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Sample records for acrylic composites loaded

  1. Radiation sensitive acrylate composition

    International Nuclear Information System (INIS)

    This application relates to radiation-sensitive compositions and more particularly to such compositions comprising acrylated esters. As used in this specification, the term acrylated esters refers to either acrylic or methacrylic acid resins. 3 tabs

  2. Permittivity and Electromagnetic Interference Shielding Investigations of Activated Charcoal Loaded Acrylic Coating Compositions

    Directory of Open Access Journals (Sweden)

    Sharief ud Din Khan

    2014-01-01

    Full Text Available Acrylic resin (AR based electromagnetic interference (EMI shielding composites have been prepared by incorporation of up to 30 wt% activated charcoal (AC in AR matrix. These composites have been characterized by XRD, Raman spectroscopy, scanning electron microscopy, dielectric, and EMI shielding measurement techniques. XRD patterns and Raman studies confirm the incorporation of AC particles inside AR matrix and suggest possible interactions between phases. The SEM images show that incorporation of AC particles leads to systematic change in the morphology of composites especially the formation of porous structure. The dielectric measurements show that 30 wt% AC loading composite display higher relative permittivity value (~79 compared to pristine AR (~5. Further, the porous structure, electrical conductivity, and permittivity value contribute towards EMI shielding effectiveness value of −36 dB (attenuation of >99.9% of incident radiation for these composites, thereby demonstrating their suitability for making efficient EMI shielding coatings.

  3. Minocycline-loaded cellulose nano whiskers/poly(sodium acrylate) composite hydrogel films as wound dressing.

    Science.gov (United States)

    Bajpai, S K; Pathak, V; Soni, Bhawna

    2015-08-01

    In this work, antibiotic drug Minocycline (Mic) loaded cellulose nano-whiskers (CNWs)/poly(sodium acrylate) hydrogel films were prepared and investigated for their drug releasing capacity in physiological buffer solution (PBS) at 37 °C. The (CNWs)/poly(sodium acrylate) film, containing 9.7% (w/w) of CNWs, demonstrated Mic release of 2500 μg/g while the plain poly(acrylate) film showed 3100 μg/g of drug release. In addition, with the increase in the concentration of cross-linker N,N'-methylene bisacrylamide (MB) from to, the drug release from the resulting films decreased from 507 to 191 μg/g. The release exponent 'n' for films with different compositions was found in the range of 0.45 to 0.89, thus indicating non-Fickian release mechanism. The Schott model was employed to interpret the kinetic drug release data successfully. The film samples poly(SA) and CNWs/poly(SA) (both not containing drug) showed thrombus formation of 0.010±0.001 g and 0.007±0.001 g, respectively, thus showing the non-thrombogenic behavior. In percent Hemolysis, both of the film samples of 1.136±0.012 and 0.5±0.020, respectively, thus indicating non-hemolytic behavior. In addition, both of the film samples demonstrated protein adsorption of 49.02±0.59μ g/μL and 51.20±0.51 μg/μL per cm(2), thus revealing a fair degree of protein adsorption. Finally, the Mic-loaded films showed fair anti-fungal and antibacterial properties.

  4. Permittivity and Electromagnetic Interference Shielding Investigations of Activated Charcoal Loaded Acrylic Coating Compositions

    OpenAIRE

    Sharief ud Din Khan; Manju Arora; Wahab, M. A.; Parveen Saini

    2014-01-01

    Acrylic resin (AR) based electromagnetic interference (EMI) shielding composites have been prepared by incorporation of up to 30 wt% activated charcoal (AC) in AR matrix. These composites have been characterized by XRD, Raman spectroscopy, scanning electron microscopy, dielectric, and EMI shielding measurement techniques. XRD patterns and Raman studies confirm the incorporation of AC particles inside AR matrix and suggest possible interactions between phases. The SEM images show that incorpo...

  5. Poly(lauryl acrylate) and poly(stearyl acrylate) grafted multiwalled carbon nanotubes for polypropylene composites

    DEFF Research Database (Denmark)

    Daugaard, Anders Egede; Jankova Atanasova, Katja; Hvilsted, Søren

    2014-01-01

    Two new polymer grafts on an industrial grade multiwalled carbon nanotube (MWCNT) were prepared through a non-oxidative pathway employing controlled free radical polymerization for surface initiated polymer grafting. After photochemical introduction of an ATRP initiator onto the MWCNT......, polymerizations of lauryl or stearyl acrylate were performed, resulting in two novel polymer modifications on the MWCNT (poly(lauryl acrylate) or poly(stearyl acrylate)). The method was found to give time dependent loading of polymers as a function of time (up to 38 wt% for both acrylates), and showed a plateau...... in loading after 12 h of polymerization. The modified nanomaterials were melt mixed into polypropylene composites with very low filler loading (0.3 wt%), whereafter both the thermal and electrical properties were investigated by DSC and dielectric resonance spectroscopy. The electrical properties were found...

  6. Biocompatibility of alendronate-loaded acrylic cement for vertebroplasty

    Directory of Open Access Journals (Sweden)

    T Calvo-Fernández

    2010-10-01

    Full Text Available This paper reports a biological evaluation of a non-resorbable acrylic cement loaded with alendronate for the treatment of osteoporotic vertebral compression fractures. The cement formulation was based on polymethyl methacrylate and acrylic monomers; one of these had covalently linked vitamin E residues. The same cement in the absence of alendronate was used as a control. The setting of the charged cement presented a maximum polymerization temperature of 44ºC, a setting time of 24 min, a residual monomer content lower than 3 wt.%, a compressive strength of 99±10 MPa and an elastic modulus of 1.2±0.2 GPa. Cytotoxicity studies using human osteoblast cultures revealed that the leachable substances of the alendronate loaded cement collected between 1 and 7 days decreased cell viability to values lower than 80%. However, morphological changes and cellular damage in cells produced by the extracts decreased with the leak time. Cell adhesion and growth on charged cement was significantly lower than on the control. Implantation of the cement paste in the intra-femoral cavity of rabbits showed that initially the osteogenic activity was evident for the cement charged with alendronate, and the osteosynthesis process took place mainly in the trabeculae and was manifested by the presence of a non-mineralised osseous spicule. The interface between material and adjacent bone tissue was initially characterized by a variable fibrous response that in many cases it appeared reduced to thin connective tissue after a 24-week-period.

  7. In Situ Synthesis of Reduced Graphene Oxide-Reinforced Silicone-Acrylate Resin Composite Films Applied in Erosion Resistance

    Directory of Open Access Journals (Sweden)

    Yang Cao

    2015-01-01

    Full Text Available The reduced graphene oxide reinforced silicone-acrylate resin composite films (rGO/SAR composite films were prepared by in situ synthesis method. The structure of rGO/SAR composite films was characterized by Raman spectrum, atomic force microscope, scanning electron microscopy, and thermogravimetric analyzer. The results showed that the rGO were uniformly dispersed in silicone-acrylate resin matrix. Furthermore, the effect of rGO loading on mechanical properties of composite films was investigated by bulge test. A significant enhancement (ca. 290% and 320% in Young’s modulus and yield stress was obtained by adding the rGO to silicone-acrylate resin. At the same time, the adhesive energy between the composite films and metal substrate was also improved to be about 200%. Moreover, the erosion resistance of the composite films was also investigated as function of rGO loading. The rGO had great effect on the erosion resistance of the composite films, in which the Rcorr (ca. 0.8 mm/year of composite film was far lower than that (28.7 mm/year of pure silicone-acrylate resin film. Thus, this approach provides a novel route to investigate mechanical stability of polymer composite films and improve erosion resistance of polymer coating, which are very important to be used in mechanical-corrosion coupling environments.

  8. The influence of ultrasound on the release of gentamicin from antibiotic-loaded acrylic beads and bone cements

    NARCIS (Netherlands)

    Ensing, GT; Hendriks, JGE; Jongsma, JE; van Horn, [No Value; van der Mei, HC; Busscher, HJ

    2005-01-01

    Gentamicin-loaded acrylic beads are loosely placed in infected bone cavities, whereas gentamicin-loaded acrylic bone cement is used as a mechanical filler in bone to anchor prosthetic components. Both drug delivery systems are used to decrease infection rates by gentamicin release. The objective of

  9. Influence of Sea Water Aging on the Mechanical Behaviour of Acrylic Matrix Composites

    Science.gov (United States)

    Davies, P.; Le Gac, P.-Y.; Le Gall, M.

    2016-07-01

    A new matrix resin was recently introduced for composite materials, based on acrylic resin chemistry allowing standard room temperature infusion techniques to be used to produce recyclable thermoplastic composites. This is a significant advance, particularly for more environmentally-friendly production of large marine structures such as boats. However, for such applications it is essential to demonstrate that composites produced with these resins resist sea water exposure in service. This paper presents results from a wet aging study of unreinforced acrylic and glass and carbon fibre reinforced acrylic composites. It is shown that the acrylic matrix resin is very stable in seawater, showing lower property losses after seawater aging than those of a commonly-used epoxy matrix resin. Carbon fibre reinforced acrylic also shows good property retention after aging, while reductions in glass fibre reinforced composite strengths suggest that specific glass fibre sizing may be required for optimum durability.

  10. Loading rate effects on the fracture of Ni/Au nano-coated acrylic particles

    OpenAIRE

    Zhang, Z. L.; He, J. Y.; Nagao, S; Kristiansen, H.

    2012-01-01

    Mechanical failure of monodisperse Ni/Au coated acrylic particles has been investigated by individual compression tests using nanoindentation-based technique equipped with a flat diamond punch. We have found that both fracture property and morphology of particles depend on the compression loading rate. The breaking strain of the metal coating decreases with increasing loading rate, while the breaking stress increases. Two obvious fracture patterns with cracking in meridian or latitude directi...

  11. Effects of composition and layer thickness of a butyl acrylate/acrylic acid copolymer on the adhesion properties

    Energy Technology Data Exchange (ETDEWEB)

    Ghim, Deoukchen; Kim, Jung Hyeun [University of Seoul, Seoul (Korea, Republic of)

    2016-02-15

    Acrylic pressure-sensitive adhesives are synthesized by solution copolymerization using n-butyl acrylate and acrylic acid (AA) in ethyl acetate anhydrous. The copolymer composition is controlled for good adhesive properties by varying AA content. The monomer conversion is measured by the gravimetric method and FTIR technique. The adhesive layer thickness is measured by scanning electron microscopy, and the adhesive properties are evaluated with loop tack, 180 .deg. peel, and holding time measurements. The peel force increases with increasing the AA content up to 3 wt% and decreases at the AA content higher than 3 wt%, but the tack force decreases with increasing the AA content. The holding time increases with increasing the AA content, and it shows a similar trend with the T{sub g} of adhesives. The increase of layer thickness improves tack and peel forces, but it weakens the holding power. A tape thickness of about 20 μm shows well-balanced properties at 3 wt% AA content in the acrylic copolymer system.

  12. Synthesis of Acrylic Acid/Kaoline Powder Superabsorbent Composite by Inverse-suspending Polymerization

    Institute of Scientific and Technical Information of China (English)

    ZHONG Jin-feng; XUE Yi-ming; WU Ji-huai; LIN Jian-ming; WEI Yue-lin

    2004-01-01

    An acrylic acid/kaoline powder superabsorbent composite with a water absorbency of the superabsorbent composite about 1/800 was synthesized by inverse-suspending polymerization reaction between acrylic acid monomer and kaoline ultrafine powder. The influence of the dispersant agent on the configuration of the products in the inverse suspension polymerization is investigated. The influences of the kaoline powder, cross-linker, initiator, neutralization degree and the volume ratio of oil to water phase on the water absorbency of the superabsorbent composites are discussed in the paper.

  13. Loading rate effects on the fracture of Ni/Au nano-coated acrylic particles

    Directory of Open Access Journals (Sweden)

    Z. L. Zhang

    2012-03-01

    Full Text Available Mechanical failure of monodisperse Ni/Au coated acrylic particles has been investigated by individual compression tests using nanoindentation-based technique equipped with a flat diamond punch. We have found that both fracture property and morphology of particles depend on the compression loading rate. The breaking strain of the metal coating decreases with increasing loading rate, while the breaking stress increases. Two obvious fracture patterns with cracking in meridian or latitude direction are identified according to the loading rate, and attributed respectively to tension- or bendingdominated deformation of the coating. The findings reported here give a significant guiding to the manufacture design of metal coated polymer particles for Anisotropic Conductive Adhesive (ACA packaging.

  14. Preparation and characteristics of acrylic acid/styrene composite plasma polymerized membranes

    International Nuclear Information System (INIS)

    Plasma polymerization has gained increasing interest for the deposition of functional plasma-polymerized membranes suitable for a wide range of applications on account of its advantageous features. In this work, acrylic acid/styrene composite plasma polymerized membranes were synthesized by plasma polymerization of a mixture of acrylic acid and styrene monomers in a low-frequency after-glow capacitively coupled plasma (CCP) discharge process. The structure and composition of the plasma polymerized membranes were characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). The results showed that the partial pressure ratio between acrylic acid (AA) and styrene (St), applied discharge power and the energy of the extracted particles have considerable effects on the structure and the content of functional groups of the deposited membranes.

  15. Stiffness and strength of composite acrylic bone cements

    Directory of Open Access Journals (Sweden)

    I. Knets

    2007-01-01

    Full Text Available Purpose: Different acrylic bone cements based upon PMMA-MMA system are applicable for implant fixation inbone tissue. The aim of present study is the optimisation of the structure of some new bone acrylic cements madeon the basis of PMMA-ethylmethacrylate-triethyleneglycoldimethacrylate and bone cements having additives (HAand radio pacifier, and the finding of the effect of these modifications on the flexural strength and stiffness.Design/methodology/approach: Different new bone cements on the basis of PMMA-EMA-TEGDMA system(ABC were developed experimentally. The stiffness and strength of the samples of these modified cements weredetermined in the special three point bending equipment.Findings: A comparison of the flexural properties of new PMMA-EMA-TEGDMA cements and commercialavailable PMMA-MMA cement showed that commercial bone cement had larger values of ultimate strengthand modulus of elasticity, but the difference is not very important. As concerns the polymerisation peaktemperature, then there is a significant difference between commercial PMMA-MMA cement (~ 800C andPMMA-EMA-TEGDMA modified cements (50 – 600C. The introduction of 10% and 18% of HA into solidphase does not influence essentially strength and modulus of elasticity of the PMMA-EMA-TEGDMA bonecements. The introduction of radio pacifier BaSO4 into bone cement leads to flexural strength diminishing.Low polymerisation peak temperature and appropriate mechanical properties of bone cements developed allowsregarding new 3-D structure acrylic bone cements as promising biomaterials.Research limitations/implications: It is supposed to carry out animal testing to learn more about reaction ofmodified implanted material on the biological environment.Practical implications: The new materials could be efficiently used as bone cements because they will notdamage surrounding biological tissue during curing.Originality/value: Paper is providing the new information about possibilities to

  16. Polypyrrole-coated styrene-butyl acrylate copolymer composite particles with tunable conductivity

    Institute of Scientific and Technical Information of China (English)

    HUANG Liyan; HOU Wenbo; LIU Zhengping; ZHANG Qingyue

    2005-01-01

    A series of near or monodisperse styrene-butyl acrylate (SBA) copolymer latex particles with different butyl acrylate contents were coated with polypyrrole. The structure of the SBA/PPy composites was characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), diffuse reflectance infrared Fourier transform spectroscopy (DRIFT), X-ray photoelectron spectroscopy (XPS), differential scanning calorimetry (DSC) and standard four-probe method. The core-shell morphology of the SBA/PPy composite particles was confirmed. The result of DSC showed that Tg of the composite is mainly determined by the core component. The effects of the concentration of polypyrrole, the butyl acrylate content in SBA copolymer and the nature of the counter-anion on the electrical conductivity of compression-moulded samples were studied. It was first found that the electrical conductivity of the samples can be tuned by varying the butyl acrylate content in SBA copolymer and the highest conductivity of the core-shell composite was 0.17 S·cm-1.

  17. Influence of load on the dry frictional performance of alkyl acrylate copolymer elastomers coated with diamond-like carbon films

    NARCIS (Netherlands)

    Martinez, D. Martinez; Nohava, Jiri; De Hosson, J. Th. M.

    2015-01-01

    In this work, the influence of applied load on the frictional behavior of alkyl acrylate copolymer elastomers coated with diamond- like carbon films is studied at dry conditions. The performance of two coatings with very different microstructure (patched vs. continuous film) is compared with the unc

  18. A temporary space maintainer using acrylic resin teeth and a composite resin.

    Science.gov (United States)

    Kochavi, D; Stern, N; Grajower, R

    1977-05-01

    A one-session technique for preparing a temporary space maintainer has been described. The technique consists of attaching an acrylic resin pontic to etched surfaces of natural adjacent teeth by means of a composite resin. The main advantages of this technique are elimination of premature tooth preparation, good esthetics, fair strength, low cost, and rapid completion of the restoration without the need of a dental laboratory.

  19. Real-time monitoring of graphene oxide reduction in acrylic printable composite inks

    Science.gov (United States)

    Porro, S.; Giardi, R.; Chiolerio, A.

    2014-06-01

    This work reports the electrical characterization of a water-based graphene oxide/acrylic composite material, which was directly inkjet printed to fabricate dissipative patterns. The graphene oxide filler, which is strongly hydrophilic due to its heavily oxygenated surface and can be readily dispersed in water, was reduced by UV irradiation during photo-curing of the polymeric matrix. The concurrent polymerization of the acrylic matrix and reduction of graphene oxide filler was demonstrated by real-time resistance measurements during UV light irradiation. The presence of graphene filler allowed decreasing the resistance of the pure polymeric matrix by nearly five orders of magnitude. This was explained by the fact that clusters of reduced graphene oxide inside the polymer matrix act as preferential pathways for the mobility of charge carriers, thus leading to an overall decrease of the material's resistance.

  20. Preparation, characterization, and antibacterial activity studies of silver-loaded poly(styrene-co-acrylic acid) nanocomposites.

    Science.gov (United States)

    Song, Cunfeng; Chang, Ying; Cheng, Ling; Xu, Yiting; Chen, Xiaoling; Zhang, Long; Zhong, Lina; Dai, Lizong

    2014-03-01

    A simple method for preparing a new type of stable antibacterial agent was presented. Monodisperse poly(styrene-co-acrylic acid) (PSA) nanospheres, serving as matrices, were synthesized via soap-free emulsion polymerization. Field-emission scanning electron microscopy micrographs indicated that PSA nanospheres have interesting surface microstructures and well-controlled particle size distributions. Silver-loaded poly(styrene-co-acrylic acid) (PSA/Ag-NPs) nanocomposites were prepared in situ through interfacial reduction of silver nitrate with sodium borohydride, and further characterized by transmission electron microscopy and X-ray diffraction. Their effects on antibacterial activity including inhibition zone, minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC), and bactericidal kinetics were evaluated. In the tests, PSA/Ag-NPs nanocomposites showed excellent antibacterial activity against both gram-positive Staphylococcus aureus and gram-negative Escherichia coli. These nanocomposites are considered to have potential application in antibacterial coatings on biomedical devices to reduce nosocomial infection rates. PMID:24433897

  1. Fabrication and Characterization of Gd-DTPA-Loaded Chitosan-Poly(Acrylic Acid) Nanoparticles for Magnetic Resonance Imaging.

    Science.gov (United States)

    Ahmed, Arsalan; Zhang, Chao; Guo, Jian; Hu, Yong; Jiang, Xiqun

    2015-08-01

    Gd-DTPA-loaded chitosan-poly(acrylic acid) nanoparticles (Gd-DTPA@CS-PAA NPs) were formulated based on the reaction system of water-soluble polymer-monomer pairs of acrylic acid in chitosan solution followed by sorption of Gd-DTPA. Morphological investigations revealed the spherical shape of these NPs with about 220 nm particle size. These NPs showed charge reversal characteristic in acidic solution. In vitro and in vivo magnetic characteristics of these NPs were explored to estimate their utilization in targeted enhanced magnetic resonance imaging. Relaxation studies showed that these NPs possessed pH susceptible relaxation properties, which could introduce in vivo-specific distribution of contrast agent. MRI experiment showed that these nanoparticles had better results in contrast enhancement, and the concentration of contrast agent increased in liver and brain with increment in time. Thus, these NPs could maintain in vivo long circulation and high relaxation rate and were suitable agents for magnetic resonance imaging.

  2. Acrylic coatings exhibiting improved hardness, solvent resistance and glossiness by using silica nano-composites

    Science.gov (United States)

    Dashtizadeh, Ahmad; Abdouss, Majid; Mahdavi, Hossein; Khorassani, Manuchehr

    2011-01-01

    To prepare nano-composite emulsion acrylic resins with improved surface hardness and solvent resistance, nano-silica particles were treated with surfactants. The monomers of methyl methacrylate/butylacrylate were co-polymerized on the surface of dispersed silica particles. Several emulsions with different silica contents and copolymer mole fractions were prepared. Finally the emulsions were modified to water-based acrylic coatings and improved properties such as surface hardness, solvent resistance and glossiness were determined. The study of coatings was directed to find the improved resin by optimum surface properties. Size distribution and morphology of latexes were characterized by Fourier transform infrared spectroscopy, dynamic light scattering, transmission electron microscopy and scanning electron microscopy. The glass transition temperature of nano-composites was measured and discussed its relation with silica contents, monomer mole fractions and improved properties of coatings. The optimum pendulum hardness of coatings was on 0.46 methyl methacrylate mole fraction and 120 g silica content. An increase in pendulum hardness of nano-composites with the addition of modified silica was observed. DLS and TEM studies indicate that silica particles were dispersed homogenously through the polymer matrix.

  3. Multi-walled carbon nanotubes/polymer composites in absence and presence of acrylic elastomer (ACM).

    Science.gov (United States)

    Kumar, S; Rath, T; Mahaling, R N; Mukherjee, M; Khatua, B B; Das, C K

    2009-05-01

    Polyetherimide/Multiwall carbon nanotube (MWNTs) nanocomposites containing as-received and modified (COOH-MWNT) carbon nanotubes were prepared through melt process in extruder and then compression molded. Thermal properties of the composites were characterized by thermo-gravimetric analysis (TGA). Field emission scanning electron microscopy (FESEM) images showed that the MWNTs were well dispersed and formed an intimate contact with the polymer matrix without any agglomeration. However the incorporation of modified carbon nanotubes formed fascinating, highly crosslinked, and compact network structure throughout the polymer matrix. This showed the increased adhesion of PEI with modified MWNTs. Scanning electron microscopy (SEM) also showed high degree of dispersion of modified MWNTs along with broken ends. Dynamic mechanical analysis (DMA) results showed a marginal increase in storage modulus (E') and glass transition temperature (T(g)) with the addition of MWNTs. Increase in tensile strength and impact strength of composites confirmed the use the MWNTs as possible reinforcement agent. Both thermal and electrical conductivity of composites increased, but effect is more pronounced on modification due to formation of network of carbon nanotubes. Addition of acrylic elastomer to developed PEI/MWNTs (modified) nanocomposites resulted in the further increase in thermal and electrical properties due to the formation of additional bond between MWNTs and acrylic elastomers at the interface. All the results presented are well corroborated by SEM and FESEM studies. PMID:19452959

  4. Investigation of Regenerated Cellulose/Poly(acrylic acid Composite Films for Potential Wound Healing Applications: A Preliminary Study

    Directory of Open Access Journals (Sweden)

    Manjula Bajpai

    2014-01-01

    Full Text Available Regenerated cellulose/poly(acrylic acid composite films have been synthesized for wound dressing applications. The water absorbency of these films was studied as a function of amount of cross-linker N,N′-methylenebisacrylamide and cellulose contents in the feed mixture. The samples, having different compositions, showed tensile strength and percent elongation in the range of 9.98×105 to 13.40×105 N/m2 and 110 to 265, respectively. The water vapor transmission rate (WVTR for various films was found to be in the range of 2.03 to 7.18 mg/cm2/h. These films were loaded with antibacterial drug miconazole nitrate and their release was studied in the physiological pH at 37°C. The release data was found to fit well the diffusion controlled Higuchi model. Finally the films demonstrated fair antibacterial and antifungal action, thus establishing their strong candidature as wound dressing materials.

  5. Radiation-curing of acrylate composites including carbon fibres: A customized surface modification for improving mechanical performances

    Science.gov (United States)

    Martin, Arnaud; Pietras-Ozga, Dorota; Ponsaud, Philippe; Kowandy, Christelle; Barczak, Mariusz; Defoort, Brigitte; Coqueret, Xavier

    2014-12-01

    The lower transverse mechanical properties of radiation-cured acrylate-based composites reinforced with carbon-fibre with respect to the thermosettable analogues was investigated from the viewpoint of chemical interactions at the interface between the matrix and the carbon material. XPS analysis of representative commercial carbon fibres revealed the presence of a significant amount of chemical functions potentially exerting an adverse effect on the initiation and propagation of the free radical polymerization initiated under high energy radiation. The EB-induced polymerization of n-butyl acrylate as a simple model monomer was conducted in the presence of various aromatic additives exhibiting a strong inhibiting effect, whereas thiols efficiently sensitize the initiation mechanism and undergo transfer reactions. A method based on the surface modification of sized fibres by thiomalic acid is proposed for overcoming the localized inhibition phenomenon and for improving the mechanical properties of the resulting acrylate-based composites.

  6. Synthesis of polyoxometalate-loaded epoxy composites

    Science.gov (United States)

    Anderson, Benjamin J

    2014-10-07

    The synthesis of a polyoxometalate-loaded epoxy uses a one-step cure by applying an external stimulus to release the acid from the polyoxometalate and thereby catalyze the cure reaction of the epoxy resin. Such polyoxometalate-loaded epoxy composites afford the cured epoxy unique properties imparted by the intrinsic properties of the polyoxometalate. For example, polyoxometalate-loaded epoxy composites can be used as corrosion resistant epoxy coatings, for encapsulation of electronics with improved dielectric properties, and for structural applications with improved mechanical properties.

  7. Preparation, characterization, and antibacterial activity studies of silver-loaded poly(styrene-co-acrylic acid) nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Song, Cunfeng [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Chang, Ying; Cheng, Ling; Xu, Yiting [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Chen, Xiaoling, E-mail: tinachen0628@163.com [Department of Endodontics, Xiamen Stomatology Hospital, Teaching Hospital of Fujian Medical University, Xiamen 361003 (China); Zhang, Long; Zhong, Lina [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Dai, Lizong, E-mail: lzdai@xmu.edu.cn [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China)

    2014-03-01

    A simple method for preparing a new type of stable antibacterial agent was presented. Monodisperse poly(styrene-co-acrylic acid) (PSA) nanospheres, serving as matrices, were synthesized via soap-free emulsion polymerization. Field-emission scanning electron microscopy micrographs indicated that PSA nanospheres have interesting surface microstructures and well-controlled particle size distributions. Silver-loaded poly(styrene-co-acrylic acid) (PSA/Ag-NPs) nanocomposites were prepared in situ through interfacial reduction of silver nitrate with sodium borohydride, and further characterized by transmission electron microscopy and X-ray diffraction. Their effects on antibacterial activity including inhibition zone, minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC), and bactericidal kinetics were evaluated. In the tests, PSA/Ag-NPs nanocomposites showed excellent antibacterial activity against both gram-positive Staphylococcus aureus and gram-negative Escherichia coli. These nanocomposites are considered to have potential application in antibacterial coatings on biomedical devices to reduce nosocomial infection rates. - Highlights: • A new type of antibacterial agent (PSA/Ag-NPs nanocomposites) was synthesized. • The antibacterial activity against S. aureus and E. coli was studied. • Inhibition zone, MIC, MBC, and bactericidal kinetics were evaluated. • PSA/Ag-NPs nanocomposites showed excellent antibacterial activity.

  8. Enhanced Dielectric Constant for Efficient Electromagnetic Shielding Based on Carbon-Nanotube-Added Styrene Acrylic Emulsion Based Composite

    OpenAIRE

    Chen Changxin; Zhang Song; Ni Yuwei; Cai Seng; Huang Jie; Li Yong; Li Jiang-Tao

    2010-01-01

    Abstract An efficient electromagnetic shielding composite based on multiwalled carbon nanotubes (MWCNTs)-filled styrene acrylic emulsion-based polymer has been prepared in a water-based system. The MWCNTs were demonstrated to have an effect on the dielectric constants, which effectively enhance electromagnetic shielding efficiency (SE) of the composites. A low conductivity threshold of 0.23 wt% can be obtained. An EMI SE of ~28 dB was achieved for 20 wt% MWCNTs. The AC conductivity (σ ac...

  9. A green approach to prepare silver nanoparticles loaded gum acacia/poly(acrylate) hydrogels.

    Science.gov (United States)

    Bajpai, S K; Kumari, Mamta

    2015-09-01

    In this work, gum acacia (GA)/poly(sodium acrylate) semi-interpenetrating polymer networks (Semi-IPN) have been fabricated via free radical initiated aqueous polymerization of monomer sodium acrylate (SA) in the presence of dissolved Gum acacia (GA), using N,N'-methylenebisacrylamide (MB) as cross-linker and potassium persulphate (KPS) as initiator. The semi-IPNs, synthesized, were characterized by various techniques such as X-ray diffraction (XRD), thermo gravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy. The dynamic water uptake behavior of semi-IPNs was investigated and the data were interpreted by various kinetic models. The equilibrium swelling data were used to evaluate various network parameters. The semi-IPNs were used as template for the in situ preparation of silver nanoparticles using extract of Syzygium aromaticum (clove). The formation of silver nanoparticles was confirmed by surface plasmon resonance (SPR), XRD and transmission electron microscopy (TEM). Finally, the antibacterial activity of GA/poly(SA)/silver nanocomposites was tested against E. coli. PMID:26123815

  10. Comparative Analysis of Electromagnetic Response of PVA/MWCNT and Styrene-Acrylic Copolymer/MWCNT Composites

    Science.gov (United States)

    Plyushch, A. O.; Paddubskaya, A. G.; Kuzhir, P. P.; Maksimenko, S. A.; Ivanova, T.; Merijs-Meri, R.; Bitenieks, J.; Zicans, J.; Suslyaev, V. I.; Pletnev, M. A.

    2016-06-01

    The present paper focuses on electromagnetic response of polymeric composites with different concentrations of multiwall carbon nanotubes in the radio (20 Hz - 1 MHz) and microwave (26-36 GHz) frequency ranges. Widely available polymeric materials, such as PVA latex (polyvinyl acetate) and styrene-acrylic copolymer, were used as a matrix. Analysis of the experimental data demonstrated that in electromagnetic shielding applications one should give preference to the styrene-acrylic copolymer, as far as application of this matrix type allows reducing the percolation threshold in such composites. As a result, it allows reaching the necessary level of shielding at a lower filler concentration, while unique properties of the chosen polymer allow expanding the range of applications for the new materials.

  11. Synthesis and characterization of a sphere-like modified chitosan and acrylate resin composite for organics absorbency

    Science.gov (United States)

    Xin, S. S.; Wang, Y. H.; Li, Q. R.; Zhang, Q.; Wang, X. P.

    2015-07-01

    In this study, the chitosan (deacetylation degree >95%) was modified with vinyltriethoxysilane (A151) and became hydrophobic. The modified chitosan and acrylate resin composite can be synthesized by butyl methacrylate (BMA), butyl acrylate (BA), poly vinyl alcoho(PVA), N,N’-methylene bisacrylamide (MBA), benzoyl peroxide (BPO), and ethyl acetate under microwave irradiation. The optimal synthetic condition was as follows: the molar ratio of BA and BMA was 1.5:1, the dosage of ethyl acetate, PVA, MBA, BPO and modified chitosan were 50 wt.%, 10 wt.%, 1.5 wt.%, 2.0 wt.% and 1.0 wt.% of monomers, respectively. The adsorption capacity of the composite for CHCl3 and CCl4 were approximate to 53 g/g and 44 g/g, respectively. The organics absorbency and regeneration of the samples were also tested, and the samples were characterized by analysis of the scanning electron microscope and simultaneous thermo gravimetric/differential thermal.

  12. Experimental characterization of composites. [load test methods

    Science.gov (United States)

    Bert, C. W.

    1975-01-01

    The experimental characterization for composite materials is generally more complicated than for ordinary homogeneous, isotropic materials because composites behave in a much more complex fashion, due to macroscopic anisotropic effects and lamination effects. Problems concerning the static uniaxial tension test for composite materials are considered along with approaches for conducting static uniaxial compression tests and static uniaxial bending tests. Studies of static shear properties are discussed, taking into account in-plane shear, twisting shear, and thickness shear. Attention is given to static multiaxial loading, systematized experimental programs for the complete characterization of static properties, and dynamic properties.

  13. Biobased composites from thermoplastic polyurethane elastomer and cross-linked acrylated-epoxidized soybean oil

    Science.gov (United States)

    Soybean oil is an important sustainable material. Crosslinked acrylated epoxidized soybean oil (AESO) is brittle without flexibility and the incorporation of thermoplastic polyurethane improves its toughness for industrial applications. The hydrophilic functional groups from both oil and polyurethan...

  14. Preparation and drug-loading properties of Fe{sub 3}O{sub 4}/Poly(styrene-co-acrylic acid) magnetic polymer nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Wensheng [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China); Coordination Chemistry Institute, School of Chemistry and Chemical Engineering and Life Science, Chaohu University, Chaohu 238000 (China); Shen, Yuhua, E-mail: s_yuhua@163.com [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China); Xie, Anjian [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China); Zhang, Weiqiang [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China); Coordination Chemistry Institute, School of Chemistry and Chemical Engineering and Life Science, Chaohu University, Chaohu 238000 (China)

    2013-11-15

    Fe{sub 3}O{sub 4}/poly(styrene-co-acrylic acid) magnetic polymer nanocomposites were synthesized by the dispersion polymerization method using styrene as hard monomer, acrylic acid as functional monomer, Fe{sub 3}O{sub 4} nanoparticles modified with oleic acid as core, and poly(styrene-co-acrylic acid) as shell. Drug-loading properties of magnetic polymer nanocomposites with curcumin as a model drug were also studied. The results indicated that magnetic polymer nanocomposites with monodisperse were obtained, the particle size distribution was 50–120 nm, and the average size was about 100 nm. The contents of poly(styrene-co-acrylic acid) and Fe{sub 3}O{sub 4} nanoparticles in magnetic polymer nanocomposites were 74% and 24.7%, respectively. The drug-loading capacity and entrapment efficiency were 2.5% and 44.4%, respectively. The saturation magnetization of magnetic polymer nanocomposites at 300 K was 20.2 emu/g without coercivity and remanence. The as-prepared magnetic polymer nanocomposites have not only lots of functional carboxyl groups but also stronger magnetic response, which might have potential applications in drug carrier and targeted drug release.

  15. Thick composite structures under a load pinch

    OpenAIRE

    Karama, Moussa

    2015-01-01

    Thick composites are increasingly used in the design of mechanical structures. Combined with low weight, they are generally resistant structures, which can support importante loads. In addition, depending on the number and nature of the materials used, it is possible to adapt properties for specific applications (damping structures).This work proposes the establishment of a new theoretical model of multilayer beam. The model, which is simple and easy handling, is intended for the subsequent e...

  16. A drug-loaded gel based on polyelectrolyte complexes of poly (acrylic acid) with poly (vinylpyrrolidone) and chitosan

    International Nuclear Information System (INIS)

    A drug-loaded gel (CSPP) based on ionic crosslinked chitosan (CS) and polyelectrolyte complexes of poly (acrylic acid) (PAA) with poly (vinylpyrrolidone) (PVP) was prepared by dropping CS solution containing suitable amount of PVP into PAA and trisodium citrate co-existing gelling solution. The surface and cross-section morphology of the gel was observed using scanning electron microscopy, and the observation showed that the CSPP gel had more compact structure than CS gel. In vitro release profiles of model drug from the CSPP gel, which was prepared under different conditions, were investigated in simulative gastric fluid (pH 1.8) using an UV/vis spectrophotometer. The results showed that the rapid release of the model was restrained due to the complex of PVP and PAA, and the CSPP gel could serve as a suitable candidate in drug delivery system such as the site-specific controlled release of the drug in stomach. In addition, the release mechanism of drug was analyzed by fitting the amount of drug released into Peppa's potential equation.

  17. Synthesis of linear low-density polyethylene-g-poly (acrylic acid)-co-starch/organo-montmorillonite hydrogel composite as an adsorbent for removal of Pb(Ⅱ) from aqueous solutions

    Institute of Scientific and Technical Information of China (English)

    Maryam Irani; Hanafi Ismail; Zulkifli Ahmad; Maohong Fan

    2015-01-01

    The purpose of this work is to remove Pb(Ⅱ) from the aqueous solution using a type of hydrogel composite.A hydrogel composite consisting of waste linear low density polyethylene,acrylic acid,starch,and organo-montmorillonite was prepared through emulsion polymerization method.Fourier transform infrared spectroscopy (FTIR),Solid carbon nuclear magnetic resonance spectroscopy (CNMR)),silicon-29 nuclear magnetic resonance spectroscopy (Si NMR)),and X-ray diffraction spectroscope ((XRD) were applied to characterize the hydrogel composite.The hydrogel composite was then employed as an adsorbent for the removal of Pb(Ⅱ) from the aqueous solution.The Pb(Ⅱ)-loaded hydrogel composite was characterized using Fourier transform infrared spectroscopy (FTIR)),scanning electron microscopy (SEM)),and X-ray photoelectron spectroscopy ((XPS)).From XPS results,it was found that the carboxyl and hydroxyl groups of the hydrogel composite participated in the removal of Pb(Ⅱ).Kinetic studies indicated that the adsorption of Pb(Ⅱ)followed the pseudo-second-order equation.It was also found that the Langmuir model described the adsorption isotherm better than the Freundlich isotherm.The maximum removal capacity of the hydrogel composite for Pb(Ⅱ) ions was 430 mg/g.Thus,the waste linear low-density polyethylene-g-poly (acrylic acid)-co-starch/organo-montmorillonite hydrogel composite could be a promising Pb(Ⅱ) adsorbent.

  18. Enhanced dielectric constant for efficient electromagnetic shielding based on carbon-nanotube-added styrene acrylic emulsion based composite.

    Science.gov (United States)

    Li, Yong; Chen, Changxin; Li, Jiang-Tao; Zhang, Song; Ni, Yuwei; Cai, Seng; Huang, Jie

    2010-01-01

    An efficient electromagnetic shielding composite based on multiwalled carbon nanotubes (MWCNTs)-filled styrene acrylic emulsion-based polymer has been prepared in a water-based system. The MWCNTs were demonstrated to have an effect on the dielectric constants, which effectively enhance electromagnetic shielding efficiency (SE) of the composites. A low conductivity threshold of 0.23 wt% can be obtained. An EMI SE of ~28 dB was achieved for 20 wt% MWCNTs. The AC conductivity (σac) of the composites, deduced from imaginary permittivity, was used to estimate the SE of the composites in X band (8.2-12.4 GHz), showing a good agreement with the measured results. PMID:20596498

  19. Enhanced Dielectric Constant for Efficient Electromagnetic Shielding Based on Carbon-Nanotube-Added Styrene Acrylic Emulsion Based Composite

    Directory of Open Access Journals (Sweden)

    Chen Changxin

    2010-01-01

    Full Text Available Abstract An efficient electromagnetic shielding composite based on multiwalled carbon nanotubes (MWCNTs-filled styrene acrylic emulsion-based polymer has been prepared in a water-based system. The MWCNTs were demonstrated to have an effect on the dielectric constants, which effectively enhance electromagnetic shielding efficiency (SE of the composites. A low conductivity threshold of 0.23 wt% can be obtained. An EMI SE of ~28 dB was achieved for 20 wt% MWCNTs. The AC conductivity (σ ac of the composites, deduced from imaginary permittivity, was used to estimate the SE of the composites in X band (8.2–12.4 GHz, showing a good agreement with the measured results.

  20. Preparation of pH-responsive ceramic composite membranes by grafting acrylic acid onto a-alumina membranes

    Institute of Scientific and Technical Information of China (English)

    YANG LianLi; ZHAO YiJiang; ZHOU ShouYong; LI MeiSheng; CHEN Yan; XING WeiHong

    2009-01-01

    A pH-responsive ceramic composite membrane was prepared by chemical graft polymerization of acrylic acid (AA) onto the KH-570 modified a-alumina membrane. The influence of monomer concentration on the gating characteristics of the pH-responsive membrane was investigated. The FT-IR spectrum, contact angle and water filtration rate of the membrane were measured. The monomer concentration was found to have a remarkable effect on the pH-response coefficient and the water filtration rate. In addition, the grafted membrane exhibited fast and reversible response to the pH change in the external solution.

  1. Behavior of Composite Columns Subjected to Lateral Cyclic Loading

    OpenAIRE

    AL-Bdoor, Mazen

    2013-01-01

    ABSTRACT: Nonlinear 3-D finite element models were developed to investigate the cumulative damage of composite columns subjected to cyclic loading by comparing the effects of different levels of axial loads on the cyclic capacity of steel, reinforced concrete, and composite beam-columns. The beam-column specimens were modeled as fixed cantilever beam-columns with an axial load level of 10%, 15%, and 20% of their axial load capacity as well as cyclic loading similar to that suggested ...

  2. The effect of acrylic latex-based polymer on cow blood adhesive resins for wood composites

    Science.gov (United States)

    Yan, J.; Lin, H. L.; Feng, G. Z.; Gunasekaran, S.

    2016-07-01

    In this paper, alkali-modified cow blood adhesive (BA) and blood adhesive/acrylic latex-based adhesive (BA/ALB) were prepared. The physicochemical and adhesion properties of cow blood adhesive such as UV- visible spectra, particle size, viscosity were evaluated; share strength, water resistance were tested. UV- visible spectra indicates that the strong bonding strength of BA/ALB appeared after incorporating; the particle size of adhesive decreased with the increase of ALB concentration, by mixing ALB and BA, hydrophilic polymer tends locate or extand the protein chains and provide stability of the particles; viscosity decreased as shear rate increased in concordance with a pseudoplastic behavior; both at dry and soak conditions, BA and ALB/BA show significant difference changes when mass fraction of ALB in blend adhesive was over 30% (p cow blood and acrylic latex-based adhesive significantly increased the strength and water resistance of the resulting wood.

  3. Synthesis and urea-loading of an eco-friendly superabsorbent composite based on mulberry branches

    Directory of Open Access Journals (Sweden)

    Xiying Liang

    2013-02-01

    Full Text Available Mulberry branch, consisting of bark and stalk, was used as raw skeleton material without any chemical pre-treatment to synthesize an eco-friendly mulberry branch-g-poly(acrylic acid-co-acrylamide (PMB/P(AA-co-AM superabsorbent composite. The synthesis conditions and properties of the PMB/P(AA-co-AM superabsorbent composite were investigated. The results showed that under the optimal synthesis conditions, the water absorbency of the prepared PMB/P(AA-co-AM reached 570.5 g/g in deionized water, 288.0 g/g in tap water, and 70.0 g/g in 0.9 wt% aqueous NaCl solution. The PMB/P(AA-co-AM composite also exhibited excellent water retention capacity as well as a rapid water absorbency rate. The urea loading percentage of the PMB/P(AA-co-AM composite was controlled by the concentration of aqueous urea solution. The release of urea from the loaded PMB/P(AA-co-AM composite in deionized water initially exhibited a high rate of release for 60 min, followed by a rapid decline. Meanwhile, the PMB/P(AA-co-AM superabsorbent composite with larger particle size achieved a better sustained release of urea.

  4. Influence of Methacrylic-Acrylic Copolymer Composition on Plasticiser-free Optode Films for pH Sensors

    Directory of Open Access Journals (Sweden)

    Musa Ahmad

    2003-03-01

    Full Text Available In this work we have examined the use of plasticiser-free polymeric films incorporating a proton selective chromoionophore for optical pH sensor. Four types of methacrylic-acrylic copolymers containing different compositions of n-butyl acrylate (nBA and methyl methacrylate (MMA were synthesised for use as optical sensor films. The copolymers were mixed with appropriate amounts of chromoionophore (ETH5294 and a lipophilic salt before spin coated on glass slides to form films for the evaluation of pH response using spectrophotometry. Co-polymer films with high nBA content gave good response and the response time depended on the film thickness. A preliminary evaluation of the optical films of high nBA content with pHs from 2 - 14 showed distinguishable responses from pH 5 - 9. However, the adhesion of the pH sensitive film was good for copolymers with higher content of MMA but not for films with high nBA.

  5. Incorporation of antimicrobial macromolecules in acrylic denture base resins: a research composition and update.

    Science.gov (United States)

    Sivakumar, Indumathi; Arunachalam, Kuthalingam Subbiah; Sajjan, Suresh; Ramaraju, Alluri Venkata; Rao, Bheemalingeshwara; Kamaraj, Bindu

    2014-06-01

    Contemporary research in acrylic denture base materials focuses on the development of a novel poly(methyl methacrylate) (PMMA) resin with antimicrobial properties. Although PMMA resin has fulfilled all the requirements of an ideal denture base material, its susceptibility to microbial colonization in the oral environment is a formidable concern to clinicians. Many mechanisms including the absence of ionic charge in the methyl methacrylate resins, hydrophobic interactions, electrostatic interactions, and mechanical attachment have been found to contribute to the formation of biofilm. The present article outlines the basic categories of potential antimicrobial polymer (polymeric biocides) formulations (modified PMMA resins) and considers their applicability, biological status, and usage potential over the coming years.

  6. Poly(acrylic acid) Bridged Gadolinium Metal-Organic Framework-Gold Nanoparticle Composites as Contrast Agents for Computed Tomography and Magnetic Resonance Bimodal Imaging.

    Science.gov (United States)

    Tian, Chixia; Zhu, Liping; Lin, Feng; Boyes, Stephen G

    2015-08-19

    Imaging contrast agents for magnetic resonance imaging (MRI) and computed tomography (CT) have received significant attention in the development of techniques for early stage cancer diagnosis. Gadolinium (Gd)(III), which has seven unpaired electrons and a large magnetic moment, can dramatically influence the water proton relaxation and hence exhibits excellent MRI contrast. On the other hand, gold (Au), which has a high atomic number and high X-ray attenuation coefficient, is an ideal contrast agent candidate for X-ray-based CT imaging. Gd metal-organic framework (MOF) nanoparticles with tunable size, high Gd(III) loading and multivalency can potentially overcome the limitations of clinically utilized Gd chelate contrast agents. In this work, we report for the first time the integration of GdMOF nanoparticles with gold nanoparticles (AuNPs) for the preparation of a MRI/CT bimodal imaging agent. Highly stable hybrid GdMOF/AuNPs composites have been prepared by using poly(acrylic acid) as a bridge between the GdMOF nanoparticles and AuNPs. The hybrid nanocomposites were then evaluated in MRI and CT imaging. The results revealed high longitudinal relaxivity in MRI and excellent CT imaging performance. Therefore, these GdMOF/AuNPs hybrid nanocomposites potentially provide a new platform for the development of multimodal imaging probes.

  7. Predicting the Structural Performance of Composite Structures Under Cyclic Loading

    OpenAIRE

    Kassapoglou, C.

    2012-01-01

    The increased use of advanced composite materials on primary aircraft structure has brought back to the forefront the question of how such structures perform under repeated loading. In particular, when damage or other stress risers are present, tests have shown that the load to cause failure after a given number of cycles is a decreasing function of these cycles. This is a result of damage that was already present in the structure or was created during cyclic loading. In composites, multiple ...

  8. Polymer composite material structures comprising carbon based conductive loads

    OpenAIRE

    Jérôme, Robert; Pagnoulle, Christophe; Detrembleur, Christophe; Thomassin, Jean-Michel; Huynen, Isabelle; Bailly, Christian; Bednarz, Lucasz; Daussin, Raphaël; Saib, Aimad

    2006-01-01

    The present invention provides a polymer composite material structure comprising at least one layer of a foamed polymer composite material comprising a foamed polymer matrix and 0.1 to 6 wt% carbon based conductive loads, such as e.g. carbon nanotubes, dispersed in the foamed polymer matrix. The polymer composite material structure according to embodiments of the present invention shows good shielding and absorbing properties notwithstanding the low amount of carbon based conductive loads. Th...

  9. Precise 3D printing of micro/nanostructures using highly conductive carbon nanotube-thiol-acrylate composites

    Science.gov (United States)

    Liu, Y.; Xiong, W.; Jiang, L. J.; Zhou, Y. S.; Lu, Y. F.

    2016-04-01

    Two-photon polymerization (TPP) is of increasing interest due to its unique combination of truly three-dimensional (3D) fabrication capability and ultrahigh spatial resolution of ~40 nm. However, the stringent requirements of non-linear resins seriously limit the material functionality of 3D printing via TPP. Precise fabrication of 3D micro/nanostructures with multi-functionalities such as high electrical conductivity and mechanical strength is still a long-standing challenge. In this work, TPP fabrication of arbitrary 3D micro/nanostructures using multi-walled carbon nanotube (MWNT)-thiolacrylate (MTA) composite resins has been developed. Up to 0.2 wt% MWNTs have been incorporated into thiol-acrylate resins to form highly stable and uniform composite photoresists without obvious degradation for one week at room temperature. Various functional 3D micro/nanostructures including woodpiles, micro-coils, spiral-like photonic crystals, suspended micro-bridges, micro-gears and complex micro-cars have been successfully fabricated. The MTA composite resin offers significant enhancements in electrical conductivity and mechanical strength, and on the same time, preserving high optical transmittance and flexibility. Tightly controlled alignment of MWNTs and the strong anisotropy effect were confirmed. Microelectronic devices including capacitors and resistors made of the MTA composite polymer were demonstrated. The 3D micro/nanofabrication using the MTA composite resins enables the precise 3D printing of micro/nanostructures of high electrical conductivity and mechanical strength, which is expected to lead a wide range of device applications, including micro/nano-electromechanical systems (MEMS/NEMS), integrated photonics and 3D electronics.

  10. STUDY OF COMPOSITE MEMBRANE OF CELLULOSE ACETATE OR POLYVINYL ALCOHOL BLENDED WITH METHYLMETHACRYLATE-ACRYLIC ACID COPOLYMER FOR PERVAPORATION SEPARATION

    Institute of Scientific and Technical Information of China (English)

    Huan-lin Chen; Jun Tan; Mo-e Liu; Chang-luo Zhu

    1999-01-01

    In this paper, methylmethacrylate-acrylic acid MMA-AA hydrophilic and hydrophobic copolymers were prepared by copolymerization for preparing membrane materials. The composite membrane of cellulose acetate (CA) blended with MMA-AA hydrophobic copolymer was used for the separation of methanol from pentane-methanol mixture. When the methanol concentration was only 1 wt%, the permeate flux still maintained at 350 g/m2h and separation factor was as big as 800. The composite membrane of PVA (polyvinyl alcohol) blended with MMA-AA hydrophilic copolymer was used for the separation of ethanolwater mixture. The permeate flux was increased to 975 g/m2h at 74℃ and the separation factor reached 3000at 25℃. The PVA/MMA-AA blended membrane surface modified by ammonia plasma was also investigated for separating ethanol-water mixture. Both permeate flux and separation factor of the membrane was improved. However, there was no obvious difference of plasma treatment time in the interval of 20~40 min.

  11. Electroactive behavior assessment of poly(acrylic acid)-graphene oxide composite hydrogel in the detection of cadmium

    NARCIS (Netherlands)

    Bejarano-Jimenez, A.; Escobar-Barrios, V.A.; Kleijn, J.M.; Oritz-Ledon, C.A.; Chazaro-Ruiz, L.F.

    2014-01-01

    Super absorbent polymers of acrylic acid-graphene oxide (PAA-GO) were synthesized with different percentage of chemical neutralization (0, 10, and 20%) of the acrylic acid monomer before its polymerization. The influence of their swelling and adsorption/desorption capacity of cadmium ions in aqueous

  12. Temporary space maintainers retained with composite resin. Part II: Fracture load in vitro.

    Science.gov (United States)

    Grajower, R; Stern, N; Zamir, S T; Kohavi, D

    1981-01-01

    The average fracture load during occlusal loading of pontics which were bonded to natural abutment teeth in vitro was found to be 56.1, 57.5 and 74.2 kg for natural, acrylic resin, and Restodent pontics, respectively. Coating the roots of the abutment teeth with a thin layer of silicone rubber before embedding them in stone slightly reduced the strength of the fixed partial dentures. Thermocycling the specimens with coated roots caused a considerable decrease in strength to fracture loads of 33.0, 17.9, and 37.3 kg for natural, acrylic resin, and Restodent pontics, respectively. Fracture of the enamel of natural tooth pontics was observed in a few specimens. The superior strength of the fixed partial dentures with natural tooth and Restodent pontics would indicate that these pontics are superior for clinical trials rather than acrylic resin pontics.

  13. Delamination Growth in Composites under Fatigue Loading

    NARCIS (Netherlands)

    Khan, R.

    2013-01-01

    Fiber reinforced composites are attractive for aerospace applications due to high specific strength and stiffness. Their use has been gradually increased to 50% by weight of the aircraft over past decades. As a consequence, modern aircraft utilize composites in the primary structures like wing skin

  14. Behavior of slender steel concrete composite columns in eccentric loading

    Institute of Scientific and Technical Information of China (English)

    ZHAO Gen-tian; ZHANG Meng-xi; LI Yong-he

    2009-01-01

    Ten slender steel reinforced cencrete (SRC) composite columns are tested under eccentric loading conditions.Effects of concrete strength, slenderness of columns and eccentricity of the axial load are studied. The load-carrying capacity is reduced with increased slenderness ratio and eccentricity. Concrete strength has no obvious influence on eccentrically loaded columns. Then, a nonlinear numerical method of pin-ended slender columns is also presented. This method is applicable for determining the material failure load or buckling failure load of a slender steel reinforced concrete composite column. In this method both material and geometric nonlinearities are taken into account. The results of numerical analysis accord well with the test results. The test results are also compared with the results predicted by ACI318-05 and the China Specifications.

  15. Preparation of mesoporous poly (acrylic acid)/SiO2 composite nanofiber membranes having adsorption capacity for indigo carmine dye

    Science.gov (United States)

    Xu, Ran; Jia, Min; Li, Fengting; Wang, Hongtao; Zhang, Bingru; Qiao, Junlian

    2012-03-01

    Mesoporous poly (acrylic acid)/SiO2 (PAA/SiO2) composite nanofiber membranes functionalized with mercapto groups were fabricated by a sol-gel electrospinning method, and their adsorption capacity for indigo carmine was investigated. The membranes were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, x-ray powder diffraction (XRD), and nitrogen adsorption-desorption measurement. SEM and TEM observation results showed that the PAA/SiO2 fibers had diameters between 400-800 nm and mesopores with an average pore size of 3.88 nm. The specific surface area of the mesoporous nanofiber membranes was 514.89 m2/g. The characteristic peaks for mercapto group vibration in FTIR and Raman spectra demonstrated that the mercapto groups have been incorporated into the silica skeleton. The adsorption isotherm data of indigo carmine on the membranes fit well with Redlich-Peterson model, and the maximum adsorption capacity calculated was 523.11 mg/g. It was found that the removal rate of indigo carmine by the membranes reached a maximum of 98% in 90 min and the adsorption kinetics followed a pseudo-second-order model. The high adsorption capacity of PAA/SiO2 nanofiber membrane makes it a promising adsorbent for indigo carmine removal from the wastewater.

  16. Culture-Loaded Expressions in Korean EFL Students' Compositions.

    Science.gov (United States)

    Choe, Yongjae Paul

    2001-01-01

    Discusses the inevitability of native culture-loaded expressions in Korean English-as-a-Foreign-Language students' compositions. Cultures, both native and target play a major role in forming ideas in any communicative situation. Thus, Korean EFL students' compositions all reveal without exception the traits of Korean culture. (Author/VWL)

  17. Macro-residual strains due to cyclic loading of composites

    CERN Document Server

    Hashin, Z

    1999-01-01

    Macro-residual strains produced by load cycles on elastic-brittle composites are analytically expressed in terms of the effective thermal expansion coefficients of the composite as affected by the damage states developing during the $9 cycling. Limiting values of residual strain are evaluated for unidirectional fiber composites and cross-ply laminates. Frictional losses due to internal sliding are not considered. (17 refs).

  18. Polymer composite material structures comprising carbon based conductive loads

    OpenAIRE

    Jérôme, Robert; Pagnoulle, Christophe; Detrembleur, Christophe; Thomassin, Jean-Michel; Huynen, Isabelle; Bailly, Christian; Bednarz, Luikasz; Daussin, Raphaël; Saib, Aimad; Baudouin, Anne-Christine; Laloyaux, Xavier

    2007-01-01

    The present invention provides a polymer composite material structure comprising at least one layer of a foamed polymer composite material comprising a foamed polymer matrix and 0.1 wt % to 6 wt % carbon based conductive loads, such as e.g. carbon nanotubes, dispersed in the foamed polymer matrix. The polymer composite material structure according to embodiments of the present invention shows good shielding and absorbing properties notwithstanding the low amount of carbon based conductive loa...

  19. Impact Loading of Composite and Sandwich Structures

    OpenAIRE

    Kazemahvazi, Sohrab

    2010-01-01

    Low weight is one of the most important factors in the design process of high speed naval ships, road vehicles and aircrafts. Lower structural weight enables the possibility of down-sizing the propulsion system and thus decrease manufacturing and operating costs as well as reducing the environmental impact. Two efficient ways of reducing the structural weight of a structure is by using high performance composite materials and by using geometrically efficient structures such as the sandwich co...

  20. EFFECT OF COMPOSITION AND PROCESSING CONDITION ON MICROSTRUCTURAL PROPERTIES AND DURABILITY OF FLUOROPOLYMER/ACRYLIC BLENDS

    Institute of Scientific and Technical Information of China (English)

    Li-Piin Sung; Xiaohong Gu; Derek L. Ho; Forrest. A. Landis; Diep Nguyenc

    2009-01-01

    Fluoropolymer blends have been widely used as binders for exterior coatings because of their excellent resistance to ultra-violet (UV) radiation as well as to many corrosive chemical agents.It is known that the fluorinated component usually has a lower glass transition temperature and easily crystallizes in the final structure depending upon the blend composition and sample annealing condition.We investigated the effect of blend composition and annealing process (slow and fast cooling) on the surface morphology and microstructure a poly(vinylidene fluoride)/poly(methyl methacrylate)(PVDF/PMMA) blend before and after UV exposure.Surface and subsurface microstructures were studied by atomic force microscopy (AFM) and laser scanning confocal microscopy (LSCM).Bulk microstructure of PVDF-coatings before and after UV exposure were characterized using small angle neutron and light scattering.Higher PVDF content and a slow cooling process result in larger spherulite crystallite structure and rougher surface morphology.Significant ordering in the spherulite crystallite structure has been observed on the surface and the bulk films after UV exposure.

  1. Effect of chemical composition on corneal tissue response to photopolymerized materials comprising 2-hydroxyethyl methacrylate and acrylic acid

    Energy Technology Data Exchange (ETDEWEB)

    Lai, Jui-Yang, E-mail: jylai@mail.cgu.edu.tw

    2014-01-01

    The purpose of this work was to investigate the relationship between the feed composition of 2-hydroxyethyl methacrylate (HEMA)/acrylic acid (AAc) and hydrogel material compatibility towards ocular anterior segment tissues, particularly the corneal endothelium. The monomer solutions of HEMA and AAc were mixed at varying volume ratios of 92:0, 87:5, 82:10, 77:15, and 72:20, and were subjected to UV irradiation. Then, the 7-mm-diameter membrane implants made from photopolymerized materials were placed into the ocular anterior chamber for 4 days and assessed by biomicroscopic examinations, corneal thickness measurements, and quantitative real-time reverse transcription polymerase chain reaction analyses. The poly(HEMA-co-AAc) implants prepared from the solution mixture containing 0–10 vol.% AAc displayed good biocompatibility. However, with increasing volume ratio of AAc and HEMA from 15:77 to 20:72, the enhanced inflammatory response, decreased endothelial cell density, and increased ocular score and corneal thickness were observed, probably due to the influence of surface charge of copolymer membranes. On the other hand, the ionic pump function of corneal endothelium exposed to photopolymerized membranes was examined by analyzing the Na{sup +},K{sup +}-ATPase alpha 1 subunit (ATP1A1) expression level. The presence of the implants having higher amount of AAc incorporated in the copolymers (i.e., 15.1 to 24.7 μmol) and zeta potential (i.e., -38.6 to − 56.5 mV) may lead to abnormal transmembrane transport. It is concluded that the chemical composition of HEMA/AAc has an important influence on the corneal tissue responses to polymeric biomaterials. - Highlights: • We examine the corneal tissue responses to photopolymerized biomaterials. • Carboxyl groups in copolymers increased with increasing volume ratio of AAc/HEMA. • 15–20 vol.% AAc raised ocular score and caused corneal endothelial loss and edema. • High anionic charge density stimulated inflammation

  2. Effect of chemical composition on corneal cellular response to photopolymerized materials comprising 2-hydroxyethyl methacrylate and acrylic acid

    Energy Technology Data Exchange (ETDEWEB)

    Lai, Jui-Yang, E-mail: jylai@mail.cgu.edu.tw

    2013-10-15

    Characterization of corneal cellular response to hydrogel materials is an important issue in ophthalmic applications. In this study, we aimed to investigate the relationship between the feed composition of 2-hydroxyethyl methacrylate (HEMA)/acrylic acid (AAc) and material compatibility towards corneal stromal and endothelial cells. The monomer solutions of HEMA and AAc were mixed at varying volume ratios of 92:0, 87:5, 82:10, 77:15, and 72:20, and were subjected to UV irradiation. Results of electrokinetic measurements showed that an increase in absolute zeta potential of photopolymerized membranes is observed with increasing the volume ratios of AAc/HEMA. Following 4 days of incubation with various hydrogels, the primary rabbit corneal stromal and endothelial cell cultures were examined for viability, proliferation, and pro-inflammatory gene expression. The samples prepared from the solution mixture containing 0–10 vol.% AAc displayed good cytocompatibility. However, with increasing volume ratio of AAc and HEMA from 15:77 to 20:72, the decreased viability, inhibited proliferation, and stimulated inflammation were noted in both cell types, probably due to the stronger charge–charge interactions. On the other hand, the ionic pump function of corneal endothelial cells exposed to photopolymerized membranes was examined by analyzing the Na{sup +},K{sup +}-ATPase alpha 1 subunit (ATP1A1) expression level. The presence of material samples having higher anionic charge density (i.e., zeta potential of − 38 to − 56 mV) may lead to abnormal transmembrane transport. It is concluded that the chemical composition of HEMA/AAc has an important influence on the corneal stromal and endothelial cell responses to polymeric biomaterials. - Highlights: • We examine the corneal cellular responses to photopolymerized biomaterials. • Charge density of membranes was increased with increasing volume ratio of AAc/HEMA. • 15–20 vol.% AAc decreased viability and proliferation

  3. Tetracycline Loaded Collagen/Hydroxyapatite Composite Materials for Biomedical Applications

    Directory of Open Access Journals (Sweden)

    Laura Cristina Rusu

    2015-01-01

    Full Text Available The paper describes the preparation, characterisation, and testing of tetracycline loaded collagen-carboxymethylcellulose/hydroxyapatite ternary composite materials. The synthesis of this drug delivery system consists in two steps: the first step is the mineralization of collagen-carboxymethylcellulose gel while the second step corresponds to the loading of the ternary composite material with tetracycline. The obtained DDS is characterised by physicochemical, morphological, and release behaviour by using FTIR spectroscopy and microscopy, scanning electron microscopy, and UV-VIS spectroscopy. Based on the release study, it can be assumed that tetracycline is released in a prolonged way, assuring at least 6 days of antiseptic properties.

  4. Optimum design of laminated composite under axial compressive load

    Indian Academy of Sciences (India)

    N G R Iyengar; Nilesh Vyas

    2011-02-01

    In the present study optimal design of composite laminates, with and without rectangular cut-out, is carried out for maximizing the buckling load. Optimization study is carried out for obtaining the maximum buckling load with design variables as ply thickness, cut-out size and orientation of cut-out with respect to laminate. Buckling load is evaluated using a ‘simple higher order shear deformation theory’ based on four unknown displacements $u,v,w_b$ and $w_s$. A C1 continuous shear flexible finite element based on HSDT model is developed using Hermite cubic polynomial. It is observed that for thick anti-symmetric laminates, the non-dimensional buckling load decreases with increase in aspect ratio and increase in fibre orientation angle. There is a decrease in the non-dimensional buckling load of symmetric laminate in the presence of cut-out.

  5. Lead titanate/cyclic carbonate dependence on ionic conductivity of ferro/acrylate blend polymer composites

    Science.gov (United States)

    Jayaraman, R.; Vickraman, P.; Subramanian, N. M. V.; Justin, A. Simon

    2016-05-01

    Impedance, XRD, DSC and FTIR studies had been carried out for PVdF-co-HFP/LIBETI based system for three plasticizer (EC/DMC) - filler (PbTiO3) weight ratios. The enhanced conductivity 4.18 × 10-5 Scm-1 was noted for 57.5 wt% -7.5 wt% plasticizer - filler. while blending PEMA to PVdF-co-HFP respectively 7.5: 22.5 wt % (3/7), 15 wt%: 15 wt % (5/5) and 22.5wt %: 7.5 wt % (7/3), the improved conductivity was noted for 3/7 ratio 1.22 × 10-5 S cm-1 and its temperature dependence abide Arrhenius behavior. The intensity of peaks in XRD diffractogram registered dominance of lead titanate, from 2θ = 10° to 80° and absence of VdF crystallites (α+β phase) was noted. In DSC studies, the presence of the exotherm events, filler effect was distinctively seen exhibiting recrystallization of VdF crystallites. In blending PEMA, however, no trace of exotherms was found suggestive of PEMA better inhibiting recrystallization. FTIR study confirmed molecular interactions of various constituents in the vibrational band 500 - 1000 cm-1 both in pristine PVdF-co-HFP and PEMA blended composites with reference to C-F stretching, C-H stretching and C=O carbonyl bands.

  6. Study on Crosslinkable Urethane/Styrene-acrylic Polymer Composite Emulsion%交联型聚氨酯/苯丙树脂复合乳液的研究

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The Crosslinkable polyurethane/styrene-acrylic polymer composite emulsion was obtained by mixing the styrene-acrylic polymer emulsion incorporating DAAM with the polyurethane dispersion con taining hydrazine group. The influence of the amount of DAAM on styrene-acrylic polymer emulsion was studied. The crosslinking reaction between keto group and hydrazine group was proved by FTIR and TEM (transimission electron microscope) technology. Studies on the film properties show that water-resistance, solvent-resistance, tensile strength and elongation at break of the emulsion film were all improved due to the crosslinking reaction.%将双丙酮丙烯酰胺(DAAM)参与共聚的苯丙乳液与含有肼基的聚氨酯水分散体混合后,得到了交联型聚氨酯/苯丙树脂复合乳液。研究了DAAM的用量对苯丙乳液的影响。用傅里叶红外光谱和透射电镜证实了酮羰基与肼基之间发生了交联反应。对乳液膜性能的研究结果表明,交联反应提高了乳液膜的耐水性、耐溶剂性、断裂强度、断裂伸长率。

  7. Preparation and characterization of electrically conductive composites of poly(vinyl alcohol–g–poly(acrylic acid hydrogels impregnated with polyaniline (PANI

    Directory of Open Access Journals (Sweden)

    2008-01-01

    Full Text Available Novel electrically conducting composite materials consisting of poly(aniline (PANI nanoparticles dispersed in a poly(vinyl alcohol (PVA-g-poly(acrylic acid (PAA hydrogels were prepared within the polymer matrix by in situ polymerization of aniline. The conversion yield of aniline into PANI particles was determined gravimetrically while structural confirmation of the synthesized polymer was sought by Fourier Transform Infrared (FTIR, UV-visible analysis and X-ray diffraction (XRD technique. Morphology and dimension of PANI particles embedded into the colored optically semi-transparent hydrogels were evaluated by Scanning Electron Microscopy (SEM analysis. Electrical conductivity of composite hydrogels of different composition was determined by LCR meter while electroactive behavior of composite hydrogels swollen in electrolyte solution was investigated by Effective Bend Angle (EBA measurements.

