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Sample records for atmospheric pressure glow

  1. Glow plasma jet - experimental study of a transferred atmospheric pressure glow discharge

    International Nuclear Information System (INIS)

    Guerra-Mutis, Marlon H; U, Carlos V Pelaez; H, Rafael Cabanzo

    2003-01-01

    In this paper we present the experimental study of a glow plasma jet (GPJ) obtained from a transferred atmospheric pressure glow discharge (APGD) operating at 60 Hz. The characterization of the emission spectra for both electrical discharges is presented and the electrical circuit features for APGD generation are discussed. The potentiality of GPJ as a source of active species for depletion of contaminants in liquid hydrocarbon fractions is also established

  2. Spectroscopic characterisation of an atmospheric pressure glow discharge

    International Nuclear Information System (INIS)

    Gomez, S.; Steen, P.G.; Morrow, T.; Graham, W.G.

    2001-01-01

    Recently there has been considerable interest in atmospheric discharges operating in a glow discharge mode i.e. with a spatial and sheath structure similar to that of low pressure glow discharges. Here spectroscopy has been used to characterise an atmospheric pressure glow discharge (APGD), operating with either dry air, argon or helium gas flowing through the inter-electrode space and with the inter-electrode gap either free or with woven polypropylene or polyester samples present. Emission spectroscopy is used to determine the rotational and vibrational temperature of the nitrogen gas, while electron temperatures are determined from the relative intensities of Ar emission lines. Ozone production is monitored by a simple absorption technique to evaluate its potential in process control

  3. Simulation of nonstationary phenomena in atmospheric-pressure glow discharge

    Science.gov (United States)

    Korolev, Yu. D.; Frants, O. B.; Nekhoroshev, V. O.; Suslov, A. I.; Kas'yanov, V. S.; Shemyakin, I. A.; Bolotov, A. V.

    2016-06-01

    Nonstationary processes in atmospheric-pressure glow discharge manifest themselves in spontaneous transitions from the normal glow discharge into a spark. In the experiments, both so-called completed transitions in which a highly conductive constricted channel arises and incomplete transitions accompanied by the formation of a diffuse channel are observed. A model of the positive column of a discharge in air is elaborated that allows one to interpret specific features of the discharge both in the stationary stage and during its transition into a spark and makes it possible to calculate the characteristic oscillatory current waveforms for completed transitions into a spark and aperiodic ones for incomplete transitions. The calculated parameters of the positive column in the glow discharge mode agree well with experiment. Data on the densities of the most abundant species generated in the discharge (such as atomic oxygen, metastable nitrogen molecules, ozone, nitrogen oxides, and negative oxygen ions) are presented.

  4. Simulation of nonstationary phenomena in atmospheric-pressure glow discharge

    International Nuclear Information System (INIS)

    Korolev, Yu. D.; Frants, O. B.; Nekhoroshev, V. O.; Suslov, A. I.; Kas’yanov, V. S.; Shemyakin, I. A.; Bolotov, A. V.

    2016-01-01

    Nonstationary processes in atmospheric-pressure glow discharge manifest themselves in spontaneous transitions from the normal glow discharge into a spark. In the experiments, both so-called completed transitions in which a highly conductive constricted channel arises and incomplete transitions accompanied by the formation of a diffuse channel are observed. A model of the positive column of a discharge in air is elaborated that allows one to interpret specific features of the discharge both in the stationary stage and during its transition into a spark and makes it possible to calculate the characteristic oscillatory current waveforms for completed transitions into a spark and aperiodic ones for incomplete transitions. The calculated parameters of the positive column in the glow discharge mode agree well with experiment. Data on the densities of the most abundant species generated in the discharge (such as atomic oxygen, metastable nitrogen molecules, ozone, nitrogen oxides, and negative oxygen ions) are presented.

  5. Study of short atmospheric pressure dc glow microdischarge in air

    Science.gov (United States)

    Kudryavtsev, Anatoly; Bogdanov, Eugene; Chirtsov, Alexander; Emelin, Sergey

    2011-10-01

    The results of experiments and simulations of short (without positive column) atmospheric pressure dc glow discharge in air are presented. We used metal steel electrodes with a gap of 5-100 microns. The experimental voltage-current characteristic's (VAC) have a constant or slightly increasing form at low gap. The most stable microdischarges were burning with a flat cathode and rounded anode, when the length of the discharge is automatically established near the minimum of the Paschen curve by changing their binding on the anode. In this case microdischarge was stable and it had growing VAC. For simulations we used 2D fluid model with kinetic description of electrons. We solved the balance equations for the vibrationally- and the electronically-excited states of a nitrogen and oxygen molecules; nitrogen and oxygen atoms; ozone molecule; and different nitrogen and oxygen ions with different plasmochemical reactions between them. Simulations predicted the main regions of the dc glow discharges including cathode and anode sheath and plasma of negative glow, Faraday dark space and transition region. Gas heating plays an important role in shaping the discharge profiles. The results of experiments and simulations of short (without positive column) atmospheric pressure dc glow discharge in air are presented. We used metal steel electrodes with a gap of 5-100 microns. The experimental voltage-current characteristic's (VAC) have a constant or slightly increasing form at low gap. The most stable microdischarges were burning with a flat cathode and rounded anode, when the length of the discharge is automatically established near the minimum of the Paschen curve by changing their binding on the anode. In this case microdischarge was stable and it had growing VAC. For simulations we used 2D fluid model with kinetic description of electrons. We solved the balance equations for the vibrationally- and the electronically-excited states of a nitrogen and oxygen molecules; nitrogen

  6. Synthesis of nanoparticles in an atmospheric pressure glow discharge

    International Nuclear Information System (INIS)

    Barankin, M.D.; Creyghton, Y.; Schmidt-Ott, A.

    2006-01-01

    Nanopowders are produced in a low temperature, non-equilibrium plasma jet (APPJ), which produces a glow discharge at atmospheric pressure, for the first time. Amorphous carbon and iron nanoparticles have been synthesized from Acetylene and Ferrocene/H 2 , respectively. High generation rates are achieved from the glow discharge at near-ambient temperature (40-80 deg. C), and rise with increasing plasma power and precursor concentration. Fairly narrow particle size distributions are measured with a differential mobility analyzer (DMA) and an aerosol electrometer (AEM), and are centered around 30-35 nm for carbon and 20-25 nm for iron. Particle characteristics analyzed by TEM and EDX reveal amorphous carbon and iron nanoparticles. The Fe particles are highly oxidized on exposure to air. Comparison of the mobility and micrograph diameters reveal that the particles are hardly agglomerated or unagglomerated. This is ascribed to the unipolar charge on particles in the plasma. The generated particle distributions are examined as a function of process parameters

  7. Means of introducing an analyte into liquid sampling atmospheric pressure glow discharge

    Science.gov (United States)

    Marcus, R. Kenneth; Quarles, Jr., Charles Derrick; Russo, Richard E.; Koppenaal, David W.; Barinaga, Charles J.; Carado, Anthony J.

    2017-01-03

    A liquid sampling, atmospheric pressure, glow discharge (LS-APGD) device as well as systems that incorporate the device and methods for using the device and systems are described. The LS-APGD includes a hollow capillary for delivering an electrolyte solution to a glow discharge space. The device also includes a counter electrode in the form of a second hollow capillary that can deliver the analyte into the glow discharge space. A voltage across the electrolyte solution and the counter electrode creates the microplasma within the glow discharge space that interacts with the analyte to move it to a higher energy state (vaporization, excitation, and/or ionization of the analyte).

  8. Gas Breakdown of Radio Frequency Glow Discharges in Helium at near Atmospheric Pressure

    International Nuclear Information System (INIS)

    Liu Xinkun; Xu Jinzhou; Cui Tongfei; Guo Ying; Zhang Jing; Shi Jianjun

    2013-01-01

    A one-dimensional self-consistent fluid model was developed for radio frequency glow discharge in helium at near atmospheric pressure, and was employed to study the gas breakdown characteristics in terms of breakdown voltage. The effective secondary electron emission coefficient and the effective electric field for ions were demonstrated to be important for determining the breakdown voltage of radio frequency glow discharge at near atmospheric pressure. The constant of A was estimated to be 64±4 cm −1 Torr −1 , which was proportional to the first Townsend coefficient and could be employed to evaluate the gas breakdown voltage. The reduction in the breakdown voltage of radio frequency glow discharge with excitation frequency was studied and attributed to the electron trapping effect in the discharge gap

  9. Formation and evolution of the glow-like dielectric barrier discharge at atmospheric pressure

    NARCIS (Netherlands)

    Starostin, S.A.; ElSabbagh, M.A.M.; Premkumar, P.A.; Vries, de H.W.; Paffen, R.M.J.; Creatore, M.; Sanden, van de M.C.M.

    2008-01-01

    Time resolved process of formation and evolution of the atmospheric pressure glow discharge was studied in the roll-to- roll plasma- enhanced chemical vapor deposition dielectric barrier discharge reactor operating in helium-free gas mixtures by means of fast ICCD imaging. It was observed that the

  10. Gas phase hydrogen peroxide production in atmospheric pressure glow discharges operating in He - H2O

    NARCIS (Netherlands)

    Vasko, C.A.; Veldhuizen, van E.M.; Bruggeman, P.J.

    2013-01-01

    The gas phase production of hydrogen peroxide (H2O2) in a RF atmospheric pressure glow discharge with helium and water vapour has been investigated as a function of the gas flow. It is shown that the production of H2O2 is through the recombination of two OH radicals in a three body collision and the

  11. Anode pattern formation in atmospheric pressure air glow discharges with water anode

    NARCIS (Netherlands)

    Verreycken, T.; Bruggeman, P.J.; Leys, C.

    2009-01-01

    Pattern formation in the anode layer at a water electrode in atmospheric pressure glow discharges in air is studied. With increasing current a sequence of different anode spot structures occurs from a constricted homogeneous spot in the case of small currents to a pattern consisting of small

  12. Clostridium beijerinckii mutant obtained atmospheric pressure glow discharge generates enhanced electricity in a microbial fuel cell.

    Science.gov (United States)

    Liu, Jun; Guo, Ting; Wang, Dong; Ying, Hanjie

    2015-01-01

    A Clostridium beijerinckii mutant M13 was derived from C. beijerinckii NCIMB 8052 by atmospheric pressure glow discharge. C. beijerinckii M13 generated a maximum output power density of 79.2 mW m(-2) and a maximum output voltage of 230 mV in a microbial fuel cell containing 1 g glucose l(-1) as carbon source and 0.15 g methyl viologen l(-1) as an electron carrier.

  13. Cathode fall parameters of a self-sustained normal glow discharge in atmospheric-pressure helium

    International Nuclear Information System (INIS)

    Arkhipenko, V.I.; Zgirovskii, S.M.; Kirillov, A.A.; Simonchik, L.V.

    2002-01-01

    Results from comprehensive studies of a high-current self-sustained glow discharge in atmospheric-pressure helium are presented. The main parameters of the cathode fall, namely, the electric field profile, cathode fall thickness, current density, gas temperature, and heat flux to the cathode are determined. The results obtained are discussed using one-dimensional models of the cathode fall with allowance for volumetric heat release

  14. On the regime transitions during the formation of an atmospheric pressure dielectric barrier glow discharge

    International Nuclear Information System (INIS)

    Martens, T; Bogaerts, A; Brok, W J M; Van Dijk, J

    2009-01-01

    The atmospheric pressure dielectric barrier discharge in helium is a pulsed discharge in nature. If during the electrical current pulse a glow discharge is reached, then this pulse will last only a few microseconds in operating periods of sinusoidal voltage with lengths of about 10 to 100 μs. In this paper we demonstrate that right before a glow discharge is reached, the discharge very closely resembles the commonly assumed Townsend discharge structure, but actually contains some significant differing features and hence should not be considered as a Townsend discharge. In order to clarify this, we present calculation results of high time and space resolution of the pulse formation. The results indicate that indeed a maximum of ionization is formed at the anode, but that the level of ionization remains high and that the electric field at that time is significantly disturbed. Our results also show where this intermediate structure comes from. (fast track communication)

  15. Methane Conversion to C2 Hydrocarbons by Abnormal Glow Discharge at Atmospheric Pressure

    International Nuclear Information System (INIS)

    Dai Wei; Yu Hui; Chen Qi; Yin Yongxiang; Dai Xiaoyan

    2005-01-01

    Methane conversion to C 2 hydrocarbons has been investigated with the addition of hydrogen in a plasma reactor of abnormal glow discharge at atmospheric pressure. The aim of this experiment is to minimize coke formation and improve discharge stability. The typical conditions in the experiment are 300 ml of total feed flux and 400 W of discharge power. The experimental results show that methane conversion is from 91.6% to 35.2% in mol, acetylene selectivity is from 90.2% to 57.6%, and ethylene selectivity is approximately from 7.8% to 3.6%, where the coke increases gradually along with the increase of CH 4 /H 2 from 2: 8 to 9: 1. A stable discharge for a considerable running time can be obtained only at a lower ratio of CH 4 /H 2 2: 8 or 3: 7. These phenomena indicate that the coke deposition during methane conversion is obviously reduced by adding a large amount of hydrogen during an abnormal glow discharge. A qualitative interpretation is presented, namely, with abundant hydrogen, the possibility that hydrogen molecules are activated to hydrogen radicals is increased with the help of the abnormal glow discharge. These hydrogen radicals react with carbon radicals to form C 2 hydrocarbon products. Therefore, the deposition of coke is restrained

  16. Transitions between corona, glow, and spark regimes of nanosecond repetitively pulsed discharges in air at atmospheric pressure

    OpenAIRE

    Pai , David ,; Lacoste , Deanna ,; Laux , C.

    2010-01-01

    International audience; In atmospheric pressure air preheated from 300 to 1000 K, the nanosecond repetitively pulsed (NRP) method has been used to generate corona, glow, and spark discharges. Experiments have been performed to determine the parameter space (applied voltage, pulse repetition frequency, ambient gas temperature, and interelectrode gap distance) of each discharge regime. In particular, the experimental conditions necessary for the glow regime of NRP discharges have been determine...

  17. Decomposition of toluene in a steady-state atmospheric-pressure glow discharge

    International Nuclear Information System (INIS)

    Trushkin, A. N.; Grushin, M. E.; Kochetov, I. V.; Trushkin, N. I.; Akishev, Yu. S.

    2013-01-01

    Results are presented from experimental studies of decomposition of toluene (C 6 H 5 CH 3 ) in a polluted air flow by means of a steady-state atmospheric pressure glow discharge at different water vapor contents in the working gas. The experimental results on the degree of C 6 H 5 CH 3 removal are compared with the results of computer simulations conducted in the framework of the developed kinetic model of plasma chemical decomposition of toluene in the N 2 : O 2 : H 2 O gas mixture. A substantial influence of the gas flow humidity on toluene decomposition in the atmospheric pressure glow discharge is demonstrated. The main mechanisms of the influence of humidity on C 6 H 5 CH 3 decomposition are determined. The existence of two stages in the process of toluene removal, which differ in their duration and the intensity of plasma chemical decomposition of C 6 H 5 CH 3 is established. Based on the results of computer simulations, the composition of the products of plasma chemical reactions at the output of the reactor is analyzed as a function of the specific energy deposition and gas flow humidity. The existence of a catalytic cycle in which hydroxyl radical OH acts a catalyst and which substantially accelerates the recombination of oxygen atoms and suppression of ozone generation when the plasma-forming gas contains water vapor is established.

  18. Decomposition of toluene in a steady-state atmospheric-pressure glow discharge

    Science.gov (United States)

    Trushkin, A. N.; Grushin, M. E.; Kochetov, I. V.; Trushkin, N. I.; Akishev, Yu. S.

    2013-02-01

    Results are presented from experimental studies of decomposition of toluene (C6H5CH3) in a polluted air flow by means of a steady-state atmospheric pressure glow discharge at different water vapor contents in the working gas. The experimental results on the degree of C6H5CH3 removal are compared with the results of computer simulations conducted in the framework of the developed kinetic model of plasma chemical decomposition of toluene in the N2: O2: H2O gas mixture. A substantial influence of the gas flow humidity on toluene decomposition in the atmospheric pressure glow discharge is demonstrated. The main mechanisms of the influence of humidity on C6H5CH3 decomposition are determined. The existence of two stages in the process of toluene removal, which differ in their duration and the intensity of plasma chemical decomposition of C6H5CH3 is established. Based on the results of computer simulations, the composition of the products of plasma chemical reactions at the output of the reactor is analyzed as a function of the specific energy deposition and gas flow humidity. The existence of a catalytic cycle in which hydroxyl radical OH acts a catalyst and which substantially accelerates the recombination of oxygen atoms and suppression of ozone generation when the plasma-forming gas contains water vapor is established.

  19. Bidimensional characterization of the emission spectra in a direct current atmospheric pressure glow discharge

    International Nuclear Information System (INIS)

    Orejas, Jaime; Pisonero, Jorge; Bordel, Nerea; Nelis, Thomas; Guillot, Philippe; Sanz-Medel, Alfredo

    2012-01-01

    An in-house atmospheric pressure glow discharge source, designed to be used as ionization/desorption source for ambient mass spectrometry, has been electrically characterized, and its optical emission spectra evaluated in detail. Electrical characterization showed that the plasma regime can vary from glow discharge to arc discharge depending on operating conditions (i.e. He flow rate and inter electrode distance). Furthermore, bidimensional images of the optical emission of some plasma species using filters as wavelength selectors, were registered from inside and outside the discharge chamber (inner region and afterglow region respectively), showing the spatial distribution of excited species (i.e. He*, N 2 + and O*). These distribution patterns are useful to study the chemistry of the discharge plasma, since different production pathways and different excitation energies affect the presence of these species in the plasma regions. - Highlights: ► An in-house APGD is characterized through electrical and OES measurements. ► Interelectrode distance had more effect on electric regime than He flow rate. ► Internal plume images showed differences on the production pathways for each species. ► Higher interelectrode distances and He flow rates showed better afterglow conditions.

  20. Bidimensional characterization of the emission spectra in a direct current atmospheric pressure glow discharge

    Energy Technology Data Exchange (ETDEWEB)

    Orejas, Jaime [University of Oviedo, Department of Physics, C/ Gonzazlez Quiros S/N, Mieres (Spain); Pisonero, Jorge, E-mail: pisonerojorge@uniovi.es [University of Oviedo, Department of Physics, C/ Gonzazlez Quiros S/N, Mieres (Spain); Bordel, Nerea [University of Oviedo, Department of Physics, C/ Gonzazlez Quiros S/N, Mieres (Spain); Nelis, Thomas [Bern University of Applied Sciences, Quellgasse 21, 2501 Bienne (Switzerland); Guillot, Philippe [DPHE, CUFR J. F. Champollion, Universite de Toulouse, Place de Verdun, Albi (France); Sanz-Medel, Alfredo, E-mail: asm@uniovi.es [University of Oviedo, Department of Physical and Analytical Chemistry, C/ Julian Claveria 8, Oviedo (Spain)

    2012-10-15

    An in-house atmospheric pressure glow discharge source, designed to be used as ionization/desorption source for ambient mass spectrometry, has been electrically characterized, and its optical emission spectra evaluated in detail. Electrical characterization showed that the plasma regime can vary from glow discharge to arc discharge depending on operating conditions (i.e. He flow rate and inter electrode distance). Furthermore, bidimensional images of the optical emission of some plasma species using filters as wavelength selectors, were registered from inside and outside the discharge chamber (inner region and afterglow region respectively), showing the spatial distribution of excited species (i.e. He*, N{sub 2}{sup +} and O*). These distribution patterns are useful to study the chemistry of the discharge plasma, since different production pathways and different excitation energies affect the presence of these species in the plasma regions. - Highlights: Black-Right-Pointing-Pointer An in-house APGD is characterized through electrical and OES measurements. Black-Right-Pointing-Pointer Interelectrode distance had more effect on electric regime than He flow rate. Black-Right-Pointing-Pointer Internal plume images showed differences on the production pathways for each species. Black-Right-Pointing-Pointer Higher interelectrode distances and He flow rates showed better afterglow conditions.

  1. Carbon dioxide reforming of methane by atmospheric pressure pulsed glow discharge: The effect of pulse compression

    International Nuclear Information System (INIS)

    Ghorbanzadeh, A.; Modarresi, H.

    2006-01-01

    Methane reforming by carbon dioxide in atmospheric pressure pulsed glow discharge was examined. The pulse duration of plasma was compressed to ∼50 ns or lower. This compression allowed working at higher frequencies, more than 3 k Hz, without glow to arc transition. The main outlet gases were synthetic gases (H 2 , CO) and C 2 (ethylene, ethane, and acetylene) products. At equal reactants proportion CO 2 /CH 4 =1, about 42 p ercent o f plasma energy went to chemical dissociation while reactant conversions were relatively high, i.e. near 55 p ercent % (CH 4 ) and 42 p ercent ( CO 2 ). At this point, the energy expenditure was less than 3.8 eV per each converted molecule. The reactor energy performance even gets better at higher CO 2 /CH 4 proportions. At CO 2 /CH 4 =5, The conversions of about 65 p ercent a nd 45 p ercent w ere obtained for methane and carbon dioxide respectively, while energy efficiency reached near 45 p ercent . It is discussed that high nonequilibrium state of vibrational energy at short pulses, especially in carbon dioxide, leads to this improvement.

  2. Microelectrode-assisted low-voltage atmospheric pressure glow discharge in air

    Science.gov (United States)

    Liu, Wenzheng; Zhao, Shuai; Niu, Jiangqi; Chai, Maolin

    2017-09-01

    During the process of discharge, appropriately changing the paths corresponding to electric field lines and the field strength distribution along these paths, as well as increasing the number of initial electrons, can effectively enhance the uniformity of discharge and inhibit the formation of filamentary discharge. A method is proposed that uses a microelectrode to initiate the macroscopic discharge phenomenon. An asymmetric structure was designed comprising a single electrode of carbon fiber; this electrode structure is of helical-contact type. Benefitting from the special electric field distribution and the microdischarge process, a three-dimensional atmospheric pressure glow discharge was achieved in air, characterized by low discharge voltage, low energy consumption, good diffusion performance, and less ozone generation. The plasma studied is uniform and stable with good diffusion characteristics and low levels of contaminants and hence has potential applications in the field of air purification.

  3. Surface modification of polyimide (PI) film using water cathode atmospheric pressure glow discharge plasma

    International Nuclear Information System (INIS)

    Zheng Peichao; Liu Keming; Wang Jinmei; Dai Yu; Yu Bin; Zhou Xianju; Hao Honggang; Luo Yuan

    2012-01-01

    Highlights: ► Equipment called water cathode atmospheric pressure glow discharge was used to improve the hydrophilicity of polyimide films. ► The data shows good homogeneity and the variation trends of contact angles are different for polar and non-polar testing liquids. ► The thickness of liquid layer plays an important role in plasma processing and directly affects the treatment effect. ► Surface hydrophilicity after plasma treatment is improved partly due to the increase in the roughness. ► The hydrophilicity of polyimide films is still better than untreated ones after long-term storage. - Abstract: The industrial use of polyimide film is limited because of undesirable properties such as poor wettability. In the present paper, a new kind of equipment called water cathode atmospheric pressure glow discharge was used to improve the surface properties of polyimide films and made them useful to technical applications. The changes in hydrophilicity of modified polyimide film surfaces were investigated by contact angle, surface energy and water content measurements as a function of treatment time. The results obtained show good treatment homogeneity and that the variation trends of contact angles are different for polar and non-polar testing liquids, while surface energy and water content are significantly enhanced with the increase of treatment time until they achieve saturated values after 60 s plasma treatment. Also, the thickness of liquid layer plays an important role in plasma processing and directly affects the treatment effect. Changes in morphology of polyimide films were analyzed by atomic force microscope and the results indicate that surface hydrophilicity after plasma treatment are improved partly due to the increase in the roughness. In addition, polyimide films treated by plasma are subjected to an ageing process to determine the durability of plasma treatment. It is found that the hydrophilicity is still better than untreated ones though the

  4. Surface treatment of polyethylene terephthalate film using atmospheric pressure glow discharge in air

    International Nuclear Information System (INIS)

    Fang Zhi; Qiu Yuchang; Wang Hui

    2004-01-01

    Non-thermal plasmas under atmospheric pressure are of great interest in polymer surface processing because of their convenience, effectiveness and low cost. In this paper, the treatment of Polyethylene terephthalate (PET) film surface for improving hydrophilicity using the non-thermal plasma generated by atmospheric pressure glow discharge (APGD) in air is conducted. The discharge characteristics of APGD are shown by measurement of their electrical discharge parameters and observation of light-emission phenomena, and the surface properties of PET before and after the APGD treatment are studied using contact angle measurement, x-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). It is found that the APGD is homogeneous and stable in the whole gas gap, which differs from the commonly filamentary dielectric barrier discharge (DBD). A short time (several seconds) APGD treatment can modify the surface characteristics of PET film markedly and uniformly. After 10 s APGD treatment, the surface oxygen content of PET surface increases to 39%, and the water contact angle decreases to 19 degree, respectively. (authors)

  5. Transitions between corona, glow, and spark regimes of nanosecond repetitively pulsed discharges in air at atmospheric pressure

    Science.gov (United States)

    Pai, David Z.; Lacoste, Deanna A.; Laux, Christophe O.

    2010-05-01

    In atmospheric pressure air preheated from 300 to 1000 K, the nanosecond repetitively pulsed (NRP) method has been used to generate corona, glow, and spark discharges. Experiments have been performed to determine the parameter space (applied voltage, pulse repetition frequency, ambient gas temperature, and interelectrode gap distance) of each discharge regime. In particular, the experimental conditions necessary for the glow regime of NRP discharges have been determined, with the notable result that there exists a minimum and maximum gap distance for its existence at a given ambient gas temperature. The minimum gap distance increases with decreasing gas temperature, whereas the maximum does not vary appreciably. To explain the experimental results, an analytical model is developed to explain the corona-to-glow (C-G) and glow-to-spark (G-S) transitions. The C-G transition is analyzed in terms of the avalanche-to-streamer transition and the breakdown field during the conduction phase following the establishment of a conducting channel across the discharge gap. The G-S transition is determined by the thermal ionization instability, and we show analytically that this transition occurs at a certain reduced electric field for the NRP discharges studied here. This model shows that the electrode geometry plays an important role in the existence of the NRP glow regime at a given gas temperature. We derive a criterion for the existence of the NRP glow regime as a function of the ambient gas temperature, pulse repetition frequency, electrode radius of curvature, and interelectrode gap distance.

  6. Liquid sampling-atmospheric pressure glow discharge as a secondary excitation source: Assessment of plasma characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Manard, Benjamin T. [Department of Chemistry, Clemson University, Clemson, SC 29634 (United States); Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Gonzalez, Jhanis J. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Sarkar, Arnab [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Fuel Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Dong, Meirong; Chirinos, Jose; Mao, Xianglei; Russo, Richard E. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Marcus, R. Kenneth [Department of Chemistry, Clemson University, Clemson, SC 29634 (United States)

    2014-04-01

    The liquid sampling-atmospheric pressure glow discharge (LS-APGD) has been assessed as a secondary excitation source with a parametric evaluation regarding carrier gas flow rate, applied current, and electrode distance. With this parametric evaluation, plasma optical emission was monitored in order to obtain a fundamental understanding with regards to rotational temperature (T{sub rot}), excitation temperature (T{sub exc}), electron number density (n{sub e}), and plasma robustness. Incentive for these studies is not only for a greater overall fundamental knowledge of the APGD, but also in instrumenting a secondary excitation/ionization source following laser ablation (LA). Rotational temperatures were determined through experimentally fitting of the N{sub 2} and OH molecular emission bands while atomic excitation temperatures were calculated using a Boltzmann distribution of He and Mg atomic lines. The rotational and excitation temperatures were determined to be ∼ 1000 K and ∼ 2700 K respectively. Electron number density was calculated to be on the order of ∼ 3 × 10{sup 15} cm{sup −3} utilizing Stark broadening effects of the Hα line of the Balmer series and a He I transition. In addition, those diagnostics were performed introducing magnesium (by solution feed and laser ablation) into the plasma in order to determine any perturbation under heavy matrix sampling. The so-called plasma robustness factor, derived by monitoring Mg II/Mg I emission ratios, is also employed as a reflection of potential perturbations in microplasma energetics across the various operation conditions and sample loadings. While truly a miniaturized source (< 1 mm{sup 3} volume), the LS-APGD is shown to be quite robust with plasma characteristics and temperatures being unaffected upon introduction of metal species, whether by liquid or laser ablation sample introduction. - Highlights: • Liquid sampling-atmospheric pressure glow discharge (LS-APGD) • LS-APGD as a secondary

  7. Liquid sampling-atmospheric pressure glow discharge as a secondary excitation source: Assessment of plasma characteristics

    International Nuclear Information System (INIS)

    Manard, Benjamin T.; Gonzalez, Jhanis J.; Sarkar, Arnab; Dong, Meirong; Chirinos, Jose; Mao, Xianglei; Russo, Richard E.; Marcus, R. Kenneth

    2014-01-01

    The liquid sampling-atmospheric pressure glow discharge (LS-APGD) has been assessed as a secondary excitation source with a parametric evaluation regarding carrier gas flow rate, applied current, and electrode distance. With this parametric evaluation, plasma optical emission was monitored in order to obtain a fundamental understanding with regards to rotational temperature (T rot ), excitation temperature (T exc ), electron number density (n e ), and plasma robustness. Incentive for these studies is not only for a greater overall fundamental knowledge of the APGD, but also in instrumenting a secondary excitation/ionization source following laser ablation (LA). Rotational temperatures were determined through experimentally fitting of the N 2 and OH molecular emission bands while atomic excitation temperatures were calculated using a Boltzmann distribution of He and Mg atomic lines. The rotational and excitation temperatures were determined to be ∼ 1000 K and ∼ 2700 K respectively. Electron number density was calculated to be on the order of ∼ 3 × 10 15 cm −3 utilizing Stark broadening effects of the Hα line of the Balmer series and a He I transition. In addition, those diagnostics were performed introducing magnesium (by solution feed and laser ablation) into the plasma in order to determine any perturbation under heavy matrix sampling. The so-called plasma robustness factor, derived by monitoring Mg II/Mg I emission ratios, is also employed as a reflection of potential perturbations in microplasma energetics across the various operation conditions and sample loadings. While truly a miniaturized source ( 3 volume), the LS-APGD is shown to be quite robust with plasma characteristics and temperatures being unaffected upon introduction of metal species, whether by liquid or laser ablation sample introduction. - Highlights: • Liquid sampling-atmospheric pressure glow discharge (LS-APGD) • LS-APGD as a secondary excitation source for laser-ablated (LA

  8. Studies on gas breakdown in pulsed radio frequency atmospheric pressure glow discharges

    International Nuclear Information System (INIS)

    Huo, W. G.; Jian, S. J.; Yao, J.; Ding, Z. F.

    2014-01-01

    In pulsed RF atmospheric pressure glow discharges, the gas breakdown judged by the rapid drop in the amplitude of the pulsed RF voltage is no longer universally true. The steep increment of the plasma-absorbed RF power is proposed to determine the gas breakdown. The averaged plasma-absorbed RF power over a pulse period is used to evaluate effects of the preceding pulsed RF discharge on the breakdown voltage of the following one, finding that the breakdown voltage decreases with the increment in the averaged plasma-absorbed RF power under constant pulse duty ratio. Effects of the pulse off-time on the breakdown voltage and the breakdown delay time are also studied. The obtained dependence of the breakdown voltage on the pulse off-time is indicative of the transitional plasma diffusion processes in the afterglow. The breakdown voltage varies rapidly as the plasma diffuses fast in the region of moderate pulse off-time. The contribution of nitrogen atom recombination at the alumina surface is demonstrated in the prolonged memory effect on the breakdown delay time vs. the pulse off-time and experimentally validated by introducing a trace amount of nitrogen into argon at short and long pulse off-times

  9. Anode spot patterns and fluctuations in an atmospheric-pressure glow discharge in helium

    International Nuclear Information System (INIS)

    Arkhipenko, V I; Safronau, Y A; Simonchik, L V; Tsuprik, I M; Callegari, Th

    2013-01-01

    Oscillations of the main parameters (voltage on electrodes, potential, light intensity and discharge current) in a dc atmospheric-pressure glow discharge in helium are investigated in a range of currents from milliamperes to several amperes. It is established that these oscillations are connected with the existence of anode spots. In the case of a single spot, fluctuations of discharge light intensity are observed when the supply voltage exceeds the breakdown voltage for the interelectrode gap. At the same time, voltage fluctuations have the form of relaxation oscillations with a frequency that depends on the electrical parameters of the external circuit. With an increase in discharge gap and current, the number of spots increases. They form a stable structure, and the fluctuations of current and voltage stay harmonic. The brightness of the spots seems to be determined by the frequency of their blinking. The amplitude of current fluctuation increases with the increase in discharge current and can be up to 15% of its average value. The frequency of current oscillations, which is about 0.75 MHz at a current of 0.5 A, depends weakly on the discharge gap (it varies within ±10% for the gap interval from 1 to 10 mm). The oscillation frequency is maximal (about 0.85 MHz) at a current of about 0.4 A. At higher currents (2–4 A, depending on the discharge gap), the fluctuations disappear when a contraction of the anode region into one anode spot occurs. (paper)

  10. Cell treatment and surface functionalization using a miniature atmospheric pressure glow discharge plasma torch

    International Nuclear Information System (INIS)

    Yonson, S; Coulombe, S; Leveille, V; Leask, R L

    2006-01-01

    A miniature atmospheric pressure glow discharge plasma torch was used to detach cells from a polystyrene Petri dish. The detached cells were successfully transplanted to a second dish and a proliferation assay showed the transplanted cells continued to grow. Propidium iodide diffused into the cells, suggesting that the cell membrane had been permeabilized, yet the cells remained viable 24 h after treatment. In separate experiments, hydrophobic, bacteriological grade polystyrene Petri dishes were functionalized. The plasma treatment reduced the contact angle from 93 0 to 35 0 , and promoted cell adhesion. Two different torch nozzles, 500 μm and 150 μm in internal diameter, were used in the surface functionalization experiments. The width of the tracks functionalized by the torch, as visualized by cell adhesion, was approximately twice the inside diameter of the nozzle. These results indicate that the miniature plasma torch could be used in biological micropatterning, as it does not use chemicals like the present photolithographic techniques. Due to its small size and manouvrability, the torch also has the ability to pattern complex 3D surfaces

  11. Liquid sampling-atmospheric pressure glow discharge as a secondary excitation source: Assessment of plasma characteristics

    Science.gov (United States)

    Manard, Benjamin T.; Gonzalez, Jhanis J.; Sarkar, Arnab; Dong, Meirong; Chirinos, Jose; Mao, Xianglei; Russo, Richard E.; Marcus, R. Kenneth

    The liquid sampling-atmospheric pressure glow discharge (LS-APGD) has been assessed as a secondary excitation source with a parametric evaluation regarding carrier gas flow rate, applied current, and electrode distance. With this parametric evaluation, plasma optical emission was monitored in order to obtain a fundamental understanding with regards to rotational temperature (Trot), excitation temperature (Texc), electron number density (ne), and plasma robustness. Incentive for these studies is not only for a greater overall fundamental knowledge of the APGD, but also in instrumenting a secondary excitation/ionization source following laser ablation (LA). Rotational temperatures were determined through experimentally fitting of the N2 and OH molecular emission bands while atomic excitation temperatures were calculated using a Boltzmann distribution of He and Mg atomic lines. The rotational and excitation temperatures were determined to be ~ 1000 K and ~ 2700 K respectively. Electron number density was calculated to be on the order of ~ 3 × 1015 cm- 3 utilizing Stark broadening effects of the Hα line of the Balmer series and a He I transition. In addition, those diagnostics were performed introducing magnesium (by solution feed and laser ablation) into the plasma in order to determine any perturbation under heavy matrix sampling. The so-called plasma robustness factor, derived by monitoring Mg II/Mg I emission ratios, is also employed as a reflection of potential perturbations in microplasma energetics across the various operation conditions and sample loadings. While truly a miniaturized source (laser ablation sample introduction.

  12. CO2 Reforming of CH4 by Atmospheric Pressure Abnormal Glow Plasma

    International Nuclear Information System (INIS)

    Chen Qi; Dai Wei; Tao Xumei; Yu Hui; Dai Xiaoyan; Yin Yongxiang

    2006-01-01

    A novel plasma atmospheric pressure abnormal glow discharge was used to investigate synthesis gas production from reforming methane and carbon dioxide. Special attentions were paid to the discharge characteristics and CH 4 , CO 2 conversion, H 2 , CO selectivity, and ratio of H 2 /CO varied with the changing of discharging power, the total flux, and the ratio of CH 4 /CO 2 . Experiments were performed in wider operation variables, the discharging power of 240 to 600 W, the CH 4 /CO 2 of 0.2 to 1.0 and the total flux of 140 to 500 mL/min. The experiments showed that the conversion of CH 4 and CO 2 was up to 91.9% and 83.2%, the selectivity of CO and H 2 was also up to 80% and 90% and H 2 /CO mole ratio was 0.2 to 1.2, respectively. A brief analysis for discharge characteristics and the experimental results were given

  13. On the physical processes ruling an atmospheric pressure air glow discharge operating in an intermediate current regime

    International Nuclear Information System (INIS)

    Prevosto, L.; Mancinelli, B.; Chamorro, J. C.; Cejas, E.; Kelly, H.

    2015-01-01

    Low-frequency (100 Hz), intermediate-current (50 to 200 mA) glow discharges were experimentally investigated in atmospheric pressure air between blunt copper electrodes. Voltage–current characteristics and images of the discharge for different inter-electrode distances are reported. A cathode-fall voltage close to 360 V and a current density at the cathode surface of about 11 A/cm 2 , both independent of the discharge current, were found. The visible emissive structure of the discharge resembles to that of a typical low-pressure glow, thus suggesting a glow-like electric field distribution in the discharge. A kinetic model for the discharge ionization processes is also presented with the aim of identifying the main physical processes ruling the discharge behavior. The numerical results indicate the presence of a non-equilibrium plasma with rather high gas temperature (above 4000 K) leading to the production of components such as NO, O, and N which are usually absent in low-current glows. Hence, the ionization by electron-impact is replaced by associative ionization, which is independent of the reduced electric field. This leads to a negative current-voltage characteristic curve, in spite of the glow-like features of the discharge. On the other hand, several estimations show that the discharge seems to be stabilized by heat conduction; being thermally stable due to its reduced size. All the quoted results indicate that although this discharge regime might be considered to be close to an arc, it is still a glow discharge as demonstrated by its overall properties, supported also by the presence of thermal non-equilibrium

  14. Contrasting characteristics of sub-microsecond pulsed atmospheric air and atmospheric pressure helium-oxygen glow discharges

    International Nuclear Information System (INIS)

    Walsh, J L; Liu, D X; Iza, F; Kong, M G; Rong, M Z

    2010-01-01

    Glow discharges in air are often considered to be the ultimate low-temperature atmospheric pressure plasmas for numerous chamber-free applications. This is due to the ubiquitous presence of air and the perceived abundance of reactive oxygen and nitrogen species in air plasmas. In this paper, sub-microsecond pulsed atmospheric air plasmas are shown to produce a low concentration of excited oxygen atoms but an abundance of excited nitrogen species, UV photons and ozone molecules. This contrasts sharply with the efficient production of excited oxygen atoms in comparable helium-oxygen discharges. Relevant reaction chemistry analysed with a global model suggests that collisional excitation of O 2 by helium metastables is significantly more efficient than electron dissociative excitation of O 2 , electron excitation of O and ion-ion recombination. These results suggest different practical uses of the two oxygen-containing atmospheric discharges, with air plasmas being well suited for nitrogen and UV based chemistry and He-O 2 plasmas for excited atomic oxygen based chemistry. (fast track communication)

  15. FAST TRACK COMMUNICATION: Contrasting characteristics of sub-microsecond pulsed atmospheric air and atmospheric pressure helium-oxygen glow discharges

    Science.gov (United States)

    Walsh, J. L.; Liu, D. X.; Iza, F.; Rong, M. Z.; Kong, M. G.

    2010-01-01

    Glow discharges in air are often considered to be the ultimate low-temperature atmospheric pressure plasmas for numerous chamber-free applications. This is due to the ubiquitous presence of air and the perceived abundance of reactive oxygen and nitrogen species in air plasmas. In this paper, sub-microsecond pulsed atmospheric air plasmas are shown to produce a low concentration of excited oxygen atoms but an abundance of excited nitrogen species, UV photons and ozone molecules. This contrasts sharply with the efficient production of excited oxygen atoms in comparable helium-oxygen discharges. Relevant reaction chemistry analysed with a global model suggests that collisional excitation of O2 by helium metastables is significantly more efficient than electron dissociative excitation of O2, electron excitation of O and ion-ion recombination. These results suggest different practical uses of the two oxygen-containing atmospheric discharges, with air plasmas being well suited for nitrogen and UV based chemistry and He-O2 plasmas for excited atomic oxygen based chemistry.

  16. Protein destruction by a helium atmospheric pressure glow discharge: Capability and mechanisms

    International Nuclear Information System (INIS)

    Deng, X. T.; Shi, J. J.; Kong, M. G.

    2007-01-01

    Biological sterilization represents one of the most exciting applications of atmospheric pressure glow discharges (APGD). Despite the fact that surgical instruments are contaminated by both microorganisms and proteinaceous matters, sterilization effects of APGD have so far been studied almost exclusively for microbial inactivation. This work presents the results of a detailed investigation of the capability of a helium-oxygen APGD to inactivate proteins deposited on stainless-steel surfaces. Using a laser-induced fluorescence technique for surface protein measurement, a maximum protein reduction of 4.5 logs is achieved by varying the amount of the oxygen admixture into the background helium gas. This corresponds to a minimum surface protein of 0.36 femtomole/mm 2 . It is found that plasma reduction of surface-borne protein is through protein destruction and degradation, and that its typically biphasic reduction kinetics is influenced largely by the thickness profile of the surface protein. Also presented is a complementary study of possible APGD protein inactivation mechanisms. By interplaying the protein inactivation kinetics with optical emission spectroscopy, it is shown that the main protein-destructing agents are excited atomic oxygen (via the 777 and 844 nm emission channels) and excited nitride oxide (via the 226, 236, and 246 nm emission channels). It is also demonstrated that the most effective protein reduction is achieved possibly through a synergistic effect between atomic oxygen and nitride oxide. This study is a useful step toward a full confirmation of the efficacy of APGD as a sterilization technology for surgical instruments contaminated by prion proteins

  17. Effects of easily ionizable elements on the liquid sampling-atmospheric pressure glow discharge

    International Nuclear Information System (INIS)

    Venzie, Jacob L.; Marcus, R. Kenneth

    2006-01-01

    A series of studies has been undertaken to determine the susceptibility of the liquid sampling-atmospheric pressure glow discharge (LS-APGD) atomic emission source to easily ionizable element (EIE) effects. The initial portions of the study involved monitoring the voltage drop across the plasma as a function of the pH to ascertain whether or not the conductivity of the liquid eluent alters the plasma energetics and subsequently the analyte signal strength. It was found that altering the pH (0.0 to 2.0) in the sample matrix did not significantly change the discharge voltage. The emission signal intensities for Cu(I) 327.4 nm, Mo(I) 344.7 nm, Sc(I) 326.9 nm and Hg(I) 253.6 nm were measured as a function of the easily ionizable element (sodium and calcium) concentration in the injection matrix. A range of 0.0 to 0.1% (w/v) EIE in the sample matrix did not cause a significant change in the Cu, Sc, and Mo signal-to-background ratios, with only a slight change noted for Hg. In addition to this test of analyte response, the plasma energetics as a function of EIE concentration are assessed using the ratio of Mg(II) to Mg(I) (280.2 nm and 285.2 nm, respectively) intensities. The Mg(II)/Mg(I) ratio showed that the plasma energetics did not change significantly over the same range of EIE addition. These results are best explained by the electrolytic nature of the eluent acting as an ionic (and perhaps spectrochemical) buffer

  18. Final Report DE-FG02-00ER54583: 'Physics of Atmospheric Pressure Glow Discharges' and 'Nanoparticle Nucleation and Dynamics in Low-Pressure Plasmas'

    International Nuclear Information System (INIS)

    Kortshagen, Uwe; Heberlein, Joachim; Girshick, Steven L.

    2009-01-01

    This project was funded over two periods of three years each, with an additional year of no-cost extension. Research in the first funding period focused on the physics of uniform atmospheric pressure glow discharges, the second funding period was devoted to the study of the dynamics of nanometer-sized particles in plasmas.

  19. DC negative corona discharge in atmospheric pressure helium: transition from the corona to the ‘normal’ glow regime

    International Nuclear Information System (INIS)

    Hasan, Nusair; Farouk, Bakhtier; Antao, Dion S

    2014-01-01

    Direct current (dc) negative corona discharges in atmospheric pressure helium are simulated via detailed numerical modeling. Simulations are conducted to characterize the discharges in atmospheric helium for a pin plate electrode configuration. A self-consistent two-dimensional hybrid model is developed to simulate the discharges and the model predictions are validated with experimental measurements. The discharge model considered consists of momentum and energy conservation equations for a multi-component (electrons, ions, excited species and neutrals) gas mixture, conservation equations for each component of the mixture and state relations. A drift–diffusion approximation for the electron and the ion fluxes is used. A model for the external circuit driving the discharge is also considered and solved along with the discharge model. Many of the key features of a negative corona discharge, namely non-linear current–voltage characteristics, spatially flat cathode current density and glow-like discharge in the high current regime are displayed in the predictions. A transition to the ‘normal’ glow discharge from the corona discharge regime is also observed. The transition is identified from the calculated current–voltage characteristic curve and is characterized by the radial growth of the negative glow and the engulfment of the cathode wire. (paper)

  20. Study of surface atmospheric pressure glow discharge plasma based on ultrathin laminated electrodes in air

    Science.gov (United States)

    Zhao, Luxiang; Liu, Wenzheng; Li, Zhiyi; Ma, Chuanlong

    2018-05-01

    A method to generate large-area surface plasma in air by micro-discharge is proposed. Two ultrathin laminated electrode structures of non-insulating and insulating types were formed by using the nanoscale ITO conductive layer. The surface glow discharge in atmospheric air is realized in low discharge voltage by constructing the special electric field of two-dimensional unidirectional attenuation. In particular, the insulating electrode structure can avoid the loss of ITO electrodes so that the discharge stability can be increased, and the treated objects can be prevented from metal ion pollution caused by the electrode in the discharge. It has broad application prospects in the fields of aerodynamics and material surface treatment.

  1. Spatially Resolved Gas Temperature Measurements in an Atmospheric Pressure DC Glow Microdischarge with Raman Scattering

    Science.gov (United States)

    Belostotskiy, S.; Wang, Q.; Donnelly, V.; Economou, D.; Sadeghi, N.

    2006-10-01

    Spatially resolved rotational Raman spectroscopy of ground state nitrogen N2(X^1σg^+) was used to measure the gas temperature (Tg) in a nitrogen dc glow microdischarge (gap between electrodes d˜500 μm). An original backscattering, confocal optical system was developed for collecting Raman spectra. Stray laser light and Raleigh scattering were blocked by using a triple grating monochromator and spatial filters, designed specifically for these experiments. The optical system provided a spatial resolution of electrodes, Tg increased linearly with jd, reaching 500 K at 1000 mA/cm^2 jd for a pressure of 720 Torr. Spatially resolved gas temperature measurements will also be presented and discussed in combination with a mathematical model for gas heating in the microplasma. This work is supported by DoE/NSF.

  2. Characteristics of an atmospheric pressure argon glow discharge in a coaxial electrode geometry

    International Nuclear Information System (INIS)

    Li Xuechen; Zhao Na; Fang Tongzhen; Liu Zhihui; Li Lichun; Dong Lifang

    2008-01-01

    An atmospheric glow discharge controlled by a dielectric barrier is realized in a coaxial electrode geometry in argon. The discharge characteristics are studied by the electrical method and optical emission spectroscopy. The experimental results indicate that there is only one discharge pulse per half cycle when the applied voltage is very low, and the rise time of the discharge pulses at the positive half cycle is much shorter than that at the negative one. With an increase in applied voltage, the width of the discharge pulse increases, while the inception voltage at which breakdown occurs decreases. The rise time at positive half cycle almost equals that at negative half cycle when the applied voltage is high enough. The research results pertaining to gas gap voltage indicate that the critical electric field for breakdown decreases with increasing applied voltage. The electron temperature is estimated from the Einstein relation, and the result indicates that the electron temperature and the electron density are functions of the applied voltage and the gas flow rate. The electron temperature is also studied by emission spectroscopy and a similar result is obtained

  3. Simulation of convection-stabilized low-current glow and arc discharges in atmospheric-pressure air

    International Nuclear Information System (INIS)

    Naidis, G V

    2007-01-01

    A two-dimensional model of stationary convection-stabilized low-current glow and arc discharge columns in atmospheric-pressure air is developed which accounts for deviation of the plasma state from the local thermodynamic equilibrium (LTE). In addition to equations of energy, continuity and momentum (analogous to those used in LTE arc models), the non-LTE model includes balance equations for plasma species and for the vibrational energy of nitrogen molecules. The kinetic scheme is used which was developed recently for the simulation of low-current wall-stabilized discharges in air. Results of calculation of discharge parameters over a wide current range are presented. It is shown that the non-equilibrium effects are substantial at currents lower than ∼ 100 mA. The calculated plasma parameters agree with available experimental data

  4. Peculiarities of glow modes of argon atmospheric pressure radio-frequency capacitive discharge with isolated electrodes

    International Nuclear Information System (INIS)

    Bazhenov, V.Yu.; Tsiolko, V.V.; Piun, V.M.; Chaplinskiy, R.Yu.; Kuzmichev, A.I.

    2013-01-01

    Glow characteristics of capacitive radio frequency discharge with isolated electrodes in low-current α and highcurrent gamma modes are determined experimentally. It is shown that transition from α mode to gamma mode occurs through a phase of coexistence of both modes in different parts of the discharge gap.

  5. Study of a new direct current atmospheric pressure glow discharge in helium

    Energy Technology Data Exchange (ETDEWEB)

    Gielniak, B. [University of Hamburg, Institute for Inorganic and Applied Chemistry, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany); Fiedler, T. [Johannes Gutenberg-University Mainz, Institute for Inorganic and Analytical Chemistry, Duesbergweg 10-14, 55128 Mainz (Germany); Broekaert, J.A.C., E-mail: jose.broekaert@chemie.uni-hamburg.de [University of Hamburg, Institute for Inorganic and Applied Chemistry, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany)

    2011-01-15

    In this study a new DC-APGD operated in He was developed and characterized. The discharge is operated at 0.9 kV and about 25-35 mA and at a gas flow of 100 ml/min. The source was spectroscopically studied and parameters such as the rotational temperature (T{sub rot}), the excitation temperature (T{sub exc}), the ionization temperature (T{sub ion}) and the electron number density (n{sub e}) were determined. The current-voltage characteristic of the source was studied as well. At optimized conditions the discharge operates in the normal region of the current-voltage characteristic. Rotational and excitation temperatures determined with the use of OH band and Fe I lines as thermometric species were of the order of about 900-1200 and 4500-5500 K, respectively. This indicates that despite of the atmospheric pressure, the discharge is not in LTE. Spatially resolved temperature measurements were performed with axial as well as radial resolution and showed relatively flat profiles. Axially resolved emission intensity profiles for several species such as H, N{sub 2}, N{sub 2}{sup +}, OH, He and Hg were determined. It also was found that H{sub 2} introduced into the He by electrolysis of acid solutions such as in ECHG considerably increases the spectroscopically measured gas temperatures but decreases the analyte line intensities, as shown for Hg.

  6. Study of a new direct current atmospheric pressure glow discharge in helium

    International Nuclear Information System (INIS)

    Gielniak, B.; Fiedler, T.; Broekaert, J.A.C.

    2011-01-01

    In this study a new DC-APGD operated in He was developed and characterized. The discharge is operated at 0.9 kV and about 25-35 mA and at a gas flow of 100 ml/min. The source was spectroscopically studied and parameters such as the rotational temperature (T rot ), the excitation temperature (T exc ), the ionization temperature (T ion ) and the electron number density (n e ) were determined. The current-voltage characteristic of the source was studied as well. At optimized conditions the discharge operates in the normal region of the current-voltage characteristic. Rotational and excitation temperatures determined with the use of OH band and Fe I lines as thermometric species were of the order of about 900-1200 and 4500-5500 K, respectively. This indicates that despite of the atmospheric pressure, the discharge is not in LTE. Spatially resolved temperature measurements were performed with axial as well as radial resolution and showed relatively flat profiles. Axially resolved emission intensity profiles for several species such as H, N 2 , N 2 + , OH, He and Hg were determined. It also was found that H 2 introduced into the He by electrolysis of acid solutions such as in ECHG considerably increases the spectroscopically measured gas temperatures but decreases the analyte line intensities, as shown for Hg.

  7. A diffusive atmospheric pressure glow discharge in a coaxial pin-to-ring gap with a transverse magnetic field

    Directory of Open Access Journals (Sweden)

    YongSheng Wang

    2017-09-01

    Full Text Available Atmospheric pressure glow discharge (APGD has been widely used in the industrial field. The industrial applications are based on achieving stable and diffusive APGD in a relatively large space. The existing sources only achieved stable and diffusive APGD between a short inter-electrode distance within 5 millimeters. In this paper, the effect of a transverse stationary magnetic field on the diffusion of filamentary APGD was studied in a pin-to-ring coaxial gap. The APGD was driven by a high-voltage resonant power supply, and the stationary magnetic field was supplied by a permanent magnet. The stable and diffusive APGD was achieved in the circular area, which diameter was 20 millimeters. The experimental results revealed that more collision ionization occurred and the plasma was distributed diffusively in the discharge gap by applying the external transverse magnetic field. Besides, it is likely to obtain more stable and diffusive APGD in the coaxial pin-to-ring discharge gap when adjusting the input voltage, transverse magnetic flux density and resonant frequency of the power supply.

  8. Modification of hydrophobic acrylic intraocular lens with poly(ethylene glycol) by atmospheric pressure glow discharge: A facile approach

    International Nuclear Information System (INIS)

    Lin Lin; Wang Yao; Huang Xiaodan; Xu Zhikang; Yao Ke

    2010-01-01

    To improve the anterior surface biocompatibility of hydrophobic acrylic intraocular lens (IOL) in a convenient and continuous way, poly(ethylene glycol)s (PEGs) were immobilized by atmospheric pressure glow discharge (APGD) treatment using argon as the discharge gas. The hydrophilicity and chemical changes on the IOL surface were characterized by static water contact angle and X-ray photoelectron spectroscopy to confirm the covalent binding of PEG. The morphology of the IOL surface was observed under field emission scanning electron microscopy and atomic force microscopy. The surface biocompatibility was evaluated by adhesion experiments with platelets, macrophages, and lens epithelial cells (LECs) in vitro. The results revealed that the anterior surface of the PEG-grafted IOL displayed significantly and permanently improved hydrophilicity. Cell repellency was observed, especially in the PEG-modified IOL group, which resisted the attachment of platelets, macrophages and LECs. Moreover, the spread and growth of cells were suppressed, which may be attributed to the steric stabilization force and chain mobility effect of the modified PEG. All of these results indicated that hydrophobic acrylic IOLs can be hydrophilic modified by PEG through APGD treatment in a convenient and continuous manner which will provide advantages for further industrial applications.

  9. Atmospheric-pressure solution-cathode glow discharge: A versatile ion source for atomic and molecular mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Schwartz, Andrew J. [Department of Chemistry, Indiana University, Bloomington, IN, 47405 (United States); Williams, Kelsey L. [Department of Chemistry and Biochemistry, Kent State University, Kent, OH, 44242 (United States); Hieftje, Gary M. [Department of Chemistry, Indiana University, Bloomington, IN, 47405 (United States); Shelley, Jacob T., E-mail: shellj@rpi.edu [Department of Chemistry and Biochemistry, Kent State University, Kent, OH, 44242 (United States); Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY, 12180 (United States)

    2017-01-15

    An atmospheric-pressure solution-cathode glow discharge (SCGD) has been evaluated as an ion source for atomic, molecular, and ambient desorption/ionization mass spectrometry. The SCGD consists of a direct-current plasma, supported in the ambient air in the absence of gas flows, and sustained upon the surface of a flowing liquid cathode. Analytes introduced in the flowing liquid, as an ambient gas, or as a solid held near the plasma are vaporized and ionized by interactions within or near the discharge. Introduction of acidic solutions containing metal salts produced bare elemental ions as well as H{sub 2}O, OH{sup −} and NO{sub 3}{sup −} adducts. Detection limits for these elemental species ranged from 0.1 to 4 ppb, working curves spanned more than 4 orders of linear dynamic range, and precision varied between 5 and 16% relative standard deviation. Small organic molecules were also efficiently ionized from solution, and both the intact molecular ion and fragments were observed in the resulting SCGD mass spectra. Fragmentation of molecular species was found to be tunable; high discharge currents led to harder ionization, while low discharge currents produced stronger molecular-ion signals. Ambient gases and solids, desorbed by the plasma from a glass probe, were also readily ionized by the SCGD. Indeed, strong analyte signals were obtained from solid samples placed at least 2 cm from the plasma. These findings indicate that the SCGD might be useful also for ambient desorption/ionization mass spectrometry. Combined with earlier results that showed the SCGD is useful for ionization of labile biomolecules, the results here indicate that the SCGD is a highly versatile ion source capable of providing both elemental and molecular mass-spectral information. - Highlights: • Solution-cathode glow discharge used as an ionization source for mass spectrometry. • SCGD-MS can provide atomic as well as intact molecular mass spectra. • Atomic limits of detection range

  10. Investigation of hydrophobic substrates for solution residue analysis utilizing an ambient desorption liquid sampling-atmospheric pressure glow discharge microplasma.

    Science.gov (United States)

    Paing, Htoo W; Marcus, R Kenneth

    2018-03-12

    A practical method for preparation of solution residue samples for analysis utilizing the ambient desorption liquid sampling-atmospheric pressure glow discharge optical emission spectroscopy (AD-LS-APGD-OES) microplasma is described. Initial efforts involving placement of solution aliquots in wells drilled into copper substrates, proved unsuccessful. A design-of-experiment (DOE) approach was carried out to determine influential factors during sample deposition including solution volume, solute concentration, number of droplets deposited, and the solution matrix. These various aspects are manifested in the mass of analyte deposited as well as the size/shape of the product residue. Statistical analysis demonstrated that only those initial attributes were significant factors towards the emission response of the analyte. Various approaches were investigated to better control the location/uniformity of the deposited sample. Three alternative substrates, a glass slide, a poly(tetrafluoro)ethylene (PTFE) sheet, and a polydimethylsiloxane (PDMS)-coated glass slide, were evaluated towards the microplasma analytical performance. Co-deposition with simple organic dyes provided an accurate means of determining the location of the analyte with only minor influence on emission responses. The PDMS-coated glass provided the best performance by virtue of its providing a uniform spatial distribution of the residue material. This uniformity yielded an improved limits of detection by approximately 22× for 20 μL and 4 x for 2 μL over the other two substrates. While they operate by fundamentally different processes, this choice of substrate is not restricted to the LS-APGD, but may also be applicable to other AD methods such as DESI, DART, or LIBS. Further developments will be directed towards a field-deployable ambient desorption OES source for quantitative analysis of microvolume solution residues of nuclear forensics importance.

  11. Liquid sampling-atmospheric pressure glow discharge optical emission spectroscopy detection of laser ablation produced particles: A feasibility study

    International Nuclear Information System (INIS)

    Quarles, C. Derrick; Gonzalez, Jhanis; Choi, Inhee; Ruiz, Javier; Mao, Xianglei; Marcus, R. Kenneth; Russo, Richard E.

    2012-01-01

    The use of a liquid sampling-atmospheric pressure glow discharge (LS-APGD) microplasma source as an alternative to conventional inductively coupled plasma (ICP) detection of laser ablation (LA) produced particles using a Nd:YAG laser at 1064 nm is demonstrated. This configuration utilizes a 180° geometry, which is different from the 40° geometry that was used to ionize ablated particles followed by mass spectrometric detection. The use of a hollow counter electrode (nickel, 0.3 cm o.d., 0.1 cm i.d.) was implemented to introduce ablated particles directly into the APGD plasma with helium as a carrier gas. The LS-APGD source was optimized using ablated copper as the test sample (helium carrier gas flow rate (0.30 L min −1 He), discharge current (60 mA), laser power (44 mJ), and solution electrode sheath gas (0.2 L min −1 He) and solution flow rates (10 μL min −1 5% HNO 3 )). Standard brass samples having known Zn/Cu percentages were ablated and analyzed using the LS-APGD source. As a comparison, the established technique of laser-induced breakdown spectroscopy (LIBS) was used to analyze the same set of brass standards under similar ablation conditions to the LS-AGPD measurements, yielding comparable results. The Zn/Cu ratio results for the LS-APGD and LIBS measurements showed good similarity to previous measurements using ICP-MS detection. The performance of the LS-APGD–OES microplasma, comparable to well established methods, with lower capital and operational overhead expenses, suggests a great deal of promise as an analytical excitation source. - Highlights: ► Particles formed by laser ablation are readily introduced to the LS-APGD microplasma. ► The low power microplasma has sufficient energy to vaporize laser produced particles. ► Qualitative analysis of brass alloys is performed using a simple OES ratio method. ► The qualitative performance of the LS-APGD microplasma is on-par with LIBS analysis.

  12. The back-diffusion effect of air on the discharge characteristics of atmospheric-pressure radio-frequency glow discharges using bare metal electrodes

    International Nuclear Information System (INIS)

    Sun Wenting; Liang Tianran; Wang Huabo; Li Heping; Bao Chengyu

    2007-01-01

    Radio-frequency (RF), atmospheric-pressure glow discharge (APGD) plasmas using bare metal electrodes have promising prospects in the fields of plasma-aided etching, deposition, surface treatment, disinfection, sterilization, etc. In this paper, the discharge characteristics, including the breakdown voltage and the discharge voltage for sustaining a stable and uniform α mode discharge of the RF APGD plasmas are presented. The experiments are conducted by placing the home-made planar-type plasma generator in ambient and in a vacuum chamber, respectively, with helium as the primary plasma-forming gas. When the discharge processes occur in ambient, particularly for the lower plasma-working gas flow rates, the experimental measurements show that it is the back-diffusion effect of air in atmosphere, instead of the flow rate of the gas, that results in the obvious decrease in the breakdown voltage with increasing plasma-working gas flow rate. Further studies on the discharge characteristics, e.g. the luminous structures, the concentrations and distributions of chemically active species in plasmas, with different plasma-working gases or gas mixtures need to be conducted in future work

  13. The influence of stabilizers on the production of gold nanoparticles by direct current atmospheric pressure glow microdischarge generated in contact with liquid flowing cathode

    Energy Technology Data Exchange (ETDEWEB)

    Dzimitrowicz, Anna; Jamroz, Piotr, E-mail: piotr.jamroz@pwr.edu.pl; Greda, Krzysztof; Nowak, Piotr; Nyk, Marcin; Pohl, Pawel [Wroclaw University of Technology, Faculty of Chemistry (Poland)

    2015-04-15

    Gold nanoparticles (Au NPs) were prepared by direct current atmospheric pressure glow microdischarge (dc-μAPGD) generated between a miniature argon flow microjet and a flowing liquid cathode. The applied discharge system was operated in a continuous flow liquid mode. The influence of various stabilizers added to the solution of the liquid cathode, i.e., gelatin (GEL), polyvinylpyrrolidone (PVP), or polyvinyl alcohol (PVA), as well as the concentration of the Au precursor (chloroauric acid, HAuCl{sub 4}) in the solution on the production growth of Au NPs was investigated. Changes in the intensity of the localized surface plasmon resonance (LSPR) band in UV/Vis absorption spectra of solutions treated by dc-μAPGD and their color were observed. The position and the intensity of the LSPR band indicated that relatively small nanoparticles were formed in solutions containing GEL as a capping agent. In these conditions, the maximum of the absorption LSPR band was at 531, 534, and 535 nm, respectively, for 50, 100, and 200 mg L{sup −1} of Au. Additionally, scanning electron microscopy (SEM) and dynamic light scattering (DLS) were used to analyze the structure and the morphology of obtained Au NPs. The shape of Au NPs was spherical and uniform. Their mean size was ca. 27, 73, and 92 nm, while the polydispersity index was 0.296, 0.348, and 0.456 for Au present in the solution of the flowing liquid cathode at a concentration of 50, 100, and 200 mg L{sup −1}, respectively. The production rate of synthesized Au NPs depended on the precursor concentration with mean values of 2.9, 3.5, and 5.7 mg h{sup −1}, respectively.

  14. The influence of stabilizers on the production of gold nanoparticles by direct current atmospheric pressure glow microdischarge generated in contact with liquid flowing cathode

    Science.gov (United States)

    Dzimitrowicz, Anna; Jamroz, Piotr; Greda, Krzysztof; Nowak, Piotr; Nyk, Marcin; Pohl, Pawel

    2015-04-01

    Gold nanoparticles (Au NPs) were prepared by direct current atmospheric pressure glow microdischarge (dc-μAPGD) generated between a miniature argon flow microjet and a flowing liquid cathode. The applied discharge system was operated in a continuous flow liquid mode. The influence of various stabilizers added to the solution of the liquid cathode, i.e., gelatin (GEL), polyvinylpyrrolidone (PVP), or polyvinyl alcohol (PVA), as well as the concentration of the Au precursor (chloroauric acid, HAuCl4) in the solution on the production growth of Au NPs was investigated. Changes in the intensity of the localized surface plasmon resonance (LSPR) band in UV/Vis absorption spectra of solutions treated by dc-μAPGD and their color were observed. The position and the intensity of the LSPR band indicated that relatively small nanoparticles were formed in solutions containing GEL as a capping agent. In these conditions, the maximum of the absorption LSPR band was at 531, 534, and 535 nm, respectively, for 50, 100, and 200 mg L-1 of Au. Additionally, scanning electron microscopy (SEM) and dynamic light scattering (DLS) were used to analyze the structure and the morphology of obtained Au NPs. The shape of Au NPs was spherical and uniform. Their mean size was ca. 27, 73, and 92 nm, while the polydispersity index was 0.296, 0.348, and 0.456 for Au present in the solution of the flowing liquid cathode at a concentration of 50, 100, and 200 mg L-1, respectively. The production rate of synthesized Au NPs depended on the precursor concentration with mean values of 2.9, 3.5, and 5.7 mg h-1, respectively.

  15. Application of Direct Current Atmospheric Pressure Glow Microdischarge Generated in Contact with a Flowing Liquid Solution for Synthesis of Au-Ag Core-Shell Nanoparticles.

    Science.gov (United States)

    Dzimitrowicz, Anna; Jamroz, Piotr; Nyk, Marcin; Pohl, Pawel

    2016-04-06

    A direct current atmospheric pressure glow microdischarge (dc-μAPGD) generated between an Ar nozzle microjet and a flowing liquid was applied to produce Au-Ag core-shell nanoparticles (Au@AgCSNPs) in a continuous flow system. Firstly, operating dc-μAPGD with the flowing solution of the Au(III) ions as the cathode, the Au nanoparticles (AuNPs) core was produced. Next, to produce the core-shell nanostructures, the collected AuNPs solution was immediately mixed with an AgNO₃ solution and passed through the system with the reversed polarity to fabricate the Ag nanoshell on the AuNPs core. The formation of Au@AgCSNPs was confirmed using ultraviolet-visible (UV-Vis) absorbance spectrophotometry, transmission electron microscopy (TEM), and energy-dispersive X-ray spectroscopy (EDS). Three localized surface plasmon resonance absorption bands with wavelengths centered at 372, 546, and 675 nm were observed in the UV-Vis spectrum of Au@AgCSNPs, confirming the reduction of both the Au(III) and Ag(I) ions. The right configuration of metals in Au@AgCSNPs was evidenced by TEM. The Au core diameter was 10.2 ± 2.0 nm, while the thickness of the Ag nanoshell was 5.8 ± 1.8 nm. The elemental composition of the bimetallic nanoparticles was also confirmed by EDS. It is possible to obtain 90 mL of a solution containing Au@AgCSNPs per hour using the applied microdischarge system.

