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Sample records for acrylic composites loaded

  1. Permittivity and Electromagnetic Interference Shielding Investigations of Activated Charcoal Loaded Acrylic Coating Compositions

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    Sharief ud Din Khan

    2014-01-01

    Full Text Available Acrylic resin (AR based electromagnetic interference (EMI shielding composites have been prepared by incorporation of up to 30 wt% activated charcoal (AC in AR matrix. These composites have been characterized by XRD, Raman spectroscopy, scanning electron microscopy, dielectric, and EMI shielding measurement techniques. XRD patterns and Raman studies confirm the incorporation of AC particles inside AR matrix and suggest possible interactions between phases. The SEM images show that incorporation of AC particles leads to systematic change in the morphology of composites especially the formation of porous structure. The dielectric measurements show that 30 wt% AC loading composite display higher relative permittivity value (~79 compared to pristine AR (~5. Further, the porous structure, electrical conductivity, and permittivity value contribute towards EMI shielding effectiveness value of −36 dB (attenuation of >99.9% of incident radiation for these composites, thereby demonstrating their suitability for making efficient EMI shielding coatings.

  2. Minocycline-loaded cellulose nano whiskers/poly(sodium acrylate) composite hydrogel films as wound dressing.

    Science.gov (United States)

    Bajpai, S K; Pathak, V; Soni, Bhawna

    2015-08-01

    In this work, antibiotic drug Minocycline (Mic) loaded cellulose nano-whiskers (CNWs)/poly(sodium acrylate) hydrogel films were prepared and investigated for their drug releasing capacity in physiological buffer solution (PBS) at 37 °C. The (CNWs)/poly(sodium acrylate) film, containing 9.7% (w/w) of CNWs, demonstrated Mic release of 2500 μg/g while the plain poly(acrylate) film showed 3100 μg/g of drug release. In addition, with the increase in the concentration of cross-linker N,N'-methylene bisacrylamide (MB) from to, the drug release from the resulting films decreased from 507 to 191 μg/g. The release exponent 'n' for films with different compositions was found in the range of 0.45 to 0.89, thus indicating non-Fickian release mechanism. The Schott model was employed to interpret the kinetic drug release data successfully. The film samples poly(SA) and CNWs/poly(SA) (both not containing drug) showed thrombus formation of 0.010±0.001 g and 0.007±0.001 g, respectively, thus showing the non-thrombogenic behavior. In percent Hemolysis, both of the film samples of 1.136±0.012 and 0.5±0.020, respectively, thus indicating non-hemolytic behavior. In addition, both of the film samples demonstrated protein adsorption of 49.02±0.59μ g/μL and 51.20±0.51 μg/μL per cm(2), thus revealing a fair degree of protein adsorption. Finally, the Mic-loaded films showed fair anti-fungal and antibacterial properties.

  3. Poly(lauryl acrylate) and poly(stearyl acrylate) grafted multiwalled carbon nanotubes for polypropylene composites

    DEFF Research Database (Denmark)

    Daugaard, Anders Egede; Jankova Atanasova, Katja; Hvilsted, Søren

    2014-01-01

    in loading after 12 h of polymerization. The modified nanomaterials were melt mixed into polypropylene composites with very low filler loading (0.3 wt%), whereafter both the thermal and electrical properties were investigated by DSC and dielectric resonance spectroscopy. The electrical properties were found...... to be substantially improved, where poly(lauryl acrylate) was found to be the superior surface modification, resulting in a conductive composite....

  4. Antibiotic-loaded acrylic cement: current concepts.

    Science.gov (United States)

    Buchholz, H W; Elson, R A; Heinert, K

    1984-11-01

    Antibiotic-loaded acrylic cement has been used routinely since 1972 at the authors' hospitals, where a series of some 22,000 joint arthroplasty operations was performed from 1964-1983. The current status of the material is presented with up-to-date follow-up statistics on prophylactic therapy and on established deep infections. The results of 869 exchange arthroplasties are compared with results published in 1981. In the future, results will be presented in the form of survival curves. The method by which survival tables and curves are constructed is critical. Investigators should use survival curves for ease of comparison and because of the wide range of possibilities in an analysis of covariable factors. A retrospective actuarial analysis was made of 825 one-stage reimplantations in which antibiotic-loaded acrylic cement was used for infected total hip arthroplasties. Staphylococcus aureus was the most commonly encountered organism. Failure rates of prostheses infected by S. aureus, S. species, and anaerobic corynebacteria did not differ statistically. A factor that significantly contributed to failure of this method of treatment was Pseudomonas infection. By actuarial analysis five years after operation, a success (survival) rate of 77% was calculated.

  5. Biocompatibility of alendronate-loaded acrylic cement for vertebroplasty

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    T Calvo-Fernández

    2010-10-01

    Full Text Available This paper reports a biological evaluation of a non-resorbable acrylic cement loaded with alendronate for the treatment of osteoporotic vertebral compression fractures. The cement formulation was based on polymethyl methacrylate and acrylic monomers; one of these had covalently linked vitamin E residues. The same cement in the absence of alendronate was used as a control. The setting of the charged cement presented a maximum polymerization temperature of 44ºC, a setting time of 24 min, a residual monomer content lower than 3 wt.%, a compressive strength of 99±10 MPa and an elastic modulus of 1.2±0.2 GPa. Cytotoxicity studies using human osteoblast cultures revealed that the leachable substances of the alendronate loaded cement collected between 1 and 7 days decreased cell viability to values lower than 80%. However, morphological changes and cellular damage in cells produced by the extracts decreased with the leak time. Cell adhesion and growth on charged cement was significantly lower than on the control. Implantation of the cement paste in the intra-femoral cavity of rabbits showed that initially the osteogenic activity was evident for the cement charged with alendronate, and the osteosynthesis process took place mainly in the trabeculae and was manifested by the presence of a non-mineralised osseous spicule. The interface between material and adjacent bone tissue was initially characterized by a variable fibrous response that in many cases it appeared reduced to thin connective tissue after a 24-week-period.

  6. In Situ Synthesis of Reduced Graphene Oxide-Reinforced Silicone-Acrylate Resin Composite Films Applied in Erosion Resistance

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    Yang Cao

    2015-01-01

    Full Text Available The reduced graphene oxide reinforced silicone-acrylate resin composite films (rGO/SAR composite films were prepared by in situ synthesis method. The structure of rGO/SAR composite films was characterized by Raman spectrum, atomic force microscope, scanning electron microscopy, and thermogravimetric analyzer. The results showed that the rGO were uniformly dispersed in silicone-acrylate resin matrix. Furthermore, the effect of rGO loading on mechanical properties of composite films was investigated by bulge test. A significant enhancement (ca. 290% and 320% in Young’s modulus and yield stress was obtained by adding the rGO to silicone-acrylate resin. At the same time, the adhesive energy between the composite films and metal substrate was also improved to be about 200%. Moreover, the erosion resistance of the composite films was also investigated as function of rGO loading. The rGO had great effect on the erosion resistance of the composite films, in which the Rcorr (ca. 0.8 mm/year of composite film was far lower than that (28.7 mm/year of pure silicone-acrylate resin film. Thus, this approach provides a novel route to investigate mechanical stability of polymer composite films and improve erosion resistance of polymer coating, which are very important to be used in mechanical-corrosion coupling environments.

  7. The influence of cyclic loading on gentamicin release from acrylic bone cements

    NARCIS (Netherlands)

    Hendriks, JGE; Neut, D; Hazenberg, JG; Verkerke, GJ; van Horn, [No Value; van der Mei, HC; Busscher, HJ

    2005-01-01

    Antibiotic-loaded acrylic bone cement is widely used in total joint replacement to reduce infections. Walking results in cyclic loading, which has been suggested to stimulate antibiotic release. The goal of this study is to compare antibiotic release from cyclically loaded bone cement with the relea

  8. Antifouling foldable acrylic IOLs loaded with norfloxacin by aqueous soaking and by supercritical carbon dioxide technology.

    Science.gov (United States)

    González-Chomón, Clara; Braga, Mara E M; de Sousa, Herminio C; Concheiro, Angel; Alvarez-Lorenzo, Carmen

    2012-10-01

    Cataracts treatment usually involves the extraction of the opaque crystalline lens and its replacement by an intraocular lens (IOL). A serious complication is the occurrence of endophthalmitis, a post-surgery infection mainly caused by Staphylococcus epidermidis, Staphylococcus aureus, and Pseudomonas aeruginosa. IOLs having the ability to load and to release norfloxacin in a controlled way and at efficient therapeutic levels may help to overcome these issues. In this work, acrylic hydrogels combining 2-hydroxyethyl methacrylate (HEMA) and 2-butoxyethyl methacrylate (BEM) at various ratios were prepared to attain biocompatible networks that can be foldable even in the dry state and thus insertable through minor ocular incision, and that load therapeutic amounts of norfloxacin. Acrylamide (AAm) and methacrylic acid (MAAc) were also incorporated as functional comonomers in small proportions. Water sorption, contact angle, protein adsorption, and optical properties of the networks were characterized. BEM notably decreased the T(g) of the networks, but also the loading by immersion in aqueous solution (presoaking). Then, a scCO(2)-based impregnation/deposition (SSI) method was implemented to improve the uptake of the drug. Loading capacities were discussed in terms of the comonomers composition and the employed method and operational conditions. The networks prepared with HEMA/BEM 20:80 vol/vol and processed with supercritical fluids combine adequate mechanical properties, biocompatibility and norfloxacin loading/release, and seem to be suitable for developing norfloxacin-eluting IOLs. Copyright © 2012 Elsevier B.V. All rights reserved.

  9. Development of a novel oxirane-acrylate composite restorative resin material

    Science.gov (United States)

    Sripathi Panditaradhyula, Anuhya

    The need for resin with a long clinical life can be satiated through the novel formulation of varying concentrations of oxirane and acrylate monomers with an increase in filler loading in the sample, which will allow the creation of a resin that is less susceptible to chemical degradation along with improved mechanical properties. Various concentrations of oxirane and acrylate monomers with a three-component photoinitiation system, which is capable of both free radical (acrylate) and cationic (oxirane) initiation, are used. The resin composites were placed in the Speedmixer for 30 seconds and gravitation convection oven for one minute, repeated 5-7 times. The resin composites were used to create a 9.525 mm diameter * 1.5875 mm thick resin mold. The mold was then photocured for twenty seconds on both sides using VALO blue LED light. The Rockwell hardness and shore D durometer hardness served as relative measures of bonding between the monomers. The ideal formulation of oxirane and acrylate concentrations were used to perform the Instron 3 point bend test, as well as contact angle determination. The goal is to identify a resin with a clinical life twice that of the resins being used in practice. Potential findings include ideal oxirane and acrylate concentrations with the highest shore D durometer hardness, Rockwell hardness, contact angle values, and Instron 3 point bend test values. Ideal color, transparency and properties of the resin are taken into account. Optimization of oxirane and acrylate monomers, impact while using various filler components (salination, number of fillers), filler particle size variations and variations in using different filler concentrations are observed. Results of using micro and nano-sized monomers are also studied. Addition of fluorinated acrylate monomer to the micro and nano composite was the next goal. A comparison of all the above stated compositions to the control group 70/30 BisTEG was done. A study on the degradation behavior

  10. Comparison effect of artificial tooth type and cyclic loading on the bond strength to auto-polymerized acrylic denture base resins

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    Fateme Nematollahi

    2013-05-01

    Full Text Available   Background and Aims: Failure of bonding between artificial teeth and denture base material is a considerable problem for patients who wear dentures. According to the different impact of artificial teeth and different information about resistance force of mastication and also with deficiency in researchs, this study was designed to compare the bond strength of composite and acrylic artificial teeth to auto-polymerized denture base resins with and without cyclic loading.   Materials and Methods: In this experimental and in vitro study, an acrylic resin auto-polymerized (Rapid Repair, Dentsply and four artificial teeth (Acrylic Marjan new, Composite Glamour teeth and Ivoclar acrylic and composite teeth were used. Therefore, 8 groups of 10 specimens each were evaluated. All specimens were thermocycled for 5000 cycles, in water baths between 5 and 55 ◦ C. Half the specimens in each group were treated with cyclic loading at 50N for 14, 400 cycles at 1.2 Hz. The shear bond strengths were measured using a Universal Testing Machine. Data were analyzed using Two-way ANOVA test.   Results: Statistical analysis demonstrated no significant effect of cyclic loading on the shear bond strength, but the type of artificial tooth affected the shear bond strength (P=0.006. Also, the interaction between Cyclic loading and the type of artificial tooth showed no significant difference (P=0.98. Tukey test showed that acrylic teeth (Ivoclar had statistically higher bond strength values than that of other teeth (PGlamour=0.02, (PComposite ivoclar=0.01 and (PMarjan new=0.02.   Conclusion: Within the limitation of this study, the predominant type of fracture in all groups was cohesive, therefore the bond strength was adequate in all teeth and the type of artificial tooth may influence the bond strength of denture teeth to denture base resin. Cyclic loading had no significant effect on the bond strength of denture teeth to the auto-polymerized acrylic resin.

  11. The Influence of the Constitution of Acrylate Copolymers on Electrochromic Properties of Their Pan Composite Coatings

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Several polyacrylate matrixes were prepared with monomers such as methyl methacrylate,KH-570,acrylic acid and butyl acrylate,and the electrochromic behavior of their soluble Pan composite coatings was also studied by electrochemical analysis and spectrophotometry.It shows that the constitution of the polymer matrixes have great effects on the electrochromic process and the color change of the composite coatings.When the matrix consists of acrylic acid unit,Pan of both interior and exterior composite possesses the same electrochemical reactivity,shorter responding time and wider color-changing range.But it is contrary when matrixes contain no acrylic acid.Furthermore,the composite containing acrylic acid units has still electrochemical reactivity in distilled water instead of LiClO4-PC electrolyte.

  12. Effects of composition and layer thickness of a butyl acrylate/acrylic acid copolymer on the adhesion properties

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    Ghim, Deoukchen; Kim, Jung Hyeun [University of Seoul, Seoul (Korea, Republic of)

    2016-02-15

    Acrylic pressure-sensitive adhesives are synthesized by solution copolymerization using n-butyl acrylate and acrylic acid (AA) in ethyl acetate anhydrous. The copolymer composition is controlled for good adhesive properties by varying AA content. The monomer conversion is measured by the gravimetric method and FTIR technique. The adhesive layer thickness is measured by scanning electron microscopy, and the adhesive properties are evaluated with loop tack, 180 .deg. peel, and holding time measurements. The peel force increases with increasing the AA content up to 3 wt% and decreases at the AA content higher than 3 wt%, but the tack force decreases with increasing the AA content. The holding time increases with increasing the AA content, and it shows a similar trend with the T{sub g} of adhesives. The increase of layer thickness improves tack and peel forces, but it weakens the holding power. A tape thickness of about 20 μm shows well-balanced properties at 3 wt% AA content in the acrylic copolymer system.

  13. Synthesis of Acrylic Acid/Kaoline Powder Superabsorbent Composite by Inverse-suspending Polymerization

    Institute of Scientific and Technical Information of China (English)

    ZHONG Jin-feng; XUE Yi-ming; WU Ji-huai; LIN Jian-ming; WEI Yue-lin

    2004-01-01

    An acrylic acid/kaoline powder superabsorbent composite with a water absorbency of the superabsorbent composite about 1/800 was synthesized by inverse-suspending polymerization reaction between acrylic acid monomer and kaoline ultrafine powder. The influence of the dispersant agent on the configuration of the products in the inverse suspension polymerization is investigated. The influences of the kaoline powder, cross-linker, initiator, neutralization degree and the volume ratio of oil to water phase on the water absorbency of the superabsorbent composites are discussed in the paper.

  14. Loading rate effects on the fracture of Ni/Au nano-coated acrylic particles

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    Z. L. Zhang

    2012-03-01

    Full Text Available Mechanical failure of monodisperse Ni/Au coated acrylic particles has been investigated by individual compression tests using nanoindentation-based technique equipped with a flat diamond punch. We have found that both fracture property and morphology of particles depend on the compression loading rate. The breaking strain of the metal coating decreases with increasing loading rate, while the breaking stress increases. Two obvious fracture patterns with cracking in meridian or latitude direction are identified according to the loading rate, and attributed respectively to tension- or bendingdominated deformation of the coating. The findings reported here give a significant guiding to the manufacture design of metal coated polymer particles for Anisotropic Conductive Adhesive (ACA packaging.

  15. In situ reactive compatibilization of natural rubber/acrylic-bentonite composites via peroxide-induced vulcanization

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Lihua; Lei, Zhiwen [Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004 (China); Xu, Chuanhui, E-mail: xuhuiyee@gxu.edu.cn [Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004 (China); Chen, Yukun, E-mail: cyk@scut.edu.cn [The Key Laboratory of Polymer Processing Engineering, Ministry of Education, China(South China University of Technology), Guangzhou, 510640 (China)

    2016-02-15

    To achieve good interfacial interaction between fillers and rubber matrix is always a hot topic in rubber reinforcing industry. In this paper, acid activated bentonite (Bt) was alkalified to be alkaline calcium-bentonite (ACBt), then acrylic acid (AA) was employed to modify ACBt to obtain acrylic-bentonite (ABt). The results of Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) illustrated that acrylate groups were chemically boned onto the surface of Bt and the layer spacing of Bt was increased. During peroxide-induced vulcanization, in situ compatibilization of ABt was realized via the reaction between the unsaturated bonds of acrylate groups on the surface of Bt and the natural rubber (NR) chains. This resulted in an enhanced cross-linked network which contributed to the improved mechanical properties of NR/ABt composites. - Highlights: • Acrylate groups were chemically boned onto the surface of bentonite. • In situ compatibilization was realized via the reaction of acrylate group and NR. • ABt particles participated in forming the NR crosslink network. • A potential reinforcing material options for “white” rubber products.

  16. Poly(acrylic acid) microspheres loaded with lidocaine: preparation and characterization for arterial embolization.

    Science.gov (United States)

    Cui, Dai-Chao; Lu, Wan-Liang; Sa, Er-A; Gu, Meng-Jie; Lu, Xiao-Jing; Fan, Tian-Yuan

    2012-10-15

    A new embolic agent, poly(acrylic acid) microspheres (PMs), was synthesized and the cytocompatibility was proved by mouse L929 fibroblast cells. An analgesic drug, lidocaine, was loaded on the PMs to relief pain caused by embolization. PMs and lidocaine loaded microspheres (LMs) were characterized by investigating infrared spectrum, morphology, particle size, and equilibrium water contents (EWC). A series of tests were employed to evaluate the elasticity of PMs, LMs and Embosphere™, including once compression, twice compression, and stress relaxation test. The pressures of PMs and LMs passing through a catheter were measured on line by our new designed device. Drug release was studied with T-cell apparatus. The properties of PMs and LMs were proved to be suitable for embolization. Both PMs and LMs in this study might be potential embolic agents in the future.

  17. Antibiotic elution from acrylic bone cement loaded with high doses of tobramycin and vancomycin.

    Science.gov (United States)

    Slane, Joshua; Gietman, Bradley; Squire, Matthew

    2017-09-06

    Two-stage revision treatment of prosthetic joint infection (PJI) frequently employs the use of a temporary bone cement spacer loaded with multiple antibiotic types. Tobramycin and vancomycin are commonly used antibiotics in cement spacers, however, there is no consensus on the relative concentrations and combinations that should be used. Therefore, the purpose of this study was to investigate the influence of dual antibiotic loading on the total antibiotic elution and compressive mechanical properties of acrylic bone cement. Varying concentrations of tobramycin (0-3 g) and vancomycin (0-3 g) were added either alone or in combination to acrylic cement (Palacos R), resulting in 12 experimental groups. Samples were submerged in 37°C saline for 28 d and sampled at specific time points. The collected eluent was analyzed to determine the cumulative antibiotic release. In addition, the cement's compressive mechanical properties and porosity were characterized. Interestingly, the cement with the highest concentration of antibiotics did not possess the best elution properties. Cement samples containing both 3 g of tobramycin and 2 g vancomycin demonstrated the highest cumulative antibiotic release after 28 d, which was coupled with a significant decrease in the mechanical properties and an increased porosity. The collected data also suggests that tobramycin elutes more effectively than vancomycin from cement. In conclusion, this study demonstrates that high antibiotic loading in cement does not necessarily lead to enhanced antibiotic elution. Clinically this information may be used to optimize cement spacer antibiotic loading so that both duration and amount of antibiotics eluted are optimized. © 2017 Orthopaedic Research Society. Published by Wiley Periodicals, Inc. J Orthop Res. © 2017 Orthopaedic Research Society. Published by Wiley Periodicals, Inc.

  18. Polypyrrole-coated styrene-butyl acrylate copolymer composite particles with tunable conductivity

    Institute of Scientific and Technical Information of China (English)

    HUANG Liyan; HOU Wenbo; LIU Zhengping; ZHANG Qingyue

    2005-01-01

    A series of near or monodisperse styrene-butyl acrylate (SBA) copolymer latex particles with different butyl acrylate contents were coated with polypyrrole. The structure of the SBA/PPy composites was characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), diffuse reflectance infrared Fourier transform spectroscopy (DRIFT), X-ray photoelectron spectroscopy (XPS), differential scanning calorimetry (DSC) and standard four-probe method. The core-shell morphology of the SBA/PPy composite particles was confirmed. The result of DSC showed that Tg of the composite is mainly determined by the core component. The effects of the concentration of polypyrrole, the butyl acrylate content in SBA copolymer and the nature of the counter-anion on the electrical conductivity of compression-moulded samples were studied. It was first found that the electrical conductivity of the samples can be tuned by varying the butyl acrylate content in SBA copolymer and the highest conductivity of the core-shell composite was 0.17 S·cm-1.

  19. A comparative study to determine strength of autopolymerizing acrylic resin and autopolymerizing composite resin influenced by temperature during polymerization: An In Vitro study.

    Science.gov (United States)

    Chhabra, Anuj; Rudraprasad, I V; Nandeeshwar, D B; Nidhi, C

    2017-01-01

    Temporary coverage of a prepared tooth is an important step during various stages of the fixed dental prosthesis. Provisional restorations should satisfy proper mechanical requirements to resist functional and nonfunctional loads. A few studies are carried out regarding the comparison of the effect of curing environment, air and water, on mechanical properties of autopolymerizing acrylic and composite resin. Hence, the aim of this study was to compare the transverse strength of autopolymerizing acrylic resin and autopolymerizing composite resin as influenced by the temperature of air and water during polymerization. Samples of autopolymerizing acrylic resin and composite resin were prepared by mixing as per manufacturer's instructions and were placed in a preformed stainless steel mold. The mold containing the material was placed under different controlled conditions of water temperature and air at room temperature. Polymerized samples were then tested for transverse strength using an Instron universal testing machine. Alteration of curing condition during polymerization revealed a significant effect on the transverse strength. The transverse strength of acrylic resin specimens cured at 60°C and composite resin specimens cured at 80°C was highest. Polymerizing the resin in cold water at 10°C reduced the mechanical strength. Polymerization of the resin in hot water greatly increased its mechanical properties. The method of placing resin restoration in hot water during polymerization may be useful for improving the mechanical requirements and obtaining long-lasting performance.

  20. Influence of load on the dry frictional performance of alkyl acrylate copolymer elastomers coated with diamond-like carbon films

    NARCIS (Netherlands)

    Martinez, D. Martinez; Nohava, Jiri; De Hosson, J. Th. M.

    2015-01-01

    In this work, the influence of applied load on the frictional behavior of alkyl acrylate copolymer elastomers coated with diamond- like carbon films is studied at dry conditions. The performance of two coatings with very different microstructure (patched vs. continuous film) is compared with the unc

  1. Bond Strength of Repaired Acrylic Denture Teeth Using Visible Light Cure Composite Resin.

    Science.gov (United States)

    Muhsin, Saja Ali

    2017-01-01

    Although bonding to denture teeth after surface treatment with chemical agents is desirable, there is little information on the use of Visible Light Cure composite resin (VLC) as bonding denture materials. To determine the effect of various surface treatments on shear bond strength between Visible Light Cure composite resin and the acrylic denture teeth interface. Forty cylindrical sticks of acrylic resin with denture teeth mounted atop were prepared. Various treatments were implemented upon the acrylic resin teeth surfaces. The samples were divided into four groups (n = 10). Light-cured composite resin (LC) was applied over all treated and untreated surfaces of tested groups. The shear bond was tested using a universal tensile testing apparatus with the knife-edge of a 0.8mm shear tester. Data were statistically analyzed using one-way ANOVA performed at a confidence level of 95% and significant P-value of (P ≤ 0.05). Analysis of variance (ANOVA) showed statistically significant difference (P resin denture teeth resulted in maximum bond strength with composite resin.

  2. Preparation and drug-loading properties of Fe3O4/Poly(styrene-co-acrylic acid) magnetic polymer nanocomposites

    Science.gov (United States)

    Lu, Wensheng; Shen, Yuhua; Xie, Anjian; Zhang, Weiqiang

    2013-11-01

    Fe3O4/poly(styrene-co-acrylic acid) magnetic polymer nanocomposites were synthesized by the dispersion polymerization method using styrene as hard monomer, acrylic acid as functional monomer, Fe3O4 nanoparticles modified with oleic acid as core, and poly(styrene-co-acrylic acid) as shell. Drug-loading properties of magnetic polymer nanocomposites with curcumin as a model drug were also studied. The results indicated that magnetic polymer nanocomposites with monodisperse were obtained, the particle size distribution was 50-120 nm, and the average size was about 100 nm. The contents of poly(styrene-co-acrylic acid) and Fe3O4 nanoparticles in magnetic polymer nanocomposites were 74% and 24.7%, respectively. The drug-loading capacity and entrapment efficiency were 2.5% and 44.4%, respectively. The saturation magnetization of magnetic polymer nanocomposites at 300 K was 20.2 emu/g without coercivity and remanence. The as-prepared magnetic polymer nanocomposites have not only lots of functional carboxyl groups but also stronger magnetic response, which might have potential applications in drug carrier and targeted drug release.

  3. A temporary space maintainer using acrylic resin teeth and a composite resin.

    Science.gov (United States)

    Kochavi, D; Stern, N; Grajower, R

    1977-05-01

    A one-session technique for preparing a temporary space maintainer has been described. The technique consists of attaching an acrylic resin pontic to etched surfaces of natural adjacent teeth by means of a composite resin. The main advantages of this technique are elimination of premature tooth preparation, good esthetics, fair strength, low cost, and rapid completion of the restoration without the need of a dental laboratory.

  4. A Study on Effect of Surface Treatments on the Shear Bond Strength between Composite Resin and Acrylic Resin Denture Teeth.

    Science.gov (United States)

    Chatterjee, Nirmalya; Gupta, Tapas K; Banerjee, Ardhendu

    2011-03-01

    Visible light-cured composite resins have become popular in prosthetic dentistry for the replacement of fractured/debonded denture teeth, making composite denture teeth on partial denture metal frameworks, esthetic modification of denture teeth to harmonize with the characteristics of adjacent natural teeth, remodelling of worn occlusal surfaces of posterior denture teeth etc. However, the researches published on the bond strength between VLC composite resins and acrylic resin denture teeth is very limited. The purpose of this study is to investigate the effect of five different methods of surface treatments on acrylic resin teeth on the shear bond strength between light activated composite resin and acrylic resin denture teeth. Ninety cylindrical sticks of acrylic resin with denture teeth mounted atop were prepared. Various treatments were done upon the acrylic resin teeth surfaces. The samples were divided into six groups, containing 15 samples each. Over all the treated and untreated surfaces of all groups, light-cured composite resin was applied. The shear strengths were measured in a Universal Testing Machine using a knife-edge shear test. Data were analyzed using one way analysis of variance (ANOVA) and mean values were compared by the F test. Application of bonding agent with prior treatment of methyl methacrylate on the acrylic resin denture teeth resulted in maximum bond strength with composite resin.

  5. Preparation, characterization, and antibacterial activity studies of silver-loaded poly(styrene-co-acrylic acid) nanocomposites.

    Science.gov (United States)

    Song, Cunfeng; Chang, Ying; Cheng, Ling; Xu, Yiting; Chen, Xiaoling; Zhang, Long; Zhong, Lina; Dai, Lizong

    2014-03-01

    A simple method for preparing a new type of stable antibacterial agent was presented. Monodisperse poly(styrene-co-acrylic acid) (PSA) nanospheres, serving as matrices, were synthesized via soap-free emulsion polymerization. Field-emission scanning electron microscopy micrographs indicated that PSA nanospheres have interesting surface microstructures and well-controlled particle size distributions. Silver-loaded poly(styrene-co-acrylic acid) (PSA/Ag-NPs) nanocomposites were prepared in situ through interfacial reduction of silver nitrate with sodium borohydride, and further characterized by transmission electron microscopy and X-ray diffraction. Their effects on antibacterial activity including inhibition zone, minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC), and bactericidal kinetics were evaluated. In the tests, PSA/Ag-NPs nanocomposites showed excellent antibacterial activity against both gram-positive Staphylococcus aureus and gram-negative Escherichia coli. These nanocomposites are considered to have potential application in antibacterial coatings on biomedical devices to reduce nosocomial infection rates.

  6. Fabrication and Characterization of Gd-DTPA-Loaded Chitosan-Poly(Acrylic Acid) Nanoparticles for Magnetic Resonance Imaging.

    Science.gov (United States)

    Ahmed, Arsalan; Zhang, Chao; Guo, Jian; Hu, Yong; Jiang, Xiqun

    2015-08-01

    Gd-DTPA-loaded chitosan-poly(acrylic acid) nanoparticles (Gd-DTPA@CS-PAA NPs) were formulated based on the reaction system of water-soluble polymer-monomer pairs of acrylic acid in chitosan solution followed by sorption of Gd-DTPA. Morphological investigations revealed the spherical shape of these NPs with about 220 nm particle size. These NPs showed charge reversal characteristic in acidic solution. In vitro and in vivo magnetic characteristics of these NPs were explored to estimate their utilization in targeted enhanced magnetic resonance imaging. Relaxation studies showed that these NPs possessed pH susceptible relaxation properties, which could introduce in vivo-specific distribution of contrast agent. MRI experiment showed that these nanoparticles had better results in contrast enhancement, and the concentration of contrast agent increased in liver and brain with increment in time. Thus, these NPs could maintain in vivo long circulation and high relaxation rate and were suitable agents for magnetic resonance imaging.

  7. Shear bond strength of composite veneers and acrylic veneer bonded to ni-cr alloy: a laboratory study.

    Science.gov (United States)

    Katyayan, Manish; Katyayan, Preeti; Ravishankar, K

    2011-06-01

    A growing number of composite materials are being used as an alternative for veneering cast restorations. The objective of this investigation was to evaluate and compare the shear bond strength of UDMA based composite, restorative composite, and heat cure acrylic when veneered to Ni-Cr alloy and to evaluate the type of bond failure. Three different veneering materials were used: heat cure acrylic, UDMA based composite and a restorative composite. 10 samples were fabricated, each with heat cure acrylic and restorative composite and 20 samples were fabricated with UDMA based composite; thus, the total number of samples amounted to 40. All the samples were subject to shear bond stress fracture tests and observed for the type of bond failure. The greatest mean shear bond strength was recorded in relation to the UDMA based composite material when thermal conducting paste was used during the curing (10.51 MPa). The mean bond strength values of UDMA based composite without thermal conducting paste (8.92 MPa), heat cured acrylic veneering material (4.24 MPa) and restorative composite material (5.03 MPa) were significantly different from each other (p > 0.05). Samples veneered with heat cure acrylic veneering material and restorative composite material showed adhesive failure. Samples prepared with UDMA based composite veneering composite showed cohesive or predominantly cohesive failure. UDMA based composite veneering material when used with heat protection paste exceeds the shear bond strength requirement as suggested by Matsumura et al. (>10 MPa). A statistically significant association between the test groups and the type of failure was observed.

  8. Multi-walled carbon nanotubes/polymer composites in absence and presence of acrylic elastomer (ACM).

    Science.gov (United States)

    Kumar, S; Rath, T; Mahaling, R N; Mukherjee, M; Khatua, B B; Das, C K

    2009-05-01

    Polyetherimide/Multiwall carbon nanotube (MWNTs) nanocomposites containing as-received and modified (COOH-MWNT) carbon nanotubes were prepared through melt process in extruder and then compression molded. Thermal properties of the composites were characterized by thermo-gravimetric analysis (TGA). Field emission scanning electron microscopy (FESEM) images showed that the MWNTs were well dispersed and formed an intimate contact with the polymer matrix without any agglomeration. However the incorporation of modified carbon nanotubes formed fascinating, highly crosslinked, and compact network structure throughout the polymer matrix. This showed the increased adhesion of PEI with modified MWNTs. Scanning electron microscopy (SEM) also showed high degree of dispersion of modified MWNTs along with broken ends. Dynamic mechanical analysis (DMA) results showed a marginal increase in storage modulus (E') and glass transition temperature (T(g)) with the addition of MWNTs. Increase in tensile strength and impact strength of composites confirmed the use the MWNTs as possible reinforcement agent. Both thermal and electrical conductivity of composites increased, but effect is more pronounced on modification due to formation of network of carbon nanotubes. Addition of acrylic elastomer to developed PEI/MWNTs (modified) nanocomposites resulted in the further increase in thermal and electrical properties due to the formation of additional bond between MWNTs and acrylic elastomers at the interface. All the results presented are well corroborated by SEM and FESEM studies.

  9. Injectable biocompatible and biodegradable pH-responsive hollow particle gels containing poly(acrylic acid): the effect of copolymer composition on gel properties.

    Science.gov (United States)

    Halacheva, Silvia S; Adlam, Daman J; Hendow, Eseelle K; Freemont, Tony J; Hoyland, Judith; Saunders, Brian R

    2014-05-12

    The potential of various pH-responsive alkyl (meth)acrylate ester- and (meth)acrylic acid-based copolymers, including poly(methyl methacrylate-co-acrylic acid) (PMMA-AA) and poly(n-butyl acrylate-co-methacrylic acid) (PBA-MAA), to form pH-sensitive biocompatible and biodegradable hollow particle gel scaffolds for use in non-load-bearing soft tissue regeneration have been explored. The optimal copolymer design criteria for preparation of these materials have been established. Physical gels which are both pH- and redox-sensitive were formed only from PMMA-AA copolymers. MMA is the optimal hydrophobic monomer, whereas the use of various COOH-containing monomers, e.g., MAA and AA, will always induce a pH-triggered physical gelation. The PMMA-AA gels were prepared at physiological pH range from concentrated dispersions of swollen, hollow, polymer-based particles cross-linked with either cystamine (CYS) or 3,3'-dithiodipropionic acid dihydrazide (DTP). A linear relationship between particle swelling ratios, gel elasticity, and ductility was observed. The PMMA-AA gels with lower AA contents feature lower swelling ratios, mechanical strengths, and ductilities. Increasing the swelling ratio (e.g., through increasing AA content) decreased the intraparticle elasticity; however, intershell contact and gel elasticity were found to increase. The mechanical properties and performance of the gels were tuneable upon varying the copolymers' compositions and the structure of the cross-linker. Compared to PMMA-AA/CYS, the PMMA-AA/DTP gels were more elastic and ductile. The biodegradability and cytotoxicity of the new hollow particle gels were tested for the first time and related to their composition, mechanical properties, and morphology. The new PMMA-AA/CYS and PMMA-AA/DTP gels have shown good biocompatibility, biodegradability, strength, and interconnected porosity and therefore have good potential as a tissue repair agent.

  10. Investigation of Regenerated Cellulose/Poly(acrylic acid Composite Films for Potential Wound Healing Applications: A Preliminary Study

    Directory of Open Access Journals (Sweden)

    Manjula Bajpai

    2014-01-01

    Full Text Available Regenerated cellulose/poly(acrylic acid composite films have been synthesized for wound dressing applications. The water absorbency of these films was studied as a function of amount of cross-linker N,N′-methylenebisacrylamide and cellulose contents in the feed mixture. The samples, having different compositions, showed tensile strength and percent elongation in the range of 9.98×105 to 13.40×105 N/m2 and 110 to 265, respectively. The water vapor transmission rate (WVTR for various films was found to be in the range of 2.03 to 7.18 mg/cm2/h. These films were loaded with antibacterial drug miconazole nitrate and their release was studied in the physiological pH at 37°C. The release data was found to fit well the diffusion controlled Higuchi model. Finally the films demonstrated fair antibacterial and antifungal action, thus establishing their strong candidature as wound dressing materials.

  11. Ultrasensitive Biosensor for the Detection of Vibrio cholerae DNA with Polystyrene-co-acrylic Acid Composite Nanospheres

    Science.gov (United States)

    Rahman, Mahbubur; Heng, Lee Yook; Futra, Dedi; Ling, Tan Ling

    2017-08-01

    An ultrasensitive electrochemical biosensor for the determination of pathogenic Vibrio cholerae ( V. cholerae) DNA was developed based on polystyrene-co-acrylic acid (PSA) latex nanospheres-gold nanoparticles composite (PSA-AuNPs) DNA carrier matrix. Differential pulse voltammetry (DPV) using an electroactive anthraquninone oligonucleotide label was used for measuring the biosensor response. Loading of gold nanoparticles (AuNPs) on the DNA-latex particle electrode has significantly amplified the faradaic current of DNA hybridisation. Together with the use of a reported probe, the biosensor has demonstrated high sensitivity. The DNA biosensor yielded a reproducible and wide linear response range to target DNA from 1.0 × 10-21 to 1.0 × 10-8 M (relative standard deviation, RSD = 4.5%, n = 5) with a limit of detection (LOD) of 1.0 × 10-21 M ( R 2 = 0.99). The biosensor obtained satisfactory recovery values between 91 and 109% ( n = 3) for the detection of V. cholerae DNA in spiked samples and could be reused for six consecutive DNA assays with a repeatability RSD value of 5% ( n = 5). The electrochemical biosensor response was stable and maintainable at 95% of its original response up to 58 days of storage period.

  12. Synthesis of polyoxometalate-loaded epoxy composites

    Science.gov (United States)

    Anderson, Benjamin J

    2014-10-07

    The synthesis of a polyoxometalate-loaded epoxy uses a one-step cure by applying an external stimulus to release the acid from the polyoxometalate and thereby catalyze the cure reaction of the epoxy resin. Such polyoxometalate-loaded epoxy composites afford the cured epoxy unique properties imparted by the intrinsic properties of the polyoxometalate. For example, polyoxometalate-loaded epoxy composites can be used as corrosion resistant epoxy coatings, for encapsulation of electronics with improved dielectric properties, and for structural applications with improved mechanical properties.

  13. Preparation, characterization, and antibacterial activity studies of silver-loaded poly(styrene-co-acrylic acid) nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Song, Cunfeng [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Chang, Ying; Cheng, Ling; Xu, Yiting [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Chen, Xiaoling, E-mail: tinachen0628@163.com [Department of Endodontics, Xiamen Stomatology Hospital, Teaching Hospital of Fujian Medical University, Xiamen 361003 (China); Zhang, Long; Zhong, Lina [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Dai, Lizong, E-mail: lzdai@xmu.edu.cn [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China)

    2014-03-01

    A simple method for preparing a new type of stable antibacterial agent was presented. Monodisperse poly(styrene-co-acrylic acid) (PSA) nanospheres, serving as matrices, were synthesized via soap-free emulsion polymerization. Field-emission scanning electron microscopy micrographs indicated that PSA nanospheres have interesting surface microstructures and well-controlled particle size distributions. Silver-loaded poly(styrene-co-acrylic acid) (PSA/Ag-NPs) nanocomposites were prepared in situ through interfacial reduction of silver nitrate with sodium borohydride, and further characterized by transmission electron microscopy and X-ray diffraction. Their effects on antibacterial activity including inhibition zone, minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC), and bactericidal kinetics were evaluated. In the tests, PSA/Ag-NPs nanocomposites showed excellent antibacterial activity against both gram-positive Staphylococcus aureus and gram-negative Escherichia coli. These nanocomposites are considered to have potential application in antibacterial coatings on biomedical devices to reduce nosocomial infection rates. - Highlights: • A new type of antibacterial agent (PSA/Ag-NPs nanocomposites) was synthesized. • The antibacterial activity against S. aureus and E. coli was studied. • Inhibition zone, MIC, MBC, and bactericidal kinetics were evaluated. • PSA/Ag-NPs nanocomposites showed excellent antibacterial activity.

  14. Nano ZnO/amine composites antimicrobial additives to acrylic paints

    Directory of Open Access Journals (Sweden)

    H.B. Kamal

    2015-12-01

    Full Text Available Nano ZnO has been widely used as an antimicrobial agent not only for food packaging purposes but also in many coating processes. The present work is meant to enhance such functions through the preparation of sustainable and safe conduct of nano ZnO composites with amine derivatives that are characterized by their antimicrobial and anti-fouling functional activities. The results obtained revealed a more comprehensive approach to the antimicrobial function based on the reported active oxide species role. The oxide/amine composites and the acrylic emulsion paint were characterized chemically and structurally through FT-IR, TGA and TEM supported by biological assessment of each ZnO/amine composite action. Results of the study concluded that equilibrium between the nano ZnO particles size, their dispersion form, and amine ability to stabilize the actively produced oxygen species responsible for the antimicrobial function, should all be accounted for when persistence of antimicrobial agent efficiency is regarded.

  15. A novel poly(acrylic acid-co-acrylamide)/diatomite composite flocculant with outstanding flocculation performance.

    Science.gov (United States)

    Xu, Kun; Liu, Yao; Wang, Yang; Tan, Ying; Liang, Xuecheng; Lu, Cuige; Wang, Haiwei; Liu, Xiusheng; Wang, Pixin

    2015-01-01

    Series of anionic flocculants with outstanding flocculation performance, poly(acrylic acid-co-acrylamide)/diatomite composite flocculants (PAAD) were successfully prepared through aqueous solution copolymerization and applied to flocculate from oil-field fracturing waste-water. The structure of PAAD was characterized by Fourier transform infra-red spectroscopy, (13)C nuclear magnetic resonance and X-ray diffraction tests, and its properties were systematically evaluated by viscometer, thermogravimetry analysis and flocculation measurements. Furthermore, the influences of various reaction parameters on the apparent viscosity of flocculant solution were studied, and the optimum synthesis condition was determined. The novel composite flocculants exhibited outstanding flocculation properties. Specifically, the dosage of composite flocculants that could make the transmittance of treated wastewater exceed 90% was only approximately 12-35 ppm, which was far lower than that of conventional flocculants. Meanwhile, the settling time was lower than 5 s, which was similar to that of conventional flocculants. This was because PAAD flocculants had a higher absorption capacity, and larger chain extending space than conventional linear flocculants, which could refrain from the entanglement of linear polymer chains and significantly improve flocculation capacity.

  16. Comparative Analysis of Electromagnetic Response of PVA/MWCNT and Styrene-Acrylic Copolymer/MWCNT Composites

    Science.gov (United States)

    Plyushch, A. O.; Paddubskaya, A. G.; Kuzhir, P. P.; Maksimenko, S. A.; Ivanova, T.; Merijs-Meri, R.; Bitenieks, J.; Zicans, J.; Suslyaev, V. I.; Pletnev, M. A.

    2016-06-01

    The present paper focuses on electromagnetic response of polymeric composites with different concentrations of multiwall carbon nanotubes in the radio (20 Hz - 1 MHz) and microwave (26-36 GHz) frequency ranges. Widely available polymeric materials, such as PVA latex (polyvinyl acetate) and styrene-acrylic copolymer, were used as a matrix. Analysis of the experimental data demonstrated that in electromagnetic shielding applications one should give preference to the styrene-acrylic copolymer, as far as application of this matrix type allows reducing the percolation threshold in such composites. As a result, it allows reaching the necessary level of shielding at a lower filler concentration, while unique properties of the chosen polymer allow expanding the range of applications for the new materials.

  17. Synthesis and characterization of a sphere-like modified chitosan and acrylate resin composite for organics absorbency

    Science.gov (United States)

    Xin, S. S.; Wang, Y. H.; Li, Q. R.; Zhang, Q.; Wang, X. P.

    2015-07-01

    In this study, the chitosan (deacetylation degree >95%) was modified with vinyltriethoxysilane (A151) and became hydrophobic. The modified chitosan and acrylate resin composite can be synthesized by butyl methacrylate (BMA), butyl acrylate (BA), poly vinyl alcoho(PVA), N,N’-methylene bisacrylamide (MBA), benzoyl peroxide (BPO), and ethyl acetate under microwave irradiation. The optimal synthetic condition was as follows: the molar ratio of BA and BMA was 1.5:1, the dosage of ethyl acetate, PVA, MBA, BPO and modified chitosan were 50 wt.%, 10 wt.%, 1.5 wt.%, 2.0 wt.% and 1.0 wt.% of monomers, respectively. The adsorption capacity of the composite for CHCl3 and CCl4 were approximate to 53 g/g and 44 g/g, respectively. The organics absorbency and regeneration of the samples were also tested, and the samples were characterized by analysis of the scanning electron microscope and simultaneous thermo gravimetric/differential thermal.

  18. Fabrication and mechanical characterization of graphene oxide-reinforced poly (acrylic acid)/gelatin composite hydrogels

    Science.gov (United States)

    Faghihi, Shahab; Gheysour, Mahsa; Karimi, Alireza; Salarian, Reza

    2014-02-01

    Hydrogels have found many practical uses in drug release, wound dressing, and tissue engineering. However, their applications are restricted due to their weak mechanical properties. The role of graphene oxide nanosheets (GONS) as reinforcement agent in poly (acrylic acid) (PAA)/Gelatin (Gel) composite hydrogels is investigated. Composite hydrogels are synthesized by thermal initiated redox polymerization method. Samples are then prepared with 20 and 40 wt. % of PAA, an increasing amount of GONS (0.1, 0.2, and 0.3 wt. %), and a constant amount of Gel. Subsequently, cylindrical hydrogel samples are subjected to a series of compression tests in order to measure their elastic modulus, maximum stress and strain. The results exhibit that the addition of GONS increases the Young's modulus and maximum stress of hydrogels significantly as compared with control (0.0 wt. % GONS). The highest Young's modulus is observed for hydrogel with GO (0.2 wt. %)/PAA (20 wt. %), whereas the highest maximum stress is detected for GO (0.2 wt. %)/PAA (40 wt. %) specimen. The addition of higher amounts of GONS leads to a decrease in the maximum stress of the hydrogel GO (0.3 wt. %)/PAA (40 wt. %). No significant differences are detected for the maximum strain among the hydrogel samples, as the amount of GONS increased. These results suggest that the application of GONS could be used to improve mechanical properties of hydrogel materials. This study may provide an alternative for the fabrication of low-cost graphene/polymer composites with enhanced mechanical properties beneficial for tissue engineering applications.

  19. Experimental characterization of composites. [load test methods

    Science.gov (United States)

    Bert, C. W.

    1975-01-01

    The experimental characterization for composite materials is generally more complicated than for ordinary homogeneous, isotropic materials because composites behave in a much more complex fashion, due to macroscopic anisotropic effects and lamination effects. Problems concerning the static uniaxial tension test for composite materials are considered along with approaches for conducting static uniaxial compression tests and static uniaxial bending tests. Studies of static shear properties are discussed, taking into account in-plane shear, twisting shear, and thickness shear. Attention is given to static multiaxial loading, systematized experimental programs for the complete characterization of static properties, and dynamic properties.

  20. Preparation and the Drug Release Behavior of Diclofenac Sodium-Loaded Psyllium-g-poly ( acrylic acid)/Attapulgite/Sodium Alginate Hydrogel Composite Beads%PSY-g-PAA/APT/SA载药复合凝胶小球的制备及释药性能

    Institute of Scientific and Technical Information of China (English)

    杨会霞; 张俊平; 王文波; 王爱勤

    2012-01-01

    采用离子凝胶法制备了欧车前胶-g聚丙烯酸/凹凸棒黏土/海藻酸钠(PSY-g-PAA/APT/SA)载药复合凝胶小球,以双氯芬酸钠为模型药物,考察了pH敏感性和凹凸棒黏土含量对凝胶小球的包封率、载药率、溶胀性能和药物释放行为的影响.结果表明,当释放介质为模拟胃液(pH=1.2)时,药物基本不释放;而为模拟肠液(pH=6.8)时,5h后累积释放率超过90%,复合凝胶小球具有明显的pH敏感性.随着凝胶小球中凹凸棒黏土含量的增加,溶胀率和药物累积释放率均减小,表明凹凸棒黏土的引入可以减缓药物的突释效应.%A novel psyllium-g-poly(acrylic acid)/attapulgite/sodium alginate(PSY-g-PAA/APT/SA) hydrogel composite beads were prepared by the ionic gelation technique. Effects of attapulgite( APT) content on the swelling property, encapsulation efficiency, drug release behaviors were investigated using diclofenac sodium(DS) as a model drug. pH-sensitive properties and in vitro release kinetics of DS from the hydrogel beads were also studied. The results indicated that with increasing attapulgite content of the prepared hydrogel beads, the swelling ratio and encapsulation efficiency were slowed down obviously. Moreover, DS was hardly released from the hydrogel beads in simulated gastric fluid (pH=l. 2), however, the cumulative release ratio was over 90% in simulated intestine fluid (pH=6. 8) after 5h, which indicated that the hydrogel beads had good pH-sensitive. In addition, the encapsulation efficiency, swelling ratio and DS cumulative release ratio decreased as the concentration of the APT increased, which revealed that incorporating APT into the hydrogel beads can improve the burst release effect of the drug.

  1. Biobased composites from thermoplastic polyurethane elastomer and cross-linked acrylated-epoxidized soybean oil

    Science.gov (United States)

    Soybean oil is an important sustainable material. Crosslinked acrylated epoxidized soybean oil (AESO) is brittle without flexibility and the incorporation of thermoplastic polyurethane improves its toughness for industrial applications. The hydrophilic functional groups from both oil and polyurethan...

  2. Preparation and drug-loading properties of Fe{sub 3}O{sub 4}/Poly(styrene-co-acrylic acid) magnetic polymer nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Wensheng [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China); Coordination Chemistry Institute, School of Chemistry and Chemical Engineering and Life Science, Chaohu University, Chaohu 238000 (China); Shen, Yuhua, E-mail: s_yuhua@163.com [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China); Xie, Anjian [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China); Zhang, Weiqiang [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China); Coordination Chemistry Institute, School of Chemistry and Chemical Engineering and Life Science, Chaohu University, Chaohu 238000 (China)

    2013-11-15

    Fe{sub 3}O{sub 4}/poly(styrene-co-acrylic acid) magnetic polymer nanocomposites were synthesized by the dispersion polymerization method using styrene as hard monomer, acrylic acid as functional monomer, Fe{sub 3}O{sub 4} nanoparticles modified with oleic acid as core, and poly(styrene-co-acrylic acid) as shell. Drug-loading properties of magnetic polymer nanocomposites with curcumin as a model drug were also studied. The results indicated that magnetic polymer nanocomposites with monodisperse were obtained, the particle size distribution was 50–120 nm, and the average size was about 100 nm. The contents of poly(styrene-co-acrylic acid) and Fe{sub 3}O{sub 4} nanoparticles in magnetic polymer nanocomposites were 74% and 24.7%, respectively. The drug-loading capacity and entrapment efficiency were 2.5% and 44.4%, respectively. The saturation magnetization of magnetic polymer nanocomposites at 300 K was 20.2 emu/g without coercivity and remanence. The as-prepared magnetic polymer nanocomposites have not only lots of functional carboxyl groups but also stronger magnetic response, which might have potential applications in drug carrier and targeted drug release.

  3. Ultrasensitive electrochemical immunosensor based on horseradish peroxidase (HRP)-loaded silica-poly(acrylic acid) brushes for protein biomarker detection.

    Science.gov (United States)

    Zhao, Yan; Zheng, Yiqun; Kong, Rongmei; Xia, Lian; Qu, Fengli

    2016-01-15

    We report an ultrasensitive electrochemical immunosensor designed for the detection of protein biomarkers using horseradish peroxidase (HRP)-loaded silica-poly(acrylic acid) brushes (SiO2-SPAABs) as labels. HRP could be efficiently and stably accommodated in the three-dimensional architecture of the SiO2-SPAABs and the SiO2-SPAABs-HRP exhibited high catalytic performance towards o-phenylenediamine (OPD) oxidation in the presence of H2O2, which resulted in significant differential pulse voltammetric (DPV) response change and color change. Using human IgG (HIgG) as a model analyte, a sandwich-type immunosensor was constructed. In particular, graphene oxide (GO) and SiO2-SPAABs-HRP were used to immobilize capture antibody (Ab1) and bind a layer of detection antibody (Ab2), respectively. The current biosensor exhibited a good linear response of HIgG from 100pg/mL to 100μg/mL with a detection limit of 50pg/mL (S/N=5). The sensitivity was 6.70-fold higher than the conventional enzyme-linked immunosorbent assays. The immunosensor results were validated through the detection of HIgG in serum samples.

  4. Electrospun DOXY-h loaded-poly(acrylic acid) nanofiber mats: in vitro drug release and antibacterial properties investigation.

    Science.gov (United States)

    Khampieng, Thitikan; Wnek, Gary E; Supaphol, Pitt

    2014-01-01

    Electrospun DOXY-h loaded-poly(acrylic acid) (PAA) nanofiber mats (PAA/DOXY-h nanofiber mats) were prepared by the electrospinning technique and post-spinning sorption method at various doses: PAA/DOXY-h125, PAA/DOXY-h250, PAA/DOXY-h500, and PAA/DOXY-h1000. The morphology, drug content, release characteristics, and antibacterial activities of the PAA/DOXY-h nanofiber mats were investigated with scanning electron microscopy, UV-vis spectrophotometry, and disc diffusion methodology. The PAA/DOXY-h nanofiber mats had a diameter range of 285-340 nm, and a smooth surface without beads. Adsorption isotherms of DOXY-h could be described well with the Freundlich model. The amounts of DOXY-h, after the post-spinning sorption process, in the PAA/DOXY-h nanofiber mats ranged between 27.57 and 101.71 mg/g. All of the PAA/DOXY-h nanofiber mats exhibited an initial burst release characteristic with cumulative releasing percentages between 37.14 and 45.97%, which followed the Fickian diffusion mechanism. Based on the antibacterial investigation, the tested gram-positive bacteria, Staphylococcus aureus and Streptococcus agalactiae, seemed to be more sensitive to PAA/DOXY-h nanofiber mats than the tested gram-negative bacteria, Pseudomonas aeruginosa. These PAA/DOXY-h nanofiber mats could be used as an antibacterial wound dressing.

  5. Synthesis of linear low-density polyethylene-g-poly (acrylic acid)-co-starch/organo-montmorillonite hydrogel composite as an adsorbent for removal of Pb(ΙΙ) from aqueous solutions.

    Science.gov (United States)

    Irani, Maryam; Ismail, Hanafi; Ahmad, Zulkifli; Fan, Maohong

    2015-01-01

    The purpose of this work is to remove Pb(II) from the aqueous solution using a type of hydrogel composite. A hydrogel composite consisting of waste linear low density polyethylene, acrylic acid, starch, and organo-montmorillonite was prepared through emulsion polymerization method. Fourier transform infrared spectroscopy (FTIR), Solid carbon nuclear magnetic resonance spectroscopy (CNMR)), silicon(-29) nuclear magnetic resonance spectroscopy (Si NMR)), and X-ray diffraction spectroscope ((XRD) were applied to characterize the hydrogel composite. The hydrogel composite was then employed as an adsorbent for the removal of Pb(II) from the aqueous solution. The Pb(II)-loaded hydrogel composite was characterized using Fourier transform infrared spectroscopy (FTIR)), scanning electron microscopy (SEM)), and X-ray photoelectron spectroscopy ((XPS)). From XPS results, it was found that the carboxyl and hydroxyl groups of the hydrogel composite participated in the removal of Pb(II). Kinetic studies indicated that the adsorption of Pb(II) followed the pseudo-second-order equation. It was also found that the Langmuir model described the adsorption isotherm better than the Freundlich isotherm. The maximum removal capacity of the hydrogel composite for Pb(II) ions was 430mg/g. Thus, the waste linear low-density polyethylene-g-poly (acrylic acid)-co-starch/organo-montmorillonite hydrogel composite could be a promising Pb(II) adsorbent.

  6. Synthesis of linear low-density polyethylene-g-poly (acrylic acid)-co-starch/organo-montmorillonite hydrogel composite as an adsorbent for removal of Pb(Ⅱ) from aqueous solutions

    Institute of Scientific and Technical Information of China (English)

    Maryam Irani; Hanafi Ismail; Zulkifli Ahmad; Maohong Fan

    2015-01-01

    The purpose of this work is to remove Pb(Ⅱ) from the aqueous solution using a type of hydrogel composite.A hydrogel composite consisting of waste linear low density polyethylene,acrylic acid,starch,and organo-montmorillonite was prepared through emulsion polymerization method.Fourier transform infrared spectroscopy (FTIR),Solid carbon nuclear magnetic resonance spectroscopy (CNMR)),silicon-29 nuclear magnetic resonance spectroscopy (Si NMR)),and X-ray diffraction spectroscope ((XRD) were applied to characterize the hydrogel composite.The hydrogel composite was then employed as an adsorbent for the removal of Pb(Ⅱ) from the aqueous solution.The Pb(Ⅱ)-loaded hydrogel composite was characterized using Fourier transform infrared spectroscopy (FTIR)),scanning electron microscopy (SEM)),and X-ray photoelectron spectroscopy ((XPS)).From XPS results,it was found that the carboxyl and hydroxyl groups of the hydrogel composite participated in the removal of Pb(Ⅱ).Kinetic studies indicated that the adsorption of Pb(Ⅱ)followed the pseudo-second-order equation.It was also found that the Langmuir model described the adsorption isotherm better than the Freundlich isotherm.The maximum removal capacity of the hydrogel composite for Pb(Ⅱ) ions was 430 mg/g.Thus,the waste linear low-density polyethylene-g-poly (acrylic acid)-co-starch/organo-montmorillonite hydrogel composite could be a promising Pb(Ⅱ) adsorbent.

  7. Synthesis, characterization and swelling properties of guar gum-g-poly(sodium acrylate-co-styrene)/muscovite superabsorbent composites

    Science.gov (United States)

    Wang, Wenbo; Kang, Yuru; Wang, Aiqin

    2010-04-01

    A series of novel guar gum-g-poly(sodium acrylate-co-styrene)/muscovite (GG-g-P(NaA-co-St)/MVT) superabsorbent composites were prepared by free-radical grafting copolymerization of natural guar gum (GG), partially neutralized acrylic acid (NaA), styrene (St) and muscovite (MVT) using ammonium persulfate (APS) as the initiator and N,N-methylene-bis-acrylamide (MBA) as the crosslinker. Optical absorption spectra confirmed that NaA and St had been grafted onto the GG main chain and MVT participated in the polymerization reaction. The simultaneous introduction of St and MVT into the GG-g-PNaA matrix could clearly improve the surface morphologies of the composites, and MVT led to better dispersion in the polymeric matrix without agglomeration, as revealed by electron microscopy. The effects of St and MVT on the water absorption and swelling behavior in various saline solutions, aqueous solutions of hydrophilic organic solvents and surfactant solutions were investigated. Results indicated that the swelling rate and capabilities of the composites were markedly enhanced by the incorporation of the hydrophobic monomer St and inorganic MVT clay mineral. The superabsorbent composite showed a clearer deswelling characteristic in solutions of multivalent saline, acetone and ethanol, and cationic surfactant than that in the solutions of multivalent saline, methanol and anionic surfactant.

  8. Synthesis, characterization and swelling properties of guar gum-g-poly(sodium acrylate-co-styrene)/muscovite superabsorbent composites

    Energy Technology Data Exchange (ETDEWEB)

    Wang Wenbo; Kang Yuru; Wang Aiqin, E-mail: aqwang@licp.cas.c [Center for Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)

    2010-04-15

    A series of novel guar gum-g-poly(sodium acrylate-co-styrene)/muscovite (GG-g-P(NaA-co-St)/MVT) superabsorbent composites were prepared by free-radical grafting copolymerization of natural guar gum (GG), partially neutralized acrylic acid (NaA), styrene (St) and muscovite (MVT) using ammonium persulfate (APS) as the initiator and N,N-methylene-bis-acrylamide (MBA) as the crosslinker. Optical absorption spectra confirmed that NaA and St had been grafted onto the GG main chain and MVT participated in the polymerization reaction. The simultaneous introduction of St and MVT into the GG-g-PNaA matrix could clearly improve the surface morphologies of the composites, and MVT led to better dispersion in the polymeric matrix without agglomeration, as revealed by electron microscopy. The effects of St and MVT on the water absorption and swelling behavior in various saline solutions, aqueous solutions of hydrophilic organic solvents and surfactant solutions were investigated. Results indicated that the swelling rate and capabilities of the composites were markedly enhanced by the incorporation of the hydrophobic monomer St and inorganic MVT clay mineral. The superabsorbent composite showed a clearer deswelling characteristic in solutions of multivalent saline, acetone and ethanol, and cationic surfactant than that in the solutions of multivalent saline, methanol and anionic surfactant.

  9. Synthesis, characterization and swelling properties of guar gum-g-poly(sodium acrylate-co-styrene/muscovite superabsorbent composites

    Directory of Open Access Journals (Sweden)

    Wenbo Wang, Yuru Kang and Aiqin Wang

    2010-01-01

    Full Text Available A series of novel guar gum-g-poly(sodium acrylate-co-styrene/muscovite (GG-g-P(NaA-co-St/MVT superabsorbent composites were prepared by free-radical grafting copolymerization of natural guar gum (GG, partially neutralized acrylic acid (NaA, styrene (St and muscovite (MVT using ammonium persulfate (APS as the initiator and N,N-methylene-bis-acrylamide (MBA as the crosslinker. Optical absorption spectra confirmed that NaA and St had been grafted onto the GG main chain and MVT participated in the polymerization reaction. The simultaneous introduction of St and MVT into the GG-g-PNaA matrix could clearly improve the surface morphologies of the composites, and MVT led to better dispersion in the polymeric matrix without agglomeration, as revealed by electron microscopy. The effects of St and MVT on the water absorption and swelling behavior in various saline solutions, aqueous solutions of hydrophilic organic solvents and surfactant solutions were investigated. Results indicated that the swelling rate and capabilities of the composites were markedly enhanced by the incorporation of the hydrophobic monomer St and inorganic MVT clay mineral. The superabsorbent composite showed a clearer deswelling characteristic in solutions of multivalent saline, acetone and ethanol, and cationic surfactant than that in the solutions of multivalent saline, methanol and anionic surfactant.

  10. Shear bond strength of a denture base acrylic resin and gingiva-colored indirect composite material to zirconia ceramics.

    Science.gov (United States)

    Kubochi, Kei; Komine, Futoshi; Fushiki, Ryosuke; Yagawa, Shogo; Mori, Serina; Matsumura, Hideo

    2017-04-01

    To evaluate the shear bond strengths of two gingiva-colored materials (an indirect composite material and a denture base acrylic resin) to zirconia ceramics and determine the effects of surface treatment with various priming agents. A gingiva-colored indirect composite material (CER) or denture base acrylic resin (PAL) was bonded to zirconia disks with unpriming (UP) or one of seven priming agents (n=11 each), namely, Alloy Primer (ALP), Clearfil Photo Bond (CPB), Clearfil Photo Bond with Clearfil Porcelain Bond Activator (CPB+Act), Metal Link (MEL), Meta Fast Bonding Liner (MFB), MR. bond (MRB), and V-Primer (VPR). Shear bond strength was determined before and after 5000 thermocycles. The data were analyzed with the Kruskal-Wallis test and Steel-Dwass test. The mean pre-/post-thermalcycling bond strengths were 1.0-14.1MPa/0.1-12.1MPa for the CER specimen and 0.9-30.2MPa/0.1-11.1MPa for the PAL specimen. For the CER specimen, the ALP, CPB, and CPB+Act groups had significantly higher bond strengths among the eight groups, at both 0 and 5000 thermocycles. For the PAL specimen, shear bond strength was significantly lower after thermalcycling in all groups tested. After 5000 thermocycles, bond strengths were significantly higher in the CPB and CPB+Act groups than in the other groups. For the PAL specimens, bond strengths were significantly lower after thermalcycling in all groups tested. The MDP functional monomer improved bonding of a gingiva-colored indirect composite material and denture base acrylic resin to zirconia ceramics. Copyright © 2016 Japan Prosthodontic Society. Published by Elsevier Ltd. All rights reserved.

  11. Electrochemical synthesis of polyaniline/poly(2-acryl-amido-2-methyl-1-propane-sulfonic acid) composite

    Energy Technology Data Exchange (ETDEWEB)

    Lapkowski, M. (Inst. of Physical Chemistry and Technology of Polymers, Silesian Technical Univ., Gliwice (Poland))

    1993-03-22

    Conducting polyaniline/poly(2-acryl-amido-2-methyl-1-propane sulfonic acid) (PANi/PAMPS) composite films were synthesized electrochemically on platinum electrodes using a 10% aqueous PAMPS solution as the electrolyte. The electrochemical properties of the resulting polymer are similar to those observed for polyaniline doped with classical non-polymeric anions. PANi/PAMPS exhibits high cycling stability within the potential range of the first redox couple, but it undergoes degradation when the potential range characteristic of the second redox couple is reached. The degradation occurs independently of the electrolytic medium (HCl or 10% aqueous PAMPS). (orig.)

  12. Synthesis and urea-loading of an eco-friendly superabsorbent composite based on mulberry branches

    Directory of Open Access Journals (Sweden)

    Xiying Liang

    2013-02-01

    Full Text Available Mulberry branch, consisting of bark and stalk, was used as raw skeleton material without any chemical pre-treatment to synthesize an eco-friendly mulberry branch-g-poly(acrylic acid-co-acrylamide (PMB/P(AA-co-AM superabsorbent composite. The synthesis conditions and properties of the PMB/P(AA-co-AM superabsorbent composite were investigated. The results showed that under the optimal synthesis conditions, the water absorbency of the prepared PMB/P(AA-co-AM reached 570.5 g/g in deionized water, 288.0 g/g in tap water, and 70.0 g/g in 0.9 wt% aqueous NaCl solution. The PMB/P(AA-co-AM composite also exhibited excellent water retention capacity as well as a rapid water absorbency rate. The urea loading percentage of the PMB/P(AA-co-AM composite was controlled by the concentration of aqueous urea solution. The release of urea from the loaded PMB/P(AA-co-AM composite in deionized water initially exhibited a high rate of release for 60 min, followed by a rapid decline. Meanwhile, the PMB/P(AA-co-AM superabsorbent composite with larger particle size achieved a better sustained release of urea.

  13. Influence of Methacrylic-Acrylic Copolymer Composition on Plasticiser-free Optode Films for pH Sensors

    Directory of Open Access Journals (Sweden)

    Musa Ahmad

    2003-03-01

    Full Text Available In this work we have examined the use of plasticiser-free polymeric films incorporating a proton selective chromoionophore for optical pH sensor. Four types of methacrylic-acrylic copolymers containing different compositions of n-butyl acrylate (nBA and methyl methacrylate (MMA were synthesised for use as optical sensor films. The copolymers were mixed with appropriate amounts of chromoionophore (ETH5294 and a lipophilic salt before spin coated on glass slides to form films for the evaluation of pH response using spectrophotometry. Co-polymer films with high nBA content gave good response and the response time depended on the film thickness. A preliminary evaluation of the optical films of high nBA content with pHs from 2 - 14 showed distinguishable responses from pH 5 - 9. However, the adhesion of the pH sensitive film was good for copolymers with higher content of MMA but not for films with high nBA.

  14. Incorporation of antimicrobial macromolecules in acrylic denture base resins: a research composition and update.

    Science.gov (United States)

    Sivakumar, Indumathi; Arunachalam, Kuthalingam Subbiah; Sajjan, Suresh; Ramaraju, Alluri Venkata; Rao, Bheemalingeshwara; Kamaraj, Bindu

    2014-06-01

    Contemporary research in acrylic denture base materials focuses on the development of a novel poly(methyl methacrylate) (PMMA) resin with antimicrobial properties. Although PMMA resin has fulfilled all the requirements of an ideal denture base material, its susceptibility to microbial colonization in the oral environment is a formidable concern to clinicians. Many mechanisms including the absence of ionic charge in the methyl methacrylate resins, hydrophobic interactions, electrostatic interactions, and mechanical attachment have been found to contribute to the formation of biofilm. The present article outlines the basic categories of potential antimicrobial polymer (polymeric biocides) formulations (modified PMMA resins) and considers their applicability, biological status, and usage potential over the coming years.

  15. Theoretical Studies of the Structure of the Metal-carbon Composites on the Base of Acryle-nitrile Nanopolimer

    Directory of Open Access Journals (Sweden)

    I.V. Zaporotskova

    2014-07-01

    Full Text Available The presence of the metal compounds in the acryle-nitrile nanopolimer (PPAN leads to the formation of the metal nanoparticles. The metal-carbon nanocomposites based on PPAN including pair connections with iron and cobalt has been theoretically investigated. The spatial configuration of the nanocomposite for each option of the arrangement of metal atoms has been received. The analysis of the received results for all options of the arrangement of the metal atoms allowed defining the binding energy of the systems and the width of the forbidden gap ΔЕg of the nanocomposite. The analysis of the electronic and energy structures of the system found out that the introduction of the metal atoms leaded to the essential reduction of the width of the forbidden zone of the composite in comparison with the pure PPAN.

  16. Electron-beam initiated polymerization of acrylate compositions 1 : FTIR monitoring of incremental irradiation

    CERN Document Server

    Patacz, C; Coqueret, X

    2000-01-01

    The electron-beam induced polymerization of some representative formulations including acrylate functional oligomers and diluents has been investigated by means of FTIR spectroscopy applied to films that were cured under a nitrogen flow. In order to gain a deeper insight into the reactivity of the polymerizable systems, the conversion-dose relationship was examined with emphasis on the following points : depth cure profile of the films, and the additivity of effects of incremental radiation doses on monomer conversion. It was shown to be possible to reproduce the actual polymerization profile from discontinuous measurements. This remarkable result is tentatively explained by the geometry of the samples causing limited thermal effects and by the minor influence of possible inhibition and post-polymerization that could influence each of the incremental transformations compared to a single large dose treatment. This method provides a fine tool for revealing differences in kinetic behavior between polymerizable m...

  17. The effect of acrylic latex-based polymer on cow blood adhesive resins for wood composites

    Science.gov (United States)

    Yan, J.; Lin, H. L.; Feng, G. Z.; Gunasekaran, S.

    2016-07-01

    In this paper, alkali-modified cow blood adhesive (BA) and blood adhesive/acrylic latex-based adhesive (BA/ALB) were prepared. The physicochemical and adhesion properties of cow blood adhesive such as UV- visible spectra, particle size, viscosity were evaluated; share strength, water resistance were tested. UV- visible spectra indicates that the strong bonding strength of BA/ALB appeared after incorporating; the particle size of adhesive decreased with the increase of ALB concentration, by mixing ALB and BA, hydrophilic polymer tends locate or extand the protein chains and provide stability of the particles; viscosity decreased as shear rate increased in concordance with a pseudoplastic behavior; both at dry and soak conditions, BA and ALB/BA show significant difference changes when mass fraction of ALB in blend adhesive was over 30% (p latex-based adhesive significantly increased the strength and water resistance of the resulting wood.

  18. Poly(acrylic acid) Bridged Gadolinium Metal-Organic Framework-Gold Nanoparticle Composites as Contrast Agents for Computed Tomography and Magnetic Resonance Bimodal Imaging.

