Comparison of activity coefficient models for electrolyte systems
Lin, Yi; ten Kate, Antoon; Mooijer, Miranda
2010-01-01
Three activity coefficient models for electrolyte solutions were evaluated and compared. The activity coefficient models are: The electrolyte NRTL model (ElecNRTL) by Aspentech, the mixed solvent electrolyte model (MSE) by OLI Systems Inc., and the Extended UNIQUAC model from the Technical Univer...
Sergievskii, V. V.; Rudakov, A. M.
2016-08-01
The model that considers the nonideality of aqueous solutions of electrolytes with allowance for independent contributions of hydration of ions of various types and electrostatic interactions was substantiated using the cluster ion model. The empirical parameters in the model equations were found to be the hydrophilic and hydrophobic hydration numbers of ions in the standard state and the dispersion of their distribution over the stoichiometric coefficients. A mathematically adequate description of the concentration dependences of the osmotic coefficients and average ion activity coefficients of electrolytes was given for several systems. The difference in the rate of the decrease in the hydrophilic and hydrophobic hydration numbers of ions leads to extremum concentration dependences of the osmotic coefficients, which were determined by other authors from isopiestic data for many electrolytes and did not find explanation.
Distributing Correlation Coefficients of Linear Structure-Activity/Property Models
Sorana D. BOLBOACA
2011-12-01
Full Text Available Quantitative structure-activity/property relationships are mathematical relationships linking chemical structure and activity/property in a quantitative manner. These in silico approaches are frequently used to reduce animal testing and risk-assessment, as well as to increase time- and cost-effectiveness in characterization and identification of active compounds. The aim of our study was to investigate the pattern of correlation coefficients distribution associated to simple linear relationships linking the compounds structure with their activities. A set of the most common ordnance compounds found at naval facilities with a limited data set with a range of toxicities on aquatic ecosystem and a set of seven properties was studied. Statistically significant models were selected and investigated. The probability density function of the correlation coefficients was investigated using a series of possible continuous distribution laws. Almost 48% of the correlation coefficients proved fit Beta distribution, 40% fit Generalized Pareto distribution, and 12% fit Pert distribution.
Horvath, D.; Rappleye, D.; Bagri, P.; Simpson, M. F.
2017-09-01
An electrochemical study of manganese chloride in molten salt mixtures of eutectic LiCl-KCl was carried out using a variety of electrochemical methods in a high temperature cell including cyclic voltammetry (CV), chronopotentiometry (CP), chronoamperometry (CA), and open circuit potentiometry. Single step reduction from Mn2+ to Mn(0) was observed on both W and Mo working electrodes. Using a combination of these methods, measurements were made of activity coefficient and diffusion coefficient for MnCl2 in LiCl-KCl as a function of concentration (3.54 × 10-4 to 3.60 × 10-3 mol fraction of MnCl2) at 773K. From OCP measurements, values for activity coefficient varied from 0.014 to 0.0071. Diffusion coefficients varied with concentration and differed based on measurement method (CV, CA, or CP). Based on cyclic Mn(II) ranged from 1.1 to 2.8 × 10-5 cm2/s depending on concentration.
Simultaneous Description of Activity Coefficients and Solubility with eCPA
Schlaikjer, Anders; Thomsen, Kaj; Kontogeorgis, Georgios
2017-01-01
with salt specific parameters. The focus is on accurate description of the salt solubility, and low deviation correlations are obtained for all salts investigated. The inclusion of the solubility data in the parametrization has, compared to parameters only parametrized to osmotic coefficients and activity...... coefficients, not significantly affected the deviations of the osmotic coefficients and activity coefficients. The average deviations of the activity coefficient does increase slightly and it was found that the increase in deviations was almost entirely due to reduced accuracy at high temperature and high...... molality. The model is, furthermore, compared to the activity coefficient model, Extended UNIQUAC. It is shown that the eCPA provides more accurate solubility description at higher temperatures than Extended UNIQUAC but also that Extended UNIQUAC is slightly better at describing the activity coefficients...
Paduszyński, Kamil; Domańska, Urszula
2011-06-30
This paper is a continuation of our systematic investigations on piperidinium ionic liquids and presents new data on activity coefficients at infinite dilution for 43 solutes: linear and branched alkanes, cycloalkanes, alkenes, alkynes, benzene, alkylbenzenes, alcohols, water, thiophene, tetrahyrdofuran (THF), methyl tert-butyl ether (MTBE), linear ethers, acetone, and linear ketones in the ionic liquid 1-butyl-1-methyl-piperidinium bis(trifluoromethylsulfonyl)imide, [BMPIP][NTf2]. The data were determined by gas-liquid chromatography (GLC) at temperatures from 308.15 to 358.15 K. These values were compared to those previously published for the bis-(trifluoromethylsulfonyl)imide-based ionic liquids. The partial molar excess enthalpies ΔH1(E,∞) and entropies ΔS1(E,∞) at infinite dilution were calculated from the experimental γ13(∞) values obtained over the temperature range. The values of the selectivities for different separation problems were calculated from γ13(∞) and compared to literature values for N-methyl-2-pyrrolidinone (NMP), sulfolane, and additional ionic liquids. Experimental limiting activity coefficients were used to calculate gas-IL partition coefficients of solutes, K(L). The modeling with specific linear solvation energy relationship (LSER) equations was performed for data obtained in this work and those reported earlier for 1-butyl-1-methylpiperidinium thiocyanate, [BMPIP][SCN].
Frictional coefficient depending on active friction radius with BPV ...
The braking system is essential and crucial part of the active safety control of automobiles. .... active safety of the automobiles and the passenger. .... Communications and Information Technology, China North China institute of Aerospace ...
Guerin, Helene Chloe; Iliopoulou, Elpida; CERN. Geneva. HSE Department
2017-01-01
As summer student at CERN, I have been working in the Radiation Protection group for 10 weeks. I worked with the \\textsc{Fluka} Monte Carlo simulation code, using Fluence Conversion Coefficients method to perform simulations to estimate the saturation activities for activation experiments in the \\textsc{CSBF} and the \\textsc{Charm} facility in the East Experimental Area. The provided results will be used to plan a Monte Carlo benchmark in the \\textsc{CSBF} during a beam period at the end of August 2017.
Miller, D G
2007-05-16
Activity coefficient derivatives with respect to molality are presented for the Scatchard Neutral Electrolyte description of a ternary common-ion electrolyte system. These quantities are needed for the calculation of 'diffusion Onsager coefficients' and in turn for tests of the Onsager Reciprocal Relations in diffusion. The usually-omitted b{sub 23} term is included. The direct SNE binary approximations and a further approximation are discussed. Binary evaluation strategies other than constant ionic strength are considered.
朱艳; 杨延清; 孙军
2004-01-01
Based on Kohler's ternary solution model and Miedema's model for calculating the formation heat of binary solution, the integral equation was established for calculating the activity coefficients in ternary alloys and intermetallics. The activity coefficients for components in alloy Ti-5Al-2.5Sn, Ti-6Al-4V and intermetallics TiAl, Ti3 Al and Ti2 AlNb were calculated with the equations. The calculated data coincide well with the experimental ones found in literatures. According to the calculated activity coefficients and activities, it can be predicted that the interfacial reaction in SiC/Ti3 Al composite is more severe than that in composites SiC/Ti2 AlNb and SiC/TiAl.
Yi Lin CAO; Huan Ying LI
2003-01-01
In this paper, we calculated 37 structural descriptors of 174 organic compounds. The154 molecules were used to derive quantitative structure-infinite dilution activity coefficientrelationship by genetic programming, the other 20 compounds were used to test the model. Theresult showed that molecular partition property and three-dimensional structural descriptors havesignificant influence on the infinite dilution activity coefficients.
Khan, A M; Lee, Y K; Kim, T S
2008-01-01
Automatic recognition of human activities is one of the important and challenging research areas in proactive and ubiquitous computing. In this work, we present some preliminary results of recognizing human activities using augmented features extracted from the activity signals measured using a single triaxial accelerometer sensor and artificial neural nets. The features include autoregressive (AR) modeling coefficients of activity signals, signal magnitude areas (SMA), and title angles (TA). We have recognized four human activities using AR coefficients (ARC) only, ARC with SMA, and ARC with SMA and TA. With the last augmented features, we have achieved the recognition rate above 99% for all four activities including lying, standing, walking, and running. With our proposed technique, real time recognition of some human activities is possible.
Simulations of mean ionic activity coefficients and solubilities in aqueous electrolyte solutions
Panagiotopoulos, Athanassios
Aqueous electrolyte solutions play an important role in industrial, geochemical and biological applications. The mean ionic activity coefficients quantify the deviation of salt chemical potential from ideal solution behavior; experimental measurements are available for many salts over broad ranges of concentration and temperature, but there have been practically no prior simulation results, because if sampling difficulties for explicit-solvent electrolyte solutions. We have developed a new approach for determination of activity coefficients of aqueous electrolytes. Common fixed-point-charge models for water and ions are unable to reproduce simultaneously activity coefficients and solubilities. Polarizable models perform better, but still predict an incorrect temperature dependence of these properties. Work supported by the U.S. Department of Energy, Office of Basic Energy Science.
G. Ganbavale
2014-06-01
Full Text Available This study presents a new, improved parameterisation of the temperature dependence of activity coefficients in the AIOMFAC (Aerosol Inorganic–Organic Mixtures Functional groups Activity Coefficients model applicable for aqueous as well as water-free organic solutions. For electrolyte-free organic and organic–water mixtures the AIOMFAC model uses a group-contribution approach based on UNIFAC (UNIversal quasi-chemical Functional-group Activity Coefficients. This group-contribution approach explicitly accounts for interactions among organic functional groups and between organic functional groups and water. The previous AIOMFAC version uses a simple parameterisation of the temperature dependence of activity coefficients, aimed to be applicable in the temperature range from ~275 to ~400 K. With the goal to improve the description of a wide variety of organic compounds found in atmospheric aerosols, we extend the AIOMFAC parameterisation for the functional groups carboxyl, hydroxyl, ketone, aldehyde, ether, ester, alkyl, aromatic carbon-alcohol, and aromatic hydrocarbon to atmospherically relevant low temperatures with the introduction of a new temperature dependence parameterisation. The improved temperature dependence parameterisation is derived from classical thermodynamic theory by describing effects from changes in molar enthalpy and heat capacity of a multicomponent system. Thermodynamic equilibrium data of aqueous organic and water-free organic mixtures from the literature are carefully assessed and complemented with new measurements to establish a comprehensive database, covering a wide temperature range (~190 to ~440 K for many of the functional group combinations considered. Different experimental data types and their processing for the estimation of AIOMFAC model parameters are discussed. The new AIOMFAC parameterisation for the temperature dependence of activity coefficients from low to high temperatures shows an overall improvement of
Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution
马征; 董晓霞; 胡玉峰; 张柏松; 徐长英; 刘艳升
2013-01-01
It is important to know how ILs (ionic liquids) influence organic reaction. In this paper, activity coeffi-cients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.
A thermodynamic model of mixed organic-inorganic aerosols to predict activity coefficients
Zuend, A.; Marcolli, C.; Luo, B. P.; Peter, T.
2008-08-01
Tropospheric aerosols contain mixtures of inorganic salts, acids, water, and a large variety of organic compounds. Interactions between these substances in liquid mixtures lead to discrepancies from ideal thermodynamic behaviour. By means of activity coefficients, non-ideal behaviour can be taken into account. We present here a thermodynamic model named AIOMFAC (Aerosol Inorganic-Organic Mixtures Functional groups Activity Coefficients) that is able to calculate activity coefficients covering inorganic, organic, and organic-inorganic interactions in aqueous solutions over a wide concentration range. This model is based on the activity coefficient model LIFAC by Yan et al. (1999) that we modified and reparametrised to better describe atmospherically relevant conditions and mixture compositions. Focusing on atmospheric applications we considered H+, Li+, Na+, K+, NH+4, Mg2+, Ca2+, Cl-, Br-, NO-3, HSO-4, and SO2-4 as cations and anions and a wide range of alcohols/polyols composed of the functional groups CHn and OH as organic compounds. With AIOMFAC, the activities of the components within an aqueous electrolyte solution are well represented up to high ionic strength. Most notably, a semi-empirical middle-range parametrisation of direct organic-inorganic interactions in alcohol+water+salt solutions strongly improves the agreement between experimental and modelled activity coefficients. At room temperature, this novel thermodynamic model offers the possibility to compute equilibrium relative humidities, gas/particle partitioning and liquid-liquid phase separations with high accuracy. In further studies, other organic functional groups will be introduced. The model framework is not restricted to specific ions or organic compounds and is therefore also applicable for other research topics.
A thermodynamic model of mixed organic-inorganic aerosols to predict activity coefficients
A. Zuend
2008-08-01
Full Text Available Tropospheric aerosols contain mixtures of inorganic salts, acids, water, and a large variety of organic compounds. Interactions between these substances in liquid mixtures lead to discrepancies from ideal thermodynamic behaviour. By means of activity coefficients, non-ideal behaviour can be taken into account. We present here a thermodynamic model named AIOMFAC (Aerosol Inorganic-Organic Mixtures Functional groups Activity Coefficients that is able to calculate activity coefficients covering inorganic, organic, and organic-inorganic interactions in aqueous solutions over a wide concentration range. This model is based on the activity coefficient model LIFAC by Yan et al. (1999 that we modified and reparametrised to better describe atmospherically relevant conditions and mixture compositions. Focusing on atmospheric applications we considered H^{+}, Li^{+}, Na^{+}, K^{+}, NH^{+}_{4}, Mg^{2+}, Ca^{2+}, Cl^{−}, Br^{−}, NO^{−}_{3}, HSO^{−}_{4}, and SO^{2−}_{4} as cations and anions and a wide range of alcohols/polyols composed of the functional groups CH_{n} and OH as organic compounds. With AIOMFAC, the activities of the components within an aqueous electrolyte solution are well represented up to high ionic strength. Most notably, a semi-empirical middle-range parametrisation of direct organic-inorganic interactions in alcohol+water+salt solutions strongly improves the agreement between experimental and modelled activity coefficients. At room temperature, this novel thermodynamic model offers the possibility to compute equilibrium relative humidities, gas/particle partitioning and liquid-liquid phase separations with high accuracy. In further studies, other organic functional groups will be introduced. The model framework is not restricted to specific ions or organic compounds and is therefore also
A thermodynamic model of mixed organic-inorganic aerosols to predict activity coefficients
A. Zuend
2008-03-01
Full Text Available Tropospheric aerosols contain mixtures of inorganic salts, acids, water, and a large variety of organic compounds. Interactions between these substances in liquid mixtures lead to discrepancies from ideal thermodynamic behaviour. By means of activity coefficients, non-ideal behaviour can be taken into account. We present here a thermodynamic model named AIOMFAC (Aerosol Inorganic–Organic Mixtures Functional groups Activity Coefficients that is able to calculate activity coefficients covering inorganic, organic, and organic–inorganic interactions in aqueous solutions over a wide concentration range. This model is based on the activity coefficient model LIFAC by Yan et al. (1999 that we modified and reparametrised to better describe atmospherically relevant conditions and mixture compositions. Focusing on atmospheric applications we considered H^{+}, Li^{+}, Na^{+}, K^{+}, NH_{4}^{+}, Mg^{2+}, Ca^{2+}, Cl^{−}, Br^{−}, NO_{3}^{−}, HSO_{4}^{−}, and SO_{4}^{2−} as cations and anions and a wide range of alcohols/polyols composed of the functional groups CH_{n} and OH as organic compounds. With AIOMFAC, the activities of the components within an aqueous electrolyte solution are well represented up to high ionic strength. Most notably, a semi-empirical middle-range parametrisation of direct organic–inorganic interactions in alcohol + water + salt solutions strongly improves the agreement between experimental and modelled activity coefficients. At room temperature, this novel thermodynamic model offers the possibility to compute equilibrium relative humidities, gas/particle partitioning and liquid–liquid phase separations with high accuracy. In further studies, other organic functional groups will be introduced. The model framework is not restricted to specific ions or organic compounds and is therefore
Determination of the activity coefficient of neodymium in liquid aluminium by potentiometric methods
De Cordoba, G. [HLW/DFN/DE, CIEMAT, Avda. Complutense 22, Madrid 28040 (Spain)], E-mail: g.cordoba@ciemat.es; Laplace, A.; Conocar, O.; Lacquement, J. [DEN/DRCP/SCPS/LPP, CEA, Site de Marcoule. Bat. 399, BP 17171, 30207 Bagnols sur Ceze (France); Caravaca, C. [HLW/DFN/DE, CIEMAT, Avda. Complutense 22, Madrid 28040 (Spain)
2008-12-30
The activity coefficient of neodymium in liquid aluminium phase has been determined potentiometrically in the temperature range of 973-1073 K. To the author's knowledge, no data on this parameter has been published yet. Three different electrochemical methods have been tested: the cyclic voltammetry technique, the coulometric additions method and the direct use of an Al-Nd alloy. In addition, an experimental set-up has been designed which allows working with small amounts of solvent (30 g). The molten eutectic mixture CaCl{sub 2}-NaCl (52-48 mol%) has been selected as the electrolyte. From the results obtained, the variation of the activity coefficient of Nd in Al(l) as a function of the temperature can be expressed as follows: log {gamma}{sub Nd(Al)} = 9.81 - 17134/T(K), in the range 973-1073 K. It has been found a good agreement between the activity coefficient values obtained from the different methods tested. Hence, it can be stated that either of the techniques used allows determining reliable values for the activity coefficient.
Jana Shafi
2016-09-01
Full Text Available In this paper, we discuss project scheduling with conflicting activity-resources. Several project activities require same resources but, may be scheduled with the certain lapse of time resulting in repeatedly using the same kind of resources for executing dissimilar activities. Due to the frequent usage of same resources multiple times, expenditure become more expensive and project duration extends. The problem is to find out such kind of activities which are developing implicit relations amid them. , we proposed a solution by introducing TVs (Transparent view of Scheduling model. First, we analyze and enlists activities according to required resources, categorize them and then we segregate dependent and independent activities by indicating a value. Performing Dependency test on activities by using Pearson's Correlation Coefficient (PCC to calculate the rate of relations among the ordered activities for similar resources. By using this model we can reschedule activities to avoid confusion and disordering of resources without consumption of time and capital.
Tong, Chinghang; Clegg, Simon L.; Seinfeld, John H.
Atmospheric aerosols generally comprise a mixture of electrolytes, organic compounds, and water. Determining the gas-particle distribution of volatile compounds, including water, requires equilibrium or mass transfer calculations, at the heart of which are models for the activity coefficients of the particle-phase components. We evaluate here the performance of four recent activity coefficient models developed for electrolyte/organic/water mixtures typical of atmospheric aerosols. Two of the models, the CSB model [Clegg, S.L., Seinfeld, J.H., Brimblecombe, P., 2001. Thermodynamic modelling of aqueous aerosols containing electrolytes and dissolved organic compounds. Journal of Aerosol Science 32, 713-738] and the aerosol diameter dependent equilibrium model (ADDEM) [Topping, D.O., McFiggans, G.B., Coe, H., 2005. A curved multi-component aerosol hygroscopicity model framework: part 2—including organic compounds. Atmospheric Chemistry and Physics 5, 1223-1242] treat ion-water and organic-water interactions but do not include ion-organic interactions; these can be referred to as "decoupled" models. The other two models, reparameterized Ming and Russell model 2005 [Raatikainen, T., Laaksonen, A., 2005. Application of several activity coefficient models to water-organic-electrolyte aerosols of atmospheric interest. Atmospheric Chemistry and Physics 5, 2475-2495] and X-UNIFAC.3 [Erdakos, G.B., Change, E.I., Pandow, J.F., Seinfeld, J.H., 2006. Prediction of activity coefficients in liquid aerosol particles containing organic compounds, dissolved inorganic salts, and water—Part 3: Organic compounds, water, and ionic constituents by consideration of short-, mid-, and long-range effects using X-UNIFAC.3. Atmospheric Environment 40, 6437-6452], include ion-organic interactions; these are referred to as "coupled" models. We address the question—Does the inclusion of a treatment of ion-organic interactions substantially improve the performance of the coupled models over
Del Serra, Daniele; Aquaro, Donato; Mazed, Dahmane; Pazzagli, Fabio; Ciolini, Riccardo, E-mail: r.ciolini@ing.unipi.it
2015-07-15
Highlights: • An experimental test facility for qualification of the krypton and xenon adsorption properties of activated carbons. • The measurement of the adsorption coefficient by using the elution curve method. • The simultaneous on-line control of the main physical parameters influencing the adsorption property of activated carbon. - Abstract: An automated experimental test facility, intended specifically for qualification of the krypton and xenon adsorption properties of activated carbon samples, was designed and constructed. The experimental apparatus was designed to allow an on-line control of the main physical parameters influencing greatly the adsorption property of activated carbon. The measurement of the adsorption coefficient, based upon the elution curve method, can be performed with a precision better than 5% at gas pressure values ranging from atmospheric pressure up to 9 bar and bed temperature from 0 up to 80 °C. The carrier gas flow rate can be varied from 40 up to 4000 N cm{sup 3} min{sup −1} allowing measurement of dynamic adsorption coefficient with face velocities from 0.3 up to 923 cm min{sup −1} depending on the gas pressure and the test cell being used. The moisture content of the activated carbon can be precisely controlled during measurement, through the relative humidity of the carrier gas.
Molecular radiotherapy: The NUKFIT software for calculating the time-integrated activity coefficient
Kletting, P.; Schimmel, S.; Luster, M. [Klinik für Nuklearmedizin, Universität Ulm, Ulm 89081 (Germany); Kestler, H. A. [Research Group Bioinformatics and Systems Biology, Institut für Neuroinformatik, Universität Ulm, Ulm 89081 (Germany); Hänscheid, H.; Fernández, M.; Lassmann, M. [Klinik für Nuklearmedizin, Universität Würzburg, Würzburg 97080 (Germany); Bröer, J. H.; Nosske, D. [Bundesamt für Strahlenschutz, Fachbereich Strahlenschutz und Gesundheit, Oberschleißheim 85764 (Germany); Glatting, G. [Medical Radiation Physics/Radiation Protection, Medical Faculty Mannheim, Heidelberg University, Mannheim 68167 (Germany)
2013-10-15
Purpose: Calculation of the time-integrated activity coefficient (residence time) is a crucial step in dosimetry for molecular radiotherapy. However, available software is deficient in that it is either not tailored for the use in molecular radiotherapy and/or does not include all required estimation methods. The aim of this work was therefore the development and programming of an algorithm which allows for an objective and reproducible determination of the time-integrated activity coefficient and its standard error.Methods: The algorithm includes the selection of a set of fitting functions from predefined sums of exponentials and the choice of an error model for the used data. To estimate the values of the adjustable parameters an objective function, depending on the data, the parameters of the error model, the fitting function and (if required and available) Bayesian information, is minimized. To increase reproducibility and user-friendliness the starting values are automatically determined using a combination of curve stripping and random search. Visual inspection, the coefficient of determination, the standard error of the fitted parameters, and the correlation matrix are provided to evaluate the quality of the fit. The functions which are most supported by the data are determined using the corrected Akaike information criterion. The time-integrated activity coefficient is estimated by analytically integrating the fitted functions. Its standard error is determined assuming Gaussian error propagation. The software was implemented using MATLAB.Results: To validate the proper implementation of the objective function and the fit functions, the results of NUKFIT and SAAM numerical, a commercially available software tool, were compared. The automatic search for starting values was successfully tested for reproducibility. The quality criteria applied in conjunction with the Akaike information criterion allowed the selection of suitable functions. Function fit
McBride, Devin W; Rodgers, Victor G. J.
2013-01-01
The activity coefficient is largely considered an empirical parameter that was traditionally introduced to correct the non-ideality observed in thermodynamic systems such as osmotic pressure. Here, the activity coefficient of free-solvent is related to physically realistic parameters and a mathematical expression is developed to directly predict the activity coefficients of free-solvent, for aqueous protein solutions up to near-saturation concentrations. The model is based on the free-solvent...
薛松柏; 钱乙余; 董健
2002-01-01
The relation between contents of cerium and impurity lead or bismuth to their activity coefficient in Ag, Cu and Zn-base alloy was calculated and analyzed by using the ternary system Chou model. The thermodynamic calculation results show that the "equivalent activity coefficient phenomenon" emerges among the activity coefficient of solute in a certain range of cerium (or at a certain point) for the Ce-Pb-X and Ce-Bi-X (X=Ag, Cu or Zn) ternary alloy system. Under this condition, the activity coefficient of solute has nothing to do with its own concentration. The preliminary theoretical analysis to this phenomenon was also made.
GE MingLan; XIONG JieMing; WANG LiSheng
2009-01-01
On the basis of the theoretical linear solvation energy relationship (TLSER) suggested by Wilson et al.and the quantum chemical descriptors computed by AM1 Hamiltonian,a predicting model was developed to characterize the activity coefficients at infinite dilution γi∞ 34 organic solutes in ionic liquids (ILs) 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([BMIM][CF3SO3]) and 1-propyl-2,3-dimethylimidazolium tetrafluoroborate ([PDMIM][BF4]) at 323.15 K.The results showed that the model had an good correlation and could successfully describe γi∞.In addition,correlation parameters are analyzed to understand the interactions that affect infinite dilution activity coefficients.
无
2000-01-01
@@1 INTRODUCTION Due to its short experimental time, little sample needed, suitable for broad temperature range, inverse gas chromatography (IGC) has been widely used to measure variety of properties of polymer systems, such as the intinite diluted activity coefficients of solvent in polymer, the glass transition temperature of polymer and the surface properties of polymer[1-5], etc. Those data have been used to develop the group contribution method for the prediction of thermodynamic proper-ties of polymer solution[6].
Mikuni, Shintaro; Yamamoto, Johtaro; Horio, Takashi; Kinjo, Masataka
2017-08-25
The glucocorticoid receptor (GR) is a transcription factor, which interacts with DNA and other cofactors to regulate gene transcription. Binding to other partners in the cell nucleus alters the diffusion properties of GR. Raster image correlation spectroscopy (RICS) was applied to quantitatively characterize the diffusion properties of EGFP labeled human GR (EGFP-hGR) and its mutants in the cell nucleus. RICS is an image correlation technique that evaluates the spatial distribution of the diffusion coefficient as a diffusion map. Interestingly, we observed that the averaged diffusion coefficient of EGFP-hGR strongly and negatively correlated with its transcriptional activities in comparison to that of EGFP-hGR wild type and mutants with various transcriptional activities. This result suggests that the decreasing of the diffusion coefficient of hGR was reflected in the high-affinity binding to DNA. Moreover, the hyper-phosphorylation of hGR can enhance the transcriptional activity by reduction of the interaction between the hGR and the nuclear corepressors.
Ren, Da-Bing; Yang, Zhao-Hui; Liang, Yi-Zeng; Ding, Qiong; Chen, Chen; Ouyang, Mei-Lan
2013-08-02
Selection of a suitable solvent system is the first and foremost step for a successful counter-current chromatography (CCC) separation. In this paper, a thermodynamic model, nonrandom two-liquid segment activity coefficient model (NRTL-SAC) which uses four types of conceptual segments to describe the effective surface interactions for each solvent and solute molecule, was employed to correlate and predict the partition coefficients (K) of a given compound in a specific solvent system. Then a suitable solvent system was selected according to the predicted partition coefficients. Three solvent system families, heptane/methanol/water, heptane/ethyl acetate/methanol/water (Arizona) and hexane/ethyl acetate/methanol/water, and several solutes were selected to investigate the effectiveness of the NRTL-SAC model for predicting the partition coefficients. Comparison between experimental results and predicted results showed that the NRTL-SAC model is of potential for estimating the K value of a given compound. Also a practical separation case on magnolol and honokiol suggests the NRTL-SAC model is effective, reliable and practical for the purpose of predicting partition coefficients and selecting a suitable solvent system for CCC separation. Copyright © 2013. Published by Elsevier B.V.
Ganbavale, G.; Zuend, A.; Marcolli, C.; Peter, T.
2015-01-01
This study presents a new, improved parameterisation of the temperature dependence of activity coefficients in the AIOMFAC (Aerosol Inorganic-Organic Mixtures Functional groups Activity Coefficients) model applicable for aqueous as well as water-free organic solutions. For electrolyte-free organic and organic-water mixtures the AIOMFAC model uses a group-contribution approach based on UNIFAC (UNIversal quasi-chemical Functional-group Activity Coefficients). This group-contribution approach explicitly accounts for interactions among organic functional groups and between organic functional groups and water. The previous AIOMFAC version uses a simple parameterisation of the temperature dependence of activity coefficients, aimed to be applicable in the temperature range from ~ 275 to ~ 400 K. With the goal to improve the description of a wide variety of organic compounds found in atmospheric aerosols, we extend the AIOMFAC parameterisation for the functional groups carboxyl, hydroxyl, ketone, aldehyde, ether, ester, alkyl, aromatic carbon-alcohol, and aromatic hydrocarbon to atmospherically relevant low temperatures. To this end we introduce a new parameterisation for the temperature dependence. The improved temperature dependence parameterisation is derived from classical thermodynamic theory by describing effects from changes in molar enthalpy and heat capacity of a multi-component system. Thermodynamic equilibrium data of aqueous organic and water-free organic mixtures from the literature are carefully assessed and complemented with new measurements to establish a comprehensive database, covering a wide temperature range (~ 190 to ~ 440 K) for many of the functional group combinations considered. Different experimental data types and their processing for the estimation of AIOMFAC model parameters are discussed. The new AIOMFAC parameterisation for the temperature dependence of activity coefficients from low to high temperatures shows an overall improvement of 28% in
Predicting Pyrolysis Products of PE, PP, and PET Using NRTL Activity Coefficient Model
Seyed Mousa FakhrHoseini
2013-01-01
Full Text Available Using thermodynamic models is a desired method for predicting an equilibrium when occurring in a system. If a thermodynamic model can predict an equilibrium condition in a pyrolysis, for a new way will be open for scientists in predicting equilibrium in a reaction without need to kinetic models. In this work, low-density polyethylene, polypropylene, and polyethylene terephthalate were used instead of feed of pyrolysis process. The process was maintained at 500°C with 5 different temperature raising ratios 6, 8, 10, 12, and 14. Then the process was modeled thermodynamically using NRTL activity coefficient model. Using this model, the binary interaction coefficients were investigated for the system of “char, oil, and gas.” Results showed that polyethylene and polypropylene produced the maximum liquid product. Calculated RMSD objective function was 0.0157; that it is acceptable for this process.
Stegen, J.H.G. van der; Weerdenburg, H.; Veen, A.J. van der; Hogendoorn, J.A.; Versteeg, G.F.
1999-01-01
The Pitzer model can be applied to predict the mean activity coefficients of salts in aqueous electrolyte solutions as a function of the molality. In this work it is shown that the mean activity coefficients for NaOH and NaCl solutions as predicted by the Pitzer model are in good agreement with expe
Devin W McBride
Full Text Available The activity coefficient is largely considered an empirical parameter that was traditionally introduced to correct the non-ideality observed in thermodynamic systems such as osmotic pressure. Here, the activity coefficient of free-solvent is related to physically realistic parameters and a mathematical expression is developed to directly predict the activity coefficients of free-solvent, for aqueous protein solutions up to near-saturation concentrations. The model is based on the free-solvent model, which has previously been shown to provide excellent prediction of the osmotic pressure of concentrated and crowded globular proteins in aqueous solutions up to near-saturation concentrations. Thus, this model uses only the independently determined, physically realizable quantities: mole fraction, solvent accessible surface area, and ion binding, in its prediction. Predictions are presented for the activity coefficients of free-solvent for near-saturated protein solutions containing either bovine serum albumin or hemoglobin. As a verification step, the predictability of the model for the activity coefficient of sucrose solutions was evaluated. The predicted activity coefficients of free-solvent are compared to the calculated activity coefficients of free-solvent based on osmotic pressure data. It is observed that the predicted activity coefficients are increasingly dependent on the solute-solvent parameters as the protein concentration increases to near-saturation concentrations.
McBride, Devin W; Rodgers, Victor G J
2013-01-01
The activity coefficient is largely considered an empirical parameter that was traditionally introduced to correct the non-ideality observed in thermodynamic systems such as osmotic pressure. Here, the activity coefficient of free-solvent is related to physically realistic parameters and a mathematical expression is developed to directly predict the activity coefficients of free-solvent, for aqueous protein solutions up to near-saturation concentrations. The model is based on the free-solvent model, which has previously been shown to provide excellent prediction of the osmotic pressure of concentrated and crowded globular proteins in aqueous solutions up to near-saturation concentrations. Thus, this model uses only the independently determined, physically realizable quantities: mole fraction, solvent accessible surface area, and ion binding, in its prediction. Predictions are presented for the activity coefficients of free-solvent for near-saturated protein solutions containing either bovine serum albumin or hemoglobin. As a verification step, the predictability of the model for the activity coefficient of sucrose solutions was evaluated. The predicted activity coefficients of free-solvent are compared to the calculated activity coefficients of free-solvent based on osmotic pressure data. It is observed that the predicted activity coefficients are increasingly dependent on the solute-solvent parameters as the protein concentration increases to near-saturation concentrations.
Miyi Li; Tao Fang
2015-01-01
A rigorous approach is proposed to model the mean ion activity coefficient for strong electrolyte systems using the Poisson–Boltzmann equation. An effective screening radius similar to the Debye decay length is introduced to define the local composition and new boundary conditions for the central ion. The crystallographic ion size is also considered in the activity coefficient expressions derived and non-electrostatic contributions are neglected. The model is presented for aqueous strong electrolytes and compared with the classical Debye–Hückel (DH) limiting law for dilute solutions. The radial distribution function is compared with the DH and Monte Carlo studies. The mean ion activity coefficients are calculated for 1:1 aqueous solutions containing strong electrolytes composed of alkali halides. The individual ion activity coefficients and mean ion activity coefficients in mixed sol-vents are predicted with the new equations.
Gray, M.; Nilsson, M. [University of California Irvine, 916 Engineering Tower, UC Irvine, Irvine, CA 92697-2575 (United States); Zalupski, P. [Idaho National Laboratory, 2525 Fremont Avenue, Idaho Falls, ID 83415 (United States)
2013-07-01
A thorough understanding of the non-ideal behavior of the chemical components utilized in solvent extraction contributes to the success of any large-scale spent nuclear fuel treatment. To address this, our current work uses vapor pressure osmometry to characterize the non-ideal behavior of the solvent extraction agent di-(2-ethylhexyl) phosphoric acid (HDEHP), a common extractant in proposed separation schemes. Solubility parameters were fit to data on HDEHP at four temperatures using models based on Scatchard Hildebrand regular solution theory with Flory Huggins entropic corrections. The results are comparable but not identical to the activity coefficients from prior slope analysis in the literature. (authors)
Gjorgjeska, Biljana
2011-01-01
There is the need for defining standard technique for quantitative determination of bactericidal activity of chemical disinfectant substances, as well as the need for defining parameter for comparing various chemical disinfectants. The methods which are usually used for evaluation of antiseptic activity of disinfectant aqueous solutions are microbiological.
Schüürmann, Gerrit; Ebert, Ralf-Uwe; Chen, Jingwen; Wang, Bin; Kühne, Ralph
2008-11-01
The external prediction capability of quantitative structure-activity relationship (QSAR) models is often quantified using the predictive squared correlation coefficient, q (2). This index relates the predictive residual sum of squares, PRESS, to the activity sum of squares, SS, without postprocessing of the model output, the latter of which is automatically done when calculating the conventional squared correlation coefficient, r (2). According to the current OECD guidelines, q (2) for external validation should be calculated with SS referring to the training set activity mean. Our present findings including a mathematical proof demonstrate that this approach yields a systematic overestimation of the prediction capability that is triggered by the difference between the training and test set activity means. Example calculations with three regression models and data sets taken from literature show further that for external test sets, q (2) based on the training set activity mean may become even larger than r (2). As a consequence, we suggest to always use the test set activity mean when quantifying the external prediction capability through q (2) and to revise the respective OECD guidance document accordingly. The discussion includes a comparison between r (2) and q (2) value ranges and the q (2) statistics for cross-validation.
T. Raatikainen
2005-01-01
Full Text Available In this work, existing and modified activity coefficient models are examined in order to assess their capabilities to describe the properties of aqueous solution droplets relevant in the atmosphere. Five different water-organic-electrolyte activity coefficient models were first selected from the literature. Only one of these models included organics and electrolytes which are common in atmospheric aerosol particles. In the other models, organic species were solvents such as alcohols, and important atmospheric ions like NH4+ could be missing. The predictions of these models were compared to experimental activity and solubility data in aqueous single electrolyte solutions with 31 different electrolytes. Based on the deviations from experimental data and on the capabilities of the models, four predictive models were selected for fitting of new parameters for binary and ternary solutions of common atmospheric electrolytes and organics. New electrolytes (H+, NH4+, Na+, Cl-, NO3- and SO42- and organics (dicarboxylic and some hydroxy acids were added and some modifications were made to the models if it was found useful. All new and most of the existing parameters were fitted to experimental single electrolyte data as well as data for aqueous organics and aqueous organic-electrolyte solutions. Unfortunately, there are very few data available for organic activities in binary solutions and for organic and electrolyte activities in aqueous organic-electrolyte solutions. This reduces model capabilities in predicting solubilities. After the parameters were fitted, deviations from measurement data were calculated for all fitted models, and for different data types. These deviations and the calculated property values were compared with those from other non-electrolyte and organic-electrolyte models found in the literature. Finally, hygroscopic growth factors were calculated for four 100 nm organic-electrolyte particles and these predictions were compared to
[Influence of human activities on groundwater environment based on coefficient variation method].
Zhao, Wei; Lin, Jian; Wang, Shu-Fang; Liu, Ji-Lai; Chen, Zhong-Rong; Kou, Wen-Jie
2013-04-01
Groundwater system in the plain area of Beijing can be divided into six subsystems. Due to the different hydrogeological conditions of the subsystems, the degrees to which human activities affect the subsystems are also diverse. In order to evaluate the influence of human activities on each subsystem, the first and second aquifer with relatively poor water quality were chosen to be the evaluating positions, based on the data of groundwater sampled in September, 2011. With respect to human activities affect index such as total hardness, TDS, sulfate and ammonium, variation coefficient methods were used to calculate the weight of each index. Then scores were obtained for each index with national standard as reference, and superposition calculations were used to gain comprehensive scores, finally the groundwater quality conditions were evaluated. Contrast analyses were used to evaluate the incidence of human activities with groundwater subsystems as evaluation unit and water quality partitions as evaluation factors. The results indicate that the influence of human activities on the first aquifer is greater than that of the second aquifer, the Yongding river groundwater subsystems and the Chaobai river groundwater subsystems are affected more than other groundwater subsystems.
Huang, Congzhi; Sira-Ramírez, Hebertt
2015-12-01
A flatness-based active disturbance rejection control approach is proposed to deal with the linear systems with unknown time-varying coefficients and external disturbances. By selecting appropriate nominal values for the parameters of the system, all the deviation between the nominal and actual dynamics of the controlled process, as well as all the external disturbances can be viewed as a total disturbance. Based on the accurately estimated total disturbance with the aid of the proposed extended state observer, a linear proportional derivative feedback control law taking into account the derivatives of the desired output is designed to eliminate the effect of the total disturbance on the system performance. Finally, the load frequency control problem of a single-area power system with non-reheated unit is employed as an illustrative example to demonstrate the effectiveness of the proposed approach.
Dallaudière, Benjamin, E-mail: benjamin.dallaudiere@gmail.com [Hôpital Bichat – Claude Bernard, Service de Radiologie, 46, rue Henri Huchard, Paris 75018 (France); Hôpital Bichat – Claude Bernard, Inserm U698, 46, rue Henri Huchard, Paris 75018 (France); Université Paris Diderot, Paris (France); Dautry, Raphaël, E-mail: raphael_dautry@yahoo.fr [Hôpital Bichat – Claude Bernard, Service de Radiologie, 46, rue Henri Huchard, Paris 75018 (France); Université Paris Diderot, Paris (France); Preux, Pierre-Marie, E-mail: pierre-marie.preux@unilim.fr [Faculté de Médecine de Limoges, Unité fonctionelle de recherche clinique et de biostatistique, hôpital Le Cluzeau, 23, avenue Dominique Larrey, 87042 Limges Cedex (France); Perozziello, Anne, E-mail: aperozziello@gmail.com [Université Paris Diderot, Paris (France); Hôpital Bichat – Claude Bernard, Unité de recherche clinique, 46, rue Henri Huchard, Paris 75018 (France); Lincot, Julien, E-mail: julienlincot@gmail.com [Hôpital Bichat – Claude Bernard, Service de Radiologie, 46, rue Henri Huchard, Paris 75018 (France); Schouman-Claeys, Elisabeth, E-mail: elisabeth.schouman-claeys@bch.aphp.fr [Hôpital Bichat – Claude Bernard, Service de Radiologie, 46, rue Henri Huchard, Paris 75018 (France); Université Paris Diderot, Paris (France); and others
2014-02-15
Objective: The goal of this study was to evaluate whether the values of ADC in spondylarthritis axial active inflammatory lesions are different from ADC values in type 1 Modic changes. Subjects and methods: 95 patients with recent lumbar pain, including 46 patients with diagnosed or suspected spondylarthritis and 49 patients with purely degenerative history, underwent spine MRI. T1w, STIR, and diffusion-weighted images (DWI) were obtained. Two musculoskeletal radiologists interpreted the images. Axial active inflammatory lesions from the SpA group and type 1 Modic changes from the degenerative group were identified on T1w and STIR sequences. ADC values from these lesions and from healthy subchondral bone were compared. Results: All axial active inflammatory lesions (n = 27) and type 1 Modic changes (n = 22) identified in T1w and STIR images were visible on DWI. ADC values were significantly higher (p < 0.05) for axial active inflammatory lesions (median = 0.788 × 10{sup −3} mm{sup 2}/s, IQR 25–75 [0.7 × 10{sup −3} mm{sup 2}/s; 0.9 × 10{sup −3} mm{sup 2}/s]) than for type 1 Modic changes (median = 0.585 × 10{sup −3} mm{sup 2}/s, IQR 25–75 [0.55 × 10{sup −3} mm{sup 2}/s; 0.60 × 10{sup −3} mm{sup 2}/s]) and normal subchondral bone (median = 0.443 × 10{sup −3} mm{sup 2}/s, IQR 25–75 [0.40 × 10{sup −3} mm{sup 2}/s; 0.50 × 10{sup −3} mm{sup 2}/s]). Intra-class correlation coefficients for intra- and inter-reader ADC values comparison were excellent (0.89 and 0.98 respectively). Conclusion: DWI is a sensitive and fast sequence that offer the possibility of quantifying diffusion coefficients of the lesions, which could help to discriminate between spondylarthritis axial active inflammatory and type 1 Modic changes.
A simple method of determination of partition coefficient for biologically active molecules.
Sersen, F
1995-02-01
A simple method is presented for the determination of partition coefficient of an effector between water environment and biological material, based on concentration-dependent effects. The method allows the determination of partition coefficients for biological objects such as algae, bacteria and other microorganisms.
Prediction of Infinite Dilution Activity Coefficients of Halogenated Hydrocarbons in Water
XU Hui-Ying; MIN Jian-Qing
2008-01-01
Geometrical optimization and electrostatic potential calculations have been performed for a series of halogenated hydrocarbons at the HF/Gen-6d level. A number of electrostatic potentials and the statistically based structural descriptors derived from these electrostatic potentials have been obtained. Multiple linear regression analysis and artificial neural network are employed simultaneously in this paper. The result shows that the parameters derived from electrostatic potentials σ2tot, Vs and ΣVs+, together with the molecular volume (Vmc) can be used to express the quantitative structure-infinite dilution activity coefficients (γ∞) relationship of halogenated hydrocarbons in water. The result also demonstrates that the model obtained by using BFGS quasi-Newton neural network method has much better predictive capability than that from multiple linear regression. The goodness of the model has been validated through exploring the predictive power for the external test set. The model obtained via neural network may be applied to predict γ∞ of other halogenated hydrocarbons not present in the data set.
Pomiès, M; Choubert, J M; Wisniewski, C; Miège, C; Budzinski, H; Coquery, M
2015-03-01
The nitrifying/denitrifying activated sludge process removes several micropollutants from wastewater by sorption onto sludge and/or biodegradation. The objective of this paper is to propose and evaluate a lab-scale experimental strategy for the determination of partition coefficient and biodegradation constant for micropollutant with an objective of modelling their removal. Four pharmaceutical compounds (ibuprofen, atenolol, diclofenac and fluoxetine) covering a wide hydrophobicity range (log Kow from 0.16 to 4.51) were chosen. Dissolved and particulate concentrations were monitored for 4 days, inside two reactors working under aerobic and anoxic conditions, and under different substrate feed conditions (biodegradable carbon and nitrogen). We determined the mechanisms responsible for the removal of the target compounds: (i) ibuprofen was biodegraded, mainly under aerobic conditions by cometabolism with biodegradable carbon, whereas anoxic conditions suppressed biodegradation; (ii) atenolol was biodegraded under both aerobic and anoxic conditions (with a higher biodegradation rate under aerobic conditions), and cometabolism with biodegradable carbon was the main mechanism; (iii) diclofenac and fluoxetine were removed by sorption only. Finally, the abilities of our strategy were evaluated by testing the suitability of the parameters for simulating effluent concentrations and removal efficiency at a full-scale plant.
Zarubin, Dmitri P., E-mail: dmitri.zarubin@mtu-net.ru [Department of Physical and Collod Chemistry, Moscow State University of Technology and Management, 73 Zemlyanoi Val, Moscow 109803 (Russian Federation)
2011-08-15
Highlights: > Problem of ionic activity coefficients, determined by potentiometry, is reconsidered. > They are found to be functions of mean activity coefficients and transport numbers of ions. > The finding is verified by calculations and comparing the results with reported data. > Calculations are performed for systems with single electrolytes and binary mixtures. - Abstract: Potentiometric measurements on cells with liquid junctions are sometimes used for calculations of single-ion activity coefficients in electrolyte solutions, the incidence of this being increased recently. As surmised by Guggenheim in the 1930s, such coefficients (of ions i), {gamma}{sub i}, are actually complicated functions of mean ionic activity coefficients, {gamma}{sub {+-}}, and transport numbers of ions, t{sub i}. In the present paper specific functions {gamma}{sub i}({gamma}{sub {+-}}, t{sub i}) are derived for a number of cell types with an arbitrary mixture of strong electrolytes in a one-component solvent in the liquid-junction system. The cell types include cells with (i) identical electrodes, (ii) dissimilar electrodes reversible to the same ions, (iii) dissimilar electrodes reversible to ions of opposite charge signs, (iv) dissimilar electrodes reversible to different ions of the same charge sign, and (v) identical reference electrodes and an ion-selective membrane permeable to ions of only one type. Pairs of functions for oppositely charged ions are found to be consistent with the mean ionic activity coefficients as would be expected for pairs of the proper {gamma}{sub i} quantities by definition of {gamma}{sub {+-}}. The functions are tested numerically on some of the reported {gamma}{sub i} datasets that are the more tractable. A generally good agreement is found with data reported for cells with single electrolytes HCl and KCl in solutions, and with binary mixtures in the liquid-junction systems of KCl from the reference solutions and NaCl and HCl from the test solutions. It
Experimental Identification of Dynamic Coefficients of Tilting-Pad Bearings with Active Lubrication
Salazar, Jorge Andrés González; Cerda Varela, Alejandro Javier; Santos, Ilmar
This article presents the experimental identification of the equivalent dynamic coefficients of an activelylubricated bearing under different lubrication regimes, namely: passive (no injection flow), hybrid (constant injection flow) and feedback-controlled (variable injection flow) lubrication. T...
Activity Coefficients for NaBr in Aqueous D-Trehalose/D-Cellobiose Solutions at 298.15 K
ZHUO,Kelei; WANG,Wenhao; CHEN,Yujuan; WANG,Jianji
2009-01-01
The ionic mean activity coefficients of NaBr in trehalose-water and cellobiose-water mixtures have been experimentally determined at 298.15 K from electrochemical potential measurements by an electrochemical cell conraining two ion selective electrodes (ISE),together with the activity coefficients of the disaccharides.The parameters C1 representing the pair interactions between the disaccharides and NaBr have been obtained.The interactions of NaBr with trehaiose,cellobiose and glucose were compared and discussed in terms of their difference in the stereo-structures.
Sheikholeslami, Paniz; Dehghani, M. R.; Safahieh, Tina
2016-08-01
An electrochemical cell with two ion-selective electrodes (Na+ glass) and (Cl- solid state) was used to measure the mean ionic activity coefficient of NaCl in an aqueous mixture containing NaCl, glycine, and NaNO3 at 308.15 K. The experiments were conducted at fixed molality of NaNO3 (0.1 m) and various molalities of glycine (0-1 m) and NaCl (up to 0.8 m). The experimental data were modeled using a modified version of the Pitzer equation. Finally the activity coefficient ratio of glycine was determined based on the Maxwell equation.
Lorentz JÄNTSCHI
2006-01-01
Full Text Available Octanol-water partition coefficient of two hundred and six polychlorinated biphenyls was model by the use of an original method based on complex information obtained from compounds structure. The regression analysis shows that best results are obtained in four-varied model (r2 = 0.9168. The prediction ability of the model was studied through leave-one-out analysis (r2cv(loo = 0.9093 and in training and test sets analysis. Modeling the octanol-water partition coefficient of polychlorinated biphenyls by integration of complex structural information provide a stable and performing four-varied model, allowing us to make remarks about relationship between structure of polychlorinated biphenyls and associated octanol-water partition coefficients.
ZHU Jiqin; YU Yanmei; CHEN Jian; FEI Weiyang
2007-01-01
The separations of olefin/paraffin,aromatic/aliphatic hydrocarbons or olefin isomers using ionic liquids instead of volatile solvents have interested many researchers.Activity coefficients γ∞ at infinite dilution of a solute in ionic liquid are generally used in the selection of solvents for extraction or extractive distillation.In fact,the measurement of γ∞ by gas-liquid chromatography is a speedy and costsaving method.Activity coefficients at infinite dilution of hydrocarbon solutes,such as alkanes,hexenes,alkylbenzenes,styrene,in 1-allyl-3-methylimidazolium tetrafluoroborate ([AMIM][BF4]) and 1-butyl-3-methyl imidazolium hexafluorophosphate ([BMIM][PF6]), 1-isobutenyl-3-methylimidazolium tetrafluoroborate ([MPMIM][BF4]) and [MPMIM][BF4]-AgBF4 have been determined by gas-liquid chromatography using ionic liquids as stationary phase.The measurements were carried out at different temperatures from 298 to 318 K.The separating effects of these ionic liquids for alkanes/hexane,aliphatic hydrocarbons/benzene and hexene isomers have been discussed.The hydrophobic parameter,dipole element,frontier molecular orbital energy gap and hydration energy of these hydrocarbons were calculated with the PM3 semi-empirical quantum chemistry method.The quantitative relations among the computed structure parameters and activity coefficients at infinite dilution were also developed.The experimental activity coefficient data are consistent with the correlated and predicted results using QSPR models.