  8. Hybrid S2/Carbon Epoxy Composite Armours Under Blast Loads

    Science.gov (United States)

    Dolce, F.; Meo, Michele; Wright, A.; French, M.; Bernabei, M.

    2012-06-01

    Civil and military structures, such as helicopters, aircrafts, naval ships, tanks or buildings are susceptible to blast loads as terroristic attacks increases, therefore there is the need to design blast resistant structures. During an explosion the peak pressure produced by shock wave is much greater than the static collapse pressure. Metallic structures usually undergo large plastic deformations absorbing blast energy before reaching equilibrium. Due to their high specific properties, fibre-reinforced polymers are being considered for energy absorption applications in blast resistant armours. A deep insight into the relationship between explosion loads, composite architecture and deformation/fracture behaviour will offer the possibility to design structures with significantly enhanced energy absorption and blast resistance performance. This study presents the results of a numerical investigation aimed at understanding the performance of a hybrid composite (glass/carbon fibre) plate subjected to blast loads using commercial LS-DYNA software. In particular, the paper deals with numerical 3D simulations of damages caused by air blast waves generated by C4 charges on two fully clamped rectangular plates made of steel and hybrid (S2/Carbon) composite, respectively. A Multi Materials Arbitrary Lagrangian Eulerian (MMALE) formulation was used to simulate the shock phenomenon. For the steel plates, the Johnson-Cook material model was employed. For the composite plates both in-plane and out-of-plane failure criteria were employed. In particular, a contact tiebreak formulation with a mixed mode failure criteria was employed to simulate delamination failure. As for the steel plates the results showed that excellent correlation with the experimental data for the two blast load conditions in terms of dynamic and residual deflection for two different C4 charges. For the composite plates the numerical results showed that, as expected, a wider delamination damage was observed

  9. A pH-, salt- and solvent-responsive carboxymethylcellulose-g-poly(sodium acrylate/medical stone superabsorbent composite with enhanced swelling and responsive properties

    Directory of Open Access Journals (Sweden)

    2011-05-01

    Full Text Available Free-radical graft copolymerization among sodium carboxymethylcellulose (CMC, partially neutralized acrylic acid (NaA, medical stone (MS and crosslinker N,N'-methylene-bis-acrylamide (MBA was performed to prepare new carboxymethylcellulose-g-poly(sodium acrylate/medical stone (CMC-g-PNaA/MS superabsorbent composites. Fourier transform infrared (FTIR spectra, thermogravimetry- differential scanning calorimetry (TG-DSC and field emission scanning electromicrsocopic (FESEM analysis confirmed that NaA had been grafted onto CMC backbone and MS participated in polymerization, and the thermal stability and surface morphologies were improved by the addition of MS. Energy dispersive spectrometer (EDS and elemental map (EM analyses revealed the better distribution of MS in the CMC-g-PNaA matrix. The incorporation of 20 wt% MS clearly enhanced the water absorption by 100% (from 317 to 634 g/g. The developed composites showed enhanced swelling rate and On-Off switching swelling characteristics in various pH solutions, saline solutions and hydrophilic organic solvents, which represented interesting and reversible pH-, saline- and hydrophilic organic solvent-responsive characteristics. In addition, the composite exhibited intriguing time-dependent kinetic swelling properties in various heavy metal solutions.

  10. Antibiotic-loaded acrylic bone cements: An in vitro study on the release mechanism and its efficacy

    Energy Technology Data Exchange (ETDEWEB)

    Miola, Marta, E-mail: marta.miola@polito.it [Applied Science and Technology Department, Politecnico di Torino (Italy); Bistolfi, Alessandro [Department of Orthopaedics, Traumatology and HM, University of Turin (Italy); AO CTO, M Adelaide Hospital, Turin (Italy); Valsania, Maria Carmen; Bianco, Carlotta [Department of Orthopaedics, Traumatology and HM, University of Turin (Italy); Fucale, Giacomo [Chemical, Clinical and Microbiological Analyses Dept., CTO, Turin (Italy); Verné, Enrica [Applied Science and Technology Department, Politecnico di Torino (Italy)

    2013-07-01

    An in vitro study was carried out in order to investigate the antibiotic release mechanism and the antibacterial properties of commercially (Palacos® R + G and Palacos® LV + G) and manually (Palacos® R + GM and Palacos® LV + GM) blended gentamicin-loaded bone cements. Samples were characterized by means of scanning electron microscopy (SEM) and compression strength was evaluated. The antibiotic release was investigated by dipping sample in simulated body fluid (SBF) and periodically analyzing the solution by means of high pressure liquid chromatography (HPLC). Different antibacterial tests were performed to investigate the possible influence of blending technique on antibacterial properties. Only some differences were observed between gentamicin manually added and commercial ones, in the release curves, while the antibacterial effect and the mechanical properties seem to not feel the blending technique. Highlights: • The efficacy of commercially and manually mixed antibiotic-loaded cements is studied. • Exhaustive mechanical, drug release and antibacterial studies are carried out. • The blending technique does not affect the antibacterial and mechanical properties. • The blending process influences only the release curve, not the released drug amount.

  11. Micromechanical design of hierarchical composites using global load sharing theory

    Science.gov (United States)

    Rajan, V. P.; Curtin, W. A.

    2016-05-01

    Hierarchical composites, embodied by natural materials ranging from bone to bamboo, may offer combinations of material properties inaccessible to conventional composites. Using global load sharing (GLS) theory, a well-established micromechanics model for composites, we develop accurate numerical and analytical predictions for the strength and toughness of hierarchical composites with arbitrary fiber geometries, fiber strengths, interface properties, and number of hierarchical levels, N. The model demonstrates that two key material properties at each hierarchical level-a characteristic strength and a characteristic fiber length-control the scalings of composite properties. One crucial finding is that short- and long-fiber composites behave radically differently. Long-fiber composites are significantly stronger than short-fiber composites, by a factor of 2N or more; they are also significantly tougher because their fiber breaks are bridged by smaller-scale fibers that dissipate additional energy. Indeed, an "infinite" fiber length appears to be optimal in hierarchical composites. However, at the highest level of the composite, long fibers localize on planes of pre-existing damage, and thus short fibers must be employed instead to achieve notch sensitivity and damage tolerance. We conclude by providing simple guidelines for microstructural design of hierarchical composites, including the selection of N, the fiber lengths, the ratio of length scales at successive hierarchical levels, the fiber volume fractions, and the desired properties of the smallest-scale reinforcement. Our model enables superior hierarchical composites to be designed in a rational way, without resorting either to numerical simulation or trial-and-error-based experimentation.

  12. Analysis of delamination growth in compressively loaded composite laminates

    Science.gov (United States)

    Tratt, Matthew D.

    The present analytical and empirical study of composite structure delamination has attempted to predict the threshold stress for the initiation of delamination growth in compressively loaded composite laminates. The strain-energy release-rate distributions around circular delaminations are computed via MSC/NASTRAN analysis in conjunction with a virtual crack-opening technique. Static compression tests were conducted on specimens of graphite fiber-reinforced epoxy having circular delaminations of various sizes. Computed delamination growth threshold-stress prediction results were at substantial variance with the test data, but confirmed trends and gave qualitative insight into quasi-static delamination growth.

  13. Damage Characteristic of Interpenetrating Phase Composites under Dynamic Loading

    Institute of Scientific and Technical Information of China (English)

    WANG Fuchi; ZHANG Xu; WANG Yangwei; WANG Lu; MA Zhuang; FAN Qunbo

    2014-01-01

    In order to investigate the damage characteristic of ceramic-metal interpenetrating phase composite (IPC) under dynamic loading, uniaxial dynamic compression was performed to characterize the failure of SiC/Al composite with 15%porosity using a modified Split Hopkinson Pressure Bar (SHPB). High speed photography was used to capture the failure procedure and set up the relationship between deformation and real stress. The deformation control technology was used to obtain collected samples in different deformations under dynamic loading. Micro CT technology was utilized to acquire real damage distribution of these specimens. Moreover, SEM was employed in comparing the damage characteristics in IPC. A summary of the available experimental results showed that IPC without lateral confinement formed double cones. The different features compared with ceramic materials without restraint was shown to be the result of the lateral restraint effect provided by metal phase to ceramics skeleton.

  14. Load sequence effects on the fatigue of unnotched composite materials

    Science.gov (United States)

    Yang, J. N.; Jones, D. L.

    1981-01-01

    A more comprehensive version of an earlier fatigue and residual strength degradation model is proposed to predict the effect of load sequence on the statistical fatigue behavior of composite laminates. The model, which reduces to various fatigue models proposed in the literature by means of approximations, is verified by a survey of experiments on glass/epoxy laminates. It is shown that the correlation between the model and the test results under dual stress levels is reasonable, and that a simplified version of the model is verified by experiments on graphite/epoxy laminates in which the correlation between theoretical predictions and results under dual stress levels is satisfactory. The model is also shown capable of predicting the effect of proof loads on the fatigue behavior of composite materials.

  15. Synthesis of poly(acrylic acid-maleic acid)SiO2/Al2O3 as novel composite material for cesium removal from acidic solutions

    International Nuclear Information System (INIS)

    A novel composite material of SiO2-Al2O3 based on poly(acrylic acid-maleic acid) was synthesized by irradiated with 60Co γ-rays at a dose of 25 KGy. The composite material was characterized using FTIR, TGA and BET surface area. Adsorption of 134Cs from HNO3 was studied as a function of contact time, temperature and concentration of Cs. Sorption behavior of 134Cs in different concentration of HCl, HNO3, acetic acid, ascorbic acid, citric acid, NaCl and NaNO3 solutions has been investigated. It can be concluded that the P(AA-MA)/SiO2/Al2O3 is promising adsorbent for Cs removal from acidic liquid radioactive waste. (author)

  16. Large Area Nondestructive Evaluation of a Fatigue Loaded Composite Structure

    Science.gov (United States)

    Zalameda, Joseph N.; Burke, Eric R.; Horne, Michael R.; Madaras, Eric I.

    2016-01-01

    Large area nondestructive evaluation (NDE) inspections are required for fatigue testing of composite structures to track damage initiation and growth. Of particular interest is the progression of damage leading to ultimate failure to validate damage progression models. In this work, passive thermography and acoustic emission NDE were used to track damage growth up to failure of a composite three-stringer panel. Fourteen acoustic emission sensors were placed on the composite panel. The signals from the array were acquired simultaneously and allowed for acoustic emission location. In addition, real time thermal data of the composite structure were acquired during loading. Details are presented on the mapping of the acoustic emission locations directly onto the thermal imagery to confirm areas of damage growth leading to ultimate failure. This required synchronizing the acoustic emission and thermal data with the applied loading. In addition, processing of the thermal imagery which included contrast enhancement, removal of optical barrel distortion and correction of angular rotation before mapping the acoustic event locations are discussed.

  17. Dynamic Viscoelasticity of Polyester/Rubber Composites under Cyclic Loading

    Institute of Scientific and Technical Information of China (English)

    Yuyan LIU; Zhenhui TIAN; Zhimin XIE; Xingwen DU

    2005-01-01

    This paper focuses on the influence of dynamic viscoelasticity and surface temperature on the fatigue mechanism and fatigue lifetime of polyester/rubber composites. Rubber composites show significant viscoelasticity during fatigue process. The variations of dynamic elastic modulus, mechanical loss angle, loss energy per cycle exhibit different trend in fatigue initial stage and final stage. Due to high viscoelasticity high heat generation occurs under cyclic loading, which leads to a high surface temperature. It is found that the variation of specimen surface temperaturedepends strongly on cycling frequency and stress amplitude. SEM (scanning electron microscopy) observation and static residual stiffness studies reveal that the surface temperature affects fracture morphology and fatigue lifetime of rubber composites strongly because of heat aging.

  18. Microcracking in composite laminates under thermal and mechanical loading. Thesis

    Science.gov (United States)

    Maddocks, Jason R.

    1995-01-01

    Composites used in space structures are exposed to both extremes in temperature and applied mechanical loads. Cracks in the matrix form, changing the laminate thermoelastic properties. The goal of the present investigation is to develop a predictive methodology to quantify microcracking in general composite laminates under both thermal and mechanical loading. This objective is successfully met through a combination of analytical modeling and experimental investigation. In the analysis, the stress and displacement distributions in the vicinity of a crack are determined using a shear lag model. These are incorporated into an energy based cracking criterion to determine the favorability of crack formation. A progressive damage algorithm allows the inclusion of material softening effects and temperature-dependent material properties. The analysis is implemented by a computer code which gives predicted crack density and degraded laminate properties as functions of any thermomechanical load history. Extensive experimentation provides verification of the analysis. AS4/3501-6 graphite/epoxy laminates are manufactured with three different layups to investigate ply thickness and orientation effects. Thermal specimens are cooled to progressively lower temperatures down to -184 C. After conditioning the specimens to each temperature, cracks are counted on their edges using optical microscopy and in their interiors by sanding to incremental depths. Tensile coupons are loaded monotonically to progressively higher loads until failure. Cracks are counted on the coupon edges after each loading. A data fit to all available results provides input parameters for the analysis and shows them to be material properties, independent of geometry and loading. Correlation between experiment and analysis is generally very good under both thermal and mechanical loading, showing the methodology to be a powerful, unified tool. Delayed crack initiation observed in a few cases is attributed to a

  19. Optimization of Sandwich Composites Fuselages Under Flight Loads

    Science.gov (United States)

    Yuan, Chongxin; Bergsma, Otto; Koussios, Sotiris; Zu, Lei; Beukers, Adriaan

    2012-02-01

    The sandwich composites fuselages appear to be a promising choice for the future aircrafts because of their structural efficiency and functional integration advantages. However, the design of sandwich composites is more complex than other structures because of many involved variables. In this paper, the fuselage is designed as a sandwich composites cylinder, and its structural optimization using the finite element method (FEM) is outlined to obtain the minimum weight. The constraints include structural stability and the composites failure criteria. In order to get a verification baseline for the FEM analysis, the stability of sandwich structures is studied and the optimal design is performed based on the analytical formulae. Then, the predicted buckling loads and the optimization results obtained from a FEM model are compared with that from the analytical formulas, and a good agreement is achieved. A detailed parametric optimal design for the sandwich composites cylinder is conducted. The optimization method used here includes two steps: the minimization of the layer thickness followed by tailoring of the fiber orientation. The factors comprise layer number, fiber orientation, core thickness, frame dimension and spacing. Results show that the two-step optimization is an effective method for the sandwich composites and the foam sandwich cylinder with core thickness of 5 mm and frame pitch of 0.5 m exhibits the minimum weight.

  20. Failure behavior of composite sandwich structures under local Loading

    Energy Technology Data Exchange (ETDEWEB)

    Rizov, V. [University of Architecture, Civil Engineering and Geodesy, Department of Technical Mechanics, Sofia (Bulgaria)

    2009-03-15

    Usually when analyzing the mechanical response of foam-cored fiber-reinforced composite sandwich structures to localized static loading, the face sheets are treated as a linear-elastic material and no damage initiation and growth is considered. However, practice shows that at higher indentation magnitudes damage develops in the face sheet in the area of contact with the indentor, which could lead to local failure of the face laminate due to the loss of bending stiffness and strength. Therefore, the main objective of the present study is to develop a damage model for predicting the local failure in the composite face sheet and its influence on the load-displacement behavior of sandwich structures under local loading. For this purpose, the Hoffman failure criterion is incorporated into a finite element modeling procedure using the ABAQUS program system. Results deducted from the modeling procedure are compared with experimental data obtained in the case of static indentation tests performed on sandwich beam specimens using steel cylindrical indentors. It is shown that taking into account the damage in the face sheet leads to a substantial improvement in the performance of the model when simulating the mechanical behavior of the sandwich structures at higher indentation values. (orig.)

  1. Assessment of Composite Delamination Self-Healing Under Cyclic Loading

    Science.gov (United States)

    O'Brien, T. Kevin

    2009-01-01

    Recently, the promise of self-healing materials for enhanced autonomous durability has been introduced using a micro-encapsulation technique where a polymer based healing agent is encapsulated in thin walled spheres and embedded into a base polymer along with a catalyst phase. For this study, composite skin-stiffener flange debonding specimens were manufactured from composite prepreg containing interleaf layers with a polymer based healing agent encapsulated in thin-walled spheres. Constant amplitude fatigue tests in three-point bending showed the effect of self-healing on the fatigue response of the skin-stiffener flange coupons. After the cycling that created debonding, fatigue tests were held at the mean load for 24 hours. For roughly half the specimens tested, when the cyclic loading was resumed a decrease in compliance (increase in stiffness) was observed, indicating that some healing had occurred. However, with continued cycling, the specimen compliance eventually increased to the original level before the hold, indicating that the damage had returned to its original state. As was noted in a prevoius study conducted with specimens tested under monotonically increasing loads to failure, healing achieved via the micro-encapsulation technique may be limited to the volume of healing agent available relative to the crack volume.

  2. Testing and simulation of composite laminates under impact loading

    Science.gov (United States)

    Dang, Xinglai

    Owing to their high stiffness-to-weight and high strength-to-weight ratios, fiber-reinforced polymer-matrix composite laminates are excellent materials for high-performance structures. However, their properties in the thickness direction are very poor as they are weakly bonded by polymeric matrices through laminate interfaces. Accordingly, when a composite laminate is subjected to impact loading, high interlaminar stresses along with the low interlaminar strengths could easily result in interlaminar damage such as delamination. This thesis investigated the response of composite laminates under low-velocity impact and presented numerical techniques for impact simulation. To begin with, instrumented drop-weight impacts ranging from subperforation to perforation levels were introduced to composite laminates having various dimensions and thicknesses. Damaged composite laminates were then subjected to compression-after-impact tests for evaluations of residual properties. Experimental results revealed that perforation was an important damage milestone since impact parameters such as peak force, contact duration, maximum deflection and energy absorption, and residual properties such as compressive stiffness, strength and energy absorption all reached critical levels as perforation took place. It was also found that thickness played a more important role than in-plane dimensions in perforation process. In order to understand more about the relationship between laminate thickness and perforation resistance and to present an economical method to improve perforation resistance, thick laminated composite plates and their assembled counterparts were investigated and compared. An energy profile correlating the impact energy and absorbed energy at all energy levels for each type of composite plates investigated was established and found to be able to address the relationship between energy and damage. Experimental results concluded that increasing thickness was more efficient

  3. Composite Bonded Joints’ Lifetime for Aircraft under Random Fatigue Loads

    Directory of Open Access Journals (Sweden)

    Wei Guo Shen

    2014-04-01

    Full Text Available In this present study, a lifetime prediction model of composite bonded joint in aircraft is developed based on variation of its elastic modulus under Random Fatigue Loads (RFL of aircraft and its approach is deduced by Miner linear damage accumulated theory. Considering some assumptions, this prediction model is conservative for aircraft engineering industry. Finally, simulation approach and analysis is developed and done for verification of deduction models. As a precondition, some assumptions are defined for simulation and verification. From simulating results, we can give a conclusion that models are properly accuracy for further study and engineering application.

  4. Structural Intensity Characterization of Composite Laminates Subjected to Impact Load

    Institute of Scientific and Technical Information of China (English)

    WANG Dong-fang; HE Peng-fei; LIU Zi-shun

    2008-01-01

    Structural intensity (SI) characterization of composite laminates subjected to impact load was dis-cussed. The SI pattern of the laminates which have different fiber orientations and boundary conditions wasanalyzed. The resultant forces and velocities of the laminates were calculated, and the structural intensity wasevaluated. The SI streamlines of carbon fiber reinforced epoxy composite laminates and the steel plates werediscussed. The results show that the SI streamlines of the graphite/epoxy laminates are different from that ofthe steel plates, and the SI streamlines are influenced by the boundaries, the stacking sequence of the compositelaminates. The change of the historical central displacement of the graphite/epoxy laminates is fasten thanthat of the steel plates.

  5. Areca Fiber Reinforced Epoxy Composites: Effect of Chemical Treatments on Impact Strength

    Directory of Open Access Journals (Sweden)

    S. Dhanalakshmi

    2015-06-01

    Full Text Available In this research work, impact strength of untreated, alkali treated, potassium permanganate treated, benzoyl chloride treated and acrylic acid treated areca fiber reinforced epoxy composites were studied under 40%, 50%, 60% and 70% fiber loadings. Impact strength increased with increase in fiber loading up to 60% and then showed a decline for all untreated and chemically treated areca fiber reinforced epoxy composites. The acrylic acid treated areca fiber reinforced epoxy composites with 60% fiber loading showed highest impact strength of 28.28 J/mm2 amongst all untreated and chemically treated areca/epoxy composites with same 60% fiber loading.

  6. Study on acrylic acid bentonite of high amount/poly(sodium acrylate) superabsorbent composite Ⅰ :the preparation process and morphology%高含量丙烯酸膨润土/聚丙烯酸钠高吸水性复合材料的研究Ⅰ:制备工艺与形貌

    Institute of Scientific and Technical Information of China (English)

    付丽华; 彭英知; 韦藤幼; 童张法

    2012-01-01

    Superabsorbent composite of high amount of acrylic acid bentonite/poly(sodium acrylic) was synthesized through solution polymerization with acrylic acid bentonite(ABT) and sodium acrylic and acrylic acid. The morphology of the composite was observed by scanning electron microscope(SEM). The results show that a-crylic acid bentonite is evenly and disorder dispersed in the composite with the sheets of 20-30 nm thickness. The preparation process are optimized. The results are as follows. The amount of ABT, crosslinker and initiator are 30wt% , 0. 3wt% , 1. lwt% of the monomer mass respectively. The total water in the system is 340 % of the monomer mass, the neutralization degree is 64 %). The absorbency of the composite is 1103 g/g in deionized water in the conditions. At the same time, the water retention property of the superabsorbent composite(PAA) is better compared to that of PAA.%通过特殊工艺将丙烯酸膨润土(简称ABT)和丙烯酸钠单体采用溶液聚合法制备出高含量丙烯酸膨润土/聚丙烯酸钠高吸水性复合材料(简称HABT/PAA).SEM考察材料的形貌得知,ABT以20~30nm的尺寸较均匀、无序地分散在聚合物基体中,且与聚合物有很好的相容性.对合成工艺进行了优化得到较优的工艺:ABT用量为单体质量的30%(质量分数),交联剂用量为单体质量的0.3%(质量分数),引发剂用量为单体质量的1.1%(质量分数),体系总水量为单体质量的340%(质量分数),中和度为64%,在此条件下,材料吸附去离子水的能力为1103g/g.同时,HABT/PAA的保水性能较聚丙烯酸钠(PAA)好.

  7. Stress analysis in curved composites due to thermal loading

    Science.gov (United States)

    Polk, Jared Cornelius

    Many structures in aircraft, cars, trucks, ships, machines, tools, bridges, and buildings, consist of curved sections. These sections vary from straight line segments that have curvature at either one or both ends, segments with compound curvatures, segments with two mutually perpendicular curvatures or Gaussian curvatures, and segments with a simple curvature. With the advancements made in multi-purpose composites over the past 60 years, composites slowly but steadily have been appearing in these various vehicles, compound structures, and buildings. These composite sections provide added benefits over isotropic, polymeric, and ceramic materials by generally having a higher specific strength, higher specific stiffnesses, longer fatigue life, lower density, possibilities in reduction of life cycle and/or acquisition cost, and greater adaptability to intended function of structure via material composition and geometry. To be able to design and manufacture a safe composite laminate or structure, it is imperative that the stress distributions, their causes, and effects are thoroughly understood in order to successfully accomplish mission objectives and manufacture a safe and reliable composite. The objective of the thesis work is to expand upon the knowledge of simply curved composite structures by exploring and ascertaining all pertinent parameters, phenomenon, and trends in stress variations in curved laminates due to thermal loading. The simply curved composites consist of composites with one radius of curvature throughout the span of the specimen about only one axis. Analytical beam theory, classical lamination theory, and finite element analysis were used to ascertain stress variations in a flat, isotropic beam. An analytical method was developed to ascertain the stress variations in an isotropic, simply curved beam under thermal loading that is under both free-free and fixed-fixed constraint conditions. This is the first such solution to Author's best knowledge

  8. Active shape control of composite structures under thermal loading

    Science.gov (United States)

    Binette, P.; Dano, M.-L.; Gendron, G.

    2009-02-01

    Maintaining the shape of high-precision structures such as space antennas and optical mirrors is still a challenging issue for designers. These structures are subjected to varying temperature conditions which often introduce thermal distortions. The development of smart materials offers great potential to correct the shape and to minimize the surface error. In this study, shape control of a composite structure under thermal loading using piezocomposites is investigated. The composite structure is made of a foam core and two carbon-epoxy face sheets. Macro-fiber composite (MFC™) patches are bonded on one side of the structure. The structure is subjected to a through-the-thickness temperature gradient which induces thermal distortion, essentially in the form of bending. The objective is to apply electric potential to the MFC™ actuators such that the deflection can be minimized. Finite-element analyses are conducted using the commercial software ABAQUS. Experiments are performed to study thermally induced distortion, piezoelectric actuation, and compensation of thermal distortion using MFC™ actuators. Numerical and experimental results are compared. A control loop based on strain measurements is used to actively control the structure. The results show that MFC™ actuators can compensate thermal distortion at all times, and that this is an efficient methodology.

  9. Innovative Manufacturing of Carbon Nanotube-Loaded Fibrillar Polymer Composites

    Science.gov (United States)

    Lin, R. J. T.; Bhattacharyya, D.; Fakirov, S.

    The concept of microfibrillar composite (MFC) has been used to create a new type of polymer composites, in which the reinforcing microfibrils are loaded with carbon nanotubes (CNT). Polyamide 66 (PA66) has been melt blended with polypropylene in a twin screw extruder with and without CNT, and thereafter cold drawn to create a fibrillar state as well as to align the CNT in the PA66 microfibrils. The drawn bristles were compression moulded at 180°C to prepare MFC plates. The scanning electron microscope (SEM) observations indicate near perfect distribution of CNT in the reinforcing PA66 microfibrils. Although the fibrillated PA66 is able to improve the tensile stiffness and strength as expected from the MFC structure, the incorporation of CNT does not exhibit any further enhancing effect. It rather adversely affects the mechanical properties due to poor interface adhesion between the matrix and the reinforcing microfibrils with the presence of CNT, as demonstrated by SEM. However, the resulting highly aligned CNT within the MFC are expected to affect the physical and functional properties of these composites.

  10. Active shape control of composite structures under thermal loading

    International Nuclear Information System (INIS)

    Maintaining the shape of high-precision structures such as space antennas and optical mirrors is still a challenging issue for designers. These structures are subjected to varying temperature conditions which often introduce thermal distortions. The development of smart materials offers great potential to correct the shape and to minimize the surface error. In this study, shape control of a composite structure under thermal loading using piezocomposites is investigated. The composite structure is made of a foam core and two carbon–epoxy face sheets. Macro-fiber composite (MFC(TM)) patches are bonded on one side of the structure. The structure is subjected to a through-the-thickness temperature gradient which induces thermal distortion, essentially in the form of bending. The objective is to apply electric potential to the MFC(TM) actuators such that the deflection can be minimized. Finite-element analyses are conducted using the commercial software ABAQUS. Experiments are performed to study thermally induced distortion, piezoelectric actuation, and compensation of thermal distortion using MFC(TM) actuators. Numerical and experimental results are compared. A control loop based on strain measurements is used to actively control the structure. The results show that MFC(TM) actuators can compensate thermal distortion at all times, and that this is an efficient methodology

  11. Synthesis of acrylic prepolymer

    International Nuclear Information System (INIS)

    An acrylic prepolymer was synthesized from glycidyl methacrylate (GMA), butyl methacrylate (BMA), methyl methacrylate (MMA) and acrylic acid (AA). Butyl acetate (BAc), benzoyl peroxide (BzO), 4-methoxyphenol (MPh) and triethylamine (TEA) were used as solvent, initiator, inhibitor and catalyst respectively. Observations of the synthesis leading to the formation of acrylic prepolymer are described. (author)

  12. Synthesis of Waterborne Polyurethane-acrylate Composite Emulsions%水性聚氨酯丙烯酸酯复合乳液的合成研究

    Institute of Scientific and Technical Information of China (English)

    陈建福

    2011-01-01

    采用种子溶胀乳液聚合法,以水性聚氨酯为种子,甲基丙烯酸甲酯和丙烯酸丁酯为单体制备水性聚氨酯丙烯酸酯复合乳液,考察了聚合温度、搅拌速度、引发剂种类、引发剂用量及反应时间对聚合过程的影响.结果表明:适宜的聚合温度控制为85℃;适宜的搅拌速率为150~250 r/min;采用水溶性引发剂时引发效率较高,过硫酸钾的最佳用量为0.8%;随着反应时间的增加,乳液粒径先减小后增大.用红外光谱对聚氨酯丙烯酸酯乳液进行分析,表明丙烯酸酯参与了反应.%Polyurethane-acrylate composite emulsions were synthesized by seed swelling polymerization with aqueous polyurethane dispersion as seed,methyl methacrylate and butyl acrylate as vinyl monomers.The influences of polymerization temperature,stirring rare,the species and content of initiator and the reaction time on the polymerization process were investigated.The results showed that the suitable polymerization temperature was 85 ℃ and the stirring rare were between the 150~250 r/min;the initiating efficiency of the water-soluble initiator was higher,and the optimum content of potassium persulphate was 0.8%.The latex particle size decreased and then increased with the increase of reaction time.In addition the arylate was found in polyurethane-acrylate emulsion by FT-IR.

  13. Effect of cyclic loading on microleakage of silorane based composite compared with low shrinkage methacrylate-based composites

    Directory of Open Access Journals (Sweden)

    Hamid Kermanshah

    2016-01-01

    Conclusion: Silorane did not provide better marginal seal than the low shrinkage methacrylate-based composites (except Aelite. In addition, cyclic loading did not affect the marginal microleakage of evaluated composite restorations .

  14. Energy absorption capabilities of composite sandwich panels under blast loads

    Science.gov (United States)

    Sankar Ray, Tirtha

    As blast threats on military and civilian structures continue to be a significant concern, there remains a need for improved design strategies to increase blast resistance capabilities. The approach to blast resistance proposed here is focused on dissipating the high levels of pressure induced during a blast through maximizing the potential for energy absorption of composite sandwich panels, which are a competitive structural member type due to the inherent energy absorption capabilities of fiber reinforced polymer (FRP) composites. Furthermore, the middle core in the sandwich panels can be designed as a sacrificial layer allowing for a significant amount of deformation or progressive failure to maximize the potential for energy absorption. The research here is aimed at the optimization of composite sandwich panels for blast mitigation via energy absorption mechanisms. The energy absorption mechanisms considered include absorbed strain energy due to inelastic deformation as well as energy dissipation through progressive failure of the core of the sandwich panels. The methods employed in the research consist of a combination of experimentally-validated finite element analysis (FEA) and the derivation and use of a simplified analytical model. The key components of the scope of work then includes: establishment of quantified energy absorption criteria, validation of the selected FE modeling techniques, development of the simplified analytical model, investigation of influential core architectures and geometric parameters, and investigation of influential material properties. For the parameters that are identified as being most-influential, recommended values for these parameters are suggested in conceptual terms that are conducive to designing composite sandwich panels for various blast threats. Based on reviewing the energy response characteristic of the panel under blast loading, a non-dimensional parameter AET/ ET (absorbed energy, AET, normalized by total energy

  15. A preliminary study of the composition of commercial oil, acrylic and vinyl paints and their behaviour after accelerated ageing conditions

    Directory of Open Access Journals (Sweden)

    Francesca Caterina Izzo

    2014-12-01

    Full Text Available This study is part of a research project dealing with the establishment of monitoring and damage prevention plans for contemporary artworks. For this purpose, some commercial paints, among the most currently used by young artists, were selected: Winton oil paint (Winsor & Newton, UK, Heavy Body acrylic paint (Liquitex, USA and Flashe vinyl paint (Lefranc & Bourgeois, France. The paints were subjected to different treatments of accelerated ageing, the results indicating different behaviour in relation both to the type of binders and pigments present in the different formulations. In particular, it was observed that ageing produced by ozone plays an important role in the stability of the oil paints, above all in those containing organic azo pigments. Thermal ageing, as expected, influences the stability of all the commercial paints examined, with the formation of alteration products and visible changes in the paint films. Ageing produced by moisture clearly affects the synthetic polymer-based paints, particularly evident in the changes in mass. In all cases, the accelerated ageing treatments produced chromatic variations, more evidently for the oil paints containing organic pigment.

  16. Composite Vessels for Containment of Extreme Blast Loadings

    Energy Technology Data Exchange (ETDEWEB)

    Pastrnak, J; Henning, C; Grundler, W; Switzer, V; Hollaway, R; Morrison, J; Hagler, L; Kokko, E; Deteresa, S; Hathcoat, B; Dalder, E

    2004-07-15

    A worldwide trend for explosives testing has been to replace open-air detonations with containment vessels, especially when any hazardous materials are involved. As part of the National Nuclear Security Administration's (NNSA) effort to ensure the safety and reliability of the nation's nuclear stockpile, researchers at Lawrence Livermore National Laboratory have been developing a high performance filament wound composite firing vessel that is nearly radiographically transparent. It was intended to contain a limited number of detonations of metal cased explosive assemblies in radiographic facilities such as the Advanced Hydrodynamic Facility (AHF) being studied by Los Alamos National Laboratory. A 2-meter diameter pressure vessel was designed to contain up to 35 kg (80 lb) of TNT equivalent explosive without leakage. Over the past 5 years a total of three half-scale (1 meter diameter) vessels have been constructed, and two of them were tested to 150% load with 8.2 kg (18-pound) spheres of C4 explosive. The low density and high specific strength advantages used in this composite vessel design may have other additional applications such as transporting sensitive explosives that could otherwise be moved only in very small quantities. Also, it could be used for highly portable, explosive containment systems for law enforcement.

  17. Response of marine composites subjected to near field blast loading

    Science.gov (United States)

    LiVolsi, Frank

    Experimental studies were performed to understand the explosive response of composite panels when exposed to near-field explosive loading in different environments. The panel construction under consideration was an E-glass fiber-reinforced composite laminate infused with vinyl ester resin (Derakane 8084). The panel was layered bi-axially with plain-woven fiber orientations at 0° and 90°. Panel dimensions were approximately 203 mm x 203 mm x 1 mm (8 in x 8 in x 0.04 in). Experiments were carried out with the panel fully clamped in a holding fixture, which was in turn fastened inside a water tank. The fixture was fastened in such a way as to allow for explosive loading experiments in the following environments: water submersion with water backing, water submersion with air backing, and air immersion with air backing. Experiments were performed in room temperature conditions, and additional experiments in the submerged environments were also performed at high and low water temperatures of 40°C and 0°C, respectively. A stereo Digital Image Correlation (DIC) system was employed to capture the full-field dynamic behavior of the panel during the explosive event. Results indicated that the immersion environment contributes significantly to the blast response of the material and to the specimens' appreciable damage characteristics. The water submersion with air backing environment was found to encourage the greatest panel center point deflection and the most significant damage mechanisms around the boundary. The air immersion with air backing environment was found to encourage less center point deflection and exhibited significant impact damage from the explosive capsule. The water submersion with water backing environment encouraged the least panel deflection and minimal interlaminate damage around the panel boundary and center. Water temperature was found to influence the panel center point deflection, but not damage mechanisms. Maximum positive center point

  18. Synthesis and characterization of chitosan-graft-poly(acrylic acid)/rice husk ash hydrogels composites; Sintese e caracterizacao de hidrogeis compositos de cinza da casca de arroz e quitosana enxertada com poli(acido acrilico)

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Francisco H.A. [Universidade Estadual Vale do Acarau - UVA, Sobral, CE (Brazil); Lopes, Gabriel V.; Pereira, Antonio G.B.; Fajardo, Andre R.; Muniz, Edvani C. [Universidade Estadual de Maringa - UEM, PR (Brazil)

    2011-07-01

    According to environmental concerns, super absorbent hydrogel composites were synthesized based on rice husk ash (RHA), an industrial waste, and Chitosan-graft-poly(acrylic acid). The WAXS and FTIR data confirmed the syntheses of hydrogel composites. The effect of crystalline or amorphous RHA on water uptake was investigated. It was found that the RHA in crystalline form induces higher water capacity (W{sub eq}) of composites hydrogels due to the fact that the intra-interactions among silanol groups on RHA make available new sites in the polymer matrix, which could interact to water. (author)

  19. Synthesis of berberine loaded polymeric nanoparticles by central composite design

    Science.gov (United States)

    Mehra, Meenakshi; Sheorain, Jyoti; Kumari, Santosh

    2016-04-01

    Berberine is an isoquinoline alkaloid which is extracted from bark and roots of Berberis vulgaris plant. It has been used in ayurvedic medicine as it possess antimicrobial, antidiabetic, anticancer, antioxidant properties etc. But poor solubility of berberine leads to poor stability and bioavailability in medical formulations decreasing its efficacy. Hence nanoformulations of berberine can help in removing the limiting factors of alkaloid enhancing its utilization in pharmaceutical industry. Sodium alginate polymer was used to encapsulate berberine within nanoparticles by emulsion solvent evaporation method using tween 80 as a surfactant. Two factors and three level in central composite design was used to study the formulation. The optimized formulation (1% v/v of Tween 80 and 0.01% w/v of sodium alginate) of polymeric nanoparticles was taken for further evaluations. The size of synthesized nanoparticles was found to be 71.18 nm by particle size analysis (PSA). The berberine loaded polymeric nanoparticles showed better antibacterial activity compared to aqueous solution of berberine by well diffusion assay.

  20. LDEXPT, an intelligent database system for the Composite Load Spectra project

    Science.gov (United States)

    Ho, H.; Newell, J. F.; Hopkins, D.; Chamis, C. C.

    1990-01-01

    The Composite Load Spectra project develops probabilistic models to simulate the probabilistic loads for selected components of a generic space propulsion system. Tremendous information such as engine load variables and their distributions is needed by the simulation program. An intelligent data base system was constructed and integrated with the probabilistic load simulation program to manage and maintain the knowledge base of the Composite Load Spectra project. The intelligent data base system takes care of the data retrieval and storage functions and has expert knowledge on engine load models and associated engine variables. The integration of the intelligent data base into the load simulation program achieves a smooth coupling between the numeric processing (load simulation calculation) and the symbolic processing (intelligent load information management).

  1. Exploring the piezoelectric performance of PZT particulate-epoxy composites loaded in shear

    Science.gov (United States)

    Van Loock, F.; Deutz, D. B.; van der Zwaag, S.; Groen, W. A.

    2016-08-01

    The active and passive piezoelectric response of lead zirconium titanate (PZT)-epoxy particulate composites loaded in shear is studied using analytical models, a finite element model and by experiments. The response is compared to that of the same composites when loaded in simple tension. Analogously to bulk PZT, particulate PZT-polymer composites loaded in shear show higher piezoelectric charge coefficient (d 15) and energy density figure of merit (FOM15) values compared to simple tension (d 33) and (FOM33). This outcome demonstrates the as-yet barely explored potential of piezoelectric particulate composites for optimal strain energy harvesting when activated in shear.

  2. Impact of Waveguide Filling Material on Near-Field Microwave Inspection of Carbon-Loaded Composites

    Science.gov (United States)

    Qaddoumi, Nasser; Saleh, Wael; Sediq, Akram Bin

    2010-10-01

    The advent of carbon loaded composite materials gave a boost to many industries. This is because of their light weight, durability and strength. As new structures utilizing carbon loaded composites are built, the need for a reliable nondestructive testing technique increases. A carbon-loaded composite testing poses a challenge to most nondestructive testing and evaluation (NDT&E) techniques. Microwave NDT&I techniques main challenge is the lossy nature of carbon, especially at high microwave frequencies. Lower frequencies penetrate deeper in carbon-loaded composites, however, to operate at lower frequencies the size of the waveguide probe increases significantly which degrades the resolution rapidly. Open-ended rectangular waveguide sensors filled with a dielectric material will be used to inspect carbon-loaded composites. The filling of the waveguide reduces the frequency of operation and keeps the small size of the waveguide (i.e. increases the penetration depth and maintains the resolution). However, varying the waveguide filling material dielectric properties will have an impact on the measurement parameters optimization process and consequently on the detection sensitivity. In this paper, the use of the waveguide filling material as an optimization parameter will be investigated. Carbon-loaded composites with disbonds will be inspected and the variation of the dielectric properties of the loading material of rectangular waveguide probes for carbon loaded composites inspection will be assessed.

  3. Polymer optical waveguide composed of europium-aluminum-acrylate composite core for compact optical amplifier and laser

    Science.gov (United States)

    Mitani, Marina; Yamashita, Kenichi; Fukui, Toshimi; Ishigure, Takaaki

    2015-02-01

    We successfully fabricate polymer waveguides with Europium-Aluminum (Eu-Al) polymer composite core using the Mosquito method that utilizes a microdispenser for realizing a compact waveguide optical amplifiers and lasers. Rareearth (RE) ions are widely used as the gain medium for fiber lasers and optical fiber amplifiers. However, high concentration doping of rare-earth-ion leads to the concentration quenching resulting in observing less gain in optical amplification. For addressing the concentration quenching problem, a rare-earth metal (RE-M) polymer composite has been proposed by KRI, Inc. to be a waveguide core material. Actually, 10-wt% RE doping into organic polymer materials was already achieved. Hence, realization of compact and high-efficiency waveguide amplifiers and lasers have been anticipated using the RE-M polymer composite. In this paper, a microdispenser is adopted to fabricate a Eu-doped polymer waveguide. Then, it is experimentally confirmed that the low-loss waveguides are fabricated with a high reproducibility. Optical gain is estimated by measuring the amplified spontaneous emission using the variable stripe length method. The fabricated waveguide exhibits an optical gain as high as 7.1 dB/cm at 616-nm wavelength.

  4. 新型喷涂用双组分聚脲/丙烯酸聚氨酯复合涂料%Novel Tow-component Polyurea/Acrylic Polyurethane Composite Coating for Spray

    Institute of Scientific and Technical Information of China (English)

    仇伟; 刘见祥; 潘鲁; 张波; 刘蔚凯; 曾舒

    2013-01-01

    采用羟基丙烯酸树脂与聚天门冬氨酸酯制备喷涂用双组分聚脲/丙烯酸聚氨酯涂料,考察了涂料的基本性能,研究了两种树脂的配比、流平剂用量等对涂料性能的影响.结果表明,当羟基丙烯酸树脂与聚天门冬氨酸酯的质量比为35∶45,流平剂用量为0.3%时,涂料具有优良的综合性能和耐老化性能.%The tow-component polyurea/ acrylic polyurethane composite coating for spray was prepared by using hydrox-yl acrylic resins and polyaspartic. The basic properties of the coatings were investigated, and the influences of the ratio of two resins and flow agent on the properties of coating were studied. The results show that when using hydroxy acrylic resin and polyaspartic at 35 : 45, flow agent 0. 3% , the composite coating provides excellent comprehensive performance and anti-aging properties.

  5. Intercalation of acrylic acid and sodium acrylate into kaolinite and their in situ polymerization

    Science.gov (United States)

    Zhang, Bo; Li, Yanfeng; Pan, Xiaobing; Jia, Xin; Wang, Xiaolong

    2007-02-01

    Novel nano-composites of poly (acrylic acid)-kaolinite were prepared, and intercalation and in situ polymerization were used in this process. The nano-composites were obtained by in situ polymerization of acrylic acid (AA) and sodium acrylate (AANa) intercalated into organo-kaolinite, which was obtained by refining and chemically modifying with solution intercalation step in order to increase the basal plane distance of the original clay. The modification was completed by using dimethyl-sulfoxide (DMSO)/methanol and potassium acetate (KAc)/water systems step by step. The materials were characterized with the help of XRD, FT-IR and TEM; the results confirmed that poly(acrylic acid) (PAA) and poly(sodium acrylate) (PAANa) were intercalated into the interlamellar spaces of kaolinite, the resulting copolymer composites (CC0 : copolymer crude kaolinite composite, CC1 : copolymer DMSO kaolinite composite, CC2 : copolymer KAc kaolinite composite) of CC2 exhibited a lamellar nano-composite with a mixed nano-morphology, and partial exfoliation of the intercalating clay platelets should be the main morphology. Finally, the effect of neutralization degree on the intercalation behavior was also investigated.

  6. Silicone/Acrylate Copolymers

    Science.gov (United States)

    Dennis, W. E.

    1982-01-01

    Two-step process forms silicone/acrylate copolymers. Resulting acrylate functional fluid is reacted with other ingredients to produce copolymer. Films of polymer were formed by simply pouring or spraying mixture and allowing solvent to evaporate. Films showed good weatherability. Durable, clear polymer films protect photovoltaic cells.

  7. 聚丙烯酸-腐植酸钠复合高吸水树脂的合成研究∗%Study on the Synthesis of Poly Acrylic Acid-sodium Humate Composite Super Absorbent Polymer

    Institute of Scientific and Technical Information of China (English)

    李东芳; 杜明华

    2015-01-01

    该研究采用不除去丙烯酸中阻聚剂及不通氮气的工艺,以丙烯酸、腐植酸钠为原料,通过水溶液聚合法制备了聚丙烯酸-腐植酸钠复合高吸水树脂。研究结果表明:该复合高吸水树脂在丙烯酸的中和度为60%,腐植酸钠用量为1.0g,引发剂过硫酸钾用量为55mg,交联剂N,N′-亚甲基双丙烯酰胺用量为20mg时,吸蒸馏水量最大,为1200 g/g。%The poly acrylic acid-sodium humate composite super absorbent polymer was synthesized by aqueous solution polymerization through the technology of no nitrogen and not removing polymerization inhibitor in acrylic acid. In the synthesis process, acrylic acid and sodium humate were as monomer. The study results showed that when the neutralization degree of acrylic acid was 60%,the dosage of sodium humate was 1. 0g,the dosage of initia-tor( potassium persulfate) was 55mg, and the dosage of crosslinking agent ( N, N′-methylenebisacrylamide) was 20mg,the highest distilled water-absorbing capacity of the composite super absorbent polymer was 1200g/g.

  8. 聚丙烯酸-腐植酸钠复合高吸水树脂的合成研究∗%Study on the Synthesis of Poly Acrylic Acid-sodium Humate Composite Super Absorbent Polymer

    Institute of Scientific and Technical Information of China (English)

    李东芳; 杜明华

    2015-01-01

    The poly acrylic acid-sodium humate composite super absorbent polymer was synthesized by aqueous solution polymerization through the technology of no nitrogen and not removing polymerization inhibitor in acrylic acid. In the synthesis process, acrylic acid and sodium humate were as monomer. The study results showed that when the neutralization degree of acrylic acid was 60%,the dosage of sodium humate was 1. 0g,the dosage of initia-tor( potassium persulfate) was 55mg, and the dosage of crosslinking agent ( N, N′-methylenebisacrylamide) was 20mg,the highest distilled water-absorbing capacity of the composite super absorbent polymer was 1200g/g.%该研究采用不除去丙烯酸中阻聚剂及不通氮气的工艺,以丙烯酸、腐植酸钠为原料,通过水溶液聚合法制备了聚丙烯酸-腐植酸钠复合高吸水树脂。研究结果表明:该复合高吸水树脂在丙烯酸的中和度为60%,腐植酸钠用量为1.0g,引发剂过硫酸钾用量为55mg,交联剂N,N′-亚甲基双丙烯酰胺用量为20mg时,吸蒸馏水量最大,为1200 g/g。

  9. Effect of loading rate on tensile properties and failure behavior of glass fibre/epoxy composite

    Science.gov (United States)

    Mahato, K. K.; Biswal, M.; Rathore, D. K.; Prusty, R. K.; Dutta, K.; Ray, B. C.

    2016-02-01

    Fibre reinforced polymeric (FRP) composite materials are subjected to different range of loading rates during their service life. Present investigation is focused on to study the effects of variation of loading rates on mechanical behavior and various dominating failure modes of these potential materials when subjected to tensile loading. The results revealed that on the variation of loading rates the ultimate tensile strength varies but the tensile modulus is mostly unaffected. Furthermore, the strain to failure is also increasing with increase in loading rates. Different failure patterns of glass/epoxy composite tested at 1, 10,100, 500 and 1000 mm/min loading rates are identified. Scanning electron micrographs shows various dominating failures modes in the glass/epoxy composite.

  10. Buckling of Cracked Laminated Composite Cylindrical Shells Subjected to Combined Loading

    Science.gov (United States)

    Allahbakhsh, Hamidreza; Shariati, Mahmoud

    2013-10-01

    A series of finite element analysis on the cracked composite cylindrical shells under combined loading is carried out to study the effect of loading condition, crack size and orientation on the buckling behavior of laminated composite cylindrical shells. The interaction buckling curves of cracked laminated composite cylinders subject to different combinations of axial compression, bending, internal pressure and external pressure are obtained, using the finite element method. Results show that the internal pressure increases the critical buckling load of the CFRP cylindrical shells and bending and external pressure decrease it. Numerical analysis show that axial crack has the most detrimental effect on the buckling load of a cylindrical shell and results show that for lower values of the axial compressive load and higher values of the external pressure, the buckling is usually in the global mode and for higher values of axial compressive load and lower levels of external pressure the buckling mode is mostly in the local mode.

  11. Effect of a silane coupling agent on the optical and the mechanical characteristics of nano diamond / acrylic resin composites

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Min-Gun; Chun, Yoon-Soo; Lim, Dae-Soon [Korea University, Seoul (Korea, Republic of); Kim, Jung Youl [LG Electronics Inc., Seoul (Korea, Republic of)

    2014-10-15

    Nano diamond (ND) is a good candidate for a filler material to fabricate transparent films. This study explores a characterization of the optical and the mechanical properties of ND dispersed polymer films. An attrition milling method was adapted to break ND aggregates, and a silane coupling agent (3-methacryloxy propyl trimethoxysilane) was used to modify the ND surfaces and stabilize the dispersion. Dipentaerylthritol hexaacrylate and pentaerythritol tetraacrylate were used in the polymer matrix, and up to 3 wt.% of ND was added to improve the mechanical properties. Fabricated composites were analyzed and tested using UV-visible spectroscopy for the optical properties and a Micro-Vickers hardness tester and ball-on-disktype friction tester for the mechanical properties. Results show that the transmittance of the ND-added composite increased with decreasing aggregate size. Through the addition of small amounts of NDs, the mechanical properties were greatly improved, the material became 3.5 times as hard, and the wear rate were greatly decreased. Possible mechanisms responsible for the enhancement of the mechanical and the optical properties are discussed.

  12. Effect of a silane coupling agent on the optical and the mechanical characteristics of nanodiamond/acrylic resin composites

    Science.gov (United States)

    Jeong, Min-Gun; Chun, Yoon-Soo; Lim, Dae-Soon; Kim, Jung Youl

    2014-10-01

    Nanodiamond (ND) is a good candidate for a filler material to fabricate transparent films. This study explores a characterization of the optical and the mechanical properties of ND dispersed polymer films. An attrition milling method was adapted to break ND aggregates, and a silane coupling agent (3-methacryloxypropyltrimethoxysilane) was used to modify the ND surfaces and stabilize the dispersion. Dipentaerylthritol hexaacrylate and pentaerythritol tetraacrylate were used in the polymer matrix, and up to 3 wt.% of ND was added to improve the mechanical properties. Fabricated composites were analyzed and tested using UV-visible spectroscopy for the optical properties and a Micro-Vickers hardness tester and ball-on-disktype friction tester for the mechanical properties. Results show that the transmittance of the ND-added composite increased with decreasing aggregate size. Through the addition of small amounts of NDs, the mechanical properties were greatly improved, the material became 3.5 times as hard, and the wear rate were greatly decreased. Possible mechanisms responsible for the enhancement of the mechanical and the optical properties are discussed.

  13. Effect of a silane coupling agent on the optical and the mechanical characteristics of nano diamond / acrylic resin composites

    International Nuclear Information System (INIS)

    Nano diamond (ND) is a good candidate for a filler material to fabricate transparent films. This study explores a characterization of the optical and the mechanical properties of ND dispersed polymer films. An attrition milling method was adapted to break ND aggregates, and a silane coupling agent (3-methacryloxy propyl trimethoxysilane) was used to modify the ND surfaces and stabilize the dispersion. Dipentaerylthritol hexaacrylate and pentaerythritol tetraacrylate were used in the polymer matrix, and up to 3 wt.% of ND was added to improve the mechanical properties. Fabricated composites were analyzed and tested using UV-visible spectroscopy for the optical properties and a Micro-Vickers hardness tester and ball-on-disktype friction tester for the mechanical properties. Results show that the transmittance of the ND-added composite increased with decreasing aggregate size. Through the addition of small amounts of NDs, the mechanical properties were greatly improved, the material became 3.5 times as hard, and the wear rate were greatly decreased. Possible mechanisms responsible for the enhancement of the mechanical and the optical properties are discussed.

  14. Injectable, high modulus, and fatigue resistant composite scaffold for load-bearing soft tissue regeneration.

    Science.gov (United States)

    Hayami, James W S; Waldman, Stephen D; Amsden, Brian G

    2013-12-01

    High modulus, two-phase, bicontinuous scaffolds were prepared by photocross-linking an aqueous suspension of chondrocytes and N-methacrylate glycol chitosan with a hydrolyzable, hydrophobic, acrylated star-copolymer. Two acrylated star-copolymers were examined: poly(ε-caprolactone-co-d,l-lactide) (5446DLLACL) and poly(ε-caprolactone-co-trimethylene carbonate) (7030TMCCL). The scaffolds were assessed for injectability, two-phase interconnectivity, fatigue resistance, and long-term static culture behavior. The 7030TMCCL scaffolds demonstrated decreased moduli of 17% after 1 × 10(6) cycles at 30% strain and 5% after 56 days in culture, compared to the 5446DLLACL scaffolds, which exhibited decreases of 58 and 68%, respectively. The 7030TMCCL scaffolds accumulated more extracellular matrix after 56 days of culture (GAG: 20.1 ± 1, collagen: 35.5 ± 1.8 μg) compared to 5446DLLACL scaffolds (GAG: 13.2 ± 0.6, collagen: 6.2 ± 3.4 μg). Overall, the 7030TMCCL-based scaffolds were shown to be better suited for use as a load bearing soft tissue scaffold. PMID:24147621

  15. Study on epoxy-acrylate copolymer composite emulsion%环氧丙烯酸酯共聚物复合乳液研究

    Institute of Scientific and Technical Information of China (English)

    郭文录; 朱华伟; 张莉

    2011-01-01

    A water-based epoxy-acrylate hybrid emulsion was prepared by core-shell emulsion polymerization with epoxy-modified acrylate emulsion. The acrylate before and after modification were characterized by contact angle and polarization curve measurements, as well as Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA) and electrochemical impedance spectroscopy (EIS) techniques. The results proved that the hydrophobicity, thermal stability and corrosion resistance of the acrylate modified by 12% epoxy resin are improved evidently, as compared with the unmodified acrylate.%通过核壳乳液聚合工艺引入环氧树脂,对丙烯酸醋乳液进行改性,制备了水性环氧/丙烯酸醋杂化乳液.通过接触角、极化曲线测试以及傅里叶变换红外光谱(FT-IR)、热重分析(TGA)、电化学阻抗谱(EIS)等方法对改性前后的丙烯酸醋进行了表征.结果表明,以12%环氧树脂改性的丙烯酸醋与改性前的丙烯酸酣相比,其疏水性、热稳定性和耐蚀性能都有较大的改进.

  16. Delaminations in composite plates under transverse static loads - Experimental results

    Science.gov (United States)

    Finn, Scott R.; He, Yi-Fei; Springer, George S.

    1992-01-01

    Tests were performed measuring the damage initiation loads and the locations, shapes, and sizes of delaminations in Fiberite T300/976 graphite/epoxy, Fiberite IM7/977-2 graphite-toughened epoxy, and ICI APC-2 graphite-PEEK plates subjected to transverse static loads. The data were compared to the results of the Finn-Springer model, and good agreements were found between the measured and calculated delamination lengths and widths.

  17. The Effect of Water Acrylate Dispersion on the Properties of Polymer-Carbon Nanotube Composites / Wpływ Wodnej Dyspersji Akrylanowej Na Właściwości Kompozytów Polimer-Nanorurki Węglowe

    Directory of Open Access Journals (Sweden)

    Zygoń P.

    2015-12-01

    Full Text Available The paper presents properties of polymer composites reinforced with carbon nanotubes (CNT containing various mixtures of dispersion. Acrylates of different particle size and viscosity were used to produce composites. The mechanical strength of composites was determined by three-point bending tests. The roughness parameter of composites was determined with a profilometer and compared with the roughness parameter determined via atomic force microscopy (AFM. Also X-ray studies (phase composition analysis, crystallite sizes determination were carried out on these composites. Measurements of the surface topography using the Tapping Mode method were performed, acquiring the data on the height and on the phase imaging. The change of intensity, crystallite size and half-value width of main reflections originating from carbon within the composites have been determined using the X-ray analysis. The density of each obtained composite was determined as well as the resistivity at room temperature. The density of composites is quite satisfactory and ranges from 0.27 to 0.35 g/cm3. Different composites vary not only in strength but also in density. Different properties were achieved by the use of various dispersions. Carbon nanotubes constituting the reinforcement for a polymer composite improve the mechanical properties and conductivity composite.

  18. Effects of simulated functional loading conditions on dentin, composite, and laminate structures.

    Science.gov (United States)

    Walker, Mary P; Teitelbaum, Heather K; Eick, J David; Williams, Karen B

    2009-02-01

    Use of composite restorations continues to increase, tempered by more potential problems when placed in posterior dentition. Thus, it is essential to understand how these materials function under stress-bearing clinical conditions. Because mastication is difficult to replicate in the laboratory, cyclic loading is frequently used within in vitro evaluations but often employs traditional fatigue testing, which typically does not simulate occlusal loading because higher stresses and loading frequencies are used, so failure mechanisms may be different. This investigation utilized relevant parameters (specimen size, loading frequency) to assess the effects of cyclic loading on flexural mechanical properties and fracture morphology of (coronal) dentin, composite, and dentin-adhesive-composite "laminate" structures. Incremental monitoring of flexural modulus on individual beams over 60,000 loading cycles revealed a gradual increase across materials; post hoc comparisons indicated statistical significance only for 1 versus 60k cycles. Paired specimens were tested (one exposed to 60k loading cycles, one to static loading only), and comparisons of flexural modulus and strength showed statistically significantly higher values for cyclically loaded specimens across materials, with no observable differences in fracture morphology. Localized reorganization of dentin collagen and polymer chains could have increased flexural modulus and strength during cyclic loading, which may have implications toward the life and failure mechanisms of clinical restorations and underlying tooth structure. PMID:18823019

  19. An analytical solution for the elastoplastic response of a continuous fiber composite under uniaxial loading

    Science.gov (United States)

    Lee, Jong-Won; Allen, David H.

    1990-01-01

    A continuous fiber composite is modelled by a two-element composite cylinder in order to predict the elastoplastic response of the composite under a monotonically increasing tensile loading parallel to fibers. The fibers and matrix are assumed to be elastic-perfectly plastic materials obeying Hill's and Tresca's yield criteria, respectively. Here, the composite behavior when the fibers yield prior to the matrix is investigated.

  20. Electrical Response of Cement-Based Piezoelectric Ceramic Composites under Mechanical Loadings

    Directory of Open Access Journals (Sweden)

    Biqin Dong

    2011-01-01

    Full Text Available Electrical responses of cement-based piezoelectric ceramic composites under mechanical loadings are studied. A simple high order model is presented to explain the nonlinear phenomena, which is found in the electrical response of the composites under large mechanical loadings. For general situation, this nonlinear piezoelectric effect is quite small, and the composite is suitable for dynamic mechanical sensor as holding high static stability. The experimental results are consistent with the relationship quite well. The study shows that cement-based piezoelectric composite is suitable for potential application as dynamic mechanical sensor with excellent dynamic response and high static stability.

  1. Optimal overlap length in staggered architecture composites under dynamic loading conditions

    Science.gov (United States)

    Dutta, Abhishek; Tekalur, Srinivasan Arjun; Miklavcic, Milan

    2013-01-01

    Hybrid staggered architecture composites, like nacre and bone, are known for two discernible aspects: superior strength and synergistic toughness. What is lacking is the scientific rationale proving suitability of these materials under impact/time dependent loading. The current investigation aims to address the structure-property correlationship of these materials by development of an analytical model under dynamic rates of loading. Existing literature studies address behavior of staggered materials under quasi-static loading conditions. Critical overlap length was computed for three natural composites-nacre, spider-silk and, collagen in bone/tendon, and showed reasonable agreement with experimental data. Applicability of the analytical approach to predict lap-joint strength has been briefly discussed and quantified against experimental data. Choice of nanometer sized building blocks in natural composites has been addressed and explained from shear transfer efficiency point of view. The potentiality of these composites for use as biomimetic protective material under impact loading has been addressed as well.

  2. Assessment of particulate cellulose epoxy composites manufactured by JMFIL under impact load

    Science.gov (United States)

    Srinivasababu, Nadendla

    2015-08-01

    Increase in environmental concern towards sustainable development invites the development of new materials which are eco-friendly to satisfy various engineering needs. The present work introduces a new manufacturing method i.e. "Just Mold Fill and Immediate Loading" to prepare epoxy composites reinforced at different contents of particulate cellulose. The fabricated composites specimens are post processed and machined, tested as per ASTM procedures under impact load.

  3. Performance of composite I-beams under axial compression and bending load modes

    Energy Technology Data Exchange (ETDEWEB)

    Khalid, Y.A.; Ali, F.A.; Sahari, B.B.; Saad, E.M.A

    2005-04-15

    An experimental and finite-element analyses for glass/epoxy composite I-beams have been carried out. Four, six, eight and 10 layers of woven fabric glass/epoxy composite I-beams were fabricated by a hand lay-up (molding) process. Quasi-static axial crushing and bending loading modes were used for this investigation. The load-displacement response was obtained and the energy absorption values were calculated for all the composite I-beams. Three tests were done for each composite I-beams type and each loading case for the results conformation. The second part of this study includes the elastic behavior of composite I-beams of the same dimensions and materials using finite-element analysis. The woven fabric glass/epoxy composite I-beams mechanical properties have been obtained from tensile tests. Results from this investigation show that the load required and the specific energy absorption for composite I-beams under axial compression load were higher than those for three and four point bending. On the other hand, the loads required for composite I-beams under four point bending were higher than those for three point bending, while the specific energy absorption for composite I-beams under three point bending were higher than those for four point bending. The first crushing loads difference between the experimental and finite-element results fell in the 3.6-10.92% range for axial compression tests, while fell in the 1.44-12.99% and 4.94-22.0% range for three and four point bending, respectively.

  4. Controlled release and antibacterial activity of tetracycline hydrochloride-loaded bacterial cellulose composite membranes.

    Science.gov (United States)

    Shao, Wei; Liu, Hui; Wang, Shuxia; Wu, Jimin; Huang, Min; Min, Huihua; Liu, Xiufeng

    2016-07-10

    Bacterial cellulose (BC) is widely used in biomedical applications. In this study, we prepared an antibiotic drug tetracycline hydrochloride (TCH)-loaded bacterial cellulose (BC) composite membranes, and evaluated the drug release, antibacterial activity and biocompatibility. The structure and morphology of the fabricated BC-TCH composite membranes were characterized using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The TCH release results show that the incorporation of BC matrix to load TCH is able to control the release. In vitro antibacterial assay demonstrate that the developed BC-TCH composites displayed excellent antibacterial activity solely associated with the loaded TCH drug. More importantly, the BC-TCH composite membranes display good biocompatibility. These characteristics of BC-TCH composite membranes indicate that they may successfully serve as wound dressings and other medical biomaterials. PMID:27106158

  5. Aeroelastic Loads Modeling for Composite Aircraft Design Support

    NARCIS (Netherlands)

    Baluch, H.A.

    2009-01-01

    With regard to the simulation of structural vibrations and consequent aeroelastic loads in aircraft components, the use of elastic axis e.a as reference of vibrations is quite common. The e.a decouples the bending and torsion degrees of freedom (D.o.F) during the dynamic analysis. The use of the e.a

  6. Effect of cyclic loading on microleakage of silorane based composite compared with low shrinkage methacrylate-based composites

    Science.gov (United States)

    Kermanshah, Hamid; Yasini, Esmail; Hoseinifar, Razieh

    2016-01-01

    Background: There are many concerns regarding the marginal seal of composite restorations, especially when composite restorations are subjected to cyclic loading. The aim of this study was to evaluate the effect of cyclic loading on the microleakage of silorane based composite compared with low shrinkage methacrylate-based composites in class V cavities. Materials and Methods: In this in vitro study, class V cavities were prepared on the facial and lingual surfaces of 48 human premolars (96 cavities). The teeth were randomly divided into four groups of 12 teeth (24 cavities) each and restored as follows: Group 1 (Siloran System Adhesive + Filtek P90), Group 2 (All Bond SE + Aelite LS Posterior), Group 3 (Futurabond NR + Grandio), and Group 4 (G-Bond + Kalore-GC). All the specimens were thermocycled for 2000 cycles (5-55°C) and then half of the specimens from each group, were Load cycled. All teeth were immersed in 0.5% basic fuchsine dye, sectioned, and observed under a stereomicroscope. Data were analyzed using Wilcoxon test, Kruskal–Wallis, and Mann–Whitney U-tests. P < 0.05 was considered as significant. Results: In both unloaded and loaded groups, no statistically significant differences were observed among four composites at the occlusal margin, but a significant difference in gingival microleakage was found between Aelite and silorane. Occlusal and gingival microleakage was not affected by cyclic loading in none of the four restorative materials. Conclusion: Silorane did not provide better marginal seal than the low shrinkage methacrylate-based composites (except Aelite). In addition, cyclic loading did not affect the marginal microleakage of evaluated composite restorations. PMID:27274348

  7. Intermediate-scale Fire Performance of Composite Panels under Varying Loads

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Alexander [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Jernigan, Dann A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Dodd, Amanda B. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-04-01

    New aircraft are being designed with increasing quantities of composite materials used in their construction. Different from the more traditional metals, composites have a higher propensity to burn. This presents a challenge to transportation safety analyses, as the aircraft structure now represents an additional fuel source involved in the fire scenario. Most of the historical fire testing of composite materials is aime d at studying kinetics, flammability or yield strength under fire conditions. Most of this testing is small - scale. Heterogeneous reactions are often length - scale dependent, and this is thought to be particularly true for composites which exhibit signific ant microscopic dynamics that can affect macro - scale behavior. We have designed a series of tests to evaluate composite materials under various structural loading conditions with a consistent thermal condition. We have measured mass - loss , heat flux, and temperature throughout the experiments. Several types of panels have been tested, including simple composite panels, and sandwich panels. The main objective of the testing was to understand the importance of the structural loading on a composite to its b ehavior in response to fire - like conditions. During flaming combustion at early times, there are some features of the panel decomposition that are unique to the type of loading imposed on the panels. At load levels tested, fiber reaction rates at later t imes appear to be independent of the initial structural loading.

