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Sample records for au gaz naturel

  1. Le Gaz Naturel Véhicule Natural Gas for Vehicles

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    De Chauveron S.

    2006-11-01

    Full Text Available Cet article présente le GNV (Gaz Naturel Véhicule. Le GNV a en effet de sérieux atouts, à la fois comme carburant de substitution et comme carburant propre. Ces atouts sont aussi bien économiques que techniques. La première partie est consacrée aux enjeux du développement du GNV. Les premiers pays utilisateurs ont été ceux qui disposent sur leur sol de ressources de gaz naturel. Aujourd'hui, alors que de nombreux pays doivent faire face à l'inquiétude croissante relative à l'augmentation de la pollution urbaine, le gaz naturel apparaît également comme un carburant propre, permettant de réduire rapidement les émissions de polluants des véhicules. Dans une deuxième partie, nous donnons une description technique sommaire des stations GNV et des véhicules GNV. Il s'agit de familiariser le lecteur avec les quelques spécificités techniques du GNV, par rapport à l'essence et au gazole. On constatera d'ailleurs que les technologies GNV sont très proches des technologies classiques. Enfin, la dernière partie est consacrée aux actions en cours, qui permettront le développement du GNV en France et en Europe : programmes de recherche, réduction des coûts de la filière, actions réglementaires, communication, etc. This article presents compressed natural gas for vehicles (CNG, which can provide considerable advantages both as an alternative fuel and as a clean fuel. These assets are not only economic but also technical. The first part deals with what is at stake in developing natural gas as a motor fuel. The first countries to use CNG were those with natural gas resources in their subsoil. Today, with a large number of countries having to cope with growing concern about increasing urban pollution, natural gas is also seen as a clean fuel that can help cut vehicle pollutant emissions dramatically. In the second part a brief technical description is given of CNG stations and vehicles, with the aim of acquainting the reader with

  2. Conversion chimique du gaz naturel Chemical Conversion of Natural Gas

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    Chaumette P.

    2006-11-01

    Full Text Available Dans cet article sont passés en revue les travaux de recherche et développement et les procédés existants dans le domaine de la conversion chimique du gaz naturel. Les deux voies possibles, conversion directe du méthane et conversion indirecte, via le gaz de synthèse, sont présentées. Tant la préparation d'hydrocarbures utilisables comme carburants, que celle des composés de bases pour la pétrochimie ou la chimie sont évoquées. L'accent est mis sur l'étape clé du développement de chaque procédé qui, selon le produit visé, consiste en la mise au point d'un nouveau système catalytique, en un changement de la technologie du réacteur, ou en la mise au point d'une section fractionnement moins complexe. This article reviews the research and development work and the existing processes in the area of chemical conversion of natural gas. The two possible methods, direct conversion of methane and indirect conversion via synthesis gas, are discussed. The preparation of hydrocarbons that can be used as fuels and the production of building blocks for the petrochemical and chemical industries are both dealt with. The accent is placed on the key step in developing each process. Depending on the target product, this key step consists in working out a new catalytic system, changing reactor technology or engineering a less complex fractionation section.

  3. Natural gas drying of the solid of slurry in a fluidized bed; Sechage au gaz naturel sur lit fluidise a jet de la partie solide du lisier

    Energy Technology Data Exchange (ETDEWEB)

    Duphily, C. [Centre des technologies du gaz naturel, Boucherville, PQ (Canada)

    1999-11-01

    On the invitation and the initiative of Gas Metropolitan, le centre des technologies du gaz naturel (CTGN) received a mandate for developing a technology that could handle a problem concerning a surplus of swine manure. This problem expressed itself in four main forms: 1) a surplus of manure on the farm-site, 2) a regional surplus of the same, 3) a release of odours, and 4) environmental concerns on the surrounding countryside. In collaboration with the Polytechniqie du Montreal, a management tool, PROGEST, was developed for these wastes. This process permits the drying of the swine wastes using natural gas on a jet fluidized bed followed by a heat treatment of the drying fumes in a combustion chamber. The deposits consisting of nearly 15% solids are sent along to a drying chamber where they dried and sterilized at 120 degrees C. The dried deposit recovered in the form of a powder in an assembly of a cyclone-deduster at the exit of the dryer can be granulated as needed and sold as a co-product. For example, it can be used as a fertilizer ingredient or as an ingredient in animal feed.

  4. Le stockage de gaz naturel Natural Gas Storage

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    Choquel A.

    2006-11-01

    Full Text Available Le stockage souterrain du gaz naturel est une des principales techniques qui ont contribué à donner un rôle majeur à cette source d'énergie dans le bilan énergétique mondial. Le rôle des stockages souterrains est prépondérant pour assurer la modulation saisonnière et quotidienne des consommations. Ils contribuent également, avec la clientèle effaçable, à la sécurité d'approvisionnement par une qualité spécifique grâce à la rapidité et à la souplesse de leur mise en oeuvre. Cet article présente les différentes fonctionnalités du stockage souterrain de gaz naturel en s'appuyant sur l'exemple de la France, puis, les différentes techniques mises en oeuvre à l'heure actuelle. Une présentation d'ensemble de la situation des stockages souterrains dans le monde rappelle les ordres de grandeur importants et cite quelques tendances d'évolution. La conclusion de l'article fait le point sur les progrès techniques récents réalisés dans le domaine du stockage massif de gaz naturel en souterrain. Underground storage of natural gas is one of the main techniques that have helped make gas one of the leading energy sources in the world's energy balance. Underground storage facilities are instrumental in ensuring seasonal and daily adjustments in consumption. With interruptible consumers, they also contribute to supply security with a quality asset because they can be mobilized rapidly and flexibly. This article presents the varied functional framework for underground natural gas storage based of the example of France and then deals with the different techniques utilized at this point in time. The situation of the world's underground storage facilities is given an overall presentation, with a reminder of the important orders of magnitude and mention of a number of evolutionary trends. The recent technical achievements in massive natural gas storage underground are reviewed in the conclusion of the article.

  5. Natural Gas Storage Seismic Monitoring Suivi sismique des stockages de gaz naturel

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    Mari J.L.

    2011-02-01

    té conçues et utilisées de façon continue pendant plusieurs années pour suivre le cycle remplissage/extraction du stockage. Les dispositifs permanents ont permis d’améliorer la précision des mesures de temps d’arrivée jusqu’au dixième de milliseconde. L’arrivée de gaz dans un aquifère se traduit par une rapide variation de vitesse, qui a un impact à la fois sur les temps d’arrivée des réflexions sous les réservoirs et sur les amplitudes aux limites du réservoir. Les mouvements ultérieurs du contact gaz/eau avec le cycle de remplissage/soutirage sont plus difficiles à suivre et nécessitent une excellente précision des mesures de temps d’arrivée des réflexions. L’inversion de ces mesures pour l’estimation des saturations en gaz et en eau est délicate. Cette inversion a été tentée, avec un certain succès, dans le cas de Céré-la-Ronde. Du fait de la densité du dioxyde de carbone, au-delà d’une profondeur de 800 mètres environ, cette inversion risque d’être encore plus délicate pour les stockages de CO2 que pour les stockages de gaz naturel.

  6. Les perspectives du commerce international de gaz naturel d'ici 2000 The World Natural Gas Trade Outlook to 2000

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    Valais M.

    2006-11-01

    Full Text Available L'abondance des ressources gazières mondiales et l'excellence des qualités du gaz naturel, comme combustible et matière première pétrochimique, devraient lui permettre d'accroître sa pénétration sur les marchés énergétiques internationaux. Toutefois, la répartition géographique de ses réserves prouvées coïncide de moins en moins avec celle de sa consommation. En conséquence, la croissance du commerce international de gaz naturel apparaît comme une nécessité de plus en plus vitale du développement mondial de ses marchés. A partir d'une étude prospective menée au sein de l'Association Technique de l'industrie du Gaz en France (ATG, le présent mémoire se propose d'analyser les perspectives des échanges gaziers internationaux d'ici l'horizon 2000. The abundance of the world reserves of natural gas and the excellence of its qualities as a fuel and a petrochemical feedstock should enable natural gas to increase its penetration on international energy markets. However the geographic distribution of its proved reserves coincides less and less with the distribution of its consumption. Therefore, the increase in international gas trade appears more and more to be of vital necessity for the world development of its markets. On the basis of a study carried out within the Association Technique de l'industrie du Gaz en France (ATG, the present paper will attempt to analyse the outlook for international gas trade between now and the year 2000.

  7. Détermination de la solubilité du tétrahydrothiophène (THT) liquide dans les principaux constituants du gaz naturel (CH4, CO2 et N2) au moyen d'un dispositif dynamique avec analyse chromatographique en ligne de la phase vapeur

    Science.gov (United States)

    Ghanem, G.; Tagand, G.; Loiseleur, H.; Ingrain, D.; Jose, J.

    1998-05-01

    Some odorous products as tetrahydrothiophene (THT) whose odour is perceived at low concentration, are injected in natural gas in order to odorize it. This artificial odorization allows to detect immediately any gas leak in atmosphere. The authors have measured the equilibrium compositions of gaseous phases for binaires THT-CH4, THT-N2 and THT-CO2 in the transport and distribution conditions of natural gas [ {1 gaz naturel en vue de son odorisation. Cette odorisation artificielle rend toute fuite éventuelle de gaz dans l'atmosphère immédiatement détectable. Les auteurs ont mesuré les compositions à l'équilibre des phases gaseuses des binaires THT-CH4, THT-N02 et THT-CO2 dans les conditions de transport et de distribution du gaz [ {1 < P (bar) < 60} and {-30 < t(^circ C) < 50}] . Dans ce but, un dispositif expérimental original basé sur un principe de saturation dynamique avec analyse chromatographique en ligne de la phase vapeur a été réalisé et mis au point. Des grandeurs thermodynamiques supplémentaires sont nécessaires pour atteindre les compositions molaires de la phase vapeur. Les auteurs ont mesuré les pressions de vapeur du THT et estimé les seconds coefficients du viriel. Ces estimations font intervenir les grandeurs critiques et facteurs acentriques qui ont été calculés par diverses corrélations.

  8. On Mist Formation in Natural Gas Sur la formation de buée dans le gaz naturel

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    Muitjens M. J. E. H.

    2006-11-01

    Full Text Available Mist formation that occurs during production, handling, and transport of natural gas is shown to be the result of non equilibrium thermodynamic processes. A simple analysis is presented of these nucleation and droplet growth phenomena in natural gas, and an estimate is given of the rate at which droplets are formed for typical process conditions. A model of droplet growth due to condensation is presented. The nucleation and condensation behaviour of two samples of a natural gas is investigated in a Wilson expansion cloud chamber for the initial pressure range of 5 to 50 bar and initial temperatures of 294-297 K (21-24°C. For a cooling rate of about 1 K/ms, a typical undercooling at the onset of condensation is found of 32 ý 3K and 60 ý 5K respectively for the two samples, which emphasizes the importance of non-equilibrium effects. La formation de buée au cours de la production, du maniement et du transport de gaz naturel est le résultat d'un déséquilibre thermodynamique. Une analyse simple de la nucléation et de la croissance des gouttelettes dans le gaz naturel est présentée. Une estimation du taux de formation dans de tels processus ainsi qu'un modèle de croissance des gouttelettes par condensation sont alors établis. La nucléation et la condensation de deux échantillons de gaz naturel ont été examinées dans une chambre d'expansion de Wilson dont les gammes de pression et de température initiales sont respectivement de 5 à 10 bar et de 294 à 297 K (21-24°C. Pour un taux de refroidissement de 1 K/ms, les valeurs de sous-refroidissement trouvées au moment de l'initialisation de la condensation sont respectivement pour les deux échantillons 32 ý 3K et 60 ý 5K, ce qui souligne l'importance des effets de déséquilibre.

  9. Panorama des marchés du gaz naturel en 2010

    OpenAIRE

    Méritet, Sophie

    2010-01-01

    Doté de précieux atouts environnementaux par rapport aux autres énergies fossiles et de réserves importantes, le gaz naturel a vu sa part dans le bilan énergétique mondial augmenter régulièrement depuis les années 70. Dans le passé récent, les marchés du gaz étaient assez prévisibles, ils sont désormais incertains et connaissent de profonds changements. Pris individuellement, chaque marché régional s’était développé progressivement à partir des gisements les plus proches et de réseaux de gazo...

  10. Natural gas for vehicles; Le gaz naturel pour vehicules

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-08-04

    % of alternate vehicles by using GNV, GPL or electricity. The present (1 February 1998) GNV stock amounts about 1800 light vehicles adapted to bi-carburation and some ten urban buses (GNV fuel engines) while around 80 buses are ordered firmly.. Public authorities and supporters of the alternative aims at putting into operation a fleet of 2,500 light service vehicles and 300 urban buses by the end of 1999. There is a protocol on GNV option development joining Gaz de France, car manufacturers and public authorities.

  11. Les perspectives du gaz naturel dans le Monde World Natural Gas Prospects

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    Valais M.

    2006-11-01

    Full Text Available Dans un monde en quête de diversification énergétique, le gaz naturel apparaît comme une source d'énergie particulièrement attrayante. Par son abondance, sa facilité de substitution aux produits pétroliers dans une gamme très large d'usages, il pourrait assurément jouer un rôle beaucoup plus important dans la couverture des besoins énergétiques mondiaux. Toutefois, de nombreux obstacles semblent devoir ralentir sa progression. Cet article dégage les grands paramètres techniques et économiques qui devraient conditionner le développement de l'industrie du gaz dans le monde et présente des perspectives d'évolution de sa production et de son commerce international d'ici à la fin du siècle. For a world in search of energy diversification, natural gas is a particularly attractive source. Its abundance and its facility for being substituted for petroleum products over a wide range of uses should certainly mean that it will play a much more important rote in filling world energy needs. Nonetheless, many obstacles are hindering its progress. This article outlines the leading technical and economic parameters which should influence the development of the world gas industry, and the prospects for its production and international trade evolution between now and the end of the century.

  12. Economical and geopolitical aspects bond to the foreseen development of the natural gas in an open market; Aspects economiques et geopolitiques lies au developpement prevu du gaz naturel dans un marche ouvert

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-12-15

    For the first time in 2000, the part of natural gas is equal to those of coal in the world energy accounting. The economy and the geo-policy of this developing energy is analyzed, showing an economy dominated by the transport costs, the specificity of the european sector and the opening market since 1980. The european market opening incertitudes and opportunities are detailed. In conclusion the Gaz De France role in the european energy pole and the new regulations are discussed. (A.L.B.)

  13. Dosage du mercure dans le gaz naturel par absorption atomique sans flammes Mercury Titration in Natural Gas by Flameless Atomic Absorption

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    La Villa F.

    2006-11-01

    Full Text Available Cet article présente la méthode mise au point par l'Institut Français du Pétrole pour déterminer par absorption atomique sans flamme, les traces de mercure métallique contenu dans un gaz naturel. La méthode d'analyse nécessite une extraction du mercure soit sous forme d'ion mercurique en faisant passer le gaz dans une solution oxydante, soit sous forme d'amalgame avec de l'or ou de l'argent. Le premier mode opératoire s'applique aux échantillons dont la concentration en mercure est supérieure à I ttg/Nm3, le second pour des concentrations inférieures à 5 pg/Nm3. Les seuils de détection sont respectivement 10 ng (en solution et 0,3 ng (en amalgame. La répétabilité pour 100 ng de mercure (en amalgame est de ± 7% pour une probabilité de.95 %. En conclusion, dans un échantillon de gaz naturel, compte tenu du volume des prélèvements effectués, il est possible de détecter des concentrations de l'ordre du nanogramme de mercure par mètre cube de gaz. This article describes the method developed by IFP using flameless atomic absorption to determine metallic mercury traces in a natural gas. The analyst method requires a mercury extraction either in the form of mercuric ions by making the gas pass through an oxidizing solution or in the form of an amalgam with gold or silver. The former operating method applies ta samples having a mercury concentration greater than I !ag/Nm3, and the latter for concentrations smaller than 5 (-Lg/Nm3. Detection thresholds are respectively 10 ng (in solution and 0.3 ng (in amalgam. The repeatability for 100 ng of mercury (in amalgam is ± 7 % with a probability of 95%. To conclude, in a sample of natural gas, considering the volume of the samples taken, it is possible ta detect concentrations in the vicinity of one nanogrom of mercury per cubic meter of gas.

  14. World Gas Prospects: Which Role for the Middle East? Perspectives mondiales du gaz naturel : quel rôle pourrait jouer le Moyen-Orient ?

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    Chabrelie M. F.

    2006-12-01

    Full Text Available Since the early 1970s, the policies of energy diversification that have been implemented in the industrialized countries and in many developing countries have enabled natural gas to regularly increase its role in the world energy balance. Thus, during the past twenty years, natural gas recorded the highest growth rate among fossil fuels, and its share in the energy market has gradually risen from 18. 9% in 1975 to 23% in 1997. Today, thanks to favorable economic and environmental factors, natural gas has become the fuel of choice on many markets. Indeed, gas is blessed with a certain number of favorable assets (abundant reserves, flexibility, high-performance uses which give it a major role in all energy demand forecast scenarios. The most spectacular development will indisputably take place in the power generation sector. Endowed with a considerable gas potential, the Middle East will represent an essential source of supply for many industrialized countries and several gas export projects, either by LNG tanker or by pipelines are currently being contemplated. During the past decade, the contribution of natural gas to the energy mix also grew substantially in most Middle Eastern countries. The increase in gas demand should continue at a sustained rate, mainly driven by the power generation sector, petrochemicals and energy consumption by the hydrocarbons industry. These promising prospects for gas demand in most of the markets in the region might lead to the development of an intra-regional network. However, although opportunities exist, the region will have to meet many challenges in order to contribute more largely to the world gas balance in the years to come. de diversification énergétique mises en Suvre dans les pays industrialisés et dans de nombreux pays en voie de développement depuis le début des années 1970 ont permis au gaz naturel d'accroître régulièrement sa présence dans le bilan énergétique mondial. Ainsi, au cours des

  15. L'évolution récente des marchés internationaux du gaz naturel

    OpenAIRE

    Jean-Pierre Angelier

    2005-01-01

    Sur la plupart des grands marchés gaziers régionaux, la demande de gaz naturel augmente plus lentement que prévu, depuis 2000. Les avantages de cette énergie font qu'elle est très appréciée par les demandeurs. Mais les producteurs sont moins incités à accroître leur offre : la rente gazière est bien moins importante que la rente pétrolière, d'une part, ce qui pousse les décideurs à investir plutôt dans le pétrole que dans le gaz, lorsqu'ils ont le choix ; d'autre part, une libéralisation peut...

  16. Natural Gas Potential of the United States Ressources potentielles en gaz naturel des États Unis

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    Kent H. C.

    2006-10-01

    principaux Louisiane méridionale, Alaska et ta région du Mid-Continent qui groupe l'Oklahoma, le Kansas et l'appendice du Texas ditPanhandle . A peu près 50 % des ressources potentielles se trouvent dans quatre zones : les Etats du nord et du centre des Rocheuses, la région du Mid-Continent, le plateau continental au large de l'Alaska et celui de la Louisiane. Les prévisions indiquent que ces sources potentielles, Alaska inclus, pourraient continuer à fournir une quantité annuelle de l'ordre de celle qui est actuellement produite aux États-Unis, et cela jusque vers l'an 2000. Depuis 1968, les réserves prouvées ont diminué dans les 48 premiers États. Ce déclin peut être attribué en partie au ralentissement de l'activité de forage de 1956 à 1972, mais l'emplacement et la profondeur des puits sont aussi des facteurs importants. Environ 14 % de tous les puits forés aux États-Unis en 1978 étaient des forages d'exploration nouvelle et seulement 4 % des sondages couronnés de succès comme producteurs de gaz ont été forés comme puits d'exploration nouvelle. En 1977, 80 % des puits mis en production étaient situés dans des secteurs et à des profondeurs où seulement 22 % des ressources potentielles en gaz naturel sont censées exister. En clair, il faut réorienter l'exploration et le forage vers les régions où l'on espère de grandes ressources potentielles de gaz, pour se préparer aux rendez-vous des besoins à venir.

  17. La formation de l'oxyde azotique dans les flammes de diffusion de gaz naturel Nitrogen. Oxyde Formation in Natural-Gas Diffusion Flams

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    Portrait L. M.

    2006-11-01

    Full Text Available L'étude de la formation de l'oxyde azotique dans des flammes de diffusion de ga naturel est effectuée depuis deux ans sur le four expérimental du Groupe d'Etude des Flammes de Gaz Naturel situé à Toulouse. Un certain nombre de variables ont été explorées : type de flamme, excès d'air, préchauffage de l'air, teneur en oxygène du comburant, puissance calorifique, et débit de moment cinétique. L'étude a mis en évidence une corrélation générale, quelle que soit la variable considérée, entre la quantité maximale d'oxyde d'azote formé et la température maximale de la flamme. Certains des résultats précédents ont été exploités à l'Institut Français du Pétrole, en vue d'établir une équation de vitesse de formation de NO applicable aux flammes axiales de diffusion de gaz naturel. Les calculs s'appuient sur les connaissances obtenues lors de l'étude cinétique de formation de NO effectuée au Laboratoire d'Aérothermique Fondamentale. Les résultats du calcul théorique confirment ceux de l'étude sur le four expérimental en ce qui concerne l'influence prépondérante de la température sur la formation de l'oxyde azotique. Par ailleurs, le calcul théorique retrouve bien les résultats obtenus lors de l'étude fondamentale, selon lesquels la cinétique de formation de NO évolue le long de la flamme depuis le front de flamme jusqu'aux gaz brûlés. La généralisation à un grand nombre de flammes de l'équation cinétique expérimentale obtenue nécessite maintenant de prendre en compte certains phénomènes de diffusion négligés jusqu'à présent. Research on the formation of nitrogen oxide in natural-gas diffusion flammes has been going on for two years in the experimental furnace of the Groupe d'Etude des Flammes de Gaz Naturel located in Toulouse. Different variables have been investigoted such as type of flamme, air excess, air preheating, oxygen content in the oxidant, heating power and kinetic moment output

  18. Application of Continuous Thermodynamics to Natural-Gas Mixtures Application de la thermodynamique continue aux mélanges de gaz naturel

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    Prausnitz J. M.

    2006-11-01

    Full Text Available This work reviews recent progress in the application of continuous thermodynamics towards calculation of phase equilibria in natural-gas mixtures. In such mixtures, there may be too many components to identify each component individually. Continuous thermodynamics provides a theoretical framework for representing the composition of a portion of the natural-gas mixture by a continuous distribution function. Advances in continuous thermodynamics are discussed in three areas :(1 Characterization and representation of composition in a many-component mixture(2 Development and application of molecular-thermodynamic models for continuous mixtures, and(3 Implementation of efficient numerical techniques for solving material-balance and phase-equilibrium equations. While continuous thermodynamics provides a useful tool for calculation of phase equilibria in natural-gas mixtures, successful implementation requires better chemical-analytical characterization methods. Further, improved semi-theoretical techniques must be developed to relate experimental characterization information to physically significant parameters in molecular-thermodynamic models. Ce travail examine les récents développements de l'application de la thermodynamique continue au calcul des équilibres de phases de mélanges de gaz naturel. Dans ces mélanges, les composants sont souvent en trop grand nombre pour qu'on puisse les identifier individuellement. La thermodynamique continue fournit un schéma théorique permettant de représenter la composition d'une partie de mélange de gaz naturel par une fonction de distribution continue. Les progrès de la thermodynamique continue sont examinés dans les trois domaines suivants : 1 caractérisation et représentation de la composition d'un mélange de plusieurs produits; 2 mise au point et application des modèles de thermodynamique moléculaire aux mélanges continus; 3 mise en oeuvre de techniques numériques efficaces pour r

  19. Procédé intégré de traitement du gaz naturel Integrated Process for Natural Gas Treatment

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    Larue J.

    2006-11-01

    Full Text Available L'Institut français du pétrole a développé une nouvelle technique de traitement du gaz naturel, le procédé intégré IFPEXOL, basé sur une nouvelle mise en oeuvre de méthanol à basse température, qui incorpore dans un procédé unique les trois fonctions de déshydratation, extraction des liquides de gaz naturel (LGN et désacidification. Le procédé IFPEXOL se compose de deux sections successives : une première section IFPEX-1 de déshydratation et d'extraction des LGN, une deuxième section IFPEX-2 de désacidification si nécessaire. Pour chaque section, l'influence des paramètres principaux sur les performances du procédé est examinée. Après un programme de recherche et développement au laboratoire et sur une unité pilote, le procédé IFPEXOL a été industrialisé. La première unité IFPEX-1 a démarré en juin 1992 au Canada sur le champ d'East Gilby en association avec Petro-Canada; par la suite, 11 autres unités IFPEX-1, dont 7 sont en opération, ont été vendues. La section IFPEX-2 est en cours de commercialisation. The Institut français du pétrole has developed a new natural gas treatment technique, the integrated IFPEXOL process, based on the use of methanol at low temperature, and which includes 3 functions in only one step : dehydration, NGL recovery and acid gases removal. The IFPEXOL process is split into two successive sections : IFPEX-1 removes NGL and water, IFPEX-2 removes the acid gases when necessary. For each section, the influence of the main parameters on the process performances is examined. After a research and development program at laboratory scale and on a pilot plant, the IFPEXOL process has reached the industrial step. The first IFPEX-1 unit has started up in June 1992 in Canada at Petro-Canada's East Gilby field. Subsequently, 11 other units, of which 7 are running, have been licenced. The results obtained from the industrial plants confirm the simulation models. The IFPEX-2 section is in

  20. Natural gas, partner of plastic engineers; Le gaz naturel, partenaire des plasturgistes

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2001-03-01

    Gaz de France company wishes to develop natural gas-fueled processes in plastic engineering thanks to the transfer of some of its technologies. The processes in concern are: infrared thermo-forming, polymers drying, cold production and moulds thermoregulation. Short note. (J.S.)

  1. Electricité et gaz naturel : du monopole public à la concurrence réglementée. Une perspective historique

    OpenAIRE

    Jean-Pierre Angelier

    2005-01-01

    Les industries de l'électricité et du gaz naturel, en France comme dans la plupart des pays, ont tout d'abord été constituées en monopoles publics. Depuis la seconde guerre mondiale, EDF et GDF ont ainsi rempli leurs missions de doter la France d'une industrie électrique et d'une industrie gazières toutes les deux efficaces.Cette structure est toutefois remise en cause du fait d'un nouvel environnement concurrentiel de ces industries : la concurrence est introduite dans l'offre, les réseaux d...

  2. Reconsideration of Methane Isotope Signature As a Criterion for the Genesis of Natural Gas: Influence of Migration on Isotopic Signatures Reconsidération de la signature isotopique du méthane comme critère pour la genèse du gaz naturel : influence de la migration sur les signatures isotopiques

    Directory of Open Access Journals (Sweden)

    Pernaton E.

    2006-11-01

    Full Text Available Experiments were performed in the purpose of studying the isotopic consequences of the diffusional transport of hydrocarbon gases through sediment rocks. Linked to a numerical model, these gas diffusion experiments through a shale porous plug allowed us to correlate porosity and diffusivity of the migration medium. Significant isotopic fractionations (carbon and hydrogen of methane, and ethane at a lesser degree were observed. This is in contradiction with the actual dogma of isotope geochemistry of natural gases which claims that no fractionation occurs during gas migration. The genetic characterization of natural gases by using the isotopic signature of methane appears as an ambiguous method. Plusieurs expériences ont été réalisées dans le but d'étudier les conséquences isotopiques du transport par diffusion des gaz hydrocarbures au travers des roches sédimentaires. Associées à un modèle numérique, ces expériences de diffusion au travers d'une membrane d'argile reconstituée nous ont permis de corréler deux paramètres pétrophysiques du milieu de migration : la porosité et la diffusivité. D'importants fractionnements isotopiques ont été observés au cours de la diffusion du méthane et, à plus petite échelle, lors de la diffusion de l'éthane. Ces résultats remettent en cause le dogme actuel de la géochimie isotopique des gaz naturels qui stipule que la migration des gaz ne peut induire de fractionnements isotopiques. En conséquence, les méthodes de caractérisation génétique des gaz naturels utilisant la signature isotopique du méthane apparaissent comme insuffisantes.

  3. Solar thermal and natural gas: an efficient complementarity; Solaire thermique et gaz naturel: une complementarite performante

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-10-01

    This document summarizes the content of a conference-debate organized by Cegibat, the information service of Gaz de France for building engineering professionals, about the complementarity between natural gas and solar thermal energies, in particular for the production of domestic hot water: 1 - the market of solar thermal energy in France (development, energy efficiency, different technical solutions, financial help, questions and answers with the public); 2 - the 'Dolce Vita' solar offer for individual houses (customers expectations, available techniques, fitter's testimony, questions and answers with the public); 3 - presentation of a combines solar system: the direct solar floor; 4 - the domestic solar hot water offer 'Dolce Vita'; 5 -testimonies; 6 - results warranty; 7 - conclusion. (J.S.)

  4. The - compromised? - future of natural gas; L'avenir - compromis? - du gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, Ph

    2009-05-15

    Will natural gas be the main loser of the January 2009 crisis between Ukraine and Russia? The demonstration is made that the European Union is not free from the risk of a severe supply disruption. This is a bad news considering that the power generation is the growth vector of natural gas. Even if the gas black-out cannot exist, the power black-out still can happen. As soon as the Russian-Ukrainian conflict has occurred, the other energy sources (nuclear and renewable) have been called for help in Europe while coal is in the expectation. Since some time now, gas has to face several trend changes. First, uncertainty is increasing considering its growth prospects. The new version of the gas pluri-annual indicative plan (PIP Gaz) would foresee a stagnation of gas consumption up to 2020 (consequence of the French environmental policy), while the previous plan had foreseen a 2.1% annual growth rate between 2005 and 2015. Second, the direct indexing of gas prices on oil prices can have undesirable effects. Finally, the u-turn of the USA with respect to liquefied natural gas (LNG) may penalize its development. What answers should the European Union give in front of these uncertainties? Have the companies modified their strategy? Is the future of gas still fine? These are the questions debated during a round table organized by the BIP, the French Bulletin of Petroleum Industry. (J.S.)

  5. Hydrodynamique, transfert de chaleur et combustion de gaz naturel en lit fluidisé circulant Hydrodynamics, Heat Transfer and Combustion of Natural Gas in a Circulating Fluidized Bed

    Directory of Open Access Journals (Sweden)

    Feugier A.

    2006-11-01

    Full Text Available L'hydrodynamique, les transferts de chaleur et la combustion du gaz naturel ont été étudiés dans un réacteur à lit circulant de 15 cm de diamètre et de 7 m de haut. Ce réacteur peut opérer avec des vitesses de gaz allant jusqu'à 15 m/s, jusqu'à des températures de 880-900°C et avec des débits de solides compris entre 0 et 15t/h. Les charges utilisées sont des sables de granulométrie allant de 95 à 625 microns. Le profil de concentration en solides dans le réacteur est déterminé à partir du profil de pression. Une corrélation reliant la vitesse de glissement des particules aux principaux paramètres opératoires, rend compte de façon très satisfaisante de l'ensemble des résultats expérimentaux. La mise en place d'un échangeur en paroi dans la partie supérieure du réacteur a permis la détermination de coefficients d'échange thermique. Ces derniers sont essentiellement fonction de la, concentration en particules au droit de l'échangeur et de la granulométrie des particules. Des valeurs allant jusqu'à 200 W/m2 K peuvent, être obtenues. Enfin, la combustion du méthane s'avère très sensible à la présence de particules dans le réacteur. Ces particules ont un effet inhibiteur. Hydrodynamics, heat transfer and combustion of natural gas have been investigated in a circulating-bed reactor 15 cm in diameter and 7 m high. This reactor can operate with gas velocities up to 15 m/s, at temperature up to 880-900°C and with solids flow rates of between 0 and 15 t/h. The solids used are sands with a particle size ranging from 95 to 625 microns. The solids concentration profile in the reactor is determined from the pressure profile. A correlation linking the slippage velocity of particles to the principal operating parameters very satisfactorily takes into consideration the overall experimental results. The installation of a wall heat exchanger in the upper part of the reactor enabled the heat exchange coefficients to be

  6. Un nouvel oxyde naturel de Au et Sb

    Science.gov (United States)

    Johan, Zdenek; Šrein, Vladimir

    1998-04-01

    A gold-antimony X-ray amorphous oxide, resulting from a hydrothermal alteration of aurostibite, AuSb 2, occurs in the Krásná Hora gold deposit, Czech Republic. Its reflectivity is close to that of goethite. The average composition obtained by electron microprobe analyses (wt. %) is: Au - 68.32; Cu - 0.10; Sb - 21.26; As - 0.30; Si - 0.21; O - 8.44; total 98.63. This yields the empirical formula (Au 0.677Cu 0.003Sb 0.341As 0.008) 1.029O. The[(Au + Cu)/(Sb + As)] at ratio varies from 1.86 to 1.95. Among possible formulae satisfying the equilibrium of charges, that implying unique valence states for Au and/or Sb was retained. It can be written Au 1+2Sb 3+O 2(OH) with the theoretical composition (wt, %): Au - 69.76; Sb - 21.54; O - 8.50; H - 0.20. This Au- and Sb-bearing oxide is associated with native gold, electrum, aurostibite, arsenopyrite and pyrite in a quartz gangue. The powder pattern of AuSbO 3 was indexedon an orthorhombic unit-cell with a = 5.00(2); b = 12.46(4); c = 5.43(2) Å, Z = 4, Q calc = 7.20 g.cm 3, assuming a replacement of Sb 3+ by Au 3+ in the valentinite-type crystal structure.

  7. A Comprehensive Numerical Study on Effects of Natural Gas Composition on the Operation of an HCCI Engine Une étude numérique complète sur les effets de la composition du gaz naturel carburant sur le réglage d’un moteur HCCI

    Directory of Open Access Journals (Sweden)

    Jahanian O.

    2011-11-01

    éristiques d’auto-inflammation du mélange dans le cylindre et la performance du moteur HCCI. Cet article met l’accent sur l’influence de la composition du gaz naturel sur le fonctionnement du moteur en mode HCCI. Six différentes compositions de gaz naturel (y compris le méthane pur ont été examinées pour étudier les performances du moteur au moyen d’un modèle thermo-cinétique zéro-dimensionnel. Le code de simulation inclut la cinétique chimique détaillée de la combustion du gaz naturel, y compris le mécanisme étendu de Zeldovich pour évaluer les émissions de NOx. Les résultats ont été validés par comparaison avec des données expérimentales provenant d’autres travaux. La richesse et le taux de compression ont été maintenus constants, mais les effets de la vitesse du moteur et de la température initiale du mélange ont été étudiés. Les résultats montrent que la valeur maximale de la pression dans le cylindre et la température dépendent du nombre Wobbe du carburant. En outre, la puissance indiquée du moteur est linéairement liée au nombre Wobbe du carburant. Le travail indiqué brut, la pression moyenne indiquée brute et les NOx ont aussi été utilisés pour comparer les performances du moteur utilisant des carburants de compositions différentes.

  8. Some economic aspects of natural uranium graphite gas reactor types. Present status and trends of costs in France; Quelques aspects economiques de la filiere uranium naturel - Graphite - gaz. Etat actuel et tendance des couts en France

    Energy Technology Data Exchange (ETDEWEB)

    Gaussens, J.; Tanguy, P. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Leo, B. [Electricite de France (EDF), 75 - Paris (France)

    1964-07-01

    reduction in investment costs can be obtained without relying on fuel enrichment, and that this development is accompanied moreover by improvements in the operational safety of the reactor. The economic aspects of the main technical problems entailed by these developments are discussed: loading and unloading machines, blowers etc... (authors) [French] Dans une premiere partie, on situe l'interet economique de l'utilisation de l'uranium naturel comme combustible. Cet interet reside a la fois dans le nombre limite et la simplicite relative des operations de mise en forme des elements combustibles, dans le faible cout du produit fini par kwh et dans les immobilisations modestes en capital qu'implique ce cycle par rapport ou cycle de l'uranium enrichi. Tous ces elements permettent de reduire le caractere aleatoire des evaluations des couts, particulierement marque dans le cas de l'uranium enrichi, en raison de la complexite de son cycle et des incertitudes concernant le prix du plutonium. Enfin, la diversite des sources d'approvisionnement en concentre d'uranium naturel opposee au quasi monopole actuel de la separation isotopique, et le faible cout du stockage de ce concentre, offrent des garanties en matiere de securite d'approvisionnement et d'independance economique et politique appreciables par rapport a l'uranium enrichi. En ce qui concerne l'ensemble des capitaux immobilises, on montre que si le cout des centrales au graphite-gaz est plus eleve que celui des centrales eau legere pour certaines gammes de puissance, ce resultat est fortement nuance des que l'on fait intervenir dans un souci d'independance nationale le cout de l'equipement de production des combustibles de l'une et l'autre filiere. Enfin, le cout marginal de la puissance du reacteur au graphite est faible, ses limitations technologiques ont considerablement recule (grace en particulier a l'utilisation du beton

  9. New combustion, environment regulations: the answers for natural gas; Nouvelles reglementations, combustion, environnement: les reponses pour le gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Le Peltier-Marc, A. [Gaz de France (GDF), 75 - Paris (France)

    1997-12-31

    This paper reports on the point of view from Gaz de France (GdF) company concerning the potential consequences of the use of natural gas in combustion systems with respect to the new regulations about combustion and environment. Details concerning the measures relative to the limitation of pollutants in small combustion installations (2 - 20 MW) are given (chimney height, SO{sub x}, NO{sub x} and dusts content in exhaust gases). (J.S.)

  10. Assurer les approvisionnements futurs en gaz naturel. Un enjeu pour la recherche Ensuring Future National Gas Supplies. High Stakes for Research

    Directory of Open Access Journals (Sweden)

    Rojey A.

    2006-11-01

    Full Text Available Un accroissement important de la demande de gaz naturel est prévu dans les années à venir. En Europe, cet accroissement de la demande ne va pas pouvoir être entièrement couvert par les sources d'approvisionnement actuelles et il sera de plus en plus nécessaire de faire appel à de nouveaux fournisseurs. Le recours à ces nouvelles sources d'approvisionnement va exiger des investissements considérables et devrait se traduire par une progression des coûts. Des progrès techniques sont nécessaires pour réduire les coûts tout en assurant la protection de l'environnement et une sécurité accrue. Le recours à des solutions innovantes dans les domaines de la production, du traitement, du transport et de la conversion chimique devrait dans l'avenir élargir les options et les débouchés offerts à l'exploitant. A considerable increase in natural gas demand has been forecast for the coming years. Present-day supply sources will be unable to cover the growing demand in Europe and new suppliers will need to be called on more and more. Diversifying to new supply sources will entail heavy investments and is bound to mean rising costs. Technical progress is necessary to reduce costs, while protecting the environment and providing improved safety conditions. Innovative solutions in the areas of production, processing, transportation and chemical conversion should in the future widen the options and outlets available to operators.

  11. Replacing propane by natural gas; Liebherr SA a Bulle. Du propane au gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Matile, O.

    2009-07-01

    Liebherr Ltd., the worldwide busy manufacturer of construction site equipment, switched from propane to natural gas as energy sources for space heating and hot water in its headquarters in Bulle, Switzerland. The compound first included an industrial building of 22,000 m{sup 2} for manufacturing activities and an office building of 5,100 m{sup 2}. When it was built in 1978, the only available gas type at the site was liquefied propane. The selected heat emission devices for the very large rooms were radiant panels. As it was out of question to use electric power as energy source, propane remained the only possible choice. A 80,000 liter tank for liquid gas was installed. Later on, following the company's development, two industrial buildings and two office buildings were added to the compound, requiring a second propane tank of 100,000 liters. In 2008 a new natural gas pipeline reached the city of Bulle and Liebherr decided to adopt this newly available source of energy. The radiant panels had to be adapted or replaced and some new internal gas distribution lines were installed. Gas boilers were installed in the office buildings. The two big gas tanks have been dismantled and the propane delivery by trucks suppressed. No dangerous liquid gas transfer to the tanks was needed any longer. Also, the costly electrically heating-up of the propane gas by means of 90 kW resistors became unnecessary. The company is eased to have no longer any stored propane in its compound.

  12. Contrôle et prévention des émissions de SO² à l'usine de traitement de gaz naturel de Lacq SO² Emission Control and Prevention At the Lacq Natural Gas Processing Plant

    Directory of Open Access Journals (Sweden)

    Bonometti G.

    2006-11-01

    Full Text Available Le gisement de gaz naturel de Lacq, mis en production à partir de 1958 dans le Sud-Ouest de la France, est aujourd'hui exploité avec les gisements satellites de Meillon, Saint-Faust, Pont-d'As à un régime journalier de près de 33 millions de mètres cubes. La forte proportion d'hydrogène sulfuré qu'ils contiennent entraîne une production de plus de 5500 tonnes par jour de soufre. La concentration sur un même site d'une source potentielle aussi importante d'anhydride sulfureux pouvait laisser craindre un impact d'autant plus grave sur l'environnement que les conditions météorologiques locales étaient généralement défavorables. Les systèmes de contrôle et de prévention étudiés, développés et exploités à l'usine de Lacq par la Société Nationale Elf Aquitaine (Production SNEA (P, au fur et a mesure du développement des champs, sont présentés en même temps que les résultats obtenus. De nombreuses actions lancées simultanément ont apporté leur contribution particulière à la résolution du problème posé. The Lacq natural gas field, which has been producing since 1958 in Southwest France, is currently producing, together with thé satellite fields of Meillon, Saint-Faust and Pont-d'As, of a daily rate of nearly 33 million cubic meters. The high proportion of hydrogen sulfide they contain results in a daily production of more than 5,500 tonnes of sulfur. The concentration of such a large potentiel source of sulfur dioxide in one place might be considered as a serious threat to thé environment because local weather conditions are very often unfavorable. The control and prévention systems researched, developed and operated at the Lacq plant by Société Nationale Elf Aquitaine (Production SNEA (PI as the gas fields have been developed are described together with the results obtained. Various measures token simultaneously have collectively helped ta overcome the problem.

  13. The performance of the natural gas solutions in the accommodation; La performance des solutions gaz naturel dans l'habitat

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    This paper presents the Gaz De France Group policy concerning the utilization of the gas as energy source in residential buildings for heating and cooking. The market and more specially the manufacturers importance are discussed. (A.L.B.)

  14. Recovering Energy at Entry of Natural Gas into Customer Premises by Employing a Counter-Flow Vortex Tube Récupération d’énergie à l’arrivée du gaz naturel dans les installations des usagers grâce à l’emploi d’un tube Vortex à contre-courant

    Directory of Open Access Journals (Sweden)

    Farzaneh-Gord M.

    2010-10-01

    Full Text Available Throttling valves are currently utilised to reduce high-pressure natural gas flowing through the distribution pipeline to the working level of customers’ equipment. This wastes valuable energy of the gas. Due to low natural gas consumption at customer premises, it is not feasible to utilise expansion machines. In this study, a new idea is proposed to take advantage of the Vortex Tube and natural gas pressure reduction. The idea is to replace the throttling valve with a Vortex Tube in the natural gas pressure reduction system and take advantage of the generated cooling capacity. An experimental investigation was made to determine the effects of the cold orifice diameter and the energy separation of the counter-flow Vortex Tube when air and natural gas are used as the fluid. The energy separation was investigated by use of the experimentally obtained data. La reduction de la pression de gaz naturel entre les conduites de distribution haute pression et les installations des usagers est aujourd’hui assuree par des vannes de reduction de pression. Ce dispositif entraine une perte importante du contenu energetique du gaz. Les installations des usagers consommant trop peu de gaz naturel pour envisager d’avoir recours a des dispositifs d’expansion, notre etude explore les avantages potentiels de l’utilisation d’un tube Vortex pour la reduction de la pression de gaz naturel. Il s’agit de remplacer la vanne de reduction de pression par un tube Vortex dans le dispositif de reduction de la pression de gaz naturel et de tirer profit de la capacite de refroidissement produite. L’etude experimentale avait pour objectif de determiner l’effet du diametre de l’orifice froid ainsi que de l’utilisation de l’air et du gaz naturel comme fluides sur la production d’energie dans le tube Vortex a contre-courant. Le taux de recuperation de l’energie est determine a partir des mesures experimentales.

  15. Natural gas; Le gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Salomon, A.

    2010-09-15

    Among all the different energies which will answer to the world demand, natural gas has undoubtedly a particular and preferential position. It possesses indeed several favourable factors, among them a lower CO{sub 2} release than the other fossil resources. Natural gas will have to continue its development and to affirm its role in the years 2030. (O.M.)

  16. Technical Assessment of Isothermal and Non-Isothermal Modelings of Natural Gas Pipeline Operational Conditions Évaluation technique de modélisations isothermes et non isothermes de conditions opérationnelles de conduites de gaz naturel

    Directory of Open Access Journals (Sweden)

    Sanaye S.

    2012-05-01

    Full Text Available Modeling of equipment in a gas pipeline was performed here by deriving a new form of conservation equation set for compressible flow. Then a section of the third Iranian gas transmission pipeline (Nourabad-Pataveh-Dorahan, N-P-D was investigated by isothermal (IT and non-isothermal (NIT modeling approaches taking into account the effects of ground temperature. In the first part, the steady state operation of the N-P-D pipeline including a compressor station at Pataveh was studied. For the known values of natural gas mass flow rate, and inlet/outlet gas pressures at Nourabad/Dorahan points, the IT and NIT modelings showed about 33.7%, 16.6% and 23% maximum difference percent points for the compressors head, compressors rotational speed and fuel consumption rates respectively. In the second part, the unsteady operation of the N-P-D pipeline due to the shutdown of a compressor at Pataveh Compressor Station (PCS was studied. The results confirmed that at lower ground temperatures (0 and 20°C, the remaining compressors could compensate the loss of one compressor. However, at higher ground temperatures (40 and 50°C, the compressors had to run faster than the highest permissible speed to be able to deliver a certain mass flow rate without reducing the required pipeline pressure. In all above studied cases, the computing time for the non-isothermal modeling was about three times longer than that for the isothermal one. Une modélisation d'équipement au sein d'un gazoduc a été réalisée en dérivant une nouvelle forme d'ensemble d'équations de conservation pour un écoulement compressible. Une section du troisième réseau de distribution de gaz iranien (Nourabad-Pataveh-Dorahan, N-P-D a été ensuite étudiée selon des approches de modélisation isotherme (IT et non isotherme (NIT en prenant en compte les effets de la température du sol. Dans la première partie, le fonctionnement en régime stationnaire du gazoduc N-P-D, comprenant une station

  17. Adaptation des techniques de forage à la recherche et à l'équipement des stockages souterrains de gaz naturel Adapting Drilling Techniques to the Search for and Equipment of Underground Natural-Gas Storage Facilities

    Directory of Open Access Journals (Sweden)

    Grandin J.

    2006-11-01

    Full Text Available Pour répondre à la modulation annuelle de la consommation de gaz, le Gaz de France a décidé, il y a une trentaine d'années, de stocker du gaz, soit dans des nappes aquifères, soit dans des cavités salines. La recherche de structures géologiques aptes à recevoir ce gaz, la réalisation et l'équipement de puits d'exploration ou d'exploitation, l'entretien de ces puits et le contrôle des stockages ont été confiés au Département réservoirs souterrains de la Direction des études et techniques nouvelles. Les phases d'exploration et de développement d'un stockage souterrain nécessitent le forage de puits du type pétrolier. Ces sondages permettent, d'une part la récupération d'un maximum de renseignements concernant les différentes couches géologiques traversées et l'évaluation de leur aptitude à stocker le gaz, et d'autre part, d'assurer une exploitation optimale et fiable du stockage dans les meilleures conditions de sécurité. La pratique acquise dans l'exécution de ces forages par le Gaz de France lui a permis d'adapter aux stockages souterrains de nombreuses techniques des forages pétroliers. Parallèlement des procédés originaux ont pu être mis au point pour répondre à certaines exigences particulières du forage des puits de réservoirs souterrains, notamment à celles concernant le bon calibrage du trou foré ou la qualité des cimentations des cuvelages. L'article présente l'ensemble de ces adaptationset pratiques originales; bien que ne prétendant rien d'autre qu'apporter une contribution au chapitre problèmes particuliers des forages pour stockages souterrains de la technique pétrolière, certaines de celles-ci devraient pouvoir, en retour, trouver des applications intéressantes dans les forages pétroliers de moyenne profondeur. About 30 years ago and with a view to keep pace with the annual variation of gas consumption, Gaz de France decided to store gas in either aquifer layers or salt cavities. The

  18. Algeria facing the challenges of Europe natural gas supply and the respect of the environment.; L'Algerie face aux defis de l'approvisionnement de l'Europe en gaz naturel et le respect de l'environnement

    Energy Technology Data Exchange (ETDEWEB)

    Ali, Nadia Nait

    2010-09-15

    Taking into account the expectations, for the next decades, of a strong increase in the demand for gas in Europe, Algeria has committed to large structuring projects, adding to the two gas pipeline linking Algeria to Spain via Morocco and Algeria to Italy via Tunisia. Two more undertakings are added linking Algeria directly to two European partners. Sonatrach will play an important role in global environment protection, natural gas being less polluting than oil and coal and emitting less co2. Substitution of coal by natural gas will generate socio economical advantages and will preserve the environment. [French] Compte tenu des attentes, pour les decennies prochaines, d'une forte croissance de la demande de gaz en Europe, l'Algerie s'est engagee dans de grands projet structurants s'ajoutant aux deux gazoducs reliant l'Algerie a l'Espagne via le Maroc et l'Algerie a l'Italie via la Tunisie, viennent s'ajouter deux autres ouvrages reliant directement l'Algerie a deux partenaires europeens. Sonatrach Jouera un role important dans la protection de l'environnement a l'echelle mondiale, le gaz naturel est moins polluants que le petrole, le charbon et emet moins de co2. La substitution du charbon par le gaz naturel generera des avantages socio-economiques, preservation de l'environnement.

  19. Surface Gas Geochemistry above the Natural CO2 Reservoir of Montmiral (Drôme, France, Source Tracking and Gas Exchange between the Soil, Biosphere and Atmosphere Échanges gazeux et géochimie des gaz à la surface du réservoir naturel profond de CO2 de Montmiral (Drôme

    Directory of Open Access Journals (Sweden)

    Gal F.

    2010-07-01

    Full Text Available One of the options considered to mitigate greenhouse gas concentrations in the atmosphere is underground storage of CO2. There is a strong need for enhancing and developing methods that would help throughout the duration life of such underground storage, to ensure the safety and able to monitor the evolution of the injected CO2 plume. Among these, geochemical methods can play an important role. Here, we describe results acquired under the research programme “Géocarbone-Monitoring”, partially funded by the French National Research Agency, on the Montmiral natural analogue in South-Eastern France. Other results obtained under the same research programme in the French Massif Central are reported elsewhere in this volume. Spot sampling methods allowing a great geographical coverage and continuous measurements on selected points were undertaken in 2006 and 2007, in order to determine soil gas concentrations and fluxes as well as carbon isotope ratio determinations. One important result is that without any evidence of deep CO2 leakage, both CO2 concentrations and fluxes appear to be higher than can be explained only by biological activities. Further investigations are thus needed to understand the gas evolution better throughout the year. Une des options envisagées pour réguler les concentrations de gaz à effet de serre dans l’atmosphère est le stockage souterrain du CO2. Dans ce domaine existe un fort besoin de renforcer et de développer des méthodes susceptibles d’être utilisées tout au long de la durée de vie de ces stockages souterrains, afin de s’assurer de leur sécurité et de pouvoir suivre l’évolution du panache de CO2 injecté. Parmi elles, les méthodes géochimiques peuvent jouer un rôle important. Nous décrivons ici les résultats acquis dans le cadre du programme de recherche « Géocarbone-Monitoring » financé en partie par l’Agence Nationale de la Recherche sur l’analogue naturel de Montmiral dans le Sud

  20. L'approvisionnement de l'Europe en gaz naturel à l'horizon 2010 European Natural Gas Supplies in Year 2010

    Directory of Open Access Journals (Sweden)

    Bauquis P. R.

    2006-11-01

    Full Text Available Cet article présente une prévision à l'horizon 2010 des besoins et de l'approvisionnement en gaz de l'Europe (Europe occidentale et orientale. Il montre qu'à cet horizon, tant la Norvège que l'Afrique du Nord augmenteront substantiellement leurs approvisionnements destinés à l'Europe, tandis que la plus forte augmentation en terme de volumes proviendra de l'ex-URSS et principalement de Russie. D'après cette analyse, la Russie serait capable de produire les volumes requis, même sans mettre en production les gisements de la péninsule de Yamal, tandis que les réserves gazières de la mer de Barentz russe (nommément le champ de Stockmanovskoye pourraient être développées d'ici 2005 ou même plus tôt. Durant la période 1995-2005, les quantités de gaz destinées à l'Europe en provenance du Moyen-Orient resteraient très limitées, alors qu'un premier gazoduc vers l'Europe pourrait entrer en opération vers 2010. Ultérieurement, le gaz du Moyen-Orient serait nécessaire pour maintenir un approvisionnement gazier de l'Europe en ligne avec les besoins européens. This article attempts to forecast european (Western and Eastern natural gas demand and gas supplies up to 2010. It shows that at such a horizon both Norway and North Africa will have substantially increased their gas exports supplied to the European markets while the largest increase in terms of additionnal volumes will comes the former USSR, essentially from Russia. According to this analysis, Russia would be able to produce the required volumes even without putting into production the Yamal Peninsula fields, while the Russian Barentz Sea gas reserves (namely Stockmanovskoye could be developed by 2005 or even earlier. During the period 1995-2005 only very limited gas exports to Europe would be required from the Middle East gas sources but the first gas pipeline between this region and Europe could begin to operate around 2010. Later on additionnal Middle East gas will be

  1. Guidebook of natural gas air conditioning in the buildings of territorial organizations; Guide de la climatisation gaz naturel dans les batiments des collectives territotiales

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-06-01

    In the framework of the 'common energy' approach, a partnership between Gaz de France (GdF) and the territorial associations (association of French territorial engineers (AITF) and association of French territorial graduate technicians (ATTF)), the publication since 15 years of this book of good practices makes a status of the implementation of natural gas air-conditioning in the buildings of the territorial organizations. Its aim is to supply information about the absorption principle, the existing products, the design of a natural gas air-conditioning system, its implementation, exploitation and maintenance. It presents also some experience feedbacks (town halls, swimming pools..) and three reference files in appendix. (J.S.)

  2. A Geochemical Approach for Monitoring a CO2 Pilot Site: Rousse, France. A Major gases, CO2-Carbon Isotopes and Noble Gases Combined Approach Une méthode géochimique pour la surveillance d’un site pilote de stockage de CO2 : Rousse, France. Approche combinant les gaz majeurs, l’isotopie du carbone du CO2 et les gaz rares

    Directory of Open Access Journals (Sweden)

    Garcia B.

    2012-02-01

    storage pilot suggest that noble gas compositions produced by oxyfuel process are sufficiently exotic compared to compositions found in nature (reservoir, aquifer and air to be directly used as tracers of the injected CO2, and to detect and quantify leaks at soil and aquifer levels. Ce papier presente la caracterisation geochimique des differents gaz, naturels et anthropogeniques, impliques dans un pilote de stockage de CO2 en champ de gaz naturel appauvri (Rousse, France. Dans ce pilote, le CO2 est produit par oxycombustion d’un gaz naturel transforme en gaz domestique a l’usine de Lacq. Ce CO2 est transporte dans un pipeline de 30 km de longueur jusqu’au reservoir de gaz appauvri de Rousse. Les gaz produits a Rousse avant injection de CO2, le gaz commercial de Lacq et le CO2 resultant de l’oxycombustion ont ete echantillonnes, ainsi que les gaz situes dans un puits de surveillance (a une profondeur de 45 m et les gaz du sol situes au voisinage de Rousse. Pour tous ces echantillons, la composition en gaz majeurs, la signature isotopique du carbone ainsi que l’abondance et signature isotopique des gaz rares ont ete determinees. Les compositions gazeuses du gaz naturel de Rousse sont comparables a celle du gaz domestique de Lacq avec le methane comme compose principal et la fraction C2-C5 et CO2 comme gaz residuels. Les gaz des sols refletent typiquement des melanges entre l’air (pole pur et le CO2 d’origine biogenique (avec des teneurs maximales de l’ordre de 9-10 %, tandis que les gaz presents dans le puits de monitoring refletent typiquement la composition de l’air sans exces de CO2. Le gaz de Rousse et le gaz domestique du site de Lacq ont une composition isotopique δ13CCH4 egale a –41,0 ‰ et –43,0 ‰ respectivement. Le CO2 injecte sur Rousse a une composition isotopique δ13CCO2 egale a –40,0 ‰ a la sortie de la chambre d’oxycombustion, tandis que la composition isotopique δ13CCO2 des gaz des sols est comprise entre –15 et –25

  3. DEVELOPPEMENT D'UN MODELE NUMERIQUE POUR L'OPTIMISATION D'UN MICRO COGENERATEUR GAZ COUPLE AU BATIMENT

    OpenAIRE

    Bouvenot, Jean-Baptiste; Latour, Benjamin; Stabat, Pascal; Flament, Bernard; Siroux, Monica; Marchio, Dominique

    2014-01-01

    International audience; Une solution de micro cogénération à moteur Stirling à gaz est testée sur la plateforme Climatherm à l'INSA de Strasbourg. Ce micro cogénérateur intègre une chaudière auxiliaire montée en série et en aval du moteur Stirling. Un modèle numérique, permettant de simuler les performances énergétiques du moteur Stirling et de la chaudière auxiliaire a été développé et calibré à partir d'essais expérimentaux réalisés au laboratoire. Sur la base de ce modèle, implémenté dans ...

  4. Natural Gas Hydrate Phase Equilibria and Kinetics : Understanding the State-Of-The-Art Équilibres des phases des hydrates de gaz naturel et cinétique

    Directory of Open Access Journals (Sweden)

    Sloan E. D.

    2006-11-01

    Full Text Available An overview is given of gas hydrate phase equilibria and kinetics. It is suggested that with only a few exceptions hydrate phase equilibrium conditions may be predicted with acceptable accuracy for industrial purposes via the current state-of-the art. Hydrate research is at a milestone, going beyond equilibrium experiments to time-dependent measurements, such as in the kinetic arena, where there is a severe paucity of date. To illustrate the concepts, two qualitative microscopic models are presented :1 the hydrate guest: cavity size ratio and2 the dissolution of apolar molecules in liquid water. Hypotheses for macroscopic phase equilibria and kinetic nucleation phenomena are given, based upon the two models. Cet article présente brièvement les équilibres des phases des hydrates de gaz naturel et leur cinétique. Il signale qu'en l'état actuel des connaissances, les conditions d'équilibre des phases des hydrates peuvent être connues, à quelques exceptions près, avec une précision acceptable dans un but industriel. La recherche sur les hydrates atteint un point décisif, elle dépasse les expériences d'équilibre et s'intéresse aux mesures variant en fonction du temps, celles de la cinétique par exemple, où les données sont particulièrement rares. Pour illustrer le concept deux modèles qualitatifs microscopiques sont présentés : 1 le rapport de grosseur hydrate hôte/cavité, et 2 la dissolution des molécules apolaires dans l'eau liquide. L'auteur émet des hypothèses relatives aux phénomènes macroscopiques d'équilibres des phases et de nucléation cinétique, basées sur ces deux modèles.

  5. Effets de la nature de l’addition minérale sur la diffusion et la perméabilité au gaz des BAP

    OpenAIRE

    SIAD, H.; MESBAH, H.A.; KHELAFI, H.; Escadeillas, G.; MOULI, M.

    2011-01-01

    Les études antérieures se focalisant beaucoup plus sur la comparaison entre le BAP et le béton ordinaire vibré (BOV). Cet article vise à montrer l’influence de la nature de certains ajouts minéraux (filler calcaire, pouzzolane naturelle et cendre volante) sur les propriétés de transferts des bétons et à chercher une relation entre la diffusion et la perméabilité au gaz des BAP. Le programme expérimental comprend, au total, douze formulations couvrant trois différentes classes d...

  6. Optimisation énergétique des procédés de séparation en raffinage et en traitement de gaz naturel Optimal Use of Energy in Separation Processes for Refining and Natural Gas Treatment

    Directory of Open Access Journals (Sweden)

    Rojey A.

    2006-11-01

    Full Text Available Cet article présente une méthode d'optimisation des procédés de séparation basée sur une analyse thermodynamique. Cette analyse s'appuie sur un bilan exergétique qui est établi dans le cas général d'un système quelconque opérant en régime permanent. Les facteurs qui conditionnent le rendement exergétique d'un procédé de séparation sont ensuite examinés. Il en résulte une méthode d'optimisation basée sur une réduction des irréversibilités thermodynamiques. Des exemples concrets d'application en raffinage et en traitement de gaz naturel sont présentés, et on montre comment cette analyse peut déboucher sur la conception de procédés innovants. The optimization of separation units in refining and natural-gas processing must take into consideration new needs and constraints that may seem incompatible. New installations must be designed not only on the basis of energy optimization but also by seeking to minimize investments and to respect new rules concerning environmental protection. The optimization described in this article is based on a thermodynamic analysis of different material and energy exchanges, The energybalance provides a suitable basis for making this analysis. It leads to the defining of an exergy efficiency that is all the higher as the thermodynamic irreversibilities are reduced, and that tends toward one for an ideal reversible system. For a separation process, a separation exergyterm is defined that correspond to the minimum separation work . Distillation is the basic separation operation. The exergy efficiency of this operation is low, and we show that, even in a relatively favorable cas, it is no greater than a value of about 6%. For an atmospheric distillation operation of crude oil, the exergy efficiency is about 4%. This overall exergy efficiency is the product of an external exergy efficiency and an internal exergy efficiency. The external exergy efficiency can be improved by better thermal

  7. Natural gas storage; Stockage de gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Bautz, R.

    2009-07-01

    Storage is an important link in the natural gas supply chain. It is a valuable aid to providing the link between remote sources of production and consumption locations. After a brief recall covering the role of storage this article describes the various options for storing natural gas: saline cavities, aquifers, liquefied gas tanks or artificial cavities. A report follows on the different solutions adopted in Europe and in Switzerland, more particularly that chosen by Gaznat in order to contribute to securing supplies in Western Switzerland. Market deregulation has brought changes to the regulations, which are in turn modifying the rules that were in force until just recently, and new topics are arising, such as strategic reserves and pricing rules for stored natural gas. (author)

  8. Liquefied natural gas; Gaz naturel liquefie

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    Total has interests in five of the world's largest liquefaction plants, which together account for roughly 40% of global LNG production capacity. This presentation illustrates the activities of the Group in the LNG sector. It discusses the advantages of the LNG as a clean energy, the LNG market, the liquefaction process and plants, the LNG trading marketing and shipping, the re-gasification and TOTAL promoting innovation. (A.L.B.)

  9. Proposition d'explication de la formation d'hydrogène sulfuré dans les stockages souterrains de gaz naturel par réduction des sulfures minéraux de la roche magasin Proposed Explanation of Hydrogen-Sulfide Formation in Underground Natural-Gas Storage Structures by Reduction of Mineral Sulfides in the Reservoir Rock.

    Directory of Open Access Journals (Sweden)

    Bourgeois J. P.

    2006-11-01

    Full Text Available La formation d'hydrogène sulfuré dans les structures de stockage peu expliquer autrement que par l'action de bactéries sulfato-réductrices. La contenue dans la roche magasin constitue une source de sulfures capable d'alimenter en H2S le gaz naturel. La réduction de la pyrite en sulfures du type Fe 1-x S et l'équilibre de dissolution précipitation, lié principalement à la pression de CO2, dans les structures stockages, constituent un processus de formation d'H2S capable d'expliquer tativement et quantitativement les phénomènes observés sur le terrain. Un modèle simplifié de stockage reprend ce schéma et teste la sensibililté de la teneur en H2S à la valeur des paramètres physiques et chimiques définissant le stockage. Cette étude permet de proposer un certain nombre d'actions susceptibles de limiter la formation d'H2S et d'orienter les choix futurs du couple gaz naturel - structures de stockage. The formation of hydrogen sulfide in storage structures can be explained otherwise thon by the action of sulfate-reducing bacteria. The pyrite contained in the reservoir rock makes up a source of sulfides capable of supplying the natural gas with H2S.Reduction of pyrite ta sulfides of the Fe,-,S type and the dissolution precipitation equilibrium, linked mainly ta C02 pressure in storage structures, make up an H2S for-mation process capable of qualitatively and quantitatively explained phenomena observed in the field.A simplified storage model reflects this scheme and can be used ta test the sensi-tivity of the H2S content ta the value of the physical and chemical parameters defining the storage structure.This investigation can be used to propose various means of action (sable ta "mit H2S formation and ta guide future choices of natural gas/storage-structure pairs.

  10. National measures fostering alternative vehicles: electric, natural gas, liquefied oil gas vehicles; Dispositions nationales en faveur des vehicules alternatifs: vehicules electriques, au gaz naturel (GNv) et au gaz de petrole liquefie (GPLc)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-02-07

    This document, issued by the French Ministry of Economy, Finances and Industry, presents national measures fostering alternative vehicles, i.e., electric, natural gas and liquefied oil gas vehicles. Financial supports for studies aiming at optimizing the fleet and choosing the alternative vehicles as well as for purchasing vehicles both by counter procedure and for demonstration programmes are provided. Amount of subsidies, conditions of obtaining and categories of addressees are indicated. The document contains also two relating studies. The first one is titled 'the policy of developing alternative vehicles'. The following four items are addressed: - the present frame favouring the alternative vehicles; - the electric vehicles; - natural gas fuelled vehicles (GNV); - liquefied oil gas fuelled vehicles (GPLc). Although non-polluting the electric vehicles are not tempting because of their rather limited range (80 Km at a battery charging). So far only around 3,000 vehicles were sold. Fifty GNV buses were ordered by RATP and the figure raised at 70 in 1998 and 1999. The GPLc fleet amounts up to 70,000 vehicles and by the end of 2000 it is foreseen to reach the level of 300,000 vehicles. The second study addresses to the issue of natural gas for vehicles. It presents: - its advantages; - its peculiarities; - the action of public authorities; -the current state and trends of GNV vehicles. In a joint effort public authorities and partners of this option are aiming at a fleet of 2500 light service vehicles and 300 bus for urban transport by the end of 1999.

  11. Support to the electric power, natural gas or liquefied petroleum gas (LPG) vehicles; Les aides aux vehicules electriques, au gaz naturel (GNV) ou au gaz de petrole liquefie (GPLc)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-01-15

    This document brings together the different financial incentives proposed to the acquisition and utilization of electric power, natural gas or LPG vehicles. The financial assistance of the ADEME, the fiscal incentives and other proposals are detailed. (A.L.B.)

  12. Price cap regulation: the case of natural gas transport in the UK; La reglementation par price cap: le cas du transport de gaz naturel au Royaume Uni

    Energy Technology Data Exchange (ETDEWEB)

    David, L. [ATER, Paris-1 Univ., 75 (France)

    1999-09-01

    The transport and storage activities of British Gas company are controlled by a distinct organization named Transco. The access charges paid by the suppliers for the use of Transco's network are regulated by a price cap since October 1, 1994. However, Ofgas, the office of gas supply which is the regulation authority in charge of the control of competition and of British Gas activities, considers this control system as inefficient and has chosen a RPI (retail price index)-X (expected productivity factor)-type price cap for the control of gas transport tariffs. This has led to a disagreement between Transco and Ofgas which has delayed the implementation of the new system up to February 1998. This article compares the choices made by Ofgas for the control of gas transport tariffs with the economical theory. It recalls first, the reasons why the price cap appears as more efficient than the service cost regulation, the alternate method used by regulation authorities to control the tariffs of natural monopolies. Then, the difficulties linked with the implementation of the price cap for the transport of natural gas in the UK are analyzed in order to explain the reasons that led Ofgas to change its formula. Finally, the bases of an optimum hybrid formula are proposed. (J.S.)

  13. Low intensity natural gas infrared in sports centres; L'infrarouge a basse intensite au gaz naturel dans les centres sportifs

    Energy Technology Data Exchange (ETDEWEB)

    Lajoie, S. [Gaz Metropolitain, Montreal, PQ (Canada)

    2002-09-30

    Infrared devices are being employed more and more for heating buildings. They were traditionally used to heat large spaces higher than 3 metres, such as aviation hangars and industrial buildings. Natural gas infrared devices have found other applications, namely in sports centres, due in large part to the energy efficiency and the resulting comfort. There are three types of infrared devices: low intensity or low intensity tubes, high intensity, and catalytic infrared. Each type of device possesses specific characteristics and applications. For example, infrared tubes are used to uniformly heat a specific area. High intensity devices possess a more intense heat and concentrated in a confined space. Catalytic devices do not have flames, and they can be used in industrial drying processes and thermoforming. In the case of skating rinks, the use of low intensity natural gas infrared tubes is ideal. They reduce the crossed effects of ice cooling load and the spectators need for heat. This is due to infrared acting more on mass (spectators and bleachers) than ambient air. The author described the situation at the Val d'Or arena, Quebec where an energy saving project was initiated two years ago, involving the installation for one of the ice surfaces, of movement sensors to turn off infrared tubes when the rink is unoccupied. The payback period for such equipment is short. The case of the Soccerplex at Lachine, part of the larger City of Montreal, was also discussed. This sports centre comprises indoor soccer fields with 30 foot-high ceilings and large area covering 66,000 square feet (3 soccer fields). Once again, low intensity natural gas infrared tubes were installed and have proved successful.

  14. Performance of natural gas distribution networks during the Kocaeli earthquake - 17 august 1999; Comportement des reseaux de distributions de gaz naturel lors du tremblement de terre de Kocaeli 17 aout 1999

    Energy Technology Data Exchange (ETDEWEB)

    Zarea, M.; Adrien, M. [Gaz de France (GDF), 75 - Paris (France)

    2000-07-01

    The Kocaeli (Izmit) earthquake struck recently, on August 17, 1999, a well developed area of Turkey. This earthquake, of a magnitude 7.4 on the open Richter scale, severely damaged numerous buildings, industrial infrastructure, and made a lot of victims. In this context, most attention is given to issues like: seismology (why and how did it happen, what will happen next, etc.), seismic design and construction (why buildings collapsed and how to avoid this in the future). Some other subjects get less attention, because their direct influence in the overall damage is smaller. The behaviour of 'lifelines', designating all the networks which contribute to 'modern' lifestyle: water, energy, communications, etc., belong to this category. Nevertheless, the performance of lifelines during such strong earthquakes is also important, because they can contribute to minimise its impact. This impact has its usual two aspects: integrity and operability. For instance, the integrity requirement means that failures of the considered lifeline due to the earthquake should not directly affect property and life. The operability requirement means that a given subset of the lifeline remains operational, in order to fulfill vital tasks. We propose here a brief analysis of the performance of two relatively recently commissioned gas distribution systems: IZGAZ in Izmit, close the epicenter, and IDGAS in Istanbul. They have the advantage of representing a large sample of a recent implementation of the PE (polyethylene) technique, which has reached maturity. Both are cases of the Gaz de France 4 bar PE technology transferred to a Turkish operator, who completely managed the crisis. The first part describes the two networks, both their high medium pressure steel network, regulators, and the intermediate PE network, finishing with service lines and boxes. Then, the damage reported by the operational teams and their very important shut-down and blowdown actions are summarised

  15. Dépollution des gaz d'échappement des moteurs diesel au moyen de pots catalytiques Depolluting Exhaust Gases from Diesel Engines by Catalytic Mufflers

    Directory of Open Access Journals (Sweden)

    Goldenberg E.

