Quantifying sediment connectivity in an actively eroding gully complex, Waipaoa catchment, New Zealand

Science.gov (United States)

Taylor, Richard J.; Massey, Chris; Fuller, Ian C.; Marden, Mike; Archibald, Garth; Ries, William

2018-04-01

Using a combination of airborne LiDAR (2005) and terrestrial laser scanning (2007, 2008, 2010, 2011), sediment delivery processes and sediment connectivity in an 20-ha gully complex, which significantly contributes to the Waipaoa sediment cascade, are quantified over a 6-year period. The acquisition of terrain data from high-resolution surveys of the whole gully-fan system provides new insights into slope processes and slope-channel linkages operating in the complex. Raw terrain data from the airborne and ground-based laser scans were converted into raster DEMs with a vertical accuracy between surveys of models of change across the gully and fan complex. In these models deposition equates to positive and erosion to negative vertical change. Debris flows, slumping, and erosion by surface runoff (gullying in the conventional sense) generated on average 95,232 m3 of sediment annually, with a standard deviation of ± 20,806 m3. The volumes of debris eroded from those areas dominated by surface erosion processes were higher than in areas dominated by landslide processes. Over the six-year study period, sediment delivery from the source zones to the fan was a factor of 1.4 times larger than the volume of debris exported from the fan into Te Weraroa Stream. The average annual volume of sediment exported to Te Weraroa Stream varies widely from 23,195 to 102,796 m3. Fluctuations in the volume of stored sediment within the fan, rather than external forcing by rainstorms or earthquakes, account for this annual variation. No large rainfall events occurred during the monitoring period; therefore, sediment volumes and transfer processes captured by this study are representative of the background conditions that operate in this geomorphic system.

Sedimentation rates in Lake Pukaki, New Zealand

International Nuclear Information System (INIS)

Ditchburn, R.G.; McCabe, W.J.

1977-10-01

The layers of Lake Pukaki sediments and their possible relationship to other cyclic events have been considered with a view to determining the rate of sediment deposition. There was no evidence to determine whether the rhytmic layers in the sediments are annual deposits or controlled by flood conditions. In the hope of resolving the question, radiometric dating techniques were applied to sediment cores in which the concentrations of radionuclides such as lead 210 and caesium 137 were measured with respect to depth and then related to some known input pattern. 210 Pb and 137 Cs were determined in all three cores investigated. 147 Pr and 144 Ce were also determined in one of the cores. The 137 Cs measurements indicated sedimentation rates of 14 kg/y/m 2 for one core and 17 kg/y/m 2 for the other two

Contrasts in Sediment Delivery and Dispersal from River Mouth to Accumulation Zones in High Sediment Load Systems: Fly River, Papua New Guinea and Waipaoa River, New Zealand

Science.gov (United States)

Ogston, A. S.; Walsh, J. P.; Hale, R. P.

2011-12-01

The relationships between sediment-transport processes, short-term sedimentary deposition, subsequent burial, and long-term accumulation are critical to understanding the morphological development of the continental margin. This study focuses on processes involved in formation and evolution of the clinoform in the Gulf of Papua, Papua New Guinea in which much of the riverine sediment accumulates, and comparison to those processes active off the Waipaoa River, New Zealand that form mid-shelf deposits and export sediment to the slope. In tidally dominated deltas, sediment discharged from the river sources must transit through an estuarine region located within the distributary channels, where particle pathways can undergo significant transformations. Within the distributaries of the Fly River tidally dominated delta, near-bed fluid-mud concentrations were observed at the estuarine turbidity maximum and sediment delivery to the nearshore was controlled by the morphology and gradient of the distributary. El Niño results in anonymously low flow and sediment discharge conditions, which limits transport of sediment from the distributaries to the nearshore zone of temporary storage. Because the sediment stored nearshore feeds the prograding clinoform, this perturbation propagates throughout the dispersal system. In wave-dominated regions, transport mechanisms actively move sediment away from the river source, separating the site of deposition and accumulation from the river mouth. River-flood and storm-wave events each create discrete deposits on the Waipaoa River shelf and data has been collected to determine their form, distribution, and relationship to factors such as flood magnitude or wave energy. In this case, transport pathways appear to be influenced by structurally controlled shelf bathymetry. In both cases, the combined fluvial and marine processes can initiate and maintain gravity-driven density flows, and although their triggers and controls differ vastly

A Hydrodynamic and Sediment Transport Model for the Waipaoa Shelf, New Zealand: Sensitivity of Fluxes to Spatially-Varying Erodibility and Model Nesting

Directory of Open Access Journals (Sweden)

Julia M. Moriarty

2014-04-01

Full Text Available Numerical models can complement observations in investigations of marine sediment transport and depositional processes. A coupled hydrodynamic and sediment transport model was implemented for the Waipaoa River continental shelf offshore of the North Island of New Zealand, to complement a 13-month field campaign that collected seabed and hydrodynamic measurements. This paper described the formulations used within the model, and analyzed the sensitivity of sediment flux estimates to model nesting and seabed erodibility. Calculations were based on the Regional Ocean Modeling System—Community Sediment Transport Modeling System (ROMS-CSTMS, a primitive equation model using a finite difference solution to the equations for momentum and water mass conservation, and transport of salinity, temperature, and multiple classes of suspended sediment. The three-dimensional model resolved the complex bathymetry, bottom boundary layer, and river plume that impact sediment dispersal on this shelf, and accounted for processes including fluvial input, winds, waves, tides, and sediment resuspension. Nesting within a larger-scale, lower resolution hydrodynamic model stabilized model behavior during river floods and allowed large-scale shelf currents to impact sediment dispersal. To better represent observations showing that sediment erodibility decreased away from the river mouth, the seabed erosion rate parameter was reduced with water depth. This allowed the model to account for the observed spatial pattern of erodibility, though the model held the critical shear stress for erosion constant. Although the model neglected consolidation and swelling processes, use of a spatially-varying erodibility parameter significantly increased export of fluvial sediment from Poverty Bay to deeper areas of the shelf.

Surface sediment quality relative to port activities: A contaminant-spectrum assessment.

Science.gov (United States)

Yu, Shen; Hong, Bing; Ma, Jun; Chen, Yongshan; Xi, Xiuping; Gao, Jingbo; Hu, Xiuqin; Xu, Xiangrong; Sun, Yuxin

2017-10-15

Ports are facing increasing environmental concerns with their importance to the global economy. Numerous studies indicated sediment quality deterioration in ports; however, the deterioration is not discriminated for each port activity. This study investigated a spectrum of contaminants (metals and organic pollutants) in surface sediments at 20 sampling points in Port Ningbo, China, one of the top five world ports by volume. The spectrum of contaminants (metals and organic pollutants) was quantified following marine sediment quality guidelines of China and USA and surface sediment quality was assessed according to thresholds of the two guidelines. Coupling a categorical matrix of port activities with the matrix of sedimentary contaminants revealed that contaminants were highly associated with the port operations. Ship repair posed a severe chemical risk to sediment. Operations of crude oil and coal loadings were two top activities related to organic pollutants in sediments while port operations of ore and container loadings discharged metals. Among the 20 sampling points, Cu, Zn, Pb, and DDT and its metabolites were the priority contaminants influencing sediment quality. Overall, surface sediments in Port Ningbo had relatively low environmental risks but ship repair is an environmental concern that must be addressed. This study provides a practical approach for port activity-related quality assessment of surface sediments in ports that could be applicable in many world sites. Copyright © 2017 Elsevier B.V. All rights reserved.

Sediment studies at Bikini Atoll part 1. distribution of fine and coarse components in surface sediments

International Nuclear Information System (INIS)

Noshkin, V. E.; Eagle, R.J.; Robison, W.L.

1997-01-01

In 1979, 21 years after the moratorium on nuclear testing in the Marshall Islands, surface sediment samples (to depths of 2 and 4 cm) were collected from 87 locations over the floor of Bikini lagoon. The main purpose for the collections was to map the distribution of long- lived man-made radionuclides associated with the bottom material. In addition the samples were processed to estimate the fraction of fine and coarse components to show what modifications occurred since the sediment composition was first described in samples collected before testing in 1946. In this report a comparison is made of the amount and distribution of fine material associated with the lagoon surface sediment before and after the testing of nuclear devices. Nuclear testing produced more finely divided material in-the surface sediment layer over large areas of the lagoon and especially in regions of the lagoon and reef adjacent to test sites. Five cratering events at Bikini Atoll generated sufficient material to account for the inventory of new fine material found over the bottom surface of the lagoon. Although the fraction of fine material in the bottom sediments was altered by the nuclear events, the combined processes of formation, transport and deposition were not sufficiently dynamic to alter the geographical features of the major sedimentary components over most of the lagoon floor

Sediment studies at Bikini Atoll part 1. distribution of fine and coarse components in surface sediments

Energy Technology Data Exchange (ETDEWEB)

Noshkin, V. E.; Eagle, R.J.; Robison, W.L.

1997-01-01

In 1979, 21 years after the moratorium on nuclear testing in the Marshall Islands, surface sediment samples (to depths of 2 and 4 cm) were collected from 87 locations over the floor of Bikini lagoon. The main purpose for the collections was to map the distribution of long- lived man-made radionuclides associated with the bottom material. In addition the samples were processed to estimate the fraction of fine and coarse components to show what modifications occurred since the sediment composition was first described in samples collected before testing in 1946. In this report a comparison is made of the amount and distribution of fine material associated with the lagoon surface sediment before and after the testing of nuclear devices. Nuclear testing produced more finely divided material in-the surface sediment layer over large areas of the lagoon and especially in regions of the lagoon and reef adjacent to test sites. Five cratering events at Bikini Atoll generated sufficient material to account for the inventory of new fine material found over the bottom surface of the lagoon. Although the fraction of fine material in the bottom sediments was altered by the nuclear events, the combined processes of formation, transport and deposition were not sufficiently dynamic to alter the geographical features of the major sedimentary components over most of the lagoon floor.

Urbanization increased metal levels in lake surface sediment and catchment topsoil of waterscape parks

Energy Technology Data Exchange (ETDEWEB)

Li, Hong-Bo [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Graduate University of Chinese Academy of Sciences, Beijing 100049 (China); Yu, Shen, E-mail: syu@iue.ac.cn [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Li, Gui-Lin [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Liu, Yi; Yu, Guang-Bin [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Graduate University of Chinese Academy of Sciences, Beijing 100049 (China); Deng, Hong [Department of Environmental Sciences, Tiantong National Station of Forest Ecosystem, Key Laboratory of Urbanization and Ecological Restoration, East China Normal University, Shanghai 200062 (China); Wu, Sheng-Chun [State Key Laboratory in Marine Pollution, Biology and Chemistry Department, City University of Hong Kong, Hong Kong (China); Wong, Ming-Hung [Croucher Institute for Environmental Sciences, Hong Kong Baptist University, Hong Kong (China)

2012-08-15

Lake surface sediment is mainly derived from topsoil in its catchment. We hypothesized that distribution of anthropogenic metals would be homogenous in lake surface sediment and the lake's catchment topsoil. Anthropogenic metal distributions (cadmium (Cd), copper (Cu), lead (Pb), and zinc (Zn)) in fourteen waterscape parks were investigated in surface sediments and catchment topsoils and possible source homogeneity was tested using stable Pb isotopic ratio analysis. The parks were located along an urbanization gradient consisting of suburban (SU), developing urban (DIU), developed urban (DDU), and central urban core (CUC) areas in Shanghai, China. Results indicated that surface lake sediments and catchment topsoils in the CUC parks were highly contaminated by the investigated anthropogenic metals. Total metal contents in surface sediment and topsoil gradually increased along the urbanization gradient from the SU to CUC areas. Generally, the surface sediments had greater total metal contents than their catchment topsoils. These results suggest that urbanization drives the anthropogenic metal enrichment in both surface sediment and its catchment topsoil in the waterscape parks. Soil fine particles (< 63 {mu}m) and surface sediments had similar enrichment ratios of metals, suggesting that surface runoff might act as a carrier for metals transporting from catchment to lake. Stable Pb isotope ratio analysis revealed that the major anthropogenic Pb source in surface sediment was coal combustion as in the catchment topsoil. Urbanization also correlated with chemical fractionation of metals in both surface sediment and catchment topsoil. From the SU to the CUC parks, amounts of labile metal fractions increased while the residual fraction of those metals remained rather constant. In short, urbanization in Shanghai drives anthropogenic metal distribution in environmental matrices and the sources were homogenous. -- Highlights: Black-Right-Pointing-Pointer Obvious

Urbanization increased metal levels in lake surface sediment and catchment topsoil of waterscape parks

International Nuclear Information System (INIS)

Li, Hong-Bo; Yu, Shen; Li, Gui-Lin; Liu, Yi; Yu, Guang-Bin; Deng, Hong; Wu, Sheng-Chun; Wong, Ming-Hung

2012-01-01

Lake surface sediment is mainly derived from topsoil in its catchment. We hypothesized that distribution of anthropogenic metals would be homogenous in lake surface sediment and the lake's catchment topsoil. Anthropogenic metal distributions (cadmium (Cd), copper (Cu), lead (Pb), and zinc (Zn)) in fourteen waterscape parks were investigated in surface sediments and catchment topsoils and possible source homogeneity was tested using stable Pb isotopic ratio analysis. The parks were located along an urbanization gradient consisting of suburban (SU), developing urban (DIU), developed urban (DDU), and central urban core (CUC) areas in Shanghai, China. Results indicated that surface lake sediments and catchment topsoils in the CUC parks were highly contaminated by the investigated anthropogenic metals. Total metal contents in surface sediment and topsoil gradually increased along the urbanization gradient from the SU to CUC areas. Generally, the surface sediments had greater total metal contents than their catchment topsoils. These results suggest that urbanization drives the anthropogenic metal enrichment in both surface sediment and its catchment topsoil in the waterscape parks. Soil fine particles (< 63 μm) and surface sediments had similar enrichment ratios of metals, suggesting that surface runoff might act as a carrier for metals transporting from catchment to lake. Stable Pb isotope ratio analysis revealed that the major anthropogenic Pb source in surface sediment was coal combustion as in the catchment topsoil. Urbanization also correlated with chemical fractionation of metals in both surface sediment and catchment topsoil. From the SU to the CUC parks, amounts of labile metal fractions increased while the residual fraction of those metals remained rather constant. In short, urbanization in Shanghai drives anthropogenic metal distribution in environmental matrices and the sources were homogenous. -- Highlights: ► Obvious urbanization effect on metal

Eruptive and environmental processes recorded by diatoms in volcanically-dispersed lake sediments from the Taupo Volcanic Zone, New Zealand

Science.gov (United States)

Harper, Margaret A.; Pledger, Shirley A.; Smith, Euan G. C.; Van Eaton, Alexa; Wilson, Colin J. N.

2015-01-01

Late Pleistocene diatomaceous sediment was widely dispersed along with volcanic ash (tephra) across and beyond New Zealand by the 25.4 ka Oruanui supereruption from Taupo volcano. We present a detailed analysis of the diatom populations in the Oruanui tephra and the newly discovered floras in two other eruptions from the same volcano: the 28.6 ka Okaia and 1.8 ka Taupo eruptions. For comparison, the diatoms were also examined in Late Pleistocene and Holocene lake sediments from the Taupo Volcanic Zone (TVZ). Our study demonstrates how these microfossils provide insights into the lake history of the TVZ since the Last Glacial Maximum. Morphometric analysis of Aulacoseira valve dimensions provides a useful quantitative tool to distinguish environmental and eruptive processes within and between individual tephras. The Oruanui and Okaia diatom species and valve dimensions are highly consistent with a shared volcanic source, paleolake and eruption style (involving large-scale magma-water interaction). They are distinct from lacustrine sediments sourced elsewhere in the TVZ. Correspondence analysis shows that small, intact samples of erupted lake sediment (i.e., lithic clasts in ignimbrite) contain heterogeneous diatom populations, reflecting local variability in species composition of the paleolake and its shallowly-buried sediments. Our analysis also shows a dramatic post-Oruanui supereruption decline in Cyclostephanos novaezelandiae, which likely reflects a combination of (1) reorganisation of the watershed in the aftermath of the eruption, and (2) overall climate warming following the Last Glacial Maximum. This decline is reflected in substantially lower proportions of C. novaezelandiae in the 1.8 ka Taupo eruption deposits, and even fewer in post-1.8 ka sediments from modern (Holocene) Lake Taupo. Our analysis highlights how the excellent preservation of siliceous microfossils in volcanic tephra may fingerprint the volcanic source region and retain a valuable record

Measuring the role of seagrasses in regulating sediment surface elevation

KAUST Repository

Potouroglou, Maria

2017-09-13

Seagrass meadows provide numerous ecosystem services and their rapid global loss may reduce human welfare as well as ecological integrity. In common with the other \\'blue carbon\\' habitats (mangroves and tidal marshes) seagrasses are thought to provide coastal defence and encourage sediment stabilisation and surface elevation. A sophisticated understanding of sediment elevation dynamics in mangroves and tidal marshes has been gained by monitoring a wide range of different sites, located in varying hydrogeomorphological conditions over long periods. In contrast, similar evidence for seagrasses is sparse; the present study is a contribution towards filling this gap. Surface elevation change pins were deployed in four locations, Scotland, Kenya, Tanzania and Saudi Arabia, in both seagrass and unvegetated control plots in the low intertidal and shallow subtidal zone. The presence of seagrass had a highly significant, positive impact on surface elevation at all sites. Combined data from the current work and the literature show an average difference of 31 mm per year in elevation rates between vegetated and unvegetated areas, which emphasizes the important contribution of seagrass in facilitating sediment surface elevation and reducing erosion. This paper presents the first multi-site study for sediment surface elevation in seagrasses in different settings and species.

Measuring the role of seagrasses in regulating sediment surface elevation

Science.gov (United States)

Potouroglou, Maria; Bull, James C.; Krauss, Ken W.; Kennedy, Hilary A.; Fusi, Marco; Daffonchio, Daniele; Mangora, Mwita M.; Githaiga, Michael N.; Diele, Karen; Huxham, Mark

2017-01-01

Seagrass meadows provide numerous ecosystem services and their rapid global loss may reduce human welfare as well as ecological integrity. In common with the other ‘blue carbon’ habitats (mangroves and tidal marshes) seagrasses are thought to provide coastal defence and encourage sediment stabilisation and surface elevation. A sophisticated understanding of sediment elevation dynamics in mangroves and tidal marshes has been gained by monitoring a wide range of different sites, located in varying hydrogeomorphological conditions over long periods. In contrast, similar evidence for seagrasses is sparse; the present study is a contribution towards filling this gap. Surface elevation change pins were deployed in four locations, Scotland, Kenya, Tanzania and Saudi Arabia, in both seagrass and unvegetated control plots in the low intertidal and shallow subtidal zone. The presence of seagrass had a highly significant, positive impact on surface elevation at all sites. Combined data from the current work and the literature show an average difference of 31 mm per year in elevation rates between vegetated and unvegetated areas, which emphasizes the important contribution of seagrass in facilitating sediment surface elevation and reducing erosion. This paper presents the first multi-site study for sediment surface elevation in seagrasses in different settings and species.

Shallow methane hydrate system controls ongoing, downslope sediment transport in a low-velocity active submarine landslide complex, Hikurangi Margin, New Zealand

Science.gov (United States)

Mountjoy, Joshu J.; Pecher, Ingo; Henrys, Stuart; Crutchley, Gareth; Barnes, Philip M.; Plaza-Faverola, Andreia

2014-11-01

Morphological and seismic data from a submarine landslide complex east of New Zealand indicate flow-like deformation within gas hydrate-bearing sediment. This "creeping" deformation occurs immediately downslope of where the base of gas hydrate stability reaches the seafloor, suggesting involvement of gas hydrates. We present evidence that, contrary to conventional views, gas hydrates can directly destabilize the seafloor. Three mechanisms could explain how the shallow gas hydrate system could control these landslides. (1) Gas hydrate dissociation could result in excess pore pressure within the upper reaches of the landslide. (2) Overpressure below low-permeability gas hydrate-bearing sediments could cause hydrofracturing in the gas hydrate zone valving excess pore pressure into the landslide body. (3) Gas hydrate-bearing sediment could exhibit time-dependent plastic deformation enabling glacial-style deformation. We favor the final hypothesis that the landslides are actually creeping seafloor glaciers. The viability of rheologically controlled deformation of a hydrate sediment mix is supported by recent laboratory observations of time-dependent deformation behavior of gas hydrate-bearing sands. The controlling hydrate is likely to be strongly dependent on formation controls and intersediment hydrate morphology. Our results constitute a paradigm shift for evaluating the effect of gas hydrates on seafloor strength which, given the widespread occurrence of gas hydrates in the submarine environment, may require a reevaluation of slope stability following future climate-forced variation in bottom-water temperature.

Fine and coarse components in surface sediments from Bikini Lagoon

Energy Technology Data Exchange (ETDEWEB)

Noshkin, V. E., LLNL

1997-01-01

In 1979, 21 years after the moratorium on nuclear testing in the Marshall Islands, surface sediment samples (to depths of 2 and 4 cm) were collected from 87 locations in the lagoon of Bikini Atoll, one of the two sites in the Marshall Islands used by the United States to test nuclear devices from 1946 through 1958. The main purpose for the collections was to map the distribution of long-lived man-made radionuclides associated with the bottom material. In addition the samples were processed to estimate the fraction of fine and coarse components to show, by comparison, what modifications occurred in the composition since the sediments were first described in samples collected before testing in 1946. Nuclear testing produced more finely divided material that is now found in the surface sediment layer over large areas of the lagoon and especially in regions of the lagoon and reef adjacent to test sites. The 5 cratering events alone at Bikini Atoll redistributed sufficient material to account for the higher inventory of fine material found over the surface 4 cm of the sediment of the lagoon. Although the fraction of fine material in the bottom sediments was altered by the nuclear events, the combined processes of formation, transport and deposition were not sufficiently dynamic to greatly change the general geographical features of the major sedimentary components over most of the lagoon floor.

Sediment studies at Bikini Atoll part 3. Inventories of some long-lived gamma-emitting radionuclides associated with lagoon surface sediments

Energy Technology Data Exchange (ETDEWEB)

Noshkin, V.E.

1997-12-01

Surface sediment samples were collected during 1979 from 87 locations in the lagoon at Bikini Atoll. The collections were made to better define the concentrations and distribution of long-lived radionuclides associated with the bottom material and to show what modifications occurred to the composition of the surface sediment from the nuclear testing program conducted by the United States at the Atoll between 1946 and 1958. This is the last of three reports on Bikini sediment studies. In this report, we discuss the concentrations and inventories of the residual long-lived gamma-emitting radionuclides in sediments from the lagoon. The gamma-emitting radionuclides detected most frequently in sediments collected in 1979, in addition to Americium-241 ({sup 241}Am) (discussed in the second report of this series), included Cesium-137 ({sup 137}Cs), Bismuth-207 ({sup 207}Bi), Europium-155 ({sup 155}Eu), and Cobalt-60 ({sup 60}Co). Other man-made, gamma-emitting radionuclides such as Europium-152,154 ({sup 152,154}Eu), Antimony-125 ({sup 125}Sb), and Rhodium-101,102m ({sup 101,102m}Rh) were occasionally measured above detection limits in sediments near test site locations. The mean inventories for {sup 137}Cs, {sup 207}Ei, {sup 155}Eu, and {sup 60}Co in the surface 4 cm of the lagoon sediment to be 1.7, 0.56, 7.76, and 0.74 TBq, respectively. By June 1997, radioactive decay would reduce these values to 1.1, 0.38, 0.62, and 0.07 TBq, respectively. Some additional loss results from a combination of different processes that continuously mobilize and return some amount of the radionuclides to the water column. The water and dissolved constituents are removed from the lagoon through channels and exchange with the surface waters of the north equatorial Pacific Ocean. Highest levels of these radionuclides are found in surface deposits lagoonward of the Bravo Crater. Lowest concentrations and inventories are associated with sediment lagoonward of the eastern reef. The quantities in

Seasonal variation of monomethylmercury concentrations in surface sediments of the Tagus Estuary (Portugal)

International Nuclear Information System (INIS)

Canario, Joao; Branco, Vasco; Vale, Carlos

2007-01-01

Surface sediments (0-2 cm) were collected at 40 sites along the Tagus Estuary in July and December 2004. The sediments were analysed for total mercury, monomethylmercury (MMHg) and interpretative parameters (e.g. redox potential, pH, C org ). No significant differences in total Hg, pH, Al, Fe, Mn and C org were found between sediments collected in the two periods, but MMHg concentrations were higher in July. On average sediments were warmer and more reducing in summer. On the basis of these results, an increase of 7 kg of MMHg (+37%) in surface sediments of the Tagus Estuary was estimated. Presumably higher temperatures in summer promote the increase of microbial activity and higher methylation rates. The alterations observed in this study point to the potential importance of seasonal changes in MMHg production at surface sediments with eventual changes in the MMHg uptake by benthic invertebrates and other organisms in the food web. - Seasonal changes in monomethylmercury production in sediments may increase its uptake by benthic invertebrates and other organisms in the food web

Effect of high sedimentation rates on surface sediment dynamics and mangrove growth in the Porong River, Indonesia.

Science.gov (United States)

Sidik, Frida; Neil, David; Lovelock, Catherine E

2016-06-15

Large quantities of mud from the LUSI (Lumpur Sidoarjo) volcano in northeastern Java have been channeled to the sea causing high rates of sediment delivery to the mouth of the Porong River, which has a cover of natural and planted mangroves. This study investigated how the high rates of sediment delivery affected vertical accretion, surface elevation change and the growth of Avicennia sp., the dominant mangrove species in the region. During our observations in 2010-2011 (4-5years after the initial volcanic eruption), very high rates of sedimentation in the forests at the mouth of the river gave rise to high vertical accretion of over 10cmy(-1). The high sedimentation rates not only resulted in reduced growth of Avicennia sp. mangrove trees at the two study sites at the Porong River mouth, but also gave rise to high soil surface elevation gains. Copyright © 2016 Elsevier Ltd. All rights reserved.

Extractable organics in surface sediments from Thana creek and Bombay harbour

Digital Repository Service at National Institute of Oceanography (India)

Rokade, M.A.; Bhosle, N.B.; Kadam, A.N.

Considerable variations in hydrocarbon and fatty acid levels in surface sediments from Thana creek and Bombay harbour were observed Sediments from the westernside nearshore locations yielded higher values The residues were characterised by infrared...

Effects of engineered nano-titanium dioxide on pore surface properties and phosphorus adsorption of sediment: Its environmental implications

International Nuclear Information System (INIS)

Luo, Zhuanxi; Wang, Zhenhong; Wei, QunShan; Yan, Changzhou; Liu, Feng

2011-01-01

Highlights: → The attachment of Enano-TiO 2 to surface enhanced markedly sediment BET surface area and t-Plot external surface area. → The fill of Enano-TiO 2 into the micropores reduced significantly the sediment t-Plot micropore surface area. → Enano-TiO 2 could increase sediment phosphorus (P) adsorption maximum and decrease in sediment P binding energy. → P would be easily released because of the decreasing P binding energy of the sediment with elevated Enano-TiO 2 . - Abstract: Understanding the environmental safety and human health implications of engineered nanoparticles (ENPs) is of worldwide importance. As an important ENPs, engineered nano-TiO 2 (Enano-TiO 2 ) may have been substantially deposited in aquatic sediments because of its widely uses. Sediment pore surface properties would be thus significantly influenced due to the large surface area of Enano-TiO 2 . In this study, Enano-TiO 2 was found to greatly impact on sediment pore surface properties. The attachment of Enano-TiO 2 particles to sediment surfaces enhanced markedly BET specific surface area and t-Plot external specific surface area, and thereby increased sediment phosphorus (P) adsorption maximum (S max ). Contrarily, the fill of Enano-TiO 2 particles into the micropores of sediments could significantly reduce t-Plot micropore specific surface area, and cause slight decrease in sediment P binding energy (K). Clearly, P sorbed in sediment would be easily released because of the decreasing P binding energy of the sediment with elevated Enano-TiO 2 . Enano-TiO 2 would thus cause aggravated endogenous pollution in water if such sediment was re-suspended on disturbance. The results obtained in this study contribute to our increasing knowledge of how to regulate physicochemical behavior of pollutants in sediments under the influences of Enano-TiO 2 and/or similar ENPs.

Development of a New Zealand SedNet model for assessment of catchment-wide soil-conservation works

Science.gov (United States)

Dymond, John R.; Herzig, Alexander; Basher, Les; Betts, Harley D.; Marden, Mike; Phillips, Chris J.; Ausseil, Anne-Gaelle E.; Palmer, David J.; Clark, Maree; Roygard, Jon

2016-03-01

Much hill country in New Zealand has been converted from indigenous forest to pastoral agriculture, resulting in increased soil erosion. Following a severe storm that hit the Manawatu-Wanaganui region in 2004 and caused 62,000 landslides, the Horizons Regional Council have implemented the Sustainable Land Use Initiative (SLUI), a programme of widespread soil conservation. We have developed a New Zealand version (SedNetNZ) of the Australian SedNet model to evaluate the impact of the SLUI programme in the 5850 km2 Manawatu catchment. SedNetNZ spatially distributes budgets of fine sediment in the landscape. It incorporates landslide, gully, earthflow erosion, surficial erosion, bank erosion, and flood-plain deposition, the important forms of soil erosion in New Zealand. Modelled suspended sediment loads compared well with measured suspended sediment loads with an R2 value of 0.85 after log transformation. A sensitivity analysis gave the uncertainty of estimated suspended sediment loads to be approximately plus or minus 50% (at the 95% confidence level). It is expected that by 2040, suspended sediment loads in targeted water management zones will decrease by about 40%. The expected decrease for the whole catchment is 34%. The expected reduction is due to maturity of tree planting on land at risk to soil erosion. The 34% reduction represents an annual rate of return of 20% on 20 million NZ of investment on soil conservation works through avoided damage to property and infrastructure and avoided clean-up costs.

Distribution of 137Cs in surface seawater and sediment around Sabahs Sulu-Sulawesi Sea

International Nuclear Information System (INIS)

Mohd Izwan Abdul Aziz; Ahmad Sanadi Abu Bakar; Yii, Mei Wo; Nurrul Assyikeen Jaffary; Zaharudin Ahmad

2010-01-01

The studies on distribution of 137 Cs in surface seawater and sediment around Sabahs Sulu-Sulawesi Sea were carried out during Ekspedisi Pelayaran Saintifik Perdana (EPSP) in July 2009. About sixteen and twenty five sampling locations were identified for surface seawater and sediment respectively in Sabahs Sulu-Sulawesi Sea. Large volumes of seawater samples are collected and co-precipitation technique was employed to concentrate cesium content before known amounts of 134 Cs tracer were added as yield determinant. Grab sampler were used to collect surface sediment sample. The caesium precipitate and sediment were dried and finely ground before counted using gamma-ray spectrometry system at 661 keV. The activity of 137 Cs was found in surface seawater and sediment to be in the range 1.73 Bq/ m 3 to 5.50 Bq/ m 3 and 1.15 Bq/ kg to 4.53 Bq/ kg respectively. (author)

Sediment size of surface floodplain sediments along a large lowland river

Science.gov (United States)

Swanson, K. M.; Day, G.; Dietrich, W. E.

2007-12-01

Data on size distribution of surface sediment across a floodplain should place important constraints of modeling of floodplain deposition. Diffusive or advective models would predict that, generally, grain size should decrease away from channel banks. Variations in grain size downstream along floodplains may depend on downstream fining of river bed material, exchange rate with river banks and net deposition onto the floodplain. Here we report detailed grain size analyses taken from 17 floodplain transects along 450 km (along channel distance) reach of the middle Fly River, Papua New Guinea. Field studies have documented a systematic change in floodplain characteristics downstream from forested, more topographically elevated and topography bounded by an actively shifting mainstem channel to a downstream swamp grass, low elevation topography along which the river meanders are currently stagnant. Frequency and duration of flooding increase downstream. Flooding occurs both by overbank flows and by injections of floodwaters up tributary and tie channels connected to the mainstem. Previous studies show that about 40% of the total discharge of water passes across the floodplain, and, correspondingly, about 40% of the total load is deposited on the plain - decreasing exponentially from channel bank. We find that floodplain sediment is most sandy at the channel bank. Grain size rapidly declines away from the bank, but surprisingly two trends were also observed. A relatively short distance from the bank the surface material is finest, but with further distance from the bank (out to greater than 1 km from the 250 m wide channel) clay content decreases and silt content increases. The changes are small but repeated at most of the transects. The second trend is that bank material fines downstream, corresponding to a downstream finding bed material, but once away from the bank, there is a weak tendency for a given distance away from the bank the floodplain surface deposits to

Natural radioactivity assessment of surface sediments in the Yangtze Estuary

International Nuclear Information System (INIS)

Wang, Jinlong; Du, Jinzhou; Bi, Qianqian

2017-01-01

The activities of the natural radionuclides ( 238 U, 232 Th, 226 Ra and 40 K) of the surface sediments in the Yangtze Estuary were determined and used to evaluate radiation hazards in the study area. The of activities of 238 U, 232 Th, 226 Ra and 40 K ranges from 14.1 to 62.3, 26.1 to 71.9, 13.7 to 52.3, and 392 to 898 Bq kg −1 , respectively, which were comparable to values of other regions in China. The activities of 232 Th, 40 K and 226 Ra were clearly different from the global recommended values. The radium equivalent activity was less than the recommended limit of 370 Bq kg −1 ; therefore, the sediment in this area can be safely used for reclamation. The external hazard index values were less than one. The average absorbed gamma dose rate and annual effective dose equivalent values were slightly greater than the world average value. 226 Ra/ 238 U and 232 Th/ 238 U ratios could potentially be applied for tracing sediment source. - Highlights: • The natural radioactivity of surface sediments in the Yangtze Estuary was observed. • The radiological hazards of the sediments are insignificant in this study area. • The ratios of natural radionuclides can potentially be applied for sediment source.

Heavy metal contamination in surface runoff sediments of the urban area of Vilnius, Lithuania

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Gytautas Ignatavičius

2017-02-01

Full Text Available Surface runoff from urbanized territories carries a wide range of pollutants. Sediments in untreated runoff from direct discharge stormwater systems significantly contribute to urban waterway pollution. In this study, heavy metal (Pb, Zn, Cu, Cr, Ba, As and Fe contamination in surface runoff sediments of the urban area of the city of Vilnius was investigated. The surface runoff sediment samples were collected from seven dischargers with the highest volume rate of water flow and concentrations of suspended solids. The geospatial analysis of the distribution of heavy metals shows that there are several active pollution sources supplying the dischargers with contaminated sediments. Most of these areas are located in the central part of the city and in old town with intense traffic. Principal components analysis and t-test results clearly depicted the significantly different chemical compositions of winter and autumn surface sediment samples. The sampling approach and assessment of results provide a useful tool to examine the contamination that is generated in urban areas, distinguish pollution sources and give a better understanding of the importance of permeable surfaces and green areas.

Analysis of sediments and plant remains from the find-spot of a cache of Polynesian gardening tools at Ruakaka, northern New Zealand

International Nuclear Information System (INIS)

Horrocks, M.; Best, S.B.; Byrami, M.

2001-01-01

We outline a record of sedimentology and fossil plant remains of a prehistoric archaeological site in a small valley at Ruakaka, northern New Zealand. The evidence provides a ca. 850-year record of the sedimentation, hydrology and vegetation of the catchment, allowing the following deductions to be made: 1) the dramatically increased erosion rate of local hill slopes was a result of Polynesian deforestation by fire commencing at an estimated date of 700-550 14 C yr BP, and 2) the subsequent stabilisation of these hill slope soils occurred as a result of establishment of European pasture in the catchment after ca. AD 1800. (author). 41 refs., 11 figs., 3 tabs

Fallout Radionuclides as Tracers in Southern Alps Sediment Studies

Science.gov (United States)

Carey, A. E.; Karanovic, Z.; Dibb, J. E.

2005-12-01

The primary geologic processes shaping the landscape are physical and chemical weathering and the transport of solids by erosion. As part of our studies on the coupling between physical erosion and chemical weathering, we have determined depositional and erosional processes in New Zealand's tectonically active, rapidly uplifting Southern Alps, specifically focusing on the Hokitika River watershed. The South Island watersheds we are studying are subject to extreme orographic precipitation (as high as 7-12 m annually) and high landslide frequency, but have modest topography due to the rapid erosion. In concert with our studies of chemical weathering and physical erosion, we have used the atmospherically-delivered radionuclides of 7Be, 137Cs and 210Pbexcess to determine the relative magnitude of particle residence time in the high elevation Cropp and Whitcombe subwatersheds and the rates of sedimentation. One- and two-box modeling with 7Be and 210Pbexcess was used to determine soil and sediment residence times. Residence time of fine suspended particles is short and particles can travel the length of the river during a single storm, probably due to the short duration, high-intensity rainfalls which produce rapidly moving, steep flood waves. The readily detected peak of 137Cs activity in Cropp terrace and Hokitika gorge soils yielded sedimentation rates of 0.06-0.12 cm yr-1. At the Cropp terrace, inventory models of 210Pbexcess yield soil accumulation rates significantly less than those determined using the 137Cs activity peak. We attribute the differences to overestimation of 210Pbexcess in surface soils and to contrasting fallout fluxes, geochemical behavior and radionuclide contents of sedimenting materials. Total inventories of 210Pbexcess in soils greatly exceed the expected direct atmospheric deposition, suggesting that lateral transport of this nuclide occurs within the watershed. At the Hokitika gorge, all nuclides studied yielded similar sedimentation rates

Effects of engineered nano-titanium dioxide on pore surface properties and phosphorus adsorption of sediment: Its environmental implications

Energy Technology Data Exchange (ETDEWEB)

Luo, Zhuanxi [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Wang, Zhenhong [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Zhangzhou Normal University, Department of Chemistry and Environment Sciences, Zhangzhou 363000 (China); Wei, QunShan [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Yan, Changzhou, E-mail: czyan@iue.ac.cn [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Liu, Feng [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China)

2011-09-15

Highlights: {yields} The attachment of Enano-TiO{sub 2} to surface enhanced markedly sediment BET surface area and t-Plot external surface area. {yields} The fill of Enano-TiO{sub 2} into the micropores reduced significantly the sediment t-Plot micropore surface area. {yields} Enano-TiO{sub 2} could increase sediment phosphorus (P) adsorption maximum and decrease in sediment P binding energy. {yields} P would be easily released because of the decreasing P binding energy of the sediment with elevated Enano-TiO{sub 2}. - Abstract: Understanding the environmental safety and human health implications of engineered nanoparticles (ENPs) is of worldwide importance. As an important ENPs, engineered nano-TiO{sub 2} (Enano-TiO{sub 2}) may have been substantially deposited in aquatic sediments because of its widely uses. Sediment pore surface properties would be thus significantly influenced due to the large surface area of Enano-TiO{sub 2}. In this study, Enano-TiO{sub 2} was found to greatly impact on sediment pore surface properties. The attachment of Enano-TiO{sub 2} particles to sediment surfaces enhanced markedly BET specific surface area and t-Plot external specific surface area, and thereby increased sediment phosphorus (P) adsorption maximum (S{sub max}). Contrarily, the fill of Enano-TiO{sub 2} particles into the micropores of sediments could significantly reduce t-Plot micropore specific surface area, and cause slight decrease in sediment P binding energy (K). Clearly, P sorbed in sediment would be easily released because of the decreasing P binding energy of the sediment with elevated Enano-TiO{sub 2}. Enano-TiO{sub 2} would thus cause aggravated endogenous pollution in water if such sediment was re-suspended on disturbance. The results obtained in this study contribute to our increasing knowledge of how to regulate physicochemical behavior of pollutants in sediments under the influences of Enano-TiO{sub 2} and/or similar ENPs.

MICROBIAL DIVERSITY IN SURFACE SEDIMENTS: A COMPARISON OF TWO ESTUARINE CONTINUUMS

Science.gov (United States)

The microbial diversity in estuarine sediments of the Altamaha and Savannah Rivers in Georgia were compared temporally and spatially using phospholipid fatty acid (PLFA) analysis. Surface sediment samples collected along a salinity gradient were also analyzed for ATP, TOC, and C ...

Land to ocean transfer of erosion-related organic carbon, Waipaoa sedimentary system, East Coast, New Zealand

International Nuclear Information System (INIS)

Brackley, H.L.

2006-01-01

Mountainous islands of the Pacific Rim (such as New Zealand) purportedly deliver up to 40% of the suspended sediment load and up to 35% of the riverine particulate organic carbon (POC) load to the world's oceans. On the east coast of New Zealand's North Island, the Waipaoa River drains a steep, 2205 km 2 catchment located on the active collisional East Coast Continental Margin. It has an annual suspended sediment load of 15 Tg (15 x 10 1 2 g), making up ∼ 7% of New Zealand's total yield to the Pacific Ocean, and a mean annual POC discharge to the Pacific Ocean of 86.7 Gg (86.7 x 10 9 g). The annual loss of OC to the floodplain is ∼ 9% of this annual POC discharge (∼ 7.8 Gg). A range of analyses (including organic carbon content (%OC), stable carbon isotopes (δ 1 3C), radiocarbon ( 1 4C), carbon to nitrogen ratios (C/N)a and carbon loadings (OC:SA)) were performed on correlative sediments from a transect of 7 cores from depositional sites located on the Waipaoa River floodplain and adjacent continental shelf and slope. Results were used to determine biogeochemical characteristics of organic carbon (OC) at a range of depositional sites during its transfer from terrestrial source to marine sink, and how large floods impact OC transfer to the marine environment. The high temporal variability in OC content (0.2 to 3.5%) and different source signatures (δ 1 3C of -26.7 to -20.6 permille) of Waipaoa River floodplain deposits prevented the establishment of a clear benchmark signature for flood deposits that may be recognisable in the marine sedimentary record. The high spatial and temporal variability of floodplain sediment OC, combined with the areal extent of floodplains within the catchment, indicates the appreciable modulating effect the floodplain has on OC transfers to the ocean. Since extensive stopbanks were constructed on the main floodplain since the 1940's, sequestration of OC in floodplain sediments has reduced by about half, increasing the overall

Copper in the sediment and sea surface microlayer near a fallowed, open-net fish farm.

Science.gov (United States)

Loucks, Ronald H; Smith, Ruth E; Fisher, Clyde V; Fisher, E Brian

2012-09-01

Sediment and sea surface microlayer samples near an open-net salmon farm in Nova Scotia, were analysed for copper. Copper is a constituent of the feed and is an active ingredient of anti-foulants. The salmon farm was placed in fallow after 15 years of production. Sampling was pursued over 27 months. Elevated copper concentrations in the sediments indicated the farm site as a source. Bubble flotation due to gas-emitting sediments from eutrophication is a likely process for accumulating copper in the sea surface microlayer at enriched concentrations. Elevated and enriched concentrations in the sea surface microlayer over distance from the farm site led, as a result of wind-drift, to an enlarged farm footprint. The levels of copper in both sediments and sea surface microlayer exceeded guidelines for protection of marine life. Over the 27 months period, copper levels persisted in the sediments and decreased gradually in the sea surface microlayer. Copyright © 2012 Elsevier Ltd. All rights reserved.

Total mercury concentrations in surface water and sediments from Danube Delta lakes

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TEODOROF Liliana

2007-10-01

Full Text Available The samples were collected from surface water and sediments of Danube Delta lakes, during april and may 2006. The sediments were digested with nitric acid, and the surface water with real aqua, at Microwave Oven Anton Paar and analised at FIMS 400 Perkin Elmer. The results show that the total mercury is compared with the maximum allowed limits according with Normative 161/2006.

Environmental and geochemical assessment of surface sediments on irshansk ilmenite deposit area

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Наталия Олеговна Крюченко

2015-03-01

Full Text Available It is revealed the problem of pollution of surface sediments of Irshansk ilmenite deposit area of various chemical elements hazard class (Mn, V, Ba, Ni, Co, Cr, Mo, Cu, Pb, Zn. It is determined its average content in surface sediments of various functional areas (forest and agricultural land, flood deposits, reclaimed land, calculated geochemical criteria, so given ecological and geochemical assessment of area

Variability of nutrient and thermal structure in surface waters between New Zealand and Antarctica, October 2004–January 2005

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Alessandra Campanelli

2011-04-01

Full Text Available We describe the upper ocean thermal structure and surface nutrient concentrations between New Zealand and Antarctica along five transects that cross the Subantarctic Front, the Polar Front (PF and the southern Antarctic Circumpolar Current (ACC front. The surface water thermal structure is coupled with variations in surface nutrient concentrations, making water masses identifiable by both temperature and nutrient ranges. In particular, a strong latitudinal gradient in orthosilicate concentration is centred at the PF. On the earlier sections that extend south-west from the Campbell Plateau, orthosilicate increases sharply southward from 10–15 to 50–55 µmol l−1 between 58° S and 60° S, while surface temperature drops from 7°C to 2°C. Nitrate increases more regularly toward the south, with concentrations ranging from 10–12 µmol l−1 at 54° S to 25–30 µmol l−1 at 66° S. The same features are observed during the later transects between New Zealand and the Ross Sea, but the sharp silica and surface temperature gradients are shifted between 60° S and 64° S. Both temporal and spatial factors may influence the observed variability. The January transect suggests an uptake of silica, orthophosphate and nitrate between 63° S and 70° S over the intervening month, with an average depletion near 37%, 44% and 29%, respectively. An N/P (nitrite + nitrate/orthophosphate apparent drawdown ratio of 8.8±4.1 and an Si/N (silicic acid/nitrite + nitrate apparent drawdown ratio >1 suggest this depletion results from a seasonal diatom bloom. A southward movement of the oceanic fronts between New Zealand and the Ross Sea relative to prior measurements is consistent with reports of recent warming and changes in the ACC.

Microplastics Baseline Surveys at the Water Surface and in Sediments of the North-East Atlantic

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Thomas Maes

2017-05-01

Full Text Available Microplastic contamination was determined in sediments of the Southern North Sea and floating at the sea surface of North West Europe. Floating concentrations ranged between 0 and 1.5 microplastic/m3, whereas microplastic concentrations in sediments ranged between 0 and 3,146 particles/kg dry weight sediment. In sediments, mainly fibers and spheres were found, whereas at the sea surface fragments were dominant. At the sea surface, concentrations of microplastics are lower and more variable than in sediments, meaning that larger sample sizes and water volumes are required to find detectable concentrations. We have calculated the widths of the confidence intervals (CI for different sample sizes, to give a first indication of the necessary sample size for a microplastic survey at the water surface. Higher concentrations of floating microplastics were found near estuaries. In sediments, estuaries and areas with a high organic carbon content were likely hotspots. Standardization of monitoring methods within marine regions is recommended to compare and assess microplastics pollution over time.

UPWARD MOVEMENT OF PLUTONIUM TO SURFACE SEDIMENTS DURING AN 11-YEAR FIELD STUDY

Energy Technology Data Exchange (ETDEWEB)

Kaplan, D.; Beals, D.; Cadieux, J.; Halverson, J.

2010-01-25

An 11-y lysimeter study was established to monitor the movement of Pu through vadose zone sediments. Sediment Pu concentrations as a function of depth indicated that some Pu moved upward from the buried source material. Subsequent numerical modeling suggested that the upward movement was largely the result of invading grasses taking up the Pu and translocating it upward. The objective of this study was to determine if the Pu of surface sediments originated from atmosphere fallout or from the buried lysimeter source material (weapons-grade Pu), providing additional evidence that plants were involved in the upward migration of Pu. The {sup 240}Pu/{sup 239}Pu and {sup 242}Pu/{sup 239}Pu atomic fraction ratios of the lysimeter surface sediments, as determined by Thermal Ionization Mass Spectroscopy (TIMS), were 0.063 and 0.00045, respectively; consistent with the signatures of the weapons-grade Pu. Our numerical simulations indicate that because plants create a large water flux, small concentrations over multiple years may result in a measurable accumulation of Pu on the ground surface. These results may have implications on the conceptual model for calculating risk associated with long-term stewardship and monitored natural attenuation management of Pu contaminated subsurface and surface sediments.

Spatiotemporal distributions of Fukushima-derived radionuclides in nearby marine surface sediments

Energy Technology Data Exchange (ETDEWEB)

Kusakabe, M.; Oikawa, S.; Takata, H.; Misonoo, J. [Marine Ecology Research Institute, Tokyo (Japan)

2013-07-01

Spatiotemporal distributions of anthropogenic radionuclides in marine surface sediments off Miyagi, Fukushima, and Ibaraki Prefectures were analyzed on the basis of data collected during the monitoring program launched by the Japanese Ministry of Education, Sports, Science and Technology in 2011 right after the Fukushima Dai-ichi Nuclear Power Plant accident began. Concentrations of {sup 137}Cs in the surface sediments varied spatially by two orders of magnitude, from 1.7 to 580 Bq kg-dry{sup -1}, and there was no obvious correlation between {sup 137}Cs concentration and the proximity of the sampling location to the accident site. The total inventory of {sup 137}Cs accumulated in the upper 3 cm of surface sediments in the monitoring area was estimated to be 3.78 x 10{sup 13} Bq, that is, 0.1-2% of the total {sup 137}Cs flux from the plant to the ocean as a result of the accident (the percentage depends on the model used to estimate the total flux). The spatial variations of {sup 137}Cs concentration and inventory depended on two main factors: the {sup 137}Cs concentration in the overlying water during the first several months after the accident and the physical characteristics of the sediments (water content and bulk density). The temporal variations of the concentrations of other anthropogenic radionuclides ({sup 90}Sr, {sup 95}Nb, {sup 110} {sup m}Ag, {sup 125}Sb, {sup 129}Te, and {sup 129} {sup m}Te) in the sediments were also investigated. Activity ratios of these nuclides to {sup 137}Cs suggest that the nuclides themselves were not homogenized before they were removed from seawater to the sediments.

The Association of Cryptosporidium parvum With Suspended Sediments: Implications for Transport in Surface Waters

Science.gov (United States)

Searcy, K. E.; Packman, A. I.; Atwill, E. R.; Harter, T.

2003-12-01

Understanding the transport and fate of microorganisms in surface waters is of vital concern in protecting the integrity and safety of municipal water supply systems. The human pathogen Cryptosporidium parvum is a particular public health interest, as it is ubiquitous in the surface waters of the United States, it can persist for long periods in the environment, and it is difficult to disinfect in water treatment plants. Due to its small size (5 um), low specific gravity (1.05 g/cm3), and negative surface charge, C. parvum oocysts are generally considered to move through watersheds from their source to drinking water reservoirs with little attenuation. However, the transport of the oocysts in surface waters may be mediated by interactions with suspended sediments. Batch experiments were conducted to determine the extent of C. parvum oocyst attachment to several inorganic and organic sediments under varying water chemical conditions, and settling column experiments were performed to demonstrate how these associations influence the effective settling velocity of C. parvum oocysts. Results from these experiments showed that C. parvum oocysts do associate with inorganic and organic sediments and often settle at the rate of the suspended sediment. The size and surface charge of the host suspended sediment influenced the extent of oocyst attachment as oocysts preferentially associated with particles greater than 3 um, and fewer oocysts associated with particles having a highly negative surface charge. Background water chemical conditions including ionic strength, ion composition, and pH did not have a significant effect on oocyst attachment to suspended sediments.

Soil, Groundwater, Surface Water, and Sediments of Kennedy Space Center, Florida: Background Chemical and Physical Characteristics

Science.gov (United States)

Shmalzer, Paul A.; Hensley, Melissa A.; Mota, Mario; Hall, Carlton R.; Dunlevy, Colleen A.

2000-01-01

This study documented background chemical composition of soils, groundwater, surface; water, and sediments of Kennedy Space Center. Two hundred soil samples were collected, 20 each in 10 soil classes. Fifty-one groundwater wells were installed in 4 subaquifers of the Surficial Aquifer and sampled; there were 24 shallow, 16 intermediate, and 11 deep wells. Forty surface water and sediment samples were collected in major watershed basins. All samples were away from sites of known contamination. Samples were analyzed for organochlorine pesticides, aroclors, chlorinated herbicides, polycyclic aromatic hydrocarbons (PAH), total metals, and other parameters. All aroclors (6) were below detection in all media. Some organochlorine pesticides were detected at very low frequencies in soil, sediment, and surface water. Chlorinated herbicides were detected at very low frequencies in soil and sediments. PAH occurred in low frequencies in soiL, shallow groundwater, surface water, and sediments. Concentrations of some metals differed among soil classes, with subaquifers and depths, and among watershed basins for surface water but not sediments. Most of the variation in metal concentrations was natural, but agriculture had increased Cr, Cu, Mn, and Zn.

Effects of engineered nano-titanium dioxide on pore surface properties and phosphorus adsorption of sediment: its environmental implications.

Science.gov (United States)

Luo, Zhuanxi; Wang, Zhenhong; Wei, Qunshan; Yan, Changzhou; Liu, Feng

2011-09-15

Understanding the environmental safety and human health implications of engineered nanoparticles (ENPs) is of worldwide importance. As an important ENPs, engineered nano-TiO(2) (Enano-TiO(2)) may have been substantially deposited in aquatic sediments because of its widely uses. Sediment pore surface properties would be thus significantly influenced due to the large surface area of Enano-TiO(2). In this study, Enano-TiO(2) was found to greatly impact on sediment pore surface properties. The attachment of Enano-TiO(2) particles to sediment surfaces enhanced markedly BET specific surface area and t-Plot external specific surface area, and thereby increased sediment phosphorus (P) adsorption maximum (S(max)). Contrarily, the fill of Enano-TiO(2) particles into the micropores of sediments could significantly reduce t-Plot micropore specific surface area, and cause slight decrease in sediment P binding energy (K). Clearly, P sorbed in sediment would be easily released because of the decreasing P binding energy of the sediment with elevated Enano-TiO(2). Enano-TiO(2) would thus cause aggravated endogenous pollution in water if such sediment was re-suspended on disturbance. The results obtained in this study contribute to our increasing knowledge of how to regulate physicochemical behavior of pollutants in sediments under the influences of Enano-TiO(2) and/or similar ENPs. Copyright © 2011 Elsevier B.V. All rights reserved.

Gross Nitrogen Mineralization in Surface Sediments of the Yangtze Estuary

Science.gov (United States)

Liu, Min; Li, Xiaofei; Yin, Guoyu; Zheng, Yanling; Deng, Fengyu

2016-01-01

Nitrogen mineralization is a key biogeochemical process transforming organic nitrogen to inorganic nitrogen in estuarine and coastal sediments. Although sedimentary nitrogen mineralization is an important internal driver for aquatic eutrophication, few studies have investigated sedimentary nitrogen mineralization in these environments. Sediment-slurry incubation experiments combined with 15N isotope dilution technique were conducted to quantify the potential rates of nitrogen mineralization in surface sediments of the Yangtze Estuary. The gross nitrogen mineralization (GNM) rates ranged from 0.02 to 5.13 mg N kg-1 d-1 in surface sediments of the study area. The GNM rates were generally higher in summer than in winter, and the relative high rates were detected mainly at sites near the north branch and frontal edge of this estuary. The spatial and temporal distributions of GNM rates were observed to depend largely on temperature, salinity, sedimentary organic carbon and nitrogen contents, and extracellular enzyme (urease and L-glutaminase) activities. The total mineralized nitrogen in the sediments of the Yangtze Estuary was estimated to be about 6.17 × 105 t N yr-1, and approximately 37% of it was retained in the estuary. Assuming the retained mineralized nitrogen is totally released from the sediments into the water column, which contributed 12–15% of total dissolved inorganic nitrogen (DIN) sources in this study area. This result indicated that the mineralization process is a significant internal nitrogen source for the overlying water of the Yangtze Estuary, and thus may contribute to the estuarine and coastal eutrophication. PMID:26991904

Effect of different concentrations of sodium hyaluronate on the ocular surface change of dry eye in New Zealand rabbits

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Shuang-Yong Wang

2015-10-01

Full Text Available AIM:To observe the effect of different concentrations of sodium hyaluronate on ocular surface change of dry eye. METHODS: New Zealand rabbits with dry eye was prepared and treated with 0.1% and 0.3% sodium hyaluronate drops fluid respectively, which were regarded as low concentration treatment group(group Band high concentration treatment group(group Crespectively. However, the rabbits treated with saline were regarded as control group(group A. And then, corneal fluorescein staining, Schirmer test, conjunctival goblet cells, mucin expression and histological changes were observed.RESULTS: On D7 and D14 after treatment, corneal fluorescein staining scores were lower in group B and group C than that in group A(PP PCONCLUSION: The sodium hyaluronate can improve ocular surface damage of dry eye in New Zealand rabbits. The high concentration of sodium hyaluronate has better effect than low concentration.

Emplacement of rock avalanche material across saturated sediments, Southern Alp, New Zealand

Science.gov (United States)

Dufresne, A.; Davies, T. R.; McSaveney, M. J.

2012-04-01

The spreading of material from slope failure events is not only influenced by the volume and nature of the source material and the local topography, but also by the materials encountered in the runout path. In this study, evidence of complex interactions between rock avalanche and sedimentary runout path material were investigated at the 45 x 106 m3 long-runout (L: 4.8 km) Round Top rock avalanche deposit, New Zealand. It was sourced within myolinitic schists of the active strike-slip Alpine Fault. The narrow and in-failure-direction elongate source scarp is deep-seated, indicating slope failure was triggered by strong seismic activity. The most striking morphological deposit features are longitudinal ridges aligned radially to source. Trenching and geophysical surveys show bulldozed and sheared substrate material at ridge termini and laterally displaced sedimentary strata. The substrate failed at a minimum depth of 3 m indicating a ploughing motion of the ridges into the saturated material below. Internal avalanche compression features suggest deceleration behind the bulldozed substrate obstacle. Contorted fabric in material ahead of the ridge document substrate disruption by the overriding avalanche material deposited as the next down-motion hummock. Comparison with rock avalanches of similar volume but different emplacement environments places Round Top between longer runout avalanches emplaced over e.g. playa lake sediments and those with shorter travel distances, whose runout was apparently retarded by topographic obstacles or that entrained high-friction debris. These empirical observations indicate the importance of runout path materials on tentative trends in rock avalanche emplacement dynamics and runout behaviour.

The geochemistry of coprostanol in waters and surface sediments from Narragansett Bay

Science.gov (United States)

LeBlanc, Lawrence A.; Latimer, James S.; Ellis, John T.; Quinn, James G.

1992-05-01

A geochemical study of coprostanol (5β-Cholestan-3β-ol) was undertaken, to examine the transport and fate of a compound of moderate polarity and reactivity in the marine environment, and also because of the interest in coprostanol for use as a sewage tracer. During 1985-86, 20 sites in Narragansett Bay, including the major point sources and rivers discharging into the bay estuary, were sampled at four different times. In addition, surface sediments from 26 stations in the bay were collected. The large number and diversity of samples allowed for an assessment of major inputs of sewage into the bay as well as the recent fate of sewage-derived particles in surface sediments. Results from the study revealed that 50% of the total particulate coprostanol entering the bay was discharged into the Providence River, primarily due to inputs from the wastewater treatment facility (WWTF) at Fields Point, as well as input from the Pawtuxet and Blackstone Rivers. In the lower bay, the Newport WWTF was the largest single source of coprostanol (37% of the total particulate coprostanol) to the bay. Effluent concentrations of coprostanol from secondary WWTFs were consistently lower than those of primary treatment facilities, demonstrating the usefulness of corporstanol as an indicator of treatment plant efficiency. The distribution of coprostanol in waters and surface sediments showed a gradient of decreasing concentration downbay. When coprostanol concentrations in surface sediments were normalized to organic carbon (OC) concentrations, elevated levels were seen only in the Providence River, with a more or less even distribution throughout the rest of the bay. Results also suggest that coprostanol degrades more rapidly in the water column compared to the petroleum hydrocarbons (PHCs), polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs), however, it is relatively stable once it is buried in the sediments. Coprostanol concentrations in waters (0·02-0·22 �

Modern processes of sediment formation in Lake Towuti, Indonesia, as derived from the composition of lake surface sediments

Science.gov (United States)

Hasberg, Ascelina; Melles, Martin; Morlock, Marina; Vogel, Hendrik; Russel, James M.; Bijaksana, Satria

2016-04-01

In summer 2015, a drilling operation funded by the International Continental Scientific Drilling Program (ICDP) was conducted at Lake Towuti (2.75°S, 121.5°E), the largest tectonically formed lake (surface area: 561 km²) of the Republic Indonesia. The Towuti Drilling Project (TDP) recovered more than 1000 meters of sediment core from three sites. At all three sites replicate cores down to 133, 154, and 174 m below lake floor have penetrated the entire lake sediment record, which is expected to comprise the past ca. 650.000 years continuously. Lake Towutís sediment record thus can provide unique information for instance concerning the climatic and environmental history in the Indo-Pacific-Warm-Pool (IPWP) and concerning the evolutionary biology in SE Asia. For a better understanding of the palaeoenvironmental proxies to be analyzed on the drill cores, the modern processes of sediment formation in the lake and in its catchment - under known environmental conditions - were investigated on a set of 84 lake sediment surface samples. Sampling was conducted by grab sampler (UWITEC Corp., Austria) in a grid of 1 to 4 km resolution that covers the entire lake. The samples were analyzed for inorganic geochemical composition (XRF powder scans and ICP-MS), magnetic susceptibility (Kappabridge), grain-size distribution (laser scanner), biogenic components (smear-slide analyses), biogenic silica contents (leaching), and carbonate, total organic carbon (TOC), nitrogen (TN), and sulfur (TS) concentrations (elemental analyzer). The sediments close to the lake shores and in front of the major river inlets are characterized by mean grain sizes coarser than average and high magnetic susceptibilities presented by high ratios of Cr, Ni, Co, and Zr. This reflects higher energies due to wave action and fluvial sediment supply, as well as the occurrence of magnetic minerals particularly in the sand and gravel fractions of the sediments. In regions of deeper waters and more distal to

Methane Bubbles Transport Particles From Contaminated Sediment to a Lake Surface

Science.gov (United States)

Delwiche, K.; Hemond, H.

2017-12-01

Methane bubbling from aquatic sediments has long been known to transport carbon to the atmosphere, but new evidence presented here suggests that methane bubbles also transport particulate matter to a lake surface. This transport pathway is of particular importance in lakes with contaminated sediments, as bubble transport could increase human exposure to toxic metals. The Upper Mystic Lake in Arlington, MA has a documented history of methane bubbling and sediment contamination by arsenic and other heavy metals, and we have conducted laboratory and field studies demonstrating that methane bubbles are capable of transporting sediment particles over depths as great as 15 m in Upper Mystic Lake. Methane bubble traps were used in-situ to capture particles adhered to bubble interfaces, and to relate particle mass transport to bubble flux. Laboratory studies were conducted in a custom-made 15 m tall water column to quantify the relationship between water column height and the mass of particulate transport. We then couple this particle transport data with historical estimates of ebullition from Upper Mystic Lake to quantify the significance of bubble-mediated particle transport to heavy metal cycling within the lake. Results suggest that methane bubbles can represent a significant pathway for contaminated sediment to reach surface waters even in relatively deep water bodies. Given the frequent co-occurrence of contaminated sediments and high bubble flux rates, and the potential for human exposure to heavy metals, it will be critical to study the significance of this transport pathway for a range of sediment and contaminant types.

An Eulerian two-phase flow model for sediment transport under realistic surface waves

Science.gov (United States)

Hsu, T. J.; Kim, Y.; Cheng, Z.; Chauchat, J.

2017-12-01

Wave-driven sediment transport is of major importance in driving beach morphology. However, the complex mechanisms associated with unsteadiness, free-surface effects, and wave-breaking turbulence have not been fully understood. Particularly, most existing models for sediment transport adopt bottom boundary layer approximation that mimics the flow condition in oscillating water tunnel (U-tube). However, it is well-known that there are key differences in sediment transport when comparing to large wave flume datasets, although the number of wave flume experiments are relatively limited regardless of its importance. Thus, a numerical model which can resolve the entire water column from the bottom boundary layer to the free surface can be a powerful tool. This study reports an on-going effort to better understand and quantify sediment transport under shoaling and breaking surface waves through the creation of open-source numerical models in the OpenFOAM framework. An Eulerian two-phase flow model, SedFoam (Cheng et al., 2017, Coastal Eng.) is fully coupled with a volume-of-fluid solver, interFoam/waves2Foam (Jacobsen et al., 2011, Int. J. Num. Fluid). The fully coupled model, named SedWaveFoam, regards the air and water phases as two immiscible fluids with the interfaces evolution resolved, and the sediment particles as dispersed phase. We carried out model-data comparisons with the large wave flume sheet flow data for nonbreaking waves reported by Dohmen-Janssen and Hanes (2002, J. Geophysical Res.) and good agreements were obtained for sediment concentration and net transport rate. By further simulating a case without free-surface (mimic U-tube condition), the effects of free-surface, most notably the boundary layer streaming effect on total transport, can be quantified.

Approaches to surface complexation modeling of Uranium(VI) adsorption on aquifer sediments

Science.gov (United States)

Davis, J.A.; Meece, D.E.; Kohler, M.; Curtis, G.P.

