.H.; He, Z.J.; Huang, H.Z.; Long, J.L.; Shen, W.Q.; Shi, X.H.; Zhong, C.; Zuo, J.X.

    2007-01-01

    We present a study of three-particle correlations among a trigger particle and two associated particles in Au+Au collisions at s NN =200 GeV using a multi-phase transport model (AMPT) with both partonic and hadronic interactions. We found that three-particle correlation densities in different angular directions with respect to the triggered particle ('center', 'cone', 'deflected', 'near' and 'near-away') increase with the number of participants. The ratio of 'deflected' to 'cone' density approaches to 1.0 with the increasing of number of participants, which indicates that partonic Mach-like shock waves can be produced by strong parton cascades in central Au+Au collisions

  15. pH-Induced transformation of ligated Au25 to brighter Au23 nanoclusters.

    Science.gov (United States)

    Waszkielewicz, Magdalena; Olesiak-Banska, Joanna; Comby-Zerbino, Clothilde; Bertorelle, Franck; Dagany, Xavier; Bansal, Ashu K; Sajjad, Muhammad T; Samuel, Ifor D W; Sanader, Zeljka; Rozycka, Miroslawa; Wojtas, Magdalena; Matczyszyn, Katarzyna; Bonacic-Koutecky, Vlasta; Antoine, Rodolphe; Ozyhar, Andrzej; Samoc, Marek

    2018-05-01

    Thiolate-protected gold nanoclusters have recently attracted considerable attention due to their size-dependent luminescence characterized by a long lifetime and large Stokes shift. However, the optimization of nanocluster properties such as the luminescence quantum yield is still a challenge. We report here the transformation of Au25Capt18 (Capt labels captopril) nanoclusters occurring at low pH and yielding a product with a much increased luminescence quantum yield which we have identified as Au23Capt17. We applied a simple method of treatment with HCl to accomplish this transformation and we characterized the absorption and emission of the newly created ligated nanoclusters as well as their morphology. Based on DFT calculations we show which Au nanocluster size transformations can lead to highly luminescent species such as Au23Capt17.

  16. Feasibility of Seismic Monitoring at a Potential CO2 Injection Test Site in the Paris Basin Évaluation des apports de la sismique à la surveillance d’un test d’injection de CO2 sur un site pilote potentiel du Bassin de Paris

    Directory of Open Access Journals (Sweden)

    Becquey M.

    2009-09-01

    Full Text Available Seismic effects of the injection of CO2 into a partially depleted oil field have been evaluated. Seismic modelling yields small time-lapse effects, including 0.4 ms time-shifts and 4 to 6% amplitude variations at the top and bottom of the reservoir. Amplitude variations at the reservoir level should be slightly larger at large incidence angles, but wave equation modelling shows that picking these reflections will not be easy, because of the presence of shear waves generated at upper interfaces. In-situ fracturation generates azimuthal anisotropy with velocity and amplitude variations with the propagation direction. These variations bear some information about the crack density, about the relation between the fracture nets and the porous medium, and about the fluid content in the pores and fractures. All these effects are however weak and their measurement requires careful seismic data acquisition and processing. Les effets sismiques de l’injection de dioxyde de carbone dans un gisement de petrole deplete ont fait l’objet d’une simulation. Ces effets sont faibles. On peut s’attendre a une variation des temps d’arrivee des reflexions sur des interfaces situees en dessous des reservoirs, de l’ordre de la demi-milliseconde, et a une variation d’amplitude au toit et au mur du reservoir de l’ordre de 6 %. La variation d’amplitude sera legerement plus forte pour les reflexions a grand deport, mais le pointe des reflexions et la mesure des amplitudes seront probablement plus difficiles, en raison de la presence d’ondes converties. La mesure de l’anisotropie azimutale, due a la presence de fractures, peut nous donner des informations sur l’etat de fracturation du reservoir et sur la connexion entre ces fractures et la matrice poreuse. La mesure de ces variations subtiles necessitera une acquisition soignee et un traitement precautionneux des donnees.

  17. Synthesis and characterization of Au incorporated Alq3 nanowires

    Science.gov (United States)

    Khan, Mohammad Bilal; Ahmad, Sultan; Parwaz, M.; Rahul, Khan, Zishan H.

    2018-05-01

    We report the synthesis and characterization of pure and Au incorporated Alq3 nanowires. These nanowires are synthesized using thermal vapor transport method. The luminescence intensity of Au incorporated Alq3 nanowires are recorded to be higher than that of pure Alq3 nanowires, which is found to increase with the increase in Au concentration. Fluorescence quenching is also observed when Au concentration is increased beyond the certain limit.

  18. Energy dependence of collective flow of neutrons and charged particles in 197Au+197Au collisions

    International Nuclear Information System (INIS)

    Blaich, T.; Freiesleben, H.; Holzmann, R.; Keller, J.G.; Prokopowicz, W.; Schuetter, C.; Wajda, E.; Zude, E.

    1994-01-01

    Our contribution focusses on one particular aspect of collective flow of nuclear matter: the so-called ''squeeze-out'', i.e. the preferential emission of mid-rapidity particles perpendicular to the reaction plane. The data were taken for the system 197 Au + 197 Au at 400, 600 and 800 MeV/u. We cover two topics, the comparison of neutrons and protons, and the bombarding energy dependence of the neutrons' squeeze-out. (orig.)

  19. Appui au réseautage et au renforcement des télécentres ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    En Afrique de l'Ouest francophone, les télécentres luttent pour atteindre la viabilité financière tout en demeurant au diapason des collectivités, une situation qui tient au fait qu'ils ont accès à un moins grand nombre de ressources en ligne et à une communauté d'utilisateurs plus restreinte que les télécentres anglophones.

  20. Strangeness production in Au+Au collisions at the AGS: recent results from E917

    International Nuclear Information System (INIS)

    Chang, W.-C.; Back, B.B.; Betts, R.R.; Britt, H.C.; Chang, W.C.; Gillitzer, A.; Henning, W.F.; Hofman, D.J.; Holzman, B.; Nanal, V.; Wuosmaa, A.H.

    1999-01-01

    Strangeness production in Au+Au collisions has been measured via the yields of K + , K - at 6, 8 AGeV and of bar Λ at 10.8 AGeV beam kinetic energy in experiment E917. By varying the collision centrally and beam energy, a systematic search for indications of new phenomena and in-medium effects under high baryon density is undertaken

  1. Pondération de la base juridique du droit au logement au Zimbabwe ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    13 déc. 2016 ... La criminalité et la pauvreté au Ghana urbain. La manière dont la criminalité et la pauvreté interagissent a été étudiée et débattue dans la littérature de recherche occidentale, mais on sait pe. Voir davantageLa criminalité et la pauvreté au Ghana urbain ...

  2. Flow and bose-einstein correlations in Au-Au collisions at RHIC

    Science.gov (United States)

    Phobos Collaboration; Manly, Steven; Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; Garcia, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Henderson, C.; Hofman, D.; Hollis, R. S.; Hołyinski, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Michałowski, J.; Mignerey, A.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S. F.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wadsworth, B.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2003-03-01

    Argonne flow and Bose-Einstein correlations have been measured in Au-Au collisions at S=130 and 200 GeV using the PHOBOS detector at RHIC. The systematic dependencies of the flow signal on the transverse momentum, pseudorapidity, and centrality of the collision, as well as the beam energy are shown. In addition, results of a 3-dimensional analysis of two-pion correlations in the 200 GeV data are presented.

  3. The effect of Au amount on size uniformity of self-assembled Au nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Chen, S-H; Wang, D-C; Chen, G-Y; Chen, K-Y [Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology, Taiwan (China)

    2008-03-15

    The self-assembled fabrication of nanostructure, a dreaming approach in the area of fabrication engineering, is the ultimate goal of this research. A finding was proved through previous research that the size of the self-assembled gold nanoparticles could be controlled with the mole ratio between AuCl{sub 4}{sup -} and thiol. In this study, the moles of Au were fixed, only the moles of thiol were adjusted. Five different mole ratios of Au/S with their effect on size uniformity were investigated. The mole ratios were 1:1/16, 1:1/8, 1:1, 1:8, 1:16, respectively. The size distributions of the gold nanoparticles were analyzed by Mac-View analysis software. HR-TEM was used to derive images of self-assembled gold nanoparticles. The result reached was also the higher the mole ratio between AuCl{sub 4}{sup -} and thiol the bigger the self-assembled gold nanoparticles. Under the condition of moles of Au fixed, the most homogeneous nanoparticles in size distribution derived with the mole ratio of 1:1/8 between AuCl{sub 4}{sup -} and thiol. The obtained nanoparticles could be used, for example, in uniform surface nanofabrication, leading to the fabrication of ordered array of quantum dots.

  4. A reagentless amperometric immunosensor based on nano-au and ...

    African Journals Online (AJOL)

    In this paper, carboxyl-ferrocene (Fc-COOH) was explored to label alphafetoprotein antibody (anti-AFP), which was then mixed with AU nanoparticles (nano-Au) and multi-walled carbon nanotubes (MWCNTs) dispersed by chitosan (CS) to form the nano-Au/MWCNTs/anti-AFP-Fc chitosan composite. After that, the composite ...

  5. Viscoelastic nature of Au nanoparticle–PDMS nanocomposite gels

    Indian Academy of Sciences (India)

    A stable gel of Au nanoparticles in polydimethylsiloxane (PDMS) nanocomposite is prepared by employing the curing agent of PDMS elastomer as a reducing agent for the formation of Au nanoparticles by an in-situ process. The viscoelastic nature of these gels is very sensitive to the Au nanoparticle loading and the ...

  6. The point-defect of carbon nanotubes anchoring Au nanoparticles

    DEFF Research Database (Denmark)

    Lv, Y. A.; Cui, Y. H.; Li, X. N.

    2010-01-01

    The understanding of the interaction between Au and carbon nanotubes (CNTs) is very important since Au/CNTs composites have wide applications in many fields. In this study, we investigated the dispersion of Au nanoparticles on the CNTs by transmission electron microscopy and the bonding mechanism...

  7. Preparation and use of 195m Au-containing liquid

    International Nuclear Information System (INIS)

    Panek, K.J.

    1983-01-01

    A 195m Au-containing liquid is prepared by adsorbing 195m-Hg on an adsorption agent and then eluting the daughter radioisotope 195m-Au. A radioisotope generator and the adsorption agent to be used in preparation of 195m Au-containing liquids are also claimed

  8. Anomolous, intensity dependent losses in Au(32+) beams

    International Nuclear Information System (INIS)

    Blaskiewicz, M.; Ahrens, L.; Calvani, H.

    1997-01-01

    The AGS Booster is a rapid cycling proton and heavy ion synchrotron. Anomolous, intensity dependent losses in Au(32+) beams have been observed in the AGS Booster. No collective signal is expected, or observed, but increasing the number of injected ions decreases the beam lifetime. The loss rates for Au(32+) are compared with those for Au(15+)

  9. Electrochemical fabrication of clean dendritic Au supported Pt clusters for electrocatalytic oxidation of formic acid

    International Nuclear Information System (INIS)

    Xia Yue; Liu Jun; Huang Wei; Li Zelin

    2012-01-01

    Highlights: ► A smooth Au surface was rebuilt into clean dendrite via square wave potential pulses. ► It was performed in blank H 2 SO 4 solution without Au(III) species and other additives. ► Dendritic Au provided certain advantage for dispersing Pt due to its unique structure. ► Pt-decorated dendritic Au demonstrated high activity for the HCOOH electrooxidation. - Abstract: We report here the fabrication of clean dendritic gold (DG) directly on a smooth Au electrode via square wave potential pulses (SWPPs) in a blank H 2 SO 4 solution containing no Au(III) species and additives. The effects of potential range, frequency and duration time of SWPPs and H 2 SO 4 concentration on the construction of DG were systematically investigated. A possible mechanism was proposed to explain the growth of DG. The whole process was templateless and surfactantless, and therefore effectively avoided possible contaminations that occurred in other synthetic routes. Further, the prepared DG electrode functioned as a scaffold to support electrodeposited Pt clusters, producing Pt-decorated DG (Pt-DG) electrodes. The electrocatalytic properties of Pt-DG electrodes with various Pt loadings were examined for the oxidation of formic acid. The low Pt loading Pt-DG demonstrated different electrochemical behavior from that on Pt-decorated smooth gold (Pt-SG) and on Pt-decorated gold nanoparticles because there were more defect sites like steps and edges on the DG surface. Ensemble effect, as well as electronic effect, accounts for the improved electrocatalytic activity of low Pt loading Pt-DG.

  10. φ meson production in Au + Au and p + p collisions at √sNN=200 GeV

    International Nuclear Information System (INIS)

    Adams, J.; Adler, C.; Aggarwal, M.M.; Ahammed, Z.; Amonett, J.; Anderson, B.D.; Arkhipkin, D.; Averichev, G.S.; Badyal, S.K.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellwied, R.; Berger, J.; Bezverkhny, B.I.; Bhardwaj, S.; Bhati, A.K.; Bichsel, H.; Billmeier, A.; Bland, L.C.; Blyth, C.O.; Bonner, B.E.; Botje, M.; Boucham, A.; Brandin, A.; Bravar, A.; Cadman, R.V.; Cai, X.Z.; Caines, H.; Calderon de la Barca Sanchez, M.; Carroll, J.; Castillo, J.; Cebra, D.; Chaloupka, P.; Chattopadhyay, S.; Chen, H.F.; Chen, Y.; Chernenko, S.P.; Cherney, M.; Chikanian, A.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Cramer, J.G.; Crawford, H.J.; Das, D.; Das, S.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Dong, W.J.; Dong, X.; Draper, J.E.; Du, F.; Dubey, A.K.; Dunin, V.B.; Dunlop, J.C.; Dutta Majumdar, M.R.; Eckardt, V.; Efimov, L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Faine, V.; Faivre, J.; Fatemi, R.; Filimonov, K.; Filip, P.; Finch, E.; Fisyak, Y.; Flierl, D.; Foley, K.J.; Fu, J.; Gagliardi, C.A.; Gagunashvili, N.; Gans, J.; Ganti, M.S.; Gaudichet, L.; Germain, M.; Geurts, F.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J.E.; Grachov, O.; Grebenyuk, O.; Gronstal, S.; Grosnick, D.; Guedon, M.; Guertin, S.M.; Gupta, A.; Gutierrez, T.D.; Hallman, T.J.; Hamed, A.; Hardtke, D.; Harris, J.W.; Heinz, M.; Henry, T.W.; Heppelmann, S.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffmann, G.W.; Horsley, M.; Huang, H.Z.; Huang, S.L.; Hughes, E.; Humanic, T.J.; Igo, G.; Ishihara, A.; Jacobs, P.; Jacobs, W.W.; Janik, M.; Johnson, I.; Jones, P.G.; Judd, E.G.; Kabana, S.; Kaplan, M.; Keane, D.; Khodyrev; Kiryluk, J.; Kisiel, A.; Klay, J.; Klein, S.R.; Klyachko, A.; Koetke, D.D.; Kollegger, T.; Kopytine, S.M.; Kotchenda, L.; Kovalenko, A.D.; Kramer, M.; Kravtsov, P.; Kravstov, V.I.; Krueger, K.; Kuhn, C.; Kulikov, A.I.; Kumar, A.; Kunde, G.J.; Kunz, C.L.; Kutuev, R.Kh.

    2004-01-01

    We report the STAR measurement of ψ meson production in Au + Au and p + p collisions at √s NN = 200 GeV. Using the event mixing technique, the ψ spectra and yields are obtained at midrapidity for five centrality bins in Au+Au collisions and for non-singly-diffractive p+p collisions. It is found that the ψ transverse momentum distributions from Au+Au collisions are better fitted with a single-exponential while the p+p spectrum is better described by a double-exponential distribution. The measured nuclear modification factors indicate that ψ production in central Au+Au collisions is suppressed relative to peripheral collisions when scaled by the number of binary collisions ( bin >). The systematics of T > versus centrality and the constant ψ/K - ratio versus beam species, centrality, and collision energy rule out kaon coalescence as the dominant mechanism for ψ production

  11. Jet-Hadron Correlations in √sNN =200 GeV p +p and Central Au +Au Collisions

    Science.gov (United States)