    2006-11-01

    Full Text Available On présente dans cet article les résultats d'une première série de recherches sur la dépollution des gaz d'échappement des moteurs diesel au moyen de pots catalytiques. L'efficacité des catalyseurs à base de platine pour l'oxydation du monoxyde de carbone et des hydrocarbures imbrûlés a pu être établie par des essais sur banc moteur et sur véhicule. L'emploi de certaines phases actives à base de métaux non nobles permet d'autre part d'abaisser la température de début d'oxydation des particules de suie de 380 à 250 °C environ, avec, entre 250 et 350 °C, élimination de 15 à 20 % des produits piégés. L'essai de divers media filtrants a mis en évidence l'importance des phénomènes d'adsorption des revêtements en alumine et a orienté la recherche vers de nouveaux supports pour filtres catalytiques. This article describes the results of a first series of research on the depollution of exhaust gases from diesel engines by catalytic mufflers. The effectiveness of platinum-base catalysts for the oxidation of carbon monoxide and unburned hydrocarbons was determined by test on an engine test bed and on vehicles on the road. The use of some active non-noble metal phases reduced on the other hand the starting oxidation temperature of soot particulates from 380°C to about 250°C, eliminating 15 to 20% of the trapped products between 250 and 350° C. Tests of different filtering media revealed the importance of adsorption phenomena on alumina coatings and directed research toward new supports for catalytic filters.

  16. Fluctuations Magnetiques des Gaz D'electrons Bidimensionnels: Application AU Compose Supraconducteur LANTHANE(2-X) Strontium(x) Cuivre OXYGENE(4)

    Science.gov (United States)

    Benard, Pierre

    Nous presentons une etude des fluctuations magnetiques de la phase normale de l'oxyde de cuivre supraconducteur La_{2-x}Sr _{x}CuO_4 . Le compose est modelise par le Hamiltonien de Hubbard bidimensionnel avec un terme de saut vers les deuxiemes voisins (modele tt'U). Le modele est etudie en utilisant l'approximation de la GRPA (Generalized Random Phase Approximation) et en incluant les effets de la renormalisation de l'interaction de Hubbard par les diagrammes de Brueckner-Kanamori. Dans l'approche presentee dans ce travail, les maximums du facteur de structure magnetique observes par les experiences de diffusion de neutrons sont associes aux anomalies 2k _{F} de reseau du facteur de structure des gaz d'electrons bidimensionnels sans interaction. Ces anomalies proviennent de la diffusion entre particules situees a des points de la surface de Fermi ou les vitesses de Fermi sont tangentes, et conduisent a des divergences dont la nature depend de la geometrie de la surface de Fermi au voisinage de ces points. Ces resultats sont ensuite appliques au modele tt'U, dont le modele de Hubbard usuel tU est un cas particulier. Dans la majorite des cas, les interactions ne determinent pas la position des maximums du facteur de structure. Le role de l'interaction est d'augmenter l'intensite des structures du facteur de structure magnetique associees a l'instabilite magnetique du systeme. Ces structures sont souvent deja presentes dans la partie imaginaire de la susceptibilite sans interaction. Le rapport d'intensite entre les maximums absolus et les autres structures du facteur de structure magnetique permet de determiner le rapport U_ {rn}/U_{c} qui mesure la proximite d'une instabilite magnetique. Le diagramme de phase est ensuite etudie afin de delimiter la plage de validite de l'approximation. Apres avoir discute des modes collectifs et de l'effet d'une partie imaginaire non-nulle de la self-energie, l'origine de l'echelle d'energie des fluctuations magnetiques est examinee

  17. The natural gas vehicles; Le gaz naturel vehicules

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    The NGV (Natural Gas Vehicles) is a new ''clean'' fuel used for the urban public transports which can be adapted to the vehicles. It is the same gas as those for the cooking and the heating, but compressed at 200 bars. this document presents this abundant energy sources, the bound emissions standards, the technical and economical aspects, the environmental advantages, the today implementation and compare the french policy towards the NGV to other countries. (A.L.B.)

  18. A hopeful Quebec gets ready to produce gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Harrison, L.

    2010-06-15

    Quebec's natural gas industry is poised to expand as a result of a breakthrough well drilled in the Utica shale gas play in February 2010. The well has produced more than 12 million cubic feet per day. The Quebec Oil and Gas Association (QOGA) was formed in 2009, and has lobbied the provincial government to keep royalty rates at between 10 to 12.5 per cent. A task force has also been deployed to ensure the development of a prompt regulatory process. It is hoped that increased investment will encourage more drilling activity in the province. Quebec consumes approximately 200 billion cubic feet of natural gas per year. Increased sales are expected to come from new residential construction, where 1 in 5 homes are now being equipped with gas-fired heating. The QOGA is currently designing a training program for potential rig workers. Studies have indicated that gas royalties collected by the provincial government could exceed $1 billion per year in the future. 1 fig.

  19. The natural gas for vehicles; Le gaz naturel pour vehicules

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-11-15

    This document aims to present the trumps of the natural gas for vehicle (NGV). It discusses the particularities, the actions of the government in favor of the NGV by the creation of financial and legal incentives and the challenges. A detail description of the financial and fiscal assistances and the regulation references are given. (A.L.B.)

  20. Improvement of the decay heat removal characteristics of the generation IV gas-cooled fast reactor; Amelioration des caracteristiques de la dissipation de la chaleur de decroissance pour les reacteurs a neutrons rapides de quatrieme generation refroidi au gaz

    Energy Technology Data Exchange (ETDEWEB)

    Epiney, A.S.

    2010-09-07

    comparaisons de benchmark entre les codes, servant a identifier la sensibilite des resultats aux differentes hypotheses considerees dans les modeles. Les parametres trouves dans l'analyse comme etant les plus sensibles, comme par exemple les modeles de transfert de chaleur et de la friction, sont ensuite valides via une re-analyse specifique d'anciennes experiences de boucles a gaz. Ces experiences ont ete effectuees dans les annees 1970 au PSI (EIR a l'epoque). Des conclusions et recommandations concernant les modeles a utiliser pour les calculs de transitoires ont ete obtenues. En general, il a ete montre que les accords entre experiences et les correlations pour le transfert de chaleur et la friction utilisees dans TRACE et CATHARE sont assez satisfaisants. Les codes valides de cette facon sont ensuite utilises dans les deux etudes detaillees d'amelioration du systeme DHR. La premiere amelioration de reference de la strategie DHR est l'injection de gaz lourds. En admettant une defaillance des soufflantes suite a un accident de perte de caloporteur, la pression d'helium dans l'enceinte rapprochee n'est plus assez elevee pour evacuer la chaleur residuelle par convection naturelle. Pour ameliorer la convection naturelle, les effets d'injection de differents gaz lourds (N{sub 2}, CO{sub 2}, Ar et un melange N{sub 2}/He) dans le systeme primaire ont ete analyses. Ainsi la possibilite d'accepter une defaillance des soufflantes tout en ayant une pression intermediaire dans l'enceinte rapprochee a ete consideree. En outre, differents endroits et debits d'injection ont ete analyses ainsi que la sensibilite au nombre de boucles DHR disponibles et a la taille de la breche ont ete adresses. Il a ete trouve que l'injection d'un gaz lourd a proximite du coeur pouvait aboutir a des problemes de surrefroidissement. Pourtant, pour un point d'injection suffisamment loin du coeur, le CO{sub 2} et le N{sub 2} ont ete

  1. Opening up natural gas exploration and production in Mexico, liberalism or nationalism; L'ouverture de l'exploration et de la production de gaz naturel au Mexique, liberalisme ou nationalisme?

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez-Padilla, V. [Universite Nationale Autonome UNAM (Mexico); Cavatorta, T.; Favennec, J.P. [Institut Francais du Petrole (IFP), 92 - Rueil Malmaison (France)

    2002-11-01

    Mexico, which not long ago did not want to call on international oil companies to conduct exploration and production activities in its territory, is changing. After a small opening carried out by President Zedillo (1994-2000), President Vicente Fox wishes to conduct much more radical changes, by opening natural gas fields to major groups. But the President's party is still a minority in Congress, and the majority nationalist party refuses any constitutional amendment allowing the granting of mining rights. Thus, Vicente Fox is considering using special service agreements, known as 'Multiple Service contracts' (CSMs) which would first apply to developing proven gas reserves, and then to areas with greater geological risks, including oil areas. Many major international companies answered the CSM call for bids, as they cannot stay away from a country opening up with as much hydrocarbons, all the more since they feel that legally, such contracts are compliant with the Mexican Constitution and Law. However, they expressed concerns regarding the unbalance of the contracts in terms or risk sharing and profits, saying that such an unbalance put Mexico in a unfavourable position compared with other exporting countries such as Venezuela and Iran. These first CSMs in Cuenca de Burgos between PEMEX and international companies are only a first co-operation step. But a true opening of Mexico request essential institutional reforms that need a majority at Congress. Though Chamber of Representatives elections are scheduled for 2003, Senate elections will not take place before 2006. (authors)

  2. LA LIBÉRALISATION DES MARCHÉS DE L´ÉLECTRICITÉ ET DU GAZ NATUREL AU NIVEAU EUROPÉEN – ENJEUX ET DÉFIS ACTUELS

    Directory of Open Access Journals (Sweden)

    Irina Maria Găman

    2010-06-01

    Full Text Available The creation of an internal energy market at the European level becomes nowadays a sine qua non condition for a single and coherent voice on energy issues at the global level for the EU. One essential step to be done is the liberalization of energy sectors, such as electricity and natural gas. This process of liberalization for the electricity and gas market should have been totally and homogeneously accomplished by the mid of 2007 by the member states of the EU, goal established by the European Commission through two legal instruments, more precisely the Directive 2003/54/EC and the Directive 2003/55/EC. Despite the European legislative settlement and despite the existence of common institutions of regularization, the liberalization has its limits. How these limits can be explained and which are the factors for the heterogeneous degree of liberalization of the electricity and gas markets at the European level? This article is focusing on the specific economic and political factors through which the limits of liberalization of energy markets can be explained.

  3. Draft of law relating to revamping of natural gas supply public service and to development of gas enterprises; Avant projet de loi relatif a la modernisation du service public du gaz naturel et au developpement des entreprises gazieres

    Energy Technology Data Exchange (ETDEWEB)

    Bricq [ed.] [Deputee de Seine-et-Marne, Assemblee Nationale, Paris (France)

    2000-02-07

    The state secretariat for industry has launched a large public debate between June and October 1999 based on a white book titled 'Towards the future organization of the gas sector'. The suggestions obtained were substantial. A brief presentation is added to the draft of the law devoted to revamping of natural gas supply public service and to development of gas enterprises. The presentation addresses the following points: 1. A public gas supply service modern and thought to reconcile the dynamism, equity and solidarity. 2. A controlled opening of the natural gas market towards competition: participating to the struggle for employment. 3. Tools ensuring the quality of gas supply and security of resources. 4. A transparent and efficient regulation: creating the conditions of a nondiscriminatory competition. 5. Requirements for developing the transport of natural gas regime. 6. Storage. 7. Social questions. The draft of the law relating to revamping of natural gas supply public service and to development of gas enterprises is a working document, not engaging the government. It is based on six titles. Title 1 and Title 2 treat the points 1 and 2 mentioned above. Title 3 contains two chapters devoted to transparency and accounting dissociation and to regulation in the natural gas sector, respectively. The Title 4 contains three chapters devoted to: 1. authorization of the works of natural gas transport; 2. gas distribution and 3. exploitation of the transport and natural gas distribution network. The fifth Title is dedicated to underground storage. The sixth Title presents diverse directives.

  4. Development of a cryogenic flexible pipe for the transfer of liquefied natural gas; Mise au point d'un flexible cryogenique pour le transfert du gaz naturel liquefie

    Energy Technology Data Exchange (ETDEWEB)

    Rigaud, J.; Gerez, J.M.; Dieumegard, C. [Coflexip Stena Offshore, 75 - Paris (France)

    2000-07-01

    For historical reasons, the liquefaction of natural gas is performed with onshore equipments and LNG tanker-ships are loaded and unloaded using rigid articulated arms. When these operations are performed in harbors, the movement of the ship with respect to the pier are relatively limited. Today, several companies aim at liquefying natural gas using floating facilities. The loading of tanker-ships is performed offshore, and thus movements between the ship and the floating facility are enhanced. The use of a flexible pipe can be an interesting alternative solution to the articulated arm. This article describes the state-of-the-art of the LNG flexible technology developed by Coflexip Stena Offshore and the progress of the program of development of a cryogenic flexible: structure, fittings, safety (leaks detection), thermal calculations, optimization of the corrugated hose profile, pressure drops, fatigue tests and service life, materials development, prototype and real tests. (J.S.)

  5. Tariff proposal of the Commission of energy regulation from February 28, 2008 for the use of public natural gas distribution networks; Proposition tarifaire de la Commission de regulation de l'energie du 28 fevrier 2008 pour l'utilisation des reseaux publics de distribution de gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    With the complete opening of natural gas markets to competition and the legal separation of distribution networks, Gaz de France Reseau Distribution requested the implementation of a new tariff of use of gas distribution networks to the Commission of energy regulation (CRE). A new tariff of networks utilisation has thus been proposed by CRE after a public consultation and the audition of gas suppliers. This tariff foresees a 5.6% increase of the present day tariff by July 1, 2008. The impact on the end-users' gas retail price will be a 1.5% rise of the regulated tariff. (J.S.)

  6. Structure du marche gazier americain, reglementation et tarification de l'acces des tiers au reseau.

    OpenAIRE

    David, L.; Mirabel, F.

    2000-01-01

    L'ouverture de la concurrence du marche americain du gaz naturel s'accompagne de profondes modifications des reglementations mises en place pour une organisation et un fonctionnement efficace de l'industrie gaziere. L'object principal de notre papier est d'essayer de transcrire les faits stylises du marche du gaz naturel en Amerique du Nord et de modeliser la structure de l'industrie dans ce secteur ouvert en aval a la concurrence (ou en voie de l'etre).

  7. Natural gas news; Gaz actualites

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    1998-12-01

    This brochure is a compilation of practical information concerning the Gaz de France group: organization chart, daughter companies, services, economical activity, natural gas market, trade, regulations etc. A list of partners, directions, centres, groups, associations and other various organisms in relation with Gaz de France company is given. (J.S.)

  8. Law project on the gas utility modernization and gas industries development. Law project synthesis on the gas utility modernization and gas industries development; Projet de loi relatif a la modernisation du service public du gaz naturel et au developpement des entreprises gazieres.Synthese du projet de loi sur la modernisation du service public du gaz et le developpement des entreprises gazieres

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-05-01

    The french government would like to develop a law concerning the gas utility modernization and gas industries development, which completes the today system, more particularly, the law of 1946. This project specifies and comforts the gas utility, it gives to the energy policy tools adapted to the new european context. It helps the natural gas industry to become more competitive. The method chosen by the government is presented and discussed in these three documents. (A.L.B.)

  9. No 3017. Resolution proposal aiming at creating an inquiry commission relative to the project of merger between Gaz de France and Suez, to the conditions of its preparation and announcement and to the consequences of Gaz de France privatization on users and on the energy market balance; N. 3017. Proposition de resolution tendant a la creation d'une commission d'enquete relative au projet de fusion entre Gaz de France et Suez, aux conditions de sa preparation et de son annonce et aux consequences de la privatisation de Gaz de France pour les usagers et l'equilibre du marche de l'energie

    Energy Technology Data Exchange (ETDEWEB)

    Balligand, J.P.; Ayrault, J.M.; Hollande, F.; Besson, E.; Migaud, D.; Emmanuelli, H.; Brottes, F.; Bataille, Ch.; Ducout, P.; Gaubert, J.; Habib, D

    2006-04-15

    On February 25, 2006, the French government took the decision of merging together Gaz de France and Suez energy companies as an answer to Enel's project of takeover bid on Suez. This document wonders about: the real motivations of Gaz de France (the French gas utility) privatization, the possible intervention of public authorities in Enel and Veolia companies project of controlling the Suez group, the governing way of the share-holding government and the preservation of its industrial interests, and the consequences for consumers. Therefore, the creation of a parliamentary inquiry commission is requested to shade light on these different points and to give notice of any bad practices in this affair. (J.S.)

  10. La gazéification souterraine profonde du charbon en France. L'expérience de Bruay-en-Artois Underground Coal Gasification At Great Depth. The French Field Test of Bruay-En-Artois

    Directory of Open Access Journals (Sweden)

    Gadelle C.

    2006-11-01

    Full Text Available Le projet français de gazéification souterraine du charbon, dont l'objectif à terme est la production d'un substitut de gaz naturel, vise la gazéification de veines de charbon de faible épaisseur, situées à grande profondeur et non exploitables par les méthodes classiques. De nombreuses difficultés sont liées à la profondeur (plus de 1000 m, en particulier la nécessité d'opérer sous pression élevée dans un charbon très peu perméable. Les premiers essais, effectués sur un pilote à 1200 m de la surface sur le site de Bruay-en-Artois (nord de la France, ont consisté à :- relier deux puits distants de 65 m par fracturation hydraulique, un test de la liaison par injection d'azote indiquant un taux de récupération du gaz injecté proche de 50 % ; - allumer le charbon au moyen d'un allumeur électrique ; - initier et tenter de propager une combustion à contre-courant avec injection d'air à faible débit. Des expériences de laboratoire, consécutives à cet essai pilote, ont mis en évidence les risques d'allumage spontané du charbon lorsque la pression partielle d'oxygène dans le gaz injecté est élevée. Un nouvel essai de combustion à contre-courant a alors été entrepris sur le site de Bruay-en-Artois, avec injection d'un gaz contenant 5 % d'oxygène et 95 % d'azote. Les résultats de cette expérimentation arrêtée en juillet 1981 sont en cours d'exploitation. The French underground coal gasification (UCG project, which has the objective of producing synthetic natural gas, aims to gasify deep thin coal seams that cannot be mined by conventional methods. Many difficulties are connected with depth (more than 1000 m, in particular the necessity to operate under high pressure in low permeable coal. The initial pilot tests performed at a depth of 1200 m from the surface at Bruay-en-Artois (northern France consisted in: (a linking two boreholes 65 m apart by hydraulic fracturing, a linkage test by nitrogen injection

  11. Risk Analysis of Flare Flame-out Condition in a Gas Process Facility Analyse des risques des conditions d’extinction de torche au sein d’une installation de traitement de gaz

    Directory of Open Access Journals (Sweden)

    Zadakbar O.

    2011-02-01

    Full Text Available Flaring is a common method of disposal of flammable waste gases in the downstream industries. Flare flame out (flame lift-off or blow-outs often occurs causing toxic vapors to discharge. The toxic gases released may have hazardous effects on the surrounding environment. To study the effect of inhalation exposure of these toxic gases on human health, the four steps of the EPA (Environmental Protection Agency framework with the field data to quantify the cancer and non-cancer health risks are integrated in this paper. As a part of exposure assessment, gas dispersion modeling using AERMOD and UDM-PHAST is applied in two different conditions of normal flaring and flare flame out during a particular climate condition in Khangiran region. Recommendations to avoid flare flame out conditions are also presented here. Le torchage est un procédé courant d’élimination des gaz résiduaires inflammables dans les industries de traitement. L’extinction de la torche (par décollage ou soufflage de flamme provoque souvent une émission de vapeurs toxiques. Ces gaz toxiques libérés peuvent présenter des effets dangereux sur le milieu environnant. Pour étudier l’effet d’une exposition par inhalation de ces gaz toxiques sur la santé, cet article croise les quatre étapes de la démarche de l’EPA (Environmental Protection Agency, Agence de protection de l’environnement avec les données d’exploitation afin de quantifier le risque sanitaire cancérologique et non cancérologique. Dans le cadre de l’estimation d’exposition, une modélisation de dispersion des gaz utilisant AERMOD et UDM-PHAST est évaluée dans deux configurations différentes de torchage normal et d’extinction de torche à l’occasion de conditions climatiques particulières dans la région du Khangiran. L’article propose également des recommandations destinées à éviter les conditions d’une extinction de flamme de torche.

  12. Application de la combustion catalytique aux turbines à gaz

    Science.gov (United States)

    Lebas, E.; Martin, G. H.

    2002-04-01

    La réduction des émissions d'oxydes d'azote sur turbines à gaz est obtenue par diminution de la température au sein de la chambre de combustion. Les techniques possibles comprennent l'injection d'eau ou de vapeur, la combustion pauvre et l'oxydation catalytique. Parmi celles-ci, la dernière est la plus prometteuse en terme de coûts et de performances, avec des émissions de NOx ramenées à un seul chiffre (typiquement inférieures à 3 ppm). L'IFP travaille depuis maintenant 10 ans sur l'adaptation de la combustion catalytique aux turbines à gaz. Les études ont été conduites au travers de projets européen tels que AGATA (Advance Gas Turbine for Automotive Application) et ULECAT (Ultra Low CATalytic combustor for dual fuel gas turbine). Le premier projet était destiné au développement de véhicules hybrides et le second à la combustion stationnaire de biogaz et de combustible Diesel. Les études en cours dans ce domaine portent sur le développement d'une unité de cogénération intégrant une microturbine à combustion catalytique. Les travaux menés à l'IFP concernent la mise au point de catalyseurs répondant aux exigences de la combustion catalytique en turbine à gaz et le développement de chambres de combustion permettant la mise en oeuvre de ces catalyseurs.

  13. Project of law relative to the electricity and gas public utilities and to the power and gas companies; Projet de loi relatif au service public de l'electricite et du gaz et aux entreprises electriques et gazieres

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This document is the definitive text of this project of law adopted by the French house of commons. The aim of this law is to allow the administrations to avoid to use their eligibility right with the opening of the electricity and gas markets to competition. It changes the juridical status of the two public utilities Electricite de France (EdF) and Gaz de France (GdF) into two anonymous companies and creates two additional companies for the management of the power and gas networks. It ensures also the transposition of the European directives from June 26, 2003 (2003/54/CE and 2003/55/CE). It contains some proper dispositions and modifies various existing French laws, in particular the law no. 46-628 from April 8, 1946 about the electricity and gas nationalization and the law no. 2000-108 from February 10, 2000 relative to the modernization and development of the electric public utility. (J.S.)

  14. Gaz de France, european leader of the liquefied natural gas (LNG); Gaz de France, leader europeen du gaz naturel liquefie (GNL)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    These five analysis present the activities of Gas De France in the domain of the LNG transportation: technology aspects of the maritime transport, the development of this international market, its place of european leader and two examples of ports for liquid natural gas tankers. (A.L.B.)

  15. Caractérisation des propriétés du gaz naturel

    Science.gov (United States)

    Rahmouni, Camal; Le Corre, Olivier; Tazerout, Mohand

    2003-08-01

    Methane number and Lower Heating Value ( LHV) of natural gas are determined by the online measurement of thermal conductivity at two different temperatures. Natural gas is first considered as a ternary mixture of the most important components. A pseudo-ternary composition can then be calculated, using the thermal conductivity formula for mixtures derived from kinetic theory. A non-linear system is solved numerically using the Newton-Raphson method. A sensor based on thermal conductivity measurement has been developed and tested successfully for many natural gas compositions. To cite this article: C. Rahmouni et al., C. R. Mecanique 331 (2003).

  16. Natural gas supplies; Le point sur l'approvisionnement en gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-10-15

    This article comments data about the share of natural gas in the energy demand in Europe, about the uses of natural gas by different sectors (housing and office buildings, electricity production, and industry) in Europe, and about gas European imports and about gas supply origins. Graphs are displaying the evolution of energy demand in some European countries between 1990 and 2006 and for different energy sources (natural gas, coal, oil, primary energy, and renewable energies), the evolution of gas production and consumption in different countries of the European Union between 1990 and 2006, and gas import origins in the European Union in 2006. Gas pipeline projects between gas producing countries and Europe are briefly presented, and the development of liquefied natural gas is briefly commented and outlined as a contribution to supply diversification.

  17. Energy, petroleum, natural gas, automobiles, environment; Energie, petrole, gaz naturel, automobile, environnement

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    The IFP Group organized, for the eighth consecutive year, its international colloquium Panorama at Paris the 6 february, Lyon the 13 february and Bruxelles (Brussels) the 19 february 2003. The subject was ''the hydrocarbons reserves: abundance or penury?''. The presented allocution bring information on the reserves estimation and petroleum production forecasts, the geographical and political context instability of the energy and the fundamental question of the world resources availability. (A.L.B.)

  18. Energy: solidifying natural gas for storage; Energie: stocker le gaz naturel en le solidifiant

    Energy Technology Data Exchange (ETDEWEB)

    Lepetit, V.

    2003-05-01

    Mitsubishi Heavy Industries and Mitsui Engineering companies (Japan) are carrying out two competitive projects of natural gas solidification for its storage and transport. The principle consists in changing natural gas into solid hydrates which are stable between -15 and +5 deg. C at atmospheric pressure and can be handled easily (1 m{sup 3} of hydrate represents 160 m{sup 3} of gas at the atmospheric pressure). The solidification method is simple: methane bubbles are introduced in a pressure vessel filled with water at a temperature of 3-5 deg. C and under a pressure of 50 bars. The mixture is shacked and the pressure is progressively lowered down to the atmospheric pressure. Flakes of ice-gas mixture occur in the vessel are are subsequently transformed into 20 mm diameter bars of high density more tolerant to temperature changes and more easily transportable. Short paper. (J.S.)

  19. Composite films purify the natural gas; Les films composites purifient le gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Lepetit, V.

    2002-05-01

    American researchers from different universities have developed an ultra-selective polymer membrane made of poly(4-methyl-2-pentyne) (PMP) which can separate methane from the other hydrocarbons (butane and propane) present in the natural gas. This membrane combines the diffusion and the permeability effects to trap the smallest molecules (methane) and to release the biggest ones. The permeability of the membrane has been enhanced by a factor three thanks to the introduction of silica particulates between the polymer chains. Short paper. (J.S.)

  20. Solid natural gas, a resource accessible soon; Le gaz naturel solide, une ressource bientot accessible

    Energy Technology Data Exchange (ETDEWEB)

    Lepetit, V.

    2004-03-01

    The Mallik project, launched by an international consortium of geologists, aims at adapting the classical oil and gas exploration-production methods to the recovery of gas hydrates. The dissociation of gas hydrates (separation between methane and water) is obtained even by the injection of hot water or steam inside the hydrate layer, or by depressurization. The main obstacle remains the identification of rich hydrate deposits (60 to 80% of methane). Short paper. (J.S.)

  1. Liquefied natural gas in full euphoria; Le gaz naturel liquefie en pleine euphorie

    Energy Technology Data Exchange (ETDEWEB)

    Lepetit, V.; Ketels, O

    2007-04-15

    Liquefied natural gas (LNG) is making progress with several projects of terminal facilities and liquefaction plants everywhere in the world. This too fast development leads to an increase of costs and delays in the construction of LNG facilities and at the medium term the offer will become unable to meet the demand. Today, the LNG engineering market is living on the 2005-2006 endorsed projects but the turning point will be 2010 when all main projects will be achieved. (J.S.)

  2. 2002 survey - energy, petroleum, natural gas, automobile, environment; Panorama 2002 - energie, petrole, gaz naturel, automobile, environnement

    Energy Technology Data Exchange (ETDEWEB)

    Giannesini, J.F. [Institut Francais du Petrole (IFP), 92 - Rueil-Malmaison (France); Schweitzer, L.; Fayolle, J.P. [Renault, 92 - Boulogne Billancourt (France); Nejat Veziroglu, T. [Association Hydrogen Energy (Canada); Alleau, Th. [Association Francaise de l' Hydogene, 75 - Paris (France); Gueguen, C. [Totalfinaelf raffinerie de Feyzin, 69 - Lyon (France)

    2002-07-01

    The French institute of petroleum (IFP) has organized its seventh annual international 'Panorama' colloquium on the theme: fuels of the future. This document brings together the different invited talks given in Paris, Lyon and Brussels on this theme: a summary of 2001 highlights in the oil and gas industry given by J.F. Giannesini (IFP head's adviser), a prospective analysis of future automotive fuels with respect to fossil fuel reserves depletion and environmental policy constraints given by L. Schweitzer (president of Renault car making industry), a presentation of the hydrogen and synthetic fuel energy systems of the 21. century by T. Nejat Veziroglu (president of the international association for hydrogen energy), a presentation of the economical, environmental, technical and political aspects of hydrogen as a future energy vector by T. Alleau (president of the French association of hydrogen AFH2), the formulation of future automotive fuels as seen from the eye of the refinery engineer by C. Geguen (technical director of Feyzin refinery (TotalFinaElf)), and a last paper about the recent and future evolutions of diesel engines for industrial vehicles by J.P. Fayolle (director of engines R and D, Renault industrial vehicles). (J.S.)

  3. Study of a method of detection for natural carbon-14 using a liquid scintillator, recent variations in the natural radio-activity due to artificial carbon-14 (1963); Etude d'une methode de detection du carrons 14 naturel, utilisant un scintillateur liquide - variations recentes de l'activite naturelle dues au carbone 14 artificiel (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Leger, C. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-06-15

    Among the various natural isotopes of carbon, a radioactive isotope, carbon-14, is formed by the action of secondary neutrons from cosmic rays on nitrogen in the air. Until 1950, the concentration of this isotope in ordinary carbon underwent weak fluctuations of about 2-3 per cent. The exact measurement of this concentration 6 X 10{sup 12} Ci/gm of carbon, and of its fluctuations, are difficult and in the first part of this report a highly sensitive method is given using a liquid scintillator. Since 1950 this natural activity has shown large fluctuations because of the carbon-14 formed during nuclear explosions, and in the second part, the evolution in France of this specific activity of carbon in the atmosphere and biosphere is examined. In the last part is studied the local increase in carbon activity in the atmosphere around the Saclay site, an increase caused by the carbon-14 given off as C{sup 14}O{sub 2}, by the reactors cooled partially with exterior air. (author) [French] Parmi les differents isotopes naturels du carbone, un isotope radioactif, le carbone 14, est forme par l'action de neutrons secondaires due aux rayons cosmiques sir l'azote de l'air. Jusqu'en 1950, la concentration de cet isotope dans le carbone ordinaire est soumise a des fluctuations de faible amplitude, de l'ordre de 2 a 3 pour cent. Les mesures precises de cette concentration, 6. 10{sup -12} Ci/g de carbone, et de ses fluctuations sont delicates, et dans la premiere partie de ce rapport, on decrit une methode de detection a grande sensibilite utilisant un scintillateur liquide. Depuis 1950, cette activite naturelle subit des fluctuations importantes dues au carbone 14 forme lors des explosions nucleaires, et dans la seconde partie, on examine l'evolution en France de l'activite specifique du carbone de l'atmosphere et ce la biosphere. Dans la derniere partie, on etudie l'accroissement local de l'activite du carbone de l'air aux

  4. Risques naturels en montagne et analyse spatiale

    Directory of Open Access Journals (Sweden)

    Yannick Manche

    1999-06-01

    Full Text Available Le concept de risque repose sur deux notions :l'aléa, qui représente le phénomène physique par son amplitude et sa période retour ;la vulnérabilité, qui représente l'ensemble des biens et des personnes pouvant être touchés par un phénomène naturel.Le risque se définit alors comme le croisement de ces deux notions. Cette vision théorique permet de modéliser indépendamment les aléas et la vulnérabilité.Ce travail s'intéresse essentiellement à la prise en compte de la vulnérabilité dans la gestion des risques naturels. Son évaluation passe obligatoirement par une certaine analyse spatiale qui prend en compte l'occupation humaine et différentes échelles de l'utilisation de l'espace. Mais l'évaluation spatiale, que ce soit des biens et des personnes, ou des effets indirects se heurte à de nombreux problèmes. Il faut estimer l'importance de l'occupation de l'espace. Par ailleurs, le traitement des données implique des changements constants d'échelle pour passer des éléments ponctuels aux surfaces, ce que les systèmes d'information géographique ne gèrent pas parfaitement. La gestion des risques entraîne de fortes contraintes d'urbanisme, la prise en compte de la vulnérabilité permet de mieux comprendre et gérer les contraintes spatiales qu'impliquent les risques naturels. aléa, analyse spatiale, risques naturels, S.I.G., vulnérabilité

  5. Le rôle des facteurs locaux sur les effets des changements climatiques au Quaternaire supérieur sur les environnements naturel du Néguev septentrional

    Directory of Open Access Journals (Sweden)

    Aaron Yair

    2010-10-01

    Full Text Available Les régions sèches sont souvent considérées sensibles aux changements climatiques. Pour ces régions, une relation positive est souvent proposée entre la pluie annuelle moyenne et les données de l'environnement, par des scientifiques appartenant à des disciplines diverses. Cependant les modèles climatiques globaux sont encore incapables de prévoir d'une façon précise l'évolution du climat à l'échelle régionale et ses effets possibles sur l'environnement. De plus, ces modèles sont impuissants à traduire l'influence que des facteurs non climatiques tels que la lithologie et les sols, ainsi que des facteurs biologiques, exercent sur la répartition de l'eau dans l'espace et le temps. En d'autres termes, le même changement climatique régional prévu aura probablement des effets différents dans les secteurs rocheux, lœssiques ou sableux. Le Néguev septentrional offre des conditions très favorables pour l'étude des effets possibles du changement climatique prévu, le long d'un gradient pluviométrique régional où les unités physiographiques varient dans l'espace. Deux cas sont considérés. Le premier traite des effets sur l'environnement du dépôt d'un couvert lœssique lors d'une phase climatique humide au Quaternaire supérieur. Le second examine l'influence de croûtes biologiques de surface sur le régime hydrique d'une zone sableuse le long d'un gradient pluviométrique actuel. Dans les deux cas, le gradient pluviométrique est accompagné par d'autres gradients (géomorphologiques, pédologiques, biologiques. Les données obtenues attirent l'attention sur les relations complexes entre le gradient pluviométrique et les autres gradients, qui peuvent entraîner des effets négatifs sur les ressources hydriques et sur la qualité de l'environnement.Dryland areas are usually regarded as highly sensitive to climate change. A positive relationship between average annual rainfall and environmental variables is often assumed

  6. Pressure Build-up and Decay in Acid Gas Injection Operations in Reefs in the Zama Field, Canada, and Implications for CO2 Storage Variations de pression au cours de l’injection de gaz acides dans le réservoir récifal duchamp de Zama, Canada. Implications pour le stockage géologique de CO2

    Directory of Open Access Journals (Sweden)

    Pooladi-Darvish M.

    2011-03-01

    pressure communication to geological storage of CO2 in aquifers are briefly discussed. Le but de l’article est de comprendre l’accroissement de pression dans le gisement de Zama X2X, utilisé pour le stockage degaz acide (NO de l’Alberta, Canada, et aussi d’examiner si la baisse de pression, observée ultérieurement,est la conséquence d’une dissipation par un aquifère de grande taille. Le gisement de Zama X2X, d’uneextension de 1 km2 environ, est connecté à quatre autres gisements voisins par l’intermédiaire d’un aquifère commun sous-jacent. L’analyse de la pression à travers tous ces gisements indique un bon niveau decommunication hydraulique. La pression initiale de l’accumulation de Zama X2X était d’environ 15 MPa.Pendant la production d’huile, la pression a commencé par décroître, pour se stabiliser vers 10 MPa audébut de la décennie 1970. Mais ensuite la pression a repris son ascension, jusqu’à atteindre 26 MPa en1986. Un nouvel épisode de baisse est alors intervenu et la pression s’est établie vers 22 MPa en 1995,au moment où l’on a commencé à injecter du gaz acide (80 % CO2 et 20 % H2S – l’opérateur, toutefois,injectait ce gaz à des débits et à des pressions en tête de puits qui se situaient en deçà des seuils autoriséspar l’Administration. En dépit d’une production significative d’eau et d’hydrocarbures, la pression à ZamaX2X est ensuite restée plus élevée que la pression vierge, d’au moins 5 MPa, au point qu’en 1998 les opérations d’injection de gaz furent suspendues. La production d’huile a cependant été maintenue jusqu’en 2002. Des simulations numériques effectuées avec CMG-IMEXTM, assorties d’une analyse de sensibilité,montrent ici que la ré-injection de plus de 1 million de m3 d’eau dans le gisement voisin de Zama YY,entre 1970 et 1988 puis en 1992-93, est la principale cause du comportement de la pression à Zama X2X.Les deux champs sont en effet connect

  7. La rapide création du Parc Naturel marin de Mayotte

    OpenAIRE

    Nicolas Legoff

    2012-01-01

    Le second Parc Naturel marin français a été officialisé à Mayotte en janvier 2010. C’est à la fois le résultat d’une procédure rapide et d’une forte détermination politique. Il marque clairement la volonté de la France de gérer un large espace dans le sud-ouest de l’océan Indien même si les moyens d’action restent à déterminer. Au-delà de la protection environnementale, le Parc est perçu comme un outil utile à cette île encore synonyme de sous-développement. De la pêche au tourisme, bien des ...

  8. Gaz de France. Operation note; Gaz de France. Note d'operation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    This note was published for the public at the occasion of the admission to Euronext's Eurolist of the existing shares that make the capital of Gaz de France company, the French gas utility. The note gives some informations about Gaz de France activity, and about its strategy of development in the European gas market. Then it describes the offer relative to the opening of Gaz de France capital. Some selected financial data and some precision about the risk factors and the management of the company complete the document. (J.S.)

  9. Abatement of nitrogen oxides (NO{sub x}) by natural gas re-burning in a 4 MW{sub TH} furnace; Reduction des oxydes d'azote (NO{sub x}) par le reburning au gaz naturel sur un four de 4 MW{sub th}

    Energy Technology Data Exchange (ETDEWEB)

    Sorriau, O.; Delvinquier, V. [Centre d' Etudes et de Recherches sur la Combustion, CERCHAR, Societe Nationale d' Electricite et de Thermique, SNET, 62 - Mazingarbe (France); Czernicki, M.; Pietrzyk, S. [Ecole Nationale Superieure de Chimie de Lille, Lab. de Catalyse de Lille, 59 - Villeneuve d' Ascq (France)

    2001-07-01

    The re-burning process, or mixed staging of the fuel and combustion air, is a method of abatement of NO{sub x} emissions which allows to respect the maximum levels of emissions authorized for the new and existing industrial facilities. It leads to a relatively low investment cost in comparison with the obtained result in terms of NO{sub x} abatement. Moreover, the method is interesting for retrofitting operations too. The basic idea of re-burning is to stage the combustion into three zones: primary, secondary (re-combustion or re-burning) and tertiary (post-combustion or burnout). The efficiency of the process has been tested on a 4 MW{sub TH} gas fueled furnace at the center of studies and researches on combustion (CERCHAR). The variables considered are the stoichiometry and the residence time in the re-burning zone, but also the temperature and the NO{sub x} concentration at the input of this zone. The global abatement of NO{sub x} obtained for a reference flame with 20% of air excess ranges from 20 and 65%, depending on the studied configuration. However, an increase of the CO content of smokes and of unburnt carbon in fly ashes has been observed. Thus, the conditions of gas injection must be optimized in order to maintain a good combustion efficiency. Some gas concentration mapping has been performed in order to find some information about the evolution of gases inside the 3 combustion zones and to find some possible improvements of the process. (J.S.)

  10. An experimental investigation of a lean-burn natural-gas pre-chamber spark ignition engine for cogeneration; Swiss Motor. Modification d'un moteur diesel pour le fonctionnement au gaz naturel en cogeneration. Fonctionnement avec prechambre de combustion

    Energy Technology Data Exchange (ETDEWEB)

    Roethlisberger, R.; Favrat, D.

    2001-07-01

    This thesis presented at the Department of Mechanical Engineering of the Swiss Federal Institute of Technology in Lausanne describes the conversion and testing of a commercial diesel engine for use as a lean-burn, natural gas, pre-chamber, spark ignition engine with a rated power of 150 kW, in combined heat and power (CHP) plants. The objective of the investigations - to evaluate the potential of reducing exhaust gas emissions - is discussed in detail with respect to NO{sub x} and CO emissions. The approach adopted includes both experimental work and numerical simulation. The report describes the testing facilities used. The results obtained with experimental spark-plug configurations based on simulation results are presented and the influence of various pre-chamber configuration variants are discussed. The results of the tests are presented and the significant reduction of NO{sub x}, CO and unburned-hydrocarbon (THC) emissions are discussed. The authors state that the engine, which achieves a fuel efficiency of more than 36.5%, fulfils the Swiss requirements on exhaust gas emissions. Also, ways of compensating for the slight loss in fuel-conversion efficiency in the pre-chamber configuration are discussed.

  11. Chemical and isotopic fractionations of natural gases during their migration. Importance of methane solubilization and diffusion during geological times; Fractionnements chimiques et isotopiques des gaz naturels lors de leur migration. Importance de la solubilisation et de la diffusion du methane au cours des temps geologiques

    Energy Technology Data Exchange (ETDEWEB)

    Pernaton, E.

    1998-09-09

    Two experimental devices have been elaborated in the purpose of simulating in laboratory the solubilization of methane in water and the migration by solubilization/diffusion of some gas species (methane, ethane, propane and nitrogen) through porous media saturated with water. Significant shifts in isotopic ratios of diffused methane (carbon and hydrogen) have been observed. Those fractionations for carbon isotopes, which in most cases are characterised by a {sup 12}C-enriched diffused methane, have fundamental consequences about the interpretation of the origin of methane in sedimentary basins and, in a more general way, about the genetic characterisation of hydrocarbon gases in reservoirs. Indeed, this gives an ambiguous origin for any gas having {sup 12}C-enriched methane, two different interpretations are possible: mixing between thermogenic and bacterial hydrocarbon gases and a diffusive trend during migration. Using a diagram C2/C1 versus {delta}{sup 13}C1, we have shown that in some geological cases, these two processes, mixing and diffusion, exist and that it is possible to discern them.The chemical and isotopic compositions of natural gases do not only reflect genetic processes but are also an indication of their migration. Moreover, the experiments have shown that the gas transport by solubilization/diffusion is a potential operator of gas leakage from natural accumulations. In consequence, a numerical model of gas migration through cap rocks of reservoirs has been elaborated and will be integrated into sedimentary basin models. (author)

  12. Gaz de France. Source document; Gaz de France. Document de base

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This document was issued by Gaz de France, the French gas utility, at the occasion of the opening of the capital of the company. It is intended to shareholders and presents some informations relative to the stocks admitted to Euronext's Eurolist, some general informations about the company and its capital, some informations about the activities of Gaz de France group, about its financial situation and results, about its management, and about its recent evolution and future perspectives. (J.S.)

  13. Visual Investigation of Retrograde Phenomena and Gas Condensate Flow in Porous Media Étude visuelle des phénomènes rétrogrades et de l'écoulement des gaz de condensat en milieux poreux

    Directory of Open Access Journals (Sweden)

    Danesh A.

    2006-11-01

    és avec des mélanges synthétiques d'hydrocarbures gazeux multicomposants, mais aussi avec un condensat naturel provenant de la mer du Nord. Le comportement en écoulement polyphasique des systèmes soumis à l'essai, observé et enregistré en vidéo, est présenté ici, accompagné des données mesurées. En milieu poreux mouillé à l'eau, on a observé que le condensat se forme en film mince continu sur l'eau connée, site préférentiel de condensation. En abaissant la pression au-dessous de la cricondenbar du système, on a provoqué la croissance du condensat presque exclusivement sur les anneaux d'eau à l'entrée des pores et sur les pores aveugles. On a constaté que le condensat passe à travers les films minces même en cas de saturation faible, sans que cela améliore sa récupération. Le rythme de la baisse de pression influence le cisaillement de l'écoulement de gaz et influence fortement, on l'a constaté, la propagation du condensat. Des instabilités localisées pourraient entraîner des mouvements importants du condensat dans certaines zones poreuses, mais en aval les effets capillaires exerceraient une action retardatrice qui diminuerait la récupération du condensat. On ne doit pas penser que les rapports entre la perméabilité relative et la saturation du gaz de condensat prendront la même forme que la perméabilité relative pétrole-gaz dans le cas de récupération par un gaz en solution ou un gaz injecté.

  14. Images et modèles 3D en milieux naturels

    OpenAIRE

    Jaillet, Stéphane; Ployon, Estelle; Villemin, Thierry

    2011-01-01

    Ce numéro 12 de la Collection EDYTEM est à l'image des précédents : un espace ouvert d'expression dédié au croisement de regards scientifiques. L'accent est ici mis sur les méthodes dédiées aux représentations 3D des milieux naturels afin d'en extraire les données nécessaires aux recherches aussi bien en géosciences, en sciences de l'environnement, qu'en sciences humaines et sociales. Ce numéro recueille plus de vingt articles consacrés à l'imagerie et à la modélisation 3D. Ce volume s'ouvre ...

  15. Gaz de France annual report 2003; Gaz de France rapport annuel 2003

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    Today, Gaz de France Group ranks as one of the largest gas utilities in Europe. This success is the fruit of a growth strategy that fuses economic, social and environmental imperatives. To respond more efficiently to fluctuations in the natural gas market and continue to expand its range of competitive products and services, Gaz de France has committed to integrated development across the full spectrum of natural gas activities, from exploration and production to the sale of energy and related services. As the leading supplier of natural gas in France, Gaz de France has honed a targeted policy to acquire equity interests and assets, mainly in Europe, assuring the Group of a privileged place at the heart of the European gas grid. As European energy markets continue to open more widely to competition, the Group intends to benefit from its presence in all the sectors of the natural gas industry and in the European market to confirm its position as an integrated energy operator, focused on gas, among Europe's leaders. To achieve this goal, Gaz de France will concentrate in a balanced fashion on activities linked to infrastructures and activities related to energy supply and services. While assuming its public service responsibilities, the Group will expand the range of products and services to customers. This activity report presents: consolidated financial highlights, profile, corporate governance, Gaz de France's ambition, panorama of activities: energy supply and services (exploration - production, purchase and sale of energy, services), infrastructures (transmission and storage - France, distribution - France, transmission and distribution - international), Commitments of Gaz de France (human resources, research and development, sustainable development, map of main subsidiaries and affiliates)

  16. Geochemical Study of Natural CO2 Emissions in the French Massif Central: How to Predict Origin, Processes and Evolution of CO2 Leakage Étude géochimique des émissions naturelles de CO2 du Massif Central : origine et processus de migration du gaz

    Directory of Open Access Journals (Sweden)

    Battani A.

    2010-05-01

    de surveillance des futurs sites de stockage de CO2. Au cours des campagnes de terrain, nous avons analysé des flux de CO2 entre le sol et l’atmosphère, et nous avons prélevé et analysé à la fois des gaz des sols, et du gaz provenant de sources carbo-gazeuses, présentes dans toute la région. Un dispositif de « monitoring continu » dans le temps a également été testé, afin d’enregistrer conjointement les teneurs en CO2 de l’atmosphère et dans le sol en un point précis. Nous avons pu mettre au point un suivi géochimique basé sur la composition isotopique des gaz rares prélevés dans les sols. L’ensemble de nos résultats, confronté à la géologie de terrain, nous a permis de mettre en évidence l’origine mantellique du CO2. Ce CO2 remonte rapidement à la surface à l’état gazeux, le long de failles normales et/ou décrochantes, actives actuellement. Les teneurs et flux de CO2 dans le sol sont spatialement variables et élevés, et montrent également une origine mantellique. Les teneurs atmosphériques semblent faiblement augmenter par rapport à l’important dégazage observé dans la région.

  17. La gouvernance des risques naturels et la problematique des ...

    African Journals Online (AJOL)

    Depuis quelques années, la gouvernance des risques naturels dus aux inondations remet en cause les processus de mise en oeuvre des politiques urbaines et la qualité de la structure des aménagements dans les grandes villes du Golfe de Guinée. La perception de la gouvernance et l'application des politiques de ...

  18. A natural gas filling station for cars at home; Faire le plein de gaz naturel carburant chez soi

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    This short article is devoted to the possibilities the 7500 owners of natural gas driven cars have to refill the gas storage tank in Switzerland. 105 public filling stations are available in the country. The market share of cars that can be fueled both by gasoline and natural gas is much lower in Switzerland than in Italy or Germany. One way of promoting this kind of environmentally more friendly vehicles - compared to gasoline or diesel fueled cars - has been created by a gas company that rents small gas refill stations for installation in private homes. The article describes such automatic gas stations. It is stated that they are absolutely safe and easy to use. One advantage of fueling cars by natural gas is a significant reduction on the fuel levy, in accordance with the air pollution abatement obtained by this type of fueling.

  19. The natural gas in the world. The 2010 edition; Le gaz naturel dans le monde. Edition 2010

    Energy Technology Data Exchange (ETDEWEB)

    Lecarpentier, A.; Favreau, D. [Cedigaz, 75 - Paris (France)

    2010-11-15

    In this work are described at first the tendency of the production and of the external trade of natural gas in 2010. The second part deals with the medium term market outlook of the gas industry. At last, the non conventional gases in the world are presented. (O.M.)

  20. Influence de la microporosité sur le piégeage du gaz dans un milieu poreux naturel

    Science.gov (United States)

    Suzanne, Karine; Billiotte, Joël

    2004-09-01

    Trapped-gas content in natural porous media, also called residual gas saturation ( Sgr), corresponds to the imbibition end-point. To define the parameters controlling Sgr, two parameters were studied: the influence of rock characteristics (on 400 sandstone samples) and initial gas saturation ( Sgi), on the basis of 60 experimental curves between Sgr and Sgi. Based on an extensive experimental database, this study establishes the dominant influence of microporosity on trapped gas saturation, and indirectly that of the contained clays. To cite this article: K. Suzanne, J. Billiotte, C. R. Geoscience 336 (2004).

  1. Liberalization of natural gas supply prices in Spain; La liberation des prix de fourniture de gaz naturel en Espagne

    Energy Technology Data Exchange (ETDEWEB)

    Rasines, L.A. [Faculte de Sciences Economiques et de l' Entreprise de l' UNED, Madrid (Spain)

    2009-05-15

    This paper constitutes a follow-up to the one published in this journal in 2004 (no. 562). In this update we describe the new regulations introduced in the Spanish natural gas sector and analyse the behaviour of the market since then. From this study we can deduce that the liberalization of the Spanish natural gas market has led to an oligopoly of suppliers of natural gas. As the Government has liberalized final prices of natural gas, distributors have been able to increase the margin between final prices and the average import price paid for this gas. (author)

  2. Annual survey of the natural gas market: 2010 results; Enquete annuelle sur le marche du gaz naturel: resultats 2010

    Energy Technology Data Exchange (ETDEWEB)

    Welter-Nicol, Cecile

    2011-12-15

    This document presents and briefly comments the main data of the natural gas market in France in 2010: gas production (only 2 pc of supplies), gas transit evolutions since 2007 (entry points receiving gas from various origins and export points to Spain and Switzerland), outlines the increase of imports from Norway, comments gas storage capacities, the evolution of gas distribution in France, the evolution of gas consumption, and gas sales in the different French regions and to different kinds of customers or industries

  3. Natural gas integration in latin america: forward or backwards?; Integration du gaz naturel en Amerique Latine: avance ou recul?

    Energy Technology Data Exchange (ETDEWEB)

    Moutinho Dos Santos, E.; Oxilia Davalos, V.E.; Tadeu Werneck Faga, M. [Sao Paulo Univ., Graduate Energy Program, SP (Brazil)

    2006-05-15

    Throughout the 1990's to Year 2000, energy integration, and particularly natural gas integration, was seen as a major goal in the Southern Cone of South America, The regional perspective for energy was related to an even more challenging objective - Latin American economic integration, which was quickly moving forward by the constitution of MERCOSUR, the free trade zone built by Argentina, Brazil, Uruguay and Paraguay, and also having Bolivia and Chile as special partners. MERCOSUR was getting stronger and becoming a successful political project. Trade conflicts existed, but they were considered normal and nobody would disagree about the viability of MERCOSUR. By the beginning of the 21. Century, the economic integration process in South America was already advancing timidly as compared to the impetus from the beginning of 1990's. MERCOSUR started facing complex and almost insurmountable challenges after the numerous global financial crises (from 1998 to 2003) which had affected the economic balances in the region. Energy and gas integration in South America has equally lost perspective as fast as the importance of economic integration has declined. The economic crises in the region and poor energy policies have discouraged energy companies to invest. The paper presents this recent history of rising and falling in the concept of economic and energy integration in the Southern Cone of South America. Despite the abundance of energy resources, and particularly the plethora of recently discovered natural gas, the region has been experiencing systematic and important energy shortages, which may threaten its economic recovery. A stronger energy integration policy would help all the partner countries to reduce energy supply risks. Yet, energy (and gas) integration in the Southern Cone is still a complex long-term political project, which must involve all countries, but whose future perspective is unclear. It seems almost impossible to keep pushing forward this project without revitalizing the former communitarian and regional perception of the world that had led to the creation of MYIERCOSUR. The idea of energy or gas integration alone can hardly survive without the strong umbrella of a sustainable and wider economic integration policy. South American countries need a new initiative to restart the debate about such vital regional integration. (authors)

  4. The possibilities of the natural gas for vehicles (NGV); Le gaz naturel pour vehicules (GNV): quel potentiel?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-11-15

    The transportation sector is today responsible of about 35% of the CO{sub 2} emissions. If the biofuels can replace 10 at 15% of the petroleum fuels, they will not completely substitute for the petroleum. The natural gas for vehicles (NGV) seems to be particularly interesting. The gas reserves are important and well geographically distributed. Its use is compatible with the new engines technologies. Meanwhile, in France, the distribution and the vehicle are too little. This study aims to know if the natural gas for vehicle utilization allows substantial profits in term of CO{sub 2} emission. (A.L.B.)

  5. The natural gas storage in France and in Europe; Le stockage de gaz naturel en France et en Europe

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-02-15

    The natural gas storages play a great role in the gas supplying security. They allow to compensate for the variations of the supply and demand. This document presents the different natural gas storage technic: in the phreatic cave, in salt hollows, in abandoned deposits and the natural liquefied gas. It includes also a map of the natural gas storage situation in France. (A.L.B.)

  6. Natural gas in France: main results in 2008; Gaz naturel en France: les principaux resultats en 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    This document briefly presents and comments the main data about natural gas in France: gas consumption, natural gas-based electricity production, refineries, energetic final consumption of natural gas, non-energetic final consumption of natural gas, gas imports and suppliers (countries), national production, and stocks.

  7. Solubility of natural gases in water under high pressure; Solubilite des gaz naturels dans l`eau a pression elevee

    Energy Technology Data Exchange (ETDEWEB)

    Dhima, A.

    1998-10-08

    Under high pressure (up to 1200 bar) and high temperature (up to 200 deg C) petroleum reservoir conditions the hydrocarbon-water mutual solubilities may become important. Under such conditions, the prediction of hydrocarbon water solubilities is a challenge for petroleum engineers. Indeed, very few studies have been done ar pressures higher that 700 bars. New solubility data for methane, ethane, n-butane, CO{sub 2} and their mixtures in pure water were obtained at 344.25 K and from 2.5 to 100 MPa. The results agree very well with those of the literature in the case of pure hydrocarbons in water, but differ for the hydrocarbon mixtures. A rigorous thermodynamic analysis allows the elaboration of a model that combines a cubic equation of state (Peng-Robinson with k{sub ij} given in literature) with the Henry`s law approach. The (P,T) functional form of Henry`s constant is given by the Krichevsky-Kasarnovsky equation which involves two important parameters: partial molar volume at infinite dilution and Henry`s constant at the vapour pressure of water. For a given solute both parameters are only functions of temperature. A critical selection of binary solubility data for a large number of solutes has been used as a basis for a new correlation for calculating both this partial molar volume and the corresponding Henry`s constants as a function of temperature. (author) 169 refs.

  8. New regulations, combustion, environment: responses for natural gas; Nouvelles reglementations, combustion, environnement: les reponses pour le gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Le Peltier-Marc, A. [Gaz de France (GDF), 75 - Paris (France). Direction Commerciale

    1997-12-31

    The impacts of the new French regulations concerning low- to medium-power combustion equipment with regards to their energy sources, energy efficiency and pollution control, on natural gas fired boilers, are discussed: lower pollutant emission limits are set for SO{sub 2}, NO{sub x} and ashes. The decree gives new regulations concerning plant location, combustion control systems, plant monitoring and maintenance, and air pollution control measures such as chimney stack height and emission limits. The French national gas utility promotes environmental high performance boilers

  9. Controlling processes that are sensitive to natural gas quality; Procedes de controle sensibles a la qualite du gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Wild, K.R. [BG Technology Ltd (United Kingdom)

    2000-07-01

    In the UK, and in many other countries throughout the world, the quality of natural gas supplied to customers is maintained to a safe specification. Nevertheless, the specification usually allows some variation in the calorific value of the gas. For a small number of industrial or commercial consumers, this variation can present some difficulties. Measurement of these small, and sometimes rapid, changes is required to allow suitable control systems to be implemented. In the past, the measurement of gas quality has been either inadequate for accurate control or too expensive. BG Technology has developed an acceptable cost solution to this long-standing problem. This paper describes how this novel technology presents exciting new opportunities for gas combustion control and other applications. (author)

  10. Gaz de France annual report 2001; Gaz de France rapport annuel 2001

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    One of Europe's leading gas utilities, the Gaz de France Group operates in all sectors of the natural gas industry, from exploration and production to energy distribution and services, to respond to customer demand efficiently and achieve sustained and profitable growth. To this end, the Group is organized in five lines of business: exploration and production, supply and trading, transmission, distribution and services. Active in 33 countries, the Gaz de France Group first targets growth in Europe, its natural environment. The opening of energy markets and its position at the center of Europe's gas grids offers the Group many opportunities in trading, transmission for third parties, distribution and services. Since August 10, 2000, Gaz de France has made it possible for other gas operators to access its transmission system. The Group capitalizes on its expertise at the global level as well, in emerging markets like Mexico and in fields in which it has recognized know-how, such as liquefied natural gas (LNG). To ensure this growth and pursue its penetration of European and world markets, the Gaz de France Group implements a policy of cooperation and partnership with other energy sector operators, demonstrates its well-developed ability to innovate and practices a customer-focused organization that offers competitive, tailored services to residential users, companies and local governments. The Group has chosen to pursue this growth through a strategy of sustainable development. By making natural gas more accessible and promoting its uses, Gaz de France integrates demand-side management of energy, fosters human development and ensures environmental protection in France, Europe and the world. This activity report presents: the corporate profile of the group, the international natural gas businesses, the financial highlights, the growth objectives of the group in all its businesses (exploration and production, supply and trading, transmission, distribution

  11. La rapide création du Parc Naturel marin de Mayotte

    Directory of Open Access Journals (Sweden)

    Nicolas Legoff

    2010-04-01

    Full Text Available Le second Parc Naturel marin français a été officialisé à Mayotte en janvier 2010. C’est à la fois le résultat d’une procédure rapide et d’une forte détermination politique. Il marque clairement la volonté de la France de gérer un large espace dans le sud-ouest de l’océan Indien même si les moyens d’action restent à déterminer. Au-delà de la protection environnementale, le Parc est perçu comme un outil utile à cette île encore synonyme de sous-développement. De la pêche au tourisme, bien des activités espèrent tirer profit de la dynamique enclenchée.The 2nd french Marine Protected Area was officially created in Mayotte in January 2010, thanks both to a swift procedure and to a strong determined policy. It clearly shows the will of France to manage a broad area in south-west of the Indian Ocean even if its means of action are still to settle. Beyond environemental protection, the park is seen as a useful tool for an island still considered as emergent. From fishing to tourism, many activities hope to take advantage from the dynamic set in motion.

  12. Activite locomotrice de souris isolees, de deux lignees consanguines, dans un environnement semi-naturel ou en cages d'elevage.

    Science.gov (United States)

    Le Pape, G; Lassalle, J M

    1979-10-01

    Des enregistrements continus d'activité locomotrice ont été effectués sur des souris mâles isolées des lignées Balb/c et C57bl/6, vivant en cages d'élevage ou en milieu semi- naturel. Les résultats montrent que les différences entre ces deux situations ne sont pas perçues de la même façon par les animaux des deux lign'ees: alors qu'en cages d'élevage les souris des deux lignées experiment la même quantité totale d'activaté, en milieu semi-naturel les souris Balb/c sont plus actives que les C57bl/6. En outre, l≐s différences observées entre les lignées pour la repartition de l'activité au cours du nycthèmere s'inversent lorsque l'on passe d'une situation à l'autre. L'étude de la variabilité fait aparaître une dispersion plus grande des performances dans la lignée C57bl/6 en cages d'élevage, alors qu'en milieu semi-naturel la dispersion est plus chez Bal/c. Copyright © 1979. Published by Elsevier B.V.

  13. Postface : La gestion des risques naturels est une dynamique

    NARCIS (Netherlands)

    Jaboyedoff, M.; Charriere, M.K.M.; Derron, M.H.; Nicolet, P.; Sudmeier-Rieux, K.

    2013-01-01

    Les risques sont contrôlés par de nombreux facteurs dont, en premier lieu, les dangers, exprimés par leur fréquence (aléa) à une intensité donnée, mais aussi relativement à un fonctionnement de la société. La gestion des risques, liés aux dangers naturels, implique de les évaluer, en premier lieu,

  14. Etat d'avancement d'un nouveau type de réfrigérateur : le tube a gaz pulsé

    Science.gov (United States)

    David, Marc; Maréchal, Jean-Claude

    1991-02-01

    We describe the state of the art of pulse tube refrigerator. Experiments have been performed showing that the heat exchanges between the gas and the walls are more important in the basic pulse tube than in the orifice pulse tube. We show that the ratio R/δ determines the amount of heat exchanges. Then, we subsequently describe the pulse tube operation with emphasis on gas to gas heat exchanges. We show qualitatively that heat exchanges separate from hot and cold heat exchangers, must exist. L'article fait le point sur le tube à gaz pulsé. Nous avons réalisé des expériences qui nous ont permis de montrer que les échanges de chaleur entre le gaz et la paroi du tube sont plus efficaces dans un tube fermé que dans un tube avec orifice. Nous montrons que le rapport R/δ caractérise correctement ces échanges de chaleur. Nous rappelons ensuite le concept des échanges gaz-gaz et montrons qualitativement qu'il doit exister d'autres échanges de chaleur que ceux existant au niveau des échangeurs chaud et froid. Enfin l'article décrit le système à un étage qui nous a permis d'atteindre une température de 70 K avec une puissance de 4 W à 85 K.

  15. Formation and evolution of aerosols in filtered air and in natural air. Effect of radioactivity; Formation et evolution des aerosols dans l'air filtre et dans l'air naturel action de la radioactivite

    Energy Technology Data Exchange (ETDEWEB)

    Madelaine, G.J. [Commissariat a l' Energie Atomique, 92 - Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-06-01

    Results are presented concerning the formation, the evolution, the coagulation and the electrical charge of aerosols which form in natural filtered air containing only gaseous impurities, under the influence of solar light (photolysis) and of radioactive disintegrations (radiolysis). The modifications brought about in the aerosol by an increase in the sulphur dioxide content and in the natural radioactive gas content are studied. The work is then repeated with non-filtered natural atmospheric air. A comparison is also made of the behaviour of non-radioactive and radioactive particles (active thoron deposit). In conclusion, the possible consequences of these phenomena on the origin and the size distribution of particles occurring in the atmosphere is considered. (author) [French] On expose les resultats obtenus sur la formation, l'evolution, la coagulation et la charge electrique des aerosols qui se forment dans l'air naturel filtre, ne contenant que des impuretes gazeuses, sous l'influence de la lumiere solaire (photolyse) et des desintegrations radioactives (radiolyse). On examine les modifications apportees a l'aerosol forme par l'augmentation de la teneur de l'air en anhydride sulfureux et en gaz radioactif naturel. Cette etude est ensuite reprise mais avec de l'air naturel atmospherique non filtre. On compare egalement le comportement des particules non radioactives et radioactives (depot actif du thoron). En conclusion, on examine les consequences que peuvent avoir ces phenomenes sur l'origine et la granulometrie des particules contenues dans l'atmosphere. (auteur)

  16. Canyoning et gestion de l’espace naturel.

    Directory of Open Access Journals (Sweden)

    Clémence Perrin-Malterre

    2009-09-01

    Full Text Available L’objectif de cette étude est de comprendre comment est organisée l’activité canyoning dans les parcs naturels régionaux du Vercors et du massif des Bauges. Pour analyser cette organisation, les concepts développés par Friedberg pour l’analyse de l’action organisée sont utilisés. Il s’agit également de s’interroger sur la pertinence du cadre théorique choisi. Les résultats mettent en évidence que les différents contextes d’action ne sont pas « organisés » de la même manière. Il y a une coexistence de systèmes plus ou moins structurés en fonction des problèmes posés et des acteurs en présence. La gestion d’un sport de nature est donc complexe : si au départ elle relève du privé, elle peut basculer vers une gestion publique ou gestion mixte plus ou moins aboutie. Par ailleurs, nous avons montré que si le cadre théorique de Friedberg permet une analyse fine du degré d’organisation de chaque contexte d’action, il trouve ses limites lorsqu’il s’agit d’analyser la manière dont ces contextes s’articulent entre eux. On se trouve alors confronté aux limites d’une approche théorique qui pose le focus sur un ordre local relié à un unique problème alors que les sports de nature ne sont pas réductibles à cela en ce qui concerne leur gestion. The goal of this study is to understand how the canyoneering activity is organized in the regional natural parks of Vercors and of the massif of Bauges. To analyze this organization, the concepts developed by Friedberg for the analysis of organized action are used. We also want to question the relevance of the theory. Results highlight that the various contexts of action are not organized in the same way. There is a coexistence of more or less structured systems, according to the problems and actors involved. The management of a sport of nature is complex: private at the beginning, it may slide toward public administration or mixed management. In

  17. The public safety and Gaz de France; La securite du public et Gaz de France

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    In the framework of its utilities missions, Gaz de France has to assure the public safety and the continuity of the gas supply chain. To avoid accidents and help victims of accidents, Gas de France implemented a system of financial assistance but also a preventive action to verify the installations. The first part of the document presents the liabilities of Gas de France, the second part deals with the voluntarist approach of Gas de france towards the public safety. (A.L.B.)

  18. Evolution dans la gestion de la détection gaz

    CERN Document Server

    Bonthond, F

    1999-01-01

    Cet article présente l'interface graphique qui a été développée pour gérer d'une façon visuelle et globale la détection des gaz inflammables utilisés dans les expériences du hall EHN1 (NA49, NA56, tests pour ATLAS, CMS, Alice, etc.). A cet effet, on utilise des détecteurs catalytiques connectés à une centrale. Afin de retransmettre les alarmes à la salle de contrôle des pompiers, cette centrale est couplée à un automate programmable connecté au réseau Ethernet du CERN. Une liaison filaire entre l'automate et le synoptique câblé des alarmes de niveau 3 assure la redondance nécessaire à ce type d'alarmes. Le logiciel de contrôle LabView a été utilisé pour développer l'interface graphique. Elle permet de visualiser sur n'importe quel PC ou X-Terminal le taux de remplissage des bouteilles de gaz, la position des électrovannes ainsi que les asservissements qui pilotent lors d'une alarme, notamment les ventilations, les panneaux de signalisation et les arrêts d'urgence.

  19. Dévalaison et survie d'alevins de saumon atlantique (Salmo salar L. en milieu semi-naturel contrôlé

    Directory of Open Access Journals (Sweden)

    BEALL E.

    1983-04-01

    Full Text Available Dans un chenal artificiel expérimental, des œufs de saumon atlantique (Salmo salar L. ont été pondus naturellement ou ont été enfouis au stade embryonné. A la fin de la résorption de la vésicule, une fraction importante des alevins survivants dévale de la zone de frayère. La dévalaison semble stimulée par des baisses de niveau ou des hausses de température et ralentie en période de pleine lune. D'autres facteurs pouvant être responsables de cette dévalaison sont discutés. La survie jusqu'à la collecte de tous les alevins est estimée à 74 p. 100 pour les sujets issus de la reproduction naturelle et est égale à 80 p. 100 pour ceux issus d'œufs introduits dans le gravier au stade embryonné. Des comparaisons entre ces résultats et ceux obtenus dans d'autres chenaux de fraie ou en milieu naturel montrent la validité de cette méthode pour la production d'alevins de saumon atlantique destinés au repeuplement.

  20. Gaz de France 2006 sustainable development report; Gaz de France 2006 rapport developpement durable

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    A major European energy utility, the Gaz de France Group produces, purchases, transports, distributes and sells natural gas, electricity and related services for its residential, corporate and local government customers. this report presents the actions implemented by the group to incorporate sustainable development into its strategy. From the point of view of risks and opportunities, the group analyzes what it takes to ensure development that respects people and the environment, and it implements them in all its business lines and management systems. Content: Gaz de France, portrait of a major energy utility, highlights of 2006, challenges and strategy (defining strategy and sustainable development policy, specific risks and opportunities, activities of the Gaz de France group: challenges, impact for stakeholders, transparency and independence in governing), ranking and implementing (defining sustainable development policy: reviewing priorities, meeting all the challenges, publicizing and defending positions, increasing awareness, overseeing and monitoring results), results of the 2004-2006 sustainable development action plan, dialogue and action with stakeholders, performance assessment, performance in response to challenges: energy challenges (guaranteeing regular supplies, controlling atmospheric emissions, promoting energy conservation, developing renewable energy), industrial challenges (ensuring health and safety, limiting the overall environmental impact of group activities), social responsibility challenges (advocating corporate social responsibility, promoting human rights and fighting corruption, encouraging commitment to solidarity, promoting regional development through local initiatives, reconciling acquisitions, procurement and sustainable development, ensuring transparency in natural gas rates, providing shareholders with quality information, promoting diversity, a source of enrichment, making working conditions a performance factor), indicators and

  1. Gaz de France annual report 2000; Gaz de France rapport annuel 2000

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    A leader in the natural gas market in Europe, Gaz de France is an integrated group active in all sectors of the natural gas industry. In exploration and production, trading of natural gas, transmission, storage, distribution, energy management, air conditioning and heating, the Group has developed recognized skills and know-how both upstream and down to assure its customers of diversified, efficient and competitive services. A leader in liquefied natural gas, storage and distribution technologies, the Gaz de France Group has strong positions in Europe and operates throughout the world by promoting a strategy of alliances and partnerships at all levels of the gas industry. The goal of the Gaz de France Group is to continue to expand and develop its activities from the wellhead to the burner tip, and to seize, in France and throughout the world, the best opportunities offered to capitalize on its strengths. This activity report presents: the corporate profile, the financial highlights, the principal subsidiaries and affiliates, the major European trunk lines the responsive, customer-focused services (exploration-production, trading, transmission, distribution, services), the actions to ensure performance (productive research, comprehensive quality assurance, mobilized workforce ready for the opening of the markets)

  2. Şeyl Gazı (Kaya Gazı ve Çevresel Etkileri

    Directory of Open Access Journals (Sweden)

    Nazan YALCIN ERİK

    2016-11-01

    Full Text Available Özet. Son yıllarda şeyl formasyonlarından doğal gaz üretimi (şeyl gaz karadaki hidrokarbon (petrol ve gaz arama ve üretimlerindeki en hızlı gelişen eğilimdir. Şeyl gaz operasyonlarında teknolojik gelişmeler özellikle Amerika’da son birkaç yılda daha da hızlanmış ve bu süreç küresel olarak ilerlemeye devam etmektedir. Petrol ve gaz sektöründeki yeni gelişmeler çevre ve sosyo-ekonomik alanda, özellikle de doğal gaz gelişiminin yeni olduğu alanlarda birçok değişimi de beraberinde getirmiştir. Şeyl gaz ile ilgili çevresel etkiler küresel ve yerel düzeylerde etkili olmaktadır. Bunlar iklim değişikliği, sera gazı (GHG emisyonları, yerel hava kalitesi, su temini, su kalitesi, sismik aktivite, yerleşim yeri ve toplumsal etkilerdir. Yoğun kuyu aralıkları, operasyonlardan dolayı oluşan gürültü, artan kamyon trafiği halk ve çevre için düşünülmesi gereken diğer konuları oluşturmaktadır. Bazı çevresel etkiler ise yeni teknolojik gelişmeleri kullanarak azaltılmıştır. Örneğin, şeyl gazı üretimi sırasındaki sera gazları azaltılmaya başlanmış ve tatlı su ihtiyacı ise operasyonda kullanılan suyun arıtılması ve yeniden kullanılmasının yaygınlaşması sonucunda azalmaya başlamıştır. Sismik aktivitenin önlenmesi gibi diğer konular ise hala detaylı inceleme ve araştırmaya ihtiyaç duymaktadır. Anahtar Kelimeler: Şeyl gazı, hidrokarbon, çevre kirliliği, sera gazı, doğal gaz, su kirliliği Abstract. In recent years, natural gas production from shale formations (shale gas is one of the most rapidly expanding trends in onshore hydrocarbon (oil and gas exploration and production. Especially in the United States the development of technology within shale gas operations has been rapid within the last few years and is still ongoing globally. New developments about oil and gas sector create change to the environmental and socio-economic view, particularly in those

  3. Gaz de France and the sustainable development in 2005; Gaz de France et le developpement durable en 2005

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    This booklet provides information on the Gaz de France group involvement in the sustainable development: the stakes, the approach, the energy challenge answers, the security and the solidarity and the active part in the territories development. (A.L.B.)