2004-01-01

Uranium(VI) adsorption onto aquifer sediments was studied in batch experiments as a function of pH and U(VI) and dissolved carbonate concentrations in artificial groundwater solutions. The sediments were collected from an alluvial aquifer at a location upgradient of contamination from a former uranium mill operation at Naturita, Colorado (USA). The ranges of aqueous chemical conditions used in the U(VI) adsorption experiments (pH 6.9 to 7.9; U(VI) concentration 2.5 ?? 10-8 to 1 ?? 10-5 M; partial pressure of carbon dioxide gas 0.05 to 6.8%) were based on the spatial variation in chemical conditions observed in 1999-2000 in the Naturita alluvial aquifer. The major minerals in the sediments were quartz, feldspars, and calcite, with minor amounts of magnetite and clay minerals. Quartz grains commonly exhibited coatings that were greater than 10 nm in thickness and composed of an illite-smectite clay with occluded ferrihydrite and goethite nanoparticles. Chemical extractions of quartz grains removed from the sediments were used to estimate the masses of iron and aluminum present in the coatings. Various surface complexation modeling approaches were compared in terms of the ability to describe the U(VI) experimental data and the data requirements for model application to the sediments. Published models for U(VI) adsorption on reference minerals were applied to predict U(VI) adsorption based on assumptions about the sediment surface composition and physical properties (e.g., surface area and electrical double layer). Predictions from these models were highly variable, with results overpredicting or underpredicting the experimental data, depending on the assumptions used to apply the model. Although the models for reference minerals are supported by detailed experimental studies (and in ideal cases, surface spectroscopy), the results suggest that errors are caused in applying the models directly to the sediments by uncertain knowledge of: 1) the proportion and types of

Lead-210 analyses of sediment accumulation rates in five Southern Illinois surface mine lakes

International Nuclear Information System (INIS)

Brugam, R.B.; Carlson, M.A.

1981-01-01

210 Pb is a naturally occurring radionuclide with a short half-life (22 yrs) which can be used to determine sedimentation rates in lakes. The technique was applied in 5 Southern Illinois surface mine lakes where it revealed past sedimentation rates to have been extremely variable. In some of the lakes there was evidence for extensive slumping immediately after mining ceased followed by a more regular sedimentary regime that continued until the present. In others there have been one or more changes in sediment accumulation rates since lacustrine sedimentation began. These results suggest that simply measuring the amount of sediment that has accumulated in a surface mine lake since mining ceased is inadequate to determine filling rates. Sedimentation rates in the 5 lakes varied from .60 +- .19 to 1.46 +- .19 cm/y. These rates are similar to natural lakes with moderately disturbed watersheds

Sedimentation and fouling of optical surfaces at the ANTARES site

Science.gov (United States)

ANTARES Collaboration; CAU CEFREM Collaboration; Amram, P.; Anghinolfi, M.; Anvar, S.; Ardellier-Desages, F. E.; Aslanides, E.; Aubert, J.-J.; Azoulay, R.; Bailey, D.; Basa, S.; Battaglieri, M.; Bellotti, R.; Beltramelli, J.; Benhammou, Y.; Berthier, R.; Bertin, V.; Billault, M.; Blaes, R.; Bland, R. W.; Blondeau, F.; de Botton, N.; Boulesteix, J.; Brooks, C. B.; Brunner, J.; Cafagna, F.; Calzas, A.; Capone, A.; Caponetto, L.; Cârloganu, C.; Carmona, E.; Carr, J.; Cartwright, S. L.; Cecchini, S.; Ciacio, F.; Circella, M.; Compère, C.; Cooper, S.; Coyle, P.; Cuneo, S.; Danilov, M.; van Dantzig, R.; de Marzo, C.; Destelle, J.-J.; de Vita, R.; Dispau, G.; Druillole, F.; Engelen, J.; Feinstein, F.; Ferdi, C.; Festy, D.; Fopma, J.; Gallone, J.-M.; Giacomelli, G.; Goret, P.; Gournay, J.-F.; Hallewell, G.; Heijboer, A.; Hernández-Rey, J. J.; Hubbard, J. R.; Jaquet, M.; de Jong, M.; Karolak, M.; Keller, P.; Kooijman, P.; Kouchner, A.; Kudryavtsev, V. A.; Lafoux, H.; Lagier, P.; Lamare, P.; Languillat, J.-C.; Laubier, L.; Laugier, J.-P.; Leilde, B.; Le Provost, H.; Le van Suu, A.; Lo Nigro, L.; Lo Presti, D.; Loucatos, S.; Louis, F.; Lyashuk, V.; Magnier, P.; Marcelin, M.; Margiotta, A.; Masullo, R.; Mazéas, F.; Mazeau, B.; Mazure, A.; McMillan, J. E.; Migneco, E.; Millot, C.; Mols, P.; Montanet, F.; Montaruli, T.; Moscoso, L.; Musumeci, M.; Nezri, E.; Nooren, G. J.; Oberski, J. E. J.; Olivetto, C.; Oppelt-Pohl, A.; Palanque-Delabrouille, N.; Papaleo, R.; Payre, P.; Perrin, P.; Petruccetti, M.; Petta, C.; Piattelli, P.; Poinsignon, J.; Potheau, R.; Queinec, Y.; Racca, C.; Raia, G.; Randazzo, N.; Rethore, F.; Riccobene, G.; Ricol, J.-S.; Ripani, M.; Roca-Blay, V.; Romeyer, A.; Rostovstev, A.; Russo, G. V.; Sacquin, Y.; Salusti, E.; Schuller, J.-P.; Schuster, W.; Soirat, J.-P.; Souvorova, O.; Spooner, N. J. C.; Spurio, M.; Stolarczyk, T.; Stubert, D.; Taiuti, M.; Tao, C.; Thompson, L. F.; Tilav, S.; Triay, R.; Usik, A.; Valdy, P.; Valente, V.; Varlamov, I.; Vaudaine, G.; Vernin, P.; Vladimirsky, E.; Vorobiev, M.; de Witt Huberts, P.; de Wolf, E.; Zakharov, V.; Zavatarelli, S.; Zornoza, Juan de Dios; Zún~Iga, J.; Aloïsi, J.-C.; Kerhervé, Ph.; Monaco, A.

2003-05-01

ANTARES is a project leading towards the construction and deployment of a neutrino telescope in the deep Mediterranean Sea. The telescope will use an array of photomultiplier tubes to detect the Cherenkov light emitted by muons resulting from the interaction with matter of high energy neutrinos. In the vicinity of the deployment site the ANTARES Collaboration has performed a series of in situ measurements to study the change in light transmission through glass surfaces during immersions of several months. The average loss of light transmission is estimated to be only ~2% at the equator of a glass sphere one year after deployment. It decreases with increasing zenith angle, and tends to saturate with time. The transmission loss, therefore, is expected to remain small for the several year lifetime of the ANTARES detector whose optical modules are oriented downwards. The measurements were complemented by the analysis of the 210Pb activity profile in sediment cores and the study of biofouling on glass plates. Despite a significant sedimentation rate at the site, in the 0.02-0.05 cmyr-1 range, the sediments adhere loosely to the glass surfaces and can be washed off by water currents. Further, fouling by deposits of light-absorbing particulates is only significant for surfaces facing upwards.

Aeolian sediment transport on a beach: Surface moisture, wind fetch, and mean transport

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Bauer, B. O.; Davidson-Arnott, R. G. D.; Hesp, P. A.; Namikas, S. L.; Ollerhead, J.; Walker, I. J.

2009-04-01

Temporal and spatial changes in wind speed, wind direction, and moisture content are ubiquitous across sandy coastal beaches. Often these factors interact in unknown ways to create complexity that confounds our ability to model sediment transport at any point across the beach as well as our capacity to predict sediment delivery into the adjacent foredunes. This study was designed to measure wind flow and sediment transport over a beach and foredune at Greenwich Dunes, Prince Edward Island National Park, with the express purpose of addressing these complex interactions. Detailed measurements are reported for one stormy day, October 11, 2004, during which meteorological conditions were highly variable. Wind speed ranged from 4 ms - 1 to over 20 ms - 1 , wind direction was highly oblique varying between 60° and 85° from shore perpendicular, and moisture content of the sand surface ranged from a minimum of about 3% (by mass) to complete saturation depending on precipitation, tidal excursion, and storm surge that progressively inundated the beach. The data indicate that short-term variations (i.e., minutes to hours) in sediment transport across this beach arise predominantly because of short-term changes in wind speed, as is expected, but also because of variations in wind direction, precipitation intensity, and tide level. Even slight increases in wind speed are capable of driving more intense saltation events, but this relationship is mediated by other factors on this characteristically narrow beach. As the angle of wind approach becomes more oblique, the fetch distance increases and allows greater opportunity for the saltation system to evolve toward an equilibrium transport state before reaching the foredunes. Whether the theoretically-predicted maximum rate of transport is ever achieved depends on the character of the sand surface (e.g., grain size, slope, roughness, vegetation, moisture content) and on various attributes of the wind field (e.g., average wind

Bacterial biogeography influenced by shelf-basin exchange in the Arctic surface sediment at the Chukchi Borderland.

Science.gov (United States)

Han, Dukki; Nam, Seung-Il; Ha, Ho Kyung; Kim, Hyoungjun; Sadowsky, Michael J; Lee, Yoo Kyung; Hur, Hor-Gil

2016-02-01

It has been known that continental shelves around the Arctic Ocean play a major role in the ventilation of the deep basins as a consequence of shelf-basin exchange. In the present study, we found that bacterial assemblage of the surface sediment was different from that of seawater while seawater harboured local bacterial assemblages in response to the Arctic hydrography. This finding suggests that the Arctic seafloor sediments may have distinctive bacterial biogeography. Moreover, the distribution of bacterial assemblages and physicochemical properties in surface sediments changed gradually from the Arctic continental shelf to deep-sea basin. Based on the results, bacterial biogeography in the Arctic seafloor sediments may be influenced by winnowing and re-deposition of surface sediments through the sediment gravity flow. The present study offers a deeper understanding of shelf convection and its role for the construction of bacterial assemblages in the Arctic Ocean. © 2015 Society for Applied Microbiology and John Wiley & Sons Ltd.

[Surface Property and Sorption Characteristics of Phosphorus onto Surface Sediments in Sanggou Bay].

Science.gov (United States)

Zhu, Jia-mei; Cao, Xiao-yan; Liu, Su-mei; Wang, Li-sha; Yang, Gui-peng; Ge, Cheng-feng; Lu, Min

2016-02-15

Kinetic curves and isotherms were investigated to study the sorption mechanism of phosphorus onto the sediments of Sanggou Bay, together with the surface charge properties of sediments and the forms of phosphorus studied. The results showed that the sorption including a fast process and a slow one, and could be described by a two-compartment first order equation. The thermodynamic isotherms were well fitted with a modified Langmuir equation. The maximum adsorption capacity was larger in summer than in spring, and the smaller particle size was favorable to the sorption. The maximum adsorption capacities (Qm) were 0.0471-0.1230 mg x g(-1), and the zero equilibrium phosphorus concentration (EPC0) of the sediments ranged from 0.0596 mg x L(-1) to 0.1927 mg x L(-1), which indicated that the sediments from Sanggou Bay were sources of phosphorus. Inorganic phosphorus (IP) was the main form of total phosphorus (TP). The contents of exchangeable or loosely absorbed P and Fe-bound P increased significantly in the samples after sorption. The sorption process involved physical sorption and chemical sorption, with the former being the predominant.

Surface water, particulate matter, and sediments of inland waters

International Nuclear Information System (INIS)

Mundschenk, H.

1985-01-01

The Bundesanstalt fuer Gewaesserkunde (BfG) since 1958 runs a system for monitoring the surface water and sediments of Federal German waterways in its capacity as a directing water monitoring centre. The data recorded over the years show that the radioactivity released by the various emission sources leads to radionuclide concentrations in water, particulate matter, or sediments that generally are below the detection limits defined in the relevant legal provisions governing monitoring and surveillance of nuclear facilities effluents. Representative examples of measuring methods and results (as for e.g. for H-3) are given. (DG) [de

Aliphatic hydrocarbons in surface sediments from South China Sea off Kuching Division, Sarawak

International Nuclear Information System (INIS)

Hafidz Yusoff; Zaini Assim; Samsur Mohamad

2012-01-01

Eighteen surface sediment samples collected from South China Sea off Kuching Division, Sarawak were analyzed for aliphatic hydrocarbons. These hydrocarbons were recovered from sediment by Soxhlet extraction method and then analyzed using gas chromatography equipped with mass spectrometer (GC/ MS). Total concentrations of aliphatic hydrocarbons in surface sediments from South China Sea off Kuching division are ranged from 35.6 μg/ g to 1466.1 μg/ g dry weights. The sediments collected from Bako Bay, Kuching showed high concentrations of total aliphatic hydrocarbons. Several molecular indices were used to predict the predominant sources of hydrocarbons. Carbon preference index (CPI) value revealed widespread anthropogenic input in this study area (CPI= 0 to 4.1). The ratio of C 31 / C 19 and C 29 / C 31 indicated that major input of aliphatic hydrocarbon mostly transfer by lateral input to the marine environment than atmospheric movements. Generally, the concentrations of aliphatic hydrocarbons in sediment from South China Sea off Kuching division are generally higher compare to other area in the world. (author)

Regional and sediment depth differences in nematode community structure greater than between habitats on the New Zealand margin: Implications for vulnerability to anthropogenic disturbance

Science.gov (United States)

Rosli, Norliana; Leduc, Daniel; Rowden, Ashley A.; Probert, P. Keith; Clark, Malcolm R.

2018-01-01

Deep-sea community attributes vary at a range of spatial scales. However, identifying the scale at which environmental factors affect variability in deep-sea communities remains difficult, as few studies have been designed in such a way as to allow meaningful comparisons across more than two spatial scales. In the present study, we investigated nematode diversity, community structure and trophic structure at different spatial scales (sediment depth (cm), habitat (seamount, canyon, continental slope; 1-100 km), and geographic region (100-10000 km)), while accounting for the effects of water depth, in two regions on New Zealand's continental margin. The greatest variability in community attributes was found between sediment depth layers and between regions, which explained 2-4 times more variability than habitats. The effect of habitat was consistently stronger in the Hikurangi Margin than the Bay of Plenty for all community attributes, whereas the opposite pattern was found in the Bay of Plenty where effect of sediment depth was greater in Bay of Plenty. The different patterns at each scale in each region reflect the differences in the environmental variables between regions that control nematode community attributes. Analyses suggest that nematode communities are mostly influenced by sediment characteristics and food availability, but that disturbance (fishing activity and bioturbation) also accounts for some of the observed patterns. The results provide new insight on the relative importance of processes operating at different spatial scales in regulating nematode communities in the deep-sea, and indicate potential differences in vulnerability to anthropogenic disturbance.

[Accumulation, distribution and pollution assessment of heavy metals in surface sediment of Caohai plateau wetland, Guizhou province].

Science.gov (United States)

Zhang, Qing-Hai; Lin, Chang-Hu; Tan, Hong; Lin, Shao-Xia; Yang, Hong-Bo

2013-03-01

The objective of this paper is to investigate the concentrations and distribution characteristics of heavy metals in surface sediments of different areas in the Caohai plateau wetland. 16 samples of surface sediments were collected and 7 heavy metals were analyzed. Heavy metal pollution in surface sediments of different areas in the Caohai plateau wetland was estimated by the Tomlinson Pollution Load Index (PLI) method. The analyzed results indicated that the average contents of Cd, Hg, As, Pb, Cr, Cu, Zn were 0.985, 0.345, 15.8, 38.9, 38.6, 22.8 and 384 mg x kg(-1), respectively. The heavy metal distributions varied with regional environment changes, the order of average contents of Cd and Hg in different regions was E (the eastern region) > S (the southern region) > N (the northern region), the order of the average content of Pb was N > E > S, and that of Zn was S > E > N. The results also suggested a medium heavy metal pollution level in the surface sediment of the Caohai plateau wetland with the PLI(zone) reaching 1.17. The order of pollution level in surface sediments of different regions was E > S > N. The results showed medium pollution levels in E and Hg which reached the extreme intensity pollution level were also the major polluted elements in surface sediments of the Caohai plateau wetland. And also, results showed medium pollution levels of Cd and Pb in surface sediments of Caohai plateau wetland. Cluster analysis results showed similar pollution sources of Cd, Zn, Pb and Hg, which should be attached great importance in terms of the prevention of the Caohai plateau wetland.

Spatial distribution and source apportionment of PFASs in surface sediments from five lake regions, China.

Science.gov (United States)

Qi, Yanjie; Huo, Shouliang; Xi, Beidou; Hu, Shibin; Zhang, Jingtian; He, Zhuoshi

2016-03-07

Perfluoroalkyl substances (PFASs) have been found in environment globally. However, studies on PFAS occurrence in sediments of lakes or reservoirs remain relatively scarce. In this study, two hundred and sixty-two surface sediment samples were collected from forty-eight lakes and two reservoirs all over China. Average PFAS concentrations in surface sediments from each lake or reservoir varied from 0.086 ng/g dw to 5.79 ng/g dw with an average of 1.15 ng/g dw. Among five lake regions, average PFAS concentrations for the lakes from Eastern Plain Region were the highest. Perfluorooctanoic acid, perfluoroundecanoic acid and perfluorooctane sulfonic acid (PFOS) were the predominant PFASs in surface sediments. The significant positive correlations between PFAS concentrations and total organic carbon, total nitrogen and total phosphorus contents in sediments revealed the influences of sedimentary characteristics on PFAS occurrence. A two-dimensional hierarchical cluster analysis heat map was depicted to analyze the possible origins of sediments and individual PFAS. The food-packaging, textile, electroplating, firefighting and semiconductor industry emission sources and the precious metals and coating industry emission sources were identified as the main sources by two receptor models, with contributions of 77.7 and 22.3% to the total concentrations of C4-C14- perfluoroalkyl carboxylic acids and PFOS, respectively.

Trace metal pollution assessment in the surface sediments of nearshore area, off Calicut, southwest coast of India.

Science.gov (United States)

Srinivas, Reji; Shynu, R; Sreeraj, M K; Ramachandran, K K

2017-07-15

Metal concentrations (Al, Cr, Ni, Cu, Zn, and Pb), grain size, and total organic carbon content in 29 surface sediment samples from the nearshore area off Calicut were analyzed to determine their distribution and pollution status. Surface sediments were dominantly silts with low percentage of clay and sand at nearshore and offshore areas. The mean metal concentrations were in the following order: Cr>Ni>Zn>Pb>Cu. The enrichment factor and geo-accumulation index of metals suggest that the surface sediments were not polluted by Zn and moderately polluted by Cu and Ni. By contrast, Cr and Pb showed significant enrichment levels. Results from a multivariate statistical analysis suggested that the spatial enrichment of these heavy metals was related to sediment type. Thus, the sediment distribution and their metal enrichment were mainly controlled by local hydrodynamic conditions that caused the winnowing of fine-grained sediments. Copyright © 2017. Published by Elsevier Ltd.

Surface Sediment Analysis on Petroleum Hydrocarbon and Total Organic Carbon from Coastal Area of Papar to Tuaran, Sabah

International Nuclear Information System (INIS)

Siti Aishah Mohd Ali; Payus, C.; Masni Mohd Ali

2015-01-01

Total petroleum hydrocarbons (TPH) and total organic carbon (TOC) were investigated in surface sediments along coastal area of Papar to Tuaran, Sabah. Surface sediment samples were collected in 24 different stations in each area by using Ponar grab sampler. Samples were extracted for TPH using standard method sediment/ sludge APHA 5520E and analyzed using UV/VIS spectrophotometer while for TOC method analysis using United Nations Environment Programme (UNEP)/ MAP Athens (2006). The range of TPH concentrations in surface sediments were recorded at 0.24 - 20.65 mg/ kg dw Miri crude oil equivalents, meanwhile the TOC percentage ranged from 0.03 - 4.02 %. In the mean time, the statistical analysis by Pearson correlation showed a positive correlation with coefficient, r = 0.790 which showing the TPH concentrations significantly have influence on the TOC accumulations in the surface sediment. (author)

Water quality in New Zealand's planted forests: A review

Science.gov (United States)

Brenda R. Baillie; Daniel G. Neary

2015-01-01

This paper reviewed the key physical, chemical and biological water quality attributes of surface waters in New Zealand’s planted forests. The purpose was to: a) assess the changes in water quality throughout the planted forestry cycle from afforestation through to harvesting; b) compare water quality from planted forests with other land uses in New Zealand; and c)...

Distribution and sources of n-alkanes in surface sediments of Taihu Lake, China

Directory of Open Access Journals (Sweden)

Yu Yunlong

2016-03-01

Full Text Available The last study on n-alkanes in surface sediments of Taihu Lake was in 2000, only 13 surface sediment samples were analysed, in order to have a comprehensive and up-to-date understanding of n-alkanes in the surface sediments of Taihu Lake, 41 surface sediment samples were analyzed by GC-MS. C10 to C37 were detected, the total concentrations of n-alkanes ranged from 2109 ng g−1 to 9096 ng g−1 (dry weight. There was strong odd carbon predominance in long chain n-alkanes and even carbon predominance in short chain n-alkanes. When this finding was combined with the analysis results of wax n-alkanes (WaxCn, carbon preference index (CPI, unresolved complex mixture (UCM, hopanes and steranes, it was considered that the long chain n-alkanes were mainly from terrigenous higher plants, and that the short chain n-alkanes mainly originated from bacteria and algae in the lake, compared with previous studies, there were no obvious anthropogenic petrogenic inputs. Terrestrial and aquatic hydrocarbons ratio (TAR and C21−/C25+ indicated that terrigenous input was higher than aquatic sources and the nearshore n-alkanes were mainly from land-derived sources. Moreover, the distribution of short chain n-alkanes presented a relatively uniform pattern, while the long chain n-alkanes presented a trend that concentrations dropped from nearshore places to the middle of lake.

Problems and Possible Solutions Concerning Radiocarbon Dating of Surface Marine Sediments, Ross Sea, Antarctica

Science.gov (United States)

Andrews, John T.; Domack, Eugene W.; Cunningham, Wendy L.; Leventer, Amy; Licht, Kathy J.; Jull, A. J. Timothy; DeMaster, David J.; Jennings, Anne E.

1999-09-01

Radiocarbon accelerator mass spectrometric (AMS) dates on the acid-insoluble fraction from 38 core tops from the western Ross Sea, Antarctica, are used to address these questions: (1) What are the apparent ages of sediments at or close to the present sediment/water interface? (2) Is there a statistically significant pattern to the spatial distribution of core top ages? and (3) Is there a "correction factor" that can be applied to these age determinations to obtain the best possible Holocene (downcore) chronologies? Ages of core top sediments range from 2000 to 21,000 14C yr B.P. Some "old" core top dates are from piston cores and probably represent the loss of sediment during the coring process, but some core top samples >6000 14C yr B.P. may represent little or no Holocene deposition. Four possible sources of variability in dates ≤6000 14C yr B.P. (n = 28) are associated with (1) different sample preparation methods, (2) different sediment recovery systems, (3) different geographic regions, and (4) within-sample lateral age variability. Statistical analysis on an a posteriori design indicates that geographic area is the major cause of variability; there is a difference in mean surface sediment age of nearly 2000 yr between sites in the western Ross Sea and sites east of Ross Bank in south-central Ross Sea. The systematic variability in surface age between areas may be attributed to: (a) variable sediment accumulation rates (SAR) (surface age is inversely related to SAR), (b) differences in the percentage of reworked (dead) carbon between each area, and/or (c) differences in the CO2 exchange between the ocean and the atmosphere.

Automated Measurement for Sensitivity Analysis of Runoff-Sediment Load at Varying Surface Gradients

Directory of Open Access Journals (Sweden)

Imanogor P.A.

2015-07-01

Full Text Available Direct measurement of surface runoff is often associated with errors and inaccuracies which results to unreliable hydrological data. An automatic Runoff-meter using tipping buckets arrangement calibrated to tip 0.14 liter of runoff water per tip with an accuracy of ± 0.001 litre was used to measure surface runoff from a steel bounded soil tray of dimension (1200 mm X 900 mm X 260 mm filled with sand loamy to the depth of 130 mm and inclined at angle (0 0 , 5 0 ,12 0 and 15 0 horizontal to the instrument. The effect of varying angles of inclination on runoff intensity, sediment loss rate and sediment loss is significant at 5 % confidence level, while surface runoff is not significant at 5 % confidence level. Total highest sediment loss of 458.2 g and 313.4 g were observed at angle 15 0 and 12 0 respectively. Total surface runoff of 361.5 mm and 445.8 mm were generated at inclined angle of 0 0 and 5 0 , while at angle 12 0 and 15 0 , 564.3 mm and 590.0 mm of surface runoff were generated. In addition, runoff intensity and sediment loss rate were highest at angle 15 0 , while the lowest values of 1.5mm/min and 5.43 g/min were obtained at angle of inclination 5 0 . The results showed that strong relationship existed among the hydrological variables as a result of subjecting the steel bounded soil tray to different angles of inclination. Such results would provide useful data for the running of physics-based deterministic model of surface runoff and erosion which will be useful for the design of hydrological structures, land use planning and management.

Identification of trophic interactions within an estuarine food web (northern New Zealand) using fatty acid biomarkers and stable isotopes

Science.gov (United States)

Alfaro, Andrea C.; Thomas, François; Sergent, Luce; Duxbury, Mark

2006-10-01

Fatty acid biomarkers and stable isotope signatures were used to identify the trophic dynamics of a mangrove/seagrass estuarine food web at Matapouri, northern New Zealand. Specific fatty acids were used to identify the preferred food sources (i.e., mangroves, seagrass, phytoplankton, macroalgae, bacteria, and zooplankton) of dominant fauna (i.e., filter feeders, grazing snails, scavenger/predatory snails, shrimp, crabs, and fish), and their presence in water and sediment samples throughout the estuary. The diets of filter feeders were found to be dominated by dinoflagellates, whereas grazers showed a higher diatom contribution. Bacteria associated with organic debris on surface sediments and brown algal ( Hormosira banksii) material in the form of suspended organic matter also accounted for a high proportion of most animal diets. Animals within higher trophic levels had diverse fatty acid profiles, revealing their varied feeding strategies and carbon sources. The stable isotope (δ 13C and δ 15N) analyses of major primary producers and consumers/predators revealed a trend of 15N enrichment with increasing trophic level, while δ 13C values provided a generally good description of carbon flow through the food web. Overall results from both fatty acid profiles and stable isotopes indicate that a variety of carbon sources with a range of trophic pathways typify this food web. Moreover, none of the animals studied was dependent on a single food source. This study is the first to use a comprehensive fatty acid biomarker and stable isotope approach to investigate the food web dynamics within a New Zealand temperate mangrove/seagrass estuary. This quantitative research may contribute to the currently developing management strategies for estuaries in northern New Zealand, especially for those perceived to have expanding mangrove fringes.

Sorption processes affecting arsenic solubility in oxidized surface sediments from Tulare Lake Bed, California

Science.gov (United States)

Gao, S.; Goldberg, S.; Herbel, M.J.; Chalmers, A.T.; Fujii, R.; Tanji, K.K.

2006-01-01

Elevated concentrations of arsenic (As) in shallow groundwater in Tulare Basin pose an environmental risk because of the carcinogenic properties of As and the potential for its migration to deep aquifers that could serve as a future drinking water source. Adsorption and desorption are hypothesized to be the major processes controlling As solubility in oxidized surface sediments where arsenate [As(V)] is dominant. This study examined the relationship between sorption processes and arsenic solubility in shallow sediments from the dry Tulare Lake bed by determining sorption isotherms, pH effect on solubility, and desorption-readsorption behavior (hysteresis), and by using a surface complexation model to describe sorption. The sediments showed a high capacity to adsorb As(V). Estimates of the maximum adsorption capacity were 92 mg As kg- 1 at pH 7.5 and 70 mg As kg- 1 at pH 8.5 obtained using the Langmuir adsorption isotherm. Soluble arsenic [> 97% As(V)] did not increase dramatically until above pH 10. In the native pH range (7.5-8.5), soluble As concentrations were close to the lowest, indicating that As was strongly retained on the sediment. A surface complexation model, the constant capacitance model, was able to provide a simultaneous fit to both adsorption isotherms (pH 7.5 and 8.5) and the adsorption envelope (pH effect on soluble As), although the data ranges are one order of magnitude different. A hysteresis phenomenon between As adsorbed on the sediment and As in solution phase was observed in the desorption-readsorption processes and differs from conventional hysteresis observed in adsorption-desorption processes. The cause is most likely due to modification of adsorbent surfaces in sediment samples upon extensive extractions (or desorption). The significance of the hysteresis phenomenon in affecting As solubility and mobility may be better understood by further microscopic studies of As interaction mechanisms with sediments subjected to extensive leaching

Localised human impacts on the Harataonga coastal landscape, Great Barrier Island, northern New Zealand

International Nuclear Information System (INIS)

Horrocks, M.; Nichol, S.; Cockrem, J.; Shane, P.

2008-01-01

Here we present results of analyses of sediment profiles and cores, and coprolites, from Harataonga Bay, Great Barrier Island. Using a range of analyses (sedimentological, plant microfossils, parasitological, microbial, and steroids and myoglobin) we concentrate on human impact and reconstruction of the geomorphology and vegetation of the near-shore environments. Two different sub--environments are represented: dunes and alluvial plain. Dune instability coincides with a major increase in disturbance-related plants (especially ground ferns) as a result of forest clearance. The present form of much of the Harataonga dunes and the swamp at the eastern end of the bay is directly a result of human impact, no earlier than 737 ± 178 14 C yr BP. In the record from the alluvial plain of the main Harataonga watercourse, at the western end of the bay, it is difficult to clearly resolve sedimentary inputs that directly relate to human presence in this former tidal inlet that was open to storm surge and stream floods. The only exception is the slopewash materials forming the terrace surface, sediments of which bear pollen consistent with vegetation disturbance. The landforms are natural but the rate at which the tidal inlet was infilled to form a terrace was accelerated by human activity. The nature and timing of the localised human impacts at Harataonga are consistent with those observed elsewhere on Great Barrier Island and mainland New Zealand. Some of our techniques (e.g. bacteria, steroids) are newly applied to coprolites in New Zealand but none provided any useful information because of poor preservation. (author). 34 refs., 13 figs., 3 tabs

Occurrence and profiles of organic sun-blocking agents in surface waters and sediments in Japanese rivers and lakes

International Nuclear Information System (INIS)

Kameda, Yutaka; Kimura, Kumiko; Miyazaki, Motonobu

2011-01-01

Sun-blocking agents including eight UV filters (UVF) and 10 UV light stabilizers (UVLS) were measured in water and sediment collected from 22 rivers, four sewage treatment plant effluents (STPE) and three lakes in Japan. Total sun blocking agents levels ranged from N.D. to 4928 ng/L and from 2.0 to 3422 μg/kg dry wt in surface water and in sediment, respectively. Benzyl salicylate, benzophenone-3, 2-ethyl hexyl-4-methoxycinnamte (EHMC) and octyl salicylate were dominant in surface water receiving wastewater effluents and STPE, although UV-328, benzophenone and EHMC were dominant in other surface water except background sites. Three UVF and nine UVLS were observed from all sediment and their compositions showed similar patterns with UV-328 and UV-234 as the most prevalent compounds. Homosalate, octocrylene, UV-326, UV-327, UV-328 and UV-234 were significantly correlated with Galaxolide in sediments. Concentrations of UV-327 and UV-328 also had strong correlation between those of UV-326 in sediment. - Highlights: → Total sun-blocking agents levels ranged from N.D. to 4928 ng/L in surface water from 29 sampling sites. → The maximum concentration of total sun-blocking agents was 3422 μg/kg dry wt. in sediment. → Residential wastewaters and STPE were considered to be potential sources of UVLS in river and lakes. → Most of sun-blocking agents in sediment were significantly correlated with HHCB. → UV-326 had a strong linear correlation between UV-327 as well as UV-328 in all sediment. - Occurrence of eight UV filters and 10 UV light stabilizers in surface water and sediment were investigated and characterized their compositions in water and sediment.

Spatial distribution and source apportionment of PFASs in surface sediments from five lake regions, China

Science.gov (United States)

Qi, Yanjie; Huo, Shouliang; Xi, Beidou; Hu, Shibin; Zhang, Jingtian; He, Zhuoshi

2016-03-01

Perfluoroalkyl substances (PFASs) have been found in environment globally. However, studies on PFAS occurrence in sediments of lakes or reservoirs remain relatively scarce. In this study, two hundred and sixty-two surface sediment samples were collected from forty-eight lakes and two reservoirs all over China. Average PFAS concentrations in surface sediments from each lake or reservoir varied from 0.086 ng/g dw to 5.79 ng/g dw with an average of 1.15 ng/g dw. Among five lake regions, average PFAS concentrations for the lakes from Eastern Plain Region were the highest. Perfluorooctanoic acid, perfluoroundecanoic acid and perfluorooctane sulfonic acid (PFOS) were the predominant PFASs in surface sediments. The significant positive correlations between PFAS concentrations and total organic carbon, total nitrogen and total phosphorus contents in sediments revealed the influences of sedimentary characteristics on PFAS occurrence. A two-dimensional hierarchical cluster analysis heat map was depicted to analyze the possible origins of sediments and individual PFAS. The food-packaging, textile, electroplating, firefighting and semiconductor industry emission sources and the precious metals and coating industry emission sources were identified as the main sources by two receptor models, with contributions of 77.7 and 22.3% to the total concentrations of C4-C14- perfluoroalkyl carboxylic acids and PFOS, respectively.

Great differences in the critical erosion threshold between surface and subsurface sediments: A field investigation of an intertidal mudflat, Jiangsu, China

Science.gov (United States)

Shi, Benwei; Wang, Ya Ping; Wang, Li Hua; Li, Peng; Gao, Jianhua; Xing, Fei; Chen, Jing Dong

2018-06-01

Understanding of bottom sediment erodibility is necessary for the sustainable management and protection of coastlines, and is of great importance for numerical models of sediment dynamics and transport. To investigate the dependence of sediment erodibility on degree of consolidation, we measured turbidity, waves, tidal currents, intratidal bed-level changes, and sediment properties on an exposed macrotidal mudflat during a series of tidal cycles. We estimated the water content of surface sediments (in the uppermost 2 cm of sediment) and sub-surface sediments (at 2 cm below the sediment surface). Bed shear stress values due to currents (τc), waves (τw), and combined current-wave action (τcw) were calculated using a hydrodynamic model. In this study, we estimate the critical shear stress for erosion using two approaches and both of them give similar results. We found that the critical shear stress for erosion (τce) was 0.17-0.18 N/m2 in the uppermost 0-2 cm of sediment and 0.29 N/m2 in sub-surface sediment layers (depth, 2 cm), as determined by time series of τcw values and intratidal bed-level changes, and values of τce, obtained using the water content of bottom sediments, were 0.16 N/m2 in the uppermost 2 cm and 0.28 N/m2 in the sub-surface (depth, 2 cm) sediment. These results indicate that the value of τce for sub-surface sediments (depth, 2 cm) is much greater than that for the uppermost sediments (depth, 0-2 cm), and that the τce value is mainly related to the water content, which is determined by the extent of consolidation. Our results have implications for improving the predictive accuracy of models of sediment transport and morphological evolution, by introducing variable τce values for corresponding sediment layers, and can also provide a mechanistic understanding of bottom sediment erodibility at different sediment depths on intertidal mudflats, as related to differences in the consolidation time.

Application of a surface complexation model to the interactions of Pu and Am with Esk Estuary sediments

International Nuclear Information System (INIS)

Turner, D.R.; Knox, S.; Titley, J.G.; Hamilton-Taylor, J.; Kelly, M.; Williams, G.

1990-10-01

Previous work has shown that Pu is remobilised from Esk sediments at low salinities of overlying water. A constant capacitance surface complexation model has been developed in order to understand and model the chemical processes occurring. The model is based on detailed chemical characterisation of sediment samples from the estuary. The following measurements were carried out to provide input parameters for the model: specific surface area; total surface sites (tritium exchange); proton and major ion exchange (potentiometric titration); and actinide (Pu and Am) partition coefficient as a function of pH and salinity at sediment and actinide concentrations typical of the Esk. (author)

Conditions affecting the release of phosphorus from surface lake sediments.

Science.gov (United States)

Christophoridis, Christophoros; Fytianos, Konstantinos

2006-01-01

Laboratory studies were conducted to determine the effect of pH and redox conditions, as well as the effect of Fe, Mn, Ca, Al, and organic matter, on the release of ortho-phosphates in lake sediments taken from Lakes Koronia and Volvi (Northern Greece). Results were evaluated in combination with experiments to determine P fractionation in the sediment. The study revealed the major effect of redox potential and pH on the release of P from lake sediments. Both lakes showed increased release rates under reductive conditions and high pH values. The fractionation experiments revealed increased mobility of the reductive P fraction as well as of the NaOH-P fraction, indicating participation of both fractions in the overall release of sediment-bound P, depending on the prevailing environmental conditions. The results were assessed in combination with the release patterns of Fe, Mn, Ca, Al, and organic matter, enabling the identification of more specific processes of P release for each lake. The basic release patterns included the redox induced reductive dissolution of P-bearing metal oxides and the competitive exchange of phosphate anions with OH- at high pH values. The formation of an oxidized surface microlayer under oxic conditions acted as a protective film, preventing further P release from the sediments of Lake Volvi, while sediments from Lake Koronia exhibited a continuous and increased tendency to release P under various physicochemical conditions, acting as a constant source of internal P loading.

Analysis of Heavy Metals in Surface Sediments from Agh Gel Wetland, Iran

Directory of Open Access Journals (Sweden)

Soheil Sobhanardakani

2016-06-01

Full Text Available Background: Soil and sediment serve as major reservoir for contaminants as they possess ability to bind various chemicals together. In this study the concentrations of heavy metals Cd, Cr and Cu were analyzed in surface sediments of Agh Gel Wetland in west of Iran. Methods: The sediment samples were taken from 10 stations. The samples were subjected to bulk digestion and chemical partitioning and Cd, Cr and Cu concentrations of the sediments were determined by ICP-OES. Geo-accumulation index (I-geo, Contamination factor (CF and Pollution load index (PLI were used to evaluate the magnitude of contaminants in the sediment profile. Results: The mean sediment concentrations (mg kg-1 dry weight ranged within 0.20-0.29 (Cd, 58-71 (Cr and 23-36 (Cu. According to the I-geo values, the sediments' qualities are classified as unpolluted to moderately polluted category. According to the CF values, the sediments' qualities are classified as low to moderate contamination. Furthermore, the PLI values indicated that there were no metal pollution exists for all sampling stations. Conclusion: The Agh Gel Wetland is potential to be threatened by chemical pollutants such as agricultural effluent. So to preserve the environment of the Agh Gel Wetland from deterioration, periodically monitoring of the water and sediment qualities is recommended.

Mathematical simulation of sediment and contaminant transport in surface waters. Annual report, October 1977--September 1978

International Nuclear Information System (INIS)

Onishi, Y.; Arnold, E.M.; Serne, R.J.; Cowan, C.E.; Thompson, F.L.; Mayer, D.W.

1979-01-01

Various pathways exist for exposure of humans and biota to radioactive materials released from nuclear facilities. Hydrologic transport (liquid pathway) is one element in the evaluation of the total radiation dose to man. Mathematical models supported by well-planned field data collection programs can be useful tools in assessing the hydrologic transport and ultimate fate of radionuclides. Radionuclides with high distribution coefficients or radionuclides in surface waters with high suspended sediment concentrations are, to a great extent, adsorbed by river and marine sediments. Thus, otherwise dilute contaminants are concentrated. Contaminated sediments may be deposited on the river and ocean beds creating a significant pathway to man. Contaminated bed sediment in turn may become a long-term source of pollution through desorption and resuspension. In order to assess migration and accumulation of radionuclides in surface waters, mathematical models must correctly simulate essential mechanisms of radionuclide transport. The objectives of this study were: (1) to conduct a critical review of (a) radionuclide transport models as well as sediment transport and representative water quality models in rivers, estuaries, oceans, lakes, and reservoirs, and (b) adsorption and desorption mechanisms of radionuclides with sediments in surface waters; (2) to synthesize a mathematical model capable of predicting short- and long-term transport and accumulation of radionuclides in marine environments

A paleoenvironmental study of subsurface Quaternary sediments at Wainuiomata, Wellington, New Zealand, and tectonic implications

Energy Technology Data Exchange (ETDEWEB)

Begg, J G; Mildenhall, D C; Lyon, G L; Stephenson, W R; Funnell, R H; Van Dissen, R J; Bannister, S; Brown, L J [Institute of Geological and Nuclear Sciences Ltd., Lower Hutt (New Zealand); Pillans, B; Harper, M A [Research School of Earth Sciences, Victoria University of Wellington, Wellington (New Zealand); Whitton, J [Manaaki Whenua - Landcare Research, Lower Hutt, (New Zealand)

1994-12-31

A stratigraphic drillhole (WS-1) sited on the floor of Wainuiomata Valley near Lower Hutt, revealed a 61.6 m thick Quaternary sequence overlying Torlesse Supergroup greywacke sandstone and argillite. The Quaternary sediments consist of three sequences separated by disconformities. The lower sequence, 10.7 m thick (61.6-50.9 m), consists of fluvial sediments of probable early Quaternary age. The middle sequence, about 48.3 m in thickness (50.9-c. 2.6 m), spans most of the Last Glaciation. Fluvial/overbnak (50.9-42.0 m), floodplain/swamp (42.9-34.5 m), and fluvial (34.5-31.3 m) sediments overlie the disconformity at 50.9 m. Conformably overlying these sediments are swamp and lacustrine deposits between 31.3 and 4.1 m. Diatoms and algal spores and coenobia show the existence of an extensive lake during much of this sequence, from 25.6 to 4.0 m. at the peak of its development, at a drillhole depth of c. 23 m, the lake was >10 m deep and had a high algal biomass. Kawakawa Tephra (22 600 yr b.p.) occurs near the top of the middle sequence at 4.1 m depth. The upper sequence, of Holocene-Recent age, is <2.6 m thick, including .06 m of fill. The existence of sediments of the lower sequence of at least Castlecliffian age (early Pleistocene) uncomformably overlying basement greywacke provides a minimum age for the K-surface in the area. The Last Glacial sediments show evidence of ponfing, which may be a result of one factor or a more of the following: ponding behind an aggradational terrace of the Wainuiomata River; landslide blockage of the Black Stream drainage near its confluence with Wainuiomata River; and tectonic deformation. Progressive tectonic deformation since the start of the Last Glaciation is considered the most likely dominant factor. This has resulted in the elevation of greywacke basement near the junction of Black Stream and Wainuiomata River. The nature of the deformation - faulting, tilting, and/or folding - has not been established. 38 refs,6 figs,2 tables.

A paleoenvironmental study of subsurface Quaternary sediments at Wainuiomata, Wellington, New Zealand, and tectonic implications

International Nuclear Information System (INIS)

Begg, J.G.; Mildenhall, D.C.; Lyon, G.L.; Stephenson, W.R.; Funnell, R.H.; Van Dissen, R.J.; Bannister, S.; Brown, L.J.; Pillans, B.; Harper, M.A.; Whitton, J.

1993-01-01

A stratigraphic drillhole (WS-1) sited on the floor of Wainuiomata Valley near Lower Hutt, revealed a 61.6 m thick Quaternary sequence overlying Torlesse Supergroup greywacke sandstone and argillite. The Quaternary sediments consist of three sequences separated by disconformities. The lower sequence, 10.7 m thick (61.6-50.9 m), consists of fluvial sediments of probable early Quaternary age. The middle sequence, about 48.3 m in thickness (50.9-c. 2.6 m), spans most of the Last Glaciation. Fluvial/overbnak (50.9-42.0 m), floodplain/swamp (42.9-34.5 m), and fluvial (34.5-31.3 m) sediments overlie the disconformity at 50.9 m. Conformably overlying these sediments are swamp and lacustrine deposits between 31.3 and 4.1 m. Diatoms and algal spores and coenobia show the existence of an extensive lake during much of this sequence, from 25.6 to 4.0 m. at the peak of its development, at a drillhole depth of c. 23 m, the lake was >10 m deep and had a high algal biomass. Kawakawa Tephra (22 600 yr b.p.) occurs near the top of the middle sequence at 4.1 m depth. The upper sequence, of Holocene-Recent age, is <2.6 m thick, including .06 m of fill. The existence of sediments of the lower sequence of at least Castlecliffian age (early Pleistocene) uncomformably overlying basement greywacke provides a minimum age for the K-surface in the area. The Last Glacial sediments show evidence of ponfing, which may be a result of one factor or a combination of the following: ponding behind an aggradational terrace of the Wainuiomata River; landslide blockage of the Black Stream drainage near its confluence with Wainuiomata River; and tectonic deformation. Progressive tectonic deformation since about the start of the Last Glaciation is considered the most likely dominant factor. This has resulted in the elevation of greywacke basement near the junction of Black Stream and Wainuiomata River. The nature of the deformation - faulting, tilting, and/or folding - has not been established. (authors

Vertical migration of fine-grained sediments from interior to surface of seabed driven by seepage flows-`sub-bottom sediment pump action'

Science.gov (United States)

Zhang, Shaotong; Jia, Yonggang; Wen, Mingzheng; Wang, Zhenhao; Zhang, Yaqi; Zhu, Chaoqi; Li, Bowen; Liu, Xiaolei

2017-02-01

A scientific hypothesis is proposed and preliminarily verified in this paper: under the driving of seepage flows, there might be a vertical migration of fine-grained soil particles from interior to surface of seabed, which is defined as `sub-bottom sediment pump action' in this paper. Field experiments were performed twice on the intertidal flat of the Yellow River delta to study this process via both trapping the pumped materials and recording the pore pressures in the substrate. Experimental results are quite interesting as we did observe yellow slurry which is mainly composed of fine-grained soil particles appearing on the seabed surface; seepage gradients were also detected in the intertidal flat, under the action of tides and small wind waves. Preliminary conclusions are that `sediment pump' occurs when seepage force exceeds a certain threshold: firstly, it is big enough to disconnect the soil particles from the soil skeleton; secondly, the degree of seabed fluidization or bioturbation is big enough to provide preferred paths for the detached materials to migrate upwards. Then they would be firstly pumped from interior to the surface of seabed and then easily re-suspended into overlying water column. Influential factors of `sediment pump' are determined as hydrodynamics (wave energy), degree of consolidation, index of bioturbation (permeability) and content of fine-grained materials (sedimentary age). This new perspective of `sediment pump' may provide some implications for the mechanism interpretation of several unclear geological phenomena in the Yellow River delta area.

Entrapped Sediments as a Source of Phosphorus in Epilithic Cyanobacterial Proliferations in Low Nutrient Rivers

Science.gov (United States)

Wood, Susanna A.; Depree, Craig; Brown, Logan; McAllister, Tara; Hawes, Ian

2015-01-01

Proliferations of the benthic mat-forming cyanobacteria Phormidium have been reported in rivers worldwide. Phormidium commonly produces natural toxins which pose a health risk to animal and humans. Recent field studies in New Zealand identified that sites with Phormidium proliferations consistently have low concentrations of water column dissolved reactive phosphorus (DRP). Unlike other river periphyton, Phormidium mats are thick and cohesive, with water and fine sediment trapped in a mucilaginous matrix. We hypothesized that daytime photosynthetic activity would elevate pH inside the mats, and/or night time respiration would reduce dissolved oxygen. Either condition could be sufficient to facilitate desorption of phosphates from sediment incorporated within mats, thus allowing Phormidium to utilize it for growth. Using microelectrodes, optodes and pulse amplitude modulation fluorometry we demonstrated that photosynthetic activity results in elevated pH (>9) during daytime, and that night-time respiration causes oxygen depletion (river water and this, together with elevated concentrations of elements, including iron, suggest phosphorus release from entrapped sediment. Sequential extraction of phosphorus from trapped sediment was used to investigate the role of sediment at sites on the Mangatainoka River (New Zealand) with and without Phormidium proliferations. Deposition of fine sediment (sediment can provide a source of phosphorus to support Phormidium growth and proliferation. PMID:26479491

Towards a climate event stratigraphy for New Zealand over the past 30,000 years

International Nuclear Information System (INIS)

Barrell, D.J.A.; Alloway, B.V.; Shulmeister, J.; Newnham, R.M.

2005-01-01

A poster summarizing a representative selection of evidence for environmental conditions and climate change in New Zealand during the last 30,000 years has been prepared as a 'first-step' contribution to the INTIMATE (INTegration of Ice-core, Marine and TerrEstrial records) initiative of the INQUA Paleoclimate Commission. This international initiative aims to establish a more detailed knowledge of the nature, timing and regional to global extent of climatic and environmental changes associated with the Last Termination. The poster depicts key New Zealand onshore and offshore records for the Last Glacial Maximum and the Last Glacial-Interglacial Transition, from a variety of latitudes and elevations. Inset maps show New Zealand's oceanographic setting, principal currents and water masses, extent of glaciers, and distribution of vegetation zones at approximately 22,000 calendar years ago and at modern times (incorporating the inferred vegetation distribution at c. 1250 AD, before deforestation associated with human settlement). A calendar-age timescale is based on a combination of volcanic ash (tephra) and radiometric dates. Paleoclimate records from ice cores from Antarctica and Greenland are presented for comparison with New Zealand records. High-resolution records are presented for sediment-filled volcanic craters in Auckland (total carbon, carbon isotopes and pollen), wetlands in northeast North Island, central North Island and western South Island (pollen), marine sediments off eastern North Island (oxygen isotopes), and stalagmites in caves in northwest South Island (carbon and oxygen isotopes). In addition, the poster includes a range of lower resolution or fragmentary records of climate events, based on glacial landforms and deposits (central Southern Alps, South Island), river terraces and deposits, loess deposits (eastern North and South Islands), and Aeolian quartz silt in non-quartzose, loess-like, andesitic tephric deposits of western North Island. The

CoBOP: Microbial Biofilms: A Parameter Altering the Apparent Optical Properties of Sediments, Seagrasses and Surfaces

Science.gov (United States)

2002-09-30

CoBOP: Microbial Biofilms: A Parameter Altering the Apparent Optical Properties of Sediments, Seagrasses and Surfaces Alan W. Decho Department...TITLE AND SUBTITLE CoBOP: Microbial Biofilms: A Parameter Altering the Apparent Optical Properties of Sediments, Seagrasses and Surfaces 5a. CONTRACT...structures produced by bacteria. Their growth appears to depend on biofilm processes and light distributions ( photosynthesis ). Therefore, the data acquired

Surface sediment remobilization triggered by earthquakes in the Nankai forearc region

Science.gov (United States)

Okutsu, N.; Ashi, J.; Yamaguchi, A.; Irino, T.; Ikehara, K.; Kanamatsu, T.; Suganuma, Y.; Murayama, M.

2017-12-01

Submarine landslides triggered by earthquakes generate turbidity currents (e.g. Piper et al., 1988; 1999). Recently several studies report that the remobilization of the surface sediment triggered by earthquakes can also generate turbidity currents. However, studies that proposed such process are still limited (e.g. Ikehara et al., 2016; Mchugh et al., 2016; Moernaut et al., 2017). The purpose of this study is to examine those sedimentary processes in the Nankai forearc region, SW Japan using sedimentary records. We collected 46 cm-long multiple core (MC01) and a 6.7 m-long piston core (PC03) from the small basin during the R/V Shinsei Maru KS-14-8 cruise. The small confined basin, which is our study site, block the paths of direct sediment supply from river-submarine canyon system. The sampling site is located at the ENE-WSW elongated basin between the accretionary prism and the forearc basin off Kumano without direct sediment supply from river-submarine canyon system. The basin exhibits a confined basin that captures almost of sediments supplied from outside. Core samples are mainly composed of silty clay or very fine sand. Cs-137 measurement conducted on a MC01 core shows constantly high value at the upper 17 cm section and no detection below it. Moreover, the sedimentary structure is similar to fine-grained turbidite described by Stow and Shanmgam (1980), we interpret the upper 17 cm of MC01 as muddy turbidite. Grain size distribution and magnetic susceptibility also agree to this interpretation. Rapid sediment deposition after 1950 is assumed and the most likely event is the 2004 off Kii peninsula earthquakes (Mw=6.6-7.4). By calculation from extent of provenance area, which are estimated by paleocurrent analysis and bathymetric map, and thickness of turbidite layer we conclude that surface 1 cm of slope sediments may be remobilized by the 2004 earthquakes. Muddy turbidites are also identified in a PC03 core. The radiocarbon age gap of 170 years obtained

Environmental assessment of coastal surface sediments at Tarut Island, Arabian Gulf (Saudi Arabia)

International Nuclear Information System (INIS)

Youssef, Mohamed; El-Sorogy, Abdelbaset; Al Kahtany, Khaled; Al Otiaby, Naif

2015-01-01

Highlights: • The present work deal with the environmental assessment of Tarut Island Coastal area. • Thirty eight surface sediments samples have been chemically analyzed. • Thirteen major and trace metals have been recorded. • The area of study is highly polluted with Arsenic and Mercury. - Abstract: Thirty eight surface sediments samples have been collected in the area around Tarut Island, Saudi Arabian Gulf to determine the spatial distribution of metals, and to assess the magnitude of pollution. Total concentrations of Fe, Mn, As, B, Cd, Co, Cr, Cu, Hg, Mo, Pb, Se, and Zn in the sediments were measured using ICP-MS (Inductively Coupled Plasma-Mass Spectrometer). Nature of sediments and heavy metals distribution reflect marked changes in lithology, biological activities in Tarut bay. Very high arsenic concentrations were reported in all studied locations from Tarut Island. The concentrations of Mercury are generally high comparing to the reported values from the Gulf of Oman, Red Sea. The concentrations of As and Hg exceeded the wet threshold safety values (MEC, PEC) indicating possible As and Hg contamination. Dredging and land filling, sewage, and oil pollution are the most important sources of pollution in the study area

Pesticides distribution in surface waters and sediments of lotic and ...

African Journals Online (AJOL)

An investigation on the availability and distribution of Lindane (HCHs) and Total organochlorine phosphate (TOCP) in the surface waters and sediments of selected water bodies in Agbede wetlands was carried out from December, 2012 to May, 2014 in order to cover seasonal trends in both matrixes. A Gas Chromatograph ...

PBDD/Fs in surface sediments from the East River, China.

Science.gov (United States)

Ren, M; Peng, P A; Chen, D Y; Chen, P; Zhou, L

2009-09-01

The contamination status of polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) was preliminarily investigated in surface sediments from the East River. The concentrations of eight 2,3,7,8-substituted tetra- to hexa- PBDD/Fs were found to be in the range of 0.32-110 (mean 13) pg g(-1) and the corresponding TEQ concentrations were 0.087-18 (mean 2) pg I-TEQ g(-1). All sediments were characterized by the dominant PBDFs. 2,3,4,7,8-PeBDF was the most important TEQ contributor, accounting for 47%-77% of the total I-TEQ of PBDD/Fs. PCDD/Fs contributed dominantly to the total TEQs of PCDD/Fs, PBDD/Fs and dioxin-like PCBs in most samples except of the sediment from the Shima River. The higher PBDD/F concentrations in the Shima River may be attributed to the use of BFRs in the electrical and electronics industries, which posed a potential risk of dioxins on ecological system.

Patterns and drivers of bacterial α- and β-diversity across vertical profiles from surface to subsurface sediments.

Science.gov (United States)

Luna, Gian Marco; Corinaldesi, Cinzia; Rastelli, Eugenio; Danovaro, Roberto

2013-10-01

We investigated the patterns and drivers of bacterial α- and β-diversity, along with viral and prokaryotic abundance and the carbon production rates, in marine surface and subsurface sediments (down to 1 m depth) in two habitats: vegetated sediments (seagrass meadow) and non-vegetated sediments. Prokaryotic abundance and production decreased with depth in the sediment, but cell-specific production rates and the virus-to-prokaryote ratio increased, highlighting unexpectedly high activity in the subsurface. The highest diversity was observed in vegetated sediments. Bacterial β-diversity between sediment horizons was high, and only a minor number of taxa was shared between surface and subsurface layers. Viruses significantly contributed to explain α- and β-diversity patterns. Despite potential limitations due to the only use of fingerprinting techniques, this study indicates that the coastal subsurface host highly active and diversified bacterial assemblages, that subsurface cells are more active than expected and that viruses promote β-diversity and stimulate bacterial metabolism in subsurface layers. The limited number of taxa shared between habitats, and between surface and subsurface sediment horizons, suggests that future investigations of the shallow subsurface will provide insights into the census of bacterial diversity, and the comprehension of the patterns and drivers of prokaryotic diversity in marine ecosystems. © 2013 John Wiley & Sons Ltd and Society for Applied Microbiology.

Sedimentology and geochemistry of surface sediments, outer continental shelf, southern Bering Sea

Science.gov (United States)

Gardner, J.V.; Dean, W.E.; Vallier, T.L.

1980-01-01

Islands and the outer continental shelf and slope, indicates that Holocene sediment dynamics cannot be used to explain the observed distribution of surface sediment derived from the Aleutian Islands. We suggest that this pattern is relict and resulted from sediment dynamics during lower sea levels of the Pleistocene. ?? 1980.

Nonlinear Changes in Land Cover and Sediment Runoff in a New Zealand Catchment Dominated by Plantation Forestry and Livestock Grazing

Directory of Open Access Journals (Sweden)

Ioannis Kamarinas

2016-10-01

Full Text Available Land cover can change frequently on intensively managed landscapes, affecting water quality across different spatiotemporal scales. Multi-resolution datasets are necessary in order to assess the extent and trends of these changes, as well as potential cross-scale interactions. In this study, both spatial and temporal analyses of land disturbance (i.e., soil exposure from vegetation removal and water quality were performed on datasets ranging from daily to yearly time scales. Time-series analyses of land disturbance were compared against the water quality variables of total suspended solids (TSS, turbidity, and visual clarity for the Hoteo River catchment on the North Island of New Zealand for the 2000–2013 period. During forest harvest and recovery phases, exotic forests were the dominant disturbance, up to five times the area of grassland disturbance; while after recovery, grasslands assumed the dominant role, for up to 16 times the area of forest disturbance. Time-series of TSS from field sampling (2000–2013 and TSS-event analyses (2012–2014 displayed distinct nonlinear patterns, suggesting that after major events, sediment that is stored in the landscape is exhausted and a period of sediment build-up follows until the next major event. Time-series analyses also showed a connection between trends in connected land disturbance and visual water clarity, with connected disturbance having the potential to be a water quality indicator. Future research should be conducted at even finer spatiotemporal scales over longer periods in order to identify effects of localized land disturbances on downstream water quality.

GPS based surface displacements – a proxy for discharge and sediment transport from the Greenland Ice Sheet

DEFF Research Database (Denmark)

Hasholt, Bent; Khan, Shfaqat Abbas; Mikkelsen, Andreas Bech

2014-01-01

winter precipitation correlated fairly well with surface depression (R2=0.69). The relationships are based on seven years of runoff and sediment transport observations from the Watson River (2007–2013), winter precipitation from Kangerlussuaq Airport and GPS observations at Kellyville. GPS recordings...... of surface subsidence and uplift from 1996–2013 are used to calculate 18 years time series of annual runoff, sediment and solute transport and 10 winter precipitation. Runoff and related transport of sediment and solutes increase over the period, while winter precipitation (land depression) tends to decrease......The elastic respond of the Earth’s surface to mass changes has been measured with Global Positioning System (GPS). Mass loss as accumulated runoff and sediment transport from a 10000 km2 segment of the Greenland Ice Sheet (GrIS) correlated very well (R2=0.83) with GPS measured uplift. Accumulated...

E. coli Surface Properties Differ between Stream Water and Sediment Environments

Directory of Open Access Journals (Sweden)

Xiao Liang

2016-11-01

Full Text Available The importance of E. coli as an indicator organism in fresh water has led to numerous studies focusing on cell properties and transport behavior. However, previous studies have been unable to assess if differences in E. coli cell surface properties and genomic variation are associated with different environmental habitats. In this study, we investigated the variation in characteristics of E. coli obtained from stream water and stream bottom sediments. Cell properties were measured for 77 genomically different E. coli strains (44 strains isolated from sediments and 33 strains isolated from water under common stream conditions in the Upper Midwestern United States: pH 8.0, ionic strength 10mM and 22˚C. Measured cell properties include hydrophobicity, zeta potential, net charge, total acidity and extracellular polymeric substance (EPS composition. Our results indicate that stream sediment E. coli had significantly greater hydrophobicity, greater EPS protein content and EPS sugar content, less negative net charge, and higher point of zero charge than stream water E. coli. A significant positive correlation was observed between hydrophobicity and EPS protein for stream sediment E. coli but not for stream water E. coli. Additionally, E. coli surviving in the same habitat tended to have significantly larger (GTG5 genome similarity. After accounting for the intrinsic impact from the genome, environmental habitat was determined to be a factor influencing some cell surface properties, such as hydrophobicity. The diversity of cell properties and its resulting impact on particle interactions should be considered for environmental fate and transport modeling of aquatic indicator organisms such as E. coli.

E. coli Surface Properties Differ between Stream Water and Sediment Environments.

Science.gov (United States)

Liang, Xiao; Liao, Chunyu; Thompson, Michael L; Soupir, Michelle L; Jarboe, Laura R; Dixon, Philip M

2016-01-01

The importance of E. coli as an indicator organism in fresh water has led to numerous studies focusing on cell properties and transport behavior. However, previous studies have been unable to assess if differences in E. coli cell surface properties and genomic variation are associated with different environmental habitats. In this study, we investigated the variation in characteristics of E. coli obtained from stream water and stream bottom sediments. Cell properties were measured for 77 genomically different E. coli strains (44 strains isolated from sediments and 33 strains isolated from water) under common stream conditions in the Upper Midwestern United States: pH 8.0, ionic strength 10 mM and 22°C. Measured cell properties include hydrophobicity, zeta potential, net charge, total acidity, and extracellular polymeric substance (EPS) composition. Our results indicate that stream sediment E. coli had significantly greater hydrophobicity, greater EPS protein content and EPS sugar content, less negative net charge, and higher point of zero charge than stream water E. coli . A significant positive correlation was observed between hydrophobicity and EPS protein for stream sediment E. coli but not for stream water E. coli . Additionally, E. coli surviving in the same habitat tended to have significantly larger (GTG) 5 genome similarity. After accounting for the intrinsic impact from the genome, environmental habitat was determined to be a factor influencing some cell surface properties, such as hydrophobicity. The diversity of cell properties and its resulting impact on particle interactions should be considered for environmental fate and transport modeling of aquatic indicator organisms such as E. coli .

Heavy metals pollution and pb isotopic signatures in surface sediments collected from Bohai Bay, North China.

Science.gov (United States)

Gao, Bo; Lu, Jin; Hao, Hong; Yin, Shuhua; Yu, Xiao; Wang, Qiwen; Sun, Ke

2014-01-01

To investigate the characteristics and potential sources of heavy metals pollution, surface sediments collected from Bohai Bay, North China, were analyzed for the selected metals (Cd, Cr, Cu, Ni, Pb, and Zn). The Geoaccumulation Index was used to assess the level of heavy metal pollution. Pb isotopic compositions in sediments were also measured to effectively identify the potential Pb sources. The results showed that the average concentrations of Cd, Cr, Cu, Ni, Pb, and Zn were 0.15, 79.73, 28.70, 36.56, 25.63, and 72.83 mg/kg, respectively. The mean concentrations of the studied metals were slightly higher than the background values. However, the heavy metals concentrations in surface sediments in Bohai Bay were below the other important bays or estuaries in China. The assessment by Geoaccumulation Index indicated that Cr, Zn, and Cd were classified as "the unpolluted" level, while Ni, Cu, and Pb were ranked as "unpolluted to moderately polluted" level. The order of pollution level of heavy metals was: Pb > Ni > Cu > Cr > Zn > Cd. The Pb isotopic ratios in surface sediments varied from 1.159 to 1.185 for (206)Pb/(207)Pb and from 2.456 to 2.482 for (208)Pb/(207)Pb. Compared with Pb isotopic radios in other sources, Pb contaminations in the surface sediments of Bohai Bay may be controlled by the mix process of coal combustion, aerosol particles deposition, and natural sources.

Evaluation of Near-Surface Gases in Marine Sediments to Assess Subsurface Petroleum Gas Generation and Entrapment

Directory of Open Access Journals (Sweden)

Michael A. Abrams

2017-05-01

Full Text Available Gases contained within near-surface marine sediments can be derived from multiple sources: shallow microbial activity, thermal cracking of organic matter and inorganic materials, or magmatic-mantle degassing. Each origin will display a distinctive hydrocarbon and non-hydrocarbon composition as well as compound-specific isotope signature and thus the interpretation of origin should be relatively straightforward. Unfortunately, this is not always the case due to in situ microbial alteration, non-equilibrium phase partitioning, mixing, and fractionation related to the gas extraction method. Sediment gases can reside in the interstitial spaces, bound to mineral or organic surfaces and/or entrapped in carbonate inclusions. The interstitial sediment gases are contained within the sediment pore space, either dissolved in the pore waters (solute or as free (vapour gas. The bound gases are believed to be attached to organic and/or mineral surfaces, entrapped in structured water or entrapped in authigenic carbonate inclusions. The purpose of this paper is to provide a review of the gas types found within shallow marine sediments and examine issues related to gas sampling and extraction. In addition, the paper will discuss how to recognise mixing, alteration and fractionation issues to best interpret the seabed geochemical results and determine gas origin to assess subsurface petroleum gas generation and entrapment.