  16. Two discharge modes of a repetitive nanosecond pulsed helium glow discharge under sub-atmospheric pressure in the repetition frequency range of 20 to 600 kHz

    Science.gov (United States)

    Kikuchi, Yusuke; Maegawa, Takuya; Otsubo, Akira; Nishimura, Yoshimi; Nagata, Masayoshi; Yatsuzuka, Mitsuyasu

    2018-05-01

    Two discharge modes, α and γ, of a repetitive nanosecond pulsed helium glow discharge at a gas pressure of 10 kPa in the repetition frequency range from 20 to 600 kHz are reported for the first time. The pulsed glow discharge is produced in a pair of parallel plate metal electrodes without insertion of dielectrics. The α mode discharge is volumetrically produced in the electrode gap at a low-repetition frequency, whereas the γ mode discharge is localized at the cathode surface at a high-repetition frequency. At high-repetition frequency, the time interval between voltage pulses is shorter than the lifetime of the afterglow produced by the preceding discharge. Then, the γ mode discharge is maintained by a large number of secondary electrons emitted from the cathode exposed to high-density ions and metastable helium atoms in the afterglow. In the α mode discharge with a low-repetition frequency operation, primary electrons due to gas ionization dominate the ionization process. Thus, a large discharge voltage is needed for the excitation of the α mode discharge. It is established that the bifurcation of α-γ discharge mode, accompanied by a decrease in the discharge voltage, occurs at the high-repetition frequency of ∼120 kHz.

  17. Comparison of dielectric barrier discharge, atmospheric pressure radiofrequency-driven glow discharge and direct analysis in real time sources for ambient mass spectrometry of acetaminophen

    Energy Technology Data Exchange (ETDEWEB)

    Kratzer, Jan [Institute for National Measurement Standards, National Research Council of Canada, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6 (Canada); Institute of Analytical Chemistry of the ASCR, v.v.i., Veveri 97, CZ-602 00 Brno (Czech Republic); Mester, Zoltan [Institute for National Measurement Standards, National Research Council of Canada, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6 (Canada); Sturgeon, Ralph E., E-mail: Ralph.Sturgeon@nrc-cnrc.gc.ca [Institute for National Measurement Standards, National Research Council of Canada, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6 (Canada)

    2011-08-15

    Three plasma-based ambient pressure ion sources were investigated; laboratory constructed dielectric barrier and rf glow discharges, as well as a commercial corona discharge (DART source). All were used to desorb and ionize a model analyte, providing sampling techniques for ambient mass spectrometry (MS). Experimental parameters were optimized to achive highest signal for acetaminophen as the analyte. Insight into the mechanisms of analyte desorption and ionization was obtained by means of emission spectrometry and ion current measurements. Desorption and ionization mechanisms for this analyte appear to be identical for all three plasma sources. Emission spectra differ only in the intensities of various lines and bands. Desorption of solid analyte requires transfer of thermal energy from the plasma source to sample surface, in the absence of which complete loss of MS response occurs. For acetaminophen, helium was the best plasma gas, providing 100- to 1000-fold higher analyte response than with argon or nitrogen. The same trend was also evident with background ions (protonated water clusters). MS analyte signal intensity correlates with the ion density (expressed as ion current) in the plasma plume and with emission intensity from excited state species in the plasma. These observations support an ionization process which occurs via proton transfer from protonated water clusters to analyte molecules.

  18. Photo-preionization stabilized high-pressure glow-discharge lasers

    International Nuclear Information System (INIS)

    Von Bergmann, H.M.

    1980-07-01

    Simple nanosecond stabilization and pulsing techniques were developed to excite high-pressure gas-discharge lasers at high overvoltages and high specific power loadings. The techniques were applied to a variety of ultraviolet and visible laser systems employing fast transmission line pulsers and conventional LC generators. The stabilization procedures are evaluated and the parameters which control the geometry and uniformity of the high-pressure glow discharges are investigated. A detailed study of the formation, distribution and spectral characteristics of the fast surface corona discharges is provided. The stabilization and pulsing techniques were used for the corona and glow discharge excitation of high-pressure ultraviolet N 2 lasers. A detailed spectrally- and temporally-resolved study of the gain, fluorescence and energy extraction characteristics of the atmospheric pressure N 2 plasmas is provided

  19. Determination of Hg(2+) by on-line separation and pre-concentration with atmospheric-pressure solution-cathode glow discharge atomic emission spectrometry.

    Science.gov (United States)

    Li, Qing; Zhang, Zhen; Wang, Zheng

    2014-10-03

    A simple and sensitive method to determine Hg(2+) was developed by combining solution-cathode glow discharge atomic emission spectrometry (SCGD-AES) with flow injection (FI) based on on-line solid-phase extraction (SPE). We synthesized l-cysteine-modified mesoporous silica and packed it in an SPE microcolumn, which was experimentally determined to possess a good mercury adsorption capacity. An enrichment factor of 42 was achieved under optimized Hg(2+) elution conditions, namely, an FI flow rate of 2.0 mL min(-1) and an eluent comprised of 10% thiourea in 0.2 mol L(-1) HNO3. The detection limit of FI-SCGD-AES was determined to be 0.75 μg L(-1), and the precision of the 11 replicate Hg(2+) measurements was 0.86% at a concentration of 100 μg L(-1). The proposed method was validated by determining Hg(2+) in certified reference materials such as human hair (GBW09101b) and stream sediment (GBW07310). Copyright © 2014. Published by Elsevier B.V.

  20. Determination of Hg{sup 2+} by on-line separation and pre-concentration with atmospheric-pressure solution-cathode glow discharge atomic emission spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Li, Qing [Shanghai Institute of Ceramics, Chinese Academy of Science, Shanghai 200050 (China); Zhang, Zhen [Shanghai Institute of Ceramics, Chinese Academy of Science, Shanghai 200050 (China); School of Materials Science and Engineering, Shanghai University, Shanghai 200072 (China); Wang, Zheng, E-mail: wangzheng@mail.sic.ac.cn [Shanghai Institute of Ceramics, Chinese Academy of Science, Shanghai 200050 (China)

    2014-10-03

    Highlights: • A modified SBA-15 mesoporous silica (SH-SBA-15) was synthesized as a sorbent. • On-line SPE combined with SCGD-AES based on FIA was used to detect Hg{sup 2+} firstly. • A simple, low-cost Hg{sup 2+} analysis in a complex matrix was established. • The sensitive detection of Hg{sup 2+} was achieved with a detection limit of 0.75 μg L{sup −1}. - Abstract: A simple and sensitive method to determine Hg{sup 2+} was developed by combining solution-cathode glow discharge atomic emission spectrometry (SCGD-AES) with flow injection (FI) based on on-line solid-phase extraction (SPE). We synthesized L-cysteine-modified mesoporous silica and packed it in an SPE microcolumn, which was experimentally determined to possess a good mercury adsorption capacity. An enrichment factor of 42 was achieved under optimized Hg{sup 2+} elution conditions, namely, an FI flow rate of 2.0 mL min{sup −1} and an eluent comprised of 10% thiourea in 0.2 mol L{sup −1} HNO{sub 3}. The detection limit of FI–SCGD-AES was determined to be 0.75 μg L{sup −1}, and the precision of the 11 replicate Hg{sup 2+} measurements was 0.86% at a concentration of 100 μg L{sup −1}. The proposed method was validated by determining Hg{sup 2+} in certified reference materials such as human hair (GBW09101b) and stream sediment (GBW07310)

  1. Organic chemistry of NH3 and HCN induced by an atmospheric abnormal glow discharge in N2-CH4 mixtures

    OpenAIRE

    2010-01-01

    Abstract The formation of the chemical products produced in an atmospheric glow discharge fed by a N2-CH4 gas mixture has been studied using Fourier Transform InfraRed (FTIR) and Optical Emission Spectrometry (OES). The measurements were carried out in a flowing regime at ambient temperature and pressure with CH4 concentrations ranging from 0.5% to 2%. In the recorded emission spectra the lines of the second positive system CN system and the first negative s...

  2. On OH production in water containing atmospheric pressure plasmas

    NARCIS (Netherlands)

    Bruggeman, P.J.; Schram, D.C.

    2010-01-01

    In this paper radical production in atmospheric pressure water containing plasmas is discussed. As OH is often an important radical in these discharges the paper focuses on OH production. Besides nanosecond pulsed coronas and diffusive glow discharges, several other atmospheric pressure plasmas

  3. The effect of a miniature argon flow rate on the spectral characteristics of a direct current atmospheric pressure glow micro-discharge between an argon microjet and a small sized flowing liquid cathode

    Energy Technology Data Exchange (ETDEWEB)

    Jamroz, Piotr, E-mail: piotr.jamroz@pwr.wroc.pl; Zyrnicki, Wieslaw; Pohl, Pawel

    2012-07-15

    A stable direct current atmospheric pressure glow microdischarge (dc-{mu}APGD) was generated between a miniature Ar flow microjet and a small sized flowing liquid cathode. The microdischarge was operated in the open to air atmosphere. High energy species, including OH, NH, NO, N{sub 2}, H, O and Ar were identified in the emission spectra of this microdischarge. Additionally, atomic lines of metals dissolved in water solutions were easily excited. The near cathode and the near anode zones of the microdischarge were investigated as a function of an Ar flow rate up to 300 sccm. The spectroscopic parameters, i.e., the excitation, the vibrational and the rotational temperatures as well as the electron number density, were determined in the near cathode and the near anode regions of the microdischarge. In the near cathode region, the rotational temperatures obtained for OH (2000-2600 K) and N{sub 2} bands (1600-1950 K) were significantly lower than the excitation temperatures of Ar (7400 K-7800 K) and H (11 000-15 500 K) atoms. Vibrational temperatures of N{sub 2}, OH and NO varied from 3400 to 4000 K, from 2900 to 3400 K and from 2700 to 3000 K, respectively. In the near anode region, rotational temperatures of OH (350-1750 K) and N{sub 2} (400-1350 K) and excitation temperatures of Ar (5200-5500 K) and H (3600-12 600 K) atoms were lower than those measured in the near cathode region. The effect of the introduction of a liquid sample on the microdischarge radiation and spectroscopic parameters was also investigated in the near cathode zone. The electron number density was calculated from the Stark broadening of the H{sub {beta}} line and equals to (0.25-1.1) Multiplication-Sign 10{sup 15} cm{sup -3} and (0.68-1.2) Multiplication-Sign 10{sup 15} cm{sup -3} in the near cathode and the near anode zones, respectively. The intensity of the Na I emission line and the signal to background ratio (SBR) of this line were investigated in both zones to evaluate the excitation

  4. The effect of a miniature argon flow rate on the spectral characteristics of a direct current atmospheric pressure glow micro-discharge between an argon microjet and a small sized flowing liquid cathode

    International Nuclear Information System (INIS)

    Jamróz, Piotr; Żyrnicki, Wiesław; Pohl, Paweł

    2012-01-01

    A stable direct current atmospheric pressure glow microdischarge (dc-μAPGD) was generated between a miniature Ar flow microjet and a small sized flowing liquid cathode. The microdischarge was operated in the open to air atmosphere. High energy species, including OH, NH, NO, N 2 , H, O and Ar were identified in the emission spectra of this microdischarge. Additionally, atomic lines of metals dissolved in water solutions were easily excited. The near cathode and the near anode zones of the microdischarge were investigated as a function of an Ar flow rate up to 300 sccm. The spectroscopic parameters, i.e., the excitation, the vibrational and the rotational temperatures as well as the electron number density, were determined in the near cathode and the near anode regions of the microdischarge. In the near cathode region, the rotational temperatures obtained for OH (2000–2600 K) and N 2 bands (1600–1950 K) were significantly lower than the excitation temperatures of Ar (7400 K–7800 K) and H (11 000–15 500 K) atoms. Vibrational temperatures of N 2 , OH and NO varied from 3400 to 4000 K, from 2900 to 3400 K and from 2700 to 3000 K, respectively. In the near anode region, rotational temperatures of OH (350–1750 K) and N 2 (400–1350 K) and excitation temperatures of Ar (5200–5500 K) and H (3600–12 600 K) atoms were lower than those measured in the near cathode region. The effect of the introduction of a liquid sample on the microdischarge radiation and spectroscopic parameters was also investigated in the near cathode zone. The electron number density was calculated from the Stark broadening of the H β line and equals to (0.25–1.1) × 10 15 cm −3 and (0.68–1.2) × 10 15 cm −3 in the near cathode and the near anode zones, respectively. The intensity of the Na I emission line and the signal to background ratio (SBR) of this line were investigated in both zones to evaluate the excitation properties of the developed excitation microsource. The limit of

  5. Period multiplication and chaotic phenomena in atmospheric dielectric-barrier glow discharges

    International Nuclear Information System (INIS)

    Wang, Y. H.; Zhang, Y. T.; Wang, D. Z.; Kong, M. G.

    2007-01-01

    In this letter, evidence of temporal plasma nonlinearity in which atmospheric dielectric-barrier discharges undergo period multiplication and chaos using a one-dimensional fluid model is reported. Under the conditions conducive for chaotic states, several frequency windows are identified in which period multiplication and secondary bifurcations are observed. Such time-domain nonlinearity is important for controlling instabilities in atmospheric glow discharges

  6. Electrical Characterization of an RF Glow Discharge at Room Pressure

    International Nuclear Information System (INIS)

    Perez-Martinez, J. A.; Piedad-Beneitez, A. de la; Pena-Eguiluz, R.; Mercado-Cabrera, A.; Valencia A, R.; Barocio, S. R.; Lopez-Callejas, R.; Godoy-Cabrera, O. G.; Benitez-Read, J. S.; Pacheco-Sotelo, J. O.

    2006-01-01

    A non-thermal atmospheric-like plasma source able to operate at room temperature represents, by its physical nature, a considerable potential for biological applications, given its highly accurate action and extremely controllable penetration on the surface of biological tissue. As we start up a research line into this technology, we report the electrical characterization of a room pressure plasma discharge by means of a coupling network model. The discharge is produced by a 13.56MHz commercial generator. As it is impossible to measure directly its state variables (voltage and current intensity) due to the considerable perturbation created by introducing a low impedance at the system output, then an indirect estimation of such variables is achieved from experimental diagnostics at the input, so to validate the proposed electrical model

  7. The role of magnetic energy on plasma localization during the glow discharge under reduced pressure

    Directory of Open Access Journals (Sweden)

    Chodun Rafal

    2016-06-01

    Full Text Available In this work, we present the first results of our research on the synergy of fields, electric and magnetic, in the initiation and development of glow discharge under reduced pressure. In the two-electrode system under reduced pressure, the breakdown voltage characterizes a minimum energy input of the electric field to initiate and sustain the glow discharge. The glow discharge enhanced by the magnetic field applied just above the surface of the cathode influences the breakdown voltage decreasing its value. The idea of the experiment was to verify whether the contribution of potential energy of the magnetic field applied around the cathode is sufficiently effective to locate the plasma of glow discharge to the grounded cathode, which, in fact, is the part of a vacuum chamber wall (the anode is positively biased in this case. In our studies, we used the grounded magnetron unit with positively biased anode in order to achieve favorable conditions for the deposition of thin films on fibrous substrates such as fabrics for metallization, assuming that locally applied magnetic field can effectively locate plasma. The results of our studies (Paschen curve with the participation of the magnetic field seem to confirm the validity of the research assumption. What is the most spectacular - the glow discharge was initiated between introduced into the chamber anode and the grounded cathode of magnetron ‘assisted’ by the magnetic field (discharge did not include the area of the anode, which is a part of the magnetron construction.

  8. Study of a dual frequency atmospheric pressure corona plasma

    International Nuclear Information System (INIS)

    Kim, Dan Bee; Moon, S. Y.; Jung, H.; Gweon, B.; Choe, Wonho

    2010-01-01

    Radio frequency mixing of 2 and 13.56 MHz was investigated by performing experimental measurements on the atmospheric pressure corona plasma. As a result of the dual frequency, length, current density, and electron excitation temperature of the plasma were increased, while the gas temperature was maintained at roughly the same level when compared to the respective single frequency plasmas. Moreover, observation of time-resolved images revealed that the dual frequency plasma has a discharge mode of 2 MHz positive streamer, 2 MHz negative glow, and 13.56 MHz continuous glow.

  9. Low-pressure glow discharges with oscillating electrons in different electrode systems

    International Nuclear Information System (INIS)

    Bersenev, V.V.; Gavriolv, N.V.; Nikulin, S.P.

    1995-01-01

    One of the main applications of low - pressure glow discharges is the development on their basis of charged - particle beam sources. The use of glow discharges with oscillating electrons, which can operate stably in the voltage and pressure range to the left of the left branch of Pashen's curve, shows promise, because the decrease in critical pressure p 0 , below which the discharge operation becomes impossible, in the discharge system of a source promotes an increase in the electrical strength of its accelerating system. This, in its turn, makes possible the expansion of the operation range of accelerating voltages. This experimental investigation of glow discharges in such well - known systems with oscillating electrons, as Hollow Cathode (HC), Penning's System (PS) and Inverse Magnetron (IM), is aimed at revealing the system operating at the lowest pressure. Besides, both common features and peculiarities of discharge operation in these systems are discussed. Though there is an extensive amount of published information covering all the specified discharges, the carrying out of such investigation is justified, since a comparative analysis of results obtained by different authors is hampered by various conditions of their experiments

  10. Double streamer phenomena in atmospheric pressure low frequency corona plasma

    International Nuclear Information System (INIS)

    Kim, Dan Bee; Jung, H.; Gweon, B.; Choe, Wonho

    2010-01-01

    Time-resolved images of an atmospheric pressure corona discharge, generated at 50 kHz in a single pin electrode source, show unique positive and negative corona discharge features: a streamer for the positive period and a glow for the negative period. However, unlike in previous reports of dc pulse and low frequency corona discharges, multistreamers were observed at the initial time stage of the positive corona. A possible physical mechanism for the multistreamers is suggested.

  11. Characterization of the large area plane-symmetric low-pressure DC glow discharge

    Science.gov (United States)

    Avtaeva, S.; Gorokhovsky, V.; Myers, S.; Robertson, S.; Shunko, E.; Zembower, Z.

    2016-10-01

    Electron density and temperature as well as nitrogen dissociation degree in the low-pressure (10-50 mTorr) large area plane-symmetric DC glow discharge in Ar-N2 mixtures are studied by probes and spectral methods. Electron density measured by a hairpin probe is in good agreement with that derived from the intensity ratio of the N2 2nd positive system bands IC, 1 - 3/IC, 0 - 2 and from the intensity ratio of argon ions and atom lines IArII/IArI, while Langmuir probe data provides slightly higher values of electron density. Electron density in the low-pressure DC glow discharge varies with the discharge conditions in the limits of 108-1010 cm- 3. The concept of electron temperature can be used in low-pressure glow discharges with reservations. The intensity ratio of (0-0) vibrational bands of N2 1st negative and 2nd positive systems I391.4/I337.1 exhibits the electron temperature of 1.5-2.5 eV when argon fraction in the mixture is higher than nitrogen fraction and this ratio quickly increases with nitrogen fraction up to 10 eV in pure nitrogen. The electron temperature calculated from Langmuir probe I-V characteristics assuming a Maxwellian EEDF, gives Te 0.3-0.4 eV. In-depth analysis of the EEDF using the second derivative of Langmuir probe I-V characteristics shows that in a low-pressure glow discharge the EEDF is non-Maxwellian. The EEDF has two populations of electrons: the main background non-Maxwellian population of ;cold; electrons with the mean electron energy of 0.3-0.4 eV and the small Maxwellian population of ;hot; electrons with the mean electron energy of 1.0-2.5 eV. Estimations show that with electron temperature lower than 1 eV the rate of the direct electron impact ionization of N2 is low and the main mechanism of N2 ionization becomes most likely Penning and associative ionization. In this case, assumptions of the intensity ratio IN2+, 391/IN2, 337 method are violated. In the glow discharge, N2 dissociation degree reaches about 7% with the argon

  12. Sputtering in a glow discharge ion source - pressure dependence: theory and experiment

    International Nuclear Information System (INIS)

    Mason, R.S.; Pichilingi, Melanie

    1994-01-01

    A simplified theoretical expression has been developed for a glow discharge to show how the average cathode erosion rate (expressed as the number of atoms per ion of the total bombarding flux) varies with primary sputter yield, pressure, 'diffusion length' and sputtered atom 'stopping' cross section. An inverse pressure dependence is predicted which correlates well with experiment in the 2 and He, tend to converge. It is suggested that this could be due to a change in the mechanism to self-sputtering. Under constant conditions, the erosion rates of different cathode materials still correlate quite well with the differences in their primary sputter yields. (author)

  13. Columnar discharge mode between parallel dielectric barrier electrodes in atmospheric pressure helium

    Energy Technology Data Exchange (ETDEWEB)

    Hao, Yanpeng; Zheng, Bin; Liu, Yaoge [School of Electric Power, South China University of Technology, Guangzhou 510640 (China)

    2014-01-15

    Using a fast-gated intensified charge-coupled device, end- and side-view photographs were taken of columnar discharge between parallel dielectric barrier electrodes in atmospheric pressure helium. Based on three-dimensional images generated from end-view photographs, the number of discharge columns increased, whereas the diameter of each column decreased as the applied voltage was increased. Side-view photographs indicate that columnar discharges exhibited a mode transition ranging from Townsend to glow discharges generated by the same discharge physics as atmospheric pressure glow discharge.

  14. Microwave Atmospheric-Pressure Sensor

    Science.gov (United States)

    Flower, D. A.; Peckham, G. E.; Bradford, W. J.

    1986-01-01

    Report describes tests of microwave pressure sounder (MPS) for use in satellite measurements of atmospheric pressure. MPS is multifrequency radar operating between 25 and 80 GHz. Determines signal absorption over vertical path through atmosphere by measuring strength of echoes from ocean surface. MPS operates with cloud cover, and suitable for use on current meteorological satellites.

  15. Atmospheric Pressure Indicator.

    Science.gov (United States)

    Salzsieder, John C.

    1995-01-01

    Discusses observable phenomena related to air pressure. Describes a simple, unobtrusive, semiquantitative device to monitor the changes in air pressure that are associated with altitude, using a soft-drink bottle and a balloon. (JRH)

  16. The nonlocal electron kinetics for a low-pressure glow discharge dusty plasma

    Science.gov (United States)

    Liang, Yonggan; Wang, Ying; Li, Hui; Tian, Ruihuan; Yuan, Chengxun; Kudryavtsev, A. A.; Rabadanov, K. M.; Wu, Jian; Zhou, Zhongxiang; Tian, Hao

    2018-05-01

    The nonlocal electron kinetic model based on the Boltzmann equation is developed in low-pressure argon glow discharge dusty plasmas. The additional electron-dust elastic and inelastic collision processes are considered when solving the kinetic equation numerically. The orbital motion limited theory and collision enhanced collection approximation are employed to calculate the dust surface potential. The electron energy distribution function (EEDF), effective electron temperature Teff, and dust surface potential are investigated under different plasma and dust conditions by solving the Boltzmann and the dust charging current balance equations self-consistently. A comparison of the calculation results obtained from nonlocal and local kinetic models is made. It is shown that the appearance of dust particles leads to a deviation of the EEDF from its original profile for both nonlocal and local kinetic models. With the increase in dust density and size, the effective electron temperature and dust surface potential decrease due to the high-energy electron loss on the dust surface. Meanwhile, the nonlocal and local results differ much from each other under the same calculation condition. It is concluded that, for low-pressure (PR ≤ 1 cm*Torr) glow discharge dusty plasmas, the existence of dust particles will amplify the difference of local and nonlocal EEDFs, which makes the local kinetic model more improper to determine the main parameters of the positive column. The nonlocal kinetic model should be used for the calculation of the EEDFs and dusty plasma parameters.

  17. Generation of uniform atmospheric pressure argon glow plasma by ...

    Indian Academy of Sciences (India)

    The electron temperature and electron density of the plasma are determined ... Dielectric barrier discharge (DBD) and APGD are the subjects of research for the last ... The gap between the electrodes can be varied from 0.5 mm to 2 mm and Ar ...

  18. A dielectric barrier discharge in neon at atmospheric pressure

    International Nuclear Information System (INIS)

    Ran Junxia; Luo Haiyun; Wang Xinxin

    2011-01-01

    A dielectric barrier discharge in neon at atmospheric pressure is investigated with electrical measurement and fast photography. It is found that a stable diffuse discharge can be easily generated in a gap with a gap space of 0.5-6 mm and is identified with a glow discharge. The first breakdown voltage of the gap is considerably higher than that of the same gap working in a stable diffuse discharge mode, which indicates that Penning ionization of neon metastables from the previous discharge with inevitable gas impurities plays an important role in the decrease in the breakdown voltage. Discharge patterns are observed in a gap shorter than 1 mm. From the experiments with a wedge-like gap, it is found that the discharge patterns are formed in the area with a higher applied electric field, which suggests that a higher applied electric field may cause a transition from a diffuse glow to discharge patterns.

  19. Spatiotemporally resolved characteristics of a gliding arc discharge in a turbulent air flow at atmospheric pressure

    DEFF Research Database (Denmark)

    Zhu, Jiajian; Gao, Jinlong; Ehn, Andreas

    2017-01-01

    A gliding arc discharge was generated in a turbulent air flow at atmospheric pressure driven by a 35 kHz alternating current (AC) electric power. The spatiotemporally resolved characteristics of the gliding arc discharge, including glow-type discharges, spark-type discharges, short-cutting events...... and transitions among the different types of discharges, were investigated using simultaneously optical and electrical diagnostics. The glow-type discharge shows sinusoidal-like voltage and current waveforms with a peak current of hundreds of milliamperes. The frequency of the emission intensity variation...... of the glow-type discharge is the same as that of the electronic power dissipated in the plasma column. The glow-type discharge can transfer into a spark discharge characterized by a sharp peak current of several amperes and a sudden increase of the brightness in the plasma column. Transitions can also...

  20. Study of atmospheric air AC glow discharge using optical emission spectroscopy and near infrared diode laser cavity ringdown spectroscopy

    Science.gov (United States)

    Srivastava, Nimisha; Wang, Chuji; Dibble, Theodore S.

    2008-11-01

    AC glow discharges were generated in atmospheric pressure by applying high voltage AC in the range of 3500-15000 V to a pair of stainless steel electrodes separated by an air gap. The discharges were characterized by optical emission spectroscopy (OES) and continuous wave cavity ringdown spectroscopy (cw-CRDS). The electronic (Tex), vibrational (Tv), and rotational (Tr) temperatures were measured. Spectral stimulations of the emission spectra of several vibronic bands of the 2^nd positive system of N2, the 1^st negative system of N2^+, the (0,1,2,3-0) bands of NO (A-X), and the (0-0) band of OH (A-X), which were obtained under various plasma operating conditions, show that Tr, Tv, and Tex are in the ranges of 2000 - 3800, 3500 - 5000, and 6000 - 10500^ K, respectively. Emission spectra show that OH concentration increases while NO concentration decreases with an increase of electrode spacing. The absorption spectra of H2O and OH overtone in the near infrared (NIR) were measured by the cw-CRDS with a telecommunications diode laser at wavelength near 1515 nm.

  1. Atmospheric Pressure During Landing

    Science.gov (United States)

    1997-01-01

    This figure shows the variation with time of pressure (dots) measured by the Pathfinder MET instrument during the landing period shown in image PIA00797. The two diamonds indicate the times of bridal cutting and 1st impact. The overall trend in the data is of pressure increasing with time. This is almost certainly due to the lander rolling downhill by roughly 10 m. The spacing of the horizontal dotted lines indicates the pressure change expected from 10 m changes in altitude. Bounces may also be visible in the data.

  2. Atmospheric pressure plasma vapour coatings

    NARCIS (Netherlands)

    Sanden, van de M.C.M.; Starostine, S.; Premkumar, P.A.; Creatore, M.; Vries, de H.W.; Kondruweit, S.; Szyszka, B.; Pütz, J.

    2010-01-01

    The dielectric barrier discharge (DBD) is recognized as a promising tool of thin films deposition on various substrates at atmospheric pressure. Emerging applications including encapsulation of flexible solar cells and flexible displays require large scale low costs production cif transparent

  3. Electron beam generation in high voltage glow discharges

    International Nuclear Information System (INIS)

    Rocca, J.J.; Szapiro, B.; Murray, C.

    1989-01-01

    The generation of intense CW and pulsed electron beams in glow discharges in reviewed. Glow discharge electron guns operate at a pressure of the order of 1 Torr and often have an advantage in applications that require a broad area electron beam in a gaseous atmosphere, such as laser excitation and some aspects of materials processing. Aspects of electron gun design are covered. Diagnostics of the high voltage glow discharges including the electric field distribution mapped by Doppler free laser spectroscopy, and plasma density and electron temperature measurements of the electron yield of different cathode materials under glow discharge conditions are presented

  4. Non-linear macro evolution of a dc driven micro atmospheric glow discharge

    Energy Technology Data Exchange (ETDEWEB)

    Xu, S. F.; Zhong, X. X., E-mail: xxzhong@sjtu.edu.cn [The State Key Laboratory on Fiber Optic Local Area, Communication Networks and Advanced Optical Communication Systems, Key Laboratory for Laser Plasmas and Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240 (China)

    2015-10-15

    We studied the macro evolution of the micro atmospheric glow discharge generated between a micro argon jet into ambient air and static water. The micro discharge behaves similarly to a complex ecosystem. Non-linear behaviors are found for the micro discharge when the water acts as a cathode, different from the discharge when water behaves as an anode. Groups of snapshots of the micro discharge formed at different discharge currents are captured by an intensified charge-coupled device with controlled exposure time, and each group consisted of 256 images taken in succession. Edge detection methods are used to identify the water surface and then the total brightness is defined by adding up the signal counts over the area of the micro discharge. Motions of the water surface at different discharge currents show that the water surface lowers increasingly rapidly when the water acts as a cathode. In contrast, the water surface lowers at a constant speed when the water behaves as an anode. The light curves are similar to logistic growth curves, suggesting that a self-inhibition process occurs in the micro discharge. Meanwhile, the total brightness increases linearly during the same time when the water acts as an anode. Discharge-water interactions cause the micro discharge to evolve. The charged particle bomb process is probably responsible for the different behaviors of the micro discharges when the water acts as cathode and anode.

  5. Atmospheric-pressure plasma technology

    International Nuclear Information System (INIS)

    Kogelschatz, U

    2004-01-01

    Major industrial plasma processes operating close to atmospheric pressure are discussed. Applications of thermal plasmas include electric arc furnaces and plasma torches for generation of powders, for spraying refractory materials, for cutting and welding and for destruction of hazardous waste. Other applications include miniature circuit breakers and electrical discharge machining. Non-equilibrium cold plasmas at atmospheric pressure are obtained in corona discharges used in electrostatic precipitators and in dielectric-barrier discharges used for generation of ozone, for pollution control and for surface treatment. More recent applications include UV excimer lamps, mercury-free fluorescent lamps and flat plasma displays

  6. Atmospheric-pressure plasma jet

    Science.gov (United States)

    Selwyn, Gary S.

    1999-01-01

    Atmospheric-pressure plasma jet. A .gamma.-mode, resonant-cavity plasma discharge that can be operated at atmospheric pressure and near room temperature using 13.56 MHz rf power is described. Unlike plasma torches, the discharge produces a gas-phase effluent no hotter than 250.degree. C. at an applied power of about 300 W, and shows distinct non-thermal characteristics. In the simplest design, two concentric cylindrical electrodes are employed to generate a plasma in the annular region therebetween. A "jet" of long-lived metastable and reactive species that are capable of rapidly cleaning or etching metals and other materials is generated which extends up to 8 in. beyond the open end of the electrodes. Films and coatings may also be removed by these species. Arcing is prevented in the apparatus by using gas mixtures containing He, which limits ionization, by using high flow velocities, and by properly shaping the rf-powered electrode. Because of the atmospheric pressure operation, no ions survive for a sufficiently long distance beyond the active plasma discharge to bombard a workpiece, unlike low-pressure plasma sources and conventional plasma processing methods.

  7. Determining Atmospheric Pressure Using a Water Barometer

    Science.gov (United States)

    Lohrengel, C. Frederick, II; Larson, Paul R.

    2012-01-01

    The atmosphere is an envelope of compressible gases that surrounds Earth. Because of its compressibility and nonuniform heating by the Sun, it is in constant motion. The atmosphere exerts pressure on Earth's surface, but that pressure is in constant flux. This experiment allows students to directly measure atmospheric pressure by measuring the…

  8. The Influence of CO2 Admixtures on the Product Composition in a Nitrogen-Methane Atmospheric Glow Discharge Used as a Prebiotic Atmosphere Mimic.

    Science.gov (United States)

    Mazankova, V; Torokova, L; Krcma, F; Mason, N J; Matejcik, S

    2016-11-01

    This work extends our previous experimental studies of the chemistry of Titan's atmosphere by atmospheric glow discharge. The Titan's atmosphere seems to be similarly to early Earth atmospheric composition. The exploration of Titan atmosphere was initiated by the exciting results of the Cassini-Huygens mission and obtained results increased the interest about prebiotic atmospheres. Present work is devoted to the role of CO 2 in the prebiotic atmosphere chemistry. Most of the laboratory studies of such atmosphere were focused on the chemistry of N 2  + CH 4 mixtures. The present work is devoted to the study of the oxygenated volatile species in prebiotic atmosphere, specifically CO 2 reactivity. CO 2 was introduced to the standard N 2  + CH 4 mixture at different mixing ratio up to 5 % CH 4 and 3 % CO 2 . The reaction products were characterized by FTIR spectroscopy. This work shows that CO 2 modifies the composition of the gas phase with the detection of oxygenated compounds: CO and others oxides. There is a strong influence of CO 2 on increasing concentration other products as cyanide (HCN) and ammonia (NH 3 ).

  9. Thermal structure of atmospheric pressure non-equilibrium plasmas

    International Nuclear Information System (INIS)

    Nozaki, Tomohiro; Unno, Yasuko; Okazaki, Ken

    2002-01-01

    The thermal structure of a methane-fed dielectric barrier discharge (DBD) and a atmospheric pressure glow-discharge (APG) has been extensively investigated in terms of time-averaged gas temperature profile between two parallel-plate electrodes separated by 1.0 mm. Emission spectroscopy of the rotational band of CH ((0, 0) A 2 Δ→X 2 Π:431 nm) was performed for this purpose. In order to minimize average temperature increase in the reaction field, DBD and APG were activated by 10 kHz with 2% duty cycle pulsed voltage (2 μs pulse width/100 μs interval). In DBD, temperature increase of a single microdischarge, on a time average, reached 200 K. It suddenly decreased below 100 K associated with the dark space formation near the dielectric barrier. Also, gas temperature in the surface discharge was fairly low because emission in these regions was limited within the initial stages of propagation (∼5 ns), whereas energy deposition would continue until microdischarge extinction; these facts implied that rotational temperature seemed to be far below the actual gas temperature in these regions. In APG, gas temperature was uniformly increased by positive column formation. In addition, a remarkable temperature increase due to negative glow formation was obtained only near the metallic electrode. For practical interest, we also investigated the net temperature increase with high frequency operations (AC-80 kHz), which depends not only on plasma properties, but also various engineering factors such as flow field, external cooling conditions, and total input power. In DBD, gas temperature in the middle of gas gap was significantly increased with increasing input power because of poor cooling conditions. In APG, in contrast, gas temperature near the electrodes was significantly increased associated with negative glow formation

  10. Electric field measurements at near-atmospheric pressure by coherent Raman scattering of laser beams

    International Nuclear Information System (INIS)

    Ito, Tsuyohito; Kobayashi, Kazunobu; Hamaguchi, Satoshi; Mueller, Sarah; Czarnetzki, Uwe

    2010-01-01

    Electric field measurements at near-atmospheric pressure environments based on electric-field induced Raman scattering are applied to repetitively pulsed nanosecond discharges. The results have revealed that the peak electric field near the centre of the gap is almost independent of the applied voltage. Minimum sustainable voltage measurements suggests that, at each discharge pulse, charged particles that remain from the previous pulse serve as discharge seeds and play an important role for generation of uniform glow-like discharges.

  11. Generation of high-power-density atmospheric pressure plasma with liquid electrodes

    International Nuclear Information System (INIS)

    Dong Lifang; Mao Zhiguo; Yin Zengqian; Ran Junxia

    2004-01-01

    We present a method for generating atmospheric pressure plasma using a dielectric barrier discharge reactor with two liquid electrodes. Four distinct kinds of discharge, including stochastic filaments, regular square pattern, glow-like discharge, and Turing stripe pattern, are observed in argon with a flow rate of 9 slm. The electrical and optical characteristics of the device are investigated. Results show that high-power-density atmospheric pressure plasma with high duty ratio in space and time can be obtained. The influence of wall charges on discharge power and duty ratio has been discussed

  12. Transport Equations Resolution By N-BEE Anti-Dissipative Scheme In 2D Model Of Low Pressure Glow Discharge

    International Nuclear Information System (INIS)

    Kraloua, B.; Hennad, A.

    2008-01-01

    The aim of this paper is to determine electric and physical properties by 2D modelling of glow discharge low pressure in continuous regime maintained by term constant source. This electric discharge is confined in reactor plan-parallel geometry. This reactor is filled by Argon monatomic gas. Our continuum model the order two is composed the first three moments the Boltzmann's equations coupled with Poisson's equation by self consistent method. These transport equations are discretized by the finite volumes method. The equations system is resolved by a new technique, it is about the N-BEE explicit scheme using the time splitting method.

  13. Cathode fall thickness of abnormal glow discharges between parallel-plane electrodes in different radii at low pressure

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Yangyang; Luo, Haiyun; Zou, Xiaobing; Wang, Xinxin, E-mail: wangxx@tsinghua.edu.cn [Department of Electrical Engineering, Tsinghua University, Beijing 100084 (China)

    2015-02-15

    In order to investigate the influence of electrode radius on the characteristics of cathode fall thickness, experiments of low-pressure (20 Pa ≤ p ≤ 30 Pa) abnormal glow discharge were carried out between parallel-plane electrodes in different radii keeping gap distance unchanged. Axial distributions of light intensity were obtained from the discharge images captured using a Charge Coupled Device camera. The assumption that the position of the negative glow peak coincides with the edge of cathode fall layer was verified based on a two-dimensional model, and the cathode fall thicknesses, d{sub c}, were calculated from the axial distributions of light intensity. It was observed that the position of peak emission shifts closer to the cathode as current or pressure grows. The dependence of cathode fall thickness on the gas pressure and normalized current J/p{sup 2} was presented, and it was found that for discharges between electrodes in large radius the curves of pd{sub c} against J/p{sup 2} were superimposed on each other, however, this phenomenon will not hold for discharges between the smaller electrodes. The reason for this phenomenon is that the transverse diffusions of charged particles are not the same in two gaps between electrodes with different radii.

  14. An Atmospheric Pressure Ping-Pong "Ballometer"

    Science.gov (United States)

    Kazachkov, Alexander; Kryuchkov, Dmitriy; Willis, Courtney; Moore, John C.

    2006-01-01

    Classroom experiments on atmospheric pressure focus largely on demonstrating its existence, often in a most impressive way. A series of amusing physics demonstrations is widely known and practiced by educators teaching the topic. However, measuring the value of atmospheric pressure(P[subscript atm]) is generally done in a rather mundane way,…

  15. Atmospheric pressure plasma polymerization of 1,3-butadiene for hydrophobic finishing of textile substrates

    International Nuclear Information System (INIS)

    Samanta, Kartick K; Jassal, Manjeet; Agrawal, Ashwini K

    2010-01-01

    Atmospheric pressure plasma processing of textile has both ecological and economical advantages over the wet-chemical processing. However, reaction in atmospheric pressure plasma has important challenges to be overcome before it can be successfully used for finishing applications in textile. These challenges are (i) generating stable glow plasma in presence liquid/gaseous monomer, and (ii) keeping the generated radicals active in the presence of contaminants such as oxygen and air. In this study, a stable glow plasma was generated at atmospheric pressure in the mixture of gaseous reactive monomer-1,3-butadiene and He and was made to react with cellulosic textile substrate. After 12 min of plasma treatment, the hydrophilic surface of the cellulosic substrate turned into highly hydrophobic surface. The hydrophobic finish was found to be durable to soap washing. After soap washing, a water drop of 37 μl took around 250 s to get absorbed in the treated sample compared to 0 . Both top and bottom sides of the fabric showed similar hydrophobic results in terms of water absorbency and contact angle. The results may be attributed to chemical reaction of butadiene with the cellulosic textile substrate. The surface characterization of the plasma modified samples under SEM and AFM revealed modification of the surface under <100 nm. The results showed that atmospheric pressure plasma can be successfully used for carrying out reaction of 1,3-butadiene with cellulosic textile substrates for producing hydrophobic surface finish.

  16. A dc non-thermal atmospheric-pressure plasma microjet

    Science.gov (United States)

    Zhu, WeiDong; Lopez, Jose L.

    2012-06-01

    A direct current (dc), non-thermal, atmospheric-pressure plasma microjet is generated with helium/oxygen gas mixture as working gas. The electrical property is characterized as a function of the oxygen concentration and show distinctive regions of operation. Side-on images of the jet were taken to analyze the mode of operation as well as the jet length. A self-pulsed mode is observed before the transition of the discharge to normal glow mode. Optical emission spectroscopy is employed from both end-on and side-on along the jet to analyze the reactive species generated in the plasma. Line emissions from atomic oxygen (at 777.4 nm) and helium (at 706.5 nm) were studied with respect to the oxygen volume percentage in the working gas, flow rate and discharge current. Optical emission intensities of Cu and OH are found to depend heavily on the oxygen concentration in the working gas. Ozone concentration measured in a semi-confined zone in front of the plasma jet is found to be from tens to ˜120 ppm. The results presented here demonstrate potential pathways for the adjustment and tuning of various plasma parameters such as reactive species selectivity and quantities or even ultraviolet emission intensities manipulation in an atmospheric-pressure non-thermal plasma source. The possibilities of fine tuning these plasma species allows for enhanced applications in health and medical related areas.

  17. A dc non-thermal atmospheric-pressure plasma microjet

    International Nuclear Information System (INIS)

    Zhu Weidong; Lopez, Jose L

    2012-01-01

    A direct current (dc), non-thermal, atmospheric-pressure plasma microjet is generated with helium/oxygen gas mixture as working gas. The electrical property is characterized as a function of the oxygen concentration and show distinctive regions of operation. Side-on images of the jet were taken to analyze the mode of operation as well as the jet length. A self-pulsed mode is observed before the transition of the discharge to normal glow mode. Optical emission spectroscopy is employed from both end-on and side-on along the jet to analyze the reactive species generated in the plasma. Line emissions from atomic oxygen (at 777.4 nm) and helium (at 706.5 nm) were studied with respect to the oxygen volume percentage in the working gas, flow rate and discharge current. Optical emission intensities of Cu and OH are found to depend heavily on the oxygen concentration in the working gas. Ozone concentration measured in a semi-confined zone in front of the plasma jet is found to be from tens to ∼120 ppm. The results presented here demonstrate potential pathways for the adjustment and tuning of various plasma parameters such as reactive species selectivity and quantities or even ultraviolet emission intensities manipulation in an atmospheric-pressure non-thermal plasma source. The possibilities of fine tuning these plasma species allows for enhanced applications in health and medical related areas. (paper)

  18. Atmospheric-pressure electric discharge as an instrument of chemical activation of water solutions

    Science.gov (United States)

    Rybkin, V. V.; Shutov, D. A.

    2017-11-01

    Results of experimental studies and numerical simulations of physicochemical characteristics of plasmas generated in different types of atmospheric-pressure discharges (pulsed streamer corona, gliding electric arc, dielectric barrier discharge, glow-discharge electrolysis, diaphragmatic discharge, and dc glow discharge) used to initiate various chemical processes in water solutions are analyzed. Typical reactor designs are considered. Data on the power supply characteristics, plasma electron parameters, gas temperatures, and densities of active particles in different types of discharges excited in different gases and their dependences on the external parameters of discharges are presented. The chemical composition of active particles formed in water is described. Possible mechanisms of production and loss of plasma particles are discussed.

  19. Sustained diffusive alternating current gliding arc discharge in atmospheric pressure air

    Science.gov (United States)

    Zhu, Jiajian; Gao, Jinlong; Li, Zhongshan; Ehn, Andreas; Aldén, Marcus; Larsson, Anders; Kusano, Yukihiro

    2014-12-01

    Rapid transition from glow discharge to thermal arc has been a common problem in generating stable high-power non-thermal plasmas especially at ambient conditions. A sustained diffusive gliding arc discharge was generated in a large volume in atmospheric pressure air, driven by an alternating current (AC) power source. The plasma column extended beyond the water-cooled stainless steel electrodes and was stabilized by matching the flow speed of the turbulent air jet with the rated output power. Comprehensive investigations were performed using high-speed movies measured over the plasma column, synchronized with simultaneously recorded current and voltage waveforms. Dynamic details of the novel non-equilibrium discharge are revealed, which is characterized by a sinusoidal current waveform with amplitude stabilized at around 200 mA intermediate between thermal arc and glow discharge, shedding light to the governing mechanism of the sustained spark-suppressed AC gliding arc discharge.

  20. A kinetic model for low pressure glow discharges in the presence of dust particles

    International Nuclear Information System (INIS)

    Wang Dezhen; Dong, J.Q.; Mahajan, S.M.

    1996-05-01

    A kinetic model for electrons in dusty plasmas is developed. The Boltzmann and the dust charging balance equations are solved self-consistently. The dependence of the dust particle surface potential on plasma parameters and the effects of particulate contamination on electron energy distribution are investigated for direct-current argon glow discharges. It is shown that the dust particle surface potential obtained from this model is higher than that obtained for a Maxwellian electron distribution, and that the higher energy portion of the electron distribution is reduced in the presence of dust particles. Electron-dust collection and electron-atom inelastic collision are the main electron energy loss processes, and the electron energy loss due to electron-dust elastic collision is negligibly small for 10 -16 V cm 2 -15 V cm 2 under the discharge conditions considered in this work, where E is the externally applied electric field and N is the argon atom density. (author). 16 refs, 8 figs

  1. Optical diagnostics of atmospheric pressure air plasmas

    International Nuclear Information System (INIS)

    Laux, C O; Spence, T G; Kruger, C H; Zare, R N

    2003-01-01

    Atmospheric pressure air plasmas are often thought to be in local thermodynamic equilibrium owing to fast interspecies collisional exchange at high pressure. This assumption cannot be relied upon, particularly with respect to optical diagnostics. Velocity gradients in flowing plasmas and/or elevated electron temperatures created by electrical discharges can result in large departures from chemical and thermal equilibrium. This paper reviews diagnostic techniques based on optical emission spectroscopy and cavity ring-down spectroscopy that we have found useful for making temperature and concentration measurements in atmospheric pressure plasmas under conditions ranging from thermal and chemical equilibrium to thermochemical nonequilibrium

  2. Study of spatiotemporal dynamics of a nanosecond atmospheric-pressure dielectric barrier discharge in millimeter-long air gaps

    Energy Technology Data Exchange (ETDEWEB)

    Malashin, M. V.; Moshkunkov, S. I.; Khomich, V. Yu.; Shershunova, E. A., E-mail: eshershunova@gmail.com [Russian Academy of Sciences, Institute for Electrophysics and Electric Power (Russian Federation)

    2017-02-15

    The spatiotemporal dynamics of a nanosecond atmospheric-pressure dielectric barrier discharge in 1- to 3-mm-long air gaps was studied experimentally. By using a segmented electrode, data on the time evolution of the discharge in different regions of the discharge gap were obtained. The uniformity of the discharge over the cross section is estimated by analyzing the spatial distribution of its glow.

  3. Study of geometrical and operational parameters controlling the low frequency microjet atmospheric pressure plasma characteristics

    International Nuclear Information System (INIS)

    Kim, Dan Bee; Rhee, J. K.; Moon, S. Y.; Choe, W.

    2006-01-01

    Controllability of small size atmospheric pressure plasma generated at low frequency in a pin to dielectric plane electrode configuration was studied. It was shown that the plasma characteristics could be controlled by geometrical and operational parameters of the experiment. Under most circumstances, continuous glow discharges were observed, but both the corona and/or the dielectric barrier discharge characteristics were observed depending on the position of the pin electrode. The plasma size and the rotational temperature were also varied by the parameters. The rotational temperature was between 300 and 490 K, being low enough to treat thermally sensitive materials

  4. Sustained diffusive alternating current gliding arc discharge in atmospheric pressure air

    DEFF Research Database (Denmark)

    Zhu, Jiajian; Gao, Jinlong; Li, Zhongshan

    2014-01-01

    Rapid transition from glow discharge to thermal arc has been a common problem in generating stable high-power non-thermal plasmas especially at ambient conditions. A sustained diffusive gliding arc discharge was generated in a large volume in atmospheric pressure air, driven by an alternating...... current (AC) power source. The plasma column extended beyond the water-cooled stainless steel electrodes and was stabilized by matching the flow speed of the turbulent air jet with the rated output power. Comprehensive investigations were performed using high-speed movies measured over the plasma column...

  5. Boundary-Layer Separation Control under Low-Pressure Turbine Airfoil Conditions using Glow-Discharge Plasma Actuators

    Science.gov (United States)

    Hultgren, Lennart S.; Ashpis, David E.

    2003-01-01

    transition. Gad-el-Hak provides a review of various techniques for flow control in general and Volino discusses recent studies on separation control under low-pressure-turbine conditions utilizing passive as well as active devices. As pointed out by Volino, passive devices optimized for separation control at low Reynolds numbers tend to increase losses at high Reynolds numbers, Active devices have the attractive feature that they can be utilized only in operational regimes where they are needed and when turned off would not affect the flow. The focus in the present paper is an experimental Separation is induced on a flat plate installed in a closed-circuit wind tunnel by a shaped insert on the opposite wall. The flow conditions represent flow over the suction surface of a modem low-pressure-turbine airfoil ('Pak-B'). The Reynolds number, based on wetted plate length and nominal exit velocity, is varied from 50,000 to 300,000, covering cruise to takeoff conditions. Low (0.2%) and high (2.5%) Gee-stream turbulence intensities are set using passive grids. A spanwise-oriented phased-plasma-array actuator, fabricated on a printed circuit board, is surface- flush-mounted upstream of the separation point and can provide forcing in a wide frequency range. Static surface pressure measurements and hot-wire anemometry of the base and controlled flows are performed and indicate that the glow-discharge plasma actuator is an effective device for separation control. of active separation control using glow discharge plasma actuators.

  6. Low Pressure DC Glow Discharge Air Plasma Surface Treatment of Polyethylene (PE) Film for Improvement of Adhesive Properties

    International Nuclear Information System (INIS)

    Pandiyaraj, Krishnasamy Navaneetha; Yoganand, Paramasivam; Selvarajan, Vengatasamy; Deshmukh, Rajendrasing R.; Balasubramanian, Suresh; Maruthamuthu, Sundaram

    2013-01-01

    The present work deals with the change in surface properties of polyethylene (PE) film using DC low pressure glow discharge air plasma and makes it useful for technical applications. The change in hydrophilicity of the modified PE film surface was investigated by measuring contact angle and surface energy as a function of exposure time. Changes in the morphological and chemical composition of PE films were analyzed by atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). The improvement in adhesion was studied by measuring T-peel and lap-shear strength. The results show that the wettability and surface energy of the PE film has been improved due to the introduction of oxygen-containing polar groups and an increase in surface roughness. The XPS result clearly shows the increase in concentration of oxygen content and the formation of polar groups on the polymer surface. The AFM observation on PE film shows that the roughness of the surface increased due to plasma treatment. The above morphological and chemical changes enhanced the adhesive properties of the PE film surfaces, which was confirmed by T-peel and lap-shear tests.

  7. Graphene Membranes for Atmospheric Pressure Photoelectron Spectroscopy.

    Science.gov (United States)

    Weatherup, Robert S; Eren, Baran; Hao, Yibo; Bluhm, Hendrik; Salmeron, Miquel B

    2016-05-05

    Atmospheric pressure X-ray photoelectron spectroscopy (XPS) is demonstrated using single-layer graphene membranes as photoelectron-transparent barriers that sustain pressure differences in excess of 6 orders of magnitude. The graphene serves as a support for catalyst nanoparticles under atmospheric pressure reaction conditions (up to 1.5 bar), where XPS allows the oxidation state of Cu nanoparticles and gas phase species to be simultaneously probed. We thereby observe that the Cu(2+) oxidation state is stable in O2 (1 bar) but is spontaneously reduced under vacuum. We further demonstrate the detection of various gas-phase species (Ar, CO, CO2, N2, O2) in the pressure range 10-1500 mbar including species with low photoionization cross sections (He, H2). Pressure-dependent changes in the apparent binding energies of gas-phase species are observed, attributable to changes in work function of the metal-coated grids supporting the graphene. We expect atmospheric pressure XPS based on this graphene membrane approach to be a valuable tool for studying nanoparticle catalysis.

  8. Runaway electron beam in atmospheric pressure discharges

    International Nuclear Information System (INIS)

    Oreshkin, E V; Barengolts, S A; Chaikovsky, S A; Oreshkin, V I

    2015-01-01

    A numerical simulation was performed to study the formation of a runaway electron (RAE) beam from an individual emission zone in atmospheric pressure air discharges with a highly overvolted interelectrode gap. It is shown that the formation of a RAE beam in discharges at high overvoltages is much contributed by avalanche processes. (paper)

  9. Device for determining pressures in aggressive atmospheres

    International Nuclear Information System (INIS)

    Schley, Robert; Voituriez, Bernard.

    1982-01-01

    This invention concerns a compact device for measuring rapidly changing pressures at high temperature and in corrosive or radioactive atmospheres. The device includes a case in which there is a support having two plane surfaces, an elliptical flexible membrane fixed to the first plane surface and supporting a strain gauge, a second gauge fixed to the second plane surface, the support being fitted with a passage enabling the membrane to distort under the action of the fluid it is desired to measure for pressure. Applies to the determination of pressures in nuclear reactors [fr

  10. Atmospheric pressure plasma polymerization of 1,3-butadiene for hydrophobic finishing of textile substrates

    Energy Technology Data Exchange (ETDEWEB)

    Samanta, Kartick K; Jassal, Manjeet; Agrawal, Ashwini K, E-mail: ashwini@smita-iitd.co, E-mail: manjeet.jassal@smita-iitd.co [Smart and Innovative Textile Materials Group (SMITA), Department of Textile Technology, Indian Institute of Technology, Hauz Khas, New Delhi-110016 (India)

    2010-02-01

    Atmospheric pressure plasma processing of textile has both ecological and economical advantages over the wet-chemical processing. However, reaction in atmospheric pressure plasma has important challenges to be overcome before it can be successfully used for finishing applications in textile. These challenges are (i) generating stable glow plasma in presence liquid/gaseous monomer, and (ii) keeping the generated radicals active in the presence of contaminants such as oxygen and air. In this study, a stable glow plasma was generated at atmospheric pressure in the mixture of gaseous reactive monomer-1,3-butadiene and He and was made to react with cellulosic textile substrate. After 12 min of plasma treatment, the hydrophilic surface of the cellulosic substrate turned into highly hydrophobic surface. The hydrophobic finish was found to be durable to soap washing. After soap washing, a water drop of 37 {mu}l took around 250 s to get absorbed in the treated sample compared to < 1 s in the untreated samples. The plasma modified samples showed water contact angle of around 134{sup 0}. Both top and bottom sides of the fabric showed similar hydrophobic results in terms of water absorbency and contact angle. The results may be attributed to chemical reaction of butadiene with the cellulosic textile substrate. The surface characterization of the plasma modified samples under SEM and AFM revealed modification of the surface under <100 nm. The results showed that atmospheric pressure plasma can be successfully used for carrying out reaction of 1,3-butadiene with cellulosic textile substrates for producing hydrophobic surface finish.

  11. Diagnostics of atmospheric pressure air plasmas

    International Nuclear Information System (INIS)

    Laux, C.O.; Kruger, C.H.; Zare, R.N.

    2001-01-01

    Atmospheric pressure air plasmas are often thought to be in Local Thermodynamics Equilibrium (LTE) owing to fast interspecies collisional exchanges at high pressure. As will be seen here, this assumption cannot be relied upon, particularly with respect to optical diagnostics. Large velocity gradients in flowing plasmas and/or elevated electron temperatures created by electrical discharges can result in large departures from chemical and thermal equilibrium. Diagnostic techniques based on optical emission spectroscopy (OES) and Cavity Ring-Down Spectroscopy (CRDS) have been developed and applied at Stanford University to the investigation of atmospheric pressure plasmas under conditions ranging from thermal and chemical equilibrium to thermochemical nonequilibrium. This article presents a review of selected temperature and species concentration measurement techniques useful for the study of air and nitrogen plasmas

  12. Equivalent effect of neutral gas pressure and transverse magnetic field in low-pressure glow discharge plasma

    International Nuclear Information System (INIS)

    Toma, M.; Rusu, Ioana; Pohoata, V.; Mihaila, I.

    2001-01-01

    In the paper it is emphasized the equivalent effect of the neutral gas pressure and the action of a transverse magnetic field (TMF), respectively, on a striated positive plasma column. Experimental and theoretical results prove that the distance between striations has the same variation under the influence of both neutral gas pressure and the action of TMF. The pressure modification as well as the action of a TMF can induce ionization instability in the plasma column which explains the standing striation appearance. (authors)

  13. Large area atmospheric-pressure plasma jet

    Science.gov (United States)

    Selwyn, Gary S.; Henins, Ivars; Babayan, Steve E.; Hicks, Robert F.

    2001-01-01

    Large area atmospheric-pressure plasma jet. A plasma discharge that can be operated at atmospheric pressure and near room temperature using 13.56 MHz rf power is described. Unlike plasma torches, the discharge produces a gas-phase effluent no hotter than 250.degree. C. at an applied power of about 300 W, and shows distinct non-thermal characteristics. In the simplest design, two planar, parallel electrodes are employed to generate a plasma in the volume therebetween. A "jet" of long-lived metastable and reactive species that are capable of rapidly cleaning or etching metals and other materials is generated which extends up to 8 in. beyond the open end of the electrodes. Films and coatings may also be removed by these species. Arcing is prevented in the apparatus by using gas mixtures containing He, which limits ionization, by using high flow velocities, and by properly spacing the rf-powered electrode. Because of the atmospheric pressure operation, there is a negligible density of ions surviving for a sufficiently long distance beyond the active plasma discharge to bombard a workpiece, unlike the situation for low-pressure plasma sources and conventional plasma processing methods.

  14. Research on atmospheric pressure plasma processing sewage

    Science.gov (United States)

    Song, Gui-cai; Na, Yan-xiang; Dong, Xiao-long; Sun, Xiao-liang

    2013-08-01

    The water pollution has become more and more serious with the industrial progress and social development, so it become a worldwide leading environmental management problem to human survival and personal health, therefore, countries are looking for the best solution. Generally speaking, in this paper the work has the following main achievements and innovation: (1) Developed a new plasma device--Plasma Water Bed. (2) At atmospheric pressure condition, use oxygen, nitrogen, argon and helium as work gas respectively, use fiber spectrometer to atmospheric pressure plasma discharge the emission spectrum of measurement, due to the different work gas producing active particle is different, so can understand discharge, different particle activity, in the treatment of wastewater, has the different degradation effects. (3) Methyl violet solution treatment by plasma water bed. Using plasma drafting make active particles and waste leachate role, observe the decolorization, measurement of ammonia nitrogen removal.

  15. Atmospheric pressure does not influence acute diverticular disease

    OpenAIRE

    Velayos Jiménez, Benito; Pons Renedo, Fernando; Feranández Salazar, Luis; Muñoz, María Fe; Olmo, Lourdes del; Almaraz Gómez, Ana; Beltrán de Heredia, Juan; Hernández González, José Manuel

    2013-01-01

    Producción Científica The article offers information on a study which examines the influence of atmospheric pressure on the development of acute diverticular disease. The value of atmospheric pressure and its daily trends in 2012 was collected to prove whether atmospheric pressure influence this disease by raising intra-diverticular pressure in days with higher atmospheric pressure. The study involved patients with acute diverticulitis who underwent computed tomography.

  16. Martian Atmospheric Pressure Static Charge Elimination Tool

    Science.gov (United States)

    Johansen, Michael R.

    2014-01-01

    A Martian pressure static charge elimination tool is currently in development in the Electrostatics and Surface Physics Laboratory (ESPL) at NASA's Kennedy Space Center. In standard Earth atmosphere conditions, static charge can be neutralized from an insulating surface using air ionizers. These air ionizers generate ions through corona breakdown. The Martian atmosphere is 7 Torr of mostly carbon dioxide, which makes it inherently difficult to use similar methods as those used for standard atmosphere static elimination tools. An initial prototype has been developed to show feasibility of static charge elimination at low pressure, using corona discharge. A needle point and thin wire loop are used as the corona generating electrodes. A photo of the test apparatus is shown below. Positive and negative high voltage pulses are sent to the needle point. This creates positive and negative ions that can be used for static charge neutralization. In a preliminary test, a floating metal plate was charged to approximately 600 volts under Martian atmospheric conditions. The static elimination tool was enabled and the voltage on the metal plate dropped rapidly to -100 volts. This test data is displayed below. Optimization is necessary to improve the electrostatic balance of the static elimination tool.

  17. A microwave pressure sounder. [for remote measurement of atmospheric pressure

    Science.gov (United States)

    Peckham, G. E.; Flower, D. A.

    1981-01-01

    A technique for the remote measurement of atmospheric surface pressure will be described. Such measurements could be made from a satellite in polar orbit and would cover many areas for which conventional meteorological data are not available. An active microwave instrument is used to measure the strength of return echoes from the ocean surface at a number of frequencies near the 60 GHz oxygen absorption band. Factors which affect the accuracy with which surface pressure can be deduced from these measurements will be discussed and an instrument designed to test the method by making measurements from an aircraft will be described.

  18. On the formation mechanisms of the diffuse atmospheric pressure dielectric barrier discharge in CVD processes of thin silica-like films

    International Nuclear Information System (INIS)

    Starostin, S A; Premkumar, P Antony; Creatore, M; Van Veldhuizen, E M; Van de Sanden, M C M; De Vries, H; Paffen, R M J

    2009-01-01

    Pathways of formation and temporal evolution of the diffuse dielectric barrier discharge at atmospheric pressure were experimentally studied in this work by means of optical (fast imaging camera) and electrical diagnostics. The chosen model system is relevant for applications of plasma-enhanced chemical vapor deposition of thin silica-like film on the polymeric substrate, from cost-efficient gas mixtures of Ar/N 2 /O 2 /hexamethyldisiloxane. It was found that the discharge can gradually experience the phases of homogeneous low current Townsend-like mode, local Townsend to glow transition and expanding high current density (∼0.7 A cm -2 ) glow-like mode. While the glow-like current spot occupies momentarily only a small part of the electrode area, its expanding behavior provides uniform treatment of the whole substrate surface. Alternatively, it was observed that a visually uniform discharge can be formed by the numerous microdischarges overlapping over the large electrode area.

  19. Atmospheric Pressure Plasma Processing for Polymer Adhesion: A Review

    DEFF Research Database (Denmark)

    Kusano, Yukihiro

    2014-01-01

    Atmospheric pressure plasma processing has attracted significant interests over decades due to its usefulness and a variety of applications. Adhesion improvement of polymer surfaces is among the most important applications of atmospheric pressure plasma treatment. Reflecting recent significant de...

  20. Nanocapillary Atmospheric Pressure Plasma Jet: A Tool for Ultrafine Maskless Surface Modification at Atmospheric Pressure.

    Science.gov (United States)

    Motrescu, Iuliana; Nagatsu, Masaaki

    2016-05-18

    With respect to microsized surface functionalization techniques we proposed the use of a maskless, versatile, simple tool, represented by a nano- or microcapillary atmospheric pressure plasma jet for producing microsized controlled etching, chemical vapor deposition, and chemical modification patterns on polymeric surfaces. In this work we show the possibility of size-controlled surface amination, and we discuss it as a function of different processing parameters. Moreover, we prove the successful connection of labeled sugar chains on the functionalized microscale patterns, indicating the possibility to use ultrafine capillary atmospheric pressure plasma jets as versatile tools for biosensing, tissue engineering, and related biomedical applications.

  1. Metals analysis for emission spectroscopic in the incandescent discharge operated with continuous flow of He to atmospheric pressure

    International Nuclear Information System (INIS)

    Alzate Londono, Hugo

    1990-01-01

    By means of a small power source a glow discharge in generated with he flowing at atmospheric pressure. Into a device situated to some distance from the discharge an aqueous sample of a metallic ion is injected. The device is then gradually moved to the discharge for producing solvent vaporization, charring, atomization, excitation and finally atomic emission of the sample. By emission spectrophotometer the following elements were analyzed: Ag, Cd, Cr, Cu, Hg, K, Na, Pb and Zn. For every one the useful range and the detection limit were established after founding the best operation conditions for the discharge

  2. Preliminary Investigation of a Dielectric Barrier Discharge Lamp in Open Air at Atmospheric Pressure

    International Nuclear Information System (INIS)

    Liu Feng; Wang Wei-Wei; Chang Xi-Jiang; Liang Rong-Qing

    2011-01-01

    A dielectric barrier discharge (DBD) lamp is investigated by using sinusoidal power with a 10 kHz frequency in open air at atmospheric pressure. With increasing applied voltages, the different discharge phenomena appear. At relatively low voltages, the discharge states are general stochastic filamentary discharges with weak light. However, at relatively high voltages, the walls of quartz tubes are heated sharply by plasma, and then the dazzling light is emitted very quickly to form the DBD Lamp, corresponding to the low maintaining voltage that is lower than the ignited voltage. The discharge state or mode of the DBD lamp that corresponds to the glow discharge is deduced according to the wave form of the circuit current, which is evidently different from the filamentary discharges. Under these conditions, the spectrum of the DBD lamp is continuous in the range 400–932 nm, which is scanned in the range 300–932 nm. It is also shown that there is another discharge state or mode that is different from the traditional filamentary discharges. Therefore, it is concluded that the discharge state or mode of the DBD lamp is a glow discharge. (physics of gases, plasmas, and electric discharges)

  3. Electric and spectroscopic properties of argon-hydrogen RF microplasma jets at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Souza-Correa, J A; Oliveira, C; Amorim, J [Laboratorio Nacional de Ciencia e Tecnologia do Bioetanol-CTBE, Caixa Postal 6170, 13083-970, Campinas, Sao Paulo (Brazil); Gomes, M P, E-mail: jorge.correa@bioetanol.org.b, E-mail: carlos.filho@bioetanol.org.b, E-mail: gomesmp@ita.b, E-mail: jayr.amorim@bioetanol.org.b [Departamento de Fisica, Instituto Tecnologico de Aeronautica-ITA, Praca Marechal Eduardo Gomes 50, 12.228-900, Sao Jose dos Campos, Sao Paulo (Brazil)

    2010-10-06

    Microplasma jets of argon-hydrogen (Ar-H{sub 2}) gas mixture were generated by 144.0 MHz radio-frequency (RF) waves at powers of 5 W, 10 W, 20 W and 50 W. The experimental setup employed creates stable microplasmas at atmospheric pressure from 5.0 mm up to 20.0 mm visual glow lengths. We have determined the rms voltages, the rms electric currents and the power absorptions of these microplasma jets. By making use of optical spectroscopy, the emission spectra of Ar-H{sub 2} microplasma jets were recorded in the range 3060-8200 A, in order to estimate the axial distribution profiles of electron density, rotational temperature, excitation temperature and hydrogen atomic temperature.

  4. Electromagnetic Wave Attenuation in Atmospheric Pressure Plasma

    International Nuclear Information System (INIS)

    Zhang Shu; Hu Xiwei; Liu Minghai; Luo Fang; Feng Zelong

    2007-01-01

    When an electromagnetic (EM) wave propagates in an atmospheric pressure plasma (APP) layer, its attenuation depends on the APP parameters such as the layer width, the electron density and its profile and collision frequency between electrons and neutrals. This paper proposes that a combined parameter-the product of the line average electron density n-bar and width d of the APP layer (i.e., the total number of electrons in a unit volume along the wave propagation path) can play a more explicit and decisive role in the wave attenuation than any of the above individual parameters does. The attenuation of the EM wave via the product of n-bar and d with various collision frequencies between electrons and neutrals is presented

  5. Hydrogen discharges operating at atmospheric pressure in a semiconductor gas discharge system

    Energy Technology Data Exchange (ETDEWEB)

    Aktas, K; Acar, S; Salamov, B G [Physics Department, Faculty of Arts and Sciences, Gazi University, 06500 Ankara (Turkey)

    2011-08-15

    Analyses of physical processes which initiate electrical breakdown and spatial stabilization of current and control it with a photosensitive cathode in a semiconductor gas discharge system (SGDS) are carried out in a wide pressure range up to atmospheric pressure p, interelectrode distance d and diameter D of the electrode areas of the semiconductor cathode. The study compares the breakdown and stability curves of the gas discharge in the planar SGDS where the discharge gap is filled with hydrogen and air in two cases. The impact of the ionizing component of the discharge plasma on the control of the stable operation of the planar SGDS is also investigated at atmospheric pressure. The loss of stability is primarily due to modification of the semiconductor-cathode properties on the interaction with low-energy hydrogen ions and the formation of a space charge of positive ions in the discharge gap which changes the discharge from Townsend to glow type. The experimental results show that the discharge current in H{sub 2} is more stable than in air. The breakdown voltages are measured for H{sub 2} and air with parallel-plane electrodes, for pressures between 28 and 760 Torr. The effective secondary electron emission (SEE) coefficient is then determined from the breakdown voltage results and compared with the experimental results. The influence of the SEE coefficient is stated in terms of the differences between the experimental breakdown law.

