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Sample records for absorption edge detector

  1. CFAR Edge Detector for Polarimetric SAR Images

    DEFF Research Database (Denmark)

    Schou, Jesper; Skriver, Henning; Nielsen, Allan Aasbjerg;

    2003-01-01

    Finding the edges between different regions in an image is one of the fundamental steps of image analysis, and several edge detectors suitable for the special statistics of synthetic aperture radar (SAR) intensity images have previously been developed. In this paper, a new edge detector...

  2. Evaluation of edge detectors using avarage risk

    OpenAIRE

    Spreeuwers, L.J.; Heijden, van der, RW Rob

    1992-01-01

    A new method for evaluation of edge detectors, based on the average risk of a decision, is discussed. The average risk is a performance measure well-known in Bayesian decision theory. Since edge detection can be regarded as a compound decision making process, the performance of an edge detector is context dependent. Therefore, the application of average risk to edge detection is non-trivial. The paper describes a method to estimate the probabilities on a number of different types of (context ...

  3. Development of planar detectors with active edge

    Energy Technology Data Exchange (ETDEWEB)

    Povoli, M., E-mail: povoli@disi.unitn.it [Dipartimento di Ingegneria e Scienza dell' Informazione, Universita di Trento, Via Sommarive, 14, I-38123 Povo di Trento (Italy); INFN, Sezione di Padova (Gruppo Collegato di Trento) (Italy); Bagolini, A.; Boscardin, M. [Fondazione Bruno Kessler, Centro per i Materiali e i Microsistemi (FBK-CMM), Via Sommarive, 18, I-38123 Povo di Trento (Italy); Dalla Betta, G.-F. [Dipartimento di Ingegneria e Scienza dell' Informazione, Universita di Trento, Via Sommarive, 14, I-38123 Povo di Trento (Italy); INFN, Sezione di Padova (Gruppo Collegato di Trento) (Italy); Giacomini, G.; Vianello, E.; Zorzi, N. [Fondazione Bruno Kessler, Centro per i Materiali e i Microsistemi (FBK-CMM), Via Sommarive, 18, I-38123 Povo di Trento (Italy)

    2011-12-01

    We report on the first batch of planar active edge sensors fabricated at Fondazione Bruno Kessler (Trento, Italy) on the way to the development of full 3D detectors with active edges. The main design and technological aspects are reported, along with selected results from the electrical characterization of detectors and test structures.

  4. Polarimetric Edge Detector Based on the Complex Wishart Distribution

    DEFF Research Database (Denmark)

    Skriver, Henning; Schou, Jesper; Nielsen, Allan Aasbjerg

    2001-01-01

    A new edge detector for polarimetric SAR data has been developed. The edge detector is based on a newly developed test statistic for equality of two complex covariance matrices following the complex Wishart distribution and an associated asymptotic probability for the test statistic. The new...... polarimetric edge detector provides a constant false alarm rate and it utilizes the full polarimetric information. The edge detector has been applied to polarimetric SAR data from the Danish dual-frequency, airborne polarimetric SAR, EMISAR. The results show clearly an improved edge detection performance...

  5. Three Dimensional Digital Image Processing using Edge Detectors

    Directory of Open Access Journals (Sweden)

    John Schmeelk

    2005-11-01

    Full Text Available This paper provides an introduction to three dimensional image edge detection and its relationship to partial derivatives, convolutions and wavelets. We are especially addressing the notion of edge detection because it has far reaching applications in all areas of research to include medical research. A patient can be diagnosed as having an aneurysm by studying an angiogram. An angiogram is the visual view of the blood vessels whereby the edges are highlighted through the implementation of edge detectors. This process is completed through convolution, wavelets and matrix techniques. Some illustrations included will be vertical, horizontal, Sobel and wavelet edge detectors.

  6. Image Steganography using Hybrid Edge Detector and Ridgelet Transform

    OpenAIRE

    S.UMA MAHESWARI; D. Jude Hemanth

    2015-01-01

    Steganography is the art of hiding high sensitive information in digital image, text, video, and audio. In this paper, authors have proposed a frequency domain steganography method operating in the Ridgelet transform. Authors engage the advantage of ridgelet transform, which represents the digital image with straight edges. In the embedding phase, the proposed hybrid edge detector acts as a preprocessing step to obtain the edge image from the cover image, then the edge image is partitioned in...

  7. Performance Analysis of Two CFAR Detectors in Clutter Edge Situation

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    This paper studies the performance of the GOSGO and GOSSO CFAR detectors [1] in clutter edge situation. The authors derive the analytic expressions of the false alarm probabilities in that situation, analyze their performances against clutter edge, and compare them with the OS, CA, GO and SO detectors. The results show that GOSGO possesses better performance than GO for countering clutter, but the performance of GOSSO is very unideal.

  8. Virtual edge illumination and one dimensional beam tracking for absorption, refraction, and scattering retrieval

    Energy Technology Data Exchange (ETDEWEB)

    Vittoria, Fabio A., E-mail: fabio.vittoria.12@ucl.ac.uk; Diemoz, Paul C. [Department of Medical Physics and Bioengineering, University College London, Malet Place, Gower Street, London WC1E 6BT (United Kingdom); Research Complex at Harwell, Harwell Oxford Campus, OX11 0FA Didcot (United Kingdom); Endrizzi, Marco; Olivo, Alessandro [Department of Medical Physics and Bioengineering, University College London, Malet Place, Gower Street, London WC1E 6BT (United Kingdom); Wagner, Ulrich H.; Rau, Christoph [Diamond Light Source, Harwell Oxford Campus, OX11 0DE Didcot (United Kingdom); Robinson, Ian K. [Research Complex at Harwell, Harwell Oxford Campus, OX11 0FA Didcot (United Kingdom); London Centre for Nanotechnology, WC1H 0AH London (United Kingdom)

    2014-03-31

    We propose two different approaches to retrieve x-ray absorption, refraction, and scattering signals using a one dimensional scan and a high resolution detector. The first method can be easily implemented in existing procedures developed for edge illumination to retrieve absorption and refraction signals, giving comparable image quality while reducing exposure time and delivered dose. The second method tracks the variations of the beam intensity profile on the detector through a multi-Gaussian interpolation, allowing the additional retrieval of the scattering signal.

  9. Edge detector tolerant to object defocusing

    Science.gov (United States)

    Mazzaferri, Javier; Campos, Juan; Escalera, Juan C.; Sheppard, Colin J. R.; Ledesma, Silvia

    2010-10-01

    Different methods for edge extraction have been studied in the past years. In a recent paper we have presented a rotation-invariant edge extractor based on a spiral phase filter placed in the frequency plane of a convergent correlator. In this architecture, the axial position of the output plane strongly depends on the axial position of the object. This condition limits the processing of three dimensional objects, because only a narrow axial region of the object would be correctly imaged to the output. The other axial regions of the target yield defocused results. Likewise, a rather small axial misalignment of planar scenes could produce completely inaccurate correlations. Besides, annular pupils have been widely used to regulate the depth of focus (DOF) and the transversal resolution of optical systems. In this paper we present a novel filter that combines the advantages of a spiral phase-based edge extractor and those of an axial-apodizing annular pupil. This design allows edge extraction of objects in a widened axial range. Numerical simulations and experimental results that demonstrate edge extraction with improved tolerance to defocusing are presented.

  10. A Review of Classic Edge Detectors

    Directory of Open Access Journals (Sweden)

    Haldo Spontón

    2015-06-01

    Full Text Available In this paper some of the classic alternatives for edge detection in digital images are studied. The main idea behind edge detection is to find where abrupt changes in the intensity of an image have occurred. The first family of algorithms reviewed in this work uses the first derivative to find the changes of intensity, such as Sobel, Prewitt and Roberts. In the second reviewed family it is used second derivative, for example in algorithms like Marr-Hildreth and Haralick. Results obtained from a qualitative point of view (perceptual and from a quantitative point of view (number of operations, execution time are compared, considering different ways to convolve an image with a kernel (step required in some of the algorithms.

  11. Investigation of cutting edge in edge-on silicon microstrip detector

    Energy Technology Data Exchange (ETDEWEB)

    Vrtacnik, D., E-mail: Danilo.Vrtacnik@fe.uni-lj.s [Faculty of Electrical Engineering, University of Ljubljana (Slovenia); Resnik, D.; Mozek, M.; Pecar, B.; Amon, S. [Faculty of Electrical Engineering, University of Ljubljana (Slovenia)

    2010-08-21

    Investigation of cutting edge properties in edge-on silicon microstrip detector has been performed. An advanced approach for reducing dead layer thickness has been introduced. It consists of standard wafer sawing through entire wafer thickness, followed by dry chemical etching and thin layer passivation of the cutting surface. Proposed approach is developed in such a way that no additional photolithographic process steps and critical handling with individual chips are needed after detector fabrication. Results presented in the paper show that this approach results in effective reduction of cutting edge thickness down to 50 {mu}m. Such reduction of dead layer thickness, together with applied efficient current termination technique resulted in substantial improvement of detector structure performance. By described optimization of detector dead layer thickness, detection efficiency has been improved up to 15%.

  12. Using quantum filters as edge detectors in infrared images

    Science.gov (United States)

    Bolaños Marín, Daniela

    2014-06-01

    Some new filters inspired in quantum models are used as edge detectors in infrared images. In this case, Bessel, Hermite and Morse filters will be applied to detect edges and fibrillar structures in infrared images. The edge detectors will be built by the Laplacian of the mentioned quantum filters. Furthermore, using curvature operators, curvature detectors and amplifiers of contrast will be constructed to analyze infrared images. The quantum filter prototyping will be done using computer algebra software, specifically Maple and its package, ImageTools. The quantum filters will be applied to infrared images using the technique of convolutions and blurred derivatives. It is expected that designed quantum filters will be useful for analysis and processing of infrared images. As future investigations, we propose to design plugins with the quantum filters that can be incorporated into the program ImageJ, which will facilitate the use of the quantum filters for the infrared image processing.

  13. Simultaneous x-ray fluorescence and K-edge CT imaging with photon-counting detectors

    Science.gov (United States)

    Li, Liang; Li, Ruizhe; Zhang, Siyuan; Chen, Zhiqiang

    2016-10-01

    Rapid development of the X-ray phonon-counting detection technology brings tremendous research and application opportunities. In addition to improvements in conventional X-ray imaging performance such as radiation dose utilization and beam hardening correction, photon-counting detectors allows significantly more efficient X-ray fluorescence (XRF) and K-edge imaging, and promises a great potential of X-ray functional, cellular and molecular imaging. XRF is the characteristic emission of secondary X-ray photons from a material excited by initial X-rays. The phenomenon is widely used for chemical and elemental analysis. K-edge imaging identifies a material based on its chemically-specific absorption discontinuity over X-ray photon energy. In this paper, we try to combine XRF and K-edge signals from the contrast agents (e.g., iodine, gadolinium, gold nanoparticles) to simultaneously realize XFCT and K-edge CT imaging for superior image performance. As a prerequisite for this dual-modality imaging, the accurate energy calibration of multi-energy-bin photon-counting detectors is critically important. With the measured XRF data of different materials, we characterize the energy response function of a CZT detector for energy calibration and spectrum reconstruction, which can effectively improve the energy resolution and decrease the inconsistence of the photon counting detectors. Then, a simultaneous K-edge and X-ray fluorescence CT imaging (SKYFI) experimental setup is designed which includes a cone-beam X-ray tube, two separate photon counting detector arrays, a pin-hole collimator and a rotation stage. With a phantom containing gold nanoparticles the two types of XFCT and K-edge CT datasets are collected simultaneously. Then, XFCT and K-edge CT images are synergistically reconstructed in a same framework. Simulation results are presented and quantitative analyzed and compared with the separate XFCT and K-edge CT results.

  14. Image Steganography using Hybrid Edge Detector and Ridgelet Transform

    Directory of Open Access Journals (Sweden)

    S. Uma Maheswari

    2015-05-01

    Full Text Available Steganography is the art of hiding high sensitive information in digital image, text, video, and audio. In this paper, authors have proposed a frequency domain steganography method operating in the Ridgelet transform. Authors engage the advantage of ridgelet transform, which represents the digital image with straight edges. In the embedding phase, the proposed hybrid edge detector acts as a preprocessing step to obtain the edge image from the cover image, then the edge image is partitioned into several blocks to operate with straight edges and Ridgelet transform is applied to each block. Then, the most significant gradient vectors (or significant edges are selected to embed the secret data. The proposed method has shown the advantages of imperceptibility of the stego image is increased because the secret data is hidden in the significant gradient vector. Authors employed the hybrid edge detector to obtain the edge image, which increases the embedding capacity. Experimental results demonstrates that peak signal-to-noise (PSNR ratio of stego image generated by this method versus the cover image is guaranteed to be above 49 dB. PSNR is much higher than that of all data hiding techniques reported in the literature.Defence Science Journal, Vol. 65, No. 3, May 2015, pp.214-219, DOI: http://dx.doi.org/10.14429/dsj.65.7871

  15. Optimizing edge detectors for robust automatic threshold selection : Coping with edge curvature and noise

    NARCIS (Netherlands)

    Wilkinson, Michael H.F.

    1998-01-01

    The Robust Automatic Threshold Selection algorithm was introduced as a threshold selection based on a simple image statistic. The statistic is an average of the grey levels of the pixels in an image weighted by the response at each pixel of a specific edge detector. Other authors have suggested that

  16. Dual Edge Triggered Phase Detector for DLL and PLL Applications

    Directory of Open Access Journals (Sweden)

    Prasanna Kumar L

    2015-05-01

    Full Text Available An ASIC design of Dual Edge Triggered Phase Detector(DET PD for Delay locked loop(DLL and Phase locked loop(PLL applications is proposed in this paper.The proposed DET PD has high locking speed and less jitter. The designs are based on TSPC flip flop logic, which overcomes the issue of narrow capture range. The Double edge triggered phase detector dissipates less power than conventional designs and can be operated at a frequency range of 250MHz to 1GHz.The proposed DET-PD is designed using 180nm CMOS process technology at a 1.8V supply voltage in cadence virtuoso and circuit simulated in cadence spectre.

  17. A distributed Canny edge detector: algorithm and FPGA implementation.

    Science.gov (United States)

    Xu, Qian; Varadarajan, Srenivas; Chakrabarti, Chaitali; Karam, Lina J

    2014-07-01

    The Canny edge detector is one of the most widely used edge detection algorithms due to its superior performance. Unfortunately, not only is it computationally more intensive as compared with other edge detection algorithms, but it also has a higher latency because it is based on frame-level statistics. In this paper, we propose a mechanism to implement the Canny algorithm at the block level without any loss in edge detection performance compared with the original frame-level Canny algorithm. Directly applying the original Canny algorithm at the block-level leads to excessive edges in smooth regions and to loss of significant edges in high-detailed regions since the original Canny computes the high and low thresholds based on the frame-level statistics. To solve this problem, we present a distributed Canny edge detection algorithm that adaptively computes the edge detection thresholds based on the block type and the local distribution of the gradients in the image block. In addition, the new algorithm uses a nonuniform gradient magnitude histogram to compute block-based hysteresis thresholds. The resulting block-based algorithm has a significantly reduced latency and can be easily integrated with other block-based image codecs. It is capable of supporting fast edge detection of images and videos with high resolutions, including full-HD since the latency is now a function of the block size instead of the frame size. In addition, quantitative conformance evaluations and subjective tests show that the edge detection performance of the proposed algorithm is better than the original frame-based algorithm, especially when noise is present in the images. Finally, this algorithm is implemented using a 32 computing engine architecture and is synthesized on the Xilinx Virtex-5 FPGA. The synthesized architecture takes only 0.721 ms (including the SRAM READ/WRITE time and the computation time) to detect edges of 512 × 512 images in the USC SIPI database when clocked at 100

  18. Absorption-edge transmission technique using Ce- 139 for measurement of stable iodine concentration.

    Science.gov (United States)

    Sorenson, J A

    1979-12-01

    We have investigated a technique for measuring stable iodine concentrations by absorption-edge transmission measurements using a Ce 139 radiation source. The lanthanum daughter emits characteristic x-rays whose energies just bracket the absorption edge of iodine at 33.2 keV. Relative transmission of these x-rays is sensitive to iodine concentration in the sample, but is relatively insensitive to other elements. By applying energy-selective beam filtration, it is possible to determine the relative transmission of these closely spaced x-ray energies with NaI(Tl) detectors. Optimizations of sample thickness, detector thickness, and Ce-139 source activity are discussed. Using sample volumes of about 10 ml, one can determine iodine concentration to an uncertainty (standard deviation) of +/- 5 microgram/ml with a 5-mCi source in a measurement time of 400 sec. Potential clinical applications of the in vitro technique are discussed, along with comparative aspects of the Ce-139 technique and other absorption and fluorescence techniques for measuring stable iodine.

  19. Detection of text in images using SUSAN edge detector

    Institute of Scientific and Technical Information of China (English)

    MAO Wen-ge; ZHANG Tian-wen; WANG Li

    2005-01-01

    Text embedded in images is one of many important cues for indexing and retrieval of images and videos. In the paper, we present a novel method of detecting text aligned either horizontally or vertically, in which a pyramid structure is used to represent an image and the features of the text are extracted using SUSAN edge detector. Text regions at each level of the pyramid are identified according to the autocorrelation analysis. New techniques are introduced to split the text regions into basic ones and merge them into text lines. By evaluating the method on a set of images, we obtain a very good performance of text detection.

  20. The interstellar oxygen-K absorption edge as observed by XMM-Newton

    CERN Document Server

    De Vries, C P; Paerels, F B S; Den Boggende, A J F; Rasmussen, A P

    2003-01-01

    High resolution X-ray spectra of the Reflection Grating Spectrometer (RGS) on board the XMM satellite are used to resolve the oxygen K absorption edge. By combining spectra of low and high extinction sources, the observed absorption edge can be split in the true interstellar (ISM) extinction and the instrumental absorption. The detailed ISM edge structure closely follows the edge structure of neutral oxygen as derived by theoretical R-matrix calculations. However, the position of the theoretical edge requires a wavelength shift. In addition the detailed instrumental RGS absorption edge structure is presented. All results are verified by comparing to a subset of Chandra LETG-HRC observations.

  1. Quantitative investigation of two metallohydrolases by X-ray absorption spectroscopy near-edge spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, W. [Hefei National Laboratory for Physical Sciences at Microscale and School of Life Sciences, University of Science and Technology of China, Hefei, Anhui 230027 (China); Chu, W.S.; Yang, F.F.; Yu, M.J.; Chen, D.L.; Guo, X.Y. [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Zhou, D.W.; Shi, N. [Hefei National Laboratory for Physical Sciences at Microscale and School of Life Sciences, University of Science and Technology of China, Hefei, Anhui 230027 (China); Marcelli, A. [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali di Frascati, P.O. Box 13, Frascati 00044 (Italy); Niu, L.W.; Teng, M.K. [Hefei National Laboratory for Physical Sciences at Microscale and School of Life Sciences, University of Science and Technology of China, Hefei, Anhui 230027 (China); Gong, W.M. [Institute of Biophysics, Chinese Academy of Sciences, Beijing 100101 (China); Benfatto, M. [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali di Frascati, P.O. Box 13, Frascati 00044 (Italy); Wu, Z.Y. [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali di Frascati, P.O. Box 13, Frascati 00044 (Italy)], E-mail: wuzy@ihep.ac.cn

    2007-09-21

    The last several years have witnessed a tremendous increase in biological applications using X-ray absorption spectroscopy (BioXAS), thanks to continuous advancements in synchrotron radiation (SR) sources and detector technology. However, XAS applications in many biological systems have been limited by the intrinsic limitations of the Extended X-ray Absorption Fine Structure (EXAFS) technique e.g., the lack of sensitivity to bond angles. As a consequence, the application of the X-ray absorption near-edge structure (XANES) spectroscopy changed this scenario that is now continuously changing with the introduction of the first quantitative XANES packages such as Minut XANES (MXAN). Here we present and discuss the XANES code MXAN, a novel XANES-fitting package that allows a quantitative analysis of experimental data applied to Zn K-edge spectra of two metalloproteins: Leptospira interrogans Peptide deformylase (LiPDF) and acutolysin-C, a representative of snake venom metalloproteinases (SVMPs) from Agkistrodon acutus venom. The analysis on these two metallohydrolases reveals that proteolytic activities are correlated to subtle conformation changes around the zinc ion. In particular, this quantitative study clarifies the occurrence of the LiPDF catalytic mechanism via a two-water-molecules model, whereas in the acutolysin-C we have observed a different proteolytic activity correlated to structural changes around the zinc ion induced by pH variations.

  2. Quantitative investigation of two metallohydrolases by X-ray absorption spectroscopy near-edge spectroscopy

    Science.gov (United States)

    Zhao, W.; Chu, W. S.; Yang, F. F.; Yu, M. J.; Chen, D. L.; Guo, X. Y.; Zhou, D. W.; Shi, N.; Marcelli, A.; Niu, L. W.; Teng, M. K.; Gong, W. M.; Benfatto, M.; Wu, Z. Y.

    2007-09-01

    The last several years have witnessed a tremendous increase in biological applications using X-ray absorption spectroscopy (BioXAS), thanks to continuous advancements in synchrotron radiation (SR) sources and detector technology. However, XAS applications in many biological systems have been limited by the intrinsic limitations of the Extended X-ray Absorption Fine Structure (EXAFS) technique e.g., the lack of sensitivity to bond angles. As a consequence, the application of the X-ray absorption near-edge structure (XANES) spectroscopy changed this scenario that is now continuously changing with the introduction of the first quantitative XANES packages such as Minut XANES (MXAN). Here we present and discuss the XANES code MXAN, a novel XANES-fitting package that allows a quantitative analysis of experimental data applied to Zn K-edge spectra of two metalloproteins: Leptospira interrogans Peptide deformylase ( LiPDF) and acutolysin-C, a representative of snake venom metalloproteinases (SVMPs) from Agkistrodon acutus venom. The analysis on these two metallohydrolases reveals that proteolytic activities are correlated to subtle conformation changes around the zinc ion. In particular, this quantitative study clarifies the occurrence of the LiPDF catalytic mechanism via a two-water-molecules model, whereas in the acutolysin-C we have observed a different proteolytic activity correlated to structural changes around the zinc ion induced by pH variations.

  3. Size and refinement edge-shape effects of graphene quantum dots on UV–visible absorption

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Ruiqiang; Qi, Shifei; Jia, Jianfeng [School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004 (China); Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Linfen 041004 (China); Torre, Bryna [Department of Physics, University at Buffalo, The State University of New York, Buffalo, NY 14260 (United States); Zeng, Hao [School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004 (China); Department of Physics, University at Buffalo, The State University of New York, Buffalo, NY 14260 (United States); Wu, Haishun [School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004 (China); Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Linfen 041004 (China); Xu, Xiaohong, E-mail: xuxiaohong_ly@163.com [School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004 (China); Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Linfen 041004 (China)

    2015-02-25

    Highlights: • The size effect affects both the visible light absorption and the zigzag edge state. • Zigzag edge state is important than armchair edge state for visible light absorption. • The Seam atoms should be noted for the randomly shaped GQDs. - Abstract: Using the ab initio density-functional theory method, we calculated the size effect and edge shape effect on UV–visible light absorption of different shapes of graphene quantum dots (GQDs). There are two interesting findings in this study. First, the edge shape effect increase with increasing the size of square GQDs. Second, the Seam atoms, located at the boundary between zigzag and armchair edges, hardly contribute to the strongest visible light absorption. This refinement of the edge-shape effect can be found in rectangular, triangular and hexagonal GQDs. This new finding will be useful in applications of GQDs in the visible light absorption nanodevices.

  4. Parameters Influencing Sulfur Speciation in Environmental Samples Using Sulfur K-Edge X-Ray Absorption Near-Edge Structure

    Directory of Open Access Journals (Sweden)

    Siwatt Pongpiachan

    2012-01-01

    Full Text Available This paper aims to enhance the credibility of applying the sulfur K-edge XANES spectroscopy as an innovative “fingerprint” for characterizing environmental samples. The sensitivities of sulfur K-edge XANES spectra of ten sulfur compound standards detected by two different detectors, namely, Lytle detector (LyD and Germanium detector (GeD, were studied and compared. Further investigation on “self-absorption” effect revealed that the maximum sensitivities of sulfur K-edge XANES spectra were achieved when diluting sulfur compound standards with boron nitride (BN at the mixing ratio of 0.1%. The “particle-size” effect on sulfur K-edge XANES spectrum sensitivities was examined by comparing signal-to-noise ratios of total suspended particles (TSP and particulate matter of less than 10 millionths of a meter (PM10 collected at three major cities of Thailand. The analytical results have demonstrated that the signal-to-noise ratios of sulfur K-edge XANES spectra were positively correlated with sulfate content in aerosols and negatively connected with particle sizes. The combination of hierarchical cluster analysis (HCA and principal component analysis (PCA has proved that sulfur K-edge XANES spectrum can be used to characterize German terrestrial soils and Andaman coastal sediments. In addition, this study highlighted the capability of sulfur K-edge XANES spectra as an innovative “fingerprint” to distinguish tsunami backwash deposits (TBD from typical marine sediments (TMS.

  5. Attenuation studies near K-absorption edges using Compton scattered 241Am gamma rays

    Indian Academy of Sciences (India)

    K K Abdullah; N Ramachandran; K Karunakaran Nair; B R S Babu; Antony Josephm; Rajive Thomas; K M Varier

    2008-04-01

    We have carried out photon attenuation measurements at several energies in the range from 49.38 keV to 57.96 keV around the K-absorption edges of the rare earth elements Sm, Eu, Gd, Tb, Dy and Er using 59.54 keV gamma rays from 241Am source after Compton scattering from an aluminium target. Pellets of oxides of the rare earth elements were chosen as mixture absorbers in these investigations. A narrow beam good geometry set-up was used for the attenuation measurements. The scattered gamma rays were detected by an HPGe detector. The results are consistent with theoretical values derived from the XCOM package.

  6. Design and testing of an innovative slim-edge termination for silicon radiation detectors

    Science.gov (United States)

    Povoli, M.; Bagolini, A.; Boscardin, M.; Dalla Betta, G.-F.; Giacomini, G.; Mattedi, F.; Mendicino, R.; Zorzi, N.

    2013-11-01

    Silicon detectors with reduced or no dead volume along the edges have been attracting a lot of interest in the past few years in many different fields. High Energy Physics (HEP) experiments are demanding this feature to ease the assembly of the innermost tracking layers, where space and material budget are usually a concern. At the same time, other applications like X-Ray imaging, are starting to use matrixes of silicon detectors to cover increasingly larger areas and, in order to do so in a seamless way, minimum edge extension is required. In this paper we report on the design and testing of a new edge termination for silicon 3D detectors able to reduce the edge extension to about 50 μm without increasing the fabrication complexity. In addition, the same edge termination can also be applied to planar detectors with little additional process complexity.

  7. Numerical analysis of edge effects in side illuminated strip detectors for digital radiology

    CERN Document Server

    Krizaj, D

    2000-01-01

    The influence of edge defects on side illuminated X-ray strip detectors for digital radiology is investigated by numerical device modeling. By assuming positive fixed oxide charges on side and top surfaces simulations have shown strong curvature of the equipotential lines in the edge region. A fraction of the edge generated current surpasses the edge guard-ring junction and is collected by the readout strips. As a consequence, strips cannot be placed close to the edge of the structure and collection efficiency is reduced. An n-on-n instead of a p-on-n strip detector is proposed enabling collection of edge generated carriers by a very narrow guard-ring junction and placement of the readout strip close to the edge without increase of the strip leakage current.

  8. 3D Active Edge Silicon Detector Tests With 120 GeV Muons

    CERN Document Server

    Da Via, Cinzia; Hasi, Jasmine; Kenney, Christopher; Kok, Angela; Parker, Sherwood; Watts, Stephen; Anelli, Giovanni; Avati, Valentina; Bassetti, Valerio; Boccone, Vittorio; Bozzo, Marco; Eggert, Karsten; Ferro, Fabrizio; Inyakin, Alexandre; Kaplon, Jan; Lozano Bahilo, Julio; Morelli, Aldo; Niewiadomski, Hubert; Noschis, Elias; Oljemark, Fredrik; Oriunno, Marco; Österberg, Kenneth; Ruggiero, Gennaro; Snoeys, Walter; Tapprogge, Stefan

    2009-01-01

    3D detectors with electrodes penetrating through the silicon wafer and covering the edges were tested in the SPS beam line X5 at CERN in autumn 2003. Detector parameters including efficiency, signal-to-noise ratio, and edge sensitivity were measured using a silicon telescope as a reference system. The measured sensitive width and the known silicon width were equal within less than 10 mum.

  9. Calculation Research of Fitting Area for L-Absorption Edge Densimeter

    Institute of Scientific and Technical Information of China (English)

    SONG; You; ZHENG; Wei-ming; LIU; Gui-jiao

    2012-01-01

    <正>After the phases of principle prototype, research prototype, utility equipment, the development of L-absorption edge densimeter has basically been completed. The fitting areas have important influence on the measurement precision.

  10. Enhancement of broadband optical absorption in photovoltaic devices by band-edge effect of photonic crystals.

    Science.gov (United States)

    Tanaka, Yoshinori; Kawamoto, Yosuke; Fujita, Masayuki; Noda, Susumu

    2013-08-26

    We numerically investigate broadband optical absorption enhancement in thin, 400-nm thick microcrystalline silicon (µc-Si) photovoltaic devices by photonic crystals (PCs). We realize absorption enhancement by coupling the light from the free space to the large area resonant modes at the photonic band-edge induced by the photonic crystals. We show that multiple photonic band-edge modes can be produced by higher order modes in the vertical direction of the Si photovoltaic layer, which can enhance the absorption on multiple wavelengths. Moreover, we reveal that the photonic superlattice structure can produce more photonic band-edge modes that lead to further optical absorption. The absorption average in wavelengths of 500-1000 nm weighted to the solar spectrum (AM 1.5) increases almost twice: from 33% without photonic crystal to 58% with a 4 × 4 period superlattice photonic crystal; our result outperforms the Lambertian textured structure.

  11. Surface Micromachined Arrays of Transition-Edge Detectors Project

    Data.gov (United States)

    National Aeronautics and Space Administration — An innovative surface micromachining technique is described for the fabrication of closely-packed arrays of transition edge sensor (TES) x-ray microcalorimeters....

  12. Edge Detector Design Based on LS-SVR

    OpenAIRE

    Zhongdang Yu; Hamid Reza Karimi

    2014-01-01

    For locating inaccurate problem of the discrete localization criterion proposed by Demigny, a new criterion expression of "good localization" is proposed. Firstly, a discrete expression of good detection and good localization criterion of two dimension edge detection operator is employed, and then an experiment to measure optimal parameters of two dimension Canny's edge detection operator is introduced after. Moreover, a detailed performance comparison and analysis of two dimension optimal fi...

  13. Global Properties of Natural Scenes Shape Local Properties of Human Edge Detectors

    Directory of Open Access Journals (Sweden)

    P Neri

    2011-04-01

    Full Text Available Visual cortex analyzes images by first extracting relevant details (eg, edges via a large array of specialized detectors. The resulting edge map is then relayed to a processing pipeline, the final goal of which is to attribute meaning to the scene. As this process unfolds, does the global interpretation of the image affect how local feature detectors operate? The results show that some aspects of local processing were significantly affected by scene manipulations that were specifically probing the higher-level semantic interpretation of the scene. It may therefore be inaccurate to regard early feature detectors as operating completely outside the domain of higher-level vision.

  14. Model-based edge detector for spectral imagery using sparse spatiospectral masks.

    Science.gov (United States)

    Paskaleva, Biliana S; Godoy, Sebastián E; Jang, Woo-Yong; Bender, Steven C; Krishna, Sanjay; Hayat, Majeed M

    2014-05-01

    Two model-based algorithms for edge detection in spectral imagery are developed that specifically target capturing intrinsic features such as isoluminant edges that are characterized by a jump in color but not in intensity. Given prior knowledge of the classes of reflectance or emittance spectra associated with candidate objects in a scene, a small set of spectral-band ratios, which most profoundly identify the edge between each pair of materials, are selected to define a edge signature. The bands that form the edge signature are fed into a spatial mask, producing a sparse joint spatiospectral nonlinear operator. The first algorithm achieves edge detection for every material pair by matching the response of the operator at every pixel with the edge signature for the pair of materials. The second algorithm is a classifier-enhanced extension of the first algorithm that adaptively accentuates distinctive features before applying the spatiospectral operator. Both algorithms are extensively verified using spectral imagery from the airborne hyperspectral imager and from a dots-in-a-well midinfrared imager. In both cases, the multicolor gradient (MCG) and the hyperspectral/spatial detection of edges (HySPADE) edge detectors are used as a benchmark for comparison. The results demonstrate that the proposed algorithms outperform the MCG and HySPADE edge detectors in accuracy, especially when isoluminant edges are present. By requiring only a few bands as input to the spatiospectral operator, the algorithms enable significant levels of data compression in band selection. In the presented examples, the required operations per pixel are reduced by a factor of 71 with respect to those required by the MCG edge detector.

  15. Edge Detector Design Based on LS-SVR

    Directory of Open Access Journals (Sweden)

    Zhongdang Yu

    2014-01-01

    Full Text Available For locating inaccurate problem of the discrete localization criterion proposed by Demigny, a new criterion expression of “good localization” is proposed. Firstly, a discrete expression of good detection and good localization criterion of two dimension edge detection operator is employed, and then an experiment to measure optimal parameters of two dimension Canny's edge detection operator is introduced after. Moreover, a detailed performance comparison and analysis of two dimension optimal filter obtained via utilizing tensor product for one dimension optimal filter are provided which can prove that least square support vector regression (LS-SVR is a smoothness filter and give the construct method of the derivate operator. This paper uses LS-SVR as the object function constructor and then realizes the approximation of two dimension optimal edge detection operator. This paper proposes the utility method of using singleness operator to realize multiscale edge detection by referencing the multiscale analysis technology of the wavelets theory. Experiment shows that the method has utility and efficiency.

  16. Transient and near-edge absorption in YVO{sub 4} crystals

    Energy Technology Data Exchange (ETDEWEB)

    Millers, D.; Pankratov, V.; Grigorjeva, L. [Institute of Solid State Physics, University of Latvia, Riga (Latvia); Yochum, H.M. [Department of Physics and Engineering, Sweet Briar College, VA (United States); Potera, P. [Mat-Phys Department, Institute of Physics, University of Rzeszow (Poland)

    2007-03-15

    The process of near-edge absorption annealing in air was studied up to 1500C in YVO{sub 4}. In this annealing process, two stages with activation energies of 0.16 eV and 0.38 eV were obtained. (Should combine to make this one paragraph)In addition to the annealing study, the transient absorption induced by pulsed electron beam excitation (270 keV, 8 ns) was completed on a set of YVO{sub 4} samples with different near-edge absorption levels in the spectral region 3.2-3.5 eV. The spectral range from {proportional_to}1.25 eV up to 3.0 eV is covered by strong transient absorption. Transient absorption spectra show at least three broad overlapping bands ({proportional_to}1.3 eV, {proportional_to}2.0 eV and {proportional_to}3.0 eV). The 3 eV peak position is close to the near-edge absorption band and correlation between transient absorption bands and absorption due to stable colour centers was studied. It is suggested that absorption bands at {proportional_to}1.3 eV and {proportional_to}2.0 eV are due to electron and hole polarons, correspondingly. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  17. Bayesian edge detector for SAR imagery using discontinuity-adaptive Markov random field modeling

    Institute of Scientific and Technical Information of China (English)

    Yuan Zhan; He You; Cai Fuqing

    2013-01-01

    Synthetic aperture radar (SAR) image is severely affected by multiplicative speckle noise, which greatly complicates the edge detection. In this paper, by incorporating the discontinuity-adaptive Markov random field (DAMRF) and maximum a posteriori (MAP) estimation criterion into edge detection, a Bayesian edge detector for SAR imagery is accordingly developed. In the pro-posed detector, the DAMRF is used as the a priori distribution of the local mean reflectivity, and a maximum a posteriori estimation of it is thus obtained by maximizing the posteriori energy using gradient-descent method. Four normalized ratios constructed in different directions are computed, based on which two edge strength maps (ESMs) are formed. The final edge detection result is achieved by fusing the results of two thresholded ESMs. The experimental results with synthetic and real SAR images show that the proposed detector could efficiently detect edges in SAR images, and achieve better performance than two popular detectors in terms of Pratt’s figure of merit and visual evaluation in most cases.

  18. Optimized Superconducting Nanowire Single Photon Detectors to Maximize Absorptance

    CERN Document Server

    Csete, Maria; Szenes, Andras; Banhelyi, Balazs; Csendes, Tibor; Szabo, Gabor

    2015-01-01

    Dispersion characteristics of four types of superconducting nanowire single photon detectors, nano-cavity-array- (NCA-), nano-cavity-deflector-array- (NCDA-), nano-cavity-double-deflector-array- (NCDDA-) and nano-cavity-trench-array- (NCTA-) integrated (I-A-SNSPDs) devices was optimized in three periodicity intervals commensurate with half-, three-quarter- and one SPP wavelength. The optimal configurations capable of maximizing NbN absorptance correspond to periodicity dependent tilting in S-orientation (90{\\deg} azimuthal orientation). In NCAI-A-SNSPDs absorptance maxima are reached at the plasmonic Brewster angle (PBA) due to light tunneling. The absorptance maximum is attained in a wide plasmonic-pass-band in NCDAI_1/2*lambda-A, inside a flat-plasmonic-pass-band in NCDAI_3/4*lambda-A and inside a narrow plasmonic-band in NCDAI_lambda-A. In NCDDAI_1/2*lambda-A bands of strongly-coupled cavity and plasmonic modes cross, in NCDDAI_3/4*lambda-A an inverted-plasmonic-band-gap develops, while in NCDDAI_lambda-A ...

  19. Nitrogen K-edge x-ray absorption near edge structure of pyrimidine-containing nucleotides in aqueous solution.

    Science.gov (United States)

    Shimada, Hiroyuki; Minami, Hirotake; Okuizumi, Naoto; Sakuma, Ichiro; Ukai, Masatoshi; Fujii, Kentaro; Yokoya, Akinari; Fukuda, Yoshihiro; Saitoh, Yuji

    2015-05-07

    X-ray absorption near edge structure (XANES) was measured at energies around the N K-edge of the pyrimidine-containing nucleotides, cytidine 5'-monophosphate (CMP), 2'-deoxythymidine 5'-monophosphate (dTMP), and uridine 5'-monophosphate (UMP), in aqueous solutions and in dried films under various pH conditions. The features of resonant excitations below the N K-edge in the XANES spectra for CMP, dTMP, and UMP changed depending on the pH of the solutions. The spectral change thus observed is systematically explained by the chemical shift of the core-levels of N atoms in the nucleobase moieties caused by structural changes due to protonation or deprotonation at different proton concentrations. This interpretation is supported by the results of theoretical calculations using density functional theory for the corresponding nucleobases in the neutral and protonated or deprotonated forms.

  20. Nitrogen K-edge x-ray absorption near edge structure of pyrimidine-containing nucleotides in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Shimada, Hiroyuki, E-mail: hshimada@cc.tuat.ac.jp; Minami, Hirotake; Okuizumi, Naoto; Sakuma, Ichiro; Ukai, Masatoshi [Department of Applied Physics, Tokyo University of Agriculture and Technology, Koganei-shi, Tokyo 184-8588 (Japan); Fujii, Kentaro; Yokoya, Akinari [Advanced Science Research Center, Japan Atomic Energy Agency, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Fukuda, Yoshihiro; Saitoh, Yuji [Synchrotron Radiation Research Center, Japan Atomic Energy Agency, Sayo-gun, Hyogo 679-5148 (Japan)

    2015-05-07

    X-ray absorption near edge structure (XANES) was measured at energies around the N K-edge of the pyrimidine-containing nucleotides, cytidine 5′-monophosphate (CMP), 2′-deoxythymidine 5′-monophosphate (dTMP), and uridine 5′-monophosphate (UMP), in aqueous solutions and in dried films under various pH conditions. The features of resonant excitations below the N K-edge in the XANES spectra for CMP, dTMP, and UMP changed depending on the pH of the solutions. The spectral change thus observed is systematically explained by the chemical shift of the core-levels of N atoms in the nucleobase moieties caused by structural changes due to protonation or deprotonation at different proton concentrations. This interpretation is supported by the results of theoretical calculations using density functional theory for the corresponding nucleobases in the neutral and protonated or deprotonated forms.

  1. Recent results on 3D double sided detectors with slim edges

    Energy Technology Data Exchange (ETDEWEB)

    Pellegrini, G., E-mail: giulio.pellegrini@csic.es [Centro Nacional de Microelectrónica, CNM-IMB (CSIC), Barcelona 08193 (Spain); Baselga, M. [Centro Nacional de Microelectrónica, CNM-IMB (CSIC), Barcelona 08193 (Spain); Christophersen, M. [U.S. Naval Research Laboratory, Code 7654, Washington, DC 20375 (United States); Ely, S.; Fadeyev, V. [Santa Cruz Institute for Particle Physics, University of California, Santa Cruz, CA 95064 (United States); Fleta, C. [Centro Nacional de Microelectrónica, CNM-IMB (CSIC), Barcelona 08193 (Spain); Gimenez, A.; Grinstein, S.; Lopez, I. [ICREA and Institut de Física d' Altes Energies (IFAE), Barcelona 08193 (Spain); Lozano, M. [Centro Nacional de Microelectrónica, CNM-IMB (CSIC), Barcelona 08193 (Spain); Micelli, A. [ICREA and Institut de Física d' Altes Energies (IFAE), Barcelona 08193 (Spain); Phlips, B.F. [U.S. Naval Research Laboratory, Code 7654, Washington, DC 20375 (United States); Quirion, D. [Centro Nacional de Microelectrónica, CNM-IMB (CSIC), Barcelona 08193 (Spain); Sadrozinski, H.F.-W. [Santa Cruz Institute for Particle Physics, University of California, Santa Cruz, CA 95064 (United States); Tsiskaridze, S. [ICREA and Institut de Física d' Altes Energies (IFAE), Barcelona 08193 (Spain)

    2013-12-11

    This paper reports on the first characterization of double sided 3D silicon radiation pixel detectors with slim edges. These detectors consist of a three-dimensional array of electrodes that penetrate into the detector bulk with the anode and cathode electrodes etched from opposite sides of the substrate. Different detectors were post-processed using the scribe-cleave-passivate (SCP) technology to make “slim edge” sensors. These sensors have only a minimal amount of inactive peripheral region, for the benefit of the construction of large-area tracker and imaging systems. The target application for this work is the use of 3D slim edge detectors for the ATLAS Forward Physics (AFP) CERN Project, where pixel detectors for position resolution and timing detectors for removal of pile up protons, will be placed as close as possible to the beam to detect diffractive protons at 220 m on either side of the ATLAS interaction point. For this reason the silicon areas should feature the narrowest possible insensitive zone on the sensor edge closest to the beam and withstand high nonuniform irradiation fluences.

  2. Origin of the chemical shift in X-ray absorption near-edge spectroscopy at the Mn K-Edge in manganese oxide compounds

    NARCIS (Netherlands)

    de Vries, AH; Hozoi, L; Broer, R; Broer-Braam, H.B.

    2003-01-01

    The absorption edge in Mn K-edge X-ray absorption spectra of manganese oxide compounds shows a shift of several electronvolts in going from MnO through LaMnO3 to CaMnO3. On the other hand, in X-ray photoelectron spectra much smaller shifts are observed. To identify the mechanisms that cause the obse

  3. Origin of the chemical shift in X-ray absorption near-edge spectroscopy at the Mn K-Edge in manganese oxide compounds

    NARCIS (Netherlands)

    de Vries, AH; Hozoi, L.; Broer, R.

    2003-01-01

    The absorption edge in Mn K-edge X-ray absorption spectra of manganese oxide compounds shows a shift of several electronvolts in going from MnO through LaMnO3 to CaMnO3. On the other hand, in X-ray photoelectron spectra much smaller shifts are observed. To identify the mechanisms that cause the

  4. Simulation of active-edge pixelated CdTe radiation detectors

    Energy Technology Data Exchange (ETDEWEB)

    Duarte, D.D., E-mail: diana.duarte@stfc.ac.uk [STFC Rutherford Appleton Laboratory, Harwell Oxford, Didcot OX11 0QX (United Kingdom); Faculty of Engineering and Physical Sciences, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom); Lipp, J.D.; Schneider, A.; Seller, P.; Veale, M.C.; Wilson, M.D. [STFC Rutherford Appleton Laboratory, Harwell Oxford, Didcot OX11 0QX (United Kingdom); Baker, M.A.; Sellin, P.J. [Faculty of Engineering and Physical Sciences, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom)

    2016-01-11

    The edge surfaces of single crystal CdTe play an important role in the electronic properties and performance of this material as an X-ray and γ-ray radiation detector. Edge effects have previously been reported to reduce the spectroscopic performance of the edge pixels in pixelated CdTe radiation detectors without guard bands. A novel Technology Computer Aided Design (TCAD) model based on experimental data has been developed to investigate these effects. The results presented in this paper show how localized low resistivity surfaces modify the internal electric field of CdTe creating potential wells. These result in a reduction of charge collection efficiency of the edge pixels, which compares well with experimental data.

  5. Edge sensitivity of “edgeless” silicon pad detectors measured in a high-energy beam

    Science.gov (United States)

    Perea Solano, B.; Abreu, M. C.; Avati, V.; Boccali, T.; Boccone, V.; Bozzo, M.; Capra, R.; Casagrande, L.; Chen, W.; Eggert, K.; Heijne, E.; Klauke, S.; Li, Z.; Mäki, T.; Mirabito, L.; Morelli, A.; Niinikoski, T. O.; Oljemark, F.; Palmieri, V. G.; Rato Mendes, P.; Rodrigues, S.; Siegrist, P.; Silvestris, L.; Sousa, P.; Tapprogge, S.; Trocmé, B.

    2005-09-01

    We report measurements in a high-energy beam of the sensitivity of the edge region in “edgeless” planar silicon pad diode detectors. The edgeless side of these rectangular diodes is formed by a cut and break through the contact implants. A large surface current on such an edge prevents the normal reverse biasing of this device above the full depletion voltage, but we have shown that the current can be sufficiently reduced by the use of a suitable cutting method, followed by edge treatment, and by operating the detector at a low temperature. A pair of these edgeless silicon diode pad sensors was exposed to the X5 high-energy pion beam at CERN, to determine the edge sensitivity. The signal of the detector pair triggered a reference telescope made of silicon microstrip detector modules. The gap width between the edgeless sensors, determined using the tracks measured by the reference telescope, was then compared with the results of precision metrology. It was concluded that the depth of the dead layer at the diced edge is compatible with zero within the statistical precision of ±8 μm and systematic error of ±6 μm.

  6. Edge physics of the quantum spin Hall insulator from a quantum dot excited by optical absorption.

    Science.gov (United States)

    Vasseur, Romain; Moore, Joel E

    2014-04-11

    The gapless edge modes of the quantum spin Hall insulator form a helical liquid in which the direction of motion along the edge is determined by the spin orientation of the electrons. In order to probe the Luttinger liquid physics of these edge states and their interaction with a magnetic (Kondo) impurity, we consider a setup where the helical liquid is tunnel coupled to a semiconductor quantum dot that is excited by optical absorption, thereby inducing an effective quantum quench of the tunneling. At low energy, the absorption spectrum is dominated by a power-law singularity. The corresponding exponent is directly related to the interaction strength (Luttinger parameter) and can be computed exactly using boundary conformal field theory thanks to the unique nature of the quantum spin Hall edge.

  7. New detector array - the HRIBF Modular Total Absorption Spectrometer

    Science.gov (United States)

    Wolinska-Cichocka, Marzena; Rykaczewski, Krzysztof; Karny, Marek; Kuzniak, Aleksandra; Grzywacz, Robert; Rasco, Charlie; Miller, David; Gross, Carl J.; Johnson, Jim

    2011-10-01

    The construction of a new Modular Total Absorption Spectrometer (MTAS) at the Holifield Radioactive Ion Beam Facility (HRIBF) at Oak Ridge National Laboratory will be presented. The total absorption gamma spectra measured with MTAS will be used to derive a true beta-feeding pattern and resulting beta strength function for fission products. In particular, the measurements of decay heat released by radioactive nuclei produced in nuclear fuels at power reactors will be performed. MTAS is made up of 19 large NaI(Tl) crystals each encapsulated with a 0.8-mm-thick carbon fiber. There are also two 1-mm- thick Silicon Strip Detectors surrounding a moving tape collector that count beta-energy loss signals. The structure is shielded by more than 1-inch of lead around MTAS which reduces background radiation significantly. MTAS efficiency for full energy deposition of gamma ray approaches nearly 90% for 300 keV gammas and over 75% for a 5 MeV gamma transition. Research supported by the DOE Office of Nuclear Physics.

  8. Using Hierarchical Adaptive Neuro Fuzzy Systems And Design Two New Edge Detectors In Noisy Images

    Directory of Open Access Journals (Sweden)

    M. H. Olyaee

    2013-10-01

    Full Text Available One of the most important topics in image processing is edge detection. Many methods have been proposed for this end but most of them have weak performance in noisy images because noise pixels are determined as edge. In this paper, two new methods are represented based on Hierarchical Adaptive Neuro Fuzzy Systems (HANFIS. Each method consists of desired number of HANFIS operators that receive the value of some neighbouring pixels and decide central pixel is edge or not. Simple train images are used in order to set internal parameters of each HANFIS operator. The presented methods are evaluated by some test images and compared with several popular edge detectors. The experimental results show that these methods are robust against impulse noise and extract edge pixels exactly.

  9. An efficient circle detector not relying on edge detection

    Science.gov (United States)

    Cai, Jia; Huang, Panfeng; Chen, Lu; Zhang, Bin

    2016-06-01

    Accurate and efficient detection of circular modules fixed on non-cooperative target is a key technology for Tethered Space Robot. This paper presents an efficient circle detector based on region-growing of gradient and histogram distribution of Euclidean distance. Region-growing of gradient is applied to generate arc support regions from single point. And the corresponding square fitting areas are defined to accelerate the detection and decrease storage. A histogram is then used to count frequency of the distances that participates in the accumulator and the parameters of each circle are acquired. Finally, a verification strategy of circular integrity is designed to test the detection results. We have tested our algorithm on 35 images dealing with kinds of circles and ellipses. Experimental results demonstrate that our method is able to detect circular objects under occlusion, image noises and moderate shape deformations with a good precision.

  10. Influence of Uniaxial Stress on the Indirect Absorption Edge in Silicon and Germanium

    DEFF Research Database (Denmark)

    Balslev, I.

    1966-01-01

    The indirect optical absorption edge in silicon and germanium has been studied in the presence of shear strain. The splitting observed in the transmission spectrum is dependent on the direction and magnitude of the applied stress and on the polarization of the light with respect to the stress axi...... with uniaxial stress. A special experimental technique using a vibrating slit in the spectrometer was used in order to obtain an accurate determination of the fine structure in the absorption spectrum....

  11. Characterization of Thin p-on-p Radiation Detectors with Active Edges

    CERN Document Server

    Peltola, T; Kalliopuska, J; Granja, C; Jakubek, J; Jakubek, M; Härkönen, J; Gädda, A

    2016-01-01

    Active edge p-on-p silicon pixel detectors with thickness of 100 $\\mu$m were fabricated on 150 mm Float zone silicon wafers at VTT. By combining measured results and TCAD simulations, a detailed study of electric field distributions and charge collection performances as a function of applied voltage in a p-on-p detector was carried out. A comparison with the results of a more conventional active edge p-on-n pixel sensor is presented. The results from 3D spatial mapping show that at pixel-to-edge distances less than 100 $\\mu$m the sensitive volume is extended to the physical edge of the detector when the applied voltage is above full depletion. The results from a spectroscopic measurement demonstrate a good functionality of the edge pixels. The interpixel isolation above full depletion and the breakdown voltage were found to be equal to the p-on-n sensor while lower charge collection was observed in the p-on-p pixel sensor below 80 V. Simulations indicated this to be partly a result of a more favourable weight...

  12. Global properties of natural scenes shape local properties of human edge detectors

    Directory of Open Access Journals (Sweden)

    Peter eNeri

    2011-08-01

    Full Text Available Visual cortex analyzes images by first extracting relevant details (e.g. edges via a large array of specialized detectors. The resulting edge map is then relayed to a processing pipeline, the final goal of which is to attribute meaning to the scene. As this process unfolds, does the global interpretation of the image affect how local feature detectors operate? We characterized the local properties of human edge detectors while we manipulated the extent to which the statistical properties of the surrounding image conformed to those encountered in natural vision. Although some aspects of local processing were unaffected by contextual manipulations, we observed significant alterations in the operating characteristics of the detector which were solely attributable to a higher-level semantic interpretation of the scene, unrelated to lower-level aspects of image statistics. Our results suggest that it may be inaccurate to regard early feature detectors as operating outside the domain of higher-level vision; although there is validity in this approach, a full understanding of their properties requires the inclusion of knowledge-based effects specific to the statistical regularities found in the natural environment.

  13. X-ray absorption near edge spectroscopy at the Mn K-edge in highly homogeneous GaMnN diluted magnetic semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Sancho-Juan, O.; Cantarero, A.; Garro, N.; Cros, A. [Materials Science Institute, University of Valencia, PO Box 22085, 46071 Valencia (Spain); Martinez-Criado, G.; Salome, M.; Susini, J. [ESRF, Polygone Scientifique Louis Neel, 6 rue Jules Horowitz, 38000 Grenoble (France); Olguin, D. [Dept. de Fisica, CINVESTAV-IPN, 07300 Mexico D.F. (Mexico); Dhar, S.; Ploog, K. [Paul Drude Institute, Hausvogteiplatz 5-7, 10117 Berlin (Germany)

    2006-06-15

    We have studied by X-ray absorption spectroscopy the local environment of Mn in highly homogeneous Ga{sub 1-x}Mn{sub x}N (0.06edges. In this report, we focus our attention to the X-ray absorption near edge spectroscopy (XANES) results. The comparison of the XANES spectra corresponding to the Ga and Mn edges indicates that Mn is substitutional to Ga in all samples studied. The XANES spectra measured at the Mn absorption edge shows in the near-edge region a double peak and a shoulder below the absorption edge and the main absorption peak after the edge, separated around 15 eV above the pre-edge structure. We have compared the position of the edge with that of MnO (Mn{sup 2+}) and Mn{sub 2}O{sub 3} (Mn{sup 3+}). All samples studied present the same Mn oxidation state, 2{sup +}. In order to interprete the near-edge structure, we have performed ab initio calculations with a 2 x 2 x 1supercell ({proportional_to}6% Mn) using the full potential linear augmented plane wave method as implemented in the Wien2k code. The calculations show the appearance of Mn anti-bonding t{sub 2g} bands, which are responsible for the pre-edge absorption. The shoulder and main absorption peaks are due to transitions from the valence band 1s-states of Mn to the p-contributions of the conduction bands. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  14. Single shot near edge x-ray absorption fine structure spectroscopy in the laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Mantouvalou, I., E-mail: ioanna.mantouvalou@tu-berlin.de; Witte, K.; Martyanov, W.; Jonas, A.; Grötzsch, D.; Kanngießer, B. [Institute for Optics and Atomic Physics, Technical University of Berlin, D-10623 Berlin (Germany); Streeck, C. [Physikalisch-Technische Bundesanstalt (PTB), D-10587 Berlin (Germany); Löchel, H.; Rudolph, I.; Erko, A. [Helmholtz-Zentrum Berlin, D-14109 Berlin (Germany); Stiel, H. [Max Born Institute for Nonlinear Optics and Short Pulse Spectroscopy, D-12489 Berlin (Germany)

    2016-05-16

    With the help of adapted off-axis reflection zone plates, near edge X-ray absorption fine structure spectra at the C and N K-absorption edge have been recorded using a single 1.2 ns long soft X-ray pulse. The transmission experiments were performed with a laser-produced plasma source in the laboratory rendering time resolved measurements feasible independent on large scale facilities. A resolving power of E/ΔE ∼ 950 at the respective edges could be demonstrated. A comparison of single shot spectra with those collected with longer measuring time proves that all features of the used reference samples (silicon nitrate and polyimide) can be resolved in 1.2 ns. Hence, investigations of radiation sensitive biological specimen become possible due to the high efficiency of the optical elements enabling low dose experiments.

  15. Theory of edge-state optical absorption in two-dimensional transition metal dichalcogenide flakes

    Science.gov (United States)

    Trushin, Maxim; Kelleher, Edmund J. R.; Hasan, Tawfique

    2016-10-01

    We develop an analytical model to describe sub-band-gap optical absorption in two-dimensional semiconducting transition metal dichalcogenide (s-TMD) nanoflakes. The material system represents an array of few-layer molybdenum disulfide crystals, randomly orientated in a polymer matrix. We propose that optical absorption involves direct transitions between electronic edge states and bulk bands, depends strongly on the carrier population, and is saturable with sufficient fluence. For excitation energies above half the band gap, the excess energy is absorbed by the edge-state electrons, elevating their effective temperature. Our analytical expressions for the linear and nonlinear absorption could prove useful tools in the design of practical photonic devices based on s-TMDs.

  16. Interpretation of the pre-edge X-ray absorption fine structures in MnO

    Institute of Scientific and Technical Information of China (English)

    LI Shu-Jun; HU Rong; HU Tian-Dou; XIE Ya-Ning; ZHANG Jing; TAO Ye; WU Zi-Yu

    2003-01-01

    The weak pre-edge features in the Mn K-edge X-ray absorption near-edge structure (XANES) spectrumof manganese monoxide (MnO) were investigated by comparing experimental data with dipolar and quadrupolarcross-section calculations in the framework of multiple-scattering theory. We assign the first pre-edge feature to a di-rect quadrupolar transition from Is core state to 3d molecular orbitals of the central atom, e.g., the lowest in energy,due to the more effective attraction of the core hole. The second peak in this region arises unambiguously from thehybridization between p-orbitals of the central atom with higher-shell metal octahedral orbitals.

  17. Optical readout uncooled infrared imaging detector using knife-edge filter operation

    Institute of Scientific and Technical Information of China (English)

    ZHANG Q; MIAO Z; GUO Z; DONG F; XIONG Z; WU X; CHEN D; LI C; JIAO B

    2007-01-01

    An optical readout uncooled infrared (IR) imaging detector of bimaterial cantilever array using knife-edge filter operation(KEFO) is demonstrated. The angle change of each cantilever in a focal plane array (FPA) can be simultaneously detected with a resolution of 10-5 degree. A deformation magnifying substrate-free micro-cantilever unit with multi-fold interval metallized legs is specially designed and modeled. A FPA with 160× 160 pixels is fabricated and thermal images with noise equivalent temperature difference (NETD) of 400 mK are obtained by this imaging detector.

  18. X-Ray Absorption Spectroscopy of Mo and Ni K-edge of Supported Hydrotreating Catalysts

    Institute of Scientific and Technical Information of China (English)

    DuanAijun; XuChunming; ZhaoZhen; DongPeng

    2005-01-01

    X-ray absorption fine structure (XAFS) and other techniques have been used to characterize Ni-Mo/Al2O3 supported catalysts. The analysis of Mo K-edge spetrum shows that the active species over sulfide catalysts are MoS2-alike and the dispersion of Mo is high at the level of nanometer particles. There may exist some distortion of the local environment of MoS2, which has an influence on the hydrotreating activities of catalysts. Ni K-edge analysis shows that the coordination effects of Ni-Mo favor the dispersion state of active phase and imply a close relationship with catalyst activities.

  19. Cyclic voltammetry and near edge X-ray absorption fine structure spectroscopy at the Ag L3-edge on electrochemical halogenation of Ag layers on Au(111)

    Science.gov (United States)

    Endo, Osamu; Nakamura, Masashi

    2011-05-01

    One to three layers of Ag grown on a Au(111) electrode were studied by cyclic voltammetry in chloride and bromide solutions and by ex-situ near-edge X-ray absorption fine structure spectroscopy at the Ag L3-edge (Ag L3-NEXAFS). The one and two layers obtained by underpotential deposition exhibited reduced intensity at the absorption edge in the Ag L3-NEXAFS spectra, which suggests the gain of d-electrons in these layers. The cyclic voltammograms and the Ag L3-NEXAFS spectra indicate that the second and third layers of Ag halogenated at positive potentials, whereas the first layer remained in metallic form.

  20. Identifying anthropogenic uranium compounds using soft X-ray near-edge absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Ward, Jesse D.; Bowden, Mark; Tom Resch, C.; Eiden, Gregory C.; Pemmaraju, C. D.; Prendergast, David; Duffin, Andrew M.

    2017-01-01

    Uranium ores mined for industrial use are typically acid-leached to produce yellowcake and then converted into uranium halides for enrichment and purification. These anthropogenic chemical forms of uranium are distinct from their mineral counterparts. The purpose of this study is to use soft X-ray absorption spectroscopy to characterize several common anthropogenic uranium compounds important to the nuclear fuel cycle. Non-destructive chemical analyses of these compounds is important for process and environmental monitoring and X-ray absorption techniques have several advantages in this regard, including element-specificity, chemical sensitivity, and high spectral resolution. Oxygen K-edge spectra were collected for uranyl nitrate, uranyl fluoride, and uranyl chloride, and fluorine K-edge spectra were collected for uranyl fluoride and uranium tetrafluoride. Interpretation of the data is aided by comparisons to calculated spectra. These compounds have unique spectral signatures that can be used to identify unknown samples.

  1. Retinal vessel extraction by means of motion contrast, matched filter and combined corner-edge detector

    Science.gov (United States)

    Yu, Lei; Qi, Yue; Xia, Mingliang; Xuan, Li

    2014-05-01

    The microvasculature network of retina plays an important role in understanding of the retinal function and diagnosis of many diseases. Although it is possible to noninvasively acquire diffraction-limited resolution retinal images at microscopic cellular level, noises and other structures still make it difficult for diagnosis. In this paper, a new vessel extraction method is introduced. First, we use motion contrast method to trace the motion of the blood components and get the main vessel contour. Second, an improved matched filter method is applied to extract the vessel contour while the single-side edges are eliminated. Then, the combined corner/edge detector is adopted to eliminate the elongated fragments caused by the motion artifacts. Finally, we use mathematical morphology method to dilate the edges of vessels acquired in last step and obtain the exact contour of the vessels. The contrast of the vessels is significantly enhanced and the noises as well as other structures are effectively eliminated.

  2. A Novel Architecture for Real Time Implementation of Edge Detectors on FPGA

    Directory of Open Access Journals (Sweden)

    Sudeep K C

    2011-01-01

    Full Text Available With the introduction of reconfigurable platform such as Field Programmable Gate Arrays (FPGA and advent of new high level tools to configure them, image processing on FPGA has emerged as a practical solutions for most of computer vision and image processing problems. This paper briefly explains the implementation of several edge detection algorithms like Sobel, Prewitt, Robert and Compass edge detectors on FPGA and makes a comparative study of their performance. The design utilizes powerful design tool System Generator (SysGen and Embedded Development Kit (EDK for hardware-software codesign and integrates the edge detection hardware as a peripheral to the Microblaze 32 bit soft RISC processor with an input from a CMOS camera and output to a DVI display and verified the results video in real time.

  3. MMSE Multiuser Detector Alleviating Edge Effect in Asynchronous DS-CDMA Systems

    Institute of Scientific and Technical Information of China (English)

    WANGLing; JIAOLicheng; TAOHaihong; LIUFang

    2005-01-01

    Multiuser detection is a key technique in DS-CDMA systems. At the base station, the received signal is the compositive signal transmitted by active users in the system over asynchronous channels, the Multiple access interference (MAI) components of which is more serious than that in synchronous systems. In this paper, based on the compact matrix signal model of the asynchronous system, a MMSE (Minimum mean square error) Multiuser detector alleviating edge effect (MMSEAEE) with low complexity is proposed. The asymptotic efficiency, near-far effect resistance and computational complexity of the multiuser detector are analyzed qualitatively. Finally, the bit error rate is simulated via plentiful Monte Carlo numerical experiments. With performance analysis and numerical simulation, it is shown that MMSEAEE with low complexity offers significant performance improvement over some existing popular detectors in eliminating multiple access interference and near-far resistance.

  4. The effects of dust scattering on high-resolution X-ray absorption edge structure

    Science.gov (United States)

    Corrales, L.; García, J.; Wilms, J.; Baganoff, F.

    2016-06-01

    High energy studies of astrophysical dust complement observations of dusty interstellar gas at other wavelengths. With high resolution X-ray spectroscopy, dust scattering significantly enhances the total extinction optical depth and alters the shape of photoelectric absorption edges. This effect is modulated by the dust grain size distribution, spatial location along the line of sight, and the imaging resolution of the X-ray telescope. At soft energies, the spectrum of scattered light is likely to have significant features at the 0.3 keV (C-K), 0.5 keV (O-K), and 0.7 keV (Fe-L) photoelectric absorption edges. This direct probe of ISM dust grain elements will be important for (i) understanding the relative abundances of graphitic grains or PAHs versus silicates, and (ii) measuring the depletion of gas phase elements into solid form. We focus in particular on the Fe-L edge, fitting a template for the total extinction to the high resolution spectrum of three X-ray binaries from the Chandra archive: GX 9+9, XTE J1817-330, and Cyg X-1. We discuss ways in which spectroscopy with XMM can yield insight into dust obscured objects such as stars, binaries, AGN, and foreground quasar absorption line systems.

  5. X-ray absorption spectroscopy of diluted system by undulator photon source and multi-element solid-state detector

    CERN Document Server

    Tanida, H

    2001-01-01

    In order to measure the extended X-ray absorption fine structure (EXAFS) spectrum of an ultra-diluted system, an optics and detector control system for a synchrotron radiation beamline is developed. The undulator gap width is continuously tuned to obtain the maximum X-ray photon flux during the energy scan for the EXAFS measurement. A piezoelectric translator optimizes the parallelism of the double crystal in a monochromator at each measurement point to compensate for mechanical errors of the monochromator, resulting in a smooth and intense X-ray photon flux during the measurement. For a detection of a weak fluorescence signal from diluted samples, a 19-element solid-state detector and digital signal processor are used. A K-edge EXAFS spectrum of iron in a myoglobin aqueous solution with a concentration of 5.58 parts per million was obtained by this system.

  6. Electronic States of LaCoO3: Co K-edge and La L-edge X-ray Absorption Studies

    Energy Technology Data Exchange (ETDEWEB)

    Pandey,S.; Kumar, A.; Khalid, S.; Pimpale, A.

    2006-01-01

    Room-temperature Co K-edge and La L-edge x-ray absorption studies have been carried out on LaCoO{sub 3}. Experimental near-edge structures have been analyzed by theoretical LDA+U density of states (DOS) and multiple scattering (MS) calculations. Use of both MS and DOS calculations yields additional information about hybridization of the states of the central atom with neighboring atoms responsible for producing the near-edge structures. Absorption processes at the Co K-edge, and the La L1-, L2-, and L3-edges have been attributed to electronic transitions from Co1s {yields} Co4p, La2s {yields} La6p, La 2{sub 1/2}{yields} La 5d, and La 2p{sub 3/2} {yields} La5d, respectively. All the pre-edge and post-edge features including the shape of the main absorption edge have been generated by taking the convolution of the calculated DOS, indicating that single particle approximation is sufficient to express all experimentally observed major structures. Two pre-edge structures observed in the Co K-edge spectrum are attributed to Co1s {yields} e{sub g}{sup {up_arrow}} and e{sub g}{sup {down_arrow}} quadrupole transitions in contrast to earlier identification of the same to Co1s {yields} t{sub 2g} and e{sub g} transitions. The influence of La 6p states on the Co 4p states is such that the inclusion of La atoms in the MS calculations is necessary to generate post-edge structures in the Co K-edge spectrum. The importance of the hybridization of the O 2p state with La 6p and 5d in the L-edge absorption processes is also discussed. A 10% contribution of the quadrupole channel has been estimated in the La L-edges.

  7. X-ray absorption spectroscopy systematics at the tungsten L-edge.

    Science.gov (United States)

    Jayarathne, Upul; Chandrasekaran, Perumalreddy; Greene, Angelique F; Mague, Joel T; DeBeer, Serena; Lancaster, Kyle M; Sproules, Stephen; Donahue, James P

    2014-08-18

    A series of mononuclear six-coordinate tungsten compounds spanning formal oxidation states from 0 to +VI, largely in a ligand environment of inert chloride and/or phosphine, was interrogated by tungsten L-edge X-ray absorption spectroscopy. The L-edge spectra of this compound set, comprised of [W(0)(PMe3)6], [W(II)Cl2(PMePh2)4], [W(III)Cl2(dppe)2][PF6] (dppe = 1,2-bis(diphenylphosphino)ethane), [W(IV)Cl4(PMePh2)2], [W(V)(NPh)Cl3(PMe3)2], and [W(VI)Cl6], correlate with formal oxidation state and have usefulness as references for the interpretation of the L-edge spectra of tungsten compounds with redox-active ligands and ambiguous electronic structure descriptions. The utility of these spectra arises from the combined correlation of the estimated branching ratio of the L3,2-edges and the L1 rising-edge energy with metal Zeff, thereby permitting an assessment of effective metal oxidation state. An application of these reference spectra is illustrated by their use as backdrop for the L-edge X-ray absorption spectra of [W(IV)(mdt)2(CO)2] and [W(IV)(mdt)2(CN)2](2-) (mdt(2-) = 1,2-dimethylethene-1,2-dithiolate), which shows that both compounds are effectively W(IV) species even though the mdt ligands exist at different redox levels in the two compounds. Use of metal L-edge XAS to assess a compound of uncertain formulation requires: (1) Placement of that data within the context of spectra offered by unambiguous calibrant compounds, preferably with the same coordination number and similar metal ligand distances. Such spectra assist in defining upper and/or lower limits for metal Zeff in the species of interest. (2) Evaluation of that data in conjunction with information from other physical methods, especially ligand K-edge XAS. (3) Increased care in interpretation if strong π-acceptor ligands, particularly CO, or π-donor ligands are present. The electron-withdrawing/donating nature of these ligand types, combined with relatively short metal-ligand distances, exaggerate

  8. Identifying anthropogenic uranium compounds using soft X-ray near-edge absorption spectroscopy

    Science.gov (United States)

    Ward, Jesse D.; Bowden, Mark; Tom Resch, C.; Eiden, Gregory C.; Pemmaraju, C. D.; Prendergast, David; Duffin, Andrew M.

    2017-01-01

    Uranium ores mined for industrial use are typically acid-leached to produce yellowcake and then converted into uranium halides for enrichment and purification. These anthropogenic chemical forms of uranium are distinct from their mineral counterparts. The purpose of this study is to use soft X-ray absorption spectroscopy to characterize several common anthropogenic uranium compounds important to the nuclear fuel cycle. Chemical analyses of these compounds are important for process and environmental monitoring. X-ray absorption techniques have several advantages in this regard, including element-specificity, chemical sensitivity, and high spectral resolution. Oxygen K-edge spectra were collected for uranyl nitrate, uranyl fluoride, and uranyl chloride, and fluorine K-edge spectra were collected for uranyl fluoride and uranium tetrafluoride. Interpretation of the data is aided by comparisons to calculated spectra. The effect of hydration state on the sample, a potential complication in interpreting oxygen K-edge spectra, is discussed. These compounds have unique spectral signatures that can be used to identify unknown samples.

  9. Zr and Ba edge phenomena in the scintillation intensity of fluorozirconate-based glass-ceramic X-ray detectors.

    Science.gov (United States)

    Henke, Bastian; Schweizer, Stefan; Johnson, Jacqueline A; Keane, Denis T

    2007-05-01

    The energy-dependent scintillation intensity of Eu-doped fluorozirconate glass-ceramic X-ray detectors has been investigated in the energy range from 10 to 40 keV. The experiments were performed at the Advanced Photon Source, Argonne National Laboratory, USA. The glass ceramics are based on Eu-doped fluorozirconate glasses, which were additionally doped with chlorine to initiate the nucleation of BaCl(2) nanocrystals therein. The X-ray excited scintillation is mainly due to the 5d-4f transition of Eu(2+) embedded in the BaCl(2) nanocrystals; Eu(2+) in the glass does not luminesce. Upon appropriate annealing the nanocrystals grow and undergo a phase transition from a hexagonal to an orthorhombic phase of BaCl(2). The scintillation intensity is investigated as a function of the X-ray energy, particle size and structure of the embedded nanocrystals. The scintillation intensity versus X-ray energy dependence shows that the intensity is inversely proportional to the photoelectric absorption of the material, i.e. the more photoelectric absorption the less scintillation. At 18 and 37.4 keV a significant decrease in the scintillation intensity can be observed; this energy corresponds to the K-edge of Zr and Ba, respectively. The glass matrix as well as the structure and size of the embedded nanocrystals have an influence on the scintillation properties of the glass ceramics.