    Science.gov (United States)

    Tian, Chixia; Zhu, Liping; Lin, Feng; Boyes, Stephen G

    2015-08-19

    Imaging contrast agents for magnetic resonance imaging (MRI) and computed tomography (CT) have received significant attention in the development of techniques for early stage cancer diagnosis. Gadolinium (Gd)(III), which has seven unpaired electrons and a large magnetic moment, can dramatically influence the water proton relaxation and hence exhibits excellent MRI contrast. On the other hand, gold (Au), which has a high atomic number and high X-ray attenuation coefficient, is an ideal contrast agent candidate for X-ray-based CT imaging. Gd metal-organic framework (MOF) nanoparticles with tunable size, high Gd(III) loading and multivalency can potentially overcome the limitations of clinically utilized Gd chelate contrast agents. In this work, we report for the first time the integration of GdMOF nanoparticles with gold nanoparticles (AuNPs) for the preparation of a MRI/CT bimodal imaging agent. Highly stable hybrid GdMOF/AuNPs composites have been prepared by using poly(acrylic acid) as a bridge between the GdMOF nanoparticles and AuNPs. The hybrid nanocomposites were then evaluated in MRI and CT imaging. The results revealed high longitudinal relaxivity in MRI and excellent CT imaging performance. Therefore, these GdMOF/AuNPs hybrid nanocomposites potentially provide a new platform for the development of multimodal imaging probes.

  19. Preparation of chitosan/poly(acrylic acid) magnetic composite microspheres and applications in the removal of copper(II) ions from aqueous solutions.

    Science.gov (United States)

    Yan, Han; Yang, Lingyun; Yang, Zhen; Yang, Hu; Li, Aimin; Cheng, Rongshi

    2012-08-30

    In this current work, the magnetic composite microspheres (MCM), consisting of Fe(3)O(4) nanoparticles and poly(acrylic acid) (PAA) blended chitosan (CS), were prepared successfully by a simple method, co-precipitation of the compounds in alkaline solution. SEM, FTIR and TG techniques have been applied to investigate the structures of the MCM materials. The vibrating-sample magnetometer (VSM) measurement illustrated a paramagnetic property as well as a fast magnetic response, which indicated the significant separability of the MCM in the aqueous suspensions. Then, the MCM materials were employed as absorbents for removal of copper(II) (Cu(II)) ions from aqueous solutions. The fundamental adsorption behaviors of MCM were studied also. Experimental results revealed that the CS/PAA-MCM had greater adsorption capacity than CS-MCM, and PAA played an important role for the adsorption of Cu(II) ions. Moreover, the adsorption isotherms were all well described by the Langmuir model, while the adsorption kinetics followed the pseudo-second order equation. Furthermore, the adsorbent could be easily regenerated at lower pH and reused almost without any loss of adsorption capacity. On the contrary, the Cu(II) ions loaded CS-MCM and CS/PAA-MCM were stable enough at pH higher than 4.0, and both exhibited efficient phosphate removal with maximal uptakes around 63.0 and 108.0 mg Pg(-1), respectively. Copyright © 2012 Elsevier B.V. All rights reserved.

  20. Precise 3D printing of micro/nanostructures using highly conductive carbon nanotube-thiol-acrylate composites

    Science.gov (United States)

    Liu, Y.; Xiong, W.; Jiang, L. J.; Zhou, Y. S.; Lu, Y. F.

    2016-04-01

    Two-photon polymerization (TPP) is of increasing interest due to its unique combination of truly three-dimensional (3D) fabrication capability and ultrahigh spatial resolution of ~40 nm. However, the stringent requirements of non-linear resins seriously limit the material functionality of 3D printing via TPP. Precise fabrication of 3D micro/nanostructures with multi-functionalities such as high electrical conductivity and mechanical strength is still a long-standing challenge. In this work, TPP fabrication of arbitrary 3D micro/nanostructures using multi-walled carbon nanotube (MWNT)-thiolacrylate (MTA) composite resins has been developed. Up to 0.2 wt% MWNTs have been incorporated into thiol-acrylate resins to form highly stable and uniform composite photoresists without obvious degradation for one week at room temperature. Various functional 3D micro/nanostructures including woodpiles, micro-coils, spiral-like photonic crystals, suspended micro-bridges, micro-gears and complex micro-cars have been successfully fabricated. The MTA composite resin offers significant enhancements in electrical conductivity and mechanical strength, and on the same time, preserving high optical transmittance and flexibility. Tightly controlled alignment of MWNTs and the strong anisotropy effect were confirmed. Microelectronic devices including capacitors and resistors made of the MTA composite polymer were demonstrated. The 3D micro/nanofabrication using the MTA composite resins enables the precise 3D printing of micro/nanostructures of high electrical conductivity and mechanical strength, which is expected to lead a wide range of device applications, including micro/nano-electromechanical systems (MEMS/NEMS), integrated photonics and 3D electronics.

  1. STUDY OF COMPOSITE MEMBRANE OF CELLULOSE ACETATE OR POLYVINYL ALCOHOL BLENDED WITH METHYLMETHACRYLATE-ACRYLIC ACID COPOLYMER FOR PERVAPORATION SEPARATION

    Institute of Scientific and Technical Information of China (English)

    Huan-lin Chen; Jun Tan; Mo-e Liu; Chang-luo Zhu

    1999-01-01

    In this paper, methylmethacrylate-acrylic acid MMA-AA hydrophilic and hydrophobic copolymers were prepared by copolymerization for preparing membrane materials. The composite membrane of cellulose acetate (CA) blended with MMA-AA hydrophobic copolymer was used for the separation of methanol from pentane-methanol mixture. When the methanol concentration was only 1 wt%, the permeate flux still maintained at 350 g/m2h and separation factor was as big as 800. The composite membrane of PVA (polyvinyl alcohol) blended with MMA-AA hydrophilic copolymer was used for the separation of ethanolwater mixture. The permeate flux was increased to 975 g/m2h at 74℃ and the separation factor reached 3000at 25℃. The PVA/MMA-AA blended membrane surface modified by ammonia plasma was also investigated for separating ethanol-water mixture. Both permeate flux and separation factor of the membrane was improved. However, there was no obvious difference of plasma treatment time in the interval of 20~40 min.

  2. Radiation cured epoxy acrylate composites based on graphene, graphite oxide and functionalized graphite oxide with enhanced properties.

    Science.gov (United States)

    Guo, Yuqiang; Bao, Chenlu; Song, Lei; Qian, Xiaodong; Yuan, Bihe; Hu, Yuan

    2012-03-01

    Epoxy acrylate (EA) composites containing graphite oxide (GO), graphene and nitrogen-double bond functionalized graphite oxide (FGO) were fabricated using UV-radiation and electron beam radiation via in-situ polymerization. Graphene and FGO were homogenously dispersed in EA matrix and enhanced properties, including thermal stability, flame retardancy, electrical conductivity and reduced deleterious gas releasing in thermo decomposition were obtained. Microscale combustion colorimeter results illustrated improved flame retardancy; EA/FGO composites achieved a 29.7% reduction in total heat release (THR) when containing only 0.1% FGO and a 38.6% reduction in peak-heat release rate (PHRR) when containing 3% FGO. The onset decomposition temperatures were delayed and the maximum decomposition values were reduced, according to thermogravimetric analysis which indicated enhanced thermal stabilities. The electrical conductivity was increased by 6 orders of magnitude (3% graphene) and the deleterious gas released during the thermo decomposition was reduced with the addition of all the graphite samples. This study represented a new approach to functionalize GO with flame retardant elements and active curable double bond to achieve better dispersion of GO into polymer matrix to obtain nanocomposites and paved a way for achieving graphene-based materials with high-performance of graphene in enhancement of flame retardancy of polymers for practical applications.

  3. Fracture mechanics and statistical modeling of ternary blends of polylactide/ethylene-acrylate copolymer /wood-flour composites

    Science.gov (United States)

    Afrifah, Kojo Agyapong

    This study examined the mechanisms of toughening the brittle bio-based poly(lactic acid) (PLA) with a biodegradable rubbery impact modifier to develop biodegradable and cost effective PLA/wood-flour composites with improved impact strength, toughness, high ductility, and flexibility. Semicrystalline and amorphous PLA grades were impact modified by melt blending with an ethylene-acrylate copolymer (EAC) impact modifier. EAC content was varied to study the effectiveness and efficiency of the impact modifier in toughening the semicrystalline and amorphous grades of the PLA. Impact strength was used to assess the effectiveness and efficiency of the EAC in toughening the blends, whereas the toughening mechanisms were determined with the phase morphologies and the miscibilities of the blends. Subsequent tensile property analyses were performed on the most efficiently toughened PLA grade. Composites were made from PLA, wood flour of various particle sizes, and EAC. Using two-level factorial design the interaction between wood flour content, wood flour particle size, and EAC content and its effect on the mechanical properties of the PLA/wood-flour composites was statistically studied. Numerical optimization was also performed to statistically model and optimize material compositions to attain mechanical properties for the PLA/wood-flour composites equivalent to at least those of unfilled PLA. The J-integral method of fracture mechanics was applied to assess the crack initiation (Jin) and complete fracture (J f) energies of the composites to account for imperfections in the composites and generate data useful for engineering designs. Morphologies of the fractured surfaces of the composites were analyzed to elucidate the failure and toughening mechanisms of the composites. The EAC impact modifier effectively improved the impact strength of the PLA/EAC blends, regardless of the PLA type. However, the EAC was more efficient in the semicrystalline grades of PLA compared to the

  4. Electroactive behavior assessment of poly(acrylic acid)-graphene oxide composite hydrogel in the detection of cadmium

    NARCIS (Netherlands)

    Bejarano-Jimenez, A.; Escobar-Barrios, V.A.; Kleijn, J.M.; Oritz-Ledon, C.A.; Chazaro-Ruiz, L.F.

    2014-01-01

    Super absorbent polymers of acrylic acid-graphene oxide (PAA-GO) were synthesized with different percentage of chemical neutralization (0, 10, and 20%) of the acrylic acid monomer before its polymerization. The influence of their swelling and adsorption/desorption capacity of cadmium ions in aqueous

  5. Acrylate-endcapped polymer precursors: effect of chemical composition on the healing efficiency of active concrete cracks

    Science.gov (United States)

    Araújo, Maria; Van Tittelboom, Kim; Dubruel, Peter; Van Vlierberghe, Sandra; De Belie, Nele

    2017-05-01

    The repair of cracks in concrete is an unavoidable practice since these cracks endanger the durability of the structure. Inspired by nature, the self-healing concept has been widely investigated in concrete as a promising solution to solve the limitations of manual repair. This self-healing functionality may be realized by the incorporation of encapsulated healing agents in concrete. Depending on the nature of the cracks, different healing agents can be used. For structures subjected to repeated loads, elastic materials should be considered to cope with the crack opening and closing movement. In this study, various acrylate-endcapped polymer precursors were investigated for their suitability to heal active cracks. The strain capacity of the polymers was assessed by means of visual observation together with water flow tests after widening of the healed cracks in a stepwise manner. A strain of at least 50% could be sustained by epoxy- and siloxane-based healing agents. For polyester- and urethane/poly(propylene glycol)-based precursors, failure occurred at 50% elongation due to detachment of the polymer from the crack walls. However, for urethane/poly(propylene glycol)-based healing agent, debonding was limited to some local spots. The resistance of the polymerized healing agents against degradation in the strong alkaline environment characteristic for concrete has also been evaluated, with the urethane/poly(propylene glycol)-based precursor showing the best performance to withstand degradation.

  6. Temporary space maintainers retained with composite resin. Part II: Fracture load in vitro.

    Science.gov (United States)

    Grajower, R; Stern, N; Zamir, S T; Kohavi, D

    1981-01-01

    The average fracture load during occlusal loading of pontics which were bonded to natural abutment teeth in vitro was found to be 56.1, 57.5 and 74.2 kg for natural, acrylic resin, and Restodent pontics, respectively. Coating the roots of the abutment teeth with a thin layer of silicone rubber before embedding them in stone slightly reduced the strength of the fixed partial dentures. Thermocycling the specimens with coated roots caused a considerable decrease in strength to fracture loads of 33.0, 17.9, and 37.3 kg for natural, acrylic resin, and Restodent pontics, respectively. Fracture of the enamel of natural tooth pontics was observed in a few specimens. The superior strength of the fixed partial dentures with natural tooth and Restodent pontics would indicate that these pontics are superior for clinical trials rather than acrylic resin pontics.

  7. Antibacterial properties of a self-cured acrylic resin composed of a polymer coated with a silver-containing organic composite antibacterial agent.

    Science.gov (United States)

    Kiriyama, Takashi; Kuroki, Kenjiro; Sasaki, Keisuke; Tomino, Masahumi; Asakura, Masaki; Kominami, Yoshiko; Takahashi, Yoshihumi; Kawai, Tatsushi

    2013-01-01

    A novel antibacterial polymer, coated with a silver-containing organic composite antibacterial agent, was dispersed in a self-cured acrylic resin. Residual viable cell count of each oral bacterial and fungal species cultivated on acrylic resin specimens containing the antibacterial polymer was significantly decreased when compared to those cultivated on specimens prepared from untreated polymer. A strong inverse correlation was found between the amount of eluted silver ions and the residual viable cell count of all species grown on the antibacterial polymer: the lower the viable cell count, the higher the amount of eluted silver ions. This clearly indicated the antibacterial activity of silver ions. As the content of organic composite antibacterial agent added to the polymer increased from 0.5% to 1.5% in 0.5% increments, amount of eluted silver ions significantly increased with each 0.5% increment to exert greater antibacterial effect.

  8. PMMA-based composite materials with reactive ceramic fillers: IV. Radiopacifying particles embedded in PMMA beads for acrylic bone cements.

    Science.gov (United States)

    Abboud, M; Casaubieilh, L; Morvan, F; Fontanille, M; Duguet, E

    2000-01-01

    New acrylic bone cements were prepared from alumina particles previously treated by 3-(trimethoxysilyl)propylmethacrylate (gamma-MPS) and embedded in poly(methylmethacrylate-co-ethylacrylate) beads with about 7 mol% of ethyl acrylate repeating units. The encapsulation was performed through a conventional suspension polymerization process. The influence of (i) the concentration of the dispersion stabilizer and (ii) the alumina content upon the shape, size, and size distribution of the acrylic beads was studied. Cements were prepared from each batch by hand-mixing alumina-filled acrylic beads with a liquid monomer mixture containing methyl methacrylate, n-butyl methacrylate, and N,N-dimethyl-p-toluidine. Benzoyl peroxide was previously added to the solid part. The powder-to-liquid ratio was equal to 2 for each formulation. Compressive strength of cured cement decreases with alumina content, whereas compressive modulus remains roughly constant. These results are in contradiction to those obtained for cements based on a mixture of gamma-MPS-treated alumina and unfilled acrylic beads. Nevertheless, they are interpreted in terms of alumina arrangement in the cement. In the first case, alumina particles contribute to the reinforcement of the dispersed acrylic phase, with poor benefits for the whole materials. In the second case, they allow the reinforcement of the continuous acrylic phase and, therefore, the cement's one.

  9. Anisotropy in CNT composite fabricated by combining directional freezing and gamma irradiation of acrylic acid

    OpenAIRE

    Osička, Josef; Ilčíková, Marketa; Mrlík, Miroslav; Al-Maadeed, Mariam Ali S.A.; Šlouf, Miroslav; Tkac, Jan; Kasák, Peter

    2016-01-01

    A novel fabrication process for composite consisting of organized modified carbon nanotubes (CNT) in the polyacrylic acid (PAA) matrix has been developed. The CNT were organized along crystallite domains during a directional freezing process and subsequently fixed by the gamma irradiation induced polymerization and crosslinking in solid state. Different morphology and distribution of CNT in fabricated and conventionally prepared composites were investigated by scanning and transmission electr...

  10. Tetracycline Loaded Collagen/Hydroxyapatite Composite Materials for Biomedical Applications

    OpenAIRE

    2015-01-01

    The paper describes the preparation, characterisation, and testing of tetracycline loaded collagen-carboxymethylcellulose/hydroxyapatite ternary composite materials. The synthesis of this drug delivery system consists in two steps: the first step is the mineralization of collagen-carboxymethylcellulose gel while the second step corresponds to the loading of the ternary composite material with tetracycline. The obtained DDS is characterised by physicochemical, morphological, and release behavi...

  11. Delamination Growth in Composites under Fatigue Loading

    NARCIS (Netherlands)

    Khan, R.

    2013-01-01

    Fiber reinforced composites are attractive for aerospace applications due to high specific strength and stiffness. Their use has been gradually increased to 50% by weight of the aircraft over past decades. As a consequence, modern aircraft utilize composites in the primary structures like wing skin

  12. Delamination Growth in Composites under Fatigue Loading

    NARCIS (Netherlands)

    Khan, R.

    2013-01-01

    Fiber reinforced composites are attractive for aerospace applications due to high specific strength and stiffness. Their use has been gradually increased to 50% by weight of the aircraft over past decades. As a consequence, modern aircraft utilize composites in the primary structures like wing skin

  13. Load Composition Model Workflow (BPA TIP-371 Deliverable 1A)

    Energy Technology Data Exchange (ETDEWEB)

    Chassin, David P.; Cezar, Gustavo V.; /SLAC

    2017-07-17

    This project is funded under Bonneville Power Administration (BPA) Strategic Partnership Project (SPP) 17-005 between BPA and SLAC National Accelerator Laboratory. The project in a BPA Technology Improvement Project (TIP) that builds on and validates the Composite Load Model developed by the Western Electric Coordinating Council's (WECC) Load Modeling Task Force (LMTF). The composite load model is used by the WECC Modeling and Validation Work Group to study the stability and security of the western electricity interconnection. The work includes development of load composition data sets, collection of load disturbance data, and model development and validation. This work supports reliable and economic operation of the power system. This report was produced for Deliverable 1A of the BPA TIP-371 Project entitled \\TIP 371: Advancing the Load Composition Model". The deliverable documents the proposed work ow for the Composite Load Model, which provides the basis for the instrumentation, data acquisition, analysis and data dissemination activities addressed by later phases of the project.

  14. Predicting the Structural Performance of Composite Structures Under Cyclic Loading

    NARCIS (Netherlands)

    Kassapoglou, C.

    2012-01-01

    The increased use of advanced composite materials on primary aircraft structure has brought back to the forefront the question of how such structures perform under repeated loading. In particular, when damage or other stress risers are present, tests have shown that the load to cause failure after

  15. A Highly Sensitive Electrochemical DNA Biosensor from Acrylic-Gold Nano-composite for the Determination of Arowana Fish Gender

    Science.gov (United States)

    Rahman, Mahbubur; Heng, Lee Yook; Futra, Dedi; Chiang, Chew Poh; Rashid, Zulkafli A.; Ling, Tan Ling

    2017-08-01

    The present research describes a simple method for the identification of the gender of arowana fish ( Scleropages formosus). The DNA biosensor was able to detect specific DNA sequence at extremely low level down to atto M regimes. An electrochemical DNA biosensor based on acrylic microsphere-gold nanoparticle (AcMP-AuNP) hybrid composite was fabricated. Hydrophobic poly(n-butylacrylate-N-acryloxysuccinimide) microspheres were synthesised with a facile and well-established one-step photopolymerization procedure and physically adsorbed on the AuNPs at the surface of a carbon screen printed electrode (SPE). The DNA biosensor was constructed simply by grafting an aminated DNA probe on the succinimide functionalised AcMPs via a strong covalent attachment. DNA hybridisation response was determined by differential pulse voltammetry (DPV) technique using anthraquinone monosulphonic acid redox probe as an electroactive oligonucleotide label (Table 1). A low detection limit at 1.0 × 10-18 M with a wide linear calibration range of 1.0 × 10-18 to 1.0 × 10-8 M ( R 2 = 0.99) can be achieved by the proposed DNA biosensor under optimal conditions. Electrochemical detection of arowana DNA can be completed within 1 hour. Due to its small size and light weight, the developed DNA biosensor holds high promise for the development of functional kit for fish culture usage.

  16. Preparation and swelling properties of pH-sensitive composite hydrogel beads based on chitosan-g-poly (acrylic acid)/vermiculite and sodium alginate for diclofenac controlled release.

    Science.gov (United States)

    Wang, Qin; Xie, Xiaoling; Zhang, Xiaowei; Zhang, Junping; Wang, Aiqin

    2010-04-01

    A series of pH-sensitive composite hydrogel beads, chitosan-g-poly (acrylic acid)/vermiculite/sodium alginate (CTS-g-PAA/VMT/SA), was prepared using CTS-g-PAA/VMT composite and SA by Ca(2+) as the crosslinking agent. The structure and morphologies of the developed composite hydrogel beads were characterized by Fourier transform infrared spectroscopy and scanning electron microscopy. The swelling properties and pH-sensitivity of the beads were investigated. In addition, the drug loading and controlled release behaviors of the beads were also evaluated using diclofenac sodium (DS) as the model drug in stimulated gastric fluids (pH 2.1) and intestinal fluids (pH 6.8). The results indicate that the composite hydrogel beads showed good pH-sensitivity. The release rate of the drug from the composite hydrogel beads is remarkably slowed down, which indicated that incorporating VMT into the composite hydrogel beads can improve the burst release effect of the drug.

  17. Culture-Loaded Expressions in Korean EFL Students' Compositions.

    Science.gov (United States)

    Choe, Yongjae Paul

    2001-01-01

    Discusses the inevitability of native culture-loaded expressions in Korean English-as-a-Foreign-Language students' compositions. Cultures, both native and target play a major role in forming ideas in any communicative situation. Thus, Korean EFL students' compositions all reveal without exception the traits of Korean culture. (Author/VWL)

  18. Macro-residual strains due to cyclic loading of composites

    CERN Document Server

    Hashin, Z

    1999-01-01

    Macro-residual strains produced by load cycles on elastic-brittle composites are analytically expressed in terms of the effective thermal expansion coefficients of the composite as affected by the damage states developing during the $9 cycling. Limiting values of residual strain are evaluated for unidirectional fiber composites and cross-ply laminates. Frictional losses due to internal sliding are not considered. (17 refs).

  19. A randomized controlled trial comparing interim acrylic prostheses with and without cast metal base for immediate loading of dental implants in the edentulous mandible.

    Science.gov (United States)

    Thomé, Eloana; Lee, Hyung Joo; Sartori, Ivete Aparecida de Mattias; Trevisan, Roseli Latenek; Luiz, Jaques; Tiossi, Rodrigo

    2015-12-01

    This randomized controlled trial used resonance frequency analysis (RFA) to assess the effects of the presence or absence of a cast rigid bar splinting multiple implants in the stability of immediately loaded implants. Twenty-nine edentulous patients were randomly divided into two groups: G1 with full-arch implant-fixed prostheses and G2 with multiple implant splinting via acrylic resin denture bases. All implants were immediately loaded. RFA measurements assessed implant stability at three different times (T0--at baseline, T1--4 months, and T2--8 months. Wilcoxon and Friedman tests and a multivariate model with repeated measures for longitudinal data were used for statistical comparison (α = 0.05). Twenty-nine patients were assessed (G1 = 15 and G2 = 14). Implant and prostheses survival rates were 100% for both groups after the 8-month observation period and no significant differences in the mean ISQ values were found at the different implant stability assessment times (P > 0.05). The different splinting protocols did not appear to affect implant stability during the 8-month observation period. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  20. Analysis of Mechanical and Thermogravimetric Properties of Composite Materials Based on PVA/MWCNT and Styrene-Acrylic Copolymer/MWCNT

    Science.gov (United States)

    Volynets, N. I.; Poddubskaya, O. G.; Demidenko, M. I.; Lyubimov, A. G.; Kuzhir, P. P.; Suslyaev, V. I.; Pletnev, M. A.; Zicans, Janis

    2017-08-01

    Mechanical and thermogravimetric properties of polymer composite materials with various concentrations of multiwalled carbon nanotubes effectively shielding radiation in the radio frequency (20 Hz - 1 MHz) and microwave (26-36 GHz) frequency ranges are studied. As a matrix, widely available polymeric materials, such as polyvinyl acetate and styrene-acrylate, were used in the form of dispersions. From the analysis of the obtained experimental data, it was shown that the introduction of carbon nanotubes into the polymer matrix makes it possible to increase mechanical properties and thermal stability of composite materials.

  1. EFFECT OF COMPOSITION AND PROCESSING CONDITION ON MICROSTRUCTURAL PROPERTIES AND DURABILITY OF FLUOROPOLYMER/ACRYLIC BLENDS

    Institute of Scientific and Technical Information of China (English)

    Li-Piin Sung; Xiaohong Gu; Derek L. Ho; Forrest. A. Landis; Diep Nguyenc

    2009-01-01

    Fluoropolymer blends have been widely used as binders for exterior coatings because of their excellent resistance to ultra-violet (UV) radiation as well as to many corrosive chemical agents.It is known that the fluorinated component usually has a lower glass transition temperature and easily crystallizes in the final structure depending upon the blend composition and sample annealing condition.We investigated the effect of blend composition and annealing process (slow and fast cooling) on the surface morphology and microstructure a poly(vinylidene fluoride)/poly(methyl methacrylate)(PVDF/PMMA) blend before and after UV exposure.Surface and subsurface microstructures were studied by atomic force microscopy (AFM) and laser scanning confocal microscopy (LSCM).Bulk microstructure of PVDF-coatings before and after UV exposure were characterized using small angle neutron and light scattering.Higher PVDF content and a slow cooling process result in larger spherulite crystallite structure and rougher surface morphology.Significant ordering in the spherulite crystallite structure has been observed on the surface and the bulk films after UV exposure.

  2. Effect of chemical composition on corneal tissue response to photopolymerized materials comprising 2-hydroxyethyl methacrylate and acrylic acid

    Energy Technology Data Exchange (ETDEWEB)

    Lai, Jui-Yang, E-mail: jylai@mail.cgu.edu.tw

    2014-01-01

    The purpose of this work was to investigate the relationship between the feed composition of 2-hydroxyethyl methacrylate (HEMA)/acrylic acid (AAc) and hydrogel material compatibility towards ocular anterior segment tissues, particularly the corneal endothelium. The monomer solutions of HEMA and AAc were mixed at varying volume ratios of 92:0, 87:5, 82:10, 77:15, and 72:20, and were subjected to UV irradiation. Then, the 7-mm-diameter membrane implants made from photopolymerized materials were placed into the ocular anterior chamber for 4 days and assessed by biomicroscopic examinations, corneal thickness measurements, and quantitative real-time reverse transcription polymerase chain reaction analyses. The poly(HEMA-co-AAc) implants prepared from the solution mixture containing 0–10 vol.% AAc displayed good biocompatibility. However, with increasing volume ratio of AAc and HEMA from 15:77 to 20:72, the enhanced inflammatory response, decreased endothelial cell density, and increased ocular score and corneal thickness were observed, probably due to the influence of surface charge of copolymer membranes. On the other hand, the ionic pump function of corneal endothelium exposed to photopolymerized membranes was examined by analyzing the Na{sup +},K{sup +}-ATPase alpha 1 subunit (ATP1A1) expression level. The presence of the implants having higher amount of AAc incorporated in the copolymers (i.e., 15.1 to 24.7 μmol) and zeta potential (i.e., -38.6 to − 56.5 mV) may lead to abnormal transmembrane transport. It is concluded that the chemical composition of HEMA/AAc has an important influence on the corneal tissue responses to polymeric biomaterials. - Highlights: • We examine the corneal tissue responses to photopolymerized biomaterials. • Carboxyl groups in copolymers increased with increasing volume ratio of AAc/HEMA. • 15–20 vol.% AAc raised ocular score and caused corneal endothelial loss and edema. • High anionic charge density stimulated inflammation

  3. CuS-poly (N-isopropylacryl-amide-co-acrylic acid) composite microspheres with patterned surface structures:preparation and characterization

    Institute of Scientific and Technical Information of China (English)

    YANG Juxiang; FANG Yu; BAI Chaoliang; HU Daodao; ZHANG Ying

    2004-01-01

    N-isopropylacrylamide (NIPAM) and acrylic acid (AA) copolymer microspheres with various compositions were prepared by reverse suspension polymerization technique. The microspheres thus prepared were employed as micro-reactors for the deposition of CuS. In this way, several CuS-P(NIPAM-co-AA) composite microspheres with different surface morphologies were prepared. It was demonstrated that the surface structures of the composite microspheres can be tailored to a certain extent by varying the ratio of the two monomer units in the template (microgels) and/or the amount of CuS deposited. It is in prospect that the inherent advantages of microgel templates (the size, composition, charge nature and density, and crosslinking density could be easily controlled) would make the microgel template method extremely useful in the preparation of composite microspheres with different patterned surface structures.

  4. Lead titanate/cyclic carbonate dependence on ionic conductivity of ferro/acrylate blend polymer composites

    Energy Technology Data Exchange (ETDEWEB)

    Jayaraman, R. [Department of Physics, GTN Arts and Science College, Dindigul (India); Vickraman, P., E-mail: vrsvickraman@yahoo.com; Subramanian, N. M. V.; Justin, A. Simon [Department of Physics, Gandhigram Rural Institute- Deemed University, Gandhigram (India)

    2016-05-23

    Impedance, XRD, DSC and FTIR studies had been carried out for PVdF-co-HFP/LIBETI based system for three plasticizer (EC/DMC) – filler (PbTiO3) weight ratios. The enhanced conductivity 4.18 × 10{sup −5} Scm{sup −1} was noted for 57.5 wt% −7.5 wt% plasticizer – filler. while blending PEMA to PVdF-co-HFP respectively 7.5: 22.5 wt % (3/7), 15 wt%: 15 wt % (5/5) and 22.5wt %: 7.5 wt % (7/3), the improved conductivity was noted for 3/7 ratio 1.22 × 10{sup −5} S cm{sup −1} and its temperature dependence abide Arrhenius behavior. The intensity of peaks in XRD diffractogram registered dominance of lead titanate, from 2θ = 10° to 80° and absence of VdF crystallites (α+β phase) was noted. In DSC studies, the presence of the exotherm events, filler effect was distinctively seen exhibiting recrystallization of VdF crystallites. In blending PEMA, however, no trace of exotherms was found suggestive of PEMA better inhibiting recrystallization. FTIR study confirmed molecular interactions of various constituents in the vibrational band 500 – 1000 cm{sup −1} both in pristine PVdF-co-HFP and PEMA blended composites with reference to C-F stretching, C-H stretching and C=O carbonyl bands.

  5. Lead titanate/cyclic carbonate dependence on ionic conductivity of ferro/acrylate blend polymer composites

    Science.gov (United States)

    Jayaraman, R.; Vickraman, P.; Subramanian, N. M. V.; Justin, A. Simon

    2016-05-01

    Impedance, XRD, DSC and FTIR studies had been carried out for PVdF-co-HFP/LIBETI based system for three plasticizer (EC/DMC) - filler (PbTiO3) weight ratios. The enhanced conductivity 4.18 × 10-5 Scm-1 was noted for 57.5 wt% -7.5 wt% plasticizer - filler. while blending PEMA to PVdF-co-HFP respectively 7.5: 22.5 wt % (3/7), 15 wt%: 15 wt % (5/5) and 22.5wt %: 7.5 wt % (7/3), the improved conductivity was noted for 3/7 ratio 1.22 × 10-5 S cm-1 and its temperature dependence abide Arrhenius behavior. The intensity of peaks in XRD diffractogram registered dominance of lead titanate, from 2θ = 10° to 80° and absence of VdF crystallites (α+β phase) was noted. In DSC studies, the presence of the exotherm events, filler effect was distinctively seen exhibiting recrystallization of VdF crystallites. In blending PEMA, however, no trace of exotherms was found suggestive of PEMA better inhibiting recrystallization. FTIR study confirmed molecular interactions of various constituents in the vibrational band 500 - 1000 cm-1 both in pristine PVdF-co-HFP and PEMA blended composites with reference to C-F stretching, C-H stretching and C=O carbonyl bands.

  6. Tetracycline Loaded Collagen/Hydroxyapatite Composite Materials for Biomedical Applications

    Directory of Open Access Journals (Sweden)

    Laura Cristina Rusu

    2015-01-01

    Full Text Available The paper describes the preparation, characterisation, and testing of tetracycline loaded collagen-carboxymethylcellulose/hydroxyapatite ternary composite materials. The synthesis of this drug delivery system consists in two steps: the first step is the mineralization of collagen-carboxymethylcellulose gel while the second step corresponds to the loading of the ternary composite material with tetracycline. The obtained DDS is characterised by physicochemical, morphological, and release behaviour by using FTIR spectroscopy and microscopy, scanning electron microscopy, and UV-VIS spectroscopy. Based on the release study, it can be assumed that tetracycline is released in a prolonged way, assuring at least 6 days of antiseptic properties.

  7. Optimum design of laminated composite under axial compressive load

    Indian Academy of Sciences (India)

    N G R Iyengar; Nilesh Vyas

    2011-02-01

    In the present study optimal design of composite laminates, with and without rectangular cut-out, is carried out for maximizing the buckling load. Optimization study is carried out for obtaining the maximum buckling load with design variables as ply thickness, cut-out size and orientation of cut-out with respect to laminate. Buckling load is evaluated using a ‘simple higher order shear deformation theory’ based on four unknown displacements $u,v,w_b$ and $w_s$. A C1 continuous shear flexible finite element based on HSDT model is developed using Hermite cubic polynomial. It is observed that for thick anti-symmetric laminates, the non-dimensional buckling load decreases with increase in aspect ratio and increase in fibre orientation angle. There is a decrease in the non-dimensional buckling load of symmetric laminate in the presence of cut-out.

  8. Loading rate sensitivity of open hole composites in compression

    Science.gov (United States)

    Lubowinski, Steve J.; Guynn, E. G.; Elber, Wolf; Whitcomb, J. D.

    1988-01-01

    The results are reported of an experimental study on the compressive, time-dependent behavior of graphite fiber reinforced polymer composite laminates with open holes. The effect of loading rate on compressive strength was determined for six material systems ranging from brittle epoxies to thermoplastics at both 75 F and 220 F. Specimens were loaded to failure using different loading rates. The slope of the strength versus elapsed time-to-failure curve was used to rank the materials' loading rate sensitivity. All of the materials had greater strength at 75 F than at 220 F. All the materials showed loading rate effects in the form of reduced failure strength for longer elapsed-time-to-failure. Loading rate sensitivity was less at 220 F than the same material at 70 F. However, C12000/ULTEM and IM7/8551-7 were more sensitive to loading rate than the other materials at 220 F. AS4/APC2 laminates with 24, 32, and 48 plies and 1/16 and 1/4 inch diameter holes were tested. The sensitivity to loading rate was less for either increasing number of plies or larger hole size. The failure of the specimens made from brittle resins was accompanied by extensive delaminations while the failure of the roughened systems was predominantly by shear crippling. Fewer delamination failures were observed at the higher temperature.

  9. Alignment and Load Transfer in Carbon Nanotube and Dicyclopentadiene Composites

    Science.gov (United States)

    Severino, Joseph Vincent

    Individual carbon nanotubes (CNTs) are the strongest materials available but their macroscopic assemblies are weak. This work establishes a new thermosetting dicyclopentadiene (DCPD) and CNT composite that increases the strength of CNT assemblies. These high volume fraction and void free structures constitute advanced materials that could one day replace traditional composite systems. To further the understanding of physical interactions between polymer and CNTs, a novel "capstan" load transfer mechanism is also introduced. Self-supporting assemblies of interconnected carbon nanotubes were stretched, twisted and compressed to fashion composites by the infusion and polymerization of low viscosity DCPD based monomeric resins. The properties of the CNTs, polymer and composite were characterized with thermal gravimetric analysis (TGA), dynamic mechanical analysis (DMA) and Raman spectroscopy. The microstructure was analyzed by wide angle X-ray scattering (WAXS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Sheets were drawn at 15 m/min from a growth furnace to impart alignment then stretched to further modify alignment. The mechanical properties were determined in five orientations with respect to the growth direction. The strength was nearly three times higher along this growth direction than it was perpendicular, and modulus was nearly six times higher. Transverse stretching achieved 1.5 times the elongation but alignment was inferior due to CNT kinking that prevented alignment and consolidation. Composites yarns and sheets were investigated for the mechanical properties, microstructure and load transfer. The DCPD resin was found to wet the CNTs and lubricated deformation. This reduced loads during processing, and curing solidified the aligned and consolidated structure. The stretched and twisted composite yarns increased the failure stress 51%. In aligned composite sheet, the failure stress increased 200%. The increased stresses

  10. Hybrid S2/Carbon Epoxy Composite Armours Under Blast Loads

    Science.gov (United States)

    Dolce, F.; Meo, Michele; Wright, A.; French, M.; Bernabei, M.

    2012-06-01

    Civil and military structures, such as helicopters, aircrafts, naval ships, tanks or buildings are susceptible to blast loads as terroristic attacks increases, therefore there is the need to design blast resistant structures. During an explosion the peak pressure produced by shock wave is much greater than the static collapse pressure. Metallic structures usually undergo large plastic deformations absorbing blast energy before reaching equilibrium. Due to their high specific properties, fibre-reinforced polymers are being considered for energy absorption applications in blast resistant armours. A deep insight into the relationship between explosion loads, composite architecture and deformation/fracture behaviour will offer the possibility to design structures with significantly enhanced energy absorption and blast resistance performance. This study presents the results of a numerical investigation aimed at understanding the performance of a hybrid composite (glass/carbon fibre) plate subjected to blast loads using commercial LS-DYNA software. In particular, the paper deals with numerical 3D simulations of damages caused by air blast waves generated by C4 charges on two fully clamped rectangular plates made of steel and hybrid (S2/Carbon) composite, respectively. A Multi Materials Arbitrary Lagrangian Eulerian (MMALE) formulation was used to simulate the shock phenomenon. For the steel plates, the Johnson-Cook material model was employed. For the composite plates both in-plane and out-of-plane failure criteria were employed. In particular, a contact tiebreak formulation with a mixed mode failure criteria was employed to simulate delamination failure. As for the steel plates the results showed that excellent correlation with the experimental data for the two blast load conditions in terms of dynamic and residual deflection for two different C4 charges. For the composite plates the numerical results showed that, as expected, a wider delamination damage was observed

  11. A pH-, salt- and solvent-responsive carboxymethylcellulose-g-poly(sodium acrylate/medical stone superabsorbent composite with enhanced swelling and responsive properties

    Directory of Open Access Journals (Sweden)

    2011-05-01

    Full Text Available Free-radical graft copolymerization among sodium carboxymethylcellulose (CMC, partially neutralized acrylic acid (NaA, medical stone (MS and crosslinker N,N'-methylene-bis-acrylamide (MBA was performed to prepare new carboxymethylcellulose-g-poly(sodium acrylate/medical stone (CMC-g-PNaA/MS superabsorbent composites. Fourier transform infrared (FTIR spectra, thermogravimetry- differential scanning calorimetry (TG-DSC and field emission scanning electromicrsocopic (FESEM analysis confirmed that NaA had been grafted onto CMC backbone and MS participated in polymerization, and the thermal stability and surface morphologies were improved by the addition of MS. Energy dispersive spectrometer (EDS and elemental map (EM analyses revealed the better distribution of MS in the CMC-g-PNaA matrix. The incorporation of 20 wt% MS clearly enhanced the water absorption by 100% (from 317 to 634 g/g. The developed composites showed enhanced swelling rate and On-Off switching swelling characteristics in various pH solutions, saline solutions and hydrophilic organic solvents, which represented interesting and reversible pH-, saline- and hydrophilic organic solvent-responsive characteristics. In addition, the composite exhibited intriguing time-dependent kinetic swelling properties in various heavy metal solutions.

  12. Influence of mechanical load bias on converse magnetoelectric laminate composites

    Science.gov (United States)

    Wu, Tao; Emmons, Michael; Chung, Tien-Kan; Sorge, Jian; Carman, Gregory P.

    2010-05-01

    A piezofiber/Metglas (PFM) magnetoelectric (ME) laminate has been integrated into a graphite epoxy composite (GEC) to study the converse ME effect (CME). Experimental data on a PFM/GEC subjected to both a dc magnetic field bias and a dc mechanical load bias while exciting it with an ac electric driving voltage are presented. Results of these tests indicate that both the mechanical load and the dc magnetic field strongly influence the CME response. Furthermore, an optimum mechanical load exists to maximize the CME coefficient, which should also be present in standalone ME laminates. These results reveal that the CME coefficient can be further increased with a proper mechanical load bias. Therefore, the selection of an appropriate mechanical preload as well as dc magnetic bias will maximize the CME response and sensitivity in ME laminates as well as integrated structural systems.

  13. Micromechanical design of hierarchical composites using global load sharing theory

    Science.gov (United States)

    Rajan, V. P.; Curtin, W. A.

    2016-05-01

    Hierarchical composites, embodied by natural materials ranging from bone to bamboo, may offer combinations of material properties inaccessible to conventional composites. Using global load sharing (GLS) theory, a well-established micromechanics model for composites, we develop accurate numerical and analytical predictions for the strength and toughness of hierarchical composites with arbitrary fiber geometries, fiber strengths, interface properties, and number of hierarchical levels, N. The model demonstrates that two key material properties at each hierarchical level-a characteristic strength and a characteristic fiber length-control the scalings of composite properties. One crucial finding is that short- and long-fiber composites behave radically differently. Long-fiber composites are significantly stronger than short-fiber composites, by a factor of 2N or more; they are also significantly tougher because their fiber breaks are bridged by smaller-scale fibers that dissipate additional energy. Indeed, an "infinite" fiber length appears to be optimal in hierarchical composites. However, at the highest level of the composite, long fibers localize on planes of pre-existing damage, and thus short fibers must be employed instead to achieve notch sensitivity and damage tolerance. We conclude by providing simple guidelines for microstructural design of hierarchical composites, including the selection of N, the fiber lengths, the ratio of length scales at successive hierarchical levels, the fiber volume fractions, and the desired properties of the smallest-scale reinforcement. Our model enables superior hierarchical composites to be designed in a rational way, without resorting either to numerical simulation or trial-and-error-based experimentation.

  14. Damage Characteristic of Interpenetrating Phase Composites under Dynamic Loading

    Institute of Scientific and Technical Information of China (English)

    WANG Fuchi; ZHANG Xu; WANG Yangwei; WANG Lu; MA Zhuang; FAN Qunbo

    2014-01-01

    In order to investigate the damage characteristic of ceramic-metal interpenetrating phase composite (IPC) under dynamic loading, uniaxial dynamic compression was performed to characterize the failure of SiC/Al composite with 15%porosity using a modified Split Hopkinson Pressure Bar (SHPB). High speed photography was used to capture the failure procedure and set up the relationship between deformation and real stress. The deformation control technology was used to obtain collected samples in different deformations under dynamic loading. Micro CT technology was utilized to acquire real damage distribution of these specimens. Moreover, SEM was employed in comparing the damage characteristics in IPC. A summary of the available experimental results showed that IPC without lateral confinement formed double cones. The different features compared with ceramic materials without restraint was shown to be the result of the lateral restraint effect provided by metal phase to ceramics skeleton.

  15. UHPC SANDWICH STRUCTURES WITH COMPOSITE COATING UNDER COMPRESSIVE LOAD

    Directory of Open Access Journals (Sweden)

    Jan Markowski

    2016-12-01

    Full Text Available Ultra-high-performance concrete (UHPC sandwich structures with composite coating serve as multipurpose load-bearing elements. The UHPC’s extraordinary compressive strength is used in a multi-material construction element, while issues regarding the concrete’s brittle failure behaviour are properly addressed. A hollow section concrete core is covered by two steel tubes. The outer steel tube is wrapped in a composite material. By this design, UHPC is used in a material- and shape-optimised way with a low dead weight ratio[1] concerning the load-bearing capacity and stability[2]. The cross-section’s hollow shape optimises the construction’s buckling stability while saving self-weight. The composite coating on the column’s outside functions both as a layer increasing the construction’s durability and as a structural component increasing the the maximum and the residual load capacity. Investigations on the construction’s structural behaviour were performed.

  16. Large Area Nondestructive Evaluation of a Fatigue Loaded Composite Structure

    Science.gov (United States)

    Zalameda, Joseph N.; Burke, Eric R.; Horne, Michael R.; Madaras, Eric I.

    2016-01-01

    Large area nondestructive evaluation (NDE) inspections are required for fatigue testing of composite structures to track damage initiation and growth. Of particular interest is the progression of damage leading to ultimate failure to validate damage progression models. In this work, passive thermography and acoustic emission NDE were used to track damage growth up to failure of a composite three-stringer panel. Fourteen acoustic emission sensors were placed on the composite panel. The signals from the array were acquired simultaneously and allowed for acoustic emission location. In addition, real time thermal data of the composite structure were acquired during loading. Details are presented on the mapping of the acoustic emission locations directly onto the thermal imagery to confirm areas of damage growth leading to ultimate failure. This required synchronizing the acoustic emission and thermal data with the applied loading. In addition, processing of the thermal imagery which included contrast enhancement, removal of optical barrel distortion and correction of angular rotation before mapping the acoustic event locations are discussed.

  17. Microcracking in composite laminates under thermal and mechanical loading. Thesis

    Science.gov (United States)

    Maddocks, Jason R.

    1995-01-01

    Composites used in space structures are exposed to both extremes in temperature and applied mechanical loads. Cracks in the matrix form, changing the laminate thermoelastic properties. The goal of the present investigation is to develop a predictive methodology to quantify microcracking in general composite laminates under both thermal and mechanical loading. This objective is successfully met through a combination of analytical modeling and experimental investigation. In the analysis, the stress and displacement distributions in the vicinity of a crack are determined using a shear lag model. These are incorporated into an energy based cracking criterion to determine the favorability of crack formation. A progressive damage algorithm allows the inclusion of material softening effects and temperature-dependent material properties. The analysis is implemented by a computer code which gives predicted crack density and degraded laminate properties as functions of any thermomechanical load history. Extensive experimentation provides verification of the analysis. AS4/3501-6 graphite/epoxy laminates are manufactured with three different layups to investigate ply thickness and orientation effects. Thermal specimens are cooled to progressively lower temperatures down to -184 C. After conditioning the specimens to each temperature, cracks are counted on their edges using optical microscopy and in their interiors by sanding to incremental depths. Tensile coupons are loaded monotonically to progressively higher loads until failure. Cracks are counted on the coupon edges after each loading. A data fit to all available results provides input parameters for the analysis and shows them to be material properties, independent of geometry and loading. Correlation between experiment and analysis is generally very good under both thermal and mechanical loading, showing the methodology to be a powerful, unified tool. Delayed crack initiation observed in a few cases is attributed to a

  18. Optimization of composite sandwich cover panels subjected to compressive loadings

    Science.gov (United States)

    Cruz, Juan R.

    1991-01-01

    An analysis and design method is presented for the design of composite sandwich cover panels that include the transverse shear effects and damage tolerance considerations. This method is incorporated into a sandwich optimization computer program entitled SANDOP. As a demonstration of its capabilities, SANDOP is used in the present study to design optimized composite sandwich cover panels for for transport aircraft wing applications. The results of this design study indicate that optimized composite sandwich cover panels have approximately the same structural efficiency as stiffened composite cover panels designed to satisfy individual constraints. The results also indicate that inplane stiffness requirements have a large effect on the weight of these composite sandwich cover panels at higher load levels. Increasing the maximum allowable strain and the upper percentage limit of the 0 degree and +/- 45 degree plies can yield significant weight savings. The results show that the structural efficiency of these optimized composite sandwich cover panels is relatively insensitive to changes in core density. Thus, core density should be chosen by criteria other than minimum weight (e.g., damage tolerance, ease of manufacture, etc.).

  19. Assessment of Composite Delamination Self-Healing Under Cyclic Loading

    Science.gov (United States)

    O'Brien, T. Kevin

    2009-01-01

    Recently, the promise of self-healing materials for enhanced autonomous durability has been introduced using a micro-encapsulation technique where a polymer based healing agent is encapsulated in thin walled spheres and embedded into a base polymer along with a catalyst phase. For this study, composite skin-stiffener flange debonding specimens were manufactured from composite prepreg containing interleaf layers with a polymer based healing agent encapsulated in thin-walled spheres. Constant amplitude fatigue tests in three-point bending showed the effect of self-healing on the fatigue response of the skin-stiffener flange coupons. After the cycling that created debonding, fatigue tests were held at the mean load for 24 hours. For roughly half the specimens tested, when the cyclic loading was resumed a decrease in compliance (increase in stiffness) was observed, indicating that some healing had occurred. However, with continued cycling, the specimen compliance eventually increased to the original level before the hold, indicating that the damage had returned to its original state. As was noted in a prevoius study conducted with specimens tested under monotonically increasing loads to failure, healing achieved via the micro-encapsulation technique may be limited to the volume of healing agent available relative to the crack volume.

  20. Load redistribution considerations in the fracture of ceramic matrix composites

    Science.gov (United States)

    Thomas, David J.; Wetherhold, Robert C.

    1992-01-01

    Using a macroscopic viewpoint, composite laminae are homogeneous orthotropic solids whose directional strengths are random variables. Incorporation of these random variable strengths into failure models, either interactive or noninteractive, allows for the evaluation of the lamina reliability under a given stress state. Using a noninteractive criterion for demonstration purposes, laminate reliabilities are calculated assuming previously established load sharing rules for the redistribution of load as the failure of laminae occur. The matrix cracking predicted by ACK theory is modeled to allow a loss of stiffness in the fiber direction. The subsequent failure in the fiber direction is controlled by a modified bundle theory. Results are compared with previous models which did not permit separate consideration of matrix cracking, as well as to results obtained from experimental data. The effects of variations from the ideal physical geometry which is normally used to depict the matrix cracking are also studied.

  1. Composite Bonded Joints’ Lifetime for Aircraft under Random Fatigue Loads

    Directory of Open Access Journals (Sweden)

    Wei Guo Shen

    2014-04-01

    Full Text Available In this present study, a lifetime prediction model of composite bonded joint in aircraft is developed based on variation of its elastic modulus under Random Fatigue Loads (RFL of aircraft and its approach is deduced by Miner linear damage accumulated theory. Considering some assumptions, this prediction model is conservative for aircraft engineering industry. Finally, simulation approach and analysis is developed and done for verification of deduction models. As a precondition, some assumptions are defined for simulation and verification. From simulating results, we can give a conclusion that models are properly accuracy for further study and engineering application.

  2. Areca Fiber Reinforced Epoxy Composites: Effect of Chemical Treatments on Impact Strength

    Directory of Open Access Journals (Sweden)

    S. Dhanalakshmi

    2015-06-01

    Full Text Available In this research work, impact strength of untreated, alkali treated, potassium permanganate treated, benzoyl chloride treated and acrylic acid treated areca fiber reinforced epoxy composites were studied under 40%, 50%, 60% and 70% fiber loadings. Impact strength increased with increase in fiber loading up to 60% and then showed a decline for all untreated and chemically treated areca fiber reinforced epoxy composites. The acrylic acid treated areca fiber reinforced epoxy composites with 60% fiber loading showed highest impact strength of 28.28 J/mm2 amongst all untreated and chemically treated areca/epoxy composites with same 60% fiber loading.

  3. Structural Intensity Characterization of Composite Laminates Subjected to Impact Load

    Institute of Scientific and Technical Information of China (English)

    WANG Dong-fang; HE Peng-fei; LIU Zi-shun

    2008-01-01

    Structural intensity (SI) characterization of composite laminates subjected to impact load was dis-cussed. The SI pattern of the laminates which have different fiber orientations and boundary conditions wasanalyzed. The resultant forces and velocities of the laminates were calculated, and the structural intensity wasevaluated. The SI streamlines of carbon fiber reinforced epoxy composite laminates and the steel plates werediscussed. The results show that the SI streamlines of the graphite/epoxy laminates are different from that ofthe steel plates, and the SI streamlines are influenced by the boundaries, the stacking sequence of the compositelaminates. The change of the historical central displacement of the graphite/epoxy laminates is fasten thanthat of the steel plates.

  4. Study on acrylic acid bentonite of high amount/poly(sodium acrylate) superabsorbent composite Ⅰ :the preparation process and morphology%高含量丙烯酸膨润土/聚丙烯酸钠高吸水性复合材料的研究Ⅰ:制备工艺与形貌

    Institute of Scientific and Technical Information of China (English)

    付丽华; 彭英知; 韦藤幼; 童张法

    2012-01-01

    Superabsorbent composite of high amount of acrylic acid bentonite/poly(sodium acrylic) was synthesized through solution polymerization with acrylic acid bentonite(ABT) and sodium acrylic and acrylic acid. The morphology of the composite was observed by scanning electron microscope(SEM). The results show that a-crylic acid bentonite is evenly and disorder dispersed in the composite with the sheets of 20-30 nm thickness. The preparation process are optimized. The results are as follows. The amount of ABT, crosslinker and initiator are 30wt% , 0. 3wt% , 1. lwt% of the monomer mass respectively. The total water in the system is 340 % of the monomer mass, the neutralization degree is 64 %). The absorbency of the composite is 1103 g/g in deionized water in the conditions. At the same time, the water retention property of the superabsorbent composite(PAA) is better compared to that of PAA.%通过特殊工艺将丙烯酸膨润土(简称ABT)和丙烯酸钠单体采用溶液聚合法制备出高含量丙烯酸膨润土/聚丙烯酸钠高吸水性复合材料(简称HABT/PAA).SEM考察材料的形貌得知,ABT以20~30nm的尺寸较均匀、无序地分散在聚合物基体中,且与聚合物有很好的相容性.对合成工艺进行了优化得到较优的工艺:ABT用量为单体质量的30%(质量分数),交联剂用量为单体质量的0.3%(质量分数),引发剂用量为单体质量的1.1%(质量分数),体系总水量为单体质量的340%(质量分数),中和度为64%,在此条件下,材料吸附去离子水的能力为1103g/g.同时,HABT/PAA的保水性能较聚丙烯酸钠(PAA)好.

  5. Synthesis and Characterization of Chemically Cross-Linked Acrylic Acid/Gelatin Hydrogels: Effect of pH and Composition on Swelling and Drug Release

    Directory of Open Access Journals (Sweden)

    Syed Majid Hanif Bukhari

    2015-01-01

    Full Text Available This present work was aimed at synthesizing pH-sensitive cross-linked AA/Gelatin hydrogels by free radical polymerization. Ammonium persulfate and ethylene glycol dimethacrylate (EGDMA were used as initiator and as cross-linking agent, respectively. Different feed ratios of acrylic acid, gelatin, and EGDMA were used to investigate the effect of monomer, polymer, and degree of cross-linking on swelling and release pattern of the model drug. The swelling behavior of the hydrogel samples was studied in 0.05 M USP phosphate buffer solutions of various pH values pH 1.2, pH 5.5, pH 6.5, and pH 7.5. The prepared samples were evaluated for porosity and sol-gel fraction analysis. Pheniramine maleate used for allergy treatment was loaded as model drug in selected samples. The release study of the drug was investigated in 0.05 M USP phosphate buffer of varying pH values (1.2, 5.5, and 7.5 for 12 hrs. The release data was fitted to various kinetic models to study the release mechanism. Hydrogels were characterized by Fourier transformed infrared (FTIR spectroscopy which confirmed formation of structure. Surface morphology of unloaded and loaded samples was studied by surface electron microscopy (SEM, which confirmed the distribution of model drug in the gel network.

  6. Modeling of damage evaluation in thin composite plate loaded by pressure loading

    Directory of Open Access Journals (Sweden)

    Dudinský M.

    2012-12-01

    Full Text Available This article presents the results of numerical analysis of elastic damage of thin laminated long fiber-reinforced composite plate consisting of unidirectional layers which is loaded by uniformly distributed pressure. The analysis has been performed by means of the finite element method (FEM. The numerical implementation uses layered plate finite elements based on the Kirchhoff plate theory. System of nonlinear equations has been solved by means of the Newton- Raphson procedure. Evolution of damage has been solved using the return-mapping algorithm based on the continuum damage mechanics (CDM. The analysis was performed using own program created in MATLAB. Problem of laminated fiber-reinforced composite plate fixed on edges for two different materials and three different laminate stacking sequences (LSS was simulated. Evolution of stresses vs. strains and also evolution of damage variables in critical points of the structure are shown.

  7. Effect of fiber-reinforced composites on the failure load and failure mode of composite veneers.

    Science.gov (United States)

    Turkaslan, Suha; Tezvergil-Mutluay, Arzu; Bagis, Bora; Vallittu, Pekka k; Lassila, Lippo V J

    2009-09-01

    This study compared the initial and final failure loads and failure modes of indirect resin composite laminate veneers with and without fiber reinforcement. Forty intact lower canines received standard laminate preparations and were randomly assigned into four test groups (n=10). In Group 1, indirect resin composite veneers were repaired with two layers of preimpregnated bidirectional glass fiber weave and a restorative composite; in Group 2, with a layer of preimpregnated unidirectional glass fibers and a restorative composite; and in Group 3, with an experimental semi-IPN matrix composed of multidirectional short glass fibers. Indirect resin composite veneers without any fiber reinforcement were used as control (Group 4). All specimens were thermocycled and tested with a universal testing machine. On the final failure load, there were no statistically significant differences (p>0.05) among the test groups. Within each group, pairwise comparison of initial and final failure loads revealed statistically significant differences (p0.05). On failure mode, unreinforced specimens showed instantaneous failure, whereas reinforced specimens mostly demonstrated elongated failure.

  8. COLLAPSE KINETIC OF COMPOSITES BASED ON COPOLYMERS OF ACRYLIC ACID AND ACRYLAMIDE FILLED WITH BENTONITE IN AQUEOUS SOLUTIONS OF POLYVALENT METALS

    Directory of Open Access Journals (Sweden)

    V. E. Sitnikova

    2017-01-01

    Full Text Available Polymer polyelectrolyte hydrogel composites of acrylic acid and acrylamide copolymer filled with different amounts of bentonite (from 1 to 5 wt.% were synthesized. Collapse kinetics of hydrogel composites was studied in solutions of different concentrations of polyvalent metal salts at a constant temperature of 25 °C. The mass of water given away from hydrogels into the solution was determined by gravimetric method. It has been found that the presence of bentonite in the polyelectrolyte hydrogel composites prevents to some extent collapse in electrolyte solutions, due to steric and electrostatic interactions between the filler particles. These interactions preclude further collapse of hydrogels. The Peleg's kinetic model, most precisely describing experimental data, was applied to calculation of kinetic constants of polymer hydrogels collapse. It is shown that the initial collapse rate and the kinetic constant of collapse and swelling depend non-monotonically on the concentration (ionic strength in the electrolyte solution. At the identical concentration of salts in the solution the kinetic constant of hydrogel collapse is independent of the radius of ions of metals of the studied salts.

  9. Rapid removal of Pb(II) from aqueous solution by chitosan-g-poly(acrylic acid)/attapulgite/ sodium humate composite hydrogels.

    Science.gov (United States)

    Zhang, Junping; Jin, Yeling; Wang, Aiqin

    2011-04-01

    A series of novel granular chitosan-g-poly(acrylic acid)/attapulgite/sodium humate (CTS-g-PAA/APT/SH) composite hydrogels were successfully prepared by one-step free radical graft polymerization and applied as adsorbents for the removal of Pb(II) from aqueous solution. The effects of adsorbent composition (including the contents of APT, SH and CTS) on adsorption capacity and adsorption rate were investigated in detail. Results from kinetic experiments showed that the rate of Pb(II) adsorption on the composite hydrogels was quite fast, that more than 90% of the equilibrium adsorption capacity occurs within two minutes and that the adsorption equilibrium could be achieved within 10 minutes. The adsorption kinetics fit well with the pseudo-second order equation. The introduced SH is helpful for both adsorption capacity and adsorption rate. The -COOH and -COO of PAA, -NH2 of CTS, Ph-O and -COO- of SH, as well as cation exchange and Si-OH of APT, participate in adsorption of Pb(II). The synergistic effect of these groups is responsible for the high adsorption capacity and rate.

  10. Stress analysis in curved composites due to thermal loading

    Science.gov (United States)

    Polk, Jared Cornelius

    Many structures in aircraft, cars, trucks, ships, machines, tools, bridges, and buildings, consist of curved sections. These sections vary from straight line segments that have curvature at either one or both ends, segments with compound curvatures, segments with two mutually perpendicular curvatures or Gaussian curvatures, and segments with a simple curvature. With the advancements made in multi-purpose composites over the past 60 years, composites slowly but steadily have been appearing in these various vehicles, compound structures, and buildings. These composite sections provide added benefits over isotropic, polymeric, and ceramic materials by generally having a higher specific strength, higher specific stiffnesses, longer fatigue life, lower density, possibilities in reduction of life cycle and/or acquisition cost, and greater adaptability to intended function of structure via material composition and geometry. To be able to design and manufacture a safe composite laminate or structure, it is imperative that the stress distributions, their causes, and effects are thoroughly understood in order to successfully accomplish mission objectives and manufacture a safe and reliable composite. The objective of the thesis work is to expand upon the knowledge of simply curved composite structures by exploring and ascertaining all pertinent parameters, phenomenon, and trends in stress variations in curved laminates due to thermal loading. The simply curved composites consist of composites with one radius of curvature throughout the span of the specimen about only one axis. Analytical beam theory, classical lamination theory, and finite element analysis were used to ascertain stress variations in a flat, isotropic beam. An analytical method was developed to ascertain the stress variations in an isotropic, simply curved beam under thermal loading that is under both free-free and fixed-fixed constraint conditions. This is the first such solution to Author's best knowledge

  11. Synthesis of Waterborne Polyurethane-acrylate Composite Emulsions%水性聚氨酯丙烯酸酯复合乳液的合成研究

    Institute of Scientific and Technical Information of China (English)

    陈建福

    2011-01-01

    采用种子溶胀乳液聚合法,以水性聚氨酯为种子,甲基丙烯酸甲酯和丙烯酸丁酯为单体制备水性聚氨酯丙烯酸酯复合乳液,考察了聚合温度、搅拌速度、引发剂种类、引发剂用量及反应时间对聚合过程的影响.结果表明:适宜的聚合温度控制为85℃;适宜的搅拌速率为150~250 r/min;采用水溶性引发剂时引发效率较高,过硫酸钾的最佳用量为0.8%;随着反应时间的增加,乳液粒径先减小后增大.用红外光谱对聚氨酯丙烯酸酯乳液进行分析,表明丙烯酸酯参与了反应.%Polyurethane-acrylate composite emulsions were synthesized by seed swelling polymerization with aqueous polyurethane dispersion as seed,methyl methacrylate and butyl acrylate as vinyl monomers.The influences of polymerization temperature,stirring rare,the species and content of initiator and the reaction time on the polymerization process were investigated.The results showed that the suitable polymerization temperature was 85 ℃ and the stirring rare were between the 150~250 r/min;the initiating efficiency of the water-soluble initiator was higher,and the optimum content of potassium persulphate was 0.8%.The latex particle size decreased and then increased with the increase of reaction time.In addition the arylate was found in polyurethane-acrylate emulsion by FT-IR.

  12. Effect of cyclic loading on microleakage of silorane based composite compared with low shrinkage methacrylate-based composites

    Directory of Open Access Journals (Sweden)

    Hamid Kermanshah

    2016-01-01

    Conclusion: Silorane did not provide better marginal seal than the low shrinkage methacrylate-based composites (except Aelite. In addition, cyclic loading did not affect the marginal microleakage of evaluated composite restorations .

  13. A preliminary study of the composition of commercial oil, acrylic and vinyl paints and their behaviour after accelerated ageing conditions

    Directory of Open Access Journals (Sweden)

    Francesca Caterina Izzo

    2014-12-01

    Full Text Available This study is part of a research project dealing with the establishment of monitoring and damage prevention plans for contemporary artworks. For this purpose, some commercial paints, among the most currently used by young artists, were selected: Winton oil paint (Winsor & Newton, UK, Heavy Body acrylic paint (Liquitex, USA and Flashe vinyl paint (Lefranc & Bourgeois, France. The paints were subjected to different treatments of accelerated ageing, the results indicating different behaviour in relation both to the type of binders and pigments present in the different formulations. In particular, it was observed that ageing produced by ozone plays an important role in the stability of the oil paints, above all in those containing organic azo pigments. Thermal ageing, as expected, influences the stability of all the commercial paints examined, with the formation of alteration products and visible changes in the paint films. Ageing produced by moisture clearly affects the synthetic polymer-based paints, particularly evident in the changes in mass. In all cases, the accelerated ageing treatments produced chromatic variations, more evidently for the oil paints containing organic pigment.

  14. Biodegradability and mechanical properties of poly(butylene succinate) composites with finely dispersed hydrophilic poly(acrylic acid)

    Science.gov (United States)

    Mizuno, Sawako; Hotta, Atsushi

    2014-03-01

    Biodegradability and mechanical properties of aliphatic poly(butylene succinate) (PBS) films with finely dispersed hydrophilic poly(acrylic acid) (PAA) were investigated. First, 3.5 wt% of PAA was chemically grafted onto the surface of the PBS films (surface-grafted PBS) by photo grafting polymerization, and then the grafted PAA was homogeneously and finely dispersed into PBS by dissolving the surface-grafted PBS into chloroform before mixing and drying to get solid PAA-dispersed PBS. Degradation of these modified PBS was investigated using gel permeation chromatography (GPC) and tensile testing. According to the GPC results, it was found that the PAA-dispersed PBS had intermediate biodegradability with the intermediate water intake, and the reaction constant of PAA-dispersed PBS was in between those of untreated PBS and surface-grafted PBS, in fact 25% higher and 17% lower, respectively. The experimental results presented that the biodegradability of PBS could be well controlled by the dispersion of PAA, possibly leading to the widespread use of PBS for biodegradable polymers.

  15. Requalification analysis of a circular composite slab for seismic load

    Energy Technology Data Exchange (ETDEWEB)

    Srinivasan, M.G.; Kot, C.A.

    1992-11-01

    The circular roof slab of an existing facility was analyzed to requalify the structure for supporting a significant seismic load that it was not originally designed for. The slab has a clear span of 66 ft and consists of a 48 in thick reinforced concrete member and a steel liner plate. Besides a number of smaller penetrations, the slab contains two significant cutouts: a 9 ft square opening and a 3 ft dia hole. The issues that complicated the analysis of this non-typical structure, i.e., composite action and nonlinear stiffness of reinforced concrete (R. C.) sections, are discussed. It was possible to circumvent the difficulties by making conservative and simplifying assumptions. If codes incorporate guidelines on practical methods for dynamic analysis of R. C. structures, some of the unneeded conservatism could be eliminated in future designs.

  16. COMPOSITE STRENGTHENING SOLUTIONS FOR REINFORCED CONCRETE LOAD BEARING ELEMENTS

    Directory of Open Access Journals (Sweden)

    Nicolae ȚĂRANU

    2015-11-01

    Full Text Available The results of a complex research and development program relating to the use of fiber reinforced polymeric composite strengthening solutions carried out at the Faculty of Civil Engineering and Building Services Iasi, are presented in this paper. The program has included the conceiving of the structural rehabilitation systems, the detailing and experimental testing of some solutions applied to reinforced concrete beams, slabs and columns (with circular and square cross-section. An efficient use of the component materials to improve the structural performance of the studied reinforced concrete element has been the main target of the research program. The main benefits resulted from the research program refer to the increase of the load capacities, the improvement of the structural response of all strengthened elements and a better control of the failure modes.

  17. Composite Vessels for Containment of Extreme Blast Loadings

    Energy Technology Data Exchange (ETDEWEB)

    Pastrnak, J; Henning, C; Grundler, W; Switzer, V; Hollaway, R; Morrison, J; Hagler, L; Kokko, E; Deteresa, S; Hathcoat, B; Dalder, E

    2004-07-15

    A worldwide trend for explosives testing has been to replace open-air detonations with containment vessels, especially when any hazardous materials are involved. As part of the National Nuclear Security Administration's (NNSA) effort to ensure the safety and reliability of the nation's nuclear stockpile, researchers at Lawrence Livermore National Laboratory have been developing a high performance filament wound composite firing vessel that is nearly radiographically transparent. It was intended to contain a limited number of detonations of metal cased explosive assemblies in radiographic facilities such as the Advanced Hydrodynamic Facility (AHF) being studied by Los Alamos National Laboratory. A 2-meter diameter pressure vessel was designed to contain up to 35 kg (80 lb) of TNT equivalent explosive without leakage. Over the past 5 years a total of three half-scale (1 meter diameter) vessels have been constructed, and two of them were tested to 150% load with 8.2 kg (18-pound) spheres of C4 explosive. The low density and high specific strength advantages used in this composite vessel design may have other additional applications such as transporting sensitive explosives that could otherwise be moved only in very small quantities. Also, it could be used for highly portable, explosive containment systems for law enforcement.

  18. Synthesis and characterization of chitosan-graft-poly(acrylic acid)/rice husk ash hydrogels composites; Sintese e caracterizacao de hidrogeis compositos de cinza da casca de arroz e quitosana enxertada com poli(acido acrilico)

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Francisco H.A. [Universidade Estadual Vale do Acarau - UVA, Sobral, CE (Brazil); Lopes, Gabriel V.; Pereira, Antonio G.B.; Fajardo, Andre R.; Muniz, Edvani C. [Universidade Estadual de Maringa - UEM, PR (Brazil)

    2011-07-01

    According to environmental concerns, super absorbent hydrogel composites were synthesized based on rice husk ash (RHA), an industrial waste, and Chitosan-graft-poly(acrylic acid). The WAXS and FTIR data confirmed the syntheses of hydrogel composites. The effect of crystalline or amorphous RHA on water uptake was investigated. It was found that the RHA in crystalline form induces higher water capacity (W{sub eq}) of composites hydrogels due to the fact that the intra-interactions among silanol groups on RHA make available new sites in the polymer matrix, which could interact to water. (author)

  19. Color stability and flexural strength of poly (methyl methacrylate) and bis-acrylic composite based provisional crown and bridge auto-polymerizing resins exposed to beverages and food dye: an in vitro study.

    Science.gov (United States)

    Gujjari, Anil K; Bhatnagar, Vishrut M; Basavaraju, Ravi M

    2013-01-01

    To evaluate the color stability and flexural strength of poly (methyl methacrylate) (PMMA) and bis-acrylic composite based provisional crown and bridge auto-polymerizing resins exposed to tea, coffee, cola, and food dye. Two provisional crown and bridge resins, one DPI self-cure tooth molding powder (PMMA) (Group A), and one Protemp 4 Temporization Material (bis-acrylic composite) (Group B) were used. Disk-shaped specimens for color stability testing (n = 30 for each material) and bar-shaped specimens for flexural strength testing (n = 30 for each material) were fabricated using a metal mold. The specimens were immersed in artificial saliva, artificial saliva + tea, artificial saliva + coffee, artificial saliva + cola, and artificial saliva + food dye solutions and stored in an incubator at 37°C. Color measurements were taken before immersion, and then after 3 and 7 days of immersion. Flexural strength was evaluated after 7 days of immersion. Group A showed significantly higher color stability as compared to Group B, and artificial saliva + coffee solution had the most staining capacity for the resins. Test solutions had no effect on the flexural strength of Group A, but Group B specimens immersed in artificial saliva + cola showed significantly lower flexural strength values as compared to the control group. The findings of the study showed that for materials used in the study, PMMA was more color stable than bis-acrylic composite based resin. Also, material based on PMMA was more resistant to damage from dietary beverages as compared to bis-acrylic composite based provisional crown and bridge resin.

  20. Acrylate Systemic Contact Dermatitis.

    Science.gov (United States)

    Sauder, Maxwell B; Pratt, Melanie D

    2015-01-01

    Acrylates, the 2012 American Contact Dermatitis Society allergen of the year, are found in a range of products including the absorbent materials within feminine hygiene pads. When fully polymerized, acrylates are nonimmunogenic; however, if not completely cured, the monomers can be potent allergens.A 28-year-old woman is presented, who had her teeth varnished with Isodan (Septodont, Saint-Maur-des-Fossés, France) containing HEMA (2-hydroxyethyl methacrylate) with no initial reaction. Approximately 1 month later, the patient developed a genital dermatitis secondary to her feminine hygiene pads. The initial reaction resolved, but 5 months later, the patient developed a systemic contact dermatitis after receiving a second varnishing.The patient was dramatically patch test positive to many acrylates. This case demonstrates a reaction to likely unpolymerized acrylates within a feminine hygiene pad, as well as broad cross-reactivity or cosensitivity to acrylates, and possibly a systemic contact dermatitis with systemic re-exposure to unpolymerized acrylates.

  1. Effect of fiber loading on the mechanical properties of bagasse fiber–reinforced polypropylene composites

    OpenAIRE

    2016-01-01

    It is evident that sugarcane/bagasse is a highly potential natural composite fiber. In this study, the correlation of composition fiber amount to the mechanical strength was presented. Bagasse was treated with alkali and then reinforced in polypropylene by means of hot pressing. Fiber loading was set to be varied from 10 to 20 wt%. Composite samples were subjected to tensile, hardness, and flexural characterization. Composites with 30 wt% of fiber loading registered maximum tensile strength w...