  8. Compressive damage mechanism of GFRP composites under off-axis loading: Experimental and numerical investigations

    DEFF Research Database (Denmark)

    Zhou, H.W.; Li, H.Y.; Gui, L.L.;

    2013-01-01

    Experimental and computational studies of the microscale mechanisms of damage formation and evolution in unidirectional glass fiber reinforced polymer composites (GFRP) under axial and off-axis compressive loading are carried out. A series of compressive testing of the composites with different a...

  9. General Factor Loadings and Specific Effects of the Differential Ability Scales, Second Edition Composites

    Science.gov (United States)

    Maynard, Jennifer L.; Floyd, Randy G.; Acklie, Teresa J.; Houston, Lawrence, III

    2011-01-01

    The purpose of this study was to investigate the "g" loadings and specific effects of the core and diagnostic composite scores from the Differential Abilities Scales, Second Edition (DAS-II; Elliott, 2007a). Scores from a subset of the DAS-II standardization sample for ages 3:6 to 17:11 were submitted to principal factor analysis. Four composites,…

  10. Modeling the Tensile Strength of Carbon Fiber - Reinforced Ceramic - Matrix Composites Under Multiple Fatigue Loading

    Science.gov (United States)

    Li, Longbiao

    2016-06-01

    An analytical method has been developed to investigate the effect of interface wear on the tensile strength of carbon fiber - reinforced ceramic - matrix composites (CMCs) under multiple fatigue loading. The Budiansky - Hutchinson - Evans shear - lag model was used to describe the micro stress field of the damaged composite considering fibers failure and the difference existed in the new and original interface debonded region. The statistical matrix multicracking model and fracture mechanics interface debonding criterion were used to determine the matrix crack spacing and interface debonded length. The interface shear stress degradation model and fibers strength degradation model have been adopted to analyze the interface wear effect on the tensile strength of the composite subjected to multiple fatigue loading. Under tensile loading, the fibers failure probabilities were determined by combining the interface wear model and fibers failure model based on the assumption that the fiber strength is subjected to two - parameter Weibull distribution and the loads carried by broken and intact fibers satisfy the Global Load Sharing criterion. The composite can no longer support the applied load when the total loads supported by broken and intact fibers approach its maximum value. The conditions of a single matrix crack and matrix multicrackings for tensile strength corresponding to multiple fatigue peak stress levels and different cycle number have been analyzed.

  11. Consolidation Theory for a Stone Column Composite Foundation under Multistage Loading

    Directory of Open Access Journals (Sweden)

    Shenggen Huang

    2016-01-01

    Full Text Available The consolidation theories considering instant load cannot fully reveal the consolidation mechanism of a stone column composite foundation used in the expressway embankments due to the time effect of loading; that is, the expressway embankments are often constructed in several stages for a long time. Meanwhile, owing to the special property that the pile-soil stress ratio is larger than 1, the consolidation theory for sand drain well foundation cannot be used directly in the consolidation analysis of stone column composite foundation. Based on the principle that the vertical load applied on the composite foundation is shared by the stone column and the surrounding soil, the governing solutions for the stone column composite foundation under a multistage load are established. By virtue of the separation of variables, the corresponding solutions of degree of consolidation for loading stage and maintaining load stage are derived separately. According to the Carrillo theorem, the solution for the average total degree of consolidation of entire composite foundation is also obtained. Finally, the reasonableness of the present solution has been verified by comparing the consolidation curve calculated by the present solution with that measured by site test.

  12. DYNAMIC ANALYSIS OF UNDERGROUND COMPOSITE STRUCTURES UNDER EXPLOSION LOADING

    Institute of Scientific and Technical Information of China (English)

    赵晓兵; 薛大为; 赵玉祥

    2004-01-01

    In selecting rational types of underground structures resisting explosion, in order to improve stress states of the structural section and make full use of material strength of each part of the section, the research method of composite structures is presented. Adopting the analysis method of micro-section free body, equilibrium equations, constraint equations and deformation coordination equations are given. Making use of the concept of generalized work and directly introducing Lagrange multiplier specific in physical meaning, the validity of the constructed generalized functional is proved by using variation method. The rational rigidity matching relationship of composite structure section is presented through example calculations.

  13. Mechanical behavior of a continuous fiber reinforced aluminum matrix composite subjected to transverse and thermal loading

    Science.gov (United States)

    Jansson, S.; Leckie, F. A.

    1991-01-01

    The transverse properties of an aluminum alloy metal matrix composite reinforced by continuous alumina fibers were investigated. The composite is subjected to both mechanical and cyclic thermal loading. The results of an experimental program indicate that the shakedown concept of structural mechanics provides a means of describing the material behavior. When the loading conditions are within the shakedown region, the material finally responds in an elastic manner after initial plastic response, and for loading conditions outside the shakedown region, the material exhibits a rapid incremental plastic strain accumulation. The failure strain varies by an order of magnitude according to the operating conditions. Hence, for high mechanical and low thermal loading, the failure strains is small; for low mechanical and high thermal loading, the failure strain is large.

  14. HYDROESTERIFICATION OF ACETYLENE WITH METHYL FORMATE TO METHYL ACRYLATE OVER A NiO/Al203 CATALYST: EFFECTS OF NiO LOADING AND CALCINATION TEMPERATURE

    Institute of Scientific and Technical Information of China (English)

    Huang Xinhan; Yang Xiangui; Zhang Jiaqi; Liu Zhaotie

    2001-01-01

    Hydroesterification of acetylene with methyl formate (MF) was studied over a series of nickel-supported catalysts with NiO loading varing from 0.8 wt% to 18.7 wt% and calcination temperature ranging from 623 K to 873 K. The catalyst was studied by TPR, XPS, XRD and BET. The interactions between impregnated Ni2+ and alumina during catalyst preparation produced different kinds of nickel species such as NiO crystallites and NiAl2O4-like species, and their distributions varied with NiO loading and calcination temperature, which leads to different activities of catalyst in hydroesterification of acetylene with methyl formate. Experimental results indicated that 10wt% NiO/Al2O3 calcined at 773 K is suitable for the hydroesterification of acetylene with methyl formate.

  15. Preparation of anti-yellowing polyurethane-acrylate hybrid emulsion with composite polyols%多元醇复配制备耐黄变聚氨酯丙烯酸酯复合乳液

    Institute of Scientific and Technical Information of China (English)

    沈慧芳; 严小妹; 刘天亮

    2011-01-01

    以异佛尔酮二异氰酸酯( IPDI)、混合多元醇、甲基丙烯酸甲酯(MMA)为主要原料合成了脂肪族聚氨酯丙烯酸酯复合乳液.混合多元醇由聚碳酸酯二醇( PCDL)、聚四亚甲基醚二醇(PTMEG)、聚醚二醇( N220)以不同比例复配而成.重点探讨了PCDL与N220、PTMEG与N220及PTMEG与PCDL复配比例对乳液、胶膜性能的影响.实验发现,当PTMEG与N220以相同质量比复配且控制硬段含量在60%时,得到贮存稳定性好,胶膜硬度高、耐水、耐溶剂性能好、耐黄变性优异的PUA复合乳液.%The aliphatic polyurethane-acrylate hybrid emulsions were prepared with isophorone diisocyanate (IPDI),composite polyols,and methyl methacrylate (MMA) as the main raw materials.The composite polyols were obtained by mixing polytetramethylene ether glycol (PTMEG) and polyether diol(N220),PTMEG and polycarbonate diol (PCDL),PCDL and N220 respectively at different ratio.The influences of mixing ratio of polyols on the properties of polyurethane-acrylate hybrid emulsions and their dry films were mainly discussed.The results showed that the polyurethane-acrylate hybrid emulsions had good stability,high film hardness,good water resistance and solvent resistance and excellent yollowing resistance when PTMEG and N220 were mixed by the same mass ratio and the content of hard segments was 60% in polyurethane prepolymer.

  16. Research on Mechanical Behaviors of Micro-crystal Muscovite/UHMWPE Composites to Impact Loading

    Directory of Open Access Journals (Sweden)

    Hu Huarong

    2016-01-01

    Full Text Available UHMWPE composites were prepared by hot pressing process with micro-crystal muscovite as reinforced particulates. The mechanical behaviors of composites to impact loading was evaluated by split Hopkinson bar. The results demonstrated that dynamic yield stress and failure stress of UHMWPE composites were gradually increased when the filling amount was less than 20%; when the filling content of muscovite was around 15%, the energy absorption efficiency of the composite reaches maximum value. It was also found that when strain rate within 3200/s, the dynamic yield stress, failure stress and energy absorption efficiency of UHMWPE composites increased with the increase of strain rate and display strain rate enhancement effect.

  17. Bearing capacity investigation of pin-ended composite columns with eccentricity loading using finite element simulation

    OpenAIRE

    Ahmed Abdulhaq; W.H. WAN BADARUZZAMAN

    2011-01-01

    In this paper, a complete non-linear finite element model that could represent the behaviour of the composite columns tested under axial compression in the laboratory was developed. A numerical analyses study was presented based on experimental results for investigating the effects of introducing column head on the structural behaviour of 10 finite element models of fully encased composite columns with embedded I-beam. Effects of parameters such as length of composite columns and loading cond...

  18. Delaminations in composite plates under transverse impact loads - Experimental results

    Science.gov (United States)

    Finn, Scott R.; He, Ye-Fei; Springer, George S.

    1993-01-01

    Tests were performed measuring the locations and geometries of delaminations in Fiberite T300/976 graphite/epoxy, Fiberite IM7/977-2 graphite-toughened epoxy, and ICI APC-2 graphite/PEEK plates subjected to transverse impact loads. The data provide specific information on the effects of impactor velocity, impactor mass, material, thickness of back ply group, difference in fiber orientation between adjacent ply groups, plate thickness, and impactor nose radius. The data were compared to the results of the Finn-Springer model. The model was found to describe the data with reasonable accuracy.

  19. Cyclic loadings on steel and lightweight concrete composite beams

    OpenAIRE

    Valente, Isabel; Cruz, Paulo J. S.

    2006-01-01

    This communication describes the experimental cyclic tests performed on steel and high strength lightweight concrete composite beams, at Universidade do Minho, Portugal. The experimental study involves tests on simply supported beams, all with the same geometrical disposition, supports and materials. Headed studs are used to provide the connection between the steel profile and the lightweight concrete slab. The parameters in study are the stud disposition and the number and range of the...

  20. Properties of natural rubber/attapulgite composites prepared by latex compounding method: Effect of filler loading

    Energy Technology Data Exchange (ETDEWEB)

    Muttalib, Siti Nadzirah Abdul, E-mail: sitinadzirah.amn@gmail.com; Othman, Nadras, E-mail: srnadras@usm.my; Ismail, Hanafi, E-mail: ihanafi@usm.my [School of Materials and Mineral Resources Engineering, Engineering Campus, Universiti Sains Malaysia, Seri Ampangan, 14300 Nibong Tebal, Pulau Pinang (Malaysia)

    2015-07-22

    This paper reports on the effect of filler loading on properties of natural rubber (NR)/attapulgite (ATP) composites. The NR/ATP composites were prepared by latex compounding method. It is called as masterbatch. The masterbatch was subsequently added to the NR through melt mixing process. The vulcanized NR/ATP composites were subjected to mechanical, swelling and morphological tests. All the results were compared with NR/ATP composites prepared by conventional system. The composites from masterbatch method showed better results compared to composites prepared by conventional method. They have higher tensile properties, elongation at break and tear strength. The images captured through scanning electron microscopy test revealed the improvement of tensile strength in masterbatch NR/ATP composites. It can be seen clearly that masterbatch NR/ATP have better filler dispersion compared to conventional method NR/ATP composites.

  1. Research on torsional friction behavior and fluid load support of PVA/HA composite hydrogel.

    Science.gov (United States)

    Chen, Kai; Zhang, Dekun; Yang, Xuehui; Cui, Xiaotong; Zhang, Xin; Wang, Qingliang

    2016-09-01

    Hydrogels have been extensively studied for use as synthetic articular cartilage. This study aimed to investigate (1) the torsional friction contact state and the transformation mechanism of PVA/HA composite hydrogel against CoCrMo femoral head and (2) effects of load and torsional angle on torsional friction behavior. The finite element method was used to study fluid load support of PVA/HA composite hydrogel. Results show fluid loss increases gradually of PVA/HA composite hydrogel with torsional friction time, leading to fluid load support decreases. The contact state changes from full slip state to stick-slip mixed state. As the load increases, friction coefficient and adhesion zone increase gradually. As the torsional angle increases, friction coefficient and slip trend of the contact interface increase, resulting in the increase of the slip zone and the reduction of the adhesion zone. Fluid loss increases of PVA/HA composite hydrogel as the load and the torsional angle increase, which causes the decrease of fluid load support and the increase of friction coefficient. PMID:27209115

  2. Static and dynamic moduli of posterior dental resin composites under compressive loading.

    Science.gov (United States)

    Tanimoto, Yasuhiro; Hirayama, Satoshi; Yamaguchi, Masaru; Nishiwaki, Tsuyoshi

    2011-10-01

    Dental resin composites are commonly used as restorative materials for dental treatment. To comprehend the static and dynamic moduli of dental resin composites, we investigated the mechanical behaviors of resin composites under static and dynamic loading conditions. Four commercially available resin composites for posterior restorations were evaluated. The percentages, by weight, of inorganic fillers of resin composites were examined by the ashing technique. The static compressive tests were undertaken with a constant loading speed of 1.0 mm/min using a computer-controlled INSTRON testing machine. The dynamic properties of composites were determined using the split Hopkinson pressure bar (SHPB) technique. When inorganic filler content was increased, a remarkable increase in the static modulus and dynamic modulus were observed. Furthermore, there was a strong relationship between the static modulus and dynamic modulus (r(2) = 0.947). The SHPB technique clearly demonstrated the dynamic properties of composites, and was a useful technique for determining the mechanical behavior of composites under dynamic compressive loading.

  3. Acrylic purification and coatings

    CERN Document Server

    ,

    2012-01-01

    Radon (Rn) and its decay daughters are a well-known source of background in direct WIMP detection experiments, as either a Rn decay daughter or an alpha particle emitted from a thin inner surface layer of a detector could produce a WIMP-like signal. Different surface treatment and cleaning techniques have been employed in the past to remove this type of contamination. A new method of dealing with the problem has been proposed and used for a prototype acrylic DEAP-1 detector. Inner surfaces of the detector were coated with a layer of ultra pure acrylic, meant to shield the active volume from alphas and recoiling nuclei. An acrylic purification technique and two coating techniques are described: a solvent-borne (tested on DEAP-1) and solvent-less (being developed for the full scale DEAP-3600 detector).

  4. Finite Element Analysis of Ultimate Load Capacity of Slender Concrete-Filled Steel Composite Columns

    Directory of Open Access Journals (Sweden)

    Alireza Bahrami

    2011-01-01

    Full Text Available Ultimate load capacity of slender concrete-filled steel composite columns is investigated in this paper. Nonlinear analyses are done by the use of finite element software, LUSAS, to study the ultimate axial load behaviour of the columns. Verification of the finite element modelling is done by comparing the result with the corresponding experimental result reported by other researchers. Analyses are carried out to assess different shapes and number of cold-formed steel sheeting stiffeners with various thicknesses of cold-formed steel sheets and their effects on the behaviour and ultimate axial load capacity of the columns. The results are presented in the form of axial load-normalized axial shortening plots. It is demonstrated that the ultimate axial load capacity of the slender concrete-filled steel composite columns can be accurately predicted by proposed finite element modelling. Obtained results from the study show that various thicknesses of cold-formed steel sheets, and different shapes and number of stiffeners influence the ultimate axial load capacity and behaviour of the columns. Also, the ultimate axial load capacity of the columns is improved by increase of number of stiffeners. Moreover, increase of thickness of cold-formed steel sheet enhances the ultimate axial load capacity.

  5. High-Density Protein Loading on Hierarchically Porous Layered Double Hydroxide Composites with a Rational Mesostructure.

    Science.gov (United States)

    Tokudome, Yasuaki; Fukui, Megu; Tarutani, Naoki; Nishimura, Sari; Prevot, Vanessa; Forano, Claude; Poologasundarampillai, Gowsihan; Lee, Peter D; Takahashi, Masahide

    2016-09-01

    Hierarchically porous biocompatible Mg-Al-Cl-type layered double hydroxide (LDH) composites containing aluminum hydroxide (Alhy) have been prepared using a phase-separation process. The sol-gel synthesis allows for the hierarchical pores of the LDH-Alhy composites to be tuned, leading to a high specific solid surface area per unit volume available for high-molecular-weight protein adsorptions. A linear relationship between the effective surface area, SEFF, and loading capacity of a model protein, bovine serum albumin (BSA), is established following successful control of the structure of the LDH-Alhy composite. The threshold of the mean pore diameter, Dpm, above which BSA is effectively adsorbed on the surface of LDH-Alhy composites, is deduced as 20 nm. In particular, LDH-Alhy composite aerogels obtained via supercritical drying exhibit an extremely high capacity for protein loading (996 mg/g) as a result of a large mean mesopore diameter (>30 nm). The protein loading on LDH-Alhy is >14 times that of a reference LDH material (70 mg/g) prepared via a standard procedure. Importantly, BSA molecules pre-adsorbed on porous composites were successfully released on soaking in ionic solutions (HPO4(2-) and Cl(-) aqueous). The superior capability of the biocompatible LDH materials for loading, encapsulation, and releasing large quantities of proteins was clearly demonstrated. PMID:27501777

  6. Experimental and Numerical Analysis of Notched Composites Under Tension Loading

    Science.gov (United States)

    Aidi, Bilel; Case, Scott W.

    2015-12-01

    Experimental quasi-static tests were performed on center notched carbon fiber reinforced polymer (CFRP) composites having different stacking sequences made of G40-600/5245C prepreg. The three-dimensional Digital Image Correlation (DIC) technique was used during quasi-static tests conducted on quasi-isotropic notched samples to obtain the distribution of strains as a function of applied stress. A finite element model was built within Abaqus to predict the notched strength and the strain profiles for comparison with measured results. A user-material subroutine using the multi-continuum theory (MCT) as a failure initiation criterion and an energy-based damage evolution law as implemented by Autodesk Simulation Composite Analysis (ASCA) was used to conduct a quantitative comparison of strain components predicted by the analysis and obtained in the experiments. Good agreement between experimental data and numerical analyses results are observed. Modal analysis was carried out to investigate the effect of static damage on the dominant frequencies of the notched structure using the resulted degraded material elements. The first in-plane mode was found to be a good candidate for tracking the level of damage.

  7. The effects of rattan filler loadings on properties of rattan powder-filled polypropylene composites

    Directory of Open Access Journals (Sweden)

    Nurshamila Shaari Balakrishna

    2012-11-01

    Full Text Available This study investigates the effects of filler loading on the properties of rattan powder-filled polypropylene composites. The composites were prepared by incorporating rattan powder of average size 180 µm into polypropylene matrix using a Polydrive Thermo Haake internal mixer. Filler loadings of the rattan powders ranged between 0 and 40 parts per hundred parts of resin (phr. Mechanical, morphological, and thermal properties were studied. The tensile strength, elongation at tensile failure, and impact strength decreased, while stabilization torque, thermal stability, and water absorption increased with increasing filler loading. Tensile modulus increased with addition of rattan powder and eventually decreased at 40 phr filler loading due to the weakening adhesion between the filler and the matrix. The morphological studies of fractured surfaces using SEM confirmed the deterioration in tensile properties.

  8. Composite slab behavior and strength analysis under static and dynamic loads

    Directory of Open Access Journals (Sweden)

    Florin Radu HARIGA

    2012-07-01

    Full Text Available Steel-framed buildings are typically constructed using steel-deck-reinforced concrete floor slabs. The in-plane (or diaphragm strength and stiffness of the floor system are frequently utilized in the lateral load-resisting system design. This paper presents the results of an experimental research program in which four full size composite diaphragms were vertically loaded to the limit state, under static or dynamic loads. Two test specimens were provided with longitudinal steel-deck ribs, and the other two specimens with cross steel-deck ribs. Typical composite diaphragm limit states are described, and the controlling limit state for each of the full size tests is indicated. The interaction effects between the reinforced concrete slab and the steel girder on the composite slab strength and stiffness were mainly studied.

  9. The composite method: An improved method for stream-water solute load estimation

    Science.gov (United States)

    Aulenbach, Brent T.; Hooper, R.P.

    2006-01-01

    The composite method is an alternative method for estimating stream-water solute loads, combining aspects of two commonly used methods: the regression-model method (which is used by the composite method to predict variations in concentrations between collected samples) and a period-weighted approach (which is used by the composite method to apply the residual concentrations from the regression model over time). The extensive dataset collected at the outlet of the Panola Mountain Research Watershed (PMRW) near Atlanta, Georgia, USA, was used in data analyses for illustrative purposes. A bootstrap (subsampling) experiment (using the composite method and the PMRW dataset along with various fixed-interval and large storm sampling schemes) obtained load estimates for the 8-year study period with a magnitude of the bias of less than 1%, even for estimates that included the fewest number of samples. Precisions were always method load estimates varies depending on the variability in the regression-model residuals, how residuals systematically deviated from the regression model over time, sampling design, and the time interval of the load estimate. The regression-model method did not estimate loads precisely during shorter time intervals, from annually to monthly, because the model could not explain short-term patterns in the observed concentrations. Load estimates using the period-weighted approach typically are biased as a result of sampling distribution and are accurate only with extensive sampling. The formulation of the composite method facilitates exploration of patterns (trends) contained in the unmodelled portion of the load. Published in 2006 by John Wiley & Sons, Ltd.

  10. Influence of metal loading on hydrocracking of rapeseed oil using bifunctional micro-/mesoporous composite materials

    Energy Technology Data Exchange (ETDEWEB)

    Gille, T.; Busse, O.; Reschetilowski, W. [Technische Univ. Dresden (Germany). Inst. of Industrial Chemistry

    2013-11-01

    Hydrocracking of rapeseed oil has been investigated in a fixed bed reactor under integral conditions. A synthesized micro-/mesoporous composite material Al-MCM-41/ZSM-5 modified by different metal loadings (NiMo, PtNiMo, Pt) was used as catalyst system. It could be demonstrated that the support material and their metal loading influence the product selectivity as well as the deactivation tendencies of the catalyst sample. (orig.)

  11. Finite Element Analysis of Ultimate Load Capacity of Slender Concrete-Filled Steel Composite Columns

    OpenAIRE

    Alireza Bahrami; Wan Hamidon Wan Badaruzzaman; Siti Aminah Osman

    2011-01-01

    Ultimate load capacity of slender concrete-filled steel composite columns is investigated in this paper. Nonlinear analyses are done by the use of finite element software, LUSAS, to study the ultimate axial load behaviour of the columns. Verification of the finite element modelling is done by comparing the result with the corresponding experimental result reported by other researchers. Analyses are carried out to assess different shapes and number of cold-formed steel sheeting stiffeners with...

  12. Consolidation Theory for a Stone Column Composite Foundation under Multistage Loading

    OpenAIRE

    Shenggen Huang; Yingtao Feng; Hao Liu; Wenbing Wu; Guoxiong Mei

    2016-01-01

    The consolidation theories considering instant load cannot fully reveal the consolidation mechanism of a stone column composite foundation used in the expressway embankments due to the time effect of loading; that is, the expressway embankments are often constructed in several stages for a long time. Meanwhile, owing to the special property that the pile-soil stress ratio is larger than 1, the consolidation theory for sand drain well foundation cannot be used directly in the consolidation ana...

  13. Evaluation of flawed composite structural components under static and cyclic loading. [fatigue life of graphite-epoxy composite materials

    Science.gov (United States)

    Porter, T. R.

    1979-01-01

    The effects of initial defects on the fatigue and fracture response of graphite-epoxy composite laminates are presented. The structural laminates investigated were a typical angle ply laminate, a polar/hoop wound pressure vessel laminate, and a typical engine fan blade laminate. Defects investigated were full and half penetration circular holes, full and half penetration slits, and countersink holes. The effects of the defect size and type on the static fracture strength, fatigue performance, and residual static strength are shown as well as the results of loadings on damage propagation in composite laminates. The data obtained were used to define proof test levels as a qualification procedure in composite structure subjected to cyclic loading.

  14. Optimization Formulations for the Maximum Nonlinear Buckling Load of Composite Structures

    DEFF Research Database (Denmark)

    Lindgaard, Esben; Lund, Erik

    2011-01-01

    This paper focuses on criterion functions for gradient based optimization of the buckling load of laminated composite structures considering different types of buckling behaviour. A local criterion is developed, and is, together with a range of local and global criterion functions from literature......, benchmarked on a number of numerical examples of laminated composite structures for the maximization of the buckling load considering fiber angle design variables. The optimization formulations are based on either linear or geometrically nonlinear analysis and formulated as mathematical programming problems...

  15. Synthesis and photocatalytic activity of carbon spheres loaded Cu{sub 2}O/Cu composites

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yinhui, E-mail: lillian09281@hotmail.com; Zhao, Mengyao; Zhang, Na; Li, Ruijuan; Chen, Jianxin

    2015-09-15

    Highlights: • Carbon spheres loaded Cu{sub 2}O/Cu composites are obtained by hydrothermal process. • Cu{sub 2}O/Cu nanocrystals grow on the surface of carbon spheres. • The composites with core–shell structure show highly photo-catalytic activity. • The composites can degrade methyl orange under simulated solar light irradiation. • The composites can be used to treat dye wastewater or organic pollutants. - Abstract: In this work, using amylose as carbon source and cupric acetate as copper source, carbon spheres loaded Cu{sub 2}O/Cu composites were obtained by hydrothermal synthesis. The effects of the molar ratios between glucose and Cu(II), and hydrothermal time on the morphology and sizes of the composites were investigated. The result of photocatalytic experiments demonstrated that the composites could degrade methyl orange in aqueous solution under simulated solar light irradiation. The highest degradation rate was achieved to 93.83% when the composites were prepared by hydrothermal synthesis at 180 °C for 16 h and the molar ratio between glucose and Cu(II) was 10/1. The composites, as new and promising materials, can be used to treat dye wastewater or other organic pollutants.

  16. Buckling of Laminated Composite Stiffened Panels Subjected to Linearly Varying In-Plane Edge Loading

    Science.gov (United States)

    Mallela, Upendra K.; Upadhyay, Akhil

    2014-01-01

    The presence of in-plane loading may cause buckling of stiffened panels. An accurate knowledge of critical buckling load and mode shapes is essential for reliable and lightweight structural design. This paper presents parametric studies on simply supported laminated composite blade-stiffened panels subjected to linearly varying in-plane edge/compressive loading. Studies are carried out by changing the panel orthotropy ratio, stiffener depth, pitch length (number of stiffeners), smeared extensional stiffness ratio of stiffener to that of the plate and load distribution parameter. Based on the studies, a few important parameters influencing the buckling behavior are identified and their significance is discussed. Further, the interaction equations for combined loadings are validated by carrying out numerical studies.

  17. DELAMINATION FORMATION AND DELAMINATION PROPAGATION OF COMPOSITE LAMINATES UNDER COMPRESSIVE FATIGUE LOADING

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Fatigue tests of the smooth composite laminates and the notched composite laminates under compressive cyclic loading have been carried out. The damage mechanism is discussed and analyzed. Damage evolution is monitored using stiffness decay. From these tests, it is found that the initial delamination occurs at the free boundary of smooth specimens, or the notch boundary of notched specimens, subjected to the compression-compression cyclic load. A point of view in relation to two-phases of compression fatigue delamination of composites is proposed, namely, compression-compression delamination consists of the delamination formation phase and the delamination propagation, and there is a "damage transition point" to separate this two-phases. Furthermore, an empirical modulus degradation formula and its parameters fitting method are presented. According to the test data handling results, it is shown that this formula is univocal and can fit the test data conveniently. In addition, two kinds of new anti-buckling devices are designed for these tests. At last, the E-N curves, the D-N curves and the S-N curve of the smooth carbon fiber reinforced composite laminates of T300/648C are determined to predict the fatigue life of the notched composite laminate. And the E-N curve of the notched specimens at the given load ratio R=10 and minimum load P min=-0.45 kN is also measured to verify the estimated result of fatigue life.

  18. Self-Sensing of Damage Progression in Unidirectional Multiscale Hierarchical Composites Subjected to Cyclic Tensile Loading

    Science.gov (United States)

    Ku-Herrera, J. J.; Pacheco-Salazar, O. F.; Ríos-Soberanis, C. R.; Domínguez-Rodríguez, G.; Avilés, F.

    2016-01-01

    The electrical sensitivity of glass fiber/multiwall carbon nanotube/vinyl ester hierarchical composites containing a tailored electrically-percolated network to self-sense accumulation of structural damage when subjected to cyclic tensile loading-unloading is investigated. The hierarchical composites were designed to contain two architectures differentiated by the location of the multiwall carbon nanotubes (MWCNTs), viz. MWCNTs deposited on the fibers and MWCNTs dispersed within the matrix. The changes in electrical resistance of the hierarchical composites are associated to their structural damage and correlated to acoustic emissions. The results show that such tailored hierarchical composites are able to self-sense damage onset and accumulation upon tensile loading-unloading cycles by means of their electrical response, and that the electrical response depends on the MWCNT location. PMID:26999158

  19. Self-Sensing of Damage Progression in Unidirectional Multiscale Hierarchical Composites Subjected to Cyclic Tensile Loading.

    Science.gov (United States)

    Ku-Herrera, J J; Pacheco-Salazar, O F; Ríos-Soberanis, C R; Domínguez-Rodríguez, G; Avilés, F

    2016-01-01

    The electrical sensitivity of glass fiber/multiwall carbon nanotube/vinyl ester hierarchical composites containing a tailored electrically-percolated network to self-sense accumulation of structural damage when subjected to cyclic tensile loading-unloading is investigated. The hierarchical composites were designed to contain two architectures differentiated by the location of the multiwall carbon nanotubes (MWCNTs), viz. MWCNTs deposited on the fibers and MWCNTs dispersed within the matrix. The changes in electrical resistance of the hierarchical composites are associated to their structural damage and correlated to acoustic emissions. The results show that such tailored hierarchical composites are able to self-sense damage onset and accumulation upon tensile loading-unloading cycles by means of their electrical response, and that the electrical response depends on the MWCNT location.

  20. Self-Sensing of Damage Progression in Unidirectional Multiscale Hierarchical Composites Subjected to Cyclic Tensile Loading.

    Science.gov (United States)

    Ku-Herrera, J J; Pacheco-Salazar, O F; Ríos-Soberanis, C R; Domínguez-Rodríguez, G; Avilés, F

    2016-01-01

    The electrical sensitivity of glass fiber/multiwall carbon nanotube/vinyl ester hierarchical composites containing a tailored electrically-percolated network to self-sense accumulation of structural damage when subjected to cyclic tensile loading-unloading is investigated. The hierarchical composites were designed to contain two architectures differentiated by the location of the multiwall carbon nanotubes (MWCNTs), viz. MWCNTs deposited on the fibers and MWCNTs dispersed within the matrix. The changes in electrical resistance of the hierarchical composites are associated to their structural damage and correlated to acoustic emissions. The results show that such tailored hierarchical composites are able to self-sense damage onset and accumulation upon tensile loading-unloading cycles by means of their electrical response, and that the electrical response depends on the MWCNT location. PMID:26999158

  1. Self-Sensing of Damage Progression in Unidirectional Multiscale Hierarchical Composites Subjected to Cyclic Tensile Loading

    Directory of Open Access Journals (Sweden)

    J. J. Ku-Herrera

    2016-03-01

    Full Text Available The electrical sensitivity of glass fiber/multiwall carbon nanotube/vinyl ester hierarchical composites containing a tailored electrically-percolated network to self-sense accumulation of structural damage when subjected to cyclic tensile loading-unloading is investigated. The hierarchical composites were designed to contain two architectures differentiated by the location of the multiwall carbon nanotubes (MWCNTs, viz. MWCNTs deposited on the fibers and MWCNTs dispersed within the matrix. The changes in electrical resistance of the hierarchical composites are associated to their structural damage and correlated to acoustic emissions. The results show that such tailored hierarchical composites are able to self-sense damage onset and accumulation upon tensile loading-unloading cycles by means of their electrical response, and that the electrical response depends on the MWCNT location.

  2. TENSILE AND FLEXURAL STUDIES ON GLASS - CARBON HYBRID COMPOSITES SUBJECTED TO LOW FREQUENCY CYCLIC LOADING

    Directory of Open Access Journals (Sweden)

    K. Poyyathappan

    2014-03-01

    Full Text Available Glass fiber reinforced polymeric composite (GFRP, Carbon fiber reinforced polymeric composite (CFRP, glass-carbon-glass, carbon-glass-carbon hybrid composite laminates have been prepared by hand layup method. The test specimens have been prepared according to ASTM standard size to carry out the tensile and flexural tests. Six specimens with 0±90° orientation have been prepared for both the tests. The specimens have been subjected to low frequency cyclic load for specific duration prior to the flexural bending analysis. Three point bend method has been adopted to find out the flexural strength and flexural modulus. Flexural strength and modulus have been calculated from the load deflection curve obtained from the tensometer for respective specimens. The results show that the hybrid composites have better flexural properties than the GFRP.

  3. Hyperbranched urethane-acrylates

    Directory of Open Access Journals (Sweden)

    Tasić Srba

    2004-01-01

    Full Text Available The synthesis, characterization and UV-curing of hyperbranched urethaneacrylates (HB-UA were investigated in this study. They were evaluated as oli-gomers in model UV curable coatings. HB-UAs were synthesized by reaction of an aliphatic hyperbranched polyester of the second generation (HBRG2 and an isocyanate adduct, obtained by the reaction of isophoronediisocyana-te and different hydroxy alkyl acrylates. Their thermal properties and viscosities depend on the degree of modification of HBRG2 and the type of hydroxy alkyl acrylate used. The introduction of a flexible alkoxylated spacer between the HBP core and acrylate end groups reduces steric hindrance by moving the cross linkable acrylate groups away from the HBP core and increase its reactivity. Due to the presence of abstractable H-atoms in the α-position to the ether links, HB-UAs based on poly(ethylene oxide monoacrylate are very reactive and do not show oxygen inhibition. The obtained coatings combine a high cross linking density with flexible segments between the cross links, which results in a good compromise between hardness and flexibility and have the potential to be used in different UV-curing applications.

  4. Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites

    Science.gov (United States)

    Qian, D.; Dickey, E. C.; Andrews, R.; Rantell, T.

    2000-05-01

    Multiwall carbon nanotubes have been dispersed homogeneously throughout polystyrene matrices by a simple solution-evaporation method without destroying the integrity of the nanotubes. Tensile tests on composite films show that 1 wt % nanotube additions result in 36%-42% and ˜25% increases in elastic modulus and break stress, respectively, indicating significant load transfer across the nanotube-matrix interface. In situ transmission electron microscopy studies provided information regarding composite deformation mechanisms and interfacial bonding between the multiwall nanotubes and polymer matrix.

  5. Self-Sensing of Damage Progression in Unidirectional Multiscale Hierarchical Composites Subjected to Cyclic Tensile Loading

    OpenAIRE

    Ku-Herrera, J. J.; Pacheco-Salazar, O. F.; Ríos-Soberanis, C. R.; G. Domínguez-Rodríguez; Avilés, F.

    2016-01-01

    The electrical sensitivity of glass fiber/multiwall carbon nanotube/vinyl ester hierarchical composites containing a tailored electrically-percolated network to self-sense accumulation of structural damage when subjected to cyclic tensile loading-unloading is investigated. The hierarchical composites were designed to contain two architectures differentiated by the location of the multiwall carbon nanotubes (MWCNTs), viz. MWCNTs deposited on the fibers and MWCNTs dispersed within the matrix. T...

  6. Finite element analysis of composite tubes with integral ends subjected to bending loads

    OpenAIRE

    Adams, Michael B.

    1995-01-01

    An analytical investigation was perfonned to study the effect of applied bending loads on laminated composite tubes. Elasticity-based linear models were developed using finite element software to predict stresses within the individual plies of the tubes. The tubes under investigation were graphite/epoxy laminated composites with a stacking sequence of [0/-45/+45/90/90/+45/ -45/0] X 2 (Sixteen plies per tube). End pieces of isotropic titanium were integrally constructed with bon...

  7. Finite Element Analysis of Composite Hardened Walls Subjected to Blast Loads

    OpenAIRE

    Girum S. Urgessa

    2009-01-01

    Problem statement: There is currently no standard design guideline to determine the number of composites needed to retrofit masonry walls in order to withstand a given explosion. Past design approaches were mainly based on simplified single-degree-of-freedom analysis. A finite element analysis was conducted for concrete masonry walls hardened with composites and subjected to short duration blast loads. Approach: The analysis focused on displacement time history responses which form the basis ...

  8. Study of the damaging mechanisms of a copper / carbon - carbon composite under thermomechanical loading

    International Nuclear Information System (INIS)

    The purpose of this work is to understand and to identify the damaging mechanisms of Carbon-Carbon composite bonded to copper under thermomechanical loading. The study of the composite allowed the development of non-linear models. These ones have been introduced in the finite elements analysis code named CASTEM2000. They have been validated according to a correlation between simulation and mechanical tests on multi-material samples. These tests have also permitted us to better understand the behaviour of the bonding between composite and copper (damaging and fracture modes for different temperatures) under shear and tensile loadings. The damaging mechanisms of the bond under thermomechanical loading have been studied and identified according to microscopic observations on mock-ups which have sustained thermal cycling tests: some cracks appear in the composite, near the bond between the composite and the copper. The correlation between numerical and experimental results have been improved because of the reliability of the composite modelization, the use of residual stresses and the results of the bond mechanical characterization. (author)

  9. Enhanced photocatalytic activity of fish scale loaded TiO2 composites under solar light irradiation

    Institute of Scientific and Technical Information of China (English)

    Li-Ngee Ho; Soon-An Ong; Hakimah Osman; Fong-Mun Chong

    2012-01-01

    Fish scale (FS) loaded TiO2 composites were investigated as photocatalysts in degradation of Methyl Orange under solar light irradiation.Composites were prepared through sol-gel method by varying mass ratio of TiO2/FS at 90:10,70:30 and 50:50,respectively.The catalysts prepared in this study were characterized by using XRD,SEM,FT-IR and nitrogen sorption.The effects of solar irradiation,mass ratio of TiO2/FS composites,irradiation time and catalyst loadings were studied.Synergistic effect was found in TiO2/FS of 90:10 composite which performed higher photocatalytic degradation than synthesized TiO2 under solar light irradiation.However,further increasing fish scale content in the composites reduced the photocatalytic activity drastically.Under solar light irradiation,all the catalysts in this study exhibited photocatalytic activity,except TiO2/FS of 50:50 composite that only acted as a weak biosorbent without performing any photocatalytic property.Photocatalytic degradation increased with increasing catalyst loading and irradiation time but decreased with increased of initial dye concentration.

  10. Study of the damaging mechanisms of a carbon - carbon composite bonded to copper under thermomechanical loading

    International Nuclear Information System (INIS)

    The purpose of this work is to understand and to identify the damaging mechanisms of Carbon-Carbon composite bonded to copper under thermomechanical loading. The study of the composite allowed the development of non-linear models. These ones have been introduced in the finite elements analysis code named CASTEM 2000. They have been validated according to a correlation between simulation and mechanical tests on multi-material samples. These tests have also permitted us to better understand the behaviour of the bonding between composite and copper (damaging and fracture modes for different temperatures) under shear and tensile loadings. The damaging mechanisms of the bond under thermomechanical loading have been studied and identified according to microscopic observations on mock-ups which have sustained thermal cycling tests: some cracks appear in the composite, near the bond between the composite and the copper. The correlation between numerical and experimental results have been improved because of the reliability of the composite modelization, the use of residual stresses and the results of the bond mechanical characterisation. (author)

  11. Effect of Nanoclay on Thermal Conductivity and Flexural Strength of Polymethyl Methacrylate Acrylic Resin

    OpenAIRE

    Tahereh Ghaffari; Ali Barzegar; Fahimeh Hamedi Rad; Elnaz Moslehifard

    2016-01-01

    Statement of the Problem: The mechanical and thermal properties of polymethyl methacrylate (PMMA) acrylic resin should be improved to counterweigh its structural deficiencies. Purpose: The aim of this study was to compare the flexural strength and thermal conductivity of conventional acrylic resin and acrylic resin loaded with nanoclay. Materials and Method: The methacrylate monomer containing the 0.5, 1 and 2 wt% of nanoclay was placed in an ultrasonic probe and mixed with the PMMA p...

  12. Behavior of plywood and fiberglass steel composite tube structures subjected to impact loading

    Science.gov (United States)

    Armaghani, Seyamend Bilind

    Paratransit buses are custom built as the major vehicle manufacturer produces the custom built passenger cage installed on the chassis for the Paratransit bus. In order for these Paratransit bus members to be sufficient, they have to be evaluated for crashworthiness and energy absorption. This has prompted Florida Department of Transportation (FDOT) to fund research for the safety evaluation of Paratransit busses consisting of crash and safety analysis. There has been a large body of research done on steel subjected to static loads, but more research is needed for steel applied under dynamic loading and high speeds in order to improve crashworthiness in events such as rollovers and side impacts. Bare steel Hollow Structural Section (HSS) tubing are used a lot as structural members of Paratransit buses because of their lightness and progressive buckling under loading. The research will be conducted on quantifying the tubing's behavior under bending by conducting static three point bending and impact loading tests. In addition to the bare tubing, plywood and fiberglass composites are investigated because they are both strong and lightweight and their behavior under dynamic loading hasn't been quantified. As a result, the main purpose of this research is to quantify the differences between the dynamic and static behavior of plywood steel composite and fiberglass steel composite tubing and compare these findings with those of bare steel tubing. The differences will be quantified using detailed and thorough experiments that will examine the composites behavior under both static and dynamic loading. These tests will determine if there are any advantages of using the composite materials and thus allow for recommendations to be made to the FDOT with the goal of improving the safety of Paratransit busses. Tensile tests were conducted to determine the material properties of the tested specimens. Before the static and dynamic experiments are run to investigate the differences

  13. Interface debond crack growth in tension–tension cyclic loading of single fiber polymer composites

    DEFF Research Database (Denmark)

    Pupurs, Andrejs; Goutianos, Stergios; Brøndsted, Povl;

    2013-01-01

    Fiber/matrix interface debond crack growth from a fiber break is defined as one of the key mechanisms of fatigue damage in unidirectional composites. Considering debond as an interface crack its growth in cyclic loading is analyzed utilizing a power law, where the debond growth rate is a power fu...

  14. A micromechanical study of porous composites under longitudinal shear and transverse normal loading

    DEFF Research Database (Denmark)

    Ashouri Vajari, Danial

    2015-01-01

    The mechanical response of porous unidirectional composites under transverse normal and longitudinal shear loading is studied using the finite element analysis. The 3D model includes discrete and random distribution of fibers and voids. The micromechanical failure mechanisms are taken into accoun...

  15. Reliability Analysis for Adhesive Bonded Composite Stepped Lap Joints Loaded in Fatigue

    DEFF Research Database (Denmark)

    Kimiaeifar, Amin; Sørensen, John Dalsgaard; Lund, Erik;

    2012-01-01

    This paper describes a probabilistic approach to calculate the reliability of adhesive bonded composite stepped lap joints loaded in fatigue using three- dimensional finite element analysis (FEA). A method for progressive damage modelling is used to assess fatigue damage accumulation and residual...

  16. INTERFACIAL DEBONDING OF COATED-FIBER-REINFORCED COMPOSITES UNDER TENSION-TENSION CYCLIC LOADING

    Institute of Scientific and Technical Information of China (English)

    Shi Zhifei; Zhou Limin

    2000-01-01

    A new degradation function of the friction coefficient is used. Based on the double shear-lag model and Paris formula, the interfacial damage of coated fiber-reinforced composites under tension-tension cyclic loading is studied. The effects of strength and thickness of the coating materials on the debond stress, debond rate as well as debond length are simulated.

  17. Load-induced debonding of FRP composites applied to reinforced concrete

    Science.gov (United States)

    Blok, Joel; Brown, Jeff

    2009-05-01

    Fiber-reinforced polymer (FRP) composites are widely used to increase the flexural and shear capacity of reinforced concrete (RC) elements. One potential disadvantage is that strengthened surfaces are no longer visible and cracks or delaminations that result from excessive loading or fatigue may go undetected. This research investigated thermal imaging techniques for monitoring and evaluating load-induced delamination of FRP composites applied to small scale RC beams. Two beams (3.5 in x 4.5 in x 58 in) were loaded monotonically to failure. Infrared thermography (IRT) inspections were performed at various load levels through failure using a composite phase imaging technique. Two similar beams were tested in fatigue and periodic IRT inspections were performed at 50,000-cycle intervals. Individual phase values for each pixel were designated as "well-bonded", "suspect" or "unbonded" to indicate the quality of FRP bond. Suspect areas included regions of excess thickened-epoxy tack-coat and smaller installation defects in the unloaded specimens. The long-term objective of this research is to develop a practical framework for conducting quantitative IRT inspections of FRP composites applied to RC and incorporating these results into acceptance criteria for new installations and predictions for the remaining service life of in-service FRP systems. This method may also offer insight into the necessity for repairs to in-service systems.

  18. Discrete Meso-Element Simulation of Failure Behavior of Short-Fiber Composites under Shock Loading

    Science.gov (United States)

    Tang, Z. P.; Liu, Wenyan; Liu, Yunxin

    1999-06-01

    Recent years, it was paid more attention to better understanding the failure behavior and mechanism of heterogeneous materials at meso- scale level. In this paper, the crack initiation and development in epoxy composite reinforced with short steel fibre under dynamic loading were simulated and analyzed with 2D Discrete Meso-Element Dynamic Method. Results show that cracks initiate at the tips of fibres on the Loading side where stress concentrates. The effective strength of the composite sample is related to shape, orientation, weight percentage of the fibres, and particularly, the bonding strength between fibre and matrix. In the case of low bonding strength, the crack will propagate along the fibre and finally penetrate the whole sample. The differences compared with static loading are also discussed.

  19. The relationship of compliance changes during fatigue loading to the fracture of composite materials

    Science.gov (United States)

    Reifsnider, K. L.; Highsmith, A.

    1982-01-01

    The study outlined here is based on measurements of the change in engineering stiffness values induced by the development of damage in composite laminates during quasi-static or cyclic (fatigue) loading. These changes are found to be related to the individual details of the damage events in the laminates, as well as to the residual strength and life of the laminates. It is believed that the stiffness changes can also be used to relate composite material behavior under cyclic loading to its behavior under quasi-static loading. Results are presented for both notched and unnotched laminates. Compliance changes are found to be caused by damage events that bring about both global and local redistributions of stress. It is also found that the redistributions of stress determine the residual strength of the laminate. The quantitative link between compliance changes and fracture strength is the mechanics of the internal stress redistributions.

  20. A test method to measure the response of composite materials under reversed cyclic loads

    Science.gov (United States)

    Bakis, Charles E.; Simonds, Robert A.; Stinchcomb, Wayne W.

    1989-01-01

    A test method to measure the response of composite materials under reversed cyclic loads is described. The method approximates the long-term response of a component by permitting the composite specimen to respond to the imposed loads and fail in an unconstrained mode rather than in a constrained mode. The method has been successfully used for the reversed cyclic loading of unnotched and notched graphite/epoxy and graphite/PEEK laminates of various stacking sequences. Included in the paper are monotonic tensile and compressive stiffness and strength data at several points in the fatigue lifetime, and damage development information obtained via X-ray radiography for quasi-isotropic T300/5208 and AS4/PEEK laminates with unloaded circular holes.

  1. STATIC AND FATIGUE BEHAVIOR OF IMPACTED AS4/PEEK THERMOPLASTIC COMPOSITES UNDER COMPRESSION LOAD

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Static and fatigue tests under compression load were made on impacted AS4/PEEK and T300/913C graphite/epoxy with [45/90/-45/0]5S stacking sequence. The comparison of the damage tolerance assessment for thermosetting and thermoplastic composites shows that thermoplastics are more damage tolerant under compression. Impacted thermoplastic composites have excellent compression-compression fatigue behavior. The damage growth life is only a few percent of their total fatigue life and no regular damage growth can be found. Some design principles for thermosetting composite structures may still be used.

  2. Testing and Analysis of Composite Skin/Stringer Debonding Under Multi-Axial Loading

    Science.gov (United States)

    Krueger, Ronald; Cvitkovich, Michael K.; O'Brien, T. Kevin; Minguet, Pierre J.

    2000-01-01

    A consistent step-wise approach is presented to investigate the damage mechanism in composite bonded skin/stringer constructions under uniaxial and biaxial (in-plane/out-of-plane) loading conditions. The approach uses experiments to detect the failure mechanism, computational stress analysis to determine the location of first matrix cracking and computational fracture mechanics to investigate the potential for delamination growth. In a first step, tests were performed on specimens, which consisted of a tapered composite flange, representing a stringer or frame, bonded onto a composite skin. Tests were performed under monotonic loading conditions in tension, three-point bending, and combined tension/bending to evaluate the debonding mechanisms between the skin and the bonded stringer. For combined tension/bending testing, a unique servohydraulic load frame was used that was capable of applying both in-plane tension and out-of-plane bending loads simultaneously. Specimen edges were examined on the microscope to document the damage occurrence and to identify typical damage patterns. For all three load cases, observed failure initiated in the flange, near the flange tip, causing the flange to almost fully debond from skin. In a second step, a two dimensional plane-strain finite element model was developed to analyze the different test cases using a geometrically nonlinear solution. For all three loading conditions, computed principal stresses exceeded the transverse strength of the material in those areas of the flange where the matrix cracks had developed during the tests. In a third step, delaminations of various lengths were simulated in two locations where delaminations were observed during the tests. The analyses showed that at the loads corresponding to matrix ply crack initiation computed strain energy release rates exceeded the values obtained from a mixed mode failure criterion in one location, Hence. Unstable delamination propagation is likely to occur as

  3. Onset of failure in finitely strained layered composites subjected to combined normal and shear loading

    Science.gov (United States)

    Nestorović, M. D.; Triantafyllidis, N.

    2004-04-01

    A limiting factor in the design of fiber-reinforced composites is their failure under axial compression along the fiber direction. These critical axial stresses are significantly reduced in the presence of shear stresses. This investigation is motivated by the desire to study the onset of failure in fiber-reinforced composites under arbitrary multi-axial loading and in the absence of the experimentally inevitable imperfections and finite boundaries. By using a finite strain continuum mechanics formulation for the bifurcation (buckling) problem of a rate-independent, perfectly periodic (layered) solid of infinite extent, we are able to study the influence of load orientation, material properties and fiber volume fraction on the onset of instability in fiber-reinforced composites. Two applications of the general theory are presented in detail, one for a finitely strained elastic rubber composite and another for a graphite-epoxy composite, whose constitutive properties have been determined experimentally. For the latter case, extensive comparisons are made between the predictions of our general theory and the available experimental results as well as to the existing approximate structural theories. It is found that the load orientation, material properties and fiber volume fraction have substantial effects on the onset of failure stresses as well as on the type of the corresponding mode (local or global).

  4. STACKING SEQUENCE OPTIMIZATION OF LAMINATED COMPOSITE CYLINDER SHELL FOR MAXIMAL BUCKLING LOAD

    Institute of Scientific and Technical Information of China (English)

    TANG Qian; LIAO Xiaoyun; GAO Zhan

    2008-01-01

    A new optimization method for the optimization of stacking of composite glass fiber laminates is developed. The fiber orientation and angle of the layers of the cylindrical shells are sought considering the buckling load. The proposed optimization algorithm applies both finite element analysis and the mode-pursuing sampling (MPS)method. The algorithms suggest the optimal stacking sequence for achieving the maximal buckling load. The procedure is implemented by integrating ANSYS and MATLAB. The stacking sequence designing for the symmetric angle-ply three-layered and five-layered composite cylinder shells is presented to illustrate the optimization process, respectively. Compared with the genetic algorithms, the proposed optimization method is much faster and efficient for composite staking sequence plan.

  5. Effects of nanosized metallic palladium loading and calcination on characteristics of composite silica

    Institute of Scientific and Technical Information of China (English)

    吴玉程; 吴侠; 李广海; 张立德

    2003-01-01

    In order to investigate the effects of nanosized metallic palladium loading and calcination on the characteristics of composite silica,the silica was prepared by sol-gel technique,leading to an amorphous solid with mesoporosity,and the pore size distribution is narrow,centered at 3-5 nm.The composite silica was formed by impregnating palladium precursor into the porous network with sequel calcination in hydrogen.The results show that the nanosized palladium as guest phase in the composite silica is subjected to the mesoporous structure and calcination,resulting in the changes of optical adsorption that red-shifted to higher wavelength with the palladium loading and the heating temperature.The tailoring of the optical properties can be ascribed to the effect of the nanosized metal particles and interactions occurred between palladium and silica.

  6. FT-IR and FT-Raman studies of cross-linking processes with Ca2+ ions, glutaraldehyde and microwave radiation for polymer composition of poly(acrylic acid)/sodium salt of carboxymethyl starch - Part I

    Science.gov (United States)

    Grabowska, Beata; Sitarz, Maciej; Olejnik, Ewa; Kaczmarska, Karolina

    2015-01-01

    FT-IR and FT-Raman spectroscopic methods allowed to identify the cross-linking process of the aqueous composition of poly(acrylic acid)/sodium salt of carboxymethyl starch (PAA/CMS-Na) applied as a binder for moulding sands. The cross-linking was performed by chemical methods by introducing cross-linking substances with Ca2+ ions or glutaraldehyde and by physical way, applying the microwave radiation. It was found that Ca2+ ions cause formation of cross-linking ionic bonds within carboxyl and carboxylate groups. Glutaraldehyde generates formation of cross-linking bonds with hemiacetal and acetal structures. Whereas in the microwave radiation field, due to dehydration, lattices are formed by anhydride bonds.

  7. Prediction of Spring Rate and Initial Failure Load due to Material Properties of Composite Leaf Spring

    Energy Technology Data Exchange (ETDEWEB)

    Oh, Sung Ha [Maxoft Inc., Seongnam (Korea, Republic of); Choi, Bok Lok [Gangneung-Wonju National University, Gangneung (Korea, Republic of)

    2014-12-15

    This paper presented analysis methods for adapting E-glass fiber/epoxy composite (GFRP) materials to an automotive leaf spring. It focused on the static behaviors of the leaf spring due to the material composition and its fiber orientation. The material properties of the GFRP composite were directly measured based on the ASTM standard test. A reverse implementation was performed to obtain the complete set of in-situ fiber and matrix properties from the ply test results. Next, the spring rates of the composite leaf spring were examined according to the variation of material parameters such as the fiber angles and resin contents of the composite material. Finally, progressive failure analysis was conducted to identify the initial failure load by means of an elastic stress analysis and specific damage criteria. As a result, it was found that damage first occurred along the edge of the leaf spring owing to the shear stresses.

  8. Modelling of Fiber/Matrix Debonding of Composites Under Cyclic Loading

    Science.gov (United States)

    Naghipour, Paria; Pineda, Evan J.; Bednarcyk, Brett A.; Arnold, Steven M.

    2013-01-01

    The micromechanics theory, generalized method of cells (GMC), was employed to simulate the debonding of fiber/matrix interfaces, within a repeating unit cell subjected to global, cyclic loading, utilizing a cyclic crack growth law. Cycle dependent, interfacial debonding was implemented as a new module to the available GMC formulation. The degradation of interfacial stresses, with applied load cycles, was achieved via progressive evolution of the interfacial compliance. A periodic repeating unit cell, representing the fiber/matrix architecture of a composite, was subjected to combined normal and shear loadings, and degradation of the global transverse stress in successive cycles was monitored. The obtained results were compared to values from a corresponding finite element model. Reasonable agreement was achieved for combined normal and shear loading conditions, with minimal variation for pure loading cases. The local effects of interfacial debonding, and fatigue damage will later be combined as sub-models to predict the experimentally obtained fatigue life of Ti-15-3/Sic composites at the laminate level.

  9. A Numerical and Experimental Study of Compression-Loaded Composite Panels With Cutouts

    Science.gov (United States)

    Thornburgh, Robert P.; Hilburger, Mark W.

    2006-01-01

    Results from a numerical and experimental study on the effects of laminate orthotropy and circular cutout size on the response of compression-loaded composite curved panels are presented. Several 60-in-radius composite panels with four different laminate configurations were tested with cutout diameters that range from 10% to 60% of the panel width. Finite-element analyses were performed for each panel in order to identify the effects boundary conditions, measured initial geometric imperfections and thickness variations had on the nonlinear and buckling behavior of the panels. The compression-loaded panels considered herein exhibited two separate types of behavior depending on the laminate stacking sequence and cutout size. More specifically, some of the panels exhibited the classical snap-through type buckling response; however, some of the panels exhibited a monotonically increasing stable response and achieved compressive loads in excess of twice the predicted linear bifurcation buckling load. In general, the finite-element analyses were able to predict accurately the nonlinear response and buckling loads of the panels and the prebuckling and postbuckling out-of-plane deformations and strains.

  10. Calculation method of composite foundation sedimentation of grouting pile with cover plate under embankment load

    Institute of Scientific and Technical Information of China (English)

    顾长存; 洪昌地; 马文彬; 李雪平

    2008-01-01

    Grouting pile is a new soft soil foundation treatment method with characteristics such as no vibration, no noise, no soil compaction, light construction machines and quick construction velocity and so on. At present, study on reinforcement mechanism and design calculation method of composite foundation of grouting pile is initially started without design specifications, so it is usually required to draw on design specifications of stump pile when designing composite foundation of grouting pile while grouting pile has its characteristics and difference although reinforcement mechanisms and construction processes of two types of piles are similar. Sedimentation formula of composite foundation of grouting pile with cover plate is educed and a suitable deformation mode is proposed by aiming to deformation characteristics of composite foundation of grouting pile with cover plate under embankment load on basis of relevant sedimentation theories of composite foundation by combination of characteristics of composite foundation of grouting pile. The sedimentation calculation formula of grouting pile with cover plate under embankment load is educed according to balance relation of force and displacement coordination conditions by elastic theory and sedimentation calculation model established is validated by sedimentation monitoring documents of one expressway in China.

  11. Relationship between the Composition of Polymer of n-Alkyl Substituted Acrylate and Vinyl Amine and Their Performance on Pour Point Depression

    Institute of Scientific and Technical Information of China (English)

    Jiang Qingzhe; Luo Fangmin; Song Zhaozheng; Ke Ming

    2005-01-01

    Polymer of n-alkyl substituted acrylate (PA) with the alkyl side chains C16- 30 were synthesized.Their crystallinity, solubility and effect on pour point depression were studied. Results showed that only carbon atoms located far away from polar groups of PA pour point depressants participated in crystallization.When the number of carbon atoms that participated in crystallization is about three fourths of the average carbon number of wax in crude, the effect of PA is the best. The molecular weight distribution of PA pour point depressant has little influence on the effect of pour point depression, and the average molecular weight of PA in the range of (1.5- 2.2)× 104 shows the best effect. The introduction of polar groups into the molecule of PA can improve its performance. However, a too high content of polar groups in PA would cause deterioration, and even lead to loss of PA's performance for pour point depression.

  12. Regularity of acoustic radiation at ascending load on a pair of friction from a composite material

    Directory of Open Access Journals (Sweden)

    С. Ф. Філоненко

    2013-07-01

    Full Text Available In this article the simulation the results of acoustic emission signals formed by friction surfaces with composite materials at load increasing were showed. The results showed that at increase of axial load increases the amplitude of the resulting parameters of acoustic emission signals, such as the average amplitude, its standard deviation and variance. Thus were obtained the basic changes of amplitude parameters generated signals. Was determined that the variation of the percentage increase in the average amplitude, its standard deviation and variance were  the same type of character, with well approximate by linear functions. The results showed that with growing of axial load the percent increase in average amplitude of the resulting acoustic emission signals. Also, an analysis of the energy parameters of acoustic emission with increasing axial load on the friction pair with composite materials was conducted. The simulation results showed that the percentage increase in the average level of energy and its standard deviation are approximate by linear functions. At the same time the greatest percentage increase with increasing axial load on the friction pair is observed in the dispersion of the average energy of the resulting acoustic emission signals. The results showed that at experimental study of the acoustic emission signals with increasing axial load on the friction pair with composite materials greatest growth is expected in the average amplitude of the resulting AE signals. The growth of its standard deviation and variance will be not significant. At the same time, the greatest growth is expected in the dispersion of the average energy of acoustic emission signals

  13. Effect of organic loading rate and feedstock composition on foaming in manure-based biogas reactors

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; Angelidaki, Irini

    2013-01-01

    Foaming is one of the major problems that occasionally occur in biogas plants, affecting negatively the overall digestion process. In the present study, the effect of organic loading rate (OLR) and feedstock composition on foaming was elucidated in continuous reactor experiments. By stepwise...... increasing the OLR and the concentration of proteins or lipids in the substrate, foaming in biogas reactors was investigated. No foam formation was observed at the OLR of 3.5. g volatile solids/(L-reactor·day). Organic loading was the main factor affecting foam formation in manure digester, while the organic...

  14. Dynamic stability of simply supported composite cylindrical shells under partial axial loading

    Science.gov (United States)

    Dey, Tanish; Ramachandra, L. S.

    2015-09-01

    The parametric vibration of a simply supported composite circular cylindrical shell under periodic partial edge loadings is discussed in this article. Donnell's nonlinear shallow shell theory considering first order shear deformation theory is used to model the shell. The applied partial edge loading is represented in terms of a Fourier series and stress distributions within the cylindrical shell are determined by prebuckling analysis. The governing equations of the dynamic instability of shells are derived in terms of displacements (u-v-w) and rotations (φx, φθ). Employing the Galerkin and Bolotin methods the dynamic instability regions are computed. Using the expression for the stress function derived in this paper, the pre-buckling stresses in the cylindrical shell due to partial loading can be calculated explicitly. Numerical results are presented to show the influence of radius-to-thickness ratio, different partial edge loading distributions and shear deformation on the dynamic instability regions. The linear and nonlinear responses in the stable and unstable regions are presented to bring out the characteristic features of the dynamic instability regions, such as the existence of beats, its dependence on forcing frequency and effect of nonlinearity on the response. The effect of dynamic load amplitude on the nonlinear response is also studied. It is found that for higher values of dynamic loading, the shell exhibits chaotic behavior.

  15. Monotonic and fatigue properties of kenaf /glass hybrid composites under fully reversed cyclic loading

    Science.gov (United States)

    Sharba, M. J.; Leman, Z.; Sultan, M. T. H.; Ishak, M. R.; Hanim, M. A. A.

    2015-12-01

    The aim of this work is to investigate the effect of hybridization of kenaf-glass fibers reinforced unsaturated polyester on fatigue life. Three types of composites were fabricated using hands lay-up method, namely, kenaf, glass, and hybrid composites with 30% of weight fraction, the hybrid was mixed with a ratio of kenaf: glass 10:20. Monotonic tests were achieved (Tensile and compression) to determine the fatigue stress levels. Fully reversed fatigue loading was conducted with a stress ratio of -1 and stress levels 55-85% of the ultimate static stresses, all tests were conducted at 10 Hz of frequency. The results proof a positive hybrid composite; also agree with the rule of mixture that can predict the final composite properties. Moreover, it's been observed an improvement in overall mechanical properties of hybrid compared to individual ones.

  16. Conductivity of microfibrillar polymer-polymer composites with CNT-loaded microfibrils or compatibilizer: A comparative study

    OpenAIRE

    Fakirov, S.; S. M. Panamoottil; P. Potschke; R. J. T. Lin; Bhattacharyya, D

    2013-01-01

    Conductive polymer composites have wide ranging applications, but when they are produced by conventional melt blending, high conductive filler loadings are normally required, hindering their processability and reducing mechanical properties. In this study, two types of polymer-polymer composites were studied: i) microfibrillar composites (MFC) of polypropylene (PP) and 5 wt% carbon nanotube (CNT) loaded poly(butylene terephthalate) (PBT) as reinforcement, and ii) maleic anhydride-grafted poly...

  17. Impact damage evolution under fatigue loading by InfraRed Thermography on composite structures

    Directory of Open Access Journals (Sweden)

    Pastor M.-L.

    2010-06-01

    Full Text Available This study deals with cumulative damage and its evolution in already impact damage composite structure. In order to follow the growing damage and to compare it with cumulative model, tests are monitored with an InfraRed thermography system. A carbon-epoxy composite is first low-energy impacted and then fatigued under tensioncompression loading. This study also enables a very fast analysis of predicting the damage evolution coupling InfraRed Thermography as NDT method and InfraRed thermography as a following system.

  18. Meshless Analysis of Laminated Composite and Sandwich Plates Subjected to Various Types of Loads

    Science.gov (United States)

    Singh, Jeeoot; Singh, Sandeep; Shukla, K. K.

    2014-03-01

    The bending analysis of laminated composite and sandwich plates using different radial basis functions and higher-order shear deformation theory is presented. This meshfree technique is insensitive to spatial dimension and considers only a cloud of nodes (centers) for the spatial discretization of both the problem domain and the boundary. Numerical results for simply supported isotropic, symmetric cross-ply composite and sandwich plate are presented. The results are compared with other available results. It is observed that convergence of the polynomial function is faster as compared to other radial basis functions, whereas Gaussian function takes the least solution time. The effect of various types of loadings on sandwich plate is presented.

  19. High-Velocity Impact Behaviour of Prestressed Composite Plates under Bird Strike Loading

    Directory of Open Access Journals (Sweden)

    Sebastian Heimbs

    2012-01-01

    Full Text Available An experimental and numerical analysis of the response of laminated composite plates under high-velocity impact loads of soft body gelatine projectiles (artificial birds is presented. The plates are exposed to tensile and compressive preloads before impact in order to cover realistic loading conditions of representative aeronautic structures under foreign object impact. The modelling methodology for the composite material, delamination interfaces, impact projectile, and preload using the commercial finite element code Abaqus are presented in detail. Finally, the influence of prestress and of different delamination modelling approaches on the impact response is discussed and a comparison to experimental test data is given. Tensile and compressive preloading was found to have an influence on the damage pattern. Although this general behaviour could be predicted well by the simulations, further numerical challenges for improved bird strike simulation accuracy are highlighted.

  20. Optimum Design of Composite Sandwich Structures Subjected to Combined Torsion and Bending Loads

    Science.gov (United States)

    Li, Xiang; Li, Gangyan; Wang, Chun H.; You, Min

    2012-06-01

    This research is motivated by the increase use of composite sandwich structures in a wide range of industries such as automotive, aerospace and civil infrastructure. To maximise stiffness at minimum weight, the paper develops a minimum weight optimization method for sandwich structure under combined torsion and bending loads. We first extend the minimum-weight design of sandwich structures under bending load to the case of torsional deformation and then present optimum solutions for the combined requirements of both bending and torsional stiffness. Three design cases are identified for a sandwich structure required to meet multiple design constraints of torsion and bending stiffness. The optimum solutions for all three cases are derived. To illustrate the newly developed optimum design solutions, numerical examples are presented for sandwich structures made of either isotropic face skins or orthotropic composite face skins.

  1. Load bearing enhancement of pin joined composite laminates using electrospun polyacrylonitrile nanofiber mats

    Directory of Open Access Journals (Sweden)

    J. Herwan

    2016-03-01

    Full Text Available Polyacrylonitrile (PAN nanofibers were produced by an electrospinning technique and directly deposited onto carbon fabric to improve the load bearing strength of pin joined composite laminates. Two types of specimens, virgin laminates and nano-modified laminates, were prepared. A modified carbon fiber reinforced polymer (CFRP laminate was fabricated by interleaving electrospun nanofibers at all of the interlayers of an eight-ply woven carbon fiber fabric. The load bearing test results of the pin joined laminates indicated the electrospun PAN nanofibers increased the load bearing strength by 18.9%. In addition, three point bending tests were also conducted to investigate the flexural modulus and flexural strength of both types of laminates. The flexural modulus and flexural strength also increased by 20.9% and 55.91%, respectively.