  4. Synthesis Gas Purification Purification des gaz de synthèse

    Directory of Open Access Journals (Sweden)

    Chiche D.

    2013-10-01

    ce faire, une étape de gazéification convertit la charge carbonée en un gaz de synthèse (mélange de CO et H2, lequel, après ajustement du ratio H2/CO et élimination du CO2, subit ensuite la réaction de FischerTropsch. Les gaz de synthèse contiennent cependant de nombreuses impuretés qui nécessitent d’être éliminées afin d’éviter l’empoisonnement des catalyseurs Fischer-Tropsch. En raison de la grande variété de charges pouvant être mises en oeuvre, la composition des gaz de synthèse est susceptible de subir d’importantes variations, en particulier de part la nature des impuretés (éléments, spéciation présentes ainsi que leurs teneurs relatives. La composition des gaz de synthèse est également soumise à des spécifications extrêmement sévères en terme de pureté liées à l’importante sensibilité aux poisons des catalyseurs FT. Pour ces raisons, la purification des gaz de synthèse constitue un défi majeur pour le développement des procédés B-XTL. Dans cet article, nous présentons les principaux enjeux liés à la purification des gaz de synthèse. Les différents types d’impuretés pouvant être présentes dans les gaz de synthèse sont présentées. L’influence de la nature de la charge, des technologies de gazéification ainsi que des conditions opératoires associées sur la nature des impuretés et leurs teneurs relatives est discutée. Une attention particulière est portée au devenir des composés soufrés, azotés, des halogènes, métaux lourds et métaux de transition. Les principales technologies de purification des gaz de synthèse (adsorption, absorption, réactions catalytiques, etc. sont finalement décrites, ainsi que les défis associés.

  5. Law no. 2004-803 from August 9, 2004 relative to electricity and gas public utilities and to the power and gas companies; Loi no. 2004-803 du 9 aout 2004 relative au service public de l'electricite et du gaz et aux entreprises electriques et gazieres

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-09-01

    The aim of this law is to allow the administrations to avoid to use their eligibility right with the opening of the electricity and gas markets to competition. It changes the juridical status of the two public utilities Electricite de France (EdF) and Gaz de France (GdF) into two anonymous companies and creates two additional companies for the management of the power and gas networks. It ensures also the transposition of the European directives from June 26, 2003 (2003/54/CE and 2003/55/CE). It contains some proper dispositions and modifies various existing French laws, in particular the law no. 46-628 from April 8, 1946 about the electricity and gas nationalization and the law no. 2000-108 from February 10, 2000 relative to the modernization and development of the electric public utility. (J.S.)

  6. The Gas Congress; Congres du gaz

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    This document is published before a congress which will address the struggle against climate change, the security of the gas supply chain, the responses of energy groups to environmental and economic challenges, the opening of the gas market, the European energy policy, the future role of gas in the third industrial revolution, and the security of gas supplies. After an introduction briefly discussing these issues and the impacts of the French 'Grenelle de l'Environnement' and the struggle against climate change for gas production and consumption, several interviews are proposed with actors belonging to the AFG (Association Francaise du Gaz), ADEME, European Commission, Total, GDF Suez, other professional bodies, or local communities

  7. Impact environnemental d'une désulfuration poussée des gazoles Environmental Impact of Gaz Oil Desulfurization

    Directory of Open Access Journals (Sweden)

    Armengol C.

    2006-11-01

    Full Text Available En une dizaine d'années, le diesel a connu un développement spectaculaire sur les marchés automobile français et européen et pourrait atteindre, en 1995, la moitié des immatriculations de véhicules particuliers en France et le quart en Europe de l'Ouest. Cette situation n'est évidemment pas sans poser de problèmes. Problèmes environnementaux puisque le moteur diesel est une source plus importante d'émissions d'oxydes d'azote et de particules que le convertisseur essence, mais également au niveau de l'industrie du raffinage qui, en France, n'est plus en mesure de satisfaire la demande en gazole. De plus, à compter du 1er octobre 1996, la teneur en soufre du gazole routier ne devra pas excéder 0,05 %, conformément aux nouvelles spécifications européennes. Cette perspective de production de carburants fortement désulfurés va affecter directement l'équilibre en hydrogène de la raffinerie et donc les autoconsommations et les émissions de CO2. L'objectif de cette étude est de mesurer l'impact sur l'environnement d'une réduction de la teneur en soufre des gazoles de 0,3 à 0,05 %. Le bilan est réalisé sur l'ensemble de la filière énergétique, depuis l'extraction du pétrole jusqu'à la combustion du carburant dans le moteur. Les gains et les pertes en termes de pollution locale ou globale sont évalués suivant la nature de l'hydrogène utilisé (oxydation partielle de résidus sous vide ou de charbon, reformage à la vapeur de gaz naturel ou de naphta électrolyse et la nature de la charge à traiter (gazole straight run ou light cycle oil lors de l'hydrodésulfuration. Over the past decade, diesel had made large advances in the French and European automobile markets. In 1995, diesel could account for half of all private vehicle registrations in France, and a quarter in Western Europe. This situation inevitably raises a number of problems : environmental problems, because the diesel engine emits more nitrogen oxides and

  8. Le développement durable du tourisme dans les territoires insulaires français et la valorisation touristique des espaces naturels littoraux métropolitains

    Directory of Open Access Journals (Sweden)

    Nadège Lombard

    2009-05-01

    Full Text Available Cet article aborde la question du développement touristique dans les territoires insulaires, et propose un éclairage plus particulier sur la valorisation touristique des espaces naturels. Il présente, tout d’abord, les enjeux du développement durable du tourisme dans les territoires insulaires français. En fonction de la taille des îles, de leur accessibilité, de l’importance de leur fréquentation touristique on peut distinguer différents types d’îles.  Le défi pour chaque  île réside dans la mise en oeuvre d’un projet en étroite adéquation avec ses propres ressources et les spécificités de son territoire pour assurer un développement durable du tourisme. L’article illustre ensuite l’exemple de la valorisation touristique des espaces naturels, l’ambivalence du rapport entre le tourisme et ces espaces. Il s’attache à montrer en quoi le tourisme qui peut être parfois à l’origine de la  dégradation des espaces naturels peut être source de retombées positives pour l’environnement dès lors que les acteurs du territoire sont en situation de gérer leur développement. L’article s’achève sur un essai d’élaboration de grille d’évaluation des retombées économiques liées à la valorisation touristique des espaces naturels, appliqué à l’exemple du site naturel de la Pointe d’Agon, situé au nord du Mont Saint Michel, dans le département de la Manche.This article tackles with the issue of tourism in islands and focuses on tourist development of natural sites. First it highlights the issue of sustainable tourism for French islands. Several types of islands can be characterized, according to size, accessibility, tourist-going... To guarantee a sustainable development, the challenge is to lead a project based on the characteristics of the island and its own ressources.Then, this article enlarges on the paradox between tourism and conservation. Tourism can damage the environment but, when it

  9. Désulfuration sélective du gaz soutiré d'un stockage souterrain Selective Desulfurization of Gas Withdrawn from an Underground Storage Facility

    Directory of Open Access Journals (Sweden)

    Jaubertou G.

    2006-11-01

    Full Text Available La présence d'H2S constatée dès les premiers soutirages de gaz au stockage souterrain en nappe aquifère de Chémery avait nécessité la mise en place d'unités de désulfuration. Le gaz injecté étant exempt de gaz carbonique, le procédé par voie liquide utilisant la monoéthanolamine avait été retenu. Depuis 1977, le gaz injecté contenant des quantités appréciables de gaz carbonique a rendu inutilisable ce procédé. Parallèlement à l'injection de ce composé acide, la production d'H2S a fortement augmenté. La mise en oeuvre d'une amine sélective (MDEA a permis d'éliminer les composés soufrés en laissant pratiquement inchangée la composition du gaz chargé en C02. Les installations existantes ont pu être conservées, la banalisation des circuits facilitant l'utilisation de cette nouvelle amine. La communication présente les études et essais réalisés ainsi que les résultats d'exploitation qui se sont révélés particulièrement intéressants tant au point de vue technique qu'économique The presence of H2S in the first gas withdrawn from the underground storage aquifer at Chémery, France, required the installation of desulfurization units. Since there was no carton dioxide in the injected gas, a liquid process using monoethanolamine was selected. This process has become unusable since 1977 because the injected gas contains appreciable amounts of carton dioxide. At the same time as the injection of this acid compound, the production of H2S has considerably increased. A selective amine (MDEA was used tg eliminate the sulfur-containing compounds while leaving the composition of the C02-containing gas almost unchanged. The existing installations have been maintained as the result of the standardizing of the circuits for this new amine. This article describes the research and tests performed as well as the operational results which have turned out to be particularly intersting from both the technical and economic stand

  10. Gaz de France. 2006 reference document; Gaz de France. Document de reference 2006

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    This document was issued by Gaz de France, the French gas utility, at the occasion of the opening of the capital of the company. It is intended to shareholders and presents the relevant informations relative to the annual consolidated financial statements of the group according to IFRS and French standards for the year 2005 (selected financial information, business overview, liquidity and capital resources, profit forecasts or estimates, compensation and benefits, issuer assets etc..). It includes also some complementary information about the activities of the group, its estate property, plants and equipments, its R and D and patenting activities, its management and administration, its 2005 and 2006 contracts etc.. (J.S.)

  11. Law project modified by the Senate after urgency declaration relative to the electric and gas public utilities and to the power and gas companies; Projet de loi modifie par le Senat apres declaration d'urgence relatif au service public de l'electricite et du gaz et aux entreprises electriques et gazieres

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This document is the modifications made by the French Senate after the first reading of the law project adopted by the House of Commons and relative to the change of status of the power and gas public utilities in the framework of the deregulation of European energy markets. This law changes the juridical status of the two state monopolies Electricite de France (EdF) and Gaz de France (GdF) into two anonymous companies and creates two additional companies for the management of the power and gas networks. It ensures also the transposition of the European directives from June 26, 2003 (2003/54/CE and 2003/55/CE). It contains some proper dispositions and modifies various existing French laws, in particular the law no. 46-628 from April 8, 1946 about the electricity and gas nationalization and the law no. 2000-108 from February 10, 2000 relative to the modernization and development of the electric public utility. The document lists the modifications made by the Senate article by article. (J.S.)

  12. Project of law modified by the Senate relative to the electric and gas public utilities and to the electric and gas companies; Projet de loi modifie par le Senat relatif au service public de l'electricite et du gaz et aux entreprises electriques et gazieres

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This project of law aims to adapt the electricity and gas sector to the new economical context of opening of the energy markets to competition. It gives to energy companies the internal organization base necessary to warrant a high level of service and a transparent and non-discriminatory access of third parties to transport and distribution networks. These evolutions will allow Electricite de France (EdF) and Gaz de France (GdF) companies to compete on equal terms with their European competitors. It confirms first the prime role of public utility of both companies and then transposes the dispositions of the European directives relative to the organization of EdF and GdF integrated companies. It foresees the creation of two daughter companies for the management of energy transport activities. The project of law foresees also the change of the status of EdF and GdF companies and the reform of the retirement pensions of the personnel. This report presents the modifications added by the Senate to the text of law adopted at first reading by the House of Commons. (J.S.)

  13. Law proposal adopted by the Senate, aiming at authorizing the small domestic and non-domestic gas and electricity consumers to have access to or to get back to the regulated tariff; Proposition de loi adoptee par le Senat, tendant a autoriser les petits consommateurs domestiques et non domestiques d'electricite et de gaz naturel a acceder ou a retourner au tarif reglemente

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-03-15

    This unique article aims at modifying some articles of the law no. 2005-781 from July 13 2005 about the setting down of the French energy policy trends. Thanks to this change, the end-users can benefit by the gas and electricity regulated tariff. (J.S.)

  14. Report made on behalf of the commission of economic affairs, environment and territory about the proposal of law, adopted in second lecture with modifications by the Senate, relative to the electricity and natural gas regulated tariffs; Rapport fait au nom de la Commission des Affaires Economiques, de l'Environnement et du Territoire sur la proposition de loi, adoptee avec modifications par le Senat en deuxieme lecture, relative aux tarifs reglementes d'electricite et de gaz naturel (n.565)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-01-15

    This text is the conclusion of a long parliamentary procedure with several debates about electricity and natural gas prices, for both individual users and companies. The first article of the proposal of law relative to regulated electricity and gas tariffs, is the only one that remains to be discussed, and concerns the households and the companies with a low power consumption. Examined first at the Senate on October 1, 2007, this proposal of law was debated at the House of Commons on December 11, 2007 and modified for one important point: the possibility for households who have made the choice of a de-regulated energy supplier to change back and benefit again of the regulated tariffs. The adoption of this amendment has led to make some adjustments in the proposal of law which are presented in this document. (J.S.)

  15. Report made on behalf of the commission of economic affairs, of environment and of the territory about the proposal of law, adopted by the Senate, relative to electricity and natural gas regulated tariffs; Rapport fait au nom de la Commission des Affaires Economiques, de l'Environnement et du Territoire sur la proposition de loi, adoptee par le Senat, relative aux tarifs reglementes d'electricite et de gaz naturel (n.238)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-12-15

    This report aims at filling up some gaps in the French legislation relative to the determination of electricity and natural gas regulated tariffs and to the beneficiaries of these tariffs. It makes a synthesis of four proposals of law dealing with: the possibility for end-users and small companies to benefit again of the regulated electricity prices (proposals no 369 and 149), the permission of reversibility in the exercise of the rights relative to the eligibility for the purchase of electric power (proposal no 427), and the preservation of households' purchasing power by keeping up the regulated prices of electricity and natural gas (proposal no 462). The different articles are examined and some amendments are proposed by the commission. (J.S.)

  16. Advice presented on behalf of the commission of finances, economy and plan about the law project (no. 1613) relative to the electric and gas public utilities and to the power and gas companies; Avis presente au nom de la Commission des finances, de l'economie generale et du plan sur le projet de loi (no. 1613), relatif au service public de l'electricite et du gaz et aux entreprises electriques et gazieres

    Energy Technology Data Exchange (ETDEWEB)

    Carayon, B.

    2004-06-01

    The aim of this report is to present to the French deputies the advice of the commission of finances and economy about the law project relative to the change of status of the power and gas public utilities in the framework of the deregulation of European energy markets. This law changes the juridical status of the two state monopolies Electricite de France (EdF) and Gaz de France (GdF) into two anonymous companies and creates two additional companies for the management of the power and gas networks. It ensures also the transposition of the European directives from June 26, 2003 (2003/54/CE and 2003/55/CE). It contains some proper dispositions and modifies various existing French laws, in particular the law no. 46-628 from April 8, 1946 about the electricity and gas nationalization and the law no. 2000-108 from February 10, 2000 relative to the modernization and development of the electric public utility. The first part of the document reports on the general discussions and comments made by the commission about the law project while the second part concerns the detailed analysis of the articles 16 and 22 about the pension funds of EdF and GdF agents and the change of the status of both utilities. The amendments adopted by the commission for these articles conclude the report. (J.S.)

  17. Report made on behalf of the commission of economic affairs, environment and territory about the law project (no. 1613), relative to the electric and gas public utilities and to the power and gas companies; Rapport fait au nom de la Commission des affaires economiques, de l'environnement et du territoire sur le projet de loi (no. 1613), relatif au service public de l'electricite et du gaz et aux entreprises electriques et gazieres

    Energy Technology Data Exchange (ETDEWEB)

    Lenoir, J.C.

    2004-06-01

    The aim of this report is to present to the French deputies the comments made by the commission of economic affairs, environment and territory about the law project relative to the change of status of the power and gas public utilities in the framework of the deregulation of European energy markets. This law changes the juridical status of the two state monopolies Electricite de France (EdF) and Gaz de France (GdF) into two anonymous companies and creates two additional companies for the management of the power and gas networks. It ensures also the transposition of the European directives from June 26, 2003 (2003/54/CE and 2003/55/CE). It contains some proper dispositions and modifies various existing French laws, in particular the law no. 46-628 from April 8, 1946 about the electricity and gas nationalization and the law no. 2000-108 from February 10, 2000 relative to the modernization and development of the electric public utility. The first part of the document reports on the general discussions about the law project while the second part makes a detailed analysis of each article with some proposals of modifications. A comparative table puts in parallel the existing texts, the law project and the proposals made by the commission. (J.S.)

  18. Gaz de France 2006 annual report; Gaz de France 2006 rapport d'activite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    Gaz de France is major European energy utility, which produces, purchases, transports, distributes and sells natural gas, electricity and related services for its residential, corporate and local government customers. Its strategic focuses are to develop an ambitious marketing strategy, pursue a supply and procurement policy that guarantees the Group's competitiveness, confirm its position as a benchmark infrastructure manager, and speed up its profitable growth in Europe. Gaz de France aligns its strategy with a concrete and ambitious sustainable development policy. Its growth model is based on responsiveness to customers and constructive dialogue with its employees and partners. This document is the activity report of the group for the year 2006. It presents: 1 - the corporate profile of the group; 2 - its strategies (energy, energy supply, infrastructures); 3 - its financial highlights; 4 - its governance, shareholders and human resources; 5 - the activities of the group (exploration and production, energy procurement, energy sales, services, transmission France, storage France, LNG terminals, distribution France, transmission and distribution international, research and development); 6 - its 2006 financial data and financial summary.

  19. Hydrodynamique sur lits naturels : turbulence, transport et transferts

    OpenAIRE

    Moulin, Frédéric

    2013-01-01

    Dans ce document, je présente une synthèse de mes activités de recherche menées depuis 2002. Le fil conducteur est celui de l’étude des couches limites dans le contexte des écoulements naturels. Je commence par les études qui s’inscrivent dans le prolongement de mes travaux de thèse, soutenue en 2002, et qui concernent les écoulements géophysiques. Des études expérimentales, combinées à une approche numérique et/ou analytique, conduisent à une paramétrisation simple des effets de couche limit...

  20. Ecoulements intermittents de gaz et de liquide en conduite verticale Intermittent Gas and Liquid Flows in a Vertical Pipe.

    Directory of Open Access Journals (Sweden)

    Line A.

    2006-11-01

    Full Text Available Le modèle présenté ici permet la pré-détermination du gradient de pression, du taux global de gaz, et de grandeurs caractéristiques de l'intermittence, dans un écoulement à poches et bouchons en conduite verticale. L'écriture des lois de conservation en moyenne phasique conditionnelle conduit à la définition d'une cellule moyenne équivalente. La fermeture du modèle est assurée par des lois de contrainte de cisaillement film-paroi, film-poche, bouchon-paroi, par une loi d'arrachage du gaz au culot de la poche, une loi de glissement du gaz dans les bouchons et par une loi de la vitesse moyenne de propagation des fronts de poches. Le calibrage et la qualification du modèle s'appuient sur deux banques de données, dont l'une a été obtenue avec des fluides pétroliers dans des conditions proches des situations industrielles (boucle diphasique de Boussens. The model described here can be used to predetermine the pressure gradient, the overall gas rate and the characteristic intermittence magnitudes in pocket and slug flow in a vertical pipe. The way governing equations in the conditional phase average are written defines an equivalent average cell. The model is closed by film/wall, film/pocket and slug/wall shear-stress laws, by a pulloff law for the gas at the bottom of the pocket, a slippage law for the gas in the slugs, and a mean propagation velocity law for the pocket fronts. The calibration and qualification of the model are based on two data banks, one of which contains data on petroleum fluids under conditions close to industrial situations (two-phase loop at Boussens.

  1. Unconventional Gas Resources in the Paleozoic of Central Europe Ressources de gaz non conventionnels dans le Paléozoïque de l’Europe Centrale

    Directory of Open Access Journals (Sweden)

    Littke R.

    2011-05-01

    Full Text Available Whereas gas production from unconventional reserves has greatly increased over the past decades, there is still a largely unexplored potential in the Paleozoic of Central Europe. For this area, the paper summarizes some important aspects of the geology of tight sandstone gas reservoirs, gas shales and coalbed methane. Tight sandstones with low permeabilities are especially present in the Permian (Rotliegend Formation of The Netherlands and northern Germany, but also in the underlying Carboniferous. There is already active production from some of these reservoirs. Further development greatly depends on understanding of gas charge as well as the regional distribution of porosity and permeability which in turn depend on facies and diagenesis. In contrast exploration for gas shales is just at the very beginning. Whereas Mesozoic shales in the southern Lower Saxony Basin have to be regarded as prime targets due to thickness, maturity and organic matter content, there are additional targets in the Mississippian, but also in older rocks. Currently an international gas shale research programme (Gas shales in Europe, GASH gathers relevant data for these units. Coalbed methane exploration started already about 20 years ago in the Ruhr Basin, but was not successful at that time due to small flow rates. On the other hand, production from abandoned coal mines provided substantial amounts of gas. Due to the abundance of coal seams and the suitable maturity conditions and gas contents, there is a high potential for future substantial coalbed methane in the area. Alors que l’extraction du gaz naturel des gisements non conventionnels a fortement augmenté ces dernières dizaines d’années, un large potentiel de ressources reste inexploré dans les couches paléozoïques de l’Europe Centrale. Cet article présente, pour cette région, quelques aspects importants de la géologie des grès de faible perméabilité (tight gas sands, des gaz de schiste (gas

  2. De la recherche des principes des mixtes naturels chez Du Clos

    Directory of Open Access Journals (Sweden)

    Rémi Franckowiak

    2012-03-01

    Full Text Available Samuel Cottereau Du Clos (1598–1685 paraît être le premier Français à marier dans une chimie, pour lui science des substances, physique des qualités, une démonstration légale – suivant les lois du mouvement – et une démonstration causale – suivant les interprétations principielles –, en ramenant les phénomènes naturels à deux ordres de raisons différents et complémentaires. Les considérations mécanistes représentent pour lui une première approche, une étape vers la connaissance de la « vérité des choses » en chimie. Cette proposition originale qui vise à introduire en chimie des considérations mécanistes tout en conservant les explications principielles est développée au sein de l’ancienne Académie des Sciences, en particulier à travers sa critique de 1668/1669 des Certain Physiological Essays de Boyle.Samuel Cottereau Du Clos (1598–1685 appears as the first French chemist to combine in chemistry (for him, the science of substances, the physics of qualities demonstrations using the laws of motion with demonstrations using the qualities of chemical principles. In this way, he brought to bear two different and complementary orders of explanation. According to Du Clos, the mechanical considerations represent a first approach, a stage towards the knowledge of “the truth of things” (la vérité des choses in natural philosophy. He set out his chemistry at the Académie royale des sciences de Paris, especially through his criticism of Boyle’s Certain Physiological Essays in 1668–1669.

  3. Ecoulements diphasiques gaz-liquide à poches et à bouchons en conduites Two-Phase Gas-Liquid Slug Flow in Pipes

    Directory of Open Access Journals (Sweden)

    Ferschneider G.

    2006-11-01

    Full Text Available Les écoulements diphasiques gaz-liquide ont été étudiés afin de contribuer à développer des modèles de calculs prédictifs des pertes de charge dans les conduites de production des bruts pétroliers. Les expériences nécessaires ont été réalisées sur la boucle diphasique de Boussens dans les conditions suivantes représentatives des conditions industrielles : diamètre 6 , longueur 120 m, disposition de la conduite horizontale ou faiblement ascendante, couple de fluide gaz naturel-huile légère. Le gradient de pression, le contenu global, et la distribution locale des phases ont été mesurés. Le traitement des équations de conservation phasique intégrées sur la section par différents types de moyennes a permis de développer un modèle cellulaire qui inclue un nombre limité d'équations constitutives nécessaires à sa fermeture. Ce modèle prédétermine convenablement le gradient de pression, le contenu gaz global et la longueur des poches et des bouchons. Two-phase gas-liquid flows were analyzed so as to develop models for prediction of pressure drops in crude-oil production lines. The experiments were performed on the two-phase loop at Boussens under the following representative industrial conditions: 6 diameter, 120 m length, horizontal or slightly rising pipe, couple of fluids natural gas and light oil. The pressure gradient, average content and local phase distribution were measured. Conservation phase equations integrated along the cross-section were processed by different time-averaged operators so as to develop a cellular model including a limited number of constitutive equations required for its closure. This model suitably predetermines the pressure gradient, the average gas content and the length of gas and liquid slug.

  4. Bactériophages et phagothérapie: utilisation de virus naturels pour traiter les infections bactériennes

    OpenAIRE

    Ravat, F.; Jault, P; Gabard, J.

    2015-01-01

    L’utilisation des bactériophages, prédateurs naturels des bactéries, est une technique pionnière efficace de lutte contre les infections bactériennes. Tombée dans l’oubli depuis un demi-siècle du coté occidental de l’ex-rideau de fer, elle fait toujours partie de l’arsenal thérapeutique des pays de l’ex-Europe de l’Est, au point de constituer une arme de choix dans la politique de santé publique de ces pays. l’émergence de bactéries multirésistantes et le risque de revenir à l’ère pré-antibio...

  5. Investigation of Methane Hydrate Formation in a Recirculating Flow Loop: Modeling of the Kinetics and Tests of Efficiency of Chemical Additives on Hydrate Inhibition Étude de la formation de l'hydrate de méthane dans une conduite de recirculation : modélisation de la cinétique et tests d'efficacité d'additifs chimiques inhibiteurs d'hydrates de gaz

    Directory of Open Access Journals (Sweden)

    Peytavy J. L.

    2006-12-01

    Full Text Available Gas hydrates can be formed when light gases, such as the components of natural gas, come into contact with water under particular conditions of temperature and pressure. These solid compounds give rise to problems in natural gas and oil industry because they can plug pipelines and process equipment. To prevent hydrate formation methanol and glycols are commonly and extensively used as inhibitors. Today, the thermodynamic equilibria of hydrate formation are well known, but the kinetics of gas hydrate formation and growth has to be studied in order to find means of controlling these processes and to explore the mechanisms for hydrate formation that follows non equilibrium laws. The present work deals with the kinetics of methane hydrate formation studied in a laboratory loop where the liquid blend saturated with methane is circulated up to a pressure of 75 bar. Pressure is maintained at a constant value during experimental runs by means of methane gas make-up. First the effects of pressure (35-75 bar, liquid velocity (0. 5-3 m/s, liquid cooling temperature ramp (2-15°C/h, and liquid hydrocarbon amount (0-96%, on hydrate formation kinetics are investigated. Then a new method is proposed to predict firstly the thermodynamic conditions (pressure and temperature at the maximum values of the growth rate of methane hydrate and secondly the methane hydrate growth rate. A good agreement is found between calculated and experimental data. Finally the evaluation of the efficiency of some kinetic additives and some surfactants developed to avoid either nucleation or crystal growth and agglomeration of methane hydrates is tested based on the proposed experimental procedure. Les hydrates de gaz des composés légers du gaz naturel se forment lorsque ceux-ci entrent en contact avec l'eau dans certaines conditions de température et de pression. Ces composés solides sont nuisibles pour les industries gazière et pétrolière car des bouchons solides peuvent

  6. 77 FR 37936 - Central Vermont Public Service Corporation, Gaz Métro Limited Partnership, Dominion Nuclear...

    Science.gov (United States)

    2012-06-25

    ... COMMISSION Central Vermont Public Service Corporation, Gaz M tro Limited Partnership, Dominion Nuclear... Central Vermont Public Service Corporation and Gaz M tro Limited Partnership and Indirect Transfer of... Renewed Facility Operating License No. NPF-49. Central Vermont Public Service Corporation (CVPS), one of...

  7. Simulations et optimisation des transferts thermochimiques dans un réacteur solide-gaz

    Science.gov (United States)

    Forestier, A.; Forges, P.; Amouroux, M.

    1997-07-01

    connaissance spatiale et temporelle de la température et de l'avancement de la réaction chimique en phase d'absorption ou de désorption du gaz réactif. Un système d'équations aux dérivées partielles non linéaire modélise les phénomènes physico-chimiques dans le réacteur. Deux études de résolution numérique ont été menées au laboratoire, la première utilisant la technique des différences finies et la seconde, celle des éléments finis. Une confrontation de ces deux méthodes a permis de déterminer l'outil numérique le mieux adapté au problème d'optimisation posé.

  8. A contribution from Gaz de France to the economic performance of industries; Contribution de Gaz de France a la perfomance economique des industriels

    Energy Technology Data Exchange (ETDEWEB)

    Depail, J.C. [Gaz de France (GDF), 75 - Paris (France)

    1996-12-31

    The aim of the policy of the French national gas utility, Gaz de France, towards industries, is to promote natural gas as a competitive fuel compared to fuels and electric power, with energy efficient solutions that are easy to implement and maintain: space heating, paint curing, surface cleaning, bath heating, vapour generation, waste treatment (especially for molding sand and volatile organic compounds, sludge drying). Gaz de France proposes also expertise schemes and audits

  9. Géomorphologie structurale et risque naturel dans une portion de ...

    African Journals Online (AJOL)

    Mots-clés: géomorphologie structurale, risques naturels, Lolodorf-Mvengué, complexe du Nyong, SW Cameroun. Structural geomorphology and natural hazard of a portion of mobile belt in the nyong complex, sw cameroon: case of the lolodorf region. Natural hazard and disaster identified and studied these last thirty years ...

  10. Un produit naturel abordable réduit les pertes de fruits et augmente ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Faire avancer la science, améliorer la durée de conservation des fruits ... chercheurs canadiens, indiens et srilankais ont collaboré à une innovation fort prometteuse : les applications nanotechnologiques d'un extrait végétal naturel appelé hexanal pourraient permettre de retarder le mûrissement des fruits. Journal articles.

  11. Towards a competitive european market of the natural gas: uncertainties and tariff choices; Vers un marche europeen concurrentiel du gaz naturel: incertitudes et choix tarifaires

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-04-01

    This document reveals that, by reason of external supply and contract pregnancy, the gas market deregulation will not present the same effects as for the electricity market. The first part deals with the competition in Europe in the natural gas sector (prices policy, transportation prices, administrative procedures). The second part deals with the tariffing in France and the access to the LNG networks and installations. (A.L.B.)

  12. The liquefied natural gas, a major strategic interest, limited by economic constraints; Le gaz naturel liquefie, un interet strategique majeur, limite par des contraintes economiques

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    As the share of liquefied natural gas (LNG) on the energy market has been increasing during the last fifty years, this report recalls that its use and operation needs expensive installations and infrastructures. It also recalls that France has very soon developed methane terminals (the first one in 1972 and the last one in 2010) which are to be modernized, and observes the significant and continuous increase of LNG imports. The imported LNG has now several origins as Algeria was nearly the only provider during the early 2000's and is still the main one. The evolution of the World market is briefly commented and some figures of the evolution of gas and LNG imports since 1970 are given for several countries (France, Italy, Spain, United Kingdom, USA), in terms of quantity as well as in terms of origin

  13. The value-added tax (VAT) rate of international natural gas trade; Le regime TVA des echanges internationaux de gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Botter, E

    2008-07-15

    Since January 1, 2005, international gas trades are controlled by common right derogatory VAT rules. Transfrontier exchanges do not obey to the classical territory rules of exchange of goods but to a particular VAT regime. Moreover, the access to networks and the transportation of natural gas are subjected to particular VAT regulations. This article explains these particularities. (J.S.)

  14. A revolution in Israel: Natural gas discoveries change the energy situation; Une revolution en Israel: des decouvertes de gaz naturel modifient la situation energetique

    Energy Technology Data Exchange (ETDEWEB)

    Meritet, S. [Universite Paris-Dauphine, CGEMP, 75 - Paris (France)

    2011-05-15

    Recent discoveries of large sources of gas off the coast are expected to make Israel an energy-independent county and even a possible gas exporter. Even if the new resource estimates are correct, a number of factors still raise doubts about the viability of exports. This paper focuses on the Israel's possible energy policy choices with the natural gas discoveries. After the presentation of the current energy situation, the new energy resources are analysed along with the uncertainties around them and the new regulatory framework. The economic consequences of these new resources are then analyzed in terms of exporting strategies and electricity generation prospects. Even more than other countries, Israel's energy policy is centered on security of supply through diversification of sources and suppliers. (author)

  15. Panorama 2010: Update on hydrocarbon resources. 2 - Natural gas; Panorama 2010: Un point sur les ressources en hydrocarbures. 2 - Le gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Mathieu, Y.

    2010-07-01

    Current gas reserves could sustain a slight increase in world production until 2020. The development of all existing conventional resources would bring them up to about 4.5 Tm{sup 3} by 2030. The effect of a generalized development of unconventional gas resources would be to slow down rather than postpone the decline in production. (author)

  16. Annual survey on the natural gas market: 2008 main results; Enquete annuelle sur le marche du gaz naturel: principaux resultats 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-09-15

    This document presents and briefly comments the main data of the natural gas market in France in 2008: gas production, gas transit (entry points receiving gas from various origins and export points to Spain and Switzerland), gas storage, gas distribution, gas sales in the different French regions and to different kinds of customers or industries.

  17. Structure and operation of the natural gas market in France; La structure et le fonctionnement du marche du gaz naturel en France

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    The French natural gas market is organized around six main activities: production, transport, methane terminals, storage, distribution and commercialization. This paper describes the facilities related to each activity: gas fields, pipelines network and distribution systems, terminals capacity and underground storage facilities. The selling activity is opened to competition but the French gas market follows a progressive and controlled opening which will be complete in July 2007. (J.S.)

  18. Natural gas integration in Latin America: end of a dream?; Integration du gaz naturel en Amerique latine: la fin d'un reve?

    Energy Technology Data Exchange (ETDEWEB)

    Moutinho dos Santos, E.; Oxilia Davalos, V.E.; Tadeu Werneck Faga, M. [Sao Paulo Univ., SP (Brazil)

    2007-07-01

    Throughout the 1990's to year 2000, energy integration, and particularly natural gas integration, was seen as a major goal in the southern cone of South America. The regional perspective for energy was related to an even more challenging objective - Latin American economic integration, which was quickly moving forward by the constitution of Mercosur, the free trade zone built by Argentina, Brazil, Uruguay and Paraguay, and also having Bolivia and Chile as special partners. Mercosur was getting stronger and becoming a successful political project. Trade conflicts existed, but they were considered normal and nobody would disagree about the viability of Mercosur. By the beginning of the 21. century, the economic integration process in South America was already advancing timidly as compared to the impetus from the beginning of 1990's. Mercosur started facing complex and almost insurmountable challenges after the numerous global financial crises (from 1998 to 2003) had affected the economic balances in the region. Energy and gas integration in South America has equally lost perspective as fast as the importance of economic integration has declined. The economic crises in the region and poor energy policies have discourage energy companies to invest. The paper presents this recent history of rise and fall in the concept of economic and energy integration in the southern cone of South America. Despite the abundance of energy resources, and particularly the plethora of recently discovered natural gas, the region has been experiencing systematic and important energy shortages, which may threaten its economic recovery. A stronger energy integration policy would help all the partner countries to reduce energy supply risks. Yet, energy (and gas) integration in the southern cone is still a complex long-term political project, which must involve all countries, but whose future perspective is unclear. It seems almost impossible to keep pushing forward this project without revitalizing the former 'communitarian and regional perception of the world' that had led to the creation of Mercosur. The idea of energy or gas integration alone can hardly survive without the strong umbrella of a sustainable and wider economic integration policy. South American countries need a new initiative to restart the debate about such vital regional integration. (author)

  19. Proposal of law relative to the electricity and natural gas regulated prices; Proposition de loi relative aux tarifs reglementes d'electricite et de gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-01-15

    This proposal of law relative to regulated electricity and gas tariffs, concerns one important modification of the article 66 from the law no 2005-781 of July 13, 2005 about the main guidelines of the French energy policy. This modification allows the households who have made the choice of a de-regulated energy supplier to change back and benefit again of the regulated tariffs. This document presents the items added in this way to the article 66. (J.S.)

  20. Future development of peak-shaving rock salt underground gas storage in Russia; Russie - developpement futur de stockages souterrains du gaz naturel pour satisfaire les demandes de pointe

    Energy Technology Data Exchange (ETDEWEB)

    Remizov, V.V.; Parfenov, V.I. [OAO Gazprom (Russian Federation)

    2000-07-01

    In addition to other critical factors, sustained operation of the Russian fuel and energy sector largely depends on secure and uniform gas shipments across the country's transmission grid. Underground storage facilities built in rock salt have been increasingly prioritized world-wide, and this is a sustainable trend now. Operated in alternating mode, these facilities offer significant gas off-take capacity and are believed to be most suitable to ensure gas pipeline emergency needs and peak-shaving capability to meet consumption variations. Given the dynamics of natural gas seasonal and peak demand, a concept for rock-salt underground storage expansion through 2015 and beyond has been developed in Russia. (author)

  1. Social tariff of the natural gas. Part of the receivers and the lessors; Tarif social du gaz naturel. Role des syndics et des bailleurs

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    Since the fifteen of August 2008, low resources customers can buy their natural gas at a special social cost. This document presents the content of this derogation and the corresponding administrative procedures. A particular attention is given to the case of the group housing. (A.L.B.)

  2. The multi service cable network along a natural gas network for urban distribution; Reseau cable multiservice associe a un reseau de gaz naturel pour la consommation publique

    Energy Technology Data Exchange (ETDEWEB)

    Markovic, D.; Krsmanovic, Z. [NIS-Energogas (Yugoslavia)

    2000-07-01

    The paper discusses parallel construction and development of natural gas and telecommunications projects in Europe, with an emphasis on the situation in FR Yugoslavia. Deregulation of postal services has created an opportunity for joint construction of multipurpose cable networks and gas distribution systems. Advantages are shown of such joint construction of gas pipeline and cable systems, and the strategy of further development of telecommunications and gas supply projects in FR Yugoslavia is presented. (authors)

  3. Natural gas combustion and indoor air quality in domestic premises; Combustion du gaz naturel et qualite de l'air a l'interieur des habitations

    Energy Technology Data Exchange (ETDEWEB)

    Occhio, L.; Riva, A. [Snam, (Italy); Canci, F.; Scevarolli, V. [Italgas, Torino (Italy)

    2000-07-01

    Indoor air quality depends on many factors; combustion appliances are one of the sources of emissions inside dwellings. Their installation is regulated by UNI-CIG standards which also establish the ventilation and aeration requirements needed to guarantee the safety and healthiness of the environment. In order to critically evaluate the effect on indoor air quality of using gas appliances under different operational regimes and in different types of building, Snam and Italgas have developed a research project in co-operation with Enitecnologie and Turin Polytechnic, even to provide theoretical and experimental support for standardisation activities. The results of the presented research include experimental measurements made in real buildings, mathematical modelling and analysis of Italian and international literature. The results show that use of combustion appliances has little influence on indoor air quality and does not affect people's health. (authors)

  4. Pollution atmospherique par emission de gaz d'echappement des ...

    African Journals Online (AJOL)

    La pollution atmosphérique a été pendant longtemps considérée comme un mal propre aux pauvres mais de nos jours, elle n'épargne ni pays africains, ni pays européens et devient un problème mondial de santé. L'objectif du présent travail est d'étudier la pollution atmosphérique engendrée par les gaz d'échappement ...

  5. Contribution to the dosimetry of tritium in the presence of inactive or active gases; Contribution a la dosimetrie du tritium en presence de gaz inactifs ou actifs

    Energy Technology Data Exchange (ETDEWEB)

    Soudain, G. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-07-01

    Tritium is a dangerous gas for man and the maximum admissible doses in the atmosphere are sufficiently low for the dosage to be fairly difficult. We have developed an apparatus for measuring selectively the contamination of air by this gas when it is alone or when it is associated with other gaseous contaminants. The differential apparatus using two ionization chambers makes it possible to eliminate a parasitic {gamma} radiation field. In a few particular cases, the presence of the radio-active gas has been studied. From the practical point of view, the use of these chambers made of stainless steel makes for easier use since the problems connected with wall adsorption have been satisfactorily resolved. The method can be applied without restriction and very easily to the dosage of traces tritium in air or in the form of tritiated water or tritiated steam in the atmosphere. (author) [French] Le tritium est un gaz dangereux pour l'homme et les concentrations maximales admissibles dans l'atmosphere sont suffisamment basses pour que le dosage soit delicat. Nous avons etudie et realise un appareil qui permet de mesurer selectivement la contamination de l'air par ce gaz lorsqu'il est seul ou lorsqu'il est associe a d'autres agents gazeux contaminants. Le montage differentiel a deux chambres d'ionisation permet d'eliminer un champ de rayonnement {beta} parasite. Dans certains cas particuliers, la presence du gaz radioactif a ete etudiee. Sur le plan pratique, l'utilisation des chambres en acier inoxydable facilite les applications car les problemes d'adsorption aux parois ont ete bien resolus. La methode peut s'appliquer sans restriction et tres pratiquement au dosage des traces de tritium dans l'air ou encore sous forme d'eau tritiee ou de vapeur d'eau tritiee dans l'atmosphere. (auteur)

  6. Caractérisation de quelques peuplements naturels de Baobab ...

    African Journals Online (AJOL)

    Objectif : Le Baobab est une espèce utilisée à diverses fins par les populations locales au Bénin. Cependant, l'état des peuplements de l'espèce reste peu connu dans plusieurs localités du pays. Cette étude a permis de caractériser les peuplements de baobab dans les communes de Dassa, Matéri et Comè situées dans ...

  7. Description d'un nouveau brûleur compact. Fonctionnement en régime de gaz prémélangés Description of a New Compact Premixed Gas Burner

    Directory of Open Access Journals (Sweden)

    Minetti R.

    2006-11-01

    Full Text Available On décrit un nouveau brûleur compact à gaz, de haut rendement et d'une puissance variable de 1 à 5 kW. La source de chaleur est une flamme plate d'un prémélange stoechiométrique de gaz naturel et d'air stabilisé sur une grille d'une surface de 100 cm2. Plusieurs grilles en acier inoxydable sont comparées. Elles diffèrent par leur épaisseur, le nombre et la dimension des trous. Un échangeur de chaleur en laiton à circulation d'eau peut être approché jusqu'à 7 mm de la surface du brûleur. La température des gaz frais, le débit et la position de l'échangeur ont été modifiés et les conditions optimales de fonctionnement sont décrites. Les températures à travers les gaz frais, la flamme, les gaz brûlés et les fumées, ont été mesurées. Un modèle simple des échanges de chaleurs est présenté. Il permet une meilleure compréhension des processus de transfert et facilite le choix des conditions opératoires. Dans les meilleures conditions, 93 % du contenu thermique du mélange gazeux est transféré à l'échangeur. Some general characteristics of a compact and efficient gas burner are described (1-5 kW. The heat source is a premixed flat flame stabilized on a 100 cm2 grid fed by a stoechiometric mixture of air and natural gas. Various types of stainless steel grids have been investigated. They differ according to their thickness and to the number and size of the holes. A circulating water heat exchanger made of brass can be approached to the flame as close as 7 mm above the burner surface. The temperature of the inlet gas mixture, the flow rate, and the position of the heat exchanger have been varied. The best working conditions are given as well as the temperature through the fresh gaseous mixture, the temperature profiles of the flame and the temperature of the fumes. From heat transfer calculations a simple model is presented. It gives better insight into the heat transfer processes and facilitates a judicious

  8. Le monument naturel dans le mythe de l’Ouest chez Washington Irving, Mark Twain et Walt Whitman

    Directory of Open Access Journals (Sweden)

    Delphine Louis-Dimitrov

    2012-01-01

    Full Text Available Cet article s’intéresse à la fonction de l’image du monument naturel dans les représentations de l’Ouest au xixe siècle, et plus particulièrement dans trois récits de voyages, A Tour on the Prairies de Washington Irving, Roughing It de Mark Twain et Specimen Days de Walt Whitman. Icône des vieilles nations européennes, le monument est paradoxalement omniprésent dans les représentations de l’espace sauvage et y fait figure de paradigme structurant. Il s’agit d’analyser conjointement les enjeux esthétiques et politiques de sa transposition sur le sol américain. On montrera ainsi comment ce motif autour duquel se construit le paysage de l’Ouest se fait aussi incarnation de la démocratie américaine et, simultanément, principe d’écriture.This article deals with the image of the natural monument and considers its function in 19th-century representations of the West, especially in three travel narratives—A Tour on the Prairies by Washington Irving, Roughing It by Mark Twain and Specimen Days by Walt Whitman. An emblem of the old European nations, the monument is paradoxically omnipresent in the representations of the Western wilderness and appears as a structuring paradigm. The purpose of this reflexion is to analyse jointly the aesthetic and political implications of its transposition onto the American soil. Indeed, this motive on which the construction of the Western landscape is based also appears as the embodiment of American democracy while defining a writing principle.

  9. Les filtres plantés de roseaux, le lagunage naturel et leurs associations : comment? pourquoi?

    OpenAIRE

    Boutin, C.; Liénard, A.; Molle, P.

    2007-01-01

    / Le lagunage naturel et, plus récemment, les filtres plantés de roseaux se sont fortement développés dans le domaine du traitement des eaux usées des petites collectivités. Leur association permet, dans certains cas, d'accroitre les capacités hydrauliques tout en maintenant un niveau de qualité optimum.

  10. Structure démographique de peuplement naturel et répartition ...

    African Journals Online (AJOL)

    Pterocarpus erinaceus de la famille des Fabaceae, est un arbre éminemment utile pour les populations. C'est une espèce endémique multi-usage des zones guinéo-soudaniennes et soudano-sahéliennes. La présente étude analyse les paramètres structuraux du peuplement naturel de P. erinaceus, détermine la ...

  11. Fractionation of Hydrocarbons Between Oil and Gas Phases Fractionnement des hydrocarbures entre les phases huile et gaz

    Directory of Open Access Journals (Sweden)

    Ruffier-Meray V.

    2006-12-01

    expliquer certains phénomènes de migration. Lors de l'injection de gaz, la dissolution préférentielle de certains constituants dans le gaz peut modifier la composition et le comportement le l'huile en place. Le stockage souterrain de gaz dans des réservoirs contenant encore de l'huile peut également être concerné par ce problème. Des études ont été menées à l'IFP, dans le cadre de différents projets, de façon à mettre en évidence ce phénomène et à le quantifier. Deux d'entre elles, qui concernent la géochimie de réservoir, ont été menées sur des fluides réels. La troisième étude, qui est un test de gonflement, concerne l'injection de gaz, le fluide considéré est un mélange synthétique comprenant des hydrocarbures jusqu'à C30. Les équipements utilisés sont, d'une part, une cellule saphir ayant une pression maximale d'utilisation de 400 bar, et d'autre part un équipement appelé Hercule dont la pression maximale d'utilisation est de 1500 bar. Pour chacun des fluides étudiés, la pression de saturation a été mesurée. Pour plusieurs paliers, inférieurs à la pression de saturation, les phases liquides et gazeuses à l'équilibre ont été prélevées à pression constante et analysées. Dans le cas de l'injection de gaz, les compositions à l'équilibre ont été déterminées pour des mélanges contenant des quantités variables de gaz. Par rapport aux n-alcanes de même nombre d'atomes de carbone, les hydrocarbures aromatiques restent préférentiellement dans la phase liquide, de même que les cycloalcanes pour lesquels ce phénomène est moins net toutefois. Par contre, la phase gazeuse s'enrichit légèrement en isoalcanes. Ces phénomènes de fractionnement sont moins marqués au voisinage de la région critique. Ils ont été modélisés au moyen d'une équation d'état cubique assortie d'une règle de mélange par contribution de groupes.

  12. Development of the control assembly pattern and dynamic analysis of the generation IV large gas-cooled fast reactor (GFR); Developpement du design d'un assemblage de controle et analyse dynamique des reacteurs a neutrons rapides de quatrieme generation refroidis au gaz

    Energy Technology Data Exchange (ETDEWEB)

    Girardin, G.

    2009-07-09

    modeles neutroniques 2D et 3D du coeur du reacteur ont ete crees, bases sur le schema de calculs de reference ERANOS-2.0/ERALIB1. Pour l'analyse thermo-hydraulique, le code COPERNIC du CEA a ete utilise. Le travail de design a ete poursuivi par l'etude d'un schema de l'implantation des assemblages de controle (nombre et position dans le coeur). Des etudes detaillees de neutronique ont reveles l'existence de grands effets d'interaction entre les AC, appeles effets d'ombre/d'anti-ombre, conduisant a une amplification/reduction de l'antireactivite des AC. Les interactions entre les barreaux absorbants a l'interieur d'un AC, ainsi qu'entre les AC eux-memes, ont ete investiguees dans le detail, dans le but d'optimiser l'efficacite des AC (en terme de la fraction d'absorbant et la minimisation des effets d'heterogeneite associes). Resultant d'investigations detaillees, le diametre des pastilles absorbantes a ete choisi de maniere a minimiser l'influence 'barreau-a-barreau' a l'interieur de l'assemblage. En particulier, une partie centrale de l'assemblage a ete concue sans aucun barreau absorbant (zone remplie d'helium statique). Par ce biais, une reduction, a 13%, des effets d'heterogeneite, a ete obtenue. Les investigations neutroniques effectuees pour le coeur RNR-G de reference ('2004-Coeur'), specialement, celles liees a l'Etude des interactions entre les AC, ont directement contribue au nouveau design du coeur ('2007-Coeur'). Le rapport hauteur sur diametre a ete augmente a 0.6, compare a la valeur de 0.3 pour le coeur de reference. Pendant la troisieme phase, des modeles couples et detailles, cinetiques 3D et thermohydrauliques 1D, ont ete developpes pour le coeur RNR-G; le but etait d'arriver a une comprehension, en profondeur, du comportement 3D du coeur pendant des transitoires induits par le mouvement d

  13. Les conditions du développement des banques d’actifs naturels en FranceAnalyse du régime institutionnel de la première Réserve d’Actifs Naturels française What conditions to enlarge habitat banks in France ?Institutional regime analysis of the first French habitat bank

    Directory of Open Access Journals (Sweden)

    Fanny Chabran

    2012-05-01

    Full Text Available Les marchés d’actifs naturels sont encore rares en Europe, mais les premières expériences permettent de s’interroger sur le dispositif mis en place au regard de l’objectif de conservation des milieux naturels. Nous avons analysé la première expérience française de banque d’actifs naturels, mise en place dans le cadre des dispositifs de compensation des impacts écologiques des aménagements. Ce projet repose sur d’importants travaux de réhabilitation écologique pour faire retourner un verger intensif vers une végétation herbacée méditerranéenne. Les résultats en écologie de la restauration sont encourageants. En revanche, ils sont encore à évaluer dans les champs politiques ou économiques. Une analyse du régime institutionnel régissant les usages du site montre que l’action mercantile entreprise, tout autant que l’incomplétude du dispositif public de régulation, ne confèrent pas d’assurances définitives quant à la pérennité du dispositif de conservation environnementale du site.Habitat banks are not numerous in Europe but the first experiments allow wondering about the device in relation to the conservation purpose. We analyzed the first French experience of habitat banking introduced in the mitigation regulatory framework. This project is based on important ecological rehabilitation of an intensive orchard to Mediterranean herbaceous vegetation. Results in ecological restoration are good ; however, they are still assessing in the political and economic fields. An analysis of the institutional regime of site uses shows that the mercantile action as well as the public device incompleteness does not provide insurance about the site’s conservation sustainability.

  14. Des risques « naturels » aux politiques urbaines à Mexico

    Directory of Open Access Journals (Sweden)

    François Mancebo

    2009-07-01

    Full Text Available L’agglomération de Mexico, à plus de 2 000 mètres d’altitude, adossée à la Sierra Madre et la Cordillère Volcanique est assise sur un site accueillant mais redoutable. Il s’agit d’un des endroits les plus exposés du globe, soumis à une combinaison de risques naturels, de risques technologiques souvent mal maîtrisés dus à des industries lourdes, de nuisances, de cumul des polluants et d’un épuisement des ressources locales utilisables, tout particulièrement les ressources en eau. Après le séisme dévastateur de 1985, les acteurs de l’aménagement de Mexico tentent d’intégrer risques et durabilité dans la définition de nouvelles politiques urbaines. Mais, si les risques sont bien identifiés et des réponses sont données, leur applicabilité est quasi-nulle. Une approche normative et n’incluant pas l’ensemble de l’agglomération, mais utilisant les périphéries pour améliorer la durabilité des centres (sorte de durabilité importée à l’échelle de la métropole explique cette situation. Comme dans le mythe de Sisyphe, acteurs locaux et nationaux tentent de faire remonter la pente au rocher du risque mais ce dernier finit toujours par redescendre ? C’est qu’en réalité le problème n’est pas le rocher. Le problème, c’est la pente, c’est-à-dire le substrat fait de représentations territoriales et d’usages de l’espace qui fondent la société mexicaine, sur laquelle roule le rocher.Mexico City is located at an altitude of over 2 000 metres where it occupies an attractive but hazardous site hemmed in by the Sierra Madre and volcanic mountain ranges.The site is one of the most disaster-prone locations in the world, threatened by a combination of natural hazards, poorly controlled technological hazards created by the city’s heavy industry, pollution – particularly air pollution and diminishing local resources, the most seriously threatened being water. Since the devastating earthquake

  15. Caractérisation de quelques stabilisants naturels de l'émulsion d'eau dans le pétrole brut, grace à l'extension de la technique de "moussage" au système liquide-liquide eau-huile Characterising Several Natural Stabilizants of Water Emulsion in Crude Oil by Extending the "Foaming" Technique to Oil/Water Liquid-Liquid Systems

    Directory of Open Access Journals (Sweden)

    Coste J. -F.

    2006-11-01

    Full Text Available L'extension de la technique, de " moussage "au système liquide-liquide eau-pétrole brut a permis d'augmenter la concentration d'une fraction du pétrole en acides naphténiques, amines, asphaltènes et porphyrines, grâce à l'accroissement de l'aire de l'interface entre les deux phases non miscibles. Ces espèces chimiques présentes à l'interface favorisent la formation des films entre les gouttelettes de phase aqueuse dispersée. Elles sont à l'origine de la stabilité de I'émulsion d'eau dans le pétrole. The " foaming " technique was extended to a water/crude-oil liquid-liquid system so as to increase the concentration of naphthenic acids, amines, asphaltenes and porphyrins in an oil fraction by enlarging the interface orea between the two immiscible phases. The presence of these chemical species at the interface promotes the formation of films between the dispersed aqueuss-phase droplets. They are at the origin of the stability of a water in oil emulsion.

  16. RISQUE D'INONDATION DANS LA VALLEE DE NYOS

    African Journals Online (AJOL)

    opiyo

    Ce barrage naturel d'éjectas grossiers protège les populations et les installations en aval, sa rupture ferait au moins 10000 morts du Cameroun au Nigeria selon McKIE (2000). En effet avec ses 2 km de long, 1 km de large et 210 m de profondeur, le lac Nyos contient 3 milliards de m3 d'eau et il retient beaucoup de gaz ...

  17. Report made on behalf of the mixed parity commission in charge of the text proposal about the remaining dispositions to be discussed of the project of law relative to the electric and gas public utilities and to the electric and gas companies; Rapport fait au nom de la Commission mixte paritaire chargee de proposer un texte sur les dispositions restant en discussion du projet de loi relatif au service public de l'electricite et du gaz et aux entreprises electriques et gaziere

    Energy Technology Data Exchange (ETDEWEB)

    Lenoir, J.C.; Poniatowski, L

    2004-07-01

    This project of law aims to adapt the electricity and gas sector to the new economical context of opening of the energy markets to competition. It gives to energy companies the internal organization base necessary to warrant a high level of service and a transparent and non-discriminatory access of third parties to transport and distribution networks. These evolutions will allow Electricite de France (EdF) and Gaz de France (GdF) companies to compete on equal terms with their European competitors. It confirms first the prime role of public utility of both companies and then transposes the dispositions of the European directives relative to the organization of EdF and GdF integrated companies. It foresees the creation of two daughter companies for the management of energy transport activities. The project of law foresees also the change of the status of EdF and GdF companies and the reform of the retirement pensions of the personnel. This report presents, first, in a comparative table the articles adopted by the French house of commons and the changes adopted by the Senate. Then, a common text is proposed by the mixed parity commission for the articles that remained under discussion. (J.S.)

  18. Fuel cells, a technology developed by Gaz De France Group; Les piles a combustible, une haute technologie developpee par le groupe Gaz de France

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    Gaz De France implies in the fuel cells development, as suppliers of natural gas for electric power production but also as designer and operator. The research programs and the today experiment of the Chelles fuel cell are presented. (A.L.B.)

  19. EdF-Gaz de France. No merger without dismembering; EdF-Gaz de France. Pas de fusion sans depecage

    Energy Technology Data Exchange (ETDEWEB)

    Lepetit, V

    2007-03-15

    Gathering together the two historical French energy monopolies, Electricite de France (EdF) and Gaz de France (GdF), and warranting low electricity and gas prices is still an attractive idea for some political and syndicate representatives. However, such a merger would create a dominating position which is forbidden with respect to Brussels criteria. (J.S.)

  20. Cycle e-business: the e-business of Gaz De France; Cycle e-business: l'e-business de Gaz de France

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    This paper deals with the Gaz De France Group position in the e-business context. In terms of e-business, all is done to put Internet at the marketing service. Three examples of Internet sites realization and the future policy are presented. (A.L.B.)

  1. Gas permeability of cement based materials; Etude de la permeabilite au gaz des materiaux cimentaires

    Energy Technology Data Exchange (ETDEWEB)

    Galle, Ch.; Pin, M. [CEA Saclay, Dept. d' Entreposage et de Stockage des Dechets (DCC/DESD/SESD), 91 - Gif-sur-Yvette (France); Daian, J.F. [Universite Joseph-Fourier, Grenoble I, (INPG/CNRS/IRD), 38 (France)

    2000-07-01

    The study of the permeability of cement based materials is an important issue for their transport properties, which are good indicators of their durability. Studies were undertaken to acquire experimental data and to model the gas permeability of cement based materials. Among many parameters like cement type, water-cement ratio (w/c), curing, etc, the degree of water saturation and microstructural properties are the two main parameters controlling the ability of such type of materials to transport gas. It is well known that the higher the water saturation, the lower the gas permeability. Under pressure, gas will be also transported through the biggest pore accesses. It must be emphasized that the w/c ratio is the fundamental parameter for cement based materials. This ratio controls the hydration process and hence the material porosity. Gas permeability was calculated with Darcy law as modified by the Hagen-Poiseuille formula (1). Various materials were investigated: pure cement pastes prepared with different types of cement (CEM I-OPC, CEM V-BFS-PFA) and various w/c ratios, and industrial concretes. After curing, the samples were stored under controlled relative humidity conditions using saline solutions to reach a stable hydric state. N{sup 2} gas permeability tests were then performed with a Hassler apparatus. The microstructural properties of CEM I and CEM V materials are given in Figure 2. Examples of experimental results obtained with pure pastes are shown in Figure 3. A comparative example of paste and concrete data is provided in Figure 4. It was experimentally observed that gas permeability is extremely sensitive to material water saturation: up to five orders of magnitude of variation (between 10{sup -16} and 10{sup -21} m{sup 2} on average) for water saturations from a few % to 100%. The higher the w/c ratio, the higher the gas permeability. CEM I pastes are also less permeable than CEM V pastes. The higher total porosity effect of CEM V materials is not offset by their finer microstructure. No significant material desaturation was observed at high gas pressure. Approaching saturation, the porous medium probably reaches a critical state involving random gas transport. Finally, concretes behave similarly to pastes regarding gas permeability. This study also offered an opportunity to model the gas permeability of cement based materials [4] with a conceptual model recently developed by the LTHE Laboratory of Grenoble University. This model, called XDQ, is based on percolation theory and uses the mercury intrusion porosimetry (MIP) test. It provides reconstitutions of porous media and serves to estimate their transport properties [4], [5], [6], [7]. The principle of the XDQ model is to reconstitute the pore size distribution with an iterative process by superimposing randomly distributed elementary cubic networks which numerically reproduce the volume and pore size distribution of the material. After using a renormalization method (scaling-up process), a permeability coefficient is then calculated. Three fitting parameters are involved in the calculation procedure: the number of classes n determined by the portion of the intrusion curve that is regarded as significant, the sample size N of the percolation network, and {alpha}, which characterizes a pore shape factor and the non porous fraction of the material. The best reconstitution is selected by comparing the trapped volumes estimated by the model and those obtained with MIP tests. Modeling results obtained for pure pastes showed that the XDQ model evaluated the gas permeability with a good order of magnitude. For heterogeneous materials like concretes, the identification of fitting parameters (N, {alpha}) is difficult. Concretes cannot be seen as totally disordered porous media, especially if the zone located at the paste-aggregate interface, which is more porous and micro-cracked, modifies the gas transport capacity of the material. The degree of water saturation of cement based materials is one of the most important parameters for gas transport. A knowledge of the porous and microstructural properties is therefore necessary. On the whole, concrete materials behave similarly to pastes. The XDQ model serves to estimate the gas permeability of cement based materials as a function of water saturation. Application to various and extended cases should help adjust some parameters of the model and to confirm its robustness. (authors)

  2. Centrales au gaz et Energies renouvelables: comparer des pommes avec des pommes

    Energy Technology Data Exchange (ETDEWEB)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-10-20

    The fundamental conclusion that we draw from this analysis is that one should not to base itself blindly on forecasts prices of natural gas when one compare contracts at price fixes with producers of renewable energy with contracts at variable prices with promoters power stations with gas. Indeed, forecasts of the prices of gas do not succeed not to enter the associated costs with the covering of the risk, that they are connected to the negative pressure against the cover, with the CAPM, with costs of transaction or with unspecified combination of three. Thus, insofar as price stability to length term is developed, better way of comparing the two choices would be to have recourse to the data on the prices in the long term natural gas, and not with forecasts of the prices. During three last years at least, the use of these prices in the long term would have besides license to correct a methodological error who, obviously, seem to have supported unduly, and of relatively important way, power stations with natural gas compared to their competitors of renewable energies.

  3. La palmeraie des Îles Kerkennah (Tunisie), un paysage d'oasis maritime en dégradation : déterminisme naturel ou responsabilité anthropique ?

    OpenAIRE

    Fehri, Noômène

    2012-01-01

    L'archipel des Kerkennah, situé dans le Golfe de Gabès à environ 18 kilomètres au large de la ville de Sfax, se caractérise par la fragilité de son "milieu naturel". Une fragilité qui peut être résumée en trois points :- un climat semi-aride caractérisé par la longue durée de la saison estivale sèche avec un déficit hydrique moyen qui dépasse 1000 mm/an ; - une prépondérance des formations meubles, en particulier les limons rouges würmiens favorables à l'érosion marine, aggravée par u...

  4. Simulations aux grandes échelles : application au jet transverse

    OpenAIRE

    Prière, Céline

    2005-01-01

    Depuis plusieurs années, l'industrie des turbines à gaz place au cœur de sa stratégie de recherche les enjeux à la fois environnementaux et économiques tels que : la diminution des polluants et des nuisances sonores et la réduction de consommation du carburant. Les progrès considérables enregistrés dans ce domaine sont particulièrement dus au développement de nouveaux moteurs à grand taux de dilution dont le fonctionnement s'effectue en régime globalement pauvre, ainsi qu'à l'amélioration du ...

  5. Energy transition and security: which voluntary codes? Energy efficiency: IEA, IEC and ISO dialogue. The European Commission's safety, solidarity and efficiency measures. Securing natural gas supplies and favoring cogeneration. Less energy consuming buildings: rework of the energy efficiency directive. Energy efficiency inside buildings: GDF Suez report; Transition et securite energetiques: quels codes volontaires? Efficacite energetique: dialogue AIE, CEI et ISO. Les mesures de securite, solidarite et efficacite de la commission europeenne. Securiser l'approvisionnement en gaz naturel et favoriser la cogeneration. Des batiments moins gourmands en energie: refonte de la directive sur la performance energetique. Efficacite energetique dans les batiments: GDF Suez au rapport (volontaire)

    Energy Technology Data Exchange (ETDEWEB)

    Tourneur, J.C

    2009-10-15

    This dossier gathers a series of short articles about energy security and efficiency in a context of policy transition. The first paper deals with the use of international standards to promote energy efficiency thanks to efficient public policies and private sector actions. This was the main topic of the mixed workshop organized by the International electrotechnics Commission (IEC) in spring 2009. The second paper presents the new strategic analysis of the European commission in the domain of energy which stresses on the '20-20-20' climate change proposals approved in December 2008. A new European action plan for energy security and solidarity defines 5 domains requiring an extra action to warrant a sustainable energy supply. The commission is also examining the challenges that Europe will have to face between 2020 and 2050. The third article treats of the security of natural gas supplies which represents a quarter of the European Union (EU) energy mix. The supply crises susceptible to occur may have serious economic and social consequences. Therefore, the EU must be prepared to warrant its security of supplies. Cogeneration allows the EU to stay close to its energy goals. Buildings play a key role in the realisation of the EU's energy saving objectives and fight against climate change. The new directive on buildings energy efficiency (2002/91/CE) will allow to exploit this potential of saving and to stimulate sustainable investment and employment as well. Finally, the publication of the second WBCSD (World business council for sustainable development) international report on buildings energy efficiency has led GDF Suez utility to reaffirm its commitment in favour of energy saving and efficiency. (J.S.)

  6. Law no 2002-3 from January 3, 2002 relative to the safety of transportation systems, to the technical inquiries after sea event, accident or incident during terrestrial or aerial transport, and to the underground storage of natural gas, hydrocarbons and chemical products; Loi no 2002-3 du 3 janvier 2002 relative a la securite des infrastructures et systemes de transport, aux enquetes techniques apres evenement de mer, accident ou incident de transport terrestre ou aerien et au stockage souterrain de gaz naturel, d'hydrocarbures et produits chimiques

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-01-01

    This legislative text comprises 3 parts. The first part concerns the general safety of roadway, railway, airport, harbour and of any other infrastructure involved in the terrestrial, aerial, maritime or fluvial transport of goods or people in the French territory. The second part treats of the security of underground storage facilities for natural gas, hydrocarbons and other chemical products (obligations, rights-of-way). The last part deals with the carrying out of technical inquiries after any accident relative to a terrestrial, aerial or maritime transport. (J.S.)

  7. Bactériophages et phagothérapie: utilisation de virus naturels pour traiter les infections bactériennes

    Science.gov (United States)

    Ravat, F.; Jault, P.; Gabard, J.

    2015-01-01

    Summary L’utilisation des bactériophages, prédateurs naturels des bactéries, est une technique pionnière efficace de lutte contre les infections bactériennes. Tombée dans l’oubli depuis un demi-siècle du coté occidental de l’ex-rideau de fer, elle fait toujours partie de l’arsenal thérapeutique des pays de l’ex-Europe de l’Est, au point de constituer une arme de choix dans la politique de santé publique de ces pays. l’émergence de bactéries multirésistantes et le risque de revenir à l’ère pré-antibiotique ont fait ressortir la phagothérapie de l’oubli injuste auquel elle avait été confinée. la biologie et la place du bactériophage dans la nature sont décrites ici. les tenants et les aboutissants de la phagothérapie et les conditions de son retour sur le devant de la scène sont explicitées. PMID:26668557

  8. Oil and Gas Prospects in Egypt Recherches d'huile et de gaz en Égypte

    Directory of Open Access Journals (Sweden)

    El Ayouti M. K.

    2006-10-01

    and gas pools mainly vvithin the Upper and Lower Cretaceous. Recent advances in seismic techniques are helping in locating deeper structures, which might prove instrumental in the upgrading of the oil possibilites of the region. At present, the exploration activities are going on in the different oil and gas provinces in Egypt. These activilles are expected to increase and are also expected to expand to new areas in the eastern part of the Gulf of Suez Basin, offshore and onland, in Northern Sinai and in the Offshore Mediterranean. These new areas are believed to house very good prospects which will be tested not before long. It is also hoped that progress in seismic tools and techniques will add to the possibilities of finding more oil and gas. On connaît des accumulations d'huiles depuis 1868, quelque 10 ans après le célèbre puits de Drake en Pennsylvanie (août 1859. Ces accumulations ont été trouvées comme des suintements dans des tunnels forés pour l'extraction du soufre dans la région de Gemsa sur la côte ouest du golfe de Suez. Depuis cette époque, les activités d'exploration se sont poursuivies à travers une longue histoire d'opérations qui témoignaient des derniers développement dans les outils et les techniques. Jusqu'à maintenant, la principale province à huile d'Egypte est le bassin du golfe de Suez où la majorité des réserves ont été trouvées. D'autres provinces à hydrocarbures sont le bassin du delta du Nil, celui d'Abu Garadig et la ride d'El Alamein, les deux derniers situés dans le désert occidental. Il y a eu trois importantes découvertes de gaz dans le delta du Nil, dont deux en mer, en plus de quelques indices de gaz encore non commerciaux. Outre les découvertes mentionnées, les activités d'exploration au cours de cette longue période ont apporté une masse d'informations géologiques et géophysiques qui ont contribué largement à la connaissance géologique de l'Egypte, et en particulier à la géologie p

  9. Low-energy electron observation of graphite and molybdenite crystals. Application to the study of graphite oxidation; Observation au moyen d'electrons de faible energie de cristaux de graphite et de molybdenite. Application a l'etude de l'oxydation du graphite

    Energy Technology Data Exchange (ETDEWEB)

    David, G. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    The LEED study of cleaved (0001) faces of crystals having a layered structure allowed to investigate flakes free of steps on graphite and molybdenite, to show twinning on natural graphite. By intensity measurements and computation in the case of a kinematical approximation it has been possible to determine an inner potential of 19 eV for graphite and to identify the direction of the Mo-S bond of the surface layer of molybdenite. The oxidation of graphite has been studied by observing changes, in symmetry of the diffraction patterns and by mass spectrometry of the gases evolved during the oxidation. No surface compounds have been detected and the carbon layers appeared to be peeled off one after the other. The oxidation took place at temperatures higher than 520 C under an oxygen pressure of 10{sup -5} torr. (author) [French] L'etude par diffraction des electrons lents des faces (0001) de cristaux ayant une structure en feuillet a permis de mettre en evidence des plages sans gradins sur des clivages de graphite et de molybdenite caracterisees par la symetrie ternaire des diagrammes, de montrer l'existence de macles sur des cristaux de graphite naturel. Un calcul utilisant une approximation cinematique a ete applique aux intensites mesurees des taches de diffraction; il a ete ainsi possible de determiner un potentiel interne de 19 eV pour le graphite et de preciser la direction de la liaison Mo-S du feuillet superficiel de la molybdenite. L'oxydation du graphite a ete etudiee en mettant en relation des changements de symetrie des diagrammes de diffraction avec l'analyse des gaz provenant de la reaction carbone-oxygene. Il a ete montre qu'il n'y avait pas formation de composes de surface et que les couches de carbone etaient enlevees les unes apres les autres. L'oxydation a ete observee sous une pression d'oxygene de 10{sup -5} torr au-dessus de 520 C. (auteur)

  10. Génération interfaciale des transistors NMOS implantes et naturels, à drain simple et doublement diffusé

    Science.gov (United States)

    Oualid, J.; Dugas, J.; Jérisian, R.; Bouassis, A.; Labrunye, D.; Mirabel, J. M.