Microplastics Baseline Surveys at the Water Surface and in Sediments of the North-East Atlantic

NARCIS (Netherlands)

Maes, Thomas; van der Meulen, Myra; Devriese, Lisa; Leslie, H.A.; Huvet, Arnaud; Frère, Laura; Robbens, Johan; Vethaak, A.D.

2017-01-01

Microplastic contamination was determined in sediments of the Southern North Sea and floating at the sea surface of NorthWest Europe. Floating concentrations ranged between 0 and 1.5 microplastic/m3, whereas microplastic concentrations in sediments ranged between 0 and 3,146 particles/kg dry weight

Modern sedimentation patterns in Lake El'gygytgyn, NE Russia, derived from surface sediment and inlet streams samples

Directory of Open Access Journals (Sweden)

V. Wennrich

2013-01-01

Full Text Available Lake El'gygytgyn/NE Russia holds a continuous 3.58 Ma sediment record, which is regarded as the most long-lasting climate archive of the terrestrial Arctic. Based on multi-proxy geochemical, mineralogical, and granulometric analyses of surface sediment, inlet stream and bedrock samples, supplemented by statistical methods, major processes influencing the modern sedimentation in the lake were investigated. Grain-size parameters and chemical elements linked to the input of feldspars from acidic bedrock indicate a wind-induced two-cell current system as major driver of sediment transport and accumulation processes in Lake El'gygytgyn. The distribution of mafic rock related elements in the sediment on the lake floor can be traced back to the input of weathering products of basaltic rocks in the catchment. Obvious similarities in the spatial variability of manganese and heavy metals indicate sorption or co-precipitation of these elements with Fe and Mn hydroxides and oxides. But the similar distribution of organic matter and clay contents might also point to a fixation to organic components and clay minerals. An enrichment of mercury in the inlet streams might be indicative of neotectonic activity around the lake. The results of this study add to the fundamental knowledge of the modern lake processes of Lake El'gygytgyn and its lake-catchment interactions, and thus, yield crucial insights for the interpretation of paleo-data from this unique archive.

Sediment plume response to surface melting and supraglacial lake drainages on the Greenland ice sheet

DEFF Research Database (Denmark)

Chu, Vena W.; Smith, Laurence C; Rennermalm, Asa K.

2009-01-01

) supraglacial lake drainage events from MODIS. Results confirm that the origin of the sediment plume is meltwater release from the ice sheet. Interannual variations in plume area reflect interannual variations in surface melting. Plumes appear almost immediately with seasonal surface-melt onset, provided...... the estuary is free of landfast sea ice. A seasonal hysteresis between melt extent and plume area suggests late-season exhaustion in sediment supply. Analysis of plume sensitivity to supraglacial events is less conclusive, with 69% of melt pulses and 38% of lake drainage events triggering an increase in plume...... area. We conclude that remote sensing of sediment plume behavior offers a novel tool for detecting the presence, timing and interannual variability of meltwater release from the ice sheet....

Targeting sediment management strategies using sediment quantification and fingerprinting methods

Science.gov (United States)

Sherriff, Sophie; Rowan, John; Fenton, Owen; Jordan, Phil; hUallacháin, Daire Ó.

2016-04-01

Cost-effective sediment management is required to reduce excessive delivery of fine sediment due to intensive land uses such as agriculture, resulting in the degradation of aquatic ecosystems. Prioritising measures to mitigate dominant sediment sources is, however, challenging, as sediment loss risk is spatially and temporally variable between and within catchments. Fluctuations in sediment supply from potential sources result from variations in land uses resulting in increased erodibility where ground cover is low (e.g., cultivated, poached and compacted soils), and physical catchment characteristics controlling hydrological connectivity and transport pathways (surface and/or sub-surface). Sediment fingerprinting is an evidence-based management tool to identify sources of in-stream sediments at the catchment scale. Potential sediment sources are related to a river sediment sample, comprising a mixture of source sediments, using natural physico-chemical characteristics (or 'tracers'), and contributions are statistically un-mixed. Suspended sediment data were collected over two years at the outlet of three intensive agricultural catchments (approximately 10 km2) in Ireland. Dominant catchment characteristics were grassland on poorly-drained soils, arable on well-drained soils and arable on moderately-drained soils. High-resolution (10-min) calibrated turbidity-based suspended sediment and discharge data were combined to quantify yield. In-stream sediment samples (for fingerprinting analysis) were collected at six to twelve week intervals, using time-integrated sediment samplers. Potential sources, including stream channel banks, ditches, arable and grassland field topsoils, damaged road verges and tracks were sampled, oven-dried (account for particle size and organic matter selectivity processes. Contributions from potential sources type groups (channel - ditches and stream banks, roads - road verges and tracks, fields - grassland and arable topsoils) were

Dating the past 7000 years of major earthquakes on the Alpine Fault, New Zealand

International Nuclear Information System (INIS)

Clark, KJ.; Biasi, G.

2009-01-01

The Alpine Fault, New Zealand, is a major plate boundary fault that accommodates two thirds of the motion between the Australian and Pacific plates. The Hokuri Stream locality at the southern end of the Alpine Fault has the potential to contain a long record of earthquakes. The field component of this study involved the description, measurement and sampling of multiple river bank outcrops of the Hokuri sedimentary sequence. Sampling was undertaken by two approaches: discrete sediment sampling and continuous push-core sampling. Radiocarbon samples were processed at the Rafter Radiocarbon Laboratory, New Zealand. 123 samples were dated and the most commonly dated organic fractions were individual leaves, reeds, and seeds. 15 refs., 6 figs.

Physical and Mechanical Properties of Surface Sediments and methane hydrate-bearing sediments in the Shenhu area of South China Sea

Science.gov (United States)

Jiang, J.; Shen, Z.; Jia, Y.

2017-12-01

Methane hydrates are superior energy resources and potential predisposing factors of geohazard. With the success in China's persistent exploitation of methane hydrates in the Shenhu area of South China Sea for 60 days, there is an increasing demand for detailed knowledge of sediment properties and hazard assessment in this area. In this paper, the physical and mechanical properties of both the surface sediments and methane hydrate-bearing sediments (MHBS) in the exploitation area, the Shenhu area of South China Sea, were investigated using laboratory geotechnical experiments, and triaxial tests were carried out on remolded sediment samples using a modified triaxial apparatus. The results show that sediments in this area are mainly silt with high moisture content, high plasticity, low permeability and low shear strength. The moisture content and permeability decrease while the shear strength increases with the increasing depth. The elastic modulus and peak strength of MHBS increase with the increasing effective confining pressure and higher hydrate saturation. The cohesion increases with higher hydrate saturation while the internal friction angle is barely affected by hydrate saturation. The obtained results demonstrate clearly that methane hydrates have significant impacts on the physical and mechanical properties of sediments and there is still a wide gap in knowledge about MHBS.

On the bioavailability of trace metals in surface sediments: a combined geochemical and biological approach.

Science.gov (United States)

Roosa, Stéphanie; Prygiel, Emilie; Lesven, Ludovic; Wattiez, Ruddy; Gillan, David; Ferrari, Benoît J D; Criquet, Justine; Billon, Gabriel

2016-06-01

The bioavailability of metals was estimated in three river sediments (Sensée, Scarpe, and Deûle Rivers) impacted by different levels of Cu, Cd, Pb, and Zn (Northern France). For that, a combination of geochemistry and biological responses (bacteria and chironomids) was used. The results obtained illustrate the complexity of the notion of "bioavailability." Indeed, geochemical indexes suggested a low toxicity, even in surface sediments with high concentrations of total metals and a predicted severe effect levels for the organisms. This was also suggested by the abundance of total bacteria as determined by DAPI counts, with high bacterial cell numbers even in contaminated areas. However, a fraction of metals may be bioavailable as it was shown for chironomid larvae which were able to accumulate an important quantity of metals in surface sediments within just a few days.We concluded that (1) the best approach to estimate bioavailability in the selected sediments is a combination of geochemical and biological approaches and that (2) the sediments in the Deûle and Scarpe Rivers are highly contaminated and may impact bacterial populations but also benthic invertebrates.

Aerobic biodegradation potential of endocrine disrupting chemicals in surface-water sediment at Rocky Mountains National Park, USA

Science.gov (United States)

Bradley, Paul M.; Battaglin, William A.; Iwanowicz, Luke R.; Clark, Jimmy M.; Journey, Celeste A.

2016-01-01

Endocrine disrupting chemicals (EDC) in surface water and bed sediment threaten the structure and function of aquatic ecosystems. In natural, remote, and protected surface-water environments where contaminant releases are sporadic, contaminant biodegradation is a fundamental driver of exposure concentration, timing, duration, and, thus, EDC ecological risk. Anthropogenic contaminants, including known and suspected EDC, were detected in surface water and sediment collected from 2 streams and 2 lakes in Rocky Mountains National Park (ROMO). The potential for aerobic EDC biodegradation was assessed in collected sediments using 6 14C-radiolabeled model compounds. Aerobic microbial mineralization of natural (estrone and 17β-estradiol) and synthetic (17α-ethinylestradiol) estrogen was significant at all sites. ROMO bed sediment microbial communities also effectively degraded the xenoestrogens, bisphenol-A and 4-nonylphenol. The same sediment samples exhibited little potential for aerobic biodegradation of triclocarban, however, illustrating the need to assess a wider range of contaminant compounds. The current results support recent concerns over the widespread environmental occurrence of carbanalide antibacterials, like triclocarban and triclosan, and suggest that backcountry use of products containing these compounds should be discouraged.

Environmental assessment of polycyclic aromatic hydrocarbons (PAHs) in surface sediments of the Santander Bay, Northern Spain.

Science.gov (United States)

Viguri, J; Verde, J; Irabien, A

2002-07-01

Samples of intertidal surface sediments (0-2 cm) were collected in 17 stations of the Santander Bay, Cantabric Sea, Northern Spain. The concentrations of polycyclic aromatic hydrocarbons (PAHs), 16, were analysed by HPLC and MS detection. Surface sediments show a good linear correlation among the parameters of the experimental organic matter evaluation, where total carbon (TC) and loss on ignition (LOI) are approximately 2.5 and 5 times total organic carbon (TOC). A wide range of TOC from 0.08% to 4.1%, and a broad distribution of the sum of sigma16PAHs, from 0.02 to 344.6 microg/g d.w., which can be correlated by an exponential equation to the TOC, has been identified. A qualitative relationship may be established between the industrial input along the rivers and the concentration of sigma6PAHs in the sediments of the estuaries: Boo estuary (8404-4631 microg/g OC), Solia-San Salvador estuaries (305-113 microg/g OC) and Cubas estuary (31-32 microg/g OC). This work shows a dramatic change in the spatial distribution in the concentration of PAHs of intertidal surface sediments. The left edge of the Bay has the main traffic around the city and the major source of PAHs is from combustion processes and estuarine inputs, leading to medium values of PAHs in the sediments; the right edge of the Bay has much lesser anthropogenic activities leading to lower values of PAHs in sediments. The distribution of individual PAHs in sediments varies widely depending on their structure and molecular weight; the 4-6 ring aromatics predominate in polluted sediments due to their higher persistence. The isomer ratio does not allow any clear identification of the PAHs origin. Environmental evaluation according to Dutch guidelines and consensus sediment quality guidelines based on ecotoxicological data leads to the same conclusion, sediments in the Santander Bay show a very different environmental quality depending on the spatial position from heavily polluted/medium effects to non

Sedimentological, mineralogical, and geochemical results from surface sediments and the sediment record from Site 2 of the ICDP drilling project at Lake Towuti, Indonesia

Science.gov (United States)

Hasberg, A. K.; Melles, M.; Wennrich, V.; Vogel, H.; Just, J.; Russell, J. M.; Bijaksana, S.; Morlock, M.; Opitz, S.

2017-12-01

More than 1000 m of sediment core were recovered in spring 2015 from three different drill sites in tropical Lake Towuti (2.5°S, 121°E), Indonesia, during the Towuti Drilling Project (TDP) of the International Continental Scientific Drilling Program (ICDP). Furthermore, a set of 84 lake surface sediment samples, distributed over the entire lake, was collected in order to better understand modern sedimentary processes. The surface samples were investigated for physical, chemical, mineralogical, and biological properties at the University of Cologne (UoC), Germany. On the sediment cores macro- and microscopical lithological descriptions, line-scan imaging, logging of physical properties (MSCL), and subsampling was conducted at the National Lacustrine Core Facility of the University of Minnesota, USA, in November 2015 and January 2016. Afterwards, the archive core halves and 672 subsamples of TDP Site 2 were shipped to the UoC for X-Ray Fluorescence (XRF) scanning and sedimentological, geochemical, and mineralogical analyses, respectively, supplemented by visible to near-infrared spectroscopy (VNIR) at Brown University, USA. The data from the surface samples evidence that allochthonous sedimentation in Lake Towuti today is dominated by fluvial supply from five distinguishable source areas: (i) the Mahalona River to the north, which drains lakes Mahalona and Matano, (ii) inlets around the village of Timampu to the northwest, (iii) the Loeha River to the east, (iv) the Lengke River to the south, and (v) the Lemo-Lemo River to the northeast of Lake Towuti. Of these, source areas (ii) and (iii) as well as (iv) and (v) have similar geochemical compositions, respectively. In addition, the lake sedimentation is significantly influenced by gravitational sediment supply from steep slopes as well as lake-internal gravitational and density-driven processes. The uppermost 41 m of sediment core 2A consist of pelagic sediments (totaling 11 m) and event layers from mass movement

Improving understanding of the underlying physical process of sediment wash-off from urban road surfaces

Science.gov (United States)

Muthusamy, Manoranjan; Tait, Simon; Schellart, Alma; Beg, Md Nazmul Azim; Carvalho, Rita F.; de Lima, João L. M. P.

2018-02-01

Among the urban aquatic pollutants, the most common is sediment which also acts as a transport medium for many contaminants. Hence there is an increasing interest in being able to better predict the sediment wash-off from urban surfaces. The exponential wash-off model is the most widely used method to predict the sediment wash-off. Although a number of studies proposed various modifications to the original exponential wash-off equation, these studies mostly looked into one parameter in isolation thereby ignoring the interactions between the parameters corresponding to rainfall, catchment and sediment characteristics. Hence in this study we aim (a) to investigate the effect of rainfall intensity, surface slope and initial load on wash-off load in an integrated and systematic way and (b) to subsequently improve the exponential wash-off equation focusing on the effect of the aforementioned three parameters. A series of laboratory experiments were carried out in a full-scale setup, comprising of a rainfall simulator, a 1 m2 bituminous road surface, and a continuous wash-off measuring system. Five rainfall intensities ranging from 33 to 155 mm/h, four slopes ranging from 2 to 16% and three initial loads ranging from 50 to 200 g/m2 were selected based on values obtained from the literature. Fine sediment with a size range of 300-600 μm was used for all of the tests. Each test was carried out for one hour with at least 9 wash-off samples per test collected. Mass balance checks were carried out for all the tests as a quality control measure to make sure that there is no significant loss of sand during the tests. Results show that the washed off sediment load at any given time is proportional to initial load for a given combination of rainfall intensity and surface slope. This indicates the importance of dedicated modelling of build-up so as to subsequently predict wash-off load. It was also observed that the maximum fraction that is washed off from the surface increases

Effects of farmhouse hotel and paper mill effluents on bacterial community structures in sediment and surface water of Nanxi River, China.

Science.gov (United States)

Lu, Xiao-Ming; Lu, Peng-Zhen

2014-11-01

The pyrosequencing technique was used to evaluate bacterial community structures in sediment and surface water samples taken from Nanxi River receiving effluents from a paper mill and a farmhouse hotel, respectively. For each sample, 4,610 effective bacterial sequences were selected and used to do the analysis of diversity and abundance, respectively. Bacterial phylotype richness in the sediment sample without effluent input was higher than the other samples, and the surface water sample with addition of effluent from the paper mill contained the least richness. Effluents from both the paper mill and farmhouse hotel have a potential to reduce the bacterial diversity and abundance in the sediment and surface water, especially it is more significant in the sediment. The effect of the paper mill effluent on the sediment and surface water bacterial communities was more serious than that of the farmhouse hotel effluent. Characterization of microbial community structures in the sediment and surface water from two tributaries of the downstream river indicated that various effluents from the paper mill and farmhouse hotel have the similar potential to decrease the natural variability in riverine microbial ecosystems.

Radiological impact of surface water and sediment near uranium mining sites.

Science.gov (United States)

Ivanova, K; Stojanovska, Z; Badulin, V; Kunovska, B; Yovcheva, M

2015-12-01

The aim of this study is to assess the radiological impact of surface water and sediment around uranium mining sites 20 years after their closing. The areas under observations are 31 former classical underground uranium mining and exploratory sites in Bulgaria, named as objects. The extraction and processing of uranium ores in the Republic of Bulgaria were ended in 1992. To assess the radiological impact of radionuclides field expeditions were performed to sample water and bottom sediment. The migration of uranium through surface water was examined as one of the major pathways for contamination spread. The range of uranium concentration in water flowing from the mining sites was from 0.012 to 6.8 mgU l(-1) with a geometric mean of 0.192 mgU l(-1). The uranium concentrations in water downstream the mining sites were approximately 3 times higher than the background value (upstream). The concentrations of Unat, (226)Ra, (210)Pb, and (232)Th in the sediment of downstream river were higher than those upstream by 3.4, 2.6, 2, and 1.7 times, respectively. The distribution coefficient of uranium reflects its high mobility in most of the sites. In order to evaluate the impact on people as well as site prioritization for more detailed assessment and water management, screening dose assessments were done.

Semi-automatic surface sediment sampling system - A prototype to be implemented in bivalve fishing surveys

Science.gov (United States)

Rufino, Marta M.; Baptista, Paulo; Pereira, Fábio; Gaspar, Miguel B.

2018-01-01

In the current work we propose a new method to sample surface sediment during bivalve fishing surveys. Fishing institutes all around the word carry out regular surveys with the aim of monitoring the stocks of commercial species. These surveys comprise often more than one hundred of sampling stations and cover large geographical areas. Although superficial sediment grain sizes are among the main drivers of benthic communities and provide crucial information for studies on coastal dynamics, overall there is a strong lack of this type of data, possibly, because traditional surface sediment sampling methods use grabs, that require considerable time and effort to be carried out on regular basis or on large areas. In face of these aspects, we developed an easy and un-expensive method to sample superficial sediments, during bivalve fisheries monitoring surveys, without increasing survey time or human resources. The method was successfully evaluated and validated during a typical bivalve survey carried out on the Northwest coast of Portugal, confirming that it had any interference with the survey objectives. Furthermore, the method was validated by collecting samples using a traditional Van Veen grabs (traditional method), which showed a similar grain size composition to the ones collected by the new method, on the same localities. We recommend that the procedure is implemented on regular bivalve fishing surveys, together with an image analysis system to analyse the collected samples. The new method will provide substantial quantity of data on surface sediment in coastal areas, using a non-expensive and efficient manner, with a high potential application in different fields of research.

Trends in total column ozone over Australia and New Zealand and its influence on clear-sky surface erythemal irradiance

International Nuclear Information System (INIS)

Bodeker, G. E.

1995-01-01

Australia and New Zealand are two of the countries closest to the Antarctic ozone depletion and may therefore be 'at risk' as a result of the associated increases in surface ultraviolet (UV) radiation. To investigate the possible impact of mid-latitude ozone decreases on surface erythemal irradiances, monthly mean total ozone has been calculated from daily total ozone mapping spectrometer data for 5 Australian cities (Canberra, Hobart, Melbourne, Perth and Sydney) and 3 New Zealand cities (Auckland, Christchurch and Wellington) from 1979 to 1992. These values have then been used as inputs to a single layer model to calculate noon clear-sky global UV irradiances and associated erythemal irradiances. In addition, the monthly mean ozone data have been modelled statistically for each location to reveal a long-term linear trend, an annual variation, a Quasi-Biennial Oscillation (QBO), a solar cycle component and a semi-annual (6 month) signal. Coefficients from these statistical models have been used to estimate monthly mean ozone and noon clear-sky erythemal irradiances to the year 2000 for each city. It is assumed that the rate of increase of stratospheric chlorine over the remainder of the century will remain constant. Given that there is some evidence that the rate of increase is decreasing, the results present here should be regarded as an upper limit. 33 refs., 7 tabs., 4 figs

The glacial record of New Zealand's Southern Alps

Science.gov (United States)

Schaefer, J. M.; Denton, G.; Lowell, T.; Anderson, B.; Rinterknecht, V.; Schlosser, P.; Ivy-Ochs, S.; Kubik, P.; Schluechter, C.; Chinn, T.; Barrell, D.; Lifton, N.; Jull, T.

2004-12-01

We present detailed mapping and surface exposure dating using in-situ Be-10 and C-14 of the moraine set of Lake Pukaki, New Zealand's Southern Alps, spanning from the penultimate glaciation, over several Last Glacial Maximum (LGM) moraines, the late glacial event to Holocene glacial advances. New Zealand, a mountain ridge in the middle of the Southern Ocean, has one of the best preserved moraine records world-wide, offering the opportunity to reconstruct amplitude and timing of climate changes from Southern mid-latitudes, an area where paleoclimate data is scarce. The extensive mapping effort by G. Denton and colleagues (http://wyvern.gns.cri.nz/website/csigg/) provides a unique background for sample selection for Surface Exposure Dating. Our extensive data set (>40 samples analyzed so far) indicate that (i) the LGM in New Zealand terminated clearly prior to the Boelling/Alleroed warming, (ii) the late glacial advance is within uncertainties consistent with the timing of the Younger Dryas cold reversal; (iii) there occurred an early Holocene glacial event of the same amplitude than the Little Ice Age. This latter event is the first Holocene glacial event from the Southern Hemisphere dated by in-situ Be-10 and C-14.

Fatty Alcohol Variations in Surface Sediments of Sungai Sepang Besar, Sepang, Selangor

International Nuclear Information System (INIS)

Masni Mohd Ali; Norfariza Humrawali; Ying, P.Q.; Mohd Talib Latif; Mohamad Pauzi Zakaria

2011-01-01

Composition of fatty alcohols from 19 surface sediment samples collected along Sungai Sepang Besar, Sepang, Selangor were determined. The sediments were extracted and analysed using the Gas Chromatography-Mass Spectrometry (GC-MS) technique. A total of 19 fatty alcohols from C 12 to C 30 including 4 branched compounds were identified with concentrations in the range 0.02 μg/ g - 9.01 μg/ g dry weight. C 26 fatty alcohols dominated most sampling stations with concentrations ranging from 0.29 to 5.43 μg/ g dry weight and constituted 15.5 % of total fatty alcohols. According to individual compounds of fatty alcohols and the [Σ(C 12 - C 20 )/ Σ(C 22 - C 30 )] ratio, Sungai Sepang Besar has a high composition of short-chain fatty alcohols (C 12 - C 20 ) which mainly originate from marine organisms. However, the Alcohol Sources Index (ASI) showed that terrestrial derived fatty alcohols dominated the area due to high concentration of C 26 compounds in most sampling stations. The value of (odd chain length)/ (even chain length) ratios were high for almost all the sampling stations due to high bacterial activities. It can be concluded that the surface sediments of Sungai Sepang Besar contained organic materials from marine, terrestrial and bacterial sources. (author)

Quantitative radiolarian assemblages in surface sediments from the central Indian Basin and their paleomonsoonal significance

Digital Repository Service at National Institute of Oceanography (India)

Gupta, S.M.

The percentage data of 47 radiolarian coarser taxonomic groups in the surface sediments from the central Indian Basin was subjected to cluster and factor analyses. The R-mode cluster analysis resulted in 3 dominant clusters which represent surface...

Radioactivity of some alpha, beta and gamma emitting radionuclides in surface marine sediments of different bays in Algeria

International Nuclear Information System (INIS)

Noureddine, A.; Baggoura, B.

1999-01-01

Samples of surface (0-15) cm marine sediments of different grain sizes, namely sand, muddy and fine sand, were collected in the western, central and east coast of Algeria, to measure concentrations of natural and artificial radioactivity. The aim of this study is to detect any radioactive contamination, its origin and also to determine the uptake of radioactivity by marine surface sediments

Comparison of phosphorus fraction distribution and influencing factors of suspended and surface sediments in the Tiaoxi watershed, China.

Science.gov (United States)

Ye, Hongmeng; Yuan, Xuyin; Han, Lei; Yin, Heng; Jin, Jing

2017-05-01

Suspended and surface sediments from the Tiaoxi watershed, fed by the Xitiaoxi and Dongtiaoxi rivers, were analyzed for total phosphorus (TP) and the inorganic P fractions of loosely adsorbed P that were extractable with NH 4 Cl (NH 4 Cl-P), reductant P (BD-P), metal oxide-bound P extractable with NaOH (NaOH-P), and calcium-bound, HCl-extractable P (HCl-P), while other physicochemical compositions were also determined. The spatial variations of P fractions in these sediments were investigated, and the major factors influencing the various fractions were explored by multivariate statistics. Compared to surface sediments, suspended sediments contained considerably higher concentrations of total nitrogen, TP, organic matter, Al, Fe, Mn and biologically available P (BAP, given as NH 4 Cl-P, BD-P and NaOH-P combined) and lower concentrations of Si, Ca and HCl-P in the studied catchments. Dongtiaoxi sediments had higher TP, inorganic phosphorus and HCl-P concentrations and a lower BAP content compared with Xitiaoxi sediments, trends that were associated with local geological backgrounds, landscapes and anthropogenic characteristics. The results of principal component analysis showed different effects of sediment properties on P fraction distributions for Xitiaoxi and Dongtiaoxi sediments. The sediment components and structure exert a strong influence on BAP in Xitiaoxi sediments, in contrast to Dongtiaoxi sediments, where P fractions are mainly affected by urbanization and other anthropogenic activities such as shipping.

Pre-European Maori fishing at Foxton, Manawatu, New Zealand

International Nuclear Information System (INIS)

Davidson, J.; Leach, F.; Greig, K.; Leach, P.

2000-01-01

Fish remains from excavations in four areas of the Foxton archaeological site (S24/3) were analysed. The 4109 identified bones produced a Minimum Mumber of Individuals of 1040 fish from 8 families. The assemblage was dominated by New Zealand snapper (Pagrus auratus, Family Sparidae), which comprised 80% of the total MNI. Kahawai (Arripis trutta, Family Arripidae) contributed 15% and other families only minor amounts. Snapper decreased in abundance and kahawai increased from the lower to the upper layers. The Foxton catch at all periods is different from other assemblages studied from central New Zealand. This partly reflects the local marine environment, which lacks rocky shores and reefs, but we also hypothesise that it is related to warmer surface sea water conditions in Cook Strait in the early phase of the New Zealand prehistoric period. Size frequency diagrams were constructed for snapper and kahawai. It was found that the mean fork length and mean ungutted weight of snapper increased over time. Similar changes have been observed for other species in archaeological sites in New Zealand. (author). 26 refs., 6 figs., 8 tabs

New Zealand Maritime Glaciation: Millennial-Scale Southern Climate Change Since 3.9 Ma

Science.gov (United States)

Carter, Robert M.; Gammon, Paul

2004-06-01

Ocean Drilling Program Site 1119 is ideally located to intercept discharges of sediment from the mid-latitude glaciers of the New Zealand Southern Alps. The natural gamma ray signal from the site's sediment core contains a history of the South Island mountain ice cap since 3.9 million years ago (Ma). The younger record, to 0.37 Ma, resembles the climatic history of Antarctica as manifested by the Vostok ice core. Beyond, and back to the late Pliocene, the record may serve as a proxy for both mid-latitude and Antarctic polar plateau air temperature. The gamma ray signal, which is atmospheric, also resembles the ocean climate history represented by oxygen isotope time series.

Distribution of polycyclic aromatic hydrocarbons (PAHs) in surface sediments of Pulau Tinggi, Johor

Science.gov (United States)

Razak, Ezzati Sulhi Abdul; Halim, Izzyan Syazwani Abdul; Ali, Masni Mohd

2016-11-01

Surface sediments samples were collected at 11 stations around the Pulau Tinggi, Johor in September 2015. A total of 15 PAHs were determined and quantified by gas chromatography coupled with mass spectrometry (GC-MS). The total PAH concentrations of surface sediments from Pulau Tinggi ranged from 39.61 ng/g to 149.2 ng/g and they were classified as being in low to moderate pollution range. Individual PAH analysis showed that two and three rings PAHs were the most frequently detected isomers and accounted for 22 - 46% of the total PAH concentrations. The sources of PAHs were evaluated by employing diagnostic ratiosof specific PAH compounds.PAH ratios analysis showed a prevalence of pyrogenic PAH origin at most of the stations with exception of only a few stations.

Heavy metals in surface sediments of the Jialu River, China: their relations to environmental factors.

Science.gov (United States)

Fu, Jie; Zhao, Changpo; Luo, Yupeng; Liu, Chunsheng; Kyzas, George Z; Luo, Yin; Zhao, Dongye; An, Shuqing; Zhu, Hailiang

2014-04-15

This work investigated heavy metal pollution in surface sediments of the Jialu River, China. Sediment samples were collected at 19 sites along the river in connection with field surveys and the total concentrations were determined using atomic fluorescence spectrometer and inductively coupled plasma optical emission spectrometer. Sediment samples with higher metal concentrations were collected from the upper reach of the river, while sediments in the middle and lower reaches had relatively lower metal concentrations. Multivariate techniques including Pearson correlation, hierarchical cluster and principal components analysis were used to evaluate the metal sources. The ecological risk associated with the heavy metals in sediments was rated as moderate based on the assessments using methods of consensus-based Sediment Quality Guidelines, Potential Ecological Risk Index and Geo-accumulation Index. The relations between heavy metals and various environmental factors (i.e., chemical properties of sediments, water quality indices and aquatic organism indices) were also studied. Nitrate nitrogen, total nitrogen, and total polycyclic aromatic hydrocarbons concentrations in sediments showed a co-release behavior with heavy metals. Ammonia nitrogen, total nitrogen, orthophosphate, total phosphate and permanganate index in water were found to be related to metal sedimentation. Heavy metals in sediments posed a potential impact on the benthos community. Copyright © 2014 Elsevier B.V. All rights reserved.

Tracing the origin of Pb using stable Pb isotopes in surface sediments along the Korean Yellow Sea coast

Science.gov (United States)

Park, Jong-Kyu; Choi, Man-Sik; Song, Yunho; Lim, Dhong-Il

2017-06-01

To investigate the factors controlling lead (Pb) concentration and identify the sources of Pb in Yellow Sea sediments along the Korean coast, the concentration of Pb and Pb isotopes in 87 surface and 6 core sediment samples were analyzed. The 1 M HCl leached Pb concentrations had a similar geographic distribution to those of fine-grained sediments, while the distribution of residual Pb concentrations resembled that of coarse-grained sediments. Leached Pb was presumed to be associated with manganese (Mn) oxide and iron (Fe) oxy/hydroxide, while residual Pb was associated with potassium (K)-feldspar, based on good linear relationships between the leached Pb and the Fe/Mn concentrations, and the residual Pb and K concentrations. Based on a ratio-ratio plot with three isotopes (207Pb/206Pb and 208Pb/206Pb) and the geographic location of each sediment, sediments were categorized into two groups of samples as group1 and group2. Group 1 sediments, which were distributed in Gyeonggi Bay and offshore (north of 36.5°N), were determined to be a mixture of anthropogenic and natural Pb originating from the Han River, based on a 208Pb/206Pb against a Cs/Pbleached mixing plot of core and surface sediments. Group 2 sediments, which were distributed in the south of 36.5°N, also showed a two endmembers mixing relationship between materials from the Geum River and offshore materials, which had very different Pb concentrations and isotope ratios. Based on the isotopes and their concentrations in core and surface sediments, this mixing relationship was interpreted as materials from two geographically different origins being mixed, rather than anthropogenic or natural mixing of materials with the same origin. Therefore, the relative percentage of materials supplied from the Geum River was calculated using a two endmembers mixing model and estimated to be as much as about 50% at 35°N. The spatial distribution of materials derived from the Geum River represented that of fine

The effect of grain size and surface area on organic matter, lignin and carbohydrate concentration, and molecular compositions in Peru Margin sediments

Science.gov (United States)

Bergamaschi, Brian A.; Tsamakis, Elizabeth; Keil, Richard G.; Eglinton, Timothy I.; Montluçon, Daniel B.; Hedges, John I.

1997-03-01

A C-rich sediment sample from the Peru Margin was sorted into nine hydrodynamically-determined grain size fractions to explore the effect of grain size distribution and sediment surface area on organic matter content and composition. The neutral monomeric carbohydrate composition, lignin oxidation product yields, total organic carbon, and total nitrogen contents were determined independently for each size fraction, in addition to sediment surface area and abundance of biogenic opal. The percent organic carbon and percent total nitrogen were strongly related to surface area in these sediments. In turn, the distribution of surface area closely followed mass distribution among the textural size classes, suggesting hydrodynamic controls on grain size also control organic carbon content. Nevertheless, organic compositional distinctions were observed between textural size classes. Total neutral carbohydrate yields in the Peru Margin sediments were found to closely parallel trends in total organic carbon, increasing in abundance among grain size fractions in proportion to sediment surface area. Coincident with the increases in absolute abundance, rhamnose and mannose increased as a fraction of the total carbohydrate yield in concert with surface area, indicating these monomers were preferentially represented in carbohydrates associated with surfaces. Lignin oxidation product yields varied with surface area when normalized to organic carbon, suggesting that the terrestrially-derived component may be diluted by sorption of marine derived material. Lignin-based parameters suggest a separate source for terrestrially derived material associated with sand-size material as opposed to that associated with silts and clays.

Neutron activation analysis to the profile surface sediments from several sites on the Havana Bay

International Nuclear Information System (INIS)

Diaz Riso, O.; Gelen, A.; Lopez, N.; Gonzalez, H.; Manso, M.V.; Graciano, A.M.; Nogueira, C.A.; Beltran, J.; Soto, J.

2003-01-01

Instrumental neutron activation analysis (INAA) technique was employed to analyze the surface sediments from several sites on the Havana Bay, Cuba. Measurements of heavy and trace elements in the sediments are reported. The results show that the concentration of the elements is site dependent. The data suggest that an anthropogenic input into the bay from domestic sewage and industries occurred

Innovative eco-friendly bio- solvent for combating sea surface and sedimented oil pollution

Science.gov (United States)

Theodorou, Paraskevas

2017-04-01

The combating of oil spill at sea surface by chemical dispersants accelerates the evaporation and disperse the oil into the water column, where it is broken down by natural processes and/or is sedimented at the sea bottom, especially at near coastal shallow areas, ports and marinas. The usual methodology for cleaning the sedimented oil from the sea bottom is mainly carried out via excavation and dumping of the polluted sediment into deeper sea areas, where the contamination is transferred from one area to another. The eco-friendly bio-solvent MSL Aqua 250 is an innovative new solution based mainly on natural constituents. The action mechanism and the effectiveness of this eco-friendly solvent is based on the high surface tension process. Organic compounds, including hydrocarbons upon coming in contact with MSL Aqua 250 solvent generate a significant surface tension reaction, which is able to alter the organic compounds to liquid form and then to drastically evaporate it. The use of MSL Aqua 250 solvent, both at sea surface and at the bottom, has the following advantages compared to the dispersants: • Efficient solution without transferring the pollution from sea surface to the water column and to the bottom or disturbing the Aquatic Eco System. • Non-Toxic. • Environmentally friendly with a restoration of marine life in the Eco System. • Cost effective. The MSL Aqua 250 solvent has been tested in cooperation with the Cyprus Department of Fisheries and Marine Research and the Technological University of Cyprus and used during the years 2015 and 2016 in marinas and fishing shelters in Cyprus faced oil pollution, with high concentration in the sea water and at the sea bottom of chemical parameters (BOD5, COD, FOG, TKN, TP, TPH), with excellent results.

Speciation and spatial distribution of solid-phase iron in surface sediments of the East China Sea continental shelf

International Nuclear Information System (INIS)

Zhu, Mao-Xu; Hao, Xiao-Chen; Shi, Xiao-Ning; Yang, Gui-Peng; Li, Tie

2012-01-01

Speciation and reactivity characterization of solid-phase Fe in marine sediments are of significance to understanding its heterogeneous mineralogy and crystallinity, the diagenetic cycling of Fe and its regulating roles on many other elements in sediments. In this study, a combination of sequential and single-step extractions was used for the determination of seven Fe pools in surface sediments of the East China Sea (ECS) continental shelf: (1) carbonate associated Fe (Fe(II) carb ) plus acid volatile sulfide-Fe (Fe(II) AVS ), (2) easily reducible amorphous/poorly crystalline Fe oxides (Fe ox1 ), (3) reducible crystalline Fe oxides (Fe ox2 ), (4) magnetite (Fe mag ), (5) poorly reactive sheet silicate Fe (Fe PRS ), (6) pyrite-Fe (Fe py ), and (7) unreactive silicate Fe (Fe U ). Total Fe (Fe T ) in the sediments is largely determined by terrestrial aluminosilicate particles as indicated by a great similarity of the Fe T with that of the Yangtze River and global riverine particulates. The size of Fe PRS is found to be the largest pool, followed by Fe U , Fe ox2 , Fe mag , Fe(II) AVS+carb , Fe ox1 and Fe py . The large Fe PRS may result from neoformation of Fe-rich clay minerals via reverse weathering and subsequent ageing. The small sizes of Fe(II) AVS+carb and Fe py pools is believed to be the result of low SO 4 reduction due to generally low labile organic matter together with the oxic/suboxic, dynamic environments of the surface sediments. The occurrence of Fe ox1 , Fe ox2 and Fe PRS in the sediments is closely associated with the clay fraction as indicated by a high spatial correlation between the former and the latter. Highly reactive Fe(Fe HR ) in the sediments is comparable to that in global marine sediments, but apparently lower than in the Yangtze River and global riverine particulates due probably to sequestration in the Yangtze Estuary. The ratios of Fe HR /Fe T , Fe PR /Fe T and Fe U /Fe T in the ECS surface sediments consistently show more similarity to

Contaminants in surface water and sediments near the Tynagh silver mine site, County Galway, Ireland

Energy Technology Data Exchange (ETDEWEB)

O' Neill, A. [School of Planning, Architecture and Civil Engineering, Queen' s University of Belfast, Belfast, Northern Ireland (United Kingdom); Phillips, D.H., E-mail: d.phillips@qub.ac.uk [School of Planning, Architecture and Civil Engineering, Queen' s University of Belfast, Belfast, Northern Ireland (United Kingdom); Bowen, J. [School of Planning, Architecture and Civil Engineering, Queen' s University of Belfast, Belfast, Northern Ireland (United Kingdom); Sen Gupta, B. [School of the Built Environment, Hariot-Watt University, Edinburgh, Scotland (United Kingdom)

2015-04-15

A former silver mine in Tynagh, Co. Galway, Ireland is one of the most contaminated mine sites in Europe with maximum concentrations of Zn, As, Pb, Mn, Ni, Cu, and Cd far exceeding guideline values for water and sediment. The aims of this research were to 1) further assess the contamination, particularly metals, in surface water and sediment around the site, and 2) determine if the contamination has increased 10 years after the Environmental Protection Agency Ireland (EPAI) identified off-site contamination. Site pH is alkaline to neutral because CaCO{sub 3}-rich sediment and rock material buffer the exposed acid generating sulphide-rich ore. When this study was compared to the previous EPAI study conducted 10 years earlier, it appeared that further weathering of exposed surface sediment had increased concentrations of As and other potentially toxic elements. Water samples from the tailings ponds and adjacent Barnacullia Stream had concentrations of Al, Cd, Mn, Zn and Pb above guideline values. Lead and Zn concentrations from the tailings pond sediment were 16 and 5 times higher, respectively, than concentrations reported 10 years earlier. Pb and Zn levels in most sediment samples exceeded the Expert Group (EGS) guidelines of 1000 and 5000 mg/kg, respectively. Arsenic concentrations were as high as 6238 mg/kg in the tailings ponds sediment, which is 62 and 862 times greater than the EGS and Canadian Soil Quality Guidelines (CSQG), respectively. Cadmium, Cu, Fe, Mn, Pb and Zn concentrations in water and sediment were above guideline values downstream of the site. Additionally, Fe, Mn and organic matter (OM) were strongly correlated and correlated to Zn, Pb, As, Cd, Cu and Ni in stream sediment. Therefore, the nearby Barnacullia Stream is also a significant pathway for contaminant transport to downstream areas. Further rehabilitation of the site may decrease the contamination around the area. - Highlights: • Tynagh silver mine in Co. Galway, Ireland is a source of

Application of carbon isotope stratigraphy to late miocene shallow marine sediments, new zealand.

Science.gov (United States)

Loutit, T S; Kennett, J P

1979-06-15

A distinct (0.5 per mil) carbon-13/carbon-12 isotopic shift in the light direction has been identified in a shallow marine sedimentary sequence of Late Miocene age at Blind River, New Zealand, and correlated with a similar shift in Late Miocene Deep Sea Drilling Project sequences throughout the Indo-Pacific. A dated piston core provides an age for the shift of 6.2 +/- 0.1 million years. Correlations based on the carbon isotopic change require a revision of the previously established magnetostratigraphy at Blind River. The carbon shift at Blind River occurs between 6.2 and 6.3 +/- 0.1 million years before present. A new chronology provides an age for the evolutionary first appearance datum of Globorotalia conomiozea at 6.1 +/- 0.1 million years, the beginning of a distinct latest Miocene cooling event associated with the Kapitean stage at 6.2 +/- 0.1 million years, and the beginning of a distinct shallowing of water depths at 6.1 +/- 0.1 million years. The Miocene-Pliocene boundary as recognized in New Zealand is now dated at 5.3 +/- 0.1 million years. Extension of carbon isotope stratigraphy to other shallow Late Miocene sequences should provide an important datum for international correlation of Late Miocene shallow and deep marine sequences.

Uranium series disequilibrium in the coastal surface sediments and sea water of the Arabian sea

Digital Repository Service at National Institute of Oceanography (India)

Joshi, L.U.; Zingde, M.D.

activity ratios in leachates, and residues after removal of surface organic matter from the sediment particles by treatment with hydrogen peroxide and 0.05M HCl, revealed disequilibrium between sup(238) U and sup(234) U only in the surface organic matter...

Aerobic biodegradation potential of endocrine-disrupting chemicals in surface-water sediment at Rocky Mountain National Park, USA.

Science.gov (United States)

Bradley, Paul M; Battaglin, William A; Iwanowicz, Luke R; Clark, Jimmy M; Journey, Celeste A

2016-05-01

Endocrine-disrupting chemicals (EDCs) in surface water and bed sediment threaten the structure and function of aquatic ecosystems. In natural, remote, and protected surface-water environments where contaminant releases are sporadic, contaminant biodegradation is a fundamental driver of exposure concentration, timing, duration, and, thus, EDC ecological risk. Anthropogenic contaminants, including known and suspected EDCs, were detected in surface water and sediment collected from 2 streams and 2 lakes in Rocky Mountain National Park (Colorado, USA). The potential for aerobic EDC biodegradation was assessed in collected sediments using 6 (14) C-radiolabeled model compounds. Aerobic microbial mineralization of natural (estrone and 17β-estradiol) and synthetic (17α-ethinylestradiol) estrogen was significant at all sites. Bed sediment microbial communities in Rocky Mountain National Park also effectively degraded the xenoestrogens bisphenol-A and 4-nonylphenol. The same sediment samples exhibited little potential for aerobic biodegradation of triclocarban, however, illustrating the need to assess a wider range of contaminant compounds. The present study's results support recent concerns over the widespread environmental occurrence of carbanalide antibacterials, like triclocarban and triclosan, and suggest that backcountry use of products containing these compounds should be discouraged. Published 2015 Wiley Periodicals Inc. on behalf of SETAC. This article is a US Government work and, as such, is in the public domain in the United States of America.

Chemical and physical properties of the surface sea sediments at the Olkiluoto offshore, South-Western Finland

International Nuclear Information System (INIS)

Lahdenperae, A.-M.; Keskinen, A.

2011-11-01

Due to land uplift, the present sea sediments near Olkiluoto will be future land areas, and thus important for the transport of possible releases from nuclear waste repositories at the site. Coastal areas are the transition zones between land and sea, and also potential sites for deep groundwater discharge. The geochemical properties of the surface sediments at the Olkiluoto sea area are summarised in this report. Thirteen sediment samples were cored during the R/V Geomari cruise in autumn 2008. In addition, surface sediment samples from six transects, altogether 57 cores, were taken near the Olkiluoto shoreline by diving in the summer of 2008. The analysis procedure included pH, moisture, dry matter, ash and LOI contents, grain size distribution, carbon and nitrogen analyses and the total concentrations of thirtythree elements. The lateral and vertical distribution of element concentrations, especially heavy metals, is caused by variations in transport and sedimentation patterns of particulate matter, in the occurrence of migration processes and bonding types. The distribution pattern in most of the elements is strongly linked to that of organic matter, carbon and fine-grained material contents. The sediments are strongly enriched by some of the studied elements possibly due to anthropogenic load, while others are only moderately or slightly present. However, the source of different natural and anthropogenic loads is not easy to point out. (orig.)

Micro contaminants in surface sediments and macrobenthic invertebrates of the North Sea

NARCIS (Netherlands)

Everaarts, J.M.; Fischer, C.V.

1989-01-01

Trace metal concentrations (copper, zinc, cadmium and lead) were measured in the silt fraction (grainsize < 63 µm) of surface sediment of the North Sea. The concentrations varied in different areas of the Dutch continental shelf of the North Sea. The trace metal concentrations were highly related

Hydrothermal alteration of sediments associated with surface emissions from the Cerro Prieto geothermal field

Energy Technology Data Exchange (ETDEWEB)

Valette-Silver, J.N.; Esquer P., I.; Elders, W.A.; Collier, P.C.; Hoagland, J.R.

1981-01-01

A study of the mineralogical changes associated with these hydrothermal vents was initiated with the aim of developing possible exploration tools for geothermal resources. The Cerro Prieto reservoir has already been explored by extensive deep drilling so that relationships between surface manifestations and deeper hydrothermal processes could be established directly. Approximately 120 samples of surface sediments were collected both inside and outside of the vents. The mineralogy of the altered sediments studied appears to be controlled by the type of emission. A comparison between the changes in mineralogy due to low temperature hydrothermal activity in the reservoir, seen in samples from boreholes, and mineralogical changes in the surface emission samples shows similar general trends below 180 C: increase of quartz, feldspar and illite, with subsequent disappearance of kaolinite, montmorillonite, calcite and dolomite. These mineral assemblages seem to be characteristic products of the discharge from high intensity geothermal fields.

Distribution and characteristics of organic micropollutants in surface sediments from Bohai Sea

International Nuclear Information System (INIS)

Liu Wenxin; Chen Jianglin; Lin Xiumei; Tao Shu

2006-01-01

Spatial distribution and compositional characteristics of PAHs, DDTs and PCBs in surface sediments from Bohai Sea were investigated. Proportion of LMW PAHs at Jinzhou Bay was significant, due probably to the petrogenic sources from neighboring oil wells and plants, while HMW PAHs were dominant in the other sea areas, inferred pyrogenic origins mainly from coal or petroleum combustion. The average ERL quotient for the PAH species in Qinhuangdao and Liaodong Bay indicated relatively stronger potential ecological risk. The concentration ratios of DDT to metabolites (DDD + DDE) exceeded 1.0 in the coastal areas of Qinhuangdao, Liaodong Bay and Bohai Bay, demonstrated some recent inputs of DDT nearby, and DDD as the major degradation product. The concentrations of PCBs were generally low, however, the contents of DDTs were greater than the ERL guidelines in the coastal areas of Qinhuangdao, Liaodong Bay and Bohai Bay, and suggested the potential ecological risk. - The recent inputs of DDT in surface sediments at some sites of Bohai Sea indicated potential ecological risk

Screening of multiple hormonal activities in surface water and sediment from the Pearl River system, South China, using effect-directed in vitro bioassays.

Science.gov (United States)

Zhao, Jian-Liang; Ying, Guang-Guo; Yang, Bin; Liu, Shan; Zhou, Li-Jun; Chen, Zhi-Feng; Lai, Hua-Jie

2011-10-01

This paper reports screening of multiple hormonal activities (estrogenic and androgenic activities, antiestrogenic and antiandrogenic activities) for surface water and sediment from the Pearl River system (Liuxi, Zhujiang, and Shijing rivers) in South China, using in vitro recombinant yeast bioassays. The detection frequencies for estrogenic and antiandrogenic activities were both 100% in surface water and 81 and 93% in sediment, respectively. The levels of estrogenic activity were 0.23 to 324 ng 17β-estradiol equivalent concentration (EEQ)/L in surface water and 0 to 101 ng EEQ/g in sediment. Antiandrogenic activities were in the range of 20.4 to 935 × 10(3) ng flutamide equivalent concentration (FEQ)/L in surface water and 0 to 154 × 10(3) ng FEQ/g in sediment. Moreover, estrogenic activity and antiandrogenic activity in sediment showed good correlation (R(2) = 0.7187), suggesting that the agonists of estrogen receptor and the antagonists of androgen receptor co-occurred in sediment. The detection frequencies for androgenic and antiestrogenic activities were 41 and 29% in surface water and 61 and 4% in sediment, respectively. The levels of androgenic activities were 0 to 45.4 ng dihydrotestosterone equivalent concentration (DEQ)/L in surface water, and the potency was very weak in the only detected sediment site. The levels of antiestrogenic activity were 0 to 1,296 × 10(3) ng tamoxifen equivalent concentration (TEQ)/L in surface water and 0 to 89.5 × 10(3) ng TEQ/g in sediment. The Shijing River displayed higher levels of hormonal activities than the Zhujiang and Liuxi rivers, indicating that the Shijing River had been suffering from heavy contamination with endocrine-disrupting chemicals. The equivalent concentrations of hormonal activities in some sites were greater than the lowest-observed-effect concentrations reported in the literature, suggesting potential adverse effects on aquatic organisms. Copyright © 2011 SETAC.

Late Pleistocene surface rupture history of the Paeroa Fault, Taupo Rift, New Zealand

International Nuclear Information System (INIS)

Berryman, K.R.; Villamor, P.; Nairn, I.A.; Van Dissen, R.J.; Begg, J.G.; Lee, J.M.

2008-01-01

The 30 km long Paeroa Fault is one of the largest and fastest slipping (c. 1.5 mm/yr vertical displacement rate) normal faults of the currently active Taupo Rift of North Island, New Zealand. Along its northern section, seven trenches excavated across 5 of 11 subparallel fault strands show that successive ruptures of individual strands probably occurred at the same time, but were individually and collectively highly variable in size and recurrence, and most fault strands have ruptured three or four times in the past 16 kyr. In the c. 16 kyr timeframe, four surface-rupturing earthquakes took place when Okataina volcano was erupting, and six occurred between eruptions. Large earthquakes on the Paeroa Fault comprise a significant component of the seismic hazard in the region between the Okataina and Taupo Volcanic Centres, and there are partial associations between these large earthquakes and volcanism. (author). 36 refs., 15 figs., 2 tabs

Radiocarbon dating the end of moa-hunting in New Zealand prehistory

International Nuclear Information System (INIS)

Schmidt, M.

2000-01-01

For over 150 years, New Zealand scientists and prehistorians have investigated and debated when the last moa (Aves : Dinornithiformes) was hunted and killed by humans (see Anderson 1989). Prior to the introduction of radiocarbon dating into New Zealand archaeology in the mid-1950s, theories on when moa predation ended were based on Maori oral tradition, dubious eye witness accounts, moa bones found on the surface of the ground and arbitrary archaeological excavations of large culling sites. Radiocarbon dating provided an absolute chronological tool for determining when the remains of moa found in prehistoric context were deposited, meaning the activity of moa-hunting could be more easily attributed to a particular period in New Zealand prehistory. (author)

Non-aromatic hydrocarbons in surface sediments near the Pearl River estuary in the South China Sea

International Nuclear Information System (INIS)

Gao Xuelu; Chen Shaoyong; Xie Xueliang; Long Aimin; Ma Fujun

2007-01-01

Surface sediment samples at 4 sites along an offshore transect from outer continental shelf off the Pearl River estuary to the shelf slope region of the northern South China Sea, have been analyzed for total organic carbon (TOC), total nitrogen (TN), solvent extractable organic matter (EOM) and non-aromatic hydrocarbons. TOC, TN and EOM show distinct spatial variations. Their highest values are all recorded at the shelf slope region. EOM varies from 18.70-38.58 μg g -1 dry sediment and accounts for 0.20-0.72% of the TOC contents. The non-aromatic hydrocarbons are an important fraction of EOM. Their contents range from 3.43-7.06 μg g -1 dry sediment. n-Alkanes with carbon number ranging from 15-38 are identified. They derive from both biogenic and petrogenic sources in different proportions. Results of isoprenoid hydrocarbons, hopanes and steranes also suggest possible petroleum contamination. - Anthropogenic activities have influences on the composition of non-aromatic hydrocarbons in the surface sediments of the northern South China Sea outer continental shelf

Fine scale distributions of porosity and particulate excess 210Pb, organic carbon and CaCO3 in surface sediments of the deep equatorial Pacific

International Nuclear Information System (INIS)

Jahnke, R.A.; Emerson, S.R.; Cochran, J.K.; Hirschberg, D.J.

1986-01-01

Sediment samples were recovered from the central equatorial Pacific Ocean, sectioned at 1-mm intervals, and analyzed for porosity, organic carbon, excess 210 Pb and CaCO 3 . Steep porosity gradients were measured in the upper 1 cm of the sediment column with extremely high values observed near the sediment surface. Similarly, particulate organic carbon contents are highest at the sediment surface, decrease sharply in the upper 1 cm, and are relatively constant between 1 and 5 cm. CaCO 3 values, on the other hand, are lowest at the sediment surface and increase to a constant value below 5-10 mm depth. At the carbonate ooze sites, excess 210 Pb is present throughout the upper 5 cm of the sediments suggesting relatively rapid particle mixing rates. However, extremely high excess 210 Pb activities (> 100 dpm/g) are observed at the sediment surface with sharp gradients present in the upper 1 cm which would suggest slow rates of mixing. This apparent contradiction along with the major features of the CaCO 3 and particulate organic carbon profiles can be explained by a particle-selective feeding mechanism in which organic carbon, excess 210 Pb-enriched particles are preferentially maintained at the sediment surface via ingestion and defecation by benthic organisms. (orig.)

Impact of Hurricane Irene on Vibrio vulnificus and Vibrio parahaemolyticus concentrations in surface water, sediment and cultured oysters in the Chesapeake Bay, Maryland, USA

Directory of Open Access Journals (Sweden)

Kristi S Shaw

2014-05-01

Full Text Available To determine if a storm event (i.e., high winds, large volumes of precipitation could alter concentrations of Vibrio vulnificus and Vibrio parahaemolyticus in aquacultured oysters (Crassostrea virginica and associated surface water and sediment, this study followed a sampling timeline before and after Hurricane Irene impacted the Chesapeake Bay estuary in late August 2011. Aquacultured oysters were sampled from two levels in the water column: surface 0.3 m and near-bottom just above the sediment. Concentrations of each Vibrio spp. and associated virulence genes were measured in oysters with a combination of real-time PCR and most probable number enrichment methods, and in sediment and surface water with real-time PCR. While concentration shifts of each Vibrio species were apparent post-storm, statistical tests indicated no significant change in concentration change for either Vibrio species by location (surface or near bottom oysters or date sampled (oyster tissue, surface water and sediment concentrations. V. vulnificus in oyster tissue was correlated with total suspended solids (r=0.41, p=0.04, and V. vulnificus in sediment was correlated with secchi depth (r=-0.93, p< 0.01, salinity (r=-0.46, p=0.02, tidal height (r=-0.45, p=0.03, and surface water V. vulnificus (r=0.98, p< 0.01. V. parahaemolyticus in oyster tissue did not correlate with environmental measurements, but V. parahaemolyticus in sediment and surface water correlated with several measurements including secchi depth (r=-0.48, p=0.02[sediment]; r=-0.97 p< 0.01[surface water] and tidal height (r=-0.96. p< 0.01[sediment], r=-0.59,p< 0.01 [surface water]. The concentrations of Vibrio spp. were higher in oysters relative to other studies (average V. vulnificus 4x105 MPN g-1, V. parahaemolyticus 1x105 MPN g-1, and virulence-associated genes were detected in most oyster samples. This study provides a first estimate of storm-related Vibrio density changes in oyster tissues, sediment and

Pollution characteristics and ecological risk assessment of heavy metals in the surface sediments from a source water reservoir

Directory of Open Access Journals (Sweden)

Changming Yang

2016-10-01

Full Text Available Surface sediment samples were collected from a source water reservoir in Zhejiang Province, East of China to investigate pollution characteristics and potential ecological risk of heavy metals. The BCR sequential extraction method was used to determine the four chemical fractions of heavy metals such as acid soluble, easily reducible, easily oxidizable and residual fractions. The heavy metals pollution and potential ecological risk were evaluated systematically using geoaccumulation index (Igeo and Hakanson potential ecological risk index (H′. The results showed that the sampling sites from the estuaries of tributary flowing through downtowns and heavy industrial parks showed significantly (p < 0.05 higher average concentrations of heavy metals in the surface sediments, as compared to the other sampling sites. Chemical fractionation showed that Mn existed mainly in acid extractable fraction, Cu and Pb were mainly in reducible fraction, and As existed mainly in residual fraction in the surface sediments despite sampling sites. The sampling sites from the estuary of tributary flowing through downtown showed significantly (p < 0.05 higher proportions of acid extractable and reducible fractions than the other sampling sites, which would pose a potential toxic risk to aquatic organisms as well as a potential threat to drinking water safety. As, Pb, Ni and Cu were at relatively high potential ecological risk with high Igeo values for some sampling locations. Hakanson potential ecological risk index (H′ showed the surface sediments from the tributary estuaries with high population density and rapid industrial development showed significantly (p < 0.05 higher heavy metal pollution levels and potential ecological risk in the surface sediments, as compared to the other sampling sites.

Ecological risk, source and preliminary assessment of metals in the surface sediments of Chabahar Bay, Oman Sea

International Nuclear Information System (INIS)

Agah, Homira; Saleh, Abolfazl; Bastami, Kazem Darvish; Fumani, Neda Sheijooni

2016-01-01

In this study, concentrations of Aluminum (Al), Iron (Fe), Chromium (Cr), Copper (Cu), Nickel (Ni), Vanadium (V), Zinc (Zn), Arsenic (As), Cobalt (Co) and lead (Pb) in the surface sediments from Chabahar Bay were studied to assess the degree of heavy metal pollution as a consequence of natural and anthropogenic sources. Metal contents in the sediments were observed in the order of: Al > Fe > Cr > V > Ni > Zn > Cu > > As > Pb > Co. According to enrichment factor (EF), Arsenic was higher than 1.5 at some sites, indicating anthropogenic inputs. Contents of Ni, As and Cr in the some sampling sites were higher than sediment quality guideline implying adverse impacts of these metals. Based on potential ecological risk (PER), the Chabahar Bay had low ecological risk. - Highlights: •Metals and major elements were determined in surface sediments from Chabahar Bay, Oman Sea. •EF values indicated non-enriched to moderate-enriched. •Ni, As and Cr were above ERL values.

Distribution, sources and ecological risk assessment of PAHs in surface sediments from the Luan River Estuary, China.

Science.gov (United States)

Zhang, Daolai; Liu, Jinqing; Jiang, Xuejun; Cao, Ke; Yin, Ping; Zhang, Xunhua

2016-01-15

The distribution, sources and risk assessment of 16 polycyclic aromatic hydrocarbons (PAHs) of surface sediments in the Luan River Estuary, China, have been investigated in the research. The results indicated that the total concentrations of 16 PAHs in surface sediments of the Luan River Estuary ranged from 5.1 to 545.1 ng g(-1)dw with a mean value of 120.8 ng g(-1)dw, which is relatively low in comparison with other estuaries around the world. The PAHs in the study area were mainly originated from pyrogenic sources. Besides, PAHs may be contaminated by petrogenic PAHs as indicated by the selected ratios of PAHs, the 2-tailed Pearson correlation analysis and principal components analysis at different sites. The result of the ecological risk assessment shows little negative effect for most individual PAHs in surface sediments of the Luan River Estuary, China. Copyright © 2015 Elsevier Ltd. All rights reserved.

Early steroid sulfurization in surface sediments of a permanently stratified lake (Ace Lake, Antarctica)

Science.gov (United States)

Kok, Marika D.; Rijpstra, W. Irene C.; Robertson, Lisette; Volkman, John K.; Sinninghe Damstéé, Jaap S.

2000-04-01

Surface sediments (0-25 cm) from Ace Lake (eastern Antarctica), a saline euxinic lake, were analyzed to study the early incorporation of reduced inorganic sulfur species into organic matter. The apolar fractions were shown to consist predominantly of dimeric (poly)sulfide linked C 27-C 29 steroids. These steroid moieties were identified by GC-MS analysis of the apolar fractions after cleavage of polysulfide linkages using MeLi and MeI and after desulfurisation. The polar fractions contained the oligomeric analogues. The S-bound steroids are most likely formed by sulfur incorporation into steroidal ketones formed from Δ 5 sterols by biohydrogenation by anaerobic bacteria. The concentrations of these sulfurised steroids increased with depth in the sediment. The sulfurisation reaction is completed in 1000-3000 years. Despite a wide range of functionalised lipids present in these sediments that are potentially available for sulfurisation, there is a very strong preference for the incorporation of sulfur into steroidal compounds. A predominance of sulfurised C 27 steroids contrasted with the distribution of free sterols, which showed a strong predominance of C 29 sterols. This indicates that the incorporation of sulfur is biased towards C 27 sterols. The results demonstrate that intermolecular sulfurisation of organic matter can occur in surface sediments at low temperatures and in the absence of light.

Accumulation of Trace Metal Elements (Cu, Zn, Cd, and Pb in Surface Sediment via Decomposed Seagrass Leaves: A Mesocosm Experiment Using Zostera marina L.

Directory of Open Access Journals (Sweden)

Shinya Hosokawa

Full Text Available Accumulation of Cu, Zn, Cd, and Pb in the sediment of seagrass ecosystems was examined using mesocosm experiments containing Zostera marina (eelgrass and reference pools. Lead was approximately 20-fold higher in the surface sediment in the eelgrass pool than in eelgrass leaves and epiphytes on the eelgrass leaves, whereas zinc and cadmium were significantly lower in the surface sediment than in the leaves, with intermediate concentrations in epiphytes. Copper concentrations were similar in both the surface sediment and leaves but significantly lower in epiphytes. Carbon and nitrogen contents increased significantly with increasing δ13C in surface sediments of both the eelgrass and reference pools. Copper, Zn, Cd, and Pb also increased significantly with increasing δ13C in the surface sediment in the eelgrass pool but not in the reference pool. By decomposition of eelgrass leaves with epiphytes, which was examined in the eelgrass pool, copper and lead concentrations increased more than 2-fold and approximately a 10-fold, whereas zinc and cadmium concentrations decreased. The high copper and lead concentrations in the surface sediment result from accumulation in decomposed, shed leaves, whereas zinc and cadmium remobilized from decomposed shed leaves but may remain at higher concentrations in the leaves than in the original sediments. The results of our mesocosm study demonstrate that whether the accumulation or remobilization of trace metals during the decomposition of seagrass leaves is trace metal dependent, and that the decomposed seagrass leaves can cause copper and lead accumulation in sediments in seagrass ecosystems.

Polycyclic aromatic hydrocarbons (PAHs) in surface sediments of two lakes of the Dongting Lake district in Hunan, China

Science.gov (United States)

He, Jiang; Yang, Yajing; Zhang, Lugang; Luo, Yushuang; Liu, Fei; Yang, Pinhong

2018-04-01

In this paper, 18 and 12 surface sediment samples were collected from Datong Lake and Shanpo Lake, respectively, and the 16 USEPA priority Polycyclic aromatic hydrocarbons (PAHs) in these samples were detected. The result indicated that the Σ16PAHs ranged from 206.56 to 1058.98 ng.g-1 with an average concentration of 667.22 ng.g-1 in sediments from Datong Lake, whereas it ranged from 90.62 to 900.70 ng.g-1 with an average concentration of 364.97 ng.g-1 in sediments from Shanpo Lake. The concentrations of individual PAHs in sediments ranged from 5.50 to 85.23 and from 4.39 to 52.74 ng.g-1 in Datong Lake and Shanpo Lake, respectively. According to the indexes such as HMW/LMW, Ant/(Ant+Phe), Flua/(Flua+Pyr), IcdP/(IcdP+BghiP), and BaA/(BaA+Chr), the PAHs in sediments from both lakes are mainly of pyrogenic origin. The total BaP equivalent in the surface sediment samples from Datong Lake and Shanpo Lake is 42.77 and 33.35 ng.g-1, respectively.