Santos, Ilmar; Watanabe, F. Y.
2003-01-01
and control techniques. The feasibility of influencing the dynamic fluid film coefficients (stiffness and damping) by means of a controllable fluid injection into opposed bearing recesses is investigated. By controlling the pressure and flow injection using servo control systems, it is possible to obtain...... significant modifications of active hybrid forces, which can be useful while reducing vibration and stabilizing rotating machines....
Sloth, Peter
1993-01-01
The grand canonical ensemble has been used to study the evaluation of single ion activity coefficients in homogeneous ionic fluids. In this work, the Coulombic interactions are truncated according to the minimum image approximation, and the ions are assumed to be placed in a structureless, homoge...
Abildskov, Jens; Constantinou, Leonidas; Gani, Rafiqul
1996-01-01
A simple modification of group contribution based models for estimation of liquid phase activity coefficients is proposed. The main feature of this modification is that contributions estimated from the present first-order groups in many instances are found insufficient since the first-order groups...
Nami, Faezeh [Department of Chemistry, Shahid Beheshti University, G.C., Evin-Tehran 1983963113 (Iran, Islamic Republic of); Deyhimi, Farzad, E-mail: f-deyhimi@sbu.ac.i [Department of Chemistry, Shahid Beheshti University, G.C., Evin-Tehran 1983963113 (Iran, Islamic Republic of)
2011-01-15
To our knowledge, this work illustrates for the first time the ability of artificial neural network (ANN) to predict activity coefficients at infinite dilution for organic solutes in ionic liquids (ILs). Activity coefficient at infinite dilution ({gamma}{sup {infinity}}) is a useful parameter which can be used for the selection of effective solvent in the separation processes. Using a multi-layer feed-forward network with Levenberg-Marquardt optimization algorithm, the resulting ANN model generated activity coefficient at infinite dilution data over a temperature range of 298 to 363 K. The unavailable input data concerning softness (S) of organic compounds (solutes) and dipole moment ({mu}) of ionic liquids were calculated using GAMESS suites of quantum chemistry programs. The resulting ANN model and its validation are based on the investigation of up to 24 structurally different organic compounds (alkanes, alkenes, alkynes, cycloalkanes, aromatics, and alcohols) in 16 common imidazolium-based ionic liquids, at different temperatures within the range of 298 to 363 K (i.e. a total number of 914 {gamma}{sub Solute}{sup {infinity}}for each IL data point). The results show a satisfactory agreement between the predicted ANN and experimental data, where, the root mean square error (RMSE) and the determination coefficient (R{sup 2}) of the designed neural network were found to be 0.103, 0.996 for training data and 0.128, 0.994 for testing data, respectively.
Topping, David; Alibay, Irfan; Ruske, Simon; Hindriksen, Vincent; Noisternig, Michael
2016-04-01
To predict the evolving concentration, chemical composition and ability of aerosol particles to act as cloud droplets, we rely on numerical modeling. Mechanistic models attempt to account for the movement of compounds between the gaseous and condensed phases at a molecular level. This 'bottom up' approach is designed to increase our fundamental understanding. However, such models rely on predicting the properties of molecules and subsequent mixtures. For partitioning between the gaseous and condensed phases this includes: saturation vapour pressures; Henrys law coefficients; activity coefficients; diffusion coefficients and reaction rates. Current gas phase chemical mechanisms predict the existence of potentially millions of individual species. Within a dynamic ensemble model, this can often be used as justification for neglecting computationally expensive process descriptions. Indeed, on whether we can quantify the true sensitivity to uncertainties in molecular properties, even at the single aerosol particle level it has been impossible to embed fully coupled representations of process level knowledge with all possible compounds, typically relying on heavily parameterised descriptions. Relying on emerging numerical frameworks, and designed for the changing landscape of high-performance computing (HPC), in this study we show that comprehensive microphysical models from single particle to larger scales can be developed to encompass a complete state-of-the-art knowledge of aerosol chemical and process diversity. We focus specifically on the ability to capture activity coefficients in liquid solutions using the UNIFAC method, profiling traditional coding strategies and those that exploit emerging hardware.
LI Chunxiang; ZHOU Dai
2004-01-01
The polynomial matrix using the block coefficient matrix representation auto-regressive moving average (referred to as the PM-ARMA) model is constructed in this paper for actively controlled multi-degree-of-freedom (MDOF) structures with time-delay through equivalently transforming the preliminary state space realization into the new state space realization. The PM-ARMA model is a more general formulation with respect to the polynomial using the coefficient representation auto-regressive moving average (ARMA) model due to its capability to cope with actively controlled structures with any given structural degrees of freedom and any chosen number of sensors and actuators. (The sensors and actuators are required to maintain the identical number.) under any dimensional stationary stochastic excitation.
Activity coefficients of CaCl{sub 2} in (maltose + water) and (lactose + water) mixtures at 298.15 K
Zhuo Kelei [School of Chemistry and Environmental Science, Henan Normal University, Xinxiang, Henan 453007 (China)], E-mail: klzhuo@263.net; Liu Hongxun; Zhang Honghao; Liu Yaohui; Wang Jianji [School of Chemistry and Environmental Science, Henan Normal University, Xinxiang, Henan 453007 (China)
2008-05-15
Activity coefficients of CaCl{sub 2} in disaccharide {l_brace}(maltose, lactose) + water{r_brace} mixtures at 298.15 K were determined by cell potentials. The molalities of CaCl{sub 2} ranged from about 0.01 mol . kg{sup -1} to 0.20 mol . kg{sup -1}, the mass fractions of maltose from 0.05 to 0.25, and those of lactose from 0.025 to 0.125. The cell potentials were analyzed by using the Debye-Hueckel extended equation and the Pitzer equation. The activity coefficients obtained from the two theoretical models are in good agreement with each other. Gibbs free energy interaction parameters (g{sub ES}) and salting constants (k{sub S}) were also obtained. These were discussed in terms of the stereo-chemistry of saccharide molecules and the structural interaction model.
Valiskó, Mónika; Boda, Dezső, E-mail: boda@almos.vein.hu [Department of Physical Chemistry, University of Pannonia, P.O. Box 158, H-8201 Veszprém (Hungary)
2014-06-21
Our implicit-solvent model for the estimation of the excess chemical potential (or, equivalently, the activity coefficient) of electrolytes is based on using a dielectric constant that depends on the thermodynamic state, namely, the temperature and concentration of the electrolyte, ε(c, T). As a consequence, the excess chemical potential is split into two terms corresponding to ion-ion (II) and ion-water (IW) interactions. The II term is obtained from computer simulation using the Primitive Model of electrolytes, while the IW term is estimated from the Born treatment. In our previous work [J. Vincze, M. Valiskó, and D. Boda, “The nonmonotonic concentration dependence of the mean activity coefficient of electrolytes is a result of a balance between solvation and ion-ion correlations,” J. Chem. Phys. 133, 154507 (2010)], we showed that the nonmonotonic concentration dependence of the activity coefficient can be reproduced qualitatively with this II+IW model without using any adjustable parameter. The Pauling radii were used in the calculation of the II term, while experimental solvation free energies were used in the calculation of the IW term. In this work, we analyze the effect of the parameters (dielectric constant, ionic radii, solvation free energy) on the concentration and temperature dependence of the mean activity coefficient of NaCl. We conclude that the II+IW model can explain the experimental behavior using a concentration-dependent dielectric constant and that we do not need the artificial concept of “solvated ionic radius” assumed by earlier studies.
Valiskó, Mónika; Boda, Dezső
2014-06-21
Our implicit-solvent model for the estimation of the excess chemical potential (or, equivalently, the activity coefficient) of electrolytes is based on using a dielectric constant that depends on the thermodynamic state, namely, the temperature and concentration of the electrolyte, ε(c, T). As a consequence, the excess chemical potential is split into two terms corresponding to ion-ion (II) and ion-water (IW) interactions. The II term is obtained from computer simulation using the Primitive Model of electrolytes, while the IW term is estimated from the Born treatment. In our previous work [J. Vincze, M. Valiskó, and D. Boda, "The nonmonotonic concentration dependence of the mean activity coefficient of electrolytes is a result of a balance between solvation and ion-ion correlations," J. Chem. Phys. 133, 154507 (2010)], we showed that the nonmonotonic concentration dependence of the activity coefficient can be reproduced qualitatively with this II+IW model without using any adjustable parameter. The Pauling radii were used in the calculation of the II term, while experimental solvation free energies were used in the calculation of the IW term. In this work, we analyze the effect of the parameters (dielectric constant, ionic radii, solvation free energy) on the concentration and temperature dependence of the mean activity coefficient of NaCl. We conclude that the II+IW model can explain the experimental behavior using a concentration-dependent dielectric constant and that we do not need the artificial concept of "solvated ionic radius" assumed by earlier studies.
Panin, V Y; Aykac, M; Casey, M E
2013-06-07
The simultaneous PET data reconstruction of emission activity and attenuation coefficient distribution is presented, where the attenuation image is constrained by exploiting an external transmission source. Data are acquired in time-of-flight (TOF) mode, allowing in principle for separation of emission and transmission data. Nevertheless, here all data are reconstructed at once, eliminating the need to trace the position of the transmission source in sinogram space. Contamination of emission data by the transmission source and vice versa is naturally modeled. Attenuated emission activity data also provide additional information about object attenuation coefficient values. The algorithm alternates between attenuation and emission activity image updates. We also proposed a method of estimation of spatial scatter distribution from the transmission source by incorporating knowledge about the expected range of attenuation map values. The reconstruction of experimental data from the Siemens mCT scanner suggests that simultaneous reconstruction improves attenuation map image quality, as compared to when data are separated. In the presented example, the attenuation map image noise was reduced and non-uniformity artifacts that occurred due to scatter estimation were suppressed. On the other hand, the use of transmission data stabilizes attenuation coefficient distribution reconstruction from TOF emission data alone. The example of improving emission images by refining a CT-based patient attenuation map is presented, revealing potential benefits of simultaneous CT and PET data reconstruction.
Mester, Zoltan; Panagiotopoulos, Athanassios Z.
2015-07-01
The mean ionic activity coefficients of aqueous KCl, NaF, NaI, and NaCl solutions of varying concentrations have been obtained from molecular dynamics simulations following a recently developed methodology based on gradual insertions of salt molecules [Z. Mester and A. Z. Panagiotopoulos, J. Chem. Phys. 142, 044507 (2015)]. The non-polarizable ion models of Weerasinghe and Smith [J. Chem. Phys. 119, 11342 (2003)], Gee et al. [J. Chem. Theory Comput. 7, 1369 (2011)], Reiser et al. [J. Chem. Phys. 140, 044504 (2014)], and Joung and Cheatham [J. Phys. Chem. B 112, 9020 (2008)] were used along with the extended simple point charge (SPC/E) water model [Berendsen et al., J. Phys. Chem. 91, 6269 (1987)] in the simulations. In addition to the chemical potentials in solution used to obtain the activity coefficients, we also calculated the chemical potentials of salt crystals and used them to obtain the solubility of these alkali halide models in SPC/E water. The models of Weerasinghe and Smith [J. Chem. Phys. 119, 11342 (2003)] and Gee et al. [J. Chem. Theory Comput. 7, 1369 (2011)] provide excellent predictions of the mean ionic activity coefficients at 298.15 K and 1 bar, but significantly underpredict or overpredict the solubilities. The other two models generally predicted the mean ionic activity coefficients only qualitatively. With the exception of NaF for which the solubility is significantly overpredicted, the model of Joung and Cheatham predicts salt solubilities that are approximately 40%-60% of the experimental values. The models of Reiser et al. [J. Chem. Phys. 140, 044504 (2014)] make good predictions for the NaCl and NaI solubilities, but significantly underpredict the solubilities for KCl and NaF. We also tested the transferability of the models to temperatures much higher than were used to parametrize them by performing simulations for NaCl at 373.15 K and 1 bar, and at 473.15 K and 15.5 bar. All models overpredict the drop in the values of mean ionic
Hintermüller, M.
2008-06-01
An output-least-squares formulation for a class of parameter identification problems for elliptic variational inequalities is considered. Based on the concept of C-stationarity an active set type solver with feasibility restoration is introduced. It is shown that the new method relates to the so-called implicit programming techniques in the context of mathematical programs with equilibrium constraints. In the discrete setting, in order to overcome the ill-posedness of the problem, the parameter of interest is discretized on a coarser mesh than the state of the system. In addition, if the parameter corresponds to the coefficient in the bilinear form of the underlying differential operator, an interior-point treatment is employed to maintain the coercivity of the elliptic operator. Moreover, the computational domain for the coefficient depends on the measurement data. The paper ends with a report on numerical tests including an application to a simplified lubrication problem in a rolling element device.
Delgado, Eduardo J.; Alderete, Joel B.
2001-11-30
A quantitative structure-property relationship (QSPR) model is developed to correlate the natural logarithm of infinite dilution activity coefficients, ln (gamma(infinity)), of 45 chlorinated organic compounds in aqueous solution from quantum-chemical descriptors. The best correlation equation contains five theoretical molecular descriptors. All descriptors were obtained from the chemical structure of the compounds and have definite physical meaning corresponding to different intermolecular interactions. The model predicts ln (gamma(infinity)) with a correlation coefficients of 0.949 and a standard error of 0.442 ln units. The obtained QSPR equation may be applied to the prediction of gamma(infinity) of other chlorinated organic compounds not present in the data set used for the development of the present model. Copyright 2001 John Wiley & Sons, Inc. J Comput Chem 22: 1851-1856, 2001
Measurement of gas/water uptake coefficients for trace gases active in the marine environment
Davidovits, P. (Boston Coll., Chestnut Hill, MA (United States). Dept. of Chemistry); Worsnop, D.W.; Zahniser, M.S.; Kolb, C.E. (Aerodyne Research, Inc., Billerica, MA (United States). Center for Chemical and Environmental Physics)
1992-02-01
Ocean produced reduced sulfur compounds including dimethylsulfide (DMS), hydrogen sulfide (H{sub 2}S), carbon disulfide (CS{sub 2}), methyl mercaptan (CH{sub 3}CH) and carbonyl sulfide (OCS) deliver a sulfur burden to the atmosphere which is roughly equal to sulfur oxides produced by fossil fuel combustion. These species and their oxidation products dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO{sub 2}) and methane sulfonic acid (MSA) dominate aerosol and CCN production in clean marine air. Furthermore, oxidation of reduced sulfur species will be strongly influenced by NO{sub x}/O{sub 3} chemistry in marine atmospheres. The multiphase chemical processes for these species must be understood in order to study the evolving role of combustion produced sulfur oxides over the oceans. We have measured the chemical and physical parameters affecting the uptake of reduced sulfur compounds, their oxidation products, ozone, and nitrogen oxides by the ocean's surface, and marine clouds, fogs, and aerosols. These parameters include: gas/surface mass accommodation coefficients; physical and chemically modified (effective) Henry's law constants; and surface and liquid phase reaction constants. These parameters are critical to understanding both the interaction of gaseous trace species with cloud and fog droplets and the deposition of trace gaseous species to dew covered, fresh water and marine surfaces.
Cerda Varela, Alejandro Javier; Santos, Ilmar
2015-01-01
This paper deals with the validation of the mathematical model for predicting the equivalent stiffness and damping of an active tilting-pad bearing. The active bearing design includes an injection nozzle in the pad and a hydraulic supply system featuring a servovalve, which enables to modify the ...
Tono-oka, T; Kaneko, I
1993-05-01
The daily level of physical activity was estimated using the heart rate monitor, PE3000 (Polar Electro, Finland). The level was expressed with the coefficient of variation (CV) of heart rates recorded from waking time to dinner time. In the course of a day of intense physical activity, CV was confirmed to rise significantly. Then the CV was estimated and compared among 3 age classes, young (10-18 years), middle-aged (30-47 years), and elderly (62-76 years). The CVs of young people were significantly higher than those of middle-aged (P < 0.001) and elderly (P < 0.01), regardless of sex. However there was no significant sex difference in all age classes. These results suggest that the CV is an accurate index of daily physical activity. Thus clinicians can use the CV of heart rates to estimate the level of physical activity of individuals which closely relates to QOL.
Moučka, Filip; Nezbeda, Ivo; Smith, William R
2015-04-14
We describe a computationally efficient molecular simulation methodology for calculating the concentration dependence of the chemical potentials of both solute and solvent in aqueous electrolyte solutions, based on simulations of the salt chemical potential alone. We use our approach to study the predictions for aqueous NaCl solutions at ambient conditions of these properties by the recently developed polarizable force fields (FFs) AH/BK3 of Kiss and Baranyai (J. Chem. Phys. 2013, 138, 204507) and AH/SWM4-DP of Lamoureux and Roux (J. Phys. Chem. B 2006, 110, 3308 - 3322) and by the nonpolarizable JC FF of Joung and Cheatham tailored to SPC/E water (J. Phys. Chem. B 2008, 112, 9020 - 9041). We also consider their predictions of the concentration dependence of the electrolyte activity coefficient, the crystalline solid chemical potential, the electrolyte solubility, and the solution specific volume. We first highlight the disagreement in the literature concerning calculations of solubility by means of molecular simulation in the case of the JC FF and provide strong evidence of the correctness of our methodology based on recent independently obtained results for this important test case. We then compare the predictions of the three FFs with each other and with experiment and draw conclusions concerning their relative merits, with particular emphasis on the salt chemical potential and activity coefficient vs concentration curves and their derivatives. The latter curves have only previously been available from Kirkwood-Buff integrals, which require approximate numerical integrations over system pair correlation functions at each concentration. Unlike the case of the other FFs, the AH/BK3 curves are nearly parallel to the corresponding experimental curves at moderate and higher concentrations. This leads to an excellent prediction of the water chemical potential via the Gibbs-Duhem equation and enables the activity coefficient curve to be brought into excellent agreement
Martins, Mónia A. R.; Coutinho, João A. P.; Pinho, Simão; Domańska, Urszula
2015-01-01
The activity coefficients at infinite dilution, gamma(infinity)(13), of 55 organic solutes and water in three ionic liquids with the common cation 1-butyl-3-methylimidazolium and the polar anions Cl--,Cl- [CH3SO3](-) and [(CH3)(2)PO4](-), were determined by (gas + liquid) chromatography at four temperatures in the range (358.15 to 388.15) K for alcohols and water, and T = (398.15 to 428.15) K for the other organic solutes including alkanes, cycloalkanes, alkenes, cycloalkenes, alkynes, ketone...
On Implicit Active Constraints in Linear Semi-Infinite Programs with Unbounded Coefficients
Goberna, M. A., E-mail: mgoberna@ua.es [Alicante University, Dep. of Statistics and Operations Research (Spain); Lancho, G. A., E-mail: lanchoga@mixteco.utm.mx [Universidad Tecnologica de Mixteca, Instituto de Fisica y Matematicas (Mexico); Todorov, M. I., E-mail: maxim.todorov@udlap.mx [UDLA, Dep. of Physics and Mathematics (Mexico); Vera de Serio, V. N., E-mail: vvera@uncu.edu.ar [Universidad Nacional de Cuyo, Facultad de Ciencias Economicas, Instituto de Ciencias Basicas (Argentina)
2011-04-15
The concept of implicit active constraints at a given point provides useful local information about the solution set of linear semi-infinite systems and about the optimal set in linear semi-infinite programming provided the set of gradient vectors of the constraints is bounded, commonly under the additional assumption that there exists some strong Slater point. This paper shows that the mentioned global boundedness condition can be replaced by a weaker local condition (LUB) based on locally active constraints (active in a ball of small radius whose center is some nominal point), providing geometric information about the solution set and Karush-Kuhn-Tucker type conditions for the optimal solution to be strongly unique. The maintaining of the latter property under sufficiently small perturbations of all the data is also analyzed, giving a characterization of its stability with respect to these perturbations in terms of the strong Slater condition, the so-called Extended-Nuernberger condition, and the LUB condition.
Debasmita Dash; Shekhar Kumar; C. Mallika; U. Kamachi Mudali
2012-01-01
Ion selective electrodes (ISEs) are used to measure the single-ion activity coefficients in aqueous solutions of KNO3 and KCl at 298.15 K against a double-junction reference electrode. The EMF responses of ISEs up to 0.01 m are plotted to obtain the slope and intercept values. The obtained slopes and intercepts are used in Nernst equation for higher concentrated solutions for calculation of individual ion activity coefficient. The mean ionic activity coefficients are estimated from single ion...
THE ROLE OF THE ACTIVITY COEFFICIENT OF THE HYDROGEN ION IN THE HYDROLYSIS OF GELATIN.
Northrop, J H
1921-07-20
1. The hydrolysis of gelatin at a constant hydrogen ion concentration follows the course of a monomolecular reaction for about one-third of the reaction. 2. If the hydrogen ion concentration is not kept constant the amount of hydrolysis in certain ranges of acidity is proportional to the square root of the time (Schütz's rule). 3. The velocity of hydrolysis in strongly acid solution (pH less than 2.0) is directly proportional to the hydrogen ion concentration as determined by the hydrogen electrode i.e., the "activity;" it is not proportional to the hydrogen ion concentration as determined by the conductivity ratio. 4. The addition of neutral salts increases the velocity of hydrolysis and the hydrogen ion concentration (as determined by the hydrogen electrode) to approximately the same extent. 5. The velocity in strongly alkaline solutions (pH greater than 10) is directly proportional to the hydroxyl ion concentration. 6. Between pH 2.0 and pH 10.0 the rate of hydrolysis is approximately constant and very much greater than would be calculated from the hydrogen and hydroxyl ion concentration. This may be roughly accounted for by the assumption that the uncombined gelatin hydrolyzes much more rapidly than the gelatin salt.
Out-of-field activity in the estimation of mean lung attenuation coefficient in PET/MR
Berker, Yannick, E-mail: yberker@ukaachen.de [Department of Physics of Molecular Imaging Systems, Institute for Experimental Molecular Imaging, RWTH Aachen University, Aachen (Germany); Salomon, André [X-Ray Imaging Systems, Philips Research, Eindhoven (Netherlands); Kiessling, Fabian [Institute for Experimental Molecular Imaging, RWTH Aachen University, Aachen (Germany); Schulz, Volkmar [Department of Physics of Molecular Imaging Systems, Institute for Experimental Molecular Imaging, RWTH Aachen University, Aachen (Germany); Philips Technologie GmbH Innovative Technologies, Research Laboratories, Aachen (Germany)
2014-01-11
In clinical PET/MR, photon attenuation is a source of potentially severe image artifacts. Correction approaches include those based on MR image segmentation, in which image voxels are classified and assigned predefined attenuation coefficients to obtain an attenuation map. In whole-body imaging, however, mean lung attenuation coefficients (LAC) can vary by a factor of 2, and the choice of inappropriate mean LAC can have significant impact on PET quantification. Previously, we proposed a method combining MR image segmentation, tissue classification and Maximum Likelihood reconstruction of Attenuation and Activity (MLAA) to estimate mean LAC values. In this work, we quantify the influence of out-of-field (OOF) accidental coincidences when acquiring data in a single bed position. We therefore carried out GATE simulations of realistic, whole-body activity and attenuation distributions derived from data of three patients. A bias of 15% was found and significantly reduced by removing OOF accidentals from our data, suggesting that OOF accidentals are the major contributor to the bias. We found approximately equal contributions from OOF scatter and OOF randoms, and present results after correction of the bias by rescaling of results. Results using temporal subsets suggest that 30-second acquisitions may be sufficient for estimation mean LAC with less than 5% uncertainty if mean bias can be corrected for. -- Highlights: • Variability of lung attenuation complicates PET attenuation correction in PET/MR. • Maximum Likelihood Reconstruction of Attenuation and Activity combined with MR image segmentation. • GATE simulations of PET acquisitions in a realistic scanner model. • Bias in full-body simulations explained by accidentals from outside the FOV.
Noort, van P.C.M.
2013-01-01
Abraham solvation equations find widespread use in environmental chemistry and pharmaco-chemistry. The coefficients in these equations, which are solvent (system) descriptors, are usually determined by fitting experimental data. To simplify the determination of these coefficients in Abraham solvatio
Porras, Simo P; Sarmini, Karim; Fanali, Salvatore; Kenndler, Ernst
2003-04-01
Association constants, Kc, were derived from the electrophoretic mobilities of the anionic solutes (seven benzoates with hydroxy or chloro substituents) by capillary zone electrophoresis in different solvent systems, consisting of binary mixtures of water with up to 20% (v/v) methanol or acetonitrile, respectively. The association constants expectedly are found to decrease with increasing organic solvent concentration. The effect of organic solvents on the Kc of the benzoates with beta-cyclodextrin was analyzed applying the concept of the transfer activity coefficient (or the medium effect). This concept enables the evaluation of the significance of the contributions of the individual species involved in the complexation equilibrium in the different solvents: the benzoate ion, beta-cyclodextrin, and the anionic benzoate-beta-cyclodextrin complex. The medium effect on benzoate was calculated from the change in acidity constant of benzoic acid in the different mixed solvents and the corresponding transfer activity coefficients of the proton and the molecular acid. The transfer activity coefficients for beta-cyclodextrin results from its solubility at saturation in the different solvents. In this way, an estimation of the standard free energy of transfer, deltaG(t)0, of each species involved in the complexation equilibrium was possible for the transfer from water into the respective mixed solvent. It was found that the organic solvents do not significantly affect deltaG(t)0 for the benzoate anion. However, the organic solvents play a different role concerning the stabilization of beta-cyclodextrin and the complex anion: whereas the addition of acetonitrile has nearly no influence on deltaG(t)0 of the anionic complex, the reduction in Kc is caused by the enhanced stabilization of beta-cyclodextrin (reflected by its better solubility). Addition of methanol, on the other hand, lowers the solubility of beta-cyclodextrin, thus giving positive values for deltaG(t)0. Thus
Michael F. Gray; Peter Zalupski; Mikael Nilsson
2013-08-01
Effective models for solvent extraction require accurate characterization of the nonideality effects for each component, including the extractants. In this study, the nonideal behavior of the industrial extractant di(2-ethylhexyl) phosphoric acid has been investigated using vapor pressure osmometry (VPO). From the osmometry data, activity coefficients for the HDEHP dimer were obtained based on a formulation of the regular solution theory of Scatchard and Hildebrand, and the Margules two- and three-suffix equations. The results show similarity with a slope-analysis based relation from previous literature, although important differences are highlighted. The work points towards VPO as a useful technique for this type of study, but care must be taken with the choice of standard and method of analysis.
Righter, K.; Pando, K.; Danielson, L. R.; Humayun, M.
2017-01-01
Earth's core contains approximately 10% of a light element that is likely a combination of S, C, Si, and O, with Si possibly being the most abundant light element. Si dissolved into Fe liquids can have a large effect on the magnitude of the activity coefficient of siderophile elements (SE) in Fe liquids, and thus the partitioning behavior of those elements between core and mantle. The effect of Si can be small such as for Ni and Co, or large such as for Mo, Ge, Sb, As. The effect of Si on many siderophile elements is unknown yet could be an important, and as yet unquantified, influence on the core-mantle partitioning of SE. Here we report new experiments designed to quantify the effect of Si on the partitioning of Pt (with Re and Ru in progress or planned) between metal and silicate melt. The results will be applied to Earth, for which we have excellent constraints on the mantle Pt concentrations.
Wu, Chuandong; Liu, Jiemin; Yan, Luchun; Chen, Haiying; Shao, Huiqi; Meng, Tian
2015-02-01
Odor activity value (OAV) has been widely used for the assessment of odor pollution from various sources. However, little attention has been paid to the extreme OAV variation and potential inaccuracies of odor contribution assessment caused by odor interaction effects. The objective of this study is to assess the odor interaction effect for precise assessment of odor contribution. In this paper, samples were collected from a food waste disposal plant, and analyzed by instrumental and olfactory method to conclude odorants' occurrence and OAV. Then odor activity value coefficient (γ) was first proposed to evaluate the type and the level of binary interaction effects based on determination of OAV variation. By multiplying OAV and γ, odor activity factor (OAF) was used to reflect the real OAV. Correlation between the sum of OAF and odor concentration reached 80.0 ± 5.7%, which was 10 times higher than the sum of OAV used before. Results showed that hydrogen sulfide contributed most (annual average 66.4 ± 15.8%) to odor pollution in the waste disposal plant. However, as odor intensity of samples in summer rising, odor contribution of trimethylamine increased to 48.3 ± 3.7% by the strong synergistic interaction effect, while odor contribution of phenol decreased to 0.1 ± 0.02% for the increasing antagonistic interaction effect.
Akiyama, T; Fozzard, H A
1975-11-01
Resting membrane potentials of rabbit right ventricular papillary muscles were measured in modified Tyrode's solutions that were isotonic (1.0 X T), hypertonic (1.58 X T), or hypotonic (0.76 X T) at eight different concentrations of external potassium, [K]o, ranging from 0.78 to 100 mM. The amount of hyperpolarization produced by exposure to the hypertonic solutions was relatively constant with an average of 4.6 mv at all levels of [K]o except 0.78 and 1.56 mM. This potential change is much less than the 10.6 mv which would be predicted if the papillary muscles behaved as nearly perfect osmometers and the activity coefficient of intracellular potassium (K) remained constant. The amount of depolarization produced by exposure to the 0.76 X T hypotonic solutions averaged 6.8 mv at all levels of [K]o except 0.78 mM; this value is close to the predicted value of 6.9 mv. Variations in the activity and the activity coefficient of intracellular K were introduced to explain these discrepancies. We estimated that the activity of intracellular K in 1.58 X T hypertonic solution was increased 15-23% compared with that in isotonic solution. This change is much less than the 58% that would be predicted if the papillary muscle behaved as a nearly perfect osmometer. We also estimated that the activity of intracellular K in 0.76 X T hypotonic solution fell 22-26%, which is very close to the predicted value of 24%. The activity coefficient of intracellular K appeared to fall in 1.58 X T hypertonic solution to about 0.76 of its value in isotonic solution. This decline in the estimated activity coefficient of intracellular K could not be attributed to an increase in Coulombic attractive and repulsive forces as predicted by the Debye-Hückel equation for a univalent electrolyte.
Tracy Burrows
2016-09-01
Full Text Available Objectives: The aims of the current study were to comprehensively assess the dietary intakes and diet quality of a sample of Australian competitive adolescent rugby union players and compare these intakes with National and Sports Dietitians Association (SDA Recommendations for adolescent athletes. A secondary aim investigated applying different physical activity level (PAL coefficients to determine total energy expenditure (TEE in order to more effectively evaluate the adequacy of energy intakes. Design: Cross-sectional. Methods: Anthropometrics and dietary intakes were assessed in 25 competitive adolescent male rugby union players (14 to 18 years old. Diet was assessed using the validated Australian Eating Survey (AES food frequency questionnaire and diet quality was assessed through the Australian Recommended Food Score. Results: The median dietary intakes of participants met national recommendations for percent energy (% E from carbohydrate, protein and total fat, but not carbohydrate intake when evaluated as g/day as proposed in SDA guidelines. Median intakes of fibre and micronutrients including calcium and iron also met national recommendations. Overall diet quality was classified as ‘good’ with a median diet quality score of 34 (out of a possible 73; however, there was a lack of variety within key food groups including carbohydrates and proteins. Non-core food consumption exceeded recommended levels at 38% of the daily total energy intake, with substantial contributions from takeaway foods and sweetened beverages. A PAL coefficient of 1.2–1.4 was found to best balance the energy intakes of these players in their pre-season. Conclusions: Adolescent rugby players met the percent energy recommendations for macronutrients and attained an overall ‘good’ diet quality score. However, it was identified that when compared to specific recommendations for athletes, carbohydrate intakes were below recommendations and these players in their
Burrows, Tracy; Harries, Simon K.; Williams, Rebecca L.; Lum, Cheryl; Callister, Robin
2016-01-01
Objectives: The aims of the current study were to comprehensively assess the dietary intakes and diet quality of a sample of Australian competitive adolescent rugby union players and compare these intakes with National and Sports Dietitians Association (SDA) Recommendations for adolescent athletes. A secondary aim investigated applying different physical activity level (PAL) coefficients to determine total energy expenditure (TEE) in order to more effectively evaluate the adequacy of energy intakes. Design: Cross-sectional. Methods: Anthropometrics and dietary intakes were assessed in 25 competitive adolescent male rugby union players (14 to 18 years old). Diet was assessed using the validated Australian Eating Survey (AES) food frequency questionnaire and diet quality was assessed through the Australian Recommended Food Score. Results: The median dietary intakes of participants met national recommendations for percent energy (% E) from carbohydrate, protein and total fat, but not carbohydrate intake when evaluated as g/day as proposed in SDA guidelines. Median intakes of fibre and micronutrients including calcium and iron also met national recommendations. Overall diet quality was classified as ‘good’ with a median diet quality score of 34 (out of a possible 73); however, there was a lack of variety within key food groups including carbohydrates and proteins. Non-core food consumption exceeded recommended levels at 38% of the daily total energy intake, with substantial contributions from takeaway foods and sweetened beverages. A PAL coefficient of 1.2–1.4 was found to best balance the energy intakes of these players in their pre-season. Conclusions: Adolescent rugby players met the percent energy recommendations for macronutrients and attained an overall ‘good’ diet quality score. However, it was identified that when compared to specific recommendations for athletes, carbohydrate intakes were below recommendations and these players in their pre
Luehrs, Dean C.; Hickey, James P.; Nilsen, Peter E.; Godbole, K.A.; Rogers, Tony N.
1995-01-01
A linear solvation energy relationship has been found for 353 values of the limiting adsorption coefficients of diverse chemicals: log K = −0.37 + 0.0341Vi − 1.07β + D + 0.65P with R = 0.951, s = 0.51, n = 353, and F = 818.0, where Vi is the intrinsic molar volume; β is a measure of the hydrogen bond acceptor strength of the solute; D is an index parameter for the research group which includes the effects of the different types of carbon used, the temperature, and the length of time allowed for the adsorption equilibrium to be established; and P is an index parameter for the flatness of the molecule. P is defined to be unity if there is an aromatic system in the molecule or if there is a double bond or series of conjugated double bonds with no more that one non-hydrogen atom beyond the double bond and zero otherwise. A slightly better fit is obtained if the two-thirds power of Vi is used as a measure of the surface area in place of the volume term: log K = −1.75 + 0.227V2/3 − 1.10β + D + 0.60P with R = 0.954, s = 0.49, n = 353, and F = 895.39. This is the first quantitative measure of the effect of the shape of the molecule on its tendency to be adsorbed on activated carbon.
Afzal, Waheed; Breil, Martin Peter; Théveneau, Pascal;
2009-01-01
In this work, we report the infinite dilution activity coefficients for four n-alkanes (n-pentane, n-hexane, n-heptane, and n-octane) in monoethylene glycol in the temperature range from 298 to 334 K and at atmospheric pressure. Experimental data were measured using a previously described inert g...
Hammers, W.E.; Meurs, G.J.; Ligny, C.L. de
1982-01-01
Literature data on activity coefficients of various solutes in water, of some tetraalkyl compounds in methanol-water mixture and of water in organic solvents have been correlated with the product of the molecular surface area of the solute and the solute-solvent interfacial tension at ambient
Osmotic and Activity Coefficients of the {xZnCl2 + (1 - x)ZnSO4}(aq) System at 298.15 K
Ninkovic, R; Miladinovic, J; Todorovic, M; Grujic, S; Rard, J A
2006-06-27
Isopiestic vapor pressure measurements were made for (xZnCl{sub 2} + (1 - x)ZnSO{sub 4})(aq) solutions with ZnCl{sub 2} molality fractions of x = (0, 0.3062, 0.5730, 0.7969, and 1) at the temperature 298.15 K, using KCl(aq) as the reference standard. These measurements cover the water activity range 0.901-0.919 {le} a{sub w} {le} 0.978. The experimental osmotic coefficients were used to evaluate the parameters of an extended ion-interaction (Pitzer) model for these mixed electrolyte solutions. A similar analysis was made of the available activity data for ZnCl{sub 2}(aq) at 298.15 K, while assuming the presence of equilibrium amounts of ZnCl{sup +}(aq) ion-pairs, to derive the ion-interaction parameters for the hypothetical pure binary electrolytes (Zn{sup 2+}, 2Cl{sup -}) and (ZnCl{sup +},Cl{sup -}). These parameters are required for the analysis of the mixture results. Although significant concentrations of higher-order zinc chloride complexes may also be present in these solutions, it was possible to represent the osmotic coefficients accurately by explicitly including only the predominant complex ZnCl{sup +}(aq) and the completely dissociated ions. The ionic activity coefficients and osmotic coefficients were calculated over the investigated molality range using the evaluated extended Pitzer model parameters.
Arakeri, Jaywant H.; Shukla, Ratnesh K.
2013-08-01
An analysis of the energy budget for the general case of a body translating in a stationary fluid under the action of an external force is used to define a power loss coefficient. This universal definition of power loss coefficient gives a measure of the energy lost in the wake of the translating body and, in general, is applicable to a variety of flow configurations including active drag reduction, self-propulsion and thrust generation. The utility of the power loss coefficient is demonstrated on a model bluff body flow problem concerning a two-dimensional elliptical cylinder in a uniform cross-flow. The upper and lower boundaries of the elliptic cylinder undergo continuous motion due to a prescribed reflectionally symmetric constant tangential surface velocity. It is shown that a decrease in drag resulting from an increase in the strength of tangential surface velocity leads to an initial reduction and eventual rise in the power loss coefficient. A maximum in energetic efficiency is attained for a drag reducing tangential surface velocity which minimizes the power loss coefficient. The effect of the tangential surface velocity on drag reduction and self-propulsion of both bluff and streamlined bodies is explored through a variation in the thickness ratio (ratio of the minor and major axes) of the elliptical cylinders.
Zhang Jun [Chemical Engineering Department, Henan University of Science and Technology, 48 Xiyuan Road, Luoyang, Henan 471003 (China)]. E-mail: zhjabc@mail.haust.edu.cn; Huang Xingyuan [Chemical Engineering Department, Henan University of Science and Technology, 48 Xiyuan Road, Luoyang, Henan 471003 (China); Xia Shuping [Institute of Salt Lakes, Chinese Academy of Sciences, Xi' an 710043 (China)
2005-11-15
Activity coefficients for rubidium chloride in the (RbCl+RbNO{sub 3}+H{sub 2}O) ternary system were determined from electromotive force (emf) measurements of the cell:Rb-ionselectiveelectrode(ISE) vertical bar RbCl(m{sub A}),RbNO{sub 3}(m{sub B}),H{sub 2}O vertical bar Ag vertical bar AgClat T=298.15 K and over total ionic strengths from (0.01 upto 3.50) mol.kg{sup -1}. The Rb{sup +} ion selective electrode (Rb-ISE) and Ag vertical bar AgCl electrode used in this work were made in our laboratory and had reasonably good Nernst responses, which demonstrate that the emf method can be applied to measure the above system with high precision. The experimental data were analyzed using the Harned rule and Pitzer model. The Harned coefficients and the Pitzer binary and ternary ionic interaction parameters for the system have been evaluated. The experimental results obey the Harned rule, and the Pitzer model can be used to describe this aqueous system satisfactorily. The activity coefficients of RbNO{sub 3}, the osmotic coefficients of the mixtures and the excess free energy of mixing were also calculated.
Fielitz, Peter; Borchardt, Günter
2016-08-10
In the dedicated literature the oxygen surface exchange coefficient KO and the equilibrium oxygen exchange rate [Fraktur R] are considered to be directly proportional to each other regardless of the experimental circumstances. Recent experimental observations, however, contradict the consequences of this assumption. Most surprising is the finding that the apparent activation energy of KO depends dramatically on the kinetic regime in which it has been determined, i.e. surface exchange controlled vs. mixed or diffusion controlled. This work demonstrates how the diffusion boundary condition at the gas/solid interface inevitably entails a correlation between the oxygen surface exchange coefficient KO and the oxygen self-diffusion coefficient DO in the bulk ("on top" of the correlation between KO and [Fraktur R] for the pure surface exchange regime). The model can thus quantitatively explain the range of apparent activation energies measured in the different regimes: in the surface exchange regime the apparent activation energy only contains the contribution of the equilibrium exchange rate, whereas in the mixed or in the diffusion controlled regime the contribution of the oxygen self-diffusivity has also to be taken into account, which may yield significantly higher apparent activation energies and simultaneously quantifies the correlation KO ∝ DO(1/2) observed for a large number of oxides in the mixed or diffusion controlled regime, respectively.
Sauerwein, Meike; Clegg, Simon
2015-01-01
Alkylaminium sulfates are frequently detected in ambient aerosols, and are believed to be important in the nucleation of new particles in the atmosphere, despite their comparatively low gas phase concentrations. In this study water activities and osmotic coefficients have been measured, using a chilled mirror dew point technique, of aqueous mixtures of sulfuric acid and the following alkylaminium sulfates: methylaminium, ethylaminium, dimethylaminium, diethylaminium and trimethylaminium sulfa...
Yoshiki Matsuda
Full Text Available Onychomycosis is difficult to treat topically due to the deep location of the infection under the densely keratinized nail plate. In order to obtain an in vitro index that is relevant to the clinical efficacy of topical anti-onychomycosis drugs, we profiled five topical drugs: amorolfine, ciclopirox, efinaconazole, luliconazole, and terbinafine, for their nail permeabilities, keratin affinities, and anti-dermatophytic activities in the presence of keratin. Efinaconazole and ciclopirox permeated full-thickness human nails more deeply than luliconazole. Amorolfine and terbinafine did not show any detectable permeation. The free-drug concentration of efinaconazole in a 5% human nail keratin suspension was 24.9%, which was significantly higher than those of the other drugs (1.1-3.9%. Additionally, efinaconazole was released from human nail keratin at a greater proportion than the other drugs. The MICs of the five drugs for Trichophyton rubrum were determined at various concentrations of keratin (0-20% in RPMI 1640 medium. The MICs of ciclopirox were not affected by keratin, whereas those of efinaconazole were slightly increased and those of luliconazole and terbinafine were markedly increased in the presence of 20% keratin. Efficacy coefficients were calculated using the nail permeation flux and MIC in media without or with keratin. Efinaconazole showed the highest efficacy coefficient, which was determined using MIC in media with keratin. The order of efficacy coefficients determined using MIC in keratin-containing media rather than keratin-free media was consistent with that of complete cure rates in previously reported clinical trials. The present study revealed that efficacy coefficients determined using MIC in keratin-containing media are useful for predicting the clinical efficacies of topical drugs. In order to be more effective, topical drugs have to possess higher efficacy coefficients.
Matsuda, Yoshiki; Sugiura, Keita; Hashimoto, Takashi; Ueda, Akane; Konno, Yoshihiro; Tatsumi, Yoshiyuki
2016-01-01
Onychomycosis is difficult to treat topically due to the deep location of the infection under the densely keratinized nail plate. In order to obtain an in vitro index that is relevant to the clinical efficacy of topical anti-onychomycosis drugs, we profiled five topical drugs: amorolfine, ciclopirox, efinaconazole, luliconazole, and terbinafine, for their nail permeabilities, keratin affinities, and anti-dermatophytic activities in the presence of keratin. Efinaconazole and ciclopirox permeated full-thickness human nails more deeply than luliconazole. Amorolfine and terbinafine did not show any detectable permeation. The free-drug concentration of efinaconazole in a 5% human nail keratin suspension was 24.9%, which was significantly higher than those of the other drugs (1.1-3.9%). Additionally, efinaconazole was released from human nail keratin at a greater proportion than the other drugs. The MICs of the five drugs for Trichophyton rubrum were determined at various concentrations of keratin (0-20%) in RPMI 1640 medium. The MICs of ciclopirox were not affected by keratin, whereas those of efinaconazole were slightly increased and those of luliconazole and terbinafine were markedly increased in the presence of 20% keratin. Efficacy coefficients were calculated using the nail permeation flux and MIC in media without or with keratin. Efinaconazole showed the highest efficacy coefficient, which was determined using MIC in media with keratin. The order of efficacy coefficients determined using MIC in keratin-containing media rather than keratin-free media was consistent with that of complete cure rates in previously reported clinical trials. The present study revealed that efficacy coefficients determined using MIC in keratin-containing media are useful for predicting the clinical efficacies of topical drugs. In order to be more effective, topical drugs have to possess higher efficacy coefficients.
Elsa Moggia
2014-01-01
This work dealt with the computation of the mean activity coefficients of rare-earth halide aqueous solutions at 25°C, by means of the Quasi Random Lattice (QRL) model. The osmotic coefficients were then calculated consistently, through the integration of the Gibbs-Duhem equation. Using of QRL was mainly motivated by its dependence on one parameter, given in the form of an elec-trolyte-dependent concentration, which was also the highest concentration at which the model could be applied. For all the electrolyte solutions here considered, this parameter was experimentally known and ranged from 1.5 to 2.2 mol/kg, at 25 °C. Accordingly, rare-earth halide concentrations from strong dilution up to 2 mol/kg about could be considered without need for best-fit treatment in order to compute their osmotic and mean activity coefficients. The experimental knowledge about the parameter was an advantageous fea-ture of QRL compared to existing literature models. Following a trend already observed with low charge electrolytes, a satisfactory agreement was obtained with the experimental values for all the investigated rare-earth chlorides and bromides. For the sake of com-pactness, in this work the considered rare-earth halides were all belonging to the P63/m space group in their crystalline (anhydrous) form.
Burnett, RW; Covington, AK; FoghAndersen, N; Kulpmann, WR; Maas, AHJ; MullerPlathe, O; SiggaardAndersen, O; VanKessel, A; Wimberley, PD; Zijlstra, WG
1997-01-01
In principle, flame photometry measures substance concentration, and ion-selective electrodes (ISEs) measure ion activity. However, the situation regarding the comparison of results from the two techniques when applied to blood plasma is complex. The problem can be approached experimentally from the
Kubota, Y; Katano, H; Senda, M
2001-01-01
The ion-transfer reaction of local anesthetics at an organic solvent/water interface has been studied using cyclic voltammetry (CV) with a stationary nitrobenzene (NB)/water (W) interface. Procaine and seven other local anesthetics gave reversible or quasi-reversible voltammograms at the NB/W interface in the pH range between 0.9 and 9.6. These drugs are present in aqueous solution in either neutral or ionic form, or both forms. The half-wave potential, as determined by the midpoint potential in CV, vs. pH curves, were determined and analyzed to determine the partition coefficients of both neutral and ionic forms of the drugs between NB and W. The partition coefficients of the ionic forms were derived from their formal potential of transfer at an NB/W interface. The dissociation constants of ionic forms of the drugs in NB were also deduced. A high correlation between the pharmacological activity and the partition coefficient of the ionic form of amide-linked local anesthetics has been shown.
Miyano, Yoshimori [Department of Chemistry and Bioscience, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajimacho, Kurashiki 712-8505 (Japan)]. E-mail: miyano@chem.kusa.ac.jp
2005-05-15
Henry's law constants and infinite dilution activity coefficients of propane, propene, butane, isobutane, 1-butene, isobutene, trans-2-butene, and 1,3-butadiene in 1-pentanol, 2-pentanol in the temperature range of (250 to 330) K and 3-pentanol in the temperature range of (260 to 330) K were measured by a gas stripping method. A rigorous formula for evaluating the Henry's law constants from the gas stripping measurements was used for the data reduction of these highly volatile mixtures. The uncertainty is about 2% for the Henry's law constants and 3% for the estimated infinite dilution activity coefficients. In the evaluation of the infinite dilution activity coefficients, the nonideality of the solute such as the fugacity coefficient and Pointing correction factor cannot be neglected, especially at higher temperatures. The estimated uncertainty of the infinite dilution activity coefficients includes 1% for nonideality.
Valiskó, Mónika; Boda, Dezső
2014-01-01
We investigate the individual activity coefficients of pure 1:1 and 2:1 electrolytes using our theory that is based on the competition of ion-ion (II) and ion-water (IW) interactions (Vincze et al., J. Chem. Phys. 133, 154507, 2010). The II term is computed from Grand Canonical Monte Carlo simulations on the basis of the implicit solvent model of electrolytes using hard sphere ions with Pauling radii. The IW term is computed on the basis of Born's treatment of solvation using experimental hyd...
Hammers, W.E.; Meurs, G.J.; Ligny, C.L. de
1982-01-01
Literature data on activity coefficients of various solutes in water, of some tetraalkyl compounds in methanol-water mixture and of water in organic solvents have been correlated with the product of the molecular surface area of the solute and the solute-solvent interfacial tension at ambient temperature. The conditions for which this relationship holds are examined. The retentions of apolar solutes have been measured on LiChrosorb RP-18 using methanol-water mixtures as eluents at 25°C. The r...
Yang, Xue-min; Li, Jin-yan; Chai, Guo-Ming; Duan, Dong-ping; Zhang, Jian
2016-08-01
According to the experimental results of hot metal dephosphorization by CaO-based slags at a commercial-scale hot metal pretreatment station, activity a_{{{{P}}_{ 2} {{O}}_{ 5} }} of P2O5 in the CaO-based slags has been determined using the calculated comprehensive mass action concentration N_{{{{Fe}}t {{O}}}}{} of iron oxides by the ion and molecule coexistence theory (IMCT) for representing the reaction ability of Fe t O, i.e., activity of a_{{{{Fe}}t {{O}}}}{} . The collected ten models from the literature for predicting activity coefficient γ_{{{{P}}_{ 2} {{O}}_{ 5} }} of P2O5 in CaO-based slags have been evaluated based on the determined activity a_{{{{P}}_{ 2} {{O}}_{ 5} }} of P2O5 by the IMCT as the criterion. The collected ten models of activity coefficient γ_{{{{P}}_{ 2} {{O}}_{ 5} }} of P2O5 in CaO-based slags can be described in the form of a linear function as log γ_{{{{P}}_{ 2} {{O}}_{ 5} }} ≡ y = c0 + c1 x , in which independent variable x represents the chemical composition of slags, intercept c0 including the constant term depicts temperature effect and other unmentioned or acquiescent thermodynamic factors, and slope c1 is regressed by the experimental results. Thus, a general approach for obtaining good prediction results of activity a_{{{{P}}_{ 2} {{O}}_{ 5} }} of P2O5 in CaO-based slags is proposed by revising the constant term in intercept c0 for the collected ten models. The better models with an ideal revising possibility or flexibility in the collected ten models have been selected and recommended.
The toxicological and regulatory communities are currently exploring the use of free-ion-activity- models as a means of reducing uncertainties in current methods for assessing metals bioavailabi- lity from contaminated aquatic media. While most practitioners would support the des...