  10. Characterization of Photon-Counting Detector Responsivity for Non-Linear Two-Photon Absorption Process

    Science.gov (United States)

    Sburlan, S. E.; Farr, W. H.

    2011-01-01

    Sub-band absorption at 1550 nm has been demonstrated and characterized on silicon Geiger mode detectors which normally would be expected to have no response at this wavelength. We compare responsivity measurements to singlephoton absorption for wavelengths slightly above the bandgap wavelength of silicon (approx. 1100 microns). One application for this low efficiency sub-band absorption is in deep space optical communication systems where it is desirable to track a 1030 nm uplink beacon on the same flight terminal detector array that monitors a 1550 nm downlink signal for pointingcontrol. The currently observed absorption at 1550 nm provides 60-70 dB of isolation compared to the response at 1064 nm, which is desirable to avoid saturation of the detector by scattered light from the downlink laser.

  11. Characterization of Photon-Counting Detector Responsivity for Non-Linear Two-Photon Absorption Process

    Science.gov (United States)

    Sburlan, S. E.; Farr, W. H.

    2011-01-01

    Sub-band absorption at 1550 nm has been demonstrated and characterized on silicon Geiger mode detectors which normally would be expected to have no response at this wavelength. We compare responsivity measurements to singlephoton absorption for wavelengths slightly above the bandgap wavelength of silicon (approx. 1100 microns). One application for this low efficiency sub-band absorption is in deep space optical communication systems where it is desirable to track a 1030 nm uplink beacon on the same flight terminal detector array that monitors a 1550 nm downlink signal for pointingcontrol. The currently observed absorption at 1550 nm provides 60-70 dB of isolation compared to the response at 1064 nm, which is desirable to avoid saturation of the detector by scattered light from the downlink laser.

  12. Interstellar dust grain composition from high-resolution X-ray absorption edge structure

    Science.gov (United States)

    Corrales, Lia

    2016-06-01

    X-ray light is sufficient to excite electrons from n=1 (K-shell) and n=2 (L-shell) energy levels of neutral interstellar metals, causing a sharp increase in the absorption cross-section. Near the ionization energy, the shape of the photoelectric absorption edge depends strongly on whether the atom is isolated or bound in molecules or minerals (dust). With high resolution X-ray spectroscopy, we can directly measure the state of metals and the mineral composition of dust in the interstellar medium. In addition, the scattering contribution to the X-ray extinction cross-section can be used to gauge grain size, shape, and filling factor. In order to fully take advantage of major advances in high resolution X-ray spectroscopy, lab measurements of X-ray absorption fine structure (XAFS) from suspected interstellar minerals are required. Optical constants derived from the absorption measurements can be used with Mie scattering or anomalous diffraction theory in order to model the full extinction cross-sections from the interstellar medium. Much like quasar spectra are used to probe other intergalactic gas, absorption spectroscopy of Galactic X-ray binaries and bright stars will yield key insights to the mineralogy and evolution of dust grains in the Milky Way.

  13. Identification of Uranyl Minerals Using Oxygen K-Edge X Ray Absorption Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Ward, Jesse D.; Bowden, Mark E.; Resch, Charles T.; Smith, Steven C.; McNamara, Bruce K.; Buck, Edgar C.; Eiden, Gregory C.; Duffin, Andrew M.

    2016-03-01

    Uranium analysis is consistently needed throughout the fuel cycle, from mining to fuel fabrication to environmental monitoring. Although most of the world’s uranium is immobilized as pitchblende or uraninite, there exists a plethora of secondary uranium minerals, nearly all of which contain the uranyl cation. Analysis of uranyl compounds can provide clues as to a sample’s facility of origin and chemical history. X-ray absorption spectroscopy is one technique that could enhance our ability to identify uranium minerals. Although there is limited chemical information to be gained from the uranium X-ray absorption edges, recent studies have successfully used ligand NEXAFS to study the physical chemistry of various uranium compounds. This study extends the use of ligand NEXAFS to analyze a suite of uranium minerals. We find that major classes of uranyl compounds (carbonate, oxyhydroxide, silicate, and phosphate) exhibit characteristic lineshapes in the oxygen K-edge absorption spectra. As a result, this work establishes a library of reference spectra that can be used to classify unknown uranyl minerals.

  14. Differentiation method for localization of Compton edge in organic scintillation detectors

    CERN Document Server

    Safari, M J; Afarideh, H

    2016-01-01

    This paper, presents a simple method for accurate calibration of organic scintillation detectors. The method is based on the fact that differentiating the response function leads to accurate estimation of the Compton edge. The differentiation method in addition to the location of the Compton edge, gives insights into the parameters of the folded Gaussian function which is useful for determination of the energy resolution. Moreover, it is observed that the uncorrelated noise in the measurement of the response function does not impose significant uncertainties in the evaluations. By simulation of the bounded electrons and considering the Doppler effects, we are able to calculate a first estimation for the intrinsic Doppler resolution of a plastic scintillator, benefiting from the capability of the differentiation method.

  15. Recent Developments in Transition-Edge Strip Detectors for Solar X-Rays

    Science.gov (United States)

    Rausch, Adam J.; Deiker, Steven W.; Hilton, Gene; Irwin, Kent D.; Martinez-Galarce, Dennis S.; Shing, Lawrence; Stern, Robert A.; Ullom, Joel N.; Vale, Leila R.

    2008-01-01

    LMSAL and NIST are developing position-sensitive x-ray strip detectors based on Transition Edge Sensor (TES) microcalorimeters optimized for solar physics. By combining high spectral (E/ delta E approximately equals 1600) and temporal (single photon delta t approximately equals 10 micro s) resolutions with imaging capabilities, these devices will be able to study high-temperature (>l0 MK) x-ray lines as never before. Diagnostics from these lines should provide significant new insight into the physics of both microflares and the early stages of flares. Previously, the large size of traditional TESs, along with the heat loads associated with wiring large arrays, presented obstacles to using these cryogenic detectors for solar missions. Implementing strip detector technology at small scales, however, addresses both issues: here, a line of substantially smaller effective pixels requires only two TESs, decreasing both the total array size and the wiring requirements for the same spatial resolution. Early results show energy resolutions of delta E(sub fwhm) approximately equals 30 eV and spatial resolutions of approximately 10-15 micron, suggesting the strip-detector concept is viable.

  16. HIGHER ORDER SPECIATION EFFECTS ON PLUTONIUM L3 X-RAY ABSORPTION NEAR EDGE SPECTRA.

    Energy Technology Data Exchange (ETDEWEB)

    Conradson, Steven D.; Abney, Kent D.; Begg, Bruce D.; Brady, Erik D.; Clark, David L.; den Auwer, Christophe; Ding, Mei; Dorhout, Peter K.; Espinosa-Faller, Francisco J.; Gordon, Pamela L.; Hess, Nancy J.; Hess, Ryan F.; Keogh, D. Webster; Lander, Gerard H.; Lupinetti, Anthony J.; Neu, Mary P.; Palmer, Phillip D.; Paviet-Hartmann, Patricia; Reilly, Sean D.; Runde, Wolfgang H.; Tait, C. Drew; Veirs, D. Kirk

    2003-06-09

    Pu L{sub 3} X-ray Near Edge Absorption Spectra for Pu(0-VII) are reported for more than 50 chalcogenides, chlorides, hydrates, hydroxides, nitrates, carbonates, oxy-hydroxides, and other compounds both as solids and in solution, and substituted in zirconlite, perovksite, and borosilicate glass. This large data base extends the known correlations between the energy and shape of these spectra from the usual association of the XANES with valence and site symmetry to higher order chemical effects. Because of the large number of compounds of these different types a number of novel and unexpected behaviors are observed.

  17. Discovery of a Transient Absorption Edge in the X-ray Spectrum of GRB 990705

    CERN Document Server

    Amati, L; Vietri, M; in 't Zand, J J M; Soffitta, P; Costa, E; Del Sordo, S; Pian, E; Piro, L; Antonelli, L A; Dal Fiume, D; Feroci, M; Gandolfi, G; Guidorzi, C; Heise, J; Kuulkers, E; Masetti, N; Montanari, E; Nicastro, L; Orlandini, M; Palazzi, E

    2000-01-01

    We report the discovery of a transient equivalent hydrogen column density with an absorption edge at ~3.8 kiloelectron volts in the spectrum of the prompt x-ray emission of gamma-ray burst (GRB) 990705. This feature can be satisfactorily modeled with a photoelectric absorption by a medium located at a redshift of ~0.86 and with an iron abundance of ~75 times the solar one. The transient behavior is attributed to the strong ionization produced in the circumburst medium by the GRB photons. The high iron abundance points to the existence of a burst environment enriched by a supernova along the line of sight. The supernova explosion is estimated to have occurred about 10 years before the burst. Our results agree with models in which GRBs originate from the collapse of very massive stars and are preceded by a supernova event

  18. Assignment of Pre-Edge Features in the Ru K-Edge X-Ray Absorption Spectra of Organometallic Ruthenium Complexes

    Energy Technology Data Exchange (ETDEWEB)

    Getty, K.; Delgado-Jaime, M.U.; Kennepohl, P.

    2009-05-18

    The nature of the lowest energy bound-state transition in the Ru K-edge X-ray absorption spectra for a series of Grubbs-type ruthenium complexes was investigated. The pre-edge feature was unambiguously assigned as resulting from formally electric dipole forbidden Ru 4d {l_arrow} 1s transitions. The intensities of these transitions are extremely sensitive to the ligand environment and the symmetry of the metal centre. In centrosymmetric complexes the pre-edge is very weak since it is limited by the weak electric quadrupole intensity mechanism. By contrast, upon breaking centrosymmetry, Ru 5p-4d mixing allows for introduction of electric dipole allowed character resulting in a dramatic increase in the pre-edge intensity. The information content of this approach is explored as it relates to complexes of importance in olefin metathesis and its relevance as a tool for the study of reactive intermediates.

  19. Detecting an infrared photon within an hour. Transition-edge detector at ALPS-II

    Energy Technology Data Exchange (ETDEWEB)

    Dreyling-Eschweiler, Jan [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Hamburg Univ. (Germany). Inst. fuer Experimentalphysik; Horns, Dieter [Hamburg Univ. (Germany). Inst. fuer Experimentalphysik; Collaboration: ALPS-II collaboration

    2013-09-15

    An essential design requirement of the ALPS-II experiment is the efficient detection of single photons with a very low instrumental background of 10 {mu}Hz. In 2011 the ALPS collaboration started to set up a TES detector (Transition-Edge Sensor) for ALPS-II, the second phase of the experiment. Since mid of 2013 the setup is ready for characterization in the ALPS laboratory: an ADR cryostat (Adiabatic Demagnetization Refrigerator) as millikelvin environment, a low noise SQUID (Superconducting Quantum Interference Device) with electronics for read-out and a fiber-coupled high-efficient TES for near-infrared photons as sensor. First measurements have shown a good discrimination between noise and 1064 nm signals.

  20. Near-edge X-ray absorption fine structure spectroscopy of MDI and TDI polyurethane polymers

    Energy Technology Data Exchange (ETDEWEB)

    Urquhart, S.G.; Smith, A.P.; Ade, H.W. [North Carolina State Univ., Raleigh, NC (United States). Dept. of Physics; Hitchcock, A.P. [McMaster Univ., Hamilton, Ontario (Canada). Brockhouse Inst. for Materials Research; Rightor, E.G. [Dow Chemical USA, Midland, MI (United States); Lidy, W. [Dow Chemical USA, Freeport, TX (United States)

    1999-06-03

    The sensitivity of near-edge X-ray absorption fine structure (NEXAFS) to differences in key chemical components of polyurethane polymers is presented. Carbon is NEXAFS spectra of polyurethane polymers made from 4,4{prime}-methylene di-p-phenylene isocyanate (MDI) and toluene diisocyanate (TDI) isocyanate monomers illustrate that there is an unambiguous spectroscopic fingerprint for distinguishing between MDI-based and TDI-based polyurethane polymers. NEXAFS spectra of MDI and TDI polyurea and polyurethane models show that the urea and carbamate (urethane) linkages in these polymers can be distinguished. The NEXAFS spectroscopy of the polyether component of these polymers is discussed, and the differences between the spectra of MDI and TDI polyurethanes synthesized with polyether polyols of different molecular composition and different molecular weight are presented. These polymer spectra reported herein provide appropriate model spectra to represent the pure components for quantitative microanalysis.

  1. Structural analysis of sulfur in natural rubber using X-ray absorption near-edge spectroscopy.

    Science.gov (United States)

    Pattanasiriwisawa, Wanwisa; Siritapetawee, Jaruwan; Patarapaiboolchai, Orasa; Klysubun, Wantana

    2008-09-01

    X-ray absorption near-edge spectroscopy (XANES) has been applied to natural rubber in order to study the local environment of sulfur atoms in sulfur crosslinking structures introduced in the vulcanization process. Different types of chemical accelerators in conventional, semi-efficient and efficient vulcanization systems were investigated. The experimental results show the good sensitivity and reproducibility of XANES to characterize the local geometry and electronic environment of the sulfur K-shell under various conditions of vulcanization and non-vulcanization of natural rubber. Several applications of XANES in this study demonstrate an alternative way of identifying sulfur crosslinks in treated natural rubber based on differences in their spectra and oxidation states.

  2. X-ray absorption near-edge structure (XANES) studies on Sb-doped Bi2UO6 at Bi and U edges

    Science.gov (United States)

    Yadav, A. K.; Misra, N. L.; Dhara, Sangita; Phatak, Rohan; Poswal, A. K.; Jha, S. N.; Bhattacharyya, D.

    2013-02-01

    X-ray absorption spectroscopy (XAS) measurements at Bi and U LIII edges with synchrotron radiation have been carried out on Bi2-xSbxUO6 samples for x= 0.04, 0.08, 0.12, 0.16 and 0.40 which are possible by-products of Bi based coolant and Uranium based fuels in advanced high temperature nuclear reactors. The chemical shift of the Bi absorption edges in the samples have been determined accurately from the XANES region of the X-ray absorption spectra and have been explained in terms of the difference in electronegativity values of Sb and Bi. The chemical shift of absorption edges show systematic variation only upto x = 0.08 (i.e., 4% Sb doping), which shows that the Sb enter in the matrix properly up to 4% doping concentration. The local structure of U is found to remain unchanged on Sb doping indicating clearly that Sb dopants preferably replace Bi atoms.

  3. Sulfur speciation in heavy petroleums: Information from X-ray absorption near-edge structure

    Science.gov (United States)

    Waldo, Geoffrey S.; Carlson, Robert M. K.; Moldowan, J. Michael; Peters, Kenneth E.; Penner-hahn, James E.

    1991-03-01

    The chemical speciation of sulfur in heavy petroleums, petroleum source rock extracts, and source rock pyrolysis products was studied using X-ray absorption near-edge structure (XANES) spectroscopy. The good energy resolution (ca. 0.5 eV) at the sulfur K edge and the strong dependence of XANES on the sulfur environment combine to give excellent sensitivity to changes in the electronic and structural environment of the sulfur. This has permitted identification and approximate quantitation of different classes of sulfur-containing compounds (e.g., sulfur, sulfides (including disulfides and polysulfides as a group), thiophenes, sulfoxides, sulfones, sulfinic acids, sulfonic acids, and sulfate) in a series of petroleums and petroleum source rocks. Our results indicate that the sulfur speciation of geological samples can be correlated with differences in source depositional environment, thermal maturity, and aromaticity. We report organosulfur compositions for the asphaltene, maltene, and liquid Chromatographie fractions of two sulfur-rich oils. In addition, we find that the organosulfur species in some, but not all, oils are subject to oxidation upon storage and thus may also be susceptible to oxidation in shallow reservoirs exposed to oxic waters. This work illustrates the utility of XANES as a direct spectroscopic probe for the quantitative determination of sulfur species in geological samples.

  4. Development of Position-sensitive Transition-edge Sensor X-ray Detectors

    Science.gov (United States)

    Smith, S. J.; Bandler, S. R.; Brekosky, R. P.; Brown, A.-D.; Chervenak, J. A.; Eckard, M. E.; Finkbeiner, F. M.; Kelley, R. L.; Kilbourne, C. A.; Porter, F. s.; Sad (eor. K/ E/); Figueroa-Feliciano, E.

    2008-01-01

    We report on the development of position-sensitive transition-edge sensors (PoST's) for future x-ray astronomy missions such as the International X-ray Observatory (IXO), currently under study by NASA and ESA. PoST's consist of multiple absorbers each with a different thermal coupling to one or more transition-edge sensor (TES). This differential thermal coupling between absorbers and TES's results in different characteristic pulse shapes and allows position discrimination between the different pixels. The development of PoST's is motivated by a desire to achieve maximum focal-plane area with the least number of readout channels and as such. PoST's are ideally suited to provide a focal-plane extension to the Constellation-X microcalorimeter array. We report the first experimental results of our latest one and two channel PoST's, which utilize fast thermalizing electroplated Au/Bi absorbers coupled to low noise Mo/Au TES's - a technology already successfully implemented in our arrays of single pixel TES's. We demonstrate 6 eV energy resolution coupled with spatial sensitivity in the keV energy range. We also report on the development of signal processing algorithms to optimize energy and position sensitivity of our detectors.

  5. Chemical shifts of K-X-ray absorption edges on copper in different compounds by X-ray absorption spectroscopy (XAS) with Synchrotron radiation

    Energy Technology Data Exchange (ETDEWEB)

    Joseph, D., E-mail: djoseph@barc.gov.in [Nuclear Physics Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Basu, S.; Jha, S.N.; Bhattacharyya, D. [Applied Spectroscopy Division, Bhabha Atomic Research Centre, Mumbai 400085 (India)

    2012-03-01

    Cu K X-ray absorption edges were measured in compounds such as CuO, Cu(CH{sub 3}CO{sub 2}){sub 2}, Cu(CO{sub 3}){sub 2}, and CuSO{sub 4} where Cu is present in oxidation state of 2+, using the energy dispersive EXAFS beamline at INDUS-2 Synchrotron radiation source at RRCAT, Indore. Energy shifts of {approx}4-7 eV were observed for Cu K X-ray absorption edge in the above compounds compared to its value in elemental copper. The difference in the Cu K edge energy shifts in the different compounds having same oxidation state of Cu shows the effect of different chemical environments surrounding the cation in the above compounds. The above chemical effect has been quantitatively described by determining the effective charges on Cu cations in the above compounds.

  6. Chemical shifts of K-X-ray absorption edges on copper in different compounds by X-ray absorption spectroscopy (XAS) with Synchrotron radiation

    Science.gov (United States)

    Joseph, D.; Basu, S.; Jha, S. N.; Bhattacharyya, D.

    2012-03-01

    Cu K X-ray absorption edges were measured in compounds such as CuO, Cu(CH3CO2)2, Cu(CO3)2, and CuSO4 where Cu is present in oxidation state of 2+, using the energy dispersive EXAFS beamline at INDUS-2 Synchrotron radiation source at RRCAT, Indore. Energy shifts of ˜4-7 eV were observed for Cu K X-ray absorption edge in the above compounds compared to its value in elemental copper. The difference in the Cu K edge energy shifts in the different compounds having same oxidation state of Cu shows the effect of different chemical environments surrounding the cation in the above compounds. The above chemical effect has been quantitatively described by determining the effective charges on Cu cations in the above compounds.

  7. Evaluation of bulk and surfaces absorption edge energy of sol-gel-dip-coating SnO2 thin films

    Directory of Open Access Journals (Sweden)

    Emerson Aparecido Floriano

    2010-12-01

    Full Text Available The absorption edge and the bandgap transition of sol-gel-dip-coating SnO2 thin films, deposited on quartz substrates, are evaluated from optical absorption data and temperature dependent photoconductivity spectra. Structural properties of these films help the interpretation of bandgap transition nature, since the obtained nanosized dimensions of crystallites are determinant on dominant growth direction and, thus, absorption energy. Electronic properties of the bulk and (110 and (101 surfaces are also presented, calculated by means of density functional theory applied to periodic calculations at B3LYP hybrid functional level. Experimentally obtained absorption edge is compared to the calculated energy band diagrams of bulk and (110 and (101 surfaces. The overall calculated electronic properties in conjunction with structural and electro-optical experimental data suggest that the nature of the bandgap transition is related to a combined effect of bulk and (101 surface, which presents direct bandgap transition.

  8. Theoretical characterization of X-ray absorption, emission, and photoelectron spectra of nitrogen doped along graphene edges.

    Science.gov (United States)

    Wang, Xianlong; Hou, Zhufeng; Ikeda, Takashi; Oshima, Masaharu; Kakimoto, Masa-aki; Terakura, Kiyoyuki

    2013-01-24

    K-edge X-ray absorption (XAS), emission (XES), and photoelectron (XPS) spectra of nitrogen doped along graphene edges are systematically investigated by using first-principles methods. In this study we considered pyridinium-like, pyridine-like, cyanide-like, and amine-like nitrogens at armchair and zigzag edges and pyrrole-like nitrogen at armchair edge as well as graphite-like nitrogen at graphene interior site. Our results indicate that nitrogen configuration and its location (armchair or zigzag edge) in nitrogen-doped graphene can be identified via the spectral analysis. Furthermore, some controversial spectral features observed in experiment for N-doped graphene-like materials are unambiguously assigned. The present analysis gives an explanation to the reason why the peak assignment is usually made differently between XPS and XAS.

  9. Nitrogen K-edge X-ray absorption near edge structure (XANES) spectra of purine-containing nucleotides in aqueous solution.

    Science.gov (United States)

    Shimada, Hiroyuki; Fukao, Taishi; Minami, Hirotake; Ukai, Masatoshi; Fujii, Kentaro; Yokoya, Akinari; Fukuda, Yoshihiro; Saitoh, Yuji

    2014-08-07

    The N K-edge X-ray absorption near edge structure (XANES) spectra of the purine-containing nucleotide, guanosine 5'-monophosphate (GMP), in aqueous solution are measured under various pH conditions. The spectra show characteristic peaks, which originate from resonant excitations of N 1s electrons to π* orbitals inside the guanine moiety of GMP. The relative intensities of these peaks depend on the pH values of the solution. The pH dependence is explained by the core-level shift of N atoms at specific sites caused by protonation and deprotonation. The experimental spectra are compared with theoretical spectra calculated by using density functional theory for GMP and the other purine-containing nucleotides, adenosine 5'-monophosphate, and adenosine 5'-triphosphate. The N K-edge XANES spectra for all of these nucleotides are classified by the numbers of N atoms with particular chemical bonding characteristics in the purine moiety.

  10. High-Resolution X-ray Spectroscopy of the Interstellar Medium II: Neon and Iron Absorption Edges

    CERN Document Server

    Juett, A M; Chakraborty, D; Gorczyca, T W; Juett, Adrienne M.; Schulz, Norbert S.; Chakrabarty, Deepto; Gorczyca, Thomas W.

    2006-01-01

    We present high-resolution spectroscopy of the neon K-shell and iron L-shell interstellar absorption edges in nine X-ray binaries using the High Energy Transmission Grating Spectrometer (HETGS) onboard the Chandra X-ray Observatory. We found that the iron absorption is well fit by an experimental determination of the cross-section for metallic iron, although with a slight wavelength shift of ~20 mA. The neon edge region is best fit by a model that includes the neutral neon edge and three Gaussian absorption lines. We identify these lines as due to the 1s-2p transitions from Ne II, Ne III, and Ne IX. As we found in our oxygen edge study, the theoretical predictions for neutral and low-ionization lines all require shifts of ~20 mA to match our data. Combined with our earlier oxygen edge study, we find that a best fit O/Ne ratio of 5.4+/-1.6, consistent with standard interstellar abundances. Our best fit Fe/Ne ratio of 0.20+/-0.03 is significantly lower than the interstellar value. We attribute this difference t...

  11. Near edge X-ray absorption mass spectrometry of gas phase proteins: the influence of protein size

    NARCIS (Netherlands)

    Egorov, Dmitrii; Schwob, Lucas; Lalande, Mathieu; Hoekstra, Ronnie; Schlathölter, Thomas

    2016-01-01

    Multiply protonated peptides and proteins in the gas phase can respond to near edge X-ray absorption in three different ways: (i) non dissociative ionization and ionization accompanied by loss of small neutrals, both known to dominate for proteins with masses in the 10 kDa range. (ii) Formation of i

  12. Probing ultrafast \\pi\\pi*/n\\pi* internal conversion in organic chromophores via K-edge resonant absorption

    CERN Document Server

    Wolf, T J A; Cryan, J P; Coriani, S; Squibb, R J; Battistoni, A; Berrah, N; Bostedt, C; Bucksbaum, P; Coslovich, G; Feifel, R; Gaffney, K J; Grilj, J; Martinez, T J; Miyabe, S; Moeller, S P; Mucke, M; Natan, A; Obaid, R; Osipov, T; Plekan, O; Wang, S; Koch, H; Gühr, M

    2016-01-01

    Organic chromophores with heteroatoms possess an important excited state relaxation channel from an optically allowed {\\pi}{\\pi}* to a dark n{\\pi}*state. We exploit the element and site specificity of soft x-ray absorption spectroscopy to selectively follow the electronic change during the {\\pi}{\\pi}*/n{\\pi}* internal conversion. As a hole forms in the n orbital during {\\pi}{\\pi}*/n{\\pi}* internal conversion, the near edge x-ray absorption fine structure (NEXAFS) spectrum at the heteroatom K-edge exhibits an additional resonance. We demonstrate the concept with the nucleobase thymine, a prototypical heteroatomic chromophore. With the help of time resolved NEXAFS spectroscopy at the oxygen K-edge, we unambiguously show that {\\pi}{\\pi}*/n{\\pi}* internal conversion takes place within (60 \\pm 30) fs. High-level coupled cluster calculations on the isolated molecules used in the experiment confirm the superb electronic structure sensitivity of this new method for excited state investigations.

  13. X-ray absorption near edge structure/electron energy loss near edge structure calculation using the supercell orthogonalized linear combination of atomic orbitals method.

    Science.gov (United States)

    Ching, Wai-Yim; Rulis, Paul

    2009-03-11

    Over the last eight years, a large number of x-ray absorption near edge structure (XANES) and/or electron energy loss near edge structure (ELNES) spectroscopic calculations for complex oxides and nitrides have been performed using the supercell-OLCAO (orthogonalized linear combination of atomic orbitals) method, obtaining results in very good agreement with experiments. The method takes into account the core-hole effect and includes the dipole matrix elements calculated from ab initio wavefunctions. In this paper, we describe the method in considerable detail, emphasizing the special advantages of this method for large complex systems. Selected results are reviewed and several hitherto unpublished results are also presented. These include the Y K edge of Y ions segregated to the core of a Σ31 grain boundary in alumina, O K edges of water molecules, C K edges in different types of single walled carbon nanotubes, and the Co K edge in the cyanocobalamin (vitamin B(12)) molecule. On the basis of these results, it is argued that the interpretation of specific features of the calculated XANES/ELNES edges is not simple for complex material systems because of the delocalized nature of the conduction band states. The long-standing notion of the 'fingerprinting' technique for spectral interpretation of experimental data is not tenable. A better approach is to fully characterize the structure under study, using either crystalline data or accurate ab initio modeling. Comparison between calculated XANES/ELNES spectra and available measurements enables us to ascertain the validity of the modeled structure. For complex crystals or structures, it is necessary to use the weighted sum of the spectra from structurally nonequivalent sites for comparison with the measured data. Future application of the supercell-OLCAO method to complex biomolecular systems is also discussed.

  14. X-ray absorption near edge structure/electron energy loss near edge structure calculation using the supercell orthogonalized linear combination of atomic orbitals method

    Energy Technology Data Exchange (ETDEWEB)

    Ching, W.-Y.; Rulis, Paul [Department of Physics, University of Missouri-Kansas City, Kansas City, MO 64110 (United States)

    2009-03-11

    Over the last eight years, a large number of x-ray absorption near edge structure (XANES) and/or electron energy loss near edge structure (ELNES) spectroscopic calculations for complex oxides and nitrides have been performed using the supercell-OLCAO (orthogonalized linear combination of atomic orbitals) method, obtaining results in very good agreement with experiments. The method takes into account the core-hole effect and includes the dipole matrix elements calculated from ab initio wavefunctions. In this paper, we describe the method in considerable detail, emphasizing the special advantages of this method for large complex systems. Selected results are reviewed and several hitherto unpublished results are also presented. These include the Y K edge of Y ions segregated to the core of a {sigma}31 grain boundary in alumina, O K edges of water molecules, C K edges in different types of single walled carbon nanotubes, and the Co K edge in the cyanocobalamin (vitamin B{sub 12}) molecule. On the basis of these results, it is argued that the interpretation of specific features of the calculated XANES/ELNES edges is not simple for complex material systems because of the delocalized nature of the conduction band states. The long-standing notion of the 'fingerprinting' technique for spectral interpretation of experimental data is not tenable. A better approach is to fully characterize the structure under study, using either crystalline data or accurate ab initio modeling. Comparison between calculated XANES/ELNES spectra and available measurements enables us to ascertain the validity of the modeled structure. For complex crystals or structures, it is necessary to use the weighted sum of the spectra from structurally nonequivalent sites for comparison with the measured data. Future application of the supercell-OLCAO method to complex biomolecular systems is also discussed.

  15. X-ray absorption near edge structure/electron energy loss near edge structure calculation using the supercell orthogonalized linear combination of atomic orbitals method

    Science.gov (United States)

    Ching, Wai-Yim; Rulis, Paul

    2009-03-01

    Over the last eight years, a large number of x-ray absorption near edge structure (XANES) and/or electron energy loss near edge structure (ELNES) spectroscopic calculations for complex oxides and nitrides have been performed using the supercell-OLCAO (orthogonalized linear combination of atomic orbitals) method, obtaining results in very good agreement with experiments. The method takes into account the core-hole effect and includes the dipole matrix elements calculated from ab initio wavefunctions. In this paper, we describe the method in considerable detail, emphasizing the special advantages of this method for large complex systems. Selected results are reviewed and several hitherto unpublished results are also presented. These include the Y K edge of Y ions segregated to the core of a Σ31 grain boundary in alumina, O K edges of water molecules, C K edges in different types of single walled carbon nanotubes, and the Co K edge in the cyanocobalamin (vitamin B12) molecule. On the basis of these results, it is argued that the interpretation of specific features of the calculated XANES/ELNES edges is not simple for complex material systems because of the delocalized nature of the conduction band states. The long-standing notion of the 'fingerprinting' technique for spectral interpretation of experimental data is not tenable. A better approach is to fully characterize the structure under study, using either crystalline data or accurate ab initio modeling. Comparison between calculated XANES/ELNES spectra and available measurements enables us to ascertain the validity of the modeled structure. For complex crystals or structures, it is necessary to use the weighted sum of the spectra from structurally nonequivalent sites for comparison with the measured data. Future application of the supercell-OLCAO method to complex biomolecular systems is also discussed.

  16. Near Edge X-Ray Absorption Fine Structure Spectroscopy with X-Ray Free-Electron Lasers

    Energy Technology Data Exchange (ETDEWEB)

    Bernstein, D.P.; Acremann, Y.; Scherz, A.; Burkhardt, M.; Stohr, J.; /SLAC; Beye, M.; Schlotter, W.F.; Beeck, T.; Sorgenfrei, F.; Pietzsch, A.; Wurth, W.; Fohlisch, A.; /Hamburg U.

    2009-12-11

    We demonstrate the feasibility of Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy on solids by means of femtosecond soft x-ray pulses from a free-electron laser (FEL). Our experiments, carried out at the Free-Electron Laser at Hamburg (FLASH), used a special sample geometry, spectrographic energy dispersion, single shot position-sensitive detection and a data normalization procedure that eliminates the severe fluctuations of the incident intensity in space and photon energy. As an example we recorded the {sup 3}D{sub 1} N{sub 4,5}-edge absorption resonance of La{sup 3+}-ions in LaMnO{sub 3}. Our study opens the door for x-ray absorption measurements on future x-ray FEL facilities.

  17. Single-step absorption and phase retrieval with polychromatic x rays using a spectral detector.

    Science.gov (United States)

    Gürsoy, Doğa; Das, Mini

    2013-05-01

    In this Letter, we present a single-step method to simultaneously retrieve x-ray absorption and phase images valid for a broad range of imaging energies and material properties. Our method relies on the availability of spectrally resolved intensity measurements, which is now possible using semiconductor x-ray photon counting detectors. The retrieval method is derived and presented, with results showing good agreement.

  18. Near-Edge X-ray Absorption Fine Structure Spectroscopy of Diamondoid Thiol Monolayers on Gold

    Energy Technology Data Exchange (ETDEWEB)

    Willey, T M; Fabbri, J; Lee, J I; Schreiner, P; Fokin, A A; Tkachenko, B A; Fokina, N A; Dahl, J; Carlson, B; Vance, A L; Yang, W; Terminello, L J; van Buuren, T; Melosh, N

    2007-11-27

    Diamondoids, hydrocarbon molecules with cubic-diamond-cage structures, have unique properties with potential value for nanotechnology. The availability and ability to selectively functionalize this special class of nanodiamond materials opens new possibilities for surface-modification, for high-efficiency field emitters in molecular electronics, as seed crystals for diamond growth, or as robust mechanical coatings. The properties of self-assembled monolayers (SAMs) of diamondoids are thus of fundamental interest for a variety of emerging applications. This paper presents the effects of thiol substitution position and polymantane order on diamondoid SAMs on gold using near-edge X-ray absorption fine structure spectroscopy (NEXAFS) and X-ray photoelectron spectroscopy (XPS). A framework to determine both molecular tilt and twist through NEXAFS is presented and reveals highly ordered diamondoid SAMs, with the molecular orientation controlled by the thiol location. C 1s and S 2p binding energies are lower in adamantane thiol than alkane thiols on gold by 0.67 {+-} 0.05 eV and 0.16 {+-} 0.04 eV respectively. These binding energies vary with diamondoid monolayer structure and thiol substitution position, consistent with different amounts of steric strain and electronic interaction with the substrate. This work demonstrates control over the assembly, in particular the orientational and electronic structure, providing a flexible design of surface properties with this exciting new class of diamond clusters.

  19. Changes in the electronic structure of highly compressed iron revealed by X-ray fluorescence lines and absorption edges

    Science.gov (United States)

    Hansen, S. B.; Harding, E. C.; Knapp, P. F.; Gomez, M. R.; Nagayama, T.; Bailey, J. E.

    2017-09-01

    We present high-resolution spectroscopic data from iron impurities in beryllium liners driven by Sandia's Z machine to temperatures near 10 eV and electron densities near 2 × 1024 cm-3, conditions independently diagnosed from the transmission depth and shape of the iron K-edge. A 12-eV redshift is observed in the Fe Kβ fluorescence line along with few-eV shifts in the Fe Kα lines and Fe K-shell absorption edge. While the measured edge shift disagrees with several common models of ionization potential depression, both line and edge shifts are in good agreement with the predictions of a self-consistent model based on density functional theory.

  20. Comparison of x-ray absorption spectra between water and ice: New ice data with low pre-edge absorption cross-section

    OpenAIRE

    Kaya, Sarp; Sellberg, Jonas A.; Segtnan, Vegard H.; Chen, Chen; Tyliszczak, Tolek; Ogasawara, Hirohito; Nordlund, Dennis; Pettersson, Lars G. M.; Nilsson, Anders

    2014-01-01

    The effect of crystal growth conditions on the O K-edge x-ray absorption spectra of ice is investigated through detailed analysis of the spectral features. The amount of ice defects is found to be minimized on hydrophobic surfaces, such as BaF2(111), with low concentration of nucleation centers. This is manifested through a reduction of the absorption cross-section at 535 eV, which is associated with distorted hydrogen bonds. Furthermore, a connection is made between the observed increase in ...

  1. Studies by Near Edge X-ray Absorption Spectroscopies of Bonding Dynamics at the Graphene/Guanine Interface - A Proposal for High Mobility, Organic Graphene Field Effect Transistors

    Science.gov (United States)

    2015-07-01

    AFRL-AFOSR-UK-TR-2015-0034 Studies by Near Edge X-ray Absorption Spectroscopies of Bonding Dynamics at the Graphene/Guanine...April 2015 4. TITLE AND SUBTITLE Studies by Near Edge X-ray Absorption Spectroscopies of Bonding Dynamics at the Graphene/Guanine Interface - A

  2. Experimental hole densities in HgBa2Can-1CunO2n+2+delta compounds from near-edge x-ray-absorption spectroscopy

    NARCIS (Netherlands)

    Pellegrin, E; Fink, J; Chen, CT; Xiong, Q; Lin, QM; Chu, CW

    1996-01-01

    Near-edge x-ray-absorption spectroscopy measurements have been performed on the O K'- and Cu L-absorption edges on a series of underdoped and optimally doped HgBa2Can-1CunO2n+2+delta samples in order to get quantitative information on the changes in the electronic structure under doping with excess

  3. Calculation of optical and K pre-edge absorption spectra for ferrous iron of distorted sites in oxide crystals

    Science.gov (United States)

    Vercamer, Vincent; Hunault, Myrtille O. J. Y.; Lelong, Gérald; Haverkort, Maurits W.; Calas, Georges; Arai, Yusuke; Hijiya, Hiroyuki; Paulatto, Lorenzo; Brouder, Christian; Arrio, Marie-Anne; Juhin, Amélie

    2016-12-01

    Advanced semiempirical calculations have been performed to compute simultaneously optical absorption and K pre-edge x-ray absorption spectra of Fe2 + in four distinct site symmetries found in minerals. The four symmetries, i.e., a distorted octahedron, a distorted tetrahedron, a square planar site, and a trigonal bipyramidal site, are representative of the Fe2 + sites found in crystals and glasses. A particular attention has been paid to the definition of the p -d hybridization Hamiltonian which occurs for noncentrosymmetric symmetries in order to account for electric dipole transitions. For the different sites under study, an excellent agreement between calculations and experiments was found for both optical and x-ray absorption spectra, in particular in terms of relative intensities and energy positions of electronic transitions. To our knowledge, these are the first calculations of optical absorption spectra on Fe2 + placed in such diverse site symmetries, including centrosymmetric sites. The proposed theoretical model should help to interpret the features of both the optical absorption and the K pre-edge absorption spectra of 3 d transition metal ions and to go beyond the usual fingerprint interpretation.

  4. Plasmonic structure integrated single-photon detector configurations to improve absorptance and polarization contrast

    CERN Document Server

    Csete, Maria; Szenes, Andras; Szalai, Aniko; Szabo, Gabor

    2014-01-01

    Configurations capable of maximizing both absorptance and polarization contrast were determined for 1550 nm polarized light illumination of different plasmonic structure integrated superconducting nanowire single-photon detectors (SNSPDs) consisting of p=264 nm and P=792 nm periodic niobium-nitride (NbN) patterns on silica substrate. Global NbN absorptance maxima appear in case of p/s-polarized light illumination in S/P-orientation (gamma=90 azimuthal angle) and the highest polarization contrast is attained in S-orientation of all devices. Common nanophotonical origin of absorptance enhancement is collective resonance on nano-cavity-gratings with different profiles, which is promoted by coupling between localized modes in quarter wavelength MIM nano-cavities and laterally synchronized Brewster-Zenneck-type surface waves in integrated SNSPDs possessing a three-quarter-wavelength-scaled periodicity. The spectral sensitivity and dispersion characteristics reveal that device design specific optimal configurations...

  5. Communication: Near edge x-ray absorption fine structure spectroscopy of aqueous adenosine triphosphate at the carbon and nitrogen K-edges.

    Science.gov (United States)

    Kelly, Daniel N; Schwartz, Craig P; Uejio, Janel S; Duffin, Andrew M; England, Alice H; Saykally, Richard J

    2010-09-14

    Near edge x-ray absorption fine structure (NEXAFS) spectroscopy at the nitrogen and carbon K-edges was used to study the hydration of adenosine triphosphate in liquid microjets. The total electron yield spectra were recorded as a function of concentration, pH, and the presence of sodium, magnesium, and copper ions (Na(+)/Mg(2+)/Cu(2+)). Significant spectral changes were observed upon protonation of the adenine ring, but not under conditions that promote π-stacking, such as high concentration or presence of Mg(2+), indicating that NEXAFS is insensitive to the phenomenon. Intramolecular inner-sphere association of Cu(2+) did create observable broadening of the nitrogen spectrum, whereas outer-sphere association with Mg(2+) did not.

  6. Li K-edge X-ray absorption near edge structure spectra for a library of lithium compounds applied in lithium batteries

    Science.gov (United States)

    Wang, Dongniu; Zuin, Lucia

    2017-01-01

    Lithium ion batteries (LIB) have achieved great success as energy supply systems in portable devices and in electrical vehicles. Identifying the local chemical structures of elemental lithium in lithium compounds is beneficial for improving understanding of battery components and performance. Herein, a library of Li K-edge X-ray absorption near edge structure (XANES) of lithium compounds relevant to Li-ion batteries is reported. Materials described include lithium metals (anode), Li-containing cathodes, electrolytes and solid electrolyte interphase (SEI). The results illustrate the characteristic spectral features stemming from the various electronic structures and chemical environment of lithium atoms for each and every possible battery component. XANES spectra of Sn based anode after discharging reveal the appearance of Li2CO3 on electrode surface. X-ray damage on sensitive lithium species is also assessed; the results reveal that more attention should be paid to irradiation effects to conduct XANES measurements for battery materials properly.

  7. Absorption and scattering by interstellar dust in the silicon K-edge of GX 5-1

    Science.gov (United States)

    Zeegers, S. T.; Costantini, E.; de Vries, C. P.; Tielens, A. G. G. M.; Chihara, H.; de Groot, F.; Mutschke, H.; Waters, L. B. F. M.; Zeidler, S.

    2017-03-01

    Context. We study the absorption and scattering of X-ray radiation by interstellar dust particles, which allows us to access the physical and chemical properties of dust. The interstellar dust composition is not well understood, especially on the densest sight lines of the Galactic plane. X-rays provide a powerful tool in this study. Aims: We present newly acquired laboratory measurements of silicate compounds taken at the Soleil synchrotron facility in Paris using the Lucia beamline. The dust absorption profiles resulting from this campaign were used in this pilot study to model the absorption by interstellar dust along the line of sight of the low-mass X-ray binary GX 5-1. Methods: The measured laboratory cross-sections were adapted for astrophysical data analysis and the resulting extinction profiles of the Si K-edge were implemented in the SPEX spectral fitting program. We derive the properties of the interstellar dust along the line of sight by fitting the Si K-edge seen in absorption in the spectrum of GX 5-1. Results: We measured the hydrogen column density towards GX 5-1 to be 3.40 ± 0.1 × 1022 cm-2. The best fit of the silicon edge in the spectrum of GX 5-1 is obtained by a mixture of olivine and pyroxene. In this study, our modeling is limited to Si absorption by silicates with different Mg:Fe ratios. We obtained an abundance of silicon in dust of 4.0 ± 0.3 × 10-5 per H atom and a lower limit for total abundance, considering both gas and dust of >4.4 × 10-5 per H atom, which leads to a gas to dust ratio of >0.22. Furthermore, an enhanced scattering feature in the Si K-edge may suggest the presence of large particles along the line of sight.

  8. Mn K-Edge X-ray Absorption Studies of Oxo- and Hydroxo-manganese(IV) Complexes: Experimental and Theoretical Insights into Pre-Edge Properties

    Science.gov (United States)

    2015-01-01

    Mn K-edge X-ray absorption spectroscopy (XAS) was used to gain insights into the geometric and electronic structures of [MnII(Cl)2(Me2EBC)], [MnIV(OH)2(Me2EBC)]2+, and [MnIV(O)(OH)(Me2EBC)]+, which are all supported by the tetradentate, macrocyclic Me2EBC ligand (Me2EBC = 4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane). Analysis of extended X-ray absorption fine structure (EXAFS) data for [MnIV(O)(OH)(Me2EBC)]+ revealed Mn–O scatterers at 1.71 and 1.84 Å and Mn–N scatterers at 2.11 Å, providing the first unambiguous support for the formulation of this species as an oxohydroxomanganese(IV) adduct. EXAFS-determined structural parameters for [MnII(Cl)2(Me2EBC)] and [MnIV(OH)2(Me2EBC)]2+ are consistent with previously reported crystal structures. The Mn pre-edge energies and intensities of these complexes were examined within the context of data for other oxo- and hydroxomanganese(IV) adducts, and time-dependent density functional theory (TD-DFT) computations were used to predict pre-edge properties for all compounds considered. This combined experimental and computational analysis revealed a correlation between the Mn–O(H) distances and pre-edge peak areas of MnIV=O and MnIV–OH complexes, but this trend was strongly modulated by the MnIV coordination geometry. Mn 3d-4p mixing, which primarily accounts for the pre-edge intensities, is not solely a function of the Mn–O(H) bond length; the coordination geometry also has a large effect on the distribution of pre-edge intensity. For tetragonal MnIV=O centers, more than 90% of the pre-edge intensity comes from excitations to the Mn=O σ* MO. Trigonal bipyramidal oxomanganese(IV) centers likewise feature excitations to the Mn=O σ* molecular orbital (MO) but also show intense transitions to 3dx2–y2 and 3dxy MOs because of enhanced 3d-4px,y mixing. This gives rise to a broader pre-edge feature for trigonal MnIV=O adducts. These results underscore the importance of reporting experimental pre-edge areas

  9. Reducing edge effects and improving position resolution in position sensitive NaI(Tl) detectors

    Energy Technology Data Exchange (ETDEWEB)

    Freifelder, R.; Haigh, A.T.; Karp, J.S. (Univ. of Pennsylvania, Philadelphia (United States))

    1993-04-01

    Large two dimensional position sensitive NaI (Tl) crystals used in positron emission tomographs and elsewhere normally have gaps or inactive, unusable areas at the edges. Experiments aimed at reducing these edge effects have been performed. Unencapsulated crystals have been used to test the feasibility of optically coupling crystals together to decrease gap size. Other experiments increased the sampling of the scintillation light at the edges in order to obtain better position sensitivity. Work was also performed to treat the edges to reduce unwanted reflections and increase the position sensitive area. Finally, experiments aimed at improving the position resolution throughout the crystal as well as at the edges were performed.

  10. K-edge imaging with the XPAD3 hybrid pixel detector, direct comparison of CdTe and Si sensors.

    Science.gov (United States)

    Cassol, F; Portal, L; Graber-Bolis, J; Perez-Ponce, H; Dupont, M; Kronland, C; Boursier, Y; Blanc, N; Bompard, F; Boudet, N; Buton, C; Clémens, J C; Dawiec, A; Debarbieux, F; Delpierre, P; Hustache, S; Vigeolas, E; Morel, C

    2015-07-21

    We investigate the improvement from the use of high-Z CdTe sensors for pre-clinical K-edge imaging with the hybrid pixel detectors XPAD3. We compare XPAD3 chips bump bonded to Si or CdTe sensors in identical experimental conditions. Image performance for narrow energy bin acquisitions and contrast-to-noise ratios of K-edge images are presented and compared. CdTe sensors achieve signal-to-noise ratios at least three times higher than Si sensors within narrow energy bins, thanks to their much higher detection efficiency. Nevertheless Si sensors provide better contrast-to-noise ratios in K-edge imaging when working at equivalent counting statistics, due to their better estimation of the attenuation coefficient of the contrast agent. Results are compared to simulated data in the case of the XPAD3/Si detector. Good agreement is observed when including charge sharing between pixels, which have a strong impact on contrast-to-noise ratios in K-edge images.

  11. A digital X-ray imaging system based on silicon strip detectors working in edge-on configuration

    Energy Technology Data Exchange (ETDEWEB)

    Bolanos, L. [CEADEN, Calle 30 502 e/ 5ta y 7ma Avenida, Playa, Ciudad Habana (Cuba); Boscardin, M. [IRST, Fondazione Bruno Kessler, Via Sommarive 18, Povo, 38100 Trento (Italy); Cabal, A.E. [CEADEN, Calle 30 502 e/ 5ta y 7ma Avenida, Playa, Ciudad Habana (Cuba); Diaz, M. [InSTEC, Ave. Salvador Allende esq. Luaces, Quinta de los Molinos, Ciudad Habana (Cuba); Grybos, P.; Maj, P. [Faculty of Electrical Engineering, Automatics, Computer Science and Electronics, Department of Measurement and Instrumentation, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Cracow (Poland); Prino, F. [Istituto Nazionale di Fisica Nucleare, Sezione di Torino, Via P. Giuria 1, 10125 Torino (Italy); Ramello, L. [Dipartimento di Scienze e Tecnologie Avanzate, Universita del Piemonte Orientale, Via T. Michel 11, 15100 Alessandria (Italy)], E-mail: luciano.ramello@mfn.unipmn.it; Szczygiel, R. [Faculty of Electrical Engineering, Automatics, Computer Science and Electronics, Department of Measurement and Instrumentation, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Cracow (Poland)

    2009-09-21

    We present the energy resolution and imaging performance of a digital X-ray imaging system based on a 512-strip silicon strip detector (SSD) working in the edge-on configuration. The SSDs tested in the system are 300 {mu}m thick with 1 or 2-cm-long strips and 100 {mu}m pitch. To ensure a very small dead area of the SSD working in edge-on configuration, the detector is cut perpendicular to the strips at a distance of only 20 {mu}m from the end of the strips. The 512-strip silicon detector is read out by eight 64-channel integrated circuits called DEDIX [Grybos et al., IEEE Trans. Nucl. Sci. NS-54 (2007) 1207]. The DEDIX IC operates in a single photon counting mode with two independent amplitude discriminators per channel. The readout electronic channel connected to a detector with effective input capacitance of about 2 pF has an average equivalent noise charge (ENC) of about 163 el. rms and is able to count 1 Mcps of average rate of input pulses. The system consisting of 512 channels has an excellent channel-to-channel uniformity-the effective threshold spread calculated to the charge-sensitive amplifier inputs is 12 el. rms (at one sigma level). With this system a few test images of a phantom have been taken in the 10-30 keV energy range.

  12. Iron speciation in human cancer cells by K-edge total reflection X-ray fluorescence-X-ray absorption near edge structure analysis

    Energy Technology Data Exchange (ETDEWEB)

    Polgari, Zs. [Eoetvoes Lorand University, Institute of Chemistry, Department of Analytical Chemistry, Laboratory of Environmental Chemistry and Bioanalytics, P.O. Box 32, H-1518, Budapest (Hungary); Meirer, F. [Institute of Atomic and Subatomic Physics, Vienna University of Technology, Vienna (Austria); MiNALab, CMM-irst, Fondazione Bruno Kessler, Povo, Trento (Italy); Sasamori, S.; Ingerle, D. [Institute of Atomic and Subatomic Physics, Vienna University of Technology, Vienna (Austria); Pepponi, G. [MiNALab, CMM-irst, Fondazione Bruno Kessler, Povo, Trento (Italy); Streli, C. [Institute of Atomic and Subatomic Physics, Vienna University of Technology, Vienna (Austria); Rickers, K. [Hamburger Synchrotronstrahlungslabor at DESY, Hamburg (Germany); Reti, A.; Budai, B. [Department of Clinical Research, National Institute of Oncology, Budapest (Hungary); Szoboszlai, N. [Eoetvoes Lorand University, Institute of Chemistry, Department of Analytical Chemistry, Laboratory of Environmental Chemistry and Bioanalytics, P.O. Box 32, H-1518, Budapest (Hungary); Zaray, G., E-mail: zaray@ludens.elte.hu [Eoetvoes Lorand University, Institute of Chemistry, Department of Analytical Chemistry, Laboratory of Environmental Chemistry and Bioanalytics, P.O. Box 32, H-1518, Budapest (Hungary)

    2011-03-15

    X-ray absorption near edge structure (XANES) analysis in combination with synchrotron radiation induced total reflection X-ray fluorescence (SR-TXRF) acquisition was used to determine the oxidation state of Fe in human cancer cells and simultaneously their elemental composition by applying a simple sample preparation procedure consisting of pipetting the cell suspension onto the quartz reflectors. XANES spectra of several inorganic and organic iron compounds were recorded and compared to that of different cell lines. The XANES spectra of cells, independently from the phase of cell growth and cell type were very similar to that of ferritin, the main Fe store within the cell. The spectra obtained after CoCl{sub 2} or NiCl{sub 2} treatment, which could mimic a hypoxic state of cells, did not differ noticeably from that of the ferritin standard. After 5-fluorouracil administration, which could also induce an oxidative-stress in cells, the absorption edge position was shifted toward higher energies representing a higher oxidation state of Fe. Intense treatment with antimycin A, which inhibits electron transfer in the respiratory chain, resulted in minor changes in the spectrum, resembling rather the N-donor Fe-{alpha},{alpha}'-dipyridyl complex at the oxidation energy of Fe(III), than ferritin. The incorporation of Co and Ni in the cells was followed by SR-TXRF measurements.

  13. Chemical shift of Mn and Cr K-edges in X-ray absorption spectroscopy with synchrotron radiation

    Indian Academy of Sciences (India)

    D Joseph; A K Yadav; S N Jha; D Bhattacharyya

    2013-11-01

    Mn and Cr K X-ray absorption edges were measured in various compounds containing Mn in Mn2+, Mn3+ and Mn4+ oxidation states and Cr in Cr3+ and Cr6+ oxidation states. Few compounds possess tetrahedral coordination in the 1st shell surrounding the cation while others possess octahedral coordination. Measurements have been carried out at the energy dispersive EXAFS beamline at INDUS-2 Synchrotron Radiation Source at Raja Ramanna Centre for Advanced Technology, Indore. Energy shifts of ∼8–16 eV were observed for Mn K edge in the Mn-compounds while a shift of 13–20 eV was observed for Cr K edge in Cr-compounds compared to values in elementalMn and Cr, respectively. The different chemical shifts observed for compounds having the same oxidation state of the cation but different anions or ligands show the effect of different chemical environments surrounding the cations in determining their X-ray absorption edges in the above compounds. The above chemical effect has been quantitatively described by determining the effective charges on Mn and Cr cations in the above compounds.

  14. Analytic model of energy-absorption response functions in compound X-ray detector materials.

    Science.gov (United States)

    Yun, Seungman; Kim, Ho Kyung; Youn, Hanbean; Tanguay, Jesse; Cunningham, Ian A

    2013-10-01

    The absorbed energy distribution (AED) in X-ray imaging detectors is an important factor that affects both energy resolution and image quality through the Swank factor and detective quantum efficiency. In the diagnostic energy range (20-140 keV), escape of characteristic photons following photoelectric absorption and Compton scatter photons are primary sources of absorbed-energy dispersion in X-ray detectors. In this paper, we describe the development of an analytic model of the AED in compound X-ray detector materials, based on the cascaded-systems approach, that includes the effects of escape and reabsorption of characteristic and Compton-scatter photons. We derive analytic expressions for both semi-infinite slab and pixel geometries and validate our approach by Monte Carlo simulations. The analytic model provides the energy-dependent X-ray response function of arbitrary compound materials without time-consuming Monte Carlo simulations. We believe this model will be useful for correcting spectral distortion artifacts commonly observed in photon-counting applications and optimal design and development of novel X-ray detectors.

  15. Nitrogen K-edge X-ray absorption near edge structure (XANES) spectra of purine-containing nucleotides in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Shimada, Hiroyuki; Fukao, Taishi; Minami, Hirotake; Ukai, Masatoshi [Department of Applied Physics, Tokyo University of Agriculture and Technology, Koganei-shi, Tokyo 184-8588 (Japan); Fujii, Kentaro; Yokoya, Akinari [Advanced Science Research Center, Japan Atomic Energy Agency, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Fukuda, Yoshihiro; Saitoh, Yuji [Synchrotron Radiation Research Center, Japan Atomic Energy Agency, Sayo-gun, Hyougo 679-5148 (Japan)

    2014-08-07

    The N K-edge X-ray absorption near edge structure (XANES) spectra of the purine-containing nucleotide, guanosine 5{sup ′}-monophosphate (GMP), in aqueous solution are measured under various pH conditions. The spectra show characteristic peaks, which originate from resonant excitations of N 1s electrons to π* orbitals inside the guanine moiety of GMP. The relative intensities of these peaks depend on the pH values of the solution. The pH dependence is explained by the core-level shift of N atoms at specific sites caused by protonation and deprotonation. The experimental spectra are compared with theoretical spectra calculated by using density functional theory for GMP and the other purine-containing nucleotides, adenosine 5{sup ′}-monophosphate, and adenosine 5{sup ′}-triphosphate. The N K-edge XANES spectra for all of these nucleotides are classified by the numbers of N atoms with particular chemical bonding characteristics in the purine moiety.

  16. Comparison of quantitative k-edge empirical estimators using an energy-resolved photon-counting detector

    Science.gov (United States)

    Zimmerman, Kevin C.; Gilat Schmidt, Taly

    2016-03-01

    Using an energy-resolving photon counting detector, the amount of k-edge material in the x-ray path can be estimated using a process known as material decomposition. However, non-ideal effects within the detector make it difficult to accurately perform this decomposition. This work evaluated the k-edge material decomposition accuracy of two empirical estimators. A neural network estimator and a linearized maximum likelihood estimator with error look-up tables (A-table method) were evaluated through simulations and experiments. Each estimator was trained on system-specific calibration data rather than specific modeling of non-ideal detector effects or the x-ray source spectrum. Projections through a step-wedge calibration phantom consisting of different path lengths through PMMA, aluminum, and a k-edge material was used to train the estimators. The estimators were tested by decomposing data acquired through different path lengths of the basis materials. The estimators had similar performance in the chest phantom simulations with gadolinium. They estimated four of the five densities of gadolinium with less than 2mg/mL bias. The neural networks estimates demonstrated lower bias but higher variance than the A-table estimates in the iodine contrast agent simulations. The neural networks had an experimental variance lower than the CRLB indicating it is a biased estimator. In the experimental study, the k-edge material contribution was estimated with less than 14% bias for the neural network estimator and less than 41% bias for the A-table method.

  17. Improvement of infrared single-photon detectors absorptance by integrated plasmonic structures

    CERN Document Server

    Csete, M; Szalai, A; Najafi, F; Berggren, K K

    2012-01-01

    The absorptance of p-polarized light in superconducting-nanowire single-photon detectors (SNSPDs) was improved by integrating (1) ~quarter-wavelength nano-optical cavity closed by a gold reflector (OC-SNSPD), (2) nano-cavity-array closed by vertical and horizontal gold segments (NCAI-SNSPD), and (3) nano-cavity-deflector-array consisting of longer vertical gold segments (NCDAI-SNSPD) into short- (p-) and long- (3p-) periodic niobium-nitride (NbN) stripe-patterns. In OC-SNSPDs the highest absorptance is observable at perpendicular incidence onto NbN stripes in P-orientation due to E-field concentration at the bottom of nano-optical cavities. In short-periodic NCAI-SNSPDs off-axis illumination results in almost polar-angle-independent perfect absorptance due to collective resonances on plasmonic MIM nano-cavity-arrays in S-orientation. In long-periodic NCAI-SNSPDs the surface wave-excitation phenomena promoting EM-field transportation to the NbN stripes in S-orientation are capable of resulting in local absorpt...

  18. A system model for pinhole SPECT simulating edge penetration, detector, and pinhole response and non-uniform attenuation

    Science.gov (United States)

    Wietholt, Christian; Hsiao, Ing-Tsung; Chen, Chin-Tu

    2007-03-01

    Small animal SPECT using low energy photons of I-125 and approaching resolutions of microscopic levels, imaging parameters such as pinhole edge penetration, detector blur, geometric response, detector and pinhole misalignment, and gamma photon attenuation and scatter can have increasingly noticeable and/or adverse effects on reconstructed image quality. Iterative reconstruction algorithms, the widelyaccepted standard for emission tomography, allow modeling of such parameters through a system matrix. For this Monte Carlo simulation study, non-uniform attenuation correction was added to the existing system model. The model was constructed using ray-tracing and further included corrections for edge penetration, detector blur, and geometric aperture response. For each ray passing through different aperture locations, this method attenuates a voxel's contribution to a detector element along the photon path, which is then weighted according to a pinhole penetration model. To lower the computational and memory expenses, symmetry along the detector axes and an incremental storage scheme for the system model were used. For evaluating the nonuniform attenuation correction method, 3 phantoms were designed of which projection images were simulated using Monte Carlo methods. The first phantom was used to examined skin artifacts, the second to simulate attenuation by bone, and the third to generate artifacts of an air-filled space surrounded by soft tissue. In reconstructions without attenuation correction, artifacts were observed with up to a 40% difference in activity. These could be corrected using the implemented method, although in one case overcorrection occurred. Overall, attenuation correction improved reconstruction accuracy of the radioisotope distribution in the presence of structural differences.

  19. Testing sTGC with small angle wire edges for the ATLAS New Small Wheel Muon Detector Upgrade

    CERN Document Server

    Roth, Itamar; Duchovni, Ehud

    2015-01-01

    The LHC upgrade scheduled for 2018 is expected to significantly increase the accelerator's luminosity, and as a result the radiation background rates in the ATLAS Muon Spectrometer will increase too. Some of its components will have to be replaced in order to cope with these high rates. Newly designed small-strip Thin Gap chambers (sTGC) will replace them at the small wheel region. One of the differences between the sTGC and the currently used TGC is the alignment of the wires along the azimuthal direction. As a result, the outermost wires approach the detector's edge with a small angle. Such a configuration may be a cause for various problems. Two small dedicated chambers were built and tested in order to study possible edge effects that may arise from the new configuration. The sTGC appears to be stable and no spark have been observed, yet some differences in the detector response near the edge is seen and further studies should be carried out.

  20. Radiative ablation with two ionizing-fronts when opacity displays a sharp absorption edge

    CERN Document Server

    Poujade, Olivier; Vandenboomgaerde, Marc

    2014-01-01

    The interaction of a strong flux of photons with matter through an ionizing-front (I-front) is an ubiquitous phenomenon in the context of astrophysics and inertial confinement fusion (ICF) where intense sources of radiation put matter into motion. When the opacity of the irradiated material varies continuously in the radiation spectral domain, only one single I-front is formed. In contrast, as numerical simulations tend to show, when the opacity of the irradiated material presents a sharp edge in the radiation spectral domain, a second I-front (an edge-front) can form. A full description of the mechanism behind the formation of this edge-front is presented in this article. It allows to understand supernumerary shocks (edge-shocks), displayed by ICF simulations, that might affect the robustness of the design of fusion capsules in actual experiments. Moreover, it may have consequences in various domains of astrophysics where ablative flows occur.

  1. Quantitative uranium speciation with U M{sub 4,5}-edge HERFD absorption spectra

    Energy Technology Data Exchange (ETDEWEB)

    Kvashnina, Kristina O.; Rossberg, Andre [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Molecular Structures

    2017-06-01

    This report gives a brief description of the quantitative uranium speciation performed by iterative transformation factor analysis (ITFA) of High Energy Resolution X-ray Fluorescence Detection (HERFD) data collected at the M{sub 4,5} edge.

  2. Near-edge x-ray absorption fine structure measurements using a laboratory-scale XUV source

    Science.gov (United States)

    Peth, Christian; Barkusky, Frank; Mann, Klaus

    2008-05-01

    We present a compact setup for near-edge x-ray absorption spectroscopy at the carbon K-edge based on a laser-driven plasma source. To generate the required broad-band emission in the spectral range of the 'water window' (λ = 2.2-4.4 nm) a krypton gas puff target was used. The table-top setup consisting basically of the laser-plasma source and a flat-field spectrometer can be used for near-edge x-ray absorption fine structure experiments in transmission as well as reflection under grazing incidence conditions (ReflEXAFS). The latter method offers the advantage that thin film preparation is not necessary and that the surface sensitivity is strongly enhanced. The results obtained for thin polymer films show good agreement with synchrotron data. Furthermore, we use the ReflEXAFS method to investigate changes in the chemical composition of PMMA induced by extreme ultraviolet (EUV) radiation. The spectra indicate a loss of the carbonyl functional group upon irradiation as well as crosslinking effects at high EUV radiation doses.

  3. Isotope effects in liquid water probed by transmission mode x-ray absorption spectroscopy at the oxygen K-edge

    Science.gov (United States)

    Schreck, Simon; Wernet, Philippe

    2016-09-01

    The effects of isotope substitution in liquid water are probed by x-ray absorption spectroscopy at the O K-edge as measured in transmission mode. Confirming earlier x-ray Raman scattering experiments, the D2O spectrum is found to be blue shifted with respect to H2O, and the D2O spectrum to be less broadened. Following the earlier interpretations of UV and x-ray Raman spectra, the shift is related to the difference in ground-state zero-point energies between D2O and H2O, while the difference in broadening is related to the difference in ground-state vibrational zero-point distributions. We demonstrate that the transmission-mode measurements allow for determining the spectral shapes with unprecedented accuracy. Owing in addition to the increased spectral resolution and signal to noise ratio compared to the earlier measurements, the new data enable the stringent determination of blue shift and broadening in the O K-edge x-ray absorption spectrum of liquid water upon isotope substitution. The results are compared to UV absorption data, and it is discussed to which extent they reflect the differences in zero-point energies and vibrational zero-point distributions in the ground-states of the liquids. The influence of the shape of the final-state potential, inclusion of the Franck-Condon structure, and differences between liquid H2O and D2O resulting from different hydrogen-bond environments in the liquids are addressed. The differences between the O K-edge absorption spectra of water from our transmission-mode measurements and from the state-of-the-art x-ray Raman scattering experiments are discussed in addition. The experimentally extracted values of blue shift and broadening are proposed to serve as a test for calculations of ground-state zero-point energies and vibrational zero-point distributions in liquid H2O and D2O. This clearly motivates the need for new calculations of the O K-edge x-ray absorption spectrum of liquid water.

  4. Edge pixel response studies of edgeless silicon sensor technology for pixellated imaging detectors

    Science.gov (United States)

    Maneuski, D.; Bates, R.; Blue, A.; Buttar, C.; Doonan, K.; Eklund, L.; Gimenez, E. N.; Hynds, D.; Kachkanov, S.; Kalliopuska, J.; McMullen, T.; O'Shea, V.; Tartoni, N.; Plackett, R.; Vahanen, S.; Wraight, K.

    2015-03-01

    Silicon sensor technologies with reduced dead area at the sensor's perimeter are under development at a number of institutes. Several fabrication methods for sensors which are sensitive close to the physical edge of the device are under investigation utilising techniques such as active-edges, passivated edges and current-terminating rings. Such technologies offer the goal of a seamlessly tiled detection surface with minimum dead space between the individual modules. In order to quantify the performance of different geometries and different bulk and implant types, characterisation of several sensors fabricated using active-edge technology were performed at the B16 beam line of the Diamond Light Source. The sensors were fabricated by VTT and bump-bonded to Timepix ROICs. They were 100 and 200 μ m thick sensors, with the last pixel-to-edge distance of either 50 or 100 μ m. The sensors were fabricated as either n-on-n or n-on-p type devices. Using 15 keV monochromatic X-rays with a beam spot of 2.5 μ m, the performance at the outer edge and corners pixels of the sensors was evaluated at three bias voltages. The results indicate a significant change in the charge collection properties between the edge and 5th (up to 275 μ m) from edge pixel for the 200 μ m thick n-on-n sensor. The edge pixel performance of the 100 μ m thick n-on-p sensors is affected only for the last two pixels (up to 110 μ m) subject to biasing conditions. Imaging characteristics of all sensor types investigated are stable over time and the non-uniformities can be minimised by flat-field corrections. The results from the synchrotron tests combined with lab measurements are presented along with an explanation of the observed effects.

  5. Understanding the shrinkage of optical absorption edges of nanostructured Cd-Zn sulphide films for photothermal applications

    Science.gov (United States)

    Hossain, Md. Sohrab; Kabir, Humayun; Rahman, M. Mahbubur; Hasan, Kamrul; Bashar, Muhammad Shahriar; Rahman, Mashudur; Gafur, Md. Abdul; Islam, Shariful; Amri, Amun; Jiang, Zhong-Tao; Altarawneh, Mohammednoor; Dlugogorski, Bogdan Z.

    2017-01-01

    In this article Cd-Zn sulphide thin films deposited onto soda lime glass substrates via chemical bath deposition (CBD) technique were investigated for photovoltaic applications. The synthesized films were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), and ultraviolet visible (UV-vis) spectroscopic methodologies. A higher degree of crystallinity of the films was attained with the increase of film thicknesses. SEM micrographs exhibited a partial crystalline structure with a particulate appearance surrounded by the amorphous grain boundaries. The optical absorbance and absorption coefficient of the films were also enhanced significantly with the increase in film thicknesses. Optical band-gap analysis indicated a monotonic decrease in direct and indirect band-gaps with the increase of thicknesses of the films. The presence of direct and indirect transitional energies due to the exponential falling edges of the absorption curves may either be due to the lack of long-range order or to the existence of defects in the films. The declination of the optical absorption edges was also confirmed via Urbach energy and steepness parameters studies.

  6. Hg $L_{3}$ edge absorption study of the $HgBa_{2}CuO_{4}\\delta$ superconductor

    CERN Document Server

    Ziyu, Wu; Bianconi, A

    2001-01-01

    The HgBa/sub 2/CuO/sub 4+ delta / superconductor has been studied by high resolution Hg L/sub 3/ X-ray absorption near-edge structure (XANES) spectroscopy. The XANES spectrum has been simulated by full multiple-scattering calculations in order to explore the origin of different features in the experimental spectrum. The experimental Hg L/sub 3/-edge spectrum could be well reproduced by considering a cluster of 85 atoms, containing 10 shells, within a radius of about 7 AA from the central Hg atom. The low energy spectral feature in the XANES spectrum is found to be due to a transition from the Hg p states to the electronic states hybridized with higher shell Ba atoms. This implies that the transition features in the Hg L/sub 3/- edge XANES are strongly influenced by medium range order effects unlike the case of L/sub 3/ edge of 3d transition metals where short- range order is enough to describe the main transition features. (25 refs).

  7. Monte Carlo Comparisons to a Cryogenic Dark Matter Search Detector with low Transition-Edge-Sensor Transition Temperature

    CERN Document Server

    Leman, S W; Brink, P L; Cabrera, B; Cherry, M; Silva, E Do Couto E; Figueroa-Feliciano, E; Kim, P; Mirabolfathi, N; Pyle, M; Resch, R; Sadoulet, B; Serfass, B; Sundqvist, K M; Tomada, A; Young, B A

    2011-01-01

    We present results on phonon quasidiffusion and Transition Edge Sensor (TES) studies in a large, 3 inch diameter, 1 inch thick [100] high purity germanium crystal, cooled to 50 mK in the vacuum of a dilution refrigerator, and exposed with 59.5 keV gamma-rays from an Am-241 calibration source. We compare calibration data with results from a Monte Carlo which includes phonon quasidiffusion and the generation of phonons created by charge carriers as they are drifted across the detector by ionization readout channels. The phonon energy is then parsed into TES based phonon readout channels and input into a TES simulator.

  8. Plasmonic Structure Integrated Single-Photon Detector Configurations to Improve Absorptance and Polarization Contrast

    Directory of Open Access Journals (Sweden)

    Mária Csete

    2015-02-01

    Full Text Available Configurations capable of maximizing both the absorption component of system detection efficiency and the achievable polarization contrast were determined for 1550 nm polarized light illumination of different plasmonic structure integrated superconducting nanowire single-photon detectors (SNSPDs consisting of p = 264 nm and P = 792 nm periodic niobium nitride (NbN patterns on silica substrate. Global effective NbN absorptance maxima appear in case of p/s-polarized light illumination in S/P-orientation (γ = 90°/0° azimuthal angle and the highest polarization contrast is attained in S-orientation of all devices. Common nanophotonical origin of absorptance enhancement is collective resonance on nanocavity gratings with different profiles, which is promoted by coupling between localized modes in quarter-wavelength metal-insulator-metal nanocavities and laterally synchronized Brewster-Zenneck-type surface waves in integrated SNSPDs possessing a three-quarter-wavelength-scaled periodicity. The spectral sensitivity and dispersion characteristics reveal that device design specific optimal configurations exist.

  9. Proposal for a GHz count rate near-IR single-photon detector based on a nanoscale superconducting transition edge sensor

    CERN Document Server

    Santavicca, Daniel F; Prober, Daniel E; 10.1117/12.883979

    2012-01-01

    We describe a superconducting transition edge sensor based on a nanoscale niobium detector element. This device is predicted to be capable of energy-resolved near-IR single-photon detection with a GHz count rate. The increased speed and sensitivity of this device compared to traditional transition edge sensors result from the very small electronic heat capacity of the nanoscale detector element. In the present work, we calculate the predicted thermal response time and energy resolution. We also discuss approaches for achieving efficient optical coupling to the sub-wavelength detector element using a resonant near-IR antenna.

  10. Solving local structure around dopants in metal nanoparticles with ab initio modeling of X-ray absorption near edge structure.