    1991-03-01

    We have compared the true interfacial generation velocities (S_0) and the diffusion lengths near the vicinity of the Si-SiO2 interface (L_s) on implanted and natural NMOS transistors with single diffused drain (SDD) or double diffused drain (DDD). An iterative procedure is proposed which allows the determination of both these electronic parameters by means of the measurement of the apparent interfacial velocities S'_0 on two transistors with different gate lengths. S'_0 values are deduced from the leakage current variation with gate polarization of the transistors used as gate controlled diodes (GCD). We show that the ionic implantation of boron for threshold voltage adjustment has a negligible influence on the true interfacial generation velocity, but it reduces L_s and consequently S'_0 when the gate length is greater than L_s. We attribute the reduction of the true interfacial generation velocity observed on DDD transistors to the gettering effect due to phosphorus which is not homogeneous along the channel. Nous avons comparé les vitesses de génération interfaciale (S_0) et les longueurs de diffusion au voisinage de l'interface Si-SiO2 (L_s) dans les transistors NMOS implantés et naturels, à drain simple (SDD) et doublement diffusé (DDD). Nous avons proposé une procédure itérative qui permet la détermination de ces deux grandeurs, qui caractérisent l'activité électronique au voisinage de l'interface, à partir des vitesses apparentes de génération interfaciale (S'_0) de deux transistors voisins, de longueurs de canal différentes, utilisés comme des diodes contrôlées par grille (DCG) en reliant la source et le drain. Nous avons montré que l'implantation ionique de bore, d'ajustement de la tension de seuil, a une influence pratiquement négligeable sur la vitesse de génération interfaciale S_0. Par contre, l'implantation ionique réduit notablement la longueur de diffusion au voisinage de l'interface, L_s, et par conséquent la vitesse

  11. Cloning and Expression of Laccase Enzyme from B. pumilus strain GAZ23

    Directory of Open Access Journals (Sweden)

    Parvin Zamani

    2014-04-01

    Full Text Available Introduction: Laccases (benzene diol oxygen oxidoreductase: EC 1.10.3.2 are one of the multicopper oxidase family members that catalyze the oxidation of various phenolic compounds by using molecular oxygen Materials and methods Laccase gene was from strain GAZ23 amplified by cloning primers. PCR product cloned in the expression vector (pET21a and transferred to BL21 strain of E. coli and sequence analysis were carried out. Biochemical properties were investigated using common laccase substrates, 2,2ˊ-azino-bis(3-ethylbenzothioazolin-6-sulphonicacid ABTS. Results: 16S rRNA gene of strain GAZ23 isolated from Iran soils, showed high similarity to Bacillus pumilus (100%. The gene of the GAZ23 has an open reading frame composed of 1533 bases, which encode 510 amino acid residues. Discussion and conclusion: The laccase gene from GAZ23 shows 67% similarity with CotA from B. subtilis. The expression was performed under microaerobic condition and decreased temperature in order to obtain high amounts of soluble protein. This protein contains four histidine rich copper-binding domains.

  12. Approche économique de l'exploration des stockages souterrains de gaz en nappe aquifère Economic Approach to Exploration for Underground Gas Storage Facilities in Aquifers

    Directory of Open Access Journals (Sweden)

    Colonna J.

    2006-11-01

    Full Text Available Dans le cadre de la recherche des stockages souterrains de gaz, le Département Réservoirs Souterrains de Gaz de France est amené à établir un programme d'exploration destiné à sélectionner définitivement, et au moindre coût, les structures capables de satisfaire la demande. Cette sélection passe par une estimation des probabilités de rejet ou d'abandon affectant les différentes structures susceptibles de donner lieu à une exploration. Il faut ensuite constituer le programme d'exploration de chacun des sites retenus après cet examen; ce programme consiste en une liste d'opérations (forage, sismique, essai hydraulique, forage à faible profondeur etc. qui mettront le plus vite possible en évidence : - d'une part les défauts; - d'autre part les principales caractéristiques techniques de la structure étudiée. La règle est d'atteindre la décision sur la faisabilité du site au stockage avec le moindre coût d'exploration. Pour ce faire, une analyse détaillée des causes potentielles d'abandon (recensement des défauts permet de choisir les opérations à effectuer, et d'associer à chacun des défauts recensés, l'opération ou l'ensemble d'opérations permettant de le détecter de façon certaine. Alors les estimateurs économiques tels que l'espérance de dépense, le risque financier, l'espérance de gain, sont calculés pour chacun des programmes, en vue de déterminer l'ordre d'exécution optimal des opérations. L'intérêt d'une telle approche, en ce qui concerne la réduction des dépenses d'exploration, est illustré par un exemple. As part of its work concerning the search for underground gas storage sites, the Underground Storage Department of Gaz de France has established an exploration program for the definitive and lowcost selection of suitable geological structures. This selection involves estimating probabilities of rejecting or abandoning different structures liable to be targets for exploration. The

  13. Dépollution des eaux usées sur un support naturel Chitosane-Bentonite

    OpenAIRE

    BENOSMAN, ASMA

    2011-01-01

    L'eau est l'élément central de tous les processus socio-économiques, quel que soit le degré de développement de la société. L'augmentation des activités agro-industrielles engendre une pression grandissante sur les réserves en eau douce de la planète. En effet, ces activités génèrent une grande diversité de produits chimiques qui se déversent dans le cycle de l'eau, mettant en péril le fragile équilibre naturel qui a permis à la vie de se développer sur la terre. Souvent, les s...

  14. Michel Mazoyer, Télipinu, le dieu au marécage. Essai sur les mythes fondateurs du Royaume hittite

    OpenAIRE

    Sergent, Bernard

    2010-01-01

    Telipinu est l’un des principaux dieux hittites, l’un de ceux pour lequel on dispose du plus de textes. Le premier mérite de M. Mazoyer est de les rassembler dans cet ouvrage. On a donc ici la transcription des textes hittites, leur traduction et un index des mots hittites, qui rendra évidemment les plus grands services au spécialiste. Les Hittites écrivaient en cunéiformes, de sorte que la hittitologie s’est naturellement développée en relation avec l’orientalisme, dont elle formait en fait ...

  15. Aflatoxin in pistachio nuts used as ingredients in Gaz sweets produced in Isfahan, Iran.

    Science.gov (United States)

    Jahanmard, Elham; Azarani, Farzaneh; Sharifi, Mehran; Esfandiari, Zahra

    2014-01-01

    In Isfahan province of Iran, pistachio and almond are used specifically as ingredients to produce Gaz sweets, which are a typical product of Isfahan and exported to many countries. In this survey, 112 samples were gathered from different corresponding Gaz producers from 2007 to 2012 to evaluate the occurrence of aflatoxins (AF) in these products. Samples were analysed for AFB1, AFB2, AFG1 and AFG2 using immunoaffinity column clean-up (IC) and quantified by high-performance liquid chromatography (HPLC) with fluorescence detection. Among the samples analysed, AFB1 was detected in 13.4% of the samples above the maximum limit (ML) as set in Iran (5 µg/kg). Total AF (AFT) was above the ML in 9.8% of the samples. This study showed that full consideration is equally essential for nuts used as ingredients in special food products such as the Gaz sweets as for nuts for direct human consumption. It suggests a need for modifying the current trend of supervision.

  16. Irreversibility of Gas-Condensate Flow in Gas Cycling Projects: Kinetically Stable Saturation Patterns Irréversibilité des écoulements de gaz à condensat dans les projets de recyclage de gaz : profils stationnaires de saturation

    Directory of Open Access Journals (Sweden)

    Mitlin V.

    2006-12-01

    Full Text Available The dynamics of a two-phase multicomponent reservoir system which is approaching the steady-state flow regime are studied. First, the compositional model is analyzed in the linear approximation, for the case of a small initial deviation from the steady-state regime. An analytical expression is obtained for the characteristic relaxation time. Next, numerical simulations are performed for situations where there is a substantial deviation from the steady-state regime. The linear injection of an enriched gas into a gas-condensate reservoir, followed by the extraction regime, is simulated. It is shown that the change in phase compositions and pressure on the way to equilibrium proceeds with characteristic times of the order of the injection time. However, the change in the saturation and overall composition takes approximately 200 times longer than the injection time. Thus, the reservoir system manifests a spatially inhomogeneous saturation distribution for an abnormally long time. Similar kinetically stable patterns have been also discovered in the nonlinear dynamics of phase transitions, plasma, and thin films. The question of the existence of discontinuous steady states for this multicomponent flow is considered. In the case of a binary mixture, it is shown that such solutions do not exist. Cet article présente une étude de la dynamique d'un réservoir biphasique multiconstituant approchant le régime d'écoulement stationnaire. En premier lieu, nous procédons à une approximation linéaire du modèle compositionnel dans le cas des petites fluctuations autour du régime permanent. Une expression analytique est ainsi obtenue pour le temps caractéristique de transition. Des simulations numériques sont ensuite effectuées pour les déviations importantes par rapport au régime permanent. Nous avons ainsi pu étudier le déplacement linéaire d'un mélange gaz/condensat par un gaz enrichi suivi d'un régime de production. On montre alors que le

  17. L'effet de serre par le CO2 et les gaz traces Greenhouse Effect from CO2 and Trace Gases

    Directory of Open Access Journals (Sweden)

    Bertrand A.

    2006-11-01

    Full Text Available Selon une opinion assez répandue le CO2 et les gaz traces, produits par l'activité humaine depuis le début de la révolution industrielle (1850, principalement du fait de la combustion et de la déforestation, et progressivement accumulés dans l'atmosphère terrestre, pourraient par effet de serre provoquer au XXIe siècle un réchauffement de la Terre de quelques degrés. Les conséquences climatiques (fonte des glaces. . . en seraient désastreuses. Aussi avons-nous étudié les principaux paramètres impliqués par ce phénomène : nature de l'effet de serre, cycle du carbone, transfert de CO2 à l'échelle du globe, gaz traces, conséquences climatiques de l'effet de serre dû au CO2 et aux gaz traces. Nous en sommes arrivés aux conclusions suivantes : - La concentration de l'atmosphère en CO2 et en gaz traces augmente de façon exponentielle en absence de toute réglementation et cela parallèlement à une production humaine également exponentielle de ces mêmes substances. - On n'a encore décelé aucun accroissement de la température moyenne de la Terre dû à l'effet de serre, d'ailleurs depuis 1940 nous traversons une période de refroidissement. - L'activité humaine engendre aussi des effets antagonistes de refroidissement (action des poussières dans l'atmosphère. . . assez mal connus. - L'étude des climats anciens indique une succession régulière de périodes froides et chaudes, cela doit nous rassurer sur le risque d'une brusque modification irréversible du climat. - Cependant il est absolument nécessaire d'améliorer nos connaissances fondamentales sur les principaux facteurs réglant le climat terrestre (chimie de l'atmosphère, transfert océan-atmosphère. . . et éventuellement de restreindre la production de certains gaz traces (fréons en particulier. According to a fairly widespread opinion, CO2 and trace gases, which have been produced by human activity since the start of the industrial revolution (1850

  18. Le Diagnostic Environnemental de la Mobilité 2006 Consommation énergétique, émissions de gaz à effet de serre et de polluants locaux de l'air : quel est l'impact des transports et des déplacements ?

    OpenAIRE

    A Dupont; HIVERT, L; Merle, N.; Quetelard, B.

    2009-01-01

    Contrat F08-11; Rapport de recherche; La communauté urbaine de Lille a confié à l'INRETS-DEST et au CETE Nord Picardie une étude portant sur l'impact environnemental au niveau local des transports en termes de consommation énergétique, d'émissions de gaz à effet de serre (GES) et de polluants locaux de l'air. Cette recherche intègre et complète l'approche « Diagnostics-Énergie-Environnement-Déplacements » (réalisée notamment avec le logiciel DEED développé par l'INRETS pour l'ADEME), qui prop...

  19. Circadian long call distribution in wild orangutans Distribution circadienne des cris longs (long calls chez l’orang-outan en milieu naturel

    Directory of Open Access Journals (Sweden)

    Thomas Geissmann

    2009-10-01

    Full Text Available We present first data on circadian long call distribution of wild orangutans in Northwest Borneo. Data were collected during two months in Batang Ai National Park. A total of 151 male long calls were heard, exhibiting a bimodal distribution pattern with peaks at 05:00-06:00 hours and 18:00-19:00 hours. An earlier study found pronounced differences between the calling rates of Bornean orangutans, which showed an almost unimodal call distribution with its peak at mid-morning, and those of Sumatran orangutans, which showed a bimodal call distribution with a distinct calling peak at predawn and a more moderate peak near dusk (MacKinnon 1974. Our findings from Batang Ai resemble more closely the pattern reported for Sumatra than those reported for other Bornean localities and, therefore, contradict earlier reports suggesting a Sumatra-Borneo dichotomy in orangutan call distribution. In addition, orangutans in Batang Ai were heard to regularly emit long calls throughout the night. This behaviour is unusual for a diurnal species.Nous présentons les premières données sur la distribution circadienne des cris longs (long calls chez les mâles orangs-outans vivant en milieu naturel au nord-ouest de Bornéo. Les données ont été récoltées lors d’une étude de terrain de deux mois au Parc National de Batang Ai. Les 151 cris longs entendus montraient une distribution bimodale, caractérisée par des pics à 05:00-06:00 et 18:00-19:00 heures. Une étude précédente avait révélé des différences profondes entre les taux de cris longs des orangs-outans de Bornéo et de Sumatra. Alors que la distribution des cris longs à Bornéo était presque unimodale et montrait un pic en milieu d’avant-midi, la distribution à Sumatra était bimodale et montrait un pic distinct avant l’aube et un second pic plus modéré au crépuscule (MacKinnon 1974. Nos résultats à Batang Ai ressemblent davantage au schéma rapporté précédemment à Sumatra qu

  20. Étude de la qualité des eaux épurées par le lagunage naturel en ...

    African Journals Online (AJOL)

    L'Algérie est l'un des pays les plus affecté par la rareté des ressources en eau, et la mauvaise répartition des précipitations, à laquelle il faut ajouter le problème de pollution des ressources en eau. Les procédés d'épuration les plus utilisé en Algérie sont les stations des boues activées et les stations de lagunage naturel.

  1. Together on the same planet. Gaz de France and sustainable development in 2006; Ensemble sur la meme planete. Gaz de France et le developpement durable en 2006

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    This document presents the sustainable development policy of Gaz de France group. It identifies the challenges the group has to face in order to control the environmental impact of the Group's activities (exploration, production, procurement, re-gasification, transmission, storage, distribution, marketing and shares, services). The approach used is based on a voluntary commitment of the Group to dialogue and share current challenges with all its stakeholders, and to imagine other roads to development. The initiatives consist in clean production practices, development of renewable energy sources, energy conservation, investment in research, safety improvement, solidarity with underprivileged people, respect of local environment and of codes of conduct, accompanying local economic development and development of clean transport systems. (J.S.)

  2. Studi Komparatif Pemikiran Tasawuf al-Gazālī dan Ibn Taimiyah

    Directory of Open Access Journals (Sweden)

    Lalu Supriadi

    2013-12-01

    Full Text Available Abstract: Al-Gazālī plays an important role in purifying Sufism and directing it into the right path of Islam. Prior to his time, many people misunderstood Sufism. While some of them were concerned only with sufi theories but lost its practices, some others simply practiced Sufism without sufficient knowledge. In his time, where splits of religious sects and disintegration spread among Muslims, he emerged to offer his notion that integrates Sufi concepts of intuition, knowledge and spiritual path to achieve the highest objective of happiness. He himself reached these sufi paths through several stages in his life and spirituality. Meanwhile Ibn Taymiyya acknowledges the validity of experimental sufi but encourages a method of external examination, namely the basic teachings of Islam, to examine the validity of Sufism. According to him, Sufism is a form of religious expressions that must be built on the Qur’an and Sunna and has to refer to the practices of the Companions.Abstrak: al-Gazālī berjasa besar dalam melakukan purifikasi ilmu tasawuf dan menariknya kembali ke pangkuan Islam. Sebelum itu banyak orang yang salah memahaminya. Di tengah gejolak dan disintegrasi keislaman antar berbagai sekte dalam tubuh umat Islam al-Gazālī tampil dengan konsepnya yang memadukan antara teori dhawq (rasa/intuisi ma‘rifah dan tharīqah rū╪iyah (jalan spiritual menuju al-sa‘ādah (kebahagiaan. Sementara Ibn Taimiyah mengakui keabsahan metode eksperimental tasawuf, tapi ia menyarankan agar tasawuf juga mempergunakan validitas eksternal untuk menguji kebenaran konsepnya. validitas eksternal yang dimaksud adalah ajaran pokok yang ada dalam Islam. Inti dari pandangan Ibn Taimiyah tentang tasawuf adalah bahwa ia (tasawuf merupakan perpanjangan dari agama Islam yang secara normatif harus bersumber dari al-Qur’an dan Sunnah dan secara historis aplikatif harus merujuk pada keteladanan para sahabat.

  3. A study of the fluorescence of the rare gases excited by nuclear particles. Use of the principle for the detection of nuclear radiation by scintillation; Etude de la fluorescence des gaz rares excites par des particules nucleaires. Utilisation pour la detection des rayonnements nucleaires par scintillation

    Energy Technology Data Exchange (ETDEWEB)

    Koch, L. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1959-12-15

    In the first part is studied the properties of atoms excited by the passage of {alpha} particles through the various rare gases at atmospheric pressure. A spectral analysis of the emitted light showed that certain impurities play an important part in producing the fluorescence, and it has led to the conclusion that the light emission contains at least two components - one very short - lived due to the direct deexcitation of the rare gas, the other relatively slower due to the energy transfers to the impurity. The measurement of the life-time of the excited states has confirmed this foregoing hypothesis, the rapid part of the impulse is extremely short: less than 2,25.10{sup -9} s in the case of xenon; the slower part has a life-time depending directly on the nitrogen concentration, nitrogen being the impurity giving the largest effect in all cases. The study of rare gases under the influence of an electric field has made it possible to show that the amount of light produced by an {alpha} particle can be multiplied (by 60, for example, in a field of 600 V:cm) so that the luminescent efficiency is greater than in the case of INaTI. In the second part the characteristics of the rare gases acting as scintillators is examined, the most important property being the absence of fluorescence saturation when the intensity of the excitation incident on the gas is very large. This, together with the very short time of scintillation has made it possible to study a certain number of nuclear physical applications (heavy particle energy-measurements, kinetic studies on nuclear reactors, neutron spectroscopy). (author) [French] On etudie dans la premiere partie les proprietes des atomes excites par le passage de particules {alpha} dans les differents gaz rares a la pression atmospherique. L'etude spectrale de la lumiere emise a montre que certaines impuretes jouent un role considerable dans la fluorescence et on a ete amene a penser que l'emission de lumiere comporte au

  4. Les aliments au soja : consommation en France, qualités nutritionnelles et données scientifiques récentes sur la santé

    OpenAIRE

    Chevalier Dominique; Debeuf Christine; Joubrel Gwénaële; Kocken Martine; Planchenault Nadine

    2016-01-01

    Aujourd’hui, 4 Français sur 10 consomment des aliments au soja. Les consommateurs les ont intégrés dans leur alimentation, sans bouleverser leurs habitudes alimentaires, parce qu’ils les considèrent naturels et sains. Les non consommateurs sont en attente de plus d’informations (origine géographique du soja et qualités nutritionnelles). La consommation est assez récente et devrait progresser dans les prochaines années. Les aliments élaborés ...

  5. Model-Based Throttle Control using Static Compensators and Pole Placement Commande des gaz basée sur un modèle utilisant des compensateurs statiques et un placement de pôles

    Directory of Open Access Journals (Sweden)

    Thomasson A.

    2011-10-01

    Full Text Available In modern spark ignited engines, the throttle is controlled by the Electronic Control Unit (ECU, which gives the ECU direct control of the air flow and thereby the engine torque. This puts high demands on the speed and accuracy of the controller that positions the throttle plate. The throttle control problem is complicated by two strong nonlinear effects, friction and limp-home torque. This paper proposes the use of two, simultaneously active, static compensators to counter these effects and approximately linearize the system. A PID controller is designed for the linearized system, where pole placement is applied to design the PD controller and a gain scheduled I-part is added for robustness against model errors. A systematic procedure for generating compensator and controller parameters from open loop experiments is also developed. The controller performance is evaluated both in simulation, on a throttle control benchmark problem, and experimentally. A robustness investigation pointed out that the limp-home position is an important parameter for the controller performance, this is emphasized by the deviations found in experiments. The proposed method for parameter identification achieves the desired accuracy. Au sein des moteurs à allumage commandé modernes, les gaz sont régulés par le boîtier de commande électronique (ECU; Electronic Control Unit, qui permet la régulation directe par l’ECU du flux d’air et ainsi du couple moteur. Cela conduit à des exigences élevées quant à la vitesse et à la précision du régulateur qui positionne le papillon des gaz. Le problème de commande des gaz est compliqué par deux forts effets non linéaires, le frottement et le couple de mode de secours (“limp-home”. Cet article propose l’utilisation de deux compensateurs statiques, actifs simultanément, pour contrer ces effets et linéariser approximativement le système. Un régulateur PID est conçu pour le système linéarisé, où un

  6. French wholesale electricity and gas markets in 2007. Monitoring report; Le fonctionnement des marches de gros francais de l'electricite et du gaz naturel en 2007. Rapport de surveillance

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-12-15

    Settled on 24 March 2000, the French Energy Regulatory Commission (CRE) is an independent authority. CRE supports an efficient functioning of the electricity and natural gas markets, to the advantage of final consumers. CRE ensures the absence of any discrimination, cross subsidy or obstacle to competition. CRE has examined the functioning of the wholesale markets for electricity and gas for the year 2007. The report discloses the results of a first set of analyses, as well as the next actions to be conducted in order to explain some observed behaviour. On the basis of analyses led on the electricity market, CRE observes that nuclear generation was marginal during 15% of the hours in 2007. Hydraulic generation was marginal during 25% of the hours, coal generation during 25% to 30% of the hours and oil generation during less than 2% of the hours in 2007. Finally, prices on the border markets were of high importance on the French prices which they determined during 20% to 25% of the hours of the year. On an efficient market, the price is driven by the marginal power plant among all those which contribute to satisfy the demand. Therefore the wholesale price formation is conditioned by the frequency of marginality of each generation sector and by the associated valuation of production. On the day-ahead market, when nuclear or hydraulic generation was marginal, the day-ahead price reflected the associated valuation which was decided by EDF. The level of this valuation was generally higher than the marginal generation cost of these plants. As a matter of fact, a producer, even market dominant, may legitimately seek to optimise its income, provided that there is no abuse of a dominant position or any price manipulation. Consequently, at this stage, the relevance of the valuation method for nuclear and hydraulic generation on the wholesale market is still to be checked. CRE has also demonstrated that generation transparency, even if it gradually increased, still needs to be improved at this stage. Published information on availability forecasts of power generation facilities were insufficient. Finally, CRE has established that the limited development of competition on the retail market and the implementation of the transitional regulated tariff for balancing markets (TaRTAM) have curbed the increase of the wholesale electricity market's activity. Considering these findings, CRE will carry out audits on the valuation methods used by EDF for its nuclear and hydraulic generation. Based on a public consultation, CRE will also formulate recommendations on generation transparency. On the gas wholesale market, CRE observes that the activity on the wholesale market has grown all along 2007 but remained focused on short-term trading. In particular, little public information was available on the market because most of the deals were concluded without intermediary. Moreover, CRE notes that the supplying conditions of suppliers who are not former incumbents in Europe were not satisfactory. These suppliers had to acquire most of their gas on the French market. In order to improve the transparency of the gas wholesale market, CRE will publish aggregated and anonymous information on the bilateral market according to information on volumes that will be collected from market participants.

  7. The opening of electricity and gas markets to professional clients. Main lessons - December 2007; L'ouverture des marches du gaz naturel et de l'electricite pour les clients professionnels. Principaux enseignements - decembre 2007

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    Since 2004, electricity and gas markets are opened to all professional clients who can freely chose their energy supplier. A quantitative inquiry has been carried out by BVA on behalf of the French Energy Regulatory Commission (CRE) on a sample of 1503 companies representative of both the private and public sectors. The aim of this inquiry is to gain information on the following points: what are the professionals' motivations or brakes concerning the change of energy supplier? What is their general opinion about markets opening? What are the false questions or ideas? what is their level of knowledge about the July 2004 opening of energy markets? What has it changed for them? Do they know the new suppliers? What are the new terms and conditions? What is their intention (faithfulness or changing). The lessons learnt from this inquiry are summarized in this document. (J.S.)

  8. Geochemical monitoring using noble gases and carbon isotopes: study of a natural reservoir; Monitoring geochimique par couplage entre les gaz rares et les isotopes du carbone: etude d'un reservoir naturel

    Energy Technology Data Exchange (ETDEWEB)

    Jeandel, E

    2008-12-15

    To limit emissions of greenhouse gases in the atmosphere, CO{sub 2} geological sequestration appears as a solution in the fight against climate change. The development of reliable monitoring tools to ensure the sustainability and the safety of geological storage is a prerequisite for the implementation of such sites. In this framework, a geochemical method using noble gas and carbon isotopes geochemistry has been tested on natural and industrial analogues. The study of natural analogues from different geological settings showed systematic behaviours of the geochemical parameters, depending on the containment sites, and proving the effectiveness of these tools in terms of leak detection and as tracers of the behaviour of CO{sub 2}. Moreover, an experience of geochemical tracing on a natural gas storage has demonstrated that it is possible to identify the physical-chemical processes taking place in the reservoir to a human time scale, increasing interest in the proposed tool and providing general information on its use. (author)

  9. Report of working committee 1 ''exploration, production, treatment and underground storage of natural gas''; Rapport du comite de travail 1 ''exploration, production, traitement et stockage souterrain du gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Rekdal, Ottar

    2000-07-01

    This report describes the activities of Working Committee 1 during the triennium 1997 - 2000. The first part of the report gives an overview of the current situation world-wide within the basic activities of the committee, i.e. exploration, production, treatment and underground storage of natural gas. In the second part of the report analyses of three prioritized topics important to the industry are described: - Improving the performance of existing gas storages; - Use of 3-D seismic data in exploration, production and underground storage. - Development of small-scale offshore gas fields. The report will be presented during the WOC 1 sessions at the World Gas Conference 2000, together with papers selected by the committee. Other relevant papers will be presented during the poster session. Furthermore, the committee will organize a round table session addressing reductions of greenhouse gas emissions along the gas chain. Representatives from industry, environmental organisations and politicians will take part in this round table discussion. (author)

  10. The gas pipeline Bolivia-Brazil and the natural gas market expansion in Sao Paulo state; Le gazoduc Bolivie-Bresil et l'expansion du marche du gaz naturel dans l'etat de Sao-Paulo

    Energy Technology Data Exchange (ETDEWEB)

    Pileggi, Valneo; Finavaro, Carlos Alberto; Itagaki, Armando Riuti [Comgas (Brazil)

    2000-07-01

    This paper will present the main interesting points of COMGAS Investments to increase the distribution and sales of the Natural Gas purchased from Bolivia. It will also present the technical and economic aspects of PETROBRAS - COMGAS Natural Gas Furnish Contract, the sale strategy adopted to achieve the objectives and the schedules coming from this contract. (authors)

  11. Health risk assessment based on injection of upgraded biogas in natural gas grid; Evaluation des risques sanitaires et accidentels lies a l'injection de biogaz epure dans un reseau de gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Leroux, C.; Modelon, H.; Rousselle, C. [AFSSET, 94 - Maisons Alfort (France); Zdanevitch, I.; Evanno, S. [INERIS, 60 - Verneuil en Halatte (France)

    2010-07-01

    This document presents the opinion of the French Agency for Environmental and Occupational Health Safety (AFSSET). Results are based on a collective expertise conducted to assess health risks associated with the injection of biogas in the natural gas grid. The complete assessment is published and available on the web site of the Agency; only the major results are presented in this document. Following recommendations issued by AFSSET in 2008, a new study has been initiated to collect and analyze data on the composition of biogas from sewage sludge. The French National Institute for Industrial Environment and Risks (INERIS) is in charge of this project. The data will be used to assess the accidental risks (resulting from the upgrading of biogas, transport by pipeline and utilization for energy purposes) and health risks for users (resulting from the injection in the natural gas grid). (authors)

  12. The articulation of Mexico into the dynamics of competition of the North American natural gas market; L'articulation du Mexique dans la dynamique concurrentielle du marche nord-americain du gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Elizalde Baltierra, A

    2002-07-01

    Deregulation is at the origin of the new dynamics of competition in the natural gas industry. The United States and Canada were the pioneer countries to suffer these changes. In fact, their natural gas markets today function in a very similar way: i) the private sector takes a place as large as possible, and ii)competition is developed within the three segments of the gas value, especially at the upstream level (emergence of hubs, spot and financial markets,...). In Mexico, its downstream gas activities (transportation, storage and distribution) were liberalized in 1995 in order to attract private investments and to develop the gas sector that has historically been operated under State control. Gas upstream operations remain reserved by the Constitution to the national oil company Petroleos Mexicanos (PEMEX). This thesis develops an evaluation framework of the articulation of Mexico into the dynamics of competition of the North American natural gas market, based on the structure-conduct-performance paradigm. In the first part, all North American's natural gas industries base conditions are analyzed. We examine in the second part, the deregulation and articulation of the dynamics of competition of the American and Canadian gas industries. Finally, in the third part we analyze the main elements of the articulation of Mexico into the dynamics of competition of United States and Canada's gas industries. Furthermore, we evaluate the impact of three of these elements (the economic growth, the electric power generation sector and eventually opening to private investments of gas upstream activities) on the adjustment of gas supply and demand in Mexico to the year 2020. (author)

  13. Proposition of the CRE for the tariffs concerning the use of natural gas transportation networks; Proposition de la CRE pour les tarifs d'utilisation des reseaux de transport de gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    The national transportation network involves: the main network constituted by the transportation works binding the access and exit points of the national territory and the underground storages; the regional network for the regional distribution upstream of the main network. The chosen tariff model is a in-out type. Each tariff includes the access terms on the main network, the exit terms of the main network, sometimes the binding terms between the equilibrium zones, the transportation terms on the regional network and the delivery terms. (A.L.B.)

  14. Natural gas: which growth and which markets in a context of high petroleum prices?; Le gaz naturel: quelle croissance, quels marches dans un conteste de prix eleves du petrole?

    Energy Technology Data Exchange (ETDEWEB)

    Appert, O. [Institut Francais du Petrole (IFP), 92 - Rueil Malmaison (France); Chabrelie, M.F. [CEDIGAZ, 92 - Rueil Malmaison (France); Zofrea, F.; Bellussi, G. [EniTecnologie (Italy); Dauger, J.M. [Gaz de France (GDF), 75 - Paris (France); Bigeard, P.H. [Institut Francais du Petrole, 69 - Vernaison (France); Courtois, A.; Renaudie, Th. [Gaz de France, 26 - Valence (France); Cervantes, V. [IRISBUS / Iveco (France); Buffet, P. [Groupe Suez (France)

    2006-07-01

    Beyond the technological stakes linked with the use of natural gas, a new geopolitical equilibrium is coming due to the different geographical distribution of gas and petroleum reserves. New countries and new markets are entering the game and may change the worldwide balance of energy powers. At the occasion of its annual 'Panorama' colloquium, the French institute of petroleum (IFP) tackles the question of the crucial role that natural gas will play in a context of high petroleum prices. Natural gas has serious economical and environmental advantages and already occupies an important position in the residential, industrial and power generation sectors and should become a major fuel for tomorrows' transportation systems. This document gathers 10 presentations (article and transparencies) given at the colloquium and dealing with: the 2005 world energy outlook: analyses and impacts (O. Appert); the future of natural gas in Europe (M.F. Chabrelie); the perspectives and new openings for LNG in a changing market (P. Buffet); the perspectives of the gas-to-liquid (GTL) industry (F. Zofrea); the opening of the natural gas market in Europe (J.M. Dauger); a presentation of natural gas (P.H. Bigeard); the 2005 world energy outlook: analyses and impacts (O. Appert); the new synthetic fuels from the GTL industry (G. Bellussi); the successes and perspectives of natural gas in the transportation sector (A. Courtois); the urban natural gas-fueled captive fleets: point of view of a car-maker (V. Cervantes). A press kit with 11 synthetic notes written by IFP's experts complete the preceding presentations, they treat of: activities and markets in exploration-production, refining and petrochemistry, natural gas industry at the 2020 prospects, petroleum supply and demand, gas reserves, discoveries and production, strategy of the European gas market actors, gas markets liberalization in Europe, natural gas for vehicles, perspectives of development of the GTL technology, LNG: a coming up convenience, ties between natural gas and petroleum prices. (J.S.)

  15. The convergence of electric power and natural gas industries. Mergers and acquisitions in the United States; La convergence des industries de l'electricite et du gaz naturel: les fusions-acquisitions aux Etats-Unis

    Energy Technology Data Exchange (ETDEWEB)

    Meritet, S

    2000-07-01

    Deep transformations have taken place in the US electric power industry, in terms of organisation and competition. The reforms of the regulation of this sector have changed the operation rules and, as an answer, the companies have adapted their behaviour. The reorganization is characterized by the combination between new competitive markets with new occupations. The deregulation and the technical progress accelerate the reconfiguration of the industry with the convergence of the natural gas and electric power activities. Since 1996, the numerous mergers-acquisitions between companies are representative of the tight links existing between the two energy sources. In this work, the convergence of the natural gas and power industries in the US is examined. The study of the reconciliation between power and gas companies (mainly the utilities) stresses on the improvement of the combined companies efficiency. The first part deals with the reconfiguration of the US power industry. The second part analyzes the consequences of the gas-electricity mergers and acquisitions. It includes the exploitation of financial data and a classical econometric test about the 'size-scale-spread' relation. The re-composition of the value chain is at the center of the industrial economy problem: it gives the opportunity for new forms of markets and firms. (J.S.)

  16. The tariffs of use of liquefied natural gas transportation networks and facilities; Les tarifs d'utilisation des reseaux de transport et des installations de gaz naturel liquefie

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    The new tariff proposals for the use of natural gas transportation networks were transmitted to the French Ministry of economy, finances and industry on October 27, 2004 by the commission of energy regulation. These proposals have been adopted and are the object of three legislative texts: the decree no. 2005-607 from May 27 2005 relative to the tariffing rules, the by-law from May 27, 2005 relative to the definition of balancing areas, and the advice from May 27, 2005 relative to the tariffs of use of natural gas transportation networks. In application of article 7 of the law from January 3, 2003, the implementation of the first tariffs of use of natural gas transportation networks and of liquefied natural gas (LNG) facilities is defined in the decree no. 2004-994 from September 21, 2004. On the main transportation network, the tariffing is of 'input-output' type and does not depend on the distance, while at the regional network scale, the tariffing is linked with the distance. The tariff of use of LNG facilities is the sum of 4 terms: a fixed term applied to each batch unloaded at the methane terminal, a term proportional to the unloaded LNG quantities, a term depending on the duration of use of LNG storage facilities and a term covering the gas consumptions of LNG facilities. This document gathers these different legislative texts with their appendixes. (J.S.)

  17. Experimental study of a separated jets burner: application to the natural gas-pure oxygen combustion; Etude experimentale du comportement de bruleurs a jets separes: application a la combustion gaz naturel-oxygene pur

    Energy Technology Data Exchange (ETDEWEB)

    Salentey, L.

    2002-04-15

    The evolution of pollution standards and the optimisation of furnaces performances require a development of new burner generation and also the improvement of combustion techniques. Actually, the use of oxy-combustion in separated jets burners offers interesting prospects for NO{sub x} emission reduction and on the modularity of flames properties (lift off, flame front topology, flame length). The complex geometry of those burners leads to several problems like the three-dimensional character of the flow, which may sometimes disturb the flame stability as flames are lifted above the burner. This experimental study deals with a simplified version of that kind of burner constituted with a central natural gas jet surrounded by two oxygen jets. Primary, the study of non-reactive jet was planned in order to understand dynamic and mixture phenomena involved between jets and to provide a database useful for the computer code validation. The reactive flow developed in a furnace, which simulates the real conditions, had been characterised. The studies of the dynamic field using Laser Doppler Velocimetry (LDV) and of the turbulent mixture by conditional Laser tomography were supplemented in combustion by the visualisation of the spontaneous emission of radical OH, in the initial and final zone of the oxy-flames, like by the measurement of pollutants like NO{sub x} and soot. The measurements carried out while varying speeds of injection as well as the gap between the jets made possible the highlight of the influence of these parameters upon the stabilisation of the oxy-flames as well as the modification of the topology and the characteristics of the flows. The comparison of the measurements made in non-reactive and reactive flow shows the influence of oxy-combustion on the dynamic and scalar development of the flow for this type of burners. (author)

  18. La palmeraie des Îles Kerkennah (Tunisie, un paysage d'oasis maritime en dégradation : déterminisme naturel ou responsabilité anthropique ?

    Directory of Open Access Journals (Sweden)

    Noômène Fehri

    2011-09-01

    Full Text Available L'archipel des Kerkennah, situé dans le Golfe de Gabès à environ 18 kilomètres au large de la ville de Sfax, se caractérise par la fragilité de son "milieu naturel". Une fragilité qui peut être résumée en trois points :- un climat semi-aride caractérisé par la longue durée de la saison estivale sèche avec un déficit hydrique moyen qui dépasse 1000 mm/an ; - une prépondérance des formations meubles, en particulier les limons rouges würmiens favorables à l'érosion marine, aggravée par une ancienne subsidence qui remonterait au Tyrrhénien ;- une prédominance des sols salés qui couvrent près de la moitié de la superficie totale.Cette fragilité se traduit par deux problèmes majeurs, à savoir : un rapide recul du trait de la côte et une extension continue des sebkhas au détriment de la palmeraie dont les arbres sont en train de mourir par centaines.Cet article met l'accent sur les interventions humaines ayant accéléré la dégradation de ces milieux naturellement fragiles.Une activité salinière en net accroissement, un déclin de l'intérêt porté par la population locale au palmier, certains aménagements entrepris sans étude d'impact, l'ouverture de carrières et l'extraction illicite des sables pour les besoins de la construction, le surpâturage, tels sont les principaux facteurs anthropiques de cette dégradation accélérée.La prise en compte de l'ensemble des particularités environnementales des Kerkennah s'impose donc comme étant une condition indispensable pour toute action de développement qui se veut rationnelle et durable.The archipelago of Kerkennah, located in the Gulf of Gabes at about 18 kilometers off the town of Sfax, is characterized by the fragility of its “natural environment”. This fragility could be summarized in three points:- a semi-arid climate characterized by a long dry summer with an annual hydric deficit greater than 1000 mm/year;- a preponderance of soft formations

  19. Catastrophes au Japon et complexité des relations homme/nature. De l’apport de la médiance…

    OpenAIRE

    Lagane, Jean

    2014-01-01

    Cet article emprunte au géographe orientaliste Augustin Berque un ensemble d’analyses mésologiques sur les désastres environnementaux qui ont affecté la société japonaise. L’œuvre de Berque, inspirée du philosophe japonais Watsuji Tetsurô, démontre que les liens qui unissent le peuple japonais à la nature (shizen) et à leur milieu (fûdo) diffèrent de la conception dualiste occidentale. En d’autres termes, le milieu naturel au Japon renvoie, d’une part, au monde habité et anthropisé – l’écoumè...

  20. Contribution to the study of the ionization and heating of gases by laser radiation; Contribution a l'etude de l'ionisation et du chauffage des gaz par le rayonnement d'un laser declenche

    Energy Technology Data Exchange (ETDEWEB)

    Veyrie, P. [Commissariat a l' Energie Atomique, Limeil-Brevannes (France). Centre d' Etudes

    1968-01-01

    The ionization and heating of gases by the concentrated radiation of a neodymium laser is studied. The power is 300 MW, the gas studied is primarily deuterium between 300 mm and 2280 mm. The first part concerns a certain number of experimental results on the absorption of the radiation and on changes produced in the plasma as a function of time. From these results are deduced a certain number of consequences, amongst which may be mentioned the definition of a pre-ionization threshold. These experimental results are interpreted in the second part. A calculation is made of the length of the period during which the electrons multiply up to when the absorption becomes measurable. The last phase corresponds to the hydrodynamics evolution, the calculations are compared with the experiments. The agreement between theory and experiment is satisfactory for the different phases. (author) [French] On etudie l'ionisation et le chauffage des gaz par le rayonnement concentre d'un laser au neodyme. La puissance est de 300 MW, le gaz etudie est principalement le deuterium entre 300 mm et 2280 mm. La premiere partie concerne un certain nombre de resultats experimentaux. Il s'agit de l'absorption du rayonnement et de l'evolution chronologique du plasma. De ces resultats on deduit un certain nombre de consequences parmi lesquelles il faut citer la definition d'un seuil de preionisation. Ces resultats experimentaux sont interpretes dans la deuxieme partie. On calcule la duree de la phase pendant laquelle se multiplient les electrons jusqu'a ce que l'absorption soit mesurable. La derniere phase correspond a l'evolution hydrodynamique. Les calculs sont confrontes avec l'experience. L'accord entre theorie et experience est satisfaisant pour les differentes phases. (auteur)

  1. New Energy Eco- Politics: Shale Gas Evoluation / Yeni Enerji Eko-Politiği: Kaya Gazı Deverimi

    OpenAIRE

    DEVELİ, ABDULKADİR

    2016-01-01

    ABD' de var olan kaya gazı rezervleri son dönemde üretim tekniklerinde meydana gelen gelişmeyle birlikte artmaya başlamıştır. Tahminlere göre ABD'deki kaya gazı rezervleri ABD'ye 100 yıllık ek enerji arzı sağlayacaktır. Bu enerji olayı kaya gazı devrimi olarak adlandırılmaktadır. Bu devrim enerji ile ilgili her hususu etkiIemekle birlikte bilinen bütün algıları da değiştirmiştir. Bu makalede kaya gazının küresel enerji arzındaki önemi ve beklenen gelişimi ülke ve bölgeler açısı...

  2. Energy Equation Derivation of the Oil-Gas Flow in Pipelines Dérivation de l’équation d’énergie de l’écoulement huile-gaz dans des pipelines

    Directory of Open Access Journals (Sweden)

    Duan J.M

    2012-09-01

    well describe the oil-gas two-phase flow. Lors de la simulation d’un écoulement multiphasique huile-gaz dans une conduite, le calcul thermodynamique représente un processus important en interaction avec le calcul hydraulique; il influence la convergence du programme et la précision des résultats. La forme de l’équation d’énergie constitue la clef du calcul thermodynamique. Basée sur l’équation d’énergie de l’écoulement huile-gaz dans un pipeline, la formule de chute de température explicite (ETDF; Explicit Temperature Drop Formula est dérivée pour un calcul de température d’état stable huile-gaz. Cette nouvelle équation d’énergie prend en compte de nombreux facteurs, tels que l’effet Joule-Thomson, le travail de pression, le travail de frottement, ainsi que l’incidence des ondulations de terrain et le transfert de chaleur avec le milieu extérieur le long de la ligne. Ainsi, il s’agit d’une forme globale de l’équation d’énergie, laquelle pourrait décrire précisément la réalité d’un pipeline à phases multiples. Pour cette raison, un certain nombre de points de vue de la littérature à propos du calcul de température d’un écoulement diphasique huile-gaz dans des pipelines sont passés en revue. L’élimination de la boucle d’itération de température et l’intégration de l’équation de température explicite, au lieu de l’équation d’énergie d’enthalpie, dans le calcul conjugué hydraulique et thermique, se sont avérées améliorer l’efficacité de l’algorithme. Le calcul a été appliqué non seulement au modèle de composants mais aussi au modèle Black-Oil. Ce modèle est incorporé respectivement dans le modèle de composants ainsi que le modèle Black-Oil et deux simulations sont effectuées sur deux pipelines en service, les pipelines multiphasiques Yingmai-Yaha et Lufeng; les résultats de température sont comparés à la simulation calculée par OLGA et aux résultats mesurés. Il

  3. Gestion des risques naturels et prise en compte du développement durable : un lien équivoque. Le cas du sud grenoblois

    Directory of Open Access Journals (Sweden)

    Lauren Andres

    2009-01-01

    Full Text Available Cet article questionne la nature du lien envisageable entre risque naturel et développement durable à travers l’étude du territoire du sud grenoblois, soumis notamment à deux aléas naturels majeurs : le mouvement de terrain de grande ampleur dit des « Ruines de Séchilienne » et les probables crues de la Romanche et du Drac. Trois étapes structurent cette réflexion questionnant la transition supposée entre une gestion des risques naturels et une gestion durable des territoires soumis aux risques naturels : une association toute relative, un lien logique mais limité sur le terrain, une relation surtout indirecte. Les interactions identifiées, en termes législatifs mais aussi idéels et opérationnels, entre risque et durabilité se révèlent ainsi complexes et ne sont pas forcément explicites ; elles dépendent en particulier de multiples échelles territoriales (nationales à locales, confrontant alors pour l’essentiel des stratégies d’acteurs – porteurs des décisions ou du savoir technique – distinctes.

  4. Senegal country study; Evaluation des couts de reduction des emissions de gaz a effect de serre au Senegal

    Energy Technology Data Exchange (ETDEWEB)

    Sow, I.

    1998-10-01

    The first part of this study consists of an analysis of the socio-economic development in Senegal and of establishment of inventory and energy balance for greenhouse gases. Scenarios for emission from single economic sectors are discussed. (EG)

  5. Gas pipeline supervision - Automatic traceability; Surveillance des canalisations de gaz - Tracabilite automatique

    Energy Technology Data Exchange (ETDEWEB)

    Dezobry, J.; Leon-Garcia, C.; Trembley, Y.

    2002-07-01

    Most of the damages occurring in a gas distribution network are caused by local human activities like for example, earthworks. To prevent such damages a general monitoring scheme is set up. The one introduced by the company Gaz de France currently consists of checking the whole network by fixedly scheduled patrols by car, aircraft, helicopter, as well as by walking, aiming at detecting unannounced construction works and supervising works in progress. The article reports on a new, computer-assisted monitoring scheme designed to improve the overall efficiency and reduce cost. All types of vehicles used for the supervision are equipped with a global-positioning-system (GPS) device for the monitoring of their trajectories. From the data analysis, which includes geographic information system (GIS) capabilities, the supervision frequency is available for each network section. Accordingly, the following patrols may be optimized and the best transportation selected, with priority given to the sections which have been neglected so far. This concept has been successfully tested on a network section of 300 km near Paris involving five monitoring cars. Gaz de France plans its extension to whole network (30,000 km).

  6. Risques naturels: de la géophysique à l'approche institutionnelle

    Directory of Open Access Journals (Sweden)

    1996-01-01

    Full Text Available Les limites de l’approche physique des risques naturels ont conduit à une collaboration novatrice des sciences sociales, particulièrement en matière de prévention et de gestion des risques. Mais dans l’approche physique, la prise en compte indispensable des comportements humains face aux risques, ne revient-elle pas à juxtaposer une Population plus ou moins sensible aux dangers encourus et une Administration plus ou moins efficace ? Une approche institutionnelle devrait pleinement prendre en compte le facteur spécifique que constituent les pouvoirs publics pour définir une politique de prévention qui soit en phase, non pas avec un idéal technique inaccessible en particulier dans les sociétés en développement, mais avec un optimum social. RIESGOS NATURALES: ENTRE LA GEOFÍSICA Y LA APROXIMACIÓN INSTITUCIONAL. Las limitaciones de la perspectiva física de los riesgos naturales han implicado una colaboración novedosa de las ciencias sociales en particular a nivel de la prevención y del manejo público de los riesgos. Sin embargo, en la perspectiva física, ¿la incorporación de los comportamientos humanos frente a los riesgos no consiste en una yuxtaposición de una Población más o menos sensible a los peligros y una Administración más o menos eficiente? Una aproximación institucional debería considerar totalmente el factor específico que representan los poderes públicos para definir una política de prevención que sea compatible, no con un ideal técnico inalcanzable en particular en las sociedades en desarrollo, sino con un óptimo social. NATURAL HAZARDS: BETWEEN THE GEOPHYSICS AND THE INSTITUTIONAL APPROACH. The limitations of the physical perspective on natural hazards have required the contribution of the social sciences, especially for the mitigation and the management of risks. But in the physical approach, the analysis of human behavior in the event of natural hazards seems to be limited to the addition of a

  7. Les recherches menées par le Gaz de France dans le domaine de l'hydrogène Research on Hydrogen by Gaz de France

    Directory of Open Access Journals (Sweden)

    Donat G.

    2006-11-01

    Full Text Available Les besoins en énergie de l'humanité allant croissant et les ressources en combustibles de la Terre étant obligatoirement limitées, le temps viendra où la demande en hydrocarbures excédera la capacité mondiale de production; cette situation s'aggravera encore ultérieurement du fait de l'épuisement des réserves récupérables. Un recours massif aux énergies nucléaire et solaire semble donc indispensable et l'utilisation de l'hydrogène comme vecteur de ces énergies retient depuis quelques années l'attention, notamment en France où les ressources propres en pétrole sont faibles. Le Gaz de France a entrepris des recherches sur la production massive de l'hydrogène par décomposition de l'eau et vient de parvenir à des conclusions pessimistes quant à la compétitivité, par rapport à la voie électrolytique, de la filière utilisant des cycles thermochimiques. Par contre, l'électrolyse de l'eau offre des perspectives intéressantes à condition d'améliorer ses performances et son économie. D'autre part, des études concernant le stockage et le transport de l'hydrogène ont permis d'ores et déjà de tirer quelques conclusions dans ces domaines où les vecteurs gazeux disposent d'excellents atouts. With the increasing energy needs of mankind and the earth's necessarily limited resources of fuel, the time will come when the demand for hydrocarbons will exceed the world production capacity. This situation will subsequently get even worse becouse of the depletion of recoverable reserves. Massive recourse ta nuclear and solar energy thus appears indispensable, and the use of hydrogen as a vector for such energies has been under consideration for several years, especially in France where petroleum resources are very limited. Gaz de France has been doing research on the mass production of hydrogen by the decomposition of water and has just come ta rather pessimistic conclusions as ta the competitiveness of thermochemical processes in

  8. Enjeux juridiques du contrôle des émissions personnelles de gaz à effet de serre par un dispositif de carte carbone

    Directory of Open Access Journals (Sweden)

    Sandrine Rousseaux

    2011-02-01

    Full Text Available La carte carbone individuelle est un dispositif innovant, qui permet d’impliquer les particuliers dans la lutte face au changement climatique. Ce dispositif consiste à limiter leurs émissions de gaz à effet de serre, ce qui suppose de suivre leur consommation de certains produits et services. Ce mode de contrôle des émissions personnelles soulève parfois des controverses, la carte carbone pouvant être perçue comme un instrument de rationnement potentiellement liberticide. Ces deux aspects sont discutés sur la base d’une analyse comparative de la conception et des modalités de mise en œuvre des différents dispositifs de carte carbone, établis ou envisagés en Europe et aux États-Unis. Il en ressort que les controverses ne sont pas réellement fondées.The individual carbon card is an innovative mechanism that helps involve individuals in the fight against climate change. It consists in limiting their greenhouse gas emissions, which requires monitoring a part of their goods and services consumption. This method of personal emissions control is much debated since the carbon card may be perceived as a rationing tool and raises civil liberty issues. Both of these controversial aspects are discussed on the basis of a comparative analysis of how the various carbon card programs, established or contemplated in Europe and in the USA, are designed and implemented. The findings are these controversies are somewhat groundless.

  9. Un produit naturel abordable réduit les pertes de fruits et augmente ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    L'utilisation de nanotechnologies vertes provenant des déchets biologiques, au lieu de nanoparticules à base de métal ou de carbone, est plus écologique et abaisse les coûts de production. Amélioration des conditions de vie et des moyens de subsistance. Le projet est censé réduire sensiblement les pertes après récolte ...

  10. Science, technologie, nature et humain ont rendez-vous au jardin

    Directory of Open Access Journals (Sweden)

    Dargent Olivier

    2015-01-01

    Full Text Available Un jardin expérimental est un espace riche en activités pédagogiques pour les élèves. Il recueille, à priori, naturellement, l’adhésion de chacun, élèves, équipe éducative et parents. Il est enfin une occasion d’avoir une approche différente de celle de la classe, les élèves étant confrontés au vivant dans son environnement. Lors de ces activités proposées dans ce contexte, leur rapport au vivant est directement confronté à la réalité. Quels sont les enjeux didactiques d’une pédagogie axée autour d’activités au jardin expérimental ? A partir de deux activités ; un « totem à insectes » et un « nichoir connecté ». La confrontation du vivant et de leur représentation est analysée.

  11. Du théâtre au cinéma, des planches à la caméra : les incursions de Gémier dans le « septième art »

    OpenAIRE

    Coutelet, Nathalie

    2008-01-01

    Firmin Gémier (1869-1933), acteur célèbre et fondateur du Théâtre National Populaire, est le symbole du passage au cinéma effectué par la plupart des artistes de théâtre au début du XXe siècle. Il participa à des films muets, puis parlants, reprit certains de ses rôles à succès. Figure emblématique de l’adaptation du jeu théâtral au cinéma, il recourut à ses techniques habituelles de composition : sincérité, émotion, intériorité, naturel. La parenté du cinéma et du théâtre se donnait pour lui...

  12. Natural uranium toxicology - evaluation of internal contamination in man; Toxicologie de l'uranium naturel - essai d'evaluation de la contamination interne chez l'homme

    Energy Technology Data Exchange (ETDEWEB)

    Chalabreysse, J. [Commissariat a l' Energie Atomique, Pierrelatte (France). Centre d' Etudes Nucleaires

    1968-07-01

    After reminding the physical and chemical properties of natural uranium which might affect its toxicology, a comprehensive investigation upon natural uranium metabolism and toxicity and after applying occupational exposure standards to this particular poison, it has been determined, from accident reports and human experience reported in the related literature, a series of formulae obtained by theoretical mathematical development giving principles for internal contamination monitoring and disclosure by determining uranium in the urine of occupationally exposed individuals. An assay is performed to determine individual internal contamination according to the various contamination cases. The outlined purposes, mainly practical, required some options and extrapolations. The proposed formula allows a preliminary approach and also to determine shortly a contamination extent or to discuss the systematical urinalysis results as compared with individual radio-toxicology monitoring professional standards. (author) [French] Apres le rappel des caracteristiques physiques et des proprietes chimiques de l'uranium naturel pouvant avoir une influence sur sa toxicologie, l'etude detaillee de son metabolisme et de sa toxicite, puis l'application des normes professionnelles d'exposition au cas particulier de ce toxique, il est etabli, a partir des comptes rendus d'accidents et de l'experimentation humaine rapportes dans la litterature, une serie de formules obtenues par developpement mathematique theorique qui posent les principes de la surveillance et de la mise en evidence de la contamination interne par la recherche et le dosage de l'uranium dans les urines d'individus professionnellement exposes. Un essai d'evaluation de la contamination interne individuelle suivant les differents cas de contamination est effectue. Le formulaire propose permet de faire une premiere approximation et d'apprecier rapidement l'importance d

  13. The Mooring Pattern Study for Q-Flex Type LNG Carriers Scheduled for Berthing at Ege Gaz Aliaga LNG Terminal

    Directory of Open Access Journals (Sweden)

    Selcuk Nas

    2014-12-01

    Full Text Available Ever growing energy industry requires larger quantities of LNG to be transported by bigger ships between terminals. Every day, new kind of large vessels created by new technologies, and these are used to trade around the globe. This is the dynamic change in shipping industry. But on the other hand these new vessels need to safely berth to existing terminals which we may accept as more static part of the trade. Thus this study born by the request of Ege Gaz Aliaga LNG Terminal management to determine if it is safe to berth to the terminal by a new breed of large LNG carrier type named as Q-Flex and Q-Max. Transas Bridge Simulator NTPRO 5000 series was used in this study for extensive experiments which had been simulated by the use of hook function. During the study, every force applied to mooring hooks and dolphins by the ship lines were divided into 3 dimensions and then measured by simulation experiments. With analysis of the data, required hook and dolphins strengths were determined for the safe mooring arrangements. Upon the completion of the study Ege Gaz Aliaga LNG Terminal became the first safe berth for Q-Flex type vessels in the Mediterranean and the Black Sea. And finally all experiments were confirmed with real life experience when the first Q-Flex type LNG carrier berthed to the Ege Gaz Aliaga LNG Terminal.

  14. Yaş baca gazı desülfürizasyon yöntemler

    Directory of Open Access Journals (Sweden)

    Hayrunnisa Çavuşoğlu

    2013-04-01

    Full Text Available Yaş baca gazı desülfürizasyon prosesi, güç santrallerinin atık gaz muamelerinde geniş çapta kullanılmaktadır. Kullanılan birçok proses arasında en etkili proses olduğundan, bu proses işletmeler tarafından tercih edilmektedir. Yüksek SO2 geri kazanımı, absorpsiyon kimyasallarının geniş uygulanabilirliği ve kimyasal prosesin yönetiminde büyük çapta bir bilgiye gerek duyulmaması bu prosesin avantajları arasında yer almaktadır. Bu yayında başta kireç/kireç taşı prosesi olmak üzere çeşitli yaş baca gazı desülfürizasyon proseslerinden bahsedilmiştir.

  15. Résistance au cisaillement des sédiments utilisation du T-bar en laboratoire et effet du diamètre

    OpenAIRE

    LEVACHER, Daniel; RAZAKAMANANTSOA, Andry; GUPTA, Ritesh

    2015-01-01

    La résistance au cisaillement non drainé sur des sols fins et en particulier des sédiments, est un paramètre important pour l'étude de la stabilité de talus, de la circulation des engins sur couches déposées en bassin de lagunage, du suivi de la déshydratation et du séchage naturel, de la consistance et sensibilité des sédiments. La résistance au cisaillement non drainé peut être mise en relation avec la teneur en eau et les limites d'Atterberg. Plusieurs outils sont disponibles pour sa déter...

  16. Influence du débit de base et de la durée des éclusées sur la dérive d'alevins de truite commune : expérimentations en canal semi-naturel

    Directory of Open Access Journals (Sweden)

    LIEBIG H.

    1998-07-01

    Full Text Available Le fonctionnement par éclusées de certains ouvrages hydroélectriques installés sur des rivières de montagne à peuplement salmonicole est souvent considéré comme responsable du déficit en alevins observé sur les secteurs à l'aval immédiat du rejet. Une des causes majeures avancée de ce déficit est l'entraînement forcé des alevins dès l'émergence. Une approche expérimentale de ce phénomène est apparue nécessaire pour identifier et quantifier les facteurs mis en jeu. Un ancien bras de la rivière Oriège a été ainsi aménagé au niveau du canal de fuite de l'usine hydroélectrique d'Orlu, en Ariège (09. Ce système semi-naturel permet, sur un substrat et des abris naturels, de simuler des éclusées et de quantifier la dérive des alevins résultante. Sur un bief à faciès d'écoulement mixte radier-plat, nous avons testé deux modalités pour la durée des éclusées (10 minutes et 3 heures, associées à deux modalités pour la valeur du débit de base (débit précédant l'éclusée, soit 150 et 250 l/s. Le débit plafond des éclusées a été fixé à 1 500 l/s, ce qui correspond à un facteur de 6 à 10 par rapport aux débits de base, situation fréquemment rencontrée sur l'Oriège. Les résultats sont comparés et discutés. En définitive, il apparaît que les éclusées entraînent systématiquement une dérive forcée des alevins. Cette dérive intervient principalement au démarrage de l'éclusée et est d'autant plus forte que le débit de base est faible.

  17. L'impact du miellat de puceron au niveau des relations tritrophiques entre les plantes-hôtes, les insectes ravageurs et leurs ennemis naturels

    Directory of Open Access Journals (Sweden)

    Leroy P.

    2009-01-01

    Full Text Available Aphid honeydew impact on the tritrophic relationships between host-plants, phytophagous insects and their natural enemies. Tritrophic relations between plants, phytophagous insects and beneficials are based on the presence of chemical cues in the environment. In this context, honeydew (the aphid excretory product, rich in sugars and amino-acids, constitutes a nutritional resource for beneficials but also acts as a volatile and a contact kairomone. On one hand, honeydew volatile chemicals cues guide beneficials to a food source, hosts or preys but also stimulate particular behaviors: searching, preys/hosts locations and attacks. On the other hand, a contact with honeydew induces the oviposition especially for syrphids (Episyrphus balteatus, etc.. The use of an artificial honeydew could be a way for enhancing the biological control efficiency in fields by increasing the number of beneficials but also the predation and parasitic rates.

  18. AU BURKINA FASO

    African Journals Online (AJOL)

    Les moyennes sur la même ligne et possédant le même indice ne diffèrent pas significativement au seuil de 5 %. ME : mélange fourrager. 10-20-30 % : pourcentage de concentré. GMQ : Gain Moyen Quotidien. L'analyse des résultats des rations. 1 et 2 montre que l'accès au pâturage permet des performances supérieures.

  19. Adsorption de gaz sur les materiaux microporeux modelisation, thermodynamique et applications

    Science.gov (United States)

    Richard, Marc-Andre

    2009-12-01

    Nos travaux sur l'adsorption de gaz dans les materiaux microporeux s'inscrivent dans le cadre des recherches visant a augmenter l'efficacite du stockage de l'hydrogene a bord des vehicules. Notre objectif etait d'etudier la possibilite d'utiliser l'adsorption afin d'ameliorer l'efficacite de la liquefaction de l'hydrogene des systemes a petite echelle. Nous avons egalement evalue les performances d'un systeme de stockage cryogenique de l'hydrogene base sur la physisorption. Comme nous avons affaire a des plages de temperatures particulierement etendues et a de hautes pressions dans la region supercritique du gaz, nous avons du commencer par travailler sur la modelisation et la thermodynamique de l'adsorption. La representation de la quantite de gaz adsorbee en fonction de la temperature et de la pression par un modele semi-empirique est un outil utile pour determiner la masse de gaz adsorbee dans un systeme mais egalement pour calculer les effets thermiques lies a l'adsorption. Nous avons adapte le modele Dubinin-Astakhov (D-A) pour modeliser des isothermes d'adsorption d'hydrogene, d'azote et de methane sur du charbon actif a haute pression et sur une grande plage de temperatures supercritiques en considerant un volume d'adsorption invariant. Avec cinq parametres de regression (incluant le volume d'adsorption Va), le modele que nous avons developpe permet de tres bien representer des isothermes experimentales d'adsorption d'hydrogene (de 30 a 293 K, jusqu'a 6 MPa), d'azote (de 93 a 298 K, jusqu'a 6 MPa) et de methane (de 243 a 333 K, jusqu'a 9 MPa) sur le charbon actif. Nous avons calcule l'energie interne de la phase adsorbee a partir du modele en nous servant de la thermodynamique des solutions sans negliger le volume d'adsorption. Par la suite, nous avons presente les equations de conservation de la niasse et de l'energie pour un systeme d'adsorption et valide notre demarche en comparant des simulations et des tests d'adsorption et de desorption. En plus de l

  20. Gas transport through porous media; Sur le transport des gaz a travers les milieux poreux

    Energy Technology Data Exchange (ETDEWEB)

    Breton, J.P. [Commissariat a l' Energie Atomique Saclay (France). Centre d' Etudes Nucleaires

    1968-06-01

    In the first part of this work we derive a rigorous transport theory for a mixture of gases passing through a bed of spheres, when the temperature is uniform. We solve the Boltzmann equation, putting boundary conditions in the solution. Two different methods are used, according to the nature of the flow. The second part deals with the experimental work: measurements of permeability, of separation and of interdiffusion. In the last part, with the help of the new theory presented here, we are for the first time able to explain all the experimental data. (author) [French] Dans la premiere partie de ce travail nous developpons une theorie rigoureuse du transport d'un melange de gaz a travers un lit de spheres, quand la temperature est uniforme. Nous integrons l'equation de Boltzmann en introduisant des conditions aux limites dans la solution. Nous utilisons deux methodes differentes selon le regime d'ecoulement. La seconde partie est consacree a l'etude experimentale: mesures de permeametrie, de separation et d'interdiffusion. Dans la derniere partie, a l'aide de la nouvelle theorie developpee ici, nous expliquons tous les resultats experimentaux, ce qui n'avait pas ete fait jusque la. (auteur)

  1. Les techniques de séparation de gaz par membranes Gas Separation Techniques by Membranes

    Directory of Open Access Journals (Sweden)

    Avrillon R.

    2006-11-01

    Full Text Available Deux types de membranes peuvent être utilisés pour la séparation des gaz. Les unes sont poreuses et séparent les gaz sur la base de leur masse moléculaire selon un mécanisme de diffusion de Knudsen dans des micropores. Les facteurs de séparation obtenus sont généralement trop faibles pour présenter un intérêt industriel. Les autres, appelées membranes non poreuses, mettent en oeuvre un mécanisme de dissolution-diffusion des gaz dans une fine couche de polymère dénuée de toute porosité. C'est de ces dernières que nous allons parler. Commencé il y a une vingtaine d'années, le développement de ce type de membranes a conduit aux premières applications industrielles en 1979 avec l'introduction par Monsanto des séparateurs PRISM pour la récupération d'hydrogène à partir de différents gaz de raffinerie et de pétrochimie. Après des débuts modestes par suite de la compétition avec des technologies éprouvées comme la cryogénie, l'adsorption et l'absorption, la perméation gazeuse est en train de conquérir sa place parmi les techniques de séparation de gaz. Elle est aujourd'hui l'une des techniques membranaires présentant le plus fort taux de progression (30 % par an. Après un rappel des principes de base de la perméation gazeuse on abordera successivement les points suivants : - le choix du polymère constituant la couche séparatrice, - l'élaboration des membranes à structure asymétrique présentant une peau dense et fine, - les principales applications industrielles. Cela permettra de mettre en évidence les avantages et les limitations actuelles de la perméation gazeuse et de souligner les différents domaines où les efforts de R et D peuvent amener des progrès significatifs. Principle of Gas permeation - Gas permeation is a technique for fractionating gas mixtures by using nonporous polymer membranes having a selective permeability to gas according to a dissolution-diffusion mechanism. Gas is made to pass

  2. Appel à projets de recherche Inter-Carnot BRGM, Cerema Effi-sciences, Irstea, Risques naturels et environnementaux, Expertise du projet MUDSLIDE : Méthodes de traitement des données imparfaites pour l'aide à la décision dans la gestion des risques naturels gravitaires

    OpenAIRE

    RAJOT, Jean-Pierre

    2017-01-01

    Rapport d'évaluation scientifique du projet MUDSLIDE, qui propose de développer une méthode pour considérer des données aléatoires et des données imparfaites ou limitées dans les études de gestion des risques naturels gravitaires. Evaluation report of research project MUDSLIDE, proposing to develop a method for dealing with uncertainties and limited data in rockslide risk management studies.

  3. LA SPECTROSCOPIE DE MASSE PAR IONISATION CHIMIQUE AVEC LA DIETHYLAMINE COMME GAZ REACTANT DES IRIDOIDES GLUCOSIDIQUES DE TYPE C-9

    Directory of Open Access Journals (Sweden)

    H SAADI

    2000-12-01

    Full Text Available Ce travail s’intéresse à l’étude de la spectrométrie de masse par ionisation chimique de quelques composés des iridoïdes glucosidiques de type C-9 extraits des plantes de l’espèce Euplantago en utilisant la diéthylamine comme gaz réactant. Nous avons appliqué la même technique que précédemment à deux d’entre eux se trouvant en abondance dans ce type de plantes, après leur acétylation.

  4. Morpho-sédimentologie des sites naturels littoraux colonisés par l’Hirondelle de rivage (Riparia riparia)

    OpenAIRE

    Fournier, Jerome; Corbeau, Alexandre; Le Mao, Patrick

    2016-01-01

    L’Hirondelle de rivage Riparia riparia revient annuellement sur un même site pour y établir une colonie. Ces sites sont naturels ou d’origine anthropique mais toujours soumis à des changements permanents. L’espèce se caractérise par sa capacité à creuser des tunnels dans lesquels elle mène à bien son cycle de reproduction. Plusieurs auteurs ont tenté d’identifier les critères utilisés par les hirondelles pour choisir un site favorable à l’installation d’une colonie Parmi les nombreux paramètr...

  5. L’environnement naturel et le changement climatique pendant les années Bush : la pertinence d’une différenciation des échelles territoriales Climate Change and the Natural Environment in the Bush Years: The Relevance of Territorial Scale Differentiation

    Directory of Open Access Journals (Sweden)

    Cynthia Ghorra-Gobin

    2010-03-01

    Full Text Available L’attitude de l’administration fédérale au cours des huit années de l’administration Bush contraste avec celle du contexte des années 1960-1970 pour ce qui concerne la prise en compte de l’environnement naturel dans les décisions économiques. Toutefois, cet engagement limité du président Bush sur la question du changement climatique dans les débats internationaux n’a pas pour autant réduit les capacités de mobilisation des États et des villes sur ce thème.On the issue of whether climate change should be taken into account in economic decisions, the federal administration’s attitude during the Bush Presidency sharply contrasted with the attitudes of earlier administrations, particularly in the 1960’s and 1970’s. The limited concern for climate change which the federal government exhibited in the international arena did not reduce, however, the mobilization of states and local communities on this issue.

  6. CO{sub 2}-fertilization via exhaust gas treatment of reciprocating gas engines: developments and experiences; Fertilisation au CO{sub 2} par traitement des gaz provenant de moteurs a gaz alternatifs: developpement et experience

    Energy Technology Data Exchange (ETDEWEB)

    Bekker, M.; Hoving, K.; Klimstra, J.; Top, H. [N.V. Nederlandse Gasunie (Netherlands)

    2000-07-01

    The Dutch climate is such that greenhouses are used to produce vegetables, flowers and other plants. To heat the greenhouse, boilers and combined heat and power systems (CHP) are used. CHP has a better fuel utilisation than a boiler because of the simultaneously production of heat and power. In a greenhouse, CO{sub 2} has to be added to compensate the CO{sub 2} consumed by the plants to grow. Higher CO{sub 2} concentration than ambient are being used to increase plant growth and yield. The use of 'clean' flue gas from boilers was common practice but nowadays flue gas of engines can be used after cleaning. Exhaust gas cleaning systems (EGC) based on a Selective Reduction Catalyst and an Oxidation Catalyst make this possible. This paper describes the principle of these EGCs, gives insight into the important parameters which determine the required cleanliness and discusses the research results of Gasunie Research on this topic. It is found that different catalyst makes have their own specific behaviour depending on the monolith and active material and the how the catalyst is manufactured, mechanical mixed or impregnated. The use of CHP gives a high fuel utilisation and, in combination with EGC, increased crop yields. This results in an even more efficient use of the primary fuel, natural gas. (authors)

  7. Strategies for Optimization and Automated Design of Gas Turbine Engines (Les strategies pour l’optimisation et la conception automatique de turbines a gaz)

    Science.gov (United States)

    2010-09-01

    Sep 2010 Strategies for Optimization and Automated Design of Gas Turbine Engines (Les Stratégies pour l’optimisation et la conception automatique de...Engines (Les Stratégies pour l’optimisation et la conception automatique de turbines à gaz) The material in this publication was assembled to support

  8. La modelisation mathematique dans l'enseignement de la chimie des gaz a des eleves de la cinquieme annee du secondaire

    Science.gov (United States)

    Gauthier, Diane

    Les problemes d'enseignement de la chimie des gaz parfaits sont donc importants. Si plusieurs etudes ont ete realisees dans le but d'identifier et d'interpreter ces problemes, aucune recherche, a notre connaissance, n'a ete realisee sur l'enseignement des lois sur les gaz parfaits. Notre recherche sur l'enseignement est donc pionniere. Elle a pour objectif general de construire et d'analyser une sequence d'enseignement de la chimie des gaz comportant diverses situations de modelisation mathematique des conduites des gaz. Les principaux objectifs specifiques sont les suivants: (1) identifier et caracteriser les situations qui provoquent une evolution des conceptions naives des eleves, evolution vers des connaissances plus adequate sur les gaz; (2) identifier et caractEriser les situations qui provoquent une evolution des connaissances mathematiques des eleves leur permettant d'interpreter convenablement les resultats des experiences, d'eprouver leurs conceptions, de donner un sens aux notions et aux relations impliquees dans les lois des gaz parfaits, lois de Boyle-Mariotte et Gay-Lussac. Une sequence d'enseignement comportant huit situations est d'eleves de secondaire V. La construction de ces situations est orientee par les recherches sur les conceptions naives des eleves, par les etudes sur l'evolution historique des conceptions sur les gaz et des pratiques scientifiques, ainsi que par les etudes theoriques et empiriques realisees en didactique des sciences et des mathematiques. La methodologie de l'ingenierie didactique (Artigue, 1998) qui constitue une application de la theorie des situations didactiques (Brousseau, 1986) est utilisee dans la construction et l'analyse des situations d'enseignement. Une analyse a priori de chacune des situations d'enseignement est effectuee; elle a pour but dexpliquer les choix des taches qui font partie des situations et de preciser la gestion didactique des situations. Diverses situations d'enseignement de la chimie ont ainsi

  9. Matériaux pour la production d'hydrogène

    Science.gov (United States)

    Saint-Just, J.

