WorldWideScience

Sample records for alternative fuels production

  1. Alternative Fuels in Cement Production

    DEFF Research Database (Denmark)

    Larsen, Morten Boberg

    for the most significant alternative fuel energy contributors in the German cement industry. Solid alternative fuels are typically high in volatile content and they may differ significantly in physical and chemical properties compared to traditional solid fossil fuels. From the process point of view......The substitution of alternative for fossil fuels in cement production has increased significantly in the last decade. Of these new alternative fuels, solid state fuels presently account for the largest part, and in particular, meat and bone meal, plastics and tyre derived fuels (TDF) accounted......, considering a modern kiln system for cement production, the use of alternative fuels mainly influences 1) kiln process stability (may accelerate build up of blockages preventing gas and/or solids flow), 2) cement clinker quality, 3) emissions, and 4) decreased production capacity. Kiln process stability...

  2. Opportunities for Alternative Fuels Production

    Science.gov (United States)

    2011-05-05

    fuels derived from a mixture of coal and biomass. It is highly uncertain whether appreciable amounts of hydrotreated renewable oils can be...affordably and cleanly produced within the United States or abroad. Hydrotreated renewable oils are produced by processing animal fats or vegetable oils...possible source of oil for hydrotreatment. Fifty-fifty blends of hydrotreated oils have already been successfully demonstrated in flight tests sponsored by

  3. Alternative Fuels in Cement Production

    OpenAIRE

    2007-01-01

    Substitutionen af fossilt med alternativt brændsel i cement produktionen er steget betydeligt i den sidste dekade. Af disse nye alternative brændsler, udgør de faste brændsler p.t. den største andel, hvor kød- og benmel, plastic og dæk i særdeleshed har været de alternative brændsler der har bidraget med mest alternativ brændsels energi til den tyske cement industri. De nye alternative brændsler er typisk karakteriseret ved et højt indhold af flygtige bestanddele og adskiller sig typisk fra t...

  4. Production of jet fuel from alternative source

    Energy Technology Data Exchange (ETDEWEB)

    Eller, Zoltan; Papp, Anita; Hancsok, Jenoe [Pannonia Univ., Veszprem (Hungary). MOL Dept. of Hydrocarbon and Coal Processing

    2013-06-01

    Recent demands for low aromatic content jet fuels have shown significant increase in the last 20 years. This was generated by the growing of aviation. Furthermore, the quality requirements have become more aggravated for jet fuels. Nowadays reduced aromatic hydrocarbon fractions are necessary for the production of jet fuels with good burning properties, which contribute to less harmful material emission. In the recent past the properties of gasolines and diesel gas oils were continuously severed, and the properties of jet fuels will be more severe, too. Furthermore, it can become obligatory to blend alternative components into jet fuels. With the aromatic content reduction there is a possibility to produce high energy content jet fuels with the desirable properties. One of the possibilities is the blending of biocomponents from catalytic hydrogenation of triglycerides. Our aim was to study the possibilities of producing low sulphur and aromatic content jet fuels in a catalytic way. On a CoMo/Al{sub 2}O{sub 3} catalyst we studied the possibilities of quality improving of a kerosene fraction and coconut oil mixture depending on the change of the process parameters (temperature, pressure, liquid hourly space velocity, volume ratio). Based on the quality parameters of the liquid products we found that we made from the feedstock in the adequate technological conditions products which have a high smoke point (> 35 mm) and which have reduced aromatic content and high paraffin content (90%), so these are excellent jet fuels, and their stack gases damage the environment less. (orig.)

  5. Use of MRF residue as alternative fuel in cement production.

    Science.gov (United States)

    Fyffe, John R; Breckel, Alex C; Townsend, Aaron K; Webber, Michael E

    2016-01-01

    Single-stream recycling has helped divert millions of metric tons of waste from landfills in the U.S., where recycling rates for municipal solid waste are currently over 30%. However, material recovery facilities (MRFs) that sort the municipal recycled streams do not recover 100% of the incoming material. Consequently, they landfill between 5% and 15% of total processed material as residue. This residue is primarily composed of high-energy-content non-recycled plastics and fiber. One possible end-of-life solution for these energy-dense materials is to process the residue into Solid Recovered Fuel (SRF) that can be used as an alternative energy resource capable of replacing or supplementing fuel resources such as coal, natural gas, petroleum coke, or biomass in many industrial and power production processes. This report addresses the energetic and environmental benefits and trade-offs of converting non-recycled post-consumer plastics and fiber derived from MRF residue streams into SRF for use in a cement kiln. An experimental test burn of 118 Mg of SRF in the precalciner portion of the cement kiln was conducted. The SRF was a blend of 60% MRF residue and 40% post-industrial waste products producing an estimated 60% plastic and 40% fibrous material mixture. The SRF was fed into the kiln at 0.9 Mg/h for 24h and then 1.8 Mg/h for the following 48 h. The emissions data recorded in the experimental test burn were used to perform the life-cycle analysis portion of this study. The analysis included the following steps: transportation, landfill, processing and fuel combustion at the cement kiln. The energy use and emissions at each step is tracked for the two cases: (1) The Reference Case, where MRF residue is disposed of in a landfill and the cement kiln uses coal as its fuel source, and (2) The SRF Case, in which MRF residue is processed into SRF and used to offset some portion of coal use at the cement kiln. The experimental test burn and accompanying analysis indicate

  6. Determination of alternative fuels combustion products: Phase 3 report

    Energy Technology Data Exchange (ETDEWEB)

    Whitney, K.A. [Southwest Research Inst., San Antonio, TX (United States)

    1997-12-01

    This report describes the laboratory efforts to characterize particulate and gaseous exhaust emissions from a passenger vehicle operating on alternative fuels. Tests were conducted at room temperature (nominally 72 F) and 20 F utilizing the chassis dynamometer portion of the FTP for light-duty vehicles. Fuels evaluated include Federal RFG, LPG meeting HD-5 specifications, a national average blend of CNG, E85, and M85. Exhaust particulate generated at room temperature was further characterized to determine polynuclear aromatic content, trace element content, and trace organic constituents. For all fuels except M85, the room temperature particulate emission rate from this vehicle was about 2 to 3 mg/mile. On M85, the particulate emission rate was more than 6 mg/mile. In addition, elemental analysis of particulate revealed an order of magnitude more sulfur and calcium from M85 than any other fuel. The sulfur and calcium indicate that these higher emissions might be due to engine lubricating oil in the exhaust. For RFG, particulate emissions at 20 F were more than six times higher than at room temperature. For alcohol fuels, particulate emissions at 20 F were two to three times higher than at room temperature. For CNG and LPG, particulate emissions were virtually the same at 72 F and 20 F. However, PAH emissions from CNG and LPG were higher than expected. Both gaseous fuels had larger amounts of pyrene, 1-nitropyrene, and benzo(g,h,i)perylene in their emissions than the other fuels.

  7. Determination of alternative fuels combustion products: Phase 1 report

    Energy Technology Data Exchange (ETDEWEB)

    Whitney, K.A. [Southwest Research Inst., San Antonio, TX (United States)

    1997-09-01

    This report describes the laboratory effort to identify and quantify organic exhaust species generated from alternative-fueled light-duty vehicles operating over the Federal Test Procedure on compressed natural gas, liquefied petroleum gas, methanol, ethanol, and reformulated gasoline. The exhaust species from these vehicles were identified and quantified for fuel/air equivalence ratios of 0.8, 1.0, and 1.2, nominally, and were analyzed with and without a vehicle catalyst in place to determine the influence of a catalytic converter on species formation.

  8. Alternative Fuels: Research Progress

    Directory of Open Access Journals (Sweden)

    Maher A.R. Sadiq Al-Baghdadi

    2013-01-01

    Full Text Available Chapter 1: Pollutant Emissions and Combustion Characteristics of Biofuels and Biofuel/Diesel Blends in Laminar and Turbulent Gas Jet Flames. R. N. Parthasarathy, S. R. Gollahalli Chapter 2: Sustainable Routes for The Production of Oxygenated High-Energy Density Biofuels from Lignocellulosic Biomass. Juan A. Melero, Jose Iglesias, Gabriel Morales, Marta Paniagua Chapter 3: Optical Investigations of Alternative-Fuel Combustion in an HSDI Diesel Engine. T. Huelser, M. Jakob, G. Gruenefeld, P. Adomeit, S. Pischinger Chapter 4: An Insight into Biodiesel Physico-Chemical Properties and Exhaust Emissions Based on Statistical Elaboration of Experimental Data. Evangelos G. Giakoumis Chapter 5: Biodiesel: A Promising Alternative Energy Resource. A.E. Atabani Chapter 6: Alternative Fuels for Internal Combustion Engines: An Overview of the Current Research. Ahmed A. Taha, Tarek M. Abdel-Salam, Madhu Vellakal Chapter 7: Investigating the Hydrogen-Natural Gas Blends as a Fuel in Internal Combustion Engine. ?lker YILMAZ Chapter 8: Conversion of Bus Diesel Engine into LPG Gaseous Engine; Method and Experiments Validation. M. A. Jemni , G. Kantchev , Z. Driss , R. Saaidia , M. S. Abid Chapter 9: Predicting the Combustion Performance of Different Vegetable Oils-Derived Biodiesel Fuels. Qing Shu, ChangLin Yu Chapter 10: Production of Gasoline, Naphtha, Kerosene, Diesel, and Fuel Oil Range Fuels from Polypropylene and Polystyrene Waste Plastics Mixture by Two-Stage Catalytic Degradation using ZnO. Moinuddin Sarker, Mohammad Mamunor Rashid

  9. Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

    1992-08-01

    The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R&D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

  10. Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

    1992-08-01

    The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

  11. Prospects of Biodiesel Production from Macadamia Oil as an Alternative Fuel for Diesel Engines

    Directory of Open Access Journals (Sweden)

    Md Mofijur Rahman

    2016-05-01

    Full Text Available This paper investigated the prospects of biodiesel production from macadamia oil as an alternative fuel for diesel engine. The biodiesel was produced using conventional transesterification process using the base catalyst (KOH. A multi-cylinder diesel engine was used to evaluate the performance and emission of 5% (B5 and 20% (B20 macadamia biodiesel fuel at different engine speeds and full load condition. It was found that the characteristics of biodiesel are within the limit of specified standards American Society for Testing and Materials (ASTM D6751 and comparable to diesel fuel. This study also found that the blending of macadamia biodiesel–diesel fuel significantly improves the fuel properties including viscosity, density (D, heating value and oxidation stability (OS. Engine performance results indicated that macadamia biodiesel fuel sample reduces brake power (BP and increases brake-specific fuel consumption (BSFC while emission results indicated that it reduces the average carbon monoxide (CO, hydrocarbons (HC and particulate matter (PM emissions except nitrogen oxides (NOx than diesel fuel. Finally, it can be concluded that macadamia oil can be a possible source for biodiesel production and up to 20% macadamia biodiesel can be used as a fuel in diesel engines without modifications.

  12. Water consumption footprint and land requirements of large-scale alternative diesel and jet fuel production.

    Science.gov (United States)

    Staples, Mark D; Olcay, Hakan; Malina, Robert; Trivedi, Parthsarathi; Pearlson, Matthew N; Strzepek, Kenneth; Paltsev, Sergey V; Wollersheim, Christoph; Barrett, Steven R H

    2013-01-01

    Middle distillate (MD) transportation fuels, including diesel and jet fuel, make up almost 30% of liquid fuel consumption in the United States. Alternative drop-in MD and biodiesel could potentially reduce dependence on crude oil and the greenhouse gas intensity of transportation. However, the water and land resource requirements of these novel fuel production technologies must be better understood. This analysis quantifies the lifecycle green and blue water consumption footprints of producing: MD from conventional crude oil; Fischer-Tropsch MD from natural gas and coal; fermentation and advanced fermentation MD from biomass; and hydroprocessed esters and fatty acids MD and biodiesel from oilseed crops, throughout the contiguous United States. We find that FT MD and alternative MD derived from rainfed biomass have lifecycle blue water consumption footprints of 1.6 to 20.1 Lwater/LMD, comparable to conventional MD, which ranges between 4.1 and 7.4 Lwater/LMD. Alternative MD derived from irrigated biomass has a lifecycle blue water consumption footprint potentially several orders of magnitude larger, between 2.7 and 22 600 Lwater/LMD. Alternative MD derived from biomass has a lifecycle green water consumption footprint between 1.1 and 19 200 Lwater/LMD. Results are disaggregated to characterize the relationship between geo-spatial location and lifecycle water consumption footprint. We also quantify the trade-offs between blue water consumption footprint and areal MD productivity, which ranges from 490 to 4200 LMD/ha, under assumptions of rainfed and irrigated biomass cultivation. Finally, we show that if biomass cultivation for alternative MD is irrigated, the ratio of the increase in areal MD productivity to the increase in blue water consumption footprint is a function of geo-spatial location and feedstock-to-fuel production pathway.

  13. Alternative Fuels Data Center

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-06-01

    Fact sheet describes the Alternative Fuels Data Center, which provides information, data, and tools to help fleets and other transportation decision makers find ways to reduce petroleum consumption through the use of alternative and renewable fuels, advanced vehicles, and other fuel-saving measures.

  14. Production Costs of Alternative Transportation Fuels. Influence of Crude Oil Price and Technology Maturity

    Energy Technology Data Exchange (ETDEWEB)

    Cazzola, Pierpaolo; Morrison, Geoff; Kaneko, Hiroyuki; Cuenot, Francois; Ghandi, Abbas; Fulton, Lewis

    2013-07-01

    This study examines the production costs of a range of transport fuels and energy carriers under varying crude oil price assumptions and technology market maturation levels. An engineering ''bottom-up'' approach is used to estimate the effect of the input cost of oil and of various technological assumptions on the finished price of these fuels. In total, the production costs of 20 fuels are examined for crude oil prices between USD 60 and USD 150 per barrel. Some fuel pathways can be competitive with oil as their production, transport and storage technology matures, and as oil price increases. Rising oil prices will offer new opportunities to switch to alternative fuels for transport, to diversify the energy mix of the transport sector, and to reduce the exposure of the whole system to price volatility and potential distuption of supply. In a time of uncertainty about the leading vehicle technology to decarbonize the transport sector, looking at the fuel cost brings key information to be considered to keep mobility affordable yet sustainable.

  15. Fuel cells are a commercially viable alternative for the production of "clean" energy.

    Science.gov (United States)

    Niakolas, Dimitris K; Daletou, Maria; Neophytides, Stylianos G; Vayenas, Constantinos G

    2016-01-01

    Fuel cells present a highly efficient and environmentally friendly alternative technology for decentralized energy production. The scope of the present study is to provide an overview of the technological and commercialization readiness level of fuel cells. Specifically, there is a brief description of their general advantages and weaknesses in correlation with various technological actions and political strategies, which are adopted towards their proper positioning in the global market. Some of the most important key performance indicators are also discussed, alongside with a few examples of broad commercialization. It is concluded that the increasing number of companies which utilize and invest on this technology, in combination with the supply chain improvements and the concomitant technological maturity and recognition, reinforce the fuel cell industry so as to become well-aligned for global success.

  16. Alternate fuels; Combustibles alternos

    Energy Technology Data Exchange (ETDEWEB)

    Romero Paredes R, Hernando; Ambriz G, Juan Jose [Universidad Autonoma Metropolitana. Iztapalapa (Mexico)

    2003-07-01

    In the definition and description of alternate fuels we must center ourselves in those technological alternatives that allow to obtain compounds that differ from the traditional ones, in their forms to be obtained. In this article it is tried to give an overview of alternate fuels to the conventional derivatives of petroleum and that allow to have a clear idea on the tendencies of modern investigation and the technological developments that can be implemented in the short term. It is not pretended to include all the tendencies and developments of the present world, but those that can hit in a relatively short term, in accordance with agreed with the average life of conventional fuels. Nevertheless, most of the conversion principles are applicable to the spectrum of carbonaceous or cellulosic materials which are in nature, are cultivated or wastes of organic origin. Thus one will approach them in a successive way, the physical, chemical and biological conversions that can take place in a production process of an alternate fuel or the same direct use of the fuel such as burning the sweepings derived from the forests. [Spanish] En la definicion y descripcion de combustibles alternos nos debemos centrar en aquellas alternativas tecnologicas que permitan obtener compuestos que difieren de los tradicionales, al menos en sus formas de ser obtenidos. En este articulo se pretende dar un panorama de los combustibles alternos a los convencionales derivados del petroleo y que permita tener una idea clara sobre las tendencias de la investigacion moderna y los desarrollos tecnologicos que puedan ser implementados en el corto plazo. No se pretende abarcar todas las tendencias y desarrollos del mundo actual, sino aquellas que pueden impactar en un plazo relativamente corto, acordes con la vida media de los combustibles convencionales. Sin embargo, la mayor parte de los principios de conversion son aplicables al espectro de materiales carbonaceos o celulosicos los cuales se

  17. Selection and properties of alternative forming fluids for TRISO fuel kernel production

    Science.gov (United States)

    Baker, M. P.; King, J. C.; Gorman, B. P.; Marshall, D. W.

    2013-01-01

    Current Very High Temperature Reactor (VHTR) designs incorporate TRi-structural ISOtropic (TRISO) fuel, which consists of a spherical fissile fuel kernel surrounded by layers of pyrolytic carbon and silicon carbide. An internal sol-gel process forms the fuel kernel using wet chemistry to produce uranium oxyhydroxide gel spheres by dropping a cold precursor solution into a hot column of trichloroethylene (TCE). Over time, gelation byproducts inhibit complete gelation, and the TCE must be purified or discarded. The resulting TCE waste stream contains both radioactive and hazardous materials and is thus considered a mixed hazardous waste. Changing the forming fluid to a non-hazardous alternative could greatly improve the economics of TRISO fuel kernel production. Selection criteria for a replacement forming fluid narrowed a list of ˜10,800 chemicals to yield ten potential replacement forming fluids: 1-bromododecane, 1-bromotetradecane, 1-bromoundecane, 1-chlorooctadecane, 1-chlorotetradecane, 1-iododecane, 1-iodododecane, 1-iodohexadecane, 1-iodooctadecane, and squalane. The density, viscosity, and surface tension for each potential replacement forming fluid were measured as a function of temperature between 25 °C and 80 °C. Calculated settling velocities and heat transfer rates give an overall column height approximation. 1-bromotetradecane, 1-chlorooctadecane, and 1-iodododecane show the greatest promise as replacements, and future tests will verify their ability to form satisfactory fuel kernels.

  18. Selection and properties of alternative forming fluids for TRISO fuel kernel production

    Energy Technology Data Exchange (ETDEWEB)

    Baker, M. P. [Colorado School of Mines, Golden, CO (United States); King, J. C. [Colorado School of Mines, Golden, CO (United States); Gorman, B. P. [Colorado School of Mines, Golden, CO (United States); Marshall, Doug W. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2013-01-01

    Current Very High Temperature Reactor (VHTR) designs incorporate TRi-structural ISOtropic (TRISO) fuel, which consists of a spherical fissile fuel kernel surrounded by layers of pyrolytic carbon and silicon carbide. An internal sol-gel process forms the fuel kernel using wet chemistry to produce uranium oxyhydroxide gel spheres by dropping a cold precursor solution into a hot column of trichloroethylene (TCE). Over time, gelation byproducts inhibit complete gelation, and the TCE must be purified or discarded. The resulting TCE waste stream contains both radioactive and hazardous materials and is thus considered a mixed hazardous waste. Changing the forming fluid to a non-hazardous alternative could greatly improve the economics of TRISO fuel kernel production. Selection criteria for a replacement forming fluid narrowed a list of ~10,800 chemicals to yield ten potential replacement forming fluids: 1-bromododecane, 1- bromotetradecane, 1-bromoundecane, 1-chlorooctadecane, 1-chlorotetradecane, 1-iododecane, 1-iodododecane, 1-iodohexadecane, 1-iodooctadecane, and squalane. The density, viscosity, and surface tension for each potential replacement forming fluid were measured as a function of temperature between 25 °C and 80 °C. Calculated settling velocities and heat transfer rates give an overall column height approximation. 1-bromotetradecane, 1-chlorooctadecane, and 1-iodododecane show the greatest promise as replacements, and future tests will verify their ability to form satisfactory fuel kernels.

  19. Alternative fuel information sources

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    This short document contains a list of more than 200 US sources of information (Name, address, phone number, and sometimes contact) related to the use of alternative fuels in automobiles and trucks. Electric-powered cars are also included.

  20. An alternative feedstock of corn meal for industrial fuel ethanol production: delignified corncob residue.

    Science.gov (United States)

    Lei, Cheng; Zhang, Jian; Xiao, Lin; Bao, Jie

    2014-09-01

    Delignified corncob residue is an industrial solid waste from xylose production using corncob as feedstock. In this study, delignified corncob residue was used as the feedstock of ethanol production by simultaneous saccharification and fermentation (SSF) and the optimal fermentation performance was investigated under various operation conditions. The ethanol titer and yield reached 75.07 g/L and 89.38%, respectively, using a regular industrial yeast strain at moderate cellulase dosage and high solids loading. A uniform SSF temperature of 37°C at both prehydrolysis and SSF stages was tested. The fermentation performance and cost of delignified corncob residue and corn meal was compared as feedstock of ethanol fermentation. The result shows that the delignified corncob residue is competitive to corn meal as ethanol production feedstock. The study gives a typical case to demonstrate the potential of intensively processed lignocellulose as the alternative feedstock of corn meal for industrial fuel ethanol production.

  1. Selection and properties of alternative forming fluids for TRISO fuel kernel production

    Energy Technology Data Exchange (ETDEWEB)

    Baker, M.P. [Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); King, J.C., E-mail: kingjc@mines.edu [Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Gorman, B.P. [Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Marshall, D.W. [Idaho National Laboratory, 2525 N. Fremont Avenue, P.O. Box 1625, Idaho Falls, ID 83415 (United States)

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer Forming fluid selection criteria developed for TRISO kernel production. Black-Right-Pointing-Pointer Ten candidates selected for further study. Black-Right-Pointing-Pointer Density, viscosity, and surface tension measured for first time. Black-Right-Pointing-Pointer Settling velocity and heat transfer rates calculated. Black-Right-Pointing-Pointer Three fluids recommended for kernel production testing. - Abstract: Current Very High Temperature Reactor (VHTR) designs incorporate TRi-structural ISOtropic (TRISO) fuel, which consists of a spherical fissile fuel kernel surrounded by layers of pyrolytic carbon and silicon carbide. An internal sol-gel process forms the fuel kernel using wet chemistry to produce uranium oxyhydroxide gel spheres by dropping a cold precursor solution into a hot column of trichloroethylene (TCE). Over time, gelation byproducts inhibit complete gelation, and the TCE must be purified or discarded. The resulting TCE waste stream contains both radioactive and hazardous materials and is thus considered a mixed hazardous waste. Changing the forming fluid to a non-hazardous alternative could greatly improve the economics of TRISO fuel kernel production. Selection criteria for a replacement forming fluid narrowed a list of {approx}10,800 chemicals to yield ten potential replacement forming fluids: 1-bromododecane, 1-bromotetradecane, 1-bromoundecane, 1-chlorooctadecane, 1-chlorotetradecane, 1-iododecane, 1-iodododecane, 1-iodohexadecane, 1-iodooctadecane, and squalane. The density, viscosity, and surface tension for each potential replacement forming fluid were measured as a function of temperature between 25 Degree-Sign C and 80 Degree-Sign C. Calculated settling velocities and heat transfer rates give an overall column height approximation. 1-bromotetradecane, 1-chlorooctadecane, and 1-iodododecane show the greatest promise as replacements, and future tests will verify their ability to form satisfactory

  2. Outlook for alternative transportation fuels

    Energy Technology Data Exchange (ETDEWEB)

    Gushee, D.E. [Univ. of Illinois, Chicago, IL (United States)

    1996-12-31

    This presentation provides a brief review of regulatory issues and Federal programs regarding alternative fuel use in automobiles. A number of U.S. DOE initiatives and studies aimed at increasing alternative fuels are outlined, and tax incentives in effect at the state and Federal levels are discussed. Data on alternative fuel consumption and alternative fuel vehicle use are also presented. Despite mandates, tax incentives, and programs, it is concluded alternative fuels will have minimal market penetration. 7 refs., 5 tabs.

  3. Biomass pyrolysis: use of some agricultural wastes for alternative fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Kimura, Lygia Maestri; Santos, Larissa Cardoso; Vieira, Paula Fraga; Parreira, Priciane Martins; Henrique, Humberto Molinar, E-mail: lygiamk@gmail.com, E-mail: larinha_cardoso@yahoo.com.br, E-mail: paulavieira88@gmail.com, E-mail: priciane.mp@bol.com.br, E-mail: humberto@ufu.br [Universidade Federal de Uberlandia (UFU), MG (Brazil). Faculdade de Engenharia Quimica

    2009-07-01

    The use of biomass for energy generation has aroused great attention and interest because of the global climate changes, environmental pollution and reduction of availability of fossil energy. This study deals with pyrolysis of four agricultural wastes (sawdust, sugarcane straw, chicken litter and cashew nut shell) in a fixed bed pyrolytic reactor. The yields of char, liquid and gas were quantified at 300, 400, 500, 600 and 700 deg C and the temperature and pressure effects were investigated. Pyrolytic liquids produced were separated into aqueous and oil phases. XRF spectroscopy was used for qualitative and quantitative elemental analysis of the liquids and solids produced at whole temperature range. Calorific value analysis of liquids and solids were also performed for energy content evaluation. Experimental results showed sawdust, sugarcane straw and cashew nut waste have very good potential for using in pyrolysis process for alternative fuel production. (author)

  4. The effect of alternative fuel combustion in the cement kiln main burner on production capacity and improvement with oxygen enrichment.

    OpenAIRE

    Ariyaratne, W.K.Hiromi; Melaaen, Morten Christian; Tokheim, Lars-André

    2013-01-01

    A mathematical model based on a mass and energy balance for the combustion in a cement rotary kiln was developed. The model was used to investigate the impact of replacing about 45 % of the primary coal energy by different alternative fuels. Refuse derived fuel, waste wood, solid hazardous waste and liquid hazardous waste were used in the modeling. The results showed that in order to keep the kiln temperature unchanged, and thereby maintain the required clinker quality, the production capa...

  5. Transportation Energy Futures Series: Alternative Fuel Infrastructure Expansion: Costs, Resources, Production Capacity, and Retail Availability for Low-Carbon Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Melaina, W. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Heath, Garvin [National Renewable Energy Lab. (NREL), Golden, CO (United States); Sandor, Debra [National Renewable Energy Lab. (NREL), Golden, CO (United States); Steward, Darlene [National Renewable Energy Lab. (NREL), Golden, CO (United States); Vimmerstedt, Laura [National Renewable Energy Lab. (NREL), Golden, CO (United States); Warner, Ethan [National Renewable Energy Lab. (NREL), Golden, CO (United States); Webster, Karen W. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2013-04-01

    The petroleum-based transportation fuel system is complex and highly developed, in contrast to the nascent low-petroleum, low-carbon alternative fuel system. This report examines how expansion of the low-carbon transportation fuel infrastructure could contribute to deep reductions in petroleum use and greenhouse gas (GHG) emissions across the U.S. transportation sector. Three low-carbon scenarios, each using a different combination of low-carbon fuels, were developed to explore infrastructure expansion trends consistent with a study goal of reducing transportation sector GHG emissions to 80% less than 2005 levels by 2050.These scenarios were compared to a business-as-usual (BAU) scenario and were evaluated with respect to four criteria: fuel cost estimates, resource availability, fuel production capacity expansion, and retail infrastructure expansion.

  6. NASA Alternative Aviation Fuel Research

    Science.gov (United States)

    Anderson, B. E.; Beyersdorf, A. J.; Thornhill, K. L., II; Moore, R.; Shook, M.; Winstead, E.; Ziemba, L. D.; Crumeyrolle, S.

    2015-12-01

    We present an overview of research conducted by NASA Aeronautics Research Mission Directorate to evaluate the performance and emissions of "drop-in" alternative jet fuels, highlighting experiment design and results from the Alternative Aviation Fuel Experiments (AAFEX-I & -II) and Alternative Fuel-Effects on Contrails and Cruise Emissions flight series (ACCESS-I & II). These projects included almost 100 hours of sampling exhaust emissions from the NASA DC-8 aircraft in both ground and airborne operation and at idle to takeoff thrust settings. Tested fuels included Fischer-Tropsch (FT) synthetic kerosenes manufactured from coal and natural-gas feedstocks; Hydro-treated Esters and Fatty-Acids (HEFA) fuels made from beef-tallow and camelina-plant oil; and 50:50 blends of these alternative fuels with Jet A. Experiments were also conducted with FT and Jet A fuels doped with tetrahydrothiophene to examine the effects of fuel sulfur on volatile aerosol and contrail formation and microphysical properties. Results indicate that although the absence of aromatic compounds in the alternative fuels caused DC-8 fuel-system leaks, the fuels did not compromise engine performance or combustion efficiency. And whereas the alternative fuels produced only slightly different gas-phase emissions, dramatic reductions in non-volatile particulate matter (nvPM) emissions were observed when burning the pure alternative fuels, particularly at low thrust settings where particle number and mass emissions were an order of magnitude lower than measured from standard jet fuel combustion; 50:50 blends of Jet A and alternative fuels typically reduced nvPM emissions by ~50% across all thrust settings. Alternative fuels with the highest hydrogen content produced the greatest nvPM reductions. For Jet A and fuel blends, nvPM emissions were positively correlated with fuel aromatic and naphthalene content. Fuel sulfur content regulated nucleation mode aerosol number and mass concentrations within aging

  7. Alternatives to traditional transportation fuels 1993

    Energy Technology Data Exchange (ETDEWEB)

    1995-01-01

    In recent years, gasoline and diesel fuel have accounted for about 80 percent of total transportation fuel and nearly all of the fuel used in on-road vehicles. Growing concerns about the environmental effects of fossil fuel use and the Nation`s high level of dependence on foreign oil are providing impetus for the development of replacements or alternatives for these traditional transportation fuels. (The Energy Policy Act of 1992 definitions of {open_quotes}replacement{close_quotes} and {open_quotes}alternative{close_quotes} fuels are presented in the following box.) The Alternative Motor Fuels Act of 1988, the Clean Air Act Amendments of 1990 (CAAA90) and the Energy Policy Act of 1992 (EPACT) are significant legislative forces behind the growth of replacement fuel use. Alternatives to Traditional Transportation Fuels 1993 provides the number of on-road alternative fueled vehicles in use in the United States, alternative and replacement fuel consumption, and information on greenhouse gas emissions resulting from the production, delivery, and use of replacement fuels for 1992, 1993, and 1995.

  8. Alternative Fuels (Briefing Charts)

    Science.gov (United States)

    2009-06-19

    SASOL Jet Fuel Qatar GTL Syntroleum Jet fuel in B-52 Nigeria GTL China Coal GTL Shell Bintulu GTL Cellulose ethanol for ground use Ocean Bio...Bintulu GTL Ocean Bio-fuel Factories Bio-butanol for ground use Future Energy Source Resurgence in Nuclear Power Bio-jet tests done ASTM Spec...High energy deoxygenated bio-jet fuel from algae PSU coal derived JP-8 B-52 emissions Scoping study HBR TF emissions New bio- fuel impacts Adv

  9. Alternative motor fuels today and tomorrow

    Energy Technology Data Exchange (ETDEWEB)

    Bensaid, B

    2004-07-01

    Today, petroleum products account for 97% of the energy consumed in road transport. The purpose of replacing these products with alternative energies is to reduce oil dependence as well as greenhouse gas emissions. The high price of oil has promoted the use of 'conventional' alternative motor fuels (biofuels, LPG, NGV) and also renewed interest in syn-fuels (GTL, CTL, BTL) that have already given rise to industrial and pilot projects. (author)

  10. Spent-fuel-storage alternatives

    Energy Technology Data Exchange (ETDEWEB)

    1980-01-01

    The Spent Fuel Storage Alternatives meeting was a technical forum in which 37 experts from 12 states discussed storage alternatives that are available or are under development. The subject matter was divided into the following five areas: techniques for increasing fuel storage density; dry storage of spent fuel; fuel characterization and conditioning; fuel storage operating experience; and storage and transport economics. Nineteen of the 21 papers which were presented at this meeting are included in this Proceedings. These have been abstracted and indexed. (ATT)

  11. Life Cycle Assessment of Miscanthus as a Fuel Alternative in District Heat Production

    DEFF Research Database (Denmark)

    Parajuli, Ranjan; Dalgaard, Tommy; Nguyen, T Lan T

    2013-01-01

    ) plant. Alternatively, we have simulated the combustion process of Miscanthus in a boiler, where only heat is produced. For NG similar scenarios are examined. Life Cycle Assessment (LCA) in relation to 1 MJ of heat production with Miscanthus fired in a CHP would lead to a Global Warming Potential (GWP...

  12. Alternative aviation turbine fuels

    Science.gov (United States)

    Grobman, J.

    1977-01-01

    The efficient utilization of fossil fuels by future jet aircraft may necessitate the broadening of current aviation turbine fuel specifications. The most significant changes in specifications would be an increased aromatics content and a higher final boiling point in order to minimize refinery energy consumption and costs. These changes would increase the freezing point and might lower the thermal stability of the fuel and could cause increased pollutant emissions, increased smoke and carbon formation, increased combustor liner temperatures, and poorer ignition characteristics. This paper discusses the effects that broadened specification fuels may have on present-day jet aircraft and engine components and the technology required to use fuels with broadened specifications.

  13. Combustion of solid alternative fuels in the cement kiln burner

    DEFF Research Database (Denmark)

    Nørskov, Linda Kaare

    In the cement industry there is an increasing environmental and financial motivation for substituting conventional fossil fuels with alternative fuels, being biomass or waste derived fuels. However, the introduction of alternative fuels may influence emissions, cement product quality, process...... stability, and process efficiency. Alternative fuel substitution in the calciner unit has reached close to 100% at many cement plants and to further increase the use of alternative fuels rotary kiln substitution must be enhanced. At present, limited systematic knowledge of the alternative fuel combustion...... modelling, data collection and observations at an industrial cement plant firing alternative fuels. Alternative fuels may differ from conventional fossil fuels in combustion behaviour through differences in physical and chemical properties and reaction kinetics. Often solid alternative fuels are available...

  14. Dimethyl ether (DME) as an alternative fuel

    Science.gov (United States)

    Semelsberger, Troy A.; Borup, Rodney L.; Greene, Howard L.

    With ever growing concerns on environmental pollution, energy security, and future oil supplies, the global community is seeking non-petroleum based alternative fuels, along with more advanced energy technologies (e.g., fuel cells) to increase the efficiency of energy use. The most promising alternative fuel will be the fuel that has the greatest impact on society. The major impact areas include well-to-wheel greenhouse gas emissions, non-petroleum feed stocks, well-to-wheel efficiencies, fuel versatility, infrastructure, availability, economics, and safety. Compared to some of the other leading alternative fuel candidates (i.e., methane, methanol, ethanol, and Fischer-Tropsch fuels), dimethyl ether appears to have the largest potential impact on society, and should be considered as the fuel of choice for eliminating the dependency on petroleum. DME can be used as a clean high-efficiency compression ignition fuel with reduced NO x, SO x, and particulate matter, it can be efficiently reformed to hydrogen at low temperatures, and does not have large issues with toxicity, production, infrastructure, and transportation as do various other fuels. The literature relevant to DME use is reviewed and summarized to demonstrate the viability of DME as an alternative fuel.

  15. Study on the production of alternative fuels by carbon dioxide hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Sim, Kyu Sung; Han, Sang Do; Kim, Jong Won; Kim, Youn Soon; Seo, Ji Mi [Korea Inst. of Energy Research, Taejon (Korea, Republic of)

    1995-12-01

    The technologies of the fuel production from carbon dioxide by catalytic hydrogenation were surveyed. For the catalytic hydrogenation we made the lab-scale reaction apparatus and carried out some experiments with various catalysts like CuO/ZnO/Al{sub 2}O{sub 3}, Raney nickel and other commercial catalysts. In this year, the third year of the project, the experiments to find optimum catalysts and obtain the good conditions of carbon dioxide were performed followed by second year. And also the processes of the methanol synthesis was investigated simultaneously. (author). 58 refs., 58 figs., 28 tabs.

  16. Special Issue: Aviation Alternative Fuels

    Directory of Open Access Journals (Sweden)

    Yang Zhang

    2014-12-01

    Full Text Available The investigation of aviation alternative fuels has increased significantly in recent years in an effort to reduce the environment and climate impact by aviation industry. Special requirements have to be met for qualifying as a suitable aviation fuel. The fuel has to be high in energy content per unit of mass and volume, thermally stable and avoiding freezing at low temperatures. There are also many other special requirements on viscosity, ignition properties and compatibility with the typical aviation materials. There are quite a few contending alternative fuels which can be derived from coal, natural gas and biomass.[...

  17. Standardization of Alternative Fuels. Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-08-15

    mean with a specific alternative fuel; a standard for the fuel. Since we today live in a global society with international trade, the work with standards has to be carried out by international standardization organizations such as CEN and ISO. In the work on standardization of alternative fuels, it is of course important that all existing knowledge and experiences on production, distribution and use of alternative fuels are taken into account to avoid duplication of work and to limit the time and resources needed to produce standards. The International Energy Agency's Implementing Agreement on Advanced Motor Fuels, (IEA/AMF) is an organization with competence and more than 20 years of experience on alternative fuels. In April 2002 IEA/AMF's Executive Committee decided to start a new Annex, Annex XXVII on 'Standardization of alternative fuels'. This report is the result of phase one of Annex XXVII.

  18. Outlook for alternative energy sources. [aviation fuels

    Science.gov (United States)

    Card, M. E.

    1980-01-01

    Predictions are made concerning the development of alternative energy sources in the light of the present national energy situation. Particular emphasis is given to the impact of alternative fuels development on aviation fuels. The future outlook for aircraft fuels is that for the near term, there possibly will be no major fuel changes, but minor specification changes may be possible if supplies decrease. In the midterm, a broad cut fuel may be used if current development efforts are successful. As synfuel production levels increase beyond the 1990's there may be some mixtures of petroleum-based and synfuel products with the possibility of some shale distillate and indirect coal liquefaction products near the year 2000.

  19. Mobile Alternative Fueling Station Locator

    Energy Technology Data Exchange (ETDEWEB)

    2009-04-01

    The Department of Energy's Alternative Fueling Station Locator is available on-the-go via cell phones, BlackBerrys, or other personal handheld devices. The mobile locator allows users to find the five closest biodiesel, electricity, E85, hydrogen, natural gas, and propane fueling sites using Google technology.

  20. Alternatives for nuclear fuel disposal

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez S, J. R.; Badillo A, V.; Palacios H, J.; Celis del Angel, L., E-mail: ramon.ramirez@inin.gob.m [ININ, Carretera Mexico-Toluca s/n, Ocoyoacac 52750, Estado de Mexico (Mexico)

    2010-10-15

    The spent fuel is one of the most important issues in the nuclear industry, currently spent fuel management is been cause of great amount of research, investments in the construction of repositories or constructing the necessary facilities to reprocess the fuel, and later to recycle the plutonium recovered in thermal reactors. What is the best solution? or, What is the best technology for a specific solution? Many countries have deferred the decision on selecting an option, while other works actively constructing repositories and others implementing the reprocessing facilities to recycle the plutonium obtained from nuclear spent fuel. In Mexico the nuclear power is limited to two reactors BWR type and medium size. So the nuclear spent fuel discharged has been accommodated at reactor's spent fuel pools. Originally these pools have enough capacity to accommodate spent fuel for the 40 years of designed plant operation. However, currently is under process an extended power up rate to 20% of their original power and also there are plans to extend operational life for 20 more years. Under these conditions there will not be enough room for spent fuel in the pools. So this work describes some different alternatives that have been studied in Mexico to define which will be the best alternative to follow. (Author)

  1. Effects of alternate fuels. Report No. 6. Analysis of low-alumina castable refractory degraded by residual oil combustion products

    Energy Technology Data Exchange (ETDEWEB)

    Wei, G. C.; Tennery, V. J.

    1978-07-01

    This is the sixth of a series of reports on analyses of several types of refractories used in industrial furnaces with fuels considered alternate to natural gas. Analyses were performed on a low-alumina castable used for only two months in the roof of a residual-oil-fired boiler. The maximum hot-face temperature during operation was about 1530/sup 0/K. The original microstructure of the castable, which consisted of mullite aggregate bonded with iron-containing gehlenite (2 CaO . Al/sub 2/O/sub 3/ . SiO/sub 2/), quartz and cristobalite, was totally altered during service in regions close to the hot face. At room temperature the altered microstructure consisted of corundum and gehlenite in a new oxide glass phase containing the elements Na, K, Ca, Fe, Ti, Al, Ni, and Si. The reactions of the fuel oil impurities Na, Fe, and Ni with mullite, quartz, and cristobalite in the original castable refractory caused the rapid degradation at the hot face during service in the boiler. Increasing the Al/sub 2/O/sub 3/ content of the castable by replacing mullite aggregate with alumina aggregate and using gehlenite with less iron impurity as the bonding material should improve the performance of this castable refractory or retard reactions of the castable with fuel oil combustion products including Na, Fe, and Ni.

  2. Alternative fuels for vehicles; Alternative drivmidler

    Energy Technology Data Exchange (ETDEWEB)

    2012-02-15

    Up until 2020 and onwards the analysis indicates that especially electricity, biogas and natural gas as propellants is economically attractive compared to conventional gasoline and diesel while other fuels have the same or higher costs for petrol and diesel. Especially biogas and electricity will also offer significant reductions in CO{sub 2} emissions, but also hydrogen, methanol, DME and to a lesser extent the second generation bioethanol and most of the other alternative fuels reduce CO{sub 2} emissions. Use of the traditional food-based first generation biofuels involves, at best, only modest climate benefits if land use changes are counted, and at worst, significant negative climate effects. Natural gas as a propellant involves a moderate climate gain, but may play a role for building infrastructure and market for gaseous fuels in large fleets, thereby contributing to the phasing in of biogas for transport. The electric-based automotive fuels are the most effective due to a high efficiency of the engine and an increasing proportion of wind energy in the electricity supply. The methanol track also has a relatively high efficiency. Among the others, the track based on diesel engines (biodiesel) is more effective than the track based on gasoline/Otto engines (gas and ethanol) as a result of the diesel engine's better efficiency. For the heavy vehicles all the selected alternative fuels to varying degrees reduce emissions of CO{sub 2}, particularly DME based on wood. The only exception to this is - as for passenger cars - the propellant synthetic diesel based on coal. (LN).

  3. Alternative Aviation Fuel Experiment (AAFEX)

    Science.gov (United States)

    Anderson, B. E.; Beyersdorf, A. J.; Hudgins, C. H.; Plant, J. V.; Thornhill, K. L.; Winstead, E. L.; Ziemba, L. D.; Howard, R.; Corporan, E.; Miake-Lye, R. C.; Herndon, S. C.; Timko, M.; Woods, E.; Dodds, W.; Lee, B.; Santoni, G.; Whitefield, P.; Hagen, D.; Lobo, P.; Knighton, W. B.; Bulzan, D.; Tacina, K.; Wey, C.; VanderWal, R.; Bhargava, A.

    2011-01-01

    The rising cost of oil coupled with the need to reduce pollution and dependence on foreign suppliers has spurred great interest and activity in developing alternative aviation fuels. Although a variety of fuels have been produced that have similar properties to standard Jet A, detailed studies are required to ascertain the exact impacts of the fuels on engine operation and exhaust composition. In response to this need, NASA acquired and burned a variety of alternative aviation fuel mixtures in the Dryden Flight Research Center DC-8 to assess changes in the aircraft s CFM-56 engine performance and emission parameters relative to operation with standard JP-8. This Alternative Aviation Fuel Experiment, or AAFEX, was conducted at NASA Dryden s Aircraft Operations Facility (DAOF) in Palmdale, California, from January 19 to February 3, 2009 and specifically sought to establish fuel matrix effects on: 1) engine and exhaust gas temperatures and compressor speeds; 2) engine and auxiliary power unit (APU) gas phase and particle emissions and characteristics; and 3) volatile aerosol formation in aging exhaust plumes

  4. Fuel cells : a viable fossil fuel alternative

    Energy Technology Data Exchange (ETDEWEB)

    Paduada, M.

    2007-02-15

    This article presented a program initiated by Natural Resources Canada (NRCan) to develop proof-of-concept of underground mining vehicles powered by fuel cells in order to eliminate emissions. Recent studies on American and Canadian underground mines provided the basis for estimating the operational cost savings of switching from diesel to fuel cells. For the Canadian mines evaluated, the estimated ventilation system operating cost reductions ranged from 29 per cent to 75 per cent. In order to demonstrate the viability of a fuel cell-powered vehicle, NRCan has designed a modified Caterpillar R1300 loader with a 160 kW hybrid power plant in which 3 stacks of fuel cells deliver up to 90 kW continuously, and a nickel-metal hydride battery provides up to 70 kW. The battery subsystem transiently boosts output to meet peak power requirements and also accommodates regenerative braking. Traction for the loader is provided by a brushless permanent magnet traction motor. The hydraulic pump motor is capable of a 55 kW load continuously. The loader's hydraulic and traction systems are operated independently. Future fuel cell-powered vehicles designed by the program may include a locomotive and a utility vehicle. Future mines running their operations with hydrogen-fueled equipment may also gain advantages by employing fuel cells in the operation of handheld equipment such as radios, flashlights, and headlamps. However, the proton exchange membrane (PEM) fuel cells used in the project are prohibitively expensive. The catalytic content of a fuel cell can add hundreds of dollars per kW of electric output. Production of catalytic precious metals will be strongly connected to the scale of use and acceptance of fuel cells in vehicles. In addition, the efficiency of hydrogen production and delivery is significantly lower than the well-to-tank efficiency of many conventional fuels. It was concluded that an adequate hydrogen infrastructure will be required for the mining industry

  5. Use of alternative fuels in solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-05-15

    A future sustainable energy system will certainly be based on a variety of environmentally benign energy production technologies. Fuel cells can be a key element in this scenario. One of the fuel cells types the solid oxide fuel cell (SOFC) has a number of advantages that places them in a favorable position: high efficiency, parallel production of electricity and high value heat, prevention of NOx emission, flexibility regarding usable fuels, and certain tolerance towards impurities. It is thus a natural option, to combine such a highly efficient energy conversion tool with a sustainable fuel supply. In the present contribution, the use of alternative compared to conventional fuels in SOFCs was evaluated. Regarding carbon containing, biomass derived fuels, SOFCs showed excellent power output and stability behavior during long-term testing under technologically relevant conditions. Moreover, ammonia can be used directly as fuel. The chemical and structural properties of the SOFC anode makes it even possible, to combine a chemical conversion of the fuel, for example methane into synthesis gas via steam reforming and decomposition of ammonia into hydrogen and nitrogen, with the electrochemical production of electricity in one step. (au)

  6. Alternatives to traditional transportation fuels: An overview

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    This report presents the first compilation by the Energy Information Administration (EIA) of information on alternatives to gasoline and diesel fuel. The purpose of the report is: (1) to provide background information on alternative transportation fuels and replacement fuels compared with gasoline and diesel fuel, and (2) to furnish preliminary estimates of alternative transportation fuels and alternative fueled vehicles as required by the Energy Policy Act of 1992 (EPACT), Title V, Section 503, ``Replacement Fuel Demand Estimates and Supply Information.`` Specifically, Section 503 requires the EIA to report annually on: (1) the number and type of alternative fueled vehicles in existence the previous year and expected to be in use the following year, (2) the geographic distribution of these vehicles, (3) the amounts and types of replacement fuels consumed, and (4) the greenhouse gas emissions likely to result from replacement fuel use. Alternative fueled vehicles are defined in this report as motorized vehicles licensed for on-road use, which may consume alternative transportation fuels. (Alternative fueled vehicles may use either an alternative transportation fuel or a replacement fuel.) The intended audience for the first section of this report includes the Secretary of Energy, the Congress, Federal and State agencies, the automobile manufacturing industry, the transportation fuel manufacturing and distribution industries, and the general public. The second section is designed primarily for persons desiring a more technical explanation of and background for the issues surrounding alternative transportation fuels.

  7. Transportation Energy Futures Series: Alternative Fuel Infrastructure Expansion: Costs, Resources, Production Capacity, and Retail Availability for Low-Carbon Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Melaina, M. W.; Heath, G.; Sandor, D.; Steward, D.; Vimmerstedt, L.; Warner, E.; Webster, K. W.

    2013-04-01

    Achieving the Department of Energy target of an 80% reduction in greenhouse gas emissions by 2050 depends on transportation-related strategies combining technology innovation, market adoption, and changes in consumer behavior. This study examines expanding low-carbon transportation fuel infrastructure to achieve deep GHG emissions reductions, with an emphasis on fuel production facilities and retail components serving light-duty vehicles. Three distinct low-carbon fuel supply scenarios are examined: Portfolio: Successful deployment of a range of advanced vehicle and fuel technologies; Combustion: Market dominance by hybridized internal combustion engine vehicles fueled by advanced biofuels and natural gas; Electrification: Market dominance by electric drive vehicles in the LDV sector, including battery electric, plug-in hybrid, and fuel cell vehicles, that are fueled by low-carbon electricity and hydrogen. A range of possible low-carbon fuel demand outcomes are explored in terms of the scale and scope of infrastructure expansion requirements and evaluated based on fuel costs, energy resource utilization, fuel production infrastructure expansion, and retail infrastructure expansion for LDVs. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored transportation-related strategies for abating GHGs and reducing petroleum dependence.

  8. HFIR spent fuel management alternatives

    Energy Technology Data Exchange (ETDEWEB)

    Begovich, J.M.; Green, V.M.; Shappert, L.B.; Lotts, A.L.

    1992-10-15

    The High Flux Isotope Reactor (HFIR) at Martin Marietta Energy Systems' Oak Ridge National Laboratory (ORNL) has been unable to ship its spent fuel to Savannah River Site (SRS) for reprocessing since 1985. The HFIR storage pools are expected to fill up in the February 1994 to February 1995 time frame. If a management altemative to existing HFIR pool storage is not identified and implemented before the HFIR pools are full, the HFIR will be forced to shut down. This study investigated several alternatives for managing the HFIR spent fuel, attempting to identify options that could be implemented before the HFIR pools are full. The options investigated were: installing a dedicated dry cask storage facility at ORNL, increasing HFIR pool storage capacity by clearing the HFIR pools of debris and either close-packing or stacking the spent fuel elements, storing the spent fuel at another ORNL pool, storing the spent fuel in one or more hot cells at ORNL, and shipping the spent fuel offsite for reprocessing or storage elsewhere.

  9. Alternative Fuel for Portland Cement Processing

    Energy Technology Data Exchange (ETDEWEB)

    Schindler, Anton K; Duke, Steve R; Burch, Thomas E; Davis, Edward W; Zee, Ralph H; Bransby, David I; Hopkins, Carla; Thompson, Rutherford L; Duan, Jingran; ; Venkatasubramanian, Vignesh; Stephen, Giles

    2012-06-30

    The production of cement involves a combination of numerous raw materials, strictly monitored system processes, and temperatures on the order of 1500 °C. Immense quantities of fuel are required for the production of cement. Traditionally, energy from fossil fuels was solely relied upon for the production of cement. The overarching project objective is to evaluate the use of alternative fuels to lessen the dependence on non-renewable resources to produce portland cement. The key objective of using alternative fuels is to continue to produce high-quality cement while decreasing the use of non-renewable fuels and minimizing the impact on the environment. Burn characteristics and thermodynamic parameters were evaluated with a laboratory burn simulator under conditions that mimic those in the preheater where the fuels are brought into a cement plant. A drop-tube furnace and visualization method were developed that show potential for evaluating time- and space-resolved temperature distributions for fuel solid particles and liquid droplets undergoing combustion in various combustion atmospheres. Downdraft gasification has been explored as a means to extract chemical energy from poultry litter while limiting the throughput of potentially deleterious components with regards to use in firing a cement kiln. Results have shown that the clinkering is temperature independent, at least within the controllable temperature range. Limestone also had only a slight effect on the fusion when used to coat the pellets. However, limestone addition did display some promise in regards to chlorine capture, as ash analyses showed chlorine concentrations of more than four times greater in the limestone infused ash as compared to raw poultry litter. A reliable and convenient sampling procedure was developed to estimate the combustion quality of broiler litter that is the best compromise between convenience and reliability by means of statistical analysis. Multi-day trial burns were conducted

  10. FUELS IN TOBACCO PRODUCTION

    Directory of Open Access Journals (Sweden)

    M. Čavlek

    2008-09-01

    Full Text Available Energy production from biomass can reduce „greenhouse effect” and contribute to solving energy security especially in the agricultural households which rely on energy from fossil fuels. In Croatia fuel-cured tobacco is produced on about 5000 ha. Gross income for the whole production is about 180 000 000 kn/year. Flue-cured tobacco is a high energy consuming crop. There are two parts of energy consumption, for mechanization used for the field production (11% and, energy for bulk-curing (89%. In each case, presently used fuels of fossil origin need to be substituted by an alternative energy source of organic origin. Hereafter attention is paid to finding a more economic and ecologically acceptable fuel for curing tobacco. Curing flue-cured tobacco is done by heated air in curing burns. Various sources of heat have been used; wood, coal, oil and gas. In each case different burning facilities of different efficiency have been used. This has had an impact on curing costs and ecology. Recently, mostly used fuel has been natural gas. However, gas is getting expensive. Consequently, an alternative fuel for curing tobacco is sought for. According to literature, agricultural crops suitable for the latter purpose could be wheat, barley, maize, sorghum, sugar beet and some other annual and perennial plant species. Wooden pellets (by-products are suitable for combustion too. Ligno-cellulose fuels have been used for heating since long time. However, not sufficient research has been done from an applied point of view (Venturi and Venturi, 2003. Fuel combustion is getting more efficient with developing technological innovations. The curing barn manufacturers are offering technology for combusting wooden pellets (by-products for curing tobacco. The pellets are available on domestic market. The same technology can be used for combustion of maize grain. Within “Hrvatski duhani” research on suitability of using wooden pellets and maize grain and whole

  11. Sustainability of fossil fuels and alternative energies for Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Tasdemiroglu, E.

    1989-01-01

    Reserves and production of fossil fuels in Turkey are discussed, as well as projections of production rates to the year 2010. Sustainability of fossil-fuel production has been estimated on the basis of presently known data. Fossil fuels will have a very limited lifetime. Bitumens, hydropower, geothermal energy, solar energy, wind power, biomass, and nuclear energy are appropriate alternative technologies. The potentials of these alternatives are given and recommendations made to enhance their contributions. 19 refs., 1 fig., 2 tabs.

  12. Sulphur release from alternative fuel firing

    DEFF Research Database (Denmark)

    Cortada Mut, Maria del Mar; Nørskov, Linda Kaare; Glarborg, Peter;

    2014-01-01

    The cement industry has long been dependent on the use of fossil fuels, although a recent trend in replacing fossil fuels with alternative fuels has arisen. 1, 2 However, when unconverted or partly converted alternative fuels are admitted directly in the rotary kiln inlet, the volatiles released...

  13. Alternate-Fueled Flight: Halophytes, Algae, Bio-, and Synthetic Fuels

    Science.gov (United States)

    Hendricks, R. C.

    2012-01-01

    Synthetic and biomass fueling are now considered to be near-term aviation alternate fueling. The major impediment is a secure sustainable supply of these fuels at reasonable cost. However, biomass fueling raises major concerns related to uses of common food crops and grasses (some also called "weeds") for processing into aviation fuels. These issues are addressed, and then halophytes and algae are shown to be better suited as sources of aerospace fuels and transportation fueling in general. Some of the history related to alternate fuels use is provided as a guideline for current and planned alternate fuels testing (ground and flight) with emphasis on biofuel blends. It is also noted that lessons learned from terrestrial fueling are applicable to space missions. These materials represent an update (to 2009) and additions to the Workshop on Alternate Fueling Sustainable Supply and Halophyte Summit at Twinsburg, Ohio, October 17 to 18, 2007.

  14. Energy balances in the production and end use of alcohols derived from biomass. A fuels-specific comparative analysis of alternate ethanol production cycles

    Energy Technology Data Exchange (ETDEWEB)

    1980-10-01

    Considerable public interest and debate have been focused on the so-called energy balance issue involved in the conversion of biomass materials into ethanol for fuel use. This report addresses questions of net gains in premium fuels that can be derived from the production and use of ethanol from biomass, and shows that for the US alcohol fuel program, energy balance need not be a concern. Three categories of fuel gain are discussed in the report: (1) Net petroleum gain; (2) Net premium fuel gain (petroleum and natural gas); and (3) Net energy gain (for all fuels). In this study the investment of energy (in the form of premium fuels) in alcohol production includes all investment from cultivating, harvesting, or gathering the feedstock and raw materials, through conversion of the feedstock to alcohol, to the delivery to the end-user. To determine the fuel gains in ethanol production, six cases, encompassing three feedstocks, five process fuels, and three process variations, have been examined. For each case, two end-uses (automotive fuel use and replacement of petrochemical feedstocks) were scrutinized. The end-uses were further divided into three variations in fuel economy and two different routes for production of ethanol from petrochemicals. Energy requirements calculated for the six process cycles accounted for fuels used directly and indirectly in all stages of alcohol production, from agriculture through distribution of product to the end-user. Energy credits were computed for byproducts according to the most appropriate current use.

  15. Aviation turbine fuels: An assessment of alternatives

    Science.gov (United States)

    1982-01-01

    The general outlook for aviation turbine fuels, the effect that broadening permissible aviation turbine fuel properties could have on the overall availability of such fuels, the fuel properties most likely to be affected by use of lower grade petroleum crudes, and the research and technology required to ensure that aviation turbine fuels and engines can function satisfactorily with fuels having a range of fuel properties differing from those of current specification fuel are assessed. Views of industry representatives on alternative aviation turbine fuels are presented.

  16. Alternative Fuels Data Center (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2013-07-01

    Fact sheet describes the Alternative Fuels Data Center, which provides information, data, and tools to help fleets and other transportation decision makers find ways to reduce petroleum consumption through the use of alternative and renewable fuels, advanced vehicles, and other fuel-saving measures.

  17. Alternate-Fueled Combustion-Sector Emissions

    Science.gov (United States)

    Saxena, Nikita T.; Thomas, Anna E.; Shouse, Dale T.; Neuroth, Craig; Hendricks, Robert C.; Lynch, Amy; Frayne, Charles W.; Stutrud, Jeffrey S.; Corporan, Edwin; Hankins, Terry

    2012-01-01

    In order to meet rapidly growing demand for fuel, as well as address environmental concerns, the aviation industry has been testing alternate fuels for performance and technical usability in commercial and military aircraft. Currently, alternate aviation fuels must satisfy MIL-DTL- 83133F(2008) (military) or ASTM D 7566- Annex(2011) (commercial) standards and are termed drop-in fuel replacements. Fuel blends of up to 50% alternative fuel blended with petroleum (JP-8), which have become a practical alternative, are individually certified on the market. In order to make alternate fuels (and blends) a viable option for aviation, the fuel must be able to perform at a similar or higher level than traditional petroleum fuel. They also attempt to curb harmful emissions, and therefore a truly effective alternate fuel would emit at or under the level of currently used fuel. This paper analyzes data from gaseous and particulate emissions of an aircraft combustor sector. The data were evaluated at various inlet conditions, including variation in pressure and temperature, fuel-to-air ratios, and percent composition of alternate fuel. Traditional JP-8+100 data were taken as a baseline, and blends of JP- 8+100 with synthetic-paraffinic-kerosene (SPK) fuel (Fischer-Tropsch (FT)) were used for comparison. Gaseous and particulate emissions, as well as flame luminosity, were assessed for differences between FT composition of 0%, 50%, and 100%. The data showed that SPK fuel (a FT-derived fuel) had slightly lower harmful gaseous emissions, and smoke number information corroborated the hypothesis that SPK-FT fuels are cleaner burning fuels.

  18. Alternative Fabrication of Recycling Fast Reactor Metal Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ki-Hwan; Kim, Jong Hwan; Song, Hoon; Kim, Hyung-Tae; Lee, Chan-Bock [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    Metal fuels such as U-Zr/U-Pu-Zr alloys have been considered as a nuclear fuel for a sodium-cooled fast reactor (SFR) related to the closed fuel cycle for managing minor actinides and reducing a high radioactivity levels since the 1980s. In order to develop innovative fabrication method of metal fuel for preventing the evaporation of volatile elements such as Am, modified casting under inert atmosphere has been applied for metal fuel slugs for SFR. Alternative fabrication method of fuel slugs has been introduced to develop an improved fabrication process of metal fuel for preventing the evaporation of volatile elements. In this study, metal fuel slugs for SFR have been fabricated by modified casting method, and characterized to evaluate the feasibility of the alternative fabrication method. In order to prevent evaporation of volatile elements such as Am and improve quality of fuel slugs, alternative fabrication methods of metal fuel slugs have been studied in KAERI. U-10Zr-5Mn fuel slug containing volatile surrogate element Mn was soundly cast by modified injection casting under modest pressure. Evaporation of Mn during alternative casting could not be detected by chemical analysis. Mn element was most recovered with prevention of evaporation by alternative casting. Modified injection casting has been selected as an alternative fabrication method in KAERI, considering evaporation prevention, and proven benefits of high productivity, high yield, and good remote control.

  19. Synthetic and Biomass Alternate Fueling in Aviation

    Science.gov (United States)

    Hendricks, R. C.; Bushnell, D. M.

    2009-01-01

    While transportation fueling can accommodate a broad range of alternate fuels, aviation fueling needs are specific, such as the fuel not freezing at altitude or become too viscous to flow properly or of low bulk energy density that shortens range. The fuel must also be compatible with legacy aircraft, some of which are more than 50 years old. Worldwide, the aviation industry alone uses some 85-95 billion gallons of hydrocarbon-based fossil fuel each year, which is about 10% of the transportation industry. US civil aviation alone consumes nearly 14 billion gallons. The enormity of the problem becomes overwhelming, and the aviation industry is taking alternate fueling issues very seriously. Biofuels (algae, cyanobacteria, halophytes, weeds that use wastelands, wastewater and seatwater), when properly sourced, have the capacity to be drop-in fuel replacements for petroleum fuels. As such, biojet from such sources solves the aviation CO2 emissions issue without the downsides of 'conventional' biofuels, such as competing with food and fresh water resources. Of the many current fundamental problems, the major biofuel problem is cost. Both research and development and creative engineering are required to reduce these biofuels costs. Research is also ongoing in several 'improvement' areas including refining/processing and biologics with greater disease resistance, greater bio-oil productivity, reduced water/nutrient requirements, etc. The authors' current research is aimed at aiding industry efforts in several areas. They are considering different modeling approaches, growth media and refining approaches, different biologic feedstocks, methods of sequestering carbon in the processes, fuel certification for aviation use and, overall, ensuring that biofuels are feasible from all aspects - operability, capacity, carbon cycle and financial. The authors are also providing common discussion grounds/opportunities for the various parties, disciplines and concerned organization to

  20. Calculation of greenhouse gas emissions of jatropha oil and jatropha biodiesel as alternative fuels for electricity production in Côte d'Ivoire

    Science.gov (United States)

    Atta, Pascal Atta; N'guessan, Yao; Morin, Celine; Voirol, Anne Jaecker; Descombes, Georges

    2017-02-01

    The electricity in Côte d'Ivoire is mainly produced from fossil energy sources. This causes damages on environment due to greenhouse gas emissions (GHG). The aim of this paper is to calculate the greenhouse gas (GHG) emissions of jatropha oil and jatropha biodiesel as alternative fuels for electricity production in Côte d'Ivoire by using Life Cycle Assessment (LCA) methodology. The functional unit in this LCA is defined as 1 kWh of electricity produced by the combustion of jatropha oil or jatropha biodiesel in the engine of a generator. Two scenarios, called short chain and long chain, were examined in this LCA. The results show that 0.132 kg CO2 equivalent is emitted for the scenario 1 with jatropha oil as an alternative fuel against 0.6376 kg CO2 equivalent for the scenario 2 with jatropha biodiesel as an alternative fuel. An 87 % reduction of kg CO2 equivalent is observed in scenario 1 and a 37 % reduction of kg CO2 equivalent is observed in the scenario 2, when compared with a Diesel fuel.