  2. Investigation and characterization of constraint effects on flaw growth during fatigue loading of composite materials

    Science.gov (United States)

    Stinchcomb, W. W.; Reifsnider, K. L.; Yeung, P.; Gibbins, M. N.

    1979-01-01

    An investigative program is presented in an attempt to add to the current understanding of constraint effects on the response of composite materials under cyclic loading. The objectives were: (1) to use existing data and to develop additional data in order to establish an understanding and quantitative description of flaw growth in unidirectional lamina under cyclic loading at different load direction to fiber direction angles; (2) to establish a similar understanding and description of flaw growth in lamina which are embedded in laminates between other unflawed lamina; (3) to determine the nature of the influence of constraint on flaw growth by quantitatively comparing the results of the tests; and (4) to develop a model and philosophy of constraints effects based on our investigative results.

  3. Structural effects of three-dimensional angle-interlock woven composite undergoing bending cyclic loading

    Science.gov (United States)

    Jin, LiMin; Yao, Yao; Yu, YiMin; Rotich, Gideon; Sun, BaoZhong; Gu, BoHong

    2014-03-01

    This paper reports the structural effects of three-dimensional (3-D) angle-interlock woven composite (3DAWC) undergoing three-point bending cyclic loading from experimental and finite element analysis (FEA) approaches. In experiment, the fatigue tests were conducted to measure the bending deflection and to observe the damage morphologies. By the FEA approach, a micro-structural unit-cell model of the 3DAWC was established at the yarn level to simulate the fatigue damage. The stress degradation at the loading condition of constant deformation amplitude was calculated to show the degradation of mechanical properties. In addition, the stress distribution, fatigue damage evolution and critical damage regions were also obtained to qualitatively reveal the structural effects and damage mechanisms of the 3DAWC subjected to three-point bending cyclic loading.

  4. Advances in Stability of Composite Airframe Structures Regarding Collapse, Robust Design and Dynamic Loading

    OpenAIRE

    Degenhardt, Richard

    2008-01-01

    European aircraft industry demands for reduced development and operating costs, by 20% and 50% in the short and long term, respectively. Structural weight reduction by exploitation of structural reserves in composite aerospace structures contributes to this aim, however, it requires accurate and experimentally validated stability analysis of real structures under realistic loading conditions. This paper presents new achievements from the area of computational and experimental stability resear...

  5. Design optimization of blade stiffened laminated composite plates for maximum buckling load

    OpenAIRE

    Achenbach, Mark R.

    1990-01-01

    Approved for public release; distribution unlimited. The buckling load of a blade stiffened laminated composite plate having midplane symmetry is maximized for a given total weight. The thickness of the layers and the width and height of the stiffener are taken as the design variables. Buckling analysis is carried out using a finite element method. The optimization problem is solved using commercially available optimization packages. Due to the highly nonlinear nature of the optimality equ...

  6. Failure Test and Finite Element Simulation of a Large Wind Turbine Composite Blade under Static Loading

    OpenAIRE

    Xiao Chen; Wei Zhao; Xiao Lu Zhao; Jian Zhong Xu

    2014-01-01

    This study presented a failure analysis of a 52.3 m composite wind turbine blade under static loading. Complex failure characteristics exhibited at the transition region of the blade were thoroughly examined and typical failure modes were indentified. In order to predict multiple failure modes observed in the tests and gain more insights into the failure mechanisms of the blade, a Finite Element (FE) simulation was performed using a global-local modeling approach and Progressive Failure Anal...

  7. Postbuckling Behaviour of Anisotropic Laminated Composite Plates due to Shear Loading

    Directory of Open Access Journals (Sweden)

    V. Balamurugan

    1998-10-01

    Full Text Available This study investigates postbuckling behaviour of laminated composite plates using a nine-noded shear flexible quadrilateral plate element. The formulation includes nonlinear strain-displacement relation based on von Karman's assumption. The nonlinear governing equations are solved through iteration. A detailed parametric study is carried out to bring out the influence of ply-angle, aspect ratio and material properties on the postbuckling strength of laminates due to in-plane shear loads.

  8. Effect of Molecular Weight on Load Transfer in Nanotube / Polymer Composites

    Science.gov (United States)

    Mu, Minfang; Du, Fangming; Haggenmueller, Reto; Winey, Karen

    2006-03-01

    The tensile moduli of nanocomposite fibers are being investigated with attention to the molecular weight of the polymer. Nanocomposites composed of single wall carbon nanotube (SWNT) and poly(methyl methacrylate) (PMMA) were prepared by our coagulation method and processed into composite fibers using melt fiber spinning. SWNT in the fibers are aligned and the nanotube - nanotube interactions are diminished, so that, the mechanical load on SWNT is mainly from polymer - SWNT interactions. The tensile moduli along the direction parallel to the SWNT were characterized at 1.0 mm / sec with the fiber length of 25.4 mm. At a weight-average molecular weight (Mw) 25 kDa, the tensile moduli of PMMA are the same with the composites. However, when the Mw is increased to 100kDa, the tensile moduli are improved greatly by adding SWNT. This indicates that the load in the composites is transferred to the SWNT more efficiently at 100 kDa molecular weight. A micromechanics model was used to relate the elastic shear stress on the polymer - SWNT interface to the polymer chain length. It showed that with increasing polymer chain length, the interfacial shear stress was enhanced. This study demonstrates the importance of the molecular weight of the polymer matrix to the load transfer in nanocomposites.

  9. Damage Tolerance of Pre-Stressed Composite Panels Under Impact Loads

    Science.gov (United States)

    Johnson, Alastair F.; Toso-Pentecôte, Nathalie; Schueler, Dominik

    2014-02-01

    An experimental test campaign studied the structural integrity of carbon fibre/epoxy panels preloaded in tension or compression then subjected to gas gun impact tests causing significant damage. The test programme used representative composite aircraft fuselage panels composed of aerospace carbon fibre toughened epoxy prepreg laminates. Preload levels in tension were representative of design limit loads for fuselage panels of this size, and maximum compression preloads were in the post-buckle region. Two main impact scenarios were considered: notch damage from a 12 mm steel cube projectile, at velocities in the range 93-136 m/s; blunt impact damage from 25 mm diameter glass balls, at velocities 64-86 m/s. The combined influence of preload and impact damage on panel residual strengths was measured and results analysed in the context of damage tolerance requirements for composite aircraft panels. The tests showed structural integrity well above design limit loads for composite panels preloaded in tension and compression with visible notch impact damage from hard body impact tests. However, blunt impact tests on buckled compression loaded panels caused large delamination damage regions which lowered plate bending stiffness and reduced significantly compression strengths in buckling.

  10. Doxorubicin-loaded mesoporous silica nanoparticle composite nanofibers for long-term adjustments of tumor apoptosis

    Science.gov (United States)

    Yuan, Ziming; Pan, Yue; Cheng, Ruoyu; Sheng, Lulu; Wu, Wei; Pan, Guoqing; Feng, Qiming; Cui, Wenguo

    2016-06-01

    There is a high local recurrence (LR) rate in breast-conserving therapy (BCT) and enhancement of the local treatment is promising as a way to improve this. Thus we propose a drug delivery system using doxorubicin (DOX)-loaded mesoporous silica nanoparticle composite nanofibers which can release anti-tumor drugs in two phases—burst release in the early stage and sustained release at a later stage—to reduce the LR of BCT. In the present study, we designed a novel composite nanofibrous scaffold to realize the efficient release of drugs by loading both DOX and DOX-loaded mesoporous silica nanoparticles into an electrospun PLLA nanofibrous scaffold. In vitro results demonstrated that this kind of nanomaterial can release DOX in two phases, and the results of in vivo experiments showed that this hybrid nanomaterial significantly inhibited the tumor growth in a solid tumor model. Histopathological examination demonstrated that the apoptosis of tumor cells in the treated group over a 10 week period was significant. The anti-cancer effects were also accompanied with decreased expression of Bcl-2 and TNF-α, along with up-regulation of Bax, Fas and the activation of caspase-3 levels. The present study illustrates that the mesoporous silica nanoparticle composite nanofibrous scaffold could have anti-tumor properties and could be further developed as adjuvant therapeutic protocols for the treatment of cancer.

  11. Finite Element Analysis of Composite Hardened Walls Subjected to Blast Loads

    Directory of Open Access Journals (Sweden)

    Girum S. Urgessa

    2009-01-01

    Full Text Available Problem statement: There is currently no standard design guideline to determine the number of composites needed to retrofit masonry walls in order to withstand a given explosion. Past design approaches were mainly based on simplified single-degree-of-freedom analysis. A finite element analysis was conducted for concrete masonry walls hardened with composites and subjected to short duration blast loads. Approach: The analysis focused on displacement time history responses which form the basis for retrofit design guidelines against blast loadings. The blast was determined from 0.5 kg equivalent TNT explosive at 1.83 m stand-off distance to simulate small mailroom bombs. Two and four layered retrofitted walls were investigated. Uncertainties in the finite model analysis of walls such as pressure distributions, effect of mid height explosive bursts versus near the ground explosive bursts and variations in modulus of elasticity of the wall were presented. Results: Uniformly distributed blast loads over the retrofitted wall height produced a small difference in peak displacement results when compared to the non-uniform pressure distribution. Ground explosive burst was shown to produce a 62.7% increase in energy and a higher peak displacement response when compared to mid-height explosive burst. Conclusion: The parametric study on the variation of modulus of elasticity of concrete masonry showed no significant effect on peak displacement affirming the use of the resistance deflection contribution of the composite in retrofit designs.

  12. Simulation of Complex Cracking in Plain Weave C/SiC Composite under Biaxial Loading

    Science.gov (United States)

    Cheng, Ron-Bin; Hsu, Su-Yuen

    2012-01-01

    Finite element analysis is performed on a mesh, based on computed geometry of a plain weave C/SiC composite with assumed internal stacking, to reveal the pattern of internal damage due to biaxial normal cyclic loading. The simulation encompasses intertow matrix cracking, matrix cracking inside the tows, and separation at the tow-intertow matrix and tow-tow interfaces. All these dissipative behaviors are represented by traction-separation cohesive laws. Not aimed at quantitatively predicting the overall stress-strain relation, the simulation, however, does not take the actual process of fiber debonding into account. The fiber tows are represented by a simple rule-of-mixture model where the reinforcing phase is a hypothetical one-dimensional material. Numerical results indicate that for the plain weave C/SiC composite, 1) matrix-crack initiation sites are primarily determined by large intertow matrix voids and interlayer tow-tow contacts, 2) the pattern of internal damage strongly depends on the loading path and initial stress, 3) compressive loading inflicts virtually no damage evolution. KEY WORDS: ceramic matrix composite, plain weave, cohesive model, brittle failure, smeared crack model, progressive damage, meso-mechanical analysis, finite element.

  13. Electric Heating Property from Butyl Rubber-Loaded Boron Carbide Composites

    Institute of Scientific and Technical Information of China (English)

    MENG Dechuan; WANG Ninghui; LI Guofeng

    2014-01-01

    We researched the electric heating property from butyl rubber-loaded boron carbide composite. The effects of boron carbide content on bulk resistivity, voltage-current characteristic, thermal conductivity and thermal stability of boron carbide/butyl rubber (IIR) polymer composite were introduced. The analysis results indicated that the bulk resistivity decreased greatly with increasing boron carbide content, and when boron carbide content reached to 60%, the bulk resistivity achieved the minimum. Accordingly, electric heating behavior of the composite is strongly dependent on boron carbide content as well as applied voltage. The content of boron carbide was found to be effective in achieving high thermal conductivity in composite systems. The thermal conductivity of the composite material with added boron carbide was improved nearly 20 times than that of the pure IIR. The thermal stability test showed that, compared with pure IIR, the thermal stable time of composites was markedly extended, which indicated that the boron carbide can significantly improve the thermal stability of boron carbide/IIR composite.

  14. The Use of Micro and Nano Particulate Fillers to Modify the Mechanical and Material Properties of Acrylic Bone Cement

    Science.gov (United States)

    Slane, Joshua A.

    Acrylic bone cement (polymethyl methacrylate) is widely used in total joint replacements to provide long-term fixation of implants. In essence, bone cement acts as a grout by filling in the voids left between the implant and the patient's bone, forming a mechanical interlock. While bone cement is considered the `gold standard' for implant fixation, issues such as mechanical failure of the cement mantle (aseptic loosening) and the development of prosthetic joint infection (PJI) still plague joint replacement procedures and often necessitate revision arthroplasty. In an effort to address these failures, various modifications are commonly made to bone cement such as mechanical reinforcement with particles/fibers and the addition of antibiotics to mitigate PJI. Despite these attempts, issues such as poor particle interfacial adhesion, inadequate drug release, and the development of multidrug resistant bacteria limit the effectiveness of bone cement modifications. Therefore, the overall goal of this work was to use micro and nanoparticles to enhance the properties of acrylic bone cement, with particular emphasis placed on improving the mechanical properties, cumulative antibiotic release, and antimicrobial properties. An acrylic bone cement (Palacos R) was modified with three types of particles in various loading ratios: mesoporous silica nanoparticles (for mechanical reinforcement), xylitol microparticles (for increased antibiotic release), and silver nanoparticles (as an antimicrobial agent). These particles were used as sole modifications, not in tandem with one another. The resulting cement composites were characterized using a variety of mechanical (macro to nano, fatigue, fracture, and dynamic), imaging, chemical, thermal, biological, and antimicrobial testing techniques. The primary outcomes of this dissertation demonstrate that: (1) mesoporous silica, as used in this work, is a poor reinforcement phase for acrylic bone cement, (2) xylitol can significantly

  15. Experimental studies on fatigue behavior of macro fiber composite (MFC) under mechanical loading

    Science.gov (United States)

    Pandey, Akash; Arockiarajan, A.

    2016-04-01

    Macro fiber Composite (MFC) finds its application in active control, vibration control and sensing elements. MFC can be laminated to surfaces or embedded in the structures to be used as an actuator and sensors. Due to its attractive properties and applications, it may be subjected to continuous loading, which leads to the deterioration of the properties. This study is focused on the fatigue lifetime of MFC under tensile and compressive loading at room temperature. Experiments were performed using 4 point bending setup, with MFC pasted at the center of the mild steel beam, to maintain constant bending stress along MFC. MFC is pasted using vacuum bagging technique. Sinusoidal loading is given to sample while maintaining R=0.13 (for tensile testing) and R=10 (for compressive testing). For d31 and d33 type of MFC, test was conducted for the strain values of 727 μ strain, 1400 μ strain, 1700 μ strain and 1900 μ strain for fatigue under tensile loading. For fatigue under compressive loading, both d33 and d31, was subjected to minimum strain of -2000 μ strain. Decrease in the slope of dielectric displacement vs. strain is the measure for the degradation. 10 percent decrease in the slope is set as the failure criteria. Experimental results show that MFC is very reliable below 1700 μ strain (R=0.13) at the room temperature.

  16. [Acrylic resin removable partial dentures

    NARCIS (Netherlands)

    Baat, C. de; Witter, D.J.; Creugers, N.H.J.

    2011-01-01

    An acrylic resin removable partial denture is distinguished from other types of removable partial dentures by an all-acrylic resin base which is, in principle, solely supported by the edentulous regions of the tooth arch and in the maxilla also by the hard palate. When compared to the other types of

  17. Effect of Load Rate on Ultimate Tensile Strength of Ceramic Matrix Composites at Elevated Temperatures

    Science.gov (United States)

    Choi, Sung R.; Gyekenyesi, John P.

    2001-01-01

    The strengths of three continuous fiber-reinforced ceramic composites, including SiC/CAS-II, SiC/MAS-5 and SiC/SiC, were determined as a function of test rate in air at 1100 to 1200 C. All three composite materials exhibited a strong dependency of strength on test rate, similar to the behavior observed in many advanced monolithic ceramics at elevated temperatures. The application of the preloading technique as well as the prediction of life from one loading configuration (constant stress-rate) to another (constant stress loading) suggested that the overall macroscopic failure mechanism of the composites would be the one governed by a power-law type of damage evolution/accumulation, analogous to slow crack growth commonly observed in advanced monolithic ceramics. It was further found that constant stress-rate testing could be used as an alternative to life prediction test methodology even for composite materials, at least for short range of lifetimes and when ultimate strength is used as the failure criterion.

  18. [Preparation and clinical application of polyvinyl alcohol/drug-loaded chitosan microsphere composite wound dressing].

    Science.gov (United States)

    Zhang, Xiuju; Lin, Zhidan; Chen, Wenbin; Song, Ying; Li, Zhizhong

    2011-04-01

    In order to prepare and apply the polyvinyl alcohol/drug-loaded chitosan microspheres composite wound dressing, we first prepared chitosan microspheres by emulsion cross-linking method, and then added chitosan microspheres into the reactants during the acetalization of polyvinyl alcohol and formaldehyde. We further studied the morphology, water absorption, swelling degree, mechanical properties and in vitro release of the sponge with different amount of chitosan microspheres. The results showed that polyvinyl alcohol/drug-loaded chitosan composite sponge has porous structure with connectionism. Increasing the amount of chitosan microspheres would make the apertures smaller, so that the water absorption and the swelling of sponge decreased, but the tensile strength and compressive strength increased. With the increase of the amount of chitosan microspheres, the drug absorption of cefradine and the release rate increase, and the release time become longer. With the results of toxicity grade of 0 to 1, this type of composite sponge is non-toxic and meets the requirement of biocompatibility. The observation of rabbit nasal cavity after surgical operation suggested that polyvinyl acetal sponge modified with the chitosan has antiphlogistic, hemostatic and non-adherent characteristic, and can promote the healing and recovering of the nasalmucosa. After using this composite material, best growing surroundings for patients' granulation tissue were provided. Exposed bone and tendon were covered well with granulation tissue.

  19. Effect of Piezoelectric Implant on the Structural Integrity of Composite Laminates Subjected to Tensile Loads

    Science.gov (United States)

    Masmoudi, Sahir; El Mahi, Abderrahim; Turki, Saïd

    2016-07-01

    The embedment of sensors within composite structures gives the opportunity to develop smart materials for health and usage monitoring systems. This study investigates the use of acoustic emission monitoring with embedded piezoelectric sensor during mechanical tests in order to identify the effects of introducing the sensor into the composite materials. The composite specimen with and without embedded sensor were subject to tensile static and fatigue loading. The analysis and observation of AE signals show that the integration of a sensor presents advantage of the detection of the acoustic events and also show the presence of three or four types of damage during tests. The incorporation of piezoelectric sensor has a negligible influence on the mechanical properties of materials.

  20. Nonlinear Viscoelastic Response of Unidirectional Polymeric Laminated Composite Plates Under Bending Loads

    Science.gov (United States)

    Falahatgar, S. R.; Salehi, Manouchehr

    2011-12-01

    Nonlinear bending analysis of polymeric laminated composite plate is examined considering material nonlinearity for viscoelastic matrix material through a Micro-macro approach. The micromechanical Simplified Unit Cell Method (SUCM) in three-dimensional closed-form solution is used for the overall behavior of the unidirectional composite in any combination of loading conditions. The elastic fibers are transversely isotropic where Schapery single integral equation in multiaxial stress state describes the matrix material by recursive-iterative formulation. The finite difference Dynamic Relaxation (DR) method is utilized to study the bending behavior of Mindlin annular sector plate including geometric nonlinearity under uniform lateral pressure with clamped and hinged edge constraints. The unsymmetrical laminated plate deflection is predicted for different thicknesses and also various pressures in different time steps and they are compared with elastic finite element results. As a main objective, the deflection results of viscoelastic laminated sector plate are obtained for various fiber volume fractions in the composite system.

  1. Combined effects of organic aerosol loading and fog processing on organic aerosols oxidation and composition

    Science.gov (United States)

    Chakraborty, Abhishek; Tripathi, Sachchida; Gupta, Tarun

    2016-04-01

    Fog is a natural meteorological phenomenon that occurs throughout the world, it contains substantial quantity of liquid water and generally seen as a natural cleansing agent but it also has the potential to form highly oxidized secondary organic aerosols (SOA) via aqueous processing of ambient aerosols. On the other hand higher organic aerosols (OA) loading tend to decrease the overall oxidation level (O/C) of the particle phase organics, due to enhanced partitioning of less oxidized organics from gas to particle phase. However, combined impact of these two parameters; aqueous oxidation and OA loading, on the overall oxidation ratio (O/C) of ambient OA has never been studied. To assess this, real time ambient sampling using HR-ToF-AMS was carried out at Kanpur, India from 15 December 2014 - 10 February 2015. In first 3 weeks of this campaign, very high OA loading is (134 ± 42 μg/m3) observed (termed as high loading or HL period) while loading is substantially reduced from 2nd January, 2016 (56 ± 20 μg/m3, termed as low loading or LL period) . However, both the loading period was affected by several fog episodes (10 in HL and 7 in LL), thus providing the opportunity of studying the combined effects of fog and OA loading on OA oxidation. It is found that O/C ratio is very strongly anti-correlated with OA loading in both the loading period, however, slope of this ant-correlation is much steep during HL period than in LL period. Source apportionment of OA revealed that there is drastic change in the types of OA from HL to LL period, clearly indicating difference in OA composition from HL to LL period. During foggy night continuous oxidation of OA is observed from early evening to early morning with 15-20% enhancement in O/C ratio, while the same is absent during non-foggy period, clearly indicating the efficient fog processing of ambient OA. It is also found that night time fog aqueous oxidation can be as effective as daytime photo chemistry in oxidation of OA. Fog

  2. Effect of Fiber Treatment and Fiber Loading on Mechanical Properties of Luffa-Resorcinol Composites

    Directory of Open Access Journals (Sweden)

    Chhatrapati Parida

    2015-01-01

    Full Text Available Tensile and compressive behaviour of resorcinol-formaldehyde (RF matrix and its composites reinforced with fibers of Luffa cylindrica (LC have been studied. LC fibers were subjected to chemical treatments such as alkali activation by NaOH followed by bleaching and acid hydrolysis in order to improve fiber-matrix adhesion. Both treated and untreated LC fibers are modified with calcium phosphate. The presence of hydroxy apatite, a polymorph of calcium phosphate and a major constituent of vertebrate bone and teeth, was confirmed from XRD peak of treated LC fiber. XRD analysis of the treated LC fiber has confirmed the crystalline nature of the chemically treated LC fiber by its crystallinity index. The effects of fiber loading of chemically treated and untreated LC fiber on ultimate stress, yield strength, breaking stress, and modulus of the composites were analyzed. The tensile and compressive modulus of the composites were increased with incorporation of both treated and untreated LC fibers into the RF matrix. The modulus of composites with treated LC fiber was enhanced compared to that of the untreated fiber composites. Furthermore the values of ultimate stress, yield stress, and breaking stress were increased with the incorporation of treated LC fiber in the composites.

  3. Dynamic Response of Rcc and Composite Structure with Brb Frame Subjected To Seismic and Temperature Load

    Directory of Open Access Journals (Sweden)

    Syeda Qurratul Aien Najia

    2016-04-01

    Full Text Available Concrete structures impart more seismic weight and less deflection whereas Steel structures instruct more deflections and ductility to the structure, which is beneficial in resisting earthquake forces. Composite Construction combines the better properties of both steel and concrete. Buckling restrained braced frames (BRBFs are primarily used as seismic-force resisting systems for buildings in seismically-active regions.The objective of the present work is to compare a twenty storied RCC and composite framed structure with BRB frame subjected to Seismic and different Temperatureloadings using Non-Linear Time History Analysis. Three dimensional modeling and analysis of the structure is carried out with the help of SAP-2000 v16 software. It is observed that the storey displacements were decreased by 36% for twenty storey RCC building and for composite buildings it was decreased by 45% for twenty storeys suggesting the effectiveness of Buckling restrained brace frame. The overall results suggested that BRB were excellent seismic control device for composite building as the roof displacement is reduced by 40% but whereas for RCC it is reduced only by 25%. For Seismic prone areas composite building with BRB frame is more effective. Under Temperature loading RCC building is more effective than composite structure.

  4. Preparation and properties of UV curable acrylic PSA by vinyl bonded graphene oxide

    Science.gov (United States)

    Pang, Beili; Ryu, Chong-Min; Jin, Xin; Kim, Hyung-Il

    2013-11-01

    Acrylic pressure sensitive adhesives (PSAs) with higher thermal stability for thin wafer handling were successfully prepared by forming composite with the graphene oxide (GO) nanoparticles modified to have vinyl groups via subsequent reaction with isophorone diisocyanate and 2-hydroxyethyl methacrylate. The acrylic copolymer was synthesized as a base resin for PSAs by solution radical polymerization of ethyl acrylate, 2-ethylhexyl acrylate, and acrylic acid followed by further modification with GMA to have the vinyl groups available for UV curing. The peel strength of PSA decreased with the increase of gel content which was dependent on both modified GO content and UV dose. Thermal stability of UV-cured PSA was improved noticeably with increasing the modified GO content mainly due to the strong and extensive interfacial bonding formed between the acrylic copolymer matrix and GO fillers

  5. Epoxy-acrylic core-shell particles by seeded emulsion polymerization.

    Science.gov (United States)

    Chen, Liang; Hong, Liang; Lin, Jui-Ching; Meyers, Greg; Harris, Joseph; Radler, Michael

    2016-07-01

    We developed a novel method for synthesizing epoxy-acrylic hybrid latexes. We first prepared an aqueous dispersion of high molecular weight solid epoxy prepolymers using a mechanical dispersion process at elevated temperatures, and we subsequently used the epoxy dispersion as a seed in the emulsion polymerization of acrylic monomers comprising methyl methacrylate (MMA) and methacrylic acid (MAA). Advanced analytical techniques, such as scanning transmission X-ray microscopy (STXM) and peak force tapping atomic force microscopy (PFT-AFM), have elucidated a unique core-shell morphology of the epoxy-acrylic hybrid particles. Moreover, the formation of the core-shell morphology in the seeded emulsion polymerization process is primarily attributed to kinetic trapping of the acrylic phase at the exterior of the epoxy particles. By this new method, we are able to design the epoxy and acrylic polymers in two separate steps, and we can potentially synthesize epoxy-acrylic hybrid latexes with a broad range of compositions.

  6. Influence of surface preparation on fracture load of resin composite-based repairs

    Science.gov (United States)

    Mateos-Palacios, Rocío; Román-Rodríguez, Juan-Luis; Solá-Ruíz, María-Fernanda; Fons-Font, Antonio

    2015-01-01

    The purpose of the present study is to evaluate the fracture load of composite-based repairs to fractured zirconium oxide (Z) crowns and to ceramic-fused-to-metal (CM) crowns, comparing different mechanical surface preparation methods. A total of 75 crowns were repaired; samples then underwent dynamic loading and thermocycling. Final fracture load values for failure of the repaired crowns were measured and the type of fracture registered. Group I: CM: Surface preparation with a diamond bur + 9.5% Hydrofluoric Acid (HF) etching; Group II): CM: air-particle (Al2O3) + 9.5% HF; Group III: CM: Silica coating (SiO2); Group IV): Z: air-particle (Al2O3) + HF 9.5%; Group V) Z: Silica coating (SiO2). Of the three CM groups, Group I (CM-diamond bur) showed the highest mean failure value, with significant difference in comparison with Group III (CM-silica coating). For the zirconia groups, the highest value was obtained by Group V (silica coating). Key words:Crown, ceramic-fused-to-metal, zirconia, resin-composite, ceramic covering. PMID:25810848

  7. Influence of surface preparation on fracture load of resin composite-based repairs.

    Science.gov (United States)

    Agustín-Panadero, Rubén; Mateos-Palacios, Rocío; Román-Rodríguez, Juan-Luis; Solá-Ruíz, María-Fernanda; Fons-Font, Antonio

    2015-02-01

    The purpose of the present study is to evaluate the fracture load of composite-based repairs to fractured zirconium oxide (Z) crowns and to ceramic-fused-to-metal (CM) crowns, comparing different mechanical surface preparation methods. A total of 75 crowns were repaired; samples then underwent dynamic loading and thermocycling. Final fracture load values for failure of the repaired crowns were measured and the type of fracture registered. Group I: CM: Surface preparation with a diamond bur + 9.5% Hydrofluoric Acid (HF) etching; Group II): CM: air-particle (Al2O3) + 9.5% HF; Group III: CM: Silica coating (SiO2); Group IV): Z: air-particle (Al2O3) + HF 9.5%; Group V) Z: Silica coating (SiO2). Of the three CM groups, Group I (CM-diamond bur) showed the highest mean failure value, with significant difference in comparison with Group III (CM-silica coating). For the zirconia groups, the highest value was obtained by Group V (silica coating). Key words:Crown, ceramic-fused-to-metal, zirconia, resin-composite, ceramic covering.

  8. Temperature effects on polymer-carbon composite sensors: evaluating the role of polymer molecular weight and carbon loading

    Science.gov (United States)

    Homer, M. L.; Lim, J. R.; Manatt, K.; Kisor, A.; Lara, L.; Jewell, A. D.; Yen, S. -P. S.; Shevade, A. V.; Ryan, M. A.

    2003-01-01

    We report the effect of environmental condtions coupled with varying polymer properties and carbon loadings on the performance of polymer-carbon black composite film, used as sensing medium in the JPL Electronic Nose.

  9. The Effect of Delamination on Damage Path and Failure Load Prediction for Notched Composite Laminates

    Science.gov (United States)

    Satyanarayana, Arunkumar; Bogert, Philip B.; Chunchu, Prasad B.

    2007-01-01

    The influence of delamination on the progressing damage path and initial failure load in composite laminates is investigated. Results are presented from a numerical and an experimental study of center-notched tensile-loaded coupons. The numerical study includes two approaches. The first approach considers only intralaminar (fiber breakage and matrix cracking) damage modes in calculating the progression of the damage path. In the second approach, the model is extended to consider the effect of interlaminar (delamination) damage modes in addition to the intralaminar damage modes. The intralaminar damage is modeled using progressive damage analysis (PDA) methodology implemented with the VUMAT subroutine in the ABAQUS finite element code. The interlaminar damage mode has been simulated using cohesive elements in ABAQUS. In the experimental study, 2-3 specimens each of two different stacking sequences of center-notched laminates are tensile loaded. The numerical results from the two different modeling approaches are compared with each other and the experimentally observed results for both laminate types. The comparisons reveal that the second modeling approach, where the delamination damage mode is included together with the intralaminar damage modes, better simulates the experimentally observed damage modes and damage paths, which were characterized by splitting failures perpendicular to the notch tips in one or more layers. Additionally, the inclusion of the delamination mode resulted in a better prediction of the loads at which the failure took place, which were higher than those predicted by the first modeling approach which did not include delaminations.

  10. Tribological Performance of NiAl Self-lubricating Matrix Composite with Addition of Graphene at Different Loads

    Science.gov (United States)

    Xiao, Yecheng; Shi, Xiaoliang; Zhai, Wenzheng; Yao, Jie; Xu, Zengshi; Chen, Long; Zhu, Qingshuai

    2015-08-01

    This research was carried out on the beneficial effect of graphene additive in self-lubricating composites for use at different loads of tribological application. The dry friction and wear behaviors of NiAl self-lubricating matrix composite with graphene (NSMG) were investigated at different loads at room temperature. Finite element method served as aided method to analyze the stress condition of contact pair, which would provide another perspective to comprehend the relationship between tribological behaviors and different degrees of load-induced deformation. In the load range of 2-16 N, the results indicated that NSMG showed excellent tribological performance at load of 16 N due to the formation of anti-friction tribo-film on the worn surface. Moreover, suitable load would lead to the contact situation transfer from multi-point contact to area contact, which could contribute to the beneficial effect on friction behavior of NSMG.

  11. Optical performance of mesostructured composite silica film loaded with organic dye.

    Science.gov (United States)

    Guli, Mina; Chen, Shijian; Zhang, Dingke; Li, Xiaotian; Yao, Jianxi; Chen, Lei; Xiao, Li

    2014-01-10

    A mesoporous composite silica film loaded with organic dye has been successfully synthesized by a solgel reaction process and a simple postgrafting method at room temperature. The composite film was characterized by x-ray diffraction, transmission electron microscopy, UV-Vis, photoluminescence (PL) spectra, and laser performance, and the results confirmed the existence of dyes in the channels of the silica film. A blue-shift and fluorescence property in the PL spectrum was observed from the composite film compared with that of dye molecules in C₂H₅OH solution. The spectrum narrowing phenomena has been observed when the composite film is pumped at λp=355  nm by a Nd:YAG pulsed laser. A narrower, higher peak was observed in emission spectra from the mesostructured composite silica film compared with the PL spectrum of dye in C₂H₅OH solution. There is a substantial reduction in the full width at half-maximum of the emitting light, which results in peaks with linewidths of 26 nm or more. This collapse of the emission spectrum is one of the signatures of the presence of amplified spontaneous emission. PMID:24514063

  12. Macroscopic Mechanical Characterization of SMAs Fiber-Reinforced Hybrid Composite Under Uniaxial Loading

    Science.gov (United States)

    Lei, Hongshuai; Wang, Zhenqing; Tong, Liyong; Tang, Xiaojun

    2013-10-01

    This paper presents an experimental and theoretical investigation on the macroscopic mechanical behavior of shape memory alloys (SMAs) fiber-reinforced glass/resin composite subject to uniaxial loading at ambient temperature. A series of unidirectional SMAs reinforced composite laminates is fabricated through vacuum-assisted resin injection. Scanning electron microscopy is conducted to evaluate the interfacial cohesive quality between SMAs fiber and matrix. A theoretical model is proposed based on the SMAs phase transformation model and rule of mixture. Uniaxial tensile tests are performed to study the effects of weak interface and SMAs fiber volume fraction on the effective modulus of composite. Failure morphology of composite is discussed based on the observation using digital HF microscope. Due to the effects of phase transformation and weak interface, the overall stiffness of SMAs composite at the second stage is on average 10% lower than theoretical results. The rupture elongation of experimental result is approximately 13% higher than theoretical result. The local interfacial debonding between SMAs fiber and glass/resin matrix is the main failure mode.

  13. Test and Modelling of Impact on Pre-Loaded Composite Panels

    Science.gov (United States)

    Pickett, A. K.; Fouinneteau, M. R. C.; Middendorf, P.

    2009-08-01

    Currently test and simulation of low and high speed impact of Aerospace composite structures is undertaken in an unloaded state. In reality this may not be the case and significant internal stresses could be present during an impact event such as bird strike during landing, or takeoff. In order to investigate the effects of internal loading on damage and failure of composite materials a series of experimental and simulation studies have been undertaken on three composite types having different fibres, resins and lay-ups. For each composite type panels have been manufactured and transversely impacted under the condition of ‘unloading’ or ‘pre-loading’. For preloading a rig has been constructed that can impose a constant in plane strain of up to 0.25% prior to impact. Results have clearly shown that preloading does lower the composite impact tolerance and change the observed failure modes. Simulation of experiments have also been conducted and have provided an encouraging agreement with test results in terms of both impact force time histories and prediction of the observed failure mechanisms.

  14. Development of Composite Scaffolds for Load-Bearing Segmental Bone Defects

    Directory of Open Access Journals (Sweden)

    Marcello Pilia

    2013-01-01

    Full Text Available The need for a suitable tissue-engineered scaffold that can be used to heal load-bearing segmental bone defects (SBDs is both immediate and increasing. During the past 30 years, various ceramic and polymer scaffolds have been investigated for this application. More recently, while composite scaffolds built using a combination of ceramics and polymeric materials are being investigated in a greater number, very few products have progressed from laboratory benchtop studies to preclinical testing in animals. This review is based on an exhaustive literature search of various composite scaffolds designed to serve as bone regenerative therapies. We analyzed the benefits and drawbacks of different composite scaffold manufacturing techniques, the properties of commonly used ceramics and polymers, and the properties of currently investigated synthetic composite grafts. To follow, a comprehensive review of in vivo models used to test composite scaffolds in SBDs is detailed to serve as a guide to design appropriate translational studies and to identify the challenges that need to be overcome in scaffold design for successful translation. This includes selecting the animal type, determining the anatomical location within the animals, choosing the correct study duration, and finally, an overview of scaffold performance assessment.

  15. The creep behavior of acrylic denture base resins.

    Science.gov (United States)

    Sadiku, E R; Biotidara, F O

    1996-01-01

    The creep behavior of acrylic dental base resins, at room temperature and at different loading conditions, has been examined. The behaviors of these resins are similar to that of "commercial perspex" at room temperature over a period of 1000 seconds. The pseudo-elastic moduli of the blends of PMMA VC show a significant increase compared with PMMA alone. The addition of the PVC powder to the heat-cured acrylic resin increased the time-dependent elastic modulus. This increase in elastic modulus is advantageous in the production of denture based resins of improv mechanical properties.

  16. Acrylic Acid and Esters Will Be Oversupply

    Institute of Scientific and Technical Information of China (English)

    Zheng Chengwang

    2007-01-01

    @@ Drastic capacity growth The production capacity of acrylic acid in China has grown drastically in recent years. With the completion of the 80 thousand t/a acrylic acid and 130 thous and t/a acrylic ester project in Shenyang Paraffin Chemical Industrial Co., Ltd., (CCR2006,No. 31) the capacity of acrylic acid in China has reached 882 thousand t/a.

  17. Electrical resistance load effect on magnetoelectric coupling of magnetostrictive/piezoelectric laminated composite

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yaojin, E-mail: wangyaojin@hotmail.co [Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 215 Chengbei Road, Jiading, Shanghai 201800 (China); Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China); Zhao, Xiangyong [Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 215 Chengbei Road, Jiading, Shanghai 201800 (China); Jiao, Jie; Liu, Linhua [Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 215 Chengbei Road, Jiading, Shanghai 201800 (China); Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China); Di, Wenning; Luo, Haosu [Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 215 Chengbei Road, Jiading, Shanghai 201800 (China); Or, Siu Wing, E-mail: eeswor@polyu.edu.h [Department of Electrical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong)

    2010-06-25

    The effect of electrical resistance load on the magnetoelectric (ME) coupling of laminated composite of Tb{sub 0.3}Dy{sub 0.7}Fe{sub 1.92} (Terfenol-D) magnetostrictive alloy and 0.7Pb (Mg{sub 1/3}Nb{sub 2/3})O{sub 3}-0.3PbTiO{sub 3} (PMN-PT) piezoelectric single crystal is investigated at both non-resonance and resonance frequencies. The results show that (i) the ME coefficient and ME resonance frequency increase with the increase in electrical resistance load, and (ii) the maximum ME power occurs in open-circuit condition. The present study provides the basis for the design of ME sensors and their signal-processing and electronic circuits.

  18. Damage Simulation in Non-Crimp Fabric Composite Plates Subjected to Impact Loads

    Science.gov (United States)

    Satyanarayana, Arunkumar; Bogert, Philip B.; Aitharaju, Venkat; Aashat, Satvir; Kia, Hamid

    2014-01-01

    Progressive failure analysis (PFA) of non-crimp fabric (NCF) composite laminates subjected to low velocity impact loads was performed using the COmplete STress Reduction (COSTR) damage model implemented through VUMAT and UMAT41 user subroutines in the frame works of the commercial finite element programs ABAQUS/Explicit and LS-DYNA, respectively. To validate the model, low velocity experiments were conducted and detailed correlations between the predictions and measurements for both intra-laminar and inter-laminar failures were made. The developed material and damage model predicts the peak impact load and duration very close with the experimental results. Also, the simulation results of delamination damage between the ply interfaces, in-plane matrix damages and fiber damages were all in good agreement with the measurements from the non-destructive evaluation data.

  19. Hertzian Load-bearing Capacity of Hybrid and Nano-hybrid Resin Composites Stored Dry and Wet

    OpenAIRE

    Farmani S; Orandi S; Sookhakiyan M; Mese A

    2016-01-01

    Statement of Problem: Hertzian indentation test has been proven to be an efficient and reliable alternative upon Vickers hardness test. This method has been used to test dental ceramics, amalgams, glass ionomers and luting cements.There is limited published information about the load-bearing capacity of resin composites using Hertizian indentation test. Objectives: To investigate the load-bearing capacity of hybrid and nano-hybrid resin composites stored dry or wet up to 30 days, using ...

  20. Compression Creep Rupture of an E-glass/Vinyl Ester Composite Subjected to Combined Mechanical and Fire Loading Conditions

    OpenAIRE

    Boyd, Steven Earl

    2006-01-01

    Polymer matrix composites are seeing increasing use in structural systems (e.g. ships, bridges) and require a quantitative basis for describing their performance under combined mechanical load and fire. Although much work has been performed to characterize the flammability, fire resistance and toxicity of these composite systems, an understanding of the structural response of sandwich type structures and laminate panels under combined mechanical and thermal loads (simulating fire conditions)...

  1. Comparative Evaluation Of Reinforced Concrete, Steel And Composite Structures Under The Effect Of Static And Dynamic Loads

    OpenAIRE

    Zafar Mujawar; Prakarsh Sangave

    2015-01-01

    Steel-concrete composite construction has gained wide acceptance all over the world as an alternative for pure steel and pure concrete construction. However this approach is a new concept for construction industry. R.C.C are no longer economical because of their increased dead load, hazardous formwork. The present study deals with comparison of reinforced concrete, steel and composite structures under the effect of static and dynamic loads. The results of this work show that compo...

  2. Preparation and properties of acrylic resin coating modified by functional graphene oxide

    Science.gov (United States)

    Dong, Rui; Liu, Lili

    2016-04-01

    To improve the dispersion and the strength of filler-matrix interface in acrylic resin, the functional graphene oxide (FGO) was obtained by surface modification of graphene oxide (GO) by γ-methacryloxypropyl trimethoxysilane (KH-570) and then the acrylic nanocomposites containing different loadings of GO and FGO were prepared. The structure, morphology and dispersion/exfoliation of the FGO were characterized by XRD, FT-IR, Raman, XPS, SEM and TEM. The results demonstrated that the KH-570 was successfully grafted onto the surface of GO sheets. Furthermore, the corresponding thermal, mechanical and chemical resistance properties of the acrylic nanocomposites filled with the FGO were studied and compared with those of neat acrylic and GO/acrylic nanocomposites. The results revealed that the loading of FGO effectively enhanced various properties of acrylic resin. These findings confirmed that the dispersion and interfacial interaction were greatly improved by incorporation of FGO, which might be the result of covalent bonds between the FGO and the acrylic matrix. This work demonstrates an in situ polymerization method to construct a flexible interphase structure, strong interfacial interaction and good dispersion of FGO in acrylic nanocomposites, which can reinforce the polymer properties and be applied in research and industrial areas.

  3. Characterization of unidirectional carbon fiber reinforced polyamide-6 thermoplastic composite under longitudinal compression loading at high strain rate

    OpenAIRE

    Ploeckl Marina; Kuhn Peter; Koerber Hannes

    2015-01-01

    In the presented work, an experimental investigation has been performed to characterize the strain rate dependency of unidirectional carbon fiber reinforced polyamide-6 composite for longitudinal compression loading. An end-loaded compression specimen geometry, suitable for contactless optical strain measurement via digital image correlation and dynamic loading in a split-Hopkinson pressure bar, was developed. For the dynamic experiments at a constant strain rate of 100 s−1 a modified version...

  4. Interpreting the "g" Loadings of Intelligence Test Composite Scores in Light of Spearman's Law of Diminishing Returns

    Science.gov (United States)

    Reynolds, Matthew R.

    2013-01-01

    The linear loadings of intelligence test composite scores on a general factor ("g") have been investigated recently in factor analytic studies. Spearman's law of diminishing returns (SLODR), however, implies that the "g" loadings of test scores likely decrease in magnitude as g increases, or they are nonlinear. The purpose of this study was to (a)…

  5. 纳米腐植酸/丙烯酸-丙烯酰胺-蒙脱土复合型树脂的制备与表征%Preparation and characterization of nanoscale humic acid /poly(acrylic acid-acryl amide)-co-montorillonite composite resin

    Institute of Scientific and Technical Information of China (English)

    程亮; 侯翠红; 徐丽; 雒廷亮; 张保林; 刘国际

    2016-01-01

    The composite resins based on (acrylic acid-acrylamide)-motorillonite/nano humic acid were prepared by aqueous solution polymerization,using methylene-bis-acrylamide as cross-linking agent,potassium persulfate as initiator,acrylic acid,acrylamide,nano humic acid and modified montmorillonite as material.The effects of the monomer ratio (mass ratio ),nano-humic acid content,reaction temperature were systematically studied through single factor and orthogonal experiment.The optimum conditions were as follows:the monomer ratio 3:7 ,nano humic acid content 15%(mass fraction),reaction temperature 65℃,neutralization degree 80%(mass fraction), cross-linking agent content 0.05% (mass fraction),and initiator content 1.0% (mass fraction).The water absorption rate and salt absorption rate of the prepared composite resins were 998.90 g/g and 102.59 g/g, respectively.The product was characterized by FT-IR,SEM and TG-DSC,and the results showed that the grafting reaction took place among nanoscale humic acid and acrylamide,and ether bond emerged;the surface was rough and had loose structure,there were also many holes,voids and pits;it had a good thermal stability.%以N,N-亚甲基双丙烯酰胺为交联剂,过二硫酸钾为引发剂,丙烯酸、丙烯酰胺、纳米腐植酸及改性蒙脱土为原料,采用水溶液聚合法制备了丙烯酸-丙烯酰胺/纳米腐植酸基复合型树脂.通过单因素及正交实验系统考察了单体比(质量比)、纳米腐植酸用量、反应温度等因素对复合型树脂吸液倍率的影响.最适宜制备工艺条件为:单体比3:7,纳米腐植酸用量为15%,反应温度65℃,中和度80%,交联剂0.05%,引发剂1.0%,所制备的复合型树脂吸水和吸盐倍率分别为998.90 g/g及102.59 g/g.用FT-IR,SEM及TG-DSC等对产物进行表征,结果表明:纳米腐植酸与丙烯酰胺发生接枝反应,产生了醚键;其表面结构疏松且粗糙,呈现较多孔洞、空隙及凹坑;热稳定性较好.

  6. Description of the HiMAT Tailored composite structure and laboratory measured vehicle shape under load

    Science.gov (United States)

    Monaghan, R. C.

    1981-01-01

    The aeroelastically tailored outer wing and canard of the highly maneuverable aircraft technology (HiMAT) vehicle are closely examined and a general description of the overall structure of the vehicle is provided. Test data in the form of laboratory measured twist under load and predicted twist from the HiMAT NASTRAN structural design program are compared. The results of this comparison indicate that the measured twist is generally less than the NASTRAN predicted twist. These discrepancies in twist predictions are attributed, at least in part, to the inability of current analytical composite materials programs to provide sufficiently accurate properties of matrix dominated laminates for input into structural programs such as NASTRAN.

  7. Damage Accumulation in Cyclically-Loaded Glass-Ceramic Matrix Composites Monitored by Acoustic Emission

    Science.gov (United States)

    Aggelis, D. G.; Dassios, K. G.; Kordatos, E. Z.; Matikas, T. E.

    2013-01-01

    Barium osumilite (BMAS) ceramic matrix composites reinforced with SiC-Tyranno fibers are tested in a cyclic loading protocol. Broadband acoustic emission (AE) sensors are used for monitoring the occurrence of different possible damage mechanisms. Improved use of AE indices is proposed by excluding low-severity signals based on waveform parameters, rather than only threshold criteria. The application of such improvements enhances the accuracy of the indices as accumulated damage descriptors. RA-value, duration, and signal energy follow the extension cycles indicating moments of maximum or minimum strain, while the frequency content of the AE signals proves very sensitive to the pull-out mechanism. PMID:24381524

  8. Multi-axial load application and DIC measurement of advanced composite beam deformation behavior

    Directory of Open Access Journals (Sweden)

    Berggreen C.

    2010-06-01

    Full Text Available For the validation of a new beam element formulation, a wide set of experimental data consisting of deformation patterns obtained for a number of specially designed composite beam elements, have been obtained. The composite materials applied in the beams consist of glass-fiber reinforced plastic with specially designed layup configurations promoting advanced coupling behavior. Furthermore, the beams are designed with different cross-section shapes. The data obtained from the experiments are also used in order to improve the general understanding related to practical implementation of mechanisms of elastic couplings due to anisotropic properties of composite materials. The knowledge gained from these experiments is therefore essential in order to facilitate an implementation of passive control in future large wind turbine blades. A test setup based on a four-column MTS servo-hydraulic testing machine with a maximum capacity of 100 kN was developed, see Figure 1. The setup allows installing and testing beams of different cross-sections applying load cases such as axial extension, shear force bending, pure bending in two principal directions as well as pure torsion, see Figure 2. In order to apply multi-axial loading, a load application system consisting of three hydraulic actuators were mounted in two planes using multi-axial servo-hydraulic control. The actuator setup consists of the main actuator on the servo-hydraulic test machine working in the vertical axis (depicted on Figure 1 placed at the testing machine crosshead and used for application of vertical forces to the specimens. Two extra actuators are placed in a horizontal plane on the T-slot table of the test machine in different positions in order to apply loading at the tip of the specimen in various configurations. In order to precisely characterize the global as well as surface deformations of the beam specimens tested, a combination of different measurement systems were used during

  9. Empirical Model Development for Predicting Shock Response on Composite Materials Subjected to Pyroshock Loading

    Science.gov (United States)

    Gentz, Steven J.; Ordway, David O; Parsons, David S.; Garrison, Craig M.; Rodgers, C. Steven; Collins, Brian W.

    2015-01-01

    The NASA Engineering and Safety Center (NESC) received a request to develop an analysis model based on both frequency response and wave propagation analyses for predicting shock response spectrum (SRS) on composite materials subjected to pyroshock loading. The model would account for near-field environment (approx. 9 inches from the source) dominated by direct wave propagation, mid-field environment (approx. 2 feet from the source) characterized by wave propagation and structural resonances, and far-field environment dominated by lower frequency bending waves in the structure. This report documents the outcome of the assessment.

  10. Empirical Model Development for Predicting Shock Response on Composite Materials Subjected to Pyroshock Loading: Appendices

    Science.gov (United States)

    Gentz, Steven J.; Ordway, David O.; Parsons, David S.; Garrison, Craig M.; Rodgers, C. Steven; Collins, Brian W.

    2015-01-01

    The NASA Engineering and Safety Center (NESC) received a request to develop an analysis model based on both frequency response and wave propagation analyses for predicting shock response spectrum (SRS) on composite materials subjected to pyroshock loading. The model would account for near-field environment (approx. 9 inches from the source) dominated by direct wave propagation, mid-field environment (approx. 2 feet from the source) characterized by wave propagation and structural resonances, and far-field environment dominated by lower frequency bending waves in the structure. This document contains appendices to the Volume I report.

  11. Empirical Model Development for Predicting Shock Response on Composite Materials Subjected to Pyroshock Loading. [Appendices

    Science.gov (United States)

    Gentz, Steven J.; Ordway, David O.; Parsons, David S.; Garrison, Craig M.; Rodgers, C. Steven; Collins, Brian W.

    2015-01-01

    The NASA Engineering and Safety Center (NESC) received a request to develop an analysis model based on both frequency response and wave propagation analyses for predicting shock response spectrum (SRS) on composite materials subjected to pyroshock loading. The model would account for near-field environment (9 inches from the source) dominated by direct wave propagation, mid-field environment (approximately 2 feet from the source) characterized by wave propagation and structural resonances, and far-field environment dominated by lower frequency bending waves in the structure. This document contains appendices to the Volume I report.

  12. Load transfer and mechanical properties of chemically reduced graphene reinforcements in polymer composites

    International Nuclear Information System (INIS)

    We report load transfer and mechanical properties of chemically derived single layer graphene (SLG) as reinforcements in poly (dimethyl) siloxane (PDMS) composites. Shear mixing reduced graphene sheets in polymers resulted in a marked decrease of the 2D band intensity due to doping and functionalization. Raman G mode shifts of 11.2 cm−1/% strain in compression and 4.2 cm−1/% strain in tension are reported. Increases in elastic modulus of PDMS by ∼42%, toughness by ∼39%, damping capability by ∼673%, and strain energy density of ∼43% by the addition of 1 wt% SLG in PDMS are reported. (paper)

  13. Capturing the Energy Absorbing Mechanisms of Composite Structures under Crash Loading

    Science.gov (United States)

    Wade, Bonnie

    different test geometries in order to define the range of its energy absorption capability. Further investigation from the crush tests has led to the development of a direct link between geometric features of the crush specimen and its resulting SEA. Through micrographic analysis, distinct failure modes are shown to be guided by the geometry of the specimen, and subsequently are shown to directly influence energy absorption. A new relationship between geometry, failure mode, and SEA has been developed. This relationship has allowed for the reduction of the element-level crush testing requirement to characterize the composite material energy absorption capability. In the numerical investigation, the LS-DYNA composite material model MAT54 is selected for its suitability to model composite materials beyond failure determination, as required by crush simulation, and its capability to remain within the scope of ultimately using this model for large-scale crash simulation. As a result of this research, this model has been thoroughly investigated in depth for its capacity to simulate composite materials in crush, and results from several simulations of the element-level crush experiments are presented. A modeling strategy has been developed to use MAT54 for crush simulation which involves using the experimental data collected from the coupon- and element-level crush tests to directly calibrate the crush damage parameter in MAT54 such that it may be used in higher-level simulations. In addition, the source code of the material model is modified to improve upon its capability. The modifications include improving the elastic definition such that the elastic response to multi-axial load cases can be accurately portrayed simultaneously in each element, which is a capability not present in other composite material models. Modifications made to the failure determination and post-failure model have newly emphasized the post-failure stress degradation scheme rather than the failure

  14. Nonlinear Analysis and Scaling Laws for Noncircular Composite Structures Subjected to Combined Loads

    Science.gov (United States)

    Hilburger, Mark W.; Rose, Cheryl A.; Starnes, James H., Jr.

    2001-01-01

    Results from an analytical study of the response of a built-up, multi-cell noncircular composite structure subjected to combined internal pressure and mechanical loads are presented. Nondimensional parameters and scaling laws based on a first-order shear-deformation plate theory are derived for this noncircular composite structure. The scaling laws are used to design sub-scale structural models for predicting the structural response of a full-scale structure representative of a portion of a blended-wing-body transport aircraft. Because of the complexity of the full-scale structure, some of the similitude conditions are relaxed for the sub-scale structural models. Results from a systematic parametric study are used to determine the effects of relaxing selected similitude conditions on the sensitivity of the effectiveness of using the sub-scale structural model response characteristics for predicting the full-scale structure response characteristics.

  15. Mechanism of Functional Responses to Loading of Carbon Fiber Reinforced Cement-based Composites

    Institute of Scientific and Technical Information of China (English)

    JIANG Cuixiang; LI Zhuoqiu; SONG Xianhui; LU Yong

    2008-01-01

    Single fiber pull-out testing was conducted to study the origin of the functional responses to loading of carbon fiber reinforced cement-based composites.The variation of electrical resistance with the bonding force on the fiber-matrix interface was measured.Single fiber electromechanical testing was also conducted by measuring the electrical resistance under static tension.Comparison of the results shows that the resistance increasing during single fiber pull-out is mainly due to the changes at the interface.The conduction mechanism of the composite can be explained by the tunneling model.The interfacial stress causes the deformation of interfacial structure and the interfacial debonding.which have influences on the tunneling effect and result in the change of resistance.

  16. Diet and environment shape fecal bacterial microbiota composition and enteric pathogen load of grizzly bears.

    Directory of Open Access Journals (Sweden)

    Clarissa Schwab

    Full Text Available BACKGROUND: Diet and environment impact the composition of mammalian intestinal microbiota; dietary or health disturbances trigger alterations in intestinal microbiota composition and render the host susceptible to enteric pathogens. To date no long term monitoring data exist on the fecal microbiota and pathogen load of carnivores either in natural environments or in captivity. This study investigates fecal microbiota composition and the presence of pathogenic Escherichia coli and toxigenic clostridia in wild and captive grizzly bears (Ursus arctos and relates these to food resources consumed by bears. METHODOLOGY/PRINCIPAL FINDINGS: Feces were obtained from animals of two wild populations and from two captive animals during an active bear season. Wild animals consumed a diverse diet composed of plant material, animal prey and insects. Captive animals were fed a regular granulated diet with a supplement of fruits and vegetables. Bacterial populations were analyzed using quantitative PCR. Fecal microbiota composition fluctuated in wild and in captive animals. The abundance of Clostridium clusters I and XI, and of C. perfringens correlated to regular diet protein intake. Enteroaggregative E. coli were consistently present in all populations. The C. sordellii phospholipase C was identified in three samples of wild animals and for the first time in Ursids. CONCLUSION: This is the first longitudinal study monitoring the fecal microbiota of wild carnivores and comparing it to that of captive individuals of the same species. Location and diet affected fecal bacterial populations as well as the presence of enteric pathogens.

  17. Hygrothermal Analysis and Failure Analysis of Composite Beams under Moving Loads

    Science.gov (United States)

    Hanif, Moiz

    Excellent combination of high structural stiffness and low weight are the qualities of composite material leading to the extensive work on such materials. In order to achieve the desired performance requirements, the designer has to take into consideration the structural requirements and the functional characteristics. Thus, in this study, the effect of hygrothermal conditions on fiber reinforced composite laminates with moving loads have been extensively studied and has been carried out that accompanies Classical Laminate Plate Theory (CLPT) as well as First Order Shear Deformation Theory (FSDT) on MATLAB. A glass/epoxy composite system has been chosen for study with which similar results may be expected for other laminated composites. The hygrothermal effect is incorporated by adjusting the stiffness coefficients of the laminate to its level of moisture concentration using empirical relations. The failure analysis is done using the maximum normal stress criterion and the factor of safety for the lamina calculated and compared with respect to the corresponding maximum stresses and strengths. Different fiber volume fraction with varying fiber orientation of the plies in the laminate were modeled and studied. The results presented show the effect of stresses and strains in dry conditions, whereas for hygrothermal analysis, they also indicate that not all the laminates behave in a similar fashion and so it is possible by selecting the proper laminate configuration, the effect of moisture can be reduced. Also deducing, that due to hygrothermal effects, changes in the stiffness coefficients of a laminate do not appear to affect the deflection results significantly.

  18. Effect of Static and Cyclic Loading on Ceramic Laminate Veneers Adhered to Teeth with and Without Aged Composite Restorations

    NARCIS (Netherlands)

    Gresnigt, Marco M. M.; Ozcan, Mutlu; Kalk, Warner; Galhano, Graziela

    2011-01-01

    Purpose: Existing composite restorations on teeth are often remade prior to the cementation of fixed dental prostheses. The aim of this study was to evaluate the effect of static and cyclic loading on ceramic laminate veneers adhered to aged resin composite restorations. Materials and Methods: Eight

  19. Mechanical interaction of Engineered Cementitious Composite (ECC) reinforced with Fiber Reinforced Polymer (FRP) rebar in tensile loading

    DEFF Research Database (Denmark)

    Lárusson, Lárus Helgi; Fischer, Gregor; Jönsson, Jeppe

    2010-01-01

    This paper introduces a preliminary study of the composite interaction of Engineered Cementitious Composite (ECC), reinforced with Glass Fiber Reinforced Polymer (GFRP) rebar. The main topic of this paper will focus on the interaction of the two materials (ECC and GFRP) during axial loading...

  20. Genetic algorithm based optimal control of smart composite shell structures under mechanical loading and thermal gradient

    International Nuclear Information System (INIS)

    In the present paper an improved genetic algorithm (GA) based linear quadratic regulator (LQR) control scheme has been proposed for active vibration control of smart fiber reinforced polymer (FRP) composite shell structures under combined mechanical and thermal loading. A layered shell finite element formulation has been done to obtain the electro-thermo-mechanical response of fiber reinforced polymer (FRP) composite shell structures bonded with piezoelectric patches. Based on the responses obtained from finite element analysis, a real coded GA based improved LQR control scheme has been incorporated, which maximizes the closed loop damping while keeping the actuator voltages within limit. It has been observed that the developed FE code can be used for determination of the accurate response of smart FRP shell structures for the simulation of active vibration control of such structures. The proposed GA based LQR control scheme could control both dynamic oscillation due to mechanical load as well as the static displacement due to a thermal gradient, which was not possible with conventional LQR control scheme

  1. Geometrically nonlinear bending analysis of Metal-Ceramic composite beams under thermomechanical loading

    Science.gov (United States)

    Torabizadeh, Mohammad Amin

    2013-07-01

    A new method is developed to derive equilibrium equations of Metal-Ceramic beams based on first order shear deformation plate theory which is named first order shear deformation beam theory2(FSDBT2). Equilibrium equations obtained from conventional method (FSDBT1) is compared with FSDBT2 and the case of cylindrical bending of Metal-Ceramic composite plates for non-linear thermomechanical deformations and various loadings and boundary conditions. These equations are solved by using three different methods (analytical, perturbation technique and finite element solution). The through-thickness variation of the volume fraction of the ceramic phase in a Metal-Ceramic beam is assumed to be given by a power-law type function. The non-linear strain-displacement relations in the von-Kármán sense are used to study the effect of geometric non-linearity. Also, four other representative averaging estimation methods, the linear rule, Mori-Tanaka, Self-Consistent and Wakashima-Tsukamoto schemes, by comparing with the power-law type function are also investigated. Temperature distribution through the thickness of the beams in thermal loadings is obtained by solving the one-dimensional heat transfer equation. Finally it is concluded that for Metal-Ceramic composites, these two theories result in identical static responses. Also the displacement field and equilibrium equations in the case of cylindrical bending of Metal-Ceramic plates are the same as those supposed in FSDBT2.

  2. Edge delamination of composite laminates subject to combined tension and torsional loading

    Science.gov (United States)

    Hooper, Steven J.

    1990-01-01

    Delamination is a common failure mode of laminated composite materials. Edge delamination is important since it results in reduced stiffness and strength of the laminate. The tension/torsion load condition is of particular significance to the structural integrity of composite helicopter rotor systems. Material coupons can easily be tested under this type of loading in servo-hydraulic tension/torsion test stands using techniques very similar to those used for the Edge Delamination Tensile Test (EDT) delamination specimen. Edge delamination of specimens loaded in tension was successfully analyzed by several investigators using both classical laminate theory and quasi-three dimensional (Q3D) finite element techniques. The former analysis technique can be used to predict the total strain energy release rate, while the latter technique enables the calculation of the mixed-mode strain energy release rates. The Q3D analysis is very efficient since it produces a three-dimensional solution to a two-dimensional domain. A computer program was developed which generates PATRAN commands to generate the finite element model. PATRAN is a pre- and post-processor which is commonly used with a variety of finite element programs such as MCS/NASTRAN. The program creates a sufficiently dense mesh at the delamination crack tips to support a mixed-mode fracture mechanics analysis. The program creates a coarse mesh in those regions where the gradients in the stress field are low (away from the delamination regions). A transition mesh is defined between these regions. This program is capable of generating a mesh for an arbitrarily oriented matrix crack. This program significantly reduces the modeling time required to generate these finite element meshes, thus providing a realistic tool with which to investigate the tension torsion problem.

  3. Studies on LCST of poly (N-isopropylacrylamide-co-acrylic acid-co-N-diacetone acrylamide)

    Institute of Scientific and Technical Information of China (English)

    Cai Hua Ni; Xiao Xia Zhu; Qing Lan Wang; Xian Yu Zeng

    2007-01-01

    Linear copolymers from N-isopropylacrylamide (NIPA), acrylic acid (AA) and diacetone acrylamide (DAA) have been prepared.The effect of composition, ionic strength and pH on their lower critical solution temperature (LCST) has been investigated.

  4. In vitro release studies of vitamin B12 from poly N-vinyl pyrrolidone /starch hydrogels grafted with acrylic acid synthesized by gamma radiation

    International Nuclear Information System (INIS)

    Co-polymeric hydrogels containing N-vinyl pyrrolidone and starch grafted with acrylic acid were synthesized by gamma radiation. Their gel contents, grafting process and swelling were evaluated. The gels were also characterized by thermal gravimetric analysis. The gel content found to be increase with increasing the irradiation dose up to 50 kGy then decrease. The grafting percent increase by increasing the percentage of acrylic acid in the grafted hydrogels. The thermal stability and the rate of the thermal decomposition showed to be changed according to the different composition of the hydrogels. It also showed a decrease in the maximum rate of the thermal decomposition by the increasing of the irradiation dose from 20 to 30 kGy and increases by increasing the irradiation dose from 30 to 70 kGy. The hydrogels loaded with vitamin B12 as drug model, demonstrated a decrease release in acidic medium than the neutral one

  5. Novel bioresorbabale composite fiber structures loaded with proteins for tissue regeneration applications: microstructure and protein release.

    Science.gov (United States)

    Levy, Yair; Zilberman, Meital

    2006-12-15

    Novel bioresorbable core/shell composite fiber structures loaded with proteins were developed and studied. These unique polymeric structures are designed to combine good mechanical properties with a desired controlled protein-release profile, to serve as scaffolds for tissue regeneration applications. Core/shell fiber structures were formed by "coating" poly(L-lactic acid) fibers with protein-containing poly(DL-lactic-co-glycolic acid) porous structures. Shell preparation (coating) was performed by the freeze-drying of water in oil emulsions. The present study focused on the effect of the emulsion's formulation on the porous shell structure and on the resulting cumulative protein release from the composite fibers for 90 days. Horseradish peroxidase (HRP) was used as the protein source. The release profiles usually exhibited an initial burst effect, accompanied by a decrease in release rate with time, as is typical for diffusion-controlled systems. The HRP content and the emulsion's organic:aqueous phase ratio exhibited significant effects on both the shell microstructure and the HRP release profile from the composite fibers, whereas the polymer content of the emulsion's organic phase only affected these fiber characteristics in certain cases. Proper selection of the emulsion's parameters can yield core/shell fiber structures with the desired protein release behavior and other useful physical properties. PMID:16883584

  6. Uncertainty in nutrient loads from tile-drained landscapes: Effect of sampling frequency, calculation algorithm, and compositing strategy

    Science.gov (United States)

    Williams, Mark R.; King, Kevin W.; Macrae, Merrin L.; Ford, William; Van Esbroeck, Chris; Brunke, Richard I.; English, Michael C.; Schiff, Sherry L.

    2015-11-01

    Accurate estimates of annual nutrient loads are required to evaluate trends in water quality following changes in land use or management and to calibrate and validate water quality models. While much emphasis has been placed on understanding the uncertainty of nutrient load estimates in large, naturally drained watersheds, few studies have focused on tile-drained fields and small tile-drained headwater watersheds. The objective of this study was to quantify uncertainty in annual dissolved reactive phosphorus (DRP) and nitrate-nitrogen (NO3-N) load estimates from four tile-drained fields and two small tile-drained headwater watersheds in Ohio, USA and Ontario, Canada. High temporal resolution datasets of discharge (10-30 min) and nutrient concentration (2 h to 1 d) were collected over a 1-2 year period at each site and used to calculate a reference nutrient load. Monte Carlo simulations were used to subsample the measured data to assess the effects of sample frequency, calculation algorithm, and compositing strategy on the uncertainty of load estimates. Results showed that uncertainty in annual DRP and NO3-N load estimates was influenced by both the sampling interval and the load estimation algorithm. Uncertainty in annual nutrient load estimates increased with increasing sampling interval for all of the load estimation algorithms tested. Continuous discharge measurements and linear interpolation of nutrient concentrations yielded the least amount of uncertainty, but still tended to underestimate the reference load. Compositing strategies generally improved the precision of load estimates compared to discrete grab samples; however, they often reduced the accuracy. Based on the results of this study, we recommended that nutrient concentration be measured every 13-26 h for DRP and every 2.7-17.5 d for NO3-N in tile-drained fields and small tile-drained headwater watersheds to accurately (±10%) estimate annual loads.