    2002-04-01

    L'émergence des piles à combustible et l'apparition de l'hydrogène comme carburant dans des véhicules grand public comme les autobus, suscitent un élan fort pour la mise au point de technologies nouvelles pour la production d'hydrogène décentralisée et à petite échelle. Du fait de sa richesse en hydrogène. des réserves disponibles et de son infrastructure de distribution, le gaz naturel est considéré comme la ressource majeure pouvant fournir les quantités d'hydrogène nécessaires pour un passage progressif vers une économie de l'hydrogène dans les décennies immédiates en attendant que progressivement les énergies renouvelables prennent le relais. Des solutions innovantes, incluant de nouveaux matériaux, sont nécessaires pour la mise au point des petits générateurs d'hydrogène efficaces et bon marché alimenté au gaz naturel qui sont attendus par les fabricants (le piles à combustible, les acteurs de l'énergie et les fabricants de véhicules.

  10. Un environnement multimédia privilégiant l’expression en langage naturel, pour des activités éducatives de type piagétien A multimedia environment favouring natural language expression, for educational piagetian games

    Directory of Open Access Journals (Sweden)

    Élisabeth Godbert

    2000-12-01

    Full Text Available Nous nous intéressons dans cet article au développement de logiciels éducatifs proposant, dans un environnement multimédia, multimodal et réactif privilégiant l’expression en langage naturel, des exercices de type piagétien pour l’aide à l’apprentissage du langage. Dans ce type de système, chaque exercice met en jeu un micro-monde d’objets graphiques sur lesquels l’enfant utilisateur peut agir (modification, déplacement, suppression d’objets, etc., en formulant des requêtes en langage naturel auxquelles le système répond. Nous présentons un logiciel éducatif de cette famille, que nous avons conçu et développé ces dernières années. Nous décrivons en premier lieu les objectifs pédagogiques et les fonctionnalités de notre logiciel, puis le système que nous y utilisons pour le traitement automatique du langage. Nous décrivons ensuite l’ensemble des composants qui structure les connaissances qu’il a été nécessaire de modéliser, articuler et gérer pour la réalisation de ce système.This paper deals with the development of educational software, which proposes, in a multimedia, multimodal and reactive environment favoring natural language expression, piagetian games designed for natural language learning. In such systems, each exercise brings into play a micro-world of graphic objects on which the user can act (for example to modify, move or withdraw the objects, by composing natural language queries to which the system gives an answer. We present a software of this type, that has been designed and implemented these last years. We firstly describe the educational objectives and the functionality of the software, then the natural language processing system which is used in it. Finally we describe the set of components that structures knowledge modeled, articulated and managed in order to carry out this educational system.

  11. Au pair trajectories

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2015-01-01

    Since 2000, thousands of young Filipino migrants have come to Denmark as au pairs. Officially, they are there to “broaden their cultural horizons” by living temporarily with a Danish host family, but they also conduct domestic labor in exchange for food and money, which allows them to send...

  12. Catalytic activity of Au nanoparticles

    DEFF Research Database (Denmark)

    Larsen, Britt Hvolbæk; Janssens, Ton V.W.; Clausen, Bjerne

    2007-01-01

    Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change with par......Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change...... with particle size. We find that the fraction of low-coordinated Au atoms scales approximately with the catalytic activity, suggesting that atoms on the corners and edges of Au nanoparticles are the active sites. This effect is explained using density functional calculations....

  13. Mise au point d'un reacteur epitaxial CBE

    Science.gov (United States)

    Pelletier, Hubert

    Ce projet de maîtrise consiste à l'asservissement et la mise en marche d'un réacteur d'épi-taxie par jets chimiques au Laboratoire d'Épitaxie Avancée de l'Université de Sherbrooke. Le réacteur sert à la croissance dans l'ultravide de matériaux semi-conducteurs tels que l'arséniure de gallium (GaAs) et le phosphure d'indium-gallium (GaInP). La programmation LabVIEW™ et du matériel informatique de National Instruments sont utilisés pour asservir le réacteur. Le contrôle de la température de l'échantillon et de la pression de contrôle des réactifs de croissance dans le réacteur est assuré par des boucles de rétroaction. Ainsi, la température de l'échantillon est stabilisée à ±0, 4 °C, alors que les pressions de contrôle de gaz peuvent être modulées sur un ordre de grandeur en 2 à 4 secondes, et stabilisées à ±0, 002 Torr. Le système de pompage du réacteur a été amélioré suite à des mesures de vitesse de pompage d'une pompe cryogénique. Ces mesures révèlent une dégradation sur plus d'un ordre de grandeur de son pompage d'hydrogène avec l'opération à long terme. Le remplacement de la pompe cryogénique par une pompe turbo-moléculaire comme pompe principale a permis d'améliorer la fiabilité du système de pompage du système sous vide. D'autre part, la conductance du système d'acheminement de gaz et d'injection a été augmentée afin de réduire un effet mémoire des sources le système et faciliter la croissance de matériaux ternaires. Ainsi, des croissances de GaAs (100) sur substrat de même nature ont été effectuées et ont révélé un matériau de bonne qualité. Sa rugosité moyenne de 0,17 nm, mesurée par microscopie à force atomique, est très faible selon la littérature. De plus, une mobilité élevée des porteurs est obtenue à fort dopage au silicium, au tellure et au carbone, notamment une mobilité de 42 ± 9 cm2V -1s-1 des porteurs majoritaires '(trous) lors du dopage au carbone à 1, 5 · 1019

  14. Etude d'un procédé d'hydroliquéfaction du charbon pour la production simultanée de gaz et de carburant . . . . . Studies of a Coal Hydrogenation Process to Produce CO-Currently Gas and Gasoline

    Directory of Open Access Journals (Sweden)

    Franckowiak S.

    2006-11-01

    Full Text Available Un des principaux moyens de réintroduire le charbon dans le marché énergétique français est de le transformer en produits utiles comme le gaz de réseau ou les carburants. Les procédés d'oxyvapogazéification permettent d'obtenir un gaz de synthèse qui peut être ensuite converti en gaz riche ou en produits liquides. L'hydrogénation en phase liquide (ou hydroliquéfaction se présente pour le long terme comme une seconde voie qui offre des avantages spécifiques - taux de conversion du charbon et rendement élevés, - production directe de gaz de substitution (GNS et de carburant, - possibilité d'utilisation d'hydrogène provenant de l'électricité nucléaire. Un programme d'étude a été lancé avec la participation du Gaz de France (GDF, du Centre d'études et de recherches des Charbonnages de France (Cerchar, de l'institut Français du Pétrole (lFP et du Centre National de la Recherche Scientifique (CNRS dans le cadre du Groupe d'Étude de la Conversion du Charbon par Hydrogénation (GECH. Un banc d'essai d'hydroliquéfaction situé au Cerchar, d'un débit de 10 kg/h de mélange charbon-solvant, permet d'obtenir des hydrogénats dans des conditions variées et en présence de divers catalyseurs. L'étude de la valorisation de ces hydrogénats est effectuée dans les laboratoires de l'lFP. Les essais et les études effectués permettent d'envisager la production à volonté du GNS, de carburants ou des deux ensemble. Un modèle d'optimisation a été réalisé au GDF pour étudier et comparer les différentes filières en prenant en compte l'utilisation d'hydrogène d'électrolyse ou d'hydrogène produit sur place à partir du résidu de liquéfaction. One of the main ways to bring coal in the future french energy market is to transform it into valuable products. The oxygen steam gasification processes give a synthesis gas which can be converted into SNG or gasoline in a catalytic stage. The liquid phase hydrogenation process is a

  15. Mise au point

    African Journals Online (AJOL)

    31 mai 2013 ... laryngocèle interne. Une surinfection a été notée chez trois patients réalisant ainsi le tableau de pyolaryngocèle. Tous les patients ont eu un examen clinique complet comportant un examen OrL et cervico-facial ainsi qu'un examen laryngé au ... pas en communication avec la lumière laryngée. La taille.

  16. Le CRDI au Mali

    International Development Research Centre (IDRC) Digital Library (Canada)

    sur la sécurité alimentaire internationale. Le CRDI continue de soutenir des travaux de recherche au Mali, quoique dans une moindre mesure en raison de la .... souvent tenues à l'écart du processus décisionnel. Les chercheurs tentent de déterminer de quelles manières les jeunes femmes du Mali et des pays avoisinants ...

  17. Mise au point

    African Journals Online (AJOL)

    7 mai 2012 ... Le carcinome folliculaire est la deuxième tumeur maligne la plus fréquente de la thyroïde et l'invasion hématologique est le moyen de propagation le plus courant de ses métastases. Les localisations secondaires à ces cancers siègent principalement au niveau des poumons, suivi par les localisations.

  18. Le CRDI au Maroc

    International Development Research Centre (IDRC) Digital Library (Canada)

    visant à aider les secteurs de l'agriculture et du tourisme à s'adapter aux changements climatiques. Dans le cadre de recherches antérieures sur la mise au point .... France. Les manifestations et protestations survenues après 2010 et auxquelles on a donné le nom de Printemps arabe ont été annonciatrices de profondes ...

  19. Mise au point

    African Journals Online (AJOL)

    7 mai 2012 ... EPIdEMIOlOgIE ET ETIOPAThOgENIE. Les angiodysplasies osseuses des maxillaires sont rares. Les premiers cas rapportés sont ceux de Berard qui a décrit en 1842 une localisation au niveau du maxillaire supérieur et de Stanley qui a rapporté en 1849 une loca- lisation mandibulaire. une prédisposition ...

  20. Le CRDI au Kenya

    International Development Research Centre (IDRC) Digital Library (Canada)

    et de l'agriculture. En produisant des connaissances dans ces secteurs essentiels, le programme contribuera à la sécurité alimentaire et améliorera la santé au Kenya. Les noms et les frontières indiqués sur la carte n'impliquent ni reconnaissance ni acceptation officielle de la part du CRDI. C. U. R. T. C. A. R. N. EM. A. R. K.

  1. Study of total ionization by {alpha} particles, in pure gases and gaseous mixtures containing metastable atoms, as a function of temperature; Etude de l'ionisation totale par les paricules {alpha}, dans les gaz purs et les melanges gazeux contenant des atomes metastables, en fonction de la temperature

    Energy Technology Data Exchange (ETDEWEB)

    Bristeau, P. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    effet de temperature sur W, dans les melanges gazeux binaires du type A - B contenant des atomes metastables A{sup *} et une 'impurete' B. On etudie systematiquement la variation {delta}W de W en fonction de la temperature et de la concentration de 'l'impurete' B dans les melanges Ne - Ar, Ne - Kr, Ne - H{sub 2}, Ne - N{sub 2}, Ne - CH{sub 4} et He - Ar. On realise des experiences sur un melange gazeux ternaire du type A - B - C, ou C est une deuxieme 'impurete' ionisable que l'on ajoute au melange binaire A - B, demontrant l'existence d'atomes excites B{sup *} de 'l'impurete' B. Enfin, on montre que la quantite d'atomes metastables formes dans un gaz pur, doit etre tres proche du nombre N{sub 0} de paires d'ions et qu'il doit y avoir correlation entre lenombre N{sub 0} de paires d'ions et le nombre {approx_equal} N{sub 0} d'atomes metastables crees dans les gaz rares purs. (auteur)

  2. Le profil SVP : sismique au voisinage du puits The Wvp (Well Vicinity Profiling Stack

    Directory of Open Access Journals (Sweden)

    Blondin E.

    2006-11-01

    Full Text Available L'augmentation de l'investigation latérale du PSV (profil sismique vertical et le calage de la sismique de surface au puits peuvent être améliorés en combinant un profil sismique réflexion de surface d'une mise en oeuvre particulière (à base réceptrice fixe appelé SVP (sismique au voisinage du puits et un profil sismique vertical. Dans cette mise en oeuvre combinée, la sonde n'est immobilisée que pour le temps d'acquisition du PSV. L'utilisation d'une base sismique réceptrice fixe rend la mise en oeuvre du profil SVP légère et peu onéreuse. Les résultats obtenus montrent que les résolutions verticales du profil SVP et du PSV sont équivalentes. L'investigation latérale de cette mise en oeuvre mixte est de plusieurs centaines de mètres quelle que soit la profondeur. Cette recherche méthodologique a été réalisée en collaboration avec Gaz de France. Increasing the lateral range of investigation of VSP (vertical seismic profiling and the calibration of surface seismic profiles with well geological horizons can be improved by combining a surface seismic profile having a specific implementation (with a fixed receiving base called WVP (well vicinity profiling and a vertical seismic profile. In this combined implementation, the drilling rig is immobilized only for the acquisition time of the VSP. The use of a fixed seismic receiving base makes the implementation of the WVP stack light and inexpensive. The results obtained show that the vertical resolutions of the WVP stack and of the VSP are the same. The lateral range of investigation of this mixed implementation is several hundred meters no matter what the depth may be. This methodological research was done in collaboration with Gaz de France.

  3. Experimental Investigation of the Asphaltene Deposition Process during Different Production Schemes Étude expérimentale du processus de dépôt d’asphaltènes au cours de différents modes de production

    Directory of Open Access Journals (Sweden)

    Bagheri M.B.

    2011-02-01

    Full Text Available This paper presents the results of asphaltene precipitation and deposition during lean gas injection, CO2 injection and natural depletion in reservoir conditions. In addition, the effect of variations in operating pressure, injection gas concentration and production rate on asphaltene precipitation and deposition were investigated. The severity of asphaltene deposition was found to be more pronounced in lean gas injection in comparison with CO2 injection and natural depletion. Increasing the flow rate in natural depletion experiments showed a considerable increase in asphaltene deposition, and consequently permeability reduction in the core matrix. Moreover, more asphaltene deposition was observed along the porous media in the gas injection experiments when the gas mol percent of the mixture was increased. Cet article présente les résultats d’une étude de la précipitation et du dépôt d’asphaltènes qui peuvent se produire lors d’une injection de gaz pauvre, d’une injection de CO2 ou d’une déplétion naturelle en conditions de réservoir. En outre, les effets de la pression de fonctionnement, de la concentration en gaz injecté et du débit de production sur la précipitation et le dépôt d’asphaltènes ont été étudiés. Il a été constaté que l’importance du dépôt d’asphaltènes est plus prononcée dans le cas d’une injection de gaz pauvre comparativement à une injection de CO2 ou à une déplétion naturelle. Une augmentation du débit au cours d’expériences de déplétion naturelle a montré un accroissement considérable du dépôt d’asphaltènes et, en conséquence, une réduction de perméabilité au sein de la matrice poreuse. Par ailleurs, un dépôt d’asphaltènes plus important a été observé au cours des expériences d’injection de gaz lorsque la concentration molaire gazeuse dans le mélange était augmentée.

  4. Mise au point

    African Journals Online (AJOL)

    31 mai 2013 ... L'attitude théra- peutique dépend du type de la laryngocèle. en effet, le traitement endoscopique au laser CO2 a gagné beaucoup d'intérêt ces dernières années. MATÉRIEL ET MÉTHOdES. Il s'agit d'une étude rétrospective portant sur 9 patients porteurs d'une laryngocèle colligés sur une période de 14.

  5. Le CRDI au Ghana

    International Development Research Centre (IDRC) Digital Library (Canada)

    poussée en mathématiques aux spécialistes de demain afin qu'ils puissent relever les défis pressants qui se posent en matière d'environnement, de santé et d'économie. La bourse de chercheur invité que le CRDI a octroyée en 2001 au regretté. John Atta-Mills, qui a par la suite été prési- dent du Ghana de 2009 à 2012, ...

  6. Au pairs on Facebook

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2016-01-01

    Ethnographers are increasingly making use of Facebook to acquire access and general acquaintance with their field of study. However, little has been written on how Facebook is used methodologically in research that does not have social media sites as the main focus of interest. This article argues...... that engagement with Facebook as a methodological tool can be useful in research among migrants in highly politicised fields. Pointing to a discursive construction of Filipina au pairs as victims of labour exploitation, the article shows how fieldwork on Facebook enables the exploration of the ways in which...... and on Facebook....

  7. Mise au point

    African Journals Online (AJOL)

    7 mai 2012 ... acquis et des anomalies génétiques associées ont été aussi incriminés (mutation du gène Fas ou de la p53, délétion au niveau du chromosome 6q, méthylation excessive de la p73) (15,16). Le mode de révélation de ces lymphomes est peu spéci- fique et parfois banal. L'obstruction nasale représente le.

  8. Des tubercules pour la mort: analyses préliminaires des relations entre l'ordre naturel et l'ordre culturel dans l'iconographie Mochica

    Directory of Open Access Journals (Sweden)

    1990-01-01

    Full Text Available Le but de cet article est de démontrer que c’est à partir de savantes observations du milieu naturel que les Mochicas ont puisé leur inspiration pour former leur iconographie. Il y aurait donc une corrélation entre les représentations de plantes ou d’animaux et leurs propriétés et comportements naturels. Nous explorons ici les relations entre les représentations de tubercules, d’humains, de certains animaux, et le monde mortuaire. LOS TUBÉRCULOS Y LA MUERTE. Análisis preliminares de las relaciones entre el orden natural y el orden cultural en la iconografía mochica. Se demuestra en este artículo que, para plasmar su iconografía, los Mochicas se inspiraron de sabias observaciones del medio natural. Entonces había un vínculo entre las representaciones de plantas y animales, sus propiedades y comportamientos naturales. Se indica aquí las relaciones entre las representaciones de tubérculos, de humanos, de ciertos animales, y el mundo mortuorio. TUBERS AND DEATH. Preliminary Analysis of the Relations Between the Natural and Cultural Order in Mochica Iconography. The objective of this article is to demonstrate that the Mochicas have designed their iconography system by studying closely their natural environment. Hence, there is a correlation between the natural comportments of the animals or the properties of the plants and their representations in the iconography. We explore the relation between the representations of tubers, human and animals beings, and the mortuary world.

  9. Fick Sistemini Kullanarak Dört Bilesenli Su-Gaz Degisim Reaksiyonunun Difüzyon Katsayılarının Teoriksel İncelenmesi

    Directory of Open Access Journals (Sweden)

    Murat ÖZTÜRK

    2009-04-01

    Full Text Available Bu çalısmada; izotermik kosulu saglanmıs, ideal boru reaktörde, ekzoterm, heterojen katalitik bir gaz reaksiyonu olan su-gaz degisim reaksiyonu model olarak alınarak dört bilesenli gaz difüzyonu incelenmistir. T=523 oK ve 623 oK'de dört bilesene ait on iki adet poliner difüzyon katsayısı Fick sistemi için elde edilmistir. Teoriksel olarak hesaplanan poliner difüzyon katsayıları CO mol sayısının (x1 degisim miktarına baglı olarak diyagramlar halinde sunulmustur. Bu diyagramlardan altı tanesinin karbonmonoksit mol sayısı azalınca arttıgı, diger altı tanesinin ise azaldıgı görülmüstür. Ayrıca, artan reaksiyon sıcaklıgı ile beraber difüzyon katsayılarının degerlerinde artıs oldugu tespit edilmistir.

  10. Charged particle density distributions in Au+ Au collisions at ...

    Indian Academy of Sciences (India)

    ... measured in Au + Au collisions using the BRAHMS detector at RHIC. The results are presented as a function of the collision centrality and the center of mass energy. They are compared to the predictions of different parton scattering models and the important role of hard scattering processes at RHIC energies is discussed ...

  11. IGCC, a queer plant for a clean power; La gazeification integree a un cycle combine. Une usine a gaz au pays de l'energie propre

    Energy Technology Data Exchange (ETDEWEB)

    Chevennement, E.; Lora Ronco, Th. [Electricite de France (EDF), 78 - Chatou (France). Dept. Machines et Systemes de Production

    1999-10-01

    Integrated Gasification Combined Cycle (IGCC) is a thermal power generation technology which allies partial oxidation of several types of feedstocks (coal, heavy oil residues, biomass) to gas turbines. It includes a wide range of processes and shows a high efficiency and very good environmental performance. IGCC has been held for several demonstration plants and EDF takes part in two of these projects: Puertollano (coal/peat-coke) and Varnamo (biomass). Now, one development path that must be considered is the heavy oil residues gasification, which can be used to produce power but also steam and hydrogen, on industrial sites. IGCC takes advantage of the gas turbines; nevertheless, its future is dependent on the decrease in the costs that remain relatively high, for coal at least, compared with competing technologies. (authors)

  12. Hydrogen in all its states: from solid to gas and liquid; L'hydrogene dans tous ses etats: du solide au gaz en passant par le liquide

    Energy Technology Data Exchange (ETDEWEB)

    Latroche, M.; Joubert, J.M.; Cuevas, F.; Paul-Boncour, V.; Percheron-Guegan, A. [Institut de Chimie et des Materiaux Paris-Est, Chimie Metallurgique des Terres Rares (CMTR-ICMPE-UMR 7182), CNRS, 94 - Thiais (France)

    2007-07-01

    Hydrogen is considered as one of the future energy vector. Several means of hydrogen storage are presented here: physical solutions (compression, liquefaction) and chemical solutions (adsorption in porous solids and absorption in chemical hydrides). Each of these means presents advantages and disadvantages according to economical, energetic, specific capacity, safety and sorption/desorption kinetics criteria. (O.M.)

  13. Integrated natural gas pipeline control and customer service system of Gasum; Le systeme integre de controle des canalisations de gaz et de service au consommateur chez Gasum

    Energy Technology Data Exchange (ETDEWEB)

    Aho, J.; Manty, O.; Ahlnas, B. [Gasul Oy (Finland)

    2000-07-01

    Due to the rapid development of the information technology, ageing is not the only driving force for replacing old computer systems with more sophisticated ones. The Finnish natural Gas company, Gasum Oy, has recently taken into use a new control and monitoring system for natural gas pipeline. A special customer service system, developed by Gasum Oy, is closely connected to monitoring system. It provides up-to-date information to all customers of Gasum Oy. The information is layered in three confidential levels: general information, operational data and invoicing information. The system is operating interactively in confidential Extranet. Inside Gasum Oy to meet the needs of departments outside the control room, a new GID system is developed. GID is a way to present pipeline process data and its further modifications with a very user-friendly interface based on geographical map. The system is based on data warehouse architecture and it is working on company's Intranet. This makes it possible to present various secrecy level information based on user ID. Gasum's new SCADA is not only the base for operating the pipeline, but it also provides lot of vital information to other systems serving different user groups within natural gas business in Finland. (authors)

  14. Development and training for the professional of the gas distribution industry in Brazil; Formation des professionnels de l'industrie de la distribution du gaz au Bresil

    Energy Technology Data Exchange (ETDEWEB)

    Hatsumi Nagato, D. [Workout Energy Business (Brazil)

    2000-07-01

    This work will present a Training and Development model for professionals of the gas distribution industry. Today's there are not schools developing gas related subjects. It's important to give to the future gas man, the knowledge needed to develop their activities. This can be achieved by focusing on criteria based on The Competency Concept and Learning Organization. To develop professional 'competency' we consider this tree of basic points: to know, to know how to do and wish to do ( willing ). We are going to present the 'minimum' 'competences' required for gas distribution companies and the methods used to qualify people for emergent gas industries, considering basically four professionals groups: workers, technicians, engineers and managers. (author)

  15. Government information report to the parliament. The gas distribution in France; Rapport d'information du gouvernement au parlement. La desserte en gaz du territoire francais

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-11-01

    This report evaluates the gas distribution state in France and presents the forecasts of the gas energy use development by the gas utilities users. In this framework the following points are presented: the juridical aspects of the gas distribution, the national plan of distribution, the new legislation occurring from the gas market deregulation and some statistical data on the gas use, consumption and demand in France. (A.L.B.)

  16. Poultry farming buildings. Natural gas heating. Guidebook of installation rules; Batiments d`elevage avicole. Chauffage au gaz. Guide des regles d`installation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The technical and economical performances of a poultry farm are greatly influenced by the mastery of ambient temperature during the first days of husbandry. The natural gas space heating installation must answer these requirements and also respect all safety rules concerning the personnel and the animals. In order to answer the questions of poultry farming professionals, the technical association of the natural gas industry (ATG) in France and the Groupama insurance company have redefined the new version of this brochure which integrates the recent technological advances and defines the minimum quality and safety rules required to achieve a natural gas heating installation. The different topics presented are: the gas supply (aerial fixed reservoirs), the general distribution panel (location, command systems, regulation systems for LPG installations, electrical equipments), the distribution pipes (general supply, indoor pipes, flexible pipes, pipe fittings), the heating systems (power, choice, power supply, fastening, air renewal), the check and sign and the start-up of the installation, the periodical control and maintenance operations. (J.S.)

  17. Magnetoresistance of Au films

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, D. L., E-mail: zhangdl@iphy.ac.cn; Song, X. H.; Zhang, X. [Institute of Physics, Chinese Academy of Sciences, Beijing 10081 (China); Zhang, X.-G., E-mail: xgz@ufl.edu [Department of Physics and Quantum Theory Project, University of Florida, Gainesville, Florida 32611 (United States); Center for Nanophase Materials Sciences and Computer Science and Mathematics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6493 (United States)

    2014-12-14

    Classical magnetoresistance (MR) in nonmagnetic metals are conventionally understood in terms of the Kohler rule, with violation usually viewed as anomalous electron transport, in particular, as evidence of non-Fermi liquid behavior. Measurement of the MR of Au films as a function of temperature and film thickness reveals a strong dependence on grain size distribution and clear violation of the Kohler rule. Using a model of random resistor network, we show that this result can be explained if the MR arises entirely from inhomogeneity due to grain boundary scattering and thermal activation of grain boundary atoms. Consequently, the Kohler rule should not be used to distinguish normal and anomalous electron transport in solids.

  18. Production of Methanol-Higher Alcohol Mixtures from Natural Gas via Syngas Chemistry Production de mélanges méthanol-alcools supérieurs à partir du gaz, via (CO + H2

    Directory of Open Access Journals (Sweden)

    Courty P.

    2006-11-01

    Full Text Available Despite the prevailing position of ethers (MTBE, TAME as octane boosters, and the low oil prices at present, alcohol synthesis remains one of the near future means of natural gas upgrading via syngas chemistry. After a review of the available process development data in the field, this paper focuses on the IFP process studies, based on the CuCo and CuNi catalysts developed by Institut Français du Pétrole (IFR, France and Idemitsu Kosan (Japan. The adequacy between the product specifications, and the optimization of the performances is then discussed in a technico-economic context, together with a presentation of lab scale, pilot scale and demonstration scale test results. As a conclusion, a prospective overall view brings together todays economics and some improvement guidelines dealing with investments, operating cost and catalyst performances. Cette publication présente les travaux de R & D (Recherche et Développement menés par l'Institut Français du Pétrole (IFP, France et Idemitsu Kosan (Japon en synthèse d'alcools. Elle situe les résultats dans le contexte technique et économique actuel. L'accroissement constant des ressources prouvées en gaz et, chronologiquement, les deux crises pétrolières, la suppression du plomb dans les essences, ont conduit le monde industriel à intensifier les recherches concernant la synthèse d'alcools. Très récemment, les effets bénéfiques de l'addition d'alcools sur les émissions de polluants ont été mis en évidence. Toutefois, l'additivation de carburants par les alcools est en voie de disparition au profit des éthers, alors que, indépendamment, les procédés de production d'ammoniac, de méthanol, d'acide acétique, également fondés sur le gaz, se sont seuls développés. La synthèse d'alcools a fait l'objet de nombreux travaux, résumés dans les tableaux 1 et 2. L'étude des différents aspects réactionnels amène à prendre en compte l'exothermicité importante des r

  19. Synthesis of a polycyclic aromatic hydrocarbon marked with carbon-14: (b, d e f) dibenzo-chrysene {sup 14}C-7,14; Synthese d'un hydrocarbure aromatique polycyclique marque au carbone 14: le dibenzo (b, d e f) chrysene {sup 14}C-7,14

    Energy Technology Data Exchange (ETDEWEB)

    Chatelain, G. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    (b, d e f) dibenzo-chrysene C-7,14 has been synthesized from radioactive carbon dioxide and the organic magnesium compound derived from 1,5 dibromo naphthalene. The product has been purified by a very precise series of fractionated chromatographs on alumina having a chromatographic activity. This has necessitated the development of a special technique. (author) [French] Le dibenzo (b, d e f) chrysene 14C-7,14 a ete synthetise au depart de gaz carbonique radioactif et de bis-organomagnesien derive du dibromo-1,5 naphtalene. Le produit a ete purifie par une serie de chromatographies fractionnees sur alumine d'activite chromatographique tres precise. Ceci a fait l'objet d'une mise au point de technique. (auteur)

  20. Multifragmentation in Au + Au collisions studied with AMD-V

    Energy Technology Data Exchange (ETDEWEB)

    Ono, Akira [Tohoku Univ., Sendai (Japan). Faculty of Science

    1998-07-01

    AMD-V is an optimum model for calculation of multifragmentation in Au + Au collisions. AMD-V consider anti-symmetry of incident nucleus, target nucleus and fragments, furthermore, it treat the quantum effect to exist many channels in the intermediate and final state. 150 and 250 MeV/nucleon incident energy were used in the experiments. The data of multifragment atom in {sup 197}Au + {sup 197}Au collisions was reproduced by AMD-V calculation using Gognny force, corresponding to the imcompressibility of nuclear substance K = 228 MeV and its mean field depend on momentum. When other interaction (SKG 2 force, corresponding to K = 373 KeV) was used an mean field does not depend on momentum, the calculation results could not reproduce the experimental values, because nucleus and deuteron were estimated too large and {alpha}-particle and intermediate fragments estimated too small. (S.Y.)

  1. 1648-IJBCS-Article-Dedjiho Comlam Achille

    African Journals Online (AJOL)

    hp

    transporter les gaz respiratoires (Dovonou,. 2008). Des teneurs de phosphore dans l'eau supérieures à 0,5 mg/L doivent ... naturel malheureusement amplifié par les activités humaines. L'azote et le phosphore en sont les principaux ... production de gaz toxiques. Selon Mama. (2010), la prolifération des plantes aquatiques.

  2. Face au risque

    CERN Document Server

    Grosse, Christian; November, Valérie

    2007-01-01

    Ce volume collectif sur le risque inaugure la collection L'ÉQUINOXE. Ancré dans l'histoire pour mesurer les continuités et les ruptures, il illustre la manière dont les sciences humaines évaluent et mesurent les enjeux collectifs du risque sur les plans politiques, scientifiques, énergétiques, juridiques et éthiques. Puisse-t-il nourrir la réflexion sur la culture et la prévention du risque. Ses formes épidémiques, écologiques, sociales, terroristes et militaires nourrissent les peurs actuelles, structurent les projets sécuritaires et constituent - sans doute - les défis majeurs à notre modernité. Dans la foulée de la richesse scientifique d'Equinoxe, L'ÉQUINOXE hérite de son esprit en prenant à son tour le pari de contribuer - non sans risque - à enrichir en Suisse romande et ailleurs le champ éditorial des sciences humaines dont notre société a besoin pour forger ses repères. Après Face au risque suivra cet automne Du sens des Lumières. (MICHEL PORRET Professeur Ordinaire à la F...

  3. Gazéification de la biomasse en double lit fluidisé circulant : étude des réactions élémentaires de gazéification et de combustion du char et de reformage des goudrons

    OpenAIRE

    Morin, Mathieu Pierre

    2017-01-01

    La conversion thermochimique à haute température (>700°C) de la biomasse en double lit fluidisé circulant est une voie alternative aux énergies fossiles (pétrole, charbon) pour la production d’un gaz de synthèse à haute valeur énergétique, utilisable dans de nombreuses applications. L’objectif de cette thèse est de développer des méthodologies et des outils théoriques et expérimentaux permettant d’accéder aux cinétiques des transformations élémentaires (pyrolyse de la biomasse, gazéification ...

  4. Contribution to the activation analysis of the rare gases. Contribution to the analysis of carbon monoxide and water vapour in gases (1963); Contribution a l'analyse par activation des gaz rares. Contribution a l'analyse de l'oxyde de carbone et de la vapeur d'eau dans les gaz (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Diebolt, J. [Commisariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1963-07-15

    In the present work, we have applied radioactive analysis to the general technique of rare gas separation. This separation is carried out on active charcoal, at constant pressure. The desorption of the gas is caused by an increase in the initial temperature of adsorption. These separations are quantitative and can be confirmed by chemical analysis. The volumes of desorbed gas are measured by radioactive counting. We have also used radioactivation to study the reduction of palladous chloride by carbon monoxide. Since this reduction is quantitative, we can have a knowledge of the mass of palladium reduced by measuring its activity. We have used the property which have organic chlorides of being hydrolysed by water vapour and of liberating hydrochloric acid to study quantitatively the amount of water vapour which a gas contains. The hydrochloric acid formed is measured by activation of the chlorine in the acid. (author) [French] Dans les travaux que nous presentons, nous avons applique l'analyse par radioactivation, a la technique generale de separation des gaz rares. Cette separation est faite sur charbon active, a pression constante. La desorption des gaz est provoquee par une augmentation de la temperature initiale d'adsorption. Ces separations sont quantitatives, et peuvent etre exploitees par l'analyse chimique. Les volumes de gaz dedorbes sont mesures par comptage de la radioactivite. Nous avons egalement utilise la radioactivation pour l'etude de la reduction du chlorure palladeux par l'oxyde de carbone. Cette reduction etant quantitative, nous pouvons connaitre la masse de palladium reduit par la mesure de son activite. Nous avons exploite la propriete que possede un chlorure organique d'etre hydrolise par la vapeur d'eau et de liberer de l'acide chlorhydrique pour etudier quantitativement la vapeur d'eau contenue dans un gaz. L'acide chlorhydrique forme est mesure par l'activation du chlore de l

  5. Chiral magnetic effect search in p+Au, d+Au and Au+Au collisions at RHIC

    Science.gov (United States)

    Zhao, Jie; STAR Collaboration

    2017-09-01

    The chiral magnetic effect (CME) is a fundamental property of QCD. A major background source for CME measurements is the intrinsic particle correlations (such as resonances/jets decay) coupled with the azimuthal elliptical anisotropy v2. In heavy-ion collisions, the magnetic field direction and event plane azimuthal angle Ψ2 are correlated, thus the CME and the v2-induced background are entangled. In small system p+Au and d+Au collisions, the Ψ2 is mostly due to geometry fluctuations, and thus magnetic field direction and Ψ2 are uncorrelated. The correlation measurements in small system collisions with respect to Ψ2 are only sensitive to v2-induced background while any CME is averaged to zero. In this talk, we will present the STAR measurements of two-particle correlations with respect to Ψ2 in p+Au, d+Au and Au+Au collisions at √{sNN} = 200 GeV. These results are analyzed as a function of particle multiplicity to shed light on the background contaminations of the CME measurements in heavy-ion collisions. We will also report results from a new analysis approach as a function of the particle pair invariant mass in order to suppress non-CME related physics backgrounds.

  6. The Hydrodynamic Characteristics of Cocurrent Downflow and Cocurrent Upflow Gas-Liquid-Solid Catalytic Fixed Bed Reactors: the Effect of Pressure Les caractéristiques hydrodynamiques des réacteurs gaz-liquide-solide à lit de catalyseur fixe à écoulement cocourant montant et descendant : l'influence de la pression

    Directory of Open Access Journals (Sweden)

    Wild G.

    2006-11-01

    ésultats de quelques années de recherches expérimentales sur les caractéristiques hydrodynamiques des réacteurs à écoulement cocourant ruisselant et enfin de réacteurs en cocourant montant. Au cours des dernières années, des résultats ont également pu être obtenus sous des pressions pouvant aller jusqu'à 8 MPa, les mesures étant faites à petite échelle (23 mm de diamètre dans une maquette froide. Différents liquides aqueux et organiques plus ou moins visqueux, éventuellement inhibiteurs de coalescence, 4 gaz et un certain nombre de particules plus ou moins mouillables non poreuses ont été utilisés. La rétention liquide a, dans tous les cas, été déterminée en mesurant la distribution des temps de séjour de la phase liquide, à l'aide de différents traceurs. Les conclusions suivantes ont pu être tirées : - Pour le régime à forte interaction, c'est l'inertie du gaz et des phases liquides qui constitue la cause principale de la dissipation d'énergie mécanique. Dans ce régime, les résultats obtenus en cocourant montant et descendant sont à peu près identiques. - La plupart des corrélations relevées dans la littérature ne permettent pas de prévoir l'influence de la pression sur la chute de pression ou la retenue liquide. - La viscosité du gaz n'influence pas l'hydrodynamique. Il est donc possible de simuler, par exemple, l'hydrogène sous forte pression par un autre gaz de même densité (à pression beaucoup plus basse. Une étude critique des corrélations et/ou des modèles de la littérature est présentée du point de vue de leur aptitude à représenter les différentes caractéristiques en fonction de la pression.

  7. Can-rupture detection in gas-cooled nuclear reactors; La detection des ruptures de gaine dans les piles nucleaires refroidies par gaz

    Energy Technology Data Exchange (ETDEWEB)

    Roguin, A. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    Can-rupture detection (DRG) is one important aspect of pile safety, more particularly so in the case of gas-cooled reactors. A rapid and sure detection constitutes also an improvement as far as the efficiency of electricity-producing nuclear power stations are concerned. Among the numerous can-rupture detection methods, that based on the measurement of the concentration of short-lived fission gases in the heat-carrying fluid has proved to be the most sensitive and the most rapid. A systematic study of detectors based on the electrostatic collection of the daughter products of fission gases has been undertaken with a view to equip the reactors EL 2, G 3, EDF 1, EDF 2 and EDF 3, the gas loops of PEGASE and EL 4. The different parameters are studied in detail in order to obtain a maximum sensitivity and to make it possible to construct detection devices having the maximum operational reliability and requiring the minimum maintenance. The primary applications of these devices are examined in the case of the above-mentioned reactors. (author) [French] La Detection des Ruptures de Gaines (D. R. G.) est un aspect important de la securite des piles et plus particulierement des piles refroidies par un gaz. Une detection rapide et sure constitue aussi un element d'amelioration du rendement des centrales nucleaires productrices d'energie electrique. Parmi les nombreuses methodes de detection des ruptures de gaines, la mesure de la concentration dans le fluide caloporteur des gaz de fission a vie courte s'est revelee comme la plus sensible et la plus rapide. Une etude systematique des detecteurs a collection electrostatique des descendants des gaz de fission a ete entreprise en vue d'equiper les piles EL 2, G 3, EDF 1, EDF 2 et EDF 3, les boucles a gaz de la pile Pegase et la pile EL 4. Les divers parametres sont etudies en detail pour obtenir une sensibilite maximum et permettre la realisation de dispositifs de detection ayant le maximum de securite de

  8. Les ultrasons en procédés polyphasiques : transfert Gaz-Liquide, réaction Liquide-Liquide

    OpenAIRE

    Laugier, Frédéric

    2007-01-01

    Les ultrasons de puissance sont connus pour augmenter la conversion et/ou la cinétique de nombreuses réactions chimiques polyphasiques grâce aux effets mécaniques de la cavitation : augmentation de l'aire interfaciale, accroissement du transfert autour des particules et gouttes... Dans le cadre de réactions catalytiques polyphasiques (gaz/liquide/liquide comme l'hydroformylation en catalyse biphasique), les ultrasons ont un effet sur les pseudo-solubilités, et les transferts ga...

  9. Éditorial

    Directory of Open Access Journals (Sweden)

    2006-12-01

    Full Text Available La livraison n° 13 des Chroniques yéménites, avec sa moisson de nouvelles études, accompagne et reflète tout particulièrement l'actualité des recherches françaises, ainsi que les évolutions les plus récentes de la société yéménite et de la région : . L’archéologie préventive est en train de se développer au Yémen, en particulier grâce au projet d’exploitation industrielle du gaz naturel (Yemen LNG, sur lequel les archéologues du CEFAS, notamment Rémy Crassard, sont intervenus en 2005-2006, e...

  10. Borophene synthesis on Au(111)

    Science.gov (United States)

    Guisinger, Nathan; Kiraly, Brian; Zhang, Zhuhua; Mannix, Andrew; Hersam, Mark C.; Yakobson, Boris I.

    The recent experimental discovery of borophene, the metallic 2-dimensional allotrope of boron, has sparked tremendous interest in further exploration of this unique material. The initial synthesis of borophene was accomplished on Ag substrates and serves as a quintessential example of predictive modeling to experimental realization. In this talk, we expand the phase-space of borophene synthesis to Au. Borophene synthesis was accomplished by evaporating elemental boron onto a Au(111) substrate. The synthesized borophene retains its metallic character on Au as verified with scanning tunneling spectroscopy. Most fascinating is the difference in growth dynamics on the Au(111) substrate where the reconstructed surface presents a unique energy landscape for borophene nucleation and growth. We find that the initial low-coverage growth of borophene modifies the herringbone reconstruction into a ``trigonal'' network, where the 2D boron islands are uniformly templated across the surface. Increasing coverage results in the increasing size of the templated borophene islands until they coalesce into larger sheets. The observed growth dynamics are supported by the computational modeling of boron nucleation on Au.

  11. L’apprentissage au cern

    CERN Multimedia

    2007-01-01

    pour les professions d’électronicien(ne) et de laborantin(e) en physique L’apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le canton de Genève. En cas de réussite à l’examen de fin d’apprentissage, les apprentis obtiennent le Certificat fédéral de capacité suisse (CFC). 6 places au total sont ouvertes au recrutement pour les deux professions. L’apprentissage dure 4 ans. Minima requis pour faire acte de candidature : avoir au moins 15 ans et moins de 21 ans à la date de début de l’apprentissage ; avoir terminé la scolarité obligatoire, au minimum 9e du Cycle d’orientation genevois (3e en France) ; être ressortissant d’un pays membre du CERN (Allemagne, Autriche, Belgique, Bulgarie, Danemark, Espagne, Finlande, France, Grèce, Hongrie, Italie, Norvège, Pays-Bas, Pologne, Portugal, Royaume-Uni, République tchèque, République slovaque , Suède, Suisse) ; pour les résidents en Suisse : être ressortissant su...

  12. Transverse Velocity Scaling in Au+Au Fragmentation

    OpenAIRE

    Lukasik, J.; Hudan, S.; Lavaud, F.; Turzo, K.; Auger, G.; Bacri, Ch.O.; Begemann-Blaich, M.L.; Bellaize, N.; Bittiger, R.; Bocage, F.; Borderie, B.; Buchet, P.; R. Bougault(LPCC); Bouriquet, B.; Charvet, J. L.

    2002-01-01

    Invariant transverse-velocity spectra of intermediate-mass fragments were measured with the 4-pi multi-detector system INDRA for collisions of Au on Au at incident energies between 40 and 150 MeV per nucleon. Their scaling properties as a function of incident energy and atomic number Z are used to distinguish and characterize the emissions in (i) peripheral collisions at the projectile and target rapidities, and in (ii) central and (iii) peripheral collisions near mid-rapidity. The importance...

  13. Report made on behalf of the commission of economic affairs about the proposal of law aiming at authorizing the end-users to get back to the regulated power supply tariff, about the proposal of law aiming at authorizing the reversibility of the use of eligibility rights for the purchase of electric power, and about the proposal of law aiming at preserving the purchasing power of households by maintaining the regulated prices of electricity and natural gas; Rapport fait au nom de la commission des Affaires economiques sur la proposition de loi tendant a autoriser les consommateurs particuliers a retourner au tarif reglemente d'electricite, la proposition de loi reversibilite de l'exercice des droits relatifs a l'eligibilite pour l'achat d'energie electrique et la proposition de loi tendant a preserver le pouvoir d'achat des menages en maintenant les tarifs reglementes de vente d'electricite et de gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    This report concerns the examination of three proposals of law in relation with the regulated prices of electricity and gas. Since July 1, 2007, the French households can freely quit their historical energy supplier and subscribe to other suppliers with de-regulated energy prices. In front of the rise of free energy prices observed during the last years, some households who made the choice of free tariffs have encountered serious financial problems. For this reason, a law is proposed by the commission of economic affairs which aims at allowing the end-users to get back to the regulated tariffs of electricity and gas. (J.S.)

  14. Multiscale Modeling of Au-Island Ripening on Au(100

    Directory of Open Access Journals (Sweden)

    Karin Kleiner

    2011-01-01

    Full Text Available We describe a multiscale modeling hierarchy for the particular case of Au-island ripening on Au(100. Starting at the microscopic scale, density functional theory was used to investigate a limited number of self-diffusion processes on perfect and imperfect Au(100 surfaces. The obtained structural and energetic information served as basis for optimizing a reactive forcefield (here ReaxFF, which afterwards was used to address the mesoscopic scale. Reactive force field simulations were performed to investigate more diffusion possibilities at a lower computational cost but with similar accuracy. Finally, we reached the macroscale by means of kinetic Monte Carlo (kMC simulations. The reaction rates for the reaction process database used in the kMC simulations were generated using the reactive force field. Using this strategy, we simulated nucleation, aggregation, and fluctuation processes for monoatomic high islands on Au(100 and modeled their equilibrium shape structures. Finally, by calculating the step line tension at different temperatures, we were able to make a direct comparison with available experimental data.

  15. Optimisation exergo-économique d’une turbine à gaz Exergoeconomic Optimization of a Gas Turbine

    Directory of Open Access Journals (Sweden)

    Dobrovicescu A.

    2012-09-01

    Full Text Available Ce travail concerne l’optimisation exergo-économique d’une turbine à gaz. La méthode d’optimisation exergo-économique est comparée avec la méthode thermoéconomique. Il est mis en évidence que l’optimisation exergoéconomique offre des études et raisonnements supplémentaires qui ne sont pas disponibles en se limitant à une optimisation énergétique classique. L’objectif d’une optimisation exergo-économique d’un système énergétique est de trouver la structure optimale et les paramètres de fonctionnement optimum qui minimisent le coût global du système, sous des contraintes imposées de fonctionnement, de maintenance et d’impact sur l’environnement. Cette optimisation est réalisée en étudiant l’évolution de paramètres exergétiques locaux et globaux. The paper deals with the exergoeconomic optimization of a gas turbine system. A parallel between thermoeconomic and exergoeconomic optimization is carried on. It is pointed out that exergoeconomics offers additional capabilities in optimization that are not available with the conventional technic optimization. The goal of exergoeconomic design optimization of an energy systems is to find the structure and the values of the system parameters that minimize the cost of final products considering restrictions imposed by the desired reliability, maintainability, operability and environmental impact of the system, using local or global exergetic parameters.

  16. Measurements and Application of Partition Coefficients of Compounds Suitable for Tracing Gas Injected Into Oil Reservoirs Mesures et applications des coefficients de partage de composants utilisables comme gaz traceurs injectés dans des réservoirs de pétrole

    Directory of Open Access Journals (Sweden)

    Dugstad O.

    2006-11-01

    connaissance de ce phénomène est importante pour une interprétation optimale des essais de traceurs réalisés in-situ. Cette ségrégation est quantifiée à l'aide du coefficient de partage. On présente un modèle mono-dimensionnel permettant de prévoir la vitesse d'écoulement du traceur en fonction du coefficient de saturation, du coefficient de partage et de la fraction écoulée lors de l'injection discontinue d'un traceur dans un milieu poreux. On a étudié deux traceurs chimiques, le perfluorométhylcyclopentane (PMCP et le perfluorométhylcyclohexane (PMCH, ainsi qu'un composé radioactif, de l'éthane marqué au 14C. Les deux composés chimiques sont nouveaux comme traceurs appliqués aux réservoirs; la littérature disponible ne fait état d'aucun résultat in-situ qui aurait été obtenu avec ces substances. Les hydrocarbures fluorés sont intéressants comme traceurs potentiels du fait de leur stabilité, y compris dans les conditions caractéristiques des réservoirs, et de leur très faible seuil de détection lorsqu'ils sont analysés par chromatographie en phase gazeuse associée à un détecteur à capture d'électrons. La meilleure sensibilité à la détection est obtenue pour les composés cycliques polyfluorés comportant une ou plusieurs chaînes latérales, ce qui est le cas pour le PMCP et le PLCH. Notre groupe a récemment utilisé avec succès ses deux composés comme traceurs dans un réservoir de la mer du Nord. Le PMCP, le PMCH et l'éthane marqué au 14C ont été étudiés à l'aide d'essais dynamiques. Le milieu poreux utilisé est un tube de 6 m de long, d'un diamètre intérieur, de 0,5 cm rempli de sable d'Ottawa. On rince le tube jusqu'à l'obtention de decane puis on injecte une quantité finie de traceur dans le gaz vecteur, juste à l'amont de l'entrée du tube mince. Les figures 4 et 5 donnent les courbes de réponse types de traceur dans le gaz effluent. Les figures montrent que le traceur de référence, du méthane marqué au

  17. Order of the 27 October 2006 relative to the national urgency measures aiming to guarantee the supplying security of the natural gas in crisis; Arrete du 27 octobre 2006 relatif aux mesures nationales d'urgence visant a garantir la securite de l'approvisionnement en gaz naturel en cas de crise

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-11-15

    The dispositions of this order and of the associated national urgency concern a crisis prevention and the management of the country natural gas supplying. The concerned articles are presented. The national urgency plan is detailed: the legal framework, the principles and organization of the national urgency device, the organization of the crisis cell and the typology of the urgency measures. (A.L.B.)

  18. Law proposal aiming at imposing the domestic consumption tax to the natural gas used for hydrogen generation for petroleum refining purposes; Proposition de loi visant a soumettre a la taxe interieure de consommation le gaz naturel utilise pour la production d'hydrogene a des fins de raffinage petrolier

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-04-15

    In France, natural gas benefits from tax exemptions in several situations and in particular when used as raw material for hydrogen generation, which in turn, is used for crude oil refining and fuels generation. However, crude oil is cheaper when it is heavier but more hydrogen, and thus more natural gas, is needed to refine it and more CO{sub 2} is released in the atmosphere. Therefore, refining cheap crude oil increases the refining margins of oil companies but their environmental impact as well. The aim of this law proposal is to impose the domestic consumption tax to natural gas when used in oil refining processes in order to finance the development of the renewable hydrogen industry through the creation of a High Council of Hydrogen Industry. This High Council would be in charge of promoting the development of renewable hydrogen production facilities and distribution circuits, of hydrogen-fueled vehicles, and of fuel cells. (J.S.)

  19. Analysis of conditions concerning the natural gas internal market organization in four european countries: Germany, Spain, Netherlands and United Kingdom; Analyse des conditions encadrant l'organisation du marche interieur du gaz naturel dans quatre pays europeens: Allemagne, Espagne, Pays-Bas, Royaume-Uni

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-02-01

    The aim of this economic study is the wording of a synthetic document for the public information in the framework of the 98/30/CE european directive transposition to the gas internal market. It is writing in four main chapters, one for each country concerned: the Germany, the Spain, the Netherlands and the United Kingdom. Each one presents the historical context, the actors of the natural gas industry and the main provisions. (A.L.B.)

  20. The opening of electricity and gas markets to residential customers. Annual barometer - First wave. December 2007; L'ouverture des marches de l'electricite et du gaz naturel pour les clients residentiels. Barometre annuel - vague 1. Decembre 2007

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    Since July 1, 2007, French residential customers can freely chose their energy supplier. A quantitative inquiry has been carried out by LH2 on behalf of the French Energy Regulatory Commission (CRE) on a sample of 1501 households representative of the overall French households. The aim of this barometer is to answer the following questions: what is the level of knowledge and information of individuals about the opening of energy markets and the new regulation in force? How do they perceive this opening? What is their behaviour in front of the opening of markets to competition? Four years after the full opening of energy markets, this first inquiry has permitted to draw up a first status of the knowledge, behaviour and opinion of individuals with respect to the opening of these markets. (J.S.)

  1. Surface Gas Geochemistry above the Natural CO{sub 2} Reservoir of Montmiral (Drome, France), Source Tracking and Gas Exchange between the Soil, Biosphere and Atmosphere; Echanges gazeux et geochimie des gaz a la surface du reservoir naturel profond de CO{sub 2} de Montmiral (Drome)

    Energy Technology Data Exchange (ETDEWEB)

    Gal, F.; Le Pierres, K.; Brach, M.; Braibant, G.; Beny, C. [Bureau de Recherches Geologiques et Minieres (BRGM), 45 - Orleans (France); Battani, A.; Jeandel, E.; Tocque, E.; Benoit, Y. [Institut francais du petrole, IFP, 92 - Rueil-Malmaison (France); Pokryszka, Z.; Charmoille, A.; Bentivegna, G. [Institut National de l' Environnement Industriel et des Risques (INERIS), Parc Technologique ALATA, 60 - Verneuil-en-Halatte (France); Pironon, J.; De Donato, P.; Garnier, C.; Cailteau, C.; Barres, O.; Radilla, G.; Bauer, A. [Institut National Polytechnique de Lorraine (INPL), 54 - Vandoeuvre-les-Nancy (France)

    2010-07-15

    One of the options considered to mitigate greenhouse gas concentrations in the atmosphere is underground storage of CO{sub 2}. There is a strong need for enhancing and developing methods that would help throughout the duration life of such underground storage, to ensure the safety and able to monitor the evolution of the injected CO{sub 2} plume. Among these, geochemical methods can play an important role. Here, we describe results acquired under the research programme 'Geocarbone-Monitoring', partially funded by the French National Research Agency, on the Montmiral natural analogue in South-Eastern France. Other results obtained under the same research programme in the French Massif Central are reported elsewhere in this volume. Spot sampling methods allowing a great geographical coverage and continuous measurements on selected points were undertaken in 2006 and 2007, in order to determine soil gas concentrations and fluxes as well as carbon isotope ratio determinations. One important result is that without any evidence of deep CO{sub 2} leakage, both CO{sub 2} concentrations and fluxes appear to be higher than can be explained only by biological activities. Further investigations are thus needed to understand the gas evolution better throughout the year. (authors)

  2. Prognosis, prospecting and development of gas fields in the far north of Siberia - as a single methodological approach to an optimal development of the territorial resources; Prevision, prospection et developpement des champs de gaz naturel du grand nord Siberien - approche methodologique unique pour un developpement optimal des ressources du territoire

    Energy Technology Data Exchange (ETDEWEB)

    Remizov, V.V.; Dmitrievsky, A.N.; Ermilov, O.M.; Neelov, Y.V.; Chugunov, L.S.; Gurari, F.G.; Goldin, S.V.; Karagodin, Y.N. [OJSC Gaprom, Russian Academy of Sciences (Russian Federation)

    2000-07-01

    This presentation realizes a systems approach to the study of the oil and gas complex of the Far North of Siberia as a single sophisticated system starting from prognosis and prospecting of fields to their development at different stages of operation. This paper shows for the first time the whole complex of studies, including the methodology of systems studies of the structure, evolution and genesis of oil and gas reservoirs, the model of geologic structure and the evaluation of oil and gas resources, the technique of prospecting and surveys of oil and gas fields, techniques and methods of an effective system of prospecting and development, particularly at the stage of achieving maximum and the onset of production decrease. (authors)

  3. The opening of electricity and natural gas markets to residential clients. Yearly barometer - run 2. December 2008; L'ouverture des marches de l'electricite et du gaz naturel pour les clients residentiels. Barometre annuel - vague 2. Decembre 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-12-15

    The opening of energy markets to competition became effective to individuals ('residential clients') on July 1, 2007 with the possibility to freely choose their energy supplier. This opening of energy markets to residential clients started 3 years after the opening to professionals (July 1, 2004). The Commission of energy regulation (CRE) and the national energy Ombudsman have set in place in 2007 a quantitative yearly survey ('barometer') addressed to residential clients in order to collect statistical data about the behaviour of these clients with regards to the opening of markets to competition. This document deals with the results of the fourth run of this survey carried out from November 10 to November 20, 2008 by the LH2 institute. For the 1502 households investigated, LH2 has questioned the person in charge of the energy bills management. The barometer aimed at answering the following questions: - what is the level of knowledge and information of residential clients about markets opening and the existing regulation? - What perception of this opening do they have? (pros/cons, advantages/drawbacks); - what behaviour do they have in front of the opening of markets to competition? (approach with respect to information needs, knowledge about the offer, intention to change supplier, brakes/motivations in entering the open market). (J.S.)

  4. The opening of electricity and natural gas markets to residential clients. Yearly barometer - run 5. September 2011; L'ouverture des marches de l'electricite et du gaz naturel pour les clients residentiels. Barometre annuel - vague 5. Septembre 2011

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-09-15

    The opening of energy markets to competition became effective to individuals ('residential clients') on July 1, 2007 with the possibility to freely choose their energy supplier. This opening of energy markets to residential clients started 3 years after the opening to professionals (July 1, 2004). The Commission of energy regulation (CRE) and the national energy Ombudsman have set in place in 2007 a quantitative yearly survey ('barometer') addressed to residential clients in order to collect statistical data about the behaviour of these clients with regards to the opening of markets to competition. This document deals with the results of the fourth run of this survey carried out from September 12 to September 23, 2011 by the LH2 institute. For the 1500 households investigated, LH2 has questioned the person in charge of the energy bills management. The barometer aimed at answering the following questions: - what is the level of knowledge and information of residential clients about markets opening and the existing regulation? - What perception of this opening do they have? (pros/cons, advantages/drawbacks); - what behaviour do they have in front of the opening of markets to competition? (approach with respect to information needs, knowledge about the offer, intention to change supplier, brakes/motivations in entering the open market). (J.S.)

  5. The opening of electricity and natural gas markets to residential clients. Yearly barometer - run 4. September 2010; L'ouverture des marches de l'electricite et du gaz naturel pour les clients residentiels. Barometre annuel - vague 4. Septembre 2010

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-09-15

    The opening of energy markets to competition became effective to individuals ('residential clients') on July 1, 2007 with the possibility to freely choose their energy supplier. This opening of energy markets to residential clients started 3 years after the opening to professionals (July 1, 2004). The Commission of energy regulation (CRE) and the national energy Ombudsman have set in place in 2007 a quantitative yearly survey ('barometer') addressed to residential clients in order to collect statistical data about the behaviour of these clients with regards to the opening of markets to competition. This document deals with the results of the fourth run of this survey carried out from September 6 to September 18, 2010 by the LH2 institute. For the 1504 households investigated, LH2 has questioned the person in charge of the energy bills management. The barometer aimed at answering the following questions: - what is the level of knowledge and information of residential clients about markets opening and the existing regulation? - What perception of this opening do they have? (pros/cons, advantages/drawbacks); - what behaviour do they have in front of the opening of markets to competition? (approach with respect to information needs, knowledge about the offer, intention to change supplier, brakes/motivations in entering the open market). (J.S.)

  6. The opening of electricity and natural gas markets to professional clients. Yearly barometer - run 6. September 2010; L'ouverture des marches de l'electricite et du gaz naturel pour les clients professionnel. Barometre annuel - vague 6. Septembre 2010

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-09-15

    The opening of energy markets to competition became effective to professionals on July 1, 2004. In 2010 this opening has entered into a mature phase. As soon as 2005, a barometer survey has been implemented to investigate the professional clients and to collect statistical data about their behaviour with regards to the opening of markets to competition. This document deals with the results of the sixth run of the professionals' barometer carried out from August 30 to September 10, 2010 by the LH2 institute. Among the 1502 surveyed entities, LH2 has questioned the decision-makers responsible for the electricity and natural gas contracts. The barometer aimed at answering the following questions: - what is the level of knowledge and information of professionals about markets opening and the existing regulation? - What perception of this opening do they have? (pros/cons, advantages/drawbacks); - what behaviour do they have in front of the opening of markets to competition? (approach with respect to information needs, knowledge about the offer, intention to change supplier, brakes/motivations in entering the open market). (J.S.)

  7. The operation of wholesale electricity, CO{sub 2} and natural gas markets in 2010-2011; Le fonctionnement des marches de gros de l'electricite, du CO{sub 2} et du gaz naturel en 2010-2011

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    The first part analyses the electricity wholesale markets: development of the main wholesale market segments, electricity price, electricity production analysis and transparency of production data, transaction analysis. The second part analyses CO{sub 2} markets: evolution of the institutional framework and perspectives, exchanges volumes on the CO{sub 2} market, the CO{sub 2} price in Europe, fundamentals of the European CO{sub 2} market. The third part addresses the gas market: development of gas trade, gas price, gas infrastructures, supply and outlets for stake holders and new comers

  8. The opening of electricity and natural gas markets to professional clients. Yearly barometer - run 4. December 2008; L'ouverture des marches de l'electricite et du gaz naturel pour les clients professionnel. Barometre annuel - vague 4. Decembre 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-12-15

    The opening of energy markets to competition became effective to professionals on July 1, 2004. In 2008 this opening is entering into a mature phase. As soon as 2005, a barometer survey has been implemented to investigate the professional clients and to collect statistical data about their behaviour with regards to the opening of markets to competition. This document deals with the results of the fourth run of the professionals' barometer carried out from November 19 to December 2, 2008 by the LH2 institute. Among the 1501 surveyed entities, LH2 has questioned the decision-makers responsible for the electricity and natural gas contracts. The barometer aimed at answering the following questions: - what is the level of knowledge and information of professionals about markets opening and the existing regulation? - What perception of this opening do they have? (pros/cons, advantages/drawbacks); - what behaviour do they have in front of the opening of markets to competition? (approach with respect to information needs, knowledge about the offer, intention to change supplier, brakes/motivations in entering the open market). (J.S.)

  9. The opening of electricity and natural gas markets to professional clients. Yearly barometer - run 5. September 2009; L'ouverture des marches de l'electricite et du gaz naturel pour les clients professionnel. Barometre annuel - vague 5. Septembre 2009

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-09-15

    The opening of energy markets to competition became effective to professionals on July 1, 2004. In 2008 this opening is entering into a mature phase. As soon as 2005, a barometer survey has been implemented to investigate the professional clients and to collect statistical data about their behaviour with regards to the opening of markets to competition. This document deals with the results of the fifth run of the professionals' barometer carried out from September 14 to September 25, 2009 by the LH2 institute. Among the 1501 surveyed entities, LH2 has questioned the decision-makers responsible for the electricity and natural gas contracts. The barometer aimed at answering the following questions: - what is the level of knowledge and information of professionals about markets opening and the existing regulation? - What perception of this opening do they have? (pros/cons, advantages/drawbacks); - what behaviour do they have in front of the opening of markets to competition? (approach with respect to information needs, knowledge about the offer, intention to change supplier, brakes/motivations in entering the open market). (J.S.)

  10. The opening of electricity and natural gas markets to professional clients. Yearly barometer - run 7. September 2011; L'ouverture des marches de l'electricite et du gaz naturel pour les clients professionnel. Barometre annuel - vague 7. Septembre 2011

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-09-15

    The opening of energy markets to competition became effective to professionals on July 1, 2004. In 2008 this opening is entering into a mature phase. As soon as 2005, a barometer survey has been implemented to investigate the professional clients and to collect statistical data about their behaviour with regards to the opening of markets to competition. This document deals with the results of the seventh run of the professionals' barometer carried out from September 5 to September 12, 2011 by the LH2 institute. Among the 1508 surveyed entities, LH2 has questioned the decision-makers responsible for the electricity and natural gas contracts. The barometer aimed at answering the following questions: - what is the level of knowledge and information of professionals about markets opening and the existing regulation? - What perception of this opening do they have? (pros/cons, advantages/drawbacks); - what behaviour do they have in front of the opening of markets to competition? (approach with respect to information needs, knowledge about the offer, intention to change supplier, brakes/motivations in entering the open market). (J.S.)

  11. The opening of electricity and natural gas markets to residential clients. Yearly barometer - run 3. September 2009; L'ouverture des marches de l'electricite et du gaz naturel pour les clients residentiels. Barometre annuel - vague 3. Septembre 2009

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-09-15

    The opening of energy markets to competition became effective to individuals ('residential clients') on July 1, 2007 with the possibility to freely choose their energy supplier. This opening of energy markets to residential clients started 3 years after the opening to professionals (July 1, 2004). The Commission of energy regulation (CRE) and the national energy Ombudsman have set in place in 2007 a quantitative yearly survey ('barometer') addressed to residential clients in order to collect statistical data about the behaviour of these clients with regards to the opening of markets to competition. This document deals with the results of the fourth run of this survey carried out in September 2009 by the LH2 institute. For the 1500 households investigated, LH2 has questioned the person in charge of the energy bills management. The barometer aimed at answering the following questions: - what is the level of knowledge and information of residential clients about markets opening and the existing regulation? - What perception of this opening do they have? (pros/cons, advantages/drawbacks); - what behaviour do they have in front of the opening of markets to competition? (approach with respect to information needs, knowledge about the offer, intention to change supplier, brakes/motivations in entering the open market). (J.S.)

  12. LNG to India - the role of innovation and technological development in enabling the Pipavav project; Le GNL (gaz naturel liquefie) en Inde - le role de l'innovation et du developpement technique dans l'etablissement du projet Pipavav

    Energy Technology Data Exchange (ETDEWEB)

    Brown, R.A.; Haynes, D.A.; Humphreys, C.E. [BG Technology Ltd. (United Kingdom); Acton, A. [British Gas International (India)

    2000-07-01

    India offers a significant potential market for LNG. However, the difficulties in marketing LNG in the area are considerable with a limited availability of buyers prepared and able to commit to long term gas purchase contracts. This combined with the large number of competing projects makes it essential that Indian LNG projects take account of recent industry cost reduction initiatives and are designed and built to exacting and, where possible, accelerated schedules. The west coast of India provides the best markets but presents difficulties of a fundamental technical nature for LNG projects. Of particular concern are the limited availability of natural harbors with sufficient protection for LNG ships to operate during the monsoon period, the long distances to deep water from the high water line and the variable nature of local marine and seabed conditions. This poster concentrates on the design of the proposed import terminal at Pipavav in North West India to be owned and operated by Gujarat Pipavav LNG Co. It discusses the technical development work undertaken by BG Technology and BG International to enable the project to proceed with acceptable capital costs and schedule. (authors)

  13. Conventional and unconventional natural gas resources in Russia and the strategy of their development in the firs half of the 21. century; Les ressources conventionnelles et non conventionnelles de gaz naturel de la Russie et la strategie de leur mise en valeur pour la premiere moitie du 21. siecle

    Energy Technology Data Exchange (ETDEWEB)

    Skorobogatov, V.A.; Istomin, V.A.; Yakushev, V.S. [Gazprom, VNIIGAZ (Russian Federation)

    2000-07-01

    The Russia's initial conventional natural gas resources in West Siberia and the Kara sea shelf accounts for 98-107 TCM (recoverable -73-80 TCM) and in the East Siberian platform - at the most 30-32 TCM. The Russian gas industry until the year 2030 will be developed at the expense of fields on Yamal and Gydan peninsulas in West Siberia, in East Siberia, on the Kara and Barents seas shelves. On the period 1999-2030 the total conventional gas production in Russia will account for 22-24 TCM. As unconventional gas sources in Russia regarded are the following: natural gas hydrates (its resources are estimated to be from 100 to 1000 TCM); coal-bed methane (from. 20 to 50 TCM); water-dissolved gases of underground hydrosphere (from 50 to 200 TCM); gases of dense low permeable formations (from 50 to 70 TCM); gases of deep-seated (over 4500 m) horizons (from 50 to 200 TCM). The main part of natural gas resources in dense low-permeable reservoirs is confined to deep horizons of already revealed fields (Urengoy, Yamburg, Bovanenkovskoe, Kharasaveiskoe etc.). By the year 2015 the total volume of gas production from such reservoirs may reach 40-50 BCM. (authors)

  14. Radiological assessment of natural radionuclides in soil within and around crude oil flow and gas compression stations in the Niger Delta, Nigeria; Evaluation radiologique de radionucleides naturels dans le sol collectes a l'interieur et autour des stations de compression des gaz dans le delta du Niger, Nigeria

    Energy Technology Data Exchange (ETDEWEB)

    Ademola, J.A.; Atare, E.E. [University of Ibadan, Department of Physics, Ibadan (Nigeria)

    2010-04-15

    Natural radionuclide concentrations in soil samples collected within and around crude oil flow and gas compression stations in the Niger Delta, Nigeria, were determined using gamma-ray spectroscopy. The mean activity concentrations of {sup 40}K, {sup 238}U and {sup 232}Th varied from 30.1 +- 3.0 to 59.0 +- 17.1, B.D.L. to 8.8 +- 2.3 and 7.9 +- 3.7 to 10.9 +- 1.9 Bq.kg-1, respectively. The {sup 40}K, {sup 238}U and {sup 232}Th contents of the soil samples are very low compared with the world average for natural background area. The absorbed dose rate and effective dose ranged from 6.9 to 11.1 n Gy.h-1 and 8.5 to 13.6 muSv.y-1, respectively. The annual gonadal dose equivalent rate ranged from 48.9 to 77.5 muSv.y-1, which is lower than the world average of 0.30 mSv.y-1. The radium equivalent activity and the external hazard index of the soil samples were below the recommended limits of 370 Bq.kg-1 and unity, respectively. The results obtained reveal that there is no significant radiation hazard due to natural radionuclides of the soil samples in the studied areas. (authors)

  15. Gestion de l'environnement urbain et risques 'naturels'. La problématique des Quebradas à Quito (Equateur

    Directory of Open Access Journals (Sweden)

    1996-01-01

    Full Text Available Les nombreuses quebradas, ravins à écoulement sporadique qui traversent le site de Quito, ont été systématiquement remblayées lors de l’urbanisation, pour servir notamment de zones de décharge plus ou moins contrôlée pour les déchets solides. À partir d’une cartographie diachronique, l’historique de ce remblaiement du réseau hydrographique est décrit, et les risques de nature morphoclimatique induits par ces profondes transformations, étudiés par ailleurs, sont brièvement évoqués. Ces zones spécifiques d’un site urbain de montagne relèvent d’un statut juridique de protection propre au réseau hydrographique en ville, lequel est profondément modifié dans la pratique après remblaiement, voire simplement oublié. Tout se passe comme si le remblaiement et l’urbanisation du réseau hydrographique faisaient l’objet d’un large consensus social, pour gagner de l’espace, donner une solution intra-urbaine à l’évacuation des déchets, et éradiquer des zones socialement incontrôlées. Les représentations sociales qui induisent une politique non explicite de gestion du site, sont analysées et discutées, au moment où les gestionnaires de la ville s’interrogent quant au bien-fondé de la poursuite du processus, alors que ce dernier se poursuit activement pour cacher la forte pollution du rio Machangara, principal émissaire du bassin. MANEJO DEL MEDIO AMBIENTE Y RIESGOS “NATURALES”. LA PROBLEMÁTICA DE LAS QUEBRADAS EN QUITO (ECUADOR. Las numerosas quebradas que atraviesan la ciudad de Quito fueron constantemente rellenadas durante el proceso de urbanización, sirviendo de basurero controlado o no. Se describe la historia del relleno de la red hidrográfica mediante su cartografía en el tiempo, y los riesgos de tipo morfoclimático producidos por esas transformaciones, que fueron investigados anteriormente, son resumidos. Las zonas de quebradas, específicas de un sitio urbano montañoso, tienen un estatuto jur

  16. A Natural Model of Active Transpressional Tectonics the en Échelon Structures of the Oriente Deep, Along the Northern Caribbean Transcurrent Plate Boundary (Southern Cuban Margin Un modèle naturel de tectonique transpressive active Les structures en échelon de la fosse de l'Oriente le long de la limite de plaques décrochante Nord-Caraïbe

    Directory of Open Access Journals (Sweden)

    Calais E.