  1. Sulfur Release during Alternative fuels Combustion in Cement Rotary Kilns

    OpenAIRE

    Cortada Mut, Maria del Mar; Dam-Johansen, Kim; Glarborg, Peter; Nørskov, Linda Kaare

    2014-01-01

    Cement production is an energy-intensive process, whic h has traditionally been dependent on fossil fuels. However, the usage of selected waste, biomass, and by-products with recoverable calorific value, defined as alternative fuels, is increasing and their combustion is mo re challenging compared to fossil fuels, due to the lack of experience in handling the different and va rying combustion characteristics caused by different chemical and physical properties, e.g. higher moisture content an...

  2. Alternatives to traditional transportation fuels 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-01

    Interest in alternative transportation fuels (ATF`s) has increased in recent years due to the drives for cleaner air and less dependence upon foreign oil. This report, Alternatives to Traditional Transportation Fuels 1996, provides information on ATFs, as well as the vehicles that consume them.

  3. Sulfur Release during Alternative fuels Combustion in Cement Rotary Kilns

    DEFF Research Database (Denmark)

    Cortada Mut, Maria del Mar

    Cement production is an energy-intensive process, whic h has traditionally been dependent on fossil fuels. However, the usage of selected waste, biomass, and by-products with recoverable calorific value, defined as alternative fuels, is increasing and their combustion is mo re challenging compared...... in order to separate the influence of the simultaneous phenomena occurring in the experimental set-up, such as mixing th e fuel with the bed material, heating up of a particle, 5 iii Abstract Cement production is an energy-intensive process, whic h has traditionally been dependent on fossil fuels. However...... to fossil fuels, due to the lack of experience in handling the different and va rying combustion characteristics caused by different chemical and physical properties, e.g. higher moisture content and larger particle sizes. When full combustion of alternative fuels in the calcin er and/or main burner...

  4. Algae fuels : a tantalizing alternative

    Energy Technology Data Exchange (ETDEWEB)

    Granson, E.

    2010-11-15

    This article surveyed the current state of research and development in the area of algae use as a basis for fuel and as a feedstock for the chemical industry. The constraints inhibiting the commercialization of algae-related processes were discussed and a brief overview of the history of algae research was presented. Interest in algae research has ebbed and flowed in conjunction with economic and social concerns. It is unknown whether algae can be grown on a scale and cost that is commercially viable. A bench-scale algae cultivation system involving photobioreactors was described. Algae are increasingly being used in treating wastewater from industrial processes, as algae can reduce ammonia and phosphate loads in effluent. Exhaust carbon dioxide is being used to feed algae crops. Advances are needed to make turning algae oil into fuel cost effective. A bench-stage process for extracting algae oil from water for biofuel conversion was described. The process results in easier-to-dry biomass without using chemical solvents or centrifuges. Algae biomass is also being explored for used as a polymer feedstock. Algae can be grown anywhere there is sun, but the challenge is in developing a large enough supply of algae biomass. Second generation algae plastic products will be more complex and may involve the creation of a monomer out of algae itself, which could make algae competitive with oil in the plastics industry. Skeptics doubt that algae processes can be commercialized, but some within the industry believe that algae biomass will eventually work within the norms of industrial processes. 5 figs.

  5. Fuel from microalgae lipid products

    Energy Technology Data Exchange (ETDEWEB)

    Hill, A.M.; Feinberg, D.A.

    1984-04-01

    The large-scale production of microalgae is a promising method of producing a renewable feedstock for a wide variety of fuel products currently refined from crude petroleum. These microalgae-derived products include lipid extraction products (triglycerides, fatty acids, and hydrocarbons) and catalytic conversion products (paraffins and olefins). Microalgal biomass productivity and lipid composition of current experimental systems are estimated at 66.0 metric tons per hectare year and 30% lipid content. Similar yields in a large-scale facility indicate that production costs are approximately six times higher than the average domestic price for crude, well-head petroleum. Based on achievable targets for productivity and production costs, the potential for microalgae as a fuel feedstock is presented in context with selected process refining routes and is compared with conventional and alternative feedstocks (e.g., oilseeds) with which microalgae must compete. 24 references, 9 figures, 4 tables.

  6. DoD use of Domestically-Produced Alternative Fuels and Alternative Fuel Vehicles

    Science.gov (United States)

    2014-04-10

    fuels and vehicles. 15. SUBJECT TERMS alternative fuel infrastructure, electric vehicles, biofuels, ethanol , biodiesel , drop-in, synthetic fuel...control number. 1. REPORT DATE 10 APR 2014 2. REPORT TYPE Final 3. DATES COVERED 06 JAN 2014 - 2014 APR 10 4. TITLE AND SUBTITLE DoD use of...based fuels and biodiesel , in DoD vehicles; (2) current and projected actions by the DoD to increase the use of alternative fuels in vehicles; (3) a

  7. Alternative Fuel and Advanced Technology Commercial Lawn Equipment (Brochure)

    Energy Technology Data Exchange (ETDEWEB)

    2014-10-01

    The U.S. Department of Energy's Clean Cities program produced this guide to help inform the commercial mowing industry about product options and potential benefits. This guide provides information about equipment powered by propane, ethanol, compressed natural gas, biodiesel, and electricity, as well as advanced engine technology. In addition to providing an overview for organizations considering alternative fuel lawn equipment, this guide may also be helpful for organizations that want to consider using additional alternative fueled equipment.

  8. Alternative Fuel and Advanced Technology Commercial Lawn Equipment

    Energy Technology Data Exchange (ETDEWEB)

    None

    2014-10-10

    The U.S. Department of Energy's Clean Cities program produced this guide to help inform the commercial mowing industry about product options and potential benefits. This guide provides information about equipment powered by propane, ethanol, compressed natural gas, biodiesel, and electricity, as well as advanced engine technology. In addition to providing an overview for organizations considering alternative fuel lawn equipment, this guide may also be helpful for organizations that want to consider using additional alternative fueled equipment.

  9. The Efficient Use of the Productive Potential of Technical Plant Cultures With the Purpose of Providing an Alternative Energetic Fuel Source

    Directory of Open Access Journals (Sweden)

    Florica Morar

    2009-12-01

    Full Text Available The identification of secure, non-polluting and renewable sources of biofuel, as an alternative to the fossil fuel, which are finite in time, constituted a concern of scientists long before the energetic crisis of 1973. According to Directive 2003/30/CE, the European Union policy considers the decrease of dependency and of the energetic import, as well as the decrease of gas emissions. By 2020, EU Member States, need to replace gasoline and diesel at a rate of 20%, with renewable fuels. In our country, in order to obtain biodiesel from vegetable oils researches are made on some crops such as sunflower, soybean, apeseed. In Mures County, have done research on the composition and production of oil of rapeseed cultivation for autumn and spring. As a mean value for the three years, varieties Bolero (spring and Digger (autumn accumulated the highest oil content.

  10. Global Energy Issues and Alternate Fueling

    Science.gov (United States)

    Hendricks, Robert C.

    2007-01-01

    This viewgraph presentation describes world energy issues and alternate fueling effects on aircraft design. The contents include: 1) US Uses about 100 Quad/year (1 Q = 10(exp 15) Btu) World Energy Use: about 433 Q/yr; 2) US Renewable Energy about 6%; 3) Nuclear Could Grow: Has Legacy Problems; 4) Energy Sources Primarily NonRenewable Hydrocarbon; 5) Notes; 6) Alternate Fuels Effect Aircraft Design; 7) Conventional-Biomass Issue - Food or Fuel; 8) Alternate fuels must be environmentally benign; 9) World Carbon (CO2) Emissions Problem; 10) Jim Hansen s Global Warming Warnings; 11) Gas Hydrates (Clathrates), Solar & Biomass Locations; 12) Global Energy Sector Response; 13) Alternative Renewables; 14) Stratospheric Sulfur Injection Global Cooling Switch; 15) Potential Global Energy Sector Response; and 16) New Sealing and Fluid Flow Challenges.

  11. Standardization of Alternative Fuels. Phase 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-08-15

    March 2003 the Executive Committee of the International Energy Agency's Implementing Agreement on Advanced Motor fuels (IEA/AMF) decided to continue annex XXVII 'Standardization of alternative fuels' with a second phase. The purpose of the second phase was to go further in the contacts with the International Organization for Standardization (ISO) as well as the European Committee for Standardization (CEN) and their technical committees, to better understand their needs and to investigate how IEA/AMF could contribute to their work. It was also scheduled to put forward proposals on how IEA/AMF could cooperate with CEN and ISO and their technical committees (TC: s), primarily ISO/TC 28 'Petroleum Products and Lubricants' and CEN/TC 19 'Petroleum Products, Lubricants and Related Products'. The main part of the work in IEA/AMF annex XXVII phase two has focused on personal contacts within CEN/TC 19 and ISO/TC 28, but also on data and information collection from websites and written information. Together with the analysis of this information, the internal organization of a cooperation between IEA/AMF and ISO/TC 28 and of a cooperation between IEA/AMF and CEN/TC 19 have also been discussed and analysed.

  12. 10 CFR 490.506 - Alternative fueled vehicle credit transfers.

    Science.gov (United States)

    2010-01-01

    ... Section 490.506 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ALTERNATIVE FUEL TRANSPORTATION PROGRAM Alternative Fueled Vehicle Credit Program § 490.506 Alternative fueled vehicle credit transfers. (a) Any fleet... fueled vehicle credit to— (1) A fleet that is required to acquire alternative fueled vehicles; or (2)...

  13. Alternative Fuels and Their Potential Impact on Aviation

    Science.gov (United States)

    Daggett, D.; Hendricks, R.; Walther, R.

    2006-01-01

    With a growing gap between the growth rate of petroleum production and demand, and with mounting environmental needs, the aircraft industry is investigating issues related to fuel availability, candidates for alternative fuels, and improved aircraft fuel efficiency. Bio-derived fuels, methanol, ethanol, liquid natural gas, liquid hydrogen, and synthetic fuels are considered in this study for their potential to replace or supplement conventional jet fuels. Most of these fuels present the airplane designers with safety, logistical, and performance challenges. Synthetic fuel made from coal, natural gas, or other hydrocarbon feedstock shows significant promise as a fuel that could be easily integrated into present and future aircraft with little or no modification to current aircraft designs. Alternatives, such as biofuel, and in the longer term hydrogen, have good potential but presently appear to be better suited for use in ground transportation. With the increased use of these fuels, a greater portion of a barrel of crude oil can be used for producing jet fuel because aircraft are not as fuel-flexible as ground vehicles.

  14. A methodology for assessing the market benefits of alternative motor fuels: The Alternative Fuels Trade Model

    Energy Technology Data Exchange (ETDEWEB)

    Leiby, P.N.

    1993-09-01

    This report describes a modeling methodology for examining the prospective economic benefits of displacing motor gasoline use by alternative fuels. The approach is based on the Alternative Fuels Trade Model (AFTM). AFTM development was undertaken by the US Department of Energy (DOE) as part of a longer term study of alternative fuels issues. The AFTM is intended to assist with evaluating how alternative fuels may be promoted effectively, and what the consequences of substantial alternative fuels use might be. Such an evaluation of policies and consequences of an alternative fuels program is being undertaken by DOE as required by Section 502(b) of the Energy Policy Act of 1992. Interest in alternative fuels is based on the prospective economic, environmental and energy security benefits from the substitution of these fuels for conventional transportation fuels. The transportation sector is heavily dependent on oil. Increased oil use implies increased petroleum imports, with much of the increase coming from OPEC countries. Conversely, displacement of gasoline has the potential to reduce US petroleum imports, thereby reducing reliance on OPEC oil and possibly weakening OPEC`s ability to extract monopoly profits. The magnitude of US petroleum import reduction, the attendant fuel price changes, and the resulting US benefits, depend upon the nature of oil-gas substitution and the supply and demand behavior of other world regions. The methodology applies an integrated model of fuel market interactions to characterize these effects.

  15. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    1999-04-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  16. Alternative Fuels and Chemicals from Synthesis Gas

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    1998-12-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  17. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    Energy Technology Data Exchange (ETDEWEB)

    Peter Tijrn

    2003-02-03

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  18. Alternative fuels and chemicals from synthesis gas

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    1998-08-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  19. Alternative Fuels and Chemicals from Synthesis Gas

    Energy Technology Data Exchange (ETDEWEB)

    Peter Tijrn

    2003-01-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  20. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    1999-01-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  1. Alternative Fuels and Chemicals From Synthesis Gas

    Energy Technology Data Exchange (ETDEWEB)

    none

    1998-07-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  2. Turbine Fuel Alternatives (Near Term)

    Science.gov (United States)

    1989-10-01

    There was some evidence that the use of the alcohol blends affected the combustion properties of the fuel. A temperature survey was conducted with a T-34C...Jet-A. Also, the corrected fuel flow is lower when using an alcohol blend than when operating on Jet-A. These two factors indicate the combustion ...VERSUS CORRECTED TURBINE OUTLET TEMPERATURE A-7 200, -T ’go-I 190 170- ETA oix 15X ETANOL ! ¶,0-1 1 20- S 110j 1. 001 9 0 I 7 0 10 zo 460 500 540 580

  3. Alternative Fuels and Sustainable Development

    DEFF Research Database (Denmark)

    Jørgensen, Kaj; Nielsen, Lars Henrik

    1996-01-01

    The main report of the project on Transportation Fuels based on Renewable Energy. The report contains a review of potential technologies for electric, hybrid and hydrogen propulsion in the Danish transport sector, including an assessment of their development status. In addition, the energy...

  4. Clean Cities Guide to Alternative Fuel Commercial Lawn Equipment (Brochure)

    Energy Technology Data Exchange (ETDEWEB)

    2011-10-01

    Guide explains the different types of alternative fuel commercial mowers and lists the makes and models of the ones available on the market. Turf grass is a fixture of the American landscape and the American economy. It is the nation's largest irrigated crop, covering more than 40 million acres. Legions of lawnmowers care for this expanse during the growing season-up to year-round in the warmest climates. The annual economic impact of the U.S. turf grass industry has been estimated at more than $62 billion. Lawn mowing also contributes to the nation's petroleum consumption and pollutant emissions. Mowers consume 1.2 billion gallons of gasoline annually, about 1% of U.S. motor gasoline consumption. Commercial mowing accounts for about 35% of this total and is the highest-intensity use. Large property owners and mowing companies cut lawns, sports fields, golf courses, parks, roadsides, and other grassy areas for 7 hours per day and consume 900 to 2,000 gallons of fuel annually depending on climate and length of the growing season. In addition to gasoline, commercial mowing consumes more than 100 million gallons of diesel annually. Alternative fuel mowers are one way to reduce the energy and environmental impacts of commercial lawn mowing. They can reduce petroleum use and emissions compared with gasoline- and diesel-fueled mowers. They may also save on fuel and maintenance costs, extend mower life, reduce fuel spillage and fuel theft, and promote a 'green' image. And on ozone alert days, alternative fuel mowers may not be subject to the operational restrictions that gasoline mowers must abide by. To help inform the commercial mowing industry about product options and potential benefits, Clean Cities produced this guide to alternative fuel commercial lawn equipment. Although the guide's focus is on original equipment manufacturer (OEM) mowers, some mowers can be converted to run on alternative fuels. For more information about propane

  5. Alternatives to traditional transportation fuels 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-01

    This report provides information on transportation fuels other than gasoline and diesel, and the vehicles that use these fuels. The Energy Information Administration (EIA) provides this information to support the U.S. Department of Energy`s reporting obligations under Section 503 of the Energy Policy Act of 1992 (EPACT). The principal information contained in this report includes historical and year-ahead estimates of the following: (1) the number and type of alterative-fueled vehicles (AFV`s) in use; (2) the consumption of alternative transportation fuels and {open_quotes}replacement fuels{close_quotes}; and (3) the number and type of alterative-fueled vehicles made available in the current and following years. In addition, the report contains some material on special topics. The appendices include a discussion of the methodology used to develop the estimates (Appendix A), a map defining geographic regions used, and a list of AFV suppliers.

  6. Outlook on Standardization of Alternative Vehicle Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Rehnlund, B. [Atrax Energi AB (Sweden)

    2008-10-15

    The use of fossil but in first hand biobased alternative fuels in transportation has increased over the last decades. This change is primarily driven by concerns about climate change that is caused by emissions of fossil carbon dioxide and other greenhouse gases, but also by the impact on health and environment, caused by emissions of regulated as well as non-regulated emissions from the transport sector. Most alternative fuels will help to reduce the emissions of regulated and non-regulated emissions, while alternative fuels based on biomass also will contribute to reduced net emissions of carbon dioxide. Since the mid 1990s, the use of biomass based fuels such as ethanol and biodiesel has reached levels high enough in for example Europe, Brazil and the U.S. to motivate national or regional specifications/standards. Especially from the vehicle/engine manufacturer's point of view standards are of high importance. From early 2000 onwards, the international trade of biofuels (for example from Brazil to the U.S. and Europe) has grown, and this has created a need for common international specifications/standards. This report presents information about national and regional standards for alternative fuels, but also, when existing and reported, standards on a global level are described and discussed. Ongoing work concerning new or revised standards on alternative fuels on national, regional or global level is also discussed. In this report we have covered standards on all kind of alternative fuels, exemplified below. However, the focus is on liquid biofuels for diesel engines and Otto engines. 1) Liquid fuels for diesel engines (compression ignition engines), such as Fatty Acid Methyl Esters (FAME), Fatty Acid Ethyl Esters (FAEE), alcohols, alcohol derivates and synthetic diesel fuels. 2) Liquid fuels for Otto engines (spark ignition engines), such as alcohols, ethers and synthetic gasoline. 3) Liquefied fossil petroleum gas (LPG). 4) Di-Methyl Ether (DME). 5

  7. Life-cycle analysis of alternative aviation fuels in GREET

    Energy Technology Data Exchange (ETDEWEB)

    Elgowainy, A.; Han, J.; Wang, M.; Carter, N.; Stratton, R.; Hileman, J.; Malwitz, A.; Balasubramanian, S. (Energy Systems)

    2012-07-23

    The Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, developed at Argonne National Laboratory, has been expanded to include well-to-wake (WTWa) analysis of aviation fuels and aircraft. This report documents the key WTWa stages and assumptions for fuels that represent alternatives to petroleum jet fuel. The aviation module in GREET consists of three spreadsheets that present detailed characterizations of well-to-pump and pump-to-wake parameters and WTWa results. By using the expanded GREET version (GREET1{_}2011), we estimate WTWa results for energy use (total, fossil, and petroleum energy) and greenhouse gas (GHG) emissions (carbon dioxide, methane, and nitrous oxide) for (1) each unit of energy (lower heating value) consumed by the aircraft or (2) each unit of distance traveled/ payload carried by the aircraft. The fuel pathways considered in this analysis include petroleum-based jet fuel from conventional and unconventional sources (i.e., oil sands); Fisher-Tropsch (FT) jet fuel from natural gas, coal, and biomass; bio-jet fuel from fast pyrolysis of cellulosic biomass; and bio-jet fuel from vegetable and algal oils, which falls under the American Society for Testing and Materials category of hydroprocessed esters and fatty acids. For aircraft operation, we considered six passenger aircraft classes and four freight aircraft classes in this analysis. Our analysis revealed that, depending on the feedstock source, the fuel conversion technology, and the allocation or displacement credit methodology applied to co-products, alternative bio-jet fuel pathways have the potential to reduce life-cycle GHG emissions by 55-85 percent compared with conventional (petroleum-based) jet fuel. Although producing FT jet fuel from fossil feedstock sources - such as natural gas and coal - could greatly reduce dependence on crude oil, production from such sources (especially coal) produces greater WTWa GHG emissions compared with petroleum jet

  8. Life-Cycle Analysis of Alternative Aviation Fuels in GREET

    Energy Technology Data Exchange (ETDEWEB)

    Elgowainy, A. [Argonne National Lab. (ANL), Argonne, IL (United States); Han, J. [Argonne National Lab. (ANL), Argonne, IL (United States); Wang, M. [Argonne National Lab. (ANL), Argonne, IL (United States); Carter, N. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Stratton, R. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Hileman, J. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Malwitz, A. [Volpe National Transportation Systems Center, Cambridge, MA (United States); Balasubramanian, S. [Volpe National Transportation Systems Center, Cambridge, MA (United States)

    2012-06-01

    The Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, developed at Argonne National Laboratory, has been expanded to include well-to-wake (WTWa) analysis of aviation fuels and aircraft. This report documents the key WTWa stages and assumptions for fuels that represent alternatives to petroleum jet fuel. The aviation module in GREET consists of three spreadsheets that present detailed characterizations of well-to-pump and pump-to-wake parameters and WTWa results. By using the expanded GREET version (GREET1_2011), we estimate WTWa results for energy use (total, fossil, and petroleum energy) and greenhouse gas (GHG) emissions (carbon dioxide, methane, and nitrous oxide) for (1) each unit of energy (lower heating value) consumed by the aircraft or(2) each unit of distance traveled/ payload carried by the aircraft. The fuel pathways considered in this analysis include petroleum-based jet fuel from conventional and unconventional sources (i.e., oil sands); Fisher-Tropsch (FT) jet fuel from natural gas, coal, and biomass; bio-jet fuel from fast pyrolysis of cellulosic biomass; and bio-jet fuel from vegetable and algal oils, which falls under the American Society for Testing and Materials category of hydroprocessed esters and fatty acids. For aircraft operation, we considered six passenger aircraft classes and four freight aircraft classes in this analysis. Our analysis revealed that, depending on the feedstock source, the fuel conversion technology, and the allocation or displacement credit methodology applied to co-products, alternative bio-jet fuel pathways have the potential to reduce life-cycle GHG emissions by 55–85 percent compared with conventional (petroleum-based) jet fuel. Although producing FT jet fuel from fossil feedstock sources — such as natural gas and coal — could greatly reduce dependence on crude oil, production from such sources (especially coal) produces greater WTWa GHG emissions compared with petroleum jet

  9. FUELS IN TOBACCO PRODUCTION

    OpenAIRE

    Čavlek, M.; Boić, M.; Kristina Gršić; V. Kozumplik

    2008-01-01

    Energy production from biomass can reduce „greenhouse effect” and contribute to solving energy security especially in the agricultural households which rely on energy from fossil fuels. In Croatia fuel-cured tobacco is produced on about 5000 ha. Gross income for the whole production is about 180 000 000 kn/year. Flue-cured tobacco is a high energy consuming crop. There are two parts of energy consumption, for mechanization used for the field production (11%) and, energy for bulk-curing (89%)....

  10. EPAct Alternative Fuel Transporation Program - State and Alternative Fuel Provider Fleets: Frequently Asked Questions

    Energy Technology Data Exchange (ETDEWEB)

    None

    2010-03-01

    Factsheet answering frequently asked questions about the U.S. Department of Energy's Alternative Fuel Transportation Program (the Program) that implements provisions of Titles III–V of the Energy Policy Act of 1992 (EPAct). Answers to questions that are frequently asked about the Program by managers of state government and alternative fuel provider fleets are provided in the factsheet.

  11. Alcohol-fueled vehicles: An alternative fuels vehicle, emissions, and refueling infrastructure technology assessment

    Energy Technology Data Exchange (ETDEWEB)

    McCoy, G.A.; Kerstetter, J.; Lyons, J.K. [and others

    1993-06-01

    Interest in alternative motor vehicle fuels has grown tremendously over the last few years. The 1990 Clean Air Act Amendments, the National Energy Policy Act of 1992 and the California Clean Air Act are primarily responsible for this resurgence and have spurred both the motor fuels and vehicle manufacturing industries into action. For the first time, all three U.S. auto manufacturers are offering alternative fuel vehicles to the motoring public. At the same time, a small but growing alternative fuels refueling infrastructure is beginning to develop across the country. Although the recent growth in alternative motor fuels use is impressive, their market niche is still being defined. Environmental regulations, a key driver behind alternative fuel use, is forcing both car makers and the petroleum industry to clean up their products. As a result, alternative fuels no longer have a lock on the clean air market and will have to compete with conventional vehicles in meeting stringent future vehicle emission standards. The development of cleaner burning gasoline powered vehicles has signaled a shift in the marketing of alternative fuels. While they will continue to play a major part in the clean vehicle market, alternative fuels are increasingly recognized as a means to reduce oil imports. This new role is clearly defined in the National Energy Policy Act of 1992. The Act identifies alternative fuels as a key strategy for reducing imports of foreign oil and mandates their use for federal and state fleets, while reserving the right to require private and municipal fleet use as well.

  12. Alternate-Fueled Combustor-Sector Performance

    Science.gov (United States)

    Thomas, Anna E.; Saxena, Nikita T.; Shouse, Dale T.; Neuroth, Craig; Hendricks, Robert C.; Lynch, Amy; Frayne, Charles W.; Stutrud, Jeffrey S.; Corporan, Edwin; Hankins, Terry

    2013-01-01

    In order to realize alternative fueling for military and commercial use, the industry has set forth guidelines that must be met by each fuel. These aviation fueling requirements are outlined in MIL-DTL-83133F(2008) or ASTM D 7566 Annex (2011) standards, and are classified as "drop-in" fuel replacements. This report provides combustor performance data for synthetic-paraffinic-kerosene- (SPK-) type (Fischer-Tropsch (FT)) fuel and blends with JP-8+100, relative to JP-8+100 as baseline fueling. Data were taken at various nominal inlet conditions: 75 psia (0.52 MPa) at 500 degF (533 K), 125 psia (0.86 MPa) at 625 degF (603 K), 175 psia (1.21 MPa) at 725 degF (658 K), and 225 psia (1.55 MPa) at 790 degF (694 K). Combustor performance analysis assessments were made for the change in flame temperatures, combustor efficiency, wall temperatures, and exhaust plane temperatures at 3, 4, and 5 percent combustor pressure drop (DP) for fuel:air ratios (F/A) ranging from 0.010 to 0.025. Significant general trends show lower liner temperatures and higher flame and combustor outlet temperatures with increases in FT fueling relative to JP-8+100 fueling. The latter affects both turbine efficiency and blade and vane lives.

  13. Review of alternative fuels data bases

    Science.gov (United States)

    Harsha, P. T.; Edelman, R. B.

    1983-01-01

    Based on an analysis of the interaction of fuel physical and chemical properties with combustion characteristics and indicators, a ranking of the importance of various fuel properties with respect to the combustion process was established. This ranking was used to define a suite of specific experiments whose objective is the development of an alternative fuels design data base. Combustion characteristics and indicators examined include droplet and spray formation, droplet vaporization and burning, ignition and flame stabilization, flame temperature, laminar flame speed, combustion completion, soot emissions, NOx and SOx emissions, and the fuels' thermal and oxidative stability and fouling and corrosion characteristics. Key fuel property data is found to include composition, thermochemical data, chemical kinetic rate information, and certain physical properties.

  14. A survey of alternative oxygen production technologies

    Science.gov (United States)

    Lueck, Dale E.; Parrish, Clyde F.; Buttner, William J.; Surma, Jan M.

    2001-02-01

    Utilization of the Martian atmosphere for the production of fuel and oxygen has been extensively studied. The baseline fuel production process is a Sabatier reactor, which produces methane and water from carbon dioxide and hydrogen. The oxygen produced from the electrolysis of the water is only half of that needed for methane-based rocket propellant, and additional oxygen is needed for breathing air, fuel cells and other energy sources. Zirconia electrolysis cells for the direct reduction of CO2 are being developed as an alternative means of producing oxygen, but present many challenges for a large-scale oxygen production system. The very high operating temperatures and fragile nature of the cells coupled with fairly high operating voltages leave room for improvement. This paper will survey alternative oxygen production technologies, present data on operating characteristics, materials of construction, and some preliminary laboratory results on attempts to implement each. .

  15. Future fuel production

    NARCIS (Netherlands)

    Jacobs, E.

    2011-01-01

    This paper is written for the TIDO-course AR0532 Smart & Bioclimatic Design Theory. The objective of this paper is to see where the possibilities are in future fuel production in a sustainable way, and the integration of it in the built environment. Technologies are compared and evaluated, and the

  16. Impact of alternate fuels on industrial refractories and refractory insulation applications. An Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Wei, G.C.; Tennery, V.J.

    1976-09-01

    The effects of use of alternate fuels such as distillate oils, residual oils, coal, producer gas, and electricity on refractory insulation are evaluated. Sections are included on alternate fuels for 1976 to 1980, assessment by industry of fuel conversion impact on industrial refractories in the period 1976 to 1980, interactions of alternate fuel combustion products with refractories and refractory insulation, and analysis of degradation mechanisms in refractories and refractory materials. (JRD)

  17. Solid Oxide Fuel Cells Operating on Alternative and Renewable Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiaoxing; Quan, Wenying; Xiao, Jing; Peduzzi, Emanuela; Fujii, Mamoru; Sun, Funxia; Shalaby, Cigdem; Li, Yan; Xie, Chao; Ma, Xiaoliang; Johnson, David; Lee, Jeong; Fedkin, Mark; LaBarbera, Mark; Das, Debanjan; Thompson, David; Lvov, Serguei; Song, Chunshan

    2014-09-30

    This DOE project at the Pennsylvania State University (Penn State) initially involved Siemens Energy, Inc. to (1) develop new fuel processing approaches for using selected alternative and renewable fuels – anaerobic digester gas (ADG) and commercial diesel fuel (with 15 ppm sulfur) – in solid oxide fuel cell (SOFC) power generation systems; and (2) conduct integrated fuel processor – SOFC system tests to evaluate the performance of the fuel processors and overall systems. Siemens Energy Inc. was to provide SOFC system to Penn State for testing. The Siemens work was carried out at Siemens Energy Inc. in Pittsburgh, PA. The unexpected restructuring in Siemens organization, however, led to the elimination of the Siemens Stationary Fuel Cell Division within the company. Unfortunately, this led to the Siemens subcontract with Penn State ending on September 23rd, 2010. SOFC system was never delivered to Penn State. With the assistance of NETL project manager, the Penn State team has since developed a collaborative research with Delphi as the new subcontractor and this work involved the testing of a stack of planar solid oxide fuel cells from Delphi.

  18. The causes and effects of the Alternative Motor Fuels Act

    Science.gov (United States)

    Liu, Yimin

    The corporate average fuel economy (CAFE) standard is the major policy tool to improve the fleet average miles per gallon of automobile manufacturers in the U.S. The Alternative Motor Fuels Act (AMFA) provides special treatment in calculating the fuel economy of alternative fuel vehicles to give manufacturers CAFE incentives to produce more alternative fuel vehicles. AMFA has as its goals an increase in the production of alternative fuel vehicles and a decrease in gasoline consumption and greenhouse gas emissions. This dissertation examines theoretically the effects of the program set up under AMFA. It finds that, under some conditions, this program may actually increase gasoline consumption and greenhouse gas emissions. The dissertation also uses hedonic techniques to examine whether the Alternative Motor Fuels Act (AMFA) has a significant effect on the implicit price of fuel economy and whether the marginal value of vehicle fuel efficiency changes over time. It estimates the change of implicit price in miles per gallon after the production of alternative fuel vehicles (AFVs). Results indicate that every year consumers may evaluate vehicle fuel economy differently, and that since AFVs came to the market, the marginal value of fuel economy from specific companies producing AFVs has decreased. This finding suggests that since the AMFA provides extra Corporate Average Fuel Economy (CAFE) credit for those automakers producing AFVs, the automakers can take advantage of the incentive to produce more profitable conventional vehicles and meet CAFE standards without improving the fleet fuel economy. In this way, manufacturers who produce AFVs are willing to offer a lower price for the fuel economy under the AMFA. Additionally, this paper suggests that the flexible fuel vehicles (FFVs) on the market are not significantly more expensive than comparable conventional vehicles, even if FFVs are also able to run on an alternative fuel and may cost more than conventional vehicles

  19. Pulse Detonation Assessment for Alternative Fuels

    Directory of Open Access Journals (Sweden)

    Muhammad Hanafi Azami

    2017-03-01

    Full Text Available The higher thermodynamic efficiency inherent in a detonation combustion based engine has already led to considerable interest in the development of wave rotor, pulse detonation, and rotating detonation engine configurations as alternative technologies offering improved performance for the next generation of aerospace propulsion systems, but it is now important to consider their emissions also. To assess both performance and emissions, this paper focuses on the feasibility of using alternative fuels in detonation combustion. Thus, the standard aviation fuels Jet-A, Acetylene, Jatropha Bio-synthetic Paraffinic Kerosene, Camelina Bio-synthetic Paraffinic Kerosene, Algal Biofuel, and Microalgae Biofuel are all asessed under detonation combustion conditions. An analytical model accounting for the Rankine-Hugoniot Equation, Rayleigh Line Equation, and Zel’dovich–von Neumann–Doering model, and taking into account single step chemistry and thermophysical properties for a stoichiometric mixture, is applied to a simple detonation tube test case configuration. The computed pressure rise and detonation velocity are shown to be in good agreement with published literature. Additional computations examine the effects of initial pressure, temperature, and mass flux on the physical properties of the flow. The results indicate that alternative fuels require higher initial mass flux and temperature to detonate. The benefits of alternative fuels appear significant.

  20. Spent Nuclear Fuel Alternative Technology Decision Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Shedrow, C.B.

    1999-11-29

    The Westinghouse Savannah River Company (WSRC) made a FY98 commitment to the Department of Energy (DOE) to recommend a technology for the disposal of aluminum-based spent nuclear fuel (SNF) at the Savannah River Site (SRS). The two technologies being considered, direct co-disposal and melt and dilute, had been previously selected from a group of eleven potential SNF management technologies by the Research Reactor Spent Nuclear Fuel Task Team chartered by the DOE''s Office of Spent Fuel Management. To meet this commitment, WSRC organized the SNF Alternative Technology Program to further develop the direct co-disposal and melt and dilute technologies and ultimately provide a WSRC recommendation to DOE on a preferred SNF alternative management technology.

  1. Utilization of waste tires as alternative fuel in cement plant

    OpenAIRE

    2016-01-01

    Cement industry is regulated by legislation in which various measures are specified for prevention and reduction of air pollution as well as protection of human health, due to atmospheric emissions, which occur during cement production. Legislation also holds emission limit values for co-incineration of wastes i.e. alternative fuels. Waste tires as an alternative fuel can be co-incinerated i.e. co-processed in cement plants, where the high calorific value of the rubber is used to substitute f...

  2. Alternative Crops and Biofuel Production

    Energy Technology Data Exchange (ETDEWEB)

    Kenkel, Philip [Oklahoma State Univ., Stillwater, OK (United States); Holcomb, Rodney B. [Oklahoma State Univ., Stillwater, OK (United States)

    2013-03-01

    In order for the biofuel industry to meet the RFS benchmarks for biofuels, new feedstock sources and production systems will have to be identified and evaluated. The Southern Plains has the potential to produce over a billion gallons of biofuels from regionally produced alternative crops, agricultural residues, and animal fats. While information on biofuel conversion processes is available, it is difficult for entrepreneurs, community planners and other interested individuals to determine the feasibility of biofuel processes or to match production alternatives with feed stock availability and community infrastructure. This project facilitates the development of biofuel production from these regionally available feed stocks. Project activities are concentrated in five major areas. The first component focused on demonstrating the supply of biofuel feedstocks. This involves modeling the yield and cost of production of dedicated energy crops at the county level. In 1991 the DOE selected switchgrass as a renewable source to produce transportation fuel after extensive evaluations of many plant species in multiple location (Caddel et al,. 2010). However, data on the yield and cost of production of switchgrass are limited. This deficiency in demonstrating the supply of biofuel feedstocks was addressed by modeling the potential supply and geographic variability of switchgrass yields based on relationship of available switchgrass yields to the yields of other forage crops. This model made it possible to create a database of projected switchgrass yields for five different soil types at the county level. A major advantage of this methodology is that the supply projections can be easily updated as improved varieties of switchgrass are developed and additional yield data becomes available. The modeling techniques are illustrated using the geographic area of Oklahoma. A summary of the regional supply is then provided.

  3. Utilization of Alternative Fuels in Cement Pyroprocessing : the Messebo Factory case study in Ethiopia

    OpenAIRE

    Ebuy Teka, Axumawi

    2015-01-01

    Energy costs and environmental standards encouraged cement manufacturers worldwide to evaluate to what extent conventional fuels (Furnace oil, Coal and Petcock) can be replaced by alternative fuels in cement production, i.e. biomass or processed waste materials like sewage sludge, MSW (municipal solid waste), Refuse Derived Fuels (RDF), Tire Derived Fuel (TDF), Plastic Derived Fuel (PDF), Biomass Derived Fuels (BDF), meat and bone meal (MBM), etc.  High temperature of >1500 C, long residen...

  4. Systems impacts of spent fuel disassembly alternatives

    Energy Technology Data Exchange (ETDEWEB)

    1984-07-01

    Three studies were completed to evaluate four alternatives to the disposal of intact spent fuel assemblies in a geologic repository. A preferred spent fuel waste form for disposal was recommended on consideration of (1) package design and fuel/package interaction, (2) long-term, in-repository performance of the waste form, and (3) overall process performance and costs for packaging, handling, and emplacement. The four basic alternative waste forms considered were (1) end fitting removal, (2) fission gas venting, (3) disassembly and close packing, and (4) shearing/immobilization. None of the findings ruled out any alternative on the basis of waste package considerations or long-term performance of the waste form. The third alternative offers flexibility in loading that may prove attractive in the various geologic media under consideration, greatly reduces the number of packages, and has the lowest unit cost. These studies were completed in October, 1981. Since then Westinghouse Electric Corporation and the Office of Nuclear Waste Isolation have completed studies in related fields. This report is now being published to provide publicly the background material that is contained within. 47 references, 28 figures, 31 tables.

  5. Biodiesel production from inedible animal tallow and an experimental investigation of its use as alternative fuel in a direct injection diesel engine

    Energy Technology Data Exchange (ETDEWEB)

    Oener, Cengiz [Technical Education Faculty, Automotive Division, Firat University, 23119 Elazig (Turkey); Altun, Sehmus [Technical Education Faculty, Automotive Division, Batman University, 72060 Batman (Turkey)

    2009-10-15

    In this study, a substitute fuel for diesel engines was produced from inedible animal tallow and its usability was investigated as pure biodiesel and its blends with petroleum diesel fuel in a diesel engine. Tallow methyl ester as biodiesel fuel was prepared by base-catalyzed transesterification of the fat with methanol in the presence of NaOH as catalyst. Fuel properties of methyl ester, diesel fuel and blends of them (5%, 20% and 50% by volume) were determined. Viscosity and density of fatty acid methyl ester have been found to meet ASTM D6751 and EN 14214 specifications. Viscosity and density of tallow methyl esters are found to be very close to that of diesel. The calorific value of biodiesel is found to be slightly lower than that of diesel. An experimental study was carried out in order to investigate of its usability as alternative fuel of tallow methyl ester in a direct injection diesel engine. It was observed that the addition of biodiesel to the diesel fuel decreases the effective efficiency of engine and increases the specific fuel consumption. This is due to the lower heating value of biodiesel compared to diesel fuel. However, the effective engine power was comparable by biodiesel compared with diesel fuel. Emissions of carbon monoxide (CO), oxides of nitrogen (NO{sub x}), sulphur dioxide (SO{sub 2}) and smoke opacity were reduced around 15%, 38.5%, 72.7% and 56.8%, respectively, in case of tallow methyl esters (B100) compared to diesel fuel. Besides, the lowest CO, NO{sub x} emissions and the highest exhaust temperature were obtained for B20 among all other fuels. The reductions in exhaust emissions made tallow methyl esters and its blends, especially B20 a suitable alternative fuel for diesel and thus could help in controlling air pollution. Based on this study, animal tallow methyl esters and its blends with petroleum diesel fuel can be used a substitute for diesel in direct injection diesel engines without any engine modification. (author)

  6. The Mississippi University Research Consortium for the Utilization of Biomass: Production of Alternative Fuels from Waste Biomass Initiative

    Energy Technology Data Exchange (ETDEWEB)

    Drs. Mark E. Zapp; Todd French; Lewis Brown; Clifford George; Rafael Hernandez; Marvin Salin (from Mississippie State University); Drs. Huey-Min Hwang, Ken Lee, Yi Zhang; Maria Begonia (from Jackson State University); Drs. Clint Williford; Al Mikell (from the University of Mississippi); Drs. Robert Moore; Roger Hester (from the University of Southern Mississippi).

    2009-03-31

    The Mississippi Consortium for the Utilization of Biomass was formed via funding from the US Department of Energy's EPSCoR Program, which is administered by the Office of Basic Science. Funding was approved in July of 1999 and received by participating Mississippi institutions by 2000. The project was funded via two 3-year phases of operation (the second phase was awarded based on the high merits observed from the first 3-year phase), with funding ending in 2007. The mission of the Consortium was to promote the utilization of biomass, both cultured and waste derived, for the production of commodity and specialty chemicals. These scientific efforts, although generally basic in nature, are key to the development of future industries within the Southeastern United States. In this proposal, the majority of the efforts performed under the DOE EPSCoR funding were focused primarily toward the production of ethanol from lignocellulosic feedstocks and biogas from waste products. However, some of the individual projects within this program investigated the production of other products from biomass feeds (i.e. acetic acid and biogas) along with materials to facilitate the more efficient production of chemicals from biomass. Mississippi is a leading state in terms of raw biomass production. Its top industries are timber, poultry production, and row crop agriculture. However, for all of its vast amounts of biomass produced on an annual basis, only a small percentage of the biomass is actually industrially produced into products, with the bulk of the biomass being wasted. This situation is actually quite representative of many Southeastern US states. The research and development efforts performed attempted to further develop promising chemical production techniques that use Mississippi biomass feedstocks. The three processes that were the primary areas of interest for ethanol production were syngas fermentation, acid hydrolysis followed by hydrolyzate fermentation, and

  7. The Mississippi University Research Consortium for the Utilization of Biomass: Production of Alternative Fuels from Waste Biomass Initiative

    Energy Technology Data Exchange (ETDEWEB)

    Drs. Mark E. Zapp; Todd French; Lewis Brown; Clifford George; Rafael Hernandez; Marvin Salin (from Mississippie State University); Drs. Huey-Min Hwang, Ken Lee, Yi Zhang; Maria Begonia (from Jackson State University); Drs. Clint Williford; Al Mikell (from the University of Mississippi); Drs. Robert Moore; Roger Hester (from the University of Southern Mississippi).

    2009-03-31

    The Mississippi Consortium for the Utilization of Biomass was formed via funding from the US Department of Energy's EPSCoR Program, which is administered by the Office of Basic Science. Funding was approved in July of 1999 and received by participating Mississippi institutions by 2000. The project was funded via two 3-year phases of operation (the second phase was awarded based on the high merits observed from the first 3-year phase), with funding ending in 2007. The mission of the Consortium was to promote the utilization of biomass, both cultured and waste derived, for the production of commodity and specialty chemicals. These scientific efforts, although generally basic in nature, are key to the development of future industries within the Southeastern United States. In this proposal, the majority of the efforts performed under the DOE EPSCoR funding were focused primarily toward the production of ethanol from lignocellulosic feedstocks and biogas from waste products. However, some of the individual projects within this program investigated the production of other products from biomass feeds (i.e. acetic acid and biogas) along with materials to facilitate the more efficient production of chemicals from biomass. Mississippi is a leading state in terms of raw biomass production. Its top industries are timber, poultry production, and row crop agriculture. However, for all of its vast amounts of biomass produced on an annual basis, only a small percentage of the biomass is actually industrially produced into products, with the bulk of the biomass being wasted. This situation is actually quite representative of many Southeastern US states. The research and development efforts performed attempted to further develop promising chemical production techniques that use Mississippi biomass feedstocks. The three processes that were the primary areas of interest for ethanol production were syngas fermentation, acid hydrolysis followed by hydrolyzate fermentation, and

  8. Effect of alternative fuel properties on NOx reduction

    OpenAIRE

    Axelsen, Ernst Petter; Tokheim, Lars-André; Bjerketvedt, Dag

    2002-01-01

    Today we see a substantial increase in the use of alternative fuels in the cement industry. The prospect of reduction in fuel costs and the environmental benefits of waste to energy conversion are the driving forces. For several years Norcem have steadily increased their use of alternative fuels such as refuse derived fuel (RDF), liquid hazardous waste (LHW), solid hazardous waste (SHW), animal meal (AM) and waste oil (WO). Alternative fuels behave differently compared to e.g. coa...

  9. Valuation of flexible solutions with alternative fuel cell energy sources

    Energy Technology Data Exchange (ETDEWEB)

    Haahtela, T.; Surakka, T.; Malinen, P. [Helsinki Univ. of Technology, Espoo (Finland). BIT Research Centre

    2009-07-01

    Fuel cells are an emerging technology with high potential, but also with significant market uncertainty. Fuel cells are currently in the transition from field trials to commercial introduction, and firms need to consider whether the technology fulfils the reliability and cost requirements of their current and upcoming products. This paper presented a framework to assist managers in finding the suitable valuation method for comparing different alternatives with emerging fuel cell technology. The dynamic valuation approaches of decision tree analysis, real options and system dynamics were discussed as they help in choosing the optimal timing and product structure over a long time period. Three examples of applications with fuel cells were briefly presented. The paper also addressed how the suggested valuation methods could be applied to them. These applications included maritime buoys; removable crisis management energy source container; and electrification of public transportation. It was concluded that the fuel cell technology has already become economically feasible in certain application areas. Improving technical reliability and cost reductions will make fuel cells even more competitive alternatives in new application areas. 9 refs., 1 tab., 1 fig.

  10. Spent Nuclear Fuel Alternative Technology Risk Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Perella, V.F.

    1999-11-29

    A Research Reactor Spent Nuclear Fuel Task Team (RRTT) was chartered by the Department of Energy (DOE) Office of Spent Fuel Management with the responsibility to recommend a course of action leading to a final technology selection for the interim management and ultimate disposition of the foreign and domestic aluminum-based research reactor spent nuclear fuel (SNF) under DOE''s jurisdiction. The RRTT evaluated eleven potential SNF management technologies and recommended that two technologies, direct co-disposal and an isotopic dilution alternative, either press and dilute or melt and dilute, be developed in parallel. Based upon that recommendation, the Westinghouse Savannah River Company (WSRC) organized the SNF Alternative Technology Program to further develop the direct co-disposal and melt and dilute technologies and provide a WSRC recommendation to DOE for a preferred SNF alternative management technology. A technology risk assessment was conducted as a first step in this recommendation process to determine if either, or both, of the technologies posed significant risks that would make them unsuitable for further development. This report provides the results of that technology risk assessment.

  11. INVESTIGATION OF LAMINAR FLAME SPEED OF ALTERNATIVE LIQUID FUEL BLENDS

    OpenAIRE

    2016-01-01

    The rapid fluctuation in oil prices and increased demand of clean fuels to reduce emissions has forced the researchers to find alternative fuels that can give the same or better overall fuel characteristics. This thesis aims at looking into the prospects of Gas to Liquid (GTL) fuel as an alternative fuel for Internal Combustion Engines (ICEs), by investigating the flame speed of GTL fuel and its 50/50 (by volume) blend with conventional diesel. The tests were conducted in a new...

  12. A life-cycle comparison of alternative automobile fuels.

    Science.gov (United States)

    MacLean, H L; Lave, L B; Lankey, R; Joshi, S

    2000-10-01

    We examine the life cycles of gasoline, diesel, compressed natural gas (CNG), and ethanol (C2H5OH)-fueled internal combustion engine (ICE) automobiles. Port and direct injection and spark and compression ignition engines are examined. We investigate diesel fuel from both petroleum and biosources as well as C2H5OH from corn, herbaceous bio-mass, and woody biomass. The baseline vehicle is a gasoline-fueled 1998 Ford Taurus. We optimize the other fuel/powertrain combinations for each specific fuel as a part of making the vehicles comparable to the baseline in terms of range, emissions level, and vehicle lifetime. Life-cycle calculations are done using the economic input-output life-cycle analysis (EIO-LCA) software; fuel cycles and vehicle end-of-life stages are based on published model results. We find that recent advances in gasoline vehicles, the low petroleum price, and the extensive gasoline infrastructure make it difficult for any alternative fuel to become commercially viable. The most attractive alternative fuel is compressed natural gas because it is less expensive than gasoline, has lower regulated pollutant and toxics emissions, produces less greenhouse gas (GHG) emissions, and is available in North America in large quantities. However, the bulk and weight of gas storage cylinders required for the vehicle to attain a range comparable to that of gasoline vehicles necessitates a redesign of the engine and chassis. Additional natural gas transportation and distribution infrastructure is required for large-scale use of natural gas for transportation. Diesel engines are extremely attractive in terms of energy efficiency, but expert judgment is divided on whether these engines will be able to meet strict emissions standards, even with reformulated fuel. The attractiveness of direct injection engines depends on their being able to meet strict emissions standards without losing their greater efficiency. Biofuels offer lower GHG emissions, are sustainable, and

  13. 18 CFR 281.304 - Computation of alternative fuel volume.

    Science.gov (United States)

    2010-04-01

    ... alternative fuel volume. 281.304 Section 281.304 Conservation of Power and Water Resources FEDERAL ENERGY... Determination § 281.304 Computation of alternative fuel volume. (a) General rule. For purposes of § 281.208(b)(1)(i)(B), and § 281.305: (1) Alternative fuel volume of an essential agricultural user is equal to...

  14. Alternate-Fuel Vehicles and Their Application in Schools.

    Science.gov (United States)

    Taggart, Chip

    1991-01-01

    Alternative fuels are becoming increasingly attractive from environmental, energy independence, and economic perspectives. Addresses the following topics: (1) federal and state legislation; (2) alternative fuels and their attributes; (3) practical experience with alternative-fuel vehicles in pupil transportation; and (4) options for school…

  15. Proceedings of the 1996 Windsor workshop on alternative fuels

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    This document contains information which was presented at the 1996 Windsor Workshop on Alternative Fuels. Topics include: international links; industry topics and infrastructure issues; propane; engine developments; the cleanliness of alternative fuels; heavy duty alternative fuel engines; California zev commercialization efforts; and in-use experience.

  16. Fourth annual report to Congress, Federal Alternative Motor Fuels Programs

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    This annual report to Congress presents the current status of the alternative fuel vehicle programs being conducted across the country in accordance with the Alternative Motor Fuels Act of 1988. These programs, which represent the most comprehensive data collection effort ever undertaken on alternative fuels, are beginning their fifth year. This report summarizes tests and results from the fourth year.

  17. 75 FR 29605 - Clean Alternative Fuel Vehicle and Engine Conversions

    Science.gov (United States)

    2010-05-26

    ... Exceptions b. Heavy-Duty Engine Types and Gross Vehicle Weight Classes c. Dual-Fuel Standards 2. Useful Life... first type, dedicated alternative fueled vehicles or engines, are only capable of operating on one type of fuel. Dual-fueled vehicles or engines, the second type, can operate on two types of fuel,...

  18. Preliminary ecotoxicity assessment of new generation alternative fuels in seawater.

    Science.gov (United States)

    Rosen, Gunther; Dolecal, Renee E; Colvin, Marienne A; George, Robert D

    2014-06-01

    The United States Navy (USN) is currently demonstrating the viability of environmentally sustainable alternative fuels to power its fleet comprised of aircraft and ships. As with any fuel used in a maritime setting, there is potential for introduction into the environment through transport, storage, and spills. However, while alternative fuels are often presumed to be eco-friendly relative to conventional petroleum-based fuels, their environmental fate and effects on marine environments are essentially unknown. Here, standard laboratory-based toxicity experiments were conducted for two alternative fuels, jet fuel derived from Camelina sativa (wild flax) seeds (HRJ5) and diesel fuel derived from algae (HRD76), and two conventional counterparts, jet fuel (JP5) and ship diesel (F76). Initial toxicity tests performed on water-accommodated fractions (WAF) from neat fuels partitioned into seawater, using four standard marine species in acute and chronic/sublethal tests, indicate that the alternative fuels are significantly less toxic to marine organisms.

  19. The impact of alternate fuels on future candidate automotive engines

    Energy Technology Data Exchange (ETDEWEB)

    Rahnke, C.J.; Nichols, R.J.

    1982-06-01

    The thermal efficiency that could occur in the future for a variety of automotive engine candidates operating on conventional and alternate fuels is projected based on current automotive engine development trends and the special characteristics of the various alternate fuels. The multi-fuel engine candidates include mixture cycle and direct injection reciprocating engines, as well as adiabatic turbocompound engines and advanced gas turbine and Stirling engines. The alternate fuels considered are propane, methanol, ethanol, diesel and methane.

  20. Engineering organisms for industrial fuel production.

    Science.gov (United States)

    Berry, David A

    2010-01-01

    Volatile fuel costs, the need to reduce greenhouse gas emissions and fuel security concerns are driving efforts to produce sustainable renewable fuels and chemicals. Petroleum comes from sunlight, CO(2) and water converted via a biological intermediate into fuel over a several million year timescale. It stands to reason that using biology to short-circuit this time cycle offers an attractive alternative--but only with relevant products at or below market prices. The state of the art of biological engineering over the past five years has progressed to allow for market needs to drive innovation rather than trying to adapt existing approaches to the market. This report describes two innovations using synthetic biology to dis-intermediate fuel production. LS9 is developing a means to convert biological intermediates such as cellulosic hydrolysates into drop-in hydrocarbon product replacements such as diesel. Joule Unlimited is pioneering approaches to eliminate feedstock dependency by efficiently capturing sunlight, CO(2) and water to produce fuels and chemicals. The innovations behind these companies are built with the market in mind, focused on low cost biosynthesis of existing products of the petroleum industry. Through successful deployment of technologies such as those behind LS9 and Joule Unlimited, alternative sources of petroleum products will mitigate many of the issues faced with our petroleum-based economy.

  1. Future Fossil Fuel Alternative; DME (A review)

    OpenAIRE

    Erdener, Hülya; Arinan, Ayca; Orman, Sultan

    2016-01-01

    The world energy consumption is steadily growing with the industrial improvements of the developing countries and the readily available fossil fuel reserves lack in fulfilling this energy requirement. The depletion of the easily achievable reserves; gives rise to the concept of oil production from oil shale and tar sands. However, the high cost and the operational difficulties stand as the major drawbacks in front of these technologies. Along with these circumstances, and the environmental co...

  2. Development of alternative fuels from coal-derived syngas

    Energy Technology Data Exchange (ETDEWEB)

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products' laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively benign'' system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE's program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  3. Southern Nevada Alternative Fuels Demonstration Project

    Energy Technology Data Exchange (ETDEWEB)

    Hyde, Dan; Fast, Matthew

    2009-12-31

    The Southern Nevada Alternative Fuels Program is designed to demonstrate, in a day-to-day bus operation, the reliability and efficiency of a hydrogen bus operation under extreme conditions. By using ICE technology and utilizing a virtually emission free fuel, benefits to be derived include air quality enhancement and vehicle performance improvements from domestically produced, renewable energy sources. The project objective is to help both Ford and the City demonstrate and evaluate the performance characteristics of the E-450 H2ICE shuttle buses developed by Ford, which use a 6.8-liter supercharged Triton V-10 engine with a hydrogen storage system equivalent to 29 gallons of gasoline. The technology used during the demonstration project in the Ford buses is a modified internal combustion engine that allows the vehicles to run on 100% hydrogen fuel. Hydrogen gives a more thorough fuel burn which results in more power and responsiveness and less pollution. The resultant emissions from the tailpipe are 2010 Phase II compliant with NO after treatment. The City will lease two of these E-450 H2ICE buses from Ford for two years. The buses are outfitted with additional equipment used to gather information needed for the evaluation. Performance, reliability, safety, efficiency, and rider comments data will be collected. The method of data collection will be both electronically and manually. Emissions readings were not obtained during the project. The City planned to measure the vehicle exhaust with an emissions analyzer machine but discovered the bus emission levels were below the capability of their machine. Passenger comments were solicited on the survey cards. The majority of comments were favorable. The controllable issues encountered during this demonstration project were mainly due to the size of the hydrogen fuel tanks at the site and the amount of fuel that could be dispensed during a specified period of time. The uncontrollable issues encountered during this

  4. Pyrolysis decomposition of tamarind seed for alternative fuel.

    Science.gov (United States)

    Kader, M A; Islam, M R; Parveen, M; Haniu, H; Takai, K

    2013-12-01

    The conversion of tamarind seed into bio-oil by pyrolysis has been taken into consideration in the present work. The major components of the system were fixed bed fire-tube heating reactor, liquid condenser and collector. The crushed tamarind seed in particle form was pyrolyzed in an electrically heated fixed bed reactor. The products were liquid, char and gasses. The parameters varied were reactor temperature, running time, gas flow rate and feed particle size. The maximum liquid yield was 45 wt% at 400°C for a feed size of 3200 μm diameter at a gas flow rate of 6l/min with a running time of 30 min. The obtained pyrolysis liquid at these optimum process conditions were analyzed for physical and chemical properties to be used as an alternative fuel. The results show the potential of tamarind seed as an important source of alternative fuel and chemicals as well.

  5. Hawaii alternative fuels utilization program. Phase 3, final report

    Energy Technology Data Exchange (ETDEWEB)

    Kinoshita, C.M.; Staackmann, M.

    1996-08-01

    The Hawaii Alternative Fuels Utilization Program originated as a five-year grant awarded by the US Department of Energy (USDOE) to the Hawaii Natural Energy Institute (HNEI) of the University of Hawaii at Manoa. The overall program included research and demonstration efforts aimed at encouraging and sustaining the use of alternative (i.e., substitutes for gasoline and diesel) ground transportation fuels in Hawaii. Originally, research aimed at overcoming technical impediments to the widespread adoption of alternative fuels was an important facet of this program. Demonstration activities centered on the use of methanol-based fuels in alternative fuel vehicles (AFVs). In the present phase, operations were expanded to include flexible fuel vehicles (FFVs) which can operate on M85 or regular unleaded gasoline or any combination of these two fuels. Additional demonstration work was accomplished in attempting to involve other elements of Hawaii in the promotion and use of alcohol fuels for ground transportation in Hawaii.

  6. Liquid alternative diesel fuels with high hydrogen content

    Energy Technology Data Exchange (ETDEWEB)

    Hancsok, Jenoe; Varga, Zoltan; Eller, Zoltan; Poelczmann, Gyoergy [Pannonia Univ., Veszprem (Hungary). MOL Dept. of Hydrocarbon Processing; Kasza, Tamas [MOL Hungarian Oil and Gas Plc., Szazhalombatta (Hungary)

    2013-06-01

    Mobility is a keystone of the sustainable development. In the operation of the vehicles as the tools of mobility internal combustion engines, so thus Diesel engines will play a remarkable role in the next decades. Beside fossil fuels - used for power these engines - liquid alternative fuels have higher and higher importance, because of their known advantages. During the presentation the categorization possibilities based on the chronology of their development and application will be presented. The importance of fuels with high hydrogen content will be reviewed. Research and development activity in the field of such kind of fuels will be presented. During this developed catalytic systems and main performance properties of the product will be presented which were obtained in case of biogasoils produced by special hydrocracking of natural triglycerides and in case of necessity followed by isomerization; furthermore in case of synthetic biogasoils obtained by the isomerization hydrocracking of Fischer-Tropsch paraffins produced from biomass based synthesis gas. Excellent combustion properties (cetane number > 65-75), good cold flow properties and reduced harmful material emission due to the high hydrogen content (C{sub n}H{sub 2n+2}) are highlighted. Finally production possibilities of linear and branched paraffins based on lignocelluloses are briefly reviewed. Summarizing it was concluded that liquid hydrocarbons with high isoparaffin content are the most suitable fuels regarding availability, economical and environmental aspects, namely the sustainable development. (orig.)

  7. Ignition Delay Properties of Alternative Fuels with Navy-Relevant Diesel Injectors

    Science.gov (United States)

    2014-06-01

    and palm oil , vegetable oil , and animal fats [8]. Of 5 particular interest in the field of HRD production is microalgae [9]. Algae-based fuels are...PROPERTIES OF ALTERNATIVE FUELS WITH NAVY-RELEVANT DIESEL INJECTORS by Andrew J. Rydalch June 2014 Thesis Advisor: Christopher M. Brophy...REPORT TYPE AND DATES COVERED Master’s Thesis 4. TITLE AND SUBTITLE IGNITION DELAY PROPERTIES OF ALTERNATIVE FUELS WITH NAVY- RELEVANT DIESEL

  8. Alternative fuels for vehicles fleet demonstration program. Final report, volume 2: Appendices

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-06-01

    The Alternative Fuels for Vehicles Fleet Demonstration Program (AFV-FDP) was a multiyear effort to collect technical data for use in determining the costs and benefits of alternative-fuel vehicles (AFVs) in typical applications in New York State. This report, Volume 2, includes 13 appendices to Volume 1 that expand upon issues raised therein. Volume 1 provides: (1) Information about the purpose and scope of the AFV-FDP; (2) A summary of AFV-FDP findings organized on the basis of vehicle type and fuel type; (3) A short review of the status of AFV technology development, including examples of companies in the State that are active in developing AFVs and AFV components; and (4) A brief overview of the status of AFV deployment in the State. Volume 3 provides expanded reporting of AFV-FDP technical details, including the complete texts of the brochure Garage Guidelines for Alternative Fuels and the technical report Fleet Experience Survey Report, plus an extensive glossary of AFV terminology. The appendices cover a wide range of issues including: emissions regulations in New York State; production and health effects of ozone; vehicle emissions and control systems; emissions from heavy-duty engines; reformulated gasoline; greenhouse gases; production and characteristics of alternative fuels; the Energy Policy Act of 1992; the Clean Fuel Fleet Program; garage design guidelines for alternative fuels; surveys of fleet managers using alternative fuels; taxes on conventional and alternative fuels; and zero-emission vehicle technology.

  9. Low Floor Americans with Disabilities Compliant Alternate Fuel Vehicle Project

    Energy Technology Data Exchange (ETDEWEB)

    James Bartel

    2004-11-26

    This project developed a low emission, cost effective, fuel efficient, medium-duty community/transit shuttle bus that meets American's with Disabilities Act (ADA) requirements and meets National Energy Policy Act requirements (uses alternative fuel). The Low Profile chassis, which is the basis of this vehicle is configured to be fuel neutral to accommodate various alternative fuels. Demonstration of the vehicle in Yellowstone Park in summer (wheeled operation) and winter (track operation) demonstrated the feasibility and flexibility for this vehicle to provide year around operation throughout the Parks system as well as normal transit operation. The unique configuration of the chassis which provides ADA access with a simple ramp and a flat floor throughout the passenger compartment, provides maximum access for all passengers as well as maximum flexibility to configure the vehicle for each application. Because this product is derived from an existing medium duty truck chassis, the completed bus is 40-50% less expensive than existing low floor transit buses, with the reliability and durability of OEM a medium duty truck.

  10. Vehicle conversion to hybrid gasoline/alternative fuel operation

    Science.gov (United States)

    Donakowski, T. D.

    1982-01-01

    The alternative fuels considered are compressed natural gas (CNG), liquefied natural gas (LNG), liquid petroleum gas (LPG), and methanol; vehicles were required to operate in a hybrid or dual-fuel gasoline/alternative fuel mode. Economic feasibility was determined by comparing the costs of continued use of gasoline fuel with the use of alternative fuel and retrofitted equipment. Differences in the amounts of future expenditures are adjusted by means of a total life-cycle costing. All fuels studied are technically feasible to allow a retrofit conversion to hybrid gasoline/alternative fuel operation except for methanol. Conversion to LPG is not recommended for vehicles with more than 100,000 km (60,000 miles) of prior use. Methanol conversion is not recommended for vehicles with more than 50,00 km (30,000 miles).