  2. Synthesis of berberine loaded polymeric nanoparticles by central composite design

    Science.gov (United States)

    Mehra, Meenakshi; Sheorain, Jyoti; Kumari, Santosh

    2016-04-01

    Berberine is an isoquinoline alkaloid which is extracted from bark and roots of Berberis vulgaris plant. It has been used in ayurvedic medicine as it possess antimicrobial, antidiabetic, anticancer, antioxidant properties etc. But poor solubility of berberine leads to poor stability and bioavailability in medical formulations decreasing its efficacy. Hence nanoformulations of berberine can help in removing the limiting factors of alkaloid enhancing its utilization in pharmaceutical industry. Sodium alginate polymer was used to encapsulate berberine within nanoparticles by emulsion solvent evaporation method using tween 80 as a surfactant. Two factors and three level in central composite design was used to study the formulation. The optimized formulation (1% v/v of Tween 80 and 0.01% w/v of sodium alginate) of polymeric nanoparticles was taken for further evaluations. The size of synthesized nanoparticles was found to be 71.18 nm by particle size analysis (PSA). The berberine loaded polymeric nanoparticles showed better antibacterial activity compared to aqueous solution of berberine by well diffusion assay.

  3. Exploring the piezoelectric performance of PZT particulate-epoxy composites loaded in shear

    NARCIS (Netherlands)

    Loock, F.V.; Deutz, D.B.; Zwaag, S.V.D.; Groen, W.A.

    2016-01-01

    The active and passive piezoelectric response of lead zirconium titanate (PZT)-epoxy particulate composites loaded in shear is studied using analytical models, a finite element model and by experiments. The response is compared to that of the same composites when loaded in simple tension. Analogousl

  4. Effect of a silane coupling agent on the optical and the mechanical characteristics of nanodiamond/acrylic resin composites

    Science.gov (United States)

    Jeong, Min-Gun; Chun, Yoon-Soo; Lim, Dae-Soon; Kim, Jung Youl

    2014-10-01

    Nanodiamond (ND) is a good candidate for a filler material to fabricate transparent films. This study explores a characterization of the optical and the mechanical properties of ND dispersed polymer films. An attrition milling method was adapted to break ND aggregates, and a silane coupling agent (3-methacryloxypropyltrimethoxysilane) was used to modify the ND surfaces and stabilize the dispersion. Dipentaerylthritol hexaacrylate and pentaerythritol tetraacrylate were used in the polymer matrix, and up to 3 wt.% of ND was added to improve the mechanical properties. Fabricated composites were analyzed and tested using UV-visible spectroscopy for the optical properties and a Micro-Vickers hardness tester and ball-on-disktype friction tester for the mechanical properties. Results show that the transmittance of the ND-added composite increased with decreasing aggregate size. Through the addition of small amounts of NDs, the mechanical properties were greatly improved, the material became 3.5 times as hard, and the wear rate were greatly decreased. Possible mechanisms responsible for the enhancement of the mechanical and the optical properties are discussed.

  5. Study on epoxy-acrylate copolymer composite emulsion%环氧丙烯酸酯共聚物复合乳液研究

    Institute of Scientific and Technical Information of China (English)

    郭文录; 朱华伟; 张莉

    2011-01-01

    A water-based epoxy-acrylate hybrid emulsion was prepared by core-shell emulsion polymerization with epoxy-modified acrylate emulsion. The acrylate before and after modification were characterized by contact angle and polarization curve measurements, as well as Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA) and electrochemical impedance spectroscopy (EIS) techniques. The results proved that the hydrophobicity, thermal stability and corrosion resistance of the acrylate modified by 12% epoxy resin are improved evidently, as compared with the unmodified acrylate.%通过核壳乳液聚合工艺引入环氧树脂,对丙烯酸醋乳液进行改性,制备了水性环氧/丙烯酸醋杂化乳液.通过接触角、极化曲线测试以及傅里叶变换红外光谱(FT-IR)、热重分析(TGA)、电化学阻抗谱(EIS)等方法对改性前后的丙烯酸醋进行了表征.结果表明,以12%环氧树脂改性的丙烯酸醋与改性前的丙烯酸酣相比,其疏水性、热稳定性和耐蚀性能都有较大的改进.

  6. Thermography Inspection for Early Detection of Composite Damage in Structures During Fatigue Loading

    Science.gov (United States)

    Zalameda, Joseph N.; Burke, Eric R.; Parker, F. Raymond; Seebo, Jeffrey P.; Wright, Christopher W.; Bly, James B.

    2012-01-01

    Advanced composite structures are commonly tested under controlled loading. Understanding the initiation and progression of composite damage under load is critical for validating design concepts and structural analysis tools. Thermal nondestructive evaluation (NDE) is used to detect and characterize damage in composite structures during fatigue loading. A difference image processing algorithm is demonstrated to enhance damage detection and characterization by removing thermal variations not associated with defects. In addition, a one-dimensional multilayered thermal model is used to characterize damage. Lastly, the thermography results are compared to other inspections such as non-immersion ultrasonic inspections and computed tomography X-ray.

  7. The Effect of Water Acrylate Dispersion on the Properties of Polymer-Carbon Nanotube Composites / Wpływ Wodnej Dyspersji Akrylanowej Na Właściwości Kompozytów Polimer-Nanorurki Węglowe

    Directory of Open Access Journals (Sweden)

    Zygoń P.

    2015-12-01

    Full Text Available The paper presents properties of polymer composites reinforced with carbon nanotubes (CNT containing various mixtures of dispersion. Acrylates of different particle size and viscosity were used to produce composites. The mechanical strength of composites was determined by three-point bending tests. The roughness parameter of composites was determined with a profilometer and compared with the roughness parameter determined via atomic force microscopy (AFM. Also X-ray studies (phase composition analysis, crystallite sizes determination were carried out on these composites. Measurements of the surface topography using the Tapping Mode method were performed, acquiring the data on the height and on the phase imaging. The change of intensity, crystallite size and half-value width of main reflections originating from carbon within the composites have been determined using the X-ray analysis. The density of each obtained composite was determined as well as the resistivity at room temperature. The density of composites is quite satisfactory and ranges from 0.27 to 0.35 g/cm3. Different composites vary not only in strength but also in density. Different properties were achieved by the use of various dispersions. Carbon nanotubes constituting the reinforcement for a polymer composite improve the mechanical properties and conductivity composite.

  8. Investigating the tension load of rubber composites by impact dynamic testing

    Indian Academy of Sciences (India)

    L AMBRIŠKO; D MARASOVÁ; M CEHLÁR

    2017-04-01

    This work deals with establishing the tension load by impact dynamic testing of rubber composite conveyor belts. The value of tension load affects the shape of the used impactor and use of a support system as well as the weight of the ram and the impact height. An increase in the allowable stress when the belt is tensioned was examined during the test, to determine the effect of impact on the tension load. The obtained values of tension load are assessed using basic mathematical and statistical methods. Using the Design of Experiments method, factors that significantly affect the value of the tension load are identified.

  9. Effects of Simulated Functional Loading Conditions on Dentin, Composite, and Laminate Structures

    Science.gov (United States)

    Walker, Mary P.; Teitelbaum, Heather K.; Eick, J. David; Williams, Karen B.

    2008-01-01

    Use of composite restorations continues to increase, tempered by more potential problems when placed in posterior dentition. Thus, it is essential to understand how these materials function under stress-bearing clinical conditions. Since mastication is difficult to replicate in the laboratory, cyclic loading is frequently used within in vitro evaluations but often employs traditional fatigue testing, which typically does not simulate occlusal loading because higher stresses and loading frequencies are used, so failure mechanisms may be different. The present investigation utilized relevant parameters (specimen size; loading frequency) to assess the effects of cyclic loading on flexural mechanical properties and fracture morphology of (coronal) dentin, composite, and dentin-adhesive-composite “laminate” structures. Incremental monitoring of flexural modulus on individual beams over 60,000 loading cycles revealed a gradual increase across materials; post-hoc comparisons indicated statistical significance only for 1 versus 60k cycles. Paired specimens were tested (one exposed to 60k loading cycles, one to static loading only), and comparisons of flexural modulus and strength showed statistically significantly higher values for cyclically-loaded specimens across materials, with no observable differences in fracture morphology. Localized reorganization of dentin collagen and polymer chains could have increased flexural modulus and strength during cyclic loading, which may have implications toward the life and failure mechanisms of clinical restorations and underlying tooth structure. PMID:18823019

  10. Electrical Response of Cement-Based Piezoelectric Ceramic Composites under Mechanical Loadings

    Directory of Open Access Journals (Sweden)

    Biqin Dong

    2011-01-01

    Full Text Available Electrical responses of cement-based piezoelectric ceramic composites under mechanical loadings are studied. A simple high order model is presented to explain the nonlinear phenomena, which is found in the electrical response of the composites under large mechanical loadings. For general situation, this nonlinear piezoelectric effect is quite small, and the composite is suitable for dynamic mechanical sensor as holding high static stability. The experimental results are consistent with the relationship quite well. The study shows that cement-based piezoelectric composite is suitable for potential application as dynamic mechanical sensor with excellent dynamic response and high static stability.

  11. Internal load transfer and damage evolution in a 3D interpenetrating metal/ceramic composite

    Energy Technology Data Exchange (ETDEWEB)

    Roy, Siddhartha, E-mail: siddhartha.roy@kit.edu [Institute for Applied Materials, Karlsruhe Institute of Technology, 76131 Karlsruhe (Germany); Gibmeier, Jens; Kostov, Vladimir; Weidenmann, Kay Andre [Institute for Applied Materials, Karlsruhe Institute of Technology, 76131 Karlsruhe (Germany); Nagel, Alwin [Hochschule Aalen, Beethovenstr. 1, 73430 Aalen (Germany); Wanner, Alexander [Institute for Applied Materials, Karlsruhe Institute of Technology, 76131 Karlsruhe (Germany)

    2012-08-15

    Highlights: Black-Right-Pointing-Pointer Internal load transfer and compressive damage in an interpenetrating composite is studied. Black-Right-Pointing-Pointer Unloading and reloading in tension initiates damage in alumina phase. Black-Right-Pointing-Pointer Load reversal causes Bauschinger effect in aluminium solid solution. Black-Right-Pointing-Pointer Compressive damage occurs by cracks at 45 Degree-Sign through the ceramic rich regions. - Abstract: The internal load transfer and compressive damage evolution in an interpenetrating Al{sub 2}O{sub 3}/AlSi12 composite have been studied in this work. The composite was fabricated by squeeze-casting eutectic aluminium-silicon alloy melt in a porous alumina preform. The preform was fabricated from a mixture of cellulose fibres and alumina particles via cold pressing and sintering. In an earlier work we reported the internal load transfer in the same composite material under monotonic compression and tension studied using energy dispersive synchrotron X-ray diffraction . The current work is a continuation of this earlier study, aimed at obtaining further understanding about load transfer occurring during load reversal and damage behaviour during external compression. The micromechanical load partitioning between the three phases present in the composite is studied during one load cycle starting in compression followed by unloading and reloading in tension until failure. Average strain and stress value in each phase is calculated from several diffraction planes of each phase and as a result the reported strain and stress are representative of the bulk material behaviour. The load transfer results allow identifying the occurrence of a substantial Bauschinger effect in the Al solid solution phase and progressive damage evolution within the alumina phase. In situ compression test inside a scanning electron microscope showed that failure of the composite occurred by propagation of cracks through the ceramic rich regions

  12. ACRYLATE-AMIDE FOAM CARDIOVASCULAR PROSTHESES.

    Science.gov (United States)

    thoracic and abdominal aorta. The use of a composite construction utilizing acrylate-amide foam is being evaluated in prostheses for mitral valve ...bleeding. The success of the initial experimental work has led to a clinical trial in which 99 replacement , bypass, or patch-angioplasty procedures... replacement , superior vena cava patch venoplasty, and esophageal replacement . (Author)

  13. FRP Composites Strengthening of Concrete Columns under Various Loading Conditions

    Directory of Open Access Journals (Sweden)

    Azadeh Parvin

    2014-04-01

    Full Text Available This paper provides a review of some of the progress in the area of fiber reinforced polymers (FRP-strengthening of columns for several loading scenarios including impact load. The addition of FRP materials to upgrade deficiencies or to strengthen structural components can save lives by preventing collapse, reduce the damage to infrastructure, and the need for their costly replacement. The retrofit with FRP materials with desirable properties provides an excellent replacement for traditional materials, such as steel jacket, to strengthen the reinforced concrete structural members. Existing studies have shown that the use of FRP materials restore or improve the column original design strength for possible axial, shear, or flexure and in some cases allow the structure to carry more load than it was designed for. The paper further concludes that there is a need for additional research for the columns under impact loading senarios. The compiled information prepares the ground work for further evaluation of FRP-strengthening of columns that are deficient in design or are in serious need for repair due to additional load or deterioration.

  14. Assessment of particulate cellulose epoxy composites manufactured by JMFIL under impact load

    Science.gov (United States)

    Srinivasababu, Nadendla

    2015-08-01

    Increase in environmental concern towards sustainable development invites the development of new materials which are eco-friendly to satisfy various engineering needs. The present work introduces a new manufacturing method i.e. "Just Mold Fill and Immediate Loading" to prepare epoxy composites reinforced at different contents of particulate cellulose. The fabricated composites specimens are post processed and machined, tested as per ASTM procedures under impact load.

  15. Stacking sequence optimisation of composite panels subjected to slamming impact loads using a genetic algorithm

    OpenAIRE

    Khedmati,Mohammad Reza; Sangtabi,Mohammad Rezai; Fakoori,Mehdi

    2013-01-01

    Optimisation of stacking sequence for composite panels under slamming impact loads using a genetic algorithm method is studied in this paper. For this purpose, slamming load is assumed to have a uniform distribution with a triangular-pulse type of intensity function. In order to perform optimisation based on a genetic algorithm, a special code is written in MATLAB software environment. The optimiser is coupled with the commercial software ANSYS in order to analyse the composite panel under st...

  16. Development of Composite Scaffolds for Load Bearing Segmental Bone Defects

    Science.gov (United States)

    2013-07-01

    composite scaffolds designed to serve as bone regenerative therapies . We analyzed the benefits and drawbacks of different composite scaffold...related to fractures, sport and blast injuries. Diseases include bone cancer (osteosarcoma), tumor resection and reconstruction, osteoporosis ...selection for the scaffold has a direct impact on the biological and physical properties of the construct, there are some factors contributing to the

  17. Optimization of sandwich composites fuselages under flight loads

    NARCIS (Netherlands)

    Yan, C.; Bergsma, O.; Koussios, S.; Zu, L.; Beukers, A.

    2010-01-01

    The sandwich composites fuselages appear to be a promising choice for the future aircrafts because of their structural efficiency and functional integration advantages. However, the design of sandwich composites is more complex than other structures because of many involved variables. In this paper,

  18. Thermography Inspection for Detection and Tracking of Composite Cylinder Damage During Load Testing

    Science.gov (United States)

    Zalameda, J. N.; Winfree, W. P.; Seebo, J. P.; Johnston, P. H.

    2010-01-01

    Two thermography techniques, passive and active, are used to detect damage initiation and progression in a cyclically loaded composite cylinder. The passive thermography tracks damage progression in real time during cyclic loading. Active flash thermography, using a flash tube enclosed within the cylinder, images delaminations in a cylinder under different loads. A differential thermography processing technique eliminates normal material variations and improves sensitivity to and sizing of delaminations. The thermography results were compared to nonimmersion ultrasonic results.

  19. Effects of Simulated Functional Loading Conditions on Dentin, Composite, and Laminate Structures

    OpenAIRE

    Walker, Mary P.; Teitelbaum, Heather K.; Eick, J. David; Williams, Karen B.

    2009-01-01

    Use of composite restorations continues to increase, tempered by more potential problems when placed in posterior dentition. Thus, it is essential to understand how these materials function under stress-bearing clinical conditions. Since mastication is difficult to replicate in the laboratory, cyclic loading is frequently used within in vitro evaluations but often employs traditional fatigue testing, which typically does not simulate occlusal loading because higher stresses and loading freque...

  20. Impact loading of an aluminum/alumina composite

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, J.N.; Hixson, R.S.; Gray, G.T. III

    1994-02-01

    The combined demands of increased strength and reduced weight in modern dynamic structural applications require improved understanding of composite materials subject to impact conditions. In order to isolate and identify individual contributions to composite material behavior under these conditions, an experimental and theoretical program was undertaken to examine dynamic behavior of an aluminum/alumina composite consisting of a 6061-T6 aluminum matrix containing elastic, spherical Al{sub 2}O{sub 3} inclusions (10 percent by volume, average diameter {approximately}25 microns). Parallel impact experiments are conducted on these composites and on pure 6061-T6 aluminum samples. This combination provides a direct and immediate qualitative picture of the effect of Al{sub 2}O{sub 3} inclusions the dynamic response of the composite in compression, release, and spallation. Additional experimental information is provided by post-shock reload tests of shock-recovered samples at quasi-static and intermediate strain rates.

  1. Temperature Effects on Hybrid Composite Plates Under Impact Loads

    Directory of Open Access Journals (Sweden)

    Metin SAYER

    2009-03-01

    Full Text Available In this work, impact responses of carbon-glass fiber/epoxy (hybrid composites were investigated under various temperatures and increasing impact energies. The increasing impact energies were applied to the specimens at various temperatures as -20, 0, 20 and 40 oC until perforation took place of specimens. Those specimens are composed by two types of fiber orientation with eight laminates hybrid composites. An Energy profiling diagram, used for showing the relationship between impact and absorbed energy, has been used to obtain penetration and perforation thresholds of hybrid composites. Beside those, temperature effects on impact characteristics such as maximum contact force (Fmax, total deflection (d and maximum contact duration (t were also presented in figures. Finally, glass and carbon fibers exhibited more brittle characteristics at -20 oC according to other temperatures. So, perforation threshold of each hybrid composites at -20 oC was found higher than other temperatures. Keywords : Hybrid composite

  2. Effect of fiber loading on the mechanical properties of bagasse fiber–reinforced polypropylene composites

    Directory of Open Access Journals (Sweden)

    Sivarao Subramonian

    2016-08-01

    Full Text Available It is evident that sugarcane/bagasse is a highly potential natural composite fiber. In this study, the correlation of composition fiber amount to the mechanical strength was presented. Bagasse was treated with alkali and then reinforced in polypropylene by means of hot pressing. Fiber loading was set to be varied from 10 to 20 wt%. Composite samples were subjected to tensile, hardness, and flexural characterization. Composites with 30 wt% of fiber loading registered maximum tensile strength while with 10 wt% fiber loading registered the minimum. Hardness increases with the amount of fiber. Flexural strength and flexural modulus were found to be greater than original polypropylene. Scanning electron microscopy examination revealed the mechanisms of the strength gain in morphological point of view. The findings give manufactures and engineers a sound basis decision whether to apply the use of this composite for weight reduction especially in automotive applications or not.

  3. Controlled release and antibacterial activity of tetracycline hydrochloride-loaded bacterial cellulose composite membranes.

    Science.gov (United States)

    Shao, Wei; Liu, Hui; Wang, Shuxia; Wu, Jimin; Huang, Min; Min, Huihua; Liu, Xiufeng

    2016-07-10

    Bacterial cellulose (BC) is widely used in biomedical applications. In this study, we prepared an antibiotic drug tetracycline hydrochloride (TCH)-loaded bacterial cellulose (BC) composite membranes, and evaluated the drug release, antibacterial activity and biocompatibility. The structure and morphology of the fabricated BC-TCH composite membranes were characterized using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The TCH release results show that the incorporation of BC matrix to load TCH is able to control the release. In vitro antibacterial assay demonstrate that the developed BC-TCH composites displayed excellent antibacterial activity solely associated with the loaded TCH drug. More importantly, the BC-TCH composite membranes display good biocompatibility. These characteristics of BC-TCH composite membranes indicate that they may successfully serve as wound dressings and other medical biomaterials.

  4. Intermediate-scale Fire Performance of Composite Panels under Varying Loads

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Alexander [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Jernigan, Dann A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Dodd, Amanda B. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-04-01

    New aircraft are being designed with increasing quantities of composite materials used in their construction. Different from the more traditional metals, composites have a higher propensity to burn. This presents a challenge to transportation safety analyses, as the aircraft structure now represents an additional fuel source involved in the fire scenario. Most of the historical fire testing of composite materials is aime d at studying kinetics, flammability or yield strength under fire conditions. Most of this testing is small - scale. Heterogeneous reactions are often length - scale dependent, and this is thought to be particularly true for composites which exhibit signific ant microscopic dynamics that can affect macro - scale behavior. We have designed a series of tests to evaluate composite materials under various structural loading conditions with a consistent thermal condition. We have measured mass - loss , heat flux, and temperature throughout the experiments. Several types of panels have been tested, including simple composite panels, and sandwich panels. The main objective of the testing was to understand the importance of the structural loading on a composite to its b ehavior in response to fire - like conditions. During flaming combustion at early times, there are some features of the panel decomposition that are unique to the type of loading imposed on the panels. At load levels tested, fiber reaction rates at later t imes appear to be independent of the initial structural loading.

  5. Aeroelastic Loads Modeling for Composite Aircraft Design Support

    NARCIS (Netherlands)

    Baluch, H.A.

    2009-01-01

    With regard to the simulation of structural vibrations and consequent aeroelastic loads in aircraft components, the use of elastic axis e.a as reference of vibrations is quite common. The e.a decouples the bending and torsion degrees of freedom (D.o.F) during the dynamic analysis. The use of the e.a

  6. Aeroelastic Loads Modeling for Composite Aircraft Design Support

    NARCIS (Netherlands)

    Baluch, H.A.

    2009-01-01

    With regard to the simulation of structural vibrations and consequent aeroelastic loads in aircraft components, the use of elastic axis e.a as reference of vibrations is quite common. The e.a decouples the bending and torsion degrees of freedom (D.o.F) during the dynamic analysis. The use of the e.a

  7. Estimation of the Residual Fatigue Life of Laminated Composites Under a Multistage Cyclic Loading

    Science.gov (United States)

    Strizhius, V.

    2016-11-01

    Problems on estimation of the residual fatigue life of laminated composites under a multistage regular cyclic loading (with a constant amplitude at each loading stage) are among the most frequently ones encountered in the practice of fatigue life estimations of laminated composites. There are several methods for solving these problems, but their use not always gives results of acceptable accuracy. To improve the accuracy of such estimations for the type of cyclic loading mentioned, a special model of nonlinear accumulation of fatigue damage is proposed.

  8. Preparation of anti-yellowing polyurethane-acrylate hybrid emulsion with composite polyols%多元醇复配制备耐黄变聚氨酯丙烯酸酯复合乳液

    Institute of Scientific and Technical Information of China (English)

    沈慧芳; 严小妹; 刘天亮

    2011-01-01

    以异佛尔酮二异氰酸酯( IPDI)、混合多元醇、甲基丙烯酸甲酯(MMA)为主要原料合成了脂肪族聚氨酯丙烯酸酯复合乳液.混合多元醇由聚碳酸酯二醇( PCDL)、聚四亚甲基醚二醇(PTMEG)、聚醚二醇( N220)以不同比例复配而成.重点探讨了PCDL与N220、PTMEG与N220及PTMEG与PCDL复配比例对乳液、胶膜性能的影响.实验发现,当PTMEG与N220以相同质量比复配且控制硬段含量在60%时,得到贮存稳定性好,胶膜硬度高、耐水、耐溶剂性能好、耐黄变性优异的PUA复合乳液.%The aliphatic polyurethane-acrylate hybrid emulsions were prepared with isophorone diisocyanate (IPDI),composite polyols,and methyl methacrylate (MMA) as the main raw materials.The composite polyols were obtained by mixing polytetramethylene ether glycol (PTMEG) and polyether diol(N220),PTMEG and polycarbonate diol (PCDL),PCDL and N220 respectively at different ratio.The influences of mixing ratio of polyols on the properties of polyurethane-acrylate hybrid emulsions and their dry films were mainly discussed.The results showed that the polyurethane-acrylate hybrid emulsions had good stability,high film hardness,good water resistance and solvent resistance and excellent yollowing resistance when PTMEG and N220 were mixed by the same mass ratio and the content of hard segments was 60% in polyurethane prepolymer.

  9. HYDROESTERIFICATION OF ACETYLENE WITH METHYL FORMATE TO METHYL ACRYLATE OVER A NiO/Al203 CATALYST: EFFECTS OF NiO LOADING AND CALCINATION TEMPERATURE

    Institute of Scientific and Technical Information of China (English)

    Huang Xinhan; Yang Xiangui; Zhang Jiaqi; Liu Zhaotie

    2001-01-01

    Hydroesterification of acetylene with methyl formate (MF) was studied over a series of nickel-supported catalysts with NiO loading varing from 0.8 wt% to 18.7 wt% and calcination temperature ranging from 623 K to 873 K. The catalyst was studied by TPR, XPS, XRD and BET. The interactions between impregnated Ni2+ and alumina during catalyst preparation produced different kinds of nickel species such as NiO crystallites and NiAl2O4-like species, and their distributions varied with NiO loading and calcination temperature, which leads to different activities of catalyst in hydroesterification of acetylene with methyl formate. Experimental results indicated that 10wt% NiO/Al2O3 calcined at 773 K is suitable for the hydroesterification of acetylene with methyl formate.

  10. Compressive damage mechanism of GFRP composites under off-axis loading: Experimental and numerical investigations

    DEFF Research Database (Denmark)

    Zhou, H.W.; Li, H.Y.; Gui, L.L.;

    2013-01-01

    Experimental and computational studies of the microscale mechanisms of damage formation and evolution in unidirectional glass fiber reinforced polymer composites (GFRP) under axial and off-axis compressive loading are carried out. A series of compressive testing of the composites with different a...

  11. General Factor Loadings and Specific Effects of the Differential Ability Scales, Second Edition Composites

    Science.gov (United States)

    Maynard, Jennifer L.; Floyd, Randy G.; Acklie, Teresa J.; Houston, Lawrence, III

    2011-01-01

    The purpose of this study was to investigate the "g" loadings and specific effects of the core and diagnostic composite scores from the Differential Abilities Scales, Second Edition (DAS-II; Elliott, 2007a). Scores from a subset of the DAS-II standardization sample for ages 3:6 to 17:11 were submitted to principal factor analysis. Four composites,…

  12. Influence of high loading of cellulose nanocrystals in polyacrylonitrile composite films

    Science.gov (United States)

    Jeffrey Luo; Huibin Chang; Amir A. Bakhtiary Davijani; H. Clive Liu; Po-Hsiang Wang; Robert J. Moon; Satish Kumar

    2017-01-01

    Polyacrylonitrile-co-methacrylic acid (PAN-co-MAA) and cellulose nanocrystal (CNC) composite films were produced with up to 40 wt% CNC loading through the solution casting method. The rheological properties of the solution/suspensions and the structural, optical, thermal, and mechanical properties of the resulting films were investigated. The viscosity of the composite...

  13. Consolidation Theory for a Stone Column Composite Foundation under Multistage Loading

    Directory of Open Access Journals (Sweden)

    Shenggen Huang

    2016-01-01

    Full Text Available The consolidation theories considering instant load cannot fully reveal the consolidation mechanism of a stone column composite foundation used in the expressway embankments due to the time effect of loading; that is, the expressway embankments are often constructed in several stages for a long time. Meanwhile, owing to the special property that the pile-soil stress ratio is larger than 1, the consolidation theory for sand drain well foundation cannot be used directly in the consolidation analysis of stone column composite foundation. Based on the principle that the vertical load applied on the composite foundation is shared by the stone column and the surrounding soil, the governing solutions for the stone column composite foundation under a multistage load are established. By virtue of the separation of variables, the corresponding solutions of degree of consolidation for loading stage and maintaining load stage are derived separately. According to the Carrillo theorem, the solution for the average total degree of consolidation of entire composite foundation is also obtained. Finally, the reasonableness of the present solution has been verified by comparing the consolidation curve calculated by the present solution with that measured by site test.

  14. Electrospun and functionalized PVDF/PAN nanocatalyst-loaded composite for dechlorination and photodegradation of pesticides in contaminated water.

    Science.gov (United States)

    Nthumbi, Richard M; Ngila, Jane C

    2016-10-01

    A novel approach for the electrospinning and functionalization of nanocatalyst-loaded polyvinylidene fluoride/polyacrylonitrile (PVDF/PAN) composite grafted with acrylic acid (AA; which form polyacrylic acid (PAA) brush) and decorated with silver (Ag/PAN/PVDF-g-PAA-TiO2/Fe-Pd) designed for the dechlorination and photodegradation of pesticides was carried out. PAN was used both as a nitrogen dopant as well as a co-polymer. Smooth nanofibers were obtained by electrospinning a solution of 12:2 wt.% PVDF/PAN blend using dimethylformamide (DMF) as solvent. The nanofibers were grafted with AA by free-radical polymerization using 2,2'azobis(2-methylpropionitrile) (AIBN) as initiator. Both bimetallic iron-palladium (Fe-Pd) and titania (TiO2) nanoparticles (NP) were anchored on the grafted nanofibers via the carboxylate groups by in situ and ex situ synthesis. The Fe-Pd and nitrogen-doped TiO2 nanoparticles were subsequently used for dechlorination and oxidation of target pollutants (dieldrin, chlorpyrifos, diuron, and fipronil) to benign products. Structural and chemical characterizations of the composites were done using various techniques. These include surface area and porosity analyzer (ASAP) using the technique by Brunner Emmett Teller (BET), Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscope (TEM) analyses were done. After dechlorination, the transformation products (TPs) for dieldrin, chlorpyrifos, diuron, and fipronil were obtained and identified using two-dimensional gas chromatography (time-of-flight) with a mass spectrometer detector (GCxGC-TOFMS). Analysis of total organic carbon (TOC) was carried out and used to extrapolate percentage mineralization. Experimental results showed that dechlorination efficiencies of 96, 93, 96, and 90 % for 1, 2, 2, and 3 h treatment period were respectively achieved for 5 ppm solutions of dieldrin, chlorpyrifos, diuron, and fipronil. The

  15. Analysis and Load Rating of Pre-flex Composite Beams

    Science.gov (United States)

    2011-09-01

    buildings and bridges in Asia and Europe (Staquet et al. 2004). The Southern Tower (Tour du Midi) in Belgium employs this system. Other common ...specified by its manufac- turers and varies from 19.62 kN (4,410 lb) to 44.1 kN (9,920 lb). Common practice in the design of reinforced concrete assumes... Mallow = maximum moment allowed Ppf = maximum pre-flexion load fs = allowable stress in steel section Sx = section modulus of steel

  16. Micromechanical Analysis of Interfacial Debonding in Metal Matrix Composites Subjected to off-axis Loading

    Institute of Scientific and Technical Information of China (English)

    Xiaojun Zhu; Xuefeng Chen; Zhi Zhai; Qiang Chen; Shaohua Tian; Zhengjia He

    2013-01-01

    This study aims to investigate the effects of interfacial debonding and fiber volume fraction on the stress -strain behavior of the fiber reinforced metal matrix composites subjected to off -axis loading .The generalized method of cells ( GMC) is used to analyze a representative element whose fiber shape is circular .The constant compliant interface model (CCI) is also adopted to study the response of composites with imperfect interfacial bonding .Results show that for the com-posites subjected to off-axis loading ,the mechanical behaviors are affected appreciably by the interfacial debonding and the fiber volume fraction .

  17. DYNAMIC ANALYSIS OF UNDERGROUND COMPOSITE STRUCTURES UNDER EXPLOSION LOADING

    Institute of Scientific and Technical Information of China (English)

    赵晓兵; 薛大为; 赵玉祥

    2004-01-01

    In selecting rational types of underground structures resisting explosion, in order to improve stress states of the structural section and make full use of material strength of each part of the section, the research method of composite structures is presented. Adopting the analysis method of micro-section free body, equilibrium equations, constraint equations and deformation coordination equations are given. Making use of the concept of generalized work and directly introducing Lagrange multiplier specific in physical meaning, the validity of the constructed generalized functional is proved by using variation method. The rational rigidity matching relationship of composite structure section is presented through example calculations.

  18. Research on Mechanical Behaviors of Micro-crystal Muscovite/UHMWPE Composites to Impact Loading

    Directory of Open Access Journals (Sweden)

    Hu Huarong

    2016-01-01

    Full Text Available UHMWPE composites were prepared by hot pressing process with micro-crystal muscovite as reinforced particulates. The mechanical behaviors of composites to impact loading was evaluated by split Hopkinson bar. The results demonstrated that dynamic yield stress and failure stress of UHMWPE composites were gradually increased when the filling amount was less than 20%; when the filling content of muscovite was around 15%, the energy absorption efficiency of the composite reaches maximum value. It was also found that when strain rate within 3200/s, the dynamic yield stress, failure stress and energy absorption efficiency of UHMWPE composites increased with the increase of strain rate and display strain rate enhancement effect.

  19. Ethyl-cyanoethyl Cellulose/Poly(Acrylic Acid) Composite: Cholesteric Structure and Optical Property%乙基氰乙基纤维素/聚丙烯酸复合物膜结构和光学性能

    Institute of Scientific and Technical Information of China (English)

    王林格; 黄勇

    2003-01-01

    Ethyl-cyanoethyl cellulose [(E-CE)C]/poly(acrylic acid) (PAA) composite films were prepared by photopolymerizing acrylic acid (AA) in (E-CE)C/AA cholesteric liquid crystalline solutions. Investigation of the structure and optical property of the (E-CE)C/PAA cholesteric composite and was undertaken by using UV-VIS spectroscopy and TEM. It was found that the wavelength of reflection light was a function of the concentration, the reflectivity was increased with increasing the film's thickness and was decreased quickly when temperature above 160 ℃.%乙基氰乙基纤维素[(E-CE)C]可溶解在丙烯酸(AA)中形成胆甾相液晶,通过光聚合AA,原胆甾相结构可以被"固定"在(E-CE)C/聚丙烯酸(PAA)复合物中,其结构和选择性反射光性能通过电镜和紫外-可见光光谱进行了研究.研究表明该复合物膜的反射光波长和浓度呈指数关系,反射光强度与膜厚有一定关系,并在低于160 ℃时有很好的热稳定性.

  20. Properties of natural rubber/attapulgite composites prepared by latex compounding method: Effect of filler loading

    Energy Technology Data Exchange (ETDEWEB)

    Muttalib, Siti Nadzirah Abdul, E-mail: sitinadzirah.amn@gmail.com; Othman, Nadras, E-mail: srnadras@usm.my; Ismail, Hanafi, E-mail: ihanafi@usm.my [School of Materials and Mineral Resources Engineering, Engineering Campus, Universiti Sains Malaysia, Seri Ampangan, 14300 Nibong Tebal, Pulau Pinang (Malaysia)

    2015-07-22

    This paper reports on the effect of filler loading on properties of natural rubber (NR)/attapulgite (ATP) composites. The NR/ATP composites were prepared by latex compounding method. It is called as masterbatch. The masterbatch was subsequently added to the NR through melt mixing process. The vulcanized NR/ATP composites were subjected to mechanical, swelling and morphological tests. All the results were compared with NR/ATP composites prepared by conventional system. The composites from masterbatch method showed better results compared to composites prepared by conventional method. They have higher tensile properties, elongation at break and tear strength. The images captured through scanning electron microscopy test revealed the improvement of tensile strength in masterbatch NR/ATP composites. It can be seen clearly that masterbatch NR/ATP have better filler dispersion compared to conventional method NR/ATP composites.

  1. Research on torsional friction behavior and fluid load support of PVA/HA composite hydrogel.

    Science.gov (United States)

    Chen, Kai; Zhang, Dekun; Yang, Xuehui; Cui, Xiaotong; Zhang, Xin; Wang, Qingliang

    2016-09-01

    Hydrogels have been extensively studied for use as synthetic articular cartilage. This study aimed to investigate (1) the torsional friction contact state and the transformation mechanism of PVA/HA composite hydrogel against CoCrMo femoral head and (2) effects of load and torsional angle on torsional friction behavior. The finite element method was used to study fluid load support of PVA/HA composite hydrogel. Results show fluid loss increases gradually of PVA/HA composite hydrogel with torsional friction time, leading to fluid load support decreases. The contact state changes from full slip state to stick-slip mixed state. As the load increases, friction coefficient and adhesion zone increase gradually. As the torsional angle increases, friction coefficient and slip trend of the contact interface increase, resulting in the increase of the slip zone and the reduction of the adhesion zone. Fluid loss increases of PVA/HA composite hydrogel as the load and the torsional angle increase, which causes the decrease of fluid load support and the increase of friction coefficient.

  2. Self-sensing piezoresistive cement composite loaded with carbon black particles

    KAUST Repository

    Monteiro, André O.

    2017-04-27

    Strain sensors can be embedded in civil engineering infrastructures to perform real-time service life monitoring. Here, the sensing capability of piezoresistive cement-based composites loaded with carbon black (CB) particles is investigated. Several composite mixtures, with a CB filler loading up to 10% of binder mass, were mechanically tested under cyclic uniaxial compression, registering variations in electrical resistance as a function of deformation. The results show a reversible piezoresistive behaviour and a quasi-linear relation between the fractional change in resistivity and the compressive strain, in particular for those compositions with higher amount of CB. Gage factors of 30 and 24 were found for compositions containing 7 and 10% of binder mass, respectively. These findings suggest that the CB-cement composites may be a promising active material to monitor compressive strain in civil infrastructures such as concrete bridges and roadways.

  3. Static and dynamic moduli of posterior dental resin composites under compressive loading.

    Science.gov (United States)

    Tanimoto, Yasuhiro; Hirayama, Satoshi; Yamaguchi, Masaru; Nishiwaki, Tsuyoshi

    2011-10-01

    Dental resin composites are commonly used as restorative materials for dental treatment. To comprehend the static and dynamic moduli of dental resin composites, we investigated the mechanical behaviors of resin composites under static and dynamic loading conditions. Four commercially available resin composites for posterior restorations were evaluated. The percentages, by weight, of inorganic fillers of resin composites were examined by the ashing technique. The static compressive tests were undertaken with a constant loading speed of 1.0 mm/min using a computer-controlled INSTRON testing machine. The dynamic properties of composites were determined using the split Hopkinson pressure bar (SHPB) technique. When inorganic filler content was increased, a remarkable increase in the static modulus and dynamic modulus were observed. Furthermore, there was a strong relationship between the static modulus and dynamic modulus (r(2) = 0.947). The SHPB technique clearly demonstrated the dynamic properties of composites, and was a useful technique for determining the mechanical behavior of composites under dynamic compressive loading. Copyright © 2011 Elsevier Ltd. All rights reserved.

  4. Influence of applied load on wear behavior of C/C-Cu composites under electric current

    Directory of Open Access Journals (Sweden)

    Jian Yin

    2017-04-01

    Full Text Available Using carbon fiber needled fabrics with Cu-mesh and graphite powder as the preform, Cu mesh modified carbon/carbon(C/C-Cu composites were prepared by chemical vapor deposition (CVD with C3H6 and impregnation-carbonization (I/C with furan resin. C/C composites, as a comparison, were also prepared. Their microstructures and wear morphologies were observed by optical microscopy (OM and scanning electron microscope (SEM, respectively. Wear behavior of C/C and C/C-Cu composites under different applied loads were investigated on a pin-on-disc wear tester. The results show that Cu meshes are well dispersed and pyrolytic carbon is in rough laminar structure. Both C/C and C/C-Cu composites had good wear properties. The current-carrying capacity of C/C-Cu composites increases and the arc discharge is hindered as the applied load increases from 40 N to 80 N. Both C/C and C/C-Cu composites had good wear properties. The mass wear rate of C/C-Cu composites under 80 N was only 4.2% of that under 60 N. In addition, C/C-Cu composites represent different wear behaviors because wear mechanisms of arc erosion, abrasive wear, adhesive wear, and oxidative wear are changing under different applied loads.

  5. Evaluation of Composite Honeycomb Sandwich Panels Under Compressive Loads at Elevated Temperatures

    Science.gov (United States)

    Walker, Sandra P.

    1998-01-01

    Fourteen composite honeycomb sandwich panels were tested to failure under compressive loading. The test specimens included panels with both 8 and 24-ply graphite-bismaleimide composite facesheets and both titanium and graphite-polyimide core materials. The panels were designed to have the load introduced through fasteners attached to pairs of steel angles on the ends of the panels to simulate double shear splice joints. The unloaded edges were unconstrained. Test temperatures included room temperature, 250F, and 300F. For the room and 250F temperature tests, the 24-ply specimen failure strains were close to the unnotched allowable strain values and failure loads were well above the design loads. However, failure strains much lower than the unnotched allowable strain values, and failure loads below the design loads were observed with several of the 8-ply specimens. For each individual test temperature, large variations in the failure strains and loads were observed for the 8-ply specimens. Dramatic decreases in the failure strains and loads were observed for the 24-ply specimens as the test temperature was increased from 250F to 300F. All 8-ply specimens appeared to have failed in a facesheet strength failure mode for all test temperatures. The 24-ply specimens displayed appreciably greater amounts of bending prior to failure than the 8-ply specimens, and panel buckling occurred prior to facesheet strength failure for the 24-ply room and 250F temperature tests.

  6. The effects of rattan filler loadings on properties of rattan powder-filled polypropylene composites

    Directory of Open Access Journals (Sweden)

    Nurshamila Shaari Balakrishna

    2012-11-01

    Full Text Available This study investigates the effects of filler loading on the properties of rattan powder-filled polypropylene composites. The composites were prepared by incorporating rattan powder of average size 180 µm into polypropylene matrix using a Polydrive Thermo Haake internal mixer. Filler loadings of the rattan powders ranged between 0 and 40 parts per hundred parts of resin (phr. Mechanical, morphological, and thermal properties were studied. The tensile strength, elongation at tensile failure, and impact strength decreased, while stabilization torque, thermal stability, and water absorption increased with increasing filler loading. Tensile modulus increased with addition of rattan powder and eventually decreased at 40 phr filler loading due to the weakening adhesion between the filler and the matrix. The morphological studies of fractured surfaces using SEM confirmed the deterioration in tensile properties.

  7. Composite slab behavior and strength analysis under static and dynamic loads

    Directory of Open Access Journals (Sweden)

    Florin Radu HARIGA

    2012-07-01

    Full Text Available Steel-framed buildings are typically constructed using steel-deck-reinforced concrete floor slabs. The in-plane (or diaphragm strength and stiffness of the floor system are frequently utilized in the lateral load-resisting system design. This paper presents the results of an experimental research program in which four full size composite diaphragms were vertically loaded to the limit state, under static or dynamic loads. Two test specimens were provided with longitudinal steel-deck ribs, and the other two specimens with cross steel-deck ribs. Typical composite diaphragm limit states are described, and the controlling limit state for each of the full size tests is indicated. The interaction effects between the reinforced concrete slab and the steel girder on the composite slab strength and stiffness were mainly studied.

  8. Acrylic mechanical bond tests

    Energy Technology Data Exchange (ETDEWEB)

    Wouters, J.M.; Doe, P.J.

    1991-02-01

    The tensile strength of bonded acrylic is tested as a function of bond joint thickness. 0.125 in. thick bond joints were found to posses the maximum strength while the acceptable range of joints varied from 0.063 in. to almost 0.25 in. Such joints are used in the Sudbury Neutrino Observatory.

  9. Hyperbranched urethane-acrylates

    Directory of Open Access Journals (Sweden)

    Tasić Srba

    2004-01-01

    Full Text Available The synthesis, characterization and UV-curing of hyperbranched urethaneacrylates (HB-UA were investigated in this study. They were evaluated as oli-gomers in model UV curable coatings. HB-UAs were synthesized by reaction of an aliphatic hyperbranched polyester of the second generation (HBRG2 and an isocyanate adduct, obtained by the reaction of isophoronediisocyana-te and different hydroxy alkyl acrylates. Their thermal properties and viscosities depend on the degree of modification of HBRG2 and the type of hydroxy alkyl acrylate used. The introduction of a flexible alkoxylated spacer between the HBP core and acrylate end groups reduces steric hindrance by moving the cross linkable acrylate groups away from the HBP core and increase its reactivity. Due to the presence of abstractable H-atoms in the α-position to the ether links, HB-UAs based on poly(ethylene oxide monoacrylate are very reactive and do not show oxygen inhibition. The obtained coatings combine a high cross linking density with flexible segments between the cross links, which results in a good compromise between hardness and flexibility and have the potential to be used in different UV-curing applications.

  10. Deformation and failure mechanisms of graphite/epoxy composites under static loading

    Science.gov (United States)

    Clements, L. L.

    1981-01-01

    The mechanisms of deformation and failure of graphite epoxy composites under static loading were clarified. The influence of moisture and temperature upon these mechanisms were also investigated. Because the longitudinal tensile properties are the most critical to the performance of the composite, these properties were investigated in detail. Both ultimate and elastic mechanical properties were investigated, but the study of mechanisms emphasized those leading to failure of the composite. The graphite epoxy composite selected for study was the system being used in several NASA sponsored flight test programs.

  11. Influence of metal loading on hydrocracking of rapeseed oil using bifunctional micro-/mesoporous composite materials

    Energy Technology Data Exchange (ETDEWEB)

    Gille, T.; Busse, O.; Reschetilowski, W. [Technische Univ. Dresden (Germany). Inst. of Industrial Chemistry

    2013-11-01

    Hydrocracking of rapeseed oil has been investigated in a fixed bed reactor under integral conditions. A synthesized micro-/mesoporous composite material Al-MCM-41/ZSM-5 modified by different metal loadings (NiMo, PtNiMo, Pt) was used as catalyst system. It could be demonstrated that the support material and their metal loading influence the product selectivity as well as the deactivation tendencies of the catalyst sample. (orig.)

  12. Optimization Formulations for the Maximum Nonlinear Buckling Load of Composite Structures

    DEFF Research Database (Denmark)

    Lindgaard, Esben; Lund, Erik

    2011-01-01

    , benchmarked on a number of numerical examples of laminated composite structures for the maximization of the buckling load considering fiber angle design variables. The optimization formulations are based on either linear or geometrically nonlinear analysis and formulated as mathematical programming problems...... solved using gradient based techniques. The developed local criterion is formulated such it captures nonlinear effects upon loading and proves useful for both analysis purposes and as a criterion for use in nonlinear buckling optimization. © 2010 Springer-Verlag....

  13. Sensing Applied Load and Damage Effects in Composites with Nondestructive Techniques

    Science.gov (United States)

    2017-05-01

    used in industry based on materials such as glass fiber, Kevlar, and carbon fiber combined with various types of epoxy.4,6 Carbon fiber-reinforced...coupons were composed of Torayca T700G/2510 unidirectional carbon fiber prepreg material. Unidirectional ply properties were given by the manufacturer...into tension- tension fatigue testing. Initial loading is done slowly and in steps to capture data while the composite sample is under loading but

  14. Effect of cyclic loading on the bond strength of class II restorations with different composite materials.

    Science.gov (United States)

    Cavalcanti, Andrea Nóbrega; Mitsui, Fabio Hiroyuki Ogata; Silva, Flávia; Peris, Alessandra Rezende; Bedran-Russo, Ana; Marchi, Giselle Maria

    2008-01-01

    This study evaluated the effect of cyclic loading on the bond strength of Class II restorations using different composite materials. Class II preparations with gingival margins located in dentin were performed on the mesial surface of 80 bovine incisors. The teeth were randomly allocated to eight groups (n=10) according to resin composite (Filtek Z250, Filtek Supreme, Tetric Ceram HB and Esthet-X) and use of cyclic loading. The restorations were bonded with the Single Bond adhesive system. Simulated aging groups were cyclic loaded for 200,000 cycles with 80N load (2Hz). The specimens were vertically sectioned (two slabs per restoration) and further trimmed into an hour-glass shape at the adhesive interface to obtain a final bonded area 1 mm2. Samples were placed in an apparatus and tested under tension using a universal testing machine. The data were analyzed using two-way ANOVA and Tukey test with a 95% confidence level. Aged groups presented significantly lower means when compared to the groups that were not aged (p=0.03). However, significant differences among composite materials were not observed (p=0.17). Regardless of the restorative composite material used, it could be concluded that the bond strength of Class II restorations at the gingival wall was affected by simulated cyclic loading.

  15. In vitro and in vivo efficacy of doxorubicin loaded biodegradable semi-interpenetrating hydrogel implants of poly (acrylic acid)/gelatin for post surgical tumor treatment.

    Science.gov (United States)

    Jaiswal, Maneesh; Naz, Farhat; Dinda, Amit K; Koul, Veena

    2013-08-01

    The paper describes the preparation and evaluation of doxorubicin loaded semi-interpenetrating polymeric hydrogel network of polyacrylic acid (PAc) and gelatin (G). Post surgical antitumor efficacy and biodistribution of doxorubicin from the implanted degradable hydrogels was investigated on Ehrlich's ascites tumor model using albino mice. Polycaprolactone diacrylate (PCL-DAr) was employed as a crosslinking agent for PAc chains whereas G was kept free. The effect of crosslinking concentration on various physico-chemical properties such as thermal behavior, swelling, degradation behavior, drug release and polymer-polymer interactions was investigated by various physico-chemical tools. Semi-interpenetrating polymeric networks (IPNs) with 0.2 mol% crosslinking concentration showed degradation within 20 days in phosphate buffer (pH 6.5). To determine the in vivo anticancer efficacy, placebo and drug laden cylindrical implants (65 ± 5 µg/implant of 10 mg) were implanted in tumor cavity post tumor excision. After predetermined time intervals (day 7, 11, 14, 20 and 25), drug biodistribution was assessed in tumor, tumor periphery, residual hydrogel and all vital organs i.e. liver, spleen, kidney, heart, lung and blood (spectrofluorimetrically). The drug distribution study showed the concentration of drug in the tumor, tumor periphery and residual hydrogel decreased with increasing time; on the 7th day, drug concentration was highest while, on the 25th day, it was negligible; however, insignificant quantities of the drug was found in vital organs. Histological examination revealed no sign of tumor recurrence until the 25th day with 100% necrosis and slight inflammation in treated the group. In vivo results established that these biodegradable implants can be utilized as post surgical therapy for solid tumors.

  16. INFLUENCE OF LOADING RATE ON DYNAMIC FRACTURE BEHAVIOR OF FIBER-REINFORCED COMPOSITES

    Institute of Scientific and Technical Information of China (English)

    Kezhuang Gong; Zheng Li; Weizhong Qin

    2008-01-01

    The effect of loading rate on the dynamic fracture properties and the failure mechanisms of glass fiber-reinforced composite materials under mode I fracture is studied.Dynamic reflective caustic experiments are carried out for two loading rates.By measuring the characteristic dimensions of the shadow spots during the caustic experiments,the dynamic SIFs are calculated for different loading rates.The experimental results indicate that the dynamic fracture toughness KId increases remarkably with increasing loading rate,and the crack grows faster under the high-velocity impact.Moreover,by examining the crack growth routes and the fracture surfaces,it is shown that the loading rate also greatly affects the failure mechanisms at micro-scale.

  17. Importance of anisotropy on design of compression-loaded composite corrugated panels

    Science.gov (United States)

    Gurdal, Zafer; Young, Richard D.

    1990-01-01

    An investigation is conducted of the importance of anisotropic terms in the design of composite corrugated panels, for a range of axial compressive load intensities. The two panel configurations treated were panels with tailored laminates and panels with a continuous laminate; both are of interest to aircraft designers and prone to anisotropic effects which are of as-yet undetermined extent. The importance of the anisotropic terms is measured by the difference between the design load and the buckling load obtained from the ultimate structural analysis.

  18. Some important aspects in testing high-modulus fiber composite tubes designed for multiaxial loading.

    Science.gov (United States)

    Sullivan, T. L.; Chamis, C. C.

    1972-01-01

    Tubular specimens were potted in metal grips to determine the feasibility of this gripping method in applying multiaxial loads. Strain gage rosettes were used to assess grip transitional strains, through thickness strain variation and strain variations along the tube length and circumference. The investigation was limited to loading 0, 45, plus or minus 45, and 90 deg graphite/epoxy and glass/epoxy tubes in axial tension. Results include modifications made to the grips to reduce transitional strains, illustrations of the tube failure modes, and some material properties. The gripping concept shows promise as a satisfactory technique for applying multiaxial loads to high-strength, high-modulus fiber composite tubes.

  19. Water absorbency properties of chitosan-g-poly(acrylic acid sodium )/kaolin superabsorbent composite%壳聚糖接枝聚丙烯酸钠/高岭土复合树脂的吸水性能

    Institute of Scientific and Technical Information of China (English)

    谢华飞; 贾振宇; 尹国强; 崔英德

    2011-01-01

    Increasing global demand for improved absorbent materials with biodegradable, non-toxic, antimicrobial, and salt-tolerant properties creates an incentive for research and development of efficient absorbent materials and systems with additional benefits, such as biodegradability or certain biomedical functions. Organic-inorganic superabsorbent composite emerges to meet this demand. Chitosan grafted poly (acrylic acid sodium)/kaolin superabsorbent composite was prepared by solution polymerization in this paper. The absorption rate and repeated absorption properties in distilled water, water absorbency in artificial urine solution, and the influence at different temperatures, electrolyte concentrations and pH values on absorbency properties of the superabsorbent composite were discussed, respectively. The results showed that absorption rate of superabsorbent composite was slower than that of polyacrylic resin and chitosan grafted polyarylic resin and water absorbency decreased with increasing repeat number, and water absorbency in artificial urine solution was higher than poly (acrylic acid) and lower than chitosan grafted poly (acrylic acid). As temperature increased, water absorbency was enhanced, while began to drop after 50 ℃. Water absorbency of superabsorbent composite decreased simultaneously when ionic strength and valence of electrolyte solution increased. Along with the increase of pH value, the absorption curve showed a hump at pH = 3. 5 and pH = 8. 5. According to this study, basic information of absorbency properties about organic-inorganic superabsorbent composite based on chitosan, poly (acrylic acid) and kaolin was provided.%利用溶液聚合法制备了壳聚糖接枝聚丙烯酸钠/高岭土复合树脂,研究了复合树脂在蒸馏水中的吸水速率、重复吸水性能和人工尿液中的吸水倍率,以及在不同温度、不同电解质溶液离子强度和不同pH值的环境下复合树脂的吸水性能.结果表明,复合树脂的

  20. Synthesis and photocatalytic activity of carbon spheres loaded Cu{sub 2}O/Cu composites

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yinhui, E-mail: lillian09281@hotmail.com; Zhao, Mengyao; Zhang, Na; Li, Ruijuan; Chen, Jianxin

    2015-09-15

    Highlights: • Carbon spheres loaded Cu{sub 2}O/Cu composites are obtained by hydrothermal process. • Cu{sub 2}O/Cu nanocrystals grow on the surface of carbon spheres. • The composites with core–shell structure show highly photo-catalytic activity. • The composites can degrade methyl orange under simulated solar light irradiation. • The composites can be used to treat dye wastewater or organic pollutants. - Abstract: In this work, using amylose as carbon source and cupric acetate as copper source, carbon spheres loaded Cu{sub 2}O/Cu composites were obtained by hydrothermal synthesis. The effects of the molar ratios between glucose and Cu(II), and hydrothermal time on the morphology and sizes of the composites were investigated. The result of photocatalytic experiments demonstrated that the composites could degrade methyl orange in aqueous solution under simulated solar light irradiation. The highest degradation rate was achieved to 93.83% when the composites were prepared by hydrothermal synthesis at 180 °C for 16 h and the molar ratio between glucose and Cu(II) was 10/1. The composites, as new and promising materials, can be used to treat dye wastewater or other organic pollutants.

  1. DELAMINATION FORMATION AND DELAMINATION PROPAGATION OF COMPOSITE LAMINATES UNDER COMPRESSIVE FATIGUE LOADING

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Fatigue tests of the smooth composite laminates and the notched composite laminates under compressive cyclic loading have been carried out. The damage mechanism is discussed and analyzed. Damage evolution is monitored using stiffness decay. From these tests, it is found that the initial delamination occurs at the free boundary of smooth specimens, or the notch boundary of notched specimens, subjected to the compression-compression cyclic load. A point of view in relation to two-phases of compression fatigue delamination of composites is proposed, namely, compression-compression delamination consists of the delamination formation phase and the delamination propagation, and there is a "damage transition point" to separate this two-phases. Furthermore, an empirical modulus degradation formula and its parameters fitting method are presented. According to the test data handling results, it is shown that this formula is univocal and can fit the test data conveniently. In addition, two kinds of new anti-buckling devices are designed for these tests. At last, the E-N curves, the D-N curves and the S-N curve of the smooth carbon fiber reinforced composite laminates of T300/648C are determined to predict the fatigue life of the notched composite laminate. And the E-N curve of the notched specimens at the given load ratio R=10 and minimum load P min=-0.45 kN is also measured to verify the estimated result of fatigue life.

  2. Experimental Investigation on Laminated Composite Leaf springs Subjected to Cyclic Loading

    Directory of Open Access Journals (Sweden)

    S.Rajesh

    2014-03-01

    Full Text Available An automobile industry have an interest in replacement of conventional leaf spring with composite leaf spring to get better performance with less weight. This paper deals with by replacing the conventional leaf spring with composite leaf spring. The dimensions of an existing conventional steel leaf spring of a light commercial vehicle were taken to fabricate the special die which is further used to manufacture the composite leaf spring. A single leaf with constant cross sectional area similar to that of conventional leaf spring(CLS in each case such as bidirectional glass fiber reinforced plastic (GFRP, bidirectional carbon fiber reinforced plastic (CFRP, bidirectional carbon-glass reinforced plastic (C-GFRP and bidirectional glass-carbon reinforced plastic (G-CFRP were fabricated by hand layup technique and tested by universal testing machine. By using universal testing machine, load per deflection and maximum load that a leaf spring can withstand were measured. The cyclic loading with specific duration was given to the above mentioned composite leaf springs by using a laboratory designed loading set up through milling machine. From the experimented results it was observed that if conventional leaf springs are replaced by composite leaf springs an appropriate amount of weight reduction and there by improved vehicle performance could be achieved.

  3. Self-Sensing of Damage Progression in Unidirectional Multiscale Hierarchical Composites Subjected to Cyclic Tensile Loading

    Science.gov (United States)

    Ku-Herrera, J. J.; Pacheco-Salazar, O. F.; Ríos-Soberanis, C. R.; Domínguez-Rodríguez, G.; Avilés, F.

    2016-01-01

    The electrical sensitivity of glass fiber/multiwall carbon nanotube/vinyl ester hierarchical composites containing a tailored electrically-percolated network to self-sense accumulation of structural damage when subjected to cyclic tensile loading-unloading is investigated. The hierarchical composites were designed to contain two architectures differentiated by the location of the multiwall carbon nanotubes (MWCNTs), viz. MWCNTs deposited on the fibers and MWCNTs dispersed within the matrix. The changes in electrical resistance of the hierarchical composites are associated to their structural damage and correlated to acoustic emissions. The results show that such tailored hierarchical composites are able to self-sense damage onset and accumulation upon tensile loading-unloading cycles by means of their electrical response, and that the electrical response depends on the MWCNT location. PMID:26999158

  4. Advanced thermoplastic composites: An attractive new material for usage in highly loaded vehicle components

    Energy Technology Data Exchange (ETDEWEB)

    Mehn, R.; Seidl, F.; Peis, R.; Heinzmann, D.; Frei, P. [BMW AG Muenchen (Germany)

    1995-10-01

    Beside the lightweight potential and further well known advantages of advanced composite materials, continuous fiber reinforced thermoplastics employed in vehicle structural parts especially offer short manufacturing cycle times and an additional economically viable manufacturing process. Presenting a frame structure concept for two highly loaded vehicle parts, a safety seat and a side door, numerous features concerning the choice of suitable composite materials, design aspects, investigations to develop a thermoforming technique, mature for a series production of vehicle parts, are discussed.

  5. Enhanced photocatalytic activity of fish scale loaded TiO2 composites under solar light irradiation

    Institute of Scientific and Technical Information of China (English)

    Li-Ngee Ho; Soon-An Ong; Hakimah Osman; Fong-Mun Chong

    2012-01-01

    Fish scale (FS) loaded TiO2 composites were investigated as photocatalysts in degradation of Methyl Orange under solar light irradiation.Composites were prepared through sol-gel method by varying mass ratio of TiO2/FS at 90:10,70:30 and 50:50,respectively.The catalysts prepared in this study were characterized by using XRD,SEM,FT-IR and nitrogen sorption.The effects of solar irradiation,mass ratio of TiO2/FS composites,irradiation time and catalyst loadings were studied.Synergistic effect was found in TiO2/FS of 90:10 composite which performed higher photocatalytic degradation than synthesized TiO2 under solar light irradiation.However,further increasing fish scale content in the composites reduced the photocatalytic activity drastically.Under solar light irradiation,all the catalysts in this study exhibited photocatalytic activity,except TiO2/FS of 50:50 composite that only acted as a weak biosorbent without performing any photocatalytic property.Photocatalytic degradation increased with increasing catalyst loading and irradiation time but decreased with increased of initial dye concentration.

  6. Loading rate sensitivity of open-hole composite specimens in compression

    Science.gov (United States)

    Lubowinski, S. J.; Guynn, E. G.; Elber, W.; Whitcomb, J. D.

    1990-01-01

    The results are reported of an experimental study on the compressive, time-dependent behavior of graphite fiber reinforced polymer composite laminates with open holes. The effect of loading rate on compressive strength was determined for six material systems ranging from brittle epoxies to thermoplastics at both 75 F and 220 F. Specimens were loaded to failure using different loading rates. The slope of the strength versus elapsed time-to-failure curve was used to rank the materials' loading rate sensitivity. All of the materials had greater strength at 75 F than at 220 F. All the materials showed loading rate effects in the form of reduced failure strength for longer elapsed-time-to-failure. Loading rate sensitivity was less at 220 F than the same material at 70 F. However, C12000/ULTEM and IM7/8551-7 were more sensitive to loading rate than the other materials at 220 F. AS4/APC2 laminates with 24, 32, and 48 plies and 1/16 and 1/4 inch diameter holes were tested. The sensitivity to loading rate was less for either increasing number of plies or larger hole size. The failure of the specimens made from brittle resins was accompanied by extensive delaminations while the failure of the roughened systems was predominantly by shear crippling. Fewer delamination failures were observed at the higher temperature.

  7. High-loading Fe2O3/SWNT composite films for lithium-ion battery applications

    Science.gov (United States)

    Wang, Ying; Guo, Jiahui; Li, Li; Ge, Yali; Li, Baojun; Zhang, Yingjiu; Shang, Yuanyuan; Cao, Anyuan

    2017-08-01

    Single-walled carbon nanotube (SWNT) films are a potential candidate as porous conductive electrodes for energy conversion and storage; tailoring the loading and distribution of active materials grafted on SWNTs is critical for achieving maximum performance. Here, we show that as-synthesized SWNT samples containing residual Fe catalyst can be directly converted to Fe2O3/SWNT composite films by thermal annealing in air. The mass loading of Fe2O3 nanoparticles is tunable from 63 wt% up to 96 wt%, depending on the annealing temperature (from 450 °C to 600 °C), while maintaining the porous network structure. Interconnected SWNT networks containing high-loading active oxides lead to synergistic effect as an anode material for lithium ion batteries. The performance is improved consistently with increasing Fe2O3 loading. As a result, our Fe2O3/SWNT composite films exhibit a high reversible capacity (1007.1 mA h g-1 at a current density of 200 mA g-1), excellent rate capability (384.9 mA h g-1 at 5 A g-1) and stable cycling performance with the discharge capacity up to 567.1 mA h g-1 after 600 cycles at 2 A g-1. The high-loading Fe2O3/SWNT composite films have potential applications as nanostructured electrodes for various energy devices such as supercapacitors and Li-ion batteries.

  8. Behavior of plywood and fiberglass steel composite tube structures subjected to impact loading

    Science.gov (United States)

    Armaghani, Seyamend Bilind

    Paratransit buses are custom built as the major vehicle manufacturer produces the custom built passenger cage installed on the chassis for the Paratransit bus. In order for these Paratransit bus members to be sufficient, they have to be evaluated for crashworthiness and energy absorption. This has prompted Florida Department of Transportation (FDOT) to fund research for the safety evaluation of Paratransit busses consisting of crash and safety analysis. There has been a large body of research done on steel subjected to static loads, but more research is needed for steel applied under dynamic loading and high speeds in order to improve crashworthiness in events such as rollovers and side impacts. Bare steel Hollow Structural Section (HSS) tubing are used a lot as structural members of Paratransit buses because of their lightness and progressive buckling under loading. The research will be conducted on quantifying the tubing's behavior under bending by conducting static three point bending and impact loading tests. In addition to the bare tubing, plywood and fiberglass composites are investigated because they are both strong and lightweight and their behavior under dynamic loading hasn't been quantified. As a result, the main purpose of this research is to quantify the differences between the dynamic and static behavior of plywood steel composite and fiberglass steel composite tubing and compare these findings with those of bare steel tubing. The differences will be quantified using detailed and thorough experiments that will examine the composites behavior under both static and dynamic loading. These tests will determine if there are any advantages of using the composite materials and thus allow for recommendations to be made to the FDOT with the goal of improving the safety of Paratransit busses. Tensile tests were conducted to determine the material properties of the tested specimens. Before the static and dynamic experiments are run to investigate the differences

  9. Effect of organic loading rate and feedstock composition on foaming in manure-based biogas reactors

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; Angelidaki, Irini

    2013-01-01

    Foaming is one of the major problems that occasionally occur in biogas plants, affecting negatively the overall digestion process. In the present study, the effect of organic loading rate (OLR) and feedstock composition on foaming was elucidated in continuous reactor experiments. By stepwise...

  10. INTERFACIAL DEBONDING OF COATED-FIBER-REINFORCED COMPOSITES UNDER TENSION-TENSION CYCLIC LOADING

    Institute of Scientific and Technical Information of China (English)

    Shi Zhifei; Zhou Limin

    2000-01-01

    A new degradation function of the friction coefficient is used. Based on the double shear-lag model and Paris formula, the interfacial damage of coated fiber-reinforced composites under tension-tension cyclic loading is studied. The effects of strength and thickness of the coating materials on the debond stress, debond rate as well as debond length are simulated.

  11. General Factor Loadings and Specific Effects of the Differential Ability Scales, Second Edition Composites

    Science.gov (United States)

    Maynard, Jennifer L.; Floyd, Randy G.; Acklie, Teresa J.; Houston, Lawrence, III

    2011-01-01

    The purpose of this study was to investigate the "g" loadings and specific effects of the core and diagnostic composite scores from the Differential Abilities Scales, Second Edition (DAS-II; Elliott, 2007a). Scores from a subset of the DAS-II standardization sample for ages 3:6 to 17:11 were submitted to principal factor analysis. Four…

  12. Effect of organic loading rate and feedstock composition on foaming in manure-based biogas reactors.

    Science.gov (United States)

    Kougias, P G; Boe, K; Angelidaki, I

    2013-09-01

    Foaming is one of the major problems that occasionally occur in biogas plants, affecting negatively the overall digestion process. In the present study, the effect of organic loading rate (OLR) and feedstock composition on foaming was elucidated in continuous reactor experiments. By stepwise increasing the OLR and the concentration of proteins or lipids in the substrate, foaming in biogas reactors was investigated. No foam formation was observed at the OLR of 3.5 g volatile solids/(L-reactor·day). Organic loading was the main factor affecting foam formation in manure digester, while the organic composition, such as content of proteins or lipids were factors that in combination with the organic loading were triggering foaming. More specifically, gelatine could initiate foam formation at a lower OLR than sodium oleate. Moreover, the volume of foam produced by gelatine was relatively stable and was not increased when further increasing either OLR or gelatine concentration in the feed.

  13. STATIC AND FATIGUE BEHAVIOR OF IMPACTED AS4/PEEK THERMOPLASTIC COMPOSITES UNDER COMPRESSION LOAD

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Static and fatigue tests under compression load were made on impacted AS4/PEEK and T300/913C graphite/epoxy with [45/90/-45/0]5S stacking sequence. The comparison of the damage tolerance assessment for thermosetting and thermoplastic composites shows that thermoplastics are more damage tolerant under compression. Impacted thermoplastic composites have excellent compression-compression fatigue behavior. The damage growth life is only a few percent of their total fatigue life and no regular damage growth can be found. Some design principles for thermosetting composite structures may still be used.

  14. Behaviour of hybrid jute-glass/epoxy composite tubes subjected to lateral loading

    Science.gov (United States)

    Khalid, A. A.

    2015-12-01

    Experimental work on hybrid and non-hybrid composite tubes subjected to lateral loading has been carried out using jute, glass and hybrid jute-glass/epoxy materials. Tubes of 200 mm length with 110 mm inner diameter were fabricated by hand lay-up method to investigate the effect of material used and the number of layers on lateral-load-displacement relations and on the failure mode. Crush force efficiency and the specific energy absorption of the composite tubes were calculated. Results show that the six layers glass/epoxy tubes supported load higher 10.6% than that of hybrid jute-glass/ epoxy made of two layers of jute/epoxy four layers of glass/epoxy. It has been found that the specific energy absorption of the glass/epoxy tubes is found higher respectively 11.6% and 46% than hybrid jute-glass/epoxy and jute/epoxy tubes. The increase in the number of layers from two to six increases the maximum lateral load from 0.53KN to 1.22 KN for jute/epoxy and from 1.35 KN to 3.87 KN for the glass/epoxy tubes. The stacking sequence of the hybrid tubes influenced on the maximum lateral load and the absorbed energy. The maximum load obtained for the six layers jute-glass/epoxy tubes of different staking sequence varies between 1.88 KN to 3.46 KN. Failure mechanisms of the laterally loaded composite tubes were also observed and discussed.

  15. Onset of failure in finitely strained layered composites subjected to combined normal and shear loading

    Science.gov (United States)

    Nestorović, M. D.; Triantafyllidis, N.

    2004-04-01

    A limiting factor in the design of fiber-reinforced composites is their failure under axial compression along the fiber direction. These critical axial stresses are significantly reduced in the presence of shear stresses. This investigation is motivated by the desire to study the onset of failure in fiber-reinforced composites under arbitrary multi-axial loading and in the absence of the experimentally inevitable imperfections and finite boundaries. By using a finite strain continuum mechanics formulation for the bifurcation (buckling) problem of a rate-independent, perfectly periodic (layered) solid of infinite extent, we are able to study the influence of load orientation, material properties and fiber volume fraction on the onset of instability in fiber-reinforced composites. Two applications of the general theory are presented in detail, one for a finitely strained elastic rubber composite and another for a graphite-epoxy composite, whose constitutive properties have been determined experimentally. For the latter case, extensive comparisons are made between the predictions of our general theory and the available experimental results as well as to the existing approximate structural theories. It is found that the load orientation, material properties and fiber volume fraction have substantial effects on the onset of failure stresses as well as on the type of the corresponding mode (local or global).

  16. Controlled release by novel lysostaphin-loaded hydroxyapatite/chitosan composites.

    Science.gov (United States)

    Wang, Jin-Cheng; Xue, Bai; Ge, Kui-Kui; Wang, Yi-Han; Li, Guo-Dong; Huang, Qing-Shan

    2014-09-01

    Lysostaphin is highly effective on eliminating methicillin resistant Staphylococcus aureus (MRSA). In order to achieve controlled release of lysostaphin, a biocompatible drug carrier is needed. Hydroxyapatite/chitosan (HA/CS) composites were chosen to carry lysostaphin and sample composites with different weight ratios of HA to CS, including 80/20, 70/30, 60/40, and 40/60, were prepared. Multiple analyses were performed to determine the structural and physicochemical properties of the composites, including scanning electron microscopy, X-ray diffraction and Fourier transform infrared spectroscopy. We immersed HA/CS composites loaded with 1 wt% lysostaphin to test in vitro release activity and cultured MC3T3-E1 cells to carry out biocompatibility test. The result of the release behavior of the composites revealed that the controlled release of lysostaphin from 60/40 HA/CS composites was the highest release rate of (87.4 ± 2.8)%, which lasted for 120 hours. In biocompatibility testing, MC3T3-E1 cells were able to proliferate on the surface of these composites, and the extract liquid from the composites could increase the growth of the cells. These results demonstrate the controlled release of lysostaphin from HA/CS composites and their biocompatibility, suggesting the potential application of these composites to bone injury and infection applications.