  7. Experimental Analysis of Repaired Masonry Elements with Flax-FRCM and PBO-FRCM Composites Subjected to Axial Bending Loads

    Directory of Open Access Journals (Sweden)

    Oscar A. Cevallos

    2015-11-01

    Full Text Available In the construction industry, the use of natural fabrics as a reinforcement for cement-based composites has shown great potential. The use of these sustainable composites to provide strengthening or repair old masonry structures that exhibit structural problems mainly due to a poor tensile strength of the mortar/brick joints is revealed to be a promising area of research. One of the most significant load conditions affecting the mechanical response of masonry structures occurs when axial bending loads are applied on the resistant cross-section. In this study, three different types of masonry elements were built using clay bricks and a lime-based mortar. After 28 days, the samples were subjected to concentric and eccentric compressive loads. In order to produce significant bending effects, the compressive loads were applied with large eccentricity, and a sudden failure characterized the behavior of the unreinforced masonry (URM elements. The tested masonry specimens were repaired using fabric-reinforced cementitious matrix (FRCM composites produced using bi-directional flax and polyparaphenylene benzobisoxazole (PBO fabrics. The mechanical behavior of the URM and repaired samples was compared in terms of load-displacement and moment-curvature responses. Furthermore, the results achieved using flax-FRCM composites were compared with those of using PBO-FRCM composites.

  8. Influence of Reaction-Induced Phase Decomposition to Dispersion of Samariam Acrylic Acid (Sm (AA)3 ) in Rubber and Shielding Property of Sm(AA) 3/NR Composites

    Institute of Scientific and Technical Information of China (English)

    Liu Li; He Lei; Zhang Wan; Yang Cheng; Liu Yandong; Jin Riguang; Zhang Liqun

    2004-01-01

    According to radiation protection theory, the radiation shielding properties of composites are closely related to dispersion condition of radiation absorbing materials in matrix. The more equably radiation-shielding materials dispersed in the matrix, the better the composites' shielding properties are. Rare earth ions have preferably absorbing ability for radiation due to their special electronic structures. From our early work, we know Sm(AA) 3 has good radiationabsorbing ability and excellent compatibility with polymer matrix. Furthermore, Sm (AA) 3 has double key structures which can in-situ react with polymer matrix in vulcanization process. This in-situ reaction can also help Sm(AA) 3 disperse better in the matrix. Based on these, we studied a new method to prepare Sm( AA)3/NR( nature rubber) composites( NR used as matrix), in which Sm(AA)3 dispersed very equably with tiny particle size. Both sulfur and peroxide exist in the system as crosslinking agent. The vulcanization process occurred at the temperature of 110℃ first and a certain degree crosslinking network formed in this stage, which we called pre-vulcanization process in this paper. In this stage sulfur was used as the crosslinking agent. Then continued the vulcanization process at higher temperature(170℃). The peroxide was used as crosslinking agent in this stage. According to reaction-induced phase decomposition mechanism, we studied the phase decomposition changing mode of Sm(AA) 3 in NR matrix of different crosslinking degrees. We also studied the influence of different degrees of pre-vulcanization to the dispersion condition of Sm (AA) 3 in NR matrix. The crystal-fusion status of both Sm(AA) 3 powder and Sm(AA) 3 in cured rubber were observed by DSC (Differential Scanning Calorimetry) and XRD (X-rays Diffraction). The dispersion condition of Sm(AA) 3 in cured rubber was observed by SEM (Scanning Electron Microscopy) and TEM (Transmission Electron Microscope).The studyresults show different

  9. The effect of acrylic resin functionality on the curing process and properties of acrylic-hexamethoxymethylmelamine coatings

    Directory of Open Access Journals (Sweden)

    Prendžov Slobodan J.

    2002-01-01

    Full Text Available In this paper the effect of the functionality of synthesized thermosetting acrylic resins (with hydroxy and carboxy groups and the cure temperature on the process of crosslinking and properties of the coatings was investigated. Methylated melamine resin, characterized by 1H and C NMR was used as the crosslinking agent. The degree of crosslinking was studied by infrared spectroscopy by determining the conversion of functional groups and the sol fraction. On the basis of the results obtained it was found that compositions with lower functionality of the acrylic resin had a higher conversion of functional groups, during which cocondensation reactions occurred (acrylic melamine crosslinks in a wide temperature crosslinking range. Consequently better control of the coating properties was achieved. The degree of crosslinking was in good correlation to the sol fraction content and the resin hardness.

  10. Geochemical composition of river loads in the Tropical Andes: first insights from the Ecuadorian Andes

    Science.gov (United States)

    Tenorio Poma, Gustavo; Govers, Gerard; Vanacker, Veerle; Bouillon, Steven; Álvarez, Lenín; Zhiminaicela, Santiago

    2015-04-01

    Processes governing the transport of total suspended material (TSM), total dissolved solids (TDS) and particulate organic carbon (POC) are currently not well known for Tropical Andean river systems. We analyzed the geochemical behavior and the budgets of the particulate and dissolved loads for several sub-catchments in the Paute River basin in the southern Ecuadorian Andes, and examined how anthropogenic activities influenced the dynamics of riverine suspended and dissolved loads. We gathered a large dataset by regularly sampling 8 rivers for their TSM, POC, and TDS. Furthermore, we determined the major elements in the dissolved load and stable isotope composition (δ13C) of both the POC, and the dissolved inorganic carbon (DIC). The rivers that were sampled flow through a wide range of land uses including: 3 nature conservation areas (100 - 300 Km²), an intensive grassland and arable zone (142 Km²); downstream of two cities (1611 and 443 Km²), and 2 degraded basins (286 and 2492 Km²). We described the geochemical characteristics of the river loads both qualitatively and quantitatively. Important differences in TSM, POC and TDS yields were found between rivers: the concentration of these loads increases according with human activities within the basins. For all rivers, TSM, TDS and POC concentrations were dependent on discharge. Overall, a clear relation between TSM and POC (r²=0.62) was observed in all tributaries. The C:N ratios and δ13CPOC suggest that the POC in most rivers is mainly derived from soil organic matter eroded from soils dominated by C3 vegetation (δ13CPOC < -22‰). Low Ca:Si ratios (<1)and high δ13CDIC (-9 to -4) in the Yanuncay, Tomebamba1 and Machángara, rivers suggest that weathering of silica rocks is dominant in these catchments, and that the DIC is mainly derived from the soil or atmospheric CO2. In contrast, the Ca:Si ratio was high for the Burgay and Jadán rivers (1-13), and the low δ13CDIC values (-9 to -15) suggest that

  11. Composite bone cements loaded with a bioactive and ferrimagnetic glass-ceramic: Leaching, bioactivity and cytocompatibility.

    Science.gov (United States)

    Verné, Enrica; Bruno, Matteo; Miola, Marta; Maina, Giovanni; Bianco, Carlotta; Cochis, Andrea; Rimondini, Lia

    2015-08-01

    In this work, composite bone cements, based on a commercial polymethylmethacrylate matrix (Palamed®) loaded with ferrimagnetic bioactive glass-ceramic particles (SC45), were produced and characterized in vitro. The ferrimagnetic bioactive glass-ceramic belongs to the system SiO2-Na2O-CaO-P2O5-FeO-Fe2O3 and contains magnetite (Fe3O4) crystals into a residual amorphous bioactive phase. Three different formulations (containing 10, 15 and 20 wt.% of glass-ceramic particles respectively) have been investigated. These materials are intended to be applied as bone fillers for the hyperthermic treatment of bone tumors. The morphological, compositional, calorimetric and mechanical properties of each formulation have been already discussed in a previous paper. The in vitro properties of the composite bone cements described in the present paper are related to iron ion leaching test (by graphite furnace atomic absorption spectrometer), bioactivity (i.e. the ability to stimulate the formation of a hydroxyapatite - HAp - layer on their surface after soaking in simulated body fluid SBF) and cytocompatibility toward human osteosarcoma cells (ATCC CRL-1427, Mg63). Morphological and chemical characterizations by scanning electron microscopy and energy dispersion spectrometry have been performed on the composite samples after each test. The iron release was negligible and all the tested samples showed the growth of HAp on their surface after 28 days of immersion in a simulated body fluid (SBF). Cells showed good viability, morphology, adhesion, density and the ability to develop bridge-like structures on all investigated samples. A synergistic effect between bioactivity and cell mineralization was also evidenced. PMID:26042695

  12. Evaluation of interlaminar shear strength of a unidirectional carbon/epoxy laminated composite under impact loading

    Science.gov (United States)

    Yokoyama, T.; Nakai, K.

    2006-08-01

    The interlaminar shear strength (ILSS) of a unidirectional carbon/epoxy (T700/2521) laminated composite under impact loading is determined using the conventional split Hopkinson pressure bar. Double-notch shear (DNS) specimens with lateral constraint from a supporting jig are used in the static and impact interlaminar compressive shear tests. Short-beam shear specimens are also used under static 3-point bending. Numerical stress analyses are performed to determine the shear stress and normal stress distributions on the expected failure plane in the DNS specimen using the MSC/NASTRAN package. The effect of deformation rate on the ILSS and failure mode is investigated. It is observed that the ILSS is independent of the deformation rate up to nearly 1.5m/s (dotγ ≈ 780/s). The validity of the test results is confirmed by microscopic examinations of both static and impact failure surfaces for the DNS specimens.

  13. A subregional model for delamination prediction of rubber composite under fatigue loading

    Institute of Scientific and Technical Information of China (English)

    TIAN Zhen-hui; TAN Hui-feng

    2005-01-01

    Results from fatigue experiments of cross-laminated steel cord-rubber composites (SCRC) indicate that fatigue damage life can be categorized into three regimes. In terms of fatigue modes, a subregional fatigue model is developed to describe the damages evolution of SCRC under fatigue loads. Firstly, finite element analysis is introduced to determine interply stress distribution of the specimen. Then, based on the experimental fatigue data, subregional models are introduced to simulate relations between maximum strain, effective stiffness,delamination shear stress and fatigue cycles. Relations between crack density, delamination length growth rate,macro crack density and cycles are modeled by two semi-empirical models. A reasonable prediction result was achieved by the current model, where model parameters can be determined by basic outputs of fatigue testing.

  14. A method for the geometrically nonlinear analysis of compressively loaded prismatic composite structures

    Science.gov (United States)

    Stoll, Frederick; Gurdal, Zafer; Starnes, James H., Jr.

    1991-01-01

    A method was developed for the geometrically nonlinear analysis of the static response of thin-walled stiffened composite structures loaded in uniaxial or biaxial compression. The method is applicable to arbitrary prismatic configurations composed of linked plate strips, such as stiffened panels and thin-walled columns. The longitudinal ends of the structure are assumed to be simply supported, and geometric shape imperfections can be modeled. The method can predict the nonlinear phenomena of postbuckling strength and imperfection sensitivity which are exhibited by some buckling-dominated structures. The method is computer-based and is semi-analytic in nature, making it computationally economical in comparison to finite element methods. The method uses a perturbation approach based on the use of a series of buckling mode shapes to represent displacement contributions associated with nonlinear response. Displacement contributions which are of second order in the model amplitudes are incorported in addition to the buckling mode shapes. The principle of virtual work is applied using a finite basis of buckling modes, and terms through the third order in the model amplitudes are retained. A set of cubic nonlinear algebraic equations are obtained, from which approximate equilibrium solutions are determined. Buckling mode shapes for the general class of structure are obtained using the VIPASA analysis code within the PASCO stiffened-panel design code. Thus, subject to some additional restrictions in loading and plate anisotropy, structures which can be modeled with respect to buckling behavior by VIPASA can be analyzed with respect to nonlinear response using the new method. Results obtained using the method are compared with both experimental and analytical results in the literature. The configurations investigated include several different unstiffened and blade-stiffening panel configurations, featuring both homogeneous, isotropic materials, and laminated composite

  15. Bonding auto-polymerising acrylic resin to acrylic denture teeth.

    LENUS (Irish Health Repository)

    Nagle, Susan

    2009-09-01

    This study investigated the effect of surface treatments on the shear bond strength of an auto-polymerising acrylic resin cured to acrylic denture teeth. The surface treatments included a combination of grit-blasting and\\/or wetting the surface with monomer. Samples were prepared and then stored in water prior to shear testing. The results indicated that the application of monomer to the surface prior to bonding did not influence the bond strength. Grit blasting was found to significantly increase the bond strength.

  16. Modeling Delamination in Postbuckled Composite Structures Under Static and Fatigue Loads

    Science.gov (United States)

    Bisagni, Chiara; Brambilla, Pietro; Bavila, Carlos G.

    2013-01-01

    The ability of the Abaqus progressive Virtual Crack Closure Technique (VCCT) to model delamination in composite structures was investigated for static, postbuckling, and fatigue loads. Preliminary evaluations were performed using simple Double Cantilever Beam (DCB) and Mixed-Mode Bending (MMB) specimens. The nodal release sequences that describe the propagation of the delamination front were investigated. The effect of using a sudden or a gradual nodal release was evaluated by considering meshes aligned with the crack front as well as misaligned meshes. Fatigue simulations were then performed using the Direct Cyclic Fatigue (DCF) algorithm. It was found that in specimens such as the DCB, which are characterized by a nearly linear response and a pure fracture mode, the algorithm correctly predicts the Paris Law rate of propagation. However, the Abaqus DCF algorithm does not consider different fatigue propagation laws in different fracture modes. Finally, skin/stiffener debonding was studied in an aircraft fuselage subcomponent in which debonding occurs deep into post-buckling deformation. VCCT was shown to be a robust tool for estimating the onset propagation. However, difficulties were found with the ability of the current implementation of the Abaqus progressive VCCT to predict delamination propagation within structures subjected to postbuckling deformations or fatigue loads.

  17. Structural Performance of a Compressively Loaded Foam-Core Hat-Stiffened Textile Composite Panel

    Science.gov (United States)

    Ambur, Damodar R.; Dexter, Benson H.

    1996-01-01

    A structurally efficient hat-stiffened panel concept that utilizes a structural foam as a stiffener core material has been designed and developed for aircraft primary structural applications. This stiffener concept is fabricated from textile composite material forms with a resin transfer molding process. This foam-filled hat-stiffener concept is structurally more efficient than most other prismatically stiffened panel configurations in a load range that is typical for both fuselage and wing structures. The panel design is based on woven/stitched and braided graphite-fiber textile preforms, an epoxy resin system, and Rohacell foam core. The structural response of this panel design was evaluated for its buckling and postbuckling behavior with and without low-speed impact damage. The results from single-stiffener and multi-stiffener specimen tests suggest that this structural concept responds to loading as anticipated and has excellent damage tolerance characteristics compared to a similar panel design made from preimpregnated graphite-epoxy tape material.

  18. Matrix Dominated Failure of Fiber-Reinforced Composite Laminates Under Static and Dynamic Loading

    Science.gov (United States)

    Schaefer, Joseph Daniel

    Hierarchical material systems provide the unique opportunity to connect material knowledge to solving specific design challenges. Representing the quickest growing class of hierarchical materials in use, fiber-reinforced polymer composites (FRPCs) offer superior strength and stiffness-to-weight ratios, damage tolerance, and decreasing production costs compared to metals and alloys. However, the implementation of FRPCs has historically been fraught with inadequate knowledge of the material failure behavior due to incomplete verification of recent computational constitutive models and improper (or non-existent) experimental validation, which has severely slowed creation and development. Noted by the recent Materials Genome Initiative and the Worldwide Failure Exercise, current state of the art qualification programs endure a 20 year gap between material conceptualization and implementation due to the lack of effective partnership between computational coding (simulation) and experimental characterization. Qualification processes are primarily experiment driven; the anisotropic nature of composites predisposes matrix-dominant properties to be sensitive to strain rate, which necessitates extensive testing. To decrease the qualification time, a framework that practically combines theoretical prediction of material failure with limited experimental validation is required. In this work, the Northwestern Failure Theory (NU Theory) for composite lamina is presented as the theoretical basis from which the failure of unidirectional and multidirectional composite laminates is investigated. From an initial experimental characterization of basic lamina properties, the NU Theory is employed to predict the matrix-dependent failure of composites under any state of biaxial stress from quasi-static to 1000 s-1 strain rates. It was found that the number of experiments required to characterize the strain-rate-dependent failure of a new composite material was reduced by an order of

  19. Numerical and experimental analysis on load sharing & optimization of the joint parameters of polymer composite multi bolted joints

    Science.gov (United States)

    Latha Shankar, B.; Sudeep Kumar, T.; Shiva Shankar, G. S.

    2016-09-01

    In the present work, the bearing failure of composite bolted connections of composite laminates was analysed both experimentally and numerically. The glass fiber woven mat 600GSM/ epoxy composite laminates were prepared using wet-layup technique. The process parameters were taken care during preparation of laminates. Examination is done for various estimations of edge-to-hole diameter and width-to-hole diameter proportion. Stress is evaluated in laminates by utilizing Hart-Smith criteria. Ideal estimation of e/d proportion, d/w proportion is recommended for most extreme effectiveness. A numerical technique is utilized for the rough determination of a load shared by bolts in a numerous "bolted" joints loaded in tension were investigated experimentally and numerically. The effect of un-evenness in load shearing is suggested.

  20. Buckling analysis of rectangular composite plates with rectangular cutout subjected to linearly varying in-plane loading using fem

    Indian Academy of Sciences (India)

    A Lakshmi Narayana; Krishnamohana Rao; R Vijaya Kumar

    2014-06-01

    A numerical study is carried out using finite element method, to examine the effects of square and rectangular cutout on the buckling behavior of a sixteen ply quasi-isotropic graphite/epoxy symmetrically laminated rectangular composite plate $[0^\\circ /+45^\\circ /-45^\\circ /90^\\circ ]_{2s}$, subjected to various linearly varying in-plane compressive loads. Further, this paper addresses the effects of size of square/rectangular cutout, orientation of square/rectangular cutout, plate aspect ratio(a/b), plate length/thickness ratio(a/t), boundary conditions on the buckling bahaviour of symmetrically laminated rectangular composite plates subjected to various linearly varying in-plane compressive loading. It is observed that the various linearly varying in-plane loads and boundary conditions have a substantial influence on buckling strength of rectangular composite plate with square/rectangular cutout.

  1. Preparation and characterization of water-based polyurethane acrylate/graphene oxide composite emulsion%水基聚氨酯丙烯酸酯/氧化石墨烯复合乳液的制备与表征

    Institute of Scientific and Technical Information of China (English)

    费贵强; 王佼; 王海花; 朱科; 郭丹慧

    2016-01-01

    Using flake graphite as a raw material ,graphite oxide was prepared by modified Hummers method ,and graphene oxide was obtained by ultrasonic process .A series of water‐based polyurethane acrylate/graphene oxide composite emulsion was prepared by in situ pol‐ymerization ,and the effects of different graphene oxide content of the latex film thermal sta‐bility and water absorption rate were researched .The results showed that :preparing a high degree of oxidation of graphene oxide ,the water absorption of film decreases first ,then in‐creases with increasing graphene oxide content .When the graphene oxide content was 0 .5% , the thermal stability of the film was preferably .%以天然石墨为原料,采用改进的 Hummers法制备了氧化石墨,进而超声剥离制备了氧化石墨烯.通过原位聚合法制备了系列水基聚氨酯丙烯酸酯/氧化石墨烯复合乳液,并研究了不同氧化石墨烯含量对乳胶膜热稳定性和吸水率的影响.实验结果表明:制备了氧化程度较高的氧化石墨烯,随着氧化石墨烯含量的增加,胶膜的吸水率先减小后增大.当氧化石墨烯的含量为0.5%时,胶膜的热稳定性最好.

  2. Effective load transfer by a chromium carbide nanostructure in a multi-walled carbon nanotube/copper matrix composite

    International Nuclear Information System (INIS)

    Multi-walled carbon nanotube (MWCNT) reinforced copper (Cu) matrix composites, which exhibit chromium (Cr) carbide nanostructures at the MWCNT/Cu interface, were prepared through a carbide formation using CuCr alloy powder. The fully densified and oriented MWCNTs dispersed throughout the composites were prepared using spark plasma sintering (SPS) followed by hot extrusion. The tensile strengths of the MWCNT/CuCr composites increased with increasing MWCNTs content, while the tensile strength of MWCNT/Cu composite decreased from that of monolithic Cu. The enhanced tensile strength of the MWCNT/CuCr composites is a result of possible load-transfer mechanisms of the interfacial Cr carbide nanostructures. The multi-wall failure of MWCNTs observed in the fracture surface of the MWCNT/CuCr composites indicates an improvement in the load-bearing capacity of the MWCNTs. This result shows that the Cr carbide nanostructures effectively transferred the tensile load to the MWCNTs during fracture through carbide nanostructure formation in the MWCNT/Cu composite. (paper)

  3. Effective load transfer by a chromium carbide nanostructure in a multi-walled carbon nanotube/copper matrix composite

    Science.gov (United States)

    Cho, Seungchan; Kikuchi, Keiko; Kawasaki, Akira; Kwon, Hansang; Kim, Yangdo

    2012-08-01

    Multi-walled carbon nanotube (MWCNT) reinforced copper (Cu) matrix composites, which exhibit chromium (Cr) carbide nanostructures at the MWCNT/Cu interface, were prepared through a carbide formation using CuCr alloy powder. The fully densified and oriented MWCNTs dispersed throughout the composites were prepared using spark plasma sintering (SPS) followed by hot extrusion. The tensile strengths of the MWCNT/CuCr composites increased with increasing MWCNTs content, while the tensile strength of MWCNT/Cu composite decreased from that of monolithic Cu. The enhanced tensile strength of the MWCNT/CuCr composites is a result of possible load-transfer mechanisms of the interfacial Cr carbide nanostructures. The multi-wall failure of MWCNTs observed in the fracture surface of the MWCNT/CuCr composites indicates an improvement in the load-bearing capacity of the MWCNTs. This result shows that the Cr carbide nanostructures effectively transferred the tensile load to the MWCNTs during fracture through carbide nanostructure formation in the MWCNT/Cu composite.

  4. Micro/nano composited tungsten material and its high thermal loading behavior

    Energy Technology Data Exchange (ETDEWEB)

    Fan, Jinglian, E-mail: fjl@csu.edu.cn; Han, Yong; Li, Pengfei; Sun, Zhiyu; Zhou, Qiang

    2014-12-15

    Tungsten (W) is considered as promising candidate material for plasma facing components (PFCs) in future fusion reactors attributing to its many excellent properties. Current commercial pure tungsten material in accordance with the ITER specification can well fulfil the performance requirements, however, it has defects such as coarse grains, high ductile–brittle transition temperature (DBTT) and relatively low recrystallization temperature compared with its using temperature, which cannot meet the harsh wall loading requirement of future fusion reactor. Grain refinement has been reported to be effective in improving the thermophysical and mechanical properties of W. In this work, rare earth oxide (Y{sub 2}O{sub 3}/La{sub 2}O{sub 3}) and carbides (TiC/ZrC) were used as dispersion phases to refine W grains, and micro/nano composite technology with a process of “sol gel – heterogeneous precipitation – spray drying – hydrogen reduction – ordinary consolidation sintering” was invented to introduce these second-phase particles uniformly dispersed into W grains and grain-boundaries. Via this technology, fine-grain W materials with near-full density and relatively high mechanical properties compared with traditional pure W material were manufactured. Preliminary transient high-heat flux tests were performed to evaluate the thermal response under plasma disruption conditions, and the results show that the W materials prepared by micro/nano composite technology can endure high-heat flux of 200 MW/m{sup 2} (5 ms)

  5. Micro/nano composited tungsten material and its high thermal loading behavior

    International Nuclear Information System (INIS)

    Tungsten (W) is considered as promising candidate material for plasma facing components (PFCs) in future fusion reactors attributing to its many excellent properties. Current commercial pure tungsten material in accordance with the ITER specification can well fulfil the performance requirements, however, it has defects such as coarse grains, high ductile–brittle transition temperature (DBTT) and relatively low recrystallization temperature compared with its using temperature, which cannot meet the harsh wall loading requirement of future fusion reactor. Grain refinement has been reported to be effective in improving the thermophysical and mechanical properties of W. In this work, rare earth oxide (Y2O3/La2O3) and carbides (TiC/ZrC) were used as dispersion phases to refine W grains, and micro/nano composite technology with a process of “sol gel – heterogeneous precipitation – spray drying – hydrogen reduction – ordinary consolidation sintering” was invented to introduce these second-phase particles uniformly dispersed into W grains and grain-boundaries. Via this technology, fine-grain W materials with near-full density and relatively high mechanical properties compared with traditional pure W material were manufactured. Preliminary transient high-heat flux tests were performed to evaluate the thermal response under plasma disruption conditions, and the results show that the W materials prepared by micro/nano composite technology can endure high-heat flux of 200 MW/m2 (5 ms)

  6. Correspondence Analysis of Soil around Micropile Composite Structures under Horizontal Load

    Directory of Open Access Journals (Sweden)

    Hai Shi

    2015-01-01

    Full Text Available The current approach, which is based on conformal transformation, is to map micropile holes in comparison with unit circle domain. The stress field of soil around a pile plane, as well as the plane strain solution to displacement field distribution, can be obtained by adopting complex variable functions of elastic mechanics. This paper proposes an approach based on Winkler Foundation Beam Model, with the assumption that the soil around the micropiles stemmed from a series of independent springs. The rigidity coefficient of the springs is to be obtained from the planar solution. Based on the deflection curve differential equation of Euler-Bernoulli beams, one can derive the pile deformation and internal force calculation method of micropile composite structures under horizontal load. In the end, we propose reinforcing highway landslides with micropile composite structure and conducting on-site pile pushing tests. The obtained results from the experiment were then compared with the theoretical approach. It has been indicated through validation analysis that the results obtained from the established theoretical approach display a reasonable degree of accuracy and reliability.

  7. Preparation and Characterization of New Nano-Composite Scaffolds Loaded With Vascular Stents

    Directory of Open Access Journals (Sweden)

    Tianbin Ren

    2012-03-01

    Full Text Available In this study, vascular stents were fabricated from poly (lactide-ε-caprolactone/collagen/nano-hydroxyapatite (PLCL/Col/nHA by electrospinning, and the surface morphology and breaking strength were observed or measured through scanning electron microscopy and tensile tests. The anti-clotting properties of stents were evaluated for anticoagulation surfaces modified by the electrostatic layer-by-layer self-assembly technique. In addition, nano-composite scaffolds of poly (lactic-co-glycolic acid/polycapr-olactone/nano-hydroxyapatite (PLGA/PCL/nHA loaded with the vascular stents were prepared by thermoforming-particle leaching and their basic performance and osteogenesis were tested in vitro and in vivo. The results show that the PLCL/Col/nHA stents and PLGA/PCL/nHA nano-composite scaffolds had good surface structures, mechanical properties, biocompatibility and could guide bone regeneration. These may provide a new way to build vascularized-tissue engineered bone to repair large bone defects in bone tissue engineering.

  8. Fatigue crack growth behavior of a titanium matrix composite under thermomechanical loading. Doctoral thesis

    Energy Technology Data Exchange (ETDEWEB)

    Blatt, P.A.

    1993-12-01

    The crack growth characteristics of a 4-ply, unidirectional, titanium matrix composite, SCS-6/ti-6Al-2Sn4Zr-2Mo, subjected to thermomechanical fatigue were investigated. A linear summation model was developed to predict the isothermal and thermomechanical fatigue (TMF) crack growth rates of the composite. The linear summation approach assumes the total fatigue crack growth rate is a combination of a cycle-dependent and a time-dependent component. To assist the modeling effort, a series of isothermal, in-phase, and out-of-phase crack growth test were conducted. The test temperatures ranged from 15000 to 53800 and the fastest thermal frequency was 0.0083 Hz. With the excepton of the 15000 isothermal test, the model was able to correlate all the baseline fangue crack growth test data between oK of 50 to 9OMPa. In additon, the model was able to predict the fatigue crack growth rate of a proof test which involved a continual change in temperature range and load range to produce a constant crack growth rate. The proof test began under isothermal conditions at the maximum temperature and ended under in-phase TMF conditions.

  9. Residual thermal stress control in composite reinforced metal structures. [by mechanical loading of metal component prior to bonding

    Science.gov (United States)

    Kelly, J. B.; June, R. R.

    1972-01-01

    Advanced composite materials, composed of boron or graphite fibers and a supporting matrix, make significant structural efficiency improvements available to aircraft and aerospace designers. Residual stress induced during bonding of composite reinforcement to metal structural elements can be reduced or eliminated through suitable modification to the manufacturing processes. The most successful method employed during this program used a steel tool capable of mechanically loading the metal component in compression prior to the adhesive bonding cycle. Compression loading combined with heating to 350 F during the bond cycle can result in creep deformation in aluminum components. The magnitude of the deformation increases with increasing stress level during exposure to 350 F.

  10. The Smart Behavior of Cement-based Composite Containing Carbon Fibers under Three-point-bending Load

    Institute of Scientific and Technical Information of China (English)

    CHEN Bing; WU Keru; YAO Wu

    2005-01-01

    The influences of the fiber volume fraction on the electrical conductivity and the fraction change of electrical resistance under three-point- bending test were discussed. It is found that the relationship between the electrical conductivity of composites and the fiber volume fraction can be explained by the percolation theory and the change of electrical resistance of specimens reflects to the process of loading. The sensitivity and the response of the change of electrical resistance to the load for specimens with different fiber volume fractions are quite different,which provide an important guide for the manufacture of conductive and intrinsically smart carbon fiber composite.

  11. Physical properties, chemical composition, and cloud forming potential of particulate emissions from a marine diesel engine at various load conditions.

    Science.gov (United States)

    Petzold, A; Weingartner, E; Hasselbach, J; Lauer, P; Kurok, C; Fleischer, F

    2010-05-15

    Particulate matter (PM) emissions from one serial 4-stroke medium-speed marine diesel engine were measured for load conditions from 10% to 110% in test rig studies using heavy fuel oil (HFO). Testing the engine across its entire load range permitted the scaling of exhaust PM properties with load. Emission factors for particle number, particle mass, and chemical compounds were determined. The potential of particles to form cloud droplets (cloud condensation nuclei, CCN) was calculated from chemical composition and particle size. Number emission factors are (3.43 +/- 1.26) x 10(16) (kg fuel)(-1) at 85-110% load and (1.06 +/- 0.10) x 10(16) (kg fuel)(-1) at 10% load. CCN emission factors of 1-6 x 10(14) (kg fuel)(-1) are at the lower bound of data reported in the literature. From combined thermal and optical methods, black carbon (BC) emission factors of 40-60 mg/(kg fuel) were determined for 85-100% load and 370 mg/(kg fuel) for 10% load. The engine load dependence of the conversion efficiency for fuel sulfur into sulfate of (1.08 +/- 0.15)% at engine idle to (3.85 +/- 0.41)% at cruise may serve as input to global emission calculations for various load conditions. PMID:20402501

  12. Phase-stress partition during uniaxial tensile loading of a TiC-particulate-reinforced Al composite

    Energy Technology Data Exchange (ETDEWEB)

    Shi, N.; Bourke, M.A.M.; Roberts, J.A. [Los Alamos National Lab., NM (United States); Allison, J.E. [Ford Motor Co., Dearborn, MI (United States). Scientific Research Lab.

    1997-12-01

    Using neutron diffraction, the authors measured during in situ loading the lattice elastic mean phase (LEMP) strains in the matrix and reinforcement of a 15 vol pct TiC-particulate-reinforced 2219 Al composite. From the strain components longitudinal to and transverse to loading, the in situ normal phase stresses (average normal stresses in the constituent phases) were obtained through Hooke`s law. The internal stress partition between the matrix and reinforcement, i.e., load sharing, can then be inferred. Internal stress development was also modeled using the finite-element method (FEM), showing good agreement with the experimental results. Both indicate that the relationship between the LEMP strains/phase stresses and the applied load noticeably deviates from linearity during composite microyielding, long before the nominal 0.2 pct proof stress is reached. The nonlinearity arises (despite the linear elastic relationship between phase stresses and LEMP strains) because the applied traction is not synonymous with the phase stresses, and the ratio of phase stresses may vary during loading. Notably, the morphology of the LEMP strain development with applied load differs in the directions parallel to or perpendicular to the load. The differences are explained by considering the evolution of local matrix plasticity. Thermal residual stresses and inelastic stress relaxation, driven by interfacial diffusion, are also discussed.

  13. Composite bone cements loaded with a bioactive and ferrimagnetic glass-ceramic: Leaching, bioactivity and cytocompatibility

    Energy Technology Data Exchange (ETDEWEB)

    Verné, Enrica, E-mail: enrica.verne@polito.it [Institute of Materials Physics and Engineering, Applied Science and Technology Department, Politecnico di Torino, C. so Duca degli Abruzzi 24, 10129 Torino (Italy); Bruno, Matteo [Institute of Materials Physics and Engineering, Applied Science and Technology Department, Politecnico di Torino, C. so Duca degli Abruzzi 24, 10129 Torino (Italy); Miola, Marta [Institute of Materials Physics and Engineering, Applied Science and Technology Department, Politecnico di Torino, C. so Duca degli Abruzzi 24, 10129 Torino (Italy); Department of Health Sciences, Università del Piemonte Orientale “Amedeo Avogadro”, Via Solaroli 17, 28100 Novara (Italy); Maina, Giovanni; Bianco, Carlotta [Traumatology Orthopedics and Occupational Medicine Dept., Università di Torino, Via G. Zuretti 29, 10126 Torino (Italy); Cochis, Andrea [Department of Health Sciences, Università del Piemonte Orientale “Amedeo Avogadro”, Via Solaroli 17, 28100 Novara (Italy); Rimondini, Lia [Department of Health Sciences, Università del Piemonte Orientale “Amedeo Avogadro”, Via Solaroli 17, 28100 Novara (Italy); Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali, Via G. Giusti, 9, 50121 Firenze (Italy)

    2015-08-01

    In this work, composite bone cements, based on a commercial polymethylmethacrylate matrix (Palamed®) loaded with ferrimagnetic bioactive glass-ceramic particles (SC45), were produced and characterized in vitro. The ferrimagnetic bioactive glass-ceramic belongs to the system SiO{sub 2}–Na{sub 2}O–CaO–P{sub 2}O{sub 5}–FeO–Fe{sub 2}O{sub 3} and contains magnetite (Fe{sub 3}O{sub 4}) crystals into a residual amorphous bioactive phase. Three different formulations (containing 10, 15 and 20 wt.% of glass-ceramic particles respectively) have been investigated. These materials are intended to be applied as bone fillers for the hyperthermic treatment of bone tumors. The morphological, compositional, calorimetric and mechanical properties of each formulation have been already discussed in a previous paper. The in vitro properties of the composite bone cements described in the present paper are related to iron ion leaching test (by graphite furnace atomic absorption spectrometer), bioactivity (i.e. the ability to stimulate the formation of a hydroxyapatite – HAp – layer on their surface after soaking in simulated body fluid SBF) and cytocompatibility toward human osteosarcoma cells (ATCC CRL-1427, Mg63). Morphological and chemical characterizations by scanning electron microscopy and energy dispersion spectrometry have been performed on the composite samples after each test. The iron release was negligible and all the tested samples showed the growth of HAp on their surface after 28 days of immersion in a simulated body fluid (SBF). Cells showed good viability, morphology, adhesion, density and the ability to develop bridge-like structures on all investigated samples. A synergistic effect between bioactivity and cell mineralization was also evidenced. - Highlights: • An in vitro biological characterization was carried out on ferromagnetic and bioactive composite cements. • No release of iron was revealed in the physiological solution. • Bioactivity tests

  14. Biocompatibility of artificial bone based on vancomycin loaded mesoporous silica nanoparticles and calcium sulfate composites.

    Science.gov (United States)

    Gu, Jisheng; Wang, Teng; Fan, Guoxin; Ma, Junhua; Hu, Wei; Cai, Xiaobing

    2016-04-01

    The aim of this study was to evaluate the in vitro and in vivo biocompatibility of artificial bone based on vancomycin loaded mesoporous silica nanoparticles and calcium sulfate composites. In vitro cytotoxicity tests by cholecystokinin octapeptide (CCK-8) assay showed that the 5%Van-MSN-CaSO4 and Van-CaSO4 bone cements were cytocompatible for mouse osteoblastic cell line MC3T3-E1. The microscopic observation confirmed that MC3T3-E1cells incubated with Van-CaSO4 group and 5%Van-MSN-CaSO4 group exhibited clear spindle-shaped changes, volume increase and maturation, showing that these cements supported adhesion of osteoblastic cells on their surfaces. In addition, the measurement of alkaline phosphatase activity revealed the osteoconductive property of these biomaterials. In order to assess in vivo biocompatibility, synthesized cements were implanted into the distal femur of twelve adult male and female New Zealand rabbits. After implantation in artificial defects of the distal femur, 5%Van-MSN-CaSO4 and Van-CaSO4 bone cements did not damage the function of main organs of rabbits. In addition, the Van-MSN-CaSO4 composite allowed complete repair of bone defects with new bone formation 3 months after implantation. These results show potential application of Van-MSN-CaSO4 composites as bone graft materials for the treatment of open fracture in human due to its mechanical, osteoconductive and potential sustained drug release characteristics and the absence of adverse effects on the body.

  15. Damage initiation mechanism in rubber sheet composites during the static loading

    Directory of Open Access Journals (Sweden)

    N. Isac

    2007-01-01

    Full Text Available Purpose: Mechanical behaviour and damage initiation mechanisms in thin rubber sheet composites were investigated under static solicitation at room temperature. Two types of rubber are used in this study; Natural rubber, NR vulcanised and reinforced by carbon black and Synthetic rubber (styrene-butadiene-rubber, SBR.Design/methodology/approach: A comprehensive study has been carried out in order to identify a threshold criterion for the damage mechanism to explain a tearing criterion for the concept of tearing energy of the elastomers and also to give a detail for the damage mechanism depending on the loading conditions. A typical type of specimen geometry of thin sheet rubber composite materials was studied under static tensile tests conducted on the smooth and notched specimens with variable depths. In this way, the effects of the plane stress on the damage mechanism are characterized depending on the rubber materials.Findings: Damage mechanisms during tensile test have been described for both of rubber types and the criteria which characterize the tearing resistance, characteristic energy for tearing (T was explained. Damage in the specimens were evaluated just at the beginning of the tearing by means of the observations in the scanning electron microscopy (SEM.Practical implications: A tearing criterion was suggested in the case of simple tension conditions by assuming large strain. In the next step of this study, a finite element analysis (FEA will be applied under the same conditions of this part in order to obtain the agreement between experimental and FEA results.Originality/value: This study propses a threshold criterion for the damage just at the beginning of the tearing for thin sheet rubber composites and gives a detail discussion for explaining the damage mechanisms by SEM results. This type of study gives many facilities for the sake of simplicity in industrial application.

  16. Effects of load mode on mechanical properties of ZrO2(2Y)/TRIP steel composites

    Institute of Scientific and Technical Information of China (English)

    周玉; 郭英奎; 李冬波; 段小明

    2003-01-01

    The ZrO2 (2Y)/TRIP steel composites were prepared by vacuum hot-pressing sintering. The room temperature static tensile and dynamic yield strength were tested using the static tensile and Split Hopkinson Pressure Bar methods, respectively. The effects of load mode on the static and dynamic mechanical behaviors were studied. The results show that the static tensile strengths of the composites decrease with the increase of ZrO2 content, for the weak bonding of ZrO2/ZrO2. Under the dynamic load, the matrix TRIP steel produces the martinsitic phase transformation, which improves the dynamic strength and deformation ability of the composites. When the volume fraction of ZrO2 exceeds 20%, the strain-hardening coefficient and the dynamic deformation ability of the composites decrease.

  17. Interpreting the g loadings of intelligence test composite scores in light of Spearman's law of diminishing returns.

    Science.gov (United States)

    Reynolds, Matthew R

    2013-03-01

    The linear loadings of intelligence test composite scores on a general factor (g) have been investigated recently in factor analytic studies. Spearman's law of diminishing returns (SLODR), however, implies that the g loadings of test scores likely decrease in magnitude as g increases, or they are nonlinear. The purpose of this study was to (a) investigate whether the g loadings of composite scores from the Differential Ability Scales (2nd ed.) (DAS-II, C. D. Elliott, 2007a, Differential Ability Scales (2nd ed.). San Antonio, TX: Pearson) were nonlinear and (b) if they were nonlinear, to compare them with linear g loadings to demonstrate how SLODR alters the interpretation of these loadings. Linear and nonlinear confirmatory factor analysis (CFA) models were used to model Nonverbal Reasoning, Verbal Ability, Visual Spatial Ability, Working Memory, and Processing Speed composite scores in four age groups (5-6, 7-8, 9-13, and 14-17) from the DAS-II norming sample. The nonlinear CFA models provided better fit to the data than did the linear models. In support of SLODR, estimates obtained from the nonlinear CFAs indicated that g loadings decreased as g level increased. The nonlinear portion for the nonverbal reasoning loading, however, was not statistically significant across the age groups. Knowledge of general ability level informs composite score interpretation because g is less likely to produce differences, or is measured less, in those scores at higher g levels. One implication is that it may be more important to examine the pattern of specific abilities at higher general ability levels.

  18. Ultrasonic velocities, densities, and excess molar volumes of binary mixtures of N,N-dimethyl formamide with methyl acrylate, or ethyl acrylate, or butyl acrylate, or 2-ethyl hexyl acrylate at T = 308.15 K

    Energy Technology Data Exchange (ETDEWEB)

    Kondaiah, M. [Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar 522510, Andhra Pradesh (India); Sravana Kumar, D. [Dr. V.S. Krishna Govt. Degree College, Visakhapatnam, Andhra Pradesh (India); Sreekanth, K. [Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar 522510, Andhra Pradesh (India); Krishna Rao, D., E-mail: krdhanekula@yahoo.co.in [Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar 522510, Andhra Pradesh (India)

    2011-12-15

    Highlights: > Positive values of V{sub m}{sup E}, indicate dispersion forces between acrylic esters and DMF. > V{sub m}{sup E} values compared with Redlich-Kister polynomial. > Partial molar volumes data conclude that weak interactions exist in the systems. > Measured velocity values compared with theoretical values obtained by polynomials. - Abstract: Ultrasonic velocities, u, densities, {rho}, of binary mixtures of N,N-dimethyl formamide (DMF) with methyl acrylate (MA), ethyl acrylate (EA), butyl acrylate (BA), and 2-ethyl hexyl acrylate (EHA), including pure liquids, over the entire composition range have been measured at T = 308.15 K. Using the experimental results, the excess molar volume, V{sub m}{sup E}, partial molar volumes, V-bar {sub m,1}, V-bar{sub m,2}, and excess partial molar volumes, V-bar{sub m,1}{sup E}, V-bar{sub m,2}{sup E} have been calculated. Molecular interactions in the systems have been studied in the light of variation of excess values of calculated properties. The excess properties have been fitted to Redlich-Kister type polynomial and the corresponding standard deviations have been calculated. The positive values of V{sub m}{sup E} indicate the presence of dispersion forces between the DMF and acrylic ester molecules. Further theoretical values of sound velocity in the mixtures have been evaluated using various theories and have been compared with experimental sound velocities to verify the applicability of such theories to the systems studied. Theoretical ultrasonic velocity data have been used to study molecular interactions in the binary systems investigated.

  19. Conductivity of microfibrillar polymer-polymer composites with CNT-loaded microfibrils or compatibilizer: A comparative study

    Directory of Open Access Journals (Sweden)

    S. Fakirov

    2013-07-01

    Full Text Available Conductive polymer composites have wide ranging applications, but when they are produced by conventional melt blending, high conductive filler loadings are normally required, hindering their processability and reducing mechanical properties. In this study, two types of polymer-polymer composites were studied: i microfibrillar composites (MFC of polypropylene (PP and 5 wt% carbon nanotube (CNT loaded poly(butylene terephthalate (PBT as reinforcement, and ii maleic anhydride-grafted polypropylene (PP-g-MA compatibilizer, loaded with 5 wt% CNTs introduced into an MFC of PP and poly(ethylene terephthalate (PET in concentrations of 5 and 10 wt%. For the compatibilized composite type, PP and PET were melt-blended, cold-drawn and pelletized, followed by dry-mixing with PP-g-MA/CNT, re-extrusion at 200°C, and cold-drawing. The drawn blends produced were compression moulded to produce sheets with MFC structure. Using scanning electron microscopy, CNTs coated with PP-g-MA could be observed at the interface between PP matrix and PET microfibrils in the compatibilized blends. The volume resistivities tested by four-point test method were: 2.87•108 and 9.93•107 Ω•cm for the 66.5/28.5/5 and 63/27/10 (by wt% PP/PET/(PP-g-MA/CNT blends, corresponding to total CNT loadings (in the composites of 0.07 vol% (0.24 wt% and 0.14 vol% (0.46 wt%, respectively. For the non-compatibilized MFC types based on PP/(PBT/CNT with higher and lower melt flow grades of PP, the resistivities of 70/(95/5 blends were 1.9•106 and 1.5•107 Ω•cm, respectively, corresponding to a total filler loading (in the composite of 0.44 vol% (1.5 wt% in both MFCs.

  20. A Study on Response of a Contoured Composite Panel with Co-cured Stiffeners Under Transient Loading

    Science.gov (United States)

    Begum, Shahnaaz; Jain, Prakash Chand; Venkatesh, Siddu

    2016-07-01

    Composite materials are emerging to be the best applied materials for aerospace applications. With rapid improvement in computational facilities, it is now possible to design the best composite lay up for a particular kind of application. This paper presents the development of a Finite Element model of a contoured composite panel with co-cured stiffeners using Finite Element Simulation. Commercial package ANSYS 15.0 is used for this study. Such half contoured panels find wide application in Aerospace industry. The panel is hinged at one of the ends and dynamically loaded at the other end over a relatively small surface area by transverse load. The response of the panel is observed for variation in stresses, deflections and failure criteria. The panel is expected to rotate about the hinge point by 4° from the initial point. The transient response of the composite panel has been observed for expected load and two test load cases and results reported in this paper. Analysis has become useful input for the design of panel.

  1. SYNTHESIS OF SOAP-FREE ACRYLIC HYDROSOLS

    Institute of Scientific and Technical Information of China (English)

    Li Jia; Zong-hui Liu; De-qing Wei

    2002-01-01

    Poly(methyl methacrylate/ethyl acrylate/acrylic acid) hydrosols were prepared by employing soap-freepolymerization, and (acrylic acid/butyl acrylate) oligomer was used as the polymeric surfactant. The effect of reactioncondition on the morphology and particle size of the hydrosols was investigated. The minimum amount of acrylic acid in thehydrosols is 2%. The maximum weight average molecular weight (Mw) of polymer that assures soap-free emulsionconversion into hydrosol is about 1.2 × 105-1.3 × 105. The particle transforming process was investigated, and an obviouschange of particle diameter and morphology was observed.

  2. Mechanical, thermal and friction properties of rice bran carbon/nitrile rubber composites: Influence of particle size and loading

    International Nuclear Information System (INIS)

    Highlights: • A novel rice bran carbon (RBC) is used to reinforce nitrile rubber. • We study the effect of RBC particle size on the performances of nitrile rubber. • We study the effect of RBC loading on the performances of nitrile rubber. • The addition of RBC improves the mechanical properties of nitrile rubber. • The addition of RBC improves the anti-skid properties of nitrile rubber. - Abstract: Four types of rice bran carbon (RBC) with different particle sizes were compounded with nitrile rubber (NBR) in a laboratory size two-roll miller. The obtained RBC/NBR composites were characterized using Field Emission Scanning Electron Microscopy (FE-SEM) and tensile tests. Experimental results showed the RBC with lowest particle size exhibited best dispersion state and superior reinforcement ability. Then, we investigated the influence of RBC loading on the morphology, vulcanization characteristics, mechanical, thermal and friction properties of NBR composites. Experimental results indicated that the incorporation of RBC resulted in higher torque values, longer curing time, but shorter scorch time. The addition of RBC remarkably improved the mechanical properties of NBR composites. However, when the RBC loading exceeded 60 phr, the improvement in the tensile strength was not significant due to the poor dispersion state and weak interfacial bonding between RBC and NBR matrix, which were confirmed by Mooney–Rivlin stress–strain curves and FE-SEM observations. The thermal stabilities of RBC/NBR composites were largely improved as the loading of RBC increased. Friction tests revealed that under a certain concentration, the presence of RBC increased the static friction coefficient of NBR composites, suggesting the anti-skid role of RBC in the NBR composites. The overall results demonstrated that RBC could act as ideal filler for NBR composites providing both economic and environmental advantages

  3. Modeling for Fatigue Hysteresis Loops of Carbon Fiber-Reinforced Ceramic-Matrix Composites under Multiple Loading Stress Levels

    Science.gov (United States)

    Longbiao, Li

    2015-12-01

    In this paper, the fatigue hysteresis loops of fiber-reinforced ceramic-matrix composites (CMCs) under multiple loading stress levels considering interface wear has been investigated using micromechanical approach. Under fatigue loading, the fiber/matrix interface shear stress decreases with the increase of cycle number due to interface wear. Upon increasing of fatigue peak stress, the interface debonded length would propagate along the fiber/matrix interface. The difference of interface shear stress existed in the new and original debonded region would affect the interface debonding and interface frictional slipping between the fiber and the matrix. Based on the fatigue damage mechanism of fiber slipping relative to matrix in the interface debonded region upon unloading and subsequent reloading, the interface slip lengths, i.e., the interface debonded length, interface counter-slip length and interface new-slip length, are determined by fracture mechanics approach. The fatigue hysteresis loops models under multiple loading stress levels have been developed. The effects of single/multiple loading stress levels and different loading sequences on fatigue hysteresis loops have been investigated. The fatigue hysteresis loops of unidirectional C/SiC composite under multiple loading stress levels have been predicted.

  4. Design and characterization of a composite material based on Sr(II)-loaded clay nanotubes included within a biopolymer matrix.

    Science.gov (United States)

    Del Buffa, Stefano; Bonini, Massimo; Ridi, Francesca; Severi, Mirko; Losi, Paola; Volpi, Silvia; Al Kayal, Tamer; Soldani, Giorgio; Baglioni, Piero

    2015-06-15

    This paper reports on the preparation, characterization, and cytotoxicity of a hybrid nanocomposite material made of Sr(II)-loaded Halloysite nanotubes included within a biopolymer (3-polyhydroxybutyrate-co-3-hydroxyvalerate) matrix. The Sr(II)-loaded inorganic scaffold is intended to provide mechanical resistance, multi-scale porosity, and to favor the in-situ regeneration of bone tissue thanks to its biocompatibility and bioactivity. The interaction of the hybrid system with the physiological environment is mediated by the biopolymer coating, which acts as a binder, as well as a diffusional barrier to the Sr(II) release. The degradation of the polymer progressively leads to the exposure of the Sr(II)-loaded Halloysite scaffold, tuning its interaction with osteogenic cells. The in vitro biocompatibility of the composite was demonstrated by cytotoxicity tests on L929 fibroblast cells. The results indicate that this composite material could be of interest for multiple strategies in the field of bone tissue engineering.

  5. Characterization of unidirectional carbon fiber reinforced polyamide-6 thermoplastic composite under longitudinal compression loading at high strain rate

    Science.gov (United States)

    Ploeckl, Marina; Kuhn, Peter; Koerber, Hannes

    2015-09-01

    In the presented work, an experimental investigation has been performed to characterize the strain rate dependency of unidirectional carbon fiber reinforced polyamide-6 composite for longitudinal compression loading. An end-loaded compression specimen geometry, suitable for contactless optical strain measurement via digital image correlation and dynamic loading in a split-Hopkinson pressure bar, was developed. For the dynamic experiments at a constant strain rate of 100 s-1 a modified version of the Dynamic Compression Fixture, developed by Koerber and Camanho [Koerber and Camanho, Composites Part A, 42, 462-470, 2011] was used. The results were compared with quasi-static test results at a strain rate of 3 · 10-4 s-1 using the same specimen geometry. It was found that the longitudinal compressive strength increased by 61% compared to the strength value obtained from the quasi-static tests.

  6. Characterization of unidirectional carbon fiber reinforced polyamide-6 thermoplastic composite under longitudinal compression loading at high strain rate

    Directory of Open Access Journals (Sweden)

    Ploeckl Marina

    2015-01-01

    Full Text Available In the presented work, an experimental investigation has been performed to characterize the strain rate dependency of unidirectional carbon fiber reinforced polyamide-6 composite for longitudinal compression loading. An end-loaded compression specimen geometry, suitable for contactless optical strain measurement via digital image correlation and dynamic loading in a split-Hopkinson pressure bar, was developed. For the dynamic experiments at a constant strain rate of 100 s−1 a modified version of the Dynamic Compression Fixture, developed by Koerber and Camanho [Koerber and Camanho, Composites Part A, 42, 462–470, 2011] was used. The results were compared with quasi-static test results at a strain rate of 3 · 10−4 s−1 using the same specimen geometry. It was found that the longitudinal compressive strength increased by 61% compared to the strength value obtained from the quasi-static tests.

  7. Preparation of poly(polyethylene glycol methacrylate-co-acrylic acid) hydrogels by radiation and their physical properties

    International Nuclear Information System (INIS)

    The pH-responsive copolymer hydrogels were prepared with the monomers of polyethylene glycol methacrylate and acrylic acid based on γ-ray irradiation technique. The gel content of these copolymer hydrogels varied depending on both the composition of monomers and the radiation dose. Maximum gel percent and degree of crosslinking were obtained at the composition of equal amount of comonomers. These copolymer hydrogels did not show any noticeable change in swelling at lower pH range. However they showed an abrupt increase in swelling at higher pH range due to the ionization of carboxyl groups. This pH-responsive swelling behavior was applied for the insulin carrier via oral delivery. Insulin-loaded copolymer hydrogels released most of their insulin in the simulated intestinal fluid which had a pH of 6.8 but not in the simulated gastric fluid which had a pH of 1.2

  8. 淀粉-丙烯酸/聚丙烯酰胺复合吸水树脂的制备及性能%Preparation and properties of starch-g-acrylic/PAM superabsorbent composites

    Institute of Scientific and Technical Information of China (English)

    杨小玲; 陈佑宁

    2012-01-01

    淀粉用环氧氯丙烷进行预交联,与丙烯酸接枝共聚,生成淀粉-丙烯酸共聚物;再与聚丙烯酰胺聚合,制备淀粉-丙烯酸/聚丙烯酰胺复合高吸水树脂.考察了淀粉用量、引发剂及交联剂对吸水倍率的影响.结果表明,当淀粉用量取2.5g,复合引发剂取0.02 mmol,交联剂取0.1%时,吸水倍率最大;吸水速率20 min内达到吸水溶胀平衡.%The starch-g-acrylic was synthesized with soluble starch containing a part of precrosslinked starch and acrylic,then starch-g-acrylic/PAM super absorbent resin was prepared by inverse suspension polymerization. The influence of starch amount,initiator and cross-linking agent on absorbability were analyzed. The results indicated that when the amount of starch,the initiator mixture (APS and CAN) and crosslinking agent were 2. 5 g,0. 02 mmol and 0. 1% , respectively, absorbability of starch-acrylic/PAM resin was the highest,and the absorbency rate test showed the earlier absorbency rate was high and absor-bence equilibrium could reach in 20 min.

  9. An Experimental Study of a Stitched Composite with a Notch Subjected to Combined Bending and Tension Loading

    Science.gov (United States)

    Palmer, Susan O.; Nettles, Alan T.; Poe, C. C., Jr.

    1999-01-01

    A series of tests was conducted to measure the strength of stitched carbon/epoxy composites containing through-thickness damage in the form of a crack-like notch. The specimens were subjected to three types of loading: pure bending, pure tension, and combined bending and tension loads. Measurements of applied loads, strains near crack tips, and crack opening displacements (COD) were monitored in all tests. The transverse displacement at the center of the specimen was measured using a Linear Variable Differential Transformer (LVDT). The experimental data showed that the outer surface of the pure tension specimen failed at approximately 6,000 microstrain, while in combined bending and tension loads the measured tensile strains reached 10,000 microstrain.

  10. Comparative Evaluation Of Reinforced Concrete, Steel And Composite Structures Under The Effect Of Static And Dynamic Loads

    Directory of Open Access Journals (Sweden)

    Zafar Mujawar

    2015-01-01

    Full Text Available Steel-concrete composite construction has gained wide acceptance all over the world as an alternative for pure steel and pure concrete construction. However this approach is a new concept for construction industry. R.C.C are no longer economical because of their increased dead load, hazardous formwork. The present study deals with comparison of reinforced concrete, steel and composite structures under the effect of static and dynamic loads. The results of this work show that composite structures are best suited for high rise buildings compared to that of steel and reinforced concrete structures. Response spectrum method is used for comparison of three structures with the help of ETABS software.

  11. Failure Test and Finite Element Simulation of a Large Wind Turbine Composite Blade under Static Loading

    Directory of Open Access Journals (Sweden)

    Xiao Chen

    2014-04-01

    Full Text Available This study presented a failure analysis of a 52.3 m composite wind turbine blade under static loading. Complex failure characteristics exhibited at the transition region of the blade were thoroughly examined and typical failure modes were indentified. In order to predict multiple failure modes observed in the tests and gain more insights into the failure mechanisms of the blade, a Finite Element (FE simulation was performed using a global-local modeling approach and Progressive Failure Analysis (PFA techniques which took into account material failure and property degradation. Failure process and failure characteristics of the transition region were satisfactorily reproduced in the simulation, and it was found that accumulated delamination in spar cap and shear web failure at the transition region were the main reasons for the blade to collapse. Local buckling played an important role in the failure process by increasing local out-of-plane deformation, while the Brazier effect was found not to be responsible for the blade failure.

  12. Synthesis and Characterization of Core-Shell Acrylate Based Latex and Study of Its Reactive Blends

    OpenAIRE

    Ying Nie; Min-Feng Tang; Xiao-Dong Fan; Xiang Liu

    2008-01-01

    Techniques in resin blending are simple and efficient method for improving the properties of polymers, and have been used widely in polymer modification field. However, polymer latex blends such as the combination of latexes, especially the latexes with water-soluble polymers, were rarely reported. Here, we report a core-shell composite latex synthesized using methyl methacrylate (MMA), butyl acrylate (BA), 2-ethylhexyl acrylate (EHA) and glycidyl methacrylate (GMA) as monomers and ammonium p...

  13. The effect of organic loading on bacterial community composition of membrane biofilms in a submerged polyvinyl chloride membrane bioreactor.

    Science.gov (United States)

    Xia, Siqing; Li, Jixiang; He, Shuying; Xie, Kang; Wang, Xiaojia; Zhang, Yanhao; Duan, Liang; Zhang, Zhiqiang

    2010-09-01

    The effect of organic loading on bacterial community composition of membrane biofilms was investigated using a submerged polyvinyl chloride membrane bioreactor. The low and high loadings were set at 0.33 and 0.52 gCOD/(gVSSd), respectively. The results showed that membrane fouling occurred earlier and faster under the high loading conditions. Denaturing gradient gel electrophoresis (DGGE) analysis revealed that the similarity of bacterial community in the membrane biofilms between the two loadings was 0.67, higher than that in the mixed liquors (0.52-0.55), which indicated that some specific bacteria were selected preferentially on the membranes. Clone library analysis of the membrane biofilms indicated that Betaproteobacteria and Bacteroidetes under the high loading were 54.72% and 19.81%, respectively. Microarray results further confirmed that the two bacteria were the dominant microorganisms in the high loading biofilm. The severe membrane fouling may be aroused mainly by the enrichment of the two bacteria under the high loading.

  14. Potential of palm kernel activated carbon epoxy (PKAC-E composite as solid lubricant: Effect of load on friction and wear properties

    Directory of Open Access Journals (Sweden)

    K.W. Chua

    2014-09-01

    Full Text Available The aim of this study is to investigate the effect of load on the friction and wear properties of palm kernel activated carbon epoxy (PKAC-E composite. The PKAC-E composite specimen was fabricated by hot compression molding method. Dry sliding test was performed by using a pin-on-disc tribometer at various load conditions with constant sliding speed and distance. The experimental results show that wear rate and friction coefficient of PKAC-E composite decreases with applied load. However, at higher load, friction coefficient increases slightly and remains almost invariant with applied load. In addition, some adhesive and abrasive wear types were identified on the worn surfaces. The main conclusion of this work is that PKAC-E composite show unique properties as solid lubricant at low load under unlubricated conditions.

  15. Using NMR chemical shift imaging to monitor swelling and molecular transport in drug-loaded tablets of hydrophobically modified poly(acrylic acid): methodology and effects of polymer (in)solubility.

    Science.gov (United States)

    Knöös, Patrik; Topgaard, Daniel; Wahlgren, Marie; Ulvenlund, Stefan; Piculell, Lennart

    2013-11-12

    A new technique has been developed using NMR chemical shift imaging (CSI) to monitor water penetration and molecular transport in initially dry polymer tablets that also contain small low-molecular weight compounds to be released from the tablets. Concentration profiles of components contained in the swelling tablets could be extracted via the intensities and chemical shift changes of peaks corresponding to protons of the components. The studied tablets contained hydrophobically modified poly(acrylic acid) (HMPAA) as the polymer component and griseofulvin and ethanol as hydrophobic and hydrophilic, respectively, low-molecular weight model compounds. The water solubility of HMPAA could be altered by titration with NaOH. In the pure acid form, HMPAA tablets only underwent a finite swelling until the maximum water content of the polymer-rich phase, as confirmed by independent phase studies, had been reached. By contrast, after partial neutralization with NaOH, the polyacid became fully miscible with water. The solubility of the polymer affected the water penetration, the polymer release, and the releases of both ethanol and griseofulvin. The detailed NMR CSI concentration profiles obtained highlighted the clear differences in the disintegration/dissolution/release behavior for the two types of tablet and provided insights into their molecular origin. The study illustrates the potential of the NMR CSI technique to give information of importance for the development of pharmaceutical tablets and, more broadly, for the general understanding of any operation that involves the immersion and ultimate disintegration of a dry polymer matrix in a solvent. PMID:24106807

  16. [Road dust loading and chemical composition at major cities in Fujian Province].

    Science.gov (United States)

    Zheng, An; Yang, Bing-yu; Wu, Shui-ping; Wang, Xin-hong; Chen, Xiao-qiu

    2013-05-01

    A total of 57 road dust and 16 urban soil samples were collected from four cities, Xiamen, Zhangzhou, Quanzhou and Putian in Fujian Province, China. Twenty-six elements, eight water soluble ions, organic carbon and elemental carbon in the fraction of particulate diameter less than 2.5 microm (PM2.5) derived through a suspension chamber were analyzed. The average loading of road dust with diameter less than 100 microm in the four cities ranged from 6.99 g x m(-2) to 10.11 g x m(-2), while the loading of PM2.5 ranged from 4.0 mg x m(-2) to 12.5 mg x m(-2). Both the soil and road dust samples were characterized with much higher concentrations of Si, Ca, Al, Fe and K. But for the anthropogenic elements such as Cu, Pb, Zn,Cr and Ti, much lower levels were found in the soil PM2.5, than those in the road dust PM2.5. Significantly higher levels of NH4+, NO3- and SO4(2-) were found in the road dust PM2.5 from Zhangzhou in comparison with those from other cities in this study. The calcium ion (Ca2+) content was significantly positively correlated with the Mg2+ content in the road dust PM2.5 from Xiamen, Zhangzhou and Quanzhou. The levels of organic carbon (OC) in the road dust PM2.5 in these four cities were higher than those reported in Ji'nan, Shijiazhuang and Beijing while the levels of elemental carbon (EC) were all lower than those in the urban road dust from Beijing, Significant positive correlation between EC and OC was found in samples from Quanzhou and Putian, suggesting the same and/or similar sources. The result of mass balance indicated that higher percentage compositions were soil and OM in both Quanzhou and Putian. Based on the cluster analysis, the 57 road dust samples were divided into four types: influenced by atmospheric deposition, influenced by soil dust, influenced by atmospheric deposition and soil dust, and influenced by soil and construction dust.

  17. Mechanical Behavior of Polyester and Fiber Glass as a Composite Material used in a Vehicle under Dynamic Loading

    Directory of Open Access Journals (Sweden)

    Ahmed Naif Al-Khazraji* Ali Yasser Hassa * Emad Abdul Hussein Abdul Sahib

    2014-04-01

    Full Text Available The automobile industry has shown increased interest in the replacement of steel spring with fiberglass composite leaf spring due to high strength compared to weight. The aim of this paper is to study two kinds of fiberglass, regular direction (0-90 and random direction immersed in polyester resin. They were tested under static load, as tensile test for their mechanical properties, and under dynamic load in fully reversible bending tests as fatigue test, to estimate S-N curves, and impact test for their mechanical properties. Results from the tensile tests showed that the tensile strength of the regular type is greater than random type. The fatigue test results showed that the number of cycles to failure in regular type of composite material is greater than that of the random type and the endurance limit is also greater than in random, the increase percentage in endurance limit is 7.5%. Results due to impact test showed that there were on increasing in fracture energy for the random type the increase ratio is 13.9%. The Important characteristics of composites that make them excellent for leaf spring instead of steel are higher strength-to-weight ratio, superior fatigue strength. Application of composite structures reduces the weight of leaf spring without any reduction on the load carrying capacity and stiffness in automobile suspension system.

  18. Hertzian Load-bearing Capacity of Hybrid and Nano-hybrid Resin Composites Stored Dry and Wet

    Directory of Open Access Journals (Sweden)

    Farmani S

    2016-03-01

    Full Text Available Statement of Problem: Hertzian indentation test has been proven to be an efficient and reliable alternative upon Vickers hardness test. This method has been used to test dental ceramics, amalgams, glass ionomers and luting cements.There is limited published information about the load-bearing capacity of resin composites using Hertizian indentation test. Objectives: To investigate the load-bearing capacity of hybrid and nano-hybrid resin composites stored dry or wet up to 30 days, using Hertzian indentation test. Materials and Methods: Three resin composites were used: two nano-hybrids (Filtek Supreme, and Luna and one hybrid, (Rok. A total of 108 disc-shaped specimens (1mm thick x 10 mm diameter were prepared using polyethylene mould. The specimens of each material were randomly divided into 6 groups of 6 (n=6 and stored at 370C either in distilled water or dry for 1, 7 and 30 days. The specimens were tested using Hertzian jig aligned in the universal testing machine. The specimen was placed on the top of a disc-shaped substrate. The load was applied at the center of each specimen and the load at the first crack was recorded. Data were analyzed by ANOVA, Tukey’sand student’s t-test using SPSS version 18.0. Results: Three-way ANOVA showed a significant interaction between all the factors (p = .0001. The load bearing capacity of almost all materials reduced significantly in the wet condition in comparison with the dry condition (p = .0001. After seven days of immersion in distilled water, Filtek Supreme had significantly lower values than those of Rok and Luna, there was no significant differences between materials in the dry condition. Conclusions:In contrast to dry condition, the load-bearing capacity of specimens stored in distilled water decreased significantly over the 30 days of immersion. The load bearing capacity of nano-hybrid composites tested in this study was shown to be comparable with that of the hybrid composite.

  19. Thermal residual stresses and stress distributions under tensile and compressive loadings of short fiber reinforced metal matrix composites

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The thermal residual stresses and the stress distributions of short fiber reinforced metal matrix composite under tensile and compressive loadings were studied using large strain axisymmetric elasto-plastic finite element method. It is demonstrated that the thermal residual stresses can result in asymmetrical stress distributions and matrix plasticity. The thermal residual stresses decrease the stress transfer in tension and enhance the stress transfer in compression. The fiber volume fraction has more important effects on the thermal residual stresses and the stress distributions under tensile and compressive loadings than the fiber aspect ratio and the fiber end distance.

