Sample records for yungul carbonatite dykes

  1. Geochemical Characteristics of a Carbonatite Dyke Rich in Rare Earths from Bayan Obo, China


    The whole-rock geochemistry of a rare earths rich carbonatite dykes that locates at Dulahala and lies 3 km north-east to the East Ore body of the giant Bayan Obo RE-Nb-Fe deposit was analysed. The dyke cuts cross H1 coarse quartz sandstone and H2 fine quartzite of the Proterozoic Bayan Obo group. RE content in the dyke varies greatly up to 20%(mass fraction), which comprises rich RE ores. Light RE in carbonatites are extremely enriched and strongly fractionated relative to heavy RE, but no Eu anomaly. The carbonatite may be produced by mechanisms as follows: the carbonatite magma is directly formed by very low degree(F<1%) partial melting of enriched lithospheric mantle, leaving residual minerals characterized by abundant garnet;then the magma arises into a chamber within the crust where they will undergo fractional crystallization, which makes RE further concentrated in carbonatite. The RE patterns and spider diagrams of the carbonatite are identical to those fine-grained dolomite marble that is the ore-host rock for the Bayan Obo deposit. However, the carbonatite is calcic, which is different from the fine-grained dolomite marble in major element geochemistry. The difference is suggested to be resulted from that the carbonatite dyke is not affected by a large scale dolomitization, while the fine-grained dolomite marble might be the product of dolomitized carbonatite intrusive body that might set up a hydrothermal system in the region, which transported Mg from the Bayan Obo sediments, especially form the shales to the carbonatite intrusion.

  2. A Geochemical Study of an REE-rich Carbonatite Dyke at Bayan Obo, Inner Mongolia, Northern China


    An REE-rich carbonatite dyke was found in Dulahala, close to the Bayan Obo superlarge REE-Nb-Fe mineral deposit in Inner Mongolia, northern China. The REE content in the dyke varies greatly, from 1% up to 20% (wt), which might constitute rich REE ores. Light REEs in the carbonatite are enriched and highly fractionated relative to heavy REEs and there is no Eu anomaly. The REE and trace element distribution patterns of the carbonatite are identical to those of fine-grained dolomite marble which is the host rock of the Bayan Obo REE-Nb-Fe superlarge mineral deposit. This indicates a petrogenetic linkage between the REE-rich carbonatite and the mineralizations in this region.

  3. Re-interpretation of zircon date in a carbonatite dyke at the Bayan Obo giant REE-Fe-Nb deposit,China


    @@ Recent re-valuation of the dating of the carbonatite dykes associated with the REE-Fe-Nb giant deposit at Bayan Obo has revealed an anomaly with one of the dates. Inspection of the post-1990 literature for the carbonatite dykes and H8 dolomite rocks and ores of Bayan Obo provides age data in the range 1223 +65 Ma to 1656 Ma, as Table 1 shows. Since Sm and Nd are relatively immobile elements, most of the Sm-Nd dates are considered to be little changed by the subsequent mineralization processes. That the dates occur in two clusters, 1656 ~ 1500 Ma and 1312 ~ 1223 Ma might refer to two related periods of carbonatitic magmatic activity, but that is not relevant at this moment.

  4. Petrological, geochemical and isotopic investigations on a carbonate-dyke and enclosed pyroxenite xenoliths from Val Mastallone (Ivrea-Verbano Zone): evidence of a cumulate carbonatite in the lower crust?

    Galli, Andrea; Grassi, Daniele; Burg, Jean-Pierre; Schwab, Leo; Rickli, Jörg; Gianola, Omar


    The Ivrea-Verbano Zone (Italy/Switzerland) represents one of the best exposed mantle-crust sections worldwide. Its geological evolution has been governed by the Permian underplating of mantle-derived basic magmas („Mafic Complex") into the high-grade basement of the Southern Alps. In the Ivrea-Verbano Zone, marbles occur as concordant bodies or partly discordant carbonate-dykes. Generally, these dykes are constituted of calcite, diopside, scapolite, contain enclave of the host rocks and display sharp contacts to the host lithologies without evidences of alteration zones. In Val Mastallone, an up to 40 m thick carbonate-dyke with different characteristics occurs within mafic granulites. This dyke is composed of calcite, clinopyroxene and subordinate allanite and zircon. No scapolite is observed. The contacts to the host granulites are characterized by alteration zones composed of actinolite, chlorite, clinozoisite, plagioclase and calcite. The carbonate-dyke bears enclave of phlogopite-amphibole-apatite-rutile-ilmenite ± garnet or spinel clinopyroxenites. These rock type is not outcropping elsewhere in the proximity of the dyke, suggesting a significant transport. Host mafic granulite enclave are found exclusively at the margin of the dyke. Calcite dykelets rich in zircon, baddeleyite and other Ba, U, Th, REE-rich phases cut across the enclave. The carbonate-dyke shows an enrichment of LREE over HREE ((La/Yb)N = 14), with a Σ REE = 338 and Y/Ho = 27. On the chondrite-normalized REE abundances diagram, no Eu anomaly is observed. Mantle-normalized pattern shows strong negative anomalies at Cs, Rb, K, Pb, P, Zr, Hf, Ti and positive Ba, Th, Sr, Nd anomalies, similarly to the "world average carbonatites". Measured absolute trace element concentrations are lower than average carbonatites but significantly higher than typical limestones and similar to cumulate carbonatites found elsewhere in the world (e.g. India, China, Brazil). Grt-bearing clinopyroxenite enclave

  5. 白云鄂博矿床碳酸岩墙/脉和赋矿白云岩中流体包裹体研究%Fluid inclusion study of carbonatite dykes/veins and ore-hosted dolostone at the Bayan Obo ore deposit