  17. STACKING SEQUENCE OPTIMIZATION OF LAMINATED COMPOSITE CYLINDER SHELL FOR MAXIMAL BUCKLING LOAD

    Institute of Scientific and Technical Information of China (English)

    TANG Qian; LIAO Xiaoyun; GAO Zhan

    2008-01-01

    A new optimization method for the optimization of stacking of composite glass fiber laminates is developed. The fiber orientation and angle of the layers of the cylindrical shells are sought considering the buckling load. The proposed optimization algorithm applies both finite element analysis and the mode-pursuing sampling (MPS)method. The algorithms suggest the optimal stacking sequence for achieving the maximal buckling load. The procedure is implemented by integrating ANSYS and MATLAB. The stacking sequence designing for the symmetric angle-ply three-layered and five-layered composite cylinder shells is presented to illustrate the optimization process, respectively. Compared with the genetic algorithms, the proposed optimization method is much faster and efficient for composite staking sequence plan.

  18. Micromechanical Analysis of FRP Composite with Orthotropic Fibers Subjected To Longitudinal and Transverse Loading

    Directory of Open Access Journals (Sweden)

    M. Gowtha Muneswara Rao

    2014-05-01

    Full Text Available The present research work deals with the micromechanical analysis of fiber reinforced composites with orthotropic fibers under fiber directional tensile loading and transverse directional tensile loading using three-dimensional finite element method. The problem is modeled in ANSYS software and the FE model is validated with bench mark results. Longitudinal Young's modulus and transverse Young's modulus corresponding Poisson's ratios are predicted. Fiber reinforced composite materials are now an important class of an engineering materials. They offer outstanding mechanical properties, unique flexibility in design capabilities, and ease of fabrication. Additional advantages include light weight and corrosion resistance, impact resistance, and excellent fatigue strength. Today fiber composites are routinely used in such diverse applications as automobiles, aircraft, space vehicles, offshore structures, containers and piping, sporting goods, electronics, and appliances.

  19. Magnetostrictive Actuation of a Bone Loading Composite for Accelerated Tissue Formation

    Directory of Open Access Journals (Sweden)

    Stephen Hart

    2012-01-01

    Full Text Available When bone is dynamically loaded it adapts its shape to better support the load. We have developed a magnetostrictive composite consisting of Terfenol-D particles encapsulated in an epoxy resin that changes length when exposed to magnetic fields. When bonded to the surface of a porcine tibia ex vitro, the composite produces surface strains greater than 900 με at a frequency of 30 Hz and magnetic field of 170 kA/m. This is more than sufficient strain magnitude and frequency to promote cortical bone growth in both rats and turkeys and to maintain cortical bone structure in humans. Key advantages of the composite over conventional electromechanical or thermomechanical actuators are its simplicity, compact size, and remote actuation. A mathematical model describing the strains and stresses in the bone is presented.

  20. Effects of nanosized metallic palladium loading and calcination on characteristics of composite silica

    Institute of Scientific and Technical Information of China (English)

    吴玉程; 吴侠; 李广海; 张立德

    2003-01-01

    In order to investigate the effects of nanosized metallic palladium loading and calcination on the characteristics of composite silica,the silica was prepared by sol-gel technique,leading to an amorphous solid with mesoporosity,and the pore size distribution is narrow,centered at 3-5 nm.The composite silica was formed by impregnating palladium precursor into the porous network with sequel calcination in hydrogen.The results show that the nanosized palladium as guest phase in the composite silica is subjected to the mesoporous structure and calcination,resulting in the changes of optical adsorption that red-shifted to higher wavelength with the palladium loading and the heating temperature.The tailoring of the optical properties can be ascribed to the effect of the nanosized metal particles and interactions occurred between palladium and silica.

  1. Prediction of Spring Rate and Initial Failure Load due to Material Properties of Composite Leaf Spring

    Energy Technology Data Exchange (ETDEWEB)

    Oh, Sung Ha [Maxoft Inc., Seongnam (Korea, Republic of); Choi, Bok Lok [Gangneung-Wonju National University, Gangneung (Korea, Republic of)

    2014-12-15

    This paper presented analysis methods for adapting E-glass fiber/epoxy composite (GFRP) materials to an automotive leaf spring. It focused on the static behaviors of the leaf spring due to the material composition and its fiber orientation. The material properties of the GFRP composite were directly measured based on the ASTM standard test. A reverse implementation was performed to obtain the complete set of in-situ fiber and matrix properties from the ply test results. Next, the spring rates of the composite leaf spring were examined according to the variation of material parameters such as the fiber angles and resin contents of the composite material. Finally, progressive failure analysis was conducted to identify the initial failure load by means of an elastic stress analysis and specific damage criteria. As a result, it was found that damage first occurred along the edge of the leaf spring owing to the shear stresses.

  2. Relationship between the Composition of Polymer of n-Alkyl Substituted Acrylate and Vinyl Amine and Their Performance on Pour Point Depression

    Institute of Scientific and Technical Information of China (English)

    Jiang Qingzhe; Luo Fangmin; Song Zhaozheng; Ke Ming

    2005-01-01

    Polymer of n-alkyl substituted acrylate (PA) with the alkyl side chains C16- 30 were synthesized.Their crystallinity, solubility and effect on pour point depression were studied. Results showed that only carbon atoms located far away from polar groups of PA pour point depressants participated in crystallization.When the number of carbon atoms that participated in crystallization is about three fourths of the average carbon number of wax in crude, the effect of PA is the best. The molecular weight distribution of PA pour point depressant has little influence on the effect of pour point depression, and the average molecular weight of PA in the range of (1.5- 2.2)× 104 shows the best effect. The introduction of polar groups into the molecule of PA can improve its performance. However, a too high content of polar groups in PA would cause deterioration, and even lead to loss of PA's performance for pour point depression.

  3. Modelling of Fiber/Matrix Debonding of Composites Under Cyclic Loading

    Science.gov (United States)

    Naghipour, Paria; Pineda, Evan J.; Bednarcyk, Brett A.; Arnold, Steven M.

    2013-01-01

    The micromechanics theory, generalized method of cells (GMC), was employed to simulate the debonding of fiber/matrix interfaces, within a repeating unit cell subjected to global, cyclic loading, utilizing a cyclic crack growth law. Cycle dependent, interfacial debonding was implemented as a new module to the available GMC formulation. The degradation of interfacial stresses, with applied load cycles, was achieved via progressive evolution of the interfacial compliance. A periodic repeating unit cell, representing the fiber/matrix architecture of a composite, was subjected to combined normal and shear loadings, and degradation of the global transverse stress in successive cycles was monitored. The obtained results were compared to values from a corresponding finite element model. Reasonable agreement was achieved for combined normal and shear loading conditions, with minimal variation for pure loading cases. The local effects of interfacial debonding, and fatigue damage will later be combined as sub-models to predict the experimentally obtained fatigue life of Ti-15-3/Sic composites at the laminate level.

  4. A Numerical and Experimental Study of Compression-Loaded Composite Panels With Cutouts

    Science.gov (United States)

    Thornburgh, Robert P.; Hilburger, Mark W.

    2006-01-01

    Results from a numerical and experimental study on the effects of laminate orthotropy and circular cutout size on the response of compression-loaded composite curved panels are presented. Several 60-in-radius composite panels with four different laminate configurations were tested with cutout diameters that range from 10% to 60% of the panel width. Finite-element analyses were performed for each panel in order to identify the effects boundary conditions, measured initial geometric imperfections and thickness variations had on the nonlinear and buckling behavior of the panels. The compression-loaded panels considered herein exhibited two separate types of behavior depending on the laminate stacking sequence and cutout size. More specifically, some of the panels exhibited the classical snap-through type buckling response; however, some of the panels exhibited a monotonically increasing stable response and achieved compressive loads in excess of twice the predicted linear bifurcation buckling load. In general, the finite-element analyses were able to predict accurately the nonlinear response and buckling loads of the panels and the prebuckling and postbuckling out-of-plane deformations and strains.

  5. Calculation method of composite foundation sedimentation of grouting pile with cover plate under embankment load

    Institute of Scientific and Technical Information of China (English)

    顾长存; 洪昌地; 马文彬; 李雪平

    2008-01-01

    Grouting pile is a new soft soil foundation treatment method with characteristics such as no vibration, no noise, no soil compaction, light construction machines and quick construction velocity and so on. At present, study on reinforcement mechanism and design calculation method of composite foundation of grouting pile is initially started without design specifications, so it is usually required to draw on design specifications of stump pile when designing composite foundation of grouting pile while grouting pile has its characteristics and difference although reinforcement mechanisms and construction processes of two types of piles are similar. Sedimentation formula of composite foundation of grouting pile with cover plate is educed and a suitable deformation mode is proposed by aiming to deformation characteristics of composite foundation of grouting pile with cover plate under embankment load on basis of relevant sedimentation theories of composite foundation by combination of characteristics of composite foundation of grouting pile. The sedimentation calculation formula of grouting pile with cover plate under embankment load is educed according to balance relation of force and displacement coordination conditions by elastic theory and sedimentation calculation model established is validated by sedimentation monitoring documents of one expressway in China.

  6. Regularity of acoustic radiation at ascending load on a pair of friction from a composite material

    Directory of Open Access Journals (Sweden)

    С. Ф. Філоненко

    2013-07-01

    Full Text Available In this article the simulation the results of acoustic emission signals formed by friction surfaces with composite materials at load increasing were showed. The results showed that at increase of axial load increases the amplitude of the resulting parameters of acoustic emission signals, such as the average amplitude, its standard deviation and variance. Thus were obtained the basic changes of amplitude parameters generated signals. Was determined that the variation of the percentage increase in the average amplitude, its standard deviation and variance were  the same type of character, with well approximate by linear functions. The results showed that with growing of axial load the percent increase in average amplitude of the resulting acoustic emission signals. Also, an analysis of the energy parameters of acoustic emission with increasing axial load on the friction pair with composite materials was conducted. The simulation results showed that the percentage increase in the average level of energy and its standard deviation are approximate by linear functions. At the same time the greatest percentage increase with increasing axial load on the friction pair is observed in the dispersion of the average energy of the resulting acoustic emission signals. The results showed that at experimental study of the acoustic emission signals with increasing axial load on the friction pair with composite materials greatest growth is expected in the average amplitude of the resulting AE signals. The growth of its standard deviation and variance will be not significant. At the same time, the greatest growth is expected in the dispersion of the average energy of acoustic emission signals

  7. Reliability Analysis for Adhesive Bonded Composite Stepped Lap Joints Loaded in Fatigue

    DEFF Research Database (Denmark)

    Kimiaeifar, Amin; Sørensen, John Dalsgaard; Lund, Erik

    2012-01-01

    strength under fully reversed cyclic loading based on stiffness/strength degradation. The FEA simulations are conducted using the commercial FEA code ANSYS 12.1. A design equation for fatigue failure of wind turbine blades is chosen based on recommendations given in the wind turbine standard IEC 61400...... by the wind turbine standard IEC 61400-1. Finally, an approach for the assessment of the reliability of adhesive bonded composite stepped lap joints loaded in fatigue is presented. The introduced methodology can be applied in the same way to calculate the reliability level of wind turbine blade components...

  8. Strain measurement in individual phases of an Al/TiC composite during mechanical loading

    Energy Technology Data Exchange (ETDEWEB)

    Bourke, M.A.M.; Goldstone, J.A.; Stout, M.G.; Lawson, A.C. (Los Alamos National Lab., NM (United States)); Allison, J.E. (Ford Motor Co., Dearborn, MI (United States). Scientific Research Lab.)

    1992-01-01

    Neutron diffraction provides a unique method for examining materials during thermo-mechanical loading because it is nondestructive and penetrating and can distinguish between the strains in individual phases. Using a pulsed neutron source, all lattice reflections are recorded in all constituents simultaneously. Preliminary in-situ strain measurements under- load of an aluminum/titanium carbide composite are presented here. The measurements were made using a compact stress rig on the neutron powder diffractometer at the Manuel Lujan Jr. Neutron Scattering Center at Los Alamos National Laboratory.

  9. Acoustic emission monitoring of fracture process of SiC/Al composites under cyclic loading

    Science.gov (United States)

    Lee, Joon-Hyun; Kim, Jong-Hwan; Yoon, Dong-Jin; Kwon, Oh-Yang

    Acoustic emission was used to clarify fatigue failure mechanisms of aliminum alloys reinforced with SiC particulate (SiCp/A356) or whisker (SiCw/Al2009). For this purpose, special attention was given to AE characteristics including AE event, energy and peak amplitude distribution which were associated with micro-fracture processes of metal matrix composites under the cyclic loading. The effects of form of reinforcements, heat treatment, orientation of whisker and loading condition on AE characteristics were discussed based on SEM fractographic results.

  10. Reliability Analysis for Adhesive Bonded Composite Stepped Lap Joints Loaded in Fatigue

    DEFF Research Database (Denmark)

    Kimiaeifar, Amin; Sørensen, John Dalsgaard; Lund, Erik

    2012-01-01

    This paper describes a probabilistic approach to calculate the reliability of adhesive bonded composite stepped lap joints loaded in fatigue using three- dimensional finite element analysis (FEA). A method for progressive damage modelling is used to assess fatigue damage accumulation and residual...... strength under fully reversed cyclic loading based on stiffness/strength degradation. The FEA simulations are conducted using the commercial FEA code ANSYS 12.1. A design equation for fatigue failure of wind turbine blades is chosen based on recommendations given in the wind turbine standard IEC 61400...

  11. Mechanical interaction of Engineered Cementitious Composite (ECC) reinforced with Fiber Reinforced Polymer (FRP) rebar in tensile loading

    DEFF Research Database (Denmark)

    Lárusson, Lárus Helgi; Fischer, Gregor; Jönsson, Jeppe

    2010-01-01

    This paper introduces a preliminary study of the composite interaction of Engineered Cementitious Composite (ECC), reinforced with Glass Fiber Reinforced Polymer (GFRP) rebar. The main topic of this paper will focus on the interaction of the two materials (ECC and GFRP) during axial loading......, particularly in post cracking phase of the concrete matrix. The experimental program carried out in this study examined composite behavior under monotonic and cyclic loading of the specimens in the elastic and inelastic deformation phases. The stiffness development of the composite during loading was evaluated...

  12. Dynamic stability of simply supported composite cylindrical shells under partial axial loading

    Science.gov (United States)

    Dey, Tanish; Ramachandra, L. S.

    2015-09-01

    The parametric vibration of a simply supported composite circular cylindrical shell under periodic partial edge loadings is discussed in this article. Donnell's nonlinear shallow shell theory considering first order shear deformation theory is used to model the shell. The applied partial edge loading is represented in terms of a Fourier series and stress distributions within the cylindrical shell are determined by prebuckling analysis. The governing equations of the dynamic instability of shells are derived in terms of displacements (u-v-w) and rotations (φx, φθ). Employing the Galerkin and Bolotin methods the dynamic instability regions are computed. Using the expression for the stress function derived in this paper, the pre-buckling stresses in the cylindrical shell due to partial loading can be calculated explicitly. Numerical results are presented to show the influence of radius-to-thickness ratio, different partial edge loading distributions and shear deformation on the dynamic instability regions. The linear and nonlinear responses in the stable and unstable regions are presented to bring out the characteristic features of the dynamic instability regions, such as the existence of beats, its dependence on forcing frequency and effect of nonlinearity on the response. The effect of dynamic load amplitude on the nonlinear response is also studied. It is found that for higher values of dynamic loading, the shell exhibits chaotic behavior.

  13. Preparation and Photocatalytic Properties of TiO2-Al2O3 Composite Loaded Catalysts

    Directory of Open Access Journals (Sweden)

    Jianzhong Pei

    2015-01-01

    Full Text Available This paper presents an experimental approach to study catalytic effects of Fe3+ modified nanometer titanium dioxide (TiO2 loaded on aluminium oxide (Al2O3. Sol-gel method was used to prepare modified TiO2 loaded on carrier. Purification tests were conducted in a self-developed instrument to study catalytic effects of TiO2 loaded on Al2O3 with different contents through degradation rate. The modification mechanism was studied by scanning electron microscope (SEM. Results showed that loading on Al2O3 improved photocatalytic effect of TiO2 modified with Fe3+. The best photocatalytic effect was achieved under catalytic action of Al2O3 loaded with 10% TiO2 composite; the degradation rates were 6.9%, 13.8%, 21.4%, and 49.2%, respectively, 0.7%, 3.9%, 1.3%, and 15.1% larger than unloaded TiO2. SEM results of four catalysts showed that nanometer TiO2 was coated in form of grain on the surface of Al2O3. The optimal loading content was 10% at which the nanometer TiO2 grains were coated on the surface of Al2O3 uniformly.

  14. Preparation and Characterization of Acrylic Primer for Concrete Substrate Application

    Directory of Open Access Journals (Sweden)

    El-Sayed Negim

    2016-01-01

    Full Text Available This study dealt with the properties of acrylic primer for concrete substrate using acrylic syrup, made from a methyl methacrylate monomer solution of terpolymers. Terpolymer systems consisting of methyl methacrylate (MMA, 2-ethylhexyl acrylate (2-EHA, and methacrylic acid (MAA with different chemical composition ratios of MMA and 2-EHA were synthesized through bulk polymerization using azobisisobutyronitrile (AIBN as initiator. The terpolymer composition is characterized by FTIR, 1H NMR, DSC, TGA, and SEM. The glass transition temperature and the thermal stability increased with increasing amounts of MMA in the terpolymer backbone. The effect of chemical composition of terpolymers on physicomechanical properties of primer films was investigated. However, increasing the amount of MMA in terpolymer backbone increased tensile and contact angle of primer films while elongation at break, water absorption, and bond strength are decreased. In particular, the primer syrup containing 65% 2-EHA has good bonding strength with concrete substrate around 1.1 MPa.

  15. Numerical modeling of nonlinear deformation and buckling of composite plate-shell structures under pulsed loading

    Science.gov (United States)

    Abrosimov, N. A.

    1999-11-01

    Nonlinear three-dimensional problems of dynamic deformation, buckling, and posteritical behavior of composite shell structures under pulsed loads are analyzed. The structure is assumed to be made of rigidly joined plates and shells of revolution along the lines coinciding with the coordinate directions of the joined elements. Individual structural elements can be made of both composite and conventional isotropic materials. The kinematic model of deformation of the structural elements is based on Timoshenko-type hypotheses. This approach is oriented to the calculation of nonstationary deformation processes in composite structures under small deformations but large displacements and rotation angles, and is implemented in the context of a simplified version of the geometrically nonlinear theory of shells. The physical relations in the composite structural elements are based on the theory of effective moduli for individual layers or for the package as a whole, whereas in the metallic elements this is done in the framework of the theory of plastic flow. The equations of motion of a composite shell structure are derived based on the principle of virtual displacements with some additional conditions allowing for the joint operation of structural elements. To solve the initial boundary-value problem formulated, an efficient numerical method is developed based on the finite-difference discretization of variational equations of motion in space variables and an explicit second-order time-integration scheme. The permissible time-integration step is determined using Neumann's spectral criterion. The above method is especially efficient in calculating thin-walled shells, as well as in the case of local loads acting on the structural element, when the discretization grid has to be condensed in the zones of rapidly changing solutions in space variables. The results of analyzing the nonstationary deformation processes and critical loads are presented for composite and isotropic

  16. Interface debond crack growth in tension–tension cyclic loading of single fiber polymer composites

    DEFF Research Database (Denmark)

    Pupurs, Andrejs; Goutianos, Stergios; Brøndsted, Povl;

    2013-01-01

    Fiber/matrix interface debond crack growth from a fiber break is defined as one of the key mechanisms of fatigue damage in unidirectional composites. Considering debond as an interface crack its growth in cyclic loading is analyzed utilizing a power law, where the debond growth rate is a power...... for glass fiber/epoxy single fiber composites. Analytical method in the steady-state growth region and FEM for short debonds are combined for calculating the strain energy release rate of the growing debond crack. Interface failure parameters in fatigue are determined by fitting the modeling...

  17. A micromechanical study of porous composites under longitudinal shear and transverse normal loading

    DEFF Research Database (Denmark)

    Ashouri Vajari, Danial

    2015-01-01

    The mechanical response of porous unidirectional composites under transverse normal and longitudinal shear loading is studied using the finite element analysis. The 3D model includes discrete and random distribution of fibers and voids. The micromechanical failure mechanisms are taken into account...... by considering the mixed-mode interfacial debonding and pressure-dependent yielding of the matrix using the modified Drucker-Prager plasticity model. The effect of the micromechanical features on the overall response of composite is discussed with a focus on the effect of microvoids and interfacial toughness...

  18. Combined-load buckling behavior of metal-matrix composite sandwich panels under different thermal environments

    Science.gov (United States)

    Ko, William L.; Jackson, Raymond H.

    1991-01-01

    Combined compressive and shear buckling analysis was conducted on flat rectangular sandwich panels with the consideration of transverse shear effects of the core. The sandwich panel is fabricated with titanium honeycomb core and laminated metal matrix composite face sheets. The results show that the square panel has the highest combined load buckling strength, and that the buckling strength decreases sharply with the increases of both temperature and panel aspect ratio. The effect of layup (fiber orientation) on the buckling strength of the panels was studied in detail. The metal matrix composite sandwich panel was much more efficient than the sandwich panel with nonreinforced face sheets and had the same specific weight.

  19. The Use of Micro and Nano Particulate Fillers to Modify the Mechanical and Material Properties of Acrylic Bone Cement

    Science.gov (United States)

    Slane, Joshua A.

    Acrylic bone cement (polymethyl methacrylate) is widely used in total joint replacements to provide long-term fixation of implants. In essence, bone cement acts as a grout by filling in the voids left between the implant and the patient's bone, forming a mechanical interlock. While bone cement is considered the `gold standard' for implant fixation, issues such as mechanical failure of the cement mantle (aseptic loosening) and the development of prosthetic joint infection (PJI) still plague joint replacement procedures and often necessitate revision arthroplasty. In an effort to address these failures, various modifications are commonly made to bone cement such as mechanical reinforcement with particles/fibers and the addition of antibiotics to mitigate PJI. Despite these attempts, issues such as poor particle interfacial adhesion, inadequate drug release, and the development of multidrug resistant bacteria limit the effectiveness of bone cement modifications. Therefore, the overall goal of this work was to use micro and nanoparticles to enhance the properties of acrylic bone cement, with particular emphasis placed on improving the mechanical properties, cumulative antibiotic release, and antimicrobial properties. An acrylic bone cement (Palacos R) was modified with three types of particles in various loading ratios: mesoporous silica nanoparticles (for mechanical reinforcement), xylitol microparticles (for increased antibiotic release), and silver nanoparticles (as an antimicrobial agent). These particles were used as sole modifications, not in tandem with one another. The resulting cement composites were characterized using a variety of mechanical (macro to nano, fatigue, fracture, and dynamic), imaging, chemical, thermal, biological, and antimicrobial testing techniques. The primary outcomes of this dissertation demonstrate that: (1) mesoporous silica, as used in this work, is a poor reinforcement phase for acrylic bone cement, (2) xylitol can significantly

  20. High-Velocity Impact Behaviour of Prestressed Composite Plates under Bird Strike Loading

    Directory of Open Access Journals (Sweden)

    Sebastian Heimbs

    2012-01-01

    Full Text Available An experimental and numerical analysis of the response of laminated composite plates under high-velocity impact loads of soft body gelatine projectiles (artificial birds is presented. The plates are exposed to tensile and compressive preloads before impact in order to cover realistic loading conditions of representative aeronautic structures under foreign object impact. The modelling methodology for the composite material, delamination interfaces, impact projectile, and preload using the commercial finite element code Abaqus are presented in detail. Finally, the influence of prestress and of different delamination modelling approaches on the impact response is discussed and a comparison to experimental test data is given. Tensile and compressive preloading was found to have an influence on the damage pattern. Although this general behaviour could be predicted well by the simulations, further numerical challenges for improved bird strike simulation accuracy are highlighted.

  1. Evaluation of novel Ti-doped 3D carbon-carbon composites under transient thermal loads

    Energy Technology Data Exchange (ETDEWEB)

    Centeno, A. [Instituto Nacional del Carbon (CSIC), Apdo. 73, 33080-Oviedo (Spain); Blanco, C., E-mail: clara@incar.csic.e [Instituto Nacional del Carbon (CSIC), Apdo. 73, 33080-Oviedo (Spain); Santamaria, R.; Granda, M.; Menendez, R. [Instituto Nacional del Carbon (CSIC), Apdo. 73, 33080-Oviedo (Spain); Pintsuk, G.; Linke, J. [Forschungszentrum Juelich GmbH, EURATOM Association, 52425-Juelich (Germany)

    2010-08-15

    3D Ti-doped and undoped carbon-carbon composites (CFCs) were exposed to transient thermal loads to simulate plasma disruptions, in the electron beam test facility JUDITH at different power densities and multiple shots in order to study the evolution in the behavior of the material. The thermal shock response of the undoped and Ti-doped materials was compared in order to study the influence of titanium carbide as dopant. The erosion itself is driven during the first shots by macroscopic erosion (brittle destruction), which is a result of thermally induced stresses. With increasing number of shots, no more brittle destruction is observed and the main erosion mechanism is sublimation due to local overheating. This is also confirmed by the decrease of the erosion rate with increasing the number of shots. The pitch fibers are hardly affected by the applied heat loads and they show almost no erosion, especially in the Ti-doped composite.

  2. Investigation and characterization of constraint effects on flaw growth during fatigue loading of composite materials

    Science.gov (United States)

    Stinchcomb, W. W.; Reifsnider, K. L.; Yeung, P.; Gibbins, M. N.

    1979-01-01

    An investigative program is presented in an attempt to add to the current understanding of constraint effects on the response of composite materials under cyclic loading. The objectives were: (1) to use existing data and to develop additional data in order to establish an understanding and quantitative description of flaw growth in unidirectional lamina under cyclic loading at different load direction to fiber direction angles; (2) to establish a similar understanding and description of flaw growth in lamina which are embedded in laminates between other unflawed lamina; (3) to determine the nature of the influence of constraint on flaw growth by quantitatively comparing the results of the tests; and (4) to develop a model and philosophy of constraints effects based on our investigative results.

  3. Characterization of debond growth mechanism in adhesively bonded composites under mode II static and fatigue loadings

    Science.gov (United States)

    Mall, S.; Kochhar, N. K.

    1988-01-01

    An experimental investigation of adhesively bonded composite joint was conducted to characterize the debond growth mechanism under mode II static and fatigue loadings. For this purpose, end-notched flexure specimens of graphite/epoxy (T300/5208) adherends bonded with EC 3445 adhesive were tested. In all specimen tested, the fatigue failure occurred in the form of cyclic debonding. The present study confirmed the result of previous studies that total strain-energy-release rate is the driving parameter for cyclic debonding. Further, the debond growth resistance under cyclic loading with full shear reversal (i.e., stress ratio, R = -1) is drastically reduced in comparison to the case when subjected to cyclic shear loading with no shear reversal (i.e., R = 0.1).

  4. Load bearing enhancement of pin joined composite laminates using electrospun polyacrylonitrile nanofiber mats

    Directory of Open Access Journals (Sweden)

    J. Herwan

    2016-03-01

    Full Text Available Polyacrylonitrile (PAN nanofibers were produced by an electrospinning technique and directly deposited onto carbon fabric to improve the load bearing strength of pin joined composite laminates. Two types of specimens, virgin laminates and nano-modified laminates, were prepared. A modified carbon fiber reinforced polymer (CFRP laminate was fabricated by interleaving electrospun nanofibers at all of the interlayers of an eight-ply woven carbon fiber fabric. The load bearing test results of the pin joined laminates indicated the electrospun PAN nanofibers increased the load bearing strength by 18.9%. In addition, three point bending tests were also conducted to investigate the flexural modulus and flexural strength of both types of laminates. The flexural modulus and flexural strength also increased by 20.9% and 55.91%, respectively.

  5. [Acrylic resin removable partial dentures

    NARCIS (Netherlands)

    Baat, C. de; Witter, D.J.; Creugers, N.H.J.

    2011-01-01

    An acrylic resin removable partial denture is distinguished from other types of removable partial dentures by an all-acrylic resin base which is, in principle, solely supported by the edentulous regions of the tooth arch and in the maxilla also by the hard palate. When compared to the other types of

  6. Deformation and Damage Accumulation in a Ceramic Composite under Dynamic Loading

    Science.gov (United States)

    Korobenkov, M. V.; Kulkov, S. N.; Naymark, O. B.; Khorechko, U. V.; Ruchina, A. V.

    2016-01-01

    Methods of computer modelling were used to investigate the processes of deformation and microdamage formation in ceramic composite materials under intense dynamic loading. It was shown that there was no damage caused by dynamic compression in the vicinity of phase borders of a nanostructured aluminum oxide matrix and reinforcing particles of tetragonal zirconium dioxide. Also, the local origination of microdamages occurs only in the zones close to micropores.

  7. Multiple spatio-temporal scale modeling of composites subjected to cyclic loading

    Science.gov (United States)

    Crouch, Robert; Oskay, Caglar; Clay, Stephen

    2013-01-01

    This manuscript presents a multiscale modeling methodology for failure analysis of composites subjected to cyclic loading conditions. Computational homogenization theory with multiple spatial and temporal scales is employed to devise the proposed methodology. Multiple spatial scales address the disparity between the length scale of material heterogeneities and the overall structure, whereas multiple temporal scales with almost periodic fields address the disparity between the load period and overall life under cyclic loading. The computational complexity of the multiscale modeling approach is reduced by employing a meso-mechanical model based on eigendeformation based homogenization with symmetric coefficients in the space domain, and an adaptive time stepping strategy based on a quadratic multistep method with error control in the time domain. The proposed methodology is employed to simulate the response of graphite fiber-reinforced epoxy composites. Model parameters are calibrated using a suite of experiments conducted on unidirectionally reinforced specimens subjected to monotonic and cyclic loading. The calibrated model is employed to predict damage progression in quasi-isotropic specimens. The capabilities of the model are validated using acoustic emission testing.

  8. Finite Element Analysis of Composite Hardened Walls Subjected to Blast Loads

    Directory of Open Access Journals (Sweden)

    Girum S. Urgessa

    2009-01-01

    Full Text Available Problem statement: There is currently no standard design guideline to determine the number of composites needed to retrofit masonry walls in order to withstand a given explosion. Past design approaches were mainly based on simplified single-degree-of-freedom analysis. A finite element analysis was conducted for concrete masonry walls hardened with composites and subjected to short duration blast loads. Approach: The analysis focused on displacement time history responses which form the basis for retrofit design guidelines against blast loadings. The blast was determined from 0.5 kg equivalent TNT explosive at 1.83 m stand-off distance to simulate small mailroom bombs. Two and four layered retrofitted walls were investigated. Uncertainties in the finite model analysis of walls such as pressure distributions, effect of mid height explosive bursts versus near the ground explosive bursts and variations in modulus of elasticity of the wall were presented. Results: Uniformly distributed blast loads over the retrofitted wall height produced a small difference in peak displacement results when compared to the non-uniform pressure distribution. Ground explosive burst was shown to produce a 62.7% increase in energy and a higher peak displacement response when compared to mid-height explosive burst. Conclusion: The parametric study on the variation of modulus of elasticity of concrete masonry showed no significant effect on peak displacement affirming the use of the resistance deflection contribution of the composite in retrofit designs.

  9. Simulation of Complex Cracking in Plain Weave C/SiC Composite under Biaxial Loading

    Science.gov (United States)

    Cheng, Ron-Bin; Hsu, Su-Yuen

    2012-01-01

    Finite element analysis is performed on a mesh, based on computed geometry of a plain weave C/SiC composite with assumed internal stacking, to reveal the pattern of internal damage due to biaxial normal cyclic loading. The simulation encompasses intertow matrix cracking, matrix cracking inside the tows, and separation at the tow-intertow matrix and tow-tow interfaces. All these dissipative behaviors are represented by traction-separation cohesive laws. Not aimed at quantitatively predicting the overall stress-strain relation, the simulation, however, does not take the actual process of fiber debonding into account. The fiber tows are represented by a simple rule-of-mixture model where the reinforcing phase is a hypothetical one-dimensional material. Numerical results indicate that for the plain weave C/SiC composite, 1) matrix-crack initiation sites are primarily determined by large intertow matrix voids and interlayer tow-tow contacts, 2) the pattern of internal damage strongly depends on the loading path and initial stress, 3) compressive loading inflicts virtually no damage evolution. KEY WORDS: ceramic matrix composite, plain weave, cohesive model, brittle failure, smeared crack model, progressive damage, meso-mechanical analysis, finite element.

  10. Doxorubicin-loaded mesoporous silica nanoparticle composite nanofibers for long-term adjustments of tumor apoptosis

    Science.gov (United States)

    Yuan, Ziming; Pan, Yue; Cheng, Ruoyu; Sheng, Lulu; Wu, Wei; Pan, Guoqing; Feng, Qiming; Cui, Wenguo

    2016-06-01

    There is a high local recurrence (LR) rate in breast-conserving therapy (BCT) and enhancement of the local treatment is promising as a way to improve this. Thus we propose a drug delivery system using doxorubicin (DOX)-loaded mesoporous silica nanoparticle composite nanofibers which can release anti-tumor drugs in two phases—burst release in the early stage and sustained release at a later stage—to reduce the LR of BCT. In the present study, we designed a novel composite nanofibrous scaffold to realize the efficient release of drugs by loading both DOX and DOX-loaded mesoporous silica nanoparticles into an electrospun PLLA nanofibrous scaffold. In vitro results demonstrated that this kind of nanomaterial can release DOX in two phases, and the results of in vivo experiments showed that this hybrid nanomaterial significantly inhibited the tumor growth in a solid tumor model. Histopathological examination demonstrated that the apoptosis of tumor cells in the treated group over a 10 week period was significant. The anti-cancer effects were also accompanied with decreased expression of Bcl-2 and TNF-α, along with up-regulation of Bax, Fas and the activation of caspase-3 levels. The present study illustrates that the mesoporous silica nanoparticle composite nanofibrous scaffold could have anti-tumor properties and could be further developed as adjuvant therapeutic protocols for the treatment of cancer.

  11. Damage Tolerance of Pre-Stressed Composite Panels Under Impact Loads

    Science.gov (United States)

    Johnson, Alastair F.; Toso-Pentecôte, Nathalie; Schueler, Dominik

    2014-02-01

    An experimental test campaign studied the structural integrity of carbon fibre/epoxy panels preloaded in tension or compression then subjected to gas gun impact tests causing significant damage. The test programme used representative composite aircraft fuselage panels composed of aerospace carbon fibre toughened epoxy prepreg laminates. Preload levels in tension were representative of design limit loads for fuselage panels of this size, and maximum compression preloads were in the post-buckle region. Two main impact scenarios were considered: notch damage from a 12 mm steel cube projectile, at velocities in the range 93-136 m/s; blunt impact damage from 25 mm diameter glass balls, at velocities 64-86 m/s. The combined influence of preload and impact damage on panel residual strengths was measured and results analysed in the context of damage tolerance requirements for composite aircraft panels. The tests showed structural integrity well above design limit loads for composite panels preloaded in tension and compression with visible notch impact damage from hard body impact tests. However, blunt impact tests on buckled compression loaded panels caused large delamination damage regions which lowered plate bending stiffness and reduced significantly compression strengths in buckling.

  12. Electric Heating Property from Butyl Rubber-Loaded Boron Carbide Composites

    Institute of Scientific and Technical Information of China (English)

    MENG Dechuan; WANG Ninghui; LI Guofeng

    2014-01-01

    We researched the electric heating property from butyl rubber-loaded boron carbide composite. The effects of boron carbide content on bulk resistivity, voltage-current characteristic, thermal conductivity and thermal stability of boron carbide/butyl rubber (IIR) polymer composite were introduced. The analysis results indicated that the bulk resistivity decreased greatly with increasing boron carbide content, and when boron carbide content reached to 60%, the bulk resistivity achieved the minimum. Accordingly, electric heating behavior of the composite is strongly dependent on boron carbide content as well as applied voltage. The content of boron carbide was found to be effective in achieving high thermal conductivity in composite systems. The thermal conductivity of the composite material with added boron carbide was improved nearly 20 times than that of the pure IIR. The thermal stability test showed that, compared with pure IIR, the thermal stable time of composites was markedly extended, which indicated that the boron carbide can significantly improve the thermal stability of boron carbide/IIR composite.

  13. Large deformation micromechanics of particle filled acrylics at elevated temperatures

    Science.gov (United States)

    Gunel, Eray Mustafa

    The main aim of this study is to investigate stress whitening and associated micro-deformation mechanism in thermoformed particle filled acrylic sheets. For stress whitening quantification, a new index was developed based on image histograms in logarithmic scale of gray level. Stress whitening levels in thermoformed acrylic composites was observed to increase with increasing deformation limit, decreasing forming rate and increasing forming temperatures below glass transition. Decrease in stress whitening levels above glass transition with increasing forming temperature was attributed to change in micro-deformation behavior. Surface deformation feature investigated with scanning electron microscopy showed that source of stress whitening in thermoformed samples was a combination of particle failure and particle disintegration depending on forming rate and temperature. Stress whitening level was strongly correlated to intensity of micro-deformation features. On the other hand, thermoformed neat acrylics displayed no surface discoloration which was attributed to absence of micro-void formation on the surface of neat acrylics. Experimental damage measures (degradation in initial, secant, unloading modulus and strain energy density) have been inadequate in describing damage evolution in successive thermoforming applications on the same sample at different levels of deformation. An improved version of dual-mechanism viscoplastic material model was proposed to predict thermomechanical behavior of neat acrylics under non-isothermal conditions. Simulation results and experimental results were in good agreement and failure of neat acrylics under non-isothermal conditions ar low forming temperatures were succesfully predicted based on entropic damage model. Particle and interphase failure observed in acrylic composites was studied in a multi-particle unit cell model with different volume fractions. Damage evolution due to particle failure and interphase failure was simulated

  14. Epoxy-acrylic core-shell particles by seeded emulsion polymerization.

    Science.gov (United States)

    Chen, Liang; Hong, Liang; Lin, Jui-Ching; Meyers, Greg; Harris, Joseph; Radler, Michael

    2016-07-01

    We developed a novel method for synthesizing epoxy-acrylic hybrid latexes. We first prepared an aqueous dispersion of high molecular weight solid epoxy prepolymers using a mechanical dispersion process at elevated temperatures, and we subsequently used the epoxy dispersion as a seed in the emulsion polymerization of acrylic monomers comprising methyl methacrylate (MMA) and methacrylic acid (MAA). Advanced analytical techniques, such as scanning transmission X-ray microscopy (STXM) and peak force tapping atomic force microscopy (PFT-AFM), have elucidated a unique core-shell morphology of the epoxy-acrylic hybrid particles. Moreover, the formation of the core-shell morphology in the seeded emulsion polymerization process is primarily attributed to kinetic trapping of the acrylic phase at the exterior of the epoxy particles. By this new method, we are able to design the epoxy and acrylic polymers in two separate steps, and we can potentially synthesize epoxy-acrylic hybrid latexes with a broad range of compositions.

  15. Effect of Cyclic Thermo-Mechanical Loads on Fatigue Reliability in Polymer Matrix Composites

    Science.gov (United States)

    Shah, A. R.; Murthy, P. L. N.; Chamis, C. C.

    1996-01-01

    A methodology to compute probabilistic fatigue life of polymer matrix laminated composites has been developed and demonstrated. Matrix degradation effects caused by long term environmental exposure and mechanical/thermal cyclic loads are accounted for in the simulation process. A unified time-temperature-stress dependent multi-factor interaction relationship developed at NASA Lewis Research Center has been used to model the degradation/aging of material properties due to cyclic loads. The fast probability integration method is used to compute probabilistic distribution of response. Sensitivities of fatigue life reliability to uncertainties in the primitive random variables (e.g., constituent properties, fiber volume ratio, void volume ratio, ply thickness, etc.) computed and their significance in the reliability- based design for maximum life is discussed. The effect of variation in the thermal cyclic loads on the fatigue reliability for a (0/+/- 45/90)(sub s) graphite/epoxy laminate with a ply thickness of 0.127 mm, with respect to impending failure modes has been studied. The results show that, at low mechanical cyclic loads and low thermal cyclic amplitudes, fatigue life for 0.999 reliability is most sensitive to matrix compressive strength, matrix modulus, thermal expansion coefficient, and ply thickness. Whereas at high mechanical cyclic loads and high thermal cyclic amplitudes, fatigue life at 0.999 reliability is more sensitive to the shear strength of matrix, longitudinal fiber modulus, matrix modulus, and ply thickness.

  16. Dynamic Fracture of Nanocomposites and Response of Fiber Composite Panels to Shock Loading

    Science.gov (United States)

    Shukla, Arun

    2009-06-01

    This lecture will present studies on the response of novel engineering materials to extreme dynamic loadings. In particular, the talk will focus on the behavior of sandwich composite materials to shock loading and dynamic fracture of nano-composite materials. Results from an experimental study on the response of sandwich materials to controlled blast loading will be presented. In this study, a shock tube facility was utilized to apply blast loading to simply supported plates of E-glass vinyl ester/PVC foam sandwich composite materials. Pressure sensors were mounted at the end of the muzzle section of the shock tube to measure the incident pressure and the reflected pressure profiles during the experiment. A high speed digital camera was utilized to capture the real time side deformation of the materials, as well as the development and progression of damage. Macroscopic and microscopic examination was then implemented to study the post-mortem damage. Conclusions on the relative performance of sandwich composites under blast loadings will also be discussed. Results from an experimental investigation conducted to evaluate the mechanical properties of novel materials fabricated using nano sized particles in polymer matrix will also be presented. Unsaturated polyester resin specimens embedded with small loadings of nano sized particles of TiO2 and Al2O3 were fabricated using a direct ultrasonification method to study the effects of nanosized particles on nanocomposite fracture properties. The ultrasonification method employed produced nanocomposites with excellent particle dispersion as verified by TEM. Experiments were conducted to investigate the dynamic crack initiation and rapid crack propagation in theses particle reinforced materials. High-speed digital imaging was employed along with dynamic photoelasticity to obtain real time, full-field quantification of the stress field associated with the dynamic fracture process. Birefringent coatings were used to conduct

  17. On the Behavior of Fiberglass Epoxy Composites under Low Velocity Impact Loading

    Directory of Open Access Journals (Sweden)

    Gautam S. Chandekar

    2010-01-01

    Full Text Available Response of fiberglass epoxy composite laminates under low velocity impact loading is investigated using LS-DYNA®, and the results are compared with experimental analysis performed using an instrumented impact test setup (Instron dynatup 8250. The composite laminates are manufactured using H-VARTM© process with basket weave E-Glass fabrics. Epon 862 is used as a resin system and Epicure-W as a hardening agent. Composite laminates, with 10 layers of fiberglass fabrics, are modeled using 3D solid elements in a mosaic fashion to represent basket weave pattern. Mechanical properties are calculated by using classical micromechanical theory and assigned to the elements using ORTHOTROPIC ELASTIC material model. The damage occurred since increasing impact energy is incorporated using ADVANCED COMPOSITE DAMAGE material model in LS-DYNA®. Good agreements are obtained with the failure damage results in LS-DYNA® and experimental results. Main considerations for comparison are given to the impact load carrying capacity and the amount of impact energy absorbed by the laminates.

  18. [Preparation and clinical application of polyvinyl alcohol/drug-loaded chitosan microsphere composite wound dressing].

    Science.gov (United States)

    Zhang, Xiuju; Lin, Zhidan; Chen, Wenbin; Song, Ying; Li, Zhizhong

    2011-04-01

    In order to prepare and apply the polyvinyl alcohol/drug-loaded chitosan microspheres composite wound dressing, we first prepared chitosan microspheres by emulsion cross-linking method, and then added chitosan microspheres into the reactants during the acetalization of polyvinyl alcohol and formaldehyde. We further studied the morphology, water absorption, swelling degree, mechanical properties and in vitro release of the sponge with different amount of chitosan microspheres. The results showed that polyvinyl alcohol/drug-loaded chitosan composite sponge has porous structure with connectionism. Increasing the amount of chitosan microspheres would make the apertures smaller, so that the water absorption and the swelling of sponge decreased, but the tensile strength and compressive strength increased. With the increase of the amount of chitosan microspheres, the drug absorption of cefradine and the release rate increase, and the release time become longer. With the results of toxicity grade of 0 to 1, this type of composite sponge is non-toxic and meets the requirement of biocompatibility. The observation of rabbit nasal cavity after surgical operation suggested that polyvinyl acetal sponge modified with the chitosan has antiphlogistic, hemostatic and non-adherent characteristic, and can promote the healing and recovering of the nasalmucosa. After using this composite material, best growing surroundings for patients' granulation tissue were provided. Exposed bone and tendon were covered well with granulation tissue.

  19. Combined effects of organic aerosol loading and fog processing on organic aerosols oxidation and composition

    Science.gov (United States)

    Chakraborty, Abhishek; Tripathi, Sachchida; Gupta, Tarun

    2016-04-01

    Fog is a natural meteorological phenomenon that occurs throughout the world, it contains substantial quantity of liquid water and generally seen as a natural cleansing agent but it also has the potential to form highly oxidized secondary organic aerosols (SOA) via aqueous processing of ambient aerosols. On the other hand higher organic aerosols (OA) loading tend to decrease the overall oxidation level (O/C) of the particle phase organics, due to enhanced partitioning of less oxidized organics from gas to particle phase. However, combined impact of these two parameters; aqueous oxidation and OA loading, on the overall oxidation ratio (O/C) of ambient OA has never been studied. To assess this, real time ambient sampling using HR-ToF-AMS was carried out at Kanpur, India from 15 December 2014 - 10 February 2015. In first 3 weeks of this campaign, very high OA loading is (134 ± 42 μg/m3) observed (termed as high loading or HL period) while loading is substantially reduced from 2nd January, 2016 (56 ± 20 μg/m3, termed as low loading or LL period) . However, both the loading period was affected by several fog episodes (10 in HL and 7 in LL), thus providing the opportunity of studying the combined effects of fog and OA loading on OA oxidation. It is found that O/C ratio is very strongly anti-correlated with OA loading in both the loading period, however, slope of this ant-correlation is much steep during HL period than in LL period. Source apportionment of OA revealed that there is drastic change in the types of OA from HL to LL period, clearly indicating difference in OA composition from HL to LL period. During foggy night continuous oxidation of OA is observed from early evening to early morning with 15-20% enhancement in O/C ratio, while the same is absent during non-foggy period, clearly indicating the efficient fog processing of ambient OA. It is also found that night time fog aqueous oxidation can be as effective as daytime photo chemistry in oxidation of OA. Fog

  20. Effect of Piezoelectric Implant on the Structural Integrity of Composite Laminates Subjected to Tensile Loads

    Science.gov (United States)

    Masmoudi, Sahir; El Mahi, Abderrahim; Turki, Saïd

    2017-02-01

    The embedment of sensors within composite structures gives the opportunity to develop smart materials for health and usage monitoring systems. This study investigates the use of acoustic emission monitoring with embedded piezoelectric sensor during mechanical tests in order to identify the effects of introducing the sensor into the composite materials. The composite specimen with and without embedded sensor were subject to tensile static and fatigue loading. The analysis and observation of AE signals show that the integration of a sensor presents advantage of the detection of the acoustic events and also show the presence of three or four types of damage during tests. The incorporation of piezoelectric sensor has a negligible influence on the mechanical properties of materials.

  1. Buckling analysis of curved composite sandwich panels subjected to inplane loadings

    Science.gov (United States)

    Cruz, Juan R.

    1993-01-01

    Composite sandwich structures are being considered for primary structure in aircraft such as subsonic and high speed civil transports. The response of sandwich structures must be understood and predictable to use such structures effectively. Buckling is one of the most important response mechanisms of sandwich structures. A simple buckling analysis is derived for sandwich structures. This analysis is limited to flat, rectangular sandwich panels loaded by uniaxial compression (N(sub x)) and having simply supported edges. In most aerospace applications, however, the structure's geometry, boundary conditions, and loading are usually very complex. Thus, a general capability for analyzing the buckling behavior of sandwich structures is needed. The present paper describes and evaluates an improved buckling analysis for cylindrically curved composite sandwich panels. This analysis includes orthotropic facesheets and first-order transverse shearing effects. Both simple support and clamped boundary conditions are also included in the analysis. The panels can be subjected to linearly varying normal loads N(sub x) and N(sub y) in addition to a constant shear load N(sub xy). The analysis is based on the modified Donnell's equations for shallow shells. The governing equations are solved by direct application of Galerkin's method. The accuracy of the present analysis is verified by comparing results with those obtained from finite element analysis for a variety of geometries, loads, and boundary conditions. The limitations of the present analysis are investigated, in particular those related to the shallow shell assumptions in the governing equations. Finally, the computational efficiency of the present analysis is considered.

  2. Effect of Fiber Treatment and Fiber Loading on Mechanical Properties of Luffa-Resorcinol Composites

    Directory of Open Access Journals (Sweden)

    Chhatrapati Parida

    2015-01-01

    Full Text Available Tensile and compressive behaviour of resorcinol-formaldehyde (RF matrix and its composites reinforced with fibers of Luffa cylindrica (LC have been studied. LC fibers were subjected to chemical treatments such as alkali activation by NaOH followed by bleaching and acid hydrolysis in order to improve fiber-matrix adhesion. Both treated and untreated LC fibers are modified with calcium phosphate. The presence of hydroxy apatite, a polymorph of calcium phosphate and a major constituent of vertebrate bone and teeth, was confirmed from XRD peak of treated LC fiber. XRD analysis of the treated LC fiber has confirmed the crystalline nature of the chemically treated LC fiber by its crystallinity index. The effects of fiber loading of chemically treated and untreated LC fiber on ultimate stress, yield strength, breaking stress, and modulus of the composites were analyzed. The tensile and compressive modulus of the composites were increased with incorporation of both treated and untreated LC fibers into the RF matrix. The modulus of composites with treated LC fiber was enhanced compared to that of the untreated fiber composites. Furthermore the values of ultimate stress, yield stress, and breaking stress were increased with the incorporation of treated LC fiber in the composites.

  3. Dynamic Response of Rcc and Composite Structure with Brb Frame Subjected To Seismic and Temperature Load

    Directory of Open Access Journals (Sweden)

    Syeda Qurratul Aien Najia

    2016-04-01

    Full Text Available Concrete structures impart more seismic weight and less deflection whereas Steel structures instruct more deflections and ductility to the structure, which is beneficial in resisting earthquake forces. Composite Construction combines the better properties of both steel and concrete. Buckling restrained braced frames (BRBFs are primarily used as seismic-force resisting systems for buildings in seismically-active regions.The objective of the present work is to compare a twenty storied RCC and composite framed structure with BRB frame subjected to Seismic and different Temperatureloadings using Non-Linear Time History Analysis. Three dimensional modeling and analysis of the structure is carried out with the help of SAP-2000 v16 software. It is observed that the storey displacements were decreased by 36% for twenty storey RCC building and for composite buildings it was decreased by 45% for twenty storeys suggesting the effectiveness of Buckling restrained brace frame. The overall results suggested that BRB were excellent seismic control device for composite building as the roof displacement is reduced by 40% but whereas for RCC it is reduced only by 25%. For Seismic prone areas composite building with BRB frame is more effective. Under Temperature loading RCC building is more effective than composite structure.

  4. The creep behavior of acrylic denture base resins.

    Science.gov (United States)

    Sadiku, E R; Biotidara, F O

    1996-01-01

    The creep behavior of acrylic dental base resins, at room temperature and at different loading conditions, has been examined. The behaviors of these resins are similar to that of "commercial perspex" at room temperature over a period of 1000 seconds. The pseudo-elastic moduli of the blends of PMMA VC show a significant increase compared with PMMA alone. The addition of the PVC powder to the heat-cured acrylic resin increased the time-dependent elastic modulus. This increase in elastic modulus is advantageous in the production of denture based resins of improv mechanical properties.

  5. Acrylic Acid and Esters Will Be Oversupply

    Institute of Scientific and Technical Information of China (English)

    Zheng Chengwang

    2007-01-01

    @@ Drastic capacity growth The production capacity of acrylic acid in China has grown drastically in recent years. With the completion of the 80 thousand t/a acrylic acid and 130 thous and t/a acrylic ester project in Shenyang Paraffin Chemical Industrial Co., Ltd., (CCR2006,No. 31) the capacity of acrylic acid in China has reached 882 thousand t/a.

  6. Hybrid Carbon-Glass Fiber/Toughened Epoxy Thick Composite Joints Subject to Drop-Weight and Ballistic Impacts

    Science.gov (United States)

    2007-12-01

    Composite Materials 1988; 22: 518-532. 111. Liaw BM, Pierides AM and Liu YX. Ultrasonic assessment of impact damage in aluminum /acrylic sandwich plates...Ninth International Conference on Composite Materials , ICCM/9, Vol. V: Composites Behaviour , Miravete A (Ed), Madrid, Spain, July 12-16, 1993: 311-320...line loading. J. of Composite Materials 1993; 27: 1443-64. 148. Mouritz AP, Gallagher J and Goodwin AA. Flexural strength and interlaminar shear

  7. Effect of cyclic high loading rates on the fatigue strength of aluminum-based composites

    Science.gov (United States)

    Calderon Arteaga, Hermes Eskander

    The study of fatigue under high loading rates is of great interest in the complete characterization of a new series of composites with Al-Cu-Mg matrix reinforced with AlB2 dispersoids. Homogeneous and functionally graded composites were prepared via gravity and centrifugal casting, respectively. Through centrifugal casting a gradual variation of the volume fraction of reinforcing particles along the cross section was obtained. In specific fabrication conditions, even complete segregation of the reinforcement particles was achieved. Charpy impact tests as well as hardness tests were conducted to assess the composite strength as a function of the weight percent of boron. The tensile properties of gravity cast samples were obtained. Then for both casting conditions, simple edge-notched bend SE(B) specimens were tested under fatigue conditions (three-point bending). The results from impact and hardness tests allowed identifying an interaction between the Mg dissolved in the matrix and the diborides. This interaction, which has never been reported before, was responsible for the strength reduction observed. It was assumed that a substitutional diffusion of Al by Mg atoms in the hp3 structure of diboride was causing the strength reduction, and three approaches were developed to estimate the amount of Mg depleted from the matrix by the diborides during the composite processing. Gravity cast samples were more sensitive to monotonic damage due to fatigue loads where compared with functionally-graded composites. Contrary to the centrifugal cast samples, gravity samples were also affected by the loading rate. The Mg-AlB2 interaction was also responsible for the reduction in the fatigue resistance as the weight percent of boron increased in both types of composites; regression models were obtained to predict the crack growth curve slope change as function of the boron level. The particle distribution showed to affect the crack growth behavior of the FGMs, decreasing the

  8. Influence of surface preparation on fracture load of resin composite-based repairs

    Science.gov (United States)

    Mateos-Palacios, Rocío; Román-Rodríguez, Juan-Luis; Solá-Ruíz, María-Fernanda; Fons-Font, Antonio

    2015-01-01

    The purpose of the present study is to evaluate the fracture load of composite-based repairs to fractured zirconium oxide (Z) crowns and to ceramic-fused-to-metal (CM) crowns, comparing different mechanical surface preparation methods. A total of 75 crowns were repaired; samples then underwent dynamic loading and thermocycling. Final fracture load values for failure of the repaired crowns were measured and the type of fracture registered. Group I: CM: Surface preparation with a diamond bur + 9.5% Hydrofluoric Acid (HF) etching; Group II): CM: air-particle (Al2O3) + 9.5% HF; Group III: CM: Silica coating (SiO2); Group IV): Z: air-particle (Al2O3) + HF 9.5%; Group V) Z: Silica coating (SiO2). Of the three CM groups, Group I (CM-diamond bur) showed the highest mean failure value, with significant difference in comparison with Group III (CM-silica coating). For the zirconia groups, the highest value was obtained by Group V (silica coating). Key words:Crown, ceramic-fused-to-metal, zirconia, resin-composite, ceramic covering. PMID:25810848

  9. Influence of surface preparation on fracture load of resin composite-based repairs.

    Science.gov (United States)

    Agustín-Panadero, Rubén; Mateos-Palacios, Rocío; Román-Rodríguez, Juan-Luis; Solá-Ruíz, María-Fernanda; Fons-Font, Antonio

    2015-02-01

    The purpose of the present study is to evaluate the fracture load of composite-based repairs to fractured zirconium oxide (Z) crowns and to ceramic-fused-to-metal (CM) crowns, comparing different mechanical surface preparation methods. A total of 75 crowns were repaired; samples then underwent dynamic loading and thermocycling. Final fracture load values for failure of the repaired crowns were measured and the type of fracture registered. Group I: CM: Surface preparation with a diamond bur + 9.5% Hydrofluoric Acid (HF) etching; Group II): CM: air-particle (Al2O3) + 9.5% HF; Group III: CM: Silica coating (SiO2); Group IV): Z: air-particle (Al2O3) + HF 9.5%; Group V) Z: Silica coating (SiO2). Of the three CM groups, Group I (CM-diamond bur) showed the highest mean failure value, with significant difference in comparison with Group III (CM-silica coating). For the zirconia groups, the highest value was obtained by Group V (silica coating). Key words:Crown, ceramic-fused-to-metal, zirconia, resin-composite, ceramic covering.

  10. Temperature effects on polymer-carbon composite sensors: evaluating the role of polymer molecular weight and carbon loading

    Science.gov (United States)

    Homer, M. L.; Lim, J. R.; Manatt, K.; Kisor, A.; Lara, L.; Jewell, A. D.; Yen, S. -P. S.; Shevade, A. V.; Ryan, M. A.

    2003-01-01

    We report the effect of environmental condtions coupled with varying polymer properties and carbon loadings on the performance of polymer-carbon black composite film, used as sensing medium in the JPL Electronic Nose.

  11. 纳米腐植酸/丙烯酸-丙烯酰胺-蒙脱土复合型树脂的制备与表征%Preparation and characterization of nanoscale humic acid /poly(acrylic acid-acryl amide)-co-montorillonite composite resin

    Institute of Scientific and Technical Information of China (English)

    程亮; 侯翠红; 徐丽; 雒廷亮; 张保林; 刘国际

    2016-01-01

    The composite resins based on (acrylic acid-acrylamide)-motorillonite/nano humic acid were prepared by aqueous solution polymerization,using methylene-bis-acrylamide as cross-linking agent,potassium persulfate as initiator,acrylic acid,acrylamide,nano humic acid and modified montmorillonite as material.The effects of the monomer ratio (mass ratio ),nano-humic acid content,reaction temperature were systematically studied through single factor and orthogonal experiment.The optimum conditions were as follows:the monomer ratio 3:7 ,nano humic acid content 15%(mass fraction),reaction temperature 65℃,neutralization degree 80%(mass fraction), cross-linking agent content 0.05% (mass fraction),and initiator content 1.0% (mass fraction).The water absorption rate and salt absorption rate of the prepared composite resins were 998.90 g/g and 102.59 g/g, respectively.The product was characterized by FT-IR,SEM and TG-DSC,and the results showed that the grafting reaction took place among nanoscale humic acid and acrylamide,and ether bond emerged;the surface was rough and had loose structure,there were also many holes,voids and pits;it had a good thermal stability.%以N,N-亚甲基双丙烯酰胺为交联剂,过二硫酸钾为引发剂,丙烯酸、丙烯酰胺、纳米腐植酸及改性蒙脱土为原料,采用水溶液聚合法制备了丙烯酸-丙烯酰胺/纳米腐植酸基复合型树脂.通过单因素及正交实验系统考察了单体比(质量比)、纳米腐植酸用量、反应温度等因素对复合型树脂吸液倍率的影响.最适宜制备工艺条件为:单体比3:7,纳米腐植酸用量为15%,反应温度65℃,中和度80%,交联剂0.05%,引发剂1.0%,所制备的复合型树脂吸水和吸盐倍率分别为998.90 g/g及102.59 g/g.用FT-IR,SEM及TG-DSC等对产物进行表征,结果表明:纳米腐植酸与丙烯酰胺发生接枝反应,产生了醚键;其表面结构疏松且粗糙,呈现较多孔洞、空隙及凹坑;热稳定性较好.

  12. The Effect of Delamination on Damage Path and Failure Load Prediction for Notched Composite Laminates

    Science.gov (United States)

    Satyanarayana, Arunkumar; Bogert, Philip B.; Chunchu, Prasad B.

    2007-01-01

    The influence of delamination on the progressing damage path and initial failure load in composite laminates is investigated. Results are presented from a numerical and an experimental study of center-notched tensile-loaded coupons. The numerical study includes two approaches. The first approach considers only intralaminar (fiber breakage and matrix cracking) damage modes in calculating the progression of the damage path. In the second approach, the model is extended to consider the effect of interlaminar (delamination) damage modes in addition to the intralaminar damage modes. The intralaminar damage is modeled using progressive damage analysis (PDA) methodology implemented with the VUMAT subroutine in the ABAQUS finite element code. The interlaminar damage mode has been simulated using cohesive elements in ABAQUS. In the experimental study, 2-3 specimens each of two different stacking sequences of center-notched laminates are tensile loaded. The numerical results from the two different modeling approaches are compared with each other and the experimentally observed results for both laminate types. The comparisons reveal that the second modeling approach, where the delamination damage mode is included together with the intralaminar damage modes, better simulates the experimentally observed damage modes and damage paths, which were characterized by splitting failures perpendicular to the notch tips in one or more layers. Additionally, the inclusion of the delamination mode resulted in a better prediction of the loads at which the failure took place, which were higher than those predicted by the first modeling approach which did not include delaminations.

  13. Mechanical Properties of Steel-FRP Composite Bars under Tensile and Compressive Loading

    Directory of Open Access Journals (Sweden)

    Zeyang Sun

    2017-01-01

    Full Text Available The factory-produced steel-fiber reinforced polymer composite bar (SFCB is a new kind of reinforcement for concrete structures. The manufacturing technology of SFCB is presented based on a large number of handmade specimens. The calculated stress-strain curves of ordinary steel bar and SFCB under repeated tensile loading agree well with the corresponding experimental results. The energy-dissipation capacity and residual strain of both steel bar and SFCB were analyzed. Based on the good simulation results of ordinary steel bar and FRP bar under compressive loading, the compressive behavior of SFCB under monotonic loading was studied using the principle of equivalent flexural rigidity. There are three failure modes of SFCB under compressive loading: elastic buckling, postyield buckling, and no buckling (ultimate compressive strength is reached. The increase in the postyield stiffness of SFCB rsf can delay the postyield buckling of SFCB with a large length-to-diameter ratio, and an empirical equation for the relationship between the postbuckling stress and rsf is suggested, which can be used for the design of concrete structures reinforced by SFCB to consider the effect of reinforcement buckling.

  14. Comparative Evaluation Of Reinforced Concrete, Steel And Composite Structures Under The Effect Of Static And Dynamic Loads

    OpenAIRE

    Zafar Mujawar; Prakarsh Sangave

    2015-01-01

    Steel-concrete composite construction has gained wide acceptance all over the world as an alternative for pure steel and pure concrete construction. However this approach is a new concept for construction industry. R.C.C are no longer economical because of their increased dead load, hazardous formwork. The present study deals with comparison of reinforced concrete, steel and composite structures under the effect of static and dynamic loads. The results of this work show that compo...

  15. Macroscopic Mechanical Characterization of SMAs Fiber-Reinforced Hybrid Composite Under Uniaxial Loading

    Science.gov (United States)

    Lei, Hongshuai; Wang, Zhenqing; Tong, Liyong; Tang, Xiaojun

    2013-10-01

    This paper presents an experimental and theoretical investigation on the macroscopic mechanical behavior of shape memory alloys (SMAs) fiber-reinforced glass/resin composite subject to uniaxial loading at ambient temperature. A series of unidirectional SMAs reinforced composite laminates is fabricated through vacuum-assisted resin injection. Scanning electron microscopy is conducted to evaluate the interfacial cohesive quality between SMAs fiber and matrix. A theoretical model is proposed based on the SMAs phase transformation model and rule of mixture. Uniaxial tensile tests are performed to study the effects of weak interface and SMAs fiber volume fraction on the effective modulus of composite. Failure morphology of composite is discussed based on the observation using digital HF microscope. Due to the effects of phase transformation and weak interface, the overall stiffness of SMAs composite at the second stage is on average 10% lower than theoretical results. The rupture elongation of experimental result is approximately 13% higher than theoretical result. The local interfacial debonding between SMAs fiber and glass/resin matrix is the main failure mode.

  16. Development of Composite Scaffolds for Load-Bearing Segmental Bone Defects

    Directory of Open Access Journals (Sweden)

    Marcello Pilia

    2013-01-01

    Full Text Available The need for a suitable tissue-engineered scaffold that can be used to heal load-bearing segmental bone defects (SBDs is both immediate and increasing. During the past 30 years, various ceramic and polymer scaffolds have been investigated for this application. More recently, while composite scaffolds built using a combination of ceramics and polymeric materials are being investigated in a greater number, very few products have progressed from laboratory benchtop studies to preclinical testing in animals. This review is based on an exhaustive literature search of various composite scaffolds designed to serve as bone regenerative therapies. We analyzed the benefits and drawbacks of different composite scaffold manufacturing techniques, the properties of commonly used ceramics and polymers, and the properties of currently investigated synthetic composite grafts. To follow, a comprehensive review of in vivo models used to test composite scaffolds in SBDs is detailed to serve as a guide to design appropriate translational studies and to identify the challenges that need to be overcome in scaffold design for successful translation. This includes selecting the animal type, determining the anatomical location within the animals, choosing the correct study duration, and finally, an overview of scaffold performance assessment.

  17. Damage Simulation in Non-Crimp Fabric Composite Plates Subjected to Impact Loads

    Science.gov (United States)

    Satyanarayana, Arunkumar; Bogert, Philip B.; Aitharaju, Venkat; Aashat, Satvir; Kia, Hamid

    2014-01-01

    Progressive failure analysis (PFA) of non-crimp fabric (NCF) composite laminates subjected to low velocity impact loads was performed using the COmplete STress Reduction (COSTR) damage model implemented through VUMAT and UMAT41 user subroutines in the frame works of the commercial finite element programs ABAQUS/Explicit and LS-DYNA, respectively. To validate the model, low velocity experiments were conducted and detailed correlations between the predictions and measurements for both intra-laminar and inter-laminar failures were made. The developed material and damage model predicts the peak impact load and duration very close with the experimental results. Also, the simulation results of delamination damage between the ply interfaces, in-plane matrix damages and fiber damages were all in good agreement with the measurements from the non-destructive evaluation data.

  18. Electrical resistance load effect on magnetoelectric coupling of magnetostrictive/piezoelectric laminated composite

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yaojin, E-mail: wangyaojin@hotmail.co [Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 215 Chengbei Road, Jiading, Shanghai 201800 (China); Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China); Zhao, Xiangyong [Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 215 Chengbei Road, Jiading, Shanghai 201800 (China); Jiao, Jie; Liu, Linhua [Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 215 Chengbei Road, Jiading, Shanghai 201800 (China); Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China); Di, Wenning; Luo, Haosu [Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 215 Chengbei Road, Jiading, Shanghai 201800 (China); Or, Siu Wing, E-mail: eeswor@polyu.edu.h [Department of Electrical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong)

    2010-06-25

    The effect of electrical resistance load on the magnetoelectric (ME) coupling of laminated composite of Tb{sub 0.3}Dy{sub 0.7}Fe{sub 1.92} (Terfenol-D) magnetostrictive alloy and 0.7Pb (Mg{sub 1/3}Nb{sub 2/3})O{sub 3}-0.3PbTiO{sub 3} (PMN-PT) piezoelectric single crystal is investigated at both non-resonance and resonance frequencies. The results show that (i) the ME coefficient and ME resonance frequency increase with the increase in electrical resistance load, and (ii) the maximum ME power occurs in open-circuit condition. The present study provides the basis for the design of ME sensors and their signal-processing and electronic circuits.

  19. Buckling of laminated composite plates subjected to mechanical and thermal loads using meshless collocations

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Sandeep; Shukla, K. K. [Motilal Nehru National Institute of Technology, Allahabad (India); Shingh, Jeeoot [Department of Mechanical Engineering, Birla Institute of Technology Mesra, Ranchi (India)

    2013-02-15

    Meshless collocations utilizing Gaussian and Multi quadric radial basis functions for the stability analysis of orthotropic and cross ply laminated composite plates subjected to thermal and mechanical loading are presented. The governing differential equations of plate are based on higher order shear deformation theory considering two different transverse shear stress functions. The plate governing differential equations are discretized using radial basis functions to cast a set of simultaneous equations. The convergence of both radial basis functions is studied for different values of shape parameters. Several numerical examples are undertaken to demonstrate the accuracy of present method and the effects of orthotropy ratio of the material, span to thickness ratio of the plate, and fiber orientation on critical load/temperature are also presented.

  20. Damage Evolution in Composite Materials and Sandwich Structures Under Impulse Loading

    Science.gov (United States)

    Silva, Michael Lee

    Damage evolution in composite materials is a rather complex phenomenon. There are numerous failure modes in composite materials stemming from the interaction of the various constituent materials and the particular loading conditions. This thesis is concerned with investigating damage evolution in sandwich structures under repeated transient loading conditions associated with impulse loading due to hull slamming of high-speed marine craft. To fully understand the complex stress interactions, a full field technique to reveal stress or strain is required. Several full field techniques exist but are limited to materials with particular optical properties. A full field technique applicable to most materials is known as thermoelastic stress analysis (TSA) and reveals the variation in sum of principal stresses of a cyclically loaded sample by correlating the stresses to a small temperature change occurring at the loading frequency. Digital image correlation (DIC) is another noncontact full field technique that reveals the deformation field by tracking the motion of subsets of a random speckle pattern during the loading cycles. A novel experimental technique to aid in the study of damage progression that combines TSA and DIC simultaneously utilizing a single infrared camera is presented in this thesis. A technique to reliably perform DIC with an infrared (IR) camera is developed utilizing variable emissivity paint. The thermal data can then be corrected for rigid-body motion and deformation such that each pixel represents the same material point in all frames. TSA is then performed on this corrected data, reducing motion blur and increasing accuracy. This combined method with a single infrared camera has several advantages, including a straightforward experimental setup without the need to correct for geometric effects of two spatially separate cameras. Additionally, there is no need for external lighting in TSA as the measured electromagnetic radiation is emitted by the

  1. Interpreting the "g" Loadings of Intelligence Test Composite Scores in Light of Spearman's Law of Diminishing Returns

    Science.gov (United States)

    Reynolds, Matthew R.

    2013-01-01

    The linear loadings of intelligence test composite scores on a general factor ("g") have been investigated recently in factor analytic studies. Spearman's law of diminishing returns (SLODR), however, implies that the "g" loadings of test scores likely decrease in magnitude as g increases, or they are nonlinear. The purpose of this study was to (a)…

  2. Interpreting the "g" Loadings of Intelligence Test Composite Scores in Light of Spearman's Law of Diminishing Returns

    Science.gov (United States)

    Reynolds, Matthew R.

    2013-01-01

    The linear loadings of intelligence test composite scores on a general factor ("g") have been investigated recently in factor analytic studies. Spearman's law of diminishing returns (SLODR), however, implies that the "g" loadings of test scores likely decrease in magnitude as g increases, or they are nonlinear. The purpose of…

  3. Two decades of occupational (meth)acrylate patch test results and focus on isobornyl acrylate

    NARCIS (Netherlands)

    Christoffers, Wietske A; Coenraads, Pieter Jan; Schuttelaar, Marie-Louise A

    2013-01-01

    BACKGROUND: Acrylates constitute an important cause of occupational contact dermatitis. Isobornyl acrylate sensitization has been reported in only 2 cases. We encountered an industrial process operator with occupational contact dermatitis caused by isobornyl acrylate. OBJECTIVES: (i) To investigate

  4. Characterization of failure processes in tungsten copper composites under fatigue loading conditions

    Science.gov (United States)

    Kim, Yong-Suk; Verrilli, Michael J.; Gabb, Timothy P.