Contamination assessment of heavy metal in surface sediments of the Wuding River, northern China

International Nuclear Information System (INIS)

Longjiang, M.; Qiang, F.; Duowen, M.; Ke, H.; Jinghong, Y.

2011-01-01

The heavy metal contents and the contamination levels of the surface sediments of the Wuding River, northern China, were investigated. Heavy metal concentration ranged in μg g -1 : 50.15 - 71.91 for Cr, 408.1 - 442.9 for Mn, 20.11 - 43.59 for Ni, 17.51 - 20.1 for Cu, 68.32 - 89.57 for Zn, 0.2 - 0.38 for Cd and 15.08 - 16.14 for Pb in the Wuding River sediments. The enrichment factor (EF) and the geo-accumulation index (Igeo) demonstrated that the sediments of the Wuding River had been polluted by Cd, Cr and Ni, which mainly originated from anthropogenic sources, whereas the sediments had not been polluted by Zn, Pb, Cu and Mn, which were derived from the crust. In addition, the assessment results of EF and Igeo suggested that the sediments of the Wuding River was 'moderately' polluted by Cd and 'unpolluted to moderately' polluted by Cr and Ni. The elevated urban sewage discharges and agriculture fertilizers usage in river basin are the anthropogenic sources of these heavy metals in river. (author)

Diverse plant and animal genetic records from Holocene and Pleistocene sediments

DEFF Research Database (Denmark)

Willerslev, E.; Hansen, Anders J.; Binladen, J.

2003-01-01

Genetic analyses of permafrost and temperate sediments reveal that plant and animal DNA may be preserved for long periods, even in the absence of obvious macrofossils. In Siberia, five permafrost cores ranging from 400,000 to 10,000 years old contained at least 19 different plant taxa, including...... the oldest authenticated ancient DNA sequences known, and megafaunal sequences including mammoth, bison, and horse. The genetic data record a number of dramatic changes in the taxonomic diversity and composition of Beringian vegetation and fauna. Temperate cave sediments in New Zealand also yielded DNA...

Heavy metals in surface sediments of the Jialu River, China: Their relations to environmental factors

Energy Technology Data Exchange (ETDEWEB)

Fu, Jie [State Key Laboratory of Pharmaceutical Biotechnology, School of Life Sciences, Nanjing University, Nanjing 210093 (China); Environmental Engineering Program, Department of Civil Engineering, Auburn University, Auburn, AL 36849 (United States); Zhao, Changpo [State Key Laboratory of Pharmaceutical Biotechnology, School of Life Sciences, Nanjing University, Nanjing 210093 (China); Luo, Yupeng [Department of Mathematics and Statistics, Auburn University, Auburn, AL 36849 (United States); Liu, Chunsheng, E-mail: liuchunshengidid@126.com [College of Fisheries, Huazhong Agricultural University, Wuhan 430070 (China); Kyzas, George Z. [Laboratory of General and Inorganic Chemical Technology, Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki 54124 (Greece); Luo, Yin [State Key Laboratory of Pharmaceutical Biotechnology, School of Life Sciences, Nanjing University, Nanjing 210093 (China); Zhao, Dongye [Environmental Engineering Program, Department of Civil Engineering, Auburn University, Auburn, AL 36849 (United States); An, Shuqing [State Key Laboratory of Pharmaceutical Biotechnology, School of Life Sciences, Nanjing University, Nanjing 210093 (China); Zhu, Hailiang, E-mail: zhuhl@nju.edu.cn [State Key Laboratory of Pharmaceutical Biotechnology, School of Life Sciences, Nanjing University, Nanjing 210093 (China)

2014-04-01

Highlights: • Zhengzhou City had major effect on the pollution of the Jialu River. • TN, OP, TP and COD{sub Mn} in water drove heavy metals to deposit in sediments. • B-IBI was sensitive to the adverse effect of heavy metals in sediments. - Abstract: This work investigated heavy metal pollution in surface sediments of the Jialu River, China. Sediment samples were collected at 19 sites along the river in connection with field surveys and the total concentrations were determined using atomic fluorescence spectrometer and inductively coupled plasma optical emission spectrometer. Sediment samples with higher metal concentrations were collected from the upper reach of the river, while sediments in the middle and lower reaches had relatively lower metal concentrations. Multivariate techniques including Pearson correlation, hierarchical cluster and principal components analysis were used to evaluate the metal sources. The ecological risk associated with the heavy metals in sediments was rated as moderate based on the assessments using methods of consensus-based Sediment Quality Guidelines, Potential Ecological Risk Index and Geo-accumulation Index. The relations between heavy metals and various environmental factors (i.e., chemical properties of sediments, water quality indices and aquatic organism indices) were also studied. Nitrate nitrogen, total nitrogen, and total polycyclic aromatic hydrocarbons concentrations in sediments showed a co-release behavior with heavy metals. Ammonia nitrogen, total nitrogen, orthophosphate, total phosphate and permanganate index in water were found to be related to metal sedimentation. Heavy metals in sediments posed a potential impact on the benthos community.

Heavy metals in surface sediments of the Jialu River, China: Their relations to environmental factors

International Nuclear Information System (INIS)

Fu, Jie; Zhao, Changpo; Luo, Yupeng; Liu, Chunsheng; Kyzas, George Z.; Luo, Yin; Zhao, Dongye; An, Shuqing; Zhu, Hailiang

2014-01-01

Highlights: • Zhengzhou City had major effect on the pollution of the Jialu River. • TN, OP, TP and COD Mn in water drove heavy metals to deposit in sediments. • B-IBI was sensitive to the adverse effect of heavy metals in sediments. - Abstract: This work investigated heavy metal pollution in surface sediments of the Jialu River, China. Sediment samples were collected at 19 sites along the river in connection with field surveys and the total concentrations were determined using atomic fluorescence spectrometer and inductively coupled plasma optical emission spectrometer. Sediment samples with higher metal concentrations were collected from the upper reach of the river, while sediments in the middle and lower reaches had relatively lower metal concentrations. Multivariate techniques including Pearson correlation, hierarchical cluster and principal components analysis were used to evaluate the metal sources. The ecological risk associated with the heavy metals in sediments was rated as moderate based on the assessments using methods of consensus-based Sediment Quality Guidelines, Potential Ecological Risk Index and Geo-accumulation Index. The relations between heavy metals and various environmental factors (i.e., chemical properties of sediments, water quality indices and aquatic organism indices) were also studied. Nitrate nitrogen, total nitrogen, and total polycyclic aromatic hydrocarbons concentrations in sediments showed a co-release behavior with heavy metals. Ammonia nitrogen, total nitrogen, orthophosphate, total phosphate and permanganate index in water were found to be related to metal sedimentation. Heavy metals in sediments posed a potential impact on the benthos community

Updating the New Zealand Glacier Inventory

Science.gov (United States)

Baumann, S. C.; Anderson, B.; Mackintosh, A.; Lorrey, A.; Chinn, T.; Collier, C.; Rack, W.; Purdie, H.

2017-12-01

The last complete glacier inventory of New Zealand dates from the year 1978 (North Island 1988) and was manually constructed from oblique aerial photographs and geodetic maps (Chinn 2001). The inventory has been partly updated by Gjermundsen et al. (2011) for the year 2002 (40% of total area) and by Sirguey & More (2010) for the year 2009 (32% of total area), both using ASTER satellite imagery. We used Landsat 8 OLI/TIRS satellite data from February/March 2016 to map the total glaciated area. Clean and debris-covered ice were mapped semi-automatically. The band ratio approach was used for clean ice (ratio: red/SWIR). We mapped debris-covered ice using a supervised classification (maximum likelihood). Manual post processing was necessary due to misclassifications (e.g. lakes, clouds) or mapping in shadowed areas. It was also necessary to manually combine the clean and debris-covered parts into single glaciers. Additional input data for the post processing were Sentinel 2 images from the same time period, orthophotos from Land Information New Zealand (resolution: 0.75 m, date: Nov 2014), and the 1978/88 outlines from the GLIMS database (http://www.glims.org/). As the Sentinel 2 data were more heavily cloud covered compared to the Landsat 8 images, they were only used for post processing and not for the classification itself. Initial results show that New Zealand glaciers covered an area of about 1050 km² in 2016, a reduction of 16% since 1978. Approximately 17% of glacier area was covered in surface debris. The glaciers in the central Southern Alps around Mt Cook reduced in area by 24%. Glaciers in the North Island of New Zealand reduced by 71% since 1988, and only 2 km² of ice cover remained in 2016. Chinn, TJH (2001). "Distribution of the glacial water resources of New Zealand." Journal of Hydrology (NZ) 40(2): 139-187 Gjermundsen, EF, Mathieu, R, Kääb, A, Chinn, TJH, Fitzharris, B & Hagen, JO (2011). "Assessment of multispectral glacier mapping methods and

Heavy metals in the surface sediments of lakes on the Tibetan Plateau, China.

Science.gov (United States)

Guo, Bixi; Liu, Yongqin; Zhang, Fan; Hou, Juzhi; Zhang, Hongbo; Li, Chaoliu

2018-02-01

Heavy metal contamination has affected many regions in the world, particularly the developing countries of Asia. We investigated 8 heavy metals (Cu, Zn, Cd, Pb, Cr, Co, Ni, and As) in the surface sediments of 18 lakes on the Tibetan Plateau. It was found that the distributions of the heavy metals showed no clear spatial pattern on the plateau. The results indicated that the mean concentrations of these metals in the sediment samples diminished as follows: Cr > As > Zn > Ni > Pb > Cu > Co > Cd. The results of geoaccumulation index (I geo ) and potential ecological risk factor (E i r ) assessments showed that the sediments were moderately polluted by Cd and As, which posed much higher risks than the other metals. The values of the potential ecological risk index (RI) showed that lake Bieruoze Co has been severely polluted by heavy metals. Principal component analysis, hierarchical cluster analysis, and Pearson correlation analysis results indicated that the 8 heavy metals in the lake surface sediments of the Tibetan Plateau could be classified into four groups. Group 1 included Cu, Zn, Pb, Co, and Ni which were mainly derived from both natural and traffic sources. Group 2 included Cd which mainly originated from anthropogenic sources like alloying, electroplating, and dyeing industries and was transported to the Tibetan Plateau by atmospheric circulation. Group 3 included Cr and it might mainly generate from parent rocks of watersheds. The last Group (As) was mainly from manufacturing, living, and the striking deterioration of atmospheric environment of the West, Central Asia, and South Asia.

Different Planctomycetes diversity patterns in latitudinal surface seawater of the open sea and in sediment.

Science.gov (United States)

Shu, Qinglong; Jiao, Nianzhi

2008-04-01

The 16S rRNA gene approach was applied to investigate the diversity of Planctomycetes in latitudinal surface seawater of the Western Pacific Ocean. The results revealed that the Pirellula-Rhodopirellula-Blastopirellula clade dominated the Planctomycetes community at all surface seawater sites while the minority genera Gemmata and Planctomyces were only found at sites H5 and H2 respectively. Although the clone frequency of the PRB clade seemed stable (between 83.3% and 94.1%) for all surface seawater sites, the retrieved Pirellula-Rhodopirellula-Blastopirellula clade presented unexpected diversity. Interestingly, low latitude seawater appeared to have higher diversity than mid-latitudes. integral-LIBSHUFF software analysis revealed significantly different diversity patterns between in latitudinal surface seawater and in the sediment of South China Sea station M2896. Our data suggested that different hydrological and geographic features contributed to the shift of Planctomycetes diversity in marine environments. This is, to our knowledge, the first systematic assessment of Planctomycetes in latitudinal surface seawater of the open sea and the first comparison of diversity pattern between surface seawater and sediments and has broadened our understanding of Planctomycetes diversity in marine environments.

Soil aggregate stability and size-selective sediment transport with surface runoff as affected by organic residue amendment.

Science.gov (United States)

Shi, Pu; Arter, Christian; Liu, Xingyu; Keller, Martin; Schulin, Rainer

2017-12-31

Aggregate breakdown influences the availability of soil particles for size-selective sediment transport with surface runoff during erosive rainfall events. Organic matter management is known to affect aggregate stability against breakdown, but little is known about how this translates into rainfall-induced aggregate fragmentation and sediment transport under field conditions. In this study, we performed field experiments in which artificial rainfall was applied after pre-wetting on three pairs of arable soil plots (1.5×0.75m) six weeks after incorporating a mixture of grass and wheat straw into the topsoil of one plot in each pair (OI treatment) but not on the other plot (NI treatment). Artificial rainfall was applied for approximately 2h on each pair at an intensity of 49.1mmh -1 . In both treatments, discharge and sediment concentration in the discharge were correlated and followed a similar temporal pattern after the onset of surface runoff: After a sharp increase at the beginning both approached a steady state. But the onset of runoff was more delayed on the OI plots, and the discharge and sediment concentration were in average only roughly half as high on the OI as on the NI plots. With increasing discharge the fraction of coarse sediment increased. This relationship did not differ between the two treatments. Thus, due to the lower discharge, the fraction of fine particles in the exported sediment was larger in the runoff from the OI plots than from the NI plots. The later runoff onset and lower discharge rate was related to a higher initial aggregate stability on the OI plots. Terrestrial laser scanning proved to be a very valuable method to map changes in the micro-topography of the soil surfaces. It revealed a much less profound decrease in surface roughness on the OI than on the NI plots. Copyright © 2017 Elsevier B.V. All rights reserved.

A preliminary investigation of the distribution of heavy metals in surface sediments of the Cona tidal marsh (Venice Lagoon)

International Nuclear Information System (INIS)

Bernardi, S.; Costa, F.; Vazzoler, S.; Zonta, R.

1988-01-01

Data are from the two series of surface sediment sampling in an interface area between the Venice Lagoon and the mainland. The distribution of heavy metals gives a correlation with polluted sourcesites-identified in the channel systems with a highly polluted input-and allows us to identify the localities of accumulation. Restricted to the estuary of the river tributary transporting a high concentration of pollutants into a tidal marsh area of the lagoon, the study shows the effect of the fresh water forcing to distribute heavy metals on surface sediments. Within the scope of this preliminary investigation, indications from sampling identify a sector of the 'palude of Cona' in this estuary, which is highly suitable for detailed studies on precesses affecting heavy-metal distributions in bottom surface sediments of shallow-water areas

Distribution, enrichment and sources of thallium in the surface sediments of the southwestern coastal Laizhou Bay, Bohai Sea.

Science.gov (United States)

Zhuang, Wen; Gao, Xuelu

2015-07-15

The concentrations of thallium (Tl) in the surface sediments of the southwestern coastal Laizhou Bay and the rivers it connects were determined. In riverine sediments, the Tl concentrations ranged from 0.34 to 0.76 μg g(-1) in summer; in autumn, the corresponding data were 0.35-1.08 μg g(-1). In marine sediments, the Tl concentrations ranged from 0.36 to 0.58 μg g(-1) in summer; and from 0.30 to 0.56 μg g(-1) in autumn. The grain size, Al and Fe oxides were major factors affecting Tl distribution. Tl in the surface sediments of the studied area was mainly from the natural input with the non-natural input as a subsidiary source. The low concentrations of Tl made it hard to cause potential negative environmental effects in this area. Copyright © 2015 Elsevier Ltd. All rights reserved.

Sedimentation of bidisperse, uncharged colloidal sphere suspensions: Influence of viscosity and irregular surfaces

NARCIS (Netherlands)

Thies-Weesie, Dominique M. E.; Philipse, Albert P.; Lekkerkerker, Henk N. W.

1996-01-01

The sedimentation velocity of uncharged, nonaggregated silica spheres under gravity is strongly reduced after addition of small amounts of nonsedimenting small spheres. This reduction is largely due to surface irregularities on a nanoscale of the large spheres at which a limited number of small

Distribution of the rare earth elements in the surface sediments from the lower Wuding River of China

International Nuclear Information System (INIS)

Longjiang, M.; Duowen, M.; Ke, H.; Jinghong, Y.

2010-01-01

The abundance and distribution of rare earth elements (REE) and their signatures in the Wuding River of China were studied from samples of surface sediments and related to the geological formation in its watershed. The total REE (ΣREE) average concentrations of the Wuding River sediments (144.56 μg g -1 ), is lower than that in the Yangtze River sediments (167.10 μg g -1 ), getting closer to the values of the Yellow River sediments (137.76 μg g -1 ), being equivalent to the values of the UCC (the upper continental crust) (146.37 μg g-1). The chondrite-normalized REEs indicated LREE enrichment and flat HREE depletion and also showed a slightly negative Eu-anomaly. A similar chondrite-normalized REE distribution pattern between the Wuding River sediments and Yellow River sediments demonstrated the Wuding River sediments are the important material sources of the Yellow River sediments. UCC-normalized REE patterns between the Wuding River sediments and the Yellow River sediments were almost equivalent and close to the UCC. These implied the Wuding River sediments and the Yellow River sediments are subjected mostly to physical weathering due to higher erosion rates. Consequently, they can be used to trace the UCC compositions. (author)

What is the Source? Post-glacial sediment flux from the Waipaoa Catchment, New Zealand

Science.gov (United States)

Bilderback, E. L.; Pettinga, J. R.; Litchfield, N. J.; Quigley, M.; Marden, M.

2011-12-01

In the Waipaoa, and for much of the eastern North Island, the shift from the last glacial coldest period to the current interglacial climatic regime resulted in Late Pleistocene-Holocene catchment-wide channel incision (Berryman et al., 2000; Litchfield and Berryman, 2005). Only ~25% of the total post 18 ka sediment yield for the Waipaoa Catchment can be accounted for by channel incision, one of the most widespread and most effective erosive processes in the catchment (Orpin et al., 2006; Marden et al., 2008). We find that deep-seated landslides, which are pervasive, cannot make up this apparent source area sediment deficit. This presents a challenge to our current understanding of the Waipaoa Sedimentary System. New high resolution topographic data sets (lidar and photogrammetry) combined with tephrochronology and field mapping have enabled us to approximate the sediment flux from post 18 ka deep-seated landslides. The sediment delivered to the offshore sink from these upper Waipaoa landslides is likely to be less than 20% of the sediment volume calculated for channel incision. A further GIS analysis of the ~2500 km2 Waipaoa catchment using work from Crosby and Whipple (2006) delineating relict topography and Marden et al. (2008) accounting for river incision and slopes stabilized behind terrace remnants indicates that only about half of the available catchment area could have contributed additional large volumes of sediment to the offshore post 18 ka sink. The presence of tephra cover older than 18 ka on landforms ranging from flat ridgelines to steep (>30 degree) slopes in this remaining terrestrial source area suggests that it has not been eroded en mass. The apparent source deficit remains even though many of the major erosive processes available to fill this deficit have been studied and the potentially contributing catchment area is dramatically reduced by these studies. This analysis raises questions about erosive processes and our ability to balance large

Spatial glyphosate and AMPA redistribution on the soil surface driven by sediment transport processes - A flume experiment.

Science.gov (United States)

Bento, Célia P M; Commelin, Meindert C; Baartman, Jantiene E M; Yang, Xiaomei; Peters, Piet; Mol, Hans G J; Ritsema, Coen J; Geissen, Violette

2018-03-01

This study investigates the influence of small-scale sediment transport on glyphosate and AMPA redistribution on the soil surface and on their off-site transport during water erosion events. Both a smooth surface (T1) and a surface with "seeding lines on the contour" (T2) were tested in a rainfall simulation experiment using soil flumes (1 × 0.5 m) with a 5% slope. A dose of 178 mg m -2 of a glyphosate-based formulation (CLINIC ® ) was applied on the upper 0.2 m of the flumes. Four 15-min rainfall events (RE) with 30-min interval in between and a total rainfall intensity of 30 mm h -1 were applied. Runoff samples were collected after each RE in a collector at the flume outlet. At the end of the four REs, soil and sediment samples were collected in the application area and in four 20 cm-segments downslope of the application area. Samples were collected according to the following visually distinguished soil surface groups: light sedimentation (LS), dark sedimentation (DS), background and aggregates. Results showed that runoff, suspended sediment and associated glyphosate and AMPA off-site transport were significantly lower in T2 than in T1. Glyphosate and AMPA off-site deposition was higher for T2 than for T1, and their contents on the soil surface decreased with increasing distance from the application area for all soil surface groups and in both treatments. The LS and DS groups presented the highest glyphosate and AMPA contents, but the background group contributed the most to the downslope off-site deposition. Glyphosate and AMPA off-target particle-bound transport was 9.4% (T1) and 17.8% (T2) of the applied amount, while water-dissolved transport was 2.8% (T1) and 0.5% (T2). Particle size and organic matter influenced the mobility of glyphosate and AMPA to off-target areas. These results indicate that the pollution risk of terrestrial and aquatic environments through runoff and deposition can be considerable. Copyright © 2017 Elsevier Ltd

Heavy metal pollution and Pb isotopic tracing in the intertidal surface sediments of Quanzhou Bay, southeast coast of China

International Nuclear Information System (INIS)

Yu, Ruilian; Zhang, Weifang; Hu, Gongren; Lin, Chengqi; Yang, Qiuli

2016-01-01

Concentrations of 16 heavy metals and Pb isotopic ratios in the intertidal surface sediments of Quanzhou Bay were determined to study the pollution level of heavy metals and the sources of Pb. The results showed that most concentrations of Cd, Sn, Mn, Cu, Zn, Cr, Pb, Hg, Ni, Co, Cs, Fe and V were higher than the background values, while most concentrations of Ti, Sb and Sr were lower than the background values. The mean concentrations of Cu, Zn, Pb, Cr and Cd exceeded the first-grade criteria of Chinese marine sediment quality. The geo-accumulation indexes revealed that the sediments had been polluted by some heavy metals. The results of Pb isotopic tracing indicated that the total Pb in the sediments were mainly from parent material, industrial emission and vehicle exhaust with the mean contributions of 38.2%, 51.3% and 10.5%, respectively, calculated by a three-end-member model of Pb isotopic ratios. - Highlights: •Level of 16 heavy metals in intertidal surface sediments of Quanzhou Bay was studied. •The sediments had been polluted by some heavy metals including Pb. •Pb isotopic compositions in the sediments and the potential sources were determined. •A three-end member model was applied to estimate the contributions of Pb sources. •Industrial emission was the major anthropogenic Pb contributor in the sediments.

Radiolarian abundance and geochemistry of the surface-sediments from the Central Indian Basin: Inferences to Antarctic bottom water current

Digital Repository Service at National Institute of Oceanography (India)

Gupta, S.M.; Jauhari, P.

The distribution trend of numbers of radiolarian shells/gram dry sediment, biogenic silica, organic carbon, and the carbon/nitrogen ratios in the surface sediments of the Central Indian Basin is similar. Ratios of two suborders of radiolaria, i...

Geochemistry and Nd-isotope systematics of chemical and terrigenous sediments from the Dun Mountain Ophiolite, New Zealand

International Nuclear Information System (INIS)

Sivell, W.J.

2002-01-01

Two sedimentary associations closely related to temporally discrete ophiolitic magma suites occur within the Early Permian Dun Mountain Ophiolite Belt (DMOB), New Zealand. These are: (1) a suite of diverse chemical sediments and turbidite argillites (TA) that bear an intimate depositional relationship to early-formed pillow lavas (back-arc basin basalts); and (2) a younger, lithic-dominated, bimodal, coarse sandstone-ophiolitic rudite assemblage of proximal turbidite/mass-flow origin, rich in clasts of infant-arc magmas which comprise the bulk of the ophiolite. There are four groups of DMOB chemical sediments. Red hematitic chert (group 1) fills interstices between basalt pillows, and black nodular Fe-Mn deposits (group 2) occur along pillow lava/sediment interfaces. These facies are overlain by red mudstones (group 3), and mottled orange-olive brown mudstones (altered hyaloclastites; group 4). Geochemical features (including REE contents, Fe/Ti and transition ratios) indicate that the cherts reflect silica and metalliferous contributions to sea water, promoted by low-temperature hydrothermal alteration of glassy basalt, while group 4 muds represent residual components in halmyrolytically altered volcanic glass. Transition metal and REE enrichments in group 2 nodules (with high Ce/Ce*, Ni/Fe, and Cu/Fe ratios) reflect hydrogenous chemisorption to a hydothermal component (with high Ba and Sr). The nodules possess ε Nd (T) values (c. 0) identical to those calculated for Permian sea water. Group 3 red muds have lower ε Nd (T) = -1 to -2, and Nd model ages (T) Nd DM) that indicate contributions from continentally derived fluvial particulate fallout of mean Proterozoic age. For the nodules and red muds, strong negative correlations between Mn/Fe, Nd, Ce*/Ce, and ε Nd (T) are attributed to increasing diagenetic influence in the muds. ε Nd (T) values (c. +2) in group 4 muds are transitional toward higher values in their (hyaloclastite) basalt glass precursors

Phosphorus forms of the surface sediment in the Iranian coast of the southern Caspian Sea

OpenAIRE

Nasrollahzadeh Saravi, H.; Pouraria, A.; Nowruzi, B.

2015-01-01

Sediments from the southern Caspian Sea, located in Iranian coast were examined on the basis of P-fractionation (five forms of phosphorus) by a sequential extraction scheme. Ninety-six surface sediment samples (for each season with triplicate) were collected from eight sampling transects in 10 and 100 m depths during summer and winter in 2010-2011. The result indicated that the most abundant forms of phosphorus were calcium bound phosphorus. Relative abundance of other forms of phosphorus fol...

Evaluation and assessment of baseline metal contamination in surface sediments from the Bernam River, Malaysia.

Science.gov (United States)

Kadhum, Safaa A; Ishak, Mohd Yusoff; Zulkifli, Syaizwan Zahmir

2016-04-01

The Bernam River is one of the most important rivers in Malaysia in that it provides water for industries and agriculture located along its banks. The present study was conducted to assess the level of contamination of heavy metals (Cd, Ni, Cr, Sn, and Fe) in surface sediments in the Bernam River. Nine surface sediment samples were collected from the lower, middle, and upper courses of the river. The results indicated that the concentrations of the metals decreased in the order of Sn > Cr > Ni > Fe > Cd (56.35, 14.90, 5.3, 4.6, and 0.62 μg/g(1) dry weight). Bernam River sediments have moderate to severe enrichment for Sn, moderate for Cd, and no enrichment for Cr, Ni, and Fe. The contamination factor (CF) results demonstrated that Cd and Sn are responsible for the high contamination. The pollution load index (PLI), for all the sampling sites, suggests that the sampling stations were generally unpolluted with the exception of the Bagan Tepi Sungai, Sabak Bernam, and Tanjom Malim stations. Multivariate techniques including Pearson's correlation and hierarchical cluster analysis were used to apportion the various sources of the metals. The results suggested that the sediment samples collected from the upper course of the river had lower metal concentrations, while sediments in the middle and lower courses of the river had higher metal concentrations. Therefore, our results can be useful as a baseline data for government bodies to adopt corrective measure on the issues related to heavy metal pollution in the Bernam River in the future.

Nickel, Lead and Zinc Contamination in the Surface Sediments of Agh Gel Wetland, Iran

Directory of Open Access Journals (Sweden)

Soheil Sobhan Ardakani

2016-07-01

Full Text Available Background & Aims of the Study: Due to the increased human activities around the Agh Gel wetland, this study aimed to measured accumulations of heavy metals (Ni, Pb and Zn in the surface sediment samples taken from this wetland. Materials & Methods: Samples were taken from 10 stations and exposed to bulk digestion and chemical partitioning. Finally, Ni, Pb and Zn concentrations were monitored with ICP-OES in the sediments. Also, geo-accumulation index, contamination factor and pollution load index were used to evaluate the magnitude of contaminants in the sediment profile. Results: The results showed, the average of metal concentration in samples (mg kg-1 wet weight were 34.20±3.58 for Ni, 25.37±2.52 for Pb and 127.20±15.21 for Zn, respectively. Therefore, the pattern of metal concentrations in sediment was determined as Zinc>Nickel >Lead. According to the mean I-geo values, sediments' qualities are classified as unpolluted category for Ni and Pb. Also, sediment's quality is classified as unpolluted to moderately polluted for Zn. The CF values for all elements are classified as moderate contamination. The PLI values indicated that metal pollution exists for all sampling stations. Conclusions: The obtained results indicated that the Agh Gel wetland has a potential to threaten by chemical pollutants such as agricultural effluent. So, in order to preserve the environment of the Agh Gel wetland from deterioration, monitoring of water and sediment qualities is recommended periodically.

Characterization of the intragranular water regime within subsurface sediments: pore volume, surface area, and mass transfer limitations

Science.gov (United States)

Hay, Michael B.; Stoliker, Deborah L.; Davis, James A.; Zachara, John M.

2011-01-01

Although "intragranular" pore space within grain aggregates, grain fractures, and mineral surface coatings may contain a relatively small fraction of the total porosity within a porous medium, it often contains a significant fraction of the reactive surface area, and can thus strongly affect the transport of sorbing solutes. In this work, we demonstrate a batch experiment procedure using tritiated water as a high-resolution diffusive tracer to characterize the intragranular pore space. The method was tested using uranium-contaminated sediments from the vadose and capillary fringe zones beneath the former 300A process ponds at the Hanford site (Washington). Sediments were contacted with tracers in artificial groundwater, followed by a replacement of bulk solution with tracer-free groundwater and the monitoring of tracer release. From these data, intragranular pore volumes were calculated and mass transfer rates were quantified using a multirate first-order mass transfer model. Tritium-hydrogen exchange on surface hydroxyls was accounted for by conducting additional tracer experiments on sediment that was vacuum dried after reaction. The complementary ("wet" and "dry") techniques allowed for the simultaneous determination of intragranular porosity and surface area using tritium. The Hanford 300A samples exhibited intragranular pore volumes of ~1% of the solid volume and intragranular surface areas of ~20%–35% of the total surface area. Analogous experiments using bromide ion as a tracer yielded very different results, suggesting very little penetration of bromide into the intragranular porosity.

Coupled penetrometer, MBES and ADCP assessments of tidal variations of the surface sediment layer along active subaqueous dunes, Danish Wadden Sea

DEFF Research Database (Denmark)

Stark, Nina; Hanff, Henrik; Svenson, Christian

2011-01-01

In-situ geotechnical measurements of surface sediments were carried out along large subaqueous dunes in the Knudedyb tidal inlet channel in the DanishWadden Sea using a small free-falling penetrometer. Vertical profiles showed a typical stratification pattern with a resolution of ~1 cm depicting...... a thin surface layer of low sediment strength and a stiffer substratum below (quasi-static bearing capacity equivalent: 1–3 kPa in the top layer, 20–140 kPa in the underlying sediment; thickness of the top layer ca. 5–8 cm). Observed variations in the thickness and strength of the surface layer during...... a tidal cycle were compared to mean current velocities (measured using an acoustic Doppler current profiler, ADCP), high-resolution bathymetry (based on multibeam echo sounding, MBES) and qualitative estimates of suspended sediment distributions in the water column (estimated from ADCP backscatter...

Source-to-Sink System Evolution as Recorded in Clastic Facies in Two New Zealand Examples: the Bounty System of South Island and the Waipaoa System of North Island

Science.gov (United States)

Marsaglia, K. M.

2010-12-01

New Zealand river sources and their submarine sinks are excellent examples for modeling source-to-sink systems. In particular, the sand fractions of these systems can be used as tracers to document links and/or disconnects between fluvial, shelf, slope, and bathyal components. Within any given system, the ability to use sand as a tracer depends on the nature of the rocks exposed in source river drainage basins. In evolving systems, the potential for erosional unroofing, change of outcrop lithology through time, can be important. Additionally, the ability of a given lithology to generate sediment of a certain size may also vary. For example in the New Zealand examples, Cenozoic mudstones generate mostly mud but can liberate recycled sand grains (if present), as well as a smaller proportion of mudstone lithic fragments depending on degree of mudstone induration; schist generates copious sand and quartz-vein pebbles; and thin-bedded sandy turbidites can generate significant gravel, as well as mud and sand. Sediment production mode also comes into play with glacial processes (South Island) generating rock flour, as well as coarser debris. The major outcropping unit across both islands is a sedimentary to metasedimentary forearc succession, the Torlesse Terrane. It served as the protolith of the Otago schist (South Island) and the source of detritus for Cretaceous and Cenozoic sedimentary units on both islands. Local magmatism also supplied sand-sized material: intraplate (South Island) volcanism produced intrabasinal epiclastic debris and magmatic arc (North Island) volcanism produced extrabasinal pyroclastic debris. Various lithologies have characteristic detrital signatures. For example, in the Cenozoic units of the Waipaoa system, Pliocene calcareous mudstone fragments are key lithic components in tracing sediment transport from source-to sink, whereas the major fingerprint of Otago schist input into the Bounty System of South Island is mica. Critical to defining

Distribution of branched GDGTs in surface sediments from the Colville River, Alaska: Implications for the MBT'/CBT paleothermometer in Arctic marine sediments

Science.gov (United States)

Hanna, Andrea J. M.; Shanahan, Timothy M.; Allison, Mead A.

2016-07-01

Significant climate fluctuations in the Arctic over the recent past, and additional predicted future temperature changes, highlight the need for high-resolution Arctic paleoclimate records. Arctic coastal environments supplied with terrigenous sediment from Arctic rivers have the potential to provide annual to subdecadal resolution records of climate variability over the last few millennia. A potential tool for paleotemperature reconstructions in these marine sediments is the revised methylation index of branched tetraethers (MBT')/cyclization ratio of branched tetraethers (CBT) proxy based on branched glycerol dialkyl glycerol tetraethers (brGDGTs). In this study, we examine the source of brGDGTs in the Colville River, Alaska, and the adjacent Simpson Lagoon and reconstruct temperatures from Simpson Lagoon sediments to evaluate the applicability of this proxy in Arctic estuarine environments. The Colville catchment soils, fluvial sediments, and estuarine sediments contain statistically similar brGDGT distributions, indicating that the brGDGTs throughout the system are soil derived with little alteration from in situ brGDGT production in the river or coastal waters. Temperatures reconstructed from the MBT'/CBT indices for surface samples show good agreement with regional summer (June through September) temperatures, suggesting a seasonal bias in Arctic temperature reconstructions from the Colville system. In addition, we reconstruct paleotemperatures from an estuarine sediment core that spans the last 75 years, revealing an overall warming trend in the twentieth century that is consistent with trends observed in regional instrumental records. These results support the application of this brGDGT-based paleotemperature proxy for subdecadal-scale summer temperature reconstructions in Arctic estuaries containing organic material derived from sediment-laden, episodic rivers.

Applying machine learning to global surface ocean and seabed data to reveal the controls on the distribution of deep-sea sediments

Science.gov (United States)

Dutkiewicz, Adriana; Müller, Dietmar; O'Callaghan, Simon

2017-04-01

World's ocean basins contain a rich and nearly continuous record of environmental fluctuations preserved as different types of deep-sea sediments. The sediments represent the largest carbon sink on Earth and its largest geological deposit. Knowing the controls on the distribution of these sediments is essential for understanding the history of ocean-climate dynamics, including changes in sea-level and ocean circulation, as well as biological perturbations. Indeed, the bulk of deep-sea sediments comprises the remains of planktonic organisms that originate in the photic zone of the global ocean implying a strong connection between the seafloor and the sea surface. Machine-learning techniques are perfectly suited to unravelling these controls as they are able to handle large sets of spatial data and they often outperform traditional spatial analysis approaches. Using a support vector machine algorithm we recently created the first digital map of seafloor lithologies (Dutkiewicz et al., 2015) based on 14,400 surface samples. This map reveals significant deviations in distribution of deep-sea lithologies from hitherto hand-drawn maps based on far fewer data points. It also allows us to explore quantitatively, for the first time, the relationship between oceanographic parameters at the sea surface and lithologies on the seafloor. We subsequently coupled this global point sample dataset of 14,400 seafloor lithologies to bathymetry and oceanographic grids (sea-surface temperature, salinity, dissolved oxygen and dissolved inorganic nutrients) and applied a probabilistic Gaussian process classifier in an exhaustive combinatorial fashion (Dutkiewicz et al., 2016). We focused on five major lithologies (calcareous sediment, diatom ooze, radiolarian ooze, clay and lithogenous sediment) and used a computationally intensive five-fold cross-validation, withholding 20% of the data at each iteration, to assess the predictive performance of the machine learning method. We find that

Earth's portfolio of extreme sediment transport events

Science.gov (United States)

Korup, Oliver

2012-05-01

Quantitative estimates of sediment flux and the global cycling of sediments from hillslopes to rivers, estuaries, deltas, continental shelves, and deep-sea basins have a long research tradition. In this context, extremely large and commensurately rare sediment transport events have so far eluded a systematic analysis. To start filling this knowledge gap I review some of the highest reported sediment yields in mountain rivers impacted by volcanic eruptions, earthquake- and storm-triggered landslide episodes, and catastrophic dam breaks. Extreme specific yields, defined here as those exceeding the 95th percentile of compiled data, are ~ 104 t km- 2 yr- 1 if averaged over 1 yr. These extreme yields vary by eight orders of magnitude, but systematically decay with reference intervals from minutes to millennia such that yields vary by three orders of magnitude for a given reference interval. Sediment delivery from natural dam breaks and pyroclastic eruptions dominate these yields for a given reference interval. Even if averaged over 102-103 yr, the contribution of individual disturbances may remain elevated above corresponding catchment denudation rates. I further estimate rates of sediment (re-)mobilisation by individual giant terrestrial and submarine mass movements. Less than 50 postglacial submarine mass movements have involved an equivalent of ~ 10% of the contemporary annual global flux of fluvial sediment to Earth's oceans, while mobilisation rates by individual events rival the decadal-scale sediment discharge from tectonically active orogens such as Taiwan or New Zealand. Sediment flushing associated with catastrophic natural dam breaks is non-stationary and shows a distinct kink at the last glacial-interglacial transition, owing to the drainage of very large late Pleistocene ice-marginal lakes. Besides emphasising the contribution of high-magnitude and low-frequency events to the global sediment cascade, these findings stress the importance of sediment storage

Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments from the Bering Sea and western Arctic Ocean.

Science.gov (United States)

Zhao, Mengwei; Wang, Weiguo; Liu, Yanguang; Dong, Linsen; Jiao, Liping; Hu, Limin; Fan, Dejiang

2016-03-15

To analyze the distribution and sources of polycyclic aromatic hydrocarbons (PAHs) and evaluate their potential ecological risks, the concentrations of 16 PAHs were measured in 43 surface sediment samples from the Bering Sea and western Arctic Ocean. Total PAH (tPAH) concentrations ranged from 36.95 to 150.21 ng/g (dry weight). In descending order, the surface sediment tPAH concentrations were as follows: Canada Basin>northern Chukchi Sea>Chukchi Basin>southern Chukchi Sea>Aleutian Basin>Makarov Basin>Bering Sea shelf. The Bering Sea and western Arctic Ocean mainly received PAHs of pyrogenic origin due to pollution caused by the incomplete combustion of fossil fuels. The concentrations of PAHs in the sediments of the study areas did not exceed effects range low (ERL) values. Copyright © 2016 Elsevier Ltd. All rights reserved.

Environmental assessment of coastal surface sediments at Tarut Island, Arabian Gulf (Saudi Arabia).

Science.gov (United States)

Youssef, Mohamed; El-Sorogy, Abdelbaset; Al Kahtany, Khaled; Al Otiaby, Naif

2015-07-15

Thirty eight surface sediments samples have been collected in the area around Tarut Island, Saudi Arabian Gulf to determine the spatial distribution of metals, and to assess the magnitude of pollution. Total concentrations of Fe, Mn, As, B, Cd, Co, Cr, Cu, Hg, Mo, Pb, Se, and Zn in the sediments were measured using ICP-MS (Inductively Coupled Plasma-Mass Spectrometer). Nature of sediments and heavy metals distribution reflect marked changes in lithology, biological activities in Tarut bay. Very high arsenic concentrations were reported in all studied locations from Tarut Island. The concentrations of Mercury are generally high comparing to the reported values from the Gulf of Oman, Red Sea. The concentrations of As and Hg exceeded the wet threshold safety values (MEC, PEC) indicating possible As and Hg contamination. Dredging and land filling, sewage, and oil pollution are the most important sources of pollution in the study area. Copyright © 2015 Elsevier Ltd. All rights reserved.

Seasonal and spatial distribution of metals in surface sediment of an urban estuary

International Nuclear Information System (INIS)

Buggy, Conor J.; Tobin, John M.

2008-01-01

Aquatic pollution by metals is of concern because of various toxic effects to marine life. The Tolka Estuary, Co. Dublin, Ireland, is a typical Irish urban estuary. It has a significant metal loading originating from the urban environment. Results of a 25 month analysis of cadmium, copper, lead and zinc spatial and temporal distribution over 10 sample locations in this estuary are presented in this paper. Metal concentrations were analysed using differential pulse polarography. Significant seasonal and spatial trends in metal distribution were observed over the 25 months. Sediment metal concentrations gradually increased (30-120%) in spring to a maximum at the end of summer which was followed by a decrease in winter months (30-60%). Sediment organic matter (OM) concentrations exhibited similar seasonal trends and a positive correlation between OM and metal distributions was observed, implying OM had an influence on metal distributions over time. - Assessment and correlation of the seasonal and spatial distribution of metals and organic matter in surface sediment of an urban estuary

The role of C:N:P stoichiometry in affecting denitrification in sediments from agricultural surface and tile-water wetlands.

Science.gov (United States)

Grebliunas, Brian D; Perry, William L

2016-01-01

Nutrient stoichiometry within a wetland is affected by the surrounding land use, and may play a significant role in the removal of nitrate (NO3-N). Tile-drained, agricultural watersheds experience high seasonal inputs of NO3-N, but low phosphorus (PO4-P) and dissolved organic carbon (DOC) loads relative to surface water dominated systems. This difference may present stoichiometric conditions that limit denitrification within receiving waterways. We investigated how C:N:P ratios affected denitrification rates of sediments from tile-drained mitigation wetlands incubated for: 0, 5, 10, and 20 days. We then tested whether denitrification rates of sediments from surface-water and tile-drained wetlands responded differently to C:N ratios of 2:1 versus 4:1. Ratios of C:N:P (P tile-drained wetland sediments. Carbon limitation of denitrification became evident at elevated NO3-N concentrations (20 mg L(-1)). Denitrification measured from tile water and surface water wetland sediments increased significantly (P < 0.05) at the 2:1 and 4:1 C:N treatments. The results from both experiments suggest wetland sediments provide a limiting pool of labile DOC to maintain prolonged NO3-N removal. Also, DOC limitation became more evident at elevated NO3-N concentrations (20 mg L(-1)). Irrespective of NO3-N concentrations, P did not limit denitrification rates. In addition to wetting period, residence time, and maintenance of anaerobic conditions, the availability of labile DOC is playing an important limiting role in sediment denitrification within mitigation wetlands.

Temporal dynamics of urbanization-driven environmental changes explored by metal contamination in surface sediments in a restoring urban wetland park

Energy Technology Data Exchange (ETDEWEB)

Ma, Jun; Liu, Yi; Yu, Guangbin; Li, Hongbo [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Yu, Shen, E-mail: syu@iue.ac.cn [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Jiang, Yueping [The Management Committee of the National Xixi Wetland Park, Hangzhou 310013 (China); Li, Guilin [Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021 (China); Lin, Jinchang [The Management Committee of the National Xixi Wetland Park, Hangzhou 310013 (China)

2016-05-15

Highlights: • Urban-rural distribution pattern of metals in sediment faded out with urbanization. • Urban emissions were identified as sources of metal elevation in surface sediment. • Metal level homogenization with urbanization posed a moderate risk to the public. - Abstract: Spatial patterns of metal distribution along urban-rural or multi-city gradients indicate that the urbanization process directly lead to metal enrichment and contamination in the environments. However, it has not yet looked at homogenization dynamics of an urban-rural gradient pattern over time with urbanization process in an area. This study monitored anthropogenic metals (Cr, Cu, Pb, and Zn) in surface sediments from channels of a newly-opened National Wetland Park to elucidate the urbanization-driven dissolution of urban-rural gradient pattern between 2008 and 2011. Sixty-eight surface sediment samples were taken from these channels in July of both 2008 and 2011. Results showed that a spatial distribution pattern of total metal contents along the gradient of urbanization influence, evident in 2008, was homogenized in 2011 with the area development. The lead stable isotope ratio analysis identified anthropogenic Pb origins from vehicular exhausts, cements, and coal flying ashes, which elevated metal contents in the inner channels via atmospheric deposition. Specific hazard quotients of the metal contamination in surface sediment were also assessed and enhanced over time in the study wetland park. These findings suggest that emissions from traffic, construction, and energy generation contribute metal loadings in the urbanizing environment.

Temporal dynamics of urbanization-driven environmental changes explored by metal contamination in surface sediments in a restoring urban wetland park

International Nuclear Information System (INIS)

Ma, Jun; Liu, Yi; Yu, Guangbin; Li, Hongbo; Yu, Shen; Jiang, Yueping; Li, Guilin; Lin, Jinchang

2016-01-01

Highlights: • Urban-rural distribution pattern of metals in sediment faded out with urbanization. • Urban emissions were identified as sources of metal elevation in surface sediment. • Metal level homogenization with urbanization posed a moderate risk to the public. - Abstract: Spatial patterns of metal distribution along urban-rural or multi-city gradients indicate that the urbanization process directly lead to metal enrichment and contamination in the environments. However, it has not yet looked at homogenization dynamics of an urban-rural gradient pattern over time with urbanization process in an area. This study monitored anthropogenic metals (Cr, Cu, Pb, and Zn) in surface sediments from channels of a newly-opened National Wetland Park to elucidate the urbanization-driven dissolution of urban-rural gradient pattern between 2008 and 2011. Sixty-eight surface sediment samples were taken from these channels in July of both 2008 and 2011. Results showed that a spatial distribution pattern of total metal contents along the gradient of urbanization influence, evident in 2008, was homogenized in 2011 with the area development. The lead stable isotope ratio analysis identified anthropogenic Pb origins from vehicular exhausts, cements, and coal flying ashes, which elevated metal contents in the inner channels via atmospheric deposition. Specific hazard quotients of the metal contamination in surface sediment were also assessed and enhanced over time in the study wetland park. These findings suggest that emissions from traffic, construction, and energy generation contribute metal loadings in the urbanizing environment.

Heavy metal enrichment and ecological risk assessment of surface sediments in Khorramabad River, West Iran.

Science.gov (United States)

Rastmanesh, F; Safaie, S; Zarasvandi, A R; Edraki, M

2018-04-11

The ecological health of rivers has often been threatened in urbanized catchments due to the expansion of industrial activities and the population growth. Khorramabad River which flows through Khorramabad city, west of Iran, is an example of such settings. The river water is used for agricultural purposes downstream. In this study, the effect of Khorramabad city on heavy metal and metalloid (Cu, Pb, Zn, Ni, Cr, and As) loads in Khorramabad River sediments was investigated. To evaluate sediment pollution and potential adverse biological effects, surface sediment samples were collected at selected locations along the river and were characterized for their geochemical properties. Contamination factor (CF), pollution load index (PLI), and ecological risk assessment (RI) were calculated. Also, sediment quality guidelines (SQGs) were used to screen contaminants of concern in the study area. The results showed that sediments were moderately polluted, with stations located in more densely populated areas showing higher pollution indicators. Copper, Zn, and Pb sources could be attributed to urban wastewater, whereas Ni, Cr, and As had both natural and anthropogenic sources. Moreover, ecological risk assessments showed that sediments could be classified in the category of low risk. The results of the present study showed the effect of anthropogenic activities on heavy metal loads of the river sediments and these findings can be used to mitigate potential impacts on the environment and human health.

Cenozoic extinction and recolonization in the New Zealand flora: the case of the fleshy-fruited epacrids (Styphelieae, Styphelioideae, Ericaceae).

Science.gov (United States)

Puente-Lelièvre, Caroline; Harrington, Mark G; Brown, Elizabeth A; Kuzmina, Maria; Crayn, Darren M

2013-01-01

The origins and evolutionary history of the New Zealand flora has been the subject of much debate. The recent description of Cyathodophyllum novaezelandieae from early Miocene sediments in New Zealand provides possible evidence for the antiquity of the fleshy fruited epacrids (tribe Styphelieae, Ericaceae) in New Zealand. Yet the extant species in this tribe are thought to be very closely related to or conspecific with Australian taxa, suggesting recent trans-Tasman origins. In order to investigate the origins and evolution of the extant New Zealand Styphelieae we produced molecular phylogenetic trees based on sequences of three plastid regions that include representatives of all the genera of the tribe and eight of the ten New Zealand species. We estimated the range of minimum ages of the New Zealand lineages with Bayesian relaxed-clock analyses using different calibration methods and relative dating. We found strong support for each of the eight extant species of New Zealand Styphelieae being a distinct lineage that is nested within an Australian clade. In all except one case the sister is from Tasmania and/or the east coast of mainland Australia; for Acrothamnus colensoi the sister is in New Guinea. Estimated dates indicate that all of the New Zealand lineages diverged from their non-New Zealand sisters within the last 7 Ma. Time discontinuity between the fossil C.novae-zelandiae (20-23 Ma) and the origins of the extant New Zealand lineages (none older than 5 Ma) indicates that the fossil and extant Styphelieae in New Zealand are not related. The relative dating analysis showed that to accept this relationship, it would be necessary to accept that the Styphelieae arose in the early-mid Mesozoic (210-120 Ma), which is starkly at odds with multiple lines of evidence on the age of Ericales and indeed the angiosperms. Therefore, our results do not support the hypothesis that Styphelieae have been continuously present in New Zealand since the early Miocene. Instead

Hydrocarbons in surface sediments from the Sfax coastal zone, (Tunisia) Mediterranean Sea.

Science.gov (United States)

Zaghden, Hatem; Kallel, Monem; Louati, Afifa; Elleuch, Boubaker; Oudot, Jean; Saliot, Alain

2005-11-01

The Semi-enclosed Mediterranean Sea records various signals of high anthropic pressures from surrounding countries and the industrialized European countries. This is particularly true for oil pollution. Although accounting for 1% of the world's ocean surface, it receives about 25% of the petroleum inputs to the ocean. To achieve a global budget we need to collect information from different parts of the Mediterranean. Particularly, we focus in this paper on the Southern Mediterranean, where data are presently very scarce. In this context, the University of Sfax has undertaken an estimation of hydrocarbon pollution along the coasts of Sfax and Gabès Gulf. Non-aromatic hydrocarbons were analysed in 8 surface sediments by FT/IR and GC/MS. Non-aromatic hydrocarbon concentrations vary in the range 310-1406 microg g(-1) sediments dry weight, which is high, compared to other Mediterranean sites. GC/MS data indicate a large group of unresolved compounds suggesting a petroleum contamination, confirmed by the identification of hopanes with predominant C29 and C30alpha,beta compounds and steranes with predominance of C27 over C28) and C29 compounds.

Distribution, Source, and Ecological Risk Assessment of Polycyclic Aromatic Hydrocarbons in Surface Sediment of Liaodong Bay, Northeast China

Science.gov (United States)

Xu, Shuang; Tao, Ping; Li, Yuxia; Guo, Qi; Zhang, Yan; Wang, Man; Jia, Hongliang; Shao, Mihua

2018-01-01

Sixteen polycyclic aromatic hydrocarbons (PAHs) were determined in surface sediments from Liaodong Bay, northeast China. The concentration levels of total PAHs (Σ16PAHs) in sediment were 11.0˜249.6 ng·g-1 dry weight (dw), with a mean value of 89.9 ng·g-1 dry weight (dw). From the point of the spatial distribution, high PAHs levels were found in the western areas of Liaodong Bay. In the paper, sources of PAHs were investigated by diagnostic ratios, which indicated that pyrogenic sources were the main sources of PAHs in the sediment of Liaodong Bay. Therefore, selected PAH levels in sediments were compared with Sediments Quality Guidelines (ERM-ERL indexes) for evaluation probable toxic effects on marine organism.

Solar energy. [New Zealand

Energy Technology Data Exchange (ETDEWEB)

Benseman, R.

1977-10-15

The potential for solar space heating and solar water heating in New Zealand is discussed. Available solar energy in New Zealand is indicated, and the economics of solar space and water heating is considered. (WHK)

The Surface of Venus is Saturated With Ancient Impact Structures, and its Plains are Marine Sediments

Science.gov (United States)

Hamilton, W. B.

2009-05-01

Conventional interpretations of Venus are forced to fit dubious pre-Magellan conjectures that the planet is as active internally as Earth and preserves no ancient surface features. Plate tectonics obviously does not operate, so it is commonly assumed that the surface must record other endogenic processes, mostly unique to Venus. Imaginative systems of hundreds of tiny to huge rising and sinking plumes and diapirs are invoked. That much of the surface in fact is saturated with overlapping large circular depressions with the morphology of impact structures is obscured by postulating plume origins for selected structures and disregarding the rest. Typical structures are rimmed circular depressions, often multiring, with lobate debris aprons; central peaks are common. Marine-sedimentation features are overlooked because dogma deems the plains to be basalt flows despite their lack of source volcanoes and fissures. The unearthly close correlation between geoid and topography at long to moderate wavelengths requires, in conventional terms, dynamic maintenance of topography by up and down plumes of long-sustained precise shapes and buoyancy. A venusian upper mantle much stronger than that of Earth, because it is cooler or poorer in volatiles, is not considered. (The unearthly large so-called volcanoes and tessera plateaus often are related to rimmed circular depressions and likely are products of impact fluidization and melting.) Plains-saturating impact structures (mostly more obvious in altimetry than backscatter) with diameters of hundreds of km are superimposed as cookie-cutter bites, are variably smoothed and smeared by apparent submarine impact and erosion, and are differentially buried by sediments compacted into them. Marine- sedimentation evidence includes this compaction; long sinuous channels and distributaries with turbidite- channel characteristics and turbidite-like lobate flows (Jones and Pickering, JGSL 2003); radar-smooth surfaces and laminated aspect in

Minimization of gully erosion on reclaimed surface mines using the stable slope and sediment transport computer model

International Nuclear Information System (INIS)

McKenney, R.A.; Gardner, T.G.

1992-01-01

Disequilibrium between slope form and hydrologic and erosion processes on reclaimed surface coal mines in the humid temperate northeastern US, can result in gully erosion and sediment loads which are elevated above natural, background values. Initial sheetwash erosion is surpassed by gully erosion on reclamation sites which are not in equilibrium with post-mining hydrology. Long-term stability can be attained by designing a channel profile which is in equilibrium with the increased peak discharges found on reclaimed surface mines. The Stable Slope and Sediment transport model (SSAST) was developed to design stable longitudinal channel profiles for post-mining hydrologic and erosional processes. SSAST is an event based computer model that calculates the stable slope for a channel segment based on the post-mine hydrology and median grain size of a reclaimed surface mine. Peak discharge, which drives post-mine erosion, is calculated from a 10-year, 24-hour storm using the Soil Conservation Service curve number method. Curve number calibrated for Pennsylvania surface mines are used. Reclamation sites are represented by the rectangle of triangle which most closely fits the shape of the site while having the same drainage area and length. Sediment transport and slope stability are calculated using a modified Bagnold's equation with a correction factor for the irregular particle shapes formed during the mining process. Data from three reclaimed Pennsylvania surface mines were used to calibrate and verify SSAST. Analysis indicates that SSAST can predict longitudinal channel profiles for stable reclamation of surface mines in the humid, temperate northeastern US

Biogeographical distribution and diversity of bacterial communities in surface sediments of the South China Sea.

Science.gov (United States)

Li, Tao; Wang, Peng

2013-05-01

This paper aims at an investigation of the features of bacterial communities in surface sediments of the South China Sea (SCS). In particular, biogeographical distribution patterns and the phylogenetic diversity of bacteria found in sediments collected from a coral reef platform, a continental slope, and a deep-sea basin were determined. Bacterial diversity was measured by an observation of 16S rRNA genes, and 18 phylogenetic groups were identified in the bacterial clone library. Planctomycetes, Deltaproteobacteria, candidate division OP11, and Alphaproteobacteria made up the majority of the bacteria in the samples, with their mean bacterial clones being 16%, 15%, 12%, and 9%, respectively. By comparison, the bacterial communities found in the SCS surface sediments were significantly different from other previously observed deep-sea bacterial communities. This research also emphasizes the fact that geographical factors have an impact on the biogeographical distribution patterns of bacterial communities. For instance, canonical correspondence analyses illustrated that the percentage of sand weight and water depth are important factors affecting the bacterial community composition. Therefore, this study highlights the importance of adequately determining the relationship between geographical factors and the distribution of bacteria in the world's seas and oceans.

[Pollution characteristics and ecological risk assessment of heavy metals in surface sediments of Qingshan Reservoir in Lin' an City, Zhejiang Province of East China].

Science.gov (United States)

Zhang, Fen; Yang, Chang-Ming; Pan, Rui-Jie

2013-09-01

A total of 8 representative surface sediment sampling sites were collected from the Qingshan Reservoir in Lin'an City of Zhejiang Province to investigate the differences in the total concentrations of As, Cr, Cu, Ni, Mn, Pb, and Zn among the sampling sites. The different forms of the heavy metals, i. e., acid soluble, easily reducible, easily oxidizable, and residual, were determined by BCR sequential extraction method, and the pollution degrees and potential ecological risk, of the heavy metals in the surface sediments at different sampling sites of the Reservoir were assessed by using geo-accumulation index (I(geo)) and Hakanson potential ecological risk index. There existed obvious spatial differences in the total concentrations of the heavy metals in the surface sediments of the Reservoir. The sampling sites nearby the estuaries of the tributaries flowing through downtowns and heavy industrial parks to the Reservoir had obviously higher heavy metals concentrations in surface sediments, as compared to the other sampling sites. In the sediments, Mn was mainly in acid extractable form, Cu and Pb were mainly in reducible form, and As was mainly in residual form. The surface sediments at the sampling sites nearby the estuaries of the tributaries flowing through downtowns to the Reservoir had higher proportions of acid extractable and reducibles forms of the heavy metals, which would have definite potential toxic risk to aquatic organisms. Among the 7 heavy metals in the surface sediments, As showed the highest pollution degree, followed by Cu, Ni, Mn, Pb, and Zn, which were at moderate pollution degree, while Cr was at non-pollution degree, with relatively low potential ecological risk. Through the comparison of the sampling sites, it was observed that the surface sediments at the sites nearby the estuaries of Jinxi River and Hengxi River flowing through downtowns and heavy industrial parks to the Reservoir showed obviously higher heavy metals pollution degree and

The effects of clam fishing on the properties of surface sediments in the lagoon of Venice, Italy

Directory of Open Access Journals (Sweden)

R. J. Aspen

2004-01-01

Full Text Available Harvesting of clams(Tapes philippinarum has important socio-economic and environmental implications for the Venice lagoon area, Italy. Clam harvesting disrupts the structure of benthic communities but the effects upon sediment stability and surface structure remain unclear. The effect of clam fishing on the sediment properties of the lagoon bed was investigated at two different sites, a heavily fished site (San Angelo and an infrequently fished site (San Giaccomo. Both sites were assessed for immediate impacts of fishing, using indicators of biogenic sediment stabilisation. Samples were taken at three points along three 100 m linear transects at each site prior to and post fishing. Paired samples were also taken parallel to each transect at a distance of 5m, to allow for temporal variation. Sediment stability, measured with a cohesive strength meter (CSM, was significantly higher at the less impacted site (F1,34 = 6.23, p a (chl a, colloidal-S carbohydrate and dry bulk density were observed on the transect after fishing but not adjacent to the fishing path. At the heavily impacted site, clam fishing by trawling had, in general, no significant effect on the biological and physical properties (although chl a did decrease significantly after fishing. The lack of a significant impact from fishing at the impacted site was attributed to the higher frequency of fishing occurring in this area. Hence, frequent fishing of the lagoon prevents establishment of biotic communities, preventing biostabilisation and thus reduces the stability of the surface sediment. Keywords: clam harvesting, erosion threshold, microphytobenthos, sediment, stability

Impacts of urbanization on surface sediment quality: evidence from polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) contaminations in the Grand Canal of China.

Science.gov (United States)

Hong, Youwei; Yu, Shen; Yu, Guangbin; Liu, Yi; Li, Guilin; Wang, Min

2012-06-01

Organic pollutants, especially synthetic organic compounds, can indicate paces of anthropogenic activities. Effects of urbanization on polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) distributions in surface sediment were conducted in urban sections of the Grand Canal, China, consisting of a four-level urbanization gradient. The four-level urbanization gradients include three countryside towns, two small-size cities, three medium-size cities, and a large-size city. Diagnostic ratio analysis and factor analysis-multiple linear regression model were used for source apportionment of PAHs. Sediment quality guidelines (SQGs) of USA and Canada were employed to assess ecological risks of PAHs and PCBs in surface sediments of the Canal. Ranges of PAH and PCB concentrations in surface sediments were 0.66-22 mg/kg and 0.5-93 μg/kg, respectively. Coal-related sources were primary PAH sources and followed by vehicular emission. Total concentration, composition, and source apportionment of PAHs exhibited urbanization gradient effects. Total PCB concentrations increased with the urbanization gradient, while total PAHs concentration in surface sediments presented an inverted U Kuznets curve with the urbanization gradient. Elevated concentrations of both PAHs and PCBs ranged at effect range low levels or interim SQG, assessed by USA and Canadian SQGs. PAHs and PCBs in surface sediments of the Grand Canal showed urbanization gradient effects and low ecological risks.

Investigating the Effects of Underplating at Raukumara Peninsula, New Zealand: Insights from DEM Modeling

Science.gov (United States)

Farrell, W. C.; Morgan, J.

2017-12-01

It is thought that subcretion and underplating are important processes at subduction zones worldwide. Despite its proposed common occurrence, the physical mechanisms controlling if underplating occurs and the rate of its associated uplift are poorly understood. Basic questions about the tectonic and geomechanical parameters governing subduction channel stability, subcretion, and the rate and shape of associated uplift have proven difficult to answer. In this study we employ the Discrete Element Method (DEM) to address these questions, using the Raukumara Peninsula of New Zealand as the real-world basis of many of our model inputs. Multiple geophysical datasets suggest that the Raukumara Peninsula is underlain by underplated sediments at Moho depths, and these may be responsible for anomalously high rates of uplift in the area. The combined geologic, geophysical, and geodetic data from the region serve to constrain model geometries and boundary conditions, allowing us to test the mechanisms for underplating and upper crustal response. The effects of surface processes and potential for shallow trenchward sliding are also investigated in the modeling effort.

Thallium dispersal and contamination in surface sediments from South China and its source identification.

Science.gov (United States)

Liu, Juan; Wang, Jin; Chen, Yongheng; Shen, Chuan-Chou; Jiang, Xiuyang; Xie, Xiaofan; Chen, Diyun; Lippold, Holger; Wang, Chunlin

2016-06-01

Thallium (Tl) is a non-essential element in humans and it is considered to be highly toxic. In this study, the contents, sources, and dispersal of Tl were investigated in surface sediments from a riverine system (the western Pearl River Basin, China), whose catchment has been contaminated by mining and roasting of Tl-bearing pyrite ores. The isotopic composition of Pb and total contents of Tl and other relevant metals (Pb, Zn, Cd, Co, and Ni) were measured in the pyrite ores, mining and roasting wastes, and the river sediments. Widespread contamination of Tl was observed in the sediments across the river, with the highest concentration of Tl (17.3 mg/kg) measured 4 km downstream from the pyrite industrial site. Application of a modified Institute for Reference Materials and Measurement (IRMM) sequential extraction scheme in representative sediments unveiled that 60-90% of Tl and Pb were present in the residual fraction of the sediments. The sediments contained generally lower (206)Pb/(207)Pb and higher (208)Pb/(206)Pb ratios compared with the natural Pb isotope signature (1.2008 and 2.0766 for (206)Pb/(207)Pb and (208)Pb/(206)Pb, respectively). These results suggested that a significant fraction of non-indigenous Pb could be attributed to the mining and roasting activities of pyrite ores, with low (206)Pb/(207)Pb (1.1539) and high (208)Pb/(206)Pb (2.1263). Results also showed that approximately 6-88% of Tl contamination in the sediments originated from the pyrite mining and roasting activities. This study highlights that Pb isotopic compositions could be used for quantitatively fingerprinting the sources of Tl contamination in sediments. Copyright © 2016 Elsevier Ltd. All rights reserved.

Impacts of lake water environmental condition on bioavailable-phosphorus of surface sediments in Lixia River basin, China

Directory of Open Access Journals (Sweden)

Y. Zhang

2015-05-01

Full Text Available Bioavailable-phosphorus (BAP fractions of the lake surface sediments (the upper 0−5cm depth and environmental indicators of the related lake water column were investigated in five lakes in Lixia River basin during three seasons in order to evaluate the impacts of environmental indicators of the water column on the BAP fractions of surface sediments. The concentration of BAP varied significantly in different seasons. Factor analysis was used to identify the factors which influence sedimentary BAP significantly in the different seasons. The results showed that AAP and Olsen-P were significantly affected by the chemical oxygen demand through the bacterial activity in summer. The high intensity of bacterial activity and density of algae, and low concentrations of NO3-N and dissolved oxygen under high temperature enhanced the BAP released from anaerobic sediment and significantly contributed to the eutrophication of the lake, especially in summer. In addition, macrophyte roots were beneficial to absorption of AAP and Olsen-P.