  11. Alternative Measuring Approaches in Gamma Scanning on Spent Nuclear Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Sihm Kvenangen, Karen

    2007-06-15

    In the future, the demand for energy is predicted to grow and more countries plan to utilize nuclear energy as their source of electric energy. This gives rise to many important issues connected to nuclear energy, such as finding methods that can verify that the spent nuclear fuel has been handled safely and used in ordinary power producing cycles as stated by the operators. Gamma ray spectroscopy is one method used for identification and verification of spent nuclear fuel. In the specific gamma ray spectroscopy method called gamma scanning the gamma radiation from the fission products Cs-137, Cs-134 and Eu-154 are measured in a spent fuel assembly. From the results, conclusions can be drawn about the fuels characteristics. This degree project examines the possibilities of using alternative measuring approaches when using the gamma scanning method. The focus is on examining how to increase the quality of the measured data. How to decrease the measuring time as compared with the present measuring strategy, has also been investigated. The main part of the study comprises computer simulations of gamma scanning measurements. The simulations have been validated with actual measurements on spent nuclear fuel at the central interim storage, Clab. The results show that concerning the quality of the measuring data the conventional strategy is preferable, but with other starting positions and with a more optimized equipment. When focusing on the time aspect, the helical measuring strategy can be an option, but this needs further investigation.

  12. Alternative fuels and chemicals from synthesis gas

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    1998-12-01

    A DOE/PETC funded study was conducted to examine the use of a liquid phase mixed alcohol synthesis (LPMAS) plant to produce gasoline blending ethers. The LPMAS plant was integrated into three utilization scenarios: a coal fed IGCC power plant, a petroleum refinery using coke as a gasification feedstock, and a standalone natural gas fed partial oxidation plant. The objective of the study was to establish targets for the development of catalysts for the LPMAS reaction. In the IGCC scenario, syngas conversions need only be moderate because unconverted syngas is utilized by the combined cycle system. A once through LPMAS plant achieving syngas conversions in the range of 38--49% was found to be suitable. At a gas hourly space velocity of 5,000 sL/Kg-hr and a methanol:isobutanol selectivity ratio of 1.03, the target catalyst productivity ranges from 370 to 460 g iBuOH/Kg-hr. In the petroleum refinery scenario, high conversions ({approximately}95%) are required to avoid overloading the refinery fuel system with low Btu content unconverted syngas. To achieve these high conversions with the low H{sub 2}/CO ratio syngas, a recycle system was required (because of the limit imposed by methanol equilibrium), steam was injected into the LPMAS reactor, and CO{sub 2} was removed from the recycle loop. At the most economical recycle ratio, the target catalyst productivity is 265 g iBuOH/Kg-hr. In the standalone LPMAS scenario, essentially complete conversions are required to achieve a fuel balanced plant. At the most economical recycle ratio, the target catalyst productivity is 285 g iBuOH/Kg-hr. The economics of this scenario are highly dependent on the cost of the natural gas feedstock and the location of the plant. For all three case scenarios, the economics of a LPMAS plant is marginal at current ether market prices. Large improvements over demonstrated catalyst productivity and alcohol selectivity are required.

  13. Engineering cyanobacteria for fuels and chemicals production.

    Science.gov (United States)

    Zhou, Jie; Li, Yin

    2010-03-01

    The world's energy and global warming crises call for sustainable, renewable, carbon-neutral alternatives to replace fossil fuel resources. Currently, most biofuels are produced from agricultural crops and residues, which lead to concerns about food security and land shortage. Compared to the current biofuel production system, cyanobacteria, as autotrophic prokaryotes, do not require arable land and can grow to high densities by efficiently using solar energy, CO(2), water, and inorganic nutrients. Moreover, powerful genetic techniques of cyanobacteria have been developed. For these reasons, cyanobacteria, which carry out oxygenic photosynthesis, are attractive hosts for production of fuels and chemicals. Recently, several chemicals including ethanol, isobutanol and isoprene have been produced by engineered cyanobacteria directly using solar energy, CO(2), and water. Cyanobacterium is therefore a potential novel cell factory for fuels and chemicals production to address global energy security and climate change issues.

  14. DEVELOPMENT OF ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    Energy Technology Data Exchange (ETDEWEB)

    Peter J. Tijrn

    2003-05-31

    This Final Report for Cooperative Agreement No. DE-FC22-95PC93052, the ''Development of Alternative Fuels and Chemicals from Synthesis Gas,'' was prepared by Air Products and Chemicals, Inc. (Air Products), and covers activities from 29 December 1994 through 31 July 2002. The overall objectives of this program were to investigate potential technologies for the conversion of synthesis gas (syngas), a mixture primarily of hydrogen (H{sub 2}) and carbon monoxide (CO), to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at the LaPorte, Texas Alternative Fuels Development Unit (AFDU). Laboratory work was performed by Air Products and a variety of subcontractors, and focused on the study of the kinetics of production of methanol and dimethyl ether (DME) from syngas, the production of DME using the Liquid Phase Dimethyl Ether (LPDME{trademark}) Process, the conversion of DME to fuels and chemicals, and the production of other higher value products from syngas. Four operating campaigns were performed at the AFDU during the performance period. Tests of the Liquid Phase Methanol (LPMEOH{trademark}) Process and the LPDME{trademark} Process were made to confirm results from the laboratory program and to allow for the study of the hydrodynamics of the slurry bubble column reactor (SBCR) at a significant engineering scale. Two campaigns demonstrated the conversion of syngas to hydrocarbon products via the slurry-phase Fischer-Tropsch (F-T) process. Other topics that were studied within this program include the economics of production of methyl tert-butyl ether (MTBE), the identification of trace components in coal-derived syngas and the means to economically remove these species, and the study of systems for separation of wax from catalyst in the F-T process. The work performed under this Cooperative Agreement has continued to promote the development of technologies that use clean syngas produced

  15. DEVELOPMENT OF ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    Energy Technology Data Exchange (ETDEWEB)

    Peter J. Tijrn

    2003-05-31

    This Final Report for Cooperative Agreement No. DE-FC22-95PC93052, the ''Development of Alternative Fuels and Chemicals from Synthesis Gas,'' was prepared by Air Products and Chemicals, Inc. (Air Products), and covers activities from 29 December 1994 through 31 July 2002. The overall objectives of this program were to investigate potential technologies for the conversion of synthesis gas (syngas), a mixture primarily of hydrogen (H{sub 2}) and carbon monoxide (CO), to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at the LaPorte, Texas Alternative Fuels Development Unit (AFDU). Laboratory work was performed by Air Products and a variety of subcontractors, and focused on the study of the kinetics of production of methanol and dimethyl ether (DME) from syngas, the production of DME using the Liquid Phase Dimethyl Ether (LPDME{trademark}) Process, the conversion of DME to fuels and chemicals, and the production of other higher value products from syngas. Four operating campaigns were performed at the AFDU during the performance period. Tests of the Liquid Phase Methanol (LPMEOH{trademark}) Process and the LPDME{trademark} Process were made to confirm results from the laboratory program and to allow for the study of the hydrodynamics of the slurry bubble column reactor (SBCR) at a significant engineering scale. Two campaigns demonstrated the conversion of syngas to hydrocarbon products via the slurry-phase Fischer-Tropsch (F-T) process. Other topics that were studied within this program include the economics of production of methyl tert-butyl ether (MTBE), the identification of trace components in coal-derived syngas and the means to economically remove these species, and the study of systems for separation of wax from catalyst in the F-T process. The work performed under this Cooperative Agreement has continued to promote the development of technologies that use clean syngas produced

  16. 77 FR 14583 - Notice to Manufacturers of Alternative Fuel Vans

    Science.gov (United States)

    2012-03-12

    ... Federal Aviation Administration Notice to Manufacturers of Alternative Fuel Vans AGENCY: Federal Aviation Administration (FAA), U.S. DOT. ACTION: Notice to Manufacturers of Alternative Fuel Vans. SUMMARY: Projects... American Preferences. The Federal Aviation Administration (FAA) is considering issuing waivers to...

  17. Preferences for alternative fuel vehicles by Dutch local governments

    NARCIS (Netherlands)

    Rijnsoever, F.J. van; Hagen, P.; Willems, M

    2013-01-01

    Using a choice model, we estimate the preferences for alternative fuel vehicles by Dutch local governments. The analysis shows that local governments are willing to pay between 25% and 50% extra for an alternative fuel vehicle without a serious loss of utility. Further, local emissions are an import

  18. A Survey of Alternative Oxygen Production Technologies

    Science.gov (United States)

    Lueck, Dale E.; Parrish, Clyde F.; Buttner, William J.; Surma, Jan M.; Delgado, H. (Technical Monitor)

    2001-01-01

    Utilization of the Martian atmosphere for the production of fuel and oxygen has been extensively studied. The baseline fuel production process is a Sabatier reactor, which produces methane and water from carbon dioxide and hydrogen. The oxygen produced from the electrolysis of the water is only half of that needed for methane-based rocket propellant, and additional oxygen is needed for breathing air, fuel cells and other energy sources. Zirconia electrolysis cells for the direct reduction of CO2 arc being developed as an alternative means of producing oxygen, but present many challenges for a large-scale oxygen production system. The very high operating temperatures and fragile nature of the cells coupled with fairly high operating voltages leave room for improvement. This paper will survey alternative oxygen production technologies, present data on operating characteristics, materials of construction, and some preliminary laboratory results on attempts to implement each. Our goal is to significantly improve upon the characteristics of proposed zirconia cells for oxygen production. To achieve that goal we are looking at electrolytic systems that operate at significantly lower temperatures, preferably below 31C to allow the incorporation of liquid CO2 in the electrolyte. Our preliminary results indicate that such a system will have much higher current densities and have simpler cathode construction than a porous gas feed electrode system. Such a system could be achieved based on nonaqueous electrolytes or ionic liquids. We are focusing our research on the anode reaction that will produce oxygen from a product generated at the cathode using CO2 as the feed. Operation at low temperatures also will open up the full range of polymer and metal materials, allowing a more robust system design to withstand the rigors of flight, landing, and long term unattended operation on the surface of Mars.

  19. Alternative membranes for polymer electrolyte fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Sahu, A.K.; Pitchumani, S.; Sridhar, P.; Shukla, A.K. [Central Electrochemical Research Inst., Karaikudi (India)

    2009-07-01

    Nafion, a perfluoro-sulfonated membrane, is utilized as a membrane electrolyte in polymer electrolyte fuel cells (PEFCs). However, to realize optimum PEFC performance, the Nafion membrane needs to be fully humidified, making the system quite costly. Therefore, in order to solve this problem, alternative membrane electrolytes that could operate under low humidity conditions are needed. This paper reported on composite Nafion membranes with ceramic/inorganic fillers such as silica and mesoporous zirconium phosphate (MZP). Silica was impregnated to the Nafion matrix by a unique water hydrolysis sol-gel route and casted as a composite membrane while MZP, a solid-super-acid-proton-conducting medium as well as water absorbing material was synthesized by a co-assembly technique and impregnated to the Nafion matrix to form a composite membrane. The performance of the PEFCs with Nafion membrane and composite membranes was tested with hydrogen/oxygen gas and hydrogen/air feeds at varying relative humidity (RH) values under ambient conditions. It was concluded that under RH value as low as 18 per cent, the PEFC with Nafion membrane delivers a peak-power density of only 130 mW/square centimeter.

  20. Effects of uncertainty in SAPRC90 rate constants and selected product yields on reactivity adjustment factors for alternative fuel vehicle emissions. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Bergin, M.S.; Russell, A.G.; Yang, Y.J.; Milford, J.B.; Kirchner, F.; Stockwell, W.R.

    1996-07-01

    Tropospheric ozone is formed in the atmosphere by a series of reactions involving volatile organic compounds (VOCs) and nitrogen oxides (NO{sub x}). While NOx emissions are primarily composed of only two compounds, nitrogen oxide (NO) and nitrogen dioxide (NO{sub 2}), there are hundreds of different VOCs being emitted. In general, VOCs promote ozone formation, however, the rate and extent of ozone produced by the individual VOCs varies considerably. For example, it is widely acknowledged that formaldehyde (HCHO) is a very reactive VOC, and produces ozone rapidly and efficiently under most conditions. On the other hand, VOCs such as methane, ethane, propane, and methanol do not react as quickly, and are likely to form less urban ozone than a comparable mass of HCHO. The difference in ozone forming potential is one of the bases for the use of alternative fuels. The fuels considered in this study included compressed natural gas, LPG, mixtures of methanol and gasoline, ethanol and gasoline, and a reformulated gasoline.

  1. Emergency fuels utilization guidebook. Alternative Fuels Utilization Program

    Energy Technology Data Exchange (ETDEWEB)

    1980-08-01

    The basic concept of an emergency fuel is to safely and effectively use blends of specification fuels and hydrocarbon liquids which are free in the sense that they have been commandeered or volunteered from lower priority uses to provide critical transportation services for short-duration emergencies on the order of weeks, or perhaps months. A wide variety of liquid hydrocarbons not normally used as fuels for internal combustion engines have been categorized generically, including limited information on physical characteristics and chemical composition which might prove useful and instructive to fleet operators. Fuels covered are: gasoline and diesel fuel; alcohols; solvents; jet fuels; kerosene; heating oils; residual fuels; crude oils; vegetable oils; gaseous fuels.

  2. Alternative Liquid Fuels Simulation Model (AltSim).

    Energy Technology Data Exchange (ETDEWEB)

    Williams, Ryan; Baker, Arnold Barry; Drennen, Thomas E.

    2009-12-01

    The Alternative Liquid Fuels Simulation Model (AltSim) is a high-level dynamic simulation model which calculates and compares the production and end use costs, greenhouse gas emissions, and energy balances of several alternative liquid transportation fuels. These fuels include: corn ethanol, cellulosic ethanol from various feedstocks (switchgrass, corn stover, forest residue, and farmed trees), biodiesel, and diesels derived from natural gas (gas to liquid, or GTL), coal (coal to liquid, or CTL), and coal with biomass (CBTL). AltSim allows for comprehensive sensitivity analyses on capital costs, operation and maintenance costs, renewable and fossil fuel feedstock costs, feedstock conversion ratio, financial assumptions, tax credits, CO{sub 2} taxes, and plant capacity factor. This paper summarizes the structure and methodology of AltSim, presents results, and provides a detailed sensitivity analysis. The Energy Independence and Security Act (EISA) of 2007 sets a goal for the increased use of biofuels in the U.S., ultimately reaching 36 billion gallons by 2022. AltSim's base case assumes EPA projected feedstock costs in 2022 (EPA, 2009). For the base case assumptions, AltSim estimates per gallon production costs for the five ethanol feedstocks (corn, switchgrass, corn stover, forest residue, and farmed trees) of $1.86, $2.32, $2.45, $1.52, and $1.91, respectively. The projected production cost of biodiesel is $1.81/gallon. The estimates for CTL without biomass range from $1.36 to $2.22. With biomass, the estimated costs increase, ranging from $2.19 per gallon for the CTL option with 8% biomass to $2.79 per gallon for the CTL option with 30% biomass and carbon capture and sequestration. AltSim compares the greenhouse gas emissions (GHG) associated with both the production and consumption of the various fuels. EISA allows fuels emitting 20% less greenhouse gases (GHG) than conventional gasoline and diesels to qualify as renewable fuels. This allows several of the

  3. Alternative Liquid Fuels Simulation Model (AltSim).

    Energy Technology Data Exchange (ETDEWEB)

    Williams, Ryan; Baker, Arnold Barry; Drennen, Thomas E.

    2009-12-01

    The Alternative Liquid Fuels Simulation Model (AltSim) is a high-level dynamic simulation model which calculates and compares the production and end use costs, greenhouse gas emissions, and energy balances of several alternative liquid transportation fuels. These fuels include: corn ethanol, cellulosic ethanol from various feedstocks (switchgrass, corn stover, forest residue, and farmed trees), biodiesel, and diesels derived from natural gas (gas to liquid, or GTL), coal (coal to liquid, or CTL), and coal with biomass (CBTL). AltSim allows for comprehensive sensitivity analyses on capital costs, operation and maintenance costs, renewable and fossil fuel feedstock costs, feedstock conversion ratio, financial assumptions, tax credits, CO{sub 2} taxes, and plant capacity factor. This paper summarizes the structure and methodology of AltSim, presents results, and provides a detailed sensitivity analysis. The Energy Independence and Security Act (EISA) of 2007 sets a goal for the increased use of biofuels in the U.S., ultimately reaching 36 billion gallons by 2022. AltSim's base case assumes EPA projected feedstock costs in 2022 (EPA, 2009). For the base case assumptions, AltSim estimates per gallon production costs for the five ethanol feedstocks (corn, switchgrass, corn stover, forest residue, and farmed trees) of $1.86, $2.32, $2.45, $1.52, and $1.91, respectively. The projected production cost of biodiesel is $1.81/gallon. The estimates for CTL without biomass range from $1.36 to $2.22. With biomass, the estimated costs increase, ranging from $2.19 per gallon for the CTL option with 8% biomass to $2.79 per gallon for the CTL option with 30% biomass and carbon capture and sequestration. AltSim compares the greenhouse gas emissions (GHG) associated with both the production and consumption of the various fuels. EISA allows fuels emitting 20% less greenhouse gases (GHG) than conventional gasoline and diesels to qualify as renewable fuels. This allows several of the

  4. Kiln process impact of alternative solid fuel combustion in the cement kiln main burner - Mathematical modelling and full-scale experiment

    OpenAIRE

    Ariyaratne, Hiromi Wijesinghe; Melaaen, Morten Christian; Tokheim, Lars André; Manjula, Edirisinghe V. P. J.

    2014-01-01

    Increased use of alternative fuels in cement kilns is a trend in the world. However, replacing fossil fuels like coal with different alternative fuels will give various impacts on the overall kiln process due to the fuel characteristics. Hence, it is important to know to what extent the fossil fuels can be replaced by different alternative fuels without severely changing process conditions, product quality or emissions. In the present study, a mass and energy balance for the combustion of dif...

  5. A Primer on Alternative Transportation Fuels

    Science.gov (United States)

    2010-09-01

    for millennia that certain sugars can be fermented (anaerobically decomposed into alcohols and carbon dioxide) in the presence of enzymes (complex...here involves the hydrolysis (decomposition by reaction with water) of cornstarch ( 6 10 5C H O− − ) and the fermentation of the resulting Maltose ( 12...transportation fuels. Fuels made from natural oils are generally referred to as biodiesel fuels. About 95% of biomass oils are triglycerides (three fatty

  6. Ultraclean Fuels Production and Utilization for the Twenty-First Century: Advances toward Sustainable Transportation Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Fox, Elise B.; Liu, Zhong-Wen; Liu, Zhao-Tie

    2013-11-21

    Ultraclean fuels production has become increasingly important as a method to help decrease emissions and allow the introduction of alternative feed stocks for transportation fuels. Established methods, such as Fischer-Tropsch, have seen a resurgence of interest as natural gas prices drop and existing petroleum resources require more intensive clean-up and purification to meet stringent environmental standards. This review covers some of the advances in deep desulfurization, synthesis gas conversion into fuels and feed stocks that were presented at the 245th American Chemical Society Spring Annual Meeting in New Orleans, LA in the Division of Energy and Fuels symposium on "Ultraclean Fuels Production and Utilization".

  7. Regional refining models for alternative fuels using shale and coal synthetic crudes: identification and evaluation of optimized alternative fuels. Annual report, March 20, 1979-March 19, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Sefer, N.R.; Russell, J.A.

    1980-11-01

    The initial phase has been completed in the project to evaluate alternative fuels for highway transportation from synthetic crudes. Three refinery models were developed for Rocky Mountain, Mid-Continent and Great Lakes regions to make future product volumes and qualities forecast for 1995. Projected quantities of shale oil and coal oil syncrudes were introduced into the raw materials slate. Product slate was then varied from conventional products to evaluate maximum diesel fuel and broadcut fuel in all regions. Gasoline supplement options were evaluated in one region for 10% each of methanol, ethanol, MTBE or synthetic naphtha in the blends along with syncrude components. Compositions and qualities of the fuels were determined for the variation in constraints and conditions established for the study. Effects on raw materials, energy consumption and investment costs were reported. Results provide the basis to formulate fuels for laboratory and engine evaluation in future phases of the project.

  8. Alternative Fuel from Biomass:Experiences and Inspirations of Alternative Fuel Production in the United States of America%关于发展生物质替代燃料的讨论--美国替代燃料生产经验对中国的启示

    Institute of Scientific and Technical Information of China (English)

    张丽丽; 张东杰

    2014-01-01

    介绍了美国发展粮食乙醇的历史、现状及世界各国对美国继续发展该产业的担忧和质疑,分析了中国未来大规模发展生物质替代燃料的途径选择:走出一条不同于美国或巴西的发展道路。%The history and current status of grain-based ethanol production in the United States of America is introduced and analyzed , which has raised great anxieties and questions among countries over the world about the future develop -ment of such industry in the United States .It shows that the massive development of alternative fuel from biomass in Chi-na should be in a different path from the United States or Brazil .

  9. Review: Circulation of Inorganic Elements in Combustion of Alternative Fuels in Cement Plants

    DEFF Research Database (Denmark)

    Cortada Mut, Maria del Mar; Nørskov, Linda Kaare; Jappe Frandsen, Flemming

    2015-01-01

    Cement production is an energy-intensive process, which traditionally has been dependent on fossil fuels. However, the use of alternative fuels, i.e., selected waste, biomass, and byproducts with recoverable calorific value, is constantly increasing. Combustion of these fuels is more challenging......, compared to fossil fuels, because of a lack of experience and different chemical and physical properties. When complete oxidation Of fuels in the calciner and main burner is not achieved, they burn in direct contact with the bed material of the rotary kiln, causing local reducing conditions and increasing...

  10. Alternatives to traditional transportation fuels 1994. Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    In this report, alternative and replacement fuels are defined in accordance with the EPACT. Section 301 of the EPACT defines alternative fuels as: methanol, denatured ethanol, and other alcohols; mixtures containing 85% or more (or such other percentage, but not less than 70%, as determined by the Secretary of Energy, by rule, to provide for requirements relating to cold start, safety, or vehicle functions) by volume of methanol, denatured ethanol, and other alcohols with gasoline or other fuels; natural gas; liquefied petroleum gas; hydrogen; coal-derived liquid fuels; fuels (other than alcohol) derived from biological materials; electricity (including electricity from solar energy); and any other fuel the Secretary determines, by rule, is substantially not petroleum and would yield substantial energy security benefits and substantial environmental benefits. The EPACT defines replacement fuels as the portion of any motor fuel that is methanol, ethanol, or other alcohols, natural gas, liquefied petroleum gas, hydrogen, coal-derived liquid fuels, fuels (other than alcohol) derived from biological materials, electricity (including electricity from solar energy), ethers, or any other fuel the Secretary of Energy determines, by rule, is substantially not petroleum and would yield substantial energy security benefits and substantial environmental benefits. This report covers only those alternative and replacement fuels cited in the EPACT that are currently commercially available or produced in significant quantities for vehicle demonstration purposes. Information about other fuels, such as hydrogen and biodiesel, will be included in later reports as those fuels become more widely used. Annual data are presented for 1992 to 1996. Data for 1996 are based on plans or projections for 1996.

  11. 75 FR 26165 - Regulation of Fuels and Fuel Additives: Alternative Affirmative Defense Requirements for Ultra...

    Science.gov (United States)

    2010-05-11

    ... Strategies Division, Office of Transportation and Air Quality, Office of Air and Radiation, Environmental... production, importation, distribution, marketing, or retailing of diesel fuel and production of gasoline... Marketers and Distributors. Industry 484220 4212 Diesel Fuel Carriers. \\a\\ North American...

  12. METHANOL PRODUCTION FROM BIOMASS AND NATURAL GAS AS TRANSPORTATION FUEL

    Science.gov (United States)

    Two processes are examined for production of methanol. They are assessed against the essential requirements of a future alternative fuel for road transport: that it (i) is producible in amounts comparable to the 19 EJ of motor fuel annually consumed in the U.S., (ii) minimizes em...

  13. Aircraft emissions of methane and nitrous oxide during the alternative aviation fuel experiment.

    Science.gov (United States)

    Santoni, Gregory W; Lee, Ben H; Wood, Ezra C; Herndon, Scott C; Miake-Lye, Richard C; Wofsy, Steven C; McManus, J Barry; Nelson, David D; Zahniser, Mark S

    2011-08-15

    Given the predicted growth of aviation and the recent developments of alternative aviation fuels, quantifying methane (CH(4)) and nitrous oxide (N(2)O) emission ratios for various aircraft engines and fuels can help constrain projected impacts of aviation on the Earth's radiative balance. Fuel-based emission indices for CH(4) and N(2)O were quantified from CFM56-2C1 engines aboard the NASA DC-8 aircraft during the first Alternative Aviation Fuel Experiment (AAFEX-I) in 2009. The measurements of JP-8 fuel combustion products indicate that at low thrust engine states (idle and taxi, or 4% and 7% maximum rated thrusts, respectively) the engines emit both CH(4) and N(2)O at a mean ± 1σ rate of 170 ± 160 mg CH(4) (kg Fuel)(-1) and 110 ± 50 mg N(2)O (kg Fuel)(-1), respectively. At higher thrust levels corresponding to greater fuel flow and higher engine temperatures, CH(4) concentrations in engine exhaust were lower than ambient concentrations. Average emission indices for JP-8 fuel combusted at engine thrusts between 30% and 100% of maximum rating were -54 ± 33 mg CH(4) (kg Fuel)(-1) and 32 ± 18 mg N(2)O (kg Fuel)(-1), where the negative sign indicates consumption of atmospheric CH(4) in the engine. Emission factors for the synthetic Fischer-Tropsch fuels were statistically indistinguishable from those for JP-8.

  14. Non-Gasoline Alternative Fueling Stations

    Data.gov (United States)

    Department of Homeland Security — Through a nationwide network of local coalitions, Clean Citiesprovides project assistance to help stakeholders in the public and private sectors deploy alternative...

  15. Engine Materials Compatibility with Alternate Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Thomson, Jeffery K [ORNL; Pawel, Steven J [ORNL; Wilson, Dane F [ORNL

    2013-05-01

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined were accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  16. Engine Materials Compatability with Alternative Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Pawel, Steve [Oak Ridge National Laboratory; Moore, D. [USCAR

    2013-04-05

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined were accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  17. Assessment of costs and benefits of flexible and alternative fuel use in the US transportation sector

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-01

    The DOE is conducting a comprehensive technical analysis of a flexible-fuel transportation system in the United States -- that is, a system that could easily switch between petroleum and another fuel, depending on price and availability. The DOE Alternative Fuels Assessment is aimed directly at questions of energy security and fuel availability, but covers a wide range of issues. This report examines environmental, health, and safety concerns associated with a switch to alternative- and flexible-fuel vehicles. Three potential alternatives to oil-based fuels in the transportation sector are considered: methanol, compressed natural gas (CNG), and electricity. The objective is to describe and discuss qualitatively potential environmental, health, and safety issues that would accompany widespread use of these three fuels. This report presents the results of exhaustive literature reviews; discussions with specialists in the vehicular and fuel-production industries and with Federal, State, and local officials; and recent information from in-use fleet tests. Each chapter deals with the end-use and process emissions of air pollutants, presenting an overview of the potential air pollution contribution of the fuel --relative to that of gasoline and diesel fuel -- in various applications. Carbon monoxide, particulate matter, ozone precursors, and carbon dioxide are emphasized. 67 refs., 6 figs. , 8 tabs.

  18. Final Technical Report for Alternative Fuel Source Study-An Energy Efficient and Environmentally Friendly Approach

    Energy Technology Data Exchange (ETDEWEB)

    Zee, Ralph [Auburn University, AL (United States); Schindler, Anton [Auburn University, AL (United States); Duke, Steve [Auburn University, AL (United States); Burch, Thom [Auburn University, AL (United States); Bransby, David [Auburn University, AL (United States); Stafford, Don [Lafarge North America, Inc., Alpharetta, GA (United States)

    2010-08-31

    The objective of this project is to conduct research to determine the feasibility of using alternate fuel sources for the production of cement. Successful completion of this project will also be beneficial to other commercial processes that are highly energy intensive. During this report period, we have completed all the subtasks in the preliminary survey. Literature searches focused on the types of alternative fuels currently used in the cement industry around the world. Information was obtained on the effects of particular alternative fuels on the clinker/cement product and on cement plant emissions. Federal regulations involving use of waste fuels were examined. Information was also obtained about the trace elements likely to be found in alternative fuels, coal, and raw feeds, as well as the effects of various trace elements introduced into system at the feed or fuel stage on the kiln process, the clinker/cement product, and concrete made from the cement. The experimental part of this project involves the feasibility of a variety of alternative materials mainly commercial wastes to substitute for coal in an industrial cement kiln in Lafarge NA and validation of the experimental results with energy conversion consideration.

  19. Describing current and potential markets for alternative-fuel vehicles

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-26

    Motor vehicles are a major source of greenhouse gases, and the rising numbers of motor vehicles and miles driven could lead to more harmful emissions that may ultimately affect the world`s climate. One approach to curtailing such emissions is to use, instead of gasoline, alternative fuels: LPG, compressed natural gas, or alcohol fuels. In addition to the greenhouse gases, pollutants can be harmful to human health: ozone, CO. The Clean Air Act Amendments of 1990 authorized EPA to set National Ambient Air Quality Standards to control this. The Energy Policy Act of 1992 (EPACT) was the first new law to emphasize strengthened energy security and decreased reliance on foreign oil since the oil shortages of the 1970`s. EPACT emphasized increasing the number of alternative-fuel vehicles (AFV`s) by mandating their incremental increase of use by Federal, state, and alternative fuel provider fleets over the new few years. Its goals are far from being met; alternative fuels` share remains trivial, about 0.3%, despite gains. This report describes current and potential markets for AFV`s; it begins by assessing the total vehicle stock, and then it focuses on current use of AFV`s in alternative fuel provider fleets and the potential for use of AFV`s in US households.

  20. Additive Effectiveness Investigations in Alternative Fuels

    Science.gov (United States)

    2014-05-01

    coupon, in a tube in shell heat exchanger. The fuel flows in the annulus and deposit forms on the outside. When a test temperature is specified, 275 °C...has a small filter made from materials similar to those found in aviation filter separators. The rating is a form of turbidity measurement with 100

  1. Synthetic and Biomass Alternate Fueling in Aviation

    Science.gov (United States)

    Hendricks, Robert C.; Bushnell, Dennis M.

    2009-01-01

    Must use earth's most abundant natural resources - Biomass, Solar, Arid land (43%), Seawater (97%) with nutrients (80%) plus brackish waters and nutrients resolve environmental triangle of conflicts energy-food-freshwater and ultrafine particulate hazards. Requires Paradigm Shift - Develop and Use Solar* for energy; Biomass for aviation and hybrid-electric-compressed air mobility fueling with transition to hydrogen long term.

  2. 78 FR 23832 - Labeling Requirements for Alternative Fuels and Alternative Fueled Vehicles

    Science.gov (United States)

    2013-04-23

    ... that run on liquid and non-liquid fuels, such as ethanol and other alcohols, including E85 ethanol... vehicle's estimated driving range (i.e., the travel distance on a single charge or tank of fuel), general... liquid fuels, or fuels (other than alcohol) derived from biological materials. See 76 FR 39478 (July...

  3. 76 FR 31513 - Labeling Requirements for Alternative Fuels and Alternative Fueled Vehicles

    Science.gov (United States)

    2011-06-01

    ... AFVs that run on liquid and non-liquid fuels, such as ethanol and other alcohols including E85 ethanol... vehicle's estimated cruising range (i.e., the travel distance on a single charge or tank of fuel), general... by liquefied petroleum gas, hydrogen, coal-derived liquid fuels, or fuels (other than...

  4. Distillate Fuel Trends: International Supply Variations and Alternate Fuel Properties

    Science.gov (United States)

    2013-01-31

    Acids derived Synthetic Paraffinic Kerosene HFRR High Frequency Reciprocating Rig, ASTM D6079 HVO Hydrotreated Vegetable Oil IARC International...including hydrotreated vegetable oil (HVO) and Biomass-to- Liquid (BTL), provided all other specifications are respected and the resulting blend meets...number of commercial, middle distillate fuels (diesel and jet). It is most often made through either hydrotreating processes or Fischer-Tropsch (FT

  5. Alternate Fuel Cell Membranes for Energy Independence

    Energy Technology Data Exchange (ETDEWEB)

    Storey, Robson, F.; Mauritz, Kenneth, A.; Patton, Derek, L.; Savin, Daniel, A.

    2012-12-18

    The overall objective of this project was the development and evaluation of novel hydrocarbon fuel cell (FC) membranes that possess high temperature performance and long term chemical/mechanical durability in proton exchange membrane (PEM) fuel cells (FC). The major research theme was synthesis of aromatic hydrocarbon polymers of the poly(arylene ether sulfone) (PAES) type containing sulfonic acid groups tethered to the backbone via perfluorinated alkylene linkages and in some cases also directly attached to the phenylene groups along the backbone. Other research themes were the use of nitrogen-based heterocyclics instead of acid groups for proton conduction, which provides high temperature, low relative humidity membranes with high mechanical/thermal/chemical stability and pendant moieties that exhibit high proton conductivities in the absence of water, and synthesis of block copolymers consisting of a proton conducting block coupled to poly(perfluorinated propylene oxide) (PFPO) blocks. Accomplishments of the project were as follows: 1) establishment of a vertically integrated program of synthesis, characterization, and evaluation of FC membranes, 2) establishment of benchmark membrane performance data based on Nafion for comparison to experimental membrane performance, 3) development of a new perfluoroalkyl sulfonate monomer, N,N-diisopropylethylammonium 2,2-bis(p-hydroxyphenyl) pentafluoropropanesulfonate (HPPS), 4) synthesis of random and block copolymer membranes from HPPS, 5) synthesis of block copolymer membranes containing high-acid-concentration hydrophilic blocks consisting of HPPS and 3,3'-disulfonate-4,4'-dichlorodiphenylsulfone (sDCDPS), 6) development of synthetic routes to aromatic polymer backbones containing pendent 1H-1,2,3-triazole moieties, 7) development of coupling strategies to create phase-separated block copolymers between hydrophilic sulfonated prepolymers and commodity polymers such as PFPO, 8) establishment of basic

  6. Findings and Recommendations from the NIST Workshop on Alternative Fuels and Materials: Biocorrosion.

    Science.gov (United States)

    Mansfield, Elisabeth; Sowards, Jeffrey W; Crookes-Goodson, Wendy J

    2015-01-01

    In 2013, the Applied Chemicals and Materials Division of the National Institute of Standards and Technology (NIST) hosted a workshop to identify and prioritize research needs in the area of biocorrosion. Materials used to store and distribute alternative fuels have experienced an increase in corrosion due to the unique conditions caused by the presence of microbes and the chemistry of biofuels and biofuel precursors. Participants in this workshop, including experts from the microbiological, fuel, and materials communities, delved into the unique materials and chemical challenges that occur with production, transport, and storage of alternative fuels. Discussions focused on specific problems including: a) the changing composition of "drop-in" fuels and the impact of that composition on materials; b) the influence of microbial populations on corrosion and fuel quality; and c) state-of-the-art measurement technologies for monitoring material degradation and biofilm formation.

  7. EPAct Alternative Fuel Transportation Program: State and Alternative Fuel Provider Fleet Compliance Annual Report; Fleet Compliance Results for MY 2013/FY 2014

    Energy Technology Data Exchange (ETDEWEB)

    2015-09-01

    Compliance rates for covered state government and alternative fuel provider fleets under the Alternative Fuel Transportation Program (pursuant to the Energy Policy Act or EPAct) are reported for MY 2013/FY 2014 in this publication.

  8. 77 FR 36423 - Labeling Requirements for Alternative Fuels and Alternative Fueled Vehicles

    Science.gov (United States)

    2012-06-19

    ..., coal-derived liquid fuels, fuels derived from biological materials (e.g., 100% biodiesel), and... requirements appear unnecessary.\\18\\ \\17\\ 42 U.S.C. 13211(3)(B). According to the legislative history,...

  9. Primer on Motor Fuel Excise Taxes and the Role of Alternative Fuels and Energy Efficient Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, Alex [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2015-08-26

    Motor fuel taxes were established to finance our nation’s transportation infrastructure, yet evolving economic, political, and technological influences are constraining this ability. At the federal level, the Highway Trust Fund (HTF), which is primarily funded by motor fuel taxes, has become increasingly dependent on general fund contributions and short-term reauthorizations to prevent insolvency. As a result, there are discussions at both the federal and state levels in which stakeholders are examining the future of motor fuel excise taxes as well as the role of electric and alternative fuel vehicles in that future. On July 1, 2015, six states increased their motor fuel tax rates.

  10. Fuels made from agricultural biomass - (biogas) alternative types(Alternativne vrste goriva iz poljoprivredne biomase - biogas)

    OpenAIRE

    Jovanovska, Vangelica; Jovanovski, Nikola; Sovreski, Zlatko; Pop-Andonov, Goran; Sinani, Feta

    2013-01-01

    Biogas is a typical "product" of urban discharges, which has a great negative environmental impact. To avoid this negative effect, it can be burnt at very high temperatures, producing smoke emissions composed of CO2. A useful alternative is to use biogas as fuel to feed co-generation plants, producing electricity. At the moment biogas is used as fuel, introducing it directly in the combustion chamber. Nevertheless the heterogeneity of the gas stresses the engine, reducing its life. The new te...

  11. N-butanol and isobutanol as alternatives to gasoline: Comparison of port fuel injector characteristics

    Science.gov (United States)

    Fenkl, Michael; Pechout, Martin; Vojtisek, Michal

    2016-03-01

    The paper reports on an experimental investigation of the relationship between the pulse width of a gasoline engine port fuel injector and the quantity of the fuel injected when butanol is used as a fuel. Two isomers of butanol, n-butanol and isobutanol, are considered as potential candidates for renewable, locally produced fuels capable of serving as a drop-in replacement fuel for gasoline, as an alternative to ethanol which poses material compatibility and other drawbacks. While the injected quantity of fuel is typically a linear function of the time the injector coil is energized, the flow through the port fuel injector is complex, non ideal, and not necessarily laminar, and considering that butanol has much higher viscosity than gasoline, an experimental investigation was conducted. A production injector, coupled to a production fueling system, and driven by a pulse width generator was operated at various pulse lengths and frequencies, covering the range of engine rpm and loads on a car engine. The results suggest that at least at room temperature, the fueling rate remains to be a linear function of the pulse width for both n-butanol and isobutanol, and the volumes of fuel injected are comparable for gasoline and both butanol isomers.

  12. N-butanol and isobutanol as alternatives to gasoline: Comparison of port fuel injector characteristics

    Directory of Open Access Journals (Sweden)

    Fenkl Michael

    2016-01-01

    Full Text Available The paper reports on an experimental investigation of the relationship between the pulse width of a gasoline engine port fuel injector and the quantity of the fuel injected when butanol is used as a fuel. Two isomers of butanol, n-butanol and isobutanol, are considered as potential candidates for renewable, locally produced fuels capable of serving as a drop-in replacement fuel for gasoline, as an alternative to ethanol which poses material compatibility and other drawbacks. While the injected quantity of fuel is typically a linear function of the time the injector coil is energized, the flow through the port fuel injector is complex, non ideal, and not necessarily laminar, and considering that butanol has much higher viscosity than gasoline, an experimental investigation was conducted. A production injector, coupled to a production fueling system, and driven by a pulse width generator was operated at various pulse lengths and frequencies, covering the range of engine rpm and loads on a car engine. The results suggest that at least at room temperature, the fueling rate remains to be a linear function of the pulse width for both n-butanol and isobutanol, and the volumes of fuel injected are comparable for gasoline and both butanol isomers.

  13. Wood fuel production technologies in EU countries

    Energy Technology Data Exchange (ETDEWEB)

    Hakkila, P. [Finnish Forest Research Institute, Vantaa (Finland)

    1997-12-31

    The presentation reviews the major technologies used for the production of fuel chips for heating plants in Europe. Three primary options are considered: production of whole-tree chips from young trees for fuel; integrated harvesting of fiber and energy from thinning based on tree-section system; and production of fuel chips from logging residue in clear-cut areas after fully mechanized logging. The characteristics of the available biomass reserve and proven technology for its recovery are discussed. The employment effects of fuel chip production and the costs of wood fuels are also briefly discussed. (author) 3 refs., 3 figs.

  14. Plant Performance of Solid Oxide Fuel Cell Systems Fed by Alternative Fuels

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2016-01-01

    Different plant design for several fuel types such as natural gas, methanol, ethanol, DME, ammonia and pure hydrogen are presented and analysed. Anode recirculation which is an important issue in SOFC plants are also explored and studied. It is shown that depending on type of the fuel whether fuel...... recirculation is needed or not and if so then what would be the effect of anode recycling on plant efficiency. A single study with similar conditions and prerequisites will thus reveal the importance of fuel recirculation on plant performance with alternative fuels. It is also shown that increasing anode...... recycle increases plant efficiency only if fuel utilization factor is low. Other important issues such as why plant efficiency is lower when it is fed with hydrogen or biogas compared to when it is fed by other fuels such as methanol, ethanol, DME and ammonia will also be discussed and explained...

  15. Photoactivated Fuel Cells (PhotoFuelCells. An alternative source of renewable energy with environmental benefits

    Directory of Open Access Journals (Sweden)

    Stavroula Sfaelou

    2016-03-01

    Full Text Available This work is a short review of Photoactivated Fuel Cells, that is, photoelectrochemical cells which consume an organic or inorganic fuel to produce renewable electricity or hydrogen. The work presents the basic features of photoactivated fuel cells, their modes of operation, the materials, which are frequently used for their construction and some ideas of cell design both for electricity and solar hydrogen production. Water splitting is treated as a special case of photoactivated fuel cell operation.

  16. Annual Report FY2014 Alternative Fuels DISI Engine Research

    Energy Technology Data Exchange (ETDEWEB)

    Sjoberg, Carl-Magnus G. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-01-01

    Due to concerns about future petroleum supply and accelerating climate change, increased engine efficiency and alternative fuels are of interest. This project contributes to the science-base needed by industry to develop highly efficient DISI engines that also beneficially exploit the different properties of alternative fuels. Lean operation is studied since it can provide higher efficiencies than traditional non-dilute stoichiometric operation. Since lean operation can lead to issues with ignition stability, slow flame propagation and low combustion efficiency, focus is on techniques that can overcome these challenges. Specifically, fuel stratification can be used to ensure ignition and completeness of combustion, but may lead to soot and NOx emissions challenges. Advanced ignition system and intake air preheating both promote ignition stability. Controlled end-gas autoignition can be used maintain high combustion efficiency for ultra-lean well-mixed conditions. However, the response of both combustion and exhaust emission to these techniques depends on the fuel properties. Therefore, to achieve optimal fuel-economy gains, the combustion-control strategies of the engine must adopt to the fuel being utilized.

  17. Arizona Public Service - Alternative Fuel (Hydrogen) Pilot Plant Design Report

    Energy Technology Data Exchange (ETDEWEB)

    James E. Francfort

    2003-12-01

    Hydrogen has promise to be the fuel of the future. Its use as a chemical reagent and as a rocket propellant has grown to over eight million metric tons per year in the United States. Although use of hydrogen is abundant, it has not been used extensively as a transportation fuel. To assess the viability of hydrogen as a transportation fuel and the viability of producing hydrogen using off-peak electric energy, Pinnacle West Capital Corporation (PNW) and its electric utility subsidiary, Arizona Public Service (APS) designed, constructed, and operates a hydrogen and compressed natural gas fueling station—the APS Alternative Fuel Pilot Plant. This report summarizes the design of the APS Alternative Fuel Pilot Plant and presents lessons learned from its design and construction. Electric Transportation Applications prepared this report under contract to the U.S. Department of Energy’s Advanced Vehicle Testing Activity. The Idaho National Engineering and Environmental Laboratory manages these activities for the Advanced Vehicle Testing Activity.

  18. FY2015 Annual Report for Alternative Fuels DISI Engine Research.

    Energy Technology Data Exchange (ETDEWEB)

    Sjöberg, Carl-Magnus G. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

    2016-01-01

    Climate change and the need to secure energy supplies are two reasons for a growing interest in engine efficiency and alternative fuels. This project contributes to the science-base needed by industry to develop highly efficient DISI engines that also beneficially exploit the different properties of alternative fuels. Our emphasis is on lean operation, which can provide higher efficiencies than traditional non-dilute stoichiometric operation. Since lean operation can lead to issues with ignition stability, slow flame propagation and low combustion efficiency, we focus on techniques that can overcome these challenges. Specifically, fuel stratification is used to ensure ignition and completeness of combustion but has soot- and NOx- emissions challenges. For ultralean well-mixed operation, turbulent deflagration can be combined with controlled end-gas auto-ignition to render mixed-mode combustion that facilitates high combustion efficiency. However, the response of both combustion and exhaust emissions to these techniques depends on the fuel properties. Therefore, to achieve optimal fuel-economy gains, the engine combustion-control strategies must be adapted to the fuel being utilized.

  19. Fuels Selection Alternatives for Army Facilities

    Science.gov (United States)

    1986-12-01

    received by rail cars carrying about 100 tons each. The cars are unloaded into an underground hopper, and coal is conveyed at a rate of 300 tons/hr to...Production from Wood Residue ( Rader Systems, inc., 1978); H. I. Hollander, 1976; Resource Planning Associates, Inc., 1977; Resource Planning...Inc., August 1980; Rader Systems, Inc., 1978; H. I. Hollander, 1976. 40 Table 14 Packaged Stoker Watertube Boilers for Coal, Waste, DRDF, or

  20. 76 FR 19829 - Clean Alternative Fuel Vehicle and Engine Conversions

    Science.gov (United States)

    2011-04-08

    ... software. Furthermore, manufacturers often change components and strategies between model years as...). ACTION: Final rule. SUMMARY: EPA is streamlining the process by which manufacturers of clean alternative... Engineering Judgment C. Vehicle/Engine Groupings and Emission Data Vehicle/Engine Selection D. Mixed-Fuel...

  1. Other Alternative Diesel Fuels from Vegetable Oils and Animal Fats

    Science.gov (United States)

    The energy crises of the 1970’s and early 1980’s provided impetus for developing alternative diesel fuels from vegetable oils and animal fats. Other driving forces may be derived from the Clean Air Act and its amendments and farmers desire to develop new uses for surplus agricultural commodities. ...

  2. Production of bio-jet fuel from microalgae

    Science.gov (United States)

    Elmoraghy, Marian

    The increase in petroleum-based aviation fuel consumption, the decrease in petroleum resources, the fluctuation of the crude oil price, the increase in greenhouse gas emission and the need for energy security are motivating the development of an alternate jet fuel. Bio-jet fuel has to be a drop in fuel, technically and economically feasible, environmentally friendly, greener than jet fuel, produced locally and low gallon per Btu. Bic jet fuel has been produced by blending petro-based jet fuel with microalgae biodiesel (Fatty Acid Methyl Ester, or simply FAME). Indoor microalgae growth, lipids extraction and transetrification to biodiesel are energy and fresh water intensive and time consuming. In addition, the quality of the biodiesel product and the physical properties of the bio-jet fuel blends are unknown. This work addressed these challenges. Minimizing the energy requirements and making microalgae growth process greener were accomplished by replacing fluorescent lights with light emitting diodes (LEDs). Reducing fresh water footprint in algae growth was accomplished by waste water use. Microalgae biodiesel production time was reduced using the one-step (in-situ transestrification) process. Yields up to 56.82 mg FAME/g dry algae were obtained. Predicted physical properties of in-situ FAME satisfied European and American standards confirming its quality. Lipid triggering by nitrogen deprivation was accomplished in order to increase the FAME production. Bio-jet fuel freezing points and heating values were measured for different jet fuel to biodiesel blend ratios.

  3. Testing and preformance measurement of straight vegetable oils as an alternative fuel for diesel engines

    Science.gov (United States)

    Lakshminarayanan, Arunachalam

    Rising fuel prices, growing energy demand, concerns over domestic energy security and global warming from greenhouse gas emissions have triggered the global interest in bio-energy and bio-fuel crop development. Backlash from these concerns can result in supply shocks of traditional fossil fuels and create immense economic pressure. It is thus widely argued that bio-fuels would particularly benefit developing countries by off-setting their dependencies on imported petroleum. Domestically, the transportation sector accounts for almost 40% of liquid fuel consumption, while on-farm application like tractors and combines for agricultural purposes uses close to an additional 18%. It is estimated that 40% of the farm budget can be attributed to the fuel costs. With the cost of diesel continuously rising, farmers are now looking at using Straight Vegetable Oil (SVO) as an alternative fuel by producing their own fuel crops. This study evaluates conventional diesel compared to the use of SVO like Camelina, Canola and Juncea grown on local farms in Colorado for their performance and emissions on a John Deere 4045 Tier-II engine. Additionally, physical properties like density and viscosity, metal/mineral content, and cold flow properties like CFPP and CP of these oils were measured using ASTM standards and compared to diesel. It was found that SVOs did not show significant differences compared to diesel fuel with regards to engine emissions, but did show an increase in thermal efficiency. Therefore, this study supports the continued development of SVO production as a viable alternative to diesel fuels, particularly for on-farm applications. The need for providing and developing a sustainable, economic and environmental friendly fuel alternative has taken an aggressive push which will require a strong multidisciplinary education in the field of bio-energy. Commercial bio-energy development has the potential to not only alleviate the energy concerns, but also to give renewed

  4. 76 FR 67287 - Alternative Fuel Transportation Program; Alternative Fueled Vehicle Credit Program (Subpart F...

    Science.gov (United States)

    2011-10-31

    ... subject to these respective acquisition mandates turns on the size and location criteria set forth in the... meets the criteria for a dual fueled automobile, as that term is defined in section 513(h)(1)(C) of the... definition would read as follows: (1) An automobile that meets the criteria for a dual fueled automobile...

  5. Air quality effects of alternative fuels. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Guthrie, P.; Ligocki, M.; Looker, R.; Cohen, J.

    1997-11-01

    To support the Alternative Fuels Utilization Program, a comparison of potential air quality effects of alternative transportation fuels is being performed. This report presents the results of Phase 1 of this program, focusing on reformulated gasoline (RFG), methanol blended with 15 percent gasoline (M85), and compressed natural gas (CNG). The fuels are compared in terms of effects on simulated future concentrations of ozone and mobile source air toxics in a photochemical grid model. The fuel comparisons were carried out for the future year 2020 and assumed complete replacement of gasoline in the projected light-duty gasoline fleet by each of the candidate fuels. The model simulations were carried out for the areas surrounding Los Angeles and Baltimore/DC, and other (non-mobile) sources of atmospheric emissions were projected according to published estimates of economic and population growth, and planned emission control measures specific to each modeling domain. The future-year results are compared to a future-year run with all gasoline vehicle emissions removed. The results of the comparison indicate that the use of M85 is likely to produce similar ozone and air toxics levels as those projected from the use of RFG. Substitution of CNG is projected to produce significantly lower levels of ozone and the mobile source air toxics than those projected for RFG or M85. The relative benefits of CNG substitution are consistent in both modeling domains. The projection methodologies used for the comparison are subject to a large uncertainty, and modeled concentration distributions depend on meteorological conditions. The quantitative comparison of fuel effects is thus likely to be sensitive to alternative assumptions. The consistency of the results for two very different modeling domains, using very different base assumptions, lends credibility to the qualitative differentiation among these fuels. 32 refs., 42 figs., 47 tabs.

  6. Impact of aviation non-CO₂ combustion effects on the environmental feasibility of alternative jet fuels.

    Science.gov (United States)

    Stratton, Russell W; Wolfe, Philip J; Hileman, James I

    2011-12-15

    Alternative fuels represent a potential option for reducing the climate impacts of the aviation sector. The climate impacts of alternatives fuel are traditionally considered as a ratio of life cycle greenhouse gas (GHG) emissions to those of the displaced petroleum product; however, this ignores the climate impacts of the non-CO(2) combustion effects from aircraft in the upper atmosphere. The results of this study show that including non-CO(2) combustion emissions and effects in the life cycle of a Synthetic Paraffinic Kerosene (SPK) fuel can lead to a decrease in the relative merit of the SPK fuel relative to conventional jet fuel. For example, an SPK fuel option with zero life cycle GHG emissions would offer a 100% reduction in GHG emissions but only a 48% reduction in actual climate impact using a 100-year time window and the nominal climate modeling assumption set outlined herein. Therefore, climate change mitigation policies for aviation that rely exclusively on relative well-to-wake life cycle GHG emissions as a proxy for aviation climate impact may overestimate the benefit of alternative fuel use on the global climate system.

  7. System comparison of hydrogen with other alternative fuels in terms of EPACT requirements

    Energy Technology Data Exchange (ETDEWEB)

    Barbir, F.; Oezay, K.; Veziroglu, T.N. [Univ. of Miami, Coral Gables, FL (United States)

    1996-10-01

    The feasibility of several alternative fuels, namely natural gas, methanol, ethanol, hydrogen and electricity, to replace 10% of gasoline by the year 2000 has been investigated. The analysis was divided in two parts: (i) analysis of vehicle technologies, and (ii) analysis of fuel production storage and distribution, from the primary energy sources to the refueling station. Only technologies that are developed to at least demonstration level were considered. The amount and type of the primary energy sources have been determined for each of the fuels being analyzed. A need for a common denominator for different types of energy has been identified.

  8. Coconut Oil Based Hybrid Fuels as Alternative Fuel for Diesel Engines

    Directory of Open Access Journals (Sweden)

    Pranil Singh

    2010-01-01

    Full Text Available Problem statement: The use of vegetable oils as a fuel in diesel engines causes some problems due to their high viscosity compared with diesel. Various techniques and methods are used to solve the problems resulting from high viscosity. Approach: One of the techniques is the preparation of a microemulsion fuel, called a hybrid fuel. In this study, hybrid fuels consisting of coconut oil, ethanol and octan-1-ol were prepared with an aim to test their suitability as a fuel for diesel engines. Density, viscosity and gross calorific values of these fuels were determined and the fuels were used to run a direct injection diesel engine. The engine performance and exhaust emissions were investigated and compared with that of diesel and coconut oil. Results: The experimental results show that the engine efficiency of the hybrid fuels is comparable to that of diesel. As the percentage of ethanol and/or octan-1-ol increased, the viscosity of the hybrid fuels decreased and the engine efficiency increased. The exhaust emissions were lower than those for diesel, except carbon monoxide, which increased. Conclusion/Recommendations: Hence, it is concluded that these hybrid fuels can be used successfully as an alternative fuel in diesel engines without any modifications. Their completely renewable nature ensures that they are environmentally friendly.

  9. Life cycle models of conventional and alternative-fueled automobiles

    Science.gov (United States)

    Maclean, Heather Louise

    This thesis reports life cycle inventories of internal combustion engine automobiles with feasible near term fuel/engine combinations. These combinations include unleaded gasoline, California Phase 2 Reformulated Gasoline, alcohol and gasoline blends (85 percent methanol or ethanol combined with 15 percent gasoline), and compressed natural gas in spark ignition direct and indirect injection engines. Additionally, I consider neat methanol and neat ethanol in spark ignition direct injection engines and diesel fuel in compression ignition direct and indirect injection engines. I investigate the potential of the above options to have a lower environmental impact than conventional gasoline-fueled automobiles, while still retaining comparable pricing and consumer benefits. More broadly, the objective is to assess whether the use of any of the alternative systems will help to lead to the goal of a more sustainable personal transportation system. The principal tool is the Economic Input-Output Life Cycle Analysis model which includes inventories of economic data, environmental discharges, and resource use. I develop a life cycle assessment framework to assemble the array of data generated by the model into three aggregate assessment parameters; economics, externalities, and vehicle attributes. The first step is to develop a set of 'comparable cars' with the alternative fuel/engine combinations, based on characteristics of a conventional 1998 gasoline-fueled Ford Taurus sedan, the baseline vehicle for the analyses. I calculate the assessment parameters assuming that these comparable cars can attain the potential thermal efficiencies estimated by experts for each fuel/engine combination. To a first approximation, there are no significant differences in the assessment parameters for the vehicle manufacture, service, fixed costs, and the end-of-life for any of the options. However, there are differences in the vehicle operation life cycle components and the state of technology

  10. Fuel composition and secondary organic aerosol formation: gas-turbine exhaust and alternative aviation fuels.

    Science.gov (United States)

    Miracolo, Marissa A; Drozd, Greg T; Jathar, Shantanu H; Presto, Albert A; Lipsky, Eric M; Corporan, Edwin; Robinson, Allen L

    2012-08-07

    A series of smog chamber experiments were performed to investigate the effects of fuel composition on secondary particulate matter (PM) formation from dilute exhaust from a T63 gas-turbine engine. Tests were performed at idle and cruise loads with the engine fueled on conventional military jet fuel (JP-8), Fischer-Tropsch synthetic jet fuel (FT), and a 50/50 blend of the two fuels. Emissions were sampled into a portable smog chamber and exposed to sunlight or artificial UV light to initiate photo-oxidation. Similar to previous studies, neat FT fuel and a 50/50 FT/JP-8 blend reduced the primary particulate matter emissions compared to neat JP-8. After only one hour of photo-oxidation at typical atmospheric OH levels, the secondary PM production in dilute exhaust exceeded primary PM emissions, except when operating the engine at high load on FT fuel. Therefore, accounting for secondary PM production should be considered when assessing the contribution of gas-turbine engine emissions to ambient PM levels. FT fuel substantially reduced secondary PM formation in dilute exhaust compared to neat JP-8 at both idle and cruise loads. At idle load, the secondary PM formation was reduced by a factor of 20 with the use of neat FT fuel, and a factor of 2 with the use of the blend fuel. At cruise load, the use of FT fuel resulted in no measured formation of secondary PM. In every experiment, the secondary PM was dominated by organics with minor contributions from sulfate when the engine was operated on JP-8 fuel. At both loads, FT fuel produces less secondary organic aerosol than JP-8 because of differences in the composition of the fuels and the resultant emissions. This work indicates that fuel reformulation may be a viable strategy to reduce the contribution of emissions from combustion systems to secondary organic aerosol production and ultimately ambient PM levels.

  11. State of the Art on Alternative Fuels in Aviation. SWAFEA. Sustainable Way for Alternative Fuels and Energy in Aviation.

    NARCIS (Netherlands)

    Blakey, S.; Novelli, P.; Costes, P.; Bringtown, S.; Christensen, D.; Sakintuna, B.; Peineke, C.; Jongschaap, R.E.E.; Conijn, J.G.; Rutgers, B.; Valot, L.; Joubert, E.; Perelgritz, J.F.; Filogonio, A.; Roetger, T.; Prieur, A.; Starck, L.; Jeuland, N.; Bogers, P.; Midgley, R.; Bauldreay, J.; Rollin, G.; Rye, L.; Wilson, C.

    2010-01-01

    Currently, the aviation sector uses petroleum derived liquid fuels as the energy carrier of choice for flight. In light the present environmental, economical and political concerns as to the sustainability of this energy source, the question of which alternatives the aviation sector should pursue in

  12. Economic Evaluation Guide for alternative transportation fuels

    Energy Technology Data Exchange (ETDEWEB)

    de Percin, D.; Werner, J.F. Jr.

    1992-01-01

    The production of this Economic Evaluation Guide is one activity of AVFCAP. The guide is intended for use by project managers and fleet operators in the public sector. Public fleets have been identified as one of the most likely areas where ATFs will first gain widespread use, because of existing and impending state and federal legislative mandates, as well as for practical reasons such as centralized servicing and refueling. The purpose of this guide is to provide balanced decision-support information to project managers who are considering conducting, or currently managing, ATF demonstration programs. Information for this guide was gathered as part of a related AVFCAP activity, the development of an Information Resource Database. Economic issues related to the development and implementation of ATF programs at the local government level are extremely complex, and require an analysis of federal policies and national and international economics that is generally beyond the scope of local government project managers. The intent of this guide is to examine the information available on the economic evaluation of ATFs, and identify key elements that will help local governments realistically assess the potential costs and savings of an ATF program. The guide also discusses how these various economic factors are related, and how local government priorities affect how different factors are weighed.

  13. Economic Evaluation Guide for alternative transportation fuels

    Energy Technology Data Exchange (ETDEWEB)

    de Percin, D.; Werner, J.F. Jr.

    1992-12-31

    The production of this Economic Evaluation Guide is one activity of AVFCAP. The guide is intended for use by project managers and fleet operators in the public sector. Public fleets have been identified as one of the most likely areas where ATFs will first gain widespread use, because of existing and impending state and federal legislative mandates, as well as for practical reasons such as centralized servicing and refueling. The purpose of this guide is to provide balanced decision-support information to project managers who are considering conducting, or currently managing, ATF demonstration programs. Information for this guide was gathered as part of a related AVFCAP activity, the development of an Information Resource Database. Economic issues related to the development and implementation of ATF programs at the local government level are extremely complex, and require an analysis of federal policies and national and international economics that is generally beyond the scope of local government project managers. The intent of this guide is to examine the information available on the economic evaluation of ATFs, and identify key elements that will help local governments realistically assess the potential costs and savings of an ATF program. The guide also discusses how these various economic factors are related, and how local government priorities affect how different factors are weighed.

  14. The California Multimedia Risk Assessment Protocol for Alternative Fuels

    Science.gov (United States)

    Hatch, T.; Ginn, T. R.; McKone, T. E.; Rice, D. W.

    2013-12-01

    Any new fuel in California requires approval by the state agencies overseeing human and environmental health. In order to provide a systematic evaluation of new fuel impacts, California now requires a multimedia risk assessment (MMRA) for fuel approval. The fuel MMRA involves all relevant state agencies including: the California Air Resources Board (CARB), the State Water Resources Control Board (SWRCB), the Office of Environmental Health Hazards Assessment (OEHHA), and the Department of Toxic Substances Control (DTSC) overseen by the California Environmental Protection Agency (CalEPA). The lead agency for MMRAs is the CARB. The original law requiring a multimedia assessment is California Health and Safety Code 43830.8. In addition, the low carbon fuel standard (LCFS), the Global Warming Solutions Act (AB32), and the Verified Diesel Emission Control Strategy (VDECS) have provisions that can require a multimedia assessment. In this presentation, I give an overview of the California multimedia risk assessment (MMRA) for new fuels that has been recently developed and applied to several alternative fuels. The objective of the California MMRA is to assess risk of potential impacts of new fuels to multiple environmental media including: air, water, and soil. Attainment of this objective involves many challenges, including varying levels of uncertainty, relative comparison of incommensurate risk factors, and differing levels of priority assigned to risk factors. The MMRA is based on a strategy of relative risk assessment and flexible accommodation of distinct and diverse fuel formulations. The approach is tiered by design, in order to allow for sequentially more sophisticated investigations as knowledge gaps are identified and re-prioritized by the ongoing research. The assessment also involves peer review in order to provide coupling between risk assessment and stakeholder investment, as well as constructive or confrontational feedback. The multimedia assessment

  15. Review: Circulation of Inorganic Elements in Combustion of Alternative Fuels in Cement Plants

    DEFF Research Database (Denmark)

    Cortada Mut, Maria del Mar; Nørskov, Linda Kaare; Jappe Frandsen, Flemming;

    2015-01-01

    Cement production is an energy-intensive process, which traditionally has been dependent on fossil fuels. However, the use of alternative fuels, i.e., selected waste, biomass, and byproducts with recoverable calorific value, is constantly increasing. Combustion of these fuels is more challenging......, compared to fossil fuels, because of a lack of experience and different chemical and physical properties. When complete oxidation Of fuels in the calciner and main burner is not achieved, they burn in direct contact with the bed material of the rotary kiln, causing local reducing conditions and increasing...... the internal circulation of S, Cl, Na, and K. Compounds containing these elements, such as alkali salts, evaporate when exposed to high temperatures and subsequently condense in colder parts of the plant. The transformation of the volatile inorganic species at different locations in the cement plant...

  16. Dimethyl ether as alternative fuel for CI engine and vehicle

    Institute of Scientific and Technical Information of China (English)

    Zhen HUANG; Xinqi QIAO; Wugao ZHANG; Junhua WU; Junjun ZHANG

    2009-01-01

    As a developing and the most populous country in the world, China faces major challenges in energy supply and environmental protection. It is of great importance to develop clean and alternative fuels for internal combustion engines. On the basis of researches on DME engine and vehicle at Shanghai Jiaotong University in the last twelve years, fuel injection, combustion, performance and exhaust emissions of DME engine and DME vehicle are introduced in this paper. The results indicate that DME engines can achieve high thermal efficiency and ultra low emissions, and will play a significant role in meeting the energy demand while minimizing environmental impact in China.