    Science.gov (United States)

    Timoshenko, Janis; Shivhare, Atal; Scott, Robert W J; Lu, Deyu; Frenkel, Anatoly I

    2016-07-20

    We adopted ab initio X-ray absorption near edge structure (XANES) modeling for structural refinement of local environments around metal impurities in a large variety of materials. Our method enables both direct modeling, where the candidate structures are known, and the inverse modeling, where the unknown structural motifs are deciphered from the experimental spectra. We present also estimates of systematic errors, and their influence on the stability and accuracy of the obtained results. We illustrate our approach by revealing the evolution of local environment of palladium atoms in palladium-doped gold thiolate clusters upon chemical and thermal treatments.

  11. The iron L edges : Fe 2p X-ray absorption and electron energy loss spectroscopy

    NARCIS (Netherlands)

    Miedema, Piter S.; de Groot, Frank M. F.

    The iron L edges are reviewed. The experimental spectra obtained with 2p XAS, XMCD and 2p EELS are discussed, including isolated iron atoms, solids and coordination compounds. The largest fraction of publications deal with iron oxide systems that are discussed in detail, including binary oxides,

  12. Correction of absorption-edge artifacts in polychromatic X-ray tomography in a scanning electron microscope for 3D microelectronics.

    Science.gov (United States)

    Laloum, D; Printemps, T; Lorut, F; Bleuet, P

    2015-01-01

    X-ray tomography is widely used in materials science. However, X-ray scanners are often based on polychromatic radiation that creates artifacts such as dark streaks. We show this artifact is not always due to beam hardening. It may appear when scanning samples with high-Z elements inside a low-Z matrix because of the high-Z element absorption edge: X-rays whose energy is above this edge are strongly absorbed, violating the exponential decay assumption for reconstruction algorithms and generating dark streaks. A method is proposed to limit the absorption edge effect and is applied on a microelectronic case to suppress dark streaks between interconnections.

  13. Correction of absorption-edge artifacts in polychromatic X-ray tomography in a scanning electron microscope for 3D microelectronics

    Energy Technology Data Exchange (ETDEWEB)

    Laloum, D., E-mail: david.laloum@cea.fr [Université Grenoble Alpes, F-38000 Grenoble (France); CEA, LETI, MINATEC Campus, 17 rue des Martyrs, 38054 Grenoble Cedex 9 (France); STMicroelectronics, 850 rue Jean Monnet, 38926 Crolles (France); Printemps, T.; Bleuet, P. [Université Grenoble Alpes, F-38000 Grenoble (France); CEA, LETI, MINATEC Campus, 17 rue des Martyrs, 38054 Grenoble Cedex 9 (France); Lorut, F. [STMicroelectronics, 850 rue Jean Monnet, 38926 Crolles (France)

    2015-01-15

    X-ray tomography is widely used in materials science. However, X-ray scanners are often based on polychromatic radiation that creates artifacts such as dark streaks. We show this artifact is not always due to beam hardening. It may appear when scanning samples with high-Z elements inside a low-Z matrix because of the high-Z element absorption edge: X-rays whose energy is above this edge are strongly absorbed, violating the exponential decay assumption for reconstruction algorithms and generating dark streaks. A method is proposed to limit the absorption edge effect and is applied on a microelectronic case to suppress dark streaks between interconnections.

  14. Iris segmentation using an edge detector based on fuzzy sets theory and cellular learning automata.

    Science.gov (United States)

    Ghanizadeh, Afshin; Abarghouei, Amir Atapour; Sinaie, Saman; Saad, Puteh; Shamsuddin, Siti Mariyam

    2011-07-01

    Iris-based biometric systems identify individuals based on the characteristics of their iris, since they are proven to remain unique for a long time. An iris recognition system includes four phases, the most important of which is preprocessing in which the iris segmentation is performed. The accuracy of an iris biometric system critically depends on the segmentation system. In this paper, an iris segmentation system using edge detection techniques and Hough transforms is presented. The newly proposed edge detection system enhances the performance of the segmentation in a way that it performs much more efficiently than the other conventional iris segmentation methods.

  15. Note: application of a pixel-array area detector to simultaneous single crystal X-ray diffraction and X-ray absorption spectroscopy measurements.

    Science.gov (United States)

    Sun, Cheng-Jun; Zhang, Bangmin; Brewe, Dale L; Chen, Jing-Sheng; Chow, G M; Venkatesan, T; Heald, Steve M

    2014-04-01

    X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) are two main x-ray techniques in synchrotron radiation facilities. In this Note, we present an experimental setup capable of performing simultaneous XRD and XAS measurements by the application of a pixel-array area detector. For XRD, the momentum transfer in specular diffraction was measured by scanning the X-ray energy with fixed incoming and outgoing x-ray angles. By selecting a small fixed region of the detector to collect the XRD signal, the rest of the area was available for collecting the x-ray fluorescence for XAS measurements. The simultaneous measurement of XRD and X-ray absorption near edge structure for Pr0.67Sr0.33MnO3 film was demonstrated as a proof of principle for future time-resolved pump-probe measurements. A static sample makes it easy to maintain an accurate overlap of the X-ray spot and laser pump beam.

  16. Experimental and theoretical study of X-ray absorption around the chlorine L edge in vinyl chloride

    Energy Technology Data Exchange (ETDEWEB)

    Kawerk, Elie, E-mail: elie.kawerk@etu.upmc.fr [Université Pierre et Marie Curie, Laboratoire de Chimie Physique-Matière et Rayonnement, UMR 7614, 11 rue Pierre et Marie Curie, 75231 Paris Cedex 05 (France); Université Libanaise, Faculté des Sciences II Fanar, Laboratoire de Physique Appliquée, 90656 Jdeidet el Metn (Lebanon); Carniato, Stéphane [Université Pierre et Marie Curie, Laboratoire de Chimie Physique-Matière et Rayonnement, UMR 7614, 11 rue Pierre et Marie Curie, 75231 Paris Cedex 05 (France); Iwayama, Hiroshi; Shigemasa, Eiji [Ultraviolet Synchrotron Orbital Radiation Facility, Institute for Molecular Science, Okazaki 444-8585 (Japan); Piancastelli, Maria Novella [Université Pierre et Marie Curie, Laboratoire de Chimie Physique-Matière et Rayonnement, UMR 7614, 11 rue Pierre et Marie Curie, 75231 Paris Cedex 05 (France); Wassaf, Joseph; Khoury, Antonio [Université Libanaise, Faculté des Sciences II Fanar, Laboratoire de Physique Appliquée, 90656 Jdeidet el Metn (Lebanon); Simon, Marc [Université Pierre et Marie Curie, Laboratoire de Chimie Physique-Matière et Rayonnement, UMR 7614, 11 rue Pierre et Marie Curie, 75231 Paris Cedex 05 (France)

    2013-02-15

    Highlights: ► We measured the X-ray absorption spectrum of C{sub 2}H{sub 3}Cl around the chlorine L edge. ► Ab-initio calculations of the spectrum shed light on eventual electronic resonances. ► Vibrational substructures for particular core excited states are considered. ► The potential energy surfaces of the core excited electronic states are evaluated. ► Sharp or narrow spectral bands are associated to bound or dissociative surfaces. -- Abstract: We present a combined experimental and theoretical study of the high-resolution chlorine L edge X-ray absorption spectrum in gas-phase vinyl chloride (C{sub 2}H{sub 3}Cl). With the help of ab-initio calculations, we interpret the experimental spectrum and attribute each band to its corresponding electronic transitions terminating at states characterized by an either binding or dissociative potential energy surface (PES). Vibrational substructures in some specific core-excited electronic states are taken into account.

  17. The dust scattering component of X-ray extinction: Effects on continuum fitting and high-resolution absorption edge structure

    CERN Document Server

    Corrales, L; Wilms, J; Baganoff, F

    2016-01-01

    Small angle scattering by dust grains causes a significant contribution to the total interstellar extinction for any X-ray instrument with sub-arcminute resolution (Chandra, Swift, XMM-Newton). However, the dust scattering component is not included in the current absorption models: phabs, tbabs, and tbnew. We simulate a large number of Chandra spectra to explore the bias in the spectral fit and NH measurements obtained without including extinction from dust scattering. We find that without incorporating dust scattering, the measured NH will be too large by a baseline level of 25%. This effect is modulated by the imaging resolution of the telescope, because some amount of unresolved scattered light will be captured within the aperture used to extract point source information. In high resolution spectroscopy, dust scattering significantly enhances the total extinction optical depth and the shape of the photoelectric absorption edges. We focus in particular on the Fe-L edge at 0.7 keV, showing that the total ext...

  18. Physical Properties of the Interstellar Medium Using High-resolution Chandra Spectra: O K-edge Absorption

    Science.gov (United States)

    Gatuzz, E.; García, J.; Mendoza, C.; Kallman, T. R.; Bautista, M. A.; Gorczyca, T. W.

    2014-08-01

    Chandra high-resolution spectra toward eight low-mass Galactic binaries have been analyzed with a photoionization model that is capable of determining the physical state of the interstellar medium. Particular attention is given to the accuracy of the atomic data. Hydrogen column densities are derived with a broadband fit that takes into account pileup effects, and in general are in good agreement with previous results. The dominant features in the oxygen-edge region are O I and O II Kα absorption lines whose simultaneous fits lead to average values of the ionization parameter of log ξ = -2.90 and oxygen abundance of A O = 0.70. The latter is given relative to the standard by Grevesse & Sauval, but rescaling with the revision by Asplund et al. would lead to an average abundance value fairly close to solar. The low average oxygen column density (N O = 9.2 × 1017 cm-2) suggests a correlation with the low ionization parameters, the latter also being in evidence in the column density ratios N(O II)/N(O I) and N(O III)/N(O I) that are estimated to be less than 0.1. We do not find conclusive evidence for absorption by any other compound but atomic oxygen in our oxygen-edge region analysis.

  19. Manganese L-edge X-ray absorption spectroscopy of manganese catalase from Lactobacillus plantarum and mixed valence manganese complexes

    Energy Technology Data Exchange (ETDEWEB)

    Grush, M.M.; Chen, J.; George, S.J. [Univ. of California, Davis, CA (United States)] [and others

    1996-01-10

    The first Mn L-edge absorption spectra of a Mn metalloprotein are presented in this paper. Both reduced and superoxidized Mn catalase have been examined by fluorescence-detected soft X-ray absorption spectroscopy, and their Mn L-edge spectra are dramatically different. The spectrum of reduced Mn(II)Mn(II) catalase has been interpreted by ligand field atomic multiplet calculations and by comparison to model compound spectra. The analysis finds a 10 Dq value of nearly 1.1 eV, consistent with coordination by predominately nitrogen and oxygen donor ligands. For interpretation of mixed valence Mn spectra, an empirical simulation procedure based on the addition of homovalent model compound spectra has been developed and was tested on a variety of Mn complexes and superoxidized Mn catalase. This routine was also used to determine the oxidation state composition of the Mn in [Ba{sub 8}Na{sub 2}ClMn{sub 16}(OH){sub 8}(CO{sub 3}){sub 4}L{sub 8}] .53 H{sub 2}O (L=1,3-diamino-2-hydroxypropane-N,N,N`N`-tetraacetic acid). 27 refs., 6 figs.

  20. Comparison of canny and V1 neural network based edge detectors applied to road extraction

    CSIR Research Space (South Africa)

    Hauptfleisch, AC

    2006-11-01

    Full Text Available The Anti-parallel edge Centerline Extractor (ACE) algorithm is designed to extract road networks from high resolution satellite images. The primary mechanism used by the algorithm to detect the presence of roads is a filter that detects parallel...

  1. High-resolution molybdenum K-edge X-ray absorption spectroscopy analyzed with time-dependent density functional theory.

    Science.gov (United States)

    Lima, Frederico A; Bjornsson, Ragnar; Weyhermüller, Thomas; Chandrasekaran, Perumalreddy; Glatzel, Pieter; Neese, Frank; DeBeer, Serena

    2013-12-28

    X-ray absorption spectroscopy (XAS) is a widely used experimental technique capable of selectively probing the local structure around an absorbing atomic species in molecules and materials. When applied to heavy elements, however, the quantitative interpretation can be challenging due to the intrinsic spectral broadening arising from the decrease in the core-hole lifetime. In this work we have used high-energy resolution fluorescence detected XAS (HERFD-XAS) to investigate a series of molybdenum complexes. The sharper spectral features obtained by HERFD-XAS measurements enable a clear assignment of the features present in the pre-edge region. Time-dependent density functional theory (TDDFT) has been previously shown to predict K-pre-edge XAS spectra of first row transition metal compounds with a reasonable degree of accuracy. Here we extend this approach to molybdenum K-edge HERFD-XAS and present the necessary calibration. Modern pure and hybrid functionals are utilized and relativistic effects are accounted for using either the Zeroth Order Regular Approximation (ZORA) or the second order Douglas-Kroll-Hess (DKH2) scalar relativistic approximations. We have found that both the predicted energies and intensities are in excellent agreement with experiment, independent of the functional used. The model chosen to account for relativistic effects also has little impact on the calculated spectra. This study provides an important calibration set for future applications of molybdenum HERFD-XAS to complex catalytic systems.

  2. Edge-promoting reconstruction of absorption and diffusivity in optical tomography

    DEFF Research Database (Denmark)

    Hannukainen, A.; Harhanen, Lauri Oskari; Hyvönen, N.;

    2015-01-01

    In optical tomography a physical body is illuminated with near-infrared light and the resulting outward photon flux is measured at the object boundary. The goal is to reconstruct internal optical properties of the body, such as absorption and diffusivity. In this work, it is assumed that the imaged...

  3. Oxygen K-edge absorption spectra of small molecules in the gas phase

    Energy Technology Data Exchange (ETDEWEB)

    Yang, B.X.; Kirz, J.; Sham, T.K.

    1986-01-01

    The absorption spectra of O/sub 2/, CO, CO/sub 2/ and OCS have been recorded in a transmission mode in the energy region from 500 to 950 eV. Recent observation of EXAFS in these molecules is confirmed in this study. 7 refs., 3 figs.

  4. Modification of the Absorption Edge of GaAs Arising from Hot-Electron Effects

    DEFF Research Database (Denmark)

    McGroddy, J. C.; Christensen, Ove

    1973-01-01

    We have observed a large enhancement of the electric-field-induced optical absorption arising from hot-electron effects in n-type GaAs at 77 K. The magnitude and field dependence of the enhancement can be approximately accounted for by a theory attributing the effect to broadening of the final st...

  5. X-ray absorption near-edge structure and valence state of Mn in (Ga,Mn)N

    Science.gov (United States)

    Titov, A.; Biquard, X.; Halley, D.; Kuroda, S.; Bellet-Amalric, E.; Mariette, H.; Cibert, J.; Merad, A. E.; Merad, G.; Kanoun, M. B.; Kulatov, E.; Uspenskii, Yu. A.

    2005-09-01

    The band structure of the diluted magnetic semiconductor (Ga,Mn)N, and the x-ray absorption near-edge structure (XANES) at the K edge of Mn, were calculated using the linearized augmented plane wave method. The calculated K-edge spectra fit well with experimental data obtained on samples of Ga1-xMnxN with a wide range of Mn content, from x=0.3% to 5.7%. These samples were grown by molecular beam epitaxy. X-ray diffraction measurements and extended x-ray absorption fine structure studies were used to confirm the wurtzite structure of the samples, the absence of any secondary phase, and the substitutional position of Mn in the gallium sublattice of GaN. The shape of the measured XANES spectra does not depend on the Mn content, implying the same valence state and local atomic structure around the Mn atom in all samples. The comparison between the measured spectra and the results of the ab initio calculation offers a clear interpretation of the preedge structure: It is mainly due to dipolar transitions, with a single peak in the case of Mn2+ and an additional peak for Mn3+ . Such a behavior of the XANES preedge of Mn2+ was confirmed experimentally on (Ga,Mn)As and (Zn,Mn)Te. We conclude that the valence state of Mn in wurtzite (Ga,Mn)N is 3+ , a conclusion which is also supported by infrared optical transmission and magnetization data obtained on the same samples.

  6. Optimum design of multi-layer K-edge filter and multi-stage detectors for triple energy bone densitometer

    Science.gov (United States)

    Mazoochi, Alireza; Rahmani, Faezeh; Abbasi Davani, Fereydoun; Ghaderi, Ruhollah

    2014-03-01

    Dual X-ray bone densitometry may cause some errors in diagnosis due to heterogeneous distribution of adipose tissue. It is necessary to develop a more accurate technique to consider the effects of fat. In this research, a triple energy X-ray method has been introduced and conceptual design of a system consisting of 160 kV X-ray tube, multi-layer K-edge filter and multi-stage detector has been presented. Design calculations have been performed using MCNP4C Monte Carlo code to select the type of filters and detectors with the best thicknesses for better distinguishing materials. The energy peaks (37 keV, 50 keV and 105 keV) can be separated optimally with a multi-layer filter composed of barium (170 μm) and gadolinium (100 μm) as the first and second layers, respectively which are coated on a 1 mm aluminum plate placed between the source and tissue. The transmitted photons have been counted by a multi-stage linear array of detectors consisting of ZnSe(Te) and CsI(Tl) with 400 μm and 5 mm thicknesses, respectively. Monte Carlo simulations show that the triple energy X-ray technique has better accuracy than that of the standard dual energy X-ray technique.

  7. Measurement of mass attenuation coefficients in some Cr, Co and Fe compounds around the absorption edge and the validity of the mixture rule

    Indian Academy of Sciences (India)

    U Turgut; O Şimşek; E Büyükkasap

    2007-08-01

    The total mass attenuation coefficients for elements Cr, Co and Fe and compounds CrCl2, CrCl3, Cr2(SO4)32SO4·24H2O, CoO, CoCl2, Co(CH3COO)2, FePO4, FeCl3·6H2O, Fe(SO4)2NH4·12H2O were measured at different energies between 4.508 and 14.142 keV using secondary excitation method. Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br, Rb, Sr were chosen as secondary exciters. 59.5 keV -rays emitted from a 241Am annular source were used to excite a secondary exciter and K (K-L3, L2) lines emitted by the secondary exciter were counted by a Si(Li) detector with a resolution of 160 eV at 5.9 keV. It was observed that mixture rule method is not a suitable method for determination of the mass attenuation coefficients of compounds, especially at an energy that is near the absorption edge. The obtained values were compared with theoretical values.

  8. Intense Photoluminescence and Movement of OpticalAbsorption Edge in Alumina Aerogels

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Alumina aerogels with high porosity of nanometer size were prepared from Al, n-butanol andethyl acetoacetate by the sol-gel route and the N2 supercritical extraction drying technique.Optical experiment results showed that for alumina aerogels after annealing at 500℃ for 4 h pneintense blue emission band appeared in the wavelength range of 400 to 800 nm, and the opticalabsorption edge moved from 8.0 eV of coarse grain Al2O3 to 3~5 eV and with increasing theannealing temperature, this luminescence band presented blue shifts. The reasons of these newoptical properties are discussed in detail.

  9. Degenerate four-wave mixing in semiconductor-doped glasses below the absorption edge

    Science.gov (United States)

    Bindra, K. S.; Oak, S. M.; Rustagi, K. C.

    1999-01-01

    We report measurements of degenerate four-wave-mixing reflectivity at a frequency below the band gap of semiconductor-doped glasses in the intensity range 0.5-10 GW/cm2. Up to intensities ~2.5 GW/cm2, the conjugate reflectivity varies like the fourth power of intensity signifying a fifth-order nonlinearity due to band filling by two-photon absorption. Surprisingly, at a higher intensity range the conjugate signal showed a cubic dependence on the pump intensity, which is typical of the χ(3) process. We show that this cubic dependence does not necessarily indicate a third-order process as usually assumed. Instead, it is shown to arise due to a reduction of the effective intensity by nonlinear absorption of the interacting beams.

  10. Temperature variation of the fundamental absorption edge in AgGaSe{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Calderon, E., E-mail: saernest@ula.v [Centro de Estudios de Semiconductores, Facultad de Ciencias, Universidad de los Andes, Merida 5101 (Venezuela, Bolivarian Republic of); Fernandez, B.; Duran, L.; Grima, P.; Morocoima, M.; Quintero, E.; Rincon, C.; Quintero, M. [Centro de Estudios de Semiconductores, Facultad de Ciencias, Universidad de los Andes, Merida 5101 (Venezuela, Bolivarian Republic of)

    2009-11-15

    Optical absorption measurements were made in the temperature range 9-300 K on the chalcopyrite semiconductor compound AgGaSe{sub 2} and the optical energy gap E{sub G} determined as a function of temperature T. In order to obtain the values of E{sub G} as a function of T, the Elliot-Toyozawa model [R.J. Elliot, J. Phys. Rev. 108 (1957) 1384; D.D. Sell, P. Lawaets, Phys. Rev. Lett. 26 (1971) 311] was employed to perform the analysis of the optical absorption spectra. The resulting E{sub G} vs. T curve was fitted to a semi-empirical model that takes into account both the thermal expansion and the electron-phonon interaction contributions. The results have been used to estimate values of the deformation potentials of the valence and conduction bands of the compound.

  11. The fundamental absorption edge in MnIn{sub 2}Se{sub 4} layer semi-magnetic semiconductor

    Energy Technology Data Exchange (ETDEWEB)

    Rincón, C., E-mail: crincon@ula.ve [Centro de Estudios de Semiconductores, Departamento de Física, Facultad de Ciencias, Universidad de Los Andes, Mérida (Venezuela, Bolivarian Republic of); Torrres, T.E. [Laboratorio de Magnetismo, Departamento de Física, Facultad de Ciencias, Universidad de Los Andes, Mérida (Venezuela, Bolivarian Republic of); Instituto de Nanociencia de Aragón, Laboratorio de Microscopías Avanzadas, Universidad de Zaragoza 50009, Zaragoza (Spain); Departamento de Física de la Materia Condensada, Facultad de Ciencias, Universidad de Zaragoza 50009, Zaragoza, Spain. (Spain); Sagredo, V. [Laboratorio de Magnetismo, Departamento de Física, Facultad de Ciencias, Universidad de Los Andes, Mérida (Venezuela, Bolivarian Republic of); Jiménez-Sandoval, Sergio J.; Mares-Jacinto, E. [CINVESTAV Querétaro, Libramiento Norponiente N° 2000, Frac. Real de Juriquilla, Querétaro, Qro. 76230 (Mexico)

    2015-11-15

    From the study of the optical absorption coefficient and photoluminescence spectra of the layer semi-magnetic semiconductor MnIn{sub 2}Se{sub 4} the nature of its fundamental absorption edge is established. It is found that the lowest-energy-gap of this compound is allowed-indirect between parabolic bands that vary from about 1.55–1.43 eV in the temperature range from 10 K to room temperature. In addition, two allowed direct band-to-band transitions beginning at 1.72 and 1.85 eV at 295 K, and at 1.82 and 1.96 eV at 10 K which are related to optical absorption processes between the uppermost Γ{sub 4}(z) and the middle Γ{sub 5}(x) valence bands and the conduction band respectively, are observed in the high energy range. It is also found that the crystal field splitting parameter (Δ{sub cf}) of MnIn{sub 2}Se{sub 4} is of about 0.15 eV nearly independent of the temperature. At energies around 2.2 eV a photoluminescence band related to internal transitions between d-excited levels of Mn{sup +2} ion to its {sup 6}A{sub 1} ground state is also observed in spectra.

  12. X-Ray Lines and Absorption Edges in GRBs and Their Afterglows

    CERN Document Server

    Böttcher, M

    2002-01-01

    Absorption and Reprocessing of Gamma-ray burst radiation in the environment of cosmological GRBs can be used as a powerful probe of the elusive nature of their progenitors. In particular, transient X-ray emission line and absorption features in the prompt and early afterglows of GRBs are sensitive to details of the location and density structure of the reprocessing and/or absorbing material. To date, there have been only rather few detections of such features, and the significance is marginal in most individual cases. However, transient X-ray emission lines in GRB afterglows have now been found by four different X-ray satellites, which may justify a more detailed theoretical investigation of their origin. In this paper, I will first present a brief review of the status of observations of transient X-ray emission line and absorption features. I will then discuss general physics constraints which those results impose on isotropy, homogeneity, and location of the reprocessing material with respect to the GRB sou...

  13. Lead uptake in diverse plant families: a study applying X-ray absorption near edge spectroscopy.

    Science.gov (United States)

    Bovenkamp, Gudrun L; Prange, Alexander; Schumacher, Wolfgang; Ham, Kyungmin; Smith, Aaron P; Hormes, Josef

    2013-05-07

    The chemical environment of lead in roots and leaves of plants from four different plant families and a lichen from a former lead mining site in the Eifel Mountains in Germany was determined by Pb L3-edge XANES measurements using solid reference compounds and also aqueous solutions of different ionic strength simulating the plant environment. Pb(2+) ions in the plants were found to have two major coordinations, one with nine oxygen atoms in the first coordination shell similar to outer-sphere complexation and a second coordination with just three oxygen atoms similar to inner-sphere complexation. This can be interpreted assuming that lead is sorbed on the surface of cell walls depending on the concentration of lead in the soil solution. Pb L3-edge XANES spectra of dried and fresh plant samples are very similar because sorption does not change with removal of water but only because of the initial ionic strength. No bonding to biologically important groups (-S, - N) or precipitation (-PO4) was found.

  14. Particle Discrimination in TeO$_{2}$ Bolometers using Light Detectors read out by Transition Edge Sensors

    CERN Document Server

    Schäffner, K; Bellini, F; Casali, N; Ferroni, F; Hauff, D; Nagorny, N; Pattavina, L; Petricca, F; Pirro, S; Pröbst, F; Reindl, F; Seidel, W; Strauss, R

    2014-01-01

    An active discrimination of the dominant $\\alpha$-background is the prerequisite for future DBD experiments based on TeO$_{2}$ bolometers. We investigate such $\\alpha$-particle rejection in cryogenic TeO$_{2}$ bolometers by the detection of Cherenkov light. For a setup consisting of a large TeO$_{2}$ crystal 285 g and a separate cryogenic light detector, both read out by transition edge sensors at around 10 mK, we obtain an event-by-event identification of e/$\\gamma$- and $\\alpha$-events. In the energy interval ranging from 2400 keV to 2800 keV and covering the Q-value of $^{130}$Te a discrimination power of 3.7 could be demonstrated.

  15. A Comparison of Fundamental Noise in Kinetic Inductance Detectors and Transition Edge Sensors for Millimeter-wave Applications

    CERN Document Server

    Lowitz, A E; Golwala, S R; Timbie, P T

    2014-01-01

    Kinetic inductance detectors (KIDs) show promise as a competitive technology for astronomical observations over a wide range of wavelengths. We are interested in comparing the fundamental limitations to the sensitivity of KIDs with that of transition edge sensors (TESs) at millimeter wavelengths, specifically over the wavelengths required for studies of the Cosmic Microwave Background (CMB). We calculate the total fundamental noise arising from optical and thermal excitations in TESs and KIDs for a variety of bath temperatures and optical loading scenarios for applications at millimeter wavelengths. Special consideration is given to the case of ground-based observations of 100 GHz radiation with a 100 mK bath temperature, conditions consistent with the planned second module of the QUBIC telescope, a CMB instrument. Under these conditions, a titanium nitride KID with optimized critical temperature pays a few percent noise penalty compared to a typical optimized TES.

  16. Extremely asymmetric diffraction as a method of determining magneto-optical constants for X-rays near absorption edges

    Energy Technology Data Exchange (ETDEWEB)

    Andreeva, M. A., E-mail: Mandreeva1@yandex.ru [Moscow State University (Russian Federation); Repchenko, Yu. L., E-mail: kent160@mail.ru [Voronezh State University (Russian Federation); Smekhova, A. G. [Moscow State University (Russian Federation); Dumesnil, K. [University of Lorraine, Institut Jean Lamour (UMR CNRS 7198) (France); Wilhelm, F.; Rogalev, A. [European Synchrotron Radiation Facility (France)

    2015-06-15

    The spectral dependence of the Bragg peak position under conditions of extremely asymmetric diffraction has been analyzed in the kinematical and dynamical approximations of the diffraction theory. Simulations have been performed for the L{sub 3} absorption edge of yttrium in a single-crystal YFe{sub 2} film; they have shown that the magneto-optical constants (or, equivalently, the dispersion corrections to the atomic scattering factor) for hard X-rays can be determined from this dependence. Comparison with the experimental data obtained for a Nb(4 nm)/YFe{sub 2}(40 nm〈110〉)/Fe(1.5 nm)/Nb(50 nm)/sapphire sample at the European Synchrotron Radiation Facility has been made.

  17. Experimental station for laser-based picosecond time-resolved x-ray absorption near-edge spectroscopy

    Science.gov (United States)

    Dorchies, F.; Fedorov, N.; Lecherbourg, L.

    2015-07-01

    We present an experimental station designed for time-resolved X-ray Absorption Near-Edge Spectroscopy (XANES). It is based on ultrashort laser-plasma x-ray pulses generated from a table-top 100 mJ-class laser at 10 Hz repetition rate. A high transmission (10%-20%) x-ray beam line transport using polycapillary optics allows us to set the sample in an independent vacuum chamber, providing high flexibility over a wide spectral range from 0.5 up to 4 keV. Some XANES spectra are presented, demonstrating 1% noise level in only ˜1 mn and ˜100 cumulated laser shots. Time-resolved measurements are reported, indicating that the time resolution of the entire experimental station is 3.3 ± 0.6 ps rms.

  18. Near-edge X-ray absorption fine structure spectroscopy-assisted purification of single-walled carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Yan Dongwei [Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080 (China); Zhong Jun [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Wang Chunru [Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080 (China)], E-mail: crwang@iccas.ac.cn; Wu Ziyu [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)], E-mail: wuzy@ihep.ac.cn

    2007-07-15

    Single-walled carbon nanotubes were produced by the conventional arc discharge method, and purified with a two-step treatment. First, the raw soot containing single-walled carbon nanotubes was burned up at ca. 350 deg. C in air to remove amorphous carbon, and then it was treated by strong acidic solvents to remove metal catalysts. Near-edge X-ray absorption fine structure spectroscopy was applied to analyze the defects on single-walled carbon nanotubes in whole purification process, so the experimental conditions can be optimized, and finally high-purity single-walled carbon nanotubes were obtained as revealed by various spectroscopic characterizations such as scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, and Raman spectroscopy.

  19. 3D Imaging of Nickel Oxidation States using Full Field X-ray Absorption Near Edge Structure Nanotomography

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, George; Harris, William; Izzo, John; Grew, Kyle N. (Connecticut); (USARL)

    2012-01-20

    Reduction-oxidation (redox) cycling of the nickel electrocatalyst phase in the solid oxide fuel cell (SOFC) anode can lead to performance degradation and cell failure. A greater understanding of nickel redox mechanisms at the microstructural level is vital to future SOFC development. Transmission x-ray microscopy (TXM) provides several key techniques for exploring oxidation states within SOFC electrode microstructure. Specifically, x-ray nanotomography and x-ray absorption near edge structure (XANES) spectroscopy have been applied to study samples of varying nickel (Ni) and nickel oxide (NiO) compositions. The imaged samples are treated as mock SOFC anodes containing distinct regions of the materials in question. XANES spectra presented for the individual materials provide a basis for the further processing and analysis of mixed samples. Images of composite samples obtained are segmented, and the distinct nickel and nickel oxide phases are uniquely identified using full field XANES spectroscopy. Applications to SOFC analysis are discussed.

  20. Experimental station for laser-based picosecond time-resolved x-ray absorption near-edge spectroscopy.

    Science.gov (United States)

    Dorchies, F; Fedorov, N; Lecherbourg, L

    2015-07-01

    We present an experimental station designed for time-resolved X-ray Absorption Near-Edge Spectroscopy (XANES). It is based on ultrashort laser-plasma x-ray pulses generated from a table-top 100 mJ-class laser at 10 Hz repetition rate. A high transmission (10%-20%) x-ray beam line transport using polycapillary optics allows us to set the sample in an independent vacuum chamber, providing high flexibility over a wide spectral range from 0.5 up to 4 keV. Some XANES spectra are presented, demonstrating 1% noise level in only ∼1 mn and ∼100 cumulated laser shots. Time-resolved measurements are reported, indicating that the time resolution of the entire experimental station is 3.3 ± 0.6 ps rms.

  1. Experimental station for laser-based picosecond time-resolved x-ray absorption near-edge spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Dorchies, F., E-mail: dorchies@celia.u-bordeaux1.fr; Fedorov, N.; Lecherbourg, L. [Université Bordeaux, CNRS, CEA, CELIA (Centre Lasers Intenses et Applications), UMR 5107, Talence F-33405 (France)

    2015-07-15

    We present an experimental station designed for time-resolved X-ray Absorption Near-Edge Spectroscopy (XANES). It is based on ultrashort laser-plasma x-ray pulses generated from a table-top 100 mJ-class laser at 10 Hz repetition rate. A high transmission (10%–20%) x-ray beam line transport using polycapillary optics allows us to set the sample in an independent vacuum chamber, providing high flexibility over a wide spectral range from 0.5 up to 4 keV. Some XANES spectra are presented, demonstrating 1% noise level in only ∼1 mn and ∼100 cumulated laser shots. Time-resolved measurements are reported, indicating that the time resolution of the entire experimental station is 3.3 ± 0.6 ps rms.

  2. Near-edge x-ray absorption fine structure spectroscopy at atmospheric pressure with a table-top laser-induced soft x-ray source

    Energy Technology Data Exchange (ETDEWEB)

    Kühl, Frank-Christian, E-mail: Frank-christian.kuehl@mail.de; Müller, Matthias, E-mail: matthias.mueller@llg-ev.de; Schellhorn, Meike; Mann, Klaus [Laser-Laboratorium Göttingen e.V., Hans-Adolf-Krebs-Weg 1, D-37077 Göttingen (Germany); Wieneke, Stefan [Hochschule für angewandte Wissenschaft und Kunst, Von-Ossietzky-Str 99, D-37085 Göttingen (Germany); Eusterhues, Karin [Friedrich-Schiller-Universität Jena, Fürstengraben 1, D-07743 Jena (Germany)

    2016-07-15

    The authors present a table-top soft x-ray absorption spectrometer, accomplishing investigations of the near-edge x-ray absorption fine structure (NEXAFS) in a laboratory environment. The system is based on a low debris plasma ignited by a picosecond laser in a pulsed krypton gas jet, emitting soft x-ray radiation in the range from 1 to 5 nm. For absorption spectroscopy in and around the “water window” (2.3–4.4 nm), a compact helium purged sample compartment for experiments at atmospheric pressure has been constructed and tested. NEXAFS measurements on CaCl{sub 2} and KMnO{sub 4} samples were conducted at the calcium and manganese L-edges, as well as at the oxygen K-edge in air, atmospheric helium, and under vacuum, respectively. The results indicate the importance of atmospheric conditions for an investigation of sample hydration processes.

  3. Sulfur K-edge absorption spectroscopy on selected biological systems; Schwefel-K-Kanten-Absorptionsspektroskopie an ausgewaehlten biologischen Systemen

    Energy Technology Data Exchange (ETDEWEB)

    Lichtenberg, Henning

    2008-07-15

    Sulfur is an essential element in organisms. In this thesis investigations of sulfur compounds in selected biological systems by XANES (X-ray Absorption Near Edge Structure) spectroscopy are reported. XANES spectroscopy at the sulfur K-edge provides an excellent tool to gain information about the local environments of sulfur atoms in intact biological samples - no extraction processes are required. Spatially resolved measurements using a Kirkpatrick-Baez mirror focusing system were carried out to investigate the infection of wheat leaves by rust fungi. The results give information about changes in the sulfur metabolism of the host induced by the parasite and about the extension of the infection into visibly uninfected plant tissue. Furthermore, XANES spectra of microbial mats from sulfidic caves were measured. These mats are dominated by microbial groups involved in cycling sulfur. Additionally, the influence of sulfate deprivation and H{sub 2}S exposure on sulfur compounds in onion was investigated. To gain an insight into the thermal degradation of organic material the influence of roasting of sulfur compounds in coffee beans was studied. (orig.)

  4. Near-edge X-ray absorption fine-structure spectroscopy of naphthalene diimide-thiophene co-polymers

    Energy Technology Data Exchange (ETDEWEB)

    Gann, Eliot; McNeill, Christopher R., E-mail: christopher.mcneill@monash.edu [Department of Materials Engineering, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Szumilo, Monika; Sirringhaus, Henning [Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Sommer, Michael [Institute of Macromolecular Chemistry, University of Freiburg, Stefan-Meier-Str. 31, 79104 Freiburg (Germany); Maniam, Subashani; Langford, Steven J. [School of Chemistry, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Thomsen, Lars [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)

    2014-04-28

    Near-edge X-ray absorption fine-structure (NEXAFS) spectroscopy is an important tool for probing the structure of conjugated polymer films used in organic electronic devices. High-performance conjugated polymers are often donor-acceptor co-polymers which feature a repeat unit with multiple functional groups. To facilitate better application of NEXAFS spectroscopy to the study of such materials, improved understanding of the observed NEXAFS spectral features is required. In order to examine how the NEXAFS spectrum of a donor-acceptor co-polymer relates to the properties of the sub-units, a series of naphthalene diimide-thiophene-based co-polymers have been studied where the nature and length of the donor co-monomer has been systematically varied. The spectra of these materials are compared with that of a thiophene homopolymer and naphthalene diimide monomer enabling peak assignment and the influence of inter-unit electronic coupling to be assessed. We find that while it is possible to attribute peaks within the π* manifold as arising primarily due to the naphthalene diimide or thiophene sub-units, very similar dichroism of these peaks is observed indicating that it may not be possible to separately probe the molecular orientation of the separate sub-units with carbon K-edge NEXAFS spectroscopy.

  5. Evidence for Al/Si tetrahedral network in aluminosilicate glasses from Al K-edge x-ray absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Z. [Laboratoire Pierre Sue, CEA-CNRS CE Saclay, Gif-sur Yvette (France)]|[INFN, Laboratori Nazionali di Frascati, Rome (Italy); Romano, C. [Rome, Univ. `Roma Tre` (Italy). Dip di Scienze Geologiche]|[Univ. Bayreuth (Germany). Bayerishes Geoinstitut; Marcelli, A.; Cibin, G. [INFN, Laboratori Nazionali di Frascati, Rome (Italy); Mottana, A.; Della Ventura, G. [Rome, Univ. `Roma Tre` (Italy). Dip di Scienze Geologiche]|[INFN, Laboratori Nazionali di Frascati, Rome (Italy); Giuli, G. [Florence Univ. (Italy). Dip. Scienze Mineralogiche; Courtial, P.; Dinwell, D.B. [Univ. Bayreuth (Germany). Bayerishes Geoinstitut

    1998-11-01

    The structure of aluminosilicate melts/glasses plays a key role in Earth Sciences for the understanding of rock-forming igneous processes, as well as in the Materials Sciences for their technical applications. In particular, the alkaline earth aluminosilicate glasses are an extremely important group of materials, with a wide range of commercial application, as well as serving as analogue for natural basaltic melts. However, definition of their structure and properties is still controversial, and in particular the role and effect of Al has long been a subject of debate. The paper reports a series of experimental x-ray absorption near-edge structure (XANES) spectra at the Al K edge on a series of synthetic glasses of peralkaline composition in the CaO-Al{sub 2}O{sub 3}-SiO{sub 2} system, together with a general theoretical framework for data analysis based on an ab initio full multiple scattering (MS) theory. It`s proposed an Al/Si tetrahedral network model for aluminosilicate glasses based on distorted polyhedra, with varying both the T-O (T=Al or Si) bond lengths and the T-O-T angles, and with different Al/Si composition. This model achieves a significant agreement between experiments and simulations. in these glasses, experimental data and theoretical results concur to support a model in which Al is network-former with a comparatively well ordered local medium-range order (up to 5 A).

  6. Multi-epoch Detections of Water Ice Absorption in Edge-on Disks around Herbig Ae Stars: PDS 144N and PDS 453

    Science.gov (United States)

    Terada, Hiroshi; Tokunaga, Alan T.

    2017-01-01

    We report the multi-epoch detections of water ice in 2.8-4.2 μ {{m}} spectra of two Herbig Ae stars, PDS 144N (A2 IVe) and PDS 453 (F2 Ve), which have an edge-on circumstellar disk. The detected water ice absorption is found to originate from their protoplanetary disks. The spectra show a relatively shallow absorption of water ice of around 3.1 μ {{m}} for both objects. The optical depths of the water ice absorption are ˜0.1 and ˜0.2 for PDS 144N and PDS 453, respectively. Compared to the water ice previously detected in low-mass young stellar objects with an edge-on disk with a similar inclination angle, these optical depths are significantly lower. It suggests that stronger UV radiation from the central stars effectively decreases the water ice abundance around the Herbig Ae stars through photodesorption. The water ice absorption in PDS 453 shows a possible variation of the feature among the six observing epochs. This variation could be due to a change of absorption materials passing through our line of sight to the central star. The overall profile of the water ice absorption in PDS 453 is quite similar to the absorption previously reported in the edge-on disk object d216-0939, and this unique profile may be seen only at a high inclination angle in the range of 76°-80°.

  7. K-edge imaging in x-ray computed tomography using multi-bin photon counting detectors.

    Science.gov (United States)

    Roessl, E; Proksa, R

    2007-08-07

    After passage through matter, the energy spectrum of a polychromatic beam of x-rays contains valuable information about the elemental composition of the absorber. Conventional x-ray systems or x-ray computed tomography (CT) systems, equipped with scintillator detectors operated in the integrating mode, are largely insensitive to this type of spectral information, since the detector output is proportional to the energy fluence integrated over the whole spectrum. The main purpose of this paper is to investigate to which extent energy-sensitive photon counting devices, operated in the pulse-mode, are capable of revealing quantitative information about the elemental composition of the absorber. We focus on the detection of element-specific, K-edge discontinuities of the photo-electric cross-section. To be specific, we address the question of measuring and imaging the local density of a gadolinium-based contrast agent, in the framework of a generalized dual-energy pre-processing. Our results are very promising and seem to open up new possibilities for the imaging of the distribution of elements with a high atomic number Z in the human body using x-ray attenuation measurements. To demonstrate the usefulness of the detection and the appropriate processing of the spectral information, we present simulated images of an artherosclerotic coronary vessel filled with gadolinium-based contrast agent. While conventional systems, equipped with integrating detectors, often fail to differentiate between contrast filled lumen and artherosclerotic plaque, the use of an energy-selective detection system based on the counting of individual photons reveals a strong contrast between plaque and contrast agent.

  8. Cauchois and S\\'en\\'emaud Tables of wavelengths of X-ray emission lines and absorption edges

    CERN Document Server

    Jonnard, Philippe; 10.1002/xrs.1293

    2011-01-01

    We present the Cauchois and S\\'en\\'emaud Tables of X-ray emission lines and absorption edges. They are written both in French and English. They were published in 1978 by Pergamon Press and are insufficiently known. However they are of large interest because of their completeness. They comprise the energies of all the K, L, M, N and O emission lines of natural elements from lithium up to uranium as well as the energies of satellite emissions and absorption discontinuities. The more intense lines of radio-elements up to fermium (Z = 100) are also given. The Tables range from the hard X-rays (122 keV, 0.01 nm) to the extreme ultra-violet (12 eV, 102 nm). For each transition, the wavelength ({\\AA} and uX) and energy (eV and Ry) are given and references are indicated. The transitions are grouped by increasing wavelength (decreasing photon energy) and also by element and spectral series. We present, as an example, the use of the Tables to identify the emissions of the molybdenum L spectrum. We decided to scan the C...

  9. A Monte Carlo simulation study of an improved K-edge log-subtraction X-ray imaging using a photon counting CdTe detector

    Science.gov (United States)

    Lee, Youngjin; Lee, Amy Candy; Kim, Hee-Joung

    2016-09-01

    Recently, significant effort has been spent on the development of photons counting detector (PCD) based on a CdTe for applications in X-ray imaging system. The motivation of developing PCDs is higher image quality. Especially, the K-edge subtraction (KES) imaging technique using a PCD is able to improve image quality and useful for increasing the contrast resolution of a target material by utilizing contrast agent. Based on above-mentioned technique, we presented an idea for an improved K-edge log-subtraction (KELS) imaging technique. The KELS imaging technique based on the PCDs can be realized by using different subtraction energy width of the energy window. In this study, the effects of the KELS imaging technique and subtraction energy width of the energy window was investigated with respect to the contrast, standard deviation, and CNR with a Monte Carlo simulation. We simulated the PCD X-ray imaging system based on a CdTe and polymethylmethacrylate (PMMA) phantom which consists of the various iodine contrast agents. To acquired KELS images, images of the phantom using above and below the iodine contrast agent K-edge absorption energy (33.2 keV) have been acquired at different energy range. According to the results, the contrast and standard deviation were decreased, when subtraction energy width of the energy window is increased. Also, the CNR using a KELS imaging technique is higher than that of the images acquired by using whole energy range. Especially, the maximum differences of CNR between whole energy range and KELS images using a 1, 2, and 3 mm diameter iodine contrast agent were acquired 11.33, 8.73, and 8.29 times, respectively. Additionally, the optimum subtraction energy width of the energy window can be acquired at 5, 4, and 3 keV for the 1, 2, and 3 mm diameter iodine contrast agent, respectively. In conclusion, we successfully established an improved KELS imaging technique and optimized subtraction energy width of the energy window, and based on

  10. A Monte Carlo simulation study of an improved K-edge log-subtraction X-ray imaging using a photon counting CdTe detector

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Youngjin, E-mail: radioyoungj@gmail.com [Department of Radiological Science, Eulji University, 553, Sanseong-daero, Sujeong-gu, Seongnam-si, Gyeonggi-do (Korea, Republic of); Lee, Amy Candy [Department of Mathematics and Statistics, McGill University (Canada); Kim, Hee-Joung [Department of Radiological Science and Radiation Convergence Engineering, Yonsei University (Korea, Republic of)

    2016-09-11

    Recently, significant effort has been spent on the development of photons counting detector (PCD) based on a CdTe for applications in X-ray imaging system. The motivation of developing PCDs is higher image quality. Especially, the K-edge subtraction (KES) imaging technique using a PCD is able to improve image quality and useful for increasing the contrast resolution of a target material by utilizing contrast agent. Based on above-mentioned technique, we presented an idea for an improved K-edge log-subtraction (KELS) imaging technique. The KELS imaging technique based on the PCDs can be realized by using different subtraction energy width of the energy window. In this study, the effects of the KELS imaging technique and subtraction energy width of the energy window was investigated with respect to the contrast, standard deviation, and CNR with a Monte Carlo simulation. We simulated the PCD X-ray imaging system based on a CdTe and polymethylmethacrylate (PMMA) phantom which consists of the various iodine contrast agents. To acquired KELS images, images of the phantom using above and below the iodine contrast agent K-edge absorption energy (33.2 keV) have been acquired at different energy range. According to the results, the contrast and standard deviation were decreased, when subtraction energy width of the energy window is increased. Also, the CNR using a KELS imaging technique is higher than that of the images acquired by using whole energy range. Especially, the maximum differences of CNR between whole energy range and KELS images using a 1, 2, and 3 mm diameter iodine contrast agent were acquired 11.33, 8.73, and 8.29 times, respectively. Additionally, the optimum subtraction energy width of the energy window can be acquired at 5, 4, and 3 keV for the 1, 2, and 3 mm diameter iodine contrast agent, respectively. In conclusion, we successfully established an improved KELS imaging technique and optimized subtraction energy width of the energy window, and based on

  11. Integrated fiber optic incoherent broadband cavity enhanced absorption spectroscopy detector for near-IR absorption measurements of nanoliter samples.

    Science.gov (United States)

    Gomez, Anthony L; Renzi, Ronald F; Fruetel, Julia A; Bambha, Ray P

    2012-05-10

    An integrated fiber-optic sensor is described that uses incoherent broadband cavity enhanced absorption spectroscopy for sensitive detection of aqueous samples in nanoliter volumes. Absorption was measured in a 100 µm gap between the ends of two short segments of multimode graded-index fiber that were integrated into a capillary using a precision machined V-grooved fixture that allowed for passive fiber alignment. The other ends of the fibers were coated with dielectric mirrors to form a 9.5 cm optical resonator. Light from a fiber-coupled superluminescent diode was directly coupled into one end of the cavity, and transmission was measured using a fiber-coupled silicon photodiode. Dilute aqueous solutions of near infrared dye were used to determine the minimum detectable absorption change of 2.4×10(-4) under experimental conditions in which pressure fluctuations limited performance. We also determined that the absolute minimum detectable absorption change would be 1.6×10(-5) for conditions of constant pressure in which absorption measurement is limited by electronic and optical noise. Tolerance requirements for alignment are also presented.

  12. Detectors for the Gamma-Ray Resonant Absorption (GRA) Method of Explosives Detection in Cargo: A Comparative Study

    CERN Document Server

    Vartsky, D; Engler, G; Shor, A; Goldschmidt, A; Feldman, G; Bar, D; Orion, I; Wielopolski, L; Vartsky, David; Goldberg, Mark B.; Engler, Gideon; Shor, Asher; Goldschmidt, Aharon; Feldman, Gennady; Bar, Doron; Orion, Itzhak; Wielopolski, Lucian

    2004-01-01

    Gamma-Ray Resonant Absorption (GRA) is an automatic-decision radiographic screening technique that combines high radiation penetration with very good sensitivity and specificity to nitrogenous explosives. The method is particularly well-suited to inspection of large, massive objects (since the incident gamma-ray probe is at 9.17 MeV) such as aviation and marine containers, heavy vehicles and railroad cars. Two kinds of gamma-ray detectors have been employed to date in GRA systems: 1) Resonant-response nitrogen-rich liquid scintillators and 2) BGO detectors. This paper analyses and compares the response of these detector-types to the resonant radiation, in terms of single-pixel figures of merit. The latter are sensitive not only to detector response, but also to accelerator-beam quality, via the properties of the nuclear reaction that produces the resonant gamma-rays. Generally, resonant detectors give rise to much higher nitrogen-contrast sensitivity in the radiographic image than their non-resonant detector ...

  13. Quantitative measurement of the reduction of platinum(IV) complexes using X-ray absorption near-edge spectroscopy (XANES).

    Science.gov (United States)

    Hall, Matthew D; Daly, Helen L; Zhang, Jenny Z; Zhang, Mei; Alderden, Rebecca A; Pursche, Daniel; Foran, Garry J; Hambley, Trevor W

    2012-06-01

    The platinum(II) drugs cisplatin, carboplatin and oxaliplatin are usefully employed against a range of malignancies, but toxicities and resistance have spurred the search for improved analogs. This has included investigation of the platinum(IV) oxidation state, which provides greater kinetic inertness. It is generally accepted that Pt(IV) complexes must be reduced to Pt(II) for activation. As such, the ability to monitor reduction of Pt(IV) complexes is critical to guiding the design of candidates, and providing mechanistic understanding. Here we report in full that the white line height of X-ray absorption near-edge spectra (XANES) of Pt complexes, normalized to the post-edge minima, can be used to quantitatively determine the proportion of each oxidation state in a mixture. A series of Pt(IV) complexes based on the Pt(II) complexes cisplatin and transplatin were prepared with chlorido, acetato or hydroxido axial ligands, and studies into their reduction potential and cytotoxicity against A2780 human ovarian cancer cells were performed, demonstrating the relationship between reduction potential and cytotoxicity. Analysis of white line height demonstrated a clear and consistent difference between Pt(II) (1.52 ± 0.05) and Pt(IV) (2.43 ± 0.19) complexes. Reduction of Pt(IV) complexes over time in cell growth media and A2780 cells was observed by XANES, and shown to correspond with their reduction potentials and cytotoxicities. We propose that this method is useful for monitoring reduction of metal-based drug candidates in complex biological systems.

  14. Electrosynthesis of ZnO nanorods and nanotowers: Morphology and X-ray Absorption Near Edge Spectroscopy studies

    Science.gov (United States)

    Sigircik, Gokmen; Erken, Ozge; Tuken, Tunc; Gumus, Cebrail; Ozkendir, Osman M.; Ufuktepe, Yuksel

    2015-06-01

    Deposition mechanism of nano-structured ZnO films has been investigated in the absence and presence of chloride ions from aqueous solution. The resulting opto-electronic properties were interpreted extensively, using X-ray diffraction (XRD), X-ray Absorption Near Edge Spectroscopy (XANES), field emission scanning electron microscopy (FE-SEM), UV-Visible spectroscopy and four probe techniques. The ZnO deposition is mass transport controlled process and the interaction of chloride ions with the surface has great influence on diffusion kinetics, considering the substantial species (Zn2+ and OH-) involved in the construction of ZnO film. This effect does not change major lattice parameters, as shown with detailed analysis of XRD data. However, the texture coefficient (Tc) (0 0 2) value is higher in presence of chloride ions containing synthesis solution which gave vertically aligned, well defined and uniformly dispersed nanorods structure. The calculated Eg values are in the range 3.28-3.41 eV and 3.22-3.31 eV for ZnO nanorods and nanotowers synthesized at different deposition periods, respectively. Furthermore, the charge mobility values regarding the deposition periods were measured to be in the ranges from 130.4 to 449.2 cm2 V-1 s-1 and 126.2 to 204.7 cm2 V-1 s-1 for nanorods and nanotowers, respectively. From XANES results, it was shown that the Zn K-edge spectrum is dominated by the transition of Zn 1s core electrons into the unoccupied Zn 4p states of the conduction band. Comparing the rod and tower nano-structured ZnO thin films, the excitation behavior of valence band electrons is different. Moreover, the density states of Zn 4p are higher for ZnO nanorods.

  15. Exploiting the P L2,3 absorption edge for optics: spectroscopic and structural characterization of cubic boron phosphide thin films

    NARCIS (Netherlands)

    Huber, S.P.; Medvedev, V.V.; Meyer-Ilse, J.; Gullikson, E.; Padavala, B.; Edgar, J.H.; Sturm, J.M.; Kruijs, van de R.W.E.; Prendergast, D.; Bijkerk, F.

    2016-01-01

    The transmission of cubic boron phosphide (c-BP) thin films, prepared by chemical vapor deposition (CVD), was evaluated near the phosphorous L2,3 and boron K absorption edge. The c-BP films were analyzed with transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and X-ray ab

  16. Influence of hybridization in the magnetic circular X-ray dichroism at the Ce-M(4,5) absorption edges of Ce-Fe systems

    NARCIS (Netherlands)

    Finazzi, M; deGroot, FMF; Dias, AM; Kappler, JP; Schulte, O; Felsch, W; Krill, G

    We have performed a Magnetic Circular X-ray Dichroism (XMCD) study at the Ce-M(4,5) absorption edges on some Ce-Fe systems. We find that the dichroism signal in these systems is very sensitive to the degree of hybridization of the 4f electrons with the valence band. XMCD is able to demonstrate that

  17. Influence of hybridization in the Magnetic Circular X-ray Dichroism at the Ce-M4,5 absorption edges of Ce-Fe systems

    NARCIS (Netherlands)

    Finazzi, M.; de Groot, F.M.F.; Dias, A.-M.; Kappler, J.-P.; Schulte, O.; Felsch, W.; Krill, G.

    2013-01-01

    We have performed a Magnetic Circular X-ray Dichroism (XMCD) study at the Ce-M*,s absorption edges on some Ce-Fe systems. We find that the dichroism signal in these systems is very sensitive to the degree of hybridization of the 4f electrons with the valence band. XMCD is able to demonstrate that th

  18. Influence of hybridization in the magnetic circular X-ray dichroism at the Ce-M(4,5) absorption edges of Ce-Fe systems

    NARCIS (Netherlands)

    Finazzi, M; deGroot, FMF; Dias, AM; Kappler, JP; Schulte, O; Felsch, W; Krill, G

    1996-01-01

    We have performed a Magnetic Circular X-ray Dichroism (XMCD) study at the Ce-M(4,5) absorption edges on some Ce-Fe systems. We find that the dichroism signal in these systems is very sensitive to the degree of hybridization of the 4f electrons with the valence band. XMCD is able to demonstrate that

  19. Experimental and ab initio investigations of the x-ray absorption near edge structure of orthorhombic LuMnO3

    Science.gov (United States)

    Hu, Y.; Borca, C. N.; Kleymenov, E.; Nachtegaal, M.; Delley, B.; Janousch, M.; Dönni, A.; Tachibana, M.; Kitazawa, H.; Takayama-Muromachi, E.; Kenzelmann, M.; Niedermayer, C.; Lippert, T.; Wokaun, A.; Schneider, C. W.

    2012-06-01

    X-ray near edge absorption spectroscopy was used to probe the electronic structure of multiferroic orthorhombic LuMnO3 polycrystalline samples and strained, twin-free orthorhombic (1-10) LuMnO3 films grown by pulsed laser deposition on (1-10) YAlO3 substrates. For all o-LuMnO3 samples x-ray near edge absorption spectroscopy spectra reveal that the pre-edge structure is influenced by the increase in MnO6 distortion as a result of the smaller Re-ion or film strain. Furthermore there is clear evidence of anisotropic Mn-O bonding and Mn orbital ordering along the c- and [110] direction. The experimental film and bulk data are in agreement with ab initio simulations.

  20. Femtosecond laser-induced modification of potassium-magnesium silicate glasses: An analysis of structural changes by near edge x-ray absorption spectroscopy

    Science.gov (United States)

    Seuthe, T.; Höfner, M.; Reinhardt, F.; Tsai, W. J.; Bonse, J.; Eberstein, M.; Eichler, H. J.; Grehn, M.

    2012-05-01

    The effects of femtosecond laser pulse irradiation on the glass structure of alkaline silicate glasses were investigated by x-ray absorption near edge structure spectroscopy using the beamline of the Physikalisch-Technische Bundesanstalt at the electron synchrotron BESSY II in Berlin (Germany) by analyzing the magnesium K-edge absorption peak for different laser fluences. The application of fluences above the material modification threshold (2.1 J/cm2) leads to a characteristic shift of ˜1.0 eV in the K-edge revealing a reduced (˜3%) mean magnesium bond length to the ligated oxygen ions (Mg-O) along with a reduced average coordination number of the Mg ions.

  1. Chemical shift of U L3 edges in different uranium compounds obtained by X-ray absorption spectroscopy with synchrotron radiation

    Indian Academy of Sciences (India)

    D Joseph; C Nayak; P Venu Babu; S N Jha; D Bhattacharyya

    2014-05-01

    Uranium L3 X-ray absorption edge was measured in various compounds containing uranium in U4+, U5+ and U6+ oxidation states. The measurements have been carried out at the Energy Dispersive EXAFS beamline (BL-08) at INDUS-2 synchrotron radiation source at RRCAT, Indore. Energy shifts of ∼ 2–3 eV were observed for U L3 edge in the U-compounds compared to their value in elemental U. The different chemical shifts observed for the compounds having the same oxidation state of the cation but different anions or ligands show the effect of different chemical environments surrounding the cations in determining their X-ray absorption edges in the above compounds. The above chemical effect has been quantitatively described by determining the effective charges on U cation in the above compounds.

  2. X-ray absorption and emission spectroscopy of Cr(III) (hydr)oxides: analysis of the K-pre-edge region.

    Science.gov (United States)

    Frommer, Jakob; Nachtegaal, Maarten; Czekaj, Izabela; Weng, Tsu-Chien; Kretzschmar, Ruben

    2009-11-05

    Pre-edge spectral features below the main X-ray absorption K-edge of transition metals show a pronounced chemical sensitivity and are promising sources of structural information. Nevertheless, the use of pre-edge analysis in applied research is limited because of the lack of definite theoretical peak-assignments. The aim of this study was to determine the factors affecting the chromium K-pre-edge features in trivalent chromium-bearing oxides and oxyhydroxides. The selected phases varied in the degree of octahedral polymerization and the degree of iron-for-chromium substitution in the crystal structure. We investigated the pre-edge fine structure by means of high-energy-resolution fluorescence detected X-ray absorption spectroscopy and by 1s2p resonant X-ray emission spectroscopy. Multiplet theory and full multiple-scattering calculations were used to analyze the experimental data. We show that the chromium K-pre-edge contains localized and nonlocalized transitions. Contributions arising from nonlocalized metal-metal transitions are sensitive to the nearest metal type and to the linkage mode between neighboring metal octahedra. Analyzing these transitions opens up new opportunities for investigating the local coordination environment of chromium in poorly ordered solids of environmental relevance.

  3. Determining Orientational Structure of Diamondoid Thiols Attached to Silver Using Near Edge X-ray Absorption Fine Structure Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Willey, T M; Lee, J I; Fabbri, J D; Wang, D; Nielsen, M; Randel, J C; Schreiner, P R; Fokin, A A; Tkachenko, B A; Fokina, N A; Dahl, J P; Carlson, R K; Terminello, L J; Melosh, N A; van Buuren, T

    2008-10-07

    Near-edge x-ray absorption fine structure spectroscopy (NEXAFS) is a powerful tool for determination of molecular orientation in self-assembled monolayers and other surface-attached molecules. A general framework for using NEXAFS to simultaneously determine molecular tilt and twist of rigid molecules attached to surfaces is presented. This framework is applied to self-assembled monolayers of higher diamondoid, hydrocarbon molecules with cubic-diamond-cage structures. Diamondoid monolayers chemisorbed on metal substrates are known to exhibit interesting electronic and surface properties. This work compares molecular orientation in monolayers prepared on silver substrates using two different thiol positional isomers of [121]tetramantane, and thiols derived from two different pentamantane structural isomers, [1212]pentamantane and [1(2,3)4]pentamantane. The observed differences in monolayer structure demonstrate the utility and limitations of NEXAFS spectroscopy and the framework. The results also demonstrate the ability to control diamondoid assembly, in particular the molecular orientational structure, providing a flexible platform for the modification of surface properties with this exciting new class of nanodiamond materials.

  4. Derivation of absorption coefficient and reduced scattering coefficient with edge-loss method and comparison with video reflectometry method

    Science.gov (United States)

    Yoshida, Kenichiro

    2016-08-01

    We derived the absorption coefficient ( μ a) and the reduced scattering coefficient ( μ s') using the edge-loss method (ELM) and the video reflectometry method (VRM), and compared the results. In a previous study, we developed the ELM to easily evaluate the lateral spread in the skin; the VRM is a conventional method. The ELM measures the translucency index, which is correlated with μ a and μ s'. To obtain a precise estimation of these parameters, we improved the treatment of a white standard and the surface reflection. For both skin phantoms and actual skin, the values for μ a and μ s' that we obtained using the ELM were similar to those obtained using the VRM, when μ a/ μ s' was less than or equal to 0.05 and the diffusion approximation was applicable. Under this condition, the spectral reflectivity is greater than 0.4. In this study, we considered wavelengths longer than 600 nm for Types III and IV of the Fitzpatrick scale. For skin, the repeatability errors of the parameters obtained with the ELM were smaller than those obtained with the VRM; this can be an advantage in field tests.

  5. [Chlorine speciation and concentration in cultivated soil in the northeastern China studied by X-ray absorption near edge structure].

    Science.gov (United States)

    Li, Jing; Lang, Chun-Yan; Ma, Ling-Ling; Xu, Dian-Dou; Zheng, Lei; Lu, Yu-Nanz; Cui Li-Rui; Zhang, Xiao-Meng

    2014-10-01

    A procedure has been proposed to determine chlorine speciation and concentration in soil with X-ray absorption near edge structure (XANES), and this method was applied to study the cultivated soil (bog, dark brown and black cultivated soil) in the Northeastern China. Qualitative analysis was carried out by least-squares fitting of sample spectra with standard spectra of three model compounds (NaCl, 3-chloropropionic acid, chlorophenol red). Linear correlation between the absolute fluorescence intensity of a series of NaCl standards and the Cl concentration was used as quantification standard for measuring the total Cl concentration in samples. The detection limits,relative standard deviation (RSD), recoveries were 2 mg · kg(-1), 0%-5% and 77%-133%, respectively. The average concentration of total Cl was 19 mg · kg(-1). The average relative content was as high as 61% of organochlorine with the concentration of 1-2 times as high as the concentration of inorganic chloride. The distribution trend of the total Cl, inorganic chloride and organic chlorine in different types of soil was: bog arable soil > dark brown soil > black soil. In conclusion, XANES is a reliable method to nondestructively characterize the speciation and concentration of chlorine in soil, which would provide some basic data for the future study of the chlorine's biogeochemical transformations.

  6. Chemical shifts of L3 X-ray absorption edges on lead and thallium compounds by DEXAFS using synchrotron radiation source

    Science.gov (United States)

    Kainth, Harpreet Singh; Singh, Ranjit

    2017-09-01

    The L3 absorption edges of 82Pb and 81Tl compounds have been measured using DEXAFS at INDUS-2 Synchrotron radiation source at RRCAT, Indore. The energy shift of ∼(-6 to 2) eV are observed in pre-edge of 82Pb compounds while energy shift varies ∼(-5 to 10) eV in pre-edge and ∼(2-9) eV in post-edge of 81Tl compounds. The chemical effects in both compounds have been described by calculating effective charge using Suchet and Pauling methods. A linear relation is established between chemical effect and effective charge of different compounds for the first time in literature.

  7. Electrosynthesis of ZnO nanorods and nanotowers: Morphology and X-ray Absorption Near Edge Spectroscopy studies

    Energy Technology Data Exchange (ETDEWEB)

    Sigircik, Gokmen, E-mail: gsigircik@cu.edu.tr [Chemistry Department, University of Cukurova, 01330 Adana (Turkey); Erken, Ozge [Department of Physics, Faculty Science and Letters, Adiyaman University, 02040 Adiyaman (Turkey); Tuken, Tunc [Chemistry Department, University of Cukurova, 01330 Adana (Turkey); Gumus, Cebrail [Physics Department, University of Cukurova, 01330 Adana (Turkey); Ozkendir, Osman M. [Department of Energy Systems Engineering Tarsus Technology Faculty, Mersin University, 33400 Tarsus (Turkey); Ufuktepe, Yuksel [Physics Department, University of Cukurova, 01330 Adana (Turkey)

    2015-06-15

    Highlights: • Deposition mechanism of nano-structured ZnO films has been investigated in the absence and presence of chloride ions from aqueous solution. • Uniform and well-defined ZnO nano-towers and rods have been obtained via electrochemical deposition. • The presence of chloride ions altered the nucleation rate of ZnO particles on ITO substrates and resulting crystallographic properties. • Comparing the rod and tower nano-structured ZnO thin films, the excitation behavior of valance band electrons is different. - Abstract: Deposition mechanism of nano-structured ZnO films has been investigated in the absence and presence of chloride ions from aqueous solution. The resulting opto-electronic properties were interpreted extensively, using X-ray diffraction (XRD), X-ray Absorption Near Edge Spectroscopy (XANES), field emission scanning electron microscopy (FE-SEM), UV-Visible spectroscopy and four probe techniques. The ZnO deposition is mass transport controlled process and the interaction of chloride ions with the surface has great influence on diffusion kinetics, considering the substantial species (Zn{sup 2+} and OH{sup −}) involved in the construction of ZnO film. This effect does not change major lattice parameters, as shown with detailed analysis of XRD data. However, the texture coefficient (T{sub c}) (0 0 2) value is higher in presence of chloride ions containing synthesis solution which gave vertically aligned, well defined and uniformly dispersed nanorods structure. The calculated E{sub g} values are in the range 3.28–3.41 eV and 3.22–3.31 eV for ZnO nanorods and nanotowers synthesized at different deposition periods, respectively. Furthermore, the charge mobility values regarding the deposition periods were measured to be in the ranges from 130.4 to 449.2 cm{sup 2} V{sup −1} s{sup −1} and 126.2 to 204.7 cm{sup 2} V{sup −1} s{sup −1} for nanorods and nanotowers, respectively. From XANES results, it was shown that the Zn K-edge

  8. Na-induced bonding and bond-length changes for CO on Pt(111): A near-edge x-ray-absorption fine-structure study

    Energy Technology Data Exchange (ETDEWEB)

    Sette, F.; Stoehr, J.; Kollin, E.B.; Dwyer, D.J.; Gland, J.L.; Robbins, J.L.; Johnson, A.L.

    1985-03-04

    Near-edge x-ray absorption fine-structure studies above the C and O K edges for CO on Pt(111) reveal a 4-eV shift of the sigma shape resonance when Na(0.2 monolayer) is coabsorbed. This allows determination of a Na-induced (0.12 +- 0.03)-A expansion of the C-O bond. Na does not affect the vertical molecular orientation on the surface. Reduction and broadening of the 1s..-->..2..pi..( resonance and the CO bond lengthening in the presence of Na signifies substantially increased metal to CO backbonding.

  9. Short-wave infrared barriode detectors using InGaAsSb absorption material lattice matched to GaSb

    Energy Technology Data Exchange (ETDEWEB)

    Craig, A. P.; Percy, B.; Marshall, A. R. J. [Physics Department, Lancaster University, Lancaster LA1 4YB (United Kingdom); Jain, M. [Amethyst Research Ltd., Kelvin Campus, West of Scotland Science Park, Glasgow G20 0SP (United Kingdom); Wicks, G.; Hossain, K. [Amethyst Research, Inc., 123 Case Circle, Ardmore, Oklahoma 73401 (United States); Golding, T. [Amethyst Research Ltd., Kelvin Campus, West of Scotland Science Park, Glasgow G20 0SP (United Kingdom); Amethyst Research, Inc., 123 Case Circle, Ardmore, Oklahoma 73401 (United States); McEwan, K.; Howle, C. [Defence Science and Technology Laboratory, Porton Down, Salisbury, Wiltshire SP4 0JQ (United Kingdom)

    2015-05-18

    Short-wave infrared barriode detectors were grown by molecular beam epitaxy. An absorption layer composition of In{sub 0.28}Ga{sub 0.72}As{sub 0.25}Sb{sub 0.75} allowed for lattice matching to GaSb and cut-off wavelengths of 2.9 μm at 250 K and 3.0 μm at room temperature. Arrhenius plots of the dark current density showed diffusion limited dark currents approaching those expected for optimized HgCdTe-based detectors. Specific detectivity figures of around 7×10{sup 10} Jones and 1×10{sup 10} Jones were calculated, for 240 K and room temperature, respectively. Significantly, these devices could support focal plane arrays working at higher operating temperatures.

  10. Multi-Epoch Detections of Water Ice Absorption in Edge-on Disks around Herbig Ae Stars: PDS 144N and PDS 453

    CERN Document Server

    Terada, Hiroshi

    2016-01-01

    We report the multi-epoch detections of the water ice in 2.8-4.2 micron spectra of two Herbig Ae stars, PDS 144N (A2 IVe) and PDS 453 (F2 Ve), which have an edge-on circumstellar disk. The detected water ice absorption is found to originate from their protoplanetary disks. The spectra show a relatively shallow absorption of water ice around 3.1 micron for both objects. The optical depths of the water ice absorption are ~0.1 and ~0.2 for PDS 144N and PDS 453, respectively. Compared to the water ice previously detected in low-mass young stellar objects with an edge-on disk with a similar inclination angle, these optical depths are significantly lower. It suggests that stronger UV radiation from the central stars effectively decreases the water ice abundance around the Herbig Ae stars through photodesorption. The water ice absorption in PDS 453 shows a possible variation of the feature among the six observing epochs. This variation could be due to a change of absorption materials passing through our line-of-sigh...

  11. INVESTIGATION OF BONDING IN NANO-SiO2 BY Si L2,3 X-RAY ABSORPTION NEAR-EDGE STRUCTURE SPECTROSCOPY

    Institute of Scientific and Technical Information of China (English)

    Z.Y. Wu; K. Ibrahim; G. Li; J. Zhang; F.Q. Liu; M.I. Abbas; R. Hu; H.J. Qian; F.Q. Tang

    2001-01-01

    The Si L2,3 X-ray absorption near-edge structure (XANES) can be used to probe thelocal structure around Si and derive electronic information of the unoccupied s- andd-like partial density of states in nano-size SiO2. We present Si L2,3-edge for threedifferent size silicates acquired by total electron yield (TEY) at the photoemission sta-tion of Beijing Synchrotron Radiation Facility (BSRF). The Si L2,3-edge spectra areinterpreted based on ab initio full multiple-scattering (MS) calculation. The Si L2.3-edge of nano-size materials has XANES similar to that of a-quartz. The similaritiesbetween the Si L2.3-edge shapes attest to a common molecular-orbital picture of theirSi-O bonding and the same coordination state. However, a considerable broadeningof Si L2,3-edge XANES spectra as decrease of particle size is also an indicative ofpolyhedral distortions.

  12. Theoretical X-ray production cross sections at incident photon energies across Li (i=1-3) absorption edges of Br

    Science.gov (United States)

    Puri, Sanjiv

    2015-08-01

    The X-ray production (XRP) cross sections, σLk (k = l, η, α, β6, β1, β3, β4, β9,10, γ1,5, γ2,3) have been evaluated at incident photon energies across the Li(i=1-3) absorption edge energies of 35Br using theoretical data sets of different physical parameters, namely, the Li(i=1-3) sub-shell the X-ray emission rates based on the Dirac-Fock (DF) model, the fluorescence and Coster Kronig yields based on the Dirac-Hartree-Slater (DHS) model, and two sets of the photoionisation cross sections based on the relativistic Hartree-Fock-Slater (RHFS) model and the Dirac-Fock (DF) model, in order to highlight the importance of electron exchange effects at photon energies in vicinity of absorption edge energies.