    1989-01-01

    A fractographic and metallographic investigation was performed on specimens of a tungsten fiber reinforced copper matrix composite (9 vol percent), which had experienced fatigue failures at elevated temperatures. Major failure modes and possible failure mechanisms, with an emphasis placed on characterizing fatigue damage accumulation, were determined. Metallography of specimens fatigued under isothermal cyclic loading suggested that fatigue damage initiates in the matrix. Cracks nucleated within the copper matrix at grain boundaries, and they propagated through cavity coalescence. The growing cracks subsequently interacted with the reinforcing tungsten fibers, producing a localized ductile fiber failure. Examinations of interrupted tests before final failure confirmed the suggested fatigue damage processes.

  5. Damage accumulation in cyclically-loaded glass-ceramic matrix composites monitored by acoustic emission.

    Science.gov (United States)

    Aggelis, D G; Dassios, K G; Kordatos, E Z; Matikas, T E

    2013-01-01

    Barium osumilite (BMAS) ceramic matrix composites reinforced with SiC-Tyranno fibers are tested in a cyclic loading protocol. Broadband acoustic emission (AE) sensors are used for monitoring the occurrence of different possible damage mechanisms. Improved use of AE indices is proposed by excluding low-severity signals based on waveform parameters, rather than only threshold criteria. The application of such improvements enhances the accuracy of the indices as accumulated damage descriptors. RA-value, duration, and signal energy follow the extension cycles indicating moments of maximum or minimum strain, while the frequency content of the AE signals proves very sensitive to the pull-out mechanism.

  6. Damage Accumulation in Cyclically-Loaded Glass-Ceramic Matrix Composites Monitored by Acoustic Emission

    Directory of Open Access Journals (Sweden)

    D. G. Aggelis

    2013-01-01

    Full Text Available Barium osumilite (BMAS ceramic matrix composites reinforced with SiC-Tyranno fibers are tested in a cyclic loading protocol. Broadband acoustic emission (AE sensors are used for monitoring the occurrence of different possible damage mechanisms. Improved use of AE indices is proposed by excluding low-severity signals based on waveform parameters, rather than only threshold criteria. The application of such improvements enhances the accuracy of the indices as accumulated damage descriptors. RA-value, duration, and signal energy follow the extension cycles indicating moments of maximum or minimum strain, while the frequency content of the AE signals proves very sensitive to the pull-out mechanism.

  7. Multi-axial load application and DIC measurement of advanced composite beam deformation behavior

    Directory of Open Access Journals (Sweden)

    Berggreen C.

    2010-06-01

    Full Text Available For the validation of a new beam element formulation, a wide set of experimental data consisting of deformation patterns obtained for a number of specially designed composite beam elements, have been obtained. The composite materials applied in the beams consist of glass-fiber reinforced plastic with specially designed layup configurations promoting advanced coupling behavior. Furthermore, the beams are designed with different cross-section shapes. The data obtained from the experiments are also used in order to improve the general understanding related to practical implementation of mechanisms of elastic couplings due to anisotropic properties of composite materials. The knowledge gained from these experiments is therefore essential in order to facilitate an implementation of passive control in future large wind turbine blades. A test setup based on a four-column MTS servo-hydraulic testing machine with a maximum capacity of 100 kN was developed, see Figure 1. The setup allows installing and testing beams of different cross-sections applying load cases such as axial extension, shear force bending, pure bending in two principal directions as well as pure torsion, see Figure 2. In order to apply multi-axial loading, a load application system consisting of three hydraulic actuators were mounted in two planes using multi-axial servo-hydraulic control. The actuator setup consists of the main actuator on the servo-hydraulic test machine working in the vertical axis (depicted on Figure 1 placed at the testing machine crosshead and used for application of vertical forces to the specimens. Two extra actuators are placed in a horizontal plane on the T-slot table of the test machine in different positions in order to apply loading at the tip of the specimen in various configurations. In order to precisely characterize the global as well as surface deformations of the beam specimens tested, a combination of different measurement systems were used during

  8. Nonlinear Analysis and Scaling Laws for Noncircular Composite Structures Subjected to Combined Loads

    Science.gov (United States)

    Hilburger, Mark W.; Rose, Cheryl A.; Starnes, James H., Jr.

    2001-01-01

    Results from an analytical study of the response of a built-up, multi-cell noncircular composite structure subjected to combined internal pressure and mechanical loads are presented. Nondimensional parameters and scaling laws based on a first-order shear-deformation plate theory are derived for this noncircular composite structure. The scaling laws are used to design sub-scale structural models for predicting the structural response of a full-scale structure representative of a portion of a blended-wing-body transport aircraft. Because of the complexity of the full-scale structure, some of the similitude conditions are relaxed for the sub-scale structural models. Results from a systematic parametric study are used to determine the effects of relaxing selected similitude conditions on the sensitivity of the effectiveness of using the sub-scale structural model response characteristics for predicting the full-scale structure response characteristics.

  9. A Damage Model for the Simulation of Delamination in Advanced Composites under Variable-Mode Loading

    Science.gov (United States)

    Turon, A.; Camanho, P. P.; Costa, J.; Davila, C. G.

    2006-01-01

    A thermodynamically consistent damage model is proposed for the simulation of progressive delamination in composite materials under variable-mode ratio. The model is formulated in the context of Damage Mechanics. A novel constitutive equation is developed to model the initiation and propagation of delamination. A delamination initiation criterion is proposed to assure that the formulation can account for changes in the loading mode in a thermodynamically consistent way. The formulation accounts for crack closure effects to avoid interfacial penetration of two adjacent layers after complete decohesion. The model is implemented in a finite element formulation, and the numerical predictions are compared with experimental results obtained in both composite test specimens and structural components.

  10. X-ray excited luminescence of polystyrene composites loaded with SrF2 nanoparticles

    Science.gov (United States)

    Demkiv, T. M.; Halyatkin, O. O.; Vistovskyy, V. V.; Hevyk, V. B.; Yakibchuk, P. M.; Gektin, A. V.; Voloshinovskii, A. S.

    2017-03-01

    The polystyrene film nanocomposites of 0.3 mm thickness with embedded SrF2 nanoparticles up to 40 wt% have been synthesized. The luminescent and kinetic properties of the polystyrene composites with embedded SrF2 nanoparticles upon the pulse X-ray excitation have been investigated. The luminescence intensity of the pure polystyrene scintillator film significantly increases when it is loaded with the inorganic SrF2 nanoparticles. The film nanocomposites show fast (∼2.8 ns) and slow (∼700 ns) luminescence decay components typical for a luminescence of polystyrene activators (p-Terphenyl and POPOP) and SrF2 nanoparticles, respectively. It is revealed that the fast decay luminescence component of the polystyrene composites is caused by the excitation of polystyrene by the photoelectrons escaped from the nanoparticles due to photoeffect, and the slow component is caused by reabsorption of the self-trapped exciton luminescence of SrF2 nanoparticles by polystyrene.

  11. Synthesis and Reactivity of Aluminized Fluorinated Acrylic (AIFA) Nanocomposites (Postprint)

    Science.gov (United States)

    2012-06-18

    REACTIVITY OF ALUMINIZED FLUORINATED ACRYLIC (ALFA) NANOCOMPOSITES (POSTPRINT) 5a. CONTRACT NUMBER In-house 5b. GRANT NUMBER 5c. PROGRAM ELEMENT...the nano Al throughout the material, the composite was compounded for 3 min in a DACA Instruments benchtop twin screw extruder at 150 C. The com

  12. Diet and environment shape fecal bacterial microbiota composition and enteric pathogen load of grizzly bears.

    Directory of Open Access Journals (Sweden)

    Clarissa Schwab

    Full Text Available BACKGROUND: Diet and environment impact the composition of mammalian intestinal microbiota; dietary or health disturbances trigger alterations in intestinal microbiota composition and render the host susceptible to enteric pathogens. To date no long term monitoring data exist on the fecal microbiota and pathogen load of carnivores either in natural environments or in captivity. This study investigates fecal microbiota composition and the presence of pathogenic Escherichia coli and toxigenic clostridia in wild and captive grizzly bears (Ursus arctos and relates these to food resources consumed by bears. METHODOLOGY/PRINCIPAL FINDINGS: Feces were obtained from animals of two wild populations and from two captive animals during an active bear season. Wild animals consumed a diverse diet composed of plant material, animal prey and insects. Captive animals were fed a regular granulated diet with a supplement of fruits and vegetables. Bacterial populations were analyzed using quantitative PCR. Fecal microbiota composition fluctuated in wild and in captive animals. The abundance of Clostridium clusters I and XI, and of C. perfringens correlated to regular diet protein intake. Enteroaggregative E. coli were consistently present in all populations. The C. sordellii phospholipase C was identified in three samples of wild animals and for the first time in Ursids. CONCLUSION: This is the first longitudinal study monitoring the fecal microbiota of wild carnivores and comparing it to that of captive individuals of the same species. Location and diet affected fecal bacterial populations as well as the presence of enteric pathogens.

  13. Effect of Static and Cyclic Loading on Ceramic Laminate Veneers Adhered to Teeth with and Without Aged Composite Restorations

    NARCIS (Netherlands)

    Gresnigt, Marco M. M.; Ozcan, Mutlu; Kalk, Warner; Galhano, Graziela

    2011-01-01

    Purpose: Existing composite restorations on teeth are often remade prior to the cementation of fixed dental prostheses. The aim of this study was to evaluate the effect of static and cyclic loading on ceramic laminate veneers adhered to aged resin composite restorations. Materials and Methods: Eight

  14. Effect of Static and Cyclic Loading on Ceramic Laminate Veneers Adhered to Teeth with and Without Aged Composite Restorations

    NARCIS (Netherlands)

    Gresnigt, Marco M. M.; Ozcan, Mutlu; Kalk, Warner; Galhano, Graziela

    2011-01-01

    Purpose: Existing composite restorations on teeth are often remade prior to the cementation of fixed dental prostheses. The aim of this study was to evaluate the effect of static and cyclic loading on ceramic laminate veneers adhered to aged resin composite restorations. Materials and Methods:

  15. Antitumor Activity of Doxorubicin-Loaded Carbon Nanotubes Incorporated Poly(Lactic-Co-Glycolic Acid) Electrospun Composite Nanofibers

    Science.gov (United States)

    Yu, Yuan; Kong, Lijun; Li, Lan; Li, Naie; Yan, Peng

    2015-08-01

    The drug-loaded composite electrospun nanofiber has attracted more attention in biomedical field, especially in cancer therapy. In this study, a composite nanofiber was fabricated by electrospinning for cancer treatment. Firstly, the carbon nanotubes (CNTs) were selected as carriers to load the anticancer drug—doxorubicin (DOX) hydrochloride. Secondly, the DOX-loaded CNTs (DOX@CNTs) were incorporated into the poly(lactic-co-glycolic acid) (PLGA) nanofibers via electrospinning. Finally, a new drug-loaded nanofibrous scaffold (PLGA/DOX@CNTs) was formed. The properties of the prepared composite nanofibrous mats were characterized by various techniques. The release profiles of the different DOX-loaded nanofibers were measured, and the in vitro antitumor efficacy against HeLa cells was also evaluated. The results showed that DOX-loaded CNTs can be readily incorporated into the nanofibers with relatively uniform distribution within the nanofibers. More importantly, the drug from the composite nanofibers can be released in a sustained and prolonged manner, and thereby, a significant antitumor efficacy in vitro is obtained. Thus, the prepared composite nanofibrous mats are a promising alternative for cancer treatment.

  16. Studies on LCST of poly (N-isopropylacrylamide-co-acrylic acid-co-N-diacetone acrylamide)

    Institute of Scientific and Technical Information of China (English)

    Cai Hua Ni; Xiao Xia Zhu; Qing Lan Wang; Xian Yu Zeng

    2007-01-01

    Linear copolymers from N-isopropylacrylamide (NIPA), acrylic acid (AA) and diacetone acrylamide (DAA) have been prepared.The effect of composition, ionic strength and pH on their lower critical solution temperature (LCST) has been investigated.

  17. Multilayered piezomagnetic/piezoelectric composites with periodic interfacial cracks subject to in-plane loading

    Science.gov (United States)

    Tian, Wenxiang; Zhong, Zheng; Li, Yaochen

    2016-01-01

    A two-dimensional fracture problem of periodically distributed interfacial cracks in multilayered piezomagnetic/piezoelectric composites is studied under in-plane magnetic or electric loading. The magnetic permittivity of the piezoelectric material and the dielectric constant of the piezomagnetic material are considered. A system of singular integral equations of the second kind with a Cauchy kernel is obtained by means of Fourier transform and further solved by using Jacobi polynomials. The problem is solved in the real domain by constructing real fundamental solutions. The primary interfacial fracture mechanic parameters, such as the stress intensity factors (SIFs), the electric displacement intensity factors (EDIFs), the magnetic induction intensity factors (MIIFs) and the energy release rates (ERRs) are then obtained. It is found that a magnetic or electric loading normal to the crack surfaces can lead to a mixture of mode I and mode II type stress singularities at the crack tips. Numerical results show that increasing the thickness of the active layer will favor the crack initiation. Inversely, increasing the thickness of the passive layer will retard the crack initiation. Furthermore, the results indicate that the crack initiation can be inhibited by adjusting the direction of the applied magnetic or electric loading.

  18. The effect of acrylic resin functionality on the curing process and properties of acrylic-hexamethoxymethylmelamine coatings

    Directory of Open Access Journals (Sweden)

    Prendžov Slobodan J.

    2002-01-01

    Full Text Available In this paper the effect of the functionality of synthesized thermosetting acrylic resins (with hydroxy and carboxy groups and the cure temperature on the process of crosslinking and properties of the coatings was investigated. Methylated melamine resin, characterized by 1H and C NMR was used as the crosslinking agent. The degree of crosslinking was studied by infrared spectroscopy by determining the conversion of functional groups and the sol fraction. On the basis of the results obtained it was found that compositions with lower functionality of the acrylic resin had a higher conversion of functional groups, during which cocondensation reactions occurred (acrylic melamine crosslinks in a wide temperature crosslinking range. Consequently better control of the coating properties was achieved. The degree of crosslinking was in good correlation to the sol fraction content and the resin hardness.

  19. Influence of Reaction-Induced Phase Decomposition to Dispersion of Samariam Acrylic Acid (Sm (AA)3 ) in Rubber and Shielding Property of Sm(AA) 3/NR Composites

    Institute of Scientific and Technical Information of China (English)

    Liu Li; He Lei; Zhang Wan; Yang Cheng; Liu Yandong; Jin Riguang; Zhang Liqun

    2004-01-01

    According to radiation protection theory, the radiation shielding properties of composites are closely related to dispersion condition of radiation absorbing materials in matrix. The more equably radiation-shielding materials dispersed in the matrix, the better the composites' shielding properties are. Rare earth ions have preferably absorbing ability for radiation due to their special electronic structures. From our early work, we know Sm(AA) 3 has good radiationabsorbing ability and excellent compatibility with polymer matrix. Furthermore, Sm (AA) 3 has double key structures which can in-situ react with polymer matrix in vulcanization process. This in-situ reaction can also help Sm(AA) 3 disperse better in the matrix. Based on these, we studied a new method to prepare Sm( AA)3/NR( nature rubber) composites( NR used as matrix), in which Sm(AA)3 dispersed very equably with tiny particle size. Both sulfur and peroxide exist in the system as crosslinking agent. The vulcanization process occurred at the temperature of 110℃ first and a certain degree crosslinking network formed in this stage, which we called pre-vulcanization process in this paper. In this stage sulfur was used as the crosslinking agent. Then continued the vulcanization process at higher temperature(170℃). The peroxide was used as crosslinking agent in this stage. According to reaction-induced phase decomposition mechanism, we studied the phase decomposition changing mode of Sm(AA) 3 in NR matrix of different crosslinking degrees. We also studied the influence of different degrees of pre-vulcanization to the dispersion condition of Sm (AA) 3 in NR matrix. The crystal-fusion status of both Sm(AA) 3 powder and Sm(AA) 3 in cured rubber were observed by DSC (Differential Scanning Calorimetry) and XRD (X-rays Diffraction). The dispersion condition of Sm(AA) 3 in cured rubber was observed by SEM (Scanning Electron Microscopy) and TEM (Transmission Electron Microscope).The studyresults show different

  20. Characterising the loading direction sensitivity of 3D woven composites: Effect of z-binder architecture

    KAUST Repository

    Saleh, Mohamed Nasr

    2016-08-29

    Three different architectures of 3D carbon fibre woven composites (orthogonal, ORT; layer-to-layer, LTL; angle interlock, AI) were tested in quasi-static uniaxial tension. Mechanical tests (tensile in on-axis of warp and weft directions as well as 45 degrees off-axis) were carried out with the aim to study the loading direction sensitivity of these 3D woven composites. The z-binder architecture (the through-thickness reinforcement) has an effect on void content, directional fibre volume fraction, mechanical properties (on-axis and off-axis), failure mechanisms, energy absorption and fibre rotation angle in off-axis tested specimens. Out of all the examined architectures, 3D orthogonal woven composites (ORT) demonstrated a superior behaviour, especially when they were tested in 45 degrees off-axis direction, indicated by high strain to failure (similar to 23%) and high translaminar energy absorption (similar to 40 MJ/m(3)). The z-binder yarns in ORT architecture suppress the localised damage and allow larger fibre rotation during the fibre

  1. Enhanced proton conductivity of Nafion composite membrane by incorporating phosphoric acid-loaded covalent organic framework

    Science.gov (United States)

    Yin, Yongheng; Li, Zhen; Yang, Xin; Cao, Li; Wang, Chongbin; Zhang, Bei; Wu, Hong; Jiang, Zhongyi

    2016-11-01

    Design and fabrication of efficient proton transport channels within solid electrolytes is crucial and challenging to new energy-relevant devices such as proton exchange membrane fuel cells (PEMFCs). In this study, the phosphoric acid (H3PO4) molecules are impregnated into SNW-1-type covalent organic frameworks (COFs) via vacuum assisted method. High loading of H3PO4 in SNW-1 and low guest leaching rate are achieved due to the similar diameter between H3PO4 and micropores in SNW-1. Then the COF-based composite membranes are fabricated for the first time with impregnated COFs (H3PO4@SNW-1) and Nafion matrix. For the composite membranes, the acid-base pairs formed between H3PO4@SNW-1 networks and Nafion optimize the interfacial interactions and hydrophilic domains. The acidic -PO3H2 groups in pores of H3PO4@SNW-1 provide abundant proton transfer sites. As a result, the continuous proton transfer channels with low energy barrier are created. At the filler content of 15 wt%, the composite membrane exhibits a superior proton conductivity of 0.0604 S cm-1 at 51% relative humidity and 80 °C. At the same time, the maximum power density of single fuel cell is 60.3% higher than that of the recast Nafion membrane.

  2. Experimental Analysis of Repaired Masonry Elements with Flax-FRCM and PBO-FRCM Composites Subjected to Axial Bending Loads

    Directory of Open Access Journals (Sweden)

    Oscar A. Cevallos

    2015-11-01

    Full Text Available In the construction industry, the use of natural fabrics as a reinforcement for cement-based composites has shown great potential. The use of these sustainable composites to provide strengthening or repair old masonry structures that exhibit structural problems mainly due to a poor tensile strength of the mortar/brick joints is revealed to be a promising area of research. One of the most significant load conditions affecting the mechanical response of masonry structures occurs when axial bending loads are applied on the resistant cross-section. In this study, three different types of masonry elements were built using clay bricks and a lime-based mortar. After 28 days, the samples were subjected to concentric and eccentric compressive loads. In order to produce significant bending effects, the compressive loads were applied with large eccentricity, and a sudden failure characterized the behavior of the unreinforced masonry (URM elements. The tested masonry specimens were repaired using fabric-reinforced cementitious matrix (FRCM composites produced using bi-directional flax and polyparaphenylene benzobisoxazole (PBO fabrics. The mechanical behavior of the URM and repaired samples was compared in terms of load-displacement and moment-curvature responses. Furthermore, the results achieved using flax-FRCM composites were compared with those of using PBO-FRCM composites.

  3. Bonding auto-polymerising acrylic resin to acrylic denture teeth.

    LENUS (Irish Health Repository)

    Nagle, Susan

    2009-09-01

    This study investigated the effect of surface treatments on the shear bond strength of an auto-polymerising acrylic resin cured to acrylic denture teeth. The surface treatments included a combination of grit-blasting and\\/or wetting the surface with monomer. Samples were prepared and then stored in water prior to shear testing. The results indicated that the application of monomer to the surface prior to bonding did not influence the bond strength. Grit blasting was found to significantly increase the bond strength.

  4. Organic matter compositions and loadings in soils and sediments along the Fly River, Papua New Guinea

    Science.gov (United States)

    Goñi, Miguel A.; Moore, Eric; Kurtz, Andrew; Portier, Evan; Alleau, Yvan; Merrell, David

    2014-09-01

    The compositions and loadings of organic matter in soils and sediments from a diverse range of environments along the Fly River system were determined to investigate carbon transport and sequestration in this region. Soil horizons from highland sites representative of upland sources have organic carbon contents (%OC) that range from 0.3 to 25 wt%, carbon:nitrogen ratios (OC/N) that range from 7 to 25 mol/mol, highly negative stable carbon isotopic compositions (δ13Corg -25‰) and non-woody vegetation biomarkers (cinnamyl phenols and cutin acids) more abundant relative to upper floodplain sites. Soils developed on relict Pleistocene floodplain terraces, which are typically not flooded and receive little sediment from the river, were characterized by low %OC contents (-21‰) and low LP concentrations (∼3 mg/100 mg OC). These relict floodplain soils contain modern carbon that reflects primarily local (C3 or C4) vegetation sources. Total suspended solids collected along the river varied widely in overall concentrations (1 < TSS < 9000 mg/L), %OC contents (0.1-60 wt%), OC/N ratios (7-17 mol/mol) and δ13Corg signatures (-26 to -32‰). These compositions reflect a mixture of C3 vascular plants and freshwater algae. However, little of this algal production appears to be preserved in floodplain soils. A comparison of organic carbon loadings of active floodplain soils (0.2 and 0.5 mg C/m2) with previous studies of actively depositing sediments in the adjacent delta-clinoform system (0.4-0.7 mg C/m2) indicates that Fly River floodplain sediments are less effective at sequestering organic carbon than deltaic sediments. Furthermore, relict Pleistocene floodplain sites with low or negligible modern sediment accumulation rates display significantly lower loadings (0.1-0.2 mg C/m2). This deficit in organic carbon likely reflects mineralization of sedimentary organic carbon during long term oxidative weathering, further reducing floodplain carbon storage.

  5. Facile Fabrication of Gradient Surface Based on (meth)acrylate Copolymer Films

    Science.gov (United States)

    Zhang, Y.; Yang, H.; Wen, X.-F.; Cheng, J.; Xiong, J.

    2016-08-01

    This paper describes a simple and economic approach for fabrication of surface wettability gradient on poly(butyl acrylate - methyl methacrylate) [P (BA-MMA)] and poly(butyl acrylate - methyl methacrylate - 2-hydroxyethyl methacrylate) [P (BA-MMA-HEMA)] films. The (meth)acrylate copolymer [including P (BA-MMA) and P (BA-MMA-HEMA)] films are hydrolyzed in an aqueous solution of NaOH and the transformation of surface chemical composition is achieved by hydrolysis in NaOH solution. The gradient wetting properties are generated based on different functional groups on the P (BA-MMA) and P (BA-MMA-HEMA) films. The effects of both the surface chemical and surface topography on wetting of the (meth)acrylate copolymer film are discussed. Surface chemical composition along the materials length is determined by XPS, and surface topography properties of the obtained gradient surfaces are analyzed by FESEM and AFM. Water contact angle system (WCAs) results show that the P (BA-MMA-HEMA) films provide a larger slope of the gradient wetting than P (BA-MMA). Moreover, this work demonstrates that the gradient concentration of chemical composition on the poly(meth) acrylate films is owing to the hydrolysis processes of ester group, and the hydrolysis reactions that have negligible influence on the surface morphology of the poly(meth) acrylate films coated on the glass slide. The gradient wettability surfaces may find broad applications in the field of polymer coating due to the compatibility of (meth) acrylate polymer.

  6. Preparation of electrospun Ag/g-C3N4 loaded composite carbon nanofibers for catalytic applications

    Science.gov (United States)

    Yu, Bo; Liu, Yongkun; Jiang, Guohua; Liu, Depeng; Yu, Weijiang; Chen, Hua; Li, Lei; Huang, Qin

    2017-01-01

    In this paper, the electrospun Ag nanoparticles and g-C3N4 (Ag/g-C3N4) loaded composite carbon nanofibers were successfully prepared combing the electrospinning technology and carbonization treatment. The composition and microstructure of the resultant composite nanofibers were characterized by x-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy dispersive spectrometer (EDS), transmission electron microscopy (TEM) and x-ray photoelectron spectrometry (XPS). Due to the synergistic effect between catalytic activity of Ag nanoparticles (NPs) and g-C3N4 and excellent adsorption capacity of carbon nanofibers, the resultant electrospun Ag/g-C3N4 loaded composite carbon nanofibers exhibited excellent conversion of 4-nitrophenol to 4-aminophenol and benzylamine to N-benzylbenzaldimine. The resultant hybrid carbon composite nanofibers offer the significant advantages, such as low dosage, high catalytic activity, easy recycling and excellent stability.

  7. Capturing the Energy Absorbing Mechanisms of Composite Structures under Crash Loading

    Science.gov (United States)

    Wade, Bonnie

    different test geometries in order to define the range of its energy absorption capability. Further investigation from the crush tests has led to the development of a direct link between geometric features of the crush specimen and its resulting SEA. Through micrographic analysis, distinct failure modes are shown to be guided by the geometry of the specimen, and subsequently are shown to directly influence energy absorption. A new relationship between geometry, failure mode, and SEA has been developed. This relationship has allowed for the reduction of the element-level crush testing requirement to characterize the composite material energy absorption capability. In the numerical investigation, the LS-DYNA composite material model MAT54 is selected for its suitability to model composite materials beyond failure determination, as required by crush simulation, and its capability to remain within the scope of ultimately using this model for large-scale crash simulation. As a result of this research, this model has been thoroughly investigated in depth for its capacity to simulate composite materials in crush, and results from several simulations of the element-level crush experiments are presented. A modeling strategy has been developed to use MAT54 for crush simulation which involves using the experimental data collected from the coupon- and element-level crush tests to directly calibrate the crush damage parameter in MAT54 such that it may be used in higher-level simulations. In addition, the source code of the material model is modified to improve upon its capability. The modifications include improving the elastic definition such that the elastic response to multi-axial load cases can be accurately portrayed simultaneously in each element, which is a capability not present in other composite material models. Modifications made to the failure determination and post-failure model have newly emphasized the post-failure stress degradation scheme rather than the failure

  8. 水基聚氨酯丙烯酸酯/氧化石墨烯复合乳液的制备与表征%Preparation and characterization of water-based polyurethane acrylate/graphene oxide composite emulsion

    Institute of Scientific and Technical Information of China (English)

    费贵强; 王佼; 王海花; 朱科; 郭丹慧

    2016-01-01

    以天然石墨为原料,采用改进的 Hummers法制备了氧化石墨,进而超声剥离制备了氧化石墨烯.通过原位聚合法制备了系列水基聚氨酯丙烯酸酯/氧化石墨烯复合乳液,并研究了不同氧化石墨烯含量对乳胶膜热稳定性和吸水率的影响.实验结果表明:制备了氧化程度较高的氧化石墨烯,随着氧化石墨烯含量的增加,胶膜的吸水率先减小后增大.当氧化石墨烯的含量为0.5%时,胶膜的热稳定性最好.%Using flake graphite as a raw material ,graphite oxide was prepared by modified Hummers method ,and graphene oxide was obtained by ultrasonic process .A series of water‐based polyurethane acrylate/graphene oxide composite emulsion was prepared by in situ pol‐ymerization ,and the effects of different graphene oxide content of the latex film thermal sta‐bility and water absorption rate were researched .The results showed that :preparing a high degree of oxidation of graphene oxide ,the water absorption of film decreases first ,then in‐creases with increasing graphene oxide content .When the graphene oxide content was 0 .5% , the thermal stability of the film was preferably .

  9. In vitro biocompatibility of magnetic thermo-responsive nanohydrogel particles of poly(N-isopropylacrylamide-co-acrylic acid) with Fe3O4 cores: effect of particle size and chemical composition.

    Science.gov (United States)

    Chou, Feng-Yi; Lai, Jui-Yang; Shih, Chao-Ming; Tsai, Meng-Chao; Lue, Shingjiang Jessie

    2013-04-01

    Biocompatibility is a critical factor in the design and development of candidate materials for biomedical use. This paper reports on the in vitro biocompatibility of magnetic stimuli-sensitive nanohydrogel particles composed of magnetite cores in poly(N-isopropylacrylamide-co-acrylic acid) shells referred to Fe(3)O(4)/P(NIPAAm-co-AAc). The AAc concentration and polymerization time were varied to fabricate magnetic nanoparticles with various AAc levels (1.80-2.37%) and particle sizes (74-213 nm). The P(NIPAAm-co-AAc) shell exhibited thermo-sensitive properties and the Fe(3)O(4) core constituted 2.25-4.10% of the particles by weight. After a 2-day incubation of L929 cells with extract media that had been conditioned with various test samples, the cellular responses were monitored in terms of cell viability and growth. The Live/Dead assays showed that high levels of cellular viability (97.3-98.1%) were observed in all groups, indicating that none of the nanoparticles were cytotoxic. However, the 3-(4,5-dimethylthiazol-2-yl)-5-(3-carboxymetho-xyphenyl)-2-(4-sulfophenyl)-2H-tetrazolium (MTS) assays demonstrated that the activity of mitochondrial dehydrogenase varied significantly in cultures exposed to different magnetic nanohydrogel particles. The murine fibroblasts exposed to the NIP-(AAc5.1-Fe)-2 sample, which contained the highest AAc content and largest particle sizes, were the least metabolically active. In contrast, the activity levels in the cultures treated with the low AAc content and small size particles (NIP-(AAc2.6-Fe)-1) were not significantly different from those in the control group. Our findings suggest that smaller magnetic stimuli-sensitive nanohydrogel particles with a lower AAc content may have little inhibitory impact on cell proliferation. Overall, the in vitro biocompatibilities of the nanoparticles depend on the chemical composition and size of the Fe(3)O(4)/P(NIPAAm-co-AAc) particles.

  10. Geochemical composition of river loads in the Tropical Andes: first insights from the Ecuadorian Andes

    Science.gov (United States)

    Tenorio Poma, Gustavo; Govers, Gerard; Vanacker, Veerle; Bouillon, Steven; Álvarez, Lenín; Zhiminaicela, Santiago

    2015-04-01

    Processes governing the transport of total suspended material (TSM), total dissolved solids (TDS) and particulate organic carbon (POC) are currently not well known for Tropical Andean river systems. We analyzed the geochemical behavior and the budgets of the particulate and dissolved loads for several sub-catchments in the Paute River basin in the southern Ecuadorian Andes, and examined how anthropogenic activities influenced the dynamics of riverine suspended and dissolved loads. We gathered a large dataset by regularly sampling 8 rivers for their TSM, POC, and TDS. Furthermore, we determined the major elements in the dissolved load and stable isotope composition (δ13C) of both the POC, and the dissolved inorganic carbon (DIC). The rivers that were sampled flow through a wide range of land uses including: 3 nature conservation areas (100 - 300 Km²), an intensive grassland and arable zone (142 Km²); downstream of two cities (1611 and 443 Km²), and 2 degraded basins (286 and 2492 Km²). We described the geochemical characteristics of the river loads both qualitatively and quantitatively. Important differences in TSM, POC and TDS yields were found between rivers: the concentration of these loads increases according with human activities within the basins. For all rivers, TSM, TDS and POC concentrations were dependent on discharge. Overall, a clear relation between TSM and POC (r²=0.62) was observed in all tributaries. The C:N ratios and δ13CPOC suggest that the POC in most rivers is mainly derived from soil organic matter eroded from soils dominated by C3 vegetation (δ13CPOC < -22‰). Low Ca:Si ratios (<1)and high δ13CDIC (-9 to -4) in the Yanuncay, Tomebamba1 and Machángara, rivers suggest that weathering of silica rocks is dominant in these catchments, and that the DIC is mainly derived from the soil or atmospheric CO2. In contrast, the Ca:Si ratio was high for the Burgay and Jadán rivers (1-13), and the low δ13CDIC values (-9 to -15) suggest that

  11. The effect of short fiber composite base on microleakage and load-bearing capacity of posterior restorations

    Science.gov (United States)

    Garoushi, Sufyan K.; Hatem, Marwa; Lassila, Lippo V. J.; Vallittu, Pekka K.

    2015-01-01

    Abstract Objectives: To determine the marginal microleakage of Class II restorations made with different composite base materials and the static load-bearing capacity of direct composite onlay restorations. Methods: Class II cavities were prepared in 40 extracted molars. They were divided into five groups (n = 8/group) depending on composite base material used (everX Posterior, SDR, Tetric EvoFlow). After Class II restorations were completed, specimens were sectioned mid-sagitally. For each group, sectioned restorations were immersed in dye. Specimens were viewed under a stereo-microscope and the percentage of cavity leakage was calculated. Ten groups of onlay restorations were fabricated (n = 8/group); groups were made with composite base materials (everX Posterior, SDR, Tetric EvoFlow, Gradia Direct LoFlo) and covered by 1 mm layer of conventional (Tetric N-Ceram) or bulk fill (Tetric EvoCeram Bulk Fill) composites. Groups made only from conventional, bulk fill and short fiber composites were used as control. Specimens were statically loaded until fracture. Data were analyzed using ANOVA (p = 0.05). Results: Microleakage of restorations made of plain conventional composite or short fiber composite base material showed statistically (p onlay restorations made from short fiber-reinforced composite (FRC) as base or plain restoration had statistically significant higher load-bearing capacity (1593 N) (p < 0.05) than other restorations. Conclusion: Restorations combining base of short FRC and surface layer of conventional composite displayed promising performance related to microleakage and load-bearing capacity. PMID:28642894

  12. A subregional model for delamination prediction of rubber composite under fatigue loading

    Institute of Scientific and Technical Information of China (English)

    TIAN Zhen-hui; TAN Hui-feng

    2005-01-01

    Results from fatigue experiments of cross-laminated steel cord-rubber composites (SCRC) indicate that fatigue damage life can be categorized into three regimes. In terms of fatigue modes, a subregional fatigue model is developed to describe the damages evolution of SCRC under fatigue loads. Firstly, finite element analysis is introduced to determine interply stress distribution of the specimen. Then, based on the experimental fatigue data, subregional models are introduced to simulate relations between maximum strain, effective stiffness,delamination shear stress and fatigue cycles. Relations between crack density, delamination length growth rate,macro crack density and cycles are modeled by two semi-empirical models. A reasonable prediction result was achieved by the current model, where model parameters can be determined by basic outputs of fatigue testing.

  13. Evaluation of interlaminar shear strength of a unidirectional carbon/epoxy laminated composite under impact loading

    Science.gov (United States)

    Yokoyama, T.; Nakai, K.

    2006-08-01

    The interlaminar shear strength (ILSS) of a unidirectional carbon/epoxy (T700/2521) laminated composite under impact loading is determined using the conventional split Hopkinson pressure bar. Double-notch shear (DNS) specimens with lateral constraint from a supporting jig are used in the static and impact interlaminar compressive shear tests. Short-beam shear specimens are also used under static 3-point bending. Numerical stress analyses are performed to determine the shear stress and normal stress distributions on the expected failure plane in the DNS specimen using the MSC/NASTRAN package. The effect of deformation rate on the ILSS and failure mode is investigated. It is observed that the ILSS is independent of the deformation rate up to nearly 1.5m/s (dotγ ≈ 780/s). The validity of the test results is confirmed by microscopic examinations of both static and impact failure surfaces for the DNS specimens.

  14. Damage Characteristics and Residual Strength of Composite Sandwich Panels Impacted with and Without Compression Loading

    Science.gov (United States)

    McGowan, David M.; Ambur, Damodar R.

    1998-01-01

    The results of an experimental study of the impact damage characteristics and residual strength of composite sandwich panels impacted with and without a compression loading are presented. Results of impact damage screening tests conducted to identify the impact-energy levels at which damage initiates and at which barely visible impact damage occurs in the impacted facesheet are discussed. Parametric effects studied in these tests include the impactor diameter, dropped-weight versus airgun-launched impactors, and the effect of the location of the impact site with respect to the panel boundaries. Residual strength results of panels tested in compression after impact are presented and compared with results of panels that are subjected to a compressive preload prior to being impacted.

  15. Catalytic CO Oxidation over Au Nanoparticles Loaded Nanoporous Nickel Phosphate Composite

    Directory of Open Access Journals (Sweden)

    Xiaonan Leng

    2015-01-01

    Full Text Available Au/nickel phosphate-5 (Au/VSB-5 composite with the noble metal loading amount of 1.43 wt.% is prepared by using microporous VSB-5 nanocrystals as the support. Carbon monoxide (CO oxidation reaction is carried out over the sample with several catalytic cycles. Complete conversion of CO is achieved at 238°C over the catalyst at the first catalytic cycle. The catalytic activity improved greatly at the second cycle with the complete conversion fulfilled at 198°C and preserved for the other cycles. A series of experiments such as X-ray diffraction (XRD, high resolution transmission electron microscopy (HRTEM, ultraviolet-visible (UV-vis spectroscopy, and X-ray photoelectron spectroscopy (XPS are carried out to characterize the catalysts before and after the reaction to study the factors influencing this promotion at the second cycle.

  16. Buckling analysis of rectangular composite plates with rectangular cutout subjected to linearly varying in-plane loading using fem

    Indian Academy of Sciences (India)

    A Lakshmi Narayana; Krishnamohana Rao; R Vijaya Kumar

    2014-06-01

    A numerical study is carried out using finite element method, to examine the effects of square and rectangular cutout on the buckling behavior of a sixteen ply quasi-isotropic graphite/epoxy symmetrically laminated rectangular composite plate $[0^\\circ /+45^\\circ /-45^\\circ /90^\\circ ]_{2s}$, subjected to various linearly varying in-plane compressive loads. Further, this paper addresses the effects of size of square/rectangular cutout, orientation of square/rectangular cutout, plate aspect ratio(a/b), plate length/thickness ratio(a/t), boundary conditions on the buckling bahaviour of symmetrically laminated rectangular composite plates subjected to various linearly varying in-plane compressive loading. It is observed that the various linearly varying in-plane loads and boundary conditions have a substantial influence on buckling strength of rectangular composite plate with square/rectangular cutout.

  17. Numerical and experimental analysis on load sharing & optimization of the joint parameters of polymer composite multi bolted joints

    Science.gov (United States)

    Latha Shankar, B.; Sudeep Kumar, T.; Shiva Shankar, G. S.

    2016-09-01

    In the present work, the bearing failure of composite bolted connections of composite laminates was analysed both experimentally and numerically. The glass fiber woven mat 600GSM/ epoxy composite laminates were prepared using wet-layup technique. The process parameters were taken care during preparation of laminates. Examination is done for various estimations of edge-to-hole diameter and width-to-hole diameter proportion. Stress is evaluated in laminates by utilizing Hart-Smith criteria. Ideal estimation of e/d proportion, d/w proportion is recommended for most extreme effectiveness. A numerical technique is utilized for the rough determination of a load shared by bolts in a numerous "bolted" joints loaded in tension were investigated experimentally and numerically. The effect of un-evenness in load shearing is suggested.

  18. Mechanical Behavior of Liquid Route Processed SiCf/Ti Composites Under Longitudinal and Transverse Loadings

    Science.gov (United States)

    Valle, Roger; Daux, Jean-Claude

    2017-02-01

    Due to the high melting point and strong chemical reactivity of titanium alloys, titanium matrix composites (TMCs) are usually processed through solid-state routes such as the foil-fiber-foil technique. An alternative method consists in the deposition of the matrix on the fibers. However, techniques such as physical vapor deposition lead to a very low deposition rate, contrary to liquid route processing using a levitating liquid alloy sphere held in a cold crucible. In order to investigate the effects of the resulting thermal shock on carbon-coated SiC fibers, and select an appropriate fiber, fibers are subjected to a pure thermal shock using a laser bench facility. These fibers are then tensile tested to failure in order to evaluate the resulting fiber strength degradation and, thus, the maximum acceptable temperature. Mechanical characterization of the liquid route processed TMC is then investigated through longitudinal and transverse tensile and creep tests at temperatures representative of aeronautical applications. The specimens, unbroken after long-duration creep tests, are then subjected to tensile loading to failure: conditions representative of service, i.e., short-time overspeeding of a gas turbine. Finally, interpretation of the mechanical tests through micrographical and microfractographical examinations is focused on the identification of the deformation and failure mechanisms specific to the liquid route processed composite, e.g., nucleation, under either longitudinal or transverse loadings, of internal cracks in the α-phase of the titanium-based matrix, explained through a physical model involving a high shear stress and normal stress combination, leading to cleavage.

  19. Mechanical Behavior of Liquid Route Processed SiCf/Ti Composites Under Longitudinal and Transverse Loadings

    Science.gov (United States)

    Valle, Roger; Daux, Jean-Claude

    2016-11-01

    Due to the high melting point and strong chemical reactivity of titanium alloys, titanium matrix composites (TMCs) are usually processed through solid-state routes such as the foil-fiber-foil technique. An alternative method consists in the deposition of the matrix on the fibers. However, techniques such as physical vapor deposition lead to a very low deposition rate, contrary to liquid route processing using a levitating liquid alloy sphere held in a cold crucible. In order to investigate the effects of the resulting thermal shock on carbon-coated SiC fibers, and select an appropriate fiber, fibers are subjected to a pure thermal shock using a laser bench facility. These fibers are then tensile tested to failure in order to evaluate the resulting fiber strength degradation and, thus, the maximum acceptable temperature. Mechanical characterization of the liquid route processed TMC is then investigated through longitudinal and transverse tensile and creep tests at temperatures representative of aeronautical applications. The specimens, unbroken after long-duration creep tests, are then subjected to tensile loading to failure: conditions representative of service, i.e., short-time overspeeding of a gas turbine. Finally, interpretation of the mechanical tests through micrographical and microfractographical examinations is focused on the identification of the deformation and failure mechanisms specific to the liquid route processed composite, e.g., nucleation, under either longitudinal or transverse loadings, of internal cracks in the α-phase of the titanium-based matrix, explained through a physical model involving a high shear stress and normal stress combination, leading to cleavage.

  20. Numerical modeling of mechanical behavior of multilayered composite plates with defects under static loading

    Science.gov (United States)

    Korepanov, V. V.; Serovaev, G. S.

    2017-06-01

    Evaluation of the mechanical state of a structure or its components in the process of operation based on detection of internal damages (damage detection) becomes especially important in such rapidly developing spheres of production as machine building, aerospace industry, etc. One of the most important features of these industries is the application of new types of materials among which polymer based composite materials occupy a significant position. Hence, they must have sufficient operational rigidity and strength. However, defects of various kinds may arise during the manufacture. Delamination is the most common defect in structures made from composite materials and represents a phenomenon that involves the complex fracture of layers and interlayer compounds. Among the reasons of delamination occurrence are: disposition of anti-adhesive lubricants, films; insufficient content of binder, high content of volatile elements; violation of the molding regime; poor quality of anti-adhesive coating on the surface of the tooling. One of the effective methods for analyzing the influence of defects is numerical simulation. With the help of numerical methods, it is possible to track the evolution of various parameters when the defect size and quantity change. In the paper, a multilayered plate of an equally resistant carbon fiber reinforced plastic was considered, with a thickness of each layer equal to 0.2 mm. Various static loading cases are studied: uniaxial tension, three and four-point bending. For each type of loading, a numerical calculation of the stress-strain state was performed for healthy and delaminated plates, with different number and size of the defects. Contact interaction between adjacent surfaces in the zone of delamination was taken into account.

  1. Electrochemical regeneration of a reduced graphene oxide/magnetite composite adsorbent loaded with methylene blue.

    Science.gov (United States)

    Sharif, Farbod; Gagnon, Luke R; Mulmi, Suresh; Roberts, Edward P L

    2017-05-01

    In this work, two different reduced graphene oxide/iron oxide (rGO-IO) nanocomposites with different iron oxide loadings were fabricated using a one-step solvothermal method. The structure, properties and applications of the synthesized nanocomposites were evaluated with Raman spectroscopy, attenuated total reflectance Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, electron microscopy, and energy-dispersive X-ray spectroscopy. The iron oxide is in the form of magnetite (Fe3O4), so that the resultant adsorbent can readily be separated from the treated water using a magnetic field. The ability of the nanocomposites to remove methylene blue (MB) from water by adsorption was investigated. The highest adsorptive capacity observed was 39 mg g(-1), for the composite containing 60 wt% iron oxide. The adsorptive capacity of the rGO-IO decreased to 26 mg g(-1) when the mass fraction of iron oxide was increased to 75 wt%. Electrochemical regeneration of MB loaded rGO-IO was also investigated. The electrochemical regeneration was found to be rapid and with low electrical energy consumption relative to conventional adsorbents, due to the high electrical conductivity and nonporous surface of the rGO. A regeneration efficiency of 100% was obtained after 30 min of electrochemical treatment using a 2 mm thick bed of rGO-IO loaded with 39 mg g(-1) MB, using a current density of 10 mA cm(-2). Multiple adsorption-electrochemical regeneration cycles demonstrated that the surface of the rGO was modified leading to increase in the adsorptive capacity to around 80 mg g(-1) after the second regeneration cycle. The morphology of the rGO was observed to change significantly after electrochemical regeneration, suggesting that the rGO based adsorbent materials could only be used for a few cycles.

  2. G-CSF loaded nanofiber/nanoparticle composite coated with collagen promotes wound healing in vivo.

    Science.gov (United States)

    Tanha, Shima; Rafiee-Tehrani, Morteza; Abdollahi, Mohamad; Vakilian, Saeid; Esmaili, Zahra; Naraghi, Zahra Safaei; Seyedjafari, Ehsan; Javar, Hamid Akbari

    2017-10-01

    Sustained release of functional growth factors can be considered as a beneficial methodology for wound healing. In this study, recombinant human granulocyte colony-stimulating factor (G-CSF)-loaded chitosan nanoparticles were incorporated in Poly(ε-caprolactone) (PCL) nanofibers, followed by surface coating with collagen type I. Physical and mechanical properties of the PCL nanofibers containing G-CSF loaded chitosan nanoparticles PCL/NP(G-CSF) and in vivo performance for wound healing were investigated. G-CSF structural stability was evaluated through SDS_PAGE, reversed phase (RP) HPLC and size-exclusion chromatography, as well as circular dichroism. Nanofiber/nanoparticle composite scaffold was demonstrated to have appropriate mechanical properties as a wound dresser and a sustained release of functional G-CSF. The PCL/NP(G-CSF) scaffold showed a suitable proliferation and well-adherent morphology of stem cells. In vivo study and histopathological evaluation outcome revealed that skin regeneration was dramatically accelerated under PCL/NP(G-CSF) as compared with control groups. Superior fibroblast maturation, enhanced collagen deposition and minimum inflammatory cells were also the beneficial properties of PCL/NP(G-CSF) over the commercial dressing. The synergistic effect of extracellular matrix-mimicking nanofibrous membrane and G-CSF could develop a suitable supportive substrate in order to extensive utilization for the healing of skin wounds. © 2017 Wiley Periodicals Inc. J Biomed Mater Res Part A: 105A: 2830-2842, 2017. © 2017 Wiley Periodicals, Inc.

  3. Effect of core density on deformation and failure in sandwich composites subjected to underwater impulsive loads

    Directory of Open Access Journals (Sweden)

    S Avachat

    2016-09-01

    Full Text Available The response of sandwich structures to underwater blast loading is analyzed. The analysis focuses on the effect of varying structural attributes on energy dissipation and deformation. The structures analyzed are simply-supported sandwich structures with PVC foam cores and fiber-reinforced polymer composite facesheets. For the analysis carried out, the material properties of the sandwich cores are varied and the total mass is kept constant. In conjunction with experiments, simulations account for underwater blast loading on structures in air-backed and water-backed conditions. Core crushing is accounted for through the Deshpande and Fleck model and facesheet failure is accounted for using the Hashin damage model. Results reveal a significant difference between the response of air-backed and water-backed/submerged structures. In general, thick and low-density cores provide superior blast mitigation and failure resistance. Scaling relations are developed to quantify the responses. These relations can be used to optimize the design of sandwich structures in critical parts of ships like keel, turbine-blades and rudders which involve different contact conditions with water.

  4. Modeling Delamination in Postbuckled Composite Structures Under Static and Fatigue Loads

    Science.gov (United States)

    Bisagni, Chiara; Brambilla, Pietro; Bavila, Carlos G.

    2013-01-01

    The ability of the Abaqus progressive Virtual Crack Closure Technique (VCCT) to model delamination in composite structures was investigated for static, postbuckling, and fatigue loads. Preliminary evaluations were performed using simple Double Cantilever Beam (DCB) and Mixed-Mode Bending (MMB) specimens. The nodal release sequences that describe the propagation of the delamination front were investigated. The effect of using a sudden or a gradual nodal release was evaluated by considering meshes aligned with the crack front as well as misaligned meshes. Fatigue simulations were then performed using the Direct Cyclic Fatigue (DCF) algorithm. It was found that in specimens such as the DCB, which are characterized by a nearly linear response and a pure fracture mode, the algorithm correctly predicts the Paris Law rate of propagation. However, the Abaqus DCF algorithm does not consider different fatigue propagation laws in different fracture modes. Finally, skin/stiffener debonding was studied in an aircraft fuselage subcomponent in which debonding occurs deep into post-buckling deformation. VCCT was shown to be a robust tool for estimating the onset propagation. However, difficulties were found with the ability of the current implementation of the Abaqus progressive VCCT to predict delamination propagation within structures subjected to postbuckling deformations or fatigue loads.

  5. The effects of fiber length and fiber loading on the mechanical properties of wood-plastic (polypropylene) composites

    OpenAIRE

    BASIJI, Farshid; SAFDARI, Vahidreza; NOURBAKHSH, Amir; Pilla, Srikanth

    2014-01-01

    This study examined the effects of wood pulp fiber length (short, medium, and long), and fiber loading (27%, 37%, 47%, and 0% [non-reinforced PP]) with 3% maleic anhydride-grafted polypropylene on the mechanical properties of wood-plastic composites (WPCs). Polypropylene and fibers were compounded into pellets using a counter-rotating twin-screw extruder and test specimens were prepared by injection molding. The results show that increases in fiber length and fiber loading significantly incre...

  6. Effect of loading weight on bond durability of composite-type resin cement under cyclic impact test (part 2). Loading with light weight of 100-120 g.

    Science.gov (United States)

    Ohsawa, Masahiro; Fujiwara, Mamoru; Hayashi, Yoshihiko

    2009-03-01

    The bond durability of composite-type resin cement was evaluated by means of cyclic impact tests using three different loads. In terms of experimental setup, a casting alloy, 12% Au-Pd-Ag, was used as the adherend and bonded to a cast block using a composite-type cement (Bistite II). A shear load--using plungers of three different weights at 100, 110, and 120 g--was dropped from a 3-mm height onto a small piece of the casting alloy until debonding. The cycle numbers that caused debonding were 1756 +/- 680 x 10(4) times for 100 g, 1403 +/- 515 x 10(4) times for 110 g, and 420 +/- 200 x 10(4) times for 120 g, respectively. Therefore, the group loaded with 120 g showed a significantly lower value as compared to the other two groups. On the fracture mode of the cement, it was a bulk fracture regardless of the loading weight employed in this study--the same result obtained in a previous study where heavier weights were employed.

  7. 40 CFR 721.2805 - Acrylate ester.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Acrylate ester. 721.2805 Section 721... Acrylate ester. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as an acrylate ester (PMN P-96-824) is subject to reporting under...

  8. Isobornyl acrylate contact allergy: Rare or underdiagnosed?

    NARCIS (Netherlands)

    Christoffers, W.A.; Coenraads, P.J.; Schuttelaar, M.L.A.

    2012-01-01

    Background: Allergic contact dermatitis to isobornyl acrylate has been reported in only two cases in literature. Therefore, isobornyl acrylate is not part of a (meth) acrylates patch test series. At our department an industrial worker presented with therapy-resistant hand eczema and sensitizations f

  9. Loading and composite restoration assessment of various non-carious cervical lesions morphologies - 3D finite element analysis.

    Science.gov (United States)

    Soares, P V; Machado, A C; Zeola, L F; Souza, P G; Galvão, A M; Montes, T C; Pereira, A G; Reis, B R; Coleman, T A; Grippo, J O

    2015-09-01

    The present study analysed the effects of different occlusal loading on premolars displaying various non-carious cervical lesions morphologies, restored (or not) with composites, by 3D finite element analysis. A three-dimensional digital model of a maxillary premolar was generated using CAD software. Three non-carious cervical lesions morphological types were simulated: wedged-shaped, saucer and mixed. All virtual models underwent three loading types (100 N): vertical, buccal and palatal loading. The simulated non-carious cervical lesions morphologies were analysed with and without restorations to consider specific regions, such as the occlusal and gingival walls as well as the depth of the lesions. Data summarizing the stress distribution were obtained in MPa using Maximum Principal Stress. Palatal loads were responsible for providing the highest values of accumulated tensile stress on the buccal wall; 27.66 MPa and 25.76 MPa for mixed and wedged-shaped morphologies, respectively. The highest tensile values found on non-carious cervical lesions morphologies restored with composite resin were 5.9 MPa in the mixed morphology, similar to those found on sound models despite their morphologies and occlusal loading. The various non-carious cervical lesions morphologies had little effect on stress distribution patterns, whereas the loading type and presence of composite restorations influenced the biomechanical behaviour of the maxillary premolars. © 2015 Australian Dental Association.

  10. Influence of load on sliding tribology of C/C composite with 40Cr steel couple coated by Cr

    Institute of Scientific and Technical Information of China (English)

    GE Yi-cheng; YI Mao-zhong; LI Li-ya

    2007-01-01

    With the 40Cr steel couple coated by Cr, the sliding tribology behavior of two kinds of C/C composites with different matrix was tested using a M2000 wear tester. The results show that with the increasing of load, the friction coefficients of the composite with resin carbon matrix(RC) decrease quickly from 0.156 under 60 N to 0.123 under 150 N, while those of the composite with rough lamination/smooth lamination /resin carbon (RL/SL/RC) change only between 0.122 and 0.101. The wear volume loss of the two composites increases except for under 100 N. The SEM morphology shows that with the increasing of load, the worn surface of the composite with RC becomes more and more integrated while the size of the debris becomes less and less. The Raman spectrum shows that the graphitization on the worn surface of the fibers draws down after 100 N, the graphitization of the boundary between the fiber and the matrix carbon rises up to 150 N, but the graphitization of the matrix carbon draws down all the while. With the increasing of load, the graphitization on the worn surface of all the worn areas becomes closer and closer, which indicates the worn surface of the different component has the similar friction ability. The composites with RL/SL/RC have better tribological characteristic than the composite with RC.

  11. Physical properties, chemical composition, and cloud forming potential of particulate emissions from a marine diesel engine at various load conditions.

    Science.gov (United States)

    Petzold, A; Weingartner, E; Hasselbach, J; Lauer, P; Kurok, C; Fleischer, F

    2010-05-15

    Particulate matter (PM) emissions from one serial 4-stroke medium-speed marine diesel engine were measured for load conditions from 10% to 110% in test rig studies using heavy fuel oil (HFO). Testing the engine across its entire load range permitted the scaling of exhaust PM properties with load. Emission factors for particle number, particle mass, and chemical compounds were determined. The potential of particles to form cloud droplets (cloud condensation nuclei, CCN) was calculated from chemical composition and particle size. Number emission factors are (3.43 +/- 1.26) x 10(16) (kg fuel)(-1) at 85-110% load and (1.06 +/- 0.10) x 10(16) (kg fuel)(-1) at 10% load. CCN emission factors of 1-6 x 10(14) (kg fuel)(-1) are at the lower bound of data reported in the literature. From combined thermal and optical methods, black carbon (BC) emission factors of 40-60 mg/(kg fuel) were determined for 85-100% load and 370 mg/(kg fuel) for 10% load. The engine load dependence of the conversion efficiency for fuel sulfur into sulfate of (1.08 +/- 0.15)% at engine idle to (3.85 +/- 0.41)% at cruise may serve as input to global emission calculations for various load conditions.

  12. The Smart Behavior of Cement-based Composite Containing Carbon Fibers under Three-point-bending Load

    Institute of Scientific and Technical Information of China (English)

    CHEN Bing; WU Keru; YAO Wu

    2005-01-01

    The influences of the fiber volume fraction on the electrical conductivity and the fraction change of electrical resistance under three-point- bending test were discussed. It is found that the relationship between the electrical conductivity of composites and the fiber volume fraction can be explained by the percolation theory and the change of electrical resistance of specimens reflects to the process of loading. The sensitivity and the response of the change of electrical resistance to the load for specimens with different fiber volume fractions are quite different,which provide an important guide for the manufacture of conductive and intrinsically smart carbon fiber composite.

  13. Ultrasonic velocities, densities, and excess molar volumes of binary mixtures of N,N-dimethyl formamide with methyl acrylate, or ethyl acrylate, or butyl acrylate, or 2-ethyl hexyl acrylate at T = 308.15 K

    Energy Technology Data Exchange (ETDEWEB)

    Kondaiah, M. [Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar 522510, Andhra Pradesh (India); Sravana Kumar, D. [Dr. V.S. Krishna Govt. Degree College, Visakhapatnam, Andhra Pradesh (India); Sreekanth, K. [Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar 522510, Andhra Pradesh (India); Krishna Rao, D., E-mail: krdhanekula@yahoo.co.in [Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar 522510, Andhra Pradesh (India)

    2011-12-15

    Highlights: > Positive values of V{sub m}{sup E}, indicate dispersion forces between acrylic esters and DMF. > V{sub m}{sup E} values compared with Redlich-Kister polynomial. > Partial molar volumes data conclude that weak interactions exist in the systems. > Measured velocity values compared with theoretical values obtained by polynomials. - Abstract: Ultrasonic velocities, u, densities, {rho}, of binary mixtures of N,N-dimethyl formamide (DMF) with methyl acrylate (MA), ethyl acrylate (EA), butyl acrylate (BA), and 2-ethyl hexyl acrylate (EHA), including pure liquids, over the entire composition range have been measured at T = 308.15 K. Using the experimental results, the excess molar volume, V{sub m}{sup E}, partial molar volumes, V-bar {sub m,1}, V-bar{sub m,2}, and excess partial molar volumes, V-bar{sub m,1}{sup E}, V-bar{sub m,2}{sup E} have been calculated. Molecular interactions in the systems have been studied in the light of variation of excess values of calculated properties. The excess properties have been fitted to Redlich-Kister type polynomial and the corresponding standard deviations have been calculated. The positive values of V{sub m}{sup E} indicate the presence of dispersion forces between the DMF and acrylic ester molecules. Further theoretical values of sound velocity in the mixtures have been evaluated using various theories and have been compared with experimental sound velocities to verify the applicability of such theories to the systems studied. Theoretical ultrasonic velocity data have been used to study molecular interactions in the binary systems investigated.

  14. Research of the launch vehicle design made of composite materials under the aerodynamic, thermal and acoustic loadings

    Directory of Open Access Journals (Sweden)

    Davydovich Denis

    2017-01-01

    Full Text Available The experimental research of the carbon composite material sample of payload fairing half structural element was carried out under different types of loading. Mathematical and physical modeling of the sample loading using aerodynamic flow was conducted. Heat loading was researched by the method of a thermal analysis during which typical heat dots corresponding to the changes in the sample structure were determined. Ultrasonic influence on the sample characteristics was considered. As a result, the value of heat leak to the structure surface while moving in the atmospheric phase of the descent was determined.

  15. Correspondence Analysis of Soil around Micropile Composite Structures under Horizontal Load

    Directory of Open Access Journals (Sweden)

    Hai Shi

    2015-01-01

    Full Text Available The current approach, which is based on conformal transformation, is to map micropile holes in comparison with unit circle domain. The stress field of soil around a pile plane, as well as the plane strain solution to displacement field distribution, can be obtained by adopting complex variable functions of elastic mechanics. This paper proposes an approach based on Winkler Foundation Beam Model, with the assumption that the soil around the micropiles stemmed from a series of independent springs. The rigidity coefficient of the springs is to be obtained from the planar solution. Based on the deflection curve differential equation of Euler-Bernoulli beams, one can derive the pile deformation and internal force calculation method of micropile composite structures under horizontal load. In the end, we propose reinforcing highway landslides with micropile composite structure and conducting on-site pile pushing tests. The obtained results from the experiment were then compared with the theoretical approach. It has been indicated through validation analysis that the results obtained from the established theoretical approach display a reasonable degree of accuracy and reliability.

  16. Preparation and characterization of new nano-composite scaffolds loaded with vascular stents.

    Science.gov (United States)

    Xu, Hongzhen; Su, Jiansheng; Sun, Jun; Ren, Tianbin

    2012-01-01

    In this study, vascular stents were fabricated from poly (lactide-ɛ-caprolactone)/collagen/nano-hydroxyapatite (PLCL/Col/nHA) by electrospinning, and the surface morphology and breaking strength were observed or measured through scanning electron microscopy and tensile tests. The anti-clotting properties of stents were evaluated for anticoagulation surfaces modified by the electrostatic layer-by-layer self-assembly technique. In addition, nano-composite scaffolds of poly (lactic-co-glycolic acid)/polycaprolactone/nano-hydroxyapatite (PLGA/PCL/nHA) loaded with the vascular stents were prepared by thermoforming-particle leaching and their basic performance and osteogenesis were tested in vitro and in vivo. The results show that the PLCL/Col/nHA stents and PLGA/PCL/nHA nano-composite scaffolds had good surface structures, mechanical properties, biocompatibility and could guide bone regeneration. These may provide a new way to build vascularized-tissue engineered bone to repair large bone defects in bone tissue engineering.

  17. Dynamic response and modeling of a carbon fiber— epoxy composite subject to shock loading

    Science.gov (United States)

    Alexander, C. S.; Key, C. T.; Schumacher, S. C.

    2013-12-01

    Unidirectional carbon fiber reinforced epoxy composite samples were tested to determine their response to one dimensional shock loading with the ultimate goal of developing a micromechanics based numerical model of the dynamic response. The material tested had high fiber content (62-68% by volume) and low porosity. Wave speeds for shocks traveling along the carbon fibers are significantly higher than for those traveling transverse to the fibers or through the bulk epoxy. As a result, the dynamic material response is dependent on the relative shock—fiber orientation; a complication that must be captured in the numerical models. Shocks traveling transverse to the fibers show an inelastic response consistent with the material constituent parts. Shocks traveling along the fiber direction travel faster and exhibit both elastic and plastic characteristics over the stress range tested; up to 15 GPa. Results presented detail the anisotropic material response, which is governed by different mechanisms along each of the two principle directions in the composite. Finally, numerical modeling of this response is described in detail and validated against the experimental data.

  18. Effect of the organic loading rate on biogas composition in continuous fermentative hydrogen production.

    Science.gov (United States)

    Spagni, Alessandro; Casu, Stefania; Farina, Roberto

    2010-10-01

    Some systems did not select for hydrogen-producing microorganisms and an unexpected growth of hydrogenotrophic methanogens was observed, although the reactors were operated under well-defined operating conditions that could result in biohydrogen production. The aim of this study was to evaluate the effect of the organic loading rate (OLR) on the hydrogen and methane composition of the biogas produced in dark fermentative processes. The study was carried out using an upflow anaerobic sludge blanket (UASB) reactor in order to evaluate the OLR effect in systems with sludge retention. During continuous operation, the UASB reactor showed the slow development of methanogenic activity, related to the applied OLR. The results demonstrate that operating an UASB reactor at pH 5.5 is not enough to prevent the acclimation of methanogens to the acidic pH and therefore long-term biohydrogen production cannot be achieved. Moreover, this study demonstrates that OLR also has an effect on the biogas composition, where the higher the OLR the greater the biogas H2 content.

  19. Preparation and Characterization of New Nano-Composite Scaffolds Loaded With Vascular Stents

    Directory of Open Access Journals (Sweden)

    Tianbin Ren

    2012-03-01

    Full Text Available In this study, vascular stents were fabricated from poly (lactide-ε-caprolactone/collagen/nano-hydroxyapatite (PLCL/Col/nHA by electrospinning, and the surface morphology and breaking strength were observed or measured through scanning electron microscopy and tensile tests. The anti-clotting properties of stents were evaluated for anticoagulation surfaces modified by the electrostatic layer-by-layer self-assembly technique. In addition, nano-composite scaffolds of poly (lactic-co-glycolic acid/polycapr-olactone/nano-hydroxyapatite (PLGA/PCL/nHA loaded with the vascular stents were prepared by thermoforming-particle leaching and their basic performance and osteogenesis were tested in vitro and in vivo. The results show that the PLCL/Col/nHA stents and PLGA/PCL/nHA nano-composite scaffolds had good surface structures, mechanical properties, biocompatibility and could guide bone regeneration. These may provide a new way to build vascularized-tissue engineered bone to repair large bone defects in bone tissue engineering.

  20. Effects of load mode on mechanical properties of ZrO2(2Y)/TRIP steel composites

    Institute of Scientific and Technical Information of China (English)

    周玉; 郭英奎; 李冬波; 段小明

    2003-01-01

    The ZrO2 (2Y)/TRIP steel composites were prepared by vacuum hot-pressing sintering. The room temperature static tensile and dynamic yield strength were tested using the static tensile and Split Hopkinson Pressure Bar methods, respectively. The effects of load mode on the static and dynamic mechanical behaviors were studied. The results show that the static tensile strengths of the composites decrease with the increase of ZrO2 content, for the weak bonding of ZrO2/ZrO2. Under the dynamic load, the matrix TRIP steel produces the martinsitic phase transformation, which improves the dynamic strength and deformation ability of the composites. When the volume fraction of ZrO2 exceeds 20%, the strain-hardening coefficient and the dynamic deformation ability of the composites decrease.

  1. Composite bone cements loaded with a bioactive and ferrimagnetic glass-ceramic: Leaching, bioactivity and cytocompatibility

    Energy Technology Data Exchange (ETDEWEB)

    Verné, Enrica, E-mail: enrica.verne@polito.it [Institute of Materials Physics and Engineering, Applied Science and Technology Department, Politecnico di Torino, C. so Duca degli Abruzzi 24, 10129 Torino (Italy); Bruno, Matteo [Institute of Materials Physics and Engineering, Applied Science and Technology Department, Politecnico di Torino, C. so Duca degli Abruzzi 24, 10129 Torino (Italy); Miola, Marta [Institute of Materials Physics and Engineering, Applied Science and Technology Department, Politecnico di Torino, C. so Duca degli Abruzzi 24, 10129 Torino (Italy); Department of Health Sciences, Università del Piemonte Orientale “Amedeo Avogadro”, Via Solaroli 17, 28100 Novara (Italy); Maina, Giovanni; Bianco, Carlotta [Traumatology Orthopedics and Occupational Medicine Dept., Università di Torino, Via G. Zuretti 29, 10126 Torino (Italy); Cochis, Andrea [Department of Health Sciences, Università del Piemonte Orientale “Amedeo Avogadro”, Via Solaroli 17, 28100 Novara (Italy); Rimondini, Lia [Department of Health Sciences, Università del Piemonte Orientale “Amedeo Avogadro”, Via Solaroli 17, 28100 Novara (Italy); Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali, Via G. Giusti, 9, 50121 Firenze (Italy)

    2015-08-01

    In this work, composite bone cements, based on a commercial polymethylmethacrylate matrix (Palamed®) loaded with ferrimagnetic bioactive glass-ceramic particles (SC45), were produced and characterized in vitro. The ferrimagnetic bioactive glass-ceramic belongs to the system SiO{sub 2}–Na{sub 2}O–CaO–P{sub 2}O{sub 5}–FeO–Fe{sub 2}O{sub 3} and contains magnetite (Fe{sub 3}O{sub 4}) crystals into a residual amorphous bioactive phase. Three different formulations (containing 10, 15 and 20 wt.% of glass-ceramic particles respectively) have been investigated. These materials are intended to be applied as bone fillers for the hyperthermic treatment of bone tumors. The morphological, compositional, calorimetric and mechanical properties of each formulation have been already discussed in a previous paper. The in vitro properties of the composite bone cements described in the present paper are related to iron ion leaching test (by graphite furnace atomic absorption spectrometer), bioactivity (i.e. the ability to stimulate the formation of a hydroxyapatite – HAp – layer on their surface after soaking in simulated body fluid SBF) and cytocompatibility toward human osteosarcoma cells (ATCC CRL-1427, Mg63). Morphological and chemical characterizations by scanning electron microscopy and energy dispersion spectrometry have been performed on the composite samples after each test. The iron release was negligible and all the tested samples showed the growth of HAp on their surface after 28 days of immersion in a simulated body fluid (SBF). Cells showed good viability, morphology, adhesion, density and the ability to develop bridge-like structures on all investigated samples. A synergistic effect between bioactivity and cell mineralization was also evidenced. - Highlights: • An in vitro biological characterization was carried out on ferromagnetic and bioactive composite cements. • No release of iron was revealed in the physiological solution. • Bioactivity tests

  2. Biocompatibility of artificial bone based on vancomycin loaded mesoporous silica nanoparticles and calcium sulfate composites.

    Science.gov (United States)

    Gu, Jisheng; Wang, Teng; Fan, Guoxin; Ma, Junhua; Hu, Wei; Cai, Xiaobing

    2016-04-01

    The aim of this study was to evaluate the in vitro and in vivo biocompatibility of artificial bone based on vancomycin loaded mesoporous silica nanoparticles and calcium sulfate composites. In vitro cytotoxicity tests by cholecystokinin octapeptide (CCK-8) assay showed that the 5%Van-MSN-CaSO4 and Van-CaSO4 bone cements were cytocompatible for mouse osteoblastic cell line MC3T3-E1. The microscopic observation confirmed that MC3T3-E1cells incubated with Van-CaSO4 group and 5%Van-MSN-CaSO4 group exhibited clear spindle-shaped changes, volume increase and maturation, showing that these cements supported adhesion of osteoblastic cells on their surfaces. In addition, the measurement of alkaline phosphatase activity revealed the osteoconductive property of these biomaterials. In order to assess in vivo biocompatibility, synthesized cements were implanted into the distal femur of twelve adult male and female New Zealand rabbits. After implantation in artificial defects of the distal femur, 5%Van-MSN-CaSO4 and Van-CaSO4 bone cements did not damage the function of main organs of rabbits. In addition, the Van-MSN-CaSO4 composite allowed complete repair of bone defects with new bone formation 3 months after implantation. These results show potential application of Van-MSN-CaSO4 composites as bone graft materials for the treatment of open fracture in human due to its mechanical, osteoconductive and potential sustained drug release characteristics and the absence of adverse effects on the body.

  3. Delamination growth behavior in cross-ply composites under compressive cyclic (fatigue) loading

    Science.gov (United States)

    Pelegri, Assimina A.

    A mode dependent fatigue delamination growth law for anisotropic composite plates is presented in this thesis. The novelty of the presented law lies in the mode dependency of the material and laminate constants m(Psi) and C(Psi). The model describing the mode dependent delamination growth law consists of an initial postbuckling solution accounting for general delaminated composites, i.e. with no restrictive assumptions on the delamination dimensions, and a fracture mechanics solution. A numerical code was developed for the implementation of the closed form solution which gives the loading and geometrical quantities as well as the energy release rates and the mode mixities. The computer code was especially designed for parametric studies. Parameters assigned in this particular investigation were: end conditions, delamination position (h/T), and applied strain. The effect of the end conditions, i.e. clamped-clamped versus simply-supported ends on the initial postbuckling and growth behavior of delaminated plates was also investigated. In conjunction with the previous analysis, a detailed experimental study was designed and carried out in order to validate the proposed model. The tests were designed so that the effect of certain parameters on the delamination growth behavior could be evaluated. The parameters included in the investigation were: initial delamination length, applied strain and delamination position (h/T). Compressive static, compressive fatigue (constant displacement amplitude), and double cantilever beam (DCB) tests were conducted. Data acquisition and analysis for these tests were performed. By comparing analytical and experimental results it is shown that a very good correlation exists, and the presented mode dependent fatigue delamination growth law can accurately predict fatigue lives of delaminated composite structures.