The toxicological and regulatory communities are currently exploring the use of the free-ion-activity (FIA) model both alone and in conjunction with the biotic ligand model (BLM) as a means of reducing uncertainties in current methods for assessing metals bioavailability from aqu...
T.V.S.L. Satyavani
2016-03-01
Full Text Available Cathode materials in nano size improve the performance of batteries due to the increased reaction rate and short diffusion lengths. Lithium Iron Phosphate (LiFePO4 is a promising cathode material for Li-ion batteries. However, it has its own limitations such as low conductivity and low diffusion coefficient which lead to high impedance due to which its application is restricted in batteries. In the present work, increase of conductivity with decreasing particle size of LiFePO4/C is studied. Also, the dependence of conductivity and activation energy for hopping of small polaron in LiFePO4/C on variation of particle size is investigated. The micro sized cathode material is ball milled for different durations to reduce the particle size to nano level. The material is characterized for its structure and particle size. The resistivities/dc conductivities of the pellets are measured using four probe technique at different temperatures, up to 150 °C. The activation energies corresponding to different particle sizes are calculated using Arrhenius equation. CR2032 cells are fabricated and electrochemical characteristics, namely, ac impedance and diffusion coefficients, are studied.
Vincze, Julianna; Valiskó, Mónika; Boda, Dezso
2010-10-21
We propose a simple model to explain the nonmonotonic concentration dependence of the mean activity coefficient of simple electrolytes without using any adjustable parameters. The primitive model of electrolytes is used to describe the interaction between ions computed by the adaptive grand canonical Monte Carlo method. For the dielectric constant of the electrolyte, we use experimental concentration dependent values. This is included through a solvation term in our treatment to describe the interaction between ions and water that changes as the dielectric constant changes with concentration. This term is computed by a Born-treatment fitted to experimental hydration energies. Our results for LiCl, NaCl, KCl, CsCl, NaBr, NaI, MgCl(2), CaCl(2), SrCl(2), and BaCl(2) demonstrate that the principal reason of the nonmonotonic behavior of the activity coefficient is a balance between the solvation and ion-ion correlation terms. This conclusion differs from previous studies that assumed that it is the balance of hard sphere repulsion and electrostatic attraction that produces the nonmonotonic behavior. Our results indicate that the earlier assumption that solvation can be taken into account by a larger, "solvated" ionic radius should be reconsidered. To explain second order effects (such as dependence on ionic size), we conclude that explicit water models are needed.
Long DI; Zongli LIN
2014-01-01
Active magnetic bearings (AMBs) have found a wide range of applications in high-speed rotating machinery industry. The instability and nonlinearity of AMBs make controller designs difficult, and when AMBs are coupled with a flexible rotor, the resulting complex dynamics make the problems of stabilization and disturbance rejection, which are critical for a stable and smooth operation of the rotor AMB system, even more difficult. Proportional-integral-derivative (PID) control dominates the current AMB applications in the field. Even though PID controllers are easy to implement, there are critical performance limitations associated with them that prevent the more advanced applications of AMBs, which usually require stronger robustness and performance offered by modern control methods such as H-infinity control andμ-synthesis. However, these advanced control designs rely heavily on the relatively accurate plant models and uncertainty characterizations, which are sometimes difficult to obtain. In this paper, we explore and report on the use of the characteristic model based all-coefficient adaptive control method to stabilize a flexible rotor AMB test rig. In spite of the simple structure of such a characteristic model based all-coefficient adaptive controller, both simulation and experimental results show its strong performance.
水-DMF-NaCl系统活度系数和粘度测定%Measurement of Activity Coefficient and Viscosity of Water-DMF-NaCl Mixture
秦原; 虞大红; 胡伟; 刘洪来; 胡英
2001-01-01
利用电池电动势法测定了298.15K下NaCl在不同DMF含量的水-DMF混合溶剂中的活度系数。结果表明，随着混合溶剂中DMF含量的增加NaCl的活度系数减小。测定了水-DMF-NaCl混合物在不同温度下的粘度。%Activity coefficients of NaCl in water-N,N-dimethylformamide (DMF) mixed solvents are determined at 298.15K by EMF measurement with sodium ion selective electrode and Ag-AgCl electrode. It is shown that the activity coefficient of NaCl decrease with the increase of concentration of DMF in mixed solvents. The viscosities of water-DMF-NaCl ternary system at different temperature have also been measured. The experimental viscosities have been correlated by using pseudo-binary solute aggregation model presented by Liu et al. The mean deviation between calculated results and experimental data is 2.5%.
Morteza Atabati
2012-01-01
A quantitative structure-property relationship （QSPR） study was suggested for the prediction of infinite dilution activity coefficients of halogenated hydrocarbons, γ∞ , in water at 298.15 K. After optimization of 3D geometry of the halogenated hydrocarbons with semi-empirical quantum chemical calculations at the AM1 level, different descriptors （1514 descriptors） were calculated by the HyperChem and Dragon softwares. A major problem of QSPR is the high dimensionality of the descriptor space; therefore, descriptor selection is the most important step. In this paper, an ant colony optimization （ACO） algorithm was proposed to select the best descriptors. Then the selected descriptors were applied for model development using multiple linear regression. The average absolute relative deviation and correlation coefficient for the training set were obtained as 4.36% and 0.951, respectively, while the corresponding values for the test set were 5.96% and 0.929, respectively. The results showed that the applied procedure is suitable for the prediction of γ∞ of halogenated hydrocarbons in water.
Righter, K.; Pando, K.; Danielson, L. R.; Humayun, M.; Righter, M.; Lapen, T.; Boujibar, A.
2016-01-01
Earth's core contains approximately 10 percent light elements that are likely a combination of S, C, Si, and O, with Si possibly being the most abundant. Si dissolved into Fe liquids can have a large effect on the magnitude of the activity coefficient of siderophile elements (SE) in Fe liquids, and thus the partitioning behavior of those elements between core and mantle. The effect of Si can be small such as for Ni and Co, or large such as for Mo, Ge, Sb, As. The effect of Si on many siderophile elements is unknown yet could be an important, and as yet unquantified, influence on the core-mantle partitioning of SE. Here we report new experiments designed to quantify the effect of Si on the partitioning of P, Au, Pd, and many other SE between metal and silicate melt. The results will be applied to Earth, for which we have excellent constraints on the mantle siderophile element concentrations.
Gwala, Nobuhle V. [Department of Chemistry, Durban University of Technology, P.O. Box 1334, Durban 4000 (South Africa); Deenadayalu, Nirmala, E-mail: NirmalaD@dut.ac.z [Department of Chemistry, Durban University of Technology, P.O. Box 1334, Durban 4000 (South Africa); Tumba, Kaniki; Ramjugernath, Deresh [Thermodynamics Research Unit, School of Chemical Engineering, University of KwaZulu-Natal, Howard College Campus, King George V Avenue, Durban 4001 (South Africa)
2010-02-15
The activity coefficient at infinite dilution (gamma{sub 13}{sup i}nfinity) for 30 solutes: alkanes, alkenes, cycloalkanes, alkynes, ketones, alcohols, and aromatic compounds was determined from gas-liquid chromatography (glc) measurements at three temperatures (303.15, 313.15, and 323.15) K. The ionic liquid: trioctylmethylammonium bis(trifluoromethylsulfonyl)imide, was used as the stationary phase. For each temperature, gamma{sub 13}{sup i}nfinity values were determined using two columns with different mass percent packing of the ionic liquid. The selectivity (S{sub 12}{sup i}nfinity) value was calculated from the gamma{sub 13}{sup i}nfinity to determine the suitability of the solvent as a potential entrainer for extractive distillation in the separation of an hexane/benzene mixture, indicative of a typical industrial separation problem for benchmarking purposes.
Wave Reflection Coefficient Spectrum
俞聿修; 邵利民; 柳淑学
2003-01-01
The wave reflection coefficient frequency spectrum and directional spectrum for concrete face slope breakwaters and rubble mound breakwaters are investigated through physical model tests in the present study. The reflection coefficients of oblique irregular waves are analyzed by the Modified Two-Point Method (MTPM) proposed by the authors. The results show that the wave reflection coefficient decreases with increasing wave frequency and incident angle or decreasing structure slope. The reflection coefficient frequency spectrum and its variation with Iribarren number are given in this paper. The paper also suggests an empirical 3-dimensional reflection coefficient spectrum, i.e. reflection coefficient directional spectrum, which can be used to illustrate quantitatively the variation of reflection coefficient with the incident angle and the Iribarren number for oblique irregular waves.
Miladinovic, J; Ninkovic, R; Todorovic, M; Rard, J A
2007-06-06
Isopiestic vapor pressure measurements were made for {l_brace}yMgCl{sub 2} + (1-y)MgSO{sub 4}{r_brace}(aq) solutions with MgCl{sub 2} ionic strength fractions of y = 0, 0.1997, 0.3989, 0.5992, 0.8008, and (1) at the temperature 298.15 K, using KCl(aq) as the reference standard. These measurements for the mixtures cover the ionic strength range I = 0.9794 to 9.4318 mol {center_dot} kg{sup -1}. In addition, isopiestic measurements were made with NaCl(aq) as reference standard for mixtures of {l_brace}xNa{sub 2}SO{sub 4} + (1-x)MgSO{sub 4}{r_brace}(aq) with the molality fraction x = 0.50000 that correspond to solutions of the evaporite mineral bloedite (astrakanite), Na{sub 2}Mg(SO{sub 4}){sub 2} {center_dot} 4H{sub 2}O(cr). The total molalities, m{sub T} = m(Na{sub 2}SO{sub 4}) + m(MgSO{sub 4}), range from m{sub T} = 1.4479 to 4.4312 mol {center_dot} kg{sup -1} (I = 5.0677 to 15.509 mol {center_dot} kg{sup -1}), where the uppermost concentration is the highest oversaturation molality that could be achieved by isothermal evaporation of the solvent at 298.15 K. The parameters of an extended ion-interaction (Pitzer) model for MgCl2(aq) at 298.15 K, which were required for an analysis of the {l_brace}yMgCl{sub 2} + (1-y)MgSO{sub 4}{r_brace}(aq) mixture results, were evaluated up to I = 12.025 mol {center_dot} kg{sup -1} from published isopiestic data together with the six new osmotic coefficients obtained in this study. Osmotic coefficients of {l_brace}yMgCl{sub 2} + (1-y)MgSO{sub 4}{r_brace}(aq) solutions from the present study, along with critically-assessed values from previous studies, were used to evaluate the mixing parameters of the extended ion-interaction model.
Activity coefficients of LiCl in (PEG 4000 + water) at T = (288.15, 298.15, and 308.15) K
Morales, Jaime W.; Galleguillos, Hector R.; Graber, Teofilo A. [Centro de Investigacion Cientifico y Tecnologico para la Mineria, Departamento de Ingenieria Quimica, Universidad de Antofagasta (Chile); Hernandez-Luis, Felipe, E-mail: ffhelu@ull.e [Departamento de Quimica Fisica, Universidad de La Laguna, Tenerife (Spain)
2010-10-15
The electromotive force of the cell containing two ion-selective electrodes (ISE), Na-ISE|LiCl(m),PEG4000(w),H{sub 2}O(1-w)|Cl-ISE has been measured at temperatures of (288.15, 298.15, and 308.15) K as a function of the mass fraction of PEG 4000 (w) in the mixture. w was varied between 0 and 0.25 in 0.05-unit steps and the molality of the electrolyte (m) was between c.a. (0.03 and 5.8) mol . kg{sup -1}. The values of the standard electromotive force, E{sup 0}, were determined using routine methods of extrapolation, together with extended Debye-Hueckel and Pitzer equations. The results obtained produced good internal consistency for all the temperatures studied. Once E{sup 0} was determined, the mean ionic activity coefficients for LiCl, the Gibbs free energy of transfer from the water to (PEG 4000 + water), and the primary LiCl hydration number were calculated.
Wu, Qihua; Zhang, Shuxiang; Zhu, Ping; Huang, Shaomin; Wang, Boren; Zhao, LinPing; Xu, Minggang
2017-01-01
The phosphorus activation coefficient (PAC, the ratio of available P to total P) is an important indicator of soil P availability and the transformation of P fractions. Understanding the details of the PAC is useful to estimate soil available P status and to provide P management guidance. In this research, soils from five long-term (23 years) fertilization treatments in three croplands were selected to examine the relationships between the PAC and P fractions and to analyse the influencing factors. PAC was affected by both soil types and fertilization treatments. Compared to the unfertilized control (CK) treatment, long-term P application significantly increased the PAC, all of the inorganic P (Pi) fractions and most of the organic P (Po) fractions in all the three soils, particularly in chemical fertilizer combined with manure treatment (NPKM). The PAC was significantly correlated to all of the Pi fractions proportions (Pvariance partitioning analysis showed that more variance of PAC is explained by soil factors (29.53%) than by P input (0.19%) and climate (0.25%) factors. Our findings demonstrate that P application increased the PAC by changing the Co content and the proportion of P fractions. Moreover, soil factors were the most important drivers of P transformations, and NPKM was optimal for improving soil fertility in Chinese croplands.
Shimazaki, M; Kikuchi, K; Yamaji, I; Kobayakawa, H; Yamamoto, M; Kudo, C; Wada, A; Mukai, H; Iimura, O
1991-01-01
The relationship between changes in sympathetic nerve activity and those in parasympathetic tone with a change in position was investigated in patients with essential hypertension using the coefficient of variation of RR intervals on electrocardiograms (CVRR). Mean arterial pressure (MAP), heart rate (HR), plasma noradrenaline concentration (pNA) and CVRR were measured in a supine position at rest and 20 min after having the head tilted 60 degrees superiorly in 10 normotensives (NT: 51.9 +/- 3.0 yrs) and 7 essential hypertensive patients (EHT: 51.0 +/- 2.8 yrs). After changing the position, CVRR decreased significantly in the NT, but not in the EHT; whereas, significant increases of both HR and pNA without significant changes in MAP were shown in both groups. A significant negative correlation between percentage changes in CVRR (% delta CVRR) and pNA (% delta pNA) were observed in the NT, but not in the EHT. However, there was no relationship of % delta CVRR to % delta MAP or to % delta HR in either group. It was suggested from the changes in CVRR that suppression of the parasympathetic tone, which occurs in the NT group corresponding to sympathetic augmentation to present a decrease in blood pressure with a change in position, may be impaired in the EHT group.
Modified Biserial Correlation Coefficients.
Kraemer, Helena Chmura
1981-01-01
Asymptotic distribution theory of Brogden's form of biserial correlation coefficient is derived and large sample estimates of its standard error obtained. Its relative efficiency to the biserial correlation coefficient is examined. Recommendations for choice of estimator of biserial correlation are presented. (Author/JKS)
李春喜; 宋红燕; 李以圭; 陆九芳
2001-01-01
An equation of state for electrolyte aqueous solution is developed by treating the ion-ion electrostatic and ion-solvent molecule interactions with primitive MSA and perturbation theory, respectively. The effect of the dielectric constant on the ionic chemical potential and the calculation accuracy of ionic mean activity coefficients for 2∶1 and 1∶1 type halide aqueous solution are discussed.By taking ionic Pauling diameter as ionic hard sphere diameter for anions and treating the cation hard sphere diameter as ionic strength dependent, the equation can be used to calculate ionic activity coefficients in the moderate concentration range with good accuracy.
Miki, Toshikatsu; Fujimoto, Akira; Jida, Shin'suke
1998-02-01
The mechanism of the electrical resistivity increase above the Curie temperature TC [so-called positive temperature coefficient of resistivity (PTCR) effect] in BaTi1-x-yNbxMnyO3 ceramics is studied with the temperature-dependent resistivity and electron paramagnetic resonance (EPR) data and the calculated energy levels of various Mn-associated centers. The activation energy of trapped electrons at grain boundary interface states is deduced from the resistivity data. The deduced value is found to be nearly equal to the activation energy of Mn2+ and/or singlet EPR signals. This indicates that the EPR signals arising at the cubic phase are due to trapped-electron centers at grain boundaries, and that the centers responsible for the EPR signals contribute to the rise of grain boundary barrier above TC. The PTCR mechanism is separately discussed for mode I of abrupt resistivity jump at TC and mode II of moderate resistivity increase at higher temperatures. From the analyses of resistivity and EPR data, we found that mode II PTCR is well explained by the Heywang model, but mode I PTCR is hardly explained only by the effect of spontaneous polarization proposed by Jonker. Defect models of Mn-VO, Mn-VO-Mn, and Mn-O-Nb-VO type are proposed for Mn associated centers and VBa-VO or VO-VTi-VO type for cation-vacancy-associated centers, taking the local electroneutrality requirement for stable defects and the electronic energy change of substitutional Mn by phase transitions into account. Changes of the electronic energy levels of such defects by phase transitions successfully explain not only the PTCR and EPR data but also the degraded PTCR by incomplete or overabundant oxidation. A part of the Mn-VO centers formed at low Mn contents release electrons at the tetragonal phase forming Mn3+-VO with an effective charge of +1 to act as a charge compensator for negatively charged acceptors at the grain boundary, but the Mn-VO centers hardly act as acceptor-type electron
Transport Coefficients of Fluids
Eu, Byung Chan
2006-01-01
Until recently the formal statistical mechanical approach offered no practicable method for computing the transport coefficients of liquids, and so most practitioners had to resort to empirical fitting formulas. This has now changed, as demonstrated in this innovative monograph. The author presents and applies new methods based on statistical mechanics for calculating the transport coefficients of simple and complex liquids over wide ranges of density and temperature. These molecular theories enable the transport coefficients to be calculated in terms of equilibrium thermodynamic properties, and the results are shown to account satisfactorily for experimental observations, including even the non-Newtonian behavior of fluids far from equilibrium.
Paduszyński, Kamil
2016-08-22
The aim of the paper is to address all the disadvantages of currently available models for calculating infinite dilution activity coefficients (γ(∞)) of molecular solutes in ionic liquids (ILs)-a relevant property from the point of view of many applications of ILs, particularly in separations. Three new models are proposed, each of them based on distinct machine learning algorithm: stepwise multiple linear regression (SWMLR), feed-forward artificial neural network (FFANN), and least-squares support vector machine (LSSVM). The models were established based on the most comprehensive γ(∞) data bank reported so far (>34 000 data points for 188 ILs and 128 solutes). Following the paper published previously [J. Chem. Inf. Model 2014, 54, 1311-1324], the ILs were treated in terms of group contributions, whereas the Abraham solvation parameters were used to quantify an impact of solute structure. Temperature is also included in the input data of the models so that they can be utilized to obtain temperature-dependent data and thus related thermodynamic functions. Both internal and external validation techniques were applied to assess the statistical significance and explanatory power of the final correlations. A comparative study of the overall performance of the investigated SWMLR/FFANN/LSSVM approaches is presented in terms of root-mean-square error and average absolute relative deviation between calculated and experimental γ(∞), evaluated for different families of ILs and solutes, as well as between calculated and experimental infinite dilution selectivity for separation problems benzene from n-hexane and thiophene from n-heptane. LSSVM is shown to be a method with the lowest values of both training and generalization errors. It is finally demonstrated that the established models exhibit an improved accuracy compared to the state-of-the-art model, namely, temperature-dependent group contribution linear solvation energy relationship, published in 2011 [J. Chem
Myint, P. C. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Hao, Y. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Firoozabadi, A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
2015-03-27
Thermodynamic property calculations of mixtures containing carbon dioxide (CO_{2}) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data [1]. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi [2], and the CO_{2} activity coefficient model by Duan and Sun [3]. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO_{2}, pure water, and both CO_{2}-rich and aqueous (H_{2}O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Sun’s model yields accurate results for the partial molar enthalpy of CO_{2}. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H_{2}O-CO_{2}-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.
孟玲菊; 玄兆坤; 焦连升
2013-01-01
离子液体受到结构上不对称性、静电作用等多种作用影响,系数特征容易发生形变,传统的测量方法在干扰状态下,很难准确测量.提出一种新的无限稀释活度系数测量模型(MCS-SVM).通过实验测量与无限稀释活度系数相关的溶质参数,并将它们分成为训练集和测试集；然后将训练集输入到一种最小二乘支持向量机分类模型,并测量活度系数,完成最优的无限稀释活度系数测量,消除测量误差.仿真结果表明,相对于传统测量方法可以准确描述无限稀释活度系数与溶质参数的非线性关系,提高了无限稀释活度系数的测量精度.%In order to improve prediction accuracy of the infinite dilution activity coefficient in ion liquid,a prediction model for infinite dilution activity coefficient based on cuckoo search algorithm and least squares support vector machine(MCS-SVM) is proposed.Firstly,the solute parameters of coefficients at infinite dilution are measured and divides into training set and test set; and then the training are input to the least squares support vector machine to train,and the cuckoo search algorithm is used to optimize the parameters of least squares support vector machine.Finally the optimal prediction model of the infinite dilution activity coefficient is established,and the simulation experiments were carried out to test the performance of model.The simulation results show that,compared with the multiple linear regression model and BP neural network,MCS-LSSVM can accurately describe the nonlinear relationship between the infinite dilution activity coefficient and solute parameters,and has improved the prediction accuracy of infinite dilution activity coefficient,provides a new research approach for infinite dilution activity coefficient which has the nonlinear characteristics.
Pfrang, Christian; King, Martin D.; Braeckevelt, Mareike; Canosa-Mas, Carlos E.; Wayne, Richard P.
Experimental difficulties sometimes force modellers to use predicted rate coefficients for reactions of oxygenated volatile organic compounds (oVOCs). We examine here methods for making the predictions for reactions of atmospheric initiators of oxidation, NO 3, OH, O 3 and O( 3P), with unsaturated alcohols and ethers. Logarithmic correlations are found between measured rate coefficients and calculated orbital energies, and these correlations may be used directly to estimate rate coefficients for compounds where measurements have not been performed. To provide a shortcut that obviates the need to calculate orbital energies, structure-activity relations (SARs) are developed. Our SARs are tested for predictive power against compounds for which experimental rate coefficients exist, and their accuracy is discussed. Estimated atmospheric lifetimes for oVOCs are presented. The SARs for alkenols successfully predict key rate coefficients, and thus can be used to enhance the scope of atmospheric models incorporating detailed chemistry. SARs for the ethers have more limited applicability, but can still be useful in improving tropospheric models.
Multidimensional extremal dependence coefficients
2017-01-01
Extreme values modeling has attracting the attention of researchers in diverse areas such as the environment, engineering, or finance. Multivariate extreme value distributions are particularly suitable to model the tails of multidimensional phenomena. The analysis of the dependence among multivariate maxima is useful to evaluate risk. Here we present new multivariate extreme value models, as well as, coefficients to assess multivariate extremal dependence.
Henao, Hector M.; Itagaki, Kimio
2007-10-01
At present, there is a scarcity of data on the activities of iron oxides in the FeO-Fe2O3-CaO-SiO2 slag system at intermediate oxygen partial pressures and temperatures relevant to sulfide smelting and nonferrous metallurgy. The present study provides relevant data at temperatures between 1573 and 1673 K and partial pressures of oxygen between 10-9 and 10-4 atm. The experiments were carried out by equilibrating the slag in a CO-CO2 gas mixture in a platinum crucible, after which the phases of all the experimental samples, including the platinum foil, were analyzed by electron probe microanalysis (EPMA). Where only liquid phase or liquid phase and tridymite (SiO2) were observed, wet chemical analysis was used to determine the ratio of (mass pct Fe2+)/(mass pct Fe3+). Activity and activity coefficients for FeO (liquid) and FeO1.33 (solid) were calculated. Tendencies of the effect of the (CaO/SiO2) ratio, temperature, and oxygen partial pressure on these thermochemical quantities are discussed in this article.
Prestarlike functions with negative coefficients
H. Silverman
1979-01-01
Full Text Available The extreme points for prestarlike functions having negative coefficients are determined. Coefficient, distortion and radii of univalence, starlikeness, and convexity theorems are also obtained.
Gorenstein Hilbert Coefficients
Khoury, Sabine El
2012-01-01
We prove upper and lower bounds for all the coefficients in the Hilbert Polynomial of a graded Gorenstein algebra $S=R/I$ with a quasi-pure resolution over $R$. The bounds are in terms of the minimal and the maximal shifts in the resolution of $R$ . These bounds are analogous to the bounds for the multiplicity found in \\cite{S} and are stronger than the bounds for the Cohen Macaulay algebras found in \\cite{HZ}.
Kontogeorgis, Georgios; Georgios, Nikolopoulos; Fredenslund, Aage
1997-01-01
of the generalized van der Waals partition function and attempts to account for all non-energetic effects of solutions of both short- and long-chain alkanes, including alkane polymers. Both the free-volume effects and the density-dependent rotational degrees of freedom are considered. The resulting G(E)-model which......, despite its derivation from a partition function resembles the Flory-Huggins formula, is suitable for vapor-liquid and solid-liquid equilibrium calculations for nearly athermal polymer solutions as well as for alkane systems. We show that using plausible assumptions for the free-volume and the external......-degree-of-freedom parameter, very good predictions are obtained for activity coefficients of asymmetric alkane systems at both concentration ends, for solid-liquid equilibrium calculations, as well as in extreme cases (polymer solutions, activity coefficients of heavy model alkane polymers in short-chain compounds recently...
Tumba, Kaniki; Reddy, Prashant; Naidoo, Paramespri [Thermodynamics Research Unit, School of Chemical Engineering, University of KwaZulu-Natal, Howard College Campus, King George V Avenue, Durban 4041 (South Africa); Ramjugernath, Deresh, E-mail: ramjuger@ukzn.ac.z [Thermodynamics Research Unit, School of Chemical Engineering, University of KwaZulu-Natal, Howard College Campus, King George V Avenue, Durban 4041 (South Africa)
2011-05-15
Research highlights: Activity coefficients at infinite dilution in the ionic liquid [3C{sub 6}C{sub 14}P][BF{sub 4}]. Twenty-seven solutes investigated at T = (313.15, 333.15, 353.15, and 373.15) K. [3C{sub 6}C{sub 14}P][BF{sub 4}] shows promise for the separation of aromatic and alcohol mixtures. - Abstract: Activity coefficients at infinite dilution have been measured by gas-liquid chromatography for 27 organic solutes (n-alkanes, 1-alkenes, 1-alkynes, cycloalkanes, aromatics, alcohols, and ketones) in the ionic liquid trihexyl(tetradecyl)phosphonium tetrafluoroborate [3C{sub 6}C{sub 14}P][BF{sub 4}]. The measurements were carried out at four different temperatures viz.T = (313.15, 333.15, 353.15, and 373.15) K. From the experimental data, partial molar excess enthalpy values at infinite dilution were calculated for the experimental temperature range. The selectivity values for the separation of n-hexane/benzene, cyclohexane/benzene, and methanol/benzene mixtures were determined from the experimental infinite dilution activity coefficient values. These values were compared to those available in the literature for other ionic liquids and commercial solvents, so as to assess the feasibility of employing [3C{sub 6}C{sub 14}P][BF{sub 4}] in solvent-enhanced industrial separations.
The Truth About Ballistic Coefficients
Courtney, Michael
2007-01-01
The ballistic coefficient of a bullet describes how it slows in flight due to air resistance. This article presents experimental determinations of ballistic coefficients showing that the majority of bullets tested have their previously published ballistic coefficients exaggerated from 5-25% by the bullet manufacturers. These exaggerated ballistic coefficients lead to inaccurate predictions of long range bullet drop, retained energy and wind drift.
Mass transfer coefficients in metallurgical reactors
无
2003-01-01
An overview on the application and achievements of physico-mathematical modeling of metallurgical processes in Chinais briefly declared. The important role of coefficients in model formulation is shown from our experience. The mass transfer coeffi-cients of the slag-metal reactions and the gas-metal reactions are discussed referring to the flow conditions near the interface. Theinfluence of the surface-active species on the mass transfer and the inteffacial reaction is also discussed briefly.
Converting Sabine absorption coefficients to random incidence absorption coefficients
Jeong, Cheol-Ho
2013-01-01
Absorption coefficients measured by the chamber method are referred to as Sabine absorption coefficients, which sometimes exceed unity due to the finite size of a sample and non-uniform intensity in the reverberation chambers under test. In this study, conversion methods from Sabine absorption...... coefficients to random incidence absorption coefficients are proposed. The overestimations of the Sabine absorption coefficient are investigated theoretically based on Miki's model for porous absorbers backed by a rigid wall or an air cavity, resulting in conversion factors. Additionally, three optimizations...
李小庆; 李晶
2015-01-01
Electrochemical cells with a calcium ion selective electrode ( Ca-ISE ) versus a chlorine ion selective electrode ( Cl-ISE) as a reference electrode were used to determine the activity coefficients for CaCl2-glucose system in water at 308. 15 K and 318. 15 K, the molality rage of glucose was from 0. 1 to 2. 0 mol · kg-1 . A comparison of the results thus obtained was made with those determined by another electromotive force ( emf) method. It was showed that agreement was excellent. At the same time, the activity coefficients for CaCl2 -glucose-water systems at these temperatures were compared with other reference data. The results suggested that the activity coefficients for CaCl2 in the systems not only related to molality but also to temperature.%用一个钙离子选择性电极( Ca-ISE )和一个氯离子选择性电极( Cl-ISE )作参比电极组成的电池测定308.15 K和318.15 K下水中CaCl2-葡萄糖体系的平均活度系数,糖的浓度从0.1~2.0 mol·kg-1,此法和用其他电动势法测得的结果一致性相当好。同时,结合参考文献的其他数据综合比较了不同温度下活度系数随浓度及温度的变化情况。结果表明,活度系数不但与浓度有关,而且也与温度有关。
Dillman, Jonathan R; Smith, Ethan A; Sanchez, Ramon; Adler, Jeremy; Fazeli, Soudabeh; Zhang, Bin; Davenport, Matthew S
2016-11-01
The purpose of this study was to determine prospectively whether bowel wall apparent diffusion coefficient (ADC) measurements can be used to monitor treatment response to infliximab therapy in the setting of pediatric small-bowel Crohn disease. Twenty-eight pediatric subjects with newly diagnosed biopsy-proven Crohn disease of the distal or terminal ileum treated with infliximab were enrolled. Subjects underwent MR enterography at baseline, 1 month after therapy, and 6 months after therapy. Imaging features were documented, including bowel wall ADC and arterial or enteric phase contrast-enhanced signal intensity normalized to that of unenhanced imaging. A linear mixed model assessed the relationship between ADC and time; patient age and sex and azathioprine combination therapy were covariates. The diagnostic performance (with 95% CIs) of an increase in bowel wall ADC of 20% or more for identifying response to infliximab was calculated using a decrease in normalized contrast-enhanced bowel wall signal intensity of 20% or more as the reference standard. Bowel wall ADC increased over time (mean [± SD], 1180 ± 200 × 10(-6) mm(2)/s at baseline, 1420 ± 420 × 10(-6) mm(2)/s at 1 month, and 1450 ± 450 × 10(-6) mm(2)/s at 6 months; p = 0.0003); azathioprine therapy modulated this rate of change (p = 0.003). There was a statistically significant negative correlation between change in ADC and change in normalized contrast-enhanced signal intensity over time (ρ = -0.36; p < 0.001). The diagnostic performance of change in ADC for identifying response to infliximab therapy was sensitivity of 0.58 (95% CI, 0.34-0.80), specificity of 0.52 (95% CI, 0.31-0.72), positive predictive value of 0.48 (95% CI, 0.27-0.69), and negative predictive value of 0.62 (95% CI, 0.38-0.82). Bowel wall ADC increases over time in pediatric subjects receiving infliximab, but the diagnostic performance of ADC is likely insufficient for reliable treatment monitoring.
Yoshiki Matsuda; Keita Sugiura; Takashi Hashimoto; Akane Ueda; Yoshihiro Konno; Yoshiyuki Tatsumi
2016-01-01
Onychomycosis is difficult to treat topically due to the deep location of the infection under the densely keratinized nail plate. In order to obtain an in vitro index that is relevant to the clinical efficacy of topical anti-onychomycosis drugs, we profiled five topical drugs: amorolfine, ciclopirox, efinaconazole, luliconazole, and terbinafine, for their nail permeabilities, keratin affinities, and anti-dermatophytic activities in the presence of keratin. Efinaconazole and ciclopirox permeat...
Yoshiki Matsuda; Keita Sugiura; Takashi Hashimoto; Akane Ueda; Yoshihiro Konno; Yoshiyuki Tatsumi
2016-01-01
Onychomycosis is difficult to treat topically due to the deep location of the infection under the densely keratinized nail plate. In order to obtain an in vitro index that is relevant to the clinical efficacy of topical anti-onychomycosis drugs, we profiled five topical drugs: amorolfine, ciclopirox, efinaconazole, luliconazole, and terbinafine, for their nail permeabilities, keratin affinities, and anti-dermatophytic activities in the presence of keratin. Efinaconazole and ciclopirox permeat...
刘植昌; 刘艳升; 胡玉峰; 曾鹏; 樊栓狮; 梁德青
2006-01-01
The simple equation relating the activity coefficient of each solute in mixed electrolyte solution to its value in binary solutions under isopiestic equilibrium was tested by comparison with the experimental data for the 18 electrolyte solutions consisting of 1:1, 1:2, and 1:3 electrolytes. The isopiestic measurements were made on the quaternary system BaCl2-NH4Br-NaI-H2O and its ternary subsystems NaI-NH4Br-H2O, NaI-BaCl2-H2O, and NH4Br-BaCl2-H2O at 298.15K. The results were used to test the applicability of the Zdanovskii's rule to the mixed electrolyte solutions which contain no common ions, and the agreement is excellent. The activity coefficients of the solutes in the above quaternary and ternary systems calculated from the above-mentioned simple equation are in good agreement with the Pitzer's equation.
Sabine absorption coefficients to random incidence absorption coefficients
Jeong, Cheol-Ho
2014-01-01
Absorption coefficients measured by the chamber method are referred to as Sabine absorption coefficients, which sometimes exceed unity due to the finite size of a specimen and non-uniform intensity in the test chamber. In this study, several methods that convert Sabine absorption coefficients...... into random incidence absorption coefficients for porous absorbers are investigated. Two optimization-based conversion methods are suggested: the surface impedance estimation for locally reacting absorbers and the flow resistivity estimation for extendedly reacting absorbers. The suggested conversion methods...
Engelmann, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires
1962-06-15
The object of this work is to study techniques of measurement using the gamma ionisation chamber, making it possible either to measure the activities of radioactive sources, or to determine the specific emission coefficient {gamma} (or the coefficient K) of a given radioelement. The ionisation chambers studied belong to two categories: graphites cavity-chambers, and 4 {pi} {gamma} chambers. For the cavity-chamber measurements, the different correction factors of which account must be taken have been calculated, in particular the geometric and hygrometric corrections. The absorption and auto-absorption corrections have led to the introduction of the notion of the 'effective energy {gamma}' of a radioelement. In the case of 4 {pi} {gamma} chambers, it has been shown that appropriately shaped electrodes make it possible to improve their performances. One of the chambers described permits the measurement of {beta} emitters using the associated Bremsstrahlung. In order to measure the K coefficient of some radioelements, it has been found useful a 4 {pi} {gamma} chamber with graphite walls, the measurement being carried out by comparison with a radium standard. The validity of the method was checked with radioelements for whom the K coefficient values are well-known ({sup 24}Na, {sup 60}Co, {sup 131}I, {sup 198}Au). For other radioelements, the following values were obtained (expressed in r cm{sup 3} mc{sup -1} h{sup -1}): {sup 51}Cr: 0,18; {sup 56}Mn: 8,8; {sup 65}Zn: 3,05; {sup 124}Sb: 9,9; {sup 134}Cs: 9,3; {sup 137}Cs: 3,35; {sup 141}Ce: 0,46; {sup 170}Tm: 0,023; {sup 192}Ir: 24,9; {sup 203}Hg: 1,18; These values have been corrected for the contribution to the dose of the fluorescent radiation which may be emitted by the source, except in the case of Tm{sup 170}. In the last part of this work, the performances of the different electro-metric devices used were compared. (author) [French] Le but de ce travail est d'etudier les techniques de mesure par
Quadrature formulas for Fourier coefficients
Bojanov, Borislav
2009-09-01
We consider quadrature formulas of high degree of precision for the computation of the Fourier coefficients in expansions of functions with respect to a system of orthogonal polynomials. In particular, we show the uniqueness of a multiple node formula for the Fourier-Tchebycheff coefficients given by Micchelli and Sharma and construct new Gaussian formulas for the Fourier coefficients of a function, based on the values of the function and its derivatives. © 2009 Elsevier B.V. All rights reserved.
Coefficient Alpha: A Reliability Coefficient for the 21st Century?
Yang, Yanyun; Green, Samuel B.
2011-01-01
Coefficient alpha is almost universally applied to assess reliability of scales in psychology. We argue that researchers should consider alternatives to coefficient alpha. Our preference is for structural equation modeling (SEM) estimates of reliability because they are informative and allow for an empirical evaluation of the assumptions…
Measuring of heat transfer coefficient
Henningsen, Poul; Lindegren, Maria
Subtask 3.4 Measuring of heat transfer coefficient Subtask 3.4.1 Design and setting up of tests to measure heat transfer coefficient Objective: Complementary testing methods together with the relevant experimental equipment are to be designed by the two partners involved in order to measure...... the heat transfer coefficient for a wide range of interface conditions in hot and warm forging processes. Subtask 3.4.2 Measurement of heat transfer coefficient The objective of subtask 3.4.2 is to determine heat transfer values for different interface conditions reflecting those typically operating in hot...
Measuring of heat transfer coefficient
Henningsen, Poul; Lindegren, Maria
Subtask 3.4 Measuring of heat transfer coefficient Subtask 3.4.1 Design and setting up of tests to measure heat transfer coefficient Objective: Complementary testing methods together with the relevant experimental equipment are to be designed by the two partners involved in order to measure...... the heat transfer coefficient for a wide range of interface conditions in hot and warm forging processes. Subtask 3.4.2 Measurement of heat transfer coefficient The objective of subtask 3.4.2 is to determine heat transfer values for different interface conditions reflecting those typically operating in hot...
The Evolution of Pearson's Correlation Coefficient
Kader, Gary D.; Franklin, Christine A.
2008-01-01
This article describes an activity for developing the notion of association between two quantitative variables. By exploring a collection of scatter plots, the authors propose a nonstandard "intuitive" measure of association; and by examining properties of this measure, they develop the more standard measure, Pearson's Correlation Coefficient. The…
The Evolution of Pearson's Correlation Coefficient
Kader, Gary D.; Franklin, Christine A.
2008-01-01
This article describes an activity for developing the notion of association between two quantitative variables. By exploring a collection of scatter plots, the authors propose a nonstandard "intuitive" measure of association; and by examining properties of this measure, they develop the more standard measure, Pearson's Correlation Coefficient. The…
A. Zuend
2011-09-01
Full Text Available We present a new and considerably extended parameterization of the thermodynamic activity coefficient model AIOMFAC (Aerosol Inorganic-Organic Mixtures Functional groups Activity Coefficients at room temperature. AIOMFAC combines a Pitzer-like electrolyte solution model with a UNIFAC-based group-contribution approach and explicitly accounts for interactions between organic functional groups and inorganic ions. Such interactions constitute the salt-effect, may cause liquid-liquid phase separation, and affect the gas-particle partitioning of aerosols. The previous AIOMFAC version was parameterized for alkyl and hydroxyl functional groups of alcohols and polyols. With the goal to describe a wide variety of organic compounds found in atmospheric aerosols, we extend here the parameterization of AIOMFAC to include the functional groups carboxyl, hydroxyl, ketone, aldehyde, ether, ester, alkenyl, alkyl, aromatic carbon-alcohol, and aromatic hydrocarbon. Thermodynamic equilibrium data of organic-inorganic systems from the literature are critically assessed and complemented with new measurements to establish a comprehensive database. The database is used to determine simultaneously the AIOMFAC parameters describing interactions of organic functional groups with the ions H^{+}, Li^{+}, Na^{+}, K^{+}, NH_{4}^{+}, Mg^{2+}, Ca^{2+}, Cl^{−}, Br^{−}, NO_{3}^{−}, HSO_{4}^{−}, and SO_{4}^{2−}. Detailed descriptions of different types of thermodynamic data, such as vapor-liquid, solid-liquid, and liquid-liquid equilibria, and their use for the model parameterization are provided. Issues regarding deficiencies of the database, types and uncertainties of experimental data, and limitations of the model, are discussed. The challenging parameter optimization problem is solved with a novel combination of powerful global minimization
A. Zuend
2011-05-01
Full Text Available We present a new and considerably extended parameterization of the thermodynamic activity coefficient model AIOMFAC (Aerosol Inorganic-Organic Mixtures Functional groups Activity Coefficients at room temperature. AIOMFAC combines a Pitzer-like electrolyte solution model with a UNIFAC-based group-contribution approach and explicitly accounts for interactions between organic functional groups and inorganic ions. Such interactions constitute the salt-effect, may cause liquid-liquid phase separation, and affect the gas-particle partitioning of aerosols. The previous AIOMFAC version was parameterized for alkyl and hydroxyl functional groups of alcohols and polyols. With the goal to describe a wide variety of organic compounds found in atmospheric aerosols, we extend here the parameterization of AIOMFAC to include the functional groups carboxyl, hydroxyl, ketone, aldehyde, ether, ester, alkenyl, alkyl, aromatic carbon-alcohol, and aromatic hydrocarbon. Thermodynamic equilibrium data of organic-inorganic systems from the literature are critically assessed and complemented with new measurements to establish a comprehensive database. The database is used to determine simultaneously the AIOMFAC parameters describing interactions of organic functional groups with the ions H^{+}, Li^{+}, Na^{+}, K^{+}, NH_{4}^{+}, Mg^{2+}, Ca^{2+}, Cl^{−}, Br^{−}, NO_{3}^{−}, HSO_{4}^{−}, and SO_{4}^{2−}. Detailed descriptions of different types of thermodynamic data, such as vapor-liquid, solid-liquid, and liquid-liquid equilibria, and their use for the model parameterization are provided. Issues regarding deficiencies of the database, types and uncertainties of experimental data, and limitations of the model, are discussed. The challenging parameter optimization problem is solved with a novel combination of powerful global minimization
Claudio A.Faundez; Jose O.Valderrama
2009-01-01
In this study,three semipredictive activity coefficient models:Wilson,non-random-two liquid model (NRTL),and universal quasi-chemical model(UNIQUAC),have been used for modeling vapor-liquid equilibrium properties oftemary mixtures that include substances found in alcoholic distillation processes ofwine and musts.In pamcular,vapor-hqmd eqmIIbnum in temary mixtures containing water+ethanol+congener has been modeled using parameters obtained from binary and ternary mixture data.Thc congeners are substances that although present in very lOW concentrations,of the order of part per million.are important cnological parameters.The results given by these difierent models have been compared with literature data and conclusions about the accuracy ofthe models studied are drawn,recommending the best models for correlating and predicting phase equilibrium properties of this type of mixtures.
Chang, Elsa I.; Pankow, James F.
A thermodynamic model is presented for predicting the formation of particulate matter (PM) within an aerosol that contains organic compounds, inorganic salts, and water. Neutral components are allowed to partition from the gas phase to the PM, with the latter potentially composed of both a primarily aqueous ( α) liquid phase and a primarily organic ( β) liquid phase. Partitioning is allowed to occur without any artificial restraints: when both α and β PM phases are present, ionic constituents are allowed to partition to both. X-UNIFAC.2, an extended UNIFAC method based on Yan et al. (1999. Prediction of vapor-liquid equilibria in mixed-solvent electrolyte systems using the group contribution concept. Fluid Phase Equilibria 162, 97-113), was developed for activity coefficient estimation. X-UNIFAC.2 utilizes the standard UNIFAC terms, a Debye-Hückel term, and a virial equation term that represents the middle-range (MR) contribution to activity coefficient effects. A large number (234) of MR parameters are already available from Yan et al. (1999). Six additional MR parameters were optimized here to enable X-UNIFAC.2 to account for interactions between the carboxylic acid group and Na +, Cl -, and Ca 2+. Predictions of PM formation were made for a hypothetical sabinene/O 3 system with varying amounts of NaCl in the PM. Predictions were also made for the chamber experiments with α-pinene/O 3 (and CaCl 2 seed) carried out by Cocker et al. (2001. The effect of water on gas-particle partitioning of secondary organic aerosol. Part I. α-pinene/ozone system. Atmospheric Environment 35, 6049-6072); good agreement between the predicted and chamber-measured PM mass concentrations was achieved.
Plummer, L. Neil; Sundquist, Eric T.
1982-01-01
We have calculated the total individual ion activity coefficients of carbonate and calcium, and , in seawater. Using the ratios of stoichiometric and thermodynamic constants of carbonic acid dissociation and total mean activity coefficient data measured in seawater, we have obtained values which differ significantly from those widely accepted in the literature. In seawater at 25°C and 35%. salinity the (molal) values of and are 0.038 ± 0.002 and 0.173 ± 0.010, respectively. These values of and are independent of liquid junction errors and internally consistent with the value . By defining and on a common scale (), the product is independent of the assigned value of and may be determined directly from thermodynamic measurements in seawater. Using the value and new thermodynamic equilibrium constants for calcite and aragonite, we show that the apparent constants of calcite and aragonite are consistent with the thermodynamic equilibrium constants at 25°C and 35%. salinity. The demonstrated consistency between thermodynamic and apparent constants of calcite and aragonite does not support a hypothesis of stable Mg-calcite coatings on calcite or aragonite surfaces in seawater, and suggests that the calcite critical carbonate ion curve of Broecker and Takahashi (1978,Deep-Sea Research25, 65–95) defines the calcite equilibrium boundary in the oceans, within the uncertainty of the data.
Miyano, Yoshimori [Department of Chemistry and Bioscience, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajimacho, Kurashiki 712-8505 (Japan)]. E-mail: miyano@chem.kusa.ac.jp; Kobashi, Takahiro [Department of Chemistry and Bioscience, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajimacho, Kurashiki 712-8505 (Japan); Shinjo, Hiroshi [Department of Chemistry and Bioscience, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajimacho, Kurashiki 712-8505 (Japan); Kumada, Shinya [Department of Chemistry and Bioscience, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajimacho, Kurashiki 712-8505 (Japan); Watanabe, Yusuke [Department of Chemistry and Bioscience, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajimacho, Kurashiki 712-8505 (Japan); Niya, Wataru [Department of Chemistry and Bioscience, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajimacho, Kurashiki 712-8505 (Japan); Tateishi, Yoko [Department of Chemistry and Bioscience, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajimacho, Kurashiki 712-8505 (Japan)
2006-06-15
Henry's law constants and infinite dilution activity coefficients of cis-2-butene, dimethylether, chloroethane, and 1,1-difluoroethane in methanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, isobutanol, tert-butanol, 1-pentanol, 2-pentanol, 3-pentanol, 2-methyl-1-butanol, 3-methyl-1-butanol, and 2-methyl-2-butanol in the temperature range of 250 K to 330 K were measured by a gas stripping method and partial molar excess enthalpies were calculated from the activity coefficients. A rigorous formula for evaluating the Henry's law constants from the gas stripping measurements was used for the data reduction of these highly volatile mixtures. The uncertainty is about 2% for the Henry's law constants and 3% for the estimated infinite dilution activity coefficients. In the evaluation of the infinite dilution activity coefficients, the nonideality of the solute such as the fugacity coefficient and Poynting correction factor cannot be neglected, especially at higher temperatures. The estimated uncertainty of the infinite dilution activity coefficients includes 1% for nonideality.
The Kauffman Constraint Coefficients Kw
Griggs, Kenneth A
2011-01-01
The Kauffman Constraint Coefficients Kw and their corresponding Elementals Ew are presented as solutions to the construction of the (beta)-derivative of Kauffman's Theta-function. Additionally, a new recursion relation is provided to construct the (beta)-derivative of Theta that requires only operational substitutions and summations; this algorithmically simplifies Kauffman's original technique. To demonstrate Kw, we generate the 30 Kw Coefficients from the corresponding Elementals Ew for the (9)-derivative of Theta and find that our results are in complete agreement with Kauffman's Mathematica\\texttrademark solutions. We further present a calculation of two coefficients for the (12)-derivative of Theta and invite readers to use Mathematica\\texttrademark or any other means to calculate and verify our results. Finally, we present a challenging calculation for a coefficient of the (40)-derivative of Theta; owing to the vast numbers of permutations involved, a Mathematica\\texttrademark approach may require subst...
Kappa Coefficients for Circular Classifications
Warrens, Matthijs J.; Pratiwi, Bunga C.
2016-01-01
Circular classifications are classification scales with categories that exhibit a certain periodicity. Since linear scales have endpoints, the standard weighted kappas used for linear scales are not appropriate for analyzing agreement between two circular classifications. A family of kappa coefficie
Properties of Traffic Risk Coefficient
TANG Tie-Qiao; HUANG Hai-Jun; SHANG Hua-Yan; XUE Yu
2009-01-01
We use the model with the consideration of the traffic interruption probability (Physica A 387(2008)6845) to study the relationship between the traffic risk coefficient and the traffic interruption probability.The analytical and numerical results show that the traffic interruption probability will reduce the traffic risk coefficient and that the reduction is related to the density, which shows that this model can improve traffic security.
Wrong Signs in Regression Coefficients
McGee, Holly
1999-01-01
When using parametric cost estimation, it is important to note the possibility of the regression coefficients having the wrong sign. A wrong sign is defined as a sign on the regression coefficient opposite to the researcher's intuition and experience. Some possible causes for the wrong sign discussed in this paper are a small range of x's, leverage points, missing variables, multicollinearity, and computational error. Additionally, techniques for determining the cause of the wrong sign are given.
Transport coefficients of heavy baryons
Tolos, Laura; Torres-Rincon, Juan M.; Das, Santosh K.
2016-08-01
We compute the transport coefficients (drag and momentum diffusion) of the low-lying heavy baryons Λc and Λb in a medium of light mesons formed at the later stages of high-energy heavy-ion collisions. We employ the Fokker-Planck approach to obtain the transport coefficients from unitarized baryon-meson interactions based on effective field theories that respect chiral and heavy-quark symmetries. We provide the transport coefficients as a function of temperature and heavy-baryon momentum, and analyze the applicability of certain nonrelativistic estimates. Moreover we compare our outcome for the spatial diffusion coefficient to the one coming from the solution of the Boltzmann-Uehling-Uhlenbeck transport equation, and we find a very good agreement between both calculations. The transport coefficients for Λc and Λb in a thermal bath will be used in a subsequent publication as input in a Langevin evolution code for the generation and propagation of heavy particles in heavy-ion collisions at LHC and RHIC energies.