  17. Greenfield Alternative Study LEU-Mo Fuel Fabrication Facility

    Energy Technology Data Exchange (ETDEWEB)

    Washington Division of URS

    2008-07-01

    This report provides the initial “first look” of the design of the Greenfield Alternative of the Fuel Fabrication Capability (FFC); a facility to be built at a Greenfield DOE National Laboratory site. The FFC is designed to fabricate LEU-Mo monolithic fuel for the 5 US High Performance Research Reactors (HPRRs). This report provides a pre-conceptual design of the site, facility, process and equipment systems of the FFC; along with a preliminary hazards evaluation, risk assessment as well as the ROM cost and schedule estimate.

  18. Sweet Sorghum Alternative Fuel and Feed Pilot Project

    Energy Technology Data Exchange (ETDEWEB)

    Slack, Donald C. [Univ. of Arizona, Tucson, AZ (United States). Agricultural and Biosystems Engineering Dept.; Kaltenbach, C. Colin [Univ. of Arizona, Tucson, AZ (United States)

    2013-07-30

    The University of Arizona undertook a “pilot” project to grow sweet sorghum on a field scale (rather than a plot scale), produce juice from the sweet sorghum, deliver the juice to a bio-refinery and process it to fuel-grade ethanol. We also evaluated the bagasse for suitability as a livestock feed and as a fuel. In addition to these objectives we evaluated methods of juice preservation, ligno-cellulosic conversion of the bagasse to fermentable sugars and alternative methods of juice extraction.

  19. Diesel fuel processor for PEM fuel cells: Two possible alternatives (ATR versus SR)

    Science.gov (United States)

    Cutillo, A.; Specchia, S.; Antonini, M.; Saracco, G.; Specchia, V.

    There are large efforts in exploring the on-board reforming technologies, which would avoid the actual lack of hydrogen infrastructure and related safety issues. From this view point, the present work deals with the comparison between two different 10 kW e fuel processors (FP) systems for the production of hydrogen-rich fuel gas starting from diesel oil, based respectively on autothermal (ATR) and steam-reforming (SR) process and related CO clean-up technologies; the obtained hydrogen rich gas is fed to the PEMFC stack of an auxiliary power unit (APU). Based on a series of simulations with Matlab/Simulink, the two systems were compared in terms of FP and APU efficiency, hydrogen concentration fed to the FC, water balance and process scheme complexity. Notwithstanding a slightly higher process scheme complexity and a slightly more difficult water recovery, the FP based on the SR scheme, as compared to the ATR one, shows higher efficiency and larger hydrogen concentration for the stream fed to the PEMFC anode, which represent key issues for auxiliary power generation based on FCs as compared, e.g. to alternators.

  20. Peat gasification and new alternatives of electricity production

    Energy Technology Data Exchange (ETDEWEB)

    Solantaus, Y.

    1986-01-01

    Electricity, chemicals and liquid fuels can be produced from peat by gasification. If the product gas is used in a gas turbine, the efficiency of electricity production is higher in a combined gasification-gas turbine plant than in a conventional condensation power plant. If the gas is first led to chemical conversion and the unreacted gas is then burnt in a gas turbine, for example, octane boosters for liquid fuels and electricity can be produced in the same plant. Experimental knowhow of gasification and new syntheses have been critically evaluated in a work carried out at the Laboratory of Fuel Processing Technology of VTT. Concepts have been developed for processes, and then the actual techno-economic evaluations have been carried out. THe gasification-gas turbine plant may in the future offer a competitive alternative to the present energy production methods. Combined process alternatives based on gasification are fairly attractive also with regard to environmental protection. The feasibility of the production of chemicals and liquid fuel blend components is hihgly dependent on the prices of other raw materials.

  1. Aviation fuel and future oil production scenarios

    OpenAIRE

    2009-01-01

    Most aviation fuels are jet fuels originating from crude oil. Crude oil must be refined to be useful and jet fuel is only one of many products that can be derived from crude oil. Jet fuel is extracted from the middle distillates fraction and competes, for example, with the production of diesel. Crude oil is a limited natural resource subject to depletion and several reports indicate that the world's crude oil production is close to the maximum level and that it will start to decrease after re...

  2. Effect of Selected Alternative Fuels and Raw Materials on the Cement Clinker Quality

    Science.gov (United States)

    Strigáč, Július

    2015-11-01

    The article deals with the study of the effects of alternative fuels and raw materials on the cement clinker quality. The clinker quality was expressed by the content of two principal minerals alite C3S and belite C2S. The additions of alternative fuels ashes and raw materials, in principle, always increased the belite content and conversely reduced the amount of alite. The alternative fuels with high ash content were used such as the meat-bone meal, sewage sludge from sewage treatment plants and paper sludge and the used alternative raw materials were metallurgical slags - granulated blastfurnace slag, air cooled blastfurnace slag and demetallized steel slag, fluidized bed combustion fly ash and waste glass. Meat-bone meal, sewage sludge from sewage treatment plants and paper sludge were evaluated as moderately suitable alternative fuels which can be added in the amounts of 2.8 wt. % addition of meat-bone meals ash, 3.64 wt. % addition of sewage sludge ash and 3.8 wt. % addition of paper sludge ash to the cement raw mixture. Demetallised steel slag is suitable for production of special sulphate resistant cement clinker for CEM I -SR cement with addition up to 5 wt. %. Granulated blastfurnace slag is a suitable alternative raw material with addition 4 wt. %. Air cooled blastfurnace slag is a suitable alternative raw material with addition 4.2 wt. %. Waste glass is not very appropriate alternative raw material with addition only 1.16 wt. %. Fluidized bed combustion fly ash appears not to be equally appropriate alternative raw material for cement clinker burning with less potential utilization in the cement industry and with addition 3.41 wt. %, which forms undesired anhydrite CaSO4 in the cement clinker.

  3. Effect of Selected Alternative Fuels and Raw Materials on the Cement Clinker Quality

    Directory of Open Access Journals (Sweden)

    Strigáč Július

    2015-11-01

    Full Text Available The article deals with the study of the effects of alternative fuels and raw materials on the cement clinker quality. The clinker quality was expressed by the content of two principal minerals alite C3S and belite C2S. The additions of alternative fuels ashes and raw materials, in principle, always increased the belite content and conversely reduced the amount of alite. The alternative fuels with high ash content were used such as the meat-bone meal, sewage sludge from sewage treatment plants and paper sludge and the used alternative raw materials were metallurgical slags - granulated blastfurnace slag, air cooled blastfurnace slag and demetallized steel slag, fluidized bed combustion fly ash and waste glass. Meat-bone meal, sewage sludge from sewage treatment plants and paper sludge were evaluated as moderately suitable alternative fuels which can be added in the amounts of 2.8 wt. % addition of meat-bone meals ash, 3.64 wt. % addition of sewage sludge ash and 3.8 wt. % addition of paper sludge ash to the cement raw mixture. Demetallised steel slag is suitable for production of special sulphate resistant cement clinker for CEM I –SR cement with addition up to 5 wt. %. Granulated blastfurnace slag is a suitable alternative raw material with addition 4 wt. %. Air cooled blastfurnace slag is a suitable alternative raw material with addition 4.2 wt. %. Waste glass is not very appropriate alternative raw material with addition only 1.16 wt. %. Fluidized bed combustion fly ash appears not to be equally appropriate alternative raw material for cement clinker burning with less potential utilization in the cement industry and with addition 3.41 wt. %, which forms undesired anhydrite CaSO4 in the cement clinker.

  4. Fatty acid alkyl esters: perspectives for production of alternative biofuels.

    Science.gov (United States)

    Röttig, Annika; Wenning, Leonie; Bröker, Daniel; Steinbüchel, Alexander

    2010-02-01

    The global economy heads for a severe energy crisis: whereas the energy demand is going to rise, easily accessible sources of crude oil are expected to be depleted in only 10-20 years. Since a serious decline of oil supply and an associated collapse of the economy might be reality very soon, alternative energies and also biofuels that replace fossil fuels must be established. In addition, these alternatives should not further impair the environment and climate. About 90% of the biofuel market is currently captured by bioethanol and biodiesel. Biodiesel is composed of fatty acid alkyl esters (FAAE) and can be synthesized by chemical, enzymatic, or in vivo catalysis mainly from renewable resources. Biodiesel is already established as it is compatible with the existing fuel infrastructure, non-toxic, and has superior combustion characteristics than fossil diesel; and in 2008, the global production was 12.2 million tons. The biotechnological production of FAAE from low cost and abundant feedstocks like biomass will enable an appreciable substitution of petroleum diesel. To overcome high costs for immobilized enzymes, the in vivo synthesis of FAAE using bacteria represents a promising approach. This article points to the potential of different FAAE as alternative biofuels, e.g., by comparing their fuel properties. In addition to conventional production processes, this review presents natural and genetically engineered biological systems capable of in vivo FAAE synthesis.

  5. 10 CFR 490.203 - Light Duty Alternative Fueled Vehicle Plan.

    Science.gov (United States)

    2010-01-01

    ... Section 490.203 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ALTERNATIVE FUEL TRANSPORTATION PROGRAM Mandatory State Fleet Program § 490.203 Light Duty Alternative Fueled Vehicle Plan. (a) General Provisions... fleets, a State may follow a Light Duty Alternative Fueled Vehicle Plan that has been approved by...

  6. Software product lines : Organizational alternatives

    NARCIS (Netherlands)

    Bosch, J

    2001-01-01

    Software product lines enjoy increasingly wide adoption in the software industry. Most authors focus on the technical and process aspects and assume an organizational model consisting of a domain engineering unit and several application engineering units. In our cooperation with several software dev

  7. 75 FR 26121 - Regulation of Fuels and Fuel Additives: Alternative Affirmative Defense Requirements for Ultra...

    Science.gov (United States)

    2010-05-11

    ...: Jaimee Dong, Compliance and Innovative Strategies Division, Office of Transportation and Air Quality... include those involved with the production, importation, distribution, marketing, or retailing of diesel... Refiners. Industry 422710 5171 Diesel Fuel Marketers and Distributors. Industry 484220 4212 Diesel...

  8. Survey of alternative feedstocks for biodiesel production

    Science.gov (United States)

    Summarized will be results obtained from the production of biodiesel from several alternative feedstocks with promising agronomic characteristics. Such feedstocks include camelina (Camelina sativa L.), coriander (Coriandrum sativum L.), field pennycress (Thlaspi arvense L.), and meadowfoam (Limnanth...

  9. Development And Testing Of Biogas-Petrol Blend As An Alternative Fuel For Spark Ignition Engine

    Directory of Open Access Journals (Sweden)

    Awogbemi

    2015-08-01

    Full Text Available Abstract This research is on the development and testing of a biogas-petrol blend to run a spark ignition engine. A2080 ratio biogaspetrol blend was developed as an alternative fuel for spark ignition engine test bed. Petrol and biogas-petrol blend were comparatively tested on the test bed to determine the effectiveness of the fuels. The results of the tests showed that biogas petrol blend generated higher torque brake power indicated power brake thermal efficiency and brake mean effective pressure but lower fuel consumption and exhaust temperature than petrol. The research concluded that a spark ignition engine powered by biogas-petrol blend was found to be economical consumed less fuel and contributes to sanitation and production of fertilizer.

  10. Alternative Sources of Energy - An Introduction to Fuel Cells

    Science.gov (United States)

    Merewether, E.A.

    2003-01-01

    Fuel cells are important future sources of electrical power and could contribute to a reduction in the amount of petroleum imported by the United States. They are electrochemical devices similar to a battery and consist of a container, an anode, a cathode, catalysts, an intervening electrolyte, and an attached electrical circuit. In most fuel cell systems, hydrogen is supplied to the anode and oxygen to the cathode which results in the production of electricity, water, and heat. Fuel cells are comparatively efficient and reliable, have no moving parts, operate without combustion, and are modular and scale-able. Their size and shape are flexible and adaptable. In operation, they are nearly silent, are relatively safe, and generally do not pollute the environment. During recent years, scientists and engineers have developed and refined technologies relevant to a variety of fuel cells. Types of fuel cells are commonly identified by the composition of their electrolyte, which could be either phosphoric acid, an alkaline solution, a molten carbonate, a solid metal oxide, or a solid polymer membrane. The electrolyte in stationary power plants could be phosphoric acid, molten carbonates, or solid metal oxides. For vehicles and smaller devices, the electrolyte could be an alkaline solution or a solid polymer membrane. For most fuel cell systems, the fuel is hydrogen, which can be extracted by several procedures from many hydrogen-bearing substances, including alcohols, natural gas (mainly methane), gasoline, and water. There are important and perhaps unresolved technical problems associated with using fuel cells to power vehicles. The catalysts required in several systems are expensive metals of the platinum group. Moreover, fuel cells can freeze and not work in cold weather and can be damaged by impacts. Storage tanks for the fuels, particularly hydrogen, must be safe, inexpensive, of a reasonable size, and contain a supply sufficient for a trip of several hundred miles

  11. State and Alternative Fuel Provider Fleets Alternative Compliance; U.S. Department of Energy (DOE), Energy Efficiency & Renewable Energy (EERE)

    Energy Technology Data Exchange (ETDEWEB)

    None

    2015-08-01

    The final rule of the Energy Policy Act of 2005 and its associated regulations enable covered state and alternative fuel provider fleets to obtain waivers from the alternative fuel vehicle (AFV)-acquisition requirements of Standard Compliance. Under Alternative Compliance, covered fleets instead meet a petroleum-use reduction requirement. This guidance document is designed to help fleets better understand the Alternative Compliance option and successfully complete the waiver application process.

  12. Potential impacts on air quality of the use of ethanol as an alternative fuel. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Gaffney, J.S.; Marley, N.A. [Argonne National Lab., IL (United States)

    1994-09-01

    The use of ethanol/gasoline mixtures in motor vehicles has been proposed as an alternative fuel strategy that might improve air quality while minimizing US dependence on foreign oil. New enzymatic production methodologies are being explored to develop ethanol as a viable, economic fuel. In an attempt to reduce urban carbon monoxide (CO) and ozone levels, a number of cities are currently mandating the use of ethanol/gasoline blends. However, it is not at all clear that these blended fuels will help to abate urban pollution. In fact, the use of these fuels may lead to increased levels of other air pollutants, specifically aldehydes and peroxyacyl nitrates. Although these pollutants are not currently regulated, their potential health and environmental impacts must be considered when assessing the impacts of alternative fuels on air quality. Indeed, formaldehyde has been identified as an important air pollutant that is currently being considered for control strategies by the State of California. This report focuses on measurements taken in Albuquerque, New Mexico during the summer of 1993 and the winter of 1994 as an initial attempt to evaluate the air quality effects of ethanol/gasoline mixtures. The results of this study have direct implications for the use of such fuel mixtures as a means to reduce CO emissions and ozone in a number of major cities and to bring these urban centers into compliance with the Clean Air Act.

  13. Multiple criteria decision making of alternative fuels for waste collection vehicles in southeast region of Serbia

    Directory of Open Access Journals (Sweden)

    Petrović Goran S.

    2016-01-01

    Full Text Available In this paper multiple criteria decision making approach of alternative fuels for waste collection vehicles in southeast region of Serbia was presented. Eight alternative fuels and advanced vehicle technologies were ranked according to thirteen criteria, including financial, socio-technical, and environmental. Assessment of alternatives was performed by using the weighted aggregated sum product assessment method and results were verified using multi-objective optimization on the basis of ratio analysis method. Considered criteria were obtained from previous researches and by assessment of professional experts from manufacturing industries, public utility companies, and academics institutions. The analysis showed that both biodiesel fuels - derived from used cooking oil or from vegetable oils are the best alternative fuels for Serbian waste collection vehicles in this point of time. Compressed natural gas-powered vehicles were also ranked high in this analysis, but due to the lack of financial capability for their purchase (especially in southeast region of Serbia, their gradual introduction into the waste collection fleet was proposed.

  14. Use of alternative fuels in cement manufacture. Effect on clinker and cement characteristics and properties

    Directory of Open Access Journals (Sweden)

    Puertas, F.

    2004-06-01

    Full Text Available This paper compares industrial clinker and cement produced using conventional and alternative fuels (animal meal, tyres or a mixture of the two. The results show no relevant differences in terms of mineralogical composition between the clinker manufactured with alternative fuels and the product obtained using conventional fuel. Clinker produced with alternative fuels at any one factory have a very similar or even lower content in heavy metals than the product manufactured with conventional fuel in the same plant (with the sole exception of Zn when the alternative fuel used is shredded tyres. Mineralogical and morphological analyses reveal no significant differences between the two types of products that can be attributed to the type of fuel used in their manufacture. All six types of cement studied are compliant with the existing legislation as regards both physical and chemical properties. Cement compressive strength is found to be to legal standards regardless of the type of fuel used. Finally, the rheological properties of the cement paste are observed to be unaffected by the type of fuel.

    Se han estudiado clínkeres y cementos obtenidos en procesos industriales que han utilizado combustibles convencionales y combustibles alternativos (harinas cárnicas, neumáticos usados y mezclas de ambos. Los resultados obtenidos han demostrado que los clínkeres fabricados con los combustibles alternativos no presentan diferencias significativas en la composición mineralógica respecto a los obtenidos con combustibles convencionales. Los contenidos de metales pesados en los clínkeres procedentes de la misma fábrica (a excepción de los contenidos en Zn en aquéllos que utilizan neumáticos son muy similares o incluso inferiores a los fabricados con combustibles convencionales. Los análisis mineralógico y morfológico de los clínkeres no evidencian diferencias asignables al tipo de combustible utilizado. Todos los cementos estudiados cumplen

  15. The origin of organic pollutants from the combustion of alternative fuels: Phase IV report

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, P.H.; Dellinger, B. [Univ. of Dayton, OH (United States). Research Institute; Sidhu, S.K. [and others

    1997-06-01

    As part of the US-DOE`s on-going interest in the use of alternative automotive fuels, the University of Dayton Research Institute has been conducting research on pollutant emissions resulting from the combustion of candidate fuels. This research, under the direction and sponsorship of the NREL, has been concerned primarily with the combustion of compressed natural gas, liquefied petroleum gas (LPG), methanol, and ethanol. In the first 24 months of this program, studies of the oxygen rich, stoichiometric, and fuel-rich thermal degradation of these fuels in the temperature range of 300 to 1100{degrees}C at atmospheric pressure and for reaction times of 1.0 and 2.0 s were completed. Trace organic products were identified and quantified for each fuel as a function of temperature. The results of these studies agreed well with the results of tail-pipe emission studies in that the types and quantity of emissions measured in both the laboratory and engine tests were shown to be very similar under certain operating conditions. However, some chemicals were observed in the laboratory studies that were not observed in the engine studies and vice versa. This result is important in that it has implications concerning the origin of these emissions. Experiments concerning the NO perturbed oxidation of methanol, M85, ethanol, and E85 indicated the presence of complex oxidation chemistry. At mild temperatures, NO addition resulted in enhanced fuel conversion. At elevated temperatures, an inhibitory effect was observed through increased yields of both partial oxidation and pyrolysis-type reaction products. Comparison of flow reactor product distributions with engine test results generally indicated improved comparisons when NO was added to the fuel. Analysis of secondary components of alcohol fuels resulted in some unexpected observations. Several previously unidentified species were observed in these experiments which may impact atmospheric reactivity assessments of these fuels.

  16. Potential use of California lignite and other alternate fuel for enhanced oil recovery. Phase I and II. Final report. [As alternative fuels for steam generation in thermal EOR

    Energy Technology Data Exchange (ETDEWEB)

    Shelton, R.; Shimizu, A.; Briggs, A.

    1980-02-01

    The Nation's continued reliance on liquid fossil fuels and decreasing reserves of light oils gives increased impetus to improving the recovery of heavy oil. Thermal enhanced oil recovery EOR techniques, such as steam injection, have generally been the most effective for increasing heavy oil production. However, conventional steam generation consumes a large fraction of the produced oil. The substitution of alternate (solid) fuels would release much of this consumed oil to market. This two-part report focuses on two solid fuels available in California, the site of most thermal EOR - petroleum coke and lignite. Phase I, entitled Economic Analysis, shows detailed cost comparisons between the two candidate fuels and also with Western coal. The analysis includes fuels characterizations, process designs for several combustion systems, and a thorough evaluation of the technical and economic uncertainties. In Phase II, many technical parameters of petroleum coke combustion were measured in a pilot-plant fluidized bed. The results of the study showed that petroleum coke combustion for EOR is feasible and cost effective in a fluidized bed combustor.

  17. Biodiesel from plant seed oils as an alternate fuel for compression ignition engines-a review.

    Science.gov (United States)

    Vijayakumar, C; Ramesh, M; Murugesan, A; Panneerselvam, N; Subramaniam, D; Bharathiraja, M

    2016-12-01

    The modern scenario reveals that the world is facing energy crisis due to the dwindling sources of fossil fuels. Environment protection agencies are more concerned about the atmospheric pollution due to the burning of fossil fuels. Alternative fuel research is getting augmented because of the above reasons. Plant seed oils (vegetable oils) are cleaner, sustainable, and renewable. So, it can be the most suitable alternative fuel for compression ignition (CI) engines. This paper reviews the availability of different types of plant seed oils, several methods for production of biodiesel from vegetable oils, and its properties. The different types of oils considered in this review are cashew nut shell liquid (CNSL) oil, ginger oil, eucalyptus oil, rice bran oil, Calophyllum inophyllum, hazelnut oil, sesame oil, clove stem oil, sardine oil, honge oil, polanga oil, mahua oil, rubber seed oil, cotton seed oil, neem oil, jatropha oil, egunsi melon oil, shea butter, linseed oil, Mohr oil, sea lemon oil, pumpkin oil, tobacco seed oil, jojoba oil, and mustard oil. Several methods for production of biodiesel are transesterification, pre-treatment, pyrolysis, and water emulsion are discussed. The various fuel properties considered for review such as specific gravity, viscosity, calorific value, flash point, and fire point are presented. The review also portrays advantages, limitations, performance, and emission characteristics of engine using plant seed oil biodiesel are discussed. Finally, the modeling and optimization of engine for various biofuels with different input and output parameters using artificial neural network, response surface methodology, and Taguchi are included.

  18. Advanced materials for alternative fuel capable directly fired heat engines

    Energy Technology Data Exchange (ETDEWEB)

    Fairbanks, J.W.; Stringer, J. (eds.)

    1979-12-01

    The first conference on advanced materials for alternative fuel capable directly fired heat engines was held at the Maine Maritime Academy, Castine, Maine. It was sponsored by the US Department of Energy, (Assistant Secretary for Fossil Energy) and the Electric Power Research Institute, (Division of Fossil Fuel and Advanced Systems). Forty-four papers from the proceedings have been entered into EDB and ERA and one also into EAPA; three had been entered previously from other sources. The papers are concerned with US DOE research programs in this area, coal gasification, coal liquefaction, gas turbines, fluidized-bed combustion and the materials used in these processes or equipments. The materials papers involve alloys, ceramics, coatings, cladding, etc., and the fabrication and materials listing of such materials and studies involving corrosion, erosion, deposition, etc. (LTN)

  19. Composition and methods for improved fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Steele, Philip H.; Tanneru, Sathishkumar; Gajjela, Sanjeev K.

    2015-12-29

    Certain embodiments of the present invention are configured to produce boiler and transportation fuels. A first phase of the method may include oxidation and/or hyper-acidification of bio-oil to produce an intermediate product. A second phase of the method may include catalytic deoxygenation, esterification, or olefination/esterification of the intermediate product under pressurized syngas. The composition of the resulting product--e.g., a boiler fuel--produced by these methods may be used directly or further upgraded to a transportation fuel. Certain embodiments of the present invention also include catalytic compositions configured for use in the method embodiments.

  20. Evaluation of wood residues from Crete as alternative fuels

    Directory of Open Access Journals (Sweden)

    D. Vamvuka, G. Bandelis

    2010-07-01

    Full Text Available Olive and citrus prunings, the main agricultural residues of Crete, are considered to be of premium importance for local energy production, substituting a large part of conventional fuels. The thermal behaviour of these fuels during combustion was studied by thermogravimetry, at non-isothermal heating conditions. Fly ashes were collected from tests in a lab-scale fluidized bed facility. The effect of the inorganic constituents of the fuels on slagging/fouling and agglomeration propensities, as well as environmental pollution was examined. Kinetic models were developed and reaction rates were determined. The agroresidues studied were characterized as good quality fuels, having high volatile and low ash and sulphur contents. Their ash was rich in Ca, Si, K and P minerals. However, fly ashes were poorer in alkali compounds, implying lower deposition and corrosion problems in boilers. The environmental impact of heavy metals is negligible. The thermochemical reactivity of the two fuels in air was very similar. A power low model fitted the experimental results accurately.

  1. Biofuel: an alternative to fossil fuel for alleviating world energy and economic crises.

    Science.gov (United States)

    Bhattarai, Keshav; Stalick, Wayne M; McKay, Scott; Geme, Gija; Bhattarai, Nimisha

    2011-01-01

    The time has come when it is desirable to look for alternative energy resources to confront the global energy crisis. Consideration of the increasing environmental problems and the possible crisis of fossil fuel availability at record high prices dictate that some changes will need to occur sooner rather than later. The recent oil spill in the Gulf of Mexico is just another example of the environmental threats that fossil fuels pose. This paper is an attempt to explore various bio-resources such as corn, barley, oat, rice, wheat, sorghum, sugar, safflower, and coniferous and non-coniferous species for the production of biofuels (ethanol and biodiesel). In order to assess the potential production of biofuel, in this paper, countries are organized into three groups based on: (a) geographic areas; (b) economic development; and(c) lending types, as classified by the World Bank. First, the total fossil fuel energy consumption and supply and possible carbon emission from burning fossil fuel is projected for these three groups of countries. Second, the possibility of production of biofuel from grains and vegetative product is projected. Third, a comparison of fossil fuel and biofuel is done to examine energy sustainability issues.

  2. Socio-environmental Impacts Associated with Burning Alternative Fuels in Clinker Kilns

    Directory of Open Access Journals (Sweden)

    F. B. Mainier

    2013-08-01

    Full Text Available The pollutants found in emissions from cement plants depend on the processes used and the operation of the clinker kilns. Another crucial aspect concerns the characteristics of raw materials and fuels. The intensive use of fuels in rotary kilns of cement plants and the increasing fuel diversification, including fuels derived from coal and oil, from a multitude of industrial waste and from biomass, charcoal and agricultural waste (sugarcane bagasse, rice husk, is increasing the possibilities of combinations or mixtures of different fuels, known as blends. Thus, there are socio-environmental impacts associated with the burning of alternative fuels in clinker kilns. In view of the growing trend of entrepreneurs who want to target the waste produced in their unit and of the owners of the cement plants who want to reduce their production costs by burning a waste with lower cost than conventional fuels, it is necessary to warn that a minimum level of environmental care should be followed regarding these decisions. It is necessary to monitor the points of emission from cement kilns and in the wider area influenced by the plant, in order to improve environmental quality. Laboratory studies of burning vulcanised rubber contaminated with arsenic simulate the burning of used tyres in cement clinker kilns producing SO2 and As2O3.

  3. EPAct Alternative Fuel Transportation Program: State and Alternative Fuel Provider Fleet Compliance Annual Report, Fleet Compliance Results for MY 2014/ FY 2015

    Energy Technology Data Exchange (ETDEWEB)

    2016-04-01

    This annual report of the Alternative Fuel Transportation Program, which ensures compliance with DOE regulations covering state government and alternative fuel provider fleets pursuant to the Energy Policy Act of 1992 (EPAct), as amended, provides fleet compliance results for manufacturing year 2014 / fiscal year 2015.

  4. Residue Derived Fuels as an Alternative Fuel for the Hellenic Power Generation Sector and their Potential for Emissions ReductionConstantinos S. Psomopoulos

    Directory of Open Access Journals (Sweden)

    Constantinos S. Psomopoulos

    2014-09-01

    Full Text Available The European Union Landfill Directive (1999/31 EC promotes more environmental friendly waste management options, by reducing the amount of wastes and more specific of biodegradable wastes, disposed of in landfills. The EU member states are adopting the mechanical-biological treatment process for municipal solid waste and non-hazardous industrial wastes to comply with the abovementioned Directive's targets on landfill diversion, and produce waste derived fuels such as refuse derived fuel and solid recovered fuel. Waste derived fuels present high calorific values depending on their synthesis and are being used both in dedicated waste-to-energy plants and as fuel substitutes in industrial processes. In this paper the refuse derived fuel and solid recovered fuel production and utilisation options in European Union are presented, and the possibilities in Greece based on the waste production and National Plan for Waste Management of the Ministry of Environment is attempted. The existing and ongoing studies on co-combustion and co-gasification with brown coal support the use of refuse derived fuel and solid recovered fuel as fuel on Hellenic Power Sector, adopting in the existing lignite power plants adequate Air Pollution Control systems. If the co-combustion or co-gasification of these alternative fuels is adopted from the Hellenic Power Sector a reduction on emissions is expected that cannot be neglected.

  5. Evaluation of hazelnut kernel oil of Turkish origin as alternative fuel in diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Gumus, M. [Automotive Division, Department of Mechanical Education, Marmara University, Ziverbey, 34722 Istanbul (Turkey)

    2008-11-15

    In the present study, hazelnut kernel oil of Turkish origin was evaluated as alternative fuel in a diesel engine. Potential hazelnut production throughout the world and the status of Turkey were examined. Hazelnut (Corylus avellana L.) kernel oil was transesterified with methanol using potassium hydroxide as catalyst to obtain hazelnut kernel oil methyl ester (HOME) and a comprehensive experimental investigation was carried out to examine performance and emissions of a direct injection diesel engine running with HOME and its blends with diesel fuel. Experimental parameters included the percentage of HOME in the blend, engine load, injection timing, compression ratio, and injector. The cost analysis of HOME production comparing to the price of conventional diesel fuel was performed for last decade was performed. Results showed that HOME and its blends with diesel fuel are generally comparable to diesel fuel and small modifications such as increasing injection timing, compression ratio and injector opening pressure provide significant improvement in performance and emissions. It is also expected that the price of HOME will be lower than the price of conventional diesel fuel in the near future. (author)

  6. Inedible vegetable oils and their derivatives for alternative diesel fuels in CI engines: A review

    Energy Technology Data Exchange (ETDEWEB)

    No, Soo-Young [Chungbuk National University, Department of Biosystems Engineering, Cheongju 361-763 (Korea, Republic of)

    2011-01-15

    The use of inedible vegetable oils as an alternative fuel for diesel engine is accelerated by the energy crisis due to depletion of resources and increased environmental problems including the great need for edible oil as food and the reduction of biodiesel production cost, etc. Of a lot of inedible vegetable oils which can be exploited for substitute fuel as diesel fuel, seven vegetable oils, i.e., jatropha, karanja, mahua, linseed, rubber seed, cottonseed and neem oils were selected for discussion in this review paper. The application of jatropha oil as a liquid fuel for CI engine can be classified with neat jatropha oil, engine modifications such as preheating, and dual fuelling, and fuel modifications such as jatropha oil blends with other fuels, mostly with diesel fuel, biodiesel, biodiesel blends and degumming. Therefore, jatropha oil is a leading candidate for the commercialization of non-edible vegetable oils. There exists a big difference in the fuel properties of seven inedible vegetable oils and its biodiesels considered in this review. It is clear from this review that biodiesel generally causes an increase in NOx emission and a decrease in HC, CO and PM emissions compared to diesel. It was reported that a diesel engine without any modification would run successfully on a blend of 20% vegetable oil and 80% diesel fuel without damage to engine parts. This trend can be applied to the biodiesel blends even though particular biodiesel shows 40% blend. In addition, the blends of biodiesel and diesel can replace the diesel fuel up to 10% by volume for running common rail direct injection system without any durability problems. (author)

  7. Measured moisture properties for alternative insulation products

    DEFF Research Database (Denmark)

    Hansen, Ernst Jan De Place; Hansen, Kurt Kielsgaard; Padfield, Tim

    1999-01-01

    During the past few years there has been a growing interest in using alternative insulation products in buildings. Among these products are the organic materials cellulose fibre, flax and sheep's wool as well as the inorganic perlite. The organic materials are regarded with some suspicion, because...... of their hygroscopicity. This paper describes two of the moisture-related properties of these materials: the water sorption and the water vapour transmission. For reference, some mineral fibre products are studied as well....

  8. Techno-economic evaluation of alternative process configurations for the production of biomass-to-liquid (BTL) fuels and chemicals; Techno-oekonomische Bewertung alternativer Verfahrenskonfigurationen zur Herstellung von Biomass-to-Liquid (BtL) Kraftstoffen und Chemikalien

    Energy Technology Data Exchange (ETDEWEB)

    Trippe, Frederik

    2013-11-01

    The aim of the present work is to identify, from a technical and economic point of view promising procedural configurations of a biomass-to-liquid (BTL) concept for the production of fuels and chemicals from biomass and to evaluate. The example of the process bioliq a techno-economic assessment model is developed, the process design parameters directly linked to their economic impact.

  9. Biomass - alternative renewable energy source to the fossil fuels

    Directory of Open Access Journals (Sweden)

    Koruba Dorota

    2017-01-01

    Full Text Available The article presents the fossil fuels combustion effects in terms of the dangers of increasing CO2 concentration in the atmosphere. Based on the bibliography review the negative impact of increased carbon dioxide concentration on the human population is shown in the area of the external environment, particularly in terms of the air pollution and especially the impact on human health. The paper presents biomass as the renewable energy alternative source to fossil fuels which combustion gives a neutral CO2 emissions and therefore should be the main carrier of primary energy in Poland. The paper presents the combustion heat results and humidity of selected dry wood pellets (pellets straw, energy-crop willow pellets, sawdust pellets, dried sewage sludge from two sewage treatment plants of the Holly Cross province pointing their energy potential. In connection with the results analysis of these studies the standard requirements were discussed (EN 14918:2010 “Solid bio-fuels-determination of calorific value” regarding the basic parameters determining the biomass energy value (combustion heat, humidity.

  10. Advisable alternative fuels for Mexico; Combustibles alternativos convenientes para Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar Gonzalez, Jorge Luis [ICA Fluor (Mexico)

    2007-07-15

    The alternative fuels are born with the goal of not damaging the environment; biodiesel, electricity, ethanol, hydrogen, methanol, natural gas, LP gas, are the main alternative fuels. However, the biodiesel and bioetanol are the only completely renewable ones, this makes them ideal to be developed in Mexico, since the agricultural sector could be fortified, the technological independence be favored, improve the conservation of the oil resources and by all means not to affect the environment. On the other hand, also efficient cultivation techniques should be developed to guarantee the economy of the process. [Spanish] Los combustibles alternativos nacen con la meta de no danar el medio ambiente; el biodiesel, electricidad, etanol, hidrogeno, metanol, gas natural, gas LP, son los principales combustibles alternativos. No obstante, el biodiesel y el bioetanol son los unicos completamente renovables, esto los hace ideales para desarrollarse en Mexico, ya que se podria fortalecer el sector agricola, favorecer la independencia tecnologica, mejorar la administracion de los recursos petroleros y por supuesto no afectar al medio ambiente. Por otro lado tambien se tendrian que desarrollar tecnicas de cultivo eficientes para garantizar la economia del proceso.

  11. Alternative Practices to Improve Surface Fleet Fuel Efficiency

    Science.gov (United States)

    2014-09-01

    practices that, if changed, could provide significant fuel savings for fossil fuel ships. Recent and potential future budget cuts give fuel conservation...changed, could provide significant fuel savings for fossil fuel ships. Recent and potential future budget cuts give fuel conservation and efficiency...Figure 1. Navy fossil fuel expenditure for FY 2013 (after Dhoran 2014). .......................1 Figure 2. Fuel curves for a DDG showing GPH burned as

  12. Chlorella protothecoides Microalgae as an Alternative Fuel for Tractor Diesel Engines

    Directory of Open Access Journals (Sweden)

    Saddam H. Al-lwayzy

    2013-02-01

    Full Text Available Biodiesel has attracted a great deal attention recently as an alternative fuel due to increasing fuel prices and the imperative to reduce emissions. Among a wide range of biodiesel resources, microalgae are a promising alternative fuel source because of the high biomass, lipid productivity and environmentally friendliness. Microalgae is also a non-edible food, therefore, there will be no impact on the human food supply chain. In this work, petroleum diesel (PD and biodiesel from the microalgae Chlorella protothecoides (MCP-B20 blend have been used to examine the performance and the emission of a 25.8 kW agriculture tractor engine. Two engine speeds at maximum power take off (PTO power and torque have been selected for analysis using analysis of variance (ANOVA. The results showed that there is no significant difference between the engine performance when microalgae biodiesel blend (MCP-B20 and PD were used. However, a significant reduction in CO, CO2 and NO emissions was found when MCP-B20 was used. These outcomes give strong indication that microalgae can be successfully used in tractors as alternative fuel.

  13. LIQUID NATURAL GAS (LNG): AN ALTERNATIVE FUEL FROM LANDFILL GAS (LFG) AND WASTEWATER DIGESTER GAS

    Energy Technology Data Exchange (ETDEWEB)

    VANDOR,D.

    1999-03-01

    This Research and Development Subcontract sought to find economic, technical and policy links between methane recovery at landfill and wastewater treatment sites in New York and Maryland, and ways to use that methane as an alternative fuel--compressed natural gas (CNG) or liquid natural gas (LNG) -- in centrally fueled Alternative Fueled Vehicles (AFVs).

  14. Development of alternative fuels from coal-derived synthesis gas: Final topical report, demonstration of one-step slurry-phase process for the co-production of methanol and isobutanol

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-01

    Liquid phase co-production of methanol and isobutanol (LPIBOH) was de, demonstrated at DOE`s Alternative Fuels Development Unit (AFDU) in LaPorte, Texas. Methanol and isobutanol are key intermediates in a synthesis gas-based route to methyl t-butyl ether (MTBE). The technology was demonstrated in a new 18 in. slurry bubble-column reactor that was designed to demonstrate higher pressures and temperatures,higher gas superficial velocities, and lower gas hourly space velocities--all of which are conducive to obtaining optimal isobutanol yield. The integration of the new reactor into the AFDU included the addition of a high-pressure synthesis gas compressor, a high-pressure hydrogen feed source, and a closed-loop methanol- solvent absorption system to remove CO{sub 2} from the unconverted synthesis gas. These modifications were completed in January 1994. The LPIBOH run followed after a short turnaround. It employed a cesium- promoted Cu/ZnO/Al{sub 2}O{sub 3} catalyst developed in Air Products` laboratories and subsequently scaled up to a production- sized batch. Over a thirteen day campaign on simulated Shell gasifier gas, the catalyst and reactor system were tested at a matrix of pressures (750, 1300, 1735 psig) and space velocities (3000, 5000, 8200 sL/kg-hr), representing numerous first-of-a-kind run conditions for the AFDU. Inlet gas superficial velocities spanned an impressive 0.16 to 1.0 ft/sec. Stable reactor performance for a full twelve-hour data period at 1.0 ft/sec was another significant milestone for the liquid phase technology program. Apart from the catalyst deactivation, the run successfully demonstrated mixed alcohol synthesis in a slurry bubble-column reactor, as well as all of the new equipment installed for the trial. Although the full capabilities of the new oxygenates system will not be tested until future runs, the design objectives for the modifications were met with respect to the LPIBOH run.

  15. Alternate-Fueled Combustor-Sector Performance: Part A: Combustor Performance Part B: Combustor Emissions

    Science.gov (United States)

    Shouse, D. T.; Neuroth, C.; Henricks, R. C.; Lynch, A.; Frayne, C.; Stutrud, J. S.; Corporan, E.; Hankins, T.

    2010-01-01

    Alternate aviation fuels for military or commercial use are required to satisfy MIL-DTL-83133F(2008) or ASTM D 7566 (2010) standards, respectively, and are classified as drop-in fuel replacements. To satisfy legacy issues, blends to 50% alternate fuel with petroleum fuels are certified individually on the basis of feedstock. Adherence to alternate fuels and fuel blends requires smart fueling systems or advanced fuel-flexible systems, including combustors and engines without significant sacrifice in performance or emissions requirements. This paper provides preliminary performance (Part A) and emissions and particulates (Part B) combustor sector data for synthetic-parafinic-kerosene- (SPK-) type fuel and blends with JP-8+100 relative to JP-8+100 as baseline fueling.

  16. Waste Cooking Oil as an Alternate Feedstock for Biodiesel Production

    Directory of Open Access Journals (Sweden)

    M. Rafiqul Islam

    2008-04-01

    Full Text Available As crude oil price reach a new high, the need for developing alternate fuels has become acute. Alternate fuels should be economically attractive in order to compete with currently used fossil fuels. In this work, biodiesel (ethyl ester was prepared from waste cooking oil collected from a local restaurant in Halifax, Nova Scotia, Canada. Ethyl alcohol with sodium hydroxide as a catalyst was used for the transesterification process. The fatty acid composition of the final biodiesel esters was determined by gas chromatography. The biodiesel was characterized by its physical and fuel properties including density, viscosity, acid value, flash point, cloud point, pour point, cetane index, water and sediment content, total and free glycerin content, diglycerides and monoglycerides, phosphorus content and sulfur content according to ASTM standards. The viscosity of the biodiesel ethyl ester was found to be 5.03 mm2/sec at 40oC. The viscosity of waste cooking oil measured in room temperature (at 21° C was 72 mm2/sec. From the tests, the flash point was found to be 164oC, the phosphorous content was 2 ppm, those of calcium and magnesium were 1 ppm combined, water and sediment was 0 %, sulfur content was 2 ppm, total acid number was 0.29 mgKOH/g, cetane index was 61, cloud point was -1oC and pour point was -16oC. Production of biodiesel from waste cooking oils for diesel substitute is particularly important because of the decreasing trend of economical oil reserves, environmental problems caused due to fossil fuel use and the high price of petroleum products in the international market.

  17. Waste cooking oil as an alternate feedstock for biodiesel production

    Energy Technology Data Exchange (ETDEWEB)

    Chhetri, A. B.; Rafiqul Islam, M. [Civil and Resources Engineering Dalhousie University, Room D510, 1360 Barrington St., Box 1000, Halifax, N.S. B3J 2X4 (Canada); Watts, K. Ch. [Process Engineering, Dalhousie University, Halifax, NS, Box 1000, Halifax, N.S. B3J 2X4 (Canada)

    2008-07-01

    As crude oil price reach a new high, the need for developing alternate fuels has become acute. Alternate fuels should be economically attractive in order to compete with currently used fossil fuels. In this work, biodiesel (ethyl ester) was prepared from waste cooking oil collected from a local restaurant in Halifax, Nova Scotia, Canada. Ethyl alcohol with sodium hydroxide as a catalyst was used for the transesterification process. The fatty acid composition of the final biodiesel esters was determined by gas chromatography. The biodiesel was characterized by its physical and fuel properties including density, viscosity, acid value, flash point, cloud point, pour point, cetane index, water and sediment content, total and free glycerin content, diglycerides and monoglycerides, phosphorus content and sulfur content according to ASTM standards. The viscosity of the biodiesel ethyl ester was found to be 5.03 mm{sup 2}/sec at 40 {sup o}C. The viscosity of waste cooking oil measured in room temperature (at 21 {sup o}C) was 72 mm{sup 2}/sec. From the tests, the flash point was found to be 164 {sup o}C, the phosphorous content was 2 ppm, those of calcium and magnesium were 1 ppm combined, water and sediment was 0 %, sulfur content was 2 ppm, total acid number was 0.29 mg KOH/g, cetane index was 61, cloud point was -1 {sup o}C and pour point was -16 {sup o}C. Production of biodiesel from waste cooking oils for diesel substitute is particularly important because of the decreasing trend of economical oil reserves, environmental problems caused due to fossil fuel use and the high price of petroleum products in the international market. (author)

  18. Emissions from Petrol Engine Fueled Gasoline–Ethanol–Methanol (GEM Ternary mixture as Alternative Fuel

    Directory of Open Access Journals (Sweden)

    Thangavelu Saravana Kannan

    2015-01-01

    Full Text Available The increasing demands of petroleum fuels due to the rapid development automotive society coupled with the environmental pollution issues have inspired the efforts on exploring alternative fuels for internal combustion engines. Bioethanol obtained from biomass and bioenergy crops has been proclaimed as one of the feasible alternative to gasoline. In this study, the effect of gasoline–ethanol–methanol (GEM ternary blend on the emission characteristics of petrol engine was studied. Three different fuel blends, namely, E0 (gasoline, G75E21M4 (75% gasoline, 21% hydrous ethanol and 4% methanol and E25 (25% anhydrous ethanol and 75% gasoline were tested in a 1.3-l K3-VE spark-ignition engine. The results indicate that, when G75E21M4 fuel blend was used, a significant drop in CO, CO2, NOx and HC emissions by about 42%, 15%, 7% and 5.2% compared to E0, respectively. Moreover, the emission results for G75E21M4 are marginally lower than E25 whereas; HC emission was slightly higher than E25.

  19. Efficiency and exhaust gas analysis of variable compression ratio spark ignition engine fuelled with alternative fuels

    Directory of Open Access Journals (Sweden)

    N. Seshaiah

    2010-09-01

    Full Text Available Considering energy crises and pollution problems today, investigations have been concentrated on decreasing fuel consumption by using alternative fuels and on lowering the concentration of toxic components in combustion products. In the present work, the variable compression ratio spark ignition engine designed to run on gasoline has been tested with pure gasoline, LPG (Isobutene, and gasoline blended with ethanol 10%, 15%, 25% and 35% by volume. Also, the gasoline mixed with kerosene at 15%, 25% and 35% by volume without any engine modifications has been tested and presented the result. Brake thermal and volumetric efficiency variation with brake load is compared and presented. CO and CO2 emissions have been also compared for all tested fuels.

  20. Spent nuclear fuel project product specification

    Energy Technology Data Exchange (ETDEWEB)

    Pajunen, A.L.

    1998-01-30

    Product specifications are limits and controls established for each significant parameter that potentially affects safety and/or quality of the Spent Nuclear Fuel (SNF) packaged for transport to dry storage. The product specifications in this document cover the spent fuel packaged in MultiCanister Overpacks (MCOs) to be transported throughout the SNF Project. The SNF includes N Reactor fuel and single-pass reactor fuel. The FRS removes the SNF from the storage canisters, cleans it, and places it into baskets. The MCO loading system places the baskets into MCO/Cask assembly packages. These packages are then transferred to the Cold Vacuum Drying (CVD) Facility. After drying at the CVD Facility, the MCO cask packages are transferred to the Canister Storage Building (CSB), where the MCOs are removed from the casks, staged, inspected, sealed (by welding), and stored until a suitable permanent disposal option is implemented. The key criteria necessary to achieve these goals are documented in this specification.

  1. Using Alcohols as an Alternative Fuel in Internal Combustion Engines

    Directory of Open Access Journals (Sweden)

    Salih ÖZER

    2014-04-01

    Full Text Available This study summarizes the studies on alcohol use in internal combustion engines nature. Nowadays, alcohol is used in internal combustion engines sometimes in order to reduce emissions and sometimes as an alternative fuel. Even vehicle manufacturers are producing and launching vehicles that are running directly with alcohol. Many types of pure alcohol that can be used on vehicles are available on the world. Using all of these types of alcohol led to the formation of engine emissions and power curves. The studies reveal that these changes are because of the physical and chemical characteristics of alcohols. Thıs study tries to explain what kind of conclusions the physical and chemical properties cause

  2. Use of certain alternative fuels in road transport in Poland

    Science.gov (United States)

    Gis, W.; Pielecha, J.; Waśkiewicz, J.; Gis, M.; Menes, M.

    2016-09-01

    The development of biomethane and hydrogen technology in the road transport in the EU countries is recommended, among the others, in the Directive of the European Parliament and of the Council 2014/94/EU of 22 October 2014. Under the provisions of the said Directive, it is recommended to EU countries to use biomethane and progressively ensure accessibility to hydrogen cars on their territories, and above all to ensure the possibility of driving hydrogen vehicles between the member States. The territorial accessibility for biomethane vehicles is determined by the availability of biomethane refuelling infrastructure in the first place in cities and then on the road network distances recommended in this directive. The territorial accessibility for hydrogen vehicles is determined by the availability of hydrogen refuelling infrastructure, in the first place along the TEN-T network. The article presents the possibilities of using these alternative fuels in Poland, presenting some of the results of research and analysis in this area.

  3. Performance, emission and economic assessment of clove stem oil-diesel blended fuels as alternative fuels for diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Mbarawa, Makame [Department of Mechanical Engineering, Tshwane University of Technology, Private Bag X680, Pretoria 0001 (South Africa)

    2008-05-15

    In this study the performance, emission and economic evaluation of using the clove stem oil (CSO)-diesel blended fuels as alternative fuels for diesel engine have been carried out. Experiments were performed to evaluate the impact of the CSO-diesel blended fuels on the engine performance and emissions. The societal life cycle cost (LCC) was chosen as an important indicator for comparing alternative fuel operating modes. The LCC using the pure diesel fuel, 25% CSO and 50% CSO-diesel blended fuels in diesel engine are analysed. These costs include the vehicle first cost, fuel cost and exhaust emissions cost. A complete macroeconomic assessment of the effect of introducing the CSO-diesel blended fuels to the diesel engine is not included in the study. Engine tests show that performance parameters of the CSO-diesel blended fuels do not differ greatly from those of the pure diesel fuel. Slight power losses, combined with an increase in fuel consumption, were experienced with the CSO-diesel blended fuels. This is due to the low heating value of the CSO-diesel blended fuels. Emissions of CO and HC are low for the CSO-diesel blended fuels. NO{sub x} emissions were increased remarkably when the engine was fuelled with the 50% CSO-diesel blended fuel operation mode. A remarkable reduction in the exhaust smoke emissions can be achieved when operating on the CSO-diesel blended fuels. Based on the LCC analysis, the CSO-diesel blended fuels would not be competitive with the pure diesel fuel, even though the environmental impact of emission is valued monetarily. This is due to the high price of the CSO. (author)

  4. Fundamental characterization of alternate fuel effects in continuous combustion systems. Summary technical progress report, August 15, 1978-January 31, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Blazowski, W.S.; Edelman, R.B.; Wong, E.

    1980-02-27

    The overall objective of this contract is to assist in the development of fuel-flexible combustion systems for gas turbines as well as Rankine and Stirling cycle engines. The primary emphasis of the program is on liquid hydrocarbons produced from non-petroleum resources. Fuel-flexible combustion systems will provide for more rapid transition of these alternative fuels into important future energy utilization centers (especially utility power generation with the combined cycle gas turbine). The specific technical objectives of the program are: (a) develop an improved understanding of relationships between alternative fuel properties and continuous combustion system effects, and (b) provide analytical modeling/correlation capabilities to be used as design aids for development of fuel-tolerant combustion systems. This is the second major report of the program. Key experimental findings during this reporting period concern stirred combustor soot production during operation at controlled temperature conditions, soot production as a function of combustor residence time, an improved measurement technique for total hydrocarbons and initial stirred combustor results of fuel nitrogen conversion. While the results to be presented concern a stirred combustor which utilizes premixed fuel vapor/oxidant mixtures, a new combustor which combusts liquid fuel injected into the reactor as a spray has been developed and will be described. Analytical program progress includes the development of new quasiglobal models of soot formation and assessment of needs for other submodel development.

  5. Alternative indicators for measuring hospital productivity.

    Science.gov (United States)

    Serway, G D; Strum, D W; Haug, W F

    1987-08-01

    This article explores the premise that the appropriateness and usefulness of typical hospital productivity measures have been affected by three changes in delivery: Organizational restructuring and other definition and data source changes that make full-time equivalent employee (FTE) measurements ambiguous. Transition to prospective payment (diagnosis-related groups). Increase in capitation (prepaid, at risk) programs. The effects of these changes on productivity management indicate the need for alternative productivity indicators. Several productivity measures that complement these changes in internal operations and the external hospital business environment are presented. These are based on an analysis of four hospitals within a multihospital system, and an illustration and interpretation of an array of measures, based on ten months of actual data, is provided. In conclusion, the recommendation is made for hospital management to collect an expanded set of productivity measures and review them in light of changing expense and revenue management schemes inherent in new payment modes.

  6. Geography of Existing and Potential Alternative Fuel Markets in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, C.; Hettinger, D.

    2014-11-01

    When deploying alternative fuels, it is paramount to match the right fuel with the right location, in accordance with local market conditions. We used six market indicators to evaluate the existing and potential regional market health for each of the five most commonly deployed alternative fuels: electricity (used by plug-in electric vehicles), biodiesel (blends of B20 and higher), E85 ethanol, compressed natural gas (CNG), and propane. Each market indicator was mapped, combined, and evaluated by industry experts. This process revealed the weight the market indicators should be given, with the proximity of fueling stations being the most important indicator, followed by alternative fuel vehicle density, gasoline prices, state incentives, nearby resources, and finally, environmental benefit. Though markets vary among states, no state received 'weak' potential for all five fuels, indicating that all states have an opportunity to use at least one alternative fuel. California, Illinois, Indiana, Pennsylvania, and Washington appear to have the best potential markets for alternative fuels in general, with each sporting strong markets for four of the fuels. Wyoming showed the least potential, with weak markets for all alternative fuels except for CNG, for which it has a patchy market. Of all the fuels, CNG is promising in the greatest number of states--largely because freight traffic provides potential demand for many far-reaching corridor markets and because the sources of CNG are so widespread geographically.

  7. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    Energy Technology Data Exchange (ETDEWEB)

    H.C. Maru; M. Farooque

    2003-03-01

    The program efforts are focused on technology and system optimization for cost reduction, commercial design development, and prototype system field trials. The program is designed to advance the carbonate fuel cell technology from full-size field test to the commercial design. FuelCell Energy, Inc. (FCE) is in the later stage of the multiyear program for development and verification of carbonate fuel cell based power plants supported by DOE/NETL with additional funding from DOD/DARPA and the FuelCell Energy team. FCE has scaled up the technology to full-size and developed DFC{reg_sign} stack and balance-of-plant (BOP) equipment technology to meet product requirements, and acquired high rate manufacturing capabilities to reduce cost. FCE has designed submegawatt (DFC300A) and megawatt (DFC1500 and DFC3000) class fuel cell products for commercialization of its DFC{reg_sign} technology. A significant progress was made during the reporting period. The reforming unit design was optimized using a three-dimensional stack simulation model. Thermal and flow uniformities of the oxidant-In flow in the stack module were improved using computational fluid dynamics based flow simulation model. The manufacturing capacity was increased. The submegawatt stack module overall cost was reduced by {approx}30% on a per kW basis. An integrated deoxidizer-prereformer design was tested successfully at submegawatt scale using fuels simulating digester gas, coal bed methane gas and peak shave (natural) gas.

  8. Industry requirements for introduction of alternative energies with emphasis on hydrogen fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Delabbio, F. [Rio Tinto, Canadian Exploration Ltd., Toronto, ON (Canada); Starbuck, D. [Newmont Mining Corp., Denver, CO (United States); Akerman, A. [CVRD-Inco, Toronto, ON (Canada); Betournay, M.C. [Natural Resources Canada, Ottawa, ON (Canada). CANMET Mining and Mineral Sciences Laboratories

    2007-07-01

    This paper discussed issues related to the use of alternate sources of energy in underground mining applications. Hydrogen power systems were examined in relation to operational drivers, available commercial supplies, site supplies, health and safety issues, capital and operating costs, mine production, and the role of government. Hydrogen power systems are being considered for mining applications in an effort to reduce greenhouse gas (GHG) emissions and reduce cooling and ventilation requirements. This article examined a range of issues that must be addressed before alternate energy systems such as hydrogen fuel cell technology can be used in larger-scale underground mining applications. The mining industry supports the development of new technologies. However, the introduction of alternate energy technologies must proceed in steps which include proof of concept testing, the development of generic infrastructure, power systems and regulations, and whole operating system studies. 13 refs., 1 fig.

  9. Air emission from the co-combustion of alternative derived fuels within cement plants: Gaseous pollutants.

    Science.gov (United States)

    Richards, Glen; Agranovski, Igor E

    2015-02-01

    Cement manufacturing is a resource- and energy-intensive industry, utilizing 9% of global industrial energy use while releasing more than 5% of global carbon dioxide (CO₂) emissions. With an increasing demand of production set to double by 2050, so too will be its carbon footprint. However, Australian cement plants have great potential for energy savings and emission reductions through the substitution of combustion fuels with a proportion of alternative derived fuels (ADFs), namely, fuels derived from wastes. This paper presents the environmental emissions monitoring of 10 cement batching plants while under baseline and ADF operating conditions, and an assessment of parameters influencing combustion. The experiential runs included the varied substitution rates of seven waste streams and the monitoring of seven target pollutants. The co-combustion tests of waste oil, wood chips, wood chips and plastic, waste solvents, and shredded tires were shown to have the minimal influence when compared to baseline runs, or had significantly reduced the unit mass emission factor of pollutants. With an increasing ADF% substitution, monitoring identified there to be no subsequent emission effects and that key process parameters contributing to contaminant suppression include (1) precalciner and kiln fuel firing rate and residence time; (2) preheater and precalciner gas and material temperature; (3) rotary kiln flame temperature; (4) fuel-air ratio and percentage of excess oxygen; and (5) the rate of meal feed and rate of clinker produced.

  10. Production of chemicals and fuels from biomass

    Energy Technology Data Exchange (ETDEWEB)

    Woods, Elizabeth; Qiao, Ming; Myren, Paul; Cortright, Randy D.; Kania, John

    2015-12-15

    Described are methods, reactor systems, and catalysts for converting biomass to fuels and chemicals in a batch and/or continuous process. The process generally involves the conversion of water insoluble components of biomass, such as hemicellulose, cellulose and lignin, to volatile C.sub.2+O.sub.1-2 oxygenates, such as alcohols, ketones, cyclic ethers, esters, carboxylic acids, aldehydes, and mixtures thereof. In certain applications, the volatile C.sub.2+O.sub.1-2 oxygenates can be collected and used as a final chemical product, or used in downstream processes to produce liquid fuels, chemicals and other products.

  11. Biotechnological processes for biodiesel production using alternative oils.

    Science.gov (United States)

    Azócar, Laura; Ciudad, Gustavo; Heipieper, Hermann J; Navia, Rodrigo

    2010-10-01

    As biodiesel (fatty acid methyl ester (FAME)) is mainly produced from edible vegetable oils, crop soils are used for its production, increasing deforestation and producing a fuel more expensive than diesel. The use of waste lipids such as waste frying oils, waste fats, and soapstock has been proposed as low-cost alternative feedstocks. Non-edible oils such as jatropha, pongamia, and rubber seed oil are also economically attractive. In addition, microalgae, bacteria, yeast, and fungi with 20% or higher lipid content are oleaginous microorganisms known as single cell oil and have been proposed as feedstocks for FAME production. Alternative feedstocks are characterized by their elevated acid value due to the high level of free fatty acid (FFA) content, causing undesirable saponification reactions when an alkaline catalyst is used in the transesterification reaction. The production of soap consumes the conventional catalyst, diminishing FAME production yield and simultaneously preventing the effective separation of the produced FAME from the glycerin phase. These problems could be solved using biological catalysts, such as lipases or whole-cell catalysts, avoiding soap production as the FFAs are esterified to FAME. In addition, by-product glycerol can be easily recovered, and the purification of FAME is simplified using biological catalysts.

  12. Biotechnological processes for biodiesel production using alternative oils

    Energy Technology Data Exchange (ETDEWEB)

    Azocar, Laura; Ciudad, Gustavo [La Frontera Univ., Temuco (Chile). Nucleo Cietifico Tecnologico en Biorrecursos; Heipieper, Hermann J. [Helmholtz Centre for Environmental Research-UFZ, Leipzig (Germany). Dept. of Environmental Biotechnology; Navia, Rodrigo [La Frontera Univ., Temuco (Chile). Nucleo Cietifico Tecnologico en Biorrecursos; La Frontera Univ., Temuco (Chile). Dept. de Ingenieria Quimica

    2010-10-15

    As biodiesel (fatty acid methyl ester (FAME)) is mainly produced from edible vegetable oils, crop soils are used for its production, increasing deforestation and producing a fuel more expensive than diesel. The use of waste lipids such as waste frying oils, waste fats, and soapstock has been proposed as low-cost alternative feedstocks. Non-edible oils such as jatropha, pongamia, and rubber seed oil are also economically attractive. In addition, microalgae, bacteria, yeast, and fungi with 20% or higher lipid content are oleaginous microorganisms known as single cell oil and have been proposed as feedstocks for FAME production. Alternative feedstocks are characterized by their elevated acid value due to the high level of free fatty acid (FFA) content, causing undesirable saponification reactions when an alkaline catalyst is used in the transesterification reaction. The production of soap consumes the conventional catalyst, diminishing FAME production yield and simultaneously preventing the effective separation of the produced FAME from the glycerin phase. These problems could be solved using biological catalysts, such as lipases or whole-cell catalysts, avoiding soap production as the FFAs are esterified to FAME. In addition, by-product glycerol can be easily recovered, and the purification of FAME is simplified using biological catalysts. (orig.)

  13. The study on injection parameters of selected alternative fuels used in diesel engines

    Science.gov (United States)

    Balawender, K.; Kuszewski, H.; Lejda, K.; Lew, K.

    2016-09-01

    The paper presents selected results concerning fuel charging and spraying process for selected alternative fuels, including regular diesel fuel, rape oil, FAME, blends of these fuels in various proportions, and blends of rape oil with diesel fuel. Examination of the process included the fuel charge measurements. To this end, a set-up for examination of Common Rail-type injection systems was used constructed on the basis of Bosch EPS-815 test bench, from which the high-pressure pump drive system was adopted. For tests concerning the spraying process, a visualisation chamber with constant volume was utilised. The fuel spray development was registered with the use of VisioScope (AVL).

  14. CO{sub 2} mitigation and fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Steinberg, M.

    1997-07-07

    Methanol as an alternative transportation fuel appears to be an effective intermediate agent, for reducing CO{sub 2} from the utility power and the transportation sectors. On the utilization side, methanol as a liquid fuel fits in well with the current infrastructure for storage and delivery to the automotive sector with better efficiency. On the production side, CO{sub 2} from fossil fuel plants together with natural gas and biomass can be used as feedstocks for methanol synthesis with reduced CO{sub 2}. Over the past several years, processes have emerged which have varying degrees of CO{sub 2} emission reduction depending on the feedstocks used for methanol synthesis process. This paper reviews the methanol processes from the point of view of production efficiency and CO{sub 2} emissions reduction. The processes include: (1) the Hydrocarb Process which primarily utilizes coal and natural gas and stores carbon, and (2) the Hynol Process which utilizes biomass (including carbonaceous wastes, municipal solid waste (MSW)) or coal and natural gas, and (3) the Carnol Process which utilizes natural gas and CO{sub 2} recovered from fossil fuel fired powered plant stacks, especially coal fired plants. The Carnol System consists of power generation, methanol production and methanol utilization as an automotive fuel. The efficiency and CO{sub 2} emissions for the entire system are compared to the conventional system of petroleum derived automotive fuel (gasoline) and coal fired power generation plants. CO{sub 2} reduction by as much as 56% and 77% can be achieved when methanol is used in internal combustion and fuel cell automotive vehicles, respectively.