  4. Field Testing and Load Rating Report for Bridge No. 4, Hybrid Composite Beam Span, at Fort Knox, Kentucky

    Science.gov (United States)

    2016-09-01

    metal guardrail as the military vehicles crossed the structure ; especially during the first tests run near the structure’s edges (Test Paths Y1 & Y3...were the first time these details were heavily loaded. In general, this type of behavior is common for newer structures and does not affect the...Composite Beams for Bridges for Project F12-AR15, “Corrosion-Resistant Hybrid Composite Bridge Beams for Structural Applications” Monitored by

  5. Interpreting the g loadings of intelligence test composite scores in light of Spearman's law of diminishing returns.

    Science.gov (United States)

    Reynolds, Matthew R

    2013-03-01

    The linear loadings of intelligence test composite scores on a general factor (g) have been investigated recently in factor analytic studies. Spearman's law of diminishing returns (SLODR), however, implies that the g loadings of test scores likely decrease in magnitude as g increases, or they are nonlinear. The purpose of this study was to (a) investigate whether the g loadings of composite scores from the Differential Ability Scales (2nd ed.) (DAS-II, C. D. Elliott, 2007a, Differential Ability Scales (2nd ed.). San Antonio, TX: Pearson) were nonlinear and (b) if they were nonlinear, to compare them with linear g loadings to demonstrate how SLODR alters the interpretation of these loadings. Linear and nonlinear confirmatory factor analysis (CFA) models were used to model Nonverbal Reasoning, Verbal Ability, Visual Spatial Ability, Working Memory, and Processing Speed composite scores in four age groups (5-6, 7-8, 9-13, and 14-17) from the DAS-II norming sample. The nonlinear CFA models provided better fit to the data than did the linear models. In support of SLODR, estimates obtained from the nonlinear CFAs indicated that g loadings decreased as g level increased. The nonlinear portion for the nonverbal reasoning loading, however, was not statistically significant across the age groups. Knowledge of general ability level informs composite score interpretation because g is less likely to produce differences, or is measured less, in those scores at higher g levels. One implication is that it may be more important to examine the pattern of specific abilities at higher general ability levels.

  6. SYNTHESIS OF SOAP-FREE ACRYLIC HYDROSOLS

    Institute of Scientific and Technical Information of China (English)

    Li Jia; Zong-hui Liu; De-qing Wei

    2002-01-01

    Poly(methyl methacrylate/ethyl acrylate/acrylic acid) hydrosols were prepared by employing soap-freepolymerization, and (acrylic acid/butyl acrylate) oligomer was used as the polymeric surfactant. The effect of reactioncondition on the morphology and particle size of the hydrosols was investigated. The minimum amount of acrylic acid in thehydrosols is 2%. The maximum weight average molecular weight (Mw) of polymer that assures soap-free emulsionconversion into hydrosol is about 1.2 × 105-1.3 × 105. The particle transforming process was investigated, and an obviouschange of particle diameter and morphology was observed.

  7. Conductivity of microfibrillar polymer-polymer composites with CNT-loaded microfibrils or compatibilizer: A comparative study

    Directory of Open Access Journals (Sweden)

    S. Fakirov

    2013-07-01

    Full Text Available Conductive polymer composites have wide ranging applications, but when they are produced by conventional melt blending, high conductive filler loadings are normally required, hindering their processability and reducing mechanical properties. In this study, two types of polymer-polymer composites were studied: i microfibrillar composites (MFC of polypropylene (PP and 5 wt% carbon nanotube (CNT loaded poly(butylene terephthalate (PBT as reinforcement, and ii maleic anhydride-grafted polypropylene (PP-g-MA compatibilizer, loaded with 5 wt% CNTs introduced into an MFC of PP and poly(ethylene terephthalate (PET in concentrations of 5 and 10 wt%. For the compatibilized composite type, PP and PET were melt-blended, cold-drawn and pelletized, followed by dry-mixing with PP-g-MA/CNT, re-extrusion at 200°C, and cold-drawing. The drawn blends produced were compression moulded to produce sheets with MFC structure. Using scanning electron microscopy, CNTs coated with PP-g-MA could be observed at the interface between PP matrix and PET microfibrils in the compatibilized blends. The volume resistivities tested by four-point test method were: 2.87•108 and 9.93•107 Ω•cm for the 66.5/28.5/5 and 63/27/10 (by wt% PP/PET/(PP-g-MA/CNT blends, corresponding to total CNT loadings (in the composites of 0.07 vol% (0.24 wt% and 0.14 vol% (0.46 wt%, respectively. For the non-compatibilized MFC types based on PP/(PBT/CNT with higher and lower melt flow grades of PP, the resistivities of 70/(95/5 blends were 1.9•106 and 1.5•107 Ω•cm, respectively, corresponding to a total filler loading (in the composite of 0.44 vol% (1.5 wt% in both MFCs.

  8. Effect of static and cyclic loading on ceramic laminate veneers adhered to teeth with and without aged composite restorations.

    Science.gov (United States)

    Gresnigt, Marco M; Ozcan, Mutlu; Kalk, Warner; Galhano, Graziela

    2011-12-01

    Existing composite restorations on teeth are often remade prior to the cementation of fixed dental prostheses. The aim of this study was to evaluate the effect of static and cyclic loading on ceramic laminate veneers adhered to aged resin composite restorations. Eighty sound maxillary incisors were collected and randomly divided into four groups: group 1: control group, no restorations; group 2: two Class III restorations; group 3: two Class IV restorations; group 4: complete composite substrate. Standard composite restorations were made using a microhybrid resin composite (Anterior Shine). Restored teeth were subjected to thermocycling (6000 cycles). Window preparations were made on the labial surface of the teeth for ceramic laminate fabrication (Empress II). Teeth were conditioned using an etch-and-rinse system. Existing composite restorations representing the aged composites were silica coated (CoJet) and silanized (ESPE-Sil). Ceramic laminates were cemented using a bis-GMA-based cement (Variolink Veneer). The specimens were randomly divided into two groups and were subjected to either static (groups 1a, 2a, 3a, 4a) or cyclic loading (groups 1b, 2b, 3b, 4b). Failure type and location after loading were classified. Data were analyzed using one-way ANOVA and Tukey's test. Significantly higher fracture strength was obtained in group 4 (330 ± 81 N) compared to the controls in group 1 (179 ± 120 N) (one-way ANOVA, p ceramic were seen. Ceramic laminate veneers bonded to conditioned aged composite restorations provided favorable results. Surface conditioning of existing restorations may eliminate the necessity of removing aged composite restorations.

  9. A Study on Response of a Contoured Composite Panel with Co-cured Stiffeners Under Transient Loading

    Science.gov (United States)

    Begum, Shahnaaz; Jain, Prakash Chand; Venkatesh, Siddu

    2016-07-01

    Composite materials are emerging to be the best applied materials for aerospace applications. With rapid improvement in computational facilities, it is now possible to design the best composite lay up for a particular kind of application. This paper presents the development of a Finite Element model of a contoured composite panel with co-cured stiffeners using Finite Element Simulation. Commercial package ANSYS 15.0 is used for this study. Such half contoured panels find wide application in Aerospace industry. The panel is hinged at one of the ends and dynamically loaded at the other end over a relatively small surface area by transverse load. The response of the panel is observed for variation in stresses, deflections and failure criteria. The panel is expected to rotate about the hinge point by 4° from the initial point. The transient response of the composite panel has been observed for expected load and two test load cases and results reported in this paper. Analysis has become useful input for the design of panel.

  10. Effect of Mechanical Loads and Surface Roughness on Wear of Silorane and Methacrylate-Based Posterior Composites

    Directory of Open Access Journals (Sweden)

    Masumeh Hasani Tabatabaei

    2017-01-01

    Full Text Available Objectives: Dental composite wear in posterior restorations is a concern and is affected by different factors. This study was conducted to evaluate the effect of polishing and mechanical loads on wear of silorane-based and methyl methacrylate-based composites resins.Materials and Methods: Of each dental composite (Filtek P90 and Filtek P60, 40 samples were fabricated in a polyethylene mold (4mm diameter, 10mm height. According to the finishing and/or polishing protocols (180-grit or 2500-grit silicon carbide papers, the samples of each composite were divided into two groups. Surface roughness (Rₔ was measured and recorded using a contact profilometer. The weight of each sample was also measured in grams. The wear test was performed in a pin-on-disc device under two different loads (70N, 150N. Afterwards, samples were subjected to profilometry and their weight was measured again. Data were analyzed using t-test and univariate ANOVA. P <0.05 was considered statistically significant.Results: Higher mechanical load resulted in greater weight loss (P<0.001. Samples polished with 2500-grit papers showed significantly lower Ra changes compared to those polished with 180-grit papers (P<0.001. Filtek P90 had greater weight loss than Filtek P60 except in one condition (180-grit, 70N.Conclusions: Results showed that wear of posterior composite restorations depends on mechanical load, type of composite resin and surface properties.Keywords: Dental Restoration Wear; Surface Properties; Silorane Composite Resin

  11. Characterization of unidirectional carbon fiber reinforced polyamide-6 thermoplastic composite under longitudinal compression loading at high strain rate

    Science.gov (United States)

    Ploeckl, Marina; Kuhn, Peter; Koerber, Hannes

    2015-09-01

    In the presented work, an experimental investigation has been performed to characterize the strain rate dependency of unidirectional carbon fiber reinforced polyamide-6 composite for longitudinal compression loading. An end-loaded compression specimen geometry, suitable for contactless optical strain measurement via digital image correlation and dynamic loading in a split-Hopkinson pressure bar, was developed. For the dynamic experiments at a constant strain rate of 100 s-1 a modified version of the Dynamic Compression Fixture, developed by Koerber and Camanho [Koerber and Camanho, Composites Part A, 42, 462-470, 2011] was used. The results were compared with quasi-static test results at a strain rate of 3 · 10-4 s-1 using the same specimen geometry. It was found that the longitudinal compressive strength increased by 61% compared to the strength value obtained from the quasi-static tests.

  12. Design and characterization of a composite material based on Sr(II)-loaded clay nanotubes included within a biopolymer matrix.

    Science.gov (United States)

    Del Buffa, Stefano; Bonini, Massimo; Ridi, Francesca; Severi, Mirko; Losi, Paola; Volpi, Silvia; Al Kayal, Tamer; Soldani, Giorgio; Baglioni, Piero

    2015-06-15

    This paper reports on the preparation, characterization, and cytotoxicity of a hybrid nanocomposite material made of Sr(II)-loaded Halloysite nanotubes included within a biopolymer (3-polyhydroxybutyrate-co-3-hydroxyvalerate) matrix. The Sr(II)-loaded inorganic scaffold is intended to provide mechanical resistance, multi-scale porosity, and to favor the in-situ regeneration of bone tissue thanks to its biocompatibility and bioactivity. The interaction of the hybrid system with the physiological environment is mediated by the biopolymer coating, which acts as a binder, as well as a diffusional barrier to the Sr(II) release. The degradation of the polymer progressively leads to the exposure of the Sr(II)-loaded Halloysite scaffold, tuning its interaction with osteogenic cells. The in vitro biocompatibility of the composite was demonstrated by cytotoxicity tests on L929 fibroblast cells. The results indicate that this composite material could be of interest for multiple strategies in the field of bone tissue engineering.

  13. Levofloxacin loaded mesoporous silica microspheres/nano-hydroxyapatite/polyurethane composite scaffold for the treatment of chronic osteomyelitis with bone defects.

    Science.gov (United States)

    Wang, Qi; Chen, Cheng; Liu, Wen; He, Xiaoqiang; Zhou, Nian; Zhang, Dongli; Gu, Hongchen; Li, Jidong; Jiang, Jiaxing; Huang, Wei

    2017-02-02

    Chronic osteomyelitis is a prolonged persistent disease accompanied by bone destruction and sequestrum formation, it is very difficult to treat. Antibiotic loaded polymethyl methacrylate (PMMA) has been used in clinical. However, when PMMA was implanted in the body, the deficiencies is that it is non-biodegradable and a second operation is needed. Here, we synthesize a novel levofloxacin loaded mesoporous silica microspheres/nano-hydroxyapatite/polyurethane composite scaffolds, and evaluated the therapeutic effect in treating chronic osteomyelitis with bone defects in rabbit model compared with bulk PMMA. X-ray, Micro CT, gross pathology as well as immunohistochemical staining were performed at predesignated time points (1, 3, 6 and 12 weeks). Our results demonstrated that the efficiency of mesoporous silica microspheres/nano-hydroxyapatite/polyurethane composite scaffolds loaded with 5 mg levofloxacin was much better at treating bone defects than the other groups. This novel synthetic scaffold may provide a solution for the treatment of chronic osteomyelitis.

  14. Levofloxacin loaded mesoporous silica microspheres/nano-hydroxyapatite/polyurethane composite scaffold for the treatment of chronic osteomyelitis with bone defects

    Science.gov (United States)

    Wang, Qi; Chen, Cheng; Liu, Wen; He, Xiaoqiang; Zhou, Nian; Zhang, Dongli; Gu, Hongchen; Li, Jidong; Jiang, Jiaxing; Huang, Wei

    2017-01-01

    Chronic osteomyelitis is a prolonged persistent disease accompanied by bone destruction and sequestrum formation, it is very difficult to treat. Antibiotic loaded polymethyl methacrylate (PMMA) has been used in clinical. However, when PMMA was implanted in the body, the deficiencies is that it is non-biodegradable and a second operation is needed. Here, we synthesize a novel levofloxacin loaded mesoporous silica microspheres/nano-hydroxyapatite/polyurethane composite scaffolds, and evaluated the therapeutic effect in treating chronic osteomyelitis with bone defects in rabbit model compared with bulk PMMA. X-ray, Micro CT, gross pathology as well as immunohistochemical staining were performed at predesignated time points (1, 3, 6 and 12 weeks). Our results demonstrated that the efficiency of mesoporous silica microspheres/nano-hydroxyapatite/polyurethane composite scaffolds loaded with 5 mg levofloxacin was much better at treating bone defects than the other groups. This novel synthetic scaffold may provide a solution for the treatment of chronic osteomyelitis. PMID:28150731

  15. Effect of post-polymerization heat treatments on the cytotoxicity of two denture base acrylic resins

    OpenAIRE

    Janaina Habib Jorge; Eunice Teresinha Giampaolo; Carlos Eduardo Vergani; Ana Lúcia Machado; Ana Cláudia Pavarina; Iracilda Zeppone Carlos

    2006-01-01

    INTRODUCTION: Most denture base acrylic resins have polymethylmethacrylate in their composition. Several authors have discussed the polymerization process involved in converting monomer into polymer because adequate polymerization is a crucial factor in optimizing the physical properties and biocompatibility of denture base acrylic resins. To ensure the safety of these materials, in vitro cytotoxicity assays have been developed as preliminary screening tests to evaluate material biocompatibil...

  16. Preparation and Property of Acrylic Acid Rare Earth Complex and Its Hydrosilylation

    Institute of Scientific and Technical Information of China (English)

    Zhang Ming; Chen Haiyan; Chen Xiaosong; Dai Shaojun; Inoue Shinich; Okamoto Hiroshi

    2004-01-01

    Acrylic acid rare earth complex was prepared. Its chemical composition was determined by chemical and elemental analysis, and its structure as well as properties was characterized using IR, Fluorescence and UV spectrum, and its solubility was also investigated. Meanwhile a kind of elastic functional polymer with rare earth units in the side chains was produced. It is confirmed by IR spectrum that the Si-H bonds really react with acrylic acid rare earth.

  17. Dexamethasone-loaded poly(ε-caprolactone)/silica nanoparticles composites prepared by supercritical CO2 foaming/mixing and deposition.

    Science.gov (United States)

    de Matos, M B C; Piedade, A P; Alvarez-Lorenzo, C; Concheiro, A; Braga, M E M; de Sousa, H C

    2013-11-18

    A supercritical carbon dioxide (scCO2)-assisted foaming/mixing method (SFM) was implemented for preparing dexamethasone (DXMT)-loaded poly(ε-caprolactone)/silica nanoparticles (PCL/SNPs) composite materials suitable for bone regeneration. The composites were prepared from PCL and mesoporous SNPs (MCM-41/SBA-15) by means of scCO2-assisted SFM at several operational pressures, processing times and depressurization conditions. DXMT was loaded into SNPs (applying a scCO2 solvent impregnation/deposition method - SSID) and into PCL/SNPs composites (using the SFM method). The effects of the employed operational and compositional variables on the physicochemical and morphological features as well as in the in vitro release profiles of DXMT were analyzed in detail. This work demonstrates that the above-referred scCO2-based methods can be very useful for the preparation of DXMT-loaded PCL/SNPs composites with tunable physicochemical, thermomechanical, morphological and drug release properties and suitable for hard-tissue regeneration applications.

  18. Influence of lipid composition and drug load on the in vitro performance of self-nanoemulsifying drug delivery systems

    DEFF Research Database (Denmark)

    Thomas, Nicky; Müllertz, Anette; Graf, Anja

    2012-01-01

    size of dispersed medium-chain (MC)-SNEDDS based on the surfactant Cremophor RH40 was not affected by increasing drug loads of SIM, whereas the droplet size of the corresponding long-chain (LC)-SNEDDS increased. During 60 min in vitro lipolysis, MC-SNEDDS maintained approximately 95% of SIM in solution......, surfactant, and cosolvent but varied in the chain length of the lipid component. Utilization of the surfactant Cremophor EL resulted in pronounced changes in the droplet size of dispersed SNEDDS containing increasing drug loads of the poorly water-soluble compound simvastatin (SIM). In contrast, the droplet......, independent of the drug load. At the start of lipolysis of LC-SNEDDS, up to 34% of the drug precipitated. However, the initial precipitate dissolved in the lipolysis medium 30 min after start of in vitro lipolysis. The study suggests that drug load and lipid composition should be considered for the design...

  19. An Experimental Study of a Stitched Composite with a Notch Subjected to Combined Bending and Tension Loading

    Science.gov (United States)

    Palmer, Susan O.; Nettles, Alan T.; Poe, C. C., Jr.

    1999-01-01

    A series of tests was conducted to measure the strength of stitched carbon/epoxy composites containing through-thickness damage in the form of a crack-like notch. The specimens were subjected to three types of loading: pure bending, pure tension, and combined bending and tension loads. Measurements of applied loads, strains near crack tips, and crack opening displacements (COD) were monitored in all tests. The transverse displacement at the center of the specimen was measured using a Linear Variable Differential Transformer (LVDT). The experimental data showed that the outer surface of the pure tension specimen failed at approximately 6,000 microstrain, while in combined bending and tension loads the measured tensile strains reached 10,000 microstrain.

  20. Comparative Evaluation Of Reinforced Concrete, Steel And Composite Structures Under The Effect Of Static And Dynamic Loads

    Directory of Open Access Journals (Sweden)

    Zafar Mujawar

    2015-01-01

    Full Text Available Steel-concrete composite construction has gained wide acceptance all over the world as an alternative for pure steel and pure concrete construction. However this approach is a new concept for construction industry. R.C.C are no longer economical because of their increased dead load, hazardous formwork. The present study deals with comparison of reinforced concrete, steel and composite structures under the effect of static and dynamic loads. The results of this work show that composite structures are best suited for high rise buildings compared to that of steel and reinforced concrete structures. Response spectrum method is used for comparison of three structures with the help of ETABS software.

  1. The Estimation of Total Nitrogen and Phosphorus Outflow Loads from Kahokugata Watersheds, Ishikawa Prefecture, Using Composite Reservoir Model

    Science.gov (United States)

    Takimoto, Hiroshi; Murashima, Kazuo; Hashimoto, Iwao; Maruyama, Toshisuke

    The amounts of the outflow loads of nitrogen and phosphorus from the Kahokugata watersheds were estimated, and measures for the pollution load reduction were examined. Composite reservoir model was used to estimate the runoff discharge from watersheds. Parameter of the composite tank model was determined by the discharge and N and P observation data of Omiya river which was small one located in Kahokugata basin. Simulation results show the good fitting of the curve representing between observed and calculated discharge. Amounts of the outflow loads of total nitrogen(T-N) and total phosphorus(T-P) were estimated by using two methods, one was the pollutant load factors of paddy, upland, forest and urban area and the other method was L(load)and Q (discharge)relation method. Based upon the loading estimates from 1998 to 2002, Kahokugata basin received approximately 678 t year-1 of T-N and 92.2 t year-1 of T-P by former method and 661 t year-1 of T-N and 31 t year-1 by the latter method. It was clear that the land use of domestic, agriculture and forest contributed to the pollution. Moreover, about the total nitrogen loads, the load factor method and LQ equation method were compared on the forest watersheds and lowland areas. A high correlation was obtained between the both methods in the forest watersheds, but the result of lowland areas was not so good. As consideration, the effect of nitrogen pollutant reduction by repeating use of irrigation water at the forest watersheds was examined.

  2. Damage evolution of composite structures at low speeds under the effect of the number of folds and impact loads

    Directory of Open Access Journals (Sweden)

    Saad Mohamed

    2016-07-01

    Full Text Available Composite materials currently occupy an important place in all industrial sectors their sensitivity to the same impacts at low velocity raises some preoccupations to limit their scope .On the basis of a numerical simulation, the code of calculation Abaqus 6.14, was used to simulate the impact behavior to predict the damage to the fibers and the matrix of the composite structures subjected to any impact. This work deals with the evolution of the damage on the individual layers of a plate composite graphite / epoxy laminated [0m / 90n ] s composite under dynamic loading effect different velocity of the impactor and the evolution of the deformation energy as a result of different speeds of impact and the various layers of the composite structure.

  3. Failure Test and Finite Element Simulation of a Large Wind Turbine Composite Blade under Static Loading

    Directory of Open Access Journals (Sweden)

    Xiao Chen

    2014-04-01

    Full Text Available This study presented a failure analysis of a 52.3 m composite wind turbine blade under static loading. Complex failure characteristics exhibited at the transition region of the blade were thoroughly examined and typical failure modes were indentified. In order to predict multiple failure modes observed in the tests and gain more insights into the failure mechanisms of the blade, a Finite Element (FE simulation was performed using a global-local modeling approach and Progressive Failure Analysis (PFA techniques which took into account material failure and property degradation. Failure process and failure characteristics of the transition region were satisfactorily reproduced in the simulation, and it was found that accumulated delamination in spar cap and shear web failure at the transition region were the main reasons for the blade to collapse. Local buckling played an important role in the failure process by increasing local out-of-plane deformation, while the Brazier effect was found not to be responsible for the blade failure.

  4. The effect of organic loading on bacterial community composition of membrane biofilms in a submerged polyvinyl chloride membrane bioreactor.

    Science.gov (United States)

    Xia, Siqing; Li, Jixiang; He, Shuying; Xie, Kang; Wang, Xiaojia; Zhang, Yanhao; Duan, Liang; Zhang, Zhiqiang

    2010-09-01

    The effect of organic loading on bacterial community composition of membrane biofilms was investigated using a submerged polyvinyl chloride membrane bioreactor. The low and high loadings were set at 0.33 and 0.52 gCOD/(gVSSd), respectively. The results showed that membrane fouling occurred earlier and faster under the high loading conditions. Denaturing gradient gel electrophoresis (DGGE) analysis revealed that the similarity of bacterial community in the membrane biofilms between the two loadings was 0.67, higher than that in the mixed liquors (0.52-0.55), which indicated that some specific bacteria were selected preferentially on the membranes. Clone library analysis of the membrane biofilms indicated that Betaproteobacteria and Bacteroidetes under the high loading were 54.72% and 19.81%, respectively. Microarray results further confirmed that the two bacteria were the dominant microorganisms in the high loading biofilm. The severe membrane fouling may be aroused mainly by the enrichment of the two bacteria under the high loading.

  5. Restoring Nonvital Premolars with Composite Resin Onlays: Effect of Different Fiber-reinforced Composite Layers on Marginal Adaptation and Fracture Load.

    Science.gov (United States)

    Monaco, Carlo; Bortolotto, Tissiana; Arena, Antonio; Krejci, Ivo

    2015-12-01

    To evaluate the marginal adaptation and fracture load of composite resin onlays reinforced with different substructures. Thirty-two extracted, caries-free premolars were selected for this study and endodontically treated. Group 1 was used as the control group, and the teeth were restored only with as-manufactured composite resin overlays. Group 2 teeth were restored with composite resin overlays with 3 fiber-reinforced composite (FRC) layers placed horizontally on the bottom of the restoration. Group 3 teeth were restored with composite resin overlays with 6 fiber-reinforced composite (FRC) layers placed as in group 2. Group 4 teeth were restored with composite resin overlays and FRC placed with an anatomical design. All specimens underwent SEM evaluation of their marginal adaptation before and after thermocycling and cyclic mechanical loading. All specimens were then subjected to a fracture test, recording the value for the initial (IF) and final (FF) failure. Differences in the means were compared using matched-pairs t-tests and one-way ANOVA. The level of significance was set at α = 0.05. No statistically significant difference between the four groups in terms of marginal adaptation was observed at the tooth/luting composite and luting composite/overlay interfaces before and after loading. The fracture loads of IF and FF, from most to least resistant were: group 4 (1431.8 ± 294.3 N/1710.1 ± 326.6 N), group 3 (1428.1 ± 251.4 N/1467.9 ± 242.4 N), group 2 (852.6 ± 413.5 N/1058.1 ± 251.5 N) and group 1 (899.8 ± 352.7 N/923.5 ± 318.8 N). Significant differences (p = 0.026) were observed comparing group 1 to groups 2 and 3, and group 1 to 4. Three irreparable fractures were found in group 3, four in group 2, and five in groups 1 and 4. The presence or absence of reinforcement and the different configuration of the reinforcement fibers affect fracture strength but only partially the failure modality. The presence or absence of reinforcement does not alter

  6. [Road dust loading and chemical composition at major cities in Fujian Province].

    Science.gov (United States)

    Zheng, An; Yang, Bing-yu; Wu, Shui-ping; Wang, Xin-hong; Chen, Xiao-qiu

    2013-05-01

    A total of 57 road dust and 16 urban soil samples were collected from four cities, Xiamen, Zhangzhou, Quanzhou and Putian in Fujian Province, China. Twenty-six elements, eight water soluble ions, organic carbon and elemental carbon in the fraction of particulate diameter less than 2.5 microm (PM2.5) derived through a suspension chamber were analyzed. The average loading of road dust with diameter less than 100 microm in the four cities ranged from 6.99 g x m(-2) to 10.11 g x m(-2), while the loading of PM2.5 ranged from 4.0 mg x m(-2) to 12.5 mg x m(-2). Both the soil and road dust samples were characterized with much higher concentrations of Si, Ca, Al, Fe and K. But for the anthropogenic elements such as Cu, Pb, Zn,Cr and Ti, much lower levels were found in the soil PM2.5, than those in the road dust PM2.5. Significantly higher levels of NH4+, NO3- and SO4(2-) were found in the road dust PM2.5 from Zhangzhou in comparison with those from other cities in this study. The calcium ion (Ca2+) content was significantly positively correlated with the Mg2+ content in the road dust PM2.5 from Xiamen, Zhangzhou and Quanzhou. The levels of organic carbon (OC) in the road dust PM2.5 in these four cities were higher than those reported in Ji'nan, Shijiazhuang and Beijing while the levels of elemental carbon (EC) were all lower than those in the urban road dust from Beijing, Significant positive correlation between EC and OC was found in samples from Quanzhou and Putian, suggesting the same and/or similar sources. The result of mass balance indicated that higher percentage compositions were soil and OM in both Quanzhou and Putian. Based on the cluster analysis, the 57 road dust samples were divided into four types: influenced by atmospheric deposition, influenced by soil dust, influenced by atmospheric deposition and soil dust, and influenced by soil and construction dust.

  7. Bonding of flowable resin composite restorations to class 1 occlusal cavities with and without cyclic load stress.

    Science.gov (United States)

    Kawai, Takatoshi; Maseki, Toshio; Nara, Yoichiro

    2016-01-01

    To examine the bonding of flowable resin composite restorations (F-restoration) to class 1 occlusal cavities with and without cyclic load stress, compared with that of a universal resin composite restoration (U-restoration). Two flowable composites and one universal composite (control) were applied with an adhesive system to 42 standardized class 1 occlusal cavities. The restored specimens were subjected to cyclic load stress and no stress modes. The microtensile bond strength (μ-TBS) of the dentin floor was measured. The U-restoration did not show pretesting failure. The F-restorations exhibited pretesting failure, regardless of the stress mode. The μ-TBS was not significantly different among the three restorations, regardless of the stress mode. The cyclic load stress did not influence the μ-TBS of the F-restorations; however, it significantly reduced μ-TBS in the U-restoration. The bonding reliability of the F-restorations was inferior to that of the U-restoration, for both stress modes.

  8. Mechanical Behavior of Polyester and Fiber Glass as a Composite Material used in a Vehicle under Dynamic Loading

    Directory of Open Access Journals (Sweden)

    Ahmed Naif Al-Khazraji* Ali Yasser Hassa * Emad Abdul Hussein Abdul Sahib

    2014-04-01

    Full Text Available The automobile industry has shown increased interest in the replacement of steel spring with fiberglass composite leaf spring due to high strength compared to weight. The aim of this paper is to study two kinds of fiberglass, regular direction (0-90 and random direction immersed in polyester resin. They were tested under static load, as tensile test for their mechanical properties, and under dynamic load in fully reversible bending tests as fatigue test, to estimate S-N curves, and impact test for their mechanical properties. Results from the tensile tests showed that the tensile strength of the regular type is greater than random type. The fatigue test results showed that the number of cycles to failure in regular type of composite material is greater than that of the random type and the endurance limit is also greater than in random, the increase percentage in endurance limit is 7.5%. Results due to impact test showed that there were on increasing in fracture energy for the random type the increase ratio is 13.9%. The Important characteristics of composites that make them excellent for leaf spring instead of steel are higher strength-to-weight ratio, superior fatigue strength. Application of composite structures reduces the weight of leaf spring without any reduction on the load carrying capacity and stiffness in automobile suspension system.

  9. Hertzian Load-bearing Capacity of Hybrid and Nano-hybrid Resin Composites Stored Dry and Wet

    Directory of Open Access Journals (Sweden)

    Farmani S

    2016-03-01

    Full Text Available Statement of Problem: Hertzian indentation test has been proven to be an efficient and reliable alternative upon Vickers hardness test. This method has been used to test dental ceramics, amalgams, glass ionomers and luting cements.There is limited published information about the load-bearing capacity of resin composites using Hertizian indentation test. Objectives: To investigate the load-bearing capacity of hybrid and nano-hybrid resin composites stored dry or wet up to 30 days, using Hertzian indentation test. Materials and Methods: Three resin composites were used: two nano-hybrids (Filtek Supreme, and Luna and one hybrid, (Rok. A total of 108 disc-shaped specimens (1mm thick x 10 mm diameter were prepared using polyethylene mould. The specimens of each material were randomly divided into 6 groups of 6 (n=6 and stored at 370C either in distilled water or dry for 1, 7 and 30 days. The specimens were tested using Hertzian jig aligned in the universal testing machine. The specimen was placed on the top of a disc-shaped substrate. The load was applied at the center of each specimen and the load at the first crack was recorded. Data were analyzed by ANOVA, Tukey’sand student’s t-test using SPSS version 18.0. Results: Three-way ANOVA showed a significant interaction between all the factors (p = .0001. The load bearing capacity of almost all materials reduced significantly in the wet condition in comparison with the dry condition (p = .0001. After seven days of immersion in distilled water, Filtek Supreme had significantly lower values than those of Rok and Luna, there was no significant differences between materials in the dry condition. Conclusions:In contrast to dry condition, the load-bearing capacity of specimens stored in distilled water decreased significantly over the 30 days of immersion. The load bearing capacity of nano-hybrid composites tested in this study was shown to be comparable with that of the hybrid composite.

  10. Thermal residual stresses and stress distributions under tensile and compressive loadings of short fiber reinforced metal matrix composites

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The thermal residual stresses and the stress distributions of short fiber reinforced metal matrix composite under tensile and compressive loadings were studied using large strain axisymmetric elasto-plastic finite element method. It is demonstrated that the thermal residual stresses can result in asymmetrical stress distributions and matrix plasticity. The thermal residual stresses decrease the stress transfer in tension and enhance the stress transfer in compression. The fiber volume fraction has more important effects on the thermal residual stresses and the stress distributions under tensile and compressive loadings than the fiber aspect ratio and the fiber end distance.

  11. The influence of FRCs reinforcement on marginal adaptation of CAD/CAM composite resin endocrowns after simulated fatigue loading.

    Science.gov (United States)

    Rocca, Giovanni Tommaso; Saratti, Carlo Massimo; Poncet, Antoine; Feilzer, Albert J; Krejci, Ivo

    2016-05-01

    To evaluate the marginal adaptation of endodontically treated molars restored with CAD/CAM composite resin endocrowns either with or without reinforcement by fibre reinforced composites (FRCs), used in different configurations. 32 human endodontically treated molars were cut 2 mm over the CEJ. Two interproximal boxes were created with the margins located 1 mm below the CEJ (distal box) and 1 mm over the CEJ (mesial box). All specimens were divided in four groups (n = 8). The pulp chamber was filled with: group 1 (control), hybrid resin composite (G-aenial Posterior, GC); group 2, as group 1 but covered by 3 meshes of E-glass fibres (EverStick NET, Stick Tech); group 3, FRC resin (EverX Posterior, GC); group 4, as group 3 but covered by 3 meshes of E-glass fibres. The crowns of all teeth were restored with CAD/CAM composite resin endocrowns (LAVA Ultimate, 3M). All specimens were thermo-mechanically loaded in a computer-controlled chewing machine (600,000 cycles, 1.6 Hz, 49 N and simultaneously 1500 thermo-cycles, 60 s, 5-55 °C). Marginal analysis before and after the loading was carried out on epoxy replicas by SEM at 200× magnification. For all the groups, the percentage values of perfect marginal adaptation after loading were always significantly lower than before loading (p 0.05). Within the limitations of this in vitro study, the use of FRCs to reinforce the pulp chamber of devitalized molars restored with CAD/CAM composite resin restorations did not significantly influenced their marginal quality.

  12. Marginal and internal adaptation of Class II ormocer and hybrid resin composite restorations before and after load cycling.

    Science.gov (United States)

    Kournetas, N; Chakmakchi, M; Kakaboura, A; Rahiotis, C; Geis-Gerstorfer, J

    2004-09-01

    To overcome the shortcomings of the conventional composite restorative materials, ormocer materials have been introduced over the past few years. The purpose of this study was to evaluate the marginal and internal adaptation of two ormocer restorative systems (Admira, Voco and Definite, Degussa) compared to a hybrid composite one (TPH Spectrum, Dentsply/ DeTrey), before and after load cycling in Class II restorations. Standardized Class II restorations with cervical margins on enamel were divided into three groups ( n=16). Teeth of each group were filled with one of the restoratives tested and its respective bonding agent. Each group was divided into two equal subgroups. The marginal and internal adaptation of the first subgroup was evaluated after 7-day water storage at room temperature and of the second after cyclic loading in a mastication simulator (1.2x10(6) cycles, 49 N, 1.6 Hz). The occlusal and cervical marginal evaluation was conducted by videomicroscope and ranked as "excellent" and "not excellent". One thin section (150 microm), in mesial-distal direction, of each restoration, was examined under metallographic microscope to determine the quality of internal adaptation. The occlusal and cervical adaptation of both ormocer restorative systems was similar and clearly worse compared with the hybrid composite restorative one before as well as after load cycling. Concerning internal adaptation, no gap-free ormocer restorations were detected, whereas all Spectrum restorations presented perfect adaptation. The bonding agents of the ormocers formed layers with unacceptable features (pores, fractures) whereas that of the hybrid composite achieved perfect bonding layer even after loading. The rheological characteristics of the bonding agents of the ormocer restorative systems are proposed to be responsible for their inferior marginal and internal quality in Class II restorations compared with the hybrid composite one.

  13. 丙烯酸酯改性水性聚氨酯复合乳液的研究进展%Research progress of acrylate-modified waterborne polyurethane composite emulsion

    Institute of Scientific and Technical Information of China (English)

    施建刚; 田呈呈; 杨少艳; 赵振河

    2014-01-01

    综介绍了丙烯酸酯改性水性聚氨酯的几种改性制备方法及其优缺点,其中包括:物理共混改性,交联共混改性,接枝共聚改性,核-壳结构乳液聚合改性,互穿网络法改性等。综述了国内外的研究现状及今后研究发展方向。%The preparation methods and their relative merits of the acrylate-modified waterborne polyurethanes were given, including the physical blending,blend crosslinking,graft copolymerization,core-shell emulsion polymerization modifying and interpenetration network modifying.The domestic and foreign research status was summarized and the further development direction was pointed out for the research of acrylate-modified waterborne polyurethane emulsions.

  14. Vinyl Acetate/butyl acrylate/acrylate Research of Ternary Soap-free Emulsion Polymerization

    Directory of Open Access Journals (Sweden)

    Xiao Li-guang

    2016-01-01

    Full Text Available Through the vinyl acetate/butyl acrylate/acrylic acrylic emulsion preparation without soap vinegar, with solid content, gel, emulsion stability and film forming properties and tensile strength as the main index to study the effect of raw materials on the properties of emulsion. Through the infrared spectrometer soap-free emulsion for microscopic analysis research. Study of the ternary soap-free vinegar acrylic emulsion with good performance.

  15. Methotrexate-loaded glass ionomer cements for drug release in the skeleton: An examination of composition-property relationships.

    Science.gov (United States)

    Kiri, Lauren; Filiaggi, Mark; Boyd, Daniel

    2016-01-01

    Chemotherapeutic-loaded bone cement may be an effective method of drug delivery for the management of cancer-related vertebral fractures that require cement injection for pain relief. Recent advancements in the development of aluminum-free glass ionomer cements (GICs) have rendered this class of biomaterials clinically viable for such applications. To expand the therapeutic benefits of these materials, this study examined, for the first time, their drug delivery potential. Through incrementally loading the GIC with methotrexate (MTX) by up to 10-wt%, composition-property relationships were established, correlating MTX loading with working time and setting time, as well as compressive strength, drug release, and cytotoxic effect over 31 days. The most significant finding of this study was that MTX was readily released from the GIC, while maintaining cytotoxic activity. Release correlated linearly with initial loading and appeared to be diffusion mediated, delivering a total of 1-2% of the incorporated drug. MTX loading in this range exerted minimal effects to handling and strength, indicating the clinical utility of the material was not compromised by MTX loading. The MTX-GIC systems examined herein are promising materials for combined structural delivery applications.

  16. Performance of hybrid cement composite elements under drop-weight impact load

    Directory of Open Access Journals (Sweden)

    Nguyen, V. D.

    2014-05-01

    Full Text Available The performance, under drop-weight impact load, of hybrid cement composite (HCC elements, consisting of a top layer of plain concrete (PC and a bottom layer of fibre reinforced concrete (FRC, in comparison with full-depth FRC and PC was studied. Apart from improving the tensile capacity of PC and saving fibre steel reinforcements of FRC, the results showed that HCC can effectively control the deformations and enhance the impact performance of the structural members as its outcomes were similar to that of a full-depth FRC. The analytical studies using Hughes empirical formulae (HEF and yield line theory (YLT adopted to investigate the practical use of HCC showed that they are applicable for design such HCC elements against impacts.Se estudió el comportamiento, frente a impacto de torre de caída, de elementos híbridos base cemento (HCC, formados por una capa superior de hormigón en masa (PC y una capa inferior de hormigón reforzado con fibras (FRC en comparación con elementos análogos íntegramente fabricados con FRC y PC. Además de proporcionar una mejora en la resistencia frente a flexo-tracción de los PC y un ahorro en refuerzo usando fibras de acero en el caso de los FRC, los resultados mostraron que el HCC puede controlar eficazmente las deformaciones y mejorar el rendimiento frente a impacto de los elementos estructurales ya que sus resultados fueron análogos a la de los FRC. Los estudios analíticos, utilizando HEF e YLT, adoptados para investigar el uso práctico de los HCC mostraron que los mismos son aplicables para el diseño de estos elementos frente a impacto.

  17. Distinct failure modes in bio-inspired 3D-printed staggered composites under non-aligned loadings

    Science.gov (United States)

    Slesarenko, Viacheslav; Kazarinov, Nikita; Rudykh, Stephan

    2017-03-01

    The superior mechanical properties of biological materials originate in their complex hierarchical microstructures, combining stiff and soft constituents at different length scales. In this work, we employ a three-dimensional multi-materials printing to fabricate the bio-inspired staggered composites, and study their mechanical properties and failure mechanisms. We observe that bio-inspired staggered composites with inclined stiff tablets are able to undergo two different failure modes, depending on the inclination angle. We find that such artificial structure demonstrates high toughness only under loading applied at relatively small angle to the tablets stacking direction, while for higher angles the composites fail catastrophically. This aspect of the failure behavior was captured experimentally as well as by means of the finite element analysis. We show that even a relatively simple failure model with a strain energy limiter, can be utilized to qualitatively distinguish these two different modes of failure, occurring in the artificial bio-inspired composites.

  18. Comparison of Fracture Characteristics of Openhole-Notch Carbon-Fiber-Reinforced Composites Subjected to Tensile and Compressive Loadings

    Science.gov (United States)

    Saeed, M.-U.; Chen, Z. F.; Chen, Z. H.; Li, B. B.

    2017-01-01

    Open-hole tension (OHT) and open-hole compression (OHC) tests were carried out on hot-pressed carbon-fiberreinforced composite samples with a singular open hole. The fracture surfaces of the OHT- and OHC-tested specimens were examined by using scanning electron microscopy (SEM). SEM micrographs showed significant features on the surface of carbon fiber, matrix, and especially in the fiber/matrix interface. Interpretation of these micrographs revealed the possible failure mechanism of composite samples with an open hole under tensile and compressive loadings. Furthermore, a comparative study of these micrographs also pointed to certain specific differences between the fracture characteristics of open-hole composite samples failed under tension and compression. This information is useful in the post-failure analysis of a composite structure.

  19. Influence of Reactive Diluent on UV-curing of Acrylate Terminated Hyperbranched Polymers

    Institute of Scientific and Technical Information of China (English)

    TANG Li-ming; FANG Yu; YAN Liang; FU Zhi-wei

    2004-01-01

    A Aeries of hydroxylic hyperbranched polymers were derived from 2,2-bis(methylol) propionic acid and tris (methylol) propane reacted with acrylic acid to various extents. The obtained acrylated hyperbranched polymers alone or with a monofunctional diluent, isobornylene acrylate(IBOA) were further cured by UV radiation. The cured films based on the modified polymers alone all demonstrated poor mechanical properties due to their high network densities and low moving ability of polymer chains. For the composite systems, the cured films demonstrated improved mechanical properties due to the low network densities and high chain moving ability. With more IBOA included in the systems, acrylate groups can react to a higher extent during the curing process.

  20. Poly(amide-graft-acrylate) interfacial compounds

    Science.gov (United States)

    Zamora, Michael Perez

    Graft copolymers with segments of dissimilar chemistries have been shown to be useful in a variety of applications as surfactants, compatibilizers, impact modifiers, and surface modifiers. The most common route to well defined graft copolymers is through the use of macromonomers, polymers containing a reactive functionality and thus capable of further polymerization. However, the majority of the studies thus far have focused on the synthesis of macromonomers capable of reacting with vinyl monomers to form graft copolymers. This study focused on the synthesis of macromonomers capable of participating in condensation polymerizations. A chain transfer functionalization method was utilized. Cysteine was evaluated as a chain transfer agent for the synthesis of amino acid functionalized poly(acrylate) and poly(methacrylate) macromonomers. Low molar mass, functionalized macromonomers were produced. These macromonomers were proven to be capable of reacting with amide precursors to form poly(amide-g-acrylate) graft copolymers. Macromonomers and graft copolymers were characterized by gel permeation chromatography (GPC), Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR) spectroscopy, elemental analysis (EA), inductively coupled plasma (ICP), and differential scanning calorimetry (DSC). The second part of this research involved poly(dimethacrylate) dental restorative materials. Volumetric shrinkage during the cure of these resins results in a poor interface between the resin and the remaining tooth structure, limiting the lifetime of these materials. Cyclic anhydrides were incorporated into common monomer compositions used in dental applications. Volume expansion from the ring opening hydrolysis of these anhydrides was shown to be feasible. The modified dental resins were characterized by swelling, extraction and ultraviolet spectroscopy (UV), and density measurements. Linear poLymers designed to model the crosslinked dental resins were

  1. Preparation and characterization of TAM-loaded HPMC/PAN composite fibers for improving drug-release profiles.

    Science.gov (United States)

    Shen, Xiaxia; Yu, Dengguang; Zhang, Xiaofei; Branford-White, Christopher; Zhu, Limin

    2011-01-01

    The present paper reports the preparation and characterization of composite hydroxypropyl methylcellulose/polyacrylonitrile (HPMC/PAN)-medicated fibers via a wet spinning technique. Tamoxifen (TAM) was selected as a model drug. Numerous analyses were conducted to characterize the mechanical, structure and morphology properties of the composite fibers. The drug content and in vitro dissolution behavior were also investigated. SEM images showed that the TAM-loaded HPMC/PAN composite fibers had a finger-like outer skin and a porous structure. FT-IR spectra demonstrated that there was a good compatibility between polymer and drug. Results from X-ray diffraction and DSC suggested that most of the incorporated TAM was evenly distributed in the fiber matrix in an amorphous state, except for a minority that aggregated on the surface of fibers. The drug content in the fibers was lower than that in the spinning solution and about 10% of TAM was lost during spinning process. In vitro dissolution results indicated that, compared to TAM-PAN fibers, HPMC/PAN composite systems had weaker initial burst release effects and more drug-loading. The combination of hydrophilic polymer HPMC with PAN could improve the performance of polymer matrix composite fibers in regulating the drug-release profiles.

  2. Evaluation of a strain based failure criterion for the multi-constituent composite model under shock loading

    Directory of Open Access Journals (Sweden)

    Key Christopher T.

    2015-01-01

    Full Text Available This study details and demonstrates a strain-based criterion for the prediction of polymer matrix composite material damage and failure under shock loading conditions. Shock loading conditions are characterized by high-speed impacts or explosive events that result in very high pressures in the materials involved. These material pressures can reach hundreds of kbar and often exceed the material strengths by several orders of magnitude. Researchers have shown that under these high pressures, composites exhibit significant increases in stiffness and strength. In this work we summarize modifications to a previous stress based interactive failure criterion based on the model initially proposed by Hashin, to include strain dependence. The failure criterion is combined with the multi-constituent composite constitutive model (MCM within a shock physics hydrocode. The constitutive model allows for decomposition of the composite stress and strain fields into the individual phase averaged constituent level stress and strain fields, which are then applied to the failure criterion. Numerical simulations of a metallic sphere impacting carbon/epoxy composite plates at velocities up to 1000 m/s are performed using both the stress and strain based criterion. These simulation results are compared to experimental tests to illustrate the advantages of a strain-based criterion in the shock environment.

  3. Evaluation of a strain based failure criterion for the multi-constituent composite model under shock loading

    Science.gov (United States)

    Key, Christopher T.; Schumacher, Shane C.; Alexander, C. Scott

    2015-09-01

    This study details and demonstrates a strain-based criterion for the prediction of polymer matrix composite material damage and failure under shock loading conditions. Shock loading conditions are characterized by high-speed impacts or explosive events that result in very high pressures in the materials involved. These material pressures can reach hundreds of kbar and often exceed the material strengths by several orders of magnitude. Researchers have shown that under these high pressures, composites exhibit significant increases in stiffness and strength. In this work we summarize modifications to a previous stress based interactive failure criterion based on the model initially proposed by Hashin, to include strain dependence. The failure criterion is combined with the multi-constituent composite constitutive model (MCM) within a shock physics hydrocode. The constitutive model allows for decomposition of the composite stress and strain fields into the individual phase averaged constituent level stress and strain fields, which are then applied to the failure criterion. Numerical simulations of a metallic sphere impacting carbon/epoxy composite plates at velocities up to 1000 m/s are performed using both the stress and strain based criterion. These simulation results are compared to experimental tests to illustrate the advantages of a strain-based criterion in the shock environment.

  4. Constitutive Theories for Woven Composite Structures Subjected to Shock Loading; Experimental Validation Using a Conical Shock Tube

    Directory of Open Access Journals (Sweden)

    David R. Hufner

    2012-01-01

    Full Text Available Woven polymer-based composites are currently used in a wide range of marine applications. These materials often exhibit highly nonlinear, rate dependent, anisotropic behavior under shock loadings. Correlation to transient response data, beyond an initial peak, is often difficult. The state of damage evolves throughout the time history and the unloading response varies based on the amount, and nature of, the accumulated damage. Constitutive theories that address the loading and unloading responses have been developed and integrated with each other. A complete theory, applicable to transient dynamic analysis, is presented. The model is implemented within the commercial finite element code, Abaqus, in the form of a user material subroutine. In this study, the conical shock tube is used to experimentally reproduce the high strain rates and fluid structure interactions typical of underwater shock loadings. The conical shock tube data is used to validate analytical model predictions. Simulation results are in good agreement with test data.

  5. Fracture load of implant-supported zirconia all-ceramic crowns luted with various cements.

    Science.gov (United States)

    Lim, Hyun-Pil; Yoo, Jeong-Min; Park, Sang-Won; Yang, Hong-So

    2010-01-01

    This study compared the fracture load and failure types of implant-supported zirconia all-ceramic crowns cemented with various luting agents. The ceramic frameworks were fabricated from a presintered yttria-stabilized zirconium dioxide block using computer-aided design/computer-assisted manufacturing technology, and were then veneered with feldspathic porcelain. Three luting agents were used. Composite resin cement (1,560.78 +/- 39.43 N) showed the highest mean fracture load, followed by acrylic/urethane cement (1,116.20 +/- 77.32 N) and zinc oxide eugenol cement (741.21 +/- 41.95 N) (P < .05). The types of failure varied between groups.

  6. The Study of Stability of Compression-Loaded Multispan Composite Panel Upon Failure of Elements Binding it to Panel Supports

    Science.gov (United States)

    Zamula, G. N.; Ierusalimsky, K. M.; Fomin, V. P.; Grishin, V. I.; Kalmykova, G. S.

    1999-01-01

    The present document is a final technical report carried out within co-operation between United States'NASA Langley RC and Russia's Goskomoboronprom in aeronautics, and continues similar programs, accomplished in 1996, 1997, and 1998, respectively). The report provides results of "The study of stability of compression-loaded multispan composite panels upon failure of elements binding it to panel supports"; these comply with requirements established at TsAGI on 24 March 1998 and at NASA on 15 September 1998.

  7. MODELING OF NONLINEAR CYCLIC LOAD BEHAVIOR OF I-SHAPED COMPOSITE STEEL-CONCRETE SHEAR WALLS OF NUCLEAR POWER PLANTS

    Directory of Open Access Journals (Sweden)

    AHMER ALI

    2013-02-01

    Full Text Available In recent years steel-concrete composite shear walls have been widely used in enormous high-rise buildings. Due to high strength and ductility, enhanced stiffness, stable cycle characteristics and large energy absorption, such walls can be adopted in the auxiliary building; surrounding the reactor containment structure of nuclear power plants to resist lateral forces induced by heavy winds and severe earthquakes. This paper demonstrates a set of nonlinear numerical studies on I-shaped composite steel-concrete shear walls of the nuclear power plants subjected to reverse cyclic loading. A three-dimensional finite element model is developed using ABAQUS by emphasizing on constitutive material modeling and element type to represent the real physical behavior of complex shear wall structures. The analysis escalates with parametric variation in steel thickness sandwiching the stipulated amount of concrete panels. Modeling details of structural components, contact conditions between steel and concrete, associated boundary conditions and constitutive relationships for the cyclic loading are explained. Later, the load versus displacement curves, peak load and ultimate strength values, hysteretic characteristics and deflection profiles are verified with experimental data. The convergence of the numerical outcomes has been discussed to conclude the remarks.

  8. SYNTHESIS AND IN VITRO CHARACTERIZATION OF HYDROXYPROPYL METHYLCELLULOSE-GRAFT-POLY (ACRYLIC ACID/2-ACRYLAMIDO-2-METHYL-1-PROPANESULFONIC ACID) POLYMERIC NETWORK FOR CONTROLLED RELEASE OF CAPTOPRIL.

    Science.gov (United States)

    Furqan Muhammad, Iqbal; Mahmood, Ahmad; Aysha, Rashid

    2016-01-01

    A super-absorbent hydrogel was developed by crosslinking of 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) and acrylic acid with hydroxypropyl methylcellulose (HPMC) for controlled release drug delivery of captopril, a well known antihypertensive drug. Acrylic acid and AMPS were polymerized and crosslinked with HPMC by free radical polymerization, a widely used chemical crosslinking method. N,N'-methylenebisacrylamide (MBA) and potassium persulfate (KPS) were added as cross-linker and initiator, respectively. The hydrogel formulation was loaded with captopril (as model drug). The concentration of captopril was monitored at 205 nm using UV spectrophotometer. Equilibrium swelling ratio was determined at pH 2, 4.5 and 7.4 to evaluate the pH responsiveness of the formed hydrogel. The super-absorbent hydrogels were evaluated by FTIR, SEM, XRD, and thermal analysis (DSC and TGA). The formation of new copolymeric network was determined by FTIR, XRD, TGA and DSC analysis. The hydrogel formulations with acrylic acid and AMPS ratio of 4: 1 and lower amounts of crosslinker had shown maximum swelling. Moreover, higher release rate of captopril was observed at pH 7.4 than at pH 2, because of more swelling capacity of copolymer with increasing pH of the aqueous medium. The present research work confirms the development of a stable hydrogel comprising of HPMC with acrylic acid and AMPS. The prepared hydrogels exhibited pH sensitive behav-ior. This superabsorbent composite prepared could be a successful drug carrier for treating hypertension.

  9. Reactivity Ratios of Diethyldiallylammonium Chloride with Acrylamide or Acrylic Acid

    Institute of Scientific and Technical Information of China (English)

    Li Hua LIU; Zhi Qiang LIU; Zhu Qing GONG

    2006-01-01

    The compositions of copolymers of diethyldiallylammonium chloride (DEDAAC) with acrylamide (AM), acrylic acid (AA) or sodium acrylic acid (NaAA) at low conversion were determined by elemental analysis, and the reactivity ratios of monomers in copolymerization were obtained by Kelen-Tudos method. The results showed that the reactivity ratios rDE and rAM are 0.31 and 5.27 for DEDAAC with AM, rDE and rAA are 0.28 and 5.15 for DEDAAC with AA, and rDE and rNaAA are 0.40 and 3.97 for DEDAAC with NaAA, respectively. The copolymerizations for DEDAAC with AM, AA or NaAA are non-ideal copolymerization and the products are random copolymers.

  10. New fly ash TiO{sub 2} composite for the sustainable treatment of wastewater with complex pollutants load

    Energy Technology Data Exchange (ETDEWEB)

    Visa, Maria, E-mail: maria.visa@unitbv.ro; Isac, Luminita; Duta, Anca

    2015-06-01

    Graphical abstract: - Highlights: • A novel substrate FADAht is obtained by hydrothermal synthesis. • The composite type structure has specific surface ten times higher than fly ash. • Simultaneous removal of three pollutants reaches efficiencies above 90%. • Kinetic investigations show fast adsorption of the dye on the new composite. - Abstract: The goal of this paper was to develop a new composite obtained in mild hydrothermal conditions starting from fly ash (a waste raising significant environmental problems), and TiO{sub 2}. The composite was characterized through XRD, SEM/EDX, AFM, and BET surface measurements. The composite was further used for the advanced treatment of wastewaters with multiple-pollutants load. The photocatalytic efficiency of the powder composite was tested on synthetic solutions containing a heavy metal cation (copper), a dye (methyl orange), and a surfactant (sodium dodecylbenzenesulfonate), under UV and simulated solar radiation. Comparative experiments were done in systems with and without H{sub 2}O{sub 2} showing a significant increase in efficiency for methyl orange removal from mono-, bi-, and tri-pollutants solutions. The process parameters were optimized and the adsorption mechanisms are discussed, outlining that adsorption is the limiting step. Experiments also outlined that homogeneous photocatalysis (using H{sub 2}O{sub 2}) is less efficient then the heterogeneous process using the novel composite, both under UV and simulated solar radiation.

  11. Predicting Failure Progression and Failure Loads in Composite Open-Hole Tension Coupons

    Science.gov (United States)

    Arunkumar, Satyanarayana; Przekop, Adam

    2010-01-01

    Failure types and failure loads in carbon-epoxy [45n/90n/-45n/0n]ms laminate coupons with central circular holes subjected to tensile load are simulated using progressive failure analysis (PFA) methodology. The progressive failure methodology is implemented using VUMAT subroutine within the ABAQUS(TradeMark)/Explicit nonlinear finite element code. The degradation model adopted in the present PFA methodology uses an instantaneous complete stress reduction (COSTR) approach to simulate damage at a material point when failure occurs. In-plane modeling parameters such as element size and shape are held constant in the finite element models, irrespective of laminate thickness and hole size, to predict failure loads and failure progression. Comparison to published test data indicates that this methodology accurately simulates brittle, pull-out and delamination failure types. The sensitivity of the failure progression and the failure load to analytical loading rates and solvers precision is demonstrated.

  12. Effect of preparation conditions on selective oxidation of propane to acrylic acid

    Institute of Scientific and Technical Information of China (English)

    YU Zhen-xing; ZHENG Wei; XU Wen-long; ZHANG Yu-hang; FU Hong-ying; ZHANG Ping

    2009-01-01

    The effects of chemical composition and preparation conditions, especially calcination atmosphere and water content on the catalytic performances of MoVTeNbO mixed oxide catalyst system for the selective oxidation of propane to acrylic acid were investigated. Among the catalysts studied, MO_(1.0)V_(0.3)Te_(0.23)Nb_(0.12)O_x catalyst calcined in inert atmosphere at 600 ℃ shows the best performance in terms of propane conversion and selectivity to acrylic acid. The results reveal that proper chemical composition, calcination atmosphere and water content affect greatly the catalysts in many ways including structure, chemical composition, which are related to their catalytic performances; and 51.0% propane conversion and 30.5% one-pass yield to acrylic acid can be achieved at the same time.

  13. Dietary carbohydrate composition can change waste production and biofilter load in recirculating aquaculture systems

    NARCIS (Netherlands)

    Meriac, A.; Eding, E.H.; Schrama, J.W.; Kamstra, A.; Verreth, J.A.J.

    2014-01-01

    This study investigated the effect of dietary carbohydrate composition on the production, recovery and degradability of fecal waste from rainbow trout (Oncorhynchus mykiss) in recirculating aquaculture systems (RAS). Dietary carbohydrate composition was altered by substituting starch with non-starch

  14. Transient Dynamic Response and Failure of Composite Structure Under Cyclic Loading with Fluid Structure Interaction

    Science.gov (United States)

    2014-09-01

    14  2.  Vacuum Assisted Resin Transfer Molding ( VARTM ) .......... 15  3.  Composite Panels...Diagram of VARTM fabrication. .......................................................... 16  Figure 12.  VARTM and composite panel being made...method chosen is to perform “wet layup” of the composite laminates, followed by Vacuum Assisted Resin Transfer Molding ( VARTM ). 1. Wet Layup “Wet

  15. Preparation and self-sterilizing properties of Ag@TiO{sub 2}–styrene–acrylic complex coatings

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Xiang-dong; Chen, Feng; Yang, Jin-tao, E-mail: yangjt@zjut.edu.cn; Yan, Xiao-hui; Zhong, Ming-qiang, E-mail: zhongmingqiang@hotmail.com

    2013-04-01

    In this study, we report a simple and cost-effective method for self-sterilized complex coatings obtained by Ag@TiO{sub 2} particle incorporation into styrene–acrylic latex. The Ag@TiO{sub 2} particles were prepared via a coupling agent modification process. The composite latices characterized by transmission electron microscopy (TEM) study were highly homogeneous at the nanometric scale, and the Ag@TiO{sub 2} particles were well dispersed and exhibited an intimate contact between both the organic and inorganic components. The Ag@TiO{sub 2} nanoparticles significantly enhanced the absorption in the visible region and engendered a good heat-insulating effect of the complex coatings. Moreover, the Ag@TiO{sub 2} nanoparticle incorporation into this polymer matrix renders self-sterilized nanocomposite materials upon light excitation, which are tested against Escherichia coli and Staphylococcus aureus. The complex coatings display an impressive performance in the killing of all micro-organisms with a maximum for a Ag@TiO{sub 2} loading concentration of 2–5 wt.%. The weathering endurance of the complex coating was also measured. - Highlights: ► We prepared Ag@TiO{sub 2}–styrene–acrylic complex latex in one pot. ► Good antibacterial performances of complex coatings were observed. ► The complex coating was resistant to weathering after 48 h. ► The complex coating exhibits good heat-insulating effect.

  16. Organic loading rates affect composition of soil-derived bacterial communities during continuous, fermentative biohydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Yonghua; Bruns, Mary Ann [Department of Crop and Soil Sciences, The Pennsylvania State University, University Park, PA 16802 (United States); Zhang, Husen; Salerno, Michael; Logan, Bruce E. [Department of Civil and Environmental Engineering, The Pennsylvania State University, University Park, PA 16802 (United States)

    2008-11-15

    Bacterial community composition during steady-state, fermentative H{sub 2} production was compared across a range of organic loading rates (OLRs) of 0.5-19 g COD l{sup -1} h{sup -1} in a 2-l continuous flow reactor at 30 C. The varied OLRs were achieved with glucose concentrations of 2.5-10 g l{sup -1} and hydraulic retention times of 1-10 h. The synthetic wastewater feed was amended with L-cysteine and maintained at a pH of 5.5. For each run at a given glucose concentration, the reactor was inoculated with an aliquot of well-mixed agricultural topsoil that had been heat-treated to reduce numbers of vegetative cells. At OLRs less than 2 g COD l{sup -1} h{sup -1}, DNA sequences from ribosomal RNA intergenic spacer analysis profiles revealed more diverse and variable populations (Selenomonas, Enterobacter, and Clostridium spp.) than were observed above 2 g COD l{sup -1} h{sup -1} (Clostridium spp. only). An isolate, LYH1, was cultured from a reactor sample (10 g glucose l{sup -1} at a 10-h HRT) on medium containing L-cysteine. In confirming H{sub 2} production by LYH1 in liquid batch culture, lag periods for H{sub 2} production in the presence and absence of L-cysteine were 5 and 50 h, respectively. The 16S rRNA gene sequence of LYH1 indicated that the isolate was a Clostridium sp. affiliated with RNA subcluster Ic, with >99% similarity to Clostridium sp. FRB1. In fluorescent in situ hybridization tests, an oligonucleotide probe complementary to the 16S rRNA of LYH1 hybridized with 90% of cells observed at an OLR of 2 g COD h{sup -1}, compared to 26% of cells at an OLR of 0.5 g COD l{sup -1} h{sup -1}. An OLR of 2 g COD l{sup -1} h{sup -1} appeared to be a critical threshold above which clostridia were better able to outcompete Enterobacteriaceae and other organisms in the mixed soil inoculum. Our results are discussed in light of other biohydrogen studies employing pure cultures and mixed inocula. (author)

  17. The effect of bulk-resin CNT-enrichment on damage and plasticity in shear-loaded laminated composites

    KAUST Repository

    Ventura, Isaac Aguilar

    2013-07-01

    One way to improve multi functionality of epoxy-based laminated composites is to dope the resin with carbon nanotubes. Many investigators have focused on the elastic and fracture behavior of such nano-modified polymers under tensile loading. Yet, in real structural applications, laminated composites can exhibit plasticity and progressive damage initiated mainly by shear loading. We investigated the damage and plasticity induced by the addition of carbon nanotubes to the matrix of a glass fiber/epoxy composite system. We characterized both the modified epoxy resin and the associated modified laminates using classical mesoscale analysis. We used dynamic mechanical analysis, scanning electron microscopy, atomic force microscopy and classical mechanical testing to characterize samples with different concentrations of nanofillers. Since the samples were prepared using the solvent evaporation technique, we also studied the influence of this process. We found that in addition to the global increase in elastic regime properties, the addition of carbon nanotubes also accelerates the damage process in both the bulk resin and its associated glass-fiber composite. © 2013 Elsevier Ltd.

  18. High mass-loading of sulfur-based cathode composites and polysulfides stabilization for rechargeable lithium/sulfur batteries.

    Directory of Open Access Journals (Sweden)

    Toru eHara

    2015-05-01

    Full Text Available Although sulfur has a high theoretical gravimetric capacity, 1672 mAh/g, its insulating nature requires a large amount of conducting additives: this tends to result in a low mass-loading of active material (sulfur, and thereby, a lower capacity than expected. Therefore, an optimal choice of conducting agents and of the method for sulfur/conducting-agent integration is critically important. In this paper, we report that the areal capacity of 4.9 mAh/cm2 was achieved at a sulfur mass loading of 4.1 mg/cm2 by casting sulfur/polyacrylonitrile/ketjenblack (S/PAN/KB cathode composite into carbon fiber paper. This is the highest value among published/reported ones even though it does not contain expensive nano-sized carbon materials such as carbon nanotubes, graphene, or graphene-derivatives, and competitive enough with the conventional LiCoO2-based cathodes (e.g., LiCoO2, <20 mg/cm2 corresponding to <2.8 mAh/cm2. Furthermore, the combination of sulfur/PAN-based composite and PAN-based carbon fiber paper enabled the sulfur-based composite to be used even in carbonate-based electrolyte solution that many lithium/sulfur battery researchers avoid the use of it because of severer irreversible active material loss than in electrolyte solutions without carbonate-based solutions, and even at the highest mass-loading ever reported (the more sulfur is loaded, the more decomposed sulfides deposit at an anode surface..

  19. Short-Term Creep Behavior of CFRP-Reinforced Wood Composites Subjected to Cyclic Loading at Different Climate Conditions

    Directory of Open Access Journals (Sweden)

    Xiaojun Yang

    2014-02-01

    Full Text Available Carbon fiber reinforced plastic (CFRP was used to adhesively reinforce Chinese fir (Cunninghamia lanceolata wood specimens. This study examined the flexural static and creep performances of CFPR-reinforced wood composites that had been subjected to changes in moisture and stress levels. The major findings were as follows: 1 the cyclic creep was slightly lower for those specimens subjected to the cyclic stress condition than for those subjected to a constant stress level due to the deflection recovery under cyclic loading; 2 the environmental conditions of high temperature and high humidity assisted in accelerating the creep by increasing the moisture content of the composite and reducing the compressive strength of wood, causing the composite specimen to fail via damage in the wood layer from compressive crushing; 3 the stress level governed the creep of the CFRP-reinforced wood composite; and 4 the Burger model was able to accurately simulate the short-term creep performance of the CFPR-reinforced wood composite. It was suggested the maximum bending stress level should be limited to 40% for the CFRP-reinforced wood composites fabricated in this study.

  20. A Novel Composite Electrode of Photocatalyst-TiO2/C Loading on the Surface of the Air (Oxygen) Electrode

    Institute of Scientific and Technical Information of China (English)

    WANG,Yu-Ling(王玉玲); CAI,Nai-Cai(蔡乃才); WANG,Ya-Ping(王亚平); ZHONG,Jia-Sheng(钟家圣)

    2002-01-01

    The methods for preparing the H2O2 generating air (oxygen)electrode and the composite electrode of photocatalyst- TiO2/C loading on the surface of the air (oxygen) dectrode were introduced. In the case of the composite electrode, the current efficiency of electro-generated H2O2 is higher than 80% (J≤15mA/cm2). The degradation of aniline was used as an example to measure the influence of the composite electrode and compared with the system in which the air (oxygen) electrode and the photocatalyst-TiO2 were separated. The results confirmed that the composite electrode played an active role on accelerating the degradation rate of aniline. According to the measurement of the polarization curves of composite electrode and TiO2photo anode, and of the adsorbing amount of aniline on the surface of the composite electrode, the principle of descending the recombination rate of photo-generated electron and hole and of enhancing the oxidation rate of organic molecule was described. The mechanism about the degradation of aniline was also discussed.

  1. Microwave Assisted Preparation of Poly (acrylic acid-co-acrylamide)/Zeolite Superabsorbent Composite and Its Properties%微波辅助聚(丙烯酸-丙烯酰胺)/沸石高吸水复合材料的制备及性能

    Institute of Scientific and Technical Information of China (English)

    栗印环; 张秀兰; 潘国华; 曾小兰; 胡红艳

    2012-01-01

    The poly (acrylic acid-co-acrylaide) / zeolite superabsorbent composite was synthesized by microwave assisted method. The effects of the amount of acrylamide,initiator,crosslinker,degree of neutralization of acrylic acid, and zeolite concentration on water absorbency of superabsorbent composite were investigated. The characterization of functional groups of the super absorbent polymer were performed with Infrared spectrum. The optimum conditions are as follows: zeolite 30 % , acrylamide 40 % , initiator 0.2% , crosslinker 0.04 % , and neutralization degree 70 %. The prepared composite adsorption rates could reach 413 g/g for tap water and 95 g/g for NaCl saline solution.%利用微波辅助合成聚(丙烯酸-丙烯酰胺)/沸石高吸水复合材料,研究丙烯酰胺用量、引发剂、交联剂、中和度以及沸石的添加量等对吸水倍率的影响,利用红外光谱分析高吸水材料的官能团.结果表明:当沸石、丙烯酰胺、引发剂和交联剂量分别为丙烯酸单体质量的30%、40%、0.2%和0.04%,中和度为70%时,复合材料对自来水的吸附倍率达413 g/g,对生理盐水溶液的吸水倍率迭95 g/g.

  2. Development of palm oil-based UV-curable epoxy acrylate and urethane acrylate resins for wood coating application

    Energy Technology Data Exchange (ETDEWEB)

    Tajau, Rida; Mahmood, Mohd Hilmi; Salleh, Mek Zah; Salleh, Nik Ghazali Nik [Radiation Processing Technology Division, Malaysian Nuclear Agency (Nuclear Malaysia), Bangi, 43000 Kajang, Selangor (Malaysia); Ibrahim, Mohammad Izzat [Faculty of Science, University of Malaya (UM), 50603 Kuala Lumpur (Malaysia); Yunus, Nurulhuda Mohd [Faculty of Science and Technology, National University Malaysia (UKM), 43600 Bangi, Selangor (Malaysia)

    2014-02-12

    The trend of using renewable sources such as palm oil as raw material in radiation curing is growing due to the demand from the market to produce a more environmental friendly product. In this study, the radiation curable process was done using epoxy acrylate and urethane acrylate resins which are known as epoxidised palm olein acrylate (EPOLA) and palm oil based urethane acrylate (POBUA), respectively. The purpose of the study was to investigate curing properties and the application of this UV-curable palm oil resins for wood coating. Furthermore, the properties of palm oil based coatings are compared with the petrochemical-based compound such as ebecryl (EB) i.e. EB264 and EB830. From the experiment done, the resins from petrochemical-based compounds resulted higher degree of crosslinking (up to 80%) than the palm oil based compounds (up to 70%), where the different is around 10-15%. The hardness property from this two type coatings can reached until 50% at the lower percentage of the oligomer. However, the coatings from petrochemical-based have a high scratch resistance as it can withstand at least up to 3.0 Newtons (N) compared to the palm oil-based compounds which are difficult to withstand the load up to 1.0 N. Finally, the test on the rubber wood substrate showed that the coatings containing benzophenone photoinitiator give higher adhesion property and their also showed a higher glosiness property on the glass substrate compared to the coatings containing irgacure-819 photoinitiator. This study showed that the palm oil coatings can be a suitable for the replacement of petrochemicals compound for wood coating. The palm oil coatings can be more competitive in the market if the problems of using high percentage palm oil oligomer can be overcome as the palm oil price is cheap enough.