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Alford, J.; Anson, C. D.; Aparin, A.; Arkhipkin, D.; Aschenauer, E. C.; Averichev, G. S.; Banerjee, A.; Beavis, D. R.; Bellwied, R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bichsel, H.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Borowski, W.; Bouchet, J.; Brandin, A. V.; Brovko, S. G.; Bültmann, S.; Bunzarov, I.; Burton, T. P.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Cebra, D.; Cendejas, R.; Cervantes, M. C.; Chaloupka, P.; Chang, Z.; Chattopadhyay, S.; Chen, H. F.; Chen, J. H.; Chen, L.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Chwastowski, J.; Codrington, M. J. M.; Contin, G.; Cramer, J. G.; Crawford, H. J.; Cui, X.; Das, S.; Davila Leyva, A.; De Silva, L. C.; Debbe, R. R.; Dedovich, T. G.; Deng, J.; Derevschikov, A. A.; Derradi de Souza, R.; Dhamija, S.; di Ruzza, B.; Didenko, L.; Dilks, C.; Ding, F.; Djawotho, P.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Du, C. M.; Dunkelberger, L. E.; Dunlop, J. C.; Efimov, L. G.; Engelage, J.; Engle, K. S.; Eppley, G.; Eun, L.; Evdokimov, O.; Eyser, O.; Fatemi, R.; Fazio, S.; Fedorisin, J.; Filip, P.; Finch, E.; Fisyak, Y.; Flores, C. E.; Gagliardi, C. A.; Gangadharan, D. R.; Garand, D.; Geurts, F.; Gibson, A.; Girard, M.; Gliske, S.; Greiner, L.; Grosnick, D.; Gunarathne, D. S.; Guo, Y.; Gupta, A.; Gupta, S.; Guryn, W.; Haag, B.; Hamed, A.; Han, L.-X.; Haque, R.; Harris, J. W.; Heppelmann, S.; Hirsch, A.; Hoffmann, G. W.; Hofman, D. J.; Horvat, S.; Huang, B.; Huang, H. Z.; Huang, X.; Huck, P.; Humanic, T. J.; Igo, G.; Jacobs, W. W.; Jang, H.; Judd, E. G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Kesich, A.; Khan, Z. H.; Kikola, D. P.; Kisel, I.; Kisiel, A.; Koetke, D. D.; Kollegger, T.; Konzer, J.; Koralt, I.; Kotchenda, L.; Kraishan, A. F.; Kravtsov, P.; Krueger, K.; Kulakov, I.; Kumar, L.; Kycia, R. A.; Lamont, M. A. C.; Landgraf, J. M.; Landry, K. D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; LeVine, M. J.; Li, C.; Li, W.; Li, X.; Li, X.; Li, Y.; Li, Z. M.; Lisa, M. A.; Liu, F.; Ljubicic, T.; Llope, W. J.; Lomnitz, M.; Longacre, R. S.; Luo, X.; Ma, G. L.; Ma, Y. G.; Madagodagettige Don, D. M. M. D.; Mahapatra, D. P.; Majka, R.; Margetis, S.; Markert, C.; Masui, H.; Matis, H. S.; McDonald, D.; McShane, T. S.; Minaev, N. G.; Mioduszewski, S.; Mohanty, B.; Mondal, M. M.; Morozov, D. A.; Mustafa, M. K.; Nandi, B. K.; Nasim, Md.; Nayak, T. K.; Nelson, J. M.; Nigmatkulov, G.; Nogach, L. V.; Noh, S. Y.; Novak, J.; Nurushev, S. B.; Odyniec, G.; Ogawa, A.; Oh, K.; Ohlson, A.; Okorokov, V.; Oldag, E. W.; Olvitt, D. L., Jr.; Pachr, M.; Page, B. S.; Pal, S. K.; Pan, Y. X.; Pandit, Y.; Panebratsev, Y.; Pawlak, T.; Pawlik, B.; Pei, H.; Perkins, C.; Peryt, W.; Pile, P.; Planinic, M.; Pluta, J.; Poljak, N.; Porter, J.; Poskanzer, A. M.; Pruthi, N. K.; Przybycien, M.; Pujahari, P. R.; Putschke, J.; Qiu, H.; Quintero, A.; Ramachandran, S.; Raniwala, R.; Raniwala, S.; Ray, R. L.; Riley, C. K.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Ross, J. F.; Roy, A.; Ruan, L.; Rusnak, J.; Rusnakova, O.; Sahoo, N. R.; Sahu, P. K.; Sakrejda, I.; Salur, S.; Sandweiss, J.; Sangaline, E.; Sarkar, A.; Schambach, J.; Scharenberg, R. P.; Schmah, A. M.; Schmidke, W. B.; Schmitz, N.; Seger, J.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P. V.; Shao, M.; Sharma, B.; Shen, W. Q.; Shi, S. S.; Shou, Q. Y.; Sichtermann, E. P.; Singaraju, R. N.; Skoby, M. J.; Smirnov, D.; Smirnov, N.; Solanki, D.; Sorensen, P.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Stevens, J. R.; Stock, R.; Strikhanov, M.; Stringfellow, B.; Sumbera, M.; Sun, X.; Sun, X. M.; Sun, Y.; Sun, Z.; Surrow, B.; Svirida, D. N.; Symons, T. J. M.; Szelezniak, M. A.; Takahashi, J.; Tang, A. H.; Tang, Z.; Tarnowsky, T.; Thomas, J. H.; Timmins, A. R.; Tlusty, D.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Trzeciak, B. A.; Tsai, O. D.; Turnau, J.; Ullrich, T.; Underwood, D. G.; Van Buren, G.; van Nieuwenhuizen, G.; Vandenbroucke, M.; Vanfossen, J. A.; Varma, R.; Vasconcelos, G. M. S.; Vasiliev, A. N.; Vertesi, R.; Videbæk, F.; Viyogi, Y. P.; Vokal, S.; Vossen, A.; Wada, M.; Wang, F.; Wang, G.; Wang, H.; Wang, J. S.; Wang, X. L.; Wang, Y.; Wang, Y.; Webb, G.; Webb, J. C.; Westfall, G. D.; Wieman, H.; Wissink, S. W.; Witt, R.; Wu, Y. F.; Xiao, Z.; Xie, W.; Xin, K.; Xu, H.; Xu, J.; Xu, N.; Xu, Q. H.; Xu, Y.; Xu, Z.; Yan, W.; Yang, C.; Yang, Y.; Yang, Y.; Ye, Z.; Yepes, P.; Yi, L.; Yip, K.; Yoo, I.-K.; Yu, N.; Zawisza, Y.; Zbroszczyk, H.; Zha, W.; Zhang, J. B.; Zhang, J. L.; Zhang, S.; Zhang, X. P.; Zhang, Y.; Zhang, Z. P.; Zhao, F.; Zhao, J.; Zhong, C.; Zhu, X.; Zhu, Y. H.; Zoulkarneeva, Y.; Zyzak, M.; STAR Collaboration

    2014-03-01

    Azimuthal angular correlations of charged hadrons with respect to the axis of a reconstructed (trigger) jet in Au +Au and p +p collisions at √sNN =200 GeV in STAR are presented. The trigger jet population in Au +Au collisions is biased toward jets that have not interacted with the medium, allowing easier matching of jet energies between Au +Au and p +p collisions while enhancing medium effects on the recoil jet. The associated hadron yield of the recoil jet is significantly suppressed at high transverse momentum (pTassoc) and enhanced at low pTassoc in 0%-20% central Au +Au collisions compared to p +p collisions, which is indicative of medium-induced parton energy loss in ultrarelativistic heavy-ion collisions.

  12. Charged hadron transverse momentum distributions in Au+Au collisions at √sNN=200 GeV

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Ballintijn, M.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Lee, J. W.; Manly, S.; McLeod, D.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Veres, G. I.; Wadsworth, B.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2004-01-01

    We present transverse momentum distributions of charged hadrons produced in Au+Au collisions at sNN=200 GeV. The spectra were measured for transverse momenta pT from 0.25 to 4.5 GeV/c in a pseudorapidity range of 0.2<η<1.4. The evolution of the spectra is studied as a function of collision centrality, from 65 to 344 participating nucleons. The results are compared to data from proton-antiproton collisions and Au+Au collisions at lower RHIC energies. We find a significant change of the spectral shape between proton-antiproton and semi-peripheral Au+Au collisions. Comparing semi-peripheral to central Au+Au collisions, we find that the yields at high pT exhibit approximate scaling with the number of participating nucleons, rather than scaling with the number of binary collisions.

  13. La situation politique du Jawf au Ier millénaire avant J.-C.

    Directory of Open Access Journals (Sweden)

    Mounir Arbach

    2003-09-01

    Full Text Available La région du Jawf, située à une centaine de kilomètres au nord-est de Sanaa, possède un nombre important de sites archéologiques sudarabiques. Les plus importants sont, du sud-est au nord-ouest : Barâqish, l’antique Yathill, dont l’enceinte est l’ouvrage défensif le mieux conservé parmi les sites préislamiques ; Ma‘în, l’antique Qarnaw, capitale du royaume de Ma‘în ; Kharibat Hamdân, l’antique Haram ; Kamna, l’antique Kaminahû ; al-Sawdâ’, l’antique Nashshân ; et al-Baydâ’, l’antique Nashq. L...

  14. Dosimetric assessments of exposure to tritium of employees of the 2M Process company, and of those of customer and partner companies who intervened on the Saint-Maur-des-Fosses (94) and Bondoufle (91) sites; Evaluations dosimetriques de l'exposition au tritium des salaries de l'entreprise 2M Process et de ceux de leurs entreprises clientes et partenaires etant intervenues sur les sites de Saint-Maur-des-Fosses (94) et de Bondoufle (91)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    This document briefly reports observations and analyses made on two sites belonging to the 2M Process Company. These observations and analyses are notably based on urinary analyses which revealed a contamination of employees by tritium on one of these sites. Exposure scenarios were elaborated, and received doses were estimated for employees, visitors belonging to other companies, and with respect to the identified period of the scenario

  15. DIRAC universal pilots

    Science.gov (United States)

    Stagni, F.; McNab, A.; Luzzi, C.; Krzemien, W.; Consortium, DIRAC

    2017-10-01

    In the last few years, new types of computing models, such as IAAS (Infrastructure as a Service) and IAAC (Infrastructure as a Client), gained popularity. New resources may come as part of pledged resources, while others are in the form of opportunistic ones. Most but not all of these new infrastructures are based on virtualization techniques. In addition, some of them, present opportunities for multi-processor computing slots to the users. Virtual Organizations are therefore facing heterogeneity of the available resources and the use of an Interware software like DIRAC to provide the transparent, uniform interface has become essential. The transparent access to the underlying resources is realized by implementing the pilot model. DIRAC’s newest generation of generic pilots (the so-called Pilots 2.0) are the “pilots for all the skies”, and have been successfully released in production more than a year ago. They use a plugin mechanism that makes them easily adaptable. Pilots 2.0 have been used for fetching and running jobs on every type of resource, being it a Worker Node (WN) behind a CREAM/ARC/HTCondor/DIRAC Computing element, a Virtual Machine running on IaaC infrastructures like Vac or BOINC, on IaaS cloud resources managed by Vcycle, the LHCb High Level Trigger farm nodes, and any type of opportunistic computing resource. Make a machine a “Pilot Machine”, and all diversities between them will disappear. This contribution describes how pilots are made suitable for different resources, and the recent steps taken towards a fully unified framework, including monitoring. Also, the cases of multi-processor computing slots either on real or virtual machines, with the whole node or a partition of it, is discussed.

  16. PULSE Pilot Certification Results

    Directory of Open Access Journals (Sweden)

    Pamela Pape-Lindstrom

    2015-08-01

    Full Text Available The pilot certification process is an ambitious, nationwide endeavor designed to motivate important changes in life sciences education that are in line with the recommendations of the 2011 Vision and Change Report: A Call to Action (American Association for the Advancement of Science [AAAS], 2011.  It is the goal of the certification process to acknowledge departments that have progressed towards full implementation of the tenets of Vision and Change and to motivate departments that have not begun to adopt the recommendations to consider doing so.  More than 70 life science departments applied to be part of the pilot certification process, funded by a National Science Foundation grant, and eight were selected based on initial evidence of transformed and innovative educational practices.  The programs chosen represent a wide variety of schools, including two-year colleges, liberal-arts institutions, regional comprehensive colleges, research universities and minority serving institutions.  Outcomes from this pilot were released June 1, 2015 (www.pulsecommunity.org, with all eight programs being recognized as having progressed along a continuum of change.  Five levels of achievement were defined as PULSE Pilot Progression Levels.  Of the eight departments in the pilot, one achieved “PULSE Progression Level III: Accomplished”.  Six departments achieved “PULSE Progression Level II: Developing” and one pilot department achieved “PULSE Progression Level I: Beginning”.  All of the schools have made significant movement towards the recommendations of Vision and Change relative to a traditional life sciences curriculum.  Overall, the response from the eight pilot schools has been positive. 

  17. Exploring Links Between Global Climate and Explosive Arc Volcanism in Tephra-Rich Quaternary Sediments: A Pilot Study from IODP Expedition 350 Site 1437B, Izu Bonin Rear-Arc Region

    Science.gov (United States)

    Corry-Saavedra, K.; Straub, S. M.; Bolge, L.; Schindlbeck, J. C.; Kutterolf, S.; Woodhead, J. D.

    2015-12-01

    Fallout tephra in marine sediment provide an excellent archive of explosive arc volcanism that can be directly related to the other parameters of climate change, such as ice volume data, IRD (ice-rafted debris) input, etc. Current studies are based on 'discrete' tephra beds, which are produced by major eruptions and visible with the naked eye. Yet the more common, but less explosive arc eruptions that are more continuous through time produce 'disperse' tephra, which is concealed by the non-volcanic host sediment and invisible to the eye. The proportion of disperse tephra in marine sediments is known to be significant and may be critical in elucidating potential synchronicity between arc volcanism and glacial cycles. We conducted a pilot study in young sediments of IODP Hole 1437B drilled at 31°47.3911'N and 139°01.5788'E at the rear-arc of the Izu Bonin volcanic arc. By means of δ18O (Vautravers, in revision), eleven climatic cycles are recorded in uppermost 120 meter of carbonate mud that is interspersed by cm-thick tephra fallout layers. We selected six tephra layers, ranging from 0.2 to 1.16 million years in age, and sampled those vertically, starting from carbonate mud below the basal contact throughout the typical gradational top into the carbonate mud above. From each tephra bed, volcanic particles (>125 micrometer) were handpicked. All other samples were powdered and leached in buffered acetic acid and hydroxylamine hydrochloride to remove the carbonate and authigenous fraction, respectively. Major and trace element abundances (except for SiO2) from all samples were determined by ICP-MS and ICP-OES methods. Strong binary mixing trends are revealed between the pure tephra end member, and detrital sediment component. The tephra is derived from the Izu Bonin volcanic front and rear-arc, while the sediment component is presumably transported by ocean surface currents from the East China Sea. Our data show that mixing proportions change systematically with

  18. Analysis of the intermediate stage in the heavy ion interactions of 208Pb+197Au and 197Au+197Au

    International Nuclear Information System (INIS)

    Nasir, Tabassum; Khan, E.U.; Baluch, J.J.; Qureshi, I.E.; Sajid, M.; Shahzad, M.I.

    2008-01-01

    Two different projectiles 208 Pb and 197 Au at the same energy (11.67MeV/u) have been bombarded on 197 Au target to study heavy ion interactions using mica as a passive detector. In this paper we present results on the study of energy damping and time scale of the existence of di-nuclear composite system in the intermediate reaction step. The plots of Q-values as well as reaction cross sections in various angular bins of scattering angles suggest that K.E. damping was complete and dynamic equilibrium was established between the first and second reaction steps. The time scale of this duration was also determined

  19. The gold-rich indide Eu{sub 5}Au{sub 17.7}In{sub 4.3} and its relation with the structures of SrAu{sub 4.76}In{sub 1.24} and BaLi{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Muts, Ihor [Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie; Ivan Franko National Univ. of Lviv (Ukraine). Inorganic Chemistry Dept.; Rodewald, Ute C.; Poettgen, Rainer [Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie; Zaremba, Vasyl' I.; Pavlosyuk, Orest [Ivan Franko National Univ. of Lviv (Ukraine). Inorganic Chemistry Dept.

    2012-02-15

    The gold-rich indide Eu{sub 5}Au{sub 17.7}In{sub 4.3} was synthesized from the elements in a sealed tantalum ampoule that was heated in a high-frequency furnace. Eu{sub 5}Au{sub 17.7}In{sub 4.3} crystallizes with a new monoclinic structure type: C2/m, a = 902.7(2), b = 722.8(3), c = 1734.1(4) pm, {beta} = 94.31(3) , wR2 = 0.0907, 2640 F{sup 2} values and 74 variables. Eu{sub 5}Au{sub 17.7}In{sub 4.3} has a pronounced gold substructure with Au.Au distances ranging from 278 to 300 pm. The striking structural motifs in the gold substructure are networks of Au6 hexagons and discrete units of corner- and edge-sharing Au{sub 4} tetrahedra. Eu{sub 5}Au{sub 17.70}In{sub 4.30} exhibits a small homogeneity range with In/Au mixing on two Wyckoff sites. Geometrically, the Eu{sub 5}Au{sub 17.7}In{sub 4.3} structure can be explained as an intergrowth variant of slightly distorted SrAu{sub 4.76}In{sub 1.24}- and BaLi{sub 4}-related slabs. The europium coordination in the BaLi{sub 4} slabs is similar to binary EuAu{sub 2}. (orig.)

  20. The Rustler Formation at the WIPP [Waste Isolations Pilot Plant] site: Report of a workshop on the geology and hydrology of the Rustler Formation as it relates to the WIPP Project

    International Nuclear Information System (INIS)

    Chaturvedi, L.

    1987-02-01

    This workshop contained eight papers characterizing the Rustler Formation at the WIPP site in New Mexico. Four of these reports were processed separately for the data bases. Information contained in the four remaining papers is available in journal articles or in the reports of other conferences and included discussions of ground water flow through the Rustler Formation, the potential migration of leached radionuclides in this rock, the effects of mineral dissolution on the removal of underlying salt deposits, and a possible pathway for radionuclide migration into the biosphere

  1. Des atomes d'antihydrogene produits en quantites substantielles au CERN

    CERN Multimedia

    Sevestre, G

    2002-01-01

    "Des quantites relativement substantielles d'atomes d'antihydrogene a basse temperature ont ete produites cet ete au Laboratoire europeen de physique des particules, le CERN a Geneve, ouvrant la voie a une etude approfondie de cette antimatiere qui pourrait remettre en cause les theories actuelles, a annonce mercredi sur le site Internet de la revue Nature une equipe internationale de chercheurs" (1 page).

  2. RGO/Au NPs/N-doped CNTs supported on nickel foam as an anode for enzymatic biofuel cells.

    Science.gov (United States)

    Zhang, He; Zhang, Lingling; Han, Yujie; Yu, You; Xu, Miao; Zhang, Xueping; Huang, Liang; Dong, Shaojun

    2017-11-15

    In this study, three-dimensional reduced graphene oxide/Au NPs/nitrogen-doped carbon nanotubes (RGO/Au NPs/N-doped CNTs) assembly supported on nickel foam was utilized as an anode for enzymatic biofuel cells (EBFCs). 3D RGO/Au NPs was obtained by electrodepositing reduced graphene oxide on nickel foam (Ni foam), while Au NPs were co-deposited during the process. Afterwards, nitrogen doped CNTs (N-CNTs) were allowed to grow seamlessly on the surfaces of 3D RGO/Au NPs via a simple chemical vapor deposition (CVD) process. In this nanostructure, Au NPs co-deposition and nitrogen doping offer more active sites for bioelectrocatalysis. Additionally, N-CNTs were demonstrated providing high specific surface area for enzyme immobilization and facilitating the electron transfer between glucose oxidase (GOx) and electrode. The resulting bioanode achieved efficient glucose oxidation with high current densities of 7.02mAcm -2 (0.3V vs. Ag/AgCl). Coupling with a Pt cathode, the fabricated glucose/air biofuel cell exhibited an open-circuit potential of 0.32V and generated a maximum power density 235µWcm -2 at 0.15V. This novel electrode substrate achieved high performance in current density at bioelectrochemical systems and could be useful for further exploiting the application of three dimensional carbon-based nanomaterials in EBFCs. Copyright © 2017 Elsevier B.V. All rights reserved.

  3. Chemial Bond and Stability of Adsorption of[Au(AsS3)]2- on the Surface of Kaolinite

    Institute of Scientific and Technical Information of China (English)

    MIN Xin-min; CHEN Yun; HONG Han-lie

    2004-01-01

    Density function theory and discrete variation method (DFT-DVM) were used to study the adsorption of [Au(AsS3 ) ]2- on the surface of kaolinite. The correlation among structure, chemical bond and stability was discussed. Several models were selected with [ Au( AsS3 ) ]2- in different directions and sites. The resultsshow that the models with gold on the edge of kaolinite basal layer contain pincerlike bond among gold and severaloxygen atoms and form strong Au - O covalent bond, so these models are more stable than those with gold aboveor under the layer. The models with gold near to [ AlO2(OH)4 ] octahedra are more stable than those with goldnear to the vacancy without aluminium. These two stable tendencies in kaolinite- [ Au( AsS3 ) ]2- are stronger thanthat in kaolinite-Au systems. The interaction between [ Au( AsS3 ) ]2- and kaolinite is stronger than that betweengold and kaolinite, and this interaction is strong enough to form the surface complexes.