Timing of Late Holocene surface rupture of the Wairau Fault, Marlborough, New Zealand

International Nuclear Information System (INIS)

Zachariasen, J.; Berryman, K.R.; Langridge, R.M.; Prentice, C.; Rymer, M.; Stirling, M.W.; Villamor, P.

2006-01-01

Three trenches excavated across the central portion of the right-lateral strike-slip Wairau Fault in South Island, New Zealand, exposed a complex set of fault strands that have displaced a sequence of late Holocene alluvial and colluvial deposits. Abundant charcoal fragments provide age control for various stratigraphic horizons dating back to c. 5610 yr ago. Faulting relations from the Wadsworth trench show that the most recent surface rupture event occurred at least 1290 yr and at most 2740 yr ago. Drowned trees in landslide-dammed Lake Chalice, in combination with charcoal from the base of an unfaulted colluvial wedge at Wadsworth trench, suggest a narrower time bracket for this event of 1811-2301 cal. yr BP. The penultimate faulting event occurred between c. 2370 and 3380 yr, and possibly near 2680 ± 60 cal. yr BP, when data from both the Wadsworth and Dillon trenches are combined. Two older events have been recognised from Dillon trench but remain poorly dated. A probable elapsed time of at least 1811 yr since the last surface rupture, and an average slip rate estimate for the Wairau Fault of 3-5 mm/yr, suggests that at least 5.4 m and up to 11.5 m of elastic shear strain has accumulated since the last rupture. This is near to or greater than the single-event displacement estimates of 5-7 m. The average recurrence interval for surface rupture of the fault determined from the trench data is 1150-1400 yr. Although the uncertainties in the timing of faulting events and variability in inter-event times remain high, the time elapsed since the last event is in the order of 1-2 times the average recurrence interval, implying that the Wairau Fault is near the end of its interseismic period. (author). 44 refs., 10 figs., 1 tab

Early steroid sulfurisation in surface sediments of a permanebtly stratified lake (Ace Lake, Antarctica)

NARCIS (Netherlands)

Sinninghe Damsté, J.S.; Rijpstra, W.I.C.; Robertson, L.; Volkman, J.K.

2000-01-01

Surface sediments (0 25 cm) from Ace Lake (eastern Antarctica), a saline euxinic lake, were analyzed to study the early incorporation of reduced inorganic sulfur species into organic matter. The apolar fractions were shown to consist predominantly of dimeric (poly)sulfide linked C27-C29 steroids.

Antibiotics in surface water and sediments from Hanjiang River, Central China: Occurrence, behavior and risk assessment.

Science.gov (United States)

Hu, Ying; Yan, Xue; Shen, Yun; Di, Mingxiao; Wang, Jun

2018-08-15

Thirteen antibiotics including sulfonamides (SAs), tetracyclines (TETs) and fluoroquinolones (FQs) were measured in Hanjiang River (HR) during two periods. The total concentrations of 13 antibiotics in surface water and sediments ranged from 3.1 to 109 ng/l and from 10 to 45 ng/g dry weight, respectively. SAs were dominant in water while the concentrations of TETs were the highest in sediments in two seasons. For their spatial distribution, total concentrations of 13 antibiotics in both matrices were significantly higher in the lower section of HR (p  5.15) due to wastewater release, agricultural activities and water transfer project. Obvious seasonal variations of sulfadiazine, sulfameter, trimethoprim and oxytetracycline in water were observed (p  4.62). Phase partition of antibiotics between water and sediments suggested a greater affinity of TETs and FQs to sediments. In addition, significantly positive relationships were found between SAs (sulfameter, sulfamethoxazole and trimethoprim) and sediment TOC (p Risk assessment indicated that the hazard quotients of antibiotics were higher in the sediment than those in the water. Moreover, antibiotic mixtures posed higher ecological risks to aquatic organisms. Copyright © 2018 Elsevier Inc. All rights reserved.

Uranium and coexisting element behaviour in surface waters and associated sediments with varied sampling techniques used for uranium exploration

International Nuclear Information System (INIS)

Wenrich-Verbeek, K.J.

1977-01-01

Optimum sampling methods in surface water and associated sediments for use in uranium exploration are being studied at thirty sites in Colorado, New Mexico, Arizona and Utah. For water samples, filtering is recommended to increase sample homogeneity and reproducibility because for most elements studied water samples which were allowed to remain unfiltered until time of analysis contained higher concentrations than field-filtered samples of the same waters. Acidification of unfiltered samples resulted in still higher concentrations. This is predominantly because of leaching of the elements from the suspended fraction. U in water correslates directly with Ca, Mg, Na, K, Ba, B, Li and As. In stream sediments, U and other trace elements are concentrated in the finer size fractions. Accordingly, in prospecting, grain size fractions less than 90 μm (170 mesh) should be analyzed for U. A greater number of elements (21) show a significant positive correlation with U in stream sediments than in water. Results have revealed that anomalous concentrations of U found in water may not be detected in associated sediments and vice versa. Hence, sampling of both surface water and coexisting sediment is strongly recommended

Uranium(VI) sorption on iron oxides in Hanford Site sediment: Application of a surface complexation model

International Nuclear Information System (INIS)

Um, Wooyong; Serne, R. Jeffrey; Brown, Christopher F.; Rod, Kenton A.

2008-01-01

Sorption of U(VI) on Hanford fine sand (HFS) with varying Fe-oxide (especially ferrihydrite) contents showed that U(VI) sorption increased with the incremental addition of synthetic ferrihydrite into HFS, consistent with ferrihydrite being one of the most reactive U(VI) sorbents present in natural sediments. Surface complexation model (SCM) calculations for U(VI) sorption, using only U(VI) surface-reaction constants obtained from U(VI) sorption data on freshly synthesized ferrihydrite at different pHs, were similar to the measured U(VI) sorption results on pure synthetic ferrihydrite and on HFS with high contents of ferrihydrite (5 wt%) added. However, the SCM prediction using only U(VI) sorption reactions and constants for synthetic ferrihydrite overestimated U(VI) sorption on the natural HFS or HFS with addition of low amounts of added ferrihydrite (1 wt% added). Over-predicted U(VI) sorption was attributed to reduced reactivity of natural ferrihydrite present in Hanford Site sediments, compared to freshly prepared synthetic ferrihydrite. Even though the SCM general composite (GC) approach is considered to be a semi-quantitative estimation technique for contaminant sorption, which requires systematic experimental data on the sorbent-sorbate system being studied to obtain credible SCM parameters, the general composite SCM model was still found to be a useful technique for describing U(VI) sorption on natural sediments. Based on U(VI) batch sorption results, two simple U(VI) monodentate surface species, SO U O 2 HCO 3 and SO U O 2 OH on ferrihydrite and phyllosillicate in HFS, respectively, can be successfully used to describe U(VI) sorption onto Hanford Site sediment contacting varying geochemical solutions

Spatial glyphosate and AMPA redistribution on the soil surface driven by sediment transport processes – A flume experiment

NARCIS (Netherlands)

Bento, Célia P.M.; Commelin, Meindert C.; Baartman, Jantiene E.M.; Yang, Xiaomei; Peters, Piet; Mol, Hans G.J.; Ritsema, Coen J.; Geissen, Violette

2018-01-01

This study investigates the influence of small-scale sediment transport on glyphosate and AMPA redistribution on the soil surface and on their off-site transport during water erosion events. Both a smooth surface (T1) and a surface with “seeding lines on the contour” (T2) were tested in a rainfall

Selected anionic and cationic surface active agents: case study on the Kłodnica sediments

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Olkowska Ewa

2017-03-01

Full Text Available Surface active agents (surfactants are a group of chemical compounds, which are used as ingredients of detergents, cleaning products, cosmetics and functional products. After use, wastes containing surfactants or their degradation products are discharged to wastewater treatment plants or directly into surface waters. Due to their specific properties of SAAs, compounds are able to migrate between different environmental compartments such as soil, sediment, water or even living organisms and accumulate there. Surfactants can have a harmful effect on living organisms. They can connect with bioactive molecules and modify their function. Additionally, they have the ability to migrate into cells and cause their damage or death. For these reasons investigation of individual surfactants should be conducted. The presented research has been undertaken to obtain information about SAA contamination of sediment from the River Kłodnica catchment caused by selected anionic (linear alkylbenzene sulfonates (LAS C10-C13 and cationic (alkylbenzyldimethylammonium (BDMA-C12-16, alkyl trimethyl ammonium (DTMA, hexadecyl piridinium chloride (HP chlorides surfactants. This river flows through an area of the Upper Silesia Industrial Region where various companies and other institutions (e.g. coal mining, power plants, metallurgy, hospitals are located. To determine their concentration the following analytical tools have been applied: accelerated solvent extraction– solid phase extraction – high performance liquid chromatography – UV-Vis (anionic SAAs and conductivity (cationic SAAs detectors. In all sediments anionic SAAs have been detected. The concentrations of HTMA and BDMA-C16 in tested samples were higher than other cationic analytes. Generally, levels of surfactants with longer alkyl chains were higher and this observation can confirm their higher susceptibility to sorption on solid surfaces.

Moringa oleifera Lam. and Its Potential Association with Aluminium Sulphate in the Process of Coagulation/Flocculation and Sedimentation of Surface Water

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Karina Cardoso Valverde

2018-01-01

Full Text Available The present study aims to optimize the operational conditions in surface water coagulation/flocculation and sedimentation step, besides evaluating the association between seeds of Moringa oleifera Lam. (M. oleifera and the synthetic coagulant aluminium sulphate for surface water treatment. The assays were performed in Jar Test using surface water from Pirapó River basin, Maringá, PR. It was observed that the operational conditions affect the coagulation/flocculation and sedimentation process efficiency. Optimal operational conditions for coagulants association are as follows: rapid mixing velocity (RMV of 105 rpm, rapid mixing times (RMT of 1 min, slow mixing velocity (SMV of 30 rpm, slow mixing times (SMT of 15 min, and sedimentation time (ST of 15 min; this enables an improvement in the process, contributing to a reduction in synthetic coagulant aluminium sulphate demand of up to 30%, combined with an increase in M. oleifera dosage, not affecting the coagulation/flocculation and sedimentation process efficiency, considering the water pH range between 7 and 9.

Temperature Reconstruction and Biomarker Variation across the Cretaceous-Paleogene Boundary, Mid-Waipara River, New Zealand

Science.gov (United States)

Taylor, K. W.; Hollis, C. J.; Pancost, R. D.

2010-12-01

The Cretaceous-Paleogene (K/Pg) boundary marks a catastrophic global extinction event, believed to be caused by an asteroid impact in northern Yucatan. Whilst the extent of mass extinction is well documented, there is ongoing debate about the immediate and longer term climatic and environmental changes triggered by the event. The northern South Island of New Zealand has several records of the K/Pg boundary, representing a range of terrestrial and marine environments. Previous studies of terrestrial palynomorphs and siliceous microfossils from these sections suggested significant cooling and terrestrial vegetation reconfiguration in the earliest Paleocene. Extinctions or local disappearances of thermophilic taxa at the K/Pg boundary are consistent with the hypothesis of a short-lived “impact winter”. The Mid-Waipara K/Pg boundary section, north Canterbury, has been identified as suitable for organic geochemical study because sufficient organic carbon is present in the siliciclastic sediments and is thermally immature. Sediments were deposited in outer shelf to upper slope depths under a neritic watermass. New estimates of sea surface temperature variation based on TEX86 elucidate the relationship between biological and climatic changes that followed the K/Pg event. Within the 0.25 m-thick interval identified as the “fern spike” in basal Paleocene sediments in this section there is no indication of a significant change in temperature relative to the Cretaceous (22-25°C). Foraminiferal and radiolarian biostratigraphy indicates that this interval spans ~100 kyrs and includes a fern succession from colonising ground ferns to tree ferns, the latter suggesting a temperate, humid climate. The transition from ferns to a conifer-dominated pollen assemblage corresponds with a remarkable decrease in temperature recorded in the TEX86 record. These cool temperatures persist over 10 m. The dominant conifer pollen type over this interval is Phyllocladites mawsonii

Cold seep epifaunal communities on the Hikurangi margin, New Zealand: composition, succession, and vulnerability to human activities.

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David A Bowden

Full Text Available Cold seep communities with distinctive chemoautotrophic fauna occur where hydrocarbon-rich fluids escape from the seabed. We describe community composition, population densities, spatial extent, and within-region variability of epifaunal communities at methane-rich cold seep sites on the Hikurangi Margin, New Zealand. Using data from towed camera transects, we match observations to information about the probable life-history characteristics of the principal fauna to develop a hypothetical succession sequence for the Hikurangi seep communities, from the onset of fluid flux to senescence. New Zealand seep communities exhibit taxa characteristic of seeps in other regions, including predominance of large siboglinid tubeworms, vesicomyid clams, and bathymodiolin mussels. Some aspects appear to be novel; however, particularly the association of dense populations of ampharetid polychaetes with high-sulphide, high-methane flux, soft-sediment microhabitats. The common occurrence of these ampharetids suggests they play a role in conditioning sulphide-rich sediments at the sediment-water interface, thus facilitating settlement of clam and tubeworm taxa which dominate space during later successional stages. The seep sites are subject to disturbance from bottom trawling at present and potentially from gas hydrate extraction in future. The likely life-history characteristics of the dominant megafauna suggest that while ampharetids, clams, and mussels exploit ephemeral resources through rapid growth and reproduction, lamellibrachid tubeworm populations may persist potentially for centuries. The potential consequences of gas hydrate extraction cannot be fully assessed until extraction methods and target localities are defined but any long-term modification of fluid flow to seep sites would have consequences for all chemoautotrophic fauna.

Investigation of Composition of Particle Size in Sediments of Stormwater Sedimentation Tank

OpenAIRE

Daiva Laučytė; Regimantas Dauknys

2011-01-01

The main object for the storm water runoff treatment is to remove suspended solids before the storm water runoff is discharged into surface waters. Therefore the sedimentation tank is the most often used treatment facility. In order to optimise the sedimentation, the tendency of particle size distribution in bottom sediments must be known. Two similar size storm water runoff sedimentation tanks in Vilnius city were selected for the analysis of the particle size distribution in sediments. The ...

Mid-late Holocene paleoseismicity of the eastern Clarence Fault, Marlborough, New Zealand

International Nuclear Information System (INIS)

Van Dissen, R.J.; Nicol, A.

2009-01-01

The middle Clarence valley, or eastern, section of the active Clarence Fault bounds the steep southeast flank of the Inland Kaikoura Range, Marlborough, New Zealand. This section of the fault extends c. 45 km northeastwards from its junction with the Elliott Fault to Mead Stream, where the active trace of the fault appears to abruptly end. Along the active trace, 41 separate right-lateral offsets of c. 3-40 m were recorded with uncertainties of 10-50% (mean 25%) using tape measurement of displaced topographic features (e.g., gully walls, landslide margins, and ridge crests). Single-event right-lateral displacements of 7 ± 2 m are inferred and indicate earthquake magnitudes of Mw 7.2-7.9. Probable rupture lengths have been in excess of 45 km, which suggests that rupture of the middle Clarence valley (eastern) section of the fault extended to the west onto the central Clarence and/or Elliott faults. Stream incision through the uphill-facing fault scarp at Ravine Stream and Dead Horse Gully has exposed progressively faulted peat and charcoal horizons. Elsewhere, there are several exposures of unfaulted sediments. Twelve radiocarbon samples dated from these horizons constrain the timing of the four most recent surface-rupture earthquakes on the Clarence Fault in the study area. The most recent surface rupture took place at c. 1700-1900 cal. yr BP (rounded to the nearest hundred years), with two surface ruptures since c. 3400 cal. yr BP, three since 6700 cal. yr BP, and most likely a fourth surface rupture at c. 6600-6900 cal. yr BP. These data suggest a recurrence interval for surface-rupture earthquakes of c. 1700 yr, and imply a lateral slip rate of c. 4 mm/yr (i.e., c. 7 m of slip every c. 1700 yr). (author). 45 refs., 9 figs., 3 tabs.

Concentrations and sources of polycyclic aromatic hydrocarbons in surface coastal sediments of the northern Gulf of Mexico

Science.gov (United States)

2014-01-01

Background Coastal sediments in the northern Gulf of Mexico have a high potential of being contaminated by petroleum hydrocarbons, such as polycyclic aromatic hydrocarbons (PAHs), due to extensive petroleum exploration and transportation activities. In this study we evaluated the spatial distribution and contamination sources of PAHs, as well as the bioavailable fraction in the bulk PAH pool, in surface marsh and shelf sediments (top 5 cm) of the northern Gulf of Mexico. Results PAH concentrations in this region ranged from 100 to 856 ng g−1, with the highest concentrations in Mississippi River mouth sediments followed by marsh sediments and then the lowest concentrations in shelf sediments. The PAH concentrations correlated positively with atomic C/N ratios of sedimentary organic matter (OM), suggesting that terrestrial OM preferentially sorbs PAHs relative to marine OM. PAHs with 2 rings were more abundant than those with 5–6 rings in continental shelf sediments, while the opposite was found in marsh sediments. This distribution pattern suggests different contamination sources between shelf and marsh sediments. Based on diagnostic ratios of PAH isomers and principal component analysis, shelf sediment PAHs were petrogenic and those from marsh sediments were pyrogenic. The proportions of bioavailable PAHs in total PAHs were low, ranging from 0.02% to 0.06%, with higher fractions found in marsh than shelf sediments. Conclusion PAH distribution and composition differences between marsh and shelf sediments were influenced by grain size, contamination sources, and the types of organic matter associated with PAHs. Concentrations of PAHs in the study area were below effects low-range, suggesting a low risk to organisms and limited transfer of PAHs into food web. From the source analysis, PAHs in shelf sediments mainly originated from direct petroleum contamination, while those in marsh sediments were from combustion of fossil fuels. PMID:24641695

Long-Term Impact of Sediment Deposition and Erosion on Water Surface Profiles in the Ner River

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Tomasz Dysarz

2017-02-01

Full Text Available The purpose of the paper is to test forecasting of the sediment transport process, taking into account two main uncertainties involved in sediment transport modeling. These are: the lack of knowledge regarding future flows, and the uncertainty with respect to which sediment transport formula should be chosen for simulations. The river reach chosen for study is the outlet part of the Ner River, located in the central part of Poland. The main characteristic of the river is the presence of an intensive morphodynamic process, increasing flooding frequency. The approach proposed here is based on simulations with a sediment-routing model and assessment of the hydraulic condition changes on the basis of hydrodynamic calculations for the chosen characteristic flows. The data used include Digital Terrain Models (DTMs, cross-section measurements, and hydrological observations from the Dabie gauge station. The sediment and hydrodynamic calculations are performed using program HEC-RAS 5.0. Twenty inflow scenarios are of a 10-year duration and are composed on the basis of historical data. Meyer-Peter and Müller and Engelund-Hansen formulae are applied for the calculation of sediment transport intensity. The methodology presented here seems to be a good tool for the prediction of long-term impacts on water surface profiles caused by sediment deposition and erosion.

A note on geochemistry of surface sediments from Krishna-Godavari basin, East Coast of India

Digital Repository Service at National Institute of Oceanography (India)

Pattan, J.N.; Parthiban, G.; PrakashBabu, C.; Khadge, N.H.; Paropkari, A.L.; Kodagali, V.N.

A closely spaced 75 surface sediments drawn from ‘Gas Hydrate` Project taken up by National Institute of Oceanography on a regional scale from the Krishna-Godavari Basin (Latitude I5 degrees 35 minutes to 16 degrees 20 minutes N; Longitude 81...

Residue determination and levels of glyphosate in surface waters, sediments and soils associated with oil palm plantation in Tasik Chini, Pahang, Malaysia

Science.gov (United States)

Mardiana-Jansar, K.; Ismail, B. S.

2014-09-01

Levels of glyphosate and its main metabolite were determined in surface water, soil and sediment samples from an oil palm plantation area located at Tasik Chini, Pahang, Malaysia. The optimization analytical method has been developed for the determination of glyphosate herbicide and its metabolite amino-methyl-phosphonic acid (AMPA) in surface waters to a level of 0.1μg/L, while in sediments and soils to a level of 0.5μg/g with a good linearity in the calibration range of 1-100μg/L. The procedure involves a pre-columnderivatization step with 9-fluorenyl-methyl-chloroformate (FMOC-Cl) yielding highly fluorescent derivatives of the analytes which can be determined by HPLC with fluorescence detection. In the field, levels of glyphosate in surface waters ranges from not detected to 1.0mg/L, while in soils and sediments were from not detected to 6.0mg/kg. For AMPA, the residues in surface waters were between not detected to 2.0mg/L, while in soil and sediment samples were from not detected to 5mg/kg. This variation of glyphosate and AMPA levels depended directly on time of pesticide application and the season.

Heavy metal contamination in surface sediments of Yangtze River intertidal zone: An assessment from different indexes

International Nuclear Information System (INIS)

Zhang Weiguo; Feng Huan; Chang Jinna; Qu Jianguo; Xie Hongxia; Yu Lizhong

2009-01-01

Surface sediments (0-5 cm) from 59 stations within the Yangtze River intertidal zone (YRIZ) were sampled for metal contamination analysis in April and August 2005. The concentrations ranged (in mg kg -1 dry weight): Al, 40,803-97,213; Fe, 20,538-49,627; Cd, 0.12-0.75; Cr, 36.9-173; Cu, 6.87-49.7; Mn, 413-1,112; Ni, 17.6-48.0; Pb, 18.3-44.1; and Zn, 47.6-154; respectively. Among the 59 sampling stations, enrichment factors (EF) indicate enrichment of Cd (52 stations), Cr (54 stations), Cu (5 stations), Ni (26 stations), Pb (5 stations) and Zn (5 stations). Geoaccumulation indexes (I geo ) also suggest individual metal contamination in localized areas. This study indicates that Cd, Cr and Ni enrichment in the YRIZ sediment is widespread whereas Cu, Mn, Pb and Zn enrichment is localized or nonexistent. Factor and cluster analyses indicate that Cd is associated with total organic carbon whereas Cu, Cr, Ni, Pb and Zn have a close association with Mn. - Surface sediment metal enrichment is evidenced for Cd, Cr and Ni in the Yangtze River intertidal zone.

CO2 leakage from carbon dioxide capture and storage (CCS) systems affects organic matter cycling in surface marine sediments.

Science.gov (United States)

Rastelli, Eugenio; Corinaldesi, Cinzia; Dell'Anno, Antonio; Amaro, Teresa; Greco, Silvestro; Lo Martire, Marco; Carugati, Laura; Queirós, Ana M; Widdicombe, Stephen; Danovaro, Roberto

2016-12-01

Carbon dioxide capture and storage (CCS), involving the injection of CO 2 into the sub-seabed, is being promoted worldwide as a feasible option for reducing the anthropogenic CO 2 emissions into the atmosphere. However, the effects on the marine ecosystems of potential CO 2 leakages originating from these storage sites have only recently received scientific attention, and little information is available on the possible impacts of the resulting CO 2 -enriched seawater plumes on the surrounding benthic ecosystem. In the present study, we conducted a 20-weeks mesocosm experiment exposing coastal sediments to CO 2 -enriched seawater (at 5000 or 20,000 ppm), to test the effects on the microbial enzymatic activities responsible for the decomposition and turnover of the sedimentary organic matter in surface sediments down to 15 cm depth. Our results indicate that the exposure to high-CO 2 concentrations reduced significantly the enzymatic activities in the top 5 cm of sediments, but had no effects on subsurface sediment horizons (from 5 to 15 cm depth). In the surface sediments, both 5000 and 20,000 ppm CO 2 treatments determined a progressive decrease over time in the protein degradation (up to 80%). Conversely, the degradation rates of carbohydrates and organic phosphorous remained unaltered in the first 2 weeks, but decreased significantly (up to 50%) in the longer term when exposed at 20,000 ppm of CO 2 . Such effects were associated with a significant change in the composition of the biopolymeric carbon (due to the accumulation of proteins over time in sediments exposed to high-pCO 2 treatments), and a significant decrease (∼20-50% at 5000 and 20,000 ppm respectively) in nitrogen regeneration. We conclude that in areas immediately surrounding an active and long-lasting leak of CO 2 from CCS reservoirs, organic matter cycling would be significantly impacted in the surface sediment layers. The evidence of negligible impacts on the deeper sediments should be

Residues of organochlorine pesticides in fish, crab and sediment from El Temsah Lake, Suez Canal, Egypt and their effect on mitochondrial ATPase of the New Zealand white rabbit.

Science.gov (United States)

Ahmed, M T; Ismail, S M

1991-01-01

Residues of organochlorine pesticides were monitored in the muscles of Bolti fish Tilapia zillii, the crab Lupa pelagicus and sediment samples collected from El Temsah lake around Ismailia using gas liquid chromatography. The beta isomer of hexachlorocyclohexane (beta.HCH) was the most dominant compound detected in all samples, followed by P, P-DDE and P, P-DDT. Results showed the crab to contain higher concentrations of organochlorine in comparison to concentrations detected in fish muscles. The In-vitro effect of the residues extracted from fish, and crab on the mitochondrial brain and liver ATPase of the New Zealand white rabbit Orcytolagus cuniculus was also studied. Residues of organochlorine pesticides have induced activation in the ATPase enzyme system of both brain and liver. The mixtures of organochlorine residues of both fish and crab were able to activate liver ATPase more than brain ATPase. The present study was conducted to extrapolate possible effects incurred on man if consumed such food.

Water erosion in surface soil conditions: runoff velocity, concentration and D50 index of sediments in runoff

OpenAIRE

Ramos,Júlio César; Bertol,Ildegardis; Barbosa,Fabrício Tondello; Bertól,Camilo; Mafra,Álvaro Luiz; Miquelluti,David José; Mecabô Júnior,José

2016-01-01

ABSTRACT Water erosion and contamination of water resources are influenced by concentration and diameter of sediments in runoff. This study aimed to quantify runoff velocity and concentration and the D50 index of sediments in runoff under different soil surface managements, in the following treatments: i) cropped systems: no-tilled soil covered by ryegrass (Lolium multiflorum Lam.) residue, with high soil cover and minimal roughness (HCR); no tilled soil covered by vetch (Vicia sativa L.) res...

Pollution, toxicity, and ecological risk of heavy metals in surface river sediments of a large basin undergoing rapid economic development.

Science.gov (United States)

Tang, Wenzhong; Zhang, Chao; Zhao, Yu; Shan, Baoqing; Song, Zhixin

2017-05-01

A comprehensive and detailed investigation of heavy metal pollution, toxicity, and ecological risk assessment was conducted for the surface river sediments of the Haihe Basin in China based on 220 sampling sites selected in 2013. The average concentrations of Cr, Cu, Ni, Pb, and Zn in the sediments were 129 mg/kg, 63.4 mg/kg, 36.6 mg/kg, 50.0 mg/kg, and 202 mg/kg, respectively. As indicated by the geoaccumulation and pollution load indices, most surface river sediments of the Haihe Basin were contaminated with the investigated metals, especially in the junction region of the Zi Ya He and Hei Long Gang watersheds. The 5 heavy metals in the sediments all had anthropogenic sources, and the enrichment degrees followed the order Cu > Pb > Zn > Cr > Ni, with mean enrichment factors of 3.27, 2.77, 2.58, 1.81, and 1.44, respectively. According to the mean index of comprehensive potential ecological risk (38.9), the studied sediments of the Haihe Basin showed low potential ecological risk, but the sediments were potentially biologically toxic based on the mean probable effect concentration quotient (0.547), which may be the result of speciation of the 5 metals in the sediments. The results indicate that heavy metal pollution should be considered during the development of ecological restoration strategies in the Haihe Basin. Environ Toxicol Chem 2017;36:1149-1155. © 2016 SETAC. © 2016 SETAC.

Petroleum Hydrocarbon in Surface Sediment from Coastal Area of Putatan and Papar, Sabah

International Nuclear Information System (INIS)

Siti Aishah Mohd Ali; Rohana Tair; Yang, S.Z.; Masni Mohd Ali

2013-01-01

Total petroleum hydrocarbons (TPH) and percent total organic carbon (TOC) were investigated in surface sediments from coastal area of Papar and Putatan, Sabah. Samples were collected in five different stations in each area by using Ponar grab sampler. Samples were extracted with Soxhlet, concentrated and analyzed by using UV/ VIS spectrophotometer. The overall mean and range of TPH concentrations in the sediments from coastal area of Papar and Putatan were 1.95 (0.53-4.59 mg/ kg dw Miri crude oil equivalents) and 0.85 (0.26-1.64 mg/ kg dw Miri crude oil equivalents) respectively. Meanwhile, the TOC ranged from 0.81-2.32 % and 0.35-0.81 % respectively. Statistical analysis using Pearson correlation showed no significant differences between TPH and TOC (p<0.05) in both areas. (author)

Spatial distribution of trace elements in the surface sediments of a major European estuary (Loire Estuary, France): Source identification and evaluation of anthropogenic contribution

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Coynel, Alexandra; Gorse, Laureline; Curti, Cécile; Schafer, Jörg; Grosbois, Cécile; Morelli, Guia; Ducassou, Emmanuelle; Blanc, Gérard; Maillet, Grégoire M.; Mojtahid, Meryem

2016-12-01

Assessing the extent of metal contamination in estuarine surface sediments is hampered by the high heterogeneity of sediment characteristics, the spatial variability of trace element sources, sedimentary dynamics and geochemical processes in addition to the need of accurate reference values for deciphering natural to anthropogenic contribution. Based on 285 surface sediment samples from the Loire Estuary, the first high-resolution spatial distributions are presented for grain-size, particulate organic carbon (POC) and the eight metals/metalloids identified as priority contaminants (Cd, Zn, Pb, Cu, As, Cr, Ni, Hg) plus Ag (an urban tracer). Grain-size and/or POC are major factors controlling the spatial distribution of trace element concentrations. The V-normalized trace metal concentrations divided by the V-normalized concentrations in the basin geochemical background showed the highest Enrichment Factors for Ag and Hg (EF; up to 34 and 140, respectively). These results suggest a severe contamination in the Loire Estuary for both elements. Intra-estuarine Ag and Hg anomalies were identified by comparison between respective normalized concentrations in the Loire Estuary surface sediments and those measured in the surface sediments at the outlet of the Loire River System (watershed-derived). Anthropogenic intra-estuarine Ag and Hg stocks in the uppermost centimetre of the sediment compared with rough annual fluvial flux estimates suggest that the overall strong Enrichment Factors for Ag (EFAg) and and Hg (EFHg) in the Loire Estuary sediments are mainly due to watershed-derived inputs, highlighting the need of high temporal hydro-geochemical monitoring to establish reliable incoming fluxes. Significant correlations obtained between EFCd and EFAg, EFCu and POC and EFHg and POC revealed common behavior and/or sources. Comparison of trace element concentrations with ecotoxicological indices (Sediment Quality Guidelines) provides first standardized information on the

Demersal fish assemblages off southern New Zealand in relation to depth and temperature

Science.gov (United States)

Jacob, W.; McClatchie, S.; Probert, P. K.; Hurst, R. J.

1998-12-01

We examined the relationship between demersal fish assemblage and depth, temperature, latitude and longitude off southern New Zealand (46-54°S and 165-180°E) in water depths of 80-787 m. Catch weight data were analysed by two-way indicator analysis (TWIA), groupaverage agglomerative clustering (UPGMA) and Detrended Correspondence Analysis (DCA). The spatial pattern of demersal fish off southern New Zealand conforms to the concept of species groups or fish assemblages related to environmental gradients. Shallow-water assemblages were dominated by species from the families Gempylidae, Squalidae, Triakidae and Moridae, mainly represented by Thyrsites atun, Squalus acanthias, Galeorhinus australis, and Pseudophycis bachus. Deep water assemblages were dominated by Chimaeridae, Argentinidae, Merlucciidae and Macrouridae, mainly represented by Hydrolagus novaezelandiae, Argentina elongata, Macruronus novaezelandiae, and Lepidorhynchus denticulatus. Total catch weight was often dominated by Merlucciidae, Macrouridae and Gempylidae. Fish assemblages were related to discrete ranges of depth (300 m) and temperature (9.5°C), but the range of sediment types was too narrow to show any correlation.

Distribution and sources of organic matter in surface sediments of the eastern continental margin of India

Digital Repository Service at National Institute of Oceanography (India)

Krishna, M.S.; Naidu, S.A.; Subbaiah, Ch.V.; Sarma, V.V.S.S.; Reddy, N.P.C.

of the northern and western Gulf of Mexico, the north coast of Alaska and the Niger Delta [Gearing et al., 1977], surface sediments from the Beaufort shelf, Beaufort Sea [Goni et al., 2000], coastal sediments from the Gulf of Trieste, N Adriatic Sea [Ogrinc et... the chemical composition of SOC off the Washington margin [Keil et al. 1994; Prahl et al. 1994], Amazon [Goni, 1997], Bengal fans [Lanord and Derry, 1994], and Gulf of Mexico [Goni et al. 1997]. Other possible reason could be preferential removal of N...

The Effect of Source Suspended Sediment Concentration on the Sediment Dynamics of a Macrotidal Creek and Salt Marsh

Science.gov (United States)

Poirier, E.; van Proosdij, D.; Milligan, T. G.

2017-12-01

Seasonal variability in the sediment dynamics of a Bay of Fundy tidal creek and salt marsh system was analyzed to better understand the ecomorphodynamics of a high suspended sediment concentration intertidal habitat. Data were collected over 62 tides for velocity, suspended sediment concentration, deposition, and grain size at four stations from the creek thalweg to the marsh surface. Five topographic surveys were also conducted throughout the 14-month study. Deposition rates per tide varied spatially from 56.4 g·m-2 at the creek thalweg to 15.3 g·m-2 at the marsh surface. Seasonal variations in deposition in the creek and marsh surface were from 38.0 g·m-2 to 97.7 g·m-2 and from 12.2 g·m-2 to 19.6 g·m-2 respectively. Deposition and erosion were greatest in late fall and winter. This seasonal change, led by higher suspended sediment concentrations, was observed in the creek and at the marsh bank but notably absent from the marsh edge and marsh surface. Sediments were predominantly deposited in floc form (76-83%). Because of high floc content, higher suspended sediment concentrations led to more rapid loss of sediment from suspension. With increasing sediment concentration, deposition increased in the tidal creek and at the marsh bank but not at the marsh edge or marsh surface. This suggests that in highly flocculated environments the water column clears fast enough that very little sediment remains in suspension when the water reaches the marsh and that the sediment concentration during marsh inundation is independent of the initial concentration in the creek.

Elemental concentration and potential ecological risk assessment of reef associated surface sediments of Appa Island, Gulf of Mannar Biosphere Reserve, Southeast coast of India.

Science.gov (United States)

Saravanan, P; Krishnakumar, S; Silva, Judith D; Pradhap, D; Vidyasakar, A; Radhakrishnan, K; Godson, Prince S; Arumugam, K; Magesh, N S

2018-03-01

Thirty three surface sediments were collected for the present study to assess the elemental concentration and its associated ecological risk in the reef associated surface sediments, Appa Island, Gulf of Mannar Biosphere Reserve, South east coast of India. The distribution of calcium carbonate in the reef sediments is controlled by coral debris and shell fragments whereas the Organic matter (OM) content are chiefly derived from mangroves and sea grasses. The circulation of trace elements and Fe, Mn are controlled by the fluvial process and re-suspended sediments. The concentration of Pb was primarily controlled by migration of pollutants through long shore sediment transport process. The main source of Pb in the study area is from coal incinerating power plants and coal handling operations from harbors. Copyright © 2018 Elsevier Ltd. All rights reserved.

Mercury cycling in surface water, pore water and sediments of Mugu Lagoon, CA, USA

Energy Technology Data Exchange (ETDEWEB)

Rothenberg, Sarah E. [Environmental Science and Engineering Program, Box 951772, University of California, Los Angeles, CA 90095-1772 (United States)], E-mail: rothenberg.sarah@gmail.com; Ambrose, Richard F. [Environmental Science and Engineering Program, Box 951772, University of California, Los Angeles, CA 90095-1772 (United States); Department of Environmental Health Sciences, Box 951772, University of California, Los Angeles, CA 90095-1772 (United States)], E-mail: rambrose@ucla.edu; Jay, Jennifer A. [Department of Civil and Environmental Engineering, Box 951593, University of California, Los Angeles, CA 90095-1593 (United States)], E-mail: jjay@seas.ucla.edu

2008-07-15

Mugu Lagoon is an estuary in southern California, listed as impaired for mercury. In 2005, we examined mercury cycling at ten sites within at most four habitats. In surface water (unfiltered and filtered) and pore water, the concentration of total mercury was correlated with methylmercury levels (R{sup 2} = 0.29, 0.26, 0.27, respectively, p < 0.05), in contrast to sediments, where organic matter and reduced iron levels were most correlated with methylmercury content (R{sup 2} = 0.37, 0.26, respectively, p < 0.05). Interestingly, levels for percent methylmercury of total mercury in sediments were higher than typical values for estuarine sediments (average 5.4%, range 0.024-38%, n = 59), while pore water methylmercury K{sub d} values were also high (average 3.1, range 2.0-4.2 l kg{sup -1}, n = 39), and the estimated methylmercury flux from sediments was low (average 1.7, range 0.14-5.3 ng m{sup -2} day{sup -1}, n = 19). Mercury levels in predatory fish tissue at Mugu are >0.3 ppm, suggesting biogeochemical controls on methylmercury mobility do not completely mitigate methylmercury uptake through the food web. - Trends in mercury cycling differed between habitats and within matrices at Mugu Lagoon.

Heavy metal concentration in mangrove surface sediments from the north-west coast of South America.

Science.gov (United States)

Fernández-Cadena, J C; Andrade, S; Silva-Coello, C L; De la Iglesia, R

2014-05-15

Mangrove ecosystems are coastal estuarine systems confined to the tropical and subtropical regions. The Estero Salado mangrove located in Guayaquil, Ecuador, has suffered constant disturbances during the past 20 years, due to industrial wastewater release. However, there are no published data for heavy metals present in its sediments and the relationship with anthropogenic disturbance. In the present study, metal concentrations were evaluated in surface sediment samples of the mangrove, showing that B, Cd, Cu, Pb, Se, V, and Zn levels exceeded those declared in international environmental quality standards. Moreover, several metals (Pb, Sn, Cd, Ag, Mo, Zn and Ni) could be linked to the industrial wastewater present in the studied area. In addition, heavy metal levels detected in this mangrove are higher than previous reports on mangrove sediments worldwide, indicating that this mangrove ecosystem is one of the most disrupted on earth. Copyright © 2014 Elsevier Ltd. All rights reserved.

Petroleum hydrocarbon concentration in surface sediments in continental shelf region along the central west coast of India

Digital Repository Service at National Institute of Oceanography (India)

Ram, A.; Kadam, A.N.

Gas chromatography revealed that nonpolar material extracted from surface sediments collected along the northern west coast of India was originated from petroleum hydrocarbon residue. Petroleum hydrocarbon levels as determinEd. by fluorescence...

Horizontal and vertical distribution of lignin in surface sediments of the Gdansk Basin

Directory of Open Access Journals (Sweden)

Andrzej Staniszewski

2001-12-01

Full Text Available The aim of this study was to identify and quantify lignin transported from the River Vistula to the accumulation area in the Gdansk Basin. Sediment samples collected along the Vistula mouth - Gdansk Deep transect were analysed for lignin. Lignin was characterised by oxidative degradation, cupric oxide being chosen as the most suitable oxidising agent. The polar functional groups of the oxidation products were silylated and the derivatives analysed by capillary gas chromatography on fused capillary silica columns with flame ionisation detection. Lignin-derived oxidation products were quantified in the range from 3 to 20 µg g-1 dry wt. for phenolic acids and from 6 to 12 µg g-1 dry wt. for phenolic aldehydes. Differences in oxidation products contents are assigned to different lignin sources in the marine environment. The horizontal and vertical gradients of these compounds in the sediments of the Gdansk Basin are documented. The results are discussed in terms of the origin and fate of organic matter in the Gdansk Basin. The measured differences in quality and quantity of the identified oxidation products provide insight into diagenetic processes in the surface marine sediments.

Natural vs human-induced changes at the Tauranga Harbour area (New Zealand): a time -series acoustic seabed classification comparison

Science.gov (United States)

Capperucci, Ruggero Maria; Bartholomä, Alexander; Renken, Sabrina; De Lange, Willem

2013-04-01

The Tauranga Harbour Bay (New Zealand) is a mesotidal estuary system, enclosed by the Matakana barrier island. It hosts the leading export port in New Zealand and the second largest import port by value. Coastal changes are well documented over the last decades, mainly at the southern entrance of the area, between Matakana Island and Mt. Maunganui. It is an extremely dynamic environment, where natural processes are strongly influenced by human activities. In particular, the understanding of the recent evolution of the system is crucial for policymakers. In fact, the cumulative impact due to the maintenance of the port (mainly dredging activities, shipping, facilities construction, but also increasing tourism) and its already approved expansion clashes with the claim of the local Maori communities, which recently leaded to a court action. A hydroacoustic multiple-device survey (Side-scan Sonar SSS, Multibeam Echo-sounder MBES and Single Beam Echo-sounder) coupled with sediment sampling was carried out in March 2011 over an area of 0.8 km2, southern Matakana Island, along the Western Channel. The area is not directly impacted by dredging activities, resulting in an optimal testing site for assessing indirect effects of human disturbance on coastal dynamics. The main goals were: 1. To test the response of different acoustic systems in such a highly dynamic environment; 2. To study the influence of dredging activities on sediment dynamics and habitat changes, by means of comparing the current data with existing ones, in order to distinguish between natural and human induced changes Results demonstrate a good agreement between acoustic classifications from different systems. They seem to be mainly driven by the sediment distribution, with a distinctive fingerprint given by shells and shell fragments. Nevertheless, the presence of relevant topographic features (i.e. large bedform fields) influences swath-looking systems (SSS and MBES). SSS and MBES classifications tend

Temporal–spatial variation and partitioning prediction of antibiotics in surface water and sediments from the intertidal zones of the Yellow River Delta, China

International Nuclear Information System (INIS)

Zhao, Shengnan; Liu, Xinhui; Cheng, Dengmiao; Liu, Guannan; Liang, Baocui; Cui, Baoshan; Bai, Junhong

2016-01-01

As special zones, the intertidal zones of the Yellow River Delta (YRD) are highly variable along with time and space. Fluvial–marine and land–ocean interactions which frequently occur in these areas have a great impact on the fate of pollutants. Antibiotics, which contribute to antibiotic-resistant genes (ARGs), are widely detected in wastewater, natural water, soil, sediments, and even drinking water. Therefore, it is meaningful to investigate the occurrence and fate of antibiotics in these special zones. In this study, eight antibiotics belonging to tetracyclines (TCs), fluoroquinolones (FQs), and macrolides (MLs) were detected in the surface water and sediments from the intertidal zones of YRD during two seasons. Two models were established to predict the partitioning coefficients of norfloxacin (NOR) and erythromycin (ETM) using physicochemical properties of sediments, respectively. The total concentrations of these antibiotics were 82.94–230.96 ng·L"− "1 and 40.97–207.44 ng·g"− "1, respectively, in the surface water and sediments. Seasonal variation was mainly influenced by the frequency of antibiotics use and environment factors. The regions with river supply exhibited the highest concentrations of antibiotics in surface water and sediments. Meanwhile, particle-size fractions, cation exchange capability (CEC), and metal ions content played dominant roles in the partitioning behaviors of NOR and ETM between the surface water and sediments. Both models established in this study featured accuracy and feasibility, which provided the methods for predicting the partitioning coefficients of emerging contaminants similar in structures to NOR and ETM in the intertidal zones. - Highlights: • The intertidal zones of YRD were polluted by antibiotics to some extent. • The river supply was a major pathway for the antibiotic pollution of the intertidal zones of YRD. • The partitioning coefficients of NOR and ETM can be predicted using the physicochemical

Terrestrial Sediments of the Earth: Development of a Global Unconsolidated Sediments Map Database (GUM)

Science.gov (United States)

Börker, J.; Hartmann, J.; Amann, T.; Romero-Mujalli, G.

2018-04-01

Mapped unconsolidated sediments cover half of the global land surface. They are of considerable importance for many Earth surface processes like weathering, hydrological fluxes or biogeochemical cycles. Ignoring their characteristics or spatial extent may lead to misinterpretations in Earth System studies. Therefore, a new Global Unconsolidated Sediments Map database (GUM) was compiled, using regional maps specifically representing unconsolidated and quaternary sediments. The new GUM database provides insights into the regional distribution of unconsolidated sediments and their properties. The GUM comprises 911,551 polygons and describes not only sediment types and subtypes, but also parameters like grain size, mineralogy, age and thickness where available. Previous global lithological maps or databases lacked detail for reported unconsolidated sediment areas or missed large areas, and reported a global coverage of 25 to 30%, considering the ice-free land area. Here, alluvial sediments cover about 23% of the mapped total ice-free area, followed by aeolian sediments (˜21%), glacial sediments (˜20%), and colluvial sediments (˜16%). A specific focus during the creation of the database was on the distribution of loess deposits, since loess is highly reactive and relevant to understand geochemical cycles related to dust deposition and weathering processes. An additional layer compiling pyroclastic sediment is added, which merges consolidated and unconsolidated pyroclastic sediments. The compilation shows latitudinal abundances of sediment types related to climate of the past. The GUM database is available at the PANGAEA database (https://doi.org/10.1594/PANGAEA.884822).

Radioactivity in New Zealand meat products

Energy Technology Data Exchange (ETDEWEB)

NONE

1986-07-01

Full text: New Zealand has no nuclear power programme of radioactive waste disposal programme. The only artificial radioactivity detectable in the New Zealand environment is global fallout from nuclear weapons tests conducted mainly in the northern hemisphere before 1964. This fallout in New Zealand is currently at its lowest level since environmental monitoring began in 1960. The total beta activity deposited in rain during 1985, for example, averaged 76 MBQ/km{sup 2}, with most of that being due to naturally occurring radionuclides, principally lead-210/Bismuth-210. Levels of artificial radioactivity in New Zealand dairy products reflect this very low deposition rate. During 1985, for example, Strontium-90 and Caesium-137 levels in cow's milk averaged 0.035 BG/GCA and 0.27BQ/QK respectively. Those levels were similar to, or less than, levels reported in northern hemisphere countries during 1985. No change in environmental contamination levels has been recorded in New Zealand during 1985. The very low deposition rate and milk contamination levels indicate that fallout contamination levels generally are insignificant in New Zealand and monitoring of other foodstuffs such as meat products is not warranted. (author)

Radioactivity in New Zealand meat products

International Nuclear Information System (INIS)

1986-01-01

Full text: New Zealand has no nuclear power programme of radioactive waste disposal programme. The only artificial radioactivity detectable in the New Zealand environment is global fallout from nuclear weapons tests conducted mainly in the northern hemisphere before 1964. This fallout in New Zealand is currently at its lowest level since environmental monitoring began in 1960. The total beta activity deposited in rain during 1985, for example, averaged 76 MBQ/km 2 , with most of that being due to naturally occurring radionuclides, principally lead-210/Bismuth-210. Levels of artificial radioactivity in New Zealand dairy products reflect this very low deposition rate. During 1985, for example, Strontium-90 and Caesium-137 levels in cow's milk averaged 0.035 BG/GCA and 0.27BQ/QK respectively. Those levels were similar to, or less than, levels reported in northern hemisphere countries during 1985. No change in environmental contamination levels has been recorded in New Zealand during 1985. The very low deposition rate and milk contamination levels indicate that fallout contamination levels generally are insignificant in New Zealand and monitoring of other foodstuffs such as meat products is not warranted. (author)

Assessment of the ecotoxicity of urban estuarine sediment using benthic and pelagic copepod bioassays

Directory of Open Access Journals (Sweden)

Maria P. Charry

2018-05-01

Full Text Available Urban estuarine sediments are sinks to a range of contaminants of anthropogenic origin, and a key challenge is to characterize the risk of these compounds to receiving environments. In this study, the toxicity of urban estuarine sediments was tested using acute and chronic bioassays in the benthic harpacticoid Quinquelaophonte sp., and in the planktonic calanoid Gladioferens pectinatus, two New Zealand copepod species. The sediment samples from the estuary tributary sites significantly impacted reproduction in Quinquelaophonte sp. However, results from one of the estuary sites were not significantly different to those from the tributaries sites, suggesting that chemicals other than trace metals, polycyclic aromatic hydrocarbons and ammonia may be the causative stressors. Sediment elutriate samples had significant effects on reproductive endpoints in G. pectinatus, and on the induction of DNA damage in cells, as shown by the comet assay. The results indicate that sediment contamination at the Ahuriri Estuary has the potential to impact biological processes of benthic and pelagic organisms. The approach used provides a standardized methodology to assess the toxicity of estuarine sediments.

Assessment of the ecotoxicity of urban estuarine sediment using benthic and pelagic copepod bioassays.

Science.gov (United States)

Charry, Maria P; Keesing, Vaughan; Costello, Mark; Tremblay, Louis A

2018-01-01

Urban estuarine sediments are sinks to a range of contaminants of anthropogenic origin, and a key challenge is to characterize the risk of these compounds to receiving environments. In this study, the toxicity of urban estuarine sediments was tested using acute and chronic bioassays in the benthic harpacticoid Quinquelaophonte sp., and in the planktonic calanoid Gladioferens pectinatus , two New Zealand copepod species. The sediment samples from the estuary tributary sites significantly impacted reproduction in Quinquelaophonte sp. However, results from one of the estuary sites were not significantly different to those from the tributaries sites, suggesting that chemicals other than trace metals, polycyclic aromatic hydrocarbons and ammonia may be the causative stressors. Sediment elutriate samples had significant effects on reproductive endpoints in G. pectinatus , and on the induction of DNA damage in cells, as shown by the comet assay. The results indicate that sediment contamination at the Ahuriri Estuary has the potential to impact biological processes of benthic and pelagic organisms. The approach used provides a standardized methodology to assess the toxicity of estuarine sediments.

The Contribution of Opal-Associated Phosphorus to Bioavailable Phosphorus in Surface and Core Sediments in the East China Sea

Science.gov (United States)

Li, Huanxin; He, Huijun; Yang, Shifeng; Liu, Yanli; Che, Hong; Li, Mujian; Zhang, Jing

2018-06-01

To improve the burial flux calculations of bioavailable phosphorus (P) and study opal-associated P (Opal-P) in the East China Sea (ECS), surface and core sediments were collected in the Changjiang Estuary (CE) and the south of the Cheju Island. In this study, sedimentary P was operationally divided into seven different forms using modified sedimentary extraction (SEDEX) technique: LSor-P (exchangeable or loosely sorbed P), Fe-P (easily reducible or reactive ferric Fe-bound P), CFA-P (authigenic carbonate fluorapatite and biogenic apatite and CaCO3-bound P), Detr-P (detrital apatite), Org-P (organic P), Opal-P and Ref-P (refractory P). The data revealed that the concentrations of the seven different P forms rank as Detr-P > CFA-P > Org-P > Ref-P > Opal-P > Fe-P > LSor-P in surface sediments and CFA-P > Detr-P > Org-P > Ref-P > Fe-P > Opal-P > LSor-P in core sediments. The distributions of the total phosphorus (TP), TIP, CFA-P, Detr-P are similar and decrease from the CE to the south of the Cheju Island. Meanwhile, Org-P and Opal-P exhibit different distribution trends; this may be affected by the grain size and TOM. The concentrations of potentially bioavailable P are 9.6-13.0 μmol g-1 and 10.0-13.6 μmol g-1, representing 61%-70% and 41%-64% of the TP in surface and core sediments, respectively. The concentrations of Opal-P are 0.6-2.3 μmol g-1 and 0.6-1.4 μmol g-1 in surface and core sediments, accounting for 5.3%-19.8% and 4.2%-10.6% of bioavailable P, respectively. The total burial fluxes of Opal-P and bioavailable P are 1.4×109 mol yr-1 and 1.1×1010 mol yr-1 in the ECS, respectively. Opal-P represents about 12.7% of potentially bioavailable P, which should be recognized when studying P cycling in marine ecosystems.

Distribution and partitioning of heavy metals in estuarine sediment cores and implications for the use of sediment quality standards

Directory of Open Access Journals (Sweden)

K. L. Spencer

2002-01-01

Full Text Available Total metal concentrations in surface sediments and historically contaminated sediments were determined in sediment cores collected from three estuaries (Thames, Medway and Blackwater in south-east England. The partitioning behaviour of metals in these sediments was also determined using a sequential extraction scheme. These data were then compared with sediment quality values (SQVs to determine the potential ecotoxicological risk to sediment dwelling organisms. When total metal concentrations in surface sediments are examined, no risk to biota in any of the estuaries is indicated. However, when historically contaminated sediments at depth are also considered, risks to biota are apparent and are greatest for the Thames, followed by the Medway and then the Blackwater. This suggests that regulatory authorities should examine vertical metal profiles, particularly in estuaries that are experiencing low sediment accumulation rates where historically contaminated sediments are in the shallow sub-surface zone and where erosion or dredging activities may take place. When metal partitioning characteristics are also considered, the risk to biota is comparable for the Medway and the Blackwater with the potentially bioavailable fraction presenting no ecotoxicological risk. Conversely, over 70% of metals are labile in the Thames Estuary sediments and toxic effects are probable. This suggests that the application of SQVs using total sediment metal concentrations may over- or under-estimate the risk to biota in geochemically dissimilar estuarine sediments. Keywords: sediment quality values, estuarine sediments, metal contamination, partitioning, sequential extraction

Sedimentology, geochronology and micropaleontology of post- and immediately pre-European Lake Tekapo sediment (based on analysis of core L1395)

International Nuclear Information System (INIS)

Graham, I.J.; Alloway, B.V.; Cochran, U.; Cook, R.A.; Ditchburn, R.G.; Mildenhall, D.C.; Morgenstern, U.; Prior, C.A.

2005-01-01

This report details sedimentological, geochronological and micropaleontological research on Lake Tekapo sediment core L1395, extracted by NIWA in November 1991. In addition to assessing the reliability of classical 'varve' counting to determine sedimentation rates, the report outlines various options for dating glacial lake sediments in southern New Zealand, and makes recommendations with respect to planned drilling of nearby Lake Pukaki. An ambitious project was launched in July 2002 within GNS's 'Global Change Through Time' PGST research program (C05X0202) to investigate New Zealand's Holocene climatic record via a deep drill core into Lake Pukaki sediment. Lake Pukaki, a pro-glacial lake similar to Lake Tekapo is located on the eastern side of the Southern Alps adjacent to Mount Cook (Aoraki), and has received ca. 400m of sediment from its catchment since forming ca. 16 k.y. ago. Its sedimentary record, therefore, has the potential to reveal a high resolution record of paleo-climatic fluctuations, provided that the appropriate climatic proxies can be identified and a robust and precise chronology can be established. This report focuses on sedimentological analysis, the principal radiometric methods available for dating lacustrine sediments within a 0-50 k.y. time-frame, and preliminary micropaleontological investigations. Lake Tekapo contains an almost complete record of sedimentation covering the past ca. 16 k.y. and hence also a record of storm events and more subtle changes in climate during that time. However, the temperate climate of the region contrasts with that of many previous lake bed studies in North America and Europe, creating new challenges for deriving robust climate proxies from the sedimentary record. (author). 124 refs., 40 figs., 21 tabs

Spatial Variation, Pollution Assessment and Source Identification of Major Nutrients in Surface Sediments of Nansi Lake, China

Directory of Open Access Journals (Sweden)

Longfeng Wang

2017-06-01

Full Text Available Nansi Lake has been seriously affected by intensive anthropogenic activities in recent years. In this study, an extensive survey on spatial variation, pollution assessment as well as the possible sources identification of major nutrients (Total phosphorus: TP, Total nitrogen: TN, and Total organic carbon: TOC in the surface sediments of Nansi Lake was conducted. Results showed that the mean contents of TP, TN and TOC were 1.13-, 5.40- and 2.50- fold higher than their background values respectively. Most of the TN and TOC contents in the surface sediments of Nansi Lake were four times as high or higher and twice as high or higher than the background values except the Zhaoyang sub-lake, and the spatial distribution of TN and TOC contents were remarkably similar over a large area. Nearly all the TP contents in the surface sediments of Nansi Lake were all higher than its background values except most part of the Zhaoyang sub-lake. Based on the enrichment factor (EF and the organic pollution evaluation index (Org-index, TP, TOC and TN showed minor enrichment (1.13, minor enrichment (2.50 and moderately severe enrichment (5.40, respectively, and most part of the Dushan sub-lake and the vicinity of the Weishan island were in moderate or heavy sediments organic pollution, while the other parts were clean. Moreover, according to the results of multivariate statistical analysis, we deduced that anthropogenic TN and TOC were mainly came from industrial sources including enterprises distributed in Jining, Yanzhou and Zoucheng along with iron and steel industries distributed in the southern of the Weishan sub-lake, whereas TP mainly originated from runoff and soil erosion coming from agricultural lands located in Heze city and Weishan island, the local aquacultural activities as well as the domestic sewage discharge of Jining city.

Trigonium curvatus sp nov and Trigonium arcticum (Bacillariophyceae) from the surface sediments of Prydz Bay, east Antarctica

Digital Repository Service at National Institute of Oceanography (India)

Abhilash, N.; Mohan, R.; Shetye, S.; Gazi, S.; Jafar, S.A

Here we propose a new species of genus Trigonium namely Trigonium curvatus from the surface sediments of coastal Antarctica A comparative study was done between Trigonium curvatus and Trigonium arcticum to find out the differential morphological...

Investigation of the role of gas hydrates in continental slope stability west of Fiordland, New Zealand

OpenAIRE

Crutchley, Gareth; Gorman, Andrew R.; Fohrmann, Miko

2007-01-01

Sediment weakening due to increased local pore fluid pressure is interpreted to be the cause of a submarine landslide that has been seismically imaged off the southwest coast of New Zealand. Data show a distinct and continuous bottom‐simulating reflection (BSR)—a seismic phenomena indicative of the presence of marine gas hydrate—below the continental shelf from water depths of c. 2400 m to c. 750 m, where it intersects the seafloor. Excess pore fluid pressure (EPP) generated in a free gas zon...

Effect of Cosolutes on the Sorption of Phenanthrene onto Mineral Surface of River Sediments and Kaolinite

Directory of Open Access Journals (Sweden)

Yinghong Wu

2014-01-01

Full Text Available Sorption of phenanthrene onto the natural sediment with low organic carbon content (OC%, organic-free sediment, and kaolinite was investigated through isotherm experiments. Effects of cosolutes (pyrene, 4-n-nonyphenol (NP, and humic acid (HA on phenanthrene sorption were also studied by comparing apparent solid-water distribution coefficients (Kdapp of phenanthrene. Two addition sequences, including “cosolute added prior to phenanthrene” and “cosolute and phenanthrene added simultaneously,” were adopted. The Freundlich model fits phenanthrene sorption on all 3 sorbents well. The sorption coefficients on these sorbents were similar, suggesting that mineral surface plays an important role in the sorption of hydrophobic organic contaminants on low OC% sediments. Cosolutes could affect phenanthrene sorption on the sorbents, which depended on their properties, concentrations, and addition sequences. Pyrene inhibited phenanthrene sorption. Sorbed NP inhibited phenanthrene sorption at low levels and promoted sorption at high levels. Similar to NP, effect of HA on phenanthrene sorption onto the natural sediment depended on its concentrations, whereas, for the organic-free sediment and kaolinite, preloading of HA at high levels led to an enhancement in phenanthrene Kdapp while no obvious effect was observed at low HA levels; dissolved HA could inhibit phenanthrene sorption on the two sorbents.

TBA biodegradation in surface-water sediments under aerobic and anaerobic conditions.

Science.gov (United States)

Bradley, Paul M; Landmeyer, James E; Chapelle, Francis H

2002-10-01

The potential for [U-14C] TBA biodegradation was examined in laboratory microcosms under a range of terminal electron accepting conditions. TBA mineralization to CO2 was substantial in surface-water sediments under oxic, denitrifying, or Mn(IV)-reducing conditions and statistically significant but low under SO4-reducing conditions. Thus, anaerobic TBA biodegradation may be a significant natural attenuation mechanism for TBA in the environment, and stimulation of in situ TBA bioremediation by addition of suitable terminal electron acceptors may be feasible. No degradation of [U-14C] TBA was observed under methanogenic or Fe(III)-reducing conditions.

Metal concentrations in surface sediments of Paraiba do Sul River (Brazil)

International Nuclear Information System (INIS)

Pereira, M.O.; Calza, C.; Lopes, R.T.; Anjos, M.J.; UERJ, Rio de Janeiro; Araujo, F.G.

2006-01-01

The Paraiba do Sul River is located in a strategic region between the most important urban and industrial centers of Brazil. In the last years, an increase in the water pollution has been reported, caused by the untreated domestic sewerage of the inhabitants, effluents discharged by various industries, mining activities and sand extraction from the riverbed. This work used total reflection X-ray fluorescence with synchrotron radiation (SRTXRF) to determine metals in the bioavailable and residual fractions from the surface sediments. The metals identified were Ti, Cr, Mn, Fe, Cu, Zn, Rb, Sr, Ba and Pb. (author)

Regional distribution patterns of chemical parameters in surface sediments of the south-western Baltic Sea and their possible causes

Science.gov (United States)

Leipe, T.; Naumann, M.; Tauber, F.; Radtke, H.; Friedland, R.; Hiller, A.; Arz, H. W.

2017-12-01

This study presents selected results of a sediment geochemical mapping program of German territorial waters in the south-western Baltic Sea. The field work was conducted mainly during the early 2000s. Due to the strong variability of sediment types in the study area, it was decided to separate and analyse the fine fraction (<63 μm, mud) from more than 600 surficial samples, combined with recalculations for the bulk sediment. For the contents of total organic carbon (TOC) and selected elements (P, Hg), the regional distribution maps show strong differences between the analysed fine fraction and the recalculated total sediment. Seeing that mud contents vary strongly between 0 and 100%, this can be explained by the well-known grain-size effect. To avoid (or at least minimise) this effect, further interpretations were based on the data for the fine fraction alone. Lateral transport from the large Oder River estuary combined with high abundances and activities of benthic fauna on the shallow-water Oder Bank (well sorted fine sand) could be some main causes for hotspots identified in the fine-fraction element distribution. The regional pattern of primary production as the main driver of nutrient element fixation (C, N, P, Si) was found to be only weakly correlated with, for example, the TOC distribution in the fine fraction. This implies that, besides surface sediment dynamics, local conditions (e.g. benthic secondary production) also have strong impacts. To the best of the authors' knowledge, there is no comparable study with geochemical analyses of the fine fraction of marine sediments to this extent (13,600 km2) and coverage (between 600 and 800 data points) in the Baltic Sea. This aspect proved pivotal in confidently pinpointing geochemical "anomalies" in surface sediments of the south-western Baltic Sea.

Microbial Communities and Organic Matter Composition in Surface and Subsurface Sediments of the Helgoland Mud Area, North Sea

Science.gov (United States)

Oni, Oluwatobi E.; Schmidt, Frauke; Miyatake, Tetsuro; Kasten, Sabine; Witt, Matthias; Hinrichs, Kai-Uwe; Friedrich, Michael W.

2015-01-01

The role of microorganisms in the cycling of sedimentary organic carbon is a crucial one. To better understand relationships between molecular composition of a potentially bioavailable fraction of organic matter and microbial populations, bacterial and archaeal communities were characterized using pyrosequencing-based 16S rRNA gene analysis in surface (top 30 cm) and subsurface/deeper sediments (30–530 cm) of the Helgoland mud area, North Sea. Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) was used to characterize a potentially bioavailable organic matter fraction (hot-water extractable organic matter, WE-OM). Algal polymer-associated microbial populations such as members of the Gammaproteobacteria, Bacteroidetes, and Verrucomicrobia were dominant in surface sediments while members of the Chloroflexi (Dehalococcoidales and candidate order GIF9) and Miscellaneous Crenarchaeota Groups (MCG), both of which are linked to degradation of more recalcitrant, aromatic compounds and detrital proteins, were dominant in subsurface sediments. Microbial populations dominant in subsurface sediments (Chloroflexi, members of MCG, and Thermoplasmata) showed strong correlations to total organic carbon (TOC) content. Changes of WE-OM with sediment depth reveal molecular transformations from oxygen-rich [high oxygen to carbon (O/C), low hydrogen to carbon (H/C) ratios] aromatic compounds and highly unsaturated compounds toward compounds with lower O/C and higher H/C ratios. The observed molecular changes were most pronounced in organic compounds containing only CHO atoms. Our data thus, highlights classes of sedimentary organic compounds that may serve as microbial energy sources in methanic marine subsurface environments. PMID:26635758

Locating women in the New Zealand computing industry

Directory of Open Access Journals (Sweden)

Alison Hunter, PhD

Full Text Available It is well recognised that women are under-represented in computing occupations in many Western countries, but is the situation similar in New Zealand? This article presents a quantitative analysis of gendered employment patterns in New Zealand\\'s computing industry. Findings from analysis of 2001 and 2006 census employment data demonstrate that women are now well represented in some newer computing occupations in New Zealand, but they remain significantly under-represented in traditional computing roles such as programming and systems analysis. Furthermore, New Zealand women in computing do not have pay parity with men. On some occasions during the early days of computing in New Zealand women participated more equally in number but they have always experienced pay discrimination.