  15. Experimental Investigation of Turbine Vane Heat Transfer for Alternative Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Nix, Andrew Carl [West Virginia Univ., Morgantown, WV (United States)

    2015-03-23

    modern turbine engines; and What advancements in film cooling hole geometry and design can increase effectiveness of film cooling in turbines burning high-hydrogen coal syngas due to the higher heat loads and mass flow rates of the core flow? Experimental and numerical investigations of advanced cooling geometries that can improve resistance to surface deposition were performed. The answers to these questions were investigated through experimental measurements of turbine blade surface temperature and coolant coverage (via infrared camera images and thermocouples) and time-varying surface roughness in the NETL high-pressure combustion rig with accelerated, simulated surface deposition and advanced cooling hole concepts, coupled with detailed materials analysis and characterization using conventional methods of Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-Ray Diffraction (XRD), 3-D Surface Topography (using a 3-D stylus profilometer). Detailed surface temperatures and cooling effectiveness could not be measured due to issues with the NETL infrared camera system. In collaboration with faculty startup funding from the principal investigator, experimental and numerical investigations were performed of an advanced film cooling hole geometry, the anti-vortex hole (AVH), focusing on improving cooling effectiveness and decreasing the counter-rotating vortex of conventional cooling holes which can entrain mainstream particulate matter to the surface. The potential benefit of this program is in gaining a fundamental understanding of how the use of alternative fuels will effect the operation of modern gas turbine engines, providing valuable data for more effective cooling designs for future turbine systems utilizing alternative fuels.

  16. Catalytic Deoxygenation of Fatty Acids and Triglycerides for Production of Fuels and Chemicals

    NARCIS (Netherlands)

    Hollak, Stefan

    2014-01-01

    Fossil fuels (i.e. coal, gas, oil) currently cover over 80 % of the world’s energy demand. The use of alternative resources for the production of fuels and chemicals has been an important research area over the last decade. This was not only stimulated by the declining fossil feedstock resources and

  17. Carpet As An Alternative Fuel in Cement Kilns

    Energy Technology Data Exchange (ETDEWEB)

    Matthew J Realff

    2007-02-06

    Approximately 5 billion lbs of carpet will be removed from buildings in the US each year for the foreseeable future. This carpet is potentially a valuable resource because it contains plastic in the face of the carpet that can be re-used. However, there are many different types of carpet, and at least four major different plastics used to make the face. The face is woven through a backing fabric and held in place by a “glue” that is in most cases a latex cross-linked polymer which is heavily loaded with chalk (calcium carbonate). This backing has almost no value as a recycled material. In addition, carpet is a bulky material that is difficult to handle and ship and must be kept dry. It would be of significant benefit to the public if this stream of material could be kept out of landfills and some of its potential value unlocked by having high volume alternatives for recycled carpet use. The research question that this project investigated was whether carpet could be used as a fuel in a cement kiln. If this could be done successfully, there is significant capacity in the US cement industry to absorb carpet and use it as a fuel. Cement kilns could serve as a way to stimulate carpet collection and then side streams be taken for higher value uses. The research demonstrated that carpet was technically a suitable fuel, but was unable to conclude that the overall system could be economically feasible at this time with the constraints placed on the project by using an existing system for feeding the kiln. Collection and transportation were relatively straightforward, using an existing collector who had the capacity to collect high volumes of material. The shredding of the carpet into a suitable form for feeding was more challenging, but these problems were successfully overcome. The feeding of the carpet into the kiln was not successfully carried out reliably. The overall economics were not positive under the prevailing conditions of costs for transportation and size

  18. Alternative fuel vehicles for the Federal fleet: Results of the 5-year planning process. Executive Order 12759, Section 11

    Energy Technology Data Exchange (ETDEWEB)

    1992-08-01

    This report describes five-year plans for acquisition of alternative fuel vehicles (AFVs) by the Federal agencies. These plans will be used to encourage Original Equipment Manufacturers (OEMs) to expand the variety of AFVs produced, reduce the incremental cost of AFVs, and to encourage fuel suppliers to expand the alternative fuel infrastructure and alternative fuel availability. This effort supplements and extends the demonstration and testing of AFVs established by the Department of Energy under the alternative Motor Fuels Act of 1988.

  19. THE FUTURE OF MOTOR TRANSPORT – ALTERNATIVE FUEL AND CANCEROGENIC SAFETY

    Directory of Open Access Journals (Sweden)

    Kanilo, P.

    2012-06-01

    Full Text Available Prospects of application of synthetic hydrocarbonic motor fuels and hydrogen as the basic and additional energy carriers are analysed. It is shown that the use of alternative fuels does not only effectively replaces oil fuel, but also provides essential decrease of environmental contamination by supertoxic substancses, namely cancerogenic and mutagen.

  20. 49 CFR 525.11 - Termination of exemption; amendment of alternative average fuel economy standard.

    Science.gov (United States)

    2010-10-01

    ... average fuel economy standard. 525.11 Section 525.11 Transportation Other Regulations Relating to... EXEMPTIONS FROM AVERAGE FUEL ECONOMY STANDARDS § 525.11 Termination of exemption; amendment of alternative average fuel economy standard. (a) Any exemption granted under this part for an affected model year...

  1. 10 CFR 490.504 - Use of alternative fueled vehicle credits.

    Science.gov (United States)

    2010-01-01

    ... 490.504 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ALTERNATIVE FUEL TRANSPORTATION PROGRAM... of a fleet or covered person in an annual report under this part, DOE shall treat each credit as the acquisition of an alternative fueled vehicle that the fleet or covered person is required to acquire...

  2. 10 CFR 490.201 - Alternative fueled vehicle acquisition mandate schedule.

    Science.gov (United States)

    2010-01-01

    .... 490.201 Section 490.201 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ALTERNATIVE FUEL TRANSPORTATION PROGRAM Mandatory State Fleet Program § 490.201 Alternative fueled vehicle acquisition mandate... annually for State government fleets, including agencies thereof but excluding municipal fleets,...

  3. Pilot Field Demonstration of Alternative Fuels in Force Projection Petroleum and Water Distribution Equipment

    Science.gov (United States)

    2014-09-04

    UNCLASSIFIED UNCLASSIFIED PILOT FIELD DEMONSTRATION OF ALTERNATIVE FUELS IN FORCE PROJECTION PETROLEUM AND WATER DISTRIBUTION EQUIPMENT...Fort Belvoir, Virginia 22060- 6218. Disposition Instructions Destroy this report when no longer needed. Do not return it to the originator ...UNCLASSIFIED UNCLASSIFIED PILOT FIELD DEMONSTRATION OF ALTERNATIVE FUELS IN FORCE PROJECTION PETROLEUM AND WATER DISTRIBUTION EQUIPMENT

  4. Technology assessment of alternative fuels for the transportation sector; Teknologivurdering af altgernative drivmidler til transportsektoren

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-05-15

    The report documents an analysis, which aims at evaluating technologies in connection with alternative fuels for the transportation sector. During the analysis process a method has been developed for consistent evaluation of the alternative transportation fuels with the largest technological and economic potential. (BA)

  5. Spent nuclear fuel project product specification

    Energy Technology Data Exchange (ETDEWEB)

    PAJUNEN, A.L.

    1999-02-25

    This document establishes the limits and controls for the significant parameters that could potentially affect the safety and/or quality of the Spent Nuclear Fuel (SNF) packaged for processing, transport, and storage. The product specifications in this document cover the SNF packaged in Multi-Canister Overpacks to be transported throughout the SNF Project.

  6. Spent Nuclear Fuel (SNF) Project Product Specification

    Energy Technology Data Exchange (ETDEWEB)

    PAJUNEN, A.L.

    2000-01-20

    This document establishes the limits and controls for the significant parameters that could potentially affect the safety and/or quality of the Spent Nuclear Fuel (SNF) packaged for processing, transport, and storage. The product specifications in this document cover the SNF packaged in Multi-Canister Overpacks to be transported throughout the SNF Project.

  7. Sinopec Commits to Cleaner Production and Fuels

    Institute of Scientific and Technical Information of China (English)

    Li Xiaocheng

    2012-01-01

    China Petrochemical Corporation, or Sinopec, has issued a report on its efforts at environmental protection - a first for a Chinese company. The report cites strategies of China's biggest oil refiner by capacity to reduce environmental impact, as well as implementation of lower-carbon fuels and less-polluting production methods.

  8. Direct fuel cell product design improvement

    Energy Technology Data Exchange (ETDEWEB)

    Maru, H.C.; Farooque, M. [Energy Research Corp., Danbury, CT (United States)

    1996-12-31

    Significant milestones have been attained towards the technology development field testing and commercialization of direct fuel cell power plant since the 1994 Fuel Cell Seminar. Under a 5-year cooperative agreement with the Department of Energy signed in December 1994, Energy Research Corporation (ERC) has been developing the design for a MW-scale direct fuel cell power plant with input from previous technology efforts and the Santa Clara Demonstration Project. The effort encompasses product definition in consultation with the Fuel Cell Commercialization Group, potential customers, as well as extensive system design and packaging. Manufacturing process improvements, test facility construction, cell component scale up, performance and endurance improvements, stack engineering, and critical balance-of-plant development are also addressed. Major emphasis of this product design improvement project is on increased efficiency, compactness and cost reduction to establish a competitive place in the market. A 2.85 MW power plant with an efficiency of 58% and a footprint of 420 m{sup 2} has been designed. Component and subsystem testing is being conducted at various levels. Planning and preparation for verification of a full size prototype unit are in progress. This paper presents the results obtained since the last fuel cell seminar.

  9. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    Energy Technology Data Exchange (ETDEWEB)

    H.C. Maru; M. Farooque

    2005-03-01

    The program was designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE, formerly Energy Research Corporation) from an early state of development for stationary power plant applications. The current program efforts were focused on technology and system development, and cost reduction, leading to commercial design development and prototype system field trials. FCE, in Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations, or at distributed locations near the customers such as hospitals, schools, universities, hotels and other commercial and industrial applications. FCE has designed three different fuel cell power plant models (DFC300A, DFC1500 and DFC3000). FCE's power plants are based on its patented DFC{reg_sign} technology, where a hydrocarbon fuel is directly fed to the fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to the existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating and air conditioning. Several sub-MW power plants based on the DFC design are currently operating in Europe, Japan and the US. Several one-megawatt power plant design was verified by operation on natural gas at FCE. This plant is currently installed at a customer site in King County, WA under another US government program and is currently in operation. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and

  10. Mixed Culture PHA Production With Alternating Feedstocks

    DEFF Research Database (Denmark)

    Oliveira, C.S.S.; Duque, A.F.; Carvalho, Gilda

    Polyhydroxyalkanoates (PHA) are a sustainable alternative to conventional plastics that can be obtained from industrial wastes/by-products using mixed microbial cultures (MMC). MMC PHA production is commonly carried out in a 3-stage process consisting of an acidogenic stage, a PHA producing culture...... selection stage, and a PHA production phase. This work investigated the performance robustness and microbial population dynamics of a PHA producing MMC when subjected to a feedstock shift, mimicking a seasonal feedstock scenario, from cheese whey to sugar cane molasses. Research was focused...... on the possibility of tailoring PHA through the selection of feedstock: either using feedstocks with different compositions or mixing two or more fermented substrates with different organic acid profiles. This knowledge is expected to contribute to the extended application of this promising process for resource...

  11. Financial products as alternatives to traditional deposits

    Directory of Open Access Journals (Sweden)

    Cristina Lidia MANEA

    2016-05-01

    In this context, increasing the safety of depositors appears as an undisputed necessity, which translates to our approach in the development of a constructive type applied research that takes into account the following stages: short description of risks and uncertainties characterizing the economic environment with emphasis on the importance of the financial instruments; analysis of empirical data on deposits in lei and euro at national level, identifying possible causes which led to one preference or another and finding the causes underlying the different options manifested in the capital, as compared to other counties; identifying the products that offer a dangerous alternative to traditional deposits from the Romanian banking market and describing these products and their related risks; the proposal of a new product, demonstrating its effectiveness by testing and confirmation of two hypotheses.

  12. Fission-product retention in HTGR fuels

    Energy Technology Data Exchange (ETDEWEB)

    Homan, F.J.; Kania, M.J.; Tiegs, T.N.

    1982-01-01

    Retention data for gaseous and metallic fission products are presented for both Triso-coated and Biso-coated HTGR fuel particles. Performance trends are established that relate fission product retention to operating parameters, such as temperature, burnup, and neutron exposure. It is concluded that Biso-coated particles are not adequately retentive of fission gas or metallic cesium, and Triso-coated particles which retain cesium still lose silver. Design implications related to these performance trends are identified and discussed.

  13. Charcoal-Oil Mixture as an Alternative Fuel: A Preliminary Study

    Directory of Open Access Journals (Sweden)

    Roila Awang

    2009-01-01

    Full Text Available The fast depletion of fuel oil and continuous increase in the demand for power is a global issue. The world energy consumption is projected to grow at an average of 2.7-3.7% from 1996 to 2010. Therefore search for alternative fuel is highly prioritized. Thus this study presents the results on the characteristic of charcoal-oil mixture as an alternative fuel. The calorific value, ash content and stability of the mixture are determined.

  14. Green Engines Development Using Compressed Natural Gas as an Alternative Fuel: A Review

    Directory of Open Access Journals (Sweden)

    Semin

    2009-01-01

    Full Text Available Problem statement: The Compressed Natural Gas (CNG is a gaseous form of natural gas, it have been recognized as one of the promising alternative fuel due to its substantial benefits compared to gasoline and diesel. Natural gas is produced from gas wells or tied in with crude oil production. Approach: Natural gas is promising alternative fuel to meet strict engine emission regulations in many countries. Compressed Natural Gas (CNG has long been used in stationary engines, but the application of CNG as a transport engines fuel has been considerably advanced over the last decade by the development of lightweight high-pressure storage cylinders. Results: The technology of engine conversion was well established and suitable conversion equipment is readily available. For petrol engines or spark ignition engines there are two options, a bi-fuel conversion and use a dedicated to CNG engine. The diesel engines converted or designed to run on natural gas, there were two main options discussed. There are dual-fuel engines and normal ignition can be initiated. Natural gas engines can be operated at lean burn and stoichiometric conditions with different combustion and emission characteristics. Conclusions: In this study, the low exhaust gas emissions of CNG engines research and development were highlighted. Stoichiometric natural gas engines were briefly reviewed. To keep the output power, torque and emissions of natural gas engines comparable to their gasoline or diesel counterparts. High activity for future green CNG engines research and development to meet future stringent emissions standards was recorded in the study.

  15. Crop production without fossil fuel: production systems for tractor fuel and mineral nitrogen based on biomass

    Energy Technology Data Exchange (ETDEWEB)

    Ahlgren, Serina

    2009-12-15

    With diminishing fossil fuel reserves and concerns about global warming, the agricultural sector needs to reduce its use of fossil fuels. The objective of this thesis was to evaluate different systems for biomass-based production of tractor fuel and mineral nitrogen fertilisers, which at present are the two largest fossil energy carriers in Swedish agriculture. The land use, energy input and environmental load of the systems were calculated using life cycle assessment methodology. Two categories of renewable tractor fuel were studied: first generation fuels and second generation fuels, the latter defined as fuels not yet produced on a commercial scale. An organic farm self-sufficient in tractor fuel was modelled. Raw material from the farm was assumed to be delivered to a large fuel production facility and fuel transported back to the farm, where it was utilised. In general, the second generation renewable fuels had higher energy balance and lower environmental impact than the first generation fuels. However all systems studied reduced the use of fossil fuels to a great extent and lowered the contribution to global warming. The land needed to be set aside for tractor fuel varied between 2% and 5% of the farm's available land. Two major routes for biomass-based production of mineral nitrogen for conventional agriculture were studied, one based on anaerobic digestion and one on thermochemical gasification of biomass. The crops studied were able to produce between 1.6 and 3.9 tonnes N per hectare in the form of ammonium nitrate. The use of fossil fuel for ammonium nitrate production was 35 MJ per kg N in the fossil reference scenario, but only 1-4 MJ per kg N in the biomass systems. The contribution to global warming can be greatly reduced by the biomass systems, but there is an increased risk of eutrophication and acidification. It is clear that the agricultural sector has great potential to reduce the use of fossil fuel and to lower the emissions of greenhouse

  16. Certification Report: Army Aviation Alternative Fuels Certification Program

    Science.gov (United States)

    2016-08-01

    fuel purchase for this program was through a qualified Defense Logistics Agency – Energy (DLA-E) vendor utilizing funding provided to the Research...Performance Related Fuel Properties Characteristics) • Hot Surface Ignition Under Turbulent Airflow • Thermal Expansion • Ignition Energy ... Fuel Acquisition The Defense Logistics Agency – Energy (DLA-E) provided a key role in the acquisition of the ATJ fuel required to complete the

  17. DOD Alternative Fuels: Policy, Initiatives and Legislative Activity

    Science.gov (United States)

    2012-12-14

    hydrotreated jet and diesel biofuels,15 alcohol-to-jet fuels, and direct-sugar-to-hydrocarbons fuels).16 All services have purchased various types of... hydrotreated jet and diesel biofuels. The Air Force has also purchased alcohol-to-jet fuels derived from both petroleum and biomass feedstocks. The...liquid fuels from coal, natural gas, or biomass feedstocks. 15 Hydrotreated jet and diesel biofuels are the more common terms for HEFA (Hydroprocessed

  18. Biodiesel production by biocatalysis using alternative method for lipase immobilization in hydrogel

    OpenAIRE

    Fernanda Marder; Mariéli Milanesi Ceolin; Mariele da Silva Mazuim; Rosana de Cassia de Souza Schneider; Marilda Teixeira Macagnan; Valeriano Antonio Corbellini

    2009-01-01

    The society has been looking for alternatives in order to stop the process of environmental destruction installed in the world, however, starting from last century, a new vision on the indiscriminate use of the environmental resources started to be discussed leading to the use of new technologies of production of cleaner fuel, as the biodiesel, produced from vegetable oils. The enzymatic processes are a production alternative, for they are methods with losses reduction and larger efficiency, ...

  19. Biodiesel From Alternative Oilseed Feedstocks: Production and Properties

    Science.gov (United States)

    Fatty acid methyl esters were prepared and evaluated as potential biodiesel fuels from several alternative oilseed feedstocks, which included camelina (Camelina sativa L.), coriander (Coriandrum sativum L.), field mustard (Brassica juncea L.), field pennycress (Thlaspi arvense L.), and meadowfoam (L...

  20. Impacts of fuel quality on power production

    DEFF Research Database (Denmark)

    Harding, S.; Wall, T.; Wigley, F.;

    2007-01-01

    The first ash deposition or slagging and fouling conference, as they are commonly called, was held at the Marchwood Engineering Laboratories in the UK in 1963. Since that time many excellent conferences have occurred to provide interchange, dialogue, experiences and results among those who deal...... with the many opportunities afforded by fuel quality. However, due to the changing sponsorship environment, it has been several years since the last conference which focused on fuel characteristics and their paramount importance in power production. This conference, the 17th in the series, was entitled “Impacts...... of Fuel Quality on Power Production” and was held in Snowbird, UT, from October 29 to November 3, 2006. More than 50 participants from 13 countries throughout the world participated....

  1. [Research and workshop on alternative fuels for aviation. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-09-01

    stand is an asset which provides an ongoing research capability dedicated to the testing of alternative fuels for aircraft engines. The test stand is now entirely functional with the exception of the electronic ignition unit which still needs adjustments.

  2. Alternative Fuel News: Official Publication of the U.S. Department of Energy's Clean Cities Network and the Alternative Fuels Data Center; Vol. 2, No. 2

    Energy Technology Data Exchange (ETDEWEB)

    1998-05-01

    Official publication of the Clean Cities Network and the Alternative Fuels Data Center featuring alternative fuels activity in every state, the Clean Cities game plan '98, and news from the Automakers.

  3. Utilisation of Used Palm Oil as an Alternative Fuel in Thailand

    Science.gov (United States)

    Permchart, W.; Tanatvanit, S.

    2007-10-01

    This paper summarises the overview of the current situation of alternative energies in Thailand. The utilisation of bio-diesel as an alternative energy in two economic sectors (i.e. transport and industrial sectors), which have the largest energy consumption in the country, is mainly presented because it has seemed to be the most promising project among various energy conservation projects of the Thai government. Actually, there is another bio-fuel project, namely, the ethanol project for blending with gasoline to produce gasohol (E10) used in gasoline engines, which has been developed and already become to an important policy for energy conservation of the country. Due to much more large number of diesel has been utilised, the bio-diesel project has been the first priority one to solve the petroleum crisis problems. However, it is remarked that the utilisation of bio-diesel as an alternative fuel seems to be unsatisfactory because of various reasons. Some issues in terms of both government policies and technical problems have not been clearly addressed. Therefore, this paper not only presents the utilisation of bio-diesel in these two sectors but also discusses the production processes, characterisations and some experimental testing results of bio-diesel.

  4. Characterization of Catalyst Materials for Production of Aerospace Fuels

    Science.gov (United States)

    Best, Lauren M.; De La Ree, Ana B.; Hepp, Aloysius F.

    2012-01-01

    Due to environmental, economic, and security issues, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to non-petroleum sources as a feedstock for aviation (and other transportation) fuels. Additionally, efforts are concentrated on reducing costs coupled with fuel production from non-conventional sources. One solution to this issue is Fischer-Tropsch gas-to-liquid technology. Fischer-Tropsch processing of synthesis gas (CO/H2) produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fisher-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur or aromatic compounds. This process is most commonly catalyzed by heterogeneous (in this case, silver and platinum) catalysts composed of cobalt supported on alumina or unsupported alloyed iron powders. Physisorption, chemisorptions, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) are described to better understand the potential performance of Fischer-Tropsch cobalt on alumina catalysts promoted with silver and platinum. The overall goal is to preferentially produce C8 to C18 paraffin compounds for use as aerospace fuels. Progress towards this goal will eventually be updated and achieved by a more thorough understanding of the characterization of catalyst materials. This work was supported by NASA s Subsonic Fixed Wing and In-situ Resource Utilization projects.

  5. Using SPL (Spent Pot-Lining) as an Alternative Fuel in Metallurgical Furnaces

    Science.gov (United States)

    Gao, Lei; Mostaghel, Sina; Ray, Shamik; Chattopadyay, Kinnor

    2016-09-01

    Replacing coke (coal) in a metallurgical furnace with other alternative fuels is beneficial for process economics and environmental friendliness. Coal injection is a common practice in blast furnace ironmaking, and spent pot-lining (SPL) was conceptualized as an alternative to coal. SPL is a resourceful waste from primary Aluminum production, with high carbon value. Equilibrium thermodynamics was used to calculate the energy content of SPL, and the compositional changes during SPL combustion. In order to capture the kinetics and mass transfer aspects, a blast furnace tuyere region CFD model was developed. The results of SPL combustion were compared with standard PCI coals, which are commonly used in blast furnaces. The CFD model was validated with experimental results for standard high volatile coals.

  6. Technical and economic feasibility of alternative fuel use in process heaters and small boilers

    Energy Technology Data Exchange (ETDEWEB)

    1980-02-01

    The technical and economic feasibility of using alternate fuels - fuels other than oil and natural gas - in combustors not regulated by the Powerplant and Industrial Fuel Use Act of 1978 (FUA) was evaluated. FUA requires coal or alternate fuel use in most large new boilers and in some existing boilers. Section 747 of FUA authorizes a study of the potential for reduced oil and gas use in combustors not subject to the act: small industrial boilers with capacities less than 100 MMBtu/hr, and process heat applications. Alternative fuel use in combustors not regulated by FUA was examined and the impact of several measures to encourage the substitution of alternative fuels in these combustors was analyzed. The primary processes in which significant fuel savings can be achieved are identified. Since feedstock uses of oil and natural gas are considered raw materials, not fuels, feedstock applications are not examined in this analysis. The combustors evaluated in this study comprise approximately 45% of the fuel demand projected in 1990. These uses would account for more than 3.5 million barrels per day equivalent fuel demand in 1990.

  7. Alternative Fuels: Are we Making the Right Choices?

    Science.gov (United States)

    2008-05-01

    diesel at any ratio with little to no modification. (U.S. Environmental Protection Agency, 2002) Homogeneous charge compression ignition ( HCCI ) engines ...have the potential to provide high, diesel-like efficiencies and very low emissions. In an HCCI engine , a dilute, premixed fuel/air charge auto...replacements for fossil fuels in the internal combustion engine . Liquefied petroleum gas (LPG), better known as propane, is a clean-burning fossil fuel

  8. Preliminary analysis of alternative fuel cycles for proliferation evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Steindler, M. J.; Ripfel, H. C.F.; Rainey, R. H.

    1977-01-01

    The ERDA Division of Nuclear Research and Applications proposed 67 nuclear fuel cycles for assessment as to their nonproliferation potential. The object of the assessment was to determine which fuel cycles pose inherently low risk for nuclear weapon proliferation while retaining the major benefits of nuclear energy. This report is a preliminary analysis of these fuel cycles to develop the fuel-recycle data that will complement reactor data, environmental data, and political considerations, which must be included in the overall evaluation. This report presents the preliminary evaluations from ANL, HEDL, ORNL, and SRL and is the basis for a continuing in-depth study. (DLC)

  9. Alternative Fuels Compatibility with Army Equipment Testing - Existent Gum

    Science.gov (United States)

    2012-02-01

    isooctane /toluene blend was proposed as a surrogate to mimic the expected low aromatic content of the 50/50 synthetic/petroleum blends. Table 3...Jet A Solvent Blends (Fuel Surrogates) CL12-3310 Fuel B 70/30 isooctane / toluene CL12-3311 Fuel D 60/40 isooctane / toluene CL12-3312 Fuel XX...90/10 isooctane / toluene proposed surrogate to mimic low aromatic content blends *JP-8 blends: ~1 mg/L Stadis 450, 15 mg/L DCI-4A, 0.15 vol

  10. Alternative Fuel and Advanced Technology Commercial Lawn Equipment (Spanish version); Clean Cities, Energy Efficiency & Renewable Energy (EERE)

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, Erik

    2015-06-01

    Powering commercial lawn equipment with alternative fuels or advanced engine technology is an effective way to reduce U.S. dependence on petroleum, reduce harmful emissions, and lessen the environmental impacts of commercial lawn mowing. Numerous alternative fuel and fuel-efficient advanced technology mowers are available. Owners turn to these mowers because they may save on fuel and maintenance costs, extend mower life, reduce fuel spillage and fuel theft, and demonstrate their commitment to sustainability.

  11. Alternative fuels in cement industry; Alternativa braenslen i cementindustrin

    Energy Technology Data Exchange (ETDEWEB)

    Nyman, K.E.; Ek, R. [Finnsementti Oy, Parainen (Finland); Maekelae, K. [Finreci Oy (Finland)

    1997-10-01

    In this project the cement industry`s possibilities to replace half of the fossil fuels with waste derived fuels are investigated. Bench-scale experiments, pilot plant tests and full scale tests have been done with used tires and plastics wastes

  12. Genetic Algorithm Based Production Planning for Alternative Process Production

    Institute of Scientific and Technical Information of China (English)

    ZHANG Fa-ping; SUN Hou-fang; SHAHID I. Butt

    2009-01-01

    Production planning under flexible job shop environment is studied. A mathematic model is formulated to help improve alternative process production. This model, in which genetic algorithm is used, is expected to result in better production planning, hence towards the aim of minimizing production cost under the constraints of delivery time and other scheduling conditions. By means of this algorithm, all planning schemes which could meet all requirements of the constraints within the whole solution space are exhaustively searched so as to find the optimal one. Also, a case study is given in the end to support and validate this model. Our results show that genetic algorithm is capable of locating feasible process routes to reduce production cost for certain tasks.

  13. Clean Hydrogen Production. Carbon Dioxide Free Alternatives. Project Phisico2

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Fierro, J. L.; Gonzalez, C.; Serrano, D.; Penelas, G.; Romero, M.; Marcos, M. J.; Rodriguez, C.

    2006-07-01

    The main goal of the PHISICO2 project, funded and promoted by Comunidad de Madrid, is the evaluation and optimisation of three different processes for the clean hydrogen production without carbon dioxide emission. Solar energy and associated Technologies are proposed to be jointly employed with the aim of improving the process efficiency and reducing the production costs. As a transition to the non-fossil fuel hydrogen economy, the thermocatalytic CO2-free production of hydrogen from natural gas will be considered. One of the most promising alternatives of this process is to develop a cheap and stable carbon-based catalyst able to efficiently decompose methane into a CO2-free hydrogen stream and solid carbon. Thus, not only pure hydrogen can be obtained through but also carbon with specific properties and commercial value can be produced. Another option to be explored is the splitting of water by means of solar light by means of two different approaches: (i) photodissociation promoted by semiconductor catalysts and (ii) thermochemical cycles in which a specific mixed oxide is first thermally reduced by sunlight and then reoxidized by steam in a second step with the parallel production of hydrogen. Indeed, option (i) implies necessarily the development of semiconductors with appropriate band-gap able to decompose water into hydrogen and oxygen in an efficient manner. Another critical issue will be the development of a strategy/concept that allows efficient separation of hydrogen and oxygen within the cell. In option (ii), the development of stable ferrites which act as the redox element of the cycle is also an important challenge. Finally, a 5 kW prototype solar engine water splitting, based on the mentioned thermochemical cycle, will developed and tested using concentrated solar light as an energy source. Moreover, thermodynamic and kinetic studies, reactor design, process optimisation, economical studies and comparison with conventional hydrogen production systems

  14. Addressing the Need for Alternative Transportation Fuels: The Joint BioEnergy Institute

    Energy Technology Data Exchange (ETDEWEB)

    Blanch, Harvey; Adams, Paul; Andrews-Cramer, Katherine; Frommer, Wolf; Simmons, Blake; Keasling, Jay

    2008-01-18

    Today, carbon-rich fossil fuels, primarily oil, coal, and natural gas, provide 85% of the energy consumed in the U.S. As world demand increases, oil reserves may become rapidly depleted. Fossil fuel use increases CO{sub 2} emissions and raises the risk of global warming. The high energy content of liquid hydrocarbon fuels makes them the preferred energy source for all modes of transportation. In the U.S. alone, transportation consumes >13.8 million barrels of oil per day and generates 0.5 gigatons of carbon per year. This release of greenhouse gases has spurred research into alternative, nonfossil energy sources. Among the options (nuclear, concentrated solar thermal, geothermal, hydroelectric, wind, solar, and biomass), only biomass has the potential to provide a high-energy-content transportation fuel. Biomass is a renewable resource that can be converted into carbon-neutral transporation fuels. Currently, biofuels such as ethanol are produced largely from grains, but there is a large, untapped resource (estimated at more than a billion tons per year) of plant biomass that could be utilized as a renewable, domestic source of liquid fuels. Well-established processes convert the starch content of the grain into sugars that can be fermented to ethanol. The energy efficiency of starch-based biofuels is however not optimal, while plant cell walls (lignocellulose) represent a huge untapped source of energy. Plant-derived biomass contains cellulose, which is more difficult to convert to sugars; hemicellulose, which contains a diversity of carbohydrates that have to be efficiently degraded by microorganisms to fuels; and lignin, which is recalcitrant to degradation and prevents cost-effective fermentation. The development of cost-effective and energy-efficient processes to transform lignocellulosic biomass into fuels is hampered by significant roadblocks, including the lack of specifically developed energy crops, the difficulty in separating biomass components, low

  15. MICROALGAE AS AN ALTERNATIVE TO BIOFUELS PRODUCTION. PART 1: BIOETHANOL

    Directory of Open Access Journals (Sweden)

    Maiara Priscilla de Souza

    2013-02-01

    Full Text Available The demand from the energy sector is one of the culminating factors to do researches that enable innovations in the biotechnology sector and to boost biofuel production. The variability of the existing feedstocks provides benefits to energy production, however, we must choose the ones that present plausible characteristics depending on the type of product that we want to obtained. In this context, it is noted that the microalgae have suitable characteristics to producing different types of fuels, depending on the type of treatment are subjected, the species being analyzed as well as the biochemical composition of the biomass. Bioethanol production from microalgae is a promising and growing energy alternative under a view that biomass of these microorganisms has an enormous biodiversity and contain high levels of carbohydrates, an indispensable factor for the bioconversion of microalgae in ethanol. Due to these factors, there is a constant search for more viable methods for pretreatment of biomass, hydrolysis and fermentation, having as one of the major aspects the approach of effectives methodologies in the ambit of quality and yield of ethanol. Therefore, we have to search to increase the interest in the developing of biofuels reconciling with the importance of using microalgae, analyzing whether these micro-organisms are capable of being used in bioethanol production.

  16. SO2 Release as a Consequence of Alternative Fuel Combustion in Cement Rotary Kiln Inlets

    DEFF Research Database (Denmark)

    Cortada Mut, Maria del Mar; Nørskov, Linda Kaare; Glarborg, Peter;

    2015-01-01

    The combustion of alternative fuels in direct contact with the bed material of the rotary kiln may cause local reducing conditions and, subsequently, decomposition of sulfates from cement raw materials, increasing the SO2 concentration in the gas phase. The decomposition of sulfates increases......-temperature rotary drum, focusing on the influence of the fuel particle size and volatile content. The SO2 release increased with a decreasing fuel particle size and with an increasing fuel volatile content. Furthermore, CO, H2, and CH4, which are the main reducing gases released during fuel devolatilization, were...

  17. Fuel Pellets Production from Biodiesel Waste

    Directory of Open Access Journals (Sweden)

    Kawalin Chaiyaomporn

    2010-01-01

    Full Text Available This research palm fiber and palm shell were used as raw materials to produce pelletised fuel, and waste glycerol were used as adhesive to reduce biodiesel production waste. The aim of this research is to find optimum ratio of raw material (ratio of palm fiber and palm shell, raw material size distribution, adhesive temperature, and ratio of ingredients (ratio of raw material, waste glycerol, and water. The optimum ratio of pelletized fuel made only by palm fiber was 50:10:40; palm fiber, water, and waste glycerol respectively. In the best practice condition; particle size was smaller than 2 mm, adhesive glycerol was heated. From the explained optimum ratio and ingredient, pelletizing ratio was 62.6%, specific density was 982.2 kg/m3, heating value was 22.5 MJ/kg, moisture content was 5.9194%, volatile matter was 88.2573%, fix carbon content was 1.5894%, and ash content was 4.2339% which was higher than the standard. Mixing palm shell into palm fiber raw material reduced ash content of the pellets. The optimum raw material ratio, which minimizes ash content, was 80 to 20 palm fiber and palm shell respectively. Adding palm shell reduced ash content to be 2.5247% which was higher than pelletized fuel standard but followed cubed fuel standard. At this raw material ratio, pelletizing ratio was 70.5%, specific density was 774.8 kg/m3, heating value was 19.71 MJ/kg, moisture content was 9.8137%, volatile matter was 86.2259%, fix carbon content was 1.4356%, and compressive force was 4.83 N. Pelletized fuel cost at optimum condition was 1.14 baht/kg.

  18. Refueling Infrastructure for Alternative Fuel Vehicles: Lessons Learned for Hydrogen; Workshop Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Melaina, M. W.; McQueen, S.; Brinch, J.

    2008-07-01

    DOE sponsored the Refueling Infrastructure for Alternative Fuel Vehicles: Lessons Learned for Hydrogen workshop to understand how lessons from past experiences can inform future efforts to commercialize hydrogen vehicles. This report contains the proceedings from the workshop.

  19. Atmospheric Photochemistry Studies of Pollutant Emissions from Transportation Vehicles Operating on Alternative Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Jeffries, H.; Sexton, K.; Yu, J.

    1998-07-01

    This project was undertaken with the goal of improving our ability to predict the changes in urban ozone resulting from the widespread use of alternative fuels in automobiles. This report presents the results in detail.

  20. Traversing the mountaintop: world fossil fuel production to 2050.

    Science.gov (United States)

    Nehring, Richard

    2009-10-27

    During the past century, fossil fuels--petroleum liquids, natural gas and coal--were the dominant source of world energy production. From 1950 to 2005, fossil fuels provided 85-93% of all energy production. All fossil fuels grew substantially during this period, their combined growth exceeding the increase in world population. This growth, however, was irregular, providing for rapidly growing per capita production from 1950 to 1980, stable per capita production from 1980 to 2000 and rising per capita production again after 2000. During the past half century, growth in fossil fuel production was essentially limited by energy demand. During the next half century, fossil fuel production will be limited primarily by the amount and characteristics of remaining fossil fuel resources. Three possible scenarios--low, medium and high--are developed for the production of each of the fossil fuels to 2050. These scenarios differ primarily by the amount of ultimate resources estimated for each fossil fuel. Total fossil fuel production will continue to grow, but only slowly for the next 15-30 years. The subsequent peak plateau will last for 10-15 years. These production peaks are robust; none of the fossil fuels, even with highly optimistic resource estimates, is projected to keep growing beyond 2050. World fossil fuel production per capita will thus begin an irreversible decline between 2020 and 2030.

  1. KHD combustion chamber. Flexible use of alternative fuels in the cement plant; KHD Brennkammer. Flexibler Einsatz von alternativen Brennstoffen im Zementwerk

    Energy Technology Data Exchange (ETDEWEB)

    Schuermann, Heiko [Humboldt Wedag GmbH, Koeln (Germany)

    2012-07-01

    In many parts of the world, the use of alternative fuels is a recognized measure for reducing the CO{sub 2} emissions that result from burning primary fuels such as coal, oil and natural gas. Alternative or secondary fuels are the terms used for combustible residues from industrial and commercial manufacturing processes, agricultural production, and sorted municipal refuse. Due to the wide range of possible sources of alternative fuels, there is very great variation in their energy content, ash, moisture content, particle size, form, density etc., so there is no patent solution for their use in a cement plant. For proper operation of the rotary kiln, it is particularly important to use alternative fuel qualities that have good heat value and reactivity in order to achieve a stable, hot sintering zone and to completely burnout the highest possible amount of the fuel while it is suspended in the air stream. Combustion in the calciner places fewer demands on the properties of the alternative fuels than combustion in the rotary kiln burner does. This means that the calciner is the ideal combustion point for the usage of alternative fuels. To enable maximum possible flexibility for the combustion of widely differing alternative fuels in the calciner, KHD Humboldt Wedag offers the option of installing a combustion chamber in the modular PYROCLON calciner system. Due to the operating characteristics of this combustion chamber, which are described in the following sections of this article, even alternative fuels with low heat values and a low degree of preparation can be safely and completely burnt. (orig.)

  2. Spent fuel management - two alternatives at the FiR 1 reactor

    Energy Technology Data Exchange (ETDEWEB)

    Salmenhaara, S.E.J. [Technical Research Centre of Finland (VTT), FIN-02044 VTT Espoo (Finland)

    2001-07-01

    The FiR 1 -reactor, a 250 kW Triga reactor, has been in operation since 1962. The reactor with its subsystems has experienced a large renovation work in 1996-97. The main purpose of the upgrading was to install the new Boron Neutron Capture Therapy (BNCT) irradiation facility. The BNCT work dominates the current utilization of the reactor: four days per week for BNCT purposes and only one day per week for neutron activation analysis and isotope production. The Council of State (government) granted for the reactor a new operating license for twelve years starting from the beginning of the year 2000. There is however a special condition in the new license. We have to achieve a binding agreement between our Research Centre and the domestic Nuclear Power Plant Companies about the possibility to use the final disposal facility of the Nuclear Power Plants for our spent fuel, if we want to continue the reactor operation beyond the year 2006. In addition to the choosing of one of the spent fuel management alternatives the future of the reactor will also depend strongly on the development of the BNCT irradiations. If the number of patients per year increases fast enough and the irradiations of the patients will be economically justified, the operation of the reactor will continue independently of the closing of the USDOE alternative in 2006. Otherwise, if the number of patients will be low, the funding of the reactor will be probably stopped and the reactor will be shut down. (author)

  3. State of the Art on Alternative Fuels in Aviation. Executive summary

    NARCIS (Netherlands)

    Blakey, S.; Novelli, P.; Costes, P.; Bringtown, S.; Christensen, D.; Sakintuna, B.; Peineke, C.; Jongschaap, R.E.E.; Conijn, J.G.; Rutgers, B.; Valot, L.; Joubert, E.; Perelgritz, J.F.; Filogonio, A.; Roetger, T.; Prieur, A.; Starck, L.; Jeuland, N.; Bogers, P.; Midgley, R.; Bauldreay, J.; Rollin, G.; Rye, L.; Wilson, C.

    2010-01-01

    This paper summarises the findings from the SWAFEA preliminary state of the art study. It covers trends in aspects of future air transport, potential candidate fuels and associated feedstock along with sustainability and economical issues relevant for alternative fuels in aviation..

  4. Investing in Alternative Fuel Infrastructure: Insights for California from Stakeholder Interviews: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Melaina, Marc; Muratori, Matteo; McLaren, Joyce; Schwabe, Paul

    2017-03-13

    Increased interest in the use of alternative transportation fuels, such as natural gas, hydrogen, and electricity, is being driven by heightened concern about the climate impacts of gasoline and diesel emissions and our dependence on finite oil resources. A key barrier to widespread adoption of low- and zero-emission passenger vehicles is the availability of refueling infrastructure. Recalling the 'chicken and egg' conundrum, limited adoption of alternative fuel vehicles increases the perceived risk of investments in refueling infrastructure, while lack of refueling infrastructure inhibits vehicle adoption. In this paper, we present the results of a study of the perceived risks and barriers to investment in alternative fuels infrastructure, based on interviews with industry experts and stakeholders. We cover barriers to infrastructure development for three alternative fuels for passenger vehicles: compressed natural gas, hydrogen, and electricity. As an early-mover in zero emission passenger vehicles, California provides the early market experience necessary to map the alternative fuel infrastructure business space. Results and insights identified in this study can be used to inform investment decisions, formulate incentive programs, and guide deployment plans for alternative fueling infrastructure in the U.S. and elsewhere.

  5. Fuel From Farms: A Guide to Small-Scale Ethanol Production.

    Science.gov (United States)

    Solar Energy Research Inst., Golden, CO.

    Ethanol and blends of ethanol and gasoline (such as gasohol) offer a near-term fuel alternative to oil. The focus of this handbook is upon the small-scale production of ethanol using farm crops as the source of raw materials. Provided are chapters on ethanol production procedures, feedstocks, plant design, and financial planning. Also presented…

  6. Use of alternative product in patients with chronic viral hepatitis

    Directory of Open Access Journals (Sweden)

    Mahmut Dulger

    2014-09-01

    Full Text Available Objectives: Some of the patients with chronic hepatitis use both alternative product and/or antiviral treatment. These herbal products sometimes lead to clinical deterioration. In this study we aimed to determine the purpose of alternative product utilization and rate among the chronic hepatitis B (CHB and C (CHC patients. Methods: This prospective cohort study included 200 consecutive adult patients with chronic hepatitis B and C at the Department of Infectious Diseases, Ondokuz Mayis University, between 1 March 2012 and 30 July 2012. At enrollment, clinical information, demographics, laboratory variables and knowledge about alternative products were recorded. Results: Of the patients 150 had CHB, 50 had CHC. 54% of patients were male. Use of alternative products was 26%. Antiviral treatment rate was 48.5% for all patients. The most used alternative products were artichoke extract and honey. 67.3% of patients were using single alternative product whereas the others were using two or more alternative products. 46.2% of patients who use alternative product provided information about the alternative product usage, but the others did not. Conclusions: Majority of patients used alternative products. More than half of these patients did not give information to their physicians about their use of alternative medicine. Use of alternative product should be asked in all patients with chronic hepatitis. Herbal product usage was detected in majority of patients and also approximately half of these patients did not give information to their doctors about taking alternative medicine. In conclusion, it is necessary to take detailed information about herbal product usage in patients with chronic hepatitis. J Microbiol Infect Dis 2014; 4(3: 102-106

  7. Use of hazelnut kernel oil methyl ester and its blends as alternative fuels in diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Guemues, M.; Atmaca, M. [Marmara Univ., Istanbul (Turkey). Mechanical Department

    2008-09-30

    Interest in vegetable oil as an alternative to diesel fuel in diesel engines has increased during the last few decades because reserves of petroleum fuel and its derivatives are diminishing rapidly, and because they have harmful effects on the environment. Numerous vegetable oil esters have been tried as alternatives to diesel fuel. Many researchers have reported that with the use of vegetable oil ester as a fuel in diesel engiens there is a decrease in harmful exhaust emissions and engine performance that is the equivalent of diesel fuel. Several studies have found that biodiesel emits far less of the most regulated pollutants than standard diesel fuel. Decreasing carbon dioxide (CO{sub 2}) emissions by using biodiesel contributes to reducing the greenhouse effect. Furthermore, diminishing carbon monoxide (CO), hydrocarbons (HC), nitrogen oxides (NO{sub x}), and smoke density improves air quality. Essential oils that have been tested in diesel engines are soybean, sunflower, corn, safflower, cottonseed, and rapeseed, which are categorized as edible oils; however, some edible oils, such as neat hazelnut kernel oil, have not been comprehensively tested as alternative fuel in diesel engines. In this study, hazelnut (Corylus avellana L.) kernel oil was evaluated as an alternative fuel in diesel engines. Firstly, the optimum transesteri.cation reaction conditions for hazelnut kernel oil, with respect to reaction temperature, volumetric ratio of reactants, and catalyst, were investigated. Secondly, an experimental investigation was carried out to examine performance and emissions of a direct injection diesel engine running on hazelnut kernel oil methyl ester and its blends with diesel fuel. Results showed that hazelnut kernel oil methyl ester and its blends with diesel fuel are generally comparable to diesel fuel, according to engine performance and emissions.

  8. Hydropyrolysis of biomass to produce liquid hydrocarbon fuels. Final report. Biomass Alternative-Fuels Program

    Energy Technology Data Exchange (ETDEWEB)

    Fujita, R K; Bodle, W W; Yuen, P C

    1982-10-01

    The ojective of the study is to provide a process design and cost estimates for a biomass hydropyrolysis plant and to establish its economic viability for commercial applications. A plant site, size, product slate, and the most probable feedstock or combination of feedstocks were determined. A base case design was made by adapting IGT's HYFLEX process to Hawaiian biomass feedstocks. The HYFLEX process was developed by IGT to produce liquid and/or gaseous fuels from carbonaceous materials. The essence of the process is the simultaneous extraction of valuable oil and gaseous products from cellulosic biomass feedstocks without forming a heavy hard-to-handle tar. By controlling rection time and temperature, the product slate can be varied according to feedstock and market demand. An optimum design and a final assessment of the applicability of the HYFLEX process to the conversion of Hawaiian biomass was made. In order to determine what feedstocks could be available in Hawaii to meet the demands of the proposed hydropyrolysis plant, various biomass sources were studied. These included sugarcane and pineapple wastes, indigenous and cultivated trees and indigenous and cultivated shrubs and grasses.

  9. Comparison of fuel production costs for future transportation

    DEFF Research Database (Denmark)

    Ridjan, Iva; Mathiesen, Brian Vad; Connolly, David

    The purpose of this poster is to provide an overview of fuel production costs for two types of synthetic fuels – methanol and methane, along with comparable costs for first and second generation biodiesel, two types of second generation bioethanol, and biogas. The model analysed is a 100% renewab...... scenario of Denmark for 2050, where the data for the transport sector has been changed to estimate the fuel production costs for eight different fuel pathways....

  10. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS. FINAL QUARTERLY STATUS REPORT NO. 10

    Energy Technology Data Exchange (ETDEWEB)

    None

    1998-11-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  11. Alternative-fueled truck demonstration natural gas program: Caterpillar G3406LE development and demonstration

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-01

    In 1990, the California Energy Commission, the South Coast Air Quality Management District, and the Southern California Gas Company joined together to sponsor the development and demonstration of compressed natural gas engines for Class 8 heavy-duty line-haul trucking applications. This program became part of an overall Alternative-Fueled Truck Demonstration Program, with the goal of advancing the technological development of alternative-fueled engines. The demonstration showed natural gas to be a technically viable fuel for Class 8 truck engines.

  12. Alternative fuels and chemicals from synthesis gas. Fourth quarterly report, 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  13. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS. FINAL QUARTERLY STATUS REPORT

    Energy Technology Data Exchange (ETDEWEB)

    None

    1999-04-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  14. Accurate High-Temperature Reaction Networks for Alternative Fuels: Butanol Isomers

    Energy Technology Data Exchange (ETDEWEB)

    Van Geem, K. M.; Pyl, S. P.; Marin, G. B.; Harper, M. R.; Green, W. H.

    2010-11-03

    Oxygenated hydrocarbons, particularly alcohol compounds, are being studied extensively as alternatives and additives to conventional fuels due to their propensity of decreasing soot formation and improving the octane number of gasoline. However, oxygenated fuels also increase the production of toxic byproducts, such as formaldehyde. To gain a better understanding of the oxygenated functional group’s influence on combustion properties—e.g., ignition delay at temperatures above the negative temperature coefficient regime, and the rate of benzene production, which is the common precursor to soot formation—a detailed pressure-dependent reaction network for n-butanol, sec-butanol, and tert-butanol consisting of 281 species and 3608 reactions is presented. The reaction network is validated against shock tube ignition delays and doped methane flame concentration profiles reported previously in the literature, in addition to newly acquired pyrolysis data. Good agreement between simulated and experimental data is achieved in all cases. Flux and sensitivity analyses for each set of experiments have been performed, and high-pressure-limit reaction rate coefficients for important pathways, e.g., the dehydration reactions of the butanol isomers, have been computed using statistical mechanics and quantum chemistry. The different alcohol decomposition pathways, i.e., the pathways from primary, secondary, and tertiary alcohols, are discussed. Furthermore, comparisons between ethanol and n-butanol, two primary alcohols, are presented, as they relate to ignition delay.

  15. Thermal Aspects of Using Alternative Nuclear Fuels in Supercritical Water-Cooled Reactors

    Science.gov (United States)

    Grande, Lisa Christine

    A SuperCritical Water-cooled Nuclear Reactor (SCWR) is a Generation IV concept currently being developed worldwide. Unique to this reactor type is the use of light-water coolant above its critical point. The current research presents a thermal-hydraulic analysis of a single fuel channel within a Pressure Tube (PT)-type SCWR with a single-reheat cycle. Since this reactor is in its early design phase many fuel-channel components are being investigated in various combinations. Analysis inputs are: steam cycle, Axial Heat Flux Profile (AHFP), fuel-bundle geometry, and thermophysical properties of reactor coolant, fuel sheath and fuel. Uniform and non-uniform AHFPs for average channel power were applied to a variety of alternative fuels (mixed oxide, thorium dioxide, uranium dicarbide, uranium nitride and uranium carbide) enclosed in an Inconel-600 43-element bundle. The results depict bulk-fluid, outer-sheath and fuel-centreline temperature profiles together with the Heat Transfer Coefficient (HTC) profiles along the heated length of fuel channel. The objective is to identify the best options in terms of fuel, sheath material and AHFPS in which the outer-sheath and fuel-centreline temperatures will be below the accepted temperature limits of 850°C and 1850°C respectively. The 43-element Inconel-600 fuel bundle is suitable for SCWR use as the sheath-temperature design limit of 850°C was maintained for all analyzed cases at average channel power. Thoria, UC2, UN and UC fuels for all AHFPs are acceptable since the maximum fuel-centreline temperature does not exceed the industry accepted limit of 1850°C. Conversely, the fuel-centreline temperature limit was exceeded for MOX at all AHFPs, and UO2 for both cosine and downstream-skewed cosine AHFPs. Therefore, fuel-bundle modifications are required for UO2 and MOX to be feasible nuclear fuels for SCWRs.

  16. Life cycle analysis and choice of natural gas-based automotive alternative fuels in Chongqing Municipality,China

    Institute of Scientific and Technical Information of China (English)

    WU Rui; LI Guangyi; ZHANG Zongyi; REN Yulong; HAN Weijian

    2007-01-01

    Road transport produces significant amounts of emissions by using crude oil as the primary energy source.A reduction of emissions can be achieved by implementing alternative fuel chains.The objective of this study is to carry out an economic,environmental and energy (EEE) life cycle study on natural gas-based automotive fuels with conventional gasoline in an abundant region of China.A set of indices of four fuels/vehicle systems on the basis of life cycle are assessed in terms of impact of EEE,in which natural gas produces compressed natural gas (CNG),methanol,dimethylether (DME) and Fischer Tropsch diesel (FTD).The study included fuel production,vehicle production,vehicle operation,infrastructure and vehicle end of life as a system for each fuel/vehicle system.A generic gasoline fueled car is used as a baseline.Data have been reviewed and modified based on the best knowledge available to Chongqing local sources.Results indicated that when we could not change electric and hydrogen fuel cell vehicles into commercial vehicles on a large scale,direct use of CNG in a dedicated or bi-fuel vehicle is an economical choice for the region which is most energy efficient and more environmental friendly.The study can be used to support decisions on how natural gas resources can best be utilized as a fuel/energy resource for automobiles,and what issues need to be resolved in Chongqing.The models and approaches for this study can be applied to other regions of China as long as all the assumptions are well defined and modified to find a substitute automotive energy source and establish an energy policy in a specific region.

  17. Alternative anode materials for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Goodenough, John B.; Huang, Yun-Hui [Texas Materials Institute, ETC 9.102, 1 University Station, C2200, The University of Texas at Austin, Austin, TX 78712 (United States)

    2007-11-08

    The electrolyte of a solid oxide fuel cell (SOFC) is an O{sup 2-}-ion conductor. The anode must oxidize the fuel with O{sup 2-} ions received from the electrolyte and it must deliver electrons of the fuel chemisorption reaction to a current collector. Cells operating on H{sub 2} and CO generally use a porous Ni/electrolyte cermet that supports a thin, dense electrolyte. Ni acts as both the electronic conductor and the catalyst for splitting the H{sub 2} bond; the oxidation of H{sub 2} to H{sub 2}O occurs at the Ni/electrolyte/H{sub 2} triple-phase boundary (TPB). The CO is oxidized at the oxide component of the cermet, which may be the electrolyte, yttria-stabilized zirconia, or a mixed oxide-ion/electron conductor (MIEC). The MIEC is commonly a Gd-doped ceria. The design and fabrication of these anodes are evaluated. Use of natural gas as the fuel requires another strategy, and MIECs are being explored for this application. The several constraints on these MIECs are outlined, and preliminary results of this on-going investigation are reviewed. (author)

  18. The life cycle assessment of alternative fuel chains for urban buses and trolleybuses.

    Science.gov (United States)

    Kliucininkas, L; Matulevicius, J; Martuzevicius, D

    2012-05-30

    This paper describes a comparative analysis of public transport alternatives in the city of Kaunas, Lithuania. An LCA (Life Cycle Assessment) inventory analysis of fuel chains was undertaken using the midi urban bus and a similar type of trolleybus. The inventory analysis of fuel chains followed the guidelines provided by the ISO 14040 and ISO 14044 standards. The ReCiPe Life Cycle Impact Assessment (LCIA) methodology was used to quantify weighted damage originating from five alternative fuel chains. The compressed biogas fuel chain had the lowest weighted damage value, namely 45.7 mPt/km, whereas weighted damage values of the fuel chains based on electricity generation for trolleybuses were 60.6 mPt/km (for natural gas) and 78.9 mPt/km (for heavy fuel oil). The diesel and compressed natural gas fuel chains exhibited considerably higher damage values of 114.2 mPt/km and 132.6 mPt/km, respectively. The comparative life cycle assessment of fuel chains suggested that biogas-powered buses and electric trolleybuses can be considered as the best alternatives to use when modernizing the public transport fleet in Kaunas.

  19. Thermodynamic Analysis of Alternative Marine Fuels for Marine Gas Turbine Power Plants

    Institute of Scientific and Technical Information of China (English)

    Mohamed M El Gohary; Nader R Ammar

    2016-01-01

    The marine shipping industry faces challenges to reduce engine exhaust emissions and greenhouse gases (GHGs) from ships, and in particular, carbon dioxide. International regulatory bodies such as the International Maritime Organization and National Environmental Agencies of many countries have issued rules and regulations to drastically reduce GHG and emissions emanating from marine sources. This study investigates the possibility of using natural gas and hydrogen as alternative fuels to diesel oil for marine gas turbines and uses a mathematical model to assess the effect of these alternative fuels on gas turbine thermodynamic performance. Results show that since natural gas is categorized as a hydrocarbon fuel, the thermodynamic performance of the gas turbine cycle using natural gas was close to that of the diesel case. However, the gas turbine thermal efficiency was found to be slightly lower for natural gas and hydrogen fuels compared to diesel fuel.

  20. Thermodynamic analysis of alternative marine fuels for marine gas turbine power plants

    Science.gov (United States)

    El Gohary, Mohamed M.; Ammar, Nader R.

    2016-03-01

    The marine shipping industry faces challenges to reduce engine exhaust emissions and greenhouse gases (GHGs) from ships, and in particular, carbon dioxide. International regulatory bodies such as the International Maritime Organization and National Environmental Agencies of many countries have issued rules and regulations to drastically reduce GHG and emissions emanating from marine sources. This study investigates the possibility of using natural gas and hydrogen as alternative fuels to diesel oil for marine gas turbines and uses a mathematical model to assess the effect of these alternative fuels on gas turbine thermodynamic performance. Results show that since natural gas is categorized as a hydrocarbon fuel, the thermodynamic performance of the gas turbine cycle using natural gas was close to that of the diesel case. However, the gas turbine thermal efficiency was found to be slightly lower for natural gas and hydrogen fuels compared to diesel fuel.

  1. Cracking and hydrocracking of triglycerides for renewable liquid fuels: alternative processes to transesterification

    Energy Technology Data Exchange (ETDEWEB)

    Frety, Roger; Rocha, Maria da Graca C. da; Brandao, Soraia T., E-mail: frety@unifacs.b [Universidade Federal da Bahia (IQ/UFBA), Salvador, BA (Brazil). Inst. de Quimica; Pontes, Luiz A.M; Padilha, Jose F. [Universidade de Salvador (UNIFACS), BA (Brazil); Borges, Luiz E.P.; Gonzalez, Wilma A. [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil). Secao de Quimica

    2011-07-01

    The most used industrial processes for the production of liquid fuels like diesel type are based on the methanolysis and ethanolysis of various oil reactants, such as palm, soybean and rapeseed oils, in the presence of homogeneous base catalysts. However, thermal and catalytic transformations of vegetable oils using available reactors and industrial processes are possible alternatives and deserve attention. In fact, three industrial processes are operating and new projects are announced. The present work analyses the experimental studies performed up to now by Brazilian researchers in the field of cracking, catalytic cracking and hydrocracking of pure or modified vegetable oils. From the published results, some research areas for the near future are suggested. (author)

  2. Combustion of solid alternative fuels in the cement kiln burner

    OpenAIRE

    Nørskov, Linda Kaare; Dam-Johansen, Kim; Glarborg, Peter; Jensen, Peter Arendt; Larsen, Morten Boberg

    2012-01-01

    I cementindustrien er der en øget miljømœssig og økonomisk motivation for at erstatte konventionelle fossile brœndsler med alternative brœndsler; biomasse og affald. Indførelsen af alternative brœndsler kan dog påvirke emissioner, cementproduktkvalitet, processtabilitet og -effektivitet. I kalcinatoren er substitutionen med alternative brœndsler nået tœt på 100% på mange cementanlœg, og for at øge anvendelsen af alternative brœndsler yderligere må substitutionen i roterovnen øges. Der er begr...

  3. Status and outlook for biofuels, other alternative fuels and new vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Nylund, N.-O.; Aakko-Saksa, P.; Sipilae, K.

    2008-03-15

    The report presents an outlook for alternative motor fuels and new vehicles. The time period covered extends up to 2030. The International Energy Agency and the U.S. Energy Information Administration predict that the world energy demand will increase by over 50% from now to 2030, if policies remain unchanged. Most of the growth in demand for energy in general, as well as for transport fuels, will take place in non-OECD countries. Gasoline and diesel are projected to remain the dominant automotive fuels until 2030. Vehicle technology and high quality fuels will eventually solve the problem of harmful exhaust emissions. However, the problem with CO{sub 2} still remains, and much attention will be given to increase efficiency. Hybrid technology is one option to reduce fuel consumption. Diesel engines are fuel efficient, but have high emissions compared with advanced gasoline engines. New combustion systems combining the best qualities of gasoline and diesel engines promise low emissions as well as high efficiency. The scenarios for alternative fuels vary a lot. By 2030, alternative fuels could represent a 10- 30% share of transport fuels, depending on policies. Ambitious goals for biofuels in transport have been set. As advanced biofuels are still in their infancy, it seems probable that traditional biofuels will also be used in 2030. Ethanol is the fastest growing biofuel. Currently the sustainability of biofuels is discussed extensively. Synthetic fuels promise excellent end-use properties, reduced emissions, and if produced from biomass, also reduced CO{sub 2} emissions. The report presents an analysis of technology options to meet the requirements for energy security, reduced CO{sub 2} emissions, reduced local emissions as well as sustainability in general in the long run. In the short term, energy savings will be the main measure for CO{sub 2} reductions in transport, fuel switches will have a secondary role. (orig.)

  4. 40 CFR 1054.645 - What special provisions apply for converting an engine to use an alternate fuel?

    Science.gov (United States)

    2010-07-01

    ... conformity. (b) Converting a certified engine that is not new to run on a different fuel type violates 40 CFR... converting an engine to use an alternate fuel? 1054.645 Section 1054.645 Protection of Environment... apply for converting an engine to use an alternate fuel? A certificate of conformity is no longer...

  5. 40 CFR 1045.645 - What special provisions apply for converting an engine to use an alternate fuel?

    Science.gov (United States)

    2010-07-01

    ...) Converting a certified engine that is not new to run on a different fuel type violates 40 CFR 1068.101(b)(1... converting an engine to use an alternate fuel? 1045.645 Section 1045.645 Protection of Environment... for converting an engine to use an alternate fuel? A certificate of conformity is no longer valid...

  6. Development of alternative fuels from coal-derived syngas. Quarterly status report No. 6, January 1--March 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products` laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively ``benign`` system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE`s program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  7. Evaluation of oxygen-enrichment system for alternative fuel vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Poola, R.B.; Sekar, R.R.; Ng, H.K.

    1995-12-01

    This report presents results on the reduction in exhaust emissions achieved by using oxygen-enriched intake air on a flexible fuel vehicle (FFV) that used Indolene and M85 as test fuels. The standard federal test procedure (FTP) and the US Environmental Protection Agency`s (EPA`s) off-cycle (REP05) test were followed. The report also provides a review of literature on the oxygen membrane device and design considerations. It presents information on the sources and contributions of cold-phase emissions to the overall exhaust emissions from light-duty vehicles (LDVs) and on the various emission standards and present-day control technologies under consideration. The effects of oxygen-enriched intake air on FTP and off-cycle emissions are discussed on the basis of test results. Conclusions are drawn from the results and discussion, and different approaches for the practical application of this technology in LDVs are recommended.

  8. Oxidative dissolution of spent nuclear fuel in aqueous alkaline solutions - An alternative to the Purex process?

    Energy Technology Data Exchange (ETDEWEB)

    Runde, Wolfgang; Peper, Shane; Brodnax, Lia; Crooks, William; Zehnder, Ralph; Jarvinen, Gordon

    2004-07-01

    As an alternative to acidic reprocessing of spent nuclear, oxidative dissolution of UO{sub 2} into aqueous alkaline solutions and subsequent separation of fission products is considered. The efficacy of such a method is limited by the kinetics of the UO{sub 2} dissolution and the capacity of alkaline solutions for dissolved U(VI) species. We performed a series of dissolution studies on UO{sub 2} and U{sub 3}O{sub 8} in aqueous alkaline solutions applying various oxidants. Among the oxidative agents commonly used to transform low-valence actinides into their higher oxidation states, H{sub 2}O{sub 2} has proven to be the most effective in basic media. Consequently, we investigated the dissolution of UO{sub 2} and U{sub 3}O{sub 8} in NaOH-H{sub 2}O{sub 2} and Na{sub 2}CO{sub 3}-H{sub 2}O{sub 2} solutions and determined the dissolution kinetics as a function of peroxide and hydroxide (carbonate) concentrations. Methods to remove fission products, e.g., Cs, Sr, Ba and Zr, from alkaline solutions will be evaluated based upon their decontamination factors. We will discuss the feasibility of using chemically oxidizing alkaline solutions as an alternative spent nuclear fuel reprocessing method based on results from experimental quantitative investigations. (authors)

  9. Alternative Observers for SI Engine Air/Fuel Ratio Control

    DEFF Research Database (Denmark)

    Hendricks, Elbert; Poulsen, Jannik; Olsen, Mads Bruun

    1996-01-01

    In earlier work it has been shown that a nonlinear observer based on the use of the manifold pressure state equation and a nonlinear fuel film compensator can maintain accurate A/F ratio control during both steady state and transient operation. This observer may be called a manifold absolute pres...... engine control system designer with a variety of robust control systems which can easily be made redundant in order to satisfy newer engine emissions and diagnosis requirements and legislation...