姜波; 王利生; 李弥异
2011-01-01
In this paper, the conductivities of NaBr in methanol, ethanol, 1-propanol, 2-propanol, NaC1 and KBr in methanol, ethanol system (solution concentration within 0. 1 mol· L-1 ) were determined at 298.15 K, 313.15 K and 323.15 K at atmosphere pressure respectively. The mean ion activity coefficients of NaBr, NaC1 and KBr in various organic solvents were calculated according to DebyeHacker limiting law and Onsager-Falkenhangen equations. The effects of concentration and temperature on activity coefficients of electrolyte solutions were discussed. The calculated results were compared with those of NaBr in ethanol, NaC1 in methanol and KBr in methanol reported in literature. The results show that the experimental data obtained by conductivity method have good agreement with data in literature.%分别测定了NaBr在甲醉、乙醇、正丙醉和异丙醇中,NaCI和KBr在甲醉和乙醉中共8个体系(溶液物质的量的浓度在0.1 mol·L(-1)范围内)在298.15,313.15和323.15 K下的电导率,利用Debye-Hiicker和Osager-Falkenhangen公式计算了以上溶液体系的平均离子活度系数,讨论了浓度和温度对电解质溶液活度系数的影响.其中NaBr在乙醇中,NaCI在甲醉中和KBr在甲醇中的平均离子活度系数的计算结果与已发表文献中的数据进行了比较.结果表明,该方法的活度系数结果与文献数据有较好的一致性.
Personal dose-equivalent conversion coefficients for 1252 radionuclides.
Otto, Thomas
2016-01-01
Dose conversion coefficients for radionuclides are useful for routine calculations in radiation protection in industry, medicine and research. They give a simple and often sufficient estimate of dose rates during production, handling and storage of radionuclide sources, based solely on the source's activity. The latest compilation of such conversion coefficients dates from 20 y ago, based on nuclear decay data published 30 y ago. The present publication provides radionuclide-specific conversion coefficients to personal dose based on the most recent evaluations of nuclear decay data for 1252 radionuclides and fluence-to-dose-equivalent conversion coefficients for monoenergetic radiations. It contains previously unknown conversion coefficients for >400 nuclides and corrects those conversion coefficients that were based on erroneous decay schemes. For the first time, estimates for the protection quantity Hp(3) are included.
Lu, Xin; Miki, Takahiro; Nagasaka, Tetsuya
2017-01-01
To design optimal pyrometallurgical processes for nickel and cobalt recycling, and more particularly for the end-of-life process of Ni-Co-Fe-based end-of-life (EoL) superalloys, knowledge of their activity coefficients in slags is essential. In this study, the activity coefficients of NiO and CoO in CaO-Al2O3-SiO2 slag, a candidate slag used for the EoL superalloy remelting process, were measured using gas/slag/metal equilibrium experiments. These activity coefficients were then used to consider the recycling efficiency of nickel and cobalt by remelting EoL superalloys using CaO-Al2O3-SiO2 slag. The activity coefficients of NiO and CoO in CaO-Al2O3-SiO2 slag both show a positive deviation from Raoult's law, with values that vary from 1 to 5 depending on the change in basicity. The activity coefficients of NiO and CoO peak in the slag with a composition near B = (%CaO)/(%SiO2) = 1, where B is the basicity. We observed that controlling the slag composition at approximately B = 1 effectively reduces the cobalt and nickel oxidation losses and promotes the oxidation removal of iron during the remelting process of EoL superalloys.
Harmonic functions with varying coefficients
Jacek Dziok
2016-05-01
Full Text Available Abstract Complex-valued harmonic functions that are univalent and sense preserving in the open unit disk can be written in the form f = h + g ‾ $f=h+\\overline{g}$ , where h and g are analytic. In this paper we investigate some classes of univalent harmonic functions with varying coefficients related to Janowski functions. By using the extreme points theory we obtain necessary and sufficient convolution conditions, coefficients estimates, distortion theorems, and integral mean inequalities for these classes of functions. The radii of starlikeness and convexity for these classes are also determined.
Marjani, Azam
2016-07-01
For biomolecules and cell particles purification and separation in biological engineering, besides the chromatography as mostly applied process, aqueous two-phase systems (ATPS) are of the most favorable separation processes that are worth to be investigated in thermodynamic theoretically. In recent years, thermodynamic calculation of ATPS properties has attracted much attention due to their great applications in chemical industries such as separation processes. These phase calculations of ATPS have inherent complexity due to the presence of ions and polymers in aqueous solution. In this work, for target ternary systems of polyethylene glycol (PEG4000)-salt-water, thermodynamic investigation for constituent systems with three salts (NaCl, KCl and LiCl) has been carried out as PEG is the most favorable polymer in ATPS. The modified perturbed hard sphere chain (PHSC) equation of state (EOS), extended Debye-Hückel and Pitzer models were employed for calculation of activity coefficients for the considered systems. Four additional statistical parameters were considered to ensure the consistency of correlations and introduced as objective functions in the particle swarm optimization algorithm. The results showed desirable agreement to the available experimental data, and the order of recommendation of studied models is PHSC EOS > extended Debye-Hückel > Pitzer. The concluding remark is that the all the employed models are reliable in such calculations and can be used for thermodynamic correlation/predictions; however, by using an ion-based parameter calculation method, the PHSC EOS reveals both reliability and universality of applications.
Rard, J A; Clegg, S L; Palmer, D A
2007-01-03
Isopiestic vapor-pressure measurements were made for Li{sub 2}SO{sub 4}(aq) from 0.1069 to 2.8190 mol {center_dot} kg{sup -1} at 298.15 K, and from 0.1148 to 2.7969 mol {center_dot} kg{sup -1} at 323.15 K, with NaCl(aq) as the reference standard. Published thermodynamic data for this system were reviewed, recalculated for consistency, and critically assessed. The present results and the more reliable published results were used to evaluate the parameters of an extended version of Pitzer's ion-interaction model with an ionic-strength dependent third virial coefficient, as well as those of the standard Pitzer model, for the osmotic and activity coefficients at both temperatures. Published enthalpies of dilution at 298.15 K were also analyzed to yield the parameters of the ion-interaction models for the relative apparent molar enthalpies of dilution. The resulting models at 298.15 K are valid to the saturated solution molality of the thermodynamically stable phase Li{sub 2}SO{sub 4} {center_dot} H{sub 2}O(cr). Solubilities of Li{sub 2}SO{sub 4} {center_dot} H{sub 2}O(cr) at 298.15 K were assessed, and the selected value of m(sat.) = 3.13 {+-} 0.04 mol {center_dot} kg{sup -1} was used to evaluate the thermodynamic solubility product K{sub s}(Li{sub 2}SO{sub 4} {center_dot} H{sub 2}O, cr, 298.15 K) = (2.62 {+-} 0.19) and a CODATA-compatible standard molar Gibbs energy of formation {Delta}{sub f}G{sub m}{sup o} (Li{sub 2}SO{sub 4} {center_dot} H{sub 2}O, cr, 298.15 K) = -(1564.6 {+-} 0.5) kJ {center_dot} mol{sup -1}.
Effective Viscosity Coefficient of Nanosuspensions
Rudyak, V. Ya.; Belkin, A. A.; Egorov, V. V.
2008-12-01
Systematic calculations of the effective viscosity coefficient of nanosuspensions have been performed using the molecular dynamics method. It is established that the viscosity of a nanosuspension depends not only on the volume concentration of the nanoparticles but also on their mass and diameter. Differences from Einstein's relation are found even for nanosuspensions with a low particle concentration.
Irrational "Coefficients" in Renaissance Algebra.
Oaks, Jeffrey A
2017-06-01
Argument From the time of al-Khwārizmī in the ninth century to the beginning of the sixteenth century algebraists did not allow irrational numbers to serve as coefficients. To multiply by x, for instance, the result was expressed as the rhetorical equivalent of . The reason for this practice has to do with the premodern concept of a monomial. The coefficient, or "number," of a term was thought of as how many of that term are present, and not as the scalar multiple that we work with today. Then, in sixteenth-century Europe, a few algebraists began to allow for irrational coefficients in their notation. Christoff Rudolff (1525) was the first to admit them in special cases, and subsequently they appear more liberally in Cardano (1539), Scheubel (1550), Bombelli (1572), and others, though most algebraists continued to ban them. We survey this development by examining the texts that show irrational coefficients and those that argue against them. We show that the debate took place entirely in the conceptual context of premodern, "cossic" algebra, and persisted in the sixteenth century independent of the development of the new algebra of Viète, Decartes, and Fermat. This was a formal innovation violating prevailing concepts that we propose could only be introduced because of the growing autonomy of notation from rhetorical text.
Estimating biokinetic coefficients in the PACT™ system.
Shen, Zhiyao; Arbuckle, Wm Brian
2016-02-01
When powdered activated carbon (PAC) is continuously added to the aeration tank of an activated sludge reactor, the modification is called a PACT™ process (for powdered activated carbon treatment). The PAC provides many benefits, but complicates the determination of biological phenomena. Determination of bio-oxidation kinetics in a PACT system is a key to fully understanding enhanced biological mechanisms resulting from PAC addition. A model is developed to account for the main mechanisms involved in the PACT system -- adsorption, air stripping and bio-oxidation. The model enables the investigation of biokinetic information, including possible synergistic effects. Six parallel reactors were used to treat a synthetic waste; three activated sludge and three PACT. The PACT reactors provided significantly reduced effluent TOC (total organic carbon). Biokinetic coefficients were obtained from steady-state data using averaged reactor data and by using all data (22 points for each reactor). As expected, the PACT reactors resulted in a substantial reduction in the effluent concentration of non-biodegradable total organic carbon. The Monod equation's half-saturation coefficient (Ks) was reduced significantly in the PACT reactors, resulting in higher growth rates at lower concentrations. The maximum specific substrate utilization (qm) rate was also reduced about 25% using the averaged data and remained unchanged using all the data. The substrate utilization values are affected by errors in biomass determination and more research is needed to accurately determine biomass.
Study of Dispersion Coefficient Channel
Akiyama, K. R.; Bressan, C. K.; Pires, M. S. G.; Canno, L. M.; Ribeiro, L. C. L. J.
2016-08-01
The issue of water pollution has worsened in recent times due to releases, intentional or not, of pollutants in natural water bodies. This causes several studies about the distribution of pollutants are carried out. The water quality models have been developed and widely used today as a preventative tool, ie to try to predict what will be the concentration distribution of constituent along a body of water in spatial and temporal scale. To understand and use such models, it is necessary to know some concepts of hydraulic high on their application, including the longitudinal dispersion coefficient. This study aims to conduct a theoretical and experimental study of the channel dispersion coefficient, yielding more information about their direct determination in the literature.
Clustering Coefficients in Multiplex Networks
Cozzo, Emanuele; De Domenico, Manlio; Solé, Albert; Arenas, Alex; Gómez, Sergio; Porter, Mason A; Moreno, Yamir
2013-01-01
Recent advances in the study of complex networked systems has highlighted that our interconnected world is made of networks that are coupled together through different layers that each stand for one type of interaction or system. Despite this situation, it is traditional to aggregate multiplex data into a single weighted network in order take advantage of existing tools. This is admittedly convenient, but it is also extremely problematic. In this paper, we generalize the concept of clustering coefficients for multiplex networks. We show how the layered structure of multiplex networks introduces a new degree of freedom that has a fundamental effect on transitivity. We compute our new multiplex clustering coefficients for several real multiplex networks and illustrate why generalizing monoplex concepts to multiplex networks must be done with great care.
Jeong, Cheol-Ho; Chang, Ji-ho
2015-01-01
Absorption coefficients measured in reverberation chambers, Sabine absorption coefficients, suffer from two major problems. Firstly, they sometimes exceed unity. Secondly, the reproducibility of the Sabine absorption coefficients is quite poor, meaning that the Sabine absorption coefficients vary...
LU Yigang; PENG Jianxin; TONG Jie; DONG Yanwu
2000-01-01
On the basis of Jacobson's free length theory and the theory of pressure coefficient and temperature coefficient of free length in liquids, the relationship between the pressure coefficient of ultrasonic velocity and the pressure coefficient of free length, and the relationship between the temperature coefficient of ultrasonic velocity and the temperature coefficient of free length were studied. Relevant equations were given, and the pressure coefficient and temperature coefficient of ultrasonic velocity were calculated, which are in agreement with the measured values.
Coefficients of Productivity for Yellowstone's Grizzly Bear Habitat
Mattson, David John; Barber, Kim; Maw, Ralene; Renkin, Roy
2004-01-01
This report describes methods for calculating coefficients used to depict habitat productivity for grizzly bears in the Yellowstone ecosystem. Calculations based on these coefficients are used in the Yellowstone Grizzly Bear Cumulative Effects Model to map the distribution of habitat productivity and account for the impacts of human facilities. The coefficients of habitat productivity incorporate detailed information that was collected over a 20-year period (1977-96) on the foraging behavior of Yellowstone's bears and include records of what bears were feeding on, when and where they fed, the extent of that feeding activity, and relative measures of the quantity consumed. The coefficients also incorporate information, collected primarily from 1986 to 1992, on the nutrient content of foods that were consumed, their digestibility, characteristic bite sizes, and the energy required to extract and handle each food. Coefficients were calculated for different time periods and different habitat types, specific to different parts of the Yellowstone ecosystem. Stratifications included four seasons of bear activity (spring, estrus, early hyperphagia, late hyperphagia), years when ungulate carrion and whitebark pine seed crops were abundant versus not, areas adjacent to (bear activity in each region, habitat type, and time period were incorporated into calculations, controlling for the effects of proximity to human facilities. The coefficients described in this report and associated estimates of grizzly bear habitat productivity are unique among many efforts to model the conditions of bear habitat because calculations include information on energetics derived from the observed behavior of radio-marked bears.
Higher Order Macro Coefficients in Periodic Homogenization
Conca, Carlos; San Martin, Jorge [Departamento de IngenierIa Matematica, Facultad de Ciencias Fisicas y Matematicas, Universidad de Chile and Centro de Modelamiento Matematico, UMR 2071 CNRS-UChile, Casilla 170/3 - Correo 3, Santiago (Chile); Smaranda, Loredana [Department of Mathematics, Faculty of Mathematics and Computer Science, University of Pitesti, 110040 Pitesti, Str. Targu din Vale Nr.1, Arges (Romania); Vanninathan, Muthusamy, E-mail: cconca@dim.uchile.cl, E-mail: jorge@dim.uchile.cl, E-mail: smaranda@dim.uchile.cl, E-mail: vanni@math.tifrbng.res.in [TIFR-CAM, Post Bag 6503, GKVK Post, Bangalore - 560065 (India)
2011-09-15
A first set of macro coefficients known as the homogenized coefficients appear in the homogenization of PDE on periodic structures. If energy is increased or scale is decreased, these coefficients do not provide adequate approximation. Using Bloch decomposition, it is first realized that the above coefficients correspond to the lowest energy and the largest scale. This naturally paves the way to introduce other sets of macro coefficients corresponding to higher energies and lower scales which yield better approximation. The next task is to compare their properties with those of the homogenized coefficients. This article reviews these developments along with some new results yet to be published.
Note on Two Generalizations of Coefficient Alpha.
Raju, Nambury S.
1979-01-01
An important relationship is given for two generalizations of coefficient alpha: (1) Rajaratnam, Cronbach, and Gleser's generalizability formula for stratified-parallel tests, and (2) Raju's coefficient beta. (Author/CTM)
Energy coefficients for a propeller series
Olsen, Anders Smærup
2004-01-01
The efficiency for a propeller is calculated by energy coefficients. These coefficients are related to four types of losses, i.e. the axial, the rotational, the frictional, and the finite blade number loss, and one gain, i.e. the axial gain. The energy coefficients are derived by use of the poten......The efficiency for a propeller is calculated by energy coefficients. These coefficients are related to four types of losses, i.e. the axial, the rotational, the frictional, and the finite blade number loss, and one gain, i.e. the axial gain. The energy coefficients are derived by use...... of the potential theory with the propeller modelled as an actuator disk. The efficiency based on the energy coefficients is calculated for a propeller series. The results show a good agreement between the efficiency based on the energy coefficients and the efficiency obtained by a vortex-lattice method....
Index-free Heat Kernel Coefficients
De van Ven, A E M
1998-01-01
Using index-free notation, we present the diagonal values of the first five heat kernel coefficients associated with a general Laplace-type operator on a compact Riemannian space without boundary. The fifth coefficient appears here for the first time. For a flat space with a gauge connection, the sixth coefficient is given too. Also provided are the leading terms for any coefficient, both in ascending and descending powers of the Yang-Mills and Riemann curvatures, to the same order as required for the fourth coefficient. These results are obtained by directly solving the relevant recursion relations, working in Fock-Schwinger gauge and Riemann normal coordinates. Our procedure is thus noncovariant, but we show that for any coefficient the `gauged' respectively `curved' version is found from the corresponding `non-gauged' respectively `flat' coefficient by making some simple covariant substitutions. These substitutions being understood, the coefficients retain their `flat' form and size. In this sense the fift...
Certain Binomial Sums with recursive coefficients
Kilic, Emrah
2010-01-01
In this short note, we establish some identities containing sums of binomials with coefficients satisfying third order linear recursive relations. As a result and in particular, we obtain general forms of earlier identities involving binomial coefficients and Fibonacci type sequences.
Erdakos, Garnet B.; Asher, William E.; Seinfeld, John H.; Pankow, James F.
The semi-empirical group contribution method (GCM) of Kikic et al. [Chem. Eng. Sci. 46 (1991) 2775-2780] for estimating activity coefficient ( ζ) values of neutral organic compounds and water in solutions composed of organic compounds, dissolved inorganic salts, and water is adapted for application to atmospheric particulate matter (PM). It is assumed that ζ values are determined by a combination of short- and long-range interactions. The ζ expression involves conventional UNIFAC terms and a Debye-Hückel term, with the former computed using group-group interaction parameters. Organic-organic interaction parameters are assigned the values from the UNIFAC-LLE model of Magnussen et al. [Ind. Eng. Chem. Process Design Develop. 20 (1981) 331-339]. Forty interaction parameters (ion-solvent group and anion-cation) were obtained from Kikic et al. [Chem. Eng. Sci. 46 (1991) 2775-2780], Achard et al. [Fluid Phase Equilibria 98 (1994) 71-89], and Ming and Russell [Am. Inst. Chem. Eng. J. 48 (2002) 1331-1348]. Twenty additional interaction parameters (ion-solvent group) are estimated based on 879 UNIQUAC-fitted ζ values for organic compounds and water. The fitted ζ values are based on liquid-liquid equilibrium (LLE) data for a range of ternary and quaternary organic/inorganic salt/water mixtures at 293-308 K. The UNIQUAC fits are analogous to those described by Fredenslund et al. [Vapor-Liquid Equilibria Using UNIFAC: A Group-Contribution Method, Elsevier Scientific Publishing, New York, 1977]. The LLE mixture compositions range from primarily organic solutions to primarily aqueous solutions with maximum ionic strengths of ˜5 mol kg -1. The groups characteristic of organic compounds found in atmospheric PM considered here include: CH 3-, -CH 2-, -CH|-, -C||-, -OH, -CH 2CO-, and -COOH. These are: single bonded carbon with three, two, one, and zero hydrogens, respectively, hydroxyl, -CH 2-carbonyl, and carboxyl, respectively. The inorganic salts represented in the mixture
Standards for Standardized Logistic Regression Coefficients
Menard, Scott
2011-01-01
Standardized coefficients in logistic regression analysis have the same utility as standardized coefficients in linear regression analysis. Although there has been no consensus on the best way to construct standardized logistic regression coefficients, there is now sufficient evidence to suggest a single best approach to the construction of a…
Comparing linear probability model coefficients across groups
Holm, Anders; Ejrnæs, Mette; Karlson, Kristian Bernt
2015-01-01
This article offers a formal identification analysis of the problem in comparing coefficients from linear probability models between groups. We show that differences in coefficients from these models can result not only from genuine differences in effects, but also from differences in one or more...... these limitations, and we suggest a restricted approach to using linear probability model coefficients in group comparisons....
Note on Methodology: The Coefficient of Variation.
Sheret, Michael
1984-01-01
Addresses applications of the coefficient of variation as a measure of educational inequality or as a means of measuring changes of inequality status. Suggests the Gini coefficient has many advantages over the coefficient of variation since it can be used with the Lorenz curve (Lorenz provides detail Gini omits). (BRR)
Coefficient of Partial Correlation and Its Calculation
段全才; 张保法
1992-01-01
This thesis offers the general concept of coefficient of partial correlation.Starting with regres-sion analysis,the paper,by using samples,infers the general formula of expressing coefficient of partial correlation by way of simple correlation coefficient.
Diffusion coefficient in photon diffusion theory
Graaff, R; Ten Bosch, JJ
2000-01-01
The choice of the diffusion coefficient to be used in photon diffusion theory has been a subject of discussion in recent publications on tissue optics. We compared several diffusion coefficients with the apparent diffusion coefficient from the more fundamental transport theory, D-app. Application to
Soccer Ball Lift Coefficients via Trajectory Analysis
Goff, John Eric; Carre, Matt J.
2010-01-01
We performed experiments in which a soccer ball was launched from a machine while two high-speed cameras recorded portions of the trajectory. Using the trajectory data and published drag coefficients, we extracted lift coefficients for a soccer ball. We determined lift coefficients for a wide range of spin parameters, including several spin…
Diffusion coefficient in photon diffusion theory
Graaff, R; Ten Bosch, JJ
2000-01-01
The choice of the diffusion coefficient to be used in photon diffusion theory has been a subject of discussion in recent publications on tissue optics. We compared several diffusion coefficients with the apparent diffusion coefficient from the more fundamental transport theory, D-app. Application to
Soccer Ball Lift Coefficients via Trajectory Analysis
Goff, John Eric; Carre, Matt J.
2010-01-01
We performed experiments in which a soccer ball was launched from a machine while two high-speed cameras recorded portions of the trajectory. Using the trajectory data and published drag coefficients, we extracted lift coefficients for a soccer ball. We determined lift coefficients for a wide range of spin parameters, including several spin…
Ageing effect of chloride diffusion coefficient
Polder, R.B.
2006-01-01
Most of the currently used models to predict chloride ingress a constant diffusion coefficient over time. However, a reduction of the diffusion coefficient over time, is ob-served at specimens that are exposed to chlorides. This reduction of the diffusion coefficient is expressed with the ageing coe
Standards for Standardized Logistic Regression Coefficients
Menard, Scott
2011-01-01
Standardized coefficients in logistic regression analysis have the same utility as standardized coefficients in linear regression analysis. Although there has been no consensus on the best way to construct standardized logistic regression coefficients, there is now sufficient evidence to suggest a single best approach to the construction of a…
Note on Methodology: The Coefficient of Variation.
Sheret, Michael
1984-01-01
Addresses applications of the coefficient of variation as a measure of educational inequality or as a means of measuring changes of inequality status. Suggests the Gini coefficient has many advantages over the coefficient of variation since it can be used with the Lorenz curve (Lorenz provides detail Gini omits). (BRR)
On cloud modelling and the mass accommodation coefficient of water
A. Laaksonen
2004-11-01
Full Text Available The mass accommodation coefficient of water is a quantity for which different experimental techniques have yielded conflicting values in the range 0.04–1. From the viewpoint of cloud modelling, this is an unfortunate situation, since the value of the mass accommodation coefficient affects the model results, e.g. the number concentration of activated cloud droplets. In this paper we argue that a mass accommodation coefficient of unity should be used in cloud modelling, since this value has been obtained in experimental studies of water droplet growth rates, a quantity which is explicitly described in cloud models. In contrast, mass accommodation coefficient values below unity have been derived from experimental results which are analyzed with different theoretical expressions than those included in cloud models.
Calculation of self-diffusion coefficients in iron
Baohua Zhang
2014-01-01
Full Text Available On the basis of available P-V-T equation of state of iron, the temperature and pressure dependence of self-diffusion coefficients in iron polymorphs (α, δ, γ and ɛ phases have been successfully reproduced in terms of the bulk elastic and expansivity data by means of a thermodynamical model that interconnects point defects parameters with bulk properties. The calculated diffusion parameters, such as self-diffusion coefficient, activation energy and activation volume over a broad temperature range (500-2500 K and pressure range (0-100 GPa, compare favorably well with experimental or theoretical ones when the uncertainties are considered.
郑照明; 李军; 马静; 杜佳; 赵白航
2016-01-01
通过批试实验研究了氨氮浓度对SNAD生物膜厌氧氨氧化性能的影响. SNAD生物膜反应器以生活污水为进水.进水NH4+-N和COD浓度平均值分别为70mg/L和180mg/L,出水NH4+-N, NO2--N, NO3--N和COD浓度平均值分别为2mg/L,2mg/L,7mg/L和50mg/L. SNAD生物膜具有良好的厌氧氨氧化活性.初始NH4+-N和NO2--N浓度都为70mg/L时,厌氧氨氧化批试NH4+-N、NO2--N和TIN去除速率分别为0.121kg N/(kg VSS·d),0.180kg N/(kg VSS·d)和0.267kg N/(kg VSS·d).采用Haldane模型可以很好的拟合氨氮浓度对厌氧氨氧化活性的影响.在高FA和低FA工况下氨氮浓度对厌氧氨氧化活性的抑制动力学常数相差不大. M1(FA浓度为0.7~20.4mg/L)和M2(FA浓度为6.3~190.5mg/L)的最大NO2--N理论去除速率rmax分别为0.209kg N/(kg VSS·d)和0.221kg N/(kg VSS·d),氨氮半饱和常数Ks分别为9.5mg/L和6.1mg/L,氨氮自身抑制常数KI分别为422mg/L和597mg/L.氨氮(而不是游离氨)对SNAD生物膜的厌氧氨氧化活性起主要抑制作用.%The effect of ammonium concentrations on the anaerobic ammonium oxidation (Anammox) activity of simultaneous partial nitrification, anaerobic ammonium oxidization and denitrification (SNAD) biofilm was investigated in batch tests. The SNAD biofilm reactor performed stable nitrogen removal performance with the influent of domestic wastewater. The average influent NH4+-N and COD concentrations were 70mg/L and 180mg/L, respectively. As a result, the average effluent NH4+-N, NO2--N and NO3--N concentrations were 2mg/L, 2mg/L, 7mg/L and 50mg/L, respectively. The SNAD biofilm performed good Anammox activity. The NH4+-N, NO2--N and total inorganic nitrogen (TIN) removal rates were 0.121kg N/(kg VSS·d), 0.180kg N/(kg VSS·d) and 0.267kg N/(kg VSS·d) with the initial NH4+-N and NO2--N concentrations of both 70mg/L. Moreover, Haldane model was applied to investigate the ammonium inhibition on the Anammox process. There is no obvious difference in kinetic
A drying coefficient for building materials
Scheffler, Gregor Albrecht; Plagge, Rudolf
2009-01-01
The drying experiment is an important element of the hygrothermal characterisation of building materials. Contrary to other moisture transport experiments as the vapour diffusion and the water absorption test, it is until now not possible to derive a simple coefficient for the drying. However...... coefficient is defined which can be determined based on measured drying data. The correlation of this coefficient with the water absorption and the vapour diffusion coefficient is analyzed and its additional information content is critically challenged. As result, a drying coefficient has been derived...... and defined as a new and independent material parameter. It contains information about the moisture transport properties throughout the wide range of moisture contents from hygroscopic up to saturation. With this new and valuable coefficient, it is now possible to distinguish and select building materials...
INVERSE COEFFICIENT PROBLEMS FOR PARABOLIC HEMIVARIATIONAL INEQUALITIES
Liu Zhenhai; I.Szántó
2011-01-01
This paper is devoted to the class of inverse problems for a nonlinear parabolic hemivariational inequality.The unknown coefficient of the operator depends on the gradient of the solution and belongs to a set of admissible coefficients.It is proved that the convergence of solutions for the corresponding direct problems continuously depends on the coefficient convergence.Based on this result the existence of a quasisolution of the inverse problem is obtained.
DIFFERENCE SCHEMES BASING ON COEFFICIENT APPROXIMATION
MOU Zong-ze; LONG Yong-xing; QU Wen-xiao
2005-01-01
In respect of variable coefficient differential equations, the equations of coefficient function approximation were more accurate than the coefficient to be frozen as a constant in every discrete subinterval. Usually, the difference schemes constructed based on Taylor expansion approximation of the solution do not suit the solution with sharp function.Introducing into local bases to be combined with coefficient function approximation, the difference can well depict more complex physical phenomena, for example, boundary layer as well as high oscillatory, with sharp behavior. The numerical test shows the method is more effective than the traditional one.
Magnetoelectric voltage coefficients of magnetoelectric composites
WAN Yong-ping; ZHONG Zheng; QIU Jin-hao
2006-01-01
The magnetoelectric(ME) effect of the particulate magnetostrictive/piezoelectric composite was theoretically studied. The dependence of the ME voltage coefficients on the material properties of the magnetostrictive phase was discussed. The permittivity,permeability and the elastic modulus of the magnetostrictive phase generally have obvious influences on the ME voltage coefficients. The magnetostrictive phase with a large permittivity,large permeability or stiffer modulus will respectively contribute to the higher ME voltage coefficients. For a certain kind of piezoelectric matrix,the ME voltage coefficients can be improved to some extent by choosing those magnetostrictive materials with large permittivity,permeability or high elastic modulus.
Why the Method of Undetermined Coefficients Works.
Ross, Clay C., Jr.
1991-01-01
This note presents a simple theorem which explains why the method of undetermined coefficients works in finding a particular solution, both for differential equations and difference equations. (Author)
Comparing linear probability model coefficients across groups
Holm, Anders; Ejrnæs, Mette; Karlson, Kristian Bernt
2015-01-01
This article offers a formal identification analysis of the problem in comparing coefficients from linear probability models between groups. We show that differences in coefficients from these models can result not only from genuine differences in effects, but also from differences in one or more...... of the following three components: outcome truncation, scale parameters and distributional shape of the predictor variable. These results point to limitations in using linear probability model coefficients for group comparisons. We also provide Monte Carlo simulations and real examples to illustrate...... these limitations, and we suggest a restricted approach to using linear probability model coefficients in group comparisons....
Why the Method of Undetermined Coefficients Works.
Ross, Clay C., Jr.
1991-01-01
This note presents a simple theorem which explains why the method of undetermined coefficients works in finding a particular solution, both for differential equations and difference equations. (Author)
Effective stress coefficient for uniaxial strain condition
Alam, Mohammad Monzurul; Fabricius, Ida Lykke
2012-01-01
the reason for change in effective stress coefficient under stress. Our model suggests that change in effective stress coefficient will be higher at uniaxial stress condition than at hydrostatic condition. We derived equations from the original definition of Biot to estimate effective stress coefficient from...... one dimensional rock mechanical deformation. We further investigated the effect of boundary condition on the stress dependency of effective stress coefficient and discussed its application in reservoir study. As stress field in the reservoirs are most unlikely to be hydrostatic, effective stress...
Inelastic Neutron Scattering and Separation Coefficient of Absorbed Hydrogen
Silvera, I. F.; Nielsen, Mourits
1976-01-01
Inelastic neutron scattering and measurement of the ortho-para separation coefficient have been used to study the low lying rotational states of molecular hydrogen adsorbed on activated alumina. The observations are consistent with a picture in which the orientational motion of the molecules...
Drag Coefficient of Thin Flexible Cylinder
Subramanian, Chelakara; Gurram, Harika
2015-11-01
Measurements of drag coefficients of thin flexible cylindrical wires are described for the Reynolds number range between 250 - 1000. Results indicate that the coefficient values are about 20 to 30 percent lower than the reported laminar flow values for rigid cylinders. Possible fluid dynamics mechanism causing the reduction in drag will be discussed.
Problems with Discontinuous Diffusion/Dispersion Coefficients
Stefano Ferraris
2012-01-01
accurate on smooth solutions and based on a special numerical treatment of the diffusion/dispersion coefficients that makes its application possible also when such coefficients are discontinuous. Numerical experiments confirm the convergence of the numerical approximation and show a good behavior on a set of benchmark problems in two space dimensions.
A gain-coefficient switched Alexandrite laser
Lee, Chris J.; Slot, van der Peter J.M.; Boller, Klaus-J.
2013-01-01
We report on a gain-coefficient switched Alexandrite laser. An electro-optic modulator is used to switch between high and low gain states by making use of the polarization dependent gain of Alexandrite. In gain-coefficient switched mode, the laser produces 85 ns pulses with a pulse energy of 240 mJ
Alternatives to Pearson's and Spearman's Correlation Coefficients
Smarandache, Florentin
2008-01-01
This article presents several alternatives to Pearson's correlation coefficient and many examples. In the samples where the rank in a discrete variable counts more than the variable values, the mixtures that we propose of Pearson's and Spearman's correlation coefficients give better results.
Efficient Estimation in Heteroscedastic Varying Coefficient Models
Chuanhua Wei
2015-07-01
Full Text Available This paper considers statistical inference for the heteroscedastic varying coefficient model. We propose an efficient estimator for coefficient functions that is more efficient than the conventional local-linear estimator. We establish asymptotic normality for the proposed estimator and conduct some simulation to illustrate the performance of the proposed method.
Estimating Runoff Coefficients Using Weather Radars
Ahm, Malte; Thorndahl, Søren Liedtke; Rasmussen, Michael R.
2012-01-01
This paper presents a method for estimating runoff coefficients of urban drainage catchments based on a combination of high resolution weather radar data and insewer flow measurements. By utilising the spatial variability of the precipitation it is possible to estimate the runoff coefficients...
Heat transfer coefficient for boiling carbon dioxide
Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik
1998-01-01
Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The calculated heat transfer coeeficient has been compared with the Chart correlation of Shah. The Chart Correlation predits too low heat transfer coefficient but the ratio...
Estimating Runoff Coefficients Using Weather Radars
Ahm, Malte; Thorndahl, Søren Liedtke; Rasmussen, Michael R.;
2012-01-01
This paper presents a method for estimating runoff coefficients of urban drainage catchments based on a combination of high resolution weather radar data and insewer flow measurements. By utilising the spatial variability of the precipitation it is possible to estimate the runoff coefficients...
Determination of the surface drag coefficient
Mahrt, L.; Vickers, D.; Sun, J.L.
2001-01-01
This study examines the dependence of the surface drag coefficient on stability, wind speed, mesoscale modulation of the turbulent flux and method of calculation of the drag coefficient. Data sets over grassland, sparse grass, heather and two forest sites are analyzed. For significantly unstable ...
Commentary on Coefficient Alpha: A Cautionary Tale
Green, Samuel B.; Yang, Yanyun
2009-01-01
The general use of coefficient alpha to assess reliability should be discouraged on a number of grounds. The assumptions underlying coefficient alpha are unlikely to hold in practice, and violation of these assumptions can result in nontrivial negative or positive bias. Structural equation modeling was discussed as an informative process both to…
Graphite friction coefficient for various conditions
2001-01-01
The friction coefficient the graphite used in the Tsinghua University 10MW High Tem-perature Gas-Cooled Reactor was analyzed for various conditions. The variation of the graphitefriction coefficient was measured for various sliding velocities, sliding distances, normal loads, en-vironments and temperatures. A scanning elector microscope (SEM) was used to analyze the fric-tion surfaces.
A gain-coefficient switched Alexandrite laser
Lee, Chris J; Boller, Klaus-J
2012-01-01
We report on a gain-coefficient switched Alexandrite laser. An electro-optic modulator is used to switch between high and low gain states by making use of the polarization dependent gain of Alexandrite. In gain-coefficient switched mode, the laser produces 85 ns pulses with a pulse energy of 240 mJ at a repetition rate of 5 Hz.
Helioseismic Solar Cycle Changes and Splitting Coefficients
S. C. Tripathy; Kiran Jain; A. Bhatnagar
2000-09-01
Using the GONG data for a period over four years, we have studied the variation of frequencies and splitting coefficients with solar cycle. Frequencies and even-order coefficients are found to change significantly with rising phase of the solar cycle. We also find temporal variations in the rotation rate near the solar surface.
In vivo lipid diffusion coefficient measurements in rat bone marrow.
Ababneh, Zaid Q; Beloeil, Helene; Berde, Charles B; Ababneh, Anas M; Maier, Stephan E; Mulkern, Robert V
2009-07-01
The diffusion coefficient of lipids, D(l), within bone marrow, fat deposits and metabolically active intracellular lipids in vivo will depend on several factors including the precise chemical composition of the lipid distribution (chain lengths, degree of unsaturation, etc.) as well as the temperature. As such, D(l) may ultimately prove of value in assessing abnormal fatty acid distributions linked to diseases such as cystic fibrosis, diabetes and coronary heart disease. A sensitive temperature dependence of D(l) may also prove of value for MR-guided thermal therapies for bone tumors or disease within other fatty tissues like the breast. Measuring diffusion coefficients of high molecular weight lipids in vivo is, however, technically difficult for a number of reasons. For instance, due to the much lower diffusion coefficients compared to water, much higher b factors than those used for central nervous system applications are needed. In addition, the pulse sequence design must incorporate, as much as possible, immunity to motion, susceptibility and chemical shift effects present whenever body imaging is performed. In this work, high b-factor line scan diffusion imaging sequences were designed, implemented and tested for D(l) measurement using a 4.7-T horizontal bore animal scanner. The gradient set available allowed for b factors as high as 0.03 micros/nm(2) (30,000 s/mm(2)) at echo times as short as 42 ms. The methods were used to measure lipid diffusion coefficients within the marrow of rat paws in vivo, yielding lipid diffusion coefficients approximately two orders of magnitude smaller than typical tissue water diffusion coefficients. Phantom experiments that demonstrate the sensitivity of lipid diffusion coefficients to chain length and temperature were also performed.
Gini coefficient as a life table function
2003-06-01
Full Text Available This paper presents a toolkit for measuring and analyzing inter-individual inequality in length of life by Gini coefficient. Gini coefficient and four other inequality measures are defined on the length-of-life distribution. Properties of these measures and their empirical testing on mortality data suggest a possibility for different judgements about the direction of changes in the degree of inequality by using different measures. A new computational procedure for the estimation of Gini coefficient from life tables is developed and tested on about four hundred real life tables. The estimates of Gini coefficient are precise enough even for abridged life tables with the final age group of 85+. New formulae have been developed for the decomposition of differences between Gini coefficients by age and cause of death. A new method for decomposition of age-components into effects of mortality and composition of population by group is developed. Temporal changes in the effects of elimination of causes of death on Gini coefficient are analyzed. Numerous empirical examples show: Lorenz curves for Sweden, Russia and Bangladesh in 1995, proportional changes in Gini coefficient and four other measures of inequality for the USA in 1950-1995 and for Russia in 1959-2000. Further shown are errors of estimates of Gini coefficient when computed from various types of mortality data of France, Japan, Sweden and the USA in 1900-95, decompositions of the USA-UK difference in life expectancies and Gini coefficients by age and cause of death in 1997. As well, effects of elimination of major causes of death in the UK in 1951-96 on Gini coefficient, age-specific effects of mortality and educational composition of the Russian population on changes in life expectancy and Gini coefficient between 1979 and 1989. Illustrated as well are variations in life expectancy and Gini coefficient across 32 countries in 1996-1999 and associated changes in life expectancy and Gini
An Efficient Approach for Computing Silhouette Coefficients
Moh'd B. Al- Zoubi
2008-01-01
Full Text Available One popular approach for finding the best number of clusters (K in a data set is through computing the silhouette coefficients. The silhouette coefficients for different values of K, are first found and then the maximum value of these coefficients is chosen. However, computing the silhouette coefficient for different Ks is a very time consuming process. This is due to the amount of CPU time spent on distance calculations. A proposed approach to compute the silhouette coefficient quickly had been presented. The approach was based on decreasing the number of addition operations when computing distances. The results were efficient and more than 50% of the CPU time was achieved when applied to different data sets.
Estimation of the simple correlation coefficient.
Shieh, Gwowen
2010-11-01
This article investigates some unfamiliar properties of the Pearson product-moment correlation coefficient for the estimation of simple correlation coefficient. Although Pearson's r is biased, except for limited situations, and the minimum variance unbiased estimator has been proposed in the literature, researchers routinely employ the sample correlation coefficient in their practical applications, because of its simplicity and popularity. In order to support such practice, this study examines the mean squared errors of r and several prominent formulas. The results reveal specific situations in which the sample correlation coefficient performs better than the unbiased and nearly unbiased estimators, facilitating recommendation of r as an effect size index for the strength of linear association between two variables. In addition, related issues of estimating the squared simple correlation coefficient are also considered.
Discharge coefficient of small sonic nozzles
Yin Zhao-Qin
2014-01-01
Full Text Available The purpose of this investigation is to understand flow characteristics in mini/micro sonic nozzles, in order to precisely measure and control miniscule flowrates. Experimental and numerical simulation methods have been used to study critical flow Venturi nozzles. The results show that the nozzle’s size and shape influence gas flow characteristics which leading the boundary layer thickness to change, and then impact on the discharge coefficient. With the diameter of sonic nozzle throat decreasing, the discharge coefficient reduces. The maximum discharge coefficient exits in the condition of the inlet surface radius being double the throat diameter. The longer the diffuser section, the smaller the discharge coefficient becomes. Diffuser angle affects the discharge coefficient slightly.
Estimating beta-mixing coefficients via histograms
McDonald, Daniel J; Schervish, Mark
2011-01-01
The literature on statistical learning for time series often assumes asymptotic independence or "mixing" of data sources. Beta-mixing has long been important in establishing the central limit theorem and invariance principle for stochastic processes; recent work has identified it as crucial to extending results from empirical processes and statistical learning theory to dependent data, with quantitative risk bounds involving the actual beta coefficients. There is, however, presently no way to actually estimate those coefficients from data; while general functional forms are known for some common classes of processes (Markov processes, ARMA models, etc.), specific coefficients are generally beyond calculation. We present an l1-risk consistent estimator for the beta-mixing coefficients, based on a single stationary sample path. Since mixing coefficients involve infinite-order dependence, we use an order-d Markov approximation. We prove high-probability concentration results for the Markov approximation and show...
Critical exponents from cluster coefficients
Rotman, Z.; Eisenberg, E.
2009-09-01
For a large class of repulsive interaction models, the Mayer cluster integrals can be transformed into a tridiagonal real symmetric matrix Rmn , whose elements converge to two constants. This allows for an effective extrapolation of the equation of state for these models. Due to a nearby (nonphysical) singularity on the negative real z axis, standard methods (e.g., Padé approximants based on the cluster integrals expansion) fail to capture the behavior of these models near the ordering transition, and, in particular, do not detect the critical point. A recent work [E. Eisenberg and A. Baram, Proc. Natl. Acad. Sci. U.S.A. 104, 5755 (2007)] has shown that the critical exponents σ and σ' , characterizing the singularity of the density as a function of the activity, can be exactly calculated if the decay of the R matrix elements to their asymptotic constant follows a 1/n2 law. Here we employ renormalization group (RG) arguments to extend this result and analyze cases for which the asymptotic approach of the R matrix elements toward their limiting value is of a more general form. The relevant asymptotic correction terms (in RG sense) are identified, and we then present a corrected exact formula for the critical exponents. We identify the limits of usage of the formula and demonstrate one physical model, which is beyond its range of validity. The formula is validated numerically and then applied to analyze a number of concrete physical models.
Hall coefficient of insulating n-type CdSe
Roy, A.; Levy, M.; Guo, X.M.; Sarachik, M.P.; Ledesma, R.; Isaacs, L.L.
1989-05-15
We report measurements of the conductivity and Hall coefficient of insulating n-type CdSe with dopant concentrations near the critical concentration for the metal-insulator transition. In the temperature range 1.2--4.2 K, where the resistivity is consistent with variable-range hopping, the Hall coefficient is finite and observable and follows an analogous temperature dependence, R/sub H//similar to/exp(K/sub H/(T/sub 0//T)/sup n/). We find n<1, so that the observed Hall coefficient is not due to carriers activated to extended states; the data are consistent instead with an exponent n = 1/4 or 1/2. We compare this result with previous experiments and with current theory.
Takebe, Shinichi; Abe, Masayoshi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment
2001-03-01
The distribution coefficient is very important parameter for environmental impact assessment on the disposal of radioactive waste arising from research institutes. The literature survey in the country was mainly carried out for the purpose of selecting the reasonable distribution coefficient value on the utilization of this value in the safety evaluation. This report was arranged much informations on the distribution coefficient for inputting to the database for each literature, and was summarized as a literature information data on the distribution coefficient. (author)
Tracking time-varying coefficient-functions
Nielsen, Henrik Aalborg; Nielsen, Torben Skov; Joensen, Alfred K.;
2000-01-01
is a combination of recursive least squares with exponential forgetting and local polynomial regression. It is argued, that it is appropriate to let the forgetting factor vary with the value of the external signal which is the argument of the coefficient functions. Some of the key properties of the modified method......, but otherwise unknown, functions of a low-dimensional input process. These coefficient functions are estimated adaptively and recursively without specifying a global parametric, form, i.e. the method allows for online tracking of the coefficient functions. Essentially, in its most simple form, the method...
Spatial correlation coefficient images for ultrasonic detection.
Cepel, Raina; Ho, K C; Rinker, Brett A; Palmer, Donald D; Lerch, Terrence P; Neal, Steven P
2007-09-01
In ultrasonics, image formation and detection are generally based on signal amplitude. In this paper, we introduce correlation coefficient images as a signal-amplitude independent approach for image formation. The correlation coefficients are calculated between A-scans digitized at adjacent measurement positions. In these images, defects are revealed as regions of high or low correlation relative to the background correlations associated with noise. Correlation coefficient and C-scan images are shown to demonstrate flat-bottom-hole detection in a stainless steel annular ring and crack detection in an aluminum aircraft structure.
Coefficient of restitution of aspherical particles.
Glielmo, Aldo; Gunkelmann, Nina; Pöschel, Thorsten
2014-11-01
We consider the motion of an aspherical inelastic particle of dumbbell type bouncing repeatedly on a horizontal flat surface. The coefficient of restitution of such a particle depends not only on material properties and impact velocity but also on the angular orientation at the instant of the collision whose variance is considerable, even for small eccentricity. Assuming random angular orientation of the particle at the instant of contact we characterize the measured coefficient of restitution as a fluctuating quantity and obtain a wide probability density function including a finite probability for negative values of the coefficient of restitution. This may be understood from the partial exchange of translational and rotational kinetic energy.
Heat transfer coefficient for boiling carbon dioxide
Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik
1998-01-01
between the measured and the calculated heat transfer coefficient is nearly constant and equal 1.9. With this factor the correlation predicts the measured data within 14% (RMS). The pressure drop is of the same order as the measuring uncertainty and the pressure drop has not been compared with correlation's.......Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The calculated heat transfer coeeficient has been compared with the Chart correlation of Shah. The Chart Correlation predits too low heat transfer coefficient but the ratio...
Soccer ball lift coefficients via trajectory analysis
Goff, John Eric [Department of Physics, Lynchburg College, Lynchburg, VA 24501 (United States); Carre, Matt J, E-mail: goff@lynchburg.ed [Department of Mechanical Engineering, University of Sheffield, Sheffield S1 3JD (United Kingdom)
2010-07-15
We performed experiments in which a soccer ball was launched from a machine while two high-speed cameras recorded portions of the trajectory. Using the trajectory data and published drag coefficients, we extracted lift coefficients for a soccer ball. We determined lift coefficients for a wide range of spin parameters, including several spin parameters that have not been obtained by today's wind tunnels. Our trajectory analysis technique is not only a valuable tool for professional sports scientists, it is also accessible to students with a background in undergraduate-level classical mechanics.
Inferences on the common coefficient of variation.
Tian, Lili
2005-07-30
The coefficient of variation is often used as a measure of precision and reproducibility of data in medical and biological science. This paper considers the problem of making inference about the common population coefficient of variation when it is a priori suspected that several independent samples are from populations with a common coefficient of variation. The procedures for confidence interval estimation and hypothesis testing are developed based on the concepts of generalized variables. The coverage properties of the proposed confidence intervals and type-I errors of the proposed tests are evaluated by simulation. The proposed methods are illustrated by a real life example.
Heat transfer coefficient of cryotop during freezing.
Li, W J; Zhou, X L; Wang, H S; Liu, B L; Dai, J J
2013-01-01
Cryotop is an efficient vitrification method for cryopreservation of oocytes. It has been widely used owing to its simple operation and high freezing rate. Recently, the heat transfer performance of cryotop was studied by numerical simulation in several studies. However, the range of heat transfer coefficient in the simulation is uncertain. In this study, the heat transfer coefficient for cryotop during freezing process was analyzed. The cooling rates of 40 percent ethylene glycol (EG) droplet in cryotop during freezing were measured by ultra-fast measurement system and calculated by numerical simulation at different value of heat transfer coefficient. Compared with the results obtained by two methods, the range of the heat transfer coefficient necessary for the numerical simulation of cryotop was determined, which is between 9000 W/(m(2)·K) and 10000 W/(m (2)·K).
Neutron kerma coefficient: Reference tissue for tumours
Paredes, L., E-mail: lydia.paredes@inin.gob.m [National Institute of Nuclear Research (Mexico); Azorin, J. [Basic Sciences Division, Autonomous Metropolitan University (Mexico); Balcazar, M. [National Institute of Nuclear Research (Mexico); Francois, J.L. [Engineering Faculty, Autonomous National University of Mexico (Mexico)
2010-12-15
Neutron kerma coefficients were calculated in different media: 4 malignant tumours, 5 normal tissues and 3 tissue substitute in the range 11 eV-29 MeV. The objective was to identify which is the material that better reproduces the behavior of these tumours and tissues. These tissues have clinical interest in interstitial brachytherapy applications with fast neutron source (Cf-252). The small differences of elemental composition among these tissues produce variation in the neutron kerma coefficients. The results show that the neutron kerma coefficients for malignant tumours are smaller than soft tissue from 6% to 9%. Also, the muscle is the tissue that best represents the dosimetric behavior for the tumours and tissues analyzed in this paper for neutron energies >1 keV, where this coefficients show minor variation.
Friction coefficient dependence on electrostatic tribocharging
Burgo, Thiago A. L.; Silva, Cristiane A.; Balestrin, Lia B. S.; Galembeck, Fernando
2013-08-01
Friction between dielectric surfaces produces patterns of fixed, stable electric charges that in turn contribute electrostatic components to surface interactions between the contacting solids. The literature presents a wealth of information on the electronic contributions to friction in metals and semiconductors but the effect of triboelectricity on friction coefficients of dielectrics is as yet poorly defined and understood. In this work, friction coefficients were measured on tribocharged polytetrafluoroethylene (PTFE), using three different techniques. As a result, friction coefficients at the macro- and nanoscales increase many-fold when PTFE surfaces are tribocharged, but this effect is eliminated by silanization of glass spheres rolling on PTFE. In conclusion, tribocharging may supersede all other contributions to macro- and nanoscale friction coefficients in PTFE and probably in other insulating polymers.