  13. Simulating Cl K-edge X-ray absorption spectroscopy in MCl62- (M= U, Np, Pu) complexes and UOCl5- using time-dependent density functional theory

    Energy Technology Data Exchange (ETDEWEB)

    Govind, Niranjan; De Jong, Wibe A.

    2014-02-21

    We report simulations of the X-ray absorption near edge structure (XANES) at the Cl K-edge of actinide hexahalides MCl62- (M = U, Np, Pu) and the UOCl5- complex using linear-response time-dependent density functional theory (LR-TDDFT) extended for core excitations. To the best of our knowledge, these are the first calculations of the Cl K-edge spectra of NpCl62- and PuCl62-. In addition, the spectra are simulated with and without the environmental effects of the host crystal as well as ab initio molecular dynamics (AIMD) to capture the dynamical effects due to atomic motion. The calculated spectra are compared with experimental results, where available and the observed trends are discussed.

  14. Simulating Ru L3-edge X-ray Absorption Spectroscopy with Time-Dependent Density Functional Theory: Model Complexes and Electron Localization in Mixed-Valence Metal Dimers

    Energy Technology Data Exchange (ETDEWEB)

    Van Kuiken, Benjamin E.; Valiev, Marat; Daifuku, Stephanie L.; Bannan, Caitlin; Strader, Matthew L.; Cho, Hana; Huse, N.; Schoenlein, R. W.; Govind, Niranjan; Khalil, Munira

    2013-05-01

    Ruthenium L2,3-edge X-ray absorption (XA) spectroscopy probes transitions from core 2p orbitals to the 4d levels of the atom and is a powerful tool for interrogating the local electronic and molecular structure around the metal atom. However, a molecular-level interpretation of the Ru L2,3-edge spectral lineshapes is often complicated by spin–orbit coupling (SOC) and multiplet effects. In this study, we develop spin-free time-dependent density functional theory (TDDFT) as a viable and predictive tool to simulate the Ru L3-edge spectra. We successfully simulate and analyze the ground state Ru L3-edge XA spectra of a series of RuII and RuIII complexes: [Ru(NH3)6]2+/3+, [Ru(CN)6]4-/3-, [RuCl6]4-/3-, and the ground (1A1) and photoexcited (3MLCT) transient states of [Ru(bpy)3]2+ and Ru(dcbpy)2(NCS)2 (termed N3). The TDDFT simulations reproduce all the experimentally observed features in Ru L3-edge XA spectra. The advantage of using TDDFT to assign complicated Ru L3-edge spectra is illustrated by its ability to identify ligand specific charge transfer features in complex molecules. We conclude that the B3LYP functional is the most reliable functional for accurately predicting the location of charge transfer features in these spectra. Experimental and simulated Ru L3-edge XA spectra are presented for the transition metal mixed-valence dimers [(NC)5MII-CN-RuIII(NH3)5]- (where M = Fe or Ru) dissolved in water. We explore the spectral signatures of electron delocalization in Ru L3-edge XA spectroscopy and our simulations reveal that the inclusion of explicit solvent molecules is crucial for reproducing the experimentally determined valencies, highlighting the importance of the role of the solvent in transition metal charge transfer chemistry.

  15. Pre-edge features in X-ray absorption structure of Mn in GaMnN, GaMnAs and GeMn

    Energy Technology Data Exchange (ETDEWEB)

    Titov, A. [A.M. Prokhorov General Physics Institute, Russian Academy of Sciences, Vavilov str. 38, 119991 Moscow (Russian Federation) and ' Nanophysique et Semiconducteurs' , CEA-CNRS-Universite Joseph Fourier Grenoble, Laboratoire de Spectrometrie Physique, BP 87, 38402 St Martin d' Heres cedex (France)]. E-mail: titov@nsc.gpi.ru; Kulatov, E. [A.M. Prokhorov General Physics Institute, Russian Academy of Sciences, Vavilov str. 38, 119991 Moscow (Russian Federation); Uspenskii, Yu.A. [Lebedev Physical Institute, Russian Academy of Sciences, Leninskii prosp. 53, 119991 Moscow (Russian Federation); Biquard, X. [DRFMC-SP2M, CEA Grenoble-38054 Grenoble cedex 9 (France); Halley, D. [' Nanophysique et Semiconducteurs' , CEA-CNRS-Universite Joseph Fourier Grenoble, Laboratoire de Spectrometrie Physique, BP 87, 38402 St Martin d' Heres cedex (France); Kuroda, S. [' Nanophysique et Semiconducteurs' , CEA-CNRS-Universite Joseph Fourier Grenoble, Laboratoire de Spectrometrie Physique, BP 87, 38402 St Martin d' Heres cedex (France); Bellet-Amalric, E. [' Nanophysique et Semiconducteurs' , CEA-CNRS-Universite Joseph Fourier Grenoble, Laboratoire de Spectrometrie Physique, BP 87, 38402 St Martin d' Heres cedex (France); DRFMC-SP2M, CEA Grenoble-38054 Grenoble cedex 9 (France); Mariette, H. [' Nanophysique et Semiconducteurs' , CEA-CNRS-Universite Joseph Fourier Grenoble, Laboratoire de Spectrometrie Physique, BP 87, 38402 St Martin d' Heres cedex (France); Cibert, J. [Laboratoire Louis Neel, CNRS, BP 166, 38042 Grenoble cedex 9 (France)

    2006-05-15

    Ga{sub 1-x}Mn{sub x}N samples with a wide range of concentrations, from x=0.003 to 0.057, were grown by molecular beam epitaxy. X-ray diffraction and the simulation of the extended X-ray absorption fine structure (EXAFS) confirmed the wurtzite structure of the samples, without any secondary phase, and the location of Mn in the gallium sublattice of GaN. The valence state of Mn was studied using the X-ray absorption near-edge structure (XANES) at the K-edge of Mn. The shape of the measured XANES spectra does not depend on the Mn concentration: that implies the same valence state and local atomic structure around the Mn atom in all samples. A calculation of the electronic band structure of GaMnN, GaMnAs, GeMn and the XANES spectra of Mn in GaMnN was performed using the linearized augmented plane wave (LAPW) method. The calculated spectra fit well our experimental data. In particular, the comparison demonstrates that a peak in the pre-edge structure is directly related to the 3+ valence state of Mn. This was confirmed experimentally by measurements of the Mn K-edge in GaMn{sup 2+}As and ZnMn{sup 2+}Te. An application of proposed interpretation for GeMn is discussed.

  16. Pre-edge features in X-ray absorption structure of Mn in GaMnN, GaMnAs and GeMn

    Science.gov (United States)

    Titov, A.; Kulatov, E.; Uspenskii, Yu. A.; Biquard, X.; Halley, D.; Kuroda, S.; Bellet-Amalric, E.; Mariette, H.; Cibert, J.

    2006-05-01

    Ga1-xMnxN samples with a wide range of concentrations, from x=0.003 to 0.057, were grown by molecular beam epitaxy. X-ray diffraction and the simulation of the extended X-ray absorption fine structure (EXAFS) confirmed the wurtzite structure of the samples, without any secondary phase, and the location of Mn in the gallium sublattice of GaN. The valence state of Mn was studied using the X-ray absorption near-edge structure (XANES) at the K-edge of Mn. The shape of the measured XANES spectra does not depend on the Mn concentration: that implies the same valence state and local atomic structure around the Mn atom in all samples. A calculation of the electronic band structure of GaMnN, GaMnAs, GeMn and the XANES spectra of Mn in GaMnN was performed using the linearized augmented plane wave (LAPW) method. The calculated spectra fit well our experimental data. In particular, the comparison demonstrates that a peak in the pre-edge structure is directly related to the 3+ valence state of Mn. This was confirmed experimentally by measurements of the Mn K-edge in GaMnAs and ZnMnTe. An application of proposed interpretation for GeMn is discussed.

  17. Limitations and design considerations for donor-acceptor systems in luminescent solar concentrators: the effect of coupling-induced red-edge absorption

    Science.gov (United States)

    MacQueen, Rowan W.; Tayebjee, Murad J. Y.; Webb, James E. A.; Falber, Alexander; Thordarson, Pall; Schmidt, Timothy W.

    2016-06-01

    Luminescent solar concentrators (LSCs) use luminescence and waveguiding to concentrate photons within thin dielectric slabs for use in photovoltaic, lighting, and photobioreactor applications. Donor-acceptor systems of organic chromophores are widely used in LSCs to broaden the sunlight absorption range and attempt to reduce loss-inducing reabsorption by the emitting chromophore. We use raytrace simulations across a large parameter space to model the performance of LSCs containing two novel donor-acceptor trimers based on the perylene moiety. We find that under certain conditions, trimers outperform single-dye LSCs as expected. However, at higher concentrations, a slight increase in red-edge absorption by the trimers increases reabsorption and has a deleterious effect on LSC performance. This underscores the large effect that even small changes in the red edge can have, and may discourage the use of donor-acceptor schemes with high interchromophore coupling that promotes red-edge absorption. Finally, we show that for a LSC-PV pair, selecting a PV cell that is well-matched with the LSC emission spectrum has a large effect on the flux gain of the system, and that the systems studied here are well-matched to emerging PV technologies.

  18. Technical Note: Impact on detective quantum efficiency of edge angle determination method by International Electrotechnical Commission methodology for cardiac x-ray image detectors

    Energy Technology Data Exchange (ETDEWEB)

    Gislason-Lee, Amber J., E-mail: A.J.Gislason@leeds.ac.uk; Tunstall, Clare M.; Kengyelics, Stephen K.; Cowen, Arnold R.; Davies, Andrew G. [LXi Research, Division of Biomedical Imaging, University of Leeds, Worsley Building, Clarendon Way, Leeds LS2 9JT (United Kingdom)

    2015-08-15

    Purpose: Cardiac x-ray detectors are used to acquire moving images in real-time for angiography and interventional procedures. Detective quantum efficiency (DQE) is not generally measured on these dynamic detectors; the required “for processing” image data and control of x-ray settings have not been accessible. By 2016, USA hospital physicists will have the ability to measure DQE and will likely utilize the International Electrotechnical Commission (IEC) standard for measuring DQE of dynamic x-ray imaging devices. The current IEC standard requires an image of a tilted tungsten edge test object to obtain modulation transfer function (MTF) for DQE calculation. It specifies the range of edge angles to use; however, it does not specify a preferred method to determine this angle for image analysis. The study aimed to answer the question “will my choice in method impact my results?” Four different established edge angle determination methods were compared to investigate the impact on DQE. Methods: Following the IEC standard, edge and flat field images were acquired on a cardiac flat-panel detector to calculate MTF and noise power spectrum, respectively, to determine DQE. Accuracy of the methods in determining the correct angle was ascertained using a simulated edge image with known angulations. Precision of the methods was ascertained using variability of MTF and DQE, calculated via bootstrapping. Results: Three methods provided near equal angles and the same MTF while the fourth, with an angular difference of 6%, had a MTF lower by 3% at 1.5 mm{sup −1} spatial frequency and 8% at 2.5 mm{sup −1}; corresponding DQE differences were 6% at 1.5 mm{sup −1} and 17% at 2.5 mm{sup −1}; differences were greater than standard deviations in the measurements. Conclusions: DQE measurements may vary by a significant amount, depending on the method used to determine the edge angle when following the IEC standard methodology for a cardiac x-ray detector. The most

  19. Technical Note: Impact on detective quantum efficiency of edge angle determination method by International Electrotechnical Commission methodology for cardiac x-ray image detectors.

    Science.gov (United States)

    Gislason-Lee, Amber J; Tunstall, Clare M; Kengyelics, Stephen K; Cowen, Arnold R; Davies, Andrew G

    2015-08-01

    Cardiac x-ray detectors are used to acquire moving images in real-time for angiography and interventional procedures. Detective quantum efficiency (DQE) is not generally measured on these dynamic detectors; the required "for processing" image data and control of x-ray settings have not been accessible. By 2016, USA hospital physicists will have the ability to measure DQE and will likely utilize the International Electrotechnical Commission (IEC) standard for measuring DQE of dynamic x-ray imaging devices. The current IEC standard requires an image of a tilted tungsten edge test object to obtain modulation transfer function (MTF) for DQE calculation. It specifies the range of edge angles to use; however, it does not specify a preferred method to determine this angle for image analysis. The study aimed to answer the question "will my choice in method impact my results?" Four different established edge angle determination methods were compared to investigate the impact on DQE. Following the IEC standard, edge and flat field images were acquired on a cardiac flat-panel detector to calculate MTF and noise power spectrum, respectively, to determine DQE. Accuracy of the methods in determining the correct angle was ascertained using a simulated edge image with known angulations. Precision of the methods was ascertained using variability of MTF and DQE, calculated via bootstrapping. Three methods provided near equal angles and the same MTF while the fourth, with an angular difference of 6%, had a MTF lower by 3% at 1.5 mm(-1) spatial frequency and 8% at 2.5 mm(-1); corresponding DQE differences were 6% at 1.5 mm(-1) and 17% at 2.5 mm(-1); differences were greater than standard deviations in the measurements. DQE measurements may vary by a significant amount, depending on the method used to determine the edge angle when following the IEC standard methodology for a cardiac x-ray detector. The most accurate and precise methods are recommended for absolute assessments and

  20. Economical and Efficient Detector for Fluorescent X-Ray Absorption Spectroscopy

    Science.gov (United States)

    Khalid, S. M.; Rosenbaum, G.; Chance, B.

    1986-08-01

    The available synchrotron radiation sources and those proposed for construction in the near future in the US and abroad can produce fluxes of x-radiation high enough that the fluorescent and scattered flux even from biological samples approach and will exceed acceptable levels of counting losses even in fast photon counting detector system. Ionization chambers in current integration mode can afford very high flux and large apertures. But they suffer time limitations in the fraction of the millisecond region, microphonics, and the necessity of a gas supply of very constant pressure. We have developed an alternative detector system consisting of a photomultiplier tube equipped with a highly efficient ZnS (Ag) scintillator in current integration mode. It can have apertures up to 5 inches in diameter and a time resolution adequate for rapid reaction studies using synchrontron radiation (70 ns decay time to 10%). In initial tests, we did not detect any saturation effects with the fluxes available. The advantages of these detectors seem to be simplicity and reliability in addition to freedom from environmental effects and the relatively low cost compared to other devices. These detectors have been used successfully at the Photon Factory, Japan and at CHESS.

  1. Near-edge X-ray absorption fine structure studies of Cr{sub 1−x}M{sub x}N coatings

    Energy Technology Data Exchange (ETDEWEB)

    Mahbubur Rahman, M. [School of Engineering and Information Technology, Murdoch University, Murdoch, WA 6150 (Australia); Department of Physics, Jahangirnagar University, Savar, Dhaka 1342 (Bangladesh); Duan, Alex [School of Chemistry, The University of Melbourne, Parkville, VIC 3010 (Australia); Jiang, Zhong-Tao, E-mail: Z.Jiang@murdoch.edu.au [School of Engineering and Information Technology, Murdoch University, Murdoch, WA 6150 (Australia); Xie, Zonghan [School of Mechanical Engineering, University of Adelaide, SA 5005 (Australia); School of Engineering, Edith Cowan University, WA 6027 (Australia); Wu, Alex [School of Chemistry, The University of Melbourne, Parkville, VIC 3010 (Australia); Amri, Amun [Department of Chemical Engineering, Riau University, Pekanbaru (Indonesia); Cowie, Bruce [Australian Synchrotron, 800 Blackburn Rd., Clayton, VIC 3168 (Australia); Yin, Chun-Yang [Chemical and Analytical Sciences, Murdoch University, Murdoch, WA 6150 (Australia)

    2013-11-25

    Highlights: •Al or Si is doped on CrN and AlN coatings using magnetron sputtering system. •NEXAFS analysis is conducted to measure the Al and Si K-edges, and chromium L-edge. •Structural evolution of CrN matrix with addition of Al or Si element is investigated. -- Abstract: Cr{sub 1−x}M{sub x}N coatings, with doping concentrations (Si or Al) varying from 14.3 to 28.5 at.%, were prepared on AISI M2 tool steel substrates using a TEER UDP 650/4 closed field unbalanced magnetron sputtering system. Near-edge X-ray absorption fine structure (NEXAFS) characterization was carried out to measure the aluminum and silicon K-edges, as well as chromium L-edge, in the coatings. Two soft X-ray techniques, Auger electron yield (AEY) and total fluorescence yield (TFY), were employed to investigate the surface and inner structural properties of the materials in order to understand the structural evolution of CrN matrix with addition of Al (or Si) elements. Investigations on the local bonding states and grain boundaries of the coatings, using NEXAFS technique, provide significant information which facilitates understanding of the local electronic structure of the atoms and shed light on the origins of the high mechanical strength and oxidation resistance of these technologically important coatings.

  2. Discovery of an ionized Fe-K edge in the z=3.91 Broad Absorption Line Quasar APM 08279+5255 with XMM-Newton

    CERN Document Server

    Hasinger, G; Komossa, S

    2002-01-01

    Recent XMM-Newton observations of the high-redshift, lensed, broad absorption line (BAL) quasi-stellar object APM 08279+5255, one of the most luminous objects in the universe, allowed the detection of a high column density absorber ($N_H \\approx 10^{23}$ cm$^{-2}$) in the form of a K-shell absorption edge of significantly ionized iron (Fe XV - XVIII) and corresponding ionized lower-energy absorption. Our findings confirm a basic prediction of phenomenological geometry models for the BAL outflow and can constrain the size of the absorbing region. The Fe/O abundance of the absorbing material is significantly higher than solar (Fe/O = 2-5), giving interesting constraints on the gas enrichment history in the early Universe.

  3. Development of the Next Generation of Multi-chroic Antenna-Coupled Transition Edge Sensor Detectors for CMB Polarimetry

    Science.gov (United States)

    Westbrook, B.; Cukierman, A.; Lee, A.; Suzuki, A.; Raum, C.; Holzapfel, W.

    2016-07-01

    We present the development of the next generation of multi-chroic sinuous antenna-coupled transition edge sensor (TES) bolometers optimized for precision measurements of polarization of the cosmic microwave background (CMB) and cosmic foreground. These devices employ a polarization sensitive broadband self-complementary sinuous antenna to feed on-chip band defining filters before delivering the power to load resistors coupled to a TES on a released bolometer island. This technology was originally developed by UC Berkeley and will be deployed by POLARBEAR-2 and SPT-3G in the next year and half. In addition, it is a candidate detector for the LiteBIRD mission which will make all sky CMB and cosmic foreground polarization observations from a satellite platform in the early 2020's. This works focuses on expanding both the bandwidth and band count per pixel of this technology in order to meet the needs of future CMB missions. This work demonstrates that these devices are well suited for observations between 20 and 380 GHz. This proceeding describes the design, fabrication, and the characterization of three new pixel types: a low-frequency triplexing pixel (LFTP) with bands centered on 40, 60, and 90 GHz, a high-frequency triplexing pixel (HFTP) with bands centered on 220, 280, and 350 GHz, and a mid-frequency tetraplexing pixel with bands (MFTP) centered on 90, 150, 220, and 280 GHz. The average fractional bandwidth of these pixels designs was 36.7, 34.5, and 31.4 % respectively. In addition we found that the polarization modulation efficiency of each band was between 1 and 3 % which is consistent with the polarization efficiency of the wire grid used to take the measurement. Finally, we find that the beams have {˜ }1 % ellipticity for each pixel type. The thermal properties of the bolometers where tuned for characterization in our lab so we do not report on G and noise values as they would be unsuitable for modern CMB experiments.

  4. An Improved Bi-Window Edge Detector for SAR Images%一种改进型双窗的SAR图像边缘检测器

    Institute of Scientific and Technical Information of China (English)

    梁鑫; 徐慧

    2015-01-01

    传统矩形双窗在检测非理想边缘时容易在边缘附近检测出错误边缘点,出现检测结果会偏移的问题。针对传统矩形窗函数平滑效果较差的局限性,设计了一种Gauss-Gamma形双窗函数算法,采用可接收操作特征(ROC)曲线来评价使用这两种双窗检测器在SAR图像中的性能。结果表明,新方法的检测有更好的边缘连接性,在边缘附近错误边缘较少,明显优于矩形双窗检测器。%With traditional rectangular bi-window to detect non-ideal edge ,iteasily detects an error about the edge point in the vicinity of the edge ,and the test results will appear offset. Aiming at the limita⁃tion of traditional rectangular window that the function smoothing effect is poorer ,designed a kind of Gauss-Gamma type double window function algorithm ,by using the ROC curve to compare and evaluate the two kinds of dual-window detector performance used in SAR images.The results showed that the new method of detection had a better edge connectivity ,the marginal error near the edge was less ,and was sig⁃nificantly better than the rectangular bi-window detector.

  5. In situ La, Ce, and Nd L-edge X-ray absorption fine structure study of an intermetallic metal hydride electrode in an operating alkaline battery

    Energy Technology Data Exchange (ETDEWEB)

    Tryk, D.A.; Bae, I.T.; Scherson, D. [Case Western Reserve Univ., Cleveland, OH (United States). Dept. of Chemistry; Antonio, M.R. [Argonne National Lab., IL (United States). Chemistry Division; Jordan, G.W.; Huston, E.L. [Energizer Power Systems, Gainesville, FL (United States)

    1995-05-01

    The X-ray absorption fine structure of a technologically important MmL{sub 5} intermetallic compound (Mm = La{sub 0.52}Ce{sub 0.34}Nd{sub 0.10}Pr{sub 0.04}, L{sub 5} Ni{sub 3.5}Ca{sub 0.8}Mn{sub 0.3}Al{sub 0.4}) in the form of a hydrogen storage cathode was recorded in situ in the region 5440-6290 eV using an electrochemical cell which is essentially a fully functioning alkaline battery. Significant differences were observed in the X-ray absorption near edge structure (XANES) of all of the absorption edges (La, Ce, and Nd) between the uncharged and fully charged states. In particular, a clear increase in the intensity of the La and Nd L{sub III}-edge resonances (due to 2P{sub 3/2} {r_arrow} 5d electronic transitions) was found upon charging the cell. This phenomenon was attributed to an increase in the density of empty d-like states near the Fermi level following hydrogen injection into the lattice. Furthermore, the behavior of the Ca L{sub II,III}-edges of this battery material upon charging was nearly the same as that observed for the gas phase hydrogenation of the Ce{sub 2}Fe{sub 17} and Ce{sub 2}Fe{sub 14}B intermetallics reported in the literature.

  6. Order-disorder in olivine minerals by synchrotron X-ray absorption near-edge structure (Xane) spectroscopy at the Mg, Fe and Ca K edges

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Z.; Marcelli, A.; Cibin, G. [Istituto Nazionale di Fisica Nucleare, Frascati, RM (Italy). Laboratori Nazionali di Frascati; Mottana, A. [Istituto Nazionale di Fisica Nucleare, Frascati, RM (Italy). Laboratori Nazionali di Frascati; Rome Univ. Roma Tre, Rome (Italy). Dipt. di Scienze Geologiche; Paris, E.; Giuli, G [INFM, Camerino Univ., Camerino, MC (Italy). Dipt. di Scienze della Terra

    1999-07-01

    In this paper, are presented new, high-resolution experimental spectra at the Mg and Fe K edges for the two Fe-Mg end members F o and F a, and for three other olivines. Two are the Ca end members of the family, namely monticellite (Mtc: CaMgSiO4) and kirschsteinite (Krs: CaFeSiO4). The main purpose of this work is to investigate the effects of Mg, Fe, and Ca partition in the Pbnm (or {alpha}) olivine structure on the electronic properties, as well as the relationships that exist between chemical substitutions and features occurring in Xanes spectra. One wants to explore the relationships that intervene between LRO, as determined by XRD, and SRO, as determined by Xanes, on the endmembers and on a well-known intermediate member as well, and deduce from it a model for the behavior of the entire olivine solid-solution system.

  7. The different nature of band edge absorption and emission in colloidal pbse/cdse core/shell quantum dots

    NARCIS (Netherlands)

    De Geyter, B.; Justo, J.; Moreels, I.; Lambert, K.; Smet, P.F.; Van Thourhout, D.; Houtepen, A.J.; Grodzinska, D.|info:eu-repo/dai/nl/315030186; de Mello Donegá, C.|info:eu-repo/dai/nl/125593899; Meijerink, A.|info:eu-repo/dai/nl/075044986; Vanmaekelbergh, D.A.M.|info:eu-repo/dai/nl/304829137; Hens, Z.

    2011-01-01

    We present a quantitative analysis of the absorption and luminescence of colloidal PbSe/CdSe core/shell quantum dots (QDs). In absorption, both the energy and the oscillator strength of the first exciton transition coincide with that of plain PbSe QDs. In contrast, luminescence lifetime measurements

  8. Study of the L{sub 2,3} edges of 3d transition metals by X-ray absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Akguel, G. [Physics Department, University of Cukurova, 01330 Adana (Turkey); Aksoy, F. [Physics Department, University of Cukurova, 01330 Adana (Turkey); Physics Department, University of Nigde, 51100 Nigde (Turkey); Bozduman, A.; Ozkendir, O.M. [Physics Department, University of Cukurova, 01330 Adana (Turkey); Ufuktepe, Y. [Physics Department, University of Cukurova, 01330 Adana (Turkey)], E-mail: ufuk@cu.edu.tr; Luening, J. [Universite Pierre and Marie Curie, Laboratoire de Chimie Physique-Matiere et Rayonnement 75231 Paris (France)

    2008-11-28

    In the soft X-rays energy region, near edge X-ray absorption fine structure (NEXAFS) spectra are generally recorded by monitoring yield signals of secondary particles. These secondary particles, electrons or fluorescence photons, follow from the decay of the core hole excited in the primary absorption process. In general the yield signals are, to a good approximation, proportional to the absorption coefficient. However, in several applications it would be desirable to measure the absorption coefficient quantitatively. To derive the absorption coefficient quantitatively from a yield spectrum, one needs to know the escape depth of the emitted electrons ({lambda}{sub e}) of the applied yield technique in the material of interest. Since this quantity is difficult to calculate, it is unknown for most materials. In this paper we present the first results of our systematic investigation of the total electron-yield (TEY) escape depth of the 3d transition metals (Fe, Co and Cu). In addition our results gave important information on the variation of the TEY escape depth with the filling of the 3d band.

  9. Self-Supported Copper Oxide Electrocatalyst for Water Oxidation at Low Overpotential and Confirmation of Its Robustness by Cu K-edge X-ray Absorption Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xiang; Cui, Shengsheng; Sun, Zijun; Ren, Yang; Zhang, Xiaoyi; Du, Pingwu

    2016-01-21

    Developing efficient water oxidation catalysts made of earth-abundant elements is a demanding challenge that should be met to fulfill the promise of water splitting for clean energy. Herein we report an annealing approach to synthesize binder-free, self-supported heterogeneous copper oxide (CuO) on conductive electrodes for oxygen evolution reaction (OER), producing electrodes with excellent electrocatalytic properties such as high efficiency, low overpotential, and good stability. The catalysts were grown in situ on fluorine-doped tin oxide (FTO) by electrodeposition from a simple Cu(II) salt solution, followed by annealing at a high temperature. Under optimal conditions, the CuO-based OER catalyst shows an onset potential of <0.58 V (vs Ag/AgCl) in 1.0 M KOH at pH 13.6. From the Tafel plot, the required overpotentials for current densities of 0.1 and 1.0 mA/cm2 are only 360 and 430 mV, respectively. The structure and the presence of a CuO motif in the catalyst have been identified by high-energy X-ray diffraction (HE-XRD), Cu K-edge X-ray absorption (XAS) spectra including X-ray absorption near-edge structure (XANES), and extended X-ray absorption fine structure (EXAFS). To the best of our knowledge, this represents the best catalytic activity for CuO-based OER catalysts to date.

  10. Investigation of the discoloration of smalt pigment in historic paintings by micro-X-ray absorption spectroscopy at the Co K-edge.

    Science.gov (United States)

    Robinet, Laurianne; Spring, Marika; Pagès-Camagna, Sandrine; Vantelon, Delphine; Trcera, Nicolas

    2011-07-01

    Smalt was commonly used as a pigment by artists between the 16th and 18th centuries. It is a powdered blue potash glass colored by cobalt ions and often degrades causing dramatic changes in the appearance of paintings. The aim of the work presented in this paper was to investigate the changes in the structure and environment around the cobalt ion on deterioration, to further our understanding of the basis of the loss of color. Particles of well-preserved and altered smalt in microsamples from paintings in the National Gallery, London, and the Louvre, Paris, were analyzed using synchrotron micro-X-ray absorption spectroscopy at the Co K-edge. X-ray absorption near-edge spectroscopy (XANES) and extended X-ray absorption fine structure (EXAFS) measurements showed that in intense blue particles the cobalt is predominantly present as Co(2+) in tetrahedral coordination, whereas in colorless altered smalt the Co(2+) coordination number in the glass structure is increased and there is a shift from tetrahedral toward octahedral coordination. The extent of this shift correlates clearly with the alkali content, indicating that it is caused by leaching of potassium cations, which act as charge compensators and stabilize the tetrahedral coordination of the cobalt ions that is responsible for the blue color.

  11. Surface structure of alpha-Fe sub 2 O sub 3 nanocrystal observed by O K-edge X-ray absorption spectroscopy

    CERN Document Server

    Zhang, J; Ibrahim, K; Abbas, M I; Ju, X

    2003-01-01

    X-ray absorption near edge structure (XANES) spectra is used as a probe of surface structure of alpha-Fe sub 2 O sub 3 nanocrystal, prepared by sol-gel method. We present O K-edge XANES of alpha-Fe sub 2 O sub 3 in nanocrystal and bulk by total electron yield at the photoemission station of Beijing Synchrotron Radiation Facility. The spectrum of alpha-Fe sub 2 O sub 3 shows a splitting of the pre-edge structure, which is interpreted as two subsets of Fe 3d t sub 2 sub g and e sub g orbitals in oxygen octahedral (O sub h) crystal field, and is also sensitive to long-range order effects. However, no distinguishable splitting of the pre-edge peak of nanocrystal alpha-Fe sub 2 O sub 3 is observed. This suggests that there exists the distorted octahedral coordination around Fe sites and also the long-range disorder due to the surface as compared with bulk alpha-Fe sub 2 O sub 3.

  12. Percolative superconductivity in La{sub 2}CuO{sub 4.06} by lattice granularity patterns with scanning micro x-ray absorption near edge structure

    Energy Technology Data Exchange (ETDEWEB)

    Poccia, Nicola [MESA Institute for Nanotechnology, University of Twente, P. O. Box 217, 7500AE Enschede (Netherlands); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Chorro, Matthieu [Synchrotron SOLEIL L' Orme des Merisiers, 91190 Paris S.Aubin (France); Ricci, Alessandro [Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, D-22607 Hamburg (Germany); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Xu, Wei [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Marcelli, Augusto [Istituto Nazionale di Fisica Nucleare - Laboratori Nazionali di Frascati, 00044 Frascati, Rome (Italy); NSRL, University of Science and Technology of China, Hefei 230026 (China); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Campi, Gaetano [Institute of Crystallography, CNR, via Salaria Km 29.300, Monterotondo, 00015 Rome (Italy); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Bianconi, Antonio [RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Institute of Crystallography, CNR, via Salaria Km 29.300, Monterotondo, 00015 Rome (Italy)

    2014-06-02

    The simplest cuprate superconductor La{sub 2}CuO{sub 4+y} with mobile oxygen interstitials exhibits a clear phase separation. It is known that oxygen interstitials enter into the rocksalt La{sub 2}O{sub 2+y} spacer layers forming oxygen interstitials rich puddles and poor puddles but only recently a bulk multiscale structural phase separation has been observed by using scanning micro X-ray diffraction. Here we get further information on their spatial distribution, using scanning La L{sub 3}-edge micro X-ray absorption near edge structure. Percolating networks of oxygen rich puddles are observed in different micrometer size portions of the crystals. Moreover, the complex surface resistivity shows two jumps associated to the onset of intra-puddle and inter-puddles percolative superconductivity. The similarity of oxygen doped La{sub 2}CuO{sub 4+y}, with the well established phase separation in iron selenide superconductors is also discussed.

  13. X-ray absorption near edge structure study on Acutolysin-C, a zinc-metalloproteinase from Agkistrodon acutus venom: Insight into the acid-inactive mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Zhao Wei [Hefei National Laboratory for Physical Sciences at Microscale and School of Life Sciences, University of Science and Technology of China, Hefei, Anhui 230027 (China); Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Chu Wangsheng; Li Shujun [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Liu Yiwei [Hefei National Laboratory for Physical Sciences at Microscale and School of Life Sciences, University of Science and Technology of China, Hefei, Anhui 230027 (China); Gao Bin [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Niu Liwen [Hefei National Laboratory for Physical Sciences at Microscale and School of Life Sciences, University of Science and Technology of China, Hefei, Anhui 230027 (China)], E-mail: lwniu@ustc.edu.cn; Teng Maikun [Hefei National Laboratory for Physical Sciences at Microscale and School of Life Sciences, University of Science and Technology of China, Hefei, Anhui 230027 (China); Benfatto, Maurizio [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali di Frascati, P.O. Box 13, 00044 Frascati (Italy); Hu Tiandou [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Wu Ziyu [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali di Frascati, P.O. Box 13, 00044 Frascati (Italy)], E-mail: wuzy@ihep.ac.cn

    2007-11-15

    Acutolysin-C, a snake-venom zinc metalloproteinase, displays a distinct pH-dependent proteolytic activity, which has been tentatively assigned to a structural change of the zinc-containing catalytic center. In this work we compare X-ray absorption near-edge structure (XANES) experimental spectra at the Zn K-edge and theoretical calculations of solutions at different pH values. The experimental data show clear differences confirmed by a best fit using the MXAN procedure. The results show that, when pH decreases from pH 8.0 to pH 3.0, the zinc-coordinating catalytic water molecule moves far from the Glu143 residue that is considered to play an essential role in the proteolytic process. Data suggests that this is the possible mechanism that deactivates the metalloproteinase.

  14. X-ray absorption near edge structure study on Acutolysin-C, a zinc-metalloproteinase from Agkistrodon acutus venom: Insight into the acid-inactive mechanism

    Science.gov (United States)

    Zhao, Wei; Chu, Wangsheng; Li, Shujun; Liu, Yiwei; Gao, Bin; Niu, Liwen; Teng, Maikun; Benfatto, Maurizio; Hu, Tiandou; Wu, Ziyu

    2007-11-01

    Acutolysin-C, a snake-venom zinc metalloproteinase, displays a distinct pH-dependent proteolytic activity, which has been tentatively assigned to a structural change of the zinc-containing catalytic center. In this work we compare X-ray absorption near-edge structure (XANES) experimental spectra at the Zn K-edge and theoretical calculations of solutions at different pH values. The experimental data show clear differences confirmed by a best fit using the MXAN procedure. The results show that, when pH decreases from pH 8.0 to pH 3.0, the zinc-coordinating catalytic water molecule moves far from the Glu143 residue that is considered to play an essential role in the proteolytic process. Data suggests that this is the possible mechanism that deactivates the metalloproteinase.

  15. A Minor Modification of Leading Edge Discriminator Circuitry with a Delay Line for Baseline Restoration of Scintillation Detectors

    Energy Technology Data Exchange (ETDEWEB)

    Izumi, N

    2003-05-27

    Multi-channel neutron time-of-flight detector arrays LaNSA, T-ion, Medusa, and Mandala, have been used for neutron spectroscopy in inertial confinement fusion experiments. These multi-channel neutron detector arrays consist of many identical scintillation detectors (842 {approx} 1024 channel), data acquisition electronics (discriminators, time-to digital converters, and controller). Each detector element is operated in neutron counting mode. Time-of-flight of individual detected neutrons are recorded by time to digital converters. The energy of each detected neutrons is determined from its time-of-flight. The accurate time measurement ({Delta}t {approx} 0.5 ns) and straightforward statistical features of the data obtained with these systems provides good integrity and reliability. The elements detector used in these systems are organic scintillators coupled with photo multiplier tubes. A scintillation detector operated in particle-counting mode requires finite recovery time after each detection event. The recovery time is determined by the time responses of scintillators, photo multiplier tubes, and the dead times of following discriminators and time-to digital converters. The harsh gamma ray background environment of fast ignitor experiments requires detectors that have fast recovery times. In high intensity laser experiments (I > 10{sup 19} W/cm{sup 2}), strong gamma ray bursts are produced by relativistic laser plasma interactions. Prior to the neutron signal, these strong gamma ray bursts hit the detectors and interfere with the detection of following neutron signals. In these situations, the recovery time of the system after preceding gamma ray bursts is determined mainly by the base line shift of the PMT signal (due to slower decay components of scintillators ''after glow''). Discriminators cannot detect following signal pulses until the proceeding burst decays below its threshold voltage. The base line shift caused by the after glow

  16. Micro-X-ray absorption near edge structure spectroscopy investigations of baroque tin-amalgam mirrors at BESSY using a capillary focusing system

    Energy Technology Data Exchange (ETDEWEB)

    Bartoll, J. [Stiftung Preussische Schloesser und Gaerten, Postfach 601462, 14414 Potsdam (Germany); Roehrs, S. [Technische Universitaet Berlin, Institut fuer Chemie, Strasse des 17. Juni 135, 10623 Berlin (Germany); Erko, A. [Berliner Elektronenspeicherring-Gesellschaft fuer Synchrotronstrahlung (BESSY) mbH, Albert-Einstein Str. 15, 12489 Berlin (Germany)]. E-mail: erko@bessy.de; Firsov, A. [Berliner Elektronenspeicherring-Gesellschaft fuer Synchrotronstrahlung (BESSY) mbH, Albert-Einstein Str. 15, 12489 Berlin (Germany); Bjeoumikhov, A. [IfG-Institut fuer Geraetebau GmbH Rudower Chaussee, 29-31, 12489 Berlin (Germany); Langhoff, N. [IfG-Institut fuer Geraetebau GmbH Rudower Chaussee, 29-31, 12489 Berlin (Germany)

    2004-10-08

    An elliptically shaped glass monocapillary with a spatial resolution of 5 {mu}m has been used for the fine focusing of the pre-focused X-ray beam produced by the graded-crystal monochromator beamline, KMC-2. The flux density gain of 50 was experimentally measured. The microprobe has been used in the energy range of 3.5-15 keV. Micro-X-ray fluorescence analysis ({mu}XFA) and micro-X-ray absorption near edge structure spectroscopy ({mu}XANES) measurements on test samples and investigations of baroque tin-amalgam mirrors were done.

  17. Micro-X-ray absorption near edge structure spectroscopy investigations of baroque tin-amalgam mirrors at BESSY using a capillary focusing system

    Science.gov (United States)

    Bartoll, J.; Röhrs, S.; Erko, A.; Firsov, A.; Bjeoumikhov, A.; Langhoff, N.

    2004-10-01

    An elliptically shaped glass monocapillary with a spatial resolution of 5 μm has been used for the fine focusing of the pre-focused X-ray beam produced by the graded-crystal monochromator beamline, KMC-2. The flux density gain of 50 was experimentally measured. The microprobe has been used in the energy range of 3.5-15 keV. Micro-X-ray fluorescence analysis (μXFA) and micro-X-ray absorption near edge structure spectroscopy (μXANES) measurements on test samples and investigations of baroque tin-amalgam mirrors were done.

  18. X-ray absorption near edge structure studies of Pb{sub 1-x}Mn{sub x}Te(In, Ga) systems

    Energy Technology Data Exchange (ETDEWEB)

    Radisavljevic, Ivana; Novakovic, Nikola; Medic, Mirjana; Paskas-Mamula, Bojana; Ivanovic, Nenad [Belgrade Univ. (Serbia). Vinca Institute of Nuclear Science; Mahnke, Heinz-Eberhard [Helmholtz-Zentrum Berlin fuer Materialien und Energie GmbH, Berlin (Germany); Romcevic, Nebojsa [Belgrade Univ. (Serbia). Inst. of Physics

    2013-03-15

    The X-ray absorption near edge structure technique was employed for studies of coordination environments and valence states of impurity atoms (Mn, In and Ga) in a series of narrow band gap PbTe-based semiconductors. Impurity atoms' absorption data were analysed with the help of the Real Space Full Multiple Scattering FEFF8.2 code. These results are complemented with band structure calculations using the full potential augmented plane waves method extended by local orbitals using WIEN2k code. Impurity atoms are found to be off-centred from the regular lattice positions each in a specific manner, which leads to formation of significantly different local structures from that expected in host PbTe. Observed structural modifications are accompanied by the change in the impurity atoms' valence states. These findings support and extend our previous results obtained with various techniques on this class of materials. (orig.)

  19. Biogeochemical reductive release of soil embedded arsenate around a crater area (Guandu) in northern Taiwan using X-ray absorption near-edge spectroscopy

    Institute of Scientific and Technical Information of China (English)

    Kai-Ying Chiang; Tsan-Yao Chen; Chih-Hao Lee; Tsang-Lang Lin; Ming-Kuang Wang; Ling-Yun Jang; Jyh-Fu Lee

    2013-01-01

    This study investigates biogeochemical reductive release of arsenate from beudantite into solution in a crater area in northern Taiwan,using a combination of X-ray absorption near-edge structure (XANES) and atomic absorption spectrometry.Total arsenic (As)concentrations in the soil were more than 200 mg/kg.Over four months of laboratory experiments,less than 0.8% As was released into solution after reduction experiments.The 71% to 83% As was chemically reduced into arsenite (As(Ⅲ)) and partially weathering into the soluble phase.The kinetic dissolution and re-precipitation of As,Fe,Pb and sulfate in this area of paddy soils merits further study.

  20. Ti K-edge X-ray absorption spectra of spray pyrolysis synthesized TiO2-x and TiO2-x Nx thin films

    Science.gov (United States)

    Sahoo, Madhusmita; Yadav, Ashok Kumar; Jha, S. N.; Bhattacharyya, Dibyendu; Mathews, Tom; Dash, S.

    2017-05-01

    Oxygen deficient TiO2 and N-TiO2 anatase thin films were synthesized by employing a two step process. First TiO2 and N-TiO2 films were synthesized by using a cost effective spray pyrolysis method. Subsequently, these films were reduced under H2 to create oxygen vacancies. Formation of oxygen vacancies was confirmed by using synchrotron source X-ray Absorption Spectroscopy (XAS). Effect of oxygen vacancies on electronic and structural properties were deduced from the near edge and extended region analysis of the X-ray absorption spectra. It is inferred that reduction time plays a crucial role in creating oxygen vacancies and number of oxygen vacancies increases with increase in reduction time. Substrate effect was delineated by using Si and FTO (Fluorine doped tin oxide coated glass) as substrates for film deposition.

  1. In Situ X-ray Absorption Near-Edge Structure Spectroscopy of ZnO Nanowire Growth During Chemical Bath Deposition

    Energy Technology Data Exchange (ETDEWEB)

    McPeak, Kevin M.; Becker, Matthew A.; Britton, Nathan G.; Majidi, Hasti; Bunker, Bruce A.; Baxter, Jason B. (Drexel); (Notre)

    2010-12-03

    Chemical bath deposition (CBD) offers a simple and inexpensive route to deposit semiconductor nanostructures, but lack of fundamental understanding and control of the underlying chemistry has limited its versatility. Here we report the first use of in situ X-ray absorption spectroscopy during CBD, enabling detailed investigation of both reaction mechanisms and kinetics of ZnO nanowire growth from zinc nitrate and hexamethylenetetramine (HMTA) precursors. Time-resolved X-ray absorption near-edge structure (XANES) spectra were used to quantify Zn(II) speciation in both solution and solid phases. ZnO crystallizes directly from [Zn(H{sub 2}O){sub 6}]{sup 2+} without long-lived intermediates. Using ZnO nanowire deposition as an example, this study establishes in situ XANES spectroscopy as an excellent quantitative tool to understand CBD of nanomaterials.

  2. 3D knife-edge characterization of two-photon absorption volume in silicon for integrated circuit testing.

    Science.gov (United States)

    Shao, K; Morisset, A; Pouget, V; Faraud, E; Larue, C; Lewis, D; McMorrow, D

    2011-11-01

    We have performed three-dimensional characterization of the TPA effective laser spot size in silicon using an integrated knife-edge sensor. The TPA-induced response of a CMOS integrated circuit is analyzed based on these results and compared to simulation; we have found that the charge injection capacity in IC's active layer could be influenced by irradiance energy and focus depth.

  3. The response functions of the HEPC/LEPC detector system measured at the Xe L edge region

    DEFF Research Database (Denmark)

    Budtz-Jørgensen, Carl; Olesen, C.; Schnopper, H.W.

    1995-01-01

    The Danish Space Research Institute will provide a set of two low energy proportional counters (LEPC) and two high energy proportional counters (HEPC) for the Russian SPECTRUM-X-Gamma mission. The detectors are based upon the technology of the microstrip gas chamber (MSGC). HEPC and LEPC use a Xe....../CH4 mixture as the counter gas. The response function as well as the pulse height-energy relation for a Xe/CH4 filled MSGC were investigated with monochromatized synchrotron radiation of the BESSY double crystal monochromator. The detector response functions were recorded at similar to 100 selected...

  4. Pushing the limits of CMOS optical parametric amplifiers with USRN:Si7N3 above the two-photon absorption edge

    Science.gov (United States)

    Ooi, K. J. A.; Ng, D. K. T.; Wang, T.; Chee, A. K. L.; Ng, S. K.; Wang, Q.; Ang, L. K.; Agarwal, A. M.; Kimerling, L. C.; Tan, D. T. H.

    2017-01-01

    CMOS platforms operating at the telecommunications wavelength either reside within the highly dissipative two-photon regime in silicon-based optical devices, or possess small nonlinearities. Bandgap engineering of non-stoichiometric silicon nitride using state-of-the-art fabrication techniques has led to our development of USRN (ultra-silicon-rich nitride) in the form of Si7N3, that possesses a high Kerr nonlinearity (2.8 × 10−13 cm2 W−1), an order of magnitude larger than that in stoichiometric silicon nitride. Here we experimentally demonstrate high-gain optical parametric amplification using USRN, which is compositionally tailored such that the 1,550 nm wavelength resides above the two-photon absorption edge, while still possessing large nonlinearities. Optical parametric gain of 42.5 dB, as well as cascaded four-wave mixing with gain down to the third idler is observed and attributed to the high photon efficiency achieved through operating above the two-photon absorption edge, representing one of the largest optical parametric gains to date on a CMOS platform. PMID:28051064

  5. Theoretical X-ray production cross sections at incident photon energies across L{sub i} (i=1-3) absorption edges of Br

    Energy Technology Data Exchange (ETDEWEB)

    Puri, Sanjiv [Department of Basic & Applied Sciences, Punjabi University, Patiala-147002, Punjab, India. E-mail address: sanjivpurichd@yahoo.com (India)

    2015-08-28

    The X-ray production (XRP) cross sections, σ{sub Lk} (k = l, η, α, β{sub 6}, β{sub 1}, β{sub 3}, β{sub 4}, β{sub 9,10}, γ{sub 1,5}, γ{sub 2,3}) have been evaluated at incident photon energies across the L{sub i}(i=1-3) absorption edge energies of {sub 35}Br using theoretical data sets of different physical parameters, namely, the L{sub i}(i=1-3) sub-shell the X-ray emission rates based on the Dirac-Fock (DF) model, the fluorescence and Coster Kronig yields based on the Dirac-Hartree-Slater (DHS) model, and two sets of the photoionisation cross sections based on the relativistic Hartree-Fock-Slater (RHFS) model and the Dirac-Fock (DF) model, in order to highlight the importance of electron exchange effects at photon energies in vicinity of absorption edge energies.

  6. X-ray structure analysis of a metalloprotein with enhanced active-site resolution using in situ x-ray absorption near edge structure spectroscopy.

    Science.gov (United States)

    Arcovito, Alessandro; Benfatto, Maurizio; Cianci, Michele; Hasnain, S Samar; Nienhaus, Karin; Nienhaus, G Ulrich; Savino, Carmelinda; Strange, Richard W; Vallone, Beatrice; Della Longa, Stefano

    2007-04-10

    X-ray absorption spectroscopy is exquisitely sensitive to the coordination geometry of an absorbing atom and therefore allows bond distances and angles of the surrounding atomic cluster to be measured with atomic resolution. By contrast, the accuracy and resolution of metalloprotein active sites obtainable from x-ray crystallography are often insufficient to analyze the electronic properties of the metals that are essential for their biological functions. Here, we demonstrate that the combination of both methods on the same metalloprotein single crystal yields a structural model of the protein with exceptional active-site resolution. To this end, we have collected an x-ray diffraction data set to 1.4-A resolution and Fe K-edge polarized x-ray absorption near edge structure (XANES) spectra on the same cyanomet sperm whale myoglobin crystal. The XANES spectra were quantitatively analyzed by using a method based on the multiple scattering approach, which yielded Fe-heme structural parameters with +/-(0.02-0.07)-A accuracy on the atomic distances and +/-7 degrees on the Fe-CN angle. These XANES-derived parameters were subsequently used as restraints in the crystal structure refinement. By combining XANES and x-ray diffraction, we have obtained an cyanomet sperm whale myoglobin structural model with a higher precision of the bond lengths and angles at the active site than would have been possible with crystallographic analysis alone.

  7. L-Edge X-ray Absorption Spectroscopy of Dilute Systems Relevant to Metalloproteins Using an X-ray Free-Electron Laser

    Science.gov (United States)

    Mitzner, Rolf; Rehanek, Jens; Kern, Jan; Gul, Sheraz; Hattne, Johan; Taguchi, Taketo; Alonso-Mori, Roberto; Tran, Rosalie; Weniger, Christian; Schröder, Henning; Quevedo, Wilson; Laksmono, Hartawan; Sierra, Raymond G.; Han, Guangye; Lassalle-Kaiser, Benedikt; Koroidov, Sergey; Kubicek, Katharina; Schreck, Simon; Kunnus, Kristjan; Brzhezinskaya, Maria; Firsov, Alexander; Minitti, Michael P.; Turner, Joshua J.; Moeller, Stefan; Sauter, Nicholas K.; Bogan, Michael J.; Nordlund, Dennis; Schlotter, William F.; Messinger, Johannes; Borovik, Andrew; Techert, Simone; de Groot, Frank M. F.; Föhlisch, Alexander; Erko, Alexei; Bergmann, Uwe; Yachandra, Vittal K.; Wernet, Philippe; Yano, Junko

    2013-01-01

    L-edge spectroscopy of 3d transition metals provides important electronic structure information and has been used in many fields. However, the use of this method for studying dilute aqueous systems, such as metalloenzymes, has not been prevalent because of severe radiation damage and the lack of suitable detection systems. Here we present spectra from a dilute Mn aqueous solution using a high-transmission zone-plate spectrometer at the Linac Coherent Light Source (LCLS). The spectrometer has been optimized for discriminating the Mn L-edge signal from the overwhelming O K-edge background that arises from water and protein itself, and the ultrashort LCLS X-ray pulses can outrun X-ray induced damage. We show that the deviations of the partial-fluorescence yield-detected spectra from the true absorption can be well modeled using the state-dependence of the fluorescence yield, and discuss implications for the application of our concept to biological samples. PMID:24466387

  8. Coupled-cluster response theory for near-edge x-ray-absorption fine structure of atoms and molecules

    DEFF Research Database (Denmark)

    Coriani, Sonia; Christiansen, Ove; Fransson, Thomas

    2012-01-01

    triple corrected excitation energies CCSDR(3). This work is a first step toward the extension of these theoretical electronic structure methods of well-established high accuracy in UV-vis absorption spectroscopies to applications concerned with x-ray radiation. From the imaginary part of the linear...

  9. Ge L{sub 3}-edge x-ray absorption near-edge structure study of structural changes accompanying conductivity drift in the amorphous phase of Ge{sub 2}Sb{sub 2}Te{sub 5}

    Energy Technology Data Exchange (ETDEWEB)

    Mitrofanov, K. V. [Nanoelectronics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8562 (Japan); Kolobov, A. V., E-mail: a.kolobov@aist.go.jp; Fons, P. [Nanoelectronics Research Institute and Green Nanoelectronics Center, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8562, Japan and Synchrotron Radiation Research Institute (JASRI), SPring-8, 1-1-1, Kouto, Sayo, Hyogo 679-5198 (Japan); Wang, X.; Tominaga, J. [Nanoelectronics Research Institute and Green Nanoelectronics Center, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8562 (Japan); Tamenori, Y.; Uruga, T. [Synchrotron Radiation Research Institute (JASRI), SPring-8, 1-1-1, Kouto, Sayo, Hyogo 679-5198 (Japan); Ciocchini, N.; Ielmini, D. [DEIB - Politecnico di Milano, Piazza L. Da Vinci 32, 20133 Milano (Italy)

    2014-05-07

    A gradual uncontrollable increase in the resistivity of the amorphous phase of phase-change alloys, such as Ge{sub 2}Sb{sub 2}Te{sub 5}, known as drift, is a serious technological issue for application of phase-change memory. While it has been proposed that drift is related to structural relaxation, no direct structural results have been reported so far. Here, we report the results of Ge L{sub 3}-edge x-ray absorption measurements that suggest that the drift in electrical conductivity is associated with the gradual conversion of tetrahedrally coordinated Ge sites into pyramidal sites, while the system still remains in the amorphous phase. Based on electronic configuration arguments, we propose that during this process, which is governed by the existence of lone-pair electrons, the concentration of free carriers in the system decreases resulting in an increase in resistance despite the structural relaxation towards the crystalline phase.

  10. The dust-scattering component of X-ray extinction: effects on continuum fitting and high-resolution absorption edge structure

    Science.gov (United States)

    Corrales, L. R.; García, J.; Wilms, J.; Baganoff, F.

    2016-05-01

    Small angle scattering by dust grains causes a significant contribution to the total interstellar extinction for any X-ray instrument with sub-arcminute resolution (Chandra, Swift, XMM-Newton). However, the dust-scattering component is not included in the current absorption models: phabs, TBabs, and TBnew. We simulate a large number of Chandra spectra to explore the bias in the spectral fit and NH measurements obtained without including extinction from dust scattering. We find that without incorporating dust scattering, the measured NH will be too large by a baseline level of 25 per cent. This effect is modulated by the imaging resolution of the telescope, because some amount of unresolved scattered light will be captured within the aperture used to extract point source information. In high-resolution spectroscopy, dust scattering significantly enhances the total extinction optical depth and the shape of the photoelectric absorption edges. We focus in particular on the Fe-L edge at 0.7 keV, showing that the total extinction template fits well to the high-resolution spectrum of three X-ray binaries from the Chandra archive: GX 9+9, XTE J1817-330, and Cyg X-1. In cases where dust is intrinsic to the source, a covering factor based on the angular extent of the dusty material must be applied to the extinction curve, regardless of angular imaging resolution. This approach will be particularly relevant for dust in quasar absorption line systems and might constrain clump sizes in active galactic nuclei.

  11. Proof of principle of a high-spatial-resolution, resonant-response gamma-ray detector for Gamma Resonance Absorption in 14N

    CERN Document Server

    Brandis, M; Vartsky, D; Friedman, E; Kreslo, I; Mardor, I; Dangendorf, V; Levi, S; Mor, I; Bar, D

    2011-01-01

    The development of a mm-spatial-resolution, resonant-response detector based on a micrometric glass capillary array filled with liquid scintillator is described. This detector was developed for Gamma Resonance Absorption (GRA) in 14N. GRA is an automatic-decision radiographic screening technique that combines high radiation penetration (the probe is a 9.17 MeV gamma ray) with very good sensitivity and specificity to nitrogenous explosives. Detailed simulation of the detector response to electrons and protons generated by the 9.17 MeV gamma-rays was followed by a proof-of-principle experiment, using a mixed gamma-ray and neutron source. Towards this, a prototype capillary detector was assembled, including the associated filling and readout systems. Simulations and experimental results indeed show that proton tracks are distinguishable from electron tracks at relevant energies, on the basis of a criterion that combines track length and light intensity per unit length.

  12. Proof of principle of a high-spatial-resolution, resonant-response γ-ray detector for Gamma Resonance Absorption in 14N

    Science.gov (United States)

    Brandis, M.; Goldberg, M. B.; Vartsky, D.; Friedman, E.; Kreslo, I.; Mardor, I.; Dangendorf, V.; Levi, S.; Mor, I.; Bar, D.

    2011-02-01

    The development of a mm-spatial-resolution, resonant-response detector based on a micrometric glass capillary array filled with liquid scintillator is described. This detector was developed for Gamma Resonance Absorption (GRA) in 14N. GRA is an automatic-decision radiographic screening technique that combines high radiation penetration (the probe is a 9.17 MeV γ-ray) with very good sensitivity and specificity to nitrogenous explosives. Detailed simulation of the detector response to electrons and protons generated by the 9.17 MeV γ-rays was followed by a proof-of-principle experiment, using a mixed γ-ray and neutron source. Towards this, a prototype capillary detector was assembled, including the associated filling and readout systems. Simulations and experimental results indeed show that proton tracks are distinguishable from electron tracks at relevant energies, based on a criterion that combines track length and light intensity per unit length.

  13. Optimization of K-edge imaging for vulnerable plaques using gold nanoparticles and energy resolved photon counting detectors: a simulation study.

    Science.gov (United States)

    Alivov, Yahya; Baturin, Pavlo; Le, Huy Q; Ducote, Justin; Molloi, Sabee

    2014-01-06

    We investigated the effect of different imaging parameters, such as dose, beam energy, energy resolution and the number of energy bins, on the image quality of K-edge spectral computed tomography (CT) of gold nanoparticles (GNP) accumulated in an atherosclerotic plaque. A maximum likelihood technique was employed to estimate the concentration of GNP, which served as a targeted intravenous contrast material intended to detect the degree of the plaque's inflammation. The simulation studies used a single-slice parallel beam CT geometry with an x-ray beam energy ranging between 50 and 140 kVp. The synthetic phantoms included small (3 cm in diameter) cylinder and chest (33 × 24 cm(2)) phantoms, where both phantoms contained tissue, calcium and gold. In the simulation studies, GNP quantification and background (calcium and tissue) suppression tasks were pursued. The x-ray detection sensor was represented by an energy resolved photon counting detector (e.g., CdZnTe) with adjustable energy bins. Both ideal and more realistic (12% full width at half maximum (FWHM) energy resolution) implementations of the photon counting detector were simulated. The simulations were performed for the CdZnTe detector with a pixel pitch of 0.5-1 mm, which corresponds to a performance without significant charge sharing and cross-talk effects. The Rose model was employed to estimate the minimum detectable concentration of GNPs. A figure of merit (FOM) was used to optimize the x-ray beam energy (kVp) to achieve the highest signal-to-noise ratio with respect to the patient dose. As a result, the successful identification of gold and background suppression was demonstrated. The highest FOM was observed at the 125 kVp x-ray beam energy. The minimum detectable GNP concentration was determined to be approximately 1.06 µmol mL(-1) (0.21 mg mL(-1)) for an ideal detector and about 2.5 µmol mL(-1) (0.49 mg mL(-1)) for a more realistic (12% FWHM) detector. The studies show the optimal

  14. Characterization of atmospheric aerosols using Synchroton radiation total reflection X-ray fluorescence and Fe K-edge total reflection X-ray fluorescence-X-ray absorption near-edge structure

    Energy Technology Data Exchange (ETDEWEB)

    Fittschen, U.E.A. [Department of Chemistry, University of Hamburg, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany)], E-mail: ursula.fittschen@chemie.uni-hamburg.de; Meirer, F. [Atominstitut, Vienna University of Technology, Stadionallee 2, 1020 Wien (Austria)], E-mail: fmeirer@ati.ac.at; Streli, C. [Atominstitut, Vienna University of Technology, Stadionallee 2, 1020 Wien (Austria)], E-mail: streli@ati.ac.at; Wobrauschek, P. [Atominstitut, Vienna University of Technology, Stadionallee 2, 1020 Wien (Austria)], E-mail: wobi@ati.ac.at; Thiele, J. [Department of Chemistry, University of Hamburg, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany)], E-mail: Julian.Thiele@gmx.de; Falkenberg, G. [Hamburger Synchrotronstrahlungslabor at Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22603 Hamburg (Germany)], E-mail: falkenbe@mail.desy.de; Pepponi, G. [ITC-irst, Via Sommarive 18, 38050 Povo (Trento) (Italy)], E-mail: pepponi@itc.it

    2008-12-15

    In this study a new procedure using Synchrotron total reflection X-ray fluorescence (SR-TXRF) to characterize elemental amounts in atmospheric aerosols down to particle sizes of 0.015 um is presented. The procedure was thoroughly evaluated regarding bounce off effects and blank values. Additionally the potential of total reflection X-ray fluorescence-X-ray absorption near edge structure (SR-TXRF-XANES) for speciation of FeII/III down to amounts of 34 pg in aerosols which were collected for 1 h is shown. The aerosols were collected in the city of Hamburg with a low pressure Berner impactor on Si carriers covered with silicone over time periods of 60 and 20 min each. The particles were collected in four and ten size fractions of 10.0-8.0 {mu}m, 8.0-2.0 {mu}m, 2.0-0.13 {mu}m 0.13-0.015 {mu}m (aerodynamic particle size) and 15-30 nm, 30-60 nm, 60-130 nm, 130-250 nm, 250-500 nm, 0.5-1 {mu}m, 1-2 {mu}m, 2-4 {mu}m, 4-8 {mu}m, 8-16 {mu}m. Prior to the sampling 'bounce off' effects on Silicone and Vaseline coated Si carriers were studied with total reflection X-ray fluorescence. According to the results silicone coated carriers were chosen for the analysis. Additionally, blank levels originating from the sampling device and the calibration procedure were studied. Blank levels of Fe corresponded to 1-10% of Fe in the aerosol samples. Blank levels stemming from the internal standard were found to be negligible. The results from the Synchroton radiation total reflection X-ray fluorescence analysis of the aerosols showed that 20 min of sampling time gave still enough sample material for elemental determination of most elements. For the determination of the oxidation state of Fe in the aerosols different Fe salts were prepared as a reference from suspensions in isopropanol. The results from the Fe K-edge Synchroton radiation total reflection X-ray fluorescence-X-ray absorption near-edge structure analysis of the aerosol samples showed that mainly Fe(III) was present in

  15. On the importance of nuclear quantum motions in near edge x-ray absorption fine structure (NEXAFS) spectroscopy of molecules

    Energy Technology Data Exchange (ETDEWEB)

    Schwartz, Craig P.; Uejio, Janel S.; Saykally, Richard J.; Prendergast, David

    2009-02-26

    We report the effects of sampling nuclear quantum motion with path integral molecular dynamics (PIMD) on calculations of the nitrogen K-edge spectra of two isolated organic molecules. S-triazine, a prototypical aromatic molecule occupying primarily its vibrational ground state at room temperature, exhibits substantially improved spectral agreement when nuclear quantum effects are included via PIMD, as compared to the spectra obtained from either a single fixed-nuclei based calculation or from a series of configurations extracted from a classical molecular dynamics trajectory. Nuclear quantum dynamics can accurately explain the intrinsic broadening of certain features. Glycine, the simplest amino acid, is problematic due to large spectral variations associated with multiple energetically accessible conformations at the experimental temperature. This work highlights the sensitivity of NEXAFS to quantum nuclear motions in molecules, and the necessity of accurately sampling such quantum motion when simulating their NEXAFS spectra.

  16. Determination and analysis of optical constants for Ga{sub 2}Se{sub 3} films near absorption edge

    Energy Technology Data Exchange (ETDEWEB)

    Afifi, M.A.; Bekheet, A.E.; El-Shair, H.T.; Zedan, I.T

    2003-01-01

    Ga{sub 2}Se{sub 3} has been prepared in bulk and thin film forms. The composition of films has been checked using energy dispersive X-ray spectroscopy technique. X-ray diffraction measurements have shown that Ga{sub 2}Se{sub 3} films evaporated at room temperature substrates were amorphous. The transmittance (T) of Ga{sub 2}Se{sub 3} thin films has been measured over the wavelength range (400-900 nm). The optical constants, the refractive index (n) and the absorption index (k) have been determined from the analysis of the transmittance data. Analysis of the refractive index (n) yields the values of the long wavelength dielectric constant ({epsilon}{sub {infinity}}), the average oscillator wavelength ({lambda}{sub o}), average oscillator strength (S{sub o}), average oscillator energy E{sub o}, the refractive index dispersion parameter (E{sub o}/S{sub o}) and the dispersion energy (E{sub d}). Analysis of absorption index (k) yields both direct and indirect allowed transitions with optical energy gaps of 2.65 and 2.056 eV, respectively. The effect of annealing at different temperatures on optical constants is also investigated.

  17. Segmentation of pelvic structures for planning CT using a geometrical shape model tuned by a multi-scale edge detector

    Science.gov (United States)

    Martínez, Fabio; Romero, Eduardo; Dréan, Gaël; Simon, Antoine; Haigron, Pascal; De Crevoisier, Renaud; Acosta, Oscar

    2014-01-01

    Accurate segmentation of the prostate and organs at risk in computed tomography (CT) images is a crucial step for radiotherapy (RT) planning. Manual segmentation, as performed nowadays, is a time consuming process and prone to errors due to the a high intra- and inter-expert variability. This paper introduces a new automatic method for prostate, rectum and bladder segmentation in planning CT using a geometrical shape model under a Bayesian framework. A set of prior organ shapes are first built by applying Principal Component Analysis (PCA) to a population of manually delineated CT images. Then, for a given individual, the most similar shape is obtained by mapping a set of multi-scale edge observations to the space of organs with a customized likelihood function. Finally, the selected shape is locally deformed to adjust the edges of each organ. Experiments were performed with real data from a population of 116 patients treated for prostate cancer. The data set was split in training and test groups, with 30 and 86 patients, respectively. Results show that the method produces competitive segmentations w.r.t standard methods (Averaged Dice = 0.91 for prostate, 0.94 for bladder, 0.89 for Rectum) and outperforms the majority-vote multi-atlas approaches (using rigid registration, free-form deformation (FFD) and the demons algorithm) PMID:24594798

  18. Investigation of Pb species in soils, celery and duckweed by synchrotron radiation X-ray absorption near-edge structure spectrometry

    Science.gov (United States)

    Luo, Liqiang; Shen, Yating; Liu, Jian; Zeng, Yuan

    2016-08-01

    The Pb species play a key role in its translocation in biogeochemical cycles. Soils, sediments and plants were collected from farmlands around Pb mines, and the Pb species in them was identified by X-ray absorption near-edge structure spectrometry. In soils, Pb5(PO4)3Cl and Pb3(PO4)2 were detected, and in sediments, Pb-fulvic acids (FAs) complex was identified. A Pb complex with FA fragments was also detected in celery samples. We found that (1) different Pb species were present in soils and sediments; (2) the Pb species in celery, which was grown in sediments, was different from the species present in duckweed, which grew in water; and (3) a Pb-FA-like compound was present in celery roots. The newly identified Pb species, the Pb-FA-like compound, may play a key role in Pb tolerance and translocation within plants.

  19. Multiple-Scattering of Near-Edge x-ray Absorption Fine Structure of Sulphur-Passivated InP(100) Surface

    Institute of Scientific and Technical Information of China (English)

    曹松; 唐景昌; 沈少来; 陈更生; 马丹

    2003-01-01

    We use the multiple-scattering cluster method to calculate the sulphur 1s near-edge x-ray absorption fine structure (NEXAFS) of S-passivated InP(100) surface. The physical origins of the resonances in the NEXAFS have been unveiled. It is shown that the most important resonance is attributed to the photoelectron scattering between the central sulphur and the nearest indium atoms. The studies show that two S-S dimers with the bond lengths of 2.05 A and 3.05 A coexist in the surface, meanwhile the bridge and antibridge site adsorption of single S could not be ruled out. We support the scanning tunnelling microscopy result that the S-passivated InP(100) surface exhibits significant disorder.

  20. X-ray-absorption near-edge structure of 3d transition elements in tetrahedral coordination: The effect of bond-length variation

    Energy Technology Data Exchange (ETDEWEB)

    Bianconi, A.; Fritsch, E.; Calas, G.; Petiau, J.

    1985-09-15

    The x-ray-absorption near-edge structure (XANES) of transition elements in tetrahedral coordination in crystals and glasses has been studied. We have identified the XANES features in the continuum that can be assigned to multiple scattering within the first coordination shell. The energy positions E/sub r/ of the XANES peaks in the continuum follow the rule (E/sub r/-E/sub b/)d/sup 2/ = const, where E/sub b/ is the energy of the prepeak, defined as the first core excitation to the bound antibonding state of T/sub 2/ symmetry, and d is the interatomic distance. This plot allows us to determine the tetrahedral coordination of a vanadium impurity in a SiO/sub 2/ glass and to get an estimation of the vanadium-oxygen distance (1.77 +- 0.05 A).

  1. X-ray absorption spectra of nucleotides (AMP, GMP, and CMP) in liquid water solutions near the nitrogen K-edge

    Science.gov (United States)

    Ukai, Masatoshi; Yokoya, Akinari; Fujii, Kentaro; Saitoh, Yuji

    2010-07-01

    The X-ray absorption of nucleotides (adenosine-5'-monophosphate, guanosine 5'-monophosphate, and cytidine 5'-monophosphate) are measured in both water solutions and thin solid films at X-ray energies near the nitrogen K-edge in the 'water-window' region. Each spectrum corresponds to the selective excitation of a nucleobase site in a nucleotide, and thus has features similar to the spectrum of the corresponding nucleobase. An additional new peak in the energy region of the nitrogen 1s → π* resonance is observed for each nucleotide. No significant difference between the water solutions and thin solid films is found, which might be attributable to the hydrophobic properties of a nucleobase in a nucleotide.

  2. X-ray absorption near the edge structure and x-ray photoelectron spectroscopy studies on pyrite prepared by thermally sulfurizing iron films

    Institute of Scientific and Technical Information of China (English)

    Zhang Hui; Liu Ying-Shu; Wang Bao-Yi; Wei Long; Kui Re-Xi; Qian Hai-Jie

    2009-01-01

    This paper reports how pyrite films were prepared by thermal sulfurization of magnetron sputtered iron films and characterized by x-ray absorption near edge structure spectra and x-ray photoelectron spectroscopy on a 4B9B beam line at the Beijing Synchrotron Radiation Facility. The band gap of the pyrite agrees well with the optical band gap obtained by a spectrophotometer. The octahedral symmetry of pyrite leads to the splitting of the d orbit into t2g and eg levels. The high spin and low spin states were analysed through the difference of electron exchange interaction and the orbital crystal field. Only when the crystal field splitting is higher than 1.5 eV, the two weak peaks above the white lines can appear, and this was approved by experiments in the present work.

  3. Particle Formation from Pulsed Laser Irradiation of SootAggregates studied with scanning mobility particle sizer, transmissionelectron microscope and near-edge x-ray absorption fine structure.

    Energy Technology Data Exchange (ETDEWEB)

    Michelsen, Hope A.; Tivanski, Alexei V.; Gilles, Mary K.; vanPoppel, Laura H.; Dansson, Mark A.; Buseck, Peter R.; Buseck, Peter R.

    2007-02-20

    We investigated the physical and chemical changes induced in soot aggregates exposed to laser radiation using a scanning mobility particle sizer, a transmission electron microscope, and a scanning transmission x-ray microscope to perform near-edge x-ray absorption fine structure spectroscopy. Laser-induced nanoparticle production was observed at fluences above 0.12 J/cm(2) at 532 nm and 0.22 J/cm(2) at 1064 nm. Our results indicate that new particle formation proceeds via (1) vaporization of small carbon clusters by thermal or photolytic mechanisms, followed by homogeneous nucleation, (2) heterogeneous nucleation of vaporized carbon clusters onto material ablated from primary particles, or (3) both processes.

  4. X-ray-absorption near-edge structure of 3d transition elements in tetrahedral coordination: The effect of bond-length variation

    Science.gov (United States)

    Bianconi, A.; Fritsch, E.; Calas, G.; Petiau, J.

    1985-09-01

    The x-ray-absorption near-edge structure (XANES) of transition elements in tetrahedral coordination in crystals and glasses has been studied. We have identified the XANES features in the continuum that can be assigned to multiple scattering within the first coordination shell. The energy positions Er of the XANES peaks in the continuum follow the rule (Er-Eb)d2= const, where Eb is the energy of the prepeak, defined as the first core excitation to the bound antibonding state of T2 symmetry, and d is the interatomic distance. This plot allows us to determine the tetrahedral coordination of a vanadium impurity in a SiO2 glass and to get an estimation of the vanadium-oxygen distance (1.77+/-0.05 Å).