  4. Linking the Pilot Structural Model and Pilot Workload

    Science.gov (United States)

    Bachelder, Edward; Hess, Ronald; Aponso, Bimal; Godfroy-Cooper, Martine

    2018-01-01

    Behavioral models are developed that closely reproduced pulsive control response of two pilots using markedly different control techniques while conducting a tracking task. An intriguing find was that the pilots appeared to: 1) produce a continuous, internally-generated stick signal that they integrated in time; 2) integrate the actual stick position; and 3) compare the two integrations to either issue or cease a pulse command. This suggests that the pilots utilized kinesthetic feedback in order to sense and integrate stick position, supporting the hypothesis that pilots can access and employ the proprioceptive inner feedback loop proposed by Hess's pilot Structural Model. A Pilot Cost Index was developed, whose elements include estimated workload, performance, and the degree to which the pilot employs kinesthetic feedback. Preliminary results suggest that a pilot's operating point (parameter values) may be based on control style and index minimization.

  5. 76 FR 54095 - Pilot in Command Proficiency Check and Other Changes to the Pilot and Pilot School Certification...

    Science.gov (United States)

    2011-08-31

    ... [Docket No.: FAA-2008-0938; Amendment Nos. 61-128, 91-324, 141-15, and 142-7] RIN 2120-AJ18 Pilot in Command Proficiency Check and Other Changes to the Pilot and Pilot School Certification Rules AGENCY... regulations concerning pilot, flight instructor, and pilot school certification. This rule will require pilot...

  6. AutoPyFactory: A Scalable Flexible Pilot Factory Implementation

    International Nuclear Information System (INIS)

    Caballero, J; Hover, J; Love, P; Stewart, G A

    2012-01-01

    The ATLAS experiment at the CERN LHC is one of the largest users of grid computing infrastructure, which is a central part of the experiment's computing operations. Considerable efforts have been made to use grid technology in the most efficient and effective way, including the use of a pilot job based workload management framework. In this model the experiment submits ‘pilot’ jobs to sites without payload. When these jobs begin to run they contact a central service to pick-up a real payload to execute. The first generation of pilot factories were usually specific to a single Virtual Organization (VO), and were bound to the particular architecture of that VO's distributed processing. A second generation provides factories which are more flexible, not tied to any particular VO, and provide new and improved features such as monitoring, logging, profiling, etc. In this paper we describe this key part of the ATLAS pilot architecture, a second generation pilot factory, AutoPyFactory. AutoPyFactory has a modular design and is highly configurable. It is able to send different types of pilots to sites and exploit different submission mechanisms and queue characteristics. It is tightly integrated with the PanDA job submission framework, coupling pilot flow to the amount of work the site has to run. It gathers information from many sources in order to correctly configure itself for a site and its decision logic can easily be updated. Integrated into AutoPyFactory is a flexible system for delivering both generic and specific job wrappers which can perform many useful actions before starting to run end-user scientific applications, e.g., validation of the middleware, node profiling and diagnostics, and monitoring. AutoPyFactory also has a robust monitoring system that has been invaluable in establishing a reliable pilot factory service for ATLAS.

  7. Hollow Au@Pd and Au@Pt core-shell nanoparticles as electrocatalysts for ethanol oxidation reactions

    KAUST Repository

    Song, Hyon Min; Anjum, Dalaver H.; Sougrat, Rachid; Hedhili, Mohamed N.; Khashab, Niveen M.

    2012-01-01

    that individual metals may not catalyze. Here, preparation of hollow Au@Pd and Au@Pt core-shell nanoparticles (NPs) and their use as electrocatalysts are reported. Galvanic displacement with Ag NPs is used to obtain hollow NPs, and higher reduction potential of Au

  8. Seed-mediated growth and manipulation of Au nanorods via size-controlled synthesis of Au seeds

    International Nuclear Information System (INIS)

    Liu Juncheng; Duggan, Jennifer N.; Morgan, Joshua; Roberts, Christopher B.

    2012-01-01

    Seed-mediated growth of gold (Au) nanorods with highly controllable length, width, and aspect ratio was accomplished via carefully size-controlled synthesis of the original Au seeds. A slow dynamic growth of Au nanoparticle seeds was observed after reduction of the Au salt (i.e., hydrogen tetrachloroaurate (III) hydrate) by sodium borohydride (NaBH 4 ) in the presence of cetyltrimethyl ammonium bromide (CTAB). As such, the size of the Au nanoparticle seeds can therefore be manipulated through control over the duration of the reaction period (i.e., aging times of 2, 8, 48, 72, and 144 h were used in this study). These differently sized Au nanoparticles were subsequently used as seeds for the growth of Au nanorods, where the additions of Au salt, CTAB, AgNO 3 , and ascorbic acid were employed. Smaller Au nanoparticle seeds obtained via short growth/aging time resulted in Au nanorods with higher aspect ratio and thus longer longitudinal surface plasmon wavelength (LSPW). The larger Au nanoparticle seeds obtained via longer growth/aging time resulted in Au nanorods with lower aspect ratio and shorter LSPW.

  9. The gold-rich indide Sr{sub 5}Au{sub 13.5}In{sub 8.5}

    Energy Technology Data Exchange (ETDEWEB)

    Muts, Ihor [Ivan Franko National Univ. of Lviv (Ukraine). Inorganic Chemistry Dept.; Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie; Rodewald, Ute C.; Poettgen, Rainer [Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie; Zaremba, Vasyl' I. [Ivan Franko National Univ. of Lviv (Ukraine). Inorganic Chemistry Dept.

    2011-11-15

    The orthorhombic indide Sr{sub 5}Au{sub 13.5}In{sub 8.5} was obtained during phase-analytical studies of the Sr-Au-In system. This new indide is formed upon melting of the elements in a sealed tantalum tube. Sr{sub 5}Au{sub 13.5}In{sub 8.5} was characterized on the basis of powder and single-crystal X-ray diffraction: Pmmn, a = 476.37(9), b = 2927.5(9), c = 894.9(2) pm, wR2 = 0.056, 2355 F{sup 2} values, 87 variables. The structure is of a new type. The gold and indium atoms build up a complex three-dimensional [Au{sub 13.5}In{sub 8.5}] polyanionic network in which the strontium atoms fill channels which extend in the a direction. One site within the polyanion shows Au/In mixing. The Sr{sub 5}Au{sub 13.5}In{sub 8.5} structure is composed of SrAu{sub 3}In{sub 3-} and SrAu-related slabs. (orig.)

  10. Transformation of Ag nanocubes into Ag-Au hollow nanostructures with enriched Ag contents to improve SERS activity and chemical stability.

    Science.gov (United States)

    Yang, Yin; Zhang, Qiang; Fu, Zheng-Wen; Qin, Dong

    2014-03-12

    We report a strategy to complement the galvanic replacement reaction between Ag nanocubes and HAuCl4 with co-reduction by ascorbic acid (AA) for the formation of Ag-Au hollow nanostructures with greatly enhanced SERS activity. Specifically, in the early stage of synthesis, the Ag nanocubes are sharpened at corners and edges because of the selective deposition of Au and Ag atoms at these sites. In the following steps, the pure Ag in the nanocubes is constantly converted into Ag(+) ions to generate voids owing to the galvanic reaction with HAuCl4, but these released Ag(+) ions are immediately reduced back to Ag atoms and are co-deposited with Au atoms onto the nanocube templates. We observe distinctive SERS properties for the Ag-Au hollow nanostructures at visible and near-infrared excitation wavelengths. When plasmon damping is eliminated by using an excitation wavelength of 785 nm, the SERS activity of the Ag-Au hollow nanostructures is 15- and 33-fold stronger than those of the original Ag nanocubes and the Ag-Au nanocages prepared by galvanic replacement without co-reduction, respectively. Additionally, Ag-Au hollow nanostructures embrace considerably improved stability in an oxidizing environment such as aqueous H2O2 solution. Collectively, our work suggests that the Ag-Au hollow nanostructures will find applications in SERS detection and imaging.

  11. A recyclable Au(I) catalyst for selective homocoupling of arylboronic acids: significant enhancement of nano-surface binding for stability and catalytic activity.

    Science.gov (United States)

    Zhang, Xin; Zhao, Haitao; Wang, Jianhui

    2010-08-01

    Au nanoparticles stabilized by polystyrene-co-polymethacrylic acid microspheres (PS-co-PMAA) were prepared and characterized via X-ray diffraction (XRD), and transmission electron microscope (TEM). The Au nanoparticles supported on the microspheres showed highly selective catalytic activity for homo-coupling reactions of arylboronic acids in a system of aryl-halides and arylboronic acids. X-ray photoelectron spectroscopy (XPS) spectra of the catalyst shows large amounts of Au(I) complexes band to the surface of the Au nanoparticles, which contributes to the selective homocoupling of the arylboronic acids. More importantly, this supported Au complex is a highly recyclable catalyst. The supported Au catalyst can be recycled and reused at least 6 times for a phenylboronic acid reactant, whereas the parent complex shows very low catalytic activity for this compound. The high catalytic activity of this material is attributed to: (1) the high surface to volume ratio which leads to more active sites being exposed to reactants; (2) the strong surface binding of the Au nanoparticle to the Au(I) complexes, which enhances both the stability and the catalytic activity of these complexes.

  12. Télécentres : de l'idée à la réalité au Mozambique | CRDI - Centre ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    1 nov. 2010 ... J'espère que ce projet débouchera sur d'autres initiatives avec d'autres gens, dans d'autres régions du pays, dit-elle, parce que nous voulons vraiment créer une sorte de franchise. Notre projet est un projet pilote qui sert à confirmer et infirmer, etc. » Elle s'inquiète, cependant, du débat actuel au ...

  13. Di-hadron correlations with identified leading hadrons in 200 GeV Au + Au and d + Au collisions at STAR

    Science.gov (United States)

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Aparin, A.; Arkhipkin, D.; Aschenauer, E. C.; Averichev, G. S.; Bai, X.; Bairathi, V.; Banerjee, A.; Bellwied, R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Bouchet, J.; Brandenburg, D.; Brandin, A. V.; Bunzarov, I.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Campbell, J. M.; Cebra, D.; Cervantes, M. C.; Chakaberia, I.; Chaloupka, P.; Chang, Z.; Chattopadhyay, S.; Chen, X.; Chen, J. H.; Cheng, J.; Cherney, M.; Christie, W.; Contin, G.; Crawford, H. J.; Das, S.; De Silva, L. C.; Debbe, R. R.; Dedovich, T. G.; Deng, J.; Derevschikov, A. A.; di Ruzza, B.; Didenko, L.; Dilks, C.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Du, C. M.; Dunkelberger, L. E.; Dunlop, J. C.; Efimov, L. G.; Engelage, J.; Eppley, G.; Esha, R.; Evdokimov, O.; Eyser, O.; Fatemi, R.; Fazio, S.; Federic, P.; Fedorisin, J.; Feng, Z.; Filip, P.; Fisyak, Y.; Flores, C. E.; Fulek, L.; Gagliardi, C. A.; Garand, D.; Geurts, F.; Gibson, A.; Girard, M.; Greiner, L.; Grosnick, D.; Gunarathne, D. S.; Guo, Y.; Gupta, S.; Gupta, A.; Guryn, W.; Hamad, A.; Hamed, A.; Haque, R.; Harris, J. W.; He, L.; Heppelmann, S.; Heppelmann, S.; Hirsch, A.; Hoffmann, G. W.; Hofman, D. J.; Horvat, S.; Huang, T.; Huang, B.; Huang, H. Z.; Huang, X.; Huck, P.; Humanic, T. J.; Igo, G.; Jacobs, W. W.; Jang, H.; Jia, J.; Jiang, K.; Judd, E. G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Khan, Z. H.; Kikoła, D. P.; Kisiel, A.; Kochenda, L.; Koetke, D. D.; Kosarzewski, L. K.; Kraishan, A. F.; Kravtsov, P.; Krueger, K.; Kumar, L.; Lamont, M. A. C.; Landgraf, J. M.; Landry, K. D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; Li, X.; Li, W.; Li, Z. M.; Li, Y.; Li, C.; Li, X.; Lisa, M. A.; Liu, F.; Ljubicic, T.; Llope, W. J.; Lomnitz, M.; Longacre, R. S.; Luo, X.; Ma, G. L.; Ma, Y. G.; Ma, R.; Ma, L.; Magdy, N.; Majka, R.; Manion, A.; Margetis, S.; Markert, C.; Masui, H.; Matis, H. S.; McDonald, D.; Meehan, K.; Mei, J. C.; Minaev, N. G.; Mioduszewski, S.; Mishra, D.; Mohanty, B.; Mondal, M. M.; Morozov, D. A.; Mustafa, M. K.; Nandi, B. K.; Nasim, Md.; Nayak, T. K.; Nigmatkulov, G.; Niida, T.; Nogach, L. V.; Noh, S. Y.; Novak, J.; Nurushev, S. B.; Odyniec, G.; Ogawa, A.; Oh, K.; Okorokov, V.; Olvitt, D.; Page, B. S.; Pak, R.; Pan, Y. X.; Pandit, Y.; Panebratsev, Y.; Pawlik, B.; Pei, H.; Perkins, C.; Peterson, A.; Pile, P.; Pluta, J.; Poniatowska, K.; Porter, J.; Posik, M.; Poskanzer, A. M.; Pruthi, N. K.; Putschke, J.; Qiu, H.; Quintero, A.; Ramachandran, S.; Raniwala, R.; Raniwala, S.; Ray, R. L.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Roy, A.; Ruan, L.; Rusnak, J.; Rusnakova, O.; Sahoo, N. R.; Sahu, P. K.; Sakrejda, I.; Salur, S.; Sandweiss, J.; Sarkar, A.; Schambach, J.; Scharenberg, R. P.; Schmah, A. M.; Schmidke, W. B.; Schmitz, N.; Seger, J.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P. V.; Shao, M.; Sharma, B.; Sharma, M. K.; Shen, W. Q.; Shi, S. S.; Shou, Q. Y.; Sichtermann, E. P.; Sikora, R.; Simko, M.; Singha, S.; Skoby, M. J.; Smirnov, N.; Smirnov, D.; Song, L.; Sorensen, P.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Stepanov, M.; Strikhanov, M.; Stringfellow, B.; Sumbera, M.; Summa, B.; Sun, Y.; Sun, Z.; Sun, X. M.; Sun, X.; Surrow, B.; Svirida, D. N.; Szelezniak, M. A.; Tang, A. H.; Tang, Z.; Tarnowsky, T.; Tawfik, A.; Thomas, J. H.; Timmins, A. R.; Tlusty, D.; Todoroki, T.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Tripathy, S. K.; Tsai, O. D.; Ullrich, T.; Underwood, D. G.; Upsal, I.; Van Buren, G.; van Nieuwenhuizen, G.; Vandenbroucke, M.; Varma, R.; Vasiliev, A. N.; Vertesi, R.; Videbæk, F.; Viyogi, Y. P.; Vokal, S.; Voloshin, S. A.; Vossen, A.; Wang, J. S.; Wang, F.; Wang, H.; Wang, G.; Wang, Y.; Wang, Y.; Webb, G.; Webb, J. C.; Wen, L.; Westfall, G. D.; Wieman, H.; Wissink, S. W.; Witt, R.; Wu, Y. F.; Wu; Xiao, Z. G.; Xie, W.; Xin, K.; Xu, H.; Xu, Z.; Xu, Q. H.; Xu, Y. F.; Xu, N.; Yang, S.; Yang, Y.; Yang, Q.; Yang, Y.; Yang, C.; Yang, Y.; Ye, Z.; Ye, Z.; Yepes, P.; Yi, L.; Yip, K.; Yoo, I.-K.; Yu, N.; Zbroszczyk, H.; Zha, W.; Zhang, Y.; Zhang, Z.; Zhang, J. B.; Zhang, J.; Zhang, X. P.; Zhang, S.; Zhang, J.; Zhao, J.; Zhong, C.; Zhou, L.; Zhu, X.; Zoulkarneeva, Y.

    2015-12-01

    The STAR Collaboration presents for the first time two-dimensional di-hadron correlations with identified leading hadrons in 200 GeV central Au + Au and minimum-bias d + Au collisions to explore hadronization mechanisms in the quark gluon plasma. The enhancement of the jet-like yield for leading pions in Au + Au data with respect to the d + Au reference and the absence of such an enhancement for leading non-pions (protons and kaons) are discussed within the context of a quark recombination scenario. The correlated yield at large angles, specifically in the ridge region, is found to be significantly higher for leading non-pions than pions. The consistencies of the constituent quark scaling, azimuthal harmonic model and a mini-jet modification model description of the data are tested, providing further constraints on hadronization.

  14. Di-hadron correlations with identified leading hadrons in 200 GeV Au+Au and d+Au collisions at STAR

    Directory of Open Access Journals (Sweden)

    L. Adamczyk

    2015-12-01

    Full Text Available The STAR Collaboration presents for the first time two-dimensional di-hadron correlations with identified leading hadrons in 200 GeV central Au+Au and minimum-bias d+Au collisions to explore hadronization mechanisms in the quark gluon plasma. The enhancement of the jet-like yield for leading pions in Au+Au data with respect to the d+Au reference and the absence of such an enhancement for leading non-pions (protons and kaons are discussed within the context of a quark recombination scenario. The correlated yield at large angles, specifically in the ridge region, is found to be significantly higher for leading non-pions than pions. The consistencies of the constituent quark scaling, azimuthal harmonic model and a mini-jet modification model description of the data are tested, providing further constraints on hadronization.