    2006-11-01

    Full Text Available A seabearn and seismic reflection structural study of the Oriente Deep, located along the northern Caribbean transcurrent plate boundary, allows us to image in three dimensions active transpressional structures (cruise SEA-CARIB II, R/V Jean Charcot. These structures are folds and reverse faults. The folds display an en échelon arrangement and are set within three E-W trending alignments. The folds appear with an axis trending 30° to 40° to the shear direction. Their axes have undergone a rotation which gives them in plan a sigmoidal Zshape. The reverse faults formed after the folds and are located at the bases of the anticlines. The folding occurs outside the main strike-slip fault, above inactive burried faults affecting the basement of the Oriente Deep. The Oriente Deep is a exceptional natural model for the study of active transpressional deformation along a major strike-slip fault. La campagne océanographique SEACARIB II du N/O Jean Charcot a permis l'étude structurale du bassin de l'Oriente, situé le long de la limite de plaques décrochante nord caraïbe au sud de Cuba. Cette étude, par Seabeam et sismique réflexion, y a révélé des structures transpressives actives (plis et failles inverses et a permis de les illustrer en trois dimensions. Au sein de ce bassin, les plis sont disposés en échelon en trois alignements E-W. La direction de l'axe des plis naissant fait un angle de 30° à 40° avec la direction du décrochement principal. Les axes des plis subissent ensuite une rotation qui leur donne, en carte, une forme sigmoïdale en Z . Des failles inverses se forment après les plis à la base des anticlinaux. Le plissement est localisé en avant du décrochement principal, au-dessus de failles inactives enfouies affectant le substratum du bassin de l'Oriente. Le bassin de l'Oriente est un modèle naturel exceptionnel pour l'étude de déformations transpressives actives le long d'un décrochement actif majeur.

  17. Au36(SPh)23 nanomolecules.

    Science.gov (United States)

    Nimmala, Praneeth Reddy; Dass, Amala

    2011-06-22

    A new core size protected completely by an aromatic thiol, Au(36)(SPh)(23), is synthesized and characterized by MALDI-TOF mass spectrometry and UV-visible spectroscopy. The synthesis involving core size changes is studied by MS, and the complete ligand coverage by aromatic thiol group is shown by NMR.

  18. Ecotourisme et parcs naturels : innovations et contradictions sud-africaines, le cas de HIP (Hluhluwe-Imfolozi Park

    Directory of Open Access Journals (Sweden)

    Fabrice Folio

    2010-09-01

    Full Text Available Comptant parmi les plus vieilles réserves naturelles d’Afrique australe, l’aire protégée de Hluhluwe-Imfolozi Parc (HIP se situe dans la province du KwaZulu-Natal en Afrique du Sud. Elle est aujourd’hui représentative d’une Afrique du Sud sauvage et ouverte aux visiteurs, dans un pays ayant fait une priorité des axes de durabilité/responsabilité touristique (sur la base d’un fort potentiel, de prestations de qualité et de l’orientation politique. En s’engageant dans la voie écotouristique, HIP est le cadre d’initiatives, en la matière, qualifiées de novatrices lors de leur établissement. Toutefois, le constat d’ensemble n’est pas exempt de fragilités, qu’il convient aussi de rapporter à d’importants défis hérités. Au-delà des résultats encourageants et des insuffisances notables, la politique du Parc, derrière la flexibilité touristique et la progression de l’échelon communautaire limitrophe, reste pour le moins ambiguë, dans ses aspects territoriaux comme dans l’implication des acteurs.As one of the oldest game reserves in austral Africa, the Hluhluwe-Imfolozi Park (HIP, set in the heart of the KwaZulu-Natal province, has become a south-african example as a conservation sanctuary involved in ecotourism practices. Its rich biodiversity has paved the way to protection, tourism and participation initiatives during its development. Located in a country, which also gave priority to the sustainable/responsible tourism issues (in relation to its rich potential, level of services as well as strong governmental policy, the results are not free from several fragilities and insufficiencies. One also has to relate these facts to the inherited national socio-economical stakes. Finally, the particularity of HIP led in a mixed of seducing and, in such way, ambiguous ecotourism reality, putting together a strong and old provincial conservation programme, a diversified and adaptable tourism activity as well as

  19. Global polarization measurement in Au+Au collisions

    Energy Technology Data Exchange (ETDEWEB)

    Abelev, B.I.; Adams, J.; Aggarwal, M.M.; Ahammed, Z.; Amonett,J.; Anderson, B.D.; Anderson, M.; Arkhipkin, D.; Averichev, G.S.; Bai,Y.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellingeri-Laurikainen, A.; Bellwied, R.; Benedosso, F.; Bhardwaj, S.; Bhasin, A.; Bhati, A.K.; Bichsel, H.; Bielcik, J.; Bielcikova, J.; Bland, L.C.; Blyth, S.-L.; Bonner, B.E.; Botje, M.; Bouchet, J.; Brandin, A.V.; Bravar, A.; Bystersky, M.; Cadman, R.V.; Cai,X.Z.; Caines, H.; Calderon de la Barca Sanchez, M.; Castillo, J.; Catu,O.; Cebra, D.; Chajecki, Z.; Chaloupka, P.; Chattopadhyay, S.; Chen,H.F.; Chen, J.H.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Cosentino, M.R.; Cramer, J.G.; Crawford,H.J.; Das, D.; Das, S.; Daugherity, M.; de Moura, M.M.; Dedovich, T.G.; DePhillips, M.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Djawotho,P.; Dogra, S.M.; Dong, W.J.; Dong, X.; Draper, J.E.; Du, F.; Dunin, V.B.; Dunlop, J.C.; Dutta Mazumdar, M.R.; Eckardt, V.; Edwards, W.R.; Efimov,L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Fatemi, R.; Fedorisin, J.; Filimonov, K.; Filip, P.; Finch,E.; Fine, V.; Fisyak, Y.; Fu, J.; Gagliardi, C.A.; Gaillard, L.; Ganti,M.S.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J.S.; Gorbunov, Y.G.; Gos,H.; Grebenyuk, O.; Grosnick, D.; Guertin, S.M.; Guimaraes, K.S.F.F.; Guo,Y.; Gupta, N.; Gutierrez, T.D.; Haag, B.; Hallman, T.J.; Hamed, A.; Harris, J.W.; He, W.; Heinz, M.; Henry, T.W.; Hepplemann, S.; Hippolyte,B.; Hirsch, A.; Hjort, E.; Hoffman, A.M.; Hoffmann, G.W.; Horner, M.J.; Huang, H.Z.; Huang, S.L.; Hughes, E.W.; Humanic, T.J.; Igo, G.; Jacobs,P.; Jacobs, W.W.; Jakl, P.; Jia, F.; Jiang, H.; Jones, P.G.; Judd, E.G.; Kabana, S.; Kang, K.; Kapitan, J.; Kaplan, M.; Keane, D.; Kechechyan, A.; Khodyrev,V.Yu.; Kim, B.C.; Kiryluk, J.; Kisiel, A.; Kislov, E.M.; Klein,S.R.; Kocoloski, A.; Koetke, D.D.; et al.

    2007-08-02

    The system created in non-central relativisticnucleus-nucleus collisions possesses large orbital angular momentum. Dueto spin-orbit coupling, particles produced in such a system could becomeglobally polarized along the direction of the system angular momentum. Wepresent the results of Lambda and anti-Lambda hyperon global polarizationmeasurements in Au+Au collisions at sqrt sNN=62.4 GeV and 200 GeVperformed with the STAR detector at RHIC. The observed globalpolarization of Lambda and anti-Lambda hyperons in the STAR acceptance isconsistent with zero within the precision of the measurements. Theobtained upper limit, lbar P Lambda, anti-Lambda rbar<= 0.02, iscompared to the theoretical values discussed recently in theliterature.

  20. pluviosite en region soudano-sahelienne au nord du cameroun

    African Journals Online (AJOL)

    AISA

    aux zones semi-aride et sub-humide, est soumis à une dégradation du milieu naturel (Donfack et al., 1996). Les sols ferrugineux tropicaux y couvrent environ 2 ... La répartition des précipitations soumet toute la région à un climat tropical à deux saisons très contrastées. La saison pluvieuse, d'une durée de 7 mois vers le ...

  1. d + Au hadron correlation measurements at PHENIX

    Energy Technology Data Exchange (ETDEWEB)

    Sickles, Anne M., E-mail: anne@bnl.gov

    2014-06-15

    In these proceedings, we discuss recent results from d + Au collisions in PHENIX ridge related measurements and their possible hydrodynamic origin. We present the v{sub 2} at midrapidity and measurements of the pseudorapidity dependence of the ridge, distinguishing between the d-going and Au-going directions. We investigate the possible geometrical origin by comparing v{sub 2} in d + Au to that in p + Pb, Au + Au and Pb + Pb collisions. Future plans to clarify the role of geometry in small collision systems at RHIC are discussed.

  2. Gas-Oil Relative Permeability and Residual Oil Saturation as Related to Displacement Instability and Dimensionless Numbers Étude de la perméabilité relative gaz-huile et de la saturation en huile résiduelle dans le cas d’une instabilité de déplacement et des nombres sans dimension s’y rapportant

    Directory of Open Access Journals (Sweden)

    Rostami B.

    2009-11-01

    éabilité relative et la saturation résiduelle. Les perméabilités relatives déterminées par des approches analytiques et numériques indiquent qu’une plus grande vitesse de déplacement engendre une plus grande perméabilité relative au gaz et une plus faible perméabilité relative à l’huile. Les résultats indiquent que la saturation en huile à la fin est très supérieure lorsque la vitesse de déplacement se situe au-dessus du critère de stabilité. Les caractéristiques du déplacement, notamment la saturation moyenne en huile en fin de déplacement, sont ensuite décrites à l’aide de groupements sans dimension expressément le nombre de Bond et le nombre capillaire. La saturation en huile en fin de déplacement déterminée expérimentalement s’exprime respectivement par une relation directe avec le nombre capillaire et inverse avec le nombre de Bond. En conséquence, un groupement sans dimension combiné a été proposé afin de généraliser l’estimation de la saturation en fin de déplacement et résiduelle en huile dans la limite des nombres sans dimension étudiés ici.

  3. Decay spectroscopy of $^{178}$Au

    CERN Document Server

    Whitmore, B

    In this thesis, the neutron-deficient nucleus $^{178}$Au is investigated through decay spectroscopy. Si and HPGe detectors were used to analyse the decay radiation of $^{178}$Au and its daughter nuclei. Previous studies have been unable to distinguish decay radiation from different isomeric states of this nucleus. This thesis represents the first time such isomeric discrimination has been achieved, and presents tentative spin assignments of both the ground state and an isomer. The neutron-deficient gold isotopes are an area of interest for the study of shape coexistence. This is the phenomenon exhibited by nuclei able to exist at a number of close lying energy minima, each reflecting a distinct type of deformation. It is hoped that studies such as this can help identify the evolution of nuclear deformation in this region of the nuclear chart.

  4. Le CRDI au Costa Rica

    International Development Research Centre (IDRC) Digital Library (Canada)

    La stabilité politique du Costa Rica a fait de ce pays un partenaire essen- tiel du CRDI en Amérique centrale pour la recherche portant sur l'agriculture, les politiques économiques, la démocratisation et la prévention des catastrophes naturelles. Le CRDI a beaucoup contribué à la recherche en agriculture au Costa Rica,.

  5. Cas de Cotonou au Benin

    African Journals Online (AJOL)

    Au nombre de ces nuisances, figurent entre autres, la perte de temps et par ricochet d'importantes recettes .... La méthodologie utilisée est basée sur deux types d'approches : l'approche théorique et celle empirique. Le premier volet de ...... Université de Bordeaux Talence, 456 pages. SEGBEDJI, E. (2001) : Impact du trafic ...

  6. DU NORMATIVISME SYMBOLIQUE A L’APPARITION DE L’ECONOMIE D’ACCUMULATION AU NEOLITHIQUE

    Directory of Open Access Journals (Sweden)

    Dan SEMENESCU

    2010-06-01

    Full Text Available Le problème de la néolithisation, considérée, dès 1929 par Gordon Childe, comme la deuxième grande révolution, après celle de l’anthropogenèse, est loin d’être un chapitre clos des sciences de l’homme. Cette « révolution néolithique », considérée comme étant le début des premières manipulations par notre espèces de son milieu naturel, directement à l’origine de sa puissance d’à présent, au delà de ses spécificités propres, représente, dans l’imaginaire et le discours des spécialistes sur le devenir de l’homme, l’origine et le fondement de notre présent, voir de notre avenir, une sorte de « laisser passer » qui légitime et autorise nos actions, de telle sorte que : l’on admet que dans notre domination de la Terre, un tournant décisif a été pris au Néolithique et que de ce tournant nous sommes les héritiers et le produit direct, c’est là que nous devons faire remonter notre histoire. Mais, bien que notre histoire en tant qu’êtres humains biologiques peut remonter avec certitude à cette époque, il reste tout de même à savoir si notre histoire culturelle ou notre idéologie, sont la prolongation évolutive de l’idéologie néolithique. La question est de savoir si l’homme du Néolithique, à une échelle plus réduite, bien sûr, pensait comme l’homme moderne sa relation avec la « nature », comme domination, ou bien si c’est notre besoin idéologique de légitimité, qui le fait penser en industriel moderne ?

  7. L’apprentissage au CERN

    CERN Multimedia

    Staff Association

    2016-01-01

    En 1961, sur la base du constat que l’évolution du marché du travail nécessitait un besoin croissant de personnel qualifié, le 1er accord entre la République et canton de Genève et le CERN fut signé. Cet accord avait notamment pour objet la formation professionnelle de jeunes électroniciens et techniciens de laboratoires en physique. Le CERN, acteur local économique d’importance, soulignait par cet accord sa volonté de participer au développement économique et social local. Le 1er apprenti arriva au CERN en 1965. En 1971, le centre d’apprentissage fut créé ; il accueille aujourd’hui plus d’une vingtaine d’apprentis au total, à raison d’environ six nouveaux apprentis chaque année. Cet apprentissage est dédié aux jeunes âgés e...

  8. Heat transfer in gas-cooled piles; Echanges thermiques dans les piles a gaz

    Energy Technology Data Exchange (ETDEWEB)

    Le Foll, J.; Gelin, P.; Robert, E. de [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    bouchons qui assurent la fermeture des cartouches peuvent supporter des contraintes mecaniques superieures a celles de la gaine. La limite admissible pour leur temperature s'en trouveissee tandis qu'ils sont voisins des parties les plus chaudes de l'uranium, situees pres de l'axe des barreaux. De plus, les bouchons ecartent les barreaux, d'ou un relevement de flux neutronique qui aggrave la difficulte precedente. Le relevement du flux a fait l'objet d'une etude numerique sur machine electronique, puis d'une verification experimentale directe. Une etude technologique portant sur l'usinage des extremites, sur l'emploi de cones metalliques en metal conducteur et l'oxydation anodique de disques metalliques tres minces a fourni les elements d'une solution du probleme obtenue en eliminant les sources de chaleur les plus genantes et en isolant l'uranium du bouchon. L'etude experimentale de la convection aux extremites permet alors de definir les conditions aux limites de la conduction pour chaque configuration etudiee. La conduction elle-meme est etudiee au moyen d'une analogie rheoelectrique qui fournit la carte des temperatures dans la zone critique. (auteur)

  9. Fabricating a Homogeneously Alloyed AuAg Shell on Au Nanorods to Achieve Strong, Stable, and Tunable Surface Plasmon Resonances

    KAUST Repository

    Huang, Jianfeng

    2015-08-13

    Colloidal metal nanocrystals with strong, stable, and tunable localized surface plasmon resonances (SPRs) can be useful in a corrosive environment for many applications including field-enhanced spectroscopies, plasmon-mediated catalysis, etc. Here, a new synthetic strategy is reported that enables the epitaxial growth of a homogeneously alloyed AuAg shell on Au nanorod seeds, circumventing the phase segregation of Au and Ag encountered in conventional synthesis. The resulting core–shell structured bimetallic nanorods (AuNR@AuAg) have well-mixed Au and Ag atoms in their shell without discernible domains. This degree of mixing allows AuNR@AuAg to combine the high stability of Au with the superior plasmonic activity of Ag, thus outperforming seemingly similar nanostructures with monometallic shells (e.g., Ag-coated Au NRs (AuNR@Ag) and Au-coated Au NRs (AuNR@Au)). AuNR@AuAg is comparable to AuNR@Ag in plasmonic activity, but that it is markedly more stable toward oxidative treatment. Specifically, AuNR@AuAg and AuNR@Ag exhibit similarly strong signals in surface-enhanced Raman spectroscopy that are some 30-fold higher than that of AuNR@Au. When incubated with a H2O2 solution (0.5 m), the plasmonic activity of AuNR@Ag immediately and severely decayed, whereas AuNR@AuAg retained its activity intact. Moreover, the longitudinal SPR frequency of AuNR@AuAg can be tuned throughout the red wavelengths (≈620–690 nm) by controlling the thickness of the AuAg alloy shell. The synthetic strategy is versatile to fabricate AuAg alloyed shells on different shaped Au, with prospects for new possibilities in the synthesis and application of plasmonic nanocrystals.

  10. Transport characteristics in Au/pentacene/Au diodes

    Science.gov (United States)

    Hayashi, Toshiaki; Naka, Akiyoshi; Hiroki, Masanobu; Yokota, Tomoyuki; Someya, Takao; Fujiwara, Akira

    2018-03-01

    We have used scanning and transmission electron microscopes (SEM and TEM) to study the structure of a pentacene thin film grown on a Au layer with and shown that it consists of randomly oriented amorphous pentacene clusters. We have also investigated the transport properties of amorphous pentacene in a metal–semiconductor–metal (MSM) diode structure and shown that the current is logarithmically proportional to the square root of the applied voltage, which indicates that transport occurs as the result of hopping between localized sites randomly distributed in space and energy.

  11. Acces au traitement anticancereux au Togo (access to treatment of ...

    African Journals Online (AJOL)

    Contexte : Au Togo, l'incidence et la mortalité des cancers ne cessent de croître en raison du diagnostic et de la prise en charge tardifs. D'autres raisons telles que l'absence d'oncologue spécialiste et la faible accessibilité aux médicaments anticancéreux sont de plus en plus évoquées. L'objectif de cette étude était de ...

  12. Transport diphasique de gaz et de condensat. Aspects techniques et économiques Technical and Economic Aspects of Two-Phase Pipelining of Gas and Condensate

    Directory of Open Access Journals (Sweden)

    Bourgeois T.

    2006-11-01

    Full Text Available L'évacuation diphasique de la production d'un gisement de gaz à condensat présente des avantages importants, en particulier sur le plan économique. Les caractéristiques des écoulements diphasiques sont exposées, avec les conséquences principales sur la définition d'un schéma d'exploitation. Une comparaison économique est ensuite présentée, pour illustrer la réduction des investissements qui peut être apportée par l'évacuation diphasique de la production. Enfin, les recherches françaises sur les écoulements diphasiques dans les conduites pétrolières sont brièvement décrites, ainsi qu'un exemple de calcul sur une conduite de gaz à condensat en exploitation diphasique. The two-phase pipelining of a wet gas field production presents many advantages, especially from an economic point of view. The characteristics of two-phase flow are described, together with their main consequences on the operational scheme. Then an economic comparison is made to illustrate the reduction in investment costs that can by achieved with two-phase pipelining. Research in France on two-phase flow in gas and condensate pipelines is briefly described, and an example is given of the designing of a wet-gas pipeline currently being operated in the two-phase mode.

  13. The analysis on of the effect of urea, iron sulfate and vermicompost fertilizers on the growth characteristics and yield of sunflower (Helianthus annuus L. The city Darreh Gaz

    Directory of Open Access Journals (Sweden)

    mahdiyeh zomorrodi

    2015-12-01

    Full Text Available To study the effect of vermicompost and urea and iron sulfate fertilizers on the growth characteristics and yield of sunflower seed (Helianthus annuus L. an pediment was conducted in Darreh Gaz located in Khorasan Razavi province in 2012. Factorial experiment in a randomized complete block design with three factors and three repetition. In this experiment three levels of urea (50; 150 and 250 kg per hectare as the first factor and two level of vermicompost (7 tons per hectare consumption and non-consumption as the second factor and two iron sulfate (80 kilogram per hectare consumption and non- consumption were considered as the third factor. The results showed that the effect of urea × vermicompost treatment combination on stem height, head diameter, stem dry weight and yield was significantly at one percent probability level. The treatment combination of 250 kg. ha-1 × iron sulfate× vermicompost increased plant height, head diameter, petiole dry weight. Vermicompost × iron sulfate treatment combination on the dry weight’s leaf, petiole, stem and head were the highest significant (p≤0.01. The application of vermicompost × iron sulfate treatment combination resulted in the highest rate of stem diameter, leaf dry weight and stem the highest yield belonged to 250 kg.ha-1 × vermicompost. Iron sulfate use different amounts of urea fertilizer redact yield. The lowest yield of 250 kg.ha-1× iron sulfate was related to treatment combination. So it seems that the combined application of organic vermicompost fertilizer and urea and iron sulfate fertilizers on the growth and yield of sunflower Darreh Gaz can be effective in improving properties.

  14. Étude par analogie électrique de différents types de tubes à gaz pulsé : modélisation et expérience

    Science.gov (United States)

    Halouane, A.; Maréchal, J.-C.; David, M.

    1998-10-01

    assemblage d'éléments électriques : résistance, capacitance ou inductance. À la source chaude du TGP, différents déphaseurs sont modélisés de la même manière et ainsi peuvent être comparés, comme l'orifice pulse tube refrigerator (OPTR) ou tube pulsé à simple orifice, le double inlet pulse tube refrigerator (DIPTR), le modified pulse tube refrigerator (MPTR) dont le déphaseur est un piston à la source chaude, le hybrid pulse tube refrigerator (HPTR) à ouverture séquentielles d'orifices, l'inertance in OPTR (IOPTR). En combinant cette analogie électrique avec l'étude thermique il est possible de prédire un bilan d'énergie à la source froide : puissance extraite, pertes du régénérateur, pertes du tube et influence des volumes morts. Différentes solutions peuvent être apportées au traitement de cette modélisation. Si les paramètres ne sont pas sinusoïdaux, le système peut être traité à un ordre supérieur à 1. Cette modélisation a été utilisée pour la conception du tube à gaz pulsé miniature qui travaille à des fréquences élevées 20-50 Hz et à des pressions supérieures à 20 MPa, construit en collaboration avec la société “Air Liquide". Le compresseur (rotatif ou linéaire) de demi volume balayé ≈ 1 cm3 est du type utilisé sur les “Stirling", il délivre une onde de pression quasi sinusoïdale. Sous 3 MPa de pression moyenne et une fréquence de 27,5 Hz, la température limite en mode double inlet est de 49 K avec une puissance disponible de 1 W à 84 K.

  15. Gasification in Petroleum Refinery of 21st Century La gazéification dans la raffinerie du pétrole du XXIe siècle

    Directory of Open Access Journals (Sweden)

    Furimsky E.

    2006-12-01

    goudrons, le coke et l'asphalte, résultant respectivement de la viscoréduction, de la carbonisation et du désasphaltage. Les résidus finaux peuvent être, à leur tour, convertis en produits utilisables comme l'hydrogène, la vapeur, l'électricité, l'ammoniac et des produits chimiques. Dans ce contexte, la gazéification est apparue comme la technologie de choix pour la valorisation des résidus en raison de ses meilleures performances. De même, les boues de raffinerie peuvent être cogazéifiées avec les résidus finaux et devenir alors des produits valorisables. Intégrée à la raffinerie de pétrole, la gazéification peut aider à résoudre les problèmes environnementaux liés à l'élimination des résidus et des boues. Les résultats économiques de la raffinerie peuvent également être améliorés. Les tendances de déréglementation du marché de l'énergie permettent aux raffineries de pétrole d'y pénétrer, soit toutes seules, soit en partenariat avec les fournisseurs d'utilités. Le potentiel de coproduction de produits chimiques et de vapeur avec l'électricité offre une souplesse de réaction permettant de répondre aux demandes du marché. L'intérêt de la technologie de la gazéification est commercialement démontré. Parmi d'autres, les gazéificateurs à lit entraîné sont les gazéificateurs de prédilection. Plusieurs projets commerciaux en Europe, en Asie et aux États-Unis font appel à un gazéificateur utilisant soit un système d'alimentation en suspension, soit un système d'alimentation par voie sèche.

  16. High-p(T) Tomography of d+Au and Au+Au at SPS, RHIC, and LHC.

    Science.gov (United States)

    Vitev, Ivan; Gyulassy, Miklos

    2002-12-16

    The interplay of nuclear effects on the p(T)>2 GeV inclusive hadron spectra in d+Au and Au+Au reactions at sqrt[s(NN)]=17, 200, and 5500 GeV is compared to leading order perturbative QCD calculations for elementary p+p (p+p) collisions. The competition between nuclear shadowing, Cronin effect, and jet energy loss due to medium-induced gluon radiation is predicted to lead to a striking energy dependence of the nuclear suppression/enhancement pattern in A+A reactions. We show that future d+Au data can be used to disentangle the initial and final state effects.

  17. Profiling hot and dense nuclear medium with high transverse momentum hadrons produced in d+Au and Au+Au collisions by the PHENIX experiment at RHIC

    Directory of Open Access Journals (Sweden)

    Sakaguchi Takao

    2014-03-01

    Full Text Available PHENIX measurements of high transverse momentum (pT identified hadrons in d+Au and Au+Au collisions are presented. The nuclear modification factors (RdA and RAA for π0 and ƞ are found to be very consistent in both collision systems, respectively. Using large amount of p + p and Au+Au datasets, the fractional momentum loss (Sloss and the path-length dependent yield of π0 in Au+Au collisions are obtained. The hadron spectra in the most central d+Au and the most peripheral Au+Au collisions are studied. The spectra shapes are found to be similar in both systems, but the yield is suppressed in the most peripheral Au+Au collisions.

  18. Au38(SPh)24: Au38 Protected with Aromatic Thiolate Ligands.

    Science.gov (United States)

    Rambukwella, Milan; Burrage, Shayna; Neubrander, Marie; Baseggio, Oscar; Aprà, Edoardo; Stener, Mauro; Fortunelli, Alessandro; Dass, Amala

    2017-04-06

    Au38(SR)24 is one of the most extensively investigated gold nanomolecules along with Au25(SR)18 and Au144(SR)60. However, so far it has only been prepared using aliphatic-like ligands, where R = -SC6H13, -SC12H25 and -SCH2CH2Ph. Au38(SCH2CH2Ph)24 when reacted with HSPh undergoes core-size conversion to Au36(SPh)24, and existing literature suggests that Au38(SPh)24 cannot be synthesized. Here, contrary to prevailing knowledge, we demonstrate that Au38(SPh)24 can be prepared if the ligand exchanged conditions are optimized, under delicate conditions, without any formation of Au36(SPh)24. Conclusive evidence is presented in the form of matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS), electrospray ionization mass spectra (ESI-MS) characterization, and optical spectra of Au38(SPh)24 in a solid glass form showing distinct differences from that of Au38(S-aliphatic)24. Theoretical analysis confirms experimental assignment of the optical spectrum and shows that the stability of Au38(SPh)24 is not negligible with respect to that of its aliphatic analogous, and contains a significant component of ligand-ligand attractive interactions. Thus, while Au38(SPh)24 is stable at RT, it converts to Au36(SPh)24 either on prolonged etching (longer than 2 hours) at RT or when etched at 80 °C.

  19. Genre et migration au Maroc

    OpenAIRE

    KHACHANI, Mohamed

    2011-01-01

    Euro-Mediterranean Consortium for Applied Research on International Migration (CARIM) Une des principales caractéristiques récentes de la migration marocaine est sa tendance à une féminisation soutenue. Le projet migratoire - qui était un projet d’hommes - intéresse de plus en plus les femmes marocaines au point de constituer actuellement près de la moitié de l’effectif migratoire marocain. Cette reconnaissance de l'importance des femmes dans la construction de l'espace migratoire a placé ...

  20. Genre et migration au Liban

    OpenAIRE

    JOUNI, Hassan

    2011-01-01

    Euro-Mediterranean Consortium for Applied Research on International Migration (CARIM) La femme possède un statut bien avancé au sein de la société libanaise : la Constitution libanaise proclame l’égalité entre les citoyens. Quelques lois et pratiques restent, toutefois, discriminatoires à l’égard de la femme, notamment la loi sur la nationalité et la loi sur le statut personnel. Une discrimination sociale très grave existe en ce qui concerne les femmes travaillant à domicile; elles subi...

  1. Nuclear Data Sheets for 181Au

    Science.gov (United States)

    Baglin, Coral M.

    1999-06-01

    Nuclear structure data pertaining to 181Au have been compiled and evaluated, and incorporated into the ENSDF data file. This evaluation of 181Au supersedes the previous publication (R. B. Firestone, Nuclear Data Sheets 62, 101 (1991) (literature cutoff date October 1990)), and includes literature available by 2 July 1999. The newly incorporated references are: 1999Mu05, 1999So01, 1995Au04, 1995Bi01, 1991Ry01, 1979Ha10, 1970Ha18.

  2. Nuclear data sheets for 181Au

    Energy Technology Data Exchange (ETDEWEB)

    Baglin, Coral M.

    1999-07-02

    Nuclear structure data pertaining to 181Au have been compiled and evaluated, and incorporated into the ENSDF data file. This evaluation of 181Au supersedes the previous publication (R. B. Firestone, Nuclear Data Sheets 62, 101 (1991) (literature cutoff date October 1990)), and includes literature available by 2 July 1999. The newly incorporated references are: 1999Mu05, 1999So01, 1995Au04, 1995Bi01, 1991Ry01, 1979Ha10, 1970Ha18.

  3. Predicted Habitat Suitability for Montipora Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Montipora in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  4. Predicted Habitat Suitability for Porites in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Porites in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  5. Predicted Habitat Suitability for Porites Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Porites in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  6. Predicted Habitat Suitability for Leptoseris Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Leptoseris in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  7. Predicted Habitat Suitability for All Mesophotic Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for all mesophotic corals in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to...

  8. Predicted Habitat Suitability for Leptoseris in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This raster denotes predicted habitat suitability for Leptoseris in the Au'au Channel region. Maximum Entropy (MaxEnt) modeling software was used to create this...

  9. Predicted Habitat Suitability for All Mesophotic Corals in the Au'au Channel Region

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset is located between the islands of Maui, Lanai, Molokai and Kahoolawe, and includes the Au'au Channel as well as parts of the Kealaikahiki, Alalakeiki...

  10. Les aliments au soja : consommation en France, qualités nutritionnelles et données scientifiques récentes sur la santé

    Directory of Open Access Journals (Sweden)

    Chevalier Dominique

    2016-07-01

    Full Text Available Aujourd’hui, 4 Français sur 10 consomment des aliments au soja. Les consommateurs les ont intégrés dans leur alimentation, sans bouleverser leurs habitudes alimentaires, parce qu’ils les considèrent naturels et sains. Les non consommateurs sont en attente de plus d’informations (origine géographique du soja et qualités nutritionnelles. La consommation est assez récente et devrait progresser dans les prochaines années. Les aliments élaborés à partir de la graine de soja fournissent des protéines de très bonne qualité nutritionnelle, des acides gras insaturés, des fibres, des vitamines et des minéraux. La graine de soja contient des isoflavones, dont une grande partie est éliminée lors de l’élaboration des aliments au soja (qui en contiennent 1 à 3 mg/g de protéine. La consommation actuelle d’aliments au soja est largement compatible avec l’apport maximal de 1mg/kg/j recommandé par l’Afssa en 2005. Le développement infantile avec les préparations à base de protéines de soja est comparable à celui observé avec celles à base de protéines de lait de vache ou avec le lait maternel, sur tous les paramètres étudiés (croissance, santé osseuse et fonctions métaboliques, reproductives, endocrines, immunitaires et neurologiques. Les aliments au soja semblent exercer un effet protecteur vis-à-vis du risque de cancer du sein (probablement lié aux isoflavones, surtout si la consommation est débutée avant l’adolescence. Chez les femmes ayant des antécédents de cancer du sein, l’alimentation peut intégrer les aliments au soja. Introduire des aliments à base de soja dans l’alimentation contribue aussi à maintenir la santé cardiovasculaire, du fait de leur effet favorable sur le taux de LDL-cholestérol, sur la fonction endothéliale, et potentiellement sur la tension artérielle.

  11. Depo Gazı Enerji Üretim Tesisi Baca Gazı Atık Isısının Seralarda Değerlendirilmesi: İstanbul Örneği / Utilization of Waste Heat in Energy Production Plant from Landfill Gas at Greenhouses – Case Study in Istanbul

    Directory of Open Access Journals (Sweden)

    Volkan Enç

    2012-12-01

    Full Text Available Evsel atık düzenli depolama sahaları kullanım ömrü dolduktan sonra yararlı kullanım alanları sınırlı sahalardır. Çoğunlukla yeşil alan olarak kullanılan bu yerler ekonomik ve çevresel anlamda atıl durumda bulunmaktadır. Depolama sahalarının İstanbul gibi arazi sıkıntısı çeken bir şehirde yararlı amaçlar için kullanılması elzemdir. Depolama sonrası sahalarda metan gazı oluşmakta ve farklı yöntemlerle kontrol altına alınmaktadır. Bu gazların toplanması, taşınması ve özel motorlarda yakılması ile elektrik enerjisi üretilmektedir. Tesislerde gazın yakılması, depo gazı içerisinde bulunan CH4 (metan gazının CO2’e indirgenmesini sağlayarak sera etkisini azaltmakta, elektrik enerjisi üreterek ekonomiye katkı sağlamaktadır. Çevresel ve ekonomik yarar göz önüne alındığında, depo gazından enerji üretim tesislerinde, enerji üretiminde mümkün olabilecek maksimum verime ulaşılmalıdır. Bu düşünce ile bakıldığında, depo gazı enerji üretim tesisinde oluşan atık ısının değerlendirilemeden atmosfere verilmesi önemli bir sorun olarak ortaya çıkmaktadır. Oldukça yüksek debi ve sıcaklığa sahip bu ısı, enerji bakımından önemli bir potansiyele sahiptir. Bu sıcaklıktaki ve debideki ısının değerlendirilmeden atmosfere verilmesi, çevreyi olumsuz etkilemesinin yanında ekonomik kayıplara yol açmaktadır. Seralarda mevsimlik çiçek üretimi, maliyeti yüksek bir faaliyettir. Maliyetlerin önemli bir kısmını sera ısıtılması ve gübre kullanımı oluşturmaktadır. Isıtma işlemi için Türkiye’nin büyük bir bölümünde kömür ve doğalgaz kullanılmaktadır. Kışın seraların ısıtılması için kullanılan fosil yakıtların hem maliyeti yüksek, hem de çevresel standardı düşüktür. Bu çalışma, İstanbul Kalkınma Ajansı (İSTKA tarafından desteklenen “Depo Gazı Enerji Üretim Tesisi Atık Isının ve Kompostun Seralarda

  12. Apport de la géostatistique à la description des stockages de gaz en aquifère Contribution of Geostatistics to Describing Aquifer Gas-Storage Reservoirs

    Directory of Open Access Journals (Sweden)

    Delhomme J. P.

    2006-11-01

    Full Text Available L'étude du comportement d'un réservoir de gaz en nappe aquifère réclame une connaissance aussi précise que possible des caractéristiques géométriques et pétrophysiques des couches réservoirs. Les moyens d'investigation sont de deux natures : - forages permettant une connaissance locale des roches réservoirs ; - mesures sismiques conduisant à une estimation approximative des cotes de certains repères stratigraphiques, en des points situés le long de profils. Les données recueillies sont donc, par nature, fragmentaires et discrètes : là où elles sont absentes, il y a lieu d'estimer les grandeurs étudiées en tenant compte au mieux de notre connaissance de leur variabilité spatiale. Ce problème d'interpolation optimale a donné lieu, depuis une vingtaine d'années, à l'élaboration et la mise en pratique d'un outil théorique particulièrement bien adapté aux besoins exprimés par les techniciens des sciences de la terre : la théorie des variables régionalisées due à G. Matheron. Des programmes informatiques mettant en oeuvre cette théorie sont actuellement opérationnels. Des exemples d'application en sont donnés : - tracé automatique de cartes structurales à partir des données de forages et des mesures sismiques ; - estimation des incertitudes de prévision sur les profondeurs ; - tracé de plusieurs variantes de carte compatibles avec les données ; - établissement d'éléments statistiques relatifs à une grandeur caractéristique d'un stockage : volume stockable par exemple ; - génération automatique des données nécessaires à la mise en oeuvre d'un modèle maillé de réservoir. Predicting and monitoring the behavior of an aquifer gas-storage reservoir requires as precise a knowledge as possible of the geometric and petrophysical properties of the reservoir layer. Two ways of obtaining this information can be given: (a Boreholes which provide local knowledge of the reservoir, and (b Seismic measurements

  13. Human Factors in the 21st Century(Les facteurs humains au 21th siecle)

    Science.gov (United States)

    2002-05-01

    in a different way. In so-called Rayleigh- Bénard convection cells, coherent structures are formed and staid between two temperature levels when a...automatismes qui puissent accepter le fonctionnement naturel , écologique de l’opérateur humain, et respecter ses objectifs, et ses apparentes...pointe, renforcent naturellement ce point de vue [1] . Deux voies s’offraient alors comme des solutions naturelles : d’une part décharger l’opérateur

  14. La pulvérisation du fuel oïl lourd par des combustibles gazeux Using Gaseous Fuels to Spray Heavy Fuel Oil

    Directory of Open Access Journals (Sweden)

    Ladurelli A.

    2006-11-01

    Full Text Available Pour faciliter l'inflammation du fuel lourd on procède à sa pulvérisation au droit du brûleur. Deux méthodes sont généralement employées à cet effet : - La pulvérisation mécanique qui consiste à faire passer le liquide sous forte pression au travers d'orifices calibrés de petit diamètre. - La pulvérisation pneumatique qui consiste à utiliser la détente d'un fluide auxiliaire préalablement comprimé. Les fluides couramment utilisés pour cela sont l'air comprimé et la vapeur d'eau ; toutefois tous les combustibles gazeux, notamment le gaz naturel et les gaz de raffinerie, peuvent également servir de fluide de pulvérisation quand ils sont disponibles sous pression. The igniting of heavy fuel oil is facilitated by spraying it at the burner. Two methods are used as a rule: - Pressure atomization, consisting in causing the liquid to pass at high pressure through calibrated small-diameter orifices. - Twin-fluid atomization, which consists in using the expansion of a previously compressed auxiliary fluid. The fluids commonly used for the purpose are compressed air and steam. However, any gaseous fuel, particularly natural gas and the refinery gases, can be used as the spraying fluid provided it is available under pressure.

  15. PHENIX results on collectivity in high-multiplicity p + Au, d + Au and 3He + Au collisions

    Science.gov (United States)

    Xu, Qiao

    2016-08-01

    We present recent PHENIX results for long-range two-particle correlation functions across a large pseudorapidity(η) gap in high-multiplicity p+Au, d+Au and 3He+Au collisions. Enhanced correlations are observed for particles with small azimuthal separation. Measurements of the second order Fourier coefficients (v 2) in p/d/3He+Au collisions, and the third order Fourier coefficient (v 3) in 3He+Au collision are performed using the event plane method. Scaling of v 2 with the initial eccentricity (ɛ 2) is performed in each system to investigate the role of the initial geometry in the development of a final-state anisotropy in the particle emission. The v 2 coefficients for identified π±, K± and (anti-)proton are measured as a function of transverse kinetic energy (KET) and their magnitudes are found to scale approximately with the number of constituent quarks in the hadron.

  16. Caractérisation de gaines en polyéthylène et noir de carbone utilisées pour les ponts à haubans après un vieillissement naturel

    OpenAIRE

    TIREAU, Jonathan; VAN SCHOORS, Laetitia; BENZARTI, Karim; COLIN, Xavier

    2009-01-01

    Le principal objectif de cette présente communication est de déterminer les conséquences de phénomènes complexes tel le couplage de la thermo- et photo-oxydation. Pour cette étude, nous nous sommes penchés sur le cas d'une gaine de polyéthylène chargée de noir de carbone et stabilisée avec un mélange classique d'antioxydants synergiques (Irganox 1010 + Irgafos 168), et ce après un vieillissement naturel d'un quart de siècle dans deux conditions d'ensoleillement distinctes: en présence et en l...

  17. Comparative study of anchoring groups for molecular electronics: structure and conductance of Au-S-Au and Au-NH{sub 2}-Au junctions

    Energy Technology Data Exchange (ETDEWEB)

    Kristensen, I S; Mowbray, D J; Thygesen, K S; Jacobsen, K W [Center for Atomic-scale Materials Design (CAMD), Department of Physics, Building 307, Technical University of Denmark, DK-2800 Kongens Lyngby (Denmark)

    2008-09-17

    The electrical properties of single-molecule junctions, consisting of an organic molecule coupled to metal electrodes, are sensitive to the detailed atomic structure of the molecule-metal contact. This, in turn, is determined by the anchoring group linking the molecule to the metal. With the aim of identifying and comparing the intrinsic properties of two commonly used anchoring groups, namely thiol and amine groups, we have calculated the atomic structure and conductance traces of different Au-S-Au and Au-NH{sub 2}-Au nanojunctions using density functional theory (DFT). Whereas NH{sub 2} shows a strong structural selectivity towards atop-gold configurations, S shows large variability in its bonding geometries. As a result, the conductance of the Au-NH{sub 2}-Au junction is less sensitive to the structure of the gold contacts than the Au-S-Au junction. These findings support recent experiments which show that amine-bonded molecules exhibit more well-defined conductance properties than do thiol-bonded molecules.

  18. Travailler avec Windows 7 au CERN (FR)

    CERN Multimedia

    CERN. Geneva

    2010-01-01

    Vue d'ensemble des nouveaux concepts et des changements dans l'interface utilisateur survenus dans Windows 7 depuis les versions antérieures de Windows (XP ou Vista). La mise à disposition de Windows 7 au CERN et son intégration dans l’infrastructure de Windows au CERN seront présentées.

  19. English for au pairs the au pair's guide to learning English

    CERN Document Server

    Curtis, Lucy

    2014-01-01

    English for Au Pairs has interlinked stories about a group of au pairs new to England. Marta, an 18-year-old from Poland arrives in the UK to work as an au pair. Throughout her year-long stay she has many different experiences - some bad, some good - but with the support of her host family she finds new friends and improves her English. English for Au Pairs offers insight into the joys and difficulties of being an au pair while at the same time reinforcing English language learning through grammar explanations and exercises.

  20. Au microstructure and the functional properties of Ni/Au finishes on ceramic IC packages

    Energy Technology Data Exchange (ETDEWEB)

    Winters, E.D.; Baxter, W.K. [Coors Electronic Package Co., Chattanooga, TN (United States); Braski, D.N.; Watkins, T.R. [Oak Ridge National Lab., TN (United States)

    1995-12-31

    Ni/Au plated finishes used on thick-film metallized multilayer ceramic packages for integrated circuits must meet functional requirements such as bondability, sealability, and solderability. Their ability to do so is dependent, among other things, on the ability of the Au deposit to inhibit the grain boundary diffusion and subsequent surface oxidation of Ni. In this study, the relation between functional performance, Ni diffusionr ate, and Au microstructure was examined. Extent of Ni diffusion during heating was determined by Auger electron spectroscopy for several electrolytic and electroless Ni/Au finishing processes. Results were correlated with differences in Au microstructures determined by SEM, atomic force microscopy, and XRD.

  1. AU-EU “Strategic Partnership”

    DEFF Research Database (Denmark)

    Rodt, Annemarie Peen; Okeke, Jide

    2013-01-01

    This article appraises strategic partnership between the African Union (AU) and European Union (EU). It examines the context and nature of AU and EU security relations and explores the conditions under which partnership has a positive impact in this regard. This includes an evaluation of converge......This article appraises strategic partnership between the African Union (AU) and European Union (EU). It examines the context and nature of AU and EU security relations and explores the conditions under which partnership has a positive impact in this regard. This includes an evaluation...... of convergence between the two organizations and its effect or lack thereof on African security. The article concludes that events leading up to and initiatives following the 2007 Joint Africa–European Union Strategy have produced a degree of AU and EU convergence, which has had limited impact on the efficacy...

  2. Structure of the thiolated Au130 cluster.

    Science.gov (United States)

    Tlahuice-Flores, Alfredo; Santiago, Ulises; Bahena, Daniel; Vinogradova, Ekaterina; Conroy, Cecil V; Ahuja, Tarushee; Bach, Stephan B H; Ponce, Arturo; Wang, Gangli; José-Yacamán, Miguel; Whetten, Robert L

    2013-10-10

    The structure of the recently discovered Au130-thiolate and -dithiolate clusters is explored in a combined experiment-theory approach. Rapid electron diffraction in scanning/transmission electron microscopy (STEM) enables atomic-resolution imaging of the gold core and the comparison with density functional theory (DFT)-optimized realistic structure models. The results are consistent with a 105-atom truncated-decahedral core protected by 25 short staple motifs, incorporating disulfide bridges linking the dithiolate ligands. The optimized structure also accounts, via time-dependent DFT (TD-DFT) simulation, for the distinctive optical absorption spectrum, and rationalizes the special stability underlying the selective formation of the Au130 cluster in high yield. The structure is distinct from, yet shares some features with, each of the known Au102 and Au144/Au146 systems.

  3. Gas-phase experiments on Au(III) photochemistry.

    Science.gov (United States)

    Marcum, Jesse C; Kaufman, Sydney H; Weber, J Mathias

    2011-04-14

    Irradiation of AuCl(4)(-) and AuCl(2)(OH)(2)(-) in the gas-phase using ultraviolet light (220-415 nm) leads to their dissociation. Observed fragment ions for AuCl(4)(-) are AuCl(3)(-) and AuCl(2)(-) and for AuCl(2)(OH)(2)(-) are AuCl(2)(-) and AuClOH(-). All fragment channels correspond to photoreduction of the gold atom to either Au(II) or Au(I) depending on the number of neutral ligands lost. Fragment branching ratios of AuCl(4)(-) are observed to be highly energy dependent and can be explained by comparison of the experimental data to calculated threshold energies obtained using density functional theory. The main observed spectral features are attributed to ligand-to-metal charge transfer transitions. These results are discussed in the context of the molecular-level mechanisms of Au(III) photochemistry.

  4. Magnetic depth profiling of Fe/Au multilayer using neutron ...

    Indian Academy of Sciences (India)

    Au multilayer sample for characterizing the layer structure and magnetic moment density profile. Fe/Au multilayer shows strong spin-dependent scattering at interfaces, making it a prospective GMR material. Fe/Au multilayer with bilayer ...

  5. Gaz - almaz / Jekaterina Rodina

    Index Scriptorium Estoniae

    Rodina, Jekaterina

    2008-01-01

    Venemaa Energiapoliitika Instituudi arvutuste kohaselt võib maagaasi tootmise ja nõudluse vahe ulatuda 2010. aastaks 100 miljardi kuupmeetrini, Kui maagaasi tarned Eestisse ära jäävad, saab meie riik omal jõul hakkama kõige rohkem kuu aega. Vt. samas: Gaas arvudes

  6. Gas mission; Mission gaz

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    This preliminary report analyses the desirable evolutions of gas transport tariffing and examines some questions relative to the opening of competition on the French gas market. The report is made of two documents: a synthesis of the previous report with some recommendations about the tariffing of gas transport, about the modalities of network access to third parties, and about the dissociation between transport and trade book-keeping activities. The second document is the progress report about the opening of the French gas market. The first part presents the European problem of competition in the gas supply and its consequences on the opening and operation of the French gas market. The second part presents some partial syntheses about each topic of the mission letter of the Ministry of Economics, Finances and Industry: future evolution of network access tariffs, critical analysis of contractual documents for gas transport and delivery, examination of auxiliary services linked with the access to the network (modulation, balancing, conversion), consideration about the processing of network congestions and denied accesses, analysis of the metering dissociation between the integrated activities of gas operators. Some documents are attached in appendixes: the mission letter from July 9, 2001, the detailed analysis of the new temporary tariffs of GdF and CFM, the offer of methane terminals access to third parties, the compatibility of a nodal tariffing with the presence of three transport operators (GdF, CFM and GSO), the contract-type for GdF supply, and the contract-type for GdF connection. (J.S.)

  7. Emballage naturel de produits biologiques

    NARCIS (Netherlands)

    Thoden van Velzen, E.U.

    2011-01-01

    Les emballages en plastique, renouvelables et biodégradables, sont-ils vraiment écologiques? Pour les entreprises d’emballage, il est difficile d’y trouver la réponse et donc de faire des choix réfléchis. Dans l’analyse ‘Emballage naturel’ le maximum de données a été collectionné et résumé.

  8. Suez-Gaz de France merger, E.ON's public takeover bid on Endesa... The new energy fight; Fusion Suez-Gaz de France, OPA d'E.ON sur Endesa... La nouvelle bataille de l'energie

    Energy Technology Data Exchange (ETDEWEB)

    Lepetit, V.; Rouaud, P.O.; Mairet, C

    2006-03-15

    The energy sector is in fever. In less than a week (February 21 to 26, 2006), the Europe of energy has fallen into a frenzy of mergers and acquisitions: the German E.ON offered 29.1 billion euros to get the Spanish Endesa, Electricite de France (EdF), who already got the Italian Edison in 2005, is ready for more major acquisitions, the Italian Enel is candidate for the repurchasing of Suez, while Gaz de France (GdF) and Suez have started a surprise merger. The stake of this match between giants is their growing up and the penetration of foreign markets before their complete liberalization in July 2007. The potential victims of these actions are the competition and the clients, the industrial ones first. (J.S.)

  9. Au dissolution during the anodic response of short-chain alkylthiols with polycrystalline Au electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Scott R. [Department of Chemistry and Biochemistry, Laurentian University, Sudbury, Ontario P3E 2C6 (Canada); Guerra, Eduard [School of Engineering, Laurentian University, Sudbury, Ontario P3E 2C6 (Canada); Siemann, Stefan [Department of Chemistry and Biochemistry, Laurentian University, Sudbury, Ontario P3E 2C6 (Canada); Shepherd, Jeffrey L., E-mail: jshepherd@laurentian.ca [Department of Chemistry and Biochemistry, Laurentian University, Sudbury, Ontario P3E 2C6 (Canada)

    2011-10-01

    Highlights: > 3-Mercaptopropionic acid (MPA) or meso-2,3-dimercaptosuccinic acid (DMSA) mediated Au corrosion in aqueous electrolytes at anodic potentials. > Au is roughened and passivated by an insoluble Au-MPA product. > Au is leached into the aqueous electrolyte as a soluble Au-DMSA species ({approx}60 ppb, 12 h). - Abstract: The electrochemical characteristics of polycrystalline Au in LiClO{sub 4} electrolyte solutions containing 3-mercaptopropionic acid (MPA) or meso-2,3-dimercaptosuccinic acid (DMSA) were studied with linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS) over a wide range of positive potentials vs. Ag/AgCl. The EIS data exhibited linear capacitive behaviour at 0.0 V with either MPA or DMSA added directly to the electrolyte suggesting the formation of an adsorbed layer of the alkylthiol on the electrode surface. Above this potential, a single well-defined impedance loop appeared for electrolyte solutions containing DMSA or MPA, an observation indicative of a charge transfer reaction that could be related to several processes including oxidative desorption, oxidation of the alkylthiol, or Au oxidation/dissolution. To test for Au dissolution, the electrode was held at 0.8 V vs. Ag/AgCl for 12 h in electrolytes containing MPA or DMSA followed by surface analysis with Atomic Force Microscopy and solution analysis with Atomic Absorption Spectroscopy. When the electrolyte contained MPA, the extended potential holding procedure resulted in significant roughening of the electrode with no detectable quantities of Au in the electrolyte. X-ray photoelectron spectroscopy (XPS) analysis of the Au surface revealed an additional species in the Au 4f{sub 7/2} spectrum indicating the presence of an insoluble electrochemically generated Au(I)-MPA species. When the electrolyte contained DMSA, the Au electrode appeared smoother, 56.6 {+-} 9.6 ppb of Au was detected in the electrolyte and the XPS analysis displayed a single species in the

  10. Au/Au@polythiophene core/shell nanospheres for heterogeneous catalysis of nitroarenes.

    Science.gov (United States)

    Shin, Hye-Seon; Huh, Seong

    2012-11-01

    Monodisperse Au/Au@polythiophene core/shell nanospheres were facilely prepared through the reduction of gold precursor, AuCl₄⁻, by 2-thiopheneacetonitrile in an aqueous solution. Concomitantly, 2-thiopheneacetonitrile polymerized during this redox process. As a result, Au nanoparticle was encapsulated by conductive polymer shell to afford novel core/shell nanospheres. Interestingly, the shell was composed of very tiny Au nanoparticles surrounded with thiophene polymers. Thus, the new material is best described as Au/Au@polythiophene core/shell nanospheres. FT-IR spectroscopy revealed that the Au nanoparticles were coordinated by the C≡N groups of the polythiophene shell. Some of the C≡N groups were partially hydrolyzed into COOH groups during the redox process because of the acidic reaction condition. The shell was conductive based on the typical ohmic behavior found in electrical measurement. The Au/Au@polythiophene core/shell nanospheres were found to be very active catalysts for the hydrogenation of various nitroarene compounds into corresponding aminoarene compounds in the presence of NaBH₄. Both hydrophilic and hydrophobic nitroarenes were efficiently hydrogenated under mild conditions.

  11. Filipino au pairs on the move

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2016-01-01

    interdependence, whilst they continuously form their trajectories in relation to opportunities and restraints posed along the way by their local and transnational social relations. The article argues that examinations of migration trajectories benefit from broadening the research out in both time and space......Most Filipina au pairs in Denmark send remittances back home, and for many, au pairing forms part of longer-term migration trajectories. This article explores how Filipina au pairs try to carve out a future for themselves abroad. It shows that they navigate within tight webs of financial...

  12. Becoming independent through au pair migration

    DEFF Research Database (Denmark)

    Dalgas, Karina Märcher

    2015-01-01

    . This article argues that, despite this critique, au pairing does play an important formative role for young Filipinas because it opens up for experiences abroad that enable them to be recognised as independent adults in Philippine society. Rather than autonomy, however, au pairs define their independence...... in terms of their capacity to assume responsibility for others, thereby achieving a position of social respect. Based on ethnographic fieldwork in Denmark and the Philippines, this article explores how young Filipinas use the social, economic, and cultural resources they gain from their au pair stay abroad...

  13. Synthesis of ultrathin face-centered-cubic Au@Pt and Au@Pd core-shell nanoplates from hexagonal-close-packed Au square sheets

    KAUST Repository

    Fan, Zhanxi

    2015-03-17

    The synthesis of ultrathin face-centered-cubic (fcc) Au@Pt rhombic nanoplates is reported through the epitaxial growth of Pt on hexagonal-close-packed (hcp) Au square sheets (AuSSs). The Pt-layer growth results in a hcp-to-fcc phase transformation of the AuSSs under ambient conditions. Interestingly, the obtained fcc Au@Pt rhombic nanoplates demonstrate a unique (101)f orientation with the same atomic arrangement extending from the Au core to the Pt shell. Importantly, this method can be extended to the epitaxial growth of Pd on hcp AuSSs, resulting in the unprecedented formation of fcc Au@Pd rhombic nanoplates with (101)f orientation. Additionally, a small amount of fcc (100)f-oriented Au@Pt and Au@Pd square nanoplates are obtained with the Au@Pt and Au@Pd rhombic nanoplates, respectively. We believe that these findings will shed new light on the synthesis of novel noble bimetallic nanostructures. Phase change: Ultrathin Au@Pt and Au@Pd core-shell nanoplates were prepared from Au square sheets. A phase transformation from hexagonal close-packed (hcp) to face-centered cubic (fcc) is observed upon coating the hcp Au square sheets with Pt or Pd under ambient conditions. The prepared fcc Au@Pt and Au@Pd rhombic nanoplates demonstrate unique (101)f orientation (picture shows a typical fcc Au@Pt rhombic nanoplate). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  14. Et pourquoi pas au CERN ?

    CERN Multimedia

    Staff Association

    2015-01-01

    Télétravail ou travail à distance, aménagement des horaires de travail et autres évolutions favorables à un meilleur équilibre vie privée et vie professionnelle sont adoptés par nombre d’entreprises et d’organisations !   Rendu possible grâce au développement de nouvelles technologies dont Internet, le travail à distance séduit de plus en plus de personnels, ainsi que de plus en plus de sociétés qui y trouvent des avantages en matière de gestion de l’espace, de sécurité (moins de trajets domicile-entreprise), de développement durable (moins de pollution), de motivation et de bien-être de leurs personnels. Les horaires aménagés, voire les « core-hours1 », sont également des pratiques de plus e...

  15. 1857-IJBCS-Article-Maman Maârouchi Inoussa

    African Journals Online (AJOL)

    hp

    naturel du fonctionnement de nombreux écosystèmes forestiers. Pendant des millénaires, les êtres humains ont ... comme processus naturel, il exerce une importante fonction dans le maintien du fonctionnement de ... sur les régimes de feu et l'émission des gaz qu'ils engendrent à travers des sites expérimentaux. Le but ...

  16. Untitled

    African Journals Online (AJOL)

    Les composts avec adjonction de produits locaux tels les phosphates naturels et la dolomie ont subi une décomposition plus rapide, atteignant après .... phate naturel du Burkina, dolomie) sus- ceptibles d'accélérer la décomposition de ..... carbone par départ de gaz carbonique et de composés volatiles). Parallèlement à.

  17. Labels de la construction : quelle contribution possible au facteur 4 ?

    Directory of Open Access Journals (Sweden)

    Valérie Laforest

    2011-03-01

    Full Text Available Le facteur 4, souvent évoqué comme objectif à atteindre face aux enjeux énergétiques et au changement climatique, est caractérisé par une double identité. Faisant à la fois référence à une augmentation de la productivité des ressources (facteur 4 « énergétique » et à l’atténuation des émissions de gaz à effet de serre (facteur 4 « climatique », il constitue l’objectif à atteindre dans les 40 ans. Dans ce but, différents secteurs d’activité se sont approprié ces concepts. Dans le secteur de la construction, la volonté d’améliorer les performances énergétiques et environnementales des bâtiments est passée par la création depuis les années 1990 des systèmes de labellisation. Les labels, par leurs approches normatives, se veulent être une des voies permettant de mettre en place les changements nécessaires pour atteindre les facteurs 4. Le but de cet article est d’étudier les différents types de labels de la construction et de voir comment et jusqu’à quel point ils permettent, ou non, d’atteindre les objectifs des facteurs 4.Factor 4, which is often presented as an objective to deal with energy and climate change issues, is characterized by a double identity. Referring at the same time to an increase of resources productivity (factor 4 for energy and to greenhouse gas attenuation (factor 4 for climate, it constitutes challenge to be reached in 40 years. To this end, the various branches of industry have adapted these concepts. In the building sector, this appropriation has been translated since 1990 by the creation of labeling systems. The labels by their standardized approach endeavor to be the precursors and the essential to drive these changes to the factors 4. The goal of this paper is to study the various types of labels that apply to sustainable construction and to study how and at which degree they contribute to factors 4 objectives.

  18. Comparative efficiencies of photothermal destruction of malignant cells using antibody-coated silica-Au nanoshells, hollow Au/Ag nanospheres and Au nanorods

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Fong-Yu; Chen, Chen-Tai; Yeh, Chen-Sheng, E-mail: csyeh@mail.ncku.edu.t [Department of Chemistry, National Cheng Kung University, Tainan 701, Taiwan (China)

    2009-10-21

    Three Au-based nanomaterials (silica-Au nanoshells, hollow Au/Ag nanospheres and Au nanorods) were evaluated for their comparative photothermal efficiencies at killing three types of malignant cells (A549 lung cancer cells, HeLa cervix cancer cells and TCC bladder cancer cells) using a CW NIR laser. Photodestructive efficiency was evaluated as a function of the number of nanoparticles required to destroy the cancer cells under 808 nm laser wavelength at fixed laser power. Of the three nanomaterials, silica/Au nanoshells needed the minimum number of particles to produce effective photodestruction, whereas Au nanorods needed the largest number of particles. Together with the calculated photothermal conversion efficiency, the photothermal efficiency rankings are silica-Au nanoshells > hollow Au/Ag nanospheres > Au nanorods. Additionally, we found that HeLa cells seem to present better heat tolerance than the other two cancer cell lines.

  19. Revue des aspects hydrodynamiques des réacteurs catalytiques gaz-liquide-solide à lit fixe arrosé Hydrodynamics of Gas-Liquid-Solid Trickle-Bed Reactors: a Critical Review

    Directory of Open Access Journals (Sweden)

    Attou A.

    2006-12-01

    élation empirique de la perte de pression et du taux de rétention de liquide ne correspond à une erreur relative moyenne de prédiction acceptable. Seul le modèle phénoménologique étendu d'Al-Dahhan et al. (1998 semble constituer une technique satisfaisante pour la prédiction des deux paramètres hydrodynamiques en régime ruisselant. Néanmoins, son principal inconvénient réside dans la nécessité de déterminer préalablement les deux coefficients du modèle au moyen d'expériences sur des écoulements monophasiques gazeux. De telles expériences restent difficiles à réaliser dans la pratique. Il est cependant regrettable de constater qu'aucune des ces méthodes, qui se distinguent par leurs résultats, n'est basée sur une approche physique des phénomènes hydrodynamiques permettant d'améliorer la connaissance de ces écoulements et de prédire leur comportement en dehors des domaines de conditions expérimentales testées. De ce travail, il ressort la nécessité d'appliquer les outils classiques de la mécanique des fluides diphasique à la description de ces écoulements, en apportant une attention particulière aux phénomènes d'interactions hydrodynamiques auxquelles sont soumises les trois phases du système (gaz, liquide et solide. While it is recognised that the hydrodynamic aspects have a considerable importance in the design and the operation of gas-liquid-solid trickle-bed reactors, the accuracy of the proposed calculation methods remains poor. Most studies in this field have been performed in atmospheric conditions in contrast of industrial reactors operating at quite high pressures. Only recently, some experimental results have been obtained at elevated pressures and correlations have been proposed in these conditions in order to predict the tricking-pulsing transition, the pressure drop and the liquid holdup. The scope of this article is twice. Firstly, the knowledge on the several hydrodynamic aspects of three-phase trickle-bed reactors, including

  20. 'Abd-Allāh Ben Yāsīn Al-Gazūlī

    OpenAIRE

    Deverdun, G.

    2013-01-01

    « Fondateur de la dynastie almoravide et un des trois principaux apôtres de l’Islam au Maghreb, avec Sidi ‘Ukba et Moulay Idrīs Ier », selon ‘Abd-Allāh Gannūn, dans ses « Célébrités Marocaines. » Vers 1040, le chef de la confédération des Ṣinhādja, chameliers du Sahara occidental, Yahiā b. Ibrahim, fit le pèlerinage à La Mecque et, durant son long voyage, constata avec peine dans quelle médiocrité religieuse vivaient ses contribules. Tombeau de Sidi ‘Abd Allah moul 1-Gara (oued Korifla, Maroc...

  1. Initial Eccentricity in Deformed 197Au+197Au and 238U+238U Collisions at RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Filip, Peter; Lednicky, Richard; Masui, Hiroshi; Xu, Nu

    2010-07-07

    Initial eccentricity and eccentricity fluctuations of the interaction volume created in relativistic collisions of deformed {sup 197}Au and {sup 238}U nuclei are studied using optical and Monte-Carlo (MC) Glauber simulations. It is found that the non-sphericity noticeably influences the average eccentricity in central collisions and eccentricity fluctuations are enhanced due to deformation. Quantitative results are obtained for Au+Au and U+U collisions at energy {radical}s{sub NN} = 200 GeV.

  2. Photovoltage responses of graphene-Au heterojunctions

    Science.gov (United States)

    Li, Kai; Ying, Xiangxiao; Wang, Juan; Wang, Jun; Jiang, Yadong; Liu, Zhijun

    2017-10-01

    As an emerging 2D material, graphene's several unique properties, such as high electron mobility, zero-bandgap and low density of states, present new opportunities for light detections. Here, we report on photovoltage responses of graphene-Au heterojunctions, which are made of monolayer graphene sheets atop Au electrodes designed as finger-shape and rectangle-shape, respectively. Besides confirming the critical role of space charge regions located at the graphene-Au boundary, photovoltage responses are measured in the visible to infrared spectral region with a cut-off wavelength at about 980 nm, which is likely imposed by the Pauli blocking of interband transition in the contact-doped graphene. The photoresponsivity is shown to decrease with increasing wavelength. A band diagram of the graphene-Au heterojunction is proposed to understand the photoresponse mechanism.

  3. Intense fluorescence of Au 20

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Chongqi; Harbich, Wolfgang; Sementa, Luca; Ghiringhelli, Luca; Apra, Edoardo; Stener, Mauro; Fortunelli, Alessandro; Brune, Harald

    2017-08-21

    Ligand-protected Au clusters are non-bleaching fluorescence markers in bio- and medical applications. We show that their fluorescence is an intrinsic property of the Au cluster itself. We find a very intense and sharp fluorescence peak located at λ =739.2 nm (1.68 eV) for Au20 clusters in a Ne matrix held at 6 K. The fluorescence reflects the HOMO-LUMO diabatic bandgap of the cluster. The cluster shows a very rich absorption fine structure reminiscent of well defined molecule-like quantum levels. These levels are resolved since Au20 has only one stable isomer (tetrahedral), therefore our sample is mono-disperse in cluster size and conformation. Density-functional theory (DFT) and time-dependent DFT calculations clarify the nature of optical absorptionand predict both main absorption peaks and intrinsic fluorescence in good agreement with experiment.

  4. PHENIX results on jets in d + Au

    Science.gov (United States)

    Hanks, J. Ali

    2016-12-01

    We present recently published results [A. Adare, et al., arxiv:arXiv:1509.04657] on fully reconstructed R=0.3 anti-kt jets measured in p+p and d+Au collisions at 200 GeV center-of-mass energy. The jet yields for four centrality classes along with the p+p reference are presented, as well as both the minimum bias RdAu and centrality dependent RdAu and RCP. We find that while the minimum bias RdA is consistent with unity, providing a strong constraint on models including cold-nuclear-matter effects or energy loss in small systems, the centrality dependent RdAu show a striking variation which presents a challenge to models attempting to describe the interplay between soft and hard processes in these systems.

  5. 22 CFR 62.31 - Au pairs.

    Science.gov (United States)

    2010-04-01

    ....31 Au pairs. (a) Introduction. This section governs Department of State-designated exchange visitor... requirements set forth at § 62.10 sponsors shall: (1) Inform all host families of the philosophy, rules, and...

  6. Unravelling Thiol’s Role in Directing Asymmetric Growth of Au Nanorod–Au Nanoparticle Dimers

    KAUST Repository

    Huang, Jianfeng

    2015-12-15

    Asymmetric nanocrystals have practical significance in nanotechnologies but present fundamental synthetic challenges. Thiol ligands have proven effective in breaking the symmetric growth of metallic nanocrystals but their exact roles in the synthesis remain elusive. Here, we synthesized an unprecedented Au nanorod-Au nanoparticle (AuNR-AuNP) dimer structure with the assistance of a thiol ligand. On the basis of our experimental observations, we unraveled for the first time that the thiol could cause an inhomogeneous distribution of surface strains on the seed crystals as well as a modulated reduction rate of metal precursors, which jointly induced the asymmetric growth of monometallic dimers. © 2015 American Chemical Society.

  7. "Dealloying" Phase Separation during Growth of Au on Ni(110)

    DEFF Research Database (Denmark)

    Nielsen, L. Pleth; Besenbacher, Flemming; Stensgaard, I.

    1995-01-01

    Combined scanning tunneling microscopy and ion-scattering studies have revealed a new "dealloying" phase transition during the growth of Au on Ni(110). The Au atoms, which initially alloy into the Ni(110) surface, phase separate into a vacancy-stabilized Au dimer-trimer chain structure at Au...

  8. Enantioselective separation on chiral Au nanoparticles.

    Science.gov (United States)

    Shukla, Nisha; Bartel, Melissa A; Gellman, Andrew J

    2010-06-30

    The surfaces of chemically synthesized Au nanoparticles have been modified with d- or l-cysteine to render them chiral and enantioselective for adsorption of chiral molecules. Their enantioselective interaction with chiral compounds has been probed by optical rotation measurements during exposure to enantiomerically pure and racemic propylene oxide. The ability of optical rotation to detect enantiospecific adsorption arises from the fact that the specific rotation of polarized light by (R)- and (S)-propylene oxide is enhanced by interaction with Au nanoparticles. This effect is related to previous observations of enhanced circular dichroism by Au nanoparticles modified by chiral adsorbates. More importantly, chiral Au nanoparticles modified with either d- or l-cysteine selectively adsorb one enantiomer of propylene oxide from a solution of racemic propylene oxide, thus leaving an enantiomeric excess in the solution phase. Au nanoparticles modified with l-cysteine (d-cysteine) selectively adsorb the (R)-propylene oxide ((S)-propylene oxide). A simple model has been developed that allows extraction of the enantiospecific equilibrium constants for (R)- and (S)-propylene oxide adsorption on the chiral Au nanoparticles.

  9. Apprentissages techniques : L'apprentissage au CERN

    CERN Document Server

    2004-01-01

    APPRENTISSAGES TECHNIQUES GESTION ET DEVELOPPEMENT DU PERSONNEL HR/PMD L'APPRENTISSAGE AU CERN pour les professions d'électronicien(ne) et de laborantin(e) en physique L'apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le Canton de Genève. En cas de réussite à l'examen de fin d'apprentissage, les apprentis obtiennent le Certificat Fédéral de Capacité Suisse (CFC). 7 places au total sont ouvertes au recrutement pour les deux professions. L'apprentissage dure 4 ans. Minima requis pour faire acte de candidature : • avoir au moins 15 ans et moins de 21 ans à la date de début de l'apprentissage • avoir terminé la scolarité obligatoire, au minimum 9ème du Cycle d'orientation genevois (3ème en France) • être ressortissant d'un pays membre du CERN (Allemagne, Autriche, Belgiqu...