    秦朝建; 裘愉卓; 周国富; 王中刚; 张台荣; 肖国望


    Fluid inclusion study has been carried out for the carbonatite dykes/veins and the ore-hosted dolostone of the Bayan Obo superlarge REE-Fe-Nb deposit in order to provide the evidence and constraint for their origin. Based on the detailed geological observation and mineralogical investigation, the heating and cooling stage and laser Raman spectroscopy were mainly used for the laboratory work of this study. Following results have been obtained: (1) The discovery of melt and melt-fluid inclusions from carbonatite dykes/veins in the Dulahara and Jianshan Mountains, combined with the fine-grained (aplitic) texture of rocks, as well as the types and features of fluid inclusions such as CO2 enrichment, higher homogenization temperature, provides a direct evidence for the magmatic origin of these dykes/veins. (2) The carbonatite dykes/veins distributed in two regions, nearby the axis of the Kuangou anticline and in the east to Bayan Obo town, mainly show coarse-grained texture. No melt inclusion was found, and the fluid inclusions possess features of less CO2, lower homogenization temperature and higher salinity. They are tentatively identified as veins formed by some carbonate-rich hydrothermal solution. (3) Bedding carbonate layers/lens within the hanging wall and foot wall of ore-hosted dolostone, previously recognized as of magmatic origin, mainly composed by dolomite. The existence of single phase pure aqueous inclusions with very low homogenization temperature indicates their sedimentary origin. (4) The ore-hosted dolostone possesses apparent bedding and laminated structures. No melt inclusion was found, but, both single phase pure aqueous inclusions and CO2bearing multi-phase fluid inclusions coexisted in dolostones. In the direction towards ore-bodies, the homogenization temperature and CO2 contents of fluid inclusion show an increasing tendency. It indicates the sedimentary origin of dolostone superimposed by late fluid metasomatism.

  6. Carbonatites in China: A review for genesis and mineralization

    Cheng Xu


    carbonatite-derived fluid has interacted with wallrock to form REE ore veins. The amount of carbonatite dykes occurring near the Bayan Obo orebodies may support the same mineralization model, i.e. that fluids evolved from the carbonatite dykes reacted with H8 dolomite marble, and thus the different REE and isotope compositions of coarse- and fine-grained dolomite may be related to reaction processes.

  7. Geochemistry and petrogenesis of carbonatites from South Nam Xe, Lai Chau area, northwest Vietnam

    Nguyen Thi, Thuy; Wada, Hideki; Ishikawa, Tsuyoshi; Shimano, Taketo


    This paper presents a study of the petrography, mineral chemistry, geochemistry, and Sr-Nd-Pb-C-O isotope systematics of carbonatite dykes and associated rocks from the northeastern part of the Song Da intracontinental rift in South Nam Xe (northwest Vietnam) aimed at constraining the origin of the carbonatite magmas. The carbonatites are characterized by SiO2 material. Because of the lack of tectonic data and the limited number of samples studied, this conclusion is still ambiguous and requires further study.

  8. Isotopic Ages of the Carbonatitic Volcanic Rocks in the Kunyang Rift Zone in Central Yunnan,China

    ZHANG Yongbei; WANG Guilan; NIE Jianfeng; ZHAO Chongshun; XU Chengyan; QIU Jiaxiang; Wang Hao


    The Mesoproterozoic Kunyang rift, which is located on the western margin of the Yangtze platform and the southern section of the Kangdian axis, is a rare massive Precambrian iron-copper polymetallic mineralization zone in China. The Mesoproterozoic Wulu (Wuding(Lufeng) basin in the middle of the rift is an elliptic basin controlled by a ring fracture system. Moreover, volcanic activities in the basin display zonation of an outer ring, a middle ring and an inner ring with carbonatitic volcanic rocks and sub-volcanic dykes discovered in the outer and middle rings. The Sm-Nd isochron ages have been determined for the outer-ring carbonatitic lavas (1685 Ma) and basaltic porphyrite of the radiating dyke swarm (1645 Ma) and the Rb-Sr isochron ages for the out-ring carbonatitic lavas (893 Ma) and the middle-ring dykes (1048 Ma). In combination of the U-Pb concordant ages of zircon (1743 Ma) in trachy-andesite of the corresponding period and stratum (1569 Ma) of the Etouchang Formation, as well as the Rb-Sr isochron age (1024 Ma) and K-Ar age (1186 Ma) of the dykes in the middle ring, the age of carbonatites in the basin is preliminarily determined. It is ensured that all of these carbonatites were formed in the Mesoproterozoic period, whereby two stages could be identified as follows: in the first stage, carbonatitic volcanic groups, such as lavas, pyroclastic rocks and volcaniclastic sedimentary rocks, were formed in the outer ring; in the second stage, carbonatitic breccias and dykes appeared in the middle ring. The metamorphic age of the carbonatitic lavas in the outer ring was determined to be concurrent with the end of the first stage of the Neoproterozoic period, corresponding to the Jinning movement in central Yunnan.

  9. Contrasting carbonatite volcanism at the Kerimasi and Oldoinyo Lengai volcanoes, northern Tanzania

    Mattsson, Hannes B.; Bosshard-Stadlin, Sonja A.; Weidendorfer, Daniel; Balashova, Anna


    The two neighboring volcanoes, Kerimasi and Oldoinyo Lengai, located 12 km apart in the eastern branch of the East African Rift in northern Tanzania display many similarities but also significant differences in terms of the types of magmas being erupted. The carbonatites of Kerimasi have a rather large compositional span (MgO=0-14 wt.% and CaO=32-56 wt.%). This is in sharp contrast to the very uniform Na-carbonatites typically erupted at Oldoinyo Lengai. As a result of this the Kerimasi carbonatites classify as Ca-carbonatites and they are all virtually devoid of alkalis. The trace elements patterns are rather uniform for the Kerimasi carbonatites and the patterns are similar to Ca-carbonatites found elsewhere. They differ to the natrocarbonatites by having considerable higher Zr and Hf concentrations. The slope of the REE ([La/Yb]N) are considerably flatter for the Kerimasi rocks (12 to 45) in comparison to natrocarbonatites (>1000) or even Ca-carbonatite dykes from Oldoinyo Lengai (~100). Interestingly, the Trig Point Hill debris avalanche deposit of Kerimasi is dominated by carbonatitic material in the form of blocks comprising intrusions, cumulates and vesicular lava flows (calculated to have a total volume of approximately 0.6 to 1.2 km3). This strongly indicates that the collapsed part of volcanic edifice at Kerimasi is in fact dominated by carbonatitic material with only minor amounts of silicate rocks. At Oldoinyo Lengai the carbonatitic material mainly occur inside the summit crater as small lava flows (with a combined volume of collapses but none of the resulting debris avalanche deposits contain lithics of carbonatitic material. This discrepancy is noteworthy, as the location of magma chamber is supposedly shallower at Oldoinyo Lengai (i.e., at a few km depth inside the volcano). Yet none of this is reflected in resulting deposits. Although much has been learned since Barry Dawson's discovery of the magmatic nature of the natrocarbonatites at Oldoinyo

  10. Anisotropy of magnetic susceptibility (AMS) in the Siilinjärvi carbonatite complex, eastern Finland

    Almqvist, Bjarne; Karell, Fredrik; Högdahl, Karin; Malehmir, Alireza; Heino, Pasi; Salo, Aleksi