  10. Development of alternative fuels from coal derived syngas. Topical report: Task 2.2, Demonstration of a one-step slurry-phase process for the production of dimethyl ether/methanol mixtures at the LaPorte Alternative Fuels Development Unit

    Energy Technology Data Exchange (ETDEWEB)

    1993-06-01

    This report documents engineering, modification, and operations efforts of demonstration of dimethyl-ether/methanol coproduction in a slurry-phase reactor, carried out in a 2-ft diameter bubble column reactor. Equipment modifications made it possible to remove the product DME and by-product CO{sub 2} from the reactor effluent. Coproduction of dimethyl-ether (DME) and methanol (MeOH) was accomplished in the slurry reactor by physically mixing two different catalysts. The catalyst used to produce MeOH from syngas was manufactured by BASF (type S3-86); the catalyst used to convert MeOH to DME was Catapal {gamma}-alumina. Ratio of MeOH to DME catalysts determined the selectivity towards DME. The demonstration sought to study effect of cocatalyst ratio on product selectivity. Three different proportions of DME catalyst were examined: 0, 6.6, and 19.3 wt % alumina. At each catalyst proportion, the plant was operated at two different gas space velocities. Some process variables were maintained at fixed conditions; most important variables included: reactor temperature (482F), reactor pressure (750 psig), and reactor feed gas composition (35% H{sub 2}, 51% CO,13% CO{sub 2} 1% other, nominal-molar basis).

  11. The USAF and Alternative Jet Fuel: How to Fuel the Future of Airpower

    Science.gov (United States)

    2009-02-01

    times that of the second largest consumer, China . 1 There are two fundamental problems with this situation. First, oil is a finite resource. As...biofuels are the most common and include ethanol, biomass fuels and biodiesel. These fuels are developed from any crop with a high sugar or starch content...two biofuels are created by processing the starches or sugars of plants (or plant waste) to create an ethanol-based fuel. In contrast, biofuel from

  12. Photosynthetic terpene hydrocarbon production for fuels and chemicals

    Science.gov (United States)

    Photosynthetic terpene production[ED1] represents an energy and carbon-efficient route for hydrocarbon fuel production. Diverse terpene structures also provide the potential to produce next-generation 'drop-in' hydrocarbon fuel molecules. However, it is highly challenging to achieve efficient redire...

  13. Alternative fuels for vehicles fleet demonstration program final report. Volume 1: Summary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The Alternative Fuels for Vehicles Fleet Demonstration Program (AFV-FDP) was a multiyear effort to collect technical data for use in determining the costs and benefits of alternative-fuel vehicles in typical applications in New York State. During 3 years of collecting data, 7.3 million miles of driving were accumulated, 1,003 chassis-dynamometer emissions tests were performed, 862,000 gallons of conventional fuel were saved, and unique information was developed about garage safety recommendations, vehicle performance, and other topics. Findings are organized by vehicle and fuel type. For light-duty compressed natural gas (CNG) vehicles, technology has evolved rapidly and closed-loop, electronically-controlled fuel systems provide performance and emissions advantages over open-loop, mechanical systems. The best CNG technology produces consistently low tailpipe emissions versus gasoline, and can eliminate evaporative emissions. Reduced driving range remains the largest physical drawback. Fuel cost is low ($/Btu) but capital costs are high, indicating that economics are best with vehicles that are used intensively. Propane produces impacts similar to CNG and is less expensive to implement, but fuel cost is higher than gasoline and safety codes limit use in urban areas. Light-duty methanol/ethanol vehicles provide performance and emissions benefits over gasoline with little impact on capital costs, but fuel costs are high. Heavy-duty CNG engines are evolving rapidly and provide large reductions in emissions versus diesel. Capital costs are high for CNG buses and fuel efficiency is reduced, but the fuel is less expensive and overall operating costs are about equal to those of diesel buses. Methanol buses provide performance and emissions benefits versus diesel, but fuel costs are high. Other emerging technologies were also evaluated, including electric vehicles, hybrid-electric vehicles, and fuel cells.

  14. Production and Testing of Coconut Oil Biodiesel Fuel and its Blend

    Directory of Open Access Journals (Sweden)

    Oguntola J ALAMU

    2010-12-01

    Full Text Available Many researchers have successfully worked on generating energy from different alternative sources including solar and biological sources such as the conversion of trapped energy from sunlight to electricity and conversion of some renewable agricultural products to fuel. This work considers the use of coconut oil for the production of alternative renewable and environmental friendly biodiesel fuel as an alternative to conventional diesel fuel. Test quantities of coconut oil biodiesel were produced through transesterification reaction using 100g coconut oil, 20.0% ethanol (wt% coconut oil, 0.8% potassium hydroxide catalyst at 65°C reaction temperature and 120 min. reaction time. The experiment was carried out three times and average results evaluated. Low yield of the biodiesel (10.4% was obtained. The coconut oil biodiesel produced was subsequently blended with petroleum diesel and characterized as alternative diesel fuel through some ASTM standard fuel tests. The products were further evaluated by comparing specific gravity and viscosity of the biodiesel blend, the raw coconut oil and conventional petroleum diesel.

  15. Using Checklists to Assess Your Transition to Alternative Fuels: A Technical Reference

    Energy Technology Data Exchange (ETDEWEB)

    Risch, C. E. [Argonne National Lab. (ANL), Argonne, IL (United States); Santini, D. J. [Argonne National Lab. (ANL), Argonne, IL (United States); Johnson, L. R. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2016-12-01

    The Checklist for Transition to New Alternative Fuel(s) was published in September 2011 by Chuck Risch and Dan Santini. Many improvements, described below, have been incorporated into this current document, Checklists for Assessing the Transitions to New Highway Fuels.2 Further, the original authors and Larry Johnson, co-author of the current report, identified a need for a succinct version of the full report and prepared a brochure based on it to aid busy decisionmakers: Check It Out: Using Checklists to Assess Your Transition to Alternative Fuels.2 These checklists are tools for those stakeholders charged with determining a feasible alternative fuel or fuels for highway transportation systems of the future. The original had four major players whose needs had to be satisfied for a successful transition. The term “activist,” intended to encompass environmental and other special interests, was included in the “customers” category. Activists are customers of the government in the sense that they organize citizens to exert political pressure to regulate the design of vehicles, fuel infrastructure, and roadway networks. Many who evaluate alternative fuels view activists, particularly environmental activists, as a separate category. Further, “activist” has become a pejorative term to many people. Therefore, we have used the word “advocate” or “activist/advocate” instead. Thus, in this update we recognize that environmental and other activists/advocates have been--and will continue to be--a powerful force promoting change in the nature of the fuels that are used in transportation.

  16. Production of distillate fuels from biomass-derived polyoxygenates

    Energy Technology Data Exchange (ETDEWEB)

    Kania, John; Blommel, Paul; Woods, Elizabeth; Dally, Brice; Lyman, Warren; Cortright, Randy

    2017-03-14

    The present invention provides methods, reactor systems and catalysts for converting biomass and biomass-derived feedstocks to C.sub.8+ hydrocarbons using heterogenous catalysts. The product stream may be separated and further processed for use in chemical applications, or as a neat fuel or a blending component in jet fuel and diesel fuel, or as heavy oils for lubricant and/or fuel oil applications.

  17. Does habitual behavior affect the choice of alternative fuel vehicles?

    DEFF Research Database (Denmark)

    Valeri, Eva; Cherchi, Elisabetta

    2016-01-01

    significant latent habitual effect on choices of type of car engine. This effect is important only for some of the car alternatives considered in the study. In particular, habitual car users prefer to buy a new car with liquefied petroleum gas and compressed natural gas types of engine technology instead...... of liquefied petroleum gas car....

  18. Biomass gasification for liquid fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Najser, Jan, E-mail: jan.najser@vsb.cz, E-mail: vaclav.peer@vsb.cz; Peer, Václav, E-mail: jan.najser@vsb.cz, E-mail: vaclav.peer@vsb.cz [VSB - Technical university of Ostrava, Energy Research Center, 17. listopadu 15/2172, 708 33 Ostrava-Poruba (Czech Republic); Vantuch, Martin [University of Zilina, Faculty of Mechanical Engineering, Department of Power Engineering, Univerzitna 1, 010 26 Zilina (Slovakia)

    2014-08-06

    In our old fix-bed autothermal gasifier we tested wood chips and wood pellets. We make experiments for Czech company producing agro pellets - pellets made from agricultural waste and fastrenewable natural resources. We tested pellets from wheat and rice straw and hay. These materials can be very perspective, because they dońt compete with food production, they were formed in sufficient quantity and in the place of their treatment. New installation is composed of allothermal biomass fixed bed gasifier with conditioning and using produced syngas for Fischer - Tropsch synthesis. As a gasifying agent will be used steam. Gas purification will have two parts - separation of dust particles using a hot filter and dolomite reactor for decomposition of tars. In next steps, gas will be cooled, compressed and removed of sulphur and chlorine compounds and carbon dioxide. This syngas will be used for liquid fuel synthesis.

  19. (Fuel, fission product, and graphite technology)

    Energy Technology Data Exchange (ETDEWEB)

    Stansfield, O.M.

    1990-07-25

    Travel to the Forschungszentrum (KFA) -- Juelich described in this report was for the purpose of participating in the annual meeting of subprogram managers for the US/DOE Umbrella Agreement for Fuel, Fission Product, and Graphite Technology. At this meeting the highlights of the cooperative exchange were reviewed for the time period June 1989 through June 1990. The program continues to contribute technology in an effective way for both countries. Revision 15 of the Subprogram Plan will be issued as a result of the meeting. There was interest expressed by KFA management in the level of support received from the NPR program and in potential participation in the COMEDIE loop experiment being conducted at the CEA.

  20. Alternatives for managing wastes from reactors and post-fission operations in the LWR fuel cycle. Volume 3. Alternatives for interim storage and transportation

    Energy Technology Data Exchange (ETDEWEB)

    1976-05-01

    Volume III of the five-volume report contains information on alternatives for interim storage and transportation. Section titles are: interim storage of spent fuel elements; interim storage of chop-leach fuel bundle residues; tank storage of high-level liquid waste; interim storage of solid non-high-level wastes; interim storage of solidified high-level waste; and, transportation alternatives. (JGB)

  1. Metabolic Engineering for Production of Biorenewable Fuels and Chemicals: Contributions of Synthetic Biology

    Directory of Open Access Journals (Sweden)

    Laura R. Jarboe

    2010-01-01

    Full Text Available Production of fuels and chemicals through microbial fermentation of plant material is a desirable alternative to petrochemical-based production. Fermentative production of biorenewable fuels and chemicals requires the engineering of biocatalysts that can quickly and efficiently convert sugars to target products at a cost that is competitive with existing petrochemical-based processes. It is also important that biocatalysts be robust to extreme fermentation conditions, biomass-derived inhibitors, and their target products. Traditional metabolic engineering has made great advances in this area, but synthetic biology has contributed and will continue to contribute to this field, particularly with next-generation biofuels. This work reviews the use of metabolic engineering and synthetic biology in biocatalyst engineering for biorenewable fuels and chemicals production, such as ethanol, butanol, acetate, lactate, succinate, alanine, and xylitol. We also examine the existing challenges in this area and discuss strategies for improving biocatalyst tolerance to chemical inhibitors.

  2. Physical Simulation of Burning Process of Alternative Engine Fuels

    Directory of Open Access Journals (Sweden)

    M. S. Assad

    2008-01-01

    Full Text Available Visualization of burning process in the closed vessel has been fulfilled with the help of method high-speed photography through a transparent glass. This method as an efficient means for investigation of fast processes permits to obtain a visual, convenient visual perception insight about the development of the burning process and understand peculiarities of the development of flame in the closed vessels.The paper contains a description of an experimental stand and methodology for execution of an experiment on visualization of the flame development and measurement of main parameters of the burning process in a closed vessel that is in the simulating combustion chamber.According to the obtained photos an analysis of form, structure and dynamics of flame front development has been carried out; some peculiarities and differences of flames of various fuel-air mixtures have been established and the paper proves an occurrence of the secondary glow during burning in the closed vessel.Body of data obtained with the help of the visualization of burning process makes it possible to determine main parameters of the burning process. In particular, relation of the pressure developed in the chamber with the mass of burnt-out mixture has been investigated and dependence has been obtained that shows the law of fuel burning-out in the graphic form.

  3. Clean Cities Guide to Alternative Fuel and Advanced Medium- and Heavy-Duty Vehicles (Book)

    Energy Technology Data Exchange (ETDEWEB)

    2013-08-01

    Today's fleets are increasingly interested in medium-duty and heavy-duty vehicles that use alternative fuels or advanced technologies that can help reduce operating costs, meet emissions requirements, improve fleet sustainability, and support U.S. energy independence. Vehicle and engine manufacturers are responding to this interest with a wide range of options across a steadily growing number of vehicle applications. This guide provides an overview of alternative fuel power systems?including engines, microturbines, electric motors, and fuel cells?and hybrid propulsion systems. The guide also offers a list of individual medium- and heavy-duty vehicle models listed by application, along with associated manufacturer contact information, fuel type(s), power source(s), and related information.

  4. Clean Cities Guide to Alternative Fuel and Advanced Medium- and Heavy-Duty Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-08-01

    Today's fleets are increasingly interested in medium-duty and heavy-duty vehicles that use alternative fuels or advanced technologies that can help reduce operating costs, meet emissions requirements, improve fleet sustainability, and support U.S. energy independence. Vehicle and engine manufacturers are responding to this interest with a wide range of options across a steadily growing number of vehicle applications. This guide provides an overview of alternative fuel power systems--including engines, microturbines, electric motors, and fuel cells--and hybrid propulsion systems. The guide also offers a list of individual medium- and heavy-duty vehicle models listed by application, along with associated manufacturer contact information, fuel type(s), power source(s), and related information.

  5. A comparative analysis of alternative fuels for the INEL vehicle fleet

    Energy Technology Data Exchange (ETDEWEB)

    Priebe, S.; Boyer, W.; Church, K.

    1992-11-01

    This report summarizes the results of a comparative systems analysis of various alternative fuels for use in the buses, mid-size vehicles, and automobiles that make up the vehicle fleet at the Idaho National Engineering Laboratory (INEL). The study was performed as part of the Laboratory Directed Research and Development (LDRD) Program for EG&G Idaho, Inc. Regulations will require the INEL to reduce total gasoline and diesel fuel use 10% by 1995 compared with 1991 levels, and will require that 50% of all new vehicles be fueled by some type of alternative fuel by 1998. A model was developed to analyze how these goals could be achieved, and what the cost would be to implement the goals.

  6. A comparative analysis of alternative fuels for the INEL vehicle fleet

    Energy Technology Data Exchange (ETDEWEB)

    Priebe, S.; Boyer, W.; Church, K.

    1992-11-01

    This report summarizes the results of a comparative systems analysis of various alternative fuels for use in the buses, mid-size vehicles, and automobiles that make up the vehicle fleet at the Idaho National Engineering Laboratory (INEL). The study was performed as part of the Laboratory Directed Research and Development (LDRD) Program for EG G Idaho, Inc. Regulations will require the INEL to reduce total gasoline and diesel fuel use 10% by 1995 compared with 1991 levels, and will require that 50% of all new vehicles be fueled by some type of alternative fuel by 1998. A model was developed to analyze how these goals could be achieved, and what the cost would be to implement the goals.

  7. Bio-Fuel Production Assisted with High Temperature Steam Electrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Grant Hawkes; James O' Brien; Michael McKellar

    2012-06-01

    Two hybrid energy processes that enable production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure are presented. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), these two hybrid energy processes have the potential to provide a significant alternative petroleum source that could reduce dependence on imported oil. The first process discusses a hydropyrolysis unit with hydrogen addition from HTSE. Non-food biomass is pyrolyzed and converted to pyrolysis oil. The pyrolysis oil is upgraded with hydrogen addition from HTSE. This addition of hydrogen deoxygenates the pyrolysis oil and increases the pH to a tolerable level for transportation. The final product is synthetic crude that could then be transported to a refinery and input into the already used transportation fuel infrastructure. The second process discusses a process named Bio-Syntrolysis. The Bio-Syntrolysis process combines hydrogen from HTSE with CO from an oxygen-blown biomass gasifier that yields syngas to be used as a feedstock for synthesis of liquid synthetic crude. Conversion of syngas to liquid synthetic crude, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model

  8. Comparative analysis of alternative fuels in detonation combustion

    OpenAIRE

    Azami, M. H.; Savill, Mark A.

    2016-01-01

    Detonation combustion prominently exhibits high thermodynamic efficiency which leads to better performance. As compared to the conventionally used isobaric heat addition in a Brayton cycle combustor, detonation uses a novel isochoric Humphrey cycle which utilises shocks and detonation waves to provide pressure-rise combustion. Such unsteady combustion has already been explored in wave rotor, pulse detonation engine and rotating detonation engine configurations as alternative technologies for ...

  9. Processing Of Neem And Jatropha Methyl Esters –Alternative Fuels From Vegetable Oil

    Science.gov (United States)

    Ramasubramanian, S.; Manavalan, S.; Gnanavel, C.; Balakrishnan, G.

    2017-03-01

    Biodiesel is an alternative fuel for diesel engine. The methyl esters of vegetable oils, known as biodiesel are becoming increasingly popular because of their low environmental impact and potential as a green alternative fuel for diesel engine. This paper deals with the manufacturing process of Biodiesel from jatropha and neem oil. Biodiesel was prepared from neem oil and jatropha oil, the transestrified having kinematic viscosity of 3 & 2.6 centistokes, methanol ratio is 6:1 & 5.1respectively. The secondary solution is preheated at 65 C & 60 C and reaction temperature is maintained at 60C & 55 C and reaction time is 60 minutes approximately with NaOH catalyst and low viscosity oil is allowed to settle 24 hours. The average yield of neem and jatropha methyl esters was about 85%. These methyl esters shows excellent alternative under optimum condition for fossil fuels.

  10. Molten carbonate fuel cell product design improvement

    Energy Technology Data Exchange (ETDEWEB)

    P. Voyentzie; T. Leo; A. Kush; L. Christner; G. Carlson; C. Yuh

    1998-12-20

    Drawing on the manufacture, field test, and post-test experience of the sixteen Santa Clara Demonstration Project (SCDP) stacks, ERC is finalizing the next generation commercial entry product design. The second generation cells are 50% larger in area, 40% lighter on equal geometric area basis, and 30% thinner than the earlier design. These improvements have resulted in doubling of the full-height stack power. A low-cost and high-strength matrix has also been developed for improving product ruggedness. The low-cost advanced cell design incorporating these improvements has been refined through six short stack tests. Power production per cell of two times the SCDP maximum power operation, over ten thermal cycles, and overall operating flexibility with respect to load and thermal changes have been demonstrated in these short stack tests. An internally insulated stack enclosure has been designed and fabricated to eliminate the need for an inert gas environment during operation. ERC has acquired the capability for testing 400kW full-height direct fuel ceil (DFC) stack and balance-of-plant equipment. With the readiness of the power plant test facility, the cell package design, and the stack module, full-height stack testing has begun. The first full- height stack incorporating the post-SCDP second generation design was completed. The stack reached a power level of 253 kW, setting a world record for the highest power production from the advanced fuel cell system. Excellent performance uniformity at this power level affirmed manufacturing reproducibility of the components at the factory. This unoptimized small size test has achieved pipeline natural gas to DC electricity conversion efficiency of 47% (based on lower heating value - LHV) including the parasitic power consumed by the BOP equipment; that should translate to more than 50% efficiency in commercial operation, before employing cogeneration. The power plant system also operated smoothly. With the success of this

  11. A Technical Review of Compressed Natural Gas as an Alternative Fuel for Internal Combustion Engines

    OpenAIRE

    Semin; Rosli A. Bakar

    2008-01-01

    Natural gas is promising alternative fuel to meet strict engine emission regulations in many countries. Compressed natural gas (CNG) has long been used in stationary engines, but the application of CNG as a transport engines fuel has been considerably advanced over the last decade by the development of lightweight high-pressure storage cylinders. Engine conversion technology is well established and suitable conversion equipment is readily available. For spark ignition engines there are two op...

  12. Theoretical investigaion of the performance of alternative aviation fuels in an aero-enginve combustion chamber

    OpenAIRE

    2009-01-01

    When considering alternative fuels for aviation, factors such as the overall efficiency of the combustion process and the levels of emissions emitted to the atmosphere, need to be critically evaluated. The physical and chemical properties of a fuel influence the combustion efficiency and emissions and therefore need to be considered. The energy content of a biofuel, which is influenced negatively by the presence of oxygen in the molecular structure (i.e. oxygenated chemical compounds), is rel...

  13. Monopole star products are non-alternative

    CERN Document Server

    Bojowald, Martin; Buyukcam, Umut; Strobl, Thomas

    2016-01-01

    Non-associative algebras appear in some quantum-mechanical systems, for instance if a charged particle in a distribution of magnetic monopoles is considered. Using methods of deformation quantization it is shown here, that algebras for such systems cannot be alternative, i.e. their associator cannot be completely anti-symmetric.

  14. Chemical state of fission products in irradiated uranium carbide fuel

    Science.gov (United States)

    Arai, Yasuo; Iwai, Takashi; Ohmichi, Toshihiko

    1987-12-01

    The chemical state of fission products in irradiated uranium carbide fuel has been estimated by equilibrium calculation using the SOLGASMIX-PV program. Solid state fission products are distributed to the fuel matrix, ternary compounds, carbides of fission products and intermetallic compounds among the condensed phases appearing in the irradiated uranium carbide fuel. The chemical forms are influenced by burnup as well as stoichiometry of the fuel. The results of the present study almost agree with the experimental ones reported for burnup simulated carbides.

  15. Combustion of Sewage Sludge as Alternative Fuel for Cement Industry

    Institute of Scientific and Technical Information of China (English)

    LI Fuzhou; ZHANG Wei

    2011-01-01

    The combustion of sewage sludge and coal was studied by thermogravimetric analysis.Both differential scanning calorimetric analysis and derivative thermogravimetric profiles showed differences between combustion of sewage sludge and coal, and non-isothermal kinetics analysis method was applied to evaluate the combustion process. Based on Coats-Redfem integral method, some reaction models were tested,the mechanism and kinetics of the combustion reaction were discussed. The results show that the combustion of sewage sludge is mainly in the Iow temperature stage, meanwhile the ignition temperature and Arrhenius activation energy are lower than that of coal. The combustion of sewage sludge has the advantage over coal in some aspects, thus sewage sludge can partly replace coal used as cement industry fuel.

  16. Fuel preparation for use in the production of medical isotopes

    Science.gov (United States)

    Policke, Timothy A.; Aase, Scott B.; Stagg, William R.

    2016-10-25

    The present invention relates generally to the field of medical isotope production by fission of uranium-235 and the fuel utilized therein (e.g., the production of suitable Low Enriched Uranium (LEU is uranium having 20 weight percent or less uranium-235) fuel for medical isotope production) and, in particular to a method for producing LEU fuel and a LEU fuel product that is suitable for use in the production of medical isotopes. In one embodiment, the LEU fuel of the present invention is designed to be utilized in an Aqueous Homogeneous Reactor (AHR) for the production of various medical isotopes including, but not limited to, molybdenum-99, cesium-137, iodine-131, strontium-89, xenon-133 and yttrium-90.

  17. SO2 Release as a Consequence of Alternative Fuel Combustion in Cement Rotary Kiln Inlets

    DEFF Research Database (Denmark)

    Cortada Mut, Maria del Mar; Nørskov, Linda Kaare; Glarborg, Peter;

    2015-01-01

    The combustion of alternative fuels in direct contact with the bed material of the rotary kiln may cause local reducing conditions and, subsequently, decomposition of sulfates from cement raw materials, increasing the SO2 concentration in the gas phase. The decomposition of sulfates increases...... the sulfur circulation and may be problematic because high sulfur circulation can cause sticky material buildup, affecting the process operation of the cement kiln system. The SO2 release from cement raw materials during combustion of pine wood and tire rubber has been studied experimentally in a high......-temperature rotary drum, focusing on the influence of the fuel particle size and volatile content. The SO2 release increased with a decreasing fuel particle size and with an increasing fuel volatile content. Furthermore, CO, H2, and CH4, which are the main reducing gases released during fuel devolatilization, were...

  18. Thermodynamic analysis of SOFC (solid oxide fuel cell) - Stirling hybrid plants using alternative fuels

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2013-01-01

    A novel hybrid power system (∼10 kW) for an average family home is proposed. The system investigated contains a solid oxide fuel cell (SOFC) on top of a Stirling engine. The off-gases produced in the SOFC cycle are fed to a bottoming Stirling engine, at which additional power is generated....... Simulations of the proposed system were conducted using different fuels, which should facilitate the use of a variety of fuels depending on availability. Here, the results for natural gas (NG), ammonia, di-methyl ether (DME), methanol and ethanol are presented and analyzed. The system behavior is further...... investigated by comparing the effects of key factors, such as the utilization factor and the operating conditions under which these fuels are used. Moreover, the effect of using a methanator on the plant efficiency is also studied. The combined system improves the overall electrical efficiency relative...

  19. Fischer-Tropsch Catalyst for Aviation Fuel Production

    Science.gov (United States)

    DeLaRee, Ana B.; Best, Lauren M.; Bradford, Robyn L.; Gonzalez-Arroyo, Richard; Hepp, Aloysius F.

    2012-01-01

    As the oil supply declines, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to nonpetroleum sources as a feedstock for aviation (and other transportation) fuels. The Fischer-Tropsch process uses a gas mixture of carbon monoxide and hydrogen which is converted into various liquid hydrocarbons; this versatile gas-to-liquid technology produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fischer-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur and aromatic compounds. It is most commonly catalyzed by cobalt supported on alumina, silica, or titania or unsupported alloyed iron powders. Cobalt is typically used more often than iron, in that cobalt is a longer-active catalyst, has lower water-gas shift activity, and lower yield of modified products. Promoters are valuable in improving Fischer-Tropsch catalyst as they can increase cobalt oxide dispersion, enhance the reduction of cobalt oxide to the active metal phase, stabilize a high metal surface area, and improve mechanical properties. Our goal is to build up the specificity of the Fischer-Tropsch catalyst while adding less-costly transition metals as promoters; the more common promoters used in Fischer-Tropsch synthesis are rhenium, platinum, and ruthenium. In this report we will describe our preliminary efforts to design and produce catalyst materials to achieve our goal of preferentially producing C8 to C18 paraffin compounds in the NASA Glenn Research Center Gas-To-Liquid processing plant. Efforts at NASA Glenn Research Center for producing green fuels using non-petroleum feedstocks support both the Sub-sonic Fixed Wing program of Fundamental Aeronautics and the In Situ Resource Utilization program of the Exploration Technology Development and Demonstration program.

  20. Summary of Plutonium-238 Production Alternatives Analysis Final Report

    Energy Technology Data Exchange (ETDEWEB)

    James Werner; Wade E. Bickford; David B. Lord; Chadwick D. Barklay

    2013-03-01

    The Team implemented a two-phase evaluation process. During the first phase, a wide variety of past and new candidate facilities and processing methods were assessed against the criteria established by DOE for this assessment. Any system or system element selected for consideration as an alternative within the project to reestablish domestic production of Pu-238 must meet the following minimum criteria: Any required source material must be readily available in the United States, without requiring the development of reprocessing technologies or investments in systems to separate material from identified sources. It must be cost, schedule, and risk competitive with existing baseline technology. Any identified facilities required to support the concept must be available to the program for the entire project life cycle (notionally 35 years, unless the concept is so novel as to require a shorter duration). It must present a solution that can generate at least 1.5 Kg of Pu-238 oxide per year, for at least 35 years. It must present a low-risk, near-term solution to the National Aeronautics and Space Administration’s urgent mission need. DOE has implemented this requirement by eliminating from project consideration any alternative with key technologies at less than Technology Readiness Level 5. The Team evaluated the options meeting these criteria using a more detailed assessment of the reasonable facility variations and compared them to the preferred option, which consists of target irradiation at the Advanced Test Reactor (ATR) and the High Flux Isotope Reactor (HFIR), target fabrication and chemical separations processing at the ORNL Radiochemical Engineering Development Center, and neptunium 237 storage at the Materials and Fuels Complex at INL. This preferred option is consistent with the Records of Decision from the earlier National Environmental Policy Act (NEPA) documentation

  1. Flame ignition studies of conventional and alternative jet fuels and surrogate components

    Science.gov (United States)

    Liu, Ning

    Practical jet fuels are widely used in air-breathing propulsion, but the chemical mechanisms that control their combustion are not yet understood. Thousands of components are contained in conventional and alternative jet fuels, making thus any effort to model their combustion behavior a daunting task. That has been the motivation behind the development of surrogate fuels that contain typically a small number of neat components, whose physical properties and combustion behavior mimic those of the real jet fuel, and whose kinetics could be modeled with increased degree of confidence. Towards that end, a large number of experimental data are required both for the real fuels and the attendant surrogate components that could be used to develop and validate detailed kinetic models. Those kinetic models could be used then upon reduction to model a combustor and eventually optimize its performance. Among all flame phenomena, ignition is rather sensitive to the oxidative and pyrolytic propensity of the fuel as well as to its diffusivity. The counterflow configuration is ideal in probing both the fuel reactivity and diffusivity aspects of the ignition process and it was used in the present work to determine the ignition temperatures of premixed and non-premixed flames of a variety of fuels relevant to air-breathing propulsion. The experiments were performed at atmospheric pressure, elevated unburned fuel mixture temperatures, and various strain rates that were measured locally. Several recent kinetic models were used in direct numerical simulations of the experiments and the computed results were tested against the experimental data. Furthermore, through sensitivity, reaction path, and structure analyses of the computed flames, insight was provided into the dominant mechanisms that control ignition. It was found that ignition is primarily sensitive to fuel diffusion and secondarily sensitive to chemical kinetics and intermediate species diffusivities under the low fuel

  2. Waste Vegetable Oil as an Alternative Fuel for Diesel Vehicles

    Science.gov (United States)

    2009-03-01

    government should procure “environmentally preferable” and “ biobased ” products. Those were non food or feed products and made by renewable agricultural...are needed. The containers should be heat resistant and convenient to move. An internet search revealed there were many different plastic ...receptacles available for about the same relative cost. U.S. Plastics in Lima, Ohio was selected due to the proximity to the base, saving on freight

  3. Preliminary Evaluation of Alternate Designs for HFIR Low-Enriched Uranium Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Renfro, David G [ORNL; Chandler, David [ORNL; Cook, David Howard [ORNL; Ilas, Germina [ORNL; Jain, Prashant K [ORNL; Valentine, Jennifer R [ORNL

    2014-11-01

    Engineering design studies of the feasibility of conversion of the High Flux Isotope Reactor (HFIR) from high-enriched uranium (HEU) to low-enriched uranium (LEU) fuel are ongoing at Oak Ridge National Laboratory (ORNL) as part of an effort sponsored by the U.S. Department of Energy s Global Threat Reduction Initiative (GTRI)/Reduced Enrichment for Research and Test Reactors (RERTR) program. The fuel type selected by the program for the conversion of the five high-power research reactors in the U.S. that still use HEU fuel is a new U-Mo monolithic fuel. Studies by ORNL have previously indicated that HFIR can be successfully converted using the new fuel provided (1) the reactor power can be increased from 85 MW to 100 MW and (2) the fuel can be fabricated to a specific reference design. Fabrication techniques for the new fuel are under development by the program but are still immature, especially for the complex aspects of the HFIR fuel design. In FY 2012, the program underwent a major shift in focus to emphasize developing and qualifying processes for the fabrication of reliable and affordable LEU fuel. In support of this new focus and in an effort to ensure that the HFIR fuel design is as suitable for reliable fabrication as possible, ORNL undertook the present study to propose and evaluate several alternative design features. These features include (1) eliminating the fuel zone axial contouring in the previous reference design by substituting a permanent neutron absorber in the lower unfueled region of all of the fuel plates, (2) relocating the burnable neutron absorber from the fuel plates of the inner fuel element to the side plates of the inner fuel element (the fuel plates of the outer fuel element do not contain a burnable absorber), (3) relocating the fuel zone inside the fuel plate to be centered on the centerline of the depth of the plate, and (4) reshaping the radial contour of the relocated fuel zone to be symmetric about this centerline. The present

  4. Preliminary Evaluation of Alternate Designs for HFIR Low-Enriched Uranium Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Renfro, David [ORNL; Chandler, David [ORNL; Cook, David [ORNL; Ilas, Germina [ORNL; Jain, Prashant [ORNL; Valentine, Jennifer [ORNL

    2014-10-30

    Engineering design studies of the feasibility of conversion of the High Flux Isotope Reactor (HFIR) from high-enriched uranium (HEU) to low-enriched uranium (LEU) fuel are ongoing at Oak Ridge National Laboratory (ORNL) as part of an effort sponsored by the U.S. Department of Energy’s Global Threat Reduction Initiative (GTRI)/Reduced Enrichment for Research and Test Reactors (RERTR) program. The fuel type selected by the program for the conversion of the five high-power research reactors in the U.S. that still use HEU fuel is a new U-Mo monolithic fuel. Studies by ORNL have previously indicated that HFIR can be successfully converted using the new fuel provided (1) the reactor power can be increased from 85 MW to 100 MW and (2) the fuel can be fabricated to a specific reference design. Fabrication techniques for the new fuel are under development by the program but are still immature, especially for the “complex” aspects of the HFIR fuel design. In FY 2012, the program underwent a major shift in focus to emphasize developing and qualifying processes for the fabrication of reliable and affordable LEU fuel. In support of this new focus and in an effort to ensure that the HFIR fuel design is as suitable for reliable fabrication as possible, ORNL undertook the present study to propose and evaluate several alternative design features. These features include (1) eliminating the fuel zone axial contouring in the previous reference design by substituting a permanent neutron absorber in the lower unfueled region of all of the fuel plates, (2) relocating the burnable neutron absorber from the fuel plates of the inner fuel element to the side plates of the inner fuel element (the fuel plates of the outer fuel element do not contain a burnable absorber), (3) relocating the fuel zone inside the fuel plate to be centered on the centerline of the depth of the plate, and (4) reshaping the radial contour of the relocated fuel zone to be symmetric about this centerline. The

  5. Evaluation of alternative treatments for spent fuel rod consolidation wastes and other miscellaneous commercial transuranic wastes

    Energy Technology Data Exchange (ETDEWEB)

    Ross, W.A.; Schneider, K.J.; Oma, K.H.; Smith, R.I.; Bunnell, L.R.

    1986-05-01

    Eight alternative treatments (and four subalternatives) are considered for both existing commercial transuranic wastes and future wastes from spent fuel consolidation. Waste treatment is assumed to occur at a hypothetical central treatment facility (a Monitored Retrieval Storage facility was used as a reference). Disposal in a geologic repository is also assumed. The cost, process characteristics, and waste form characteristics are evaluated for each waste treatment alternative. The evaluation indicates that selection of a high-volume-reduction alternative can save almost $1 billion in life-cycle costs for the management of transuranic and high-activity wastes from 70,000 MTU of spent fuel compared to the reference MRS process. The supercompaction, arc pyrolysis and melting, and maximum volume reduction alternatives are recommended for further consideration; the latter two are recommended for further testing and demonstration.

  6. MEDIUM PRESSURE HYDROUPGRADING PROCESS (MHUG) AND PRODUCTION OF CLEAN FUELS

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The medium pressure hydroupgrading process (MHUG) unit with an 800 kt/a processing capacity of Jinzhou Petrochemical Company is used to hydroupgrade the mixture of FCC LCO fuel and straight-run diesel fuel in the presence of RN/RT series catalysts for improvement of the quality of the diesel fuel. Meanwhile, catalytic reforming feedstock is also obtained. The sulfur, nitrogen and aromatics contained in the hydroupgraded diesel fuel products can be minimized and the cetane number can be heightened. The produced clean fuels can meet the requirements of environmental protection.

  7. Reducing transit bus emissions: Alternative fuels or traffic operations?

    Science.gov (United States)

    Alam, Ahsan; Hatzopoulou, Marianne

    2014-06-01

    In this study, we simulated the operations and greenhouse gas (GHG) emissions of transit buses along a busy corridor and quantified the effects of two different fuels (conventional diesel and compressed natural gas) as well as a set of driving conditions on emissions. Results indicate that compressed natural gas (CNG) reduces GHG emissions by 8-12% compared to conventional diesel, this reduction could increase to 16% with high levels of traffic congestion. However, the benefits of switching from conventional diesel to CNG are less apparent when the road network is uncongested. We also investigated the effects of bus operations on emissions by applying several strategies such as transit signal priority (TSP), queue jumper lanes, and relocation of bus stops. Results show that in congested conditions, TSP alone can reduce GHG emissions by 14% and when combined with improved technology; a reduction of 23% is achieved. The reduction benefits are even more apparent when other transit operational improvements are combined with TSP. Finally a sensitivity analysis was performed to investigate the effect of operational improvements on emissions under varying levels of network congestion. We observe that under “extreme congestion”, the benefits of TSP decrease.

  8. Advanced Electrochemical Technologies for Hydrogen Production by Alternative Thermochemical Cycles

    Energy Technology Data Exchange (ETDEWEB)

    Lvov, Serguei; Chung, Mike; Fedkin, Mark; Lewis, Michele; Balashov, Victor; Chalkova, Elena; Akinfiev, Nikolay; Stork, Carol; Davis, Thomas; Gadala-Maria, Francis; Stanford, Thomas; Weidner, John; Law, Victor; Prindle, John

    2011-01-06

    Hydrogen fuel is a potentially major solution to the problem of climate change, as well as addressing urban air pollution issues. But a key future challenge for hydrogen as a clean energy carrier is a sustainable, low-cost method of producing it in large capacities. Most of the world's hydrogen is currently derived from fossil fuels through some type of reforming processes. Nuclear hydrogen production is an emerging and promising alternative to the reforming processes for carbon-free hydrogen production in the future. This report presents the main results of a research program carried out by a NERI Consortium, which consisted of Penn State University (PSU) (lead), University of South Carolina (USC), Tulane University (TU), and Argonne National Laboratory (ANL). Thermochemical water decomposition is an emerging technology for large-scale production of hydrogen. Typically using two or more intermediate compounds, a sequence of chemical and physical processes split water into hydrogen and oxygen, without releasing any pollutants externally to the atmosphere. These intermediate compounds are recycled internally within a closed loop. While previous studies have identified over 200 possible thermochemical cycles, only a few have progressed beyond theoretical calculations to working experimental demonstrations that establish scientific and practical feasibility of the thermochemical processes. The Cu-Cl cycle has a significant advantage over other cycles due to lower temperature requirements – around 530 °C and below. As a result, it can be eventually linked with the Generation IV thermal power stations. Advantages of the Cu-Cl cycle over others include lower operating temperatures, ability to utilize low-grade waste heat to improve energy efficiency, and potentially lower cost materials. Another significant advantage is a relatively low voltage required for the electrochemical step (thus low electricity input). Other advantages include common chemical agents and

  9. Long-term sampling of dioxin-like substances from a clinker kiln stack using alternative fuels.

    Science.gov (United States)

    Rivera-Austrui, J; Martinez, K; Marco-Almagro, L; Abalos, M; Abad, E

    2014-07-01

    The aim of this work is to characterize atmospheric emissions of polychlorinated dibenzo-p-dioxins (PCDDs)/polychlorinated dibenzofurans (PCDFs) and dioxin-like polychlorinated biphenyls (dl-PCBs) from a cement production plant where the existing clinker production line was completely replaced by a new state-of-the-art installation. The project started in April 2008 with the installation of a long-term sampling system in the stack of the clinker kiln that used petroleum coke as fuel; PCDD/PCDF and dl-PCB emissions were then evaluated for a two year period. To carry out the second part of the study, in 2010 the sampling system was moved to the new installation in which, apart from conventional fuel, recovered derived fuel (RDF) and WWTP sludge were used as alternative fuels. For both the old and new clinker kilns, PCDD/PCDF emission values were well below the limit established by the European Waste Incineration Directive 2000/76/CE (EWID) of 100 pg I-TEQ/Nm(3); values ranged from 0.43 to 2.02 and from 0.07 to 3.31 pg I-TEQ/Nm(3), respectively. dl-PCBs accounted for approximately 25% of the WHO-TEQ toxicity. These results prove that the installation is capable of reducing PCDD/PCDF and dl-PCB emissions when alternative fuels are integrated into the process. In the case of PCDDs/PCDFs, the major contributions to total TEQ were usually from 2,3,7,8-TCDD (owing to its relative abundance) and 2,3,4,7,8-PeCDF (due to its high I-TEF of 0.5); while for dl-PCBs, the major contribution was from PCB-126. The slight shift in the congener profile between the old and new installations was characterized and a regression model was proposed for dl-PCB emissions depending on the RDF flow rate in the clinker.

  10. An evaluation of alternate production methods for Pu-238 general purpose heat source pellets

    Energy Technology Data Exchange (ETDEWEB)

    Mark Borland; Steve Frank

    2009-06-01

    For the past half century, the National Aeronautics and Space Administration (NASA) has used Radioisotope Thermoelectric Generators (RTG) to power deep space satellites. Fabricating heat sources for RTGs, specifically General Purpose Heat Sources (GPHSs), has remained essentially unchanged since their development in the 1970s. Meanwhile, 30 years of technological advancements have been made in the applicable fields of chemistry, manufacturing and control systems. This paper evaluates alternative processes that could be used to produce Pu 238 fueled heat sources. Specifically, this paper discusses the production of the plutonium-oxide granules, which are the input stream to the ceramic pressing and sintering processes. Alternate chemical processes are compared to current methods to determine if alternative fabrication processes could reduce the hazards, especially the production of respirable fines, while producing an equivalent GPHS product.

  11. Life-Cycle Analyses of Energy Consumption and GHG Emissions of Natural Gas-Based Alternative Vehicle Fuels in China

    Directory of Open Access Journals (Sweden)

    Xunmin Ou

    2013-01-01

    Full Text Available Tsinghua life-cycle analysis model (TLCAM has been used to examine the primary fossil energy consumption and greenhouse gas (GHG emissions for natural gas- (NG- based alternative vehicle fuels in China. The results show that (1 compress NG- and liquid NG-powered vehicles have similar well-to-wheels (WTW fossil energy uses to conventional gasoline- and diesel-fueled vehicles, but differences emerge with the distance of NG transportation. Additionally, thanks to NG having a lower carbon content than petroleum, CNG- and LNG-powered vehicles emit 10–20% and 5–10% less GHGs than gasoline- and diesel-fueled vehicles, respectively; (2 gas-to-liquid- (GTL- powered vehicles involve approximately 50% more WTW fossil energy uses than conventional gasoline- and diesel-fueled vehicles, primarily because of the low efficiency of GTL production. Nevertheless, since NG has a lower carbon content than petroleum, GTL-powered vehicles emit approximately 30% more GHGs than conventional-fuel vehicles; (3 The carbon emission intensity of the LNG energy chain is highly sensitive to the efficiency of NG liquefaction and the form of energy used in that process.

  12. Assessment of the impacts of spent fuel disassembly alternatives on the Nuclear Waste Isolation System. [Preparing and packaging spent fuel assemblies for geologic disposal

    Energy Technology Data Exchange (ETDEWEB)

    1984-07-01

    The objective of this report was to evaluate four possible alternative methods of preparing and packaging spent fuel assemblies for geologic disposal against the Reference Process of unmodified spent fuel. The four alternative processes were: (1) End fitting removal, (2) Fission gas venting and resealing, (3) Fuel bundle disassembly and close packing of fuel pins, and (4) Fuel shearing and immobilization. Systems analysis was used to develop a basis of comparison of the alternatives. Conceptual processes and facility layouts were devised for each of the alternatives, based on technology deemed feasible for the purpose. Assessments were made of 15 principal attributes from the technical, operational, safety/risk, and economic considerations related to each of the alternatives, including both the surface packaging and underground repository operations. Specific attributes of the alternative processes were evaluated by assigning a number for each that expressed its merit relative to the corresponding attribute of the Reference Process. Each alternative process was then ranked by summing the numbers for attributes in each of the four assessment areas and collectively. Fuel bundle disassembly and close packing of fuel pins was ranked the preferred method of disposal of spent fuel. 63 references, 46 figures, 46 tables.

  13. Enteric bacterial catalysts for fuel ethanol production

    Energy Technology Data Exchange (ETDEWEB)

    Ingram, L.O.; Aldrich, H.C.; Borges, A.C.C. [and others

    1999-10-01

    The technology is available to produce fuel ethanol from renewable lignocellulosic biomass. The current challenge is to assemble the various process options into a commercial venture and begin the task of incremental improvement. Current process designs for lignocellulose are far more complex than grain to ethanol processes. This complexity results in part from the complexity of the substrate and the biological limitations of the catalyst. Their work at the University of Florida has focused primarily on the genetic engineering of Enteric bacteria using genes encoding Zymomonas mobilis pyruvate decarboxylase and alcohol dehydrogenase. These two genes have been assembled into a portable ethanol production cassette, the PET operon, and integrated into the chromosome of Escherichia coli B for use with hemicellulose-derived syrups. The resulting strain, KO11, produces ethanol efficiently from all hexose and pentose sugars present in the polymers of hemicellulose. By using the same approach, the authors integrated the PET operon into the chromosome of Klebsiella oxytoca to produce strain P2 for use in the simultaneous saccharification and fermentation (SSF) process for cellulose. Strain P2 has the native ability to ferment cellobiose and cellotriose, eliminating the need for one class of cellulase enzymes.

  14. Historical Perspective of Clean Cities and Alternative Fuels Data Center Trends

    Energy Technology Data Exchange (ETDEWEB)

    O' Connor, J. K.

    2007-09-01

    This document draws on the wealth of information housed in the U.S. Department of Energy's Alternative Fuels Data Center at the National Renewable Energy Laboratory. Trends and analyses are examined from data as far back as 1991. The findings of those trends and salient features are summarized.

  15. Role of the Department of Defense in the Research and Development of Alternative Fuels

    Science.gov (United States)

    2015-06-12

    intergovernmental bureaucracy ; and (3) DOD budgeting process. This study highlights how the political process inhibits an effective DOD alternative......Ernie Sturzenbecher, Fuels Supervisor of the South Dakota Air National Guard, for his patience and leadership . I would like to thank my committee for

  16. 77 FR 14482 - Petroleum Reduction and Alternative Fuel Consumption Requirements for Federal Fleets

    Science.gov (United States)

    2012-03-12

    ... Administration (GSA) to develop a methodology to determine optimal fleet size and composition and instructs... level surface; and (2) Is propelled by an electric motor and an on-board, rechargeable energy storage...; ] DEPARTMENT OF ENERGY 10 CFR Part 438 RIN 1904-AB98 Petroleum Reduction and Alternative Fuel...

  17. Guide for Identifying and Converting High-Potential Petroleum Brownfield Sites to Alternative Fuel Stations

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, C.; Hettinger, D.; Mosey, G.

    2011-05-01

    Former gasoline stations that are now classified as brownfields can be good sites to sell alternative fuels because they are in locations that are convenient to vehicles and they may be seeking a new source of income. However, their success as alternative fueling stations is highly dependent on location-specific criteria. First, this report outlines what these criteria are, how to prioritize them, and then applies that assessment framework to five of the most popular alternative fuels--electricity, natural gas, hydrogen, ethanol, and biodiesel. The second part of this report delves into the criteria and tools used to assess an alternative fuel retail site at the local level. It does this through two case studies of converting former gasoline stations in the Seattle-Eugene area into electric charge stations. The third part of this report addresses steps to be taken after the specific site has been selected. This includes choosing and installing the recharging equipment, which includes steps to take in the permitting process and key players to include.

  18. Production of LEU Fully Ceramic Microencapsulated Fuel for Irradiation Testing

    Energy Technology Data Exchange (ETDEWEB)

    Terrani, Kurt A [ORNL; Kiggans Jr, James O [ORNL; McMurray, Jake W [ORNL; Jolly, Brian C [ORNL; Hunt, Rodney Dale [ORNL; Trammell, Michael P [ORNL; Snead, Lance Lewis [ORNL

    2016-01-01

    Fully Ceramic Microencapsulated (FCM) fuel consists of tristructural isotropic (TRISO) fuel particles embedded inside a SiC matrix. This fuel inherently possesses multiple barriers to fission product release, namely the various coating layers in the TRISO fuel particle as well as the dense SiC matrix that hosts these particles. This coupled with the excellent oxidation resistance of the SiC matrix and the SiC coating layer in the TRISO particle designate this concept as an accident tolerant fuel (ATF). The FCM fuel takes advantage of uranium nitride kernels instead of oxide or oxide-carbide kernels used in high temperature gas reactors to enhance heavy metal loading in the highly moderated LWRs. Production of these kernels with appropriate density, coating layer development to produce UN TRISO particles, and consolidation of these particles inside a SiC matrix have been codified thanks to significant R&D supported by US DOE Fuel Cycle R&D program. Also, surrogate FCM pellets (pellets with zirconia instead of uranium-bearing kernels) have been neutron irradiated and the stability of the matrix and coating layer under LWR irradiation conditions have been established. Currently the focus is on production of LEU (7.3% U-235 enrichment) FCM pellets to be utilized for irradiation testing. The irradiation is planned at INL s Advanced Test Reactor (ATR). This is a critical step in development of this fuel concept to establish the ability of this fuel to retain fission products under prototypical irradiation conditions.

  19. Determination of heating value of industrial waste for the formulation of alternative fuels

    Directory of Open Access Journals (Sweden)

    Bouabid G.

    2013-09-01

    Full Text Available The use of alternative fuels has become increasingly widespread. They are basically designed based on industrial waste so that they can substitute fossil fuels which start to become scarce. Alternative fuels must meet some criteria, namely an important calorific content, minimum humidity and ash content. When it comes to combustion, the most interesting parameter is the calorific value which represents the thermal energy released during combustion. The experiments that were conducted showed that the calorific value is influenced by other parameters namely moisture and ash content. It was therefore necessary to study the behavior of the heating value in terms of these two parameters in order to establish a relationship that is used to describe the behavior. This is expected to allow a simulation of the calorific value of a mixture of various industrial waste.

  20. Alternative fuels and chemicals from synthesis gas. Quarterly report, April 1--June 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts. The paper reports the progress on the following tasks: engineering and modifications: AFDU shakedown, operations, deactivation and disposal; and research and development on new processes for DME, chemistry and catalyst development, and oxygenates via synthesis gas.

  1. Energy and emission benefits of alternative transportation liquid fuels derived from switchgrass: a fuel life cycle assessment.

    Science.gov (United States)

    Wu, May; Wu, Ye; Wang, Michael

    2006-01-01

    We conducted a mobility chains, or well-to-wheels (WTW), analysis to assess the energy and emission benefits of cellulosic biomass for the U.S. transportation sector in the years 2015-2030. We estimated the life-cycle energy consumption and emissions associated with biofuel production and use in light-duty vehicle (LDV) technologies by using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model. Analysis of biofuel production was based on ASPEN Plus model simulation of an advanced fermentation process to produce fuel ethanol/protein, a thermochemical process to produce Fischer-Tropsch diesel (FTD) and dimethyl ether (DME), and a combined heat and power plant to co-produce steam and electricity. Our study revealed that cellulosic biofuels as E85 (mixture of 85% ethanol and 15% gasoline by volume), FTD, and DME offer substantial savings in petroleum (66-93%) and fossil energy (65-88%) consumption on a per-mile basis. Decreased fossil fuel use translates to 82-87% reductions in greenhouse gas emissions across all unblended cellulosic biofuels. In urban areas, our study shows net reductions for almost all criteria pollutants, with the exception of carbon monoxide (unchanged), for each of the biofuel production option examined. Conventional and hybrid electric vehicles, when fueled with E85, could reduce total sulfur oxide (SO(x)) emissions to 39-43% of those generated by vehicles fueled with gasoline. By using bio-FTD and bio-DME in place of diesel, SO(x) emissions are reduced to 46-58% of those generated by diesel-fueled vehicles. Six different fuel production options were compared. This study strongly suggests that integrated heat and power co-generation by means of gas turbine combined cycle is a crucial factor in the energy savings and emission reductions.

  2. Fueling the Car of Tomorrow: An Alternative Fuels Curriculum for High School Science Classes

    Science.gov (United States)

    Schumack, Mark; Baker, Stokes; Benvenuto, Mark; Graves, James; Haman, Arthur; Maggio, Daniel

    2010-01-01

    It is no secret that many high school students are fascinated with automobiles. The activities in "Fueling the Car of Tomorrow"--a free high school science curriculum, available online--(see "On the web")--capitalize on this heightened awareness and provide relevant learning opportunities designed to reinforce basic physics, chemistry, biology,…

  3. Fuel property enhancement of biodiesel fuels from common and alternative feedstocks via complementary blending

    Science.gov (United States)

    Fatty acid methyl esters (biodiesel) prepared from field pennycress and meadowfoam seed oils were blended with methyl esters from camelina, cottonseed, palm, and soybean oils in an effort to ameliorate technical deficiencies inherent to these biodiesel fuels. For instance, camelina, cottonseed, and ...

  4. State and Alternative Fuel Provider Fleets - Fleet Compliance Annual Report: Model Year 2015, Fiscal Year 2016

    Energy Technology Data Exchange (ETDEWEB)

    2016-12-01

    The U.S. Department of Energy (DOE) regulates covered state government and alternative fuel provider fleets, pursuant to the Energy Policy Act of 1992 (EPAct), as amended. Covered fleets may meet their EPAct requirements through one of two compliance methods: Standard Compliance or Alternative Compliance. For model year (MY) 2015, the compliance rate with this program for the more than 3011 reporting fleets was 100%. More than 294 fleets used Standard Compliance and exceeded their aggregate MY 2015 acquisition requirements by 8% through acquisitions alone. The seven covered fleets that used Alternative Compliance exceeded their aggregate MY 2015 petroleum use reduction requirements by 46%.

  5. Integrated coke, asphalt and jet fuel production process and apparatus

    Science.gov (United States)

    Shang, Jer Y.

    1991-01-01

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  6. Alternatives to conventional diesel fuel-some potential implications of California's TAC decision on diesel particulate.

    Energy Technology Data Exchange (ETDEWEB)

    Eberhardt, J. J.; Rote, D. M.; Saricks, C. L.; Stodolsky, F.

    1999-08-10

    Limitations on the use of petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to provisions of the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel, per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible ''mid-course'' strategies. (1) Increased penetration of natural gas and greater gasoline use in the transportation fuels market, to the extent that some compression-ignition (CI) applications revert to spark-ignition (SI) engines. (2) New specifications requiring diesel fuel reformulation based on exhaust products of individual diesel fuel constituents. Each of these alternatives results in some degree of (conventional) diesel displacement. In the first case, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles, and gasoline demand in California increases by 32.2 million liters per day overall, about 21 percent above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter equivalents per day, about 7 percent above projected (total) consumption level. In the second case, compression-ignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case we estimated localized air emission plus generalized greenhouse gas and energy changes. Economic implications of vehicle and engine replacement were not evaluated.

  7. Measurements of nitrous acid in commercial aircraft exhaust at the Alternative Aviation Fuel Experiment.

    Science.gov (United States)

    Lee, Ben H; Santoni, Gregory W; Wood, Ezra C; Herndon, Scott C; Miake-Lye, Richard C; Zahniser, Mark S; Wofsy, Steven C; Munger, J William

    2011-09-15

    The Alternative Aviation Fuel Experiment (AAFEX), conducted in January of 2009 in Palmdale, California, quantified aerosol and gaseous emissions from a DC-8 aircraft equipped with CFM56-2C1 engines using both traditional and synthetic fuels. This study examines the emissions of nitrous acid (HONO) and nitrogen oxides (NO(x) = NO + NO(2)) measured 145 m behind the grounded aircraft. The fuel-based emission index (EI) for HONO increases approximately 6-fold from idle to takeoff conditions but plateaus between 65 and 100% of maximum rated engine thrust, while the EI for NO(x) increases continuously. At high engine power, NO(x) EI is greater when combusting traditional (JP-8) rather than Fischer-Tropsch fuels, while HONO exhibits the opposite trend. Additionally, hydrogen peroxide (H(2)O(2)) was identified in exhaust plumes emitted only during engine idle. Chemical reactions responsible for emissions and comparison to previous measurement studies are discussed.

  8. Biodiesel Fuel Production from Algae as Renewable Energy

    OpenAIRE

    Sharif Hossain, A.B.M.; Aishah Salleh; Amru Nasrulhaq Boyce; Partha chowdhury; Mohd Naqiuddin

    2008-01-01

    Biodiesel is biodegradable, less CO2 and NOx emissions. Continuous use of petroleum sourced fuels is now widely recognized as unsustainable because of depleting supplies and the contribution of these fuels to the accumulation of carbon dioxide in the environment. Renewable, carbon neutral, transport fuels are necessary for environmental and economic sustainability. Algae have emerged as one of the most promising sources for biodiesel production. It can be inferred that algae grown in CO...

  9. Experimental study on spray characteristics of alternate jet fuels using Phase Doppler Anemometry

    Science.gov (United States)

    Kannaiyan, Kumaran; Sadr, Reza

    2013-11-01

    Gas-to-Liquid (GTL) fuels have gained global attention due to their cleaner combustion characteristics. The chemical and physical properties of GTL jet fuels are different from conventional jet fuels owing to the difference in their production methodology. It is important to study the spray characteristics of GTL jet fuels as the change of physical properties can affect atomization, mixing, evaporation and combustion process, ultimately affecting emission process. In this work, spray characteristics of two GTL synthetic jet fuels are studied using a pressure-swirl nozzle at different injection pressures and atmospheric ambient condition. Phase Doppler Anemometry (PDA) measurements of droplet size and velocity are compared with those of regular Jet A-1 fuel at several axial and radial locations downstream of the nozzle exit. Experimental results show that although the GTL fuels have different physical properties such as viscosity, density, and surface tension, among each other the resultant change in the spray characteristics is insignificant. Furthermore, the presented results show that GTL fuel spray characteristics exhibit close similarity to those of Jet A-1 fuel. Funded by Qatar Science and Technology Park.

  10. Polycyclic aromatic hydrocarbon emissions from the combustion of alternative fuels in a gas turbine engine.

    Science.gov (United States)

    Christie, Simon; Raper, David; Lee, David S; Williams, Paul I; Rye, Lucas; Blakey, Simon; Wilson, Chris W; Lobo, Prem; Hagen, Donald; Whitefield, Philip D

    2012-06-01

    We report on the particulate-bound polycyclic aromatic hydrocarbons (PAH) in the exhaust of a test-bed gas turbine engine when powered by Jet A-1 aviation fuel and a number of alternative fuels: Sasol fully synthetic jet fuel (FSJF), Shell gas-to-liquid (GTL) kerosene, and Jet A-1/GTL 50:50 blended kerosene. The concentration of PAH compounds in the exhaust emissions vary greatly between fuels. Combustion of FSJF produces the greatest total concentration of PAH compounds while combustion of GTL produces the least. However, when PAHs in the exhaust sample are measured in terms of the regulatory marker compound benzo[a]pyrene, then all of the alternative fuels emit a lower concentration of PAH in comparison to Jet A-1. Emissions from the combustion of Jet A-1/GTL blended kerosene were found to have a disproportionately low concentration of PAHs and appear to inherit a greater proportion of the GTL emission characteristics than would be expected from volume fraction alone. The data imply the presence of a nonlinear relation between fuel blend composition and the emission of PAH compounds. For each of the fuels, the speciation of PAH compounds present in the exhaust emissions were found to be remarkably similar (R(2) = 0.94-0.62), and the results do provide evidence to support the premise that PAH speciation is to some extent indicative of the emission source. In contrast, no correlation was found between the PAH species present in the fuel with those subsequently emitted in the exhaust. The results strongly suggests that local air quality measured in terms of the particulate-bound PAH burden could be significantly improved by the use of GTL kerosene either blended with or in place of Jet A-1 kerosene.

  11. Effects of Alternative Fuels and Aromatics on Gas-Turbine Particle Emissions

    Science.gov (United States)

    Thornhill, K. L., II; Moore, R.; Winstead, E.; Anderson, B. E.; Klettlinger, J. L.; Ross, R. C.; Surgenor, A.

    2015-12-01

    This presentation describes experiments conducted with a Honeywell GTCP36-150 Auxiliary Power Unit (APU) to evaluate the effects of varying fuel composition on particle emissions. The APU uses a single-stage compressor stage, gas turbine engine with a can-type combustor to generate bypass flow and electrical power for supporting small aircraft and helicopters. It is installed in a "hush-house" at NASA Glenn Research Center and is configured as a stand-alone unit that can be fueled from an onboard tank or external supply. It operates at constant RPM, but its fuel flow can be varied by changing the electrical load or volume of bypass flow. For these tests, an external bank of resistors were attached to the APU's DC and AC electrical outlets and emissions measurements were made at low, medium and maximum electrical current loads. Exhaust samples were drawn from several points downstream in the exhaust duct and fed to an extensive suite of gas and aerosol sensors installed within a mobile laboratory parked nearby. Aromatic- and sulfur-free synthetic kerosenes from Rentech, Gevo, UOP, Amyris and Sasol were tested and their potential to reduce PM emissions evaluated against a single Jet A1 base fuel. The role of aromatic compounds in regulating soot emissions was also evaluated by adding metered amounts of aromatic blends (Aro-100, AF-Blend, SAK) and pure compounds (tetracontane and 1-methylnaphthalene) to a base alternative fuel (Sasol). Results show that, relative to Jet A1, alternative fuels reduce nonvolatile particle number emissions by 50-80% and--by virtue of producing much smaller particles—mass emissions by 65-90%; fuels with the highest hydrogen content produced the greatest reductions. Nonvolatile particle emissions varied in proportion to fuel aromatic content, with additives containing the most complex ring structures producing the greatest emission enhancements.

  12. Medical Countermeasure Product Development - Alternatives Paper

    Science.gov (United States)

    2014-04-01

    Health Departments of Australia, Canada, the United Kingdom and the United States. The Consortium seeks to develop MedCM including drugs, vaccines...Australia, Canada, the United Kingdom and the United States. The Consortium seeks to develop MedCM including drugs, vaccines and diagnostics to assist...been very little incentive for the biotechnology /medical technology community to focus on MedCM product development. This was because the focus of

  13. Quantification of aldehydes emissions from alternative and renewable aviation fuels using a gas turbine engine

    Science.gov (United States)

    Li, Hu; Altaher, Mohamed A.; Wilson, Chris W.; Blakey, Simon; Chung, Winson; Rye, Lucas

    2014-02-01

    In this research three renewable aviation fuel blends including two HEFA (Hydrotreated Ester and Fatty Acid) blends and one FAE (Fatty Acids Ethyl Ester) blend with conventional Jet A-1 along with a GTL (Gas To Liquid) fuel have been tested for their aldehydes emissions on a small gas turbine engine. Three strong ozone formation precursors: formaldehyde, acetaldehyde and acrolein were measured in the exhaust at different operational modes and compared to neat Jet A-1. The aim is to assess the impact of renewable and alternative aviation fuels on aldehydes emissions from aircraft gas turbine engines so as to provide informed knowledge for the future deployment of new fuels in aviation. The results show that formaldehyde was a major aldehyde species emitted with a fraction of around 60% of total measured aldehydes emissions for all fuels. Acrolein was the second major emitted aldehyde species with a fraction of ˜30%. Acetaldehyde emissions were very low for all the fuels and below the detention limit of the instrument. The formaldehyde emissions at cold idle were up to two to threefold higher than that at full power. The fractions of formaldehyde were 6-10% and 20% of total hydrocarbon emissions in ppm at idle and full power respectively and doubled on a g kg-1-fuel basis.