  5. Multiple-Scattering Approaches to Near-Edge X-Ray Absorption Fine Structure of N2O/Cu(100)

    Institute of Scientific and Technical Information of China (English)

    WU Tai-Quan; TANG Jing-Chang; SHEN Shao-Lai; CAO Song; LI Hai-Yang

    2004-01-01

    @@ The nitrogen 1 s near-edge x-ray absorption fine structure (NEXAFS) spectra of the N2 O adsorbed on the Cu(100) surface have been studied by multiple-scattering cluster (MSC) and self-consistent field DV-Xα methods. It is shown that the N2O molecule is adsorbed on the hollow site with the adsorption height h = 3.0±0.1 A. The MSC calculation confirmed by a DV-Xα analysis has revealed the physical cause of the weak feature in the NEXAFS spectra mentioned above, which originates from the 1s core electrons of the centre and terminal nitrogen atoms transiting into the unoccupied σ* orbital of the N2O molecule.

  6. Near-edge X-ray absorption fine structure study of disordering in Gd2(Ti1-yZry)2O7 pyrochlores.

    Science.gov (United States)

    Nachimuthu, Ponnusamy; Thevuthasan, Suntharampillai; Adams, Evan M; Weber, William J; Begg, Bruce D; Mun, Bongjin S; Shuh, David K; Lindle, Dennis W; Gullikson, Eric M; Perera, Rupert C C

    2005-02-01

    Disorder in Gd2(Ti(1-y)Zry)2O7 pyrochlores, for y = 0.0-1.0, is investigated by Ti 2p and O 1s near-edge X-ray absorption fine structure spectroscopy. Ti(4+) ions are found to occupy octahedral sites in Gd2Ti2O7 with a tetragonal distortion induced by vacant oxygen sites. As Zr substitutes for Ti, the tetragonal distortion decreases, and Zr coordination increases from 6 to 8. The migration of oxygen ions from 48f or 8b sites to vacant 8a sites compensate for the increased Zr coordination, thereby reducing the number of vacant 8a sites, which further reduces the tetragonal distortion and introduces more disorder around Ti. This is evidence for simultaneous cation disorder with anion migration.

  7. Study of Synchrotron Radiation Near-Edge X-Ray Absorption Fine-Structure of Amorphous Hydrogenated Carbon Films at Various Thicknesses

    Directory of Open Access Journals (Sweden)

    Sarayut Tunmee

    2015-01-01

    Full Text Available The compositions and bonding states of the amorphous hydrogenated carbon films at various thicknesses were evaluated via near-edge X-ray absorption fine-structure (NEXAFS and elastic recoil detection analysis combined with Rutherford backscattering spectrometry. The absolute carbon sp2 contents were determined to decrease to 65% from 73%, while the hydrogen contents increase from 26 to 33 at.% as the film thickness increases. In addition, as the film thickness increases, the π⁎ (C=C, σ⁎ (C–H, σ⁎ (C=C, and σ⁎ (C≡C bonding states were found to increase, whereas the π⁎ (C≡C and σ⁎ (C–C bonding states were observed to decrease in the NEXAFS spectra. Consequently, the film thickness is a key factor to evaluate the composition and bonding state of the films.

  8. Composition analysis of a polymer electrolyte membrane fuel cell microporous layer using scanning transmission X-ray microscopy and near edge X-ray absorption fine structure analysis

    Science.gov (United States)

    George, Michael G.; Wang, Jian; Banerjee, Rupak; Bazylak, Aimy

    2016-03-01

    The novel application of scanning transmission X-ray microscopy (STXM) to the microporous layer (MPL) of a polymer electrolyte membrane fuel cell is investigated. A spatially resolved chemical component distribution map is obtained for the MPL of a commercially available SGL 25 BC sample. This is achieved with near edge X-ray absorption fine structure spectroscopic analysis. Prior to analysis the sample is embedded in non-reactive epoxy and ultra-microtomed to a thickness of 100 nm. Polytetrafluoroethylene (PTFE), carbon particle agglomerates, and supporting epoxy resin distributions are identified and reconstructed for a scanning area of 6 μm × 6 μm. It is observed that the spatial distribution of PTFE is strongly correlated to the carbon particle agglomerations. Additionally, agglomerate structures of PTFE are identified, possibly indicating the presence of a unique mesostructure in the MPL. STXM analysis is presented as a useful technique for the investigation of chemical species distributions in the MPL.

  9. The Be K-edge in beryllium oxide and chalcogenides: soft x-ray absorption spectra from first-principles theory and experiment.

    Science.gov (United States)

    Olovsson, W; Weinhardt, L; Fuchs, O; Tanaka, I; Puschnig, P; Umbach, E; Heske, C; Draxl, C

    2013-08-07

    We have carried out a theoretical and experimental investigation of the beryllium K-edge soft x-ray absorption fine structure of beryllium compounds in the oxygen group, considering BeO, BeS, BeSe, and BeTe. Theoretical spectra are obtained ab initio, through many-body perturbation theory, by solving the Bethe-Salpeter equation (BSE), and by supercell calculations using the core-hole approximation. All calculations are performed with the full-potential linearized augmented plane-wave method. It is found that the two different theoretical approaches produce a similar fine structure, in good agreement with the experimental data. Using the BSE results, we interpret the spectra, distinguishing between bound core-excitons and higher energy excitations.

  10. A High Position Resolution X-ray Detector: an Edge on Illuminated Capillary Plate Combined with a Gas Amplification Structure

    CERN Document Server

    Iacobaeus, C; Lund-Jensen, B; Ostling, J; Pavlopoulos, P; Peskov, Vladimir; Tokanai, F

    2006-01-01

    We have developed and successfully tested a prototype of a new type of high position resolution hybrid X-ray detector. It contains a thin wall lead glass capillary plate converter of X-rays combined with a microgap parallel-plate avalanche chamber filled with gas at 1 atm. The operation of these converters was studied in a wide range of X-ray energies (from 6 to 60 keV) at incident angles varying from 0-90 degree. The detection efficiency, depending on the geometry, photon energy, incident angle and the mode of operation, was between 5-30 percent in a single step mode and up to 50 percent in a multi-layered combination. Depending on the capillary geometry, the position resolution achieved was between 0.050-0.250 mm in digital form and was practically independent of the photon energy or gas mixture. The usual lead glass capillary plates operated without noticeable charging up effects at counting rates of 50 Hz/mm2, and hydrogen treated capillaries up to 10E5 Hz/mm2. The developed detector may open new possibil...

  11. Evidence for 5d-σ and 5d-π covalency in lanthanide sesquioxides from oxygen K-edge X-ray absorption spectroscopy.

    Science.gov (United States)

    Altman, Alison B; Pacold, Joseph I; Wang, Jian; Lukens, Wayne W; Minasian, Stefan G

    2016-06-14

    The electronic structure in the complete series of stable lanthanide sesquioxides, Ln2O3 (Ln = La to Lu, except radioactive Pm), has been evaluated using oxygen K-edge X-ray absorption spectroscopy (XAS) with a scanning transmission X-ray microscope (STXM). The experimental results agree with recent synthetic, spectroscopic and theoretical investigations that provided evidence for 5d orbital involvement in lanthanide bonding, while confirming the traditional viewpoint that there is little Ln 4f and O 2p orbital mixing. However, the results also showed that changes in the energy and occupancy of the 4f orbitals can impact Ln 5d and O 2p mixing, leading to several different bonding modes for seemingly identical Ln2O3 structures. On moving from left to right in the periodic table, abrupt changes were observed for the energy and intensity of transitions associated with Ln 5d and O 2p antibonding states. These changes in peak intensity, which were directly related to the amounts of O 2p and Ln 5d mixing, were closely correlated to the well-established trends in the chemical accessibility of the 4f orbitals towards oxidation or reduction. The unique insight provided by the O K-edge XAS is discussed in the context of several recent theoretical and physical studies on trivalent lanthanide compounds.

  12. Sulfur species in source rock bitumen before and after hydrous pyrolysis determined by X-ray absorption near-edge structure

    Science.gov (United States)

    Bolin, Trudy B.; Birdwell, Justin E.; Lewan, Michael; Hill, Ronald J.; Grayson, Michael B.; Mitra-Kirtley, Sudipa; Bake, Kyle D.; Craddock, Paul R.; Abdallah, Wael; Pomerantz, Andrew E.

    2016-01-01

    The sulfur speciation of source rock bitumen (chloroform-extractable organic matter in sedimentary rocks) was examined using sulfur K-edge X-ray absorption near-edge structure (XANES) spectroscopy for a suite of 11 source rocks from around the world. Sulfur speciation was determined for both the native bitumen in thermally immature rocks and the bitumen produced by thermal maturation of kerogen via hydrous pyrolysis (360 °C for 72 h) and retained within the rock matrix. In this study, the immature bitumens had higher sulfur concentrations than those extracted from samples after hydrous pyrolysis. In addition, dramatic and systematic evolution of the bitumen sulfur moiety distributions following artificial thermal maturation was observed consistently for all samples. Specifically, sulfoxide sulfur (sulfur double bonded to oxygen) is abundant in all immature bitumen samples but decreases substantially following hydrous pyrolysis. The loss in sulfoxide sulfur is associated with a relative increase in the fraction of thiophene sulfur (sulfur bonded to aromatic carbon) to the extent that thiophene is the dominant sulfur form in all post-pyrolysis bitumen samples. This suggests that sulfur moiety distributions might be used for estimating thermal maturity in source rocks based on the character of the extractable organic matter.

  13. Multivariate curve resolution analysis for interpretation of dynamic Cu K-edge X-ray absorption spectroscopy spectra for a Cu doped V(2)O(5) lithium battery.

    Science.gov (United States)

    Conti, Paolo; Zamponi, Silvia; Giorgetti, Marco; Berrettoni, Mario; Smyrl, William H

    2010-05-01

    Vanadium pentoxide materials prepared through sol-gel processes act as excellent intercalation hosts for lithium as well as polyvalent cations. A chemometric approach has been applied to study the X-ray absorption near-edge structure (XANES) evolution during in situ scanning of the Cu(0.1)V(2)O(5) xerogel/Li ions battery. Among the more common techniques, the fixed size windows evolving factor analysis (FSWEFA) permits the number of species involved in the experiment to be determined and the range of existence of each of them. This result, combined with the constraints of the invariance of the total concentration and non-negativity of both concentrations and spectra, enabled us to obtain the spectra of the pure components using a multivariate curve resolution refined by an alternate least squares fitting procedure. This allowed the normalized concentration profile to be understood. This data treatment evidenced the occurrence, for the first time, of three species during the battery charging. This fact finds confirmation by comparison of the pure spectra with the experimental ones. Extended X-ray absorption fine structure (EXAFS) analysis confirms the occurrence of three different chemical environments of Cu during battery charging.

  14. Comparison of the magnetic properties of GeMn thin films through Mn L-edge x-ray absorption

    Energy Technology Data Exchange (ETDEWEB)

    Ahlers, S.; Stone, P.R.; Sircar, N.; Arenholz, E.; Dubon, O. D.; Bougeard, D.

    2009-08-04

    X-ray absorption spectroscopy of epitaxial GeMn thin films reveals an experimentally indistinguishable electronic configuration of Mn atoms incorporated in Ge{sub 1?x}Mn{sub x} nanoclusters and in precipitates of the intermetallic compound Mn{sub 5}Ge{sub 3}, respectively. However, the average magnetic response of thin films containing Ge{sub 1?x}Mn{sub x} nanoclusters is lower than the response of films containing Mn{sub 5}Ge{sub 3} precipitates. This reduced magnetic response of Ge{sub 1?x}Mn{sub x} nanoclusters is explained in terms of a fraction of Mn atoms being magnetically inactive due to antiferromagnetic coupling or the presence of structural disorder. A determination of the role of magnetically inactive Mn atoms in the self-assembly of the thermodynamically metastable Ge{sub 1?x}Mn{sub x} nanoclusters seems to be an essential ingredient for an enhanced control of this promising high Curie temperature magnetic semiconductor.

  15. Assessment of chemical species of lead accumulated in tidemarks of human articular cartilage by X-ray absorption near-edge structure analysis

    Energy Technology Data Exchange (ETDEWEB)

    Meirer, Florian [Atominstitut, Vienna University of Technology, 1020 Wien (Austria); MiNALab, CMM-Irst, Fondazione Bruno Kessler, Via Sommarive 18, 38123 Trento (Italy); Pemmer, Bernhard, E-mail: bpemmer@ati.ac.at [Atominstitut, Vienna University of Technology, 1020 Wien (Austria); Pepponi, Giancarlo [MiNALab, CMM-Irst, Fondazione Bruno Kessler, Via Sommarive 18, 38123 Trento (Italy); Zoeger, Norbert; Wobrauschek, Peter [Atominstitut, Vienna University of Technology, 1020 Wien (Austria); Sprio, Simone; Tampieri, Anna [Istituto di Scienza e Tecnologia dei Materiali Ceramici CNR, Faenca (Italy); Goettlicher, Joerg; Steininger, Ralph; Mangold, Stefan [Institute for Synchrotron Radiation, Karlsruhe Institute of Technology, Campus South, 76344 Eggenstein-Leopoldshafen (Germany); Roschger, Paul [Ludwig Boltzmann Institute of Osteology, Hanusch Hospital of WGKK and AUVA Trauma Centre Meidling, 4th Medical Department, Hanusch Hospital, Vienna (Austria); Berzlanovich, Andrea [Department of Forensic Medicine, Medical University of Vienna, A-1090 Vienna (Austria); Hofstaetter, Jochen G. [Ludwig Boltzmann Institute of Osteology, Hanusch Hospital of WGKK and AUVA Trauma Centre Meidling, 4th Medical Department, Hanusch Hospital, Vienna (Austria); Department of Orthopaedics, Vienna General Hospital, Medical University of Vienna, A-1090 Vienna (Austria); Streli, Christina [Atominstitut, Vienna University of Technology, 1020 Wien (Austria)

    2011-03-01

    Lead is a toxic trace element that shows a highly specific accumulation in the transition zone between calcified and non-calcified articular cartilage, the so-called ‘tidemark’. Excellent agreement has been found between XANES spectra of synthetic Pb-doped carbonated hydroxyapatite and spectra obtained in the tidemark region and trabecular bone of normal human samples, confirming that in both tissues Pb is incorporated into the hydroxyapatite crystal structure of bone. During this study the µ-XANES set-up at the SUL-X beamline at ANKA was tested and has proven to be well suited for speciation of lead in human mineralized tissue samples. A highly specific accumulation of the toxic element lead was recently measured in the transition zone between non-calcified and calcified normal human articular cartilage. This transition zone, the so-called ‘tidemark’, is considered to be an active calcification front of great clinical importance. However, little is known about the mechanisms of accumulation and the chemical form of Pb in calcified cartilage and bone. Using spatially resolved X-ray absorption near-edge structure analysis (µ-XANES) at the Pb L{sub 3}-edge, the chemical state of Pb in the osteochondral region was investigated. The feasibility of the µ-XANES set-up at the SUL-X beamline (ANKA synchrotron light source) was tested and confirmed by comparing XANES spectra of bulk Pb-reference compounds recorded at both the XAS and the SUL-X beamline at ANKA. The µ-XANES set-up was then used to investigate the tidemark region of human bone (two patella samples and one femoral head sample). The spectra recorded at the tidemark and at the trabecular bone were found to be highly correlated with the spectra of synthetic Pb-doped carbonated hydroxyapatite, suggesting that in both of these very different tissues Pb is incorporated into the hydroxyapatite structure.

  16. Probing the influence of X-rays on aqueous copper solutions using time-resolved in situ combined video/X-ray absorption near-edge/ultraviolet-visible spectroscopy

    NARCIS (Netherlands)

    Mesu, J. Gerbrand; Beale, Andrew M.|info:eu-repo/dai/nl/325802068; de Groot, Frank M. F.|info:eu-repo/dai/nl/08747610X; Weckhuysen, Bert M.|info:eu-repo/dai/nl/285484397

    2006-01-01

    Time-resolved in situ video monitoring and ultraviolet-visible spectroscopy in combination with X-ray absorption near-edge spectroscopy (XANES) have been used for the first time in a combined manner to study the effect of synchrotron radiation on a series of homogeneous aqueous copper solutions in a

  17. Combined Speciation Analysis by X-ray Absorption Near-Edge Structure Spectroscopy, Ion Chromatography, and Solid-Phase Microextraction Gas Chromatography-Mass Spectrometry To Evaluate Biotreatment of Concentrated Selenium Wastewaters

    NARCIS (Netherlands)

    Lenz, M.; Hullebusch, van E.D.; Farges, F.; Nikitenko, S.; Corvini, P.F.X.; Lens, P.N.L.

    2011-01-01

    In this study we evaluate the potential of anaerobic granular sludge as an inoculum for the bioremediation of selenium-contaminated waters using species-specific analytical methods. Solid species formed by microbial reduction were investigated using X-ray absorption near-edge structure (XANES) spect

  18. Electronic structure and optical properties of CdS{sub x}Se{sub 1−x} solid solution nanostructures from X-ray absorption near edge structure, X-ray excited optical luminescence, and density functional theory investigations

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, M. W. [DESY (Deutsches Elektronen-Synchrotron), FS-PEX, Notkestrasse 85, 22607 Hamburg (Germany); Yiu, Y. M., E-mail: yyiu@uwo.ca; Sham, T. K. [Department of Chemistry, University of Western Ontario, London, ON N6A5B7 (Canada); Ward, M. J. [Cornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, NY 14853 (United States); Liu, L. [Institute of Functional Nano and Soft Materials (FUNSOM) and Soochow University-Western University Center for Synchrotron Radiation Research, Soochow University, Suzhou, Jiangsu, 215123 (China); Hu, Y. [Canadian Light Source, University of Saskatchewan, Saskatoon, SK S7N2V3 (Canada); Zapien, J. A. [Center Of Super-Diamond and Advanced Films (COSDAF) and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR (China); Liu, Yingkai [Institute of Physics and Electronic Information, Yunnan Normal University, Kunming, Yunnan, 650500 (China)

    2014-11-21

    The electronic structure and optical properties of a series of iso-electronic and iso-structural CdS{sub x}Se{sub 1−x} solid solution nanostructures have been investigated using X-ray absorption near edge structure, extended X-ray absorption fine structure, and X-ray excited optical luminescence at various absorption edges of Cd, S, and Se. It is found that the system exhibits compositions, with variable local structure in-between that of CdS and CdSe accompanied by tunable optical band gap between that of CdS and CdSe. Theoretical calculation using density functional theory has been carried out to elucidate the observations. It is also found that luminescence induced by X-ray excitation shows new optical channels not observed previously with laser excitation. The implications of these observations are discussed.

  19. X-ray absorption near-edge structure study on the configuration of Cu 2+ /histidine complexes at different pH values

    Science.gov (United States)

    Mei-Juan, Yu; Yu, Wang; Wei, Xu

    2016-04-01

    The local configurations around metal ions in metalloproteins are of great significance for understanding their biological functions. Cu2+/histidine (His) is a typical complex existing in many metalloproteins and plays an important role in lots of physiological functions. The three-dimensional (3D) structural configurations of Cu2+/His complexes at different pH values (2.5, 6.5, and 8.5) are quantitatively determined by x-ray absorption near-edge structure (XANES). Generally Cu2+/His complex keeps an octahedral configuration consisting of oxygen atoms from water molecules and oxygen or nitrogen atoms from histidine molecules coordinated around Cu2+. It is proved in this work that the oxygen atoms from water molecules, when increasing the pH value from acid to basic value, are gradually substituted by the Ocarboxyl, Nam, and Nim from hisitidine molecules. Furthermore, the symmetries of Cu2+/His complexes at pH 6.5 and pH 8.5 are found to be lower than at pH 2.5. Project supported by the National Natural Science Foundation of China (Grant No. 11205186).

  20. Near edge X-ray absorption fine structure study for optimization of hard diamond-like carbon film formation with Ar cluster ion beam

    CERN Document Server

    Kitagawa, T; Kanda, K; Shimizugawa, Y; Toyoda, N; Matsui, S; Yamada, I; Tsubakino, H; Matsuo, J

    2003-01-01

    Diamond-like carbon (DLC) film deposited using C sub 6 sub 0 vapor with simultaneous irradiation of an Ar cluster ion beam was characterized by a near edge X-ray absorption fine structure (NEXAFS), in order to optimize the hard DLC film deposition conditions. Contents of sp sup 2 orbitals in the films, which were estimated from NEXAFS spectra, are 30% lower than that of a conventional DLC film deposited by a RF plasma method. Those contents were obtained under the flux ratio of the C sub 6 sub 0 molecules to the Ar cluster ions to range from 1 to 20, at 5keV of Ar cluster ion acceleration energy. Average hardness of the films was 50 GPa under these flux ratios. This hardness was three times higher than that of a conventional DLC film. Furthermore, the lowest sp sup 2 content and above-mentioned high hardness were obtained at room temperature of the substrate when the depositions were performed in the range of the substrate temperature from room temperature to 250degC. (author)

  1. Local structural studies of the cubic Cd1–xCaxO system through Cd K-edge extended X-ray absorption spectroscopic studies

    Science.gov (United States)

    Srihari, Velaga; Sridharan, V.; Nomura, Masaharu; Sastry, V. Sankara; Sundar, C. S

    2012-01-01

    Cd K-edge extended X-ray absorption fine-structure spectroscopic studies were carried out on Cd1–xCaxO (0 ≤ x ≤0.9) solid solutions and the first and second nearest neighbour (NN) distances and their mean square relative displacement σ2 were estimated. The first NN distance, d Cd–O(x), was found to be smaller than its expected value, a(x)/2, obtained from the X-ray diffraction measurements. It increases monotonically and non-linearly with a negative curvature, comparable with that of the a(x) value variation. The variation σ2 of the 1NN with x is consistent with a disordered solid solution model. The 2NN distances d Cd–Cd(x) and d Cd–Ca(x) are found to follow the average values obtained by X-ray diffraction with d Cd–Ca(x) > d Cd–Cd(x). From detailed analysis it is argued that the solid solution exhibits a bimodal distribution of the 1NN distances, d Cd–O(x) and d Ca–O(x), and that the system belongs to a persistent type. PMID:22713887

  2. Identification of sources of lead in the atmosphere by chemical speciation using X-ray absorption near-edge structure (XANES) spectroscopy.

    Science.gov (United States)

    Sakata, Kohei; Sakaguchi, Aya; Tanimizu, Masaharu; Takaku, Yuichi; Yokoyama, Yuka; Takahashi, Yoshio

    2014-02-01

    Sources of Pb pollution in the local atmosphere together with Pb species, major ions, and heavy metal concentrations in a size-fractionated aerosol sample from Higashi-Hiroshima (Japan) have been determined by X-ray absorption near-edge structure (XANES) spectroscopy, ion chromatography, and ICP-MS/AES, respectively. About 80% of total Pb was concentrated in fine aerosol particles. Lead species in the coarse aerosol particles were PbC2O4, 2PbCO3 Pb(OH)2, and Pb(NO3)2, whereas Pb species in the fine aerosol particles were PbC2O4, PbSO4, and Pb(NO3)2. Chemical speciation and abundance data suggested that the source of Pb in the fine aerosol particles was different from that of the coarse ones. The dominant sources of Pb in the fine aerosol particles were judged to be fly ash from a municipal solid waste incinerator and heavy oil combustion. For the coarse aerosol particles, road dust was considered to be the main Pb source. In addition to Pb species, elemental concentrations in the aerosols were also determined. The results suggested that Pb species in size-fractionated aerosols can be used to identify the origin of aerosol particles in the atmosphere as an alternative to Pb isotope ratio measurement.

  3. Near-Edge X-Ray Absorption Fine Structure of Ultrananocrystalline Diamond/Hydrogenated Amorphous Carbon Films Prepared by Pulsed Laser Deposition

    Directory of Open Access Journals (Sweden)

    Shinya Ohmagari

    2009-01-01

    Full Text Available The atomic bonding configuration of ultrananocrystalline diamond (UNCD/hydrogenated amorphous carbon (a-C:H films prepared by pulsed laser ablation of graphite in a hydrogen atmosphere was examined by near-edge X-ray absorption fine structure spectroscopy. The measured spectra were decomposed with simple component spectra, and they were analyzed in detail. As compared to the a-C:H films deposited at room substrate-temperature, the UNCD/a-C:H and nonhydrogenated amorphous carbon (a-C films deposited at a substrate-temperature of 550∘C exhibited enhanced ∗ and ∗C≡C peaks. At the elevated substrate-temperature, the ∗ and ∗C≡C bonds formation is enhanced while the ∗C–H and ∗C–C bonds formation is suppressed. The UNCD/a-C:H film showed a larger ∗C–C peak than the a-C film deposited at the same elevated substrate-temperature in vacuum. We believe that the intense ∗C–C peak is evidently responsible for UNCD crystallites existence in the film.

  4. In situ X-ray near-edge absorption spectroscopy investigation of the state of charge of all-vanadium redox flow batteries.

    Science.gov (United States)

    Jia, Chuankun; Liu, Qi; Sun, Cheng-Jun; Yang, Fan; Ren, Yang; Heald, Steve M; Liu, Yadong; Li, Zhe-Fei; Lu, Wenquan; Xie, Jian

    2014-10-22

    Synchrotron-based in situ X-ray near-edge absorption spectroscopy (XANES) has been used to study the valence state evolution of the vanadium ion for both the catholyte and anolyte in all-vanadium redox flow batteries (VRB) under realistic cycling conditions. The results indicate that, when using the widely used charge-discharge profile during the first charge process (charging the VRB cell to 1.65 V under a constant current mode), the vanadium ion valence did not reach V(V) in the catholyte and did not reach V(II) in the anolyte. Consequently, the state of charge (SOC) for the VRB cell was only 82%, far below the desired 100% SOC. Thus, such incompletely charged mix electrolytes results in not only wasting the electrolytes but also decreasing the cell performance in the following cycles. On the basis of our study, we proposed a new charge-discharge profile (first charged at a constant current mode up to 1.65 V and then continuously charged at a constant voltage mode until the capacity was close to the theoretical value) for the first charge process that achieved 100% SOC after the initial charge process. Utilizing this new charge-discharge profile, the theoretical charge capacity and the full utilization of electrolytes has been achieved, thus having a significant impact on the cost reduction of the electrolytes in VRB.

  5. Study of apical oxygen atoms in a spin-ladder cuprate compound by X-ray absorption spectroscopy near the Cu K edge

    Energy Technology Data Exchange (ETDEWEB)

    Hatterer, C.J.; Eustache, B.; Collin, L.; Beuran, C.F.; Partiot, C.; Germain, P.; Xu, X.Z.; Lagues, M. [CNRS, Paris (France). Surfaces et Supraconducteurs; Michalowicz, A. [Laboratoire de Physique des Milieux Desordonnes, Universite Paris XII Val-de-Marne, 61 avenue du general de Gaulle, 94010, Creteil Cedex (France)]|[LURE, Universite Paris Sud, 91405, Orsay Cedex (France); Moscovici, J. [Laboratoire de Physique des Milieux Desordonnes, Universite Paris XII Val-de-Marne, 61 avenue du general de Gaulle, 94010, Creteil Cedex (France); Deville Cavellin, C. [CNRS, Paris (France). Surfaces et Supraconducteurs]|[Laboratoire d`Electronique, Universite Paris XII Val-de-Marne, 61 av. du general de Gaulle, 94010, Creteil Cedex (France); Traverse, A. [LURE, Universite Paris Sud, 91405, Orsay Cedex (France)

    1997-04-01

    The structure of high-T{sub c} superconducting cuprate compounds is based on CuO{sub 2} planes alternating with blocks that behave as charge reservoirs. The apical oxygen atoms which belong to these reservoirs are suspected to play a role in the mechanism of superconductivity. It thus seems necessary to measure the amount of apical oxygen atoms in various compounds, as a function of the superconducting properties. Polarisation dependent X-ray absorption spectroscopy (XAS) measurements were performed near the Cu K-edge on three types of phases. We collected information about the neighbourhood of the copper atom in the cuprate planes and in the direction perpendicular to these planes. Two of these phases have well known structures: Bi2212 in which copper atoms are on a pyramidal site and infinite layer phase, a square planar cuprate without apical oxygen. We used the obtained results as reference data to study a new copper-rich phase related to the spin-ladder series. (orig.)

  6. A novel surface-sensitive X-ray absorption spectroscopic detector to study the thermal decomposition of cathode materials for Li-ion batteries

    Science.gov (United States)

    Nonaka, Takamasa; Okuda, Chikaaki; Oka, Hideaki; Nishimura, Yusaku F.; Makimura, Yoshinari; Kondo, Yasuhito; Dohmae, Kazuhiko; Takeuchi, Yoji

    2016-09-01

    A surface-sensitive conversion-electron-yield X-ray absorption fine structure (CEY-XAFS) detector that operates at elevated temperatures is developed to investigate the thermal decomposition of cathode materials for Li-ion batteries. The detector enables measurements with the sample temperature controlled from room temperature up to 450 °C. The detector is applied to the LiNi0.75Co0.15Al0.05Mg0.05O2 cathode material at 0% state of charge (SOC) and 50% SOC to examine the chemical changes that occur during heating in the absence of an electrolyte. The combination of surface-sensitive CEY-XAFS and bulk-sensitive transmission-mode XAFS shows that the reduction of Ni and Co ions begins at the surface of the cathode particles at around 150 °C, and propagates inside the particle upon further heating. These changes with heating are irreversible and are more obvious at 50% SOC than at 0% SOC. The fraction of reduced Ni ions is larger than that of reduced Co ions. These results demonstrate the capability of the developed detector to obtain important information for the safe employment of this cathode material in Li-ion batteries.

  7. Modeling of normal incidence absorption in p-type GaAs/AlGaAs quantum well infrared detectors

    Science.gov (United States)

    Brown, Gail J.; Szmulowicz, Frank

    1995-04-01

    The absorption of infrared radiation at normal incidence in p-type GaAs/AlGaAs quantum wells, unlike in n-type, is fundamentally allowed. We have measured and theoretically modeled the bound-to-continuum absorption in these p-type materials. The infrared absorption coefficient was calculated are based on the electronic structure, wave functions and optical matrix elements obtained from an 8 X 8 envelope-function approximation (EFA) calculation. The 8 X 8 EFA Hamiltonian incorporates the coupling between the heavy, light, spin-orbit, and conduction bands. In calculating the continuum states for bound-to- continuum intersubband absorption, we do not enclose the well in an artificial box with infinite walls. A comparison of the theoretical absorption and measured photoresponse results verified the accuracy of our model and provided a basis for optimizing the design of p-type quantum wells for infrared detection.

  8. Carbon K-edge X-ray absorption spectroscopy and time-dependent density functional theory examination of metal-carbon bonding in metallocene dichlorides.

    Science.gov (United States)

    Minasian, Stefan G; Keith, Jason M; Batista, Enrique R; Boland, Kevin S; Kozimor, Stosh A; Martin, Richard L; Shuh, David K; Tyliszczak, Tolek; Vernon, Louis J

    2013-10-01

    Metal-carbon covalence in (C5H5)2MCl2 (M = Ti, Zr, Hf) has been evaluated using carbon K-edge X-ray absorption spectroscopy (XAS) as well as ground-state and time-dependent hybrid density functional theory (DFT and TDDFT). Differences in orbital mixing were determined experimentally using transmission XAS of thin crystalline material with a scanning transmission X-ray microscope (STXM). Moving down the periodic table (Ti to Hf) has a marked effect on the experimental transition intensities associated with the low-lying antibonding 1a1* and 1b2* orbitals. The peak intensities, which are directly related to the M-(C5H5) orbital mixing coefficients, increase from 0.08(1) and 0.26(3) for (C5H5)2TiCl2 to 0.31(3) and 0.75(8) for (C5H5)2ZrCl2, and finally to 0.54(5) and 0.83(8) for (C5H5)2HfCl2. The experimental trend toward increased peak intensity for transitions associated with 1a1* and 1b2* orbitals agrees with the calculated TDDFT oscillator strengths [0.10 and 0.21, (C5H5)2TiCl2; 0.21 and 0.73, (C5H5)2ZrCl2; 0.35 and 0.69, (C5H5)2HfCl2] and with the amount of C 2p character obtained from the Mulliken populations for the antibonding 1a1* and 1b2* orbitals [8.2 and 23.4%, (C5H5)2TiCl2; 15.3 and 39.7%, (C5H5)2ZrCl2; 20.1 and 50.9%, (C5H5)2HfCl2]. The excellent agreement between experiment, theory, and recent Cl K-edge XAS and DFT measurements shows that C 2p orbital mixing is enhanced for the diffuse Hf (5d) and Zr (4d) atomic orbitals in relation to the more localized Ti (3d) orbitals. These results provide insight into how changes in M-Cl orbital mixing within the metallocene wedge are correlated with periodic trends in covalent bonding between the metal and the cyclopentadienide ancillary ligands.

  9. X-Ray Absorption Spectroscopy of Mo and Ni K-edge of Supported Hydrotreating Catalysts%硫化态加氢精制催化剂的Mo和NiK边XAFS研究

    Institute of Scientific and Technical Information of China (English)

    段爱军; 徐春明; 赵震; 董鹏

    2005-01-01

    X-ray absorption fine structure (XAFS) and other techniques have been used to characterize Ni-Mo/Al2O3supported catalysts. The analysis of Mo K-edge spetrum shows that the active species over sulfide catalysts are MoS2-alike and the dispersion of Mo is high at the level of nanometer particles. There may exist some distortion of the local environment of MoS2, which has an influence on the hydrotreating activities of catalysts. Ni K-edge analysis shows that the coordination effects of Ni-Mo favor the dispersion state of active phase and imply a close relationship with catalyst activities.

  10. Cu K-edge X-ray Absorption Spectroscopy Reveals Differential Copper Coordimation Within Amyloid-beta Oligomers Compared to Amyloid-beta Monomers

    Energy Technology Data Exchange (ETDEWEB)

    J Shearer; P Callan; T Tran; V Szalai

    2011-12-31

    The fatal neurodegenerative disorder Alzheimer's disease (AD) has been linked to the formation of soluble neurotoxic oligomers of amyloid-{beta} (A{beta}) peptides. These peptides have high affinities for copper cations. Despite their potential importance in AD neurodegeneration few studies have focused on probing the Cu{sup 2+/1+} coordination environment within A{beta} oligomers. Herein we present a Cu K-edge X-ray absorption spectroscopic study probing the copper-coordination environment within oligomers of A{beta}(42) (sequence: DAEFRHDSGYEVHHQKLVFFAEDVGSNKGAIIGLMVGGVVIA). We find that the Cu{sup 2+} cation is contained within a square planar mixed N/O ligand environment within A{beta}(42) oligomers, which is similar to the copper coordination environment of the monomeric forms of {l_brace}Cu{sup II}A{beta}(40){r_brace} and {l_brace}Cu{sup II}A{beta}(16){r_brace}. Reduction of the Cu{sup 2+} cation within the A{beta}(42) oligomers to Cu{sup 1+} yields a highly dioxygen sensitive copper-species that contains Cu{sup 1+} in a tetrahedral coordination geometry. This can be contrasted with monomers of {l_brace}Cu{sup I}A{beta}(40){r_brace} and {l_brace}Cu{sup I}A{beta}(16){r_brace}, which contain copper in a dioxygen inert linear bis-histidine ligand environment [Shearer and Szalai, J. Am. Chem. Soc., 2008, 130, 17826]. The biological implications of these findings are discussed.

  11. [Effects of long-term fertilization on organic carbon functional groups in black soil as revealed by synchrotron radiation soft X-ray near-edge absorption spectroscopy].

    Science.gov (United States)

    Wang, Nan; Wang, Shuai; Wang, Qing-He; Dong, Pei-Bo; Li, Cui-Lan; Zhang, Jin-Jing; Gao, Qiang; Zhao, Yi-Dong

    2012-10-01

    A 20 years (1984-2004) stationary field experiment was conducted to evaluate the effects of long-term application of chemical fertilizers (N or NPK) alone or in combination with low (0.125 kg x hm(-2)) or high dose of corn stalk (0.25 kg x hm(-2)) on organic carbon functional groups in black soil using synchrotron radiation soft X-ray near-edge absorption spectroscopy (C-1s NEXAFS). Compared with the control (CK) treatment, the aromatic C and the carboxyl C of soil increased, whereas the aliphatic C, the carbonyl C and the aliphatic C/aromatic C ratio decreased after the application of chemical fertilizer alone. After the application of chemical fertilizations in combined with corn stalk, the aromatic C decreased while the aliphatic C and the aliphatic C/aromatic C ratio increased as compared to N or NPK fertilizer treatment. And the change tendency was more obvious with the increase in the dose of corn stalk applied. Regardless of corn stalk application, the aromatic C, the aliphatic C, and the aliphatic C/aromatic C ratio were all higher for NPK than for N fertilizer treatment. The above results indicated that, compared with the no-fertilizer control treatment, the application of chemical fertilizers alone resulted in the relative proportion of aromatic compounds increased whereas that of aliphatic hydrocarbon compounds decreased. On the other hand, the relative proportion of the aliphatic hydrocarbon compounds was higher after the application of chemical fertilizers with than without corn stalk, with high than with low dose of corn stalk, and with NPK than with N fertilization. C-1s NEXAFS spectroscopy could characterize in situ the changes of organic carbon functional groups in soil under long-term stationary fertilization.

  12. In-operando synchronous time-multiplexed O K-edge x-ray absorption spectromicroscopy of functioning tantalum oxide memristors

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Suhas [Hewlett-Packard Laboratories, 1501 Page Mill Road, Palo Alto, California 94304 (United States); Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States); Graves, Catherine E.; Strachan, John Paul, E-mail: john-paul.strachan@hp.com; Williams, R. Stanley [Hewlett-Packard Laboratories, 1501 Page Mill Road, Palo Alto, California 94304 (United States); Kilcoyne, A. L. David; Tyliszczak, Tolek [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Nishi, Yoshio [Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States)

    2015-07-21

    Memristors are receiving keen interest because of their potential varied applications and promising large-scale information storage capabilities. Tantalum oxide is a memristive material that has shown promise for high-performance nonvolatile computer memory. The microphysics has been elusive because of the small scale and subtle physical changes that accompany conductance switching. In this study, we probed the atomic composition, local chemistry, and electronic structure of functioning tantalum oxide memristors through spatially mapped O K-edge x-ray absorption. We developed a time-multiplexed spectromicroscopy technique to enhance the weak and possibly localized oxide modifications with spatial and spectral resolutions of <30 nm and 70 meV, respectively. During the initial stages of conductance switching of a micrometer sized crosspoint device, the spectral changes were uniform within the spatial resolution of our technique. When the device was further driven with millions of high voltage-pulse cycles, we observed lateral motion and separation of ∼100 nm-scale agglomerates of both oxygen interstitials and vacancies. We also demonstrate a unique capability of this technique by identifying the relaxation behavior in the material during electrical stimuli by identifying electric field driven changes with varying pulse widths. In addition, we show that changes to the material can be localized to a spatial region by modifying its topography or uniformity, as against spatially uniform changes observed here during memristive switching. The goal of this report is to introduce the capability of time-multiplexed x-ray spectromicroscopy in studying weak-signal transitions in inhomogeneous media through the example of the operation and temporal evolution of a memristor.

  13. An Extreme, Blueshifted Iron-Line Profile in the Narrow-Line Seyfert 1 PG 1402+261: An Edge-on Accretion Disk or Highly Ionized Absorption?

    Science.gov (United States)

    Reeves, J. N.; Porquet, D.; Turner, T. J.

    2004-11-01

    We report on a short XMM-Newton observation of the radio-quiet narrow-line Seyfert 1 galaxy PG 1402+261. The EPIC X-ray spectrum of PG 1402+261 shows a strong excess of counts between 6 and 9 keV in the rest frame. This feature can be modeled by an unusually strong (equivalent width 2 keV) and very broad (FWHM velocity of 110,000 km s-1) iron K-shell emission line. The line centroid energy at 7.3 keV appears blueshifted with respect to the iron Kα emission band between 6.4 and 6.97 keV, while the blue wing of the line extends to 9 keV in the quasar rest frame. The line profile can be fitted by reflection from the inner accretion disk, but an inclination angle of >60° is required to model the extreme blue wing of the line. Furthermore, the extreme strength of the line requires a geometry whereby the hard X-ray emission from PG 1402+261 above 2 keV is dominated by the pure-reflection component from the disk, while little or none of the direct hard power law is observed. Alternatively, the spectrum above 2 keV may be explained by an ionized absorber, if the column density is sufficiently high (NH>3×1023 cm-2) and if the matter is ionized enough to produce a deep (τ~1) iron K-shell absorption edge at 9 keV. This absorber could originate in a large column density, high-velocity outflow, perhaps similar to those that appear to be observed in several other high accretion rate active galactic nuclei. Further observations, especially at higher spectral resolution, are required to distinguish between the accretion disk reflection and outflow scenarios.

  14. Near-edge X-ray absorption fine structure (NEXAFS) spectroscopy for mapping nano-scale distribution of organic carbon forms in soil: Application to black carbon particles

    Science.gov (United States)

    Lehmann, Johannes; Liang, Biqing; Solomon, Dawit; Lerotic, Mirna; LuizãO, Flavio; Kinyangi, James; SchäFer, Thorsten; Wirick, Sue; Jacobsen, Chris

    2005-03-01

    Small-scale heterogeneity of organic carbon (C) forms in soils is poorly quantified since appropriate analytical techniques were not available up to now. Specifically, tools for the identification of functional groups on the surface of micrometer-sized black C particles were not available up to now. Scanning Transmission X-ray Microscopy (STXM) using synchrotron radiation was used in conjunction with Near-Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy to investigate nano-scale distribution (50-nm resolution) of C forms in black C particles and compared to synchrotron-based FTIR spectroscopy. A new embedding technique was developed that did not build on a C-based embedding medium and did not pose the risk of heat damage to the sample. Elemental sulfur (S) was melted to 220°C until it polymerized and quenched with liquid N2 to obtain a very viscous plastic S in which the black C could be embedded until it hardened to a noncrystalline state and was ultrasectioned. Principal component and cluster analysis followed by singular value decomposition was able to resolve distinct areas in a black carbon particle. The core of the studied biomass-derived black C particles was highly aromatic even after thousands of years of exposure in soil and resembled the spectral characteristics of fresh charcoal. Surrounding this core and on the surface of the black C particle, however, much larger proportions of carboxylic and phenolic C forms were identified that were spatially and structurally distinct from the core of the particle. Cluster analysis provided evidence for both oxidation of the black C particle itself as well as adsorption of non-black C. NEXAFS spectroscopy has great potential to allow new insight into black C properties with important implications for biogeochemical cycles such as mineralization of black C in soils and sediments, and adsorption of C, nutrients, and pollutants as well as transport in the geosphere, hydrosphere, and atmosphere.

  15. Measuring fast electron spectra and laser absorption in relativistic laser-solid interactions using differential bremsstrahlung photon detectors

    CERN Document Server

    Scott, R H H; Perez, F; Streeter, M J V; Davies, J R; Schlenvoigt, H -P; Santos, J J; Hulin, S; Lancaster, K L; Baton, S D; Rose, S J; Norreys, P A

    2013-01-01

    A photon detector suitable for the measurement of bremsstrahlung spectra generated in relativistically-intense laser-solid interactions is described. The Monte Carlo techniques used to back-out the fast electron spectrum and laser energy absorbed into fast electrons are detailed. A relativistically-intense laser-solid experiment using frequency doubled laser light is used to demonstrate the effective operation of the detector. The experimental data was interpreted using the 3-spatial-dimension Monte Carlo code MCNPX (Pelowitz 2008), and the fast electron temperature found to be 125 keV.

  16. Measuring fast electron spectra and laser absorption in relativistic laser-solid interactions using differential bremsstrahlung photon detectors.

    Science.gov (United States)

    Scott, R H H; Clark, E L; Pérez, F; Streeter, M J V; Davies, J R; Schlenvoigt, H-P; Santos, J J; Hulin, S; Lancaster, K L; Baton, S D; Rose, S J; Norreys, P A

    2013-08-01

    A photon detector suitable for the measurement of bremsstrahlung spectra generated in relativistically intense laser-solid interactions is described. The Monte Carlo techniques used to extract the fast electron spectrum and laser energy absorbed into forward-going fast electrons are detailed. A relativistically intense laser-solid experiment using frequency doubled laser light is used to demonstrate the effective operation of the detector. The experimental data were interpreted using the 3-spatial-dimension Monte Carlo code MCNPX [D. Pelowitz, MCNPX User's Manual Version 2.6.0, Los Alamos National Laboratory, 2008], and the fast electron temperature found to be 125 keV.

  17. Correlation of O (1s) and Fe (2p) near edge x-ray absorption fine structure spectra and electrical conductivity of La1-xSrxFe0.75Ni0.25O3-δ

    Science.gov (United States)

    Erat, Selma; Braun, Artur; Ovalle, Alejandro; Piamonteze, Cinthia; Liu, Zhi; Graule, Thomas; Gauckler, Ludwig J.

    2009-10-01

    A-site substitution of La3+ by Sr2+ in polaron conducting ABO3-type perovskite La1-xSrxFe0.75Ni0.25O3-δ causes oxidation of Fe3+ toward Fe4+ and formation of conducting electron holes, as evidenced by Fe (2p) and O (1s) near edge x-ray absorption fine structure spectra. Hole doping is reflected by linear variation of the prepeak ratio eg(↑)/[t2g(↓)+eg(↓)] of oxygen spectra, along with increased conductivity. The significant increase in conductivity due to NiO doping in La1-xSrxFeO3-δ is caused by increased overlap between Fe (3d) and O (2p) and charge transfer from the O (2p) to the Ni (3d) states, as concluded from near edge x-ray absorption fine structure spectra and ligand field multiplet calculations.

  18. Simulating Ru L 3 -Edge X-ray Absorption Spectroscopy with Time-Dependent Density Functional Theory: Model Complexes and Electron Localization in Mixed-Valence Metal Dimers

    Energy Technology Data Exchange (ETDEWEB)

    Van Kuiken, Benjamin E.; Valiev, Marat; Daifuku, Stephanie L.; Bannan, Caitlin; Strader, Matthew L.; Cho, Hana; Huse, Nils; Schoenlein, Robert W.; Govind, Niranjan; Khalil, Munira

    2013-05-30

    Ruthenium L3-edge X-ray absorption (XA) spectroscopy probes unoccupied 4d orbitals of the metal atom and is increasingly being used to investigate the local electronic structure in ground and excited electronic states of Ru complexes. The simultaneous development of computational tools for simulating Ru L3-edge spectra is crucial for interpreting the spectral features at a molecular level. This study demonstrates that time-dependent density functional theory (TDDFT) is a viable and predictive tool for simulating ruthenium L3-edge XA spectroscopy. We systematically investigate the effects of exchange correlation functional and implicit and explicit solvent interactions on a series of RuII and RuIII complexes in their ground and electronic excited states. The TDDFT simulations reproduce all of the experimentally observed features in Ru L3-edge XA spectra within the experimental resolution (0.4 eV). Our simulations identify ligand-specific charge transfer features in complicated Ru L3-edge spectra of [Ru(CN)6]4- and RuII polypyridyl complexes illustrating the advantage of using TDDFT in complex systems. We conclude that the B3LYP functional most accurately predicts the transition energies of charge transfer features in these systems. We use our TDDFT approach to simulate experimental Ru L3-edge XA spectra of transition metal mixed-valence dimers of the form [(NC)5MII-CN-RuIII(NH3)5] (where M = Fe or Ru) dissolved in water. Our study determines the spectral signatures of electron delocalization in Ru L3-edge XA spectra. We find that the inclusion of explicit solvent molecules is necessary for reproducing the spectral features and the experimentally determined valencies in these mixed-valence complexes. This study validates the use of TDDFT for simulating Ru 2p excitations using popular quantum chemistry codes and providing a powerful interpretive tool for equilibrium and ultrafast Ru L3-edge XA spectroscopy.

  19. Optical absorption characteristics in the assessment of powder phosphor-based x-ray detectors: from nano- to micro-scale.

    Science.gov (United States)

    Liaparinos, P F

    2015-11-21

    X-ray phosphor-based detectors have enormously improved the quality of medical imaging examinations through the optimization of optical diffusion. In recent years, with the development of science and technology in the field of materials, improved powder phosphors require structural and optical properties that contribute to better optical signal propagation. The purpose of this paper was to provide a quantitative and qualitative understanding of the optical absorption characteristics in the assessment of powder phosphor-based detectors (from nano- scale up to micro-scale). Variations on the optical absorption parameters (i.e. the light extinction coefficient [Formula: see text] and the percentage probability of light absorption p%) were evaluated based on Mie calculations examining a wide range of light wavelengths, particle refractive indices and sizes. To model and assess the effects of the aforementioned parameters on optical diffusion, Monte Carlo simulation techniques were employed considering: (i) phosphors of different layer thickness, 100 μm (thin layer) and 300 μm (thick layer), respectively, (ii) light extinction coefficient values, 1, 3 and 6 μm(-1), and (iii) percentage probability of light absorption p% in the range 10(-4)-10(-2). Results showed that the [Formula: see text] coefficient is high for phosphor grains in the submicron scale and for low light wavelengths. At higher wavelengths (above 650 nm), optical quanta follow approximately similar depths until interaction for grain diameter 500 nm and 1 μm. Regarding the variability of the refractive index, high variations of the [Formula: see text] coefficient occurred above 1.6. Furthermore, results derived from Monte Carlo modeling showed that high spatial resolution phosphors can be accomplished by increasing the [Formula: see text] parameter. More specifically, the FWHM was found to decrease (i.e. higher resolution): (i) 4.8% at 100 μm and (ii) 9.5%, at 300 μm layer thickness. This study

  20. Use of X-ray absorption near edge structure (XANES) to identify physisorption and chemisorption of phosphate onto ferrihydrite-modified diatomite.

    Science.gov (United States)

    Xiong, Wenhui; Peng, Jian; Hu, Yongfeng

    2012-02-15

    This paper presents a novel technique integrating bulk-sensitive and surface-sensitive XANES methods to distinguish between physisorption and chemisorption for phosphate adsorption onto ferrihydrite-modified diatomite (FHMD). XANES P K-edge, L-edge, and Fe M-edge spectra were obtained for reference samples (K(2)HPO(4) and FePO(4)·2H(2)O) and test samples (phosphate adsorbed onto FHMD (FHMD-Ps) and Si-containing ferrihydrite (FHYD-Ps)). A resolvable pre-edge peak in the P K-edge spectra of FHMD-Ps and FHYD-Ps provided direct evidence for the formation of P-O-Fe(III) coordination and the occurrence of chemisorption. The resemblance between the P L-edge spectra of K(2)HPO(4) and FHMD-Ps and the marked difference between the spectra of FHMD-Ps and FePO(4)·2H(2)O indicated the intact existence of the adsorbate and the adsorbent. The similarity between Fe M-edge spectra of FHMD and FHMD-Ps and the difference between the spectra of FHMD-Ps and FePO(4)·2H(2)O confirmed the findings from P L-edge analyses. Therefore, chemisorption and physisorption coexisted during phosphate adsorption onto FHMD. Phosphate chemisorption occurred in the deeper zone of FHMD (from 50 nm to 5 μm); whereas physisorption occurred in the zone of FHMD shallower than 50 nm since the probing depth of XANES P K-edge method is 5 μm and that of P L-edge and Fe M-edge methods is 50 nm. Copyright © 2011 Elsevier Inc. All rights reserved.

  1. INVISIBLE ACTIVE GALACTIC NUCLEI. II. RADIO MORPHOLOGIES AND FIVE NEW H i 21 cm ABSORPTION LINE DETECTORS

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Ting; Stocke, John T.; Darling, Jeremy [Center for Astrophysics and Space Astronomy, UCB 389, University of Colorado, Boulder, CO 80309-0389 (United States); Momjian, Emmanuel [National Radio Astronomy Observatory, P.O. Box O, Socorro, NM 87801 (United States); Sharma, Soniya [Research School of Astronomy and Astrophysics, The Australian National University, Mt Stromlo Observatory, ACT 2611 (Australia); Kanekar, Nissim [National Centre for Radio Astrophysics, TIFR, Post Bag 3, Ganeshkhind, Pune 411 007 (India)

    2016-03-15

    This is the second paper directed toward finding new highly redshifted atomic and molecular absorption lines at radio frequencies. To this end, we selected a sample of 80 candidates for obscured radio-loud active galactic nuclei (AGNs) and presented their basic optical/near-infrared (NIR) properties in Paper I. In this paper, we present both high-resolution radio continuum images for all of these sources and H i 21 cm absorption spectroscopy for a few selected sources in this sample. A-configuration 4.9 and 8.5 GHz Very Large Array continuum observations find that 52 sources are compact or have substantial compact components with size <0.″5 and flux densities >0.1 Jy at 4.9 GHz. The 36 most compact sources were then observed with the Very Long Baseline Array at 1.4 GHz. One definite and 10 candidate Compact Symmetric Objects (CSOs) are newly identified, which is a detection rate of CSOs ∼three times higher than the detection rate previously found in purely flux-limited samples. Based on possessing compact components with high flux densities, 60 of these sources are good candidates for absorption-line searches. Twenty-seven sources were observed for H i 21 cm absorption at their photometric or spectroscopic redshifts with only six detections (five definite and one tentative). However, five of these were from a small subset of six CSOs with pure galaxy optical/NIR spectra (i.e., any AGN emission is obscured) and for which accurate spectroscopic redshifts place the redshifted 21 cm line in a radio frequency intereference (RFI)-free spectral “window” (i.e., the percentage of H i 21 cm absorption-line detections could be as high as ∼90% in this sample). It is likely that the presence of ubiquitous RFI and the absence of accurate spectroscopic redshifts preclude H i detections in similar sources (only 1 detection out of the remaining 22 sources observed, 13 of which have only photometric redshifts); that is, H i absorption may well be present but is masked by

  2. Infrared and X-ray Absorption Near Edge Structure Spectroscopy Analyses of the Titan Haze Simulation (THS) Aerosols Produced at Low Temperature (200 K)

    Science.gov (United States)

    Sciamma-O'Brien, Ella; Salama, Farid

    2016-10-01

    We present our latest results on the Titan Haze Simulation (THS) experiment developed on the COSmIC simulation chamber at NASA Ames. In Titan's atmosphere, a complex organic chemistry induced by UV radiation and electron bombardment occurs between N2 and CH4 and leads to the production of larger molecules and solid aerosols. In the THS, Titan's chemistry is simulated by pulsed plasma in the stream of a supersonic expansion, at Titan-like temperature (200 K). The residence time of the gas in the pulsed plasma discharge is ~3 µs, hence the chemistry is truncated allowing us to probe the first and intermediate steps of the chemistry, by adding heavier precursors into the initial N2-CH4 gas mixture. Experiments have been performed in different gas mixtures from the simpler N2-CH4 (98:2 and 95:5), to more complex mixtures: N2-CH4-C2H2 (91:5:4 and 94.5:5:0.5), N2-CH4-C6H6 (90:5:5) and N2-CH4-C2H2-C6H6 (86:5:4:5). Both the gas and solid phases have been analyzed using a combination of in situ and ex situ diagnostics.A recent mass spectrometry analysis of the gas phase demonstrated that the THS is a unique tool to monitor the different steps of the N2-CH4 chemistry [1]. The results of the solid phase study are consistent with the chemical growth evolution observed in the gas phase. The solid phase products are in the form of grains produced in volume and not from interaction on the substrate's surface. Scanning Electron Microscopy images have shown that more complex mixtures produce larger aggregates (100-500 nm in N2-CH4, up to 5 µm in N2-CH4-C2H2-C6H6). Moreover, the morphology of the grains seems to depend on the precursors, a finding that could have an impact on Titan haze microphysical models. We will present the latest results of the infrared and x-ray absorption near edge structure spectroscopic measurements that have been performed on all four mixtures. These results provide information on the nature of the different functional groups present in our samples as

  3. Characterization of Functionalized Self-Assembled Monolayers and Surface-Attached Interlocking Molecules Using Near-Edge X-ray Absorption Fine Structure Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Willey, Trevor M. [Univ. of California, Davis, CA (United States)

    2004-04-01

    Quantitative knowledge of the fundamental structure and substrate binding, as well as the direct measurement of conformational changes, are essential to the development of self-assembled monolayers (SAMs) and surface-attached interlocking molecules, catenanes and rotaxanes. These monolayers are vital to development of nano-mechanical, molecular electronic, and biological/chemical sensor applications. This dissertation investigates properties of functionalized SAMs in sulfur-gold based adsorbed molecular monolayers using quantitative spectroscopic techniques including near-edge x-ray absorption fine structure spectroscopy (NEXAFS) and x-ray photoelectron spectroscopy (XPS). The stability of the gold-thiolate interface is addressed. A simple model SAM consisting of dodecanethiol adsorbed on Au(111) degrades significantly in less than 24 hours under ambient laboratory air. S 2p and O 1s XPS show the gold-bound thiolates oxidize to sulfinates and sulfonates. A reduction of organic material on the surface and a decrease in order are observed as the layer degrades. The effect of the carboxyl vs. carboxylate functionalization on SAM structure is investigated. Carboxyl-terminated layers consisting of long alkyl-chain thiols vs. thioctic acid with short, sterically separated, alkyl groups are compared and contrasted. NEXAFS shows a conformational change, or chemical switchability, with carboxyl groups tilted over and carboxylate endgroups more upright. Surface-attached loops and simple surface-attached rotaxanes are quantitatively characterized, and preparation conditions that lead to desired films are outlined. A dithiol is often insufficient to form a molecular species bound at each end to the substrate, while a structurally related disulfide-containing polymer yields surface-attached loops. Similarly, spectroscopic techniques show the successful production of a simple, surface-attached rotaxane that requires a ''molecular riveting'' step to hold the

  4. Demonstration of enhanced iodine K-edge imaging using an energy-dispersive X-ray computed tomography system with a 25 mm/s-scan linear cadmium telluride detector and a single comparator

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Eiichi, E-mail: dresato@iwate-med.ac.jp [Department of Physics, Iwate Medical University, 2-1-1 Nishitokuta, Yahaba, Iwate 028-3694 (Japan); Oda, Yasuyuki [Department of Physics, Iwate Medical University, 2-1-1 Nishitokuta, Yahaba, Iwate 028-3694 (Japan); Abudurexiti, Abulajiang [Faculty of Software and Information Science, Iwate Prefectural University, 152-52 Sugo, Takizawa, Iwate 020-0193 (Japan); Hagiwara, Osahiko; Matsukiyo, Hiroshi; Osawa, Akihiro; Enomoto, Toshiyuki; Watanabe, Manabu; Kusachi, Shinya [3rd Department of Surgery, Toho University School of Medicine, 2-17-6 Ohashi, Meguro-ku, Tokyo 153-8515 (Japan); Sato, Shigehiro [Department of Microbiology, School of Medicine, Iwate Medical University, 19-1 Uchimaru, Morioka, Iwate 020-0023 (Japan); Ogawa, Akira [Department of Neurosurgery, School of Medicine, Iwate Medical University, 19-1 Uchimaru, Morioka, Iwate 020-0023 (Japan); Onagawa, Jun [Department of Electronics, Faculty of Engineering, Tohoku Gakuin University, 1-13-1 Chuo, Tagajo, Miyagi 985-8537 (Japan)

    2012-05-15

    An energy-dispersive (ED) X-ray computed tomography (CT) system is useful for carrying out monochromatic imaging. To perform enhanced iodine K-edge CT, we developed an oscillation linear cadmium telluride (CdTe) detector with a scan velocity of 25 mm/s and an energy resolution of 1.2 keV. CT is performed by repeated linear scans and rotations of an object. Penetrating X-ray photons from the object are detected by the CdTe detector, and event signals of X-ray photons are produced using charge-sensitive and shaping amplifiers. The lower photon energy is determined by a comparator device, and the maximum photon energy of 60 keV corresponds to the tube voltage. Rectangular-shaped comparator outputs are counted by a counter card. In the ED-CT, tube voltage and current were 60 kV and 0.30 mA, respectively, and X-ray intensity was 14.8 {mu}Gy/s at 1.0 m from the source at a tube voltage of 60 kV. Demonstration of enhanced iodine K-edge X-ray CT for cancer diagnosis was carried out by selecting photons with energies ranging from 34 to 60 keV. - Highlights: Black-Right-Pointing-Pointer We developed an energy-dispersive X-ray CT system with a 25 mm/s-scan CdTe detector. Black-Right-Pointing-Pointer CT is performed by repeated linear scans and rotations of an object. Black-Right-Pointing-Pointer Lower photon energy is determined by a comparator device. Black-Right-Pointing-Pointer Spatial resolutions were 0.5 Multiplication-Sign 0.5 mm{sup 2}. Black-Right-Pointing-Pointer Iodine K-edge CT was carried out by selecting photons from 34 to 60 keV.

  5. Observation of the surface 4f state of CePd{sub 7} by means of the resonant-inverse-photoemission study at the Ce 4d absorption edge

    Energy Technology Data Exchange (ETDEWEB)

    Kanai, K.; Tezuka, Y.; Fujisawa, M.; Harada, Y.; Shin, S. [Synchrotron Radiation Laboratory, Institute for Solid State Physics, University of Tokyo, Tanashi, Tokyo 188 (Japan); Schmerber, G.; Kappler, J.P.; Parlebas, J.C. [IPCMS-GEMME (UMR 46 CNR), Universite Louis Pasteur, 23, rue du Loess, 67037 Strasbourg (France); Kotani, A. [Institute for Solid State Physics, University of Tokyo, 7-22-1 Roppongi, Minato-ku, Tokyo 106 (Japan)

    1997-01-01

    The resonant inverse photoemission study (RIPES) of CePd{sub 7}, has been carried out at the Ce 4d{r_arrow}4f absorption edge. The strong resonant enhancement of the 4f cross section enables us to distinguish two 4f components in the empty electronic state near the Fermi level. The incidence-angle dependence of the RIPES indicates a clear difference between ground-state configurations at the bulk and surface. It is found that the former shows a strongly hybridized 4f state, while the latter shows a localized 4f character. The angle dependence of the RIPES of {alpha}-Ce metal has been also carried out and similar results as those of CePd{sub 7} were obtained. The RIPES at the Ce 4d{r_arrow}4f edge is found to be a powerful method to investigate the surface 4f state. {copyright} {ital 1997} {ital The American Physical Society}

  6. Heterogeneous mixed valence in YbPd sub 3 S sub 4 : evidence from sup 1 sup 7 sup 0 Yb Moessbauer and x-ray L sub I sub I sub I -edge absorption measurements

    CERN Document Server

    Bonville, P; Alleno, E; Takahashi, F; Matsuoka, E; Ishikawa, M

    2003-01-01

    The intermetallic bronze YbPd sub 3 S sub 4 is shown to be a heterogeneous mixed-valence system, by means of sup 1 sup 7 sup 0 Yb Moessbauer spectroscopy and x-ray L sub I sub I sub I -edge absorption and magnetic measurements. Two valence states coexist in this compound: Yb sup 3 sup + and close-to-divalent Yb. The trivalent fraction (about 50%) undergoes a transition to magnetic ordering at about 2 K, with the GAMMA sub 7 doublet as the ground crystal field state. The possibility of charge (or valence) ordering is discussed. (letter to the editor)

  7. Image edge detection based on adaptive weighted morphology

    Institute of Scientific and Technical Information of China (English)

    Lihui Jiang; Yanying Guo

    2007-01-01

    A novel morphological edge detector based on adaptive weighted morphological operators is presented. It judges image edge and direction by adaptive weighted morphological structuring elements (SEs). If the edge direction exists, a big weight factor in SE is put; if it does not exist, a small weight factor in SE is put. Thus we can achieve an intensified edge detector. Experimental results prove that the new operator's performance dominates those of classical operators for images in edge detection, and obtains superbly detail edges.

  8. Diurnal Variation and Spatial Distribution Effects on Sulfur Speciation in Aerosol Samples as Assessed by X-Ray Absorption Near-Edge Structure (XANES

    Directory of Open Access Journals (Sweden)

    Siwatt Pongpiachan

    2012-01-01

    Full Text Available This paper focuses on providing new results relating to the impacts of Diurnal variation, Vertical distribution, and Emission source on sulfur K-edge XANES spectrum of aerosol samples. All aerosol samples used in the diurnal variation experiment were preserved using anoxic preservation stainless cylinders (APSCs and pressure-controlled glove boxes (PCGBs, which were specially designed to prevent oxidation of the sulfur states in PM10. Further investigation of sulfur K-edge XANES spectra revealed that PM10 samples were dominated by S(VI, even when preserved in anoxic conditions. The “Emission source effect” on the sulfur oxidation state of PM10 was examined by comparing sulfur K-edge XANES spectra collected from various emission sources in southern Thailand, while “Vertical distribution effects” on the sulfur oxidation state of PM10 were made with samples collected from three different altitudes from rooftops of the highest buildings in three major cities in Thailand. The analytical results have demonstrated that neither “Emission source” nor “Vertical distribution” appreciably contribute to the characteristic fingerprint of sulfur K-edge XANES spectrum in PM10.

  9. L-Edge X-ray Absorption Spectroscopy of Dilute Systems Relevant to Metalloproteins Using an X-ray Free-Electron Laser

    NARCIS (Netherlands)

    Mitzner, Rolf; Rehanek, Jens; Kern, Jan; Gul, Sheraz; Hattne, Johan; Taguchi, Taketo; Alonso-Mori, Roberto; Tran, Rosalie; Weniger, Christian; Schroeder, Henning; Quevedo, Wilson; Laksmono, Hartawan; Sierra, Raymond G.; Han, Guangye; Lassalle-Kaiser, Benedikt; Koroidov, Sergey; Kubicek, Katharina; Schreck, Simon; Kunnus, Kristjan; Brzhezinskaya, Maria; Firsov, Alexander; Minitti, Michael P.; Turner, Joshua J.; Moeller, Stefan; Sauter, Nicholas K.; Bogan, Michael J.; Nordlund, Dennis; Schlotter, William F.; Messinger, Johannes; Borovik, Andrew; Techert, Simone; de Groot, Frank M. F.; Foehlisch, Alexander; Erko, Alexei; Bergmann, Uwe; Yachandra, Vittal K.; Wernet, Philippe; Yano, Junko

    2013-01-01

    L-edge spectroscopy of 3d transition metals provides important electronic structure information and has been used in many fields. However, the use of this method for studying dilute aqueous systems, such as metalloenzymes, has not been prevalent because of severe radiation damage and the lack of sui

  10. Edge detection based on morphological amoebas

    CERN Document Server

    Lee, Won Yeol; Kim, Se Yun; Lim, Jae Young; Lim, Dong Hoon

    2011-01-01

    Detecting the edges of objects within images is critical for quality image processing. We present an edge-detecting technique that uses morphological amoebas that adjust their shape based on variation in image contours. We evaluate the method both quantitatively and qualitatively for edge detection of images, and compare it to classic morphological methods. Our amoeba-based edge-detection system performed better than the classic edge detectors.

  11. Edgeless silicon pad detectors

    Science.gov (United States)

    Perea Solano, B.; Abreu, M. C.; Avati, V.; Boccali, T.; Boccone, V.; Bozzo, M.; Capra, R.; Casagrande, L.; Chen, W.; Eggert, K.; Heijne, E.; Klauke, S.; Li, Z.; Mäki, T.; Mirabito, L.; Morelli, A.; Niinikoski, T. O.; Oljemark, F.; Palmieri, V. G.; Rato Mendes, P.; Rodrigues, S.; Siegrist, P.; Silvestris, L.; Sousa, P.; Tapprogge, S.; Trocmé, B.

    2006-05-01

    We report measurements in a high-energy pion beam of the sensitivity of the edge region in "edgeless" planar silicon pad diode detectors diced through their contact implants. A large surface current on such an edge prevents the normal reverse biasing of the device, but the current can be sufficiently reduced by the use of a suitable cutting method, followed by edge treatment, and by operating the detector at low temperature. The depth of the dead layer at the diced edge is measured to be (12.5±8 stat..±6 syst.) μm.

  12. Edgeless silicon pad detectors

    Energy Technology Data Exchange (ETDEWEB)

    Perea Solano, B. [CERN, CH-1211 Geneva 23 (Switzerland)]. E-mail: blanca.perea.solano@cern.ch; Abreu, M.C. [LIP and University of Algarve, 8000 Faro (Portugal); Avati, V. [CERN, CH-1211 Geneva 23 (Switzerland); Boccali, T. [INFN Sez. di Pisa and Scuola Normale Superiore, Pisa (Italy); Boccone, V. [INFN Sez. di Genova and Universita di Genova, Genoa (Italy); Bozzo, M. [INFN Sez. di Genova and Universita di Genova, Genoa (Italy); Capra, R. [INFN Sez. di Genova and Universita di Genova, Genoa (Italy); Casagrande, L. [INFN Sez. di Roma 2 and Universita di Roma 2, Rome (Italy); Chen, W. [Brookhaven National Laboratory, Upton, NY 11973-5000 (United States); Eggert, K. [CERN, CH-1211 Geneva 23 (Switzerland); Heijne, E. [CERN, CH-1211 Geneva 23 (Switzerland); Klauke, S. [CERN, CH-1211 Geneva 23 (Switzerland); Li, Z. [Brookhaven National Laboratory, Upton, NY 11973-5000 (United States); Maeki, T. [Helsinki Institute of Physics, Helsinki (Finland); Mirabito, L. [CERN, CH-1211 Geneva 23 (Switzerland); Morelli, A. [INFN Sez. di Genova and Universita di Genova, Genoa (Italy); Niinikoski, T.O. [CERN, CH-1211 Geneva 23 (Switzerland); Oljemark, F. [Helsinki Institute of Physics, Helsinki (Finland); Palmieri, V.G. [Helsinki Institute of Physics, Helsinki (Finland); Rato Mendes, P. [LIP and University of Algarve, 8000 Faro (Portugal); Rodrigues, S. [LIP and University of Algarve, 8000 Faro (Portugal); Siegrist, P. [CERN, CH-1211 Geneva 23 (Switzerland); Silvestris, L. [INFN Sez. Di Bari, Bari (Italy); Sousa, P. [LIP and University of Algarve, 8000 Faro (Portugal); Tapprogge, S. [Helsinki Institute of Physics, Helsinki (Finland); Trocme, B. [Institut de Physique Nucleaire, Villeurbanne (France)

    2006-05-01

    We report measurements in a high-energy pion beam of the sensitivity of the edge region in 'edgeless' planar silicon pad diode detectors diced through their contact implants. A large surface current on such an edge prevents the normal reverse biasing of the device, but the current can be sufficiently reduced by the use of a suitable cutting method, followed by edge treatment, and by operating the detector at low temperature. The depth of the dead layer at the diced edge is measured to be (12.5{+-}8{sub stat.}.{+-}6{sub syst.}) {mu}m.

  13. Element distribution and iron speciation in mature wheat grains (Triticum aestivum L.) using synchrotron X-ray fluorescence microscopy mapping and X-ray absorption near-edge structure (XANES) imaging.

    Science.gov (United States)

    De Brier, Niels; Gomand, Sara V; Donner, Erica; Paterson, David; Smolders, Erik; Delcour, Jan A; Lombi, Enzo

    2016-08-01

    Several studies have suggested that the majority of iron (Fe) and zinc (Zn) in wheat grains are associated with phytate, but a nuanced approach to unravel important tissue-level variation in element speciation within the grain is lacking. Here, we present spatially resolved Fe-speciation data obtained directly from different grain tissues using the newly developed synchrotron-based technique of X-ray absorption near-edge spectroscopy imaging, coupling this with high-definition μ-X-ray fluorescence microscopy to map the co-localization of essential elements. In the aleurone, phosphorus (P) is co-localized with Fe and Zn, and X-ray absorption near-edge structure imaging confirmed that Fe is chelated by phytate in this tissue layer. In the crease tissues, Zn is also positively related to P distribution, albeit less so than in the aleurone. Speciation analysis suggests that Fe is bound to nicotianamine rather than phytate in the nucellar projection, and that more complex Fe structures may also be present. In the embryo, high Zn concentrations are present in the root and shoot primordium, co-occurring with sulfur and presumably bound to thiol groups. Overall, Fe is mainly concentrated in the scutellum and co-localized with P. This high resolution imaging and speciation analysis reveals the complexity of the physiological processes responsible for element accumulation and bioaccessibility.