  10. Systematic Measurements of Identified Particle Spectra in pp, d+Au and Au+Au Collisions from STAR

    Energy Technology Data Exchange (ETDEWEB)

    STAR Coll

    2009-04-11

    Identified charged particle spectra of {pi}{sup {+-}}, K{sup {+-}}, p and {bar p} at mid-rapidity (|y| < 0.1) measured by the dE/dx method in the STAR-TPC are reported for pp and d + Au collisions at {radical}s{sub NN} = 200 GeV and for Au + Au collisions at 62.4 GeV, 130 GeV, and 200 GeV. Average transverse momenta, total particle production, particle yield ratios, strangeness and baryon production rates are investigated as a function of the collision system and centrality. The transverse momentum spectra are found to be flatter for heavy particles than for light particles in all collision systems; the effect is more prominent for more central collisions. The extracted average transverse momentum of each particle species follows a trend determined by the total charged particle multiplicity density. The Bjorken energy density estimate is at least several GeV/fm{sub 3} for a formation time less than 1 fm/c. A significantly larger net-baryon density and a stronger increase of the net-baryon density with centrality are found in Au + Au collisions at 62.4 GeV than at the two higher energies. Antibaryon production relative to total particle multiplicity is found to be constant over centrality, but increases with the collision energy. Strangeness production relative to total particle multiplicity is similar at the three measured RHIC energies. Relative strangeness production increases quickly with centrality in peripheral Au + Au collisions, to a value about 50% above the pp value, and remains rather constant in more central collisions. Bulk freeze-out properties are extracted from thermal equilibrium model and hydrodynamics-motivated blast-wave model fits to the data. Resonance decays are found to have little effect on the extracted kinetic freeze-out parameters due to the transverse momentum range of our measurements. The extracted chemical freeze-out temperature is constant, independent of collision system or centrality; its value is close to the predicted phase

  11. Fully Cationized Gold Clusters: Synthesis of Au25(SR+)18.

    Science.gov (United States)

    Ishida, Yohei; Narita, Kunihiro; Yonezawa, Tetsu; Whetten, Robert L

    2016-10-06

    Although many thiolate-protected Au clusters with different numbers of Au atoms and a variety of thiolate ligands have been synthesized, to date there has been no report of a fully cationized Au cluster protected with cationic thiolates. Herein, we report the synthesis of the first member of a new series of thiolate-protected Au cluster molecules: a fully cationized Au 25 (SR + ) 18 cluster.

  12. Suppression of ϒ production in d+Au and Au+Au collisions at √(s{sub NN})=200 GeV

    Energy Technology Data Exchange (ETDEWEB)

    Adamczyk, L. [AGH University of Science and Technology, Cracow (Poland); Adkins, J.K. [University of Kentucky, Lexington, KY, 40506-0055 (United States); Agakishiev, G. [Joint Institute for Nuclear Research, Dubna, 141 980 (Russian Federation); Aggarwal, M.M. [Panjab University, Chandigarh 160014 (India); Ahammed, Z. [Variable Energy Cyclotron Centre, Kolkata 700064 (India); Alekseev, I. [Alikhanov Institute for Theoretical and Experimental Physics, Moscow (Russian Federation); Alford, J. [Kent State University, Kent, OH 44242 (United States); Anson, C.D. [Ohio State University, Columbus, OH 43210 (United States); Aparin, A. [Joint Institute for Nuclear Research, Dubna, 141 980 (Russian Federation); Arkhipkin, D.; Aschenauer, E.C. [Brookhaven National Laboratory, Upton, NY 11973 (United States); Averichev, G.S. [Joint Institute for Nuclear Research, Dubna, 141 980 (Russian Federation); Balewski, J. [Massachusetts Institute of Technology, Cambridge, MA 02139-4307 (United States); Banerjee, A. [Variable Energy Cyclotron Centre, Kolkata 700064 (India); Barnovska, Z. [Nuclear Physics Institute AS CR, 250 68 Řež/Prague (Czech Republic); Beavis, D.R. [Brookhaven National Laboratory, Upton, NY 11973 (United States); Bellwied, R. [University of Houston, Houston, TX, 77204 (United States); Bhasin, A. [University of Jammu, Jammu 180001 (India); Bhati, A.K. [Panjab University, Chandigarh 160014 (India); Bhattarai, P. [University of Texas, Austin, TX 78712 (United States); and others

    2014-07-30

    We report measurements of ϒ meson production in p+p, d+Au, and Au+Au collisions using the STAR detector at RHIC. We compare the ϒ yield to the measured cross section in p+p collisions in order to quantify any modifications of the yield in cold nuclear matter using d+Au data and in hot nuclear matter using Au+Au data separated into three centrality classes. Our p+p measurement is based on three times the statistics of our previous result. We obtain a nuclear modification factor for ϒ(1S+2S+3S) in the rapidity range |y|<1 in d+Au collisions of R{sub dAu}=0.79±0.24(stat.)±0.03(syst.)±0.10(p+p syst.). A comparison with models including shadowing and initial state parton energy loss indicates the presence of additional cold-nuclear matter suppression. Similarly, in the top 10% most-central Au+Au collisions, we measure a nuclear modification factor of R{sub AA}=0.49±0.1(stat.)±0.02(syst.)±0.06(p+psyst.), which is a larger suppression factor than that seen in cold nuclear matter. Our results are consistent with complete suppression of excited-state ϒ mesons in Au+Au collisions. The additional suppression in Au+Au is consistent with the level expected in model calculations that include the presence of a hot, deconfined Quark–Gluon Plasma. However, understanding the suppression seen in d+Au is still needed before any definitive statements about the nature of the suppression in Au+Au can be made.

  13. 100-MeV proton beam intensity measurement by Au activation analysis using {sup 197}Au(p, pn){sup 196}Au and {sup 197}Au(p, p3n){sup 194}Au reactions

    Energy Technology Data Exchange (ETDEWEB)

    Mokhtari Oranj, Leila [Division of Advanced Nuclear Engineering, POSTECH, Pohang 37673 (Korea, Republic of); Jung, Nam-Suk; Oh, Joo-Hee [Pohang Accelerator Laboratory, POSTECH, Pohang 37673 (Korea, Republic of); Lee, Hee-Seock, E-mail: lee@postech.ac.kr [Pohang Accelerator Laboratory, POSTECH, Pohang 37673 (Korea, Republic of)

    2016-05-15

    The proton beam intensity of a 100-MeV proton linac at the Korea Multi-purpose Accelerator Complex (KOMAC) was measured by an Au activation analysis using {sup 197}Au(p, pn){sup 196}Au and {sup 197}Au(p, p3n){sup 194}Au reactions to determine the accuracy and precision of beam intensity measurement using Gafchromic film dosimetry method. The target, irradiated by 100-MeV protons, was arranged in a stack consisting of Au, Al foils and Pb plates. The yields of produced radio-nuclei in Au foils were obtained by gamma-ray spectroscopy. The FLUKA code was employed to calculate the energy spectrum of protons onto the front surface of Au foils located at three different depth points of the target and also to investigate the condition of incident beam on the target. A good agreement was found between the beam intensity measurements using the activation analysis method at three different depth points of the target. An excellent agreement was also observed between the beam intensity measurements using the Au activation analysis method and the dosimetry method using Gafchromic film.

  14. Possibilités de contribution de la gazéification Lurgi à notre approvisionnement énergétique futur Potential Contribution of Lurgi Gasification to Our Future Energy Supplies

    Directory of Open Access Journals (Sweden)

    Eckert G.

    2006-11-01

    Full Text Available Pour la valorisation du charbon, la gazéification est une possibilité immédiatement utilisable et industriellement éprouvée, qui présente l'avantage de permettre la production des formes d'énergie secondaire, auxquelles nous sommes habitués. Indépendamment du produit final, une unité de conversion du charbon est toujours constituée d'étapes de transformation successives, mettant en oeuvre des procédés adaptés, parmi lesquels la gazéification de charbon proprement dite constitue la première étape qui n'est cependant qu'une opération parmi d'autres. Le traitement des gaz et la séparation des produits secondaires sont mis en oeuvre également et sont importants dans l'ensemble du complexe de traitement. Dans la communication présentée, trois possibilités différentes sont évoquées : - production de gaz de chauffage de différents pouvoirs calorifiques ; - production de méthanol et transformation éventuelle de celui-ci en essence ; - production d'hydrocarbures par la synthèse de Fischer-Tropsch. Une approche économique générale dégage une idée d'ensemble sur la situation et l'intérêt des techniques de conversion du charbon à l'heure actuelle. For the upgrading of coal, gasification is an immediately available and industrially well-proven possibility which has the advantage of making it possible to produce the types of secondary energy to which we have become accustomed. Independently of the end product, a coal conversion plant always consists of successive transformation steps making use of suitable processes, among which coal gasification itself is the first such step, although being only one operation among others. Gas processing and secondary products separation are also implemented and are important in the overall processing complex. This article brings out three different possibilities: (a production of fuel gas with different heating values; (b production of methanol and eventual transformation into gasoline

  15. Conséquences des travaux d'entretien des chaussées sur les consommations en carburant et émissions de gaz à effet de serre

    OpenAIRE

    BRILLET, F; VADEPIED, C

    2007-01-01

    L'entretien des chaussées sert à restaurer les qualités d'usage, qui conditionnent sécurité, confort, silence, mais aussi diminuent la consommation en carburant et donc les émissions de gaz à effet de serre (dioxyde de carbone principalement). En contrepartie, les véhicules consomment et émettent davantage lors des travaux, du fait des ralentissements, bouchons et déviations. Lors du contrat européen FORMAT (Fully Optimised Road Maintenance, 2002-2005), un calcul du temps perdu sur chantier a...

  16. Toward hybrid Au nanorods @ M (Au, Ag, Pd and Pt) core-shell heterostructures for ultrasensitive SERS probes

    Science.gov (United States)

    Xie, Xiaobin; Gao, Guanhui; Kang, Shendong; Lei, Yanhua; Pan, Zhengyin; Shibayama, Tamaki; Cai, Lintao

    2017-06-01

    Being able to precisely control the morphologies of noble metallic nanostructures is of essential significance for promoting the surface-enhanced Raman scattering (SERS) effect. Herein, we demonstrate an overgrowth strategy for synthesizing Au @ M (M = Au, Ag, Pd, Pt) core-shell heterogeneous nanocrystals with an orientated structural evolution and highly improved properties by using Au nanorods as seeds. With the same reaction condition system applied, we obtain four well-designed heterostructures with diverse shapes, including Au concave nanocuboids (Au CNs), Au @ Ag crystalizing face central cube nanopeanuts, Au @ Pd porous nanocuboids and Au @ Pt nanotrepangs. Subsequently, the exact overgrowth mechanism of the above heterostructural building blocks is further analysed via the systematic optimiziation of a series of fabrications. Remarkably, the well-defined Au CNs and Au @ Ag nanopeanuts both exhibit highly promoted SERS activity. We expect to be able to supply a facile strategy for the fabrication of multimetallic heterogeneous nanostructures, exploring the high SERS effect and catalytic activities.

  17. Leading Hadron Production in d+Au and 3He+Au collisions in the PHENIX experiment

    Science.gov (United States)

    Sakaguchi, Takao; Phenix Collaboration

    2017-08-01

    Neutral pions have been measured in 3He+Au collisions at √{sNN } = 200 GeV up to 20 GeV/c in the RHIC Year-2014 run. The nuclear modification factor RAA was measured and compared with that from d+Au collisions. The integrated RAA as a function of Npart was calculated for d+Au, 3He+Au and Au+Au collisions at √{sNN } = 200 GeV, and found to converge for Npart > 12, while a clear system ordering RdAu >RHeAu >RAuAu was observed for Npart > 12. The fractional momentum loss for the most central 3He+Au collisions was also estimated.

  18. INDRA at GSI; INDRA au GSI

    Energy Technology Data Exchange (ETDEWEB)

    Bougault, R.; Bocage, F.; Durand, D.; Lopez, O.; Steckmeyer, J.C.; Tamain, B.; Vient, E. [Lab. de Physique Corpusculaire, Caen Univ., 14 (France); Collaboration INDRA: IPN-Orsay, DAPNIA-Saclay, SUBATECH-Nantes, IPN- Lyon, GANIL-Caen

    1997-12-31

    In connection to the decision of installing the INDRA detector by the SIS synchrocyclotron at GSI (Darmstadt, Germany) the report presents the tasks taken into account by the LPC-Caen. These refer to the detector displacement and (mechanical) installation at GSI, the tests before beam (i.e. electronics acquisition software, detectors, etc.) as well as the data acquisition and processing. The physical pro-arguments mention the possibility of disposing of heavy ion beams in a range from 50 MeV to several GeV/nucleon so extending the study of multifragmentation done at GANIL between 30 and 90 MeV/nucleon. More specific, the scientific program of INDRA at GSI inserts studies between those done at around Fermi energy, were the reaction mechanisms are of type of deep inelastic scattering/incomplete fusion, and the studies in the relativistic energy domain where the individual properties of nucleons and transparency of nuclear matter implies mechanisms of the participant-spectator type (fire-ball creation). Also mentioned as fields of extensive studies are: the multifragmentation and its fundamental relation with the nuclear matter equation of state, the role of reaction dynamics in the appearance of collective effects of the radial flow type and its relations with the nuclear compressibility and phase transitions and the thermodynamics of nuclear matter. It appeared that the heavy systems Xe + Sn and Au + Au are the best compromise for the different topics to be approached. The bombarding energies extend from 50 to 150 MeV/nucleon. The report ends with the table giving for six heavy systems (Xe + Sn, Au + Au, C + Au, Ar + Au and P + Au) the required bombarding energies 15 refs.

  19. The extraction characteristic of Au-Ag from Au concentrate by thiourea solution

    Science.gov (United States)

    Kim, Bongju; Cho, Kanghee; On, Hyunsung; Choi, Nagchoul; Park, Cheonyoung

    2013-04-01

    The cyanidation process has been used commercially for the past 100 years, there are ores that are not amenable to treatment by cyanide. Interest in alternative lixiviants, such as thiourea, halogens, thiosulfate and malononitrile, has been revived as a result of a major increase in gold price, which has stimulated new developments in extraction technology, combined with environmental concern. The Au extraction process using the thiourea solvent has many advantages over the cyanidation process, including higher leaching rates, faster extraction time and less than toxicity. The purpose of this study was investigated to the extraction characteristic of Au-Ag from two different Au concentrate (sulfuric acid washing and roasting) under various experiment conditions (thiourea concentration, pH of solvent, temperature) by thiourea solvent. The result of extraction experiment showed that the Au-Ag extraction was a fast extraction process, reaching equilibrium (maximum extraction rate) within 30 min. The Au-Ag extraction rate was higher in the roasted concentrate than in the sulfuric acid washing. The higher the Au-Ag extraction rate (Au - 70.87%, Ag - 98.12%) from roasted concentrate was found when the more concentration of thiourea increased, pH decreased and extraction temperature increased. This study informs extraction method basic knowledge when thiourea was a possibility to eco-/economic resources of Au-Ag utilization studies including the hydrometallurgy.

  20. Multistep production of eta and hard pi(0) mesons in subthreshold Au-Au collisions

    NARCIS (Netherlands)

    Appenheimer, M; Averbeck, R; Charbonnier, Y; Diaz, J; Doppenschmidt, A; Hejny, [No Value; Hlavac, S; Holzmann, R; Kugler, A; Lohner, H; Marin, A; Metag, [No Value; Novotny, R; Ostendorf, RW; Pleskac, R; Schubert, A; Schutz, Y; Simon, RS; Stratmann, R; Stroher, H; Tlusty, P; Vogt, PH; Wagner, [No Value; Weiss, J; Wilschut, HW; Wissmann, F; Wolf, M

    1998-01-01

    The neutral pi(o) and eta mesons are studied in Au-197-Au-197 collisions at an incident energy of 800A MeV, substantially below the threshold for eta production in N-N collisions. While the gross pi(o) multiplicity increases almost linearly with the number of participant nucleons, the multiplicities

  1. Au/ZnO nanoarchitectures with Au as both supporter and antenna of visible-light

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Tianyu; Chen, Wei; Hua, Yuxiang; Liu, Xiaoheng, E-mail: xhliu@mail.njust.edu.cn

    2017-01-15

    Highlights: • An inversed Au/ZnO nanostructure was fabricated with ZnO loaded onto Au. • The Au/ZnO nanocomposites showed enhanced properties in visible-light photocatalysis. • The SPR effect of Au was considered important for visible-light photocatalysis. - Abstract: In this paper, we fabricate Au/ZnO nanostructure with smaller ZnO nanoparticles loaded onto bigger gold nanoparticles via combining seed-mediated method and sol-gel method. The obtained Au/ZnO nanocomposites exhibit excellent properties in photocatalysis process like methyl orange (MO) degradation and oxidative conversion of methanol into formaldehyde under visible light irradiation. The enhanced properties were ascribed to the surface plasmon resonance (SPR) effect of Au nanoparticles, which could contribute to the separation of photo-excited electrons and holes and facilitate the process of absorbing visible light. This paper contributes to the emergence of multi-functional nanocomposites with possible applications in visible-light driven photocatalysts and makes the Au/ZnO photocatalyst an exceptional choice for practical applications such as environmental purification of organic pollutants in aqueous solution and the synthesis of fine chemicals and intermediates.

  2. Using supported Au nanoparticles as starting material for preparing uniform Au/Pd bimetallic catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Villa, Alberto [Universita di Milano, Italy; Prati, Laura [Universita di Milano, Italy; Su, Dangshen [Fritz Haber Institute of the Max Planck Society, Berlin, Germany; Wang, Di [Fritz Haber Institute of the Max Planck Society, Berlin, Germany; Veith, Gabriel M [ORNL

    2010-01-01

    One of the best methods for producing bulk homogeneous (composition) supported bimetallic AuPd clusters involves the immobilization of a protected Au seed followed by the addition of Pd. This paper investigates the importance of this gold seed in controlling the resulting bimetallic AuPd clusters structures, sizes and catalytic activities by investigating three different gold seeds. Uniform Au-Pd alloy were obtained when a steric/electrostatic protecting group, poly(vinyl alcohol) (PVA), was used to form the gold clusters on activated carbon (AC). In contrast Au/AC precursors prepared using Au nanoparticles with only electrostatic stabilization (tetrakis(hydroxypropyl)phosphonium chloride (THPC)), or no stabilization (magnetron sputtering) produced inhomogeneous alloys and segregation of the gold and palladium. The uniform alloyed catalyst (Pd{at}Au{sub PVA}/AC) is the most active and selective catalyst, while the inhomogenous catalysts are less active and selective. Further study of the PVA protected Au clusters revealed that the amount of PVA used is also critical for the preparation of uniform alloyed catalyst, their stability, and their catalytic activity.

  3. Directed flow of antiprotons in Au+Au collisions at AGS

    OpenAIRE

    Barrette, J.; Bellwied, R.; Bennett, S.; Bersch, R.; Braun-Munzinger, P.; Chang, W. C.; Cleland, W. E.; Clemen, M.; Cole, J.; Cormier, T. M.; Dai, Y.; David, G.; Dee, J.; Dietzsch, O.; Drigert, M.

    2000-01-01

    Directed flow of antiprotons is studied in Au+Au collisions at a beam momentum of 11.5A GeV/c. It is shown that antiproton directed flow is anti-correlated to proton flow. The measured transverse momentum dependence of the antiproton flow is compared with predictions of the RQMD event generator.

  4. Stability of gold cages (Au16 and Au17) at finite temperature

    Indian Academy of Sciences (India)

    2015-11-27

    Nov 27, 2015 ... We have employed ab initio molecular dynamics to investigate the stability of the smallest gold cages, namely Au16 and Au17, at finite temperatures. First, we obtain the ground state structure along with at least 50 distinct isomers for both the clusters. This is followed by the finite temperature simulations of ...

  5. Charged particle density distributions in Au·Au collisions at ...

    Indian Academy of Sciences (India)

    Charged particle pseudorapidity distributions have been measured in Au·Au collisions using the BRAHMS ... Relativistic heavy-ion collisions; charged hadron production; pseudorapidity distribu- tions; centrality .... the predictions of two different theoretical models: (i) the high density gluon saturation model of Kharzeev and ...

  6. Low-temperature solution synthesis of the non-equilibrium ordered intermetallic compounds Au3Fe, Au3Co, and Au3Ni as nanocrystals.

    Science.gov (United States)

    Vasquez, Yolanda; Luo, Zhiping; Schaak, Raymond E

    2008-09-10

    Alloys and intermetallic compounds of Au with the 3d transition metals Fe, Co, and Ni are nonequilibrium phases that have many useful potential applications as catalytic, magnetic, optic, and multifunctional magneto-optic materials. However, the atomically ordered Au-M (M = Fe, Co, Ni) intermetallics are particularly elusive from a synthetic standpoint. Here we report the low-temperature solution synthesis of the L12 (Cu3Au-type) intermetallic compounds Au3Fe, Au3Co, and Au3Ni using n-butyllithium as a reducing agent. Reaction pathway studies for the Au3Co system indicate that Au nucleates first, followed by Co incorporation to form the intermetallic. The nonequilibrium intermetallic nanocrystals have been characterized by powder XRD, TEM, EDS, selected area electron diffraction, and nanobeam electron diffraction, which collectively confirm the compositions and superlattice structures.

  7. N.3277 notice presented for the Finances, Economy and Plan Commission on the articles 4, 10, 11 and 12 of the law project n.3201 relative to the energy sector; N.3277 avis presente au nom de la Commission des Finances, de l'Economie Generale et du Plan sur les articles 4, 10, 11 et 12 du projet de loi (n.3201) relatif au secteur de l'energie

    Energy Technology Data Exchange (ETDEWEB)

    Novelli, H

    2006-08-15

    In the framework of the law project relative to the energy sector in France, this notice details the context, the markets opening and the free choice for the consumer, the dispositions relative to the capital of Gaz de France and the government control and the juridical aspects of Gaz de France privatization. (A.L.B.)

  8. Jets and dijets in Au+Au and p+p collisions at RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Hardtke, D.; STAR Collaboration

    2002-12-09

    Recent data from RHIC suggest novel nuclear effects in the production of high p{sub T} hadrons. We present results from the STAR detector on high p{sub T} angular correlations in Au+Au and p+p collisions at {radical}S = 200 GeV/c. These two-particle angular correlation measurements verify the presence of a partonic hard scattering and fragmentation component at high p{sub T} in both central and peripheral Au+Au collisions. When triggering on a leading hadron with p{sub T}>4 GeV, we observe a quantitative agreement between the jet cone properties in p+p and all centralities of Au+Au collisions. This quantitative agreement indicates that nearly all hadrons with p{sub T}>4 GeV/c come from jet fragmentation and that jet fragmentation properties are not substantially modified in Au+Au collisions. STAR has also measured the strength of back-to-back high p{sub T} charged hadron correlations, and observes a small suppression of the back-to-back correlation strength in peripheral collisions, and a nearly complete disappearance o f back-to-back correlations in central Au+Au events. These phenomena, together with the observed strong suppression of inclusive yields and large value of elliptic flow at high p{sub T}, are consistent with a model where high p{sub T} hadrons come from partons created near the surface of the collision region, and where partons that originate or propagate towards the center of the collision region are substantially slowed or completely absorbed.

  9. Rapidity density distributions in Au+Au and Au+Ag interactions at 11.6 A GeV/c

    Energy Technology Data Exchange (ETDEWEB)

    Nystrand, J.I. [Div. of Cosmic and Subatomic Physis, Lund Univ. (Sweden); Adamovich, M.I.; Aggarwal, M.M.; Alexandrov, Y.A.; Andreeva, N.P.; Anzon, Z.V.; Arora, R.; Avetyan, F.A.; Badyal, S.K.; Basova, E.; Bazarov, I.K.; Bhalla, K.B.; Bhasin, A.; Bhatia, V.S.; Bogdanov, V.G.; Bubnov, V.I.; Burnett, T.H.; Cai, X.; Carshiev, D.A.; Ceitimbetov, A.M.; Chasnikov, I.Y.; Chernova, L.P.; Chernyavsky, M.M.; Eligbaeva, G.Z.; Eremenko, L.E.; Gaitinov, A.S.; Ganssauge, E.R.; Garpman, S.; Gerassimov, S.G.; Graf, C.; Grote, J.; Gulamov, K.G.; Gupta, S.K.; Gupta, V.K.; Jakobsson, B.; Just, L.; Kachroo, S.; Kalyachkina, G.S.; Kanygina, E.K.; Karabova, M.; Kharlamov, S.P.; Kitroo, S.; Krasnov, S.A.; Kumar, V.; Larionova, V.G.; Li, Y.D.; Liu, L.S.; Lokanatan, S.; Lord, J.J.; Lukicheva, N.S.; Luo, S.B.; Maksimkina, T.N.; Mangotra, L.K.; Marutyan, N.A.; Maslennikova, N.V.; Mittra, I.S.; Mookerjee, S.; Musulmanbekov, J.J.; Nasyrov, S.Z.; Navotny, V.S.; Ochs, M.; Orlova, G.I.; Otterlund, I.; Peresadko, N.G.; Petrov, N.V.; Plyushchev, V.A.; Qian, W.Y.; Qin, Y.M.; Raniwala, R.; Raniwala, S.; Rao, N.K.; Roeper, M.; Saidkhanov, N.; Salmanova, N.A.; Sarkisova, L.G.; Sarkisyan, V.R.; Shabratova, G.S.; Shakhova, T.I.; Shpilev, S.N.; Skelding, D.; Soederstrom, K.; Solovjeva, Z.I.; Stenlund, E; Surin, E.L.; Svechnikova, L.N.; Tolstov, K.D.; Tothova, M.; Tretyakova, M.I.; Trofimova, T.P.; Tuleeva, U.; Tursunov, B.P.; Vokal, S.; Vrlakova, J.; Wang, H.Q.; Weng, Z.Q.; Wilkes, R.J.; Xia, Y.L.; Yang, C.B.; Zhang, D.H.; Zheng, P.Y.; Zhokhova, S.I.; Zhou, D.C.; EMU01 Collaboration

    1994-01-03

    Pseudorapidity density distributions of charged particles in heavy-ion collisions have been studied. The results from EMU01 have been compared to the results from the experiments WA80 and E802. The recently obtained pseudorapidity distributions from Au+Au and Au+Ag interactions have been compared to a linear extrapolation from lighter systems. (orig.)

  10. Appareils à pression de gaz ou de vapeur en acier -Qualification d'un mode opératoire de soudage - Cas d'un assemblage destiné à fixer sur une paroi une pièce boulonnée, un tirant ou une tige entretoise

    CERN Document Server

    Association Française de Normalisation. Paris

    1986-01-01

    Appareils à pression de gaz ou de vapeur en acier -Qualification d'un mode opératoire de soudage - Cas d'un assemblage destiné à fixer sur une paroi une pièce boulonnée, un tirant ou une tige entretoise

  11. Synthesis and characterization in AuCu–Si nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Novelo, T.E., E-mail: tenovelo@hotmail.com [Centro de Investigación en Materiales Avanzados, S.C., Laboratorio Nacional de Nanotecnología, Av. Miguel de Cervantes 120, Complejo Industrial Chihuahua, 31109 Chihuahua, Chihuahua Mexico (Mexico); Amézaga-Madrid, P. [Centro de Investigación en Materiales Avanzados, S.C., Laboratorio Nacional de Nanotecnología, Av. Miguel de Cervantes 120, Complejo Industrial Chihuahua, 31109 Chihuahua, Chihuahua Mexico (Mexico); Maldonado, R.D. [Universidad Anáhuac-Mayab, Carretera Mérida-Progreso Km. 15.5 A.P. 96-Cordemex, CP. 97310 Mérida, Yucatán Mexico (Mexico); Oliva, A.I. [Centro de Investigación y de Estudios Avanzados el IPN Unidad Mérida, Departamento de Física Aplicada, Km 6 Antigua Carretera a Progreso, A.P. 73-Cordemex, 97310 Mérida, Yucatán Mexico (Mexico); Alonzo-Medina, G.M. [Universidad Anáhuac-Mayab, Carretera Mérida-Progreso Km. 15.5 A.P. 96-Cordemex, CP. 97310 Mérida, Yucatán Mexico (Mexico)

    2015-03-15

    Au/Cu bilayers with different Au:Cu concentrations (25:75, 50:50 and 75:25 at.%) were deposited on Si(100) substrates by thermal evaporation. The thicknesses of all Au/Cu bilayers were 150 nm. The alloys were prepared by thermal diffusion into a vacuum oven with argon atmosphere at 690 K during 1 h. X-ray diffraction analysis revealed different phases of AuCu and CuSi alloys in the samples after annealing process. CuSi alloys were mainly obtained for 25:75 at.% samples, meanwhile the AuCuII phase dominates for samples prepared with 50:50 at.%. Additionally, the Au:Cu alloys with 75:25 at.%, produce Au{sub 2}Cu{sub 3} and Au{sub 3}Cu phases. The formed alloys were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) to study the morphology and the elemental concentration of the formed alloys. - Highlights: • AuCu/Si alloy thin films were prepared by thermal diffusion. • Alloys prepared with 50 at.% of Au produce the AuCuII phase. • Alloys prepared with 75 at.% of Au produce Au{sub 3}Cu and Au{sub 2}Cu{sub 3} phases. • All alloys present diffusion of Si and Cu through the CuSi alloy formation.

  12. Au nanoparticles films used in biological sensing

    Energy Technology Data Exchange (ETDEWEB)

    Rosales Perez, M; Delgado Macuil, R; Rojas Lopez, M; Gayou, V L [Centro de Investigacion en BiotecnologIa Aplicada del IPN, Tepetitla Tlaxcala Mexico C.P. 90700 (Mexico); Sanchez Ramirez, J F, E-mail: mrosalespe@ipn.m [CICATA Legaria Instituto Politecnico Nacional, Mexico Distrito Federal (Mexico)

    2009-05-01

    Lactobacillus para paracasei are used commonly as functional food and probiotic substances. In this work Au nanoparticles self-assembled films were used for Lactobacillus para paracasei determination at five different concentrations. Functionalized substrates were immersed in a colloidal solution for one and a half hour at room temperature and dried at room temperature during four hours. After that, drops of Lactobacillus para paracasei in aqueous solution were put into the Au nanoparticles film and let dry at room temperature for another two hours. Infrared spectroscopy in attenuated total reflectance sampling mode was used to observe generation peaks due to substrate silanization, enhancement of Si-O band intensity due to the Au colloids added to silanized substrate and also to observe the enhancement of Lactobacillus para paracasei infrared intensity of the characteristic frequencies at 1650, 1534 and 1450 cm{sup -1} due to surface enhancement infrared absorption.

  13. PHENIX Results in d + Au Collisions

    Science.gov (United States)

    Chen, Chin-Hao

    2016-04-01

    The PHENIX experiment at the Relativistic Heavy Ion Collider has performed a comprehensive set of measurements in d + Au collisions. Observables in d + Au collisions were originally conceived as a control experiment where no quark-gluon plasma is formed and one could isolate so-called cold nuclear matter effects, including nuclear modified parton distributions and parton multiple scattering. However, recent data from the PHENIX experiment in d + Au, in conjunction with new p + Pb results at the Large Hadron Collider, give strong evidence for a very different picture. We present new results that hint at the formation of a small quark-gluon plasma, that though short lived, leaves a fingerprint of evidence on final state observables. These new results will be discussed in the context of competing theoretical interpretations.

  14. A study on the isotope effects in the reduction of carbon dioxide by zinc; Etude des effets isotopiques dans la reduction du gaz carbonique par le zinc

    Energy Technology Data Exchange (ETDEWEB)

    Senegacnik, M. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1957-06-15

    We have determined the isotope effects which occur in the reduction of carbon dioxide by zinc. It has been shown that in the case of irreversible surface reactions, Bernstein's equation which permits the calculation of the fractionation factor is still valid. These experimental factors are in good agreement with those obtained by calculating the partition functions of the adsorbed activated complexes. In the reaction mechanism used, the model of the activated complex corresponds to the dissociation of one of the carbon oxygen bonds CO{sub 2} {yields} CO + O. Perturbations arising from the slight reversibility of the reaction Zn + CO{sub 2} {r_reversible} ZnO + CO on the isotope effects on the carbon and oxygen atoms have also been calculated. (author) [French] Nous avons etudie les effets isotopiques qui ont lieu dans la reduction du gaz carbonique par le zinc. La validite de l'equation de Bernstein qui permet de calculer le facteur de fractionnement a ete demontree pour le cas d'une reaction irreversible de surface. Ces facteurs de fractionnement experimentaux sont en bon accord avec ceux obtenus par le calcul des fonctions de partition isotopiques des complexes actives adsorbes. Dans le mecanisme de reaction utilise, le modele du complexe active correspond a la dissociation d'une des liaisons carbone oxygene CO{sub 2} {yields} CO + O. Les effets perturbateurs de la reversibilite de la reduction Zn + CO{sub 2} {r_reversible} ZnO + CO sur les effets isotopiques du carbone et ceux de l'oxygene ont ete egalement evalues. (auteur)

  15. Total structure determination of thiolate-protected Au38 nanoparticles.

    Science.gov (United States)

    Qian, Huifeng; Eckenhoff, William T; Zhu, Yan; Pintauer, Tomislav; Jin, Rongchao

    2010-06-23

    We report the total structure of Au(38)(SC(2)H(4)Ph)(24) nanoparticles determined by single crystal X-ray crystallography. This nanoparticle is based upon a face-fused Au(23) biicosahedral core, which is further capped by three monomeric Au(SR)(2) staples at the waist of the Au(23) rod and six dimeric staples with three on the top icosahedron and other three on the bottom icosahedron. The six Au(2)(SR)(3) staples are arranged in a staggered configuration, and the Au(38)S(24) framework has a C(3) rotation axis.

  16. Au nanorice assemble electrolytically into mesostars.

    Science.gov (United States)

    Bardhan, Rizia; Neumann, Oara; Mirin, Nikolay; Wang, Hui; Halas, Naomi J

    2009-02-24

    Star-shaped mesotructures are formed when an aqueous suspension of Au nanorice particles, which consist of prolate hematite cores and a thin Au shell, is subjected to an electric current. The nanorice particles assemble to form hyperbranched micrometer-scale mesostars. To our knowledge, this is the first reported observation of nanoparticle assembly into larger ordered structures under the influence of an electrochemical process (H(2)O electrolysis). The assembly is accompanied by significant modifications in the morphology, dimensions, chemical composition, crystallographic structure, and optical properties of the constituent nanoparticles.

  17. Greenhouse effect gases inventory in France during the years 1990-1999; Inventaire des emissions de gaz a effet de serre en France au cours de la periode 1990-1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-12-01

    The present report supplies emission data, for France and for the period 1990-1999, concerning all the substances involved in the increase in the greenhouse effect and covered under the United Nations' Framework Convention on Climate Change (UNFCCC). The substances are the six direct greenhouse gases covered by the Kyoto protocol: carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), the two species of halogenous substances - hydro-fluorocarbons (HFCs) and per-fluorocarbons (PFCs), and sulphur hexafluoride (SF{sub 6}). Emissions of sulphur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), non methane volatile organic compounds (NMVOCs), and carbon monoxide (CO), gases which indirectly make a significant contribution to the greenhouse effect, are reported under the Convention. The emissions of the six gases that directly contribute to the greenhouse effect are expressed in terms of Global Warming Potential (GWP) which decreased by 2.1 % in 1999 compared to 1990. The emissions of the four gases that indirectly contribute to the greenhouse effect are moving towards decrease: this is by 17% for NO{sub x}, 23% as regards NMVOCs, 33% for CO and by 44% regarding SO{sub 2}. Out of the six greenhouse gases covered by the Kyoto Protocol, CO{sub 2} accounts for the largest share in total GWP emissions (70 %), followed by N{sub 2}O (16 %), CH{sub 4} (12 %), HFCs (0.99 %), SF{sub 6} (0.5 %), and PFCs (0.39 %). (author)

  18. Inventory of greenhouse effect gases in France under the united nation framework convention on climatic change; Inventaire des emissions de gaz a effet de serre en France au titre de la convention cadre des nations unies sur le changement climatique

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-12-01

    The present report supplies emission data, for France and for the period 1990 - 2000 concerning all the substances involved in the increase in the greenhouse effect and covered under the United Nations' Framework Convention on Climate Change (UNFCCC). The substances are the six direct greenhouse gases covered by the Kyoto protocol: carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), the two species of halogenous substances - hydro-fluorocarbons (HFCs) and per-fluorocarbons (PFCs), and sulphur hexafluoride (SF{sub 6}). Emissions of sulphur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), non methane volatile organic compounds (NMVOCs), and carbon monoxide (CO), gases which indirectly make a significant contribution to the greenhouse effect, are reported under the Convention. For the period 1990 - 1999 as a whole, estimates provided in the previous inventories have been reviewed and corrected to take into account updated statistics, improved knowledge, possible changes in methodology and specifications contained in the guidelines (FCCC/CP/1999/7) defined by the UNFCCC on reporting for inventories of emissions, in particular the use of the Common Reporting Format (CRF). (author)

  19. Experimental study of the vaporization of a droplets injection in a fluidized gas-solid media; Etude experimentale de la vaporisation d'un jet de goutelettes au contact d'un milieu gaz-solide fluidise

    Energy Technology Data Exchange (ETDEWEB)

    Leclere, K.

    2002-09-01

    The quality of feedstock injection in the Fluid Catalytic Process (FCC) is essential to ensure a good vaporization. The vaporization should be fast so that the cracking reaction in the gaseous phase can happen within the short residence time in the riser (a few seconds). Vaporization is helped by a uniform injection of droplets as small as possible as well as a good mixing with the catalyst particles that represent the main heat source. Several models were developed to predict the droplet vaporization in a gas-solid media. However, no experimental validation exists for these models, whose predictions vary (from 1 to several hundreds of milliseconds). The objective of this study was to get a better understanding of the physical phenomena taking place during droplet vaporization. This was done in two steps. First, operating limits had to be defined to ensure an optimal vaporization and to avoid local saturation and agglomerate formation. These limits were precisely determined under laboratory conditions to validate a model that showed that agglomeration does not occur under industrial conditions. Then, a kinematic study of vaporization under operating conditions without agglomerate formation was performed. An original measurement technique was developed to get samples at very short times (tens of milliseconds). Experiments showed that heat transfer was not limiting and that mass transfer was the limiting process during vaporization. The developed model was thus based on mass transfer through a boundary layer. The validation of this model in a dense fluidized bed justified its application to operating conditions were the bed voidance is higher. A detailed study of operating parameters will help determine how to improve vaporization. (author)

  20. The hydrogen state: from the solid to the gas taking into account the liquid; L'hydrogene dans tous ses etats: du solide au gaz en passant par le liquide

    Energy Technology Data Exchange (ETDEWEB)

    Latroche, M.; Joubert, J.M.; Cuevas, F.; Paul-Boncour, V.; Percheron-Guegan, A. [Centre National de la Recherche Scientifique (CNRS), Institut de Chimie et des Materiaux Paris-Est (CMTR-ICMPE-UMR7182), 94 - Thiais (France)

    2007-07-01

    Hydrogen is considered as a future energy vector. To become a viable solution, the hydrogen storage processes must be safe, economic and adapted to the use possibilities. Today many storage modes offer interesting possibilities but need also more researches before realization of prototypes. These modes are described taking into account the physical (compression, liquefaction) and chemical (adsorption in porous solids and absorption in chemical hydrides) solutions. (A.L.B.)

  1. How competitive gas air-conditioning is being offered to domestic users by means of attractive energy selling services?; Une climatisation au gaz concurrentielle pour le marche residentiel via des services de vente d'energie attractifs

    Energy Technology Data Exchange (ETDEWEB)

    Jane, R.; Raventos, M. [Gas Natural, SDG, S.A. (Spain); Naval, J.; Martinez, J.A. [Gas Serviconfort S.A. (Spain)

    2000-07-01

    With the object of responding to the progressive increase in the demand for air-conditioning in the domestic sector with the presentation of gas as a competitive alternative to the electric systems currently available, and in order to avoid not only the loss of this specific market but also of the heating and hot water markets in the new-build residential sector, a new individualized energy selling service has been developed. This new option incorporates the advantages of the individualized and centralized systems of air-conditioning thanks to the utilisation of the medium-size gas air-conditioning systems currently available and to the geNie system as an instrument for totally individualizing the service and offering truly innovative features that will be attractive to the consumer. This new line of activity, implemented by the Serviconfort, a subsidiary company off the Gas Natural Group, has proven its viability both in technological and in service-definition terms in a series of demonstrations with more than 800 clients, which have served to indicate the considerable interest of the new-build residential sector in Spain and the expectations for the potential market over the next few years. (authors)

  2. Homogenization of some radiative heat transfer models: application to gas-cooled reactor cores; Homogeneisation de modeles de transferts thermiques et radiatifs: application au coeur des reacteurs a caloporteur gaz

    Energy Technology Data Exchange (ETDEWEB)

    El Ganaoui, K

    2006-09-15

    In the context of homogenization theory we treat some heat transfer problems involving unusual (according to the homogenization) boundary conditions. These problems are defined in a solid periodic perforated domain where two scales (macroscopic and microscopic) are to be taken into account and describe heat transfer by conduction in the solid and by radiation on the wall of each hole. Two kinds of radiation are considered: radiation in an infinite medium (non-linear problem) and radiation in cavity with grey-diffuse walls (non-linear and non-local problem). The derived homogenized models are conduction problems with an effective conductivity which depend on the considered radiation. Thus we introduce a framework (homogenization and validation) based on mathematical justification using the two-scale convergence method and numerical validation by simulations using the computer code CAST3M. This study, performed for gas cooled reactors cores, can be extended to other perforated domains involving the considered heat transfer phenomena. (author)

  3. On the Stark broadening in the Au I and Au II spectra from a helium plasma

    Science.gov (United States)

    Djeniže, S.

    2009-03-01

    The Stark FWHM (Full-Width at Half of the Maximal line intensity, W) of 5 neutral and 26 singly ionized gold (Au I and Au II, respectively) spectral lines have been measured in laboratory helium plasma at approximately 16,600 K electron temperature and 7.4 × 10 22 m - 3 electron density. Five Au I and ten Au II W values are reported for the first time. The Au II W values are compared with recent theoretical data, calculated based on a modified semi-empirical approach, and also with existing experimental W values. Our normalized Stark widths are six times higher than those measured in a laser-produced plasma. Possible explanation of this is recommended here. An agreement (within the accuracy of the experiment and uncertainties of the theoretical approach used) with the recently calculated W data was found in the 6p-7s Au II transition. The calculated hyperfine splitting for the five Au II lines in the 6s-6p transition is also presented. At the stated helium plasma conditions, Stark broadening has been found to be the dominant mechanism in the Au I and Au II line shape formation. A modified version of the linear low-pressure pulsed arc was used as a plasma source operated in helium, with gold atoms as impurities evaporated from the thin gold cylindrical plates located in the homogeneous part of the discharge, providing conditions free of self-absorption. This plasma source ensures good conditions for generation of excited gold ions due to Penning and charge exchange effects.

  4. Low energy {beta} counts at the radioactivity measurement laboratory of Grenoble; Les comptages {beta} de faibles energies effectues au L.M.R Grenoble

    Energy Technology Data Exchange (ETDEWEB)

    Duplaa, AM.; Chevalier, M.; Choudens, H. de [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1966-07-01

    Radioelements emitting {beta} low energy are very useful in biology specially in labelled compounds. The counting method with liquid scintillator is very often used. The radioactivity measurement laboratory of Grenoble uses for these measures a Tricarb-Packard. The samples to be counted are: tritiated water which is measured with a dioxane scintillator; animals textures which is measured with a dioxane scintillator; animals textures which contain {sup 14}C: these samples are dissolved in hyamine 10 X, then melted with a toluene scintillator, solid samples containing {sup 14}C or {sup 45}Ca (plant ashes); these samples are measured by suspension in scintillating mixtures. Gaseous samples {sup 14}CO{sub 2} are also counted, the gas is retained by hyamine, then mixed with a liquid scintillator. Counting of double labelled samples are also made {sup 4}5{sup C}a + {sup 32}P and {sup 14}C + {sup 32}P. The quenching corrections are made by internal standardization method, by channels ratio method or better by external standardization method. (author) [French] Les emetteurs {beta} de faible energie (C{sup 14}, H{sup 3}, Ca{sup 45}) sont tres utilises en biologie sous forme de molecules marquees. La methode de comptage par scintillateur liquide est celle qui est la plus employee. Le LMR de Grenoble effectue la mesure de ces emetteurs avec un appareil Tricarb-Packard. Les comptages portent sur des ehantillons d'eau titree comptee avec un scintillateur au dioxane; des echantillons de tissus animaux contenant du C{sup 14} sont dissous par de l'hyamine puis melange a un scintillateur au toluene. Des echantillons solides (cendres de vegetaux) contenant du C{sup 14} ou du Ca{sup 45} sont comptes sous forme de gels scintillants; des echantillons gazeux de {sup 14}CO{sub 2}, le gaz est retenu par de l'hyamine puis melange au scintillateur liquide. Enfin des comptages d'echantillons doublement marques CO{sup 45} + P{sup 32} et C{sup 14} + P{sup 32} sont effectues

  5. A novel Au SINE sequence found in a gymnosperm.

    Science.gov (United States)

    Yagi, Eiki; Akita, Toru; Kawahara, Taihachi

    2011-01-01

    Although many SINE families have been identified in the animal kingdom, only a few SINE families have been identified in plants, and their distribution is somewhat limited. The Au SINE (Au) has been found discontinuously in basal angiosperms, monocots, and eudicots. In this study, we examined the presence of the Au in gymnosperms and ferns by PCR using internal primers for Au. As a result, we found Au in a gymnosperm species, Ephedra ciliata. Therefore, Au was supposed to be present in the common ancestor of angiosperms and gymnosperms. The Au in E. ciliate was 15 bp shorter than the consensus sequence, which is similar to the Au SINE found in Glycine. However, the 3'end of the Au found in E. ciliate was more similar to the 3'end of the Medicago-type Au than that of the Glycine-type Au. A phylogenetic tree indicated that the Au sequence from E. ciliate is more closely related to the sequence found in Glycine than that found in Medicago/Lotus. These results indicated that Au were present in both angiosperms and gymnosperms.

  6. Charged hadron transverse momentum distributions in Au+Au collisions at {radical}S{sub NN} = 200 GeV

    Energy Technology Data Exchange (ETDEWEB)

    Back, B.B.; Baker, M.D.; Barton, D.S.; Betts, R.R.; Ballintijn, M.; Bickley, A.A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M.P.; Garcia, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Heintzelman, G.A.; Henderson, C.; Hofman, D.J.; Hollis, R.S.; Holynski, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J.L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C.M.; Lin, W.T.; Manly, S.; McLeod, D.; Michalowski, J.; Mignerey, A.C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I.C.; Pernegger, H.; Reed, C.; Remsberg, L.P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S.G.; Steinberg, P.; Stephans, G.S.F.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; Nieuwenhuizen, G.J. van; Verdier, R.; Wadsworth, B.; Wolfs, F.L.H.; Wosiek, B.; Wozniak, K.; Wuosmaa, A.H.; Wyslouch, B

    2003-04-01

    We present transverse momentum distributions of charged hadrons produced in Au+Au collisions at {radical}S{sub NN} = 200 GeV. The evolution of the spectra for transverse momenta p{sub T} from 0.25 to 5 GeV/C is studied as a function of collision centrality. We find a significant change of the spectral shape between proton-antiproton and peripheral Au+Au collisions. When comparing peripheral to central Au+Au collisions, we find that the yields at the highest p{sub T} exhibit approximate scaling with the number of participating nucleons, rather than scaling with the number of binary collisions.

  7. La cardiomyopathie dilatee au centre hospitalier Universitaire ...

    African Journals Online (AJOL)

    La cardiomyopathie dilatee au centre hospitalier Universitaire Tokoin de Lome : A propos de 74 cas hospitalises. ... Le traitement médical a fait appel aux diurétiques (85,1%), aux inhibiteurs de l'enzyme de conversion de l'angiotensine (83,8%) et aux digitaliques (55,4%). Des antiarythmiques, des antiaggrégants ...

  8. Nanoporous Au: an unsupported pure gold catalyst?

    Energy Technology Data Exchange (ETDEWEB)

    Wittstock, A; Neumann, B; Schaefer, A; Dumbuya, K; Kuebel, C; Biener, M; Zielasek, V; Steinrueck, H; Gottfried, M; Biener, J; Hamza, A; B?umer, M

    2008-09-04

    The unique properties of gold especially in low temperature CO oxidation have been ascribed to a combination of various effects. In particular, particle sizes below a few nm and specific particle-support interactions have been shown to play important roles. On the contrary, recent reports revealed that monolithic nanoporous gold (npAu) prepared by leaching a less noble metal, such as Ag, out of the corresponding alloy can also exhibit remarkably high catalytic activity for CO oxidation, even though no support is present. Therefore, it was claimed to be a pure and unsupported gold catalyst. We investigated npAu with respect to its morphology, surface composition and catalytic properties. In particular, we studied the reaction kinetics for low temperature CO oxidation in detail taking mass transport limitation due to the porous structure of the material into account. Our results reveal that Ag, even if removed almost completely from the bulk, segregates to the surface resulting in surface concentrations of up to 10 at%. Our data suggest that this Ag plays a significant role in activation of molecular oxygen. Therefore, npAu should be considered as a bimetallic catalyst rather than a pure Au catalyst.

  9. Anomalies hematologiques au cours des accidents vasculaires ...

    African Journals Online (AJOL)

    Anomalies hematologiques au cours des accidents vasculaires cerebraux a Abidjan des (Cote d'Ivoire) ... Introduction: En Côte d'Ivoire, les accidents vasculaires cérébraux (AVC) sont de plus en ... The objective of the study was to report the hematological abnormalities in the stroke among black African patients in Abidjan.

  10. Didaktik des außerschulischen Lernens

    CERN Document Server

    Sauerborn, Petra

    2012-01-01

    Kernprobleme schulischer Bildung sind die zunehmenden Verluste an Realitäts- und Praxisbezug sowie die einseitige Betonung der fachwissenschaftlichen Kenntnisse. In jüngster Zeit werden insbesondere moderne didaktisch-methodische Konzepte näher diskutiert und praktiziert. So finden sich etwa die Stichwörter Handlungsorientierter Unterricht und Offener Unterricht in der fachdidaktischen Diskussion wieder. Eine wesentlich aktuellere Form stellt das außerschulische Lernen dar. Ein modernes pädagogisches Verständnis sieht den Unterricht heute nicht mehr als ausschließliche Tätigkeit des Lehrers an, sondern als Aktivität der Lernenden. Außerschulisches Lernen beschreibt die originale Begegnung im Unterricht außerhalb des Klassenzimmers. An außerschulischen Lernorten findet eine unmittelbare AuseinanderSetzung des Lernenden mit seiner räumlichen Umgebung statt. Charakteristisch sind hierbei vor allem die aktive(Mit-)Gestaltung sowie die eigenständige Wahrnehmung mehrperspektivischer Bildungsinhalte d...

  11. Melamine structures on the Au(111) surface

    NARCIS (Netherlands)

    Silly, Fabien; Shaw, Adam Q.; Castell, Martin R.; Briggs, G. A. D.; Mura, Manuela; Martsinovich, Natalia; Kantorovich, Lev

    2008-01-01

    We report on a joint experimental and theoretical study of the ordered structures of melamine molecules formed on the Au(111)-(22 x root 3) surface. Scanning tunneling microscopy (STM) images taken under UHV conditions reveal two distinct monolayers one of which has never been reported before on

  12. Surface structure of AU3Cu(001)

    DEFF Research Database (Denmark)

    Eckstein, G.A.; Maupai, S.; Dakkouri, A.S.

    1999-01-01

    The surface morphology, composition, and structure of Au3Cu(001) as determined by scanning tunneling microscopy and surface x-ray diffraction are presented. Atomic resolution STM images reveal distinctive geometric features. The analysis of the surface x-ray diffraction data provides clear evidence...... for the surface structure. [S0163-1829(99)04535-X]....

  13. Le CRDI au Pérou

    International Development Research Centre (IDRC) Digital Library (Canada)

    Arequipa. Trujillo. Chiclayo. Piura. Cuzco. Pucallpa. Iquitos. 914. ○ Tumbes. Quelques activités en cours. Voici quelques exemples des travaux de recherche appuyés par le CRDI au Pérou. □ Amélioration des pratiques agricoles pour lutter contre le paludisme. Financement : 500 400 CAD. Période visée : de 2012 à 2016.

  14. Characterization of Au and Bimetallic PtAu Nanoparticles on PDDA-Graphene Sheets as Electrocatalysts for Formic Acid Oxidation

    Science.gov (United States)

    Yung, Tung-Yuan; Liu, Ting-Yu; Huang, Li-Ying; Wang, Kuan-Syun; Tzou, Huei-Ming; Chen, Po-Tuan; Chao, Chi-Yang; Liu, Ling-Kang

    2015-09-01

    Nanocomposite materials of the Au nanoparticles (Au/PDDA-G) and the bimetallic PtAu nanoparticles on poly-(diallyldimethylammonium chloride) (PDDA)-modified graphene sheets (PtAu/PDDA-G) were prepared with hydrothermal method at 90 °C for 24 h. The composite materials Au/PDDA-G and PtAu/PDDA-G were evaluated by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA) for exploring the structural characterization for the electrochemical catalysis. According to TEM results, the diameter of Au and bimetallic PtAu nanoparticles is about 20-50 and 5-10 nm, respectively. X-ray diffraction (XRD) results indicate that both of PtAu and Au nanoparticles exhibit the crystalline plane of (111), (200), (210), and (311). Furthermore, XRD data also show the 2°-3° difference between pristine graphene sheets and the PDDA-modified graphene sheets. For the catalytic activity tests of Au/PDDA-G and PtAu/PDDA-G, the mixture of 0.5 M aqueous H2SO4 and 0.5 M aqueous formic acid was used as model to evaluate the electrochemical characterizations. The catalytic activities of the novel bimetallic PtAu/graphene electrocatalyst would be anticipated to be superior to the previous electrocatalyst of the cubic Pt/graphene.

  15. Mesure et modélisation multidimensionnelle des transferts thermiques gaz-paroi dans le cas des moteurs à allumage commandé Measurement and Multidimensional Modeling of Gas-Wall Heat Transfers in Spark-Ignition Engines

    Directory of Open Access Journals (Sweden)

    Gilaber P.

    2006-11-01

    Full Text Available A cette fin, deux étapes de recherche ont été mises en oeuvre : une phase expérimentale et une phase calcul. Dans la phase expérimentale, des mesures ont été faites sur un moteur monocylindre équipé de flux-mètres à réponse rapide. Chaque flux-mètre est composé d'un cylindre d'acier, contenant deux thermocouples. Dans le but de montrer l'influence de l'aérodynamique sur les échanges thermiques, un anémomètre à Laser a été utilisé à l'aide d'une entretoise placée entre culasse et cylindre. L'entretoise comportait deux hublots et deux flux-mètres permettant la mesure simultanée des flux thermiques et des paramètres aérodynamiques à l'extérieur de la couche limite. Deux flux-mètres supplémentaires ont été placés dans la culasse et le système d'acquisition permettait d'enregistrer simultanément dix voies de mesure à chaque degré vilebrequin, parmi lesquelles deux composantes de vitesse et la pression cylindre. Une étude paramétrique a révélé les tendances suivantes : - les pertes globales aux parois au cours d'un cycle thermodynamique diminuent lorsque le régime augmente, mais la valeur maximale des flux locaux augmente en raison de l'élévation du niveau de turbulence; - le remplissage a peu d'effet sur l'aérodynamique; son influence sur les transferts thermiques est due principalement à l'augmentation de la densité des gaz, qui se traduit par une augmentation des flux. Dans la phase calcul, deux idées de base ont guidé notre travail : - pour des raisons de temps de calcul prohibitif, il est impossible de mailler la couche limite; les échanges thermiques ont donc été estimés à l'aide d'une loi de paroi; - on fait l'hypothèse que les champs locaux de densité, vitesse et turbulence conditionnent fortement les flux thermiques; ce seront les paramètres de la loi de paroi. Dans cet esprit, le modèle de transferts thermiques de DIWAKAR a été introduit dans le code multi-dimensionnel KIVA. Une

  16. Le problème des hydrates dans le contexte de la production et du transport polyphasiques des pétroles bruts et des gaz naturels. Deuxième partie : les solutions possibles aux difficultés d'exploitation générées par les hydrates Hydrates Problem Within the Framework of Multiphase Production and Transport of Crude Oils and Natural Gases. Part Two: Possible Solutions to Exploitation Difficulties Generated by Hydrates

    Directory of Open Access Journals (Sweden)

    Behar E.

    2006-11-01

    Full Text Available L'exploitation en mer des gisements de combustibles fossiles fluides a amplifié le besoin d'accroître nos connaissances sur les hydrates qui sont susceptibles de boucher les installations de production, de traitement et de transport. La première partie rappelait la structure moléculaire des hydrates I, Il et H et décrivait ensuite succinctement l'analyse physico-chimique de leur formation, tant sur les plans thermodynamique que cinétique. Dans cette deuxième partie, les remèdes possibles aux problèmes rencontrés par les compagnies opératrices sont indiqués, essentiellement les inhibiteurs thermodynamiques classiques tels que les alcools ou les sels qui diminuent la température de formation des hydrates, et les additifs dispersants qui évitent la croissance et/ou l'agglomération des cristaux. Pour terminer, une boucle pilote de circulation originale est présentée, ses caractéristiques qui permettent la validation des additifs dispersants dans des conditions hydrodynamiques et physico-chimiques représentatives étant soulignées. Offshore exploitation of fossil fluid fuels has emphasized the need of improving our knowledge on hydrates which can plug production, treatment and transport facilities. The first part recalled the molecular structure of I, II and H hydrates, then the physical-chemistry of their formation was briefly reviewed from both the thermodynamic and the kinetic points of view. In this second part, the possible remedies to the problems met by operating companies are described, mainly classical thermodynamic inhibitors such as alcohols or salts which decrease the hydrates formation temperature, and dispersant additives which avoid crystals growth and/or agglomeration. At last an original circulation loop at pilot scale is presented, its characteristics which allow the testing of dispersant additives under representative hydrodynamic and physico-chemical conditions being outlined.

  17. Le problème des hydrates dans le contexte de la production et du transport polyphasiques des pétroles bruts et des gaz naturels. Première partie : physico-chimie de la formation et de la dissociation des hydrates Hydrates Problem Within the Framework of Multiphase Production and Transport of Crude Oils and Natural Gases. Part One: Physical-Chemistry of Hydrates Formation and Dissociation

    Directory of Open Access Journals (Sweden)

    Behar E.

    2006-11-01

    Full Text Available L'exploitation en mer des gisements de combustibles fossiles fluides a amplifié le besoin d'accroître nos connaissances sur les hydrates qui sont susceptibles de boucher les installations de production, de traitement et de transport. Dans cette publication, la structure moléculaire des hydrates I, II et H est rappelée, ensuite l'analyse physico-chimique de leur formation est succinctement décrite tant sur les plans thermodynamique que cinétique. Enfin, les remèdes possibles aux problèmes rencontrés par les compagnies opératrices sont indiqués, essentiellement les inhibiteurs thermodynamiques classiques tels que les alcools ou les sels qui diminuent la température de formation des hydrates, et les additifs dispersants qui évitent la croissance et/ou l'agglomération des cristaux. Pour terminer, une boucle pilote de circulation originale est présentée, ses caractéristiques qui permettent la validation des additifs dispersants dans des conditions hydrodynamiques et physico-chimiques représentatives étant soulignées. Offshore exploitation of fossil fluid fuels has emphasized the need of improving our knowledge on hydrates which can plug production, treatment and transport facilities. In this paper, the molecular structure of I, II and H hydrates is recalled, then the physical-chemistry of their formation is briefly reviewed from both the thermodynamic and the kinetic points of view. Finally, the possible remedies to the problems met by operating companies are described, mainly classical thermodynamic inhibitors such as alcohols or salts which decrease the hydrates formation temperature, and dispersant additives which avoid crystals growth and/or agglomeration. At last an original circulation loop at pilot scale is presented, its characteristics which allow the testing of dispersant additives under representative hydrodynamic and physico-chemical conditions being outlined.

  18. Des institutions au service de villes sûres et inclusives au Venezuela

    International Development Research Centre (IDRC) Digital Library (Canada)

    Caracas, au Venezuela, est l'une des villes les plus violentes au monde; il s'y commet 122 homicides par tranche de 100 000 habitants. Selon les experts en violence urbaine, les inégalités sociales et la disparité des revenus sont étroitement liées à l'ampleur de la violence, mais cette théorie ne tient pas dans le cas ...

  19. Prévention de la violence chez les jeunes au Guatemala, au ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    La violence chez les jeunes, que ceux-ci en soient victimes ou responsables, est l'un des problèmes les plus importants en Amérique centrale. Ce projet de recherche servira à évaluer les stratégies actuelles de prévention de la violence chez les jeunes dans le triangle nord de la région, soit au Salvador, au Guatemala et ...

  20. Directed Flow of Light Nuclei in Au+Au Collisions at AGS Energies

    OpenAIRE

    E877 Collaboration; Barrette, J.; Bellwied, R.; Bennett, S.; Bersch, R.; Braun-Munzinger, P.; Chang, W. C.; Cleland, W. E.; Clemen, M.; Cole, J.; Cormier, T. M.; Dai, Y.; David, G.; Dee, J.; Dietzsch, O.

    1998-01-01

    Directed flow of deuterons, tritons, $^3$He, and $^4$He is studied in Au+Au collisions at a beam momentum of about 10.8 $A$ GeV/c. Flow of all particles is analyzed as a function of transverse momentum for different centralities of the collision. The directed flow signal, $v_1(p_t)$, is found to increase with particle mass. This mass dependence is strongest in the projectile rapidity region.

  1. A first look at Au·Au collisions at RHIC energies using the PHOBOS ...

    Indian Academy of Sciences (India)

    A first look at Au·Au collisions at RHIC energies using the PHOBOS detector. BIRGER BACK1, for the PHOBOS Collaboration. M D Baker2, D S Barton2, R R Betts6, R Bindel7, A Budzanowski3, W Busza4,. A Carroll2, J Corbo2, M P Decowski4, E Garcia6, N George1, K Gulbrandsen4, S Gushue2,. C Halliwell6, J Hamblen8, ...

  2. Flow and bose-einstein correlations in Au-Au collisions at RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Manly, Steven; Back, B.B.; Baker, M.D.; Barton, D.S.; Betts, R.R.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M.P.; Garcia, E.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Henderson, C.; Hofman, D.; Hollis, R.S.; Holyinski, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C.M.; Lin, W.T.; Manly, S.; McLeod, D.; Michalowski, J.; Mignerey, A.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I.C.; Pernegger, H.; Reed, C.; Remsberg, L.P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Skulski, W.; Steadman, S.G.; Steinberg, P.; Stephans, G.S.F.; Stodulski, M.; Sukhanov, A.; Tang, J.-L.; Teng, R.; Trzupek, A.; Vale, C.; Nieuwenhuizen, G.J. van; Verdier, R.; Wadsworth, B.; Wolfs, F.L.H.; Wosiek, B.; Wozniak, K.; Wuosmaa, A.H.; Wyslouch, B

    2003-03-10

    Argonne flow and Bose-Einstein correlations have been measured in Au-Au collisions at {radical}S{sub NN} = 130 and 200 GeV using the PHOBOS detector at RHIC. The systematic dependencies of the flow signal on the transverse momentum, pseudorapidity, and centrality of the collision, as well as the beam energy are shown. In addition, results of a 3-dimensional analysis of two-pion correlations in the 200 GeV data are presented.

  3. Femmes, migration et droits au Mali et au Sénégal | CRDI - Centre ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    En Afrique de l'Ouest, notamment au Mali et au Sénégal, les migrations féminines concernent majoritairement les flux d'une part à l'intérieur des pays et d'autre part entre les pays. Du fait de la pauvreté, manque d'opportunités économiques et manque d'éducation, les jeunes filles migrantes risquent de subir des violations ...

  4. A reagentless amperometric immunosensor based on nano-au and ...

    African Journals Online (AJOL)

    In this paper, carboxyl-ferrocene (Fc-COOH) was explored to label alphafetoprotein antibody (anti-AFP), which was then mixed with AU nanoparticles (nano-Au) and multi-walled carbon nanotubes (MWCNTs) dispersed by chitosan (CS) to form the nano-Au/MWCNTs/anti-AFP-Fc chitosan composite. After that, the composite ...

  5. Au pair på ulige vilkår

    DEFF Research Database (Denmark)

    Christiansen, Connie Carøe

    2008-01-01

    Antallet af au pairs i Danmark fra Fillipinerne er steget markant i de seneste år. Mens danske myndigheder betragter au pair-ordningen som kulturudveksling blandt unge mennesker, ser fillipinske au pairs derimod den som en mulighed for at tjene penge så de kan forsørge deres egen familie i Fillip...

  6. The point-defect of carbon nanotubes anchoring Au nanoparticles

    DEFF Research Database (Denmark)

    Lv, Y. A.; Cui, Y. H.; Li, X. N.

    2010-01-01

    between Au clusters and CNTs by means of density functional theory calculations. Both experimental and theoretical studies show that point defects are the anchoring sites of Au nanoparticles. The mechanisms of enhanced bond between Au and CNTs via the point defects are explained by the analysis of density...

  7. Common suppression pattern of η and π0 mesons at high transverse momentum in Au+Au collisions at VsNN=200 GeV

    NARCIS (Netherlands)

    Peitzmann, T.

    2006-01-01

    Inclusive transverse momentum spectra of η mesons have been measured within pT=2–10 GeV/c at midrapidity by the PHENIX experiment in Au+Au collisions at VsNN=200 GeV. In central Au+Au the η yields are significantly suppressed compared to peripheral Au+Au, d+Au, and p+p yields scaled by the

  8. Electronic and geometric structures of Au30 clusters: a network of 2e-superatom Au cores protected by tridentate protecting motifs with u3-S.

    Science.gov (United States)

    Tian, Zhimei; Cheng, Longjiu

    2016-01-14

    Density functional theory calculations have been performed to study the experimentally synthesized Au30S(SR)18 and two related Au30(SR)18 and Au30S2(SR)18 clusters. The patterns of thiolate ligands on the gold cores for the three thiolate-protected Au30 nanoclusters are on the basis of the "divide and protect" concept. A novel extended protecting motif with u3-S, S(Au2(SR)2)2AuSR, is discovered, which is termed the tridentate protecting motif. The Au cores of Au30S(SR)18, Au30(SR)18 and Au30S2(SR)18 clusters are Au17, Au20 and Au14, respectively. The superatom-network (SAN) model and the superatom complex (SAC) model are used to explain the chemical bonding patterns, which are verified by chemical bonding analysis based on the adaptive natural density partitioning (AdNDP) method and aromatic analysis on the basis of the nucleus-independent chemical shift (NICS) method. The Au17 core of the Au30S(SR)18 cluster can be viewed as a SAN of one Au6 superatom and four Au4 superatoms. The shape of the Au6 core is identical to that revealed in the recently synthesized Au18(SR)14 cluster. The Au20 core of the Au30(SR)18 cluster can be viewed as a SAN of two Au6 superatoms and four Au4 superatoms. The Au14 core of Au30S2(SR)18 can be regarded as a SAN of two pairs of two vertex-sharing Au4 superatoms. Meanwhile, the Au14 core is an 8e-superatom with 1S(2)1P(6) configuration. Our work may aid understanding and give new insights into the chemical synthesis of thiolate-protected Au clusters.

  9. The effect of Au amount on size uniformity of self-assembled Au nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Chen, S-H; Wang, D-C; Chen, G-Y; Chen, K-Y [Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology, Taiwan (China)

    2008-03-15

    The self-assembled fabrication of nanostructure, a dreaming approach in the area of fabrication engineering, is the ultimate goal of this research. A finding was proved through previous research that the size of the self-assembled gold nanoparticles could be controlled with the mole ratio between AuCl{sub 4}{sup -} and thiol. In this study, the moles of Au were fixed, only the moles of thiol were adjusted. Five different mole ratios of Au/S with their effect on size uniformity were investigated. The mole ratios were 1:1/16, 1:1/8, 1:1, 1:8, 1:16, respectively. The size distributions of the gold nanoparticles were analyzed by Mac-View analysis software. HR-TEM was used to derive images of self-assembled gold nanoparticles. The result reached was also the higher the mole ratio between AuCl{sub 4}{sup -} and thiol the bigger the self-assembled gold nanoparticles. Under the condition of moles of Au fixed, the most homogeneous nanoparticles in size distribution derived with the mole ratio of 1:1/8 between AuCl{sub 4}{sup -} and thiol. The obtained nanoparticles could be used, for example, in uniform surface nanofabrication, leading to the fabrication of ordered array of quantum dots.

  10. Effects of Excimer Irradiation Treatment on Thermocompression Au-Au Bonding

    Science.gov (United States)

    Naoko Unami,; Katsuyuki Sakuma,; Jun Mizuno,; Shuichi Shoji,

    2010-06-01

    We studied the feasibility of using vacuum ultraviolet (VUV) treatment as a surface improvement technique with Au-Au flip-chip bonding. For fine-pitch electrical interconnections in three-dimensional (3D) stack applications, robust and reliable bonding is desirable; in this case, surface modification treatment is needed before the bonding process. A VUV surface treatment was used to remove organic contaminants. Samples of electroplated Au pads were examined by X-ray photoelectron spectroscopy (XPS) to evaluate the chemical composition of the Au surfaces. The XPS results revealed that the carbon-based contaminants on the surface were removed by the VUV treatment. The shear strength of the bonded sample was also improved. The average shear strength of a bump with VUV treatment is 1.6 times larger than that of a bump without VUV treatment. Cross-sectional scanning electron microscopy (SEM) images of the bonded samples confirmed the absence of voids and cracks. The results show that VUV treatment has clear effects on Au-Au flip-chip bonding.

  11. Results from the PHOBOS Experiment on Au+Au Collisions at RHIC

    CERN Document Server

    Wozniak, K; Baker, M D; Barton, D S; Basilev, S N; Baum, R; Betts, R R; Bialas, A; Bindel, R; Bogucki, W; Budzanowski, A; Busza, W; Carroll, A; Ceglia, M; Chang, Y H; Chen, A E; Coghen, T; Conner, C L; Czyz, W; Dabrowski, B; Decowski, M P; Despet, M; Fita, P; Fitch, J; Friedl, M; Galuszka, K; Ganz, R E; García-Solis, E; George, N; Godlewski, J; Gomes, C; Griesmayer, E; Gulbrandsen, K H; Gushue, S; Halik, J; Halliwell, C; Haridas, P; Hayes, A; Heintzelman, G A; Henderson, C; Hollis, R; Holynski, R; Holzman, B; Johnson, E; Kane, J; Katzy, J M; Kita, W; Kotula, J; Kraner, H W; Kucewicz, W; Kulinich, P A; Law, C; Lemler, M A; Ligocki, T J; Lin, W T; Manly, S L; McLeod, D; Michalowski, J; Mignerey, A C; Mülmenstädt, J; Neal, M; Nouicer, R; Olszewski, A; Pak, R; Park, I C; Patel, M; Pernegger, H; Plesko, M; Reed, C; Remsberg, L P; Reuter, M; Roland, C; Roland, G; Ross, D; Rosenberg, L J; Ryan, J; Sanzgiri, A; Sarin, P; Sawicki, P; Scaduto, J; Shea, J; Sinacore, J; Skulski, W; Steadman, S G; Stephans, G S F; Steinberg, P; Straczek, A; Stodulski, M; Strek, M; Stopa, Z; Sukhanov, A; Surowiecka, K; Tang, J L; Teng, R; Trzupek, A; Vale, C J; van Nieuwenhuizen, G J; Verdier, R; Wadsworth, B; Wolfs, F L H; Wosiek, B; Wozniak, K; Wuosmaa, A H; Wyslouch, B; Zalewski, Kasper

    2001-01-01

    PHOBOS is one of four experiments studying the Au-Au interactions at RHIC. The data collected during the first few weeks after the RHIC start-up, using the initial configuration of the PHOBOS detector, were sufficient to obtain the first physics results for the most central collisions of Au nuclei at the center of mass energy of 56 and 130 AGeV. The pseudorapidity density of charged particles near midrapidity is shown and compared with data at lower energies and from $pp$ and $p\\bar{p}$ collisions. The progress of the analysis of the data is also presented.PHOBOS is one of four experiments studying the Au-Au interactions at RHIC. The data collected during the first few weeks after the RHIC start-up, using the initial configuration of the PHOBOS detector, were sufficient to obtain the first physics results for the most central collisions of Au nuclei at the center of mass energy of 56 and 130 AGeV. The pseudorapidity density of charged particles near midrapidity is shown and compared with data at lower energie...