  3. Development of palm oil-based UV-curable epoxy acrylate and urethane acrylate resins for wood coating application

    Science.gov (United States)

    Tajau, Rida; Ibrahim, Mohammad Izzat; Yunus, Nurulhuda Mohd; Mahmood, Mohd Hilmi; Salleh, Mek Zah; Salleh, Nik Ghazali Nik

    2014-02-01

    The trend of using renewable sources such as palm oil as raw material in radiation curing is growing due to the demand from the market to produce a more environmental friendly product. In this study, the radiation curable process was done using epoxy acrylate and urethane acrylate resins which are known as epoxidised palm olein acrylate (EPOLA) and palm oil based urethane acrylate (POBUA), respectively. The purpose of the study was to investigate curing properties and the application of this UV-curable palm oil resins for wood coating. Furthermore, the properties of palm oil based coatings are compared with the petrochemical-based compound such as ebecryl (EB) i.e. EB264 and EB830. From the experiment done, the resins from petrochemical-based compounds resulted higher degree of crosslinking (up to 80%) than the palm oil based compounds (up to 70%), where the different is around 10-15%. The hardness property from this two type coatings can reached until 50% at the lower percentage of the oligomer. However, the coatings from petrochemical-based have a high scratch resistance as it can withstand at least up to 3.0 Newtons (N) compared to the palm oil-based compounds which are difficult to withstand the load up to 1.0 N. Finally, the test on the rubber wood substrate showed that the coatings containing benzophenone photoinitiator give higher adhesion property and their also showed a higher glosiness property on the glass substrate compared to the coatings containing irgacure-819 photoinitiator. This study showed that the palm oil coatings can be a suitable for the replacement of petrochemicals compound for wood coating. The palm oil coatings can be more competitive in the market if the problems of using high percentage palm oil oligomer can be overcome as the palm oil price is cheap enough.

  4. Curaua fiber reinforced high-density polyethylene composites: effect of impact modifier and fiber loading

    OpenAIRE

    Jaqueline Albano de Morais; Renan Gadioli; Marco-Aurelio De Paoli

    2016-01-01

    Abstract Short fibers are used in thermoplastic composites to increase their tensile and flexural resistance; however, it often decreases impact resistance. Composites with short vegetal fibers are not an exception to this behavior. The purpose of this work is to produce a vegetal fiber reinforced composite with improved tensile and impact resistance in relation to the polymer matrix. We used poly(ethylene-co-vinyl acetate), EVA, to recover the impact resistance of high density polyethylene, ...

  5. Experimental Investigation on Laminated Composite Leaf springs Subjected to Cyclic Loading

    OpenAIRE

    Rajesh, S.; G.B.Bhaskar

    2014-01-01

    An automobile industry have an interest in replacement of conventional leaf spring with composite leaf spring to get better performance with less weight. This paper deals with by replacing the conventional leaf spring with composite leaf spring. The dimensions of an existing conventional steel leaf spring of a light commercial vehicle were taken to fabricate the special die which is further used to manufacture the composite leaf spring. A single leaf with constant cross sectional area similar...

  6. Carbonaceous composition changes of heavy-duty diesel engine particles in relation to biodiesels, aftertreatments and engine loads

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Man-Ting; Chen, Hsun-Jung [Department of Environmental Engineering, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung 40254, Taiwan (China); Young, Li-Hao, E-mail: lhy@mail.cmu.edu.tw [Department of Occupational Safety and Health, China Medical University, 91 Hsueh-Shih Road, Taichung 40402, Taiwan (China); Yang, Hsi-Hsien [Department of Environmental Engineering and Management, Chaoyang University of Technology, 168, Jifeng E. Road, Wufeng District, Taichung 41349, Taiwan (China); Tsai, Ying I. [Department of Environmental Engineering and Science, Chia Nan University of Pharmacy and Science, 60, Sec. 1, Erren Rd., Rende District, Tainan 71710, Taiwan (China); Wang, Lin-Chi [Department of Civil Engineering and Geomatics, Cheng Shiu University, 840, Chengcing Road, Niaosong District, Kaohsiung 83347, Taiwan (China); Lu, Jau-Huai [Department of Mechanical Engineering, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung 40254, Taiwan (China); Chen, Chung-Bang [Fuel Quality and Engine Performance Research, Refining and Manufacturing Research Institute, Chinese Petroleum Corporation, 217, Minsheng S. Road, West District, Chiayi 60051, Taiwan (China)

    2015-10-30

    Highlights: • We study particulate OC and EC under 3 fuels, 2 aftertreatments and 4 engine loads. • Negligible to minor OC and EC changes with low, ultralow sulfur and 10% biodiesels. • Moderate reductions of EC and particularly OC from diesel oxidation catalyst (DOC). • Large reductions of OC and particularly EC from DOC plus diesel particulate filter. • Highest at idle, whereas OC decreases but EC increases from low to high load. - Abstract: Three biodiesels and two aftertreatments were tested on a heavy-duty diesel engine under the US FTP transient cycle and additional four steady engine loads. The objective was to examine their effects on the gaseous and particulate emissions, with emphasis given to the organic and elemental carbon (OC and EC) in the total particulate matter. Negligible differences were observed between the low-sulfur (B1S50) and ultralow-sulfur (B1S10) biodiesels, whereas small reductions of OC were identified with the 10% biodiesel blend (B10). The use of diesel oxidation catalyst (DOC1) showed moderate reductions of EC and particularly OC, resulting in the OC/EC ratio well below unity. The use of DOC plus diesel particulate filter (DOC2+DPF) yielded substantial reductions of OC and particularly EC, resulting in the OC/EC ratio well above unity. The OC/EC ratios were substantially above unity at idle and low load, whereas below unity at medium and high load. The above changes in particulate OC and EC are discussed with respect to the fuel content, pollutant removal mechanisms and engine combustion conditions. Overall, the present study shows that the carbonaceous composition of PM could change drastically with engine load and aftertreatments, and to a lesser extent with the biodiesels under study.

  7. Compression creep rupture of an E-glass/vinyl ester composite subjected to combined mechanical and fire loading conditions

    Science.gov (United States)

    Boyd, Steven Earl

    Polymer matrix composites are seeing increasing use in structural systems (e.g. ships, bridges) and require a quantitative basis for describing their performance under combined mechanical load and fire. Although much work has been performed to characterize the flammability, fire resistance and toxicity of these composite systems, an understanding of the structural response of sandwich type structures and laminate panels under combined mechanical and thermal loads (simulating fire conditions) is still largely unavailable. Therefore a research effort to develop a model to describe the structural response of these glass/vinyl esters systems under fire loading conditions is relevant to the continuing and future application of polymer matrix composites aboard naval ships. The main goal of the effort presented here is to develop analytical models and finite element analysis methods and tools to predict limit states such as local compression failures due to micro-buckling, residual strength and times to failure for composite laminates at temperatures in the vicinity of the glass transition where failure is controlled by viscoelastic effects. Given the importance of compression loading to a structure subject to fire exposure, the goals of this work are succinctly stated as the: (a) Characterization of the non-linear viscoelastic and viscoplastic response of the E-glass/vinyl ester composite above Tg. (b) Description of the laminate compression mechanics as a function of stress and temperature including viscoelasticity. (c) Viscoelastic stress analysis of a laminated panel ([0/+45/90/-45/0] S) using classical lamination theory (CLT). Three manuscripts constitute this dissertation which is representative of the three steps listed above. First, a detailed characterization of the nonlinear thermoviscoelastic response of Vetrotex 324/Derakane 510A--40 through Tg was conducted using the Time--Temperature--Stress--Superposition Principle (TTSSP) and Zapas--Crissman model. Second

  8. Testing and Analysis of a Composite Non-Cylindrical Aircraft Fuselage Structure. Part 1; Ultimate Design Loads

    Science.gov (United States)

    Przekop, Adam; Jegley, Dawn C.; Lovejoy, Andrew E.; Rouse, Marshall; Wu, Hsi-Yung T.

    2016-01-01

    The Environmentally Responsible Aviation Project aimed to develop aircraft technologies enabling significant fuel burn and community noise reductions. Small incremental changes to the conventional metallic alloy-based 'tube and wing' configuration were not sufficient to achieve the desired metrics. One airframe concept identified by the project as having the potential to dramatically improve aircraft performance was a composite-based hybrid wing body configuration. Such a concept, however, presented inherent challenges stemming from, among other factors, the necessity to transfer wing loads through the entire center fuselage section which accommodates a pressurized cabin confined by flat or nearly flat panels. This paper discusses finite element analysis and testing of a large-scale hybrid wing body center section structure developed and constructed to demonstrate that the Pultruded Rod Stitched Efficient Unitized Structure concept can meet these challenging demands of the next generation airframes. Part I of the paper considers the five most critical load conditions, which are internal pressure only and positive and negative g-loads with and without internal pressure. Analysis results are compared with measurements acquired during testing. Performance of the test article is found to be closely aligned with predictions and, consequently, able to support the hybrid wing body design loads in pristine and barely visible impact damage conditions.

  9. A MORPHOLOGICAL STUDY OF POLY(DIVINYLBENZENE-co-ACRYLIC ACID) IN CROSSLINKING PRECIPITATION POLYMERIZATION

    Institute of Scientific and Technical Information of China (English)

    Feng Bai; Xin-lin Yang; Wen-qiang Huang

    2006-01-01

    Divinylbenzene-80 (DVB-80) and polar monomer acrylic acid (AA) having hydrogen bonding at a total monomer loading of 5 vol% were precipitated-copolymerized in a variety of organic solvents with 2,2'-azobis(isobutyronitrile) (AIBN) as initiator. The experiments were investigated from a two-dimensional matrix, i.e., the actual crosslinking degree of DVB varying from 0 to 80% and the solvent composition varying from 0 to 100% of toluene mixture with acetonitrile, when the mixture of acetonitrile and toluene was used as the reaction solvent. Under various reaction conditions, six distinct morphologies including soluble polymers, swellable microgels, coagulum, irregular microparticles, and nano-/micrometer microspheres were formed and the structures of these polymer architectures were described. A morphological map was utilized to discuss the effects of both crosslinking degree of DVB and composition of solvent on the transitions between morphology domains. The results demonstrated that the microspheres are formed by an internal contraction due to the marginal solvency of the continuous phase and the crosslinking of the polymer network through the covalent bonding from DVB as well as the interchain hydrogen-bonding between the carboxylic acid units.

  10. Curaua fiber reinforced high-density polyethylene composites: effect of impact modifier and fiber loading

    Directory of Open Access Journals (Sweden)

    Jaqueline Albano de Morais

    2016-01-01

    Full Text Available Abstract Short fibers are used in thermoplastic composites to increase their tensile and flexural resistance; however, it often decreases impact resistance. Composites with short vegetal fibers are not an exception to this behavior. The purpose of this work is to produce a vegetal fiber reinforced composite with improved tensile and impact resistance in relation to the polymer matrix. We used poly(ethylene-co-vinyl acetate, EVA, to recover the impact resistance of high density polyethylene, HDPE, reinforced with Curauá fibers, CF. Blends and composites were processed in a corotating twin screw extruder. The pure polymers, blends and composites were characterized by differential scanning calorimetry, thermogravimetry, infrared spectroscopy, scanning electron microscopy, tensile mechanical properties and Izod impact resistance. EVA used as impact modifier in the HDPE matrix exhibited a co-continuous phase and in the composites the fibers were homogeneously dispersed. The best combination of mechanical properties, tensile, flexural and impact, were obtained for the formulations of composites with 20 wt. % of CF and 20 to 40 wt. % of EVA. The composite prepared with 20 wt. % EVA and containing 30 wt. % of CF showed impact resistance comparable to pure HDPE and improved tensile and flexural mechanical properties.

  11. Effect of Filler Loading on Mechanical and Tribological Properties of Wood Apple Shell Reinforced Epoxy Composite

    Directory of Open Access Journals (Sweden)

    Ojha Shakuntala

    2014-01-01

    Full Text Available During the last century, natural fibers and particulates are used as reinforcement in polymer composite that has been continuously growing in the composite industry. This polymer matrix composite has wide range of applications in hostile environment where they are exposed to external attacks such as solid particle erosion. Also, the mechanical properties of different polymer composites show the best alternate to replace the metal material. In the present investigation, an attempt has been made to improve the mechanical and tribological behaviour of polymer matrix composite using wood apple shell particles as a filler material in polymer matrix. Also the temperature variation of the dynamic-mechanical parameters of epoxy matrix composites incorporated with 5, 10, 15, and 20 wt% of wood apple shell particles was investigated by DMA test. It is clearly observed that the incorporation of wood apple shell particles tends to increase the tensile strength, flexural strength, erosive wear resistance, and viscoelastic stiffness of the polymer composite. To validate the results, SEM of the polymer matrix composite has been studied.

  12. Curaua fiber reinforced high-density polyethylene composites: effect of impact modifier and fiber loading

    Directory of Open Access Journals (Sweden)

    Jaqueline Albano de Morais

    Full Text Available Abstract Short fibers are used in thermoplastic composites to increase their tensile and flexural resistance; however, it often decreases impact resistance. Composites with short vegetal fibers are not an exception to this behavior. The purpose of this work is to produce a vegetal fiber reinforced composite with improved tensile and impact resistance in relation to the polymer matrix. We used poly(ethylene-co-vinyl acetate, EVA, to recover the impact resistance of high density polyethylene, HDPE, reinforced with Curauá fibers, CF. Blends and composites were processed in a corotating twin screw extruder. The pure polymers, blends and composites were characterized by differential scanning calorimetry, thermogravimetry, infrared spectroscopy, scanning electron microscopy, tensile mechanical properties and Izod impact resistance. EVA used as impact modifier in the HDPE matrix exhibited a co-continuous phase and in the composites the fibers were homogeneously dispersed. The best combination of mechanical properties, tensile, flexural and impact, were obtained for the formulations of composites with 20 wt. % of CF and 20 to 40 wt. % of EVA. The composite prepared with 20 wt. % EVA and containing 30 wt. % of CF showed impact resistance comparable to pure HDPE and improved tensile and flexural mechanical properties.

  13. New fly ash TiO2 composite for the sustainable treatment of wastewater with complex pollutants load

    Science.gov (United States)

    Visa, Maria; Isac, Luminita; Duta, Anca

    2015-06-01

    The goal of this paper was to develop a new composite obtained in mild hydrothermal conditions starting from fly ash (a waste raising significant environmental problems), and TiO2. The composite was characterized through XRD, SEM/EDX, AFM, and BET surface measurements. The composite was further used for the advanced treatment of wastewaters with multiple-pollutants load. The photocatalytic efficiency of the powder composite was tested on synthetic solutions containing a heavy metal cation (copper), a dye (methyl orange), and a surfactant (sodium dodecylbenzenesulfonate), under UV and simulated solar radiation. Comparative experiments were done in systems with and without H2O2 showing a significant increase in efficiency for methyl orange removal from mono-, bi-, and tri-pollutants solutions. The process parameters were optimized and the adsorption mechanisms are discussed, outlining that adsorption is the limiting step. Experiments also outlined that homogeneous photocatalysis (using H2O2) is less efficient then the heterogeneous process using the novel composite, both under UV and simulated solar radiation.

  14. Paclitaxel-loaded poly(lactide-co-glycolide)/poly(ethylene vinyl acetate) composite for stent coating by ultrasonic atomizing spray

    Science.gov (United States)

    Yuk, Soon Hong; Oh, Keun Sang; Park, Jinah; Kim, Soon-Joong; Kim, Jung Ho; Kwon, Il Keun

    2012-04-01

    The mixture of poly(lactide-co-glycolide) (PLGA) and poly(ethylene vinyl acetate) (PEVA) forms a homogeneous liquid in an organic solvent such as tetrahydrofuran, and a phase-separated PLGA/PEVA composite can be prepared from it by evaporating the organic solvent. Exploiting this phenomenon, we designed a novel method of preparing a drug-loaded PLGA/PEVA composite and used it for coating drug-eluting stents (DESs). Paclitaxel (PTX), an anticancer drug, was chosen as a model drug. PLGA acts as a microdepot for PTX, and PEVA provides mechanical strength to the coating material. The presence of PLGA in the PLGA/PEVA composite suppressed PTX crystallization in the coating material, and PTX showed a sustained release rate over more than 30 days. The mechanical strength of the PLGA/PEVA composite was better than that of PEVA used as a control. After coating the stent with a PLGA/PEVA composite using ultrasonic atomizing spray, the morphology of the coated material was observed by scanning electron microscopy, and the release pattern of PTX was measured by high-performance liquid chromatography.

  15. Paclitaxel-loaded poly(lactide-co-glycolide)/poly(ethylene vinyl acetate) composite for stent coating by ultrasonic atomizing spray.

    Science.gov (United States)

    Yuk, Soon Hong; Oh, Keun Sang; Park, Jinah; Kim, Soon-Joong; Kim, Jung Ho; Kwon, Il Keun

    2012-04-01

    The mixture of poly(lactide-co-glycolide) (PLGA) and poly(ethylene vinyl acetate) (PEVA) forms a homogeneous liquid in an organic solvent such as tetrahydrofuran, and a phase-separated PLGA/PEVA composite can be prepared from it by evaporating the organic solvent. Exploiting this phenomenon, we designed a novel method of preparing a drug-loaded PLGA/PEVA composite and used it for coating drug-eluting stents (DESs). Paclitaxel (PTX), an anticancer drug, was chosen as a model drug. PLGA acts as a microdepot for PTX, and PEVA provides mechanical strength to the coating material. The presence of PLGA in the PLGA/PEVA composite suppressed PTX crystallization in the coating material, and PTX showed a sustained release rate over more than 30 days. The mechanical strength of the PLGA/PEVA composite was better than that of PEVA used as a control. After coating the stent with a PLGA/PEVA composite using ultrasonic atomizing spray, the morphology of the coated material was observed by scanning electron microscopy, and the release pattern of PTX was measured by high-performance liquid chromatography.

  16. A compact very wideband amplifying filter based on RTD loaded composite right/left-handed transmission lines.

    Science.gov (United States)

    Abu-Marasa, Mahmoud O Mahmoud; El-Khozondar, Hala Jarallah

    2015-01-01

    The composite right/left-handed (CRLH) transmission line (TL) is presented as a general TL possessing both left-handed (LH) and right-handed (RH) natures. RH materials have both positive permittivity and positive permeability, and LH materials have both negative permittivity and negative permeability. This paper aims to design and analyze nonlinear CRLH-TL transmission line loaded with resonant tunneling diode (RTD). The main application of this design is a very wideband and compact filter that amplifies the travelling signal. We used OrCAD and ADS software to analyze the proposed circuit. CRLH-TL consists of a microstrip line which is loaded with complementary split-rings resonators (CSRRs), series gaps, and shunt inductor connected parallel to the RTD. The designed structure possess a wide band that ranges from 5 to 10.5 GHz and amplifies signal up to 50 %. The proposed design is of interest to microwave compact component designers.

  17. Strong and tough magnesium wire reinforced phosphate cement composites for load-bearing bone replacement.

    Science.gov (United States)

    Krüger, Reinhard; Seitz, Jan-Marten; Ewald, Andrea; Bach, Friedrich-Wilhelm; Groll, Jürgen

    2013-04-01

    Calcium phosphate cements are brittle biomaterials of low bending strength. One promising approach to improve their mechanical properties is reinforcement with fibers. State of the art degradable reinforced composites contain fibers made of polymers, resorbable glass or whiskers of calcium minerals. We introduce a new class of composite that is reinforced with degradable magnesium alloy wires. Bending strength and ductility of the composites increased with aspect ratio and volume content of the reinforcements up to a maximal bending strength of 139±41MPa. Hybrid reinforcement with metal and polymer fibers (PLA) further improved the qualitative fracture behavior and gave indication of enhanced strength and ductility. Immersion tests of composites in SBF for seven weeks showed high corrosion stability of ZEK100 wires and slow degradation of the magnesium calcium phosphate cement by struvite dissolution. Finally, in vitro tests with the osteoblast-like cell line MG63 demonstrate cytocompatibility of the composite materials.

  18. Vocabulary Acquisition through Cloze Exercises, Sentence-Writing and Composition-Writing: Extending the Evaluation Component of the Involvement Load Hypothesis

    Science.gov (United States)

    Zou, Di

    2017-01-01

    This research inspects the allocation of involvement load to the evaluation component of the involvement load hypothesis, examining how three typical approaches to evaluation (cloze-exercises, sentence-writing, and composition-writing) promote word learning. The results of this research were partially consistent with the predictions of the…

  19. Experimental and Theoretical Deflections of Hybrid Composite Sandwich Panel under Four-point Bending Load

    Directory of Open Access Journals (Sweden)

    Jauhar Fajrin

    2017-03-01

    Full Text Available This paper presents a comparison of theoretical and experimental deflection of a hybrid sandwich panel under four-point bending load. The paper initially presents few basic equations developed under three-point load, followed by development of model under four-point bending load and a comparative analysis between theoretical and experimental results. It was found that the proposed model for predicting the deflection of hybrid sandwich panels provided fair agreement with the experimental values. Most of the sandwich panels showed theoretical deflection values higher than the experimental values, which is desirable in the design. It was also noticed that the introduction of intermediate layer does not contribute much to reduce the deflection of sandwich panel as the main contributor for the total deflection was the shear deformation of the core that mostly determined by the geometric of the samples and the thickness of the core.

  20. The effect of nanoclay filler loading on the flexural strength of fiber-reinforced composites

    Directory of Open Access Journals (Sweden)

    Vajihesadat Mortazavi

    2012-01-01

    Results: For groups with the same concentration of nanoparticles, PMMA-grafted filler-loaded group showed significantly higher flexural strength, except for 0.2% wt. For groups that contain PMMA-grafted nanoclay fillers, the 2% wt had the highest flexural strength value with significant difference to other subgroups. 1% wt and 2% wt showed significantly higher values compared to control (P 0.05. Flexural modulus of 2%, 5% wt PMMA-grafted and 0.5%, 1%, 2%, 5% wt unmodified nanoclay particles-loaded subgroups decreased significantly compared to control group (P < 0.05. Conclusions: PMMA-grafted nanoclay filler loading may enhance the flexural strength of FRCs. Addition of unmodified nanoparticles cannot significantly improve the flexural strength of FRCs. Addition of both unmodified and PMMA-grafted nanoclay particles in some concentrations decreased the flexural modulus.

  1. Parametric Study on the Response of Compression-Loaded Composite Shells With Geometric and Material Imperfections

    Science.gov (United States)

    Hilburger, Mark W.; Starnes, James H., Jr.

    2004-01-01

    The results of a parametric study of the effects of initial imperfections on the buckling and postbuckling response of three unstiffened thinwalled compression-loaded graphite-epoxy cylindrical shells with different orthotropic and quasi-isotropic shell-wall laminates are presented. The imperfections considered include initial geometric shell-wall midsurface imperfections, shell-wall thickness variations, local shell-wall ply-gaps associated with the fabrication process, shell-end geometric imperfections, nonuniform applied end loads, and variations in the boundary conditions including the effects of elastic boundary conditions. A high-fidelity nonlinear shell analysis procedure that accurately accounts for the effects of these imperfections on the nonlinear responses and buckling loads of the shells is described. The analysis procedure includes a nonlinear static analysis that predicts stable response characteristics of the shells and a nonlinear transient analysis that predicts unstable response characteristics.

  2. Effects of load cycling on the microleakage of beveled and nonbeveled margins in class V resin-based composite restorations.

    Science.gov (United States)

    Ameri, Hamideh; Ghavamnasiri, Marjaneh; Abdoli, Ehsan

    2010-10-14

    This study evaluated the influence of mechanical loading and thermocycling on microleakage of class V resin-based composite restorations with and without enamel bevel. Sixty class V cavity preparations measuring 3.0 mm wide (mesio-gingivally) x 2.0 mm high (occluso-gingivally) x 1.5 mm deep with the occlusal margin in enamel and the gingival margin in cementum were prepared on the buccal surfaces of human premolars using a #12 diamond round bur (Drendel and Zweiling Diamant GmbH, Lemgo, Germany) in a high-speed, water-cooled handpiece. The specimens were then divided into two groups of 30 specimens each, based on the type of enamel cavosurface margin configuration as beveled or nonbeveled (butt joint). After restoring the preparations with a flowable resin-based composite (Tetric Flow, Ivoclar Vivadent-AG, Schaan, Liechtenstein) and finishing and polishing with sequential discs (Sof-Lex Pop-on, 3M-ESPE, St. Paul, MN, USA), the teeth were stored at 37° and 100 percent humidity. Twenty-four hours later, half of the specimens in each group (nonbeveled "N" or beveled "B") were exposed to a cycling loading for 250,000 cycles to simulate occlusal loading and assigned to two subgroups (NL+ or BL+), while the remainder of the specimens in each group were only maintained in a 100-percent-humidity environment, without any cyclical loading, until tested (NL+ or BL+). The specimens were sealed with sticky wax (Kemdent, Associated Dental Products, Swindon, UK) and nail polish. The apical foramen of each tooth was sealed with sticky wax and the rest of the tooth was covered with nail varnish, except for an area within 1.0 mm around the composite restoration. To detect marginal leakage, all of the samples were stored in a 0.5 percent basic fuchsine solution for 24 hours. The specimens were then sectioned longitudinally using a low-speed diamond blade (IsoMet, Buehler Ltd., Lake Bluff, IL, USA), machined, and evaluated under 25X magnification using a stereomicroscope (M9, Wild

  3. 21 CFR 573.120 - Acrylamide-acrylic acid resin.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Acrylamide-acrylic acid resin. 573.120 Section 573... Food Additive Listing § 573.120 Acrylamide-acrylic acid resin. Acrylamide-acrylic acid resin... acrylamide with partial hydrolysis, or by copolymerization of acrylamide and acrylic acid with the greater...

  4. Monolithic F-16 Uniform Thickness Stretched Acrylic Canopy Transparency Program

    Science.gov (United States)

    1984-01-01

    Thermoforming Finite Strain Analysis Finite Element Modeling Mooney Formulation Tensile Testing Acrylic Material Properties F-16 Transparency Thinning Uniform...OF ACRYLIC TENSILE SPECIMEN ...... 8 MARC ANALYSIS OF ACRYLIC HEMISPHERE ............ 12 IV ACRYLIC MATERIAL PROPERTIES AT THERMOFORMING TEMPERATURES...properties (necessary for finite element stress analysis work) were generated at temperatures in the range of thermoforming . A finite element code

  5. Nail Damage (Severe Onychodystrophy) Induced by Acrylate Glue: Scanning Electron Microscopy and Energy Dispersive X-Ray Investigations

    Science.gov (United States)

    Pinteala, Tudor; Chiriac, Anca Eduard; Rosca, Irina; Larese Filon, Francesca; Pinteala, Mariana; Chiriac, Anca; Podoleanu, Cristian; Stolnicu, Simona; Coros, Marius Florin; Coroaba, Adina

    2017-01-01

    Background Scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) techniques have been used in various fields of medical research, including different pathologies of the nails; however, no studies have focused on obtaining high-resolution microscopic images and elemental analysis of disorders caused by synthetic nails and acrylic adhesives. Methods Damaged/injured fingernails caused by the use of acrylate glue and synthetic nails were investigated using SEM and EDX methods. Results SEM and EDX proved that synthetic nails, acrylic glue, and nails damaged by contact with acrylate glue have a different morphology and different composition compared to healthy human nails. Conclusions SEM and EDX analysis can give useful information about the aspects of topography (surface sample), morphology (shape and size), hardness or reflectivity, and the elemental composition of nails. PMID:28232921

  6. Eco-friendly Crosslinking Agent for Acid Functional Acrylic Resin

    Directory of Open Access Journals (Sweden)

    Archana Shah

    2009-01-01

    Full Text Available Oil from J. multifida was extracted and it was first converted into N,N-bis(2-hydroxyethyl Jatropha fatty amide (HEJFA. HEJFA has been synthesized by reaction between Jatropha oil and diethanol amine in presence of zinc oxide as a catalyst. The reaction is relatively rapid and proceeded to high yield at 200±5 OC. The resulting HEJFA was used to formulate thermosetting coating compositions. Films were cured at ambient (air drying and elevated (stove drying temperatures using N, N-bis(2-hydroxyethyl Jatropha fatty amide (HEJFA as eco-friendly crosslinking agent for acrylic resin. The coating performance of the various compositions was tested by measurement of scratch hardness, impact strength and chemical resistance. The results show better performance of the HEJFA based compositions compared to butylated melamine formaldehyde (MF based compositions.

  7. Poly(meth)acrylate-based coatings.

    Science.gov (United States)

    Nollenberger, Kathrin; Albers, Jessica

    2013-12-05

    Poly(meth)acrylate coatings for pharmaceutical applications were introduced in 1955 with the launch of EUDRAGIT(®) L and EUDRAGIT(®) S, two types of anionic polymers. Since then, by introducing various monomers into their polymer chains and thus altering their properties, diverse forms with specific characteristics have become available. Today, poly(meth)acrylates function in different parts of the gastrointestinal tract and/or release the drug in a time-controlled manner. This article reviews the properties of various poly(meth)acrylates and discusses formulation issues as well as application possibilities.

  8. Occupational respiratory disease caused by acrylates.

    Science.gov (United States)

    Savonius, B; Keskinen, H; Tuppurainen, M; Kanerva, L

    1993-05-01

    Acrylates are compounds used in a variety of industrial fields and their use is increasing. They have many features which make them superior to formerly used chemicals, regarding both their industrial use and their possible health effects. Contact sensitization is, however, one of their well known adverse health effects but they may also cause respiratory symptoms. We report on 18 cases of respiratory disease, mainly asthma, caused by different acrylates, 10 cases caused by cyanoacrylates, four by methacrylates and two cases by other acrylates.

  9. THE BEHAVIOR OF TWO COLLINEAR CRACKS IN MAGNETO-ELECTRO-ELASTIC COMPOSITES UNDER ANTI-PLANE SHEAR STRESS LOADING

    Institute of Scientific and Technical Information of China (English)

    Sun Yuguo; Zhou Zhengong

    2005-01-01

    In this paper, the behavior of two collinear cracks in magneto-electro-elastic composite material under anti-plane shear stress loading is studied by the Schmidt method for permeable electric boundary conditions. By using the Fourier transform, the problem can be solved with a set of triple integral equations in which the unknown variable is the jump of displacements across the crack surfaces. In solving the triple integral equations, the unknown variable is expanded in a series of Jacobi polynomials. Numerical solutions are obtained. It is shown that the stress field is independent of the electric field and the magnetic flux.

  10. Curcumin-Loaded Chitosan/Gelatin Composite Sponge for Wound Healing Application

    Directory of Open Access Journals (Sweden)

    Van Cuong Nguyen

    2013-01-01

    Full Text Available Three composite sponges were made with 10% of curcumin and by using polymers, namely, chitosan and gelatin with various ratios. The chemical structure and morphology were evaluated by FTIR and SEM. These sponges were evaluated for water absorption capacity, antibacterial activity, in vitro drug release, and in vivo wound healing studies by excision wound model using rabbits. The in vivo study presented a greater wound closure in wounds treated with curcumin-composite sponge than those with composite sponge without curcumin and untreated group. These obtained results showed that combination of curcumin, chitosan and gelatin could improve the wound healing activity in comparison to chitosan, and gelatin without curcumin.

  11. Effect of fiber loading on flexural strength of hybrid sisal/hemp-HDPE composites

    Science.gov (United States)

    Aggarwal, Lakshya; Sinha, Shishir; Gupta, V. K.

    2015-05-01

    The continuing demand for sustainable materials and increasing environmental concerns have led to intense research in the field of natural fiber reinforced composites. Natural fibers are favored over synthetic fibers as reinforcement due to positive environmental benefits such as raw material utilization at source and easy disposable of the biodegradable fiber. In the present work, we have investigated flexural behavior of hybrid natural fiber reinforced HDPE composites. The matrix comprises of 50-50 ratio of virgin and recycled HDPE and the content of fibers (sisal and hemp) in the composite is varied from 10 to 30%. The natural fibers were mercerized with NaOH solution and chemically treated with maleic anhydride. The flexural specimens were prepared by injection moulding process and the testing was conducted in accordance to ASTM D790 standards. It is revealed that the flexural strength of the hybrid composite increases with the increase in fibers content when compared to specimen containing 100% HDPE.

  12. Development and physicochemical characterization of alginate composite film loaded with simvastatin as a potential wound dressing.

    Science.gov (United States)

    Rezvanian, Masoud; Amin, Mohd Cairul Iqbal Mohd; Ng, Shiow-Fern

    2016-02-10

    Previously, studies have demonstrated that topical application of simvastatin can promote wound healing in diabetic mice via augmentation of angiogenesis and lymphangiogenesis. This study aimed to formulate and characterize simvastatin in alginate-based composite film wound dressings. Biopolymers used for composite films were sodium alginate blended with pectin or gelatin. The films were prepared and characterized based on their physical properties, surface morphology, mechanical strength and rheology. Then, in vitro drug releases from the films were investigated and, finally, the cell viability assay was performed to assess the cytotoxicity profile. From the pre-formulation studies, alginate/pectin composite film showed to possess desirable wound dressing properties and superior mechanical properties. The in vitro drug release profile revealed that alginate/pectin film produced a controlled release drug profile, and cell viability assay showed that the film was non-toxic. In summary, alginate/pectin composite film is suitable to be formulated with simvastatin as a potential wound dressing.

  13. EFFECT OF FILLER LOADING ON PHYSICAL AND FLEXURAL PROPERTIES OF RAPESEED STEM/PP COMPOSITES

    Directory of Open Access Journals (Sweden)

    Seyed Majid Zabihzadeh

    2011-03-01

    Full Text Available The objective of the study is to develop a new filler for the production of natural filler thermoplastic composites using the waste rapeseed stalks. The long-term water absorption and thickness swelling behaviors and flexural properties of rapeseed filled polypropylene (PP composites were investigated. Three different contents of filler were tested: 30, 45, and 60 wt%. Results of long-term hygroscopic tests indicated that by the increase in filler content from 30% to 60%, water diffusion absorption and thickness swelling rate parameter increased. A swelling model developed by Shi and Gardner can be used to quantify the swelling rate. The increasing of filler content reduced the flexural strength of the rapeseed/PP composites significantly. In contrast to the flexural strength, the flexural modulus improved with increasing the filler content. The flexural properties of these composites were decreased after the water uptake, due to the effect of the water molecules.

  14. Advanced surface chemical analysis of continuously manufactured drug loaded composite pellets

    OpenAIRE

    2016-01-01

    The aim of the present study was to develop and characterise polymeric composite pellets by means of continuous melt extrusion techniques. Powder blends of a steroid hormone (SH) as a model drug and either ethyl cellulose (EC N10 and EC P7 grades) or hydroxylpropyl methylcellulose (HPMC AS grade) as polymeric carrier were extruded using a Pharma 11 mm twin screw extruder in a continuous mode of operation to manufacture extruded composite pellets of 1 mm length. Molecular modelling study using...

  15. Preparation and characterization of carbonyl iron/glass composite absorber as matched load for isolator

    Science.gov (United States)

    Feng, Yongbao; Li, Yujiao; Qiu, Tai

    2012-09-01

    Composite absorbers made from 66 wt% carbonyl iron and 34 wt% low melting point glass powder were prepared by a pressureless sintering technique in a nitrogen atmosphere. Apparent porosity and bending strength of the as-prepared composites were investigated. The microstructure, heat resisting properties and electromagnetic properties were characterized by scanning electron microscopy, thermal gravimetric analysis-differential scanning calorimetry and vector network analyzer. The results show that the carbonyl iron/glass composite absorbers were difficult to densify. As the sintering temperature and soaking time increased, the apparent porosity first decreased and then increased, whereas the bending strength showed the opposite change. The composite absorber sintered at 520 °C for 40 min achieved the minimum apparent porosity of 13.08% and the highest bending strength of 52 MPa. Compared to the carbonyl iron/silicone rubber absorber, the carbonyl iron/glass composite absorber exhibited better heat resisting properties, and the initial oxidation temperature was increased about 200 °C. The composite absorber with a thickness of 1.25 mm showed a good microwave absorbing property in 8-12 GHz.

  16. The effect of load cycling on microleakage of low shrinkage methacrylate base composite compared with silorane base composite and SEM evaluation of marginal integrity

    Directory of Open Access Journals (Sweden)

    Hamid Kermanshah

    2013-04-01

    Full Text Available Background and Aims: Marginal seal in class V cavity and determination of the best restorative material in reducing microleakage is of great concern in operative dentistry. The aim of this study was to evaluate the effect of load cycling on the microleakage of low shrinkage composites compared with methacrylate-based composites with low shirinkage rate in class V cavity preparation. Marginal integrity of these materials was assessed using scanning electron microscope (SEM. Materials and Methods: In this in vitro study, class V cavity preparations were made on the buccal and lingual surfaces of 48 human premolars and molars (96 cavities. The specimens were divided into four groups each containing 12 teeth (24 cavities: group 1 (Kalore-GC+ G-Bond , group 2 (Futurabond NR+Grandio, group 3(All Bond SE+ Aelite LS Posterior, group 4 (LS System Adhesive Primer & Bond+Filtek P90. All the specimens were thermocycled for 2000 cycles (5-50oC. In each group, half of the specimens (n=12 were subjected to 200,000 cycles of loading at 80 N. Epoxy resin replicas of 32 specimens (4 restorations in each subgroup were evaluated using SEM and the interfacial gaps were measured. Finally, the teeth were immersed in 0.5% basic fuchsin dye for 24 hours at 370C, then sectioned and observed under stereomicroscope. The data were analyzed using Kruskal-Wallis and Mann-Whitney U tests and the comparison between occlusal and gingival microleakage was made with Wilcoxon test. Results: Within unloaded or loaded specimens, there were no significant differences in microleakage among four groups on the occlusal margins (P>0.05. But there were statistically significant differences in microleakage between silorane and Aelite on the gingival margins (P0.05. Conclusion: Silorane did not perform better than the conventional low shrinkage methacrylate-based composite in terms of sealing ability (except Aelite. Cyclic loading did not increase the extent of leakage in any groups.

  17. Fluid-structure interaction and its effect on the performance of composite structures under air-blast loading

    Directory of Open Access Journals (Sweden)

    E Wang

    2016-09-01

    Full Text Available Three material systems: E-glass Vinyl-Ester (EVE composites, sandwich composites with EVE facesheet and monolithic foam core (2 different core thicknesses, and monolithic aluminum alloy plates, were subjected to shock wave loading to study their blast response and fluid-structure interaction behaviors. High-speed photography systems were utilized to obtain the real-time side-view and back face deformation images. A 3-D Digital Image Correlation (DIC technique was used to analyze the real-time back face displacement fields and subsequently obtain the characteristic fluid-structure interaction time. The reflected pressure profiles and the deflection of the back face center point reveal that the areal density plays an important role in the fluid-structure interaction. The predictions from Taylor's model (classical solution, does not consider the compressibility and model by Wang et al. (considers the compressibility were compared with the experimental results. These results indicated that the model by Wang et al. can predict the experimental results accurately, especially during the characteristic fluid-structure interaction time. Further study revealed that the fluid-structure interaction between the fluid and the sandwich composites cannot be simplified as the fluid-structure interaction between the fluid and the facesheet. Also, it was observed that the core thickness affects the fluid-structure interaction behavior of sandwich composites.

  18. Direct Pen Writing of Adhesive Particle-Free Ultrahigh Silver Salt-Loaded Composite Ink for Stretchable Circuits.

    Science.gov (United States)

    Hu, Mingjun; Cai, Xiaobing; Guo, Qiuquan; Bian, Bin; Zhang, Tengyuan; Yang, Jun

    2016-01-26

    In this article, we describe a writable particle-free ink for fast fabrication of highly conductive stretchable circuits. The composite ink mainly consists of soluble silver salt and adhesive rubber. Low toxic ketone was employed as the main solvent. Attributed to ultrahigh solubility of silver salt in short-chain ketone and salt-assisted dissolution of rubber, the ink can be prepared into particle-free transparent solution. As-prepared ink has a good chemical stability and can be directly filled into ballpoint pens and use to write on different substrates to form well adhesive silver salt-based composite written traces as needed. As a result of high silver salt loading, the trace can be converted into highly conductive silver nanoparticle-based composites after in situ reduction. Because of the introduction of adhesive elastomeric rubber, the as-formed conductive composite written trace can not only maintain good adhesion to various substrates but also show good conductivity under various deformations. The conductivity of written traces can be enhanced by repeated writing-reduction cycles. Different patterns can be fabricated by either direct handwriting or hand-copying. As proof-of-concept demonstrations, a typical handwriting heart-like circuit was fabricated to show its capability to work under different deformations, and a pressure-sensitive switch was also manufactured to present pressure-dependent change of resistance.

  19. Study on the laser irradiation effects on carbon fiber reinforced resin composite subjected to tangential gas flow loading

    Science.gov (United States)

    Chen, Minsun; Jiang, Houman; Jiao, Luguang; Li, Junshen; Liu, Zejin

    2013-05-01

    The irradiation effects of 976nm continuous-wave laser on carbon fiber reinforced E-51 resin composite is studied experimentally, with a 0.4Ma tangential airflow or 0.4Ma tangential nitrogen gas flow on the target surface. In order to simulate the thermal response of fiber reinforced resin composite materials subjected to combined laser and tangential gas flow loading, a three-dimensional thermal response model of resin composite materials is developed. In the model, the thermal decomposition of resin is described by a multi-step model. The motion of the decomposition gas is assumed to be one-dimensional, for the case that the laser spot is significantly larger than the thickness of the sample. According the above assumption, the flow of the decomposition gas is considered in the three-dimensional model without introducing any mechanical quantities. The influences of the tangential gas flow, the outflow of the thermal decomposition gas and the ablation-including phase change ablation or oxidative ablation-of the surface material on the laser irradiation effects are included in the surface boundary conditions. The three-dimensional thermal response model is calculated numerically by use of the modified smooth particle hydrodynamics (MSPH) method which is coded with FORTRAN. The model is tested by experimentally measuring the temperature profiles during carbon fiber reinforced E-51 resin composite subjected to combined laser and tangential gas flow. The predicted temperature profiles are in good agreement with experimental temperatures obtained using thermocouples.

  20. The influence of framework design on the load-bearing capacity of laboratory-made inlay-retained fibre-reinforced composite fixed dental prostheses

    NARCIS (Netherlands)

    F. Keulemans; L.V.J. Lassilla; S. Garoushi; P.K. Vallittu; C.J. Kleverlaan; A.J. Feilzer

    2009-01-01

    Delamination of the veneering composite is frequently encountered with fibre-reinforced composite (FRC) fixed dental prosthesis (FDPs). The aim of this study is to evaluate the influence of framework design on the load-bearing capacity of laboratory-made three-unit inlay-retained FRC-FDPs. Inlay-ret

  1. Effect of type and loading of surface-modifying agent on mechanical properties of modified geothermal scale powder/stereolithography polymer composite

    Science.gov (United States)

    Tilendo, A. C.; Pajarito, B. B.

    2017-05-01

    This study investigated the effect of stearic acid (SA), glycerol monostearate (GMS) and 3-trimethoxysilylpropyl methacrylate (TSPM) at varied loadings on the hardness and flexural properties of modified geothermal scale powder (GSP)/stereolithography (SLA) polymer composite. TSPM-modified GSP/SLA composite has the highest value of hardness due to increased filler dispersion and crystallinity. Hardness of GSP/SLA composite increases with loading of surface-modifying agent due to increase filler dispersion. Pronounced effect of surface modification to flexural modulus is observed. While low loading of SA and GMS leads to reduction of flexural modulus, increasing loading enhances the said property. Further increase of SA deteriorates the property. TSPM-modified GSP enhances the modulus due to increased crystalline phase of the system owing to TSPM copolymerization. Likewise, addition of SA and GMS increases flexural strength due to efficient reduction of filler agglomerates. However, unreacted TSPM produces weak interfaces and poor adhesion between GSP and SLA matrix.

  2. Innovative design of composite structures: Axisymmetric deformations of unsymmetrically laminated cylinders loaded in axial compression

    Science.gov (United States)

    Hyer, M. W.; Paraska, P. J.

    1990-01-01

    The study focuses on the axisymmetric deformation response of unsymmetrically laminate cylinders loaded in axial compression by known loads. A geometrically nonlinear analysis is used. Though buckling is not studied, the deformations can be considered to be the prebuckling response. Attention is directed at three 16 layer laminates: a (90 sub 8/0 sub 8) sub T; a (0 sub 8/90 sub 8) sub T and a (0/90) sub 4s. The symmetric laminate is used as a basis for comparison, while the two unsymmetric laminates were chosen because they have equal but opposite bending-stretching effects. Particular attention is given to the influence of the thermally-induced preloading deformations that accompany the cool-down of any unsymmetric laminate from the consolidation temperature. Simple support and clamped boundary conditions are considered. It is concluded that: (1) The radial deformations of an unsymmetric laminate are significantly larger than the radial deformations of a symmetric laminate, although for both symmetric and unsymmetric laminates the large deformations are confined to a boundary layer near the ends of the cylinder; (2) For this nonlinear problem the length of the boundary layer is a function of the applied load; (3) The sign of the radial deformations near the supported end of the cylinder depends strongly on the sense (sign) of the laminate asymmetry; (4) For unsymmetric laminates, ignoring the thermally-induced preloading deformations that accompany cool-down results in load-induced deformations that are under predicted; and (5) The support conditions strongly influence the response but the influence of the sense of asymmetry and the influence of the thermally-induced preloading deformations are independent of the support conditions.

  3. Effects of Carbon Nanomaterial Reinforcement on Composite Joints Under Cyclic and Impact Loading

    Science.gov (United States)

    2012-03-01

    Molding ( VARTM ) technique with 7.5g/m2 of MWCNTs or CNFs dispersed at the joint interface ahead of the crack tip. The test coupons were loaded in 3...fabricated via Vacuum Assisted Resin Transfer Molding ( VARTM ) technique with 7.5g/m 2 of MWCNTs or CNFs dispersed at the joint interface ahead of... VARTM setup in the laboratory ........................................................................9 Figure 7. Arrangement of the various layers

  4. Effect of Shear Resistance on Flexural Debonding Load-Carrying Capacity of RC Beams Strengthened with Externally Bonded FRP Composites

    Directory of Open Access Journals (Sweden)

    Guibing Li

    2014-05-01

    Full Text Available Debonding failure is the main failure mode in flexurally strengthened reinforced concrete beams by externally bonded or near surface mounted fibre reinforced polymer (FRP composites. It is believed that FRP debonding will be initiated if the shear stress on the concrete-FRP interface reaches the tensile strength of concrete. However, it was found through experimental and analytical studies that the debonding mechanism of FRP composites has the potential of shear failure in combination with debonding failure. Moreover, the shear failure probably influences the debonding failure. Presently, there are very little experimental and analytical studies to investigate the influence of shear resistance of reinforced concrete (RC beam on FRP debonding failure. The current study investigates and analyzes the effect of shear resistance on FRP debonding failure based on test results. The analytical results show that the shear resistance of RC beam has a great effect on flexural debonding load-carrying capacity of FRP-strengthened RC beam. The influence of shear resistance on flexural debonding load-carrying capacity must be fully considered in flexural strengthening design of RC beams.

  5. Gel time of calcium acrylate grouting material

    Institute of Scientific and Technical Information of China (English)

    韩同春

    2004-01-01

    Calcium acrylate is a polymerized grout, and can polymerize in an aqueous solution. The polymerizationreaction utilizes ammonium persulfate as a catalyst and sodium thiosulfate as the activator. Based on the theory of reactionkinetics, this study on the relation between gel time and concentration of activator and catalyst showed that gel time ofcalcium acrylate is inversely proportional to activator and catalyst concentration. A formula of gel time is proposed, and anexample is provided to verify the proposed formula.

  6. Gel time of calcium acrylate grouting material

    Institute of Scientific and Technical Information of China (English)

    韩同春

    2004-01-01

    Calcium acrylate is a polymerized grout, and can polymerize in an aqueous solution. The polymerization reaction utilizes ammonium persulfate as a catalyst and sodium thiosulfate as the activator. Based on the theory of reaction kinetics, this study on the relation between gel time and concentration of activator and catalyst showed that gel time of calcium acrylate is inversely proportional to activator and catalyst concentration. A formula of gel time is proposed, and an example is provided to verify the proposed formula.

  7. Rapid Output Growth of Special Acrylic Esters

    Institute of Scientific and Technical Information of China (English)

    Wang Lianzhi

    2007-01-01

    @@ Acrylic esters are usually classified into general-purpose varieties and special varieties. The production and application of general-purpose varieties is already quite matured in the world and their output growth tends to be flat. Owing to the development of coatings, electronics, automobiles,textiles, printing and construction sectors, especially the application of radiation curing technology in various sectors, special acrylic esters have developed rapidly.

  8. Experimental and numerical investigations of textile hybrid composites subjected to low velocity impact loadings.

    Science.gov (United States)

    Chandekar, Gautam S; Kelkar, Ajit D

    2014-01-01

    In the present study experimental and numerical investigations were carried out to predict the low velocity impact response of four symmetric configurations: 10 ply E Glass, 10 ply AS4 Carbon, and two Hybrid combinations with 1 and 2 outer plies of E Glass and 8 and 6 inner plies of Carbon. All numerical investigations were performed using commercial finite element software, LS-DYNA. The test coupons were manufactured using the low cost Heated Vacuum Assisted Resin Transfer Molding (H-VARTM©) technique. Low velocity impact testing was carried out using an Instron Dynatup 8250 impact testing machine. Standard 6 × 6 Boeing fixture was used for all impact experiments. Impact experiments were performed over progressive damage, that is, from incipient damage till complete failure of the laminate in six successive impact energy levels for each configuration. The simulation results for the impact loading were compared with the experimental results. For both nonhybrid configurations, it was observed that the simulated results were in good agreement with the experimental results, whereas, for hybrid configurations, the simulated impact response was softer than the experimental response. Maximum impact load carrying capacity was also compared for all four configurations based on their areal density. It was observed that Hybrid262 configuration has superior impact load to areal density ratio.

  9. Experimental and Numerical Investigations of Textile Hybrid Composites Subjected to Low Velocity Impact Loadings

    Directory of Open Access Journals (Sweden)

    Gautam S. Chandekar

    2014-01-01

    Full Text Available In the present study experimental and numerical investigations were carried out to predict the low velocity impact response of four symmetric configurations: 10 ply E Glass, 10 ply AS4 Carbon, and two Hybrid combinations with 1 and 2 outer plies of E Glass and 8 and 6 inner plies of Carbon. All numerical investigations were performed using commercial finite element software, LS-DYNA. The test coupons were manufactured using the low cost Heated Vacuum Assisted Resin Transfer Molding (H-VARTM© technique. Low velocity impact testing was carried out using an Instron Dynatup 8250 impact testing machine. Standard 6 × 6 Boeing fixture was used for all impact experiments. Impact experiments were performed over progressive damage, that is, from incipient damage till complete failure of the laminate in six successive impact energy levels for each configuration. The simulation results for the impact loading were compared with the experimental results. For both nonhybrid configurations, it was observed that the simulated results were in good agreement with the experimental results, whereas, for hybrid configurations, the simulated impact response was softer than the experimental response. Maximum impact load carrying capacity was also compared for all four configurations based on their areal density. It was observed that Hybrid262 configuration has superior impact load to areal density ratio.

  10. Experimental and Numerical Investigations of Textile Hybrid Composites Subjected to Low Velocity Impact Loadings

    Science.gov (United States)

    Chandekar, Gautam S.; Kelkar, Ajit D.

    2014-01-01

    In the present study experimental and numerical investigations were carried out to predict the low velocity impact response of four symmetric configurations: 10 ply E Glass, 10 ply AS4 Carbon, and two Hybrid combinations with 1 and 2 outer plies of E Glass and 8 and 6 inner plies of Carbon. All numerical investigations were performed using commercial finite element software, LS-DYNA. The test coupons were manufactured using the low cost Heated Vacuum Assisted Resin Transfer Molding (H-VARTM©) technique. Low velocity impact testing was carried out using an Instron Dynatup 8250 impact testing machine. Standard 6 × 6 Boeing fixture was used for all impact experiments. Impact experiments were performed over progressive damage, that is, from incipient damage till complete failure of the laminate in six successive impact energy levels for each configuration. The simulation results for the impact loading were compared with the experimental results. For both nonhybrid configurations, it was observed that the simulated results were in good agreement with the experimental results, whereas, for hybrid configurations, the simulated impact response was softer than the experimental response. Maximum impact load carrying capacity was also compared for all four configurations based on their areal density. It was observed that Hybrid262 configuration has superior impact load to areal density ratio. PMID:24719573

  11. Lateral load-carrying capacity analyses of composite shear walls with double steel plates and filled concrete with binding bars

    Institute of Scientific and Technical Information of China (English)

    周德源; 刘凌飞; 朱立猛

    2016-01-01

    A method is developed to predict the lateral load-carrying capacity of composite shear walls with double steel plates and filled concrete with binding bars (SCBs). Nonlinear finite element models of SCBs were established by using the finite element tool, Abaqus. Tie constraints were used to connect the binding bars and the steel plates. Surface-to-surface contact provided by the Abaqus was used to simulate the interaction between the steel plate and the core concrete. The established models could predict the lateral load-carrying capacity of SCBs with a reasonable degree of accuracy. A calculation method was developed by superposition principle to predict the lateral load-carrying capacity of SCBs for the engineering application. The concrete confined by steel plates and binding bars is under multi-axial compression; therefore, its shear strength was calculated by using the Guo-Wang concrete failure criterion. The shear strength of the steel plates of SCBs was calculated by using the von Mises yielding criterion without considering buckling. Results of the developed method are in good agreement with the testing and finite element results.

  12. Structure and Photocatalytic Properties of Mn-Doped TiO₂ Loaded on Wood-Based Activated Carbon Fiber Composites.

    Science.gov (United States)

    Ma, Xiaojun; Zhou, Wanru; Chen, Yin

    2017-06-09

    Mn-doped TiO₂ loaded on wood-based activated carbon fiber (Mn/TiO₂-WACF) was prepared by sol-gel and impregnation method using MnSO₄·H₂O as manganese source. The structure of Mn/TiO₂-WACF was characterized by SEM, XRD, FTIR, N₂ adsorption and UV-Vis, and its photocatalytic activity for methylene blue degradation was investigated. Results show that Mn-doped TiO₂ were loaded on the surface of wood-based activated carbon fiber with high-development pore structures. The crystallite sizes of Mn-doped TiO₂ in composites were smaller than that of the undoped samples. With an increase of Mn doping content, Ti-O bending vibration intensity of Mn/TiO₂-WACF increased and then decreased. Moreover, Ti-O-Ti and Ti-O-Mn absorption peaks increased upon doping of Mn. Mn/TiO₂-WACF with low specific surface area, and pore volume was improved at 3.5-6.0 nm of mesopore distributions due to the Mn-doped TiO₂ load. In addition, the UV-Vis showed that Mn/TiO₂-WACF (photodegradation rate of 96%) has higher photocatalytic activity than the undoped samples for methylene blue degradation under visible light irradiation.

  13. A Numerical Simulation of Time-Dependent Interface Failure Under Shear and Compressive Loads in Single-Fiber Composites

    Science.gov (United States)

    Koyanagi, Jun; Yoshimura, Akinori; Kawada, Hiroyuki; Aoki, Yuichiro

    2010-02-01

    We performed a numerical simulation of a time-dependent interfacial failure accompanied by a fiber failure, and examined their evolution under shear and compressive loads in single-fiber composites. The compressive load on the interface consists of Poisson’s contraction for matrix resin subjected to longitudinal tensile load. As time progresses, compressive stress at the interface in the fiber radial direction relaxes under the constant longitudinal tensile strain condition for the specimen, directly causing the relaxation of the interface frictional stress. This relaxation facilitates the failure of the interface. In this analysis, a specific criterion for interface failure is applied; apparent interfacial shear strength is enhanced by compressive stress, which is referred as quasi-parabolic criterion in the present study. The results of the stress recovery profile around the fiber failure and the interfacial debonding length as a function of time simulated by the finite element analysis employing the criterion are very similar to experimental results obtained using micro-Raman spectroscopy.

  14. Repair of radius defect with bone-morphogenetic-protein loaded hydroxyapatite/collagen-poly(L-lactic acid) composite

    Institute of Scientific and Technical Information of China (English)

    胡蕴玉; 张超; 吕荣; 徐建强; 李丹

    2003-01-01

    Objective: To explore the method to repair bone defect with bone-morphogenetic-protein loaded hydroxyapatite/collagen-poly(L-lactic acid) composite. Methods: 18 adult beagle dogs were randomly divided into 3 groups. In Group A, bone-morphogenetic-protein (BMP) loaded hydroxyapatite/collagen-poly(L-lactic acid) (HAC-PLA) scaffold was implanted in a 2 cm diaphyseal defect in the radius. In Group B, unloaded pure HAC-PLA scaffold was implanted in the defects. No material was implanted in Group C (control group). The dogs were sacrificed 6 months postoperatively. Features of biocompatibility, biodegradability and osteoinduction were evaluated with histological, radiological examinations and bone mineral density (BMD) measurements.Results: In Group A, the radius defect healed after the treatment with BMP loaded HAC-PLA. BMD at the site of the defect was higher than that of the contralateral radius. Fibrous union developed in the animals of the control group. Conclusions: BMP not only promotes osteogenesis but also accelerates degradation of the biomaterials. Optimized design parameters of a three-dimensional porous biomaterial would give full scope to the role of BMP as an osteoinductive growth factor.

  15. Statistical Analysis of the Progressive Failure Behavior for Fiber-Reinforced Polymer Composites under Tensile Loading

    Directory of Open Access Journals (Sweden)

    Fang Wang

    2014-01-01

    Full Text Available An analytical approach with the help of numerical simulations based on the equivalent constraint model (ECM was proposed to investigate the progressive failure behavior of symmetric fiber-reinforced composite laminates damaged by transverse ply cracking. A fracture criterion was developed to describe the initiation and propagation of the transverse ply cracking. This work was also concerned with a statistical distributions of the critical fracture toughness values with due consideration given to the scale size effect. The Monte Carlo simulation technique coupled with statistical analysis was applied to study the progressive cracking behaviors of composite structures, by considering the effects of lamina properties and lay-up configurations. The results deduced from the numerical procedure were in good agreement with the experimental results obtained for laminated composites formed by unidirectional fiber reinforced laminae with different orientations.

  16. Effect of Embedded Piezoelectric Sensors on Fracture Toughness and Fatigue Resistance of Composite Laminates Under Mode I Loading

    Science.gov (United States)

    Murri, Gretchen B.

    2006-01-01

    Double-cantilevered beam (DCB) specimens of a glass/epoxy composite material with embedded piezoelectric sensors were tested both statically and under fatigue loading to determine the effect of the embedded material on the Mode I fracture toughness and fatigue resistance compared to baseline data without the embedded elements. A material known as LaRC-Macrofiber Composite (LaRC-MFC (TradeMark)), or MFC, was embedded at the midplane of the specimen during the layup. Specimens were manufactured with the embedded MFC material either at the loaded end of the specimen to simulate an initial delamination; or with the MFC material located at the delaminating interface, with a Teflon film at the loaded end to simulate an initial delamination. There were three types of specimens with the embedded material at the delaminating interface: co-cured with no added adhesive; cured with a paste adhesive applied to the embedded element; or cured with a film adhesive added to the embedded material. Tests were conducted with the sensors in both the passive and active states. Results were compared to baseline data for the same material without embedded elements. Interlaminar fracture toughness values (G(sub Ic)) for the passive condition showed little change when the MFC was at the insert end. Passive results varied when the MFC was at the delaminating interface. For the co-cured case and with the paste adhesive, G(sub Ic) decreased compared to the baseline toughness, whereas, for the film adhesive case, G(sub Ic) was significantly greater than the baseline toughness, but the failure was always catastrophic. When the MFC was in the active state, G(sub Ic) was generally lower compared to the passive results. Fatigue tests showed little effect of the embedded material whether it was active or passive compared to baseline values.

  17. The effect of a low glycemic load diet on acne vulgaris and the fatty acid composition of skin surface triglycerides.

    Science.gov (United States)

    Smith, Robyn N; Braue, Anna; Varigos, George A; Mann, Neil J

    2008-04-01

    Dietary factors have long been implicated in acne pathogenesis. It has recently been hypothesized that low glycemic load diets may influence sebum production based on the beneficial endocrine effects of these diets. To determine the effect of a low glycemic load diet on acne and the fatty acid composition of skin surface triglycerides. Thirty-one male acne patients (aged 15-25 years) completed sebum sampling tests as part of a larger 12-week, parallel design dietary intervention trial. The experimental treatment was a low glycemic load diet, comprised of 25% energy from protein and 45% from low glycemic index carbohydrates. In contrast, the control situation emphasized carbohydrate-dense foods without reference to the glycemic index. Acne lesion counts were assessed during monthly visits. At baseline and 12-weeks, the follicular sebum outflow and composition of skin surface triglycerides were assessed using lipid absorbent tapes. At 12 weeks, subjects on the experimental diet demonstrated increases in the ratio of saturated to monounsaturated fatty acids of skin surface triglycerides when compared to controls [5.3+/-2.0% (mean+/-S.E.M.) vs. -2.7+/-1.7%, P=0.007]. The increase in the saturated/monounsaturated ratio correlated with acne lesion counts(r=-0.39, P=0.03). Increased follicular sebum outflow was also associated with an increase in the proportion of monounsaturated fatty acids in sebum (r=0.49, P=0.006). This suggests a possible role of desaturase enzymes in sebaceous lipogenesis and the clinical manifestation of acne. However, further work is needed to clarify the underlying role of diet in sebum gland physiology.

  18. Experimental Evaluation of Metal Composite Multi Bolt Radial Joint on Laminate Level, under uni Axial Tensile Loading

    Directory of Open Access Journals (Sweden)

    C Sharada Prabhakar

    2017-03-01

    Full Text Available Longitudinal tensile load exerted due to internal hydraulic pressure, on bolted radial joints between large size PAN carbon epoxy filament wound composite cylindrical section and small size 15CDV6 steel cylindrical sections, were simulated and tested on flat laminate level, mainly to check the strength of PAN carbon epoxy helical wound laminate made by wet winding method. Small segmental portion of circumference of cylindrical sections was considered as width of composite laminate and of metallic plates, necessary to accommodate 5 rows of fasteners in transverse direction with specified pitch distance. Bolted radial joints between carbon epoxy helical wound flat laminate and 15CDV6 steel plates were realized with 8 numbers of steel fasteners distributed in 3 longitudinal and 5 transverse rows at each joint. Helical angle of winding, length and thickness of carbon epoxy laminate was ±22.5°, 458mm and 11mm respectively. Length and structural thickness of radial joints, total length and width of assembly test specimen were 98mm, 18mm, 870mm and 169.43mm respectively. Joints were tested under uni-axial tensile load up to failure. Joints failed at 18 tonnes (1.7 times of design load. Failure mode was observed as initiation of bearing failure at all 8, countersink fastener holes in laminate and shear out failure at edge hole. Strains in fibre direction, at 45°and at transverse to fibre direction were found very less. Maximum compressive strain and residual strain, near fastener holes were found as -1423 and -136 micro strain respectively. Test was successful

  19. The influence of loading rate on the fracture mode for the viscous-elastic composites

    Directory of Open Access Journals (Sweden)

    Alexeeva S.

    2012-08-01

    Full Text Available The study of failure processes of composites should be accompanied with the analysis of the nature of failure, three main categories of which may be identified as: the defect accumulation; macrocracks propagation; instantaneous rupture, being a consequence of the cleavage of a weak link. Usually in these type of investigations the consideration is given to one or another type of failure while the conditions of transition from one type of failure to another or a possible change in its character are not discussed. However, the determination of these conditions is crucial for an accurate analysis of the performance of a composite structural component.

  20. DETERMINATION OF COMPOSITE LAYERS HARDNESS DEPENDING ON THEIR DEPTH AND APPLIED LOAD

    Directory of Open Access Journals (Sweden)

    Minodora-Maria PASĂRE

    2015-05-01

    Full Text Available Composite materials enjoy superior properties of traditional materials at high temperature and ambient temperature. The performance that touch these materials are mainly influenced by the type of materials used and the manufacturing process, the latter having a decisive role in relation to the starting composition similar, so that at the same materials used can be obtained qualities much higher depending on the process used. The diversity of the possible combinations of components to obtain advanced materials is high. A particular interest is shown by those systems that form solid solutions continuous or interrupted, and those that form new combinations with any special properties.

  1. 纳米TiO2/有机-无机杂化丙烯酸复合涂层机械及耐腐蚀性能的研究%Study on the mechanical properties and corrosion resistance properties of nano-TiO2/organic-inorganic hybrid acrylic composite coating

    Institute of Scientific and Technical Information of China (English)

    李婕; 孙小英; 杭建忠; 施利毅; 程银银

    2012-01-01

    The organic-inorganic hybridization acrylic resin was synthesized with sol-gel method,and the effects of the addition of nano-TiO2 on mechanical properties and corrosion resistance properties of organic-inorganic hybridization acrylic composite coatings have been investigated in detail.The result showed that,when adding 15wt% nano-TiO2,the hardness of coating was improved from 3 to 6H,the salt spray resistance time increased from 100 to 500h,and the resistance got to 106Ω·cm2.Moreover,it can be observed clearly that nano particles dispersed uniformly and densely in the coatings by SEM.The coordination of organic-inorganic hybridization acrylic resin and nano-TiO2 was a good potential method for improving the mechanical properties and corrosion resistance properties of coatings.%在采用溶胶-凝胶法合成有机-无机杂化丙烯酸树脂的基础上,研究了纳米TiO2添加量对有机-无机杂化丙烯酸复合涂层机械和耐腐蚀等性能的影响。研究表明,当纳米TiO2添加量为15%时,涂层的性能有了较大的提高,其硬度由3H提高至6H,涂层的耐盐雾时间由100h提高到500h,涂层的阻抗值也由104Ω.cm2提高至106Ω.cm2。另外,通过扫描电镜观察了复合涂层的断面,发现涂层中纳米粒子分散均匀,并且粘接紧密,形成了较为致密的复合涂层。

  2. Damage Precursor Investigation of Fiber-Reinforced Composite Materials Under Fatigue Loads

    Science.gov (United States)

    2013-09-01

    measures of damage that act as damage precursors also exist, such as electric resistance (Wang et al., 1998; Irving and 4 Thiagarajan, 1998; Weber... Irving , P. E.; Thiagarajan, C. Fatigue Damage Characterization in Carbon Fibre Composite Materials Using an Electrical Potential Technique. Smart...30 NO. OF COPIES ORGANIZATION 1 DEFENSE TECHNICAL (PDF) INFORMATION CTR DTIC OCA 2 DIRECTOR (PDFS) US ARMY RESEARCH LAB

  3. Comparison of Energy Absorption of Aluminium-composite Tubes Subjected to Axial Loading

    Science.gov (United States)

    Abbas, Tahir; Ya, H. H.; Zaki Abdullah, Mohamad

    2017-06-01

    In this paper, energy absorption capability and failure modes of partially wrapped aluminium tubes have been studied. These tubes are used in the front side of automobiles and aircraft applications. Filament winding technique was used for partial wrapping of these tubes. Partially wrapping on the external surface of aluminium tubes was done with glass fibers, and epoxy resin, which is a composite material. Various composite layers and fiber angles were used in partial wrapping, which includes 4, 6 and 8 composite layers of ± 55° fiber angle. These tubes were subjected to axial crushing using the universal ‎testing machine, and testing speed was 5mm/min. Failure modes and energy absorption analysis were carried out after testing. The experimental results revealed that partially wrapped aluminium tubes are 3.81%, 8.13% and 17.06% more efficient in energy absorption as compared to the tubes without wrapping. Furthermore, the effect of composite layers and failure modes has also been described.

  4. Modelling of coil-loaded wire antenna using composite multiple domain basis functions

    CSIR Research Space (South Africa)

    Lysko, AA

    2010-03-01

    Full Text Available with electrically small features. The reduction in the number of unknowns is accomplished by a logical aggregation/grouping of the individual wire segments into equivalent continuous wires. A single composite basis function is applied over several wire segments...

  5. Study of Dynamic Behavior of Multilayered Clamped Composite Skewed Hypar Shell Roofs under Impact Load

    Directory of Open Access Journals (Sweden)

    Sanjoy Das Neogi

    2013-01-01

    Full Text Available With advancement in the field of structural engineering, hunt for smarter materials has channelised the research towards the application of composite material. It is the high specific weight and specific stiffness of this material that have drawn the interest of different industrial sectors. Civil engineers also picked up composites to use it as a roofing material. Laminated composite shells, which can cover large column-free area and reduces dead weight of structure, show vulnerability under sudden impact due to their low transverse shear resistances. This study utilises finite element tool to investigate the dynamic response of a multilayered laminated composite hypar shells for fully clamped boundary condition. This class of shells is unique in a sense that the curvature has only the radius of cross curvature and these shells do not admit easy closed form solution particularly when the boundary conditions are complicated. Contact behavior of impactor and impacted mass has been modeled by modified Hertzian contact law and time-dependent equations are solved using Newmark’s time integration technique. Basic aim is to analyse the shell for symmetrically placed multilayered angle and cross ply lamination under different impact velocities.

  6. Advanced surface chemical analysis of continuously manufactured drug loaded composite pellets.

    Science.gov (United States)

    Hossain, Akter; Nandi, Uttom; Fule, Ritesh; Nokhodchi, Ali; Maniruzzaman, Mohammed

    2017-04-15

    The aim of the present study was to develop and characterise polymeric composite pellets by means of continuous melt extrusion techniques. Powder blends of a steroid hormone (SH) as a model drug and either ethyl cellulose (EC N10 and EC P7 grades) or hydroxypropyl methylcellulose (HPMC AS grade) as polymeric carrier were extruded using a Pharma 11mm twin screw extruder in a continuous mode of operation to manufacture extruded composite pellets of 1mm length. Molecular modelling study using commercial Gaussian 09 software outlined a possible drug-polymer interaction in the molecular level to develop solid dispersions of the drug in the pellets. Solid-state analysis conducted via a differential scanning calorimetry (DSC), hot stage microscopy (HSM) and X-ray powder diffraction (XRPD) analyses revealed the amorphous state of the drug in the polymer matrices. Surface analysis using SEM/energy dispersive X-ray (EDX) of the produced pellets arguably showed a homogenous distribution of the C and O atoms in the pellet matrices. Moreover, advanced chemical surface analysis conducted via atomic force microscopy (AFM) showed a homogenous phase system having the drug molecule dispersed onto the amorphous matrices while Raman mapping confirmed the homogenous single-phase drug distribution in the manufactured composite pellets. Such composite pellets are expected to deliver multidisciplinary applications in drug delivery and medical sciences by e.g. modifying drug solubility/dissolutions or stabilizing the unstable drug (e.g. hormone, protein) in the composite network. Copyright © 2016. Published by Elsevier Inc.

  7. Food composition and acid-base balance: alimentary alkali depletion and acid load in herbivores.

    Science.gov (United States)

    Kiwull-Schöne, Heidrun; Kiwull, Peter; Manz, Friedrich; Kalhoff, Hermann

    2008-02-01

    Alkali-enriched diets are recommended for humans to diminish the net acid load of their usual diet. In contrast, herbivores have to deal with a high dietary alkali impact on acid-base balance. Here we explore the role of nutritional alkali in experimentally induced chronic metabolic acidosis. Data were collected from healthy male adult rabbits kept in metabolism cages to obtain 24-h urine and arterial blood samples. Randomized groups consumed rabbit diets ad libitum, providing sufficient energy but variable alkali load. One subgroup (n = 10) received high-alkali food and approximately 15 mEq/kg ammonium chloride (NH4Cl) with its drinking water for 5 d. Another group (n = 14) was fed low-alkali food for 5 d and given approximately 4 mEq/kg NH4Cl daily for the last 2 d. The wide range of alimentary acid-base load was significantly reflected by renal base excretion, but normal acid-base conditions were maintained in the arterial blood. In rabbits fed a high-alkali diet, the excreted alkaline urine (pH(u) > 8.0) typically contained a large amount of precipitated carbonate, whereas in rabbits fed a low-alkali diet, both pH(u) and precipitate decreased considerably. During high-alkali feeding, application of NH4Cl likewise decreased pH(u), but arterial pH was still maintained with no indication of metabolic acidosis. During low-alkali feeding, a comparably small amount of added NH4Cl further lowered pH(u) and was accompanied by a significant systemic metabolic acidosis. We conclude that exhausted renal base-saving function by dietary alkali depletion is a prerequisite for growing susceptibility to NH4Cl-induced chronic metabolic acidosis in the herbivore rabbit.