  14. Characterization of local chemistry and disorder in synthetic and natural {alpha}-Al{sub 2}O{sub 3} materials by X-ray absorption near edge structure spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Mottana, A. [Rome, Univ. `Roma Tre` (Italy). Dip. di Scienze Geologiche]|[INFN, Laboratori Nazionali di Frascati, Rome (Italy); Murata, T. [Kyoto, Univ. of Education (Japan). Dept. of Physics; Marcelli, A. [INFN, Laboratori Nazionali di Frascati, Rome (Italy)] [and others

    1997-11-01

    X-ray absorption fine spectra at the Al K-edge were measured experimentally on and calculated theoretically via the multiple-scattering formalism for a chemically pure and physically perfect synthetic {alpha}-Al{sub 2}O{sub 3} ({alpha}-alumina), a natural `ruby/sapphire` (corundum) and a series of artificial `corundum` produced for technical purposes and used as geochemical standards. The Al K-edge spectra differ despite of the identical coordination (short-range arrangement) assumed by O around Al, and vary slightly in relation to the slightly different chemistries of the materials (substitutional defects) as well as on account of the location taken by foreign atoms in the structural lattices (positional defects). A quantitative treatment of the observed changes is made in terms of short-range modification of the coordination polyhedron and of medium- to long-range modifications in the overall structure; both of them induced by substitutions. In some technical `corundums`, the impurities of admixed `{beta}-alumina`, where Al is both in four- and six-fold coordination, produce another small but detectable effect on Al K-edges. Therefore, XAFS spectroscopy proves its potentials for both measuring a light element such as Al, and detecting minor coordination changes and substitutions (ca. 1{approx}3 wt.% as oxide) of the absorber by dilute other atoms, at least under favorable conditions as those occurring in this system are.

  15. [Effect of Long-Term Fertilization on Organic Nitrogen Functional Groups in Black Soil as Revealed by Synchrotron-Based X-Ray Absorption Near-Edge Structure Spectroscopy].

    Science.gov (United States)

    Li, Hui; Gao, Qiang; Wang, Shuai; Zhu, Ping; Zhang, Jin-jing; Zhao, Yi-dong

    2015-07-01

    Nitrogen (N) is a common limiting nutrient in crop production. The N content of soil has been used as an important soil fertility index. Organic N is the major form of N in soil. In most agricultural surface soils, more than 90% of total N occurs in organic forms. Therefore, understanding the compositional characteristics of soil organic N functional groups can provide the scientific basis for formulating the reasonable farmland management strategies. Synchrotron radiation soft X-ray absorption near-edge structure (N K-edge XANES) spectroscopy is the most powerful tool to characterize in situ organic N functional groups compositions in soil. However, to our most knowledge, no studies have been conducted to examine the organic N functional groups compositions of soil using N K-edge XANES spectroscopy under long-term fertilization practices. Based on a long-term field experiment (started in 1990) in a black soil (Gongzhuling, Northeast China), we investigated the differences in organic N functional groups compositions in bulk soil and clay-size soil fraction among fertilization patterns using synchrotron-based N K- edge XANES spectroscopy. Composite soil samples (0-20 cm) were collected in 2008. The present study included six treatments: farmland fallow (FALL), no-fertilization control (CK), chemical nitrogen, phosphorus, and potassium fertilization (NPK), NPK in combination with organic manure (NPKM), 1.5 times of NPKM (1.5 NPKM), and NPK in combination with maize straw (NPKS). The results showed that N K-edge XANES spectra of all the treatments under study exhibited characteristic absorption peaks in the ranges of 401.2-401.6 and 402.7-403.1 eV, which were assigned as amides/amine-N and pyrrole-N, respectively. These characteristic absorption peaks were more obvious in clay-size soil fraction than in bulk soil. The results obtained from the semi-quantitative analysis of N K-edge XANES spectra indicated that the relative proportion of amides/amine-N was the highest

  16. Multiplet calculations of L2,3 x-ray absorption near-edge structures for 3d transition-metal compounds

    NARCIS (Netherlands)

    de Groot, F.M.F.; Ikeno, H.; Stavitski, E.; Tanaka, I.

    2009-01-01

    The purpose of this work is to compare the two different procedures to calculate the L2,3 x-ray absorption spectra of transition-metal compounds: (1) the semi-empirical charge transfer multiplet (CTM) approach and (2) the ab initio configuration-interaction (CI) method based on molecular orbitals.

  17. Nb K-edge x-ray absorption investigation of the pressure induced amorphization in A-site deficient double perovskite La1/3NbO3.

    Science.gov (United States)

    Marini, C; Noked, O; Kantor, I; Joseph, B; Mathon, O; Shuker, R; Kennedy, B J; Pascarelli, S; Sterer, E

    2016-02-03

    Nb K-edge x-ray absorption spectroscopy is utilized to investigate the changes in the local structure of the A-site deficient double perovskite La1/3NbO3 which undergoes a pressure induced irreversible amorphization. EXAFS results show that with increasing pressure up to 7.5 GPa, the average Nb-O bond distance decreases in agreement with the expected compression and tilting of the NbO6 octahedra. On the contrary, above 7.5 GPa, the average Nb-O bond distance show a tendency to increase. Significant changes in the Nb K-edge XANES spectrum with evident low energy shift of the pre-peak and the absorption edge is found to happen in La1/3NbO3 above 6.3 GPa. These changes evidence a gradual reduction of the Nb cations from Nb(5+) towards Nb(4+) above 6.3 GPa. Such a valence change accompanied by the elongation of the average Nb-O bond distances in the octahedra, introduces repulsion forces between non-bonding adjacent oxygen anions in the unoccupied A-sites. Above a critical pressure, the Nb reduction mechanism can no longer be sustained by the changing local structure and amorphization occurs, apparently due to the build-up of local strain. EXAFS and XANES results indicate two distinct pressure regimes having different local and electronic response in the La1/3NbO3 system before the occurence of the pressure induced amorphization at  ∼14.5 GPa.

  18. Characterization of an in-vacuum PILATUS 1M detector

    CERN Document Server

    Wernecke, Jan; Müller, Peter; Krumrey, Michael

    2013-01-01

    A dedicated in-vacuum X-ray detector based on the hybrid-pixel PILATUS 1M detector has been installed at the four-crystal monochromator beamline of PTB at the electron storage ring BESSY II in Berlin. Due to its windowless operation, the detector can be used in the entire photon energy range of the beamline from from 10 keV down to 1.75 keV for small-angle X-ray scattering (SAXS) experiments and anomalous SAXS (ASAXS) at absorption edges of light elements. The radiometric and geometric properties of the detector like quantum efficiency, pixel pitch and module alignment have been determined with low uncertainties. First grazing incidence SAXS (GISAXS) results demonstrate the superior resolution in momentum transfer achievable at low photon energies.

  19. Probing cation antisite disorder in Gd2 Ti2 O7 pyrochlore by site-specific near-edge x-ray-absorption fine structure and x-ray photoelectron spectroscopy

    Science.gov (United States)

    Nachimuthu, P.; Thevuthasan, S.; Engelhard, M. H.; Weber, W. J.; Shuh, D. K.; Hamdan, N. M.; Mun, B. S.; Adams, E. M.; McCready, D. E.; Shutthanandan, V.; Lindle, D. W.; Balakrishnan, G.; Paul, D. M.; Gullikson, E. M.; Perera, R. C. C.; Lian, J.; Wang, L. M.; Ewing, R. C.

    2004-09-01

    Disorder in Gd2Ti2O7 is investigated by near-edge x-ray-absorption fine structure (NEXAFS) and x-ray photoelectron spectroscopy (XPS). NEXAFS shows Ti4+ ions occupy octahedral sites with a tetragonal distortion induced by vacant oxygen sites. O1s XPS spectra obtained with a charge neutralization system from Gd2Ti2O7(100) and the Gd2Ti2O7 pyrochlore used by Chen [Phys. Rev. Lett. 88, 105901 (2002)], both yielded a single peak, unlike the previous result on the latter that found two peaks. The current results give no evidence for an anisotropic distribution of Ti and O. The extra features reported in the aforementioned communication resulted from charging effects and incomplete surface cleaning. Thus, a result confirming the direct observation of simultaneous cation-anion antisite disordering and lending credence to the split vacancy model has been clarified.

  20. K- and L-edge X-ray absorption spectrum calculations of closed-shell carbon, silicon, germanium, and sulfur compounds using damped four-component density functional response theory.

    Science.gov (United States)

    Fransson, Thomas; Burdakova, Daria; Norman, Patrick

    2016-05-21

    X-ray absorption spectra of carbon, silicon, germanium, and sulfur compounds have been investigated by means of damped four-component density functional response theory. It is demonstrated that a reliable description of relativistic effects is obtained at both K- and L-edges. Notably, an excellent agreement with experimental results is obtained for L2,3-spectra-with spin-orbit effects well accounted for-also in cases when the experimental intensity ratio deviates from the statistical one of 2 : 1. The theoretical results are consistent with calculations using standard response theory as well as recently reported real-time propagation methods in time-dependent density functional theory, and the virtues of different approaches are discussed. As compared to silane and silicon tetrachloride, an anomalous error in the absolute energy is reported for the L2,3-spectrum of silicon tetrafluoride, amounting to an additional spectral shift of ∼1 eV. This anomaly is also observed for other exchange-correlation functionals, but it is seen neither at other silicon edges nor at the carbon K-edge of fluorine derivatives of ethene. Considering the series of molecules SiH4-XFX with X = 1, 2, 3, 4, a gradual divergence from interpolated experimental ionization potentials is observed at the level of Kohn-Sham density functional theory (DFT), and to a smaller extent with the use of Hartree-Fock. This anomalous error is thus attributed partly to difficulties in correctly emulating the electronic structure effects imposed by the very electronegative fluorines, and partly due to inconsistencies in the spurious electron self-repulsion in DFT. Substitution with one, or possibly two, fluorine atoms is estimated to yield small enough errors to allow for reliable interpretations and predictions of L2,3-spectra of more complex and extended silicon-based systems.

  1. Surface and in-depth characterization of lithium-ion battery cathodes at different cycle states using confocal micro-X-ray fluorescence-X-ray absorption near edge structure analysis

    Energy Technology Data Exchange (ETDEWEB)

    Menzel, Magnus; Schlifke, Annalena [Institut für Anorganische und Angewandte Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany); Falk, Mareike; Janek, Jürgen [Physikalisch-Chemisches Institut, Justus-Liebig-Universität Gießen, Heinrich-Buff-Ring 58, 35392 Gießen (Germany); Fröba, Michael, E-mail: froeba@chemie.uni-hamburg.de [Institut für Anorganische und Angewandte Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany); Fittschen, Ursula Elisabeth Adriane, E-mail: ursula.fittschen@chemie.uni-hamburg.de [Institut für Anorganische und Angewandte Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany)

    2013-07-01

    The cathode material LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} for lithium-ion batteries has been studied with confocal micro-X-ray fluorescence (CMXRF) combined with X-ray absorption near edge structure (XANES) at the Mn-K edge and the Ni-K edge. This technique allows for a non-destructive, spatially resolved (x, y and z) investigation of the oxidation states of surface areas and to some extent of deeper layers of the electrode. Until now CMXRF-XANES has been applied to a limited number of applications, mainly geo-science. Here, we introduce this technique to material science applications and show its performance to study a part of a working system. A novel mesoporous LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} material was cycled (charged and discharged) to investigate the effects on the oxidation states at the cathode/electrolyte interface. With this approach the degradation of Mn{sup 3+} to Mn{sup 4+} only observable at the surface of the electrode could be directly shown. The spatially resolved non-destructive analysis provides knowledge helpful for further understanding of deterioration and the development of high voltage battery materials, because of its nondestructive nature it will be also suitable to monitor processes during battery cycling. - Highlights: • The potential of confocal micro-XRF-XANES for spatial resolved species analysis in a part of a working system is shown. • The spatial resolution enables differentiation of the oxidized interface from deeper layers. • With the analytical technique confocal micro-XRF-XANES 3D in-situ analyses of working systems are feasible. • The multidimensional and nondestructive analysis of Li-ion battery cathodes is shown. • The analysis will allow for a deeper understanding of processes at interfaces in battery science and others.

  2. Theoretical and experimental study of high-magnetic-field XMCD spectra at the L2,3 absorption edges of mixed-valence rare-earth compounds

    Science.gov (United States)

    Kotani, Akio; Matsuda, Yasuhiro H.; Nojiri, Hiroyuki

    2009-11-01

    X-ray magnetic circular dichroism(XMCD) spectra at the L2,3 edges of mixed-valence rare-earth compounds in high magnetic fields are studied both theoretically and experimentally. The theoretical study is based on a new framework proposed recently by Kotani. The Zeeman splitting of 4f states, the mixed-valence character of 4f states, and the 4f-5d exchange interaction are incorporated into a single impurity Anderson model. New XMCD experiments in high magnetic fields up to 40 T are carried out for the mixed-valence compounds EuNi2(Si0.18Ge0.82)2 and YbInCu4 by using a miniature pulsed magnet, which was developed recently by Matsuda et al. The XMCD data are taken at 5 K by transmission measurements for incident X-rays with ± helicities at BL39XU in SPring-8. After giving a survey on recent developments in the theory of XMCD spectra for mixed-valence Ce and Yb compounds, we calculate the XMCD spectra of YbInCu4 at the field-induced valence transition around 32 T by applying the recent theoretical framework and by newly introducing at 32 T a discontinuous change in the Yb 4f level and that in the hybridization strength between the Yb 4f and conduction electrons. The calculated results are compared with the experimental ones.

  3. [Distribution and speciation of Pb in Arabidopsis thaliana shoot and rhizosphere soil by in situ synchrotron radiation micro X-ray fluorescence and X-ray absorption near edge structure].

    Science.gov (United States)

    Shen, Ya-Ting

    2014-03-01

    In order to investigate plant reacting mechanism with heavy metal stress in organ and tissue level, synchrotron radiation micro X-ray fluorescence (micro-SRXRF) was used to determine element distribution characteristics of K, Ca, Mn, Fe, Cu, Zn, Pb in an Arabidopsis thaliana seedling grown in tailing dam soil taken from a lead-zinc mine exploration area. The results showed a regular distribution characters of K, Ca, Fe, Cu and Zn, while Pb appeared not only in root, but also in a leaf bud which was beyond previously understanding that Pb mainly appeared in plant root. Pb competed with Mn in the distribution of the whole seedling. Pb may cause the increase of oxidative stress in root and leaf bud, and restrict Mn absorption and utilization which explained the phenomenon of seedling death in this tailing damp soil. Speciation of Pb in Arabidopsis thaliana and tailing damp rhizosphere soil were also presented after using PbL3 micro X-ray absorption near edge structure (micro-XANES). By comparison of PbL3 XANES peak shape and peak position between standard samples and rhizosphere soil sample, it was demonstrated that the tailing damp soil was mainly formed by amorphous forms like PbO (64.2%), Pb (OH)2 (28.8%) and Pb3O4 (6.3%) rather than mineral or organic Pb speciations. The low plant bioavailability of Pb demonstrated a further research focusing on Pb absorption and speciation conversion is needed, especially the role of dissolve organic matter in soil which may enhance Pb bioavailability.

  4. X-ray absorption near-edge structure of chromium ions in {alpha}-Al{sub 2}O{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Wongkokua, W; Pongkrapan, S; Dararutana, P; Wathanakul, P [Gemmology and Mineral Sciences Special Research Unit, Faculty of Science, Kasetsart University, Bangkok 10900 (Thailand); T-Thienprasert, J, E-mail: pwathanakul@gmail.co [School of Physics, Suranaree University of Technology, Nakorn-Ratchasima 30000 (Thailand)

    2009-09-01

    Both synthetic and natural {alpha}-Al{sub 2}O{sub 3} samples with different Cr concentrations were investigated by XANES. The Cr contents were analyzed using LA-ICP-MS technique prior to this experiment. XANES spectra combined with first principle calculations showed the transformation from {alpha}-Al{sub 2}O{sub 3}:Cr{sup 3+} to {alpha}-Al{sub 2}O{sub 3}:Cr{sup 3+},Cr{sup 3+} or {alpha}-Cr{sub 2}O{sub 3} as the Cr-Cr content increased. The absorption transformation could be resulted from the change of environment around Cr{sup 3+} ions, i.e., the Al-O-Cr bonds decreased while the Cr-O-Cr bonds increased. Significant differences in XANES line shapes observed for synthetic and natural {alpha}-Al{sub 2}O{sub 3} samples suggested the differences in local environments around Cr ions in both samples. The XANES line shape of {alpha}-Al{sub 2}O{sub 3}:Cr{sup 3+},Cr{sup 3+} or Cr ion pairs corresponded to the Cr content, which was also confirmed by the intensity ratios between N{sub 2}-line and sideband S of R-lines of photoluminescence spectra.

  5. Vlsi Implementation of Edge Detection for Images

    Directory of Open Access Journals (Sweden)

    T. Mahalakshmi

    2012-12-01

    Full Text Available Edge is the boundary between the image and its background. Edge detection in general is defined as the local maxima obtained from high pass filters, but an optimized edge detector should mark the edges with respect to luminance or brightness changes. It is easy to obtain them in software implementation but for hardware implementation there is an issue with percentage of accuracy and processing time. This study discusses various edge detection algorithms and proposes an optimized edge detector which provides the solution for mentioned above issue. Since FPGA provides practical solutions for most of the image processing problems, the proposed architecture has been developed using Matlab System generator. Experimental results show the accuracy of edge detected using proposed architecture.

  6. A Vacuum Ultraviolet Absorption Array Spectrometer as a Selective Detector for Comprehensive Two-Dimensional Gas Chromatography: Concept and First Results.

    Science.gov (United States)

    Gröger, Thomas; Gruber, Beate; Harrison, Dale; Saraji-Bozorgzad, Mohammad; Mthembu, Makhosazana; Sutherland, Aimée; Zimmermann, Ralf

    2016-03-15

    Fast and selective detectors are very interesting for comprehensive two-dimensional gas chromatography (GC × GC). This is particularly true if the detector system can provide additional spectroscopic information on the compound structure and/or functionality. Other than mass spectrometry (MS), only optical spectroscopic detectors are able to provide selective spectral information. However, until present the application of optical spectroscopy technologies as universal detectors for GC × GC has been restricted mainly due to physical limitations such as insufficient acquisition speed or high detection limits. A recently developed simultaneous-detection spectrometer working in the vacuum ultraviolet (VUV) region of 125-240 nm overcomes these limitations and meets all the criteria of a universal detector for GC × GC. Peak shape and chromatographic resolution is preserved and unique spectral information, complementary to mass spectrometry data, is gained. The power of this detector is quickly recognized as it has the ability to discriminate between isomeric compounds or difficult to separate structurally related isobaric species; thus, it provides additional selectivity. A further promising feature of this detector is the data analysis concept of spectral filtering, which is accomplished by targeting special electronic transitions that allows for a fast screening of GC × GC chromatograms for designated compound classes.

  7. Evaluating Edge Detection through Boundary Detection

    Directory of Open Access Journals (Sweden)

    Wang Song

    2006-01-01

    Full Text Available Edge detection has been widely used in computer vision and image processing. However, the performance evaluation of the edge-detection results is still a challenging problem. A major dilemma in edge-detection evaluation is the difficulty to balance the objectivity and generality: a general-purpose edge-detection evaluation independent of specific applications is usually not well defined, while an evaluation on a specific application has weak generality. Aiming at addressing this dilemma, this paper presents new evaluation methodology and a framework in which edge detection is evaluated through boundary detection, that is, the likelihood of retrieving the full object boundaries from this edge-detection output. Such a likelihood, we believe, reflects the performance of edge detection in many applications since boundary detection is the direct and natural goal of edge detection. In this framework, we use the newly developed ratio-contour algorithm to group the detected edges into closed boundaries. We also collect a large data set ( of real images with unambiguous ground-truth boundaries for evaluation. Five edge detectors (Sobel, LoG, Canny, Rothwell, and Edison are evaluated in this paper and we find that the current edge-detection performance still has scope for improvement by choosing appropriate detectors and detector parameters.

  8. Edge detection of remote sensing image based on nonlinear intensity of curved surface

    Institute of Scientific and Technical Information of China (English)

    张连蓬; 刘国林; 江涛

    2003-01-01

    A new edge detector based on the nonlinear intensity of curved surface was proposed. The edge detector describes the largest curvature and the smallest curvature of curved surface, therefore it can reflect the real largest direction of image edge jump. By the new edge detector, it is convenient to calculate the curvature in any direction of the curved surface and the curvature can be used in the identification of edge direction and the feature extraction of objects on remote sensing image.

  9. X-ray relative intensities at incident photon energies across the L{sub i} (i=1–3) absorption edges of elements with 35≤Z≤92

    Energy Technology Data Exchange (ETDEWEB)

    Puri, Sanjiv, E-mail: sanjivpurichd@yahoo.com

    2014-07-15

    The intensity ratios, I{sub Lk}/I{sub Lα1} (k=l,η,α{sub 2},β{sub 1},β{sub 2,15},β{sub 3},β{sub 4},β{sub 5,7},β{sub 6},β{sub 9,10},γ{sub 1,5},γ{sub 6,8},γ{sub 2,3},γ{sub 4}) and I{sub Lj}/I{sub Lα} (j=β,γ), have been evaluated at incident photon energies across the L{sub i} (i=1–3) absorption edge energies of all the elements with 35≤Z≤92. Use is made of what are currently considered to be more reliable theoretical data sets of different physical parameters, namely, the L{sub i} (i=1–3) sub-shell photoionization cross sections based on the relativistic Hartree–Fock–Slater (RHFS) model, the X-ray emission rates based on the Dirac–Fock model, and the fluorescence and Coster–Kronig yields based on the Dirac–Hartree–Slater model. In addition, the Lα{sub 1} X-ray production cross sections for different elements at various incident photon energies have been tabulated so as to facilitate the evaluation of production cross sections for different resolved L X-ray components from the tabulated intensity ratios. Further, to assist evaluation of the prominent (L{sub i}−S{sub j}) (S{sub j}=M{sub j}, N{sub j} and i=1–3, j=1–7) resonant Raman scattered (RRS) peak energies for an element at a given incident photon energy (below the L{sub i} sub-shell absorption edge), the neutral-atom electron binding energies based on the relaxed orbital RHFS calculations are also listed so as to enable identification of the RRS peaks, which can overlap with the fluorescent X-ray lines. -- Highlights: •The L X-ray relative intensities and Lα{sub 1} XRP cross sections are evaluated using physical parameters based on the IPA models. •Comparison of the intensity ratios evaluated using the DHS and DF models based photoionization cross sections is presented. •Importance of many body effects including electron exchange effects is highlighted.

  10. Probing the f-state configuration of URu2Si2 with U LIII-edge resonant x-ray absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Medling, S. A. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Booth, C. H. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Tobin, J. G. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Baumbach, R. E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Bauer, E. D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Sokaras, D. [SLAC National Accelerator Lab., Menlo Park, CA (United States); Nordlund, D. [SLAC National Accelerator Lab., Menlo Park, CA (United States); Weng, T. C. [SLAC National Accelerator Lab., Menlo Park, CA (United States)

    2015-09-05

    It has often been said that the most interesting physics occurs when competing interactions are of nearly the same magnitude. Such a situation is surely occurring at URu2Si2’s so-called “hidden-order transition”, which garners its name from the missing entropy at a 17.5 K phase transition relative to that expected for a conventional antiferromagnetic phase transition, despite the presence of only a very small ordered magnetic moment. Despite this discrepancy being identified in 1985, the identification of the order parameter remains elusive, although progress toward understand- ing this transition has been steady since that time, and URu2Si2 remains an important research subject today. The work described provides measures of the 5f orbital occupancy and itinerancy using resonant x-ray emission spectroscopy (RXES) at the U LIII absorption edge and measuring U Lα1 emission that potentially acts as a dividing line between different classes of “hidden-order” theories.

  11. Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy

    Science.gov (United States)

    Ma, Tianyuan; Xu, Gui-Liang; Zeng, Xiaoqiao; Li, Yan; Ren, Yang; Sun, Chengjun; Heald, Steve M.; Jorne, Jacob; Amine, Khalil; Chen, Zonghai

    2017-02-01

    In situ high energy X-ray diffraction (HEXRD) and in situ X-ray absorption near edge spectroscopy (XANES) were carried out to understand the solid state synthesis of NaxMnO2, with particular interest on the synthesis of P2 type Na2/3MnO2. It was found that there were multi intermediate phases formed before NaMnO2 appeared at about 600 °C. And the final product after cooling process is a combination of O‧3 NaMnO2 with P2 Na2/3MnO2. A P2 type Na2/3MnO2 was synthesized at reduced temperature (600 °C). The influence of Na2CO3 impurity on the electrochemical performance of P2 Na2/3MnO2 was thoroughly investigated in our work. It was found that the content of Na2CO3 can be reduced by optimizing Na2CO3/MnCO3 ratio during the solid state reaction or other post treatment such as washing with water. We expected our results could provide a good guide for future development of high performance cathode materials for sodium-ion batteries.

  12. Local structural studies of the cubic Cd{sub 1-x}Ca{sub x}O system through Cd K-edge extended X-ray absorption spectroscopic studies

    Energy Technology Data Exchange (ETDEWEB)

    Srihari, Velaga [Saha Institute of Nuclear Physics, Kolkata (India). Surface Physics Div.; Sridharan, V.; Sankara Sastry, V.; Sundar, C.S. [Indira Gandhi Centre for Atomic Research, Kalpakkam (India). Materials Science Group; Nomura, Masaharu [High Energy Accelerator Research Organization, Tsukuba (Japan). Photon Factory

    2012-07-15

    Cd K-edge extended X-ray absorption fine-structure spectroscopic studies were carried out on Cd{sub 1-x}Ca{sub x}O (0 {<=} x {<=} 0.9) solid solutions and the first and second nearest neighbour (NN) distances and their mean square relative displacement {sigma}{sup 2} were estimated. The first NN distance, d{sub Cd-O}(x), was found to be smaller than its expected value, a(x)/2, obtained from the X-ray diffraction measurements. It increases monotonically and non-linearly with a negative curvature, comparable with that of the a(x) value variation. The variation {sigma}{sup 2} of the 1NN with x is consistent with a disordered solid solution model. The 2NN distances d{sub Cd-Cd}(x) and d{sub Cd-Ca}(x) are found to follow the average values obtained by X-ray diffraction with d{sub Cd-Ca}(x) > d{sub Cd-Cd}(x). From detailed analysis it is argued that the solid solution exhibits a bimodal distribution of the 1NN distances, d{sub Cd-O}(x) and d{sub Ca-O}(x), and that the system belongs to a persistent type. (orig.)

  13. Structure analyses using X-ray photoelectron spectroscopy and X-ray absorption near edge structure for amorphous MS3 (M: Ti, Mo) electrodes in all-solid-state lithium batteries

    Science.gov (United States)

    Matsuyama, Takuya; Deguchi, Minako; Mitsuhara, Kei; Ohta, Toshiaki; Mori, Takuya; Orikasa, Yuki; Uchimoto, Yoshiharu; Kowada, Yoshiyuki; Hayashi, Akitoshi; Tatsumisago, Masahiro

    2016-05-01

    Electronic structure changes of sulfurs in amorphous TiS3 and MoS3 for positive electrodes of all-solid-state lithium batteries are examined by X-ray photoelectron spectroscopy (XPS) and the X-ray absorption near edge structure (XANES). The all-solid-state cell with amorphous TiS3 electrode shows the reversible capacity of about 510 mAh g-1 for 10 cycles with sulfur-redox in amorphous TiS3 during charge-discharge process. On the other hand, the cell with amorphous MoS3 shows the 1st reversible capacity of about 720 mAh g-1. The obtained capacity is based on the redox of both sulfur and molybdenum in amorphous MoS3. The irreversible capacity of about 50 mAh g-1 is observed at the 1st cycle, which is attributed to the irreversible electronic structure change of sulfur during the 1st cycle. The electronic structure of sulfur in amorphous MoS3 after the 10th charge is similar to that after the 1st charge. Therefore, the all-solid-state cell with amorphous MoS3 electrode shows relatively good cyclability after the 1st cycle.

  14. Edge Matters

    DEFF Research Database (Denmark)

    Earon, Ofri

    2013-01-01

    the building. The research explores and develops the architectural characteristics of correlations between the resident, the singular unit, the building and the given location at the edge zone. It approaches the edge zone of the urban house as a platform for dynamic interactions between these behaviours....... The following text includes the first draft of the first two chapters: introduction and theory. The chapters are not written completely, and some parts are written only as headlines. These headlines and other comments are marked in red. The text is on working progress and far from being finished...

  15. Living edge

    DEFF Research Database (Denmark)

    Earon, Ofri

    2014-01-01

    of the involved actors at the border. By doing so, the study underlines a forgotten, yet important, role of this edge zone – being a zone of commonality between the house and city, between indoors and outdoors, between the man at home and the man at the street. The city of Copenhagen promotes porous borders...... is a collection of material from the case study of an ongoing PhD study titled: LIVING EDGE - The Architectural and Urban Prospect of Domestic Borders. The paper includes a description of the problem analysis, research question, method, discussion and conclusion....

  16. Electronic and chemical state of aluminum from the single- (K) and double-electron excitation (KLII&III, KLI) x-ray absorption near-edge spectra of α-alumina, sodium aluminate, aqueous Al³⁺•(H₂O)₆, and aqueous Al(OH)₄⁻

    Energy Technology Data Exchange (ETDEWEB)

    Fulton, John L. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Govind, Niranjan [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Huthwelker, Thomas [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Bylaska, Eric J. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Vjunov, Aleksei [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pin, Sonia [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Smurthwaite, Tricia D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

    2015-07-02

    We probe, at high energy resolution, the double electron excitation (KLII&II) x-ray absorption region that lies approximately 115 eV above the main Al K-edge (1566 eV) of α-alumina and sodium aluminate. The two solid standards, α-alumina (octahedral) and sodium aluminate (tetrahedral) are compared to aqueous species that have the same Al coordination symmetries, Al³⁺•6H₂O (octahedral) and Al(OH)₄⁻ (tetrahedral). For the octahedral species, the edge height of the KLII&III-edge is approximately 10% of the main K-edge however the edge height is much weaker (3% of K-edge height) for Al species with tetrahedral symmetry. For the α-alumina and aqueous Al³⁺•6H₂O the KLII&III spectra contain white line features and extended absorption fine structure (EXAFS) that mimics the K-edge spectra. The KLII&III-edge feature interferes with an important region of the extended-XAFS region of the spectra for the K-edge of the crystalline and aqueous standards. The K-edge spectra and K-edge positions are predicted using time-dependent density functional theory (TDDFT). The TDDFT calculations for the K-edge XANES spectra reproduce the observed transitions in the experimental spectra of the four Al species. The KLII&III and KLI onsets and their corresponding chemical shifts for the four standards are estimated using the delta self-consistent field (ΔSCF) method. Research by JLF, NG, EJB, AV, TDS was supported by U.S. Department of Energy’s (DOE), Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. NG thanks Amity Andersen for help with the α-Al₂O₃ and tetrahedral sodium aluminate (NaAlO₂) clusters. All the calculations were performed using the Molecular Science Computing Capability at EMSL, a national scientific user facility sponsored by the U.S. Department of Energy’s Office of Biological and Environmental Research and located at

  17. Edge detection of color images using the HSL color space

    Science.gov (United States)

    Weeks, Arthur R.; Felix, Carlos E.; Myler, Harley R.

    1995-03-01

    Various edge detectors have been proposed as well as several different types of adaptive edge detectors, but the performance of many of these edge detectors depends on the features and the noise present in the grayscale image. Attempts have been made to extend edge detection to color images by applying grayscale edge detection methods to each of the individual red, blue, and green color components as well as to the hue, saturation, and intensity color components of the color image. The modulus 2(pi) nature of the hue color component makes its detection difficult. For example, a hue of 0 and 2(pi) yields the same color tint. Normal edge detection of a color image containing adjacent pixels with hue of 0 and 2(pi) could yield the presence of an edge when an edge is really not present. This paper presents a method of mapping the 2(pi) modulus hue space to a linear space enabling the edge detection of the hue color component using the Sobel edge detector. The results of this algorithm are compared against the edge detection methods using the red, blue, and green color components. By combining the hue edge image with the intensity and saturation edge images, more edge information is observed.

  18. Electrode thickness measurement of a Si(Li) detector for the SIXA array

    OpenAIRE

    Tikkanen, T. (Tiia); Hamalainen, K.; Huotari, S.

    1997-01-01

    Cathode electrodes of the Si(Li) detector elements of the SIXA X-ray spectrometer array are formed by gold-palladium alloy contact layers. The equivalent thickness of gold in one element was measured by observing the characteristic L-shell X-rays of gold excited by monochromatised synchrotron radiation with photon energies above the L3 absorption edge of gold. The results obtained at 4 different photon energies below the L2 edge yield an average value of 22.4(35) nm which is consistent with t...

  19. Arsenate reduction and methylation in the cells of Trichoderma asperellum SM-12F1, Penicillium janthinellum SM-12F4, and Fusarium oxysporum CZ-8F1 investigated with X-ray absorption near edge structure

    Energy Technology Data Exchange (ETDEWEB)

    Su, S.M., E-mail: shimingsu@163.com [Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences/Key Laboratory of Agro-Environment, Ministry of Agriculture, Beijing (China); Zeng, X.B., E-mail: zengxb@ieda.org.cn [Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences/Key Laboratory of Agro-Environment, Ministry of Agriculture, Beijing (China); Li, L.F.; Duan, R.; Bai, L.Y. [Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences/Key Laboratory of Agro-Environment, Ministry of Agriculture, Beijing (China); Li, A.G.; Wang, J.; Jiang, S. [Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai (China)

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer Three fungal strains are capable of As(V) reduction and methylation. Black-Right-Pointing-Pointer As(V) reduction might be more easily processed than the methylation in fungal cells. Black-Right-Pointing-Pointer As sequestration and speciation transformation might be the detoxification processes. - Abstract: Synchrotron radiation-based X-ray absorption near edge structure (XANES) was introduced to directly analysis chemical species of arsenic (As) in the cells of Trichoderma asperellum SM-12F1, Penicillium janthinellum SM-12F4, and Fusarium oxysporum CZ-8F1 capable of As accumulation and volatilisation. After exposure to As(V) of 500 mg L{sup -1} for 15 days, a total of 60.5% and 65.3% of the accumulated As in the cells of T. asperellum SM-12F1 and P. janthinellum SM-12F4, respectively, was As(III), followed by 31.3% and 32.4% DMA (dimethylarsinic acid), 8.3% and 2.3% MMA (monomethylarsonic acid), respectively. However, for F. oxysporum CZ-8F1, 54.5% of the accumulated As was As(III), followed by 37.8% MMA and 7.7% As(V). The reduction and methylation of As(V) formed As(III), MMA, and DMA as the primacy products, and the reduction of As(V) might be more easily processed than the methylation. These results will help to understanding the mechanisms of As detoxification and its future application in bioremediation.

  20. Near-edge x-ray absorption fine-structure study of ion-beam-induced phase transformation in Gd2(Ti1-yZry)2O7

    Science.gov (United States)

    Nachimuthu, P.; Thevuthasan, S.; Shutthanandan, V.; Adams, E. M.; Weber, W. J.; Begg, B. D.; Shuh, D. K.; Lindle, D. W.; Gullikson, E. M.; Perera, R. C. C.

    2005-02-01

    The structural and electronic properties of Gd2(Ti1-yZry)2O7 (y =0-1) pyrochlores following a 2.0-MeV Au2+ ion-beam irradiation (˜5.0×1014Au2+/cm2) have been investigated by Ti2p and O1s near-edge x-ray absorption fine structure (NEXAFS). The irradiation of Gd2(Ti1-yZry)2O7 leads to the phase transformation from the ordered pyrochlore structure (Fd3m) to the defect fluorite structure (Fm3m) regardless of Zr concentration. Irradiated Gd2(Ti1-yZry)2O7 with y ⩽0.5 are amorphous, although significant short-range order is present. Contrasting to this behavior, compositions with y ⩾0.75 retain crystallinity in the defect fluorite structure following irradiation. The local structures of Zr4+ in the irradiated Gd2(Ti1-yZry)2O7 with y ⩾0.75 determined by NEXAFS are the same as in the cubic fluorite-structured yttria-stabilized zirconia (Y -ZrO2), thereby providing conclusive evidence for the phase transformation. The TiO6 octahedra present in Gd2(Ti1-yZry)2O7 are completely modified by ion-beam irradiation to TiOx polyhedra, and the Ti coordination is increased to eight with longer Ti -O bond distances. The similarity between cation sites and the degree of disorder in Gd2Zr2O7 facilitate the rearrangement and relaxation of Gd, Zr, and O ions/defects. This inhibits amorphization during the ion-beam-induced phase transition to the radiation-resistant defect fluorite structure, which is in contrast to the ordered Gd2Ti2O7.

  1. Invited article: The fast readout low noise camera as a versatile x-ray detector for time resolved dispersive extended x-ray absorption fine structure and diffraction studies of dynamic problems in materials science, chemistry, and catalysis

    Science.gov (United States)

    Labiche, Jean-Claude; Mathon, Olivier; Pascarelli, Sakura; Newton, Mark A.; Ferre, Gemma Guilera; Curfs, Caroline; Vaughan, Gavin; Homs, Alejandro; Carreiras, David Fernandez

    2007-09-01

    Originally conceived and developed at the European Synchrotron Radiation Facility (ESRF) as an "area" detector for rapid x-ray imaging studies, the fast readout low noise (FReLoN) detector of the ESRF [J.-C. Labiche, ESRF Newsletter 25, 41 (1996)] has been demonstrated to be a highly versatile and unique detector. Charge coupled device (CCD) cameras at present available on the public market offer either a high dynamic range or a high readout speed. A compromise between signal dynamic range and readout speed is always sought. The parameters of the commercial cameras can sometimes be tuned, in order to better fulfill the needs of specific experiments, but in general these cameras have a poor duty cycle (i.e., the signal integration time is much smaller than the readout time). In order to address scientific problems such as time resolved experiments at the ESRF, a FReLoN camera has been developed by the Instrument Support Group at ESRF. This camera is a low noise CCD camera that combines high dynamic range, high readout speed, accuracy, and improved duty cycle in a single image. In this paper, we show its application in a quasi-one-dimensional sense to dynamic problems in materials science, catalysis, and chemistry that require data acquisition on a time scale of milliseconds or a few tens of milliseconds. It is demonstrated that in this mode the FReLoN can be applied equally to the investigation of rapid changes in long range order (via diffraction) and local order (via energy dispersive extended x-ray absorption fine structure) and in situations of x-ray hardness and flux beyond the capacity of other detectors.

  2. Promising X-ray fluorescent tests for superconducting tunnel junction detector

    Energy Technology Data Exchange (ETDEWEB)

    Friedrich, Stephan; Robinson, Art

    2001-01-11

    Scientists in the Physical Biosciences Division of the Ernest Orlando Berkeley National Laboratory (Berkeley Lab) studying transition metals in proteins with fluorescence-detected L-edge absorption spectroscopy have found the measurements to be extremely challenging. The difficulty is that the metal centers are present in very dilute concentrations so that their weak fluorescence is often obscured by strong background signals from carbon and oxygen. To solve this problem, the Berkeley group has been working with researchers from the Advanced Detector Group at the Lawrence Livermore National Laboratory on an energy-dispersive superconducting tunnel junction x-ray detector. These devices in principle have the energy resolution needed to reveal the metal signal. The most recent results with the latest version of the detector on Beamline 4.0.1-2 at the Advanced Light Source (ALS) illustrate the promise of the cryogenic detector strategy not only for this application but also for spectroscopy of other types of dilute samples.

  3. Edge detection in microscopy images using curvelets

    Directory of Open Access Journals (Sweden)

    Koumoutsakos Petros

    2009-03-01

    Full Text Available Abstract Background Despite significant progress in imaging technologies, the efficient detection of edges and elongated features in images of intracellular and multicellular structures acquired using light or electron microscopy is a challenging and time consuming task in many laboratories. Results We present a novel method, based on the discrete curvelet transform, to extract a directional field from the image that indicates the location and direction of the edges. This directional field is then processed using the non-maximal suppression and thresholding steps of the Canny algorithm to trace along the edges and mark them. Optionally, the edges may then be extended along the directions given by the curvelets to provide a more connected edge map. We compare our scheme to the Canny edge detector and an edge detector based on Gabor filters, and show that our scheme performs better in detecting larger, elongated structures possibly composed of several step or ridge edges. Conclusion The proposed curvelet based edge detection is a novel and competitive approach for imaging problems. We expect that the methodology and the accompanying software will facilitate and improve edge detection in images available using light or electron microscopy.

  4. Edge Detection,

    Science.gov (United States)

    1985-09-01

    PROJECT. T ASK0 Artificial Inteligence Laboratory AREA It WORK UNIT NUMBERS V 545 Technology Square ( Cambridge, HA 02139 I I* CONTOOL1LIN@4OFFICE NAME...ARD-A1t62 62 EDGE DETECTION(U) NASSACNUSETTS INST OF TECH CAMBRIDGE 1/1 ARTIFICIAL INTELLIGENCE LAB E C HILDRETH SEP 85 AI-M-8 N99SI4-8S-C-6595...used to carry out this analysis. cce~iO a N) ’.~" D LI’BL. P p ------------ Sj. t i MASSACHUSETTS INSTITUTE OF TECHNOLOGY i ARTIFICIAL INTELLIGENCE

  5. Multiscale edge detection of noisy images using wavelets

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The classical edge detectors work fine with the high quality pictures, but often are not good enough for noisy images because they cannot distinguish edges of different significance. The paper presented a novel approach to multiscale edge detection for noisy images using wavelet transforms based on Lipschitz regularity coefficients and a cascade algorithm. The relationship between wavelet transform and Lipschitz regularity was establishod. The proposed wavelet based edge detection algorithm combined the coefficients of wavelet transforms along with a cascade algorithm which significantly improves the result. The comparison between the proposed method and the classical edge detectors was carried out. The algorithm was applied to various images and its performance was discussed. The results of edge detection of contaminated images using the proposed algorithm show that it works better than the classical edge detectors.

  6. Robust and economical multi-sample, multi-wavelength UV/vis absorption and fluorescence detector for biological and chemical contamination

    CERN Document Server

    Lu, Peter J; Macarthur, James B; Sims, Peter A; Ma, Hongshen; Slocum, Alexander H

    2012-01-01

    We present a portable multi-channel, multi-sample UV/vis absorption and fluorescence detection device, which has no moving parts, can operate wirelessly and on batteries, interfaces with smart mobile phones or tablets, and has the sensitivity of commercial instruments costing an order of magnitude more. We use UV absorption to measure the concentration of ethylene glycol in water solutions at all levels above those deemed unsafe by the United States Food and Drug Administration; in addition we use fluorescence to measure the concentration of d-glucose. Both wavelengths can be used concurrently to increase measurement robustness and increase detection sensitivity. Our small robust economical device can be deployed in the absence of laboratory infrastructure, and therefore may find applications immediately following natural disasters, and in more general deployment for much broader-based testing of food, agricultural and household products to prevent outbreaks of poisoning and disease.

  7. Edge and line oriented contour detection : State of the art

    NARCIS (Netherlands)

    Papari, Giuseppe; Petkov, Nicolai

    We present an overview of various edge and line oriented approaches to contour detection that have been proposed in the last two decades. By edge and line oriented we mean methods that do not rely on segmentation. Distinction is made between edges and contours. Contour detectors are divided in local

  8. Edge and line oriented contour detection : State of the art

    NARCIS (Netherlands)

    Papari, Giuseppe; Petkov, Nicolai

    2011-01-01

    We present an overview of various edge and line oriented approaches to contour detection that have been proposed in the last two decades. By edge and line oriented we mean methods that do not rely on segmentation. Distinction is made between edges and contours. Contour detectors are divided in local

  9. Measurement of the neutron capture cross section of the fissile isotope $^{235}$U with the CERN n_TOF Total Absorption Calorimeter and a fission tagging based on micromegas detectors

    CERN Document Server

    Mendoza, E; Cano-Ott, D; Guerrero, C; Berthoumieux, E; Altstadt, S; Andrzejewski, J; Audouin, L; Barbagallo, M; Bécares, V; Becvár, F; Belloni, F; Billowes, J; Boccone, V; Bosnar, D; Brugger, M; Calviani, M; Calviño, F; Carrapiço, C; Cerutti, F; Chiaveri, E; Chin, M; Colonna, N; Cortés, G; Cortés-Giraldo, M A; Diakaki, M; Domingo-Pardo, C; Duran, I; Dressler, R; Dzysiuk, N; Eleftheriadis, C; Ferrari, A; Fraval, K; Ganesan, S; García, A R; Giubrone, G; Gómez-Hornillos, M B; Gonçalves, I F; González-Romero, E; Griesmayer, E; Gunsing, F; Gurusamy, P; Jenkins, D G; Jericha, E; Kadi, Y; Käppeler, F; Karadimos, D; Kawano, T; Kivel, N; Koehler, P; Kokkoris, M; Korschinek, G; Krticka, M; Kroll, J; Langer, C; Lampoudis, C; Leal-Cidoncha, E; Lederer, C; Leeb, H; Leong, L S; Losito, R; Manousos, A; Marganiec, J; Martínez, T; Mastinu, P F; Mastromarco, M; Massimi, C; Meaze, M; Mengoni, A; Milazzo, P M; Mingrone, F; Mirea, M; Mondelaers, W; Paradela, C; Pavlik, A; Perkowski, J; Pignatari, M; Plompen, A; Praena, J; Quesada, J M; Rauscher, T; Reifarth, R; Riego, A; Roman, F; Rubbia, C; Sarmento, R; Schillebeeckx, P; Schmidt, S; Schumann, D; Stetcu, I; Sabaté, M; Tagliente, G; Tain, J L; Tarrío, D; Tassan-Got, L; Tsinganis, A; Valenta, S; Vannini, G; Variale, V; Vaz, P; Ventura, A; Versaci, R; Vermeulen, M J; Vlachoudis, V; Vlastou, R; Wallner, A; Ware, T; Weigand, M; Weiss, C; Wright, T; Zugec, P

    2014-01-01

    Actual and future nuclear technologies require more accurate nuclear data on the (n, $\\gamma$) cross sections and $\\alpha$-ratios of fissile isotopes. Their measurement presents several difficulties, mainly related to the strong fission $\\gamma$-ray background competing with the weaker $\\gamma$-ray cascades used as the experimental signature of the (n, $\\gamma$) process. A specific setup has been used at the CERN n_TOF facility in 2012 for the measurement of the (n,$\\gamma$ ) cross section and $\\alpha$- ratios of fissile isotopes and used for the case of the $^{235}$U isotope. The setup consists in a set of micromegas fission detectors surrounding $^{235}$U samples and placed inside the segmented BaF$_2$ Total Absorption Calorimeter.

  10. Measurement of the Neutron Capture Cross Section of the Fissile Isotope 235U with the CERN n_TOF Total Absorption Calorimeter and a Fission Tagging Based on Micromegas Detectors

    CERN Document Server

    Balibrea, J; Cano-Ott, D; Guerrero, C; Berthoumieux, E; Altstadt, S; Andrzejewski, J; Audouin, L; Barbagallo, M; Bécares, V; Bečvář, F; Belloni, F; Billowes, J; Boccone, V; Bosnar, D; Brugger, M; Calviani, M; Calviño, F; Carrapiço, C; Cerutti, F; Chiaveri, E; Chin, M; Colonna, N; Cortés, G; Cortés-Giraldo, M A; Diakaki, M; Domingo-Pardo, C; Duran, I; Dressler, R; Dzysiuk, N; Eleftheriadis, C; Ferrari, A; Fraval, K; Ganesan, S; García, A R; Giubrone, G; Gómez-Hornillos, M B; Gonçalves, I F; González-Romero, E; Griesmayer, E; Gunsing, F; Gurusamy, P; Jenkins, D G; Jericha, E; Kadi, Y; Käppeler, F; Karadimos, D; Kawano, T; Kivel, N; Koehler, P; Kokkoris, M; Korschinek, G; Krtička, M; Kroll, J; Langer, C; Lampoudis, C; Lederer, C; Leeb, H; Leong, L S; Losito, R; Manousos, A; Marganiec, J; Martínez, T; Mastinu, P F; Mastromarco, M; Massimi, C; Meaze, M; Mengoni, A; Milazzo, P M; Mingrone, F; Mirea, M; Mondelaers, W; Paradela, C; Pavlik, A; Perkowski, J; Pignatari, M; Plompen, A; Praena, J; Quesada, J M; Rauscher, T; Reifarth, R; Riego, A; Roman, F; Rubbia, C; Sarmento, R; Schillebeeckx, P; Schmidt, S; Schumann, D; Stetcu, I; Sabaté, M; Tagliente, G; Tain, J L; Tarrío, D; Tassan-Got, L; Tsinganis, A; Valenta, S; Vannini, G; Variale, V; Vaz, P; Ventura, A; Versaci, R; Vermeulen, M J; Vlachoudis, V; Vlastou, R; Wallner, A; Ware, T; Weigand, M; Weiß, C; Wright, T J; Žugec, P

    Current and future nuclear technologies require more accurate nuclear data on (n,γ) cross sections and the α-ratios of fissile isotopes. Their measurement presents several difficulties, mainly related to the strong fission γ-ray background competing with the weaker γ-ray cascades used as the experimental signature of the (n,γ) process. A specific setup was used at the CERN n_TOF facility in 2012 for the measurement of the (n,γ) cross section and α-ratios of fissile isotopes and used for the case of the 235U isotope. The setup consists of a set of micromegas fission detectors surrounding the 235U samples all placed inside a segmented BaF2 Total Absorption Calorimeter.

  11. Hybrid anode for semiconductor radiation detectors

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Ge; Bolotnikov, Aleksey E; Camarda, Guiseppe; Cui, Yonggang; Hossain, Anwar; Kim, Ki Hyun; James, Ralph B

    2013-11-19

    The present invention relates to a novel hybrid anode configuration for a radiation detector that effectively reduces the edge effect of surface defects on the internal electric field in compound semiconductor detectors by focusing the internal electric field of the detector and redirecting drifting carriers away from the side surfaces of the semiconductor toward the collection electrode(s).

  12. Enhancement in Edge Detection by Threshold Value in Sobel Operator by using Fuzzy Logic

    Directory of Open Access Journals (Sweden)

    Prof. (Dr. S. K. Singh

    2014-07-01

    Full Text Available The key uncertainty of the edge detection algorithm is Threshold decision in image processing. Fuzzy logic for threshold and generated threshold values are used for edge detection, the results of this method is compared to many well known edge detector. However, the value of the input parameters providing the appreciable results in the proposed detector is more stable than classical operator.

  13. 硅漂移探测器用于X射线标识谱与吸收实验%Silicon drift detector for characteristic X-ray spectrum and absorption experiment

    Institute of Scientific and Technical Information of China (English)

    冉书能; 贾春燕; 吴思诚

    2016-01-01

    利用硅漂移探测器测量不同元素的标识X射线,验证莫塞莱定律,计算屏蔽系数并解释其变化规律。利用不同厚度的镍吸收片做铜的标识X射线吸收,结果表明:单色化铜的标识X射线所需镍片的最佳厚度约为20μm 。%The characteristic X‐ray spectrum was measured using silicon drift detector ,the Mose‐ley law was verified ,and the shielding coefficient and its variation was calculated and explained .The absorption of the characteristic X‐ray spectrum of copper was investigated using nickel absorption sheets of different thickness .It was concluded that the optimum thickness of the nickel sheet required for the monochromatization of Cu characteristic spectrum was about 20 μm .

  14. The HOTWAXS detector

    Energy Technology Data Exchange (ETDEWEB)

    Bateman, J.E.; Derbyshire, G.E. [Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX (United Kingdom); Diakun, G. [Science and Technology Facilities Council, Daresbury Laboratory, Keckwick Lane, Daresbury, Warrington WA4 4AD (United Kingdom); Duxbury, D.M. [Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX (United Kingdom)], E-mail: d.m.duxbury@rl.ac.uk; Fairclough, J.P.A. [Department of Chemistry, University of Sheffield, Brook Hill, Sheffield S3 7HF (United Kingdom); Harvey, I.; Helsby, W.I. [Science and Technology Facilities Council, Daresbury Laboratory, Keckwick Lane, Daresbury, Warrington WA4 4AD (United Kingdom); Lipp, J.D.; Marsh, A.S.; Salisbury, J. [Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX (United Kingdom); Sankar, G. [Royal Institution of GB, 21 Albemarle Street, London W1S 4BS (United Kingdom); Spill, E.J.; Stephenson, R. [Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX (United Kingdom); Terrill, N.J. [Diamond Light Source LTD, Harwell Science and Innovation Campus, Diamond House, Chilton, Didcot, Oxfordshire OX11 0DE (United Kingdom)

    2007-10-11

    The development and testing of the HOTWAXS position-sensitive X-ray detector for Synchrotron Radiation Sources is described. Funded from a facility development grant, the aim of the project was to produce a high counting rate, parallax-free photon counting detector to be used in the combined studies of X-ray absorption fine structure and X-ray diffraction (XAFS/XRD), and also in the technique of small angle and wide angle X-ray scattering (SAXS/WAXS). The detector system is described together with results of experiments carried out at the Daresbury Laboratory Synchrotron Radiation Source.

  15. Study and Comparison of Various Techniques of Image Edge Detection

    Directory of Open Access Journals (Sweden)

    Gurjeet Singh

    2014-03-01

    Full Text Available An edge may be defined as a set of connected pixels that forms a boundary between two disjoints regions. Image Edge detection reduces the amount of data and filters out useless information, while preserving the important structural properties in an image. Edge detection plays an important role in digital image processing and practical aspects of our daily life. In this paper we studied various edge detection techniques as Prewitt, Robert, Sobel, LoG and Canny operators. On comparing them we conclude that canny edge detector performs better than all other edge detectors on various aspects such as it is adaptive in nature, performs better for noisy image, gives sharp edges, low probability of detecting false edges.

  16. Local detection efficiency of a NbN superconducting single photon detector explored by a scattering scanning near-field optical microscope.

    Science.gov (United States)

    Wang, Qiang; Renema, Jelmer J; Engel, Andreas; van Exter, Martin P; de Dood, Michiel J A

    2015-09-21

    We propose an experiment to directly probe the local response of a superconducting single photon detector using a sharp metal tip in a scattering scanning near-field optical microscope. The optical absorption is obtained by simulating the tip-detector system, where the tip-detector is illuminated from the side, with the tip functioning as an optical antenna. The local detection efficiency is calculated by considering the recently introduced position-dependent threshold current in the detector. The calculated response for a 150 nm wide detector shows a peak close to the edge that can be spatially resolved with an estimated resolution of ∼ 20 nm, using a tip with parameters that are experimentally accessible.

  17. Independent component analysis of edge information for face recognition

    CERN Document Server

    Karande, Kailash Jagannath

    2013-01-01

    The book presents research work on face recognition using edge information as features for face recognition with ICA algorithms. The independent components are extracted from edge information. These independent components are used with classifiers to match the facial images for recognition purpose. In their study, authors have explored Canny and LOG edge detectors as standard edge detection methods. Oriented Laplacian of Gaussian (OLOG) method is explored to extract the edge information with different orientations of Laplacian pyramid. Multiscale wavelet model for edge detection is also propos

  18. SAR-PC: Edge Detection in SAR Images via an Advanced Phase Congruency Model

    Directory of Open Access Journals (Sweden)

    Yuming Xiang

    2017-02-01

    Full Text Available Edge detection in Synthetic Aperture Radar (SAR images has been a challenging task due to the speckle noise. Ratio-based edge detectors are robust operators for SAR images that provide constant false alarm rates, but they are only optimal for step edges. Edge detectors developed by the phase congruency model provide the identification of different types of edge features, but they suffer from speckle noise. By combining the advantages of the two edge detectors, we propose a SAR phase congruency detector (SAR-PC. Firstly, an improved local energy model for SAR images is obtained by replacing the convolution of raw image and the quadrature filters by the ratio responses. Secondly, a new noise level is estimated for the multiplicative noise. Substituting the SAR local energy and the new noise level into the phase congruency model, SAR-PC is derived. Edge response corresponds to the max moment of SAR-PC. We compare the proposed detector with the ratio-based edge detectors and the phase congruency edge detectors. Receiver Operating Characteristic (ROC curves and visual effects are used to evaluate the performance. Experimental results of simulated images and real-world images show that the proposed edge detector is robust to speckle noise and it provides a consecutive edge response.

  19. Promising X-ray fluorescence tests for superconducting tunneljunction detector

    Energy Technology Data Exchange (ETDEWEB)

    Friedrich, Stephan; Robinson, Arthur L.

    2001-05-15

    Scientists in the Physical Biosciences Division of the Ernest Orlando Berkeley National Laboratory (Berkeley Lab) studying transition metals in proteins with fluorescence-detected L-edge absorption spectroscopy have found the measurements to be extremely challenging. The difficulty is that the metal centers are present in very dilute concentrations so that their weak fluorescence is often obscured by strong background signals carbon and oxygen. To solve this problem, the Berkeley group has been working with researchers from the Advanced Detector Group at the Lawrence Livermore National Laboratory on an energy-dispersive superconducting tunnel junction x-ray detector. These devices in principle have the energy resolution needed to reveal the metal signal. The most recent results with the latest version of the detector on Beamline 4.0.1-2 at the Advanced Light Source (ALS) illustrate the promise of the cryogenic detector strategy not only for this application but also for spectroscopy of other types of dilute samples. Transition-metal complexes are key elements in many biologically important processes that are catalyzed by proteins (enzymes), photosynthesis being a prime example. The changes in that occur in electronic structure throughout a catalytic cycle are the subject of much research aimed at understanding the mechanisms of these processes. L-edge x-ray spectroscopy offers several advantages relative to the more common K-edge techniques, since it involves allowed transitions to the d-orbitals associated with metal-ligand bonding. It also has a rich multiplet structure interpretable by theory and higher spectral resolution.

  20. Edge-based compression of cartoon-like images with homogeneous diffusion

    DEFF Research Database (Denmark)

    Mainberger, Markus; Bruhn, Andrés; Weickert, Joachim;

    2011-01-01

    Edges provide semantically important image features. In this paper a lossy compression method for cartoon-like images is presented, which is based on edge information. Edges together with some adjacent grey/colour values are extracted and encoded using a classical edge detector, binary compression...

  1. Processing and characterization of epitaxial GaAs radiation detectors

    CERN Document Server

    Wu, X; Arsenovich, T; Gädda, A; Härkönen, J; Junkes, A; Karadzhinova, A; Kostamo, P; Lipsanen, H; Luukka, P; Mattila, M; Nenonen, S; Riekkinen, T; Tuominen, E; Winkler, A

    2015-01-01

    GaAs devices have relatively high atomic numbers (Z=31, 33) and thus extend the X-ray absorption edge beyond that of Si (Z=14) devices. In this study, radiation detectors were processed on GaAs substrates with 110 $\\mu\\textrm{m}$ - 130 $\\mu\\textrm{m}$ thick epitaxial absorption volume. Thick undoped and heavily doped p$^+$ epitaxial layers were grown using a custom-made horizontal Chloride Vapor Phase Epitaxy (CVPE) reactor, the growth rate of which was about 10 $\\mu\\textrm{m}$/h. The GaAs p$^+$/i/n$^+$ detectors were characterized by Capacitance Voltage ($CV$), Current Voltage ($IV$), Transient Current Technique (TCT) and Deep Level Transient Spectroscopy (DLTS) measurements. The full depletion voltage ($V_{\\textrm{fd}}$) of the detectors with 110 $\\mu\\textrm{m}$ epi-layer thickness is in the range of 8 V - 15 V and the leakage current density is about 10 nA/cm$^2$. The signal transit time determined by TCT is about 5 ns when the bias voltage is well above the value that produces the peak saturation drift ve...

  2. IMAGE ANALYSIS BASED ON EDGE DETECTION TECHNIQUES

    Institute of Scientific and Technical Information of China (English)

    纳瑟; 刘重庆

    2002-01-01

    A method that incorporates edge detection technique, Markov Random field (MRF), watershed segmentation and merging techniques was presented for performing image segmentation and edge detection tasks. It first applies edge detection technique to obtain a Difference In Strength (DIS) map. An initial segmented result is obtained based on K-means clustering technique and the minimum distance. Then the region process is modeled by MRF to obtain an image that contains different intensity regions. The gradient values are calculated and then the watershed technique is used. DIS calculation is used for each pixel to define all the edges (weak or strong) in the image. The DIS map is obtained. This help as priority knowledge to know the possibility of the region segmentation by the next step (MRF), which gives an image that has all the edges and regions information. In MRF model,gray level l, at pixel location i, in an image X, depends on the gray levels of neighboring pixels. The segmentation results are improved by using watershed algorithm. After all pixels of the segmented regions are processed, a map of primitive region with edges is generated. The edge map is obtained using a merge process based on averaged intensity mean values. A common edge detectors that work on (MRF) segmented image are used and the results are compared. The segmentation and edge detection result is one closed boundary per actual region in the image.

  3. Towards simultaneous measurements of electronic and structural properties in ultra-fast x-ray free electron laser absorption spectroscopy experiments.

    Science.gov (United States)

    Gaudin, J; Fourment, C; Cho, B I; Engelhorn, K; Galtier, E; Harmand, M; Leguay, P M; Lee, H J; Nagler, B; Nakatsutsumi, M; Ozkan, C; Störmer, M; Toleikis, S; Tschentscher, Th; Heimann, P A; Dorchies, F

    2014-04-17

    The rapidly growing ultrafast science with X-ray lasers unveils atomic scale processes with unprecedented time resolution bringing the so called "molecular movie" within reach. X-ray absorption spectroscopy is one of the most powerful x-ray techniques providing both local atomic order and electronic structure when coupled with ad-hoc theory. Collecting absorption spectra within few x-ray pulses is possible only in a dispersive setup. We demonstrate ultrafast time-resolved measurements of the LIII-edge x-ray absorption near-edge spectra of irreversibly laser excited Molybdenum using an average of only few x-ray pulses with a signal to noise ratio limited only by the saturation level of the detector. The simplicity of the experimental set-up makes this technique versatile and applicable for a wide range of pump-probe experiments, particularly in the case of non-reversible processes.

  4. Lyman edges in AGN accretion discs

    Energy Technology Data Exchange (ETDEWEB)

    Czerny, B. (Copernicus Astronomical Center, Warsaw (Poland)); Pojmanski, G. (Warsaw Univ. (Poland). Obserwatorium Astronomiczne)

    1990-07-01

    We show that the basic difference in the two principal approaches to predictions of the Lyman edge in an accretion disc lies in the implicit assumption about the density of the radiating gas. Independent from the details, models predict a broad range of the edge sizes, both in absorption and in emission. Observed spectra do not exhibit any strong feature at 912 A but may still be consistent with an accretion disc mechanism if more advanced theory is developed. (author).

  5. Performance of active edge pixel sensors

    CERN Document Server

    Bomben, Marco; Bagolini, Alvise; Boscardin, Maurizio; Bosisio, Luciano; Calderini, Giovanni; D'Eramo, Louis; Giacomini, Gabriele; Marchiori, Giovanni; Zorzi, Nicola; Rummler, Andre; Weingarten, Jens

    2017-01-01

    this paper the performance of these modules are reported. In particular the lateral extension of the detection volume, beyond the pixel region, is investigated and the results show high hit efficiency also at the detector edge, even in presence of guard rings.

  6. X-ray Absorption Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yano, Junko; Yachandra, Vittal K.

    2009-07-09

    This review gives a brief description of the theory and application of X-ray absorption spectroscopy, both X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS), especially, pertaining to photosynthesis. The advantages and limitations of the methods are discussed. Recent advances in extended EXAFS and polarized EXAFS using oriented membranes and single crystals are explained. Developments in theory in understanding the XANES spectra are described. The application of X-ray absorption spectroscopy to the study of the Mn4Ca cluster in Photosystem II is presented.

  7. Photoinduced absorption of polyalkylthienylenevinylenes

    Energy Technology Data Exchange (ETDEWEB)

    Botta, C. (Ist. di Chimica delle Macromolecole (CNR), Milano (Italy)); Bradley, D.D.C. (Cambridge Univ. (United Kingdom). Cavendish Lab.); Friend, R.H. (Cambridge Univ. (United Kingdom). Cavendish Lab.); Musco, A. (Ist. di Scienze Chimiche, Univ. di Urbino (Italy))

    1993-03-15

    We present a photoinduced absorption study of alkyl substituted poly(2,5-thienylenevinylene)s. Three photoinduced states are detected in both the solid state and in solution. The two low-energy bands are assigned to bipolarons, while a third band peaked near the band edge has a different origin. In solution photoexcitated states are very long-lived and we propose that photoexcitation recombine via a solvent-assisted photo-doping mechanism. (orig.)

  8. Performance of active edge pixel sensors

    Science.gov (United States)

    Bomben, M.; Ducourthial, A.; Bagolini, A.; Boscardin, M.; Bosisio, L.; Calderini, G.; D'Eramo, L.; Giacomini, G.; Marchiori, G.; Zorzi, N.; Rummler, A.; Weingarten, J.

    2017-05-01

    To cope with the High Luminosity LHC harsh conditions, the ATLAS inner tracker has to be upgraded to meet requirements in terms of radiation hardness, pile up and geometrical acceptance. The active edge technology allows to reduce the insensitive area at the border of the sensor thanks to an ion etched trench which avoids the crystal damage produced by the standard mechanical dicing process. Thin planar n-on-p pixel sensors with active edge have been designed and produced by LPNHE and FBK foundry. Two detector module prototypes, consisting of pixel sensors connected to FE-I4B readout chips, have been tested with beams at CERN and DESY. In this paper the performance of these modules are reported. In particular the lateral extension of the detection volume, beyond the pixel region, is investigated and the results show high hit efficiency also at the detector edge, even in presence of guard rings.

  9. Hardware Design and Simulation of Sobel Edge Detection Algorithm

    Directory of Open Access Journals (Sweden)

    Sohag Kabir

    2014-04-01

    Full Text Available In this paper, a hardware system for Sobel Edge Detection Algorithm is designed and simulated for a 128 pixel, 8-bit monochrome line-scan camera. The system is designed to detect objects as they move along a conveyor belt in a manufacturing environment, the camera will observe dark objects on a light conveyor belt. The edge detector is required to detect horizontal and vertical edges using Sobel edge detection method. The Sobel operator requires 3 lines and takes 3 pixels per line, thus using a 3×3 input block to process each pixel. The centre pixel of the 3×3 pixel block can be classified as an edge point or otherwise by thresholding the value from the operator. The FPGA based Sobel edge detector is designed and simulated using Altera Quartus II 8.1 web edition by targeting Cyclone II development boards.

  10. Switching variability index based multiple strategy CFAR detector

    Institute of Scientific and Technical Information of China (English)

    Yang Li; Zhenyuan Ji; Bingfei Li; Gil Alterovitz

    2014-01-01

    A switching variability index (SVI) constant false alarm rate (CFAR) detector is proposed for improving the detection performance of VI-CFAR detectors in multiple targets back-grounds. When the presence of non-homogeneity in CFAR re-ference windows is indicated by a VI-CFAR detector, a switching-CFAR detector is introduced to optimize the performance of the VI-CFAR detector in homogeneous, multiple targets and clut-ter edge backgrounds. The structure and parameters selection method of the SVI-CFAR detector is presented. Comparisons with classic CFAR detectors and recently proposed detectors are also given. Theoretical analysis and simulation results show that SVI-CFAR detector maintains the good performance of the VI-CFAR detector in homogeneous and clutter edge backgrounds, while greatly improving the capacity of anti-multi targets.

  11. Detector Unit

    CERN Multimedia

    1960-01-01

    Original detector unit of the Instituut voor Kernfysisch Onderzoek (IKO) BOL project. This detector unit shows that silicon detectors for nuclear physics particle detection were already developed and in use in the 1960's in Amsterdam. Also the idea of putting 'strips' onto the silicon for high spatial resolution of a particle's impact on the detector were implemented in the BOL project which used 64 of these detector units. The IKO BOL project with its silicon particle detectors was designed, built and operated from 1965 to roughly 1977. Detector Unit of the BOL project: These detectors, notably the ‘checkerboard detector’, were developed during the years 1964-1968 in Amsterdam, The Netherlands, by the Natuurkundig Laboratorium of the N.V. Philips Gloeilampen Fabrieken. This was done in close collaboration with the Instituut voor Kernfysisch Onderzoek (IKO) where the read-out electronics for their use in the BOL Project was developed and produced.

  12. Infrared detectors

    CERN Document Server

    Rogalski, Antonio

    2010-01-01

    This second edition is fully revised and reorganized, with new chapters concerning third generation and quantum dot detectors, THz detectors, cantilever and antenna coupled detectors, and information on radiometry and IR optics materials. Part IV concerning focal plane arrays is significantly expanded. This book, resembling an encyclopedia of IR detectors, is well illustrated and contains many original references … a really comprehensive book.-F. Sizov, Institute of Semiconductor Physics, National Academy of Sciences, Kiev, Ukraine

  13. A textural approach based on Gabor functions for texture edge detection in ultrasound images.

    Science.gov (United States)

    Chen, C M; Lu, H H; Han, K C

    2001-04-01

    Edge detection is an important, but difficult, step in quantitative ultrasound (US) image analysis. In this paper, we present a new textural approach for detecting a class of edges in US images; namely, the texture edges with a weak regional mean gray-level difference (RMGD) between adjacent regions. The proposed approach comprises a vision model-based texture edge detector using Gabor functions and a new texture-enhancement scheme. The experimental results on the synthetic edge images have shown that the performances of the four tested textural and nontextural edge detectors are about 20%-95% worse than that of the proposed approach. Moreover, the texture enhancement may improve the performance of the proposed texture edge detector by as much as 40%. The experiments on 20 clinical US images have shown that the proposed approach can find reasonable edges for real objects of interest with the performance of 0.4 +/- 0.08 in terms of the Pratt's figure.

  14. Electro-absorption of silicene and bilayer graphene quantum dots

    Science.gov (United States)

    Abdelsalam, Hazem; Talaat, Mohamed H.; Lukyanchuk, Igor; Portnoi, M. E.; Saroka, V. A.

    2016-07-01

    We study numerically the optical properties of low-buckled silicene and AB-stacked bilayer graphene quantum dots subjected to an external electric field, which is normal to their surface. Within the tight-binding model, the optical absorption is calculated for quantum dots, of triangular and hexagonal shapes, with zigzag and armchair edge terminations. We show that in triangular silicene clusters with zigzag edges a rich and widely tunable infrared absorption peak structure originates from transitions involving zero energy states. The edge of absorption in silicene quantum dots undergoes red shift in the external electric field for triangular clusters, whereas blue shift takes place for hexagonal ones. In small clusters of bilayer graphene with zigzag edges the edge of absorption undergoes blue/red shift for triangular/hexagonal geometry. In armchair clusters of silicene blue shift of the absorption edge takes place for both cluster shapes, while red shift is inherent for both shapes of the bilayer graphene quantum dots.

  15. The edges of graphene.

    Science.gov (United States)

    Zhang, Xiuyun; Xin, John; Ding, Feng

    2013-04-01

    The edge of two dimensional (2D) graphene, as the surface of a three dimensional (3D) crystal, plays a crucial role in the determination of its physical, electronic and chemical properties and thus has been extensively studied recently. In this review, we summarize the recent advances in the study of graphene edges, including edge formation energy, edge reconstruction, method of graphene edge synthesis and the recent progress on metal-passivated graphene edges and the role of edges in graphene CVD growth. We expect this review to provide a guideline for readers to gain a clear picture of graphene edges from several aspects, especially the catalyst-passivated graphene edges and their role in graphene CVD growth.

  16. High-Resolution Gamma-Ray Spectrometers using Bulk Absorbers Coupled to Mo/Cu Multilayer Superconducting Transition-Edge Sensors

    Energy Technology Data Exchange (ETDEWEB)

    Chow, D.T.; Loshak, A.; Van Den Berg, M.L.; Frank, M.; Barbee Jr., T.W.; Labov, S.E.

    2000-07-04

    In x-ray and gamma-ray spectroscopy, it is desirable to have detectors with high energy resolution and high absorption efficiency. At LLNL, we have developed superconducting tunnel junction-based single photon x-ray detectors with thin film absorbers that have achieved these goals for photon energies up to 1 keV. However, for energies above 1 keV, the absorption efficiency of these thin-film detectors decreases drastically. We are developing the use of high-purity superconducting bulk materials as microcalorimeter absorbers for high-energy x-rays and gamma rays. The increase in absorber temperature due to incident photons is sensed by a superconducting transition-edge sensor (TES) composed of a Mo/Cu multilayer thin film. Films of Mo and Cu are mutually insoluble and therefore very stable and can be annealed. The multilayer structure allows scaling in thickness to optimize heat capacity and normal state resistance. We measured an energy resolution of 70 eV for 60 keV incident gamma-rays with a 1 x 1 x 0.25 mm{sup 3} Sn absorber. We present x-ray and gamma-ray results from this detector design with a Sn absorber. We also propose the use of an active negative feedback voltage bias to improve the performance of our detector and show preliminary results.

  17. Subgap Absorption in Conjugated Polymers

    Science.gov (United States)

    Sinclair, M.; Seager, C. H.; McBranch, D.; Heeger, A. J; Baker, G. L.