  15. Di-hadron correlations with identified leading hadrons in 200 GeV Au + Au and d + Au collisions at STAR

    Energy Technology Data Exchange (ETDEWEB)

    Adamczyk, L; Adkins, JK; Agakishiev, G; Aggarwal, MM; Ahammed, Z; Alekseev, I; Aparin, A; Arkhipkin, D; Aschenauer, EC; Averichev, GS; Bai, X; Bairathi, V; Banerjee, A; Bellwied, R; Bhasin, A; Bhati, AK; Bhattarai, P; Bielcik, J; Bielcikova, J; Bland, LC; Bordyuzhin, IG; Bouchet, J; Brandenburg, D; Brandin, AV; Bunzarov, I; Butterworth, J; Caines, H; Calderón de la Barca Sánchez, M; Campbell, JM; Cebra, D; Cervantes, MC; Chakaberia, I; Chaloupka, P; Chang, Z; Chattopadhyay, S; Chen, X; Chen, JH; Cheng, J; Cherney, M; Christie, W; Contin, G; Crawford, HJ; Das, S; De Silva, LC; Debbe, RR; Dedovich, TG; Deng, J; Derevschikov, AA; di Ruzza, B; Didenko, L; Dilks, C; Dong, X; Drachenberg, JL; Draper, JE; Du, CM; Dunkelberger, LE; Dunlop, JC; Efimov, LG; Engelage, J; Eppley, G; Esha, R; Evdokimov, O; Eyser, O; Fatemi, R; Fazio, S; Federic, P; Fedorisin, J; Feng, Z; Filip, P; Fisyak, Y; Flores, CE; Fulek, L; Gagliardi, CA; Garand, D; Geurts, F; Gibson, A; Girard, M; Greiner, L; Grosnick, D; Gunarathne, DS; Guo, Y; Gupta, S; Gupta, A; Guryn, W; Hamad, A; Hamed, A; Haque, R; Harris, JW; He, L; Heppelmann, S; Heppelmann, S; Hirsch, A; Hoffmann, GW; Hofman, DJ; Horvat, S; Huang, T; Huang, B; Huang, HZ; Huang, X; Huck, P

    2015-10-23

    The STAR Collaboration presents for the first time two-dimensional di-hadron correlations with identified leading hadrons in 200 GeV central Au + Au and minimum-bias d + Au collisions to explore hadronization mechanisms in the quark gluon plasma. The enhancement of the jet-like yield for leading pions in Au + Au data with respect to the d + Au reference and the absence of such an enhancement for leading non-pions (protons and kaons) are discussed within the context of a quark recombination scenario. The correlated yield at large angles, specifically in the ridge region, is found to be significantly higher for leading non-pions than pions. The consistencies of the constituent quark scaling, azimuthal harmonic model and a mini-jet modification model description of the data are tested, providing further constraints on hadronization.

  16. First results on d+Au collisions from PHOBOS

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Becker, B.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; García, E.; Gburek, T.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Harrington, A. S.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Khan, N.; Kulinich, P.; Kuo, C. M.; Lee, J. W.; Lin, W. T.; Manly, S.; Mignerey, A. C.; Noell, A.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Roland, C.; Roland, G.; Sagerer, J.; Sarin, P.; Sawicki, P.; Sedykh, I.; Skulski, W.; Smith, C. E.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Teng, R.; Tonjes, M. B.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Veres, G. I.; Wadsworth, B.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.; Zhang, J.

    2004-02-01

    We have measured transverse momentum distributions of charged hadrons produced in d+Au collisions at √SNN = 200 GeV, in the range 0.25 < pT < 6.0 GeV/c. With increasing collision centrality, the yield at high transverse momenta increases more rapidly than the overall particle density, leading to a strong modification of the spectral shape. This change in spectral shape is qualitatively different from observations in Au+Au collisions at the same energy. The results provide important information for discriminating between different models for the suppression of high-pT hadrons observed in Au+Au collisions.

  17. 229 Age au premier vêlage et intervalle entre vêlages de quatre ...

    African Journals Online (AJOL)

    Madjina TELLAH

    ... Polytechnique de Bobo-Dioulasso (UPB), 01 BP 1091 Bobo-Dioulasso, Burkina Faso ..... rapportés au Niger et au Tchad [4], au Cameroun chez les zébus Goudali [8], au ... [9], au Sénégal chez le zébu Gobra [10], au Bénin chez les vaches ...

  18. [Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]-: the longest intermetalloid chain compound of tin.

    Science.gov (United States)

    Binder, Mareike; Schrenk, Claudio; Block, Theresa; Pöttgen, Rainer; Schnepf, Andreas

    2017-10-12

    The reaction of the metalloid tin cluster [Sn 10 (Hyp) 4 ] 2- with (Ph 3 P)Au-SHyp (Hyp = Si(SiMe 3 ) 3 ) gave an intermetalloid cluster [Au 3 Sn 18 (Hyp) 8 ] - 1, which is the longest intermetalloid chain compound of tin to date. 1 shows a structural resemblance to binary AuSn phases, which is expected for intermetalloid clusters.

  19. A complete remediation process for a uranium-contaminated site and application to other sites

    International Nuclear Information System (INIS)

    Mason, C.F.V.; Lu, N.; Kitten, H.D.; Williams, M.; Turney, W.R.J.R.

    1998-01-01

    During the summer of 1996 the authors were able to test, at the pilot scale, the concept of leaching uranium (U) from contaminated soils. The results of this pilot scale operation showed that the system they previously had developed at the laboratory scale is applicable at the pilot scale. The paper discusses these results, together with laboratory scale results using soil from the Fernald Environmental Management Project (FEMP), Ohio. These FEMP results show how, with suitable adaptations, the process is widely applicable to other sites. The purpose of this paper is to describe results that demonstrate remediation of uranium-contaminated soils may be accomplished through a leach scheme using sodium bicarbonate

  20. A complete remediation process for a uranium-contaminated site and application to other sites

    Energy Technology Data Exchange (ETDEWEB)

    Mason, C.F.V.; Lu, N.; Kitten, H.D.; Williams, M.; Turney, W.R.J.R.

    1998-12-31

    During the summer of 1996 the authors were able to test, at the pilot scale, the concept of leaching uranium (U) from contaminated soils. The results of this pilot scale operation showed that the system they previously had developed at the laboratory scale is applicable at the pilot scale. The paper discusses these results, together with laboratory scale results using soil from the Fernald Environmental Management Project (FEMP), Ohio. These FEMP results show how, with suitable adaptations, the process is widely applicable to other sites. The purpose of this paper is to describe results that demonstrate remediation of uranium-contaminated soils may be accomplished through a leach scheme using sodium bicarbonate.

  1. Experimental and theoretical study of the electronic and magnetic structures of Mn1-xCr xAu2

    International Nuclear Information System (INIS)

    Hsu, L.-S.; Murakawa, T.; Fujiwara, H.; Sekiyama, A.; Suga, S.; Imada, S.; Yano, M.; Miyamachi, T.; Higashimichi, H.; Yamaguchi, J.; Funabashi, G.; Yabashi, M.; Ishikawa, T.; Higashiya, A.

    2007-01-01

    X-ray photoemission spectra of Mn 1-x Cr x Au 2 (x = 0, 0.05, and 0.13) are presented and compared with theoretical total and partial density of state (DOS) curves. Site- and spin-decomposed partial DOS and magnetism of these materials are also discussed

  2. 76 FR 3192 - Value Pricing Pilot Program Participation, Fiscal Years 2010 and 2011

    Science.gov (United States)

    2011-01-19

    ... DEPARTMENT OF TRANSPORTATION Federal Highway Administration Value Pricing Pilot Program... Value Pricing Pilot (VPP) program, which was published on October 19, 2010, at 75 FR 64397. The original... interest at the following Web site: http://ops.fhwa.dot.gov/tolling_pricing/participation.htm . FOR FURTHER...

  3. Au Based Nanocomposites Towards Plasmonic Applications

    Science.gov (United States)

    Panniello, A.; Curri, M. L.; Placido, T.; Reboud, V.; Kehagias, N.; Sotomayor Torres, C. M.; Mecerreyes, D.; Agostiano, A.; Striccoli, M.

    2010-06-01

    Incorporation of nano-sized metals in polymers can transfer their unique features to the host matrix, providing nanocomposite materials with improved optical, electric, magnetic and mechanical properties. In this work, colloidal Au nanorods have been incorporated into PMMA based random co-polymer, properly functionalized with amino groups and the optical and morphological properties of the resulting nanocomposite have been investigated by spectroscopic and AFM measurements. Au nanorods have demonstrated to preserve the plasmon absorption and to retain morphological features upon the incorporation, thus making the final metal modified polymer composite exploitable for the fabrication of plasmonic devices. The prepared nanocomposites have been then patterned by Nano Imprint Lithography technique in order to demonstrate the viability of the materials towards optical applications.

  4. The effect of defects on the catalytic activity of single Au atom supported carbon nanotubes and reaction mechanism for CO oxidation.

    Science.gov (United States)

    Ali, Sajjad; Fu Liu, Tian; Lian, Zan; Li, Bo; Sheng Su, Dang

    2017-08-23

    The mechanism of CO oxidation by O 2 on a single Au atom supported on pristine, mono atom vacancy (m), di atom vacancy (di) and the Stone Wales defect (SW) on single walled carbon nanotube (SWCNT) surface is systematically investigated theoretically using density functional theory. We determine that single Au atoms can be trapped effectively by the defects on SWCNTs. The defects on SWCNTs can enhance both the binding strength and catalytic activity of the supported single Au atom. Fundamental aspects such as adsorption energy and charge transfer are elucidated to analyze the adsorption properties of CO and O 2 and co-adsorption of CO and O 2 molecules. It is found that CO binds stronger than O 2 on Au supported SWCNT. We clearly demonstrate that the defected SWCNT surface promotes electron transfer from the supported single Au atom to O 2 molecules. On the other hand, this effect is weaker for pristine SWCNTs. It is observed that the high density of spin-polarized states are localized in the region of the Fermi level due to the strong interactions between Au (5d orbital) and the adjacent carbon (2p orbital) atoms, which influence the catalytic performance. In addition, we elucidate both the Langmuir-Hinshelwood (LH) and Eley-Rideal (ER) mechanisms of CO oxidation by O 2 . For the LH pathway, the barriers of the rate-limiting step are calculated to be 0.02 eV and 0.05 eV for Au/m-SWCNT and Au/di-SWCNT, respectively. To regenerate the active sites, an ER-like reaction occurs to form a second CO 2 molecule. The ER pathway is observed on Au/m-SWCNT, Au/SW-SWCNT and Au/SWCNT in which the Au/m-SWCNT has a smaller barrier. The comparison with a previous study (Lu et al., J. Phys. Chem. C, 2009, 113, 20156-20160.) indicates that the curvature effect of SWCNTs is important for the catalytic property of the supported single Au. Overall, Au/m-SWCNT is identified as the most active catalyst for CO oxidation compared to pristine SWCNT, SW-SWCNT and di-SWCNT. Our findings give a

  5. Photoswitchable Faraday effect in EuS-Au nanosystems

    Energy Technology Data Exchange (ETDEWEB)

    Kawashima, Akira; Nakanishi, Takayuki; Kitagawa, Yuichi; Fushimi, Koji; Hasegawa, Yasuchika [Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, North-13 West-8, Kita-ku, 060-8628, Sapporo (Japan)

    2016-01-15

    Effective photoswitchable europium sulfide nanocrystals with gold nanoparticles using dithiol (DDT: 1,10-decanedithiol) joint molecules, EuS-Au nanosystems, are demonstrated. The TEM image indicates the formation of EuS-Au nanosystems composed of cube-shaped EuS nanocrystals and spherical Au nanoparticles. Under visible-light irradiation, a drastic change of absorption band of EuS-Au nanosystems at around 600 nm was observed. The Faraday effects of EuS-Au nanosystems were estimated using magnetic circular dichroism (MCD) measurements. The effective change of the MCD spectra of EuS-Au nanosystems under visible-light irradiation was successfully observed at around 670 nm for the first time. The effective reversible changes in MCD spectra with the alternative irradiation cycles of visible light (>440 nm) and dark are also presented. The decrease rate of rotation angle at 670 nm of EuS-Au nanosystems is larger than that of absorbance. These results indicate that the effective change of MCD spectra of EuS-Au nanosystems would be dominated not only by a drastic change of absorption band related to enhanced LSPR of Au nanoparticles but also by specific interaction between EuS and Au in nanosystem under irradiation. Illustration of photoswitch and TEM image of EuS-Au nanosystems. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  6. User Participation in Pilot Implementation

    DEFF Research Database (Denmark)

    Torkilsheyggi, Arnvør Martinsdóttir á; Hertzum, Morten

    2014-01-01

    Pilot implementations provide users with real-work experiences of how a system will affect their daily work before the design of the system is finalized. On the basis of a pilot implementation of a system for coordinating the transport of patients by hospital porters, we investigate pilot...... implementation as a method for participatory design. We find that to foster participation and learning about user needs a pilot implementation must create a space for reflecting on use, in addition to the space for using the pilot system. The space for reflection must also exist during the activities preparing...... the use of the pilot system because the porters and nurses learned about their needs throughout the pilot implementation, not just during use. Finally, we discuss how the scope and duration of a pilot implementation influence the conditions for participation....

  7. Near-infrared-responsive, superparamagnetic Au@Co nanochains

    Directory of Open Access Journals (Sweden)

    Varadee Vittur

    2017-08-01

    Full Text Available This manuscript describes a new type of nanomaterial, namely superparamagnetic Au@Co nanochains with optical extinctions in the near infrared (NIR. The Au@Co nanochains were synthesized via a one-pot galvanic replacement route involving a redox-transmetalation process in aqueous medium, where Au salt was reduced to form Au shells on Co seed templates, affording hollow Au@Co nanochains. The Au shells serve not only as a protective coating for the Co nanochain cores, but also to give rise to the optical properties of these unique nanostructures. Importantly, these bifunctional, magneto-optical Au@Co nanochains combine the advantages of nanophotonics (extinction at ca. 900 nm and nanomagnetism (superparamagnetism and provide a potentially useful new nanoarchitecture for biomedical or catalytic applications that can benefit from both activation by light and manipulation using an external magnetic field.

  8. Mechanical properties and grindability of experimental Ti-Au alloys.

    Science.gov (United States)

    Takahashi, Masatoshi; Kikuchi, Masafumi; Okuno, Osamu

    2004-06-01

    Experimental Ti-Au alloys (5, 10, 20 and 40 mass% Au) were made. Mechanical properties and grindability of the castings of the Ti-Au alloys were examined. As the concentration of gold increased to 20%, the yield strength and the tensile strength of the Ti-Au alloys became higher without markedly deteriorating their ductility. This higher strength can be explained by the solid-solution strengthening of the a titanium. The Ti-40%Au alloy became brittle because the intermetallic compound Ti3Au precipitated intensively near the grain boundaries. There was no significant difference in the grinding rate and grinding ratio among all the Ti-Au alloys and the pure titanium at any speed.

  9. Synthesis of Pd-Au bimetallic nanocrystals via controlled overgrowth.

    Science.gov (United States)

    Lim, Byungkwon; Kobayashi, Hirokazu; Yu, Taekyung; Wang, Jinguo; Kim, Moon J; Li, Zhi-Yuan; Rycenga, Matthew; Xia, Younan

    2010-03-03

    This paper describes the synthesis of Pd-Au bimetallic nanocrystals with controlled morphologies via a one-step seeded-growth method. Two different reducing agents, namely, L-ascorbic acid and citric acid, were utilized for the reduction of HAuCl(4) in an aqueous solution to control the overgrowth of Au on cubic Pd seeds. When L-ascorbic acid was used as the reducing agent, conformal overgrowth of Au on the Pd nanocubes led to the formation of Pd-Au nanocrystals with a core-shell structure. On the contrary, localized overgrowth of Au was observed when citric acid was used as the reducing agent, producing Pd-Au bimetallic dimers. Through this morphological control, we were able to tune the localized surface plasmon resonance peaks of Pd-Au bimetallic nanostructures in the visible region.

  10. Electrosynthesis and characterization of polypyrrole/Au nanocomposite

    Energy Technology Data Exchange (ETDEWEB)

    Chen Wei [School of Chemical and Biomedical Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Li, C.M. [School of Chemical and Biomedical Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)]. E-mail: ecmli@ntu.edu.sg; Chen Peng [School of Chemical and Biomedical Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Sun, C.Q. [School of Electric and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)

    2006-11-12

    Polypyrrole films containing gold nanoparticles (PPy/Au) were electrosynthesized on a glassy carbon electrode. This was done by applying a constant current of 1.43 mA cm{sup -2} in solutions containing colloidal Au particles and pyrrole monomer. A chloroaurate medium with a citrate/tannic acid reducing/protection agent was employed for generating the Au colloids. The PPy/Au films were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Raman spectroscopy. Also, electrochemical behaviors of the PPy/Au films were characterized by cyclic voltammetry (CV) and AC impedance measurements. Experimental results demonstrate that PPy/Au has greater conductivity and better stability than PPy. The effect of incorporated Au nanoparticles in PPy matrix was studied and the mechanism was suggested.

  11. Synthesis of SERS active Au nanowires in different noncoordinating solvents

    Energy Technology Data Exchange (ETDEWEB)

    Hou Xiaomiao; Zhang Xiaoling, E-mail: zhangxl@bit.edu.cn [Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, Department of Chemistry, School of Science (China); Fang Yan, E-mail: fangyan@mail.cnu.edu.cn [Beijing Key Laboratory for Nano-Photonics and Nano-Structure (NPNS), Capital Normal University (China); Chen Shutang; Li Na; Zhou Qi [Key Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, Department of Chemistry, School of Science (China)

    2011-06-15

    Au nanowires with length up to micrometers were synthesized through a simple and one-pot solution growth method. HAuCl{sub 4} was reduced in a micellar structure formed by 1-octadecylamine and oleic acid in hexane, heptane, toluene and chloroform, respectively. As the non-polarity of noncoordinating solvents can affect the nucleation and growth rates of Au nanostructures, Au nanowires with different diameters could be obtained by changing the noncoordinating solvents in the synthetic process. The influences of the solvents on the morphology of Au nanowires were systematically studied. When using hexane as reaction solvent, the product turned to be high portion of Au nanowires with more uniform size than the others. Furthermore, surface-enhanced Raman scattering (SERS) spectrum of 2-thionaphthol was obtained on the Au nanowire-modified substrate, indicating that the as-synthesized Au nanowires have potential for highly sensitive optical detection application.

  12. Au-nanoparticles grafted on plasma treated PE

    International Nuclear Information System (INIS)

    Svorcik, V.; Chaloupka, A.; Rezanka, P.; Slepicka, P.; Kolska, Z.; Kasalkova, N.; Hubacek, T.; Siegel, J.

    2010-01-01

    Polyethylene (PE) surface was treated with Ar plasma. Activated surface was grafted from methanol solution of 1,2-ethanedithiol. Then the sample was immersed into freshly prepared colloid solution of Au-nanoparticles. Finally Au layer was sputtered on the samples. Properties of the modified PE were studied using various methods: AFM, EPR, RBS and nanoindentation. It was shown that the plasma treatment results in degradation of polymer chain (AFM) and creation of free radicals by EPR. After grafting with dithiol, the concentration of free radicals declines. The presence of Au and S in the surface layer after the coating with Au-nanoparticles was proved by RBS. Plasma treatment changes PE surface morphology and increases surface roughness, too. Another significant change in surface morphology and roughness was observed after deposition of Au-nanoparticles. Nanoindentation measurements show that the grafting with Au-nanoparticles increases adhesion of subsequently sputtered Au layer.