    We present a set of AMS measurements on samples from the Siilinjärvi alkaline-carbonatite complex in eastern Finland. The complex has a tabular shape (ca. 16 km long, 1.5 km wide) that strikes north-south and is constrained within a steeply dipping N-S oriented deformation zone. It consists of a mixture of lithologies, including carbonatite, fenite and glimmerite (mica-rich rocks), which is hosted within a Precambrian granite and gneiss. After emplacement of the carbonatite, the complex was subsequently intruded by diabase dykes. Deformation has occurred in several episodes after dyke intrusions, and strain is heterogeneously distributed among the different lithologies. Strain localizes mainly within glimmerite and carbonatite, and at the contacts between dykes and glimmerite/carbonatite where shear zones develop locally. Structures provide indications for both simple (strike-slip) and pure shear components in the deformation history of the complex, although the former may dominate. Thirty-six localities were sampled, providing 272 specimens for AMS measurements, within the southern and eastern parts of the Siilinjärvi open-pit mine (within the complex), mainly from diabase dykes, glimmerite and carbonatites; a smaller number of samples were collected from fenite. Sampling was carried out in order to investigate magnetic fabrics in relation to the emplacement of the dykes and their structural relationship to the glimmerite/carbonatite. Structural measurements were made to accompany the magnetic fabric study. The magnetic fabric shows a magnetic foliation plane that is oriented north-south, with sub-horizontal k3-axes oriented nearly east-west. Magnetic lineation (k1) clusters sub-vertically, but does show a tendency to spread along the north-south magnetic foliation great circle. The dataset can be further divided into two sub-sets based on the bulk susceptibility (km) and degree of anisotropy (P). The bulk of the data set ( 70 %), belonging to samples of diabase

  11. Dyke Swarms of the Paraná Triple Junction, Southern Brazil

    José Moacyr Vianna Coutinho


    Full Text Available This work intends primarily to survey the field, mineralogical and petrographic characters of the mafic dykes which occuron a stretch of 650 km along the Southeastern coast of Brazil, between the city of São Sebastião, and the island of SantaCatarina. New chemical and geochronological data are also presented. The coastal dyke swarms are envisaged as the northernand southern arms of a plume-generated triple junction system centered on the Paraná State coast, and related to the initialopening of the South Atlantic. Mafic magma intruded as dyke swarms along three directions: N-S (the southern arm, along theParaná-Santa Catarina coast, NW-SE (Ponta Grossa arch and NE-SW (the northern arm along the São Paulo coast. Fiftytwo dykes, almost all tholeiitic diabases, were mapped and sampled along the south arm coast. The Ponta Grossa arch dykes are chiefly composed of tholeiitic diabases and lesser intrusions of andesitic to rhyolitic composition. Over 240 dykes were sampled and identified along the north arm west of São Sebastião. Lamprophyres are here abundant, followed by diabases, microdiorite porphyries and lesser amounts of trachy-andesite, carbonatite and Precambrian dykes. Special attention was given to the study of lamprophyres, their field appearance relative abundance, mineral and chemical composition, enclaves and relations to neighboring alkaline intrusions.

  12. Newania carbonatites, Western India: example of mantle derived magnesium carbonatites

    Doroshkevich, Anna Gennad'evna; Ripp, German; Viladkar, Shrinivas


    The key mineralogical features of the Newania carbonatites, that illustrate their derivation from primary mantle melts (Gruau et al. Terra Nova, Abstract Suppl 1:336, 1995; Viladkar Petrology 6(3):272-283, 1998; Basu and Murty Abstracts of Goldschmidt Conference A40, 2006), are the presence of magnesite, graphite and Cr-rich magnetite. Magnesite is an early crystallizing phase. Cr-rich magnetite and graphite coexist with carbonatite minerals and precipitated from carbonate magma. Graphite, as well as gaseous CO2 and carbonate minerals such as dolomite and magnesite, can be stable in peridotite mantle. Coexistence of these minerals is controlled by fO 2 and PT-conditions. Mineral geothermometers for the Newania carbonatite give temperatures from 463 to 950°C. The parental source for Newania carbonatites was characterized by a relatively high log ( fHF/ fH2O) level which increased during the crystallization history of Newania. The estimated oxygen fugacity (for ilmenite-magnetite pairs) varies from -1.5 to +3.5 (log-bar unit deviation from FMQ buffer), which is supported by the presence of Fe-columbite, and the composition of phlogopite, amphibole and pyroxene that have an elevated concentration of Fe3+. However, the oxygen fugacity range represented by co-existing early-crystallized graphite and magnesite is below that of the FMQ buffer and lies on the CCO buffer.

  13. Study on the carbonate ocelli-bearing lamprophyre dykes in the Ailaoshan gold deposit zone, Yunnan Province

    HUANG; Zhilong(黄智龙); LIU; Congqiang(刘丛强); XIAO; Huayun(肖化云); HAN; Runsheng(韩润生); XU; Cheng(许成); LI; Wenbo(李文博); ZHONG; Kunming(钟昆明)


    Three carbonate ocelli-bearing lamprophyre dykes have been found in the Laowangzhai and Beiya gold orefields in the northern sector of the Ailaoshan gold deposit zone, Yunnan Province. Ocelli in the lamprophyre dykes are carbonates composed mainly of dolomite and calcite. Their trace elements, REE and C isotopic compositions are characteristic of carbonatite and the main mineral assemblages, major elements, trace elements and REE in the matrix are similar to those in the carbonate ocelli-barren lamprophyre dykes in the orefields, which are calc-alkaline lamprophyres that derived from the fertile mantle. The results indicate that the carbonate ocelli-bearing lamprophyre dykes in this area were produced at the time when the Himalayan lamprophyre magma evolved to a relatively late stage of silicate-carbonate liquid immiscibility. In the process of magmatic evolution there took place magmatic degassing with CO2 and H2O as the dominant released gases.

  14. The Elk Creek Carbonatite Complex, Nebraska (USA)

    Kettler, R. M.; Blessington, M.