    1991-01-01

    Along with X{sup (3)}, the magnitude of the optical absorption in the transparent window below the principal absorption edge is an important parameter which will ultimately determine the utility of conjugated polymers in active integrated optical devices. With an absorptance sensitivity of conjugated polymers poly(1,4-phenylene-vinylene) (and derivitives) and polydiacetylene-4BCMU in the spectral region from 0.55 eV to 3 eV. Our spectra show that the shape of the absorption edge varies considerably from polymer to polymer, with polydiacetylene-4BCMU having the steepest absorption edge. The minimum absorption coefficients measured varied somewhat with sample age and quality, but were typically in the range 1 cm{sup {minus}1} to 10 cm{sup {minus}1}. In the region below 1 eV, overtones of C-H stretching modes were observed, indicating that further improvements in transparency in this spectral region might be achieved via deuteration of fluorination.

  18. Gaseous Detectors: Charged Particle Detectors - Particle Detectors and Detector Systems

    CERN Document Server

    Hilke, H J

    2011-01-01

    Gaseous Detectors in 'Charged Particle Detectors - Particle Detectors and Detector Systems', part of 'Landolt-Börnstein - Group I Elementary Particles, Nuclei and Atoms: Numerical Data and Functional Relationships in Science and Technology, Volume 21B1: Detectors for Particles and Radiation. Part 1: Principles and Methods'. This document is part of Part 1 'Principles and Methods' of Subvolume B 'Detectors for Particles and Radiation' of Volume 21 'Elementary Particles' of Landolt-Börnstein - Group I 'Elementary Particles, Nuclei and Atoms'. It contains the Subsection '3.1.2 Gaseous Detectors' of Section '3.1 Charged Particle Detectors' of Chapter '3 Particle Detectors and Detector Systems' with the content: 3.1.2 Gaseous Detectors 3.1.2.1 Introduction 3.1.2.2 Basic Processes 3.1.2.2.1 Gas ionization by charged particles 3.1.2.2.1.1 Primary clusters 3.1.2.2.1.2 Cluster size distribution 3.1.2.2.1.3 Total number of ion pairs 3.1.2.2.1.4 Dependence of energy deposit on particle velocity 3.1.2.2.2 Transport of...

  19. Position-sensitive superconductor detectors

    Science.gov (United States)

    Kurakado, M.; Taniguchi, K.

    2016-12-01

    Superconducting tunnel junction (STJ) detectors and superconducting transition- edge sensors (TESs) are representative superconductor detectors having energy resolutions much higher than those of semiconductor detectors. STJ detectors are thin, thereby making it suitable for detecting low-energy X rays. The signals of STJ detectors are more than 100 times faster than those of TESs. By contrast, TESs are microcalorimeters that measure the radiation energy from the change in the temperature. Therefore, signals are slow and their time constants are typically several hundreds of μs. However, TESs possess excellent energy resolutions. For example, TESs have a resolution of 1.6 eV for 5.9-keV X rays. An array of STJs or TESs can be used as a pixel detector. Superconducting series-junction detectors (SSJDs) comprise multiple STJs and a single-crystal substrate that acts as a radiation absorber. SSJDs are also position sensitive, and their energy resolutions are higher than those of semiconductor detectors. In this paper, we give an overview of position-sensitive superconductor detectors.

  20. Diffraction Anomalous Near-Edge Structure

    Science.gov (United States)

    Moltaji, Habib O., Jr.

    1995-11-01

    To determine the atomic structure about atom of an element in a sample of a condensed multicomponent single crystal, contrast radiation is proposed with the use of Diffraction Anomalous Near-Edge Structure (DANES), which combines the long-range order sensitivity of the x-ray diffraction and short-range order of the x-ray absorption near-edge techniques. This is achieved by modulating the photon energy of the x-ray beam incident on the sample over a range of energies near an absorption edge of the selected element. Due to anomalous dispersion, x-ray diffraction, and x-ray absorption, the DANES intensity with respect to the selected element is obtained in a single experiment. I demonstrate that synchrotron DANES measurements for the single crystal of thin film and the powder samples and provide the same local atomic structural information as the x-ray absorption near-edge with diffraction condition and can be used to provide enhanced site selectivity. I demonstrate calculations of DAFS intensity and measurements of polarized DANES and XANES intensity.

  1. High-resolution three-dimensional imaging of a depleted CMOS sensor using an edge Transient Current Technique based on the Two Photon Absorption process (TPA-eTCT)

    CERN Document Server

    García, Marcos Fernández; Echeverría, Richard Jaramillo; Moll, Michael; Santos, Raúl Montero; Moya, David; Pinto, Rogelio Palomo; Vila, Iván

    2016-01-01

    For the first time, the deep n-well (DNW) depletion space of a High Voltage CMOS sensor has been characterized using a Transient Current Technique based on the simultaneous absorption of two photons. This novel approach has allowed to resolve the DNW implant boundaries and therefore to accurately determine the real depleted volume and the effective doping concentration of the substrate. The unprecedented spatial resolution of this new method comes from the fact that measurable free carrier generation in two photon mode only occurs in a micrometric scale voxel around the focus of the beam. Real three-dimensional spatial resolution is achieved by scanning the beam focus within the sample.

  2. Stability of edge states and edge magnetism in graphene nanoribbons

    OpenAIRE

    Kunstmann, Jens; Özdoğan, Cem; Quandt, Alexander; Fehske, Holger

    2010-01-01

    We critically discuss the stability of edge states and edge magnetism in zigzag edge graphene nanoribbons (ZGNRs). We point out that magnetic edge states might not exist in real systems, and show that there are at least three very natural mechanisms - edge reconstruction, edge passivation, and edge closure - which dramatically reduce the effect of edge states in ZGNRs or even totally eliminate them. Even if systems with magnetic edge states could be made, the intrinsic magnetism would not be ...

  3. Adaptively wavelet-based image denoising algorithm with edge preserving

    Institute of Scientific and Technical Information of China (English)

    Yihua Tan; Jinwen Tian; Jian Liu

    2006-01-01

    @@ A new wavelet-based image denoising algorithm, which exploits the edge information hidden in the corrupted image, is presented. Firstly, a canny-like edge detector identifies the edges in each subband.Secondly, multiplying the wavelet coefficients in neighboring scales is implemented to suppress the noise while magnifying the edge information, and the result is utilized to exclude the fake edges. The isolated edge pixel is also identified as noise. Unlike the thresholding method, after that we use local window filter in the wavelet domain to remove noise in which the variance estimation is elaborated to utilize the edge information. This method is adaptive to local image details, and can achieve better performance than the methods of state of the art.

  4. Direct contact vs. solvent-shared ion pairs in nicl2 electrolytesmonitored by multiplet effects at the ni(ii) l-edge x-ray absorptionDOC_XNOTE=Published by BESSY, Germany in collaboration with LawrenceBerkeley National Laboratory staff.

    Energy Technology Data Exchange (ETDEWEB)

    Aziz, E.F.; Eisebitt, S.; Eberhardt, W.; de Groot, F.; Chiou,J.W.; Dong, C.L.; Guo, J.-H.

    2007-03-29

    We investigate the local electronic structure in aqueous NiCl{sub 2} electrolytes by Ni L edge x-ray absorption spectroscopy. The experimental findings are interpreted in conjunction with multiplet calculations of the electronic structure and the resulting spectral shape. In contrast to the situation in the solid, the electronic structure in the electrolyte reflects the absence of direct contact Ni-Cl ion pairs. We observe a systematic change of the intensity ratio of singlet and triplet-related spectral features as a function of electrolyte concentration. These changes can be described theoretically by a changed weight of transition matrix contributions with different symmetry. We interpret these findings as being due to progressive distortions of the local symmetry induced by solvent-shared ion pairs.

  5. Plasmon enhanced broadband optical absorption in ultrathin silicon nanobowl array for photoactive devices applications

    Science.gov (United States)

    Sun, Rui-Nan; Peng, Kui-Qing; Hu, Bo; Hu, Ya; Zhang, Fu-Qiang; Lee, Shuit-Tong

    2015-07-01

    Both photonic and plasmonic nanostructures are key optical components of photoactive devices for light harvesting, enabling solar cells with significant thickness reduction, and light detectors capable of detecting photons with sub-band gap energies. In this work, we study the plasmon enhanced broadband light absorption and electrical properties of silicon nanobowl (SiNB) arrays. The SiNB-metal photonic-plasmonic nanostructure-based devices exhibited superior light-harvesting ability across a wide range of wavelengths up to the infrared regime well below the band edge of Si due to effective optical coupling between the SiNB array and incident sunlight, as well as electric field intensity enhancement around metal nanoparticles due to localized surface plasmon resonance. The photonic-plasmonic nanostructure is expected to result in infrared-light detectors and high-efficiency solar cells by extending light-harvesting to infrared frequencies.

  6. Nonequilibrium superconducting detectors

    Science.gov (United States)

    Cristiano, R.; Ejrnaes, M.; Esposito, E.; Lisitskyi, M. P.; Nappi, C.; Pagano, S.; Perez de Lara, D.

    2006-03-01

    Nonequilibrium superconducting detectors exploit the early stages of the energy down cascade which occur after the absorption of radiation. They operate on a short temporal scale ranging from few microseconds down to tens of picoseconds. In such a way they provide fast counting capability, high time discrimination and also, for some devices, energy sensitivity. Nonequilibrium superconducting detectors are developed for their use both in basic science and in practical applications for detection of single photons or single ionized macromolecules. In this paper we consider two devices: distributed readout imaging detectors (DROIDs) based on superconducting tunnel junctions (STJs), which are typically used for high-speed energy spectroscopy applications, and hot-electron superconductive detectors (HESDs), which are typically used as fast counters and time discriminators. Implementation of the DROID geometry to use a single superconductor is discussed. Progress in the fabrication technology of NbN nanostructured HESDs is presented. The two detectors share the high sensitivity that makes them able to efficiently detect even single photons down to infrared energy.

  7. Nonequilibrium superconducting detectors

    Energy Technology Data Exchange (ETDEWEB)

    Cristiano, R [CNR-Istituto di Cibernetica E. Caianiello, 80078 Pozzuoli (Namibia) (Italy); Ejrnaes, M [CNR-Istituto di Cibernetica E. Caianiello, 80078 Pozzuoli (Namibia) (Italy); INFN Sezione di Napoli, 80126 Naples (Italy); Esposito, E [CNR-Istituto di Cibernetica E. Caianiello, 80078 Pozzuoli (Namibia) (Italy); Lisitskyi, M P [CNR-Istituto di Cibernetica E. Caianiello, 80078 Pozzuoli (Namibia) (Italy); Nappi, C [CNR-Istituto di Cibernetica E. Caianiello, 80078 Pozzuoli (Namibia) (Italy); Pagano, S [CNR-Istituto di Cibernetica E. Caianiello, 80078 Pozzuoli (Namibia) (Italy); Dipartimento di Fisica, Universita di Salerno, 84081 Baronissi (Saudi Arabia) (Italy); Perez de Lara, D [CNR-Istituto di Cibernetica E. Caianiello, 80078 Pozzuoli (Namibia) (Italy)

    2006-03-15

    Nonequilibrium superconducting detectors exploit the early stages of the energy down cascade which occur after the absorption of radiation. They operate on a short temporal scale ranging from few microseconds down to tens of picoseconds. In such a way they provide fast counting capability, high time discrimination and also, for some devices, energy sensitivity. Nonequilibrium superconducting detectors are developed for their use both in basic science and in practical applications for detection of single photons or single ionized macromolecules. In this paper we consider two devices: distributed readout imaging detectors (DROIDs) based on superconducting tunnel junctions (STJs), which are typically used for high-speed energy spectroscopy applications, and hot-electron superconductive detectors (HESDs), which are typically used as fast counters and time discriminators. Implementation of the DROID geometry to use a single superconductor is discussed. Progress in the fabrication technology of NbN nanostructured HESDs is presented. The two detectors share the high sensitivity that makes them able to efficiently detect even single photons down to infrared energy.

  8. Total light absorption in graphene

    CERN Document Server

    Thongrattanasiri, Sukosin; de Abajo, F Javier Garcia

    2011-01-01

    We demonstrate that 100% light absorption can take place in a single patterned sheet of doped graphene. General analysis shows that a planar array of small lossy particles exhibits full absorption under critical-coupling conditions provided the cross section of each individual particle is comparable to the area of the lattice unit-cell. Specifically, arrays of doped graphene nanodisks display full absorption when supported on a substrate under total internal reflection, and also when lying on a dielectric layer coating a metal. Our results are relevant for infrared light detectors and sources, which can be made tunable via electrostatic doping of graphene.

  9. Pixel Detectors

    OpenAIRE

    Wermes, Norbert

    2005-01-01

    Pixel detectors for precise particle tracking in high energy physics have been developed to a level of maturity during the past decade. Three of the LHC detectors will use vertex detectors close to the interaction point based on the hybrid pixel technology which can be considered the state of the art in this field of instrumentation. A development period of almost 10 years has resulted in pixel detector modules which can stand the extreme rate and timing requirements as well as the very harsh...

  10. Characterization of heterogeneous nickel sites in CO dehydrogenase from Clostridium thermoaceticum by nickel L-edge x-ray spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Ralston, C.Y. [Univ. of California, Davis, CA (United States); Kumar, M.; Ragsdale, S.W. [Univ. of Nebraska, Lincoln, NE (United States)] [and others

    1997-04-01

    L-edge x-ray absorption spectroscopy (XAS) is a useful spectroscopic technique for determining the electronic state of transition metals. For first row transition metals, the L-edge represents a transition from 2p core levels to 3d valence levels. Coulomb and exchange interactions between the core hole and 3d valence electrons make the L-edge sensitive to the number and configuration of 3d electrons, hence to the metal spin state and oxidation state. The authors have used L-edge XAS to characterize the Ni sites in the carbon monoxide dehydrogenase (CODH) enzyme from Clostridium thermoaceticum. This CODH catalyzes both CO oxidation and acetyl-CoA synthesis at two Ni and Fe containing centers, C and A, respectively. Since the enzyme exhibits complex EPR signals that never integrate to one spin per Ni, there is evidence for heterogeneity in the types of Ni present. The Ni L-edge protein spectra were recorded at ALS beamline 9.3.2. The photon energy resolutions used for protein samples and for Ni model compound spectra were 350 and 270 meV respectively. During data collection the sample chamber was maintained at less than 5{times}10{sup {minus}9} Torr using a helium cryopump. Model compound spectra were measured using total electron yield detection, while protein spectra were recorded using fluorescence detection with a windowless 13-element germanium detector, and were calibrated using the total electron yield spectrum of NiF{sub 2} or NiO. Each protein spectrum presented represents the sum of approximately 40 15-minute scans. The authors have found that by using L-edge XAS they are able to distinguish between different spin and oxidation states of Ni compounds. They have used this result to characterize the Ni containing CODH protein in various states. The L-edge spectra are consistent with other results showing that when CODH is reacted with CO, the metal centers undergo reduction.

  11. Light absorption of silicon nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Gondorf, Andreas; Meier, Cedrik; Luettjohann, Stephan; Offer, Matthias; Lorke, Axel [Experimental Physics, University of Duisburg-Essen (Germany); Wiggers, Hartmut [Combustion and Gas Dynamics, University of Duisburg-Essen (Germany)

    2007-07-01

    We have studied silicon nanoparticles fabricated by gas-phase condensation and in-flight sintering using absorption and photoluminescence (PL) spectroscopy. We observe a quantum size effect in PL as well as in absorption spectroscopy. From an analysis of the absorption spectra we are able to identify the character of the band gap of the nanoparticles as indirect. This result is supported by measurements of the decay time of the photoluminescence of excitons. The decay time is four orders of magnitude larger than in direct semiconductors. Moreover, we are able to observe the influence of the particle size distribution in the absorption spectra. The size distribution follows the lognormal distribution. In order to explain the surprisingly small dependence of the absorption edge on the mean particle diameter, we discuss a model which takes into acount the lognormal size distribution.

  12. On-chip, photon-number-resolving, telecom-band detectors for scalable photonic information processing

    CERN Document Server

    Gerrits, Thomas; Gates, James C; Lita, Adriana E; Metcalf, Benjamin J; Calkins, Brice; Tomlin, Nathan A; Fox, Anna E; Linares, Antía Lamas; Spring, Justin B; Langford, Nathan K; Mirin, Richard P; Smith, Peter G R; Walmsley, Ian A; Nam, Sae Woo

    2011-01-01

    Integration is currently the only feasible route towards scalable photonic quantum processing devices that are sufficiently complex to be genuinely useful in computing, metrology, and simulation. Embedded on-chip detection will be critical to such devices. We demonstrate an integrated photon-number resolving detector, operating in the telecom band at 1550 nm, employing an evanescently coupled design that allows it to be placed at arbitrary locations within a planar circuit. Up to 5 photons are resolved in the guided optical mode via absorption from the evanescent field into a tungsten transition-edge sensor. The detection efficiency is 7.2 \\pm 0.5 %. The polarization sensitivity of the detector is also demonstrated. Detailed modeling of device designs shows a clear and feasible route to reaching high detection efficiencies.

  13. On-chip, photon-number-resolving, telecommunication-band detectors for scalable photonic information processing

    Energy Technology Data Exchange (ETDEWEB)

    Gerrits, Thomas; Lita, Adriana E.; Calkins, Brice; Tomlin, Nathan A.; Fox, Anna E.; Linares, Antia Lamas; Mirin, Richard P.; Nam, Sae Woo [National Institute of Standards and Technology, Boulder, Colorado, 80305 (United States); Thomas-Peter, Nicholas; Metcalf, Benjamin J.; Spring, Justin B.; Langford, Nathan K.; Walmsley, Ian A. [Clarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU (United Kingdom); Gates, James C.; Smith, Peter G. R. [Optoelectronics Research Centre, University of Southampton, Highfield SO17 1BJ (United Kingdom)

    2011-12-15

    Integration is currently the only feasible route toward scalable photonic quantum processing devices that are sufficiently complex to be genuinely useful in computing, metrology, and simulation. Embedded on-chip detection will be critical to such devices. We demonstrate an integrated photon-number-resolving detector, operating in the telecom band at 1550 nm, employing an evanescently coupled design that allows it to be placed at arbitrary locations within a planar circuit. Up to five photons are resolved in the guided optical mode via absorption from the evanescent field into a tungsten transition-edge sensor. The detection efficiency is 7.2{+-}0.5 %. The polarization sensitivity of the detector is also demonstrated. Detailed modeling of device designs shows a clear and feasible route to reaching high detection efficiencies.

  14. Metal Detectors.

    Science.gov (United States)

    Harrington-Lueker, Donna

    1992-01-01

    Schools that count on metal detectors to stem the flow of weapons into the schools create a false sense of security. Recommendations include investing in personnel rather than hardware, cultivating the confidence of law-abiding students, and enforcing discipline. Metal detectors can be quite effective at afterschool events. (MLF)

  15. Optical Detectors

    Science.gov (United States)

    Tabbert, Bernd; Goushcha, Alexander

    Optical detectors are applied in all fields of human activities from basic research to commercial applications in communication, automotive, medical imaging, homeland security, and other fields. The processes of light interaction with matter described in other chapters of this handbook form the basis for understanding the optical detectors physics and device properties.

  16. Current-biased Transition-edge Sensors Based on Re-entrant Superconductors

    Science.gov (United States)

    Gulian, A.; Nikoghosyan, V.; Tollaksen, J.; Vardanyan, V.; Kuzanyan, A.

    Transition-edge sensors are widely recognized as one of the most sensitive tools for the photon and particles detection in many areas, from astrophysics to quantum computing. Their application became practical after understanding that rather than being biased in a constant current mode, they should be biased in a constant voltage mode. Despite the methods of voltage biasing of these sensors are well developed since then, generally the current biasing is more convenient for superconducting circuits. Thus transition-edge sensors designed inherently to operate in the current-biased mode are desirable. We developed a design for such detectors based on re-entrant superconductivity. In this case constant current biasing takes place in the normal state, below the superconducting transition, so that following the absorption of a photon it does not yield a latching. Rather, the sensor gains energy and shifts towards the lower resistant (e.g., superconducting) state, and then cools down faster (since Joule heating is now reduced), and resets in a natural way to be able to detect the next photon. We prototyped this kind of transition edge sensors and tested them operational in accordance with the outlined physics. The samples used in experiments were modified compositions of YBCO-superconductors in a ceramic form (which, as we discovered, reproducibly demonstrates re-entrant superconductivity). In this presentation we report their composition, methods of preparation, and the detection results. This approach, in some areas, may have practical advantage over the traditional voltage-biased devices.

  17. Calibration of Li-glass Detector Efficiency

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Li-glass detector will be used to measure the flux of neutron beam in Gamma-ray Total Absorption Facility(GTAF). We have calibrated the detection efficiency of Li-glass detector in 5SDH-2 accelerator. The beam of neutron was produced by the reaction 7Li

  18. Edge physics Simulations

    Institute of Scientific and Technical Information of China (English)

    X.Q. Xu; C.S. Chang

    2007-01-01

    @@ The plasma edge includes the pedestal, scrape-off, and divertor regions. A complete edge physics should deal with the plasma, atomic, and the plasma-wall interaction phenomena. The edge provides the source of plasma through ionization of the incoming neutral particles and source of impurity through the wall sputtering. Edge plasma sets a boundary condition for the core confinement physics. Importance of the edge plasma has been elevated to the top list of the ITER physics research needs due to the necessity of the self-organized plasma pedestal and its destruction by edge localized mode activities. Extrapolation of the present tokamak data base predicts that a sufficient pedestal height is a necessary condition for the success of ITER.

  19. Tasting edge effects

    CERN Document Server

    Bocquet, L

    2006-01-01

    We show that the baking of potato wedges constitutes a crunchy example of edge effects, which are usually demonstrated in electrostatics. A simple model of the diffusive transport of water vapor around the potato wedges shows that the water vapor flux diverges at the sharp edges in analogy with its electrostatic counterpart. This increased evaporation at the edges leads to the crispy taste of these parts of the potatoes.

  20. Tasting edge effects

    Science.gov (United States)

    Bocquet, Lydéric

    2007-02-01

    We show that the baking of potato wedges constitutes a crunchy example of edge effects, which are usually demonstrated in electrostatics. A simple model of the diffusive transport of water vapor around the potato wedges shows that the water vapor flux diverges at the sharp edges in analogy with its electrostatic counterpart. This increased evaporation at the edges leads to the crispy taste of these parts of the potatoes.

  1. AUTOMATED EDGE DETECTION USING CONVOLUTIONAL NEURAL NETWORK

    Directory of Open Access Journals (Sweden)

    Mohamed A. El-Sayed

    2013-11-01

    Full Text Available The edge detection on the images is so important for image processing. It is used in a various fields of applications ranging from real-time video surveillance and traffic management to medical imaging applications. Currently, there is not a single edge detector that has both efficiency and reliability. Traditional differential filter-based algorithms have the advantage of theoretical strictness, but require excessive post-processing. Proposed CNN technique is used to realize edge detection task it takes the advantage of momentum features extraction, it can process any input image of any size with no more training required, the results are very promising when compared to both classical methods and other ANN based methods

  2. AN APPROACH TO SUPPRESS SPECKLE NOISE AND ENHANCE EDGE

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Anisotropic diffusion has good effect on reducing noise and preserving edge, but it may lose some details due to the blocky effect and can not suppress speckle effectively. The Laplacian factor is used to process the observed image which is considered as a piecewise planar image, so the Fourth Order Anisotropic Diffusion (FOAD) can avoid the blocky effect. The edge is preserved and enhanced by the Line Edge Detector (LED) based on stick technique and hypothesis test optimizing method. An approach called the Fourth Order Anisotropic Diffusion and Edge Enhancing (FOADEE), where the LED is combined with the FOAD, is presented. For quantitative evaluation and comparison with the LED, the FOAD and the FOADEE, two parameters as measure of the noise suppression and edge preservation are introduced. It is proved that the novel method can not only suppress speckle prominently but also preserve even enhance edge and useful details effectively by applying it to the phantoms and tissue images.

  3. Microcalorimeter Detector

    Data.gov (United States)

    Federal Laboratory Consortium — The NIST transition edge sensor microcalorimeter is energy dispersive x-ray spectrometer capable of ~5 eV resolution over a range of energies from hundreds to eV to...

  4. Edge location in the automatic track system of NGW with small slope angle

    Institute of Scientific and Technical Information of China (English)

    王朋; 张富巨; 刘重庆

    2002-01-01

    Based on the analysis of the groove images in gas metal arc welding with small slope angle, a new algorithm of the groove edge location is presented. The groove edge was effectively detected by combining Roberts Detector with the general non-linear gradient operator. In addition, using Norton Quadratic Polynomial Interpolation, the edge location precision reached sub-pixel level. The experimental results show that the edge detection system works well under the condition of short transfer arc welding.

  5. DUMAND detector

    CERN Multimedia

    This object is one of the 256 other detectors of the DUMAND (Deep Underwater Muon And Neutrino Detection) experiment. The goal of the experiment was the construction of the first deep ocean high energy neutrino detector, to be placed at 4800 m depth in the Pacific Ocean off Keahole Point on the Big Island of Hawaii. A few years ago, a European conference with Cosmic experiments was organized at CERN as they were projects like DUMAND in Hawaii. Along with the conference, a temporary exhibition was organised as well. It was a collaboration of institutions from Germany, Japan, Switzerland and the U.S.A. CERN had borrowed equipment and objects from different institutes around the world, including this detector of the DUMAND experiment. Most of the equipment were sent back to the institutes, however this detector sphere was offered to a CERN member of the personnel.

  6. On Edge Detection,

    Science.gov (United States)

    1984-08-01

    T. 0. "On boundary detection." A. I. Memo 183, MIT, 1980. Hildreth, E. C. "Implementation of a theory of edge detection ." A. /. Memo 579, MIT, 1980...Detection." IEEE Trans. PAMI, 6, 678-680, 1983. Marr, 0. C. and Hildreth, E. C, " Theory of edge detection ." Proc. R. Soc. Lond. B, 207, 187-217, 1980. Marr

  7. Measurement of Compton edge position in low-Z scintillators

    Energy Technology Data Exchange (ETDEWEB)

    Swiderski, Lukasz, E-mail: l.swiderski@ipj.gov.p [Department of Nuclear Detectors and Electronics, Soltan Institute for Nuclear Studies, Otwock-Swierk (Poland); Moszynski, Marek; Czarnacki, Wieslaw; Iwanowska, Joanna; Syntfeld-Kazuch, Agnieszka; Szczesniak, Tomasz [Department of Nuclear Detectors and Electronics, Soltan Institute for Nuclear Studies, Otwock-Swierk (Poland); Pausch, Guntram; Plettner, Cristina; Roemer, Katja [ICx Technologies GmbH, Piepersberg 12, Solingen (Germany)

    2010-03-15

    A method based on a Compton coincidence technique was applied to measure in a wide energy range the position of Compton edge in organic scintillators. The experimental setup comprised a High Purity Germanium (HPGe) detector and a tested scintillator coupled to a PMT. The detectors were set in a face-to-face geometry and the source was placed between them. Thus gating on events backscattered in the tested scintillator and detected in HPGe allowed measuring of Compton edge position for a given {gamma}-ray energy. The presented method provides a valuable tool for energy calibration of low-Z scintillators.

  8. Comparative characterisation study of a LaBr$_3$(Ce scintillation crystal in two surface wrapping scenarios: absorptive and reflective

    Directory of Open Access Journals (Sweden)

    Saad eAldawood

    2015-12-01

    Full Text Available The properties of a 50$times$50$times$30 mm$^3$ monolithic LaBr$_3$:Ce scintillator crystal coupled to a position-sensitive multi-anode photomultiplier (PMT, Hamamatsu H9500, representing the absorbing detector of a Compton camera under study for online ion (proton beam range verification in hadron-therapy, was evaluated in combination with either absorptive and reflective crystal surface coating. This study covered an assessment of the energy and position dependent energy resolution, exhibiting a factor of 2.5-3.5 improvement for the reflectively wrapped crystal at 662 keV. The spatial dependency was investigated using a collimated $^{137}$Cs source, showing a steep degradation of the energy resolution at the edges and corners of the absorptively wrapped crystal. Furthermore, the time resolution was determined to be 273 ps (FWHM and 536 ps (FWHM with reflective and absorptive coating, respectively, using a $^{60}$Co source. In contrast, the light spread function (LSF of the light amplitude distribution on the PMT segments improved for the absorptively wrapped detector. Both wrapping modalities showed almost no differences in the energy-dependent photopeak detection efficiency.

  9. Comparative Characterization Study of a LaBr3(Ce) Scintillation Crystal in Two Surface Wrapping Scenarios: Absorptive and Reflective

    Science.gov (United States)

    Aldawood, Saad; Castelhano, Ines; Gernhäuser, Roman; Van Der Kolff, Hugh; Lang, Christian; Liprandi, Silvia; Lutter, Rudolf; Maier, Ludwig; Marinšek, Tim; Schaart, Dennis R.; Parodi, Katia; Thirolf, Peter G.

    2015-01-01

    The properties of a 50 mm × 50 mm × 30 mm monolithic LaBr3:Ce scintillator crystal coupled to a position-sensitive multi-anode photomultiplier (PMT, Hamamatsu H9500), representing the absorbing detector of a Compton camera under study for online ion (proton) beam range verification in hadron therapy, was evaluated in combination with either absorptive or reflective crystal surface coating. This study covered an assessment of the energy and position-dependent energy resolution, exhibiting a factor of 2.5–3.5 improvement for the reflectively wrapped crystal at 662 keV. The spatial dependency was investigated using a collimated 137Cs source, showing a steep degradation of the energy resolution at the edges and corners of the absorptively wrapped crystal. Furthermore, the time resolution was determined to be 273 ps (FWHM) and 536 ps (FWHM) with reflective and absorptive coating, respectively, using a 60Co source. In contrast, the light spread function (LSF) of the light amplitude distribution on the PMT segments improved for the absorptively wrapped detector. Both wrapping modalities showed almost no differences in the energy-dependent photopeak detection efficiency. PMID:26697405

  10. Study of terahertz pulses at an edge

    Institute of Scientific and Technical Information of China (English)

    Zaijun Xi; Xiaohan Yu; Tiqiao Xiao

    2008-01-01

    The propagation behaviour of terahertz (THz) pulses at an edge is characterized. The phenomenon that the amplitude oscillates periodically in the frequency spectrum is similar to Young's interference, if the absorption effect is neglected. The oscillation cycle is shorter for a thicker sample. THz pulses at anedge are an alyzed by the broadband Huygens-Fresnel diffraction integral. The experimental results are in agreement with the simulation results approximately. The simulation errors are also analyzed.

  11. Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl 6 2– (M = Ti, Zr, Hf, U) and UOCl 5 Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory

    Energy Technology Data Exchange (ETDEWEB)

    Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R.; Boland, Kevin S.; Clark, David L.; Conradson, Steven D.; Kozimor, Stosh A.; Martin, Richard L.; Schwarz, Daniel E.; Shuh, David K.; Wagner, Gregory L.; Wilkerson, Marianne P.; Wolfsberg, Laura E.; Yang, Ping

    2012-03-28

    Chlorine K-edge X-ray absorption spectroscopy (XAS) and ground-state and time-dependent hybrid density functional theory (DFT) were used to probe electronic structure for O{sub h}-MCl{sub 6}{sup 2-}(M = Ti, Zr, Hf, U) and C{sub 4v}-UOCl{sub 5}{sup -}, and to determine the relative contributions of valence 3d, 4d, 5d, 6d, and 5f orbitals in M-Cl bonding. Spectral interpretations were guided by time-dependent DFT calculated transition energies and oscillator strengths, which agree well with the experimental XAS spectra. The data provide new spectroscopic evidence for the involvement of both 5f and 6d orbitals in actinide-ligand bonding in UCl{sub 6}{sup 2-}. For the MCl{sub 6}{sup 2-}, where transitions into d orbitals of t{sub 2g} symmetry are spectroscopically resolved for all four complexes, the experimentally determined Cl 3p character per M-Cl bond increases from 8.3(4)% (TiCl{sub 6}{sup 2-}) to 10.3(5)% (ZrCl{sub 6}{sup 2-}), 12(1)% (HfCl{sub 6}{sup 2-}), and 26 18(1)% (UCl{sub 6}{sup 2-}). Chlorine K-edge XAS spectra of UOCl{sub 5}{sup -} provide additional insights into the transition assignments by 27 lowering the symmetry to C{sub 4v}, where five pre-edge transitions into both 5f and 6d orbitals are observed. For UCl{sub 6}{sup 2-}, the XAS data 28 suggest that orbital mixing associated with the U 5f orbitals is considerably lower than that of the U 6d orbitals. For both UCl{sub 6}{sup 2-}29 and UOCl{sub 5}{sup -}, the ground-state DFT calculations predict a larger 5f contribution to bonding than is determined experimentally. 30 These findings are discussed in the context of conventional theories of covalent bonding for d- and f-block metal complexes.

  12. Doppler lidar wind measurement with the edge technique

    Science.gov (United States)

    Korb, C. Laurence; Gentry, Bruce M.

    1992-01-01

    The edge technique is a new and powerful method for measuring small frequency shifts. Range resolved lidar measurements of winds can be made with high accuracy and high vertical resolution using the edge technique to measure the Doppler shift of an atmospheric backscattered signal from a pulsed laser. The edge technique can be used at near-infrared or visible wavelengths using well developed solid state lasers and detectors with various edge filters. In the edge technique, the laser frequency is located on the steep slope of the spectral response function of a high resolution optical filter. Due to the steep slope of the edge, very small frequency shifts cause large changes in measured signal. The frequency of the outgoing laser pulse is determined by measuring its location on the edge of the filter. This is accomplished by sending a small portion of the beam to the edge detection setup where the incoming light is split into two channels - an edge filter and an energy monitor channel. The energy monitor signal is used to normalize the edge filter signal for magnitude. The laser return backscattered from the atmosphere is collected by a telescope and directed through the edge detection setup to determine its frequency (location on the edge) in a similar manner for each range element. The Doppler shift, and thus the wind, is determined from a differential measurement of the frequency of the outgoing laser pulse and the frequency of the laser return backscattered from the atmosphere. We have conducted simulations of the performance of an edge lidar system using an injection seeded pulsed Nd:YAG laser at 1.06 microns. The central fringe of a Fabry-Perot etalon is used as a high resolution edge filter to measure the shift of the aerosol return.

  13. First test of cold edgeless silicon microstrip detectors

    Energy Technology Data Exchange (ETDEWEB)

    Avati, V.; Boccone, V.; Borer, K.; Bozzo, M. E-mail: marco.bozzo@cern.ch; Capra, R.; Casagrande, L.; Eggert, K.; Heijne, E.; Klauke, S.; Li, Z.; Maeki, T.; Morelli, A.; Oljemark, F.; Palmieri, V.G.; Perea-Solano, B.; Tapprogge, S

    2004-02-01

    Silicon microstrip detectors will provide the forward tracking in the TOTEM experiment at the LHC. To allow efficient tracking closest to the beam ({approx}1 mm) these detectors should be sensitive up to their physical edge (i.e. edgeless). Edgeless (without guard rings) microstrip planar detectors can be operated at cryogenic temperatures (about 130 deg. K) where leakage currents due to the active edge are drastically reduced. A silicon microstrip prototype, cut perpendicular to the strips, has been tested with a pion beam at CERN to study its efficiency close to the edge by using reference tracks from a simple silicon telescope. Results indicate that the detector measures tracks with good efficiency up to the physical edge of the silicon.

  14. First test of cold edgeless silicon microstrip detectors

    CERN Document Server

    Avati, V; Borer, K; Bozzo, M; Capra, R; Casagrande, L; Eggert, Karsten; Heijne, Erik H M; Klauke, S; Li, Z; Mäki, T; Morelli, A; Oljemark, F; Palmieri, V G; Perea-Solano, B; Tapprogge, Stefan

    2004-01-01

    Silicon microstrip detectors will provide the forward tracking in the TOTEM experiment at the LHC. To allow efficient tracking closest to the beam ( approximately equals 1 mm) these detectors should be sensitive up to their physical edge (i.e. edgeless). Edgeless (without guard rings) microstrip planar detectors can be operated at cryogenic temperatures (about 130 degree K) where leakage currents due to the active edge are drastically reduced. A silicon microstrip prototype, cut perpendicular to the strips, has been tested with a pion beam at CERN to study its efficiency close to the edge by using reference tracks from a simple silicon telescope. Results indicate that the detector measures tracks with good efficiency up to the physical edge of the silicon.

  15. First test of cold edgeless silicon microstrip detectors

    Science.gov (United States)

    Avati, V.; Boccone, V.; Borer, K.; Bozzo, M.; Capra, R.; Casagrande, L.; Eggert, K.; Heijne, E.; Klauke, S.; Li, Z.; Mäki, T.; Morelli, A.; Oljemark, F.; Palmieri, V. G.; Perea-Solano, B.; Tapprogge, S.

    2004-02-01

    Silicon microstrip detectors will provide the forward tracking in the TOTEM experiment at the LHC. To allow efficient tracking closest to the beam (≈1 mm) these detectors should be sensitive up to their physical edge (i.e. edgeless). Edgeless (without guard rings) microstrip planar detectors can be operated at cryogenic temperatures (about 130° K) where leakage currents due to the active edge are drastically reduced. A silicon microstrip prototype, cut perpendicular to the strips, has been tested with a pion beam at CERN to study its efficiency close to the edge by using reference tracks from a simple silicon telescope. Results indicate that the detector measures tracks with good efficiency up to the physical edge of the silicon.

  16. Casimir edge effects

    CERN Document Server

    Gies, H; Gies, Holger; Klingmuller, Klaus

    2006-01-01

    We compute Casimir forces in open geometries with edges, involving parallel as well as perpendicular semi-infinite plates. We focus on Casimir configurations which are governed by a unique dimensional scaling law with a universal coefficient. With the aid of worldline numerics, we determine this coefficient for various geometries for the case of scalar-field fluctuations with Dirichlet boundary conditions. Our results facilitate an estimate of the systematic error induced by the edges of finite plates, for instance, in a standard parallel-plate experiment. The Casimir edge effects for this case can be reformulated as an increase of the effective area of the configuration.

  17. Adobe Edge Quickstart Guide

    CERN Document Server

    Labrecque, Joseph

    2012-01-01

    Adobe Edge Quickstart Guide is a practical guide on creating engaging content for the Web with Adobe's newest HTML5 tool. By taking a chapter-by-chapter look at each major aspect of Adobe Edge, the book lets you digest the available features in small, easily understandable chunks, allowing you to start using Adobe Edge for your web design needs immediately. If you are interested in creating engaging motion and interactive compositions using web standards with professional tooling, then this book is for you. Those with a background in Flash Professional wanting to get started quickly with Adobe

  18. Imaging responses of on-site CsI and Gd2O2S flat-panel detectors: Dependence on the tube voltage

    Science.gov (United States)

    Jeon, Hosang; Chung, Myung Jin; Youn, Seungman; Nam, Jiho; Lee, Jayoung; Park, Dahl; Kim, Wontaek; Ki, Yongkan; Kim, Ho Kyung

    2015-07-01

    One of the emerging issues in radiography is low-dose imaging to minimize patient's exposure. The scintillating materials employed in most indirect flat-panel detectors show a drastic change of X-ray photon absorption efficiency around their K-edge energies that consequently affects image quality. Using various tube voltages, we investigated the imaging performance of most popular scintillators: cesium iodide (CsI) and gadolinium oxysulfide (Gd2O2S). The integrated detective quantum efficiencies (iDQE) of four detectors installed in the same hospital were evaluated according to the standardized procedure IEC 62220-1 at tube voltages of 40 - 120 kVp. The iDQE values of the Gd2O2S detectors were normalized by those of CsI detectors to exclude the effects of image postprocessing. The contrast-to-noise ratios (CNR) were also evaluated by using an anthropomorphic chest phantom. The iDQE of the CsI detector outperformed that of the Gd2O2S detector over all tube voltages. Moreover, we noted that the iDQE of the Gd2O2S detectors quickly rolled off with decreasing tube voltage under 70 kVp. The CNRs of the two scintillators were similar at 120 kVp. At 60 kVp, however, the CNR of Gd2O2S was about half that of CsI. Compared to the Gd2O2S detectors, variations in the DQE performance of the CsI detectors were relatively immune to variations in the applied tube voltages. Therefore, we claim that Gd2O2S detectors are inappropriate for use in low-tube-voltage imaging (e.g., extremities and pediatrics) with low patient exposure.

  19. Quick-EXAFS setup at the SuperXAS beamline for in situ X-ray absorption spectroscopy with 10 ms time resolution

    Science.gov (United States)

    Müller, Oliver; Nachtegaal, Maarten; Just, Justus; Lützenkirchen-Hecht, Dirk; Frahm, Ronald

    2016-01-01

    The quick-EXAFS (QEXAFS) method adds time resolution to X-ray absorption spectroscopy (XAS) and allows dynamic structural changes to be followed. A completely new QEXAFS setup consisting of monochromator, detectors and data acquisition system is presented, as installed at the SuperXAS bending-magnet beamline at the Swiss Light Source (Paul Scherrer Institute, Switzerland). The monochromator uses Si(111) and Si(311) channel-cut crystals mounted on one crystal stage, and remote exchange allows an energy range from 4.0 keV to 32 keV to be covered. The spectral scan range can be electronically adjusted up to several keV to cover multiple absorption edges in one scan. The determination of the Bragg angle close to the position of the crystals allows high-accuracy measurements. Absorption spectra can be acquired with fast gridded ionization chambers at oscillation frequencies of up to 50 Hz resulting in a time resolution of 10 ms, using both scan directions of each oscillation period. The carefully developed low-noise detector system yields high-quality absorption data. The unique setup allows both state-of-the-art QEXAFS and stable step-scan operation without the need to exchange whole monochromators. The long-term stability of the Bragg angle was investigated and absorption spectra of reference materials as well as of a fast chemical reaction demonstrate the overall capabilities of the new setup. PMID:26698072

  20. Quick-EXAFS setup at the SuperXAS beamline for in situ X-ray absorption spectroscopy with 10 ms time resolution.

    Science.gov (United States)

    Müller, Oliver; Nachtegaal, Maarten; Just, Justus; Lützenkirchen-Hecht, Dirk; Frahm, Ronald

    2016-01-01

    The quick-EXAFS (QEXAFS) method adds time resolution to X-ray absorption spectroscopy (XAS) and allows dynamic structural changes to be followed. A completely new QEXAFS setup consisting of monochromator, detectors and data acquisition system is presented, as installed at the SuperXAS bending-magnet beamline at the Swiss Light Source (Paul Scherrer Institute, Switzerland). The monochromator uses Si(111) and Si(311) channel-cut crystals mounted on one crystal stage, and remote exchange allows an energy range from 4.0 keV to 32 keV to be covered. The spectral scan range can be electronically adjusted up to several keV to cover multiple absorption edges in one scan. The determination of the Bragg angle close to the position of the crystals allows high-accuracy measurements. Absorption spectra can be acquired with fast gridded ionization chambers at oscillation frequencies of up to 50 Hz resulting in a time resolution of 10 ms, using both scan directions of each oscillation period. The carefully developed low-noise detector system yields high-quality absorption data. The unique setup allows both state-of-the-art QEXAFS and stable step-scan operation without the need to exchange whole monochromators. The long-term stability of the Bragg angle was investigated and absorption spectra of reference materials as well as of a fast chemical reaction demonstrate the overall capabilities of the new setup.

  1. Calorimeter detectors

    CERN Document Server

    de Barbaro, P; The ATLAS collaboration

    2013-01-01

    Although the instantaneous and integrated luminosity in HL-LHC will be far higher than the LHC detectors were originally designed for, the Barrel calorimeters of the four experiments are expected to continue to perform well  throughout the Phase II program. The conditions for the End-Cap calorimeters are far more challenging and whilst some detectors will require relatively modest changes, others require far more substantial upgrades. We present the results of longevity and performance studies for the calorimeter systems of the four main LHC experiments and outline the upgrade options under consideration. We include a discussion of the R&D required to make the final technology choices for the upgraded detectors.

  2. Pixel detectors

    CERN Document Server

    Passmore, M S

    2001-01-01

    positions on the detector. The loss of secondary electrons follows the profile of the detector and increases with higher energy ions. studies of the spatial resolution predict a value of 5.3 lp/mm. The image noise in photon counting systems is investigated theoretically and experimentally and is shown to be given by Poisson statistics. The rate capability of the LAD1 was measured to be 250 kHz per pixel. Theoretical and experimental studies of the difference in contrast for ideal charge integrating and photon counting imaging systems were carried out. It is shown that the contrast differs and that for the conventional definition (contrast = (background - signal)/background) the photon counting device will, in some cases, always give a better contrast than the integrating system. Simulations in MEDICI are combined with analytical calculations to investigate charge collection efficiencies (CCE) in semiconductor detectors. Different pixel sizes and biasing conditions are considered. The results show charge shari...

  3. Multi-Material Decomposition using Low-Current X-Ray and a Photon-Counting CZT Detector.

    Science.gov (United States)

    Kim, Sangtaek; Hernandez, Andrew; Alhassen, Fares; Pivovaroff, Michael; Cho, Hyo-Min; Gould, Robert G; Seo, Youngho

    2011-01-01

    We developed and evaluated an x-ray photon-counting imaging system using an energy-resolving cadmium zinc telluride (CZT) detector coupled with application specific integrated circuit (ASIC) readouts. This x-ray imaging system can be used to identify different materials inside the object. The CZT detector has a large active area (5×5 array of 25 CZT modules, each with 16×16 pixels, cover a total area of 200 mm × 200 mm), high stopping efficiency for x-ray photons (~ 100 % at 60 keV and 5 mm thickness). We explored the performance of this system by applying different energy windows around the absorption edges of target materials, silver and indium, in order to distinguish one material from another. The photon-counting CZT-based x-ray imaging system was able to distinguish between the materials, demonstrating its capability as a radiation-spectroscopic decomposition system.

  4. Theory of edge radiation

    CERN Document Server

    Geloni, Gianluca; Saldin, Evgeni; Schneidmiller, Evgeni; Yurkov, Mikhail

    2008-01-01

    We formulate a complete theory of Edge Radiation based on a novel method relying on Fourier Optics techniques. Similar types of radiation like Transition Undulator Radiation are addressed in the framework of the same formalism. Special attention is payed in discussing the validity of approximations upon which the theory is built. Our study makes consistent use of both similarity techniques and comparisons with numerical results from simulation. We discuss both near and far zone. Physical understanding of many asymptotes is discussed. Based on the solution of the field equation with a tensor Green's function technique, we also discuss an analytical model to describe the presence of a vacuum chamber. In particular, explicit calculations for a circular vacuum chamber are reported. Finally, we consider the use of Edge Radiation as a tool for electron beam diagnostics. We discuss Coherent Edge Radiation, Extraction of Edge Radiation by a mirror, and other issues becoming important at high electron energy and long ...

  5. Adobe Edge Preview 3

    CERN Document Server

    Grover, Chris

    2011-01-01

    Want to use an Adobe tool to design animated web graphics that work on iPhone and iPad? You've come to the right book. Adobe Edge Preview 3: The Missing Manual shows you how to build HTML5 graphics using simple visual tools. No programming experience? No problem. Adobe Edge writes the underlying code for you. With this eBook, you'll be designing great-looking web elements in no time. Get to know the workspace. Learn how Adobe Edge Preview 3 performs its magic.Create and import graphics. Make drawings with Edge's tools, or use art you designed in other programs.Work with text. Build menus, lab

  6. CZT detector in multienergy x-ray imaging with different pixel sizes and pitches: Monte Carlo simulation studies

    Science.gov (United States)

    Choi, Yu-Na; Kim, Hee-Joung; Cho, Hyo-Min; Lee, Chang-Lae; Park, Hye-Suk; Kim, Dae-Hong; Lee, Seung-Wan; Ryu, Hyun-Ju

    2011-03-01

    A photon counting detector based on semiconductor materials is a very promising approach for x-ray imaging. Cadmium zinc telluride (CZT) semiconductor has a high atomic number which results in higher absorption coefficients for x-rays. However, the CZT detectors exhibit several problems with hole trapping and charge sharing. Charge sharing occurs due to diffusion of charge and characteristic x-ray escape and scattered x-rays in the detectors. In this study, we evaluated the effect of interaction with CZT detector using Monte Carlo simulations. To demonstrate the effectiveness of CZT detector in clinical application, we reported confirmation of CNR improvement in K-edge images, and material decomposition using energy selective windows. X-ray energy spectrum acquired at 120 kVp tube voltage and 2 mm Al filtration and 10 cm added water phantom in the x-ray beam. Geant4 Application for Tomographic Emission (GATE) version 6.0 was used for a CZT crystal with size of 10x10 mm2 and thickness of 4 mm. The detector pixel with sizes of 0.09x0.09, 0.45x0.45, and 0.90x0.90 mm2 were simulated. For all pixel sizes, the x-ray spectra of the simulations were distorted towards the lower energy region. Because the characteristic x-rays add counts in the range of 20-40 keV. The magnitude of this deterioration is substantial for small pixel sizes. However, we demonstrated that the distortion of spectrum does not greatly affect the x-ray imaging. The GATE simulation model and these results may be used as a basis of development of energy-resolved photon counting x-ray detector. We believe that the CZT detector may enhance the detectability of multi-energy x-ray imaging.

  7. Ultraviolet radiation-induced modifications of the optical and registration properties of a CR-39 nuclear track detector

    Energy Technology Data Exchange (ETDEWEB)

    Saad, A.F., E-mail: abdallahsaad56@hotmail.com [Physics Department, Faculty of Science, University of Benghazi, Benghazi (Libya); Physics Department, Faculty of Science, Zagazig University, Zagazig (Egypt); Al-Faitory, N.M. [Physics Department, Faculty of Science, University of Benghazi, Benghazi (Libya); Hussein, M. [Physics Department, Faculty of Science, Zagazig University, Zagazig (Egypt); Mohamed, R.A. [Physics Department, Faculty of Science, University of Benghazi, Benghazi (Libya)

    2015-09-15

    The UV–VIS (ultraviolet–visible) spectra and etching characteristics of poly allyl diglycol carbonate (PADC, a form of the CR-39 polymer) detector films after exposure to UV radiation for various times have been studied. Etching experiments were carried out on the UV-exposed CR-39 detectors after alpha particle and fission-fragment irradiation using a {sup 252}Cf source. The bulk and track etch rates were measured using the alpha and fission-fragment track diameters, and the sensitivity and the detection efficiency were also determined. The optical band gap for both indirect and direct transitions was calculated based on the absorption edge of the UV spectra of the pristine and variously UV-exposed detectors. The optical band gap evidently indicates a gradual change in the optical properties of the CR-39 detector that is induced by the UV radiation. This study shows that the UV-exposed CR-39 detectors were demonstrated to be highly sensitive to alpha particles, but proved to be somewhat less sensitive to the fission fragments.

  8. A Novel Method for Edge Detection in Images Based on Particle Swarm Optimization

    Science.gov (United States)

    Baby Sherin, C.; Mredhula, L.

    2017-01-01

    Edges give important structural information about the images. Edge detection is a process of identifying and locating the edges in an image. Edges are the points where discontinuity of intensity occurs. It also represents the boundaries of objects in images. In this paper a new edge detection method based on Particle Swarm Optimization is discussed. The proposed method uses morphological operations and a thresholding technique to improve the result of edge detector. This algorithm performs better in images comparing to other traditional methods of edge detection. The performance of proposed method is compared with traditional edge detection methods such as Sobel, Prewitt, Laplacian of Gaussian and Canny with parameters Baddeley's Delta Metric. Statistical analysis is performed to evaluate accuracy of edge detection techniques.

  9. An Interactive Procedure to Preserve the Desired Edges during the Image Processing of Noise Reduction

    Directory of Open Access Journals (Sweden)

    Huang Hsuan-Yu

    2010-01-01

    Full Text Available The paper propose a new procedure including four stages in order to preserve the desired edges during the image processing of noise reduction. A denoised image can be obtained from a noisy image at the first stage of the procedure. At the second stage, an edge map can be obtained by the Canny edge detector to find the edges of the object contours. Manual modification of an edge map at the third stage is optional to capture all the desired edges of the object contours. At the final stage, a new method called Edge Preserved Inhomogeneous Diffusion Equation (EPIDE is used to smooth the noisy images or the previously denoised image at the first stage for achieving the edge preservation. The Optical Character Recognition (OCR results in the experiments show that the proposed procedure has the best recognition result because of the capability of edge preservation.

  10. Edge and corner identification for tracking the line of sight Edge and corner identification for tracking the line of sight

    OpenAIRE

    María S Orozco; Uwe Jasnoch; Oscar Eduardo Ruiz Salguero

    2005-01-01

    This article presents an edge-corner detector, implemented in the realm of the GEIST project (an Computer Aided Touristic Information System) to extract the information of straight edges and their intersections (image corners) from camera-captured (real world) and computer-generated images (from the database of Historical Monuments, using ob- server position and orientation data). Camera and computer-generated images are processed for reduction of detail, skeletonization and corner-edge detec...

  11. Optimal edge detection using multiple operators for image understanding

    Directory of Open Access Journals (Sweden)

    Stathaki Tania

    2011-01-01

    Full Text Available Abstract Extraction of features, such as edges for the understanding of aerial images, has been an important objective since the early days of remote sensing. This work aims at describing a new framework which allows for the quantitative combination of a preselected set of edge detectors based on the correspondence between their outcomes. This is inspired from the problem that despite the enormous amount of literature on edge detection techniques, there is no single technique that performs well in every possible image context. Two approaches are proposed for this purpose. The first approach is the well-known receiver operating characteristics analysis which is introduced for a sound quality evaluation of the edge maps estimated by combining different edge detectors. In the second approach, the so-called kappa statistics are employed in a novel fashion to amalgamate the above-mentioned selected edge maps to form an improved final edge image. This method is unique in the sense that the balance between the false detections (false positives and false negatives is explicitly determined in advance and incorporated in the proposed method in a mathematical fashion. For the performance evaluation of the proposed techniques, a sample set of the RADIUS/DARPA-IU Fort Hood aerial image database with known ground truth has been used.

  12. Edge Detection in Gray Level Images based on the Shannon Entropy

    Directory of Open Access Journals (Sweden)

    Baljit Singh

    2008-01-01

    Full Text Available Most of the classical mathematical methods for edge detection based on the derivative of the pixels of the original image are Gradient operators, Laplacian and Laplacian of Gaussian operators. Gradient based edge detection methods, such as Roberts, Sobel and Prewitts, have used two 2-D linear filters to process vertical edges and horizontal edges separately to approximate first-order derivative of pixel values of the image. The Laplacian edge detection method has used a 2-D linear filter to approximate second-order derivative of pixel values of the image. Major drawback of second-order derivative approach is that the response at and around the isolated pixel is much stronger. In this research study, a novel approach utilizing Shannon entropy other than the evaluation of derivates of the image in detecting edges in gray level images has been proposed. The proposed approach solves this problem at some extent. In the proposed method, we have used a suitable threshold value to segment the image and achieve the binary image. After this the proposed edge detector is introduced to detect and locate the edges in the image. A standard test image is used to compare the results of the proposed edge detector with the Laplacian of Gaussian edge detector operator. In order to validate the results, seven different kinds of test images are considered to examine the versatility of the proposed edge detector. It has been observed that the proposed edge detector works effectively for different gray scale digital images. The results of this study were quite promising.

  13. XMASS detector

    CERN Document Server

    Abe, K; Hiraide, K; Hirano, S; Kishimoto, Y; Kobayashi, K; Moriyama, S; Nakagawa, K; Nakahata, M; Nishiie, H; Ogawa, H; Oka, N; Sekiya, H; Shinozaki, A; Suzuki, Y; Takeda, A; Takachio, O; Ueshima, K; Umemoto, D; Yamashita, M; Yang, B S; Tasaka, S; Liu, J; Martens, K; Hosokawa, K; Miuchi, K; Murata, A; Onishi, Y; Otsuka, Y; Takeuchi, Y; Kim, Y H; Lee, K B; Lee, M K; Lee, J S; Fukuda, Y; Itow, Y; Nishitani, Y; Masuda, K; Takiya, H; Uchida, H; Kim, N Y; Kim, Y D; Kusaba, F; Motoki, D; Nishijima, K; Fujii, K; Murayama, I; Nakamura, S

    2013-01-01

    The XMASS project aims to detect dark matter, pp and $^{7}$Be solar neutrinos, and neutrinoless double beta decay using ultra pure liquid xenon. The first phase of the XMASS experiment searches for dark matter. In this paper, we describe the XMASS detector in detail, including its configuration, data acquisition equipment and calibration system.

  14. XMASS detector

    Energy Technology Data Exchange (ETDEWEB)

    Abe, K. [Kamioka Observatory, Institute for Cosmic Ray Research, The University of Tokyo, Higashi-Mozumi, Kamioka, Hida, Gifu 506-1205 (Japan); Kavli Institute for the Physics and Mathematics of the Universe, the University of Tokyo, Kashiwa, Chiba 277-8582 (Japan); Hieda, K. [Kamioka Observatory, Institute for Cosmic Ray Research, The University of Tokyo, Higashi-Mozumi, Kamioka, Hida, Gifu 506-1205 (Japan); Hiraide, K. [Kamioka Observatory, Institute for Cosmic Ray Research, The University of Tokyo, Higashi-Mozumi, Kamioka, Hida, Gifu 506-1205 (Japan); Kavli Institute for the Physics and Mathematics of the Universe, the University of Tokyo, Kashiwa, Chiba 277-8582 (Japan); Hirano, S. [Kamioka Observatory, Institute for Cosmic Ray Research, The University of Tokyo, Higashi-Mozumi, Kamioka, Hida, Gifu 506-1205 (Japan); Kishimoto, Y.; Kobayashi, K.; Moriyama, S. [Kamioka Observatory, Institute for Cosmic Ray Research, The University of Tokyo, Higashi-Mozumi, Kamioka, Hida, Gifu 506-1205 (Japan); Kavli Institute for the Physics and Mathematics of the Universe, the University of Tokyo, Kashiwa, Chiba 277-8582 (Japan); Nakagawa, K. [Kamioka Observatory, Institute for Cosmic Ray Research, The University of Tokyo, Higashi-Mozumi, Kamioka, Hida, Gifu 506-1205 (Japan); Nakahata, M. [Kamioka Observatory, Institute for Cosmic Ray Research, The University of Tokyo, Higashi-Mozumi, Kamioka, Hida, Gifu 506-1205 (Japan); Kavli Institute for the Physics and Mathematics of the Universe, the University of Tokyo, Kashiwa, Chiba 277-8582 (Japan); Nishiie, H. [Kamioka Observatory, Institute for Cosmic Ray Research, The University of Tokyo, Higashi-Mozumi, Kamioka, Hida, Gifu 506-1205 (Japan); Ogawa, H. [Kamioka Observatory, Institute for Cosmic Ray Research, The University of Tokyo, Higashi-Mozumi, Kamioka, Hida, Gifu 506-1205 (Japan); Kavli Institute for the Physics and Mathematics of the Universe, the University of Tokyo, Kashiwa, Chiba 277-8582 (Japan); and others

    2013-07-11

    The XMASS project aims to detect dark matter, pp and {sup 7}Be solar neutrinos, and neutrinoless double beta decay using ultra pure liquid xenon. The first phase of the XMASS experiment searches for dark matter. In this paper, we describe the XMASS detector in detail, including its configuration, data acquisition equipment and calibration system.

  15. The Edge supersonic transport

    Science.gov (United States)

    Agosta, Roxana; Bilbija, Dushan; Deutsch, Marc; Gallant, David; Rose, Don; Shreve, Gene; Smario, David; Suffredini, Brian

    1992-01-01

    As intercontinental business and tourism volumes continue their rapid expansion, the need to reduce travel times becomes increasingly acute. The Edge Supersonic Transport Aircraft is designed to meet this demand by the year 2015. With a maximum range of 5750 nm, a payload of 294 passengers and a cruising speed of M = 2.4, The Edge will cut current international flight durations in half, while maintaining competitive first class, business class, and economy class comfort levels. Moreover, this transport will render a minimal impact upon the environment, and will meet all Federal Aviation Administration Part 36, Stage III noise requirements. The cornerstone of The Edge's superior flight performance is its aerodynamically efficient, dual-configuration design incorporating variable-geometry wingtips. This arrangement combines the benefits of a high aspect ratio wing at takeoff and low cruising speeds with the high performance of an arrow-wing in supersonic cruise. And while the structural weight concerns relating to swinging wingtips are substantial, The Edge looks to ever-advancing material technologies to further increase its viability. Heeding well the lessons of the past, The Edge design holds economic feasibility as its primary focus. Therefore, in addition to its inherently superior aerodynamic performance, The Edge uses a lightweight, largely windowless configuration, relying on a synthetic vision system for outside viewing by both pilot and passengers. Additionally, a fly-by-light flight control system is incorporated to address aircraft supersonic cruise instability. The Edge will be produced at an estimated volume of 400 aircraft and will be offered to airlines in 2015 at $167 million per transport (1992 dollars).

  16. Influence of alpha irradiation on pre and post solar exposed PM-355 polymeric nuclear track detector sheets

    Science.gov (United States)

    Alsalhi, M. S.; Baig, M. R.; Alfaramawi, K.; Alrasheedi, Mariam G.

    2017-01-01

    The effect of alpha irradiation before and after solar exposed PM-355 polymeric SSNTDs films was investigated. The absorption spectra for both non-irradiated and irradiated samples at different solar exposure time in different months showed a shift in the absorption edge towards lower wavelengths as the solar exposure time increases. This is probably ascribed to the presence of conjugate bonds. The fluorescence spectra indicated three distinguished peaks at approximately 330, 415 and 465 nm respectively. The first peak is attributed to the band gap while the other two peaks due to a probable formation of solid defects. The structure analysis using X-ray diffraction (XRD) proved the partial crystalline nature of the polymer with dominant amorphous phase. There was a slight increase in the XRD peak intensity for the sample irradiated by alpha particles indicating that the polymeric detector structure becomes more crystalline with a change in the crystallite size.

  17. Extended Klein edges in graphene.

    Science.gov (United States)

    He, Kuang; Robertson, Alex W; Lee, Sungwoo; Yoon, Euijoon; Lee, Gun-Do; Warner, Jamie H

    2014-12-23

    Graphene has three experimentally confirmed periodic edge terminations, zigzag, reconstructed 5-7, and arm-chair. Theory predicts a fourth periodic edge of graphene called the extended Klein (EK) edge, which consists of a series of single C atoms protruding from a zigzag edge. Here, we confirm the existence of EK edges in both graphene nanoribbons and on the edge of bulk graphene using atomic resolution imaging by aberration-corrected transmission electron microscopy. The formation of the EK edge stems from sputtering and reconstruction of the zigzag edge. Density functional theory reveals minimal energy for EK edge reconstruction and bond distortion both in and out of plane, supporting our TEM observations. The EK edge can now be included as the fourth member of observed periodic edge structures in graphene.

  18. A New Edge-directed Subpixel Edge Localization Method

    Institute of Scientific and Technical Information of China (English)

    于新瑞; 徐威; 王石刚; 李倩

    2004-01-01

    Localization of the inspected chip image is one of the key problems with machine vision aided surface mount devices (SMD) and other micro-electronic equipments. This paper presents a new edge-directed subpixel edge localization method. The image is divided into two regions, edge and non-edge, using edge detection to emphasize the edge feature. Since the edges of the chip image are straight, they have straight-line characteristics locally and globally. First,the line segments of the straight edge are located to subpixel precision, according to their local straight properties, in a 3 × 3 neighborhood of the edge region. Second, the subpixel midpoints of the line segments are computed. Finally, the straight edge is fitted using the midpoints and the least square method, according to its global straight property in the entire edge region. In this way, the edge is located to subpixel precision. While fitting the edge, the irregular points are eliminated by the angles of the line segments to improve the precision. We can also distinguish different edges and their intersections using the angles of the line segments and distances between the edge points, then give the vectorial result of the image edge with high precision.

  19. DUAL-BAND INFRARED DETECTORS

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    As the infrared technology continues to advance, there is a growing demand for multispectral detectors for advanced IR systems with better target discrimination and identification. Both HgCdTe detectors and quantum well GaAs/AlGaAs photodetectors offer wavelength flexibility from medium wavelength to very long wavelength and multicolor capability in these regions. The main challenges facing all multicolor devices are more complicated device structtures, thicker and multilayer material growth, and more difficult device fabrication, especially when the array size gets larger and pixel size gets smaller. In the paper recent progress in development of two-color HgCdTe photodiodes and quantum well infrared photodetectors is presented.More attention is devoted to HgCdTe detectors. The two-color detector arrays are based upon an n-P-N (the capital letters mean the materials with larger bandgap energy) HgCdTe triple layer heterojunction design. Vertically stacking the two p-n junctions permits incorporation of both detectros into a single pixel. Both sequential mode and simultaneous mode detectors are fabricated. The mode of detection is determined by the fabrication process of the multilayer materials.Also the performances of stacked multicolor QWIPs detectors are presented. For multicolor arrays, QWIP's narrow band spectrum is an advantage, resulting in low spectral crosstalk. The major challenge for QWIP is developing broadband or multicolor optical coupling structures that permit efficient absorption of all required spectral bands.

  20. Absorption-Edge-Modulated Transmission Spectra for Water Contaminant Monitoring

    Science.gov (United States)

    2016-03-31

    Govender, K. Chetty, H. Bulcock, “A Review of Hyperspectral Remote Sensing and Its Application in Vegetation and Water Resource Studies,” Water SA...Spectroscopy and Chemometrics for the Detection of Undesirable Substances in Food and Feed,” Chemometrics and Intelligent Laboratory Systems, Vol. 117, No. 1

  1. Theory of edge radiation

    Energy Technology Data Exchange (ETDEWEB)

    Geloni, G.; Kocharyan, V.; Saldin, E.; Schneidmiller, E.; Yurkov, M.

    2008-08-15

    We formulate a complete theory of Edge Radiation based on a novel method relying on Fourier Optics techniques. Similar types of radiation like Transition UndulatorRadiation are addressed in the framework of the same formalism. Special attention is payed in discussing the validity of approximations upon which the theory is built. Our study makes consistent use of both similarity techniques and comparisons with numerical results from simulation. We discuss both near and far zone. Physical understanding of many asymptotes is discussed. Based on the solution of the field equation with a tensor Green's function technique, we also discuss an analytical model to describe the presence of a vacuum chamber. In particular, explicit calculations for a circular vacuum chamber are reported. Finally, we consider the use of Edge Radiation as a tool for electron beam diagnostics. We discuss Coherent Edge Radiation, Extraction of Edge Radiation by a mirror, and other issues becoming important at high electron energy and long radiation wavelength. Based on this work we also study the impact of Edge Radiation on XFEL setups and we discuss recent results. (orig.)

  2. Hybrid Contacts for CZT Virtual Frisch-grid Detectors

    Energy Technology Data Exchange (ETDEWEB)

    Camarda G.; Bolotnikov, A.E.; Chan, W.; Cui, Y.; Gul R.; Hossain, A.; Kim, K.; Yang, G.; James, R.B.

    2011-08-22

    In our previous design of virtual Frisch-grid CdZnTe (CZT) detectors, the charge drift-lines can be terminated at the side surfaces before the carriers reach the collecting anode; this results in a loss of signal from the interacting events near the detector's edges. Here, we describe our new design for the anode contact that reduces these edge effects by focusing the electric field towards the detectors' central axes. Four detectors were fabricated with the new hybrid anode contact, and their performances were evaluated and compared to those from the previous design for our virtual Frisch-grid detectors. The results obtained for all four showed similar improvement: therefore, we illustrate them with the findings from one detector.

  3. Semiconductor Detectors; Detectores de Semiconductores

    Energy Technology Data Exchange (ETDEWEB)

    Cortina, E.

    2007-07-01

    Particle detectors based on semiconductor materials are among the few devices used for particle detection that are available to the public at large. In fact we are surrounded by them in our daily lives: they are used in photoelectric cells for opening doors, in digital photographic and video camera, and in bar code readers at supermarket cash registers. (Author)

  4. Progress on CMS detector lowering

    CERN Multimedia

    2006-01-01

    It was an amazing engineering challenge - the lowering of the first hugeendcap disc (YE+3) of the CMS detector slowly and carefully 100 metres underground. The spectacular descent took place on 30 November and was documented by a film crew from Reuters news group. The uniquely shaped slice is 16 m high, about 50 cm thick, and weighs 400 tonnes. It is one of 15 sections that make up the complete CMS detector. The solid steel structure of the disc forms part of the magnet return yoke and is equipped on both sides with muon chambers. A special gantry crane lowered the element, with just 20 cm of leeway between the edges of the detector and the walls of the shaft! On 12 December, a further section of the detector (YE+2) containing the cathode strip chamber made the 10-hour journey underground. This piece is 16 m high and weighs 880 tonnes. There are now four sections of the detector in the experimental cavern, with a further 11 to follow. The endcap disc YE+3 (seen in the foreground) begins its journey down the ...

  5. High Speed Edge Detection

    Science.gov (United States)

    Prokop, Norman F (Inventor)

    2016-01-01

    Analog circuits for detecting edges in pixel arrays are disclosed. A comparator may be configured to receive an all pass signal and a low pass signal for a pixel intensity in an array of pixels. A latch may be configured to receive a counter signal and a latching signal from the comparator. The comparator may be configured to send the latching signal to the latch when the all pass signal is below the low pass signal minus an offset. The latch may be configured to hold a last negative edge location when the latching signal is received from the comparator.

  6. X-Ray Absorption and Scattering by Interstellar Grains

    OpenAIRE

    Hoffman, John A.; Draine, Bruce T.

    2015-01-01

    Interstellar abundance determinations from fits to X-ray absorption edges often rely on the incorrect assumption that scattering is insignificant and can be ignored. We show instead that scattering contributes significantly to the attenuation of X-rays for realistic dust grain size distributions and substantially modifies the spectrum near absorption edges of elements present in grains. The dust attenuation modules used in major X-ray spectral fitting programs do not take this into account. W...

  7. Graphene vertical hot-electron terahertz detectors

    Energy Technology Data Exchange (ETDEWEB)

    Ryzhii, V., E-mail: v-ryzhii@riec.tohoku.ac.jp [Research Institute for Electrical Communication, Tohoku University, Sendai 980-8577 (Japan); Center for Photonics and Infrared Engineering, Bauman Moscow State Technical University and Institute of Ultra High Frequency Semiconductor Electronics, Russian Academy of Sciences, Moscow 111005 (Russian Federation); Satou, A.; Otsuji, T. [Research Institute for Electrical Communication, Tohoku University, Sendai 980-8577 (Japan); Ryzhii, M. [Department of Computer Science and Engineering, University of Aizu, Aizu-Wakamatsu 965-8580 (Japan); Mitin, V. [Department of Electrical Engineering, University at Buffalo, Buffalo, New York 1460-1920 (United States); Shur, M. S. [Departments of Electrical, Electronics, and Systems Engineering and Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States)

    2014-09-21

    We propose and analyze the concept of the vertical hot-electron terahertz (THz) graphene-layer detectors (GLDs) based on the double-GL and multiple-GL structures with the barrier layers made of materials with a moderate conduction band off-set (such as tungsten disulfide and related materials). The operation of these detectors is enabled by the thermionic emissions from the GLs enhanced by the electrons heated by incoming THz radiation. Hence, these detectors are the hot-electron bolometric detectors. The electron heating is primarily associated with the intraband absorption (the Drude absorption). In the frame of the developed model, we calculate the responsivity and detectivity as functions of the photon energy, GL doping, and the applied voltage for the GLDs with different number of GLs. The detectors based on the cascade multiple-GL structures can exhibit a substantial photoelectric gain resulting in the elevated responsivity and detectivity. The advantages of the THz detectors under consideration are associated with their high sensitivity to the normal incident radiation and efficient operation at room temperature at the low end of the THz frequency range. Such GLDs with a metal grating, supporting the excitation of plasma oscillations in the GL-structures by the incident THz radiation, can exhibit a strong resonant response at the frequencies of several THz (in the range, where the operation of the conventional detectors based on A{sub 3}B{sub 5} materials, in particular, THz quantum-well detectors, is hindered due to a strong optical phonon radiation absorption in such materials). We also evaluate the characteristics of GLDs in the mid- and far-infrared ranges where the electron heating is due to the interband absorption in GLs.

  8. Photon Counting Using Edge-Detection Algorithm

    Science.gov (United States)

    Gin, Jonathan W.; Nguyen, Danh H.; Farr, William H.