Cohomology with Coefficients for Operadic Coalgebras
Anita Majumdar; Donald Yau
2009-09-01
Corepresentations of a coalgebra over a quadratic operad are defined, and various characterizations of them are given. Cohomology of such an operadic coalgebra with coefficients in a corepresentation is then studied.
Gao, R.; Leeuwen, van H.P.; Valenberg, van H.J.F.; Boekel, van M.A.J.S.
2011-01-01
Calcium ion selective electrode (Ca-ISE) was found to underestimate the actual Ca2+ ion activity in simulated milk ultrafiltrate (SMUF) and milk. It is shown that the ionic compositional difference between conventional calibration solutions and milk type samples had a significant effect on the singl
Torsion method for measuring piezooptic coefficients
Skab, I.; Smaga, I.; Savaryn, V.; Vasylkiv, Yu.; Vlokh, R. [Institute of Physical Optics, Lviv (Ukraine)
2011-01-15
We develop and describe analytically a torsion method for measuring piezooptic coefficients associated with shear stresses. It is shown that the method enables to increase significantly the accuracy of determination of piezooptic coefficients. The method and the appropriate apparatus are verified experimentally on the example of LiNbO{sub 3} crystals. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Diffusion coefficients in viscous sodium alginate solutions
Aoki, K.; Wang, B; Chen, J.; Nishiumi, T.
2012-01-01
Sodium alginate solution, being viscous hydrocolloid, was examined voltammetricallyin the context of viscous effects by use of a ferrocenyl compound as a redox probe.Voltammograms were almost independent of concentrations of sodium alginate even ina solid-like state. Diffusion coefficients of the ferrocenyl compound did not vary withviscosity evaluated by a viscometer. Ionic conductivity of sodium alginate was alsoindependent of the viscosity. In contrast, diffusion coefficients of the latex ...
Thermal expansion coefficient of binary semiconductors
Kumar, V.; Sastry, B.S.R. [Indian School of Mines, Dhanbad (India). Dept. of Electronics and Instrumentation
2001-07-01
The linear thermal expansion coefficient of tetrahedrally coordinated A{sup II}B{sup VI} and A{sup III}B{sup V} semiconductors has been calculated using plasmon energy data. A simple relation between the bond length and plasmon energy has been derived. The calculated values of thermal expansion coefficient and bond length have been compared with the experimental values and the values reported by different workers. An excellent experiment has been obtained between them. (orig.)
Measuring Resource Inequality: The Gini Coefficient
Michael T. Catalano
2009-07-01
Full Text Available This paper stems from work done by the authors at the Mathematics for Social Justice Workshop held in June of 2007 at Middlebury College. We provide a description of the Gini coefficient and some discussion of how it can be used to promote quantitative literacy skills in mathematics courses. The Gini Coefficient was introduced in 1921 by Italian statistician Corrado Gini as a measure of inequality. It is defined as twice the area between two curves. One, the Lorenz curve for a given population with respect to a given resource, represents the cumulative percentage of the resource as a function of the cumulative percentage of the population that shares that percentage of the resource. The second curve is the line y = x which is the Lorenz curve for a population which shares the resource equally. The Gini coefficient can be interpreted as the percentage of inequality represented in the population with respect to the given resource. We propose that the Gini coefficient can be used to enhance students’ understanding of calculus concepts and provide practice for students in using both calculus and quantitative literacy skills. Our examples are based mainly on distribution of energy resources using publicly available data from the Energy Information Agency of the United States Government. For energy resources within the United States, we find that by household, the Gini coefficient is 0.346, while using the 51 data points represented by the states and Washington D.C., the Gini coefficient is 0.158. When we consider the countries of the world as a population of 210, the Gini coefficient is 0.670. We close with ideas for questions which can be posed to students and discussion of the experiences two other mathematics instructors have had incorporating the Gini coefficient into pre-calculus-level mathematics classes.
Thermal Expansion Coefficients of Thin Crystal Films
无
2005-01-01
The formulas for atomic displacements and Hamiltonian of a thin crystal film in phonon occupation number representation are obtained with the aid of Green's function theory. On the basis of these results, the formulas for thermal expansion coefficients of the thin crystal film are derived with the perturbation theory, and the numerical calculations are carried out. The results show that the thinner films have larger thermal expansion coefficients.
Concordance correlation coefficient applied to discrete data.
Carrasco, Josep L; Jover, Lluis
2005-12-30
In any field in which decisions are subject to measurements, interchangeability between the methods used to obtain these measurements is essential. To consider methods as interchangeable, a certain degree of agreement is needed between the measurements they provide. The concordance correlation coefficient is an index that assesses the strength of agreement and it has been widely applied in situations in which measurements are made on a continuous scale. Recently the concordance correlation coefficient has been defined as a specific intraclass correlation coefficient estimated by the variance components of a Normal-Normal mixed linear model. Although this coefficient was defined for the continuous scale case, it may also be used with a discrete scale. In this case the data are often transformed and normalized, and the concordance correlation is applied. This study discusses the expression of the concordance correlation coefficient for discrete Poisson data by means of the Poisson-Normal generalized linear mixed model. The behaviour of the concordance correlation coefficient estimate is assessed by means of a simulation study, in which the estimates were compared using four models: three Normal-Normal mixed models with raw data, log-transformed data and square-root transformed data, and the Poisson-Normal generalized linear mixed model. An example is provided in which two different methods are used to measure CD34+ cells.
Local Rank Inference for Varying Coefficient Models.
Wang, Lan; Kai, Bo; Li, Runze
2009-12-01
By allowing the regression coefficients to change with certain covariates, the class of varying coefficient models offers a flexible approach to modeling nonlinearity and interactions between covariates. This paper proposes a novel estimation procedure for the varying coefficient models based on local ranks. The new procedure provides a highly efficient and robust alternative to the local linear least squares method, and can be conveniently implemented using existing R software package. Theoretical analysis and numerical simulations both reveal that the gain of the local rank estimator over the local linear least squares estimator, measured by the asymptotic mean squared error or the asymptotic mean integrated squared error, can be substantial. In the normal error case, the asymptotic relative efficiency for estimating both the coefficient functions and the derivative of the coefficient functions is above 96%; even in the worst case scenarios, the asymptotic relative efficiency has a lower bound 88.96% for estimating the coefficient functions, and a lower bound 89.91% for estimating their derivatives. The new estimator may achieve the nonparametric convergence rate even when the local linear least squares method fails due to infinite random error variance. We establish the large sample theory of the proposed procedure by utilizing results from generalized U-statistics, whose kernel function may depend on the sample size. We also extend a resampling approach, which perturbs the objective function repeatedly, to the generalized U-statistics setting; and demonstrate that it can accurately estimate the asymptotic covariance matrix.
Fourier coefficient description of left ventricular shape.
Round, W H; Bates, R H; Ikram, H
1991-12-01
A method of quantifying the shape of the left ventricle of the heart as seen in 2D echocardiograms was developed. It is based on describing the shape in terms of the coefficients a fifth-order trigonometric Fourier series. Such a series has eleven Fourier coefficients which is too large a number for clinical application so pairs of coefficients are combined to give six coefficients (alpha 0, alpha 1, ... , alpha 5). A trial was conducted to test the ability of the coefficient description to classify subjects as having normal right ventricles or ventricles with an apical abnormality. The tests showed that one of the coefficients (alpha 2) was higher for the subjects with an apical abnormality and that this difference increased with exercise. This is as was expected. However, it was found to be difficult to get a reliable estimate of alpha 2 from a single scan of a patient and that it is therefore probably necessary to average data from several scans to obtain a reliable alpha 2 value for a single patient.
A novel method for measuring polymer-water partition coefficients.
Zhu, Tengyi; Jafvert, Chad T; Fu, Dafang; Hu, Yue
2015-11-01
Low density polyethylene (LDPE) often is used as the sorbent material in passive sampling devices to estimate the average temporal chemical concentration in water bodies or sediment pore water. To calculate water phase chemical concentrations from LDPE concentrations accurately, it is necessary to know the LDPE-water partition coefficients (KPE-w) of the chemicals of interest. However, even moderately hydrophobic chemicals have large KPE-w values, making direct measurement experimentally difficult. In this study we evaluated a simple three phase system from which KPE-w can be determined easily and accurately. In the method, chemical equilibrium distribution between LDPE and a surfactant micelle pseudo-phase is measured, with the ratio of these concentrations equal to the LDPE-micelle partition coefficient (KPE-mic). By employing sufficient mass of polymer and surfactant (Brij 30), the mass of chemical in the water phase remains negligible, albeit in equilibrium. In parallel, the micelle-water partition coefficient (Kmic-w) is determined experimentally. KPE-w is the product of KPE-mic and Kmic-w. The method was applied to measure values of KPE-w for 17 polycyclic aromatic hydrocarbons, 37 polychlorinated biphenyls, and 9 polybrominated diphenylethers. These values were compared to literature values. Mass fraction-based chemical activity coefficients (γ) were determined in each phase and showed that for each chemical, the micelles and LDPE had nearly identical affinity.
Temporal correlation coefficient for directed networks.
Büttner, Kathrin; Salau, Jennifer; Krieter, Joachim
2016-01-01
Previous studies dealing with network theory focused mainly on the static aggregation of edges over specific time window lengths. Thus, most of the dynamic information gets lost. To assess the quality of such a static aggregation the temporal correlation coefficient can be calculated. It measures the overall possibility for an edge to persist between two consecutive snapshots. Up to now, this measure is only defined for undirected networks. Therefore, we introduce the adaption of the temporal correlation coefficient to directed networks. This new methodology enables the distinction between ingoing and outgoing edges. Besides a small example network presenting the single calculation steps, we also calculated the proposed measurements for a real pig trade network to emphasize the importance of considering the edge direction. The farm types at the beginning of the pork supply chain showed clearly higher values for the outgoing temporal correlation coefficient compared to the farm types at the end of the pork supply chain. These farm types showed higher values for the ingoing temporal correlation coefficient. The temporal correlation coefficient is a valuable tool to understand the structural dynamics of these systems, as it assesses the consistency of the edge configuration. The adaption of this measure for directed networks may help to preserve meaningful additional information about the investigated network that might get lost if the edge directions are ignored.
Experimental methodology for obtaining sound absorption coefficients
Carlos A. Macía M
2011-07-01
Full Text Available Objective: the authors propose a new methodology for estimating sound absorption coefficients using genetic algorithms. Methodology: sound waves are generated and conducted along a rectangular silencer. The waves are then attenuated by the absorbing material covering the silencer’s walls. The attenuated sound pressure level is used in a genetic algorithm-based search to find the parameters of the proposed attenuation expressions that include geometric factors, the wavelength and the absorption coefficient. Results: a variety of adjusted mathematical models were found that make it possible to estimate the absorption coefficients based on the characteristics of a rectangular silencer used for measuring the attenuation of the noise that passes through it. Conclusions: this methodology makes it possible to obtain the absorption coefficients of new materials in a cheap and simple manner. Although these coefficients might be slightly different from those obtained through other methodologies, they provide solutions within the engineering accuracy ranges that are used for designing noise control systems.
Drag Coefficient and Foam in Hurricane Conditions.
Golbraikh, E.; Shtemler, Y.
2016-12-01
he present study is motivated by recent findings of saturation and even decrease in the drag coefficient (capping) in hurricane conditions, which is accompanied by the production of a foam layer on the ocean surface. As it is difficult to expect at present a comprehensive numerical modeling of the drag coefficient saturation that is followed by wave breaking and foam production, there is no complete confidence and understanding of the saturation phenomenon. Our semi-empirical model is proposed for the estimation of the foam impact on the variation of the effective drag coefficient, Cd , with the reference wind speed U10 in stormy and hurricane conditions. The proposed model treats the efficient air-sea aerodynamic roughness length as a sum of two weighted aerodynamic roughness lengths for the foam-free and foam-covered conditions. On the available optical and radiometric measurements of the fractional foam coverage,αf, combined with direct wind speed measurements in hurricane conditions, which provide the minimum of the effective drag coefficient, Cd for the sea covered with foam. The present model yields Cd10 versus U10 in fair agreement with that evaluated from both open-ocean and laboratory measurements of the vertical variation of mean wind speed in the range of U10 from low to hurricane speeds. The present approach opens opportunities for drag coefficient modeling in hurricane conditions and hurricane intensity estimation by the foam-coverage value using optical and radiometric measurements.
Correlation coefficient measurement of the mode-locked laser tones using four-wave mixing.
Anthur, Aravind P; Panapakkam, Vivek; Vujicic, Vidak; Merghem, Kamel; Lelarge, Francois; Ramdane, Abderrahim; Barry, Liam P
2016-06-01
We use four-wave mixing to measure the correlation coefficient of comb tones in a quantum-dash mode-locked laser under passive and active locked regimes. We study the uncertainty in the measurement of the correlation coefficient of the proposed method.
Determination of the gas-to-membrane mass transfer coefficient in a catalytic membrane reactor
Veldsink, J.W.; Versteeg, G.F.; Swaaij, W.P.M. van
1995-01-01
A novel method to determine the external mass transfer coefficient in catalytic membrane reactors (Sloot et al., 1992a, b) was presented in this study. In a catalytically active membrane reactor, in which a very fast reaction occurs, the external transfer coefficient can conveniently be measured by
Determination of the gas-to-membrane mass transfer coefficient in a catalytic membrane reactor
Veldsink, J.W.; Versteeg, G.F.; Swaaij, W.P.M. van
1995-01-01
A novel method to determine the external mass transfer coefficient in catalytic membrane reactors (Sloot et al., 1992a, b) was presented in this study. In a catalytically active membrane reactor, in which a very fast reaction occurs, the external transfer coefficient can conveniently be measured by
Paszkuta, M.; Rosanne, M.; Adler, P.M. [Sisyphe, 75 - Paris (France)
2006-10-15
The coefficients that characterize the simultaneous transports of mass, heat, solute and current through compact clays are experimentally and theoretically determined. The role of a characteristic length scale that can be derived from conductivity and permeability is illustrated for the electrokinetic coefficients. The macroscopic Soret coefficient in clays was found five times larger than in the free fluid, presumably because of extra couplings with electrical phenomena. (authors)
Effect of Rare Earths on Diffusion Coefficient and Transfer Coefficient of Carbon during Carburizing
无
2001-01-01
The diffusion coefficient of carbon in surface layer of steel-20 rare earth carburized at 880 ℃ and 900 ℃ for 8 h was calculated by substituting the measured layer depths into the diffusion equation. The mathematical model of the transfer coefficient of carbon was deduced based on the kinetics of weight gain during gas carburizing. The calculated results show that the main reason why the gas carburizing process is accelerated is due to the obvious increase in the diffusion coefficient and transfer coefficient of carbon resulted from the addition of RE.
Coefficient of Restitution of Wet Tennis Balls
Eugene Jang
2014-12-01
Full Text Available The coefficient of restitution of a damp tennis ball is of interest to tennis players. Using a spray bottle, water was added to a tennis ball and the mass of water on the wet ball was determined. The ball was then dropped from a fixed height of 0.86 m. The motion was recorded with a video camera and the bounce height was measured. Using the bounce height and the original height, the coefficient of restitution for that mass of added water was determined. The research found the mass of water added to the tennis ball to have a negatively linear relationship with the coefficient of restitution of the tennis ball.
Coefficient of Restitution of Wet Tennis Balls
Eugene Jang
2014-01-01
Full Text Available The coefficient of restitution of a damp tennis ball is of interest to tennis players. Using a spray bottle, water was added to a tennis ball and the mass of water on the wet ball was determined. The ball was then dropped from a fixed height of 0.86 m. The motion was recorded with a video camera and the bounce height was measured. Using the bounce height and the original height, the coefficient of restitution for that mass of added water was determined. The research found the mass of water added to the tennis ball to have a negatively linear relationship with the coefficient of restitution of the tennis ball.
Curvature of Indoor Sensor Network: Clustering Coefficient
2009-03-01
Full Text Available We investigate the geometric properties of the communication graph in realistic low-power wireless networks. In particular, we explore the concept of the curvature of a wireless network via the clustering coefficient. Clustering coefficient analysis is a computationally simplified, semilocal approach, which nevertheless captures such a large-scale feature as congestion in the underlying network. The clustering coefficient concept is applied to three cases of indoor sensor networks, under varying thresholds on the link packet reception rate (PRR. A transition from positive curvature (“meshed” network to negative curvature (“core concentric” network is observed by increasing the threshold. Even though this paper deals with network curvature per se, we nevertheless expand on the underlying congestion motivation, propose several new concepts (network inertia and centroid, and finally we argue that greedy routing on a virtual positively curved network achieves load balancing on the physical network.
Estimating inbreeding coefficients from NGS data
Vieira, Filipe Garrett; Fumagalli, Matteo; Albrechtsen, Anders;
2013-01-01
Most methods for Next-Generation Sequencing (NGS) data analyses incorporate information regarding allele frequencies using the assumption of Hardy-Weinberg Equilibrium (HWE) as a prior. However, many organisms including domesticated, partially selfing or with asexual life cycles show strong...... deviations from HWE. For such species, and specially for low coverage data, it is necessary to obtain estimates of inbreeding coefficients (F) for each individual beforecalling genotypes. Here, we present two methods for estimating inbreeding coefficients from NGS data based on an Expectation...
Effective Diffusion Coefficients in Coal Chars
Johnsson, Jan Erik; Jensen, Anker
2001-01-01
Knowledge of effective diffusion coefficients in char particles is important when interpreting experimental reactivity measurements and modeling char combustion or NO and N2O reduction. In this work, NO and N2O reaction with a bituminous coal char was studied in a fixed-bed quartz glass reactor....... The experimental results were compared with theoretical values calculated from the mean pore radius and the cross-linked pore model. The method of mean pore radius underestimated the effective diffusion coefficient more than an order of magnitude. Using the cross-linked pore model, the bimodal pore size...
Sensitivity study of control rod depletion coefficients
Blomberg, Joel
2015-01-01
This report investigates the sensitivity of the control rod depletion coefficients, Sg, to different input parameters and how this affects the accumulated 10B depletion, β. Currently the coefficients are generated with PHOENIX4, but the geometries can be more accurately simulated in McScram. McScram is used to calculate Control Rod Worth, which in turn is used to calculate Nuclear End Of Life, and Sg cannot be generated in the current version of McScram. Therefore, it is also analyzed whether...
Study on the Friction Coefficient in Grinding
无
2002-01-01
The friction between the abrasive grains and workpi ec e is a crutial factor determining the main grinding output. Few studies have bee n carried out investigating the values of the friction coefficient in grinding, due to the difficulty of direct measurement. In this paper, a mathematical model of the friction coefficient in grinding has been established with the aid of a new grinding parameter C ge, which has close relations to wheel wear rate Z s, metal removal rate Z w, specific energy u and gr...
Monomeric Friction Coefficient of Metalnanodispersible Polymeric Systems
B.B. Kolupayev
2016-12-01
Full Text Available Influence of a nanodispersible metal excipient in number of 0 5,0 vol.% Cu for the size of a monomeric friction coefficient of polyvinylchloride (PVC systems in temperature range 298 Т (Tg + 10 K is investigated. It is shown that various types of coordination movements of building blocks are described by a friction coefficient which serves as a measure of influence of external fields and ingredients on viscoelastic behavior of a composite. The analysis of processes of a relaxation on the basis of the theory of flexible chains taking into account power and entropic factors is carried out.
Effective stress coefficient for uniaxial strain condition
Alam, M.M.; Fabricius, I.L.
2012-01-01
one dimensional rock mechanical deformation. We further investigated the effect of boundary condition on the stress dependency of effective stress coefficient and discussed its application in reservoir study. As stress field in the reservoirs are most unlikely to be hydrostatic, effective stress...... determined under uniaxial strain condition will be more relevant in reservoir studies. Copyright 2012 ARMA, American Rock Mechanics Association....
Effective stress coefficient for uniaxial strain condition
Alam, Mohammad Monzurul; Fabricius, Ida Lykke
2012-01-01
one dimensional rock mechanical deformation. We further investigated the effect of boundary condition on the stress dependency of effective stress coefficient and discussed its application in reservoir study. As stress field in the reservoirs are most unlikely to be hydrostatic, effective stress...
Confidence Intervals for Cronbach's Coefficient Alpha Values
A.J. Koning (Alex); Ph.H.B.F. Franses (Philip Hans)
2003-01-01
textabstractCoefficient Alpha, which is widely used in empirical research, estimates the reliability of a test consisting of parallel items. In practice it is difficult to compare values of alpha across studies as it depends on the number of items used. In this paper we provide a simple solution, wh
Recursive Construction of Operator Product Expansion Coefficients
Holland, Jan; Hollands, Stefan
2015-06-01
We derive a novel formula for the derivative of operator product expansion (OPE) coefficients with respect to a coupling constant. The formula involves just the OPE coefficients themselves but no further input, and is in this sense self-consistent. Furthermore, unlike other formal identities of this general nature in quantum field theory (such as the formal expression for the Lagrangian perturbation of a correlation function), our formula requires no further UV-renormalization, i.e., it is completely well-defined from the start. This feature is a result of a cancelation of UV- and IR-divergences between various terms in our identity. Our proof, and an analysis of the features of the identity, is given for the example of massive, Euclidean theory in 4 dimensional Euclidean space. It relies on the renormalization group flow equation method and is valid to arbitrary, but finite orders in perturbation theory. The final formula, however, makes neither explicit reference to the renormalization group flow, nor to perturbation theory, and we conjecture that it also holds non-perturbatively. Our identity can be applied constructively because it gives a novel recursive algorithm for the computation of OPE coefficients to arbitrary (finite) perturbation order in terms of the zeroth order coefficients corresponding to the underlying free field theory, which in turn are trivial to obtain. We briefly illustrate the relation of this method to more standard methods for computing the OPE in some simple examples.
Coefficient Omega Bootstrap Confidence Intervals: Nonnormal Distributions
Padilla, Miguel A.; Divers, Jasmin
2013-01-01
The performance of the normal theory bootstrap (NTB), the percentile bootstrap (PB), and the bias-corrected and accelerated (BCa) bootstrap confidence intervals (CIs) for coefficient omega was assessed through a Monte Carlo simulation under conditions not previously investigated. Of particular interests were nonnormal Likert-type and binary items.…
Molar extinction coefficients of some fatty acids
Sandhu, G.K.; Singh, K.; Lark, B.S.;
2002-01-01
) and stearic acid (C18H36O2), has been measured at the photon energies 81, 356, 511, 662, 1173 and 1332 keV. Experimental values for the molar extinction coefficient, the effective atomic number and the electron density have been derived and compared with theoretical calculations. There is good agreement...
Determination of the convective heat transfer coefficient
Spierings, D.; Bosman, F.; Peters, T.; Plasschaert, F.
1987-01-01
The value of the convective heat transfer coefficient (htc) is determined under different loading conditions by using a computer aided method. The thermal load has been applied mathematically as well as experimentally to the coronal surface of an axisymmetric tooth model. To verify the assumptions m
Infinite matrices, wavelet coefficients and frames
N. A. Sheikh
2004-01-01
Full Text Available We study the action of A on f∈L2(ℝ and on its wavelet coefficients, where A=(almjklmjk is a double infinite matrix. We find the frame condition for A-transform of f∈L2(ℝ whose wavelet series expansion is known.
Probability based calibration of pressure coefficients
Hansen, Svend Ole; Pedersen, Marie Louise; Sørensen, John Dalsgaard
2015-01-01
not depend on the type of variable action. A probability based calibration of pressure coefficients have been carried out using pressure measurements on the standard CAARC building modelled on scale of 1:383. The extreme pressures measured on the CAARC building model in the wind tunnel have been fitted...
Quantum Correlation Coefficients for Angular Coherent States
CHEN Wei; HE Yan; GUO Hao
2009-01-01
Quantum covariance and correlation coefficients of angular or SU(2) coherent states are directly calculated for all irreducible unitary representations.These results explicitly verify that the angular coherent states minimize the Robertson-Schrodinger uncertainty relation for all spins, which means that they are the so-called intelligent states.The same results can be obtained by the Schwinger representation approach.
Computer programs for the concordance correlation coefficient.
Crawford, Sara B; Kosinski, Andrzej S; Lin, Hung-Mo; Williamson, John M; Barnhart, Huiman X
2007-10-01
The CCC macro is presented for computation of the concordance correlation coefficient (CCC), a common measure of reproducibility. The macro has been produced in both SAS and R, and a detailed presentation of the macro input and output for the SAS program is included. The macro provides estimation of three versions of the CCC, as presented by Lin [L.I.-K. Lin, A concordance correlation coefficient to evaluate reproducibility, Biometrics 45 (1989) 255-268], Barnhart et al. [H.X. Barnhart, J.L. Haber, J.L. Song, Overall concordance correlation coefficient for evaluating agreement among multiple observers, Biometrics 58 (2002) 1020-1027], and Williamson et al. [J.M. Williamson, S.B. Crawford, H.M. Lin, Resampling dependent concordance correlation coefficients, J. Biopharm. Stat. 17 (2007) 685-696]. It also provides bootstrap confidence intervals for the CCC, as well as for the difference in CCCs for both independent and dependent samples. The macro is designed for balanced data only. Detailed explanation of the involved computations and macro variable definitions are provided in the text. Two biomedical examples are included to illustrate that the macro can be easily implemented.
NEGATIVE MAXWELL-STEFAN DIFFUSION-COEFFICIENTS
KRAAIJEVELD, G; WESSELINGH, JA
1993-01-01
The existence of negative Maxwell-Stefan diffusivities is investigated. For the case where the diffusion coefficients are taken to be composition dependent, it is found that the theory of irreversible thermodynamics does not require all diffusivities to be positive definite. This theoretical result
Pressure-viscosity coefficient of biobased lubricants
Film thickness is an important tribological property that is dependent on the combined effect of lubricant properties, material property of friction surfaces, and the operating conditions of the tribological process. Pressure-viscosity coefficient (PVC) is one of the lubricant properties that influe...
Regularity of the Interband Light Absorption Coefficient
M Krishna
2010-06-01
In this paper we consider the interband light absorption coefficient (ILAC), in a symmetric form, in the case of random operators on the -dimensional lattice. We show that the symmetrized version of ILAC is either continuous or has a component which has the same modulus of continuity as the density of states.
Problems on Divisibility of Binomial Coefficients
Osler, Thomas J.; Smoak, James
2004-01-01
Twelve unusual problems involving divisibility of the binomial coefficients are represented in this article. The problems are listed in "The Problems" section. All twelve problems have short solutions which are listed in "The Solutions" section. These problems could be assigned to students in any course in which the binomial theorem and Pascal's…
Integral coefficients for one-loop amplitudes
Britto, R.; Feng, B.
2008-01-01
We present a set of algebraic functions for evaluating the coefficients of the scalar integral basis of a general one-loop amplitude. The functions are derived from unitarity cuts, but the complete cut-integral procedure has been carried out in generality so that it never needs to be repeated. Where
Coupling coefficients for coupled-cavity lasers
Lang, R.J.; Yariv, A.
1987-03-01
The authors derive simple, analytic formulas for the field coupling coefficients in a two-section coupled-cavity laser using a local field rate equation treatment. They show that there is a correction to the heuristic formulas based on power flow calculated by Marcuse; the correction is in agreement with numerical calculations from a coupled-mode approach.
Effective stress coefficient for uniaxial strain condition
Alam, M.M.; Fabricius, I.L.
2012-01-01
The effective stress coefficient, introduced by Biot, is used for predicting effective stress or pore pressure in the subsurface. It is not a constant value. It is different for different types of sediment and it is stress dependent. We used a model, based on contact between the grains to describ...
Bayesian Meta-Analysis of Coefficient Alpha
Brannick, Michael T.; Zhang, Nanhua
2013-01-01
The current paper describes and illustrates a Bayesian approach to the meta-analysis of coefficient alpha. Alpha is the most commonly used estimate of the reliability or consistency (freedom from measurement error) for educational and psychological measures. The conventional approach to meta-analysis uses inverse variance weights to combine…
Determination of the convective heat transfer coefficient
Spierings, D.; Bosman, F.; Peters, T.; Plasschaert, F.
1987-01-01
The value of the convective heat transfer coefficient (htc) is determined under different loading conditions by using a computer aided method. The thermal load has been applied mathematically as well as experimentally to the coronal surface of an axisymmetric tooth model. To verify the assumptions m
Coefficient of Restitution of a Tennis Ball
Andre Roux
2007-06-01
Full Text Available The coefficient of restitution (COR of a tennis ball was investigated over a range of impact velocities. It was found that the COR of the ball was lower than ATP regulations specify, and that the COR decreased with increasing impact velocity.
Bitplane Image Coding With Parallel Coefficient Processing.
Auli-Llinas, Francesc; Enfedaque, Pablo; Moure, Juan C; Sanchez, Victor
2016-01-01
Image coding systems have been traditionally tailored for multiple instruction, multiple data (MIMD) computing. In general, they partition the (transformed) image in codeblocks that can be coded in the cores of MIMD-based processors. Each core executes a sequential flow of instructions to process the coefficients in the codeblock, independently and asynchronously from the others cores. Bitplane coding is a common strategy to code such data. Most of its mechanisms require sequential processing of the coefficients. The last years have seen the upraising of processing accelerators with enhanced computational performance and power efficiency whose architecture is mainly based on the single instruction, multiple data (SIMD) principle. SIMD computing refers to the execution of the same instruction to multiple data in a lockstep synchronous way. Unfortunately, current bitplane coding strategies cannot fully profit from such processors due to inherently sequential coding task. This paper presents bitplane image coding with parallel coefficient (BPC-PaCo) processing, a coding method that can process many coefficients within a codeblock in parallel and synchronously. To this end, the scanning order, the context formation, the probability model, and the arithmetic coder of the coding engine have been re-formulated. The experimental results suggest that the penalization in coding performance of BPC-PaCo with respect to the traditional strategies is almost negligible.
An alternative coefficient for sound absorption
Wijnant, Y.H.; Kuipers, E.R.; Boer, de A.; Sas, P.; Jonckheere, S.; Moens, D.
2013-01-01
The acoustic absorption coefficient is a number that indicates which fraction of the incident acoustic power impinging on a surface is being absorbed. The incident acoustic power is obtained by spatial integration of the incident intensity, which is (classically) defined as the time-averaged intensi
Bayesian Meta-Analysis of Coefficient Alpha
Brannick, Michael T.; Zhang, Nanhua
2013-01-01
The current paper describes and illustrates a Bayesian approach to the meta-analysis of coefficient alpha. Alpha is the most commonly used estimate of the reliability or consistency (freedom from measurement error) for educational and psychological measures. The conventional approach to meta-analysis uses inverse variance weights to combine…
LIOUVILLE'S THEOREM FOR LPDO WITH CONSTANT COEFFICIENTS
Han Yazhou; Luo Xuebo
2005-01-01
In this note, the authors consider a class of linear partial differential operators P(θ) with constant coefficients and prove that the operator P(θ) has Liouville property if and only if the polynomial P(iξ) doesn't have roots in Rn\\{O}.
Wind speed scaling and the drag coefficient
无
2005-01-01
Wind speed scaling in similarity law in wind-generated waves and the drag coefficient are studied. In analyzing the data in the wind wave channel, it is found that the u. scaling greatly reduces the scatter in the U10 scaling. The u. scaling has much less scatter than the scaling using other wind speeds. The friction velocity seems to play a distinctive role in wave growth. The result is important in the applications of the similarity law and in wave modeling. In theory it gives an insight into the mechanism of wind wave interaction. It is found that wave steepness is important in influencing the drag coefficient. The variability of the coefficients in the currently widely used drag form can be explained by the differences in wave steepness in the observations. A drag coefficient model with wind speed and wave steepness as parameters is proposed. An explanation for Kahma' s result that the u. scaling does not reduce the scatter in the U10 scaling is given.
Coefficient of variation of underwater irradiance fluctuations
Weber, V. L.
2010-06-01
We consider underwater sunlight fluctuations in the case of a one-dimensional irregular sea surface. Several rigorous and approximate models are proposed, which make it possible to analytically treat and physically explain the dependence of the coefficient of variation of the underwater irradiance on the depth, the wind velocity, and optical parameters of the sea water.
Fokker-Planck Type Equations with Sobolev Diffusion Coefficients and BV Drift Coefficients
De Jun LUO
2013-01-01
Combining Le Bris and Lions' arguments with Ambrosio's commutator estimate for BV vector fields,we prove in this paper the existence and uniqueness of solutions to the Fokker-Planck type equations with Sobolev diffusion coefficients and BV drift coefficients.
IS THE SAMPLE COEFFICIENT OF VARIATION A GOOD ESTIMATOR FOR THE POPULATION COEFFICIENT OF VARIATION?
Mahmoudvand, Rahim; HASSANI, Hossein; Wilson, Rob
2007-01-01
In this paper, we obtain bounds for the population coefficient of variation (CV) in Bernoulli, Discrete Uniform, Normal and Exponential distributions. We also show that the sample coefficient of variation (cv) is not an accurate estimator of the population CV in the above indicated distributions. Finally we provide some suggestions based on the Maximum Likelihood Estimation to improve the population CV estimate.
Dai, Guang-Ming
2006-02-15
The set of Fourier series is discussed following some discussion of Zernike polynomials. Fourier transforms of Zernike polynomials are derived that allow for relating Fourier series expansion coefficients to Zernike polynomial expansion coefficients. With iterative Fourier reconstruction, Zernike representations of wavefront aberrations can easily be obtained from wavefront derivative measurements.
Polymer-water partition coefficients in polymeric passive samplers.
Asgarpour Khansary, Milad; Shirazian, Saeed; Asadollahzadeh, Mehdi
2017-01-01
Passive samplers are of the most applied methods and tools for measuring concentration of hydrophobic organic compounds in water (c 1(W) ) in which the polymer-water partition coefficients (D) are of fundamental importance for reliability of measurements. Due to the cost and time associated with the experimental researches, development of a predictive method for estimation and evaluation of performance of polymeric passive samplers for various hydrophobic organic compounds is highly needed and valuable. For this purpose, in this work, following the fundamental chemical thermodynamic equations governing the concerned local equilibrium, successful attempts were made to establish a theoretical model of polymer-water partition coefficients. Flory-Huggins model based on the Hansen solubility parameters was used for calculation of activity coefficients. The method was examined for reliability of calculations using collected data of three polymeric passive samplers and ten compounds. A regression model of form ln(D) = 0.707ln(c 1(p) ) - 2.7391 with an R (2) = 0.9744 was obtained to relate the polymer-water partition coefficients (D) and concentration of hydrophobic organic compounds in passive sampler (c 1(p) ). It was also found that polymer-water partition coefficients are related to the concentration of hydrophobic organic compounds in water (c 1(W) ) as ln(D) = 2.412ln(c 1(p) ) - 9.348. Based on the results, the tie lines of concentration for hydrophobic organic compounds in passive sampler (c 1(p) ) and concentration of hydrophobic organic compounds in water (c 1(W) ) are in the form of ln(c 1(W) ) = 0.293ln(c 1(p) ) + 2.734. The composition of water sample and the interaction parameters of dissolved compound-water and dissolved compound-polymer, temperature, etc. actively influence the values of partition coefficient. The discrepancy observed over experimental data can be simply justified based on the local condition of sampling sites which alter
A. M. Aibinu
2010-01-01
Full Text Available A new approach for determining the coefficients of a complex-valued autoregressive (CAR and complex-valued autoregressive moving average (CARMA model coefficients using complex-valued neural network (CVNN technique is discussed in this paper. The CAR and complex-valued moving average (CMA coefficients which constitute a CARMA model are computed simultaneously from the adaptive weights and coefficients of the linear activation functions in a two-layered CVNN. The performance of the proposed technique has been evaluated using simulated complex-valued data (CVD with three different types of activation functions. The results show that the proposed method can accurately determine the model coefficients provided that the network is properly trained. Furthermore, application of the developed CVNN-based technique for MRI K-space reconstruction results in images with improve resolution.
Harmony Coefficient and Regional Agricultural Systems
YANG Shi-qi; GAO Wang-sheng
2006-01-01
The regional agricultural system (RAS) can be divided into three subsystems: ecological, economic, and social. This article examines the use of the harmony coefficient (HC), efficacy coefficient, rank of the harmony coefficient (RHC), and its appraising index system within the RAS. The harmony coefficient function was developed using a variance coefficient and then applied to Ziyang District, Yiyang City in Hunan Province (ZYH), China, as a test case. From 1995 to 2002, the HC of RAS increased from 0.2982 to 0.4826 and the RHC increased from 3 to 5, although the HC trend was an "n" type in general. This suggests that the HC was weakly maladjusted and the RAS was not harmonious. The HC of the ecological subsystem decreased from 0.3898 to 0.2850, and its RHC from 4 to 3, with the HC trend following the "n" type. For the economic subsystem, the HC value increased from 0.5767 to 0.7458 and the RHC from 6 to 8. However, the trend in HC for the economic subsystem was of the "U" type. The HC of the social subsystem increased slightly from 0.4948 to 0.4663,and the RHC did not change in value. From the HC trends, the HC curve of the economic subsystem is above the HC curve of ZYH and the HC curve of the ecological subsystem is below the HC curve of ZHY. Hence, the ZHY environment has been destroyed by economic development. Environment and social building should be regarded as important issues in the future and promoting RAS harmony development should be considered. The results of the theoretical analysis match fairly closely with reality, and suggest that the harmony theory is feasible in appraising RAS development phases.
Zhu, Xiangyu; Nordstrom, D. Kirk; McCleskey, R. Blaine; Wang, Rucheng
2016-01-01
Arsenic is known to be one of the most toxic inorganic elements, causing worldwide environmental contamination. However, many fundamental properties related to aqueous arsenic species are not well known which will inhibit our ability to understand the geochemical behavior of arsenic (e.g. speciation, transport, and solubility). Here, the electrical conductivity of Na2HAsO4 solutions has been measured over the concentration range of 0.001–1 mol kg−1 and the temperature range of 5–90°C. Ionic strength and temperature-dependent equations were derived for the molal conductivity of HAsO42−and H2AsO4− aqueous ions. Combined with speciation calculations and the approach used by McCleskey et al. (2012b), these equations can be used to calculate the electrical conductivities of arsenic-rich waters having a large range of effective ionic strengths (0.001–3 mol kg−1) and temperatures (5–90°C). Individual ion activity coefficients for HAsO42− and H2AsO4− in the form of the Hückel equation were also derived using the mean salt method and the mean activity coefficients of K2HAsO4 (0.001–1 mol kg−1) and KH2AsO4 (0.001–1.3 mol kg−1). A check on these activity coefficients was made by calculating mean activity coefficients for Na2HAsO4 and NaH2AsO4 solutions and comparing them to measured values. At the same time Na-arsenate complexes were evaluated. The NaH2AsO40 ion pair is negligible in NaH2AsO4 solutions up to 1.3 mol kg−1. The NaHAsO4− ion pair is important in NaHAsO4 solutions >0.1 mol kg−1 and the formation constant of 100.69 was confirmed. The enthalpy, entropy, free energy and heat capacity for the second and third arsenic acid dissociation reactions were calculated from pH measurements. These properties have been incorporated into a widely used geochemical calculation code WATEQ4F and applied to natural arsenic waters. For arsenic spiked water samples from Yellowstone National Park, the mean difference between the
张军
2000-01-01
用锂离子选择电极和经典Ag-AgCl电极测定了298.15K下LiCl-Li2B4O7-H2O体系中离子强度范围为0.01～2.50mol.kg-1，不同Li2B4O7离子强度分数的LiCl的平均活度系数。由实验数据，用迭代法及多元线性回归法，求取了Li2B4O7的化学计量离解平衡常数Km，热力学离解平衡常数K及Pitzer离子作用参数，并与实验值比较标准偏差为0.0500。同时该实验结果在0.01-0.50mol.kg-1离子强度范围内与298.15K下LiCl-Li2SO4-H2O体系LiCl平均活度系数的变化趋势进行了比较，得到LiCl在Li2B4O7介质中平均活度系数随Yb的增大而增大，而在Li2SO4介质中则减小。%Mean activity coefficients of LiCl for LiCI-Li2B4O7-H2O system have been deteminated in the ionic strength range from 0.01 to 2.50mol.kg-1 at 298.15K by the method of EMF using a pair of lithium ion-selective electrode and Ag/AgCl electrode. Stoichiometric equilibrium constant(Km), Thermodynamic constant(K) and Pitzer ion interaction parameters were evaluated from present measurement using multiple regression and iterative method. The experimental activity coefficients were compared with those calculated by Pitzer equations from this work and references, presenting reasonable agreement. The activity coefficients of LiCl in the medium of aq. Li2B4O7 were compared with those in aq. Li2SO4. The results show that the activity coefficients of LiCl increase with increasing of Li2B4O7 in the medium of aq. Li2B4O7 and decrease with increasing of Li2SO4 in the medium of aq. Li2SO4 in the ionic strength rang from 0.01 to 0.50mol.kg-1.
SENSITIVITY COEFFICIENTS OF SINGLE-PHASE FLOW IN LOW-PERMEABILITY HETEROGENEOUS RESERVOIRS
程时清; 张盛宗; 黄延章; 朱维耀
2002-01-01
Theoretical equations for computing sensitivity coefficients of wellbore pressures to estimate the reservoir parameters in low-permeability reservoirs conditioning to non-Darcy flow data at low velocity were obtained. It is shown by a lot of numerical calculations that the wellbore pressures are much more sensitive to permeability very near the well than to permeability a few gridblocks away from the well. When an initial pressure gradient existent sensitivity coefficients in the region are closer to the active well than to the observation well.Sensitivity coefficients of observation well at the line between the active well and the observation well are influenced greatly by the initial pressure gradient.
Wheeler, David C.; Calder, Catherine A.
2007-06-01
The realization in the statistical and geographical sciences that a relationship between an explanatory variable and a response variable in a linear regression model is not always constant across a study area has led to the development of regression models that allow for spatially varying coefficients. Two competing models of this type are geographically weighted regression (GWR) and Bayesian regression models with spatially varying coefficient processes (SVCP). In the application of these spatially varying coefficient models, marginal inference on the regression coefficient spatial processes is typically of primary interest. In light of this fact, there is a need to assess the validity of such marginal inferences, since these inferences may be misleading in the presence of explanatory variable collinearity. In this paper, we present the results of a simulation study designed to evaluate the sensitivity of the spatially varying coefficients in the competing models to various levels of collinearity. The simulation study results show that the Bayesian regression model produces more accurate inferences on the regression coefficients than does GWR. In addition, the Bayesian regression model is overall fairly robust in terms of marginal coefficient inference to moderate levels of collinearity, and degrades less substantially than GWR with strong collinearity.
Guttmann, Anthony J.
2016-10-01
Given the first 20-100 coefficients of a typical generating function of the type that arises in many problems of statistical mechanics or enumerative combinatorics, we show that the method of differential approximants performs surprisingly well in predicting (approximately) subsequent coefficients. These can then be used by the ratio method to obtain improved estimates of critical parameters. In favourable cases, given only the first 20 coefficients, the next 100 coefficients are predicted with useful accuracy. More surprisingly, this is also the case when the method of differential approximants does not do a useful job in estimating the critical parameters, such as those cases in which one has stretched exponential asymptotic behaviour. Nevertheless, the coefficients are predicted with surprising accuracy. As one consequence, significant computer time can be saved in enumeration problems where several runs would normally be made, modulo different primes, and the coefficients constructed from their values modulo different primes. Another is in the checking of newly calculated coefficients. We believe that this concept of approximate series extension opens up a whole new chapter in the method of series analysis.
Zhenrong JING
2017-06-01
Full Text Available Swept wing is widely used in civil aircraft, whose airfoil is chosen, designed and optimized to increase the cruise speed and decrease the drag coefficient. The parameters of swept wing, such as sweep angle and angle of attack, are determined according to the cruise lift coefficient requirement, and the drag coefficient is expected to be predicted accurately, which involves the instability characteristics and transition position of the flow. The pressure coefficient of the RAE2822 wing with given constant lift coefficient is obtained by solving the three-dimensional Navier-Stokes equation numerically, and then the mean flow is calculated by solving the boundary layer (BL equation with spectral method. The cross-flow instability characteristic of boundary layer of swept wing in the windward and leeward is analyzed by linear stability theory (LST, and the transition position is predicted by eN method. The drag coefficient is numerically predicted by introducing a laminar/turbulent indicator. A simple approach to calculate the lift coefficient of swept wing is proposed. It is found that there is a quantitative relationship between the angle of attack and sweep angle when the lift coefficient keeps constant; when the angle of attack is small, the flow on the leeward of the wing is stable. when the angle of attack is larger than 3°, the flow becomes unstable quickly; with the increase of sweep angle or angle of attack the disturbance on the windward becomes more unstable, leading to the moving forward of the transition position to the leading edge of the wing; the drag coefficient has two significant jumping growth due to the successive occurrence of transition in the windward and the leeward; the optimal range of sweep angle for civil aircraft is suggested.
Deriving Second Osmotic Virial Coefficients from Equations of State and from Experiment.
Koga, K; Holten, Vincent; Widom, B
2015-10-22
The osmotic virial coefficients, which are measures of the effective interactions between solute molecules in dilute solution, may be obtained from expansions of the osmotic pressure or of the solute activity in powers of the solute concentration. In these expansions, the temperature is held fixed, and one additional constraint is imposed. When the additional constraint is that of fixed chemical potential of the solvent, the coefficient of the second-order term yields directly the second osmotic virial coefficient itself. Alternative constraints, such as fixed pressure, fixed solvent density, or the specification of liquid-vapor equilibrium, yield alternative measures of the solute-solute interaction, different from but related to the osmotic virial coefficient. These relations are summarized and, where new, are derived here. The coefficient in question may be calculated from equations of state in which the parameters have been obtained by fitting to other experimental properties. Alternatively, the coefficients may be calculated from direct experimental measurements of the deviations from Henry's law based on measurements of the activity of the solute in a coexisting gas phase. It is seen for propane in water as a test case that with the latter method, even with what appear to be the best available experimental data, there are still large uncertainties in the resulting second osmotic virial coefficient. With the former method, by contrast, the coefficient may be obtained with high numerical precision but then depends for its accuracy on the quality of the equation of state from which it is derived.
Specific Rate Coefficients from Vibrational Overtone Activation of 1-Methylcyclopropene.
1994-12-01
opens forming a biradical (5) which then undergoes one of three possible hydrogen shift reactions to form product. Formation of these products via...mol), 1,2-butadiene being the least stable (-19.4 kcal/mol) and 2-butyne lying intermediate (- 23.5 kcal/mol). Another possible biradical intermediate
Transport Coefficients and nPI Methods
Carrington, M E
2011-01-01
Transport coefficients can be obtained from 2-point correlators using the Kubo formulae. It has been shown that the full leading order result for electrical conductivity and (QCD) shear viscosity is contained in the re-summed 2-point function that is obtained from the 3-loop 3PI effective action. The theory produces all leading order contributions without the necessity for power counting, and in this sense it provides a natural framework for the calculation and suggests that one can calculate the next-to-leading contribution to transport coefficients from the 4-loop 4PI effective action. The integral equations have been derived for shear viscosity for a scalar theory with cubic and quartic interactions, with a non-vanishing field expectation value. We review these results, and explain how the calculation could be done at higher orders.
Window shrink contourlet coefficients for image denoising
JIN Wei; PAN Ying-jun; WEI Biao; FENG Peng
2005-01-01
An adaptive image denosing technique was proposed to achieve the tradeoff between details retain and noises removal. In order to achieve this objective, the contourlet transform was introduced and a new threshold method, namely CWinShrink, is presented. It shrinks the contourlet coefficients with adaptive shrinkage factors. The shrinkage factors were calculated with reference to the sum of squares of the contourlet coefficients within the neighborhood window. This approach achieves enhanced results for images those are corrupted with additive Gaussian noise. In numerical comparisons with various methods, for a set of noisy images ( the PSNR range from 10.86dB to 26.91dB) , the presented method outperforms VisuShrink and Wiener filter in terms of the PSNR. Experiments also show that this method not only keeps the details of image but also yields denoised images with better visual quality.
Homomorphic Hashing for Sparse Coefficient Extraction
Kaski, Petteri; Nederlof, Jesper
2012-01-01
We study classes of Dynamic Programming (DP) algorithms which, due to their algebraic definitions, are closely related to coefficient extraction methods. DP algorithms can easily be modified to exploit sparseness in the DP table through memorization. Coefficient extraction techniques on the other hand are both space-efficient and parallelisable, but no tools have been available to exploit sparseness. We investigate the systematic use of homomorphic hash functions to combine the best of these methods and obtain improved space-efficient algorithms for problems including LINEAR SAT, SET PARTITION, and SUBSET SUM. Our algorithms run in time proportional to the number of nonzero entries of the last segment of the DP table, which presents a strict improvement over sparse DP. The last property also gives an improved algorithm for CNF SAT with sparse projections.
Varying-coefficient functional linear regression
Wu, Yichao; Müller, Hans-Georg; 10.3150/09-BEJ231
2011-01-01
Functional linear regression analysis aims to model regression relations which include a functional predictor. The analog of the regression parameter vector or matrix in conventional multivariate or multiple-response linear regression models is a regression parameter function in one or two arguments. If, in addition, one has scalar predictors, as is often the case in applications to longitudinal studies, the question arises how to incorporate these into a functional regression model. We study a varying-coefficient approach where the scalar covariates are modeled as additional arguments of the regression parameter function. This extension of the functional linear regression model is analogous to the extension of conventional linear regression models to varying-coefficient models and shares its advantages, such as increased flexibility; however, the details of this extension are more challenging in the functional case. Our methodology combines smoothing methods with regularization by truncation at a finite numb...
Meromorphic univalent function with negative coefficient
A. Dernek
1994-01-01
Full Text Available Let Mn be the classes of regular functions f(z=z−1+a0+a1z+… defined in the annulus 00, (n∈ℕ0, where I0f(z=f(z, If(z=(z−1−z(z−1−2∗f(z, Inf(z=I(In−1f(z, and ∗ is the Hadamard convolution. We denote by Γn=Mn⋃Γ, where Γ denotes the class of functions of the form f(z=z−1+∑k=1∞|ak|zk. We obtained that relates the modulus of the coefficients to starlikeness for the classes Mn and Γn, and coefficient inequalities for the classes Γn.
Transport coefficients in Chiral Perturbation Theory
Fernandez-Fraile, D.; Gomez Nicola, A. [Universidad Complutense, Departamentos de Fisica Teorica I y II, Madrid (Spain)
2007-03-15
We present recent results on the calculation of transport coefficients for a pion gas at zero chemical potential in Chiral Perturbation Theory (ChPT) using the Linear Response Theory (LRT). More precisely, we show the behavior of DC conductivity and shear viscosity at low temperatures. To compute transport coefficients, the standard power counting of ChPT has to be modified. The effects derived from imposing unitarity are also analyzed. As physical applications in relativistic heavy-ion collisions, we show the relation of the DC conductivity to soft-photon production and phenomenological effects related to a non-zero shear viscosity. In addition, our values for the shear viscosity to entropy ratio satisfy the KSS bound. (orig.)