  13. Highly Stable [C60AuC60]+/- Dumbbells.

    Science.gov (United States)

    Goulart, Marcelo; Kuhn, Martin; Martini, Paul; Chen, Lei; Hagelberg, Frank; Kaiser, Alexander; Scheier, Paul; Ellis, Andrew M

    2018-05-17

    Ionic complexes between gold and C 60 have been observed for the first time. Cations and anions of the type [Au(C 60 ) 2 ] +/- are shown to have particular stability. Calculations suggest that these ions adopt a C 60 -Au-C 60 sandwich-like (dumbbell) structure, which is reminiscent of [XAuX] +/- ions previously observed for much smaller ligands. The [Au(C 60 ) 2 ] +/- ions can be regarded as Au(I) complexes, regardless of whether the net charge is positive or negative, but in both cases, the charge transfer between the Au and C 60 is incomplete, most likely because of a covalent contribution to the Au-C 60 binding. The C 60 -Au-C 60 dumbbell structure represents a new architecture in fullerene chemistry that might be replicable in synthetic nanostructures.

  14. Solvent extraction of Au(III) for preparation of a carrier-free multitracer and an Au tracer from an Au target

    International Nuclear Information System (INIS)

    Weginwar, R.G.; Kobayashi, Y.; Ambe, S.; Liu, B.; Enomoto, S.; Ambe, F.

    1996-01-01

    Separation of Au(III) and various carrier-free radionuclides by solvent extraction was investigated using an Au target irradiated by an energetic heavy-ion beam. Percentage extraction of Au(III) and coextraction of the radionuclides were determined with varying parameters such as kinds of solvent, molarity of HCl or pH, and Au concentration. Under the conditions where Au(III) was effectively extracted, namely extraction with ethyl acetate or isobutyl methyl ketone from 3 mol*dm -3 HCl, carrier-free radionuclides of many elements were found to be more or less coextracted. Coextraction of radionuclides of some elements was found to increase with an increase in the concentration of Au(III). This finding is ascribed to the formation of strong association of the complex of these elements with chloroauric acid. In order to avoid serious loss of these elements by the extraction, lowering of the Au(III) concentration or the use of a masking agent such as sodium citrate is necessary. Gold(III) was shown to be effectively back extracted with a 0.1 mol*dm -3 aqueous solution of 2-amino-2-hydroxymethyl-1,3-propanediol. Thus, a radiochemical procedure has been established for preparing a carrier-free multitracer and an Au tracer with carrier form from an Au target irradiated with a heavy-ion beam. Both tracers are now used individually for chemical and biological experiments. (author). 22 refs., 3 figs., 2 tabs

  15. Characterization of Ir/Au pixel TES

    International Nuclear Information System (INIS)

    Kunieda, Y.; Takahashi, H.; Zen, N.; Damayanthi, R.M.T.; Mori, F.; Fujita, K.; Nakazawa, M.; Fukuda, D.; Ohkubo, M.

    2006-01-01

    Signal shapes and noise characteristics of an asymmetrical ten-pixel Ir/Au-TES have been studied. The asymmetric design may be effective to realize an imaging spectrometer. Distinct two exponential decays observed for X-ray events are consistent with a two-step R-T curve. A theoretical thermal model for noise in multi-pixel devices reasonably explains the experimental data

  16. Le CRDI au Brésil

    International Development Research Centre (IDRC) Digital Library (Canada)

    Les recherches subventionnées par le CRDI au Brésil ont permis d'éclairer les débats sur nombre de questions, dont la démocratie, la croissance économique, la santé, les services sociaux, l'innovation, la foresterie et l'eau. Pendant la dictature militaire, qui a pris fin en 1985, le CRDI s'est employé à assurer la survie de la ...

  17. La cardiomyopathie dilatee au centre hospitalier Universitaire ...

    African Journals Online (AJOL)

    But : Afin d'améliorer la prise en charge, d'éviter l'évolution rapide vers une insuffisance cardiaque réfractaire au traitement, nous avons entrepris cette étude en milieu hospitalier. Méthode : il s'est agi d'une étude rétrospective et descriptive dans le service de cardiologie du Centre Hospitalier Universitaire Tokoin de Lomé.

  18. Decay of 184Hg to 184Au

    International Nuclear Information System (INIS)

    Nettles, W.G.; Beraud, R.; Cole, J.D.; Hamilton, J.H.; Ramayya, A.V.; Spejewski, E.H.; Sastry, K.S.R.

    1977-01-01

    Levels in 184 Au were investigated by e--γ--t and γ--γ--t coincidence techniques. A level scheme with eight definite and two tentative levels is presented; gamma branching ratios are shown. The state at 156 keV was found to have a lifetime of 36 +- 6 ns; for four of the next five levels, T 1 / 2 was less than 2 ns. 2 figures

  19. Americium/Curium Vitrification Pilot Tests - Part II

    International Nuclear Information System (INIS)

    Marra, J.E.; Baich, M.A.; Fellinger, A.P.; Hardy, B.J.; Herman, D.T.; Jones, T.M.; Miller, C.B.; Miller, D.H.; Snyder, T. K.; Stone, M.E.

    1998-05-01

    Isotopes of americium (Am) and curium (Cm) were produced in the past at the Savannah River Site (SRS) for research, medical, and radiological applications. These highly radioactive and valuable isotopes have been stored in an SRS reprocessing facility for a number of years. Vitrification of this solution will allow the material to be more safely stored until it is transported to the DOE Oak Ridge Reservation for use in research and medical applications. A previous paper described operation results from the Am-Cm Melter 2A pilot system, a full-scale non-radioactive pilot facility. This paper presents the results from continued testing in the Pilot Facility and also describes efforts taken to look at alternative vitrification process operations and flowsheets designed to address the problems observed during melter 2A pilot testing

  20. Site Features

    Data.gov (United States)

    U.S. Environmental Protection Agency — This dataset consists of various site features from multiple Superfund sites in U.S. EPA Region 8. These data were acquired from multiple sources at different times...

  1. Two-dimensional ZnO ultrathin nanosheets decorated with Au nanoparticles for effective photocatalysis

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Jin; You, Ning; Yu, Zhe; Zhou, Gang [College of Physics Science and Technology, Yangzhou University, Yangzhou 225002 (China); Xu, Xiaoyong, E-mail: xxy@yzu.edu.cn [College of Physics Science and Technology, Yangzhou University, Yangzhou 225002 (China); State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096 (China)

    2016-08-21

    Two-dimensional (2D) materials, especially the inorganic 2D nanosheets (NSs), are of particular interest due to their unique structural and electronic properties, which are favorable for photoelectronic applications such as photocatalysis. Here, we design and fabricate the ultrathin 2D ZnO NSs decorated with Au nanoparticles (AuNPs), though molecular modelling 2D hydrothermal growth and followed by surface modification are used as an effective photocatalyst for photocatalytic organic dye degradation and hydrogen production. The ultrathin 2D nature enables ultrahigh atom ratio near surface to proliferate the active sites, and the Au plasmon plays a promoting role in the visible-light absorption and photogenerated charge separation, thus integrating the synergistic benefits to boost the redox reactions at catalyst/electrolyte interface. The AuNPs-decorated ZnO NSs yield the impressive photocatalytic activities such as the dye degradation rate constant of 7.69 × 10{sup −2} min{sup −1} and the hydrogen production rate of 350 μmol h{sup −1} g{sup −1}.

  2. Order in nanometer thick intergranular films at Au-sapphire interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Baram, Mor [Department of Materials Engineering, Technion-Israel Institute of Technology, Haifa 32000 (Israel); Garofalini, Stephen H. [Department of Materials Science and Engineering, Rutgers University, Piscataway, NJ 08854-8065 (United States); Kaplan, Wayne D., E-mail: kaplan@tx.technion.ac.il [Department of Materials Engineering, Technion-Israel Institute of Technology, Haifa 32000 (Israel)

    2011-08-15

    Highlights: {yields} Au particles were equilibrated on (0 0 0 1) sapphire in the presence of anorthite. {yields} 1.2 nm thick equilibrium films (complexions) were formed at the Au-sapphire interfaces. {yields} Quantitative HRTEM was used to study the atomistic structure of the films. {yields} Structural order was observed in the 1.2 nm thick films adjacent to the sapphire crystal. {yields} This demonstrates that ordering is an intrinsic part of equilibrium intergranular films. - Abstract: In recent years extensive studies on interfaces have shown that {approx}1 nm thick intergranular films (IGF) exist at interfaces in different material systems, and that IGF can significantly affect the materials' properties. However, there is great deal of uncertainty whether such films are amorphous or partially ordered. In this study specimens were prepared from Au particles that were equilibrated on sapphire substrates in the presence of anorthite glass, leading to the formation of 1.2 nm thick IGF at the Au-sapphire interfaces. Site-specific cross-section samples were characterized using quantitative high resolution transmission electron microscopy to study the atomistic structure of the films. Order was observed in the 1.2 nm thick films adjacent to the sapphire crystal in the form of 'Ca cages', experimentally demonstrating that ordering is an intrinsic part of IGF, as predicted from molecular dynamics and diffuse interface theory.

  3. Ion-irradiation induced chemical ordering of FePt and FePtAu nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Seetala, Naidu V. [Department of Physics, Grambling State University, RWE Jones Drive, Carver Hall 81, Grambling, LA 71245 (United States)]. E-mail: naidusv@gram.edu; Harrell, J.W. [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Lawson, Jeremy [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Nikles, David E. [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Williams, John R. [Department of Physics, Auburn University, Auburn, AL 36849 (United States); Isaacs-Smith, Tamara [Department of Physics, Auburn University, Auburn, AL 36849 (United States)

    2005-12-15

    We have studied the effect of ion-beam irradiation on reducing the ordering temperature of FePt and FePtAu nanoparticles. FePt and FePt(Au14%) 4 nm particles dispersed on a Si-substrate were irradiated by 300 keV Al-ions with a dose of 1 x 10{sup 16} ions/cm{sup 2} at 43 {sup o}C using a water-cooled flange in order to minimize the vacancy migration and voids formation within the collision cascades. Partial chemical ordering has been observed in as-irradiated particles with coercivity of 60-130 Oe. Post-irradiation annealing at 220 {sup o}C enhanced chemical ordering in FePt nanoparticles with coercivity of 3500 Oe, magnetic anisotropy of 1.5 x 10{sup 7} erg/cc, and thermal stability factor of 130. A much higher 375 {sup o}C post-irradiation annealing was required in FePtAu, presumably because Au atoms were trapped at Fe/Pt lattice sites at lower temperatures. As the annealing temperature increased, anomalous features in the magnetization reversal curves were observed that disappeared at higher annealing temperatures.

  4. 14 CFR 61.73 - Military pilots or former military pilots: Special rules.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 2 2010-01-01 2010-01-01 false Military pilots or former military pilots... Ratings and Pilot Authorizations § 61.73 Military pilots or former military pilots: Special rules. (a... a disciplinary action involving aircraft operations, a U.S. military pilot or former military pilot...

  5. Pilot project as enabler?

    DEFF Research Database (Denmark)

    Neisig, Margit; Glimø, Helle; Holm, Catrine Granzow

    This article deals with a systemic perspective on transition. The field of study addressed is a pilot project as enabler of transition in a highly complex polycentric context. From a Luhmannian systemic approach, a framework is created to understand and address barriers of change occurred using...... pilot projects as enabler of transition. Aspects of how to create trust and deal with distrust during a transition are addressed. The transition in focus is the concept of New Public Management and how it is applied in the management of the Employment Service in Denmark. The transition regards...

  6. Optimizing the planar structure of (1 1 1) Au/Co/Au trilayers

    International Nuclear Information System (INIS)

    Kumah, D P; Cebollada, A; Clavero, C; Garcia-MartIn, J M; Skuza, J R; Lukaszew, R A; Clarke, R

    2007-01-01

    Au/Co/Au trilayers are interesting for a range of applications which exploit their unusual optical and electronic transport behaviour in a magnetic field. Here we present a comprehensive structural and morphological study of a series of trilayers with 0-7 nm Co layer thickness fabricated on glass by ultrahigh vacuum vapour deposition. We use a combination of in situ electron diffraction, atomic force microscopy and x-ray scattering to determine the optimum deposition conditions for highly textured, flat and continuous layered structures. The 16 nm Au-on-glass buffer layer, deposited at ambient temperature, is found to develop a smooth (1 1 1) texture on annealing at 350 deg. C for 10 min. Subsequent growth of the Co layer at 150 deg. C produces a (1 1 1) textured film with lateral grain size of ∼150 nm in the 7 nm-thick Co layer. A simultaneous in-plane and out-of-plane Co lattice expansion is observed for the thinnest Co layers, converging to bulk values for the thickest films. The roughness of the Co layer is similar to that of the Au buffer layer, indicative of conformal growth. The 6 nm Au capping layer smoothens the trilayer surface, resulting in a surface roughness independent of the Co layer thickness

  7. Magnetic properties and microstructure study of high coercivity Au/FePt/Au trilayer thin films

    International Nuclear Information System (INIS)

    Chen, S.K.; Yuan, F.T.; Liao, W.M.; Hsu, C.W.; Horng, Lance

    2006-01-01

    High-coercivity Au(60 nm)/FePt(δ nm)/Au(60 nm) trilayer samples were prepared by sputtering at room temperature, followed by post annealing at different temperatures. For the sample with δ=60 nm, L1 ordering transformation occurs at 500 deg. C. Coercivity (H c ) is increased with the annealing temperature in the studied range 400-800 deg. C. The H c value of the trilayer films is also varied with thickness of FePt intermediate layer (δ), from 27 kOe for δ=60 nm to a maximum value of 33.5 kOe for δ=20 nm. X-ray diffraction data indicate that the diffusion of Au atoms into the FePt L1 lattice is negligible even after a high-temperature (800 deg. C) annealing process. Furthermore, ordering parameter is almost unchanged as δ is reduced from 60 to 15 nm. Transmission electron microscope (TEM) photos indicate that small FePt Ll particles are dispersed amid the large-grained Au. We believe that the high coercivity of the trilayer sample is attributed to the small and uniform grain sizes of the highly ordered FePt particles which have perfect phase separation with Au matrix

  8. Single-Pilot Workload Management

    Science.gov (United States)

    Rogers, Jason; Williams, Kevin; Hackworth, Carla; Burian, Barbara; Pruchnicki, Shawn; Christopher, Bonny; Drechsler, Gena; Silverman, Evan; Runnels, Barry; Mead, Andy

    2013-01-01

    Integrated glass cockpit systems place a heavy cognitive load on pilots (Burian Dismukes, 2007). Researchers from the NASA Ames Flight Cognition Lab and the FAA Flight Deck Human Factors Lab examined task and workload management by single pilots. This poster describes pilot performance regarding programming a reroute while at cruise and meeting a waypoint crossing restriction on the initial descent.

  9. Pilot pulsar surveys with LOFAR

    NARCIS (Netherlands)

    Coenen, T.

    2013-01-01

    We are performing two complementary pilot pulsar surveys as part of LOFAR commissioning. The LOFAR Pilot Pulsar Survey (LPPS) is a shallow all-sky survey using an incoherent combination of LOFAR stations. The LOFAR Tied-Array Survey (LOTAS) is a deeper pilot survey using 19 simultaneous tied-array

  10. Au 38 (SPh) 24 : Au 38 Protected with Aromatic Thiolate Ligands

    Energy Technology Data Exchange (ETDEWEB)

    Rambukwella, Milan; Burrage, Shayna; Neubrander, Marie; Baseggio, Oscar; Aprà, Edoardo; Stener, Mauro; Fortunelli, Alessandro; Dass, Amala

    2017-03-21

    Au38(SR)24 is one of the most extensively investigated gold nanomolecules along with Au25(SR)18 and Au144(SR)60. However, so far it has only been prepared using aliphatic-like ligands, where R = –SC6H13, -SC12H25 and –SCH2CH2Ph. Au38(SCH2CH2Ph)24 when reacted with HSPh undergoes core-size conversion to Au36(SPh)24, and existing literature suggest that Au38(SPh)24 cannot be synthesized. Here, contrary to prevailing knowledge, we demonstrate that Au38(SPh)24 can be prepared if the ligand exchanged conditions are optimized, without any formation of Au36(SPh)24. Conclusive evidence is presented in the form of MALDI-MS, ESI-MS characterization, and optical spectra of Au38(SPh)24 in a solid glass form showing distinct differences from that of Au38(S-aliphatic)24. Theoretical analysis confirms experimental assignment of the optical spectrum and shows that the stability of Au38(SPh)24 is comparable to that of its aliphatic analogues, but results from different physical origins, with a significant component of ligand-ligand attractive interactions.

  11. Site decontamination

    International Nuclear Information System (INIS)

    Bicker, A.E.

    1981-01-01

    Among the several DOE sites that have been radiologically decontaminated under the auspices of the Nevada Operations Office are three whose physical characteristics are unique. These are the Tatum Dome Test Site (TDTS) near Hattiesburg, Mississippi; a location of mountainous terrain (Pahute Mesa) on the Nevada Test Site; and the GNOME site near Carlsbad, New Mexico. In each case the contamination, the terrain, and the climate conditions were different. This presentation includes a brief description of each site, the methods used to perform radiological surveys, the logistics required to support the decontamination (including health physics and sample analysis), and the specific techniques used to reduce or remove the contamination

  12. PILOT DECONTAMINATION THROUGH PILOT SEQUENCE HOPPING IN MASSIVE MIMO SYSTEMS

    DEFF Research Database (Denmark)

    2015-01-01

    path between one of the users and one of the base stations define one of the channels. The system comprises a pilot generation unit configured to assign pilot sequences randomly among the users and a pilot processing unit configured to filter the pilot sequences received from a user of interest so...... that the channel coefficient of the channel of the user of interest is determined. The pilot sequences received from the user of interest are contaminated by other non-orthogonal or identical pilot sequences from other users of the cell of interest or other cells. The filter is configured so that the contamination...... caused by the other non-orthogonal or identical pilot sequences from the other users is reduced....

  13. Search for toroidal and bubble nuclei formed in the Au + Au reaction

    International Nuclear Information System (INIS)

    Planeta, R.; Brzychczyk, J.; Majka, Z.; Blicharska, J.; Grzeszczuk, A.; Zipper, W.; Schmidt, K.; Kowalski, S.; Cibor, J.; Hachaj, P.; Nicolis, N.

    2003-01-01

    In this contribution we present the feasibility study for the experimental observation of toroidal and bubble nuclei. This search is based on data collected by the CHIMERA collaboration for the Au + Au reaction at 15 MeV/nucleon. The beam time needed to achieve this goal is calculated for events with at least 5 heavy fragments. We found that the fraction of such events among the accumulated data is equal to 8*10 -4 . Assuming the Au beam intensity is 0.03 pnA and target thickness equals 0.3 mg/cm 2 we estimated that 450 hours of beam time is needed to record 10 6 multifragment events. Present status of the Monte-Carlo simulation predictions is shortly discussed. (A.C.)