  14. Biofuels Fuels Technology Pathway Options for Advanced Drop-in Biofuels Production

    Energy Technology Data Exchange (ETDEWEB)

    Kevin L Kenney

    2011-09-01

    Advanced drop-in hydrocarbon biofuels require biofuel alternatives for refinery products other than gasoline. Candidate biofuels must have performance characteristics equivalent to conventional petroleum-based fuels. The technology pathways for biofuel alternatives also must be plausible, sustainable (e.g., positive energy balance, environmentally benign, etc.), and demonstrate a reasonable pathway to economic viability and end-user affordability. Viable biofuels technology pathways must address feedstock production and environmental issues through to the fuel or chemical end products. Potential end products include compatible replacement fuel products (e.g., gasoline, diesel, and JP8 and JP5 jet fuel) and other petroleum products or chemicals typically produced from a barrel of crude. Considering the complexity and technology diversity of a complete biofuels supply chain, no single entity or technology provider is capable of addressing in depth all aspects of any given pathway; however, all the necessary expert entities exist. As such, we propose the assembly of a team capable of conducting an in-depth technology pathway options analysis (including sustainability indicators and complete LCA) to identify and define the domestic biofuel pathways for a Green Fleet. This team is not only capable of conducting in-depth analyses on technology pathways, but collectively they are able to trouble shoot and/or engineer solutions that would give industrial technology providers the highest potential for success. Such a team would provide the greatest possible down-side protection for high-risk advanced drop-in biofuels procurement(s).

  15. Bio fuels: an alternative for the sustainability of the familiar agriculture; Biocombustiveis: uma alternativa para a sustentabilidade da agricultura familiar

    Energy Technology Data Exchange (ETDEWEB)

    Freitas, Patricia Honorio [Universidade Salvador, BA (Brazil). Desenvolvimento Regional e Planejamento Ambiental], e-mail: patonorio@hotmail.com; Ventura, Andrea Cardoso [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil)], e-mail: andreaventurassa@gmail.com; Teixeira, Carlos Andre [Semear Ambiental, Salvador, BA (Brazil)], e-mail: carlosteixeira@semearambiental.com.br

    2008-07-01

    Nevertheless the criticism of various economy sectors and international organisms to the production of bio fuels, the Brazilian Government are giving incentives for that production since the year of 2004, when they launched an incentive program for the production of oleaginous species which are the raw material for the production of bio diesel, emphasizing the support to familiar agriculture. However, there are serious questionings about the real contribution of these fuels for the sustainability not only of the planet, but also the population, taking into consideration the possible social and environmental impacts of the implementation of their policies. This paper tries to debate all those problems through the analysis of the possible effects of the Brazilian policies of incentive to the bio diesel production for the family farmers from the semi-arid of the state of Bahia, Brazil. The paper intends to evaluate if this type of production is a real alternative for the sustainability of the familiar agriculture, and if there is another model of more adequate management for the production of oleaginous for bio diesel by the familiar agriculture.

  16. An alternative resource for biogas production

    Energy Technology Data Exchange (ETDEWEB)

    Patrabansh, S. [Tribhuvan Univ., Research Center for Applied Science and Technology, Kirtipur, Kathmandu (Nepal); Madan, M. [Indian Inst. of Technology, Center for Rural Development and Technology, New Delhi (India)

    2000-09-01

    Three different biomasses, namely, sericulture waste, Populus deltoides, and Eupatorium adenophorum, were studied for biogas production. It was found that these wastes produced biogas in reasonably good quantity of gas (259 l/kg of total solid in sericulture waste to 519 l/kg of total solid in E. adenophorum). The substrates were subjected to anaerobic digestion directly, without any pre-treatment, and a batch with biological treatment in triplicate set. Among the two sets, the biologically pretreated digesters gave higher yield of biogas. Chemical analysis for nitrogen content, cellulose, hemicellulose, and lignin content before and after digestion was carried out. (Author)

  17. Alternate-Fueled Combustor-Sector Performance. Parts A and B; (A) Combustor Performance; (B) Combustor Emissions

    Science.gov (United States)

    Shouse, D. T.; Hendricks, R. C.; Lynch, A.; Frayne, C. W.; Stutrud, J. S.; Corporan, E.; Hankins, T.

    2012-01-01

    Alternate aviation fuels for military or commercial use are required to satisfy MIL-DTL-83133F(2008) or ASTM D 7566 (2010) standards, respectively, and are classified as "drop-in" fuel replacements. To satisfy legacy issues, blends to 50% alternate fuel with petroleum fuels are certified individually on the basis of processing and assumed to be feedstock agnostic. Adherence to alternate fuels and fuel blends requires "smart fueling systems" or advanced fuel-flexible systems, including combustors and engines, without significant sacrifice in performance or emissions requirements. This paper provides preliminary performance (Part A) and emissions and particulates (Part B) combustor sector data. The data are for nominal inlet conditions at 225 psia and 800 F (1.551 MPa and 700 K), for synthetic-paraffinic-kerosene- (SPK-) type (Fisher-Tropsch (FT)) fuel and blends with JP-8+100 relative to JP-8+100 as baseline fueling. Assessments are made of the change in combustor efficiency, wall temperatures, emissions, and luminosity with SPK of 0%, 50%, and 100% fueling composition at 3% combustor pressure drop. The performance results (Part A) indicate no quantifiable differences in combustor efficiency, a general trend to lower liner and higher core flow temperatures with increased FT fuel blends. In general, emissions data (Part B) show little differences, but with percent increase in FT-SPK-type fueling, particulate emissions and wall temperatures are less than with baseline JP-8. High-speed photography illustrates both luminosity and combustor dynamic flame characteristics.

  18. Military Fuel and Alternative Fuel Effects on a Modern Diesel Engine Employing a Fuel-Lubricated High Pressure Common Rail Fuel Injection System

    Science.gov (United States)

    2011-08-09

    Fuel-lubricated High Pressure Common Rail Fuel Injection System, Adam C. Brandt, et al. Page 3 of 7 UNCLASSIFIED contains a two lobe camshaft ... camshafts rotation. These follower assemblies are then used to actuate the fuel plunger within the barrel to generate high pressure fuel. Fuel entering...top & bottom Camshaft light polish, seal contact wear light polish, very light burnish, seal contact wear light polish, light burnish, seal

  19. Navy Mobility Fuels Forecasting System report: Navy fuel production in the year 2000

    Energy Technology Data Exchange (ETDEWEB)

    Hadder, G.R.; Davis, R.M.

    1991-09-01

    The Refinery Yield Model of the Navy Mobility Fuels Forecasting System has been used to study the feasibility and quality of Navy JP-5 jet fuel and F-76 marine diesel fuel for two scenarios in the year 2000. Both scenarios account for environmental regulations for fuels produced in the US and assume that Eastern Europe, the USSR, and the People`s Republic of China have free market economies. One scenario is based on business-as-usual market conditions for the year 2000. The second scenario is similar to first except that USSR crude oil production is 24 percent lower. During lower oil production in the USSR., there are no adverse effects on Navy fuel availability, but JP-5 is generally a poorer quality fuel relative to business-as-usual in the year 2000. In comparison with 1990, there are two potential problems areas for future Navy fuel quality. The first problem is increased aromaticity of domestically produced Navy fuels. Higher percentages of aromatics could have adverse effects on storage, handling, and combustion characteristics of both JP-5 and F-76. The second, and related, problem is that highly aromatic light cycle oils are blended into F-76 at percentages which promote fuel instability. It is recommended that the Navy continue to monitor the projected trend toward increased aromaticity in JP-5 and F-76 and high percentages of light cycle oils in F-76. These potential problems should be important considerations in research and development for future Navy engines.

  20. Navy Mobility Fuels Forecasting System report: Navy fuel production in the year 2000

    Energy Technology Data Exchange (ETDEWEB)

    Hadder, G.R.; Davis, R.M.

    1991-09-01

    The Refinery Yield Model of the Navy Mobility Fuels Forecasting System has been used to study the feasibility and quality of Navy JP-5 jet fuel and F-76 marine diesel fuel for two scenarios in the year 2000. Both scenarios account for environmental regulations for fuels produced in the US and assume that Eastern Europe, the USSR, and the People's Republic of China have free market economies. One scenario is based on business-as-usual market conditions for the year 2000. The second scenario is similar to first except that USSR crude oil production is 24 percent lower. During lower oil production in the USSR., there are no adverse effects on Navy fuel availability, but JP-5 is generally a poorer quality fuel relative to business-as-usual in the year 2000. In comparison with 1990, there are two potential problems areas for future Navy fuel quality. The first problem is increased aromaticity of domestically produced Navy fuels. Higher percentages of aromatics could have adverse effects on storage, handling, and combustion characteristics of both JP-5 and F-76. The second, and related, problem is that highly aromatic light cycle oils are blended into F-76 at percentages which promote fuel instability. It is recommended that the Navy continue to monitor the projected trend toward increased aromaticity in JP-5 and F-76 and high percentages of light cycle oils in F-76. These potential problems should be important considerations in research and development for future Navy engines.

  1. Aviation Fuel System Reliability and Fail-Safety Analysis. Promising Alternative Ways for Improving the Fuel System Reliability

    Directory of Open Access Journals (Sweden)

    I. S. Shumilov

    2017-01-01

    Full Text Available The paper deals with design requirements for an aviation fuel system (AFS, AFS basic design requirements, reliability, and design precautions to avoid AFS failure. Compares the reliability and fail-safety of AFS and aircraft hydraulic system (AHS, considers the promising alternative ways to raise reliability of fuel systems, as well as elaborates recommendations to improve reliability of the pipeline system components and pipeline systems, in general, based on the selection of design solutions.It is extremely advisable to design the AFS and AHS in accordance with Aviation Regulations АП25 and Accident Prevention Guidelines, ICAO (International Civil Aviation Association, which will reduce risk of emergency situations, and in some cases even avoid heavy disasters.ATS and AHS designs should be based on the uniform principles to ensure the highest reliability and safety. However, currently, this principle is not enough kept, and AFS looses in reliability and fail-safety as compared with AHS. When there are the examined failures (single and their combinations the guidelines to ensure the AFS efficiency should be the same as those of norm-adopted in the Regulations АП25 for AHS. This will significantly increase reliability and fail-safety of the fuel systems and aircraft flights, in general, despite a slight increase in AFS mass.The proposed improvements through the use of components redundancy of the fuel system will greatly raise reliability of the fuel system of a passenger aircraft, which will, without serious consequences for the flight, withstand up to 2 failures, its reliability and fail-safety design will be similar to those of the AHS, however, above improvement measures will lead to a slightly increasing total mass of the fuel system.It is advisable to set a second pump on the engine in parallel with the first one. It will run in case the first one fails for some reasons. The second pump, like the first pump, can be driven from the

  2. Three-dimensional analysis of the Pratt and Whitney alternate design SSME fuel turbine

    Science.gov (United States)

    Kirtley, K. R.; Beach, T. A.; Adamczyk, J. J.

    1991-01-01

    The three dimensional viscous time-mean flow in the Pratt and Whitney alternate design space shuttle main engine fuel turbine is simulated using the average passage Navier-Stokes equations. The migration of secondary flows generated by upstream blade rows and their effect on the performance of downstream blade rows is studied. The present simulation confirms that the flow in this two stage turbine is highly three dimensional and dominated by the tip leakage flow. The tip leakage vortex generated by the first blade persists through the second blade and adversely affects its performance. The greatest mixing of the inlet total temperature distortion occurs in the second vane and is due to the large leakage vortex generated by the upstream rotor. It is assumed that the predominant spanwise mixing mechanism in this low aspect ratio turbine is the radial transport due to the deterministically unsteady vortical flow generated by upstream blade rows. A by-product of the analysis is accurate pressure and heat loads for all blade rows under the influence of neighboring blade rows. These aero loads are useful for advanced structural analysis of the vanes and blades.

  3. Alternative respiration and fumaric acid production of Rhizopus oryzae.

    Science.gov (United States)

    Gu, Shuai; Xu, Qing; Huang, He; Li, Shuang

    2014-06-01

    Under the conditions of fumaric acid fermentation, Rhizopus oryzae ME-F14 possessed at least two respiratory systems. The respiration of mycelia was partially inhibited by the cytochrome respiration inhibitor antimycin A or the alternative respiration inhibitor salicylhydroxamic acid and was completely inhibited in the presence of both antimycin A and salicylhydroxamic acid. During fumaric acid fermentation process, the activity of alternative respiration had a great correlation with fumaric acid productivity; both of them reached peak at the same time. The alternative oxidase gene, which encoded the mitochondrial alternative oxidase responsible for alternative respiration in R. oryzae ME-F14, was cloned and characterized in Escherichia coli. The activity of alternative respiration, the alternative oxidase gene transcription level, as well as the fumaric acid titer were measured under different carbon sources and different carbon-nitrogen ratios. The activity of alternative respiration was found to be comparable to the transcription level of the alternative oxidase gene and the fumaric acid titer. These results indicated that the activity of the alternative oxidase was regulated at the transcription stage under the conditions tested for R. oryzae ME-F14.

  4. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas

    Energy Technology Data Exchange (ETDEWEB)

    Underwood, R.P.

    1993-01-01

    As part of the DOE-sponsored contract Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal-Derived Syngas'' experimental evaluations of the one-step synthesis of alternative fuels were carried out. The objective of this work was to develop novel processes for converting coal-derived syngas to fuels or fuel additives. Building on a technology base acquired during the development of the Liquid Phase Methanol (LPMEOH) process, this work focused on the development of slurry reactor based processes. The experimental investigations, which involved bench-scale reactor studies, focused primarily on three areas: (1) One-step, slurry-phase syngas conversion to hydrocarbons or methanol/hydrocarbon mixtures using a mixture of methanol synthesis catalyst and methanol conversion catalyst in the same slurry reactor. (2) Slurry-phase conversion of syngas to mixed alcohols using various catalysts. (3) One-step, slurry-phase syngas conversion to mixed ethers using a mixture of mixed alcohols synthesis catalyst and dehydration catalyst in the same slurry reactor. The experimental results indicate that, of the three types of processes investigated, slurry phase conversion of syngas to mixed alcohols shows the most promise for further process development. Evaluations of various mixed alcohols catalysts show that a cesium-promoted Cu/ZnO/Al[sub 2]O[sub 3] methanol synthesis catalyst, developed in Air Products' laboratories, has the highest performance in terms of rate and selectivity for C[sub 2+]-alcohols. In fact, once-through conversion at industrially practical reaction conditions yielded a mixed alcohols product potentially suitable for direct gasoline blending. Moreover, an additional attractive aspect of this catalyst is its high selectivity for branched alcohols, potential precursors to iso-olefins for use in etherification.

  5. Comparison of Global Sizing Velocimetry and Phase Doppler Anemometry measurements of alternative jet fuel sprays

    Science.gov (United States)

    Sadr, Reza; Kannaiyan, Kumaran

    2013-11-01

    Atomization plays a crucial precursor role in liquid fuel combustion that directly affects the evaporation, mixing, and emission levels. Laser diagnostic techniques are often used to study the spray characteristics of liquid fuels. The objective of this work is to compare the spray measurements of Gas-to Liquid (GTL) jet fuels obtained using Global Sizing Velocimetry (GSV) and Phase Doppler Anemometry (PDA) techniques at global and local levels, respectively. The chemical and physical properties of GTL fuels are different from conventional jet fuels, owing to the difference in their production methodology. In this work, the experimental facility, the measurement techniques, and spray characteristics of two different GTL fuels are discussed and compared with those of Jet A-1 fuel. Results clearly demonstrate that although the global measurement gives an overall picture of the spray, fine details are obtained only through local measurements and complement in gaining more inferences into the spray characteristics. The results also show a close similarity in spray characteristics between GTL and Jet A-1 fuels. Funded by Qatar Science and Technology Park.

  6. Quantifying variability in life cycle greenhouse gas inventories of alternative middle distillate transportation fuels.

    Science.gov (United States)

    Stratton, Russell W; Wong, Hsin Min; Hileman, James I

    2011-05-15

    The presence of variability in life cycle analysis (LCA) is inherent due to both inexact LCA procedures and variation of numerical inputs. Variability in LCA needs to be clearly distinguished from uncertainty. This paper uses specific examples from the production of diesel and jet fuels from 14 different feedstocks to demonstrate general trends in the types and magnitudes of variability present in life cycle greenhouse gas (LC-GHG) inventories of middle distillate fuels. Sources of variability have been categorized as pathway specific, coproduct usage and allocation, and land use change. The results of this research demonstrate that subjective choices such as coproduct usage and allocation methodology can be more important sources of variability in the LC-GHG inventory of a fuel option than the process and energy use of fuel production. Through the application of a consistent analysis methodology across all fuel options, the influence of these subjective biases is minimized, and the LC-GHG inventories for each feedstock-to-fuel option can be effectively compared and discussed. By considering the types and magnitudes of variability across multiple fuel pathways, it is evident that LCA results should be presented as a range instead of a point value. The policy implications of this are discussed.

  7. Hybrid fusion reactor for production of nuclear fuel with minimum radioactive contamination of the fuel cycle

    Science.gov (United States)

    Velikhov, E. P.; Kovalchuk, M. V.; Azizov, E. A.; Ignatiev, V. V.; Subbotin, S. A.; Tsibulskiy, V. F.

    2015-12-01

    The paper presents the results of the system research on the coordinated development of nuclear and fusion power engineering in the current century. Considering the increasing problems of resource procurement, including limited natural uranium resources, it seems reasonable to use fusion reactors as high-power neutron sources for production of nuclear fuel in a blanket. It is shown that the share of fusion sources in this structural configuration of the energy system can be relatively small. A fundamentally important aspect of this solution to the problem of closure of the fuel cycle is that recycling of highly active spent fuel can be abandoned. Radioactivity released during the recycling of the spent fuel from the hybrid reactor blanket is at least two orders of magnitude lower than during the production of the same number of fissile isotopes after the recycling of the spent fuel from a fast reactor.

  8. Solar hydrogen production: renewable hydrogen production by dry fuel reforming

    Science.gov (United States)

    Bakos, Jamie; Miyamoto, Henry K.

    2006-09-01

    SHEC LABS - Solar Hydrogen Energy Corporation constructed a pilot-plant to demonstrate a Dry Fuel Reforming (DFR) system that is heated primarily by sunlight focusing-mirrors. The pilot-plant consists of: 1) a solar mirror array and solar concentrator and shutter system; and 2) two thermo-catalytic reactors to convert Methane, Carbon Dioxide, and Water into Hydrogen. Results from the pilot study show that solar Hydrogen generation is feasible and cost-competitive with traditional Hydrogen production. More than 95% of Hydrogen commercially produced today is by the Steam Methane Reformation (SMR) of natural gas, a process that liberates Carbon Dioxide to the atmosphere. The SMR process provides a net energy loss of 30 to 35% when converting from Methane to Hydrogen. Solar Hydrogen production provides a 14% net energy gain when converting Methane into Hydrogen since the energy used to drive the process is from the sun. The environmental benefits of generating Hydrogen using renewable energy include significant greenhouse gas and criteria air contaminant reductions.

  9. Ultra-clean Fischer-Tropsch (F-T) Fuels Production and Demonstration Project

    Energy Technology Data Exchange (ETDEWEB)

    Stephen P. Bergin

    2006-06-30

    lab evaluation; cold-start test-cell evaluations; overall feasibility, economics, and efficiency of SFP fuel production; and an economic analysis. Two unexpected issues that arose during the project were further studied and resolved: variations in NOx emissions were accounted for and fuel-injection nozzle fouling issues were traced to the non-combustible (ash) content of the engine oil, not the F-T fuel. The F-T fuel domestically produced and evaluated in this effort appears to be a good replacement candidate for petroleum-based transportation fuels. However, in order for domestic F-T fuels to become a viable cost-comparable alternative to petroleum fuels, the F-T fuels will need to be produced from abundant U.S. domestic resources such as coal and biomass, rather than stranded natural gas.

  10. Market introduction of fuel cell products: Effects on mechanical engineering and power plant engineering. Preliminary research on products using alternative power and drive systems. Final report; Markteinfuehrung von Brennstoffzellen-Produkten: Auswirkungen auf den Maschinen- und Anlagenbau. Voruntersuchung zu Forschungsfeldern fuer die Herstellung von Produkten mit alternativen Energie- und Antriebssystemen. Endbericht

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    The investigations had the following goals: 1. Analysis of the effects of the fuel cell technology on mechanical engineering and power plant engineering, i.e. a qualitative assessment and the development of scenarios for the seven VDMA associations (drives, construction machinery, fluidics, haulage, power systems, agricultural engineering, machine tools); 2. Analysis of research and development requirements, i.e. analysis of the necessary technologies for fuel cell production. [German] Zielsetzung der Untersuchung war 1. die Analyse der Auswirkungen der Brennstoffzellentechnologie auf den Maschinen- und Anlagenbau, d.h. - qualitative Bewertung der Auswirkungen auf den Maschinen-/Anlagenbau, und - Szenarien fuer sieben Fachverbaende des VDMA (d.h. Antriebstechnik, Baumaschinen, Fluidtechnik, Foerdertechnik, Power Systems, Landtechnik, Werkzeugmaschinen), sowie 2. die Analyse des FuE-Bedarfs, d.h. - Analyse der erforderlichen Produktionstechniken fuer die Herstellung von Brennstoffzellen. (orig.)

  11. Evaluation of the efficiency of alternative enzyme production technologies

    Energy Technology Data Exchange (ETDEWEB)

    Albaek, M.O.

    2012-03-15

    Enzymes are used in an increasing number of industries. The application of enzymes is extending into the production of lignocellulosic ethanol in processes that economically can compete with fossil fuels. Since lignocellulosic ethanol is based on renewable resources it will have a positive impact on for example the emission of green house gasses. Cellulases and hemi-cellulases are used for enzymatic hydrolysis of pretreated lignocellulosic biomass, and fermentable sugars are released upon the enzymatic process. Even though many years of research has decreased the amount of enzyme needed in the process, the cost of enzymes is still considered a bottleneck in the economic feasibility of lignocellulose utilization. The purpose of this project was to investigate and compare different technologies for production of these enzymes. The filamentous fungus Trichoderma reesei is currently used for industrial production of cellulases and hemi-cellulases. The aim of the thesis was to use modeling tools to identify alternative technologies that have higher energy or raw material efficiency than the current technology. The enzyme production by T. reesei was conducted as an aerobic fed-batch fermentation. The process was carried out in pilot scale stirred tank reactors and based on a range of different process conditions, a process model was constructed which satisfactory described the course of fermentation. The process was governed by the rate limiting mass transfer of oxygen from the gas to the liquid phase. During fermentation, filamentous growth of the fungus lead to increased viscosity which hindered mass transfer. These mechanisms were described by a viscosity model based on the biomass concentration of the fermentation broth and a mass transfer correlation that incorporated a viscosity term. An analysis of the uncertainty and sensitivity of the model indicated the biological parameters to be responsible for most of the model uncertainty. A number of alternative

  12. Measuring the distribution of equity in terms of energy, environmental, and economic costs in the fuel cycles of alternative fuel vehicles with hydrogen pathway scenarios

    Science.gov (United States)

    Meyer, Patrick E.

    Numerous analyses exist which examine the energy, environmental, and economic tradeoffs between conventional gasoline vehicles and hydrogen fuel cell vehicles powered by hydrogen produced from a variety of sources. These analyses are commonly referred to as "E3" analyses because of their inclusion of Energy, Environmental, and Economic indicators. Recent research as sought a means to incorporate social Equity into E3 analyses, thus producing an "E4" analysis. However, E4 analyses in the realm of energy policy are uncommon, and in the realm of alternative transportation fuels, E4 analyses are extremely rare. This dissertation discusses the creation of a novel E4 simulation tool usable to weigh energy, environmental, economic, and equity trade-offs between conventional gasoline vehicles and alternative fuel vehicles, with specific application to hydrogen fuel cell vehicles. The model, dubbed the F uel Life-cycle Analysis of Solar Hydrogen -- Energy, Environment, Economic & Equity model, or FLASH-E4, is a total fuel-cycle model that combines energy, environmental, and economic analysis methodologies with the addition of an equity analysis component. The model is capable of providing results regarding total fuel-cycle energy consumption, emissions production, energy and environmental cost, and level of social equity within a population in which low-income drivers use CGV technology and high-income drivers use a number of advanced hydrogen FCV technologies. Using theories of equity and social indicators conceptually embodied in the Lorenz Curve and Gini Index, the equity of the distribution of societal energy and environmental costs are measured for a population in which some drivers use CGVs and other drivers use FCVs. It is found, based on baseline input data representative of the United States (US), that the distribution of energy and environmental costs in a population in which some drivers use CGVs and other drivers use natural gas-based hydrogen FCVs can be

  13. Fuel from Tobacco and Arundo Donax: Synthetic Crop for Direct Drop-in Biofuel Production through Re-routing the Photorespiration Intermediates and Engineering Terpenoid Pathways

    Energy Technology Data Exchange (ETDEWEB)

    None

    2012-02-15

    PETRO Project: Biofuels offer renewable alternatives to petroleum-based fuels that reduce net greenhouse gas emissions to nearly zero. However, traditional biofuels production is limited not only by the small amount of solar energy that plants convert through photosynthesis into biological materials, but also by inefficient processes for converting these biological materials into fuels. Farm-ready, non-food crops are needed that produce fuels or fuel-like precursors at significantly lower costs with significantly higher productivity. To make biofuels cost-competitive with petroleum-based fuels, biofuels production costs must be cut in half.

  14. Simulation of a hydrogen production and purification system for a PEM fuel-cell using bioethanol as raw material

    Energy Technology Data Exchange (ETDEWEB)

    Giunta, Pablo; Amadeo, Norma; Laborde, Miguel [Facultad de Ingenieria, Universidad de Buenos Aires, Laboratorio de Procesos Cataliticos, Pabellon de Industrias, Ciudad Universitaria, 1428 Buenos Aires (Argentina); Mosquera, Carlos [Facultad de Ingenieria, Universidad de Buenos Aires, Departamento de Fisica, 1063 Buenos Aires (Argentina)

    2007-01-10

    A process to produce 'fuel-cell grade' hydrogen from ethanol steam reforming is analyzed from a thermodynamic point of view. The hydrogen purification process consists of WGS and COPROX reactors. Equations to evaluate the efficiency of the system, including the fuel cell, are presented. A heat exchange network is proposed in order to improve the exploitation of the available power. The effect of key variables such as the reformer temperature and the ethanol/water molar feed ratio on the fuel-cell efficiency is discussed. Results show that it is feasible to carry out the energy integration of the hydrogen catalytic production and purification-PEM fuel-cell system, using ethanol as raw material. The technology of 'fuel-cell grade' hydrogen production using ethanol as raw material is a very attractive alternative to those technologies based in fossil fuels. (author)

  15. FEED SYSTEM INNOVATION FOR GASIFICATION OF LOCALLY ECONOMICAL ALTERNATIVE FUELS (FIGLEAF)

    Energy Technology Data Exchange (ETDEWEB)

    Michael L. Swanson; Mark A. Musich; Darren D. Schmidt

    2001-11-01

    The Feed System Innovation for Gasification of Locally Economical Alternative Fuels (FIGLEAF) project is being conducted by the Energy and Environmental Research Center and Gasification Engineering Corporation of Houston, Texas (a subsidiary of Global Energy Inc., Cincinnati, Ohio), with 80% cofunding from the U.S. Department of Energy. The goal of the project is to identify and evaluate low-value fuels that could serve as alternative feedstocks and to develop a feed system to facilitate their use in integrated gasification combined cycle and gasification coproduction facilities. The long-term goal, to be accomplished in a subsequent project, is to install a feed system for the selected fuels at Global Energy's commercial-scale 262-MW Wabash River Coal Gasification Facility in West Terre Haute, Indiana. The feasibility study undertaken for the project consists of identifying and evaluating the economic feasibility of potential fuel sources, developing a feed system design capable of providing a fuel at 400 psig to the second stage of the E-Gas (Destec) gasifier to be cogasified with coal at up to 30% on a Btu basis, performing bench- and pilot-scale testing to verify concepts and clarify decision-based options, reviewing prior art with respect to high-pressure feed system designs, and determining the economics of cofeeding alternative feedstocks with the conceptual feed system design. Activities and results thus far include the following. Several potential alternative fuels have been obtained for evaluation and testing as potential feedstocks, including sewage sludge, used railroad ties, urban wood waste, municipal solid waste, and used waste tires/tire-derived fuel. Only fuels with potential tipping fees were considered; potential energy crop fuels were not considered since they would have a net positive cost to the plant. Based on the feedstock assessment, sewage sludge has been selected as one of the primary feedstocks for consideration at the Wabash plant

  16. FEED SYSTEM INNOVATION FOR GASIFICATION OF LOCALLY ECONOMICAL ALTERNATIVE FUELS (FIGLEAF)

    Energy Technology Data Exchange (ETDEWEB)

    Michael L. Swanson; Mark A. Musich; Darren D. Schmidt; Joseph K. Schultz

    2003-02-01

    The Feed System Innovation for Gasification of Locally Economical Alternative Fuels (FIGLEAF) project was conducted by the Energy & Environmental Research Center and Gasification Engineering Corporation of Houston, Texas (a subsidiary of Global Energy Inc., Cincinnati, Ohio), with 80% cofunding from the U.S. Department of Energy (DOE). The goal of the project was to identify and evaluate low-value fuels that could serve as alternative feedstocks and to develop a feed system to facilitate their use in integrated gasification combined-cycle and gasification coproduction facilities. The long-term goal, to be accomplished in a subsequent project, is to install a feed system for the selected fuel(s) at Global Energy's commercial-scale 262-MW Wabash River Coal Gasification Facility in West Terre Haute, Indiana. The feasibility study undertaken for the project consisted of identifying and evaluating the economic feasibility of potential fuel sources, developing a feed system design capable of providing a fuel at 400 psig to the second stage of the E-Gas (Destec) gasifier to be cogasified with coal, performing bench- and pilot-scale testing to verify concepts and clarify decision-based options, reviewing information on high-pressure feed system designs, and determining the economics of cofeeding alternative feedstocks with the conceptual feed system design. A preliminary assessment of feedstock availability within Indiana and Illinois was conducted. Feedstocks evaluated included those with potential tipping fees to offset processing cost: sewage sludge, municipal solid waste, used railroad ties, urban wood waste (UWW), and used tires/tire-derived fuel. Agricultural residues and dedicated energy crop fuels were not considered since they would have a net positive cost to the plant. Based on the feedstock assessment, sewage sludge was selected as the primary feedstock for consideration at the Wabash River Plant. Because of the limited waste heat available for drying and

  17. Environmental aspects of alternative wet technologies for producing energy/fuel from peat. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Smith, R.T.

    1981-05-01

    Peat in situ contains up to 90% moisture, with about 50% of this moisture trapped as a colloidal gel. This colloidal moisture cannot be removed by conventional dewatering methods (filter presses, etc.) and must be removed by thermal drying, solvent extraction, or solar drying before the peat can be utilized as a fuel feedstock for direct combustion or gasification. To circumvent the drying problem, alternative technologies such as wet oxidation, wet carbonization, and biogasification are possible for producing energy or enhanced fuel from peat. This report describes these three alternative technologies, calculates material balances for given raw peat feed rates of 1000 tph, and evaluates the environmental consequences of all process effluent discharges. Wastewater discharges represent the most significant effluent due to the relatively large quantities of water removed during processing. Treated process water returned to the harvested bog may force in situ, acidic bog water into recieving streams, disrupting local aquatic ecosystems.

  18. Determinants of alternative fuel vehicle choice in the continental United States.

    Energy Technology Data Exchange (ETDEWEB)

    Tompkins, M.

    1997-12-18

    This paper describes the ongoing investigation into the determinants of alternative fuel vehicle choice. A stated preference vehicle choice survey was conducted for the 47 of the continental U.S. states, excluding California. The national survey is based on and is an extension of previous studies on alternative fuel vehicle choice for the State of California conducted by the University of California's Institute of Transportation Studies (UC ITS). Researchers at UC ITS have used the stated-preference national survey to produce a series of estimates for new vehicle choice models. Three of these models are presented in this paper. The first two of the models were estimated using only the data from the national survey. The third model presented in this paper pools information from the national and California surveys to estimate a true national model for new vehicle choice.

  19. New co-products from grain-based fuel ethanol production and their drying performance

    Science.gov (United States)

    Fuel ethanol production in the U.S. and elsewhere is an important and growing industry. In the U.S, about 40% of annual corn production is now converted into fuel ethanol. During co-product recovery, condensed distillers solubles (CDS) has to be mixed with distillers wet grains before drying due to ...

  20. EVermont Renewable Hydrogen Production and Transportation Fueling System

    Energy Technology Data Exchange (ETDEWEB)

    Garabedian, Harold T.

    2008-03-30

    A great deal of research funding is being devoted to the use of hydrogen for transportation fuel, particularly in the development of fuel cell vehicles. When this research bears fruit in the form of consumer-ready vehicles, will the fueling infrastructure be ready? Will the required fueling systems work in cold climates as well as they do in warm areas? Will we be sure that production of hydrogen as the energy carrier of choice for our transit system is the most energy efficient and environmentally friendly option? Will consumers understand this fuel and how to handle it? Those are questions addressed by the EVermont Wind to Wheels Hydrogen Project: Sustainable Transportation. The hydrogen fueling infrastructure consists of three primary subcomponents: a hydrogen generator (electrolyzer), a compression and storage system, and a dispenser. The generated fuel is then used to provide transportation as a motor fuel. EVermont Inc., started in 1993 by then governor Howard Dean, is a public-private partnership of entities interested in documenting and advancing the performance of advanced technology vehicles that are sustainable and less burdensome on the environment, especially in areas of cold climates, hilly terrain and with rural settlement patterns. EVermont has developed a demonstration wind powered hydrogen fuel producing filling system that uses electrolysis, compression to 5000 psi and a hydrogen burning vehicle that functions reliably in cold climates. And that fuel is then used to meet transportation needs in a hybrid electric vehicle whose internal combustion engine has been converted to operate on hydrogen Sponsored by the DOE EERE Hydrogen, Fuel Cells & Infrastructure Technologies (HFC&IT) Program, the purpose of the project is to test the viability of sustainably produced hydrogen for use as a transportation fuel in a cold climate with hilly terrain and rural settlement patterns. Specifically, the project addresses the challenge of building a renewable

  1. Cellulosic fuel ethanol: alternative fermentation process designs with wild-type and recombinant Zymomonas mobilis.

    Science.gov (United States)

    Lawford, Hugh G; Rousseau, Joyce D

    2003-01-01

    Iogen (Canada) is a major manufacturer of industrial cellulase and hemicellulase enzymes for the textile, pulp and paper, and poultry feed industries. Iogen has recently constructed a 40 t/d biomass-to-ethanol demonstration plant adjacent to its enzyme production facility. The integration of enzyme and ethanol plants results in significant reduction in production costs and offers an alternative use for the sugars generated during biomass conversion. Iogen has partnered with the University of Toronto to test the fermentation performance characteristics of metabolically engineered Zymomonas mobilis created at the National Renewable Energy Laboratory. This study focused on strain AX101, a xylose- and arabinose-fermenting stable genomic integrant that lacks the selection marker gene for antibiotic resistance. The "Iogen Process" for biomass depolymerization consists of a dilute-sulpfuric acid-catalyzed steam explosion, followed by enzymatic hydrolysis. This work examined two process design options for fermentation, first, continuous cofermentation of C5 and C6 sugars by Zm AX101, and second, separate continuous fermentations of prehydrolysate by Zm AX101 and cellulose hydrolysate by either wildtype Z. mobilis ZM4 or an industrial yeast commonly used in the production of fuel ethanol from corn. Iogen uses a proprietary process for conditioning the prehydrolysate to reduce the level of inhibitory acetic acid to at least 2.5 g/L. The pH was controlled at 5.5 and 5.0 for Zymomonas and yeast fermentations, respectively. Neither 2.5 g/L of acetic acid nor the presence of pentose sugars (C6:C5 = 2:1) appreciably affected the high-performance glucose fermentation of wild-type Z. mobilis ZM4. By contrast, 2.5 g/L of acetic acid significantly reduced the rate of pentose fermentation by strain AX101. For single-stage continuous fermentation of pure sugar synthetic cellulose hydrolysate (60 g/L of glucose), wild-type Zymomonas exhibited a four-fold higher volumetric productivity

  2. Airports offer unrealized potential for alternative energy production.

    Science.gov (United States)

    DeVault, Travis L; Belant, Jerrold L; Blackwell, Bradley F; Martin, James A; Schmidt, Jason A; Wes Burger, L; Patterson, James W

    2012-03-01

    Scaling up for alternative energy such as solar, wind, and biofuel raises a number of environmental issues, notably changes in land use and adverse effects on wildlife. Airports offer one of the few land uses where reductions in wildlife abundance and habitat quality are necessary and socially acceptable, due to risk of wildlife collisions with aircraft. There are several uncertainties and limitations to establishing alternative energy production at airports, such as ensuring these facilities do not create wildlife attractants or other hazards. However, with careful planning, locating alternative energy projects at airports could help mitigate many of the challenges currently facing policy makers, developers, and conservationists.

  3. Characteristics of Waste Plastics Pyrolytic Oil and Its Applications as Alternative Fuel on Four Cylinder Diesel Engines

    Directory of Open Access Journals (Sweden)

    Nosal Nugroho Pratama

    2014-02-01

    Full Text Available Waste plastics recycling using pyrolysis method is not only able to decrease a number of environment pollutant but also able to produce economical and high quality hydrocarbon products. Two experiments were conducted to completely study Waste Plastic Pyrolytic Oil (WPPO characteristics and its applications.  First experiment investigated oil characteristics derived from pyrolysis process in two stages batch reactors: pyrolysis and catalytic reforming reactor, at maximum temperature 500oC and 450oC respectively. Waste Polyethylene (PE, Polypropylene (PP, Polystyrene (PS, Polyethylene Terepthalate (PET and others were used as raw material. Nitrogen flow rate at 0.8 l/minutes was used to increase oil weight percentage. Indonesian natural zeolite was used as catalyst. Then, second experiment was carried out on Diesel Engine Test Bed (DETB used blending of WPPO and Biodiesel fuel with a volume ratio of 1:9. This experiment was specifically conducted to study how much potency of blending of WPPO and biodiesel in diesel engine. The result of first experiment showed that the highest weight percentage of WPPO derived from mixture of PE waste (50%wt, PP waste (40%wt and PS waste (10%wt is 45.13%wt. The more weight percentage of PE in feedstock effected on the less weight percentage of WPPO, the more percentage of C12-C20 content in WPPO and the higher calorific value of WPPO. Characteristics of WPPO such as, Specific Gravity, Flash point, Pour Point, Kinematic Viscosity, Calorific value and percentage of C12-C20 showed interesting result that WPPO could be developed as alternative fuel on diesel fuel blending due to the proximity of their characteristics. Performance of diesel engine using blending of WPPO and biodiesel on second experiment gave good result so the WPPO will have great potency to be valuable alternative liquid fuel in future, especially on stationary diesel engine and transportation engine application.

  4. Applying fuel cell experience to sustainable power products

    Science.gov (United States)

    King, Joseph M.; O'Day, Michael J.

    Fuel cell power plants have demonstrated high efficiency, environmental friendliness, excellent transient response, and superior reliability and durability in spacecraft and stationary applications. Broader application of fuel cell technology promises significant contribution to sustainable global economic growth, but requires improvement to size, cost, fuel flexibility and operating flexibility. International Fuel Cells (IFC) is applying lessons learned from delivery of more than 425 fuel cell power plants and 3 million h of operation to the development of product technology which captures that promise. Key findings at the fuel cell power plant level include: (1) ancillary components account for more than 40% of the weight and nearly all unscheduled outages of hydrocarbon-fuelled power plants; a higher level of integration and simplification is required to achieve reasonable characteristics, (2) hydrocarbon fuel cell power plant components are highly interactive; the fuel processing approach and power plant operating pressure are major determinants of overall efficiency, and (3) achieving the durability required for heavy duty vehicles and stationary applications requires simultaneous satisfaction of electrochemical, materials and mechanical considerations in the design of the cell stack and other power plant components. Practical designs must minimize application specific equipment. Related lessons for stationary fuel cell power plants include: (1) within fuel specification limits, natural gas varies widely in heating value, minor constituents such as oxygen and nitrogen content and trace compounds such as the odorant; (2) city water quality varies widely; recovery of product water for process use avoids costly, complicated and site-specific water treatment systems, but water treatment is required to eliminate impurities and (3) the embedded protection functions for reliable operation of fuel cell power conditioners meet or exceed those required for connection to

  5. PRODUCTION OF NEW BIOMASS/WASTE-CONTAINING SOLID FUELS

    Energy Technology Data Exchange (ETDEWEB)

    David J. Akers; Glenn A. Shirey; Zalman Zitron; Charles Q. Maney

    2001-04-20

    CQ Inc. and its team members (ALSTOM Power Inc., Bliss Industries, McFadden Machine Company, and industry advisors from coal-burning utilities, equipment manufacturers, and the pellet fuels industry) addressed the objectives of the Department of Energy and industry to produce economical, new solid fuels from coal, biomass, and waste materials that reduce emissions from coal-fired boilers. This project builds on the team's commercial experience in composite fuels for energy production. The electric utility industry is interested in the use of biomass and wastes as fuel to reduce both emissions and fuel costs. In addition to these benefits, utilities also recognize the business advantage of consuming the waste byproducts of customers both to retain customers and to improve the public image of the industry. Unfortunately, biomass and waste byproducts can be troublesome fuels because of low bulk density, high moisture content, variable composition, handling and feeding problems, and inadequate information about combustion and emissions characteristics. Current methods of co-firing biomass and wastes either use a separate fuel receiving, storage, and boiler feed system, or mass burn the biomass by simply mixing it with coal on the storage pile. For biomass or biomass-containing composite fuels to be extensively used in the U.S., especially in the steam market, a lower cost method of producing these fuels must be developed that includes both moisture reduction and pelletization or agglomeration for necessary fuel density and ease of handling. Further, this method of fuel production must be applicable to a variety of combinations of biomass, wastes, and coal; economically competitive with current fuels; and provide environmental benefits compared with coal. Notable accomplishments from the work performed in Phase I of this project include the development of three standard fuel formulations from mixtures of coal fines, biomass, and waste materials that can be used in

  6. Acceptability of genetically modified cheese presented as real product alternative

    DEFF Research Database (Denmark)

    Lähteenmäki, Liisa; Grunert, Klaus G.; Ueland, Øydis

    2002-01-01

    alternatives. Consumers in Denmark, Finland, Norway and Sweden (n=738) assessed two cheeses: one was labelled as genetically modified (preferred in an earlier product test) and the other as conventional (neutral in an ealier product test). A smaller control group received two cheeses with blind codes......European consumers, in general, have negative attitudes towards the use of gene technology in food production. The objective of this study was to examine whether taste and health benefits influence the acceptability of genetically modified (gm) products when they are presented as real product...

  7. A Technical Review of Compressed Natural Gas as an Alternative Fuel for Internal Combustion Engines

    Directory of Open Access Journals (Sweden)

    Semin

    2008-01-01

    Full Text Available Natural gas is promising alternative fuel to meet strict engine emission regulations in many countries. Compressed natural gas (CNG has long been used in stationary engines, but the application of CNG as a transport engines fuel has been considerably advanced over the last decade by the development of lightweight high-pressure storage cylinders. Engine conversion technology is well established and suitable conversion equipment is readily available. For spark ignition engines there are two options, a bi-fuel conversion and use a dedicated to CNG engine. For compression ignition engines converted to run on natural gas, there are two main options discussed, there are dual-fuel engines and normal ignition can be initiated. Natural gas engines can operate at lean burn and stoichiometric conditions with different combustion and emission characteristics. In this paper, the CNG engines research and development fueled using CNG are highlighted to keep the output power, torque and emissions of natural gas engines comparable to their gasoline or diesel counterparts. The high activities for future CNG engines research and development to meet future CNG engines is recorded in the paper.

  8. A new alternating copolymerized derivative as a cold flow improver for diesel fuel

    Institute of Scientific and Technical Information of China (English)

    ZHANG Haikuan; LIU Hongyan; WANG Shujun

    2009-01-01

    Synthesis of a cold flow improver (MAVA-a) for diesel fuel and its effect on solidifying point (SP) and cold filter plugging point (CFPP) of diesel fuels were investigated. The cold flow improver was prepared by using maleic anhydride (MA) and vinyl acetate (VA) as raw materials, toluene as solvent, dibenzoyl peroxide (BPO) as initiator, through alternating polymerization under nitrogen to obtain a binary-polymer and then through aminolysis by using a higher carbon amine as aminating agent at a temperature of 80 ℃. A cold flow improver was designed and prepared for No. 0 diesel fuel from Zhang Jia-Gang Petrochemical Company according to the contents of n-paraffin and its carbon number distribution in the No. 0 diesel fuel. It was also used together with two kinds of ethene-vinyl acetate copolymer improvers (EVA) separately. The test result showed that the CFPP of the No.0 diesel fuel could be lowered by 3-5 ℃ when the improver MAVA-a was used.The CFPP was lowered by 8 ℃ when the improver MAVA-a was used together with EVA-2.

  9. Advanced laser processing in fuel cells production

    Energy Technology Data Exchange (ETDEWEB)

    Stollhof, J.; Havrilla, D.; Schaupp, R. [TRUMPF Inc., Plymouth, MI (United States); Loeffler, K. [TRUMPF Laser und Systemtechnik TLD, Ditzingen (Germany)

    2009-07-01

    This paper discussed TRUMPF methods of joining bipolar plates to create fuel cell stacks and manufacture thin foils using diode pumped solid state lasers (DPSSLs). Beam delivery systems and processing optics were discussed. CW disk lasers were used to allow spot diameters smaller than 30 {mu}m and combined with a Galvo technology-based scanning optics systems to enable welding speeds greater than 1 m/s. A TruFiber 300 diffraction limited fiber laser was used for CW laser cutting. Short and ultra-short laser pulses were used to drill thousands of holes per second without a measurable heat-affected zone. The attributes and specifications of the 3 major TRUMPF lasers developed to manufacture fuel cells were also provided.

  10. A comparison of estimates of cost-effectiveness of alternative fuels and vehicles for reducing emissions

    Energy Technology Data Exchange (ETDEWEB)

    Hadder, G.R.

    1995-11-01

    The cost-effectiveness ratio (CER) is a measure of the monetary value of resources expended to obtain reductions in emissions of air pollutants. The CER can lead to selection of the most effective sequence of pollution reduction options. Derived with different methodologies and technical assumptions, CER estimates for alternative fuel vehicles (AFVs) have varied widely among pervious studies. In one of several explanations of LCER differences, this report uses a consistent basis for fuel price to re-estimate CERs for AFVs in reduction of emissions of criteria pollutants, toxics, and greenhouse gases. The re-estimated CERs for a given fuel type have considerable differences due to non-fuel costs and emissions reductions, but the CERs do provide an ordinal sense of cost-effectiveness. The category with CER less than $5,000 per ton includes compressed natural gas and ed Petroleum gas vehicles; and E85 flexible-fueled vehicles (with fuel mixture of 85 percent cellulose-derived ethanol in gasoline). The E85 system would be much less attractive if corn-derived ethanol were used. The CER for E85 (corn-derived) is higher with higher values placed on the reduction of gas emissions. CER estimates are relative to conventional vehicles fueled with Phase 1 California reformulated gasoline (RFG). The California Phase 2 RFG program will be implemented before significant market penetration by AFVs. CERs could be substantially greater if they are calculated incremental to the Phase 2 RFG program. Regression analysis suggests that different assumptions across studies can sometimes have predictable effects on the CER estimate of a particular AFV type. The relative differences in cost and emissions reduction assumptions can be large, and the effect of these differences on the CER estimate is often not predictable. Decomposition of CERs suggests that methodological differences can make large contributions to CER differences among studies.

  11. Liquid fuels production from biomass. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Levy, P. F.; Sanderson, J. E.; Ashare, E.; Wise, D. L.; Molyneaux, M. S.

    1980-06-30

    The current program to convert biomass into liquid hydrocarbon fuels is an extension of a previous program to ferment marine algae to acetic acid. In that study it was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation broth by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids via Kolbe electrolysis to aliphatic hydrocarbons, which may be used as a diesel fuel. The specific goals for the current porgram are: (1) establish conditions under which substrates other than marine algae may be converted in good yield to organic acids, here the primary task is methane suppression; (2) modify the current 300-liter fixed packed bed batch fermenter to operate in a continuous mode; (3) change from membrane extraction of organic acids to liquid-liquid extraction; (4) optimize the energy balance of the electrolytic oxidation process, the primary task is to reduce the working potential required for the electrolysis while maintaining an adequate current density; (5) scale the entire process up to match the output of the 300 liter fermenter; and (6) design pilot plant and commercial size plant (1000 tons/day) processes for converting biomass to liquid hydrocarbon fuels and perform an economic analysis for the 1000 ton/day design.

  12. Multi-level multi-criteria analysis of alternative fuels for waste collection vehicles in the United States.

    Science.gov (United States)

    Maimoun, Mousa; Madani, Kaveh; Reinhart, Debra

    2016-04-15

    Historically, the U.S. waste collection fleet was dominated by diesel-fueled waste collection vehicles (WCVs); the growing need for sustainable waste collection has urged decision makers to incorporate economically efficient alternative fuels, while mitigating environmental impacts. The pros and cons of alternative fuels complicate the decisions making process, calling for a comprehensive study that assesses the multiple factors involved. Multi-criteria decision analysis (MCDA) methods allow decision makers to select the best alternatives with respect to selection criteria. In this study, two MCDA methods, Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) and Simple Additive Weighting (SAW), were used to rank fuel alternatives for the U.S. waste collection industry with respect to a multi-level environmental and financial decision matrix. The environmental criteria consisted of life-cycle emissions, tail-pipe emissions, water footprint (WFP), and power density, while the financial criteria comprised of vehicle cost, fuel price, fuel price stability, and fueling station availability. The overall analysis showed that conventional diesel is still the best option, followed by hydraulic-hybrid WCVs, landfill gas (LFG) sourced natural gas, fossil natural gas, and biodiesel. The elimination of the WFP and power density criteria from the environmental criteria ranked biodiesel 100 (BD100) as an environmentally better alternative compared to other fossil fuels (diesel and natural gas). This result showed that considering the WFP and power density as environmental criteria can make a difference in the decision process. The elimination of the fueling station and fuel price stability criteria from the decision matrix ranked fossil natural gas second after LFG-sourced natural gas. This scenario was found to represent the status quo of the waste collection industry. A sensitivity analysis for the status quo scenario showed the overall ranking of diesel and

  13. Biodiesel production by biocatalysis using alternative method for lipase immobilization in hydrogel

    Directory of Open Access Journals (Sweden)

    Fernanda Marder

    2009-03-01

    Full Text Available The society has been looking for alternatives in order to stop the process of environmental destruction installed in the world, however, starting from last century, a new vision on the indiscriminate use of the environmental resources started to be discussed leading to the use of new technologies of production of cleaner fuel, as the biodiesel, produced from vegetable oils. The enzymatic processes are a production alternative, for they are methods with losses reduction and larger efficiency, presenting however, high production cost. With the objective of reducing costs and increasing the efficiency we have searched the enzymes immobilization through alternative method and to use them as biocatalysts in the biodiesel production. The immobilization of the lipase PS Amano was accomplished in spheres formed by the hydration of commercial hydrogel in aqueous solution containing the enzyme. With the immobilized enzyme it was accomplished the transesterification, in which it was obtained conversions in methyl esters of up to 70%, in organic solvent, with 24h, 55°C, 100 rpm and 40 hydrogel spheres with immobilized enzyme. The method comes as a promising alternative technology for the biodiesel obtaining.

  14. Formate Formation and Formate Conversion in Biological Fuels Production

    Directory of Open Access Journals (Sweden)

    Bryan R. Crable

    2011-01-01

    Full Text Available Biomethanation is a mature technology for fuel production. Fourth generation biofuels research will focus on sequestering CO2 and providing carbon-neutral or carbon-negative strategies to cope with dwindling fossil fuel supplies and environmental impact. Formate is an important intermediate in the methanogenic breakdown of complex organic material and serves as an important precursor for biological fuels production in the form of methane, hydrogen, and potentially methanol. Formate is produced by either CoA-dependent cleavage of pyruvate or enzymatic reduction of CO2 in an NADH- or ferredoxin-dependent manner. Formate is consumed through oxidation to CO2 and H2 or can be further reduced via the Wood-Ljungdahl pathway for carbon fixation or industrially for the production of methanol. Here, we review the enzymes involved in the interconversion of formate and discuss potential applications for biofuels production.

  15. Management of radioactive waste gases from the nuclear fuel cycle. Volume I. Comparison of alternatives

    Energy Technology Data Exchange (ETDEWEB)

    Evans, A.G.; Prout, W.E.; Buckner, J.T.; Buckner, M.R.

    1980-12-01

    Alternatives were compared for collection and fixation of radioactive waste gases released during normal operation of the nuclear fuel cycle, and for transportation and storage/disposal of the resulting waste forms. The study used a numerical rating scheme to evaluate and compare the alternatives for krypton-85, iodine-129, and carbon-14; whereas a subjective evaluation, based on published reports and engineering judgement, was made for transportation and storage/disposal options. Based on these evaluations, certain alternatives are recommended for an integrated scheme for waste management of each of the subject waste gases. Phase II of this project, which is concerned with the development of performance criteria for the waste forms associated with the subject gases, will be completed by the end of 1980. This work will be documented as Volume II of this report.

  16. Hydrogen production econometric studies. [hydrogen and fossil fuels

    Science.gov (United States)

    Howell, J. R.; Bannerot, R. B.

    1975-01-01

    The current assessments of fossil fuel resources in the United States were examined, and predictions of the maximum and minimum lifetimes of recoverable resources according to these assessments are presented. In addition, current rates of production in quads/year for the fossil fuels were determined from the literature. Where possible, costs of energy, location of reserves, and remaining time before these reserves are exhausted are given. Limitations that appear to hinder complete development of each energy source are outlined.

  17. A Preliminary Study on the Conceptual Design of Thorium/Uranium Mixed Nuclear Fuel for the Alternative of Burnable Poison in Commercial Pressurized Water Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dong Hwan; Kim, Song Hyun; Kim, Jong Kyung [Hanyang Univ., Seoul (Korea, Republic of)

    2013-10-15

    Thorium has higher neutron absorption cross section than that of U-238. Thus, the thorium mixed uranium oxide nuclear fuel can reduce the initial excessive reactivity and the long-live radio-wastes with increasing the fuel utilization efficiency. In this study, a preliminary study on the application of the thorium/uranium mixed fuel is performed for the alternative of the PLUS7 fuel assembly which includes burnable poison. A conceptual design without geometrical change is proposed and the reactor characteristics are analyzed. In this study, a fuel assembly using the uranium/thorium mixed fuel was designed to substitute the assembly which includes burnable poison. The reactor characteristics, which are k{sub inf}, power distribution and plutonium production rate, were evaluated and the results are compared with the E1 assembly which is used in the OPR1000 reactor. The results show that the proposed design can efficiently reduce the excessive reactivity, peak power, and plutonium production with increasing the fuel utilization period.

  18. The economic production of alcohol fuels from coal-derived synthesis gas

    Energy Technology Data Exchange (ETDEWEB)

    Kugler, E.L.; Dadyburjor, D.B.; Yang, R.Y.K. [West Virginia Univ., Morgantown, WV (United States)] [and others

    1995-12-31

    The objectives of this project are to discover, (1) study and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas. Specifically, alternative methods of preparing catalysts are to be investigated, and novel catalysts, including sulfur-tolerant ones, are to be pursued. (Task 1); (2) explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. (Task 1); (3) simulate by computer the most energy efficient and economically efficient process for converting coal to energy, with primary focus on converting syngas to fuel alcohols. (Task 2); (4) develop on the bench scale the best holistic combination of chemistry, catalyst, reactor and total process configuration integrated with the overall coal conversion process to achieve economic optimization for the conversion of syngas to liquid products within the framework of achieving the maximum cost effective transformation of coal to energy equivalents. (Tasks 1 and 2); and (5) evaluate the combustion, emission and performance characteristics of fuel alcohols and blends of alcohols with petroleum-based fuels. (Task 2)

  19. Artificial photosynthesis for production of hydrogen peroxide and its fuel cells.

    Science.gov (United States)

    Fukuzumi, Shunichi

    2016-05-01

    The reducing power released from photosystem I (PSI) via ferredoxin enables the reduction of NADP(+) to NADPH, which is essential in the Calvin-Benson cycle to make sugars in photosynthesis. Alternatively, PSI can reduce O2 to produce hydrogen peroxide as a fuel. This article describes the artificial version of the photocatalytic production of hydrogen peroxide from water and O2 using solar energy. Hydrogen peroxide is used as a fuel in hydrogen peroxide fuel cells to make electricity. The combination of the photocatalytic H2O2 production from water and O2 using solar energy with one-compartment H2O2 fuel cells provides on-site production and usage of H2O2 as a more useful and promising solar fuel than hydrogen. This article is part of a Special Issue entitled Biodesign for Bioenergetics--The design and engineering of electronc transfer cofactors, proteins and protein networks, edited by Ronald L. Koder and J.L. Ross Anderson.

  20. Study of Gasohol as Alternative Fuel for Gasoline Substitution: Characteristics and Performances

    Directory of Open Access Journals (Sweden)

    Bardi Murachman

    2014-12-01

    Full Text Available Gasohol is a mixture of premium petrol (gasoline with alcohol, in this case ethanol. The use of gasohol can reduce fuel consumption without having to modify the existing engine. Therefore, this research is conducted to study the characteristics and performance of gasohol in various mixing ratios, which includes analysis of physical properties and the use of gasohol in the machine. Results show that the addition of technical ethanol at 7.0169%v increases the value of gasohol vapor pressure on the value of 8.6682 psi (7.7 psi for regular gasoline. Gasohol with technical ethanol content above 30%v decreases vapor pressure, promotes phase separation, and causes a sharp drop in temperature from 40%v distillation. In term of corrosivity, gasohol with up to 50%v ethanol content has the same corrosion level with regular gasoline, which is corrosion level 1A. Based on gasohol characteristics test, it is known that gasohol with technical ethanol content below 20%v can be used as a fuel substitute for gasoline. Real-time performance test of gasohol in engines has shown that the addition of ethanol content in gasohol tend to increase the engine power at a certain compression ratio, but it also increases fuel consumption because the heat value of ethanol is lower than gasoline. Machine in gasohol with ethanol content below 20%v can operate smoothly without having to modify the engine. Based on the studies that have been done, gasohol in the range of 10%v ethanol content is well-functioned as a substitute for gasoline fuel and meets fuel specifications required by the General Director of Oil and Gas. The feasibility of using gasohol as an alternative fuel can be studied further.

  1. Determination of the Emissions from an Aircraft Auxiliary Power Unit (APU) during the Alternative Aviation Fuel Experiment (AAFEX)

    Science.gov (United States)

    The emissions from a Garrett-AiResearch (now Honeywell) Model GTCP85-98CK APU were determined as part of the National Aeronautics and Space Administration's (NASA's) Alternative Aviation Fuels Experiment using both JP-8 and a coal-derived Fischer Tropsch fuel (FT-2). Measurements...

  2. Sustainable Production of Asphalt using Biomass as Primary Process Fuel

    DEFF Research Database (Denmark)

    Bühler, Fabian; Nguyen, Tuong-Van; Elmegaard, Brian

    2016-01-01

    The production of construction materials is very energy intensive and requires large quantities of fossil fuels.Asphalt is the major road paving material in Europe and is being produced primarily in stationary batch mixasphalt factories. The production process requiring the most energy...... is the heating and drying of aggregate,where natural gas, fuel oil or LPG is burned in a direct-fired rotary dryer. Replacing this energy source with amore sustainable one presents several technical and economic challenges, as high temperatures, short startuptimes and seasonal production variations are required....... This paper analyses different pathways for the useof biomass feedstock as a primary process fuel. The analysed cases consider the gasification of straw andwood chips and the direct combustion of wood pellets. The additional use of syngas from the gasifier for theproduction of heat or combined heat and power...

  3. Volatile organic compounds (VOCs) in surface coating materials: Their compositions and potential as an alternative fuel.

    Science.gov (United States)

    Dinh, Trieu-Vuong; Choi, In-Young; Son, Youn-Suk; Song, Kyu-Yong; Sunwoo, Young; Kim, Jo-Chun

    2016-03-01

    A sampling system was designed to determine the composition ratios of VOCs emitted from 31 surface coating materials (SCMs). Representative architectural, automotive, and marine SCMs in Korea were investigated. Toluene, ethylbenzene, and xylene were the predominant VOCs. The VOC levels (wt%) from automotive SCMs were significantly higher than those from architectural and marine paints. It was found that target SCMs comprised mainly VOCs with 6-10 carbon atoms in molecules, which could be adsorbed by activated carbon. The saturated activated carbon which had already adsorbed toluene, ethylbenzene, and m-xylene was combusted. The saturated activated carbon was more combustible than new activated carbon because it comprised inflammable VOCs. Therefore, it could be an alternative fuel when using in a "fuelization system". To use the activated carbon as a fuel, a control technology of VOCs from a coating process was also designed and introduced.

  4. Fission-product SiC reaction in HTGR fuel

    Energy Technology Data Exchange (ETDEWEB)

    Montgomery, F.

    1981-07-13

    The primary barrier to release of fission product from any of the fuel types into the primary circuit of the HTGR are the coatings on the fuel particles. Both pyrolytic carbon and silicon carbide coatings are very effective in retaining fission gases under normal operating conditions. One of the possible performance limitations which has been observed in irradiation tests of TRISO fuel is chemical interaction of the SiC layer with fission products. This reaction reduces the thickness of the SiC layer in TRISO particles and can lead to release of fission products from the particles if the SiC layer is completely penetrated. The experimental section of this report describes the results of work at General Atomic concerning the reaction of fission products with silicon carbide. The discussion section describes data obtained by various laboratories and includes (1) a description of the fission products which have been found to react with SiC; (2) a description of the kinetics of silicon carbide thinning caused by fission product reaction during out-of-pile thermal gradient heating and the application of these kinetics to in-pile irradiation; and (3) a comparison of silicon carbide thinning in LEU and HEU fuels.

  5. Direct production of fractionated and upgraded hydrocarbon fuels from biomass

    Science.gov (United States)

    Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

    2014-08-26

    Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

  6. Emulsification of waste cooking oils and fatty acid distillates as diesel engine fuels: An attractive alternative

    Directory of Open Access Journals (Sweden)

    Eliezer Ahmed Melo Espinosa

    2016-06-01

    Full Text Available The scope of this paper is to analyze the possibility and feasibility of the use of emulsification method applied to waste cooking oils and fatty acid distillates as diesel engine fuels, compared with other commonly used methods. These waste products are obtained from the refining oil industry, food industry and service sector, mainly. They are rarely used as feedstock to produce biofuels and other things, in spite of constitute a potential source of environmental contamination. From the review of the state of arts, significant decreases in exhaust emissions of nitrogen oxides, cylinder pressure as well as increases of the ignition delay, brake specific fuel consumption, hydrocarbon, smoke opacity, carbon monoxide, particulate matters to emulsified waste cooking oils and fatty acid distillates compared with diesel fuel are reported. In some experiments the emulsified waste cooking oils achieved better performance than neat fatty acid distillates, neat waste cooking oils and their derivatives methyl esters.

  7. Technical and Economic Evaluation of Macroalgae Cultivation for Fuel Production (Draft)

    Energy Technology Data Exchange (ETDEWEB)

    Feinberg, D. A.; Hock, S. M.

    1985-04-01

    The potential of macroalgae as sources of renewable liquid and gaseous fuels is evaluated. A series of options for production of macroalgae feedstock is considered. Because of their high carbohydrate content, the fuel products for which macroalgae are most suitable are methane and ethanol. Fuel product costs were compared with projected fuel costs in the year 1995.

  8. Preferences for Alternative Fuel Vehicles of Lease Car Drivers in The Netherlands

    Energy Technology Data Exchange (ETDEWEB)

    Koetse, M.J.; Hoen, A.