Is coefficient alpha robust to nonnormal data?
Yanyan eSheng
2012-02-01
Full Text Available Coefficient alpha has been a widely used measure by which internal consistency reliability is assessed. In addition to essential tau-equivalence and uncorrelated errors, normality has been noted as another important assumption for alpha. Earlier work on evaluating this assumption considered either exclusively nonnormal error score distributions, or limited conditions. In view of this and the availability of advanced methods for generating univariate nonnormal data, Monte Carlo simulations were conducted to show that nonnormal distributions for true or error scores do create problems for using alpha to estimate the internal consistency reliability. The sample coefficient alpha is affected by leptokurtic true score distributions, or skewed and/or kurtotic error score distributions. Increased sample sizes, not test lengths, help improve the accuracy, bias or precision of using it with nonnormal data.
Shear Viscosity Coefficient from Microscopic Models
Muronga, A
2004-01-01
The transport coefficient of shear viscosity is studied for a hadron matter through microscopic transport model, the Ultra--relativistic Quantum Molecular Dynamics (UrQMD), using the Green--Kubo formulas. Molecular--dynamical simulations are performed for a system of light mesons in a box with periodic boundary conditions. Starting from an initial state composed of $\\pi, \\eta ,\\omega ,\\rho ,\\phi$ with a uniform phase--space distribution, the evolution takes place through elastic collisions, production and annihilation. The system approaches a stationary state of mesons and their resonances, which is characterized by common temperature. After equilibration, thermodynamic quantities such as the energy density, particle density, and pressure are calculated. From such an equilibrated state the shear viscosity coefficient is calculated from the fluctuations of stress tensor around equilibrium using Green--Kubo relations. We do our simulations here at zero net baryon density so that the equilibration times depend o...
Hadronic Transport Coefficients from Effective Field Theories
Torres-Rincon, Juan M
2012-01-01
This dissertation focuses on the calculation of transport coefficients in the matter created in a relativistic heavy-ion collision after the chemical freeze-out. This matter can be well approximated by a pion gas out of equilibrium. We describe the theoretical framework to obtain the shear and bulk viscosities, the thermal and electrical conductivities and the flavor diffusion coefficients of a meson gas at low temperatures. To describe the interactions of the degrees of freedom, we use effective field theories with chiral and heavy quark symmetries. We introduce the unitarization methods in order to obtain a scattering amplitude that satisfies the unitarity condition exactly. We perform the calculation of the transport properties of the low temperature phase of quantum chromodynamics -the hadronic medium- that can be used in the hydrodynamic simulations of a relativistic heavy-ion collision and its subsequent evolution. We show that the shear viscosity over entropy density exhibits a minimum in a phase trans...
ON DAMPING COEFFICIENT DUE TO PHASE TRANSFORMATION
Din-YuHSIEH
2003-01-01
The damping coefficient of capillary waves due to the evaporation-condensation process at the interface of the two phases of a fluid is evaluated. To highlight the mechanism of the effect of heat and mass transfer across the interface between regions of liquid and vapor, potential flow of incompressible fluids are assumed. Thus other mechanisms of damping are neglected. To fascilitate the analysis, the method of multiple-scale is employed in the analysis, even though the problem is linear.
Basketball Surfaces and Coefficient of Restitution
Kristyn Peacock; Faith Pearson
2015-01-01
A basketball was released from varying drop heights to simulate the impact speeds of a typical soft, medium, and hard dribble. This was repeated across four different surfaces that students typically play on–exposed aggregate concrete, maple wood flooring, EPI Outdoor Sport flooring, and playground rubber mesh. From the measured drop and bounce heights, the coefficient of restitution(COR)was calculated. It was concluded that only playground rubber mesh had COR’s below the regula...
Numerical Integral of Resistance Coefficients in Diffusion
Zhang, Q. S.
2017-01-01
The resistance coefficients in the screened Coulomb potential of stellar plasma are evaluated to high accuracy. I have analyzed the possible singularities in the integral of scattering angle. There are possible singularities in the case of an attractive potential. This may result in a problem for the numerical integral. In order to avoid the problem, I have used a proper scheme, e.g., splitting into many subintervals where the width of each subinterval is determined by the variation of the integrand, to calculate the scattering angle. The collision integrals are calculated by using Romberg’s method, therefore the accuracy is high (i.e., ∼10‑12). The results of collision integrals and their derivatives for ‑7 ≤ ψ ≤ 5 are listed. By using Hermite polynomial interpolation from those data, the collision integrals can be obtained with an accuracy of 10‑10. For very weakly coupled plasma (ψ ≥ 4.5), analytical fittings for collision integrals are available with an accuracy of 10‑11. I have compared the final results of resistance coefficients with other works and found that, for a repulsive potential, the results are basically the same as others’ for an attractive potential, the results in cases of intermediate and strong coupling show significant differences. The resulting resistance coefficients are tested in the solar model. Comparing with the widely used models of Cox et al. and Thoul et al., the resistance coefficients in the screened Coulomb potential lead to a slightly weaker effect in the solar model, which is contrary to the expectation of attempts to solve the solar abundance problem.
Heterodiffusion coefficients in alpha-iron
Katsika-Tsigourakou, Vassiliki, E-mail: vkatsik@phys.uoa.g [Department of Solid State Physics, Faculty of Physics, University of Athens, Panepistimiopolis Zografos, 15784 Athens (Greece); Skordas, Efthimios S. [Department of Solid State Physics, Faculty of Physics, University of Athens, Panepistimiopolis Zografos, 15784 Athens (Greece)
2010-04-01
The diffusion of tungsten in alpha-iron is important for the application of ferritic-iron alloys to thermal power plants. These data, over a wide temperature range across the Curie temperature, have been recently reported. We show that these diffusion coefficients can be satisfactory reproduced in terms of the bulk elastic and expansivity data by means of a thermodynamical model that interconnects point defects parameters with bulk qualities.
Correlation and prediction of gaseous diffusion coefficients.
Marrero, T. R.; Mason, E. A.
1973-01-01
A new correlation method for binary gaseous diffusion coefficients from very low temperatures to 10,000 K is proposed based on an extended principle of corresponding states, and having greater range and accuracy than previous correlations. There are two correlation parameters that are related to other physical quantities and that are predictable in the absence of diffusion measurements. Quantum effects and composition dependence are included, but high-pressure effects are not. The results are directly applicable to multicomponent mixtures.
Negative Temperature Coefficient in Chemical Reactions
Leenson, I. A.; Sergeev, Gleb B.
1984-05-01
A systematic analysis of reactions whose rate decreases with increase of temperature is presented. The possibility of a negative temperature coefficient in the elementary reactions is examined from the standpoint of the transition state theory and of collision theory. The mechanisms of complex reactions in which the temperature dependence of the rate is anomalous are discussed, and possible reasons for the anomaly are examined. The bibliography contains 175 references.
Coefficient inequalities for starlikeness and convexity
Ali Rosihan M.
2013-06-01
Full Text Available For an analytic function $f(z=z+\\sum_{n=2}^\\infty a_n z^n$ satisfying the inequality $\\sum_{n=2}^\\infty n(n-1|a_n|\\leq \\beta$, sharp bound on $\\beta$ is determined so that $f$ is either starlike or convex of order $\\alpha$. Several other coefficient inequalities related to certain subclasses are also investigated.
Coefficients of symmetric square L-functions
LAU; Yuk-Kam
2010-01-01
Let λsym2f(n) be the n-th coefficient in the Dirichlet series of the symmetric square L-function associated with a holomorphic primitive cusp form f.We prove Ω± results for λsym2f(n) and evaluate the number of positive(resp.,negative) λsym2f(n) in some intervals.
Detailed Investigations of Load Coefficients on Grates
Andersen, Thomas Lykke; Rasmussen, Michael R.; Frigaard, Peter
In this report is presented the results of model tests carried out at Dept. of Civil Engineering, aalborg University (AAU) on behalf of DONG Energy A/S and Vattenfall A/S, Denmark. The objective of the tests was to investigate the load coefficient on different grates and a solid plate for designi...... offshore windmill access platforms against run-up generated forces with special attention to the influence of air entrainment and the angle of attack....
ACCUMULATION COEFFICIENT OF PB IN SOILS FROM ZLATNA AREA
Alexandrina Manea
2010-01-01
Full Text Available Activity of Zlatna floating and smelting factory causes the soil loading with heavy metals, especially with Pb and Cu. Inthe area of Zlatna smelting influence, the assessment of soil loading degree with Pb was made using accumulationcoefficient. The content of total Pb was studied on 30 soil profiles. The most of the sites are located on the direction ofprevailing winds. The soil samples were taken from each soil horizons. The total Pb content was measured with atomicabsorption spectrometer and was extracted by a mixture of strong acids (hydrochloric, sulphuric and perchloric acid -5:10:1 ratio. This coefficient ranges from 1.25 to 49.4. Average values of this coefficient in studied area were 9.7.Median concentration was 7.1 and percentiles of 75% and 90% were 11.9 and respectively 19.8. General trend of Pbaccumulation coefficient decreased with distance from processing plant. Pb accumulation was strong influenced by typeof land uses and type of soils.
Study on resistance coefficient in compound channels
Kejun Yang; Shuyou Cao; Xingnian Liu; Ron Marshall
2005-01-01
This paper presents a further study of the Manning and Darcy-Weisbach resistance coefficients, as they play a significant role in assessing the cross-sectional mean velocity, conveyance capacity and determining the lateral distribution of depth mean velocity and local boundary shear stress in compound channels. The relationships between the local, zonal and overall resistance coefficients, and a wide range of geometries and different roughness between the main channel and the flood plain are established by analyzing a vast amount of experimental data from a British Science and Engineering Research Council Flood Channel Facility (SERC-FCF). And the experimental results also show that the overall Darcy-Weisbach resistance coefficient for a compound channel is the function of Reynolds number, but the function relationship is different from that for a single channel. By comparing and analyzing the conventional methods with the experimental data to predict composite roughness in compound channels, it is found that these methods are not suitable for compound channels. Moreover, the reason why the conventional methods cannot assess correctly the conveyance capacity of com pound channels is also analyzed in this paper.
Control in the coefficients with variational crimes
Evgrafov, Anton; Marhadi, Kun Saptohartyadi
2012-01-01
We study convergence of discontinuous Galerkin-type discretizations of the problems of control in the coefficients of uniformly elliptic partial differential equations (PDEs). As a model problem we use that of the optimal design of thin (Kirchhoff) plates, where the governing equations are of the......We study convergence of discontinuous Galerkin-type discretizations of the problems of control in the coefficients of uniformly elliptic partial differential equations (PDEs). As a model problem we use that of the optimal design of thin (Kirchhoff) plates, where the governing equations...... are of the fourth order. Methods which do not require approximation subspaces to conform to the smoothness requirements dictated by the PDE are very attractive for such problems. However, variational formulations of such methods normally contain boundary integrals whose dependence on the small, with respect...... to “volumetric” Lebesgue norm, changes of the coefficients is generally speaking not continuous. We utilize the lifting formulation of the discontinuous Galerkin method to deal with this issue.Our main result is that limit points of sequences of designs verifying discrete versions of stationarity can also...
Michelson interferometer for the piezoelectric coefficient measurements
Muensit, S.
2002-01-01
Full Text Available The present work has described the Michelson interferometer which is capable of measuring the vibrational amplitudes in a sub-angstrom range. In the system, a He-Ne laser is used as a monochromatic source of light and a photodiode as a detector to convert an optical signal into an electronic one. Lock-in detections of the electronic signals are applied to relate the vibrational amplitudes to the wavelength of the laser beam. A feedback circuit is introduced in order to stabilize the sensitivity of the interferometric system. With this setup, a mechanical displacement referred to a change in thickness of a vibrating sample can be measured and the corresponding piezoelectric coefficient, i.e. the ratio of the change in sample thickness to the applied voltage, evaluated. In order to check the performance of the system, measurements on lithium niobate (LiNbO3 have been made and its piezoelectric coefficient d33 was confirmed with 2% accuracy. The piezoelectric coefficient d33 for lead zirconate titanate (PZT ceramics was, therefore, determined by this interferometer and found to be 270 pm/V.
MULTIVARIATE VARYING COEFFICIENT MODEL FOR FUNCTIONAL RESPONSES.
Zhu, Hongtu; Li, Runze; Kong, Linglong
2012-10-01
Motivated by recent work studying massive imaging data in the neuroimaging literature, we propose multivariate varying coefficient models (MVCM) for modeling the relation between multiple functional responses and a set of covariates. We develop several statistical inference procedures for MVCM and systematically study their theoretical properties. We first establish the weak convergence of the local linear estimate of coefficient functions, as well as its asymptotic bias and variance, and then we derive asymptotic bias and mean integrated squared error of smoothed individual functions and their uniform convergence rate. We establish the uniform convergence rate of the estimated covariance function of the individual functions and its associated eigenvalue and eigenfunctions. We propose a global test for linear hypotheses of varying coefficient functions, and derive its asymptotic distribution under the null hypothesis. We also propose a simultaneous confidence band for each individual effect curve. We conduct Monte Carlo simulation to examine the finite-sample performance of the proposed procedures. We apply MVCM to investigate the development of white matter diffusivities along the genu tract of the corpus callosum in a clinical study of neurodevelopment.
Khayrullin, M.K.
1981-01-01
Formulas for calculating the influential coefficients according to pressure based on finite differences. Based on these formulas, it is shown that if the finite-difference approcimation coefficient of hydrodynamic conductibility sigmaeta satisfies the condition ..lambda..omicron..sqrt..sigmaeta-omicron..sqrt..sigmaeta= O, where ..lambda..omicron is the differential analog of the operato Laplas, then the influential coefficient is alpha st=lambdast..mu..st, where lambdast depends on the physical parameters of the layer and the liquid, and ..mu..st defines the geometry of the field and distribution of the wells. This hypothesis is also used as a method of finding a partial solution for calculating the hydrodynamic conductibility coefficient for area wells regarding finite-difference functions satisfying the condition..lambda..omicron..sqrt..sigmaeta = O.
Hagelaar, G J M; Pitchford, L C [Centre de Physique des Plasmas et de leurs Applications de Toulouse, Universite Paul Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France)
2005-11-15
Fluid models of gas discharges require the input of transport coefficients and rate coefficients that depend on the electron energy distribution function. Such coefficients are usually calculated from collision cross-section data by solving the electron Boltzmann equation (BE). In this paper we present a new user-friendly BE solver developed especially for this purpose, freely available under the name BOLSIG+, which is more general and easier to use than most other BE solvers available. The solver provides steady-state solutions of the BE for electrons in a uniform electric field, using the classical two-term expansion, and is able to account for different growth models, quasi-stationary and oscillating fields, electron-neutral collisions and electron-electron collisions. We show that for the approximations we use, the BE takes the form of a convection-diffusion continuity-equation with a non-local source term in energy space. To solve this equation we use an exponential scheme commonly used for convection-diffusion problems. The calculated electron transport coefficients and rate coefficients are defined so as to ensure maximum consistency with the fluid equations. We discuss how these coefficients are best used in fluid models and illustrate the influence of some essential parameters and approximations.
Conditional Reliability Coefficients for Test Scores.
Nicewander, W Alan
2017-04-06
The most widely used, general index of measurement precision for psychological and educational test scores is the reliability coefficient-a ratio of true variance for a test score to the true-plus-error variance of the score. In item response theory (IRT) models for test scores, the information function is the central, conditional index of measurement precision. In this inquiry, conditional reliability coefficients for a variety of score types are derived as simple transformations of information functions. It is shown, for example, that the conditional reliability coefficient for an ordinary, number-correct score, X, is equal to, ρ(X,X'|θ)=I(X,θ)/[I(X,θ)+1] Where: θ is a latent variable measured by an observed test score, X; p(X, X'|θ) is the conditional reliability of X at a fixed value of θ; and I(X, θ) is the score information function. This is a surprisingly simple relationship between the 2, basic indices of measurement precision from IRT and classical test theory (CTT). This relationship holds for item scores as well as test scores based on sums of item scores-and it holds for dichotomous as well as polytomous items, or a mix of both item types. Also, conditional reliabilities are derived for computerized adaptive test scores, and for θ-estimates used as alternatives to number correct scores. These conditional reliabilities are all related to information in a manner similar-or-identical to the 1 given above for the number-correct (NC) score. (PsycINFO Database Record (c) 2017 APA, all rights reserved).
Peltier coefficient measurement in a thermoelectric module
Garrido, Javier; Casanovas, Alejandro; María Chimeno, José
2013-09-01
A new method for measuring the Peltier coefficient in a thermocouple X/Y based on the energy balance at the junction has been proposed recently. This technique needs only the hot and cold temperatures of a thermoelectric module when an electric current flows through it as the operational variables. The temperature evolutions of the two module sides provide an evident and accurate idea of the Peltier effect. From these temperatures, the heat transfer between the module and the ambient is also evaluated. The thermoelectric phenomena are described in the framework of an observable theory. Based on this procedure, an experiment is presented for a university teaching laboratory at the undergraduate level.
Onsager coefficients for systems with periodic potentials
Rosas, Alexandre; Van den Broeck, Christian; Lindenberg, Katja
2016-11-01
We carry out the thermodynamic analysis of a Markovian stochastic engine, driven by a spatially and temporally periodic modulation in a d -dimensional space. We derive the analytic expressions for the Onsager coefficients characterizing the linear response regime for the isothermal transfer of one type of work (a driver) to another (a load), mediated by a stochastic time-periodic machine. As an illustration, we obtain the explicit results for a Markovian kangaroo process coupling two orthogonal directions and find extremely good agreement with numerical simulations. In addition, we obtain and discuss expressions for the entropy production, power, and efficiency for the kangaroo process.
Tracking Time-Varying Coefficient-Functions
Nielsen, Henrik Aalborg; Nielsen, Torben Skov; Joensen, Alfred K.;
1999-01-01
of recursive least squares with exponential forgetting and local polynomial regression. However, it is argued, that it is appropriate to let the forgetting factor vary with the value of the external signal shich is argument of the coeffieient-functions.The properties of the modified method are sutdied......A conditional parametric ARX-model is an ARX-model in which the parameters re replaced by smooth functions of an, possibly multivariate, externalinput signal. These functions are called coefficient functions is suggested. Essentially, in its most simple form, this method is a combination...
Gauge Invariance of Thermal Transport Coefficients
Ercole, Loris; Marcolongo, Aris; Umari, Paolo; Baroni, Stefano
2016-10-01
Thermal transport coefficients are independent of the specific microscopic expression for the energy density and current from which they can be derived through the Green-Kubo formula. We discuss this independence in terms of a kind of gauge invariance resulting from energy conservation and extensivity, and demonstrate it numerically for a Lennard-Jones fluid, where different forms of the microscopic energy density lead to different time correlation functions for the heat flux, all of them, however, resulting in the same value for the thermal conductivity.
Random Matrices and Lyapunov Coefficients Regularity
Gallavotti, Giovanni
2017-02-01
Analyticity and other properties of the largest or smallest Lyapunov exponent of a product of real matrices with a "cone property" are studied as functions of the matrices entries, as long as they vary without destroying the cone property. The result is applied to stability directions, Lyapunov coefficients and Lyapunov exponents of a class of products of random matrices and to dynamical systems. The results are not new and the method is the main point of this work: it is is based on the classical theory of the Mayer series in Statistical Mechanics of rarefied gases.
Transmission eigenvalues for operators with constant coefficients
Hitrik, Michael; Ola, Petri; Päivärinta, Lassi
2010-01-01
In this paper we study the interior transmission problem and transmission eigenvalues for multiplicative perturbations of linear partial differential operator of order $\\ge 2$ with constant real coefficients. Under suitable growth conditions on the symbol of the operator and the perturbation, we show the discreteness of the set of transmission eigenvalues and derive sufficient conditions on the existence of transmission eigenvalues. We apply these techniques to the case of the biharmonic operator and the Dirac system. In the hypoelliptic case we present a connection to scattering theory.
Flash ADC data processing with correlation coefficients
Blyth, D.; Gibson, M.; Mcfarland, D.; Comfort, J.R., E-mail: Joseph.Comfort@asu.edu
2014-02-21
The large growth of flash ADC techniques for processing signals, especially in applications of streaming data, raises issues such as data flow through an acquisition system, long-term storage, and greater complexity in data analysis. In addition, experiments that push the limits of sensitivity need to distinguish legitimate signals from noise. The use of correlation coefficients is examined to address these issues. They are found to be quite successful well into the noise region. The methods can also be extended to Field Programmable Gate Array modules for compressing the data flow and greatly enhancing the event rate capabilities.
Basketball Surfaces and Coefficient of Restitution
Kristyn Peacock
2015-01-01
Full Text Available A basketball was released from varying drop heights to simulate the impact speeds of a typical soft, medium, and hard dribble. This was repeated across four different surfaces that students typically play on–exposed aggregate concrete, maple wood flooring, EPI Outdoor Sport flooring, and playground rubber mesh. From the measured drop and bounce heights, the coefficient of restitution(CORwas calculated. It was concluded that only playground rubber mesh had COR’s below the regulation range, with the other three surfaces having COR’s within regulation.
Campbell, J.R.; Luthy, R.G.
1984-06-01
Experimental and modeling activities were performed to assess techniques for measurement and prediction of distribution coefficients for aromatic solutes between water and immiscible organic solvents. Experiments were performed to measure distribution coefficients in both clean water and wastewater systems, and to assess treatment of a wastewater by solvent extraction. The theoretical portions of this investigation were directed towards development of techniques for prediction of solute-solvent/water distribution coefficients. Experiments were performed to assess treatment of a phenolic-laden coal conversion wastewater by solvent extraction. The results showed that solvent extraction for recovery of phenolic material offered several wastewater processing advantages. Distribution coefficients were measured in clean water and wastewater systems for aromatic solutes of varying functionality with different solvent types. It was found that distribution coefficients for these compounds in clean water systems were not statistically different from distribution coefficients determined in a complex coal conversion process wastewater. These and other aromatic solute distribution coefficient data were employed for evaluation of modeling techniques for prediction of solute-solvent/water distribution coefficients. Eight solvents were selected in order to represent various chemical classes: toluene and benzene (aromatics), hexane and heptane (alkanes), n-octanol (alcohols), n-butyl acetate (esters), diisopropyl ether (ethers), and methylisobutyl ketone (ketones). The aromatic solutes included: nonpolar compounds such as benzene, toluene and naphthalene, phenolic compounds such as phenol, cresol and catechol, nitrogenous aromatics such as aniline, pyridine and aminonaphthalene, and other aromatic solutes such as naphthol, quinolinol and halogenated compounds. 100 references, 20 figures, 34 tables.
Hydrodynamic Coefficients of Ships with Forward Speed in Shallow Waters
M.HASANADIL; DUANWen-yang; WANGYu
2004-01-01
Effects of depth and forward speed on hydrodynamic coefficients of ships are presented in this paper. A modified simple Green function technique was used to calculate 2D coefficients while strip theory was used to calculate 3D coefficients. Numerical results are provided for hydrodynamic coefficients of parabolic hull ship. It is found out that both depth and forward speed have considerable effects on hydrodynamic coefficients of ship.
Tests of Hypotheses Arising In the Correlated Random Coefficient Model.
Heckman, James J; Schmierer, Daniel
2010-11-01
This paper examines the correlated random coefficient model. It extends the analysis of Swamy (1971), who pioneered the uncorrelated random coefficient model in economics. We develop the properties of the correlated random coefficient model and derive a new representation of the variance of the instrumental variable estimator for that model. We develop tests of the validity of the correlated random coefficient model against the null hypothesis of the uncorrelated random coefficient model.
Recursive construction of operator product expansion coefficients
Holland, J
2014-01-01
We derive a novel formula for the derivative of operator product expansion (OPE) coefficients with respect to a coupling constant. The formula only involves the OPE coefficients themselves, and no further input, and is in this sense self-consistent. Furthermore, unlike other formal identities of this general nature in quantum field theory (such as the formal expression for the Lagrangian perturbation of a correlation function), our formula is completely well-defined from the start, i.e. requires no further UV-renormalization. This feature is a result of a cancelation of UV-divergences between various terms in our identity. Our proof, and an analysis of the features, of our identity is given for the example of massive, Euclidean $\\varphi^4$ theory in 4 dimensional Euclidean space, and relies heavily on the framework of the renormalization group flow equations. It is valid to arbitrary, but finite orders in perturbation theory. The final formula, however, makes no explicit reference to the renormalization group...
Coefficient adaptive triangulation for strongly anisotropic problems
D`Azevedo, E.F.; Romine, C.H.; Donato, J.M.
1996-01-01
Second order elliptic partial differential equations arise in many important applications, including flow through porous media, heat conduction, the distribution of electrical or magnetic potential. The prototype is the Laplace problem, which in discrete form produces a coefficient matrix that is relatively easy to solve in a regular domain. However, the presence of anisotropy produces a matrix whose condition number is increased, making the resulting linear system more difficult to solve. In this work, we take the anisotropy into account in the discretization by mapping each anisotropic region into a ``stretched`` coordinate space in which the anisotropy is removed. The region is then uniformly triangulated, and the resulting triangulation mapped back to the original space. The effect is to generate long slender triangles that are oriented in the direction of ``preferred flow.`` Slender triangles are generally regarded as numerically undesirable since they tend to cause poor conditioning; however, our triangulation has the effect of producing effective isotropy, thus improving the condition number of the resulting coefficient matrix.
Hydrazoic acid distribution coefficients in Purex processing
Kelmers, A.D.; Browning, D.N.
1977-01-01
Mixtures of hydroxylamine nitrate and hydrazine are being considered for the reductive stripping of plutonium during Purex processing. The hydrazine functions as a holding reductant for plutonium(III) by destroying nitrous acid via the fast reaction N/sub 2/H/sub 4/ + HNO/sub 2/ ..-->.. HN/sub 3/ + 2H/sub 2/O which leads to the stoichiometric formation of hydrazoic acid. We have measured the distribution coefficients for hydrazoic acid between nitric acid solutions and tributylphosphate-dodecane solutions. Values in the range of 1 to 10 were obtained under typical Purex process conditions. This indicates that most of the hydrazoic acid will be present in the organic phase leaving the plutonium stripping contactors. The distribution coefficients can be expressed as log(E O/A) = n log(Free TBP) + log K' where K' is 7.0, 10.0, 5.1 and 4.7, respectively, at 25, 35, 45 and 55/sup 0/C; and the corresponding values of n are 1.11, 1.27, 0.97 and 1.20.
Predicting diffusion coefficients of chemicals in and through packaging materials.
Fang, Xiaoyi; Vitrac, Olivier
2017-01-22
Most of the physicochemical properties in polymers such as activity and partition coefficients, diffusion coefficients, and their activation with temperature are accessible to direct calculations from first principles. Such predictions are particularly relevant for food packaging as they can be used (1) to demonstrate the compliance or safety of numerous polymer materials and of their constitutive substances (e.g. additives, residues…), when they are used: as containers, coatings, sealants, gaskets, printing inks, etc. (2) or to predict the indirect contamination of food by pollutants (e.g. from recycled polymers, storage ambiance…) (3) or to assess the plasticization of materials in contact by food constituents (e.g. fat matter, aroma…). This review article summarizes the classical and last mechanistic descriptions of diffusion in polymers and discusses the reliability of semi-empirical approaches used for compliance testing both in EU and US. It is concluded that simulation of diffusion in or through polymers is not limited to worst-case assumptions but could also be applied to real cases for risk assessment, designing packaging with low leaching risk or to synthesize plastic additives with low diffusion rates.
无
2002-01-01
It is a problem to be solved that the experimental selectivity coefficients of ion selective electrodes (ISEs) depend on the activity.This paper studied the new method of determining selectivity coefficients.A mixed ion response equation,which was similar to Nicolsky-Eisenman (N-E) equation recommended by IUPAC,was proposed.The equation includes the practical response slope of ISEs to the primary ion and the interfering ion.The selectivity coefficient was defined by the equation instead of the N-E equation.The experimental part of the method is similar to that based on the N-E equation.The values of selectivity coefficients obtained with this method do not depend on the activity whether the electrodes exhibit the Nernst response or non-Nernst response.The feasibility of the new method is illustrated experimentally.
Optimization of dielectric constant temperature coefficient of pyrochlores containing bismuth
REN Qing-li; LUO Qiang; CHEN Shou-tian
2005-01-01
The Bi2O3-ZnO-Nb2O5 (BZN)-based ceramic samples were prepared according to the optimum composition of (Bi3xZn2-3x)(Znx Nb2-x)O7 by solid state reaction. The BZN ceramic structure and the dielectric properties were explored via X-ray diffractometer(XRD), differential thermal analysis(DTA), scanning electron microscope (SEM), and HP4275A impedance analysis. The amphoteric surface active agent with alcohol amine double nature is introduced when the raw materials are mixed and ground. The anatase titania doped BZN-based ceramics was also investigated. Either doping the anatase TiO3 or adding the surface active agent or both of them can widen sintering temperature range which satisfies the zero temperature coefficient (0±30 × 10-6/℃) of the BZN ceramics. And these BZN ceramics with diphasic pyrochlore structure possess excellent dielectric properties.
GUAN Hsin; WANG Bo; LU Pingping; XU Liang
2014-01-01
The identification of maximum road friction coefficient and optimal slip ratio is crucial to vehicle dynamics and control. However, it is always not easy to identify the maximum road friction coefficient with high robustness and good adaptability to various vehicle operating conditions. The existing investigations on robust identification of maximum road friction coefficient are unsatisfactory. In this paper, an identification approach based on road type recognition is proposed for the robust identification of maximum road friction coefficient and optimal slip ratio. The instantaneous road friction coefficient is estimated through the recursive least square with a forgetting factor method based on the single wheel model, and the estimated road friction coefficient and slip ratio are grouped in a set of samples in a small time interval before the current time, which are updated with time progressing. The current road type is recognized by comparing the samples of the estimated road friction coefficient with the standard road friction coefficient of each typical road, and the minimum statistical error is used as the recognition principle to improve identification robustness. Once the road type is recognized, the maximum road friction coefficient and optimal slip ratio are determined. The numerical simulation tests are conducted on two typical road friction conditions(single-friction and joint-friction) by using CarSim software. The test results show that there is little identification error between the identified maximum road friction coefficient and the pre-set value in CarSim. The proposed identification method has good robustness performance to external disturbances and good adaptability to various vehicle operating conditions and road variations, and the identification results can be used for the adjustment of vehicle active safety control strategies.
Thermal Conductivity Coefficient from Microscopic Models
Nemakhavhani, T E
2016-01-01
Thermal conductivity of hadron matter is studied using a microscopic transport model, which will be used to simulate ultra-relativistic heavy ion collisions at different energy densities, namely the Ultra-relativistic Quantum Molecular Dynamics (UrQMD). The molecular dynamics simulation is performed for a system of light mesons species (pion, rho, kaon) in a box with periodic boundary conditions. The equilibrium state is investigated by studying chemical equilibrium and thermal equilibrium of the system. Particle multiplicity equilibrates with time, and the energy spectra of different light mesons species have the same slopes and common temperatures when thermal equilibrium is reached. Thermal conductivity transport coefficient is calculated from the heat current - current correlations using the Green-Kubo relations.
Secondary Ionization Coefficient of Dielectric Electrode
Kashiwagi, Yasuhide; Suzuki, Susumu; Itoh, Haruo
Experiments for observations and stabilization of discharge paths in several electrode systems are carried out aiming at precise measurement of the secondary ionization coefficient γ of MgO film electrode. The discharge chamber is filled with Ar gas. The waveforms of the applied voltage between the electrodes and the discharge current are measured with visual observation of the discharge light. Two MgO coated electrodes are placed so that they are facing each other. For these MgO electrodes, the discharge paths take a detour, not the shortest distance. Smaller prebreakdown current pulses are observed before the breakdown. After breakdown, discontinuous discharge current is observed. Therefore, it is prepared a glass tube surrounding the discharge area. As the result, the discharge paths take a straight perpendicular for the electrode surface, and the discharge is stabilized.
Molar extinction coefficients of some fatty acids
Sandhu, G. K.; Singh, Kulwant; Lark, B. S.; Gerward, L.
2002-10-01
The attenuation of gamma rays in some fatty acids, viz. formic acid (CH 2O 2), acetic acid (C 2H 4O 2), propionic acid (C 3H 6O 2), butyric acid (C 4H 8O 2), n-hexanoic acid (C 6H 12O 2), n-caprylic acid (C 8H 16O 2), lauric acid (C 12H 24O 2), myristic acid (C 14H 28O 2), palmitic acid (C 16H 32O 2), oleic acid (C 18H 34O 2) and stearic acid (C 18H 36O 2), has been measured at the photon energies 81, 356, 511, 662, 1173 and 1332 keV. Experimental values for the molar extinction coefficient, the effective atomic number and the electron density have been derived and compared with theoretical calculations. There is good agreement between experiment and theory.
Clustering stocks using partial correlation coefficients
Jung, Sean S.; Chang, Woojin
2016-11-01
A partial correlation analysis is performed on the Korean stock market (KOSPI). The difference between Pearson correlation and the partial correlation is analyzed and it is found that when conditioned on the market return, Pearson correlation coefficients are generally greater than those of the partial correlation, which implies that the market return tends to drive up the correlation between stock returns. A clustering analysis is then performed to study the market structure given by the partial correlation analysis and the members of the clusters are compared with the Global Industry Classification Standard (GICS). The initial hypothesis is that the firms in the same GICS sector are clustered together since they are in a similar business and environment. However, the result is inconsistent with the hypothesis and most clusters are a mix of multiple sectors suggesting that the traditional approach of using sectors to determine the proximity between stocks may not be sufficient enough to diversify a portfolio.
ROUGHNESS COEFFICIENT FOR UNSUBMERGED AND SUBMERGED REED
无
2007-01-01
The characteristics of the roughness coefficient are very important for practical application. Some experiments are conducted to study the variation of Manning's n with flow depth, mean velocity, and density of vegetation,. An assumed velocity distribution to describe the vegetative flow of submerged vegetation is confirmed by experimental results. The measured velocities in this study seem to have little effect on the curve of n ～ h, and a new linear relationship between Manning's n and flow depths is observed clearly. According to the arguments that the flow resistance of densely unsubmerged vegetation is dominated by the resistance exerted on vegetations, the influence of the density of vegetation on Manning's n is estimated. On the basis of the velocity distribution, the n ～ h curve under submerged condition is theoretically obtained from the n ～ h curve under unsubmerged condition. These results are also well confirmed by experimental results and very significant for practical applications.
Condensation heat transfer coefficient versus wettability
Roudgar, M.; De Coninck, J.
2015-05-01
In this paper we show how condensation on substrates can induce wetting behavior that is quite different from that of deposited or impinging drops. We describe surfaces with the same wettability in ambient conditions presenting different wetting behavior and growth of droplets in condensation. The experimental results show a rapid spread of droplets and formation of the film on the copper surface, while droplets on SU-8 surface remains on the regular shape while they grow within the time, without coalescence, as observed for Cu. Although the heat conductivity of SU-8 is much lower, due to a difference in wetting behavior, the heat transfer coefficient (h) is higher for dropwise condensation on Cu with a thin layer of SU-8 than filmwise on the bare copper.
Effective Electrocardiogram Steganography Based on Coefficient Alignment.
Yang, Ching-Yu; Wang, Wen-Fong
2016-03-01
This study presents two types of data hiding methods based on coefficient alignment for electrocardiogram (ECG) signals, namely, lossy and reversible ECG steganographys. The lossy method is divided into high-quality and high-capacity ECG steganography, both of which are capable of hiding confidential patient data in ECG signals. The reversible data hiding method can not only hide secret messages but also completely restore the original ECG signal after bit extraction. Simulations confirmed that the perceived quality generated by the lossy ECG steganography methods was good, while hiding capacity was acceptable. In addition, these methods have a certain degree of robustness, which is rare in conventional ECG stegangraphy schemes. Moreover, the proposed reversible ECG steganography method can not only successfully extract hidden messages but also completely recover the original ECG data.
Coefficient of performance of Stirling refrigerators
E Mungan, Carl
2017-09-01
Stirling coolers transfer heat in or out of the working fluid during all four stages of their operation, and their coefficient of performance depends on whether the non-isothermal heat exchanges are performed reversibly or irreversibly. Both of these possibilities can in principle be arranged. Notably, if the working fluid is an ideal gas, the input of energy in the form of heat during one isochoric step is equal in magnitude to the output during the other isochoric step in the cycle. The theoretical performance of the fridge can then attain the reversible Carnot limit if a regenerator is used, which is a high heat capacity material through which the gas flows. Various Stirling refrigerator configurations are analysed in this article at a level of presentation suitable for an introductory undergraduate thermodynamics course.
Friction Experiments for Dynamical Coefficient Measurement
J. J. Arnoux
2011-01-01
Full Text Available An experimental study, including three experimental devices, is presented in order to investigate dry friction phenomena in a wide range of sliding speeds for the steel on steel contact. A ballistic setup, with an air gun launch, allows to estimate the friction coefficient between 20 m/s and 80 m/s. Tests are completed by an adaptation of the sensor on a hydraulic tensile machine (0.01 m/s to 3 m/s and a pin-on-disk tribometer mounted on a CNC lathe (1 to 30 m/s. The interactions at the asperity scale are characterized by a white light interferometer surface analysis.
Transport coefficients in superfluid neutron stars
Tolos, Laura [Instituto de Ciencias del Espacio (IEEC/CSIC) Campus Universitat Autònoma de Barcelona, Facultat de Ciències, Torre C5, E-08193 Bellaterra (Barcelona) (Spain); Frankfurt Institute for Advances Studies. Johann Wolfgang Goethe University, Ruth-Moufang-Str. 1, 60438 Frankfurt am Main (Germany); Manuel, Cristina [Instituto de Ciencias del Espacio (IEEC/CSIC) Campus Universitat Autònoma de Barcelona, Facultat de Ciències, Torre C5, E-08193 Bellaterra (Barcelona) (Spain); Sarkar, Sreemoyee [Tata Institute of Fundamental Research, Homi Bhaba Road, Mumbai-400005 (India); Tarrus, Jaume [Physik Department, Technische Universität München, D-85748 Garching (Germany)
2016-01-22
We study the shear and bulk viscosity coefficients as well as the thermal conductivity as arising from the collisions among phonons in superfluid neutron stars. We use effective field theory techniques to extract the allowed phonon collisional processes, written as a function of the equation of state and the gap of the system. The shear viscosity due to phonon scattering is compared to calculations of that coming from electron collisions. We also comment on the possible consequences for r-mode damping in superfluid neutron stars. Moreover, we find that phonon collisions give the leading contribution to the bulk viscosities in the core of the neutron stars. We finally obtain a temperature-independent thermal conductivity from phonon collisions and compare it with the electron-muon thermal conductivity in superfluid neutron stars.
Experimental measurement of dispersion coefficients for gases
De Delgado, E. [National University at Comahue (Brazil); Da Franca Correa, A.C. [State Univ. of Campinas (Brazil)
2001-06-01
A series of experiments were conducted on dispersion, a phenomenon by which molecules of two miscible fluids diffuse into one another when they come into contact with each other. Both longitudinal and transverse diffusion is a result of forced flow. Longitudinal dispersion occurs in the direction of flow, while transverse dispersion occurs perpendicular to the direction of flow. This study focused on measuring longitudinal dispersion coefficients on natural gas displaced by an inert gas (nitrogen) at very low pressure. The experiments were carried out at two different pressure ranges on unconsolidated porous media at a Gas Plant Laboratory near Neuquen, Argentina. Two different types of porous media were used, a plastic hose and a metallic slim tube. They were each filled twice with both natural and synthetic sand grains. The study provided a better understanding of how gases behave at low pressures. 4 refs., 4 tabs., 5 figs.
Fractai Estimation of Joint Roughness Coefficients
谢和平; Willian G.Pariseau
1994-01-01
Based on the triadic Koch curve,a generalized fractal model of joint profiles is establishedto simulate joint roughness.The fractal dimension of a joint profile can be directly obtained from the two pa-rameters,L~* and h~*, the average base length and average height of asperities of the joint,respectively,i,e D=log4/log[2(1+cos tan~1(2h’/L’))]This fractal dimension is strongly correlated with the value of the joint roughness coefficient (JRC). An empirical relationship is found in the form,JRC=85.2671·(D-1)~0.5679 Thus, the fractal analysis proposed provides a new method of estimating JRC values
Comment on "Generalized exclusion processes: Transport coefficients"
Becker, T.; Nelissen, K.; Cleuren, B.; Partoens, B.; Van den Broeck, C.
2016-04-01
In a recent paper, Arita et al. [Phys. Rev. E 90, 052108 (2014), 10.1103/PhysRevE.90.052108] consider the transport properties of a class of generalized exclusion processes. Analytical expressions for the transport-diffusion coefficient are derived by ignoring correlations. It is claimed that these expressions become exact in the hydrodynamic limit. In this Comment, we point out that (i) the influence of correlations upon the diffusion does not vanish in the hydrodynamic limit, and (ii) the expressions for the self- and transport diffusion derived by Arita et al. are special cases of results derived in Becker et al. [Phys. Rev. Lett. 111, 110601 (2013), 10.1103/PhysRevLett.111.110601].
Transport coefficients in superfluid neutron stars
Tolos, Laura; Sarkar, Sreemoyee; Tarrus, Jaume
2014-01-01
We study the shear and bulk viscosity coefficients as well as the thermal conductivity as arising from the collisions among phonons in superfluid neutron stars. We use effective field theory techniques to extract the allowed phonon collisional processes, written as a function of the equation of state and the gap of the system. The shear viscosity due to phonon scattering is compared to calculations of that coming from electron collisions. We also comment on the possible consequences for r-mode damping in superfluid neutron stars. Moreover, we find that phonon collisions give the leading contribution to the bulk viscosities in the core of the neutron stars. We finally obtain a temperature-independent thermal conductivity from phonon collisions and compare it with the electron-muon thermal conductivity in superfluid neutron stars.
Irreducible polynomials with prescribed sums of coefficients
Tuxanidy, Aleksandr; Wang, Qiang
2016-01-01
Let $q$ be a power of a prime, let $\\mathbb{F}_q$ be the finite field with $q$ elements and let $n \\geq 2$. For a polynomial $h(x) \\in \\mathbb{F}_q[x]$ of degree $n \\in \\mathbb{N}$ and a subset $W \\subseteq [0,n] := \\{0, 1, \\ldots, n\\}$, we define the sum-of-digits function $$S_W(h) = \\sum_{w \\in W}[x^{w}] h(x)$$ to be the sum of all the coefficients of $x^w$ in $h(x)$ with $w \\in W$. In the case when $q = 2$, we prove, except for a few genuine exceptions, that for any $c \\in \\mathbb{F}_2$ an...
Partitioning coefficients between olivine and silicate melts
Bédard, J. H.
2005-08-01
Variation of Nernst partition coefficients ( D) between olivine and silicate melts cannot be neglected when modeling partial melting and fractional crystallization. Published natural and experimental olivine/liquidD data were examined for covariation with pressure, temperature, olivine forsterite content, and melt SiO 2, H 2O, MgO and MgO/MgO + FeO total. Values of olivine/liquidD generally increase with decreasing temperature and melt MgO content, and with increasing melt SiO 2 content, but generally show poor correlations with other variables. Multi-element olivine/liquidD profiles calculated from regressions of D REE-Sc-Y vs. melt MgO content are compared to results of the Lattice Strain Model to link melt MgO and: D0 (the strain compensated partition coefficient), EM3+ (Young's Modulus), and r0 (the size of the M site). Ln D0 varies linearly with Ln MgO in the melt; EM3+ varies linearly with melt MgO, with a dog-leg at ca. 1.5% MgO; and r0 remains constant at 0.807 Å. These equations are then used to calculate olivine/liquidD for these elements using the Lattice Strain Model. These empirical parameterizations of olivine/liquidD variations yield results comparable to experimental or natural partitioning data, and can easily be integrated into existing trace element modeling algorithms. The olivine/liquidD data suggest that basaltic melts in equilibrium with pure olivine may acquire small negative Ta-Hf-Zr-Ti anomalies, but that negative Nb anomalies are unlikely to develop. Misfits between results of the Lattice Strain Model and most light rare earth and large ion lithophile partitioning data suggest that kinetic effects may limit the lower value of D for extremely incompatible elements in natural situations characterized by high cooling/crystallization rates.
Apparent diffusion coefficient of normal adrenal glands*
Teixeira, Sara Reis; Elias, Paula Condé Lamparelli; Leite, Andrea Farias de Melo; de Oliveira, Tatiane Mendes Gonçalves; Muglia, Valdair Francisco; Elias Junior, Jorge
2016-01-01
Objective To assess the feasibility and reliability of apparent diffusion coefficient (ADC) measurements of normal adrenal glands. Materials and methods This was a retrospective study involving 32 healthy subjects, divided into two groups: prepubertal (PreP, n = 12), aged from 2 months to 12.5 years (4 males; 8 females); and postpubertal (PostP, n = 20), aged from 11.9 to 61 years (5 males; 15 females). Diffusion-weighted magnetic resonance imaging (DW-MRI) sequences were acquired at a 1.5 T scanner using b values of 0, 20, 500, and 1000 s/mm2. Two radiologists evaluated the images. ADC values were measured pixel-by-pixel on DW-MRI scans, and automatic co-registration with the ADC map was obtained. Results Mean ADC values for the right adrenal glands were 1.44 × 10-3 mm2/s for the PreP group and 1.23 × 10-3 mm2/s for the PostP group, whereas they were 1.58 × 10-3 mm2/s and 1.32 × 10-3 mm2/s, respectively, for the left glands. ADC values were higher in the PreP group than in the PostP group (p < 0.05). Agreement between readers was almost perfect (intraclass correlation coefficient, 0.84-0.94; p < 0.05). Conclusion Our results demonstrate the feasibility and reliability of performing DW-MRI measurements of normal adrenal glands. They could also support the feasibility of ADC measurements of small structures. PMID:28057963
Apparent diffusion coefficient of normal adrenal glands
Sara Reis Teixeira
Full Text Available Abstract Objective: To assess the feasibility and reliability of apparent diffusion coefficient (ADC measurements of normal adrenal glands. Materials and methods: This was a retrospective study involving 32 healthy subjects, divided into two groups: prepubertal (PreP, n = 12, aged from 2 months to 12.5 years (4 males; 8 females; and postpubertal (PostP, n = 20, aged from 11.9 to 61 years (5 males; 15 females. Diffusion-weighted magnetic resonance imaging (DW-MRI sequences were acquired at a 1.5 T scanner using b values of 0, 20, 500, and 1000 s/mm2. Two radiologists evaluated the images. ADC values were measured pixel-by-pixel on DW-MRI scans, and automatic co-registration with the ADC map was obtained. Results: Mean ADC values for the right adrenal glands were 1.44 × 10-3 mm2/s for the PreP group and 1.23 × 10-3 mm2/s for the PostP group, whereas they were 1.58 × 10-3 mm2/s and 1.32 × 10-3 mm2/s, respectively, for the left glands. ADC values were higher in the PreP group than in the PostP group (p < 0.05. Agreement between readers was almost perfect (intraclass correlation coefficient, 0.84-0.94; p < 0.05. Conclusion: Our results demonstrate the feasibility and reliability of performing DW-MRI measurements of normal adrenal glands. They could also support the feasibility of ADC measurements of small structures.
Lee, Kil Yong; Burnett, William C
A simple method for the direct determination of the air-loop volume in a RAD7 system as well as the radon partition coefficient was developed allowing for an accurate measurement of the radon activity in any type of water. The air-loop volume may be measured directly using an external radon source and an empty bottle with a precisely measured volume. The partition coefficient and activity of radon in the water sample may then be determined via the RAD7 using the determined air-loop volume. Activity ratios instead of absolute activities were used to measure the air-loop volume and the radon partition coefficient. In order to verify this approach, we measured the radon partition coefficient in deionized water in the temperature range of 10-30 °C and compared the values to those calculated from the well-known Weigel equation. The results were within 5 % variance throughout the temperature range. We also applied the approach for measurement of the radon partition coefficient in synthetic saline water (0-75 ppt salinity) as well as tap water. The radon activity of the tap water sample was determined by this method as well as the standard RAD-H2O and BigBottle RAD-H2O. The results have shown good agreement between this method and the standard methods.
Adler, Jeremy; Parmryd, Ingela
2010-08-01
The Pearson correlation coefficient (PCC) and the Mander's overlap coefficient (MOC) are used to quantify the degree of colocalization between fluorophores. The MOC was introduced to overcome perceived problems with the PCC. The two coefficients are mathematically similar, differing in the use of either the absolute intensities (MOC) or of the deviation from the mean (PCC). A range of correlated datasets, which extend to the limits of the PCC, only evoked a limited response from the MOC. The PCC is unaffected by changes to the offset while the MOC increases when the offset is positive. Both coefficients are independent of gain. The MOC is a confusing hybrid measurement, that combines correlation with a heavily weighted form of co-occurrence, favors high intensity combinations, downplays combinations in which either or both intensities are low and ignores blank pixels. The PCC only measures correlation. A surprising finding was that the addition of a second uncorrelated population can substantially increase the measured correlation, demonstrating the importance of excluding background pixels. Overall, since the MOC is unresponsive to substantial changes in the data and is hard to interpret, it is neither an alternative to nor a useful substitute for the PCC. The MOC is not suitable for making measurements of colocalization either by correlation or co-occurrence.
EXTENDED CLUSTERING COEFFICIENTS:GENERALIZATION OF CLUSTERING COEFFICIENTS IN SMALL-WORLD NETWORKS
无
2007-01-01
The clustering coefficient C of a network, which is a measure of direct connectivity between neighbors of the various nodes, ranges from 0 (for no connectivity) to 1 (for full connectivity). We define extended clustering coefficients C(h) of a small-world network based on nodes that are at distance h from a source node, thus generalizing distance-1 neighborhoods employed in computing the ordinary clustering coefficient C = C(1). Based on known results about the distance distribution Pδ(h) in a network, that is, the probability that a randomly chosen pair of vertices have distance h, we derive and experimentally validate the law Pδ(h)C(h) ≤ c log N / N, where c is a small constant that seldom exceeds 1. This result is significant because it shows that the product Pδ(h)C(h) is upper-bounded by a value that is considerably smaller than the product of maximum values for Pδ(h) and C(h). Extended clustering coefficients and laws that govern them offer new insights into the structure of small-world networks and open up avenues for further exploration of their properties.
Bromaghin, Jeffrey; Budge, Suzanne M.; Thiemann, Gregory W.; Rode, Karyn D.