  6. Special issue: diagnostics of atmospheric pressure microplasmas

    Science.gov (United States)

    Bruggeman, Peter; Czarnetzki, Uwe; Tachibana, Kunihide

    2013-11-01

    In recent decades, a strong revival of non-equilibrium atmospheric pressure plasma studies has developed in the form of microplasmas. Microplasmas have typical scales of 1 mm or less and offer a very exciting research direction in the field of plasma science and technology as the discharge physics can be considerably different due to high collisionality and the importance of plasma-surface interaction. These high-pressure small-scale plasmas have a diverse range of physical and chemical properties. This diversity coincides with various applications including light/UV sources [1], material processing [2], chemical analysis [3], material synthesis [4], electromagnetics [5], combustion [6] and even medicine [7]. At atmospheric pressure, large scale plasmas have the tendency to become unstable due to the high collision rates leading to enhanced heating and ionization compared to their low-pressure counterparts. As low-pressure plasmas typically operate in reactors with sizes of tens of centimetres, scaling up the pressure to atmospheric pressure the size of the plasma reduces to typical sizes below 1 mm. A natural approach of stabilizing atmospheric pressure plasmas is thus the use of microelectrode geometries. Traditionally microplasmas have been produced in confined geometries which allow one to stabilize dc excited discharges. This stabilization is intrinsically connected to the large surface-to-volume ratio which enhances heat transfer and losses of charged and excited species to the walls. Currently challenging boundaries are pushed by producing microcavity geometries with dimensions of the order of 1 µm [8]. The subject of this special issue, diagnostics of microplasmas, is motivated by the many challenges in microplasma diagnostics in view of the complex chemistry and strong spatial (and even temporal) gradients of species densities and plasma properties. Atmospheric pressure plasmas have a very long history dating back more than 100 years, with early work of

  7. Influence of oxygen gas on characteristics of self-organized luminous pattern formation observed in an atmospheric dc glow discharge using a liquid electrode

    International Nuclear Information System (INIS)

    Shirai, Naoki; Uchida, Satoshi; Tochikubo, Fumiyoshi

    2014-01-01

    Self-organized luminous pattern formation is observed in the liquid surface of an atmospheric dc glow discharge using a liquid electrode with a miniature helium flow. The factors affecting pattern formation are the gap length, discharge current, helium mass flow rate and polarity. The pattern shape depends on the conductivity and temperature of the liquid electrode. A variety of patterns were observed by changing the conductivity and temperature of the liquid. We clarified that the self-organized pattern formation depends on the amount of electronegative gas, such as oxygen, in the gas in the electrode gap. When an oxygen gas flow was fed to the liquid surface from the outside in an obliquely downward direction, namely, the amount of oxygen gas on the liquid surface was increased locally, self-organized pattern formation was observed in the region with the increased amount of oxygen gas. When the amount of oxygen in the gas in the gap was changed by using a sheath flow system, the appearance of the pattern changed. The presence of oxygen gas strongly affected the self-organized pattern formation of the atmospheric dc discharge using a liquid anode. (paper)

  8. dc glow-discharge cleaning for accelerator

    International Nuclear Information System (INIS)

    Chou, T.S.; Hseuh, H.C.

    1982-01-01

    Average pressure of 1 x 10 -11 torr and vacuum stability are necessary for the successful operation of the proton storage rings such as ISABELLE. Vacuum degassing at high temperature and in situ bake-out will reduce the thermoout-gassing rate of the beam tubes to approx. 10 -13 Tl/cm 2 sec, therefore achieving the required static pressure. The vacuum instability caused by beam-induced ion desorption can be solved by dc glow discharge cleaning. With evidence from this study, the present understanding of glow discharge in a cylindrically symmetric geometry is reviewed. Argon and argon/oxygen mixture serve as plasmas in the glow. The role of oxygen in cleaning the beam tubes during the glow discharge is demonstrated experimentally. Glow discharge cleaning with and without bake-out is also studied

  9. Atmospheric pressure variations and abdominal aortic aneurysm rupture.

    LENUS (Irish Health Repository)

    Killeen, S D

    2012-02-03

    BACKGROUND: Ruptured abdominal aortic aneurysm (RAAA) presents with increased frequency in the winter and spring months. Seasonal changes in atmospheric pressure mirrors this pattern. AIM: To establish if there was a seasonal variation in the occurrence of RAAA and to determine if there was any association with atmospheric pressure changes. METHODS: A retrospective cohort-based study was performed. Daily atmospheric pressure readings for the region were obtained. RESULTS: There was a statistically significant monthly variation in RAAA presentation with 107 cases (52.5%) occurring from November to March. The monthly number of RAAA and the mean atmospheric pressure in the previous month were inversely related (r = -0.752, r (2) = 0.566, P = 0.03), and there was significantly greater daily atmospheric pressure variability on days when patients with RAAA were admitted. CONCLUSION: These findings suggest a relationship between atmospheric pressure and RAAA.

  10. Cold plasma brush generated at atmospheric pressure

    International Nuclear Information System (INIS)

    Duan Yixiang; Huang, C.; Yu, Q. S.

    2007-01-01

    A cold plasma brush is generated at atmospheric pressure with low power consumption in the level of several watts (as low as 4 W) up to tens of watts (up to 45 W). The plasma can be ignited and sustained in both continuous and pulsed modes with different plasma gases such as argon or helium, but argon was selected as a primary gas for use in this work. The brush-shaped plasma is formed and extended outside of the discharge chamber with typical dimension of 10-15 mm in width and less than 1.0 mm in thickness, which are adjustable by changing the discharge chamber design and operating conditions. The brush-shaped plasma provides some unique features and distinct nonequilibrium plasma characteristics. Temperature measurements using a thermocouple thermometer showed that the gas phase temperatures of the plasma brush are close to room temperature (as low as 42 deg. C) when running with a relatively high gas flow rate of about 3500 ml/min. For an argon plasma brush, the operating voltage from less than 500 V to about 2500 V was tested, with an argon gas flow rate varied from less than 1000 to 3500 ml/min. The cold plasma brush can most efficiently use the discharge power as well as the plasma gas for material and surface treatment. The very low power consumption of such an atmospheric argon plasma brush provides many unique advantages in practical applications including battery-powered operation and use in large-scale applications. Several polymer film samples were tested for surface treatment with the newly developed device, and successful changes of the wettability property from hydrophobic to hydrophilic were achieved within a few seconds

  11. Small surface wave discharge at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Kiss' ovski, Zh; Kolev, M; Ivanov, A; Lishev, St; Koleva, I, E-mail: kissov@phys.uni-sofia.b [Faculty of Physics, Sofia University, BG-1164 Sofia (Bulgaria)

    2009-09-21

    A small surface wave driven source produces plasma at atmospheric pressure. Microwave power at frequency 2.45 GHz is coupled with the source and a discharge is ignited at power levels below 10 W. The coaxial exciter of the surface waves has a length of 10 mm because its dielectric is a high permittivity discharge tube. The plasma source operates as a plasma jet in the case of plasma columns longer than the tube length. The source maintains stable plasma columns over a wide range of neutral gas flow and applied power in continuous and pulse regimes. An additional advantage of this source is the discharge self-ignition. An electron temperature of T{sub e} {approx} 1.9 eV and a density of n{sub e} {approx} 3.9 x 10{sup 14} cm{sup -3} are estimated by the probe diagnostics method. The emission spectra in the wavelength range 200-1000 nm under different experimental conditions are analysed and they prove the applicability of the source for analytical spectroscopy. The dependences of column length, reflected power and plasma parameters on the gas flow and the input power are discussed. (fast track communication)

  12. Simple microwave plasma source at atmospheric pressure

    International Nuclear Information System (INIS)

    Kim, Jeong H.; Hong, Yong C.; Kim, Hyoung S.; Uhm, Han S.

    2003-01-01

    We have developed a thermal plasma source operating without electrodes. One electrodeless torch is the microwave plasma-torch, which can produce plasmas in large quantities. We can generate plasma at an atmospheric pressure by marking use of the same magnetrons used as commercial microwave ovens. Most of the magnetrons are operated at the frequency of 2.45 GHz; the magnetron power microwave is about 1kW. Electromagnetic waves from the magnetrons propagate through a shorted waveguide. Plasma was generated under a resonant condition, by an auxiliary ignition system. The plasma is stabilized by vortex stabilization. Also, a high-power and high-efficiency microwave plasma-torch has been operated in air by combining two microwave plasma sources with 1kW, 2.45 GHz. They are arranged in series to generate a high-power plasma flame. The second torch adds all its power to the plasma flame of the first torch. Basically, electromagnetic waves in the waveguide were studied by a High Frequency Structure Simulator (HFSS) code and preliminary experiments were conducted

  13. Laser induced fluorescence in atmospheric pressure discharges

    International Nuclear Information System (INIS)

    Dilecce, G; De Benedictis, S; Martini, L M; Tosi, P; Scotoni, M

    2015-01-01

    This paper offers an outline of laser induced fluorescence (LIF) diagnostics and practical recommendations for its use in atmospheric pressure discharges. LIF principles, technical requirements and rationalization of experimental outcomes by modelling are addressed. Important issues that are particularly relevant to small scale, spatially inhomogeneous discharges, like plasma-jets, are emphasized. For the first time, all collision processes and the spatial non-homogeneity of the laser beam are together accounted for in the LIF model. Saturation characteristics are discussed and used for the assessment of model parameters. A calibration procedure is discussed and implemented. Gas temperature measurements by LIF are also addressed. The whole description of the technique is given, without loss of generality, through the example of its application to the OH radical. Notes on other diatomic radicals, CH, NO and CN, are given along the paper. Some results in a RF plasma-jet are presented as an example of application in a discharge system where all the concepts developed in the paper are applied. (paper)

  14. Examination of fluctuations in atmospheric pressure related to migraine.

    Science.gov (United States)

    Okuma, Hirohisa; Okuma, Yumiko; Kitagawa, Yasuhisa

    2015-01-01

    Japan has four seasons and many chances of low atmospheric pressure or approaches of typhoon, therefore it has been empirically known that the fluctuation of weather induces migraine in people. Generally, its mechanism has been interpreted as follows: physical loading, attributed by atmospheric pressure to human bodies, compresses or dilates human blood vessels, which leads to abnormality in blood flow and induces migraine. We report our examination of the stage in which migraine tends to be induced focusing on the variation of atmospheric pressure. Subjects were 34 patients with migraine, who were treated in our hospital. The patients included 31 females and three males, whose mean age was 32 ± 6.7. 22 patients had migraine with aura and 12 patients had migraine without aura. All of patients with migraine maintained a headache diary to record atmospheric pressures when they developed a migraine. The standard atmospheric pressure was defined as 1013 hPa, and with this value as the criterion, we investigated slight fluctuations in the atmospheric pressure when they developed a migraine. It was found that the atmospheric pressure when the patients developed a migraine was within 1003-1007 hPa in the approach of low atmospheric pressure and that the patients developed a migraine when the atmospheric pressure decreased by 6-10 hPa, slightly less than the standard atmospheric pressure. Small decreases of 6-10 hPa relative to the standard atmospheric pressure of 1013 hPa induced migraine attacks most frequently in patients with migraine.

  15. Simulation study of one-dimensional self-organized pattern in an atmospheric-pressure dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Jiao; Wang, Yanhui, E-mail: wangyh@dlut.edu.cn; Wang, Dezhen, E-mail: wangdez@dlut.edu.cn [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2015-04-15

    A two-dimensional fluid model is developed to simulate the one-dimensional self-organized patterns in an atmospheric-pressure dielectric barrier discharge (DBD) driven by sinusoidal voltage in argon. Under certain conditions, by changing applied voltage amplitude, the transversely uniform discharge can evolve into the patterned discharge and the varied self-organized patterned discharges with different numbers and arrangements of discharge channels can be observed. Similar to the uniform atmospheric-pressure DBD, the patterned discharge mode is found to undergo a transition from Townsend regime, sub-glow regime to glow regime with increasing applied voltage amplitude. In the different regimes, charged particles and electric field display different dynamical behaviors. If the voltage amplitude is increased over a certain value, the discharge enters an asymmetric patterned discharge mode, and then transforms into the spatially chaotic state with out-of-order discharge channels. The reason for forming the one-dimensional self-organized pattern is mainly due to the so-called activation-inhibition effect resulting from the local high electron density region appearing in discharge space. Electrode arrangement is the reason that induces local high electron density.

  16. Influence of atmospheric pressure on infrarenal abdominal aortic aneurysm rupture.

    Science.gov (United States)

    Robert, Nicolas; Frank, Michael; Avenin, Laure; Hemery, Francois; Becquemin, Jean Pierre

    2014-04-01

    Meteorologic conditions have a significant impact on the occurrence of cardiovascular events. Previous studies have shown that abdominal aortic aneurysm rupture (AAAR) may be associated with atmospheric pressure, with conflicting results. Therefore, we aimed to further investigate the nature of the correlation between atmospheric pressure variations and AAAR. Hospital admissions related to AAAR between 2005-2009 were assessed in 19 districts of metropolitan France and correlated with geographically and date-matched mean atmospheric pressures. In parallel and from 2005-2009, all fatal AAARs as reported by death certificates were assessed nationwide and correlated to local atmospheric pressures at the time of aortic rupture. Four hundred ninety-four hospital admissions related to AAAR and 6,358 deaths nationwide by AAAR were identified between 2005-2009. Both in-hospital ruptures and aneurysm-related mortality had seasonal variations, with peak/trough incidences in January and June, respectively. Atmospheric pressure peaks occurred during winter. Univariate analysis revealed a significant association (P atmospheric pressure values and AAAR. After multivariate analysis, mean maximum 1-month prerupture atmospheric pressure had a persistent correlation with both in-hospital relative risk (1.05 [95% confidence interval: 1.03-1.06]; P atmospheric pressure. Copyright © 2014 Elsevier Inc. All rights reserved.

  17. Atmospheric pressure microwave plasma system with ring waveguide

    International Nuclear Information System (INIS)

    Liu Liang; Zhang Guixin; Zhu Zhijie; Luo Chengmu

    2007-01-01

    Some scientists used waveguide as the cavity to produce a plasma jet, while large volume microwave plasma was relatively hard to get in atmospheric pressure. However, a few research institutes have already developed devices to generate large volume of atmospheric pressure microwave plasma, such as CYRANNUS and SLAN series, which can be widely applied. In this paper, present a microwave plasma system with ring waveguide to excite large volume of atmospheric pressure microwave plasma, plot curves on theoretical disruption electric field of some working gases, emulate the cavity through software, measure the power density to validate and show the appearance of microwave plasma. At present, large volume of argon and helium plasma have already been generated steadily by atmospheric pressure microwave plasma system. This research can build a theoretical basis of microwave plasma excitation under atmospheric pressure and will be useful in study of the device. (authors)

  18. Absorption spectroscopic studies of carbon dioxide conversion in a low pressure glow discharge using tunable infrared diode lasers

    International Nuclear Information System (INIS)

    Hempel, F; Roepcke, J; Miethke, F; Wagner, H-E

    2002-01-01

    The time and spatial dependence of the chemical conversion of CO 2 to CO were studied in a closed glow discharge reactor (p = 50 Pa, I = 2-30 mA) consisting of a small plasma zone and an extended stationary afterglow. Tunable infrared diode laser absorption spectroscopy has been applied to determine the absolute ground state concentrations of CO and CO 2 . After a certain discharge time an equilibrium of the concentrations of both species could be observed. The spatial dependence of the equilibrium CO concentration in the afterglow was found to be varying less than 10%. The feed gas was converted to CO more predominantly between 43% and 60% with increasing discharge current, forming so-called quasi-equilibrium states of the stable reaction products. The formation time of the stable gas composition also decreased with the current. For currents higher than 10 mA the conversion rate of CO 2 to CO was estimated to be 1.2x10 13 molecules J -1 . Based on the experimental results, a plasma chemical modelling has been established

  19. Low Temperature Atmospheric Pressure Plasma Sterilization Shower

    Data.gov (United States)

    National Aeronautics and Space Administration — The goal is to develop an atmospheric plasma jet that is capable of depositing a wide variety of materials on flexible substrates such as paper, plastic, cotton and...

  20. Optical emission spectroscopy diagnostics of an atmospheric pressure direct current microplasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Sismanoglu, B.N., E-mail: bogos@ita.b [Departamento de Fisica, Instituto Tecnologico de Aeronautica, Comando-Geral de Tecnologia Aeroespacial, Pca Marechal Eduardo Gomes 50, 12 228-900, Sao Jose dos Campos, SP (Brazil); Amorim, J., E-mail: jayr.amorim@bioetanol.org.b [Centro de Ciencia e Tecnologia do Bioetanol - CTBE, Caixa Postal 6170, 13083-970 Campinas, Sao Paulo (Brazil); Souza-Correa, J.A., E-mail: jorge.correa@bioetanol.org.b [Centro de Ciencia e Tecnologia do Bioetanol - CTBE, Caixa Postal 6170, 13083-970 Campinas, Sao Paulo (Brazil); Oliveira, C., E-mail: carlosf@ita.b [Departamento de Fisica, Instituto Tecnologico de Aeronautica, Comando-Geral de Tecnologia Aeroespacial, Pca Marechal Eduardo Gomes 50, 12 228-900, Sao Jose dos Campos, SP (Brazil); Gomes, M.P., E-mail: gomesmp@ita.b [Departamento de Fisica, Instituto Tecnologico de Aeronautica, Comando-Geral de Tecnologia Aeroespacial, Pca Marechal Eduardo Gomes 50, 12 228-900, Sao Jose dos Campos, SP (Brazil)

    2009-11-15

    This paper is about the use of optical emission spectroscopy as a diagnostic tool to determine the gas discharge parameters of a direct current (98% Ar-2% H{sub 2}) non-thermal microplasma jet, operated at atmospheric pressure. The electrical and optical behaviors were studied to characterize this glow discharge. The microplasma jet was investigated in the normal and abnormal glow regimes, for current ranging from 10 to 130 mA, at approx 220 V of applied voltage for copper cathode. OH (A {sup 2}SIGMA{sup +}, nu = 0 -> X {sup 2}PI, nu' = 0) rotational bands at 306.357 nm and also the 603.213 nm Ar I line, which is sensitive to van der Waals broadening, were used to determine the gas temperature, which ranges from 550 to 800 K. The electron number densities, ranging from 6.0 x 10{sup 14} to 1.4 x 10{sup 15} cm{sup -3}, were determined through a careful analysis of the main broadening mechanisms of the H{sub beta} line. From both 603.213 nm and 565.070 nm Ar I line broadenings, it was possible to obtain simultaneously electron number density and temperature (approx 8000 K). Excitation temperatures were also measured from two methods: from two Cu I lines and from Boltzmann-plot of 4p-4s and 5p-4s Ar I transitions. By employing H{sub alpha} line, the hydrogen atoms' H temperature was estimated (approx 18,000 K) and found to be surprisingly hotter than the excitation temperature.

  1. Measuring Viscosities of Gases at Atmospheric Pressure

    Science.gov (United States)

    Singh, Jag J.; Mall, Gerald H.; Hoshang, Chegini

    1987-01-01

    Variant of general capillary method for measuring viscosities of unknown gases based on use of thermal mass-flowmeter section for direct measurement of pressure drops. In technique, flowmeter serves dual role, providing data for determining volume flow rates and serving as well-characterized capillary-tube section for measurement of differential pressures across it. New method simple, sensitive, and adaptable for absolute or relative viscosity measurements of low-pressure gases. Suited for very complex hydrocarbon mixtures where limitations of classical theory and compositional errors make theoretical calculations less reliable.

  2. Charge Exchange Reaction in Dopant-Assisted Atmospheric Pressure Chemical Ionization and Atmospheric Pressure Photoionization.

    Science.gov (United States)

    Vaikkinen, Anu; Kauppila, Tiina J; Kostiainen, Risto

    2016-08-01

    The efficiencies of charge exchange reaction in dopant-assisted atmospheric pressure chemical ionization (DA-APCI) and dopant-assisted atmospheric pressure photoionization (DA-APPI) mass spectrometry (MS) were compared by flow injection analysis. Fourteen individual compounds and a commercial mixture of 16 polycyclic aromatic hydrocarbons were chosen as model analytes to cover a wide range of polarities, gas-phase ionization energies, and proton affinities. Chlorobenzene was used as the dopant, and methanol/water (80/20) as the solvent. In both techniques, analytes formed the same ions (radical cations, protonated molecules, and/or fragments). However, in DA-APCI, the relative efficiency of charge exchange versus proton transfer was lower than in DA-APPI. This is suggested to be because in DA-APCI both dopant and solvent clusters can be ionized, and the formed reagent ions can react with the analytes via competing charge exchange and proton transfer reactions. In DA-APPI, on the other hand, the main reagents are dopant-derived radical cations, which favor ionization of analytes via charge exchange. The efficiency of charge exchange in both DA-APPI and DA-APCI was shown to depend heavily on the solvent flow rate, with best efficiency seen at lowest flow rates studied (0.05 and 0.1 mL/min). Both DA-APCI and DA-APPI showed the radical cation of chlorobenzene at 0.05-0.1 mL/min flow rate, but at increasing flow rate, the abundance of chlorobenzene M(+.) decreased and reagent ion populations deriving from different gas-phase chemistry were recorded. The formation of these reagent ions explains the decreasing ionization efficiency and the differences in charge exchange between the techniques. Graphical Abstract ᅟ.

  3. Interaction of EM Waves with Atmospheric Pressure Plasmas

    National Research Council Canada - National Science Library

    Laroussi, Mounir

    2000-01-01

    .... The focus of the main activities is the generation of large volume, non-thermal, atmospheric pressure plasmas, their diagnostics, and their interactions with EM waves and with the cells of microorganism...

  4. Evaluation of Packed Distillation Columns I - Atmospheric Pressure

    National Research Council Canada - National Science Library

    Reynolds, Thaine

    1951-01-01

    .... Four column-packing combinations of the glass columns and four column-packing combinations of the steel columns were investigated at atmospheric pressure using a test mixture of methylcyclohexane...

  5. Non-Thermal Sanitation By Atmospheric Pressure Plasma, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — ORBITEC proposes to develop a non-thermal technology based on atmospheric-pressure (AP) cold plasma to sanitize foods, food packaging materials, and other hardware...

  6. Origin of fluctuations in atmospheric pressure arc plasma devices

    International Nuclear Information System (INIS)

    Ghorui, S.; Das, A.K.

    2004-01-01

    Fluctuations in arc plasma devices are extremely important for any technological application in thermal plasma. The origin of such fluctuations remains unexplained. This paper presents a theory for observed fluctuations in atmospheric pressure arc plasma devices. A qualitative explanation for observed behavior on atmospheric pressure arc plasma fluctuations, reported in the literature, can be obtained from the theory. The potential of the theory is demonstrated through comparison of theoretical predictions with reported experimental observations

  7. Decontamination of chemical and biological warfare (CBW) agents using an atmospheric pressure plasma jet (APPJ)

    International Nuclear Information System (INIS)

    Herrmann, H.W.; Henins, I.; Park, J.; Selwyn, G.S.

    1999-01-01

    The atmospheric pressure plasma jet (APPJ) [A. Schuetze et al., IEEE Trans. Plasma Sci. 26, 1685 (1998)] is a nonthermal, high pressure, uniform glow plasma discharge that produces a high velocity effluent stream of highly reactive chemical species. The discharge operates on a feedstock gas (e.g., He/O 2 /H 2 O), which flows between an outer, grounded, cylindrical electrode and an inner, coaxial electrode powered at 13.56 MHz rf. While passing through the plasma, the feedgas becomes excited, dissociated or ionized by electron impact. Once the gas exits the discharge volume, ions and electrons are rapidly lost by recombination, but the fast-flowing effluent still contains neutral metastable species (e.g., O 2 * , He * ) and radicals (e.g., O, OH). This reactive effluent has been shown to be an effective neutralizer of surrogates for anthrax spores and mustard blister agent. Unlike conventional wet decontamination methods, the plasma effluent does not cause corrosion and it does not destroy wiring, electronics, or most plastics, making it highly suitable for decontamination of sensitive equipment and interior spaces. Furthermore, the reactive species in the effluent rapidly degrade into harmless products leaving no lingering residue or harmful by-products. copyright 1999 American Institute of Physics

  8. Decontamination of chemical and biological warfare (CBW) agents using an atmospheric pressure plasma jet (APPJ)

    Science.gov (United States)

    Herrmann, H. W.; Henins, I.; Park, J.; Selwyn, G. S.

    1999-05-01

    The atmospheric pressure plasma jet (APPJ) [A. Schütze et al., IEEE Trans. Plasma Sci. 26, 1685 (1998)] is a nonthermal, high pressure, uniform glow plasma discharge that produces a high velocity effluent stream of highly reactive chemical species. The discharge operates on a feedstock gas (e.g., He/O2/H2O), which flows between an outer, grounded, cylindrical electrode and an inner, coaxial electrode powered at 13.56 MHz rf. While passing through the plasma, the feedgas becomes excited, dissociated or ionized by electron impact. Once the gas exits the discharge volume, ions and electrons are rapidly lost by recombination, but the fast-flowing effluent still contains neutral metastable species (e.g., O2*, He*) and radicals (e.g., O, OH). This reactive effluent has been shown to be an effective neutralizer of surrogates for anthrax spores and mustard blister agent. Unlike conventional wet decontamination methods, the plasma effluent does not cause corrosion and it does not destroy wiring, electronics, or most plastics, making it highly suitable for decontamination of sensitive equipment and interior spaces. Furthermore, the reactive species in the effluent rapidly degrade into harmless products leaving no lingering residue or harmful by-products.

  9. Decontamination of Chemical/Biological Warfare (CBW) Agents Using an Atmospheric Pressure Plasma Jet (APPJ)

    Science.gov (United States)

    Herrmann, Hans W.

    1998-11-01

    The atmospheric pressure plasma jet (APPJ) is a non-thermal, high pressure, uniform glow discharge that produces a high velocity effluent stream of highly reactive chemical species. The discharge operates on a feedstock gas (e.g. He/O_2/H_2O) which flows between an outer, grounded, cylindrical electrode and an inner, coaxial electrode powered at 13.56 MHz RF. While passing through the plasma, the feedgas becomes excited, dissociated or ionized by electron impact. Once the gas exits the discharge volume, ions and electrons are rapidly lost by recombination, but the fast-flowing effluent still contains metastables (e.g. O2*, He*) and radicals (e.g. O, OH). These reactive species have been shown to be effective neutralizers of surrogates for anthrax spores, mustard blister agent and VX nerve gas. Unlike conventional, wet decontamination methods, the plasma effluent does not cause corrosion of most surfaces and does not damage wiring, electronics, nor most plastics. This makes it highly suitable for decontamination of high value sensitive equipment such as is found in vehicle interiors (i.e. tanks, planes...) for which there is currently no good decontamination technique. Furthermore, the reactive species rapidly degrade into harmless products leaving no lingering residue or harmful byproducts. Physics of the APPJ will be discussed and results of surface decontamination experiments using simulant and actual CBW agents will be presented.

  10. Design and development of a low cost, high current density power supply for streamer free atmospheric pressure DBD plasma generation in air.

    Science.gov (United States)

    Jain, Vishal; Visani, Anand; Srinivasan, R; Agarwal, Vivek

    2018-03-01

    This paper presents a new power supply architecture for generating a uniform dielectric barrier discharge (DBD) plasma in air medium at atmospheric pressure. It is quite a challenge to generate atmospheric pressure uniform glow discharge plasma, especially in air. This is because air plasma needs very high voltage for initiation of discharge. If the high voltage is used along with high current density, it leads to the formation of streamers, which is undesirable for most applications like textile treatment, etc. Researchers have tried to generate high-density plasma using a RF source, nanosecond pulsed DC source, and medium frequency AC source. However, these solutions suffer from low current discharge and low efficiency due to the addition of an external resistor to control the discharge current. Moreover, they are relatively costly and bulky. This paper presents a new power supply configuration which is very compact and generates high average density (∼0.28 W/cm 2 ) uniform glow DBD plasma in air at atmospheric pressure. The efficiency is also higher as no external resistor is required to control the discharge current. An inherent feature of this topology is that it can drive higher current oscillations (∼50 A peak and 2-3 MHz frequency) into the plasma that damp out due to the plasma dissipation only. A newly proposed model has been used with experimental validation in this paper. Simulations and experimental validation of the proposed topology are included. Also, the application of the generated plasma for polymer film treatment is demonstrated.

  11. A Spectacular Experiment Exhibiting Atmospheric Pressure

    Science.gov (United States)

    Le Noxaïc, Armand

    2014-01-01

    The experiment described here is fairly easy to reproduce and dramatically shows the magnitude of ambient air pressure. Two circular plates of aluminum are applied one against the other. How do you make their separation very difficult? With only the help of an elastic band! You don't have to use a vacuum pump for this experiment.

  12. Ultrasound enhanced plasma surface modification at atmospheric pressure

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Singh, Shailendra Vikram; Norrman, Kion

    2012-01-01

    Efficiency of atmospheric pressure plasma treatment can be highly enhanced by simultaneous high power ultrasonic irradiation onto the treating surface. It is because ultrasonic waves with a sound pressure level (SPL) above ∼140 dB can reduce the thickness of a boundary gas layer between the plasma...... arc at atmospheric pressure to study adhesion improvement. The effect of ultrasonic irradiation with the frequency diapason between 20 and 40 kHz at the SPL of ∼150 dB was investigated. After the plasma treatment without ultrasonic irradiation, the wettability was significantly improved...

  13. Unusual neurological syndrome induced by atmospheric pressure change.

    Science.gov (United States)

    Ptak, Judy A; Yazinski, Nancy A; Block, Clay A; Buckey, Jay C

    2013-05-01

    We describe a case of a 46-yr-old female who developed hypertension, tachycardia, dysarthria, and leg weakness provoked by pressure changes associated with flying. Typically during the landing phase of flight, she would feel dizzy and note that she had difficulty with speech and leg weakness. After the flight the leg weakness persisted for several days. The symptoms were mitigated when she took a combined alpha-beta blocker (labetalol) prior to the flight. To determine if these symptoms were related to atmospheric pressure change, she was referred for testing in a hyperbaric chamber. She was exposed to elevated atmospheric pressure (maximum 1.2 ATA) while her heart rate and blood pressure were monitored. Within 1 min she developed tachycardia and hypertension. She also quickly developed slurred speech, left arm and leg weakness, and sensory changes in her left leg. She was returned to sea level pressure and her symptoms gradually improved. A full neurological workup has revealed no explanation for these findings. She has no air collections, cysts, or other anatomic findings that could be sensitive to atmospheric pressure change. The pattern is most consistent with a vascular event stimulated by altitude exposure. This case suggests that atmospheric pressure change can produce neurological symptoms, although the mechanism is unknown.

  14. Thermoluminescence glow curves of irradiated PMMA and low density polyethylene

    International Nuclear Information System (INIS)

    Matsuda, Koji; Nakase, Yoshiaki; Kumakiri, Yasuhito; Tsuji, Yoshio.

    1985-03-01

    Light emission from polymers is observed when polymers preirradiated with ionizing radiation at low temperature are heated gradually. The light emission is supposedly resulted from recombination of electrons with active centers produced in polymers or from some other processes involving charge transfer, but no definite explanation has been given at present on the thermoluminescent centers. This report describes our studies on the effects of impurities contained in polymers and pressure of ambient gases on the thermoluminescent glow curve of PMMA and low density polyethylene, which are often used for plastic film dosimeters. In the glow curve of PMMA, only one peak was observed at 110 K in an H 2 or He atmosphere at 760 Torr, but the intensity of the peak decreased with decreasing the H 2 or He gas pressure. At 10 -5 Torr H 2 or He atmosphere the peak disappered, and two sharp peaks appeared in the temperature range from 200 to 250 K. On the other hand, in the glow curve of low density polyethylene, three peaks were observed at 120 K, 180 K and 250 K in the presence of H 2 or He gas at 760 Torr. The effects of pressure of ambient gases and impurities in the polyethylene on these peaks indicate that the peak at 120 K is due to luminescent center produced on the surface or just below the surface of the matrix by collision of excited atoms or molecules of gases with polymer molecules, the peak at 120 K is originated from impurities in the matrix, and the peak at 250 0 K corresponds to luminescent center produced in polyethylene matrix. (author)

  15. Microplasma-based flowing atmospheric-pressure afterglow (FAPA) source for ambient desorption-ionization mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Zeiri, Offer M.; Storey, Andrew P.; Ray, Steven J., E-mail: sjray2@buffalo.edu; Hieftje, Gary M.

    2017-02-01

    A new direct-current microplasma-based flowing atmospheric pressure afterglow (FAPA) source was developed for use in ambient desorption-ionization mass spectrometry. The annular-shaped microplasma is formed in helium between two concentric stainless-steel capillaries that are separated by an alumina tube. Current-voltage characterization of the source shows that this version of the FAPA operates in the normal glow-discharge regime. A glass surface placed in the path of the helium afterglow reaches temperatures of up to approximately 400 °C; the temperature varies with distance from the source and helium flow rate through the source. Solid, liquid, and vapor samples were examined by means of a time-of-flight mass spectrometer. Results suggest that ionization occurs mainly through protonation, with only a small amount of fragmentation and adduct formation. The mass range of the source was shown to extend up to at least m/z 2722 for singly charged species. Limits of detection for several small organic molecules were in the sub-picomole range. Examination of competitive ionization revealed that signal suppression occurs only at high (mM) concentrations of competing substances. - Highlights: • The first microplasma version of the FAPA source. • Current-voltage behavior reflects the behavior of a normal glow discharge. • Detection limits below 1 pmol for the classes of organic compounds studied over a wide mass range. • Mass spectra show limited fragmentation.

  16. Foundations of atmospheric pressure non-equilibrium plasmas

    Science.gov (United States)

    Bruggeman, Peter J.; Iza, Felipe; Brandenburg, Ronny

    2017-12-01

    Non-equilibrium plasmas have been intensively studied over the past century in the context of material processing, environmental remediation, ozone generation, excimer lamps and plasma display panels. Research on atmospheric pressure non-equilibrium plasmas intensified over the last two decades leading to a large variety of plasma sources that have been developed for an extended application range including chemical conversion, medicine, chemical analysis and disinfection. The fundamental understanding of these discharges is emerging but there remain a lot of unexplained phenomena in these intrinsically complex plasmas. The properties of non-equilibrium plasmas at atmospheric pressure span over a huge range of electron densities as well as heavy particle and electron temperatures. This paper provides an overview of the key underlying processes that are important for the generation and stabilization of atmospheric pressure non-equilibrium plasmas. The unique physical and chemical properties of theses discharges are also summarized.

  17. Surface cleaning of metal wire by atmospheric pressure plasma

    International Nuclear Information System (INIS)

    Nakamura, T.; Buttapeng, C.; Furuya, S.; Harada, N.

    2009-01-01

    In this study, the possible application of atmospheric pressure dielectric barrier discharge plasma for the annealing of metallic wire is examined and presented. The main purpose of the current study is to examine the surface cleaning effect for a cylindrical object by atmospheric pressure plasma. The experimental setup consists of a gas tank, plasma reactor, and power supply with control panel. The gas assists in the generation of plasma. Copper wire was used as an experimental cylindrical object. This copper wire was irradiated with the plasma, and the cleaning effect was confirmed. The result showed that it is possible to remove the tarnish which exists on the copper wire surface. The experiment reveals that atmospheric pressure plasma is usable for the surface cleaning of metal wire. However, it is necessary to examine the method for preventing oxidization of the copper wire.

  18. Direct current plasma jet at atmospheric pressure operating in nitrogen and air

    Science.gov (United States)

    Deng, X. L.; Nikiforov, A. Yu.; Vanraes, P.; Leys, Ch.

    2013-01-01

    An atmospheric pressure direct current (DC) plasma jet is investigated in N2 and dry air in terms of plasma properties and generation of active species in the active zone and the afterglow. The influence of working gases and the discharge current on plasma parameters and afterglow properties are studied. The electrical diagnostics show that discharge can be sustained in two different operating modes, depending on the current range: a self-pulsing regime at low current and a glow regime at high current. The gas temperature and the N2 vibrational temperature in the active zone of the jet and in the afterglow are determined by means of emission spectroscopy, based on fitting spectra of N2 second positive system (C3Π-B3Π) and the Boltzmann plot method, respectively. The spectra and temperature differences between the N2 and the air plasma jet are presented and analyzed. Space-resolved ozone and nitric oxide density measurements are carried out in the afterglow of the jet. The density of ozone, which is formed in the afterglow of nitrogen plasma jet, is quantitatively detected by an ozone monitor. The density of nitric oxide, which is generated only in the air plasma jet, is determined by means of mass-spectroscopy techniques.

  19. Effects of oxygen concentration on atmospheric pressure dielectric barrier discharge in Argon-Oxygen Mixture

    Science.gov (United States)

    Li, Xuechun; Li, Dian; Wang, Younian

    2016-09-01

    A dielectric barrier discharge (DBD) can generate a low-temperature plasma easily at atmospheric pressure and has been investigated for applications in trials in cancer therapy, sterilization, air pollution control, etc. It has been confirmed that reactive oxygen species (ROS) play a key role in the processes. In this work, we use a fluid model to simulate the plasma characteristics for DBD in argon-oxygen mixture. The effects of oxygen concentration on the plasma characteristics have been discussed. The evolution mechanism of ROS has been systematically analyzed. It was found that the ground state oxygen atoms and oxygen molecular ions are the dominated oxygen species under the considered oxygen concentrations. With the oxygen concentration increasing, the densities of electrons, argon atomic ions, resonance state argon atoms, metastable state argon atoms and excited state argon atoms all show a trend of decline. The oxygen molecular ions density is high and little influenced by the oxygen concentration. Ground state oxygen atoms density tends to increase before falling. The ozone density increases significantly. Increasing the oxygen concentration, the discharge mode begins to change gradually from the glow discharge mode to Townsend discharge mode. Project supported by the National Natural Science Foundation of China (Grant No. 11175034).

  20. Blow-out limits of nonpremixed turbulent jet flames in a cross flow at atmospheric and sub-atmospheric pressures

    KAUST Repository

    Wang, Qiang; Hu, Longhua; Yoon, Sung Hwan; Lu, Shouxiang; Delichatsios, Michael; Chung, Suk-Ho

    2015-01-01

    The blow-out limits of nonpremixed turbulent jet flames in cross flows were studied, especially concerning the effect of ambient pressure, by conducting experiments at atmospheric and sub-atmospheric pressures. The combined effects of air flow

  1. MicroScale - Atmospheric Pressure Plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Sankaran, Mohan [Case Western Reserve University

    2012-01-25

    Low-temperature plasmas play an essential role in the manufacturing of integrated circuits which are ubiquitous in modern society. In recent years, these top-down approaches to materials processing have reached a physical limit. As a result, alternative approaches to materials processing are being developed that will allow the fabrication of nanoscale materials from the bottom up. The aim of our research is to develop a new class of plasmas, termed “microplasmas” for nanomaterials synthesis. Microplasmas are a special class of plasmas formed in geometries where at least one dimension is less than 1 mm. Plasma confinement leads to several unique properties including high-pressure stability and non-equilibrium that make microplasams suitable for nanomaterials synthesis. Vapor-phase precursors can be dissociated to homogeneously nucleate nanometer-sized metal and alloyed nanoparticles. Alternatively, metal salts dispersed in liquids or polymer films can be electrochemically reduced to form metal nanoparticles. In this talk, I will discuss these topics in detail, highlighting the advantages of microplasma-based systems for the synthesis of well-defined nanomaterials.

  2. Is atmospheric pressure change an Independent risk factor for hemoptysis?

    Science.gov (United States)

    Araz, Omer; Ucar, Elif Yilmazel; Akgun, Metin; Aydin, Yener; Meral, Mehmet; Saglam, Leyla; Kaynar, Hasan; Gorguner, Ali Metin

    2014-05-01

    Hemoptysis is one of the most important and challenging symptoms in pulmonary medicine. Because of the increased number of patients with hemoptysis in certain periods of the year, we aimed to investigate whether atmospheric changes have an effect on the development of hemoptysis with or without a secondary cause. The data of patients presenting with hemoptysis between January 2006 and December 2011 were analyzed. Data on the daily atmospheric pressure (hectopascal, hPa), relative humidity (%), and temperature ((o) C) during that time were obtained. A total of 232 patients with hemoptysis, 145 male (62.5%) and 87 female (37.5%) with an average age of 48.1(±17.6), were admitted to our hospital between 2006 and 2011. The highest admission rates were in the spring season, the highest in May (n=37, 15.9%), and the lowest admission rates were in December (n=10, 4.3%). A statistically significant negative correlation was found between the number of hemoptysis cases and mean atmospheric pressure but no relative humidity or outdoor temperature. Hemoptysis is very much influenced by weather factors; in particular, low atmospheric pressures significantly affect the development of hemoptysis. Fluctuations in atmospheric pressure may also play a role in hemoptysis.

  3. Ions in carbon dioxide at an atmospheric pressure

    International Nuclear Information System (INIS)

    Ikezoe, Yasumasa; Onuki, Kaoru; Shimizu, Saburo; Nakajima, Hayato; Sato, Shoichi; Matsuoka, Shingo; Nakamura, Hirone; Tamura, Takaaki

    1985-01-01

    The formation and the subsequent reactions of positive and negative ions were observed by a time resolved atmospheric pressure ionization mass spectrometer (TRAPI) in an atmospheric pressure carbon dioxide added with small amounts of carbon monoxide and oxygen. A relatively stable ion of (44 x n) + (n >= 2) having a different reactivity from that of (CO 2 ) + sub(n) was found to be one of major ionic species in this gas system. This species was tentatively assigned as [O 2 (CO) 2 ] + (CO 2 )sub(n-2). A new reaction sequence of positive ions is proposed which can be operative in the radiolysis of carbon dioxide at 1 atm. (author)

  4. Atmospheric pressure H20 plasma treatment of polyester cord threads

    International Nuclear Information System (INIS)

    Simor, M.; Krump, H.; Hudec, I.; Rahel, J.; Brablec, A.; Cernak, M.

    2004-01-01

    Polyester cord threads, which are used as a reinforcing materials of rubber blend, have been treated in atmospheric-pressure H 2 0 plasma in order to enhance their adhesion to rubber. The atmospheric-pressure H 2 0 plasma was generated in an underwater diaphragm discharge. The plasma treatment resulted in approximately 100% improvement in the adhesion. Scanning electron microscopy investigation indicates that not only introduced surface polar groups but also increased surface area of the fibres due to a fibre surface roughening are responsible for the improved adhesive strength (Authors)

  5. On the formation mechanisms of the diffuse atmospheric pressure dielectric barrier discharge in CVD processes of thin silica-like films

    Energy Technology Data Exchange (ETDEWEB)

    Starostin, S A; Premkumar, P Antony [Materials Innovation Institute (M2i), Mekelweg 2, 2600 GA Delft, The Netherland (Netherlands); Creatore, M; Van Veldhuizen, E M; Van de Sanden, M C M [Department of Applied Physics, Eindhoven University of Technology, 5600 MB Eindhoven (Netherlands); De Vries, H; Paffen, R M J [FUJIFILM Manufacturing Europe B.V, PO Box 90156, Tilburg (Netherlands)

    2009-11-15

    Pathways of formation and temporal evolution of the diffuse dielectric barrier discharge at atmospheric pressure were experimentally studied in this work by means of optical (fast imaging camera) and electrical diagnostics. The chosen model system is relevant for applications of plasma-enhanced chemical vapor deposition of thin silica-like film on the polymeric substrate, from cost-efficient gas mixtures of Ar/N{sub 2}/O{sub 2}/hexamethyldisiloxane. It was found that the discharge can gradually experience the phases of homogeneous low current Townsend-like mode, local Townsend to glow transition and expanding high current density ({approx}0.7 A cm{sup -2}) glow-like mode. While the glow-like current spot occupies momentarily only a small part of the electrode area, its expanding behavior provides uniform treatment of the whole substrate surface. Alternatively, it was observed that a visually uniform discharge can be formed by the numerous microdischarges overlapping over the large electrode area.

  6. Seed disinfection effect of atmospheric pressure plasma and low pressure plasma on Rhizoctonia solani.

    Science.gov (United States)

    Nishioka, Terumi; Takai, Yuichiro; Kawaradani, Mitsuo; Okada, Kiyotsugu; Tanimoto, Hideo; Misawa, Tatsuya; Kusakari, Shinichi

    2014-01-01

    Gas plasma generated and applied under two different systems, atmospheric pressure plasma and low pressure plasma, was used to investigate the inactivation efficacy on the seedborne pathogenic fungus, Rhizoctonia solani, which had been artificially introduced to brassicaceous seeds. Treatment with atmospheric plasma for 10 min markedly reduced the R. solani survival rate from 100% to 3% but delayed seed germination. The low pressure plasma treatment reduced the fungal survival rate from 83% to 1.7% after 10 min and the inactivation effect was dependent on the treatment time. The seed germination rate after treatment with the low pressure plasma was not significantly different from that of untreated seeds. The air temperature around the seeds in the low pressure system was lower than that of the atmospheric system. These results suggested that gas plasma treatment under low pressure could be effective in disinfecting the seeds without damaging them.

  7. Computational study of plasma-solid interaction in DC glow discharge in argon plasma at medium pressures

    International Nuclear Information System (INIS)

    Havlickova, E; Bartos, P; Hrach, R

    2007-01-01

    In the presented contribution two groups of techniques of computational physics-fluid modelling and non self-consistent particle technique were used to study plasma-solid interaction in argon plasma. We focused both on the physical processes taking place in the sheath at various pressures and on the problems of computational physics. The attention was given to preparation of two-dimensional fluid models with realistic assumptions about physical processes taking place in plasma during the plasma-solid interaction, further to improvement of the non self-consistent technique of particle modelling, where the external electric field was obtained either from the fluid model or directly from the trajectories of charged particles and finally to efficiency of individual algorithms

  8. Influence of geomagnetic activity and atmospheric pressure in hypertensive adults.

    Science.gov (United States)

    Azcárate, T; Mendoza, B

    2017-09-01

    We performed a study of the systolic and diastolic arterial blood pressure behavior under natural variables such as the atmospheric pressure and the horizontal geomagnetic field component. We worked with a group of eight adult hypertensive volunteers, four men and four women, with ages between 18 and 27 years in Mexico City during a geomagnetic storm in 2014. The data was divided by gender, age, and day/night cycle. We studied the time series using three methods: correlations, bivariate analysis, and superposed epoch (within a window of 2 days around the day of occurrence of a geomagnetic storm) analysis, between the systolic and diastolic blood pressure and the natural variables. The correlation analysis indicated a correlation between the systolic and diastolic blood pressure and the atmospheric pressure and the horizontal geomagnetic field component, being the largest during the night. Furthermore, the correlation and bivariate analyses showed that the largest correlations are between the systolic and diastolic blood pressure and the horizontal geomagnetic field component. Finally, the superposed epoch analysis showed that the largest number of significant changes in the blood pressure under the influence of geomagnetic field occurred in the systolic blood pressure for men.

  9. Influence of geomagnetic activity and atmospheric pressure in hypertensive adults

    Science.gov (United States)

    Azcárate, T.; Mendoza, B.

    2017-09-01

    We performed a study of the systolic and diastolic arterial blood pressure behavior under natural variables such as the atmospheric pressure and the horizontal geomagnetic field component. We worked with a group of eight adult hypertensive volunteers, four men and four women, with ages between 18 and 27 years in Mexico City during a geomagnetic storm in 2014. The data was divided by gender, age, and day/night cycle. We studied the time series using three methods: correlations, bivariate analysis, and superposed epoch (within a window of 2 days around the day of occurrence of a geomagnetic storm) analysis, between the systolic and diastolic blood pressure and the natural variables. The correlation analysis indicated a correlation between the systolic and diastolic blood pressure and the atmospheric pressure and the horizontal geomagnetic field component, being the largest during the night. Furthermore, the correlation and bivariate analyses showed that the largest correlations are between the systolic and diastolic blood pressure and the horizontal geomagnetic field component. Finally, the superposed epoch analysis showed that the largest number of significant changes in the blood pressure under the influence of geomagnetic field occurred in the systolic blood pressure for men.

  10. On the permanent hip-stabilizing effect of atmospheric pressure.

    Science.gov (United States)

    Prietzel, Torsten; Hammer, Niels; Schleifenbaum, Stefan; Kaßebaum, Eric; Farag, Mohamed; von Salis-Soglio, Georg

    2014-08-22

    Hip joint dislocations related to total hip arthroplasty (THA) are a common complication especially in the early postoperative course. The surgical approach, the alignment of the prosthetic components, the range of motion and the muscle tone are known factors influencing the risk of dislocation. A further factor that is discussed until today is atmospheric pressure which is not taken into account in the present THA concepts. The aim of this study was to investigate the impact of atmospheric pressure on hip joint stability. Five joint models (Ø 28-44 mm), consisting of THA components were hermetically sealed with a rubber capsule, filled with a defined amount of fluid and exposed to varying ambient pressure. Displacement and pressure sensors were used to record the extent of dislocation related to intraarticular and ambient pressure. In 200 experiments spontaneous dislocations of the different sized joint models were reliably observed once the ambient pressure was lower than 6.0 kPa. Increasing the ambient pressure above 6.0 kPa immediately and persistently reduced the joint models until the ambient pressure was lowered again. Displacement always exceeded half the diameter of the joint model and was independent of gravity effects. This experimental study gives strong evidence that the hip joint is permanently stabilized by atmospheric pressure, confirming the theories of Weber and Weber (1836). On basis of these findings the use of larger prosthetic heads, capsular repair and the deployment of an intracapsular Redon drain are proposed to substantially decrease the risk of dislocation after THA. Copyright © 2014 Elsevier Ltd. All rights reserved.

  11. Electrolytic synthesis of ammonia in molten salts under atmospheric pressure.

    Science.gov (United States)

    Murakami, Tsuyoshi; Nishikiori, Tokujiro; Nohira, Toshiyuki; Ito, Yasuhiko

    2003-01-15

    Ammonia was successfully synthesized by using a new electrochemical reaction with high current efficiency at atmospheric pressure and at lower temperatures than the Haber-Bosch process. In this method, nitride ion (N3-), which is produced by the reduction from nitrogen gas at the cathode, is anodically oxidized and reacts with hydrogen to produce ammonia at the anode.

  12. Atmospheric-Pressure Plasma Cleaning of Contaminated Surfaces

    International Nuclear Information System (INIS)

    Hicks, Robert F.; Herrmann, Hans W.

    2003-01-01

    The objective of this work is to demonstrate a practical, atmospheric pressure plasma tool for the surface decontamination of radioactive waste. Decontamination of radioactive materials that have accumulated on the surfaces of equipment and structures is a challenging and costly undertaking for the US Department of Energy. Our technology shows great potential for accelerating this clean up effort

  13. Reduced Lung Cancer Mortality With Lower Atmospheric Pressure.

    Science.gov (United States)

    Merrill, Ray M; Frutos, Aaron

    2018-01-01

    Research has shown that higher altitude is associated with lower risk of lung cancer and improved survival among patients. The current study assessed the influence of county-level atmospheric pressure (a measure reflecting both altitude and temperature) on age-adjusted lung cancer mortality rates in the contiguous United States, with 2 forms of spatial regression. Ordinary least squares regression and geographically weighted regression models were used to evaluate the impact of climate and other selected variables on lung cancer mortality, based on 2974 counties. Atmospheric pressure was significantly positively associated with lung cancer mortality, after controlling for sunlight, precipitation, PM2.5 (µg/m 3 ), current smoker, and other selected variables. Positive county-level β coefficient estimates ( P atmospheric pressure were observed throughout the United States, higher in the eastern half of the country. The spatial regression models showed that atmospheric pressure is positively associated with age-adjusted lung cancer mortality rates, after controlling for other selected variables.

  14. Atmospheric pressure plasma surface modification of carbon fibres

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Løgstrup Andersen, Tom; Michelsen, Poul

    2008-01-01

    Carbon fibres are continuously treated with dielectric barrier discharge plasma at atmospheric pressure in various gas conditions for adhesion improvement in mind. An x-ray photoelectron spectroscopic analysis indicated that oxygen is effectively introduced onto the carbon fibre surfaces by He, He...

  15. Atmospheric pressure helium afterglow discharge detector for gas chromatography

    Science.gov (United States)

    Rice, Gary; D'Silva, Arthur P.; Fassel, Velmer A.

    1986-05-06

    An apparatus for providing a simple, low-frequency electrodeless discharge system for atmospheric pressure afterglow generation. A single quartz tube through which a gas mixture is passed is extended beyond a concentric electrode positioned thereabout. A grounding rod is placed directly above the tube outlet to permit optical viewing of the discharge between the electrodes.

  16. Atmospheric pressure photoionization using tunable VUV synchrotron radiation

    International Nuclear Information System (INIS)

    Giuliani, A.; Giorgetta, J.-L.; Ricaud, J.-P.; Jamme, F.; Rouam, V.; Wien, F.; Laprévote, O.; Réfrégiers, M.

    2012-01-01

    Highlights: ► Coupling of an atmospheric pressure photoionization source with a vacuum ultra-violet (VUV) beamline. ► The set up allows photoionization up to 20 eV. ► Compared to classical atmospheric pressure photoionization (APPI), our set up offers spectral purity and tunability. ► Allows photoionization mass spectrometry on fragile and hard to vaporize molecules. - Abstract: We report here the first coupling of an atmospheric pressure photoionization (APPI) source with a synchrotron radiation beamline in the vacuum ultra-violet (VUV). A commercial APPI source of a QStar Pulsar i from AB Sciex was modified to receive photons from the DISCO beamline at the SOLEIL synchrotron radiation facility. Photons are delivered at atmospheric pressure in the 4–20 eV range. The advantages of this new set up, termed SR-APPI, over classical APPI are spectral purity and continuous tunability. The technique may also be used to perform tunable photoionization mass spectrometry on fragile compounds difficult to vaporize by classical methods.

  17. Einstein's Tea Leaves and Pressure Systems in the Atmosphere

    Science.gov (United States)

    Tandon, Amit; Marshall, John

    2010-01-01

    Tea leaves gather in the center of the cup when the tea is stirred. In 1926 Einstein explained the phenomenon in terms of a secondary, rim-to-center circulation caused by the fluid rubbing against the bottom of the cup. This explanation can be connected to air movement in atmospheric pressure systems to explore, for example, why low-pressure…

  18. Glow discharging device

    International Nuclear Information System (INIS)

    Maeno, Katsuki; Kawasaki, Kozo; Hiratsuka, Hajime; Kawashima, Shuichi.

    1989-01-01

    In a thermonuclear device, etc. impurities adsorbed to inner walls of a vacuum vessel by glow discharge are released to clean the vacuum vessel for preventing intrusion of the impurities into plasmas. The object of the present invention is to minimize the capacity of a power source equipment for the glow discharge device to the least extent. That is, a stabilization resistance is connected in series between each of a plurality of anodes which are inserted and arranged at the inside of a vacuum vessel as a cathode and a power source respectively. The resistance value R is selected so as to satisfy the relation: R < (Vi - Vm)/Ii, in which Vi: glow discharge starting voltage, Vm: glow discharge keeping voltage, Ii: glow discharge starting current. Accordingly, if a voltage is applied from a power source to a plurality of anodes, scattering of electric discharge between the anodes can be suppressed and the effect of voltage drop during discharge by the stabilization resistance can be eliminated. As a result, it is possible to provide an economically advantageous glow discharge device with the capacity for the power source facility being to the least extent. (K.M.)

  19. Atmospheric-pressure guided streamers for liposomal membrane disruption

    International Nuclear Information System (INIS)

    Svarnas, P.; Aleiferis, Sp.; Matrali, S. H.; Gazeli, K.; Clément, F.; Antimisiaris, S. G.

    2012-01-01

    The potential to use liposomes (LIPs) as a cellular model in order to study interactions of cold atmospheric-pressure plasma with cells is herein investigated. Cold atmospheric-pressure plasma is formed by a dielectric-barrier discharge reactor. Large multilamellar vesicle liposomes, consisted of phosphatidylcholine and cholesterol, are prepared by the thin film hydration technique, to encapsulate a small hydrophilic dye, i.e., calcein. The plasma-induced release of calcein from liposomes is then used as a measure of liposome membrane integrity and, consequently, interaction between the cold atmospheric plasma and lipid bilayers. Physical mechanisms leading to membrane disruption are suggested, based on the plasma characterization including gas temperature calculation.

  20. Ultrasound enhanced plasma surface modification at atmospheric pressure

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Singh, Shailendra Vikram; Norrman, Kion

    and the material surface, and thus many reactive species generated in the plasma can reach the surface before inactivated, and be efficiently utilized for surface modification. In the present work polyester plates are treated using a dielectric barrier discharge (DBD) and a gliding arc at atmospheric pressure......Atmospheric pressure plasma treatment can be highly enhanced by simultaneous high-power ultrasonic irradiation onto the treating surface. It is because ultrasonic waves with a sound pressure level (SPL) above approximately 140 dB can reduce the thickness of a boundary gas layer between the plasma...... irradiation, the water contact angle dropped markedly, and tended to decrease furthermore at higher power. The ultrasonic irradiation during the plasma treatment consistently improved the wettability. Oxygen containing polar functional groups were introduced at the surface by the plasma treatment...

  1. Atmospheric pressure loading parameters from very long baseline interferometry observations

    Science.gov (United States)

    Macmillan, D. S.; Gipson, John M.

    1994-01-01

    Atmospheric mass loading produces a primarily vertical displacement of the Earth's crust. This displacement is correlated with surface pressure and is large enough to be detected by very long baseline interferometry (VLBI) measurements. Using the measured surface pressure at VLBI stations, we have estimated the atmospheric loading term for each station location directly from VLBI data acquired from 1979 to 1992. Our estimates of the vertical sensitivity to change in pressure range from 0 to -0.6 mm/mbar depending on the station. These estimates agree with inverted barometer model calculations (Manabe et al., 1991; vanDam and Herring, 1994) of the vertical displacement sensitivity computed by convolving actual pressure distributions with loading Green's functions. The pressure sensitivity tends to be smaller for stations near the coast, which is consistent with the inverted barometer hypothesis. Applying this estimated pressure loading correction in standard VLBI geodetic analysis improves the repeatability of estimated lengths of 25 out of 37 baselines that were measured at least 50 times. In a root-sum-square (rss) sense, the improvement generally increases with baseline length at a rate of about 0.3 to 0.6 ppb depending on whether the baseline stations are close to the coast. For the 5998-km baseline from Westford, Massachusetts, to Wettzell, Germany, the rss improvement is about 3.6 mm out of 11.0 mm. The average rss reduction of the vertical scatter for inland stations ranges from 2.7 to 5.4 mm.

  2. ATMOSPHERE PRESSURE EFFECT ON THE FIBER OPTIC GYROSCOPE OUTPUT SYGNAL

    Directory of Open Access Journals (Sweden)

    Ilya A. Sharkov

    2017-05-01

    Full Text Available The paper describes research results of the atmospheric pressure effect on the output signal of a fiber optic gyroscope (FOG. In the course of experiments, FOG was placed into a hermetic chamber. The atmosphere pressure was varying in the range from 0.8 to 1.5 atm. All the data, including the FOG output signal, temperature, and data from the pressure sensor installed inside the FOG, were synchronously registered with the computer software. The separation of scale factor change from zero offset in the experiment was carried out by setting the sensitive FOG axis at 0°, 90° and 270° relative to the East (the FOG was set perpendicular to the horizon. After the data processing it was concluded that the FOG signal error associated with the pressure affects mainly on the additive component. The pressure effect on the multiplicative component appeared to be negligible at rotational velocities used in the experiment (0 - 130 /h. At the same time, the FOG signal has a high linear correlation coefficient with the derivative of pressure over time (in some cases, more than 0.9. The experiment was repeated several times and the high degree of the drift repeatability was shown. That makes it possible to implement the compensation algorithm. Application of the simplest algorithmic compensation based on the polynomial of the first degree (ax + b enabled to reduce the root-mean-square (RMS and drift of the signal by 2-9 times.

  3. The driving frequency effects on the atmospheric pressure corona jet plasmas from low frequency to radio frequency

    International Nuclear Information System (INIS)

    Kim, Dan Bee; Jung, H.; Gweon, B.; Rhee, J. K.; Choe, W.; Moon, S. Y.

    2011-01-01

    Lately, the atmospheric pressure jet type corona plasma, which has been typically driven by dc to low frequency (LF: several tens of kHz), is often generated by using radio frequency of 13.56 MHz. Yet, the relationship between the plasma and its driving frequency has seldom been investigated. Hence, in this study, dependence of the atmospheric pressure corona plasma characteristics on the driving frequency was explored experimentally from LF to rf (5 kHz-13.56 MHz). The plasmas generated by the driving frequency under 2 MHz were cylindrical shape of several tens of millimeters long while the 13.56 MHz plasma is spherical and a few millimeters long. As the driving frequency was increased, the plasma length became shortened. At the lower driving frequencies (below 2 MHz), the plasmas existed as positive streamer and negative glow for each half period of the applied voltage, but the discharge was more continuous in time for the 13.56 MHz plasma. It was inferred from the measured I-V curves that the higher driving frequency induced higher discharge currents, and the gas temperature was increased as the driving frequency was increased.

  4. Easy to implement diagnostics of a glow dielectric barrier discharge

    International Nuclear Information System (INIS)

    Massines, F.; Segur, P.

    2001-01-01

    It is relatively easier to generate plasma at atmospheric pressure rather than low pressure. In retaliation, due to the short mean free path of different particles, the diagnostics giving microscopic characteristics are more difficult to implement. This, for example, is the case of Langmuir probe or mass spectrometry although solutions have been put forward. Likewise, the strong contribution of the excited state quenching can render optical characterization result interpretation difficult. Nevertheless, there are easy to implement basic diagnostics like optical emission spectroscopy, the ultra rapid photography or the discharge current measurement. A possible approach to get to the microscopic data consists in associating the experimental results with the results of a numerical model. This is the approach undertaken for the study of a glow dielectric barrier discharge (DBD) and is described in the following text in order to illustrate the possibilities of those easy to implement diagnostics supported by the analysis of surfaces having interacted with the plasma

  5. Basic principles and applications of atmospheric-pressure discharge plasmas

    International Nuclear Information System (INIS)

    Becker, K.H.

    2002-01-01

    The principles that govern the generation and maintenance of atmospheric - pressure discharge plasmas are summarized. The properties and operating parameters of various types such as dielectric barrier discharge plasmas (DBDs), corona discharge plasmas (CDs), microhollow cathode discharge plasmas (MHCDs) , and dielectric capillary electrode discharge plasmas (CDEDs) are introduced. All of them are self sustained, non equilibrium gas discharges that can be operated at atmospheric pressure. CDs and DBDDs represent very similar types of discharges, while DBDs are characterized by insulating layers on one or both electrodes, CDs depend on inhomogeneous electric fields at least in some parts of the electrode configuration to restrict the primary ionization processes to a small fraction of the inter - electrode region. Their application to novel light sources in the ultraviolet (UV) and vacuum ultraviolet (VUV) spectral region is described. (nevyjel)

  6. A Study on Decontamination Process Using Atmospheric Pressure Plasma

    International Nuclear Information System (INIS)

    Kim, Yong Soo; Jeon, Sang Hwan; Jin, Dong Sik; Park, Dong Min

    2010-05-01

    Radioactive decontamination process using atmospheric pressure plasma which can be operated parallel with low vacuum cold plasma processing is studied. Two types of cold plasma torches were designed and manufactured. One of them is the cylindrical type applicable to the treatment of three-dimensional surfaces. The other is the rectangular type for the treatment of flat and large surface areas. Ar palsam was unstable but using He as a carrier gas, discharge condition was improved. Besides filtering module using pre, medium, charcoal, and HEPA filter was designed and manufactured. More intensive study for developing filtering system will be followed. Atmospheric pressure plasma decontamination process can be used to the equipment and facility wall decontamination

  7. Characterization of DC argon plasma jet at atmospheric pressure

    International Nuclear Information System (INIS)

    Yan Jianhua; Ma Zengyi; Pan Xinchao; Cen Kefa; Bruno, C

    2006-01-01

    An original DC double anode plasma torch operating with argon at atmospheric pressure which provides a long time and highly stable plasma jet is analyzed through its electrical and optical signals. Effects of gas flow rate and current intensity on the arc dynamics behaviour are studied using standard diagnostic tools such as FFT and correlation function. An increasing current-voltage characteristic is reported for different argon flow rates. It is noted that the takeover mode is characteristic for argon plasma jet and arc fluctuations in our case are mainly induced by the undulation of torch power supply. Furthermore, the excitation temperatures and electron densities of the plasma jet inside and outside the arc chamber have been determined by means of optical emission spectroscopy (OES). The criteria for the existence of local thermodynamic equilibrium (LTE) in plasma is then discussed. The results show that argon plasma jet at atmospheric pressure under our experimental conditions is close to LTE. (authors)

  8. Atmospheric sugar alcohols: evaporation rates and saturation vapor pressures

    DEFF Research Database (Denmark)

    Bilde, Merete; Zardini, Alessandro Alessio; Hong, Juan

    alcohols. These polyols are common in the water soluble fraction of atmospheric aerosols. In our experimental system sub-micron particles are generated by nebulization from aqueous solution, and a mono disperse fraction of the aerosol is selected using a differential mobility analyzer. The particles......The atmospheric partitioning between gas and condensed phase of organic molecules is poorly understood, and discrepancies exist between predicted and observed concentrations of secondary organic aerosols. A key problem is the lack of information about thermodynamic properties of semi- and low...... volatile organic molecules. Saturation vapor pressure and the associated temperature dependence (dH) are key parameters for improving predictive atmospheric models. In this work we combine experiments and thermodynamic modeling to investigate these parameters for a series of polyols, so-called sugar...

  9. Structural bifurcation of microwave helium jet discharge at atmospheric pressure

    International Nuclear Information System (INIS)

    Takamura, Shuichi; Kitoh, Masakazu; Soga, Tadasuke

    2008-01-01

    Structural bifurcation of microwave-sustained jet discharge at atmospheric gas pressure was found to produce a stable helium plasma jet, which may open the possibility of a new type of high-flux test plasma beam for plasma-wall interactions in fusion devices. The fundamental discharge properties are presented including hysteresis characteristics, imaging of discharge emissive structure, and stable ignition parameter area. (author)

  10. Use of Atmospheric Pressure Cold Plasma for Meat Industry

    OpenAIRE

    Lee, Juri; Lee, Cheol Woo; Yong, Hae In; Lee, Hyun Jung; Jo, Cheorun; Jung, Samooel

    2017-01-01

    Novel, effective methods to control and prevent spoilage and contamination by pathogenic microorganisms in meat and meat products are in constant demand. Non-thermal pasteurization is an ideal method for the preservation of meat and meat products because it does not use heat during the pasteurization process. Atmospheric pressure cold plasma (APCP) is a new technology for the non-thermal pasteurization of meat and meat products. Several recent studies have shown that APCP treatment reduces th...

  11. Transmission geometry laserspray ionization vacuum using an atmospheric pressure inlet.

    Science.gov (United States)

    Lutomski, Corinne A; El-Baba, Tarick J; Inutan, Ellen D; Manly, Cory D; Wager-Miller, James; Mackie, Ken; Trimpin, Sarah

    2014-07-01

    This represents the first report of laserspray ionization vacuum (LSIV) with operation directly from atmospheric pressure for use in mass spectrometry. Two different types of electrospray ionization source inlets were converted to LSIV sources by equipping the entrance of the atmospheric pressure inlet aperture with a customized cone that is sealed with a removable glass plate holding the matrix/analyte sample. A laser aligned in transmission geometry (at 180° relative to the inlet) ablates the matrix/analyte sample deposited on the vacuum side of the glass slide. Laser ablation from vacuum requires lower inlet temperature relative to laser ablation at atmospheric pressure. However, higher inlet temperature is required for high-mass analytes, for example, α-chymotrypsinogen (25.6 kDa). Labile compounds such as gangliosides and cardiolipins are detected in the negative ion mode directly from mouse brain tissue as intact doubly deprotonated ions. Multiple charging enhances the ion mobility spectrometry separation of ions derived from complex tissue samples.