    The Elk Creek carbonatite complex (ECCC) is a large Early Cambrian carbonatite-alkaline syenite complex located in SE Nebraska (USA). The carbonatite and related rocks are buried by more than 200 m of Pennsylvanian marine sedimentary rocks and Quaternary till. The pre-Pennsylvanian sub-crop is crudely circular in plan-view and exceeds 30 km2, making it one of the larger carbonatite complexes in North America. The rocks of the complex were intruded in Precambrian granite and gneiss on the eastern margin of the Mid-Continent rift where it has been offset by one of a series of southeasterly trending structures. The primary rock type in the ECCC is dolomite carbonatite. The dolomite carbonatite ranges from fine-grained flow-banded dolomite to a coarse-grained rock comprising large prismatic dolomite crystals. The central portion of the complex comprises a pipe-like intrusion of magnetite dolomite carbonatite and magnetite dolomite carbonatite breccia. Magnetite dolomite carbonatite is typically fine-grained and contains angular or rounded elongate fragments of dolomite carbonatite. Fragments of magnetite dolomite carbonatite are also included in dolomite carbonatite and other carbonatite rocks in the complex. Emplacement of a discreet pulse of reduced, iron-rich carbonatite magma was, therefore, a likely early event in the evolution of the ECCC. The magnetite is altered locally to hematite and other iron oxides. The oxidation ranges from a dusting of hematite to pervasive alteration to hematite and ferric oxyhydroxides and occurs to depths as much as 630 m below the modern land surface. Other volumetrically important rock types include apatite dolomite carbonatite and barite dolomite carbonatite. Both of these rock types are localized largely along fractures, occur later in the intrusive sequence, and may reflect exsolution of phosphates and sulfates with decreasing temperatures. The magnetite dolomite carbonatite hosts significant pyrochlore mineralization. Microprobe

  15. Formation of carbonatite-related giant rare-earth-element deposits by the recycling of marine sediments.

    Hou, Zengqian; Liu, Yan; Tian, Shihong; Yang, Zhiming; Xie, Yuling


    Carbonatite-associated rare-earth-element (REE) deposits are the most significant source of the world's REEs; however, their genesis remains unclear. Here, we present new Sr-Nd-Pb and C-O isotopic data for Cenozoic carbonatite-hosted giant REE deposits in southwest China. These REE deposits are located along the western margin of the Yangtze Craton that experienced Proterozoic lithospheric accretion, and controlled by Cenozoic strike-slip faults related to Indo-Asian continental collision. The Cenozoic carbonatites were emplaced as stocks or dykes with associated syenites, and tend to be extremely enriched in Ba, Sr, and REEs and have high (87)Sr/(86)Sr ratios (>0.7055). These carbonatites were likely formed by melting of the sub-continental lithospheric mantle (SCLM), which had been previously metasomatized by high-flux REE- and CO2-rich fluids derived from subducted marine sediments. The fertility of these carbonatites depends on the release of REEs from recycled marine sediments and on the intensity of metasomatic REE refertilization of the SCLM. We suggest that cratonic edges, particularly along ancient convergent margins, possess the optimal configuration for generating giant REE deposits; therefore, areas of metamorphic basement bounded or cut by translithospheric faults along cratonic edges have a high potential for such deposits.

  16. Petrological and geochemical characteristics of Paleoproterozoic ultramafic lamprophyres and carbonatites from the Chitrangi region, Mahakoshal supracrustal belt, central India

    Rajesh K Srivastava


    A number of ENE–WSW trending Paleoproterozoic dykes and plugs of mafic, ultramafic, alkaline and carbonatite rocks intrude Mahakoshal supracrustal belt (MSB), which is a part of the Central Indian Tectonic Zone (CITZ). Best exposures of these intrusions are found in the eastern parts of the MSB, particularly in and around Chitrangi area. Many of these intrusions have greenschist facies mineral composition and show sharp contact with supracrustal rocks. However, igneous textures, such as porphyritic/glomeroporphyritic, are still preserved in the form of partly pseudomorphed olivines, phlogopites and pyroxenes. Striking feature observed in some ultramafic samples is the presence of melanite garnet and rounded or elliptical carbonate ocelli. The petrographic characteristics suggest occurrence of carbonate-rich ultramafic lamprophyres; close to aillikite composition. Coarse-grained carbonatites show hypidiomorphic texture and mostly composed of calcite with appreciable amount of silicate minerals like clinopyroxene, phlogopite and olivine (often pseudomorphed by calcite, amphibole and chlorite). It is difficult to establish any direct genetic relationship between carbonatite and ultramafic lamprophyre samples on the basis of their chemistry; they were likely derived from distinct parental melts. High Mg#(up to ∼78), and high Ni and Cr contents (up to ∼1700 and ∼1100, respectively) and low HREE concentration in few ultramafic lamprophyre samples apparently suggest their derivation from a near-primary mantle-derived melts originated at great depths. Geochemistry and presence of carbonate ocellae in ultramafic lamprophyre samples suggest genesis of these silicate rocks and associated carbonatites through liquid immiscibility, however possibility of their derivation through vein-plus-wall-rock melting model cannot be ignored. A multi-stage veined mantle melting model is suitable in the latter case. It is suggested that early stages of rifting in the Mahakoshal

  17. Petrography and mineral chemistry of carbonatites and mica-rich rocks from the Araxa Complex (Alto Paranaiba Province, Brazil)

    Traversa, Gianbosco; Morbidelli, Lucio; Ronca, Sara [Roma Univ. (Italy). Dipt. di Scienze della Terra; Gomes, Celso B.; Ruberti, Excelso [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias].E-mail:; Brotzu, Piero [Napoli Univ. (Italy). Dipt. di Scienze della Terra; Buraglini, Nicoletta [Catania Univ. (Italy). Dipt. di Scienza della Terra; Principato, Maria Speranza [Milano Univ. (Italy). Dipt. di Scienza della Terra


    The Araxa complex (16 km{sup 2}) comprises carbonatites forming a central core and a complex network of concentric and radial dykes as well as small veins; additionally, it includes mica-rich rocks, phoscorities and lamprophyres. Fenites also occur and rare represented by Proterozoic quartzites and schists of the Araxa Group. The petrographic study of 130 borehole samples indicates that the complex is basically made up by two rock-types, carbonatites and mica-rich rocks, and subordinately by a third unit of hybrid composition. Carbonatites range chemically in composition, the most abundant type being magnesio-carbonatites. Dolomite and calcite correspond to the chief constituents, but other carbonate phases, including the Ce-group RE minerals, are also recognized. phosphates and oxides are widespread accessories whereas silicate minerals consist of olivine, clinopyroxene, mica and amphibole. Mica-rich rocks are represented by abundant glimmeritic rocks and scare cumulitic phlogopite-, olivine-and diopside-bearing pyroxenites. Hybrid rocks mainly contain phlogopite and tetraferriphlopite as cumulus and intercumulus phases, respectively; carbonate minerals may also be found. Chemical data indicate that the carbonatities are strongly enriched in REE and have lower contents of Nb, Zr, V, Cr, Ni and Rb compared to the mica-rich rocks. The higher K, Nb and Zr contents of the latter rocks are believed to be related to metasomatic processes (glimmeritization) of the pyroxenites. Similar REE patterns for carbonatites and mica-rich rocks seem to suggest that they are related to a single parental magma, possibly of ijolitic composition. Steep LREE/HREE fractionation and high {sigma}REE content of some carbonatite samples would be explained by hydrothermal and supergenic processes. (author)

  18. Carbonatites and primary carbonates in the Rio Apa and Amambay regions, NE Paraguay

    Comin-Chiaramonti, Piero; De Min, Angelo; Girardi, Vicente A. V.; Gomes, Celso B.