  12. Au(I/Au(III-catalyzed Sonogashira-type reactions of functionalized terminal alkynes with arylboronic acids under mild conditions

    Directory of Open Access Journals (Sweden)

    Deyun Qian

    2011-06-01

    Full Text Available A straightforward, efficient, and reliable redox catalyst system for the Au(I/Au(III-catalyzed Sonogashira cross-coupling reaction of functionalized terminal alkynes with arylboronic acids under mild conditions has been developed.

  13. From the Ternary Eu(Au/In)2 and EuAu4(Au/In)2 with Remarkable Au/In Distributions to a New Structure Type: The Gold-Rich Eu5Au16(Au/In)6 Structure.

    Science.gov (United States)

    Steinberg, Simon; Card, Nathan; Mudring, Anja-Verena

    2015-09-08

    The ternary Eu(Au/In)2 (EuAu(0.46)In(1.54(2))) (I), EuAu4(Au/In)2 (EuAu(4+x)In(2-x) with x = 0.75(2) (II), 0.93(2), and 1.03(2)), and Eu5Au16(Au/In)6 (Eu5Au(17.29)In(4.71(3))) (III) have been synthesized, and their structures were characterized by single-crystal X-ray diffraction. I and II crystallize with the CeCu2-type (Pearson Symbol oI12; Imma; Z = 4; a = 4.9018(4) Å; b = 7.8237(5) Å; c = 8.4457(5) Å) and the YbAl4Mo2-type (tI14; I4/mmm; Z = 2; a = 7.1612(7) Å; c = 5.5268(7) Å) and exhibit significant Au/In disorder. I is composed of an Au/In-mixed diamond-related host lattice encapsulating Eu atoms, while the structure of II features ribbons of distorted, squared Au8 prisms enclosing Eu, Au, and In atoms. Combination of these structural motifs leads to a new structure type as observed for Eu5Au16(Au/In)6 (Eu5Au(17.29)In(4.71(3))) (oS108; Cmcm; Z = 4; a = 7.2283(4) Å; b = 9.0499(6) Å; c = 34.619(2) Å), which formally represents a one-dimensional intergrowth of the series EuAu2-"EuAu4In2". The site preferences of the disordered Au/In positions in II were investigated for different hypothetical "EuAu4(Au/In)2" models using the projector-augmented wave method and indicate that these structures attempt to optimize the frequencies of the heteroatomic Au-In contacts. A chemical bonding analysis on two "EuAu5In" and "EuAu4In2" models employed the TB-LMTO-ASA method and reveals that the subtle interplay between the local atomic environments and the bond energies determines the structural and site preferences for these systems.

  14. Contribution to the study and to the development of continuous infrared absorption analyzers; Contribution a l'etude et a la mise au point des analyseurs en continu par absorption infrarouge

    Energy Technology Data Exchange (ETDEWEB)

    Coste, A. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-12-01

    The continuous infra-red absorption determination of corrosive gases implies the construction of an original single-beam spectrometer. The use of a vibration-rotation line means that the apparatus function has to undergo an alternating displacement: for one position this function is centered on the line, for other position it is placed close by, but away from any absorption. A non-linear relationship is derived between the concentration of the impurity under consideration, the optical density measured at the centre of the line and the total pressure of the gas mixture. The problem is then solved using an associated specific analog computer. The system is applicable to the determination of low concentrations. The principle proposed in then adapted to an analysis using a non-resolved vibration-rotation band. (authors) [French] Le dosage en continu par absorption infrarouge des gaz corrosifs, implique la construction d'un spectrometre original en simple faisceau. L'utilisation d'une raie de vibration - rotation, conduit a effectuer un deplacement alternatif de la fonction d'appareil: pour une position, celle-ci est centree sur la raie, pour l'autre position elle est placee a proximite mais en dehors de toute absorption. On etablit une relation non lineaire entre la concentration de l'impurete consideree, la densite optique mesuree au centre de la raie et la pression totale du melange gazeux. Le probleme est alors resolu par un calculateur analogique specifique associe. Le systeme s'applique au dosage des faibles concentrations. Le principe propose est ensuite adapte a l'analyse a partir d'une bande de vibration - rotation non resolue. (auteurs)

  15. In-situ STM study of phosphate adsorption on Cu(111), Au(111) and Cu/Au(111) electrodes

    DEFF Research Database (Denmark)

    Schlaup, Christian; Horch, Sebastian

    2013-01-01

    The interaction of Cu(111), Au(111) and Cu-covered Au(111) electrodes with a neutral phosphate buffer solution has been studied by means of cyclic voltammetry (CV) and in situ electrochemical scanning tunneling microscopy (EC-STM). Under low potential conditions, both the Cu(111) and the Au(111) ...

  16. Tuning the kondo effect in thin Au films by depositing a thin layer of Au on molecular spin-dopants

    NARCIS (Netherlands)

    Ataç, Derya; Gang, T.; Yilmaz, M.D.; Bose, Saurabh; Lenferink, Aufrid T.M.; Otto, Cornelis; de Jong, Machiel Pieter; Huskens, Jurriaan; van der Wiel, Wilfred Gerard

    2013-01-01

    We report on the tuning of the Kondo effect in thin Au films containing a monolayer of cobalt(II) terpyridine complexes by altering the ligand structure around the Co2+ ions by depositing a thin Au capping layer on top of the monolayer on Au by magnetron sputtering (more energetic) and e-beam

  17. Probing the quenching of CdSe/ZnS qdots by Au, Au/Ag, and Au/Pd nanoparticles.

    Science.gov (United States)

    Han, Hyunjoo; Valle, Valerie; Maye, Mathew M

    2012-11-02

    The resonance energy transfer between CdSe/ZnS quantum dots (qdots) and three metallic nanoparticles (NPs) with different surface plasmon resonance (SPR) characteristics were studied. Gold, gold/silver and gold/palladium NPs were used as energy acceptors for qdots with donor emission at 570 nm. Due to the different spectral overlaps between the SPR signatures and qdot emission, varied energy transfer characteristics were observed. The energy transfer was quantified via the Stern-Volmer relationship, since in this study the energy transfer was collision based. The Au/Ag and Au/Pd NPs in particular showed high K(SV) values, while the Au NPs showed much lower energy transfer efficiency. Since the NPs used in this study were relatively large (d ~ 15-20 nm), the experimental system was also influenced by the NP extinction coefficients of ≈10(8) M(-1) cm(-1). To address this potential inner filter effect, the quenching profiles were normalized by SPR transmittance. The results are important to the field, as many of these classes of nanomaterials are being employed in energy transfer based studies, as well as in colorimetric sensing.

  18. Di-hadron correlations with identified leading hadrons in 200 GeV Au + Au and d + Au collisions at STAR

    Energy Technology Data Exchange (ETDEWEB)

    Adamczyk, L. [AGH University of Science and Technology, Cracow 30-059 (Poland); Adkins, J.K. [University of Kentucky, Lexington, KY, 40506-0055 (United States); Agakishiev, G. [Joint Institute for Nuclear Research, Dubna, 141 980 (Russian Federation); Aggarwal, M.M. [Panjab University, Chandigarh 160014 (India); Ahammed, Z. [Variable Energy Cyclotron Centre, Kolkata 700064 (India); Alekseev, I. [Alikhanov Institute for Theoretical and Experimental Physics, Moscow 117218 (Russian Federation); Aparin, A. [Joint Institute for Nuclear Research, Dubna, 141 980 (Russian Federation); Arkhipkin, D.; Aschenauer, E.C. [Brookhaven National Laboratory, Upton, NY 11973 (United States); Averichev, G.S. [Joint Institute for Nuclear Research, Dubna, 141 980 (Russian Federation); Bai, X. [University of Illinois at Chicago, Chicago, IL 60607 (United States); Bairathi, V. [National Institute of Science Education and Research, Bhubaneswar 751005 (India); Banerjee, A. [Variable Energy Cyclotron Centre, Kolkata 700064 (India); Bellwied, R. [University of Houston, Houston, TX 77204 (United States); Bhasin, A. [University of Jammu, Jammu 180001 (India); Bhati, A.K. [Panjab University, Chandigarh 160014 (India); Bhattarai, P. [University of Texas, Austin, TX 78712 (United States); Bielcik, J. [Czech Technical University in Prague, FNSPE, Prague, 115 19 (Czech Republic); Bielcikova, J. [Nuclear Physics Institute AS CR, 250 68 Řež/Prague (Czech Republic); Bland, L.C. [Brookhaven National Laboratory, Upton, NY 11973 (United States); and others

    2015-12-17

    The STAR Collaboration presents for the first time two-dimensional di-hadron correlations with identified leading hadrons in 200 GeV central Au + Au and minimum-bias d + Au collisions to explore hadronization mechanisms in the quark gluon plasma. The enhancement of the jet-like yield for leading pions in Au + Au data with respect to the d + Au reference and the absence of such an enhancement for leading non-pions (protons and kaons) are discussed within the context of a quark recombination scenario. The correlated yield at large angles, specifically in the ridge region, is found to be significantly higher for leading non-pions than pions. The consistencies of the constituent quark scaling, azimuthal harmonic model and a mini-jet modification model description of the data are tested, providing further constraints on hadronization.

  19. Di-hadron correlations with identified leading hadrons in 200 GeV Au+Au and d+Au collisions at STAR

    Directory of Open Access Journals (Sweden)

    L. Adamczyk

    2015-12-01

    Full Text Available The STAR Collaboration presents for the first time two-dimensional di-hadron correlations with identified leading hadrons in 200 GeV central Au+Au and minimum-bias d+Au collisions to explore hadronization mechanisms in the quark gluon plasma. The enhancement of the jet-like yield for leading pions in Au+Au data with respect to the d+Au reference and the absence of such an enhancement for leading non-pions (protons and kaons are discussed within the context of a quark recombination scenario. The correlated yield at large angles, specifically in the ridge region, is found to be significantly higher for leading non-pions than pions. The consistencies of the constituent quark scaling, azimuthal harmonic model and a mini-jet modification model description of the data are tested, providing further constraints on hadronization.

  20. Di-hadron correlations with identified leading hadrons in 200 GeV Au + Au and d + Au collisions at STAR

    Energy Technology Data Exchange (ETDEWEB)

    Adamczyk, L; Adkins, JK; Agakishiev, G; Aggarwal, MM; Ahammed, Z; Alekseev, I; Aparin, A; Arkhipkin, D; Aschenauer, EC; Averichev, GS; Bai, X; Bairathi, V; Banerjee, A; Bellwied, R; Bhasin, A; Bhati, AK; Bhattarai, P; Bielcik, J; Bielcikova, J; Bland, LC; Bordyuzhin, IG; Bouchet, J; Brandenburg, D; Brandin, AV; Bunzarov, I; Butterworth, J; Caines, H; Calderón de la Barca Sánchez, M; Campbell, JM; Cebra, D; Cervantes, MC; Chakaberia, I; Chaloupka, P; Chang, Z; Chattopadhyay, S; Chen, X; Chen, JH; Cheng, J; Cherney, M; Christie, W; Contin, G; Crawford, HJ; Das, S; De Silva, LC; Debbe, RR; Dedovich, TG; Deng, J; Derevschikov, AA; di Ruzza, B; Didenko, L; Dilks, C; Dong, X; Drachenberg, JL; Draper, JE; Du, CM; Dunkelberger, LE; Dunlop, JC; Efimov, LG; Engelage, J; Eppley, G; Esha, R; Evdokimov, O; Eyser, O; Fatemi, R; Fazio, S; Federic, P; Fedorisin, J; Feng, Z; Filip, P; Fisyak, Y; Flores, CE; Fulek, L; Gagliardi, CA; Garand, D; Geurts, F; Gibson, A; Girard, M; Greiner, L; Grosnick, D; Gunarathne, DS; Guo, Y; Gupta, S; Gupta, A; Guryn, W; Hamad, A; Hamed, A; Haque, R; Harris, JW; He, L; Heppelmann, S; Heppelmann, S; Hirsch, A; Hoffmann, GW; Hofman, DJ; Horvat, S; Huang, T; Huang, B; Huang, HZ; Huang, X; Huck, P

    2015-10-23

    The STAR Collaboration presents for the first time two-dimensional di-hadron correlations with identified leading hadrons in 200 GeV central Au + Au and minimum-bias d + Au collisions to explore hadronization mechanisms in the quark gluon plasma. The enhancement of the jet-like yield for leading pions in Au + Au data with respect to the d + Au reference and the absence of such an enhancement for leading non-pions (protons and kaons) are discussed within the context of a quark recombination scenario. The correlated yield at large angles, specifically in the ridge region, is found to be significantly higher for leading non-pions than pions. The consistencies of the constituent quark scaling, azimuthal harmonic model and a mini-jet modification model description of the data are tested, providing further constraints on hadronization.

  1. THE VALENCE OF AU IN AUTE2 AND AUSE STUDIED BY X-RAY-ABSORPTION SPECTROSCOPY

    NARCIS (Netherlands)

    ETTEMA, ARHF; STEGINK, TA; HAAS, C

    The gold compounds AuTe2 and AuSe contain Au atoms in two different chemical surroundings. In the literature these different coordinations have been associated with a difference in valency of the Au atoms. In this paper the occupation of the 5d shell in AuSe and AuTe2 is deduced from a study of the

  2. Thermal desorption of Au from W(001) surface

    CERN Document Server

    Blaszczyszyn, R; Godowski, P J

    2002-01-01

    Adsorption of Au on W(001) at 450 K up to multilayer structures was investigated. Temperature programmed desorption technique was used in determination of coverage dependent desorption energy (region up to one monolayer). Results were discussed in terms of competitive interactions of Au-Au and Au-W atoms. Simple procedure for prediction of faceting behavior on the interface, basing on the desorption data, was postulated. It was deduced that the Au/W(001) interface should not show faceting tendency after thermal treatment. (author)

  3. Etude expérimentale de l'écoulement gaz-liquide ascendant à deux et trois fluides en conduite verticale Experimental Study of Upward Gas-Liquid Flow of Two and Three Fluids in a Vertical Pipe

    Directory of Open Access Journals (Sweden)

    Frechou D.

    2006-11-01

    Full Text Available Cette étude a pour objet de préciser certains phénomènes essentiels des écoulements ascendants diphasiques et triphasiques rencontrés dans les puits de production pétrolière. Des expériences ont été réalisées sur une conduite verticale de 5 cm de diamètre et de 12,5 m de long. Les mesures du gradient de pression, des fractions volumiques et des célérités des poches de gaz, en écoulement intermittent d'eau, d'huile et d'air, mettent en évidence le rôle important (a de la viscosité du liquide, (b du comportement du mélange d'eau et d'huile. A partir des données expérimentales, on propose une loi de fermeture sur la célérité des poches. Elle est utilisée dans les modèles cellulaires pour améliorer la prédiction du glissement du gaz en écoulement intermittent gaz-liquide, à deux ou trois fluides. The aim of this study is to determine various essential phenomena in the two-phase and three-phase upward flows encountered in petroleum production wells. Experiments were performed on a vertical tube 5 cm in diameter and 12. 5 m long. The pressure gradient, volume fractions and velocities of gas pockets were measured with intermittent flow of water, oil and air. These measurements revealed the important role of both the liquid viscosity and the behavior of the water/oil mixture. On the basis of experimental data, a closure law is proposed for the velocity of the pockets, This law is used in cellular models to improve the forecasting of gas slippage in intermittent gas-liquid flow with two or three fluids.

  4. [Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]-: the longest intermetalloid chain compound of tin.

    Science.gov (United States)

    Binder, Mareike; Schrenk, Claudio; Block, Theresa; Pöttgen, Rainer; Schnepf, Andreas

    2017-10-12

    The reaction of the metalloid tin cluster [Sn10(Hyp)4]2- with (Ph3P)Au-SHyp (Hyp = Si(SiMe3)3) gave an intermetalloid cluster [Au3Sn18(Hyp)8]-1, which is the longest intermetalloid chain compound of tin to date. 1 shows a structural resemblance to binary AuSn phases, which is expected for intermetalloid clusters.

  5. Photoswitchable Faraday effect in EuS-Au nanosystems

    Energy Technology Data Exchange (ETDEWEB)

    Kawashima, Akira; Nakanishi, Takayuki; Kitagawa, Yuichi; Fushimi, Koji; Hasegawa, Yasuchika [Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, North-13 West-8, Kita-ku, 060-8628, Sapporo (Japan)

    2016-01-15

    Effective photoswitchable europium sulfide nanocrystals with gold nanoparticles using dithiol (DDT: 1,10-decanedithiol) joint molecules, EuS-Au nanosystems, are demonstrated. The TEM image indicates the formation of EuS-Au nanosystems composed of cube-shaped EuS nanocrystals and spherical Au nanoparticles. Under visible-light irradiation, a drastic change of absorption band of EuS-Au nanosystems at around 600 nm was observed. The Faraday effects of EuS-Au nanosystems were estimated using magnetic circular dichroism (MCD) measurements. The effective change of the MCD spectra of EuS-Au nanosystems under visible-light irradiation was successfully observed at around 670 nm for the first time. The effective reversible changes in MCD spectra with the alternative irradiation cycles of visible light (>440 nm) and dark are also presented. The decrease rate of rotation angle at 670 nm of EuS-Au nanosystems is larger than that of absorbance. These results indicate that the effective change of MCD spectra of EuS-Au nanosystems would be dominated not only by a drastic change of absorption band related to enhanced LSPR of Au nanoparticles but also by specific interaction between EuS and Au in nanosystem under irradiation. Illustration of photoswitch and TEM image of EuS-Au nanosystems. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  6. Capital and operating costs of irradiated natural uranium reprocessing plants; Couts d'investissement et d'exploitation des usines de retraitement de l'uranium naturel irradie

    Energy Technology Data Exchange (ETDEWEB)

    Thiriet, L.; Jouannaud, C.; Couture, J.; Duboz, J. [Commissariat a l' Energie Atomique (France). Centre d' Etudes Nucleaires; Oger, C. [Saint Gobain Nucleaire (France)

    1966-07-01

    This paper presents first a method of analysing natural uranium reprocessing plants investment costs (method similar to LANG and BACH well known in the fuel oil industry) and their operating costs (analysed according to their economic type). This method helps establishing standard cost structures for these plants, allowing thus comparisons between existing or planned industrial facilities. It also helps evaluating the foreseeable consequences of technical progress. Some results obtained are given, concerning: the investment costs sensitivity to the various technical parameters defining the fuel and their comparison according to the country or the economic area taken into account. Finally, the influence of the plants size on their investment costs is shown. (author) [French] La communication expose d'abord une methode d'analyse des couts d'investissement des usines de retraitement de l'uranium naturel irradie (inspiree de celles de LANG et de BACH, bien connues dans l'industrie petroliere) et de leurs couts d'exploitation (selon leur nature economique). Cette methode permet d'etablir des structures types de couts de ces usines et de comparer les realisations industrielles et les projets. Elle facilite l'exploration des consequences previsibles du progres technique. On indique un certain nombre de resultats obtenus, concernant la sensibilite des couts d'investissement de ces usines aux differents parametres techniques definissant le combustible et leur confrontation selon les pays ou aires economiques envisages. On montre enfin comment doit pouvoir s'exprimer l'influence de la taille des usines sur leur cout d'investissement. (auteur)

  7. Introduction au numéro

    Directory of Open Access Journals (Sweden)

    Diane-Gabrielle Tremblay

    2005-07-01

    Full Text Available Depuis quelques années, le thème de l’économie sociale fait couler beaucoup d’encre au Québec, comme ailleurs. Ce numéro présente un bilan de l’économie sociale au Québec, coordonné par Jean-Marc Fontan et Denis Bussières. Toutefois, afin d’avoir un portrait plus global et une perspective théorique sur la question, Interventions économiques a sollicité un texte de Jacques Defourny, afin de compléter le dossier. En effet, l’économie sociale, les secteurs non-marchands, les services de proximi...

  8. Le fonds Gabriel Tarde au CHEVS

    OpenAIRE

    Louise Salmon

    2016-01-01

    Le fonds d’archives « Gabriel Tarde » déposé au CHEVS nous permet de mieux saisir l’érudit autodidacte que fut Gabriel Tarde. De la genèse de sa pensée à ses réseaux de sociabilité, de l’homme de sciences à l’homme de lettres, ses archives témoignent à la fois des usages et des enjeux des ressources archivistiques en histoire, mais elles permettent surtout un renouvellement du regard sur Gabriel Tarde en l’inscrivant au cœur de son temps que fut la fin du XIXème siècle.At the CHEVS in Paris, ...

  9. Identification of sup 186 Au. alpha. activity

    Energy Technology Data Exchange (ETDEWEB)

    Akovali, Y.A.; Toth, K.S. (Oak Ridge National Laboratory, Oak Ridge, TN (USA)); Bingham, C.R. (University of Tennessee, Knoxville, TN (USA) Oak Ridge National Laboratory, Oak Ridge, TN (USA)); Kassim, M.B.; Zhang, M. (University of Tennessee, Knoxville, TN (USA)); Carter, H.K. (UNISOR, Oak Ridge Associated Universities, Oak Ridge, TN (USA)); Hamilton, W.D. (Joint Institute for Heavy Ion Research, Holifield Heavy Ion Research Facility, Oak Ridge, TN (USA) Vanderbilt University, Nashville, TN (USA)); Kormicki, J. (Vanderbilt University, Nashville, TN (USA))

    1990-09-01

    With the use of an on-line isotope separator, the {alpha} activity of {sup 186}Au was identified for the first time. Only one {alpha} group ({ital E}{sub {alpha}}=4653{plus minus}15 keV) was observed. This transition was found not to be in coincidence with {gamma} rays so that it probably proceeds either to the {sup 182}Ir ground state or to a low-lying level whose deexciting {gamma} rays could not be detected. The {alpha}-decay branching was determined to be (8{plus minus}2){times}10{sup {minus}4}% from which a hindrance factor of 1.9{plus minus}0.9 was deduced. The 4653-keV {alpha} transition must therefore connect the 3{sup {minus}} {sup 186}Au ground state with a {sup 182}Ir level with the same spin and configuration.

  10. Au Based Nanocomposites Towards Plasmonic Applications

    Science.gov (United States)

    Panniello, A.; Curri, M. L.; Placido, T.; Reboud, V.; Kehagias, N.; Sotomayor Torres, C. M.; Mecerreyes, D.; Agostiano, A.; Striccoli, M.

    2010-06-01

    Incorporation of nano-sized metals in polymers can transfer their unique features to the host matrix, providing nanocomposite materials with improved optical, electric, magnetic and mechanical properties. In this work, colloidal Au nanorods have been incorporated into PMMA based random co-polymer, properly functionalized with amino groups and the optical and morphological properties of the resulting nanocomposite have been investigated by spectroscopic and AFM measurements. Au nanorods have demonstrated to preserve the plasmon absorption and to retain morphological features upon the incorporation, thus making the final metal modified polymer composite exploitable for the fabrication of plasmonic devices. The prepared nanocomposites have been then patterned by Nano Imprint Lithography technique in order to demonstrate the viability of the materials towards optical applications.

  11. Near-infrared-responsive, superparamagnetic Au@Co nanochains

    Directory of Open Access Journals (Sweden)

    Varadee Vittur

    2017-08-01

    Full Text Available This manuscript describes a new type of nanomaterial, namely superparamagnetic Au@Co nanochains with optical extinctions in the near infrared (NIR. The Au@Co nanochains were synthesized via a one-pot galvanic replacement route involving a redox-transmetalation process in aqueous medium, where Au salt was reduced to form Au shells on Co seed templates, affording hollow Au@Co nanochains. The Au shells serve not only as a protective coating for the Co nanochain cores, but also to give rise to the optical properties of these unique nanostructures. Importantly, these bifunctional, magneto-optical Au@Co nanochains combine the advantages of nanophotonics (extinction at ca. 900 nm and nanomagnetism (superparamagnetism and provide a potentially useful new nanoarchitecture for biomedical or catalytic applications that can benefit from both activation by light and manipulation using an external magnetic field.

  12. Tuning the collective switching behavior of azobenzene/Au hybrid materials: flexible versus rigid azobenzene backbones and Au(111) surfaces versus curved Au nanoparticles.

    Science.gov (United States)

    Liu, Chunyan; Zheng, Dong; Hu, Weigang; Zhu, Qiang; Tian, Ziqi; Zhao, Jun; Zhu, Yan; Ma, Jing

    2017-11-09

    The combination of photo-responsive azobenzene (AB) and biocompatible Au nanomaterials possesses potential applications in diverse fields such as biosensing and thermotherapy. To explore the influence of azobenzene moieties and Au substrates on the collective switching behavior, two different azobenzene derivatives (rigid biphenyl-controlled versus flexible alkoxyl chain-linked) and three different Au substrates (a planar Au(111) surface, curved Au 102 (SR) 44 and Au 25 (SR) 18 clusters) were chosen to form six Au@AB combinations. A reactive molecular dynamics (RMD) model considering both the torsion and inversion path was implemented to simulate the collective photo-induced cis-to-trans switching process of AB monolayers on Au substrates. The major driving force for isomerization is demonstrated to be the torsion of the C-N[double bond, length as m-dash]N-C dihedral angle, in addition to the minor contribution from an inversion pathway. The isomerization process can be divided into the preliminary conformation switching stage and the later relaxation stage, in which a gradual self-organization is observed for 40 ps. The Au substrate affects the packing structure of the AB monolayer, while the choice of different kinds of ABs tunes the intermolecular interaction in the monolayer. Flexible alkoxyl-linked F-AB may achieve much faster conversion on Au clusters than on the surface. For rigid biphenyl-based R-AB anchored on Au nanoparticles (AuNPs), a competitive torsion between the biphenyl and C-N[double bond, length as m-dash]N-C dihedral may delay the C-N[double bond, length as m-dash]N-C dihedral torsion and the following isomerization process. After the R-AB molecules were anchored on the Au(111) surface, the strong π-π stacking between biphenyl units accelerates the collective isomerization process. A curvature-dependent effect is observed for R-AB SAMs on different-sized substrates. The cooperation between functional AB monolayers and the Au substrate

  13. Les entreprises au Royaume-Uni

    OpenAIRE

    Appay, Beatrice

    1987-01-01

    This chapter of the book "Formations et emplois qualifiés. Les transformations dans le Bâtiment en France et au Royaume-Uni" analyses management strategies and organisational changes during a period of continuous crisis. The concept of cascading subcontracting (sous-traitance en cascade) introduced here encapsulates a new phenomenon observed simultaneously in the ever changing organisation of work between and within the firms. This is an important result of a research based on a 34 firm monog...

  14. la lutte contre le SIDA au Cameroun

    African Journals Online (AJOL)

    Chantel

    plurielles'). Tsala Tsala, J.-Ph. (2001). Medicina tradicional y sistema de salud publica en Camerun. Siso/Saude. 35: 48 -57. UNICEF, ONUSIDA, OMS (2001). Suivi et évaluation (au niveau local) de la prévention intégrée de la transmission mère-enfant du VIH dans les pays à revenus faibles.(doc ined. Projet 03/2001). 156.

  15. Le CRDI au Népal

    International Development Research Centre (IDRC) Digital Library (Canada)

    et visant à évaluer et à faire connaître les innovations en matière de production agricole, de transformation et de mise en marché. Le CRDI collabore avec le Fonds international de développement agricole à la mise sur pied de ce réseau, dont les membres sont reliés au moyen de technologies numériques. TE. K. G. U. R.

  16. Interstellar Pickup Ion Observations to 38 au

    Science.gov (United States)

    McComas, D. J.; Zirnstein, E. J.; Bzowski, M.; Elliott, H. A.; Randol, B.; Schwadron, N. A.; Sokół, J. M.; Szalay, J. R.; Olkin, C.; Spencer, J.; Stern, A.; Weaver, H.

    2017-11-01

    We provide the first direct observations of interstellar H+ and He+ pickup ions in the solar wind from 22 to 38 au. We use the Vasyliunas and Siscoe model functional form to quantify the pickup ion distributions, and while the fit parameters generally lie outside their physically expected ranges, this form allows fits that quantify variations in the pickup H+ properties with distance. By ∼20 au, the pickup ions already provide the dominant internal pressure in the solar wind. We determine the radial trends and extrapolate them to the termination shock at ∼90 au, where the pickup H+ to core solar wind density reaches ∼0.14. The pickup H+ temperature and thermal pressure increase from 22 to 38 au, indicating additional heating of the pickup ions. This produces very large extrapolated ratios of pickup H+ to solar wind temperature and pressure, and an extrapolated ratio of the pickup ion pressure to the solar wind dynamic pressure at the termination shock of ∼0.16. Such a large ratio has profound implications for moderating the termination shock and the overall outer heliospheric interaction. We also identify suprathermal tails in the H+ spectra and complex features in the He+ spectra, likely indicating variations in the pickup ion history and processing. Finally, we discover enhancements in both H+ and He+ populations just below their cutoff energies, which may be associated with enhanced local pickup. This study serves to document the release and serves as a citable reference of these pickup ion data for broad community use and analysis.

  17. Functionalized Au@Ag-Au nanoparticles as an optical and SERS dual probe for lateral flow sensing.

    Science.gov (United States)

    Bai, Tingting; Wang, Meng; Cao, Min; Zhang, Juan; Zhang, Kangzhen; Zhou, Ping; Liu, Zhengxia; Liu, Ying; Guo, Zhirui; Lu, Xiang

    2018-02-14

    Lateral flow assay strips (LFASs) with Au nanoparticles (NPs) have been widely used as a probe for biomarkers in point-of-care testing; however, there still remain challenges in detection sensitivity and quantitative analysis. In this study, we developed a surface-enhanced Raman scattering (SERS)-based LFAS for quantitative analysis of a biomarker in the low concentration range. Moreover, apart from conventional Au NPs, three other types of citrate-capped Au-Ag bimetallic NPs: Au core with Ag shell NPs (Au@Ag NPs), rattle-like Au core in Ag-Au shell NPs (Au@Ag-Au NPs) and Ag-Au NPs were prepared and functionalized, and their solution-based SERS activities were comprehensively studied by experimental measurement and theoretical analysis. The results clearly indicated that the citrate-capped Au@Ag-Au NPs exhibited the highest SERS activity among the probes tested. Au@Ag-Au NPs were used as both optical and SERS probes in a SERS-based LFAS. In the presence of the analyte at high concentrations, a purple color appeared in the test zone. Highly sensitive and quantitative analysis was realized by measurement of SERS signals from the test lines. One of the most specific markers for cardiac injury, cardiac troponin I (cTnI), was chosen as the detection model. The detection limit of the SERS-based LFAS for cardiac troponin I was 0.09 ng/mL, lowered by nearly 50 times compared with visual results, and could be further lowered by optimization. These results demonstrated that the SERS-based LFAS using citrate-capped Au@Ag-Au NPs as probes can be a powerful tool for highly sensitive and quantitative detection of biomarkers. Graphical abstract A surface-enhanced Raman scattering (SERS)-based lateral flow assay strip using rattle-like Au core in Ag-Au shell (Au@Ag-Au) nanoparticles as probes was developed for quantitative analysis of a biomarker, with a detection limit nearly 50 times lower than that of visual assessment. C control line, T test line.

  18. A photoresponsive Au25 nanocluster protected by azobenzene derivative thiolates

    Science.gov (United States)

    Negishi, Yuichi; Kamimura, Ukyo; Ide, Mao; Hirayama, Michiyo

    2012-06-01

    An Au25 cluster protected by azobenzene derivative thiolates (S-Az) ([Au25(S-Az)18]-) was synthesized with the aim of producing a photoresponsive Au25 cluster. The matrix-assisted laser desorption/ionization mass spectrum of the product revealed that [Au25(S-Az)18]- was synthesized in high purity. Optical absorption spectra of [Au25(S-Az)18]- obtained before and after photoirradiation suggest that the azobenzenes in the ligands of Au25(S-Az)18 isomerize with an efficiency of nearly 100%, both from the trans to cis conformation and from the cis to trans conformation. Furthermore, the redox potential and optical absorption of Au25(S-Az)18 were found to change reversibly due to photoisomerization of azobenzenes.An Au25 cluster protected by azobenzene derivative thiolates (S-Az) ([Au25(S-Az)18]-) was synthesized with the aim of producing a photoresponsive Au25 cluster. The matrix-assisted laser desorption/ionization mass spectrum of the product revealed that [Au25(S-Az)18]- was synthesized in high purity. Optical absorption spectra of [Au25(S-Az)18]- obtained before and after photoirradiation suggest that the azobenzenes in the ligands of Au25(S-Az)18 isomerize with an efficiency of nearly 100%, both from the trans to cis conformation and from the cis to trans conformation. Furthermore, the redox potential and optical absorption of Au25(S-Az)18 were found to change reversibly due to photoisomerization of azobenzenes. Electronic supplementary information (ESI) available: Details of the experimental procedure and characterization of the products. See DOI: 10.1039/c2nr30830d

  19. Nonlinear EGR and VGT Control with Integral Action for Diesel Engines Régulation de Recirculation des Gaz d’Echappement (RGE et de Turbine à Géométrie Variable (TGV non linéaire avec action intégrée pour moteurs Diesel

    Directory of Open Access Journals (Sweden)

    Wahlström J.

    2011-10-01

    Full Text Available A nonlinear multivariable control design with integral action is proposed and investigated for control of Exhaust Gas Recirculation (EGR and Variable Geometry Turbine (VGT in heavy duty Diesel engines. The main control goal is to regulate oxygen/fuel ratio and intake manifold EGR-fraction, and they are specified in an outer loop. These are chosen as main performance variables since they are strongly coupled to the emissions. An existing nonlinear control design based on feedback linearization is extended with integral action. In particular, the control design method utilizes a control Lyapunov function, inverse optimal control, and a nonlinear input transformation. Comparisons between different control structures are performed in simulations showing the following four points. Firstly, integral action is necessary to handle model errors so that the controller can track the performance variables specified in the outer loop. Secondly, the proposed control design handles the nonlinear effects in the Diesel engine that results in less control errors compared to a control structure with PID controllers. Thirdly, it is important to use the input transformation and it is sufficient to use a control structure with PID controllers and input transformation to handle the nonlinear effects. Fourthly, the proposed control design is sensitive to model errors in the input transformation while a control structure with PID controllers and input transformation handles these model errors. Une conception de régulation non linéaire à variables multiples avec action intégrée est proposée et étudiée pour une régulation de la Recirculation des Gaz d’Echappement (RGE et une Turbine à Géométrie Variable (TGV au sein de moteurs Diesel à usage industriel. L’objectif principal de la régulation consiste à réguler le rapport oxygène / carburant et la fraction de RGE de tubulure d’admission, qui sont spécifiés au sein d’une boucle extérieure. Ceux

  20. Photocatalysis enhancement of Au/BFO nanoparticles using plasmon resonance of Au NPs

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yan; Cai, Zhongyang; Ma, Xueming, E-mail: xmma@phy.ecnu.edu.cn

    2015-12-15

    BiFeO{sub 3} (BFO) nanoparticles was synthesized via sol–gel technique, and successfully loaded with small sizes of gold nanoparticles (Au NPs) by impregnation-reduction method to extremely enhance the BFO photocatalytic activity. The obviously stronger optical absorption of Au/BFO observed from the UV–vis diffuse reflectance spectrum confirmed that the surface plasmon resonance (SPR) effect occured on the surface of Au NPs. And the surface plasmon-induced localized electric field could allow the formation of electron/hole pairs in the near surface region of BFO which can migrate to the surface without undergoing electron/hole (e{sup −}/h{sup +}) pair recombination. The more electrons and holes formed, the more ·OH will be generated to decompose the CR solution. When the gold loading in Au/BFO nanoparticles is 3.36 wt%, the obtained Au/BFO catalyst exhibits best photocatalytic activity evaluated by photocatalysis degradation of Congo red (CR) solution under the visible light irradiation.

  1. Virus-templated Au and Au/Pt Core/shell Nanowires and Their Electrocatalytic Activitives for Fuel Cell Applications

    Science.gov (United States)

    LEE, YOUJIN; KIM, JUNHYUNG; YUN, DONG SOO; NAM, YOON SUNG; SHAO-HORN, YANG; BELCHER, ANGELA M.

    2014-01-01

    A facile synthetic route was developed to make Au nanowires (NWs) from surfactant-mediated bio-mineralization of a genetically engineered M13 phage with specific Au binding peptides. From the selective interaction between Au binding M13 phage and Au ions in aqueous solution, Au NWs with uniform diameter were synthesized at room temperature with yields greater than 98 % without the need for size selection. The diameters of Au NWs were controlled from 10 nm to 50 nm. The Au NWs were found to be active for electrocatalytic oxidation of CO molecules for all sizes, where the activity was highly dependent on the surface facets of Au NWs. This low-temperature high yield method of preparing Au NWs was further extended to the synthesis of Au/Pt core/shell NWs with controlled coverage of Pt shell layers. Electro-catalytic studies of ethanol oxidation with different Pt loading showed enhanced activity relative to a commercial supported Pt catalyst, indicative of the dual functionality of Pt for the ethanol oxidation and Au for the anti-poisoning component of Pt. These new one-dimensional noble metal NWs with controlled compositions could facilitate the design of new alloy materials with tunable properties. PMID:24910712

  2. Au 38 (SPh) 24 : Au 38 Protected with Aromatic Thiolate Ligands

    Energy Technology Data Exchange (ETDEWEB)

    Rambukwella, Milan; Burrage, Shayna; Neubrander, Marie; Baseggio, Oscar; Aprà, Edoardo; Stener, Mauro; Fortunelli, Alessandro; Dass, Amala

    2017-03-21

    Au38(SR)24 is one of the most extensively investigated gold nanomolecules along with Au25(SR)18 and Au144(SR)60. However, so far it has only been prepared using aliphatic-like ligands, where R = –SC6H13, -SC12H25 and –SCH2CH2Ph. Au38(SCH2CH2Ph)24 when reacted with HSPh undergoes core-size conversion to Au36(SPh)24, and existing literature suggest that Au38(SPh)24 cannot be synthesized. Here, contrary to prevailing knowledge, we demonstrate that Au38(SPh)24 can be prepared if the ligand exchanged conditions are optimized, without any formation of Au36(SPh)24. Conclusive evidence is presented in the form of MALDI-MS, ESI-MS characterization, and optical spectra of Au38(SPh)24 in a solid glass form showing distinct differences from that of Au38(S-aliphatic)24. Theoretical analysis confirms experimental assignment of the optical spectrum and shows that the stability of Au38(SPh)24 is comparable to that of its aliphatic analogues, but results from different physical origins, with a significant component of ligand-ligand attractive interactions.

  3. High Pressure Behavior of Hydrocarbons. Joule-Thomson Expansion of Gas Condensates Comportement des hydrocarbures à haute pression. Détente de Joule-Thomson de gaz à condensats

    Directory of Open Access Journals (Sweden)

    Kortekaas W. G.

    2006-12-01

    Full Text Available This paper presents calculations of Joule-Thomson inversion effects in high-pressure-high-temperature gas condensates. Isenthalpic expansions were modeled for several gas condensate mixtures reported in literature using the Soave-Redlich-Kwong and the Peng-Robinson equations of state. The calculations confirmed qualitatively the heating of gas condensates at expansion. Although reservoir temperatures are in the region where cooling occurs, i. e. , inside the inversion curve, it was shown that reservoir pressures lie outside this region, and that the temperature will increase until the inversion curve is reached. The calculated temperature increases are not very large. Although exact values depend on fluid composition, reservoir conditions, and pressure drop, typical calculated temperature increases are in the range of 10-30°C for reservoir pressures of 1000 bar. A sensitivity study showed that both reservoir pressure and fluid composition greatly affect the temperature increase. With increasing pressures and increasing amounts of heavy constituents present in gas condensate mixtures, the maximum possible temperature effect will also increase. Unfortunately, due to lack of experimental information, the reliability of the calculated results could not be verified. Cet article présente des calculs de l'effet d'inversion de Joule-Thomson pour des gaz à condensats à haute température et haute pression. La détente isenthalpique a été modélisée pour plusieurs compositions de gaz à condensats trouvées dans la littérature, en utilisant les équations d'état de Soave-Redlich-Kwong et de Peng-Robinson. Ces calculs confirment qualitativement le réchauffement des gaz à condensat lors de la détente. Bien que les températures de gisement se trouvent dans la région où un refroidissement s'observe, c'est-à-dire à l'intérieur de la courbe d'inversion, on a montré que les pressions de gisement correspondent à l'extérieur de cette r

  4. Observatoire National sur les Effets du Réchauffement Climatique (ONERC) : L’adaptation de la France au changement climatique. Rapport au Premier ministre et au Parlement

    OpenAIRE

    Norrant-Romand, Caroline

    2013-01-01

    Á l’heure actuelle, le changement climatique, constaté par les experts et qui fait consensus dans la communauté scientifique, a commencé à affecter nos sociétés et les milieux naturels environnants. Ces conséquences seront de plus en plus présentes dans les décennies à venir, c’est pourquoi en plus de la lutte contre le changement climatique, les territoires doivent également s’adapter et anticiper. C’est la raison pour laquelle, en 2001, lorsqu’est promulguée la loi déclarant la lutte contre...

  5. Au99(SPh)42 nanomolecules: aromatic thiolate ligand induced conversion of Au144(SCH2CH2Ph)60.

    Science.gov (United States)

    Nimmala, Praneeth Reddy; Dass, Amala

    2014-12-10

    A new aromatic thiolate protected gold nanomolecule Au99(SPh)42 has been synthesized by reacting the highly stable Au144(SCH2CH2Ph)60 with thiophenol, HSPh. The ubiquitous Au144(SR)60 is known for its high stability even at elevated temperature and in the presence of excess thiol. This report demonstrates for the first time the reactivity of the Au144(SCH2CH2Ph)60 with thiophenol to form a different 99-Au atom species. The resulting Au99(SPh)42 compound, however, is unreactive and highly stable in the presence of excess aromatic thiol. The molecular formula of the title compound is determined by high resolution electrospray mass spectrometry (ESI-MS) and confirmed by the preparation of the 99-atom nanomolecule using two ligands, namely, Au99(SPh)42 and Au99(SPh-OMe)42. This mass spectrometry study is an unprecedented advance in nanoparticle reaction monitoring, in studying the 144-atom to 99-atom size evolution at such high m/z (∼12k) and resolution. The optical and electrochemical properties of Au99(SPh)42 are reported. Other substituents on the phenyl group, HS-Ph-X, where X = -F, -CH3, -OCH3, also show the Au144 to Au99 core size conversion, suggesting minimal electronic effects for these substituents. Control experiments were conducted by reacting Au144(SCH2CH2Ph)60 with HS-(CH2)n-Ph (where n = 1 and 2), bulky ligands like adamantanethiol and cyclohexanethiol. It was observed that conversion of Au144 to Au99 occurs only when the phenyl group is directly attached to the thiol, suggesting that the formation of a 99-atom species is largely influenced by aromaticity of the ligand and less so on the bulkiness of the ligand.

  6. Charge transport through O-deficient Au-MgO-Au junctions

    KAUST Repository

    Fadlallah, M. M.

    2009-12-29

    Metal-oxide heterostructures have been attracting considerable attention in recent years due to various technological applications. We present results of electronic structure and transport calculations for the Au-MgO-Au (metal-insulator-metal) heterostructure based on density-functional theory and the nonequilibrium Green’s functions method. The dependence of the conductance of the heterostructure on the thickness of the MgO interlayer and the interface spacing is studied. In addition, we address the effects of O vacancies. We observe deviations from an exponentially suppressed conductance with growing interlayer thickness caused by Au-O chemical bonds. Electronic states tracing back to O vacancies can increase the conductance. Furthermore, this effect can be enhanced by enlarging the interface spacing as the vacancy induced Mg states are shifted toward the Fermi energy.

  7.  Standardy rachunkowości stanowiące podstawę sporządzania sprawozdań finansowych przez jednostki wydobywające gaz łupkowy w Polsce i w Stanach Zjednoczonych

    Directory of Open Access Journals (Sweden)

    Anna Galimska

    2015-12-01

    Full Text Available Celem artykułu jest analiza oraz porównanie standardów rachunkowości wykorzystywanych przez przedsiębiorstwa poszukujące i wydobywające gaz łupkowy w Stanach Zjednoczonych i w Polsce. Autorka dokonała zestawienia regulacji służących do sporządzania i prezentacji sprawozdań finansowych, na których opierają się jednostki eksploatujące węglowodory niekonwencjonalne. Wciąż postępujący rozwój rynków kapitałowych znajduje swoje odzwierciedlenie w intensyfikacji oczekiwań interesariuszy względem atrybutów, którymi winny charakteryzować się sprawozdania finansowe. Rozważania zawarte w artykule ukazują wysoki poziom specjalizacji amerykańskich standardów rachunkowości, na których bazują podmioty wydobywające gaz łupkowy w Stanach Zjednoczonych. Natomiast standardy międzynarodowe poruszają jedynie kwestię początkowego stadium procesu wydobycia alternatywnych węglowodorów, co rzutuje na spójność przygotowywanych na ich podstawie sprawozdań finansowych. Ponadto istotna jest kwestia rozbieżności merytorycznych czy też interpretacyjnych analizowanych standardów zarówno w zakresie identyfikacji kosztów oraz ich klasyfikacji, jak i określania wysokości odpisów z tytułu utraty wartości.

  8. Karabük İlindeki Hava Kirliliğinin Doğal Gaz Kullanımı İle Değişimi

    Directory of Open Access Journals (Sweden)

    Abdülaziz YILDIZ

    2012-12-01

    Full Text Available ÖzetFosil kaynaklı yakıtların kullanımı, hava kirliliğine sebebiyet veren en önemli unsurlardan bir tanesidir. Bu yakıtların bilinçsizce kullanılması sonucunda çevre problemlerine özellikle de hava kirliliğine neden olmaktadır. Yapılan bu çalışmada, Karabük ilinin doğalgaz kullanmaya başlamadan önceki ve doğalgaza geçiş ile hava kirlilik parametreleri (SO2 ve PM10 incelenmiştir. Doğal gaz kullanımının hava kalitesine etkisi araştırılmıştır. İlde ısınma ihtiyacını karşılamak için kömür, fuel-oil ve mazot kullanılırken 2010 yılı itibariyle doğal gaza geçilmiştir. Doğal gazın kullanılmaya başlanmasıyla bu yakıtların kullanımı azalmıştır. Çalışmanın sonunda, Hava Kalitesi Değerlendirme ve Yönetimi Yönetmeliğinde (HKDYY belirtilen, SO2 için 250 μg/m3 değerinin doğal gaz kullanımına geçilmeden önce bazı aylarda üzerinde olduğu görülmüş ve doğal gaz kullanılmaya başlanmasından sonraki dönemlerde ise 250 μg/m3 değerinin aşılmadığı görülmüştür. PM10 için yönetmelikte belirtilen 200 μg/m3 değerinin kış sezonunda aşıldığı tespit edilmiştir. 2010 yılında Doğal gaz kullanımına geçiş ile birlikte bu değerde tekrar bir düşüş gözlenmiştir. Doğal gaz kullanım oranı artıkça havadaki SO2 ve PM10 değerlerinde ciddi düşüşler olduğu gözlenmiştir.AbstractThe Usage of fossil origin fuels is one of the most important cause of air pollution. The usage of these fuels unconsciously causes environmental problems especially air pollution. In this study air pollution parameters (SO2 ve PM10 were analyzed before and after the usage of natural gas in Karabuk. The effect of usage natural gas on air quality is researched. In this city before 2010 coal, foul-oil and diesel were used to provide heat demanded then it is started using natural gas by 2010.With starting the usage of natural gas, the usage of these kind of fuels (coal, foul

  9. Elliptic flow in Au+Au collisions at $\\sqrt{S_{NN}}$=130 GeV

    CERN Document Server

    Ackermann, K H; Adler, C; Ahammed, Z; Ahmad, S; Allgower, C; Amsbaugh, J; Anderson, M; Anderssen, E; Arnesen, H; Arnold, L; Averichev, G S; Baldwin, A R; Balewski, J T; Barannikova, O Yu; Barnby, L S; Baudot, J; Beddo, M E; Bekele, S; Belaga, V V; Bellwied, R; Bennett, S; Bercovitz, J; Berger, J; Betts, W; Bichsel, H; Bieser, F; Bland, L C; Bloomer, M A; Blyth, C O; Böhm, J; Bonner, B E; Bonnet, D; Bossingham, R R; Botlo, M; Boucham, A; Bouillo, N; Bouvier, S; Bradley, K; Brady, F P; Braithwaite, E S; Braithwaite, W; Brandin, A B; Brown, R L; Brugalette, G; Byrd, C; Caines, H; Calderón de la Barca-Sanchez, M; Cardenas, A; Carr, L; Carroll, J; Castillo, J; Caylor, B; Cebra, D; Chathopadhyay, S; Chen, M L; Chen, W; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Chrin, J; Christie, W; Coffin, J P; Conin, L; Consiglio, C; Cormier, T M; Cramer, J G; Crawford, H J; Danilov, V I; Dayton, D; De Mello, M; Deng, W S; Derevshchikov, A A; Dialinas, M; Díaz, H; De Young, P A; Didenko, L; Dimassimo, D; Dioguardi, J; Dominik, Wojciech; Drancourt, C; Draper, J E; Dunin, V B; Dunlop, J C; Eckardt, V; Edwards, W R; Efimov, L G; Eggert, T; Emelyanov, V I; Engelage, J; Eppley, G; Erazmus, B; Etkin, A; Fachini, P; Feliciano, C; Ferenc, D; Ferguson, M I; Fessler, H; Finch, E; Fine, V; Fisyak, Yu; Flierl, D; Flores, I; Foley, Kenneth J; Fritz, D; Gagunashvili, N D; Gans, J; Gazdzicki, M; Germain, M; Geurts, F J M; Ghazikhanian, V; Gojak, C; Grabski, J; Grachov, O A; Grau, M; Greiner, D E; Greiner, L; Grigoriev, V; Grosnick, D P; Gross, J; Guilloux, G; Gushin, E M; Hall, J; Hallman, T J; Hardtke, D; Harper, G; Harris, J W; He, P; Heffner, M; Heppelmann, S; Herston, T; Hill, D; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Howe, M; Huang, H Z; Humanic, T J; Hümmler, H; Hunt, W; Hunter, J; Igo, G; Ishihara, A; Ivanshin, Yu I; Jacobs, P; Jacobs, W W; Jacobson, S; Jared, R; Jensen, P; Johnson, I; Jones, P G; Judd, E; Kaneta, M; Kaplan, M; Keane, D; Kenney, V P; Khodinov, A; Klay, J L; Klein, S R; Klyachko, A A; Koehler, G; Konstantinov, A S; Kormilitsyne, V; Kotchenda, L; Kotov, I V; Kovalenko, A D; Krämer, M; Kravtsov, P; Krüger, K; Krupien, T; Kuczewski, P; Kühn, C E; Kunde, G J; Kunz, C L; Kutuev, R K; Kuznetsov, A A; Lakehal-Ayat, L; Lamont, M A C; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lebedev, A; LeCompte, T J; Leonhardt, W; Leontiev, V M; Leszczynski, P; Le Vine, M J; Li, Q; Li, Z; Liaw, C J; Lin, J; Lindenbaum, S J; Lindenstruth, V; Lindstrom, P J; Lisa, M A; Liu, H; Ljubicic, T; Llope, W J; Lo Curto, G; Long, H; Longacre, R S; López-Noriega, M; Lopiano, D; Love, W A; Lutz, Jean Robert; Lynn, D; Madansky, L; Maier, R S; Majka, R; Maliszewski, A; Margetis, S; Marks, K; Marstaller, R; Martin, L; Marx, J; Matis, H S; Matulenko, Yu A; Matyushevsky, E A; McParland, C P; McShane, T S; Meier, J; Melnik, Yu M; Meshchanin, A P; Middlekamp, P; Mikhalin, N; Miller, B; Milosevich, Z; Minaev, N G; Minor, B; Mitchell, J; Mogavero, E; Moiseenko, V A; Moltz, D M; Moore, C F; Morozov, V; Morse, R; De Moura, M M; Munhoz, M G; Mutchler, G S; Nelson, J M; Nevski, P; Ngo, T; Nguyen, M; Nguyen, T; Nikitin, V A; Nogach, L V; Noggle, T; Norman, B; Nurushev, S B; Nussbaum, T; Nystrand, J; Odyniec, Grazyna Janina; Ogawa, A; Ogilvie, C A; Olchanski, K; Oldenburg, M; Olson, D; Ososkov, G A; Ott, G; Padrazo, D; Paic, G; Pandey, S U; Panebratsev, Yu A; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Pentia, M; Perevozchikov, V; Peryt, W; Petrov, V; Pinganaud, W; Pirogov, S; Platner, E D; Pluta, J; Polk, I; Porile, N T; Porter, J; Poskanzer, A M; Potrebenikova, E V; Prindle, D J; Pruneau, C A; Puskar-Pasewicz, J; Rai, G; Rasson, J E; Ravel, O; Ray, R L; Razin, S V; Reichhold, D M; Reid, J; Renfordt, R E; Retière, F; Ridiger, A; Riso, J; Ritter, H G; Roberts, J B; Röhrich, D; Rogachevski, O V; Romero, J L; Roy, C; Russ, D; Rykov, V L; Sakrejda, I; Sánchez, R; Sandler, Z; Sandweiss, J; Sappenfield, P; Saulys, A C; Savin, I A; Schambach, J; Scharenberg, R P; Scheblien, J; Scheetz, R; Schlüter, R; Schmitz, N; Schröder, L S; Schulz, M; Schüttauf, A; Sedlmeir, J; Seger, J E; Seliverstov, D M; Seyboth, J; Seyboth, P; Seymour, R; Shakaliev, E I; Shestermanov, K E; Shi, Y; Shimansky, S S; Shuman, D B; Shvetcov, V S; Skoro, G P; Smirnov, N; Smykov, L P; Snellings, R; Solberg, K; Sowinski, J; Spinka, H M; Srivastava, B; Stephenson, E J; Stock, Reinhard; Stolpovsky, A; Stone, N; Stone, R; Strikhanov, M N; Stringfellow, B C; Ströbele, H; Struck, C; Suaide, A A P; Sugarbaker, E R; Suire, C; Symons, T J M; Takahashi, J; Tang, A H; Tarchini, A; Tarzian, J; Thomas, J H; Tikhomirov, V; Szanto de Toledo, A; Tonse, S R; Trainor, T; Trentalange, S; Tokarev, M; Tonjes, M B; Trofimov, V N; Tsai, O; Turner, K; Ullrich, T S; Underwood, D G; Vakula, I; Van Buren, G; Van der Molen, A; Vanyashin, A V; Vasilevskii, I M; Vasilev, A N; Vigdor, S E; Visser, G; Voloshin, S A; Vu, C; Wang, F; Ward, H; Weerasundara, D D; Weidenbach, R; Wells, R; Wenaus, T J; Westfall, G D; Whitfield, J P; Whitten, C; Wieman, H H; Willson, R; Wilson, K; Wirth, J; Wisdom, J; Wissink, S W; Witt, R; Wolf, J; Wood, L; Xu, N; Xu, Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yokosawa, A; Yurevich, V I; Zanevsky, Yu V; Zhang, J; Zhang, W M; Zhu, J; Zimmerman, D; Zoulkarneev, R; Zubarev, A N

    2001-01-01

    Elliptic flow from nuclear collisions is a hadronic observable sensitive to the early stages of system evolution. We report first results on elliptic flow of charged particles at midrapidity in Au+Au collisions at sqrt(s_NN)=130 GeV using the STAR TPC at RHIC. The elliptic flow signal, v_2, averaged over transverse momentum, reaches values of about 6% for relatively peripheral collisions and decreases for the more central collisions. This can be interpreted as the observation of a higher degree of thermalization than at lower collision energies. Pseudorapidity and transverse momentum dependence of elliptic flow are also presented.

  10. D and $^{3}He$ production in $\\sqrt{s}$ = 130 GeV Au + Au collisions

    CERN Document Server

    Adler, C; Allgower, C; Amonett, J; Anderson, B D; Anderson, M; Averichev, G S; Balewski, J T; Barannikova, O Yu; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bichsel, H; Bland, L C; Blyth, C O; Bonner, B E; Boucham, A; Brandin, A B; Cadman, R V; Caines, H; Calderón de la Barca-Sanchez, M; Cardenas, A; Carroll, J; Castillo, J; Castro, M; Cebra, D; Chattopadhyay, S; Chen, M L; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Christie, W; Cormier, T M; Cramer, J G; Crawford, H J; De Mello, M; Deng, W S; Derevshchikov, A A; Didenko, L; Draper, J E; Dunin, V B; Dunlop, J C; Eckardt, V; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Fachini, P; Faine, V; Finch, E; Fisyak, Yu; Flierl, D; Foley, Kenneth J; Fu, J; Gagunashvili, N D; Gans, J; Gaudichet, L; Germain, M; Geurts, F J M; Ghazikhanian, V; Grabski, J; Grachov, O A; Greiner, D E; Grigoriev, V; Guedon, M; Guschin, E; Hallman, T J; Hardtke, D; Harris, J W; Heffner, M; Heppelmann, S; Herston, T; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Huang, H Z; Humanic, T J; Hümmler, H; Igo, G; Ishihara, A; Ivanshin, Yu I; Jacobs, P; Jacobs, W W; Janik, M; Johnson, I; Jones, P G; Judd, E; Kaneta, M; Kaplan, M; Keane, D; Kisiel, A; Klay, J L; Klein, S R; Klyachko, A A; Konstantinov, A S; Kotchenda, L; Kovalenko, A D; Krämer, M; Kravtsov, P; Krüger, K; Kuhn, C; Kulikov, A V; Kunde, G J; Kunz, C L; Kutuev, R K; Kuznetsov, A A; Lakehal-Ayat, L; Lamas-Valverde, J; Lamont, M A C; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lebedev, A; LeCompte, T J; Lednicky, R; Leontiev, V M; Le Vine, M J; Li, Q; Lindenbaum, S J; Lisa, M A; Ljubicic, T; Llope, W J; Lo Curto, G; Long, H; Longacre, R S; López-Noriega, M; Love, W A; Lynn, D; Majka, R; Margetis, S; Martin, L; Marx, J; Matis, H S; Matulenko, Yu A; McShane, T S; Meissner, F; Melnik, Yu M; Meshchanin, A P; Messer, M; Miller, M L; Milosevich, Z; Minaev, N G; Mitchell, J; Moiseenko, V A; Moltz, D; Moore, C F; Morozov, V; De Moura, M M; Munhoz, M G; Mutchler, G S; Nelson, J M; Nevski, P; Nikitin, V A; Nogach, L V; Norman, B; Nurushev, S B; Odyniec, Grazyna Janina; Ogawa, A; Okorokov, V; Oldenburg, M; Oson, D; Paic, G; Pandey, S U; Panebratsev, Yu A; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Perevozchikov, V; Peryt, W; Petrov, V A; Platner, E D; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potrebenikova, E V; Prindle, D J; Pruneau, C A; Radomski, S; Rai, G; Ravel, O; Ray, R L; Razin, S V; Reichhold, D M; Reid, J G; Retière, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Roy, C; Russ, D; Rykov, V L; Sakrejda, I; Sandweiss, J; Saulys, A C; Savin, I; Schambach, J; Scharenberg, R P; Schmitz, N; Schröder, L S; Schüttauf, A; Schweda, K; Seger, J E; Seliverstov, D M; Seyboth, P; Shahaliev, E; Shestermanov, K E; Shimansky, S S; Shvetcov, V S; Skoro, G P; Smirnov, N; Snellings, R; Sowinski, J; Spinka, H M; Srivastava, B; Stephenson, E J; Stock, Reinhard; Stolpovsky, A; Strikhanov, M N; Stringfellow, B C; Struck, C; Suaide, A A P; Sugarbaker, E R; Suire, C; Sumbera, M; Symons, T J M; Szanto de Toledo, A; Szarwas, P; Takahashi, J; Tang, A H; Thomas, J H; Tikhomirov, V; Trainor, T A; Trentalange, S; Tokarev, M; Tonjes, M B; Trofimov, V; Tsai, O; Turner, K; Ullrich, T S; Underwood, D G; Van Buren, G; Van der Molen, A; Vanyashin, A V; Vasilevski, I M; Vasilev, A N; Vigdor, S E; Voloshin, S A; Wang, F; Ward, H; Watson, J W; Wells, R; Wenaus, T J; Westfall, G D; Whitten, C; Wieman, H H; Willson, R; Wissink, S W; Witt, R; Xu, N; Xu, Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yokosawa, A; Yurevich, V I; Zanevsky, Yu V; Zborovský, I; Zhang, H; Zhang, W M; Zoulkarneev, R; Zubarev, A N; 10.1103/PhysRevLett.87.262301

    2001-01-01

    The first measurements of light antinucleus production in Au + Au collisions at the Relativistic Heavy-Ion Collider are reported. The observed production rates for d and /sup 3/He are much larger than in lower energy nucleus-nucleus collisions. A coalescence model analysis of the yields indicates that there is little or no increase in the antinucleon freeze-out volume compared to collisions at CERN SPS energy. These analyses also indicate that the 3He freeze-out volume is smaller than the d freeze-out volume. (22 refs).

  11. Nuclear Stopping in Central Au+Au Collisions at RHIC Energies

    Directory of Open Access Journals (Sweden)

    Ying Yuan

    2014-01-01

    Full Text Available Nuclear stopping in central Au+Au collisions at relativistic heavy-ion collider (RHIC energies is studied in the framework of a cascade mode and the modified ultrarelativistic quantum molecular dynamics (UrQMD transport model. In the modified mode, the mean field potentials of both formed and “preformed” hadrons (from string fragmentation are considered. It is found that the nuclear stopping is increasingly influenced by the mean-field potentials in the projectile and target regions with the increase of the reaction energy. In the central region, the calculations of the cascade model considering the modifying factor can describe the experimental data of the PHOBOS collaboration.

  12. Coût des soins de santé attribuables au tabagisme au Cambodge ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Au Cambodge, l'incidence de la tuberculose et du tabagisme est élevée de sorte que le coût du tabagisme comprendra aussi le coût des décès " supplémentaires " occasionnés par la tuberculose liée au tabagisme. Dans ce pays, les systèmes d'information sur la santé ne sont ni rigoureux, ni fiables. Par conséquent, on ne ...

  13. Relativistic multireference many-body perturbation theory calculations on Au64+ - Au69+ ions

    Energy Technology Data Exchange (ETDEWEB)

    Vilkas, M J; Ishikawa, Y; Trabert, E

    2006-03-31

    Many-body perturbation theory (MBPT) calculations are an adequate tool for the description of the structure of highly charged multi-electron ions and for the analysis of their spectra. They demonstrate this by way of a re-investigation of n=3, {Delta}n=0 transitions in the EUV spectra of Na-, Mg-, Al-like, and Si-like ions of Au that have been obtained previously by heavy-ion accelerator based beam-foil spectroscopy. They discuss the evidence and propose several revisions on the basis of the multi-reference many-body perturbation theory calculations of Ne- through P-like ions of Au.

  14. Measurements of direct photons in Au+Au collisions with PHENIX

    CERN Document Server

    Bannier, Benjamin

    2014-01-01

    The PHENIX experiment has published direct photon yields and elliptic flow coefficients $v_2$ from Au+Au collisions at RHIC energies. These results have sparked much theoretical discussion. The measured yields and flow parameters are difficult to reconcile in current model calculations of thermal radiation based on hydrodynamic time evolution of the collision volume. Our latest analyses which use high statistics data from the 2007 and 2010 runs allow the determination of direct photon yields with finer granularity in centrality and photon momentum and down to $p_T$ as low as 0.4 GeV/$c$. We will summarize the current status and present new results from PHENIX.

  15. Méthode analytique généralisée pour le calcul du coning. Nouvelle solution pour calculer le coning de gaz, d'eau et double coning dans les puits verticaux et horizontaux Generalized Analytical Method for Coning Calculation. New Solution to Calculation Both the Gas Coning, Water Coning and Dual Coning for Vertical and Horizontal Wells

    Directory of Open Access Journals (Sweden)

    Pietraru V.

    2006-11-01

    Full Text Available Une nouvelle méthode analytique d'évaluation du coning d'eau par bottom water drive et/ou de gaz par gas-cap drive dans les puits horizontaux et verticaux a été développée pour les réservoirs infinis [1]. Dans cet article, une généralisation de cette méthode est présentée pour les réservoirs confinés d'extension limitée dont le toit est horizontal. La généralisation proposée est basée sur la résolution des équations différentielles de la diffusivité avec prise en compte des effets de drainage par gravité et des conditions aux limites pour un réservoir confiné. La méthode est applicable aux réservoirs isotropes ou anisotropes. L'hypothèse de pression constante à la limite de l'aire de drainage dans l'eau et/ou dans le gaz a été adoptée. Les pertes de charge dans l'aquifère et dans le gas-cap sont donc négligées. Les principales contributions de cet article sont : - L'introduction de la notion de rayon de cône, différent du rayon de puits. La hauteur du cône et le débit critique dépendent du rayon de cône alors qu'ils sont indépendants du rayon du puits. - Une nouvelle corrélation pour le calcul du débit critique sous forme adimensionnelle en fonction de trois paramètres : le temps, la longueur du drain horizontal (nulle pour un puits vertical et le rayon de drainage. - Des corrélations pour le calcul du rapport des débits gaz/huile (GOR ou de la fraction en eau (fw, pendant les périodes critique et postcritique, qui tiennent compte de la pression capillaire et des perméabilités relatives. - Des corrélations pour le calcul des rapports de débits gaz/huile et eau/huile pendant les périodes pré, post et supercritique en double coning. - Des critères pour le calcul du temps de percée au puits en simple coning de gaz ou d'eau, ou en double coning de gaz et d'eau. A new analytical method for assessing water and/or gas coning in horizontal and vertical wells has been developed for infinite

  16. Au/Pd core-shell nanoparticles with varied hollow Au cores for enhanced formic acid oxidation

    Science.gov (United States)

    Hsu, Chiajen; Huang, Chienwen; Hao, Yaowu; Liu, Fuqiang

    2013-03-01

    A facile method has been developed to synthesize Au/Pd core-shell nanoparticles via galvanic replacement of Cu by Pd on hollow Au nanospheres. The unique nanoparticles were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, ultraviolet-visible spectroscopy, and electrochemical measurements. When the concentration of the Au solution was decreased, grain size of the polycrystalline hollow Au nanospheres was reduced, and the structures became highly porous. After the Pd shell formed on these Au nanospheres, the morphology and structure of the Au/Pd nanoparticles varied and hence significantly affected the catalytic properties. The Au/Pd nanoparticles synthesized with reduced Au concentrations showed higher formic acid oxidation activity (0.93 mA cm-2 at 0.3 V) than the commercial Pd black (0.85 mA cm-2 at 0.3 V), suggesting a promising candidate as fuel cell catalysts. In addition, the Au/Pd nanoparticles displayed lower CO-stripping potential, improved stability, and higher durability compared to the Pd black due to their unique core-shell structures tuned by Au core morphologies.

  17. Analysis of Simultaneous Gas-Liquid Flow Through an Orifice and Its Application to Flow Metering Etude de l'écoulement simultané d'un mélange gaz-liquide à travers un orifice et son application à la mesure du débit

    Directory of Open Access Journals (Sweden)

    Pascal H.

    2006-11-01

    Full Text Available The purpose of this article is to show a more accurate orifice equation for a two-phase flow, such a compressible mixture of gas and liquid. The orifice equation given here con be used for the measurement of a gas-liquid mixture of fine emulsions by the orificemeter method. From the thermodynamic point of view, an equation of state has been formulated which provides the relationship between the specific mass of the mixture and pressure, under conditions of adiabatic expansion. The results obtained enable the mass flow rates of gas and liquid ta be determined without separation of the phases, provided thot the gas liquid mass ratio is known. The critical pressure ratio corresponding ta sonic velocity is also determined. Cet article présente une relation plus précise pour l'écoulement d'un système à deux phases, tel qu'un mélange compressible gaz-liquide, à travers un diaphragme. Cette relation peut être utilisée pour des mesures de mélanges gaz-liquide très finement divisés, c'est-à-dire des émulsions ou brouillards, par la méthode du diaphragme en paroi mince. Du point de vue thermodynamique, on a formulé une équation d'état donnant la relation entre la masse spécifique du mélange et la pression dans des conditions d'expansion adiabatique. Les résultats obtenus per-mettent de déterminer le débit massique du gaz et du liquide, sans séparation des deux phases, à condition que le rapport de masse gaz-liquide soit connu. On détermine également le rapport de pression critique correspondantà la vitesse du son.

  18. Un guide colonial. Le Guide du Voyageur au Congo belge et au Ruanda-Urundi A colonial guidebook. Travel guide to Belgian Congo and Ruanda-Urundi

    Directory of Open Access Journals (Sweden)

    Henri Nicolaï

    2013-03-01

    Full Text Available Le Guide, qui a connu cinq éditions pendant les dix dernières années du Congo belge, est un archétype du guide colonial. L’article rappelle d’abord la naissance du tourisme en Afrique centrale et ses caractéristiques. Fasciné longtemps par les mythes des Monts de la Lune et des sources du Nil, le tourisme congolais est, au départ, essentiellement élitiste, orienté surtout vers la grande chasse sportive. Gorilles de montagne, ascensions du Ruwenzori, danseurs Tutsi, Parc National Albert, pêcheurs wagenia deviennent les icônes d’un tourisme attiré en ordre principal par le Kivu, les Grands Lacs, Stanleyville et secondairement le Katanga. Le premier guide, édité par Vicicongo, en 1934, s’intitule d’ailleurs Congo-Nil. Tous ces mythes et ces décors se retrouvent dans quelques grands films américains d’aventure du début des années 50.L’article décrit ensuite la genèse du Guide, ses caractéristiques générales, son plan, son contenu. Beaucoup d’informations générales, pas de véritables circuits mais plutôt des itinéraires routiers. Produit par les services officiels d’information de la Colonie, le Guide a, parmi ses objectifs, de montrer la persistance et les résultats de l’action civilisatrice de la Belgique. Il affirme que le Congo n’est pas un pays d’art ni d’histoire et accorde donc une part prépondérante au milieu naturel. Il fournit une image tronquée de son histoire et exprime sur ses habitants les préjugés de l’époque.L’article se termine par quelques réflexions sur les tentatives d’un reporter d’une chaîne de télévision et d’un photographe d’utiliser le Guide de 1958 pour parcourir le pays un demi-siècle plus tard.The Travel Guide to Belgian Congo and Ruanda-Urundi, of which five editions were released during the last ten years of Belgian Congo, is an archetypal colonial guide.The paper first highlights the emergence and the features of tourism in Central Africa

  19. Conductive Au nanowires regulated by silk fibroin nanofibers

    Science.gov (United States)

    Dong, Bo-Ju; Lu, Qiang

    2014-03-01

    Conductive Au-biopolymer composites have promising applications in tissue engineering such as nerve tissue regeneration. In this study, silk fibroin nanofibers were formed in aqueous solution by regulating silk self-assembly process and then used as template for Au nanowire fabrication. We performed the synthesis of Au seeds by repeating the seeding cycles for several times in order to increase the density of Au seeds on the nanofibers. After electroless plating, densely decorated Au seeds grew into irregularly shaped particles following silk nanofiber to fill the gaps between particles and finally form uniform continuous nanowires. The conductive property of the Au-silk fibroin nanowires was studied with current-voltage ( I-V) measurement. A typical ohmic behavior was observed, which highlighted their potential applications in nerve tissue regeneration.

  20. Lateral spreading of Au contacts on InP

    Science.gov (United States)

    Fatemi, Navid S.; Weizer, Victor G.

    1990-01-01

    The contact spreading phenomenon observed when small area Au contacts on InP are annealed at temperatures above about 400 C was investigated. It was found that the rapid lateral expansion of the contact metallization which consumes large quantities of InP during growth is closely related to the third stage in the series of solid state reactions that occur between InP and Au, i.e., to the Au3In-to-Au9In4 transition. Detailed descriptions are presented of both the spreading process and the Au3In-to-Au9In4 transition along with arguments that the two processes are manifestations of the same basic phenomenon.