  12. Atmospheric pressure plasma jet treatment of Salmonella Enteritidis inoculated eggshells.

    Science.gov (United States)

    Moritz, Maike; Wiacek, Claudia; Koethe, Martin; Braun, Peggy G

    2017-03-20

    Contamination of eggshells with Salmonella Enteritidis remains a food safety concern. In many cases human salmonellosis within the EU can be traced back to raw or undercooked eggs and egg products. Atmospheric pressure plasma is a novel decontamination method that can reduce a wide range of pathogens. The aim of this work was to evaluate the possibility of using an effective short time cold plasma treatment to inactivate Salmonella Enteritidis on the eggshell. Therefore, artificially contaminated eggshells were treated with an atmospheric pressure plasma jet under different experimental settings with various exposure times (15-300s), distances from the plasma jet nozzle to the eggshell surface (5, 8 or 12mm), feed gas compositions (Ar, Ar with 0.2, 0.5 or 1.0% O 2 ), gas flow rates (5 and 7slm) and different inoculations of Salmonella Enteritidis (10 1 -10 6 CFU/cm 2 ). Atmospheric pressure plasma could reduce Salmonella Enteritidis on eggshells significantly. Reduction factors ranged between 0.22 and 2.27 log CFU (colony-forming units). Exposure time and, particularly at 10 4 CFU/cm 2 inoculation, feed gas had a major impact on Salmonella reduction. Precisely, longer exposure times led to higher reductions and Ar as feed gas was more effective than ArO 2 mixtures. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Infrared laser ablation atmospheric pressure photoionization mass spectrometry.

    Science.gov (United States)

    Vaikkinen, Anu; Shrestha, Bindesh; Kauppila, Tiina J; Vertes, Akos; Kostiainen, Risto

    2012-02-07

    In this paper we introduce laser ablation atmospheric pressure photoionization (LAAPPI), a novel atmospheric pressure ion source for mass spectrometry. In LAAPPI the analytes are ablated from water-rich solid samples or from aqueous solutions with an infrared (IR) laser running at 2.94 μm wavelength. Approximately 12 mm above the sample surface, the ablation plume is intercepted with an orthogonal hot solvent (e.g., toluene or anisole) jet, which is generated by a heated nebulizer microchip and directed toward the mass spectrometer inlet. The ablated analytes are desolvated and ionized in the gas-phase by atmospheric pressure photoionization using a 10 eV vacuum ultraviolet krypton discharge lamp. The effect of operational parameters and spray solvent on the performance of LAAPPI is studied. LAAPPI offers ~300 μm lateral resolution comparable to, e.g., matrix-assisted laser desorption ionization. In addition to polar compounds, LAAPPI efficiently ionizes neutral and nonpolar compounds. The bioanalytical application of the method is demonstrated by the direct LAAPPI analysis of rat brain tissue sections and sour orange (Citrus aurantium) leaves. © 2012 American Chemical Society

  14. Stimulation of wound healing by helium atmospheric pressure plasma treatment

    International Nuclear Information System (INIS)

    Nastuta, Andrei Vasile; Topala, Ionut; Pohoata, Valentin; Popa, Gheorghe; Grigoras, Constantin

    2011-01-01

    New experiments using atmospheric pressure plasma have found large application in treatment of living cells or tissues, wound healing, cancerous cell apoptosis, blood coagulation on wounds, bone tissue modification, sterilization and decontamination. In this study an atmospheric pressure plasma jet generated using a cylindrical dielectric-barrier discharge was applied for treatment of burned wounds on Wistar rats' skin. The low temperature plasma jet works in helium and is driven by high voltage pulses. Oxygen and nitrogen based impurities are identified in the jet by emission spectroscopy. This paper analyses the natural epithelization of the rats' skin wounds and two methods of assisted epithelization, a classical one using polyurethane wound dressing and a new one using daily atmospheric pressure plasma treatment of wounds. Systemic and local medical data, such as haematological, biochemical and histological parameters, were monitored during entire period of study. Increased oxidative stress was observed for plasma treated wound. This result can be related to the presence in the plasma volume of active species, such as O and OH radicals. Both methods, wound dressing and plasma-assisted epithelization, provided positive medical results related to the recovery process of burned wounds. The dynamics of the skin regeneration process was modified: the epidermis re-epitelization was accelerated, while the recovery of superficial dermis was slowed down.

  15. Sterilization and decontamination of surfaces using atmospheric pressure plasma discharges

    Energy Technology Data Exchange (ETDEWEB)

    Garate, E.; Gornostaeva, O.; Alexeff, I.; Kang, W.L.

    1999-07-01

    The goal of the program is to demonstrate that an atmospheric pressure plasma discharge can rapidly and effectively sterilize or decontaminate surfaces that are contaminated with model biological and chemical warfare agents. The plasma is produced by corona discharge from an array of pins and a ground plane. The array is constructed so that various gases, like argon or helium, can be flowed past the pins where the discharge is initiated. The pin array can be biased using either DC. AC or pulsed discharges. the work done to date has focused on the sterilization of aluminum, polished steel and tantalum foil metal coupons, about 2 cm on a side and 2 mm thick, which have been inoculated with up to 10{sup 6} spores per coupon of Bacillus subtilis var niger or Bascillus stearothermorphilus. Results indicate that 5 minute exposures to the atmospheric pressure plasma discharge can reduce the viable spore count by 4 orders of magnitude. The atmospheric pressure discharge is also effective in decomposing organic phosphate compounds that are stimulants for chemical warfare agents. Details of the decomposition chemistry, by-product formation, and electrical energy consumption of the system will be discussed.

  16. Atmospheric pressure loading effects on Global Positioning System coordinate determinations

    Science.gov (United States)

    Vandam, Tonie M.; Blewitt, Geoffrey; Heflin, Michael B.

    1994-01-01

    Earth deformation signals caused by atmospheric pressure loading are detected in vertical position estimates at Global Positioning System (GPS) stations. Surface displacements due to changes in atmospheric pressure account for up to 24% of the total variance in the GPS height estimates. The detected loading signals are larger at higher latitudes where pressure variations are greatest; the largest effect is observed at Fairbanks, Alaska (latitude 65 deg), with a signal root mean square (RMS) of 5 mm. Out of 19 continuously operating GPS sites (with a mean of 281 daily solutions per site), 18 show a positive correlation between the GPS vertical estimates and the modeled loading displacements. Accounting for loading reduces the variance of the vertical station positions on 12 of the 19 sites investigated. Removing the modeled pressure loading from GPS determinations of baseline length for baselines longer than 6000 km reduces the variance on 73 of the 117 baselines investigated. The slight increase in variance for some of the sites and baselines is consistent with expected statistical fluctuations. The results from most stations are consistent with approximately 65% of the modeled pressure load being found in the GPS vertical position measurements. Removing an annual signal from both the measured heights and the modeled load time series leaves this value unchanged. The source of the remaining discrepancy between the modeled and observed loading signal may be the result of (1) anisotropic effects in the Earth's loading response, (2) errors in GPS estimates of tropospheric delay, (3) errors in the surface pressure data, or (4) annual signals in the time series of loading and station heights. In addition, we find that using site dependent coefficients, determined by fitting local pressure to the modeled radial displacements, reduces the variance of the measured station heights as well as or better than using the global convolution sum.

  17. GlowPhones

    DEFF Research Database (Denmark)

    Merritt, Timothy Robert; Nielsen, Christine Linding; Jakobsen, Frederik Lund

    2017-01-01

    Location-based mobile games often utilize built-in sensors for supporting game experiences tied to the physical world, yet the visual user interface remains constrained to the small high-resolution screen. GlowPhones is a location-based mobile social game using low-resolution displays to augment...... the physical space and move the attention away from the mobile screen. Players explore the physical world and collaborate to overcome challenges relying on the screen glow intensity emitted from the phone’s screen and light flash frequency of the camera flash for navigation. Three game stages explore proxemics...

  18. Time and space variability of spectral estimates of atmospheric pressure

    Science.gov (United States)

    Canavero, Flavio G.; Einaudi, Franco

    1987-01-01

    The temporal and spatial behaviors of atmospheric pressure spectra over the northern Italy and the Alpine massif were analyzed using data on surface pressure measurements carried out at two microbarograph stations in the Po Valley, one 50 km south of the Alps, the other in the foothills of the Dolomites. The first 15 days of the study overlapped with the Alpex Intensive Observation Period. The pressure records were found to be intrinsically nonstationary and were found to display substantial time variability, implying that the statistical moments depend on time. The shape and the energy content of spectra depended on different time segments. In addition, important differences existed between spectra obtained at the two stations, indicating a substantial effect of topography, particularly for periods less than 40 min.

  19. Two-dimensional simulation of argon dielectric barrier discharge excited by a Gaussian voltage at atmospheric pressure

    Science.gov (United States)

    Xu, Yonggang; Wang, Jing; Li, Jing; Lei, Bingying; Tang, Jie; Wang, Yishan; Li, Yongfang; Zhao, Wei; Duan, Yixiang

    2017-04-01

    A two-dimensional self-consistent fluid model was employed to investigate the spatiotemporal characteristics of discharges in atmospheric pressure argon (Ar) dielectric barrier discharge driven by a Gaussian voltage. The simulation results show that a discharge with multiple current pulses occurs each half-cycle in the gas gap. A transition from the Townsend mode to the glow mode is observed with the increasing applied voltage each half-cycle at a lower driving frequency (7.5 kHz). It is also found that the glow mode survives all the discharge phases at a higher driving frequency (12.5 kHz and 40 kHz). The change in the discharge mode with the driving frequency mainly lies in the fact that a lot of charged particles created in the discharge gap have no enough time to drift and diffuse around, and then these particles are assembled in the discharge space at higher frequency. Additionally, the spatial distributions of the electron density indicate that a center-advantage discharge is ignited at the driving frequencies of interest, resulting in the radial non-uniformity of discharge because of the edge effects. However, this overall non-uniformity is weakened with the driving frequency increased to 40 kHz, at which concentric ring patterns are observed. These distinct behaviors are mainly attributed to the fact that many charged particles generated are trapped in the gas gap and then accumulated to make the extension along the radial direction due to the charged particles transport and diffusion, and that the effective overlapping of a large number of avalanches induced by the increased "seed" electron density with the driving frequency. Meanwhile, the surface charged particles accumulated on the dielectric barriers are also shown to play a role in the formation of the discharge structure.

  20. The updated bottom up solution applied to atmospheric pressure photoionization and electrospray ionization mass spectrometry

    Science.gov (United States)

    The Updated Bottom Up Solution (UBUS) was recently applied to atmospheric pressure chemical ionization (APCI) mass spectrometry (MS) of triacylglycerols (TAGs). This report demonstrates that the UBUS applies equally well to atmospheric pressure photoionization (APPI) MS and to electrospray ionizatio...

  1. Atmospheric Pressure Effect of Retained Gas in High Level Waste

    International Nuclear Information System (INIS)

    Weber, A.H.

    1999-01-01

    Isolated high level waste tanks in H-Area have unexplained changes in waste-level which have been attributed to environmental effects including pressure, temperature, and relative humidity. Previous studies at SRS have considered waste-level changes from causes not including the presence of gas in the salt cake. This study was undertaken to determine the effect of atmospheric pressure on gas in the salt cake and resultant changes in the supernate level of Tank 41H, and to model that effect if possible. A simple theory has been developed to account for changes in the supernate level in a high level waste tank containing damp salt cake as the response of trapped gases to changes in the ambient pressure. The gas is modeled as an ideal gas retained as bubbles within the interstitial spaces in the salt cake and distributed uniformly throughout the tank. The model does not account for consistent long term increases or decreases in the tank level. Any such trend in the tank level is attributed to changes in the liquid content in the tank (from condensation, evaporation, etc.) and is removed from the data prior to the void estimation. Short term fluctuations in the tank level are explained as the response of the entrained gas volume to changes in the ambient pressure. The model uses the response of the tank level to pressure changes to estimate an average void fraction for the time period of interest. This estimate of the void is then used to predict the expected level response. The theory was applied to three separate time periods of the level data for tank 41H as follows: (1) May 3, 1993 through August 3, 1993, (2) January 23, 1994 through April 21, 1994, and (3) June 4, 1994 through August 24, 1994. A strong correlation was found between fluctuations in the tank level and variations in the ambient pressure. This correlation is a clear marker of the presence of entrained gases in the tank. From model calculations, an average void fraction of 11 percent was estimated to

  2. Fabrication of Al doped ZnO films using atmospheric pressure cold plasma

    International Nuclear Information System (INIS)

    Suzaki, Yoshifumi; Miyagawa, Hayato; Yamaguchi, Kenzo; Kim, Yoon-Kee

    2012-01-01

    Under atmospheric pressure, homogeneous non-equilibrium cold plasma was generated stably by high voltage pulsed power (1 kV, 20 kHz, 38 W) excitation of a mixture of He and O 2 gases produced by a dielectric barrier discharge setup. By feeding Bis (2 methoxy‐6-methyl‐3, 5-heptanedione) Zn (Zn-MOPD, C 18 H 3 O 6 Zn) and Tris (2-methoxy‐6‐methy l‐3, 5-heptanedione) Al (Al-MOPD, C 27 H 45 O 9 Al) into this plasma with He carrier gas, transparent flat Al-doped ZnO (ZnO:Al) films about 120–240 nm thick were prepared on glass substrates directly under the slit made into the cathode. Deposition rates of the films were about 20–40 nm/min. The concentration of Al was measured by inductively coupled plasma atomic emission spectroscopy. The composition ratio of Al to Zn was 7.8 mol% when the carrier He gas flow rate of Al-MOPD was 30 cm 3 . The average transmittance of all films was more than 85% in the wavelength range from 400 to 800 nm. When the composition ratio of Al/Zn was between 1.1 and 7.8 mol%, the optical band gap of the film increased from 3.28 to 3.40 eV. The resistivity of ZnO:Al film was 2.96 Ω cm at 1.3 mol% of Al/Zn. In addition, the microstructure of the films was studied by X-ray diffraction measurement and field emission scanning electron microscope observation. It was revealed that doped Al is substituted onto the Zn site of the ZnO crystalline structure in ZnO:Al films. - Highlights: ► An atmospheric pressure cold plasma generator generated stable glow discharge. ► We fabricated Al doped ZnO films on glass substrates using cold plasma. ► Al concentration measured by inductively coupled plasma atomic emission spectroscopy. ► The transmission spectrum and the resistivity of the films were measured. ► The microstructure of the films was studied.

  3. Expansion of the cathode spot and generation of shock waves in the plasma of a volume discharge in atmospheric-pressure helium

    International Nuclear Information System (INIS)

    Omarov, O. A.; Kurbanismailov, V. S.; Arslanbekov, M. A.; Gadzhiev, M. Kh.; Ragimkhanov, G. B.; Al-Shatravi, Ali J. G.

    2012-01-01

    The expansion of the cathode spot and the generation of shock waves during the formation and development of a pulsed volume discharge in atmospheric-pressure helium were studied by analyzing the emission spectra of the cathode plasma and the spatiotemporal behavior of the plasma glow. The transition of a diffuse volume discharge in a centimeter-long gap into a high-current diffuse mode when the gas pressure increased from 1 to 5 atm and the applied voltage rose from the statistical breakdown voltage to a 100% overvoltage was investigated. Analytical expressions for the radius of the cathode spot and its expansion velocity obtained in the framework of a spherically symmetric model agree satisfactorily with the experimental data.

  4. Atmospheric Pressure Plasma Induced Sterilization and Chemical Neutralization

    Science.gov (United States)

    Garate, Eusebio; Evans, Kirk; Gornostaeva, Olga; Alexeff, Igor; Lock Kang, Weng; Wood, Thomas K.

    1998-11-01

    We are studying chemical neutralization and surface decontamination using atmospheric pressure plasma discharges. The plasma is produced by corona discharge from an array of pins and a ground plane. The array is constructed so that various gases, like argon or helium, can be flowed past the pins where the discharge is initiated. The pin array can be biased using either DC, AC or pulsed discharges. Results indicate that the atmospheric plasma is effective in sterilizing surfaces with biological contaminants like E-coli and bacillus subtilus cells. Exposure times of less than four minutes in an air plasma result in a decrease in live colony counts by six orders of magnitude. Greater exposure times result in a decrease of live colony counts of up to ten orders of magnitude. The atmospheric pressure discharge is also effective in decomposing organic phosphate compounds that are simulants for chemical warfare agents. Details of the decomposition chemistry, by-product formation, and electrical energy consumption of the system will be discussed.

  5. Glow discharge in singlet oxygen

    International Nuclear Information System (INIS)

    Vagin, N.P.; Ionin, A.A.; Klimachev, Yu.M.; Sinitsyn, D.V.; Yuryshev, N.N.; Kochetov, I.V.; Napartovich, A.P.

    2003-01-01

    Currently, there is no experimental data on the plasma balance in gas mixtures with a high content of singlet delta oxygen O 2 ( 1 Δ g ). These data can be obtained by studying the parameters of an electric discharge in singlet oxygen produced by a chemical generator. The O 2 ( 1 Δ g ) molecules significantly change the kinetics of electrons and negative ions in plasma. Hence, the discharge conditions at low and high O 2 ( 1 Δ g ) concentrations are very different. Here, the parameters of the positive column of a glow discharge in a gas flow from a chemical singlet-oxygen generator are studied. It is experimentally shown that, at an O 2 ( 1 Δ g ) concentration of 50% and at pressures of 1.5 and 2 torr, the electric field required to sustain the discharge is considerably lower than in the case when all of the oxygen molecules are in the ground state. A theoretical model of the glow discharge is proposed whose predictions are in good agreement with the experimental data

  6. When API Mass Spectrometry Meets Super Atmospheric Pressure Ion Sources

    Science.gov (United States)

    Chen, Lee Chuin

    2015-01-01

    In a tutorial paper on the application of free-jet technique for API-MS, John Fenn mentioned that “…for a number of years and a number of reasons, it has been found advantageous in many situations to carry out the ionization process in gas at pressures up to 1000 Torr or more” (Int. J. Mass Spectrom. 200: 459–478, 2000). In fact, the first ESI mass spectrometer constructed by Yamashita and Fenn had a counter-flow curtain gas source at 1050 Torr (ca. 1.4 atm) to sweep away the neutral (J. Phys. Chem. 88: 4451–4459, 1984). For gaseous ionization using electrospray plume, theoretical analysis also shows that “super-atmospheric operation would be more preferable in space-charge-limited situations.”(Int. J. Mass Spectrom. 300: 182–193, 2011). However, electrospray and the corona-based chemical ion source (APCI) in most commercial instrument are basically operated under an atmospheric pressure ambient, perhaps out of the concern of safety, convenience and simplicity in maintenance. Running the ion source at pressure much higher than 1 atm is not so common, but had been done by a number of groups as well as in our laboratory. A brief review on these ion sources will be given in this paper. PMID:26819912

  7. Driven Motion and Instability of an Atmospheric Pressure Arc

    International Nuclear Information System (INIS)

    Max Karasik

    1999-01-01

    Atmospheric pressure arcs are used extensively in applications such as welding and metallurgy. However, comparatively little is known of the physics of such arcs in external magnetic fields and the mechanisms of the instabilities present. In order to address questions of equilibrium and stability of such arcs, an experimental arc furnace is constructed and operated in air with graphite cathode and steel anode at currents 100-250 A. The arc is diagnosed with a gated intensified camera and a collimated photodiode array, as well as fast voltage and current probes

  8. Electrode erosion in arc discharges at atmospheric pressure

    Science.gov (United States)

    Hardy, T. L.

    1985-01-01

    An experimental investigation was performed in an effort to measure and increase lifetime of electrodes in an arcjet thruster. The electrode erosion of various anode and cathode materials was measured after tests in an atmospheric pressure nitrogen arc discharge at powers less than 1 kW. A free-burning arc configuration and a constricted arc configuration were used to test the materials. Lanthanum hexboride and thoriated tungsten had low cathode erosion rates while thoriated tungsten and pure tungsten had the lowest anode erosion rates of the materials tested. Anode cooling, reverse gas flow, an external magnetic fields were all found to reduce electrode mass loss.

  9. Driven Motion and Instability of an Atmospheric Pressure Arc

    Energy Technology Data Exchange (ETDEWEB)

    Max Karasik

    1999-12-01

    Atmospheric pressure arcs are used extensively in applications such as welding and metallurgy. However, comparatively little is known of the physics of such arcs in external magnetic fields and the mechanisms of the instabilities present. In order to address questions of equilibrium and stability of such arcs, an experimental arc furnace is constructed and operated in air with graphite cathode and steel anode at currents 100-250 A. The arc is diagnosed with a gated intensified camera and a collimated photodiode array, as well as fast voltage and current probes.

  10. Electrical characterization of atmospheric pressure DBD in air

    International Nuclear Information System (INIS)

    Shrestha, P.; Joshi, U.M.; Subedi, D.P.

    2013-01-01

    Atmospheric pressure dielectric barrier discharge (DBD) in air was generated between two rectangular copper electrodes covering the lower electrode with a dielectric (glass or polycarbonate -PC) using low frequency (line frequency-50Hz) high voltage power supply. The discharge was studied for inter-electrode gap spacing in the range of 2 mm – 5 mm and their influence on breakdown voltage. Voltage-current characteristics and the analysis of the distribution of current pulses per half cycle of the current waveform indicated that the discharge is more uniform in 3 mm inter-electrode gap spacing with PC as a dielectric rather than glass. (author)

  11. Marangoni flows induced by atmospheric-pressure plasma jets

    International Nuclear Information System (INIS)

    Berendsen, C W J; Van Veldhuizen, E M; Kroesen, G M W; Darhuber, A A

    2015-01-01

    We studied the interaction of atmospheric-pressure plasma jets of Ar or air with liquid films of an aliphatic hydrocarbon on moving solid substrates. The hydrodynamic jet-liquid interaction induces a track of lower film thickness. The chemical plasma-surface interaction oxidizes the liquid, leading to a local increase of the surface tension and a self-organized redistribution of the liquid film. We developed a numerical model that qualitatively reproduces the formation, instability and coarsening of the flow patterns observed in the experiments. Monitoring the liquid flow has potential as an in-situ, spatially and temporally resolved, diagnostic tool for the plasma-liquid surface interaction. (paper)

  12. Generation of subnanosecond electron beams in air at atmospheric pressure

    Science.gov (United States)

    Kostyrya, I. D.; Tarasenko, V. F.; Baksht, E. Kh.; Burachenko, A. G.; Lomaev, M. I.; Rybka, D. V.

    2009-11-01

    Optimum conditions for the generation of runaway electron beams with maximum current amplitudes and densities in nanosecond pulsed discharges in air at atmospheric pressure are determined. A supershort avalanche electron beam (SAEB) with a current amplitude of ˜30 A, a current density of ˜20 A/cm2, and a pulse full width at half maximum (FWHM) of ˜100 ps has been observed behind the output foil of an air-filled diode. It is shown that the position of the SAEB current maximum relative to the voltage pulse front exhibits a time shift that varies when the small-size collector is moved over the foil surface.

  13. Atmospheric pressure cold plasma as an antifungal therapy

    International Nuclear Information System (INIS)

    Sun Peng; Wu Haiyan; Sun Yi; Liu Wei; Li Ruoyu; Zhu Weidong; Lopez, Jose L.; Zhang Jue; Fang Jing

    2011-01-01

    A microhollow cathode based, direct-current, atmospheric pressure, He/O 2 (2%) cold plasma microjet was used to inactive antifungal resistants Candida albicans, Candida krusei, and Candida glabrata in air and in water. Effective inactivation (>90%) was achieved in 10 min in air and 1 min in water. Antifungal susceptibility tests showed drastic reduction of the minimum inhibitory concentration after plasma treatment. The inactivation was attributed to the reactive oxygen species generated in plasma or in water. Hydroxyl and singlet molecular oxygen radicals were detected in plasma-water system by electron spin resonance spectroscopy. This approach proposed a promising clinical dermatology therapy.

  14. Evaluation of the impact of atmospheric pressure in different seasons on blood pressure in patients with arterial hypertension.

    Science.gov (United States)

    Kamiński, Marek; Cieślik-Guerra, Urszula I; Kotas, Rafał; Mazur, Piotr; Marańda, Witold; Piotrowicz, Maciej; Sakowicz, Bartosz; Napieralski, Andrzej; Trzos, Ewa; Uznańska-Loch, Barbara; Rechciński, Tomasz; Kurpesa, Małgorzata

    2016-01-01

    Atmospheric pressure is the most objective weather factor because regardless of if outdoors or indoors it affects all objects in the same way. The majority of previous studies have used the average daily values of atmospheric pressure in a bioclimatic analysis and have found no correlation with blood pressure changes. The main objective of our research was to assess the relationship between atmospheric pressure recorded with a frequency of 1 measurement per minute and the results of 24-h blood pressure monitoring in patients with treated hypertension in different seasons in the moderate climate of the City of Łódź (Poland). The study group consisted of 1662 patients, divided into 2 equal groups (due to a lower and higher average value of atmospheric pressure). Comparisons between blood pressure values in the 2 groups were performed using the Mann-Whitney U test. We observed a significant difference in blood pressure recorded during the lower and higher range of atmospheric pressure: on the days of the spring months systolic (p = 0.043) and diastolic (p = 0.005) blood pressure, and at nights of the winter months systolic blood pressure (p = 0.013). A significant inverse relationship between atmospheric pressure and blood pressure during the spring days and, only for systolic blood pressure, during winter nights was observed. Int J Occup Med Environ Health 2016;29(5):783-792. This work is available in Open Access model and licensed under a CC BY-NC 3.0 PL license.

  15. Development of atmospheric pressure plasma needle jet for sterilization applications

    Science.gov (United States)

    Elfa, Rizan Rizon; Ahmad, Mohd Khairul; Soon, Chin Fhong; Sahdan, Mohd Zainizan; Lias, Jais; Wibowo, Kusnanto Mukti; Bakar, Ahmad Shuhaimi Abu; Arshad, Mohd Khairuddin Md; Hashim, Uda; Nayan, Nafarizal

    2017-09-01

    Inactivation of bacteria or sterilization has been a major issue in the medical field, especially regarding of human safety, whereby, in a huge scenario fatality can be caused by hazardous bacteria. Often, E-coli as gram-negative bacteria are selected as a key indicator of proper sterilization process as E-coli is tough and dormant bacteria. The technology in sterilization has moved on from chemical, wet and irradiation sterilization to a high promising device such as atmospheric pressure plasma needle jet (APPNJ). It has been reported that atmospheric pressure plasma has provided bundle of advantages over earlier sterilization process. The APPNJ is developed in our lab using high frequency and high voltage neon transformer power supply connected to copper needle and copper sheet electrodes. The gas discharge is Ar gas flowing at 40 L/min through a quartz glass tube. The E-coli bacteria are self-cultured from waste water and then treated with APPNJ. The treatment processes are run into two difference gaps between the plasma orifice and sample with various treatment times. Only 40s is required by direct treatment to achieve 100% killing of E-coli. On the other hand, indirect treatment has inactivated 50% of the E-coli in 40s. In this study, direct and indirect effect of APPNJ to the E-coli can be observed which can be utilized into sterilization of bio-compatible material applications.

  16. Atmospheric Pressure Plasma Treatment for Grey Cotton Knitted Fabric

    Directory of Open Access Journals (Sweden)

    Chi-wai Kan

    2018-01-01

    Full Text Available 100% grey cotton knitted fabric contains impurities and yellowness and needs to be prepared for processing to make it suitable for coloration and finishing. Therefore, conventionally 100% grey cotton knitted fabric undergoes a process of scouring and bleaching, which involves the use of large amounts of water and chemicals, in order to remove impurities and yellowness. Due to increased environmental awareness, pursuing a reduction of water and chemicals is a current trend in textile processing. In this study, we explore the possibility of using atmospheric pressure plasma as a dry process to treat 100% grey cotton knitted fabric (single jersey and interlock before processing. Experimental results reveal that atmospheric pressure plasma treatment can effectively remove impurities from 100% grey cotton knitted fabrics and significantly improve its water absorption property. On the other hand, if 100% grey cotton knitted fabrics are pretreated with plasma and then undergo a normal scouring process, the treatment time is reduced. In addition, the surface morphological and chemical changes in plasma-treated fabrics were studied and compared with the conventionally treated fabrics using scanning electron microscope (SEM, Fourier-transform infrared spectroscopy-attenuated total reflection (FTIR-ATR and X-ray photoelectron spectroscopy (XPS. The decrease in carbon content, as shown in XPS, reveal the removal of surface impurities. The oxygen-to-carbon (O/C ratios of the plasma treated knitted fabrics reveal enhanced hydrophilicity.

  17. Polythiophene films obtained by polymerization under atmospheric pressure plasma conditions

    Energy Technology Data Exchange (ETDEWEB)

    Teslaru, T.; Topala, I., E-mail: ionut.topala@uaic.ro; Dobromir, M.; Pohoata, V.; Curecheriu, L.; Dumitrascu, N.

    2016-02-01

    The present work describes the experimental arrangement used to initiate polymerization reactions of thiophene monomer based on a dielectric barrier discharge with plane – parallel geometry, working at atmospheric pressure in argon, in turn to obtain conductive polymeric films for different applications. The resulting plasma polymerized polythiophene (pPTh) film was characterized by FT-IR, UV–Vis, XPS spectroscopy, AFM and contact angle measurements. Characterization of pPTh films showed a higher hydrophobic character and roughness, as compared with films obtained by chemical methods, and the thickness is depending on polymerization duration. Also it can conclude that our samples represent oxidised state of pPTh. As a possible application, it analysed in situ the iodine absorption phenomenon in the pPTh matrix and its time evolution by UV–Vis spectroscopy. The presence of iodine 3d{sub 5/2} and 3d{sub 3/2} peaks in the pPTh sample after absorption was identified by XPS spectroscopy. The hydrophobic pPTh film is transformed in a super hydrophilic film after absorption of iodine vapors. - Highlights: • We obtained polythiophene films (pPTh) by atmospheric pressure plasma technique. • The pPTh films showed a hydrophobic character and conducting properties. • The pPTh films were used as sensor for iodine vapors in biological environment.

  18. Atmospheric-pressure plasma decontamination/sterilization chamber

    Science.gov (United States)

    Herrmann, Hans W.; Selwyn, Gary S.

    2001-01-01

    An atmospheric-pressure plasma decontamination/sterilization chamber is described. The apparatus is useful for decontaminating sensitive equipment and materials, such as electronics, optics and national treasures, which have been contaminated with chemical and/or biological warfare agents, such as anthrax, mustard blistering agent, VX nerve gas, and the like. There is currently no acceptable procedure for decontaminating such equipment. The apparatus may also be used for sterilization in the medical and food industries. Items to be decontaminated or sterilized are supported inside the chamber. Reactive gases containing atomic and metastable oxygen species are generated by an atmospheric-pressure plasma discharge in a He/O.sub.2 mixture and directed into the region of these items resulting in chemical reaction between the reactive species and organic substances. This reaction typically kills and/or neutralizes the contamination without damaging most equipment and materials. The plasma gases are recirculated through a closed-loop system to minimize the loss of helium and the possibility of escape of aerosolized harmful substances.

  19. Characterization of a steam plasma jet at atmospheric pressure

    International Nuclear Information System (INIS)

    Ni Guohua; Zhao Peng; Cheng Cheng; Song Ye; Meng Yuedong; Toyoda, Hirotaka

    2012-01-01

    An atmospheric steam plasma jet generated by an original dc water plasma torch is investigated using electrical and spectroscopic techniques. Because it directly uses the water used for cooling electrodes as the plasma-forming gas, the water plasma torch has high thermal efficiency and a compact structure. The operational features of the water plasma torch and the generation of the steam plasma jet are analyzed based on the temporal evolution of voltage, current and steam pressure in the arc chamber. The influence of the output characteristics of the power source, the fluctuation of the arc and current intensity on the unsteadiness of the steam plasma jet is studied. The restrike mode is identified as the fluctuation characteristic of the steam arc, which contributes significantly to the instabilities of the steam plasma jet. In addition, the emission spectroscopic technique is employed to diagnose the steam plasma. The axial distributions of plasma parameters in the steam plasma jet, such as gas temperature, excitation temperature and electron number density, are determined by the diatomic molecule OH fitting method, Boltzmann slope method and H β Stark broadening, respectively. The steam plasma jet at atmospheric pressure is found to be close to the local thermodynamic equilibrium (LTE) state by comparing the measured electron density with the threshold value of electron density for the LTE state. Moreover, based on the assumption of LTE, the axial distributions of reactive species in the steam plasma jet are estimated, which indicates that the steam plasma has high chemical activity.

  20. Hazardous gas treatment using atmospheric pressure microwave discharges

    International Nuclear Information System (INIS)

    Mizeraczyk, Jerzy; Jasinski, Mariusz; Zakrzewski, Zenon

    2005-01-01

    Atmospheric pressure microwave discharge methods and devices used for producing non-thermal plasmas for control of gaseous pollutants are described in this paper. The main part of the paper is concerned with microwave torch discharges (MTDs). Results of laboratory experiments on plasma abatement of several volatile organic compounds (VOCs) in their mixtures with either synthetic air or nitrogen in low (∼100 W) and moderate (200-400 W) microwave torch plasmas at atmospheric pressure are presented. Three types of MTD generators, i.e. low-power coaxial-line-based MTDs, moderate-power waveguide-based coaxial-line MTDs and moderate-power waveguide-based MTDs were used. The gas flow rate and microwave (2.45 GHz) power delivered to the discharge were in the range of 1-3 litre min -1 and 100-400 W, respectively. The concentrations of the processed gaseous pollutants were from several to several tens of per cent. The results showed that the MTD plasmas fully decomposed the VOCs at a relatively low energy cost. The energy efficiency of decomposition of several gaseous pollutants reached 1000 g (kW-h) -1 . This suggests that MTD plasmas can be useful tools for decomposition of highly concentrated VOCs

  1. Plasma Beam Interaction with Negative glow discharge

    International Nuclear Information System (INIS)

    El-Tayeb, H.A.; El-Gamal, H.A.

    2000-01-01

    A miniature coaxial gun has been used to study the effect of the energy spectrum of the ejected plasma on the interaction with negative glow region in a normal glow discharge. The peak discharge current flow between the coaxial electrodes was 5.25 K A as a single pulse with pulse duration of 60 MUs. Investigations are carried out with argon gas at pressure 0.4 Torr. The sheath thickness of the ejected plasma from the coaxial discharge was 6 cm with different densities and energies. The spectrum of electron energy varies between 6 eV and 1 eV, while the electron density varies between 5 x 10 12 cm -3 and 4x10 13 cm -3 . The peak velocity of the ejected plasma was 0. 8 x 10 5 cm sec -1 in the neutral argon atoms. Argon negative glow region used as base plasma has an electron temperature of 2.2 eV and electron density of 6.2 x10 7 cm -3 . It had been found that the velocity of the ejected plasma decreased when it moves in the negative glow region and its mean electron temperature decreased. The results are compared with the theory of beam interaction with cold plasma

  2. On the distribution of plasma parameters in RF glow discharge

    International Nuclear Information System (INIS)

    Ning Cheng; Liu Zuli; Liu Donghui; Han Caiyuan.

    1993-01-01

    A self-consistent numerical model based on the two-fluid equations for describing the transport of charged particles in the RF glow discharge is presented. For a plasma generator filled with low-pressure air and parallel-plate electrodes, the model is numerical solved. The space-time distribution of parameters and the spatial distribution of some time-averaged parameters in plasma, which show the physical picture of the RF glow discharge, are obtained

  3. Measurement of viscosity of gaseous mixtures at atmospheric pressure

    Science.gov (United States)

    Singh, J. J.; Mall, G. H.; Chegini, H.

    1986-01-01

    Coefficients of viscosity of various types of gas mixtures, including simulated natural-gas samples, have been measured at atmospheric pressure and room temperature using a modified capillary tube method. Pressure drops across the straight capillary tube section of a thermal mass flowmeter were measured for small, well-defined, volume flow rates for the test gases and for standard air. In this configuration, the flowmeter provides the volumetric flow rates as well as a well-characterized capillary section for differential pressure measurements across it. The coefficients of viscosity of the test gases were calculated using the reported value of 185.6 micro P for the viscosity of air. The coefficients of viscosity for the test mixtures were also calculated using Wilke's approximation of the Chapman-Enskog (C-E) theory. The experimental and calculated values for binary mixtures are in agreement within the reported accuracy of Wilke's approximation of the C-E theory. However, the agreement for multicomponent mixtures is less satisfactory, possible because of the limitations of Wilkes's approximation of the classical dilute-gas state model.

  4. Atmospheric-Pressure Plasma Cleaning of Contaminated Surfaces

    International Nuclear Information System (INIS)

    Hicks, Robert F.; Selwyn, Gary S.

    2001-01-01

    Project was to develop a low-cost, environmentally benign technology for the decontamination and decommissioning of transuranic waste. With the invention of the atmospheric-pressure plasma jet the goal was achieved. This device selectively etches heavy metals from surfaces, rendering objects radiation free and suitable for decommissioning. The volatile reaction products are captured on filters, which yields a tremendous reduction in the volume of the waste. Studies on tantalum, a surrogate material for plutonium, have shown that etch rate of 6.0 microns per minute can be achieved under mild conditions. Over the past three years, we have made numerous improvements in the design of the plasma jet. It may now be operated for hundreds of hours and not undergo any degradation in performance. Furthermore, small compact units have been developed, which are easily deployed in the field

  5. Sterilization of Turmeric by Atmospheric Pressure Dielectric Barrier Discharge Plasma

    International Nuclear Information System (INIS)

    Salarieh Setareh; Dorranian Davoud

    2013-01-01

    In this study atmospheric pressure dielectric barrier discharge (DBD) plasma has been employed for sterilizing dry turmeric powders. A 6 kV, 6 kHz frequency generator was used to generate plasma with Ar, Ar/O 2 , He, and He/O 2 gases between the 5 mm gap of two quartz covered electrodes. The complete sterilization time of samples due to plasma treatment was measured. The most important contaminant of turmeric is bacillus subtilis. The results show that the shortest sterilization time of 15 min is achieved by exposing the samples to Ar/O 2 plasma. Survival curves of samples are exponential functions of time and the addition of oxygen to plasma leads to a significant increase of the absolute value of time constant of the curves. Magnitudes of protein and DNA in treated samples were increased to a similar value for all samples. Taste, color, and solubility of samples were not changed after the plasma treatment

  6. Sterilization of Turmeric by Atmospheric Pressure Dielectric Barrier Discharge Plasma

    Science.gov (United States)

    Setareh, Salarieh; Davoud, Dorranian

    2013-11-01

    In this study atmospheric pressure dielectric barrier discharge (DBD) plasma has been employed for sterilizing dry turmeric powders. A 6 kV, 6 kHz frequency generator was used to generate plasma with Ar, Ar/O2, He, and He/O2 gases between the 5 mm gap of two quartz covered electrodes. The complete sterilization time of samples due to plasma treatment was measured. The most important contaminant of turmeric is bacillus subtilis. The results show that the shortest sterilization time of 15 min is achieved by exposing the samples to Ar/O2 plasma. Survival curves of samples are exponential functions of time and the addition of oxygen to plasma leads to a significant increase of the absolute value of time constant of the curves. Magnitudes of protein and DNA in treated samples were increased to a similar value for all samples. Taste, color, and solubility of samples were not changed after the plasma treatment.

  7. Electrical characterization of atmospheric pressure dielectric barrier discharge in air

    International Nuclear Information System (INIS)

    Shrestha, P.; Subedi, D.P.; Joshi, U.M.

    2013-01-01

    This paper reports the electrical characterization of dielectric barrier discharge produced at atmospheric pressure using a high voltage power supply operating at 50Hz. The characteristics of the discharge have been studied under different values as such applied voltage and the electrode gap width. The results presented in this work can be helpful in understanding the influence of dielectric material on the nature of the discharge. An attempt has also been made to investigate the influence of ballast resistor on the magnitude of discharge current and also the density of micro-discharges. Our results indicated that with this power supply and electrode geometry, a relatively more homogenous discharge is observed for 3 mm spacing. (author)

  8. Use of Atmospheric Pressure Cold Plasma for Meat Industry.

    Science.gov (United States)

    Lee, Juri; Lee, Cheol Woo; Yong, Hae In; Lee, Hyun Jung; Jo, Cheorun; Jung, Samooel

    2017-01-01

    Novel, effective methods to control and prevent spoilage and contamination by pathogenic microorganisms in meat and meat products are in constant demand. Non-thermal pasteurization is an ideal method for the preservation of meat and meat products because it does not use heat during the pasteurization process. Atmospheric pressure cold plasma (APCP) is a new technology for the non-thermal pasteurization of meat and meat products. Several recent studies have shown that APCP treatment reduces the number of pathogenic microorganisms in meat and meat products. Furthermore, APCP treatment can be used to generate nitrite, which is an essential component of the curing process. Here, we introduce the effectiveness of APCP treatment as a pasteurization method and/or curing process for use in the meat and meat product processing industry.

  9. A Planar Source of Atmospheric-Pressure Plasma Jet

    Science.gov (United States)

    Zhdanova, O. S.; Kuznetsov, V. S.; Panarin, V. A.; Skakun, V. S.; Sosnin, E. A.; Tarasenko, V. F.

    2018-01-01

    In a single-barrier discharge with voltage sharpening and low gas consumption (up to 1 L/min), plane atmospheric pressure plasma jets with a width of up to 3 cm and length of up to 4 cm in air are formed in the slit geometry of the discharge zone. The energy, temperature, and spectral characteristics of the obtained jets have been measured. The radiation spectrum contains intense maxima corresponding to vibrational transitions of the second positive system of molecular nitrogen N2 ( C 3Π u → B 3Π g ) and comparatively weak transition lines of the first positive system of the N 2 + ion ( B 2Σ u + → X 2Σ g ). By an example of inactivation of the Staphylococcus aureus culture (strain ATCC 209), it is shown that plasma is a source of chemically active particles providing the inactivation of microorganisms.

  10. Atmospheric pressure DBD gun and its application in ink printability

    International Nuclear Information System (INIS)

    Chen Qiang; Zhang Yuefei; Han Erli; Ge Yuanjing

    2005-01-01

    In this paper, a plasma source discharging at atmospheric pressure and its characterization diagnosed by a Langmuir probe and a digital camera are presented. As an application the dielectric barrier discharge (DBD) gun modifying an ultraviolet cured resin surface for ink printability is reported. The results from the digital camera indicate the uniformity and homogeneity of the plasma generated from the gun in the downstream but depending on the input power, diameter of electrodes, gas flow rates and the distance between the substrates and the nozzle. The contact angle measurement proves the efficiency of gun during the surface modification. The ink printability following DBD gun processing described here was significantly improved. The performed surface analysis using Fourier transform infrared indicates that the polarity of surface grafted in plasma is responsible for the film printability

  11. Electron-ion recombination study in argon at atmospheric pressure

    International Nuclear Information System (INIS)

    Kafrouni, Hanna.

    1979-01-01

    This study deals with a wall-stabilized arc burning in argon at atmospheric pressure. A transient mode is obtained using a fast thyristor connected to the electrodes, which short-circuits the discharge. By means of two wavelengths laser interferometry and spectroscopy measurements we have determined the temporal changes of the electron density, ground state atom density and excited atom density. We have shown that, when the electric field is suppressed, the electron temperature rapidly decreases to the gas temperature before changing electron and atom densities. This phenomenon is applied to determine the gas temperature and to evaluate the role played by ionization in electron density balance. The coefficients of ambipolar diffusion, ionization and recombination and an apparent recombination coefficient are determined versus electron temperature and compared with theoretical values [fr

  12. Atmospheric pressure dielectric barrier discharges for sterilization and surface treatment

    Energy Technology Data Exchange (ETDEWEB)

    Chin, O. H.; Lai, C. K.; Choo, C. Y.; Wong, C. S.; Nor, R. M. [Plasma Technology Research Centre, Physics Department, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Thong, K. L. [Microbiology Division, Institute of Biological Sciences, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2015-04-24

    Atmospheric pressure non-thermal dielectric barrier discharges can be generated in different configurations for different applications. For sterilization, a parallel-plate electrode configuration with glass dielectric that discharges in air was used. Gram-negative bacteria (Escherichia coli and Salmonella enteritidis) and Gram-positive bacteria (Bacillus cereus) were successfully inactivated using sinusoidal high voltage of ∼15 kVp-p at 8.5 kHz. In the surface treatment, a hemisphere and disc electrode arrangement that allowed a plasma jet to be extruded under controlled nitrogen gas flow (at 9.2 kHz, 20 kVp-p) was applied to enhance the wettability of PET (Mylar) film.

  13. Electron Density in Atmospheric Pressure Microwave Surface Wave Discharges

    International Nuclear Information System (INIS)

    Jasinski, M.; Zakrzewski, Z.; Mizeraczyk, J.

    2008-01-01

    In this paper, we present results of the spectroscopic measurements of the electron density in a microwave surface wave sustained discharges in Ar and Ne at atmospheric pressure. The discharge in the form of a plasma column was generated inside a quartz tube cooled with a dielectric liquid. The microwave power delivered to the discharge via rectangular waveguide was applied in the range of 200-1500 W. In all investigations presented in this paper, the gas flow rate was relatively low (0.5 l/min), so the plasma column was generated in the form of a single filament, and the lengths of the upstream and downstream plasma columns were almost the same. The electron density in the plasma columns was determined using the method based on the Stark broadening of H β spectral line, including plasma region inside the waveguide which was not investigated earlier

  14. Acetonitrile Ion Suppression in Atmospheric Pressure Ionization Mass Spectrometry

    Science.gov (United States)

    Colizza, Kevin; Mahoney, Keira E.; Yevdokimov, Alexander V.; Smith, James L.; Oxley, Jimmie C.

    2016-11-01

    Efforts to analyze trace levels of cyclic peroxides by liquid chromatography/mass spectrometry gave evidence that acetonitrile suppressed ion formation. Further investigations extended this discovery to ketones, linear peroxides, esters, and possibly many other types of compounds, including triazole and menadione. Direct ionization suppression caused by acetonitrile was observed for multiple adduct types in both electrospray ionization and atmospheric pressure chemical ionization. The addition of only 2% acetonitrile significantly decreased the sensitivity of analyte response. Efforts to identify the mechanism were made using various nitriles. The ion suppression was reduced by substitution of an acetonitrile hydrogen with an electron-withdrawing group, but was exacerbated by electron-donating or steric groups adjacent to the nitrile. Although current theory does not explain this phenomenon, we propose that polar interactions between the various functionalities and the nitrile may be forming neutral aggregates that manifest as ionization suppression.

  15. Plasmid DNA damage induced by helium atmospheric pressure plasma jet

    Science.gov (United States)

    Han, Xu; Cantrell, William A.; Escobar, Erika E.; Ptasinska, Sylwia

    2014-03-01

    A helium atmospheric pressure plasma jet (APPJ) is applied to induce damage to aqueous plasmid DNA. The resulting fractions of the DNA conformers, which indicate intact molecules or DNA with single- or double-strand breaks, are determined using agarose gel electrophoresis. The DNA strand breaks increase with a decrease in the distance between the APPJ and DNA samples under two working conditions of the plasma source with different parameters of applied electric pulses. The damage level induced in the plasmid DNA is also enhanced with increased plasma irradiation time. The reactive species generated in the APPJ are characterized by optical emission spectra, and their roles in possible DNA damage processes occurring in an aqueous environment are also discussed.

  16. Atmospheric-Pressure Plasma Cleaning of Contaminated Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Robert F. Hicks; Gary S. Selwyn

    2001-01-09

    Project was to develop a low-cost, environmentally benign technology for the decontamination and decommissioning of transuranic waste. With the invention of the atmospheric-pressure plasma jet the goal was achieved. This device selectively etches heavy metals from surfaces, rendering objects radiation free and suitable for decommissioning. The volatile reaction products are captured on filters, which yields a tremendous reduction in the volume of the waste. Studies on tantalum, a surrogate material for plutonium, have shown that etch rate of 6.0 microns per minute can be achieved under mild conditions. Over the past three years, we have made numerous improvements in the design of the plasma jet. It may now be operated for hundreds of hours and not undergo any degradation in performance. Furthermore, small compact units have been developed, which are easily deployed in the field.

  17. Inverting Coseismic TEC Disturbances for Neutral Atmosphere Pressure Wave

    Science.gov (United States)

    Lee, R. F.; Mikesell, D.; Rolland, L.

    2017-12-01

    Research from the past 20 years has shown that we can detect coseismic disturbances in the total electron content (TEC) using global navigation space systems (GNSS). In the near field, TEC disturbances are created by the direct wave from rupture on the surface. This pressure wave travels through the neutral atmosphere to the ionosphere within about 10 minutes. This provides the opportunity to almost immediately characterize the source of the acoustic disturbance on the surface using methods from seismology. In populated areas, this could provide valuable information to first responders. To retrieve the surface motion amplitude information we must account for changes in the waveform caused by the geomagnetic field, motion of the satellites and the geometry of the satellites and receivers. One method is to use a transfer function to invert for the neutral atmosphere pressure wave. Gómez et al (2015) first employed an analytical model to invert for acoustic waves produced by Rayleigh waves propagating along the Earth's surface. Here, we examine the same model in the near field using the TEC disturbances from the direct wave produced by rupture at the surface. We compare results from the forward model against a numerical model that has been shown to be in good agreement with observations from the 2011 Van (Turkey) earthquake. We show the forward model predictions using both methods for the Van earthquake. We then analyze results for hypothetical events at different latitudes and discuss the reliability of the analytical model in each scenario. Gómez, D., R. Jr. Smalley, C. A. Langston, T. J. Wilson, M. Bevis, I. W. D. Dalziel, E. C. Kendrick, S. A. Konfal, M. J. Willis, D. A. Piñón, et al. (2015), Virtual array beamforming of GPS TEC observations of coseismic ionospheric disturbances near the Geomagnetic South Pole triggered by teleseismic megathrusts, J. Geophys. Res. Space Physics, 120, 9087-9101, doi:10.1002/2015JA021725.

  18. Sterilization of Surfaces with a Handheld Atmospheric Pressure Plasma

    Science.gov (United States)

    Hicks, Robert; Habib, Sara; Chan, Wai; Gonzalez, Eleazar; Tijerina, A.; Sloan, Mark

    2009-10-01

    Low temperature, atmospheric pressure plasmas have shown great promise for decontaminating the surfaces of materials and equipment. In this study, an atmospheric pressure, oxygen and argon plasma was investigated for the destruction of viruses, bacteria, and spores. The plasma was operated at an argon flow rate of 30 L/min, an oxygen flow rate of 20 mL/min, a power density of 101.0 W/cm^3 (beam area = 5.1 cm^2), and at a distance from the surface of 7.1 mm. An average 6log10 reduction of viable spores was obtained after only 45 seconds of exposure to the reactive gas. By contrast, it takes more than 35 minutes at 121^oC to sterilize anthrax in an autoclave. The plasma properties were investigated by numerical modeling and chemical titration with nitric oxide. The numerical model included a detailed reaction mechanism for the discharge as well as for the afterglow. It was predicted that at a delivered power density of 29.3 W/cm^3, 30 L/min argon, and 0.01 volume% O2, the plasma generated 1.9 x 10^14 cm-3 O atoms, 1.6 x 10^12 cm-3 ozone, 9.3 x 10^13 cm-3 O2(^1δg), and 2.9 x 10^12 cm-3 O2(^1σ^+g) at 1 cm downstream of the source. The O atom density measured by chemical titration with NO was 6.0 x 10^14 cm-3 at the same conditions. It is believe that the oxygen atoms and the O2(^1δg) metastables were responsible for killing the anthrax and other microorganisms.

  19. Atmospheric Pressure Effects on Cryogenic Storage Tank Boil-Off

    Science.gov (United States)

    Sass, J. P.; Frontier, C. R.

    2007-01-01

    The Cryogenics Test Laboratory (CTL) at the Kennedy Space Center (KSC) routinely utilizes cryostat test hardware to evaluate comparative and absolute thermal conductivities of a wide array of insulation systems. The test method is based on measurement of the flow rate of gas evolved due to evaporative boil-off of a cryogenic liquid. The gas flow rate typically stabilizes after a period of a couple of hours to a couple of days, depending upon the test setup. The stable flow rate value is then used to calculate the thermal conductivity for the insulation system being tested. The latest set of identical cryostats, 1,000-L spherical tanks, exhibited different behavior. On a macro level, the flow rate did stabilize after a couple of days; however the stable flow rate was oscillatory with peak to peak amplitude of up to 25 percent of the nominal value. The period of the oscillation was consistently 12 hours. The source of the oscillation has been traced to variations in atmospheric pressure due to atmospheric tides similar to oceanic tides. This paper will present analysis of this phenomenon, including a calculation that explains why other cryostats are not affected by it.

  20. Atmospheric temperature and pressure influence the onset of spontaneous pneumothorax.

    Science.gov (United States)

    Motono, Nozomu; Maeda, Sumiko; Honda, Ryumon; Tanaka, Makoto; Machida, Yuichiro; Usuda, Katsuo; Sagawa, Motoyasu; Uramoto, Hidetaka

    2018-02-01

    The aim of the study was to examine the influence of the changes in the atmospheric temperature (ATemp) and the atmospheric pressure (APres) on the occurrence of a spontaneous pneumothorax (SP). From January 2000 to March 2014, 192 consecutive SP events were examined. The ATemp and APres data at the onset of SP, as well as those data at 12, 24, 36, 48, 60, and 72 h prior to the onset time, were analyzed. The frequencies of SP occurrence were not statistically different according to the months or seasons, but were statistically different according to the time period (P < .01) and SP events occurred most frequently from 12:00 to 18:00. SP events frequently occurred at an ATemp of 25 degrees Celsius or higher. There was a significantly negative correlation between the APres and the ATemp at the SP onset time. The values of change in the APres from 36 to 24 h prior to SP onset were significantly lower than the preceding values. In this study, we observed that a SP event was likely to occur in the time period from 12:00 to 18:00, at an ATemp of 25 degrees Celsius or higher, and at 24-36 h after a drop of APres. © 2016 John Wiley & Sons Ltd.

  1. Non-equilibrium synergistic effects in atmospheric pressure plasmas.

    Science.gov (United States)

    Guo, Heng; Zhang, Xiao-Ning; Chen, Jian; Li, He-Ping; Ostrikov, Kostya Ken

    2018-03-19

    Non-equilibrium is one of the important features of an atmospheric gas discharge plasma. It involves complicated physical-chemical processes and plays a key role in various actual plasma processing. In this report, a novel complete non-equilibrium model is developed to reveal the non-equilibrium synergistic effects for the atmospheric-pressure low-temperature plasmas (AP-LTPs). It combines a thermal-chemical non-equilibrium fluid model for the quasi-neutral plasma region and a simplified sheath model for the electrode sheath region. The free-burning argon arc is selected as a model system because both the electrical-thermal-chemical equilibrium and non-equilibrium regions are involved simultaneously in this arc plasma system. The modeling results indicate for the first time that it is the strong and synergistic interactions among the mass, momentum and energy transfer processes that determine the self-consistent non-equilibrium characteristics of the AP-LTPs. An energy transfer process related to the non-uniform spatial distributions of the electron-to-heavy-particle temperature ratio has also been discovered for the first time. It has a significant influence for self-consistently predicting the transition region between the "hot" and "cold" equilibrium regions of an AP-LTP system. The modeling results would provide an instructive guidance for predicting and possibly controlling the non-equilibrium particle-energy transportation process in various AP-LTPs in future.

  2. Oxidation of 1020 steel in the abnormal glow discharge

    International Nuclear Information System (INIS)

    Zúñiga, J A García; Santos, A Sarmiento; Gómez, E Y Soto

    2017-01-01

    1020 steel is a material very used for surface treatment in the abnormal glow discharge. Because the composition of the gaseous atmosphere has an important influence on the results of plasma treatment, in this work the oxidation process of 1020 steel is verified on the abnormal glow discharge under different concentrations of air (20% to 100%) at temperatures of 600°C and 900°C. For each atmosphere used mass variation is measured during the process of surface oxidation, the structure and microstructure of the oxide film formed is observed and also its mechanical properties through its microhardness. (paper)

  3. The ionization mechanisms in direct and dopant-assisted atmospheric pressure photoionization and atmospheric pressure laser ionization.

    Science.gov (United States)

    Kauppila, Tiina J; Kersten, Hendrik; Benter, Thorsten

    2014-11-01

    A novel, gas-tight API interface for gas chromatography-mass spectrometry was used to study the ionization mechanism in direct and dopant-assisted atmospheric pressure photoionization (APPI) and atmospheric pressure laser ionization (APLI). Eight analytes (ethylbenzene, bromobenzene, naphthalene, anthracene, benzaldehyde, pyridine, quinolone, and acridine) with varying ionization energies (IEs) and proton affinities (PAs), and four common APPI dopants (toluene, acetone, anisole, and chlorobenzene) were chosen. All the studied compounds were ionized by direct APPI, forming mainly molecular ions. Addition of dopants suppressed the signal of the analytes with IEs above the IE of the dopant. For compounds with suitable IEs or Pas, the dopants increased the ionization efficiency as the analytes could be ionized through dopant-mediated gas-phase reactions, such as charge exchange, proton transfer, and other rather unexpected reactions, such as formation of [M + 77](+) in the presence of chlorobenzene. Experiments with deuterated toluene as the dopant verified that in case of proton transfer, the proton originated from the dopant instead of proton-bound solvent clusters, as in conventional open or non-tight APPI sources. In direct APLI using a 266 nm laser, a narrower range of compounds was ionized than in direct APPI, because of exceedingly high IEs or unfavorable two-photon absorption cross-sections. Introduction of dopants in the APLI system changed the ionization mechanism to similar dopant-mediated gas-phase reactions with the dopant as in APPI, which produced mainly ions of the same form as in APPI, and ionized a wider range of analytes than direct APLI.

  4. Ionization of EPA contaminants in direct and dopant-assisted atmospheric pressure photoionization and atmospheric pressure laser ionization.

    Science.gov (United States)

    Kauppila, Tiina J; Kersten, Hendrik; Benter, Thorsten

    2015-06-01

    Seventy-seven EPA priority environmental pollutants were analyzed using gas chromatography-mass spectrometry (GC-MS) equipped with an optimized atmospheric pressure photoionization (APPI) and an atmospheric pressure laser ionization (APLI) interface with and without dopants. The analyzed compounds included e.g., polycyclic aromatic hydrocarbons (PAHs), nitro compounds, halogenated compounds, aromatic compounds with phenolic, acidic, alcohol, and amino groups, phthalate and adipatic esters, and aliphatic ethers. Toluene, anisole, chlorobenzene, and acetone were tested as dopants. The widest range of analytes was ionized using direct APPI (66/77 compounds). The introduction of dopants decreased the amount of compounds ionized in APPI (e.g., 54/77 with toluene), but in many cases the ionization efficiency increased. While in direct APPI the formation of molecular ions via photoionization was the main ionization reaction, dopant-assisted (DA) APPI promoted ionization reactions, such as charge exchange and proton transfer. Direct APLI ionized a much smaller amount of compounds than APPI (41/77 compounds), showing selectivity towards compounds with low ionization energies (IEs) and long-lived resonantly excited intermediate states. DA-APLI, however, was able to ionize a higher amount of compounds (e.g. 51/77 with toluene), as the ionization took place entirely through dopant-assisted ion/molecule reactions similar to those in DA-APPI. Best ionization efficiency in APPI and APLI (both direct and DA) was obtained for PAHs and aromatics with O- and N-functionalities, whereas nitro compounds and aliphatic ethers were the most difficult to ionize. Halogenated aromatics and esters were (mainly) ionized in APPI, but not in APLI.

  5. Combined effects of γ-ray radiation and high atmospheric pressure on peripheral blood lymphocytes

    International Nuclear Information System (INIS)

    Zhu Bingchai; Lu Jiaben; Wang Zongwu; Chen Tiehe

    1989-01-01

    The combined effects of γ-ray radiation and high atmospheric pressure on chromosome aberration, micronucleus and transformation frequency in peripheral blood lymphocytes have been studied. The results indicated that there were no significant influence for effects of high atmospheric pressure on chromosome aberrations, transformation frequency in peripheral blood lymphocytes induced γ-ray radiation, and that high atmospheric pressure increased effect of micronucleus in human peripheral blood lymphocytes in vitro induced γ-ray radiation

  6. Micro glow plasma for localized nanostructural modification of carbon nanotube forest

    Energy Technology Data Exchange (ETDEWEB)

    Sarwar, Mirza Saquib us; Xiao, Zhiming; Saleh, Tanveer; Nojeh, Alireza; Takahata, Kenichi [University of British Columbia, Vancouver, British Columbia V6T 1Z4 (Canada)

    2016-08-22

    This paper reports the localized selective treatment of vertically aligned carbon nanotubes, or CNT forests, for radial size modification of the nanotubes through a micro-scale glow plasma established on the material. An atmospheric-pressure DC glow plasma is shown to be stably sustained on the surface of the CNT forest in argon using micromachined tungsten electrodes with diameters down to 100 μm. Experiments reveal thinning or thickening of the nanotubes under the micro glow depending on the process conditions including discharge current and process time. These thinning and thickening effects in the treated nanotubes are measured to be up to ∼30% and ∼300% in their diameter, respectively, under the tested conditions. The elemental and Raman analyses suggest that the treated region of the CNT forest is pure carbon and maintains a degree of crystallinity. The local plasma treatment process investigated may allow modification of material characteristics in different domains for targeted regions or patterns, potentially aiding custom design of micro-electro-mechanical systems and other emerging devices enabled by the CNT forest.

  7. A comparison of hydrogen vs. helium glow discharge effects on fusion device first-wall conditioning

    International Nuclear Information System (INIS)

    Dylla, H.F.

    1989-09-01

    Hydrogen- and deuterium-fueled glow discharges are used for the initial conditioning of magnetic fusion device vacuum vessels following evacuation from atmospheric pressure. Hydrogenic glow discharge conditioning (GDC) significantly reduces the near-surface concentration of simple adsorbates, such as H 2 O, CO, and CH 4 , and lowers ion-induced desorption coefficients by typically three orders of magnitude. The time evolution of the residual gas production observed during hydrogen-glow discharge conditioning of the carbon first-wall structure of the TFTR device is similar to the time evolution observed during hydrogen GDC of the initial first-wall configuration in TFTR, which was primarily stainless steel. Recently, helium GDC has been investigated for several wall-conditioning tasks on a number of tokamaks including TFTR. Helium GDC shows negligible impurity removal with stainless steel walls. For impurity conditioning with carbon walls, helium GDC shows significant desorption of H 2 O, CO, and CO 2 ; however, the total desorption yield is limited to the monolayer range. In addition, helium GDC can be used to displace hydrogen isotopes from the near-surface region of carbon first-walls in order to lower hydrogenic retention and recycling. 38 refs., 6 figs

  8. High Pressure Atmospheric Sampling Inlet System for Venus or the Gas Giants, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Thorleaf Research, Inc. proposes to develop a miniaturized high pressure atmospheric sampling inlet system for sample acquisition in extreme planetary environments,...

  9. Influence of atmospheric pressure on the incidence of spontaneous pneumothorax.

    Science.gov (United States)

    Díaz, Raúl; Díez, Manuel Mariano; Medrano, María José; Vera, Cristina; Guillamot, Paloma; Sánchez, Ana; Ratia, Tomás; Granell, Javier

    2014-01-01

    This study analyses the relationship between the incidence of idiopathic spontaneous pneumothorax (ISP) and atmospheric pressure (AP). A total of 288 cases of ISP were included, 229 men and 59 women. The AP of the day of diagnosis, of the 3 prior days and the monthly average was registered. The association between the incidence of ISP and AP was analyzed by calculating standardized incidence ratio (SIR) and Poisson regression. The AP on the day of admission (mean±standard deviation) (1,017.9±7 hectopascals [hPa]) was higher than the monthly average AP (1,016.9±4.1 hPa) (P=.005). There was a monthly distribution pattern of ISP with the highest incidence in the months of January, February and September and the lowest in April. When AP was less than 1,014 hPa, there were fewer cases registered than what would statistically have been expected (58/72 cases). In contrast, when the pressure was higher than 1,019 hPa, the registered cases were more than expected (109/82 cases) (SIR=1.25; 95% CI: 1.04 to 1.51). The risk of ISP increased 1.15 times (95% CI: 1.05 to 1.25, P=.001) for each hPa of AP, regardless of sex, age and monthly average AP. A dose-response relationship was observed, with progressive increases in risk (IRR=1.06 when the AP was 1,014-1016 hPa; 1.17 hPa when the AP was 1,016-1,019 hPa and 1.69 when AP was superior to 1,019 hPa) (P for trend=.089). The AP is a risk factor for the onset of idiopathic spontaneous pneumothorax. Copyright © 2012 AEC. Published by Elsevier Espana. All rights reserved.

  10. Blow-out limits of nonpremixed turbulent jet flames in a cross flow at atmospheric and sub-atmospheric pressures

    KAUST Repository

    Wang, Qiang

    2015-07-22

    The blow-out limits of nonpremixed turbulent jet flames in cross flows were studied, especially concerning the effect of ambient pressure, by conducting experiments at atmospheric and sub-atmospheric pressures. The combined effects of air flow and pressure were investigated by a series of experiments conducted in an especially built wind tunnel in Lhasa, a city on the Tibetan plateau where the altitude is 3650 m and the atmospheric pressure condition is naturally low (64 kPa). These results were compared with results obtained from a wind tunnel at standard atmospheric pressure (100 kPa) in Hefei city (altitude 50 m). The size of the fuel nozzles used in the experiments ranged from 3 to 8 mm in diameter and propane was used as the fuel. It was found that the blow-out limit of the air speed of the cross flow first increased (“cross flow dominant” regime) and then decreased (“fuel jet dominant” regime) as the fuel jet velocity increased in both pressures; however, the blow-out limit of the air speed of the cross flow was much lower at sub-atmospheric pressure than that at standard atmospheric pressure whereas the domain of the blow-out limit curve (in a plot of the air speed of the cross flow versus the fuel jet velocity) shrank as the pressure decreased. A theoretical model was developed to characterize the blow-out limit of nonpremixed jet flames in a cross flow based on a Damköhler number, defined as the ratio between the mixing time and the characteristic reaction time. A satisfactory correlation was obtained at relative strong cross flow conditions (“cross flow dominant” regime) that included the effects of the air speed of the cross flow, fuel jet velocity, nozzle diameter and pressure.

  11. Searching for order in atmospheric pressure plasma jets

    Science.gov (United States)

    Schäfer, Jan; Sigeneger, Florian; Šperka, Jiří; Rodenburg, Cornelia; Foest, Rüdiger

    2018-01-01

    The self-organized discharge behaviour occurring in a non-thermal radio-frequency plasma jet in rare gases at atmospheric pressure was investigated. The frequency of the azimuthal rotation of filaments in the active plasma volume and their inclination were measured along with the gas temperature under varying discharge conditions. The gas flow and heating were described theoretically by a three-dimensional hydrodynamic model. The rotation frequencies obtained by both methods qualitatively agree. The results demonstrate that the plasma filaments forming an inclination angle α with the axial gas velocity u z are forced to a transversal movement with the velocity {u}φ =\\tan (α )\\cdot {u}z, which is oriented in the inclination direction. Variations of {u}φ in the model reveal that the observed dynamics minimizes the energy loss due to convective heat transfer by the gas flow. The control of the self-organization regime motivates the application of the plasma jet for precise and reproducible material processing.

  12. Atmospheric pressure plasma-assisted femtosecond laser engraving of aluminium

    Science.gov (United States)

    Gerhard, Christoph; Gimpel, Thomas; Tasche, Daniel; Koch née Hoffmeister, Jennifer; Brückner, Stephan; Flachenecker, Günter; Wieneke, Stephan; Schade, Wolfgang; Viöl, Wolfgang

    2018-05-01

    In this contribution, we report on the impact of direct dielectric barrier discharge argon plasma at atmospheric pressure on femtosecond laser engraving of aluminium. It is shown that the assisting plasma strongly affects the surface geometry and formation of spikes of both laser-engraved single lines and patterns of adjacent lines with an appropriate overlap. Further, it was observed that the overall ablation depth is significantly increased in case of large-scale patterning whereas no notable differences in ablation depth are found for single lines. Several possible mechanisms and underlying effects of this behaviour are suggested. The increase in ablation depth is supposed to be due to a plasma-induced removal of debris particles from the cutting point via charging and oxidation as supported by EDX analysis of the re-solidified debris. Furthermore, the impact of a higher degree of surface wrinkling as well as direct interactions of plasma species with the aluminium surface on the ablation process are discussed.

  13. Pulsed, atmospheric pressure plasma source for emission spectrometry

    Science.gov (United States)

    Duan, Yixiang; Jin, Zhe; Su, Yongxuan

    2004-05-11

    A low-power, plasma source-based, portable molecular light emission generator/detector employing an atmospheric pressure pulsed-plasma for molecular fragmentation and excitation is described. The average power required for the operation of the plasma is between 0.02 W and 5 W. The features of the optical emission spectra obtained with the pulsed plasma source are significantly different from those obtained with direct current (dc) discharge higher power; for example, strong CH emission at 431.2 nm which is only weakly observed with dc plasma sources was observed, and the intense CN emission observed at 383-388 nm using dc plasma sources was weak in most cases. Strong CN emission was only observed using the present apparatus when compounds containing nitrogen, such as aniline were employed as samples. The present apparatus detects dimethylsulfoxide at 200 ppb using helium as the plasma gas by observing the emission band of the CH radical. When coupled with a gas chromatograph for separating components present in a sample to be analyzed, the present invention provides an apparatus for detecting the arrival of a particular component in the sample at the end of the chromatographic column and the identity thereof.