2017-01-01
Knowledge of animal diets provides essential insights into their life history and ecology, although diet estimation is challenging and remains an active area of research. Quantitative fatty acid signature analysis (QFASA) has become a popular method of estimating diet composition, especially for marine species. A primary assumption of QFASA is that constants called calibration coefficients, which account for the differential metabolism of individual fatty acids, are known. In practice, however, calibration coefficients are not known, but rather have been estimated in feeding trials with captive animals of a limited number of model species. The impossibility of verifying the accuracy of feeding trial derived calibration coefficients to estimate the diets of wild animals is a foundational problem with QFASA that has generated considerable criticism. We present a new model that allows simultaneous estimation of diet composition and calibration coefficients based only on fatty acid signature samples from wild predators and potential prey. Our model performed almost flawlessly in four tests with constructed examples, estimating both diet proportions and calibration coefficients with essentially no error. We also applied the model to data from Chukchi Sea polar bears, obtaining diet estimates that were more diverse than estimates conditioned on feeding trial calibration coefficients. Our model avoids bias in diet estimates caused by conditioning on inaccurate calibration coefficients, invalidates the primary criticism of QFASA, eliminates the need to conduct feeding trials solely for diet estimation, and consequently expands the utility of fatty acid data to investigate aspects of ecology linked to animal diets.
The Attenuation of Correlation Coefficients: A Statistical Literacy Issue
Trafimow, David
2016-01-01
Much of the science reported in the media depends on correlation coefficients. But the size of correlation coefficients depends, in part, on the reliability with which the correlated variables are measured. Understanding this is a statistical literacy issue.
Recovering DC coefficients in block-based DCT.
Uehara, Takeyuki; Safavi-Naini, Reihaneh; Ogunbona, Philip
2006-11-01
It is a common approach for JPEG and MPEG encryption systems to provide higher protection for dc coefficients and less protection for ac coefficients. Some authors have employed a cryptographic encryption algorithm for the dc coefficients and left the ac coefficients to techniques based on random permutation lists which are known to be weak against known-plaintext and chosen-ciphertext attacks. In this paper we show that in block-based DCT, it is possible to recover dc coefficients from ac coefficients with reasonable image quality and show the insecurity of image encryption methods which rely on the encryption of dc values using a cryptoalgorithm. The method proposed in this paper combines dc recovery from ac coefficients and the fact that ac coefficients can be recovered using a chosen ciphertext attack. We demonstrate that a method proposed by Tang to encrypt and decrypt MPEG video can be completely broken.
TESTS FOR VARIANCE COMPONENTS IN VARYING COEFFICIENT MIXED MODELS
Zaixing Li; Yuedong Wang; Ping Wu; Wangli Xu; Lixing Zhu
2012-01-01
.... To address the question of whether a varying coefficient mixed model can be reduced to a simpler varying coefficient model, we develop one-sided tests for the null hypothesis that all the variance components are zero...
Determination of reversible protein equilibrium association coefficients using light scattering
Larkin, Michael
2009-03-01
The characterization in solution of reversible protein associations as well as associations between proteins and small molecules is essential in many areas of science. Understanding cellular function or developing and formulating pharmaceuticals or other biologically active materials often requires quantitation of such associations. Most pharmaceuticals have functionality due solely to association with molecules within the body, and the discovery and accurate characterization of these associations is a key element for pharmaceutical development. Unfortunately, most methods used to measure associations of proteins require either immobilizing the protein on a surface (e.g. surface plasmon resonance), which potentially alters the protein characteristics, or require considerable time and effort and large quantities of sample (e.g. analytical ultracentrifugation, isothermal titration calorimetry). Light scattering based measurements of reversible association coefficients require much less sample and may be performed much more rapidly than other free solution techniques. In this talk I describe how static and dynamic light scattering may each independently be used to measure equilibrium association coefficients between proteins in free solution, and may also be used to observe and quantitate the association of small molecules with them. I present background theory for both static and dynamic light scattering measurements of equilibrium associations, and examples of measurements made of both model systems and of systems with commercial relevance in the pharmaceutical industry.
Inverse Coefficient Problems for Nonlinear Parabolic Differential Equations
Yun Hua OU; Alemdar HASANOV; Zhen Hai LIU
2008-01-01
This paper is devoted to a class of inverse problems for a nonlinear parabolic differential equation.The unknown coefficient of the equation depends on the gradient of the solution and belongs to a set of admissible coefficients.It is proved that the convergence of solutions for the corresponding direct problems continuously depends on the coefficient convergence.Based on this result the existence of a quasisolution of the inverse problem is obtained in the appropriate class of admissible coefficients.
Inverse Coefficient Problems for Nonlinear Elliptic Variational Inequalities
Run-sheng Yang; Yun-hua Ou
2011-01-01
This paper is devoted to a class of inverse coefficient problems for nonlinear elliptic variational inequalities. The unknown coefficient of elliptic variational inequalities depends on the gradient of the solution and belongs to a set of admissible coefficients. It is shown that the nonlinear elliptic variational inequalities is unique solvable for the given class of coefficients. The existence of quasisolutions of the inverse problems is obtained.
On Coefficient problem for bi-univalent analytic functions
Bohra, Nisha; Ravichandran, V.
2017-01-01
Estimates for initial coefficients of Taylor-Maclaurin series of bi-univalent functions belonging to certain classes defined by subordination are obtained. Our estimates improve upon the earlier known estimates for second and third coefficient. The bound for the fourth coefficient is new. In addition, bound for the fifth coefficient is obtained for bi-starlike and strongly bi-starlike functions of order $\\rho$ and $\\beta$ respectively.
Describing spatiotemporal couplings in ultrashort pulses using coupling coefficients
Zeng Shu-Guang; Dan You-Quan; Zhang Bin; Sun Nian-Chun; Sui Zhan
2011-01-01
Three coupling coefficients are defined to describe spatiotemporal coupling in ultrashort pulses.With these coupling coefficients,the first-order spatiotemporal couplings of Gaussian pulse and beam are described analytically.Also,the first-order and the second-order spatiotemporal couplings caused by angular dispersion elements are studied using these coupling coefficients.It can be shown that these coupling coefficients are dimensionless and normalized,and readily indicate the severity of spatiotemporal coupling.
Control rod drop surveillance using two friction coefficients
Blázquez, Juan; Vallejo, I.; García-Berrocal Sánchez, Agustin; Balbás Antón, Miguel
2011-01-01
In the case of large burnup, a control rod (CR) guide tube in the pressurized water reactor of a commercial nuclear power plant might bend. As a consequence, a CR drop experiment may indicate an event of a CR partially inserted and whether the CR should be deemed inoperable. Early prevention of such an event can be achieved by measuring two friction coefficients: the hydraulic coefficient and the sliding coefficient. The hydraulic coefficient hardly changes, so that the curvature of the guide...
EXACT SAMPLING DISTRIBUTION OF SAMPLE COEFFICIENT OF VARIATION
Dr.G.S.David Sam Jayakumar; A.Sulthan
2015-01-01
This paper proposes the sampling distribution of sample coefficient of variation from the normal population. We have derived the relationship between the sample coefficient of variation, standard normal and chi-square variate. We have derived density function of the sample coefficient of variation in terms of the confluent hyper-geometric distribution. Moreover, the first two moments of the distribution are derived and we have proved that the sample coefficient of variation (cv...
Additional studies on heterodiffusion coefficients in periclase
E. Dologlou
2012-11-01
Full Text Available By using a thermodynamical model, the activation entropy is extracted from the experimental diffusion data of Al in MgO. Furthermore, we estimate the activation volume. We find a value for the activation entropy of (4.21 ± 0.05 k. As for the activation volume, we calculate the value (3.65 ± 0.16 cm^{3} mol ^{−1} which is comparable with the experimental values when errors are considered.
On Estimation and Hypothesis Testing Problems for Correlation Coefficients
Kraemer, Helena Chmura
1975-01-01
A selection of statistical problems commonly encountered in psychological or psychiatric research concerning correlation coefficients are re-evaluated in the light of recently developed simplifications in the forms of the distribution theory of the intraclass correlation coefficient, of the product-moment correlation coefficient, and the Spearman…
General Symmetry Approach to Solve Variable-Coefficient Nonlinear Equations
RUAN HangYu; CHEN YiXin; LOU SenYue
2001-01-01
After considering the variable coefficient of a nonlinear equation as a new dependent variable, some special types of variable-coefficient equation can be solved from the corresponding constant-coefficient equations by using the general classical Lie approach. Taking the nonlinear Schrodinger equation as a concrete example, the method is recommended in detail.``
Sample controllability of impulsive differential systems with random coefficients
Zhang, Shuorui; Sun, Jitao
2016-07-01
In this paper, we investigate the controllability of impulsive differential systems with random coefficients. Impulsive differential systems with random coefficients are a different stochastic model from stochastic differential equations. Sufficient conditions of sample controllability for impulsive differential systems with random coefficients are obtained by using random Sadovskii's fixed-point theorem. Finally, an example is given to illustrate our results.
Detection Performance of the Circular Correlation Coefficient Receiver,
of the squared modulus of the circular serial correlation coefficient is found when no signal is present, allowing computation of the detection...threshold. For small data records, as is typical in radar applications, the performance of the correlation coefficient detector is compared to a standard... Correlation Coefficient , Autoregressive, CFAR, Autocorrelation Estimation, Radar Receiver, and Digital Signal Processing.
Interpretation of Standardized Regression Coefficients in Multiple Regression.
Thayer, Jerome D.
The extent to which standardized regression coefficients (beta values) can be used to determine the importance of a variable in an equation was explored. The beta value and the part correlation coefficient--also called the semi-partial correlation coefficient and reported in squared form as the incremental "r squared"--were compared for…
Clebsch-Gordan coefficients of finite magnetic groups
Broek, van den P.M.
1979-01-01
A detailed method is given for the calculation of Clebsch–Gordan coefficients of finite magnetic groups. This method is a generalization of a new method for the calculation of Clebsch–Gordan coefficients of finite nonmagnetic groups which makes use of the fact that the Clebsch–Gordan coefficients ma
Testing the Difference between Reliability Coefficients Alpha and Omega
Deng, Lifang; Chan, Wai
2017-01-01
Reliable measurements are key to social science research. Multiple measures of reliability of the total score have been developed, including coefficient alpha, coefficient omega, the greatest lower bound reliability, and others. Among these, the coefficient alpha has been most widely used, and it is reported in nearly every study involving the…
The Discharge Coefficient of a Centre-Pivot Roof Window
Iqbal, Ahsan; Afshari, Alireza; Nielsen, Peter V.
2012-01-01
value of discharge coefficient is used. The constant value of discharge coefficient leads to deceptive airflow estimation in the cases of centre-pivot roof windows. The object of this paper is to study and evaluate the discharge coefficient of the centre pivot roof window. Focus is given...
Review of analysis methods for rotating systems with periodic coefficients
Dugundji, J.; Wendell, J. H.
1981-01-01
Two of the more common procedures for analyzing the stability and forced response of equations with periodic coefficients are reviewed: the use of Floquet methods, and the use of multiblade coordinate and harmonic balance methods. The analysis procedures of these periodic coefficient systems are compared with those of the more familiar constant coefficient systems.
Some analysis methods for rotating systems with periodic coefficients
Dugundji, J.; Wendell, J. H.
1983-01-01
Two of the more common procedures for analyzing the stability and forced response of equations with periodic coefficients are reviewed: the use of Floquet methods, and the use of multiblade coordinate and harmonic balance methods. The analysis procedures of these periodic coefficient systems are compared with those of the more familiar constant coefficient systems. Previously announced in STAR as N82-23702
On some properties of SU(3) Fusion Coefficients
Coquereaux, Robert
2016-01-01
Three aspects of the SU(3) fusion coefficients are revisited: the generating polynomials of fusion coefficients are written explicitly; some curious identities generalizing the classical Freudenthal-de Vries formula are derived; and the properties of the fusion coefficients under conjugation of one of the factors, previously analysed in the classical case, are extended to the affine algebra of su(3) at finite level.
On the Occurrence of Standardized Regression Coefficients Greater than One.
Deegan, John, Jr.
1978-01-01
It is demonstrated here that standardized regression coefficients greater than one can legitimately occur. Furthermore, the relationship between the occurrence of such coefficients and the extent of multicollinearity present among the set of predictor variables in an equation is examined. Comments on the interpretation of these coefficients are…
Transport coefficients of a relativistic plasma
Pike, O. J.; Rose, S. J.
2016-05-01
In this work, a self-consistent transport theory for a relativistic plasma is developed. Using the notation of Braginskii [S. I. Braginskii, in Reviews of Plasma Physics, edited by M. A. Leontovich (Consultants Bureau, New York, 1965), Vol. 1, p. 174], we provide semianalytical forms of the electrical resistivity, thermoelectric, and thermal conductivity tensors for a Lorentzian plasma in a magnetic field. This treatment is then generalized to plasmas with arbitrary atomic number by numerically solving the linearized Boltzmann equation. The corresponding transport coefficients are fitted by rational functions in order to make them suitable for use in radiation-hydrodynamic simulations and transport calculations. Within the confines of linear transport theory and on the assumption that the plasma is optically thin, our results are valid for temperatures up to a few MeV. By contrast, classical transport theory begins to incur significant errors above kBT ˜10 keV, e.g., the parallel thermal conductivity is suppressed by 15% at kBT =20 keV due to relativistic effects.
Transport coefficients of He+ ions in helium
Johnsen, Rainer; Viehland, Larry; Gray, Benjamin; Wright, Timothy
2016-09-01
New experimental mobilities of 4He+ in 4He at 298.7 K, as a function of E/N, have been determined. Uncertainties in the mobilities were reduced to about 1% by using a shuttered drift tube. Comparison with previously measured values show that only one set of previous data is reliable. We demonstrate that the mobilities and diffusion coeffcients of 4He+ in 4He can be calculated over wide ranges of E/N with high precision if accurate potential energy curves are available for the X2Σu+ and A2Σg+ states, and if one takes into account resonant charge transfer and corrects for quantum-mechanical effects. Potentials, obtained by extrapolation of results from d-aug-cc-pVXZ (X =6,7) basis sets using the CASSCF +MRCISD approach were found to be in exceptionally close agreement with the best potentials available (separately) and with experiment, and those were subsequently used in a new computer program to determine semi-classical phase shifts and transport cross sections, from which the gaseous ion transport coefficients are determined. A new set of data for the mobilities of alpha particles (He2+) ions was obtained as a byproduct of the experiment, but the transport theory has not yet been completed.
Numerical integral of resistance coefficients in diffusion
Zhang, Q S
2016-01-01
The resistance coefficients in screen Coulomb potential of stellar plasma are evaluated in high accuracy. I have analyzed the possible singularities in the integral of scattering angle. There are possible singularities in the case of attractive potential. This may result in problem for numerical integral. In order to avoid the problem, I have used a proper scheme, e.g., splitting into many subintervals and the width of each subinterval is determined by the variation of the integrand, to calculate the scattering angle. The collision integrals are calculated by using Romberg's method therefore the accuracy is high (i.e., $ \\sim 10^{-12}$). The results of collision integrals and their derivatives in $-12 \\leq \\psi \\leq 5$ are listed. By using Hermite polynomial interpolation from those data, the collision integrals can be obtained with an accuracy of $10^{-10}$. For very weak coupled plasma ($\\psi \\geq 4.5$), analytical fittings for collision integrals are available with an accuracy of $10^{-11}$. I have compare...
Testing the Correlated Random Coefficient Model*
Heckman, James J.; Schmierer, Daniel; Urzua, Sergio
2010-01-01
The recent literature on instrumental variables (IV) features models in which agents sort into treatment status on the basis of gains from treatment as well as on baseline-pretreatment levels. Components of the gains known to the agents and acted on by them may not be known by the observing economist. Such models are called correlated random coe cient models. Sorting on unobserved components of gains complicates the interpretation of what IV estimates. This paper examines testable implications of the hypothesis that agents do not sort into treatment based on gains. In it, we develop new tests to gauge the empirical relevance of the correlated random coe cient model to examine whether the additional complications associated with it are required. We examine the power of the proposed tests. We derive a new representation of the variance of the instrumental variable estimator for the correlated random coefficient model. We apply the methods in this paper to the prototypical empirical problem of estimating the return to schooling and nd evidence of sorting into schooling based on unobserved components of gains. PMID:21057649
Backscatter coefficient estimation using tapers with gaps.
Luchies, Adam C; Oelze, Michael L
2015-04-01
When using the backscatter coefficient (BSC) to estimate quantitative ultrasound parameters such as the effective scatterer diameter (ESD) and the effective acoustic concentration (EAC), it is necessary to assume that the interrogated medium contains diffuse scatterers. Structures that invalidate this assumption can affect the estimated BSC parameters in terms of increased bias and variance and decrease performance when classifying disease. In this work, a method was developed to mitigate the effects of echoes from structures that invalidate the assumption of diffuse scattering, while preserving as much signal as possible for obtaining diffuse scatterer property estimates. Backscattered signal sections that contained nondiffuse signals were identified and a windowing technique was used to provide BSC estimates for diffuse echoes only. Experiments from physical phantoms were used to evaluate the effectiveness of the proposed BSC estimation methods. Tradeoffs associated with effective mitigation of specular scatterers and bias and variance introduced into the estimates were quantified. Analysis of the results suggested that discrete prolate spheroidal (PR) tapers with gaps provided the best performance for minimizing BSC error. Specifically, the mean square error for BSC between measured and theoretical had an average value of approximately 1.0 and 0.2 when using a Hanning taper and PR taper respectively, with six gaps. The BSC error due to amplitude bias was smallest for PR (Nω = 1) tapers. The BSC error due to shape bias was smallest for PR (Nω = 4) tapers. These results suggest using different taper types for estimating ESD versus EAC. © The Author(s) 2014.
Coefficient of Performance Enhancement of Refrigeration Cycles
Eng. Naser R. M. AL-Ajmi
2015-03-01
Full Text Available Refrigerator is one of the home appliance utilizing mechanical vapor compression cycle in its process. Performance of the systems become the main issue and many researches are still ongoing to evaluate and improve the efficiency of any used system. Therefore, this paper presents an experimental investigation of the performance of the refrigeration cycles. A small rrefrigerator is used as the test rig. The Coefficient of Performance (COP is studied by using different condenser designs and under varying evaporator loads. Three condenser designs are used in present work. These condensers are regular condenser of domestic refrigerator, condenser with copper plain tubes (Cond.1 and condenser with copper tubes welded with stainless steel flat plate (Cond.2. pressures and temperatures measurements of each point in the refrigeration cycle are collected in order to evaluate the refrigerator performance. The results showed that the average COP of Cond.1 and Cond.2 are increased up to 20 % and 14% respectively more than regular condenser design under no load. The evaporator load effects on the machine performance, where the COP of the machine increases with the increase of the evaporator load.
Pulmonary interstitial compliance and microvascular filtration coefficient.
Goldberg, H S
1980-08-01
Static and dynamic properties governing the fluid movement into the pulmonary interstitium were examined in isolated canine lobes. The system was driven by altering intravascular presure (Piv) when the lobe was isogravimetric (change in weight (W) = 0) and allowing the lobe to become isogravimetric again. By making use of an analogy to charging a capacitor across a resistor, calculation of the filtration coefficient for transvascular fluid movement (KF) and determination of the pressure-volume relationship of the pulmonary interstitial space (Pis-Vis), with a minimum of untested assumptions, was possible. KF was found to be the same for fluid moving out of or into the intravascular space, and when the relationship between Piv and alveolar pressure (PAlv) was constant, KF was independent of transpulmonary pressure (PL). When PAlv exceeded Piv, changes in Piv did not influence KF, suggesting no significant change in either surface area available for fluid transudation or vascular permeability. The Pis-Vis curve for increasing values of Vis and Pis is best described by an exponential relationhip and is independent of PL. However, the Pis-Vis curve with decreasing values of Vis and Pis is dependent on PL.
Attenuation coefficients for water quality trading.
Keller, Arturo A; Chen, Xiaoli; Fox, Jessica; Fulda, Matt; Dorsey, Rebecca; Seapy, Briana; Glenday, Julia; Bray, Erin
2014-06-17
Water quality trading has been proposed as a cost-effective approach for reducing nutrient loads through credit generation from agricultural or point source reductions sold to buyers facing costly options. We present a systematic approach to determine attenuation coefficients and their uncertainty. Using a process-based model, we determine attenuation with safety margins at many watersheds for total nitrogen (TN) and total phosphorus (TP) loads as they transport from point of load reduction to the credit buyer. TN and TP in-stream attenuation generally increases with decreasing mean river flow; smaller rivers in the modeled region of the Ohio River Basin had TN attenuation factors per km, including safety margins, of 0.19-1.6%, medium rivers of 0.14-1.2%, large rivers of 0.13-1.1%, and very large rivers of 0.04-0.42%. Attenuation in ditches transporting nutrients from farms to receiving rivers is 0.4%/km for TN, while for TP attenuation in ditches can be up to 2%/km. A 95 percentile safety margin of 30-40% for TN and 6-10% for TP, applied to the attenuation per km factors, was determined from the in-stream sensitivity of load reductions to watershed model parameters. For perspective, over 50 km a 1% per km factor would result in 50% attenuation = 2:1 trading ratio.
Sedimentation coefficient distributions of large particles.
Schuck, Peter
2016-07-21
The spatial and temporal evolution of concentration boundaries in sedimentation velocity analytical ultracentrifugation reports on the size distribution of particles with high hydrodynamic resolution. For large particles such as large protein complexes, fibrils, viral particles, or nanoparticles, sedimentation conditions usually allow migration from diffusion to be neglected relative to sedimentation. In this case, the shape of the sedimentation boundaries of polydisperse mixtures relates directly to the underlying size-distributions. Integral and derivative methods for calculating sedimentation coefficient distributions g*(s) of large particles from experimental boundary profiles have been developed previously, and are recapitulated here in a common theoretical framework. This leads to a previously unrecognized relationship between g*(s) and the time-derivative of concentration profiles. Of closed analytical form, it is analogous to the well-known Bridgman relationship for the radial derivative. It provides a quantitative description of the effect of substituting the time-derivative by scan differences with finite time intervals, which appears as a skewed box average of the true distribution. This helps to theoretically clarify the differences between results from time-derivative method and the approach of directly fitting the integral definition of g*(s) to the entirety of experimental boundary data.
Modeling Complex System Correlation Using Detrended Cross-Correlation Coefficient
Keqiang Dong
2014-01-01
Full Text Available The understanding of complex systems has become an area of active research for physicists because such systems exhibit interesting dynamical properties such as scale invariance, volatility correlation, heavy tails, and fractality. We here focus on traffic dynamic as an example of a complex system. By applying the detrended cross-correlation coefficient method to traffic time series, we find that the traffic fluctuation time series may exhibit cross-correlation characteristic. Further, we show that two traffic speed time series derived from adjacent sections exhibit much stronger cross-correlations than the two speed series derived from adjacent lanes. Similarly, we also demonstrate that the cross-correlation property between the traffic volume variables from two adjacent sections is stronger than the cross-correlation property between the volume variables of adjacent lanes.
Coefficient estimates of negative powers and inverse coefficients for certain starlike functions
MD FIROZ ALI; A VASUDEVARAO
2017-06-01
For −1 $\\leq B < A \\leq 1$, let $S^{\\ast}(A,B)$ denote the class of normalized analytic functions $f(z) = z+\\sum^{\\infty}_{n=2}a_{n}z^{n}$ in $\\mid z\\mid <1$ which satisfy the subordination relation $zf'(z)/f(z)\\prec(1+Az)/(1+Bz)$ and $\\sum^{\\ast}(A,B)$ be the corresponding class of meromorphic functions in $\\mid z\\mid > 1$. For $f \\in S^{\\ast}(A,B)$ and $\\lambda > 0$, we shall estimate the absolute value of the Taylor coefficients $a_{n}(−\\lambda,f )$ of the analytic function $(f(z)/z)^{−\\lambda}$. Using this we shall determine the coefficient estimate for inverses of functions in the classes $S^{\\ast}(A,B)$ and $\\sum^{\\ast}(A,B)$.
Gülfen TUNA
2013-03-01
Full Text Available The aim of this study is to test the validity of Downside Capital Asset Pricing Model (D-CAPM on the ISE. At the same time, the explanatory power of CAPM's traditional beta and D-CAPM's downside beta on the changes in the average return values are examined comparatively. In this context, the monthly data for seventy three stocks that are continuously traded on the ISE for the period 1991-2009 is used. Regression analysis is applied in this study. The research results have shown that D-CAPM is valid on the ISE. In addition, it is obtained that the power of downside beta coefficient is higher than traditional beta coefficient on explaining the return changes. Therefore, it can be said that the downside beta is superior to traditional beta in the ISE for chosen period.
Aerosol hygroscopic growth parameterization based on a solute specific coefficient
Metzger, S.; Steil, B.; Xu, L.; Penner, J. E.; Lelieveld, J.
2011-09-01
Water is a main component of atmospheric aerosols and its amount depends on the particle chemical composition. We introduce a new parameterization for the aerosol hygroscopic growth factor (HGF), based on an empirical relation between water activity (aw) and solute molality (μs) through a single solute specific coefficient νi. Three main advantages are: (1) wide applicability, (2) simplicity and (3) analytical nature. (1) Our approach considers the Kelvin effect and covers ideal solutions at large relative humidity (RH), including CCN activation, as well as concentrated solutions with high ionic strength at low RH such as the relative humidity of deliquescence (RHD). (2) A single νi coefficient suffices to parameterize the HGF for a wide range of particle sizes, from nanometer nucleation mode to micrometer coarse mode particles. (3) In contrast to previous methods, our analytical aw parameterization depends not only on a linear correction factor for the solute molality, instead νi also appears in the exponent in form x · ax. According to our findings, νi can be assumed constant for the entire aw range (0-1). Thus, the νi based method is computationally efficient. In this work we focus on single solute solutions, where νi is pre-determined with the bisection method from our analytical equations using RHD measurements and the saturation molality μssat. The computed aerosol HGF and supersaturation (Köhler-theory) compare well with the results of the thermodynamic reference model E-AIM for the key compounds NaCl and (NH4)2SO4 relevant for CCN modeling and calibration studies. The equations introduced here provide the basis of our revised gas-liquid-solid partitioning model, i.e. version 4 of the EQuilibrium Simplified Aerosol Model (EQSAM4), described in a companion paper.
谢培培; 李淑妮; 翟全国; 蒋育澄; 胡满成
2013-01-01
Activity coefficients of the ternary system (CsBr + NaBr + H2O) were determined by electromotive force (EMF) measurements using the cell: Cs-ion selective electrode(ISE) | CsBr (mA), NaBr (mB) | Br-ion selective electrode (ISE) at 298. 15 K, and over total ionic strengths from range 0. 01 to 1. 0 mol/kg for different ionic strength fractions (0. 25, 0. 5 and 0. 75). The experimental data were satisfactorily described via the Pitzer and Harned models. The Pitzer binary and ternary ionic interaction parameters and the Harned parameters have also been calculated.%采用电池Cs-ISE | CsBr(mA),NaBr (mB)| Br-ISE测定了298.15 K温度下CsBr+NaBr+H2O体系在离子强度I=0.01～1.00 mol/kg范围内,离子强度分数yB=0,0.25,0.50和0.75时的电动势,实验结果分别用Pitzer方程和Harned经验公式进行拟合,得到该体系的Pitzer二离子、三离子相互作用参数和Harned参数.拟合结果表明,Pitzer方程和Harned经验公式均能理想地适用于该三元盐水体系.
Continuous and robust clustering coefficients for weighted and directed networks
Miyajima, Kent
2014-01-01
We introduce new clustering coefficients for weighted networks. They are continuous and robust against edge weight changes. Recently, generalized clustering coefficients for weighted and directed networks have been proposed. These generalizations have a common property, that their values are not continuous. They are sensitive with edge weight changes, especially at zero weight. With these generalizations, if vanishingly low weights of edges are truncated to weight zero for some reason, the coefficient value may change significantly from the original value. It is preferable that small changes of edge weights cause small changes of coefficient value. We call this property the continuity of generalized clustering coefficients. Our new coefficients admit this property. In the past, few studies have focused on the continuity of generalized clustering coefficients. In experiments, we performed comparative assessments of existing and our generalizations. In the case of a real world network dataset (C. Elegans Neural...
A generalized concordance correlation coefficient for continuous and categorical data.
King, T S; Chinchilli, V M
2001-07-30
This paper discusses a generalized version of the concordance correlation coefficient for agreement data. The concordance correlation coefficient evaluates the accuracy and precision between two measures, and is based on the expected value of the squared function of distance. We have generalized this coefficient by applying alternative functions of distance to produce more robust versions of the concordance correlation coefficient. In this paper we extend the application of this class of estimators to categorical data as well, and demonstrate similarities to the kappa and weighted kappa statistics. We also introduce a stratified concordance correlation coefficient which adjusts for explanatory factors, and an extended concordance correlation coefficient which measures agreement among more than two responses. With these extensions, the generalized concordance correlation coefficient provides a unifying approach to assessing agreement among two or more measures that are either continuous or categorical in scale.
Methods for Accurate Free Flight Measurement of Drag Coefficients
Courtney, Elya; Courtney, Michael
2015-01-01
This paper describes experimental methods for free flight measurement of drag coefficients to an accuracy of approximately 1%. There are two main methods of determining free flight drag coefficients, or equivalent ballistic coefficients: 1) measuring near and far velocities over a known distance and 2) measuring a near velocity and time of flight over a known distance. Atmospheric conditions must also be known and nearly constant over the flight path. A number of tradeoffs are important when designing experiments to accurately determine drag coefficients. The flight distance must be large enough so that the projectile's loss of velocity is significant compared with its initial velocity and much larger than the uncertainty in the near and/or far velocity measurements. On the other hand, since drag coefficients and ballistic coefficients both depend on velocity, the change in velocity over the flight path should be small enough that the average drag coefficient over the path (which is what is really determined)...
Changes in Electrokinetic Coupling Coefficients of Granite under Triaxial Deformation
Osamu Kuwano
2012-01-01
Full Text Available Electrokinetic phenomena are believed to be the most likely origin of electromagnetic signals preceding or accompanying earthquakes. The intensity of the source current due to the electrokinetic phenomena is determined by the fluid flux and the electrokinetic coupling coefficient called streaming current coefficient; therefore, how the coefficient changes before rupture is essential. Here, we show how the electrokinetic coefficients change during the rock deformation experiment up to failure. The streaming current coefficient did not increase before failure, but continued to decrease up to failure, which is explained in terms of the elastic closure of capillary. On the other hand, the streaming potential coefficient, which is the product of the streaming current coefficient and bulk resistivity of the rock, increased at the onset of dilatancy. It may be due to change in bulk resistivity. Our result indicates that the zeta potential of the newly created surface does not change so much from that of the preexisting fluid rock interface.
Temperature-Dependent Diffusion Coefficients from ab initio Computations: Hydrogen in Nickel
E Wimmer; W Wolf; J Sticht; P Saxe; C Geller; R Najafabadi; G Young
2006-03-16
The temperature-dependent mass diffusion coefficient is computed using transition state theory. Ab initio supercell phonon calculations of the entire system provide the attempt frequency, the activation enthalpy, and the activation entropy as a function of temperature. Effects due to thermal lattice expansion are included and found to be significant. Numerical results for the case of hydrogen in nickel demonstrate a strong temperature dependence of the migration enthalpy and entropy. Trapping in local minima along the diffusion path has a pronounced effect especially at low temperatures. The computed diffusion coefficients with and without trapping bracket the available experimental values over the entire temperature range between 0 and 1400 K.
Review on cation exchange selectivity coefficients for MX-80 bentonite
Domenech, C.; Arcos, D.; Duro, L. [ENVIROS, Passeig de Rubi, 29-31, 08197 Valldoreix (Spain); Sellin, P. [SKB, Brahegatan 47, SE-102 40 Stockholm (Sweden)
2005-07-01
Full text of publication follows: Bentonite is considered as engineered barrier in the near field of a nuclear waste repository due to its low permeability, what impedes groundwater flow to the nuclear waste, and its high retention capacity (sorption) of radionuclides in the eventuality of groundwater intrusion. One of the main retention processes occurring at the bentonite surface is ion exchange. This process may exert a strong control on the mobility of major pore water cations. Changes in major cation concentration, especially calcium, can affect the dissolution-precipitation of calcite, which in turn controls one of the key parameters in the system: pH. The cation exchange process is usually described according to the Gaines-Thomas convention: Ca{sup 2+} + 2 NaX = CaX{sub 2} + 2 Na{sup +}, K{sub Ca} = (N{sub Ca} x a{sup 2}{sub Na{sup +}})/(N{sup 2}{sub Na} x a{sub Ca{sup 2+}}) where K{sub Ca} is the selectivity coefficient for the Ca by Na exchange, ai is the activity of cation 'i' in solution and NJ the equivalent fractional occupancy of cation 'J' in bentonite. Parameters such as solid to liquid (S:L) ratio and dry density of the solid have an important influence on the value of selectivity coefficients (K{sub ex}). Although in most geochemical modelling works, K{sub ex} values are directly taken from experiments conducted at low S:L ratios and low dry densities, the expected conditions in a deep geological nuclear waste repository are higher S:L and higher bentonite density (1.6 g.cm{sup -3} in the SKB design to obtain a fully water saturated density of around 2.0 g.cm{sup -3}). Experiments focused at obtaining selectivity coefficients under the conditions of interest face the difficulty of achieving a proper extraction and analyses of pore water without disturbing the system by the sampling method itself. In this work we have conducted a complete analyses of published data on MX-80 bentonite cationic exchange in order to assess the
Effective dose conversion coefficients for radionuclides exponentially distributed in the ground
Saito, Kimiaki [Japan Atomic Energy Agency, Tokyo (Japan); Ishigure, Nobuhito [Nagoya University, Graduate School of Medicine, Nagoya City (Japan); Petoussi-Henss, Nina; Schlattl, Helmut [Helmholtz Zentrum Muenchen-German Research Center for Environmental Health, Department of Radiation Physics and Diagnostics, Neuherberg (Germany)
2012-11-15
In order to provide fundamental data required for dose evaluation due to environmental exposures, effective dose conversion coefficients, that is, the effective dose rate per unit activity per unit area, were calculated for a number of potentially important radionuclides, assuming an exponential distribution in ground, over a wide range of relaxation depths. The conversion coefficients were calculated for adults and a new-born baby on the basis of dosimetric methods that the authors and related researchers have previously developed, using Monte Carlo simulations and anthropomorphic computational phantoms. The differences in effective dose conversion coefficients due to body size between the adult and baby phantoms were found to lie within 50 %, for most cases; however, for some low energies, differences could amount to a factor of 3. The effective dose per unit source intensity per area was found to decrease by a factor of 2-5, for increasing relaxation depths from 0 to 5 g/cm{sup 2}, above a source energy of 50 keV. It is also shown that implementation of the calculated coefficients into the computation of the tissue weighting factors and the adult reference computational phantoms of ICRP Publication 103 does not significantly influence the effective dose conversion coefficients of the environment. Consequently, the coefficients shown in this paper could be applied for the evaluation of effective doses, as defined according to both recommendations of ICRP Publications 103 and 60. (orig.)
Roughness coefficient and its uncertainty in gravel-bed river
Ji-Sung KIM; Chan-Joo LEE; Won KIM; Yong-Jeon KIM
2010-01-01
Manning's roughness coefficient was estimated for a gravel-bed river reach using field measurements of water level and discharge,and the applicability of various methods used for estimation of the roughness coefficient was evaluated.Results show that the roughness coefficient tends to decrease with increasing discharge and water depth,and over a certain range it appears to remain constant.Comparison of roughness coefficients calculated by field measurement data with those estimated by other methods shows that,although the field-measured values provide approximate roughness coefficients for relatively large discharge,there seems to be rather high uncertainty due to the difference in resultant values.For this reason,uncertainty related to the roughness coefficient was analyzed in terms of change in computed variables.On average,a 20%increase of the roughness coefficient causes a 7% increase in the water depth and an 8% decrease in velocity,but there may be about a 15% increase in the water depth and an equivalent decrease in velocity for certain cross-sections in the study reach.Finally,the validity of estimated roughness coefficient based on field measurements was examined.A 10% error in discharge measurement may lead to more than 10% uncertainty in roughness coefficient estimation,but corresponding uncertainty in computed water depth and velocity is reduced to approximately 5%.Conversely,the necessity for roughness coefficient estimation by field measurement is confirmed.
Jeong, Cheol-Ho; Ih, Jeong-Guon; Rindel, Jens Holger
2005-01-01
the measured surface impedance. However, it is not always possible to get the measured impedance data of the surface, so that a practical way of getting reflection characteristics is needed. Generally, in the architectural acoustics field, the absorption coefficients have been employed in the calculations......The phased beam tracing method (PBTM) is a technique which can calculate the pressure impulse response instead of energy impulse response, by taking the phase information into account. Inclusion of the phase information can extend the application of beam tracing technique to the mid frequency range...
A dynamic coefficient polynomial predistorter based on direct learning architecture
Li Bo; Ge Jianhua; Ai Bo
2008-01-01
A dynamic coefficient polynomial predistorter based on direct learning architecture is proposed. Compared to the existing polynomial predistorter, on the one hand, the proposed predistorter based on the direct learning architecture is more robust to initial conditions of the tap coefficients than that based on indirect learning architecture; on the other hand, by using two polynomial coefficient combinations, different polynomial coefficient combination can be selected when the input signal amplitude changes, which effectively decreases the estimate error. This paper introduces the direct learning architecture and gives the dynamic coefficient polynomial expression. A simplified nonlinear recursive least-squares (RLS) algorithm for polynomial coefficient estimation is also derived in detail. Computer simulations show that the proposed predistorter can attain 31dB, 28dB and 40dB spectrum suppression gain when our method is applied to the traveling wave tube amplifier (TWTA), solid state power amplifier (SSPA) and polynomial power amplifier (PA) model, respectively.
Fusion of Daubechies Wavelet Coefficients for Human Face Recognition
Bhowmik, Mrinal Kanti; Nasipuri, Mita; Basu, Dipak Kumar; Kundu, Mahantapas
2010-01-01
In this paper fusion of visual and thermal images in wavelet transformed domain has been presented. Here, Daubechies wavelet transform, called as D2, coefficients from visual and corresponding coefficients computed in the same manner from thermal images are combined to get fused coefficients. After decomposition up to fifth level (Level 5) fusion of coefficients is done. Inverse Daubechies wavelet transform of those coefficients gives us fused face images. The main advantage of using wavelet transform is that it is well-suited to manage different image resolution and allows the image decomposition in different kinds of coefficients, while preserving the image information. Fused images thus found are passed through Principal Component Analysis (PCA) for reduction of dimensions and then those reduced fused images are classified using a multi-layer perceptron. For experiments IRIS Thermal/Visual Face Database was used. Experimental results show that the performance of the approach presented here achieves maximum...
Piezo-optic coefficients of CaWO4 crystals
Mytsyk, B. G.; Kost', Ya. P.; Demyanyshyn, N. M.; Andrushchak, A. S.; Solskii, I. M.
2015-01-01
All components of the piezo-optic coefficient matrix of calcium tungstate crystals, belonging to the 4/ m symmetry class, are determined. The reliability of the piezo-optic effect measurements in CaWO4 crystals is achieved by determining each piezo-optic coefficient from several experimental geometries and is also based on the correlation of the absolute piezo-electric coefficients and the path-difference coefficients. The rotation-shear diagonal coefficients π44 and π66 and three principal piezo-optic coefficients π11, π13, and π31 are refined by the polarization-optical method. It is confirmed that both the interferometric and polarization-optical methods should be used to study the piezo-optic effect with high accuracy. The results show that calcium tungstate is a promising material for acousto-optical and photoelastic modulation.
Modified Regression Correlation Coefficient for Poisson Regression Model
Kaengthong, Nattacha; Domthong, Uthumporn
2017-09-01
This study gives attention to indicators in predictive power of the Generalized Linear Model (GLM) which are widely used; however, often having some restrictions. We are interested in regression correlation coefficient for a Poisson regression model. This is a measure of predictive power, and defined by the relationship between the dependent variable (Y) and the expected value of the dependent variable given the independent variables [E(Y|X)] for the Poisson regression model. The dependent variable is distributed as Poisson. The purpose of this research was modifying regression correlation coefficient for Poisson regression model. We also compare the proposed modified regression correlation coefficient with the traditional regression correlation coefficient in the case of two or more independent variables, and having multicollinearity in independent variables. The result shows that the proposed regression correlation coefficient is better than the traditional regression correlation coefficient based on Bias and the Root Mean Square Error (RMSE).
Calculation of transport coefficients in an axisymmetric plasma
Shumaker, D.E.
1977-01-01
A method of calculating the transport coefficient in an axisymmetric toroidal plasma is presented. This method is useful in calculating the transport coefficients in a Tokamak plasma confinement device. The particle density and temperature are shown to be a constant on a magnetic flux surface. Transport equations are given for the total particle flux and total energy flux crossing a closed toroidal surface. Also transport equations are given for the toroidal magnetic flux. A computer code was written to calculate the transport coefficients for a three species plasma, electrons and two species of ions. This is useful for calculating the transport coefficients of a plasma which contains impurities. It was found that the particle and energy transport coefficients are increased by a large amount, and the transport coefficients for the toroidal magnetic field are reduced by a small amount.
EXACT SAMPLING DISTRIBUTION OF SAMPLE COEFFICIENT OF VARIATION
Dr.G.S.David Sam Jayakumar
2015-06-01
Full Text Available This paper proposes the sampling distribution of sample coefficient of variation from the normal population. We have derived the relationship between the sample coefficient of variation, standard normal and chi-square variate. We have derived density function of the sample coefficient of variation in terms of the confluent hyper-geometric distribution. Moreover, the first two moments of the distribution are derived and we have proved that the sample coefficient of variation (cv is the biased estimator of the population coefficient of variation (CV. Moreover, the shape of the density function of sample co-efficient of variation is also visualized and the critical points of sample (cv at 5% and 1% level of significance for different sample sizes have also been computed.
Linjun, Xie, E-mail: linjunx@zjut.edu.cn [College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou 310014 (China); Guohong, Xue; Ming, Zhang [Shanghai Nuclear Engineering Research & Design Institute, Shanghai 200233 (China)
2016-08-01
Graphical abstract: HDS stress coefficient test apparatus. - Highlights: • This paper performs mathematic deduction to the physical model of Hold Down Spring (HDS), establishes a mathematic model of axial load P and stress, stress coefficient and friction coefficient and designs a set of test apparatuses for simulating the pretightening process of the HDS for the first time according to a model similarity criterion. • The mathematical relation between the load and the strain is obtained about the HDS, and the mathematical model of the stress coefficient and the friction coefficient is established. So, a set of test apparatuses for obtaining the stress coefficient is designed according to the model scaling criterion and the friction coefficient of the K1000 HDS is calculated to be 0.336 through the obtained stress coefficient. • The relation curve between the theoretical load and the friction coefficient is obtained through analysis and indicates that the change of the friction coefficient f would influence the pretightening load under the condition of designed stress. The necessary pretightening load in the design process is calculated to be 5469 kN according to the obtained friction coefficient. Therefore, the friction coefficient and the pretightening load under the design conditions can provide accurate pretightening data for the analysis and design of the reactor HDS according to the operations. - Abstract: This paper performs mathematic deduction to the physical model of Hold Down Spring (HDS), establishes a mathematic model of axial load P and stress, stress coefficient and friction coefficient and designs a set of test apparatuses for simulating the pretightening process of the HDS for the first time according to a model similarity criterion. By carrying out tests and researches through a stress testing technique, P–σ curves in loading and unloading processes of the HDS are obtained and the stress coefficient k{sub f} of the HDS is obtained. So, the
The Frictional Coefficient of Bovine Knee Articular Cartilage
Qian Shan-hua; Ge Shi-rong; Wang Qing-liang
2006-01-01
The normal displacement of articular cartilage was measured under load and in sliding, and the coefficient of friction during sliding was measured using a UMT-2 Multi-Specimen Test System. The maximum normal displacement under load and the start-up frictional coefficient have similar tendency of variation with loading time. The sliding speed does not significantly influence the frictional coefficient of articular cartilage.
DCFPAK: Dose coefficient data file package for Sandia National Laboratory
Eckerman, K.F.; Leggett, R.W.
1996-07-31
The FORTRAN-based computer package DCFPAK (Dose Coefficient File Package) has been developed to provide electronic access to the dose coefficient data files summarized in Federal Guidance Reports 11 and 12. DCFPAK also provides access to standard information regarding decay chains and assembles dose coefficients for all dosimetrically significant radioactive progeny of a specified radionuclide. DCFPAK was designed for application on a PC but, with minor modifications, may be implemented on a UNIX workstation.
Table for constructing the spin coefficients in general relativity
Cocke, W. J.
1989-07-15
The spin coefficients in spinor calculus in Riemannian space-time are linear functions of the curls of the connecting quantities (the Infeld--Van der Waerden symbols). We show that in the Newman-Penrose formalism the expressions for the spin coefficients are quite manageable, if they are written in terms of the Newman-Penrose tetrad vectors. We present a table of the components of the spin coefficients explicitly in terms of the curls of the individual tetrad vectors.
Scanning measurement of Seebeck coefficient of a heated sample
Snyder, G. Jeffrey; Iwanaga, Shiho
2016-04-19
A novel scanning Seebeck coefficient measurement technique is disclosed utilizing a cold scanning thermocouple probe tip on heated bulk and thin film samples. The system measures variations in the Seebeck coefficient within the samples. The apparatus may be used for two dimensional mapping of the Seebeck coefficient on the bulk and thin film samples. This technique can be utilized for detection of defective regions, as well as phase separations in the sub-mm range of various thermoelectric materials.
Spatial Correlation Coefficient Images for Ultrasonic Detection (Preprint)
2006-07-01
for image formation and detection based on the similarity of adjacent signals. Signal similarity is quantified in terms of the correlation coefficient calculated...between A-scans digitized at adjacent measurement positions. Correlation coefficient images are introduced for visualizing the similarity...beam field with the defect. Correlation coefficient and C-scan images are shown to demonstrate flat-bottom-hole detection in a stainless steel annular
Wavelet Correlation Coefficient of 'strongly correlated' financial time series
Ashok Razdan
2003-01-01
In this paper we use wavelet concepts to show that correlation coefficient between two financial data's is not constant but varies with scale from high correlation value to strongly anti-correlation value This studies is important because correlation coefficient is used to quantify degree of independence between two variables. In econophysics correlation coefficient forms important input to evolve hierarchial tree and minimum spanning tree of financial data.
ON TESTING THE EQUALITY OF K MULTIPLEAND PARTIAL CORRELATION COEFFICIENTS
无
2001-01-01
Coutsourides (1980) derives an ad hoc nuisance parameter removal test for testing the equality of two multiple correlation coefficients of two independent p variate normal populations, under the assumption that a sample of size n is available from each population. He also extends his ad hoc nuisance parameter removal test to the testing of the equality of two multiple correlation matrices. This paper presents likelihood ratio tests for testing the equality of k multiple correlation coefficients, and also k partial correlation coefficients.
Photo-ionization rate coefficients for the rare gases
Pang, Xuexia
2005-01-01
By introducing the converting method from electron-impact ionization cross sections to rate coefficients through using a semi-experiential formula, we try to probe a semi-experiential formula for converting the photo-ionization cross sections into photo-ionization rate coefficient. It"s found that photo-ionization rate coefficient is direct proportion to photo-ionization cross sections, the rate S is related with light resource.
Refinement of Fourier Coefficients from the Stokes Deconvoluted Profile
无
2002-01-01
Computer-aided experimental technique was used to study the Stokes deconvolution of X-ray diffraction profile.Considerable difference can be found between the Fourier coefficients obtained from the deconvolutions of singlet and doublet experimental profiles. Nevertheless, the resultant physical profiles corresponding to singlet and doublet profiles are identical. An approach is proposed to refine the Fourier coefficients, and the refined Fourier coefficients coincide well with that obtained from the deconvolution of singlet experimental profile.
On some properties of SU(3 fusion coefficients
Robert Coquereaux
2016-11-01
Full Text Available Three aspects of the SU(3 fusion coefficients are revisited: the generating polynomials of fusion coefficients are written explicitly; some curious identities generalizing the classical Freudenthal–de Vries formula are derived; and the properties of the fusion coefficients under conjugation of one of the factors, previously analyzed in the classical case, are extended to the affine algebra suˆ(3 at finite level.
Liu, Cong; Kolarik, Barbara; Gunnarsen, Lars; Zhang, Yinping
2015-10-20
Polychlorinated biphenyls (PCBs) have been found to be persistent in the environment and possibly harmful. Many buildings are characterized with high PCB concentrations. Knowledge about partitioning between primary sources and building materials is critical for exposure assessment and practical remediation of PCB contamination. This study develops a C-depth method to determine diffusion coefficient (D) and partition coefficient (K), two key parameters governing the partitioning process. For concrete, a primary material studied here, relative standard deviations of results among five data sets are 5%-22% for K and 42-66% for D. Compared with existing methods, C-depth method overcomes the inability to obtain unique estimation for nonlinear regression and does not require assumed correlations for D and K among congeners. Comparison with a more sophisticated two-term approach implies significant uncertainty for D, and smaller uncertainty for K. However, considering uncertainties associated with sampling and chemical analysis, and impact of environmental factors, the results are acceptable for engineering applications. This was supported by good agreement between model prediction and measurement. Sensitivity analysis indicated that effective diffusion distance, contacting time of materials with primary sources, and depth of measured concentrations are critical for determining D, and PCB concentration in primary sources is critical for K.
Akataki, K; Mita, K; Itoh, Y
1999-01-01
The within-day and between-day repeatability of the mechanomyogram (MMG) was assessed using the coefficient of variation (CV) and the intraclass correlation coefficient (ICC) and was compared with that of the electromyogram (EMG). The MMG and EMG were recorded simultaneously during isometric elbow flexion trials at different submaximal levels of 10% to 90% MVC. The testing session consisting of 9 submaximal trials was repeated 8 times on the same day for estimation of the within-day variation. In order to examine the between-day variation, the same testing session was also performed 8 times over 3 weeks with a 2-day rest interval between each session. The CVs within-day and between-day in both the MMG and EMG did not demonstrate any significant differences relating to the magnitude of force exerted. The CVs combined over all the force levels were approximately 10% within the same day and 25% between days for both the MMG and EMG. These corresponded to the within-day ICC of approximately 0.95 and the between-day ICC of 0.80. The repeatability of the MMG during submaximal isometric contractions of biceps brachii muscles is considered to be similar to that of the more established EMG.