  20. Marginal and internal adaptation of Class II ormocer and hybrid resin composite restorations before and after load cycling.

    Science.gov (United States)

    Kournetas, N; Chakmakchi, M; Kakaboura, A; Rahiotis, C; Geis-Gerstorfer, J

    2004-09-01

    To overcome the shortcomings of the conventional composite restorative materials, ormocer materials have been introduced over the past few years. The purpose of this study was to evaluate the marginal and internal adaptation of two ormocer restorative systems (Admira, Voco and Definite, Degussa) compared to a hybrid composite one (TPH Spectrum, Dentsply/ DeTrey), before and after load cycling in Class II restorations. Standardized Class II restorations with cervical margins on enamel were divided into three groups ( n=16). Teeth of each group were filled with one of the restoratives tested and its respective bonding agent. Each group was divided into two equal subgroups. The marginal and internal adaptation of the first subgroup was evaluated after 7-day water storage at room temperature and of the second after cyclic loading in a mastication simulator (1.2x10(6) cycles, 49 N, 1.6 Hz). The occlusal and cervical marginal evaluation was conducted by videomicroscope and ranked as "excellent" and "not excellent". One thin section (150 microm), in mesial-distal direction, of each restoration, was examined under metallographic microscope to determine the quality of internal adaptation. The occlusal and cervical adaptation of both ormocer restorative systems was similar and clearly worse compared with the hybrid composite restorative one before as well as after load cycling. Concerning internal adaptation, no gap-free ormocer restorations were detected, whereas all Spectrum restorations presented perfect adaptation. The bonding agents of the ormocers formed layers with unacceptable features (pores, fractures) whereas that of the hybrid composite achieved perfect bonding layer even after loading. The rheological characteristics of the bonding agents of the ormocer restorative systems are proposed to be responsible for their inferior marginal and internal quality in Class II restorations compared with the hybrid composite one.

  1. The influence of FRCs reinforcement on marginal adaptation of CAD/CAM composite resin endocrowns after simulated fatigue loading.

    Science.gov (United States)

    Rocca, Giovanni Tommaso; Saratti, Carlo Massimo; Poncet, Antoine; Feilzer, Albert J; Krejci, Ivo

    2016-05-01

    To evaluate the marginal adaptation of endodontically treated molars restored with CAD/CAM composite resin endocrowns either with or without reinforcement by fibre reinforced composites (FRCs), used in different configurations. 32 human endodontically treated molars were cut 2 mm over the CEJ. Two interproximal boxes were created with the margins located 1 mm below the CEJ (distal box) and 1 mm over the CEJ (mesial box). All specimens were divided in four groups (n = 8). The pulp chamber was filled with: group 1 (control), hybrid resin composite (G-aenial Posterior, GC); group 2, as group 1 but covered by 3 meshes of E-glass fibres (EverStick NET, Stick Tech); group 3, FRC resin (EverX Posterior, GC); group 4, as group 3 but covered by 3 meshes of E-glass fibres. The crowns of all teeth were restored with CAD/CAM composite resin endocrowns (LAVA Ultimate, 3M). All specimens were thermo-mechanically loaded in a computer-controlled chewing machine (600,000 cycles, 1.6 Hz, 49 N and simultaneously 1500 thermo-cycles, 60 s, 5-55 °C). Marginal analysis before and after the loading was carried out on epoxy replicas by SEM at 200× magnification. For all the groups, the percentage values of perfect marginal adaptation after loading were always significantly lower than before loading (p  0.05). Within the limitations of this in vitro study, the use of FRCs to reinforce the pulp chamber of devitalized molars restored with CAD/CAM composite resin restorations did not significantly influenced their marginal quality. PMID:25854165

  2. Performance of hybrid cement composite elements under drop-weight impact load

    Directory of Open Access Journals (Sweden)

    Nguyen, V. D.

    2014-05-01

    Full Text Available The performance, under drop-weight impact load, of hybrid cement composite (HCC elements, consisting of a top layer of plain concrete (PC and a bottom layer of fibre reinforced concrete (FRC, in comparison with full-depth FRC and PC was studied. Apart from improving the tensile capacity of PC and saving fibre steel reinforcements of FRC, the results showed that HCC can effectively control the deformations and enhance the impact performance of the structural members as its outcomes were similar to that of a full-depth FRC. The analytical studies using Hughes empirical formulae (HEF and yield line theory (YLT adopted to investigate the practical use of HCC showed that they are applicable for design such HCC elements against impacts.Se estudió el comportamiento, frente a impacto de torre de caída, de elementos híbridos base cemento (HCC, formados por una capa superior de hormigón en masa (PC y una capa inferior de hormigón reforzado con fibras (FRC en comparación con elementos análogos íntegramente fabricados con FRC y PC. Además de proporcionar una mejora en la resistencia frente a flexo-tracción de los PC y un ahorro en refuerzo usando fibras de acero en el caso de los FRC, los resultados mostraron que el HCC puede controlar eficazmente las deformaciones y mejorar el rendimiento frente a impacto de los elementos estructurales ya que sus resultados fueron análogos a la de los FRC. Los estudios analíticos, utilizando HEF e YLT, adoptados para investigar el uso práctico de los HCC mostraron que los mismos son aplicables para el diseño de estos elementos frente a impacto.

  3. Methotrexate-loaded glass ionomer cements for drug release in the skeleton: An examination of composition-property relationships.

    Science.gov (United States)

    Kiri, Lauren; Filiaggi, Mark; Boyd, Daniel

    2016-01-01

    Chemotherapeutic-loaded bone cement may be an effective method of drug delivery for the management of cancer-related vertebral fractures that require cement injection for pain relief. Recent advancements in the development of aluminum-free glass ionomer cements (GICs) have rendered this class of biomaterials clinically viable for such applications. To expand the therapeutic benefits of these materials, this study examined, for the first time, their drug delivery potential. Through incrementally loading the GIC with methotrexate (MTX) by up to 10-wt%, composition-property relationships were established, correlating MTX loading with working time and setting time, as well as compressive strength, drug release, and cytotoxic effect over 31 days. The most significant finding of this study was that MTX was readily released from the GIC, while maintaining cytotoxic activity. Release correlated linearly with initial loading and appeared to be diffusion mediated, delivering a total of 1-2% of the incorporated drug. MTX loading in this range exerted minimal effects to handling and strength, indicating the clinical utility of the material was not compromised by MTX loading. The MTX-GIC systems examined herein are promising materials for combined structural delivery applications.

  4. Evaluation of a strain based failure criterion for the multi-constituent composite model under shock loading

    Science.gov (United States)

    Key, Christopher T.; Schumacher, Shane C.; Alexander, C. Scott

    2015-09-01

    This study details and demonstrates a strain-based criterion for the prediction of polymer matrix composite material damage and failure under shock loading conditions. Shock loading conditions are characterized by high-speed impacts or explosive events that result in very high pressures in the materials involved. These material pressures can reach hundreds of kbar and often exceed the material strengths by several orders of magnitude. Researchers have shown that under these high pressures, composites exhibit significant increases in stiffness and strength. In this work we summarize modifications to a previous stress based interactive failure criterion based on the model initially proposed by Hashin, to include strain dependence. The failure criterion is combined with the multi-constituent composite constitutive model (MCM) within a shock physics hydrocode. The constitutive model allows for decomposition of the composite stress and strain fields into the individual phase averaged constituent level stress and strain fields, which are then applied to the failure criterion. Numerical simulations of a metallic sphere impacting carbon/epoxy composite plates at velocities up to 1000 m/s are performed using both the stress and strain based criterion. These simulation results are compared to experimental tests to illustrate the advantages of a strain-based criterion in the shock environment.

  5. Strontium-loaded mineral bone cements as sustained release systems : Compositions, release properties, and effects on human osteoprogenitor cells

    OpenAIRE

    Tadier, Solène; Bareille, Reine; Siadous, Robin; Marsan, Olivier; Charvillat, Cédric; Cazalbou, Sophie; Amédée, Joelle; Rey, Christian; Combes, Christèle

    2012-01-01

    This study aims to evaluate in vitro the release properties and biological behavior of original compositions of strontium (Sr)-loaded bone mineral cements. Strontium was introduced into vaterite CaCO3-dicalcium phosphate dihydrate cement via two routes: as SrCO3 in the solid phase (SrS cements), and as SrCl2 dissolved in the liquid phase (SrL cements), leading to different cement compositions after setting. Complementary analytical techniques implemented to thoroughly investigate the re...

  6. Dynamic analysis of composite beam subjected to harmonic moving load based on the third-order shear deformation theory

    Science.gov (United States)

    Rezvanil, Mohammad Javad; Kargarnovin, Mohammad Hossein; Younesian, Davood

    2011-12-01

    The response of an infinite Timoshenko beam subjected to a harmonic moving load based on the thirdorder shear deformation theory (TSDT) is studied. The beam is made of laminated composite, and located on a Pasternak viscoelastic foundation. By using the principle of total minimum potential energy, the governing partial differential equations of motion are obtained. The solution is directed to compute the deflection and bending moment distribution along the length of the beam. Also, the effects of two types of composite materials, stiffness and shear layer viscosity coefficients of foundation, velocity and frequency of the moving load over the beam response are studied. In order to demonstrate the accuracy of the present method, the results TSDT are compared with the previously obtained results based on first-order shear deformation theory, with which good agreements are observed.

  7. Constitutive Theories for Woven Composite Structures Subjected to Shock Loading; Experimental Validation Using a Conical Shock Tube

    Directory of Open Access Journals (Sweden)

    David R. Hufner

    2012-01-01

    Full Text Available Woven polymer-based composites are currently used in a wide range of marine applications. These materials often exhibit highly nonlinear, rate dependent, anisotropic behavior under shock loadings. Correlation to transient response data, beyond an initial peak, is often difficult. The state of damage evolves throughout the time history and the unloading response varies based on the amount, and nature of, the accumulated damage. Constitutive theories that address the loading and unloading responses have been developed and integrated with each other. A complete theory, applicable to transient dynamic analysis, is presented. The model is implemented within the commercial finite element code, Abaqus, in the form of a user material subroutine. In this study, the conical shock tube is used to experimentally reproduce the high strain rates and fluid structure interactions typical of underwater shock loadings. The conical shock tube data is used to validate analytical model predictions. Simulation results are in good agreement with test data.

  8. Influence of lipid composition and drug load on the in vitro performance of self-nanoemulsifying drug delivery systems

    DEFF Research Database (Denmark)

    Thomas, Nicky; Müllertz, Anette; Graf, Anja;

    2012-01-01

    The influence of lipid composition and drug load on the in vitro performance of lipid-based drug delivery systems was investigated during dispersion and in vitro lipolysis of two self-nanoemulsifying drug delivery systems (SNEDDS). SNEDDS preconcentrates consisted of the same mass ratios of lipid......, surfactant, and cosolvent but varied in the chain length of the lipid component. Utilization of the surfactant Cremophor EL resulted in pronounced changes in the droplet size of dispersed SNEDDS containing increasing drug loads of the poorly water-soluble compound simvastatin (SIM). In contrast, the droplet...... size of dispersed medium-chain (MC)-SNEDDS based on the surfactant Cremophor RH40 was not affected by increasing drug loads of SIM, whereas the droplet size of the corresponding long-chain (LC)-SNEDDS increased. During 60 min in vitro lipolysis, MC-SNEDDS maintained approximately 95% of SIM in solution...

  9. Vinyl Acetate/butyl acrylate/acrylate Research of Ternary Soap-free Emulsion Polymerization

    Directory of Open Access Journals (Sweden)

    Xiao Li-guang

    2016-01-01

    Full Text Available Through the vinyl acetate/butyl acrylate/acrylic acrylic emulsion preparation without soap vinegar, with solid content, gel, emulsion stability and film forming properties and tensile strength as the main index to study the effect of raw materials on the properties of emulsion. Through the infrared spectrometer soap-free emulsion for microscopic analysis research. Study of the ternary soap-free vinegar acrylic emulsion with good performance.

  10. 聚偏氟乙烯-丙烯酸酯原位乳液聚合的研究%Study of PVDF-Acrylate Composite Emulsion Synthesized by i n-situ Emulsion Polymerization

    Institute of Scientific and Technical Information of China (English)

    张侃; 潘智存; 刘德山; 周其庠

    2001-01-01

    Acrylate emulsion modified with polyvinylidene fluoride(P VDF) was prepared by in-situ emulsion polymerization through dissolving PVDF in the acrylate monome rs and in the presence of carbon-fluorine surfacta nts(FC-80,fluorinated polyether)and carbon-hydrogen surfactants(SLS,OP-10). The emulsion did not separate in six months.The crystallization behavior of emulsio n films was investigated with differential scanning calorimeter and polarized opt ical microscope.The results i ndicated that emulsion films were transparent because the crystallization of PVD F was destroyed by acrylate.%采用原位乳液聚合, 将聚偏氟乙烯(PVDF)溶解于 丙烯酸 酯单体中,以碳氟表面活性剂(FC-80,氟醚)和碳氢表面活性剂(SLS、OP-10)为乳化剂, 合成了PVDF改性的聚丙烯酸酯乳液,乳液在六个月内无分层现象。并用偏光显微镜和示差量 热扫描仪对涂膜的结晶行为和热行为进行了研究,结果表明:聚丙烯酸酯破坏了聚偏氟乙烯 的结晶性使得改性后的胶膜透明

  11. Discrete meso-element simulation of the failure behavior of short-fiber composites under dynamic loading

    Science.gov (United States)

    Liu, Wenyan; Tang, Z. P.; Liu, Yunxin

    2000-04-01

    In recent years, more attention has been paid to a better understanding of the failure behavior and mechanism of heterogeneous materials at the meso-scale level. In this paper, the crack initiation and development in epoxy composites reinforced with short steel fibers under dynamic loading were simulated and analyzed with the 2D Discrete Meso-Element Dynamic Method. Results show that the damage process depends greatly on the binding property between matrix and fibers.

  12. The Study of Stability of Compression-Loaded Multispan Composite Panel Upon Failure of Elements Binding it to Panel Supports

    Science.gov (United States)

    Zamula, G. N.; Ierusalimsky, K. M.; Fomin, V. P.; Grishin, V. I.; Kalmykova, G. S.

    1999-01-01

    The present document is a final technical report carried out within co-operation between United States'NASA Langley RC and Russia's Goskomoboronprom in aeronautics, and continues similar programs, accomplished in 1996, 1997, and 1998, respectively). The report provides results of "The study of stability of compression-loaded multispan composite panels upon failure of elements binding it to panel supports"; these comply with requirements established at TsAGI on 24 March 1998 and at NASA on 15 September 1998.

  13. Effect of a low glycemic load on body composition and Homeostasis Model Assessment (HOMA) in overweight and obese subjects

    OpenAIRE

    A. L. Armendáriz-Anguiano; A. Jiménez-Cruz; M. Bacardí-Gascón; L. Hurtado-Ayala

    2011-01-01

    bjective: The aim of this study was to compare the effects of different glycemic load diets on biochemical data and body composition, in overweight and obese subjects, during a 6-month period. Research design and methods: This study was an experimental, randomized, parallel design. Anthropometric measurements and biochemical data were measured at baseline at 3 and at 6 months. All subjects completed 3-day dietary intake diaries at the baseline period and during the third and the sixth months....

  14. Radiation curing applications of palm oil acrylates

    International Nuclear Information System (INIS)

    Various palm oil based urethan acrylate prepolymers (UP) were prepared from palm oil based polyols, diisocyanate compounds and hydroxyl terminated acrylate monomers by following procedure derived from established methods. The products were compared with each other in term of their molecular weights (MW), viscosities, curing speed by UV irradiation, gel contents and film hardness. The molecular structure of diisocyanate compounds and hydroxyl acrylate monomers were tend to determine the molecular weights and hence viscosities of the final products of urethan acrylate prepolymers (UP), whereas, the MW of the UP has no direct effects on the UV curing properties of the prepolymers. (author)

  15. New fly ash TiO2 composite for the sustainable treatment of wastewater with complex pollutants load

    International Nuclear Information System (INIS)

    Graphical abstract: - Highlights: • A novel substrate FADAht is obtained by hydrothermal synthesis. • The composite type structure has specific surface ten times higher than fly ash. • Simultaneous removal of three pollutants reaches efficiencies above 90%. • Kinetic investigations show fast adsorption of the dye on the new composite. - Abstract: The goal of this paper was to develop a new composite obtained in mild hydrothermal conditions starting from fly ash (a waste raising significant environmental problems), and TiO2. The composite was characterized through XRD, SEM/EDX, AFM, and BET surface measurements. The composite was further used for the advanced treatment of wastewaters with multiple-pollutants load. The photocatalytic efficiency of the powder composite was tested on synthetic solutions containing a heavy metal cation (copper), a dye (methyl orange), and a surfactant (sodium dodecylbenzenesulfonate), under UV and simulated solar radiation. Comparative experiments were done in systems with and without H2O2 showing a significant increase in efficiency for methyl orange removal from mono-, bi-, and tri-pollutants solutions. The process parameters were optimized and the adsorption mechanisms are discussed, outlining that adsorption is the limiting step. Experiments also outlined that homogeneous photocatalysis (using H2O2) is less efficient then the heterogeneous process using the novel composite, both under UV and simulated solar radiation

  16. New fly ash TiO{sub 2} composite for the sustainable treatment of wastewater with complex pollutants load

    Energy Technology Data Exchange (ETDEWEB)

    Visa, Maria, E-mail: maria.visa@unitbv.ro; Isac, Luminita; Duta, Anca

    2015-06-01

    Graphical abstract: - Highlights: • A novel substrate FADAht is obtained by hydrothermal synthesis. • The composite type structure has specific surface ten times higher than fly ash. • Simultaneous removal of three pollutants reaches efficiencies above 90%. • Kinetic investigations show fast adsorption of the dye on the new composite. - Abstract: The goal of this paper was to develop a new composite obtained in mild hydrothermal conditions starting from fly ash (a waste raising significant environmental problems), and TiO{sub 2}. The composite was characterized through XRD, SEM/EDX, AFM, and BET surface measurements. The composite was further used for the advanced treatment of wastewaters with multiple-pollutants load. The photocatalytic efficiency of the powder composite was tested on synthetic solutions containing a heavy metal cation (copper), a dye (methyl orange), and a surfactant (sodium dodecylbenzenesulfonate), under UV and simulated solar radiation. Comparative experiments were done in systems with and without H{sub 2}O{sub 2} showing a significant increase in efficiency for methyl orange removal from mono-, bi-, and tri-pollutants solutions. The process parameters were optimized and the adsorption mechanisms are discussed, outlining that adsorption is the limiting step. Experiments also outlined that homogeneous photocatalysis (using H{sub 2}O{sub 2}) is less efficient then the heterogeneous process using the novel composite, both under UV and simulated solar radiation.

  17. Dietary carbohydrate composition can change waste production and biofilter load in recirculating aquaculture systems

    NARCIS (Netherlands)

    Meriac, A.; Eding, E.H.; Schrama, J.W.; Kamstra, A.; Verreth, J.A.J.

    2014-01-01

    This study investigated the effect of dietary carbohydrate composition on the production, recovery and degradability of fecal waste from rainbow trout (Oncorhynchus mykiss) in recirculating aquaculture systems (RAS). Dietary carbohydrate composition was altered by substituting starch with non-starch

  18. Bearing-bypass loading in composite joints - Testing and stress analysis

    Science.gov (United States)

    Crews, John H., Jr.; Naik, Rajiv A.

    1989-01-01

    A combined experimental and analytical study of bearing and bypass loading on single-fastener specimens of a 16-ply, quasi-isotropic T300/5208 graphite/epoxy laminate with a centrally located hole is reported. The specimens were loaded in either tension or compression, and onset damage, ultimate strengths, and corresponding failure modes were determined. The tension data showed the expected linear interaction for combined bearing-bypass loading with damage developing in the net-section tension mode. However, the bearing-onset strengths showed an unexpected interaction of the bearing and compressive bypass loads in which the latter reduced the bearing-onset strength. A linear finite element analysis showed that bearing-bypass loading had a marked influence on the bolt-hole contact which in turn had a significant effect on local stresses.

  19. Predicting Failure Progression and Failure Loads in Composite Open-Hole Tension Coupons

    Science.gov (United States)

    Arunkumar, Satyanarayana; Przekop, Adam

    2010-01-01

    Failure types and failure loads in carbon-epoxy [45n/90n/-45n/0n]ms laminate coupons with central circular holes subjected to tensile load are simulated using progressive failure analysis (PFA) methodology. The progressive failure methodology is implemented using VUMAT subroutine within the ABAQUS(TradeMark)/Explicit nonlinear finite element code. The degradation model adopted in the present PFA methodology uses an instantaneous complete stress reduction (COSTR) approach to simulate damage at a material point when failure occurs. In-plane modeling parameters such as element size and shape are held constant in the finite element models, irrespective of laminate thickness and hole size, to predict failure loads and failure progression. Comparison to published test data indicates that this methodology accurately simulates brittle, pull-out and delamination failure types. The sensitivity of the failure progression and the failure load to analytical loading rates and solvers precision is demonstrated.

  20. Computed Tomography analysis of damage in composites subjected to impact loading

    OpenAIRE

    E. Guglielmino; G. Epasto; Crupi, V.

    2011-01-01

    The composites, used in the transportation engineering, include different classes with a wide range of materials and properties within each type. The following different typologies of composites have been investigated: laminated composites, PVC foam sandwiches, aluminium foam and honeycomb sandwiches.Aim of this paper was the analysis of low-velocity impact response of such composites and the investigation of their collapse modes. Low velocity impact tests were carried out by a drop test mach...

  1. SYNTHESIS AND IN VITRO CHARACTERIZATION OF HYDROXYPROPYL METHYLCELLULOSE-GRAFT-POLY (ACRYLIC ACID/2-ACRYLAMIDO-2-METHYL-1-PROPANESULFONIC ACID) POLYMERIC NETWORK FOR CONTROLLED RELEASE OF CAPTOPRIL.

    Science.gov (United States)

    Furqan Muhammad, Iqbal; Mahmood, Ahmad; Aysha, Rashid

    2016-01-01

    A super-absorbent hydrogel was developed by crosslinking of 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) and acrylic acid with hydroxypropyl methylcellulose (HPMC) for controlled release drug delivery of captopril, a well known antihypertensive drug. Acrylic acid and AMPS were polymerized and crosslinked with HPMC by free radical polymerization, a widely used chemical crosslinking method. N,N'-methylenebisacrylamide (MBA) and potassium persulfate (KPS) were added as cross-linker and initiator, respectively. The hydrogel formulation was loaded with captopril (as model drug). The concentration of captopril was monitored at 205 nm using UV spectrophotometer. Equilibrium swelling ratio was determined at pH 2, 4.5 and 7.4 to evaluate the pH responsiveness of the formed hydrogel. The super-absorbent hydrogels were evaluated by FTIR, SEM, XRD, and thermal analysis (DSC and TGA). The formation of new copolymeric network was determined by FTIR, XRD, TGA and DSC analysis. The hydrogel formulations with acrylic acid and AMPS ratio of 4: 1 and lower amounts of crosslinker had shown maximum swelling. Moreover, higher release rate of captopril was observed at pH 7.4 than at pH 2, because of more swelling capacity of copolymer with increasing pH of the aqueous medium. The present research work confirms the development of a stable hydrogel comprising of HPMC with acrylic acid and AMPS. The prepared hydrogels exhibited pH sensitive behav-ior. This superabsorbent composite prepared could be a successful drug carrier for treating hypertension. PMID:27008813

  2. The effect of bulk-resin CNT-enrichment on damage and plasticity in shear-loaded laminated composites

    KAUST Repository

    Ventura, Isaac Aguilar

    2013-07-01

    One way to improve multi functionality of epoxy-based laminated composites is to dope the resin with carbon nanotubes. Many investigators have focused on the elastic and fracture behavior of such nano-modified polymers under tensile loading. Yet, in real structural applications, laminated composites can exhibit plasticity and progressive damage initiated mainly by shear loading. We investigated the damage and plasticity induced by the addition of carbon nanotubes to the matrix of a glass fiber/epoxy composite system. We characterized both the modified epoxy resin and the associated modified laminates using classical mesoscale analysis. We used dynamic mechanical analysis, scanning electron microscopy, atomic force microscopy and classical mechanical testing to characterize samples with different concentrations of nanofillers. Since the samples were prepared using the solvent evaporation technique, we also studied the influence of this process. We found that in addition to the global increase in elastic regime properties, the addition of carbon nanotubes also accelerates the damage process in both the bulk resin and its associated glass-fiber composite. © 2013 Elsevier Ltd.

  3. Reactivity Ratios of Diethyldiallylammonium Chloride with Acrylamide or Acrylic Acid

    Institute of Scientific and Technical Information of China (English)

    Li Hua LIU; Zhi Qiang LIU; Zhu Qing GONG

    2006-01-01

    The compositions of copolymers of diethyldiallylammonium chloride (DEDAAC) with acrylamide (AM), acrylic acid (AA) or sodium acrylic acid (NaAA) at low conversion were determined by elemental analysis, and the reactivity ratios of monomers in copolymerization were obtained by Kelen-Tudos method. The results showed that the reactivity ratios rDE and rAM are 0.31 and 5.27 for DEDAAC with AM, rDE and rAA are 0.28 and 5.15 for DEDAAC with AA, and rDE and rNaAA are 0.40 and 3.97 for DEDAAC with NaAA, respectively. The copolymerizations for DEDAAC with AM, AA or NaAA are non-ideal copolymerization and the products are random copolymers.

  4. Controlled nanostructure and high loading of single-walled carbon nanotubes reinforced polycarbonate composite

    International Nuclear Information System (INIS)

    This paper presents an effective technique to fabricate thermoplastic nanocomposites with high loading of well-dispersed single-walled carbon nanotubes (SWNTs). SWNT membranes were made from a multi-step dispersion and filtration method, and then impregnated with polycarbonate solution to make thermoplastic nanocomposites. High loading of nanotubes was achieved by controlling the viscosity of polycarbonate solution. SEM and AFM characterization results revealed the controlled nanostructure in the resultant nanocomposites. Dynamic mechanical property tests indicated that the storage modulus of the resulting nanocomposites at 20 wt% nanotubes loading was improved by a factor of 3.4 compared with neat polycarbonate material. These results suggest the developed approach is an effective way to fabricate thermoplastic nanocomposites with good dispersion and high SWNT loading

  5. Preparation and self-sterilizing properties of Ag@TiO2–styrene–acrylic complex coatings

    International Nuclear Information System (INIS)

    In this study, we report a simple and cost-effective method for self-sterilized complex coatings obtained by Ag@TiO2 particle incorporation into styrene–acrylic latex. The Ag@TiO2 particles were prepared via a coupling agent modification process. The composite latices characterized by transmission electron microscopy (TEM) study were highly homogeneous at the nanometric scale, and the Ag@TiO2 particles were well dispersed and exhibited an intimate contact between both the organic and inorganic components. The Ag@TiO2 nanoparticles significantly enhanced the absorption in the visible region and engendered a good heat-insulating effect of the complex coatings. Moreover, the Ag@TiO2 nanoparticle incorporation into this polymer matrix renders self-sterilized nanocomposite materials upon light excitation, which are tested against Escherichia coli and Staphylococcus aureus. The complex coatings display an impressive performance in the killing of all micro-organisms with a maximum for a Ag@TiO2 loading concentration of 2–5 wt.%. The weathering endurance of the complex coating was also measured. - Highlights: ► We prepared Ag@TiO2–styrene–acrylic complex latex in one pot. ► Good antibacterial performances of complex coatings were observed. ► The complex coating was resistant to weathering after 48 h. ► The complex coating exhibits good heat-insulating effect

  6. Acrylates and methacrylates of formal-glycerine

    International Nuclear Information System (INIS)

    Present article is devoted acrylates and methacrylates of formal-glycerine. The formal-glycerine was obtained in the form of mixture of isomers 1.2 and 1.3 from glycerine and paraform with hydrochloric acid. The structure of obtained acrylates and methacrylates is studied by means of molecular refraction, element analysis and infrared spectroscopy.

  7. Numerical simulation of progressive debonding in fiber reinforced composite under transverse loading

    DEFF Research Database (Denmark)

    Kushch, V.; Shmegera, S.V.; Brøndsted, Povl;

    2011-01-01

    . Then, the effect on debonding progress of local stress redistribution due to interaction between the fibers was studied in the framework of two-inclusion model. Simulation of progressive debonding in fiber reinforced composite using the many-fiber models of composite has been performed. It has been...... shown that the developed model provides detailed analysis of the progressive debonding phenomenon including the interface crack cluster formation, overall stiffness reduction and induced anisotropy of the effective elastic moduli of composite....

  8. 纳米TiO2原位聚合硅丙复合乳液的制备%Preparation of Nano TiO2 Silicone- Acrylate Composite Emulsion by In-Situ Polymerization

    Institute of Scientific and Technical Information of China (English)

    张绍原; 潘峥; 潘金炎; 方青; 郑豪

    2012-01-01

    采用硅烷偶联剂对纳米二氧化钛进行表面处理,以改性纳米二氧化钛和有机硅中间体为种子乳液,以过硫酸钾为引发剂,甲基丙烯酸甲酯(MMA)、甲基丙烯酸丁酯(MBA)为主要共聚单体,通过原位聚合反应,合成纳米TiO2 -硅丙复合乳液.采用红外光谱、透射电镜(TEM)、激光粒度分布等手段,对所制备的纳米TiO2 -硅丙复合乳液进行了表征,证明所得产品是硅氧烷和丙烯酸酯的共聚物,具有核/壳结构,且乳液粒径分布较窄,平均粒径在63 nm左右.%The nanometer TiO2 was modified by silane coupling agent. With the modified TiO2 and sili-cone intermediate as seed emulsion, the methyl methacrylate (MMA) , methyl butylacrylate (MBA) as the main monomers, the potassium peroxydisulfate as initiator, the nano TiO2/silicone - acrylate core/shell emulsions were prepared by in situ emulsion polymerization. The nano TiO2/silicone - acrylate copolymer was characterized by infrared spectroscopy, transmission electron microscopy ( TEM) and laser particle size distribution. The product was determined as a silicone - acrylate copolymer with a core/shell structure and an average particle size about 63 nm.

  9. Carbonaceous composition changes of heavy-duty diesel engine particles in relation to biodiesels, aftertreatments and engine loads

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Man-Ting; Chen, Hsun-Jung [Department of Environmental Engineering, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung 40254, Taiwan (China); Young, Li-Hao, E-mail: lhy@mail.cmu.edu.tw [Department of Occupational Safety and Health, China Medical University, 91 Hsueh-Shih Road, Taichung 40402, Taiwan (China); Yang, Hsi-Hsien [Department of Environmental Engineering and Management, Chaoyang University of Technology, 168, Jifeng E. Road, Wufeng District, Taichung 41349, Taiwan (China); Tsai, Ying I. [Department of Environmental Engineering and Science, Chia Nan University of Pharmacy and Science, 60, Sec. 1, Erren Rd., Rende District, Tainan 71710, Taiwan (China); Wang, Lin-Chi [Department of Civil Engineering and Geomatics, Cheng Shiu University, 840, Chengcing Road, Niaosong District, Kaohsiung 83347, Taiwan (China); Lu, Jau-Huai [Department of Mechanical Engineering, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung 40254, Taiwan (China); Chen, Chung-Bang [Fuel Quality and Engine Performance Research, Refining and Manufacturing Research Institute, Chinese Petroleum Corporation, 217, Minsheng S. Road, West District, Chiayi 60051, Taiwan (China)

    2015-10-30

    Highlights: • We study particulate OC and EC under 3 fuels, 2 aftertreatments and 4 engine loads. • Negligible to minor OC and EC changes with low, ultralow sulfur and 10% biodiesels. • Moderate reductions of EC and particularly OC from diesel oxidation catalyst (DOC). • Large reductions of OC and particularly EC from DOC plus diesel particulate filter. • Highest at idle, whereas OC decreases but EC increases from low to high load. - Abstract: Three biodiesels and two aftertreatments were tested on a heavy-duty diesel engine under the US FTP transient cycle and additional four steady engine loads. The objective was to examine their effects on the gaseous and particulate emissions, with emphasis given to the organic and elemental carbon (OC and EC) in the total particulate matter. Negligible differences were observed between the low-sulfur (B1S50) and ultralow-sulfur (B1S10) biodiesels, whereas small reductions of OC were identified with the 10% biodiesel blend (B10). The use of diesel oxidation catalyst (DOC1) showed moderate reductions of EC and particularly OC, resulting in the OC/EC ratio well below unity. The use of DOC plus diesel particulate filter (DOC2+DPF) yielded substantial reductions of OC and particularly EC, resulting in the OC/EC ratio well above unity. The OC/EC ratios were substantially above unity at idle and low load, whereas below unity at medium and high load. The above changes in particulate OC and EC are discussed with respect to the fuel content, pollutant removal mechanisms and engine combustion conditions. Overall, the present study shows that the carbonaceous composition of PM could change drastically with engine load and aftertreatments, and to a lesser extent with the biodiesels under study.

  10. Compression creep rupture of an E-glass/vinyl ester composite subjected to combined mechanical and fire loading conditions

    Science.gov (United States)

    Boyd, Steven Earl

    Polymer matrix composites are seeing increasing use in structural systems (e.g. ships, bridges) and require a quantitative basis for describing their performance under combined mechanical load and fire. Although much work has been performed to characterize the flammability, fire resistance and toxicity of these composite systems, an understanding of the structural response of sandwich type structures and laminate panels under combined mechanical and thermal loads (simulating fire conditions) is still largely unavailable. Therefore a research effort to develop a model to describe the structural response of these glass/vinyl esters systems under fire loading conditions is relevant to the continuing and future application of polymer matrix composites aboard naval ships. The main goal of the effort presented here is to develop analytical models and finite element analysis methods and tools to predict limit states such as local compression failures due to micro-buckling, residual strength and times to failure for composite laminates at temperatures in the vicinity of the glass transition where failure is controlled by viscoelastic effects. Given the importance of compression loading to a structure subject to fire exposure, the goals of this work are succinctly stated as the: (a) Characterization of the non-linear viscoelastic and viscoplastic response of the E-glass/vinyl ester composite above Tg. (b) Description of the laminate compression mechanics as a function of stress and temperature including viscoelasticity. (c) Viscoelastic stress analysis of a laminated panel ([0/+45/90/-45/0] S) using classical lamination theory (CLT). Three manuscripts constitute this dissertation which is representative of the three steps listed above. First, a detailed characterization of the nonlinear thermoviscoelastic response of Vetrotex 324/Derakane 510A--40 through Tg was conducted using the Time--Temperature--Stress--Superposition Principle (TTSSP) and Zapas--Crissman model. Second

  11. Curaua fiber reinforced high-density polyethylene composites: effect of impact modifier and fiber loading

    Directory of Open Access Journals (Sweden)

    Jaqueline Albano de Morais

    2016-01-01

    Full Text Available Abstract Short fibers are used in thermoplastic composites to increase their tensile and flexural resistance; however, it often decreases impact resistance. Composites with short vegetal fibers are not an exception to this behavior. The purpose of this work is to produce a vegetal fiber reinforced composite with improved tensile and impact resistance in relation to the polymer matrix. We used poly(ethylene-co-vinyl acetate, EVA, to recover the impact resistance of high density polyethylene, HDPE, reinforced with Curauá fibers, CF. Blends and composites were processed in a corotating twin screw extruder. The pure polymers, blends and composites were characterized by differential scanning calorimetry, thermogravimetry, infrared spectroscopy, scanning electron microscopy, tensile mechanical properties and Izod impact resistance. EVA used as impact modifier in the HDPE matrix exhibited a co-continuous phase and in the composites the fibers were homogeneously dispersed. The best combination of mechanical properties, tensile, flexural and impact, were obtained for the formulations of composites with 20 wt. % of CF and 20 to 40 wt. % of EVA. The composite prepared with 20 wt. % EVA and containing 30 wt. % of CF showed impact resistance comparable to pure HDPE and improved tensile and flexural mechanical properties.

  12. Changes in muscle size and MHC composition in response to resistance exercise with heavy and light loading intensity

    DEFF Research Database (Denmark)

    Holm, Lars; Reitelseder, Søren; Pedersen, T.G.;

    2008-01-01

    Muscle mass accretion is accomplished by heavy-load resistance training. The effect of light-load resistance exercise has been far more sparsely investigated with regard to potential effect on muscle size and contractile strength. We applied a resistance exercise protocol in which the same indivi...... in healthy young men. However, LL resistance training was inferior to HL training in evoking adaptive changes in muscle size and contractile strength and was insufficient to induce changes in MHC composition.......Muscle mass accretion is accomplished by heavy-load resistance training. The effect of light-load resistance exercise has been far more sparsely investigated with regard to potential effect on muscle size and contractile strength. We applied a resistance exercise protocol in which the same.......05) in HL but remained unchanged in LL (4 +/- 5%, not significant). Finally, MHC IIX protein expression was decreased with HL but not LL, despite identical total workload in HL and LL. Our main finding was that LL resistance training was sufficient to induce a small but significant muscle hypertrophy...

  13. Large Scale Applications Using FBG Sensors: Determination of In-Flight Loads and Shape of a Composite Aircraft Wing

    Directory of Open Access Journals (Sweden)

    Matthew J. Nicolas

    2016-06-01

    Full Text Available Technological advances have enabled the development of a number of optical fiber sensing methods over the last few years. The most prevalent optical technique involves the use of fiber Bragg grating (FBG sensors. These small, lightweight sensors have many attributes that enable their use for a number of measurement applications. Although much literature is available regarding the use of FBGs for laboratory level testing, few publications in the public domain exist of their use at the operational level. Therefore, this paper gives an overview of the implementation of FBG sensors for large scale structures and applications. For demonstration, a case study is presented in which FBGs were used to determine the deflected wing shape and the out-of-plane loads of a 5.5-m carbon-composite wing of an ultralight aerial vehicle. The in-plane strains from the 780 FBG sensors were used to obtain the out-of-plane loads as well as the wing shape at various load levels. The calculated out-of-plane displacements and loads were within 4.2% of the measured data. This study demonstrates a practical method in which direct measurements are used to obtain critical parameters from the high distribution of FBG sensors. This procedure can be used to obtain information for structural health monitoring applications to quantify healthy vs. unhealthy structures.

  14. Testing and Analysis of a Composite Non-Cylindrical Aircraft Fuselage Structure. Part 1; Ultimate Design Loads

    Science.gov (United States)

    Przekop, Adam; Jegley, Dawn C.; Lovejoy, Andrew E.; Rouse, Marshall; Wu, Hsi-Yung T.

    2016-01-01

    The Environmentally Responsible Aviation Project aimed to develop aircraft technologies enabling significant fuel burn and community noise reductions. Small incremental changes to the conventional metallic alloy-based 'tube and wing' configuration were not sufficient to achieve the desired metrics. One airframe concept identified by the project as having the potential to dramatically improve aircraft performance was a composite-based hybrid wing body configuration. Such a concept, however, presented inherent challenges stemming from, among other factors, the necessity to transfer wing loads through the entire center fuselage section which accommodates a pressurized cabin confined by flat or nearly flat panels. This paper discusses finite element analysis and testing of a large-scale hybrid wing body center section structure developed and constructed to demonstrate that the Pultruded Rod Stitched Efficient Unitized Structure concept can meet these challenging demands of the next generation airframes. Part I of the paper considers the five most critical load conditions, which are internal pressure only and positive and negative g-loads with and without internal pressure. Analysis results are compared with measurements acquired during testing. Performance of the test article is found to be closely aligned with predictions and, consequently, able to support the hybrid wing body design loads in pristine and barely visible impact damage conditions.

  15. Load-to-failure bending test of wood composite beams connected by gang nail

    Directory of Open Access Journals (Sweden)

    A.V. Karelskiy

    2015-03-01

    Full Text Available The results of a bending test of wood composite beams connected by gang nail are presented in this paper. Two types of wood composite beams fracture were observed: brittle and ductile. In addition, a numerical model of wood composite beams was produced and the results of the numerical investigations were analyzed. Compliance of connection «gang nail – wood» was considered by means of input elements with a reduced modulus of elasticity in the numerical model. Then the theoretical and experimental results of stress and strain state of a composite beam with gang nail were compared. The conclusion was made about the efficiency of gang nail application for increased shear resistance of wood composite structures not only for reinforcement but also for production of new beam structures.

  16. Paclitaxel-loaded poly(lactide-co-glycolide)/poly(ethylene vinyl acetate) composite for stent coating by ultrasonic atomizing spray

    Science.gov (United States)

    Yuk, Soon Hong; Oh, Keun Sang; Park, Jinah; Kim, Soon-Joong; Kim, Jung Ho; Kwon, Il Keun

    2012-04-01

    The mixture of poly(lactide-co-glycolide) (PLGA) and poly(ethylene vinyl acetate) (PEVA) forms a homogeneous liquid in an organic solvent such as tetrahydrofuran, and a phase-separated PLGA/PEVA composite can be prepared from it by evaporating the organic solvent. Exploiting this phenomenon, we designed a novel method of preparing a drug-loaded PLGA/PEVA composite and used it for coating drug-eluting stents (DESs). Paclitaxel (PTX), an anticancer drug, was chosen as a model drug. PLGA acts as a microdepot for PTX, and PEVA provides mechanical strength to the coating material. The presence of PLGA in the PLGA/PEVA composite suppressed PTX crystallization in the coating material, and PTX showed a sustained release rate over more than 30 days. The mechanical strength of the PLGA/PEVA composite was better than that of PEVA used as a control. After coating the stent with a PLGA/PEVA composite using ultrasonic atomizing spray, the morphology of the coated material was observed by scanning electron microscopy, and the release pattern of PTX was measured by high-performance liquid chromatography.

  17. New fly ash TiO2 composite for the sustainable treatment of wastewater with complex pollutants load

    Science.gov (United States)

    Visa, Maria; Isac, Luminita; Duta, Anca

    2015-06-01

    The goal of this paper was to develop a new composite obtained in mild hydrothermal conditions starting from fly ash (a waste raising significant environmental problems), and TiO2. The composite was characterized through XRD, SEM/EDX, AFM, and BET surface measurements. The composite was further used for the advanced treatment of wastewaters with multiple-pollutants load. The photocatalytic efficiency of the powder composite was tested on synthetic solutions containing a heavy metal cation (copper), a dye (methyl orange), and a surfactant (sodium dodecylbenzenesulfonate), under UV and simulated solar radiation. Comparative experiments were done in systems with and without H2O2 showing a significant increase in efficiency for methyl orange removal from mono-, bi-, and tri-pollutants solutions. The process parameters were optimized and the adsorption mechanisms are discussed, outlining that adsorption is the limiting step. Experiments also outlined that homogeneous photocatalysis (using H2O2) is less efficient then the heterogeneous process using the novel composite, both under UV and simulated solar radiation.

  18. The effect of nanoclay filler loading on the flexural strength of fiber-reinforced composites

    Directory of Open Access Journals (Sweden)

    Vajihesadat Mortazavi

    2012-01-01

    Results: For groups with the same concentration of nanoparticles, PMMA-grafted filler-loaded group showed significantly higher flexural strength, except for 0.2% wt. For groups that contain PMMA-grafted nanoclay fillers, the 2% wt had the highest flexural strength value with significant difference to other subgroups. 1% wt and 2% wt showed significantly higher values compared to control (P 0.05. Flexural modulus of 2%, 5% wt PMMA-grafted and 0.5%, 1%, 2%, 5% wt unmodified nanoclay particles-loaded subgroups decreased significantly compared to control group (P < 0.05. Conclusions: PMMA-grafted nanoclay filler loading may enhance the flexural strength of FRCs. Addition of unmodified nanoparticles cannot significantly improve the flexural strength of FRCs. Addition of both unmodified and PMMA-grafted nanoclay particles in some concentrations decreased the flexural modulus.

  19. Study of fatigue durability of advanced composite materials under conditions of accelerated loading

    Science.gov (United States)

    Shih, H. M.

    1979-01-01

    The effect of temperature on the tension-tension fatigue life of the T300/5208 graphite/epoxy angle-ply laminate system was investigated in an effort to develop an acceptable and reliable method of accelerated loading. Typical S log sub 10 N curves were determined experimentally at 25 C, 75 C, and 115 C. The time-temperature superposition principle was employed to find the shift factors of uniaxial fatigue strength, and a general linear equation of S log sub 10 N for shifting purpose was established. The combined techniques of cyclic creep measurements and optical microscopy upon fatigue failure allow some assessment of the possible physical basis of S log 10 N curve shifting. Before fatigue, the laminates at all test temperatures and stress levels undergo a unique damage mechanism during fatigue loading. It is concluded that an accelerated loading method is feasible.

  20. Parametric Study on the Response of Compression-Loaded Composite Shells With Geometric and Material Imperfections

    Science.gov (United States)

    Hilburger, Mark W.; Starnes, James H., Jr.

    2004-01-01

    The results of a parametric study of the effects of initial imperfections on the buckling and postbuckling response of three unstiffened thinwalled compression-loaded graphite-epoxy cylindrical shells with different orthotropic and quasi-isotropic shell-wall laminates are presented. The imperfections considered include initial geometric shell-wall midsurface imperfections, shell-wall thickness variations, local shell-wall ply-gaps associated with the fabrication process, shell-end geometric imperfections, nonuniform applied end loads, and variations in the boundary conditions including the effects of elastic boundary conditions. A high-fidelity nonlinear shell analysis procedure that accurately accounts for the effects of these imperfections on the nonlinear responses and buckling loads of the shells is described. The analysis procedure includes a nonlinear static analysis that predicts stable response characteristics of the shells and a nonlinear transient analysis that predicts unstable response characteristics.

  1. A compact very wideband amplifying filter based on RTD loaded composite right/left-handed transmission lines.

    Science.gov (United States)

    Abu-Marasa, Mahmoud O Mahmoud; El-Khozondar, Hala Jarallah

    2015-01-01

    The composite right/left-handed (CRLH) transmission line (TL) is presented as a general TL possessing both left-handed (LH) and right-handed (RH) natures. RH materials have both positive permittivity and positive permeability, and LH materials have both negative permittivity and negative permeability. This paper aims to design and analyze nonlinear CRLH-TL transmission line loaded with resonant tunneling diode (RTD). The main application of this design is a very wideband and compact filter that amplifies the travelling signal. We used OrCAD and ADS software to analyze the proposed circuit. CRLH-TL consists of a microstrip line which is loaded with complementary split-rings resonators (CSRRs), series gaps, and shunt inductor connected parallel to the RTD. The designed structure possess a wide band that ranges from 5 to 10.5 GHz and amplifies signal up to 50 %. The proposed design is of interest to microwave compact component designers. PMID:26636021

  2. A compact very wideband amplifying filter based on RTD loaded composite right/left-handed transmission lines.

    Science.gov (United States)

    Abu-Marasa, Mahmoud O Mahmoud; El-Khozondar, Hala Jarallah

    2015-01-01

    The composite right/left-handed (CRLH) transmission line (TL) is presented as a general TL possessing both left-handed (LH) and right-handed (RH) natures. RH materials have both positive permittivity and positive permeability, and LH materials have both negative permittivity and negative permeability. This paper aims to design and analyze nonlinear CRLH-TL transmission line loaded with resonant tunneling diode (RTD). The main application of this design is a very wideband and compact filter that amplifies the travelling signal. We used OrCAD and ADS software to analyze the proposed circuit. CRLH-TL consists of a microstrip line which is loaded with complementary split-rings resonators (CSRRs), series gaps, and shunt inductor connected parallel to the RTD. The designed structure possess a wide band that ranges from 5 to 10.5 GHz and amplifies signal up to 50 %. The proposed design is of interest to microwave compact component designers.

  3. Development of palm oil-based UV-curable epoxy acrylate and urethane acrylate resins for wood coating application

    Energy Technology Data Exchange (ETDEWEB)

    Tajau, Rida; Mahmood, Mohd Hilmi; Salleh, Mek Zah; Salleh, Nik Ghazali Nik [Radiation Processing Technology Division, Malaysian Nuclear Agency (Nuclear Malaysia), Bangi, 43000 Kajang, Selangor (Malaysia); Ibrahim, Mohammad Izzat [Faculty of Science, University of Malaya (UM), 50603 Kuala Lumpur (Malaysia); Yunus, Nurulhuda Mohd [Faculty of Science and Technology, National University Malaysia (UKM), 43600 Bangi, Selangor (Malaysia)

    2014-02-12

    The trend of using renewable sources such as palm oil as raw material in radiation curing is growing due to the demand from the market to produce a more environmental friendly product. In this study, the radiation curable process was done using epoxy acrylate and urethane acrylate resins which are known as epoxidised palm olein acrylate (EPOLA) and palm oil based urethane acrylate (POBUA), respectively. The purpose of the study was to investigate curing properties and the application of this UV-curable palm oil resins for wood coating. Furthermore, the properties of palm oil based coatings are compared with the petrochemical-based compound such as ebecryl (EB) i.e. EB264 and EB830. From the experiment done, the resins from petrochemical-based compounds resulted higher degree of crosslinking (up to 80%) than the palm oil based compounds (up to 70%), where the different is around 10-15%. The hardness property from this two type coatings can reached until 50% at the lower percentage of the oligomer. However, the coatings from petrochemical-based have a high scratch resistance as it can withstand at least up to 3.0 Newtons (N) compared to the palm oil-based compounds which are difficult to withstand the load up to 1.0 N. Finally, the test on the rubber wood substrate showed that the coatings containing benzophenone photoinitiator give higher adhesion property and their also showed a higher glosiness property on the glass substrate compared to the coatings containing irgacure-819 photoinitiator. This study showed that the palm oil coatings can be a suitable for the replacement of petrochemicals compound for wood coating. The palm oil coatings can be more competitive in the market if the problems of using high percentage palm oil oligomer can be overcome as the palm oil price is cheap enough.

  4. Development of palm oil-based UV-curable epoxy acrylate and urethane acrylate resins for wood coating application

    International Nuclear Information System (INIS)

    Full-text: The trend of using renewable sources such as palm oil as raw material in radiation curing is growing due to the demand from the market to produce a more environmental friendly product. In this study, the radiation curable process was done using epoxy acrylate and urethane acrylate resins which are known as epoxidized palm olein acrylate (EPOLA) and palm oil based urethane acrylate (POBUA), respectively. The purpose of the study was to investigate curing properties and the application of this UV-curable palm oil resins for wood coating. Furthermore, the properties of palm oil based coatings are compared with the petrochemical-based compound such as ebecryl (EB) for example EB264 and EB830. From the experiment done, the resins from petrochemical-based compounds resulted higher degree of crosslinking (up to 80 %) than the palm oil based compounds (up to 70 %), where the different is around 10-15 %. The hardness property from this two type coatings can reached until 50 % at the lower percentage of the oligomer. However, the coatings from petrochemical-based have a high scratch resistance as it can withstand at least up to 3.0 Newton's (N) compared to the palm oil-based compounds which are difficult to withstand the load up to 1.0 N. Finally, the test on the rubber wood substrate showed that the coatings containing benzophenone photo initiator give higher adhesion property and their also showed a higher glossiness property on the glass substrate compared to the coatings containing irgacure-819 photo initiator. This study showed that the palm oil coatings can be a suitable for the replacement of petrochemicals compound for wood coating. The palm oil coatings can be more competitive in the market if the problems of using high percentage palm oil oligomer can be overcome as the palm oil price is cheap enough. (author)

  5. Development of palm oil-based UV-curable epoxy acrylate and urethane acrylate resins for wood coating application

    International Nuclear Information System (INIS)

    The trend of using renewable sources such as palm oil as raw material in radiation curing is growing due to the demand from the market to produce a more environmental friendly product. In this study, the radiation curable process was done using epoxy acrylate and urethane acrylate resins which are known as epoxidised palm olein acrylate (EPOLA) and palm oil based urethane acrylate (POBUA), respectively. The purpose of the study was to investigate curing properties and the application of this UV-curable palm oil resins for wood coating. Furthermore, the properties of palm oil based coatings are compared with the petrochemical-based compound such as ebecryl (EB) i.e. EB264 and EB830. From the experiment done, the resins from petrochemical-based compounds resulted higher degree of crosslinking (up to 80%) than the palm oil based compounds (up to 70%), where the different is around 10-15%. The hardness property from this two type coatings can reached until 50% at the lower percentage of the oligomer. However, the coatings from petrochemical-based have a high scratch resistance as it can withstand at least up to 3.0 Newtons (N) compared to the palm oil-based compounds which are difficult to withstand the load up to 1.0 N. Finally, the test on the rubber wood substrate showed that the coatings containing benzophenone photoinitiator give higher adhesion property and their also showed a higher glosiness property on the glass substrate compared to the coatings containing irgacure-819 photoinitiator. This study showed that the palm oil coatings can be a suitable for the replacement of petrochemicals compound for wood coating. The palm oil coatings can be more competitive in the market if the problems of using high percentage palm oil oligomer can be overcome as the palm oil price is cheap enough

  6. Curcumin-Loaded Chitosan/Gelatin Composite Sponge for Wound Healing Application

    Directory of Open Access Journals (Sweden)

    Van Cuong Nguyen

    2013-01-01

    Full Text Available Three composite sponges were made with 10% of curcumin and by using polymers, namely, chitosan and gelatin with various ratios. The chemical structure and morphology were evaluated by FTIR and SEM. These sponges were evaluated for water absorption capacity, antibacterial activity, in vitro drug release, and in vivo wound healing studies by excision wound model using rabbits. The in vivo study presented a greater wound closure in wounds treated with curcumin-composite sponge than those with composite sponge without curcumin and untreated group. These obtained results showed that combination of curcumin, chitosan and gelatin could improve the wound healing activity in comparison to chitosan, and gelatin without curcumin.

  7. THE BEHAVIOR OF TWO COLLINEAR CRACKS IN MAGNETO-ELECTRO-ELASTIC COMPOSITES UNDER ANTI-PLANE SHEAR STRESS LOADING

    Institute of Scientific and Technical Information of China (English)

    Sun Yuguo; Zhou Zhengong

    2005-01-01

    In this paper, the behavior of two collinear cracks in magneto-electro-elastic composite material under anti-plane shear stress loading is studied by the Schmidt method for permeable electric boundary conditions. By using the Fourier transform, the problem can be solved with a set of triple integral equations in which the unknown variable is the jump of displacements across the crack surfaces. In solving the triple integral equations, the unknown variable is expanded in a series of Jacobi polynomials. Numerical solutions are obtained. It is shown that the stress field is independent of the electric field and the magnetic flux.

  8. Empirical Model Development for Predicting Shock Response on Composite Materials Subjected to Pyroshock Loading. Volume 2, Part 1; Appendices

    Science.gov (United States)

    Gentz, Steven J.; Ordway, David O.; Parsons, David S.; Garrison, Craig M.; Rodgers, C. Steven; Collins, Brian W.

    2015-01-01

    The NASA Engineering and Safety Center (NESC) received a request to develop an analysis model based on both frequency response and wave propagation analyses for predicting shock response spectrum (SRS) on composite materials subjected to pyroshock loading. The model would account for near-field environment (approximately 9 inches from the source) dominated by direct wave propagation, mid-field environment (approximately 2 feet from the source) characterized by wave propagation and structural resonances, and far-field environment dominated by lower frequency bending waves in the structure. This document contains appendices to the Volume I report.

  9. Fatigue life prediction in composites using progressive damage modelling under block and spectrum loading

    DEFF Research Database (Denmark)

    Passipoularidis, Vaggelis; Philippidis, T.P.; Brøndsted, Povl

    2010-01-01

    series can be simulated. The predictions are validated against fatigue life data both from repeated block tests at a single stress ratio as well as against spectral fatigue using the WISPER, WISPERX and NEW WISPER load sequences on a Glass/Epoxy multidirectional laminate typical of a Wind Turbine Rotor...

  10. EFFECT OF FILLER LOADING ON PHYSICAL AND FLEXURAL PROPERTIES OF RAPESEED STEM/PP COMPOSITES

    Directory of Open Access Journals (Sweden)

    Seyed Majid Zabihzadeh

    2011-03-01

    Full Text Available The objective of the study is to develop a new filler for the production of natural filler thermoplastic composites using the waste rapeseed stalks. The long-term water absorption and thickness swelling behaviors and flexural properties of rapeseed filled polypropylene (PP composites were investigated. Three different contents of filler were tested: 30, 45, and 60 wt%. Results of long-term hygroscopic tests indicated that by the increase in filler content from 30% to 60%, water diffusion absorption and thickness swelling rate parameter increased. A swelling model developed by Shi and Gardner can be used to quantify the swelling rate. The increasing of filler content reduced the flexural strength of the rapeseed/PP composites significantly. In contrast to the flexural strength, the flexural modulus improved with increasing the filler content. The flexural properties of these composites were decreased after the water uptake, due to the effect of the water molecules.

  11. Effect of fiber loading on flexural strength of hybrid sisal/hemp-HDPE composites

    Science.gov (United States)

    Aggarwal, Lakshya; Sinha, Shishir; Gupta, V. K.

    2015-05-01

    The continuing demand for sustainable materials and increasing environmental concerns have led to intense research in the field of natural fiber reinforced composites. Natural fibers are favored over synthetic fibers as reinforcement due to positive environmental benefits such as raw material utilization at source and easy disposable of the biodegradable fiber. In the present work, we have investigated flexural behavior of hybrid natural fiber reinforced HDPE composites. The matrix comprises of 50-50 ratio of virgin and recycled HDPE and the content of fibers (sisal and hemp) in the composite is varied from 10 to 30%. The natural fibers were mercerized with NaOH solution and chemically treated with maleic anhydride. The flexural specimens were prepared by injection moulding process and the testing was conducted in accordance to ASTM D790 standards. It is revealed that the flexural strength of the hybrid composite increases with the increase in fibers content when compared to specimen containing 100% HDPE.

  12. Effect of velocity on roll/slip for low and high load conditions in polymer composite

    OpenAIRE

    Sukumaran, J.; Ando, M.; Rodriguez, V.; De Baets, P.

    2011-01-01

    In the last decade polymer composites are often used without lubrication on both low and high speed applications. Some of the application areas are marine, automotive and agriculture used as bearings and cams where roll-slip is the dominant mechanism. Limited studies are made for composites relating such applications where rolling/sliding condition influences the tribological behavior of the material. Investigating the roll-slip phenomenon for identifying the influence of velocity on friction...

  13. Durability of polymer matrix composites: Viscoelastic effect on static and fatigue loading

    OpenAIRE

    Guedes, RM

    2007-01-01

    The structural applications of polymer matrix composites (PMC) demand lifetimes of 15, 25 and 50 years. However, the mechanical properties of these composites have a time dependent nature, i.e. strength and stiffness are time-dependent due to the hereditary nature (viscoelasticity) of polymers. In this context lifetime models for viscoelastic materials, i.e. energy-based criteria and fracture mechanics extended to viscoelastic media, are revised. These models are applied to predict the lifeti...

  14. A MORPHOLOGICAL STUDY OF POLY(DIVINYLBENZENE-co-ACRYLIC ACID) IN CROSSLINKING PRECIPITATION POLYMERIZATION

    Institute of Scientific and Technical Information of China (English)

    Feng Bai; Xin-lin Yang; Wen-qiang Huang

    2006-01-01

    Divinylbenzene-80 (DVB-80) and polar monomer acrylic acid (AA) having hydrogen bonding at a total monomer loading of 5 vol% were precipitated-copolymerized in a variety of organic solvents with 2,2'-azobis(isobutyronitrile) (AIBN) as initiator. The experiments were investigated from a two-dimensional matrix, i.e., the actual crosslinking degree of DVB varying from 0 to 80% and the solvent composition varying from 0 to 100% of toluene mixture with acetonitrile, when the mixture of acetonitrile and toluene was used as the reaction solvent. Under various reaction conditions, six distinct morphologies including soluble polymers, swellable microgels, coagulum, irregular microparticles, and nano-/micrometer microspheres were formed and the structures of these polymer architectures were described. A morphological map was utilized to discuss the effects of both crosslinking degree of DVB and composition of solvent on the transitions between morphology domains. The results demonstrated that the microspheres are formed by an internal contraction due to the marginal solvency of the continuous phase and the crosslinking of the polymer network through the covalent bonding from DVB as well as the interchain hydrogen-bonding between the carboxylic acid units.

  15. Enhancement of seal life through carbon composite back-up rings under shock loading conditions in defence applications

    Institute of Scientific and Technical Information of China (English)

    Shankar BHAUMIK; A. KUMARASWAMY; S. GURUPRASAD

    2016-01-01

    The life of Nitrile Butadiene Rubber (NBR) O-ring seal having shore hardness of A70 and A90 under shock loading conditions was investigated by a specially designed pneumo-hydraulic shock test rig. Shock tests have been carried out on bare seals, seal with conventional polytetrafluoroethylene (PTFE) back-up rings and seal with newly developed carbon composite back-up rings to study its behaviour under different operating conditions until failure. Experiments were conducted by varying annular gap ranging from 0.3 to 0.5 mm, oil temperature from 30 ℃ to 70 ℃ and rate of pressure rise from 600 to 2400 MPa/s. Significant enhancement in seal life was observed with carbon composite back-up ring at reduced annular clearances compared to seal life with conventional PTFE back-up ring and without back-up rings.

  16. Radiopurity measurement of acrylic for DEAP-3600

    International Nuclear Information System (INIS)

    The spherical acrylic vessel that contains the liquid argon target is the most critical detector component in the DEAP-3600 dark matter experiment. Alpha decays near the inner surface of the acrylic vessel are one of the main sources of background in the detector. A fraction of the alpha energy, or the recoiling nucleus from the alpha decay, could misreconstruct in the fiducial volume and result in a false candidate dark matter event. Acrylic has low levels of inherent contamination from 238U and 232Th. Another background of particular concern is diffusion of 222Rn during manufacturing, leading to 210Pb contamination. The maximum acceptable concentrations in the DEAP-3600 acrylic vessel are ppt levels of 238U and 232Th equivalent, and 10−8 ppt 210Pb. The impurities in the bulk acrylic will be measured by vaporizing a large quantity of acrylic and counting the concentrated residue with ultra-low background HPGe detectors and a low background alpha spectrometer. An overview of the acrylic assay technique is presented

  17. Radiopurity measurement of acrylic for DEAP-3600

    Energy Technology Data Exchange (ETDEWEB)

    Nantais, C. M.; Boulay, M. G. [Department of Physics, Engineering Physics, and Astronomy, Queen' s University, Kingston, Ontario K7L 3N6 (Canada); Cleveland, B. T. [SNOLAB, Lively, Ontario P3Y 1N2 Canada and Department of Physics, Laurentian University, Sudbury, Ontario P3E 2C6 (Canada)

    2013-08-08

    The spherical acrylic vessel that contains the liquid argon target is the most critical detector component in the DEAP-3600 dark matter experiment. Alpha decays near the inner surface of the acrylic vessel are one of the main sources of background in the detector. A fraction of the alpha energy, or the recoiling nucleus from the alpha decay, could misreconstruct in the fiducial volume and result in a false candidate dark matter event. Acrylic has low levels of inherent contamination from {sup 238}U and {sup 232}Th. Another background of particular concern is diffusion of {sup 222}Rn during manufacturing, leading to {sup 210}Pb contamination. The maximum acceptable concentrations in the DEAP-3600 acrylic vessel are ppt levels of {sup 238}U and {sup 232}Th equivalent, and 10{sup −8} ppt {sup 210}Pb. The impurities in the bulk acrylic will be measured by vaporizing a large quantity of acrylic and counting the concentrated residue with ultra-low background HPGe detectors and a low background alpha spectrometer. An overview of the acrylic assay technique is presented.

  18. 海藻酸钠接枝丙烯酸-丙烯酰胺共聚物/凹凸棒石复合材料的制备与表征%Preparation and Characterization of Sodium Alginate with Acrylic Acid-acrylamide Copolymers/Attapulgite Composites

    Institute of Scientific and Technical Information of China (English)

    胡盛; 姚雪; 周红艳; 段雯怡; 田大听; 张升晖

    2012-01-01

    Sodium alginate grafted acrylic acid-acrylamide copolymers/attapulgite composite using sodium alginate( SA), acrylic acid( AA), acrylamide( AM)was synthesized by aqueous solution polymerization with and attapulgite(AT)as raw material, potassium persulfate as initiator, and N, N-methylene-bis-acrylamide as crosslinker. The effects of the synthesis factors on water absorbency were investigated. The composites were characterized by FTIR and SEM. The results showed that when the mass ratio of acrylamide: acrylic acid was 5:1, the content of sodium alginate, attapulgite, crosslinker and initiator was 15% , 25% , 0. 095% , 0. 55%(compare to the mass of monomer), respectively, and the absorbency of the composites was highest and the water absorbent rate of the sample was 1 693.3 g·g-1 at 80℃. The FT-IR spectra showed that sodium alginate and AT participated in graft polymerization reaction with A A and AM. The structure of the sodium alginate with acrylic acid-acrylamide copolymers/attapulgite composites shown by SEM was tight but own porous surface and different sizes of holes which are beneficial to improve the water absorbent rate.%以凹凸棒石(AT)为原料、过硫酸钾为引发剂、N,N-亚甲基双丙烯酰胺为交联剂、丙烯酰胺(AM)、丙烯酸(AA)两种单体同时对海藻酸钠(sA)进行接枝改性,采用水溶液聚合法制备了海藻酸钠接枝丙烯酸-丙烯酰胺共聚物/凹凸棒石复合材料.考察了各合成因素对复合材料吸液倍率的影响,并采用FTIR、SEM对复合材料进行了表征.结果表明,当丙烯酰胺与丙烯酸的质量比为5∶1、海藻酸钠质量分数为15%(占单体丙烯酸质量,下同)、凹凸棒石用量为25%、交联剂用量为0.095%、引发剂用量为0.55%和反应温度为80℃时,制备的复合材料的吸蒸馏水倍率最高,达到l 693.3 g/g.FTIR表明,海藻酸钠、丙烯酸、丙烯酰胺和凹凸棒石共同参与了接枝聚合反应.SEM表明,凹凸棒石的引入,

  19. Gas sensing properties of conducting polymer/Au-loaded ZnO nanoparticle composite materials at room temperature

    Science.gov (United States)

    Kruefu, Viruntachar; Wisitsoraat, Anurat; Tuantranont, Adisorn; Phanichphant, Sukon

    2014-09-01

    In this work, a new poly (3-hexylthiophene):1.00 mol% Au-loaded zinc oxide nanoparticles (P3HT:Au/ZnO NPs) hybrid sensor is developed and systematically studied for ammonia sensing applications. The 1.00 mol% Au/ZnO NPs were synthesized by a one-step flame spray pyrolysis (FSP) process and mixed with P3HT at different mixing ratios (1:1, 2:1, 3:1, 4:1, and 1:2) before drop casting on an Al2O3 substrate with interdigitated gold electrodes to form thick film sensors. Particle characterizations by X-ray diffraction (XRD), nitrogen adsorption analysis, and high-resolution transmission electron microscopy (HR-TEM) showed highly crystalline ZnO nanoparticles (5 to 15 nm) loaded with ultrafine Au nanoparticles (1 to 2 nm). Film characterizations by XRD, field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray (EDX) spectroscopy, and atomic force microscopy (AFM) revealed the presence of P3HT/ZnO mixed phases and porous nanoparticle structures in the composite thick film. The gas sensing properties of P3HT:1.00 mol% Au/ZnO NPs composite sensors were studied for reducing and oxidizing gases (NH3, C2H5OH, CO, H2S, NO2, and H2O) at room temperature. It was found that the composite film with 4:1 of P3HT:1.00 mol% Au/ZnO NPs exhibited the best NH3 sensing performances with high response (approximately 32 to 1,000 ppm of NH3), fast response time (4.2 s), and high selectivity at room temperature. Plausible mechanisms explaining the enhanced NH3 response by composite films were discussed.