    2010-01-01

    New applications such as high-datarate, photon-starved, free-space optical communications require photon counting at flux rates into gigaphoton-per-second regimes coupled with subnanosecond timing accuracy. Current single-photon detectors that are capable of handling such operating conditions are designed in an array format and produce output pulses that span multiple sample times. In order to discern one pulse from another and not to overcount the number of incoming photons, a detection algorithm must be applied to the sampled detector output pulses. As flux rates increase, the ability to implement such a detection algorithm becomes difficult within a digital processor that may reside within a field-programmable gate array (FPGA). Systems have been developed and implemented to both characterize gigahertz bandwidth single-photon detectors, as well as process photon count signals at rates into gigaphotons per second in order to implement communications links at SCPPM (serial concatenated pulse position modulation) encoded data rates exceeding 100 megabits per second with efficiencies greater than two bits per detected photon. A hardware edge-detection algorithm and corresponding signal combining and deserialization hardware were developed to meet these requirements at sample rates up to 10 GHz. The photon discriminator deserializer hardware board accepts four inputs, which allows for the ability to take inputs from a quadphoton counting detector, to support requirements for optical tracking with a reduced number of hardware components. The four inputs are hardware leading-edge detected independently. After leading-edge detection, the resultant samples are ORed together prior to deserialization. The deserialization is performed to reduce the rate at which data is passed to a digital signal processor, perhaps residing within an FPGA. The hardware implements four separate analog inputs that are connected through RF connectors. Each analog input is fed to a high-speed 1

  9. Lifshitz Tails for the Interband Light Absorption Coefficient

    Indian Academy of Sciences (India)

    W Kirsch; M Krishna

    2010-09-01

    In this paper we consider the interband light absorption coefficient (ILAC) for various models. We show that at the lower and upper edges of the spectrum the Lifshitz tails behaviour of the density of states implies similar behaviour for the ILAC at appropriate energies. The Lifshitz tails property is also exhibited at some points corresponding to the internal band edges of the spectrum.

  10. Si K Edge Structure and Variability in Galactic X-Ray Binaries

    CERN Document Server

    Schulz, Norbert S; Canizares, Claude R

    2016-01-01

    We survey the Si K edge structure in various absorbed Galactic low-mass X-ray binaries (LMXBs) to study states of silicon in the inter- and circum-stellar medium. The bulk of these LMXBs lie toward the Galactic bulge region and all have column densities above $10^{22}$ cm$^{-2}$. The observations were performed with the \\emph{Chandra} High Energy Transmission Grating Spectrometer. The Si K edge in all sources appears at an energy value of 1844$\\pm$0.001 eV. The edge exhibits significant substructure which can be described by a near edge absorption feature at 1849$\\pm$0.002 eV and a far edge absorption feature at 1865$\\pm$0.002 eV. Both of these absorption features appear variable with equivalent widths up to several m\\AA. We can describe the edge structure with several components: multiple edge functions, near edge absorption excesses from silicates in dust form, signatures from X-ray scattering optical depths, and a variable warm absorber from ionized atomic silicon. The measured optical depths of the edges ...

  11. Superpixel edges for boundary detection

    Energy Technology Data Exchange (ETDEWEB)

    Moya, Mary M.; Koch, Mark W.

    2016-07-12

    Various embodiments presented herein relate to identifying one or more edges in a synthetic aperture radar (SAR) image comprising a plurality of superpixels. Superpixels sharing an edge (or boundary) can be identified and one or more properties of the shared superpixels can be compared to determine whether the superpixels form the same or two different features. Where the superpixels form the same feature the edge is identified as an internal edge. Where the superpixels form two different features, the edge is identified as an external edge. Based upon classification of the superpixels, the external edge can be further determined to form part of a roof, wall, etc. The superpixels can be formed from a speckle-reduced SAR image product formed from a registered stack of SAR images, which is further segmented into a plurality of superpixels. The edge identification process is applied to the SAR image comprising the superpixels and edges.

  12. Spectrally narrowed leaky waveguide edge emission and transient electrluminescent dynamics of OLEDs

    Energy Technology Data Exchange (ETDEWEB)

    Zhengqing, Gan [Iowa State Univ., Ames, IA (United States)

    2010-01-01

    In summary, there are two major research works presented in this dissertation. The first research project (Chapter 4) is spectrally narrowed edge emission from Organic Light Emitting Diodes. The second project (Chapter 5) is about transient electroluminescent dynamics in OLEDs. Chapter 1 is a general introduction of OLEDs. Chapter 2 is a general introduction of organic semiconductor lasers. Chapter 3 is a description of the thermal evaporation method for OLED fabrication. The detail of the first project was presented in Chapter 4. Extremely narrowed spectrum was observed from the edge of OLED devices. A threshold thickness exists, above which the spectrum is narrow, and below which the spectrum is broad. The FWHM of spectrum depends on the material of the organic thin films, the thickness of the organic layers, and length of the OLED device. A superlinear relationship between the output intensity of the edge emission and the length of the device was observed, which is probably due to the misalignment of the device edge and the optical fiber detector. The original motivation of this research is for organic semiconductor laser that hasn't been realized due to the extremely high photon absorption in OLED devices. Although we didn't succeed in fabricating an electrically pumped organic laser diode, we made a comprehensive research in edge emission of OLEDs which provides valuable results in understanding light distribution and propagation in OLED devices. Chapter 5 focuses on the second project. A strong spike was observed at the falling edge of a pulse, and a long tail followed. The spike was due to the recombination of correlated charge pair (CCP) created by trapped carriers in guest molecules of the recombination zone. When the bias was turned off, along with the decreasing of electric field in the device, the electric field induced quenching decreases and the recombination rate of the CCP increases which result in the spike. This research project provides

  13. How noise affects quantum detector tomography

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Q., E-mail: wang@physics.leidenuniv.nl; Renema, J. J.; Exter, M. P.van; Dood, M. J. A. de [Huygens Kamerlingh-Onnes Laboratory, Leiden University, Niels Bohrweg 2, 2333 CA Leiden (Netherlands); Gaggero, A.; Mattioli, F.; Leoni, R. [Istituto di Fotonica e Nanotecnologie (IFN), CNR, via Cineto Romano 42, 00156 Roma (Italy)

    2015-10-07

    We determine the full photon number response of a NbN superconducting nanowire single photon detector via quantum detector tomography, and the results show the separation of linear, effective absorption efficiency from the internal detection efficiencies. In addition, we demonstrate an error budget for the complete quantum characterization of the detector. We find that for short times, the dominant noise source is shot noise, while laser power fluctuations limit the accuracy for longer timescales. The combined standard uncertainty of the internal detection efficiency derived from our measurements is about 2%.

  14. Edge Detection Operators: Peak Signal to Noise Ratio Based Comparison

    Directory of Open Access Journals (Sweden)

    D. Poobathy

    2014-09-01

    Full Text Available Edge detection is the vital task in digital image processing. It makes the image segmentation and pattern recognition more comfort. It also helps for object detection. There are many edge detectors available for pre-processing in computer vision. But, Canny, Sobel, Laplacian of Gaussian (LoG, Robert’s and Prewitt are most applied algorithms. This paper compares each of these operators by the manner of checking Peak signal to Noise Ratio (PSNR and Mean Squared Error (MSE of resultant image. It evaluates the performance of each algorithm with Matlab and Java. The set of four universally standardized test images are used for the experimentation. The PSNR and MSE results are numeric values, based on that, performance of algorithms identified. The time required for each algorithm to detect edges is also documented. After the Experimentation, Canny operator found as the best among others in edge detection accuracy.

  15. Edge detection by nonlinear dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Wong, Yiu-fai

    1994-07-01

    We demonstrate how the formulation of a nonlinear scale-space filter can be used for edge detection and junction analysis. By casting edge-preserving filtering in terms of maximizing information content subject to an average cost function, the computed cost at each pixel location becomes a local measure of edgeness. This computation depends on a single scale parameter and the given image data. Unlike previous approaches which require careful tuning of the filter kernels for various types of edges, our scheme is general enough to be able to handle different edges, such as lines, step-edges, corners and junctions. Anisotropy in the data is handled automatically by the nonlinear dynamics.

  16. Graphene edges; localized edge state and electron wave interference

    Directory of Open Access Journals (Sweden)

    Enoki Toshiaki

    2012-03-01

    Full Text Available The electronic structure of massless Dirac fermion in the graphene hexagonal bipartite is seriously modified by the presence of edges depending on the edge chirality. In the zigzag edge, strongly spin polarized nonbonding edge state is created as a consequence of broken symmetry of pseudo-spin. In the scattering at armchair edges, the K-K’ intervalley transition gives rise to electron wave interference. The presence of edge state in zigzag edges is observed in ultra-high vacuum STM/STS observations. The electron wave interference phenomenon in the armchair edge is observed in the Raman G-band and the honeycomb superlattice pattern with its fine structure in STM images.

  17. Symmetric Absorber-Coupled Far-Infrared Microwave Kinetic Inductance Detector

    Science.gov (United States)

    U-yen, Kongpop (Inventor); Wollack, Edward J. (Inventor); Brown, Ari D. (Inventor); Stevenson, Thomas R. (Inventor); Patel, Amil A. (Inventor)

    2016-01-01

    The present invention relates to a symmetric absorber-coupled far-infrared microwave kinetic inductance detector including: a membrane having an absorber disposed thereon in a symmetric cross bar pattern; and a microstrip including a plurality of conductor microstrip lines disposed along all edges of the membrane, and separated from a ground plane by the membrane. The conducting microstrip lines are made from niobium, and the pattern is made from a superconducting material with a transition temperature below niobium, including one of aluminum, titanium nitride, or molybdenum nitride. The pattern is disposed on both a top and a bottom of the membrane, and creates a parallel-plate coupled transmission line on the membrane that acts as a half-wavelength resonator at readout frequencies. The parallel-plate coupled transmission line and the conductor microstrip lines form a stepped impedance resonator. The pattern provides identical power absorption for both horizontal and vertical polarization signals.

  18. Edge turbulence in tokamaks

    Science.gov (United States)

    Nedospasov, A. V.

    1992-12-01

    Edge turbulence is of decisive importance for the distribution of particle and energy fluxes to the walls of tokamaks. Despite the availability of extensive experimental data on the turbulence properties, its nature still remains a subject for discussion. This paper contains a review of the most recent theoretical and experimental studies in the field, including mainly the studies to which Wootton (A.J. Wooton, J. Nucl. Mater. 176 & 177 (1990) 77) referred to most in his review at PSI-9 and those published later. The available theoretical models of edge turbulence with volume dissipation due to collisions fail to fully interpret the entire combination of experimental facts. In the scrape-off layer of a tokamak the dissipation prevails due to the flow of current through potential shifts near the surface of limiters of divertor plates. The different origins of turbulence at the edge and in the core plasma due to such dissipation are discussed in this paper. Recent data on the electron temperature fluctuations enabled one to evaluate the electric probe measurements of turbulent flows of particles and heat critically. The latest data on the suppression of turbulence in the case of L-H transitions are given. In doing so, the possibility of exciting current instabilities in biasing experiments (rather than only to the suppression of existing turbulence) is given some attention. Possible objectives of further studies are also discussed.

  19. Final Size Planar Edgeless Silicon Detectors for the TOTEM Experiment

    CERN Document Server

    Noschis, E; Anelli, G; Avati, V; Berardi, V; Boccone, V; Bozzo, M; Brucken, E; Buzzo, A; Catanesi, M G; Cereseto, R; Cuneo, S; Da Vià, C; Deile, M; Dinapoli, R; Eggert, K; Egorov, N; Eremin, I; Ferro, F; Hasi, J; Haug, F; Heino, J; Jarron, P; Kalliopuska, J; Kaspar, J; Kok, A; Kozlov, Y; Kundrat, W; Kurvinen, K; Lauhakangas, R; Lokajícek, M; Luntama, T; Macina, D; Macri, M; Minutoli, S; Mirabito, L; Morelli, A; Musico, P; Negri, M; Niewiadomski, H; Oljemark, F; Orava, R; Oriunno, M; Österberg, K; Perrot, A L; Puppo, R; Radermacher, E; Radicioni, E; Saarikko, H; Santroni, A; Sette, G; Sidorov, A; Siegrist, P; Smotlacha, J; Snoeys, W; Taylor, C; Watts, S; Whitmoree, J

    2006-01-01

    The TOTEM experiment will detect leading protons scattered in angles of microradians from the interaction point at the Large Hadron Collider. This will be achieved using detectors with a minimized dead area at the edge. The collaboration has developed an innovative structure at the detector edge reducing the conventional dead width to less than 100 microns, still using standard planar fabrication technology. In this new development, the current of the surface is decoupled from the sensitive volume current within a few tens of micrometers. The basic working principle is explained in this paper. Final size detectors have been produced using this approach. The current-voltage and current-temperature characteristics of the detectors were studied and the detectors were successfully tested in a coasting beam experiment.

  20. Comparative study of ionization chamber detectors vis-a-vis a CCD detector for dispersive XAS measurement in transmission geometry

    Energy Technology Data Exchange (ETDEWEB)

    Poswal, A. K.; Agrawal, A.; Bhattachryya, D.; Jha, S. N.; Sahoo, N. K. [Applied Spectroscopy Division, Bhabha Atomic Research Centre, Mumbai -400 085 (India)

    2013-02-05

    We have designed and fabricated parallel plate ionization chamber detectors and voltage vs. current characteristics (V-I curve) of the detectors were recorded with synchrotron radiation to qualify for use in X-ray Absorption Spectroscopy (XAS) measurements. After qualifying the ionization chambers, the detectors were used in the dispersive EXAFS beamline (BL-08) at INDUS-2 SRS in Turbo-XAS geometry. Using the same setup and under the same setting, XAS spectra were also recorded with a CCD detector and the observation on relative performance of the ionization chamber vis-a-vis the CCD detector is presented in this paper.

  1. Absorption spectroscopy of EBT model GAFCHROMIC film.

    Science.gov (United States)

    Devic, Slobodan; Tomic, Nada; Pang, Zhiyu; Seuntjens, Jan; Podgorsak, Ervin B; Soares, Christopher G

    2007-01-01

    The introduction of radiochromic films has solved some of the problems associated with conventional 2D radiation detectors. Their high spatial resolution, low energy dependence, and near-tissue equivalence make them ideal for measurement of dose distributions in radiation fields with high dose gradients. Precise knowledge of the absorption spectra of these detectors can help to develop more suitable optical densitometers and potentially extend the use of these films to other areas such as the measurement of the radiation beam spectral information. The goal of this study is to present results of absorption spectra measurements for the new GAFCHROMIC film, EBT type, exposed to 6 MV photon beam in the dose range from 0 to 6 Gy. Spectroscopic analysis reveals that in addition to the two main absorption peaks, centered at around 583 and 635 nm, the absorption spectrum in the spectral range from 350 to 800 nm contains six more absorption bands. Comparison of the absorption spectra reveals that previous HD-810, MD-55, as well as HS GAFCHROMIC film models, have nearly the same sensitive layer base material, whereas the new EBT model, GAFCHROMIC film has a different composition of its sensitive layer. We have found that the two most prominent absorption bands in EBT model radiochromic film do not change their central wavelength position with change in a dose deposited to the film samples.

  2. Smoothness in Binomial Edge Ideals

    Directory of Open Access Journals (Sweden)

    Hamid Damadi

    2016-06-01

    Full Text Available In this paper we study some geometric properties of the algebraic set associated to the binomial edge ideal of a graph. We study the singularity and smoothness of the algebraic set associated to the binomial edge ideal of a graph. Some of these algebraic sets are irreducible and some of them are reducible. If every irreducible component of the algebraic set is smooth we call the graph an edge smooth graph, otherwise it is called an edge singular graph. We show that complete graphs are edge smooth and introduce two conditions such that the graph G is edge singular if and only if it satisfies these conditions. Then, it is shown that cycles and most of trees are edge singular. In addition, it is proved that complete bipartite graphs are edge smooth.

  3. Radiation detector

    Energy Technology Data Exchange (ETDEWEB)

    Taleyarkhan, Rusi P.

    2017-06-27

    Alpha particle detecting devices are disclosed that have a chamber that can hold a fluid in a tensioned metastable state. The chamber is tuned with a suitable fluid and tension such that alpha emitting materials such as radon and one or more of its decay products can be detected. The devices can be portable and can be placed in areas, such as rooms in dwellings or laboratories and used to measure radon in these areas, in situ and in real time. The disclosed detectors can detect radon at and below 4 pCi/L in air; also, at and below 4,000 pCi/L or 300 pCi/L in water.

  4. A Detector for Cosmic Microwave Background Polarimetry

    Science.gov (United States)

    Wollack, E.; Cao, N.; Chuss, D.; Hsieh, W.-T.; Moseley, S. Harvey; Stevenson, T.; U-yen, K.

    2008-01-01

    We present preliminary design and development work on polarized detectors intended to enable Cosmic Microwave Background polarization measurements that will probe the first moments of the universe. The ultimate measurement will be challenging, requiring background-limited detectors and good control of systematic errors. Toward this end, we are integrating the beam control of HE-11 feedhorns with the sensitivity of transition-edge sensors. The coupling between these two devices is achieved via waveguide probe antennas and superconducting microstrip lines. This implementation allows band-pass filters to be incorporated on the detector chip. We believe that a large collection of single-mode polarized detectors will eventually be required for the reliable detection of the weak polarized signature that is expected to result from gravitational waves produced by cosmic inflation. This focal plane prototype is an important step along the path to this detection, resulting in a capability that will enable various future high performance instrument concepts.

  5. A Detector for Cosmic Microwave Background Polarimetry

    Science.gov (United States)

    Wollack, E.; Cao, N.; Chuss, D.; Hsieh, W.-T.; Moseley, S. Harvey; Stevenson, T.; U-yen, K.

    2008-01-01

    We present preliminary design and development work on polarized detectors intended to enable Cosmic Microwave Background polarization measurements that will probe the first moments of the universe. The ultimate measurement will be challenging, requiring background-limited detectors and good control of systematic errors. Toward this end, we are integrating the beam control of HE-11 feedhorns with the sensitivity of transition-edge sensors. The coupling between these two devices is achieved via waveguide probe antennas and superconducting microstrip lines. This implementation allows band-pass filters to be incorporated on the detector chip. We believe that a large collection of single-mode polarized detectors will eventually be required for the reliable detection of the weak polarized signature that is expected to result from gravitational waves produced by cosmic inflation. This focal plane prototype is an important step along the path to this detection, resulting in a capability that will enable various future high performance instrument concepts.

  6. High-Resolution X-ray Emission and X-ray Absorption Spectroscopy

    OpenAIRE

    de Groot, F. M. F.

    2001-01-01

    In this review, high-resolution X-ray emission and X-ray absorption spectroscopy will be discussed. The focus is on the 3d transition-metal systems. To understand high-resolution X-ray emission and reso-nant X-ray emission, it is first necessary to spend some time discussing the X-ray absorption process. Section II discusses 1s X-ray absorption, i.e., the K edges, and section III deals with 2p X-ray absorption, the L edges. X-ray emission is discussed in, respectively, the L edges. X-ray emis...

  7. The physics of nanowire superconducting single-photon detectors

    NARCIS (Netherlands)

    Renema, Jelmer Jan

    2015-01-01

    We investigate the detection mechanism in superconducting single photon detectors via quantum detector tomography. We find that the detection event is caused by diffusion of quasiparticles from the absorption spot, combined with entrance of a vortex. Moreover, we investigate the behaviour of

  8. X-Ray Absorption and Scattering by Interstellar Grains

    CERN Document Server

    Hoffman, John A

    2015-01-01

    Interstellar abundance determinations from fits to X-ray absorption edges often rely on the following false assumptions: (1) the grains are "optically thin" at the observed X-ray wavelengths, and (2) scattering is insignificant and can be ignored. We show instead that scattering contributes significantly to the attenuation of X-rays for realistic dust grain size distributions and substantially modifies the spectrum near absorption edges of elements present in grains. The dust attenuation modules used in major X-ray spectral fitting programs do not take this into account. We show that the consequences of neglecting scattering on the determination of interstellar elemental abundances are modest; however, scattering (along with uncertainties in the grain size distribution) must be taken into account when near-edge extinction fine structure is used to infer dust mineralogy. We advertise the benefits and accuracy of anomalous diffraction theory for both X-ray halo analysis and near edge absorption studies. An open...

  9. Combined use of synchrotron radiation based micro-X-ray fluorescence, micro-X-ray diffraction, micro-X-ray absorption near-edge, and micro-fourier transform infrared spectroscopies for revealing an alternative degradation pathway of the pigment cadmium yellow in a painting by Van Gogh.

    Science.gov (United States)

    Van der Snickt, Geert; Janssens, Koen; Dik, Joris; De Nolf, Wout; Vanmeert, Frederik; Jaroszewicz, Jacub; Cotte, Marine; Falkenberg, Gerald; Van der Loeff, Luuk

    2012-12-04

    Over the past years a number of studies have described the instability of the pigment cadmium yellow (CdS). In a previous paper we have shown how cadmium sulfide on paintings by James Ensor oxidizes to CdSO(4)·H(2)O. The degradation process gives rise to the fading of the bright yellow color and the formation of disfiguring white crystals that are present on the paint surface in approximately 50 μm sized globular agglomerations. Here, we study cadmium yellow in the painting "Flowers in a blue vase" by Vincent van Gogh. This painting differs from the Ensor case in the fact that (a) a varnish was superimposed onto the degraded paint surface and (b) the CdS paint area is entirely covered with an opaque crust. The latter obscures the yellow color completely and thus presents a seemingly more advanced state of degradation. Analysis of a cross-sectioned and a crushed sample by combining scanning microscopic X-ray diffraction (μ-XRD), microscopic X-ray absorption near-edge spectroscopy (μ-XANES), microscopic X-ray fluorescence (μ-XRF) based chemical state mapping and scanning microscopic Fourier transform infrared (μ-FT-IR) spectrometry allowed unravelling the complex alteration pathway. Although no crystalline CdSO(4) compounds were identified on the Van Gogh paint samples, we conclude that the observed degradation was initially caused by oxidation of the original CdS pigment, similar as for the previous Ensor case. However, due to the presence of an overlying varnish containing lead-based driers and oxalate ions, secondary reactions took place. In particular, it appears that upon the photoinduced oxidation of its sulfidic counterion, the Cd(2+) ions reprecipitated at the paint/varnish interface after having formed a complex with oxalate ions that themselves are considered to be degradation products of the resin and/or oil in the varnish. The SO(4)(2-) anions, for their part, found a suitable reaction partner in Pb(2+) ions stemming from a dissolved lead

  10. Comparative Analysis of Arsenic Speciation in Sediments of the Diaojiang River Using X-Ray Absorption Near Edge Structure Spectra and Sequential Chemical Extraction%刁江底泥砷形态的化学分级法与XANES方法比较

    Institute of Scientific and Technical Information of China (English)

    蹇丽; 黄泽春; 刘永轩; 杨子良; 胡天斗

    2012-01-01

    采用XANES(X射线近边分析)方法和化学分级法,研究了刁江污染源区尾砂及刁江底泥的砷形态组成特征.XANES方法结果表明,尾砂中砷的形态主要以毒砂(FeAsS)存在,其相对百分含量为63%~99%;而刁江底泥中的砷形态主要是毒砂、砷酸盐和亚砷酸盐,其中毒砂的比例较高,表现出典型的尾砂污染特征.化学分级法结果表明,尾砂中砷形态主要是残渣态砷(Res-As),而底泥中的砷主要以铁合态、钙合态及残渣态形式存在.刁江底泥中毒砂相对百分含量和残渣态砷随着与污染源区距离的增大而减小,砷酸盐和亚砷酸盐则呈相反的趋势.化学分级法和XANES方法所反映的刁江底泥和污染源的砷形态组成和变化趋势总体上较为一致,但这2种方法所获得的定量数据存在一定的差异.%Sequential chemical extraction method and X-Ray absorption near edge structure (XANES) spectra were used to investigate arsenic speciation in sediments of the Diaojiang River and tailings from a pollution source area. XANES spectra showed that arsenic was mainly present as arsenopyrite (FeAsS) in the tailings, with range from 63% to 99%. Arsenic fractions in the sediments were mainly present as arsenite, arsenate and arsenopyrite. A high proportion of FeAsS in the sediments showed the typical character of a mining tailing contaminated river. The relative percentage contents of FeAsS and Res-As in the sediments gradually decreased with the increase of distance to the pollution sources, while arsenite and arsenate showed the opposite pattern. The results from sequential chemical extraction method and XANES spectra showed that the composition and trend of arsenic speciation in pollution sources and sediments of the Diaojiang River were generally in good agreement, although the quantitative data from the two methods showed some differences.

  11. Neutron responsive self-powered radiation detector

    Science.gov (United States)

    Brown, Donald P.; Cannon, Collins P.

    1978-01-01

    An improved neutron responsive self-powered radiation detector is disclosed in which the neutron absorptive central emitter has a substantially neutron transmissive conductor collector sheath spaced about the emitter and the space between the emitter and collector sheath is evacuated.

  12. Solid-State Neutron Detector Device

    Science.gov (United States)

    Bensaoula, Abdelhak (Inventor); Starikov, David (Inventor); Pillai, Rajeev (Inventor)

    2017-01-01

    The structure and methods of fabricating a high efficiency compact solid state neutron detector based on III-Nitride semiconductor structures deposited on a substrate. The operation of the device is based on absorption of neutrons, which results in generation of free carriers.

  13. CLIC Detector Power Requirements

    CERN Document Server

    Gaddi, A

    2013-01-01

    An estimate for the CLIC detector power requirements is outlined starting from the available data on power consumptions of the four LHC experiments and considering the differences between a typical LHC Detector (CMS) and the CLIC baseline detector concept. In particular the impact of the power pulsing scheme for the CLIC Detector electronics on the overall detector consumption is considered. The document will be updated with the requirements of the sub-detector electronics once they are more defined.

  14. Pixel Vertex Detectors

    OpenAIRE

    Wermes, Norbert

    2006-01-01

    Pixel vertex detectors are THE instrument of choice for the tracking of charged particles close to the interaction point at the LHC. Hybrid pixel detectors, in which sensor and read-out IC are separate entities, constitute the present state of the art in detector technology. Three of the LHC detectors use vertex detectors based on this technology. A development period of almost 10 years has resulted in pixel detector modules which can stand the extreme rate and timing requirements as well as ...

  15. Diamond detector - material science, design and application

    Science.gov (United States)

    Gaowei, Mengjia

    diamond valence-band maximum was determined by theoretically calculating the diamond density of states and applying cross section corrections. The diamond-platinum Schottky barrier height was lowered by 0.2 eV after thermal annealing, indicating annealing may increase carrier injection in diamond devices leading to photoconductive gain. In order to adapt our device to soft x-ray applications, efforts are made to develop a thin diamond position monitor for lowering device absorption. In section 5 we have discussed the fabrication and testing of thin diamond x-ray monitors made from diamond plates with nominal thickness of 30microm, which is 1/10th of the thickness of the diamonds we previously used. Calibration results of this detector are presented and discussed in comparison with thicker diamond sensors. Section 6 introduces our effort on the investigation of carrier loss mechanism in diamond detectors. Near edge responsivity in diamond x-ray detectors has been used to confirm the carrier loss mechanism as recombination due to diffusion into the incident electrode. We present a detailed study of the bias dependence of the diamond responsivity across the carbon k-edge. The carrier loss is modeled by incorporating a characteristic recombination length into the absorption model and is shown to agree well with Monte Carlo simulated carrier losses. In addition, nitrogen doped ultrananocrystalline diamond (nUNCD) grown on the surface of a CVD single crystal diamond as an alternative contact to metal is tested in the similar measurements as the metal contact diamond. nUNCD has a much lower x-ray absorption than metal contacts and is designed to improve the performance of our device. This diamond is calibrated over a wide photon energy range from 0.2 keV to 28 keV, and compared with platinum coated diamond. Results of these studies will be presented and discussed in section 7. Future work has been proposed in the last section in improving the design and fabrication of diamond

  16. Design of transition edge sensor microcalorimeters for optimal performance

    Energy Technology Data Exchange (ETDEWEB)

    Bandler, S.R. E-mail: sbandler@milkyway.gsfc.nasa.gov; Figueroa-Feliciano, E.; Stahle, C.K.; Boyce, K.; Brekosky, R.; Chervenak, J.; Finkbeiner, F.; Kelley, R.; Lindeman, M.; Porter, F.S.; Saab, T

    2004-03-11

    We have developed a model for transition edge sensors to optimize performance under a variety of different conditions. There are three design trade-offs when engineering a microcalorimeter for a particular application: energy resolution, energy range and maximum count rate. All three are interdependent and are determined by various design parameters such as the detector heat capacity, the sharpness of the transition, and the thermal conductance of the detector to the frame. Our model includes all known sources of intrinsic noise in our calorimeters including the observed broad band excess noise. We will present the results of this model, and its predictions for optimally designed microcalorimeters.

  17. Topological Number of Edge States

    CERN Document Server

    Hashimoto, Koji

    2016-01-01

    We show that the edge states of the four-dimensional class A system can have topological charges, which are characterized by Abelian/non-Abelian monopoles. The edge topological charges are a new feature of relations among theories with different dimensions. From this novel viewpoint, we provide a non-Abelian analogue of the TKNN number as an edge topological charge, which is defined by an SU(2) 't Hooft-Polyakov BPS monopole through an equivalence to Nahm construction. Furthermore, putting a constant magnetic field yields an edge monopole in a non-commutative momentum space, where D-brane methods in string theory facilitate study of edge fermions.

  18. Electrochemistry of folded graphene edges.

    Science.gov (United States)

    Ambrosi, Adriano; Bonanni, Alessandra; Pumera, Martin

    2011-05-01

    There is enormous interest in the investigation of electron transfer rates at the edges of graphene due to possible energy storage and sensing applications. While electrochemistry at the edges and the basal plane of graphene has been studied in the past, the new frontier is the electrochemistry of folded graphene edges. Here we describe the electrochemistry of folded graphene edges and compare it to that of open graphene edges. The materials were characterized in detail by high-resolution transmission electron microscopy, Raman spectroscopy, high-resolution X-ray photoelectron spectroscopy, electrochemical impedance spectroscopy and cyclic voltammetry. We found that the heterogeneous electron transfer rate is significantly lower on folded graphene edges compared to open edge sites for ferro/ferricyanide, and that electrochemical properties of open edges offer lower potential detection of biomarkers than the folded ones. It is apparent, therefore, that for sensing and biosensing applications the folded edges are less active than open edges, which should then be preferred for such applications. As folded edges are the product of thermal treatment of multilayer graphene, such thermal procedures should be avoided when fabricating graphene for electrochemical applications.

  19. EDGE COVERING COLORING AND FRACTIONAL EDGE COVERING COLORING

    Institute of Scientific and Technical Information of China (English)

    MIAOLianying; LIUGuizhen

    2002-01-01

    Let G be a graph with edge set E(G).S E(G)is called an edge cover of G if every vertex of G is an end vertex of some edges in S.The edge covering chromatic number of a graph G,denoted by Xc(G),is the maximum size of a partition of E(G) into edge covers of G.It is known that for any graph G with minimum degree δ,δ-1≤Xc(G)≤δ.The fractional edge covering chromatic number of a graph G,denoted by Xcf(G),is the fractional matiching number of the edge covering hypergraph H of G whose vertices are the edges of G and whose hypereges the edge covers of G.In this paper,we study the relation between Xc(G) and δfor any graph G,and give a new simple proof of the inequalities δ-1≤Xc(G)≤δ by the technique of graph coloring.For any graph G,we give an exact formula o Xcf(G),that is,Xcf(G)=min{δ,λ(G)},where λ(G)=minCS/S/2 and the minimum is taken over all noempty subsets S of V(G) and C[S] is the set of edges that have at least one end in S.δ

  20. EDGE COVERING COLORING AND FRACTIONAL EDGE COVERING COLORING

    Institute of Scientific and Technical Information of China (English)

    MIAO Lianying; LIU Guizhen

    2002-01-01

    Let G be a graph with edge set E(G). S _C E(G) is called an edge cover of G if every vertex of G is an end vertex of some edges in S. The edge covering chromatic number of a graph G, denoted by X'c(G) , is the maximum size of a partition of E(G) into edge covers of G. It is known that for any graph G with minimum degree δ, δ - 1 ≤ X'c(G) ≤ δ.The fractional edge covering chromatic number of a graph G, denoted by X'cf(G), is the fractional matching number of the edge covering hypergraph H of G whose vertices are the edges of G and whose hyperedges the edge covers of G. In this paper, we study the relation between X'c(G) and δ for any graph G, and give a new simple proof of the inequalities δ - 1 ≤ X'c(G) ≤ δ by the technique of graph coloring. For any graph G, we give an exact formula of X'cf(G), that is, X'cf(G)=min{δ,λ(G)}, where λ(G)=min |C[S]|/[|S|/2]and the minimum is taken over all noempty subsets S of V(G) and C[S] is the set of edges that have at least one end in S.

  1. Determination of the total absorption peak in an electromagnetic calorimeter

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Jia-Hua [Institute of Physics, National Chiao-Tung University, Hsinchu (China); Wang, Zhe, E-mail: wangzhe-hep@mail.tsinghua.edu.cn [Department of Engineering Physics, Tsinghua University, Beijing (China); Key Laboratory of Particle & Radiation Imaging (Tsinghua University), Ministry of Education (China); Lebanowski, Logan [Department of Engineering Physics, Tsinghua University, Beijing (China); Key Laboratory of Particle & Radiation Imaging (Tsinghua University), Ministry of Education (China); Lin, Guey-Lin [Institute of Physics, National Chiao-Tung University, Hsinchu (China); Chen, Shaomin [Department of Engineering Physics, Tsinghua University, Beijing (China); Key Laboratory of Particle & Radiation Imaging (Tsinghua University), Ministry of Education (China)

    2016-08-11

    A physically motivated function was developed to accurately determine the total absorption peak in an electromagnetic calorimeter and to overcome biases present in many commonly used methods. The function is the convolution of a detector resolution function with the sum of a delta function, which represents the complete absorption of energy, and a tail function, which describes the partial absorption of energy and depends on the detector materials and structures. Its performance was tested with the simulation of three typical cases. The accuracy of the extracted peak value, resolution, and peak area was improved by an order of magnitude on average, relative to the Crystal Ball function.

  2. Determination of the total absorption peak in an electromagnetic calorimeter

    CERN Document Server

    Cheng, Jia-Hua; Lebanowski, Logan; Lin, Guey-Lin; Chen, Shaomin

    2016-01-01

    A physically-motivated function was developed to accurately determine the total absorption peak in an electromagnetic calorimeter and to overcome biases present in many commonly used methods. The function is the convolution of a detector resolution function with the sum of a delta function, which represents the complete absorption of energy, and a tail function, which describes the partial absorption of energy and depends on the detector materials and structures. Its performance was tested with the simulation of three typical cases. The accuracy of the extracted peak value, resolution, and peak area was improved by an order of magnitude on average, relative to the Crystal Ball function.

  3. MUON DETECTOR

    CERN Multimedia

    F. Gasparini

    DT As announced in the previous Bulletin MU DT completed the installation of the vertical chambers of barrel wheels 0, +1 and +2. 242 DT and RPC stations are now installed in the negative barrel wheels. The missing 8 (4 in YB-1 and 4 in YB-2) chambers can be installed only after the lowering of the two wheels into the UX cavern, which is planned for the last quarter of the year. Cabling on the surface of the negative wheels was finished in May after some difficulties with RPC cables. The next step was to begin the final commissioning of the wheels with the final trigger and readout electronics. Priority was giv¬en to YB0 in order to check everything before the chambers were covered by cables and services of the inner detectors. Commissioning is not easy since it requires both activity on the central and positive wheels underground, as well as on the negative wheels still on the surface. The DT community is requested to commission the negative wheels on surface to cope with a possible lack of time a...

  4. An iris segmentation algorithm based on edge orientation for off-angle iris recognition

    Science.gov (United States)

    Karakaya, Mahmut; Barstow, Del; Santos-Villalobos, Hector; Boehnen, Christopher

    2013-03-01

    Iris recognition is known as one of the most accurate and reliable biometrics. However, the accuracy of iris recognition systems depends on the quality of data capture and is negatively affected by several factors such as angle, occlusion, and dilation. In this paper, we present a segmentation algorithm for off-angle iris images that uses edge detection, edge elimination, edge classification, and ellipse fitting techniques. In our approach, we first detect all candidate edges in the iris image by using the canny edge detector; this collection contains edges from the iris and pupil boundaries as well as eyelash, eyelids, iris texture etc. Edge orientation is used to eliminate the edges that cannot be part of the iris or pupil. Then, we classify the remaining edge points into two sets as pupil edges and iris edges. Finally, we randomly generate subsets of iris and pupil edge points, fit ellipses for each subset, select ellipses with similar parameters, and average to form the resultant ellipses. Based on the results from real experiments, the proposed method shows effectiveness in segmentation for off-angle iris images.

  5. An Iris Segmentation Algorithm based on Edge Orientation for Off-angle Iris Recognition

    Energy Technology Data Exchange (ETDEWEB)

    Karakaya, Mahmut [ORNL; Barstow, Del R [ORNL; Santos-Villalobos, Hector J [ORNL; Boehnen, Chris Bensing [ORNL

    2013-01-01

    Iris recognition is known as one of the most accurate and reliable biometrics. However, the accuracy of iris recognition systems depends on the quality of data capture and is negatively affected by several factors such as angle, occlusion, and dilation. In this paper, we present a segmentation algorithm for off-angle iris images that uses edge detection, edge elimination, edge classification, and ellipse fitting techniques. In our approach, we first detect all candidate edges in the iris image by using the canny edge detector; this collection contains edges from the iris and pupil boundaries as well as eyelash, eyelids, iris texture etc. Edge orientation is used to eliminate the edges that cannot be part of the iris or pupil. Then, we classify the remaining edge points into two sets as pupil edges and iris edges. Finally, we randomly generate subsets of iris and pupil edge points, fit ellipses for each subset, select ellipses with similar parameters, and average to form the resultant ellipses. Based on the results from real experiments, the proposed method shows effectiveness in segmentation for off-angle iris images.

  6. Overview on low-flux detectors

    Energy Technology Data Exchange (ETDEWEB)

    Seggern, Jan Eike von

    2013-10-15

    Laboratory based searches for weakly-interacting slim particles (WISPs) of the light-shining-through-a-wall type (LSW) use visible or near-infrared (NIR) laser light. Low-noise and highly efficient detectors are necessary to improve over previous experiments. These requirements overlap with the requirements for single-photon detectors (SPDs) for quantum information (QI) experiments. In this contribution, the sensitivity of several QI SPDs is compared to photo-multiplier tubes (PMTs) and imaging charge-coupled devices (CCDs). It is found that only transition edge sensors (TESs) are viable alternatives to CCDs if the signal can be focussed to a few {mu}m.

  7. Overview on Low-flux Detectors

    CERN Document Server

    von Seggern, Jan Eike

    2013-01-01

    Laboratory based searches for weakly-interacting slim particles (WISPs) of the light-shining-through-a-wall type (LSW) use visible or near-infrared (NIR) laser light. Low-noise and highly efficient detectors are necessary to improve over previous experiments. These requirements overlap with the requirements for single-photon detectors (SPDs) for quantum information (QI) experiments. In this contribution, the sensitivity of several QI SPDs is compared to photo-multiplier tubes (PMTs) and imaging charge-coupled devices (CCDs). It is found that only transition edge sensors (TESs) are viable alternatives to CCDs if the signal can be focussed to a few micro meters.

  8. Comparison measurements of DQE for two flat panel detectors: fluoroscopic detector vs. cone beam CT detector

    Science.gov (United States)

    Betancourt Benítez, Ricardo; Ning, Ruola; Conover, David

    2006-03-01

    The physical performance of two flat panel detectors (FPD) has been evaluated using a standard x-ray beam quality set by IEC, namely RQA5. The FPDs evaluated in this study are based on an amorphous silicon photodiode array that is coupled to a thallium-doped Cesium Iodide scintillator and to a thin film transistor (TFT) array. One detector is the PaxScan 2520 that is designed for fluoro imaging, and has a small dynamic range and a large image lag. The other detector is the PaxScan 4030CB that is designed for cone beam CT, and has a large dynamic range (>16-bit), a reduced image lag and many imaging modes. Varian Medical Systems manufactured both detectors. The linearity of the FPDs was investigated by using an ionization chamber and aluminum filtration in order to obtain the beam quality. Since the FPDs are used in fluoroscopic mode, image lag of the FPD was measured in order to investigate its effect on this study, especially its effect on DQE. The spatial resolution of the FPDs was determined by obtaining the pre-sampling modulation transfer function for each detector. A sharp edge was used in accordance to IEC 62220-1. Next, the Normalized Noise Power Spectrum (NNPS) was calculated for various exposures levels at RQA5 radiation quality. Finally, the DQE of each FPD was obtained with a modified version of the international standard set by IEC 62220-1. The results show that the physical performance in DQE and MTF of the PaxScan 4030CB is superior to that of PaxScan2520.

  9. Examination of the Measurement of Absorption Using the Reverberant Room Method for Highly Absorptive Acoustic Foam

    Science.gov (United States)

    Hughes, William O.; McNelis, Anne M.; Chris Nottoli; Eric Wolfram

    2015-01-01

    The absorption coefficient for material specimens are needed to quantify the expected acoustic performance of that material in its actual usage and environment. The ASTM C423-09a standard, "Standard Test Method for Sound Absorption and Sound Absorption Coefficients by the Reverberant Room Method" is often used to measure the absorption coefficient of material test specimens. This method has its basics in the Sabine formula. Although widely used, the interpretation of these measurements are a topic of interest. For example, in certain cases the measured Sabine absorption coefficients are greater than 1.0 for highly absorptive materials. This is often attributed to the diffraction edge effect phenomenon. An investigative test program to measure the absorption properties of highly absorbent melamine foam has been performed at the Riverbank Acoustical Laboratories. This paper will present and discuss the test results relating to the effect of the test materials' surface area, thickness and edge sealing conditions. A follow-on paper is envisioned that will present and discuss the results relating to the spacing between multiple piece specimens, and the mounting condition of the test specimen.

  10. Edge remap for solids

    Energy Technology Data Exchange (ETDEWEB)

    Kamm, James R.; Love, Edward; Robinson, Allen C; Young, Joseph G.; Ridzal, Denis

    2013-12-01

    We review the edge element formulation for describing the kinematics of hyperelastic solids. This approach is used to frame the problem of remapping the inverse deformation gradient for Arbitrary Lagrangian-Eulerian (ALE) simulations of solid dynamics. For hyperelastic materials, the stress state is completely determined by the deformation gradient, so remapping this quantity effectively updates the stress state of the material. A method, inspired by the constrained transport remap in electromagnetics, is reviewed, according to which the zero-curl constraint on the inverse deformation gradient is implicitly satisfied. Open issues related to the accuracy of this approach are identified. An optimization-based approach is implemented to enforce positivity of the determinant of the deformation gradient. The efficacy of this approach is illustrated with numerical examples.

  11. Evaluation of the effective focal spot size of x-ray tubes by utilizing the edge response analysis

    Science.gov (United States)

    Nishiki, Masayuki

    2015-03-01

    Evaluation of the effective focal spot size of X-ray tube has been made utilizing the slit or the pin-hole camera, but is not widely used in a daily practice due to the need of specialized tools. The author proposes a simplified method in which only a metal edge and a digital detector are used, together with a process of removing detector blur inherently associated with the adoption of such a detector. The evaluation was made through the OTF (Optical Transfer Function) measurements by using the edge response analysis. Through the whole study, the use of OTF instead of MTF (Modulation Transfer Function) was essential in order to stay within the linear systems theory framework, at cost of handling complex functions. Evaluation steps were as follows; 1. The inherent OTF of the detector (OTFdet) was measured by acquiring an image of the edge being closely contacted to the detector. 2. The second OTF (OTFmulti) was measured with the edge placed apart from the detector so as to implement 2 times geometrical magnification of the edge. OTFmulti is the product of OTFdet and the focal spot OTF (OTFfocus). 3. OTFfocus was obtained by calculating OTFmulti / OTFdet, thus removing the detector blur completely. 4. The LSF of the focal spot was obtained through the inverse Fourier transform of OTFfocus. The resultant LSFfocus was assured to be a real function due to the fact that original LSFdet and LSFmulti were both real functions. Preliminary results well matched those obtained by the pinhole camera.

  12. Fano fluctuations in superconducting-nanowire single-photon detectors

    Science.gov (United States)

    Kozorezov, A. G.; Lambert, C.; Marsili, F.; Stevens, M. J.; Verma, V. B.; Allmaras, J. P.; Shaw, M. D.; Mirin, R. P.; Nam, Sae Woo

    2017-08-01

    Because of their universal nature, Fano fluctuations are expected to influence the response of superconducting-nanowire single-photon detectors (SNSPDs). We predict that photon counting rate (P C R ) as a function of bias current (IB) in SNSPDs is described by an integral over a transverse coordinate-dependent complementary error function. Fano fluctuations in the amount of energy deposited into the electronic system contribute to the finite width of this error function Δ IB . The local response of an SNSPD can also affect this width: the location of the initial photon absorption site across the width of the wire can impact the probability of vortex-antivortex unbinding and vortex entry from the edges. In narrow-nanowire SNSPDs, the local responses are uniform, and Fano fluctuations dominate Δ IB . We demonstrate good agreement between theory and experiments for a series of bath temperatures and photon energies in narrow-wire WSi SNSPDs. In a wide-nanowire device, the strong local dependence will introduce a finite width to the P C R curve, but with sharp cusps. We show how Fano fluctuations can smooth these features to produce theoretical curves that better match experimental data. We also show that the time-resolved hotspot relaxation curves predicted by Fano fluctuations match the previously measured Lorentzian shapes (except for their tails) over the entire range of bias currents investigated experimentally.

  13. Edge phonons in black phosphorus

    Science.gov (United States)

    Ribeiro, H. B.; Villegas, C. E. P.; Bahamon, D. A.; Muraca, D.; Castro Neto, A. H.; de Souza, E. A. T.; Rocha, A. R.; Pimenta, M. A.; de Matos, C. J. S.

    2016-07-01

    Black phosphorus has recently emerged as a new layered crystal that, due to its peculiar and anisotropic crystalline and electronic band structures, may have important applications in electronics, optoelectronics and photonics. Despite the fact that the edges of layered crystals host a range of singular properties whose characterization and exploitation are of utmost importance for device development, the edges of black phosphorus remain poorly characterized. In this work, the atomic structure and behaviour of phonons near different black phosphorus edges are experimentally and theoretically studied using Raman spectroscopy and density functional theory calculations. Polarized Raman results show the appearance of new modes at the edges of the sample, and their spectra depend on the atomic structure of the edges (zigzag or armchair). Theoretical simulations confirm that the new modes are due to edge phonon states that are forbidden in the bulk, and originated from the lattice termination rearrangements.

  14. Event processing in X-IFU detector onboard Athena.

    Science.gov (United States)

    Ceballos, M. T.; Cobos, B.; van der Kuurs, J.; Fraga-Encinas, R.

    2015-05-01

    The X-ray Observatory ATHENA was proposed in April 2014 as the mission to implement the science theme "The Hot and Energetic Universe" selected by ESA for L2 (the second Large-class mission in ESA's Cosmic Vision science programme). One of the two X-ray detectors designed to be onboard ATHENA is X-IFU, a cryogenic microcalorimeter based on Transition Edge Sensor (TES) technology that will provide spatially resolved high-resolution spectroscopy. X-IFU will be developed by a consortium of European research institutions currently from France (leadership), Italy, The Netherlands, Belgium, UK, Germany and Spain. From Spain, IFCA (CSIC-UC) is involved in the Digital Readout Electronics (DRE) unit of the X-IFU detector, in particular in the Event Processor Subsytem. We at IFCA are in charge of the development and implementation in the DRE unit of the Event Processing algorithms, designed to recognize, from a noisy signal, the intensity pulses generated by the absorption of the X-ray photons, and lately extract their main parameters (coordinates, energy, arrival time, grade, etc.) Here we will present the design and performance of the algorithms developed for the event recognition (adjusted derivative), and pulse grading/qualification as well as the progress in the algorithms designed to extract the energy content of the pulses (pulse optimal filtering). IFCA will finally have the responsibility of the implementation on board in the (TBD) FPGAs or micro-processors of the DRE unit, where this Event Processing part will take place, to fit into the limited telemetry of the instrument.

  15. Self consistent, absolute calibration technique for photon number resolving detectors.

    Science.gov (United States)

    Avella, A; Brida, G; Degiovanni, I P; Genovese, M; Gramegna, M; Lolli, L; Monticone, E; Portesi, C; Rajteri, M; Rastello, M L; Taralli, E; Traina, P; White, M

    2011-11-07

    Well characterized photon number resolving detectors are a requirement for many applications ranging from quantum information and quantum metrology to the foundations of quantum mechanics. This prompts the necessity for reliable calibration techniques at the single photon level. In this paper we propose an innovative absolute calibration technique for photon number resolving detectors, using a pulsed heralded photon source based on parametric down conversion. The technique, being absolute, does not require reference standards and is independent upon the performances of the heralding detector. The method provides the results of quantum efficiency for the heralded detector as a function of detected photon numbers. Furthermore, we prove its validity by performing the calibration of a Transition Edge Sensor based detector, a real photon number resolving detector that has recently demonstrated its effectiveness in various quantum information protocols.

  16. Characterization of edgeless pixel detectors coupled to Medipix2 readout chip

    Science.gov (United States)

    Kalliopuska, Juha; Tlustos, Lukas; Eränen, Simo; Virolainen, Tuula

    2011-08-01

    VTT has developed a straightforward and fast process to fabricate four-side buttable (edgeless) microstrip and pixel detectors on 6 in. (150 mm) wafers. The process relies on advanced ion implantation to activate the edges of the detector instead of using polysilicon. The article characterizes 150 μm thick n-on-n edgeless pixel detector prototypes with a dead layer at the edge below 1 μm. Electrical and radiation response characterization of 1.4×1.4 cm2 n-on-n edgeless detectors has been done by coupling them to the Medipix2 readout chips. The distance of the detector's physical edge from the pixels was either 20 or 50 μm. The leakage current of flip-chip bonded edgeless Medipix2 detector assembles were measured to be ˜90 nA/cm2 and no breakdown was observed below 110 V. Radiation response characterization includes X-ray tube and radiation source responses. The characterization results show that the detector's response at the pixels close to the physical edge of the detector depend dramatically on the pixel-to-edge distance.

  17. Ca L2,3-edge XANES and Sr K-edge EXAFS study of hydroxyapatite and fossil bone apatite.

    Science.gov (United States)

    Zougrou, I M; Katsikini, M; Brzhezinskaya, M; Pinakidou, F; Papadopoulou, L; Tsoukala, E; Paloura, E C

    2016-08-01

    Upon burial, the organic and inorganic components of hard tissues such as bone, teeth, and tusks are subjected to various alterations as a result of interactions with the chemical milieu of soil, groundwater, and presence of microorganisms. In this study, simulation of the Ca L 2,3-edge X-ray absorption near edge structure (XANES) spectrum of hydroxyapatite, using the CTM4XAS code, reveals that the different symmetry of the two nonequivalent Ca(1) and Ca(2) sites in the unit cell gives rise to specific spectral features. Moreover, Ca L 2,3-edge XANES spectroscopy is applied in order to assess variations in fossil bone apatite crystallinity due to heavy bacterial alteration and catastrophic mineral dissolution, compared to well-preserved fossil apatite, fresh bone, and geologic apatite reference samples. Fossilization-induced chemical alterations are investigated by means of Ca L 2,3-edge XANES and scanning electron microscopy (SEM) and are related to histological evaluation using optical microscopy images. Finally, the variations in the bonding environment of Sr and its preference for substitution in the Ca(1) or Ca(2) sites upon increasing the Sr/Ca ratio is assessed by Sr K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy.

  18. Ca L2,3-edge XANES and Sr K-edge EXAFS study of hydroxyapatite and fossil bone apatite

    Science.gov (United States)

    Zougrou, I. M.; Katsikini, M.; Brzhezinskaya, M.; Pinakidou, F.; Papadopoulou, L.; Tsoukala, E.; Paloura, E. C.

    2016-08-01

    Upon burial, the organic and inorganic components of hard tissues such as bone, teeth, and tusks are subjected to various alterations as a result of interactions with the chemical milieu of soil, groundwater, and presence of microorganisms. In this study, simulation of the Ca L 2,3-edge X-ray absorption near edge structure (XANES) spectrum of hydroxyapatite, using the CTM4XAS code, reveals that the different symmetry of the two nonequivalent Ca(1) and Ca(2) sites in the unit cell gives rise to specific spectral features. Moreover, Ca L 2,3-edge XANES spectroscopy is applied in order to assess variations in fossil bone apatite crystallinity due to heavy bacterial alteration and catastrophic mineral dissolution, compared to well-preserved fossil apatite, fresh bone, and geologic apatite reference samples. Fossilization-induced chemical alterations are investigated by means of Ca L 2,3-edge XANES and scanning electron microscopy (SEM) and are related to histological evaluation using optical microscopy images. Finally, the variations in the bonding environment of Sr and its preference for substitution in the Ca(1) or Ca(2) sites upon increasing the Sr/Ca ratio is assessed by Sr K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy.

  19. Reflection symmetry detection using locally affine invariant edge correspondence.

    Science.gov (United States)

    Wang, Zhaozhong; Tang, Zesheng; Zhang, Xiao

    2015-04-01

    Reflection symmetry detection receives increasing attentions in recent years. The state-of-the-art algorithms mainly use the matching of intensity-based features (such as the SIFT) within a single image to find symmetry axes. This paper proposes a novel approach by establishing the correspondence of locally affine invariant edge-based features, which are superior to the intensity based in the aspects that it is insensitive to illumination variations, and applicable to textureless objects. The locally affine invariance is achieved by simple linear algebra for efficient and robust computations, making the algorithm suitable for detections under object distortions like perspective projection. Commonly used edge detectors and a voting process are, respectively, used before and after the edge description and matching steps to form a complete reflection detection pipeline. Experiments are performed using synthetic and real-world images with both multiple and single reflection symmetry axis. The test results are compared with existing algorithms to validate the proposed method.

  20. 2-D MULTIRATE ALGORITHMS FOR EFFICIENT IMPLEMENTATION OF EDGE DETECTION

    Institute of Scientific and Technical Information of China (English)

    Chen Ken; Wang Ping

    2005-01-01

    Edge detection is a fundamental issue in image analysis. This paper proposes multirate algorithms for efficient implementation of edge detector, and a design example is illustrated.The multirate (decimation and/or interpolation) signal processing algorithms can achieve considerable savings in computation and storage. The proposed algorithms result in mapping relations of their z-transfer functions between non-multirate and multirate mathematical expressions in terms of time-varying coefficient instead of traditional polyphase decomposition counterparts.The mapping properties can be readily utilized to efficiently analyze and synthesize multirate edge detection filters. The Very high-speed Hardware Description Language (VHDL) simulation results verify efficiency of the algorithms for real-time Field Programmable Gate-Array (FPGA)implementation.

  1. Liver ultrasound image classification by using fractal dimension of edge

    Science.gov (United States)

    Moldovanu, Simona; Bibicu, Dorin; Moraru, Luminita

    2012-08-01

    Medical ultrasound image edge detection is an important component in increasing the number of application of segmentation, and hence it has been subject of many studies in the literature. In this study, we have classified the liver ultrasound images (US) combining Canny and Sobel edge detectors with fractal analysis in order to provide an indicator about of the US images roughness. We intend to provide a classification rule of the focal liver lesions as: cirrhotic liver, liver hemangioma and healthy liver. For edges detection the Canny and Sobel operators were used. Fractal analyses have been applied for texture analysis and classification of focal liver lesions according to fractal dimension (FD) determined by using the Box Counting method. To assess the performance and accuracy rate of the proposed method the contrast-to-noise (CNR) is analyzed.

  2. Optical nonlinearities in semiconductor-doped glasses near and below the band edge

    Science.gov (United States)

    Bindra, K. S.; Oak, S. M.; Rustagi, K. C.

    1998-03-01

    We present a brief review of our recent experimental results on optical nonlinearities in semiconductor-doped glasses. It is shown that even below the absorption edge the nonlinearities are determined by nonlinear absorption. The optical Kerr effect is found to have a susceptibility which is comparable to that for nonlinear refraction. We also find that in degenerate four-wave mixing the observed intensity dependence can be strongly influenced by nonlinear absorption.

  3. Electrical properties of the sensitive side in Si edgeless detectors

    CERN Document Server

    Verbitskaya, E; Eremin, I; Ilyashenko, I; Cavallini, A; Castaldini, A; Pellegrini, G; Lozano, M; Golubkov, S; Egorov, N; Konkov, K; Tuuva, T

    2009-01-01

    Silicon edgeless detectors represent a novel type of detector that are being developed for close-to-beam applications in high-energy physics and for large-scale tiled 1D and 2D arrays used in radiation imaging. In this work, the electric field and potential distributions on the device cut side, key factors in detector performance, have been investigated using two methods—the Conductive Microprobe Technique and the Scanning Transient Current Technique. It has been found that the behaviour of the potential distribution at the edge indicates a significant presence of positively charged states, with the charge density changing with the applied voltage. This work will predict, to a first approximation, the trend of the electric field at the edge of these devices after irradiation to high fluences. This prediction will provide key inputs in the development of edgeless radiation hard detectors.

  4. Current gain mechanism in planar GaAs MESFETs due to new photovoltaic self-biasing edge-effect.

    OpenAIRE

    Abbott, Derek; Eshraghian, K.

    1996-01-01

    A significant new internal gain effect, in planar MES­FETs has been discovered which we call the "photo­voltaic self-biasing edge-effect." The edge-effect can be exploited to attain up to a factor of ten improvement in detector photosensitivity.

  5. Edge conduction in vacuum glazing

    Energy Technology Data Exchange (ETDEWEB)

    Simko, T.M.; Collins, R.E. [Sydney Univ., NSW (Australia). Dept. of Applied Physics; Beck, F.A.; Arasteh, D. [Lawrence Berkeley Lab., CA (United States)

    1995-03-01

    Vacuum glazing is a form of low-conductance double glazing using in internal vacuum between the two glass sheets to eliminate heat transport by gas conduction and convection. An array of small support pillars separates the sheets; fused solder glass forms the edge seal. Heat transfer through the glazing occurs by radiation across the vacuum gap, conduction through the support pillars, and conduction through the bonded edge seal. Edge conduction is problematic because it affects stresses in the edge region, leading to possible failure of the glazing; in addition, excessive heat transfer because of thermal bridging in the edge region can lower overall window thermal performance and decrease resistance to condensation. Infrared thermography was used to analyze the thermal performance of prototype vacuum glazings, and, for comparison, atmospheric pressure superwindows. Research focused on mitigating the edge effects of vacuum glazings through the use of insulating trim, recessed edges, and framing materials. Experimentally validated finite-element and finite-difference modeling tools were used for thermal analysis of prototype vacuum glazing units and complete windows. Experimental measurements of edge conduction using infrared imaging were found to be in good agreement with finite-element modeling results for a given set of conditions. Finite-element modeling validates an analytic model developed for edge conduction.

  6. Edge effects in a small pixel CdTe for X-ray imaging

    Science.gov (United States)

    Duarte, D. D.; Bell, S. J.; Lipp, J.; Schneider, A.; Seller, P.; Veale, M. C.; Wilson, M. D.; Baker, M. A.; Sellin, P. J.; Kachkanov, V.; Sawhney, K. J. S.

    2013-10-01

    Large area detectors capable of operating with high detection efficiency at energies above 30 keV are required in many contemporary X-ray imaging applications. The properties of high Z compound semiconductors, such as CdTe, make them ideally suitable to these applications. The STFC Rutherford Appleton Laboratory has developed a small pixel CdTe detector with 80 × 80 pixels on a 250 μm pitch. Historically, these detectors have included a 200 μm wide guard band around the pixelated anode to reduce the effect of defects in the crystal edge. The latest version of the detector ASIC is capable of four-side butting that allows the tiling of N × N flat panel arrays. To limit the dead space between modules to the width of one pixel, edgeless detector geometries have been developed where the active volume of the detector extends to the physical edge of the crystal. The spectroscopic performance of an edgeless CdTe detector bump bonded to the HEXITEC ASIC was tested with sealed radiation sources and compared with a monochromatic X-ray micro-beam mapping measurements made at the Diamond Light Source, U.K. The average energy resolution at 59.54 keV of bulk and edge pixels was 1.23 keV and 1.58 keV, respectively. 87% of the edge pixels present fully spectroscopic performance demonstrating that edgeless CdTe detectors are a promising technology for the production of large panel radiation detectors for X-ray imaging.

  7. Plasmonic lens enhanced mid-infrared quantum cascade detector

    Energy Technology Data Exchange (ETDEWEB)

    Harrer, Andreas, E-mail: andreas.harrer@tuwien.ac.at; Schwarz, Benedikt; Gansch, Roman; Reininger, Peter; Detz, Hermann; Zederbauer, Tobias; Andrews, Aaron Maxwell; Schrenk, Werner; Strasser, Gottfried [Institute for Solid State Electronics and Center for Micro- and Nanostructures, Vienna University of Technology, 1040 Vienna (Austria)

    2014-10-27

    We demonstrate monolithic integrated quantum cascade detectors enhanced by plasmonic lenses. Surface normal incident mid-infrared radiation is coupled to surface plasmon polaritons guided to and detected by the active region of the detector. The lens extends the optical effective active area of the device up to a 5 times larger area than for standard mesa detectors or pixel devices while the electrical active region stays the same. The extended optical area increases the absorption efficiency of the presented device as well as the room temperature performance while it offers a flexible platform for various detector geometries. A photocurrent response increase at room temperature up to a factor of 6 was observed.

  8. Cutting Edge Localisation in an Edge Profile Milling Head

    NARCIS (Netherlands)

    Fernandez Robles, Laura; Azzopardi, George; Alegre, Enrique; Petkov, Nicolai

    2015-01-01

    Wear evaluation of cutting tools is a key issue for prolonging their lifetime and ensuring high quality of products. In this paper, we present a method for the effective localisation of cutting edges of inserts in digital images of an edge profile milling head. We introduce a new image data set of 1

  9. Precision Vapor Deposited Coatings for Detector and Optical Coupling Applications Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this effort the following tasks will be addressed:1) Develop reliable multilayer coatings for transition edge detectors, kinetic inductance films, and optical...

  10. Giant edge state splitting at atomically precise graphene zigzag edges.

    Science.gov (United States)

    Wang, Shiyong; Talirz, Leopold; Pignedoli, Carlo A; Feng, Xinliang; Müllen, Klaus; Fasel, Roman; Ruffieux, Pascal

    2016-05-16

    Zigzag edges of graphene nanostructures host localized electronic states that are predicted to be spin-polarized. However, these edge states are highly susceptible to edge roughness and interaction with a supporting substrate, complicating the study of their intrinsic electronic and magnetic structure. Here, we focus on atomically precise graphene nanoribbons whose two short zigzag edges host exactly one localized electron each. Using the tip of a scanning tunnelling microscope, the graphene nanoribbons are transferred from the metallic growth substrate onto insulating islands of NaCl in order to decouple their electronic structure from the metal. The absence of charge transfer and hybridization with the substrate is confirmed by scanning tunnelling spectroscopy, which reveals a pair of occupied/unoccupied edge states. Their large energy splitting of 1.9 eV is in accordance with ab initio many-body perturbation theory calculations and reflects the dominant role of electron-electron interactions in these localized states.

  11. Recent Progress on 3D Silicon Detectors

    CERN Document Server

    Lange, Jörn

    2015-01-01

    3D silicon detectors, in which the electrodes penetrate the sensor bulk perpendicular to the surface, have recently undergone a rapid development from R\\&D over industrialisation to their first installation in a real high-energy-physics experiment. Since June 2015, the ATLAS Insertable B-Layer is taking first collision data with 3D pixel detectors. At the same time, preparations are advancing to install 3D pixel detectors in forward trackers such as the ATLAS Forward Proton detector or the CMS-TOTEM Proton Precision Spectrometer. For those experiments, the main requirements are a slim edge and the ability to cope with non-uniform irradiation. Both have been shown to be fulfilled by 3D pixel detectors. For the High-Luminosity LHC pixel upgrades of the major experiments, 3D detectors are promising candidates for the innermost pixel layers to cope with harsh radiation environments up to fluences of $2\\times10^{16}$\\,n$_{eq}$/cm$^2$ thanks to their excellent radiation hardness at low operational voltages and ...

  12. Overview on Measured Properties of VTT's Edgeless Detectors and their use in High Energy Physics

    Science.gov (United States)

    Kalliopuska, Juha; Jakubek, Jan; Tlustos, Lukas

    During the past five years VTT has actively developed fabrication processes for the state-of-the-art edgeless strip and pixel detectors with a negligible dead region at the edges. The article summarizes the measured properties of VTT's edgeless detectors and gives references to the relevant journal papers. The measured properties include leakage current, breakdown voltage and capacitance dependences on the detector thickness and polarity. Earlier X-ray tube and radiation source characterization results are revised and new ones are introduced to reveal a pixel response as a function of bias voltage and pixel location in the detector's pixel matrix. Part of the article concentrates on alpha particle characterization of the detectors, especially to the pixel response properties at the edge regions of the detector. The article shows that the edgeless detectors are not losing charge collections efficiency at the edge and the spectroscopic response is comparable to the inner regions of the detector. In addition, the distortion of the electric field at the edge of the detector is almost independent on the applied reverse bias voltage.

  13. Widely tunable edge emitters

    Science.gov (United States)

    Sarlet, Gert; Wesstrom, Jan-Olof; Rigole, Pierre-Jean; Broberg, Bjoern

    2001-11-01

    We will present the current state-of-the-art in widely tunable edge emitting lasers for WDM applications. Typical applications for a tunable laser will be discussed, and the different types of tunable lasers available today will be compared with respect to the requirements posed by these applications. We will focus on the DBR-type tunable lasers - DBR, SG-DBR and GCSR - which at present seem to be the only tunable lasers mature enough for real-life applications. Their main advantages are that they are all monolithic, with no moving parts, and can be switched from one frequency to the other very rapidly since the tuning is based on carrier injection and not on thermal or mechanical changes. We will briefly discuss the working principle of each of these devices, and present typical performance characteristics. From a manufacturing point of view, rapid characterization of the lasers is crucial; therefore an overview will be given of different characterization schemes that have recently been proposed. For the end user, reliability is the prime issue. We will show results of degradation studies on these lasers and outline how the control electronics that drive the laser can compensate for any frequency drift. Finally, we will also discuss the impact of the requirement for rapid frequency switching on the design of the control electronics.

  14. LDRD final report on enhanced edge detection techniques for manufacturing quality control and materials characterization

    Energy Technology Data Exchange (ETDEWEB)

    Osbourn, G.C.

    1997-01-01

    Detecting object boundaries in the presence of cast shadows is a difficult task for machine vision systems. A new edge detector is presented which responds to shadow penumbras and abrupt object edges with distinguishable signals. The detector requires the use of spatially extended light sources and sufficient video resolution to resolve the shadow penumbras of interest. Detection of high frequency noise is suppressed without requiring image-dependent adjustment of signal thresholds. The ability of the edge operator to distinguish shadow penumbras from abrupt object boundaries while suppressing responses to high frequency noise and texture is illustrated with idealized shadow and object edge intensity profiles. Selective detection of object boundaries in a video scene with a cast shadow has also been demonstrated with this operator.

  15. Improved Edge Performance in MRF

    Science.gov (United States)

    Shorey, Aric; Jones, Andrew; Durnas, Paul; Tricard, Marc

    2004-01-01

    The fabrication of large segmented optics requires a polishing process that can correct the figure of a surface to within a short distance from its edges-typically, a few millimeters. The work here is to develop QED's Magnetorheological Finishing (MRF) precision polishing process to minimize residual edge effects.

  16. Quick-EXAFS setup at the SuperXAS beamline for in situ X-ray absorption spectroscopy with 10 ms time resolution

    Energy Technology Data Exchange (ETDEWEB)

    Müller, Oliver, E-mail: o.mueller@uni-wuppertal.de [University of Wuppertal, Gaußstraße 20, 42119 Wuppertal (Germany); Nachtegaal, Maarten [Paul Scherrer Institute, 5232 Villigen (Switzerland); Just, Justus [University of Wuppertal, Gaußstraße 20, 42119 Wuppertal (Germany); Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Lützenkirchen-Hecht, Dirk; Frahm, Ronald [University of Wuppertal, Gaußstraße 20, 42119 Wuppertal (Germany)

    2016-01-01

    A new quick-scanning EXAFS (QEXAFS) monochromator, ionization chambers and data acquisition system have been developed and installed at the SuperXAS beamline at the Swiss Light Source to reach a temporal resolution of 10 ms. The quick-EXAFS (QEXAFS) method adds time resolution to X-ray absorption spectroscopy (XAS) and allows dynamic structural changes to be followed. A completely new QEXAFS setup consisting of monochromator, detectors and data acquisition system is presented, as installed at the SuperXAS bending-magnet beamline at the Swiss Light Source (Paul Scherrer Institute, Switzerland). The monochromator uses Si(111) and Si(311) channel-cut crystals mounted on one crystal stage, and remote exchange allows an energy range from 4.0 keV to 32 keV to be covered. The spectral scan range can be electronically adjusted up to several keV to cover multiple absorption edges in one scan. The determination of the Bragg angle close to the position of the crystals allows high-accuracy measurements. Absorption spectra can be acquired with fast gridded ionization chambers at oscillation frequencies of up to 50 Hz resulting in a time resolution of 10 ms, using both scan directions of each oscillation period. The carefully developed low-noise detector system yields high-quality absorption data. The unique setup allows both state-of-the-art QEXAFS and stable step-scan operation without the need to exchange whole monochromators. The long-term stability of the Bragg angle was investigated and absorption spectra of reference materials as well as of a fast chemical reaction demonstrate the overall capabilities of the new setup.

  17. Determination of Scattering and Absorption Coefficients for Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings at Elevated Temperatures

    Science.gov (United States)

    Eldridge, Jeffrey I.; Spuckler, Charles M.; Markham, James R.

    2009-01-01

    The temperature dependence of the scattering and absorption coefficients for a set of freestanding plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) thermal barrier coatings (TBCs) was determined at temperatures up to 1360 C in a wavelength range from 1.2 micrometers up to the 8YSZ absorption edge. The scattering and absorption coefficients were determined by fitting the directional-hemispherical reflectance and transmittance values calculated by a four-flux Kubelka Munk method to the experimentally measured hemispherical-directional reflectance and transmittance values obtained for five 8YSZ thicknesses. The scattering coefficient exhibited a continuous decrease with increasing wavelength and showed no significant temperature dependence. The scattering is primarily attributed to the relatively temperature-insensitive refractive index mismatch between the 8YSZ and its internal voids. The absorption coefficient was very low (less than 1 per centimeter) at wavelengths between 2 micrometers and the absorption edge and showed a definite temperature dependence that consisted of a shift of the absorption edge to shorter wavelengths and an increase in the weak absorption below the absorption edge with increasing temperature. The shift in the absorption edge with temperature is attributed to strongly temperature-dependent multiphonon absorption. While TBC hemispherical transmittance beyond the absorption edge can be predicted by a simple exponential decrease with thickness, below the absorption edge, typical TBC thicknesses are well below the thickness range where a simple exponential decrease in hemispherical transmittance with TBC thickness is expected. [Correction added after online publication August 11, 2009: "edge to a shorter wavelengths" has been updated as edge to shorter wavelengths."

  18. The Robotic Edge Finishing Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Loucks, C.S.; Selleck, C.B.

    1990-08-01

    The Robotic Edge Finishing Laboratory at Sandia National Laboratories is developing four areas of technology required for automated deburring, chamfering, and blending of machined edges: (1) the automatic programming of robot trajectories and deburring processes using information derived from a CAD database, (2) the use of machine vision for locating the workpiece coupled with force control to ensure proper tool contact, (3) robotic deburring, blending, and machining of precision chamfered edges, and (4) in-process automated inspection of the formed edge. The Laboratory, its components, integration, and results from edge finishing experiments to date are described here. Also included is a discussion of the issues regarding implementation of the technology in a production environment. 24 refs., 17 figs.

  19. The MINOS Detectors

    CERN Document Server

    Grashorn, A H E W

    2005-01-01

    The Main Injector Neutrino Oscillation Search (MINOS) experiment's primary goal is the precision measurement of the neutrino oscillation parameters in the atmospheric neutrino sector. This long-baseline experiment uses Fermilab's NuMI beam, measured with a Near Detector at Fermilab, and again 735 km later using a Far Detector in the Soudan Mine Underground Lab in northern Minnesota. The detectors are magnetized iron/scintillator calorimeters. The Far Detector has been operational for cosmic ray and atmospheric neutrino data from July of 2003, the Near Detector from September 2004, and the NuMI beam started in early 2005. This poster presents details of the two detectors.

  20. GADRAS Detector Response Function.

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Dean J.; Harding, Lee; Thoreson, Gregory G; Horne, Steven M.

    2014-11-01

    The Gamma Detector Response and Analysis Software (GADRAS) applies a Detector Response Function (DRF) to compute the output of gamma-ray and neutron detectors when they are exposed to radiation sources. The DRF is fundamental to the ability to perform forward calculations (i.e., computation of the response of a detector to a known source), as well as the ability to analyze spectra to deduce the types and quantities of radioactive material to which the detectors are exposed. This document describes how gamma-ray spectra are computed and the significance of response function parameters that define characteristics of particular detectors.