  14. Search for toroidal and bubble nuclei formed in the Au + Au reaction

    Energy Technology Data Exchange (ETDEWEB)

    Planeta, R.; Brzychczyk, J.; Majka, Z. [M.Smoluchowski Institute of Physics, Jagellonian University, Krakow (Poland); Blicharska, J.; Grzeszczuk, A.; Zipper, W.; Schmidt, K.; Kowalski, S. [Silesian University, Institute of Physics, Katowice (Poland); Cibor, J. [Institute of Nuclear Physics, Krakow (Poland); Hachaj, P. [Cracow Univ. of Technology, Krakow (Poland); Nicolis, N. [Ioannina Univ. (Greece)

    2003-07-01

    In this contribution we present the feasibility study for the experimental observation of toroidal and bubble nuclei. This search is based on data collected by the CHIMERA collaboration for the Au + Au reaction at 15 MeV/nucleon. The beam time needed to achieve this goal is calculated for events with at least 5 heavy fragments. We found that the fraction of such events among the accumulated data is equal to 8*10{sup -4}. Assuming the Au beam intensity is 0.03 pnA and target thickness equals 0.3 mg/cm{sup 2} we estimated that 450 hours of beam time is needed to record 10{sup 6} multifragment events. Present status of the Monte-Carlo simulation predictions is shortly discussed. (A.C.)

  15. Photoluminescence from Au nanoparticles embedded in Au:oxide composite films

    Science.gov (United States)

    Liao, Hongbo; Wen, Weijia; Wong, George K.

    2006-12-01

    Au:oxide composite multilayer films with Au nanoparticles sandwiched by oxide layers (such as SiO2, ZnO, and TiO2) were prepared in a magnetron sputtering system. Their photoluminescence (PL) spectra were investigated by employing a micro-Raman system in which an Argon laser with a wavelength of 514 nm was used as the pumping light. Distinct PL peaks located at a wavelength range between 590 and 680 nm were observed in most of our samples, with Au particle size varying from several to hundreds of nanometers. It was found that the surface plasmon resonance (SPR) in these composites exerted a strong influence on the position of the PL peaks but had little effect on the PL intensity.

  16. Photoluminescence from Au nanoparticles embedded in Au:oxide composite films

    International Nuclear Information System (INIS)

    Liao Hongbo; Wen Weijia; Wong, George K. L.

    2006-01-01

    Au:oxide composite multilayer films with Au nanoparticles sandwiched by oxide layers (such as SiO 2 , ZnO, and TiO 2 ) were prepared in a magnetron sputtering system. Their photoluminescence (PL) spectra were investigated by employing a micro-Raman system in which an Argon laser with a wavelength of 514 nm was used as the pumping light. Distinct PL peaks located at a wavelength range between 590 and 680 nm were observed in most of our samples, with Au particle size varying from several to hundreds of nanometers. It was found that the surface plasmon resonance (SPR) in these composites exerted a strong influence on the position of the PL peaks but had little effect on the PL intensity

  17. Charge transport through O-deficient Au-MgO-Au junctions

    KAUST Repository

    Fadlallah, M. M.; Eckern, Ulrich; Rungger, Ivan; Schuster, Cosima; Schwingenschlö gl, Udo

    2009-01-01

    Metal-oxide heterostructures have been attracting considerable attention in recent years due to various technological applications. We present results of electronic structure and transport calculations for the Au-MgO-Au (metal-insulator-metal) heterostructure based on density-functional theory and the nonequilibrium Green’s functions method. The dependence of the conductance of the heterostructure on the thickness of the MgO interlayer and the interface spacing is studied. In addition, we address the effects of O vacancies. We observe deviations from an exponentially suppressed conductance with growing interlayer thickness caused by Au-O chemical bonds. Electronic states tracing back to O vacancies can increase the conductance. Furthermore, this effect can be enhanced by enlarging the interface spacing as the vacancy induced Mg states are shifted toward the Fermi energy.

  18. Charge transport through O-deficient Au-MgO-Au junctions

    KAUST Repository

    Fadlallah, M. M.

    2009-12-29

    Metal-oxide heterostructures have been attracting considerable attention in recent years due to various technological applications. We present results of electronic structure and transport calculations for the Au-MgO-Au (metal-insulator-metal) heterostructure based on density-functional theory and the nonequilibrium Green’s functions method. The dependence of the conductance of the heterostructure on the thickness of the MgO interlayer and the interface spacing is studied. In addition, we address the effects of O vacancies. We observe deviations from an exponentially suppressed conductance with growing interlayer thickness caused by Au-O chemical bonds. Electronic states tracing back to O vacancies can increase the conductance. Furthermore, this effect can be enhanced by enlarging the interface spacing as the vacancy induced Mg states are shifted toward the Fermi energy.

  19. Cation-Poor Complex Metallic Alloys in Ba(Eu)-Au-Al(Ga) Systems: Identifying the Keys that Control Structural Arrangements and Atom Distributions at the Atomic Level.

    Science.gov (United States)

    Smetana, Volodymyr; Steinberg, Simon; Mudryk, Yaroslav; Pecharsky, Vitalij; Miller, Gordon J; Mudring, Anja-Verena

    2015-11-02

    Four complex intermetallic compounds BaAu(6±x)Ga(6±y) (x = 1, y = 0.9) (I), BaAu(6±x)Al(6±y) (x = 0.9, y = 0.6) (II), EuAu6.2Ga5.8 (III), and EuAu6.1Al5.9 (IV) have been synthesized, and their structures and homogeneity ranges have been determined by single crystal and powder X-ray diffraction. Whereas I and II originate from the NaZn13-type structure (cF104-112, Fm3̅c), III (tP52, P4/nbm) is derived from the tetragonal Ce2Ni17Si9-type, and IV (oP104, Pbcm) crystallizes in a new orthorhombic structure type. Both I and II feature formally anionic networks with completely mixed site occupation by Au and triel (Tr = Al, Ga) atoms, while a successive decrease of local symmetry from the parental structures of I and II to III and, ultimately, to IV correlates with increasing separation of Au and Tr on individual crystallographic sites. Density functional theory-based calculations were employed to determine the crystallographic site preferences of Au and the respective triel element to elucidate reasons for the atom distribution ("coloring scheme"). Chemical bonding analyses for two different "EuAu6Tr6" models reveal maximization of the number of heteroatomic Au-Tr bonds as the driving force for atom organization. The Fermi levels fall in broad pseudogaps for both models allowing some electronic flexibility. Spin-polarized band structure calculations on the "EuAu6Tr6" models hint to singlet ground states for europium and long-range magnetic coupling for both EuAu6.2Ga5.8 (III) and EuAu6.1Al5.9 (IV). This is substantiated by experimental evidence because both compounds show nearly identical magnetic behavior with ferromagnetic transitions at TC = 6 K and net magnetic moments of 7.35 μB/f.u. at 2 K. The effective moments of 8.3 μB/f.u., determined from Curie-Weiss fits, point to divalent oxidation states for europium in both III and IV.

  20. Evidence of significant covalent bonding in Au(CN)(2)(-).

    Science.gov (United States)

    Wang, Xue-Bin; Wang, Yi-Lei; Yang, Jie; Xing, Xiao-Peng; Li, Jun; Wang, Lai-Sheng

    2009-11-18

    The Au(CN)(2)(-) ion is the most stable Au compound known for centuries, yet a detailed understanding of its chemical bonding is still lacking. Here we report direct experimental evidence of significant covalent bonding character in the Au-C bonds in Au(CN)(2)(-) using photoelectron spectroscopy and comparisons with its lighter congeners, Ag(CN)(2)(-) and Cu(CN)(2)(-). Vibrational progressions in the Au-C stretching mode were observed for all detachment transitions for Au(CN)(2)(-), in contrast to the atomic-like transitions for Cu(CN)(2)(-), revealing the Au-C covalent bonding character. In addition, rich electronic structural information was obtained for Au(CN)(2)(-) by employing 118 nm detachment photons. Density functional theory and high-level ab initio calculations were carried out to understand the photoelectron spectra and obtain insight into the nature of the chemical bonding in the M(CN)(2)(-) complexes. Significant covalent character in the Au-C bonding due to the strong relativistic effects was revealed in Au(CN)(2)(-), consistent with its high stability.

  1. Evaluatie pilot Financieringslink

    NARCIS (Netherlands)

    Rosenboom, N.; Rougoor, W.; Fijnje, J.; Biesenbeek, C.

    Veel mkb-ondernemers hebben moeite om financiering te krijgen. Daarom heeft het ministerie van Economische Zaken in 2015 de pilot Financieringslink (Fink) opgezet– een online portal waar het mkb een financieringsverkenning kan indienen. Het hoofddoel van Fink is het verbeteren, standaardiseren en

  2. The Epoch Pilot Program.

    Science.gov (United States)

    Uhlenberg, Donald M.; Molenaar, Richard A.

    1982-01-01

    Describes a program for high school students who are between their junior and senior years which provides an opportunity to take part in aviation courses at the University of North Dakota. Students take courses leading to a private pilot license, and earn college credit for their efforts. (JN)

  3. Evaluatie pilot Endogene Factoren

    NARCIS (Netherlands)

    Viet AL; Fiolet D; Voortman JK; Rover C de; Hanning C; Uitenbroek D; Loon AJM van; PZO; GGD Achterhoek; GGD Midden Holland; GG&GD Amsterdam

    2004-01-01

    As a part of the project on the Local and National Monitor for Public Health several pilot studies were carried out in three Municipal Health Centres (GGDs). The first aim was to investigate the feasibility of a physical examination at the health centre in combination with a health interview (or

  4. Site organization and site arrangement

    International Nuclear Information System (INIS)

    Boissonnet, B.; Macqueron, J.F.

    1976-01-01

    The present paper deals with criteria for the choice of a production unit or power plant site, the organization and development of a site in terms of its particular characteristics and takes into account personnel considerations in site organizations as well as the problem of integrating the architecture into the environment. (RW) [de

  5. Production of φ mesons in Au-Au collisions at the AGS

    International Nuclear Information System (INIS)

    Back, B. B.; Betts, R. R.; Chang, J.; Gillitzer, A.; Henning, W. F.; Hofman, D. J.; Nanal, V.; Seto, R.; Wuosmaa, A. H.; Xiang, H.

    1999-01-01

    The first measurements of φ meson production in Au-Au collisions at AGS energies are presented via the decay to K + K - . A measurement of the centrality dependence of the yield shows an increase similar to that seen for the K - with a spectral shape consistent with a relativistic Breit-Wigner distribution within the statistical errors of the present data set. Future analysis using the full data set with 4 times the statistics will allow a more accurate determination of the yields, slopes and spectral shapes

  6. Elliptic Flow in Au+Au Collisions at √sNN = 130 GeV

    Science.gov (United States)

    Ackermann, K. H.; Adams, N.; Adler, C.; Ahammed, Z.; Ahmad, S.; Allgower, C.; Amsbaugh, J.; Anderson, M.; Anderssen, E.; Arnesen, H.; Arnold, L.; Averichev, G. S.; Baldwin, A.; Balewski, J.; Barannikova, O.; Barnby, L. S.; Baudot, J.; Beddo, M.; Bekele, S.; Belaga, V. V.; Bellwied, R.; Bennett, S.; Bercovitz, J.; Berger, J.; Betts, W.; Bichsel, H.; Bieser, F.; Bland, L. C.; Bloomer, M.; Blyth, C. O.; Boehm, J.; Bonner, B. E.; Bonnet, D.; Bossingham, R.; Botlo, M.; Boucham, A.; Bouillo, N.; Bouvier, S.; Bradley, K.; Brady, F. P.; Braithwaite, E. S.; Braithwaite, W.; Brandin, A.; Brown, R. L.; Brugalette, G.; Byrd, C.; Caines, H.; Calderón de La Barca Sánchez, M.; Cardenas, A.; Carr, L.; Carroll, J.; Castillo, J.; Caylor, B.; Cebra, D.; Chatopadhyay, S.; Chen, M. L.; Chen, W.; Chen, Y.; Chernenko, S. P.; Cherney, M.; Chikanian, A.; Choi, B.; Chrin, J.; Christie, W.; Coffin, J. P.; Conin, L.; Consiglio, C.; Cormier, T. M.; Cramer, J. G.; Crawford, H. J.; Danilov, V. I.; Dayton, D.; Demello, M.; Deng, W. S.; Derevschikov, A. A.; Dialinas, M.; Diaz, H.; Deyoung, P. A.; Didenko, L.; Dimassimo, D.; Dioguardi, J.; Dominik, W.; Drancourt, C.; Draper, J. E.; Dunin, V. B.; Dunlop, J. C.; Eckardt, V.; Edwards, W. R.; Efimov, L. G.; Eggert, T.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Etkin, A.; Fachini, P.; Feliciano, C.; Ferenc, D.; Ferguson, M. I.; Fessler, H.; Finch, E.; Fine, V.; Fisyak, Y.; Flierl, D.; Flores, I.; Foley, K. J.; Fritz, D.; Gagunashvili, N.; Gans, J.; Gazdzicki, M.; Germain, M.; Geurts, F.; Ghazikhanian, V.; Gojak, C.; Grabski, J.; Grachov, O.; Grau, M.; Greiner, D.; Greiner, L.; Grigoriev, V.; Grosnick, D.; Gross, J.; Guilloux, G.; Gushin, E.; Hall, J.; Hallman, T. J.; Hardtke, D.; Harper, G.; Harris, J. W.; He, P.; Heffner, M.; Heppelmann, S.; Herston, T.; Hill, D.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffmann, G. W.; Horsley, M.; Howe, M.; Huang, H. Z.; Humanic, T. J.; Hümmler, H.; Hunt, W.; Hunter, J.; Igo, G. J.; Ishihara, A.; Ivanshin, Yu. I.; Jacobs, P.; Jacobs, W. W.; Jacobson, S.; Jared, R.; Jensen, P.; Johnson, I.; Jones, P. G.; Judd, E.; Kaneta, M.; Kaplan, M.; Keane, D.; Kenney, V. P.; Khodinov, A.; Klay, J.; Klein, S. R.; Klyachko, A.; Koehler, G.; Konstantinov, A. S.; Kormilitsyne, V.; Kotchenda, L.; Kotov, I.; Kovalenko, A. D.; Kramer, M.; Kravtsov, P.; Krueger, K.; Krupien, T.; Kuczewski, P.; Kuhn, C.; Kunde, G. J.; Kunz, C. L.; Kutuev, R. Kh.; Kuznetsov, A. A.; Lakehal-Ayat, L.; Lamas-Valverde, J.; Lamont, M. A.; Landgraf, J. M.; Lange, S.; Lansdell, C. P.; Lasiuk, B.; Laue, F.; Lebedev, A.; Lecompte, T.; Leonhardt, W. J.; Leontiev, V. M.; Leszczynski, P.; Levine, M. J.; Li, Q.; Li, Q.; Li, Z.; Liaw, C.-J.; Lin, J.; Lindenbaum, S. J.; Lindenstruth, V.; Lindstrom, P. J.; Lisa, M. A.; Liu, H.; Ljubicic, T.; Llope, W. J.; Locurto, G.; Long, H.; Longacre, R. S.; Lopez-Noriega, M.; Lopiano, D.; Love, W. A.; Lutz, J. R.; Lynn, D.; Madansky, L.; Maier, R.; Majka, R.; Maliszewski, A.; Margetis, S.; Marks, K.; Marstaller, R.; Martin, L.; Marx, J.; Matis, H. S.; Matulenko, Yu. A.; Matyushevski, E. A.; McParland, C.; McShane, T. S.; Meier, J.; Melnick, Yu.; Meschanin, A.; Middlekamp, P.; Mikhalin, N.; Miller, B.; Milosevich, Z.; Minaev, N. G.; Minor, B.; Mitchell, J.; Mogavero, E.; Moiseenko, V. A.; Moltz, D.; Moore, C. F.; Morozov, V.; Morse, R.; de Moura, M. M.; Munhoz, M. G.; Mutchler, G. S.; Nelson, J. M.; Nevski, P.; Ngo, T.; Nguyen, M.; Nguyen, T.; Nikitin, V. A.; Nogach, L. V.; Noggle, T.; Norman, B.; Nurushev, S. B.; Nussbaum, T.; Nystrand, J.; Odyniec, G.; Ogawa, A.; Ogilvie, C. A.; Olchanski, K.; Oldenburg, M.; Olson, D.; Ososkov, G. A.; Ott, G.; Padrazo, D.; Paic, G.; Pandey, S. U.; Panebratsev, Y.; Panitkin, S. Y.; Pavlinov, A. I.; Pawlak, T.; Pentia, M.; Perevotchikov, V.; Peryt, W.; Petrov, V. A.; Pinganaud, W.; Pirogov, S.; Platner, E.; Pluta, J.; Polk, I.; Porile, N.; Porter, J.; Poskanzer, A. M.; Potrebenikova, E.; Prindle, D.; Pruneau, C.; Puskar-Pasewicz, J.; Rai, G.; Rasson, J.; Ravel, O.; Ray, R. L.; Razin, S. V.; Reichhold, D.; Reid, J.; Renfordt, R. E.; Retiere, F.; Ridiger, A.; Riso, J.; Ritter, H. G.; Roberts, J. B.; Roehrich, D.; Rogachevski, O. V.; Romero, J. L.; Roy, C.; Russ, D.; Rykov, V.; Sakrejda, I.; Sanchez, R.; Sandler, Z.; Sandweiss, J.; Sappenfield, P.; Saulys, A. C.; Savin, I.; Schambach, J.; Scharenberg, R. P.; Scheblien, J.; Scheetz, R.; Schlueter, R.; Schmitz, N.; Schroeder, L. S.; Schulz, M.; Schüttauf, A.; Sedlmeir, J.; Seger, J.; Seliverstov, D.; Seyboth, J.; Seyboth, P.; Seymour, R.; Shakaliev, E. I.; Shestermanov, K. E.; Shi, Y.; Shimanskii, S. S.; Shuman, D.; Shvetcov, V. S.; Skoro, G.; Smirnov, N.; Smykov, L. P.; Snellings, R.; Solberg, K.; Sowinski, J.; Spinka, H. M.; Srivastava, B.; Stephenson, E. J.; Stock, R.; Stolpovsky, A.; Stone, N.; Stone, R.; Strikhanov, M.; Stringfellow, B.; Stroebele, H.; Struck, C.; Suaide, A. A.; Sugarbaker, E.; Suire, C.; Symons, T. J.; Takahashi, J.; Tang, A. H.; Tarchini, A.; Tarzian, J.; Thomas, J. H.; Tikhomirov, V.; Szanto de Toledo, A.; Tonse, S.; Trainor, T.; Trentalange, S.; Tokarev, M.; Tonjes, M. B.; Trofimov, V.; Tsai, O.; Turner, K.; Ullrich, T.; Underwood, D. G.; Vakula, I.; van Buren, G.; Vandermolen, A. M.; Vanyashin, A.; Vasilevski, I. M.; Vasiliev, A. N.; Vigdor, S. E.; Visser, G.; Voloshin, S. A.; Vu, C.; Wang, F.; Ward, H.; Weerasundara, D.; Weidenbach, R.; Wells, R.; Wells, R.; Wenaus, T.; Westfall, G. D.; Whitfield, J. P.; Whitten, C.; Wieman, H.; Willson, R.; Wilson, K.; Wirth, J.; Wisdom, J.; Wissink, S. W.; Witt, R.; Wolf, J.; Wood, L.; Xu, N.; Xu, Z.; Yakutin, A. E.; Yamamoto, E.; Yang, J.; Yepes, P.; Yokosawa, A.; Yurevich, V. I.; Zanevski, Y. V.; Zhang, J.; Zhang, W. M.; Zhu, J.; Zimmerman, D.; Zoulkarneev, R.; Zubarev, A. N.