    In the Rio Apa and Amambay regions, north-eastern Paraguay (NPAA), potassic, alkaline-carbonatitic rocks (138-139 Ma) predate the eruption of tholeiitic flood basalts (133 ± 1 Ma). These rocks, mainly outcropping as dykes or ring-like complexes, intrude a Cambro-Ordovician carbonate platform and Precambrian metamorphic rocks along with their Silurian and Permo-Carboniferous sediments. The main rock-types range from basanite to trachyte and trachyphonolite (and intrusive equivalents) to carbonatite, in addition to glimmeritic and pyroxenitic veins. Geological and geophysical evidence indicate that the NPAA magmatism is related to extensional tectonics, like the Early Cretaceous alkaline-carbonatitic complexes from central-eastern Paraguay (127 ± 1 Ma) and the eastern magmatic occurrences of the Paraná Basin. Oxygen and carbon isotope compositions (whole rocks and carbonates) vary from values close to the field of continental lithospheric mantle, or that of primary carbonatites, up to values typical of a hydrothermal environment. An isotope exchange model implies that the main isotope variations, ranging from a magmatic (e.g., 1200 °C) to a low temperature (< 400 °C) environment, involved fluids with CO2/H2O ratios between 0.8 and 1.0. In particular, the Osbnd C isotopic variations, in combination with the La vs La/Yb ratios, suggest an increasingly higher level of carbonate in the silicate liquids, with increasing evolution, i.e., basanite → phonotephrite → trachyphonolite-phonolite (trachyte) → carbonatite. Srsbnd Nd isotopes show that the carbonatites are mantle derived without significant crustal contamination and that they can be related to isotopically enriched sources where newly formed veins (enriched component) and peridotite matrix (depleted component) underwent differing isotopic evolution. TDM model ages for NPAA range from 1.2 to 2.3 Ga. Considering that in the whole Paraná Basin isotopically distinct K-alkaline and tholeiitic magmas were

  19. Tectonic significance of dykes in the Sarnu-Dandali alkaline complex, Rajasthan, northwestern Deccan Traps

    Anjali Vijayan; Hetu Sheth; Kamal Kant Sharma


    Whether swarms of preferentially oriented dykes are controlled by regional stress fields, or passively exploit basement structural fabric, is a much debated question, with support for either scenario in individual case studies. The Sarnu-Dandali alkaline complex, near the northwestern limit of the Deccan Traps continental flood basalt province, contains mafic to felsic alkaline volcano-plutonic rocks and carbonatites. The complex is situated near the northern end of the 600 km long, NNWeSSE-trending Barmer-Cambay rift. Mafic enclave swarms in the syenites suggest synplutonic mafic dykes injected into a largely liquid felsic magma chamber. Later coherent dykes in the complex, of all compositions and sizes, dominantly strike NNWeSSE, parallel to the Barmer-Cambay rift. The rift formed during two distinct episodes of extension, NWeSE in the early Cretaceous and NEeSW in the late Cretaceous. Control of the southern Indian Dharwar structural fabric on the rift trend, as speculated previously, is untenable, whereas the regional Precambrian basement trends (Aravalli and Malani) run NEeSW and NNEeSSW. We therefore suggest that the small-scale Sarnu-Dandali dykes and the much larger-scale Barmer-Cambay rift were not controlled by basement structure, but related to contemporaneous, late Cretaceous regional ENEeWSW extension, for which there is varied independent evidence.

  20. Dyke-Davidoff-Masson syndrome

    Manas R Behera


    Full Text Available A 14-month-old male child presented with recurrent generalized seizures, spastic hemiplegia, microcephaly and had developmental delay in motor and speech domains. CT of the brain revealed characteristic features diagnostic of infantile type of cerebral hemiatrophy or Dyke-Davidoff-Masson syndrome.

  1. Carbonatite ring-complexes explained by caldera-style volcanism.

    Andersson, Magnus; Malehmir, Alireza; Troll, Valentin R; Dehghannejad, Mahdieh; Juhlin, Christopher; Ask, Maria


    Carbonatites are rare, carbonate-rich magmatic rocks that make up a minute portion of the crust only, yet they are of great relevance for our understanding of crustal and mantle processes. Although they occur in all continents and from Archaean to present, the deeper plumbing system of carbonatite ring-complexes is usually poorly constrained. Here, we show that carbonatite ring-complexes can be explained by caldera-style volcanism. Our geophysical investigation of the Alnö carbonatite ring-complex in central Sweden identifies a solidified saucer-shaped magma chamber at ~3 km depth that links to surface exposures through a ring fault system. Caldera subsidence during final stages of activity caused carbonatite eruptions north of the main complex, providing the crucial element to connect plutonic and eruptive features of carbonatite magmatism. The way carbonatite magmas are stored, transported and erupt at the surface is thus comparable to known emplacement styles from silicic calderas.

  2. Dyke-Davidoff-Masson Syndrome

    Zawar, Ifrah; Khan, Ashfa A.; Sultan, Tipu; Rathore, Ahsan W.


    The Dyke-Davidoff-Masson Syndrome (DDMS) results from an insult to the growing brain in utero or early infancy, which lead to loss of neurons compromising the growth of the brain. Clinical presentation includes seizures, hemiparesis, facial asymmetry, and learning disability. Radiological findings include cerebral atrophy on one side. Here, we present a case with status epilepticus who had underlying DDMS. It is a rare syndrome and uncommon cause for status epilepticus. Infections of CNS, hyp...