  14. Mass spectrometric diagnosis of an atmospheric pressure helium microplasma jet

    International Nuclear Information System (INIS)

    McKay, K; Oh, J-S; Walsh, J L; Bradley, J W

    2013-01-01

    Ambient molecular beam mass spectrometry (MBMS) has been used to study how different capillary widths (530 µm and 2.4 mm) and excitation waveforms (continuous wave kHz and pulsed dc) affect the ionic composition of atmospheric pressure plasma jets. It is shown from time-averaged ion intensities that reducing the width of the jet capillary results in a significant increase in the variety of both positive and negative ions detected within the discharge. We discuss this in terms of changes in flow velocity and the onset of turbulence within the plasma plume. Changing the mode of excitation had little effect on the ionic species detected from the microplasma jet; however, there was a notable shift in dominance towards higher mass ions when operated in a continuous wave kHz mode. The temporal evolution of the ions within the microplasma jet was observed for both excitation sources, operated at 5 and 15 kHz. Positive ions were created during periods correlated with the positive and negative peaks in discharge current, while negative ions were predominantly created at times when the discharge current peak was negative. This phenomenon was independent of the driving waveform. For pulsed dc excitation, considerably fewer positive ions were created in periods related to the negative current peaks, especially at higher frequencies. We propose a simple explanation for these processes based on ideas of streamer propagation and the influence of self-induced electric fields in the plasma plume. (paper)

  15. Investigation of the characteristics of atmospheric pressure surface barrier discharges

    International Nuclear Information System (INIS)

    Zhang Rui; Zhan Rujuan; Wen Xiaohui; Wang Lei

    2003-01-01

    Experiments were performed on atmospheric pressure surface barrier discharges. Two types of panels were used. Both have pectinate high voltage electrodes on their upper surface, but the difference is that in type I, the grounded electrode consists of the same pectinate electrodes on the lower surface, whereas type II has an extended grounded plane electrode on the lower surface. The excitation temperature was determined from a Fermi-Dirac model and a temperature near 0.7 eV is obtained. The electron density was estimated from an electrical conductivity approach (Ohmic heating model) - an equivalent circuit model is proposed and the electron density is found to be of the order of 10 11 cm -3 . The electrical behaviour was studied, and it was found that the average power consumed in the discharge plasma increases with increasing strip width in the type I discharge, whereas it remains almost constant with increasing strip width in the type II discharge. The average discharge power remains almost constant with variation in the strip-to-strip distance. The type II discharge consumes much higher average discharge power than type I. We also find that panels with a larger height of high voltage electrodes can generate brighter and thicker discharge plasmas. The equivalent circuit model was used to interpret these phenomena

  16. Using atmospheric pressure plasma treatment for treating grey cotton fabric.

    Science.gov (United States)

    Kan, Chi-Wai; Lam, Chui-Fung; Chan, Chee-Kooi; Ng, Sun-Pui

    2014-02-15

    Conventional wet treatment, desizing, scouring and bleaching, for grey cotton fabric involves the use of high water, chemical and energy consumption which may not be considered as a clean process. This study aims to investigate the efficiency of the atmospheric pressure plasma (APP) treatment on treating grey cotton fabric when compared with the conventional wet treatment. Grey cotton fabrics were treated with different combinations of plasma parameters with helium and oxygen gases and also through conventional desizing, scouring and bleaching processes in order to obtain comparable results. The results obtained from wicking and water drop tests showed that wettability of grey cotton fabrics was greatly improved after plasma treatment and yielded better results than conventional desizing and scouring. The weight reduction of plasma treated grey cotton fabrics revealed that plasma treatment can help remove sizing materials and impurities. Chemical and morphological changes in plasma treated samples were analysed by FTIR and SEM, respectively. Finally, dyeability of the plasma treated and conventional wet treated grey cotton fabrics was compared and the results showed that similar dyeing results were obtained. This can prove that plasma treatment would be another choice for treating grey cotton fabrics. Copyright © 2013 Elsevier Ltd. All rights reserved.

  17. Room-temperature atmospheric pressure plasma plume for biomedical applications

    International Nuclear Information System (INIS)

    Laroussi, M.; Lu, X.

    2005-01-01

    As low-temperature nonequilibrium plasmas come to play an increasing role in biomedical applications, reliable and user-friendly sources need to be developed. These plasma sources have to meet stringent requirements such as low temperature (at or near room temperature), no risk of arcing, operation at atmospheric pressure, preferably hand-held operation, low concentration of ozone generation, etc. In this letter, we present a device that meets exactly such requirements. This device is capable of generating a cold plasma plume several centimeters in length. It exhibits low power requirements as shown by its current-voltage characteristics. Using helium as a carrier gas, very little ozone is generated and the gas temperature, as measured by emission spectroscopy, remains at room temperature even after hours of operations. The plasma plume can be touched by bare hands and can be directed manually by a user to come in contact with delicate objects and materials including skin and dental gum without causing any heating or painful sensation

  18. Hydrocarbon analysis using desorption atmospheric pressure chemical ionization

    KAUST Repository

    Jjunju, Fred Paul Mark; Badu-Tawiah, Abraham K.; Li, Anyin; Soparawalla, Santosh; Roqan, Iman S.; Cooks, Robert Graham

    2013-01-01

    Characterization of the various petroleum constituents (hydronaphthalenes, thiophenes, alkyl substituted benzenes, pyridines, fluorenes, and polycyclic aromatic hydrocarbons) was achieved under ambient conditions without sample preparation by desorption atmospheric pressure chemical ionization (DAPCI). Conditions were chosen for the DAPCI experiments to control whether ionization was by proton or electron transfer. The protonated molecule [M+H]+ and the hydride abstracted [MH]+ form were observed when using an inert gas, typically nitrogen, to direct a lightly ionized plasma generated by corona discharge onto the sample surface in air. The abundant water cluster ions generated in this experiment react with condensed-phase functionalized hydrocarbon model compounds and their mixtures at or near the sample surface. On the other hand, when naphthalene was doped into the DAPCI gas stream, its radical cation served as a charge exchange reagent, yielding molecular radical cations (M+) of the hydrocarbons. This mode of sample ionization provided mass spectra with better signal/noise ratios and without unwanted side-products. It also extended the applicability of DAPCI to petroleum constituents which could not be analyzed through proton transfer (e.g., higher molecular PAHs such as chrysene). The thermochemistry governing the individual ionization processes is discussed and a desorption/ionization mechanism is inferred. © 2012 Elsevier B.V.

  19. Directional mass transport in an atmospheric pressure surface barrier discharge.

    Science.gov (United States)

    Dickenson, A; Morabit, Y; Hasan, M I; Walsh, J L

    2017-10-25

    In an atmospheric pressure surface barrier discharge the inherent physical separation between the plasma generation region and downstream point of application reduces the flux of reactive chemical species reaching the sample, potentially limiting application efficacy. This contribution explores the impact of manipulating the phase angle of the applied voltage to exert a level of control over the electrohydrodynamic forces generated by the plasma. As these forces produce a convective flow which is the primary mechanism of species transport, the technique facilitates the targeted delivery of reactive species to a downstream point without compromising the underpinning species generation mechanisms. Particle Imaging Velocimetry measurements are used to demonstrate that a phase shift between sinusoidal voltages applied to adjacent electrodes in a surface barrier discharge results in a significant deviation in the direction of the plasma induced gas flow. Using a two-dimensional numerical air plasma model, it is shown that the phase shift impacts the spatial distribution of the deposited charge on the dielectric surface between the adjacent electrodes. The modified surface charge distribution reduces the propagation length of the discharge ignited on the lagging electrode, causing an imbalance in the generated forces and consequently a variation in the direction of the resulting gas flow.

  20. Ga2O3 nanowires preparation at atmospheric pressure

    Directory of Open Access Journals (Sweden)

    Korbutowicz R.

    2017-07-01

    Full Text Available An attempt has been undertaken to produce gallium oxide nanowires by thermal synthesis from metallic gallium source at atmospheric pressure. Silicon substrates of (1 0 0 and (1 1 1 orientation with and without silicon oxide layers (0.5 μm were used as support. Evaporated thin gold films were deposited on the top of those silicon carriers as a catalytic agent. After thermal treatment by Rapid Thermal Processing RTP (at various temperatures and times, which was applied to make small Au islands with the diameters of about several tens of nanometers, the substrate surfaces were observed by SEM. The Ga2O3 syntheses were made at various conditions: time, temperature and gas mixture were changed. As a result, monoclinic gallium oxide β-Ga2O3 nanostructures with dominant [1 1 1] and [0 0 2] growth directions were grown. The obtained nanostructures of several tens micrometers length were studied by SEM, PL and X-ray methods.

  1. Atmospheric pressure plasma accelerates tail regeneration in tadpoles Xenopus laevis

    Science.gov (United States)

    Rivie, A.; Martus, K.; Menon, J.

    2017-08-01

    Atmospheric pressure plasma is a partially ionized gas composed of neutral and charged particles, including electrons and ions, as well as reactive oxygen species (ROS). Recently, it is utilized as possible therapy in oncology, sterilization, skin diseases, wound healing and tissue regeneration. In this study we focused on effect of plasma exposure on tail regeneration of tadpoles, Xenopus leavis with special emphasis on role of ROS, antioxidant defenses and morphological features of the regenerate. When amputated region of the tail was exposed to the helium plasma it resulted in a faster rate of growth, elevated ROS and increase in antioxidant enzymes in the regenerate compared to that of untreated control. An increase in nitric oxide (free radical) as well as activity of nitric oxide synthase(s) were observed once the cells of the regeneration blastema - a mass of proliferating cells are ready for differentiation. Microscopically the cells of the regenerate of plasma treated tadpoles show altered morphology and characteristics of cellular hypoxia and oxidative stress. We summarize that plasma exposure accelerates the dynamics of wound healing and tail regeneration through its effects on cell proliferation and differentiation as well as angiogenesis mediated through ROS signaling.

  2. Helium atmospheric pressure plasma jets touching dielectric and metal surfaces

    Science.gov (United States)

    Norberg, Seth A.; Johnsen, Eric; Kushner, Mark J.

    2015-07-01

    Atmospheric pressure plasma jets (APPJs) are being investigated in the context plasma medicine and biotechnology applications, and surface functionalization. The composition of the surface being treated ranges from plastics, liquids, and biological tissue, to metals. The dielectric constant of these materials ranges from as low as 1.5 for plastics to near 80 for liquids, and essentially infinite for metals. The electrical properties of the surface are not independent variables as the permittivity of the material being treated has an effect on the dynamics of the incident APPJ. In this paper, results are discussed from a computational investigation of the interaction of an APPJ incident onto materials of varying permittivity, and their impact on the discharge dynamics of the plasma jet. The computer model used in this investigation solves Poisson's equation, transport equations for charged and neutral species, the electron energy equation, and the Navier-Stokes equations for the neutral gas flow. The APPJ is sustained in He/O2 = 99.8/0.2 flowing into humid air, and is directed onto dielectric surfaces in contact with ground with dielectric constants ranging from 2 to 80, and a grounded metal surface. Low values of relative permittivity encourage propagation of the electric field into the treated material and formation and propagation of a surface ionization wave. High values of relative permittivity promote the restrike of the ionization wave and the formation of a conduction channel between the plasma discharge and the treated surface. The distribution of space charge surrounding the APPJ is discussed.

  3. Assessment of Atmospheric Pressure Plasma Treatment for Implant Osseointegration

    Directory of Open Access Journals (Sweden)

    Natalie R. Danna

    2015-01-01

    Full Text Available This study assessed the osseointegrative effects of atmospheric pressure plasma (APP surface treatment for implants in a canine model. Control surfaces were untreated textured titanium (Ti and calcium phosphate (CaP. Experimental surfaces were their 80-second air-based APP-treated counterparts. Physicochemical characterization was performed to assess topography, surface energy, and chemical composition. One implant from each control and experimental group (four in total was placed in one radius of each of the seven male beagles for three weeks, and one implant from each group was placed in the contralateral radius for six weeks. After sacrifice, bone-to-implant contact (BIC and bone area fraction occupancy (BAFO were assessed. X-ray photoelectron spectroscopy showed decreased surface levels of carbon and increased Ti and oxygen, and calcium and oxygen, posttreatment for Ti and CaP surfaces, respectively. There was a significant (P<0.001 increase in BIC for APP-treated textured Ti surfaces at six weeks but not at three weeks or for CaP surfaces. There were no significant (P=0.57 differences for BAFO between treated and untreated surfaces for either material at either time point. This suggests that air-based APP surface treatment may improve osseointegration of textured Ti surfaces but not CaP surfaces. Studies optimizing APP parameters and applications are warranted.

  4. Hydrocarbon analysis using desorption atmospheric pressure chemical ionization

    KAUST Repository

    Jjunju, Fred Paul Mark

    2013-07-01

    Characterization of the various petroleum constituents (hydronaphthalenes, thiophenes, alkyl substituted benzenes, pyridines, fluorenes, and polycyclic aromatic hydrocarbons) was achieved under ambient conditions without sample preparation by desorption atmospheric pressure chemical ionization (DAPCI). Conditions were chosen for the DAPCI experiments to control whether ionization was by proton or electron transfer. The protonated molecule [M+H]+ and the hydride abstracted [MH]+ form were observed when using an inert gas, typically nitrogen, to direct a lightly ionized plasma generated by corona discharge onto the sample surface in air. The abundant water cluster ions generated in this experiment react with condensed-phase functionalized hydrocarbon model compounds and their mixtures at or near the sample surface. On the other hand, when naphthalene was doped into the DAPCI gas stream, its radical cation served as a charge exchange reagent, yielding molecular radical cations (M+) of the hydrocarbons. This mode of sample ionization provided mass spectra with better signal/noise ratios and without unwanted side-products. It also extended the applicability of DAPCI to petroleum constituents which could not be analyzed through proton transfer (e.g., higher molecular PAHs such as chrysene). The thermochemistry governing the individual ionization processes is discussed and a desorption/ionization mechanism is inferred. © 2012 Elsevier B.V.

  5. Characteristics of Atmospheric Pressure Rotating Gliding Arc Plasmas

    Science.gov (United States)

    Zhang, Hao; Zhu, Fengsen; Tu, Xin; Bo, Zheng; Cen, Kefa; Li, Xiaodong

    2016-05-01

    In this work, a novel direct current (DC) atmospheric pressure rotating gliding arc (RGA) plasma reactor has been developed for plasma-assisted chemical reactions. The influence of the gas composition and the gas flow rate on the arc dynamic behaviour and the formation of reactive species in the N2 and air gliding arc plasmas has been investigated by means of electrical signals, high speed photography, and optical emission spectroscopic diagnostics. Compared to conventional gliding arc reactors with knife-shaped electrodes which generally require a high flow rate (e.g., 10-20 L/min) to maintain a long arc length and reasonable plasma discharge zone, in this RGA system, a lower gas flow rate (e.g., 2 L/min) can also generate a larger effective plasma reaction zone with a longer arc length for chemical reactions. Two different motion patterns can be clearly observed in the N2 and air RGA plasmas. The time-resolved arc voltage signals show that three different arc dynamic modes, the arc restrike mode, takeover mode, and combined modes, can be clearly identified in the RGA plasmas. The occurrence of different motion and arc dynamic modes is strongly dependent on the composition of the working gas and gas flow rate. supported by National Natural Science Foundation of China (No. 51576174), the Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20120101110099) and the Fundamental Research Funds for the Central Universities (No. 2015FZA4011)

  6. Atmospheric pressure arc discharge with ablating graphite anode

    International Nuclear Information System (INIS)

    Nemchinsky, V A; Raitses, Y

    2015-01-01

    The anodic carbon arc discharge is used to produce carbon nanoparticles. Recent experiments with the carbon arc at atmospheric pressure helium demonstrated the enhanced ablation rate for narrow graphite anodes resulting in high deposition rates of carbonaceous products on the copper cathode (Fetterman et al 2008 Carbon 46 1322–6). The proposed model explains these results with interconnected steady-state models of the cathode and the anode processes. When considering cathode functioning, the model predicts circulation of the particles in the near-cathode region: evaporation of the cathode material, ionization of evaporated atoms and molecules in the near-cathode plasma, return of the resulting ions to the cathode, surface recombination of ions and electrons followed again by cathode evaporation etc. In the case of the low anode ablation rate, the ion acceleration in the cathode sheath provides the major cathode heating mechanism. In the case of an intensive anode ablation, an additional cathode heating is due to latent fusion heat of the atomic species evaporated from the anode and depositing at the cathode. Using the experimental arc voltage as the only input discharge parameter, the model allows us to calculate the anode ablation rate. A comparison of the results of calculations with the available experimental data shows reasonable agreement. (paper)

  7. Atmospheric pressure arc discharge with ablating graphite anode

    Science.gov (United States)

    Nemchinsky, V. A.; Raitses, Y.

    2015-06-01

    The anodic carbon arc discharge is used to produce carbon nanoparticles. Recent experiments with the carbon arc at atmospheric pressure helium demonstrated the enhanced ablation rate for narrow graphite anodes resulting in high deposition rates of carbonaceous products on the copper cathode (Fetterman et al 2008 Carbon 46 1322-6). The proposed model explains these results with interconnected steady-state models of the cathode and the anode processes. When considering cathode functioning, the model predicts circulation of the particles in the near-cathode region: evaporation of the cathode material, ionization of evaporated atoms and molecules in the near-cathode plasma, return of the resulting ions to the cathode, surface recombination of ions and electrons followed again by cathode evaporation etc. In the case of the low anode ablation rate, the ion acceleration in the cathode sheath provides the major cathode heating mechanism. In the case of an intensive anode ablation, an additional cathode heating is due to latent fusion heat of the atomic species evaporated from the anode and depositing at the cathode. Using the experimental arc voltage as the only input discharge parameter, the model allows us to calculate the anode ablation rate. A comparison of the results of calculations with the available experimental data shows reasonable agreement.

  8. Influence of geomagnetic activity and atmospheric pressure on human arterial pressure during the solar cycle 24

    Science.gov (United States)

    Azcárate, T.; Mendoza, B.; Levi, J. R.

    2016-11-01

    We performed a study of the systolic (SBP) and diastolic (DBP) arterial blood pressure behavior under natural variables such as the atmospheric pressure (AtmP) and the horizontal geomagnetic field component (H). We worked with a sample of 304 healthy normotense volunteers, 152 men and 152 women, with ages between 18 and 84 years in Mexico City during the period 2008-2014, corresponding to the minimum, ascending and maximum phases of the solar cycle 24. The data was divided by gender, age and day/night cycle. We studied the time series using three methods: Correlations, bivariate and superposed epochs (within a window of three days around the day of occurrence of a geomagnetic storm) analysis, between the SBP and DBP and the natural variables (AtmP and H). The correlation analysis indicated correlation between the SBP and DBP and AtmP and H, being the largest during the night. Furthermore, the correlation and bivariate analysis showed that the largest correlations are between the SBP and DBP and the AtmP. The superposed epoch analysis found that the largest number of significant SBP and DBP changes occurred for women. Finally, the blood pressure changes are larger during the solar minimum and ascending solar cycle phases than during the solar maximum; the storms of the minimum were more intense than those of the maximum and this could be the reason of behavior of the blood pressure changes along the solar cycle.

  9. Atmospheric pressure X-ray photoelectron spectroscopy apparatus: Bridging the pressure gap

    Energy Technology Data Exchange (ETDEWEB)

    Velasco-Vélez, J. J., E-mail: velasco@fhi-berlin.mpg.de, E-mail: mh@fhi-berlin.mpg.de; Schlögl, R. [Department of Heterogeneous Reactions, Max Planck Institute for Chemical Energy Conversion, Mülheim an der Ruhr 45470 (Germany); Department of Inorganic Chemistry, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin 14195 (Germany); Pfeifer, V.; Algara-Siller, G.; Stotz, E.; Teschner, D.; Kube, P.; Knop-Gericke, A. [Department of Inorganic Chemistry, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin 14195 (Germany); Hävecker, M., E-mail: velasco@fhi-berlin.mpg.de, E-mail: mh@fhi-berlin.mpg.de; Skorupska, K. [Department of Heterogeneous Reactions, Max Planck Institute for Chemical Energy Conversion, Mülheim an der Ruhr 45470 (Germany); Wang, R.; Braeuninger-Weimer, P.; Hofmann, S. [Engineering Department, University of Cambridge, Cambridge CB3 0FA (United Kingdom); Centeno, A.; Zurutuza, A. [Graphenea, San Sebastian 20018 (Spain)

    2016-05-15

    One of the main goals in catalysis is the characterization of solid/gas interfaces in a reaction environment. The electronic structure and chemical composition of surfaces become heavily influenced by the surrounding environment. However, the lack of surface sensitive techniques that are able to monitor these modifications under high pressure conditions hinders the understanding of such processes. This limitation is known throughout the community as the “pressure gap.” We have developed a novel experimental setup that provides chemical information on a molecular level under atmospheric pressure and in presence of reactive gases and at elevated temperatures. This approach is based on separating the vacuum environment from the high-pressure environment by a silicon nitride grid—that contains an array of micrometer-sized holes—coated with a bilayer of graphene. Using this configuration, we have investigated the local electronic structure of catalysts by means of photoelectron spectroscopy and in presence of gases at 1 atm. The reaction products were monitored online by mass spectrometry and gas chromatography. The successful operation of this setup was demonstrated with three different examples: the oxidation/reduction reaction of iridium (noble metal) and copper (transition metal) nanoparticles and with the hydrogenation of propyne on Pd black catalyst (powder).

  10. Near 7-day response of ocean bottom pressure to atmospheric surface pressure and winds in the northern South China Sea

    Science.gov (United States)

    Zhang, Kun; Zhu, Xiao-Hua; Zhao, Ruixiang

    2018-02-01

    Ocean bottom pressures, observed by five pressure-recording inverted echo sounders (PIESs) from October 2012 to July 2014, exhibit strong near 7-day variability in the northern South China Sea (SCS) where long-term in situ bottom pressure observations are quite sparse. This variability was strongest in October 2013 during the near two years observation period. By joint analysis with European Center for Medium-Range Weather Forecasts (ECMWF) data, it is shown that the near 7-day ocean bottom pressure variability is closely related to the local atmospheric surface pressure and winds. Within a period band near 7 days, there are high coherences, exceeding 95% significance level, of observed ocean bottom pressure with local atmospheric surface pressure and with both zonal and meridional components of the wind. Ekman pumping/suction caused by the meridional component of the wind in particular, is suggested as one driving mechanism. A Kelvin wave response to the near 7-day oscillation would propagate down along the continental slope, observed at the Qui Nhon in the Vietnam. By multiple and partial coherence analyses, we find that local atmospheric surface pressure and Ekman pumping/suction show nearly equal influence on ocean bottom pressure variability at near 7-day periods. A schematic diagram representing an idealized model gives us a possible mechanism to explain the relationship between ocean bottom pressure and local atmospheric forcing at near 7-day periods in the northern SCS.

  11. Synthesis and atmospheric pressure field emission operation of W18O49 nanowires

    NARCIS (Netherlands)

    Agiral, A.; Gardeniers, Johannes G.E.

    2008-01-01

    Tungsten oxide W18O49 nanorods with diameters of 15−20 nm were grown on tungsten thin films exposed to ethene and nitrogen at 700 °C at atmospheric pressure. It was found that tungsten carbide formation enhances nucleation and growth of nanorods. Atmospheric pressure field emission measurements in

  12. The impact of relative humidity and atmospheric pressure on mortality in Guangzhou, China.

    Science.gov (United States)

    Ou, Chun Quan; Yang, Jun; Ou, Qiao Qun; Liu, Hua Zhang; Lin, Guo Zhen; Chen, Ping Yan; Qian, Jun; Guo, Yu Ming

    2014-12-01

    Although many studies have examined the effects of ambient temperatures on mortality, little evidence is on health impacts of atmospheric pressure and relative humidity. This study aimed to assess the impacts of atmospheric pressure and relative humidity on mortality in Guangzhou, China. This study included 213,737 registered deaths during 2003-2011 in Guangzhou, China. A quasi-Poisson regression with a distributed lag non-linear model was used to assess the effects of atmospheric pressure/relative humidity. We found significant effect of low atmospheric pressure/relative humidity on mortality. There was a 1.79% (95% confidence interval: 0.38%-3.22%) increase in non-accidental mortality and a 2.27% (0.07%-4.51%) increase in cardiovascular mortality comparing the 5th and 25th percentile of atmospheric pressure. A 3.97% (0.67%-7.39%) increase in cardiovascular mortality was also observed comparing the 5th and 25th percentile of relative humidity. Women were more vulnerable to decrease in atmospheric pressure and relative humidity than men. Age and education attainment were also potential effect modifiers. Furthermore, low atmospheric pressure and relative humidity increased temperature-related mortality. Both low atmospheric pressure and relative humidity are important risk factors of mortality. Our findings would be helpful to develop health risk assessment and climate policy interventions that would better protect vulnerable subgroups of the population. Copyright © 2014 The Editorial Board of Biomedical and Environmental Sciences. Published by China CDC. All rights reserved.

  13. Hydrophilic surface modification of coronary stent using an atmospheric pressure plasma jet for endothelialization.

    Science.gov (United States)

    Shim, Jae Won; Bae, In-Ho; Park, Dae Sung; Lee, So-Youn; Jang, Eun-Jae; Lim, Kyung-Seob; Park, Jun-Kyu; Kim, Ju Han; Jeong, Myung Ho

    2018-03-01

    The first two authors contributed equally to this study. Bioactivity and cell adhesion properties are major factors for fabricating medical devices such as coronary stents. The aim of this study was to evaluate the advantages of atmospheric-pressure plasma jet in enhancing the biocompatibility and endothelial cell-favorites. The experimental objects were divided into before and after atmospheric-pressure plasma jet treatment with the ratio of nitrogen:argon = 3:1, which is similar to air. The treated surfaces were basically characterized by means of a contact angle analyzer for the activation property on their surfaces. The effect of atmospheric-pressure plasma jet on cellular response was examined by endothelial cell adhesion and XTT analysis. It was difficult to detect any changeable morphology after atmospheric-pressure plasma jet treatment on the surface. The roughness was increased after atmospheric-pressure plasma jet treatment compared to nonatmospheric-pressure plasma jet treatment (86.781 and 7.964 nm, respectively). The X-ray photoelectron spectroscopy results showed that the surface concentration of the C-O groups increased slightly from 6% to 8% after plasma activation. The contact angle dramatically decreased in the atmospheric-pressure plasma jet treated group (22.6 ± 15.26°) compared to the nonatmospheric-pressure plasma jet treated group (72.4 ± 15.26°) ( n = 10, p atmospheric-pressure plasma jet on endothelial cell migration and proliferation was 85.2% ± 12.01% and 34.2% ± 2.68%, respectively, at 7 days, compared to the nonatmospheric-pressure plasma jet treated group (58.2% ± 11.44% in migration, n = 10, p atmospheric-pressure plasma jet method. Moreover, the atmospheric-pressure plasma jet might affect re-endothelialization after stenting.

  14. Pulsed microwave discharge at atmospheric pressure for NOx decomposition

    International Nuclear Information System (INIS)

    Baeva, M; Gier, H; Pott, A; Uhlenbusch, J; Hoeschele, J; Steinwandel, J

    2002-01-01

    A 3.0 GHz pulsed microwave source operated at atmospheric pressure with a pulse power of 1.4 MW, a maximum repetition rate of 40 Hz, and a pulse length of 3.5 μs is experimentally studied with respect to the ability to remove NO x from synthetic exhaust gases. Experiments in gas mixtures containing N 2 /O 2 /NO with typically 500 ppm NO are carried out. The discharge is embedded in a high-Q microwave resonator, which provides a reliable plasma ignition. Vortex flow is applied to the exhaust gas to improve gas treatment. Concentration measurements by Fourier transform infrared spectroscopy confirm an NO x reduction of more than 90% in the case of N 2 /NO mixtures. The admixture of oxygen lowers the reductive potential of the reactor, but NO x reduction can still be observed up to 9% O 2 concentration. Coherent anti-Stokes Raman scattering technique is applied to measure the vibrational and rotational temperature of N 2 . Gas temperatures of about 400 K are found, whilst the vibrational temperature is 3000-3500 K in pure N 2 . The vibrational temperature drops to 1500 K when O 2 and/or NO are present. The randomly distributed relative frequency of occurrence of selected breakdown field intensities is measured by a calibrated, short linear-antenna. The breakdown field strength in pure N 2 amounts to 2.2x10 6 V m -1 , a value that is reproducible within 2%. In the case of O 2 and/or NO admixture, the frequency distribution of the breakdown field strength scatters more and extends over a range from 3 to 8x10 6 V m -1

  15. Collaborative Research. Atmospheric Pressure Microplasma Chemistry-Photon Synergies

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sung-Jin [Univ. of Illinois, Urbana, IL (United States); Eden, James Gary [Univ. of Illinois, Urbana, IL (United States)

    2015-12-01

    Combining the effects of low temperature, atmospheric pressure microplasmas and microplasma photon sources offers the promise of greatly expanding the range of applications for each of them. The plasma sources create active chemical species and these can be activated further by the addition of photons and the associated photochemistry. There are many ways to combine the effects of plasma chemistry and photochemistry, especially if there are multiple phases present. This project combined the construction of appropriate test experimental systems, various spectroscopic diagnostics and mathematical modeling. Through a continuous discussion and co-design process with the UC-Berkeley Team, we have successfully completed the fabrication and testing of all components for a microplasma array-assisted system designed for photon-activated plasma chemistry research. Microcavity plasma lamps capable of generating more than 20 mW/cm2 at 172 nm (Xe dimer) were fabricated with a custom form factor to mate to the plasma chemistry setup, and a lamp was current being installed by the Berkeley team so as to investigate plasma chemistry-photon synergies at a higher photon energy (~7.2 eV) as compared to the UVA treatment that is afforded by UV LEDs operating at 365 nm. In particular, motivated by the promising results from the Berkeley team with UVA treatment, we also produced the first generation of lamps that can generate photons in the 300-370 nm wavelength range. Another set of experiments, conducted under the auspices of this grant, involved the use of plasma microjet arrays. The combination of the photons and excited radicals produced by the plasma column resulted in broad area deactivation of bacteria.

  16. Atmospheric Pressure Plasma Jet as an Accelerator of Tooth Bleaching

    Directory of Open Access Journals (Sweden)

    Vedran Šantak

    2014-01-01

    Full Text Available Objective: To study the effect of atmospheric pressure plasma (APP jet as a potential accelerator of the degradation of hydrogen peroxide in bleaching gels which could lead to better and faster bleaching. Material and Methods: 25 pastilles of hydroxylapatite were colored in green tea for 8 hours and were randomly divided into five groups (n = 5. The bleaching process was performed with 30% and 40% hydrogen peroxide (HP gel alone and in conjunction with helium APP jet. During the bleaching treatment, optical emission spectroscopy and non-contact surface temperature measurement using pyrometer were performed. Color of the pastilles was determined by a red– green–blue (RGB colorimeter. PH values of bleaching gels were measured before and after the plasma treatment on additional 10 pastilles using a pH meter with contact pH electrode. Results: The color measurements of pastilles before and after the treatment showed that treatment with APP jet improved the bleaching effect by 32% and 15% in the case of 30 % and 40% HP gel. Better results were obtained approximately six times faster than with a procedure suggested by the bleaching gel manufacturer. Optical emission spectroscopy proved that plasma has a chemically active role on the gel. After the APP treatment, pH values of bleaching gels dropped to about 50–75% of their initial value while the surface temperature increased by 8–10˚C above baseline. Conclusion: The use of plasma jet provides more effective bleaching results in a shorter period of time without a significant temperature increase which may cause damage of the surrounding tissue.

  17. Advancements, Challenges and Prospects of Chemical Vapour Pressure at Atmospheric Pressure on Vanadium Dioxide Structures

    Directory of Open Access Journals (Sweden)

    Charalampos Drosos

    2018-03-01

    Full Text Available Vanadium (IV oxide (VO2 layers have received extensive interest for applications in smart windows to batteries and gas sensors due to the multi-phases of the oxide. Among the methods utilized for their growth, chemical vapour deposition is a technology that is proven to be industrially competitive because of its simplicity when performed at atmospheric pressure (APCVD. APCVD’s success has shown that it is possible to create tough and stable materials in which their stoichiometry may be precisely controlled. Initially, we give a brief overview of the basic processes taking place during this procedure. Then, we present recent progress on experimental procedures for isolating different polymorphs of VO2. We outline emerging techniques and processes that yield in optimum characteristics for potentially useful layers. Finally, we discuss the possibility to grow 2D VO2 by APCVD.

  18. Improving the low temperature dyeability of polyethylene terephthalate fabric with dispersive dyes by atmospheric pressure plasma discharge

    International Nuclear Information System (INIS)

    Elabid, Amel E.A.; Zhang, Jie; Shi, Jianjun; Guo, Ying; Ding, Ke; Zhang, Jing

    2016-01-01

    Graphical abstract: - Highlights: • Atmospheric pressure glow-like plasma with fine and uniform filament discharge has been successfully applied to the low temperature dyeing (95 °C) of PET fabric. • Simultaneously the dye uptake was increased as twice as much and the color strength rate was increased by about 20% for less than 3 min plasma treated PET. • Dyeing mechanism research showed the significance of surface roughing and functional group introduction by this kind of discharge. • Results highlight a novel environmentally friendly dyeing process for one of the largest commodity in polymer fabric. - Abstract: Polyethylene terephthalate (PET) fiber and textile is one of the largest synthetic polymer commodity in the world. The great energy consumption and pollution caused by the high temperature and pressure dyeing of PET fibers and fabrics with disperse dyes has been caused concern these years. In this study, an atmospheric pressure plasma with fine and uniform filament discharge operated at 20 kHz has been used to improve the low temperature dyeability of PET fabric at 95 °C with three cation disperse dyes: Red 73, Blue 183 and Yellow 211. The dyes uptake percentage of the treated PET fabrics was observed to increase as twice as much of untreated fabric. The color strength rate was increased more than 20%. The reducing of the water contact angle and the raising of the capillary height of treated PET fabric strip indicate its hydrophilicity improvement. Scanning electron microscope (SEM) results display nano to micro size of etching pits appeared uniformly on the fiber surface of the treated PET. Simultaneously, X-ray photoelectron spectroscopy (XPS) analysis indicates an increase of the oxygen content in the surface caused by the introduction of polar groups such as C=O and COOH. The rough surface with improved polar oxygen groups showed hydrophilicity and affinity to C.I. dispersive dyes and is believed to be caused by the strong and very fine

  19. Novel Plasma Reactor with Rotary Helix Electrode Used in Coupling of CH4 at Atmospheric Pressure

    International Nuclear Information System (INIS)

    Wang Dawang; Ma Tengcai

    2006-01-01

    At the ambient temperature and pressure a glow discharge plasma was used as a new approach for the coupling of methane with the newly-developed rotary multidentate helix electrode. In the presence of hydrogen, the effects of the input peak voltages and gas flow rates on methane conversion, C 2 single pass yield and selectivity were investigated, and then the results were compared with those from the three-disc multidentate electrode. This demonstrated, on an experimental scale, that the rotary multidentate helix electrode was better than the multidentate three-disc electrode as there was little accumulation of coke, and the C 2 yield per pass was 69.85% and C 2 selectivity over 99.14% with 70.46% methane conversion at an input peak voltage of 2300 V and 60 ml/min gas flow rate

  20. Atmospheric-pressure plasma activation and surface characterization on polyethylene membrane separator

    Science.gov (United States)

    Tseng, Yu-Chien; Li, Hsiao-Ling; Huang, Chun

    2017-01-01

    The surface hydrophilic activation of a polyethylene membrane separator was achieved using an atmospheric-pressure plasma jet. The surface of the atmospheric-pressure-plasma-treated membrane separator was found to be highly hydrophilic realized by adjusting the plasma power input. The variations in membrane separator chemical structure were confirmed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Chemical analysis showed newly formed carbonyl-containing groups and high surface concentrations of oxygen-containing species on the atmospheric-pressure-plasma-treated polymeric separator surface. It also showed that surface hydrophilicity primarily increased from the polar component after atmospheric-pressure plasma treatment. The surface and pore structures of the polyethylene membrane separator were examined by scanning electron microscopy, revealing a slight alteration in the pore structure. As a result of the incorporation of polar functionalities by atmospheric-pressure plasma activation, the electrolyte uptake and electrochemical impedance of the atmospheric-pressure-plasma-treated membrane separator improved. The investigational results show that the separator surface can be controlled by atmospheric-pressure plasma surface treatment to tailor the hydrophilicity and enhance the electrochemical performance of lithium ion batteries.

  1. Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS): review.

    Science.gov (United States)

    Li, Du-Xin; Gan, Lin; Bronja, Amela; Schmitz, Oliver J

    2015-09-03

    Although the coupling of GC/MS with atmospheric pressure ionization (API) has been reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was expanded in the last decade. The demand of a "soft" ion source for preserving highly diagnostic molecular ion is desirable, as compared to the "hard" ionization technique such as electron ionization (EI) in traditional GC/MS, which fragments the molecule in an extensive way. These API sources include atmospheric pressure chemical ionization (APCI), atmospheric pressure photoionization (APPI), atmospheric pressure laser ionization (APLI), electrospray ionization (ESI) and low temperature plasma (LTP). This review discusses the advantages and drawbacks of this analytical platform. After an introduction in atmospheric pressure ionization the review gives an overview about the history and explains the mechanisms of various atmospheric pressure ionization techniques used in combination with GC such as APCI, APPI, APLI, ESI and LTP. Also new developments made in ion source geometry, ion source miniaturization and multipurpose ion source constructions are discussed and a comparison between GC-FID, GC-EI-MS and GC-API-MS shows the advantages and drawbacks of these techniques. The review ends with an overview of applications realized with GC-API-MS. Copyright © 2015. Published by Elsevier B.V.

  2. Electrostatic Properties of PE and PTFE Subjected to Atmospheric Pressure Plasma Treatment; Correlation of Experimental Results with Atomistic Modeling

    Science.gov (United States)

    Trigwell, Steve; Boucher, Derrick; Calle, Carlos

    2006-01-01

    The use of an atmospheric pressure glow discharge (APGD) plasma was used at KSC to increase the hydrophilicity of spaceport materials to enhance their surface charge dissipation and prevent possible ESD in spaceport operations. Significant decreases in charge decay times were observed after tribocharging the materials using the standard KSC tribocharging test. The polarity and amount of charge transferred was dependent upon the effective work function differences between the respective materials. In this study, polyethylene (PE) and polytetrafluoroethylene (PTFE) were exposed to a He+O2 APGD. The pre and post treatment surface chemistry was analyzed by X-ray photoelectron spectroscopy and contact angle measurements. Semi-empirical and ab initio calculations were performed to correlate the experimental results with some plausible molecular and electronic structure features of the oxidation process. For the PE, significant surface oxidation was observed, as indicated by XPS showing C-O, C=O, and O-C=O bonding, and a decrease in the surface contact angle from 98.9 deg to 61.2 deg. For the PTFE, no C-O bonding appeared and the surface contact angle increased indicating the APGD only succeeded in cleaning the PTFE surface without affecting the surface structure. The calculations using the PM3 and DFT methods were performed on single and multiple oligomers to simulate a wide variety of oxidation scenarios. Calculated work function results suggest that regardless of oxidation mechanism, e.g. -OH, =0 or a combination thereof, the experimentally observed levels of surface oxidation are unlikely to lead to a significant change in the electronic structure of PE and that its increased hydrophilic properties are the primary reason for the observed changes in its electrostatic behavior. The calculations for PTFE argue strongly against significant oxidation of that material, as confirmed by the XPS results.

  3. Direct measurement of electron density in microdischarge at atmospheric pressure by Stark broadening

    International Nuclear Information System (INIS)

    Dong Lifang; Ran Junxia; Mao Zhiguo

    2005-01-01

    We present a method and results for measurement of electron density in atmospheric-pressure dielectric barrier discharge. The electron density of microdischarge in atmospheric pressure argon is measured by using the spectral line profile method. The asymmetrical deconvolution is used to obtain Stark broadening. The results show that the electron density in single filamentary microdischarge at atmospheric pressure argon is 3.05x10 15 cm -3 if the electron temperature is 10,000 K. The result is in good agreement with the simulation. The electron density in dielectric barrier discharge increases with the increase of applied voltage

  4. The effect of atmospheric temperature and pressure on the occurrence of acute myocardial infarction in Kaunas.

    Science.gov (United States)

    Radišauskas, Ričardas; Vaičiulis, Vidmantas; Ustinavičienė, Rūta; Bernotienė, Gailutė

    2013-01-01

    OBJECTIVE. The aim of the study was to evaluate the impact of meteorological variables (atmospheric temperature and pressure) on the daily occurrence of acute myocardial infarction (AMI). MATERIAL AND METHODS. The study used the daily values of atmospheric temperature and pressure in 2000-2007. The meteorological data were obtained from the Lithuanian Hydrometeorological Service for Kaunas. The relative risks of event occurrence were computed for 5°C atmospheric temperature and for 10-hPa atmospheric pressure variations by means of the Poisson regression model. RESULTS. The occurrence of AMI and atmospheric temperature showed an inverse linear relationship, while the occurrence of AMI and atmospheric pressure, a positive linear relationship. Among the youngest subjects (25-44 years old), no relationships were detected. Contrary, among the subjects aged 45-64 years and those aged 65 years and older, the occurrence of AMI significantly decreased with higher temperature (P=0.001 and P=0.002, respectively). A decrease in atmospheric temperature by 10ºC reduced the risk of AMI by 8.7% in the age groups of 45-64 and 65 years and older and by 19% in the age group of 25 years and older. Among the first AMI cases, the risk increased by 7.5% in the age group of 45-64-year olds and by 6.4% in the age group of 25-64-year olds. The relationship between atmospheric temperature and pressure, and AMI occurrence was found to be linear but inverse. An increase in atmospheric pressure by 10 hPa resulted in an increase in risk by 4% among the subjects aged 65 years and more and by 3% among the subjects aged 25 years and more. CONCLUSIONS. Atmospheric temperature and pressure variations had the greatest effect on middle-aged and aging subjects (starting from 45 years). At younger age, the effect of such factors on the AMI risk was considerably lower.

  5. Atmospheric Pressure Plasma-Electrospin Hybrid Process for Protective Applications

    Science.gov (United States)

    Vitchuli Gangadharan, Narendiran

    2011-12-01

    Chemical and biological (C-B) warfare agents like sarin, sulfur mustard, anthrax are usually dispersed into atmosphere in the form of micro aerosols. They are considered to be dangerous weapon of mass destruction next to nuclear weapons. The airtight protective clothing materials currently available are able to stop the diffusion of threat agents but not good enough to detoxify them, which endangers the wearers. Extensive research efforts are being made to prepare advanced protective clothing materials that not only prevent the diffusion of C-B agents, but also detoxify them into harmless products thus ensuring the safety and comfort of the wearer. Electrospun nanofiber mats are considered to have effective filtration characteristics to stop the diffusion of submicron level particulates without sacrificing air permeability characteristics and could be used in protective application as barrier material. In addition, functional nanofibers could be potentially developed to detoxify the C-B warfare threats into harmless products. In this research, electrospun nanofibers were deposited on fabric surface to improve barrier efficiency without sacrificing comfort-related properties of the fabrics. Multi-functional nanofibers were fabricated through an electrospinning-electrospraying hybrid process and their ability to detoxify simulants of C-B agents was evaluated. Nanofibers were also deposited onto plasma-pretreated woven fabric substrate through a newly developed plasma-electrospinning hybrid process, to improve the adhesive properties of nanofibers on the fabric surface. The nanofiber adhesion and durability properties were evaluated by peel test, flex and abrasion resistance tests. In this research work, following tasks have been carried out: i) Controlled deposition of nanofiber mat onto woven fabric substrate Electrospun Nylon 6 fiber mats were deposited onto woven 50/50 Nylon/Cotton fabric with the motive of making them into protective material against submicron

  6. Mechanism of Runaway Electron Generation at Gas Pressures from a Few Atmospheres to Several Tens of Atmospheres

    Science.gov (United States)

    Zubarev, N. M.; Ivanov, S. N.

    2018-04-01

    The mechanism of runaway electron generation at gas pressures from a few atmospheres to several tens of atmospheres is proposed. According to this mechanism, the electrons pass into the runaway mode in the enhanced field zone that arises between a cathode micropoint—a source of field-emission electrons—and the region of the positive ion space charge accumulated near the cathode in the tails of the developing electron avalanches. As a result, volume gas ionization by runaway electrons begins with a time delay required for the formation of the enhanced field zone. This process determines the delay time of breakdown. The influence of the gas pressure on the formation dynamics of the space charge region is analyzed. At gas pressures of a few atmospheres, the space charge arises due to the avalanche multiplication of the very first field-emission electron, whereas at pressures of several tens of atmospheres, the space charge forms as a result of superposition of many electron avalanches with a relatively small number of charge carriers in each.

  7. Space structure of the glow discharge with free side boundary

    International Nuclear Information System (INIS)

    Yatsenko, N.A.

    1995-01-01

    The main purpose of this work is to reveal physical reasons, which are responsible for the formation of space structure of glow type discharge with free side boundary, both in DC and in RF electric fields. By now extensive experimental material have been accumulated in discharge physics. Also many theoretical models have been proposed for describing separate parts of discharge with the cold electrodes (cathode and anode regions, positive column and transition zones - glow luminescence and Farraday's dark space of DC-discharge, electrode regions and plasma column of RF capacitive discharge). As this takes place, the majority of known works are devoted to some one part of gas discharge - positive column, electrode regions, transition zones and so on. At the same time just now we don't know anything about space structure of free, steady-state gas discharge of glow type, as a whole, especially when the pressure p much-gt 1 Torr

  8. Temperature-independent fiber-Bragg-grating-based atmospheric pressure sensor

    Science.gov (United States)

    Zhang, Zhiguo; Shen, Chunyan; Li, Luming

    2018-03-01

    Atmospheric pressure is an important way to achieve a high degree of measurement for modern aircrafts, moreover, it is also an indispensable parameter in the meteorological telemetry system. With the development of society, people are increasingly concerned about the weather. Accurate and convenient atmospheric pressure parameters can provide strong support for meteorological analysis. However, electronic atmospheric pressure sensors currently in application suffer from several shortcomings. After an analysis and discussion, we propose an innovative structural design, in which a vacuum membrane box and a temperature-independent strain sensor based on an equal strength cantilever beam structure and fiber Bragg grating (FBG) sensors are used. We provide experimental verification of that the atmospheric pressure sensor device has the characteristics of a simple structure, lack of an external power supply, automatic temperature compensation, and high sensitivity. The sensor system has good sensitivity, which can be up to 100 nm/MPa, and repeatability. In addition, the device exhibits desired hysteresis.

  9. Keratinocytes at the uppermost layer of epidermis might act as sensors of atmospheric pressure change.

    Science.gov (United States)

    Denda, Mitsuhiro

    2016-01-01

    It has long been suggested that climate, especially atmospheric pressure change, can cause health problems ranging from migraine to myocardial infarction. Here, I hypothesize that the sensory system of epidermal keratinocytes mediates the influence of atmospheric pressure change on the human physiological condition. We previously demonstrated that even subtle changes of atmospheric pressure (5-20 hPa) induce elevation of intracellular calcium level in cultured human keratinocytes (excitation of keratinocytes). It is also established that communication occurs between epidermal keratinocytes and peripheral nerve systems. Moreover, various neurotransmitters and hormones that influence multiple systems (nervous, cardiovascular, endocrine, and immune systems) are generated and released from epidermal keratinocytes in response to various external stimuli. Thus, I suggest that pathophysiological phenomena induced by atmospheric pressure changes might be triggered by epidermal keratinocytes.

  10. Adhesion improvement of fibres by continuous plasma treatment at atmospheric pressure

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Løgstrup Andersen, Tom; Sørensen, Bent F.

    2013-01-01

    Carbon fibres and ultra-high-molecular-weight polyethylene (UHMWPE) fibres were continuously treated by a dielectric barrier discharge plasma at atmospheric pressure for adhesion improvement with epoxy resins. The plasma treatment improved wettability, increased the oxygen containing polar...

  11. Relating landfill gas emissions to atmospheric pressure using numerical modeling and state-space analysis

    DEFF Research Database (Denmark)

    Poulsen, T.G.; Christophersen, Mette; Moldrup, P.

    2003-01-01

    were applied: (I) State-space analysis was used to identify relations between gas flux and short-term (hourly) variations in atmospheric pressure. (II) A numerical gas transport model was fitted to the data and used to quantify short-term impacts of variations in atmospheric pressure, volumetric soil......-water content, soil gas permeability, soil gas diffusion coefficients, and biological CH4 degradation rate upon landfill gas concentration and fluxes in the soil. Fluxes and concentrations were found to be most sensitive to variations in volumetric soil water content, atmospheric pressure variations and gas...... permeability whereas variations in CH4 oxidation rate and molecular coefficients had less influence. Fluxes appeared to be most sensitive to atmospheric pressure at intermediate distances from the landfill edge. Also overall CH4 fluxes out of the soil over longer periods (years) were largest during periods...

  12. Atmospheric-Pressure Plasma Interaction with Soft Materials as Fundamental Processes in Plasma Medicine.

    Science.gov (United States)

    Takenaka, Kosuke; Miyazaki, Atsushi; Uchida, Giichiro; Setsuhara, Yuichi

    2015-03-01

    Molecular-structure variation of organic materials irradiated with atmospheric pressure He plasma jet have been investigated. Optical emission spectrum in the atmospheric-pressure He plasma jet has been measured. The spectrum shows considerable emissions of He lines, and the emission of O and N radicals attributed to air. Variation in molecular structure of Polyethylene terephthalate (PET) film surface irradiated with the atmospheric-pressure He plasma jet has been observed via X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR). These results via XPS and FT-IR indicate that the PET surface irradiated with the atmospheric-pressure He plasma jet was oxidized by chemical and/or physical effect due to irradiation of active species.

  13. Thermal conductivity in an argon arc at atmospheric pressure

    NARCIS (Netherlands)

    Bol, L.; Timmermans, C.J.; Schram, D.C.

    1984-01-01

    The thermal conductivity of an argon plasma has been determined in a phi 5 mm wall stabilized atmospheric argon arc in the temperature range from 10000 to 16000 K. The calculations are based on the energy balance, and include non-LTE effects like ambipolar diffusion and overpopulation of the ground

  14. Atmospheric Pressure and Velocity Fluctuations Near the Auroral Electrojet.

    Science.gov (United States)

    1982-01-15

    various aspects of the atmosphere’s dynamical response to auroral activity have been carried out by Blumen and Hendl (1969), Testud (1970), Francis...Geophys. Res. 80, 2839, 1975. Testud , 3., Gravity waves generated during magnetic substorms, 3. Atmos. Terr. Phys. 32, 1793, 1970. Waco, D. E., A

  15. Diagnostics of plasma-biological surface interactions in low pressure and atmospheric pressure plasmas

    International Nuclear Information System (INIS)

    Ishikawa, Kenji; Hori, Masaru

    2014-01-01

    Mechanisms of plasma-surface interaction are required to understand in order to control the reactions precisely. Recent progress in atmospheric pressure plasma provides to apply as a tool of sterilization of contaminated foodstuffs. To use the plasma with safety and optimization, the real time in situ detection of free radicals - in particular dangling bonds by using the electron-spin-resonance (ESR) technique has been developed because the free radical plays important roles for dominantly biological reactions. First, the kinetic analysis of free radicals on biological specimens such as fungal spores of Penicillium digitatum interacted with atomic oxygen generated plasma electric discharge. We have obtained information that the in situ real time ESR signal from the spores was observed and assignable to semiquinone radical with a g-value of around 2.004 and a line width of approximately 5G. The decay of the signal was correlated with a link to the inactivation of the fungal spore. Second, we have studied to detect chemical modification of edible meat after the irradiation. Using matrix-assisted laser desorption/ionization time-of-flight mass spectroscopy (MALDI-TOF-MS) and ESR, signals give qualification results for chemical changes on edible liver meat. The in situ real-time measurements have proven to be a useful method to elucidate plasma-induced surface reactions on biological specimens. (author)

  16. Selection of suitable diagnostic techniques for an RF atmospheric pressure plasma

    International Nuclear Information System (INIS)

    Kong, M.G.; Deng, X.T.

    2001-01-01

    As an early report of our study, this paper summaries the RF atmospheric pressure plasma system we intend to characterize and a number of diagnostic techniques presently under assessment for our plasma rig. By discussing the advantages and disadvantages of these diagnostic techniques at this meeting, we hope to gain feedback and comments to improve our choice of appropriate diagnostic techniques as well as our subsequent application of these techniques to nonthermal RF atmospheric pressure plasmas

  17. Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS): Review

    International Nuclear Information System (INIS)

    Li, Du-Xin; Gan, Lin; Bronja, Amela; Schmitz, Oliver J.

    2015-01-01

    Although the coupling of GC/MS with atmospheric pressure ionization (API) has been reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was expanded in the last decade. The demand of a “soft” ion source for preserving highly diagnostic molecular ion is desirable, as compared to the “hard” ionization technique such as electron ionization (EI) in traditional GC/MS, which fragments the molecule in an extensive way. These API sources include atmospheric pressure chemical ionization (APCI), atmospheric pressure photoionization (APPI), atmospheric pressure laser ionization (APLI), electrospray ionization (ESI) and low temperature plasma (LTP). This review discusses the advantages and drawbacks of this analytical platform. After an introduction in atmospheric pressure ionization the review gives an overview about the history and explains the mechanisms of various atmospheric pressure ionization techniques used in combination with GC such as APCI, APPI, APLI, ESI and LTP. Also new developments made in ion source geometry, ion source miniaturization and multipurpose ion source constructions are discussed and a comparison between GC-FID, GC-EI-MS and GC-API-MS shows the advantages and drawbacks of these techniques. The review ends with an overview of applications realized with GC-API-MS. - Highlights: • Atmospheric pressure ion sources (APCI, ESI, APPI, APLC etc) enable the coupling of LC-based high-end MS to GC. • APIs show advantages in selectivity and sensitivity compared with EI in GC-MS. • Accurate mass database in GC-APCI/MS is emerging as an alternative to GC-EI/MS database.

  18. Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS): Review

    Energy Technology Data Exchange (ETDEWEB)

    Li, Du-Xin; Gan, Lin; Bronja, Amela [University of Duisburg-Essen, Applied Analytical Chemistry, Universitaetsstr. 5-7, 45141 Essen (Germany); Schmitz, Oliver J., E-mail: oliver.schmitz@uni-due.de [University of Duisburg-Essen, Applied Analytical Chemistry, Universitaetsstr. 5-7, 45141 Essen (Germany)

    2015-09-03

    Although the coupling of GC/MS with atmospheric pressure ionization (API) has been reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was expanded in the last decade. The demand of a “soft” ion source for preserving highly diagnostic molecular ion is desirable, as compared to the “hard” ionization technique such as electron ionization (EI) in traditional GC/MS, which fragments the molecule in an extensive way. These API sources include atmospheric pressure chemical ionization (APCI), atmospheric pressure photoionization (APPI), atmospheric pressure laser ionization (APLI), electrospray ionization (ESI) and low temperature plasma (LTP). This review discusses the advantages and drawbacks of this analytical platform. After an introduction in atmospheric pressure ionization the review gives an overview about the history and explains the mechanisms of various atmospheric pressure ionization techniques used in combination with GC such as APCI, APPI, APLI, ESI and LTP. Also new developments made in ion source geometry, ion source miniaturization and multipurpose ion source constructions are discussed and a comparison between GC-FID, GC-EI-MS and GC-API-MS shows the advantages and drawbacks of these techniques. The review ends with an overview of applications realized with GC-API-MS. - Highlights: • Atmospheric pressure ion sources (APCI, ESI, APPI, APLC etc) enable the coupling of LC-based high-end MS to GC. • APIs show advantages in selectivity and sensitivity compared with EI in GC-MS. • Accurate mass database in GC-APCI/MS is emerging as an alternative to GC-EI/MS database.

  19. A new humane method of stunning broilers using low atmospheric pressure

    Science.gov (United States)

    This research project evaluated an alternative method of controlled atmosphere stunning of commercial broilers to induce anoxia utilizing a vacuum pump to reduce the oxygen tension, low atmospheric pressure stun (LAPS). A custom built 2 cage-module system (holding a total of 600 broilers each) with...

  20. Physiological responses to low atmospheric pressure stunning and the implications for welfare

    NARCIS (Netherlands)

    Mckeegan, D.E.F.; Sandercock, D.A.; Gerritzen, M.A.

    2013-01-01

    In low atmospheric pressure stunning (LAPS), poultry are rendered unconscious before slaughter by gradually reducing oxygen tension in the atmosphere to achieve a progressive anoxia. The effects of LAPS are not instantaneous, so there are legitimate welfare concerns around the experience of birds

  1. Super-atmospheric pressure ionization mass spectrometry and its application to ultrafast online protein digestion analysis.

    Science.gov (United States)

    Chen, Lee Chuin; Ninomiya, Satoshi; Hiraoka, Kenzo

    2016-06-01

    Ion source pressure plays a significant role in the process of ionization and the subsequent ion transmission inside a mass spectrometer. Pressurizing the ion source to a gas pressure greater than atmospheric pressure is a relatively new approach that aims to further improve the performance of atmospheric pressure ionization sources. For example, under a super-atmospheric pressure environment, a stable electrospray can be sustained for liquid with high surface tension such as pure water, because of the suppression of electric discharge. Even for nano-electrospray ionization (nano-ESI), which is known to work with aqueous solution, its stability and sensitivity can also be enhanced, particularly in the negative mode when the ion source is pressurized. A brief review on the development of super-atmospheric pressure ion sources, including high-pressure electrospray, field desorption and superheated ESI, and the strategies to interface these ion sources to a mass spectrometer will be given. Using a recent ESI prototype with an operating temperature at 220 °C under 27 atm, we also demonstrate that it is possible to achieve an online Asp-specific protein digestion analysis in which the whole processes of digestion, ionization and MS acquisition could be completed on the order of a few seconds. This method is fast, and the reaction can even be monitored on a near-real-time basis. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

  2. Water cycles in closed ecological systems: effects of atmospheric pressure.

    Science.gov (United States)

    Rygalov, Vadim Y; Fowler, Philip A; Metz, Joannah M; Wheeler, Raymond M; Bucklin, Ray A

    2002-01-01

    In bioregenerative life support systems that use plants to generate food and oxygen, the largest mass flux between the plants and their surrounding environment will be water. This water cycle is a consequence of the continuous change of state (evaporation-condensation) from liquid to gas through the process of transpiration and the need to transfer heat (cool) and dehumidify the plant growth chamber. Evapotranspiration rates for full plant canopies can range from ~1 to 10 L m-2 d-1 (~1 to 10 mm m-2 d-1), with the rates depending primarily on the vapor pressure deficit (VPD) between the leaves and the air inside the plant growth chamber. VPD in turn is dependent on the air temperature, leaf temperature, and current value of relative humidity (RH). Concepts for developing closed plant growth systems, such as greenhouses for Mars, have been discussed for many years and the feasibility of such systems will depend on the overall system costs and reliability. One approach for reducing system costs would be to reduce the operating pressure within the greenhouse to reduce structural mass and gas leakage. But managing plant growth environments at low pressures (e.g., controlling humidity and heat exchange) may be difficult, and the effects of low-pressure environments on plant growth and system water cycling need further study. We present experimental evidence to show that water saturation pressures in air under isothermal conditions are only slightly affected by total pressure, but the overall water flux from evaporating surfaces can increase as pressure decreases. Mathematical models describing these observations are presented, along with discussion of the importance for considering "water cycles" in closed bioregenerative life support systems.

  3. Water cycles in closed ecological systems: effects of atmospheric pressure

    Science.gov (United States)

    Rygalov, Vadim Y.; Fowler, Philip A.; Metz, Joannah M.; Wheeler, Raymond M.; Bucklin, Ray A.; Sager, J. C. (Principal Investigator)

    2002-01-01

    In bioregenerative life support systems that use plants to generate food and oxygen, the largest mass flux between the plants and their surrounding environment will be water. This water cycle is a consequence of the continuous change of state (evaporation-condensation) from liquid to gas through the process of transpiration and the need to transfer heat (cool) and dehumidify the plant growth chamber. Evapotranspiration rates for full plant canopies can range from 1 to 10 L m-2 d-1 (1 to 10 mm m-2 d-1), with the rates depending primarily on the vapor pressure deficit (VPD) between the leaves and the air inside the plant growth chamber. VPD in turn is dependent on the air temperature, leaf temperature, and current value of relative humidity (RH). Concepts for developing closed plant growth systems, such as greenhouses for Mars, have been discussed for many years and the feasibility of such systems will depend on the overall system costs and reliability. One approach for reducing system costs would be to reduce the operating pressure within the greenhouse to reduce structural mass and gas leakage. But managing plant growth environments at low pressures (e.g., controlling humidity and heat exchange) may be difficult, and the effects of low-pressure environments on plant growth and system water cycling need further study. We present experimental evidence to show that water saturation pressures in air under isothermal conditions are only slightly affected by total pressure, but the overall water flux from evaporating surfaces can increase as pressure decreases. Mathematical models describing these observations are presented, along with discussion of the importance for considering "water cycles" in closed bioregenerative life support systems.

  4. Investigation of Gas Heating by Nanosecond Repetitively Pulsed Glow Discharges Used for Actuation of a Laminar Methane-Air Flame

    KAUST Repository

    Lacoste, Deanna

    2017-05-24

    This paper reports on the quantification of the heating induced by nanosecond repetitively pulsed (NRP) glow discharges on a lean premixed methane-air flame. The flame, obtained at room temperature and atmospheric pressure, has an M-shape morphology. The equivalence ratio is 0.95 and the thermal power released by the flame is 113 W. The NRP glow discharges are produced by high voltage pulses of 10 ns duration, 7 kV amplitude, applied at a repetition frequency of 10 kHz. The average power of the plasma, determined from current and voltage measurements, is 1 W, i.e. about 0.9 % of the thermal power of the flame. Broadband vibrational coherent anti-Stokes Raman spectroscopy of nitrogen is used to determine the temperature of the flame with and without plasma enhancement. The temperature evolution in the flame area shows that the thermal impact of NRP glow discharges is in the uncertainty range of the technique, i.e., +/- 40 K.

  5. A Study of Electron Decay in Nitrogen Time After-glow

    International Nuclear Information System (INIS)

    Veis, P.; Coitout, H.; Magne, L.; Cernogora, G.

    1999-01-01

    This paper deals with electron density measurements in nitrogen time after-glow using hyper frequency resonant cavity. The studied pressures are from the range 9-530 Pa and discharge currents from 20 mA up to 500 mA. Electrons decreases up to the time of 1,4 ms in after-glow depending on pressure, pulse current and pulse duration (Authors)

  6. Ignition during hydrogen release from high pressure into the atmosphere

    Science.gov (United States)

    Oleszczak, P.; Wolanski, P.

    2010-12-01

    The first investigations concerned with a problem of hydrogen jet ignition, during outflow from a high-pressure vessel were carried out nearly 40 years ago by Wolanski and Wojcicki. The research resulted from a dramatic accident in the Chorzow Chemical Plant Azoty, where the explosion of a synthesis gas made up of a mixture composed of three moles of hydrogen per mole of nitrogen, at 300°C and 30 MPa killed four people. Initial investigation had excluded potential external ignition sources and the main aim of the research was to determine the cause of ignition. Hydrogen is currently considered as a potential fuel for various vehicles such as cars, trucks, buses, etc. Crucial safety issues are of potential concern, associated with the storage of hydrogen at a very high pressure. Indeed, the evidence obtained nearly 40 years ago shows that sudden rupture of a high-pressure hydrogen storage tank or other component can result in ignition and potentially explosion. The aim of the present research is identification of the conditions under which hydrogen ignition occurs as a result of compression and heating of the air by the shock wave generated by discharge of high-pressure hydrogen. Experiments have been conducted using a facility constructed in the Combustion Laboratory of the Institute of Heat Engineering, Warsaw University of Technology. Tests under various configurations have been performed to determine critical conditions for occurrence of high-pressure hydrogen ignition. The results show that a critical pressure exists, leading to ignition, which depends mainly on the geometric configuration of the outflow system, such as tube diameter, and on the presence of obstacles.

  7. Seasonal emanation of radon at Ghuttu, northwest Himalaya: Differentiation of atmospheric temperature and pressure influences

    International Nuclear Information System (INIS)

    Kamra, Leena

    2015-01-01

    Continuous monitoring of radon along with meteorological parameters has been carried out in a seismically active area of Garhwal region, northwest Himalaya, within the frame work of earthquake precursory research. Radon measurements are carried out by using a gamma ray detector installed in the air column at a depth of 10 m in a 68 m deep borehole. The analysis of long time series for 2006–2012 shows strong seasonal variability masked by diurnal and multi-day variations. Isolation of a seasonal cycle by minimising short-time by 31 day running average shows a strong seasonal variation with unambiguous dependence on atmospheric temperature and pressure. The seasonal characteristics of radon concentrations are positively correlated to atmospheric temperature (R=0.95) and negatively correlated to atmospheric pressure (R=−0.82). The temperature and pressure variation in their annual progressions are negatively correlated. The calculations of partial correlation coefficient permit us to conclude that atmospheric temperature plays a dominant role in controlling the variability of radon in borehole, 71% of the variability in radon arises from the variation in atmospheric temperature and about 6% of the variability is contributed by atmospheric pressure. The influence of pressure variations in an annual cycle appears to be a pseudo-effect, resulting from the negative correlation between temperature and pressure variations. Incorporation of these results explains the varying and even contradictory claims regarding the influence of the pressure variability on radon changes in the published literature. Temperature dependence, facilitated by the temperature gradient in the borehole, controls the transportation of radon from the deep interior to the surface. - Highlights: • Seasonal variability of radon in borehole. • Influence of atmospheric temperature and pressure on radon variability. • Partial correlation coefficient.

  8. Rates of chemical reaction and atmospheric heating during core debris expulsion from a pressurized vessel

    International Nuclear Information System (INIS)

    Powers, D.A.; Tarbell, W.W.; Brockman, J.E.; Pilch, M.

    1986-01-01

    Core debris may be expelled from a pressurized reactor vessel during a severe nuclear reactor accident. Experimental studies of core debris expulsion from pressurized vessels have established that the expelled material can be lofted into the atmosphere of the reactor containment as particulate 0.4 to 2 mm in diameter. These particles will vigorously react with steam and oxygen in the containment atmosphere. Data on such reactions during tests with 80 kg of expelled melt will be reported. A model of the reaction rates based on gas phase mass transport will be described and shown to account for atmospheric heating and aerosol generation observed in the tests

  9. Desorption atmospheric pressure photoionization high-resolution mass spectrometry: a complementary approach for the chemical analysis of atmospheric aerosols.

    Science.gov (United States)

    Parshintsev, Jevgeni; Vaikkinen, Anu; Lipponen, Katriina; Vrkoslav, Vladimir; Cvačka, Josef; Kostiainen, Risto; Kotiaho, Tapio; Hartonen, Kari; Riekkola, Marja-Liisa; Kauppila, Tiina J

    2015-07-15

    On-line chemical characterization methods of atmospheric aerosols are essential to increase our understanding of physicochemical processes in the atmosphere, and to study biosphere-atmosphere interactions. Several techniques, including aerosol mass spectrometry, are nowadays available, but they all suffer from some disadvantages. In this research, desorption atmospheric pressure photoionization high-resolution (Orbitrap) mass spectrometry (DAPPI-HRMS) is introduced as a complementary technique for the fast analysis of aerosol chemical composition without the need for sample preparation. Atmospheric aerosols from city air were collected on a filter, desorbed in a DAPPI source with a hot stream of toluene and nitrogen, and ionized using a vacuum ultraviolet lamp at atmospheric pressure. To study the applicability of the technique for ambient aerosol analysis, several samples were collected onto filters and analyzed, with the focus being on selected organic acids. To compare the DAPPI-HRMS data with results obtained by an established method, each filter sample was divided into two equal parts, and the second half of the filter was extracted and analyzed by liquid chromatography/mass spectrometry (LC/MS). The DAPPI results agreed with the measured aerosol particle number. In addition to the targeted acids, the LC/MS and DAPPI-HRMS methods were found to detect different compounds, thus providing complementary information about the aerosol samples. DAPPI-HRMS showed several important oxidation products of terpenes, and numerous compounds were tentatively identified. Thanks to the soft ionization, high mass resolution, fast analysis, simplicity and on-line applicability, the proposed methodology has high potential in the field of atmospheric research. Copyright © 2015 John Wiley & Sons, Ltd.

  10. Atmospheric pressure plasma analysis by modulated molecular beam mass spectrometry

    NARCIS (Netherlands)

    Aranda Gonzalvo, Y.; Whitmore, T.D.; Rees, J.A.; Seymour, D.L.; Stoffels - Adamowicz, E.