    2012-04-15

    In this paper we aim to get insight into preferences of Dutch lease car drivers for alternative fuel vehicles (AFVs) and their characteristics. Since AFVs are either not yet available on the market or have only very limited market shares, we have to rely on stated preference research. We perform a state-of-the-art conjoint analysis, based on data obtained through an online choice experiment among Dutch lease car drivers. Results show that under current tax regulations the average lease car driver is indifferent between the conventional technology, flexifuel and the hybrid car, while negative preferences exist for the plug-in hybrid, the electric and the fuel cell car. When current tax regulations would be abolished, strong negative preferences would result for all AFCs, and especially for the electric and fuel cell car. Increases in driving range, reductions in refuelling time, and reductions in additional detour time for reaching an appropriate fuel station, increase AFV preferences substantially. On average the gap between conventional technologies and AFVs remains large, however. We also find that there is considerable heterogeneity in preferences of lease car drivers, and that various market segments and potential early adopters can be identified. In this respect the most interesting finding is that preferences for electric and fuel cell cars decrease substantially, and willingness to pay for driving range increases substantially, when annual mileage increases. Annual mileage also has a substantial impact on sensitivity to monthly costs. We therefore use simulations to assess market shares of electric and fuel cell cars for different annual mileage categories. We find that people with a relatively low annual mileage are more likely to adopt than people with a relatively high annual mileage, regardless of driving range and monthly costs. For the fuel cell car we find similar results, although when driving range is high and cost differences are large, lease car

  9. Ignition of Metal Powders in Combustion Products of Model Fuel

    Science.gov (United States)

    1974-11-13

    y AD/A-001 172 IGNITION OF METAL POWDERS IN COMBUSTION PRODUCTS OF MODEL FUEL A. K. Klyauzov, et al Foreign Technology...S. Air Force UNCLASSIFIED »b. s»ouc » "I»0«T TITLE IGNITION OF METAL POWDERS IN COMBUSTION PRODUCTS OF MODEL FUEL f* OCJCPIPTIVK NOTKI (Typ* o...report mnd Inclumiv «**»••) Translation S »UTMö«I|I ( Firn tSSS», rnlddl* Inltlml, faar .tarna; A. K. Klyauzov, M. M. Arsh, et al 6

  10. Fuel-cycle assessment of selected bioethanol production.

    Energy Technology Data Exchange (ETDEWEB)

    Wu, M.; Wang, M.; Hong, H.; Energy Systems

    2007-01-31

    A large amount of corn stover is available in the U.S. corn belt for the potential production of cellulosic bioethanol when the production technology becomes commercially ready. In fact, because corn stover is already available, it could serve as a starting point for producing cellulosic ethanol as a transportation fuel to help reduce the nation's demand for petroleum oil. Using the data available on the collection and transportation of corn stover and on the production of cellulosic ethanol, we have added the corn stover-to-ethanol pathway in the GREET model, a fuel-cycle model developed at Argonne National Laboratory. We then analyzed the life-cycle energy use and emission impacts of corn stover-derived fuel ethanol for use as E85 in flexible fuel vehicles (FFVs). The analysis included fertilizer manufacturing, corn farming, farming machinery manufacturing, stover collection and transportation, ethanol production, ethanol transportation, and ethanol use in light-duty vehicles (LDVs). Energy consumption of petroleum oil and fossil energy, emissions of greenhouse gases (carbon dioxide [CO{sub 2}], nitrous oxide [N{sub 2}O], and methane [CH{sub 4}]), and emissions of criteria pollutants (carbon monoxide [CO], volatile organic compounds [VOCs], nitrogen oxide [NO{sub x}], sulfur oxide [SO{sub x}], and particulate matter with diameters smaller than 10 micrometers [PM{sub 10}]) during the fuel cycle were estimated. Scenarios of ethanol from corn grain, corn stover, and other cellulosic feedstocks were then compared with petroleum reformulated gasoline (RFG). Results showed that FFVs fueled with corn stover ethanol blends offer substantial energy savings (94-95%) relative to those fueled with RFG. For each Btu of corn stover ethanol produced and used, 0.09 Btu of fossil fuel is required. The cellulosic ethanol pathway avoids 86-89% of greenhouse gas emissions. Unlike the life cycle of corn grain-based ethanol, in which the ethanol plant consumes most of the fossil

  11. Use of citric acid esters as alternative fuel for diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Huber, Georg; Thuneke, Klaus; Remmele, Edgar [Technologie- und Foerderzentrum, Straubing (Germany); Schieder, Doris [Technische Univ. Muenchen, Straubing (Germany). Lehrstuhl fuer Chemie Biogener Rohstoffe

    2013-06-01

    Common fuels for (adapted) diesel engines are fossil diesel fuel, fatty acid methyl ester (FAME or biodiesel) or vegetable oils. Furthermore the citric acid esters tributylcitrate (TBC) and triethylcitrate (TEC) are expected to be a possible diesel substitute. Their use as fuel was applied for a patent in Germany in 2010. According to the patent applicant the advantages are low soot combustion, independence of energy imports due to the possibility of local production and a broad raw material base. Their fuel properties have been analysed in the laboratory and compared with the relevant fuel standards. Only some of the determined values are meeting the specifications, but on the other hand few rapeseed oil characteristics (e. g. oxidation stability and viscosity) can be improved if the citric acid esters are used as a blend component. The operating and emission behaviour of a vegetable oil compatible CHP unit fuelled with various rapeseed oil and TBC blends were investigated and a trouble free and soot emission reduced engine operation due to the high molecularly bound oxygen content was observed. Long term test runs are necessary for an entire technical validation. (orig.)

  12. Alternatives for managing wastes from reactors and post-fission operations in the LWR fuel cycle. Volume 2. Alternatives for waste treatment

    Energy Technology Data Exchange (ETDEWEB)

    1976-05-01

    Volume II of the five-volume report is devoted to the description of alternatives for waste treatment. The discussion is presented under the following section titles: fuel reprocessing modifications; high-level liquid waste solidification; treatment and immobilization of chop-leach fuel bundle residues; treatment of noncombustible solid wastes; treatment of combustible wastes; treatment of non-high-level liquid wastes; recovery of transuranics from non-high-level wastes; immobilization of miscellaneous non-high-level wastes; volatile radioisotope recovery and off-gas treatment; immobilization of volatile radioisotopes; retired facilities (decontamination and decommissioning); and, modification and use of selected fuel reprocessing wastes. (JGB)

  13. Combustion instability and active control: Alternative fuels, augmentors, and modeling heat release

    Science.gov (United States)

    Park, Sammy Ace

    Experimental and analytical studies were conducted to explore thermo-acoustic coupling during the onset of combustion instability in various air-breathing combustor configurations. These include a laboratory-scale 200-kW dump combustor and a 100-kW augmentor featuring a v-gutter flame holder. They were used to simulate main combustion chambers and afterburners in aero engines, respectively. The three primary themes of this work includes: 1) modeling heat release fluctuations for stability analysis, 2) conducting active combustion control with alternative fuels, and 3) demonstrating practical active control for augmentor instability suppression. The phenomenon of combustion instabilities remains an unsolved problem in propulsion engines, mainly because of the difficulty in predicting the fluctuating component of heat release without extensive testing. A hybrid model was developed to describe both the temporal and spatial variations in dynamic heat release, using a separation of variables approach that requires only a limited amount of experimental data. The use of sinusoidal basis functions further reduced the amount of data required. When the mean heat release behavior is known, the only experimental data needed for detailed stability analysis is one instantaneous picture of heat release at the peak pressure phase. This model was successfully tested in the dump combustor experiments, reproducing the correct sign of the overall Rayleigh index as well as the remarkably accurate spatial distribution pattern of fluctuating heat release. Active combustion control was explored for fuel-flexible combustor operation using twelve different jet fuels including bio-synthetic and Fischer-Tropsch types. Analysis done using an actuated spray combustion model revealed that the combustion response times of these fuels were similar. Combined with experimental spray characterizations, this suggested that controller performance should remain effective with various alternative fuels

  14. A Study of Pollutant Formation from the Lean Premixed Combustion of Gaseous Fuel Alternatives to Natural Gas

    Science.gov (United States)

    Fackler, Keith Boyd, Jr.

    The goal of this research is to identify how nitrogen oxide (NO x) emissions and flame stability (blowout) are impacted by the use of fuels that are alternatives to typical pipeline natural gas. The research focuses on lean, premixed combustors that are typically used in state-of-the-art natural gas fueled systems. An idealized laboratory lean premixed combustor, specifically the jet-stirred reactor, is used for experimental data. A series of models, including those featuring detailed fluid dynamics and those focusing on detailed chemistry, are used to interpret the data and understand the underlying chemical kinetic reasons for differences in emissions between the various fuel blends. An ultimate goal is to use these data and interpretive tools to develop a way to predict the emission and stability impacts of changing fuels within practical combustors. All experimental results are obtained from a high intensity, single-jet stirred reactor (JSR). Five fuel categories are studied: (1) pure H 2, (2) process and refinery gas, including combinations of H2, CH4, C2H6, and C3H8, (3) oxygen blown gasified coal/petcoke composed of H2, CO, and CO2, (4) landfill and digester gas composed of CH4, CO2, and N2, and (5) liquified natural gas (LNG)/shale/associated gases composed of CH4, C2H6, and C3 H8. NOx measurements are taken at a nominal combustion temperature of 1800 K, atmospheric pressure, and a reactor residence time of 3 ms. This is done to focus the results on differences caused by fuel chemistry by comparing all fuels at a common temperature, pressure, and residence time. This is one of the few studies in the literature that attempts to remove these effects when studying fuels varying in composition. Additionally, the effects of changing temperature and residence time are investigated for selected fuels. At the nominal temperature and residence time, the experimental and modeling results show the following trends for NOx emissions as a function of fuel type: 1.) NOx

  15. The new gold rush: fueling ethanol production while protecting water quality.

    Science.gov (United States)

    Simpson, Thomas W; Sharpley, Andrew N; Howarth, Robert W; Paerl, Hans W; Mankin, Kyle R

    2008-01-01

    Renewable fuel production, particularly grain-based ethanol, is expanding rapidly in the USA. Although subsidized grain-based ethanol may provide a competitively priced transportation fuel, concerns exist about potential environmental impacts. This contribution focuses on potential water quality implications of expanded grain-based ethanol production and potential impacts of perennial-grass-based cellulosic ethanol. Expanded grain-based ethanol will increase and intensify corn production. Even with recommended fertilizer and land conservation measures, corn acreage can be a major source of N loss to water (20-40 kg ha(-1) yr(-1)). A greater acreage of corn is estimated to increase N and P loss to water by 37% (117 million kg) and 25% (9 million kg), respectively, and measures to encourage adoption of conservation practices are essential to mitigate water quality impairments. Dried distiller's grains remaining after ethanol production from corn grain are used as animal feed and can increase manure P content and may increase N content. Cellulosic fuel-stocks from perennials such as switchgrass and woody materials have the potential to produce ethanol. Although production, storage, and handling of cellulosic materials and conversion technology are limitations, accelerating development of cellulosic ethanol has the potential to reduce dependence on grain fuel-stocks and provide water quality and other environmental benefits. All alternative fuel production technologies could have environmental impacts. There is a need to understand these impacts to help guide policy and help make programmatic and scientific decisions that avoid or mitigate unintended environmental consequences of biofuel production.

  16. Metabolic engineering for the production of hydrocarbon fuels.

    Science.gov (United States)

    Lee, Sang Yup; Kim, Hye Mi; Cheon, Seungwoo

    2015-06-01

    Biofuels have been attracting increasing attention to provide a solution to the problems of climate change and our dependence on limited fossil oil. During the last decade, metabolic engineering has been performed to develop superior microorganisms for the production of so called advanced biofuels. Among the advanced biofuels, hydrocarbons possess high-energy content and superior fuel properties to other biofuels, and thus have recently been attracting much research interest. Here we review the recent advances in the microbial production of hydrocarbon fuels together with the metabolic engineering strategies employed to develop their production strains. Strategies employed for the production of long-chain and short-chain hydrocarbons derived from fatty acid metabolism along with the isoprenoid-derived hydrocarbons are reviewed. Also, the current limitations and future prospects in hydrocarbon-based biofuel production are discussed.

  17. Microalgae: a new alternative raw material for biodiesel production

    Energy Technology Data Exchange (ETDEWEB)

    Gouveia, L.; Rosa, F. [Instituto Nacional de Engenharia, Tecnologia e Inovacao -INETI-DER- Unidade Biomassa. Estrada do Paco do Lumiar, 1649-038 Lisboa (Portugal); Melo, A. [Faculdade de Ciencias, Universidade de Lisboa, 1749-016 Lisboa (Portugal); Medeiros, R. [Universidade Lusofona de Humanidades e Tecnologias, Campo Grande, n. 376, Lisboa (Portugal); Oliveira, A. [Extensao da Escola Superior de Biotecnologia em Caldas da Rainha, Universidade Catolica Portuguesa, Rua Mestre Mateus Fernandes, 2500-237 Caldas da Rainha (Portugal)

    2008-07-01

    Biofuels will play an increasingly important role in diversifying energy supplies to meet the world's growing energy needs. Algae are considered a promising potential feedstock for next-generation biofuels because certain species contain high amounts of oil, which could be extracted, processed and refined into transportation fuels using currently available technology. Other benefits of algae as a potential feedstock are their abundance and fast growth rates. Key technical challenges include identifying the strains with the highest oil content and growth rates and developing cost-effective growing and harvesting methods. In this work, a microalgae screening in terms of oil quantity and composition were done in order to choose the best one as oil source for biodiesel production. Oil extraction procedure was optimized and the oil obtained from each microalgae analyzed in terms of fatty acid profile and of some parameters that can influenced the biodiesel production process and the final product quality.

  18. Recent developments in the production of liquid fuels via catalytic conversion of microalgae: experiments and simulations

    Energy Technology Data Exchange (ETDEWEB)

    Shi, Fan; Wang, Pin; Duan, Yuhua; Link, Dirk; Morreale, Bryan

    2012-01-01

    Due to continuing high demand, depletion of non-renewable resources and increasing concerns about climate change, the use of fossil fuel-derived transportation fuels faces relentless challenges both from a world markets and an environmental perspective. The production of renewable transportation fuel from microalgae continues to attract much attention because of its potential for fast growth rates, high oil content, ability to grow in unconventional scenarios, and inherent carbon neutrality. Moreover, the use of microalgae would minimize ‘‘food versus fuel’’ concerns associated with several biomass strategies, as microalgae do not compete with food crops in the food chain. This paper reviews the progress of recent research on the production of transportation fuels via homogeneous and heterogeneous catalytic conversions of microalgae. This review also describes the development of tools that may allow for a more fundamental understanding of catalyst selection and conversion processes using computational modelling. The catalytic conversion reaction pathways that have been investigated are fully discussed based on both experimental and theoretical approaches. Finally, this work makes several projections for the potential of various thermocatalytic pathways to produce alternative transportation fuels from algae, and identifies key areas where the authors feel that computational modelling should be directed to elucidate key information to optimize the process.

  19. Coal from the waste disposal site of the Siersza mine (Trzebinia, Poland and its properties as a possible alternative fuel

    Directory of Open Access Journals (Sweden)

    Kosa Beata

    2016-01-01

    Full Text Available The authors recovered bituminous coal from the dump of the closed down Siersza mine in Trzebinia, determined its properties and evaluated a possibility of applying it as an alternative fuel for the cement industry. The dump material was enriched in a laboratory using the gravity (jigs, shaking tables and flotation methods of coal cleaning. The gross calorific value of the processing products, measured with a calorimetric bomb, ranges from 13.588 to 22.543 MJ·kg−1. The contents of heavy metals, determined with XRF, are as follows: Fe 3.76–5.25 mg·kg−1, Mn 0.037–0.132 mg·kg−1, Ti 0.325–0.493 mg·kg−1 and Zn 0.113–0.329 mg·kg−1, while of Hg (determined with ASA from 0.02689 to 0.21870 mg·kg−1. The content of sulphur is 0.7349–1.0484 wt.% and of chlorine Cl 0.131–0.135 wt.%, the net calorific value of 13.446–22.538 MJ·kg−1. The results indicate that the laboratory jigging and flotation provide products that meet the parameters of the solid fuels selected by applicable to the needs of cement plants.

  20. Alternative fuels and chemicals from synthesis gas. Quarterly status report number 2, 1 January--31 March 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit. Results are discussed for the following tasks: liquid phase hydrodynamic run; catalyst activation with CO; new processes for DME (dehydration catalyst screening runs, and experiments using Robinson-Mahoney basket internal and pelletized catalysts); new fuels from DME; and new processes for alcohols and oxygenated fuel additives.

  1. Assessment of costs and benefits of flexible and alternative fuel use in the U.S. transportation sector. Technical report fourteen: Market potential and impacts of alternative fuel use in light-duty vehicles -- A 2000/2010 analysis

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-01-01

    In this report, estimates are provided of the potential, by 2010, to displace conventional light-duty vehicle motor fuels with alternative fuels--compressed natural gas (CNG), liquefied petroleum gas (LPG), methanol from natural gas, ethanol from grain and from cellulosic feedstocks, and electricity--and with replacement fuels such as oxygenates added to gasoline. The 2010 estimates include the motor fuel displacement resulting both from government programs (including the Clean Air Act and EPACT) and from potential market forces. This report also provides an estimate of motor fuel displacement by replacement and alterative fuels in the year 2000. However, in contrast to the 2010 estimates, the year 2000 estimate is restricted to an accounting of the effects of existing programs and regulations. 27 figs., 108 tabs.

  2. Renewable hydrogen production for fossil fuel processing

    Energy Technology Data Exchange (ETDEWEB)

    Greenbaum, E.; Lee, J.W.; Tevault, C.V. [and others

    1995-06-01

    In the fundamental biological process of photosynthesis, atmospheric carbon dioxide is reduced to carbohydrate using water as the source of electrons with simultaneous evolution of molecular oxygen: H{sub 2}O + CO{sub 2} + light {yields} O{sub 2} + (CH{sub 2}O). It is well established that two light reactions, Photosystems I and II (PSI and PSII) working in series, are required to perform oxygenic photosynthesis. Experimental data supporting the two-light reaction model are based on the quantum requirement for complete photosynthesis, spectroscopy, and direct biochemical analysis. Some algae also have the capability to evolve molecular hydrogen in a reaction energized by the light reactions of photosynthesis. This process, now known as biophotolysis, can use water as the electron donor and lead to simultaneous evolution of molecular hydrogen and oxygen. In green algae, hydrogen evolution requires prior incubation under anaerobic conditions. Atmospheric oxygen inhibits hydrogen evolution and also represses the synthesis of hydrogenase enzyme. CO{sub 2} fixation competes with proton reduction for electrons relased from the photosystems. Interest in biophotolysis arises from both the questions that it raises concerning photosynthesis and its potential practical application as a process for converting solar energy to a non-carbon-based fuel. Prior data supported the requirement for both Photosystem I and Photosystem II in spanning the energy gap necessary for biophotolysis of water to oxygen and hydrogen. In this paper we report the at PSII alone is capable of driving sustained simultaneous photoevolution of molecular hydrogen and oxygen in an anaerobically adapted PSI-deficient strain of Chlamydomonas reinhardtii, mutant B4, and that CO{sub 2} competes as an electron acceptor.

  3. Jet Fuel Production from TAG and FAME

    Science.gov (United States)

    2010-12-01

    hydrotreating catalyst. A picture of the HDO reactor is shown in Figure 2. The HDO reactor products were hydrocarbons, carbon dioxide, carbon monoxide...reactor operated at elevated temperature and pressure and contained a fixed bed of commercial hydrotreating catalyst. A picture of the HDO reactor is

  4. Alternative Technologies for Biofuels Production in Kraft Pulp Mills—Potential and Prospects

    Directory of Open Access Journals (Sweden)

    Esa Vakkilainen

    2012-07-01

    Full Text Available The current global conditions provide the pulp mill new opportunities beyond the traditional production of cellulose. Due to stricter environmental regulations, volatility of oil price, energy policies and also the global competitiveness, the challenges for the pulp industry are many. They range from replacing fossil fuels with renewable energy sources to the export of biofuels, chemicals and biomaterials through the implementation of biorefineries. In spite of the enhanced maturity of various bio and thermo-chemical conversion processes, the economic viability becomes an impediment when considering the effective implementation on an industrial scale. In the case of kraft pulp mills, favorable conditions for biofuels production can be created due to the availability of wood residues and generation of black liquor. The objective of this article is to give an overview of the technologies related to the production of alternative biofuels in the kraft pulp mills and discuss their potential and prospects in the present and future scenario.

  5. Harnessing Solar Energy for the Production of Clean Fuel

    NARCIS (Netherlands)

    Pandit, A.; Holzwarth, A.; de Groot, H.J.M.

    2008-01-01

    The European Union and its member states are being urged by leading scientists to make a major multi million Euro commitment to solar driven production of environmentally clean electricity, hydrogen and other fuels, as the only sustainable long-term solution for global energy needs. The most promisi

  6. Antimicrobial peptides against contaminating bacteria in fuel ethanol production

    Science.gov (United States)

    Lactic acid bacteria (LAB) are commonly found as contaminants of fuel ethanol production, resulting in reduced ethanol yields (1). Recent reports suggest that LAB can develop resistance to antibiotics such as virginiamycin and penicillin that are commonly used to control bacterial contamination (2)...

  7. Fuel ethanol production from alkaline peroxide pretreated corn stover

    Science.gov (United States)

    Corn stover (CS) has the potential to serve as an abundant low-cost feedstock for production of fuel ethanol. Due to heterogeneous complexity and recalcitrance of lignocellulosic feedstocks, pretreatment is required to break the lignin seal and/or disrupt the structure of crystalline cellulose to in...

  8. 40 CFR 80.590 - What are the product transfer document requirements for motor vehicle diesel fuel, NRLM diesel...

    Science.gov (United States)

    2010-07-01

    ... requirements for motor vehicle diesel fuel, NRLM diesel fuel, heating oil, ECA marine fuel, and other... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive... the product transfer document requirements for motor vehicle diesel fuel, NRLM diesel fuel,...

  9. Alternative Fuel Implementation in a Cement Plant: Human Health Risks and Economical Valuation.

    Science.gov (United States)

    Rovira, Joaquim; Nadal, Martí; Schuhmacher, Marta; Domingo, José L

    2016-11-01

    In June 2010, the cement plant of Montcada i Reixac (MR) (Catalonia, Spain) began a gradual implementation of alternative fuel to replace fossil fuel. Between December 2010 and November 2014, we conducted three monitoring surveys to evaluate the state of the environment around the facility. Data were compared with results from three monitoring surveys performed in 2008-2009. In all these studies, samples of soil, vegetation, and air were collected, being the content of a number of trace elements and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in these matrices determined. In general terms, a decrease of metal and PCDD/F concentrations was found. Human health risks followed a similar temporal trend, being acceptable according to national and international standards and independent on the fuel used. The Disability-Adjusted Life Year and the costs of cancer cases were also estimated for the population living around the MR cement plant, accounting for 4 years and 31,000 €/year, respectively.

  10. Theoretical and experimental studies on combustion of alternative fuels in cement kilns

    Energy Technology Data Exchange (ETDEWEB)

    Axelsen, Ernst Petter

    2002-07-01

    In this thesis, the utilization of alternative fuels for NOx reduction by means of reburning and advanced reburning is considered. Laboratory experiments, full-scale experiments and computational fluid dynamic (CFD) simulations are the basis of the thesis. The goal of the work was to characterize alternative fuels used in cement kilns, with focus on the processes taking place in the precalciner of the cement kiln. To facilitate testing under controlled process conditions, a lab-scale circulating fluidized bed combustion (CFBC) reactor was designed and constructed. A co prehensive study on the fluidization regime in CFBC reactors and precalciners was required to ensure and verify that the operational regime in the CFBC reactor was similar to the regime in a precalciner. Different alternative fuels, such as refuse derived fuel, animal meal and solid hazardous waste, were tested in the CFBC reactor, which proved well suited for characterization of alternative fuels and investigations of NOx reduction, even though the operation of a CFBC reactor is quite complex and gives a certain variation in stability. Experiments with and without circulating mass in the CFBC reactor demonstrated the importance of executing the laboratory combustion experiments in an environment similar to that in the full-scale process, i.e. in the precalciner. Animal meal is believed to follow the reduction route of selective non-catalytic r duction or advanced reburning and to have a special capability of reducing NOx during increased NOx concentrations at the reactor inlet. The increased CO emissions during advanced reburning and reburning with animal meal are most likely to be due to the competition for the OH radical during oxidation of CO and of NH{sub 3}. Furthermore, it was shown, for all fuels, that an increased concentration of NOx at the reactor inlet increases the ratio of NOx at the exit and NOx supplied. Full-scale experiments were executed at Norcem's kiln 6 in Brevik, using

  11. An alternative solution for heavy liquid metal cooled reactors fuel assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Vitale Di Maio, Damiano, E-mail: damiano.vitaledimaio@uniroma1.it [“SAPIENZA” University of Rome – DIAEE, Corso Vittorio Emanuele II, 244, 00186 Rome (Italy); Cretara, Luca; Giannetti, Fabio [“SAPIENZA” University of Rome – DIAEE, Corso Vittorio Emanuele II, 244, 00186 Rome (Italy); Peluso, Vincenzo [“ENEA”, Via Martiri di Monte Sole 4, 40129 Bologna (Italy); Gandini, Augusto [“SAPIENZA” University of Rome – DIAEE, Corso Vittorio Emanuele II, 244, 00186 Rome (Italy); Manni, Fabio [“SRS Engineering Design S.r.l.”, Vicolo delle Palle 25-25/b, 00186 Rome (Italy); Caruso, Gianfranco [“SAPIENZA” University of Rome – DIAEE, Corso Vittorio Emanuele II, 244, 00186 Rome (Italy)

    2014-10-15

    Highlights: • A new fuel assembly locking system for heavy metal cooled reactor is proposed. • Neutronic, mechanical and thermal-hydraulic evaluations of the system behavior have been performed. • A comparison with other solutions has been presented. - Abstract: In the coming future, the electric energy production from nuclear power plants will be provided by both thermal reactors and fast reactors. In order to have a sustainable energy production through fission reactors, fast reactors should provide an increasing contribution to the total electricity production from nuclear power plants. Fast reactors have to achieve economic and technical targets of Generation IV. Among these reactors, Sodium cooled Fast Reactors (SFRs) and Lead cooled Fast Reactors (LFRs) have the greatest possibility to be developed as industrial power plants within few decades. Both SFRs and LFRs require a great R and D effort to overcome some open issues which affect the present designs (e.g. sodium-water reaction for the SFRs, erosion/corrosion for LFRs, etc.). The present paper is mainly focused on LFR fuel assembly (FA) design: issues linked with the high coolant density of lead or lead–bismuth eutectic cooled reactors have been investigated and an innovative solution for the core mechanical design is here proposed and analyzed. The solution, which foresees cylindrical fuel assemblies and exploits the buoyancy force due to the lead high density, allows to simplify the FAs locking system, to reduce their length and could lead to a more uniform neutron flux distribution.

  12. Ethanol Production for Automotive Fuel Usage

    Energy Technology Data Exchange (ETDEWEB)

    May, S.C.; Stenzel, R.A.; Weekes, M.C.; Yu, J.

    1979-10-01

    The production of ethanol from potatoes, sugar beet, and wheat using geothermal resources at the Raft River area of idaho is being evaluated. The south central section of Idaho produces approximately 18 million bushels of wheat, 1.3 million tons of sugar beet and 24 million cwt potatoes annually. Based on these production figures, a 20 million gallon/yr ethanol facility has been selected as the largest scale plant that can be supported with the current agricultural resources. The plant will operate on all three feedstocks nominally processing potatoes for five months, sugar beet for four months and wheat for three months of the year. The process facility will use conventional alcohol technology utilizing geothermal fluid at a maximum of 280 F as an energy source. The process flow diagrams for all three feedstocks are currently being prepared. There will be basically three feedstock preparation sections, although the liquefaction and saccharification steps for potatoes and wheat will involve common equipment. The fermentation, distillation and by-product handling sections will be common to all three feedstocks. Three geothermal energy extraction systems were considered to accommodate the energy requirements of the ethanol facility (flashed steam, pressurized fluid and secondary heat transfer). Pressured geothermal fluid with direct heat transfer has been selected as the usage mode to minimize scale deposition. Tentatively, the geothermal supply wells will be laid out in square grids with 1/4 mile spacing. The number of wells required will be determined after the process heat load is calculated.

  13. Consideration of applications of olefin metathesis in synthetic fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Heveling, J.

    1984-07-01

    One of the characteristics of Fischer-Tropsch synthesis and many oligomerization processes, is insufficient selectivity. Efforts have to be made to bring the products obtained in line with the market requirements. The olefin metathesis reaction has the potential to convert less desirable olefins to more useful ones and provides new ways of producing petrochemicals. Based on existing and suggested process technologies, applications of this reaction for the production of synthetic liquid fuels are discussed.

  14. High-Intensity Sweeteners in Alternative Tobacco Products

    Science.gov (United States)

    Miao, Shida; Beach, Evan S.; Sommer, Toby J.; Zimmerman, Julie B.

    2016-01-01

    toxicants. This study is the first to quantify high intensity sweeteners in snus and dissolvable products. Snus and dissolvables contain the high intensity sweetener, sucralose, at levels higher than in confectionary products. The high sweetness of alternative tobacco products makes these products attractive to adolescents. Regulation of sweetener content in non-cigarette products is suggested as an efficient means to control product palatability and to reduce initiation in adolescents. PMID:27217475

  15. Energy Efficiency Indicators for Public Electricity Production from Fossil Fuels

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    This paper presents a set of indicators that are used to analyse the energy efficiency of electricity production from fossil fuels on a global level and for a number of key countries and regions. The analysis is based on IEA statistics and includes public electricity plants and public CHP plants. Electricity production by autoproducers is not included and represents less than 6% of global electricity production. However, the share of autoproducers is significant in certain countries, particularly in Europe. Austria, Finland, Luxembourg, the Netherlands and Spain all have a share of electricity production from autoproducers that is more than twice the global average.

  16. Direct Utilization of Liquid Fuels in SOFC for Portable Applications: Challenges for the Selection of Alternative Anodes

    Directory of Open Access Journals (Sweden)

    Massimiliano Cimenti

    2009-06-01

    Full Text Available Solid oxide fuel cells (SOFC have the advantage of being able to operate with fuels other than hydrogen. In particular, liquid fuels are especially attractive for powering portable applications such as small power generators or auxiliary power units, in which case the direct utilization of the fuel would be convenient. Although liquid fuels are easier to handle and transport than hydrogen, their direct use in SOFC can lead to anode deactivation due to carbon formation, especially on traditional nickel/yttria stabilized zirconia (Ni/YSZ anodes. Significant advances have been made in anodic materials that are resistant to carbon formation but often these materials are less electrochemically active than Ni/YSZ. In this review the challenges of using liquid fuels directly in SOFC, in terms of gas-phase and catalytic reactions within the anode chamber, will be discussed and the alternative anode materials so far investigated will be compared.

  17. Renewable hydrogen production for fossil fuel processing

    Energy Technology Data Exchange (ETDEWEB)

    Greenbaum, E.; Lee, J.W.; Tevault, C.V.; Blankinship, S.L.

    1996-06-01

    In the current and prevailing concept of photosynthesis, the Z-scheme, first proposed by Hill and Bendall, PSII can split water, but is not thought to be able to perform one of PSI`s assigned functions-the reduction of ferredoxin/NADP{sup +} essential for CO{sub 2} assimilation. The Z-scheme therefore requires both PSII and PSI working in sequence for complete photosynthesis using water as the source of electrons and CO{sub 2} as the terminal electron acceptor. Despite disagreement from several investigators, the Z-scheme has become the textbook model of photosynthesis. Recently, we have demonstrated that sustained photoassimilation of CO{sub 2} and evolution of H{sub 2} and O{sub 2} in minimal medium can be achieved by the PSII light reaction without involvement of PSI in a PSI-deficient mutant of Chlamydomonas grown photoheterotrophically using an organic nutrient (acetate). In this paper, we report a more exciting discovery that PSI-deficient mutants of Chlamydomonas were capable of growing photoautotrophically with CO{sub 2} as the sole source of carbon. Since the Z-scheme requires both PSI and PSII working together in series for complete photosynthesis, it predicts that PSI-deficient mutants of green algae will not grow photoautotrophically. The discovery of photoautotrophic growth of PSI-deficient green algae without any organic nutrients, therefore, provides clear and solid evidence for the existence of a new type of photosynthesis-{open_quotes}PSII photosynthesis{close_quotes} that is an alternative to the Z-scheme. Our discovery may also provide an explanation for many {open_quotes}anomalous{close_quotes} quantum requirements that have been reported over the last 50 years, but failed to be explained by the Z-scheme.

  18. Bioelectricity production from various wastewaters through microbial fuel cell technology

    Directory of Open Access Journals (Sweden)

    Abhilasha S Mathuriya

    2009-12-01

    Full Text Available Microbial fuel cell technology is a new type of renewable and sustainable technology for electricity generation since it recovers energy from renewable materials that can be difficult to dispose of, such as organic wastes and wastewaters. In the present contribution we demonstrated electricity production by beer brewery wastewater, sugar industry wastewater, dairy wastewater, municipal wastewater and paper industry wastewater. Up to 14.92 mA current and 90.23% COD removal was achieved in 10 days of operation. Keywords: Bioelectricity, COD, Microbial Fuel Cells, Wastewater Received: 12 November 2009 / Received in revised form: 30 November 2009, Accepted: 30 November 2009, Published online: 10 March 2010

  19. Production of New Biomass/Waste-Containing Solid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Glenn A. Shirey; David J. Akers

    2005-09-23

    CQ Inc. and its industry partners--PBS Coals, Inc. (Friedens, Pennsylvania), American Fiber Resources (Fairmont, West Virginia), Allegheny Energy Supply (Williamsport, Maryland), and the Heritage Research Group (Indianapolis, Indiana)--addressed the objectives of the Department of Energy and industry to produce economical, new solid fuels from coal, biomass, and waste materials that reduce emissions from coal-fired boilers. This project builds on the team's commercial experience in composite fuels for energy production. The electric utility industry is interested in the use of biomass and wastes as fuel to reduce both emissions and fuel costs. In addition to these benefits, utilities also recognize the business advantage of consuming the waste byproducts of customers both to retain customers and to improve the public image of the industry. Unfortunately, biomass and waste byproducts can be troublesome fuels because of low bulk density, high moisture content, variable composition, handling and feeding problems, and inadequate information about combustion and emissions characteristics. Current methods of co-firing biomass and wastes either use a separate fuel receiving, storage, and boiler feed system, or mass burn the biomass by simply mixing it with coal on the storage pile. For biomass or biomass-containing composite fuels to be extensively used in the U.S., especially in the steam market, a lower cost method of producing these fuels must be developed that is applicable to a variety of combinations of biomass, wastes, and coal; economically competitive with current fuels; and provides environmental benefits compared with coal. During Phase I of this project (January 1999 to July 2000), several biomass/waste materials were evaluated for potential use in a composite fuel. As a result of that work and the team's commercial experience in composite fuels for energy production, paper mill sludge and coal were selected for further evaluation and demonstration

  20. Spray and atomization of diesel fuel and its alternatives from a single-hole injector using a common rail fuel injection system

    KAUST Repository

    Chen, PinChia

    2013-01-01

    Fuel spray and atomization characteristics play an important role in the performance of internal combustion engines. As the reserves of petroleum fuel are expected to be depleted within a few decades, finding alternative fuels that are economically viable and sustainable to replace the petroleum fuel has attracted much research attention. In this work, the spray and atomization characteristics were investigated for commercial No. 2 diesel fuel, biodiesel (FAME) derived from waste cooking oil (B100), 20% biodiesel blended diesel fuel (B20), renewable diesel fuel produced in house, and civil aircraft jet fuel (Jet-A). Droplet diameters and particle size distributions were measured by a laser diffraction particle analyzing system and the spray tip penetrations and cone angles were acquired using a high speed imaging technique. All experiments were conducted by employing a common-rail high-pressure fuel injection system with a single-hole nozzle under room temperature and pressure. The experimental results showed that biodiesel and jet fuel had different features compared with diesel. Longer spray tip penetration and larger droplet diameters were observed for B100. The smaller droplet size of the Jet-A were believed to be caused by its relatively lower viscosity and surface tension. B20 showed similar characteristics to diesel but with slightly larger droplet sizes and shorter tip penetration. Renewable diesel fuel showed closer droplet size and spray penetration to Jet-A with both smaller than diesel. As a result, optimizing the trade-off between spray volume and droplet size for different fuels remains a great challenge. However, high-pressure injection helps to optimize the trade-off of spray volume and droplet sizes. Furthermore, it was observed that the smallest droplets were within a region near the injector nozzle tip and grew larger along the axial and radial direction. The variation of droplet diameters became smaller with increasing injection pressure.

  1. Impact of alternative fuels on emissions characteristics of a gas turbine engine - part 1: gaseous and particulate matter emissions.

    Science.gov (United States)

    Lobo, Prem; Rye, Lucas; Williams, Paul I; Christie, Simon; Uryga-Bugajska, Ilona; Wilson, Christopher W; Hagen, Donald E; Whitefield, Philip D; Blakey, Simon; Coe, Hugh; Raper, David; Pourkashanian, Mohamed

    2012-10-01

    Growing concern over emissions from increased airport operations has resulted in a need to assess the impact of aviation related activities on local air quality in and around airports, and to develop strategies to mitigate these effects. One such strategy being investigated is the use of alternative fuels in aircraft engines and auxiliary power units (APUs) as a means to diversify fuel supplies and reduce emissions. This paper summarizes the results of a study to characterize the emissions of an APU, a small gas turbine engine, burning conventional Jet A-1, a fully synthetic jet fuel, and other alternative fuels with varying compositions. Gas phase emissions were measured at the engine exit plane while PM emissions were recorded at the exit plane as well as 10 m downstream of the engine. Five percent reduction in NO(x) emissions and 5-10% reduction in CO emissions were observed for the alternative fuels. Significant reductions in PM emissions at the engine exit plane were achieved with the alternative fuels. However, as the exhaust plume expanded and cooled, organic species were found to condense on the PM. This increase in organic PM elevated the PM mass but had little impact on PM number.

  2. Impacts of alternative fuels in aviation on microphysical aerosol properties and predicted ice nuclei concentration at aircraft cruise altitude

    Science.gov (United States)

    Weinzierl, B.; D'Ascoli, E.; Sauer, D. N.; Kim, J.; Scheibe, M.; Schlager, H.; Moore, R.; Anderson, B. E.; Ullrich, R.; Mohler, O.; Hoose, C.

    2015-12-01

    In the past decades air traffic has been substantially growing affecting air quality and climate. According to the International Civil Aviation Authority (ICAO), in the next few years world passenger and freight traffic is expected to increase annually by 6-7% and 4-5%, respectively. One possibility to reduce aviation impacts on the atmosphere and climate might be the replacement of fossil fuels by alternative fuels. However, so far the effects of alternative fuels on particle emissions from aircraft engines and their ability to form contrails remain uncertain. To study the effects of alternative fuels on particle emissions and the formation of contrails, the Alternative Fuel Effects on Contrails and Cruise Emissions (ACCESS) field experiment was conducted in California. In May 2014, the DLR Falcon 20 and the NASA HU-25 jet aircraft were instrumented with an extended aerosol and trace gas payload probing different types of fuels including JP-8 and JP-8 blended with HEFA (Hydroprocessed Esters and Fatty Acids) while the NASA DC8 aircraft acted as the source aircraft for ACCESS-2. Emission measurements were taken in the DC8 exhaust plumes at aircraft cruise level between 9-12 km altitude and at distances between 50 m and 20 km behind the DC8 engines. Here, we will present results from the ACCESS-2 aerosol measurements which show a 30-60% reduction of the non-volatile (mainly black carbon) particle number concentration in the aircraft exhaust for the HEFA-blend compared to conventional JP-8 fuel. Size-resolved particle emission indices show the largest reductions for larger particle sizes suggesting that the HEFA blend contains fewer and smaller black carbon particles. We will combine the airborne measurements with a parameterization of deposition nucleation developed during a number of ice nucleation experiments at the AIDA chamber in Karlsruhe and discuss the impact of alternative fuels on the abundance of potential ice nuclei at cruise conditions.

  3. Production of fuels by cellulose liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Datta, B.K.; McAuliffe, C.A. [Univ. of Manchester Institute of Science and Technology (United Kingdom)

    1993-12-31

    The effect of temperature on the liquefaction of cellulose was investigated in a range 200{degrees} to 350{degrees}C in aqueous medium with 5% pt/Al{sub 2}O{sub 3} catalyst, at 35 bars of hydrogen as reducing gas and a reaction time of 2 hours. Experiments were conducted in a 1 liter batch rocker autoclave reactor. The conversion increased from 46.5% at 200{degrees}C to 92.46% at 350{degrees}C, the oil yield increased from 18% at 200{degrees} to 33% at 350{degrees}C. At the high temperature, 350{degrees}C, the water soluble fraction and char formation decreased due to the conversion of the above to various gases. Moreover, ether solubles in water soluble fractions also decreased while the production of water increased from 8% at 200{degrees}C to 29% at 350{degrees}C. It suggests the possibility of removal of oxidants from the feedstocks as water. Initial dehydration reactions were obviously responsible for the high yield of water. Water yield increased gradually with the increase in temperature which was probably due to the dehydration of the intermediary products and the concurrent removal of oxygen atom as water instead of as CO or CO{sub 2}. At high temperatures, more CO{sub 2} gas was formed due to the water gas shift reaction. The formation of CO{sub 2} is favored over the formation of CO. At high temperatures more hydrocarbon gases were formed. Solvent extraction of the oils showed that the maximum percentage of carboxylic acids and phenolic compounds formed in comparison with carbonyl and neutral compounds when temperature increased.

  4. Biohydrogen production as a potential energy fuel in South Africa

    Directory of Open Access Journals (Sweden)

    P.T. Sekoai

    2015-06-01

    Full Text Available Biohydrogen production has captured increasing global attention due to it social, economic and environmental benefits. Over the past few years, energy demands have been growing significantly in South Africa due to rapid economic and population growth. The South African parastatal power supplier i.e. Electricity Supply Commission (ESKOM has been unable to meet the country’s escalating energy needs. As a result, there have been widespread and persistent power cuts throughout the country. This prompts an urgent need for exploration and implementation of clean and sustainable energy fuels like biohydrogen production in order to address this crisis. Therefore, this paper discusses the current global energy challenges in relation to South Africa’s problems. It then examines the feasibility of using biohydrogen production as a potential energy fuel in South Africa. Finally, it reviews the hydrogen-infrastructure development plans in the country.

  5. Photocatalysis for Renewable Energy Production Using PhotoFuelCells

    Directory of Open Access Journals (Sweden)

    Robert Michal

    2014-11-01

    Full Text Available The present work is a short review of our recent studies on PhotoFuelCells, that is, photoelectrochemical cells which consume a fuel to produce electricity or hydrogen, and presents some unpublished data concerning both electricity and hydrogen production. PhotoFuelCells have been constructed using nanoparticulate titania photoanodes and various cathode electrodes bearing a few different types of electrocatalyst. In the case where the cell functioned with an aerated cathode, the cathode electrode was made of carbon cloth carrying a carbon paste made of carbon black and dispersed Pt nanoparticles. When the cell was operated in the absence of oxygen, the electrocatalyst was deposited on an FTO slide using a special commercial carbon paste, which was again enriched with Pt nanoparticles. Mixing of Pt with carbon paste decreased the quantity of Pt necessary to act as electrocatalyst. PhotoFuelCells can produce electricity without bias and with relatively high open-circuit voltage when they function in the presence of fuel and with an aerated cathode. In that case, titania can be sensitized in the visible region by CdS quantum dots. In the present work, CdS was deposited by the SILAR method. Other metal chalcogenides are not functional as sensitizers because the combined photoanode in their presence does not have enough oxidative power to oxidize the fuel. Concerning hydrogen production, it was found that it is difficult to produce hydrogen in an alkaline environment even under bias, however, this is still possible if losses are minimized. One way to limit losses is to short-circuit anode and cathode electrode and put them close together. This is achieved in the “photoelectrocatalytic leaf”, which was presently demonstrated capable of producing hydrogen even in a strongly alkaline environment.

  6. Photocatalysis for renewable energy production using PhotoFuelCells.

    Science.gov (United States)

    Michal, Robert; Sfaelou, Stavroula; Lianos, Panagiotis

    2014-11-27

    The present work is a short review of our recent studies on PhotoFuelCells, that is, photoelectrochemical cells which consume a fuel to produce electricity or hydrogen, and presents some unpublished data concerning both electricity and hydrogen production. PhotoFuelCells have been constructed using nanoparticulate titania photoanodes and various cathode electrodes bearing a few different types of electrocatalyst. In the case where the cell functioned with an aerated cathode, the cathode electrode was made of carbon cloth carrying a carbon paste made of carbon black and dispersed Pt nanoparticles. When the cell was operated in the absence of oxygen, the electrocatalyst was deposited on an FTO slide using a special commercial carbon paste, which was again enriched with Pt nanoparticles. Mixing of Pt with carbon paste decreased the quantity of Pt necessary to act as electrocatalyst. PhotoFuelCells can produce electricity without bias and with relatively high open-circuit voltage when they function in the presence of fuel and with an aerated cathode. In that case, titania can be sensitized in the visible region by CdS quantum dots. In the present work, CdS was deposited by the SILAR method. Other metal chalcogenides are not functional as sensitizers because the combined photoanode in their presence does not have enough oxidative power to oxidize the fuel. Concerning hydrogen production, it was found that it is difficult to produce hydrogen in an alkaline environment even under bias, however, this is still possible if losses are minimized. One way to limit losses is to short-circuit anode and cathode electrode and put them close together. This is achieved in the "photoelectrocatalytic leaf", which was presently demonstrated capable of producing hydrogen even in a strongly alkaline environment.

  7. Advanced turbine systems program conceptual design and product development Task 8.3 - autothermal fuel reformer (ATR). Topical report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-01

    Autothermal fuel reforming (ATR) consists of reacting a hydrocarbon fuel such as natural gas or diesel with steam to produce a hydrogen-rich {open_quotes}reformed{close_quotes} fuel. This work has been designed to investigate the fuel reformation and the product gas combustion under gas turbine conditions. The hydrogen-rich gas has a high flammability with a wide range of combustion stability. Being lighter and more reactive than methane, the hydrogen-rich gas mixes readily with air and can be burned at low fuel/air ratios producing inherently low emissions. The reformed fuel also has a low ignition temperature which makes low temperature catalytic combustion possible. ATR can be designed for use with a variety of alternative fuels including heavy crudes, biomass and coal-derived fuels. When the steam required for fuel reforming is raised by using energy from the gas turbine exhaust, cycle efficiency is improved because of the steam and fuel chemically recuperating. Reformation of natural gas or diesel fuels to a homogeneous hydrogen-rich fuel has been demonstrated. Performance tests on screening various reforming catalysts and operating conditions were conducted on a batch-tube reactor. Producing over 70 percent of hydrogen (on a dry basis) in the product stream was obtained using natural gas as a feedstock. Hydrogen concentration is seen to increase with temperature but less rapidly above 1300{degrees}F. The percent reforming increases as the steam to carbon ratio is increased. Two basic groups of reforming catalysts, nickel - and platinum-basis, have been tested for the reforming activity.

  8. Technology assessment of alternative fuels for the transportation sector. Fact sheets on technology elements and system calculations for technology tracks; Teknologivurdering af alternative drivmidler til transportsektoren. Fakta-ark for teknologi-elementer og systemberegninger for teknologi-spor

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-05-15

    The report documents an analysis, which aims at evaluating technologies in connection with alternative fuels for the transportation sector. During the analysis process a method has been developed for consistent evaluation of alternative transportation fuels with the largest technological and economic potential. This appendix presents key fact sheets which substantiate the analysis presented in the report 'Technology assessment of alternative fuels for the transportation sector'. (BA)

  9. Experimental Investigations on the Engine Performance and Characteristics of Compression Ignition (CI Engine Using Dual Bio – Fuel Methyl Ester As Alternate Fuel With Exhaust Gas Recirculation

    Directory of Open Access Journals (Sweden)

    Inturi Vamsi,

    2015-05-01

    Full Text Available Petroleum products and resources are limited and their consumption is increasing very fast with globalization and high technology development since last decade. The emissions from the petroleum products polluting the environment considerably. Bio-fuels can be produced from diverse sources, which are subject to local geography, topology and climatology. Hence, every nation will have its own choice of a source. Duel bio-fuel represents an untapped resource of energy easily available in India. This study investigates the potential substitution of duel bio-fuel methyl ester blends for diesel as fuel for automobiles and other industrial purposes. This study is concerned with the analysis of the performance and emission characteristics of the duel bio-fuel methyl esters and comparing with petroleum diesel. The fuels used were neat methyl ester, diesel and different blends of the methyl ester with diesel. The tests were carried out on a 4.4 KW, single cylinder, direct injection, air-cooled diesel engine. The fuels used were neat duel bio-fuel methyl ester, diesel and different blends of the methyl ester with diesel. The experimental result shows that 20% of blend shows better performance with reduced pollution. This analysis shows that duel bio-fuel methyl ester and its blends are a potential substitute for diesel.

  10. H2 PRODUCTION AND FUEL CELLS.

    Energy Technology Data Exchange (ETDEWEB)

    WANG, X.; RODRIGUEZ, J.A.

    2006-06-30

    Oxide nanosystems play a key role as components of catalysts used for the production of H{sub 2} via the steam reforming or the partial oxidation of hydrocarbons, and for the water-gas shift reaction. The behavior seen for Cu-ceria and Au-ceria WGS catalysts indicates that the oxide is much more than a simple support. The special chemical properties of the oxide nanoparticles (defect rich, high mobility of oxygen) favor interactions with the reactants or other catalyst components. More in-situ characterization and mechanistic studies are necessary for the optimization of these nanocatalysts. The use of oxide nanomaterials for the fabrication of PEMFCs and SOFCs can lead to devices with a high practical impact. One objective is to build electrodes with low cost conducting oxide nanoarrays. The electron and oxygen-ion conducting capabilities of many oxides improve when going from the bulk to the nanoscale. Furthermore, one can get a more homogeneous surface morphology and an increase of the effective reaction area. Much more fundamental and practical research needs to be done in this area.

  11. Alternate economical starchy substrates for the production of 70% sorbitol

    Energy Technology Data Exchange (ETDEWEB)

    Upadhyay, C.M. (Sarabhai Research Centre, Baroda (India). Industrial Enzymes Dept.); Nehete, P.N. (Sarabhai Research Centre, Baroda (India). Industrial Fermentation Div.); Shah, D.N. (GSFC Research and Development Centre, Fertilizernagar (India). Biotechnology Dept.); Shah, N.K. (Armour Chemicals Pvt. Ltd., Ankleshwar (India)); Shankar, V. (National Chemical Lab., Pune (India). Biochemistry Div.); Kothari, R.M. (Thapar Corporate Research and Development Centre, Patiala (India). Biotechnology Div.)

    1991-03-01

    In view of the soaring prices of corn and tapioca starch, use of their hydrolysate in the production of 70% sorbitol became less remunerative. Therefore, an economical alternative is explored by using hydrolysates of cereal flours, namely, rice (Oryzae sativa), wheat (Triticum aestivum), jowar (Sorghum vulgare) and bajra (Pennisetum typhoideum). A protocol is devised to (a) prepare their high DE hydrolysates, (b) purify it after saccharification, (c) monitor the chemical chracteristics of concentrated hydrolysate, as feedstock for Raney nickel catalyzed pressure hydrogenation and (d) finally prepare 70% sorbital. Merits and demerits of hydrolysates of these cereal flours are discussed in terms of operational limitations and percentage recovery, the governing factors for their industrial acceptability. Rice flour hydrolysate appears to be an alternative substrate, operationally and economically. (orig.).

  12. Inter-esterified palm products as alternatives to hydrogenation.

    Science.gov (United States)

    Idris, Nor Aini; Dian, Noor Lida Habi Mat

    2005-01-01

    Inter-esterification is one of the processes used to modify the physico-chemical characteristics of oils and fats. Inter-esterification is an acyl-rearrangement reaction on the glycerol molecule. On the other hand, hydrogenation involves addition of hydrogen to the double bonds of unsaturated fatty acids. Due to health implications of trans fatty acids, which are formed during hydrogenation, the industry needs to find alternatives to hydrogenated fats. This paper discusses some applications of inter-esterified fats, with particular reference to inter-esterified palm products, as alternatives to hydrogenation. Some physico-chemical properties of inter-esterified fats used in shortenings are discussed. With inter-esterification, more palm stearin can be incorporated in vanaspati. For confectionary fats and infant formulations, enzymatic inter-esterification has been employed.

  13. Reactions of the Carbon Anode in Alternative Battery and Fuel Cell Configurations

    Energy Technology Data Exchange (ETDEWEB)

    Cooper, J F; Krueger, R

    2003-10-01

    A model is formulated by combining carbonate dissociation with pre-existing anode mechanisms involving heterogeneous reaction kinetics. The proposed model accounts for both the observed preponderance of CO{sub 2} evolution and dependence of rate on carbon anode microstructure. Implications of the model for the design of carbon batteries and fuel cells are discussed, and the laboratory cells used in earlier research are described. High coulombic efficiencies for the net reaction C + O{sub 2} = CO{sub 2} require severely limiting the thickness of paste anodes in powder-fed fuel cells while the unreacting surfaces of solid prismatic anodes must be isolated from the CO{sub 2} product atmosphere to prevent Boudouard corrosion, according to C + CO{sub 2} = 2CO.

  14. Coding potential of the products of alternative splicing in human.

    KAUST Repository

    Leoni, Guido

    2011-01-20

    BACKGROUND: Analysis of the human genome has revealed that as much as an order of magnitude more of the genomic sequence is transcribed than accounted for by the predicted and characterized genes. A number of these transcripts are alternatively spliced forms of known protein coding genes; however, it is becoming clear that many of them do not necessarily correspond to a functional protein. RESULTS: In this study we analyze alternative splicing isoforms of human gene products that are unambiguously identified by mass spectrometry and compare their properties with those of isoforms of the same genes for which no peptide was found in publicly available mass spectrometry datasets. We analyze them in detail for the presence of uninterrupted functional domains, active sites as well as the plausibility of their predicted structure. We report how well each of these strategies and their combination can correctly identify translated isoforms and derive a lower limit for their specificity, that is, their ability to correctly identify non-translated products. CONCLUSIONS: The most effective strategy for correctly identifying translated products relies on the conservation of active sites, but it can only be applied to a small fraction of isoforms, while a reasonably high coverage, sensitivity and specificity can be achieved by analyzing the presence of non-truncated functional domains. Combining the latter with an assessment of the plausibility of the modeled structure of the isoform increases both coverage and specificity with a moderate cost in terms of sensitivity.

  15. Biodiesel Fuel Production from Algae as Renewable Energy

    Directory of Open Access Journals (Sweden)

    A. B.M. Sharif Hossain

    2008-01-01

    Full Text Available Biodiesel is biodegradable, less CO2 and NOx emissions. Continuous use of petroleum sourced fuels is now widely recognized as unsustainable because of depleting supplies and the contribution of these fuels to the accumulation of carbon dioxide in the environment. Renewable, carbon neutral, transport fuels are necessary for environmental and economic sustainability. Algae have emerged as one of the most promising sources for biodiesel production. It can be inferred that algae grown in CO2-enriched air can be converted to oily substances. Such an approach can contribute to solve major problems of air pollution resulting from CO2 evolution and future crisis due to a shortage of energy sources. This study was undertaken to know the proper transesterification, amount of biodiesel production (ester and physical properties of biodiesel. In this study we used common species Oedogonium and Spirogyra to compare the amount of biodiesel production. Algal oil and biodiesel (ester production was higher in Oedogonium than Spirogyra sp. However, biomass (after oil extraction was higher in Spirogyra than Oedogonium sp. Sediments (glycerine, water and pigments was higher in Spirogyra than Oedogonium sp. There was no difference of pH between Spirogyra and Oedogonium sp. These results indicate that biodiesel can be produced from both species and Oedogonium is better source than Spirogyra sp.

  16. Dioxin-like pcb emissions from cement kilns during the use of alternative fuels.

    Science.gov (United States)

    Richards, Glen; Agranovski, Igor E

    2017-02-05

    The substitution of combustion fuels in cement plants is increasing throughout many countries, and its individual performance is constantly assessed against strict regulatory standards. For cement plants within Australia, normal operations remain to use petroleum coal as the dominate energy source at the precalciner, avoiding the opportunity to reduce carbon-based resources and pollutant emissions (such as carbon dioxide, oxides of nitrogen, persistent organic pollutants) whilst providing the necessary energy needs through resource recovery. This paper presents stack emission monitoring of health-critical dl-PCB (dioxin-like polychlorinated biphenyl) congeners during the substitution of alternative fuels at ten Australian cement plants, and to distinguish statistical similarities between other key pollutants (such as polychlorinated dibenzo-p-dioxins and furans (PCDD-F) and hydrogen halogens) and amongst the fuels used. Sampling of plant emissions was performed during normal operations (as baseline trials) and with the varied substitution rates of waste oil, solvents, chipped wood, refuge waste, carbon dust, shredded tyres and black sand (as experimental trials). The extraction of field and analytical data during these trials allowed for determining the total and individual unit mass of dl-PCB and PCDD-F isomers, standardised to 10% O2 and to World Health Organization (2005) toxicity equivalence (TEQ) values. The findings showed waste co-incineration during cement operations does reduce health-critical congeners of dioxins and dl-PCBs whilst providing the necessary energy and calcination needs. Experimental trials showed all dl-PCBs and PCB TEQ are below the internationally regulated Stockholm Convention article of 10pg TEQ/Nm(3). In several cases, an increased rate of substituted fuel also identified a consistent reduction to baseline dl-PCBs. The distribution of toxic isomers (TCDD-F and PeCDD-F) were shown to be predominate during waste oil, wood chips, and

  17. Hanford spent nuclear fuel project recommended path forward, volume III: Alternatives and path forward evaluation supporting documentation

    Energy Technology Data Exchange (ETDEWEB)

    Fulton, J.C.

    1994-10-01

    Volume I of the Hanford Spent Nuclear Fuel Project - Recommended Path Forward constitutes an aggressive series of projects to construct and operate systems and facilities to safely retrieve, package, transport, process, and store K Basins fuel and sludge. Volume II provided a comparative evaluation of four Alternatives for the Path Forward and an evaluation for the Recommended Path Forward. Although Volume II contained extensive appendices, six supporting documents have been compiled in Volume III to provide additional background for Volume II.

  18. Metabolic engineering of Clostridium acetobutylicum for the enhanced production of isopropanol-butanol-ethanol fuel mixture.

    Science.gov (United States)

    Jang, Yu-Sin; Malaviya, Alok; Lee, Joungmin; Im, Jung Ae; Lee, Sang Yup; Lee, Julia; Eom, Moon-Ho; Cho, Jung-Hee; Seung, Do Young

    2013-01-01

    Butanol is considered as a superior biofuel, which is conventionally produced by clostridial acetone-butanol-ethanol (ABE) fermentation. Among ABE, only butanol and ethanol can be used as fuel alternatives. Coproduction of acetone thus causes lower yield of fuel alcohols. Thus, this study aimed at developing an improved Clostridium acetobutylicum strain possessing enhanced fuel alcohol production capability. For this, we previously developed a hyper ABE producing BKM19 strain was further engineered to convert acetone into isopropanol. The BKM19 strain was transformed with the plasmid pIPA100 containing the sadh (primary/secondary alcohol dehydrogenase) and hydG (putative electron transfer protein) genes from the Clostridium beijerinckii NRRL B593 cloned under the control of the thiolase promoter. The resulting BKM19 (pIPA100) strain produced 27.9 g/l isopropanol-butanol-ethanol (IBE) as a fuel alcohols with negligible amount of acetone (0.4 g/l) from 97.8 g/l glucose in lab-scale (2 l) batch fermentation. Thus, this metabolically engineered strain was able to produce 99% of total solvent produced as fuel alcohols. The scalability and stability of BKM19 (pIPA100) were evaluated at 200 l pilot-scale fermentation, which showed that the fuel alcohol yield could be improved to 0.37 g/g as compared to 0.29 g/g obtained at lab-scale fermentation, while attaining a similar titer. To the best of our knowledge, this is the highest titer of IBE achieved and the first report on the large scale fermentation of C. acetobutylicum for IBE production.

  19. Techno-Economic Basis for Coproduct Manufacturing To Enable Hydrocarbon Fuel Production from Lignocellulosic Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, Mary J.; Davis, Ryan; Humbird, David; Tao, Ling; Dowe, Nancy; Guarnieri, Michael T.; Linger, Jeffrey G.; Karp, Eric M.; Salvachua, Davinia; Vardon, Derek R.; Beckham, Gregg T.

    2016-06-06

    Biorefinery process development relies on techno-economic analysis (TEA) to identify primary cost drivers, prioritize research directions, and mitigate technical risk for scale-up through development of detailed process designs. Here, we conduct TEA of a model 2000 dry metric ton-per-day lignocellulosic biorefinery that employs a two-step pretreatment and enzymatic hydrolysis to produce biomass-derived sugars, followed by biological lipid production, lipid recovery, and catalytic hydrotreating to produce renewable diesel blendstock (RDB). On the basis of projected near-term technical feasibility of these steps, we predict that RDB could be produced at a minimum fuel selling price (MFSP) of USD $9.55/gasoline-gallon-equivalent (GGE), predicated on the need for improvements in the lipid productivity and yield beyond current benchmark performance. This cost is significant given the limitations in scale and high costs for aerobic cultivation of oleaginous microbes and subsequent lipid extraction/recovery. In light of this predicted cost, we developed an alternative pathway which demonstrates that RDB costs could be substantially reduced in the near term if upgradeable fractions of biomass, in this case hemicellulose-derived sugars, are diverted to coproducts of sufficient value and market size; here, we use succinic acid as an example coproduct. The coproduction model predicts an MFSP of USD $5.28/GGE when leaving conversion and yield parameters unchanged for the fuel production pathway, leading to a change in biorefinery RDB capacity from 24 to 15 MM GGE/year and 0.13 MM tons of succinic acid per year. Additional analysis demonstrates that beyond the near-term projections assumed in the models here, further reductions in the MFSP toward $2-3/GGE (which would be competitive with fossil-based hydrocarbon fuels) are possible with additional transformational improvements in the fuel and coproduct trains, especially in terms of carbon efficiency to both fuels and

  20. High surface area graphite as alternative support for proton exchange membrane fuel cell catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira-Aparicio, P.; Folgado, M.A. [Centro de Investigaciones Energeticas, Medioambientales y Tecnologicas (CIEMAT), Avda. Complutense 22, E-28040 Madrid (Spain); Daza, L. [Centro de Investigaciones Energeticas, Medioambientales y Tecnologicas (CIEMAT), Avda. Complutense 22, E-28040 Madrid (Spain); Instituto de Catalisis y Petroleoquimica (CSIC), C/Marie Curie, 2 Campus de Cantoblanco, E-28049 Madrid (Spain)

    2009-07-01

    The suitability of a high surface area graphite (HSAG) as proton exchange membrane fuel cell (PEMFC) catalyst support has been evaluated and compared with that of the most popular carbon black: the Vulcan XC72. It has been observed that Pt is arranged on the graphite surface resulting in different structures which depend on the catalysts synthesis conditions. The influence that the metal particle size and the metal-support interaction exert on the catalysts degradation rate is analyzed. Temperature programmed oxidation (TPO) under oxygen containing streams has been shown to be a useful method to assess the resistance of PEMFC catalysts to carbon corrosion. The synthesized Pt/HSAG catalysts have been evaluated in single cell tests in the cathode catalytic layer. The obtained results show that HSAG can be a promising alternative to the traditionally used Vulcan XC72 carbon black when suitable catalysts synthesis conditions are used. (author)