  3. Geology, geochemistry and geochronology of the Songwe Hill carbonatite, Malawi

    Broom-Fendley, Sam; Brady, Aoife E.; Horstwood, Matthew S. A.; Woolley, Alan R.; Mtegha, James; Wall, Frances; Dawes, Will; Gunn, Gus


    Songwe Hill, Malawi, is one of the least studied carbonatites but has now become particularly important as it hosts a relatively large rare earth deposit. The results of new mapping, petrography, geochemistry and geochronology indicate that the 0.8 km diameter Songwe Hill is distinct from the other Chilwa Alkaline Province carbonatites in that it intruded the side of the much larger (4 × 6 km) and slightly older (134.6 ± 4.4 Ma) Mauze nepheline syenite and then evolved through three different carbonatite compositions (C1-C3). Early C1 carbonatite is scarce and is composed of medium-coarse-grained calcite carbonatite containing zircons with a U-Pb age of 132.9 ± 6.7 Ma. It is similar to magmatic carbonatite in other carbonatite complexes at Chilwa Island and Tundulu in the Chilwa Alkaline Province and others worldwide. The fine-grained calcite carbonatite (C2) is the most abundant stage at Songwe Hill, followed by a more REE- and Sr-rich ferroan calcite carbonatite (C3). Both stages C2 and C3 display evidence of extensive (carbo)-hydrothermal overprinting that has produced apatite enriched in HREE (<2000 ppm Y) and, in C3, synchysite-(Ce). The final stages comprise HREE-rich apatite fluorite veins and Mn-Fe-rich veins. Widespread brecciation and incorporation of fenite into carbonatite, brittle fracturing, rounded clasts and a fenite carapace at the top of the hill indicate a shallow level of emplacement into the crust. This shallow intrusion level acted as a reservoir for multiple stages of carbonatite-derived fluid and HREE-enriched apatite mineralisation as well as LREE-enriched synchysite-(Ce). The close proximity and similar age of the large Mauze nepheline syenite suggests it may have acted as a heat source driving a hydrothermal system that has differentiated Songwe Hill from other Chilwa carbonatites.

  4. Fluid Inclusion Study of Quartz Xenocrysts in Mafic Dykes from Kawant Area, Chhota Udaipur District, Gujarat, India

    Randive Kirtikumar


    Full Text Available Unusual mafic dykes occur in the proximity of the Ambadongar Carbonatite Complex, Lower Narmada Valley, Gujarat, India. The dykes contain dense population of quartz xenocrysts within the basaltic matrix metasomatised by carbonate-rich fluids. Plagioclase feldspars, relict pyroxenes, chlorite, barite, rutile, magnetite, Fe-Ti oxides and glass were identified in the basaltic matrix. Quartz xenocrysts occur in various shapes and sizes and form an intricate growth pattern with carbonates. The xenocrysts are fractured and contain several types of primary and secondary, single phase and two-phase fluid inclusions. The two-phase inclusions are dominated by aqueous liquid, whereas the monophase inclusions are composed of carbonic gas and the aqueous inclusions homogenize to liquid between 226°C and 361°C. Majority of the inclusions are secondary in origin and are therefore unrelated to the crystallization of quartz. Moreover, the inclusions have mixed carbonic-aqueous compositions that inhibit their direct correlation with the crustal or mantle fluids. The composition of dilute CO2-rich fluids observed in the quartz xenocrysts appear similar to those exsolved during the final stages of evolution of the Amba Dongar carbonatites. However, the carbonates are devoid of fluid inclusions and therefore their genetic relation with the quartz xenocrysts cannot be established.

  5. Carbonatite complexes from Brazil: A review

    Gomes, C. B.; Ruperti, E.; Morbidelli, L.

    This paper reviews general aspects regarding the occurrences of alkaline rocks associated with carbonatites in Brazil. Currently twenty-two complexes are listed in the literature, but only a few have been thoroughly studied. Special attention is given to the geological association and geochronology of such rocks, and petrological problems are only briefly discussed as a consequence of insufficient information. Data on mineral resources are also provided for some complexes. Eight occurrence are being mined, particularly for phosphate and niobium.

  6. Micas from the Khaluta carbonatite deposit, western Transbaikal region

    Ripp, G. S.; Doroshkevich, A. G.; Karmanov, N. S.; Kanakin, S. V.


    The Khaluta carbonatite deposit located in the western Transbaikal region was formed during the Late Mesozoic rifting in the southern framework of the Siberian Craton. Carbonatite is associated with shonkinite and syenite and is accompanied by fenitization. The composition of mica in more than 160 samples of country rocks, carbonatites, silicate rocks, and fenites was studied. The Fe3+ and Fe2+ contents, as well as oxygen isotopic composition, were determined. The Mg and Fe contents increase, whereas the Ti and Al contents decrease in micas when passing from silicate rocks and fenites to carbonatites. Micas from carbonatites are depleted in Al, enriched in Fe3+, and distinguished by high Si and F contents. According to our calculations, in some cases Al replaces Si in the tetrahedral site instead of replacement of Fe3+ as is characteristic of tetraferriphlogopite. Formally, the mica from carbonatites falls within the tetraferriphlogopite field, but typical inverse pleochroism is not always observable. The δ18O values of micas from carbonatite, shonkinite, syenite, and fenite are similar to those of mantle-derived silicate minerals. The δ18O values in the minerals coexisting with phlogopite testify to their isotopic equilibrium and make it possible to calculate the crystallization temperature of carbonatite.

  7. Magma deformation and emplacement in rhyolitic dykes

    McGowan, Ellen; Tuffen, Hugh; James, Mike; Wynn, Peter


    Silicic eruption mechanisms are determined by the rheological and degassing behaviour of highly-viscous magma ascending within shallow dykes and conduits. However, we have little knowledge of how magmatic behaviour shifts during eruptions as dykes and conduits evolve. To address this we have analysed the micro- to macro-scale textures in shallow, dissected rhyolitic dykes at the Tertiary Húsafell central volcano in west Iceland. Dyke intrusion at ~3 Ma was associated with the emplacement of subaerial rhyolitic pyroclastic deposits following caldera formation[1]. The dykes are dissected to ~500 m depth, 2-3 m wide, and crop out in two stream valleys with 5-30 m-long exposures. Dykes intrude diverse country rock types, including a welded ignimbrite, basaltic lavas, and glacial conglomerate. Each of the six studied dykes is broadly similar, exhibiting obsidian margins and microcrystalline cores. Dykes within pre-fractured lava are surrounded by external tuffisite vein networks, which are absent from dykes within conglomerate, whereas dykes failed to penetrate the ignimbrite. Obsidian at dyke margins comprises layers of discrete colour. These display dramatic thickness variations and collapsed bubble structures, and are locally separated by zones of welded, brecciated and flow-banded obsidian. We use textural associations to present a detailed model of dyke emplacement and evolution. Dykes initially propagated with the passage of fragmented, gas-charged magma and generation of external tuffisite veins, whose distribution was strongly influenced by pre-existing fractures in the country rock. External tuffisites retained permeability throughout dyke emplacement due to their high lithic content. The geochemically homogenous dykes then evolved via incremental magma emplacement, with shear deformation localised along emplacement boundary layers. Shear zones migrated between different boundary layers, and bubble deformation promoted magma mobility. Brittle