Taylor coefficients and coefficient multipliers of Hardy and Bergman-type spaces
Jevtić, Miroljub; Arsenović, Miloš
2016-01-01
This book provides a systematic overview of the theory of Taylor coefficients of functions in some classical spaces of analytic functions and especially of the coefficient multipliers between spaces of Hardy type. Offering a comprehensive reference guide to the subject, it is the first of its kind in this area. After several introductory chapters covering the basic material, a large variety of results obtained over the past 80 years, including the most recent ones, are treated in detail. Several chapters end with discussions of practical applications and related topics that graduate students and experts in other subjects may find useful for their own purposes. Thus, a further aim of the book is to communicate to non-specialists some concrete facts that may be of value in their own work. The book can also be used as a textbook or a supplementary reference for an advanced graduate course. It is primarily intended for specialists in complex and functional analysis, graduate students, and experts in other related...
Consideration on Singularities in Learning Theory and the Learning Coefficient
Miki Aoyagi
2013-09-01
Full Text Available We consider the learning coefficients in learning theory and give two new methods for obtaining these coefficients in a homogeneous case: a method for finding a deepest singular point and a method to add variables. In application to Vandermonde matrix-type singularities, we show that these methods are effective. The learning coefficient of the generalization error in Bayesian estimation serves to measure the learning efficiency in singular learning models. Mathematically, the learning coefficient corresponds to a real log canonical threshold of singularities for the Kullback functions (relative entropy in learning theory.
Improvement of Similarity Measure： Pearson Product-Moment Correlation Coefficient
LIUYong-suo; MENGQing-hua; CHENRong; WANGJian-song; JIANGShu-min; HUYu-zhu
2004-01-01
Aim To study the reason of the insensitiveness of Pearson preduct-moment correlation coefficient as a similarity measure and the method to improve its sensitivity. Methods Experimental and simulated data sets were used. Results The distribution range of the data sets influences the sensitivity of Pearson product-moment correlation coefficient. Weighted Pearson product-moment correlation coefficient is more sensitive when the range of the data set is large. Conclusion Weighted Pearson product-moment correlation coefficient is necessary when the range of the data set is large.
Correlation Degree and Correlation Coefficient of Multi- Output Functions
JU Gui-zhi; ZHAO Ya-qun
2005-01-01
We present definitions of the correlation degree and correlation coefficient of multi-output functions. Two relationships about the correlation degree of multi-output functions are proved. One is between the correlation degree and independency,the other is between the correlation degree and balance. Especially the paper discusses the correlation degree of affine multioutput functions. We demonstrate properties of the correlation coefficient of multi-output functions. One is the value range of the correlation coefficient, one is the relationship between the correlation coefficient and independency, and another is the sufficient and necessary condition that two multi-output functions are equivalent to each other.
Classification of coefficients of variation in experiments with commercial layers
DE Faria Filho
2010-12-01
Full Text Available This study aimed at determining a specific classification of coefficients of variation in experiments with commercial layers. Coefficients of variation were collected from papers published in Brazilian journals between 2000 and 2009 for performance, internal egg quality, and eggshell quality parameters. The coefficients of variation of each parameter were classified as low, intermediate, high, and very high according to the ratio between the median and the pseudo-sigma. It was concluded that the parameters used in experiments with commercial layers have a specific classification of coefficients of variation, and that this must be considered to evaluate experimental accuracy.
Influence of Dynamical Change of Edges on Clustering Coefficients
Yuhong Ruan
2015-01-01
Full Text Available Clustering coefficient is a very important measurement in complex networks, and it describes the average ratio between the actual existent edges and probable existent edges in the neighbor of one vertex in a complex network. Besides, in a complex networks, the dynamic change of edges can trigger directly the evolution of network and further affect the clustering coefficients. As a result, in this paper, we investigate the effects of the dynamic change of edge on the clustering coefficients. It is illustrated that the increase and decrease of the clustering coefficient can be effectively controlled by adding or deleting several edges of the network in the evolution of complex networks.
Diffusion coefficient of three-dimensional Yukawa liquids
Dzhumagulova, K. N.; Ramazanov, T. S.; Masheeva, R. U. [IETP, Al Farabi Kazakh National University, 71, al Farabi ave., Almaty 050040 (Kazakhstan)
2013-11-15
The purpose of this work is an investigation of the diffusion coefficient of the dust component in complex plasma. The computer simulation of the Yukawa liquids was made on the basis of the Langevin equation, which takes into account the influence of buffer plasma on the dust particles dynamics. The Green–Kubo relation was used to calculate the diffusion coefficient. Calculations of the diffusion coefficient for a wide range of the system parameters were performed. Using obtained numerical data, we constructed the interpolation formula for the diffusion coefficient. We also show that the interpolation formula correctly describes experimental data obtained under microgravity conditions.
Spielmann, V.; Li, W.B.; Zankl, M.; Oeh, U.
2015-11-15
The dose coefficients used in nuclear medicine for dose calculations of radiopharmaceuticals are based on recommendations by ICRP (International Commission on radiological protection) and the MIRD (Medical Internal Radiation Dose Committee) using mathematical models for the temporal activity distributions in organs and tissues (biokinetic models) and mathematical models of the human body. These models using an idealized human body do not include uncertainty estimations. The research project is aimed to determine the uncertainties and thus the reliability of the dose coefficients for radiopharmaceuticals and to identify the biokinetic and dosimetric parameters that contribute most of the uncertainties.
Road Friction Coefficient Real-Time Identification Based on the Tire Dynamic Friction Model
FAN Xiao-bin; DENG Pan; JIANG Yu; FAN Bing-xu
2013-01-01
Road friction coefficient real-time estimation methods is an important issue and problem in automotive active safety con-trol system development. First a fixed feedback gain sliding mode observer of road adhesion coefficient is designed through the es-tablishment of tire/road dynamic friction model in this article. The simulation results shows that the observer can well real-time iden-tify the current road adhesion characteristics. And more importantly, the observer only need wheel speed signal and the braking torque (brake pressure) signal, so the system is low cost, and its adaptability is good. There is no doubt this estimation method has a good application prospect.
Influence of effective stress coefficient on mechanical failure of chalk
Alam, Mohammad Monzurul; Fabricius, Ida Lykke; Hjuler, M.L.
2012-01-01
and vice versa. However, as the effective stress working on the rock decreases with increased effective stress coefficient, the reduction of elastic region will have less effect on pore collapse strength if we consider the change in the effective stress coefficient. This finding will help estimate a more...
Reliability Coefficients from Two Administrations of the Willoughby Personality Schedule
Hay, Nancy M.; Stewart, Norman R.
1974-01-01
This study determined internal consistency and test-retest reliability coefficients for the Willoughby Personality Schedule, currently used as an outcome measure in research and in clinical practice. The Hoyt analysis of variance yielded an internal consistency reliability coefficient of .90 on the first testing. The test-retest reliability…
Minimum wall pressure coefficient of orifice plate energy dissipater
Wan-zheng Ai; Jia-hong Wang
2015-01-01
Orifice plate energy dissipaters have been successfully used in large-scale hydropower projects due to their simple structure, convenient construction procedure, and high energy dissipation ratio. The minimum wall pressure coefficient of an orifice plate can indirectly reflect its cavitation characteristics:the lower the minimum wall pressure coefficient is, the better the ability of the orifice plate to resist cavitation damage is. Thus, it is important to study the minimum wall pressure coefficient of the orifice plate. In this study, this coefficient and related parameters, such as the contraction ratio, defined as the ratio of the orifice plate diameter to the flood-discharging tunnel diameter;the relative thickness, defined as the ratio of the orifice plate thickness to the tunnel diameter;and the Reynolds number of the flow through the orifice plate, were theoretically analyzed, and their relationships were obtained through physical model experiments. It can be concluded that the minimum wall pressure coefficient is mainly dominated by the contraction ratio and relative thickness. The lower the contraction ratio and relative thickness are, the larger the minimum wall pressure coefficient is. The effects of the Reynolds number on the minimum wall pressure coefficient can be neglected when it is larger than 105. An empirical expression was presented to calculate the minimum wall pressure coefficient in this study.
Minimum wall pressure coefficient of orifice plate energy dissipater
Wan-zheng AI
2015-01-01
Full Text Available Orifice plate energy dissipaters have been successfully used in large-scale hydropower projects due to their simple structure, convenient construction procedure, and high energy dissipation ratio. The minimum wall pressure coefficient of an orifice plate can indirectly reflect its cavitation characteristics: the lower the minimum wall pressure coefficient is, the better the ability of the orifice plate to resist cavitation damage is. Thus, it is important to study the minimum wall pressure coefficient of the orifice plate. In this study, this coefficient and related parameters, such as the contraction ratio, defined as the ratio of the orifice plate diameter to the flood-discharging tunnel diameter; the relative thickness, defined as the ratio of the orifice plate thickness to the tunnel diameter; and the Reynolds number of the flow through the orifice plate, were theoretically analyzed, and their relationships were obtained through physical model experiments. It can be concluded that the minimum wall pressure coefficient is mainly dominated by the contraction ratio and relative thickness. The lower the contraction ratio and relative thickness are, the larger the minimum wall pressure coefficient is. The effects of the Reynolds number on the minimum wall pressure coefficient can be neglected when it is larger than 105. An empirical expression was presented to calculate the minimum wall pressure coefficient in this study.
Permeability dependence of streaming potential coefficient in porous media
L.D. Thanh; R. Sprik
2015-01-01
In theory, the streaming potential coefficient depends not only on the zeta potential but also on the permeability of the rocks that partially determines the surface conductivity of the rocks. However, in practice, it is hard to show the permeability dependence of streaming potential coefficients be
Mass transfer coefficients in cross-flow ultrafiltration
Berg, van den G.B.; Rácz, I.G.; Smolders, C.A.
1989-01-01
Usually, in concentration polarization models, the mass transfer coefficient is an unknown parameter. Also, its variation with changing experimental circumstances is in question. In the literature, many relationships can be found to describe the mass transfer coefficient under various conditions, as
Mass transfer coefficients in cross-flow ultrafiltration
van den Berg, G.B.; Racz, I.G.; Smolders, C.A.
1989-01-01
Usually, in concentration polarization models, the mass transfer coefficient is an unknown parameter. Also, its variation with changing experimental circumstances is in question. In the literature, many relationships can be found to describe the mass transfer coefficient under various conditions, as
Determination of storage coefficients during pumping and recovery.
Ashjari, Javad
2013-01-01
An aquifer test is used mostly to determine the storage coefficient and transmissivity. Although residual drawdown data are widely used in estimating the transmissivity of aquifers, the estimation of storage coefficients with recovery data is controversial. Some researchers have proposed methods to estimate storage coefficients with recovery data by assuming equality of storage coefficients for the recovery and pumping periods (S = S'). The aim of this study is to determine storage coefficients without such an assumption, that is, S≠S'. The method is a modified version of Banton-Bangoy's method without considering drawdown data due to pumping. Drawdown is plotted vs. the logarithmic ratio (t'/t) or time since pumping stopped to the duration of pumping and the ratio of storage coefficient during recovery to the storage coefficient from the pumping period (S'/S). The method is verified with one case study and two synthetic examples. Thus, it is possible to determine storage coefficient of pumping period accurately without any data from pumping period by recovery data.
Confidence intervals for intraclass correlation coefficients in variance components models
Demetrashvili, Nino; Wit, Ernst C; Van Den Heuvel, Edwin R.
2016-01-01
Confidence intervals for intraclass correlation coefficients in agreement studies with continuous outcomes are model-specific and no generic approach exists. This paper provides two generic approaches for intraclass correlation coefficients of the form -' q = 1 Q σ q 2 / (-' q = 1 Q σ q 2 + -' p = Q
A Note on the Correlated Random Coefficient Model
Kolodziejczyk, Christophe
In this note we derive the bias of the OLS estimator for a correlated random coefficient model with one random coefficient, but which is correlated with a binary variable. We provide set-identification to the parameters of interest of the model. We also show how to reduce the bias of the estimator...
Anderson-Witting transport coefficients for flows in general relativity
Ambrus, Victor E
2016-01-01
The transport coefficients induced by the Anderson-Witting approximation of the collision term in the relativistic Boltzmann equation are derived for close to equilibrium flows in general relativity. Using the tetrad formalism, it is shown that the expression for these coefficients is the same as that obtained on flat space-time, in agreement with the generalized equivalence principle.
Predicting blood:air partition coefficients using basic physicochemical properties
Buist, H.E.; Wit-Bos, L. de; Bouwman, T.; Vaes, W.H.J.
2012-01-01
Quantitative Property Property Relationships (QPPRs) for human and rat blood:air partition coefficients (PBAs) have been derived, based on vapour pressure (Log(VP)), the octanol:water partition coefficient (Log(K_OW)) and molecular weight (MW), using partial least squares multilinear modelling. Thes
Coefficients for tests from a decision theoretic point of view
van der Linden, Willem J.; Mellenbergh, Gideon J.
1978-01-01
From a decision theoretic point of view a general coefficient for tests, d, is derived. The coefficient is applied to three kinds of decision situations. First, the situation is considered in which a true score is estimated by a function of the observed score of a subject on a test (point
Permeability dependence of streaming potential coefficient in porous media
Thanh, L.D.; Sprik, R.
2015-01-01
In theory, the streaming potential coefficient depends not only on the zeta potential but also on the permeability of the rocks that partially determines the surface conductivity of the rocks. However, in practice, it is hard to show the permeability dependence of streaming potential coefficients
Supercongruences satisfied by coefficients of 2F1 hypergeometric series
Chan, Heng Huat; Krattenthaler, Christian; Osburn, Robert
2009-01-01
Recently, Chan, Cooper and Sica conjectured two congruences for coefficients of classical 2F1 hypergeometric series which also arise from power series expansions of modular forms in terms of modular functions. We prove these two congruences using combinatorial properties of the coefficients.
REE and Strontium Partition Coefficients for Nakhla Pyroxenes
Oe, K.; McKay, G.; Le, L.
2001-01-01
We present new partition coefficients for REE and Sr determined using a synthetic melt that crystallizes pyroxenes very similar in composition to Nakhla pyroxene cores. We believe these are the most appropriate partition coefficients to use in studying Nakhla Additional information is contained in the original extended abstract..
Delimiting Coefficient a from Internal Consistency and Unidimensionality
Sijtsma, Klaas
2015-01-01
I discuss the contribution by Davenport, Davison, Liou, & Love (2015) in which they relate reliability represented by coefficient a to formal definitions of internal consistency and unidimensionality, both proposed by Cronbach (1951). I argue that coefficient a is a lower bound to reliability and that concepts of internal consistency and…
Influence of effective stress coefficient on mechanical failure of chalk
Alam, Mohammad Monzurul; Fabricius, Ida Lykke; Hjuler, M.L.
2012-01-01
The Effective stress coefficient is a measure of how chalk grains are connected with each other. The stiffness of chalk may decrease if the amount of contact cements between the grains decreases, which may lead to an increase of the effective stress coefficient. We performed CO2 injection in chal...
Solitary Wave in Linear ODE with Variable Coefficients
LIU Shi-Da; FU Zun-Tao; LIU Shi-Kuo; XIN Guo-Jun; LIANG Fu-Ming; FENG Bei-Ye
2003-01-01
In this paper, the linear ordinary differential equations with variable coefficients are obtained from thecontrolling equations satisfied by wavelet transform or atmospheric internal gravity waves, and these linear equationscan be further transformed into Weber equations. From Weber equations, the homoclinic orbit solutions can be derived,so the solitary wave solutions to linear equations with variable coefficients are obtained.
A Simple Geometric Approach to Approximating the Gini Coefficient
Kasper, Hirschel; Golden, John
2008-01-01
The author shows how a quick approximation of the Lorenz curve's Gini coefficient can be calculated empirically using numerical data presented in cumulative income quintiles. When the technique here was used to estimate 621 income quintile/Gini coefficient observations from the Deninger and Squire/World Bank data set, this approach performed…
On the Coefficients of a Hyperbolic Hydrodynamic Model
Muroya, Shin
2012-01-01
Based on the Nakajima-Zubarev type nonequilibrium density operator, we derive a hyperbolic hydrodynamical equation. Microscopic Kubo-formulas for all coefficients in the hyperbolic hydrodynamics are obtained. Coefficients $\\alpha_{i}$'s and $\\beta_{i}$'s in the Israel-Stewart equation are given as current-weighted correlation lengths which are to be calculated in statistical mechanics.
Digital speckle pattern interferometric measurement of diffusion coefficients in hydrogels
周金芳; 韩雁; 章献民; 徐坚
2003-01-01
The technique of real-time digital speckle pattern interferometry is proposed to study diffusion of surfactants in hydrogel. The diffusion coefficient is simply and directly determined from the interferograms. An example of diffusion coefficient measurement of surfactant in agarose gel demonstrates the usefulness of the method. The results obtained are compared with the theoretical simulating values.
Confidence intervals for intraclass correlation coefficients in variance components models
Demetrashvili, Nino; Wit, Ernst C; Van Den Heuvel, Edwin R.
2016-01-01
Confidence intervals for intraclass correlation coefficients in agreement studies with continuous outcomes are model-specific and no generic approach exists. This paper provides two generic approaches for intraclass correlation coefficients of the form -' q = 1 Q σ q 2 / (-' q = 1 Q σ q 2 + -' p = Q
4-manifolds and intersection forms with local coefficients
Frøyshov, Kim Anders
2012-01-01
We extend Donaldson's diagonalization theorem to intersection forms with certain local coefficients, under some constraints. This provides new examples of non-smoothable topological 4-manifolds.......We extend Donaldson's diagonalization theorem to intersection forms with certain local coefficients, under some constraints. This provides new examples of non-smoothable topological 4-manifolds....
Spacetime Variation of Lorentz-Violation Coefficients at Nonrelativistic Scale
Lane, Charles D
2016-01-01
When the Standard-Model Extension (SME) is applied in curved spacetime, the Lorentz-violation coefficients must depend on spacetime position. This work describes some of the consequences of this spacetime variation. We focus on effects that appear at a nonrelativistic scale and extract sensitivity of completed experiments to derivatives of SME coefficient fields.
Confidence bounds for normal and lognormal distribution coefficients of variation
Steve Verrill
2003-01-01
This paper compares the so-called exact approach for obtaining confidence intervals on normal distribution coefficients of variation to approximate methods. Approximate approaches were found to perform less well than the exact approach for large coefficients of variation and small sample sizes. Web-based computer programs are described for calculating confidence...
Measurement of diffusion coefficients by means of cataphoresis
Hogervorst, W.; Freudenthal, J.
1967-01-01
A new measuring method for diffusion coefficients in gas mixtures is described, using the cataphoretic segregation. A DC-discharge in a gas mixture causes a segregation, which vanishes by diffusion after extinguishing the discharge. The diffusion coefficient can be calculated from the time dependenc
Stochastic Modelling of the Diffusion Coefficient for Concrete
Thoft-Christensen, Palle
In the paper, a new stochastic modelling of the diffusion coefficient D is presented. The modelling is based on physical understanding of the diffusion process and on some recent experimental results. The diffusion coefficients D is strongly dependent on the w/c ratio and the temperature....
The κ-Generalizations of Stirling Approximation and Multinominal Coefficients
Tatsuaki Wada
2013-11-01
Full Text Available Stirling approximation of the factorials and multinominal coefficients are generalized based on the κ-generalized functions introduced by Kaniadakis. We have related the κ-generalized multinominal coefficients to the κ-entropy by introducing a new κ-product operation, which exists only when κ ≠ 0.
Projection-type estimation for varying coefficient regression models
Lee, Young K; Park, Byeong U; 10.3150/10-BEJ331
2012-01-01
In this paper we introduce new estimators of the coefficient functions in the varying coefficient regression model. The proposed estimators are obtained by projecting the vector of the full-dimensional kernel-weighted local polynomial estimators of the coefficient functions onto a Hilbert space with a suitable norm. We provide a backfitting algorithm to compute the estimators. We show that the algorithm converges at a geometric rate under weak conditions. We derive the asymptotic distributions of the estimators and show that the estimators have the oracle properties. This is done for the general order of local polynomial fitting and for the estimation of the derivatives of the coefficient functions, as well as the coefficient functions themselves. The estimators turn out to have several theoretical and numerical advantages over the marginal integration estimators studied by Yang, Park, Xue and H\\"{a}rdle [J. Amer. Statist. Assoc. 101 (2006) 1212--1227].
Limb-Darkening Coefficients for Eclipsing White Dwarfs
Gianninas, A; Kilic, Mukremin; Bergeron, P
2013-01-01
We present extensive calculations of linear and non-linear limb-darkening coefficients as well as complete intensity profiles appropriate for modeling the light-curves of eclipsing white dwarfs. We compute limb-darkening coefficients in the Johnson-Kron-Cousins UBVRI photometric system as well as the Large Synoptic Survey Telescope (LSST) ugrizy system using the most up-to-date model atmospheres available. In all, we provide the coefficients for seven different limb-darkening laws. We describe the variations of these coefficients as a function of the atmospheric parameters, including the effects of convection at low effective temperatures. Finally, we discuss the importance of having readily available limb-darkening coefficients in the context of present and future photometric surveys like the LSST, Palomar Transient Factory (PTF), and the Panoramic Survey Telescope and Rapid Response System (Pan-STARRS). The LSST, for example, may find ~10^5 eclipsing white dwarfs. The limb-darkening calculations presented h...
Direct Extraction of One-loop Integral Coefficients
Forde, Darren
2007-04-16
We present a general procedure for obtaining the coefficients of the scalar bubble and triangle integral functions of one-loop amplitudes. Coefficients are extracted by considering two-particle and triple unitarity cuts of the corresponding bubble and triangle integral functions. After choosing a specific parameterization of the cut loop momentum we can uniquely identify the coefficients of the desired integral functions simply by examining the behavior of the cut integrand as the unconstrained parameters of the cut loop momentum approach infinity. In this way we can produce compact forms for scalar integral coefficients. Applications of this method are presented for both QCD and electroweak processes, including an alternative form for the recently computed three-mass triangle coefficient in the six-photon amplitude A{sub 6}(1{sup -}, 2{sup +}, 3{sup -}, 4{sup +}, 5{sup -}, 6{sup +}). The direct nature of this extraction procedure allows for a very straightforward automation of the procedure.
Reflection and absorption coefficients for use in room acoustic simulations
Jeong, Cheol-Ho
2013-01-01
Two ideas to improve the boundary conditions for room acoustic simulations are presented. First, all rooms have finite boundary surfaces, thereby a reflection coefficient for finite surfaces should be physically more suitable than that for infinitely large surfaces. Second, absorption coefficients...... measured by the chamber method, so-called the Sabine absorption coefficients, have certain problems to be used in geometrical acoustics simulations; one serious problem is that they often exceed unity for porous absorbers due to the finite sample size and non-uniform intensity in the test reverberation...... chamber. Therefore the Sabine absorption coefficients should be converted into the random incidence absorption coefficients, which never exceed unity, thus are more proper for room acoustic simulations....
Stochastic back analysis of permeability coefficient using generalized Bayesian method
Zheng Guilan; Wang Yuan; Wang Fei; Yang Jian
2008-01-01
Owing to the fact that the conventional deterministic back analysis of the permeability coefficient cannot reflect the uncertainties of parameters, including the hydraulic head at the boundary, the permeability coefficient and measured hydraulic head, a stochastic back analysis taking consideration of uncertainties of parameters was performed using the generalized Bayesian method. Based on the stochastic finite element method (SFEM) for a seepage field, the variable metric algorithm and the generalized Bayesian method, formulas for stochastic back analysis of the permeability coefficient were derived. A case study of seepage analysis of a sluice foundation was performed to illustrate the proposed method. The results indicate that, with the generalized Bayesian method that considers the uncertainties of measured hydraulic head, the permeability coefficient and the hydraulic head at the boundary, both the mean and standard deviation of the permeability coefficient can be obtained and the standard deviation is less than that obtained by the conventional Bayesian method. Therefore, the present method is valid and applicable.
Optimization of Submarine Hydrodynamic Coefficients Based on Immune Genetic Algorithm
HU Kun; XU Yi-fan
2010-01-01
Aiming at the demand for optimization of hydrodynamic coefficients in submarine's motion equations, an adaptive weight immune genetic algorithm was proposed to optimize hydrodynamic coefficients in motion equations. Some hydrody-namic coefficients of high sensitivity to control and maneuver were chosen as the optimization objects in the algorithm. By using adaptive weight method to determine the weight and target function, the multi-objective optimization could be transla-ted into single-objective optimization. For a certain kind of submarine, three typical maneuvers were chosen to be the objects of study: overshoot maneuver in horizontal plane, overshoot maneuver in vertical plane and turning circle maneuver in horizontal plane. From the results of computer simulations using primal hydrodynamic coefficient and optimized hydrody-namic coefficient, the efficiency of proposed method is proved.
Determining pitch-angle diffusion coefficients from test particle simulations
Ivascenko, A; Spanier, F; Vainio, R
2016-01-01
Transport and acceleration of charged particles in turbulent media is a topic of great interest in space physics and interstellar astrophysics. These processes are dominated by the scattering of particles off magnetic irregularities. The scattering process itself is usually described by small-angle scattering with the pitch-angle coefficient $D_{\\mu\\mu}$ playing a major role. Since the diffusion coefficient $D_{\\mu\\mu}$ can be determined analytically only for the approximation of quasi-linear theory, the determination of this coefficient from numerical simulations has, therefore, become more important. So far these simulations yield particle tracks for small-scale scattering, which can then be interpreted using the running diffusion coefficients. This method has a limited range of validity. This paper presents two new methods that allow for the calculation of the pitch-angle diffusion coefficient from numerical simulations. These methods no longer analyse particle trajectories, but the change of particle dist...
Translation of dose coefficients From ICRP 53 to ICRP 80.
Moussa, Hanna M; Melanson, Mark A
2013-02-01
The effective dose coefficients tabulated in Publication 80 of the International Commission on Radiological Protection (ICRP) for the radiopharmaceuticals addressed earlier in ICRP Publication 53 are based on the tissue weighting factors of ICRP Publication 60. Presumably these values are derived from the tissue dose coefficients tabulated in Publication 53; however, no details regarding their derivation are provided. The tissue weighting factors of Publication 60 explicitly address tissue for which no dose coefficients were tabulated in Publication 53; for example, esophagus and a number of tissues comprising the remainder. In the absence of guidance, the authors have defined a set of rules for the translation and have undertaken an effort to derive the effective dose coefficients of Publication 80 starting with the organ/tissue dose coefficient of Publication 53.
Determination of absolute internal conversion coefficients using the SAGE spectrometer
Sorri, J.; Greenlees, P. T.; Papadakis, P.; Konki, J.; Cox, D. M.; Auranen, K.; Partanen, J.; Sandzelius, M.; Pakarinen, J.; Rahkila, P.; Uusitalo, J.; Herzberg, R.-D.; Smallcombe, J.; Davies, P. J.; Barton, C. J.; Jenkins, D. G.
2016-03-01
A non-reference based method to determine internal conversion coefficients using the SAGE spectrometer is carried out for transitions in the nuclei of 154Sm, 152Sm and 166Yb. The Normalised-Peak-to-Gamma method is in general an efficient tool to extract internal conversion coefficients. However, in many cases the required well-known reference transitions are not available. The data analysis steps required to determine absolute internal conversion coefficients with the SAGE spectrometer are presented. In addition, several background suppression methods are introduced and an example of how ancillary detectors can be used to select specific reaction products is given. The results obtained for ground-state band E2 transitions show that the absolute internal conversion coefficients can be extracted using the methods described with a reasonable accuracy. In some cases of less intense transitions only an upper limit for the internal conversion coefficient could be given.
Friction Coefficient of UHMWPE During Dry Reciprocating Sliding
F. Zivic
2014-09-01
Full Text Available This paper deals with the friction coefficient behaviour during dry reciprocating sliding of UHMWPE in contact with alumina (Al2O3, within a range of velocities typical for hip implants. Five values of normal force (100 - 1000 mN and three values of sliding speed (4 - 12 mm/s have been observed. Real time diagrams of the friction coefficient as a function of the sliding cycles were recorded for each test. Dynamic friction coefficient curves exhibited rather uniform behavior for all test conditions. Somewhat larger values of friction coefficient could be observed during the running-in period in case of low loads (100 - 250 mN and the lowest velocity (4 mm/s. In case of high loads and speeds, friction coefficient reached steady state values shortly after the beginning of the test.
Determination of absolute internal conversion coefficients using the SAGE spectrometer
Sorri, J., E-mail: juha.m.t.sorri@jyu.fi [University of Jyvaskyla, Department of Physics, P.O. Box 35, FI-40014 University of Jyvaskyla (Finland); Greenlees, P.T.; Papadakis, P.; Konki, J. [University of Jyvaskyla, Department of Physics, P.O. Box 35, FI-40014 University of Jyvaskyla (Finland); Cox, D.M. [University of Jyvaskyla, Department of Physics, P.O. Box 35, FI-40014 University of Jyvaskyla (Finland); Department of Physics, University of Liverpool, Oxford Street, Liverpool L69 7ZE (United Kingdom); Auranen, K.; Partanen, J.; Sandzelius, M.; Pakarinen, J.; Rahkila, P.; Uusitalo, J. [University of Jyvaskyla, Department of Physics, P.O. Box 35, FI-40014 University of Jyvaskyla (Finland); Herzberg, R.-D. [Department of Physics, University of Liverpool, Oxford Street, Liverpool L69 7ZE (United Kingdom); Smallcombe, J.; Davies, P.J.; Barton, C.J.; Jenkins, D.G. [Department of Physics, University of York, Heslington, York YO10 5DD (United Kingdom)
2016-03-11
A non-reference based method to determine internal conversion coefficients using the SAGE spectrometer is carried out for transitions in the nuclei of {sup 154}Sm, {sup 152}Sm and {sup 166}Yb. The Normalised-Peak-to-Gamma method is in general an efficient tool to extract internal conversion coefficients. However, in many cases the required well-known reference transitions are not available. The data analysis steps required to determine absolute internal conversion coefficients with the SAGE spectrometer are presented. In addition, several background suppression methods are introduced and an example of how ancillary detectors can be used to select specific reaction products is given. The results obtained for ground-state band E2 transitions show that the absolute internal conversion coefficients can be extracted using the methods described with a reasonable accuracy. In some cases of less intense transitions only an upper limit for the internal conversion coefficient could be given.
The Determinants of Gini Coefficient in Iran Based on Bayesian Model Averaging
Mohsen Mehrara
2015-03-01
Full Text Available This paper has tried to apply BMA approach in order to investigate important influential variables on Gini coefficient in Iran over the period 1976-2010. The results indicate that the GDP growth is the most important variable affecting the Gini coefficient and has a positive influence on it. Also the second and third effective variables on Gini coefficient are respectively the ratio of government current expenditure to GDP and the ratio of oil revenue to GDP which lead to an increase in inequality. This result is corresponding with rentier state theory in Iran economy. Injection of massive oil revenue to Iran's economy and its high share of the state budget leads to inefficient government spending and an increase in rent-seeking activities in the country. Economic growth is possibly a result of oil revenue in Iran economy which has caused inequality in distribution of income.
Determination of the concentration dependent diffusion coefficient of nitrogen in expanded austenite
Christiansen, Thomas; Somers, Marcel A. J.
2008-01-01
The concentration dependent diffusion coefficient of nitrogen in expanded austenite was determined from of the rate of retracting nitrogen from thin initially N-saturated coupons. Nitrogen saturated homogeneous foils of expanded austenite were obtained by nitriding AISI 304 and AISI 316 in pure...... ammonia at 693 K and 718 K. Denitriding experiments were performed by equilibrating the foils with a successively lower nitrogen activity, as imposed by a gas mixture of ammonia and hydrogen. The concentration dependent diffusion coefficient of nitrogen in expanded austenite was approximated...... in the composition range where nitrogen can be extracted by hydrogen gas at the diffusion temperature. Numerical simulation of the denitriding experiments shows that the thus determined concentration dependent diffusion coefficients are an accurate approximation of the actual diffusivity of nitrogen in expanded...
de Vienne, D; Bost, B; Fiévet, J; Dillmann, C
2001-01-01
In the metabolic control theory, the control coefficient is a key parameter in quantifying the sensitivity of the flux towards an infinitesimal variation of enzyme activity. This concept does not apply just as it is for variations of enzyme concentrations whenever there is spatial, energy or resources limitations in the cell. Due to constraint on total enzyme concentration, the variation of concentration of any given enzyme may affect the concentrations of other enzymes. To take into account these correlations between enzyme concentrations, we propose the concept of "combined response coefficient". Its definition is similar to that of the control coefficient, but its mathematical expression is different. Its range of variation is from -infinity to +1, the null value corresponding to optimum enzyme concentration, i.e. to concentrations that maximise the flux, and the negative values to concentrations beyond the optimum value. A summation property could be derived using a simple weighting of the combined response coefficients, the sum of the weighed coefficient being 0.
Development and assessment of atomistic models for predicting static friction coefficients
Jahangiri, Soran; Heverly-Coulson, Gavin S.; Mosey, Nicholas J.
2016-08-01
The friction coefficient relates friction forces to normal loads and plays a key role in fundamental and applied areas of science and technology. Despite its importance, the relationship between the friction coefficient and the properties of the materials forming a sliding contact is poorly understood. We illustrate how simple relationships regarding the changes in energy that occur during slip can be used to develop a quantitative model relating the friction coefficient to atomic-level features of the contact. The slip event is considered as an activated process and the load dependence of the slip energy barrier is approximated with a Taylor series expansion of the corresponding energies with respect to load. The resulting expression for the load-dependent slip energy barrier is incorporated in the Prandtl-Tomlinson (PT) model and a shear-based model to obtain expressions for friction coefficient. The results indicate that the shear-based model reproduces the static friction coefficients μs obtained from first-principles molecular dynamics simulations more accurately than the PT model. The ability of the model to provide atomistic explanations for differences in μs amongst different contacts is also illustrated. As a whole, the model is able to account for fundamental atomic-level features of μs, explain the differences in μs for different materials based on their properties, and might be also used in guiding the development of contacts with desired values of μs.
A hierarchical estimator development for estimation of tire-road friction coefficient
Zhang, Xudong; Göhlich, Dietmar
2017-01-01
The effect of vehicle active safety systems is subject to the friction force arising from the contact of tires and the road surface. Therefore, an adequate knowledge of the tire-road friction coefficient is of great importance to achieve a good performance of these control systems. This paper presents a tire-road friction coefficient estimation method for an advanced vehicle configuration, four-motorized-wheel electric vehicles, in which the longitudinal tire force is easily obtained. A hierarchical structure is adopted for the proposed estimation design. An upper estimator is developed based on unscented Kalman filter to estimate vehicle state information, while a hybrid estimation method is applied as the lower estimator to identify the tire-road friction coefficient using general regression neural network (GRNN) and Bayes' theorem. GRNN aims at detecting road friction coefficient under small excitations, which are the most common situations in daily driving. GRNN is able to accurately create a mapping from input parameters to the friction coefficient, avoiding storing an entire complex tire model. As for large excitations, the estimation algorithm is based on Bayes' theorem and a simplified “magic formula” tire model. The integrated estimation method is established by the combination of the above-mentioned estimators. Finally, the simulations based on a high-fidelity CarSim vehicle model are carried out on different road surfaces and driving maneuvers to verify the effectiveness of the proposed estimation method. PMID:28178332
The solid-phase diffusion coefficient (Dm) and material-air partition coefficient (Kma) are key parameters for characterizing the sources and transport of semivolatile organic compounds (SVOCs) in the indoor environment. In this work, a new experimental method was developed to es...
Automatic estimation of pressure-dependent rate coefficients
Allen, Joshua W.
2012-01-01
A general framework is presented for accurately and efficiently estimating the phenomenological pressure-dependent rate coefficients for reaction networks of arbitrary size and complexity using only high-pressure-limit information. Two aspects of this framework are discussed in detail. First, two methods of estimating the density of states of the species in the network are presented, including a new method based on characteristic functional group frequencies. Second, three methods of simplifying the full master equation model of the network to a single set of phenomenological rates are discussed, including a new method based on the reservoir state and pseudo-steady state approximations. Both sets of methods are evaluated in the context of the chemically-activated reaction of acetyl with oxygen. All three simplifications of the master equation are usually accurate, but each fails in certain situations, which are discussed. The new methods usually provide good accuracy at a computational cost appropriate for automated reaction mechanism generation. This journal is © the Owner Societies.
Activity Coefficients of CuSO4-NiSO4-H2 O System at 298.15 K%298．15K时CuSO4-NiSO4-H2O三元溶液体系的活度
陈香; 刘士军; 黄华强
2014-01-01
The osmotic coefficients of the CuSO4-NiSO4-H2 O system at 298.15 K was determined by the iso-piestic method in the ion strength range from 0.387 7~5.798 6 mol/kg.The experimental data were represented by the pitzer ion-interaction model, and the Pitzer ion interaction parameters were obtained from resulting osmotic coefficients by multiple linear regression.The osmotic coefficients values determined experimentally and those cal-culated by the model in reasonable agreement indicated that the Pitzer model can describle the system's thermody-namics properties well at 298 .15 K.The function between acitivity coefficients and the ionic strength was studied.%用等压法测定了298．15 K时CuSO4-NiSO4-H2 O溶液体系在离子强度范围为0．3877～5．7986 mol· kg-1内的渗透系数，用Pitzer离子相互作用模型对实验结果进行参数化研究，获得了CuSO4和NiSO4纯盐参数以及混盐参数，渗透系数的模型计算值与实验值的相对偏差为±0．03，表明Pitzer模型能较好描述298．15 K时该溶液体系的热力学性质；得到了该溶液体系中离子平均活度系数随离子强度的变化规律．
Factors influencing the stream-aquifer flow exchange coefficient.
Morel-Seytoux, Hubert J; Mehl, Steffen; Morgado, Kyle
2014-01-01
Knowledge of river gain from or loss to a hydraulically connected water table aquifer is crucial in issues of water rights and also when attempting to optimize conjunctive use of surface and ground waters. Typically in groundwater models this exchange flow is related to a difference in head between the river and some point in the aquifer, through a "coefficient." This coefficient has been defined differently as well as the location for the head in the aquifer. This paper proposes a new coefficient, analytically derived, and a specific location for the point where the aquifer head is used in the difference. The dimensionless part of the coefficient is referred to as the SAFE (stream-aquifer flow exchange) dimensionless conductance. The paper investigates the factors that influence the value of this new conductance. Among these factors are (1) the wetted perimeter of the cross-section, (2) the degree of penetration of the cross-section, and (3) the shape of the cross-section. The study shows that these factors just listed are indeed ordered in their respective level of importance. In addition the study verifies that the analytical correct value of the coefficient is matched by finite difference simulation only if the grid system is sufficiently fine. Thus the use of the analytical value of the coefficient is an accurate and efficient alternative to ad hoc estimates for the coefficient typically used in finite difference and finite element methods. © 2013, National Ground Water Association.
Approximate reflection coefficients for a thin VTI layer
Hao, Qi
2017-09-18
We present an approximate method to derive simple expressions for the reflection coefficients of P- and SV-waves for a thin transversely isotropic layer with a vertical symmetry axis (VTI) embedded in a homogeneous VTI background. The layer thickness is assumed to be much smaller than the wavelengths of P- and SV-waves inside. The exact reflection and transmission coefficients are derived by the propagator matrix method. In the case of normal incidence, the exact reflection and transmission coefficients are expressed in terms of the impedances of vertically propagating P- and S-waves. For subcritical incidence, the approximate reflection coefficients are expressed in terms of the contrast in the VTI parameters between the layer and the background. Numerical examples are designed to analyze the reflection coefficients at normal and oblique incidence, and investigate the influence of transverse isotropy on the reflection coefficients. Despite giving numerical errors, the approximate formulae are sufficiently simple to qualitatively analyze the variation of the reflection coefficients with the angle of incidence.
Transparent composite model for DCT coefficients: design and analysis.
Yang, En-Hui; Yu, Xiang; Meng, Jin; Sun, Chang
2014-03-01
The distributions of discrete cosine transform (DCT) coefficients of images are revisited on a per image base. To better handle, the heavy tail phenomenon commonly seen in the DCT coefficients, a new model dubbed a transparent composite model (TCM) is proposed and justified for both modeling accuracy and an additional data reduction capability. Given a sequence of the DCT coefficients, a TCM first separates the tail from the main body of the sequence. Then, a uniform distribution is used to model the DCT coefficients in the heavy tail, whereas a different parametric distribution is used to model data in the main body. The separate boundary and other parameters of the TCM can be estimated via maximum likelihood estimation. Efficient online algorithms are proposed for parameter estimation and their convergence is also proved. Experimental results based on Kullback-Leibler divergence and χ(2) test show that for real-valued continuous ac coefficients, the TCM based on truncated Laplacian offers the best tradeoff between modeling accuracy and complexity. For discrete or integer DCT coefficients, the discrete TCM based on truncated geometric distributions (GMTCM) models the ac coefficients more accurately than pure Laplacian models and generalized Gaussian models in majority cases while having simplicity and practicality similar to those of pure Laplacian models. In addition, it is demonstrated that the GMTCM also exhibits a good capability of data reduction or feature extraction-the DCT coefficients in the heavy tail identified by the GMTCM are truly outliers, and these outliers represent an outlier image revealing some unique global features of the image. Overall, the modeling performance and the data reduction feature of the GMTCM make it a desirable choice for modeling discrete or integer DCT coefficients in the real-world image or video applications, as summarized in a few of our further studies on quantization design, entropy coding design, and image understanding
Radon diffusion coefficients in soils of varying moisture content
Papachristodoulou, C.; Ioannides, K.; Pavlides, S.
2009-04-01
Radon is a naturally occurring radioactive gas that is generated in the Earth's crust and is free to migrate through soil and be released to the atmosphere. Due to its unique properties, soil gas radon has been established as a powerful tracer used for a variety of purposes, such as exploring uranium ores, locating geothermal resources and hydrocarbon deposits, mapping geological faults, predicting seismic activity or volcanic eruptions and testing atmospheric transport models. Much attention has also been given to the radiological health hazard posed by increased radon concentrations in the living and working environment. In order to exploit radon profiles for geophysical purposes and also to predict its entry indoors, it is necessary to study its transport through soils. Among other factors, the importance of soil moisture in such studies has been largely highlighted and it is widely accepted that any measurement of radon transport parameters should be accompanied by a measurement of the soil moisture content. In principle, validation of transport models in the field is encountered by a large number of uncontrollable and varying parameters; laboratory methods are therefore preferred, allowing for experiments to be conducted under well-specified and uniform conditions. In this work, a laboratory technique has been applied for studying the effect of soil moisture content on radon diffusion. A vertical diffusion chamber was employed, in which radon was produced from a 226Ra source, was allowed to diffuse through a soil column and was finally monitored using a silicon surface barrier detector. By solving the steady-state radon diffusion equation, diffusion coefficients (D) were determined for soil samples of varying moisture content (m), from null (m=0) to saturation (m=1). For dry soil, a D value of 4.1×10-7 m2s-1 was determined, which increased moderately by a factor of ~3 for soil with low moisture content, i.e. up to m ~0.2. At higher water fractions, a decrease
Robust Stabilization of Nonlinear Systems with Uncertain Varying Control Coefficient
Zaiyue Yang
2014-01-01
Full Text Available This paper investigates the stabilization problem for a class of nonlinear systems, whose control coefficient is uncertain and varies continuously in value and sign. The study emphasizes the development of a robust control that consists of a modified Nussbaum function to tackle the uncertain varying control coefficient. By such a method, the finite-time escape phenomenon has been prevented when the control coefficient is crossing zero and varying its sign. The proposed control guarantees the asymptotic stabilization of the system and boundedness of all closed-loop signals. The control performance is illustrated by a numerical simulation.
On the Li Coefficients for the Hecke L-functions
Omar, Sami; Ouni, Raouf; Mazhouda, Kamel
2014-06-01
In this paper, we compute and verify the positivity of the Li coefficients for the Hecke L-functions using an arithmetic formula established in Omar and Mazhouda, J. Number Theory 125(1), 50-58 (2007) and J. Number Theory 130(4), 1098-1108 (2010) and the Serre trace formula. Additional results are presented, including new formulas for the Li coefficients and a formulation of a criterion for the partial Riemann hypothesis. Basing on the numerical computations made below, we conjecture that these coefficients are increasing in n.
Spacetime Variation of Lorentz-Violation Coefficients at Nonrelativistic Scale
Lane, Charles D
2016-01-01
The notion of uniform and/or constant tensor fields of rank $>0$ is incompatible with general curved spacetimes. This work considers the consequences of certain tensor-valued coefficients for Lorentz violation in the Standard-Model Extension varying with spacetime position. We focus on two of the coefficients, $a_\\mu$ and $b_\\mu$, that characterize Lorentz violation in massive fermions, particularly in those fermions that constitute ordinary matter. We calculate the nonrelativistic hamiltonian describing these effects, and use it to extract the sensitivity of several precision experiments to coefficient variation.
Thermal Conductivity and Heat Transfer Coefficient of Concrete
GUO Lixia; GUO Lei; ZHONG Ling; ZHU Yueming
2011-01-01
A very simple model for predicting thermal conductivity based on its definiensis was presented.The thermal conductivity obtained using the model provided a good coincidence to the investigations performed by other authors.The heat transfer coefficient was determined by inverse analysis using the temperature measurements.From experimental results,it is noted that heat transfer coefficient increases with the increase of wind velocity and relative humidity,a prediction equation on heat transfer coefficient about wind velocity and relative humidity is given.
Static pressure and temperature coefficients of working standard microphones
Barrera Figueroa, Salvador; Cutanda Henriquez, Vicente; Torras Rosell, Antoni
2016-01-01
The sensitivity of measurement microphones is affected by changes in the environmental conditions, mainly temperature and static pressure. This rate of change has been the object of previous studies focused on Laboratory Standard microphones. The literature describes frequency dependent values...... for these coefficients which are used for calibration purposes. Working standard microphones are not exempt of these influences. However, manufacturers usually provide a low frequency value of the environmental coefficient. While in some applications the influence of this coefficient may be negligible, in others it may...
Prediction of Aerodynamic Coefficients using Neural Networks for Sparse Data
Rajkumar, T.; Bardina, Jorge; Clancy, Daniel (Technical Monitor)
2002-01-01
Basic aerodynamic coefficients are modeled as functions of angles of attack and sideslip with vehicle lateral symmetry and compressibility effects. Most of the aerodynamic parameters can be well-fitted using polynomial functions. In this paper a fast, reliable way of predicting aerodynamic coefficients is produced using a neural network. The training data for the neural network is derived from wind tunnel test and numerical simulations. The coefficients of lift, drag, pitching moment are expressed as a function of alpha (angle of attack) and Mach number. The results produced from preliminary neural network analysis are very good.
Fractional crystallization of iron meteorites: Constant versus changing partition coefficients
Jones, J. H.
1994-01-01
Analyses of magmatic iron meteorites, plotted on LogC(sub i) vs LogC(sub Ni) diagrams, often form linear arrays. Traditionally, this linearity has been ascribed to fractional crystallization under the assumption of constant partition coefficients (i.e., Rayleigh fractionation). Paradoxically, however, partition coefficients in the Fe-Ni-S-P system are decidedly not constant. This contribution provides a rationale for understanding how trends on LogC(sub i) vs LogC(sub Ni) diagrams can be linear, even when partition coefficients are changing rapidly.
Orientation and velocity dependence of the nonequilibrium partition coefficient
Beatty, K. M.; Jackson, K. A.
1995-01-01
Monte Carlo simulations based on a Spin-1 Ising Model for binary alloys have been used to investigate the non-equilibrium partition coefficient (k(sub neq)) as a function of solid-liquid interface velocity and orientation. In simulations of Si with a second component k(sub neq) is greater in the [111] direction than the [100] direction in agreement with experimental results reported by Azlz et al. The simulated partition coefficient scales with the square of the step velocity divided by the diffusion coefficient of the secondary component in the liquid.
Inflationary Weak Anisotropic Model with General Dissipation Coefficient
Sharif, M
2015-01-01
This paper explores the dynamics of warm intermediate and logamediate inflationary models during weak dissipative regime with a general form of dissipative coefficient. We analyze these models within the framework of locally rotationally symmetric Bianchi type I universe. In both cases, we evaluate solution of inflaton, effective scalar potential, dissipative coefficient, slow-roll parameters, scalar and tensor power spectra, scalar spectral index and tensor to scalar ratio under slow-roll approximation. We constrain the model parameters using recent data and conclude that anisotropic inflationary universe model with generalized dissipation coefficient remains compatible with WMAP9, Planck and BICEP2 data.
Measurement of friction coefficient in aluminum sheet warm forming
GUO Zheng-hua; LI Zhi-gang; HUANG Chong-jiu; DONG Xiang-huai
2005-01-01
Aluminum alloy sheets are used more and more to manufacture auto panels. Because the friction behavior is very complicated, it is necessary to study the friction during the aluminum sheet warm forming process. The author has designed a new probe sensor based on an online tribotest method which directly measures friction coefficient in the forming process. Experiments of cup drawing have been conducted and the friction coefficients under different forming conditions have been measured. The results indicate that the forming parameters, such as forming temperature, blankholding force and lubrication status have great effect upon the friction coefficient.
Bayesian Inference of Empirical Coefficient for Foundation Settlement
LI Zhen-yu; WANG Yong-he; YANG Guo-lin
2009-01-01
A new approach based on Bayesian theory is proposed to determine the empirical coefficient in soil settlement calculation. Prior distribution is assumed to be uniform in [0.2,1.4]. Posterior density function is developed in the condition of prior distribution combined with the information of observed samples at four locations on a passenger dedicated line. The results show that the posterior distribution of the empirical coefficient obeys Gaussian distribution. The mean value of the empirical coefficient decreases gradually with the increasing of the load on ground, and variance variation shows no regularity.
Adaptive Peak Frequency Estimation Using a Database of PARCOR Coefficients
Iiguni Youji
2005-01-01
Full Text Available This paper presents an adaptive peak frequency estimation method using a database that stores PARCOR coefficients as key attributes and the corresponding peak frequencies as nonkey attributes. The least-square lattice algorithm is used to recursively estimate the PARCOR coefficients to adapt to changing circumstances. The nearest neighbor to the current PARCOR coefficient is retrieved from the database, and the corresponding peak frequency is regarded as the estimation. A simultaneous execution of database construction and peak estimation with database update is performed to accelerate the processing time and to improve the estimation accuracy.
Experimental investigation of friction coefficient in tube hydroforming
Hyae Kyung YI; Hong Sup YIM; Gun Yeop LEE; Sung Mun LEE; Gi Suk CHUNG; Young-Hoon MOON
2011-01-01
The friction coefficient between tube and die in guide zone of tube hydroforming was obtained. In hydroforming, the tube is expanded by an internal pressure against the tool wall. By pushing the tube through tool, a friction force at the contact surface between the tube and the tool occurs. In guiding zone, the friction coefficients between tube and die can be estimated from the measured axial feeding forces. In expansion zone, the friction coefficients between tube and die can be evaluated from the measured geometries of expanded tubes and FE analysis.