Spatio-temporal variations in the composition of organic matter in surface sediments of a mangrove receiving shrimp farm effluents (New Caledonia)

International Nuclear Information System (INIS)

Aschenbroich, Adélaïde; Marchand, Cyril; Molnar, Nathalie; Deborde, Jonathan; Hubas, Cédric; Rybarczyk, Hervé; Meziane, Tarik

2015-01-01

In order to investigate spatio-temporal variations in the composition and origin of the benthic organic matter (OM) at the sediment surface in mangrove receiving shrimp farm effluents, fatty acid (FA) biomarkers, natural stable isotopes (δ 13 C and δ 15 N), C:N ratios and chlorophyll-a (chl-a) concentrations were determined during the active and the non-active period of the farm. Fatty acid compositions in surface sediments within the mangrove forest indicated that organic matter inputs varied along the year as a result of farm activity. Effluents were the source of fresh particulate organic matter for the mangrove, as evidenced by the unsaturated fatty acid (UFA) distribution. The anthropogenic MUFA 18:1ω9 was not only accumulated at the sediment surface in some parts of the mangrove, but was also exported to the seafront. Direct release of bacteria and enhanced in situ production of fungi, as revealed by specific FAs, stimulated mangrove litter decomposition under effluent runoff condition. Also, microalgae released from ponds contributed to maintain high benthic chl-a concentrations in mangrove sediments in winter and to a shift in microphytobenthic community assemblage. Primary production was high whether the farm released effluent or not which questioned the temporary effect of shrimp farm effluent on benthic microalgae dynamic. This study outlined that mangrove benthic organic matter was qualitatively and quantitatively affected by shrimp farm effluent release and that responses to environmental condition changes likely depended on mangrove stand characteristics. - Highlights: • Fatty acid 18:1ω9 is a relevant marker to monitor effluent pathway in the mangrove. • OM nature and distribution at sediment surface varied in relation to farm activity. • Enhancement of litter-decomposer biomass and activity stimulates litter degradation. • Diatoms dominate the microalgae community under effluent runoff conditions. • Chl-a concentrations suggest

Spatio-temporal variations in the composition of organic matter in surface sediments of a mangrove receiving shrimp farm effluents (New Caledonia)

Energy Technology Data Exchange (ETDEWEB)

Aschenbroich, Adélaïde, E-mail: adelaide.aschenbroich@univ-brest.fr [UMR BOREA 7208 CNRS/MNHN/UPMC/IRD/UCBN, Muséum National d' Histoire Naturelle, CP 53, 61 rue Buffon, 75231 Paris cedex 5 (France); Marchand, Cyril [Institut de Recherche pour le Développement (IRD), UMR 7590, UR 206, BP A5, 98848 Nouméa, New Caledonia (France); Molnar, Nathalie [UMR BOREA 7208 CNRS/MNHN/UPMC/IRD/UCBN, Muséum National d' Histoire Naturelle, CP 53, 61 rue Buffon, 75231 Paris cedex 5 (France); Institut de Recherche pour le Développement (IRD), UMR 7590, UR 206, BP A5, 98848 Nouméa, New Caledonia (France); Deborde, Jonathan [Institut de Recherche pour le Développement (IRD), UMR 7590, UR 206, BP A5, 98848 Nouméa, New Caledonia (France); Hubas, Cédric; Rybarczyk, Hervé; Meziane, Tarik [UMR BOREA 7208 CNRS/MNHN/UPMC/IRD/UCBN, Muséum National d' Histoire Naturelle, CP 53, 61 rue Buffon, 75231 Paris cedex 5 (France)

2015-04-15

In order to investigate spatio-temporal variations in the composition and origin of the benthic organic matter (OM) at the sediment surface in mangrove receiving shrimp farm effluents, fatty acid (FA) biomarkers, natural stable isotopes (δ{sup 13}C and δ{sup 15}N), C:N ratios and chlorophyll-a (chl-a) concentrations were determined during the active and the non-active period of the farm. Fatty acid compositions in surface sediments within the mangrove forest indicated that organic matter inputs varied along the year as a result of farm activity. Effluents were the source of fresh particulate organic matter for the mangrove, as evidenced by the unsaturated fatty acid (UFA) distribution. The anthropogenic MUFA 18:1ω9 was not only accumulated at the sediment surface in some parts of the mangrove, but was also exported to the seafront. Direct release of bacteria and enhanced in situ production of fungi, as revealed by specific FAs, stimulated mangrove litter decomposition under effluent runoff condition. Also, microalgae released from ponds contributed to maintain high benthic chl-a concentrations in mangrove sediments in winter and to a shift in microphytobenthic community assemblage. Primary production was high whether the farm released effluent or not which questioned the temporary effect of shrimp farm effluent on benthic microalgae dynamic. This study outlined that mangrove benthic organic matter was qualitatively and quantitatively affected by shrimp farm effluent release and that responses to environmental condition changes likely depended on mangrove stand characteristics. - Highlights: • Fatty acid 18:1ω9 is a relevant marker to monitor effluent pathway in the mangrove. • OM nature and distribution at sediment surface varied in relation to farm activity. • Enhancement of litter-decomposer biomass and activity stimulates litter degradation. • Diatoms dominate the microalgae community under effluent runoff conditions. • Chl-a concentrations suggest

Enrichment of Arsenic in Surface Water, Stream Sediments and Soils in Tibet.

Science.gov (United States)

Li, Shehong; Wang, Mingguo; Yang, Qiang; Wang, Hui; Zhu, Jianming; Zheng, Baoshan; Zheng, Yan

2013-12-01

Groundwater in sedimentary deposits in China, Southern, and Southeast Asia down gradient from the Tibetan plateau contain elevated As concentrations on a regional scale. To ascertain the possibility of source region As enrichment, samples of water (n=86), stream sediment (n=77) and soil (n=73) were collected from the Singe Tsangpo (upstream of the Indus River), Yarlung Tsangpo (upstream of the Brahmaputra River) and other drainage basins in Tibet in June of 2008. The average arsenic concentration in stream waters, sediments and soils was 58±70 μg/L (n=39, range 2-252 μg/L), 42±40 mg/kg (n=37, range 12-227 mg/kg), and 44±27mg/kg (n=28, range 12-84 mg/kg) respectively for the Singe Tsangpo and was 11±17 μg/L (n=30, range 2-83 μg/L), 28±11 mg/kg (n=28, range 2-61 mg/kg), and 30±34 mg/kg (n=21, range 6-173 mg/kg) respectively for the Yarlung Tsangpo. A dug well contained 195 μg/L of As. In addition to elevated As levels in surface and shallow groundwater of Tibet, hot spring and alkaline salt lake waters displayed very high As levels, reaching a maximum value of 5,985 μg/L and 10,626 μg/L As, respectively. The positive correlation between [As] and [Na]+[K] in stream waters indicates that these surface water arsenic enrichments are linked to the hot springs and/or salt lakes. Further, 24% of As in stream sediment is reductively leachable, with bulk As displaying a positive correlation with stream water As, suggesting sorption from stream water. In contrast, the fraction of reductively leachable As is negligible for soils and several rock samples, suggesting that As in them are associated with unweathered minerals. Whether the pronounced As anomaly found in Tibet affects the sedimentary As content in deltas downstream or not requires further study.

Primary care and health reform in New Zealand.

Science.gov (United States)

Grant, C C; Forrest, C B; Starfield, B

1997-02-14

(1) To describe New Zealand's primary care system (2) to compare New Zealand to other Anglo-American members of the OECD with respect to the adequacy of primary care, and (3) to assess the cost-efficiency and effectiveness of New Zealand's system by comparing health spending and health indicators relevant to primary care. A cross-national comparison of primary care, health spending and health indicators in New Zealand, Australia, Canada, the United Kingdom and the United States of America. Main outcome measures were health spending measured in purchasing power parties. Health indicators: mean life expectancy in years, years of potential life lost and infant mortality rates. New Zealand's primary care system ranked below the UK, above the USA and similar to Canada and Australia. Favourable characteristics of New Zealand's primary care system were the use of generalists as the predominant type of practitioner and the low proportion of active physicians who were specialists. Compared to the other countries, New Zealand scored poorly for financial that are necessary for the practise of good primary care. New Zealand and the UK had the lowest spending per capita on health care. New Zealand and the USA scored lowest for all three of the health care indicators. The quality of primary care in New Zealand is limited by barriers to access to care and the intermediate level of practise characteristics essential to primary care. Compared to other AngloAmerican OECD nations, New Zealand has relatively low levels of national health expenditure. In order to improve the quality of primary care, future reform should aim to facilitate access to care, increase the gatekeeping role of primary care physicians, and promote the practise characteristics essential to primary care.

Uptake of radioactivity by marine surface sediments collected in Ghazaouet, west coast of Algeria

International Nuclear Information System (INIS)

Noureddine, A.; Baggoura, B.; Hocini, N.; Boulahdid, M.

1998-01-01

Samples of surface marine sediments of different grain sizes collected in Ghazaouet, a small bay on the western coast of Algeria, have been examined to measure concentrations of natural and artificial gamma-emitting radionuclides. The aim of this study is to determine the level of radioactivity and its repartition in the sedimentary area. The samples analyzed by direct counting gamma spectrometry, showed relatively high activities for natural radioactivity and revealed measurable quantities of 137 Cs, ranging from 0.66-8.47 Bq kg -1 dry weight. In addition, some of the samples of different nature were sieved in different grain-sizes, to study the uptake of radioactivity. It is found that the sediments of less than 100 μm grain-size have the highest level of uptake of radioactivity

Uptake of radioactivity by marine surface sediments collected in Ghazaouet, west coast of Algeria

Energy Technology Data Exchange (ETDEWEB)

Noureddine, A.; Baggoura, B. [Laboratoire d' Environnement, Centre de Radioprotection et de Surete (C.R.S.), Algiers (Algeria); Hocini, N. [Laboratoire de Sedimentologie, Centre de Developpement des Techniques Nucleaires (C.D.T.N.), Algiers (Algeria); Boulahdid, M. [Departement de la Pollution Chimique, Institut des Sciences de la Mer et de l' Amenagement du Littoral, Tipaza (Algeria)

1998-12-01

Samples of surface marine sediments of different grain sizes collected in Ghazaouet, a small bay on the western coast of Algeria, have been examined to measure concentrations of natural and artificial gamma-emitting radionuclides. The aim of this study is to determine the level of radioactivity and its repartition in the sedimentary area. The samples analyzed by direct counting gamma spectrometry, showed relatively high activities for natural radioactivity and revealed measurable quantities of {sup 137}Cs, ranging from 0.66-8.47 Bq kg{sup -1} dry weight. In addition, some of the samples of different nature were sieved in different grain-sizes, to study the uptake of radioactivity. It is found that the sediments of less than 100 {mu}m grain-size have the highest level of uptake of radioactivity.

Role of urban surface roughness in road-deposited sediment build-up and wash-off

Science.gov (United States)

Zhao, Hongtao; Jiang, Qian; Xie, Wenxia; Li, Xuyong; Yin, Chengqing

2018-05-01

Urban road surface roughness is one of the most important factors in estimation of surface runoff loads caused by road-deposited sediment (RDS) wash-off and design of its control measures. However, because of a lack of experimental data to distinguish the role of surface roughness, the effects of surface roughness on RDS accumulation and release are not clear. In this study, paired asphalt and concrete road surfaces and rainfall simulation designs were used to distinguish the role of surface roughness in RDS build-up and wash-off. Our results showed that typical asphalt surfaces often have higher depression depths than typical concrete surfaces, indicating that asphalt surfaces are relatively rougher than concrete surface. Asphalt surfaces can retain a larger RDS amount, relative higher percentage of coarser particles, larger RDS wash-off loads, and lower wash-off percentage, than concrete surfaces. Surface roughness has different effects in RDS motilities with different particle sizes during rainfall runoff, and the settleable particles (44-149 μm) were notably influenced by it. Furthermore, the first flush phenomenon tended to be greater on relatively smooth surfaces than relatively rough surfaces. Overall, surface roughness plays an important role in influencing the complete process of RDS build-up and wash-off on different road characteristics.

Influence of exogenous lead pollution on enzyme activities and organic matter degradation in the surface of river sediment.

Science.gov (United States)

Huang, Danlian; Xu, Juanjuan; Zeng, Guangming; Lai, Cui; Yuan, Xingzhong; Luo, Xiangying; Wang, Cong; Xu, Piao; Huang, Chao

2015-08-01

As lead is one of the most hazardous heavy metals in river ecosystem, the influence of exogenous lead pollution on enzyme activities and organic matter degradation in the surface of river sediment with high moisture content were studied at laboratory scale. The dynamic changes of urease, catalase, protease activities, organic matter content, and exchangeable or ethylenediaminetetraacetic acid (EDTA)-extractable Pb concentration in sediment were monitored during different levels of exogenous lead infiltrating into sediment. At the early stage of incubation, the activities of catalase and protease were inhibited, whereas the urease activities were enhanced with different levels of exogenous lead. Organic matter content in polluted sediment with exogenous lead was lower than control and correlated with enzyme activities. In addition, the effects of lead on the three enzyme activities were strongly time-dependent and catalase activities showed lower significant difference (P < 0.05) than urease and protease. Correlations between catalase activities and EDTA-extractable Pb in the experiment were significantly negative. The present findings will improve the understandings about the ecotoxicological mechanisms in sediment.

The New Zealand Food Composition Database: A useful tool for assessing New Zealanders' nutrient intake.

Science.gov (United States)

Sivakumaran, Subathira; Huffman, Lee; Sivakumaran, Sivalingam

2018-01-01

A country-specific food composition databases is useful for assessing nutrient intake reliably in national nutrition surveys, research studies and clinical practice. The New Zealand Food Composition Database (NZFCDB) programme seeks to maintain relevant and up-to-date food records that reflect the composition of foods commonly consumed in New Zealand following Food Agricultural Organisation of the United Nations/International Network of Food Data Systems (FAO/INFOODS) guidelines. Food composition data (FCD) of up to 87 core components for approximately 600 foods have been added to NZFCDB since 2010. These foods include those identified as providing key nutrients in a 2008/09 New Zealand Adult Nutrition Survey. Nutrient data obtained by analysis of composite samples or are calculated from analytical data. Currently >2500 foods in 22 food groups are freely available in various NZFCDB output products on the website: www.foodcomposition.co.nz. NZFCDB is the main source of FCD for estimating nutrient intake in New Zealand nutrition surveys. Copyright © 2016 Elsevier Ltd. All rights reserved.

Midwifery in New Zealand 1904-1971.

Science.gov (United States)

Stojanovic, Jane

2008-10-01

Childbirth for European women in early twentieth century New Zealand was family centred. The majority of births took place in the home, accepted as a difficult but natural part of a woman's role in life. Midwives were mostly married women who worked autonomously and had usually borne children themselves. By the 1970s this picture had dramatically changed. Virtually all births took place in hospital and were under the control of medical men and women. When legislation was passed (the Nurses Act 1971) that removed the right of New Zealand midwives to practice autonomously, New Zealand midwifery had largely been subsumed by nursing, controlled by medicine and displaced from a community based profession into a hospital based workforce. This article examines how the trends of medicalisation, hospitalisation, and nursification changed the New Zealand maternity services from 1900 to 1971, outlining the effect those changes had on the midwifery profession. The changes described here were also common to other western societies; examining how they occurred provides a context for understanding the history of midwifery in New Zealand.

Sources and distribution of yttrium and rare earth elements in surface sediments from Tagus estuary, Portugal.

Science.gov (United States)

Brito, Pedro; Prego, Ricardo; Mil-Homens, Mário; Caçador, Isabel; Caetano, Miguel

2018-04-15

The distribution and sources of yttrium and rare-earth elements (YREE) in surface sediments were studied on 78 samples collected in the Tagus estuary (SW Portugal, SW Europe). Yttrium and total REE contents ranged from 2.4 to 32mg·kg -1 and 18 to 210mg·kg -1 , respectively, and exhibited significant correlations with sediment grain-size, Al, Fe, Mg and Mn, suggesting a preferential association to fine-grained material (e.g. aluminosilicates but also Al hydroxides and Fe oxyhydroxides). The PAAS (Post-Archean Australian Shale) normalized patterns display three distinct YREE fractionation pattern groups along the Tagus estuary: a first group, characterized by medium to coarse-grained material, a depleted and almost flat PAAS-normalized pattern, with a positive anomaly of Eu, representing one of the lithogenic components; a second group, characterized mainly by fine-grained sediment, with higher shale-normalized ratios and an enrichment of LREE relative to HREE, associated with waste water treatment plant (WWTP) outfalls, located in the northern margin; and, a third group, of fine-grained material, marked by a significant enrichment of Y, a depletion of Ce and an enrichment of HREE over LREE, located near an inactive chemical-industrial complex (e.g. pyrite roast plant, chemical and phosphorous fertilizer industries), in the southern margin. The data allow the quantification of the YREE contents and its spatial distribution in the surface sediments of the Tagus estuary, identifying the main potential sources and confirming the use of rare earth elements as tracers of anthropogenic activities in highly hydrodynamic estuaries. Copyright © 2017 Elsevier B.V. All rights reserved.

Geotechnical properties of surface sediments in the INDEX area

Digital Repository Service at National Institute of Oceanography (India)

Khadge, N.H.

As a part of the environmental impact assessment studies, geotechnical properties of sediments were determined in the Central Indian Basin. The undrained shear strength and index properties of the siliceous sediments were determined on 20 box cores...

Preliminary assessment of Miramar Petrochemical Harbor as PAH source to Guajará bay (Belém-PA-Brazil surface sediments

Directory of Open Access Journals (Sweden)

Silvana do Socorro Veloso Sodré

Full Text Available Abstract A preliminary study on a petrochemical harbor as a potential source of polycyclic aromatic hydrocarbons (PAH to surface sediments of Guajará bay, located in Belém City, Pará State, Brazil, over the last 10 years is presented here. The 16 priority USEPA PAH were identified and quantified. Surface sediment samples, collected at 5 sites in the bay, near Miramar Petrochemical Harbor (TEMIR, were extracted and analyzed by high performance liquid chromatography with a diode array detector. Total PAH concentration ranged from 533.0 to 3123.3 ng g-1 dry weight with a mean concentration of 1091.9 ng g-1. The most contaminated places were those where muddy sediments were found with highest concentrations of organic matter. The priority PAH with low molecular weight represented 54.4% of the total abundance and indicate that the main source of contamination of the sediments was petrogenic, indicative of the relevant contribution of the petrochemical harbor activity to the input of PAH to Guajará bay. However, pyrolytic PAH coming from fuel combustion, household waste combustion and untreated sewage discharge are also potential contamination sources to this environment.

Quantification of Surface Suspended Sediments along a River Dominated Coast with NOAA AVHRR and SeaWiFS Measurements: Louisiana, USA

Science.gov (United States)

Myint, S. W.; Walker, N. D.

2002-01-01

The ability to quantify suspended sediment concentrations accurately over both time and space using satellite data has been a goal of many environmental researchers over the past few decades This study utilizes data acquired by the NOAA Advanced Very High Resolution Radiometer (AVHRR) and the Orbview-2 Sea-viewing wide field-of-view (SeaWiFS) ocean colour sensor, coupled with field measurements to develop statistical models for the estimation of near-surface suspended sediment and suspended solids "Ground truth" water samples were obtained via helicopter, small boat and automatic water sampler within a few hours of satellite overpasses The NOAA AVHRR atmospheric correction was modified for the high levels of turbidity along the Louisiana coast. Models were developed based on the field measurements and reflectance/radiance measurements in the visible and near infrared Channels of NOAA-14 and Orbview-2 SeaWiFS. The best models for predicting surface suspended sediment concentrations were obtained with a NOAA AVHRR Channel 1 (580-680nm) cubic model, Channel 2 (725-1100 nm) linear mod$ and SeaWiFs Channel 6 (660-68Onm) power modeL The suspended sediment models developed using SeaWiFS Channel 5 (545-565 nm) were inferior, a result that we attribute mainly to the atmospheric correction technique, the shallow depth of the water samples and absorption effects from non-sediment water constituents.

Performing Manaaki and New Zealand Refugee Theatre

Science.gov (United States)

Hazou, Rand T.

2018-01-01

In September 2015, and in response to the Syrian refugee crisis, there were widespread calls in New Zealand urging the Government to raise its annual Refugee Quota. Maori Party co-leader Marama Fox argued that New Zealand could afford to take on more refugees as part of its global citizenship and suggested that New Zealand's policy might be shaped…

Temporal–spatial variation and partitioning prediction of antibiotics in surface water and sediments from the intertidal zones of the Yellow River Delta, China

Energy Technology Data Exchange (ETDEWEB)

Zhao, Shengnan [State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing 100875 (China); Liu, Xinhui, E-mail: xhliu@bnu.edu.cn [State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing 100875 (China); Cheng, Dengmiao [Institute of Agricultural Resources and Regional Planning, Chinese Academy of Agricultural Sciences, Key Laboratory of Plant Nutrition and Fertilizer, Ministry of Agriculture, Beijing 100081 (China); Liu, Guannan [MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, CAGS, Beijing 100037 (China); Liang, Baocui; Cui, Baoshan; Bai, Junhong [State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing 100875 (China)

2016-11-01

As special zones, the intertidal zones of the Yellow River Delta (YRD) are highly variable along with time and space. Fluvial–marine and land–ocean interactions which frequently occur in these areas have a great impact on the fate of pollutants. Antibiotics, which contribute to antibiotic-resistant genes (ARGs), are widely detected in wastewater, natural water, soil, sediments, and even drinking water. Therefore, it is meaningful to investigate the occurrence and fate of antibiotics in these special zones. In this study, eight antibiotics belonging to tetracyclines (TCs), fluoroquinolones (FQs), and macrolides (MLs) were detected in the surface water and sediments from the intertidal zones of YRD during two seasons. Two models were established to predict the partitioning coefficients of norfloxacin (NOR) and erythromycin (ETM) using physicochemical properties of sediments, respectively. The total concentrations of these antibiotics were 82.94–230.96 ng·L{sup −} {sup 1} and 40.97–207.44 ng·g{sup −} {sup 1}, respectively, in the surface water and sediments. Seasonal variation was mainly influenced by the frequency of antibiotics use and environment factors. The regions with river supply exhibited the highest concentrations of antibiotics in surface water and sediments. Meanwhile, particle-size fractions, cation exchange capability (CEC), and metal ions content played dominant roles in the partitioning behaviors of NOR and ETM between the surface water and sediments. Both models established in this study featured accuracy and feasibility, which provided the methods for predicting the partitioning coefficients of emerging contaminants similar in structures to NOR and ETM in the intertidal zones. - Highlights: • The intertidal zones of YRD were polluted by antibiotics to some extent. • The river supply was a major pathway for the antibiotic pollution of the intertidal zones of YRD. • The partitioning coefficients of NOR and ETM can be predicted using

Soft-sediment deformation in New Zealand: Structures resulting from the 2010/11 Christchurch earthquakes and comparison with Pleistocene sediments of the Taupo Volcanic Zone (TVZ)

Science.gov (United States)

Scholz, C.; Downs, D. T.; Gravley, D.; Quigley, M.; Rowland, J. V.

2011-12-01

The distinction between seismites and other event-related soft-sediment deformation is a challenging problem. Recognition and interpretation is aided by comparison of recent examples produced during known seismic events and those generated experimentally. Seismites are important features, once recognized in a rock, for interpretations of paleotectonic environment, tectonic relationships of sediments in basins, sedimentary facies analysis, evaluation of earthquake frequency and hazard and consequent land managment. Two examples of soft-sediment deformation, potentially generated through ground shaking and associated liquefaction, are described from within the TVZ: 1) Near Matata on the western margin of the Whakatane Graben. This location has a complicated en-echelon fault history and large earthquakes occur from time to time (e.g., 1987 ML6.3 Edgecumbe event). The structures occur in ~550 ka volcanic sediments, and represent soft-sediment deformation within stratigraphically-bounded layers. Based on paleoenvironment, appearance, and diagnostic criteria described by other authors (Sims 1975; Hempton and Dewey 1983), we interpret these features to have formed by ground shaking related to an earthquake and/or possibly accompanying large volcanic eruptions, rather than by slope failure. 2) Near Taupo, 3 km from the active Kaiapo fault. Lakeward dipping, nearly horizontal lacustrine sediments overlay Taupo Ignimbrite (1.8 ka). At one outcrop the lake beds have subsided into the underlying substrate resulting in kidney-shaped features. These structures formed as a result of liquefaction of the underlying substrate, which may have been caused by ground shaking related to either seismic or volcanic activity. However, inferred time relationships are more consistent with seismic-induced ground shaking. We compare and contrast the form and geometry of the above structures with seismites generated during the recent Christchurch earthquakes (Sep. 2010 and Feb. 2011). Hempton, M

210Pb-137Cs dating of glacial lake sediments

International Nuclear Information System (INIS)

Graham, I.J.; Ditchburn, R.G.; Barry, B.J.

2004-01-01

Sediments deposited in New Zealand lakes in the recent past provide excellent archives of local climate change via their trapped biodiversity, varve structure ad sedimentological composition. To unlock the archival information, accurate and fine-scale dating of the deposits is essential. A combination of 210 Pb and 137 Cs dating provides the most reliable and robust approach. Under favourable conditions, 210 Pb dating can provide a detailed chronology to c.120-140 y, and can be accurately calibrated by 137 Cs for the last 40 y or thereabouts. (author). 6 refs., 4 figs

Factors influencing mercury in freshwater surface sediments of northeastern North America

Science.gov (United States)

Kamman, N.C.; Chalmers, A.; Clair, T.A.; Major, A.; Moore, R.B.; Norton, S.A.; Shanley, J.B.

2005-01-01

We report on an inventory and analysis of sediment mercury (Hg) concentrations from 579 sites across northeastern North America. Sediment Hg concentrations ranged from the limit of detection ca. 0.01-3.7 ??g g -1 (dry weight, d.w.), and the average concentration was 0.19 ??g g-1 (d.w.) Sediment methylmercury concentrations ranged from 0.15 to 21 ng g-1 (d.w.) and the mean concentration was 3.83 ng g -1 (d.w.). Total Hg concentrations (HgT) were greatest in lakes > reservoirs > rivers, although the proportion of Hg as methylmercury showed an inverse pattern. Total Hg was weakly and positively correlated with the sediment organic matter and percent of watershed as forested land, and weakly and negatively correlated with sediment solids content, drainage area, and agricultural land. Sediment methylmercury concentrations were weakly and positively correlated to wetland area, and weakly and negatively correlated to drainage area. Methylmercury, expressed as a percentage of HgT was positively correlated to agricultural land area. For sites with co-located sediment and fish-tissue sampling results, there was no relationship between sediment Hg and fish-tissue Hg. Finally, our data indicate that at least 44% of waters across the region have sediment HgT concentrations in excess of Canadian and United States minimum sediment contaminant guidelines for the protection of aquatic biota. ?? 2005 Springer Science+Business Media, Inc.

Organic carbon burial in fjords: Terrestrial versus marine inputs

Science.gov (United States)

Cui, Xingqian; Bianchi, Thomas S.; Savage, Candida; Smith, Richard W.

2016-10-01

Fjords have been identified as sites of enhanced organic carbon (OC) burial and may play an important role in regulating climate change on glacial-interglacial timescales. Understanding sediment processes and sources of sedimentary OC are necessary to better constrain OC burial in fjords. In this study, we use Fiordland, New Zealand, as a case study and present data on surface sediments, sediment down-cores and terrestrial end-members to examine dynamics of sediments and the sources of OC in fjord sediments. Sediment cores showed evidence of multiple particle sources, frequent bioturbation and mass-wasting events. A multi-proxy approach (stable isotopes, lignin-phenols and fatty acids) allowed for separation of marine, soil and vascular plant OC in surface sediments. The relationship between mass accumulation rate (MAR) and OC contents in fjord surface sediments suggested that mineral dilution is important in controlling OC content on a global scale, but is less important for specific regions (e.g., New Zealand). The inconsistency of OC budgets calculated by using MAR weighted %OC and OC accumulation rates (AR; 6 vs 21-31 Tg OC yr-1) suggested that sediment flux in fjords was likely underestimated. By using end-member models, we propose that 55% to 62% of total OC buried in fjords is terrestrially derived, and accounts for 17 ± 12% of the OCterr buried in all marine sediments. The strong correlation between MAR and OC AR indicated that OC flux will likely decrease in fjords in the future with global warming due to decrease in sediment flux caused by glacier denudation.

New Zealand; Selected Issues

OpenAIRE

International Monetary Fund

2009-01-01

This Selected Issues paper conducts a comparative analysis of the main determinants of GDP per capita growth in New Zealand and in other OECD countries to assess the relative importance of macroeconomic factors, institutional settings, and geographical location in New Zealand’s growth performance during the last 30 years. The estimation results find strong support for the view that geographical isolation has significantly hampered growth in New Zealand. The paper also reviews the internationa...

Dynamics of organic and inorganic carbon in surface sediments of the Yellow River Estuary

Science.gov (United States)

Yu, Z.; Wang, X.; Liu, X.; Zhang, E.; Hang, F.

2017-12-01

Estuarine sediment is an important carbon reservoir thus may play an important role in the global carbon cycle. However, little is known on the dynamics of organic carbon (OC) and inorganic carbon (IC) in the surface sediment of the Yellow River Estuary, a large estuary in northern China. In this study, we applied element analyses and isotopic approach to study spatial distribution and sources of OC and IC in the Yellow River Estuary. We found that TIC concentration (6.3-20.1 g kg-1) was much higher than TOC (0.2-4.4 g kg-1) in the surface sediment. There showed a large spatial variability in TOC and TIC and their stable isotopes. Both TOC and TIC were higher to the north (2.6 and 14.5 g kg-1) than to the south (1.6 and 12.2 g kg-1), except in the southern bay where TOC and TIC reached 2.7 and 15.4 g kg-1, respectively. Generally, TOC and TIC in our study area was mainly autochthonous. The lower TOC values in the south section were due to relatively higher kinetic energy level whereas the higher values in the bay was attributable to terrigenous matters accumulation and lower kinetic energy level. However, the southern bay revealed the most negative δ13Corg and δ13Ccarb, suggesting that there might exist some transfer of OC to IC in the section. Our study points out that the dynamics of sedimentary carbon in the Yellow River Estuary is influenced by multiple and complex processes, and highlights the importance of carbonate in carbon sequstration.

Sediment transport under breaking waves

DEFF Research Database (Denmark)

Christensen, Erik Damgaard; Hjelmager Jensen, Jacob; Mayer, Stefan

2000-01-01

The sediment transport in the surf zone is modelled by combining a Navier-Stokes solver, a free surface model, a turbulence model, and a sediment transport model. The flow solver is based on the finite volume technique for non-orthogonal grids. The model is capable of simulating the turbulence...... generated at the surface where the wave breaks as well as the turbulence generated near the bed due to the wave-motion and the undertow. In general, the levels of turbulent kinetic energy are found to be higher than experiments show. This results in an over prediction of the sediment transport. Nevertheless...

Lipid composition of water and surface sediments in Takapoto atoll lagoon (French Polynesia)

Science.gov (United States)

Saliot, A.; Bouloubassi, I.; Lorre-Boireau, A.; Trichet, J.; Poupet, P.; Charpy, L.

1994-11-01

Dissolved, particulate and sedimentary lipid compounds were analyzed in samples collected in May 1988 at three sites in the lagoon of the closed atoll of Takapoto (Tuamotu archipelago, French Polynesia). The study provides background information dealing with water quality and the nature and concentration of lipids. Non-aromatic hydrocarbons and fatty acids were isolated from lipids and analyzed by gas chromatography/mass spectrometry. Non-aromatic hydrocarbon concentrations did not exceed 1000 ng l-1 in water, and 2300 ng g-1 in surface sediments and are among the lowest encountered in pristine marine environments. No noticeable petroleum pollution was evidenced in the lagoon. Nevertheless, traces of petroleum-derived compounds were detected at the central site for both surface and deep water. Total fatty acid concentrations varied in the range 6.3 14.4 μg l-1 for the particulate phase and in the range 0.5 3.2 μg l-1 for the dissolved phase. The molecular fingerprints of fatty acids and hydrocarbons evidenced a predominant algal, and to a lesser extent microbial, origin of the organic matter present in water and sediments. Mono- and polyunsaturated fatty acids, which are essential components for animal metabolism, were identified in noticeable amounts in suspended matter (1.8 4.6 μg l-1), and at highly variable levels in the dissolved phase (0.08 1.21 μg l-1).

Integrating chronological uncertainties for annually laminated lake sediments using layer counting, independent chronologies and Bayesian age modelling (Lake Ohau, South Island, New Zealand)

Science.gov (United States)

Vandergoes, Marcus J.; Howarth, Jamie D.; Dunbar, Gavin B.; Turnbull, Jocelyn C.; Roop, Heidi A.; Levy, Richard H.; Li, Xun; Prior, Christine; Norris, Margaret; Keller, Liz D.; Baisden, W. Troy; Ditchburn, Robert; Fitzsimons, Sean J.; Bronk Ramsey, Christopher

2018-05-01

Annually resolved (varved) lake sequences are important palaeoenvironmental archives as they offer a direct incremental dating technique for high-frequency reconstruction of environmental and climate change. Despite the importance of these records, establishing a robust chronology and quantifying its precision and accuracy (estimations of error) remains an essential but challenging component of their development. We outline an approach for building reliable independent chronologies, testing the accuracy of layer counts and integrating all chronological uncertainties to provide quantitative age and error estimates for varved lake sequences. The approach incorporates (1) layer counts and estimates of counting precision; (2) radiometric and biostratigrapic dating techniques to derive independent chronology; and (3) the application of Bayesian age modelling to produce an integrated age model. This approach is applied to a case study of an annually resolved sediment record from Lake Ohau, New Zealand. The most robust age model provides an average error of 72 years across the whole depth range. This represents a fractional uncertainty of ∼5%, higher than the <3% quoted for most published varve records. However, the age model and reported uncertainty represent the best fit between layer counts and independent chronology and the uncertainties account for both layer counting precision and the chronological accuracy of the layer counts. This integrated approach provides a more representative estimate of age uncertainty and therefore represents a statistically more robust chronology.

EDXRF and INAA analyses of surface sediments of the Gulf of Saros

International Nuclear Information System (INIS)

Akyuz, T.; Mukhamedshina, N.; Mirsagatova, A.A.; Akyuz, S.; Sari, E.

2004-01-01

Full text: A variety of elements and organic matter have been introduced to the environment as a result of human activities. Such substances find their way to the aquatic sediments from direct discharges to waterways, atmospheric emissions, and run of. In aquatic systems, sediments become the eventual sink for most of these chemicals. One of the most useful approaches to long-term monitoring of aquatic systems is the analysis of marine sediments. The Gulf of Saros in the northeastern Aegean Sea (Turkey) is a relatively unpolluted marine environment. It is located between latitudes 40 o 19 ' N - 40 o 37 ' N and longitudes 26 o 19 ' E - 26 o 50 ' E and has approximately 60 km length and 6-33 km wide. The main sources of fresh water and sediment to the Gulf are the Meric River in the northwest and the Kavak Creek in the east. In this study, 54 surface sediment samples, collected at different water depths in the Saros Gulf, by cruise of Sismik-1 of Mineral Research and Exploration Institute of Turkey, using Van Veen graph sampler were analysed quantitatively by radioisotope energy dispersive X-ray fluorescence (EDXRF) and instrumental neutron activation analysis (INAA) techniques. In the case of EDXRF analysis, samples were excited using an 241 Am source (10 mCi) and a HPGe detector or a 109 Cd source (25 mCi) and a Si(Li) detector for 50,000 s with resolutions of approximately 350 eV and 185 eV FWHM, respectively, at 5.89 keV. The quantitative analyses were performed by the fundamental parameter technique, in order to minimise the matrix effects in X-ray fluorescence analysis. In the case of INAA method, the samples of 0.1 - 0.15 g mass were irradiated simultaneously with reference materials at a fission spectra neutron flux of the density of ∼5.10 13 cm -2 .s -1 (WWR-SM) nuclear reactor of Institute of Nuclear Physics, Tashkent, Uzbekistan. The concentrations of 40 elements were determined. The main interest of the present study is to assess the environmental state

Variation in PAH inputs and microbial community in surface sediments of Hamilton Harbour: Implications to remediation and monitoring

International Nuclear Information System (INIS)

Slater, G.F.; Cowie, B.R.; Harper, N.; Droppo, I.G.

2008-01-01

Variations in concentrations of polycyclic aromatic hydrocarbons (PAHs) and microbial community indicators were investigated in representative highly contaminated and less contaminated surface sediment sites of Hamilton Harbour. Inputs of PAH to the upper 3 cm of sediments up to four times the average upper sediment concentrations were observed. Associated PAH fingerprint profiles indicated that the source was consistent with the PAH source to the industrial region of the harbour. Increased PAH loadings were associated with decreased bacterial populations as indicated by phospholipid fatty acid (PLFA) concentrations. However, relatively minor impacts on overall community composition were indicated. Porewater methane concentrations and isotopic data indicated a difference in the occurrence of methane oxidation between the two sites. This study confirms temporally limited transport of contaminants from highly impacted regions as a vector for contaminants within the harbour and the impact on microbial carbon cycling and bed stability. - Variations in PAH inputs to harbour sediments have implications to implementation and monitoring of mitigation/remediation efforts

It's Our Fault: better defining earthquake risk in Wellington, New Zealand

Science.gov (United States)

Van Dissen, R.; Brackley, H. L.; Francois-Holden, C.

2012-12-01

The Wellington region, home of New Zealand's capital city, is cut by a number of major right-lateral strike slip faults, and is underlain by the currently locked west-dipping subduction interface between the down going Pacific Plate, and the over-riding Australian Plate. In its short historic period (ca. 160 years), the region has been impacted by large earthquakes on the strike-slip faults, but has yet to bear the brunt of a subduction interface rupture directly beneath the capital city. It's Our Fault is a comprehensive study of Wellington's earthquake risk. Its objective is to position the capital city of New Zealand to become more resilient through an encompassing study of the likelihood of large earthquakes, and the effects and impacts of these earthquakes on humans and the built environment. It's Our Fault is jointly funded by New Zealand's Earthquake Commission, Accident Compensation Corporation, Wellington City Council, Wellington Region Emergency Management Group, Greater Wellington Regional Council, and Natural Hazards Research Platform. The programme has been running for six years, and key results to date include better definition and constraints on: 1) location, size, timing, and likelihood of large earthquakes on the active faults closest to Wellington; 2) earthquake size and ground shaking characterization of a representative suite of subduction interface rupture scenarios under Wellington; 3) stress interactions between these faults; 4) geological, geotechnical, and geophysical parameterisation of the near-surface sediments and basin geometry in Wellington City and the Hutt Valley; and 5) characterisation of earthquake ground shaking behaviour in these two urban areas in terms of subsoil classes specified in the NZ Structural Design Standard. The above investigations are already supporting measures aimed at risk reduction, and collectively they will facilitate identification of additional actions that will have the greatest benefit towards further

Distribution and seasonal variation of trace metals in surface sediments of the Mandovi estuary, west coast of India

Digital Repository Service at National Institute of Oceanography (India)

Alagarsamy, R.

The concentration and distribution of selected trace metals in surface sediments of the Mandovi estuary were studied to determine the extent of anthropogenic inputs from mining activities and to estimate the effects of monsoon on geochemical...

Surface complexation modeling for predicting solid phase arsenic concentrations in the sediments of the Mississippi River Valley alluvial aquifer, Arkansas, USA

Science.gov (United States)

Sharif, M.S.U.; Davis, R.K.; Steele, K.F.; Kim, B.; Hays, P.D.; Kresse, T.M.; Fazio, J.A.

2011-01-01

The potential health impact of As in drinking water supply systems in the Mississippi River Valley alluvial aquifer in the state of Arkansas, USA is significant. In this context it is important to understand the occurrence, distribution and mobilization of As in the Mississippi River Valley alluvial aquifer. Application of surface complexation models (SCMs) to predict the sorption behavior of As and hydrous Fe oxides (HFO) in the laboratory has increased in the last decade. However, the application of SCMs to predict the sorption of As in natural sediments has not often been reported, and such applications are greatly constrained by the lack of site-specific model parameters. Attempts have been made to use SCMs considering a component additivity (CA) approach which accounts for relative abundances of pure phases in natural sediments, followed by the addition of SCM parameters individually for each phase. Although few reliable and internally consistent sorption databases related to HFO exist, the use of SCMs using laboratory-derived sorption databases to predict the mobility of As in natural sediments has increased. This study is an attempt to evaluate the ability of the SCMs using the geochemical code PHREEQC to predict solid phase As in the sediments of the Mississippi River Valley alluvial aquifer in Arkansas. The SCM option of the double-layer model (DLM) was simulated using ferrihydrite and goethite as sorbents quantified from chemical extractions, calculated surface-site densities, published surface properties, and published laboratory-derived sorption constants for the sorbents. The model results are satisfactory for shallow wells (10.6. m below ground surface), where the redox condition is relatively oxic or mildly suboxic. However, for the deep alluvial aquifer (21-36.6. m below ground surface) where the redox condition is suboxic to anoxic, the model results are unsatisfactory. ?? 2011 Elsevier Ltd.

The Enduring Legacy of New Zealand's UNCLOS Investment (Invited)

Science.gov (United States)

Wood, R.; Davy, B. W.; Herzer, R. H.; Barnes, P.; Barker, D. H.; Stagpoole, V.; Uruski, C.

2013-12-01

Data collected by surveys for New Zealand's extended continental shelf project have contributed to research into the tectonic history and resource potential of New Zealand. More than 20 scientific papers and a similar number of conference presentations and posters have used the data collected by these surveys. Data collected by these surveys have added significantly to national and international databases. Although the surveys were generally oriented to establish prolongation rather than to cross structural trends, the data have revealed the crustal, basement and sedimentary structure of many parts of the New Zealand region. In the area east of New Zealand, the data provide insight into the Cretaceous evolution of the New Zealand sector of Gondwana. Data collected southwest of New Zealand provided details about the relatively sudden transition from sea floor spreading between New Zealand and Australia in the Tasman Sea to orthogonal spreading in the Emerald Basin and the development of the modern Australian-Pacific plate boundary, including Late Tertiary motion on the Alpine Fault in the South Island, New Zealand. The data have been used to understand the formation of the New Caledonia Basin, the Norfolk Ridge and their associated structures, and they underpin the international collaboration between New Zealand, New Caledonia and Australia to promote resource exploration in the Tasman Sea. Data north of New Zealand have been used to understand the complex tectonic history of back arc spreading and island arc migration in the South Fiji Basin region. Seismic data collected along the axis of the New Caledonia Basin led to extensive hydrocarbon exploration surveys in the deepwater Taranaki region inside New Zealand's EEZ, and to an application for a hydrocarbon exploration licence in New Zealand's extended continental shelf.

Shift in the microbial community composition of surface water and sediment along an urban river.

Science.gov (United States)

Wang, Lan; Zhang, Jing; Li, Huilin; Yang, Hong; Peng, Chao; Peng, Zhengsong; Lu, Lu

2018-06-15

Urban rivers represent a unique ecosystem in which pollution occurs regularly, leading to significantly altered of chemical and biological characteristics of the surface water and sediments. However, the impact of urbanization on the diversity and structure of the river microbial community has not been well documented. As a major tributary of the Yangtze River, the Jialing River flows through many cities. Here, a comprehensive analysis of the spatial microbial distribution in the surface water and sediments in the Nanchong section of Jialing River and its two urban branches was conducted using 16S rRNA gene-based Illumina MiSeq sequencing. The results revealed distinct differences in surface water bacterial composition along the river with a differential distribution of Proteobacteria, Cyanobacteria, Actinobacteria, Bacteroidetes and Acidobacteria (P urban water. PICRUSt metabolic inference analysis revealed a growing number of genes associated with xenobiotic metabolism and nitrogen metabolism in the urban water, indicating that urban discharges might act as the dominant selective force to alter the microbial communities. Redundancy analysis suggested that the microbial community structure was influenced by several environmental factors. TP (P urban river. These results highlight that river microbial communities exhibit spatial variation in urban areas due to the joint influence of chemical variables associated with sewage discharging and construction of hydropower stations. Copyright © 2018 Elsevier B.V. All rights reserved.

Origin and migration of trace elements in the surface sediments of Majuro Atoll, Marshall Islands.

Science.gov (United States)

Ito, Lisa; Omori, Takayuki; Yoneda, Minoru; Yamaguchi, Toru; Kobayashi, Ryuta; Takahashi, Yoshio

2018-07-01

The sediments of Majuro Atoll, Marshall Islands, consist of bioclastic materials, including foraminifera and coral debris. The sedimentary depth profiles of elements showed that various elements including zinc (Zn) and copper (Cu) were enriched in the upper layers of the islands of Majuro Atoll. Carbon-14 dating revealed that the sedimentation of the upper layer was completed before 1670 and 542 cal BP in Laura and Calalen, respectively. The enriched elements could be categorized by their origins: (a) terrestrial elements transported as dust (aluminum (Al) and rare earth elements (REEs)); (b) anthropogenic elements (Zn and Cu); and (c) elements supplied by seabirds (phosphorus (P)). From the results of the total amount of Al supplied to sediments for ca. 2000 years, Al in Majuro Atoll was suggested to be airborne origin. The enrichment factors of the elements normalized to Al concentration of continental crust showed that REEs were also transported as dust, while Zn and Cu were mainly of anthropogenic origin. The speciation analysis by X-ray absorption near-edge structure (XANES) showed the presence of Zn-Cu alloys originated from industrial products. It was also revealed that Zn was enriched in the surface due to anthropogenic emission after urbanization on Majuro Atoll and fixed by carbonate and phosphate at the upper layer, which inhibits migration of Zn into the deeper layer and its release to the groundwater and costal water. Hence, the fixation of heavy metals at the surface prevents their exposure to aquatic organisms and residents via fresh groundwater in the island. Copyright © 2018 Elsevier Ltd. All rights reserved.

Fiscal 2000 survey report on coal exploitability overseas. Rajah area, New Zealand; 2000 nendo kaigaitan kaihatsu kanosei chosa hokokusho. New Zealand Rajah chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

A geological structure survey was conducted in the Rajah mining field, New Zealand, to study coil exploitability there. Conducted were the drilling of five boreholes (and three more by Solid Energy Corporation, New Zealand), surface exploration, surface survey, borehole core specimen examination, coal specimen analysis, and the like. It was found that the coal from this field includes 3-5% of ash and 0.3-0.4% of sulfur and therefore is excellent as coal for coke making. There are three working coal beds, 1.7m at the thinnest section and approximately 7m at the thickest section. It is concluded, on the assumption that sections not less than 2m in thickness are productive, that there are approximately 15-million tons in reserve. Since the coal beds are inclined and very variable in thickness, it is believed that hydraulic coal mining will be the best method to use. Water for hydraulic coal mining is sufficiently supplied from rivers in the neighborhood. The field is located near Rapahoe which serves as depot for coal produced in this area, is equipped with facilities for shipment by rail, and has various industries necessary for supporting coal mine operation. Coal is shipped from Greymouth Port in the area aboard 8,000-tons class barges. (NEDO)

Distribution and contamination status of chromium in surface sediments of northern Kaohsiung Harbor, Taiwan.

Science.gov (United States)

Dong, Cheng-Di; Chen, Chiu-Wen; Chen, Chih-Feng

2013-07-01

The distribution, enrichment, accumulation, and potential ecological risk of chromium (Cr) in the surface sediments of northern Kaohsiung Harbor, Taiwan, China were investigated. Sediment samples from ten locations located between the river mouths and harbor entrance of northern Kaohsiung Harbor were collected quarterly in 2011 and characterized for Cr, aluminum, water content, organic matter, total nitrogen, total phosphorous, total grease, and grain size. Results showed that the Cr concentrations varied from 27.0 to 361.9 mg/kg with an average of (113.5 +/- 87.0) mg/kg. High Cr concentration was observed near the Jen-Gen River mouth. The mean Cr concentration was high at 255.5 mg/kg, which was at least 2 to 7 times than that of other sites. This might imply significant Cr contribution from upstream receiving tanneries wastewater into the Jen-Gen River. The spatial distribution of Cr reveals relatively high in the river mouth region, especially in Jen-Gen River, and gradually diminishes toward the harbor entrance region. This indicates that the major sources of Cr pollution from upstream industrial and municipal wastewaters discharged along the river bank; and Cr may drift with sea current and be dispersed into open sea. Moreover, Cr concentrations correlated closely to the physical-chemical properties of the sediments, which suggested the influence of industrial and municipal wastewaters discharged from the neighboring industrial parks and river basins. Results from the enrichment factor and geo-accumulation index analyses imply that the Jen-Gen River sediments can be characterized as moderate enrichment and none to medium accumulation of Cr, respectively. However, results of potential ecological risk index indicate that the sediment has low ecological potential risk. The results can provide valuable information to developing future strategies for the management of river mouth and harbor.

A palynological study of Polynesian and European effects on vegetation in Coromandel, New Zealand, showing the variability between four records from a single swamp

International Nuclear Information System (INIS)

Byrami, M.; Ogden, J.; Horrocks, M.; Deng, Y.; Shane, P.; Palmer, J.

2002-01-01

Seven cores were extracted from a river terrace swamp in the forested Kauaeranga valley, Coromandel Peninsula, New Zealand. High-resolution (c. 36-73 yr interval) pollen records were obtained from four of the cores and aged by radiocarbon dating and with stratigraphic reference to the 665 ± 15 14 C yr BP Kaharoa Tephra. The records span the last c. 1800 yr and show that the vegetation consisted of lowland podocarp-hardwood forest before deforestation by burning occurred. The pattern of deforestation at Kauaeranga, indicated by the abrupt dominance of Pteridium with concurrent increased charcoal, is typical of pollen records associated with early Polynesian settlement in New Zealand. Peaks of Pteridium and charcoal were also found in sediments deposited after European settlement. Different cores show marked palynological and stratigraphic differences relative to the Kaharoa Tephra, most importantly with regard to the timing of deforestation. Deforestation occurred close to the Kaharoa, at a calculated age of c. 750 BP in one core but well above the Kaharoa (c. 480 BP) in another. The stratigraphic unconformities between cores are attributed to variable fluvial processes causing an uneven deposition of sediments within the swamp. (author). 32 refs., 8 figs., 4 tabs

Ability of One-Dimensional Hairsine-Rose Erosion Model to Predict Sediment Transport over a Soil with Significant Surface Stones

Science.gov (United States)

Jomaa, S.; Barry, D. A.; Sander, G. C.; Parlange, J.-Y.; Heng, B. C. P.; Tromp-van Meerveld, H. J.

2010-05-01

Surface stones affect erosion rates by reducing raindrop-driven detachment and protecting the original soil against overland flow induced-hydraulic stress. Numerous studies have shown that the effect of surface stones on erosion depends on both the stone characteristics (e.g., size, distribution) and the soil properties. The aim of this study was (i) to quantify how the stone characteristics can affect the total sediment concentration and the concentrations of the individual size classes, (ii) to test if stones affect preferentially a particular size class within the eroded sediment and (iii) to determine whether the 1D Hairsine-Rose (H-R) erosion model can represent the experimental data. A series of laboratory experiments were conducted using the 2 m × 6 m EPFL erosion flume for a high rainfall intensity (60 mm/h) event on a gentle slope (2.2%). The flume was divided into two identical 1-m wide flumes. This separation was done to allow simultaneous replicate experiments. Experiments were conducted with different configurations and scenarios (stone coverage, size and emplacement). Three coverage proportions (20%, 40%, and 70%), two stone diameters (3-4 and 6-7 cm) and two emplacement types (topsoil and partially embedded) were tested. For each experiment, the total sediment concentration, the concentration for the individual size classes, and the flume discharge were measured. Infiltration rates were measured at different depths and locations. A high resolution laser scanner provided details of the surface change due to erosion during the experiments. This technique allowed us to quantify the spatial distribution of eroded soil and to understand better if sediment transport is 1D or rather 2D over the flumes. The one-dimensional Hairsine-Rose (H-R) erosion model was used to fit the integrated data and to provide estimates of the parameters. The ability of the 1D H-R model to predict the measured sediment concentrations in the presence of stones in the soil matrix

Extreme pressure differences at 0900 NZST and winds across New Zealand

Science.gov (United States)

Salinger, M. James; Griffiths, Georgina M.; Gosai, Ashmita

2005-07-01

Trends in extremes in station daily sea-level pressure differences at 0900 NZST are examined, and extreme daily wind gusts, across New Zealand, since the 1960s. Annual time series were examined (with indices of magnitude and frequency over threshold percentiles) from the daily indices selected. These follow from earlier indices of normalized monthly mean sea-level pressure differences between station pairs, except the daily indices are not normalized. The frequency statistics quantify the number of extreme zonal (westerly and easterly), or extreme meridional (southerly or northerly), pressure gradient events. The frequency and magnitude of extreme westerly episodes has increased slightly over New Zealand, with a significant increase in the westerly extremes to the south of New Zealand. In contrast, the magnitude and frequency of easterly extremes has decreased over New Zealand, but increased to the south, with some trends weakly significant. The frequency and magnitude of daily southerly extremes has decreased significantly in the region.Extreme daily wind gust events at key climate stations in New Zealand and at Hobart, Australia, are highly likely to be associated with an extreme daily pressure difference. The converse was less likely to hold: extreme wind gusts were not always observed on days with extreme daily pressure difference, probably due to the strong influence that topography has on localized station winds. Significant correlations exist between the frequency indices and both annual-average mean sea-level pressures around the Australasian region and annual-average sea surface temperature (SST) anomalies in the Southern Hemisphere. These correlations are generally stronger for indices of extreme westerly or extreme southerly airflows. Annual-average pressures in the Tasman Sea or Southern Ocean are highly correlated to zonal indices (frequency of extreme westerlies). SST anomalies in the NINO3 region or on either side of the South Island are

Antarctic air over New Zealand following vortex breakdown in 1998

Directory of Open Access Journals (Sweden)

J. Ajtic

2003-11-01

Full Text Available An ozonesonde profile over the Network for Detection of Stratospheric Change (NDSC site at Lauder (45.0° S, 169.7° E, New Zealand, for 24 December 1998 showed atypically low ozone centered around 24 km altitude (600 K potential temperature. The origin of the anomaly is explained using reverse domain filling (RDF calculations combined with a PV/O3 fitting technique applied to ozone measurements from the Polar Ozone and Aerosol Measurement (POAM III instrument. The RDF calculations for two isentropic surfaces, 550 and 600 K, show that ozone-poor air from the Antarctic polar vortex reached New Zealand on 24–26 December 1998. The vortex air on the 550 K isentrope originated in the ozone hole region, unlike the air on 600 K where low ozone values were caused by dynamical effects. High-resolution ozone maps were generated, and their examination shows that a vortex remnant situated above New Zealand was the cause of the altered ozone profile on 24 December. The maps also illustrate mixing of the vortex filaments into southern midlatitudes, whereby the overall mid-latitude ozone levels were decreased.Key words. Atmospheric composition and structure (middle atmosphere composition and chemistry – Meteorology and atmospheric dynamics (middle atmosphere dynamics

Antarctic air over New Zealand following vortex breakdown in 1998

Directory of Open Access Journals (Sweden)

J. Ajtic

Full Text Available An ozonesonde profile over the Network for Detection of Stratospheric Change (NDSC site at Lauder (45.0° S, 169.7° E, New Zealand, for 24 December 1998 showed atypically low ozone centered around 24 km altitude (600 K potential temperature. The origin of the anomaly is explained using reverse domain filling (RDF calculations combined with a PV/O₃ fitting technique applied to ozone measurements from the Polar Ozone and Aerosol Measurement (POAM III instrument. The RDF calculations for two isentropic surfaces, 550 and 600 K, show that ozone-poor air from the Antarctic polar vortex reached New Zealand on 24–26 December 1998. The vortex air on the 550 K isentrope originated in the ozone hole region, unlike the air on 600 K where low ozone values were caused by dynamical effects. High-resolution ozone maps were generated, and their examination shows that a vortex remnant situated above New Zealand was the cause of the altered ozone profile on 24 December. The maps also illustrate mixing of the vortex filaments into southern midlatitudes, whereby the overall mid-latitude ozone levels were decreased.

Key words. Atmospheric composition and structure (middle atmosphere composition and chemistry – Meteorology and atmospheric dynamics (middle atmosphere dynamics

Salinity shapes microbial diversity and community structure in surface sediments of the Qinghai-Tibetan Lakes.

Science.gov (United States)

Yang, Jian; Ma, Li'an; Jiang, Hongchen; Wu, Geng; Dong, Hailiang

2016-04-26

Investigating microbial response to environmental variables is of great importance for understanding of microbial acclimatization and evolution in natural environments. However, little is known about how microbial communities responded to environmental factors (e.g. salinity, geographic distance) in lake surface sediments of the Qinghai-Tibetan Plateau (QTP). In this study, microbial diversity and community structure in the surface sediments of nine lakes on the QTP were investigated by using the Illumina Miseq sequencing technique and the resulting microbial data were statistically analyzed in combination with environmental variables. The results showed total microbial community of the studied lakes was significantly correlated (r = 0.631, P diversity and community structure in the studied samples. In addition, the abundant and rare taxa (OTUs with relative abundance higher than 1% and lower than 0.01% within one sample, respectively) were significantly (P < 0.05) correlated (r = 0.427 and 0.783, respectively) with salinity, suggesting rare taxa might be more sensitive to salinity than their abundant counterparts, thus cautions should be taken in future when evaluating microbial response (abundant vs. rare sub-communities) to environmental conditions.

Polycyclic aromatic hydrocarbon (PAH) contamination of surface sediments and oysters from the inter-tidal areas of Dar es Salaam, Tanzania

International Nuclear Information System (INIS)

Gaspare, Lydia; Machiwa, John F.; Mdachi, S.J.M.; Streck, Georg; Brack, Werner

2009-01-01

Surface sediment and oyster samples from the inter-tidal areas of Dar es Salaam were analyzed for 23 polycyclic aromatic hydrocarbons (PAHs) including the 16 compounds prioritized by US-EPA using GC/MS. The total concentration of PAHs in the sediment ranged from 78 to 25,000 ng/g dry weight, while oyster concentrations ranged from 170 to 650 ng/g dry weight. Hazards due to sediment contamination were assessed using Equilibrium Partitioning Sediment Benchmarks and Threshold Effect Levels. Diagnostic indices and principle component analysis were used to identify possible sources. Interestingly, no correlation between sediment and oyster concentrations at the same sites was found. This is supported by completely different contamination patterns, suggesting different sources for both matrices. Hazard assessment revealed possible effects at six out of eight sites on the benthic communities and oyster populations. The contribution of PAH intake via oyster consumption to carcinogenic risks in humans seems to be low. - PAH contamination may pose hazards to benthos but limited risks to humans

Polycyclic aromatic hydrocarbon (PAH) contamination of surface sediments and oysters from the inter-tidal areas of Dar es Salaam, Tanzania

Energy Technology Data Exchange (ETDEWEB)

Gaspare, Lydia; Machiwa, John F. [Department of Aquatic Environment and Conservation, University of Dar es Salaam, P.O. Box 60091, Dar es Salaam (Tanzania, United Republic of); Mdachi, S.J.M. [Department of Chemistry, University of Dar es Salaam, P.O. Box 35062, Dar es Salaam (Tanzania, United Republic of); Streck, Georg [UFZ Helmholtz Centre for Environmental Research Leipzig-Halle, Department of Effect-Directed Analysis, Permoserstrasse 15, 04318 Leipzig (Germany); Brack, Werner [UFZ Helmholtz Centre for Environmental Research Leipzig-Halle, Department of Effect-Directed Analysis, Permoserstrasse 15, 04318 Leipzig (Germany)], E-mail: werner.brack@ufz.de

2009-01-15

Surface sediment and oyster samples from the inter-tidal areas of Dar es Salaam were analyzed for 23 polycyclic aromatic hydrocarbons (PAHs) including the 16 compounds prioritized by US-EPA using GC/MS. The total concentration of PAHs in the sediment ranged from 78 to 25,000 ng/g dry weight, while oyster concentrations ranged from 170 to 650 ng/g dry weight. Hazards due to sediment contamination were assessed using Equilibrium Partitioning Sediment Benchmarks and Threshold Effect Levels. Diagnostic indices and principle component analysis were used to identify possible sources. Interestingly, no correlation between sediment and oyster concentrations at the same sites was found. This is supported by completely different contamination patterns, suggesting different sources for both matrices. Hazard assessment revealed possible effects at six out of eight sites on the benthic communities and oyster populations. The contribution of PAH intake via oyster consumption to carcinogenic risks in humans seems to be low. - PAH contamination may pose hazards to benthos but limited risks to humans.

Gases (CH4, CO2 and N2 and pore water chemistry in the surface sediments of Lake Orta, Italy: acidification effects on C and N gas cycling

Directory of Open Access Journals (Sweden)

Donald D. ADAMS

2001-02-01

Full Text Available Lake Orta, a subalpine, warm monomictic lake in northwestern Italy was heavily polluted from rayon factory discharges of ammonium and copper since 1926. In the 1950s accumulations of contaminants resulted in whole lake pHs of 3.8-4.0 from ammonium oxidation. Partial remediation started in the 1950s, but by 1985-89 the water remained acidified at pHs of 4.0. Artificial liming (14,500 t in 1989-90 resulted in improved water quality and substantial recovery of the biological community. Sediment gases, sampled in 1989 before liming, from the lake's four basins showed severe inhibition of methanogenesis (CH4 = 0.0-0.15 mM in the surface sediments (0.5-5 cm of the southern basin, location of the plant effluent, as compared to the deep central and northern basins (0.9-1.4 mM. Four years after liming, cores collected in 1994 near the 1989 southern basin sites showed a slight change in surface sediment methane (0.07-0.82 mM, yet suggested continual sediment toxicity, at least to carbon cycling through methanogenesis. Calculations of diffuse flux of CH4 at the sediment-water interface (SWI in 1989 were 6.6-7.4 mM m-2 day-1 for the central and northern basins and 0.13 for the southern basin. CH4 fluxes increased 16x to 2 mM m-2 day-1 in 1994 in the southern basin, possibly from remediation of near surface sediments. The impact of pollution on denitrification (formation of sediment N2 gas was not so obvious since two processes could counteract each other (high NO3 - stimulating denitrification versus possible negative effects from acidity and metals. The calculated flux of N2 from the southern basin sediments increased 5x four years after liming compared to the period of acidification, suggesting possible toxicity towards denitrifiers during the earlier period. Core overlying water (0.68 mM exhibited N2 concentrations close to saturation, while most surface sediments were twice as much (1.5 mM. Surface (0-6 cm sediment N2 was similar at most sites, with the

Spatial distribution of pollen grains and spores in surface sediments of Guanabara Bay, Rio de Janeiro, Brazil.

Science.gov (United States)

Barreto, Cintia F; Vilela, Claudia G; Baptista-Neto, José A; Barth, Ortrud M

2012-09-01

Aiming to investigate the deposition of pollen grains and spores in Guanabara Bay, Rio de Janeiro State, 61 surface sediment samples were analyzed. The results showed that the current deposition of palynomorphs in surface sediments of Guanabara Bay represents the regional vegetation of this hydrographic basin. The differential distribution of palynomorphs followed a pattern influenced by bathymetry, tidal currents speed, discharge of numerous rivers, and by human activity. The dominance of representatives of Field Vegetation reflects the changes of the original flora caused by intense human activities in the region. The continued presence and richness of pollen types of rain forest in the samples indicates that their source area might be the vegetation from riparian border of rivers in the western sector of the Bay, where the mangrove vegetation is being preserved. The large amount of damaged palynomorphs may be related to abrasion that occurs during river transport, indicating removal or reworking from their areas of origin.

Coastal surface sediment quality assessment in Leizhou Peninsula (South China Sea) based on SEM-AVS analysis.

Science.gov (United States)

Li, Feng; Lin, Jin-qin; Liang, Yan-yan; Gan, Hua-yang; Zeng, Xiang-yun; Duan, Zhi-peng; Liang, Kai; Liu, Xing; Huo, Zhen-hai; Wu, Chang-hua

2014-07-15

Surface sediments from the coastal area of the Leizhou Peninsula in the South China Sea were collected and analyzed and the potential ecological risks in the area were assessed based on acid-volatile sulfide (AVS) model. The AVS levels are between 0.109 and 55.6 μmol g(-1), with the average at 4.45 μmol g(-1). The high AVS-concentration zones include the aquaculture areas of Liusha Bay and the densely populated areas of Zhanjiang Bay. The simultaneously extracted metals (SEM) range from 0.026 μmol g(-1) to 8.61 μmol g(-1), with the average at 0.843 μmol g(-1). Most of high SEM-concentration stations were located in ports or aquaculture zones. Most of the coastal surface sediments of the Leizhou Peninsula (90%) had no adverse biological effects according to the criterion proposed by USEPA (2005); while adverse effects were uncertain in some stations (8%); even in 2 stations (2%) adverse biological effects may be expected. Copyright © 2014 Elsevier Ltd. All rights reserved.