    2001-01-01

    Elliptic flow from nuclear collisions is a hadronic observable sensitive to the early stages of system evolution. We report first results on elliptic flow of charged particles at midrapidity in Au+Au collisions at sNN = 130 GeV using the STAR Time Projection Chamber at the Relativistic Heavy Ion Collider. The elliptic flow signal, v2, averaged over transverse momentum, reaches values of about 6% for relatively peripheral collisions and decreases for the more central collisions. This can be interpreted as the observation of a higher degree of thermalization than at lower collision energies. Pseudorapidity and transverse momentum dependence of elliptic flow are also presented.

  7. Narrowing of the balance function with centrality in Au + Au collisions at √sNN

    International Nuclear Information System (INIS)

    Adams, J.; Alder, C.; Ahammed, Z.; Allgower, C.; Amonett, J.; Anderson, B.D.; Anderson, M.; Averichev, G.S.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellwied, R.; Berger, J.; Bichsel, H.; Billmeier, A.; Bland, L.C.; Blyth, C.O.; Bonner, B.E.; Boucham, A.; Brandin, A.; Bravar, A.; Cadman, R.V.; Caines, H.; Calderonde la Barca Sanchez, M.; Cardenas, A.; Carroll, J.; Castillo, J.; Castro, M.; Cebra, D.; Chaloupka, P.; Chattopadhyay, S.; Chen, Y.; Chernenko, S.P.; Cherney, M.; Chikanian, A.; Choi, B.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Corral, M.M.; Cramer, J.G.; Crawford, H.J.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Draper, J.E.; Dunin, V.B.; Dunlop, J.C.; Eckardt, V.; Efimov, L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Fachini, P.; Faine, V.; Faivre, J.; Fatemi, R.; Filimonov, K.; Finch, E.; Fisyak, Y.; Flierl, D.; Foley, K.J.; Fu, J.; Gagliardi, C.A.; Gagunashvili, N.; Gans, J.; Gaudichet, L.; Germain, M.; Geurts, F.; Ghazikhanian, V.; Grachov, O.; Grigoriev, V.; Guedon, M.; Guertin, S.M.; Gushin, E.; Hallman, T.J.; Hardtke, D.; Harris, J.W.; Heinz, M.; Henry, T.W.; Heppelmann, S.; Herston, T.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffmann, G.W.; Horsley, M.; Huang, H.Z.; Humanic, T.J.; Igo, G.; Ishihara, A.; Ivanshin, Yu.I.; Jacobs, P.; Jacobs, W.W.; Janik, M.; Johnson, I.; Jones, P.G.; Judd, E.G.; Kaneta, M.; Kaplan, M.; Keane, D.; Kiryluk, J.; Kisiel, A.; Klay, J.; Klein, S.R.; Klyachko, A.; Kollegger, T.; Konstantinov, A.S.; Kopytine, M.; Kotchenda, L.; Kovalenko, A.D.; Kramer, M.; Kravtsov, P.; Krueger, K.; Kuhn, C.; Kulikov, A.I.; Kunde, G.J.; Kunz, C.L.; Kutuev, R.Kh.; Kuznetsov, A.A.; Lamont, M.A.C.; Landgraf, J.M.; Lange, S.; Lansdell, C.P.; Lasiuk, B.; Laue, F.; Lauret, J.; Lebedev, A.; Lednicky, R.; Leontiev, V.M.; LeVine, M.J.; Li, Q.; Lindenbaum, S.J.; Lisa, M.A.; Liu, F.; Liu, L.; Liu, Z.; Liu, Q.J.; Ljubicic, T.; Llope, W.J.; Long, H.

    2003-01-01

    The balance function is a new observable based on the principle that charge is locally conserved when particles are pair produced. Balance functions have been measured for charged particle pairs and identified charged pion pairs in Au + Au collisions at √sNN = 130 GeV at the Relativistic Heavy Ion Collider using STAR. Balance functions for peripheral collisions have widths consistent with model predictions based on a superposition of nucleon-nucleon scattering. Widths in central collisions are smaller, consistent with trends predicted by models incorporating late hadronization

  8. Proton channeling in Au at low energies; Canalizacion de protones en Au a bajas energias

    Energy Technology Data Exchange (ETDEWEB)

    Valdes, J E; Vargas, P [Chile Univ., Santiago (Chile). Dept. de Fisica

    1997-12-31

    The electronic energy loss for low velocity protons channeled in the <100> direction single crystal Au is calculated. The spatial distribution of valence electronic density in Au is calculated using Tight Binding Linear Muffin Tin Method. The proton trajectories are determined by numerical integration of the classical motion equation, and the energy loss is evaluated using the calculated valence electronic density in the friction term. The results allow to describe qualitatively the non linear behavior of energy loss with ion velocity observed experimentally. (author). 14 refs., 4 figs.

  9. D and $^{3}He$ production in $\\sqrt{s}$ = 130 GeV Au + Au collisions

    CERN Document Server

    Adler, C; Allgower, C; Amonett, J; Anderson, B D; Anderson, M; Averichev, G S; Balewski, J T; Barannikova, O Yu; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bichsel, H; Bland, L C; Blyth, C O; Bonner, B E; Boucham, A; Brandin, A B; Cadman, R V; Caines, H; Calderón de la Barca-Sanchez, M; Cardenas, A; Carroll, J; Castillo, J; Castro, M; Cebra, D; Chattopadhyay, S; Chen, M L; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Christie, W; Cormier, T M; Cramer, J G; Crawford, H J; De Mello, M; Deng, W S; Derevshchikov, A A; Didenko, L; Draper, J E; Dunin, V B; Dunlop, J C; Eckardt, V; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Fachini, P; Faine, V; Finch, E; Fisyak, Yu; Flierl, D; Foley, Kenneth J; Fu, J; Gagunashvili, N D; Gans, J; Gaudichet, L; Germain, M; Geurts, F J M; Ghazikhanian, V; Grabski, J; Grachov, O A; Greiner, D E; Grigoriev, V; Guedon, M; Guschin, E; Hallman, T J; Hardtke, D; Harris, J W; Heffner, M; Heppelmann, S; Herston, T; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Huang, H Z; Humanic, T J; Hümmler, H; Igo, G; Ishihara, A; Ivanshin, Yu I; Jacobs, P; Jacobs, W W; Janik, M; Johnson, I; Jones, P G; Judd, E; Kaneta, M; Kaplan, M; Keane, D; Kisiel, A; Klay, J L; Klein, S R; Klyachko, A A; Konstantinov, A S; Kotchenda, L; Kovalenko, A D; Krämer, M; Kravtsov, P; Krüger, K; Kuhn, C; Kulikov, A V; Kunde, G J; Kunz, C L; Kutuev, R K; Kuznetsov, A A; Lakehal-Ayat, L; Lamas-Valverde, J; Lamont, M A C; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lebedev, A; LeCompte, T J; Lednicky, R; Leontiev, V M; Le Vine, M J; Li, Q; Lindenbaum, S J; Lisa, M A; Ljubicic, T; Llope, W J; Lo Curto, G; Long, H; Longacre, R S; López-Noriega, M; Love, W A; Lynn, D; Majka, R; Margetis, S; Martin, L; Marx, J; Matis, H S; Matulenko, Yu A; McShane, T S; Meissner, F; Melnik, Yu M; Meshchanin, A P; Messer, M; Miller, M L; Milosevich, Z; Minaev, N G; Mitchell, J; Moiseenko, V A; Moltz, D; Moore, C F; Morozov, V; De Moura, M M; Munhoz, M G; Mutchler, G S; Nelson, J M; Nevski, P; Nikitin, V A; Nogach, L V; Norman, B; Nurushev, S B; Odyniec, Grazyna Janina; Ogawa, A; Okorokov, V; Oldenburg, M; Oson, D; Paic, G; Pandey, S U; Panebratsev, Yu A; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Perevozchikov, V; Peryt, W; Petrov, V A; Platner, E D; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potrebenikova, E V; Prindle, D J; Pruneau, C A; Radomski, S; Rai, G; Ravel, O; Ray, R L; Razin, S V; Reichhold, D M; Reid, J G; Retière, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Roy, C; Russ, D; Rykov, V L; Sakrejda, I; Sandweiss, J; Saulys, A C; Savin, I; Schambach, J; Scharenberg, R P; Schmitz, N; Schröder, L S; Schüttauf, A; Schweda, K; Seger, J E; Seliverstov, D M; Seyboth, P; Shahaliev, E; Shestermanov, K E; Shimansky, S S; Shvetcov, V S; Skoro, G P; Smirnov, N; Snellings, R; Sowinski, J; Spinka, H M; Srivastava, B; Stephenson, E J; Stock, Reinhard; Stolpovsky, A; Strikhanov, M N; Stringfellow, B C; Struck, C; Suaide, A A P; Sugarbaker, E R; Suire, C; Sumbera, M; Symons, T J M; Szanto de Toledo, A; Szarwas, P; Takahashi, J; Tang, A H; Thomas, J H; Tikhomirov, V; Trainor, T A; Trentalange, S; Tokarev, M; Tonjes, M B; Trofimov, V; Tsai, O; Turner, K; Ullrich, T S; Underwood, D G; Van Buren, G; Van der Molen, A; Vanyashin, A V; Vasilevski, I M; Vasilev, A N; Vigdor, S E; Voloshin, S A; Wang, F; Ward, H; Watson, J W; Wells, R; Wenaus, T J; Westfall, G D; Whitten, C; Wieman, H H; Willson, R; Wissink, S W; Witt, R; Xu, N; Xu, Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yokosawa, A; Yurevich, V I; Zanevsky, Yu V; Zborovský, I; Zhang, H; Zhang, W M; Zoulkarneev, R; Zubarev, A N; 10.1103/PhysRevLett.87.262301

    2001-01-01

    The first measurements of light antinucleus production in Au + Au collisions at the Relativistic Heavy-Ion Collider are reported. The observed production rates for d and /sup 3/He are much larger than in lower energy nucleus-nucleus collisions. A coalescence model analysis of the yields indicates that there is little or no increase in the antinucleon freeze-out volume compared to collisions at CERN SPS energy. These analyses also indicate that the 3He freeze-out volume is smaller than the d freeze-out volume. (22 refs).

  10. Light Fragment Production and Power Law Behavior in Au + Au Collisions

    International Nuclear Information System (INIS)

    Wang, S.; Albergo, S.; Bieser, F.; Brady, F.P.; Caccia, Z.; Cebra, D.A.; Chacon, A.D.; Chance, J.L.; Choi, Y.; Costa, S.; Elliott, J.B.; Gilkes, M.L.; Hauger, J.A.; Hirsch, A.S.; Hjort, E.L.; Insolia, A.; Justice, M.; Keane, D.; Kintner, J.; Lisa, M.A.; Matis, H.S.; McMahan, M.; McParland, C.; Olson, D.L.; Partlan, M.D.; Porile, N.T.; Potenza, R.; Rai, G.; Rasmussen, J.; Ritter, H.G.; Romanski, J.; Romero, J.L.; Russo, G.V.; Scharenberg, R.P.; Scott, A.; Shao, Y.; Srivastava, B.K.; Symons, T.J.M.; Tincknell, M.L.; Tuve, C.; Warren, P.G.; Weerasundara, D.; Wieman, H.H.; Wolf, K.L.

    1995-01-01

    Using charged-particle-exclusive measurements of Au+Au collisions in the LBL Bevalac's EOS time projection chamber, we investigate momentum-space densities of fragments up to 4 He as a function of fragment transverse momentum, azimuth relative to the reaction plane, rapidity, multiplicity, and beam energy. Most features of these densities above a transverse momentum threshold are consistent with momentum-space coalescence, and, in particular, the increase in sideward flow with fragment mass is generally well described by a momentum-space power law

  11. Energy Dependence of Particle Multiplicities in Central Au+Au Collisions

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Corbo, J.; Decowski, M. P.; Garcia, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Henderson, C.; Hicks, D.; Hofman, D.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Michałowski, J.; Mignerey, A.; Mülmenstädt, J.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Rafelski, M.; Rbeiz, M.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S. G.; Steinberg, P.; Stephans, G. S.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Verdier, R.; Wadsworth, B.; Wolfs, F. L.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    2002-01-01

    We present the first measurement of the pseudorapidity density of primary charged particles in Au+Au collisions at (sNN) = 200 GeV. For the 6% most central collisions, we obtain dNch/dη\\|\\|η\\|<1 = 650+/-35(syst). Compared to collisions at (sNN) = 130 GeV, the highest energy studied previously, an increase by a factor of 1.14+/-0.05 at 90% confidence level, is found. The energy dependence of the pseudorapidity density is discussed in comparison with data from proton-induced collisions and theoretical predictions.

  12. CHARGED PARTICLE MULTIPLICITIES IN ULTRA-RELATIVISTIC AU+AU AND CU+CU COLLISIONS

    Science.gov (United States)

    Back, B. B.; Alver, B.; Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Busza, W.; Carroll, A.; Chai, Z.; Chetluru, V.; Decowski, M. P.; Garcia, E.; Gburek, T.; George, N.; Gulbrandsen, K.; Halliwell, C.; Hamblen, J.; Harnarine, I.; Hauer, M.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Holynski, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Khan, N.; Kulinich, P.; Kuo, C. M.; Li, W.; Lin, W. T.; Loizides, C.; Manly, S.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Reed, C.; Richardson, E.; Roland, C.; Roland, G.; Sagerer, J.; Seals, H.; Sedykh, I.; Smith, C. E.; Stankiewicz, M. A.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Szostak, A.; Tonjes, M. B.; Trzupek, A.; Vale, C.; Vannieuwenhuizen, G. J.; Vaurynovich, S. S.; Verdier, R.; Veres, G. I.; Walters, P.; Wenger, E.; Willhelm, D.; Wolfs, F. L. H.; Wosiek, B.; Wozniak, K.; Wyngaardt, S.; Wyslouch, B.

    The PHOBOS collaboration has carried out a systematic study of charged particle multiplicities in Cu+Cu and Au+Au collisions at the Relativistic Heavy-Ion Collider (RHIC) at Brookhaven National Laboratory. A unique feature of the PHOBOS detector is its ability to measure charged particles over a very wide angular range from 0.5° to 179.5° corresponding to |η| <5.4. The general features of the charged particle multiplicity distributions as a function of pseudo-rapidity, collision energy and centrality, as well as system size, are discussed.

  13. Fermi surfaces properties of AuAl2, AuGa2, and AuIn2 with the CaF2-type cubic structure

    Science.gov (United States)

    Nishimura, K.; Kakihana, M.; Suzuki, F.; Yara, T.; Hedo, M.; Nakama, T.; Ōnuki, Y.; Harima, H.

    2018-05-01

    We grew high-quality single crystals of AuAl2, AuGa2, and AuIn2 with the fluorite (CaF2)-type cubic structure and determined the Fermi surface properties by the de Haas-van Alphen (dHvA) experiments using full-potential LAPW bad calculations. The Fermi surface and optical properties for three compounds were once studied from an interest of colors because AuAl2 has a striking bright reddish-purple color, whereas AuGa2 and AuIn2 are, respectively, neutral and bluish. The detected dHvA frequencies in the present study are found to be in a wide range of (0.1-13)×107 Oe. The main dHvA branches for three compounds are in excellent agreement with the theoretical ones, but some dHvA branches with small dHvA frequencies are slightly deviated from the theoretical ones, especially in AuGa2 and AuIn2.