    2006-01-01

    Fractional no. d. measurements for a radiofrequency plasma needle operating at atm. pressure were obtained using a mol. beam mass spectrometer (MBMS) system designed for diagnostics of atm. plasmas. The MBMS system comprises three differentially pumped stages and a mass/energy analyzer and includes

  11. High pressure gas laser technology for atmospheric remote sensing

    Science.gov (United States)

    Javan, A.

    1980-01-01

    The development of a fixed frequency chirp-free and highly stable intense pulsed laser made for Doppler wind velocity measurements with accurate ranging is described. Energy extraction from a high pressure CO2 laser at a tunable single mode frequency is also examined.

  12. The conceptual design of high temporal resolution HCN interferometry for atmospheric pressure air plasmas

    Science.gov (United States)

    Zhang, J. B.; Liu, H. Q.; Jie, Y. X.; Wei, X. C.; Hu, L. Q.

    2018-01-01

    A heterodyne interferometer operating at the frequency f = 890 GHz has been designed for measuring the electron density of atmospheric pressure air plasmas, it's density range is from 1015 to 3×1019 m-3 and the pressure range is from 1 Pa to 20 kPa. The system is configured as a Mach\

  13. Spectroscopic Study of Electrical Glow Discharges in Gases

    Science.gov (United States)

    Reyes, P. G.; Evangelista, M.; Trujillo, C.; Castillo, F.; Rangel, J.

    2006-12-01

    The variation of the power of the light emitted in a Glow Discharge in Gases of low pressure (GDGLP) excited by a DC source was studied. A lack of dependency of the kind of gas used and the pressure it is located at was obtained. This is comparable to the potential drop which takes place in the discharge by inelastic collisions such as ionization, recombination, excitation, relaxation, etc.

  14. Cancer therapy using non-thermal atmospheric pressure plasma with ultra-high electron density

    International Nuclear Information System (INIS)

    Tanaka, Hiromasa; Mizuno, Masaaki; Toyokuni, Shinya; Maruyama, Shoichi; Kodera, Yasuhiro; Terasaki, Hiroko; Adachi, Tetsuo; Kato, Masashi; Kikkawa, Fumitaka; Hori, Masaru

    2015-01-01

    Cancer therapy using non-thermal atmospheric pressure plasma is a big challenge in plasma medicine. Reactive species generated from plasma are key factors for treating cancer cells, and thus, non-thermal atmospheric pressure plasma with high electron density has been developed and applied for cancer treatment. Various cancer cell lines have been treated with plasma, and non-thermal atmospheric plasma clearly has anti-tumor effects. Recent innovative studies suggest that plasma can both directly and indirectly affect cells and tissues, and this observation has widened the range of applications. Thus, cancer therapy using non-thermal atmospheric pressure plasma is promising. Animal experiments and understanding the mode of action are essential for clinical application in the future. A new academic field that combines plasma science, the biology of free radicals, and systems biology will be established

  15. Surface modification of polylactic acid films by atmospheric pressure plasma treatment

    Science.gov (United States)

    Kudryavtseva, V. L.; Zhuravlev, M. V.; Tverdokhlebov, S. I.

    2017-09-01

    A new approach for the modification of polylactic acid (PLA) materials using atmospheric pressure plasma (APP) is described. PLA films plasma exposure time was 20, 60, 120 s. The surface morphology and wettability of the obtained PLA films were investigated by atomic force microscopy (AFM) and the sitting drop method. The atmospheric pressure plasma increased the roughness and surface energy of PLA film. The wettability of PLA has been improved with the application of an atmospheric plasma surface treatment. It was shown that it is possible to obtain PLA films with various surface relief and tunable wettability. Additionally, we demonstrated that the use of cold atmospheric pressure plasma for surface activation allows for the immobilization of bioactive compounds like hyaluronic acid (HA) on the surface of obtained films. It was shown that composite PLA-HA films have an increased long-term hydrophilicity of the films surface.

  16. Cancer therapy using non-thermal atmospheric pressure plasma with ultra-high electron density

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, Hiromasa [Institute of Innovation for Future Society, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Center for Advanced Medicine and Clinical Research, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Mizuno, Masaaki [Center for Advanced Medicine and Clinical Research, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Toyokuni, Shinya [Department of Pathology and Biological Responses, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Maruyama, Shoichi [Department of Nephrology, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Kodera, Yasuhiro [Department of Gastroenterological Surgery (Surgery II), Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Terasaki, Hiroko [Department of Ophthalmology, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Adachi, Tetsuo [Laboratory of Clinical Pharmaceutics, Gifu Pharmaceutical University, 501-1196 Gifu (Japan); Kato, Masashi [Department of Occupational and Environmental Health, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Kikkawa, Fumitaka [Department of Obstetrics and Gynecology, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Hori, Masaru [Institute of Innovation for Future Society, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan)

    2015-12-15

    Cancer therapy using non-thermal atmospheric pressure plasma is a big challenge in plasma medicine. Reactive species generated from plasma are key factors for treating cancer cells, and thus, non-thermal atmospheric pressure plasma with high electron density has been developed and applied for cancer treatment. Various cancer cell lines have been treated with plasma, and non-thermal atmospheric plasma clearly has anti-tumor effects. Recent innovative studies suggest that plasma can both directly and indirectly affect cells and tissues, and this observation has widened the range of applications. Thus, cancer therapy using non-thermal atmospheric pressure plasma is promising. Animal experiments and understanding the mode of action are essential for clinical application in the future. A new academic field that combines plasma science, the biology of free radicals, and systems biology will be established.

  17. Atmospheric pressure and temperature profiling using near IR differential absorption lidar

    Science.gov (United States)

    Korb, C. L.; Schwemmer, G. K.; Dombrowski, M.; Weng, C. Y.

    1983-01-01

    The present investigation is concerned with differential absorption lidar techniques for remotely measuring the atmospheric temperature and pressure profile, surface pressure, and cloud top pressure-height. The procedure used in determining the pressure is based on the conduction of high-resolution measurements of absorption in the wings of lines in the oxygen A band. Absorption with respect to these areas is highly pressure sensitive in connection with the mechanism of collisional line broadening. The method of temperature measurement utilizes a determination of the absorption at the center of a selected line in the oxygen A band which originates from a quantum state with high ground state energy.

  18. Modelling of microwave sustained capillary plasma columns at atmospheric pressure

    International Nuclear Information System (INIS)

    Pencheva, M; Petrova, Ts; Benova, E; Zhelyazkov, I

    2006-01-01

    In this work we present a model of argon microwave sustained discharge at high pressure (1 atm), which includes two self-consistently linked parts - electrodynamic and kinetic ones. The model is based on a steady-state Boltzmann equation in an effective field approximation coupled with a collisional-radiative model for high-pressure argon discharge numerically solved together with Maxwell's equation for an azimuthally symmetric TM surface wave and wave energy balance equation. It is applied for the purpose of theoretical description of the discharge in a stationary state. The phase diagram, the electron energy distribution function as well as the dependences of the electron and heavy particles densities and the mean input power per electron on the electron number density and wave number are presented

  19. Glow discharge based device for solving mazes

    Energy Technology Data Exchange (ETDEWEB)

    Dubinov, Alexander E., E-mail: dubinov-ae@yandex.ru; Mironenko, Maxim S.; Selemir, Victor D. [Russian Federal Nuclear Center − All-Russian Scientific and Research Institute of Experimental Physics (RFNC-VNIIEF), Sarov, Nizhni Novgorod region 607188 (Russian Federation); Sarov Institute of Physics and Technology (SarFTI) of National Research Nuclear University “MEPhI,” Sarov, Nizhni Novgorod region 607188 (Russian Federation); Maksimov, Artem N.; Pylayev, Nikolay A. [Russian Federal Nuclear Center − All-Russian Scientific and Research Institute of Experimental Physics (RFNC-VNIIEF), Sarov, Nizhni Novgorod region 607188 (Russian Federation)

    2014-09-15

    A glow discharge based device for solving mazes has been designed and tested. The device consists of a gas discharge chamber and maze-transformer of radial-azimuth type. It allows changing of the maze pattern in a short period of time (within several minutes). The device has been tested with low pressure air. Once switched on, a glow discharge has been shown to find the shortest way through the maze from the very first attempt, even if there is a section with potential barrier for electrons on the way. It has been found that ionization waves (striations) can be excited in the maze along the length of the plasma channel. The dependancy of discharge voltage on the length of the optimal path through the maze has been measured. A reduction in discharge voltage with one or two potential barriers present has been found and explained. The dependency of the magnitude of discharge ignition voltage on the length of the optimal path through the maze has been measured. The reduction of the ignition voltage with the presence of one or two potential barriers has been observed and explained.

  20. Research of Infrared Imaging at Atmospheric Pressure Using a Substrate-Free Focal Plane Array

    International Nuclear Information System (INIS)

    Wu Jian-Xiong; Cheng Teng; Zhang Qing-Chuan; Zhang Yong; Mao Liang; Gao Jie; Wu Xiao-Ping; Chen Da-Peng

    2013-01-01

    An equivalent circuit model to the substrate-free focal plane array (FPA) is established. Using this fast and effective model, the performance of infrared (IR) imaging at atmospheric pressure is investigated and it is found that the substrate-free FPA has the ability of IR imaging at atmospheric pressure, whereas it has a slightly degraded noise equivalent temperature difference (NETD) as compared with IR imaging under a high vacuum. This feature is also identified experimentally by a substrate-free FPA with pixel size of 50 × 50 μm 2 . The NETDs are measured to be 160 mK at 10 −2 Pa pressure and 1.08 K at atmospheric pressure

  1. Correlation between the season, temperature and atmospheric pressure with incidence and pathogenesis of acute appendicitis.

    Science.gov (United States)

    Karanikolić, Aleksandar; Karanikolić, Vesna; Djordjević, Lidija; Pešić, Ivan

    2016-01-01

    There is very little literature data on the correlation between the seasons, temperature and atmospheric pressure, and pathogenesis of acute appendicitis (AA). The aim of this research is to investigate the association between the seasons, changes in atmospheric temperature and pressure, and patients’ age and severity of the clinical form of AA in the city of Niš This study included 395 patients diagnosed with AA, who, during the two-year period, from July 1st 2011 to June 30th 2013, were hospitalized and operated on at the Department of General Surgery, Clinical Center in Niš, Serbia. The increased average daily values of barometric pressure by 1 millibar on the day when the event took place was associated (p atmospheric temperature and pressure.

  2. Effects of ambient temperature and water vapor on chamber pressure and oxygen level during low atmospheric pressure stunning of poultry.

    Science.gov (United States)

    Holloway, Paul H; Pritchard, David G

    2017-08-01

    The characteristics of the vacuum used in a low atmospheric pressure stunning system to stun (render unconscious) poultry prior to slaughter are described. A vacuum chamber is pumped by a wet screw compressor. The vacuum pressure is reduced from ambient atmospheric pressure to an absolute vacuum pressure of ∼250 Torr (∼33 kPa) in ∼67 sec with the vacuum gate valve fully open. At ∼250 Torr, the sliding gate valve is partially closed to reduce effective pumping speed, resulting in a slower rate of decreasing pressure. Ambient temperature affects air density and water vapor pressure and thereby oxygen levels and the time at the minimum total pressure of ∼160 Torr (∼21 kPa) is varied from ∼120 to ∼220 sec to ensure an effective stun within the 280 seconds of each cycle. The reduction in total pressure results in a gradual reduction of oxygen partial pressure that was measured by a solid-state electrochemical oxygen sensor. The reduced oxygen pressure leads to hypoxia, which is recognized as a humane method of stunning poultry. The system maintains an oxygen concentration of air always reduces the oxygen concentrations to a value lower than in dry air. The partial pressure of water and oxygen were found to depend on the pump down parameters due to the formation of fog in the chamber and desorption of water from the birds and the walls of the vacuum chamber. © The Author 2017. Published by Oxford University Press on behalf of Poultry Science Association.

  3. Germination and growth of lettuce (Lactuca sativa) at low atmospheric pressure

    Science.gov (United States)

    Spanarkel, Robert; Drew, Malcolm C.

    2002-01-01

    The response of lettuce (Lactuca sativa L. cv. Waldmann's Green) to low atmospheric pressure was examined during the initial 5 days of germination and emergence, and also during subsequent growth to vegetative maturity at 30 days. Growth took place inside a 66-l-volume low pressure chamber maintained at 70 kPa, and plant response was compared to that of plants in a second, matching chamber that was at ambient pressure (approximately 101 kPa) as a control. In other experiments, to determine short-term effects of low pressure transients, plants were grown at ambient pressure until maturity and then subjected to alternating periods of 24 h of low and ambient atmospheric pressures. In all treatments the partial pressure of O2 was maintained at 21 kPa (approximately the partial pressure in air at normal pressure), and the partial pressure of CO2 was in the range 66.5-73.5 Pa (about twice that in normal air) in both chambers, with the addition of CO2 during the light phase. With continuous exposure to low pressure, shoot and root growth was at least as rapid as at ambient pressure, with an overall trend towards slightly greater performance at the lower pressure. Dark respiration rates were greater at low pressure. Transient periods at low pressure decreased transpiration and increased dark respiration but only during the period of exposure to low pressure. We conclude that long-term or short-term exposure to subambient pressure (70 kPa) was without detectable detriment to vegetative growth and development.

  4. The Healing Effect of Low-Temperature Atmospheric-Pressure Plasma in Pressure Ulcer: A Randomized Controlled Trial.

    Science.gov (United States)

    Chuangsuwanich, Apirag; Assadamongkol, Tananchai; Boonyawan, Dheerawan

    2016-12-01

    Pressure ulcers are difficult to treat. Recent reports of low-temperature atmospheric-pressure plasma (LTAPP) indicated its safe and effectiveness in chronic wound care management. It has been shown both in vitro and vivo studies that LTAPP not only helps facilitate wound healing but also has antimicrobial efficacy due to its composition of ion and electron, free radicals, and ultraviolet ray. We studied the beneficial effect of LTAPP specifically on pressure ulcers. In a prospective randomized study, 50 patients with pressure ulcers were divided into 2 groups: Control group received standard wound care and the study group was treated with LTAPP once every week for 8 consecutive weeks in addition to standard wound care. We found that the group treated with LTAPP had significantly better PUSH (Pressure Ulcer Scale for Healing) scores and exudate amount after 1 week of treatment. There was also a reduction in bacterial load after 1 treatment regardless of the species of bacteria identified.

  5. Effects of initiating anaerobic digestion of layer-hen poultry dung at sub-atmospheric pressure

    Directory of Open Access Journals (Sweden)

    Chima C. Ngumah

    2013-12-01

    Full Text Available This study investigated the effects of initiating anaerobic digestion (AD of dry layer-hen poultry dung at the sub-atmospheric pressure of -30 cmHg on biodegradation, biogasification, and biomethanation. The setup was performed as a batch process at an average ambient temperature of 29±2 0C and a retention time of 15 days. Comparisons were made with two other experiments which were both begun at ambient atmospheric pressure; one was inoculated with digestate from a previous layer-hen dung AD, while the other was not inoculated. The bioreactors initiated at sub-atmospheric pressure, ambient atmospheric pressure without inoculum, and ambient atmospheric pressure with inoculum showed the following for biogas and biomethane yields respectively: 16.8 cm3 g-1 VS and 15.46 cm3 g 1 VS, 25.10 cm3 g-1 VS and 12.85 cm3 g-1 VS, 21.44 cm3 g-1 VS and 14.88 cm3 g 1 VS. In the same order, after AD, the following values were recorded for volatile solids and total viable counts (prokaryotes and fungi in the digestates: 40.33% and 23.22 x 106 cfu mL-1, 43.42% and 22.17 x 106 cfu mL-1, 41.11% and 13.3 x 106 cfu mL-1. The feedstock showed values of 83.93% and 3.98 x 106 cfu mL-1 for volatile solids and total viable count respectively. There was a slight difference in the volatile solids of the digestates of the three bioreactors after AD. The pH recorded for the feedstock slurry before AD was 7.9 at 30oC, while after AD, the digestates from all the three bioreactors showed the same pH of 5.9 at 29 0C. Statistical analysis using ANOVA showed no significant difference in biogas yields of the feedstock for the three bioreactors (A, B, C. ANOVA showed no significant difference for biomethane yields in the bioreactors initiated at sub-atmospheric pressure and for those initiated at ambient atmospheric pressure with inoculums. However, it showed significant difference in the bioreactor initiated at sub-atmospheric pressure and that initiated at ambient atmospheric

  6. The Effect of Varying Atmospheric Pressure upon Habitability and Biosignatures of Earth-like Planets.

    Science.gov (United States)

    Keles, Engin; Grenfell, John Lee; Godolt, Mareike; Stracke, Barbara; Rauer, Heike

    2018-02-01

    Understanding the possible climatic conditions on rocky extrasolar planets, and thereby their potential habitability, is one of the major subjects of exoplanet research. Determining how the climate, as well as potential atmospheric biosignatures, changes under different conditions is a key aspect when studying Earth-like exoplanets. One important property is the atmospheric mass, hence pressure and its influence on the climatic conditions. Therefore, the aim of the present study is to understand the influence of atmospheric mass on climate, hence habitability, and the spectral appearance of planets with Earth-like, that is, N 2 -O 2 dominated, atmospheres orbiting the Sun at 1 AU. This work utilizes a 1D coupled, cloud-free, climate-photochemical atmospheric column model; varies atmospheric surface pressure from 0.5 to 30 bar; and investigates temperature and key species profiles, as well as emission and brightness temperature spectra in a range between 2 and 20 μm. Increasing the surface pressure up to 4 bar leads to an increase in the surface temperature due to increased greenhouse warming. Above this point, Rayleigh scattering dominates, and the surface temperature decreases, reaching surface temperatures below 273 K (approximately at ∼34 bar surface pressure). For ozone, nitrous oxide, water, methane, and carbon dioxide, the spectral response either increases with surface temperature or pressure depending on the species. Masking effects occur, for example, for the bands of the biosignatures ozone and nitrous oxide by carbon dioxide, which could be visible in low carbon dioxide atmospheres. Key Words: Planetary habitability and biosignatures-Atmospheres-Radiative transfer. Astrobiology 18, 116-132.

  7. Real-time analysis of ambient organic aerosols using aerosol flowing atmospheric-pressure afterglow mass spectrometry (AeroFAPA-MS)

    Science.gov (United States)

    Brüggemann, Martin; Karu, Einar; Stelzer, Torsten; Hoffmann, Thorsten

    2015-04-01

    Organic aerosol accounts for a major fraction of atmospheric aerosols and has implications on the earth's climate and human health. However, due to the chemical complexity its measurement remains a major challenge for analytical instrumentation.1 Here, we present the development, characterization and application of a new soft ionization technique that allows mass spectrometric real-time detection of organic compounds in ambient aerosols. The aerosol flowing atmospheric-pressure afterglow (AeroFAPA) ion source utilizes a helium glow discharge plasma to produce excited helium species and primary reagent ions. Ionization of the analytes occurs in the afterglow region after thermal desorption and results mainly in intact molecular ions, facilitating the interpretation of the acquired mass spectra. In the past, similar approaches were used to detect pesticides, explosives or illicit drugs on a variety of surfaces.2,3 In contrast, the AeroFAPA source operates 'online' and allows the detection of organic compounds in aerosols without a prior precipitation or sampling step. To our knowledge, this is the first application of an atmospheric-pressure glow discharge ionization technique to ambient aerosol samples. We illustrate that changes in aerosol composition and concentration are detected on the time scale of seconds and in the ng-m-3 range. Additionally, the successful application of AeroFAPA-MS during a field study in a mixed forest region in Central Europe is presented. Several oxidation products of monoterpenes were clearly identified using the possibility to perform tandem MS experiments. The acquired data are in agreement with previous studies and demonstrate that AeroFAPA-MS is a suitable tool for organic aerosol analysis. Furthermore, these results reveal the potential of this technique to enable new insights into aerosol formation, growth and transformation in the atmosphere. References: 1) IPCC, 2013: Summary for Policymakers. In: Climate Change 2013: The

  8. Surface chemical changes of atmospheric pressure plasma treated rabbit fibres important for felting process

    Energy Technology Data Exchange (ETDEWEB)

    Štěpánová, Vlasta, E-mail: vstepanova@mail.muni.cz [Department of Physical Electronics, Faculty of Science Masaryk University, Kotlářská 2, 611 37 Brno (Czech Republic); Slavíček, Pavel; Stupavská, Monika; Jurmanová, Jana [Department of Physical Electronics, Faculty of Science Masaryk University, Kotlářská 2, 611 37 Brno (Czech Republic); Černák, Mirko [Department of Physical Electronics, Faculty of Science Masaryk University, Kotlářská 2, 611 37 Brno (Czech Republic); Department of Experimental Physics, Faculty of Mathematics, Physics and Informatics, Comenius University, Mlynská dolina F2, 842 48 Bratislava (Slovakia)

    2015-11-15

    Graphical abstract: - Highlights: • Rabbit fibres plasma treatment is an effective method for fibres modification. • Atmospheric pressure plasma treatment is able to affect fibres properties. • Surface changes on fibres after plasma treatment were analysed via SEM, ATR-FTIR, XPS. • Significant increase of fibres wettability after plasma treatment was observed. • Plasma treatment at atmospheric pressure can replace the chemical treatment of fibres. - Abstract: We introduce the atmospheric pressure plasma treatment as a suitable procedure for in-line industrial application of rabbit fibres pre-treatment. Changes of rabbit fibre properties due to the plasma treatment were studied in order to develop new technology of plasma-based treatment before felting. Diffuse Coplanar Surface Barrier Discharge (DCSBD) in ambient air at atmospheric pressure was used for plasma treatment. Scanning electron microscopy was used for determination of the fibres morphology before and after plasma treatment. X-ray photoelectron spectroscopy and attenuated total reflectance-Fourier transform infrared spectroscopy were used for evaluation of reactive groups. The concentration of carbon decreased and conversely the concentration of nitrogen and oxygen increased after plasma treatment. Aging effect of plasma treated fibres was also investigated. Using Washburn method the significant increase of fibres wettability was observed after plasma treatment. New approach of pre-treatment of fibres before felting using plasma was developed. Plasma treatment of fibres at atmospheric pressure can replace the chemical method which consists of application of strong acids on fibres.

  9. Seasonal emanation of radon at Ghuttu, northwest Himalaya: Differentiation of atmospheric temperature and pressure influences.

    Science.gov (United States)

    Kamra, Leena

    2015-11-01

    Continuous monitoring of radon along with meteorological parameters has been carried out in a seismically active area of Garhwal region, northwest Himalaya, within the frame work of earthquake precursory research. Radon measurements are carried out by using a gamma ray detector installed in the air column at a depth of 10m in a 68m deep borehole. The analysis of long time series for 2006-2012 shows strong seasonal variability masked by diurnal and multi-day variations. Isolation of a seasonal cycle by minimising short-time by 31 day running average shows a strong seasonal variation with unambiguous dependence on atmospheric temperature and pressure. The seasonal characteristics of radon concentrations are positively correlated to atmospheric temperature (R=0.95) and negatively correlated to atmospheric pressure (R=-0.82). The temperature and pressure variation in their annual progressions are negatively correlated. The calculations of partial correlation coefficient permit us to conclude that atmospheric temperature plays a dominant role in controlling the variability of radon in borehole, 71% of the variability in radon arises from the variation in atmospheric temperature and about 6% of the variability is contributed by atmospheric pressure. The influence of pressure variations in an annual cycle appears to be a pseudo-effect, resulting from the negative correlation between temperature and pressure variations. Incorporation of these results explains the varying and even contradictory claims regarding the influence of the pressure variability on radon changes in the published literature. Temperature dependence, facilitated by the temperature gradient in the borehole, controls the transportation of radon from the deep interior to the surface. Copyright © 2015 Elsevier Ltd. All rights reserved.

  10. In-situ reactive glow discharge cleaning of NSLS distributed ion pumps

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, E.D.; Chou, T.S.

    1988-01-01

    Based on our experience with the in-situ cleaning of optical systems by reactive r.f. glow discharges and the conditioning and preparation of distributed ion pump (DIP) elements, we have sought to develop strategies for recovering from severe vacuum accidents by restoring DIP elements of storage rings such as those at the NSLS in-situ. In this paper we will describe a series of experiments conducted in a test apparatus to condition a so called ''egg-crate'' DIP in-situ, (this older type element being common in older storage rings). A new untreated element which was unable to pump below 5x10 /sup /minus/8/ Torr in its initial condition was treated in oxygen and subsequent argon r.f. discharges utilizing the pump element as the discharge electrode producing a nitrogen pumping speed of 168 l/s at 2x10 /sup /minus/8/ Torr. A light bake at 75/degree/C increased this to nearly 500 l/s at 5x10 /sup /minus/8/ Torr. After exposure to atmosphere the speed was reduced to nil at these pressures but subsequently recovered, without bakeout, by glow discharge cleaning. 22 refs., 6 figs.

  11. In-situ reactive glow discharge cleaning of NSLS distributed ion pumps

    International Nuclear Information System (INIS)

    Johnson, E.D.; Chou, T.S.

    1988-01-01

    Based on our experience with the in-situ cleaning of optical systems by reactive r.f. glow discharges and the conditioning and preparation of distributed ion pump (DIP) elements, we have sought to develop strategies for recovering from severe vacuum accidents by restoring DIP elements of storage rings such as those at the NSLS in-situ. In this paper we will describe a series of experiments conducted in a test apparatus to condition a so called ''egg-crate'' DIP in-situ, (this older type element being common in older storage rings). A new untreated element which was unable to pump below 5x10 /sup /minus/8/ Torr in its initial condition was treated in oxygen and subsequent argon r.f. discharges utilizing the pump element as the discharge electrode producing a nitrogen pumping speed of 168 l/s at 2x10 /sup /minus/8/ Torr. A light bake at 75/degree/C increased this to nearly 500 l/s at 5x10 /sup /minus/8/ Torr. After exposure to atmosphere the speed was reduced to nil at these pressures but subsequently recovered, without bakeout, by glow discharge cleaning. 22 refs., 6 figs

  12. Borax as flux on sintering of iron Ancor Steel 1000® under glow discharge

    Science.gov (United States)

    Ariza Suarez, H. G.; Sarmiento Santos, A.; Ortiz Otálora, C. A.

    2016-02-01

    This work studies the flux effect of borax (di sodium tetraborate decahydrate) on sintering of iron Ancor Steel 1000® in abnormal glow discharge. The incidence of the percentage by weight of borax and the sintering temperature in the process were observed. Samples of powder metallurgical iron were prepared with proportions of 0.50%, 2.0%, 4.0% and 6.0% by weight of borax using the procedures of powder metallurgy. The samples were sintered at 800 and 1100°C for 30min, by glow discharge at low pressure in a reducing atmosphere composed of 20% H2+80% Ar. The samples in compact green-state were analyzed by TGA-DSC to determine the fusion process and mass loss during sintering. The analysis of microhardness and density, shows that at a sintering temperature of 800°C the sample density decreases and the sample microhardness increases with respect to sintered samples without borax. Sintered samples were analysed by DRX showing the absence of precipitates.

  13. Three electrode atmospheric pressure plasma jet in helium flow

    Science.gov (United States)

    Maletic, Dejan; Puac, Nevena; Malovic, Gordana; Petrovic, Zoran Lj.

    2015-09-01

    Plasma jets are widely used in various types of applications and lately more and more in the field of plasma medicine. However, it is not only their applicability that distinguishes them from other atmospheric plasma sources, but also the behavior of the plasma. It was shown that plasma plume is not continuous, but discrete set of plasma packages. Here we present iCCD images and current voltage characteristics of a three electrode plasma jet. Our plasma jet has a simple design with body made of glass tube and two transparent electrodes wrapped around it. The additional third metal tip electrode was positioned at 10 and 25 mm in front of the jet nozzle and connected to the same potential as the powered electrode. Power transmitted to the plasma was from 0.5 W to 4.0 W and the helium flow rate was kept constant at 4 slm. For the 10 mm configuration plasma is ignited on the metal tip in the whole period of the excitation signal and in the positive half cycle plasma ``bullet'' is propagating beyond the metal tip. In contrast to that, for the 25 mm configuration at the tip electrode plasma can be seen only in the minimum and maximum of the excitation signal, and there is no plasma ``bullet'' formation. This research has been supported by the Ministry of Education, Science and Technological Development, Republic of Serbia, under projects ON171037 and III41011.

  14. Optical Emission Spectroscopy of an Atmospheric Pressure Plasma Jet During Tooth Bleaching Gel Treatment.

    Science.gov (United States)

    Šantak, Vedran; Zaplotnik, Rok; Tarle, Zrinka; Milošević, Slobodan

    2015-11-01

    Optical emission spectroscopy was performed during atmospheric pressure plasma needle helium jet treatment of various tooth-bleaching gels. When the gel sample was inserted under the plasma plume, the intensity of all the spectral features increased approximately two times near the plasma needle tip and up to two orders of magnitude near the sample surface. The color change of the hydroxylapatite pastille treated with bleaching gels in conjunction with the atmospheric pressure plasma jet was found to be in correlation with the intensity of OH emission band (309 nm). Using argon as an additive to helium flow (2 L/min), a linear increase (up to four times) of OH intensity and, consequently, whitening (up to 10%) of the pastilles was achieved. An atmospheric pressure plasma jet activates bleaching gel, accelerates OH production, and accelerates tooth bleaching (up to six times faster).

  15. Effect of the atmospheric pressure nonequilibrium plasmas on the conformational changes of plasmid DNA

    International Nuclear Information System (INIS)

    Yan Xu; He Guangyuan; Shi Mengjun; Gao Xuan; Li Yin; Ma Fengyun; Yu Men; Wang Changdong; Wang Yuesheng; Yang Guangxiao; Zou Fei; Lu Xinpei; Xiong Qing; Xiong Zilan

    2009-01-01

    The cold atmospheric pressure plasma, which has been widely used for biomedical applications, may potentially affect the conformation of DNA. In this letter, an atmospheric pressure plasma plume is used to investigate its effects on the conformational changes of DNA of plasmid pAHC25. It is found that the plasma plume could cause plasmid DNA topology alteration, resulting in the percentage of the supercoiled plasmid DNA form decreased while that of the open circular and linearized form of plasmid DNA increased as detected by agrose gel electrophoresis. On the other hand, further investigation by using polymerase chain reaction method shows that the atmospheric pressure plasma jet treatments under proper conditions does not affect the genes of the plasmid DNA, which may have potential application in increasing the transformation frequency by genetic engineering.

  16. Achieving uniform layer deposition by atmospheric-pressure plasma-enhanced chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jae-Ok [Department of Plasma Engineering, Korea Institute of Machinery & Materials (KIMM), Daejeon 305-343 (Korea, Republic of); Kang, Woo Seok, E-mail: kang@kimm.re.kr [Department of Plasma Engineering, Korea Institute of Machinery & Materials (KIMM), Daejeon 305-343 (Korea, Republic of); Department of Environment & Energy Mechanical Engineering, University of Science & Technology (UST), Daejeon 305-350 (Korea, Republic of); Hur, Min; Lee, Jin Young [Department of Plasma Engineering, Korea Institute of Machinery & Materials (KIMM), Daejeon 305-343 (Korea, Republic of); Song, Young-Hoon [Department of Plasma Engineering, Korea Institute of Machinery & Materials (KIMM), Daejeon 305-343 (Korea, Republic of); Department of Environment & Energy Mechanical Engineering, University of Science & Technology (UST), Daejeon 305-350 (Korea, Republic of)

    2015-12-31

    This work investigates the use of plasma-enhanced chemical vapor deposition under atmospheric pressure for achieving uniform layer formation. Electrical and optical measurements demonstrated that the counterbalance between oxygen and precursors maintained the homogeneous discharge mode, while creating intermediate species for layer deposition. Several steps of the deposition process of the layers, which were processed on a stationary stage, were affected by flow stream and precursor depletion. This study showed that by changing the flow streamlines using substrate stage motion uniform layer deposition under atmospheric pressure can be achieved. - Highlights: • Zirconium oxide was deposited by atmospheric-pressure plasma-enhanced chemical vapor deposition. • Homogeneous plasma was maintained by counterbalancing between discharge gas and precursors. • Several deposition steps were observed affected by the gas flow stream and precursor depletion. • Thin film layer was uniformly grown when the substrate underwent a sweeping motion.

  17. Physico-chemical characteristics of high performance polymer modified by low and atmospheric pressure plasma

    International Nuclear Information System (INIS)

    Bhatnagar, Nitu; Sangeeta, Jha; Bhowmik, Shantanu; Gupta, Govind; Moon, J.B.; Kim, C.G.

    2012-01-01

    In this work, the effect of low pressure plasma and atmospheric p ressure plasma treatment on surface properties and adhesion characteristics of high performance polymer, Polyether Ether Ketone (PEEK) are investigated in terms of Fourier Transform Infrared Spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and Atomic Force Microscopy (AFM). The experimental results show that the PEEK surface treated by atmospheric pressure plasma lead to an increase in the polar component of the surface energy, resulting in improving the adhesion characteristics of the PEEK/Epoxy adhesive system. Also, the roughness of the treated surfaces is largely increased as confirmed by AFM observation. These results can be explained by the fact that the atmospheric pressure plasma treatment of PEEK surface yields several oxygen functionalities on hydrophobic surface, which play an important role in increasing the surface polarity, wettability, and the adhesion characteristics of the PEEK/Epoxy adhesive system. (authors)

  18. Atmospheric Airborne Pressure Measurements Using the Oxygen A Band for the ASCENDS Mission

    Science.gov (United States)

    Riris, Haris; Rodriguez, Mike; Stephen, Mark; Hasselbrack, William; Allan, Graham; Mao, Jiamping,; Kawa, Stephan R.; Weaver, Clark J.

    2011-01-01

    We report on airborne atmospheric pressure measurements using new fiber-based laser technology and the oxygen A-band at 765 nm. Remote measurements of atmospheric temperature and pressure are required for a number of NASA Earth science missions and specifically for the Active Sensing of CO2 Emissions Over Nights, Days, and Seasons (ASCENDS) mission. Accurate measurements of tropospheric CO2 on a global scale are very important in order to better understand its sources and sinks and to improve predictions on any future climate change. The ultimate goal of a CO2 remote sensing mission, such as ASCENDS, is to derive the CO2 concentration in the atmosphere in terms of mole fraction in unit of parts-per-million (ppmv) with regard to dry air. Therefore, both CO2 and the dry air number of molecules in the atmosphere are needed in deriving this quantity. O2 is a stable molecule and uniformly mixed in the atmosphere. Measuring the O2 absorption in the atmosphere can thus be used to infer the dry air number of molecules and then used to calculate CO2 concentration. With the knowledge of atmospheric water vapor, we can then estimate the total surface pressure needed for CO2 retrievals. Our work, funded by the ESTO IIP program, uses fiber optic technology and non-linear optics to generate 765 nm laser radiation coincident with the Oxygen A-band. Our pulsed, time gated technique uses several on- and off-line wavelengths tuned to the O2 absorption line. The choice of wavelengths allows us to measure the pressure by using two adjacent O2 absorptions in the Oxygen A-band. Our retrieval algorithm fits the O2 lineshapes and derives the pressure. Our measurements compare favorably with a local weather monitor mounted outside our laboratory and a local weather station.

  19. Source of temperature and pressure pulsations during sessile droplet evaporation into multicomponent atmospheres.

    Science.gov (United States)

    Persad, Aaron H; Sefiane, Khellil; Ward, Charles A

    2013-10-29

    During sessile droplet evaporation, studies with IR thermography and shadowgraphs have indicated temperature pulsations. We confirm those observations with microthermocouples, but microthermocouples also indicate temperature pulsations in the atmosphere of the droplet. The pressure in this atmosphere pulsated as well and was correlated with the temperature pulsations in the droplet. Also, we find that if a droplet evaporates into its own vapor, there are no temperature or pressure pulsations. The pulsations occur only if the droplet evaporates into an atmosphere with a component having a heat of solution with the droplet when it adsorbs-absorbs. None of the currently proposed mechanisms for the temperature pulsations provide an explanation for the coupling between the temperature pulsations in the droplet and the vapor-phase pressure pulsations, and for the absence of the pulsations when the system is single-component. As a mechanism for the pulsations, we propose that when a droplet is exposed to an atmosphere containing a component that has a heat of solution with the droplet, energy will be released from adsorption-absorption. This energy will cause pulsations in the evaporation flux, and these pulsations could cause the observed temperature and pressure pulsations. We examine this mechanism by showing that, if the measured temperature pulsations in a water droplet exposed to a methanol atmosphere are used as the input to a theory of evaporation kinetics (statistical rate theory), the pressure pulsations of the water vapor in the methanol atmosphere are predicted and agree with those measured with a quadrupole mass analyzer. When the inputs and outputs are reversed in the theory, we find that the temperature pulsations in the droplet are correctly predicted from the measured water vapor pulsations in the atmosphere.

  20. Electronic quenching of OH(A) by water in atmospheric pressure plasmas and its influence on the gas temperature determination by OH(A-X) emission

    International Nuclear Information System (INIS)

    Bruggeman, Peter; Schram, Daan C; Iza, Felipe; Kong, Michael G; Guns, Peter; Lauwers, Daniel; Leys, Christophe; Gonzalvo, Yolanda Aranda

    2010-01-01

    In this paper it is shown that electronic quenching of OH(A) by water prevents thermalization of the rotational population distribution of OH(A). This means that the observed ro-vibrational OH(A-X) emission band is (at least partially) an image of the formation process and is determined not only by the gas temperature. The formation of negative ions and clusters for larger water concentrations can contribute to the non-equilibrium. The above is demonstrated in RF excited atmospheric pressure glow discharges in He-water mixtures in a parallel metal plate reactor by optical emission spectroscopy. For this particular case a significant overpopulation of high rotational states appears around 1000 ppm H 2 O in He. The smallest temperature parameter of a non-Boltzmann (two-temperature) distribution fitted to the experimental spectrum of OH(A-X) gives a good representation of the gas temperature. Only the rotational states with the smallest rotational numbers (J ≤ 7) are thermalized and representative for the gas temperature.

  1. Electronic quenching of OH(A) by water in atmospheric pressure plasmas and its influence on the gas temperature determination by OH(A-X) emission

    Energy Technology Data Exchange (ETDEWEB)

    Bruggeman, Peter; Schram, Daan C [Department of Applied Physics, Technische Universiteit Eindhoven, PO Box 513, 5600 MB Eindhoven (Netherlands); Iza, Felipe; Kong, Michael G [Department of Electronic and Electrical Engineering, Loughborough University, Loughborough, Leicestershire LE11 3TU (United Kingdom); Guns, Peter; Lauwers, Daniel; Leys, Christophe [Department of Applied Physics, Ghent University, Jozef Plateaustraat 22, B-9000 Ghent (Belgium); Gonzalvo, Yolanda Aranda [Plasma and Surface Analysis Division, Hiden Analytical Ltd, 420 Europa Boulevard, Warrington WA5 7UN (United Kingdom)], E-mail: p.j.bruggeman@tue.nl

    2010-02-15

    In this paper it is shown that electronic quenching of OH(A) by water prevents thermalization of the rotational population distribution of OH(A). This means that the observed ro-vibrational OH(A-X) emission band is (at least partially) an image of the formation process and is determined not only by the gas temperature. The formation of negative ions and clusters for larger water concentrations can contribute to the non-equilibrium. The above is demonstrated in RF excited atmospheric pressure glow discharges in He-water mixtures in a parallel metal plate reactor by optical emission spectroscopy. For this particular case a significant overpopulation of high rotational states appears around 1000 ppm H{sub 2}O in He. The smallest temperature parameter of a non-Boltzmann (two-temperature) distribution fitted to the experimental spectrum of OH(A-X) gives a good representation of the gas temperature. Only the rotational states with the smallest rotational numbers (J {<=} 7) are thermalized and representative for the gas temperature.

  2. An Atmospheric Pressure Plasma Setup to Investigate the Reactive Species Formation

    OpenAIRE

    Gorbanev, Yury; Soriano, Robert; O'Connell, Deborah; Chechik, Victor

    2016-01-01

    Non-thermal atmospheric pressure ('cold') plasmas have received increased attention in recent years due to their significant biomedical potential. The reactions of cold plasma with the surrounding atmosphere yield a variety of reactive species, which can define its effectiveness. While efficient development of cold plasma therapy requires kinetic models, model benchmarking needs empirical data. Experimental studies of the source of reactive species detected in aqueous solutions exposed to pla...

  3. Atmospheric pressure ionization-tandem mass spectrometry of the phenicol drug family.

    Science.gov (United States)

    Alechaga, Élida; Moyano, Encarnación; Galceran, M Teresa

    2013-11-01

    In this work, the mass spectrometry behaviour of the veterinary drug family of phenicols, including chloramphenicol (CAP) and its related compounds thiamphenicol (TAP), florfenicol (FF) and FF amine (FFA), was studied. Several atmospheric pressure ionization sources, electrospray (ESI), atmospheric pressure chemical ionization and atmospheric pressure photoionization were compared. In all atmospheric pressure ionization sources, CAP, TAP and FF were ionized in both positive and negative modes; while for the metabolite FFA, only positive ionization was possible. In general, in positive mode, [M + H](+) dominated the mass spectrum for FFA, while the other compounds, CAP, TAP and FF, with lower proton affinity showed intense adducts with species present in the mobile phase. In negative mode, ESI and atmospheric pressure photoionization showed the deprotonated molecule [M-H](-), while atmospheric pressure chemical ionization provided the radical molecular ion by electron capture. All these ions were characterized by tandem mass spectrometry using the combined information obtained by multistage mass spectrometry and high-resolution mass spectrometry in a quadrupole-Orbitrap instrument. In general, the fragmentation occurred via cyclization and losses or fragmentation of the N-(alkyl)acetamide group, and common fragmentation pathways were established for this family of compounds. A new chemical structure for the product ion at m/z 257 for CAP, on the basis of the MS(3) and MS(4) spectra is proposed. Thermally assisted ESI and selected reaction monitoring are proposed for the determination of these compounds by ultra high-performance liquid chromatography coupled to tandem mass spectrometry, achieving instrumental detection limits down to 0.1 pg. Copyright © 2013 John Wiley & Sons, Ltd.

  4. Turbulent jet diffusion flame length evolution with cross flows in a sub-pressure atmosphere

    International Nuclear Information System (INIS)

    Wang, Qiang; Hu, Longhua; Zhang, Xiaozheng; Zhang, Xiaolei; Lu, Shouxiang; Ding, Hang

    2015-01-01

    Highlights: • Quantifying turbulent jet diffusion flame length with cross flows. • Unique data revealed for a sub-atmospheric pressure. • Non-dimensional global correlation proposed for flame trajectory-line length. - Abstract: This paper investigates the evolution characteristics of turbulent jet diffusion flame (flame trajectory-line length, flame height in vertical jet direction) with increasing cross flows in a sub-pressure (64 kPa) atmosphere. The combined effect of cross flow and a special sub-pressure atmosphere condition is revealed, where no data is available in the literatures. Experiments are carried out with a wind tunnel built specially in Lhasa city (altitude: 3650 m; pressure: 64 kPa) and in Hefei city (altitude: 50 m; pressure: 100 kPa), using nozzles with diameter of 3 mm, 4 mm and 5 mm and propane as fuel. It is found that, as cross flow air speed increases from zero, the flame trajectory-line length firstly decreases and then becomes almost stable (for relative small nozzle, 3 mm in this study) or increases (for relative large nozzle, 4 mm and 5 mm in this study) beyond a transitional critical cross flow air speed in normal pressure, however decreases monotonically until being blown-out in the sub-pressure atmosphere. The flame height in jet direction decreases monotonically with cross air flow speed and then reaches a steady value in both pressures. For the transitional state of flame trajectory-line length with increasing cross air flow speed, the corresponding critical cross flow air speed is found to be proportional to the fuel jet velocity, meanwhile independent of nozzle diameter. Correlation models are proposed for the flame height in jet direction and the flame trajectory-line length for both ambient pressures, which are shown to be in good agreement with the experimental results.

  5. Use of Atmospheric-Pressure Plasma Jet for Polymer Surface Modification: An Overview

    Energy Technology Data Exchange (ETDEWEB)

    Kuettner, Lindsey A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-03-16

    Atmospheric-pressure plasma jets (APPJs) are playing an increasingly important role in materials processing procedures. Plasma treatment is a useful tool to modify surface properties of materials, especially polymers. Plasma reacts with polymer surfaces in numerous ways thus the type of process gas and plasma conditions must be explored for chosen substrates and materials to maximize desired properties. This report discusses plasma treatments and looks further into atmospheric-pressure plasma jets and the effects of gases and plasma conditions. Following the short literature review, a general overview of the future work and research at Los Alamos National Laboratory (LANL) is discussed.

  6. Plasma chemistry in an atmospheric pressure Ar/NH3 dielectric barrier discharge

    DEFF Research Database (Denmark)

    Fateev, A.; Leipold, F.; Kusano, Y.

    2005-01-01

    An atmospheric pressure dielectric barrier discharge (DBD) in Ar/NH3 (0.1 - 10%) mixtures with a parallel plate electrode geometry was studied. The plasma was investigated by emission and absorption spectroscopy in the UV spectral range. Discharge current and voltage were measured as well. UV...... of an atmospheric pressure Ar/NH3 DBD are H-2, N-2 and N2H4. The hydrazine (N2H4) concentration in the plasma and in the exhaust gases at various ammonia concentrations and different discharge powers was measured. Thermal N2H4 decomposition into NH2 radicals may be used for NOx reduction processes....

  7. Effects of initiating anaerobic digestion of layer-hen poultry dung at sub-atmospheric pressure

    OpenAIRE

    Ngumah, Chima C.; Ogbulie, Jude N.; Orji, Justina C.; Amadi, Ekperechi S.

    2013-01-01

    This study investigated the effects of initiating anaerobic digestion (AD) of dry layer-hen poultry dung at the sub-atmospheric pressure of -30 cmHg on biodegradation, biogasification, and biomethanation. The setup was performed as a batch process at an average ambient temperature of 29±2 ºC and a retention time of 15 days. Comparisons were made with two other experiments which were both begun at ambient atmospheric pressure; one was inoculated with digestate from a previous layer-hen dung AD...

  8. Effect of Atmospheric Pressure Plasma and Subsequent Enzymatic Treatment on Flax Fabrics

    International Nuclear Information System (INIS)

    Zhong Shaofeng; Yang Bin; Ou Qiongrong

    2015-01-01

    The objective is to investigate the effect of atmospheric pressure dielectric barrier discharge (APDBD) plasma and subsequent cellulase enzyme treatment on the properties of flax fabrics. The changes of surface morphology and structure, physico-mechanical properties, hydrophilicity, bending properties, whiteness, and dyeing properties of the treated substrate were investigated. The results indicated that atmospheric pressure dielectric barrier discharge plasma pre-treatment and subsequent cellulase enzyme treatment could diminish the hairiness of flax fabrics, endowing the flax fabrics with good bending properties, water uptake and fiber accessibility while keeping their good mechanical properties compared with those treated with cellulase enzyme alone. (paper)

  9. Atmospheric pressure plasmas for surface modification of flexible and printed electronic devices: A review

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kyong Nam; Lee, Seung Min; Mishra, Anurag [Department of Materials Science and Engineering, Sungkyunkwan University, Suwon, Gyeonggi-do 440-746 (Korea, Republic of); Yeom, Geun Young, E-mail: gyyeom@skku.edu [Department of Materials Science and Engineering, Sungkyunkwan University, Suwon, Gyeonggi-do 440-746 (Korea, Republic of); SKKU Advanced Institute of Nano Technology (SAINT), Sungkyunkwan University, Suwon, Gyeonggi-do 440-746 (Korea, Republic of)

    2016-01-01

    Recently, non-equilibrium atmospheric pressure plasma, especially those operated at low gas temperatures, have become a topic of great interest for the processing of flexible and printed electronic devices due to several benefits such as the reduction of process and reactor costs, the employment of easy-to-handle apparatuses and the easier integration into continuous production lines. In this review, several types of typical atmospheric pressure plasma sources have been addressed, and the processes including surface treatment, texturing and sintering for application to flexible and printed electronic devices have been discussed.

  10. Destruction of Bacillus subtilis cells using an atmospheric-pressure dielectric capillary electrode discharge plasma

    International Nuclear Information System (INIS)

    Panikov, N.S.; Paduraru, S.; Crowe, R.; Ricatto, P.J.; Christodoulatos, C.; Becker, K.

    2002-01-01

    The results of experiments aimed at the investigation of the destruction of spore-forming bacteria, which are believed to be among the most resistant microorganisms, using a novel atmospheric-pressure dielectric capillary electrode discharge plasma are reported. Various well-characterized cultures of Bacillus subtilis were prepared, subjected to atmospheric-pressure plasma jets emanating from a plasma shower reactor operated either in He or in air (N 2 /O 2 mixture) at various power levels and exposure times, and analyzed after plasma treatment. Reductions in colony-forming units ranged from 10 4 (He plasma) to 10 8 (air plasma) for plasma exposure times of less than 10 minutes. (author)

  11. Dissolution glow curve in LLD

    International Nuclear Information System (INIS)

    Haverkamp, U.; Wiezorek, C.; Poetter, R.

    1990-01-01

    Lyoluminescence dosimetry is based upon light emission during dissolution of previously irradiated dosimetric materials. The lyoluminescence signal is expressed in the dissolution glow curve. These curves begin, depending on the dissolution system, with a high peak followed by an exponentially decreasing intensity. System parameters that influence the graph of the dissolution glow curve, are, for example, injection speed, temperature and pH value of the solution and the design of the dissolution cell. The initial peak does not significantly correlate with the absorbed dose, it is mainly an effect of the injection. The decay of the curve consists of two exponential components: one fast and one slow. The components depend on the absorbed dose and the dosimetric materials used. In particular, the slow component correlates with the absorbed dose. In contrast to the fast component the argument of the exponential function of the slow component is independent of the dosimetric materials investigated: trehalose, glucose and mannitol. The maximum value, following the peak of the curve, and the integral light output are a measure of the absorbed dose. The reason for the different light outputs of various dosimetric materials after irradiation with the same dose is the differing solubility. The character of the dissolution glow curves is the same following irradiation with photons, electrons or neutrons. (author)

  12. Alteration of five organic compounds by glow discharge plasma and UV light under simulated Mars conditions

    Science.gov (United States)

    Hintze, Paul E.; Buhler, Charles R.; Schuerger, Andrew C.; Calle, Luz M.; Calle, Carlos I.

    2010-08-01

    The Viking missions to Mars failed to detect any organic material in regolith samples. Since then, several removal mechanisms of organic material have been proposed. Two of these proposed methods are removal due to exposure to plasmas created in dust devils and exposure to UV irradiation. The experiments presented here were performed to identify similarities between the two potential removal mechanisms and to identify any compounds produced from these mechanisms that would have been difficult for the Viking instruments to detect. Five organic compounds, phenanthrene, octadecane, octadecanoic acid, decanophenone and benzoic acid, were exposed to a glow discharge plasma created in simulated martian atmospheres as might be present in dust devils, and to UV irradiation similar to that found at the surface of Mars. Glow discharge exposure was carried out in a chamber with 6.9 mbar pressure of a Mars like gas composed mostly of carbon dioxide. The plasma was characterized using emission spectroscopy and found to contain cations and excited neutral species including carbon dioxide, carbon monoxide, and nitrogen. UV irradiation experiments were performed in a Mars chamber which simulates the temperature, pressure, atmospheric composition, and UV fluence rates of equatorial Mars. The non-volatile residues left after each exposure were characterized by mass loss, infrared spectroscopy and high resolution mass spectrometry. Oxidized, higher molecular weight versions of the parent compounds containing carbonyl, hydroxyl and alkenyl functional groups were identified. The presence of these oxidized compounds suggests that searches for organic material in soils on Mars use instrumentation suitable for detection of compounds which contain the above functional groups. Discussions of possible reaction mechanisms are given.

  13. Fructooligosaccharides integrity after atmospheric cold plasma and high-pressure processing of a functional orange juice.

    Science.gov (United States)

    Almeida, Francisca Diva Lima; Gomes, Wesley Faria; Cavalcante, Rosane Souza; Tiwari, Brijesh K; Cullen, Patrick J; Frias, Jesus Maria; Bourke, Paula; Fernandes, Fabiano A N; Rodrigues, Sueli

    2017-12-01

    In this study, the effect of atmospheric pressure cold plasma and high-pressure processing on the prebiotic orange juice was evaluated. Orange juice containing 7g/100g of commercial fructooligosaccharides (FOS) was directly and indirectly exposed to a plasma discharge at 70kV with processing times of 15, 30, 45 and 60s. For high-pressure processing, the juice containing the same concentration of FOS was treated at 450MPa for 5min at 11.5°C in an industrial equipment (Hyperbaric, model: 300). After the treatments, the fructooligosaccharides were qualified and quantified by thin layer chromatography. The organic acids and color analysis were also evaluated. The maximal overall fructooligosaccharides degradation was found after high-pressure processing. The total color difference was pressure and plasma processing. citric and ascorbic acid (Vitamin C) showed increased content after plasma and high-pressure treatment. Thus, atmospheric pressure cold plasma and high-pressure processing can be used as non-thermal alternatives to process prebiotic orange juice. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Common Gamma-ray Glows above Thunderclouds

    Science.gov (United States)

    Kelley, Nicole; Smith, David; Dwyer, Joseph; Hazelton, Bryna; Grefenstette, Brian; Lowell, Alex; Splitt, Michael; Lazarus, Steven; Rassoul, Hamid

    2013-04-01

    Gamma-ray glows are continuous, long duration gamma- and x-ray emission seen coming from thunderclouds. The Airborne for Energetic Lightning Emissions (ADELE) observed 12 gamma-ray glows during its summer 2009 flight campaign over the areas of Colorado and Florida in the United States. For these glows we shall present their spectra, relationship to lightning activity and how their duration and size changes as a function of distance. Gamma-ray glows follow the relativistic runaway electron avalanche (RREA) spectrum and have been previously measured from the ground and inside the cloud. ADELE measured most glows as it flew above the screening layer of the cloud. During the brightest glow on August 21, 2009, we can show that we are flying directly into a downward facing relativistic runaway avalanche, indicative of flying between the upper positive and negative screening layer of the cloud. In order to explain the brightness of this glow, RREA with an electric field approaching the limit for relativistic feedback must be occurring. Using all 12 glows, we show that lightning activity diminishes during the onset of the glow. Using this along with the fact that glows occur as the field approaches the level necessary for feedback, we attempt to distinguish between two possibilities: that glows are evidence that RREA with feedback, rather than lightning, is sometimes the primary channel for discharging the cloud, or else that the overall discharging is still controlled by lightning, with glows simply appearing during times when a subsidence of lightning allows the field to rise above the threshold for RREA.

  15. Surface modification of nanofibrillated cellulose films by atmospheric pressure dielectric barrier discharge

    DEFF Research Database (Denmark)

    Siró, Istvan; Kusano, Yukihiro; Norrman, Kion

    2013-01-01

    of atmospheric pressure plasma treatment, the water contact angle of NFC films increased and the values were comparable with those of PLA films. On the other hand, surface chemical characterization revealed inhomogeneity of the plasma treatment and limited improvement in adhesion between NFC and PLA films...

  16. Atmospheric pressure plasma treatment of glass fibre composite for adhesion improvement

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Mortensen, H.; Stenum, Bjarne

    2007-01-01

    Glass-fibre-reinforced polyester composite plates were treated with an atmospheric pressure dielectric barrier discharge. Synthetic air was used as the treatment gas. The water contact angle dropped markedly from 84 to 22° after a 2-s treatment, and decreased to 0° when the composite plates were...

  17. Patterned deposition by atmospheric pressure plasma-enhanced spatial atomic layer deposition

    NARCIS (Netherlands)

    Poodt, P.; Kniknie, B.J.; Branca, A.; Winands, G.J.J.; Roozeboom, F.

    2011-01-01

    An atmospheric pressure plasma enhanced atomic layer deposition reactor has been developed, to deposit Al2O3 films from trimethyl aluminum and an He/O2 plasma. This technique can be used for 2D patterned deposition in a single in-line process by making use of switched localized plasma sources. It

  18. Cold atmospheric pressure plasma treatment of ready-to-eat meat

    DEFF Research Database (Denmark)

    Röd, Sara Katrine Solhøj; Hansen, Flemming; Leipold, Frank

    Sliced ready-to-eat (RTE) meat products are susceptible to growth of the foodborne pathogenic bacterium, Listeria monocytogenes. Cold atmospheric pressure plasma (CAPP) may be applicable for surface decontamination in sealed bags thus avoiding recontamination. Plasmas (Fig. 1), created in neutral...

  19. Thin-Layer Chromatography/Desorption Atmospheric Pressure Photoionization Orbitrap Mass Spectrometry of Lipids

    Czech Academy of Sciences Publication Activity Database

    Rejšek, Jan; Vrkoslav, Vladimír; Vaikkinen, A.; Haapala, M.; Kauppila, T. J.; Kostiainen, R.; Cvačka, Josef

    2016-01-01

    Roč. 88, č. 24 (2016), s. 12279-12286 ISSN 0003-2700 R&D Projects: GA ČR GAP206/12/0750 Institutional support: RVO:61388963 Keywords : desorption atmospheric pressure photoionization * thin-layer chromatography * lipids Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 6.320, year: 2016

  20. Atmospheric pressure photoionisation : An ionization method for liquid chromatography-mass spectrometry

    NARCIS (Netherlands)

    Robb, DB; Covey, TR; Bruins, AP

    2000-01-01

    Atmospheric pressure photoionization (APPI) has been successfully demonstrated to provide high sensitivity to LC-MS analysis. A vacuum-ultraviolet lamp designed for photoionization detection in gas chromatography is used as a source of 10-eV photons. The mixture of samples and solvent eluting from

  1. Fluoropolymer coated alanine films treated by atmospheric pressure plasmas − In comparison with gamma irradiation

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Bardenshtein, Alexander; Morgen, Per

    2018-01-01

    Fluoropolymer coated alanine films are treated by a dielectric barrier discharge and a gliding arc at atmospheric pressure as well as with gamma irradiation. The film surfaces and the underlying bulk materials are characterized before and after each treatment. The fluorine content decreases...

  2. Comparison of the sensitivity of mass spectrometry atmospheric pressure ionization techniques in the analysis of porphyrinoids.

    Science.gov (United States)

    Swider, Paweł; Lewtak, Jan P; Gryko, Daniel T; Danikiewicz, Witold

    2013-10-01

    The porphyrinoids chemistry is greatly dependent on the data obtained in mass spectrometry. For this reason, it is essential to determine the range of applicability of mass spectrometry ionization methods. In this study, the sensitivity of three different atmospheric pressure ionization techniques, electrospray ionization, atmospheric pressure chemical ionization and atmospheric pressure photoionization, was tested for several porphyrinods and their metallocomplexes. Electrospray ionization method was shown to be the best ionization technique because of its high sensitivity for derivatives of cyanocobalamin, free-base corroles and porphyrins. In the case of metallocorroles and metalloporphyrins, atmospheric pressure photoionization with dopant proved to be the most sensitive ionization method. It was also shown that for relatively acidic compounds, particularly for corroles, the negative ion mode provides better sensitivity than the positive ion mode. The results supply a lot of relevant information on the methodology of porphyrinoids analysis carried out by mass spectrometry. The information can be useful in designing future MS or liquid chromatography-MS experiments. Copyright © 2013 John Wiley & Sons, Ltd.

  3. Decontamination of burn wounds using a cold atmospheric pressure plasma jet

    NARCIS (Netherlands)

    van Gils, Koen; Hofmann, S.; Boekema, B.K.H.L.; Bruggeman, P.J.

    2012-01-01

    Decontamination of burn wounds using a cold atmospheric pressure plasma jet C.A.J. van Gils, S. Hofmann, B. Boekema and P. Bruggeman Eindhoven University of Technology, Department of Applied Physics, group EPG, P.O. Box 513, 5600 MB Eindhoven In the treatment of burn wounds bacterial infections are

  4. Ultrasound enhanced 50 Hz plasma treatment of glass-fiber-reinforced polyester at atmospheric pressure

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Norrman, Kion; Singh, Shailendra Vikram

    2013-01-01

    Glass-fiber-reinforced polyester (GFRP) plates are treated using a 50Hz dielectric barrier discharge at a peak-to-peak voltage of 30 kV in helium at atmospheric pressure with and without ultrasonic irradiation to study adhesion improvement. The ultrasonic waves at the fundamental frequency...

  5. 50-Hz plasma treatment of glass fibre reinforced polyester at atmospheric pressure enhanced by ultrasonic irradiation

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Norrman, Kion; Singh, Shailendra Vikram

    2011-01-01

    Glass fibre reinforced polyester (GFRP) plates are treated using a 50-Hz dielectric barrier discharge at peak-to-peak voltage of 30 kV in helium at atmospheric pressure with and without ultrasonic irradiation to study adhesion improvement. The ultrasonic waves at the fundamental frequency of around...

  6. Hydrogen termination of CVD diamond films by high-temperature annealing at atmospheric pressure

    NARCIS (Netherlands)

    Seshan, V.; Ullien, D.; Castellanos-Gomez, A.; Sachdeva, S.; Murthy, D.H.K.; Savenije, T.J.; Ahmad, H.A.; Nunney, T.S.; Janssens, S.D.; Haenen, K.; Nesládek, M.; Van der Zant, H.S.J.; Sudhölter, E.J.R.; De Smet, L.C.P.M.

    2013-01-01

    A high-temperature procedure to hydrogenate diamond films using molecular hydrogen at atmospheric pressure was explored. Undoped and doped chemical vapour deposited (CVD) polycrystalline diamond films were treated according to our annealing method using a H2 gas flow down to ?50 ml/min (STP) at

  7. Simulation of N-atom production in dielectric-barrier discharge in nitrogen at atmospheric pressure

    International Nuclear Information System (INIS)

    Tsyganov, Dmitry; Pancheshnyi, Sergey

    2012-01-01

    A plasma-chemical model of atomic nitrogen production in a Townsend dielectric-barrier discharge in nitrogen at atmospheric pressure is presented. On the basis of the comparison with measured densities, a significant discrepancy between the calculated and the measured production rate of nitrogen atoms is observed and discussed. (paper)

  8. Atmospheric-pressure-plasma-enhanced fabrication of nonfouling nanocoatings for 316 stainless steel biomaterial interfaces

    Science.gov (United States)

    Huang, Chun; Lin, Jin-He; Li, Chi-Heng; Yu, I.-Chun; Chen, Ting-Lun

    2018-03-01

    Atmospheric-pressure plasma, which was generated with electrical RF power, was fed to a tetramethyldisiloxane/argon gas mixture to prepare bioinert organosilicon coatings for 316 stainless steel. The surface characteristics of atmospheric-pressure-plasma-deposited nanocoatings were evaluated as a function of RF plasma power, precursor gas flow, and plasma working distance. After surface deposition, the chemical features, elemental compositions, and surface morphologies of the organosilicon nanocoatings were examined. It was found that RF plasma power and plasma working distance are the essential factors that affect the formation of plasma-deposited nanocoatings. Fourier transform infrared spectroscopy spectra indicate that the atmospheric-pressure-plasma-deposited nanocoatings formed showed inorganic features. Atomic force microscopy analysis showed the surface roughness variation of the plasma-deposited nanocoating at different RF plasma powers and plasma working distances during surface treatment. From these surface analyses, it was found that the plasma-deposited organosilicon nanocoatings under specific operational conditions have relatively hydrophobic and inorganic characteristics, which are essential for producing an anti-biofouling interface on 316 stainless steel. The experimental results also show that atmospheric-pressure-plasma-deposited nanocoatings have potential use as a cell-resistant layer on 316 stainless steel.

  9. Atmospheric pressure photoionization for enhanced compatibility in on-line micellar electrokinetic chromatography-mass spectrometry

    NARCIS (Netherlands)

    Mol, Roelof; De Jong, Gerhardus J.; Somsen, Govert W.

    2005-01-01

    Atmospheric pressure photoionization (APPI) is presented as a novel means for the combination of micellar electrokinetic chromatography (MEKC) and mass spectrometry (MS). The on-line coupling is achieved using an adapted sheath flow interface installed on an orthogonal APPI source. Acetone or

  10. Translational, rotational and vibrational temperatures of a gliding arc discharge at atmospheric pressure air

    DEFF Research Database (Denmark)

    Zhu, Jiajian; Gao, Jinlong; Ehn, Andreas

    2014-01-01

    and vibrational temperatures of a gliding arc generated at atmospheric pressure air are investigated. Translational temperatures (about 1100 K) were measured by laser-induced Rayleigh scattering, and two-dimensional temperature imaging was performed. Rotational and vibrational temperatures (about 3600 K and 6700...

  11. Laser scattering on an atmospheric pressure plasma jet : disentangling Rayleigh, Raman and Thomson scattering

    NARCIS (Netherlands)

    Gessel, van A.F.H.; Carbone, E.A.D.; Bruggeman, P.J.; Mullen, van der J.J.A.M.

    2012-01-01

    Laser scattering provides a very direct method for measuring the local densities and temperatures inside a plasma. We present new experimental results of laser scattering on an argon atmospheric pressure microwave plasma jet operating in an air environment. The plasma is very small so a high spatial

  12. An initial study on atmospheric pressure ion transport by laser ionization and electrostatic fields.

    OpenAIRE

    Peralta Conde, Álvaro; Romero, Carolina; Boyero, Juan; Apiñaniz Aginako, Jon Imanol; Raposo Funcia, Cesar; Roso Franco, Luis; Padilla Moreno, Carlos Manuel

    2014-01-01

    Laser ionization of mixtures of gases at atmospheric pressure and the subsequent transport through electrostatic field is studied. A prototype is designed to perform the transport and detection of the ions. Relevance of the composition of the mixture of gases and ionization parameters is shown

  13. Characterization of typical chemical background interferences in atmospheric pressure ionization liquid chromatography-mass spectrometry

    NARCIS (Netherlands)

    Guo, Xinghua; Bruins, Andries P.; Covey, Thomas R.

    2006-01-01

    The structures and origins of typical chemical background noise ions in positive atmospheric pressure ionization liquid chromatography/mass spectrometry (API LC/MS) are investigated and summarized in this study. This was done by classifying chemical background ions using precursor and product ion

  14. Characteristics of atmospheric pressure air discharges with a liquid cathode and a metal anode

    Czech Academy of Sciences Publication Activity Database

    Bruggeman, P.; Ribežl, E.; Degroote, J.; Malesevic, A.; Rego, R.; Vierendeels, J.; Leys, C.; Mašláni, Alan

    2008-01-01

    Roč. 17, č. 2 (2008), s. 1-11 ISSN 0963-0252 Institutional research plan: CEZ:AV0Z20430508 Keywords : atmospheric pressure air discharge * liquid cathode * voltage drop * optical emission spectroscopy Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.685, year: 2008

  15. Effects of long-term low atmospheric pressure on gas exchange and growth of lettuce

    Science.gov (United States)

    Tang, Yongkang; Guo, Shuangsheng; Dong, Wenping; Qin, Lifeng; Ai, Weidang; Lin, Shan

    2010-09-01

    The objectives of this research were to determine photosynthesis, evapotranspiration and growth of lettuce at long-term low atmospheric pressure. Lettuce ( Lactuca sativa L . cv. Youmaicai) plants were grown at 40 kPa total pressure (8.4 kPa p) or 101 kPa total pressure (20.9 kPa p) from seed to harvest for 35 days. Germination rate of lettuce seeds decreased by 7.6% at low pressure, although this was not significant. There was no significant difference in crop photosynthetic rate between hypobaria and ambient pressure during the 35-day study. The crop evapotranspiration rate was significantly lower at low pressure than that at ambient pressure from 20 to 30 days after planting (DAP), but it had no significant difference before 20 DAP or after 30 DAP. The growth cycle of lettuce plants at low pressure was delayed. At low pressure, lettuce leaves were curly at the seedling stage and this disappeared gradually as the plants grew. Ambient lettuce plants were yellow and had an epinastic growth at harvest. The shoot height, leaf number, leaf length and shoot/root ratio were lower at low pressure than those at ambient pressure, while leaf area and root growth increased. Total biomass of lettuce plants grown at two pressures had no significant difference. Ethylene production at low pressure decreased significantly by 38.8% compared with ambient pressure. There was no significant difference in microelements, nutritional phytochemicals and nitrate concentrations at the two treatments. This research shows that lettuce can be grown at long-term low pressure (40 kPa) without significant adverse effects on seed germination, gas exchange and plant growth. Furthermore, ethylene release was reduced in hypobaria.