  8. Geochemistry of carbonatites in Maoniuping REE deposit, Sichuan Province, China

    许成; 黄智龙; 刘丛强; 漆亮; 李文博; 管涛


    Carbonatites in the Maoniuping REE deposit, Sichuan Province, which are spatially and temporally associated with rare earth mineralization, were emplaced at the time of Himalayan. The rocks are carbonatite-syenite complexes, with the mineral assemblages of calcite-aegirine-acmite- arfvedsonite-mica-orthoclase. The rocks are characterized by the enrichment in incompatible elements, such as Sr, Ba and REE, with C and O isotopic compositions of the "primary igneous carbonatites", relatively high initial 87Sr/86Sr ratios and low ??Nd values. All of these suggest that the rocks were derived from the metasomatic enriched mantle. It is demonstrated by geological and geochemical evidence that the mixing of the Himalayan subducting crustal materials with mantle source EM1 is probably the main factor responsible for the formation of carbonatites. The carbonatite-syenite complexes were generated from liquid immiscibility of CO2-rich alkalic silicate magma, which was derived from partial melting of the metasomatic mantle.

  9. From Carbonatite to Ikaite: How high-T carbonates are transformed into low-T carbonate minerals in SW Greenland

    Stockmann, G. J.; Tollefsen, E.; Ranta, E.; Skelton, A.; Sturkell, E.; Lundqvist, L.


    The 1300 Ma Grønnedal-Íka igneous complex in southwest Greenland comprises nepheline syenites and carbonatites. It belongs to a suite of intrusions formed 1300-1100 Ma ago referred to as the Gardar period. In modern time (the last ca. 8000 years), fluid-rock interactions involving the nepheline syenites and carbonatites gives rise to about one thousand submarine columns made of the rare low-T mineral ikaite (CaCO3x6H2O). The columns are found in a shallow, narrow fjord named Ikka Fjord and their distribution clearly follows the outcrop of the Grønnedal-Íka complex. When meteoric water percolates through the highly fractured complex, a sodium carbonate solution of pH 10 is formed through hitherto unknown fluid-rock reactions. This basic solution seeps up through fractures at the bottom of Ikka Fjord and when mixed with seawater, the mineral ikaite is formed. As the seepage water has a lower density than seawater, there is an upwards flow that creates columns. What is peculiar about ikaite is its limited stability making it unstable above +6 °C. Isotopic studies of ikaite reveal a seawater origin for the Ca2+ ions, and the carbonatite being the most likely source for the CO32- ions. The carbonatite is mainly of søvite composition (CaCO3) with high contents of siderite and ankerite in certain areas. The nepheline syenites contain Na,K-rich minerals like nepheline, alkali-feldspar, aegirine-augite, katophorite and biotite. Nepheline is mainly replaced by muscovite, and aegirine-augite partly by chlorite, which could release sodium into solution. A dolerite dyke of unknown age prompted extensive mineralization of magnetite by activating hydrothermal fluid convection. The fluid interacted with the carbonatite, replacing siderite and ankerite by magnetite and later hematite. In a newly launched project at Stockholm University, we are trying to unravel the chemical reactions taking place inside the Grønnedal-Íka igneous complex leading to the formation of the

  10. Origin of heavy REE mineralisation in carbonatites: Constraints form the Huanglongpu Mo-HREE deposit, Qinling, China.

    Smith, Martin; Cheng, Xu; Kynicky, Jindrich; Cangelosi, Delia; Wenlei, Song


    The carbonatite dykes of the Huanglongpu area, Lesser Qinling, China, are unusual in that they are quartz-bearing, Mo-mineralised and enriched in the heavy rare earth elements (HREE) relative to typical carbonatites. Carbonatite monazite (208.9±4.6 Ma to 213.6±4.0; Song et al., 2016) gives a comparable U-Pb radiometric age to molybdenite (220Ma; Stein et al., 1997), confirming interpretations that Mo is derived from the carbonatite, and not a subsequent overprint from regional porphyry-style mineralisation ( 141Ma). The sulphides in the carbonatites have mantle-like 34S ( 1‰) and low δ26Mg values (-1.89 to -1.07‰), similar to sedimentary carbonates, suggesting a recycled sediment contribution in their mantle sources that may be responsible for the Mo and HREE enrichment (Song et al., 2016). The textures of REE minerals indicate crystallisation of monazite-(Ce), bastnäsite-(Ce), parisite-(Ce) and aeschynite-(Ce) as magmatic phases. Monazite-(Ce) was subsequently altered to produce apatite, which was in turn replaced by britholite-(Ce), accompanied by the formation of allanite-(Ce). The REE-fluorcarbonates where replaced by synchysite-(Ce) and röntgenite-(Ce). Aeschynite-(Ce) was altered initially to uranopyrochlore and then pyrochlore with uraninite inclusions. The mineralogical evolution reflects the evolution from magmatic carbonatite, through to more silica-rich conditions during the magmatic-hydrothermal transition, to fully hydrothermal conditions accompanied by the formation of sulphate minerals. Each alteration stage resulted in the preferential leaching of the LREE and enrichment in the HREE. Mass balance considerations indicate that the HREE enrichment could not be a passive process, and that hydrothermal fluids must have contributed HREE to the system. The evolution of the fluorcarbonate mineral assemblage requires an increase in aCa2+ and aCO32- in the metasomatic fluid, and so breakdown of HREE-enriched calcite may have been the HREE source

  11. River dykes investigation using seismic surface waves

    Bitri, Adnand; Jousset, Philippe; Samyn, Kévin; Naylor, Adam


    Natural underground caves such as karsts are quite common in the region "Centre", France. These subsurface perturbations can be found underneath the protection dykes around "the Loire" River and the damage caused can create routes for floods. Geophysical methods such as Multi-channel Analysis of Surface Waves (MASW) can be used for locating voids or karsts systems, but its efficiency on surface with strong topography such as dykes is not certain. Three dimensional Rayleigh wave modelling was used to understand the role of topography in the propagation of surface waves and with the aim of determining the best way for MASW investigations of surfaces with strong topography such as river dykes. Numerical modelling shows that surface waves propagation is not strongly affected by topography for an array parallel to the dyke. For homogeneous models with topography, a diminution of surface waves amplitude is observed while higher propagation modes are amplified in the dispersion curves in the case of heterogeneous models with topography. For an array perpendicular to the dyke, numerical modeling shows that Rayleigh waves' velocity is lower. MASW investigations can then be applied if lateral variations of the topography are not too strong along the seismic line. Diffraction hyperbolas created by a full of water cavity were identified in numerical modelling with topography. According to these elements, a MASW survey has been performed on the dykes of "the Loire" river close to a collapsed cavity and potential karstic systems were discovered.