  20. The effect of load cycling on microleakage of low shrinkage methacrylate base composite compared with silorane base composite and SEM evaluation of marginal integrity

    Directory of Open Access Journals (Sweden)

    Hamid Kermanshah

    2013-04-01

    Full Text Available Background and Aims: Marginal seal in class V cavity and determination of the best restorative material in reducing microleakage is of great concern in operative dentistry. The aim of this study was to evaluate the effect of load cycling on the microleakage of low shrinkage composites compared with methacrylate-based composites with low shirinkage rate in class V cavity preparation. Marginal integrity of these materials was assessed using scanning electron microscope (SEM. Materials and Methods: In this in vitro study, class V cavity preparations were made on the buccal and lingual surfaces of 48 human premolars and molars (96 cavities. The specimens were divided into four groups each containing 12 teeth (24 cavities: group 1 (Kalore-GC+ G-Bond , group 2 (Futurabond NR+Grandio, group 3(All Bond SE+ Aelite LS Posterior, group 4 (LS System Adhesive Primer & Bond+Filtek P90. All the specimens were thermocycled for 2000 cycles (5-50oC. In each group, half of the specimens (n=12 were subjected to 200,000 cycles of loading at 80 N. Epoxy resin replicas of 32 specimens (4 restorations in each subgroup were evaluated using SEM and the interfacial gaps were measured. Finally, the teeth were immersed in 0.5% basic fuchsin dye for 24 hours at 370C, then sectioned and observed under stereomicroscope. The data were analyzed using Kruskal-Wallis and Mann-Whitney U tests and the comparison between occlusal and gingival microleakage was made with Wilcoxon test. Results: Within unloaded or loaded specimens, there were no significant differences in microleakage among four groups on the occlusal margins (P>0.05. But there were statistically significant differences in microleakage between silorane and Aelite on the gingival margins (P0.05. Conclusion: Silorane did not perform better than the conventional low shrinkage methacrylate-based composite in terms of sealing ability (except Aelite. Cyclic loading did not increase the extent of leakage in any groups.

  1. 纳米二氧化钛/丙烯酸酯复合乳液的制备及反应稳定性研究%Research on preparation of nano-titanium dioxide/acrylates composite emulsions and its reaction stability

    Institute of Scientific and Technical Information of China (English)

    李红强; 叶超贤; 蔡阿满; 胡哲; 曾幸荣; 吴伟卿

    2011-01-01

    采用预乳化及种子乳液聚合方法制备了纳米二氧化钛/丙烯酸酯复合乳液,研究了丙烯酸(AA)、过硫酸钾(KPS)、乳化剂及纳米二氧化钛用量对聚合反应稳定性的影响,并采用红外光谱对复合乳胶膜的结构进行了表征.结果表明:当AA、KPS、乳化剂和纳米二氧化钛的用量分别为3.0%,0.5%,3.3%和2.0%时,体系中的凝胶较少,具有良好的聚合反应稳定性.%Nano-titanium dioxide (TiO2)/acrylate composite emulsions were synthesized by pre-emulsification technology and seed emulsion polymerization method.The effect of the amount of acrylic acid ( AA) , potassium persulfate (KPS) ,emulsifier and nano-TiO2 on the polymerization reaction stability was studied,and the structure of the composite latex film was characterized.The results showed that when the amount of AA,KPS,emulsifier and nano-TiO2 were 3.0% ,0.5% ,3.3% and 2.0% ,respectively,the gel in the reaction system was little and the polymerization reaction stability was good.

  2. Numerical Investigation of T-joints with 3D Four Directional Braided Composite Fillers Under Tensile Loading

    Science.gov (United States)

    Li, Xiao-kang; Liu, Zhen-guo; Hu, Long; Wang, Yi-bo; Lei, Bing; Huang, Xiang

    2016-08-01

    Numerical studied on T-joints with three-dimensional four directional (3D4D) braided composite fillers was presented in this article. Compared with conventional unidirectional prepreg fillers, the 3D braided composite fillers have excellent ability to prevent crack from penetrating trigone fillers, which constantly occurred in the conventional fillers. Meanwhile, the 3D braided composite fillers had higher fiber volume fraction and eliminated the fiber folding problem in unidirectional prepreg fillers. The braiding technology and mechanical performance of 3D4D braided fillers were studied. The numerical model of carbon fiber T-joints with 3D4D braided composite fillers was built by finite element analysis software. The damage formation, extension and failing process of T-joints with 3D4D braided fillers under tensile load were investigated. Further investigation was extended to the effect of 3D4D braided fillers with different braiding angles on mechanical behavior of the T-joints. The study results revealed that the filling area was the weakest part of the T-joints where the damage first appeared and the crack then rapidly spread to the glue film around the filling area and the interface between over-laminate and soleplate. The 3D4D braided fillers were undamaged and the braiding angle change induced a little effect on the bearing capacity of T-joints.

  3. Direct Pen Writing of Adhesive Particle-Free Ultrahigh Silver Salt-Loaded Composite Ink for Stretchable Circuits.

    Science.gov (United States)

    Hu, Mingjun; Cai, Xiaobing; Guo, Qiuquan; Bian, Bin; Zhang, Tengyuan; Yang, Jun

    2016-01-26

    In this article, we describe a writable particle-free ink for fast fabrication of highly conductive stretchable circuits. The composite ink mainly consists of soluble silver salt and adhesive rubber. Low toxic ketone was employed as the main solvent. Attributed to ultrahigh solubility of silver salt in short-chain ketone and salt-assisted dissolution of rubber, the ink can be prepared into particle-free transparent solution. As-prepared ink has a good chemical stability and can be directly filled into ballpoint pens and use to write on different substrates to form well adhesive silver salt-based composite written traces as needed. As a result of high silver salt loading, the trace can be converted into highly conductive silver nanoparticle-based composites after in situ reduction. Because of the introduction of adhesive elastomeric rubber, the as-formed conductive composite written trace can not only maintain good adhesion to various substrates but also show good conductivity under various deformations. The conductivity of written traces can be enhanced by repeated writing-reduction cycles. Different patterns can be fabricated by either direct handwriting or hand-copying. As proof-of-concept demonstrations, a typical handwriting heart-like circuit was fabricated to show its capability to work under different deformations, and a pressure-sensitive switch was also manufactured to present pressure-dependent change of resistance.

  4. Study on the laser irradiation effects on carbon fiber reinforced resin composite subjected to tangential gas flow loading

    Science.gov (United States)

    Chen, Minsun; Jiang, Houman; Jiao, Luguang; Li, Junshen; Liu, Zejin

    2013-05-01

    The irradiation effects of 976nm continuous-wave laser on carbon fiber reinforced E-51 resin composite is studied experimentally, with a 0.4Ma tangential airflow or 0.4Ma tangential nitrogen gas flow on the target surface. In order to simulate the thermal response of fiber reinforced resin composite materials subjected to combined laser and tangential gas flow loading, a three-dimensional thermal response model of resin composite materials is developed. In the model, the thermal decomposition of resin is described by a multi-step model. The motion of the decomposition gas is assumed to be one-dimensional, for the case that the laser spot is significantly larger than the thickness of the sample. According the above assumption, the flow of the decomposition gas is considered in the three-dimensional model without introducing any mechanical quantities. The influences of the tangential gas flow, the outflow of the thermal decomposition gas and the ablation-including phase change ablation or oxidative ablation-of the surface material on the laser irradiation effects are included in the surface boundary conditions. The three-dimensional thermal response model is calculated numerically by use of the modified smooth particle hydrodynamics (MSPH) method which is coded with FORTRAN. The model is tested by experimentally measuring the temperature profiles during carbon fiber reinforced E-51 resin composite subjected to combined laser and tangential gas flow. The predicted temperature profiles are in good agreement with experimental temperatures obtained using thermocouples.

  5. Occupational respiratory disease caused by acrylates.

    Science.gov (United States)

    Savonius, B; Keskinen, H; Tuppurainen, M; Kanerva, L

    1993-05-01

    Acrylates are compounds used in a variety of industrial fields and their use is increasing. They have many features which make them superior to formerly used chemicals, regarding both their industrial use and their possible health effects. Contact sensitization is, however, one of their well known adverse health effects but they may also cause respiratory symptoms. We report on 18 cases of respiratory disease, mainly asthma, caused by different acrylates, 10 cases caused by cyanoacrylates, four by methacrylates and two cases by other acrylates. PMID:8334539

  6. Characterization and Analysis of Triaxially Braided Polymer Composites under Static and Impact Loads

    Science.gov (United States)

    Goldberg, Robert K.; Roberts, Gary D.; Blinzler, Brina J.; Kohlman, Lee W.; Binienda, Wieslaw K.

    2012-01-01

    In order to design impact resistant aerospace components made of triaxially-braided polymer matrix composite materials, a need exists to have reliable impact simulation methods and a detailed understanding of the material behavior. Traditional test methods and specimen designs have yielded unrealistic material property data due to material mechanisms such as edge damage. To overcome these deficiencies, various alternative testing geometries such as notched flat coupons have been examined to alleviate difficulties observed with standard test methods. The results from the coupon level tests have been used to characterize and validate a macro level finite element-based model which can be used to simulate the mechanical and impact response of the braided composites. In the analytical model, the triaxial braid unit cell is approximated by using four parallel laminated composites, each with a different fiber layup, which roughly simulates the braid architecture. In the analysis, each of these laminated composites is modeled as a shell element. Currently, each shell element is considered to be a smeared homogeneous material. Simplified micromechanics techniques and lamination theory are used to determine the equivalent stiffness properties of each shell element, and results from the coupon level tests on the braided composite are used to back out the strength properties of each shell element. Recent improvements to the model include the incorporation of strain rate effects into the model. Simulations of ballistic impact tests have been carried out to investigate and verify the analysis approach.

  7. High-Fidelity Nonlinear Analysis of Compression-Loaded Composite Shells

    Science.gov (United States)

    Hilburger, Mark W.; Starnes, James H., Jr.

    2001-01-01

    The results of an experimental and analytical study of the effects of initial imperfections on the buckling and postbuckling response of unstiffened thin-walled compression-loaded graphite-epoxy cylindrical shells are presented. The shells considered in the study have four different shell-wall laminates and two different shell-radius-to-thickness ratios. The shell-wall laminates include two different orthotropic laminates and two different quasi-isotropic laminates. The shell-radius-to-thickness ratios include shell-radius-to-thickness ratios equal to 100 and 200. The results identify the effects of traditional and nontraditional initial imperfections on the nonlinear response characteristics and buckling loads of the shells. The traditional imperfections include the geometric shell-wall mid-surface imperfections that are commonly discussed in the literature on thin shell buckling. The nontraditional imperfections include shell-wall thickness variations, local shell-wall ply-gaps associated with the fabrication process, shell-end geometric imperfections, nonuniform applied end loads, and variations in the boundary conditions including the effects of elastic boundary conditions. A high-fidelity nonlinear shell analysis procedure that accurately accounts for the effects of these traditional and nontraditional imperfections on the nonlinear response characteristics and buckling loads of the shells is described. The analysis procedure includes a nonlinear static analysis that predicts the stable response characteristics of the shells, and a nonlinear transient analysis that predicts the unstable response characteristics. The results of a local shell-wall stress analysis used to estimate failure stresses are also described.

  8. Numerical analysis of singly curved shallow composite panels under three-point bend load

    OpenAIRE

    Guedes, RM; Alcides Sa

    2008-01-01

    The experimental methodology to test curved panels under three-point bend (3PB) load is assessed. The problem arises when mechanical and strength characterization of pipe material systems is required. Test specimens cut out from pipe samples oriented in the tangential direction were used to measure hoop modulus and strength. In this procedure singly curved beams with the same radius as the pipe are obtained. The present assessment was made using three different approaches: Finite Element Meth...

  9. Buckling and failure characteristics of compression-loaded stiffened composite panels with a hole

    Science.gov (United States)

    Nagendra, S.; Gurdal, Z.; Haftka, R. T.; Starnes, J. H.

    An experimental and analytical study was carried out to investigate the buckling and failure characteristics of stiffened compression-loaded panels with holes and to assess the validity of analytical models used for the design of such panels. Graphite-epoxy panels with four equally spaced blade stiffeners were fabricated with a laminate stacking sequence optimally designed for stiffened panels without holes. Panels with different hole sizes and panels without holes were tested.

  10. The influence of framework design on the load-bearing capacity of laboratory-made inlay-retained fibre-reinforced composite fixed dental prostheses

    NARCIS (Netherlands)

    F. Keulemans; L.V.J. Lassilla; S. Garoushi; P.K. Vallittu; C.J. Kleverlaan; A.J. Feilzer

    2009-01-01

    Delamination of the veneering composite is frequently encountered with fibre-reinforced composite (FRC) fixed dental prosthesis (FDPs). The aim of this study is to evaluate the influence of framework design on the load-bearing capacity of laboratory-made three-unit inlay-retained FRC-FDPs. Inlay-ret

  11. Experimental and Numerical Investigations of Textile Hybrid Composites Subjected to Low Velocity Impact Loadings

    Directory of Open Access Journals (Sweden)

    Gautam S. Chandekar

    2014-01-01

    Full Text Available In the present study experimental and numerical investigations were carried out to predict the low velocity impact response of four symmetric configurations: 10 ply E Glass, 10 ply AS4 Carbon, and two Hybrid combinations with 1 and 2 outer plies of E Glass and 8 and 6 inner plies of Carbon. All numerical investigations were performed using commercial finite element software, LS-DYNA. The test coupons were manufactured using the low cost Heated Vacuum Assisted Resin Transfer Molding (H-VARTM© technique. Low velocity impact testing was carried out using an Instron Dynatup 8250 impact testing machine. Standard 6 × 6 Boeing fixture was used for all impact experiments. Impact experiments were performed over progressive damage, that is, from incipient damage till complete failure of the laminate in six successive impact energy levels for each configuration. The simulation results for the impact loading were compared with the experimental results. For both nonhybrid configurations, it was observed that the simulated results were in good agreement with the experimental results, whereas, for hybrid configurations, the simulated impact response was softer than the experimental response. Maximum impact load carrying capacity was also compared for all four configurations based on their areal density. It was observed that Hybrid262 configuration has superior impact load to areal density ratio.

  12. Effects of repeated bending load at room temperature for composite Nb{sub 3}Sn wires

    Energy Technology Data Exchange (ETDEWEB)

    Awaji, Satoshi [High Field Laboratory for Superconducting Materials, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577 (Japan); Watanabe, Kazuo [High Field Laboratory for Superconducting Materials, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577 (Japan); Katagiri, Kazumune [Faculty of Engineering, Iwate University, Ueda 4-3-5, Morioka 020-8511 (Japan)

    2003-09-01

    In order to realize a react and wind (R and W) method for Nb{sub 3}Sn wires, the influences of a bending load at room temperature are investigated. Usually, the superconducting wires undergo bending loads at room temperature repeatedly during winding and insulation processes. We define these bending loads as 'pre-bending' treatments. We applied the pre-bending strain of 0 and 0.5% to the highly strengthened CuNb/(Nb, Ti){sub 3}Sn wires, and measured the stress/strain properties and critical currents. The improvements of stress dependence of normalized critical current and the increase of the maximum critical current by the pre-bending treatments were found. The model based on the distribution of the local tensile strain as a bending strain describes the experimental results well without the increase of the maximum critical current. When the pre-bending strain was applied, the calculated results indicate that the mechanical properties are improved due to the local work hardening, and hence the stress dependence of I{sub c} increases.

  13. Graphite/Polyimide Composites Subjected to Biaxial Loads at Elevated Temperatures

    Science.gov (United States)

    Kumosa, Maciej S.; Sutter, J. K.

    2007-01-01

    First, we will review our most important research accomplishments from a five year study concerned with the prediction of mechanical properties of unidirectional and woven graphite/polyimide composites based on T650-35, M40J and M60J fibers embedded in either PMR-15 or PMR-II-50 polyimide resins. Then, an aging model recently developed for the composites aged in nitrogen will be proposed and experimentally verified on an eight harness satin (8HS) woven T650-35/PMR-15 composite aged in nitrogen at 315 C for up to 1500 hours. The study was supported jointly between 1999 and 2005 by the AFOSR, the NASA Glenn Research Center, and the National Science Foundation.

  14. Statistical Analysis of the Progressive Failure Behavior for Fiber-Reinforced Polymer Composites under Tensile Loading

    Directory of Open Access Journals (Sweden)

    Fang Wang

    2014-01-01

    Full Text Available An analytical approach with the help of numerical simulations based on the equivalent constraint model (ECM was proposed to investigate the progressive failure behavior of symmetric fiber-reinforced composite laminates damaged by transverse ply cracking. A fracture criterion was developed to describe the initiation and propagation of the transverse ply cracking. This work was also concerned with a statistical distributions of the critical fracture toughness values with due consideration given to the scale size effect. The Monte Carlo simulation technique coupled with statistical analysis was applied to study the progressive cracking behaviors of composite structures, by considering the effects of lamina properties and lay-up configurations. The results deduced from the numerical procedure were in good agreement with the experimental results obtained for laminated composites formed by unidirectional fiber reinforced laminae with different orientations.

  15. Modeling of Nonlinear Mechanical Behavior for 3D Needled C/C-SiC Composites Under Tensile Load

    Science.gov (United States)

    Xie, Junbo; Fang, Guodong; Chen, Zhen; Liang, Jun

    2016-08-01

    This paper established a macroscopic constitutive model to describe the nonlinear stress-strain behavior of 3D needled C/C-SiC composites under tensile load. Extensive on- and off-axis tensile tests were performed to investigate the macroscopic mechanical behavior and damage characteristics of the composites. The nonlinear mechanical behavior of the material was mainly induced by matrix tensile cracking and fiber/matrix debonding. Permanent deformations and secant modulus degradation were observed in cyclic loading-unloading tests. The nonlinear stress-strain relationship of the material could be described macroscopically by plasticity deformation and stiffness degradation. In the proposed model, we employed a plasticity theory with associated plastic flow rule to describe the evolution of plastic strains. A novel damage variable was also introduced to characterize the stiffness degradation of the material. The damage evolution law was derived from the statistical distribution of material strength. Parameters of the proposed model can be determined from off-axis tensile tests. Stress-strain curves predicted by this model showed reasonable agreement with experimental results.

  16. Effect of Shear Resistance on Flexural Debonding Load-Carrying Capacity of RC Beams Strengthened with Externally Bonded FRP Composites

    Directory of Open Access Journals (Sweden)

    Guibing Li

    2014-05-01

    Full Text Available Debonding failure is the main failure mode in flexurally strengthened reinforced concrete beams by externally bonded or near surface mounted fibre reinforced polymer (FRP composites. It is believed that FRP debonding will be initiated if the shear stress on the concrete-FRP interface reaches the tensile strength of concrete. However, it was found through experimental and analytical studies that the debonding mechanism of FRP composites has the potential of shear failure in combination with debonding failure. Moreover, the shear failure probably influences the debonding failure. Presently, there are very little experimental and analytical studies to investigate the influence of shear resistance of reinforced concrete (RC beam on FRP debonding failure. The current study investigates and analyzes the effect of shear resistance on FRP debonding failure based on test results. The analytical results show that the shear resistance of RC beam has a great effect on flexural debonding load-carrying capacity of FRP-strengthened RC beam. The influence of shear resistance on flexural debonding load-carrying capacity must be fully considered in flexural strengthening design of RC beams.

  17. A Numerical Simulation of Time-Dependent Interface Failure Under Shear and Compressive Loads in Single-Fiber Composites

    Science.gov (United States)

    Koyanagi, Jun; Yoshimura, Akinori; Kawada, Hiroyuki; Aoki, Yuichiro

    2010-02-01

    We performed a numerical simulation of a time-dependent interfacial failure accompanied by a fiber failure, and examined their evolution under shear and compressive loads in single-fiber composites. The compressive load on the interface consists of Poisson’s contraction for matrix resin subjected to longitudinal tensile load. As time progresses, compressive stress at the interface in the fiber radial direction relaxes under the constant longitudinal tensile strain condition for the specimen, directly causing the relaxation of the interface frictional stress. This relaxation facilitates the failure of the interface. In this analysis, a specific criterion for interface failure is applied; apparent interfacial shear strength is enhanced by compressive stress, which is referred as quasi-parabolic criterion in the present study. The results of the stress recovery profile around the fiber failure and the interfacial debonding length as a function of time simulated by the finite element analysis employing the criterion are very similar to experimental results obtained using micro-Raman spectroscopy.

  18. Repair of radius defect with bone-morphogenetic-protein loaded hydroxyapatite/collagen-poly(L-lactic acid) composite

    Institute of Scientific and Technical Information of China (English)

    胡蕴玉; 张超; 吕荣; 徐建强; 李丹

    2003-01-01

    Objective: To explore the method to repair bone defect with bone-morphogenetic-protein loaded hydroxyapatite/collagen-poly(L-lactic acid) composite. Methods: 18 adult beagle dogs were randomly divided into 3 groups. In Group A, bone-morphogenetic-protein (BMP) loaded hydroxyapatite/collagen-poly(L-lactic acid) (HAC-PLA) scaffold was implanted in a 2 cm diaphyseal defect in the radius. In Group B, unloaded pure HAC-PLA scaffold was implanted in the defects. No material was implanted in Group C (control group). The dogs were sacrificed 6 months postoperatively. Features of biocompatibility, biodegradability and osteoinduction were evaluated with histological, radiological examinations and bone mineral density (BMD) measurements.Results: In Group A, the radius defect healed after the treatment with BMP loaded HAC-PLA. BMD at the site of the defect was higher than that of the contralateral radius. Fibrous union developed in the animals of the control group. Conclusions: BMP not only promotes osteogenesis but also accelerates degradation of the biomaterials. Optimized design parameters of a three-dimensional porous biomaterial would give full scope to the role of BMP as an osteoinductive growth factor.

  19. DETERMINATION OF COMPOSITE LAYERS HARDNESS DEPENDING ON THEIR DEPTH AND APPLIED LOAD

    Directory of Open Access Journals (Sweden)

    Minodora-Maria PASĂRE

    2015-05-01

    Full Text Available Composite materials enjoy superior properties of traditional materials at high temperature and ambient temperature. The performance that touch these materials are mainly influenced by the type of materials used and the manufacturing process, the latter having a decisive role in relation to the starting composition similar, so that at the same materials used can be obtained qualities much higher depending on the process used. The diversity of the possible combinations of components to obtain advanced materials is high. A particular interest is shown by those systems that form solid solutions continuous or interrupted, and those that form new combinations with any special properties.

  20. Study of Dynamic Behavior of Multilayered Clamped Composite Skewed Hypar Shell Roofs under Impact Load

    Directory of Open Access Journals (Sweden)

    Sanjoy Das Neogi

    2013-01-01

    Full Text Available With advancement in the field of structural engineering, hunt for smarter materials has channelised the research towards the application of composite material. It is the high specific weight and specific stiffness of this material that have drawn the interest of different industrial sectors. Civil engineers also picked up composites to use it as a roofing material. Laminated composite shells, which can cover large column-free area and reduces dead weight of structure, show vulnerability under sudden impact due to their low transverse shear resistances. This study utilises finite element tool to investigate the dynamic response of a multilayered laminated composite hypar shells for fully clamped boundary condition. This class of shells is unique in a sense that the curvature has only the radius of cross curvature and these shells do not admit easy closed form solution particularly when the boundary conditions are complicated. Contact behavior of impactor and impacted mass has been modeled by modified Hertzian contact law and time-dependent equations are solved using Newmark’s time integration technique. Basic aim is to analyse the shell for symmetrically placed multilayered angle and cross ply lamination under different impact velocities.

  1. Crystal structure transformation in potassium acrylate

    Science.gov (United States)

    Pai Verneker, V. R.; Vasanthakumari, R.

    1983-10-01

    Potassium acrylate undergoes a reversible phase transformation around 335°K with an activation energy of 133 kcal/mole. Differential scanning calorimetry and high temperature X-ray powder diffraction techniques have been used to probe this phenomenon.

  2. Characterization of electron beam cured epoxy acrylate

    International Nuclear Information System (INIS)

    Epoxy resin has wide application in various industrial fields because of their good mechanical strength, superiority adhesion and low shrinkage etc. And the typical curing method for epoxy resins is thermal and press compaction. However, a curing method was used electron beam process in this study. Epoxy acrylate was fabricated from mixture of epoxy, acrylic acid, tetraphenylporphyrin (TPP) and hydroquinone monomethyl ether (MEHQ) with mole ratios. Then electron beam irradiation effect on the curing of the epoxy acrylate resin was investigated various absorption dose in nitrogen atmospheres at room temperature. The dynamic mechanical and thermal properties of the irradiated epoxy acrylate resins were characterized using dynamic mechanical analysis (DMA) and thermogravimetric analyzer (TGA). And the tensile and flexural strength were measured by an universal tensile machine (UTM)

  3. The mechanisms of plastic strain accommodation and post critical behavior of heterogeneous reactive composites subject to dynamic loading

    Science.gov (United States)

    Olney, Karl L.

    The dynamic behavior of granular/porous and laminate reactive materials is of interest due to their practical applications; reactive structural components, reactive fragments, etc. The mesostructural properties control meso- and macro-scale dynamic behavior of these heterogeneous composites including the behavior during the post-critical stage of deformation. They heavily influence mechanisms of fragment generation and the in situ development of local hot spots, which act as sites of ignition in these materials. This dissertation concentrates on understanding the mechanisms of plastic strain accommodation in two representative reactive material systems with different heterogeneous mesostructrues: Aluminum-Tungsten granular/porous and Nickel-Aluminum laminate composites. The main focus is on the interpretation of results of the following dynamic experiments conducted at different strain and strain rates: drop weight tests, explosively expanded ring experiments, and explosively collapsed thick walled cylinder experiments. Due to the natural limitations in the evaluation of the mesoscale behavior of these materials experimentally and the large variation in the size scales between the mesostructural level and the sample, it is extremely difficult, if not impossible, to examine the mesoscale behavior in situ. Therefore, numerical simulations of the corresponding experiments are used as the main tool to explore material behavior at the mesoscale. Numerical models were developed to elucidate the mechanisms of plastic strain accommodation and post critical behavior in these heterogeneous composites subjected to dynamic loading. These simulations were able to reproduce the qualitative and quantitative features that were observable in the experiments and provided insight into the evolution of the mechanisms of plastic strain accommodation and post critical behavior in these materials with complex mesotructure. Additionally, these simulations provided a framework to examine

  4. Interaction between Interfacial Collinear Griffith Cracks in Composite Media under Thermal Loading

    Science.gov (United States)

    Mishra, P. K.; Das, S.

    2016-05-01

    This article deals with the interactions between a central crack and a pair of outer cracks situated at the interface of orthotropic elastic half planes under thermo-mechanical loading. The mixed boundary value problem has been reduced to a pair of singular integral equations which has been solved numerically using Jacobi polynomial method. The interaction effects have been obtained in terms of stress magnification factors depending on the crack spacing and crack length. The phenomena of crack shielding and crack amplification have been depicted through graphs for different particular cases.

  5. Modelling and simulation of randomly oriented carbon fibre-reinforced composites under thermal load

    Science.gov (United States)

    Treffler, R.; Fröschl, J.; Drechsler, K.; Ladstätter, E.

    2016-03-01

    Carbon fibre-reinforced sheet moulding compounds (CF-SMC) already exhibit a complex material behaviour under uniaxial loads due to the random orientation of the fibres in the matrix resin. Mature material models for metallic materials are generally not transferable. This paper proposes an approach for modelling the fatigue behaviour of CF-SMC based on extensive static and cyclic tests using low cost secondary carbon fibres (SCF). The main focus is on describing the stiffness degradation considering the dynamic modulus of the material. Influence factors such as temperature, orientation, rate dependence and specimen thickness were additionally considered.

  6. Resistance of acrylic vessel to gamma irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Carneiro, Andre Cavalcanti; Menezes, Maria Angela de B.C.; Pereira, Marcio Tadeu; Rocha, Nirlando Antonio; Vilela, Jefferson Jose, E-mail: andreccarneiro@gmail.com, E-mail: menezes@cdtn.br, E-mail: mtp@cdtn.br, E-mail: nar@cdtn.br, E-mail: jjv@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil); Braga, Mario Roberto Martins S.S., E-mail: mariomartins@gmail.com [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Programa de Pos-Graduacao em Ciencias e Tecnicas Nucleares

    2013-07-01

    This paper describes the preliminary studies made in acrylic material in order to verify the effects of radiolysis in acrylic recipients in which the uranium ore standards are conditioned and check if the material is able to keep the {sup 222}Rn inside the vessel. The preliminary results after gamma irradiation of two kinds of recipients indicate no differences between the vessels irradiated and the ones no irradiated, related to color changes and tension resistance. (author)

  7. Rapid Output Growth of Special Acrylic Esters

    Institute of Scientific and Technical Information of China (English)

    Wang Lianzhi

    2007-01-01

    @@ Acrylic esters are usually classified into general-purpose varieties and special varieties. The production and application of general-purpose varieties is already quite matured in the world and their output growth tends to be flat. Owing to the development of coatings, electronics, automobiles,textiles, printing and construction sectors, especially the application of radiation curing technology in various sectors, special acrylic esters have developed rapidly.

  8. Gel time of calcium acrylate grouting material.

    Science.gov (United States)

    Han, Tong-Chun

    2004-08-01

    Calcium acrylate is a polymerized grout, and can polymerize in an aqueous solution. The polymerization reaction utilizes ammonium persulfate as a catalyst and sodium thiosulfate as the activator. Based on the theory of reaction kinetics, this study on the relation between gel time and concentration of activator and catalyst showed that gel time of calcium acrylate is inversely proportional to activator and catalyst concentration. A formula of gel time is proposed, and an example is provided to verify the proposed formula. PMID:15236477

  9. Gel time of calcium acrylate grouting material

    Institute of Scientific and Technical Information of China (English)

    韩同春

    2004-01-01

    Calcium acrylate is a polymerized grout, and can polymerize in an aqueous solution. The polymerization reaction utilizes ammonium persulfate as a catalyst and sodium thiosulfate as the activator. Based on the theory of reaction kinetics, this study on the relation between gel time and concentration of activator and catalyst showed that gel time of calcium acrylate is inversely proportional to activator and catalyst concentration. A formula of gel time is proposed, and an example is provided to verify the proposed formula.

  10. Gel time of calcium acrylate grouting material

    Institute of Scientific and Technical Information of China (English)

    韩同春

    2004-01-01

    Calcium acrylate is a polymerized grout, and can polymerize in an aqueous solution. The polymerizationreaction utilizes ammonium persulfate as a catalyst and sodium thiosulfate as the activator. Based on the theory of reactionkinetics, this study on the relation between gel time and concentration of activator and catalyst showed that gel time ofcalcium acrylate is inversely proportional to activator and catalyst concentration. A formula of gel time is proposed, and anexample is provided to verify the proposed formula.

  11. Host–guest composite materials of dyes loaded zeolite LTL for antenna applications

    Energy Technology Data Exchange (ETDEWEB)

    Insuwan, W. [Rajamangala University of Technology Isan Surin Campus, Facculty of Agriculture and Technology, Surin 32000 (Thailand); Jungsuttiwong, S. [Center for Organic Electronic and Alternative Energy, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Ubon Ratchathani University, Ubon Ratchathani 34190 (Thailand); Rangsriwatananon, K., E-mail: kunwadee@sut.ac.th [School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000 (Thailand)

    2015-05-15

    This research work directly focuses on a new feasible light harvesting antenna material constructed with Acridine hydrochloride (Ac)/Acriflavine hydrochloride (AF), as donor/acceptor for energy transfer, loaded on a round shape zeolite LTL (K-LTL and H-LTL). The energy transfer was monitored by absorption and fluorescence spectra while the calculated Förster distance (R{sub DA}) and Quenching efficiency (%Q) of Ac/AF on K-LTL and H-LTL varied between 22.0 Å to 19.6 Å and 71.4% to 65.5%, respectively. Also, it was found that the microenvironment of a solid host such as K-LTL and H-LTL has significantly influenced the fluorescence spectra of Ac/AF on H-LTL approximately 50 nm longer than that on K-LTL. - Highlights: • New antenna materials have been performed using dyes loaded on zeolite LTL. • Light emission takes place from acriflavine hydrochloride (AF) due to fluorescence resonance energy transfer (FRET). • The microenvironment of zeolite LTL has significantly influenced the fluorescence spectra.

  12. Host–guest composite materials of dyes loaded zeolite LTL for antenna applications

    International Nuclear Information System (INIS)

    This research work directly focuses on a new feasible light harvesting antenna material constructed with Acridine hydrochloride (Ac)/Acriflavine hydrochloride (AF), as donor/acceptor for energy transfer, loaded on a round shape zeolite LTL (K-LTL and H-LTL). The energy transfer was monitored by absorption and fluorescence spectra while the calculated Förster distance (RDA) and Quenching efficiency (%Q) of Ac/AF on K-LTL and H-LTL varied between 22.0 Å to 19.6 Å and 71.4% to 65.5%, respectively. Also, it was found that the microenvironment of a solid host such as K-LTL and H-LTL has significantly influenced the fluorescence spectra of Ac/AF on H-LTL approximately 50 nm longer than that on K-LTL. - Highlights: • New antenna materials have been performed using dyes loaded on zeolite LTL. • Light emission takes place from acriflavine hydrochloride (AF) due to fluorescence resonance energy transfer (FRET). • The microenvironment of zeolite LTL has significantly influenced the fluorescence spectra

  13. Prediction and measurement of composite tube twist and bending due to thermal loading

    Science.gov (United States)

    Bluth, A. Marcel; Tucker, James R.; Thompson, Troy

    2013-09-01

    Composite materials are applied in precision optical metering structures because of their low thermal expansion properties in concert with high specific stiffness. Twisting and bending of long composite tubes, such as the secondary mirror support structure for the JWST telescope, requires control and verification. A stochastic modeling method was applied that simulates the manufacturing process variability and estimates ranges for expected twist and bend over the tube length from ambient to cryogenic temperatures. A development strut for the JWST secondary mirror support structure was fabricated and a metrology system was designed and implemented that measured the bend and twist response from ambient to 30 K. Modeling methods and predictions are outlined. The test metrology and results are summarized, along with a comparison between test and prediction.

  14. Modelling of damage initiation mechanism in rubber sheet composites under the static loading

    OpenAIRE

    Da Silva Botelho, T; N. Isac; E. Bayraktar

    2007-01-01

    Purpose: Modelling – Finite Element Analysis (FEA) of the damage initiation mechanisms in thin rubber sheet composites were carried out under static solicitation at room temperature. Natural rubber vulcanised and reinforced by carbon, NR is used in this study.Design/methodology/approach: Experimental results were compared with that of the Finite Element Analysis (FEA). Damage mechanism has been described with a threshold criterion to identify the tearing resistance, characteristic energy for ...

  15. Postbuckling Behaviour of Anisotropic Laminated Composite Plates due to Shear Loading

    OpenAIRE

    V. Balamurugan; Ganapathi, M; Patel, B.P.

    1998-01-01

    This study investigates postbuckling behaviour of laminated composite plates using a nine-noded shear flexible quadrilateral plate element. The formulation includes nonlinear strain-displacement relation based on von Karman's assumption. The nonlinear governing equations are solved through iteration. A detailed parametric study is carried out to bring out the influence of ply-angle, aspect ratio and material properties on the postbuckling strength of laminates due to in-plane shear loa...

  16. 纳米TiO2/有机-无机杂化丙烯酸复合涂层机械及耐腐蚀性能的研究%Study on the mechanical properties and corrosion resistance properties of nano-TiO2/organic-inorganic hybrid acrylic composite coating

    Institute of Scientific and Technical Information of China (English)

    李婕; 孙小英; 杭建忠; 施利毅; 程银银

    2012-01-01

    The organic-inorganic hybridization acrylic resin was synthesized with sol-gel method,and the effects of the addition of nano-TiO2 on mechanical properties and corrosion resistance properties of organic-inorganic hybridization acrylic composite coatings have been investigated in detail.The result showed that,when adding 15wt% nano-TiO2,the hardness of coating was improved from 3 to 6H,the salt spray resistance time increased from 100 to 500h,and the resistance got to 106Ω·cm2.Moreover,it can be observed clearly that nano particles dispersed uniformly and densely in the coatings by SEM.The coordination of organic-inorganic hybridization acrylic resin and nano-TiO2 was a good potential method for improving the mechanical properties and corrosion resistance properties of coatings.%在采用溶胶-凝胶法合成有机-无机杂化丙烯酸树脂的基础上,研究了纳米TiO2添加量对有机-无机杂化丙烯酸复合涂层机械和耐腐蚀等性能的影响。研究表明,当纳米TiO2添加量为15%时,涂层的性能有了较大的提高,其硬度由3H提高至6H,涂层的耐盐雾时间由100h提高到500h,涂层的阻抗值也由104Ω.cm2提高至106Ω.cm2。另外,通过扫描电镜观察了复合涂层的断面,发现涂层中纳米粒子分散均匀,并且粘接紧密,形成了较为致密的复合涂层。

  17. Displacements and stresses in composite multi-layered media due to varying temperature and concentrated load

    Institute of Scientific and Technical Information of China (English)

    M. K. Ghosh; M. Kanoria

    2007-01-01

    This paper deals with the determination of the thermo-elastic displacements and stresses in a multi-layered body set up in different layers of different thickness having different elastic properties due to the application of heat and a concentrated load in the uppermost surface of the medium. Each layer is assumed to be made of homogeneous and isotropic elastic material. The relevant displacement components for each layer are taken to be axisymmetric about a line, which is perpendicular to the plane surfaces of all layers. The stress function for each layer, therefore, satisfies a single equation in absence of any body forces. The equation is then solved by integral transform technique. Analytical expressions for thermo-elastic displacements and stresses in the underlying mass and the corresponding numerical codes are constructed for any number of layers. However, the numerical comparison is made for three and four layers.

  18. In vitro haematic proteins adsorption and cytocompatibility study on acrylic copolymer to realise coatings for drug-eluting stents

    International Nuclear Information System (INIS)

    In the present paper, a preliminary in vitro analysis of biocompatibility of newly-synthesised acrylic copolymers is reported. In particular, with the aim to obtain coatings for drug-eluting stents, blood protein absorption and cytocompatibility were studied. For protein absorption tests, bovine serum albumin and bovine plasma fibrinogen were considered. Cytocompatibility was tested using C2C12 cell line as model, analysing the behaviour of polymeric matrices and of drug-eluting systems, obtained loading polymeric matrices with paclitaxel, an anti-mitotic drug, in order to evaluate the efficacy of a pharmacological treatment locally administered from these materials. Results showed that the amount of albumin absorbed was greater than the amount of fibrinogen (comprised in the range of 70%–85% and 10%–22% respectively) and it is a good behaviour in terms of haemocompatibility. Cell culture tests showed good adhesion properties and a relative poor proliferation. In addition, a strong effect related to drug elution and a correlation with the macromolecular composition were detected. In this preliminary analysis, tested materials showed good characteristics and can be considered possible candidates to obtain coatings for drug-eluting stents. Highlights: ► Preliminary evaluation of haemo- and cytocompatibility of newly-synthesised acrylic copolymers ► Materials adsorb higher amounts of albumin and with a faster rate than fibrinogen. ► Protein adsorption depended on the macromolecular composition and surface properties. ► Cell viability on pure samples and efficacy of paclitaxel release were verified in C2C12 cultures.

  19. In vitro haematic proteins adsorption and cytocompatibility study on acrylic copolymer to realise coatings for drug-eluting stents

    Energy Technology Data Exchange (ETDEWEB)

    Gagliardi, Mariacristina, E-mail: mariacristina.gagliardi@iit.it

    2012-12-01

    In the present paper, a preliminary in vitro analysis of biocompatibility of newly-synthesised acrylic copolymers is reported. In particular, with the aim to obtain coatings for drug-eluting stents, blood protein absorption and cytocompatibility were studied. For protein absorption tests, bovine serum albumin and bovine plasma fibrinogen were considered. Cytocompatibility was tested using C2C12 cell line as model, analysing the behaviour of polymeric matrices and of drug-eluting systems, obtained loading polymeric matrices with paclitaxel, an anti-mitotic drug, in order to evaluate the efficacy of a pharmacological treatment locally administered from these materials. Results showed that the amount of albumin absorbed was greater than the amount of fibrinogen (comprised in the range of 70%-85% and 10%-22% respectively) and it is a good behaviour in terms of haemocompatibility. Cell culture tests showed good adhesion properties and a relative poor proliferation. In addition, a strong effect related to drug elution and a correlation with the macromolecular composition were detected. In this preliminary analysis, tested materials showed good characteristics and can be considered possible candidates to obtain coatings for drug-eluting stents. Highlights: Black-Right-Pointing-Pointer Preliminary evaluation of haemo- and cytocompatibility of newly-synthesised acrylic copolymers Black-Right-Pointing-Pointer Materials adsorb higher amounts of albumin and with a faster rate than fibrinogen. Black-Right-Pointing-Pointer Protein adsorption depended on the macromolecular composition and surface properties. Black-Right-Pointing-Pointer Cell viability on pure samples and efficacy of paclitaxel release were verified in C2C12 cultures.

  20. Effect of ceramic preform geometry on load partitioning in Al2O3-Al composites with three-dimensional periodic architecture

    International Nuclear Information System (INIS)

    Interpenetrating Al2O3/Al composites were created by liquid-metal infiltration of 3D periodic ceramic preforms with face-centered-tetragonal symmetry produced by direct-write assembly. Volume-averaged lattice strains in the ceramic phase of the composite were measured by synchrotron X-ray diffraction for various levels of uniaxial compression stresses. Load transfer is found to occur from the metal phase to the ceramic phase, and the magnitude of the effect is in general agreement with simple rule-of-mixtures models. Spatially resolved diffraction measurements show variations in load transfer at two different positions within the composite for the elastic- and damage-deformation regimes, the latter being observed using phase-enhanced synchrotron imaging. The mechanical behavior of these interpenetrating Al2O3/Al composites with face-centered-tetragonal symmetry are compared with previous interpenetrating Al2O3/Al composites with simple-tetragonal symmetry.

  1. CHEMICAL COMPOSITION AND PCT DATA FOR THE INITIAL SET OF HANFORD ENHANCED WASTE LOADING GLASSES

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K.; Edwards, T.

    2014-06-02

    In this report, the Savannah River National Laboratory provides chemical analyses and Product Consistency Test results for 20 simulated high level waste glasses fabricated by the Pacific Northwest National Laboratory. The results of these analyses will be used as part of efforts to revise or extend the validation ranges of the current Hanford Waste Treatment and Immobilization Plant glass property models to cover a broader span of waste compositions. The measured chemical composition data are reported and compared with the targeted values for each component for each glass. Two components of the study glasses, fluorine and silver, were not measured since each of these species would have required the use of an additional preparation method and their measured values were likely to be near or below analytical detection limits. Some of the glasses were difficult to prepare for chemical analysis. A sodium peroxide fusion dissolution method was successful in completely dissolving the glasses. Components present in the glasses in minor concentrations can be difficult to measure using this dissolution method due to dilution requirements. The use of a lithium metaborate preparation method for the minor components (planned for use since it is typically successful in digesting Defense Waste Processing Facility HLW glasses) resulted in an unacceptable amount of undissolved solids remaining in the sample solutions. An acid dissolution method was used instead, which provided more thorough dissolution of the glasses, although a small amount of undissolved material remained for some of the study glasses. The undissolved material was analyzed to determine those components of the glasses that did not fully dissolve. These components (e.g., calcium and chromium) were present in sufficient quantities to be reported from the measurements resulting from the sodium peroxide fusion preparation method, which did not leave undissolved material. Overall, the analyses resulted in sums of

  2. Modelling of damage initiation mechanism in rubber sheet composites under the static loading

    Directory of Open Access Journals (Sweden)

    T. Da Silva Botelho

    2007-06-01

    Full Text Available Purpose: Modelling – Finite Element Analysis (FEA of the damage initiation mechanisms in thin rubber sheet composites were carried out under static solicitation at room temperature. Natural rubber vulcanised and reinforced by carbon, NR is used in this study.Design/methodology/approach: Experimental results were compared with that of the Finite Element Analysis (FEA. Damage mechanism has been described with a threshold criterion to identify the tearing resistance, characteristic energy for tearing (T and damage in the specimens was evaluated just at the beginning of the tearing by assuming large strain. Typical specimen geometry of thin sheet rubber composite materials was considered under static tensile tests conducted on the smooth and notched specimens with variable depths.Findings: This stage of this research, a finite element analysis (FEA has been applied under the same conditions of this part in order to obtain the agreement between experimental and FEA results. The numerical modelling is a representation of a previous experimental study. The specimen is stretched more than once its initial size, so that large strains occur. A hyper elastic Mooney-Rivlin law and a Griffith criterion are chosen.Practical implications: A tearing criterion was suggested in the case of simple tension conditions by assuming large strain. In the next step of this study, a finite element analysis (FEA will be applied under the same conditions of this part in order to obtain the agreement between experimental and FEA results.Originality/value: This study proposes a threshold criterion for the damage just at the beginning of the tearing for thin sheet rubber composites and gives a detail discussion for explaining the damage mechanisms. Comparison of FEA results with those of experimental studies gives many facilities for the sake of simplicity in industrial application.

  3. Behaviour of a Moment Resisting Composite Steel and Concrete Joint Under Alternate Loading

    Institute of Scientific and Technical Information of China (English)

    Alberto Zanchettin; Bruno Briseghella; Tobia Zordan; Junqing Xue

    2011-01-01

    The authors show the results of a study conducted on a joint connecting a concrete column to a composite steel concrete floor, subjected to tension on the beams as a result of the decomposition of sagging bending moment. The beam to column connection is achieved by means of headed studs welded to the beam and embedded in the concrete cast. Five different configurations have been tested at failure and the results are compared to formulae proposed in literature. Different degrees of ductility, reliability and strength have been obtained varying geometry and reinforcement ratio on the joints tested.

  4. Dynamic finite element analysis of the crack-inclusion interaction in aligned CNF composites under impact loading conditions

    Science.gov (United States)

    Ting, Huat Tung

    The interaction between a crack and an inclusion of microfiber in an aligned carbon nanofiber (CNF) toughened composite under impact loading conditions was studied by using dynamic finite element analysis (FEA). The nanocomposite material used in this study was T300/Epon 862 enhanced with aligned carbon nanofibers (CNFs). The dynamic stress intensity factors (DSIFs) were evaluated to describe the dynamic fracture behavior of the fracture model. In this study, a numerical homogenization model using FEA was first employed to determine the effective material properties of the equivalent matrix material of Epon 862 and aligned CNFs. The effects of T300 microfiber inclusion eccentricity and CNF alignment angle on the DSIFs were examined in this study. The displacement extrapolation method for monoclinic materials was utilized to calculate the DSIFs. The numerical results demonstrated a mechanism known as "crack-tip shielding" and demonstrated that the CNF alignment angle has an impact on the DSIFs.

  5. Direct Synthesis of Hyperbranched Poly(acrylic acid-co-3-hydroxypropionate

    Directory of Open Access Journals (Sweden)

    Efkan Çatıker

    2015-01-01

    Full Text Available Hyperbranched poly(acrylic acid-co-3-hydroxypropionate (PAcHP was synthesized by base-catalyzed hydrogen transfer polymerization of acrylic acid through one step. The copolymers obtained through solution and bulk polymerization were insoluble in water and all organic solvents tried. Structural and compositional characterizations of hyperbranched PAcHP were performed by using FTIR, solid 13C-NMR, TGA, and titrimetric analysis. Acrylate fraction of the hyperbranched PAcHP obtained via bulk polymerization was determined as 60–65% by comparing TGA curves of hyperbranched PAcHP and pure poly(3-hydroxy propionate (PHP. However, analytical titration of the same sample revealed that acrylic acid units were about 47.3%. The results obtained from TGA and analytical titration were used to evaluate the chemical structure of the copolymer. Hyperbranched PAcHP exhibited hydrogel properties. Swelling behavior of the copolymer was investigated at a wide pH range and ionic strength. The dynamic swelling profiles of hyperbranched PAcHP exhibited a fast swelling behavior in the first hour and achieved the equilibrium state within 12 h in PBS. Depending on the conditions, the copolymers exhibited swelling ratios up to 2100%. As the copolymer has easily biodegradable propionate and versatile functional acrylic acid units, it can be used as not only biodegradable material in medical applications but also raw material in personal care commodities.

  6. Transparent bulk-size nanocomposites with high inorganic loading

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Shi [CREOL, College of Optics and Photonics, University of Central Florida, Orlando, Florida 32816 (United States); Gaume, Romain, E-mail: gaume@ucf.edu [CREOL, College of Optics and Photonics, University of Central Florida, Orlando, Florida 32816 (United States); Department of Materials Science and Engineering, University of Central Florida, Orlando, Florida 32816 (United States); NanoScience Technology Center, University of Central Florida, Orlando, Florida 32816 (United States)

    2015-12-14

    With relatively high nanoparticle loading in polymer matrices, hybrid nanocomposites made by colloidal dispersion routes suffer from severe inhomogeneous agglomeration, a phenomenon that deteriorates light transmission even when the refractive indices of the inorganic and organic phases are closely matched. The dispersion of particles in a matrix is of paramount importance to obtain composites of high optical quality. Here, we describe an innovative, yet straightforward method to fabricate monolithic transparent hybrid nanocomposites with very high particle loading and high refractive index mismatch tolerance between the inorganic and organic constituents. We demonstrate 77% transmission at 800 nm in a 2 mm-thick acrylate polymer nanocomposite containing 61 vol. % CaF{sub 2} nanoparticles. Modeling shows that similar performance could easily be obtained with various inorganic phases relevant to a number of photonic applications.

  7. Pattern of aerosol mass loading and chemical composition over the atmospheric environment of an urban coastal station

    Science.gov (United States)

    Bindu, G.; Nair, Prabha R.; Aryasree, S.; Hegde, Prashant; Jacob, Salu

    2016-02-01

    Aerosol sampling was carried out at four locations in and around Cochin (9°58‧ N, 76°17‧ E), an urban area, located on the southwest coast of India. The gravimetric estimates of aerosol mass loading showed wide range from 78 μg m-3 to >450 μg m-3, occasionally reaching values >500 μg m-3, associated with regional source characteristics. Most of the values were above the air quality standard. Both boundary layer and synoptic scale airflow pattern play role in the temporal features in aerosol mass loading and chemical composition. Chemical analysis of the aerosol samples were done for anionic species viz; F-, Cl-, Br-, NO2-,   NO3-,   PO43-,   SO42- and metallic/cationic species viz; Na, Ca, K, Mg, NH4+, Fe, Al, Cu, Mg, Pb, etc using Ion Chromatography, Atomic Absorption Spectroscopy (AAS) and Inductively Coupled Plasma- Atomic Emission Spectroscopy (ICP-AES). At all the locations, extremely high mass concentration of SO42- was observed with the mean value of 13±6.4 μg m-3 indicating the strong anthropogenic influence. Statistical analysis of the chemical composition data was carried out and the principal factors presented. Seasonal variation of these chemical species along with their percentage contributions and regional variations were also examined. Increase in level of Na in aerosol samples indicated the influence of monsoonal activity. Most of the species showed mass concentrations well above those measured over another coastal site Thiruvananthapuram (8°29‧ N, 76°57‧ E) situated ~220 km south of Cochin revealing the highly localized aerosol features.

  8. Demonstrate Scale-up Procedure for Glass Composite Material (GCM) for Incorporation of Iodine Loaded AgZ.

    Energy Technology Data Exchange (ETDEWEB)

    Nenoff, Tina M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Garino, Terry J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Croes, Kenneth James [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rodriguez, Mark A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-07-01

    Two large size Glass Composite Material (GCM) waste forms containing AgI-MOR were fabricated. One contained methyl iodide-loaded AgI-MOR that was received from Idaho National Laboratory (INL, Test 5, Beds 1 – 3) and the other contained iodine vapor loaded AgIMOR that was received from Oak Ridge National Laboratory (ORNL, SHB 2/9/15 ). The composition for each GCM was 20 wt% AgI-MOR and 80 wt% Ferro EG2922 low sintering temperature glass along with enough added silver flake to prevent any I2 loss during the firing process. The silver flake amounts were 1.2 wt% for the GCM with the INL AgI-MOR and 3 wt% for the GCM contained the ORNL AgI-MOR. The GCMs, nominally 100 g, were first uniaxially pressed to 6.35 cm (2.5 inch) diameter disks then cold isostatically pressed, before firing in air to 550°C for 1hr. They were cooled slowly (1°C/min) from the firing temperature to avoid any cracking due to temperature gradients. The final GCMs were ~5 cm in diameter (~2 inches) and non-porous with densities of ~4.2 g/cm³. X-ray diffraction indicated that they consisted of the amorphous glass phase with small amounts of mordenite and AgI. Furthermore, the presence of the AgI was confirmed by X-ray fluorescence. Methodology for the scaled up production of GCMs to 6 inch diameter or larger is also presented.

  9. Preparation and evaluation of chitosan-poly (acrylic acid hydrogels as stomach specific delivery for amoxicillin and metronidazole

    Directory of Open Access Journals (Sweden)

    Hemant Yadav K

    2007-01-01

    Full Text Available The objective of the present work was to develop stomach specific delivery systems for amoxicillin and metronidazole using chitosan and poly(acrylic acid hydrogels. Chitosan and poly(acrylic acid hydrogels were prepared with different composition of copolymers. The hydrogels were evaluated for swelling studies, mucoadhesive studies, in vitro drug release, scanning electron microscopic and FTIR analysis. The effect of chitosan and poly (acrylic acid on swelling and in vitro drug release was carried out. The n value calculated was < 0.5 for all the formulations containing amoxicillin and metronidazole indicating Fickian diffusion mechanism. The hydrogels with chitosan and poly (acrylic acid ratio of 0.25:1 showed greater mucoadhesive property, maximum swelling and complete release of drugs, hence can be used for stomach specific delivery of drugs.

  10. Excess molar volumes and deviation in viscosities of binary liquid mixtures of acrylic esters with hexane-1-ol at 303.15 and 313.15 K

    OpenAIRE

    Sujata S. Patil; Sunil R. Mirgane; Balasaheb R. Arbad

    2014-01-01

    Densities and viscosities for the four binary liquid mixtures of methyl acrylate, ethyl acrylate, butyl acrylate and methyl methacrylate with hexane-1-ol at temperatures 303.15 and 313.15 K and at atmospheric pressure were measured over the entire composition range. These values were used to calculate excess molar volumes and deviation in viscosities which were fitted to Redlich–Kister polynomial equation. Recently proposed Jouyban Acree model was also used to correlate the experimental value...

  11. Facile Synthesis of Gold Nanoparticle-loaded Carbon Nanofiber Composites and Their Electrocatalytic Activity Towards Dopamine, Ascorbic Acid and Uric Acid

    Institute of Scientific and Technical Information of China (English)

    TENG Hong; LIU Yang; YOU Tian-yan

    2011-01-01

    A facile approach for the synthesis of gold nanoparticle-loaded carbon nanofibcr(Au/CNF) composites was developed. When applied to electrochemistry, these composites showed attractive performances such as high conductivity and facile electron transfer kinetics. Under physiological conditions, the Au/CNF composite modified electrode exhibits highly electrocatalytic activity for the oxidation of dopamine, ascorbic acid and uric acid. Owing to the good selectivity for the simultaneous detection of these three species, the novel composites are promising for the development of effective electrochemical biosensors.

  12. 氟硅丙烯酸酯/钠基蒙脱土复合乳胶涂层的制备及防腐蚀性能%Preparation and anticorrosion performance of fluorine-silicon-acrylate/sodium montmorillonite composite emulsion coating

    Institute of Scientific and Technical Information of China (English)

    高晓辉; 李玉峰; 祝晶晶; 张毅志

    2015-01-01

    以甲基丙烯酸十二氟庚酯和乙烯基三甲氧基硅烷为功能单体,采用种子乳液聚合法合成氟硅丙烯酸酯乳液(氟硅),然后将钠基蒙脱土(钠土)分散于其中,制成复合乳胶涂层并涂覆在Q235钢上。研究了乳液种类和钠土用量对涂层防腐性的影响。采用红外光谱(FT-IR)、透射电子显微镜(TEM)和扫描电子显微镜(SEM)表征了氟硅丙烯酸酯乳液和涂层。通过极化曲线、交流阻抗测量和中性盐雾试验探讨了复合涂层的耐腐蚀性。结果表明,乳胶粒子呈核壳结构,涂层连续、致密,钠土在涂层中分散均匀。当钠土用量为4%时,复合涂层的耐蚀性最好,水接触角达到102.4°,附着力为0级,电化学阻抗达到104.4Ω,腐蚀速率仅为4.3×10−5 mm/a,盐雾试验240 h后膜下金属未发生腐蚀扩散。%A fluorine-silicon-acrylate emulsion was synthesized by seed emulsion polymerization using dodecafluoroheptyl methacrylate and vinyltrimethoxysilane as monomers. Sodium montmorillonite (Na-MMT) was dispersed in the fluorine-silicon-acrylate emulsion for preparing a composite emulsion coating for Q235 steel. The influences of emulsion type and Na-MMT content on anticorrosion properties of the coating were studied. The fluorine-silicon-acrylate emulsion and coating were characterized by Fourier-transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The corrosion resistance of the composite coating was examined by polarization curve measurement, electrochemical impedance spectroscopy, and neutral salt spray test. The results showed that the emulsion particles possess obvious core-shell structure and the composite coating is continuous and compact with well-dispersed Na-MMT. The composite emulsion coating obtained with 4%Na-MMT has optimal anticorrosion performance with a water contact angle of 102.4°, adhesion strength of 0 grade

  13. Multiscale Failure Analysis of Laminated Composite Panels Subjected to Blast Loading Using FEAMAC/Explicit

    Science.gov (United States)

    Pineda, Evan J.; Waas, Anthony M.; Berdnarcyk, Brett A.; Arnold, Steven M.; Collier, Craig S.

    2009-01-01

    This preliminary report demonstrates the capabilities of the recently developed software implementation that links the Generalized Method of Cells to explicit finite element analysis by extending a previous development which tied the generalized method of cells to implicit finite elements. The multiscale framework, which uses explicit finite elements at the global-scale and the generalized method of cells at the microscale is detailed. This implementation is suitable for both dynamic mechanics problems and static problems exhibiting drastic and sudden changes in material properties, which often encounter convergence issues with commercial implicit solvers. Progressive failure analysis of stiffened and un-stiffened fiber-reinforced laminates subjected to normal blast pressure loads was performed and is used to demonstrate the capabilities of this framework. The focus of this report is to document the development of the software implementation; thus, no comparison between the results of the models and experimental data is drawn. However, the validity of the results are assessed qualitatively through the observation of failure paths, stress contours, and the distribution of system energies.

  14. Quasi-Plastic Deformation of WC-Co Composites Loaded with a Spherical Indenter

    Science.gov (United States)

    Zhang, Haibo; Fang, Zhigang Zak; Belnap, J. Daniel

    2007-03-01

    The quasi-plastic deformation behavior of cemented tungsten carbide (WC-Co) materials was studied using Hertzian indentation techniques. The indentation stress-strain curves of three WC-10 wt pct Co alloys with different hardness values demonstrate that WC-Co alloys exhibit “quasi-plasticity” behavior under indentation load and the increase of indentation stress vs indentation strain bears similarity to “strain hardening” in ductile metals. The analysis of the subsurface indentation damage shows that the mechanisms of the quasi-plastic deformation of WC-Co material are the formation of microcracks. Microcracks were found at heavily damaged areas in all three alloys, and the number of microcracks was higher for the sample with the higher apparent quasi-plasticity. The threshold stress values for the onset of quasi-plastic deformation and formation of ring cracks were determined and used to evaluate the brittleness index of these materials. The correlation of the brittleness index with hardness values gives insight with regard to the brittle or quasi-plastic responses of WC-Co materials.

  15. Impact of Packing and Processing Technique on Mechanical Properties of Acrylic Denture Base Materials

    Directory of Open Access Journals (Sweden)

    Touraj Nejatian

    2015-04-01

    Full Text Available The fracture resistance of polymethylmethacrylate (PMMA as the most popular denture base material is not satisfactory. Different factors can be involved in denture fracture. Among them, flexural fatigue and impact are the most common failure mechanisms of an acrylic denture base. It has been shown that there is a correlation between the static strength and fatigue life of composite resins. Therefore, the transverse strength of the denture base materials can be an important indicator of their service life. In order to improve the fracture resistance of PMMA, extensive studies have been carried out; however, only a few promising results were achieved, which are limited to some mechanical properties of PMMA at the cost of other properties. This study aimed at optimizing the packing and processing condition of heat-cured PMMA as a denture base resin in order to improve its biaxial flexural strength (BFS. The results showed that the plain type of resin with a powder/monomer ratio of 2.5:1 or less, packed conventionally and cured in a water bath for 2 h at 95 °C provides the highest BFS. Also, it was found that the performance of the dry heat processor is inconsistent with the number of flasks being loaded.

  16. The effect of fibre layering pattern in resisting bending loads of natural fibre-based hybrid composite materials

    Directory of Open Access Journals (Sweden)

    Jusoh Muhamad Shahirul Mat

    2016-01-01

    Full Text Available The effect of fibre layering pattern and hybridization on the flexural properties of composite hybrid laminates between natural fibres of basalt, jute and flax with synthetic fibre of E-glass reinforced epoxy have been investigated experimentally. Results showed that the effect fibre layering pattern was highly significant on the flexural strength and modulus, which were strongly dependent on the hybrid configuration between sandwich-like (SL and intercalation (IC sequence of fibre layers. In addition, specific modulus based on the variation densities of the hybrid laminates was used to discover the best combination either basalt, jute or flax with E-glass exhibits superior properties concerning on the strength to weight-ratio. Generally, SL sequence of glass/basalt exhibited superior strength and stiffness compared with glass/jute and glass/flax in resisting bending loads. In terms of hybridization effect, glass/jute was found to be the best combination with E-glass compared to the rest of natural fibres investigated in the present study. Hence, the proper stacking sequences and material selection are among predominant factors that influence on mechanical properties and very crucial in designing composite hybrid system to meet the desired requirements.

  17. Adding glycaemic index and glycaemic load functionality to DietPLUS, a Malaysian food composition database and diet intake calculator.

    Science.gov (United States)

    Shyam, Sangeetha; Wai, Tony Ng Kock; Arshad, Fatimah

    2012-01-01

    This paper outlines the methodology to add glycaemic index (GI) and glycaemic load (GL) functionality to food DietPLUS, a Microsoft Excel-based Malaysian food composition database and diet intake calculator. Locally determined GI values and published international GI databases were used as the source of GI values. Previously published methodology for GI value assignment was modified to add GI and GL calculators to the database. Two popular local low GI foods were added to the DietPLUS database, bringing up the total number of foods in the database to 838 foods. Overall, in relation to the 539 major carbohydrate foods in the Malaysian Food Composition Database, 243 (45%) food items had local Malaysian values or were directly matched to International GI database and another 180 (33%) of the foods were linked to closely-related foods in the GI databases used. The mean ± SD dietary GI and GL of the dietary intake of 63 women with previous gestational diabetes mellitus, calculated using DietPLUS version3 were, 62 ± 6 and 142 ± 45, respectively. These values were comparable to those reported from other local studies. DietPLUS version3, a simple Microsoft Excel-based programme aids calculation of diet GI and GL for Malaysian diets based on food records.

  18. Ag/AgCl Loaded Bi2WO6 Composite: A Plasmonic Z-Scheme Visible Light-Responsive Photocatalyst

    Directory of Open Access Journals (Sweden)

    Xiangchao Meng

    2016-01-01

    Full Text Available Hierarchical flower-like Bi2WO6 was successfully synthesized by facile hydrothermal method at low pH. And Ag/AgCl was loaded by photoreduction on its surface. As-prepared photocatalysts were characterized by various techniques. Bi2WO6 was successfully synthesized at a size of 2-3 μm. Depositing Ag/AgCl did not destroy the crystal structure, and both Ag+ and metallic Ag0 were found. The band gap of the composite was 2.57 eV, which indicates that visible light could be the activating irradiation. In the photocatalytic activity test, the composite with 10 wt% Ag/AgCl boasted the highest removal efficiency (almost 100% in 45 min. The significant enhancement can be attributed to the surface plasmon resonance (SPR effect and the establishment of heterostructures between Ag/AgCl and Bi2WO6. A possible mechanism of photocatalytic oxidation in the presence of Ag/AgCl-Bi2WO6 was proposed. This work sheds light on the potential applications of plasmonic metals in photocatalysis to enhance their activities.

  19. Relationship Between Hysteresis Dissipated Energy and Temperature Rising in Fiber-Reinforced Ceramic-Matrix Composites Under Cyclic Loading

    Science.gov (United States)

    Longbiao, Li

    2016-06-01

    In this paper, the relationship between hysteresis dissipated energy and temperature rising of the external surface in fiber-reinforced ceramic-matrix composites (CMCs) during the application of cyclic loading has been analyzed. The temperature rise, which is caused by frictional slip of fibers within the composite, is related to the hysteresis dissipated energy. Based on the fatigue hysteresis theories considering fibers failure, the hysteresis dissipated energy and a hysteresis dissipated energy-based damage parameter changing with the increase of cycle number have been investigated. The relationship between the hysteresis dissipated energy, a hysteresis dissipated energy-based damage parameter and a temperature rise-based damage parameter have been established. The experimental temperature rise-based damage parameter of unidirectional, cross-ply and 2D woven CMCs corresponding to different fatigue peak stresses and cycle numbers have been predicted. It was found that the temperature rise-based parameter can be used to monitor the fatigue damage evolution and predict the fatigue life of fiber-reinforced CMCs.

  20. 2D micromechanical analysis of SiC/Al metal matrix composites under tensile, shear and combined tensile/shear loads

    DEFF Research Database (Denmark)

    Qing, Hai

    2013-01-01

    and aluminum alloy matrix, respectively. A series of computational experiments are performed to study the influence of particle arrangements, interface strengths and loading conditions of the representative volume element (RVE) on composite stiffness and strength properties. © 2013 Elsevier Ltd.......The influence of interface strength and loading conditions on the mechanical behavior of the metal-matrix composites is investigated in this paper. A program is developed to generate automatically 2D micromechanical Finite element (FE) models including interface, in which both the locations...

  1. Use of an acrylic painting to increase the durability of reinforced concrete in a seawater environment

    OpenAIRE

    Aguiar, J. L. Barroso de; Sousa, M.B.

    2000-01-01

    One of the most aggressive environments for reinforced concrete is the contact with seawater. The chlorides present in seawater penetrate into the concrete and the possibility to armatures corrosion increases significantly. In this study an acrylic painting was used to protect the concrete and decrease the diffusion of chlorides. We used two concretes with different compositions. One composition respects the exigencies of European standardisation for this environment and the other one no. The...

  2. FT-IR and FT-Raman studies of cross-linking processes with Ca²⁺ ions, glutaraldehyde and microwave radiation for polymer composition of poly(acrylic acid)/sodium salt of carboxymethyl starch - In moulding sands, Part II.