  16. Self-sustained carbon monoxide oxidation oscillations on size-selected platinum nanoparticles at atmospheric pressure

    DEFF Research Database (Denmark)

    Jensen, Robert; Andersen, Thomas; Nierhoff, Anders Ulrik Fregerslev

    2013-01-01

    High-quality mass spectrometry data of the oscillatory behavior of CO oxidation on SiO2 supported Pt-nanoparticles at atmospheric pressure have been acquired as a function of pressure, coverage, gas composition and nanoparticle size. The oscillations are self-sustained for several days at constant......, temperature, pressure and CO/O2 ratio. The frequency of the oscillations is very well defined and increases over time. The oscillation frequency is furthermore strongly temperature dependent with increasing temperature resulting in increasing frequency. A plausible mechanism for the oscillations is proposed...

  17. Relation between plasma plume density and gas flow velocity in atmospheric pressure plasma

    International Nuclear Information System (INIS)

    Yambe, Kiyoyuki; Taka, Shogo; Ogura, Kazuo

    2014-01-01

    We have studied atmospheric pressure plasma generated using a quartz tube, helium gas, and copper foil electrode by applying RF high voltage. The atmospheric pressure plasma in the form of a bullet is released as a plume into the atmosphere. To study the properties of the plasma plume, the plasma plume current is estimated from the difference in currents on the circuit, and the drift velocity is measured using a photodetector. The relation of the plasma plume density n plu , which is estimated from the current and the drift velocity, and the gas flow velocity v gas is examined. It is found that the dependence of the density on the gas flow velocity has relations of n plu ∝ log(v gas ). However, the plasma plume density in the laminar flow is higher than that in the turbulent flow. Consequently, in the laminar flow, the density increases with increasing the gas flow velocity

  18. Rapid Chemical Vapor Infiltration of Silicon Carbide Minicomposites at Atmospheric Pressure.

    Science.gov (United States)

    Petroski, Kenneth; Poges, Shannon; Monteleone, Chris; Grady, Joseph; Bhatt, Ram; Suib, Steven L

    2018-02-07

    The chemical vapor infiltration technique is one of the most popular for the fabrication of the matrix portion of a ceramic matrix composite. This work focuses on tailoring an atmospheric pressure deposition of silicon carbide onto carbon fiber tows using the methyltrichlorosilane (CH 3 SiCl 3 ) and H 2 deposition system at atmospheric pressure to create minicomposites faster than low pressure systems. Adjustment of the flow rate of H 2 bubbled through CH 3 SiCl 3 will improve the uniformity of the deposition as well as infiltrate the substrate more completely as the flow rate is decreased. Low pressure depositions conducted at 50 Torr deposit SiC at a rate of approximately 200 nm*h -1 , while the atmospheric pressure system presented has a deposition rate ranging from 750 nm*h -1 to 3.88 μm*h -1 . The minicomposites fabricated in this study had approximate total porosities of 3 and 6% for 10 and 25 SCCM infiltrations, respectively.

  19. Eustachian tube function and middle ear barotrauma associated with extremes in atmospheric pressure.

    Science.gov (United States)

    Miyazawa, T; Ueda, H; Yanagita, N

    1996-11-01

    Eustachian tube (ET) function was studied by means of sonotubometry and tubotympano-aerodynamography (TTAG) prior to and following exposure to hypobaric or hyperbaric conditions. Forty normal adults were subjected to hypobaric pressure. Fifty adults who underwent hyperbaric oxygen (HBO) therapy also were studied. Following hypobaric exposure, 14 of 80 ears (17.5%) exhibited middle ear barotrauma. Following hyperbaric exposure, 34 of 100 ears (34%) exhibited middle ear barotrauma. Dysfunction of the ET, characterized by altered active and passive opening capacity, was more prevalent following exposure to extremes in atmospheric pressure compared to baseline. The ET function, which was impaired after the first HBO treatment, improved gradually over the next 2 hours. Overall, however, ET function was worse after the seventh treatment. The patients who developed barotrauma exhibited worse ET function prior to hypobaric or hyperbaric exposure. Thus, abnormal ET function can be used to predict middle ear barotrauma prior to exposure to hypobaric or hyperbaric atmospheric pressure.

  20. Two dimensional radial gas flows in atmospheric pressure plasma-enhanced chemical vapor deposition

    Science.gov (United States)

    Kim, Gwihyun; Park, Seran; Shin, Hyunsu; Song, Seungho; Oh, Hoon-Jung; Ko, Dae Hong; Choi, Jung-Il; Baik, Seung Jae

    2017-12-01

    Atmospheric pressure (AP) operation of plasma-enhanced chemical vapor deposition (PECVD) is one of promising concepts for high quality and low cost processing. Atmospheric plasma discharge requires narrow gap configuration, which causes an inherent feature of AP PECVD. Two dimensional radial gas flows in AP PECVD induces radial variation of mass-transport and that of substrate temperature. The opposite trend of these variations would be the key consideration in the development of uniform deposition process. Another inherent feature of AP PECVD is confined plasma discharge, from which volume power density concept is derived as a key parameter for the control of deposition rate. We investigated deposition rate as a function of volume power density, gas flux, source gas partial pressure, hydrogen partial pressure, plasma source frequency, and substrate temperature; and derived a design guideline of deposition tool and process development in terms of deposition rate and uniformity.

  1. Featured Image: Identifying a Glowing Shell

    Science.gov (United States)

    Kohler, Susanna

    2018-05-01

    New nebulae are being discovered and classified every day and this false-color image reveals one of the more recent objects of interest. This nebula, IPHASX J210204.7+471015, was recently imaged by the Andalucia Faint Object Spectrograph and Camera mounted on the 2.5-m Nordic Optical Telescope in La Palma, Spain. J210204 was initially identified as a possible planetary nebula a remnant left behind at the end of a red giants lifetime. Based on the above imaging, however, a team of authors led by Martn Guerrero (Institute of Astrophysics of Andalusia, Spain) is arguing that this shell of glowing gas was instead expelled around a classical nova. In a classical nova eruption, a white dwarf and its binary companion come very close together, and mass transfers to form a thin atmosphere of hydrogen around the white dwarf. When this hydrogen suddenly ignites in runaway fusion, this outer atmosphere can be expelled, forming a short-lived nova remnant which is what Guerrero and collaborators think were seeing with J210204. If so, this nebula can reveal information about the novathat caused it. To find out more about what the authors learned from this nebula, check out the paper below.CitationMartn A. Guerrero et al 2018 ApJ 857 80. doi:10.3847/1538-4357/aab669

  2. Weather forecasting by insects: modified sexual behaviour in response to atmospheric pressure changes.

    Science.gov (United States)

    Pellegrino, Ana Cristina; Peñaflor, Maria Fernanda Gomes Villalba; Nardi, Cristiane; Bezner-Kerr, Wayne; Guglielmo, Christopher G; Bento, José Maurício Simões; McNeil, Jeremy N

    2013-01-01

    Prevailing abiotic conditions may positively or negatively impact insects at both the individual and population levels. For example while moderate rainfall and wind velocity may provide conditions that favour development, as well as movement within and between habitats, high winds and heavy rains can significantly decrease life expectancy. There is some evidence that insects adjust their behaviours associated with flight, mating and foraging in response to changes in barometric pressure. We studied changes in different mating behaviours of three taxonomically unrelated insects, the curcurbit beetle, Diabrotica speciosa (Coleoptera), the true armyworm moth, Pseudaletia unipuncta (Lepidoptera) and the potato aphid, Macrosiphum euphorbiae (Hemiptera), when subjected to natural or experimentally manipulated changes in atmospheric pressure. In response to decreasing barometric pressure, male beetles exhibited decreased locomotory activity in a Y-tube olfactometer with female pheromone extracts. However, when placed in close proximity to females, they exhibited reduced courtship sequences and the precopulatory period. Under the same situations, females of the true armyworm and the potato aphid exhibited significantly reduced calling behaviour. Neither the movement of male beetles nor the calling of armyworm females differed between stable and increasing atmospheric pressure conditions. However, in the case of the armyworm there was a significant decrease in the incidence of mating under rising atmospheric conditions, suggesting an effect on male behaviour. When atmospheric pressure rose, very few M. euphorbiae oviparae called. This was similar to the situation observed under decreasing conditions, and consequently very little mating was observed in this species except under stable conditions. All species exhibited behavioural modifications, but there were interspecific differences related to size-related flight ability and the diel periodicity of mating activity. We

  3. [Automatic adjustment control system for DC glow discharge plasma source].

    Science.gov (United States)

    Wan, Zhen-zhen; Wang, Yong-qing; Li, Xiao-jia; Wang, Hai-zhou; Shi, Ning

    2011-03-01

    There are three important parameters in the DC glow discharge process, the discharge current, discharge voltage and argon pressure in discharge source. These parameters influence each other during glow discharge process. This paper presents an automatic control system for DC glow discharge plasma source. This system collects and controls discharge voltage automatically by adjusting discharge source pressure while the discharge current is constant in the glow discharge process. The design concept, circuit principle and control program of this automatic control system are described. The accuracy is improved by this automatic control system with the method of reducing the complex operations and manual control errors. This system enhances the control accuracy of glow discharge voltage, and reduces the time to reach discharge voltage stability. The glow discharge voltage stability test results with automatic control system are provided as well, the accuracy with automatic control system is better than 1% FS which is improved from 4% FS by manual control. Time to reach discharge voltage stability has been shortened to within 30 s by automatic control from more than 90 s by manual control. Standard samples like middle-low alloy steel and tin bronze have been tested by this automatic control system. The concentration analysis precision has been significantly improved. The RSDs of all the test result are better than 3.5%. In middle-low alloy steel standard sample, the RSD range of concentration test result of Ti, Co and Mn elements is reduced from 3.0%-4.3% by manual control to 1.7%-2.4% by automatic control, and that for S and Mo is also reduced from 5.2%-5.9% to 3.3%-3.5%. In tin bronze standard sample, the RSD range of Sn, Zn and Al elements is reduced from 2.6%-4.4% to 1.0%-2.4%, and that for Si, Ni and Fe is reduced from 6.6%-13.9% to 2.6%-3.5%. The test data is also shown in this paper.

  4. Numerical analysis of thermoluminescence glow curves

    International Nuclear Information System (INIS)

    Gomez Ros, J. M.; Delgado, A.

    1989-01-01

    This report presents a method for the numerical analysis of complex thermoluminescence glow curves resolving the individual glow peak components. The method employs first order kinetics analytical expressions and is based In a Marquart-Levenberg minimization procedure. A simplified version of this method for thermoluminescence dosimetry (TLD) is also described and specifically developed to operate whit Lithium Fluoride TLD-100. (Author). 36 refs

  5. Atmospheric Pressure Variation is a Delayed Trigger for Aneurysmal Subarachnoid Hemorrhage.

    Science.gov (United States)

    van Donkelaar, Carlina E; Potgieser, Adriaan R E; Groen, Henk; Foumani, Mahrouz; Abdulrahman, Herrer; Sluijter, Rob; van Dijk, J Marc C; Groen, Rob J M

    2018-04-01

    There is an ongoing search for conditions that induce spontaneous subarachnoid hemorrhage (SAH). The seasonal pattern of SAH is shown in a large meta-analysis of the literature, but its explanation remains undecided. There is a clear need for sound meteorologic data to further elucidate the seasonal influence on SAH. Because of the stable and densely monitored atmospheric situation in the north of the Netherlands, we reviewed our unique cohort on the seasonal incidence of SAH and the association between SAH and local atmospheric changes. Our observational cohort study included 1535 patients with spontaneous SAH admitted to our neurovascular center in the north of the Netherlands between 2000 and 2015. Meteorologic data could be linked to the day of the ictus. To compare SAH incidences over the year and to test the association with meteorologic conditions, incidence rate ratios (IRRs) with corresponding 95% confidence intervals (CIs) were used, calculated by Poisson regression analyses. Atmospheric pressure variations were significantly associated with aneurysmal SAH. In particular, the pressure change on the second and third day before the ictus was independently correlated to a higher incidence of aneurysmal SAH (IRR, 1.11; 95% CI, 1.00-1.23). The IRR for aneurysmal SAH in July was calculated 0.67 (95% CI, 0.49-0.92) after adjustment for temperature and atmospheric pressure changes. Atmospheric pressure variations are a delayed trigger for aneurysmal SAH. Also, a significantly decreased incidence of aneurysmal SAH was noted in July. Copyright © 2018 Elsevier Inc. All rights reserved.

  6. Simulation Tool for Dielectric Barrier Discharge Plasma Actuators at Atmospheric and Sub-Atmospheric Pressures: SBIR Phase I Final Report

    Science.gov (United States)

    Likhanskii, Alexandre

    2012-01-01

    This report is the final report of a SBIR Phase I project. It is identical to the final report submitted, after some proprietary information of administrative nature has been removed. The development of a numerical simulation tool for dielectric barrier discharge (DBD) plasma actuator is reported. The objectives of the project were to analyze and predict DBD operation at wide range of ambient gas pressures. It overcomes the limitations of traditional DBD codes which are limited to low-speed applications and have weak prediction capabilities. The software tool allows DBD actuator analysis and prediction for subsonic to hypersonic flow regime. The simulation tool is based on the VORPAL code developed by Tech-X Corporation. VORPAL's capability of modeling DBD plasma actuator at low pressures (0.1 to 10 torr) using kinetic plasma modeling approach, and at moderate to atmospheric pressures (1 to 10 atm) using hydrodynamic plasma modeling approach, were demonstrated. In addition, results of experiments with pulsed+bias DBD configuration that were performed for validation purposes are reported.

  7. Photosynthesis and growth response of almond to increased atmospheric ozone partial pressures

    Energy Technology Data Exchange (ETDEWEB)

    Retzlaff, W.A.; Williams, L.E. (Univ. of California, Davis (United States) Kearney Agricultural Center, Parlier, CA (United States)); DeJong, T.M. (Univ. of California, Davis (United States))

    Uniform nursery stock of five almond cultivars [Prunus dulcis (Mill) D.A. Webb syn. P. amygdalus Batsch, cv. Butte, Carmel, Mission, Nonpareil, and Sonora] propagated on peach (P. domstica L. Batsch.) rootstock were exposed to three different atmospheric ozone (O[sub 3]) partial pressures. The trees were planted in open-top fumigation chambers on 19 Apr. 1989 at the University of California Kearny Agricultural Center located in the San Joaquin Valley of California. Exposures of the trees to three atmospheric O[sub 3] partial pressures lasted from 1 June to 2 Nov. 1989. The mean 12-h [0800-2000 h Pacific Daylight Time (PDT)] O[sub 3] partial pressures measured in the open-top chambers during the experimental period were 0.038, 0.060, and 0.112 [mu]Pa Pa[sup [minus]1] O[sub 3] in the charcoal filtered, ambient, and ambient + O[sub 3] treatments, respectively. Leaf net CO[sub 2] assimilation, trunk cross-sectional area growth, and root, trunk, foliage, and total dry weight of Nonpareil were reduced by increased atmospheric O[sub 3] partial pressures. Mission was unaffected by O[sub 3] and Butte, Carmel, and Sonora were intermediate in their responses. Foliage of Nonpareil also abscised prematurely in the ambient and ambient + O[sub 3] treatments. The results indicate that there are almond cultivars that are sensitive to O[sub 3] exposure.

  8. Photosynthesis and growth response of almond to increased atmospheric ozone partial pressures

    International Nuclear Information System (INIS)

    Retzlaff, W.A.; Williams, L.E.; DeJong, T.M.

    1992-01-01

    Uniform nursery stock of five almond cultivars [Prunus dulcis (Mill) D.A. Webb syn. P. amygdalus Batsch, cv. Butte, Carmel, Mission, Nonpareil, and Sonora] propagated on peach (P. domstica L. Batsch.) rootstock were exposed to three different atmospheric ozone (O 3 ) partial pressures. The trees were planted in open-top fumigation chambers on 19 Apr. 1989 at the University of California Kearny Agricultural Center located in the San Joaquin Valley of California. Exposures of the trees to three atmospheric O 3 partial pressures lasted from 1 June to 2 Nov. 1989. The mean 12-h [0800-2000 h Pacific Daylight Time (PDT)] O 3 partial pressures measured in the open-top chambers during the experimental period were 0.038, 0.060, and 0.112 μPa Pa -1 O 3 in the charcoal filtered, ambient, and ambient + O 3 treatments, respectively. Leaf net CO 2 assimilation, trunk cross-sectional area growth, and root, trunk, foliage, and total dry weight of Nonpareil were reduced by increased atmospheric O 3 partial pressures. Mission was unaffected by O 3 and Butte, Carmel, and Sonora were intermediate in their responses. Foliage of Nonpareil also abscised prematurely in the ambient and ambient + O 3 treatments. The results indicate that there are almond cultivars that are sensitive to O 3 exposure

  9. Decontamination of objects in a sealed container by means of atmospheric pressure plasmas

    DEFF Research Database (Denmark)

    Leipold, Frank; Schultz-Jensen, Nadja; Kusano, Yukihiro

    2011-01-01

    . The ambient atmosphere was air at atmospheric pressure. A plasma is generated inside the bag forming ozone from the oxygen. The maximum ozone concentration in the bag was found to be 140 ppm. A log 6 reduction of L. innocua is obtained after 15 min of exposure time. The temperature of the slides after...... for the experiments. Glass slides were inoculated with L. innocua. The slides were placed inside a low density polyethylene (LDPE) bag. The bag was filled with a gas mixture of 97.5 Vol% Ar and 2.5 Vol% O2 and subsequently sealed. The bag was placed between the electrodes of a dielectric barrier discharge...

  10. Atmospheric pressure plasma jet's characterization and surface wettability driven by neon transformer

    Science.gov (United States)

    Elfa, R. R.; Nafarizal, N.; Ahmad, M. K.; Sahdan, M. Z.; Soon, C. F.

    2017-03-01

    Atmospheric pressure plasma driven by Neon transformer power supply argon is presented in this paper. Atmospheric pressure plasma system has attracted researcher interest over low pressure plasma as it provides a flexibility process, cost-efficient, portable device and vacuum-free device. Besides, another golden key of this system is the wide promising application in the field of work cover from industrial and engineering to medical. However, there are still numbers of fundamental investigation that are necessary such as device configuration, gas configuration and its effect. Dielectric barrier discharge which is also known as atmospheric pressure plasma discharge is created when there is gas ionization process occur which enhance the movement of atom and electron and provide energetic particles. These energetic particles can provide modification and cleaning property to the sample surface due to the bombardment of the high reactive ion and radicals to the sample surface. In order to develop atmospheric pressure plasma discharge, a high voltage and high frequency power supply is needed. In this work, we used a neon transformer power supply as the power supply. The flow of the Ar is feed into 10 mm cylinder quartz tube with different treatment time in order to investigate the effect of the plasma discharge. The analysis of each treatment time is presented by optical emission spectroscopy (OES) and water contact angle (WCA) measurement. The increase of gas treatment time shows increases intensity of reactive Ar and reduces the angle of water droplets in water contact angle. Treatment time of 20 s microslide glass surface shows that the plasma needle discharges have modified the sample surface from hydrophilic surface to superhydrophilic surface. Thus, this leads to another interesting application in reducing sample surface adhesion to optimize productivity in the industry of paintings, semiconductor and more.

  11. Studies on Microscopic Structure of Diesel Sprays under Atmospheric and High Gas Pressures

    Directory of Open Access Journals (Sweden)

    D. Deshmukh

    2014-06-01

    Full Text Available In the present work, the spray structure of diesel from a 200-μm, single-hole solenoid injector is studied using microscopic imaging at injection pressures of 700, 1000 and 1400 bar for various gas pressures. A long-distance microscope with a high resolution camera is used for spray visualization with a direct imaging technique. This study shows that even at very high injection pressures, the spray structure in an ambient environment of atmospheric pressure reveals presence of entangled ligaments and non-spherical droplets during the injection period. With increase in the injection pressure, the ligaments tend to get smaller and spread radially. The spray structure studies are also conducted at high gas pressures in a specially designed high pressure chamber with optical access. The near nozzle spray structure at the end of the injection shows that the liquid jet breakup is improved with increase in gas density. The droplet size measurement is possible only late in the injection duration when the breakup appears to be complete and mostly spherical droplets are observed. Hence, droplet size measurements are performed after 1.3 ms from start of the injection pulse. Spatial and temporal variation in Sauter Mean Diameter (SMD is observed and reported for the case corresponding to an injection pressure of 700 bar. Overall, this study has highlighted the importance of verifying the extentof atomization and droplet shape even in dense sprays before using conventional dropsizing methods such as PDPA.

  12. Atmospheric Pressure and Abdominal Aortic Aneurysm Rupture: Results From a Time Series Analysis and Case-Crossover Study.

    Science.gov (United States)

    Penning de Vries, Bas B L; Kolkert, Joé L P; Meerwaldt, Robbert; Groenwold, Rolf H H

    2017-10-01

    Associations between atmospheric pressure and abdominal aortic aneurysm (AAA) rupture risk have been reported, but empirical evidence is inconclusive and largely derived from studies that did not account for possible nonlinearity, seasonality, and confounding by temperature. Associations between atmospheric pressure and AAA rupture risk were investigated using local meteorological data and a case series of 358 patients admitted to hospital for ruptured AAA during the study period, January 2002 to December 2012. Two analyses were performed-a time series analysis and a case-crossover study. Results from the 2 analyses were similar; neither the time series analysis nor the case-crossover study showed a significant association between atmospheric pressure ( P = .627 and P = .625, respectively, for mean daily atmospheric pressure) or atmospheric pressure variation ( P = .464 and P = .816, respectively, for 24-hour change in mean daily atmospheric pressure) and AAA rupture risk. This study failed to support claims that atmospheric pressure causally affects AAA rupture risk. In interpreting our results, one should be aware that the range of atmospheric pressure observed in this study is not representative of the atmospheric pressure to which patients with AAA may be exposed, for example, during air travel or travel to high altitudes in the mountains. Making firm claims regarding these conditions in relation to AAA rupture risk is difficult at best. Furthermore, despite the fact that we used one of the largest case series to date to investigate the effect of atmospheric pressure on AAA rupture risk, it is possible that this study is simply too small to demonstrate a causal link.

  13. Correlation between atmospheric pressure changes and abdominal aortic aneurysm rupture: results of a single-center study.

    Science.gov (United States)

    Molacek, Jiri; Treska, Vladislav; Kasik, Miroslav; Houdek, Karel; Baxa, Jan

    2013-09-01

    There is much interest in all factors that influence the etiopathogenesis of abdominal aortic aneurysm (AAA) rupture. Apart from the well-established factors such as arterial hypertension, smoking, age, and genetic predisposition, less common factors that may play a role in the mechanism of the rupture are the subject of much discussion. These include atmospheric conditions, temperature, and atmospheric pressure. We conducted this study to investigate the effects of the absolute value of atmospheric pressure and its changes on the frequency of AAA rupture. We retrospectively examined 54 patients who underwent treatment for a ruptured AAA at the Clinic of Surgery in the University Hospital in Pilsen between 1 January 2005 and 31 December 2009. We collected data on the atmospheric pressure in this period from the Czech Hydrometeorological Institute in Pilsen. We did not find a significant difference in atmospheric pressure values between the days when the rupture occurred versus the other days (p atmospheric pressure during the 48 h preceding the rupture (Student's test p atmospheric pressure in that month. These findings suggest that atmospheric pressure and its changes do not affect the pathogenesis of AAA rupture.

  14. Infrared Absorption Spectroscopic Study on Reaction between Self-Assembled Monolayers and Atmospheric-Pressure Plasma

    Directory of Open Access Journals (Sweden)

    Masanori Shinohara

    2015-01-01

    Full Text Available Plasma is becoming increasingly adopted in bioapplications such as plasma medicine and agriculture. This study investigates the interaction between plasma and molecules in living tissues, focusing on plasma-protein interactions. To this end, the reaction of air-pressure air plasma with NH2-terminated self-assembled monolayer is investigated by infrared spectroscopy in multiple internal reflection geometry. The atmospheric-pressure plasma decomposed the NH2 components, the characteristic units of proteins. The decomposition is attributed to water clusters generated in the plasma, indicating that protein decomposition by plasma requires humid air.

  15. Quasi-periodic fluctuations of atmospheric pressure and cosmic rays observed in the stratosphere

    International Nuclear Information System (INIS)

    Kodama, Masahiro; Abe, Toshiaki; Sakai, Takasuke; Kato, Masato; Kogami, Shinichi.

    1976-01-01

    Quasi-periodicities of barometric pressure and cosmic ray intensity, with 5.5-minute period and one hour persistency, have been observed by means of a high-precision barometer and a large plastic scintillation counter in a balloon at an altitude of --18 km over the Pacific Ocean. From characteristics of such short period fluctuations, it is suggested that the observed pressure fluctuation may possibly be caused by the internal atmospheric gravity wave whose amplitude and wave length are --30 m and --30 km respectively. (auth.)

  16. Development of data logger for atmospheric pressure, temperature and relative humidity for gas-filled detector

    International Nuclear Information System (INIS)

    Sahu, S.; Sahu, P.K.; Bhuyan, M.R.; Biswas, S.; Mohanty, B.

    2014-01-01

    At IoP-NISER an initiative has been taken to build and test micro-pattern gas detector such as Gas Electron Multiplier (GEM) for several upcoming High-Energy Physics (HEP) experiment projects. Temperature (t), atmospheric pressure (p) and relative humidity (RH) monitor and recording is very important for gas filled detector development. A data logger to monitor and record the ambient parameters such as temperature, relative humidity and pressure has been developed. With this data logger continuous recording of t, p, RH and time stamp can be done with a programmable sampling interval. This data is necessary to correct the gain of a gas filled detector

  17. The effect of meteorological data on atmospheric pressure loading corrections in VLBI data analysis

    Science.gov (United States)

    Balidakis, Kyriakos; Glaser, Susanne; Karbon, Maria; Soja, Benedikt; Nilsson, Tobias; Lu, Cuixian; Anderson, James; Liu, Li; Andres Mora-Diaz, Julian; Raposo-Pulido, Virginia; Xu, Minghui; Heinkelmann, Robert; Schuh, Harald

    2015-04-01

    Earth's crustal deformation is a manifestation of numerous geophysical processes, which entail the atmosphere and ocean general circulation and tidal attraction, climate change, and the hydrological circle. The present study deals with the elastic deformations induced by atmospheric pressure variations. At geodetic sites, APL (Atmospheric Pressure Loading) results in displacements covering a wide range of temporal scales which is undesirable when rigorous geodetic/geophysical analysis is intended. Hence, it is of paramount importance that the APL signal are removed at the observation level in the space geodetic data analysis. In this study, elastic non-tidal components of loading displacements were calculated in the local topocentric frame for all VLBI (Very Long Baseline Interferometry) stations with respect to the center-of-figure of the solid Earth surface and the center-of-mass of the total Earth system. The response of the Earth to the load variation at the surface was computed by convolving Farrell Green's function with the homogenized in situ surface pressure observations (in the time span 1979-2014) after the subtraction of the reference pressure and the S1, S2 and S3 thermal tidal signals. The reference pressure was calculated through a hypsometric adjustment of the absolute pressure level determined from World Meteorological Organization stations in the vicinity of each VLBI observatory. The tidal contribution was calculated following the 2010 International Earth Rotation and Reference Systems Service conventions. Afterwards, this approach was implemented into the VLBI software VieVS@GFZ and the entirety of available VLBI sessions was analyzed. We rationalize our new approach on the basis that the potential error budget is substantially reduced, since several common errors are not applicable in our approach, e.g. those due to the finite resolution of NWM (Numerical Weather Models), the accuracy of the orography model necessary for adjusting the former as

  18. Experimental study of spatial distribution of Ar glow discharge plasma

    International Nuclear Information System (INIS)

    Guo, X.M.; Zhou, T.D.; Pai, S.T.

    1996-01-01

    The characteristics of the spatial distribution of Ar glow discharge plasma were experimentally investigated. By means of direct comparisons between theory and experiment, the effects of the variation of gap separation, gas pressure, and electrode radius on the spatial distributions of electron density and electric field were studied. Results indicate that the maximum electron density moves toward the cathode as the gap separation or gas pressure increases while variation of electrode radius produces little effect. Predictions from a theoretical model have been experimentally verified. General agreements between theory and experiment were found to be reasonably good except in the cathode region, where discrepancy exists. copyright 1996 American Institute of Physics

  19. Atmospheric pressure surface sampling/ionization techniques for direct coupling of planar separations with mass spectrometry.

    Science.gov (United States)

    Pasilis, Sofie P; Van Berkel, Gary J

    2010-06-18

    Planar separations, which include thin layer chromatography and gel electrophoresis, are in widespread use as important and powerful tools for conducting separations of complex mixtures. To increase the utility of planar separations, new methods are needed that allow in situ characterization of the individual components of the separated mixtures. A large number of atmospheric pressure surface sampling and ionization techniques for use with mass spectrometry have emerged in the past several years, and several have been investigated as a means for mass spectrometric read-out of planar separations. In this article, we review the atmospheric pressure surface sampling and ionization techniques that have been used for the read-out of planar separation media. For each technique, we briefly explain the operational basics and discuss the analyte type for which it is appropriate and some specific applications from the literature. Copyright (c) 2010 Elsevier B.V. All rights reserved.

  20. Propagation of atmospheric-pressure ionization waves along the tapered tube

    Science.gov (United States)

    Xia, Yang; Wang, Wenchun; Liu, Dongping; Yan, Wen; Bi, Zhenhua; Ji, Longfei; Niu, Jinhai; Zhao, Yao

    2018-02-01

    Gas discharge in a small radius dielectric tube may result in atmospheric pressure plasma jets with high energy and density of electrons. In this study, the atmospheric pressure ionization waves (IWs) were generated inside a tapered tube. The propagation behaviors of IWs inside the tube were studied by using a spatially and temporally resolved optical detection system. Our measurements show that both the intensity and velocity of the IWs decrease dramatically when they propagate to the tapered region. After the taper, the velocity, intensity, and electron density of the IWs are improved with the tube inner diameter decreasing from 4.0 to 0.5 mm. Our analysis indicates that the local gas conductivity and surface charges may play a role in the propagation of the IWs under such a geometrical constraint, and the difference in the dynamics of the IWs after the taper can be related to the restriction in the size of IWs.

  1. Numerical simulation of torus breakdown to chaos in an atmospheric-pressure dielectric barrier discharge

    International Nuclear Information System (INIS)

    Zhang, J.; Wang, Y. H.; Wang, D. Z.

    2013-01-01

    Understanding the routes to chaos occurring in atmospheric-pressure dielectric barrier discharge systems by changing controlling parameters is very important to predict and control the dynamical behaviors. In this paper, a route of a quasiperiodic torus to chaos via the strange nonchaotic attractor is observed in an atmospheric-pressure dielectric barrier discharge driven by triangle-wave voltage. By increasing the driving frequency, the discharge system first bifurcates to a quasiperiodic torus from a stable single periodic state, and then torus and phase-locking periodic state appear and disappear alternately. In the meantime, the torus becomes increasingly wrinkling and stretching, and gradually approaches a fractal structure with the nonpositive largest Lyapunov exponent, i.e., a strange nonchaotic attractor. After that, the discharge system enters into chaotic state. If the driving frequency is further increased, another well known route of period-doubling bifurcation to chaos is also observed

  2. Numerical simulation of torus breakdown to chaos in an atmospheric-pressure dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, J.; Wang, Y. H.; Wang, D. Z. [Key Laboratory of Materials Modification by Laser, Electron, and Ion Beams, School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2013-08-15

    Understanding the routes to chaos occurring in atmospheric-pressure dielectric barrier discharge systems by changing controlling parameters is very important to predict and control the dynamical behaviors. In this paper, a route of a quasiperiodic torus to chaos via the strange nonchaotic attractor is observed in an atmospheric-pressure dielectric barrier discharge driven by triangle-wave voltage. By increasing the driving frequency, the discharge system first bifurcates to a quasiperiodic torus from a stable single periodic state, and then torus and phase-locking periodic state appear and disappear alternately. In the meantime, the torus becomes increasingly wrinkling and stretching, and gradually approaches a fractal structure with the nonpositive largest Lyapunov exponent, i.e., a strange nonchaotic attractor. After that, the discharge system enters into chaotic state. If the driving frequency is further increased, another well known route of period-doubling bifurcation to chaos is also observed.

  3. Synergistic effects of atmospheric pressure plasma-emitted components on DNA oligomers: a Raman spectroscopic study.

    Science.gov (United States)

    Edengeiser, Eugen; Lackmann, Jan-Wilm; Bründermann, Erik; Schneider, Simon; Benedikt, Jan; Bandow, Julia E; Havenith, Martina

    2015-11-01

    Cold atmospheric-pressure plasmas have become of increasing importance in sterilization processes especially with the growing prevalence of multi-resistant bacteria. Albeit the potential for technological application is obvious, much less is known about the molecular mechanisms underlying bacterial inactivation. X-jet technology separates plasma-generated reactive particles and photons, thus allowing the investigation of their individual and joint effects on DNA. Raman spectroscopy shows that particles and photons cause different modifications in DNA single and double strands. The treatment with the combination of particles and photons does not only result in cumulative, but in synergistic effects. Profilometry confirms that etching is a minor contributor to the observed DNA damage in vitro. Schematics of DNA oligomer treatment with cold atmospheric-pressure plasma. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Mycotoxin Decontamination of Food: Cold Atmospheric Pressure Plasma versus "Classic" Decontamination.

    Science.gov (United States)

    Hojnik, Nataša; Cvelbar, Uroš; Tavčar-Kalcher, Gabrijela; Walsh, James L; Križaj, Igor

    2017-04-28

    Mycotoxins are secondary metabolites produced by several filamentous fungi, which frequently contaminate our food, and can result in human diseases affecting vital systems such as the nervous and immune systems. They can also trigger various forms of cancer. Intensive food production is contributing to incorrect handling, transport and storage of the food, resulting in increased levels of mycotoxin contamination. Mycotoxins are structurally very diverse molecules necessitating versatile food decontamination approaches, which are grouped into physical, chemical and biological techniques. In this review, a new and promising approach involving the use of cold atmospheric pressure plasma is considered, which may overcome multiple weaknesses associated with the classical methods. In addition to its mycotoxin destruction efficiency, cold atmospheric pressure plasma is cost effective, ecologically neutral and has a negligible effect on the quality of food products following treatment in comparison to classical methods.

  5. Gas Diffusion Barriers Prepared by Spatial Atmospheric Pressure Plasma Enhanced ALD.

    Science.gov (United States)

    Hoffmann, Lukas; Theirich, Detlef; Pack, Sven; Kocak, Firat; Schlamm, Daniel; Hasselmann, Tim; Fahl, Henry; Räupke, André; Gargouri, Hassan; Riedl, Thomas

    2017-02-01

    In this work, we report on aluminum oxide (Al 2 O 3 ) gas permeation barriers prepared by spatial ALD (SALD) at atmospheric pressure. We compare the growth characteristics and layer properties using trimethylaluminum (TMA) in combination with an Ar/O 2 remote atmospheric pressure plasma for different substrate velocities and different temperatures. The resulting Al 2 O 3 films show ultralow water vapor transmission rates (WVTR) on the order of 10 -6 gm -2 d -1 . In notable contrast, plasma based layers already show good barrier properties at low deposition temperatures (75 °C), while water based processes require a growth temperature above 100 °C to achieve equally low WVTRs. The activation energy for the water permeation mechanism was determined to be 62 kJ/mol.

  6. State of the art in medical applications using non-thermal atmospheric pressure plasma

    Science.gov (United States)

    Tanaka, Hiromasa; Ishikawa, Kenji; Mizuno, Masaaki; Toyokuni, Shinya; Kajiyama, Hiroaki; Kikkawa, Fumitaka; Metelmann, Hans-Robert; Hori, Masaru

    2017-12-01

    Plasma medical science is a novel interdisciplinary field that combines studies on plasma science and medical science, with the anticipation that understanding the scientific principles governing plasma medical science will lead to innovations in the field. Non-thermal atmospheric pressure plasma has been used for medical treatments, such as for cancer, blood coagulation, and wound healing. The interactions that occur between plasma and cells/tissues have been analyzed extensively. Direct and indirect treatment of cells with plasma has broadened the applications of non-thermal atmospheric pressure plasma in medicine. Examples of indirect treatment include plasma-assisted immune-therapy and plasma-activated medium. Controlling intracellular redox balance may be key in plasma cancer treatment. Animal studies are required to test the effectiveness and safety of these treatments for future clinical applications.

  7. Atmospheric pressure plasma jets: an overview of devices and new directions

    International Nuclear Information System (INIS)

    Winter, J; Brandenburg, R; Weltmann, K-D

    2015-01-01

    Atmospheric pressure plasma jets have a long history of more than 50 years. During this time their design and plasma generation mechanism has been developed and adapted to various fields of applications. This review aims at giving an overview of jet devices by starting with a brief history of their development. This is followed by an overview of commonly used terms and definitions as well as a survey of different classification schemes (e.g. geometry, excition frequency or specific energy input) described in literature. A selective update of new designs and novel research achievments on atmospheric pressure plasma jets published in 2012 or later shows the impressive variety and rapid development of the field. Finally, a brief outlook on the future trends and directions is given. (paper)

  8. Numerical solution of the model problem of CCRF-discharge at atmospheric pressure

    Directory of Open Access Journals (Sweden)

    Zheltukhin Viktor

    2017-01-01

    Full Text Available This work describes a 1D mathematical model of capacitive coupled RF discharge between symmetrical electrodes in argon at atmospheric pressure in a local approximation. Electrons, atomic and molecular ions, metastable atoms and argon dimmers as well as ground-state atoms are considered. A simplified diagram of argon excited states when two metastable and two resonance states are replaced with the uniform level. Such diagram is frequently used to simulate argon plasma due to efficient mixing of these layers at electron impacts. Velocity factors of electron impact processes were calculated using Boltzmann equation with a glance to electron-electron collisions. This work describes numerical algorithm of mathematical model implementation, which is based on finite-dimensional approximation of the problem using difference schemes together with iteration process. The software was developed to implement iterative processes using MatLab. Characteristics of atmospheric pressure capacitive coupled RF discharge at interelectrod distance 20 mm are calculated.

  9. Parameters of a supershort avalanche electron beam generated in atmospheric-pressure air

    International Nuclear Information System (INIS)

    Tarasenko, V. F.

    2011-01-01

    Conditions under which the number of runaway electrons in atmospheric-pressure air reaches ∼5 × 10 10 are determined. Recommendations for creating runaway electron accelerators are given. Methods for measuring the parameters of a supershort avalanche electron beam and X-ray pulses from gas-filled diodes, as well as the discharge current and gap voltage, are described. A technique for determining the instant of runaway electron generation with respect to the voltage pulse is proposed. It is shown that the reduction in the gap voltage and the decrease in the beam current coincide in time. The mechanism of intense electron beam generation in gas-filled diodes is analyzed. It is confirmed experimentally that, in optimal regimes, the number of electrons generated in atmospheric-pressure air with energies T > eU m , where U m is the maximum gap voltage, is relatively small.

  10. Parameters of a supershort avalanche electron beam generated in atmospheric-pressure air

    Science.gov (United States)

    Tarasenko, V. F.

    2011-05-01

    Conditions under which the number of runaway electrons in atmospheric-pressure air reaches ˜5 × 1010 are determined. Recommendations for creating runaway electron accelerators are given. Methods for measuring the parameters of a supershort avalanche electron beam and X-ray pulses from gas-filled diodes, as well as the discharge current and gap voltage, are described. A technique for determining the instant of runaway electron generation with respect to the voltage pulse is proposed. It is shown that the reduction in the gap voltage and the decrease in the beam current coincide in time. The mechanism of intense electron beam generation in gas-filled diodes is analyzed. It is confirmed experimentally that, in optimal regimes, the number of electrons generated in atmospheric-pressure air with energies T > eU m , where U m is the maximum gap voltage, is relatively small.

  11. Atmospheric-pressure air microplasma jets in aqueous media for the inactivation of Pseudomonas fluorescens cells

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xianhui; Yang, Si-ze [Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, School of Physics and Mechanical and Electrical Engineering, Xiamen University, Xiamen, Fujian 361005 (China); Liu, Dongping [Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, School of Physics and Mechanical and Electrical Engineering, Xiamen University, Xiamen, Fujian 361005 (China); School of Physics and Materials Engineering, Dalian Nationalities University, Dalian 116600 (China); Song, Ying [School of Physics and Materials Engineering, Dalian Nationalities University, Dalian 116600 (China); School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116023 (China); Sun, Yue [School of Physics, Changchun University of Science and Technology, Changchun 130022 (China)

    2013-05-15

    The hollow fiber-based cold air microplasma jet array running at atmospheric pressure has been designed to inactivate Pseudomonas fluorescens (P. fluorescens) cells in vitro in aqueous media. The influences of electrode configurations, air flow rate, and applied voltage on the discharge characteristics of the single microplasma jet operating in aqueous media are presented, and the bactericidal efficiency of the hollow fibers-based and large-volume microplasma jet array is reported. Optical emission spectroscopy is utilized to identify excited species during the antibacterial testing of plasma in solutions. These well-aligned and rather stable air microplasma jets containing a variety of short-lived species, such as OH and O radicals and charged particles, are in direct contact with aqueous media and are very effective in killing P. fluorescens cells in aqueous media. This design shows its potential application for atmospheric pressure air plasma inactivation of bacteria cells in aqueous media.

  12. ATMOSPHERIC PRESSURE AND ITS INFLUENCE ON TOURISTS AND TOURISM ACTIVITIES IN THE PRAHOVA CORRIDOR

    Directory of Open Access Journals (Sweden)

    HAVRIŞ LOREDANA-ELENA

    2014-03-01

    Full Text Available In the climate literature it is known that the atmospheric temperature directly and permanently acts on the all organisms and all geographical environment components, influencing the wellness of the weather sensitive persons and implicitly the wellness of tourists in this region. In the same time, its evolution is a good indicator in shaping the short and medium term meteorological forecast, considering that the region chosen for research is a very tripper one, especially during the winter season when the atmospheric pressure variation trend is much more pronounced. Within this framework, the present paper tries to develop a climatic diagnosis on the reference climate parameters (annual and monthly average pressure values, seasonal values, minimum and maximum absolute values and their emergence probability but also the non-periodic variability based on data recorded during 1961-2007 at Câmpina, Sinaia 1500, Predeal, Omu Peak and Braşov weather stations.

  13. The effects of extra-low-frequency atmospheric pressure oscillations on human mental activity

    Science.gov (United States)

    Delyukov, A. A.; Didyk, L.

    Slight atmospheric pressure oscillations (APO) in the extra-low-frequency range below 0.1 Hz, which frequently occur naturally, can influence human mental activity. This phenomenon has been observed in experiments with a group of 12 healthy volunteers exposed to experimentally created APO with amplitudes 30-50 Pa in the frequency band 0.011-0.17 Hz. Exposure of the subjects to APO for 15-30 min caused significant changes in attention and short-term memory functions, performance rate, and mental processing flexibility. The character of the response depended on the APO frequency and coherence. Periodic APO promoted purposeful mental activity, accompanied by an increase in breath-holding duration and a slower heart rate. On the other hand, quasi-chaotic APO, similar to the natural perturbations of atmospheric pressure, disrupted mental activity. These observations suggest that APO could be partly responsible for meteorosensitivity in humans.

  14. Charge dependence of the plasma travel length in atmospheric-pressure plasma

    International Nuclear Information System (INIS)

    Yambe, Kiyoyuki; Konda, Kohmei; Masuda, Seiya

    2016-01-01

    Plasma plume is generated using a quartz tube, helium gas, and foil electrode by applying AC high voltage under the atmosphere. The plasma plume is released into the atmosphere from inside of the quartz tube and is seen as the continuous movement of the plasma bullet. The travel length of plasma bullet is defined from plasma energy and force due to electric field. The drift velocity of plasma bullet has the upper limit under atmospheric-pressure because the drift velocity is determined from the balance between electric field and resistive force due to collisions between plasma and air. The plasma plume charge depends on the drift velocity. Consequently, in the laminar flow of helium gas flow state, the travel length of the plasma plume logarithmically depends on the plasma plume charge which changes with both the electric field and the resistive force.

  15. Charge dependence of the plasma travel length in atmospheric-pressure plasma

    Energy Technology Data Exchange (ETDEWEB)

    Yambe, Kiyoyuki; Konda, Kohmei; Masuda, Seiya [Graduate School of Science and Technology, Niigata University, Niigata 950-2181 (Japan)

    2016-06-15

    Plasma plume is generated using a quartz tube, helium gas, and foil electrode by applying AC high voltage under the atmosphere. The plasma plume is released into the atmosphere from inside of the quartz tube and is seen as the continuous movement of the plasma bullet. The travel length of plasma bullet is defined from plasma energy and force due to electric field. The drift velocity of plasma bullet has the upper limit under atmospheric-pressure because the drift velocity is determined from the balance between electric field and resistive force due to collisions between plasma and air. The plasma plume charge depends on the drift velocity. Consequently, in the laminar flow of helium gas flow state, the travel length of the plasma plume logarithmically depends on the plasma plume charge which changes with both the electric field and the resistive force.

  16. Impact of aerosol particles on the structure of an atmospheric pressure microwave plasma afterglow

    Energy Technology Data Exchange (ETDEWEB)

    Chen Chunku [Ceramic and Composite Materials Centre, 209 Farris Engineering Centre, University of New Mexico, Albuquerque, NM (United States); Phillips, Jonathan [Los Alamos National Laboratory, MS C930, Los Alamos, NM (United States)

    2002-05-21

    Several novel ceramic processing technologies (e.g. oxide ceramic melting and spheroidization) using an atmospheric pressure microwave plasma torch were recently developed in our lab. Understanding the processes and optimization requires complete characterization of the plasma as a function of operating condition. As a first step, a non-intrusive spectroscopic method was employed to map rotational (gas), electron and excitation temperatures and electron densities of the afterglow region of microwave generated atmospheric plasmas with and without alumina particle aerosol. Two-dimensional spatially resolved mapping of rotational (gas), excitation and electron temperatures and electron densities as a function of operating conditions during material processing were developed. It was shown that the passage of an aerosol dramatically changes the structure of the afterglow. Also the non-equilibrium nature of microwave generated atmospheric argon plasma was confirmed, suggesting that only multi-temperature models are capable of modelling this region of the plasma. (author)

  17. High quality graphene synthesized by atmospheric pressure CVD on copper foil

    OpenAIRE

    Trinsoutrot, Pierre; Rabot, Caroline; Vergnes, Hugues; Delamoreanu, Alexandru; Zenasni, Aziz; Caussat, Brigitte

    2013-01-01

    International audience; Graphene was synthesized at 1000 °C by Atmospheric Pressure Chemical Vapor Deposition on copper foil from methane diluted in argon and hydrogen. The influence of the main synthesis parameters was studied on 2 × 2 cm2 foils in order to obtain continuous monolayer graphenewithout crystalline defect. The uniformity, crystal quality and number of layers of graphenewere analyzed by Raman spectroscopy and Scanning Electronic Microscopy. First, an increase of the annealing pr...

  18. Characteristics of meter-scale surface electrical discharge propagating along water surface at atmospheric pressure

    Czech Academy of Sciences Publication Activity Database

    Hoffer, Petr; Sugiyama, Y.; Hosseini, S.H.R.; Akiyama, H.; Lukeš, Petr; Akiyama, M.

    2016-01-01

    Roč. 49, č. 41 (2016), č. článku 415202. ISSN 0022-3727 Institutional support: RVO:61389021 Keywords : water surface * spectroscopy * high-speed photography * pulsed plasma discharge * Atmospheric - pressure plasmas * electric discharges * liquids * water Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.588, year: 2016 http://iopscience.iop.org/article/10.1088/0022-3727/49/41/415202

  19. Characterization of Nitrated Sugar Alcohols by Atmospheric-Pressure Chemical-Ionization Mass Spectrometry

    Science.gov (United States)

    2016-07-27

    Chemical, Microsystem, and Nanoscale Technology Group MIT-Lincoln Laboratory, Lexington, MA 02420 jude.kelley@ll.mit.edu RATIONALE: The...formed by the loss of NO2, HNO2, NO3, and CH2NO2 groups , and in the presence of dichloromethane chlorinated adduct ions were observed. It was determined...explosives trace detection, such as electrospray ionization ( ESI ) and atmospheric pressure chemical ionization (APCI) mass spectrometry (MS) along

  20. Characterization of a dielectric barrier plasma gun discharging at atmospheric pressure

    International Nuclear Information System (INIS)

    Zhang Guangqiu; Ge Yuanjing; Zhang Yuefei; Chen Guangliang

    2004-01-01

    The authors develop a plasma gun based on dielectric barrier discharge and working at atmospheric pressure. A theoretical model to predict the gun discharge voltage is built, which is in agreement with the experimental results. After investigating the characterization of discharging gun and utilizing it for polymerization, authors find that the gun can be used as a source to generate a stable uniform plasma for different plasma-processing technologies. (author)

  1. Parameters of an avalanche of runaway electrons in air under atmospheric pressure

    Science.gov (United States)

    Oreshkin, E. V.

    2018-01-01

    The features of runaway-electron avalanches developing in air under atmospheric pressures are investigated in the framework of a three-dimensional numerical simulation. The simulation results indicate that an avalanche of this type can be characterized, besides the time and length of its exponential growth, by the propagation velocity and by the average kinetic energy of the runaway electrons. It is shown that these parameters obey the similarity laws applied to gas discharges.

  2. Characterization of Carbon Nanotubes Deposited in Microwave Torch at Atmospheric Pressure

    Czech Academy of Sciences Publication Activity Database

    Zajíčková, L.; Eliáš, M.; Jašek, O.; Kučerová, Z.; Synek, P.; Matějková, Jiřina; Kadlečíková, M.; Klementová, Mariana; Buršík, Jiří; Vojačková, A.

    2007-01-01

    Roč. 4, Suppl. 1 (2007), S245-S249 ISSN 1612-8850 R&D Projects: GA ČR(CZ) GA202/05/0607 Institutional research plan: CEZ:AV0Z20650511; CEZ:AV0Z40320502; CEZ:AV0Z20410507 Keywords : carbon nanotubes * microwave torch * atmospheric pressure * scanning electron microscopy * Raman spectroscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.132, year: 2007

  3. Characteristics of meter-scale surface electrical discharge propagating along water surface at atmospheric pressure

    Czech Academy of Sciences Publication Activity Database

    Hoffer, Petr; Sugiyama, Y.; Hosseini, S.H.R.; Akiyama, H.; Lukeš, Petr; Akiyama, M.

    2016-01-01

    Roč. 49, č. 41 (2016), č. článku 415202. ISSN 0022-3727 Institutional support: RVO:61389021 Keywords : water surface * spectroscopy * high-speed photography * pulsed plasma discharge * Atmospheric-pressure plasmas * electric discharges * liquids * water Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.588, year: 2016 http://iopscience.iop.org/article/10.1088/0022-3727/49/41/415202

  4. Collaborative Research: Atmospheric Pressure Microplasma Chemistry-Photon Synergies Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Graves, David [Univ. of California, Berkeley, CA (United States)

    2017-02-07

    Combining the effects of low temperature, atmospheric pressure microplasmas and microplasma photon sources shows greatly expanded range of applications of each of them. The plasma sources create active chemical species and these can be activated further by addition of photons and associated photochemistry. There are many ways to combine the effects of plasma chemistry and photochemistry, especially if there are multiple phases present. The project combines construction of appropriate test experimental systems, various spectroscopic diagnostics and mathematical modeling.

  5. Characterization of an atmospheric pressure air plasma source for polymer surface modification

    Science.gov (United States)

    Yang, Shujun; Tang, Jiansheng

    2013-10-01

    An atmospheric pressure air plasma source was generated through dielectric barrier discharge (DBD). It was used to modify polyethyleneterephthalate (PET) surfaces with very high throughput. An equivalent circuit model was used to calculate the peak average electron density. The emission spectrum from the plasma was taken and the main peaks in the spectrum were identified. The ozone density in the down plasma region was estimated by Absorption Spectroscopy. NSF and ARC-ODU

  6. Fundamental Studies of Transient, Atmospheric-Pressure, Small-Scale Plasmas

    Science.gov (United States)

    2017-01-23

    C. Jiang, R. Heller, J. Lane, and K. H. Schoenbach, " Ozone -free nitric oxide production using an atmospheric pressure surface discharge – a way to...Electrostatic modeling and energy-dependent studies showed that the direct and indirect electron-induced processes in the pulsed plasma jet are responsible for...Coupled sliding discharges : a scalable nonthermal plasma system utilizing positive and negative streamers on DISTRIBUTION A: Distribution

  7. Cleaning of niobium surface by plasma of diffuse discharge at atmospheric pressure

    Science.gov (United States)

    Tarasenko, V. F.; Erofeev, M. V.; Shulepov, M. A.; Ripenko, V. S.

    2017-07-01

    Elements composition of niobium surface before and after plasma treatment by runaway electron preionized diffuse discharge was investigated in atmospheric pressure nitrogen flow by means of an Auger electron spectroscopy. Surface characterizations obtained from Auger spectra show that plasma treatment by diffuse discharge after exposure of 120000 pulses provides ultrafine surface cleaning from carbon contamination. Moreover, the surface free energy of the treated specimens increased up to 3 times, that improve its adhesion property.

  8. REFERENCE ON THERMOPHYSICAL PROPERTIES: DENSITY AND VISCOSITY OF WATER FOR ATMOSPHERIC PRESSURE

    Directory of Open Access Journals (Sweden)

    Elin Yusibani

    2016-09-01

    Full Text Available A reference on thermophysical properties, density and viscosity, for water at atmospheric pressure has been developed in MS Excel (as a macros. Patterson’s density equations and Kestin’s viscosity equations have been chosen as a basic equation in the VBA programming as a user-defined function. These results have been compared with REFPROF as a wellknow standart reference

  9. Analysis of insect triacylglycerols using liquid chromatography-atmospheric pressure chemical ionization-mass spectrometry

    Czech Academy of Sciences Publication Activity Database

    Kofroňová, Edita; Cvačka, Josef; Jiroš, Pavel; Sýkora, D.; Valterová, Irena

    2009-01-01

    Roč. 111, č. 5 (2009), s. 519-525 ISSN 1438-7697 R&D Projects: GA AV ČR IAA4055403; GA MŠk 2B06007 Institutional research plan: CEZ:AV0Z40550506 Keywords : atmospheric pressure chemical ionization * bumblebees * fat body * NARP-HPLC Subject RIV: CC - Organic Chemistry Impact factor: 1.831, year: 2009

  10. Using dimers to measure biosignatures and atmospheric pressure for terrestrial exoplanets.

    Science.gov (United States)

    Misra, Amit; Meadows, Victoria; Claire, Mark; Crisp, Dave

    2014-02-01

    We present a new method to probe atmospheric pressure on Earth-like planets using (O2-O2) dimers in the near-infrared. We also show that dimer features could be the most readily detectable biosignatures for Earth-like atmospheres and may even be detectable in transit transmission with the James Webb Space Telescope (JWST). The absorption by dimers changes more rapidly with pressure and density than that of monomers and can therefore provide additional information about atmospheric pressures. By comparing the absorption strengths of rotational and vibrational features to the absorption strengths of dimer features, we show that in some cases it may be possible to estimate the pressure at the reflecting surface of a planet. This method is demonstrated by using the O2 A band and the 1.06 μm dimer feature, either in transmission or reflected spectra. It works best for planets around M dwarfs with atmospheric pressures between 0.1 and 10 bar and for O2 volume mixing ratios above 50% of Earth's present-day level. Furthermore, unlike observations of Rayleigh scattering, this method can be used at wavelengths longer than 0.6 μm and is therefore potentially applicable, although challenging, to near-term planet characterization missions such as JWST. We also performed detectability studies for JWST transit transmission spectroscopy and found that the 1.06 and 1.27 μm dimer features could be detectable (SNR>3) for an Earth analogue orbiting an M5V star at a distance of 5 pc. The detection of these features could provide a constraint on the atmospheric pressure of an exoplanet and serve as biosignatures for oxygenic photosynthesis. We calculated the required signal-to-noise ratios to detect and characterize O2 monomer and dimer features in direct imaging-reflected spectra and found that signal-to-noise ratios greater than 10 at a spectral resolving power of R=100 would be required.

  11. Controlling hydrophilicity of polymer film by altering gas flow rate in atmospheric-pressure homogeneous plasma

    International Nuclear Information System (INIS)

    Kang, Woo Seok; Hur, Min; Lee, Jae-Ok; Song, Young-Hoon

    2014-01-01

    Graphical abstract: - Highlights: • Controlling hydrophilicity of polymer film by varying gas flow rate is proposed in atmospheric-pressure homogeneous plasma treatment. • Without employing additional reactive gas, requiring more plasma power and longer treatment time, hydrophilicity of polyimide films was improved after the low-gas-flow plasma treatment. • The gas flow rate affects the hydrophilic properties of polymer surface by changing the discharge atmosphere in the particular geometry of the reactor developed. • Low-gas-flow induced wettability control suggests effective and economical plasma treatment. - Abstract: This paper reports on controlling the hydrophilicity of polyimide films using atmospheric-pressure homogeneous plasmas by changing only the gas flow rate. The gas flow changed the discharge atmosphere by mixing the feed gas with ambient air because of the particular geometry of the reactor developed for the study, and a low gas flow rate was found to be favorable because it generated abundant nitrogen or oxygen species that served as sources of hydrophilic functional groups over the polymer surface. After low-gas-flow plasma treatment, the polymer surface exhibited hydrophilic characteristics with increased surface roughness and enhanced chemical properties owing to the surface addition of functional groups. Without adding any reactive gases or requiring high plasma power and longer treatment time, the developed reactor with low-gas-flow operation offered effective and economical wettability control of polyimide films

  12. Intracellular effects of atmospheric-pressure plasmas on melanoma cancer cells

    Energy Technology Data Exchange (ETDEWEB)

    Ishaq, M., E-mail: ishaqmusarat@gmail.com [Peter MacCallum Cancer Centre, East Melbourne, VIC 3002 (Australia); Comonwealth Scientific and Industrial Research Organization, Sydney, New South Wales (Australia); Bazaka, K. [Institute for Health and Biomedical Innovation, School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology, Brisbane, QLD 4000 (Australia); Ostrikov, K. [Comonwealth Scientific and Industrial Research Organization, Sydney, New South Wales (Australia); Institute for Health and Biomedical Innovation, School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology, Brisbane, QLD 4000 (Australia)

    2015-12-15

    Gas discharge plasmas formed at atmospheric pressure and near room temperature have recently been shown as a promising tool for cancer treatment. The mechanism of the plasma action is attributed to generation of reactive oxygen and nitrogen species, electric fields, charges, and photons. The relative importance of different modes of action of atmospheric-pressure plasmas depends on the process parameters and specific treatment objects. Hence, an in-depth understanding of biological mechanisms that underpin plasma-induced death in cancer cells is required to optimise plasma processing conditions. Here, the intracellular factors involved in the observed anti-cancer activity in melanoma Mel007 cells are studied, focusing on the effect of the plasma treatment dose on the expression of tumour suppressor protein TP73. Over-expression of TP73 causes cell growth arrest and/or apoptosis, and hence can potentially be targeted to enhance killing efficacy and selectivity of the plasma treatment. It is shown that the plasma treatment induces dose-dependent up-regulation of TP73 gene expression, resulting in significantly elevated levels of TP73 RNA and protein in plasma-treated melanoma cells. Silencing of TP73 expression by means of RNA interference inhibited the anticancer effects of the plasma, similar to the effect of caspase inhibitor z-VAD or ROS scavenger N-acetyl cysteine. These results confirm the role of TP73 protein in dose-dependent regulation of anticancer activity of atmospheric-pressure plasmas.

  13. Atmospheric pressure MALDI for the noninvasive characterization of carbonaceous ink from Renaissance documents.

    Science.gov (United States)

    Grasso, Giuseppe; Calcagno, Marzia; Rapisarda, Alessandro; D'Agata, Roberta; Spoto, Giuseppe

    2017-06-01

    The analytical methods that are usually applied to determine the compositions of inks from ancient manuscripts usually focus on inorganic components, as in the case of iron gall ink. In this work, we describe the use of atmospheric pressure/matrix-assisted laser desorption ionization-mass spectrometry (AP/MALDI-MS) as a spatially resolved analytical technique for the study of the organic carbonaceous components of inks used in handwritten parts of ancient books for the first time. Large polycyclic aromatic hydrocarbons (L-PAH) were identified in situ in the ink of XVII century handwritten documents. We prove that it is possible to apply MALDI-MS as a suitable microdestructive diagnostic tool for analyzing samples in air at atmospheric pressure, thus simplifying investigations of the organic components of artistic and archaeological objects. The interpretation of the experimental MS results was supported by independent Raman spectroscopic investigations. Graphical abstract Atmospheric pressure/MALDI mass spectrometry detects in situ polycyclic aromatic hydrocarbons in the carbonaceous ink of XVII century manuscripts.

  14. Non-thermal atmospheric-pressure plasma possible application in wound healing.

    Science.gov (United States)

    Haertel, Beate; von Woedtke, Thomas; Weltmann, Klaus-Dieter; Lindequist, Ulrike

    2014-11-01

    Non-thermal atmospheric-pressure plasma, also named cold plasma, is defined as a partly ionized gas. Therefore, it cannot be equated with plasma from blood; it is not biological in nature. Non-thermal atmospheric-pressure plasma is a new innovative approach in medicine not only for the treatment of wounds, but with a wide-range of other applications, as e.g. topical treatment of other skin diseases with microbial involvement or treatment of cancer diseases. This review emphasizes plasma effects on wound healing. Non-thermal atmospheric-pressure plasma can support wound healing by its antiseptic effects, by stimulation of proliferation and migration of wound relating skin cells, by activation or inhibition of integrin receptors on the cell surface or by its pro-angiogenic effect. We summarize the effects of plasma on eukaryotic cells, especially on keratinocytes in terms of viability, proliferation, DNA, adhesion molecules and angiogenesis together with the role of reactive oxygen species and other components of plasma. The outcome of first clinical trials regarding wound healing is pointed out.

  15. Effect of feed-gas humidity on nitrogen atmospheric-pressure plasma jet for biological applications.

    Science.gov (United States)

    Stephan, Karl D; McLean, Robert J C; DeLeon, Gian; Melnikov, Vadim

    2016-11-14

    We investigate the effect of feed-gas humidity on the oxidative properties of an atmospheric-pressure plasma jet using nitrogen gas. Plasma jets operating at atmospheric pressure are finding uses in medical and biological settings for sterilization and other applications involving oxidative stress applied to organisms. Most jets use noble gases, but some researchers use less expensive nitrogen gas. The feed-gas water content (humidity) has been found to influence the performance of noble-gas plasma jets, but has not yet been systematically investigated for jets using nitrogen gas. Low-humidity and high-humidity feed gases were used in a nitrogen plasma jet, and the oxidation effect of the jet was measured quantitatively using a chemical dosimeter known as FBX (ferrous sulfate-benzoic acid-xylenol orange). The plasma jet using high humidity was found to have about ten times the oxidation effect of the low-humidity jet, as measured by comparison with the addition of measured amounts of hydrogen peroxide to the FBX dosimeter. Atmospheric-pressure plasma jets using nitrogen as a feed gas have a greater oxidizing effect with a high level of humidity added to the feed gas.

  16. [Investigation on the gas temperature of a plasma jet at atmospheric pressure by emission spectrum].

    Science.gov (United States)

    Li, Xue-chen; Yuan, Ning; Jia, Peng-ying; Niu, Dong-ying

    2010-11-01

    A plasma jet of a dielectric barrier discharge in coaxial electrode was used to produce plasma plume in atmospheric pressure argon. Spatially and temporally resolved measurement was carried out by photomultiplier tubes. The light emission signals both from the dielectric barrier discharge and from the plasma plume were analyzed. Furthermore, emission spectrum from the plasma plume was collected by high-resolution optical spectrometer. The emission spectra of OH (A 2sigma + --> X2 II, 307.7-308.9 nm) and the first negative band of N2+ (B2 sigma u+ --> X2 IIg+, 390-391.6 nm) were used to estimate the rotational temperature of the plasma plume by fitting the experimental spectra to the simulated spectra. The rotational temperature obtained is about 443 K by fitting the emission spectrum from the OH, and that from the first negative band of N2+ is about 450 K. The rotational temperatures obtained by the two method are consistent within 5% error band. The gas temperature of the plasma plume at atmospheric pressure was obtained because rotational temperature equals to gas temperature approximately in gas discharge at atmospheric pressure. Results show that gas temperature increases with increasing the applied voltage.

  17. Efficacy of Atmospheric Pressure Plasma as an Antibacterial Agent Against Enterococcus Faecalis in Vitro

    International Nuclear Information System (INIS)

    Cao Yingguang; Yang Ping; Lu Xinpei; Xiong Zilan; Ye Tao; Xiong Qing; Sun Ziyong

    2011-01-01

    Enterococcus faecalis (E. faecalis) is a microorganism that can survive extreme challenges in obturated root canals. The aim of this study was to evaluate the efficacy of a non-thermal atmospheric pressure plasma plume against E. faecalis in vitro. A non-thermal atmospheric pressure plasma jet device which could generate a cold plasma plume carrying a peak current of 300 mA was used. The antibacterial efficacy of this device against E. faecalis and its biofilm under different conditions was detected. The antibacterial efficacy of the plasma against E. faecalis and Staphylococcus aureus (S. aureus) was also evaluated. After plasma treatment, the average diameter of inhibition zone on S. aureus and E. faecalis was 2.62±0.26 cm and 1.06±0.30 cm, respectively (P < 0.05). The diameter was increased with prolongation of the treatment duration. The diameters of inhibition zone of the sealed Petri dishes were larger than those of the uncovered Petri dishes. There was significant difference in colony-forming units between plasma group and control group on E. faecalis biofilm (P < 0.01). The transmission electron microscopy revealed that the ultrastructural changes cytoderm of E. faecalis were observed after treatment for 2 min. It is concluded that the non-thermal atmospheric pressure plasma could serve as an effective adjunct to standard endodontic microbial treatment.

  18. Atmospheric pressure plasma jet with high-voltage power supply based on piezoelectric transformer.

    Science.gov (United States)

    Babij, Michał; Kowalski, Zbigniew W; Nitsch, Karol; Silberring, Jerzy; Gotszalk, Teodor

    2014-05-01

    The dielectric barrier discharge plasma jet, an example of the nonthermal atmospheric pressure plasma jet (APPJ), generates low-temperature plasmas that are suitable for the atomization of volatile species and can also be served as an ionization source for ambient mass and ion mobility spectrometry. A new design of APPJ for mass spectrometry has been built in our group. In these plasma sources magnetic transformers (MTs) and inductors are typically used in power supplies but they present several drawbacks that are even more evident when dealing with high-voltage normally used in APPJs. To overcome these disadvantages, high frequency generators with the absence of MT are proposed in the literature. However, in the case of miniaturized APPJs these conventional power converters, built of ferromagnetic cores and inductors or by means of LC resonant tank circuits, are not so useful as piezoelectric transformer (PT) based power converters due to bulky components and small efficiency. We made and examined a novel atmospheric pressure plasma jet with PT supplier served as ionization source for ambient mass spectrometry, and especially mobile spectrometry where miniaturization, integration of components, and clean plasma are required. The objective of this paper is to describe the concept, design, and implementation of this miniaturized piezoelectric transformer-based atmospheric pressure plasma jet.

  19. Analysis of atmospheric pressure and temperature effects on cosmic ray measurements

    Science.gov (United States)

    de MendonçA, R. R. S.; Raulin, J.-P.; Echer, E.; Makhmutov, V. S.; Fernandez, G.

    2013-04-01

    In this paper, we analyze atmospheric pressure and temperature effects on the records of the cosmic ray detector CARPET. This detector has monitored secondary cosmic ray intensity since 2006 at Complejo Astronómico El Leoncito (San Juan, Argentina, 31°S, 69°W, 2550 m over sea level) where the geomagnetic rigidity cutoff, Rc, is ~9.8 GV. From the correlation between atmospheric pressure deviations and relative cosmic ray variations, we obtain a barometric coefficient of -0.44 ± 0.01 %/hPa. Once the data are corrected for atmospheric pressure, they are used to analyze temperature effects using four methods. Three methods are based on the surface temperature and the temperature at the altitude of maximum production of secondary cosmic rays. The fourth method, the integral method, takes into account the temperature height profile between 14 and 111 km above Complejo Astronómico El Leoncito. The results obtained from these four methods are compared on different time scales from seasonal time variations to scales related to the solar activity cycle. Our conclusion is that the integral method leads to better results to remove the temperature effect of the cosmic ray intensity observed at ground level.