Bisphenol analogues in surface water and sediment from the shallow Chinese freshwater lakes: Occurrence, distribution, source apportionment, and ecological and human health risk.

Science.gov (United States)

Yan, Zhengyu; Liu, Yanhua; Yan, Kun; Wu, Shengmin; Han, Zhihua; Guo, Ruixin; Chen, Meihong; Yang, Qiulian; Zhang, Shenghu; Chen, Jianqiu

2017-10-01

Compared to Bisphenol A (BPA), current knowledge on the spatial distribution, potential sources and environmental risk assessment of other bisphenol analogues (BPs) remains limited. The occurrence, distribution and sources of seven BPs were investigated in the surface water and sediment from Taihu Lake and Luoma Lake, which are the Chinese shallow freshwater lakes. Because there are many industries and living areas around Taihu Lake, the total concentrations of ∑BPs were much higher than that in Luoma Lake, which is away from the industry-intensive areas. For the two lakes, BPA was still the dominant BPs in both surface water and sediment, followed by BPF and BPS. The spatial distribution and principal component analysis showed that BPs in Luoma Lake was relatively homogeneous and the potential sources were relatively simple than that in Taihu Lake. The spatial distribution of BPs in sediment of Taihu Lake indicated that ∑BPs positively correlated with the TOC content. For both Taihu Lake and Luoma Lake, the risk assessment at the sampling sites showed that no high risk in surface water and sediment (RQ t  < 1.0, and EEQ t  < 1.0 ng E 2 /L). Copyright © 2017 Elsevier Ltd. All rights reserved.

Abundance and δ13C values of fatty acids in lacustrine surface sediments: Relationships with in-lake methane concentrations

Science.gov (United States)

Stötter, Tabea; Bastviken, David; Bodelier, Paul L. E.; van Hardenbroek, Maarten; Rinta, Päivi; Schilder, Jos; Schubert, Carsten J.; Heiri, Oliver

2018-07-01

Proxy-indicators in lake sediments provide the only approach by which the dynamics of in-lake methane cycling can be examined on multi-decadal to centennial time scales. This information is necessary to constrain how lacustrine methane production, oxidation and emissions are expected to respond to global change drivers. Several of the available proxies for reconstructing methane cycle changes of lakes rely on interpreting past changes in the abundance or relevance of methane oxidizing bacteria (MOB), either directly (e.g. via analysis of bacterial lipids) or indirectly (e.g. via reconstructions of the past relevance of MOB in invertebrate diet). However, only limited information is available about the extent to which, at the ecosystem scale, variations in abundance and availability of MOB reflect past changes in in-lake methane concentrations. We present a study examining the abundances of fatty acids (FAs), particularly of 13C-depleted FAs known to be produced by MOB, relative to methane concentrations in 29 small European lakes. 39 surface sediment samples were obtained from these lakes and FA abundances were compared with methane concentrations measured at the lake surface, 10 cm above the sediments and 10 cm within the sediments. Three of the FAs in the surface sediment samples, C16:1ω7c, C16:1ω5c/t, and C18:1ω7c were characterized by lower δ13C values than the remaining FAs. We show that abundances of these FAs, relative to other short-chain FAs produced in lake ecosystems, are related with sedimentary MOB concentrations assessed by quantitative polymerase chain reaction (qPCR). We observed positive relationships between methane concentrations and relative abundances of C16:1ω7c, C16:1ω5c/t, and C18:1ω7c and the sum of these FAs. For the full dataset these relationships were relatively weak (Spearman's rank correlation (rs) of 0.34-0.43) and not significant if corrected for multiple testing. However, noticeably stronger and statistically significant

Ecological and taphonomical influences on coccoliths in surface sediments in the shelf of the Yellow and East China Seas

Science.gov (United States)

Jin, Xiaobo; Liu, Chuanlian

2017-05-01

Coccoliths, combined with sediment grain size, carbonate calcium and organic matters content, were analyzed to assess the ecological and taphonomical influences on coccolith distribution patterns in surface sediments in the continental shelf of the Yellow and East China Seas. Coccolith abundances ranged from 0 to 2.08×109 coccoliths g-1 sediment. The increasing abundance from the coastal inner shelf to the seaward middle shelf generally reflects the ecological fact that living coccolithophores are more abundant in the mesotrophic shelf waters than in the eutrophic coastal waters, although their deposits are still controlled by taphonomical effects, such as bottom (tidal) currents and calcite preservation conditions. Most abundant coccoliths are found in the fine-grained sediments of southwestern Cheju Island, where both ecology and taphonomy favor coccolith preservation. Still, large densities of coccoliths (>108 coccoliths g-1 sediment) are also found in coarse-grained relict sediments in the middle shelf. Coccolith assemblages were predominated by Gephyrocapsa oceanica and Emiliania huxleyi. The relative abundance of E. huxleyi, in addition to ecological reasons, may relate to selective post-mortem dissolution, since small E. huxleyi coccoliths are more susceptible to dissolution. Coccolith calcite has minor contributions (<1% to 12%) to total sediment CaCO3, and the main parts are attributed to terrigenous CaCO3 debris and relict shell fragments.

Geochemistry of organic carbon and nitrogen in surface sediments of coastal Bohai Bay inferred from their ratios and stable isotopic signatures

International Nuclear Information System (INIS)

Gao Xuelu; Yang Yuwei; Wang Chuanyuan

2012-01-01

Total organic carbon (TOC), total nitrogen (TN) and their δ 13 C and δ 15 N values were determined for 42 surface sediments from coastal Bohai Bay in order to determine the concentration and identify the source of organic matter. The sampling sites covered both the marine region of coastal Bohai Bay and the major rivers it connects with. More abundant TOC and TN in sediments from rivers than from the marine region reflect the situation that most of the terrestrial organic matter is deposited before it meets the sea. The spatial variation in δ 13 C and δ 15 N signatures implies that the input of organic matter from anthropogenic activities has a more significant influence on its distribution than that from natural processes. Taking the area as a whole, surface sediments in the marine region of coastal Bohai Bay are dominated by marine derived organic carbon, which on average accounts for 62 ± 11% of TOC.

Field studies of estuarine turbidity under different freshwater flow conditions, Kaipara River, New Zealand

Science.gov (United States)

Mitchell, Steven B.; Green, Malcolm O.; MacDonald, Iain T.; Pritchard, Mark

2017-11-01

We present a first interpretation of three days of measurements made in 2013 from the tidal reaches of the Kaipara River (New Zealand) under both low and high freshwater inputs and a neap tidal cycle. During the first day, we occupied two stations that were approximately 6 km apart in a tidal reach that runs for 25 km from the river mouth to the upstream limit of tidal influence. During the second day, longitudinal surveys were conducted over a distance of 6 km centred on the upstream station. The data reveal a turbidity maximum in the form of a high-concentration 'plug' of suspended mud that was advected downstream on the ebbing tide past the upper (HB) measurement station and which exchanged sediment with the seabed by settling at low slack water and by resuspension in the early flooding tide. The data suggest that fine sediment is transported landwards and trapped in the upper part of the tidal reach under these low-flow conditions. On the third day of measurements we repeated the experiments of the first day but later in the year, for a much higher freshwater flow. This interpretation of our data set highlights the potential contribution of a range of processes to the generation of the observed suspended-sediment signals, including resuspension of local bed sediment, advection by the tidal current, settling of suspended sediment over a long timescale compared to the advection timescale, advection of longitudinal gradients in suspended sediment, and suppression of vertical mixing by density stratification of the water column. The level of temporal and spatial detail afforded by these measurements allows a much clearer understanding of the timing and importance of vertical stratification on the transport of suspended particulate matter than is generally possible using fixed-point sensors.

International migration and New Zealand labour markets.

Science.gov (United States)

Farmer, R S

1986-06-01

"This paper seeks to assess the value of the overseas-born members of the labour force in ensuring a flexible labour supply in New Zealand since the beginning of the 1970s. Three main issues are considered: first, the role of the labour market in New Zealand's immigration policy; second, international migration trends and the labour market; and third, the evidence on migration and labour market segmentation in New Zealand." Data used are from official external migration statistics, quinquennial censuses, and recent research. The author notes that "in New Zealand immigration measures are currently being taken that emphasize that immigration continues to add to the flexibility of the labour market while uncontrolled emigration is a major cause of labour market instability." (SUMMARY IN FRE AND SPA) excerpt

[Heavy metals distribution characteristics and ecological risk evaluation in surface sediments of dammed Jinshan lake].

Science.gov (United States)

Zhou, Xiao-Hong; Liu, Long-Mei; Chen, Xi; Chen, Zhi-Gang; Zhang, Jin-Ping; Li, Yi-Min; Liu, Biao

2014-11-01

In order to reveal the pollution loading of heavy metals in Dammed Jinshan lake, six heavy metals (As, Cu, Pb, Cd, Zn, Cr) from 18 sediment samples were analyzed using ICP, and the distribution characteristics of heavy metals in the sediment were comprehensively evaluated through concentration coefficient, geo-acumulation indexes, potential ecological risk evaluation and traceability analysis. The results showed that (1) the average contents of As, Pb, Cu, Zn, Cr, Cd were 23.22, 26.20, 24.42, 143.12, 245.30 and 0.67 mg x kg(-1), respectively, in the surface sediments of dammed Jinshan Lake. The average contents of Pb and Cu were lower than the primary standard and secondary standards of soil environmental quality standards. The average contents of Zn and Cr were lower than the primary standard and higher than the secondary standards of soil environmental quality standards. The average contents of As and Cd were higher than the primary and secondary standards of soil environmental quality standards. From the spatial distribution, the contents of Pb and Zn were the highest at sampling site No. 1, which was located at the Beigushan Square. The contents of As,Cu, Cr, Cd were the highest at sampling sites Nos. 12, 3, 14, and 7, respectively; (2) The order of concentration coefficient was As > Cr > Cd > Pb > Zn > Cu, which indicated that the enrichment amount of As was the highest and that of Cu was the lowest; (3) Based on the geo-acumulation indexes, the Cu is clean and Pb, Zn, Cd is the light pollution and As, Cr moderate pollution; (4) The order of Potential ecological risk coefficient was Cd > As > Cr > Pb > Cu > Zn, Cr, Pb, Cu, Zn were of light ecological risk and As, Cd were of medium ecological risk. From the spatial distribution, the sampling sites Nos. 1, 6, 7 and 12 had medium potential ecological risk, and the rest sample points had slight potential ecological risk; (5) The principal component analysis (PCA) revealed that the main reason for the differences

Arsenic Fate, Transport And Stability Study: Groundwater, Surface Water, Soil And Sediment Investigation At Fort Devens Superfund Site

Science.gov (United States)

A field investigation was conducted to examine the distribution of arsenic in groundwater, surface water, and sediments at the Fort Devens Superfund Site. The study area encompassed a portion of plow Shop Pond (Red Cove), which receives groundwater discharge from the aquifer und...

'Poorly defined': unknown unknowns in New Zealand Rural Health.

Science.gov (United States)

Fearnley, David; Lawrenson, Ross; Nixon, Garry

2016-08-05

There is a considerable mismatch between the population that accesses rural healthcare in New Zealand and the population defined as 'rural' using the current statistics New Zealand rural and urban categorisations. Statistics New Zealand definitions (based on population size or density) do not accurately identify the population of New Zealanders who actually access rural health services. In fact, around 40% of people who access rural health services are classified as 'urban' under the Statistics New Zealand definition, while a further 20% of people who are currently classified as 'rural' actually have ready access to urban health services. Although there is some recognition that current definitions are suboptimal, the extent of the uncertainty arising from these definitions is not widely appreciated. This mismatch is sufficient to potentially undermine the validity of both nationally-collated statistics and also any research undertaken using Statistics New Zealand data. Under these circumstances it is not surprising that the differences between rural and urban health care found in other countries with similar health services have been difficult to demonstrate in New Zealand. This article explains the extent of this mismatch and suggests how definitions of rural might be improved to allow a better understanding of New Zealand rural health.

Distribution of tributyltin in surface sediments from transitional marine-lagoon system of the south-eastern Baltic Sea, Lithuania.

Science.gov (United States)

Suzdalev, Sergej; Gulbinskas, Saulius; Blažauskas, Nerijus

2015-02-01

The current research paper presents the results of contamination by tributyltin (TBT) compounds in Klaipėda Port, which is situated in a unique marine-lagoon water interaction zone. One hundred fifty-four surface sediment samples have been taken along the whole transition path from lagoon to the sea and analysed in order to quantify the contamination rate in specific environment of high anthropogenic pressure. The detected TBT concentrations ranged from 1 to 5,200 ng Sn g(-1) of dry weight of sediment. The back-trace of horizontal distribution of TBT-contaminated sediments show obvious increase of tributyltin concentrations closer to port areas dealing with ship repair and places of dry-docking facilities. This is a clear indication that those activities are the main source of contamination in the study area. The estimated correlation of TBT concentration in sediments with total organic carbon and the amount of fine fraction (tributyltin is related to potential contamination source areas (ship repairing, dockyards) due to direct input of hazardous substances into the water.

Health Risks to Children and Adults Residing in Riverine Environments where Surficial Sediments Contain Metals Generated by Active Gold Mining in Ghana.

Science.gov (United States)

Armah, Frederick Ato; Gyeabour, Elvis Kyere

2013-03-01

The purpose of this study was to investigate the current status of metal pollution in the sediment from rivers, lakes, and streams in active gold mining districts in Ghana. Two hundred and fifty surface sediment samples from 99 locations were collected and analyzed for concentrations of As, Hg, Cr, Co, Cu, Fe, Zn, Pb, Cd, Ni, and Mn using inductively coupled plasma-mass spectroscopy (ICP-MS). Metal concentrations were then used to assess the human health risks to resident children and adults in central tendency exposure (CTE) and reasonable maximum exposure (RME) scenarios. The concentrations of Pb, Cd, and As were almost twice the threshold values established by the Hong Kong Interim Sediment Quality Guidelines (ISQG). Hg, Cu, and Cr concentrations in sediment were 14, 20, and 26 times higher than the Canadian Freshwater Sediment Guidelines for these elements. Also, the concentrations of Pb, Cu, Cr, and Hg were 3, 11, 12, and 16 times more than the Australian and New Zealand Environment and Conservation Council (ANZECC) sediment guideline values. The results of the human health risk assessment indicate that for ingestion of sediment under the central tendency exposure (CTE) scenario, the cancer risks for child and adult residents from exposure to As were 4.18 × 10(-6) and 1.84 × 10(-7), respectively. This suggests that up to 4 children out of one million equally exposed children would contract cancer if exposed continuously to As over 70 years (the assumed lifetime). The hazard index for child residents following exposure to Cr(VI) in the RME scenario was 4.2. This is greater than the United States Environmental Protection Agency (USEPA) threshold of 1, indicating that adverse health effects to children from exposure to Cr(VI) are possible. This study demonstrates the urgent need to control industrial emissions and the severe heavy metal pollution in gold mining environments.

Flow-sediment-large woody debris interplay: Introducing an appropriately scaled laboratory experiment

Science.gov (United States)

Friedrich, H.; Spreitzer, G.; Tunnicliffe, J. F.

2017-12-01

The morphology of steep (>0.01 m/m) forested streams is governed not only by water-sediment interplay, but also by accumulations of coarse and fine organic debris. In this project we look at the jamming dynamics (formation, persistence and hydraulic feedbacks) of large woody debris with the help of scaled laboratory experiments. In New Zealand, the recruitment of wood from both natural tree-fall and forest harvesting has led to obstruction of culverts, bridges and other river constrictions. Understanding the dynamics of jam formation and persistence is important for harvest practice guidelines, management of sediment accumulation, as well as establishing impacts to habitat and infrastructure. In this study, we provide the context of our work, present our experimental setup for studying the complex flow-sediment-wood interactions and present some initial results. In our experimental setup, we varied feed rates of sediment and organic fine material in order to establish concentration thresholds for jam formation, and development of sediment retention capacity upstream of the jam. Large woody debris accumulation is studied for different blocking scenarios, and the effect on sediment transport is measured. Sediment quantities and changes in channel bed morphology upstream of the critical cross section are evaluated, together with resulting backwater effects, and associated energy losses. In the long term, our results will inform our understanding of the processes that take place from the mobilization of woody debris to accumulation.

Vegetation death and rapid loss of surface elevation in two contrasting Mississippi delta salt marshes: The role of sedimentation, autocompaction and sea-level rise

Science.gov (United States)

Day, J.W.; Kemp, G.P.; Reed, D.J.; Cahoon, D.R.; Boumans, R.M.; Suhayda, J.M.; Gambrell, R.

2011-01-01

From 1990 to 2004, we carried out a study on accretionary dynamics and wetland loss in salt marshes surrounding two small ponds in the Mississippi delta; Old Oyster Bayou (OB), a sediment-rich area near the mouth of the Atchafalaya River and Bayou Chitigue (BC), a sediment-poor area about 70. km to the east. The OB site was stable, while most of the marsh at BC disappeared within a few years. Measurements were made of short-term sedimentation, vertical accretion, change in marsh surface elevation, pond wave activity, and marsh soil characteristics. The OB marsh was about 10. cm higher than BC; the extremes of the elevation range for Spartina alterniflora in Louisiana. Vertical accretion and short-term sedimentation were about twice as high at BC than at OB, but the OB marsh captured nearly all sediments deposited, while the BC marsh captured <30%. The OB and BC sites flooded about 15% and 85% of the time, respectively. Marsh loss at BC was not due to wave erosion. The mineral content of deposited sediments was higher at OB. Exposure and desiccation of the marsh surface at OB increased the efficiency that deposited sediments were incorporated into the marsh soil, and displaced the marsh surface upward by biological processes like root growth, while also reducing shallow compaction. Once vegetation dies, there is a loss of soil volume due to loss of root turgor and oxidation of root organic matter, which leads to elevation collapse. Revegetation cannot occur because of the low elevation and weak soil strength. The changes in elevation at both marsh sites are punctuated, occurring in steps that can either increase or decrease elevation. When a marsh is low as at BC, a step down can result in an irreversible change. At this point, the option is not restoration but creating a new marsh with massive sediment input either from the river or via dredging. ?? 2010 Elsevier B.V.

Occurrence and distribution of selected heavy metals in the surface sediments of South Brittany coastal waters: An assessment using pollution indicators

Science.gov (United States)

Ong, M. C.; Menier, D.; Noor Azhar, M. S.; Dupont, V.; Révillon, S.

2012-04-01

In order to avoid the pollution of heavy metals in South Brittany water, it is necessary to establish the data and understand the mechanisms influencing the distribution of heavy metals of the area. One of the aims of this work was to assess heavy metals contamination in Gulf of Morbihan and Quiberon Bay. Another aim was to use interpolation surfaces per metals to assess the contamination separately per metal. A total of 196 bottom sediment samples were collected from the coastal waters in order to determine the spatial concentration of Cr, Mn, Co, Cu, Zn, Cd and Pb by Inductively Coupled Plasma Mass Spectrometry (ICPMS) after acid digestion. The average heavy metal concentrations are ranked as follows: Mn>Zn>Cr>Pb>Cu>Cu>Cd. In the gulf, metal enrichments observed compared to the bay environment may due river run-off from three major river (Auray, Le Marle and Novalo rivers) which carried municipal waste and maritime activities along the coastal area within the gulf. Beside those factors, the natural factors such as the sheltered basin morphology itself, fine sediment and low hydrodynamic regime which favour the in situ accumulation of pollutants. The level of pollution levels attributed to heavy metals was evaluated using several pollution indicators in order to determine anthropogenically derived sediment contamination. Comparison to sediment quality guidelines (SQGs), enrichment factors (EFs), index of geoaccumulation (Igeo) and contamination factors (CF) based on reference element and background value to compensate for the influence of the natural variability in sediment mineralogy and to assess whether the concentration observed in surface sediment represent background and contaminated levels and visualize using ArcGIS software. These analyses validated that the bottom sediment only enriched in Pb and the other metals in most sample are not due to artificial contamination. Overall, geochemistry of the samples show the effect of both natural and anthropogenic

Fluvial sediment transport: Analytical techniques for measuring sediment load

International Nuclear Information System (INIS)

2005-07-01

Sediment transport data are often used for the evaluation of land surface erosion, reservoir sedimentation, ecological habitat quality and coastal sediment budgets. Sediment transport by rivers is usually considered to occur in two major ways: (1) in the flow as a suspended load and (2) along the bed as a bed load. This publication provides guidance on selected techniques for the measurement of particles moving in both modes in the fluvial environment. The relative importance of the transport mode is variable and depends on the hydraulic and sedimentary conditions. The potential user is directed in the selection of an appropriate technique through the presentation of operating principles, application guidelines and estimated costs. Techniques which require laboratory analysis are grab sample, pump sample, depth sample, point integrated and radioactive tracers. Techniques which will continuously record data are optical backscattering, nuclear transmission, single frequency acoustic and laser diffraction

Quantifying dust input to the Subarctic North Pacific - Results from surface sediments and sea water thorium isotope measurements

Science.gov (United States)

Winckler, G.; Serno, S.; Hayes, C.; Anderson, R. F.; Gersonde, R.; Haug, G. H.

2012-12-01

The Subarctic North Pacific is one of the three primary high-nutrient-low chlorophyll regions of the modern ocean, where the biological pump is relatively inefficient at transferring carbon from the atmosphere to the deep sea. The system is thought to be iron-limited. Aeolian dust is a significant source of iron and other nutrients that are essential for the health of marine ecosystems and potentially a controlling factor of the high-nutrient-low chlorophyll status of the Subarctic North Pacific. However, constraining the size of the dust flux to the surface ocean remains difficult. Here we apply two different approaches, based on surface sediment and water column samples, respectively, obtained during the SO202/INOPEX research cruise to the Subarctic North Pacific in 2009. We map the spatial patterns of Th/U isotopes, helium isotopes and rare earth elements across surface sediments from 37 multi-core core-top sediments across the Subarctic North Pacific. In order to deconvolve the detrital endmembers in regions of the North Pacific affected by volcanic material, IRD and hemipelagic input, we use a combination of trace elements with distinct characteristics in the different endmembers. This approach allows us to calculate the relative aeolian fraction, and in combination with Thorium230-normalized mass flux data, to quantify the dust supply. Secondly, we present an innovative approach to use paired Thorium-232 and Thorium-230 concentrations of upper-ocean seawater at 7 stations along the INOPEX track. Thorium-232 in the upper water column is dominantly derived from dissolution of aeolian dust, whereas Thorium-230 data provide a measure of the thorium removal from the surface waters and, thus, allow us to derive Thorium-232 fluxes. Combined with a mean Thorium-232 concentration in dust and estimate of the thorium solubility, the Thorium-232 flux can be translated in a dust flux to the surface ocean. Dust flux estimates for the Subarctic North Pacific will be

Uranium Phases in Contaminated Sediments Below Hanford's U Tank Farm

International Nuclear Information System (INIS)

Um, Wooyong; Wang, Zheming; Serne, R. Jeffrey; Williams, Benjamin D.; Brown, Christopher F.; Dodge, Cleveland J.; Francis, Arokiasamy J.

2009-01-01

Macroscopic and spectroscopic investigations (XAFS, XRF and TRLIF) on Hanford contaminated vadose zone sediments from the U-tank farm showed that U(VI) exists as different surface phases as a function of depth below ground surface (bgs). Dominant U(VI) silicate precipitates (boltwoodite and uranophane) were present in shallow-depth sediments (15-16 m bgs). In the intermediate depth sediments (20-25 m bgs), adsorbed U(VI) phases dominated but small amounts of surface precipitates consisting of polynuclear U(VI) surface complex were also identified. The deep depth sediments (> 28 m bgs) showed no signs of contact with tank wastes containing Hanford-derived U(VI), but natural uranium solid phases were observed. Most of the U(VI) was preferentially associated with the silt and clay size fractions and showed strong correlation with Ca, especially for the precipitated U(VI) silicate phase in the shallow depth sediments. Because U(VI) silicate precipitates dominate the U(VI) phases in the shallow depth sediments, macroscopic (bi)carbonate leaching should result in U(VI) releases from both desorption and dissolution processes. Having several different U(VI) surface phases in the Hanford contaminated sediments indicates that the U(VI) release mechanism could be complicated and that detailed characterization of the sediments would be needed to estimate U(VI) fate and transport in vadose zone

Distribution and temporal variation of trace metal enrichment in surface sediments of San Jorge Bay, Chile.

Science.gov (United States)

Valdés, Jorge; Román, Domingo; Guiñez, Marcos; Rivera, Lidia; Morales, Tatiana; Morales, Tomás; Avila, Juan; Cortés, Pedro

2010-08-01

Cu, Pb, and Hg concentrations were determined in surface sediment samples collected at three sites in San Jorge Bay, northern Chile. This study aims to evaluate differences in their spatial distribution and temporal variability. The highest metal concentrations were found at the site "Puerto", where minerals (Cu and Pb) have been loaded for more than 60 years. On the other hand, Hg does not pose a contamination problem in this bay. Cu and Pb concentrations showed significant variations from 1 year to another. These variations seem to be a consequence of the combination of several factors, including changes in the loading and/or storage of minerals in San Jorge Bay, the dredging of bottom sediments (especially at Puerto), and seasonal changes in physical-chemical properties of the water column that modify the exchange of metals at the sediment-water interface. Differences in the contamination factor and geoaccumulation index suggest that pre-industrial concentrations measured in marine sediments of this geographical zone, were better than geological values (average shale, continental crust average) for evaluating the degree of contamination in this coastal system. Based on these last two indexes, San Jorge Bay has a serious problem of Cu and Pb pollution at the three sampling locations. However, only Cu exceeds the national maximum values used to evaluate ecological risk and the health of marine environments. It is suggested that Chilean environmental legislation for marine sediment quality--presently under technical discussion--is not an efficient tool for protecting the marine ecosystem.

[Sources, pollution statue and potential ecological risk of heavy metals in surface sediments of Aibi Lake, Northwest China].

Science.gov (United States)

Zhang, Zhao-Yong; Abuduwaili, Jilili; Jiang, Feng-Qing

2015-02-01

In this paper, the surface sediment samples were harvested from Aibi Lake, and total contents of 8 heavy metals ( Cu, Pb, Zn, As, Hg, Cr, Ni and Cd) were determined. Then the sources, pollution statue, and potential ecological risk were analyzed by using multiple analysis methods. The results show that: (1) The order of the skewness for these 8 heavy metals is: Hg > Cd > Pb > Zn > As > Cu > Cr > Ni. (2) Multivariate statistical analysis shows that 8 heavy metals can be classified to 2 principle components, among which PC1 ( Cd, Pb, Hg and Zn) is man-made source factor and mainly came from all kinds of waste of agriculture; PC2 ( Cu, Ni, Cr and As) is natural source and was mainly controlled by the background of the natural geography of this area. (3) Accumulation of index evaluation results show that the order of pollution degree values of 8 heavy metals in surface sediments of Aibi Lake is: Cd > Hg > Pb > Zn > As > Cu > Ni > Cr. In all samples, heavy metals Hg, Cd and Pb all belong to low and partial moderate pollution statue, while Zn, As, Cr, Ni and Cu belong to no pollution statue in majority samples. (4) Potential ecological risk assessment results show that the potential ecological risk of heavy metals in surface sediments of Aibi Lake mainly caused by Cd, Hg and Pb, and they accounting for 42.6%, 28.6% and 24.0% of the total amount, respectively, among which Cd is the main ecological risk factor, followed by Hg and Pb. In all samples, the potential ecological risk index values (RI) of 8 heavy metals are all lower than 150, and they are all at low ecological risk levels. However, this research also shows that there have high content of Cd and Pb in the sediment. Therefore, we should make long-term monitoring of the lake environment.

Biogeochemistry of sulfur and iron in Thioploca-colonized surface sediments in the upwelling area off central Chile

DEFF Research Database (Denmark)

Zopfi, Jakob; Michael E., Böttcher; Jørgensen, Bo Barker

2008-01-01

suggest further that pyritization at depth includes light sulfide, potentially originating from bacterial sulfur disproportionation. The δ34S-values of pyrite down to -38‰ vs. V-CDT are among the lightest found in organic-rich marine sediments. Seasonal variations in the sulfur isotope composition...... of dissolved sulfate indicated a dynamic non-steady-state sulfur cycle in the surface sediments. The 18O content of porewater sulfate increased with depth at all sites compared to the bottom water composition due to intracellular isotope exchange reactions during microbial sulfur transformations....

Study of cadmium, lead and tin distribution in surface marine sediment samples from Ria de Arousa (NW of Spain)

International Nuclear Information System (INIS)

Barciela-Alonso, M.C.; Pazos-Capeans, P.; Regueira-Miguens, M.E.; Bermejo-Barrera, A.; Bermejo-Barrera, P.

2004-01-01

In this work a study of the Cd, Pb and Sn content in marine surface sediment from the Ria de Arousa has been realised. For this, 21 sediment samples were taken in triplicate, lyophilised and sieved, and the fraction -1 Cd, 26.5-91.3 μg g -1 Pb and 5.0-20.8 μg g -1 Sn. The highest concentrations of these metals are in the inner part of the Ria, near to the port and urban nucleus such as Vilagarcia or Rianxo, and decrease toward the mouth of the Ria

Accumulation patterns of lipophilic organic contaminants in surface sediments and in economic important mussel and fish species from Jakarta Bay, Indonesia

International Nuclear Information System (INIS)

Dwiyitno; Dsikowitzky, Larissa; Nordhaus, Inga; Andarwulan, Nuri; Irianto, Hari Eko; Lioe, Hanifah Nuryani; Ariyani, Farida; Kleinertz, Sonja

2016-01-01

Non-target screening analyses were conducted in order to identify a wide range of organic contaminants in sediment and animal tissue samples from Jakarta Bay. High concentrations of di-iso-propylnaphthalenes (DIPNs), linear alkylbenzenes (LABs) and polycyclic aromatic hydrocarbons (PAHs) were detected in all samples, whereas phenylmethoxynaphthalene (PMN), DDT and DDT metabolites (DDX) were detected at lower concentrations. In order to evaluate the uptake and accumulation by economic important mussel (Perna viridis) and fish species, contaminant patterns of DIPNs, LABs and PAHs in different compartments were compared. Different patterns of these contaminant groups were found in sediment and animal tissue samples, suggesting compound-specific accumulation and metabolism processes. Significantly higher concentrations of these three contaminant groups in mussel tissue as compared to fish tissue from Jakarta Bay were found. Because P. viridis is an important aquaculture species in Asia, this result is relevant for food safety. - Highlights: • Analyses of surface sediment and animal tissue samples from a tropical coastal system • Non-target screening enabled identification of a wide range of organic contaminants. • Comparison of contaminant patterns in surface sediments and animal tissue samples • Results illustrate compound-specific accumulation and metabolism processes. • Higher concentrations of all contaminants in mussel tissue as compared to fish tissue

Pesticide management and their residues in sediments and surface and drinking water in the Mekong Delta, Vietnam.

Science.gov (United States)

Toan, Pham Van; Sebesvari, Zita; Bläsing, Melanie; Rosendahl, Ingrid; Renaud, Fabrice G

2013-05-01

Public concern in Vietnam is increasing with respect to pesticide pollution of the environment and of drinking water resources. While established monitoring programs in the Mekong Delta (MD) focus on the analysis of organochlorines and some organophosphates, the environmental concentrations of more recently used pesticides such as carbamates, pyrethroides, and triazoles are not monitored. In the present study, household level pesticide use and management was therefore surveyed and combined with a one year environmental monitoring program of thirteen relevant pesticides (buprofezin, butachlor, cypermethrin, α-endosulfan, β-endosulfan, endosulfan-sulfate, fenobucarb, fipronil, isoprothiolane, pretilachlor, profenofos, propanil, and propiconazole) in surface water, soil, and sediment samples. The surveys showed that household level pesticide management remains suboptimal in the Mekong Delta. As a consequence, a wide range of pesticide residues were present in water, soil, and sediments throughout the monitoring period. Maximum concentrations recorded were up to 11.24 μg l(-1) in water for isoprothiolane and up to 521 μg kg(-1) dm in sediment for buprofezin. Annual average concentrations ranged up to 3.34 μg l(-1) in water and up to 135 μg kg(-1) dm in sediment, both for isoprothiolane. Occurrence of pesticides in the environment throughout the year and co-occurrence of several pesticides in the samples indicate a considerable chronic exposure of biota and humans to pesticides. This has a high relevance in the delta as water for drinking is often extracted from canals and rivers by rural households (GSO, 2005, and own surveys). The treatment used by the households for preparing surface water prior to consumption (flocculation followed by boiling) is insufficient for the removal of the studied pesticides and boiling can actually increase the concentration of non-volatile pollutants. Copyright © 2012 Elsevier B.V. All rights reserved.

Marine sediments as a sink, and contaminated sediments as a diffuse source of radionuclides

International Nuclear Information System (INIS)

Salbu, B.; Borretzen, P.

1997-01-01

Full text: Marine sediments may act as a sink for radionuclides originating from atmospheric fallout (e.g. Chernobyl accident), for radionuclides in discharges from nuclear installations (e.g. Sellafield, UK) for river transported radionuclides, and radionuclides released from nuclear waste dumped at sea (e.g. fjords at Novaya Zemlya). In order to assess short and long term consequences of radionuclides entering the marine ecosystem, the role of sediments as a relatively permanent sink and the potential for contaminated sediments to act as a diffuse source should be focused. The retention of radionuclides in sediments will depend on the source term, i.e. the physico-chemical forms of radionuclides entering the system and on interactions with various sediment components. Radionuclides associated with particles or aggregating polymers are removed from the water phase by sedimentation, while sorption to surface sediment layers is of relevance for ionic radionuclide species including negatively charged colloids. With time, transformation processes will influence the mobility of radionuclides in sediments. The diffusion into mineral lattices will increase fixation, while the influence of for instance red/ox conditions and bio-erosion may mobilize radionuclides originally fixed in radioactive particles. Thus, information of radionuclides species, surface interactions, transformation processes and kinetics is essential for reducing the uncertainties in marine transfer models. Dynamic model experiments where chemically well defined tracers are added to a sea water-marine sediment system are useful for providing information on time dependent interactions and distribution coefficients. When combined with sequential extraction techniques, information on mobility and rate of fixation is subsequently attained. In the present work experimental results from the Irish Sea and the Kara Sea will be discussed

226Ra, 228Ra and 228Ra/226Ra in surface marine sediment of Malaysia

International Nuclear Information System (INIS)

Mei-Wo Yii; Zal Uyun Wan-Mahmood

2013-01-01

Surface sediment samples were collected at the West (east coast and west coast of Peninsular Malaysia) and East (Sabah and Sarawak) Malaysia in several expeditions within August 2003 until June 2008 for determining the level of natural radium isotopes. Activity concentrations of 226 Ra and 228 Ra in surface marine sediment at 176 sampling stations were measured. The activity concentrations of both radionuclides in Malaysia (East and West Malaysia) display varied with the range from 9 to 158 Bq/kg dry wt. and 13 to 104 Bq/kg dry wt., respectively. Meanwhile, the ratio distributions of 228 Ra/ 226 Ra were ranged from 0.62 to 3.75. This indicated that the ratios were slightly high at west coast of Peninsular Malaysia compared to other regions (east coast of Peninsular Malaysia, Sabah and Sarawak). The variation of activity concentrations of 226 Ra and 228 Ra and its ratios were also supported by the statistical analyses of one-way ANOVA and t test at 95 % confidence level, whereby there were proved that the measured values were different between the regions. These different were strictly related to their half-life, potential input sources (included their parents, 238 U and 232 Th), parent's characteristic, the geological setting/formation of the study area, environment origin and behavior. (author)

226Ra-210Pb-210Po Levels in Marine Biota and Surface Coastal Sediments from the Red Sea, Sudan

International Nuclear Information System (INIS)

Sirelkhatim, D.A.; Sam, A.K.; Hassona, R.K.

2003-01-01

This paper presents data on 226 Ra, 210 Pb and 210 Po activity concentration levels in multicellular marine algae, molluscs, coral as well as in surface marine sediments collected from the shallower waters of the fringing reefs area extending towards north and south (Flamingo bay) of Port sudan harbour. The analyses were performed adopting a simple time efficient method combining alpha-spectrometry, liquid scintillation and Cerenkov counting technique. Generally speaking, surface sediments from this coastal region are poor in their radioactivity content in contrast to similar data reported from different coastal areas around the globe. There is surface enrichment of 210 Pb and 210 Po with respect to their progenitor 226 Ra as it is evident from the activity ratios of 210 Pb/ 226 Ra (3.03±1.79) and 210 Po/ 226 Ra (2.23±1.56). Among marine plants and animals investigated, the green algae species, Halimeda, and coral species, Favites, show substantial concentration of radium at 8.2 Bq/KXg and 21.9 Bq/KXg dry weight, respectively

Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments of rivers and an estuary in Shanghai, China

International Nuclear Information System (INIS)

Ying Liu; Ling Chen; Zhao Jianfu; Huang Qinghui; Zhu Zhiliang; Gao Hongwen

2008-01-01

Concentrations, spatial distribution and sources of 17 polycyclic aromatic hydrocarbons (PAHs) and methylnaphthalene were investigated in surface sediments of rivers and an estuary in Shanghai, China. Total PAH concentrations, excluding perylene, ranged from 107 to 1707 ng/g-dw. Sedimentary PAH concentrations of the Huangpu River were higher than those of the Yangtze Estuary. The concentration of the Suzhou River was close to the average concentration of the Huangpu River. PAHs source analysis suggested that, in the Yangtze Estuary, PAHs at locations far away from cities were mainly from petrogenic sources. At other locations, both petrogenic and pyrogenic inputs were significant. In the Huangpu and Suzhou Rivers, pyrogenic input outweighed other sources. The pyrogenic PAHs in the upper reaches of the Huangpu River were mainly from the incomplete combustion of grass, wood and coal, and those in the middle and lower reaches were from vehicle and vessel exhaust. - Surface sediments of two rivers and an estuary in Shanghai were contaminated by PAHs

Heavy metal distributions in Peru Basin surface sediments in relation to historic, present and disturbed redox environments

Science.gov (United States)

Koschinsky, Andrea

Heavy metal distributions in deep-sea surface sediments and pore water profiles from five areas in the Peru Basin were investigated with respect to the redox environment and diagenetic processes in these areas. The 10-20-cm-thick Mn oxide-rich and minor metal-rich top layer is underlain by an increase in dissolved Mn and Ni concentrations resulting from the reduction of the MnO 2 phase below the oxic zone. The mobilised associated metals like Co, Zn and Cu are partly immobilised by sorption on clay, organic or Fe compounds in the post-oxic environment. Enrichment of dissolved Cu, Zn, Ni, Co, Pb, Cd, Fe and V within the upper 1-5 cm of the oxic zone can be attributed to the degradation of organic matter. In a core from one area at around 22-25 cm depth, striking enrichments of these metals in dissolved and solid forms were observed. Offset distributions between oxygen penetration and Mn reduction and the thickness of the Mn oxide-rich layer indicate fluctuations of the Mn redox boundary on a short-term time scale. Within the objectives of the German ATESEPP research programme, the effect of an industrial impact such as manganese nodule mining on the heavy metal cycle in the surface sediment was considered. If the oxic surface were to be removed or disturbed, oxygen would penetrate deep into the formerly suboxic sediment and precipitate Mn 2+ and metals like Ni and Co which are preferably scavenged by MnO 2. The solid enrichments of Cd, V, and other metals formed in post-oxic environments would move downward with the new redox boundary until a new equilibrium between oxygen diffusion and consumption is reached.

Perceptions of migrant doctors joining the New Zealand medical workforce.

Science.gov (United States)

Lillis, Steven; St George, Ian; Upsdell, Ruth

2006-02-17

New Zealand, like many first World countries, has become increasingly dependent on overseas-trained doctors (OTDs). This qualitative study identifies and explores issues of concern to OTDs when first integrating into the New Zealand medical system through the New Zealand Registration Examination (NZREX) pathway. The data were collected using semistructured interviews and focus groups involving 10 OTDs who were working in a New Zealand hospital. The study identified four key issues: work issues which included difficulty finding employment and difficulty integrating into their work role; a bridging programme which improved the ability of OTDs to gain knowledge and experience of the New Zealand medical working environment; financial difficulties which were a major impediment to attaining registration and a career pathway in New Zealand; and bureaucratic barriers (including examinations and information availability), which were seen as necessary but unsympathetic processes in gaining registration. Sociocultural educational theory provides a useful framework for understanding the difficulties faced by OTDs integrating into a New Zealand medical workforce.

Beryllium-10 in Chesapeake Bay sediments: an indicator of sediment provenance

International Nuclear Information System (INIS)

Helz, G.R.; Valette-Silver, Nathalie

1992-01-01

In a plot of 10 Be vs. Fe, central Chesapeake Bay sediments can be segregated into distinct units. This plot reveals an unexpected, statistically significant difference between sediments on the eastern and western flanks of the main channel, implying different origins. Although the 10 Be concentrations in sediments from these two regions span as much as an order of magnitude range, the 10 Be/Fe ratios vary by an amount approximating analytical error alone. The large concentration ranges are ascribed to hydraulic sorting, which can produce variance in composition while not affecting ratios between grain surface components such as Fe and Be. On the basis of 10 Be/Fe signatures, sediments on the western flank of the main channel appear to have been derived from the Susquehanna or another Piedmont/Appalachian river. Sediments on the eastern flank may have been transported from the south, by landward flowing bottom currents, or may be relics of a Pleistocene estuarine system. Conditions under which 10 Be may prove a useful tool in sediment provenance studies elsewhere are discussed. (Author)

Radionuclides in sediments and seawater at Rongelap Atoll

Energy Technology Data Exchange (ETDEWEB)

Noshkin, V.E.; Robison, W.L.; Eagle, R.J.; Brunk, J.L.

1998-03-01

The present concentrations and distributions of long-lived, man-made radionuclides in Rongelap Atoll lagoon surface sediments, based on samples collected and analyzed in this report. The radionuclides were associated with debris generated with the 1954 Bravo thermonuclear test at Bikini Atoll. Presently, only {sup 90}Sr and the transuranic radionuclides are found associated with the surface sediments in any quantity. Other radionuclides, including {sup 60}Co and {sup 137} Cs, are virtually absent and have either decayed or migrated from the deposits to the overlying seawater. Present inventories of {sup 241}Am and {sup 249+240}Pu in the surface layer at Rongelap are estimated to be 3% of the respective inventories in surface sediments from Bikini Atoll. There is a continuous slow release of the transuranics from the sediments back to the water column. The inventories will only slowly change with time unless the chemical-physical processes that now regulate this release to the water column are changed or altered.

Characterizing bacterial communities in tilapia pond surface sediment and their responses to pond differences and temporal variations.

Science.gov (United States)

Fan, Limin; Barry, Kamira; Hu, Gengdong; Meng, Shunlong; Song, Chao; Qiu, Liping; Zheng, Yao; Wu, Wei; Qu, Jianhong; Chen, Jiazhang; Xu, Pao

2017-01-01

Bacterial community compositions in the surface sediment of tilapia ponds and their responses to pond characteristics or seasonal variations were investigated. For that, three ponds with different stocking densities were selected to collect the samples. And the method of Illumina high-throughput sequencing was used to amplify the bacterial 16S rRNA genes. A total of 662, 876 valid reads and 5649 operational taxonomic units were obtained. Further analysis showed that the dominant phyla in all three ponds were Proteobacteria, Bacteroidetes, Chloroflexi, and Acidobacteria. The phyla Planctomycetes, Firmicutes, Chlorobi, and Spirochaetae were also relatively abundant. Among the eight phyla, the abundances of only Proteobacteria, Bacteroidetes, Firmicutes, and Spirochaetae were affected by seasonal variations, while seven of these (with the exception of Acidobacteria) were affected by pond differences. A comprehensive analysis of the richness and diversity of the bacterial 16S rRNA gene, and of the similarity in bacterial community composition in sediment also showed that the communities in tilapia pond sediment were shaped more by pond differences than by seasonal variations. Linear discriminant analysis further indicated that the influences of pond characteristics on sediment bacterial communities might be related to feed coefficients and stocking densities of genetically improved farmed tilapia (GIFT).

Heavy metals and metalloids in the surface sediments of the Xiangjiang River, Hunan, China: distribution, contamination, and ecological risk assessment.

Science.gov (United States)

Chai, Liyuan; Li, Huan; Yang, Zhihui; Min, Xiaobo; Liao, Qi; Liu, Yi; Men, Shuhui; Yan, Yanan; Xu, Jixin

2017-01-01

Here, we aim to determine the distribution, ecological risk and sources of heavy metals and metalloids in the surface sediments of the Xiangjiang River, Hunan Province, China. Sixty-four surface sediment samples were collected in 16 sites of the Xiangjiang River, and the concentrations of ten heavy metals and metalloids (Mn, Zn, Cr, V, Pb, Cu, As, Ni, Co, and Cd) in the sediment samples were investigated using an inductively coupled plasma mass spectrometer (ICP-MS) and an atomic fluorescence spectrophotometer (AFS), respectively. The results showed that the mean concentrations of the ten heavy metals and metalloids in the sediment samples followed the order Mn > Zn > Cr > V > Pb > Cu > As ≈ Ni >Co > Cd. The geoaccumulation index (I geo ), enrichment factor (EF), modified degree of contamination (mC d ), and potential ecological risk index (RI) revealed that Cd, followed by Pb, Zn, and Cu, caused severely contaminated and posed very highly potential ecological risk in the Xiangjiang River, especially in Shuikoushan of Hengyang, Xiawan of Zhuzhou, and Yijiawan of Xiangtan. The Pearson's correlation coefficient (PCC) analysis, principal component analysis (PCA), and hierarchical cluster analysis (HCA) indicated that the ten heavy metals and metalloids in the sampling sediments of the Xiangjiang River were classified into three groups: (1) Cd, Pb, Zn, and Cu which possibly originated from Shuikoushan, Xiawan, and Yijiawan clustering Pb-Zn mining and smelting industries; (2) Co, V, Ni, Cr, and Al from natural resources; and (3) Mn and As. Therefore, our results suggest that anthropogenic activities, especially mining and smelting, have caused severe contamination of Cd, Pb, Zn, and Cu and posed very high potential ecological risk in the Xiangjiang River.

Algal stabilisation of estuarine sediments

International Nuclear Information System (INIS)

1992-01-01

The presence of benthic microalgae can increase the stability of intertidal sediments and influence sediment fluxes within an estuarine environment. Therefore the relative importance of algal stabilisation needs to be understood to help predict the effects of a tidal barrage. The biogenic stabilisation of intertidal estuarine sediments by epipelic diatom films and the macrophyte Vaucheria was studied at three sites on the Severn Estuary. The cohesive strength meter (CSM) was developed to measure surface critical shear stress with varied algal density. A number of techniques have been used to determine the general in situ erodibility of cohesive estuarine sediments. The measurements of sediment shear strength and critical erosion velocity were investigated. Field experiments were undertaken to investigate the effect of algae on binding sediments, and a predictive method for the assessment of sediment stabilisation by algal binding was developed. (author)

The Little Ice Age climate of New Zealand reconstructed from Southern Alps cirque glaciers: a synoptic type approach

Science.gov (United States)

Lorrey, Andrew; Fauchereau, Nicolas; Stanton, Craig; Chappell, Petra; Phipps, Steven; Mackintosh, Andrew; Renwick, James; Goodwin, Ian; Fowler, Anthony

2014-06-01

Little Ice Age (LIA) austral summer temperature anomalies were derived from palaeoequilibrium line altitudes at 22 cirque glacier sites across the Southern Alps of New Zealand. Modern analog seasons with temperature anomalies akin to the LIA reconstructions were selected, and then applied in a sampling of high-resolution gridded New Zealand climate data and global reanalysis data to generate LIA climate composites at local, regional and hemispheric scales. The composite anomaly patterns assist in improving our understanding of atmospheric circulation contributions to the LIA climate state, allow an interrogation of synoptic type frequency changes for the LIA relative to present, and provide a hemispheric context of the past conditions in New Zealand. An LIA summer temperature anomaly of -0.56 °C (±0.29 °C) for the Southern Alps based on palaeo-equilibrium lines compares well with local tree-ring reconstructions of austral summer temperature. Reconstructed geopotential height at 1,000 hPa (z1000) suggests enhanced southwesterly flow across New Zealand occurred during the LIA to generate the terrestrial temperature anomalies. The mean atmospheric circulation pattern for summer resulted from a crucial reduction of the `HSE'-blocking synoptic type (highs over and to the west of NZ; largely settled conditions) and increases in both the `T'- and `SW'-trough synoptic types (lows passing over NZ; enhanced southerly and southwesterly flow) relative to normal. Associated land-based temperature and precipitation anomalies suggest both colder- and wetter-than-normal conditions were a pervasive component of the base climate state across New Zealand during the LIA, as were colder-than-normal Tasman Sea surface temperatures. Proxy temperature and circulation evidence were used to corroborate the spatially heterogeneous Southern Hemisphere composite z1000 and sea surface temperature patterns generated in this study. A comparison of the composites to climate mode archetypes

Marine biodiversity of Aotearoa New Zealand.

Science.gov (United States)

Gordon, Dennis P; Beaumont, Jennifer; MacDiarmid, Alison; Robertson, Donald A; Ahyong, Shane T

2010-08-02

The marine-biodiversity assessment of New Zealand (Aotearoa as known to Māori) is confined to the 200 nautical-mile boundary of the Exclusive Economic Zone, which, at 4.2 million km(2), is one of the largest in the world. It spans 30 degrees of latitude and includes a high diversity of seafloor relief, including a trench 10 km deep. Much of this region remains unexplored biologically, especially the 50% of the EEZ deeper than 2,000 m. Knowledge of the marine biota is based on more than 200 years of marine exploration in the region. The major oceanographic data repository is the National Institute of Water and Atmospheric Research (NIWA), which is involved in several Census of Marine Life field projects and is the location of the Southwestern Pacific Regional OBIS Node; NIWA is also data manager and custodian for fisheries research data owned by the Ministry of Fisheries. Related data sources cover alien species, environmental measures, and historical information. Museum collections in New Zealand hold more than 800,000 registered lots representing several million specimens. During the past decade, 220 taxonomic specialists (85 marine) from 18 countries have been engaged in a project to review New Zealand's entire biodiversity. The above-mentioned marine information sources, published literature, and reports were scrutinized to give the results summarized here for the first time (current to 2010), including data on endemism and invasive species. There are 17,135 living species in the EEZ. This diversity includes 4,315 known undescribed species in collections. Species diversity for the most intensively studied phylum-level taxa (Porifera, Cnidaria, Mollusca, Brachiopoda, Bryozoa, Kinorhyncha, Echinodermata, Chordata) is more or less equivalent to that in the ERMS (European Register of Marine Species) region, which is 5.5 times larger in area than the New Zealand EEZ. The implication is that, when all other New Zealand phyla are equally well studied, total marine

Regional model simulations of New Zealand climate

Science.gov (United States)

Renwick, James A.; Katzfey, Jack J.; Nguyen, Kim C.; McGregor, John L.

1998-03-01

Simulation of New Zealand climate is examined through the use of a regional climate model nested within the output of the Commonwealth Scientific and Industrial Research Organisation nine-level general circulation model (GCM). R21 resolution GCM output is used to drive a regional model run at 125 km grid spacing over the Australasian region. The 125 km run is used in turn to drive a simulation at 50 km resolution over New Zealand. Simulations with a full seasonal cycle are performed for 10 model years. The focus is on the quality of the simulation of present-day climate, but results of a doubled-CO2 run are discussed briefly. Spatial patterns of mean simulated precipitation and surface temperatures improve markedly as horizontal resolution is increased, through the better resolution of the country's orography. However, increased horizontal resolution leads to a positive bias in precipitation. At 50 km resolution, simulated frequency distributions of daily maximum/minimum temperatures are statistically similar to those of observations at many stations, while frequency distributions of daily precipitation appear to be statistically different to those of observations at most stations. Modeled daily precipitation variability at 125 km resolution is considerably less than observed, but is comparable to, or exceeds, observed variability at 50 km resolution. The sensitivity of the simulated climate to changes in the specification of the land surface is discussed briefly. Spatial patterns of the frequency of extreme temperatures and precipitation are generally well modeled. Under a doubling of CO2, the frequency of precipitation extremes changes only slightly at most locations, while air frosts become virtually unknown except at high-elevation sites.

Trampolines in New Zealand: a decade of injuries.

Science.gov (United States)

Chalmers, D J; Hume, P A; Wilson, B D

1994-01-01

Despite international concern about the safety of trampolines, they have become increasingly popular in New Zealand. While internationally attention has centred on a relatively few cases of catastrophic cervical spine injury, little research effort has been directed at placing these incidents in a wider context. To redress this, a descriptive epidemiological study of trampoline-related injury in New Zealand was undertaken. National hospitalization and mortality data for a 10-year period revealed 2098 hospitalizations and two deaths. The incidence rate for hospitalizations increased from 3.1 per 100,000 population per year in 1979 to 9.3 in 1988. Of the hospitalized victims, 71% were injured on home trampolines and 80% fell from the trampoline to the surrounding surface. Fractures were the commonest type of injury (68%), and the body site most frequently involved was the upper limb (53%). There was no evidence of a high incidence of severe head and neck injuries. It was concluded that, although existing trampoline standards addressed many of the issues raised by this research, measures to reduce the impact of falls from trampolines to the ground and to prohibit the provision of trampolines as 'play equipment' are required. PMID:7894953

Trampolines in New Zealand: a decade of injuries.

Science.gov (United States)

Chalmers, D J; Hume, P A; Wilson, B D

1994-12-01

Despite international concern about the safety of trampolines, they have become increasingly popular in New Zealand. While internationally attention has centred on a relatively few cases of catastrophic cervical spine injury, little research effort has been directed at placing these incidents in a wider context. To redress this, a descriptive epidemiological study of trampoline-related injury in New Zealand was undertaken. National hospitalization and mortality data for a 10-year period revealed 2098 hospitalizations and two deaths. The incidence rate for hospitalizations increased from 3.1 per 100,000 population per year in 1979 to 9.3 in 1988. Of the hospitalized victims, 71% were injured on home trampolines and 80% fell from the trampoline to the surrounding surface. Fractures were the commonest type of injury (68%), and the body site most frequently involved was the upper limb (53%). There was no evidence of a high incidence of severe head and neck injuries. It was concluded that, although existing trampoline standards addressed many of the issues raised by this research, measures to reduce the impact of falls from trampolines to the ground and to prohibit the provision of trampolines as 'play equipment' are required.

Strategic perspective: Nuclear issues in the New Zealand media

International Nuclear Information System (INIS)

Fridriksson, L.N.

1992-01-01

New Zealand's anti-nuclear policy drew international attention and threw the nation into a foreign policy crisis with the United States over the trilateral mutual security pact ANZUS. After more than a year of diminished intelligence and military cooperation, New Zealand was expelled from the alliance. This study involved a content analysis of coverage of these events and other nuclear issues in selected newspapers of New Zealand and the United States. Research points to the roles of the media as a critical one in the overall relations among countries. Through their frequent use of official government sources, the media tend to uphold the government line or status quo with regard to foreign affairs. This study sought to identify the nuclear issues covered in the New Zealand and US media, the characteristics of that coverage, the sources of that coverage and how coverage varied during changing US-New Zealand relations. The official frame prevailed in coverage of nuclear issues. In the New Zealand and US newspapers under study, most sources of nuclear issue news were government officials. This research also found that most coverage of nuclear issues in the New Zealand media was related to some aspect of US interests, and that coverage of New Zealand's policy in the US media was covered most often when related to the United States. Nuclear issue coverage was most often not crisis-oriented in New Zealand and US newspapers, but coverage of all nuclear issues increased dramatically during the period of the ANZUS policy crisis. This study found a number of changes in nuclear issue coverage in the New Zealand media after the policy crisis was resolved. Among those changes were a tendency to focus less on economic and trade effects of the anti-nuclear policy, a tendency to focus more on ties with other South Pacific nations, use more sources from those countries, and a tendency to focus less on the moral and ethical position of the country

[Current situation of acupuncture in New Zealand].

Science.gov (United States)

Li, Xiaoji; Hu, Youping

2017-04-12

The beginning of TCM acupuncture in New Zealand dates back to the middle of 19th century. After self-improvement for more than 100 years, TCM acupuncture has gained a considerable development. From the perspective of history and current situation, the development of acupuncture in New Zealand was elaborated in this article; in addition, the sustainable development of acupuncture was discussed from the perspective of education and training. In New Zealand, the TCM acupuncture and dry needling have played a dominant role in acupuncture treatments, which are practiced by TCM practitioners and physical therapists. The TCM acupuncture is widely applied in department of internal medicine, surgery, gynecology, and pediatrics, etc., while the dry needling is li-mited for traumatology and pain disorder. Therefore, including TCM acupuncture into the public medical and educational system in New Zealand should be an essential policy of Ministry of Health to provide welfare for the people.

Toxicity of silicon carbide nanowires to sediment-dwelling invertebrates in water or sediment exposures

Science.gov (United States)

Mwangi, Joseph N.; Wang, Ning; Ritts, Andrew; Kunz, James L.; Ingersoll, Christopher G.; Li, Hao; Deng, Baolin

2011-01-01

Silicon carbide nanowires (SiCNW) are insoluble in water. When released into an aquatic environment, SiCNW would likely accumulate in sediment. The objective of this study was to assess the toxicity of SiCNW to four freshwater sediment-dwelling organisms: amphipods (Hyalella azteca), midges (Chironomus dilutus), oligochaetes (Lumbriculus variegatus), and mussels (Lampsilis siliquoidea). Amphipods were exposed to either sonicated or nonsonicated SiCNW in water (1.0 g/L) for 48 h. Midges, mussels, and oligochaetes were exposed only to sonicated SiCNW in water for 96 h. In addition, amphipods were exposed to sonicated SiCNW in whole sediment for 10 d (44% SiCNW on dry wt basis). Mean 48-h survival of amphipods exposed to nonsonicated SiCNW in water was not significantly different from the control, whereas mean survival of amphipods exposed to sonicated SiCNW in two 48-h exposures (0 or 15% survival) was significantly different from the control (90 or 98% survival). In contrast, no effect of sonicated SiCNW was observed on survival of midges, mussels, or oligochaetes. Survival of amphipods was not significantly reduced in 10-d exposures to sonicated SiCNW either mixed in the sediment or layered on the sediment surface. However, significant reduction in amphipod biomass was observed with the SiCNW either mixed in sediment or layered on the sediment surface, and the reduction was more pronounced for SiCNW layered on the sediment. These results indicated that, under the experimental conditions, nonsonicated SiCNW in water were not acutely toxic to amphipods, sonicated SiCNW in water were acutely toxic to the amphipods, but not to other organisms tested, and sonicated SiCNW in sediment affected the growth but not the survival of amphipods.

The Sorption Of 137-Cs and 60-Co by RSG-LP Surface Soil And By The Sediment Of Cisadane River

International Nuclear Information System (INIS)

Lubis, E.

1990-01-01

Investigations on the sorption of 137-Cs and 60-Co by the RSG-LP surface soil and by the sediment of the Cisadane river have been carried out. In these experiments, the soil and the sediment were immersade in aqueous solution that was contaminated with 137-Cs and 60-Co. The sorption of 137-Cs and 60-Co is known by measuring the activity of the solution. The results indicated that the concentration factors (Kd) of the 60-Co and 137-Cs are functions of the specific activity of the solution in steady state conditions. The equations for 60-Co in soil and sediment are Kd = 4.45 exp. (-0.292 x C) and Kd = 2.09 exp. (-0.39 x C) respectively. The aquation for 137-Cs in soil and sediment are Kd = 9.19 exp (-0.21 x C) and Kd = 18.29 exp. (-0.18 x C), respectively. (author). 5 refs, 4 figs, 4 tabs

Investigation of Composition of Particle Size in Sediments of Stormwater Sedimentation Tank

Directory of Open Access Journals (Sweden)

Daiva Laučytė

2011-04-01

Full Text Available The main object for the storm water runoff treatment is to remove suspended solids before the storm water runoff is discharged into surface waters. Therefore the sedimentation tank is the most often used treatment facility. In order to optimise the sedimentation, the tendency of particle size distribution in bottom sediments must be known. Two similar size storm water runoff sedimentation tanks in Vilnius city were selected for the analysis of the particle size distribution in sediments. The composite samples of drained storm water runoff sediments were collected at the sedimentation tanks located in the districts of Verkiai and Karoliniskes on the 2nd of June, 2008. The analyses of grain size distribution were performed according the standard ISO/TS 17892-4:2004. The results showed that the particles with the particle size of 1–2 mm were obtained up to 10 m from the inlet and the particles with the size of 0,01–0,05 mm mainly were obtained close to the outlet of sedimentation tank. It is recommended to divide the sedimentation tank in two parts in order to get proper management of sediments: the particles that size is 1–10 mm could be managed as waste from grit chambers and particles of smaller size could be managed as primary sludge.Article in Lithuanian

Isotopic provenance analysis and terrane tectonics: a warning about sediment transport distances

International Nuclear Information System (INIS)

Bassett, K.N.

1999-01-01

Full text: In the last 10 years the field of provenance analysis has undergone a revolution with the development of single-crystal isotopic dating techniques, the most common being U/Pb zircon and 40Ar/39Ar techniques. These have allowed age determination of single crystals thus providing more detail about probable provenance of each individual grain rather than an averaged population of grains. The usefulness for resolving complex terrane accretion and translation histories was immediately obvious and there have been many studies in many different regions aimed at tracking terrane motions by provenance of individual grains upward through the stratigraphy of a basin. Recent research in the North American Cordilleran terranes and in the New Zealand Torlesse Superterrane show how widely used and powerful these provenance analysis techniques are. However, isotopic provenance analysis has often been presented as key information to resolve controversies around terrane translation histories with very little discussion of the context of sedimentary facies and sediment transport mechanisms. An example is the recent use of U/Pb detrital zircon ages as the supposedly controversy-ending evidence for the amount of lateral translation of the Insular Superterrane in British Columbia (Baja BC) (Mahoney et al., 1999). The zircon grains were separated from fine-grained turbidite deposits and could easily have been transported over very large distances by a variety of mechanisms; yet they were presented as definitively resolving the Baja BC controversy. Modern examples illustrate the problem of using the provenance of fine grained sediment to constrain terrane tectonics. Sediment in the tip of the Bengal submarine fan was transported ∼3000 km from source, first by fluvial processes then by sediment gravity flow in the submarine fan. The detrital isotopic ages of single grains are the same as the depositional ages indicating a very rapid unroofing and transport rate with minimal

Late Otiran sedimentation and glacial chronology in the Warwick valley, southeast Nelson

International Nuclear Information System (INIS)

Mabin, M.C.G.

1983-01-01

Approximately 14 m of sediment are exposed in a road cutting beneath a landslide deposit in the Warwick valley, southeast Nelson, New Zealand. Three radiocarbon dates and 5 pollen spectra were obtained from organic horizons in these sediments. The dates indicate that lacustrine sedimentation predominated from before 17 500 until 14 450 years ago. This was interrupted by a brief period of gravel aggradation between 17 500 and 16 650 years ago, which is attributed to a glacial advance. Vegetation at the site was consistently dominated by Cyperaceae, with some Gramineae, suggesting a bleak, treeless landscape. Correlation of this information with other radiocarbon dated sites indicates the need for some revision of the chronology of the late Otira Glaciation. A late phase of the Kumara 2 2 advance occurred between 17 000 and 16 000 years ago, and the Kumara 3 1 advance did not occur until after about 15 000 years ago. The end of the Otira Glaciation probably occurred between 13 000 and 12 500 years ago. (auth)

Late Otiran sedimentation and glacial chronology in the Warwick valley, southeast Nelson

Energy Technology Data Exchange (ETDEWEB)

Mabin, M C.G. [Canterbury Univ., Christchurch (New Zealand). Dept. of Geology

1983-01-01

Approximately 14 m of sediment are exposed in a road cutting beneath a landslide deposit in the Warwick valley, southeast Nelson, New Zealand. Three radiocarbon dates and 5 pollen spectra were obtained from organic horizons in these sediments. The dates indicate that lacustrine sedimentation predominated from before 17,500 until 14,450 years ago. This was interrupted by a brief period of gravel aggradation between 17,500 and 16,650 years ago, which is attributed to a glacial advance. Vegetation at the site was consistently dominated by Cyperaceae, with some Gramineae, suggesting a bleak, treeless landscape. Correlation of this information with other radiocarbon dated sites indicates the need for some revision of the chronology of the late Otira Glaciation. A late phase of the Kumara 2/sub 2/ advance occurred between 17,000 and 16,000 years ago, and the Kumara 3/sub 1/ advance did not occur until after about 15,000 years ago. The end of the Otira Glaciation probably occurred between 13,000 and 12,500 years ago.

Isolation of 2-pyridone alkaloids from a New Zealand marine-derived penicillium species.

Science.gov (United States)

de Silva, E Dilip; Geiermann, Anna-Skrollan; Mitova, Maya I; Kuegler, Philipp; Blunt, John W; Cole, Anthony L J; Munro, Murray H G

2009-03-27

Fermentation of a Penicillium sp. isolated from a surface-sterilized thallus segment of the brown alga Xiphophora gladiata, collected from Macrocarpa Point, Otago, New Zealand, in half-strength potato dextrose broth led to the isolation and characterization of three alkaloids: the known N-hydroxy-2-pyridone, PF1140 (1), and two new 2-pyridones, 2 and 3.