    Science.gov (United States)

    Grabowska, Beata; Sitarz, Maciej; Olejnik, Ewa; Kaczmarska, Karolina; Tyliszczak, Bozena

    2015-12-01

    The hardening process of moulding sands on quartz matrices bound by polymer binders containing carboxyl and hydroxyl groups can be carried out by using physical (microwave radiation, thermal holding) and chemical (Ca(2+) cations, glutaraldehyde) cross-linking agents. The highest hardening level obtain moulding sand samples containing binders in a form of the aqueous composition of poly(acrylic acid)/sodium salt of carboxymethyl starch (PAA/CMS-Na) within the microwave radiation field, for which the bending strength is of 1.6 MPa value even after 24h from ending the agent activity. The authors focused, in this study, on finding the reason of this effect. It was shown, by means of the FT-IR and FT-Raman spectroscopic methods, that the chemical adsorption process activated by microwaves plays an essential role. The applied microwaves activate the polar groups present in the polymer composition structure as well as the quartz crystals surfaces (silane groups). Then the chemical adsorption occurs in the binder-matrix system within the microwave radiation field and intermolecular lattices are formed with a participation of hydrogen bridges (SiOH⋯OC, SiOH⋯OH) and COSi type bonds. PMID:26125981

  3. Investigation of Ionic Polymer Metal Composite Actuators Loaded with Various Tetraethyl Orthosilicate Contents

    Institute of Scientific and Technical Information of China (English)

    Qingsong He; Min Yu; Yuxiu Li; Yan Ding; Dongjie Guo; Zhendong Dai

    2012-01-01

    Ionic Polymer Metal Composite (IPMC) can be used as an electrically activated actuator,which has been widely used in artificial muscles,bionic robotic actuators,and dynamic sensors since it has the advantages of large deformation,light weight,flexibility,and low driving voltage,etc.To further improve the mechanical properties of IPMC,this paper reports a new method for preparing organic-inorganic hybrid Nafion/SiO2 membranes.Beginning from cast Nation membranes,IPMCs with various tetraethyl orthosilicate (TEOS) contents were fabricated by electroless plating.The elastic moduli of cast Nation membranes were measured with nano indenters,the water contents were calculated,and the cross sections of Nafion membranes were observed by scanning electron microscopy.The blocking force,the displacement,and the electric current of IPMCs were then measured on a test apparatus.The results show that the blocking force increases as the TEOS content gradually increases,and that both the displacement and the electric current initially decrease,then increase.When the TEOS content is 1.5%,the IPMC shows the best improved mechanical properties.Finally,the IPMC with the best improved performance was used to successfully actuate the artificial eye and tested.

  4. Fatigue Performance Assessment of Composite Arch Bridge Suspenders Based on Actual Vehicle Loads

    Directory of Open Access Journals (Sweden)

    Bin Chen

    2015-01-01

    Full Text Available In the through arch bridges, the suspenders are the key components connecting the arch rib and the bridge deck in the middle, and their safety is an increasing focus in the field of bridge engineering. In this study, various vehicle traffic flow parameters are investigated based on the actual vehicle data acquired from the long-term structural health monitoring system of a composite arch bridge. The representative vehicle types and the probability density functions of several parameters are determined, including the gross vehicle weight, axle weight, time headway, and speed. A finite element model of the bridge structure is constructed to determine the influence line of the cable force for various suspenders. A simulated vehicle flow, generated using the Monte Carlo method, is applied on the influence lines of the target suspender to determine the stress process, and then the stress amplitude spectrum is obtained based on the statistical analysis of the stress process using the rainflow counting method. The fatigue performance levels of various suspenders are analyzed according to the Palmgren-Miner linear cumulative damage theory, which helps to manage the safety of the suspenders.

  5. Sustainable Antibiofouling Properties of Thin Film Composite Forward Osmosis Membrane with Rechargeable Silver Nanoparticles Loading.

    Science.gov (United States)

    Liu, Zhongyun; Hu, Yunxia

    2016-08-24

    Microbial attachment and biofilm formation on filtration membrane can greatly compromise its flux and separation efficiency. Here, a simple and facile approach has been developed to in situ generate silver nanoparticles (Ag NPs) on the thin film composite forward osmosis (TFC FO) membrane for sustainable antibiofouling performances. Mussel-inspired dopamine chemistry was applied to grow polydopamine coating on both surfaces of FO membranes, followed by the generation of Ag NPs upon a simple dip coating in silver nitrate aqueous solution. Furthermore, the Ag NPs deposited membranes had a long-term silver release profile with rechargability for multiple times upon their depletion, and exhibited strong sustainable bactericidal efficacy against Gram-negative bacteria and Gram-positive bacteria. The Ag NPs had a controllable effect on the membrane performances including the water flux and reverse salt flux in the FO test mode. Our practicable antibacterial strategy may apply to other types of filtration membranes with diverse material surfaces and may pave a new way to achieve the sustainable membrane antibiofouling performance on a large scale. PMID:27467542

  6. Sustainable Antibiofouling Properties of Thin Film Composite Forward Osmosis Membrane with Rechargeable Silver Nanoparticles Loading.

    Science.gov (United States)

    Liu, Zhongyun; Hu, Yunxia

    2016-08-24

    Microbial attachment and biofilm formation on filtration membrane can greatly compromise its flux and separation efficiency. Here, a simple and facile approach has been developed to in situ generate silver nanoparticles (Ag NPs) on the thin film composite forward osmosis (TFC FO) membrane for sustainable antibiofouling performances. Mussel-inspired dopamine chemistry was applied to grow polydopamine coating on both surfaces of FO membranes, followed by the generation of Ag NPs upon a simple dip coating in silver nitrate aqueous solution. Furthermore, the Ag NPs deposited membranes had a long-term silver release profile with rechargability for multiple times upon their depletion, and exhibited strong sustainable bactericidal efficacy against Gram-negative bacteria and Gram-positive bacteria. The Ag NPs had a controllable effect on the membrane performances including the water flux and reverse salt flux in the FO test mode. Our practicable antibacterial strategy may apply to other types of filtration membranes with diverse material surfaces and may pave a new way to achieve the sustainable membrane antibiofouling performance on a large scale.

  7. Effect of thermal shock loadings on stability of dentin-composite polymer material adhesive interfaces

    Science.gov (United States)

    Bessudnova, Nadezda O.; Shlyapnikova, Olga A.; Venig, Sergey B.; Gribov, Andrey N.

    2015-03-01

    In the past several decades the problem of longevity and durability of adhesive interfaces between hard tooth tissues and composite resin-based materials are of great interest among dental researchers and clinicians. These parameters are partially determined by adhesive system mechanical properties. In the present research project nanoindentation has been examined to test hardness of dental adhesive systems. A series of laboratory experiments was performed to study the effect of light curing time and oxygen inhibition phenomenon on light-cured adhesive material hardness. An adhesive system AdperTM Single Bond (3M ESPE) was selected as a material for testing. The analysis of experimental data revealed that the maximum values of hardness were observed after the material had been light-cured for 20 seconds, as outlined in guidelines for polymerization time of the adhesive system. The experimental studies of oxygen inhibition influence on adhesive system hardness pointed out to the fact that the dispersive layer removal led to increase in adhesive system hardness. A long - time exposure of polymerized material of adhesive system at open air at room temperature resulted in no changes in its hardness, which was likely to be determined by the mutual effect of rival processes of air oxygen inhibition and directed light curing.

  8. Characterization and adsorption properties of a lanthanum-loaded magnetic cationic hydrogel composite for fluoride removal.

    Science.gov (United States)

    Dong, Shuoxun; Wang, Yili

    2016-01-01

    In this study, a novel lanthanum-loaded magnetic cationic hydrogel (MCH-La) was synthesized for fluoride adsorption from drinking water. The adsorption kinetics, isotherms, and effects of pH and co-existing anions on fluoride uptake by MCH-La were evaluated. FTIR, Raman and XPS were used to analyze the fluoride adsorption mechanism of MCH-La. Results showed that MCH-La had positive zeta potential values of 23.6-8.0 mV at pH 3.0-11.0, with the magnitude of saturation magnetization up to 10.3 emu/g. The fluoride adsorption kinetics by MCH-La fitted well with the fractal-like-pseudo-second-order model, and the adsorption capacity reached 93% of the ultimate adsorption capacity within the first 10 min. The maximum fluoride adsorption capacity for MCH-La was 136.78 mg F(-)/g at an equilibrium fluoride concentration of 29.3 mg/L and pH 7.0. Equilibrium adsorption data showed that the Sips model was more suitable than the Langmuir and Freundlich models. MCH-La still had more than 100 mg of F(-)/g adsorption capacity at a strongly alkaline solution (pH > 10). The adsorption process was highly pH-dependent, and the optimal adsorption was attained at pH 2.8-4.0, corresponding to ligand exchange, electrostatic interactions, and Lewis acid-base interactions. With the exception of both anions of HCO3(-) and SiO4(4-), Cl(-), NO3(-), and SO4(2-) did not evidently prevent fluoride removal by MCH-La at their real concentrations in natural groundwater. The fluoride adsorption capacity of the regenerated MCH-La approached 70% of the fresh MCH-La from the second to fifth recycles. FTIR and Raman spectra revealed that C-O and CO functional groups on MCH contributed to the fluoride adsorption, this finding was also confirmed by the XPS F 1s spectra. Deconvolution of C 1s spectra before and after fluoride adsorption indicated that the carboxyl, anhydride, and phenol groups of MCH were involved in the fluoride removal.

  9. Optimizing flurbiprofen-loaded NLC by central composite factorial design for ocular delivery

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez-Mira, E; Egea, M A; Garcia, M L [Department of Physical Chemistry, Faculty of Pharmacy, Institute of Nanoscience and Nanotechnology, University of Barcelona, Avenida Joan XXIII s/n, E-08028 Barcelona (Spain); Souto, E B [Faculty of Health Sciences, Fernando Pessoa University, Rua Carlos da Maia, Nr. 296, Office S.1, P-4200-150 Porto (Portugal); Calpena, A C, E-mail: eligonzalezmi@ub.edu [Department of Biopharmacy and Pharmaceutical Technology, Faculty of Pharmacy, University of Barcelona, Avenida Joan XXIII s/n, E-08028 Barcelona (Spain)

    2011-01-28

    The purpose of this study was to design and optimize a new topical delivery system for ocular administration of flurbiprofen (FB), based on lipid nanoparticles. These particles, called nanostructured lipid carriers (NLC), were composed of a fatty acid (stearic acid (SA)) as the solid lipid and a mixture of Miglyol 812 and castor oil (CO) as the liquid lipids, prepared by the hot high pressure homogenization method. After selecting the critical variables influencing the physicochemical characteristics of the NLC (the liquid lipid (i.e. oil) concentration with respect to the total lipid (cOil/L (wt%)), the surfactant and the flurbiprofen concentration, on particle size, polydispersity index and encapsulation efficiency), a three-factor five-level central rotatable composite design was employed to plan and perform the experiments. Morphological examination, crystallinity and stability studies were also performed to accomplish the optimization study. The results showed that increasing cOil/L (wt%) was followed by an enhanced tendency to produce smaller particles, but the liquid to solid lipid proportion should not exceed 30 wt% due to destabilization problems. Therefore, a 70:30 ratio of SA to oil (miglyol + CO) was selected to develop an optimal NLC formulation. The smaller particles obtained when increasing surfactant concentration led to the selection of 3.2 wt% of Tween 80 (non-ionic surfactant). The positive effect of the increase in FB concentration on the encapsulation efficiency (EE) and its total solubilization in the lipid matrix led to the selection of 0.25 wt% of FB in the formulation. The optimal NLC showed an appropriate average size for ophthalmic administration (228.3 nm) with a narrow size distribution (0.156), negatively charged surface (-33.3 mV) and high EE ({approx}90%). The in vitro experiments proved that sustained release FB was achieved using NLC as drug carriers. Optimal NLC formulation did not show toxicity on ocular tissues.

  10. Optimizing flurbiprofen-loaded NLC by central composite factorial design for ocular delivery

    Science.gov (United States)

    Gonzalez-Mira, E.; Egea, M. A.; Souto, E. B.; Calpena, A. C.; García, M. L.

    2011-01-01

    The purpose of this study was to design and optimize a new topical delivery system for ocular administration of flurbiprofen (FB), based on lipid nanoparticles. These particles, called nanostructured lipid carriers (NLC), were composed of a fatty acid (stearic acid (SA)) as the solid lipid and a mixture of Miglyol® 812 and castor oil (CO) as the liquid lipids, prepared by the hot high pressure homogenization method. After selecting the critical variables influencing the physicochemical characteristics of the NLC (the liquid lipid (i.e. oil) concentration with respect to the total lipid (cOil/L (wt%)), the surfactant and the flurbiprofen concentration, on particle size, polydispersity index and encapsulation efficiency), a three-factor five-level central rotatable composite design was employed to plan and perform the experiments. Morphological examination, crystallinity and stability studies were also performed to accomplish the optimization study. The results showed that increasing cOil/L (wt%) was followed by an enhanced tendency to produce smaller particles, but the liquid to solid lipid proportion should not exceed 30 wt% due to destabilization problems. Therefore, a 70:30 ratio of SA to oil (miglyol + CO) was selected to develop an optimal NLC formulation. The smaller particles obtained when increasing surfactant concentration led to the selection of 3.2 wt% of Tween® 80 (non-ionic surfactant). The positive effect of the increase in FB concentration on the encapsulation efficiency (EE) and its total solubilization in the lipid matrix led to the selection of 0.25 wt% of FB in the formulation. The optimal NLC showed an appropriate average size for ophthalmic administration (228.3 nm) with a narrow size distribution (0.156), negatively charged surface (-33.3 mV) and high EE (~90%). The in vitro experiments proved that sustained release FB was achieved using NLC as drug carriers. Optimal NLC formulation did not show toxicity on ocular tissues.

  11. Surface cross-linked humic acid - polysodium acrylate superabsorbent

    Energy Technology Data Exchange (ETDEWEB)

    Chu, M.; Zhu, S.; Li, H.; Huang, Z.; Zhang, X. [China University of Mining and Technology, Beijing (China)

    2005-03-01

    A novel composite super-absorbent of humic acid-polysodium acrylate was invented by surface cross-linking reaction of lignite humic acid and poly. Humic acid was abstracted from leonardite and poly was synthesized by solution polymerization. Water absorbing mechanism of composite superabsorbent was explored based on FTIR and SEM. The effect of surface cross-linking reaction conditions, such as the ratio of methanol to water, cross-linking agent concentration, and the amount of humic acid on water absorbing were investigated. Experiments show that the water absorbency of superabsorbent can be greatly improved by humic acid. When the mass fraction of humic acid is 10%, the ratio of cross-linking agent to PSA is 0.2%, and the ratio of methanol to water is 1.8, the water absorbency is the best: 750 g/g for deionied water and 260 g/g for running. water. 9 refs., 5 figs., 1 tab.

  12. Polymerisation by acrylamide and acrylic acid inverse suspension

    Directory of Open Access Journals (Sweden)

    Sergio Alejandro LLoreda Blanco

    2010-04-01

    Full Text Available This work describes polymerisation by inverse suspension of acrylamide monomers and acrylic acid for forming homopolymers or copolymers This type of polymersitaion's advantages are described and reasons given for why it should be studied. The article stresses the importance of these types of monomer for obtaining materials presenting great affinity for water, such as super-absorbents and controlled liberation mechanism. Important aspects are presented such as type of initiation, monomer composition and continuous phase composition; parameters are described offering an important basis for formulating a system leading to successfully obtaining the desired materials' most relevant characteristics such as particle distribution and size polymerisation kinetics, conversion and water absorption capacity respecting the system's modifiable parameters. The foregoing is important since the product can be modified, bestowing propierties on it which are suitable for its use.

  13. Swelling Behaviors of Polyaniline-Poly(Acrylic Acid) Hydrogels

    Institute of Scientific and Technical Information of China (English)

    ZHANG You-wei; ZHAO Jiong-xin; LI Xiao-feng; TAO Yong; WU Cheng-xun

    2005-01-01

    Using poly(acrylic acid) (PAA) aqueous solution, NaOH aqueous solution, aniline(An) and ammonim persulfate(APS), PAn-PAA hydrogels with a semi-interpenetrating structure connected by physical interlocks, chemical ion bonds and hydrogen bonds wcre prepared. The swelling properties of the hydrogels in solutions of different pH values(adjusted by adding NaOH or HCl) were studied. All the hydrogels prepared have similar swelling curves (the curves of equilibrium swelling ratio vs. pH value) and reach their maximum swelling at pH of 8 - 10. The maximum swelling ratio of the hydrogels is dependent on composition, including molecular weight of PAA, polymer content of the hydrogel,and molar ratios of AA to An, APS to An, and NaOH to AA.And the compositional dependence of the swelling capacity of PAn-PAA hydrogels was also studied.

  14. Effect of Compaction Load and Sintering Temperature on Tribological and Mechanical Behavior of Ni/SiC/MoS2 Composites

    Science.gov (United States)

    Prabhu, T. Ram

    2016-04-01

    In the present investigation, the effects of compaction load and sintering temperature on the tribological and mechanical behavior of Ni/20%SiC/7%MoS2 hybrid composites was studied. The density, compression strength, and hardness of the composites were evaluated and compared. The wear properties of the composites were evaluated for the test condition of 1 m/s speed and 10 N load using a pin-on-disk tribometer. The braking performance of the composites was evaluated in a subscale dynamometer for the 500 kJ energy condition. The microstructure and wear surface morphology of the composites were analyzed by stereo, optical, and scanning electron microscopes. From the results, the following important conclusions are drawn: (1) the compaction load of 1400 kN and sintering temperature of 900 °C are optimum to obtain the best combination of tribological and mechanical properties; (2) the properties such as density, compression strength, hardness, wear, and friction increase up to a critical sintering temperature, and then decrease later; (3) the composition and thickness of the interface reaction product phases (Ni2Si, Ni3Si, and graphite) play a key role in deciding the strength of Ni/SiC interface that consequently affects the mechanical and tribological properties of the composites; (4) the abrasive wear is found to be the main wear mechanism in the highly densified composites, whereas the delamination wear and the third-body wear are major wear mechanisms in the poorly densified composites; and (5) the better braking performance of the highly densified composites is attributed to the absence of third-body wear, controlled flow of solid lubricant, and lower porosity.

  15. Effect of light-curing, pressure, oxygen inhibition, and heat on shear bond strength between bis-acryl provisional restoration and bis-acryl repair materials

    Science.gov (United States)

    Shim, Ji-Suk; Lee, Jeong-Yol; Choi, Yeon-Jo; Shin, Sang-Wan

    2015-01-01

    PURPOSE This study aimed to discover a way to increase the bond strength between bis-acryl resins, using a comparison of the shear bond strengths attained from bis-acryl resins treated with light curing, pressure, oxygen inhibition, and heat. MATERIALS AND METHODS Self-cured bis-acryl resin was used as both a base material and as a repair material. Seventy specimens were distributed into seven groups according to treatment methods: pressure - stored in a pressure cooker at 0.2 Mpa; oxygen inhibition- applied an oxygen inhibitor around the repaired material,; heat treatment - performed heat treatment in a dry oven at 60℃, 100℃, or 140℃. The shear bond strength was measured with a universal testing machine, and the shear bond strength (MPa) was calculated from the peak load of failure. A comparison of the bond strength between the repaired specimens was conducted using one-way ANOVA and Tukey multiple comparison tests (α=.05). RESULTS There were no statistically significant differences in the shear bond strength between the control group and the light curing, pressure, and oxygen inhibition groups. However, the heat treatment groups showed statistically higher bond strengths than the groups treated without heat, and the groups treated at a higher temperature resulted in higher bond strengths. Statistically significant differences were seen between groups after different degrees of heat treatment, except in groups heated at 100℃ and 140℃. CONCLUSION Strong bonding can be achieved between a bis-acryl base and bis-acryl repair material after heat treatment. PMID:25722837

  16. Occupational fingertip eczema from acrylates in a manicurist

    OpenAIRE

    Denitza Zheleva; Razvigor Darlenski

    2015-01-01

    Occupational hand eczema due to acrylates present in the workplace is a disease frequently reported among dentists, printers, and fiberglass workers. Acrylate monomers are used in the production of a great variety of polymers, including nail cosmetics. Our case report demonstrates a rare clinical presentations of allergic contact dermatitis from acrylic nails. Our patient was working as a manicurist and the diagnostic analyses revealed sensitation to some of the (meth) acrylate compounds of h...

  17. Concepts for stereoselective acrylate insertion

    KAUST Repository

    Neuwald, Boris

    2013-01-23

    Various phosphinesulfonato ligands and the corresponding palladium complexes [{((PaO)PdMeCl)-μ-M}n] ([{( X1-Cl)-μ-M}n], (PaO) = κ2- P,O-Ar2PC6H4SO2O) with symmetric (Ar = 2-MeOC6H4, 2-CF3C6H4, 2,6-(MeO)2C6H3, 2,6-(iPrO)2C 6H3, 2-(2′,6′-(MeO)2C 6H3)C6H4) and asymmetric substituted phosphorus atoms (Ar1 = 2,6-(MeO)2C6H 3, Ar2 = 2′-(2,6-(MeO)2C 6H3)C6H4; Ar1 = 2,6-(MeO)2C6H3, Ar2 = 2-cHexOC 6H4) were synthesized. Analyses of molecular motions and dynamics by variable temperature NMR studies and line shape analysis were performed for the free ligands and the complexes. The highest barriers of ΔGa = 44-64 kJ/mol were assigned to an aryl rotation process, and the flexibility of the ligand framework was found to be a key obstacle to a more effective stereocontrol. An increase of steric bulk at the aryl substituents raises the motional barriers but diminishes insertion rates and regioselectivity. The stereoselectivity of the first and the second methyl acrylate (MA) insertion into the Pd-Me bond of in situ generated complexes X1 was investigated by NMR and DFT methods. The substitution pattern of the ligand clearly affects the first MA insertion, resulting in a stereoselectivity of up to 6:1 for complexes with an asymmetric substituted phosphorus. In the consecutive insertion, the stereoselectivity is diminished in all cases. DFT analysis of the corresponding insertion transition states revealed that a selectivity for the first insertion with asymmetric (P aO) complexes is diminished in the consecutive insertions due to uncooperatively working enantiomorphic and chain end stereocontrol. From these observations, further concepts are developed. © 2012 American Chemical Society.

  18. Do Milk Samples Stored for 12 Days after Collection Exhibit a Change in Composition Related to the Initial Bacterial Load?

    Science.gov (United States)

    de Freitas, Larissa Nazareth; Cassoli, Laerte Dagher; da Silva, Janielen; de Figueiredo Pantoja, José Carlos; Machado, Paulo Fernando

    2016-05-01

    Total bacterial count (TBC) is a tool used to assess milk quality and is associated with not only the initial sample contamination but also the sample storage time and temperature. Several countries have reported milk samples with a high TBC, and the influence of TBC on milk preservation remains unclear. Thus, the aim of this study was to evaluate the impact of the initial bacterial contamination level on the macrocomponents and somatic cell count (SCC) of raw milk samples preserved with bronopol and maintained at two storage temperatures (7 and 25°C) for up to 12 days. Thus, we collected milk samples from 51 dairy farms, which were divided into two groups according to the initial bacterial load: low TBC (<100,000 CFU/ml) and high TBC (≥100,000 CFU/ml). We analyzed the sample composition for protein, fat, total solids, lactose, milk urea nitrogen, and the SCC. We did not observe an effect from TBC and storage time and temperature on the concentration of protein, fat, total solids, and lactose. SCC changes were not observed for samples maintained under refrigeration (7°C); however, samples maintained at room temperature (25°C) exhibited a decrease in the SCC beginning on day 6 of storage. For milk urea nitrogen, values increased when the samples were maintained at room temperature, beginning on the ninth storage day. Samples with the preservative bronopol added and maintained under refrigeration may be analyzed up to 12 days after collection, regardless of the milk microbial load.

  19. A Novel High Mechanical Property PLGA Composite Matrix Loaded with Nanodiamond-Phospholipid Compound for Bone Tissue Engineering.

    Science.gov (United States)

    Zhang, Fan; Song, Qingxin; Huang, Xuan; Li, Fengning; Wang, Kun; Tang, Yixing; Hou, Canglong; Shen, Hongxing

    2016-01-20

    A potential bone tissue engineering material was produced from a biodegradable polymer, poly(lactic-co-glycolic acid) (PLGA), loaded with nanodiamond phospholipid compound (NDPC) via physical mixing. On the basis of hydrophobic effects and physical absorption, we modified the original hydrophilic surface of the nanodiamond (NDs) with phospholipids to be amphipathic, forming a typical core-shell structure. The ND-phospholipid weight ratio was optimized to generate sample NDPC50 (i.e., ND-phospholipid weight ratio of 100:50), and NDPC50 was able to be dispersed in a PLGA matrix at up to 20 wt %. Compared to a pure PLGA matrix, the introduction of 10 wt % of NDPC (i.e., sample NDPC50-PF10) resulted in a significant improvement in the material's mechanical and surface properties, including a decrease in the water contact angle from 80 to 55°, an approximately 100% increase in the Young's modulus, and an approximate 550% increase in hardness, thus closely resembling that of human cortical bone. As a novel matrix supporting human osteoblast (hFOB1.19) growth, NDPC50-PFs with different amounts of NDPC50 demonstrated no negative effects on cell proliferation and osteogenic differentiation. Furthermore, we focused on the behaviors of NDPC-PFs implanted into mice for 8 weeks and found that NDPC-PFs induced acceptable immune response and can reduce the rapid biodegradation of PLGA matrix. Our results represent the first in vivo research on ND (or NDPC) as nanofillers in a polymer matrix for bone tissue engineering. The high mechanical properties, good in vitro and in vivo biocompatibility, and increased mineralization capability suggest that biodegradable PLGA composite matrices loaded with NDPC may potentially be useful for a variety of biomedical applications, especially bone tissue engineering.

  20. One-Step Formation of WO3-Loaded TiO2 Nanotubes Composite Film for High Photocatalytic Performance

    Directory of Open Access Journals (Sweden)

    Wai Hong Lee

    2015-04-01

    Full Text Available High aspect ratio of WO3-loaded TiO2 nanotube arrays have been successfully synthesized using the electrochemical anodization method in an ethylene glycol electrolyte containing 0.5 wt% ammonium fluoride in a range of applied voltage of 10–40 V for 30 min. The novelty of this research works in the one-step formation of WO3-loaded TiO2 nanotube arrays composite film by using tungsten as the cathode material instead of the conventionally used platinum electrode. As compared with platinum, tungsten metal has lower stability, forming dissolved ions (W6+ in the electrolyte. The W6+ ions then move towards the titanium foil and form a coherent deposit on titanium foil. By controlling the oxidation rate and chemical dissolution rate of TiO2 during the electrochemical anodization, the nanotubular structure of TiO2 film could be achieved. In the present study, nanotube arrays were characterized using FESEM, EDAX, XRD, as well as Raman spectroscopy. Based on the results obtained, nanotube arrays with average pore diameter of up to 74 nm and length of 1.6 µm were produced. EDAX confirmed the presence of tungsten element within the nanotube arrays which varied in content from 1.06 at% to 3.29 at%. The photocatalytic activity of the nanotube arrays was then investigated using methyl orange degradation under TUV 96W UV-B Germicidal light irradiation. The nanotube with the highest aspect ratio, geometric surface area factor and at% of tungsten exhibited the highest photocatalytic activity due to more photo-induced electron-hole pairs generated by the larger surface area and because WO3 improves charge separation, reduces charge carrier recombination and increases charge carrier lifetime via accumulation of electrons and holes in the two different metal oxide semiconductor components.

  1. Fracture behavior under fatigue loading at room temperature and its influence on critical current of Nb-Ti/Cu composite wire

    Science.gov (United States)

    Hojo, Masaki; Iwasaki, Naoya; Sekino, Fumiaki; Ochiai, Shojiro; Sakai, Shuji; Watanabe, Kazuo

    1999-11-01

    Fracture behavior under fatigue loading at room temperature and its influence on critical superconducting current at 4.2 K were investigated for Nb-Ti/Cu multifilamentary composite wire with a copper ratio of 7.83 and an overall diameter of 0.504 mm in which 24 Nb-Ti filaments were embedded. There was a knee in the relation between the applied maximum stress and the number of cycles to failure ( S- N relations). The fracture mechanism below and above this knee was different. When the maximum stress in the fatigue test was high, extensive multiple necking of the Nb-Ti filament occurred, and this was responsible for the final fracture of the composite wire. On the other hand, when the maximum stress in the fatigue tests was low, the fatigue crack nucleated in the copper, which grew and caused the fracture of the Nb-Ti filaments. The critical current was insensitive to fatigue loading when the maximum stress was low. When the maximum stress was high, the critical current after fatigue loading was lower than that after static loading. This was due to severe multiple necking during fatigue loading. Extracted Nb-Ti filaments were also fatigued using a specially designed fatigue testing machine. The S- N curve of filaments agreed well with the stress component of the filament calculated from the S- N relation of the composite wire.

  2. SYNTHESIS OF BIOCOMPATIBLE ACRYLIC POLYMERS HAVING ASPIRIN-MOIETIES

    Institute of Scientific and Technical Information of China (English)

    LI Fumian; GU Zhongwei; FENG Xinde(S. T. Voong)

    1983-01-01

    Several new monomers, β-(acetylsalicylyloxy)ethyl methacrylate, β-(acetylsalicylyloxy)propyl methacrylate, β-(acetylsalicylyloxy)ethyl acrylate, β-hydroxy-γ-(acetylsalicylyloxy)propyl methacrylate, β-hydroxy-γ-(acetylsalicylyloxy)propyl acrylate have been synthesized from aspirin with corresponding hydroxyalkyl or glycidyl acrylates, and then polymerized by free radical initiator.

  3. 40 CFR 721.5325 - Nickel acrylate complex.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Nickel acrylate complex. 721.5325... Substances § 721.5325 Nickel acrylate complex. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance nickel acrylate complex (PMN P-85-1034) is subject to reporting...

  4. 21 CFR 175.210 - Acrylate ester copolymer coating.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Acrylate ester copolymer coating. 175.210 Section... COATINGS Substances for Use as Components of Coatings § 175.210 Acrylate ester copolymer coating. Acrylate ester copolymer coating may safely be used as a food-contact surface of articles intended for...

  5. 21 CFR 573.120 - Acrylamide-acrylic acid resin.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Acrylamide-acrylic acid resin. 573.120 Section 573.120 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED... Food Additive Listing § 573.120 Acrylamide-acrylic acid resin. Acrylamide-acrylic acid...

  6. Investigation of Acrylic Acid at High Pressure using Neutron Diffraction

    DEFF Research Database (Denmark)

    Johnston, Blair F.; Marshall, William G.; Parsons, Simon;

    2014-01-01

    This article details the exploration of perdeuterated acrylic acid at high pressure using neutron diffraction. The structural changes that occur in acrylic acid-d4 are followed via diffraction and rationalised using the Pixel method. Acrylic acid undergoes a reconstructive phase transition to a n...

  7. 21 CFR 176.110 - Acrylamide-acrylic acid resins.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Acrylamide-acrylic acid resins. 176.110 Section 176... Substances for Use Only as Components of Paper and Paperboard § 176.110 Acrylamide-acrylic acid resins. Acrylamide-acrylic acid resins may be safely used as components of articles intended for use in...

  8. 40 CFR 721.324 - Alkoxylated acrylate polymer (generic).

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Alkoxylated acrylate polymer (generic... Substances § 721.324 Alkoxylated acrylate polymer (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as alkoxylated acrylate...

  9. Amylase catalyzed synthesis of glycosyl acrylates and their polymerization

    NARCIS (Netherlands)

    Kloosterman, Wouter M.J.; Jovanovic, Danijela; Brouwer, Sander; Loos, Katja

    2014-01-01

    The enzymatic synthesis of novel (di)saccharide acrylates from starch and 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate and 4-hydroxybutyl acrylate (2-HEA, 2-HEMA and 4-HBA) catalyzed by various commercially available amylase preparations is demonstrated. Both liquefaction and saccharificatio

  10. Natural compositional variation of the river Meuse (Maas) suspended load: a 13 ka bulk geochemical record from the upper Kreftenheye and Betuwe Formations in northern Limburg

    NARCIS (Netherlands)

    Tebbens, L.A.; Veldkamp, A.; Kroonenberg, S.B.

    2000-01-01

    Unambiguously pristine and largely unpolluted sediments from the Late Weichselian and Holocene infillings of the Meuse residual channels in northern Limburg (the Netherlands) have been sampled to determine the natural compositional variation of the river’s suspended load. Bulk geochemical and granul

  11. GROWING ALTERNATIVE SUSTAINABLE BUILDINGS: BIO-COMPOSITE PRODUCTS FROM NATURAL FIBER, BIODEGRADABLE AND RECYCLABLE POLYMER MATERIALS FOR LOAD-BEARING CONSTRUCTION COMPONENTS

    Science.gov (United States)

    The project is an integrative educational and research project that will revolutionize design and construction methods towards more sustainable buildings. The project will develop and test new product design concepts using bio-composite materials in load-bearing and fa&cced...

  12. Proton Exchange Membrane from the Blend of Copolymers of Vinyl Acetate- Acrylic Ester and Styrene-Acrylic Ester for Power Generation Using Fuel Cell

    Directory of Open Access Journals (Sweden)

    Alvaro Realpe

    2014-10-01

    Full Text Available Proton exchange membranes for fuel cells were synthesized from the blend of copolymers of vinyl acetate-acrylic ester and styrene-acrylic ester, which were modified by sulfonation and addition of silica gel. Water uptake, ion exchange capacity, infrared spectroscopy and tensile tests were applied to characterize the prepared membranes. The results show that the prepared membranes with the processes of sulfonation and loaded with silica have the highest water uptake (92,7%. On the other hand, the sulfonation process lead to membranes with high ion exchange capacity and high mechanical strength (0,68 meq/g and 1,29 MPa, respectively. Therefore, the sulfonated membrane represents an alternative for the application as proton exchange membrane in fuel cells.

  13. Notch Sensitivity of Woven Ceramic Matrix Composites Under Tensile Loading: An Experimental, Analytical, and Finite Element Study

    Science.gov (United States)

    Haque, A.; Ahmed, L.; Ware, T.; Jeelani, S.; Verrilli, Michael J. (Technical Monitor)

    2001-01-01

    The stress concentrations associated with circular notches and subjected to uniform tensile loading in woven ceramic matrix composites (CMCs) have been investigated for high-efficient turbine engine applications. The CMC's were composed of Nicalon silicon carbide woven fabric in SiNC matrix manufactured through polymer impregnation process (PIP). Several combinations of hole diameter/plate width ratios and ply orientations were considered in this study. In the first part, the stress concentrations were calculated measuring strain distributions surrounding the hole using strain gages at different locations of the specimens during the initial portion of the stress-strain curve before any microdamage developed. The stress concentration was also calculated analytically using Lekhnitskii's solution for orthotropic plates. A finite-width correction factor for anisotropic and orthotropic composite plate was considered. The stress distributions surrounding the circular hole of a CMC's plate were further studied using finite element analysis. Both solid and shell elements were considered. The experimental results were compared with both the analytical and finite element solutions. Extensive optical and scanning electron microscopic examinations were carried out for identifying the fracture behavior and failure mechanisms of both the notched and notched specimens. The stress concentration factors (SCF) determined by analytical method overpredicted the experimental results. But the numerical solution underpredicted the experimental SCF. Stress concentration factors are shown to increase with enlarged hole size and the effects of ply orientations on stress concentration factors are observed to be negligible. In all the cases, the crack initiated at the notch edge and propagated along the width towards the edge of the specimens.

  14. Assessment of the flexural strength of two heat-curing acrylic resins for artificial eyes.

    Science.gov (United States)

    Fernandes, Aline Ursula Rocha; Portugal, Aline; Veloso, Letícia Rocha; Goiato, Marcelo Coelho; Santos, Daniela Micheline dos

    2009-01-01

    Prosthetic eyes are artificial substitutes for the eyeball, made of heat-curing acrylic resin, serving to improve the esthetic appearance of the mutilated patient and his/her inclusion in society. The aim of this study was to assess the flexural strength of two heat-curing acrylic resins used for manufacturing prosthetic eyes. Thirty-six specimens measuring 64 x 10 x 3.3 mm were obtained and divided into four groups: acrylic resin for artificial sclera N1 (Artigos Odontológicos Clássico, São Paulo, SP, Brazil), heat-cure water technique (GI) and microwave-cured (GII); colorless acrylic resin for prosthetic eyes (Artigos Odontológicos Clássico, São Paulo, SP, Brazil), heat-cure water technique (GIII) and microwave-cured (GIV). Mechanical tests using three point loads were performed in a test machine (EMIC, São José dos Pinhais, PR, Brazil). The analysis of variance and the Tukey test were used to identify significant differences (p < 0.01). Groups GII and GIV presented, respectively, the highest (98.70 +/- 11.90 MPa) and lowest means (71.07 +/- 8.93 MPa), with a statistically significant difference. The cure method used for the prosthetic eye resins did not interfere in their flexural strength. It was concluded that all the resins assessed presented sufficient flexural strength values to be recommended for the manufacture of prosthetic eyes. PMID:19893960

  15. Effect of Nanoclay on Thermal Conductivity and Flexural Strength of Polymethyl Methacrylate Acrylic Resin

    Directory of Open Access Journals (Sweden)

    Tahereh Ghaffari

    2016-06-01

    Full Text Available Statement of the Problem: The mechanical and thermal properties of polymethyl methacrylate (PMMA acrylic resin should be improved to counterweigh its structural deficiencies. Purpose: The aim of this study was to compare the flexural strength and thermal conductivity of conventional acrylic resin and acrylic resin loaded with nanoclay. Materials and Method: The methacrylate monomer containing the 0.5, 1 and 2 wt% of nanoclay was placed in an ultrasonic probe and mixed with the PMMA powder. Scanning electron microscopy was used to verify homogeneous distribution of particles. Twenty-four 20×20×200-mm cubic samples were prepared for flexural strength test; 18 samples containing nanoclay and 6 samples for the control group. Another 24 cylindrical samples of 38×25 mm were prepared for thermal conductivity test. One-way ANOVA was used for statistical analysis, followed by multiple-comparison test (Scheffé’s test. Statistical significance was set at p< 0.05. Results: Increasing the concentration of nanoclay incorporated into the acrylic resin samples increased thermal conductivity but decreased flexural strength (p< 0.05. Conclusion: Based on the results of this study, adding nanoclay particles to PMMA improved its thermal conductivity, while it had a negative effect on the flexural strength.

  16. Class I and Class II restorations of resin composite: an FE analysis of the influence of modulus of elasticity on stresses generated by occlusal loading

    DEFF Research Database (Denmark)

    Asmussen, Erik; Peutzfeldt, Anne

    2008-01-01

    OBJECTIVES: It was the aim of the study to analyze by the FE method stresses generated in tooth and restoration by occlusal loading of Class I and Class II restorations of resin composite. On the basis of available information on the influence of the modulus of elasticity, the research hypothesis...... was that the marginal stresses would decrease with increasing modulus of elasticity of the restoration. METHODS: A cylindrical tooth was modelled in enamel and dentin and fitted with a Class I or a Class II restoration of resin composite. In one scenario the restoration was bonded to the tooth, in another...... the restoration was left nonbonded. The resin composite was modelled with a modulus of elasticity of 5, 10, 15 or 20 GPa and loaded occlusally with 100 N. By means of the soft-ware program ABAQUS the von Mises stresses in enamel and dentin were calculated. RESULTS: In the bonded scenario, the maximum stresses...

  17. DEVELOPMENT OF ASME SECTION X CODE RULES FOR HIGH PRESSURE COMPOSITE HYDROGEN PRESSURE VESSELS WITH NON-LOAD SHARING LINERS

    Energy Technology Data Exchange (ETDEWEB)

    Rawls, G.; Newhouse, N.; Rana, M.; Shelley, B.; Gorman, M.

    2010-04-13

    The Boiler and Pressure Vessel Project Team on Hydrogen Tanks was formed in 2004 to develop Code rules to address the various needs that had been identified for the design and construction of up to 15000 psi hydrogen storage vessel. One of these needs was the development of Code rules for high pressure composite vessels with non-load sharing liners for stationary applications. In 2009, ASME approved new Appendix 8, for Section X Code which contains the rules for these vessels. These vessels are designated as Class III vessels with design pressure ranging from 20.7 MPa (3,000 ps)i to 103.4 MPa (15,000 psi) and maximum allowable outside liner diameter of 2.54 m (100 inches). The maximum design life of these vessels is limited to 20 years. Design, fabrication, and examination requirements have been specified, included Acoustic Emission testing at time of manufacture. The Code rules include the design qualification testing of prototype vessels. Qualification includes proof, expansion, burst, cyclic fatigue, creep, flaw, permeability, torque, penetration, and environmental testing.

  18. Design and Optimization of a Composite Canard Control Surface of an Advanced Fighter Aircraft under Static Loading

    Directory of Open Access Journals (Sweden)

    Shrivastava Sachin

    2015-01-01

    Full Text Available The minimization of weight and maximization of payload is an ever challenging design procedure for air vehicles. The present study has been carried out with an objective to redesign control surface of an advanced all-metallic fighter aircraft. In this study, the structure made up of high strength aluminum, titanium and ferrous alloys has been attempted to replace by carbon fiber composite (CFC skin, ribs and stiffeners. This study presents an approach towards development of a methodology for optimization of first-ply failure index (FI in unidirectional fibrous laminates using Genetic-Algorithms (GA under quasi-static loading. The GAs, by the application of its operators like reproduction, cross-over, mutation and elitist strategy, optimize the ply-orientations in laminates so as to have minimum FI of Tsai-Wu first-ply failure criterion. The GA optimization procedure has been implemented in MATLAB and interfaced with commercial software ABAQUS using python scripting. FI calculations have been carried out in ABAQUS with user material subroutine (UMAT. The GA's application gave reasonably well-optimized ply-orientations combination at a faster convergence rate. However, the final optimized sequence of ply-orientations is obtained by tweaking the sequences given by GA's based on industrial practices and experience, whenever needed. The present study of conversion of an all metallic structure to partial CFC structure has led to 12% of weight reduction. Therefore, the approach proposed here motivates designer to use CFC with a confidence.

  19. Acrylic Tanks for Stunning Chemical Demonstrations

    Science.gov (United States)

    Mirholm, Alexander; Ellervik, Ulf

    2009-01-01

    We describe the use of acrylic tanks (400 x 450 x 27 mm) for visualization of chemical demonstrations in aqueous solutions. Examples of well-suited demonstrations are oscillating reactions, pH indicators, photochemical reduction of Lauth's violet, and chemoluminiscent reactions. (Contains 1 figure.)

  20. Study of the damaging mechanisms of a copper / carbon - carbon composite under thermomechanical loading; Etude des mecanismes d'endommagement d'un assemblage cuivre / composite carbone - carbone sous chargement thermomecanique

    Energy Technology Data Exchange (ETDEWEB)

    Moncel, L

    1999-06-18

    The purpose of this work is to understand and to identify the damaging mechanisms of Carbon-Carbon composite bonded to copper under thermomechanical loading. The study of the composite allowed the development of non-linear models. These ones have been introduced in the finite elements analysis code named CASTEM2000. They have been validated according to a correlation between simulation and mechanical tests on multi-material samples. These tests have also permitted us to better understand the behaviour of the bonding between composite and copper (damaging and fracture modes for different temperatures) under shear and tensile loadings. The damaging mechanisms of the bond under thermomechanical loading have been studied and identified according to microscopic observations on mock-ups which have sustained thermal cycling tests: some cracks appear in the composite, near the bond between the composite and the copper. The correlation between numerical and experimental results have been improved because of the reliability of the composite modelization, the use of residual stresses and the results of the bond mechanical characterization. (author)

  1. Study of the damaging mechanisms of a carbon - carbon composite bonded to copper under thermomechanical loading; Etude des mecanismes d'endommagement d'un assemblage cuivre / composite carbone - carbone sous chargement thermomecanique

    Energy Technology Data Exchange (ETDEWEB)

    Moncel, L

    1999-06-15

    The purpose of this work is to understand and to identify the damaging mechanisms of Carbon-Carbon composite bonded to copper under thermomechanical loading. The study of the composite allowed the development of non-linear models. These ones have been introduced in the finite elements analysis code named CASTEM 2000. They have been validated according to a correlation between simulation and mechanical tests on multi-material samples. These tests have also permitted us to better understand the behaviour of the bonding between composite and copper (damaging and fracture modes for different temperatures) under shear and tensile loadings. The damaging mechanisms of the bond under thermomechanical loading have been studied and identified according to microscopic observations on mock-ups which have sustained thermal cycling tests: some cracks appear in the composite, near the bond between the composite and the copper. The correlation between numerical and experimental results have been improved because of the reliability of the composite modelization, the use of residual stresses and the results of the bond mechanical characterisation. (author)

  2. Poly(dimethyl siloxane) (PDMS) network blends of amphiphilic acrylic copolymers with poly(ethylene glycol)-fluoroalkyl side chains for fouling-release coatings. II. Laboratory assays and field immersion trials.

    Science.gov (United States)

    Martinelli, Elisa; Sarvothaman, Mahesh K; Galli, Giancarlo; Pettitt, Michala E; Callow, Maureen E; Callow, James A; Conlan, Sheelagh L; Clare, Anthony S; Sugiharto, Albert B; Davies, Cait; Williams, David

    2012-01-01

    Amphiphilic copolymers containing different amounts of poly(ethylene glycol)-fluoroalkyl acrylate and polysiloxane methacrylate units were blended with a poly(dimethyl siloxane) (PDMS) matrix in different proportions to investigate the effect of both copolymer composition and loading on the biological performance of the coatings. Laboratory bioassays revealed optimal compositions for the release of sporelings of Ulva linza, and the settlement of cypris larvae of Balanus amphitrite. The best-performing coatings were subjected to field immersion tests. Experimental coatings containing copolymer showed significantly reduced levels of hard fouling compared to the control coatings (PDMS without copolymer), their performance being equivalent to a coating based on Intersleek 700™. XPS analysis showed that only small amounts of fluorine at the coating surface were sufficient for good antifouling/fouling-release properties. AFM analyses of coatings under immersion showed that the presence of a regular surface structure with nanosized domains correlated with biological performance.

  3. Large Acrylic Spherical Windows In Hyperbaric Underwater Photography

    Science.gov (United States)

    Lones, Joe J.; Stachiw, Jerry D.

    1983-10-01

    Both acrylic plastic and glass are common materials for hyperbaric optical windows. Although glass continues to be used occasionally for small windows, virtually all large viewports are made of acrylic. It is easy to uderstand the wide use of acrylic when comparing design properties of this plastic with those of glass, and glass windows are relatively more difficult to fabricate and use. in addition there are published guides for the design and fabrication of acrylic windows to be used in the hyperbaric environment of hydrospace. Although these procedures for fabricating the acrylic windows are somewhat involved, the results are extremely reliable. Acrylic viewports are now fabricated to very large sizes for manned observation or optical quality instrumen tation as illustrated by the numerous acrylic submersible vehicle hulls for hu, an occupancy currently in operation and a 3600 large optical window recently developed for the Walt Disney Circle Vision under-water camera housing.

  4. A novel approach to predict the pin load distribution of multiple bolt-jointed composite laminate based on the circuit model

    Science.gov (United States)

    Yang, Xiankun; Chen, Haoyuan; Cheng, Linan; Zheng, Xitao

    2012-04-01

    The circuit model was applied to predict the pin load distribution of composite multiple bolt-joint structure. The load, flexibility and deformation of the mechanics model were equivalent to the current, resistance and voltage of the circuit model, respectively. Based on the above assumption, it could be found that the Hooke's law and the deformation compatibility equation in the origin mechanics model transformed into the Ohm's law and the voltage balance equation in the new circuit model. This approach translated the complex model of composite multiple bolt-jointed into a simple circuit model which consisted of some series circuits and parallel circuits. The analysis of the new circuit model had formed n-1 independence voltage balance equations and a current balance equation, thus, the current and load of each bolt could be calculated. In the new model, power sources which were added as required in some branch circuits could also simulate the clearance or interference in the origin model. Compared with the result of the multiple bolt-joints composite laminate test, the new approach could make an excellent performance to estimate the load distribution.

  5. Load sensor

    OpenAIRE

    van den Ende, D.; Almeida, P.M.R.; Dingemans, T.J.; Van der Zwaag, S.

    2007-01-01

    The invention relates to a load sensor comprising a polymer matrix and a piezo-ceramic material such as PZT, em not bedded in the polymer matrix, which together form a compos not ite, wherein the polymer matrix is a liquid crystalline resin, and wherein the piezo-ceramic material is a PZT powder forming 30-60% by volume of the composite, and wherein the PZT powder forms 40-50% by volume of the composite.

  6. How the Impacts of N Loading on Resource Limitation, Functional Composition of Plankton, and Net Primary Production Influence Nitrate Uptake and Trophic Transfer in Lake Ecosystems

    Science.gov (United States)

    Ballantyne, F.; Mellard, J.

    2015-12-01

    Nitrogen (N) loading in aquatic ecosystems can have a multitude of effects. Increased N availability often elevates primary production, but typically also alters community composition and trophic structure. How all the myriad impacts of N loading conspire to produce whole ecosystem responses to perturbation is not well understood. To characterize how whole ecosystems response to perturbation along a gradient of N loading, we added nitrate (and phosphate) to large in situ aquatic mesocosms at different rates over the course of three months and quantified biomass distributions across multiple size classes, plankton community composition (including functional traits), and N flow among size classes in both the epilimnion and the hypolimnion prior and subsequent to a one week shading perturbation. Increased N loading resulted in greater rates of light attenuation with depth, which in turn selected for species with higher tolerance to light limitation and low inorganic C availability, but also resulted in increased rates of primary production and top-down grazing pressure. Different degrees of N loading resulted in different rates of nitrate uptake and trophic transfer, as calculated from 15N pulse-chase additions, both prior and subsequent to the shading pertubation, with the loading effect diminished after the perturbation. N loading was positively associated with the rate of N transfer between the epilimnion, where the N was added, and the hypolimnion. A complex picture of whole ecosystem response to perturbation along a gradient of N loading emerges. N loading appears to simplify resource competition among phytoplankton by alleviating N limitation to an extent, and at the same time supports elevated production across trophic levels. Nitrate uptake rate is contingent on standing stock phytoplankton biomass and resource limitation status. Rates of nitrate removal from the water column depend on how N loading alters the abiotic environment (primarily light availability

  7. Electromagnetic and microwave absorbing properties of carbonyl iron/BaTiO{sub 3} composite absorber for matched load of isolator

    Energy Technology Data Exchange (ETDEWEB)

    Ren, Xiaohu [Southwest Institute of Applied Magnetics, Mianyang 621000 (China); Cheng, Yankui [Department of Manufacturing Engineering, Yibin Vocational and Technical College, Yibin 644003 (China)

    2015-11-01

    Composite absorbers made from carbonyl iron powder and BaTiO{sub 3} were prepared by blending technique with the matrix of epoxy resin. The structure and microtopography of the carbonyl iron and BaTiO{sub 3} particles were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The microstructure and electromagnetic properties of the as-prepared composites were investigated by SEM and vector network analyzer (VNA). The effect of the mass ratio of BaTiO{sub 3}/carbonyl iron on the electromagnetic properties of the composites is investigated. The bandwidth with an absorption loss exceeding 30 dB is obtained in the whole measured frequency range for all composites, and an optimal reflection loss drop below 1.5 dB with 24 wt% BaTiO{sub 3}. It is found that the carbonyl iron/BaTiO{sub 3} composite absorber can be a promising candidate as a matched load for the isolator. - Highlights: • Composite absorbers made from carbonyl iron powder and BaTiO3 were prepared by blending technique with the matrix of epoxy resin. • The microwave absorption properties of composites were measured by stripline method. • The bandwidth with an absorption loss exceeding 30 dB is obtained in the whole measured frequency range for all composites, and an optimal reflection loss drop below 1.5 dB with 24 wt% BaTiO{sub 3}. • It is found that the carbonyl iron/BaTiO{sub 3} composite absorber can be a promising candidate as a matched load for the isolator.

  8. Analytical Modelling of Transverse Matrix Cracking of [plus or minus Theta/90(sub n)](sub s) Composite Laminates Under Multiaxial Loading

    Science.gov (United States)

    Mayugo, J A.; Camanho, P. P.; Maimi, P.; Davila, C. G.

    2010-01-01

    An analytical model based on the analysis of a cracked unit cell of a composite laminate subjected to multiaxial loads is proposed to predict the onset and accumulation of transverse matrix cracks in the 90(sub n) plies of uniformly stressed [plus or minus Theta/90(sub n)](sub s) laminates. The model predicts the effect of matrix cracks on the stiffness of the laminate, as well as the ultimate failure of the laminate, and it accounts for the effect of the ply thickness on the ply strength. Several examples describing the predictions of laminate response, from damage onset up to final failure under both uniaxial and multiaxial loads, are presented.

  9. Reciprocating Wear Behaviour of 7075Al/SiC and 6061Al/Al2O3 Composites: A study of Effect of Reinforcement, Stroke and Load

    OpenAIRE

    J. Lakshmipathy; B. Kulendran

    2014-01-01

    The wear behaviour comparison of Al/SiC and Al/Al2O3 composites prepared by stir casting technique is investigated to find out the effects of weight percentage of SiC/Al2O3, load and the number of strokes on a reciprocating wear testing machine. The MMC pins are prepared with different weight percentage of SiC and Al2O3 (10, 15 and 20 %). The tests are carried out with different load conditions (25, 50 and 75 N) and different number of strokes (420,780 and 1605 strokes). Wear surfaces of test...

  10. METHACRYLATE AND ACRYLATE ALLERGY IN DENTAL STUDENTS.

    Directory of Open Access Journals (Sweden)

    Maya Lyapina

    2013-09-01

    Full Text Available A multitude of acrylic monomers is used in dentistry, and when dental personnel, patients or students of dental medicine become sensitized, it is of great importance to identify the dental ;acrylic preparations to which the sensitized individual can be exposed. Numerous studies confirm high incidence of sensitization to (meth acrylates in dentatal professionals, as well as in patients undergoing dental treatment and exposed to resin-based materials. Quite a few studies are available aiming to evaluate the incidence of sensitization in students of dental medicineThe purpose of the study is to evaluate the incidence of contact sensitization to some (meth acrylates in students of dental medicine at the time of their education, in dental professionals (dentists, nurses and attendants and in patients, the manifestation of co-reactivity.A total of 139 participants were included in the study, divided into four groups: occupationally exposed to (methacrylates and acrylic monomers dental professionals, 3-4 year-of-education students of dental medicine, 6th year–of-education students of dental medicine and patients with suspected or established sensitization to acrylates, without occupational exposure. All of them were patch-tested with methyl methacrylate (MMA, triethyleneglycol dimethacrylate (TREGDMA, ethyleneglycol dimethacrylate (EGDMA, 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy phenyl]propane (bis-GMA, 2-hydroxyethyl methacrylate (2-HEMA, and tetrahidrofurfuril metacrylate. The overall sensitization rates to methacrylates in the studied population are comparative high – from 25.9% for MMA to 31.7% for TREGDMA. Significantly higher incidence of sensitization in the group of 3-4 course students compared to the one in the group of dental professionals for MMA and TREGDMA was observed. Highest was the incidence of sensitization to ethyleneglycol dimethacrylate, BIS-GMA, 2-HEMA and tetrahydrofurfuryl methacrylate in the group of patients, with

  11. Effects of load ratio, R, and test temperature on high cycle fatigue behavior of nano-structured Al-4Y-4Ni-X alloy composites

    Energy Technology Data Exchange (ETDEWEB)

    El-Shabasy, Adel B., E-mail: ashabasy@hotmail.com [Department of Design and Production Engineering, Faculty of Engineering, Ain Shams University, Cairo 11517 (Egypt); Hassan, Hala A. [Department of Design and Production Engineering, Faculty of Engineering, Ain Shams University, Cairo 11517 (Egypt); Lewandowski, John J. [Department of Material' s Science and Engineering, Case Western Reserve University, Cleveland, OH 44106 (United States)

    2012-12-15

    Nanostructured Al-4Y-4Ni-X composites created by extruding atomized amorphous powders at different extrusion ratios were tested under high cycle bending fatigue at load ratios, R=0.1, 0.33 and -1 at room temperature, 149 Degree-Sign C and 260 Degree-Sign C. Increasing the extrusion ratio generally improved the fatigue life and the fatigue limits were well in excess of that obtained on conventional aluminum alloys at all temperatures tested. The fatigue limits obtained in this work were also compared to previously reported values for a nanostructured composite Al-Gd-Ni-Fe alloy produced via similar means.

  12. Mechanics, degradability, bioactivity, in vitro, and in vivo biocompatibility evaluation of poly(amino acid)/hydroxyapatite/calcium sulfate composite for potential load-bearing bone repair.

    Science.gov (United States)

    Fan, Xiaoxia; Ren, Haohao; Luo, Xiaoman; Wang, Peng; Lv, Guoyu; Yuan, Huipin; Li, Hong; Yan, Yonggang

    2016-03-01

    A ternary composite of poly(amino acid), hydroxyapatite, and calcium sulfate (PAA/HA/CS) was prepared using in situ melting polycondensation method and evaluated in terms of mechanical strengths, in vitro degradability, bioactivity, as well as in vitro and in vivo biocompatibility. The results showed that the ternary composite exhibited a compressive strength of 147 MPa, a bending strength of 121 MPa, a tensile strength of 122 MPa, and a tensile modulus of 4.6 GPa. After immersion in simulated body fluid, the compressive strength of the composite decreased from 147 to 98 MPa for six weeks and the bending strength decreased from 121 to 75 MPa for eight weeks, and both of them kept stable in the following soaking period. The composite could be slowly degraded with 7.27 wt% loss of initial weight after soaking in phosphate buffered solution for three weeks when started to keep stable weight in the following days. The composite was soaked in simulated body fluid solution and the hydroxyapatite layer, as flower-like granules, formed on the surface of the composite samples, showing good bioactivity. Moreover, it was found that the composite could promote proliferation of MG-63 cells, and the cells with normal phenotype extended and spread well on the composite surface. The implantation of the composite into the ulna of sheep confirmed that the composite was biocompatible and osteoconductive in vivo, and offered the PAA/HA/CS composite promising material for load-bearing bone substitutes for clinical application.

  13. Loading Effect of Aluminum Hydroxide onto the Mechanical, Thermal Conductivity, Acoustical and Burning Properties of the Palm-based Polyurethane Composites

    International Nuclear Information System (INIS)

    Effects of aluminium hydroxide (ATH) addition on the properties of palm-based polyurethane composites were investigated. The hybrid composites were prepared by mixing 10 wt % of oil palm empty fruit bunch fiber (EFB) with ATH at varying amount of 2, 4 and 6 wt % of the overall mass of the resin. The compression stress and modulus gave the highest values of 575 and 2301 kPa, respectively at 2 wt % loading of ATH. The compression stress and modulus decreased drastically at 4 wt % (431 kPa and 1659 kPa, respectively) and further decreased at 6 wt % ATH (339 and 1468 kPa, respectively). However, the burning rate is inversely proportional to the loading percentage where the highest burning rate was observed at 2 wt % ATH. Sound absorption analysis indicated a large absorption coefficient at high frequency (4000 Hz) for all samples. The highest absorption coefficient was obtained from PU-EFB/ ATH with 4 wt % ATH. (author)

  14. Preparation and Application of Crosslinked Poly(sodium acrylate-Coated Magnetite Nanoparticles as Corrosion Inhibitors for Carbon Steel Alloy

    Directory of Open Access Journals (Sweden)

    Ayman M. Atta

    2015-01-01

    Full Text Available This work presents a new method to prepare poly(sodium acrylate magnetite composite nanoparticles. Core/shell type magnetite nanocomposites were synthesized using sodium acrylate as monomer and N,N-methylenebisacrylamide (MBA as crosslinker. Microemulsion polymerization was used for constructing core/shell structures with magnetite nanoparticles as core and poly(sodium acrylate as shell. Fourier transform infrared spectroscopy (FTIR was employed to characterize the nanocomposite chemical structure. Transmittance electron microscopy (TEM was used to examine the morphology of the modified poly(sodium acrylate magnetite composite nanoparticles. These particle will be evaluated for effective anticorrosion behavior as a hydrophobic surface on stainless steel. The composite nanoparticles has been designed by dispersing nanocomposites which act as a corrosion inhibitor. The inhibition effect of AA-Na/magnetite composites on steel corrosion in 1 M HCl solution was investigated using potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS. Polarization measurements indicated that the studied inhibitor acts as mixed type corrosion inhibitor. EIS spectra exhibit one capacitive loop. The different techniques confirmed that the inhibition efficiency reaches 99% at 50 ppm concentration. This study has led to a better understanding of active anticorrosive magnetite nanoparticles with embedded nanocomposites and the factors influencing their anticorrosion performance.

  15. Preparation and application of crosslinked poly(sodium acrylate)--coated magnetite nanoparticles as corrosion inhibitors for carbon steel alloy.

    Science.gov (United States)

    Atta, Ayman M; El-Mahdy, Gamal A; Al-Lohedan, Hamad A; El-Saeed, Ashraf M

    2015-01-14

    This work presents a new method to prepare poly(sodium acrylate) magnetite composite nanoparticles. Core/shell type magnetite nanocomposites were synthesized using sodium acrylate as monomer and N,N-methylenebisacrylamide (MBA) as crosslinker. Microemulsion polymerization was used for constructing core/shell structures with magnetite nanoparticles as core and poly(sodium acrylate) as shell. Fourier transform infrared spectroscopy (FTIR) was employed to characterize the nanocomposite chemical structure. Transmittance electron microscopy (TEM) was used to examine the morphology of the modified poly(sodium acrylate) magnetite composite nanoparticles. These particle will be evaluated for effective anticorrosion behavior as a hydrophobic surface on stainless steel. The composite nanoparticles has been designed by dispersing nanocomposites which act as a corrosion inhibitor. The inhibition effect of AA-Na/magnetite composites on steel corrosion in 1 M HCl solution was investigated using potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS). Polarization measurements indicated that the studied inhibitor acts as mixed type corrosion inhibitor. EIS spectra exhibit one capacitive loop. The different techniques confirmed that the inhibition efficiency reaches 99% at 50 ppm concentration. This study has led to a better understanding of active anticorrosive magnetite nanoparticles with embedded nanocomposites and the factors influencing their anticorrosion performance.

  16. The impacts of aerosol loading, composition, and water uptake on aerosol extinction variability in the Baltimore–Washington, D.C. region

    OpenAIRE

    A. J. Beyersdorf; L. D. Ziemba; G. Chen; C. A. Corr; J. H. Crawford; G. S. Diskin; Moore, R H; K. L. Thornhill; E. L. Winstead; Anderson, B E

    2016-01-01

    In order to utilize satellite-based aerosol measurements for the determination of air quality, the relationship between aerosol optical properties (wavelength-dependent, column-integrated extinction measured by satellites) and mass measurements of aerosol loading (PM2.5 used for air quality monitoring) must be understood. This connection varies with many factors including those specific to the aerosol type – such as composition, size, and hygroscopicity – and to the surround...

  17. Acrylic Bone Cements Modified with Starch

    OpenAIRE

    Krilova, V; Vītiņš, V

    2010-01-01

    The successful result of restorative and replacement surgical operation depends significantly on properties of used bone cement. Acrylic bone cements are usually based on methylmethacrylate polymer, while monomer polymerization begins after mixing of components in mixing device and terminates in living tissue. Polymerization of methylmethacrylate is exothermic process, and temperature increase might cause tissue necrosis with concomitant implant aseptic loosening. Developed non-ionogenic and ...

  18. Measurement of large deformation of nylon cord-rubber composite and effects of perpendicular loads on its stress-strain behaviors

    Institute of Scientific and Technical Information of China (English)

    张丰发; 杜星文; 于增信

    2003-01-01

    Effects of transverse loads on longitudinal stress-strain behaviors and longitudinal constant tensile loads on transverse stress-strain behaviors of single ply of nylon cord-rubber composite are studied respectively under biaxial tensile condition with cruciform specimen. Effects of transverse constant tensile load on longitudinal tensile mechanical properties are indistinctive compared with corresponding uniaxial longitudinal tensile mechanical properties. It can be relative to larger difference between longitudinal and transverse mechanical properties. Its dominating failure mode is typical fiber-dominated mode; However, Experiment results indicate that transverse mechanical properties of nylon cord-rubber composite with longitudinal constant tensile loads are distinct from its uniaxial transverse tensile mechanical properties. It can be attribute to action of longitudinal tension that makes material rigidify in the direction perpendicular to fiber, Mode of failure is representative of matrix-dominated failure. For the measurement of large deformation up to 50 percent, a special CCD imaging method is employed in the experimental investigation that makes measurement of large deformations more precise.

  19. Enhanced loading efficiency and sustained release of doxorubicin from hyaluronic acid/graphene oxide composite hydrogels by a mussel-inspired catecholamine.

    Science.gov (United States)

    Byun, Eunkyoung; Lee, Haeshin

    2014-10-01

    Hydrogels have been widely investigated as depots and carriers for drug delivery. For example, hydrogels have been successfully used to encapsulate a variety of pharmaceuticals, such as peptides and proteins. Recently, carbon material/hydrogel hybrid systems have been of interest as new hydrogel systems because of the attractiveness of structural reinforcement for biomedical applications. In particular, graphene and graphene oxide (GO) have been recognized as novel biomaterials with unique physical, electrical, and thermal properties. Among the various applications of these materials, many research groups are intensively exploring the biomedical applications of graphene and GO. In this study, we propose a new role for GO in hybrid hydrogels, with the inclusion of GO in the gel network resulting in a nearly 90% enhancement in the loading of small, hydrophobic drugs (e.g., doxorubicin, Dox) compared to the hydrogel without encapsulated GO. The hydrogels were prepared from hyaluronic acid (HA), with a mussel-inspired crosslinking chemistry used to prepare the HA hydrogels. Dox was then loaded into the hydrogels. The HA/GO composite hydrogel not only enhanced the loading amount but also exhibited long-lasting anticancer activity over 10 days. We believe that these graphene oxide-containing composite hydrogels can solve one of the challenges in the application of hydrogels by improving the loading efficiency of small-molecule drugs. PMID:25942800

  20. The Effects of Bud Load and Applied Water Amounts on the Biochemical Composition of the ‘Narince’ Grape Variety (Vitis vinifera L.

    Directory of Open Access Journals (Sweden)

    Serpil GOK TANGOLAR

    2015-12-01

    Full Text Available This study evaluated the effects of various bud load and water amounts (WA on the berry composition of the ‘Narince’ white wine grape variety. Two water amounts (WA-I and WA-II administered during growth stages or a non-irrigated (rain-fed control treatment were paired with two different bud loads (K (normal and 2K (two-fold buds to assess their effects on sugar, organic acid and  phenolic compound contents, as well as antioxidant capacity of the berries for a white wine grape variety ‘Narince’. Despite a slight decrease observed only in sugars in the second year, increases in all phenolic compounds examined (especially in catechin and epicatechin were detected in the WA-I application. The total phenolic compound values obtained for 2K in the same application was also high. The antioxidant capacity values were not significantly affected by the irrigation or bud load applications. Therefore, a 2K bud load with WA-I treatments in which 50% and 75% of the cumulative evaporation from the Class A pan during berry set to veraison and veraison to ripening, respectively, are recommended for irrigation in high plateau viticulture. By maintaining or increasing the fruit composition of ‘Narince’ grapes, these treatments can optimize grape yield and the earnings of growers. In all applications, glucose (among the sugars, tartaric acid (among the organic acids, and catechin and epicatechin (among the phenolic compounds were higher than their counterparts.