  14. Azimuthal di-hadron correlations in d plus Au and Au plus Au collisions at root s(NN)=200 GeV measured at the STAR detector

    Czech Academy of Sciences Publication Activity Database

    Aggarwal, M. M.; Ahammed, Z.; Alakhverdyants, A. V.; Alekseev, I.; Alford, J.; Anderson, B.D.; Arkhipkin, D.; Averichev, G. S.; Balewski, J.; Barnby, L. S.; Baumgart, S.; Beavis, D.R.; Bellwied, R.; Betancourt, M.J.; Betts, R. R.; Bhasin, A.; Bhati, A.K.; Bichsel, H.; Bielčík, Jaroslav; Bielčíková, Jana; Biritz, B.; Bland, L.C.; Bonner, B.E.; Bouchet, J.; Braidot, E.; Brandin, A.V.; Bridgeman, A.; Bruna, E.; Bueltmann, S.; Bunzarov, I.; Burton, T. P.; Cai, X.Z.; Caines, H.; Sanchez, M.C.D.; Catu, O.; Cebra, D.; Cendejas, R.; Cervantes, M.C.; Chajecki, Z.; Chaloupka, Petr; Chattopadhyay, S.; Chen, H.F.; Chen, J.H.; Chen, J.Y.; Cheng, J.; Cherney, M.; Chikanian, A.; Choi, K.E.; Christie, W.; Chung, P.; Clarke, R.F.; Codrington, M.J.M.; Corliss, R.; Cramer, J. G.; Crawford, H. J.; Das, D.; Dash, S.; Leyva, A.D.; De Silva, L.C.; Debbe, R.R.; Dedovich, T. G.; Derevschikov, A.A.; de Souza, R.D.; Didenko, L.; Djawotho, P.; Dogra, S.M.; Dong, X.; Drachenberg, J.L.; Draper, J. E.; Dunlop, J.C.; Mazumdar, M.R.D.; Efimov, L.G.; Elhalhuli, E.; Elnimr, M.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Eun, L.; Evdokimov, O.; Fachini, P.; Fatemi, R.; Fedorisin, J.; Fersch, R.G.; Filip, P.; Finch, E.; Fine, V.; Fisyak, Y.; Gagliardi, C. A.; Gangaharan, D.R.; Ganti, M. S.; Garcia-Solis, E.J.; Geromitsos, A.; Geurts, F.; Ghazikhanian, V.; Ghosh, P.; Gorbunov, Y.N.; Gordon, A.; Grebenyuk, O.; Grosnick, D.; Guertin, S.M.; Gupta, A.; Gupta, N.; Guryn, W.; Haag, B.; Hamed, A.; Han, L.X.; Harris, J.W.; Hays-Wehle, J.P.; Heinz, M.; Heppelmann, S.; Hirsch, A.; Hjort, E.; Hoffmann, A.M.; Hoffmann, G.W.; Hofman, D.J.; Horner, M.J.; Huang, B.; Huang, H.Z.; Humanic, T.J.; Huo, L.; Igo, G.; Jacobs, P.; Jacobs, W.W.; Jena, C.; Jin, F.; Jones, C.L.; Jones, P.G.; Joseph, J.; Judd, E.G.; Kabana, S.; Kajimoto, K.; Kang, K.; Kapitán, Jan; Kauder, K.; Keane, D.; Kechechyan, A.; Kettler, D.; Kikola, D.P.; Kiryluk, J.; Kisiel, A.; Klein, S.R.; Knospe, A.G.; Kocoloski, A.; Koetke, D.D.; Kollegger, T.; Konzer, J.; Koralt, I.; Koroleva, L.; Korsch, W.; Kotchenda, L.; Kushpil, Vasilij; Kravtsov, P.; Krueger, K.; Krus, M.; Kumar, L.; Kurnadi, P.; Lamont, M.A.C.; Landgraf, J.M.; LaPointe, S. (ed.); Lauret, J.; Lebedev, A.; Lednický, Richard; Lee, Ch.; Lee, J.H.; Leight, W.; LeVine, M.J.; Li, C.; Li, L.; Li, N.; Li, W.; Li, X.; Li, Y.; Li, Z.M.; Lin, G.; Lindenbaum, S.J.; Lisa, M.A.; Liu, F.; Liu, H.; Liu, J.; Ljubicic, T.; Llope, W.J.; Longacre, R.S.; Love, W.A.; Lu, Y.; Luo, X.; Ma, G.L.; Ma, Y.G.; Mahapatra, D. P.; Majka, R.; Mall, O.I.; Mangotra, L.K.; Manweiler, R.; Margetis, S.; Markert, C.; Masui, H.; Matis, H.S.; Matulenko, Yu.A.; McDonald, D.; McShane, T.S.; Meschanin, A.; Milner, R.; Minaev, N.G.; Mioduszewski, S.; Mischke, A.; Mitrovski, M.K.; Mohanty, B.; Mondal, M.M.; Morozov, B.; Morozov, D.A.; Munhoz, M. G.; Nandi, B.K.; Nattrass, C.; Nayak, T. K.; Nelson, J.M.; Netrakanti, P.K.; Ng, M.J.; Nogach, L.V.; Nurushev, S.B.; Odyniec, G.; Ogawa, A.; Okorokov, V.; Oldag, E.W.; Olson, D.; Pachr, M.; Page, B.S.; Pal, S.K.; Pandit, Y.; Panebratsev, Yu.; Pawlak, T.; Peitzmann, T.; Perevoztchikov, V.; Perkins, C.; Peryt, W.; Phatak, S.C.; Pile, P.; Planinic, M.; Ploskon, M.A.; Pluta, J.; Plyku, D.; Poljak, N.; Poskanzer, A.M.; Potukuchi, B.V.K.S.; Powell, C.B.; Prindle, D.; Pruneau, C.; Pruthi, N.K.; Pujahari, P.R.; Putschke, J.; Raniwala, R.; Raniwala, S.; Ray, R.L.; Redwine, R.; Reed, R.; Ritter, H.G.; Roberts, J.B.; Rogachevskiy, O.V.; Romero, J.L.; Rose, A.; Roy, C.; Ruan, L.; Sahoo, R.; Sakai, S.; Sakrejda, I.; Sakuma, T.; Salur, S.; Sandweiss, J.; Sangaline, E.; Schambach, J.; Scharenberg, R.P.; Schmitz, N.; Schuster, T.R.; Seele, J.; Seger, J.; Selyuzhenkov, I.; Seyboth, P.; Shahaliev, E.; Shao, M.; Sharma, M.; Shi, S.S.; Sichtermann, E.P.; Simon, F.; Singaraju, R.N.; Skoby, M.J.; Smirnov, N.; Sorensen, P.; Sowinski, J.; Spinka, H.M.; Srivastava, B.; Stanislaus, T.D.S.; Staszak, D.; Stevens, J.R.; Stock, R.; Strikhanov, M.; Stringfellow, B.; Suaide, A. A. P.; Suarez, M.C.; Subba, N.L.; Šumbera, Michal; Sun, X.M.; Sun, Y.; Sun, Z.; Surrow, B.; Svirida, D.N.; Symons, T.J.M.; de Toledo, A. S.; Takahashi, J.; Tang, A.H.; Tang, Z.; Tarini, L.H.; Tarnowsky, T.; Thein, D.; Thomas, J.H.; Tian, J.; Timmins, A.R.; Timoshenko, S.; Tlustý, David; Tokarev, M. V.; Trainor, T.A.; Tram, V.N.; Trentalange, S.; Tribble, R. E.; Tsai, O.D.; Ulery, J.; Ullrich, T.; Underwood, D.G.; Van Buren, G.; van Leeuwen, M.; van Nieuwenhuizen, G.; Vanfossen, J.A.; Varma, R.; Vasconcelos, G.M.S.; Vasiliev, A. N.; Videbaek, F.; Viyogi, Y. P.; Vokal, S.; Voloshin, S.A.; Wada, M.; Walker, M.; Wang, F.; Wang, G.; Wang, H.; Wang, J.S.; Wang, Q.; Wang, X.L.; Wang, Y.; Webb, G.; Westfall, G.D.; Whitten, C.; Wieman, H.; Wissink, S.W.; Witt, R.; Wu, Y.F.; Xie, W.; Xu, N.; Xu, Q.H.; Xu, W.; Xu, Y.; Xu, Z.; Xue, L.; Yang, Y.; Yepes, P.; Yip, K.; Yoo, I.K.; Yue, Q.; Zawisza, M.; Zbroszczyk, H.; Zhan, W.; Zhang, J.B.; Zhang, S.; Zhang, W.M.; Zhang, X.P.; Zhang, Y.; Zhang, Z.P.; Zhao, J.; Zhong, C.; Zhou, J.; Zhou, W.; Zhu, X.; Zhu, Y.H.; Zoulkarneev, R.; Zoulkarneeva, Y.

    2010-01-01

    Roč. 82, č. 2 (2010), 024912/1-024912/14 ISSN 0556-2813 Institutional research plan: CEZ:AV0Z10480505; CEZ:AV0Z10100502 Keywords : AU+AU COLLISIONS * RADIATION * PLASMA Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 3.416, year: 2010

  15. Balance functions from Au+Au, d+Au, and p+p collisions at root s(NN)=200 GeV

    Czech Academy of Sciences Publication Activity Database

    Aggarwal, M. M.; Ahammed, Z.; Alakhverdyants, A. V.; Alekseev, I.; Alford, J.; Anderson, B.D.; Arkhipkin, D.; Averichev, G. S.; Balewski, J.; Barnby, L. S.; Baumgart, S.; Beavis, D.R.; Bellwied, R.; Betancourt, M.J.; Betts, R. R.; Bhasin, A.; Bhati, A.K.; Bichsel, H.; Bielčík, Jaroslav; Bielčíková, Jana; Biritz, B.; Bland, L.C.; Bonner, B.E.; Bouchet, J.; Braidot, E.; Brandin, A.V.; Bridgeman, A.; Bruna, E.; Bueltmann, S.; Bunzarov, I.; Burton, T. P.; Cai, X.Z.; Caines, H.; Sanchez, M.C.D.; Catu, O.; Cebra, D.; Cendejas, R.; Cervantes, M.C.; Chajecki, Z.; Chaloupka, Petr; Chattopadhyay, S.; Chen, H.F.; Chen, J.H.; Chen, J.Y.; Cheng, J.; Cherney, M.; Chikanian, A.; Choi, K.E.; Christie, W.; Chung, P.; Clarke, R.F.; Codrington, M.J.M.; Corliss, R.; Cramer, J. G.; Crawford, H. J.; Das, D.; Dash, S.; Leyva, A.D.; De Silva, L.C.; Debbe, R.R.; Dedovich, T. G.; Derevschikov, A.A.; de Souza, R.D.; Didenko, L.; Djawotho, P.; Dogra, S.M.; Dong, X.; Drachenberg, J.L.; Draper, J. E.; Dunlop, J.C.; Mazumdar, M.R.D.; Efimov, L.G.; Elhalhuli, E.; Elnimr, M.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Eun, L.; Evdokimov, O.; Fachini, P.; Fatemi, R.; Fedorisin, J.; Fersch, R.G.; Filip, P.; Finch, E.; Fine, V.; Fisyak, Y.; Gagliardi, C. A.; Gangaharan, D.R.; Ganti, M. S.; Garcia-Solis, E.J.; Geromitsos, A.; Geurts, F.; Ghazikhanian, V.; Ghosh, P.; Gorbunov, Y.N.; Gordon, A.; Grebenyuk, O.; Grosnick, D.; Guertin, S.M.; Gupta, A.; Gupta, N.; Guryn, W.; Haag, B.; Hamed, A.; Han, L.X.; Harris, J.W.; Hays-Wehle, J.P.; Heinz, M.; Heppelmann, S.; Hirsch, A.; Hjort, E.; Hoffmann, A.M.; Hoffmann, G.W.; Hofman, D.J.; Horner, M.J.; Huang, B.; Huang, H.Z.; Humanic, T.J.; Huo, L.; Igo, G.; Jacobs, P.; Jacobs, W.W.; Jena, C.; Jin, F.; Jones, C.L.; Jones, P.G.; Joseph, J.; Judd, E.G.; Kabana, S.; Kajimoto, K.; Kang, K.; Kapitán, Jan; Kauder, K.; Keane, D.; Kechechyan, A.; Kettler, D.; Kikola, D.P.; Kiryluk, J.; Kisiel, A.; Klein, S.R.; Knospe, A.G.; Kocoloski, A.; Koetke, D.D.; Kollegger, T.; Konzer, J.; Koralt, I.; Koroleva, L.; Korsch, W.; Kotchenda, L.; Kushpil, Vasilij; Kravtsov, P.; Krueger, K.; Krus, M.; Kumar, L.; Kurnadi, P.; Lamont, M.A.C.; Landgraf, J.M.; LaPointe, S. (ed.); Lauret, J.; Lebedev, A.; Lednický, Richard; Lee, Ch.; Lee, J.H.; Leight, W.; LeVine, M.J.; Li, C.; Li, L.; Li, N.; Li, W.; Li, X.; Li, Y.; Li, Z.M.; Lin, G.; Lindenbaum, S.J.; Lisa, M.A.; Liu, F.; Liu, H.; Liu, J.; Ljubicic, T.; Llope, W.J.; Longacre, R.S.; Love, W.A.; Lu, Y.; Luo, X.; Ma, G.L.; Ma, Y.G.; Mahapatra, D. P.; Majka, R.; Mall, O.I.; Mangotra, L.K.; Manweiler, R.; Margetis, S.; Markert, C.; Masui, H.; Matis, H.S.; Matulenko, Yu.A.; McDonald, D.; McShane, T.S.; Meschanin, A.; Milner, R.; Minaev, N.G.; Mioduszewski, S.; Mischke, A.; Mitrovski, M.K.; Mohanty, B.; Mondal, M.M.; Morozov, B.; Morozov, D.A.; Munhoz, M. G.; Nandi, B.K.; Nattrass, C.; Nayak, T. K.; Nelson, J.M.; Netrakanti, P.K.; Ng, M.J.; Nogach, L.V.; Nurushev, S.B.; Odyniec, G.; Ogawa, A.; Okorokov, V.; Oldag, E.W.; Olson, D.; Pachr, M.; Page, B.S.; Pal, S.K.; Pandit, Y.; Panebratsev, Yu.; Pawlak, T.; Peitzmann, T.; Perevoztchikov, V.; Perkins, C.; Peryt, W.; Phatak, S.C.; Pile, P.; Planinic, M.; Ploskon, M.A.; Pluta, J.; Plyku, D.; Poljak, N.; Poskanzer, A.M.; Potukuchi, B.V.K.S.; Powell, C.B.; Prindle, D.; Pruneau, C.; Pruthi, N.K.; Pujahari, P.R.; Putschke, J.; Raniwala, R.; Raniwala, S.; Ray, R.L.; Redwine, R.; Reed, R.; Ritter, H.G.; Roberts, J.B.; Rogachevskiy, O.V.; Romero, J.L.; Rose, A.; Roy, C.; Ruan, L.; Sahoo, R.; Sakai, S.; Sakrejda, I.; Sakuma, T.; Salur, S.; Sandweiss, J.; Sangaline, E.; Schambach, J.; Scharenberg, R.P.; Schmitz, N.; Schuster, T.R.; Seele, J.; Seger, J.; Selyuzhenkov, I.; Seyboth, P.; Shahaliev, E.; Shao, M.; Sharma, M.; Shi, S.S.; Sichtermann, E.P.; Simon, F.; Singaraju, R.N.; Skoby, M.J.; Smirnov, N.; Sorensen, P.; Sowinski, J.; Spinka, H.M.; Srivastava, B.; Stanislaus, T.D.S.; Staszak, D.; Stevens, J.R.; Stock, R.; Strikhanov, M.; Stringfellow, B.; Suaide, A. 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P.; Vokal, S.; Voloshin, S.A.; Wada, M.; Walker, M.; Wang, F.; Wang, G.; Wang, H.; Wang, J.S.; Wang, Q.; Wang, X.L.; Wang, Y.; Webb, G.; Westfall, G.D.; Whitten, C.; Wieman, H.; Wissink, S.W.; Witt, R.; Wu, Y.F.; Xie, W.; Xu, N.; Xu, Q.H.; Xu, W.; Xu, Y.; Xu, Z.; Xue, L.; Yang, Y.; Yepes, P.; Yip, K.; Yoo, I.K.; Yue, Q.; Zawisza, M.; Zbroszczyk, H.; Zhan, W.; Zhang, J.B.; Zhang, S.; Zhang, W.M.; Zhang, X.P.; Zhang, Y.; Zhang, Z.P.; Zhao, J.; Zhong, C.; Zhou, J.; Zhou, W.; Zhu, X.; Zhu, Y.H.; Zoulkarneev, R.; Zoulkarneeva, Y.

    2010-01-01

    Roč. 82, č. 2 (2010), 024905/1-024905/16 ISSN 0556-2813 Institutional research plan: CEZ:AV0Z10480505; CEZ:AV0Z10100502 Keywords : HEAVY-ION COLLISIONS * AU-AU COLLISIONS * TIME PROJECTION CHAMBER Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 3.416, year: 2010

  16. Electron diffraction on amorphous and crystalline AuAl2 , AuGa2 and AuIn2 thin films

    International Nuclear Information System (INIS)

    Bohorquez, A.

    1991-01-01

    Experimental (in situ) measurements of electron diffraction and resistivity of amorphous and crystalline AuAl 2 , AuGa 2 and AuIn 2 thin films were performed. Thin films were produced by quench condensation. Interference and atomic distribution functions were analyzed assuming the same short range order for the three systems in the amorphous phase. The experimental results do not agree with this assumption, giving evidence that the short range order is not the same for the three amorphous systems. Further discussion of interference and atomic distribution functions shows a more evident tendency in amorphous AuIn 2 where short order of AuIn 2 and In can be inferred. (Author)

  17. Site operations

    International Nuclear Information System (INIS)

    House, W.B.; Ebenhack, D.G.

    1989-01-01

    This chapter is a discussion of the management and operations practices used at the Barnwell Waste Management Facility in Barnwell, SC. The following topics are discussed: (1) Waste receiving and inspection, including manifest and certificates of compliance, radiological surveys, disposition of nonconforming items, and decontamination and disposition of secondary waste streams; (2) Waste disposal, including Title 10 CFR 61 requirements, disposal area evaluations, shipment offloading, container emplacement, and radiation protection; (3) Trench closure, including trench backfilling, trench capping, and permanent markers; (4) Site maintenance and stabilization, including trench maintenance, surface water management, and site closure activities; (5) Site monitoring programs, including operational monitoring, and environmental monitoring program; (6) Personnel training and qualifications, including basic training program, safety training program, special skills training, and physical qualifications; (7) Records management, including waste records, personnel training records, personnel dosimetry records, site monitoring records, trench qualification and construction records, and site drawings and stabilization records; (8) Site security; (9) Emergency response plans; and (10) Quality assurance

  18. MPI support in the DIRAC Pilot Job Workload Management System

    International Nuclear Information System (INIS)

    Tsaregorodtsev, A; Hamar, V

    2012-01-01

    Parallel job execution in the grid environment using MPI technology presents a number of challenges for the sites providing this support. Multiple flavors of the MPI libraries, shared working directories required by certain applications, special settings for the batch systems make the MPI support difficult for the site managers. On the other hand the workload management systems with Pilot Jobs became ubiquitous although the support for the MPI applications in the Pilot frameworks was not available. This support was recently added in the DIRAC Project in the context of the GISELA Latin American Grid Initiative. Special services for dynamic allocation of virtual computer pools on the grid sites were developed in order to deploy MPI rings corresponding to the requirements of the jobs in the central task queue of the DIRAC Workload Management System. Pilot Jobs using user space file system techniques install the required MPI software automatically. The same technique is used to emulate shared working directories for the parallel MPI processes. This makes it possible to execute MPI jobs even on the sites not supporting them officially. Reusing so constructed MPI rings for execution of a series of parallel jobs increases dramatically their efficiency and turnaround. In this contribution we describe the design and implementation of the DIRAC MPI Service as well as its support for various types of MPI libraries. Advantages of coupling the MPI support with the Pilot frameworks are outlined and examples of usage with real applications are presented.

  19. Transferring manual ultrasonic inspection procedures - results of a pilot study

    International Nuclear Information System (INIS)

    Anderson, M.; Taylor, T.; Kadenko, I.

    2002-01-01

    Results of a manual ultrasonic pilot study for NDE specialists at RBMK nuclear reactor sites are presented. Probabilities of detection and false calls, using two different grading criteria, are estimated. Analyses of performance parameters lead to conclusions regarding attributes for improved test discrimination capabilities. (orig.)

  20. Conductive Au nanowires regulated by silk fibroin nanofibers

    Science.gov (United States)

    Dong, Bo-Ju; Lu, Qiang

    2014-03-01

    Conductive Au-biopolymer composites have promising applications in tissue engineering such as nerve tissue regeneration. In this study, silk fibroin nanofibers were formed in aqueous solution by regulating silk self-assembly process and then used as template for Au nanowire fabrication. We performed the synthesis of Au seeds by repeating the seeding cycles for several times in order to increase the density of Au seeds on the nanofibers. After electroless plating, densely decorated Au seeds grew into irregularly shaped particles following silk nanofiber to fill the gaps between particles and finally form uniform continuous nanowires. The conductive property of the Au-silk fibroin nanowires was studied with current-voltage ( I-V) measurement. A typical ohmic behavior was observed, which highlighted their potential applications in nerve tissue regeneration.