  8. Application of Functionalized SWCNTs for Increase of Degradation Resistance of Acrylic Paint for Cars

    Directory of Open Access Journals (Sweden)

    Osiel Lucas Flores

    2013-01-01

    Full Text Available Physical properties of automotive acrylic paint are improved by incorporation of three different types of carbon nanotubes: single-wall carbon nanotubes (SWCNTs, OH-functionalized single-wall carbon nanotubes (OH-SWCNTs, and aniline-functionalized single-wall carbon nanotubes (aniline-SWCNTs. The formed composites are studied by electron miscroscopy methods and Raman spectrometry. It is found that the acrylic paints with addition of OH-SWCNTs and aniline-SWCNTs show better quality for their applications. In particular, the resistance against degradation by electron beam increased in ~500%.

  9. In vitro haematic proteins adsorption and cytocompatibility study on acrylic copolymer to realise coatings for drug-eluting stents

    Energy Technology Data Exchange (ETDEWEB)

    Gagliardi, Mariacristina, E-mail: mariacristina.gagliardi@iit.it

    2012-12-01

    In the present paper, a preliminary in vitro analysis of biocompatibility of newly-synthesised acrylic copolymers is reported. In particular, with the aim to obtain coatings for drug-eluting stents, blood protein absorption and cytocompatibility were studied. For protein absorption tests, bovine serum albumin and bovine plasma fibrinogen were considered. Cytocompatibility was tested using C2C12 cell line as model, analysing the behaviour of polymeric matrices and of drug-eluting systems, obtained loading polymeric matrices with paclitaxel, an anti-mitotic drug, in order to evaluate the efficacy of a pharmacological treatment locally administered from these materials. Results showed that the amount of albumin absorbed was greater than the amount of fibrinogen (comprised in the range of 70%-85% and 10%-22% respectively) and it is a good behaviour in terms of haemocompatibility. Cell culture tests showed good adhesion properties and a relative poor proliferation. In addition, a strong effect related to drug elution and a correlation with the macromolecular composition were detected. In this preliminary analysis, tested materials showed good characteristics and can be considered possible candidates to obtain coatings for drug-eluting stents. Highlights: Black-Right-Pointing-Pointer Preliminary evaluation of haemo- and cytocompatibility of newly-synthesised acrylic copolymers Black-Right-Pointing-Pointer Materials adsorb higher amounts of albumin and with a faster rate than fibrinogen. Black-Right-Pointing-Pointer Protein adsorption depended on the macromolecular composition and surface properties. Black-Right-Pointing-Pointer Cell viability on pure samples and efficacy of paclitaxel release were verified in C2C12 cultures.

  10. Pluronic-poly (acrylic acid)-cysteine/Pluronic L121 mixed micelles improve the oral bioavailability of paclitaxel.

    Science.gov (United States)

    Zhao, Yanli; Li, Yanli; Ge, Jianjun; Li, Na; Li, Ling-Bing

    2014-11-01

    The aim of the study is to synthesize a thiolated Pluronic copolymer, Pluronic-poly (acrylic acid)-cysteine copolymer, to construct a mixed micelle system with the Pluronic-poly (acrylic acid)-cysteine copolymer and Pluronic L121 (PL121) and to evaluate the potential of these mixed micelles as an oral drug delivery system for paclitaxel. Compared with Pluronic-poly (acrylic acid)-cysteine micelles, drug-loading capacity of Pluronic-poly (acrylic acid)-cysteine/PL121 mixed micelles was increased from 0.4 to 2.87%. In vitro release test indicated that Pluronic-poly (acrylic acid)-cysteine/PL121 mixed micelles exhibited a pH sensitivity. The permeability of drug-loaded micelles in the intestinal tract was studied with an in situ perfusion method in rats. The presence of verapamil and Pluronic both improved the intestinal permeability of paclitaxel, which further certified the inhibition effect of thiolated Pluronic on P-gp. In pharmacokinetic study, the area under the plasma concentration-time curve (AUC0→∞) of paclitaxel-loaded mixed micelles was four times greater than that of the paclitaxel solution (p cysteine/PL121 micelles were proven to be a potential oral drug delivery system for paclitaxel.

  11. Host–guest composite materials of dyes loaded zeolite LTL for antenna applications

    Energy Technology Data Exchange (ETDEWEB)

    Insuwan, W. [Rajamangala University of Technology Isan Surin Campus, Facculty of Agriculture and Technology, Surin 32000 (Thailand); Jungsuttiwong, S. [Center for Organic Electronic and Alternative Energy, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Ubon Ratchathani University, Ubon Ratchathani 34190 (Thailand); Rangsriwatananon, K., E-mail: kunwadee@sut.ac.th [School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000 (Thailand)

    2015-05-15

    This research work directly focuses on a new feasible light harvesting antenna material constructed with Acridine hydrochloride (Ac)/Acriflavine hydrochloride (AF), as donor/acceptor for energy transfer, loaded on a round shape zeolite LTL (K-LTL and H-LTL). The energy transfer was monitored by absorption and fluorescence spectra while the calculated Förster distance (R{sub DA}) and Quenching efficiency (%Q) of Ac/AF on K-LTL and H-LTL varied between 22.0 Å to 19.6 Å and 71.4% to 65.5%, respectively. Also, it was found that the microenvironment of a solid host such as K-LTL and H-LTL has significantly influenced the fluorescence spectra of Ac/AF on H-LTL approximately 50 nm longer than that on K-LTL. - Highlights: • New antenna materials have been performed using dyes loaded on zeolite LTL. • Light emission takes place from acriflavine hydrochloride (AF) due to fluorescence resonance energy transfer (FRET). • The microenvironment of zeolite LTL has significantly influenced the fluorescence spectra.

  12. Modelling the behaviour of composite sandwich structures when subject to air-blast loading

    Directory of Open Access Journals (Sweden)

    H Arora

    2016-09-01

    Full Text Available Large-scale glass fibre reinforced polymer (GFRP and carbon fibre reinforced polymer (CFRP sandwich structures (1.6 m x 1.3 m were subject to explosive air blast (100 kg TNT equivalent at stand-off distances of 14 m. Digital image correlation (DIC was used to obtain full-field data for the rear-face of each deforming target. A steel plate of comparable mass per unit area was also subjected to the same blast conditions for comparison. The experimental data was then verified with finite element models generated in Abaqus/Explicit. Close agreement was obtained between the numerical and experimental results, confirming that the CFRP panels had a superior blast performance to the GFRP panels. Moreover all composite targets sustained localised failures (that were more severe in the GFRP targets but retained their original shape post blast. The rear-skins remained intact for each composite target with core shear failure present.

  13. Fatigue Behaviour and Life Assessment of Jute-epoxy Composites under Tension-Tension Loading

    Science.gov (United States)

    Padmaraj, N. H.; Chethan, K. N.; Pavan; Onkar, Anand

    2017-08-01

    The present study involves fabrication and fatigue life assessment of multi-layered, woven jute fibres with epoxy matrix composites. Jute fabric were treated with 1N sodium hydroxidesolution for a duration of 6 hours. Alkali treatment was done to modify internal structure as well as surface properties of fibre. Laminates were fabricated by laying up multi layered woven jute fabric at varying angle [0-900/ (±450)2/0-900]. Vacuum bagging method was used to reduce the void content and thus increase the quality of composites. Tension-Tension fatigue tests were performed with a constant fatigue stress ratio (R=0.1) and results obtained from the tests were used to plot S-N Curve. A model based on power law equation was used for curve fitting.

  14. (GameChanger) Multifunctional Design of Hybrid Composites of Load Bearing Antennas

    Science.gov (United States)

    2011-06-01

    applications. Electrically conductive fibers, comprised of thin metal coated polymer strands ( Zylon , Kevlar etc.), are extremely flexible. They are also easy...fibers can be stitched into the platform for higher structural stability. An optional layer of non- conductive fiber such as Kevlar or Zylon can...Composites To demonstrate the embroidering concept, we used Amberstrand ® silver-coated Zylon fibers as the E-fiber conductor (see Figure 3). This e-fiber

  15. Viscoelastic behaviour of hydrogel-based composites for tissue engineering under mechanical load.

    Science.gov (United States)

    Kocen, Rok; Gasik, Michael; Gantar, Ana; Novak, Saša

    2017-03-06

    Along with biocompatibility, bioinductivity and appropriate biodegradation, mechanical properties are also of crucial importance for tissue engineering scaffolds. Hydrogels, such as gellan gum (GG), are usually soft materials, which may benefit from the incorporation of inorganic particles, e.g. bioactive glass, not only due to the acquired bioactivity, but also due to improved mechanical properties. They exhibit complex viscoelastic properties, which can be evaluated in various ways. In this work, to reliably evaluate the effect of the bioactive glass (BAG) addition on viscoelastic properties of the composite hydrogel, we employed and compared the three most commonly used techniques, analyzing their advantages and limitations: monotonic uniaxial unconfined compression, small amplitude oscillatory shear (SAOS) rheology and dynamic mechanical analysis (DMA). Creep and small amplitude dynamic strain-controlled tests in DMA are suggested as the best ways for the characterization of mechanical properties of hydrogel composites, whereas the SAOS rheology is more useful for studying the hydrogel's processing kinetics, as it does not induce volumetric changes even at very high strains. Overall, the results confirmed a beneficial effect of BAG (nano)particles on the elastic modulus of the GG-BAG composite hydrogel. The Young's modulus of 6.6 ± 0.8 kPa for the GG hydrogel increased by two orders of magnitude after the addition of 2 wt.% BAG particles (500-800 kPa).

  16. Screening of Catalyst and Important Variable for The Esterification of Acrylic Acid with 2 Ethylhexanol

    Science.gov (United States)

    Ahmad, M. A. A.; Chin, S. Y.

    2017-06-01

    The global demand of 2-ethylhexyl acrylate (2EHA) market has witnessed a significant growth in the past few years and this growth is anticipated to increase in the coming years. 2EHA is one of the basic organic building blocks that mainly used in the production of coatings, adhesives, superabsorbents, thickeners and plastic additives. Homogenous acid-catalysed esterification of acrylic acid (AA) with 2-ethylhexanol (2EH) is commonly used for the production of 2EHA. The homogeneous catalysts such as sulfuric and para-toluene sulfonic acid have resulted the costly and complicated downstream process that generates acidic, corrosive and non-environmental friendly waste. Therefore, it is importance to develop a cheaper process that employing heterogeneous catalysts and alternative raw material from wastewater containing acrylic acid. In this research, the study for the esterification of AA with 2EH catalysed by ion-exchange resin was conducted. The best sulfonic acid functional cation-exchange resin among SK104, SK1B, PK208, PK216, PK228, RCP145, and RCP160 was screened. PK208 outperformed the other resins and it was used subsequently in the parametric studies. The effect of important parameters (initial concentration of acrylic acid (AA), temperature, molar ratio of reactant (AA and 2EH), catalyst loading, and polymerisation inhibitor loading) was studied using 2 factorial design to determine the significant parameters to the esterification. It was found that the initial concentration of AA and temperature were most significantly affecting the esterification of AA with 2EH.

  17. Direct Synthesis of Hyperbranched Poly(acrylic acid-co-3-hydroxypropionate

    Directory of Open Access Journals (Sweden)

    Efkan Çatıker

    2015-01-01

    Full Text Available Hyperbranched poly(acrylic acid-co-3-hydroxypropionate (PAcHP was synthesized by base-catalyzed hydrogen transfer polymerization of acrylic acid through one step. The copolymers obtained through solution and bulk polymerization were insoluble in water and all organic solvents tried. Structural and compositional characterizations of hyperbranched PAcHP were performed by using FTIR, solid 13C-NMR, TGA, and titrimetric analysis. Acrylate fraction of the hyperbranched PAcHP obtained via bulk polymerization was determined as 60–65% by comparing TGA curves of hyperbranched PAcHP and pure poly(3-hydroxy propionate (PHP. However, analytical titration of the same sample revealed that acrylic acid units were about 47.3%. The results obtained from TGA and analytical titration were used to evaluate the chemical structure of the copolymer. Hyperbranched PAcHP exhibited hydrogel properties. Swelling behavior of the copolymer was investigated at a wide pH range and ionic strength. The dynamic swelling profiles of hyperbranched PAcHP exhibited a fast swelling behavior in the first hour and achieved the equilibrium state within 12 h in PBS. Depending on the conditions, the copolymers exhibited swelling ratios up to 2100%. As the copolymer has easily biodegradable propionate and versatile functional acrylic acid units, it can be used as not only biodegradable material in medical applications but also raw material in personal care commodities.

  18. Modeling Strength Degradation of Fiber-Reinforced Ceramic-Matrix Composites Subjected to Cyclic Loading at Elevated Temperatures in Oxidative Environments

    Science.gov (United States)

    Longbiao, Li

    2017-04-01

    In this paper, the strength degradation of non-oxide and oxide/oxide fiber-reinforced ceramic-matrix composites (CMCs) subjected to cyclic loading at elevated temperatures in oxidative environments has been investigated. Considering damage mechanisms of matrix cracking, interface debonding, interface wear, interface oxidation and fibers fracture, the composite residual strength model has been established by combining the micro stress field of the damaged composites, the damage models, and the fracture criterion. The relationships between the composite residual strength, fatigue peak stress, interface debonding, fibers failure and cycle number have been established. The effects of peak stress level, initial and steady-state interface shear stress, fiber Weibull modulus and fiber strength, and testing temperature on the degradation of composite strength and fibers failure have been investigated. The evolution of residual strength versus cycle number curves of non-oxide and oxide/oxide CMCs under cyclic loading at elevated temperatures in oxidative environments have been predicted.

  19. Damage depth estimation on a fatigue loaded composite structure using thermography and acoustic emission

    Science.gov (United States)

    Zalameda, Joseph N.; Winfree, William P.; Horne, Michael R.

    2017-02-01

    Passive thermography and acoustic emission data were obtained on a three stringer panel during periodic fatigue loading. The acoustic emission data were mapped onto thermal data, revealing the cluster of acoustic emission event locations around the thermal signatures of interest. By combining both techniques, progression of damage growth is confirmed and areas of failure are identified. Furthermore, sudden changes in thermally measured damage growth related to a previously measured higher energy acoustic emission event are studied to determine damage depth. A thermal model with a periodic flux heat source is presented to determine the relationship between the damage depth and thermal response. The model results are compared to the measured data. Lastly, the practical application and limitations of this technique are discussed.

  20. Displacements and stresses in composite multi-layered media due to varying temperature and concentrated load

    Institute of Scientific and Technical Information of China (English)

    M. K. Ghosh; M. Kanoria

    2007-01-01

    This paper deals with the determination of the thermo-elastic displacements and stresses in a multi-layered body set up in different layers of different thickness having different elastic properties due to the application of heat and a concentrated load in the uppermost surface of the medium. Each layer is assumed to be made of homogeneous and isotropic elastic material. The relevant displacement components for each layer are taken to be axisymmetric about a line, which is perpendicular to the plane surfaces of all layers. The stress function for each layer, therefore, satisfies a single equation in absence of any body forces. The equation is then solved by integral transform technique. Analytical expressions for thermo-elastic displacements and stresses in the underlying mass and the corresponding numerical codes are constructed for any number of layers. However, the numerical comparison is made for three and four layers.

  1. Impact of Packing and Processing Technique on Mechanical Properties of Acrylic Denture Base Materials

    Directory of Open Access Journals (Sweden)

    Touraj Nejatian

    2015-04-01

    Full Text Available The fracture resistance of polymethylmethacrylate (PMMA as the most popular denture base material is not satisfactory. Different factors can be involved in denture fracture. Among them, flexural fatigue and impact are the most common failure mechanisms of an acrylic denture base. It has been shown that there is a correlation between the static strength and fatigue life of composite resins. Therefore, the transverse strength of the denture base materials can be an important indicator of their service life. In order to improve the fracture resistance of PMMA, extensive studies have been carried out; however, only a few promising results were achieved, which are limited to some mechanical properties of PMMA at the cost of other properties. This study aimed at optimizing the packing and processing condition of heat-cured PMMA as a denture base resin in order to improve its biaxial flexural strength (BFS. The results showed that the plain type of resin with a powder/monomer ratio of 2.5:1 or less, packed conventionally and cured in a water bath for 2 h at 95 °C provides the highest BFS. Also, it was found that the performance of the dry heat processor is inconsistent with the number of flasks being loaded.

  2. Shell and core cross-linked poly(L-lysine)/poly(acrylic acid) complex micelles.

    Science.gov (United States)

    Hsieh, Yi-Hsuan; Hsiao, Yung-Tse; Jan, Jeng-Shiung

    2014-12-21

    We report the versatility of polyion complex (PIC) micelles for the preparation of shell and core cross-linked (SCL and CCL) micelles with their surface properties determined by the constituent polymer composition and cross-linking agent. The negatively and positively charged PIC micelles with their molecular structure and properties depending on the mixing weight percentage and polymer molecular weight were first prepared by mixing the negatively and positively charged polyions, poly(acrylic acid) (PAA) and poly(L-lysine) (PLL). The feasibility of preparing SCL micelles was demonstrated by cross-linking the shell of the negatively and positively charged micelles using cystamine and genipin, respectively. The core of the micelles can be cross-linked by silica deposition to stabilize the assemblies. The shell and/or core cross-linked micelles exhibited excellent colloid stability upon changing solution pH. The drug release from the drug-loaded SCL micelles revealed that the controllable permeability of the SCL micelles can be achieved by tuning the cross-linking degree and the SCL micelles exhibited noticeable pH-responsive behavior with accelerated release under acidic conditions. With the versatility of cross-linking strategies, it is possible to prepare a variety of SCL and CCL micelles from PIC micelles.

  3. 氟硅丙烯酸酯/钠基蒙脱土复合乳胶涂层的制备及防腐蚀性能%Preparation and anticorrosion performance of fluorine-silicon-acrylate/sodium montmorillonite composite emulsion coating

    Institute of Scientific and Technical Information of China (English)

    高晓辉; 李玉峰; 祝晶晶; 张毅志

    2015-01-01

    以甲基丙烯酸十二氟庚酯和乙烯基三甲氧基硅烷为功能单体,采用种子乳液聚合法合成氟硅丙烯酸酯乳液(氟硅),然后将钠基蒙脱土(钠土)分散于其中,制成复合乳胶涂层并涂覆在Q235钢上。研究了乳液种类和钠土用量对涂层防腐性的影响。采用红外光谱(FT-IR)、透射电子显微镜(TEM)和扫描电子显微镜(SEM)表征了氟硅丙烯酸酯乳液和涂层。通过极化曲线、交流阻抗测量和中性盐雾试验探讨了复合涂层的耐腐蚀性。结果表明,乳胶粒子呈核壳结构,涂层连续、致密,钠土在涂层中分散均匀。当钠土用量为4%时,复合涂层的耐蚀性最好,水接触角达到102.4°,附着力为0级,电化学阻抗达到104.4Ω,腐蚀速率仅为4.3×10−5 mm/a,盐雾试验240 h后膜下金属未发生腐蚀扩散。%A fluorine-silicon-acrylate emulsion was synthesized by seed emulsion polymerization using dodecafluoroheptyl methacrylate and vinyltrimethoxysilane as monomers. Sodium montmorillonite (Na-MMT) was dispersed in the fluorine-silicon-acrylate emulsion for preparing a composite emulsion coating for Q235 steel. The influences of emulsion type and Na-MMT content on anticorrosion properties of the coating were studied. The fluorine-silicon-acrylate emulsion and coating were characterized by Fourier-transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The corrosion resistance of the composite coating was examined by polarization curve measurement, electrochemical impedance spectroscopy, and neutral salt spray test. The results showed that the emulsion particles possess obvious core-shell structure and the composite coating is continuous and compact with well-dispersed Na-MMT. The composite emulsion coating obtained with 4%Na-MMT has optimal anticorrosion performance with a water contact angle of 102.4°, adhesion strength of 0 grade

  4. CHEMICAL COMPOSITION AND PCT DATA FOR THE INITIAL SET OF HANFORD ENHANCED WASTE LOADING GLASSES

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K.; Edwards, T.

    2014-06-02

    In this report, the Savannah River National Laboratory provides chemical analyses and Product Consistency Test results for 20 simulated high level waste glasses fabricated by the Pacific Northwest National Laboratory. The results of these analyses will be used as part of efforts to revise or extend the validation ranges of the current Hanford Waste Treatment and Immobilization Plant glass property models to cover a broader span of waste compositions. The measured chemical composition data are reported and compared with the targeted values for each component for each glass. Two components of the study glasses, fluorine and silver, were not measured since each of these species would have required the use of an additional preparation method and their measured values were likely to be near or below analytical detection limits. Some of the glasses were difficult to prepare for chemical analysis. A sodium peroxide fusion dissolution method was successful in completely dissolving the glasses. Components present in the glasses in minor concentrations can be difficult to measure using this dissolution method due to dilution requirements. The use of a lithium metaborate preparation method for the minor components (planned for use since it is typically successful in digesting Defense Waste Processing Facility HLW glasses) resulted in an unacceptable amount of undissolved solids remaining in the sample solutions. An acid dissolution method was used instead, which provided more thorough dissolution of the glasses, although a small amount of undissolved material remained for some of the study glasses. The undissolved material was analyzed to determine those components of the glasses that did not fully dissolve. These components (e.g., calcium and chromium) were present in sufficient quantities to be reported from the measurements resulting from the sodium peroxide fusion preparation method, which did not leave undissolved material. Overall, the analyses resulted in sums of

  5. CHEMICAL COMPOSITION AND PCT DATA FOR THE INITIAL SET OF HANFORD ENHANCED WASTE LOADING GLASSES

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K.; Edwards, T.

    2014-06-02

    In this report, the Savannah River National Laboratory provides chemical analyses and Product Consistency Test results for 20 simulated high level waste glasses fabricated by the Pacific Northwest National Laboratory. The results of these analyses will be used as part of efforts to revise or extend the validation ranges of the current Hanford Waste Treatment and Immobilization Plant glass property models to cover a broader span of waste compositions. The measured chemical composition data are reported and compared with the targeted values for each component for each glass. Two components of the study glasses, fluorine and silver, were not measured since each of these species would have required the use of an additional preparation method and their measured values were likely to be near or below analytical detection limits. Some of the glasses were difficult to prepare for chemical analysis. A sodium peroxide fusion dissolution method was successful in completely dissolving the glasses. Components present in the glasses in minor concentrations can be difficult to measure using this dissolution method due to dilution requirements. The use of a lithium metaborate preparation method for the minor components (planned for use since it is typically successful in digesting Defense Waste Processing Facility HLW glasses) resulted in an unacceptable amount of undissolved solids remaining in the sample solutions. An acid dissolution method was used instead, which provided more thorough dissolution of the glasses, although a small amount of undissolved material remained for some of the study glasses. The undissolved material was analyzed to determine those components of the glasses that did not fully dissolve. These components (e.g., calcium and chromium) were present in sufficient quantities to be reported from the measurements resulting from the sodium peroxide fusion preparation method, which did not leave undissolved material. Overall, the analyses resulted in sums of

  6. Porcelain versus composite inlays/onlays: effects of mechanical loads on stress distribution, adhesion, and crown flexure.

    Science.gov (United States)

    Magne, Pascal; Belser, Urs C

    2003-12-01

    This study used 2-D finite element modeling to simulate cuspal flexure and stresses at the surface and tooth-restoration interface of a restored maxillary molar using three restorative materials; the influence of four inlay/onlay preparation configurations on stress distribution within the complex was also investigated. A buccolingual cross-section of an intact molar was digitized and used to create 2-D models restored with different restorative materials (feldspathic porcelain, high- and low-elastic modulus composites) and tooth preparations (small and large inlays, small and large onlays). Two simulated 25-N oblique loads were applied to the cusps. The tangential stress for each finite element node located at the tooth surface, interfacial stress, and relative cuspal flexure were analyzed. All materials and tooth preparations exhibited similar surface tangential stress patterns, with a definite compressive area at the external cusp ridges, a tensile zone at the occlusal surface, and compression stress peaks at the CEJ. The low-elastic modulus composite showed reduced tensile stresses at its surface but increased tension at the dentin-adhesive interface when compared to ceramics. All types of onlays demonstrated a majority of compressive interfacial stresses, while inlays showed a majority of tensile stresses. The interfacial tension at the dentin level increased with the flexibility of the restorative material. Only the large ceramic onlay displayed almost pure compression at the interface. Composite-restored teeth exhibited increased crown flexure, while porcelain-restored teeth showed increased crown stiffness. Porcelain inlays/onlays featured more detrimental stresses at the occlusal surface but better potential protection against debonding at the dentin-restoration interface compared to composite inlays/onlays. Ceramic onlays/overlays seem to represent an effective answer to restore severely damaged posterior teeth.

  7. Spherical Acrylic Plastic Hulls under External Explosive Loading

    Science.gov (United States)

    1976-03-01

    61-4l2-O0l. Rcleased by H. R. Taikington, Head, Ocean I echnology Department ACKNOWLEDGEMENTS The testing of mne-del -size and full-size NEMO-type...Thle cage itself It mas kept sus-pendted at 50 Pt dlepth by meianls of a cable attached to at large mobile crane. For tile first three Shots, thle

  8. Preparation and Swelling Properties of pH Responsive Psyllium-Graft-Poly(Acrylic Acid)/Biotite Superabsorbent Composites%欧车前胶-g-聚丙烯酸/黑云母高吸水性树脂的合成与溶胀行为

    Institute of Scientific and Technical Information of China (English)

    安建科; 王文波; 王爱勤

    2011-01-01

    A series of novel psyllium gum-g-poly(acrylic acid)/biotite superabsorbent composites with various biotite contents were prepared by the solution polymerization,using ammonium persulfate as the initiator and N,N′-methylenebisacrylamide as the crosslinker.The swelling kinetics of superabsorbent composites with various contents of biobite in distilled water and the swelling behaviour in saline solutions were investigated systematically.Biotite participating in graft polymerization was confirmed by FT-IR spectra and the swelling test.Results indicate that the introducing biotite into psyllium gum-g-poly(acrylic acid) remarkably improves the water absorbency in distilled water and NaCl solutions,also exhibits a pH sensitivity and the excellent reswelling capabilities.Therefore,the superabsorbent composites may be considered as an excellent candidate for agriculture and horticulture applications or as pH-responsive materials.%以欧车前胶(PSY)、丙烯酸(AA)和黑云母(BT)为原料,N,N′-亚甲基双丙烯酰胺(MBA)为交联剂,过硫酸铵(APS)为引发剂,采用水溶液聚合法制备了欧车前胶接枝聚丙烯酸复合黑云母(PSY-g-PAA/BT)高吸水性树脂。考察了不同含量BT树脂在蒸馏水和盐水中的吸水倍率和溶胀行为。红外光谱和溶胀性能测试结果表明,BT参与了接枝聚合反应,BT的引入明显改善了树脂在蒸馏水和盐水溶液中的吸水倍率,PSY-g-PAA/BT复合高吸水性树脂具有良好的pH敏感性。

  9. Behaviour of a Moment Resisting Composite Steel and Concrete Joint Under Alternate Loading

    Institute of Scientific and Technical Information of China (English)

    Alberto Zanchettin; Bruno Briseghella; Tobia Zordan; Junqing Xue

    2011-01-01

    The authors show the results of a study conducted on a joint connecting a concrete column to a composite steel concrete floor, subjected to tension on the beams as a result of the decomposition of sagging bending moment. The beam to column connection is achieved by means of headed studs welded to the beam and embedded in the concrete cast. Five different configurations have been tested at failure and the results are compared to formulae proposed in literature. Different degrees of ductility, reliability and strength have been obtained varying geometry and reinforcement ratio on the joints tested.

  10. Effect of thermal residual stresses on yielding behavior under tensile or compressive loading of short fiber reinforced metal matrix composite

    Institute of Scientific and Technical Information of China (English)

    丁向东; 连建设; 江中浩; 孙军

    2001-01-01

    Using large strain two-dimension axisymmetric elasto-plastic finite element method and the modified law of mixture, the effects of thermal residual stresses on the yielding behavior of short fiber reinforced metal matrix composite and their dependencies on the material structure parameters (fiber volume fraction, fiber aspect ratio and fiber end distance) were studied. It is demonstrated that the stress-strain partition parameter can be used to describe the stress transfer from the matrix to the fiber. The variation of the second derivation of the stress-strain partition parameter can be used to determine the elastic modulus, the proportion limit, the initial and final yield strengths. In the presence of thermal residual stress, these yielding properties are asymmetric and are influenced differently by the material structure parameters under tensile and compressive loadings.

  11. The ultimate state of polymeric materials and laminated and fibrous composites under asymmetric high-cycle loading

    Science.gov (United States)

    Golub, V. P.; Pogrebniak, A. D.; Kochetkova, E. S.

    2008-01-01

    The prediction of the high-cycle fatigue strength of polymeric and composite materials in asymmetric loading is considered. The problem is solved on the basis of a nonlinear model of ultimate state allowing us to describe all typical forms of the diagrams of ultimate stresses. The material constants of the model are determined from the results of fatigue tests in symmetric reversed cycling, in a single fatigue test with the minimum stress equal to zero, and in a short-term strength test. The fatigue strength characteristics of some polymers, glass-fiber laminates, glass-fiber-reinforced plastics, organic-fiber-reinforced plastics, and wood laminates in asymmetric tension-compression, bending, and torsion have been calculated and approved experimentally.

  12. Synergistic Effects of Frequency and Temperature on Damage Evolution and Life Prediction of Cross-Ply Ceramic Matrix Composites under Tension-Tension Fatigue Loading

    Science.gov (United States)

    Longbiao, Li

    2016-12-01

    In this paper, the synergistic effects of loading frequency and testing temperature on the fatigue damage evolution and life prediction of cross-ply SiC/MAS ceramic-matrix composite have been investigated. The damage parameters of the fatigue hysteresis modulus, fatigue hysteresis dissipated energy and the interface shear stress were used to monitor the damage evolution inside of SiC/MAS composite. The evolution of fatigue hysteresis dissipated energy, the interface shear stress and broken fibers fraction versus cycle number, and the fatigue life S-N curves of SiC/MAS composite under the loading frequency of 1 and 10 Hz at 566 °C and 1093 °C in air condition have been predicted. The synergistic effects of the loading frequency and testing temperature on the degradation rate of fatigue hysteresis dissipated energy and the interface shear stress have been analyzed.

  13. Demonstrate Scale-up Procedure for Glass Composite Material (GCM) for Incorporation of Iodine Loaded AgZ.

    Energy Technology Data Exchange (ETDEWEB)

    Nenoff, Tina M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Garino, Terry J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Croes, Kenneth James [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rodriguez, Mark A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-07-01

    Two large size Glass Composite Material (GCM) waste forms containing AgI-MOR were fabricated. One contained methyl iodide-loaded AgI-MOR that was received from Idaho National Laboratory (INL, Test 5, Beds 1 – 3) and the other contained iodine vapor loaded AgIMOR that was received from Oak Ridge National Laboratory (ORNL, SHB 2/9/15 ). The composition for each GCM was 20 wt% AgI-MOR and 80 wt% Ferro EG2922 low sintering temperature glass along with enough added silver flake to prevent any I2 loss during the firing process. The silver flake amounts were 1.2 wt% for the GCM with the INL AgI-MOR and 3 wt% for the GCM contained the ORNL AgI-MOR. The GCMs, nominally 100 g, were first uniaxially pressed to 6.35 cm (2.5 inch) diameter disks then cold isostatically pressed, before firing in air to 550°C for 1hr. They were cooled slowly (1°C/min) from the firing temperature to avoid any cracking due to temperature gradients. The final GCMs were ~5 cm in diameter (~2 inches) and non-porous with densities of ~4.2 g/cm³. X-ray diffraction indicated that they consisted of the amorphous glass phase with small amounts of mordenite and AgI. Furthermore, the presence of the AgI was confirmed by X-ray fluorescence. Methodology for the scaled up production of GCMs to 6 inch diameter or larger is also presented.

  14. Pattern of aerosol mass loading and chemical composition over the atmospheric environment of an urban coastal station

    Science.gov (United States)

    Bindu, G.; Nair, Prabha R.; Aryasree, S.; Hegde, Prashant; Jacob, Salu

    2016-02-01

    Aerosol sampling was carried out at four locations in and around Cochin (9°58‧ N, 76°17‧ E), an urban area, located on the southwest coast of India. The gravimetric estimates of aerosol mass loading showed wide range from 78 μg m-3 to >450 μg m-3, occasionally reaching values >500 μg m-3, associated with regional source characteristics. Most of the values were above the air quality standard. Both boundary layer and synoptic scale airflow pattern play role in the temporal features in aerosol mass loading and chemical composition. Chemical analysis of the aerosol samples were done for anionic species viz; F-, Cl-, Br-, NO2-,   NO3-,   PO43-,   SO42- and metallic/cationic species viz; Na, Ca, K, Mg, NH4+, Fe, Al, Cu, Mg, Pb, etc using Ion Chromatography, Atomic Absorption Spectroscopy (AAS) and Inductively Coupled Plasma- Atomic Emission Spectroscopy (ICP-AES). At all the locations, extremely high mass concentration of SO42- was observed with the mean value of 13±6.4 μg m-3 indicating the strong anthropogenic influence. Statistical analysis of the chemical composition data was carried out and the principal factors presented. Seasonal variation of these chemical species along with their percentage contributions and regional variations were also examined. Increase in level of Na in aerosol samples indicated the influence of monsoonal activity. Most of the species showed mass concentrations well above those measured over another coastal site Thiruvananthapuram (8°29‧ N, 76°57‧ E) situated ~220 km south of Cochin revealing the highly localized aerosol features.

  15. Strength and failure behaviour of spark plasma sintered steel-zirconia composites under compressive Loading

    Energy Technology Data Exchange (ETDEWEB)

    Krueger, L.; Decker, S.; Ehinger, D. [Institute of Materials Engineering, TU Bergakademie Freiberg (Germany); Ohser-Wiedemann, R.; Martin, S.; Martin, U.; Seifert, H.J. [Institute of Materials Science, TU Bergakademie Freiberg (Germany)

    2011-09-15

    Several composites, consisting of a metastable austenitic steel matrix and varying amounts of MgO partially stabilized zirconia particles (Mg-PSZ), were produced through spark plasma sintering (SPS). Compression tests were carried out at room temperature in a wide range of strain rate (4 . 10{sup -4} s{sup -1}, 2 . 10{sup -3} s{sup -1}, 10{sup -1} s{sup -1}, 1 s{sup -1}, 10{sup 2} s{sup -1}). In conjunction with subsequent microstructural investigations, the mechanical material behaviour was clarified. All composites showed a good ductility and a high strength. The strength increased with an increase of the ceramic content and with higher strain rates. Both, the martensitic transformation of the steel matrix and of the ceramic particles, could be proved at all strain rates. In this study no significant influence of the strain rate on the amount of transformed ceramic could be detected while the steel matrix showed less {alpha}'-martensite after compression at rising strain rates. Local material failure occurred around 0.3 true compressive strain depending on the applied strain rate and the amount of the Mg-PSZ powder. The main reason for the damage is the relatively weak ceramic-ceramic interface within the ceramic clusters. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  16. Facile Synthesis of Gold Nanoparticle-loaded Carbon Nanofiber Composites and Their Electrocatalytic Activity Towards Dopamine, Ascorbic Acid and Uric Acid

    Institute of Scientific and Technical Information of China (English)

    TENG Hong; LIU Yang; YOU Tian-yan

    2011-01-01

    A facile approach for the synthesis of gold nanoparticle-loaded carbon nanofibcr(Au/CNF) composites was developed. When applied to electrochemistry, these composites showed attractive performances such as high conductivity and facile electron transfer kinetics. Under physiological conditions, the Au/CNF composite modified electrode exhibits highly electrocatalytic activity for the oxidation of dopamine, ascorbic acid and uric acid. Owing to the good selectivity for the simultaneous detection of these three species, the novel composites are promising for the development of effective electrochemical biosensors.

  17. Numerical study of internal load transfer in metal/ceramic composites based on freeze-cast ceramic preforms and experimental validation

    Energy Technology Data Exchange (ETDEWEB)

    Sinchuk, Yuriy [Institute of Engineering Mechanics, Karlsruhe Institute of Technology, Kaiserstr. 10, 76131 Karlsruhe (Germany); Roy, Siddhartha, E-mail: siddhartha.roy@kennametal.com [Institute for Applied Materials, Karlsruhe Institute of Technology, Kaiserstr. 12, 76131 Karlsruhe (Germany); Gibmeier, Jens [Institute for Applied Materials, Karlsruhe Institute of Technology, Kaiserstr. 12, 76131 Karlsruhe (Germany); Piat, Romana [Institute of Engineering Mechanics, Karlsruhe Institute of Technology, Kaiserstr. 10, 76131 Karlsruhe (Germany); Wanner, Alexander [Institute for Applied Materials, Karlsruhe Institute of Technology, Kaiserstr. 12, 76131 Karlsruhe (Germany)

    2013-11-15

    The elastic–plastic deformation and internal load transfer in metal/ceramic composites are studied in this work both numerically and experimentally. The composite was fabricated by squeeze-casting AlSi12 melt in an open porous preform made by freeze-casting and drying of alumina suspension. Such composites exhibit a complex microstructure composed of lamellar domains. Single-domain samples were extracted from bulk material. Uniaxial compression tests were carried out parallel to the direction of the alternating metallic alloy and ceramic lamellae in the plane normal to the direction of freeze-casting. This loading mode is selected as highest load transfer occurs when loaded along the ceramic lamellae. Numerical modeling was done using the finite element method using quasi-3D microstructure based on metallographic 2D section and a modified Voigt homogenization technique assuming plastic behavior of the metallic alloy, absence of any damage and ideal interface between the phases. Internal load transfer mechanism was predicted for composites with different ceramic volume fractions. Results show that at any applied stress, as the ceramic content increases, the phase stress in alumina along the loading direction continuously decreases. Experimental validation of the numerical results is carried out by in-situ compression test along with energy dispersive synchrotron X-ray diffraction in one sample with 41 vol% ceramic. Results show that both the numerical techniques yield similar results, which match well with the experimental measurements. The ratio of the phase stress to the applied stress in alumina reaches a highest value between 2 and 2.5 up to a compressive stress of about 300 MPa. At higher applied stresses both the experimentally determined lattice microstrain and the phase stress along the loading direction in alumina decrease due to the initiation of possible damage. This study shows that the applied economic and more flexible homogenization technique is a

  18. The effect of increased loads of dissolved organic matter on estuarine microbial community composition and function

    DEFF Research Database (Denmark)

    Traving, Sachia J.; Rowe, Owen; Jakobsen, Nina M.

    2017-01-01

    phytoplankton biomass which was observed to increase towards the end of the experiment. This suggests that the nutrient access partially outweighed the negative effect of increased light attenuation by accumulating DOM. Taken together, our experimental data suggest that parts of the future elevated riverine DOM....... The DOM additions stimulated protease activity and a release of inorganic nutrients, suggesting that DOM was actively processed. However, no difference between DOM types was detected in these functions despite different community compositions. Extensive release of re-mineralized carbon, nitrogen...... and phosphorus was associated with the bacterial processing, corresponding to 25-85% of the supplied DOM. The DOM additions had a negative effect on phytoplankton with decreased Chl a and biomass, particularly during the first half of the experiment. However, the accumulating nutrients likely stimulated...

  19. Failure Behavior of Unidirectional Composites under Compression Loading: Effect of Fiber Waviness

    Directory of Open Access Journals (Sweden)

    Swaroop Narayanan Nair

    2017-08-01

    Full Text Available The key objective of this work is to highlight the effect of manufacturing-induced fiber waviness defects on the compressive failure of glass fiber-reinforced unidirectional specimens. For this purpose, in-plane, through-thickness waviness defects (with different waviness severities are induced during the manufacturing of the laminate. Numerical and experimental results show that the compressive strength of the composites decreases as the severity of the waviness defects increases. A reduction of up to 75% is noted with a wave severity of 0.075. Optical and scanning electron microscopy observations of the failed specimens reveal that kink-bands are created in the wavy regions and lead to failure.

  20. Preparation, characterization and properties of butyl acrylate-styrene- acrylonitrile copolymer/titanium dioxide composite film%丙烯酸丁酯-苯乙烯-丙烯腈共聚物/二氧化钛复合薄膜的制备、表征及性能

    Institute of Scientific and Technical Information of China (English)

    徐慧; 史铁钧; 孙建新; 杨兆攀

    2011-01-01

    先以丙烯酸丁酯、苯乙烯和丙烯腈为原料,通过种子乳液聚合制得了以聚丙烯酸丁酯为核、苯乙烯-丙烯腈共聚物为壳的核壳接枝共聚物ASA;再以钛酸正四丁酯和偶联剂γ-(甲基丙烯酰氧基)丙基三甲氧基硅(KH-570)为原料,经水解缩合生成KH-570-g-TiO粒子.将ASA与KH-570-g-TiO粒子按照一定比例溶解并超声共混,在普通玻璃表面制得了ASA/TiO复合薄膜.用傅里叶变换红外光谱、热重分析、透射电镜及紫外可见光谱等对产物和薄膜进行了分析表征.结果显示,制得的ASA接枝共聚物具有明显的核壳结构,乳液粒子大小均匀,聚丙烯酸丁酯核的平均粒径为60 nm左右,壳的平均厚为20 nm.KH-570水解的羟基与纳米TiO表面的羟基发生了缩合反应.与纯ASA薄膜相比,ASA/TiO复合薄膜在紫外区的吸收更强,且最大吸收波长蓝移;复合薄膜的耐热性能要优于纯ASA薄膜,同时耐酸碱性能有所提高.%Butyl acrylate-styrene-acrylonitrile core-shell graft copolymer( ASA ) with poly( butyl acrylate ) as core and styrene-acrylonitrile copolymer as shell was synthesized by seeded emulsion polymerization, KH-570-g-TiO2 particle was prepared through hydrolysis condensation of coupling agent KH-570 and tetra-n-butyl titanate, and ASA and KH-570-g-TiO2 were blended with a certain ratio by ultrasonic mixing. Finally , the composite films were prepared on a glass substrate and characterized by Fourier transform-infrared spectroscopy, thermogravimetric analysis, transmission electron microscope and ultraviolet-visible spectroscopy. The results showed that the ASA graft copolymer had an obvious core-shell structure and the particle size of the emulsion was homogeneous. The average diameter of poly( butyl acrylate ) core was about 60 nm,and the shell thickness was about 20 nm. The condensation reaction occurred between the hydroxyl groups from the hydrolysis of KH-570 and on TiO2 surface. The ASA-TiO2 composite

  1. Polymerisation by acrylamide and acrylic acid inverse suspension

    Directory of Open Access Journals (Sweden)

    Sergio Alejandro LLoreda Blanco

    2010-04-01

    Full Text Available This work describes polymerisation by inverse suspension of acrylamide monomers and acrylic acid for forming homopolymers or copolymers This type of polymersitaion's advantages are described and reasons given for why it should be studied. The article stresses the importance of these types of monomer for obtaining materials presenting great affinity for water, such as super-absorbents and controlled liberation mechanism. Important aspects are presented such as type of initiation, monomer composition and continuous phase composition; parameters are described offering an important basis for formulating a system leading to successfully obtaining the desired materials' most relevant characteristics such as particle distribution and size polymerisation kinetics, conversion and water absorption capacity respecting the system's modifiable parameters. The foregoing is important since the product can be modified, bestowing propierties on it which are suitable for its use.

  2. Swelling Behaviors of Polyaniline-Poly(Acrylic Acid) Hydrogels

    Institute of Scientific and Technical Information of China (English)

    ZHANG You-wei; ZHAO Jiong-xin; LI Xiao-feng; TAO Yong; WU Cheng-xun

    2005-01-01

    Using poly(acrylic acid) (PAA) aqueous solution, NaOH aqueous solution, aniline(An) and ammonim persulfate(APS), PAn-PAA hydrogels with a semi-interpenetrating structure connected by physical interlocks, chemical ion bonds and hydrogen bonds wcre prepared. The swelling properties of the hydrogels in solutions of different pH values(adjusted by adding NaOH or HCl) were studied. All the hydrogels prepared have similar swelling curves (the curves of equilibrium swelling ratio vs. pH value) and reach their maximum swelling at pH of 8 - 10. The maximum swelling ratio of the hydrogels is dependent on composition, including molecular weight of PAA, polymer content of the hydrogel,and molar ratios of AA to An, APS to An, and NaOH to AA.And the compositional dependence of the swelling capacity of PAn-PAA hydrogels was also studied.

  3. Photochemistry of acrylates at 222 nm

    Science.gov (United States)

    Knolle, Wolfgang; Naumov, Sergej; Madani, Mohamed; von Sonntag, Clemens

    2005-07-01

    Excimer lamps as monochromatic UV sources with an intense short-wavelength emission (especially KrCl∗, 222 nm) allow a photoinitiator-free initiation of the acrylate polymerisation. Laser photolysis (KrCl∗ excimer laser, pulse width 20 ns, up to 5 mJ per pulse) gives rise to similar transient spectra (λmax ≈ 280 nm) for all acrylates studied. As the rather unspecific spectra do not allow conclusions as to the main reaction channel, a product study has been performed by GC-MS following steady-state photolysis of acrylate solutions in acetonitrile, methanol and n-hexane. Somewhat unexpected, α-cleavage seems to be a main reaction channel, and quantum chemical calculations show that such a reaction can occur from either the excited singlet state or the unrelaxed triplet state, but not from the relaxed triplet state that is observed spectroscopically. A reaction scheme accounting for the observed products is presented.

  4. Synthesis of the Supported Au Polystyrene/poly(acrylic acid) Composite Microspheres and Their pH Regulated Performance†%负载金纳米粒子的聚苯乙烯/聚丙烯酸微球的合成及pH响应性能

    Institute of Scientific and Technical Information of China (English)

    滕小波; 张春霞; 张颖

    2016-01-01

    The core-shell polystyrene( PS)/poly( acrylic acid) ( PAA) composite microgels with pH sensitivity were synthesized via two-step polymerization method. Au nanoparticles were supported onto pH sensitivity composite microgels via in situ reduction of chloroauric acid ( HAuCl4 ) using NaBH4 as reduction agent and sodium citrate as stabilizer. The results demonstrated that the plasmonic coupling of gold nanoparticles could be regulated, and the diffusion of reactive substrates availably controlled, due to the shrinkage and swelling performance of the shell chains under the different acid and alkali conditions. The optical property and catalytic activity of Au NPs could be regulated by changing the micro-environment of composite microgels. Therefore, the performance of composite materials could be realized the pH-controllable.%以两步聚合法合成的聚苯乙烯( PS)/聚丙烯酸( PAA)核-壳结构复合微凝胶为载体,硼氢化钠为还原剂,柠檬酸钠为稳定剂,通过原位控制性还原获得pH敏感性微凝胶负载纳米金粒子的PS/PAA-Au复合材料。研究发现,不同酸碱条件时,复合微凝胶壳层高分子链的溶胀/收缩变化,不仅可以调节纳米金粒子的表面等离子吸收,还可以调节反应底物的扩散传质,即借助载体微环境的变化来调控纳米金光学性能和催化性能,从而实现复合纳米金材料的pH调控性。

  5. Ag/AgCl Loaded Bi2WO6 Composite: A Plasmonic Z-Scheme Visible Light-Responsive Photocatalyst

    Directory of Open Access Journals (Sweden)

    Xiangchao Meng

    2016-01-01

    Full Text Available Hierarchical flower-like Bi2WO6 was successfully synthesized by facile hydrothermal method at low pH. And Ag/AgCl was loaded by photoreduction on its surface. As-prepared photocatalysts were characterized by various techniques. Bi2WO6 was successfully synthesized at a size of 2-3 μm. Depositing Ag/AgCl did not destroy the crystal structure, and both Ag+ and metallic Ag0 were found. The band gap of the composite was 2.57 eV, which indicates that visible light could be the activating irradiation. In the photocatalytic activity test, the composite with 10 wt% Ag/AgCl boasted the highest removal efficiency (almost 100% in 45 min. The significant enhancement can be attributed to the surface plasmon resonance (SPR effect and the establishment of heterostructures between Ag/AgCl and Bi2WO6. A possible mechanism of photocatalytic oxidation in the presence of Ag/AgCl-Bi2WO6 was proposed. This work sheds light on the potential applications of plasmonic metals in photocatalysis to enhance their activities.

  6. Fatigue life prediction in a unidirectional glass-epoxy composite material subjected to off-axis cyclic loads

    Directory of Open Access Journals (Sweden)

    Revuelta, D.

    2005-03-01

    Full Text Available Most of today s fatigue analysis and design methods for composite laminates were developed primarily on the basis of experience with homogeneous metals. Such methods are subject to serious drawbacks, however, because the failure the modes of failure observed in metals. A theoretical model for predicting the fatigue life of continuous glass-fibre/epoxy composite materials under general loading conditions has been developed on the basis of fundamental fatigue failure modes and local failure criteria.

    La mayoría de los actuales métodos de cálculo y diseño a fatiga de estructuras de materiales compuestos se han desarrollado principalmente a partir de la experiencia previa en materiales metálicos homogéneos. Sin embargo, estos métodos presentan serios inconvenientes debido a que la heterogeneidad y micro estructura orientada características de los materiales compuestos laminados provocan modos de fallo diferentes a los de los metales. Basándose en los modos fundamentales de rotura por fatiga y en criterios de rotura local, se desarrolla un modelo teórico de vida a fatiga para materiales compuestos de matriz epoxi reforzados con fibra de vidrio bajo condiciones generales de carga

  7. Enhanced photocatalytic degradation of phenol and photogenerated charges transfer property over BiOI-loaded ZnO composites.

    Science.gov (United States)

    Jiang, Jingjing; Wang, Hongtao; Chen, Xiaodong; Li, Shuo; Xie, Tengfeng; Wang, Dejun; Lin, Yanhong

    2017-05-15

    In this paper, a series of BiOI/ZnO photocatalysts containing various BiOI contents were prepared by a facile two-step synthetic method. The structure and crystal phase, morphology, surface element analysis, optical property of as-prepared samples are measured by X-ray diffraction (XRD), Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and UV-Vis diffuse reflectance spectrometry (DRS). BiOI/ZnO photocatalytic activities of the prepared photocatalysts were evaluated by photocatalytic degradation of phenol under simulated light irradiation. The phenol degradation rate reached 99.9% within 2h under simulated solar light irradiation. The probable photocatalytic mechanism of composites photocatalysts is discussed by active species trapping experiments, the surface photovoltage (SPV), the transient photovoltage (TPV) and photoluminescence (PL) measurements. The results manifest that the superior photocatalytic activity of BiOI/ZnO composites is derived from the strong internal electric field between BiOI and ZnO, which is beneficial for the effective separation and transfer of photogenerated charges in ZnO. Moreover, the loading of BiOI on the surface of ZnO inhibited the recombination of photogenerated charge carriers in ZnO, resulting in excellent photocatalytic activity. On the contrary, the effect of an extension of the light absorption range induced by the introduction of BiOI on the phenol degradation activity is not significant.

  8. The effect of fibre layering pattern in resisting bending loads of natural fibre-based hybrid composite materials

    Directory of Open Access Journals (Sweden)

    Jusoh Muhamad Shahirul Mat

    2016-01-01

    Full Text Available The effect of fibre layering pattern and hybridization on the flexural properties of composite hybrid laminates between natural fibres of basalt, jute and flax with synthetic fibre of E-glass reinforced epoxy have been investigated experimentally. Results showed that the effect fibre layering pattern was highly significant on the flexural strength and modulus, which were strongly dependent on the hybrid configuration between sandwich-like (SL and intercalation (IC sequence of fibre layers. In addition, specific modulus based on the variation densities of the hybrid laminates was used to discover the best combination either basalt, jute or flax with E-glass exhibits superior properties concerning on the strength to weight-ratio. Generally, SL sequence of glass/basalt exhibited superior strength and stiffness compared with glass/jute and glass/flax in resisting bending loads. In terms of hybridization effect, glass/jute was found to be the best combination with E-glass compared to the rest of natural fibres investigated in the present study. Hence, the proper stacking sequences and material selection are among predominant factors that influence on mechanical properties and very crucial in designing composite hybrid system to meet the desired requirements.

  9. Relationship Between Hysteresis Dissipated Energy and Temperature Rising in Fiber-Reinforced Ceramic-Matrix Composites Under Cyclic Loading

    Science.gov (United States)

    Longbiao, Li

    2016-06-01

    In this paper, the relationship between hysteresis dissipated energy and temperature rising of the external surface in fiber-reinforced ceramic-matrix composites (CMCs) during the application of cyclic loading has been analyzed. The temperature rise, which is caused by frictional slip of fibers within the composite, is related to the hysteresis dissipated energy. Based on the fatigue hysteresis theories considering fibers failure, the hysteresis dissipated energy and a hysteresis dissipated energy-based damage parameter changing with the increase of cycle number have been investigated. The relationship between the hysteresis dissipated energy, a hysteresis dissipated energy-based damage parameter and a temperature rise-based damage parameter have been established. The experimental temperature rise-based damage parameter of unidirectional, cross-ply and 2D woven CMCs corresponding to different fatigue peak stresses and cycle numbers have been predicted. It was found that the temperature rise-based parameter can be used to monitor the fatigue damage evolution and predict the fatigue life of fiber-reinforced CMCs.

  10. Adding glycaemic index and glycaemic load functionality to DietPLUS, a Malaysian food composition database and diet intake calculator.

    Science.gov (United States)

    Shyam, Sangeetha; Wai, Tony Ng Kock; Arshad, Fatimah

    2012-01-01

    This paper outlines the methodology to add glycaemic index (GI) and glycaemic load (GL) functionality to food DietPLUS, a Microsoft Excel-based Malaysian food composition database and diet intake calculator. Locally determined GI values and published international GI databases were used as the source of GI values. Previously published methodology for GI value assignment was modified to add GI and GL calculators to the database. Two popular local low GI foods were added to the DietPLUS database, bringing up the total number of foods in the database to 838 foods. Overall, in relation to the 539 major carbohydrate foods in the Malaysian Food Composition Database, 243 (45%) food items had local Malaysian values or were directly matched to International GI database and another 180 (33%) of the foods were linked to closely-related foods in the GI databases used. The mean ± SD dietary GI and GL of the dietary intake of 63 women with previous gestational diabetes mellitus, calculated using DietPLUS version3 were, 62 ± 6 and 142 ± 45, respectively. These values were comparable to those reported from other local studies. DietPLUS version3, a simple Microsoft Excel-based programme aids calculation of diet GI and GL for Malaysian diets based on food records.

  11. Development and characterization of cefazolin loaded zinc oxide nanoparticles composite gelatin nanofiber mats for postoperative surgical wounds

    Energy Technology Data Exchange (ETDEWEB)

    Rath, Goutam, E-mail: goutamrath123@gamil.com [Department of Pharmaceutics, ISF College of Pharmacy, Moga, Punjab (India); PhD Research Scholar at Punjab Technical University, Jalandhar, Punjab (India); Hussain, Taqadus, E-mail: taqadus.hussain@gmail.com [Department of Pharmaceutics, ISF College of Pharmacy, Moga, Punjab (India); Chauhan, Gaurav, E-mail: gauravpharmaorg@gmail.com [Department of Pharmaceutics, ISF College of Pharmacy, Moga, Punjab (India); Garg, Tarun, E-mail: tarun.garg9@gmail.com [Department of Pharmaceutics, ISF College of Pharmacy, Moga, Punjab (India); Goyal, Amit Kumar, E-mail: amitkumargoyal1979@gmail.com [Department of Pharmaceutics, ISF College of Pharmacy, Moga, Punjab (India)

    2016-01-01

    Systemic antibiotic therapy in post-operative wound care remain controversial leading to escalation in levels of multi-resistant bacteria with unwanted morbidity and mortality. Recently zinc (Zn) because of multiple biophysiological functions, gain considerable interest for wound care. Based on our current understanding, the present study was designed with an intent to produce improve therapeutic approaches for post-operative wound management using composite multi-functional antibiotic carrier. The study involved the fabrication, characterization and pre-clinical evaluation of cefazolin nanofiber mats loaded with zinc oxide (ZnO) and comparing co-formulated mats with individual component, enable a side by side comparison of the benefits of our intervention. Minimum inhibitory concentration (MIC) of the drug, ZnO nanoparticles (ZnONPs) and drug-ZnONP mixture against Staphylococcus aureus was determined using micro dilution assay. The fabricated nanofibers were then evaluated for in-vitro antimicrobial activity and the mechanism of inhibition was predicted by scanning electron microscopy (SEM). Further these nanofiber mats were evaluated in-vivo for wound healing efficacy in Wistar rats. Study revealed that the average diameter of the nanofibers is around 200–900 nm with high entrapment efficiency and display sustained drug release behavior. The combination of ZnO and cefazolin in 1:1 weight ratio showed higher anti-bacterial activity of 1.9 ± 0.2 μg/ml. Transmission electron microscopy of bacterial cells taken from the zone of inhibition revealed the phenomenon of cell lysis in tested combination related to cell wall disruption. Further composite medicated nanofiber mats showed an accelerated wound healing as compared to plain cefazolin and ZnONP loaded mats. Macroscopical and histological evaluations demonstrated that ZnONP hybrid cefazolin nanofiber showed enhanced cell adhesion, epithelial migration, leading to faster and more efficient collagen synthesis

  12. Radiation Shielding System Using a Composite of Carbon Nanotubes Loaded with Electropolymers

    Science.gov (United States)

    McKay, Chris; Chen, Bin

    2012-01-01

    Single-wall carbon nanotubes (SWCNTs) coated with a hydrogen-rich, electrically conducting polymer such as polyethylene, receive and dissipate a portion of incoming radiation pulse energy to electrical signals that are transmitted along the CNT axes, and are received at energy-dissipating terminals. In this innovation, an array of highly aligned nanowires is grown using a strong electric field or another suitable orientation procedure. Polyethylene (PE), polymethymlethacrylate (PMMA), or other electrically conducting polymer is spin-coated onto the SWCNTs with an average thickness of a few hundred nanometers to a few tenths of micrometers to form a PE/SWCNT composite. Alternatively, the polymer is spin-coated onto the nanowire array or an anodized alumina membrane (AAM) to form a PE/metal core shell structure, or PE can be electropolymerized using the SWCNTs or the metal nanowires as an electrode to form a PE/SWCNT core shell structure. The core shell structures can be extruded as anisotropic fibers. A monomer can be polymerized in the presence of SWCNTs to form highly cross-linked PE/SWCNT films. Alternatively, Pb colloid solution can be impregnated into a three-dimensional PE/SWCNT nanostructure to form a PW/SWCNT/Pb composite structure. A face-centered cubic (FCC) arrangement provides up to 12 interconnection channels connected to each core, with transverse channel dimensions up to 20 nm, with adequate mechanical compressive strength, and with an associated electrical conductivity of around 3 Seimens/cm for currents ranging from 0.01 to 10 mA. This threedimensional nanostructure is used as a host material to house appropriate radiation shielding material such as hydrogen- rich polymer/CNT structures, metal nanoparticles, and nanowires. Thicknesses of this material required to attenuate 10 percent, 50 percent, and 90 percent of an incident beam (gamma, X-ray, ultraviolet, neutron, proton, and electron) at energies in the range of 0 440 MeV are being determined

  13. Osteoinductivity Assessment of BMP-2 Loaded Composite Chitosan-Nano-Hydroxyapatite Scaffolds in a Rat Muscle Pouch

    Directory of Open Access Journals (Sweden)

    Warren O. Haggard

    2011-08-01

    Full Text Available The objective of this study was to evaluate the osteoinductivity of composite chitosan-nano-hydroxyapatite scaffolds in a rat muscle pouch model. Previous in vitro characterization demonstrated the ability of the scaffolds to promote bone regeneration and as a carrier for local delivery of BMP-2. Composite microspheres were prepared using a co-precipitation method, and scaffolds were fabricated using an acid wash to adhere beads together. To determine the in vivo osteoinductivity of the scaffolds, the following groups (n = 6 were implanted into muscle pouches created in the latissimus dorsi of Sprague Dawley rats: (A lyophilized scaffolds without rhBMP-2, (B lyophilized scaffolds with rhBMP-2, (C non-lyophilized scaffolds with rhBMP-2, and (D absorbable collagen sponge with rhBMP-2 (control. Groups B, C, and D were loaded with 4 mL of a 9.0 μg/mL solution of rhBMP-2 for 48 h. The rats were sacrificed after one month and samples were analyzed for amount of residual implant material, new bone, and osteoid. Although the experimental groups displayed minimal degradation after one month, all of the scaffolds contained small amounts of woven bone and considerable amounts of osteoid. Approximately thirty percent of the open space available for tissue ingrowth in the scaffolds contained new bone or osteoid in the process of mineralization. The ability of the composite scaffolds (with and without BMP-2 to promote ectopic bone growth in vivo was demonstrated.

  14. Concepts for stereoselective acrylate insertion

    KAUST Repository

    Neuwald, Boris

    2013-01-23

    Various phosphinesulfonato ligands and the corresponding palladium complexes [{((PaO)PdMeCl)-μ-M}n] ([{( X1-Cl)-μ-M}n], (PaO) = κ2- P,O-Ar2PC6H4SO2O) with symmetric (Ar = 2-MeOC6H4, 2-CF3C6H4, 2,6-(MeO)2C6H3, 2,6-(iPrO)2C 6H3, 2-(2′,6′-(MeO)2C 6H3)C6H4) and asymmetric substituted phosphorus atoms (Ar1 = 2,6-(MeO)2C6H 3, Ar2 = 2′-(2,6-(MeO)2C 6H3)C6H4; Ar1 = 2,6-(MeO)2C6H3, Ar2 = 2-cHexOC 6H4) were synthesized. Analyses of molecular motions and dynamics by variable temperature NMR studies and line shape analysis were performed for the free ligands and the complexes. The highest barriers of ΔGa = 44-64 kJ/mol were assigned to an aryl rotation process, and the flexibility of the ligand framework was found to be a key obstacle to a more effective stereocontrol. An increase of steric bulk at the aryl substituents raises the motional barriers but diminishes insertion rates and regioselectivity. The stereoselectivity of the first and the second methyl acrylate (MA) insertion into the Pd-Me bond of in situ generated complexes X1 was investigated by NMR and DFT methods. The substitution pattern of the ligand clearly affects the first MA insertion, resulting in a stereoselectivity of up to 6:1 for complexes with an asymmetric substituted phosphorus. In the consecutive insertion, the stereoselectivity is diminished in all cases. DFT analysis of the corresponding insertion transition states revealed that a selectivity for the first insertion with asymmetric (P aO) complexes is diminished in the consecutive insertions due to uncooperatively working enantiomorphic and chain end stereocontrol. From these observations, further concepts are developed. © 2012 American Chemical Society.

  15. Influence of the Purity of Attapuigite on Water Absorbency of Carboxymethyl-cellulose Sodium/Poly(acrylic acid)/Attapulgite Superabsorbent Composites%凹凸棒黏土纯度对复合高吸水性树脂吸水性能的影响

    Institute of Scientific and Technical Information of China (English)

    陈红; 王文波; 王爱勤

    2011-01-01

    Carboxymethylcellulose sodium-g-poly ( acrylic acid )/attapulgite superabsorbent composites were prepared by aqueous solution polymerization, using N, N'-methylenebisacrylamide as crosslinker and ammonium petrsulfate as an initiator in the presence of different purity of attapulgite.The influence of the purity of attapulgite on water absorbency, water absorption rate and swelling properties in different pH medium were studied.FTIR spectra demonstrates that acrylic acid monomers were grafted onto the backbone of earboxymethylcellulose sodium backbone, and attapulgite participated in polymerization through its active silanol groups.FESEM observation shows that attapulgite fibrils led to a better dispersion in the polymeric matrix and improved the surface porous strueture of the matrix.More Ca2+ and Mg2+ in attapulgite are conducive to improving the swelling behaviors of the superabsorbent composites with the same content of attapulgite.%将凹凸棒黏土分级处理后,以不同纯度的凹凸棒黏土为无机组分,过硫酸铵为引发剂,N,N'-亚甲基双丙烯酰胺为交联剂,制备了羧甲基纤维素接枝丙烯酸/凹凸棒黏土复合高吸水性树脂,考察了复合高吸水性树脂的吸水倍率、吸水速率和在不同pH介质中的溶胀性能.红外光谱表明,丙烯酸已接枝到羧甲基纤维素的骨架上,凹凸棒黏土参与了聚合反应.扫描电镜观察表明,凹凸棒黏土在高吸水性树脂中有良好的分散性能,改善了基体表面的多孔结构.研究表明,在相同添加量下,凹凸棒黏土中含有更多的Ca和Mg离子,有助于改善复合高吸水性树脂的综合性能.

  16. Fatigue Performance Assessment of Composite Arch Bridge Suspenders Based on Actual Vehicle Loads

    Directory of Open Access Journals (Sweden)

    Bin Chen

    2015-01-01

    Full Text Available In the through arch bridges, the suspenders are the key components connecting the arch rib and the bridge deck in the middle, and their safety is an increasing focus in the field of bridge engineering. In this study, various vehicle traffic flow parameters are investigated based on the actual vehicle data acquired from the long-term structural health monitoring system of a composite arch bridge. The representative vehicle types and the probability density functions of several parameters are determined, including the gross vehicle weight, axle weight, time headway, and speed. A finite element model of the bridge structure is constructed to determine the influence line of the cable force for various suspenders. A simulated vehicle flow, generated using the Monte Carlo method, is applied on the influence lines of the target suspender to determine the stress process, and then the stress amplitude spectrum is obtained based on the statistical analysis of the stress process using the rainflow counting method. The fatigue performance levels of various suspenders are analyzed according to the Palmgren-Miner linear cumulative damage theory, which helps to manage the safety of the suspenders.

  17. Effect of thermal shock loadings on stability of dentin-composite polymer material adhesive interfaces

    Science.gov (United States)

    Bessudnova, Nadezda O.; Shlyapnikova, Olga A.; Venig, Sergey B.; Gribov, Andrey N.

    2015-03-01

    In the past several decades the problem of longevity and durability of adhesive interfaces between hard tooth tissues and composite resin-based materials are of great interest among dental researchers and clinicians. These parameters are partially determined by adhesive system mechanical properties. In the present research project nanoindentation has been examined to test hardness of dental adhesive systems. A series of laboratory experiments was performed to study the effect of light curing time and oxygen inhibition phenomenon on light-cured adhesive material hardness. An adhesive system AdperTM Single Bond (3M ESPE) was selected as a material for testing. The analysis of experimental data revealed that the maximum values of hardness were observed after the material had been light-cured for 20 seconds, as outlined in guidelines for polymerization time of the adhesive system. The experimental studies of oxygen inhibition influence on adhesive system hardness pointed out to the fact that the dispersive layer removal led to increase in adhesive system hardness. A long - time exposure of polymerized material of adhesive system at open air at room temperature resulted in no changes in its hardness, which was likely to be determined by the mutual effect of rival processes of air oxygen inhibition and directed light curing.

  18. Investigation of Ionic Polymer Metal Composite Actuators Loaded with Various Tetraethyl Orthosilicate Contents

    Institute of Scientific and Technical Information of China (English)

    Qingsong He; Min Yu; Yuxiu Li; Yan Ding; Dongjie Guo; Zhendong Dai

    2012-01-01

    Ionic Polymer Metal Composite (IPMC) can be used as an electrically activated actuator,which has been widely used in artificial muscles,bionic robotic actuators,and dynamic sensors since it has the advantages of large deformation,light weight,flexibility,and low driving voltage,etc.To further improve the mechanical properties of IPMC,this paper reports a new method for preparing organic-inorganic hybrid Nafion/SiO2 membranes.Beginning from cast Nation membranes,IPMCs with various tetraethyl orthosilicate (TEOS) contents were fabricated by electroless plating.The elastic moduli of cast Nation membranes were measured with nano indenters,the water contents were calculated,and the cross sections of Nafion membranes were observed by scanning electron microscopy.The blocking force,the displacement,and the electric current of IPMCs were then measured on a test apparatus.The results show that the blocking force increases as the TEOS content gradually increases,and that both the displacement and the electric current initially decrease,then increase.When the TEOS content is 1.5%,the IPMC shows the best improved mechanical properties.Finally,the IPMC with the best improved performance was used to successfully actuate the artificial eye and tested.

  19. Sustainable Antibiofouling Properties of Thin Film Composite Forward Osmosis Membrane with Rechargeable Silver Nanoparticles Loading.

    Science.gov (United States)

    Liu, Zhongyun; Hu, Yunxia

    2016-08-24

    Microbial attachment and biofilm formation on filtration membrane can greatly compromise its flux and separation efficiency. Here, a simple and facile approach has been developed to in situ generate silver nanoparticles (Ag NPs) on the thin film composite forward osmosis (TFC FO) membrane for sustainable antibiofouling performances. Mussel-inspired dopamine chemistry was applied to grow polydopamine coating on both surfaces of FO membranes, followed by the generation of Ag NPs upon a simple dip coating in silver nitrate aqueous solution. Furthermore, the Ag NPs deposited membranes had a long-term silver release profile with rechargability for multiple times upon their depletion, and exhibited strong sustainable bactericidal efficacy against Gram-negative bacteria and Gram-positive bacteria. The Ag NPs had a controllable effect on the membrane performances including the water flux and reverse salt flux in the FO test mode. Our practicable antibacterial strategy may apply to other types of filtration membranes with diverse material surfaces and may pave a new way to achieve the sustainable membrane antibiofouling performance on a large scale.

  20. Dexamethasone-loaded poly(D, L-lactic acid) microspheres/poly(ethylene glycol)-poly(epsilon-caprolactone)-poly(ethylene glycol) micelles composite for skin augmentation.

    Science.gov (United States)

    Fan, Min; Liao, Jinfeng; Guo, Gang; Ding, Qiuxia; Yang, Yi; Luo, Feng; Qian, Zhiyong

    2014-04-01

    Soft tissue augmentation using various injectable fillers has gained popularity as more patients seek esthetic improvement through minimally invasive procedures requiring little or no recovery time. The currently available injectable skin fillers can be divided into three categories. With careful assessment, stimulatory fillers are the most ideal fillers. In this study, dexamethasone-loaded poly(D, L-lactic acid) (PLA) microspheres of approximately 90 micro m suspended in poly(ethylene glycol)-poly(epsilon-caprolactone)-poly(ethylene glycol) (PEG-PCL-PEG, PECE) micelles were prepared as stimulatory filler for skin augmentation. The biodegradable PECE copolymer can form nano-sized micelles in water, which instantly turns into a non-flowing gel at body temperature due to micellar aggregation. The PECE micelles (making up 90% of composite) served as vehicle for subcutaneous injection were metabolized within 44 days. At the same time, the dexamethasone-loaded PLA microspheres (10% of composite) merely served as stimulus for connective tissue formation. Dexamethasone-loaded PLA microspheres/PECE micelles composite presented great hemocompatibility in vitro. It was demonstrated in the in vive study that the composite was biodegradable, biocompatible, nontoxic and nonmigratory. Histopathological studies indicated that the composite could stimulate collagen regeneration. Furthermore, granuloma, the main complication of the stimulatory fillers, did not appear when the composite was injected into the back of SD rats, because of the dexamethasone controlled release from the composite. All results suggested that dexamethasone-loaded PLA microspheres/PECE micelles composite may be an efficient and promising biomaterial for skin augmentation.