  20. Atmospheric pressure plasma jet with high-voltage power supply based on piezoelectric transformer

    Energy Technology Data Exchange (ETDEWEB)

    Babij, Michał; Kowalski, Zbigniew W., E-mail: zbigniew.w.kowalski@pwr.wroc.pl; Nitsch, Karol; Gotszalk, Teodor [Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław (Poland); Silberring, Jerzy [AGH University of Science and Technology, Al. A. Mickiewicza 30, 30-059 Kraków (Poland)

    2014-05-15

    The dielectric barrier discharge plasma jet, an example of the nonthermal atmospheric pressure plasma jet (APPJ), generates low-temperature plasmas that are suitable for the atomization of volatile species and can also be served as an ionization source for ambient mass and ion mobility spectrometry. A new design of APPJ for mass spectrometry has been built in our group. In these plasma sources magnetic transformers (MTs) and inductors are typically used in power supplies but they present several drawbacks that are even more evident when dealing with high-voltage normally used in APPJs. To overcome these disadvantages, high frequency generators with the absence of MT are proposed in the literature. However, in the case of miniaturized APPJs these conventional power converters, built of ferromagnetic cores and inductors or by means of LC resonant tank circuits, are not so useful as piezoelectric transformer (PT) based power converters due to bulky components and small efficiency. We made and examined a novel atmospheric pressure plasma jet with PT supplier served as ionization source for ambient mass spectrometry, and especially mobile spectrometry where miniaturization, integration of components, and clean plasma are required. The objective of this paper is to describe the concept, design, and implementation of this miniaturized piezoelectric transformer-based atmospheric pressure plasma jet.

  1. Atmospheric pressure plasma enhanced chemical vapor deposition of zinc oxide and aluminum zinc oxide

    International Nuclear Information System (INIS)

    Johnson, Kyle W.; Guruvenket, Srinivasan; Sailer, Robert A.; Ahrenkiel, S. Phillip; Schulz, Douglas L.

    2013-01-01

    Zinc oxide (ZnO) and aluminum-doped zinc oxide (AZO) thin films were deposited via atmospheric pressure plasma enhanced chemical vapor deposition. A second-generation precursor, bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(N,N′-diethylethylenediamine) zinc, exhibited significant vapor pressure and good stability at one atmosphere where a vaporization temperature of 110 °C gave flux ∼ 7 μmol/min. Auger electron spectroscopy confirmed that addition of H 2 O to the carrier gas stream mitigated F contamination giving nearly 1:1 metal:oxide stoichiometries for both ZnO and AZO with little precursor-derived C contamination. ZnO and AZO thin film resistivities ranged from 14 to 28 Ω·cm for the former and 1.1 to 2.7 Ω·cm for the latter. - Highlights: • A second generation precursor was utilized for atmospheric pressure film growth. • Addition of water vapor to the carrier gas stream led to a marked reduction of ZnF 2 . • Carbonaceous contamination from the precursor was minimal

  2. Atmospheric Pressure and Onset of Episodes of Menière's Disease - A Repeated Measures Study.

    Science.gov (United States)

    Gürkov, Robert; Strobl, Ralf; Heinlin, Nina; Krause, Eike; Olzowy, Bernhard; Koppe, Christina; Grill, Eva

    2016-01-01

    External changes of air pressure are transmitted to the middle and inner ear and may be used therapeutically in Menière's disease, one of the most common vertigo disorders. We analyzed the possible relationship of atmospheric pressure and other meteorological parameters with the onset of MD vertigo episodes in order to determine whether atmospheric pressure changes play a role in the occurrence of MD episodes. Patients of a tertiary outpatient dizziness clinic diagnosed with MD were asked to keep a daily vertigo diary to document MD episodes (2004-2009). Local air pressure, absolute temperature and dew point temperature were acquired on an hourly basis. Change in meteorological parameters was conceptualized as the maximum difference in a 24 hour time frame preceding each day. Effects were estimated using additive mixed models with a random participant effect. We included lagged air parameters, age, sex, weekday and season in the model. A total of 56 persons (59% female) with mean age 54 years were included. Mean follow-up time was 267 days. Persons experienced on average 10.3 episodes during the observation period (median 8). Age and change in air pressure were significantly associated with vertigo onset risk (Odds Ratio = 0.979 and 1.010). We could not show an effect of sex, weekday, season, air temperature, and dew point temperature. Change in air pressure was significantly associated with onset of MD episodes, suggesting a potential triggering mechanism in the inner ear. MD patients may possibly use air pressure changes as an early warning system for vertigo attacks in the future.

  3. Kinetics and dynamics of nanosecond streamer discharge in atmospheric-pressure gas bubble suspended in distilled water under saturated vapor pressure conditions

    KAUST Repository

    Sharma, Ashish; Levko, Dmitry; Raja, Laxminarayan L; Cha, Min

    2016-01-01

    We perform computational studies of nanosecond streamer discharges generated in helium bubbles immersed in distilled water under atmospheric pressure conditions. The model takes into account the presence of water vapor in the gas bubble

  4. Comparisons of Fabric Strength and Development in Polycrystalline Ice at Atmospheric and Basal Hydrostatic Pressures

    Science.gov (United States)

    Breton, Daniel; Baker, Ian; Cole, David

    2013-04-01

    Understanding and predicting the flow of polycrystalline ice is crucial to ice sheet modeling and paleoclimate reconstruction from ice cores. Ice flow rates depend strongly on the fabric (i.e. the distribution of grain sizes and crystallographic orientations) which evolves over time and enhances the flow rate in the direction of applied stress. The mechanisms for fabric evolution in ice have been extensively studied at atmospheric pressures, but little work has been done to observe these processes at the high pressures experienced deep within ice sheets where long-term changes in ice rheology are expected to have significance. We conducted compressive creep tests to ~10% strain on 917 kg m-3, initially randomly-oriented polycrystalline ice specimens at 0.1 (atmospheric) and 20 MPa (simulating ~2,000 m depth) hydrostatic pressures, performing microstructural analyses on the resulting deformed specimens to characterize the evolution and strength of crystal fabric. Our microstructural analysis technique simultaneously collects grain shape and size data from Scanning Electron Microscope (SEM) micrographs and obtains crystallographic orientation data via Electron BackScatter Diffraction (EBSD). Combining these measurements allows rapid analysis of the ice fabric over large numbers of grains, yielding statistically useful numbers of grain size and orientation data. We present creep and microstructural data to demonstrate pressure-dependent effects on the mechanical and microstructural evolution of polycrystalline ice and discuss possible mechanisms for the observed differences.

  5. ANNEALING OF POLYCRYSTALLINE THIN FILM SILICON SOLAR CELLS IN WATER VAPOUR AT SUB-ATMOSPHERIC PRESSURES

    Directory of Open Access Journals (Sweden)

    Peter Pikna

    2014-10-01

    Full Text Available Thin film polycrystalline silicon (poly-Si solar cells were annealed in water vapour at pressures below atmospheric pressure. PN junction of the sample was contacted by measuring probes directly in the pressure chamber filled with steam during passivation. Suns-VOC method and a Lock-in detector were used to monitor an effect of water vapour to VOC of the solar cell during whole passivation process (in-situ. Tested temperature of the sample (55°C – 110°C was constant during the procedure. Open-circuit voltage of a solar cell at these temperatures is lower than at room temperature. Nevertheless, voltage response of the solar cell to the light flash used during Suns-VOC measurements was good observable. Temperature dependences for multicrystalline wafer-based and polycrystalline thin film solar cells were measured and compared. While no significant improvement of thin film poly-Si solar cell parameters by annealing in water vapour at under-atmospheric pressures was observed up to now, in-situ observation proved required sensitivity to changing VOC at elevated temperatures during the process.

  6. Effects of periodic atmospheric pressure variation on radon entry into buildings

    Science.gov (United States)

    Tsang, Y. W.; Narasimhan, T. N.

    1992-06-01

    Using a mathematical model, we have investigated the temporal variations of radon entry into a house basement in the presence of time-dependent periodic variations of barometric pressure as well as a persistent small steady depressurization within the basement. The tool for our investigation is an integral finite difference numerical code which can solve for both diffusive and advective flux of radon in the soil gas which is treated as a slightly compressible fluid. Two different boundary conditions at the house basement are considered: (1) a dirt floor basement so that diffusion is equally or more important than advective transport, and (2) an "impermeable" cement basement except for a 1-cm-wide crack near the perimeter of the basement floor; in which case, advective transport of radon flux dominates. Two frequencies of barometric pressure fluctuation with representative values of amplitudes, based on a Fourier decomposition of barometric pressure data, were chosen in this study: one with a short period of 0.5 hour with pressure amplitude of 50 Pa, the other a diurnal variation with a period of 24 hours with the typical pressure amplitude of 250 Pa. For a homogeneous soil medium with soil permeability to air between 10-13 and 10-10 m2, we predict that the barometric fluctuations increase the radon entry into the basement by up to 120% of the steady radon inflow into the basement owing to a steady depressurization of 5 Pa. If soil permeability heterogeneity is present, such as the presence of a thin layer of higher permeability aggregate immediately below the basement floor, radon flux due to atmospheric pumping is further increased. Effects of pressure pumping on radon entry are also compared to diffusion-only transport when the steady depressurization is absent. It is found that contribution to radon entry is significant for the basement crack configuration. In particular, for pressure pumping at 0.5-hour period and for a homogeneous medium of permeability of 10

  7. Meteorology in ruptured abdominal aortic aneurysm: an institutional study and a meta-analysis of published studies reporting atmospheric pressure.

    Science.gov (United States)

    Takagi, H; Watanabe, T; Mizuno, Y; Kawai, N; Umemoto, T

    2014-12-01

    The aim of this paper was to determine whether weather factors including atmospheric pressure are associated with the occurrence of ruptured abdominal aortic aneurysm (RAAA). We investigated our institutional experiences of RAAA in more than 150 patients during 8 years. Further, we performed a meta-analysis of published studies reporting the influence of atmospheric pressure on RAAA. We retrospectively evaluated 152 patients who underwent surgery for RAAA (including ruptured iliac arterial aneurysm) at our institute between 1 January 2006 and 31 December 2013. Daily regional meteorological data (in the nearest weather station located 3.5 km from the hospital) were obtained online from Japan Meteorological Agency. To identify comparative studies of mean atmospheric pressure on the day with RAAA versus that on the day without RAAA, MEDLINE and EMBASE were searched through January 2014 using Web-based search engines (PubMed and OVID). Mean sea level atmospheric pressure, delta mean atmospheric pressure (difference between mean sea level atmospheric pressure on the day and that on the previous day), and sunshine duration on the day with RAAA were significantly lower than those on the day without RAAA: 1012.43±7.44 versus 1013.71±6.49 hPa, P=0.039, -1.18±5.15 versus 0.05±5.62 hPa, P=0.005; and 4.76±3.76 versus 5.47±3.88 h, P=0.026; respectively. A pooled analysis of 8 studies (including our institutional study) demonstrated that mean atmospheric pressure on the day with RAAA was significantly lower than that on the day without RAAA: standardized mean difference, -0.09; 95% confidence interval, -0.14 to -0.04; P=0.0009. Atmospheric pressure on the day with RAAA appears lower than that on the day without RAAA. Atmospheric pressure may be associated with the occurrence of RAAA.

  8. Is the negative glow plasma of a direct current glow discharge negatively charged?

    International Nuclear Information System (INIS)

    Bogdanov, E. A.; Saifutdinov, A. I.; Demidov, V. I.; Kudryavtsev, A. A.

    2015-01-01

    A classic problem in gas discharge physics is discussed: what is the sign of charge density in the negative glow region of a glow discharge? It is shown that traditional interpretations in text-books on gas discharge physics that states a negative charge of the negative glow plasma are based on analogies with a simple one-dimensional model of discharge. Because the real glow discharges with a positive column are always two-dimensional, the transversal (radial) term in divergence with the electric field can provide a non-monotonic axial profile of charge density in the plasma, while maintaining a positive sign. The numerical calculation of glow discharge is presented, showing a positive space charge in the negative glow under conditions, where a one-dimensional model of the discharge would predict a negative space charge

  9. An improved film evaporation correlation for saline water at sub-atmospheric pressures

    KAUST Repository

    Shahzada, Muhammad Wakil

    2011-10-03

    This paper presents an investigation of heat transfer correlation in a falling-film evaporator working with saline water at sub-atmospheric pressures. The experiments are conducted at different salinity levels ranging from 15000 to 90000 ppm, and the pressures were maintained between 0.92 to 2.81 kPa (corresponds to saturation temperatures of 5.9 – 23 0C). The effect of salinity, saturation pressures and chilled water temperatures on the heat transfer coefficient are accounted in the modified film evaporation correlations. The results are fitted to the Han & Fletcher\\'s and Chun & Seban\\'s falling-film correlations which are used in desalination industry. We modify the said correlations by adding salinity and saturation temperature corrections with respective indices to give a better agreement to our measured data.

  10. An improved film evaporation correlation for saline water at sub-atmospheric pressures

    KAUST Repository

    Shahzada, Muhammad Wakil; Ng, Kim Choon; Thu, Kyaw; Myat, Aung; Gee, Chun Won

    2011-01-01

    This paper presents an investigation of heat transfer correlation in a falling-film evaporator working with saline water at sub-atmospheric pressures. The experiments are conducted at different salinity levels ranging from 15000 to 90000 ppm, and the pressures were maintained between 0.92 to 2.81 kPa (corresponds to saturation temperatures of 5.9 – 23 0C). The effect of salinity, saturation pressures and chilled water temperatures on the heat transfer coefficient are accounted in the modified film evaporation correlations. The results are fitted to the Han & Fletcher's and Chun & Seban's falling-film correlations which are used in desalination industry. We modify the said correlations by adding salinity and saturation temperature corrections with respective indices to give a better agreement to our measured data.

  11. Measurement of negative ion mobilities in O2 and O3 mixtures at atmospheric pressure

    International Nuclear Information System (INIS)

    Itoh, H.; Norimoto, K.; Hayashi, T.

    1998-01-01

    Mobility measurements of negative molecular oxygen ions in pure oxygen and in an oxygen-ozone mixture are reported. A cascaded gap consisting of an ion drift gap and an ion detection gap was used in the experiment. The ion detection gap was formed by a positive point and a grounded plane electrode was operated at atmospheric pressure. The zero field mobility of negative molecular oxygen ions was determined to be 2.07+-0.02 cm 2 /V.s. A somewhat higher value of oxygen mobility was found at higher electric field/pressure ratios; this is presumed to be due to negative ozone ions. When changing the electric field/pressure ratio the mobility of negative oxygen ions in oxygen-ozone mixtures becomes smaller than that in pure oxygen; this is probably due to the cumulative effect of other particles produced by silent discharges. (J.U.)

  12. THE HABITABLE ZONE OF EARTH-LIKE PLANETS WITH DIFFERENT LEVELS OF ATMOSPHERIC PRESSURE

    Energy Technology Data Exchange (ETDEWEB)

    Vladilo, Giovanni; Murante, Giuseppe; Silva, Laura [INAF-Trieste Astronomical Observatory, Trieste (Italy); Provenzale, Antonello [Institute of Atmospheric Sciences and Climate-CNR, Torino (Italy); Ferri, Gaia; Ragazzini, Gregorio, E-mail: vladilo@oats.inaf.it [Department of Physics, University of Trieste, Trieste (Italy)

    2013-04-10

    As a contribution to the study of the habitability of extrasolar planets, we implemented a one-dimensional energy balance model (EBM), the simplest seasonal model of planetary climate, with new prescriptions for most physical quantities. Here we apply our EBM to investigate the surface habitability of planets with an Earth-like atmospheric composition but different levels of surface pressure. The habitability, defined as the mean fraction of the planet's surface on which liquid water could exist, is estimated from the pressure-dependent liquid water temperature range, taking into account seasonal and latitudinal variations of surface temperature. By running several thousands of EBM simulations we generated a map of the habitable zone (HZ) in the plane of the orbital semi-major axis, a, and surface pressure, p, for planets in circular orbits around a Sun-like star. As pressure increases, the HZ becomes broader, with an increase of 0.25 AU in its radial extent from p = 1/3 to 3 bar. At low pressure, the habitability is low and varies with a; at high pressure, the habitability is high and relatively constant inside the HZ. We interpret these results in terms of the pressure dependence of the greenhouse effect, the efficiency of horizontal heat transport, and the extent of the liquid water temperature range. Within the limits discussed in the paper, the results can be extended to planets in eccentric orbits around non-solar-type stars. The main characteristics of the pressure-dependent HZ are modestly affected by variations of planetary properties, particularly at high pressure.

  13. THE HABITABLE ZONE OF EARTH-LIKE PLANETS WITH DIFFERENT LEVELS OF ATMOSPHERIC PRESSURE

    International Nuclear Information System (INIS)

    Vladilo, Giovanni; Murante, Giuseppe; Silva, Laura; Provenzale, Antonello; Ferri, Gaia; Ragazzini, Gregorio

    2013-01-01

    As a contribution to the study of the habitability of extrasolar planets, we implemented a one-dimensional energy balance model (EBM), the simplest seasonal model of planetary climate, with new prescriptions for most physical quantities. Here we apply our EBM to investigate the surface habitability of planets with an Earth-like atmospheric composition but different levels of surface pressure. The habitability, defined as the mean fraction of the planet's surface on which liquid water could exist, is estimated from the pressure-dependent liquid water temperature range, taking into account seasonal and latitudinal variations of surface temperature. By running several thousands of EBM simulations we generated a map of the habitable zone (HZ) in the plane of the orbital semi-major axis, a, and surface pressure, p, for planets in circular orbits around a Sun-like star. As pressure increases, the HZ becomes broader, with an increase of 0.25 AU in its radial extent from p = 1/3 to 3 bar. At low pressure, the habitability is low and varies with a; at high pressure, the habitability is high and relatively constant inside the HZ. We interpret these results in terms of the pressure dependence of the greenhouse effect, the efficiency of horizontal heat transport, and the extent of the liquid water temperature range. Within the limits discussed in the paper, the results can be extended to planets in eccentric orbits around non-solar-type stars. The main characteristics of the pressure-dependent HZ are modestly affected by variations of planetary properties, particularly at high pressure.

  14. System for keeping atmospheric pressure in nuclear facility and its peripheral equipments

    International Nuclear Information System (INIS)

    Matsumoto, Hatsuo

    1993-02-01

    The design to keep radioactive materials in the facility and not to make them spread inside the facility and into the environments is an essential issue in the construction of nuclear facilities. One reason of the contamination is due to the diffusion with air flow, therefore, negative pressure for the ambients has been utilized to keep gaseous radioactivities inside the facility of interest. The pressure difference is not so large, though, the atmospheric pressure level of the contaminated and possibly contaminated areas are always kept to be lower than those of the ambient one to prevent the dissemination of radioactivity from the defined area. The technique using negative pressure, at present, is employed widely in nuclear facilities, and the basic system is the same as that of JRR-1 built as the first nuclear facility in Japan. In the present work, the conventional system with negative pressure was reexamined on the sate-of-art of the regulations for the nuclear facilities, and consequently some shortages of the system has been found. Thus, an advanced system with an excellent performance keeping the negative pressure has been developed to cover the shortage. In this report, the new system is introduced with a couple of comments, acquired from the author's experience, to the design and the maintenance of the composite equipments of the system. (author)

  15. Blow-out of nonpremixed turbulent jet flames at sub-atmospheric pressures

    KAUST Repository

    Wang, Qiang; Hu, Longhua; Chung, Suk-Ho

    2016-01-01

    Blow-out limits of nonpremixed turbulent jet flames in quiescent air at sub-atmospheric pressures (50–100 kPa) were studied experimentally using propane fuel with nozzle diameters ranging 0.8–4 mm. Results showed that the fuel jet velocity at blow-out limit increased with increasing ambient pressure and nozzle diameter. A Damköhler (Da) number based model was adopted, defined as the ratio of characteristic mixing time and characteristic reaction time, to include the effect of pressure considering the variations in laminar burning velocity and thermal diffusivity with pressure. The critical lift-off height at blow-out, representing a characteristic length scale for mixing, had a linear relationship with the theoretically predicted stoichiometric location along the jet axis, which had a weak dependence on ambient pressure. The characteristic mixing time (critical lift-off height divided by jet velocity) adjusted to the characteristic reaction time such that the critical Damköhler at blow-out conditions maintained a constant value when varying the ambient pressure.

  16. Blow-out of nonpremixed turbulent jet flames at sub-atmospheric pressures

    KAUST Repository

    Wang, Qiang

    2016-12-09

    Blow-out limits of nonpremixed turbulent jet flames in quiescent air at sub-atmospheric pressures (50–100 kPa) were studied experimentally using propane fuel with nozzle diameters ranging 0.8–4 mm. Results showed that the fuel jet velocity at blow-out limit increased with increasing ambient pressure and nozzle diameter. A Damköhler (Da) number based model was adopted, defined as the ratio of characteristic mixing time and characteristic reaction time, to include the effect of pressure considering the variations in laminar burning velocity and thermal diffusivity with pressure. The critical lift-off height at blow-out, representing a characteristic length scale for mixing, had a linear relationship with the theoretically predicted stoichiometric location along the jet axis, which had a weak dependence on ambient pressure. The characteristic mixing time (critical lift-off height divided by jet velocity) adjusted to the characteristic reaction time such that the critical Damköhler at blow-out conditions maintained a constant value when varying the ambient pressure.

  17. Temperature diagnostics of a non-thermal plasma jet at atmospheric pressure

    Science.gov (United States)

    Schäfer, Jan

    2013-09-01

    The study reflects the concept of the temperature as a physical quantity resulting from the second thermodynamic law. The reliability of different approaches of the temperature diagnostics of open non-equilibrium systems is discussed using examples of low temperature atmospheric pressure discharges. The focus of this work is a miniaturized non-thermal atmospheric pressure plasma jet for local surface treatment at ambient atmosphere. The micro-discharge is driven with a capacitively coupled radio frequency electric field at 27.12 MHz and fed with argon at rates of about 1 slm through the capillary with an inner diameter of 4 mm. The discharge consists of several contracted filaments with diameter around 300 μm which are rotating azimuthally in the capillary in a self-organized manner. While the measured temperatures of the filament core exceed 700 K, the heat impact on a target below the plasma jet remains limited leading to target temperatures below 400 K. Different kinds of temperatures and energy transport processes are proposed and experimentally investigated. Nevertheless, a reliable and detailed temperature diagnostics is a challenge. We report on a novel diagnostics approach for the spatially and temporally resolved measurement of the gas temperature based on the optical properties of the plasma. Laser Schlieren Deflectometry is adapted to explore temperature profiles of filaments and their behaviour. In parallel, the method demonstrates a fundamental Fermat's principle of minimal energy. Information acquired with this method plays an important role for the optimization of local thin film deposition and surface functionalization by means of the atmospheric pressure plasma jet. The work was supported in part by the Deutsche Forschungsgemeinschaft within SFB-TR 24.

  18. Forced wave induced by an atmospheric pressure disturbance moving towards shore

    Science.gov (United States)

    Chen, Yixiang; Niu, Xiaojing

    2018-05-01

    Atmospheric pressure disturbances moving over a vast expanse of water can induce different wave patterns, which can be determined by the Froude number Fr. Generally, Fr = 1 is a critical value for the transformation of the wave pattern and the well-known Proudman resonance happens when Fr = 1. In this study, the forced wave induced by an atmospheric pressure disturbance moving over a constant slope from deep sea to shore is numerically investigated. The wave pattern evolves from a concentric-circle type into a triangular type with the increase of the Froude number, as the local water depth decreases, which is in accord with the analysis in the unbounded flat-bottom cases. However, a hysteresis effect has been observed, which implies the obvious amplification of the forced wave induced by a pressure disturbance can not be simply predicted by Fr = 1. The effects of the characteristic parameters of pressure disturbances and slope gradient have been discussed. The results show that it is not always possible to observe significant peak of the maximum water elevation before the landing of pressure disturbances, and a significant peak can be generated by a pressure disturbance with small spatial scale and fast moving velocity over a milder slope. Besides, an extremely high run-up occurs when the forced wave hits the shore, which is an essential threat to coastal security. The results also show that the maximum run-up is not monotonously varying with the increase of disturbance moving speed and spatial scale. There exists a most dangerous speed and scale which may cause disastrous nearshore surge.

  19. Airborne Lidar Measurements of Atmospheric Pressure Made Using the Oxygen A-Band

    Science.gov (United States)

    Riris, Haris; Rodriquez, Michael D.; Allan, Graham R.; Hasselbrack, William E.; Mao, Jianping; Stephen, Mark A.; Abshire, James B.

    2012-01-01

    Accurate measurements of greenhouse gas mixing ratios on a global scale are currently needed to gain a better understanding of climate change and its possible impact on our planet. In order to remotely measure greenhouse gas concentrations in the atmosphere with regard to dry air, the air number density in the atmosphere is also needed in deriving the greenhouse gas concentrations. Since oxygen is stable and uniformly mixed in the atmosphere at 20.95%, the measurement of an oxygen absorption in the atmosphere can be used to infer the dry air density and used to calculate the dry air mixing ratio of a greenhouse gas, such as carbon dioxide or methane. OUT technique of measuring Oxygen uses integrated path differential absorption (IPDA) with an Erbium Doped Fiber Amplifier (EDF A) laser system and single photon counting module (SPCM). It measures the absorbance of several on- and off-line wavelengths tuned to an O2 absorption line in the A-band at 764.7 nm. The choice of wavelengths allows us to maximize the pressure sensitivity using the trough between two absorptions in the Oxygen A-band. Our retrieval algorithm uses ancillary meteorological and aircraft altitude information to fit the experimentally obtained lidar O2 line shapes to a model atmosphere and derives the pressure from the profiles of the two lines. We have demonstrated O2 measurements from the ground and from an airborne platform. In this paper we will report on our airborne measurements during our 2011 campaign for the ASCENDS program.

  20. Dissecting Low Atmospheric Pressure Stress: Transcriptome Responses to the Components of Hypobaria in Arabidopsis.

    Science.gov (United States)

    Zhou, Mingqi; Callaham, Jordan B; Reyes, Matthew; Stasiak, Michael; Riva, Alberto; Zupanska, Agata K; Dixon, Mike A; Paul, Anna-Lisa; Ferl, Robert J

    2017-01-01

    Controlled hypobaria presents biology with an environment that is never encountered in terrestrial ecology, yet the apparent components of hypobaria are stresses typical of terrestrial ecosystems. High altitude, for example, presents terrestrial hypobaria always with hypoxia as a component stress, since the relative partial pressure of O 2 is constant in the atmosphere. Laboratory-controlled hypobaria, however, allows the dissection of pressure effects away from the effects typically associated with altitude, in particular hypoxia, as the partial pressure of O 2 can be varied. In this study, whole transcriptomes of plants grown in ambient (97 kPa/pO 2 = 21 kPa) atmospheric conditions were compared to those of plants transferred to five different atmospheres of varying pressure and oxygen composition for 24 h: 50 kPa/pO 2 = 10 kPa, 25 kPa/pO 2 = 5 kPa, 50 kPa/pO 2 = 21 kPa, 25 kPa/pO 2 = 21 kPa, or 97 kPa/pO 2 = 5 kPa. The plants exposed to these environments were 10 day old Arabidopsis seedlings grown vertically on hydrated nutrient plates. In addition, 5 day old plants were also exposed for 24 h to the 50 kPa and ambient environments to evaluate age-dependent responses. The gene expression profiles from roots and shoots showed that the hypobaric response contained more complex gene regulation than simple hypoxia, and that adding back oxygen to normoxic conditions did not completely alleviate gene expression changes in hypobaric responses.

  1. In situ glow discharge plasma electrolytic synthesis of reduced TiO2 for enhanced visible light photocatalysis

    Science.gov (United States)

    Feng, Guang; Wu, Botao; Qayyum Khan, Abdul; Zeng, Heping

    2018-05-01

    Reduced titanium dioxide (TiO2‑x) due to its extraordinary visible light absorption has been widely investigated in photodegradation and water splitting nowadays. However, conventional routes to synthesize reduced TiO2 usually demand multiple preparation steps, harsh controlled conditions or expensive facilities. Here we developed a single-step in situ approach to prepare the gray TiO2‑x nanoparticles (sub-10 nm) effectively by the glow discharge plasma electrolysis (GDPE) under atmospheric pressure. The co-existence of self-doped oxygen vacancies and Ti3+ in the generated TiO2‑x nanoparticles is demonstrated by electron paramagnetic resonance (EPR). The tunable ratio of bulk/surface defect can be realized by controlling the glow discharge power directly. It should be noticed that Ti3+ in the synthesized TiO2‑x are quite stable in ambient air. The UV–vis spectra of gray TiO2‑x show an enhanced visible light absorption, which leads to high visible-light photocatalytic activity. Moreover, the as-prepared TiO2‑x after 6 months storage still shows excellent stability during photocatalytic reactions. Owing to its simplicity and effectivity, this preparation method with GDPE should provide a large-scale production for TiO2‑x with high photoactivity.

  2. Etching of polymers, proteins and bacterial spores by atmospheric pressure DBD plasma in air

    Science.gov (United States)

    Kuzminova, A.; Kretková, T.; Kylián, O.; Hanuš, J.; Khalakhan, I.; Prukner, V.; Doležalová, E.; Šimek, M.; Biederman, H.

    2017-04-01

    Many studies proved that non-equilibrium discharges generated at atmospheric pressure are highly effective for the bio-decontamination of surfaces of various materials. One of the key processes that leads to a desired result is plasma etching and thus the evaluation of etching rates of organic materials is of high importance. However, the comparison of reported results is rather difficult if impossible as different authors use diverse sources of atmospheric plasma that are operated at significantly different operational parameters. Therefore, we report here on the systematic study of the etching of nine different common polymers that mimic the different structures of more complicated biological systems, bovine serum albumin (BSA) selected as the model protein and spores of Bacillus subtilis taken as a representative of highly resistant micro-organisms. The treatment of these materials was performed by means of atmospheric pressure dielectric barrier discharge (DBD) sustained in open air at constant conditions. All tested polymers, BSA and spores, were readily etched by DBD plasma. However, the measured etching rates were found to be dependent on the chemical structure of treated materials, namely on the presence of oxygen in the structure of polymers.

  3. Electron density measurement of non-equilibrium atmospheric pressure plasma using dispersion interferometer

    Science.gov (United States)

    Yoshimura, Shinji; Kasahara, Hiroshi; Akiyama, Tsuyoshi

    2017-10-01

    Medical applications of non-equilibrium atmospheric plasmas have recently been attracting a great deal of attention, where many types of plasma sources have been developed to meet the purposes. For example, plasma-activated medium (PAM), which is now being studied for cancer treatment, has been produced by irradiating non-equilibrium atmospheric pressure plasma with ultrahigh electron density to a culture medium. Meanwhile, in order to measure electron density in magnetic confinement plasmas, a CO2 laser dispersion interferometer has been developed and installed on the Large Helical Device (LHD) at the National Institute for Fusion Science, Japan. The dispersion interferometer has advantages that the measurement is insensitive to mechanical vibrations and changes in neutral gas density. Taking advantage of these properties, we applied the dispersion interferometer to electron density diagnostics of atmospheric pressure plasmas produced by the NU-Global HUMAP-WSAP-50 device, which is used for producing PAM. This study was supported by the Grant of Joint Research by the National Institutes of Natural Sciences (NINS).

  4. Blast from pressurized carbon dioxide released into a vented atmospheric chamber

    Science.gov (United States)

    Hansen, P. M.; Gaathaug, A. V.; Bjerketvedt, D.; Vaagsaether, K.

    2018-03-01

    This study describes the blast from pressurized carbon dioxide (CO2) released from a high-pressure reservoir into an openly vented atmospheric chamber. Small-scale experiments with pure vapor and liquid/vapor mixtures were conducted and compared with simulations. A motivation was to investigate the effects of vent size and liquid content on the peak overpressure and impulse response in the atmospheric chamber. The comparison of vapor-phase CO2 test results with simulations showed good agreement. This numerical code described single-phase gas dynamics inside a closed chamber, but did not model any phase transitions. Hence, the simulations described a vapor-only test into an unvented chamber. Nevertheless, the simulations reproduced the incident shock wave, the shock reflections, and the jet release inside the atmospheric chamber. The rapid phase transition did not contribute to the initial shock strength in the current test geometry. The evaporation rate was too low to contribute to the measured peak overpressure that was in the range of 15-20 kPa. The simulation results produced a calculated peak overpressure of 12 kPa. The liquid tests showed a significantly higher impulse compared to tests with pure vapor. Reducing the vent opening from 0.1 to 0.01 m2 resulted in a slightly higher impulse calculated at 100 ms. The influence of the vent area on the calculated impulse was significant in the vapor-phase tests, but not so clear in the liquid/vapor mixture tests.

  5. Diffuse plasma treatment of polyamide 66 fabric in atmospheric pressure air

    International Nuclear Information System (INIS)

    Li, Lee; Peng, Ming-yang; Teng, Yun; Gao, Guozhen

    2016-01-01

    Graphical abstract: - Highlights: • A cylindrical-electrode nanosecond-pulse diffuse-discharge reactor is presented. • Large-scale non-thermal plasmas were generated steadily in atmospheric air. • Treated PA66 fabric is etched with oxygen-containing group increases. • The hydrophily of treated PA66 fabric improves effectively. • Extending the treatment time is a method to reduce the treatment frequency. - Abstract: The polyamide 66 (PA66) fabrics are hard to be colored or glued in industrial production due to the poor hydrophily. Diffuse plasma is a kind of non-thermal plasma generated at atmospheric pressure in air. This paper proposes that large-scale diffuse plasma generated between wire electrodes can be employed for improving the hydrophily of PA66 fabrics. A repetitive nanosecond-pulse diffuse-discharge reactor using a cylindrical wire electrode configuration is presented, which can generate large-scale non-thermal plasmas steadily at atmospheric pressure without any barrier dielectric. Then the reactor is used to treat PA66 fabrics in different discharge conditions. The hydrophilicity property of modified PA66 is measured by wicking test method. The modified PA66 is also analyzed by atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS) to prove the surface changes in physical microstructure and chemical functional groups, respectively. What's more, the effects of treatment time and treatment frequency on surface modification are investigated and discussed.

  6. Experimental investigation on large-area dielectric barrier discharge in atmospheric nitrogen and air assisted by the ultraviolet lamp.

    Science.gov (United States)

    Zhang, Yan; Gu, Biao; Wang, Wenchun; Wang, Dezhen; Peng, Xuwen

    2009-04-01

    In this paper, ultraviolet radiation produced by the ultraviolet lamp is employed to supply pre-ionization for the dielectric barrier discharge in N(2) or air at atmospheric pressure. The effect of the ultraviolet pre-ionization on improving the uniformity of the dielectric barrier discharge is investigated experimentally. The atmospheric pressure glow discharge of the large area (270 mm x 120 mm) is obtained successfully via the ultraviolet pre-ionization in atmospheric DBD in N(2) when the gas gap decrease to 3mm. Based on the emission spectra, the mechanism which ultraviolet pre-ionization improves the uniformity of the dielectric barrier discharge is discussed.

  7. Evaporative crystallization of salts from Electrodialysis concentrated brine at atmospheric and subatmospheric pressures

    Science.gov (United States)

    Wang, Dong; Du, Wei; Cheng, Penggao; Tang, Na; Wang, Xuekui

    2018-02-01

    A large amount of concentrated brine was produced as by-product during the process of the electrodialysis seawater desalination. In this study, the crystallization sequences of different salts from the brine through evaporative crystallization at both atmospheric and subatmospheric pressures were investigated in detail. The profile of the boiling temperature with density and the relationship between the boiling temperature and the pressure were recorded. The combination of Powder X-Ray Diffraction and the polarizing microscope was employed to identify the salts in the solid form. It can be inferred that NaCl crystallized out firstly and then MgSO4·6H2O and CaSO4 precipitate in order at both atmospheric and subatmospheric pressures, and it should be noticed that CaSO4 crystallized as anhydrate at 70°C and 90°C while as dihydrate at 50°C. At the end of all the experiments the precipitation rates of CaSO4 and NaCl have reached to more than 95% while MgSO4 only reached to about 60%.

  8. Microplasma discharge vacuum ultraviolet photoionization source for atmospheric pressure ionization mass spectrometry.

    Science.gov (United States)

    Symonds, Joshua M; Gann, Reuben N; Fernández, Facundo M; Orlando, Thomas M

    2014-09-01

    In this paper, we demonstrate the first use of an atmospheric pressure microplasma-based vacuum ultraviolet (VUV) photoionization source in atmospheric pressure mass spectrometry applications. The device is a robust, easy-to-operate microhollow cathode discharge (MHCD) that enables generation of VUV photons from Ne and Ne/H(2) gas mixtures. Photons were detected by excitation of a microchannel plate detector and by analysis of diagnostic sample ions using a mass spectrometer. Reactive ions, charged particles, and metastables produced in the discharge were blocked from entering the ionization region by means of a lithium fluoride window, and photoionization was performed in a nitrogen-purged environment. By reducing the output pressure of the MHCD, we observed heightened production of higher-energy photons, making the photoionization source more effective. The initial performance of the MHCD VUV source has been evaluated by ionizing model analytes such as acetone, azulene, benzene, dimethylaniline, and glycine, which were introduced in solid or liquid phase. These molecules represent species with both high and low proton affinities, and ionization energies ranging from 7.12 to 9.7 eV.

  9. Atmospheric Pressure and Abdominal Aortic Aneurysm Rupture : Results from a Time Series Analysis and Case-Crossover Study

    NARCIS (Netherlands)

    Penning De Vries, Bas B.L.; Kolkert, Joé L.P.; Meerwaldt, Robbert; Groenwold, Rolf H.H.

    2017-01-01

    Background: Associations between atmospheric pressure and abdominal aortic aneurysm (AAA) rupture risk have been reported, but empirical evidence is inconclusive and largely derived from studies that did not account for possible nonlinearity, seasonality, and confounding by temperature. Methods:

  10. Sterilization and Decontamination of Surfaces Contaminated With Biological and Chemical Warfare Agents Using Atmospheric Pressure Plasma Discharges

    National Research Council Canada - National Science Library

    Garate, Eusebio

    1999-01-01

    ... based on the application of an atmospheric pressure plasma. We used both a DC corona and dielectric barrier discharge for the sterilization tests which were conducted on a variety of substrates including metals and chemically resistant fabrics...

  11. Atmospheric pressure photo ionization hydrogen/deuterium exchange mass spectrometry--a method to differentiate isomers by mass spectrometry.

    Science.gov (United States)

    Ahmed, Arif; Kim, Sunghwan

    2013-12-01

    In this report, a method for in-source hydrogen/deuterium (H/D) exchange at atmospheric pressure is reported. The method was named atmospheric pressure photo ionization hydrogen/deuterium exchange mass spectrometry (APPI HDX MS). H/D exchange was performed by mixing samples dissolved in toluene with CH3OD solvent and analyzing the mixture using atmospheric pressure photo ionization mass spectrometry (APPI-MS). The APPI HDX spectra obtained with contact times between the analyte solution and methanol-OD (CH3OD) of atmospheric pressure. H/D exchange can be performed in any laboratory with a mass spectrometer and a commercial APPI source. Using this method, multiple H/D exchanges of aromatic hydrogen and/or H/D exchange of active hydrogen were observed. These results demonstrated that H/D exchange can be used to distinguish between isomers containing primary, secondary, and tertiary amines, as well as pyridine and pyrrole functional groups.

  12. Facilitating breakdown in noble gases at near-atmospheric pressure using antennas

    Energy Technology Data Exchange (ETDEWEB)

    Sobota, A; Van Veldhuizen, E M; Haverlag, M [Eindhoven University of Technology, Department of Applied Physics, Postbus 513, 5600MB Eindhoven (Netherlands); Gendre, M F; Manders, F, E-mail: a.sobota@tue.nl [Philips Lighting, Mathildelaan 1, 5600JM Eindhoven (Netherlands)

    2011-04-20

    Electrical breakdown in near-atmospheric pressure noble gases requires voltages that are quite high, which is undesirable for a large number of possible applications. Metallic structures (antennas) were used on the outer side of the lamp burner to enhance the electric field locally while keeping the same potential difference across the electrodes. Optical and electrical measurements were performed in an argon or xenon atmosphere at 0.3 or 0.7 bar, with 4 or 7 mm between the electrode tips. We used rod-shaped tungsten electrodes of 0.6 mm in diameter. We found that both active and passive antennas facilitate breakdown, and we demonstrated the differences between the two types and their effects on the breakdown process.

  13. Facilitating breakdown in noble gases at near-atmospheric pressure using antennas

    International Nuclear Information System (INIS)

    Sobota, A; Van Veldhuizen, E M; Haverlag, M; Gendre, M F; Manders, F

    2011-01-01

    Electrical breakdown in near-atmospheric pressure noble gases requires voltages that are quite high, which is undesirable for a large number of possible applications. Metallic structures (antennas) were used on the outer side of the lamp burner to enhance the electric field locally while keeping the same potential difference across the electrodes. Optical and electrical measurements were performed in an argon or xenon atmosphere at 0.3 or 0.7 bar, with 4 or 7 mm between the electrode tips. We used rod-shaped tungsten electrodes of 0.6 mm in diameter. We found that both active and passive antennas facilitate breakdown, and we demonstrated the differences between the two types and their effects on the breakdown process.

  14. Preparation of carbon nanotubes by DC arc discharge process under reduced pressure in an air atmosphere

    International Nuclear Information System (INIS)

    Kim, Hyeon Hwan; Kim, Hyeong Joon

    2006-01-01

    Carbon nanotubes (CNTs) were grown using a DC arc discharge process in an air atmosphere and relevant process parameters were investigated. Without using an inert gas, multi walled carbon nanotubes could be synthesized in the deposit area of the cathode even in an air atmosphere, but single walled carbon nanotubes were not detected in the soot area despite using the same process conditions as in the inert gas. The air pressure for the highest yield of multi walled CNTs was 300 Torr. In addition, the quantity of amorphous carbon and other nanoparticles in the process chamber was remarkably reduced by this technique, showing that an efficient, feasible method of large scale CNT fabrication could be achieved by the arc discharge process

  15. Pressure and Humidity Measurements at the MSL Landing Site Supported by Modeling of the Atmospheric Conditions

    Science.gov (United States)

    Harri, A.; Savijarvi, H. I.; Schmidt, W.; Genzer, M.; Paton, M.; Kauhanen, J.; Atlaskin, E.; Polkko, J.; Kahanpaa, H.; Kemppinen, O.; Haukka, H.

    2012-12-01

    The Mars Science Laboratory (MSL) called Curiosity Rover landed safely on the Martian surface at the Gale crater on 6th August 2012. Among the MSL scientific objectives are investigations of the Martian environment that will be addressed by the Rover Environmental Monitoring Station (REMS) instrument. It will investigate habitability conditions at the Martian surface by performing a versatile set of environmental measurements including accurate observations of pressure and humidity of the Martian atmosphere. This paper describes the instrumental implementation of the MSL pressure and humidity measurement devices and briefly analyzes the atmospheric conditions at the Gale crater by modeling efforts using an atmospheric modeling tools. MSL humidity and pressure devices are based on proprietary technology of Vaisala, Inc. Humidity observations make use of Vaisala Humicap® relative humidity sensor heads and Vaisala Barocap® sensor heads are used for pressure observations. Vaisala Thermocap® temperature sensors heads are mounted in a close proximity of Humicap® and Barocap® sensor heads to enable accurate temperature measurements needed for interpretation of Humicap® and Barocap® readings. The sensor heads are capacitive. The pressure and humidity devices are lightweight and are based on a low-power transducer controlled by a dedicated ASIC. The transducer is designed to measure small capacitances in order of a few pF with resolution in order of 0.1fF (femtoFarad). The transducer design has a good spaceflight heritage, as it has been used in several previous missions, for example Mars mission Phoenix as well as the Cassini Huygens mission. The humidity device has overall dimensions of 40 x 25 x 55 mm. It weighs18 g, and consumes 15 mW of power. It includes 3 Humicap® sensor heads and 1 Thermocap®. The transducer electronics and the sensor heads are placed on a single multi-layer PCB protected by a metallic Faraday cage. The Humidity device has measurement range

  16. Influence of atmospheric pressure plasma treatment on surface properties of PBO fiber

    International Nuclear Information System (INIS)

    Zhang Ruiyun; Pan Xianlin; Jiang Muwen; Peng Shujing; Qiu Yiping

    2012-01-01

    Highlights: ► PBO fibers were treated with atmospheric pressure plasmas. ► When 1% of oxygen was added to the plasma, IFSS increased 130%. ► Increased moisture regain could enhance plasma treatment effect on improving IFSS with long treatment time. - Abstract: In order to improve the interfacial adhesion property between PBO fiber and epoxy, the surface modification effects of PBO fiber treated by atmospheric pressure plasma jet (APPJ) in different time, atmosphere and moisture regain (MR) were investigated. The fiber surface morphology, functional groups, surface wettability for control and plasma treated samples were analyzed by scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and water contact angle measurements, respectively. Meanwhile, the fiber interfacial shear strength (IFSS), representing adhesion property in epoxy, was tested using micro-bond pull-out test, and single fiber tensile strength was also tested to evaluate the mechanical performance loss of fibers caused by plasma treatment. The results indicated that the fiber surface was etched during the plasma treatments, the fiber surface wettability and the IFSS between fiber and epoxy had much improvement due to the increasing of surface energy after plasma treatment, the contact angle decreased with the treatment time increasing, and the IFSS was improved by about 130%. The processing atmosphere could influence IFSS significantly, and moisture regains (MR) of fibers also played a positive role on improving IFSS but not so markedly. XPS analysis showed that the oxygen content on fiber surface increased after treatment, and C=O, O-C=O groups were introduced on fiber surface. On the other hand, the observed loss of fiber tensile strength caused by plasma treatment was not so remarkable to affect the overall performance of composite materials.

  17. Hydrophobic and superhydrophobic surfaces fabricated using atmospheric pressure cold plasma technology: A review.

    Science.gov (United States)

    Dimitrakellis, Panagiotis; Gogolides, Evangelos

    2018-04-01

    Hydrophobic surfaces are often used to reduce wetting of surfaces by water. In particular, superhydrophobic surfaces are highly desired for several applications due to their exceptional properties such as self-cleaning, anti-icing, anti-friction and others. Such surfaces can be prepared via numerous methods including plasma technology, a dry technique with low environmental impact. Atmospheric pressure plasma (APP) has recently attracted significant attention as lower-cost alternative to low-pressure plasmas, and as a candidate for continuous rather than batch processing. Although there are many reviews on water-repellent surfaces, and a few reviews on APP technology, there are hardly any review works on APP processing for hydrophobic and superhydrohobic surface fabrication, a topic of high importance in nanotechnology and interface science. Herein, we critically review the advances on hydrophobic and superhydrophobic surface fabrication using APP technology, trying also to give some perspectives in the field. After a short introduction to superhydrophobicity of nanostructured surfaces and to APPs we focus this review on three different aspects: (1) The atmospheric plasma reactor technology used for fabrication of (super)hydrophobic surfaces. (2) The APP process for hydrophobic surface preparation. The hydrophobic surface preparation processes are categorized methodologically as: a) activation, b) grafting, c) polymerization, d) roughening and hydrophobization. Each category includes subcategories related to different precursors used. (3) One of the most important sections of this review concerns superhydrophobic surfaces fabricated using APP. These are methodologically characterized as follows: a) single step processes where micro-nano textured topography and low surface energy coating are created at the same time, or b) multiple step processes, where these steps occur sequentially in or out of the plasma. We end the review with some perspectives in the field. We

  18. Evaluation of the optimization space for atmospheric pressure photoionization (APPI) in comparison with APCI.

    Science.gov (United States)

    Fredenhagen, Andreas; Kühnöl, Jürgen

    2014-08-01

    The usefulness of atmospheric pressure photoionization (APPI) is difficult to evaluate for unknowns due to the fragmented literature. Specifically, the variation of dopants with a wide set of compounds or the use of APPI in the negative mode have rarely been explored. Thirty compounds were selected that were not suitable for ESI with a wide variety of functional groups and investigated with atmospheric pressure chemical ionization (APCI) and APPI in the positive and negative ion modes. The influence of the mobile phase (eluents containing acetonitrile or methanol) and--for APPI--four different dopants (acetone, chlorobenzene, toluene, and toluene/anisole) were explored. Stepwise variation of the organic mobile phase allowed to elucidate the ionization mechanism. Atmospheric pressure photoionization was especially useful for compounds, where the M(●+) and not the [M + H](+) was formed. The dopants chlorobenzene and anisole promoted the formation of molecular ions M(●+) for about half of the compounds, and its formation was also positively influenced by the use of mobile phases containing methanol. In the negative ion mode, APPI offered no advantage toward APCI. Best results were generally achieved with the dopant chlorobenzene, establishing that this dopant is suitable for a wide set of compounds. For one quarter of the compounds, significantly better results were achieved with mobile phases containing methanol for both APPI and APCI than those with acetonitrile, but only in the positive mode. With either of the methods--APPI or APCI--about 10% of the compounds were not detected. Strategies to get results quickly with difficult unknowns will be discussed. Copyright © 2014 John Wiley & Sons, Ltd.

  19. Reactive species in non-equilibrium atmospheric-pressure plasmas: Generation, transport, and biological effects

    Energy Technology Data Exchange (ETDEWEB)

    Lu, X., E-mail: luxinpei@hotmail.com [State Key Laboratory of Advanced Electromagnetic Engineering and Technology, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China); IFSA Collaborative Innovation Center, Shanghai Jiao Tong University, Shanghai 200240 (China); Naidis, G.V. [Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow 125412 (Russian Federation); Laroussi, M. [Plasma Engineering & Medicine Institute, Old Dominion University, Norfolk, VA 23529 (United States); Reuter, S. [Leibniz Institute for Plasma Science and Technology, Felix-Hausdorff-Strasse 2, 17489 Greifswald (Germany); Graves, D.B. [Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA 94720 (United States); Ostrikov, K. [Institute for Future Environments, Queensland University of Technology, Brisbane, QLD 4000 (Australia); School of Physics, Chemistry, and Mechanical Engineering, Queensland University of Technology, Brisbane, QLD 4000 (Australia); Commonwealth Scientific and Industrial Research Organization, P.O.Box 218, Lindfield, NSW 2070 (Australia); School of Physics, The University of Sydney, Sydney, NSW 2006 (Australia)

    2016-05-04

    Non-equilibrium atmospheric-pressure plasmas have recently become a topical area of research owing to their diverse applications in health care and medicine, environmental remediation and pollution control, materials processing, electrochemistry, nanotechnology and other fields. This review focuses on the reactive electrons and ionic, atomic, molecular, and radical species that are produced in these plasmas and then transported from the point of generation to the point of interaction with the material, medium, living cells or tissues being processed. The most important mechanisms of generation and transport of the key species in the plasmas of atmospheric-pressure plasma jets and other non-equilibrium atmospheric-pressure plasmas are introduced and examined from the viewpoint of their applications in plasma hygiene and medicine and other relevant fields. Sophisticated high-precision, time-resolved plasma diagnostics approaches and techniques are presented and their applications to monitor the reactive species and plasma dynamics in the plasma jets and other discharges, both in the gas phase and during the plasma interaction with liquid media, are critically reviewed. The large amount of experimental data is supported by the theoretical models of reactive species generation and transport in the plasmas, surrounding gaseous environments, and plasma interaction with liquid media. These models are presented and their limitations are discussed. Special attention is paid to biological effects of the plasma-generated reactive oxygen and nitrogen (and some other) species in basic biological processes such as cell metabolism, proliferation, survival, etc. as well as plasma applications in bacterial inactivation, wound healing, cancer treatment and some others. Challenges and opportunities for theoretical and experimental research are discussed and the authors’ vision for the emerging convergence trends across several disciplines and application domains is presented to

  20. Study on the reforming of alcohols in a surface wave discharge (SWD) at atmospheric pressure

    International Nuclear Information System (INIS)

    Jimenez, M; Yubero, C; Calzada, M D

    2008-01-01

    Surface wave plasma at atmospheric pressure has been used to produce the decomposition of the alcohol molecules introduced into it, in order to obtain hydrogen. Four alcohols, methanol, ethanol, propanol and butanol, have been used for this purpose. Optical emission spectroscopy was the tool used to analyse the radiation emitted by the plasma. Hydrogen atoms and other species such as C 2 and CH in alcohols have been detected but no CO molecular bands. Also, a mass spectrometer has been used in order to detect molecular hydrogen production in methanol decomposition

  1. Decontamination of a rotating cutting tool during operation by means of atmospheric pressure plasmas

    DEFF Research Database (Denmark)

    Leipold, Frank; Kusano, Yukihiro; Hansen, F.

    2010-01-01

    , is used for the experiments. A rotating knife was inoculated with L. innocua. The surface of the rotating knife was partly exposed to an atmospheric pressure dielectric barrier discharge operated in air, where the knife itself served as a ground electrode. The rotation of the knife ensures a treatment...... of the whole cutting tool. A log 5 reduction of L. innocua is obtained after 340 s of plasma operation. The temperature of the knife after treatment was found to be below 30 °C. The design of the setup allows a decontamination during slicing operation....

  2. Evaluation of Vapor Pressure Estimation Methods for Use in Simulating the Dynamic of Atmospheric Organic Aerosols

    Directory of Open Access Journals (Sweden)

    A. J. Komkoua Mbienda

    2013-01-01

    Lee and Kesler (LK, and Ambrose-Walton (AW methods for estimating vapor pressures ( are tested against experimental data for a set of volatile organic compounds (VOC. required to determine gas-particle partitioning of such organic compounds is used as a parameter for simulating the dynamic of atmospheric aerosols. Here, we use the structure-property relationships of VOC to estimate . The accuracy of each of the aforementioned methods is also assessed for each class of compounds (hydrocarbons, monofunctionalized, difunctionalized, and tri- and more functionalized volatile organic species. It is found that the best method for each VOC depends on its functionality.

  3. Atmospheric Pressure Plasma Jet as a Dry Alternative to Inkjet Printing in Flexible Electronics

    Science.gov (United States)

    Gandhiraman, Ram Prasad; Lopez, Arlene; Koehne, Jessica; Meyyappan, M.

    2016-01-01

    We have developed an atmospheric pressure plasma jet printing system that works at room temperature to 50 deg C unlike conventional aerosol assisted techniques which require a high temperature sintering step to obtain desired thin films. Multiple jets can be configured to increase throughput or to deposit multiple materials, and the jet(s) can be moved across large areas using a x-y stage. The plasma jet has been used to deposit carbon nanotubes, graphene, silver nanowires, copper nanoparticles and other materials on substrates such as paper, cotton, plastic and thin metal foils.

  4. Electric field measurement in an atmospheric or higher pressure gas by coherent Raman scattering of nitrogen

    International Nuclear Information System (INIS)

    Ito, Tsuyohito; Kobayashi, Kazunobu; Hamaguchi, Satoshi; Mueller, Sarah; Luggenhoelscher, Dirk; Czarnetzki, Uwe

    2009-01-01

    The feasibility of electric field measurement based on field-induced coherent Raman scattering is demonstrated for the first time in a nitrogen containing gas at atmospheric or higher pressure, including open air. The technique is especially useful for the determination of temporal and spatial profiles of the electric field in air-based microdischarges, where nitrogen is abundant. In our current experimental setup, the minimum detectable field strength in open air is about 100 V mm -1 , which is sufficiently small compared with the average field present in typical microdischarges. No further knowledge of other gas/plasma parameters such as the nitrogen density is required. (fast track communication)

  5. Role of secondary emission on discharge dynamics in an atmospheric pressure dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Tay, W. H.; Kausik, S. S.; Yap, S. L.; Wong, C. S., E-mail: cswong@um.edu.my [Plasma Technology Research Centre, Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2014-04-15

    The discharge dynamics in an atmospheric pressure dielectric barrier discharge (DBD) is studied in a DBD reactor consisting of a pair of stainless steel parallel plate electrodes. The DBD discharge has been generated by a 50 Hz ac high voltage power source. The high-speed intensified charge coupled device camera is used to capture the images of filaments occurring in the discharge gap. It is observed that frequent synchronous breakdown of micro discharges occurs across the discharge gap in the case of negative current pulse. The experimental results reveal that secondary emissions from the dielectric surface play a key role in the synchronous breakdown of plasma filaments.

  6. Spatial and temporal evolutions of ozone in a nanosecond pulse corona discharge at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Duten, X; Redolfi, M; Aggadi, N; Vega, A; Hassouni, K, E-mail: duten@lspm.cnrs.fr [LSPM-CNRS UPR 3407, Universite Paris Nord, 90 Avenue J.B. Clement, 93430 Villetaneuse (France)

    2011-10-19

    This paper deals with the experimental determination of the spatial and temporal evolutions of the ozone concentration in an atmospheric pressure pulsed plasma, working in the nanosecond regime. We observed that ozone was produced in the localized region of the streamer. The ozone transport requires a characteristic time well above the millisecond. The numerical modelling of the streamer expansion confirms that the hydrodynamic expansion of the filamentary discharge region during the streamer propagation does not lead to a significant transport of atomic oxygen and ozone. It appears therefore that only diffusional transport can take place, which requires a characteristic time of the order of 50 ms.

  7. Corona discharge secondary ionization of laser desorbed neutral molecules from a liquid matrix at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Turney, Kevin [Department of Chemistry, University of Florida, Gainesville, Florida 32611 (United States); Harrison, W.W. [Department of Chemistry, University of Florida, Gainesville, Florida 32611 (United States)]. E-mail: harrison@chem.ufl.edu

    2006-06-15

    Matrix assisted laser desorption/ionization (MALDI) is studied at atmospheric pressure using liquid sampling methods. A time-of-flight mass spectrometer couples to an open sample stage accessed by a UV laser for desorption and ionization. Also coupled to the sampling state is a corona discharge for auxiliary ionization of desorbed neutral molecules. The interaction of the laser desorption and corona ionization is studied for a range of desorption conditions, showing enhanced analyte ionization, but the effect is analytically advantageous only at low desorption rates. The effect of corona discharge voltage was also explored. The decoupling of neutral molecule formation and subsequent ionization provides an opportunity to study each process separately.

  8. Corona discharge secondary ionization of laser desorbed neutral molecules from a liquid matrix at atmospheric pressure

    International Nuclear Information System (INIS)

    Turney, Kevin; Harrison, W.W.

    2006-01-01

    Matrix assisted laser desorption/ionization (MALDI) is studied at atmospheric pressure using liquid sampling methods. A time-of-flight mass spectrometer couples to an open sample stage accessed by a UV laser for desorption and ionization. Also coupled to the sampling state is a corona discharge for auxiliary ionization of desorbed neutral molecules. The interaction of the laser desorption and corona ionization is studied for a range of desorption conditions, showing enhanced analyte ionization, but the effect is analytically advantageous only at low desorption rates. The effect of corona discharge voltage was also explored. The decoupling of neutral molecule formation and subsequent ionization provides an opportunity to study each process separately

  9. Determination of sulfonamides in meat by liquid chromatography coupled with atmospheric pressure chemical ionization mass spectrometry

    International Nuclear Information System (INIS)

    Kim, Dal Ho; Choi, Jong Oh; Kim, Jin Seog; Lee, Dai Woon

    2002-01-01

    Liquid chromatography/atmospheric pressure chemical ionization-mass spectrometry (LC-APCI-MS) has been used for the determination of sulfonamides in meat. Five typical sulfonamides were selected as target compounds, and beef meat was selected as a matrix sample. As internal standards, sulfapyridine and isotope labeled sulfamethazine ( 13 C 6 -SMZ) were used. Compared to the results of recent reports, our results have shown improved precision to a RSD of 1.8% for the determination of sulfamethazine spiked with 75 ng/g level in meat

  10. Spatial and temporal evolutions of ozone in a nanosecond pulse corona discharge at atmospheric pressure

    Science.gov (United States)

    Duten, X.; Redolfi, M.; Aggadi, N.; Vega, A.; Hassouni, K.

    2011-10-01

    This paper deals with the experimental determination of the spatial and temporal evolutions of the ozone concentration in an atmospheric pressure pulsed plasma, working in the nanosecond regime. We observed that ozone was produced in the localized region of the streamer. The ozone transport requires a characteristic time well above the millisecond. The numerical modelling of the streamer expansion confirms that the hydrodynamic expansion of the filamentary discharge region during the streamer propagation does not lead to a significant transport of atomic oxygen and ozone. It appears therefore that only diffusional transport can take place, which requires a characteristic time of the order of 50 ms.

  11. Spatial and temporal evolutions of ozone in a nanosecond pulse corona discharge at atmospheric pressure

    International Nuclear Information System (INIS)

    Duten, X; Redolfi, M; Aggadi, N; Vega, A; Hassouni, K

    2011-01-01

    This paper deals with the experimental determination of the spatial and temporal evolutions of the ozone concentration in an atmospheric pressure pulsed plasma, working in the nanosecond regime. We observed that ozone was produced in the localized region of the streamer. The ozone transport requires a characteristic time well above the millisecond. The numerical modelling of the streamer expansion confirms that the hydrodynamic expansion of the filamentary discharge region during the streamer propagation does not lead to a significant transport of atomic oxygen and ozone. It appears therefore that only diffusional transport can take place, which requires a characteristic time of the order of 50 ms.

  12. Synthesis and surface engineering of nanomaterials by atmospheric-pressure microplasmas

    Science.gov (United States)

    McKenna, J.; Patel, J.; Mitra, S.; Soin, N.; Švrček, V.; Maguire, P.; Mariotti, D.

    2011-11-01

    Two different atmospheric pressure microplasma systems are discussed and used for the synthesis and surface engineering of a range of nanomaterials. Specifically a gas-phase approach from vaporized tetramethylsilane has been used to synthesize silicon carbide nanoparticles with diameters below 10 nm. A different microplasma system that interfaces with a liquid solution has then been used for the synthesis of surfactant-free electrically stabilized gold nanoparticles with varying size. A similar microplasma-liquid system has been finally successfully used to tailor surface properties of silicon nanoparticles and to reduce graphene oxide into graphene. The synthesis and surface engineering mechanisms are also discussed.

  13. DNA damage in oral cancer cells induced by nitrogen atmospheric pressure plasma jets

    Energy Technology Data Exchange (ETDEWEB)

    Han, Xu; Ptasinska, Sylwia [Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556 (United States); Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States); Klas, Matej [Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556 (United States); Liu, Yueying [Harper Cancer Research Institute, University of Notre Dame, Notre Dame, Indiana 46556 (United States); Sharon Stack, M. [Harper Cancer Research Institute, University of Notre Dame, Notre Dame, Indiana 46556 (United States); Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

    2013-06-10

    The nitrogen atmospheric pressure plasma jet (APPJ) was applied to induce DNA damage of SCC-25 oral cancer cells. Optical emission spectra were taken to characterize the reactive species produced in APPJ. In order to explore the spatial distribution of plasma effects, cells were placed onto photo-etched grid slides and the antibody H2A.X was used to locate double strand breaks of DNA inside nuclei using an immunofluorescence assay. The number of cells with double strand breaks in DNA was observed to be varied due to the distance from the irradiation center and duration of plasma treatment.

  14. DNA damage in oral cancer cells induced by nitrogen atmospheric pressure plasma jets

    International Nuclear Information System (INIS)

    Han, Xu; Ptasinska, Sylwia; Klas, Matej; Liu, Yueying; Sharon Stack, M.

    2013-01-01

    The nitrogen atmospheric pressure plasma jet (APPJ) was applied to induce DNA damage of SCC-25 oral cancer cells. Optical emission spectra were taken to characterize the reactive species produced in APPJ. In order to explore the spatial distribution of plasma effects, cells were placed onto photo-etched grid slides and the antibody H2A.X was used to locate double strand breaks of DNA inside nuclei using an immunofluorescence assay. The number of cells with double strand breaks in DNA was observed to be varied due to the distance from the irradiation center and duration of plasma treatment.

  15. Rapid Atmospheric-Pressure-Plasma-Jet Processed Porous Materials for Energy Harvesting and Storage Devices

    Directory of Open Access Journals (Sweden)

    Jian-Zhang Chen

    2015-01-01

    Full Text Available Atmospheric pressure plasma jet (APPJ technology is a versatile technology that has been applied in many energy harvesting and storage devices. This feature article provides an overview of the advances in APPJ technology and its application to solar cells and batteries. The ultrafast APPJ sintering of nanoporous oxides and 3D reduced graphene oxide nanosheets with accompanying optical emission spectroscopy analyses are described in detail. The applications of these nanoporous materials to photoanodes and counter electrodes of dye-sensitized solar cells are described. An ultrashort treatment (1 min on graphite felt electrodes of flow batteries also significantly improves the energy efficiency.

  16. Atmospheric-Pressure Plasma Jet Surface Treatment for Use in Improving Adhesion

    Energy Technology Data Exchange (ETDEWEB)

    Kuettner, Lindsey Ann [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-09-06

    Atmospheric-pressure plasma jets (APPJs) are a method of plasma treatment that plays an important role in material processing and modifying surface properties of materials, especially polymers. Gas plasmas react with polymer surfaces in numerous ways such as oxidation, radical formation, degradation, and promotion of cross-linking. Because of this, gas and plasma conditions can be explored for chosen processes to maximize desired properties. The purpose of this study is to investigate plasma parameters in order to modify surface properties for improved adhesion between aluminum and epoxy substrates using two types of adhesives. The background, results to date, and future work will be discussed.

  17. New system for vacuum deposition of refractory materials using an atmospheric-pressure inductively coupled plasma

    International Nuclear Information System (INIS)

    Merkle, B.D.; Kniseley, R.N.; Schmidt, F.A.

    1987-01-01

    We have successfully developed a technique utilizing an atmospheric-pressure inductively coupled plasma combined with a low-pressure deposition chamber for deposition of thin films. The equipment and method of operation are discussed. Refractory powders (Nb and Y 2 O 3 ) were injected into the plasma and deposited as Nb and substoichiometric yttrium oxide, YO/sub 1.49/, onto Fe and Cu substrates. The substoichiometric yttrium oxide deposit adhered well to the Fe and Cu substrates, while the Nb deposit adhered well to the Fe only. The Nb deposit on the Cu substrate flaked and peeled probably because of stresses induced from the thermal expansion mismatch between the Nb and Cu. Further studies will be undertaken to better understand the processes occurring in this type of plasma-coating system in order to optimize the instrumental parameters for particular coating applications

  18. On atmospheric-pressure non-equilibrium plasma jets and plasma bullets

    International Nuclear Information System (INIS)

    Lu, X; Laroussi, M; Puech, V

    2012-01-01

    Atmospheric-pressure non-equilibrium plasma jets (APNP-Js), which generate plasma in open space rather than in a confined discharge gap, have recently been a topic of great interest. In this paper, the development of APNP-Js will be reviewed. Firstly, the APNP-Js are grouped based on the type of gas used to ignite them and their characteristics are discussed in detail. Secondly, one of the most interesting phenomena of APNP-Js, the ‘plasma bullet’, is discussed and its behavior described. Thirdly, the very recent developments on the behavior of plasma jets when launched in a controlled environment and pressure are also introduced. This is followed by a discussion on the interaction between plasma jets. Finally, perspectives on APNP-J research are presented. (paper)

  19. Parameters of the constricted plasma discharge produced by radio-frequency for atmospheric pressures

    International Nuclear Information System (INIS)

    Zambrano R, G.

    1987-01-01

    The main electrophysical characteristics of high-frequency discharge between two electrodes for pressures of the order of atmospheric pressure were investigated. The vibrational and kinetic temperatures of the discharge, and the possibilities for creating the conditions which using these type of discharge an instability between vibrational and kinetic temperatures can be obtained. For determining main characteristics of this type of discharge, argon gas, nitrogen gas and air, when oxygen and nitrogen are predominated, were used. The obtained electrical discharge parameters were: the high frequency voltage between electrocathodes, the current, the phase displacement between current and voltage, and the discharge power. The kinetic temperature distribution in the discharge region, and the vibrational temperature of the nitrogen molecules in discharge channel were also obtained. (M.C.K.) [pt

  20. An Atmospheric Pressure Plasma Setup to Investigate the Reactive Species Formation.

    Science.gov (United States)

    Gorbanev, Yury; Soriano, Robert; O'Connell, Deborah; Chechik, Victor

    2016-11-03

    Non-thermal atmospheric pressure ('cold') plasmas have received increased attention in recent years due to their significant biomedical potential. The reactions of cold plasma with the surrounding atmosphere yield a variety of reactive species, which can define its effectiveness. While efficient development of cold plasma therapy requires kinetic models, model benchmarking needs empirical data. Experimental studies of the source of reactive species detected in aqueous solutions exposed to plasma are still scarce. Biomedical plasma is often operated with He or Ar feed gas, and a specific interest lies in investigation of the reactive species generated by plasma with various gas admixtures (O2, N2, air, H2O vapor, etc.) Such investigations are very complex due to difficulties in controlling the ambient atmosphere in contact with the plasma effluent. In this work, we addressed common issues of 'high' voltage kHz frequency driven plasma jet experimental studies. A reactor was developed allowing the exclusion of ambient atmosphere from the plasma-liquid system. The system thus comprised the feed gas with admixtures and the components of the liquid sample. This controlled atmosphere allowed the investigation of the source of the reactive oxygen species induced in aqueous solutions by He-water vapor plasma. The use of isotopically labelled water allowed distinguishing between the species originating in the gas phase and those formed in the liquid. The plasma equipment was contained inside a Faraday cage to eliminate possible influence of any external field. The setup is versatile and can aid in further understanding the cold plasma-liquid interactions chemistry.