Surface Water Geochemistry, Sediment, and Field Parameters During Snowmelt and Monsoons in the New Mexico Reach of the Animas and San Juan Rivers, 2016

Science.gov (United States)

Blake, J.; Brown, J. E.; Mast, A.

2017-12-01

Following the release of three million gallons of metals laden surface water from the Gold King Mine in August 2015, surface-water samples were collected in the New Mexico reach of the Animas and San Juan Rivers during 2016 snowmelt and in the Animas River during three 2016 monsoonal storms. These samples were evaluated for dissolved (turbidity and specific conductance can provide insight to changes in concentrations of the river on a finer time scale. Regression models developed for selected sites on the Animas and San Juan Rivers show that flow, turbidity and specific conductance may be useful in understanding the relationship between total metal concentrations and real-time parameters. Surrogates for suspended sediment such as hydroacoustic may also be useful, and potentially the best option in this system, for monitoring the concentration of metals in surface water. Further evaluation of the chemistry of the watershed soils and bedrock, the streambed sediments, and suspended sediments will improve understanding of the geochemical processes in the Animas and San Juan Rivers.

Dinoflagellate cysts from surface sediments of Syracuse Bay (Western Ionian Sea, Mediterranean)

Science.gov (United States)

Rubino, Fernando; Belmonte, Manuela; Caroppo, Carmela; Giacobbe, Mariagrazia

2010-02-01

The occurrence and abundance of dinoflagellate cysts were investigated for the first time at an Ionian locality along the south-eastern coast of Sicily, subject to spring-summer harmful algal events. Thirty-four cyst morphotypes were recognized belonging to 24 taxa identified at least at the genus level. Cyst abundance in surface sediments ranged from 43 to 828 cysts g -1 dry weight, with the highest numbers recorded at the most restricted station. Germination experiments allowed confirmation of species identification determined by cyst analysis and provided clonal cultures of Alexandrium minutum and Gymnodinium nolleri, two of the bloom-forming species in the area. This represents the first record of G. nolleri for the Mediterranean Sea.

Characterization of phosphorus interaction with sediments affected by acid mine drainage - relation with the sediment composition

OpenAIRE

Boukemara , Lamia; Boukhalfa , Chahrazed; Azzouz , Sarah; Reinert , Laurence; Duclaux , Laurent; Amrane , Abdeltif; Szymczyk , Anthony

2017-01-01

International audience; Phosphorus sorption capacity was investigated in surface sediments derived from an abandoned zinc-lead mine area located in northeastern Algeria. The forms and the distribution of phosphorus in the raw sediment were identified using the sequential chemical extractions method. Batch experiments were done to study the adsorption kinetics and isotherms. The pH effect was evaluated by macroscopic and infrared analyses. In raw sediment, speciation results show that phosphor...

Chironomid-based reconstructions of summer air temperature from lake deposits in Lyndon Stream, New Zealand spanning the MIS 3/2 transition

Science.gov (United States)

Woodward, C. A.; Shulmeister, J.

2007-01-01

We present chironomid-based temperature reconstructions from lake sediments deposited between ca 26,600 cal yr BP and 24,500 cal yr BP from Lyndon Stream, South Island, New Zealand. Summer (February mean) temperatures averaged 1 °C cooler, with a maximum inferred cooling of 3.7 °C. These estimates corroborate macrofossil and beetle-based temperature inferences from the same site and suggest climate amelioration (an interstadial) at this time. Other records from the New Zealand region also show a large degree of variability during the late Otiran glacial sequence (34,000-18,000 cal yr BP) including a phase of warming at the MIS 2/3 transition and a maximum cooling that did not occur until the global LGM (ca 20,000 cal yr BP). The very moderate cooling identified here at the MIS 2/3 transition confirms and enhances the long-standing discrepancy in New Zealand records between pollen and other proxies. Low abundances (<20%) of canopy tree pollen in records from late MIS 3 to the end of MIS 2 cannot be explained by the minor (<5 °C) cooling inferred from this and other studies unless other environmental parameters are considered. Further work is required to address this critical issue.

Geochemical assessment of heavy metals pollution in surface sediments of Vellar and Coleroon estuaries, southeast coast of India.

Science.gov (United States)

Nethaji, S; Kalaivanan, R; Arya Viswam; Jayaprakash, M

2017-02-15

Surface sediments were collected from Vellar and Coleroon estuaries for determine sediment texture, calcium carbonate, organic matter and heavy metals. Pollution indices such as pollution load index (PLI), contamination factor (CF), enrichment factor (EF) and geo-accumulation index (I geo ) were done for this study to know the level of heavy metals pollution in the estuarine ecosystem. Pearson correlation matrix and factor were used to assess the relationship and source of heavy metals in the estuarine sediments. The results of PLI values reveal that the study area was polluted by all the heavy metals. The calculated values of CF and I geo followed the decreasing order Cu>Ni>Pb>Co>Cr>Zn>Mn>Fe and illustrate that Cu, Ni and Pb are contaminated due to anthropogenic sources in both estuaries. Correlation and factor analysis suggest that FeMn oxyhydroxides, organic matter and fine particles are responsible for high concentration of heavy metals. Copyright © 2016 Elsevier Ltd. All rights reserved.

Migration of trace heavy metals at the sea water/sediment interface

International Nuclear Information System (INIS)

Terada, Kikuo; Tomiyama, Chisato

1984-01-01

Migration behavior of some trace heavy metals such as Co(II), Cu(II), Mn(II) and Zn(II) at the sea water/sediment interface was investigated by tank experiments. The sea water which was doped with these metal ions (ppb to ppm levels) allowed to contact with the raw-, ignited- and autoclaved-marine sediments and the change of the concentration of each metal was traced at definite time intervals. At the end of the experiments, a core sample of the sediment was taken and analyzed for each metal in every 1 mm thick segment. On the other hand, the surface sediment was submitted to partial extraction with various kinds of reagents to estimate the chemical species of the metals captured in the sediment. While every metal ion was quickly adsorbed on surface of the raw sediment, a concentration gradient from surface to bottom of the water phase occurred in the ignited sediment system. The migration of manganese to the sediment phase was assumed to be concerned with bacterial activity in the sediment. Copper and zinc seemed to be adsorbed very quickly onto some fine sediment particles by the formation of organometallic complexes with some organic materials existing in the sediments. Cobalt migrated relatively fast downward within the sediment phase after its deposition. (author)

International tourism and economic growth in New Zealand

OpenAIRE

Mohammad Jaforullah

2015-01-01

This paper examines whether the tourism-led growth hypothesis holds for the New Zealand economy. Using unit root tests, cointegration tests and vector error correction models, and annual data over the period 1972-2012 on international tourism expenditure, real gross domestic product (GDP) and the exchange rate for New Zealand, it finds that the tourism-led growth hypothesis holds for New Zealand. The long-run elasticity of real GDP with respect to international tourism expenditure is estimate...

Spatial distribution and ecological risk assessment of heavy metals in coastal surface sediments in the Hebei Province offshore area, Bohai Sea, China

Science.gov (United States)

Ding, Xigui; Ye, Siyuan; Yuan, Hongming; Krauss, Ken W.

2018-01-01

Seven hundred and nine surface sediment samples, along with deeper sediment samples, were collected from Hebei Province along the coastal section of the Bohai Sea, China, and analyzed for grain size, concentrations of organic carbon (Corg) and heavy metals (Cu, Pb, Zn, Cr, Cd, As, and Hg). Results indicated that the average concentrations in the sediments were 16.1 mg/kg (Cu), 19.4 mg/kg (Pb), 50 mg/kg (Zn), 48.8 mg/kg (Cr), 0.1 mg/kg (Cd), 8.4 mg/kg (As), and 20.3 μg/kg (Hg). These concentrations generally met the China Marine Sediment Quality criteria. However, both pollution assessments indicated moderate to strong Cd and Hg contamination in the study area. The potential ecological risk index suggested that the combined ecological risk of the seven studied metals may be low, but that 24.5% of the sites, where sediments were more finer and higher in Corg concentration, had high ecological risk in Hg and Cd pollution.

Health economics and health policy: experiences from New Zealand.

Science.gov (United States)

Cumming, Jacqueline

2015-06-01

Health economics has had a significant impact on the New Zealand health system over the past 30 years. In this paper, I set out a framework for thinking about health economics, give some historical background to New Zealand and the New Zealand health system, and discuss examples of how health economics has influenced thinking about the organisation of the health sector and priority setting. I conclude the paper with overall observations about the role of health economics in health policy in New Zealand, also identifying where health economics has not made the contribution it could and where further influence might be beneficial.

Effect of resuspension on the release of heavy metals and water chemistry in anoxic and oxic sediments

Energy Technology Data Exchange (ETDEWEB)

Hwang, Kyung-Yup; Kim, Hong-Seok; Hwang, Inseong [School of Civil and Environmental Engineering, Pusan National University, Busan (Korea, Republic of)

2011-10-15

Two types of river sediments with contrasting characteristics (anoxic or oxic) were resuspended and the release of heavy metals and changes in water chemistry were investigated. During resuspension of the anoxic sediment, the dissolved oxygen (DO) concentration and redox potential of the water layer decreased abruptly within the first 1 min, followed by increases toward the end of the resuspension period. Heavy metals were released rapidly in the first 6 h, probably due to the oxidation of acid volatile sulfide (AVS) of the anoxic sediment, and then the aqueous phase concentrations of the heavy metals decreased due to resorption onto the sediment until the 12-h point. During resuspension of the oxic sediment, the DO concentration and redox potential remained relatively constant in the oxic ranges. The heavy metals were released from the oxic sediment gradually during a 24-h resuspension period. The temporal maximum concentrations of Ni, Cu, Zn, and Cd in the aqueous phases in both experiments frequently exceeded the USEPA water quality criteria or the water quality guidelines of Australia and New Zealand. This suggests that a resuspension event could bring about temporal water quality deterioration in the two sediment environments. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Electroconvulsive Therapy Practice in New Zealand.

Science.gov (United States)

Fisher, Mark Wilkinson; Morrison, John; Jones, Paul Anthony

2017-06-01

The aim of this study was to describe the contemporary practice of electroconvulsive therapy (ECT) in New Zealand. A 53-item questionnaire was sent to all services providing ECT as of December 2015. Electroconvulsive therapy was provided by 16 services covering 15 district health boards funded by the New Zealand government. No private facilities provided ECT. All services providing ECT responded to an online survey questionnaire. Rates of ECT utilization were low relative to similar countries. Survey results indicated ECT was practiced to an overall good standard. Several resource and logistical issues potentially contributing to low ECT utilization were identified. Electroconvulsive therapy in New Zealand is provided using modern equipment and practices. However, overall rates of utilization remain low, perhaps as a result of controversy surrounding ECT and some resourcing issues.

History of oceanic front development in the New Zealand sector of the Southern Ocean during the Cenozoic: a synthesis

International Nuclear Information System (INIS)

Nelson, C.S.; Cooke, P.J.

2001-01-01

The New Zealand sector of the Southern Ocean (NZSSO) has opened about the Indian-Pacific spreading ridge throughout the Cenozoic. Today the NZSSO is characterised by broad zonal belts of antarctic (cold), subantarctic (cool), and subtropical (warm) surface-water masses separated by prominent oceanic fronts: the Subtropical Front (STF) c. 43 degrees S, Subantarctic Front (SAF) c. 50 degrees S, and Antarctic Polar Front (AAPF) c. 60 degrees S. Despite a meagre database, the broad pattern of Cenozoic evolution of these fronts is reviewed from the results of Deep Sea Drilling Project-based studies of sediment facies, microfossil assemblages and diversity, and stable isotope records, as well as from evidence in onland New Zealand Cenozoic sequences. Results are depicted schematically on seven paleogeographic maps covering the NZSSO at 10 m.y. intervals through the Cenozoic. During the Paleocene and most of the Eocene (65-35 Ma), the entire NZSSO was under the influence of warm to cool subtropical waters, with no detectable oceanic fronts. In the latest Eocene (c. 35 Ma), a proto-STF is shown separating subantarctic and subtropical waters offshore from Antarctica, near 65 degrees S paleolatitude. During the earliest Oligocene, this front was displaced northwards by development of an AAPF following major global cooling and biotic turnover associated with ice sheet expansion to sea level on East Antarctica. Early Oligocene full opening (c. 31 Ma) of the Tasmanian gateway initiated vigorous proto-circum-Antarctic flow of cold/cool waters, possibly through a West Antarctic seaway linking the southern Pacific and Atlantic Oceans, including detached northwards 'jetting' onto the New Zealand plateau where condensation and unconformity development was widespread in cool-water carbonate facies. Since this time, a broad tripartite division of antarctic, subantarctic, and subtropical waters has existed in the NZSSO, including possible development of a proto-SAF within the

Heavy metals pollution status in surface sediments (rivers and artifical lakes, Serbia)

Science.gov (United States)

Sakan, Sanja; Đorđević, Dragana

2017-04-01

Potentially hazardous trace elements, often in literature referred as "heavy metals", are deemed serious pollutants due to their toxicity, persistence and non-degradability in the environment. These elements play an important role in extent of water pollution and threaten the health of populations and ecosystems. As the sink of heavy metals, sediment beds adsorb metals in quantities that are many times higher than those found in the water column in the long-term polluted water environment. It is believed that most of the metal content, as much as 90% in aquatic sediments is bound to sediments. Metal contamination in these sediments could be directly affect the river water quality, resulting in potential consequences to the sensitive lowest levels of the food chain and ultimately to human health. The objective of this research was the evaluation of heavy metal contamination level in sediments of the most important rivers and artificial lakes in Serbia. The heavy metal enrichment in studied sediments was conducted by using: determination of total metal content, sequential extraction procedure for the fractionation of studied elements, quantification of the metal enrichment degree in the sediments by calculating geo-accumulation indices, determination of actual and potential element availability and application of BRAI index for the assessment of heavy metal bioavailability. The sediments were found to be contaminated by heavy metals to various extents, mostly with Cd, Cu, and Zn. The significant variation in heavy metal distribution among samples collected in this large region, encompassing all Serbian watersheds, suggests the selective contamination of sediments by heavy metals. Elevated concentrations of elements in most cases were detected in samples of river sediments, since artificial lake reservoirs are usually built in rural areas, where the less anthropogenic pollution. Rivers often flow through the towns and these water basins less or more loaded

Contamination by persistent toxic substances in surface sediment of urban rivers in Chaohu City, China.

Science.gov (United States)

Li, Feipeng; Zhang, Haiping; Meng, Xiangzhou; Chen, Ling; Yin, Daqiang

2012-01-01

The concentration and spatial distribution of persistent toxic substances (PTS) in the river sediment in Chaohu City, China were investigated. A total of nine surface sediments were collected and the selected PTS pollutants including six heavy metals and nineteen polybrominated diphenyl ethers (PBDEs) were analyzed. The mean heavy metal concentrations (in mg/kg, dry weight) ranged within 0.18-1.53 (Hg), 50.08-200.18 (Cu), 118.70-313.65 (Zn), 50.77-310.85 (Cr), 37.12-92.72 (Pb) and 13.29-197.24 (As), and Cu, Zn and As have been regarded as the main metal pollutants. The levels of PBDEs (1.2-12.1 ng/g) and BDE-209 (2.4-30.5 ng/g) were at the middle level of the global range. BDE-209 was the predominant congener (67.0%-85.7%), which agrees with the fact that technical deca-BDE mixtures are the dominant PBDE formulation in China. The relative high level of PTS pollutants in the western part of the city is probably owing to the intensive agricultural activities and lack of sewerage system there. The ecological risk assessment with the sediment quality guidelines (SOGs) indicates that the urban river sediments in the city have been heavily contaminated by heavy metals with probable ecotoxicological impacts on freshwater organisms and the main toxic pollutants are Hg and As. The results of current study imply that the city, and perhaps many other small cities in China as well, requires immediate pollution control measures with emphasis on not only conventional organic pollutants but also on PTS such as heavy metals and PBDEs.

New Zealand Police and Restorative Justice Philosophy

Science.gov (United States)

Winfree, L. Thomas, Jr.

2004-01-01

In New Zealand, selected sworn police officers called youth aid officers participate in discussions and deliberations concerning the actions required to restore the sense of community balance upset by the actions of juvenile offenders. The author explores a representative sample of all sworn police officers serving in the New Zealand Police,…

Visualization of soil structure and pore structure modifications by pioneering ground beetles (Cicindelidae) in surface sediments of an artificial catchment

Science.gov (United States)

Badorreck, Annika; Gerke, Horst H.; Weller, Ulrich; Vontobel, Peter

2010-05-01

An artificial catchment was constructed to study initial soil and ecosystem development. As a key process, the pore structure dynamics in the soil at the surface strongly influences erosion, infiltration, matter dynamics, and vegetation establishment. Little is known, however, about the first macropore formation in the very early stage. This presentation focuses on observations of soil pore geometry and its effect on water flow at the surface comparing samples from three sites in the catchment and in an adjacent "younger" site composed of comparable sediments. The surface soil was sampled in cylindrical plastic rings (10 cm³) down to 2 cm depth in three replicates each site and six where caves from pioneering ground-dwelling beetles Cicindelidae were found. The samples were scanned with micro-X-ray computed tomography (at UFZ-Halle, Germany) with a resolution of 0.084 mm. The infiltration dynamics were visualized with neutronradiography (at Paul-Scherer-Institute, Switzerland) on slab-type soil samples in 2D. The micro-tomographies exhibit formation of surface sealing whose thickness and intensity vary with silt and clay content. The CT images show several coarser- and finer-textured micro-layers at the sample surfaces that were formed as a consequence of repeated washing in of finer particles in underlying coarser sediment. In micro-depressions, the uppermost layers consist of sorted fine sand and silt due to wind erosion. Similar as for desert pavements, a vesicular pore structure developed in these sediments on top, but also scattered in fine sand- and silt-enriched micro-layers. The ground-dwelling activity of Cicindelidae beetles greatly modifies the soil structure through forming caves in the first centimetres of the soil. Older collapsed caves, which form isolated pores within mixed zones, were also found. The infiltration rates were severely affected both, by surface crusts and activity of ground-dwelling beetles. The observations demonstrate relatively

A geomorphic and tectonic model for the formation of the flight of Holocene marine terraces at Mahia Peninsula, New Zealand

Science.gov (United States)

Berryman, Kelvin; Clark, Kate; Cochran, Ursula; Beu, Alan; Irwin, Sarah

2018-04-01

At Table Cape, Mahia Peninsula, North Island, New Zealand, four marine terraces have been uplifted coseismically during the past 3500 years. Detailed facies assessment of the terrace coverbed sequence coupled with identification of modern analogues on the active shore platform were used to infer the process of marine terrace formation and to estimate the timing and amount of past uplift events (earthquakes). The modern platform can be subdivided into seven depositional zones: subtidal, outer platform, intertidal sand pockets, inner platform, high-tide, mid-storm, and storm beach. Terrace coverbeds were characterised from two trenches excavated across the full width of the uplifted terrace sequence. Off-lapping packages of high tidal, mid-storm, and storm beach sediments were most common. Outer platform sediments occurred only rarely near the base of some uplifted shore platforms. Overlying the marine sediments were near-horizontal terrestrial deposits of airfall tephra (on the two highest terraces), subsoil, topsoil, rare wedges of colluvial sediment (slopewash) shed from terrace risers, and an anomalous deposit possibly emplaced by a tsunami. Fifty-one radiocarbon ages, obtained from molluscs in the marine coverbeds, showed a general pattern of seaward-younging across the coastal plain and across each terrace and a less pronounced pattern of decreasing age upward in each coverbed sequence. The distinctive stepped geomorphology of the terraces, the facies and age structure of the terrace deposits and historical earthquake causation of similar terraces elsewhere in New Zealand provided the data to invoke an earthquake-driven model for terrace formation. Marine terrace development following an uplift event involved rapid cutting of a new intertidal shore platform and generally regressive deposition of high-tide to storm beach deposits. Following further uplift, the platform became a geomorphic terrace (above marine influence) and was then mantled by terrestrial

Age, distribution, and significance within a sediment budget, of in-channel depositional surfaces in the Normanby River, Queensland, Australia

Science.gov (United States)

Pietsch, T. J.; Brooks, A. P.; Spencer, J.; Olley, J. M.; Borombovits, D.

2015-06-01

We present the results of investigations into alluvial deposition in the catchment of the Normanby River, which flows into Princess Charlotte Bay (PCB) in the northern part of the Great Barrier Reef Lagoon. Our focus is on the fine fraction (bank attached bars or inset or inner floodplains, these more or less flat-lying surfaces within the macro-channel have hitherto received little attention in sediment budgeting models. We use high resolution LiDAR based mapping combined with optical dating of exposures cut into these in-channel deposits to compare their aggradation rates with those found in other depositional zones in the catchment, namely the floodplain and coastal plain. In total 59 single grain OSL dates were produced across 21 stratigraphic profiles at 14 sites distributed though the 24 226 km2 catchment. In-channel storage in these inset features is a significant component of the contemporary fine sediment budget (i.e. recent decades/last century), annually equivalent to more than 50% of the volume entering the channel network from hillslopes and subsoil sources. Therefore, at the very least, in-channel storage of fine material needs to be incorporated into sediment budgeting exercises. Furthermore, deposition within the channel has occurred in multiple locations coincident in time with accelerated sediment production following European settlement. Generally, this has occurred on a subset of the features we have examined here, namely linear bench features low in the channel. This suggests that accelerated aggradation on in-channel depositional surfaces has been in part a response to accelerated erosion within the catchment. The entire contribution of ~ 370 kilotonnes per annum of fine sediment estimated to have been produced by alluvial gully erosion over the last ~ 100 years can be accounted for by that stored as in-channel alluvium. These features therefore can play an important role in mitigating the impact on the receiving water of accelerated erosion.

Contaminant profiles for surface water, sediment, flora and fauna associated with the mangrove fringe along middle and lower eastern Tampa Bay.

Science.gov (United States)

Lewis, M A; Russell, M J

2015-06-15

Contaminant concentrations are reported for surface water, sediment, flora and fauna collected during 2010-2011 from the mangrove fringe along eastern Tampa Bay, Florida. Concentrations of trace metals, chlorinated pesticides, atrazine, total polycyclic aromatic hydrocarbons, and polychlorinated biphenyls were species-, chemical- and location-specific. Contaminants in sediments did not exceed proposed individual sediment quality guidelines. Most sediment quality assessment quotients were less than one indicating the likelihood of no inhibitory effect based on chemical measurements alone. Faunal species typically contained more contaminants than plant species; seagrass usually contained more chemicals than mangroves. Bioconcentration factors for marine angiosperms were usually less than 10 and ranged between 1 and 31. Mercury concentrations (ppm) in blue crabs and fish did not exceed the U.S. Environmental Protection Agency fish tissue criterion of 0.3 and the U.S. Food and Drug Administration action level of 1.0. In contrast, total mercury concentrations in faunal species often exceeded guideline values for wildlife consumers of aquatic biota. Published by Elsevier Ltd.

Effects of ghost shrimp on zinc and cadmium in sediments from Tampa Bay, FL

Science.gov (United States)

Klerks, P.L.; Felder, D.L.; Strasser, K.; Swarzenski, P.W.

2007-01-01

This study investigated the effects that ghost shrimp have on the distribution of metals in sediment. We measured levels of HNO3-extractable zinc and cadmium in surface sediment, in ghost shrimp burrow walls and in sediment ejected by the ghost shrimp from their burrows, at five sandy intertidal sites in Tampa Bay. Ghost shrimp densities and their rate of sediment ejection were also quantified, as were sediment organic content and silt + clay content. Densities of ghost shrimp (Sergio trilobata and Lepidophthalmus louisianensis) averaged 33/m2 at our sites, and they ejected sediment at an average rate of 28 g/burrow/day. Levels of both Zn and Cd were significantly higher in burrow walls than in surface sediments. Sediment ejected by the shrimp from their burrows had elevated levels of Zn (relative to surface sediments) at one of the sites. Sediment organic content and silt + clay content were higher in burrow-wall sediments than in ejected sediment, which in turn tended to have values above those of surface sediments. Differences in levels of HNO3-extractable Zn and Cd among sediment types may be a consequence of these sediments differing in other physiochemical characteristics, though the differences in metal levels remained statistically significant for some sites after correcting for differences in organic content and silt + clay content. We conclude that the presence of ghost shrimp burrows contributes to spatial heterogeneity of sedimentary metal levels, while the ghost shrimp bioturbation results in a significant flux of metals to the sediment surface and is expected to decrease heterogeneity of metal levels in sedimentary depth profiles.

Corporal punishment and child maltreatment in New Zealand.

Science.gov (United States)

Kelly, Patrick

2011-01-01

On 2 May, 2007, the New Zealand Parliament passed a law repealing Section 59 of the Crimes Act. In so doing, New Zealand became the first English-speaking nation in the world to make corporal punishment of a child illegal. The passage of this legislation was surrounded by intense and persistent public debate, and supporters of corporal punishment continue to advocate against the law change to the present day. In Sweden, where the first stage of similar repeal took place in 1957, it may be difficult for many to understand the strength of the public opposition to this change in New Zealand. This article will present a viewpoint on the evolution of the debate in New Zealand, review the wider context of child maltreatment and family violence in New Zealand and summarize a range of attempts to prevent or intervene effectively in the cycle of dysfunction. Child maltreatment and family violence are public health issues of great importance, and a stain on all societies. While corporal punishment may be a significant contributing factor, there is no single 'solution'. Change must occur on multiple levels (political, economic, cultural, familial and professional) before the tide will turn.

Asia-Born New Zealand-Educated Business Graduates' Transition to Work

Science.gov (United States)

Anderson, Vivienne; McGrath, Terry; Butcher, Andrew

2014-01-01

In 2008 the Asia New Zealand Foundation commissioned a three-year project examining Asia-born New Zealand-educated business graduates' study to work transitions. Data were collected through annual online surveys and in-depth interviews. Graduates were asked to discuss their post-study experiences, reflections on studying in New Zealand, and…

A high-resolution record of Holocene millennial-scale oscillations of surface water, foraminiferal paleoecology and sediment redox chemistry in the SE Brazilian margin

Science.gov (United States)

Dias, B. B.; Barbosa, C. F.; Albuquerque, A. L.; Piotrowski, A. M.

2014-12-01

Holocene millennial-scale oscillations and Bond Events (Bond et al. 1997) are well reported in the North Atlantic as consequence of fresh water input and weaking of the Atlantic Meridional Overturning Circulation (AMOC). It has been hypothesized that the effect of weaking of AMOC would lead to warming in the South Atlantic due to "heat piracy", causing surface waters to warm and a reorganization of surface circulation. There are few reconstructions of AMOC strength in the South Atlantic, and none with a high resolution Holocene record of changes of productivity and the biological pump. We reconstruct past changes in the surface water mass hydrography, productivity, and sediment redox changes in high-resolution in the core KCF10-01B, located 128 mbsl water depth off Cabo Frio, Brazil, a location where upwelling is strongly linked to surface ocean hydrography. We use Benthic Foraminiferal Accumulation Rate (BFAR) to reconstruct productivity, which reveals a 1.3kyr cyclicity during the mid- and late-Holocene. The geochemistry of trace and rare earth elements on foraminiferal Fe-Mn oxide coatings show changes in redox-sensitive elements indicating that during periods of high productivity there were more reducing conditions in sediment porewaters, producing a Ce anomaly and reduction and re-precipitation of Mn oxides. Bond events 1-7 were identified by a productivity increase along with reducing sediment conditions which was likely caused by Brazil Current displacement offshore allowing upwelling of the nutritive bottom water South Atlantic Central Waters (SACW) to the euphotic zone and a stronger local biological pump. In a global context, correlation with other records show that this occurred during weakened AMOC and southward displacement of the ITCZ. We conclude that Bond climatic events and millennial-scale variability of AMOC caused sea surface hydrographic changes off the Brazilian Margin leading to biological and geochemical changes recorded in coastal records

Contaminant profiles for surface water, sediment, flora and fauna associated with the mangrove fringe along middle and lower East Tampa Bay

Science.gov (United States)

Contaminant concentrations are reported for surface water, sediment, seagrass, mangroves, Florida Crown conch, blue crabs and fish collected during 2010-2011 from the mangrove fringe along eastern Tampa Bay. Concentrations of trace metals, chlorinated pesticides, atrazine, total ...

Variation of 231Pa, 230Th and 231Paex/230Thex in surface sediments of the Sabah-Sarawak coastal waters

International Nuclear Information System (INIS)

Zal U'yun Wan Mahmood; Zaharudin Ahmad; Abdul Kadir Ishak; Norfaizal Mohamed; Che Abd Rahim Mohamed

2011-01-01

Protactinium and thorium activities were measured in eight surface sediment taken in 2004 to determine effectiveness scavenging of 231 Pa at Sabah-Sarawak coastal waters. The result found that activity ratios of 231 Pa ex / 230 Th ex were ranged from 0.07 to 0.13 at all sampling stations. The high 231 Pa ex / 230 Th ex activity ratio than the production ratio of 0.093 in seawater at station SR 01, SR 02, SR 04, SB 02 and SB 05, revealed that 231 Pa is effectively removed from the water column into the sediment in comparison with 230 Th at those stations. Low percentage of 230 Th ex (90-95%) in comparison with 231 Pa ex at all stations can be attributed to less efficiently scavenged of 230 Th onto particles prior deposited at the marine sediment bed. (author)

Sediment carbon fate in phreatic karst (Part 1): Conceptual model development

Science.gov (United States)

Husic, A.; Fox, J.; Agouridis, C.; Currens, J.; Ford, W.; Taylor, C.

2017-06-01

Recent research has paid increased attention to quantifying the fate of carbon pools within fluvial networks, but few, if any, studies consider the fate of sediment organic carbon in fluviokarst systems despite that karst landscapes cover 12% of the earth's land surface. The authors develop a conceptual model of sediment carbon fate in karst terrain with specific emphasis upon phreatic karst conduits, i.e., those located below the groundwater table that have the potential to trap surface-derived sediment and turnover carbon. To assist with their conceptual model development, the authors study a phreatic system and apply a mixture of methods traditional and novel to karst studies, including electrical resistivity imaging, well drilling, instantaneous velocimetry, dye tracing, stage recording, discrete and continuous sediment and water quality sampling, and elemental and stable carbon isotope fingerprinting. Results show that the sediment transport carrying capacity of the phreatic karst water is orders of magnitude less than surface streams during storm-activated periods promoting deposition of fine sediments in the phreatic karst. However, the sediment transport carrying capacity is sustained long after the hydrologic event has ended leading to sediment resuspension and prolonged transport. The surficial fine grained laminae occurs in the subsurface karst system; but unlike surface streams, the light-limited conditions of the subsurface karst promotes constant heterotrophy leading to carbon turnover. The coupling of the hydrological processes leads to a conceptual model that frames phreatic karst as a biologically active conveyor of sediment carbon that recharges degraded organic carbon back to surface streams. For example, fluvial sediment is estimated to lose 30% of its organic carbon by mass during a one year temporary residence within the phreatic karst. It is recommended that scientists consider karst pathways when attempting to estimate organic matter stocks

Storm-driven sediment transport in Massachusetts Bay

Science.gov (United States)

Warner, J.C.; Butman, B.; Dalyander, P.S.

2008-01-01

Massachusetts Bay is a semi-enclosed embayment in the western Gulf of Maine about 50 km wide and 100 km long. Bottom sediment resuspension is controlled predominately by storm-induced surface waves and transport by the tidal- and wind-driven circulation. Because the Bay is open to the northeast, winds from the northeast ('Northeasters') generate the largest surface waves and are thus the most effective in resuspending sediments. The three-dimensional oceanographic circulation model Regional Ocean Modeling System (ROMS) is used to explore the resuspension, transport, and deposition of sediment caused by Northeasters. The model transports multiple sediment classes and tracks the evolution of a multilevel sediment bed. The surficial sediment characteristics of the bed are coupled to one of several bottom-boundary layer modules that calculate enhanced bottom roughness due to wave-current interaction. The wave field is calculated from the model Simulating WAves Nearshore (SWAN). Two idealized simulations were carried out to explore the effects of Northeasters on the transport and fate of sediments. In one simulation, an initially spatially uniform bed of mixed sediments exposed to a series of Northeasters evolved to a pattern similar to the existing surficial sediment distribution. A second set of simulations explored sediment-transport pathways caused by storms with winds from the northeast quadrant by simulating release of sediment at selected locations. Storms with winds from the north cause transport southward along the western shore of Massachusetts Bay, while storms with winds from the east and southeast drive northerly nearshore flow. The simulations show that Northeasters can effectively transport sediments from Boston Harbor and the area offshore of the harbor to the southeast into Cape Cod Bay and offshore into Stellwagen Basin. This transport pattern is consistent with Boston Harbor as the source of silver found in the surficial sediments of Cape Cod Bay and

Hyperomma of New Zealand (Coleoptera: Staphylinidae: Paederinae)

DEFF Research Database (Denmark)

Schomann, Andrea Maria

In this project a classical taxonomical revision of the New Zealand species of Hyperomma was conducted, as well as a broader molecular phylogenetic study revolving around this flightless genus, which occurs in Australia and New Zealand only. Seventeen new species were described, two new synonymies....... Additionally, the extinct Cretaceous staphylinid genus Apticax was described connected with a short review on fossil Paederinae and closely related fossils....... found, 8 known species re-described after contemporary standards, and a species inventory with keys to those 25 species and the paederine genera occurring in New Zealand was produced. The genus was placed in the phylogenetic context of its subfamily, Paederinae, for which a robust phylogenetic...

A Holocene pollen and sediment record of Whangape Harbour, far northern New Zealand

International Nuclear Information System (INIS)

Horrocks, M.; Nichol, S.L.; Gregory, M.R.; Creese, R.; Augustinus, P.C.

2001-01-01

The sediment record of Whangape Harbour shows that there were significant fluctuations in depositional energy in the harbour during the period from c. >8000 cal. yr BP to some time within the last millenium, and that fluvial influences increased as the harbour infilled. The pollen record (highly discontinuous) from Whangape Harbour indicates that conifer-hardwood forest covered the hills surrounding the harbour during this period. The main canopy conifers were Dacrydium and Prumnopitys taxifolia, with some Libocedrus, Dacrycarpus, and Phyllocladus. Agathis was also present. Common canopy hardwoods were Metrosideros and, in the latter part of the period, Elaeocarpus. Ascarina and Cyathea were abundant in the sub-canopy. Leptospermum grew on disturbed areas fringing the estuary. Marsh or swamp environments probably never developed on a large scale in the harbour. Avicennia, extremely under-represented in the pollen flora, has been present on tidal flats in the harbour since at least c. 2500 cal. yr BP. Large-scale anthropogenic deforestation by burning commenced in the Whangape catchment some time during or since 700-430 cal. yr BP. The associated increase in erosion rates in the catchment resulted in a change towards a sandier sediment regime in the harbour which has continued to the present day. Weinmannia and Ackama, previously rare in the catchment, expanded in remaining forest. (author). 39 refs., 3 figs., 1 tab

Determination of DDT and metabolites in surface water and sediment using LLE, SPE, ACE and SE.

Science.gov (United States)

Sibali, Linda L; Okonkwo, Jonathan O; Zvinowanda, Caliphs

2009-12-01

Surface water and sediment samples collected from Jukskei River in South Africa, were subjected to different extraction techniques, liquid-liquid (LLE), solid-phase extraction (SPE), activated carbon extraction (ACE) and soxhlet extraction (SE) for sediment. The samples were extracted with dichloromethane, cleaned in a silica gel column and the extracts quantified using a Varian 3800 GC-ECD. The percentage recovery test for 2,4'DDT, DDE and DDD and 4,4'DDT, DDE and DDD in water ranged from 80%-96% and 76%-95% (LLE); 56%-76% and 56%-70% (SPE) and 75%-84% (ACE), respectively; while that recoveries for sediment samples varied from 65%-95% for 2,4'DDT, DDE and DDD and 80%-91% for 4,4'DDT, DDE and DDD. The high recoveries exhibited by ACE compared very well with LLE and SE. This was not the case with SPE which exhibited the lowest value of recoveries for both 2,4 and 4,4'DDD, DDE and DDT standard samples. The mean concentrations of DDT and metabolites ranged from nd-1.10 μg/L, nd-0.80 μg/L, nd-1.21 μg/L and 1.92 μg/L for LLE, SPE, ACE and SE, respectively. The total DDT (2,4' and 4,4'-DDT) in water and sediment samples ranged from 1.20-3.25 μg/L and 1.82-5.24 μg/L, respectively. The low concentrations of the DDT metabolites obtained in the present study may suggest a recent contamination of the river by DDT.

Quantifying the contributions of sediment, sediment-P and fertiliser-P from forested, cultivated and pasture areas at the landuse and catchment scale using fallout radionuclides and geochemistry

International Nuclear Information System (INIS)

Wallbrink, P.J.; Martin, C.E.; Wilson, C.J.

2003-01-01

In this paper we use a combination of fallout nuclides and geochemistry to determine the contributions of sediment and sediment bound phosphorus (sed-P) from the major diffuse sources in the Bundella Creek catchment (8700 ha), NSW, Australia. Sources include surface erosion from cultivated, pasture and steep forested land as well as subsoil erosion from channels and gullies. We determine these contributions to the <10 μm fraction of deposited sediments. Concentrations of P were higher in the surface soils of each landuse than the underlying subsoils, and erosion from these contributed more to offsite sediment-P (∼60%) than did subsoil erosion at the individual landuse scale. At the catchment outlet, the amount of surface sediment eroded from cultivated lands was a factor of ∼84 higher than from pastures; the steep forested lands contributed ∼9 times more than pastures. Sed-P eroded from cultivated land was ∼42 times higher than from pasturelands; the forests were ∼8 times greater than from pastures. At the catchment outlet the largest contribution of sediment (∼70%) and sed-P (∼62%) was from subsoil erosion of gullies and channels within and between the different landuse areas. There was little contribution of sediment or sed-P at the catchment scale from surface erosion of pastures. Concentrations of P were highest in 'storm event' suspended sediment samples taken from the pasture and cultivated areas without gullies. In a suite of samples selected for their high P contents, fertiliser P was detected in two storm event suspended sediment samples and one deposited sediment sample, using the ratio of Nd/P. This suggests fertiliser P may be transported-off land surfaces with sediments and contribute to offsite sediment-P concentrations in some situations. However, the fertiliser contributions were episodic and variable; and probably influenced by particle size selectivity as well as timing of fertiliser application with respect to size and occurrence

Ultrasonographic Evaluation of the Urinary System in New Zealand White Rabbit and Tolai Hare

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Abdolvahed Moarabi

2011-06-01

Full Text Available Ultrasonographic examination of urinary system (kidney and urinary bladder was conducted in New Zealand white rabbit [NZwr] and Tolai hare (Lepus tolai. Ultrasound images of the kidney and urinary bladder were evaluated on fifteen healthy rabbits of New Zealand white rabbit and another fifteen Tolai hares. The healthy rabbits were 8-12 months old (mean = 9.3 months, of both sexes and weighed between 1.1-1.7 kg (mean = 1.250 kg. All examinations were performed while the rabbits were in dorsal recumbancy. The kidneys were examined from fossa by the use of an 8 MHz linear real-time scanner. This study revealed the following measurements normal rabbit kidneys: 27.80-35.70 mm and 16.90-22.40 mm in length and width in New Zealand white rabbit, respectively. The length and width were 26.67-34.50 and 15.82-20.60 mm, in Tolai hare, respectively. Bladder wall thickness varies from 1.70-2.50 mm (in New Zealand white rabbit to 1.80-2.60 mm (in Tolai hare. Statistical analysis showed that the gender did not have effect on length, width and weight (P > 0.05, but the type of the animal, had significant effect on the cortex and surface (P < 0.05. In the present study, the renal cortex was uniform in echogenicity, hyperechoic to the renal medulla, hypoechoic to the spleen, and isoechoic to the hepatic parenchyma.

Spatial distribution and ecological risk assessment of heavy metals in coastal surface sediments in the Hebei Province offshore area, Bohai Sea, China.

Science.gov (United States)

Ding, Xigui; Ye, Siyuan; Yuan, Hongming; Krauss, Ken W

2018-06-01

Seven hundred and nine surface sediment samples, along with deeper sediment samples, were collected from Hebei Province along the coastal section of the Bohai Sea, China, and analyzed for grain size, concentrations of organic carbon (Corg) and heavy metals (Cu, Pb, Zn, Cr, Cd, As, and Hg). Results indicated that the average concentrations in the sediments were 16.1 mg/kg (Cu), 19.4 mg/kg (Pb), 50 mg/kg (Zn), 48.8 mg/kg (Cr), 0.1 mg/kg (Cd), 8.4 mg/kg (As), and 20.3 μg/kg (Hg). These concentrations generally met the China Marine Sediment Quality criteria. However, both pollution assessments indicated moderate to strong Cd and Hg contamination in the study area. The potential ecological risk index suggested that the combined ecological risk of the seven studied metals may be low, but that 24.5% of the sites, where sediments were finer and higher in Corg concentration, had high ecological risk in Hg and Cd pollution. Copyright © 2018 Elsevier Ltd. All rights reserved.

Abiotic Degradation and Toxicological Impacts of Pharmaceuticals and Personal Care Products (PPCPs) in Surface Waters: Roles of Mineral Sediments and Solar Radiation

Science.gov (United States)

Rubasinghege, G. R. S.; Rijal, H.; Maldonado-Torres, S.; Gurung, R.; Rogelj, S.; Piyasena, M.

2017-12-01

The growing medical and personal needs of human populations have escalated release of pharmaceuticals and personal care products into surface waters. This work investigates abiotic degradation pathways of a particular PPCP, ibuprofen, in the presence of a major mineral component of sedimentation (kaolinite clay), as well as the health effects of the primary compound and its degradation products. Results from these studies showed that the rate and extent of ibuprofen degradation is greatly influenced by the presence of sedimentation particles and solar radiation. In the absence of solar radiation, the dominant reaction mechanism was observed to be the adsorption of ibuprofen onto sedimentation particle surface where surface silanol groups play a key role. In contrast, under solar radiation and in the presence of clay particles, ibuprofen breaks down to several fractions. The decay rates were at least 6-fold higher for irradiated samples compared to those of dark conditions. Toxicity of primary ibuprofen and its secondary residues were tested on three microorganisms: Bacillus megaterium, Pseudoaltermonas atlantica; and algae from the Chlorella genus. The results from the biological assays show that primary PPCP is more toxic than the mixture of secondary products. Overall, however, biological assays carried out using only 4-acetylbenzoic acid, the most abundant secondary product, show a higher toxic effect on algae compared to its parent compound.

Surface-sediment and hermit-crab contamination by butyltins in southeastern Atlantic estuaries after ban of TBT-based antifouling paints.

Science.gov (United States)

Sant'Anna, B S; Santos, D M; Marchi, M R R; Zara, F J; Turra, A

2014-05-01

Butyltin (BT) contamination was evaluated in hermit crabs from 25 estuaries and in sediments from 13 of these estuaries along about 2,000 km of the Brazilian coast. BT contamination in hermit crabs ranged from 2.22 to 1,746 ng Sn g(-1) of DBT and 1.32 to 318 ng Sn g(-1) of TBT. In sediment samples, the concentration also varied widely, from 25 to 1,304 ng Sn g(-1) of MBT, from 7 to 158 ng Sn g(-1) of DBT, and from 8 to 565 ng Sn g(-1) of TBT. BTs are still being found in surface sediments and biota of the estuaries after the international and Brazilian bans, showing heterogeneous distribution among and within estuaries. Although hermit crabs were previously tested as an indicator of recent BT contamination, the results indicate the presence of contamination, probably from resuspension of BTs from deeper water of the estuary.

Phreatomagmatic eruptions through unconsolidated coastal plain sequences, Maungataketake, Auckland Volcanic Field (New Zealand)

Science.gov (United States)

Agustín-Flores, Javier; Németh, Károly; Cronin, Shane J.; Lindsay, Jan M.; Kereszturi, Gábor; Brand, Brittany D.; Smith, Ian E. M.

2014-04-01

Maungataketake is a monogenetic basaltic volcano formed at ~ 85-89 ka in the southern part of the Auckland Volcanic Field (AVF), New Zealand. It comprises a basal 1100-m diameter tuff ring, with a central scoria/spatter cone and lava flows. The tuff ring was formed under hydrogeological and geographic conditions very similar to the present. The tuff records numerous density stratified, wet base surges that radiated outward up to 1 km, decelerating rapidly and becoming less turbulent with distance. The pyroclastic units dominantly comprise fine-grained expelled grains from various sedimentary deposits beneath the volcano mixed with a minor component of juvenile pyroclasts (~ 35 vol.%). Subtle lateral changes relate to deceleration with distance and vertical transformations are minor, pointing to stable explosion depths and conditions, with gradual transitions between units and no evidence for eruptive pauses. This volcano formed within and on ~ 60 m-thick Plio/Pleistocene, poorly consolidated, highly permeable shelly sands and silts (Kaawa Formation) capped by near-impermeable, water-saturated muds (Tauranga Group). These sediments rest on moderately consolidated Miocene-aged permeable turbiditic sandstones and siltstones (Waitemata Group). Magma-water fuelled thermohydraulic explosions remained in the shallow sedimentary layers, excavating fine-grained sediments without brittle fragmentation required. On the whole, the resulting cool, wet pyroclastic density currents were of low energy. The unconsolidated shallow sediments deformed to accommodate rapidly rising magma, leading to development of complex sill-like bodies and a range of magma-water contact conditions at any time. The weak saturated sediments were also readily liquefied to provide an enduring supply of water and fine sediment to the explosion loci. Changes in magma flux and/or subsequent stabilisation of the conduit area by a lava ring-barrier led to ensuing Strombolian and fire-fountaining eruption

Heavy Metal Concentration in the Surface Sediment of Tanjung Lumpur Mangrove Forest, Kuantan, Malaysia

International Nuclear Information System (INIS)

Kamaruzzaman Yunus; Shahbudin Saad; Ahmed Jalal Khan Chowdhury; Nurulnadia Mohd Yusuf; Noor Azhar Mohd Shazili; Chuan, O.M.; Bidai, J.

2011-01-01

Surface sediment samples from 2 transect (20 sampling points) of Tanjung Lumpur mangrove forest were analyzed for the concentrations of Pb, Cu, Co and Mn. In this study, the average concentrations of Pb, Cu, Co and Mn were 44.41 μg/g dry weight, 32.79 μg/g dry weight, 5.79 μg/g dry weight and 117.73 μg/g dry weight, respectively. The calculated enrichment factors (EF) obtained for Co and Mn can be considered to have the terigeneous in sources while Pb and Cu are considered to have anthropogenic input. (author)

Heavy metal pollution characteristics of surface sediments in different aquatic ecosystems in eastern China: a comprehensive understanding.

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Wenzhong Tang

Full Text Available Aquatic ecosystems in eastern China are suffering threats from heavy metal pollution because of rapid economic development and urbanization. Heavy metals in surface sediments were determined in five different aquatic ecosystems (river, reservoir, estuary, lake, and wetland ecosystems. The average Cd, Cr, Cu, Ni, Pb, and Zn concentrations were 0.716, 118, 37.3, 32.7, 56.6, and 204 mg/kg, respectively, and the higher concentrations were mainly found in sediment samples from river ecosystems. Cd was the most anthropogenically enriched pollutant, followed by Zn and Pb, indicated by enrichment factors >1.5. According to consensus-based sediment quality guidelines, potential ecological risk indices, and risk assessment codes, all five types of aquatic ecosystems were found to be polluted with heavy metals, and the most polluted ecosystems were mainly rivers. Cd was the most serious pollutant in all five aquatic ecosystems, and it was mainly found in the exchangeable fraction (about 30% of the total Cd concentration, on average. The results indicate that heavy metal contamination, especially of Cd, in aquatic ecosystems in eastern China should be taken into account in the development of management strategies for protecting the aquatic environment.

U- and Th-series nuclides in settling particles: implications to sediment transport through surface waters and interior ocean

International Nuclear Information System (INIS)

Sarin, M.M.

2012-01-01

The Bay of Bengal is a unique ocean basin receiving large quantities of fresh water and sediment supply from several rivers draining the Indian subcontinent. The annual flux of suspended sediments discharged into the Bay of Bengal is one billion tons, about one-tenth of the global sediment discharge into the ocean. The water and sediment discharge to the Bay, show significant seasonal variation, with maximum transport coinciding with the SW-monsoon (July-September). Earlier studies on the distribution of clay minerals in sediments have led to the suggestion that the sediments of the western Bengal Fan are mainly derived from the Peninsular rivers, whereas rest of the Fan sediments is influenced by the Himalayan rivers. Settling fluxes of particulate matter through the water column of the Bay of Bengal show seasonal trends resulting from monsoon enhanced sediment supply via rivers and biological processes in the water column. It is, thus, important to understand the influence of the seasonally varying particle fluxes on the solute-particle interactions and chemical scavenging processes in the surface and deep waters of the Bay of Bengal. In this context, measurements of U- and Th-series nuclides in the settling particles are most relevant. The radionuclide fluxes ( 230 Th, 228 Th and 210 Pb) in the settling particles provide insight into the role of their removal by vertical particle flux and/or lateral transport (removal at the ocean boundaries). A study carried out in the Northern Bay of Bengal documents that the authigenic flux of 230 Th, as measured in sediment trap samples from deep waters, is balanced by its production in the overhead water column. The sediment mass flux, Al and 228 Th fluxes are similar in the settling particles through shallow and deep waters, suggesting predominant removal by vertical particle flux in the North Bay of Bengal. In the Central Bay, particulate mass, Al and 228 Th fluxes are higher in the trap material from deep waters relative

Energy scenarios for New Zealand

Energy Technology Data Exchange (ETDEWEB)

Harris, G. S.; Ellis, M. J.; Scott, G. C.; Wood, J. R.

1977-10-15

Three energy scenarios have been formulated for New Zealand. They concentrate on those aspects of society which have a direct bearing on energy, emphasizing three important issues: major shifts in society's values in relation to material wealth, pollution, and resources. The scenarios make assumptions that certain overall social conditions would prevail so that all decisions of government, the private sector, and individuals would be governed by the requirement to conform to the scenario theme in a way not possible under existing social and political conditions. The 3 scenarios are known as Continuation, Low New Zealand Pollution, and Limited Growth.

Hydrochemistry of New Zealand's aquifers

International Nuclear Information System (INIS)

Rosen, M.R.

2001-01-01

Groundwater chemistry on a national scale has never been studied in New Zealand apart from a few studies on nitrate concentrations and pesticides. These studies are covered in Chapter 8 of this book. However general studies of groundwater chemistry, groundwater-rock interaction and regional characteristics of water quality have not been previously addressed in much detail. This is partly because New Zealand aquifers are relatively small on a world scale and are geologically and tectonically diverse (see Chapter 3). But New Zealand has also recently lacked a centralised agency responsible for groundwater quality, and therefore, no national assessments have been undertaken. In recent years, the Institute of Geological and Nuclear Sciences has managed a programme of collecting and analysing the groundwater chemistry of key New Zealand aquifers. This programme is called the National Groundwater Monitoring Programme (NGMP) and is funded by the New Zealand Public Good Science Fund. The programme started in 1990 using only 22 wells, with four regional authorities of the country participating. The NGMP now includes all 15 regional and unitary authorities that use groundwater and over 100 monitoring sites. The NGMP is considered a nationally significant database by the New Zealand Foundation for Research Science and Technology. The NGMP allows a national comparison of aquifer chemistries because the samples are all analysed at one laboratory in a consistent manner and undergo stringent quality control checks. Poor quality analyses are thus minimised. In addition, samples are collected quarterly so that long-term seasonal trends in water quality can be analysed, and the effects of changes in land use and the vulnerability of aquifers to contaminant leaching can be assessed. This chapter summarises the water quality data collected for the NGMP over the past 10 years. Some records are much shorter than others, but most are greater than three years. Additional information is

137Cs in northern Adriatic sediments

International Nuclear Information System (INIS)

Barisic, D.; Lulic, S.; Vdovic, N.; Vertacnik, A.; Juracic, M.

1996-01-01

The activity of 137 Cs in shallow northern Adriatic sediments was obtained on the basis of measurement results from 25 sediment box cores, sampled during the Adriatic Scientific COoperation Program (ASCOP) 16 cruise in the summer 1990. 137 Cs was determined in surface sediments (0-3 cm) and 12-15 cm-deep sediment. It was found that the lowest caesium concentrations correspond to sands, which are spread along the Croatian coast. Parallel to the Italian coast, 137 Cs concentrations in pelites are the highest. It seems that the influence of Po River is significant for 137 Cs activities in recent marine sediments along Italian coast south of Po River delta. Significantly higher 137 Cs activities in 0-3 cm sediment layer can be attributed to the deposition caused by Chernobyl accident. (author)

Immobilization and Natural Attenuation of Arsenic in Surface and Subsurface Sediments

Science.gov (United States)

O'Day, P. A.; Illera, V.; Choi, S.; Vlassopoulos, D.

2008-12-01

Understanding of molecular-scale biogeochemical processes that control the mobilization and distribution of As and other oxyanions can be used to develop remediation strategies that take advantage of natural geochemical and hydrologic gradients. Arsenic and other toxic oxyanions can be mobilized at low bulk sediment concentrations (ppm range) and thus, treatment technologies are challenged by low contaminant concentrations, widespread sources, variable pH and Eh conditions, and inaccessibility of subsurface environments. In situ chemical amendments to soils and sediments can be used to decrease the mobility and bioaccessibility of As and oxyanions through sorption to, or precipitation with, stabilizing phases. At a site near San Francisco Bay (CA, USA), treatment of As-contaminated soils with sulfate-cement amendments has effectively immobilized As. Laboratory experiments with field soils and spectroscopic characterizations showed that in high pH cement-type treatments, As is precipitated in ettringite-type phases (Ca-Al sulfates), whereas in low pH ferrous sulfate treatments, As is associated with an iron-arsenate phase (angellelite). The presence of As-associated ettringite-type phases in field sediments amended more than a decade ago indicates long-term stability of these neophases, as long as environmental conditions are relatively constant. At sites of subsurface contamination, monitored natural attenuation (MNA) as a remediation approach for As is gaining interest and acceptance. Successful implementation of MNA requires a mechanistic understanding of As sequestration processes and of the subsurface conditions that may enhance or reduce long-term effectiveness. At a former military site (MA, USA), naturally occurring As was mobilized from sediments as a result of reducing conditions from addition of organic carbon as a biodegradation treatment of chlorinated solvents. Elevated As concentrations were not detected further than about 30 m downgradient of the

Effects of land disposal of municipal sewage sludge on soil, streambed sediment, and ground- and surface-water quality at a site near Denver, Colorado

Energy Technology Data Exchange (ETDEWEB)

Gaggiani, N.G.

1991-01-01

The report describes the effects of burial and land application of municipal sewage sludge on soil and streambed sediment and water quality in the underlying aquifers and surface water within and around the Lowry sewage-sludge-disposal area. The existing ground-water observation-well network at the disposal area was expanded for the study. Surface-water-sampling sites were selected so that runoff could be sampled from intense rainstorms or snowmelt. The sampling frequency for ground-water and surface-water runoff was changed from yearly to quarterly, and soil samples were collected. Four years of data were collected from 1984 to 1987 during the expanded monitoring program at the Lowry sewage-sludge-disposal area. These data, in addition to the data collected by the U.S. Geological Survey from 1981 to 1983, were used to determine effects of sewage-sludge-disposal on soil and streambed sediment and surface- and ground-water quality at the disposal area.

Clay mineralogy of surface sediments as a tool for deciphering river contributions to the Cariaco Basin (Venezuela)

Science.gov (United States)

Bout-Roumazeilles, V.; Riboulleau, A.; du Châtelet, E. Armynot; Lorenzoni, L.; Tribovillard, N.; Murray, R. W.; Müller-Karger, F.; Astor, Y. M.

2013-02-01

The mineralogical composition of 95 surface sediment samples from the Cariaco Basin continental shelf and Orinoco delta was investigated in order to constrain the clay-mineral main provenance and distribution within the Cariaco Basin. The spatial variability of the data set was studied using a geo-statistical approach that allows drawing representative clay-mineral distribution maps. These maps are used to identify present-day dominant sources for each clay-mineral species in agreement with the geological characteristics of the main river watersheds emptying into the basin. This approach allows (1) identifying the most distinctive clay-mineral species/ratios that determine particle provenance, (2) evaluating the respective contribution of local rivers, and (3) confirming the minimal present-day influence of the Orinoco plume on the Cariaco Basin sedimentation. The Tuy, Unare, and Neveri Rivers are the main sources of clay particles to the Cariaco Basin sedimentation. At present, the Tuy River is the main contributor of illite to the western part of the southern Cariaco Basin continental shelf. The Unare River plume, carrying smectite and kaolinite, has a wide westward propagation, whereas the Neveri River contribution is less extended, providing kaolinite and illite toward the eastern Cariaco Basin. The Manzanares, Araya, Tortuga, and Margarita areas are secondary sources of local influence. These insights shed light on the origin of present-day terrigenous sediments of the Cariaco Basin and help to propose alternative explanations for the temporal variability of clay mineralogy observed in previously published studies.

Iron geochemistry and organic carbon preservation by iron (oxyhydr)oxides in surface sediments of the East China Sea and the south Yellow Sea

Science.gov (United States)

Ma, Wei-Wei; Zhu, Mao-Xu; Yang, Gui-Peng; Li, Tie

2018-02-01

In marine sediments factors that influence iron (Fe) geochemistry and its interactions with other elements are diverse and remain poorly understood. Here we comparatively study Fe speciation and reactive Fe-bound organic carbon (Fe-OC) in surface sediments of the East China Sea (ECS) and the south Yellow Sea (SYS). The objectives are to better understand the potential impacts of geochemically distinct sediment sources and depositional/diagenetic settings on Fe geochemistry and OC preservation by Fe (hydr)oxides in sediments of the two extensive shelf seas around the world. Contents of carbonate- and acid-volatile-sulfide (AVS)-associated Fe(II) (FeAVS + carb) and magnetite (Femag) in the ECS sediments are about 5 and 9 times higher, respectively, than in the SYS. This could be ascribed to the ferruginous conditions of the ECS sediments that favor the formation/accumulation of Fecarb and Femag, a unique feature of marine unsteady depositional regimes. Much lower total Fe(II) contents in the SYS than in the ECS suggest that lower availability of highly reactive Fe (FeHR) and/or weak Fe reduction is a factor limiting Fe(II) formation and accumulation in the SYS sediments. The ratio of FeHR to total Fe is, on average, markedly higher (2.4 times) in the ECS sediments than in the SYS, which may be a combined result of several factors relevant to different sediment sources and depositional/diagenetic settings. In comparison with many other marine sediments, the percent fractions (fFe-OC) of Fe-OC to total organic carbon (TOC) in the ECS and the SYS are low, which can be ascribed to surface adsorption of OC rather than coprecipitation or organic complexation as the dominant binding mechanisms. Based on the fFe-OC in this study, total Fe-OC estimated for global continental shelves is equivalent to 38% of the atmospheric CO2 pool, which indicates the important role of sorptive stabilization of Fe-OC in continental shelf sediments for buffering CO2 release to the atmosphere

Pacemaker Use in New Zealand - Data From the New Zealand Implanted Cardiac Device Registry (ANZACS-QI 15).

Science.gov (United States)

Larsen, P D; Kerr, A J; Hood, M; Harding, S A; Hooks, D; Heaven, D; Lever, N A; Sinclair, S; Boddington, D; Tang, E W; Swampillai, J; Stiles, M K

2017-03-01

The New Zealand Cardiac Implanted Device Registry (Device) has recently been developed under the auspices of the New Zealand Branch of the Cardiac Society of Australia and New Zealand. This study describes the initial Device registry cohort of patients receiving a new pacemaker, their indications for pacing and their perioperative complications. The Device Registry was used to audit patients receiving a first pacemaker between 1 st January 2014 and 1 st June 2015. We examined 1611 patients undergoing first pacemaker implantation. Patients were predominantly male (59%), and had a median age of 70 years. The most common symptom for pacemaker implantation was syncope (39%), followed by dizziness (30%) and dyspnoea (12%). The most common aetiology for a pacemaker was a conduction tissue disorder (35%), followed by sinus node dysfunction (22%). Atrioventricular (AV) block was the most common ECG abnormality, present in 44%. Dual chamber pacemakers were most common (62%), followed by single chamber ventricular pacemakers (34%), and cardiac resynchronisation therapy - pacemakers (CRT-P) (2%). Complications within 24hours of the implant procedure were reported in 64 patients (3.9%), none of which were fatal. The most common complication was the need for reoperation to manipulate a lead, occurring in 23 patients (1.4%). This is the first description of data entered into the Device registry. Patients receiving a pacemaker were younger than in European registries, and there was a low use of CRT-P devices compared to international rates. Complications rates were low and compare favourably to available international data. Copyright © 2016 Australian and New Zealand Society of Cardiac and Thoracic Surgeons (ANZSCTS) and the Cardiac Society of Australia and New Zealand (CSANZ). Published by Elsevier B.V. All rights reserved.

Occurrence of polycyclic aromatic hydrocarbons in surface sediments of a highly urbanized river system with special reference to energy consumption patterns

International Nuclear Information System (INIS)

Zhang Kai; Wang Jizhong; Liang Bo; Zeng, Eddy Y.

2011-01-01

Sediment samples collected from downstream of the Dongjiang River, a highly urbanized river network within the Pearl River Delta of South China, were analyzed for 28 polycyclic aromatic hydrocarbons (PAHs). Total concentrations of 28 PAHs, 16 priority PAHs designated by the United States Environmental Protection Agency (USEPA) and the seven carcinogenic PAHs classified by the USEPA ranged from 480 to 4600, 100 to 3400 and 10 to 1700 ng/g dry weight, respectively. Principal component analysis-based stepwise multivariate linear regression showed that sediment PAHs were predominantly derived from coal combustion, refined fossil fuel combustion and oil spills, accounting for 37%, 32% and 23%, respectively, of the total loading. The levels of sediment PAHs remained steady from 2002 to 2008, during which fossil fuel consumption had doubled, probably reflecting efforts to control PAH emissions from fossil fuel combustion. Finally, use of natural gas and liquefied petroleum gas in automobiles should be encouraged to improve environmental quality. - Highlights: → PAHs in sediment showed similar input sources as those in air particles. → Combustion of fossil fuel is the predominant source for sediment PAHs. → Local efforts to control PAHs emissions from fossil fuel combustion were effective. → Promotion of natural gas and liquefied petroleum gas can reduce emissions of PAHs. - Occurrence of PAHs in surface sediments from a highly urbanized river system is assessed in relation to energy consumption patterns.

Antagonistic Effects of Ocean Acidification and Rising Sea Surface Temperature on the Dissolution of Coral Reef Carbonate Sediments

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Daniel Trnovsky

2016-11-01

Full Text Available Increasing atmospheric CO2 is raising sea surface temperature (SST and increasing seawater CO2 concentrations, resulting in a lower oceanic pH (ocean acidification; OA, which is expected to reduce the accretion of coral reef ecosystems. Although sediments comprise most of the calcium carbonate (CaCO3 within coral reefs, no in situ studies have looked at the combined effects of increased SST and OA on the dissolution of coral reef CaCO3 sediments. In situ benthic chamber incubations were used to measure dissolution rates in permeable CaCO3 sands under future OA and SST scenarios in a coral reef lagoon on Australia’s Great Barrier Reef (Heron Island. End of century (2100 simulations (temperature +2.7°C and pH -0.3 shifted carbonate sediments from net precipitating to net dissolving. Warming increased the rate of benthic respiration (R by 29% per 1°C and lowered the ratio of productivity to respiration (P/R; ΔP/R = -0.23, which increased the rate of CaCO3 sediment dissolution (average net increase of 18.9 mmol CaCO3 m-2 d-1 for business as usual scenarios. This is most likely due to the influence of warming on benthic P/R which, in turn, was an important control on sediment dissolution through the respiratory production of CO2. The effect of increasing CO2 on CaCO3 sediment dissolution (average net increase of 6.5 mmol CaCO3 m-2 d-1 for business as usual scenarios was significantly less than the effect of warming. However, the combined effect of increasing both SST and pCO2 on CaCO3 sediment dissolution was non-additive (average net increase of 5.6 mmol CaCO3 m-2 d-1 due to the different responses of the benthic community. This study highlights that benthic biogeochemical processes such as metabolism and associated CaCO3 sediment dissolution respond rapidly to changes in SST and OA, and that the response to multiple environmental changes are not necessarily additive.

Synopsis of oxygen isotopes in geothermal solids and fluids of New Zealand

International Nuclear Information System (INIS)

Blattner, P.

1982-01-01

Geothermal minerals serve as downhole probes of oxygen isotope compositions and thus of parameters of geothermal hydrology. ''Deep'' wells (2500 m) in New Zealand show no sign of Δ 18 O values ''bottoming out''. Ngawha differs from other systems both in the level and profile details of Δ 18 O values. The reservoir fluid at Ngawha hydrogeology may or may not be suited for development of a high-throughput surface recharge system