  12. Magnesium isotope fractionation during carbonatite magmatism at Oldoinyo Lengai, Tanzania

    Li, Wang-Ye; Teng, Fang-Zhen; Halama, Ralf; Keller, Jörg; Klaudius, Jurgis


    To investigate the behaviour of Mg isotopes during carbonatite magmatism, we analyzed Mg isotopic compositions of natrocarbonatites and peralkaline silicate rocks from Oldoinyo Lengai, Tanzania. The olivine melilitites from the vicinity of Oldoinyo Lengai have homogeneous and mantle-like Mg isotopic compositions (δ26Mg of -0.30 to -0.26‰), indicating limited Mg isotope fractionation during mantle melting. The highly evolved peralkaline silicate rocks not related to silicate-carbonatite liquid immiscibility, including phonolites from the unit Lengai I, combeite-wollastonite nephelinites (CWNs) from the unit Lengai II A and carbonated combeite-wollastonite-melilite nephelinites (carbCWMNs), have δ26Mg values (from -0.25 to -0.10‰) clustered around the mantle value. By contrast, the CWNs from the unit Lengai II B, which evolved from the silicate melts that were presumably generated by silicate-carbonatite liquid immiscibility, have heavier Mg isotopes (δ26Mg of -0.06 to +0.09‰). Such a difference suggests Mg isotope fractionation during liquid immiscibility and implies, based on mass-balance calculations, that the original carbonatite melts at Lengai were isotopically light. The variable and positive δ26Mg values of natrocarbonatites (from +0.13 to +0.37‰) hence require a change of their Mg isotopic compositions subsequent to liquid immiscibility. The negative correlations between δ26Mg values and contents of alkali and alkaline earth metals of natrocarbonatites suggest Mg isotope fractionation during fractional crystallization of carbonatite melts, with heavy Mg isotopes enriched in the residual melts relative to fractionated carbonate minerals. Collectively, significant Mg isotope fractionation may occur during both silicate-carbonatite liquid immiscibility and fractional crystallization of carbonatite melts, making Mg isotopes a potentially useful tracer of these processes relevant to carbonatite petrogenesis.

  13. Determining dyke-propagation paths at Santorini volcano, Greece

    Drymoni, Kyriaki; Browning, John; Lecoeur, Nora; Gudmundsson, Agust


    The volcanic Island of Santorini constitutes a complex of collapse calderas which has experienced a range of explosive and effusive volcanic eruptions and is still active. Numerous stratigraphic horizons which constitute the upper part of the volcano have widely different mechanical properties, resulting in local stresses that may act as dyke-traps, preventing the dykes from reaching the surface to erupt. Several caldera collapses (<3.6 ka) have exposed part of the stratigraphy and a dyke swarm (composed of at least 63 dykes, many arrested and some feeders) within a section of the northern caldera wall, allowing detailed examination. This ongoing study will (1) document the petrological and structural characteristics of feeder and non-feeder (arrested) dykes and estimate their frequency; (2) determine the physiochemical and mechanical conditions that control dyke arrest/dyke penetration at contacts between layers; (3) explore the fluid and mechanical conditions of the associated magma chamber(s) that must be satisfied for chamber rupture and dyke injection to occur; (4) make numerical and probabilistic models as to the likely dyke paths in heterogeneous and anisotropic crustal segments/volcanoes (such as Santorini), including the likelihood of injected dykes reaching the surface during an unrest period in a volcano of a given type; (5) compare the data collected from Santorini with existing data on dykes worldwide, particularly those on dykes in Tenerife and Iceland. The principal aim of the study is to provide models that, during an unrest period in Santorini and other similar volcanoes, allow us to forecast (a) the condition for magma-chamber rupture and dyke injection, and (b) the likely path of the resulting dyke. The latter includes assessment of the likelihood as to dyke arrest versus dyke propagation to the surface, the latter resulting in an eruption. For dyke-fed eruptions, the study will also provide methods for forecasting the likely volumetric flow

  14. Magma transport in sheet intrusions of the Alnö carbonatite complex, central Sweden.

    Andersson, Magnus; Almqvist, Bjarne S G; Burchardt, Steffi; Troll, Valentin R; Malehmir, Alireza; Snowball, Ian; Kübler, Lutz


    Magma transport through the Earth's crust occurs dominantly via sheet intrusions, such as dykes and cone-sheets, and is fundamental to crustal evolution, volcanic eruptions and geochemical element cycling. However, reliable methods to reconstruct flow direction in solidified sheet intrusions have proved elusive. Anisotropy of magnetic susceptibility (AMS) in magmatic sheets is often interpreted as primary magma flow, but magnetic fabrics can be modified by post-emplacement processes, making interpretation of AMS data ambiguous. Here we present AMS data from cone-sheets in the Alnö carbonatite complex, central Sweden. We discuss six scenarios of syn- and post-emplacement processes that can modify AMS fabrics and offer a conceptual framework for systematic interpretation of magma movements in sheet intrusions. The AMS fabrics in the Alnö cone-sheets are dominantly oblate with magnetic foliations parallel to sheet orientations. These fabrics may result from primary lateral flow or from sheet closure at the terminal stage of magma transport. As the cone-sheets are discontinuous along their strike direction, sheet closure is the most probable process to explain the observed AMS fabrics. We argue that these fabrics may be common to cone-sheets and an integrated geology, petrology and AMS approach can be used to distinguish them from primary flow fabrics.

  15. Isotopic constraints of mantle derived carbonatitic melts from Calatrava, Spain

    Humphreys, E. R.; Bailey, K.; Hawkesworth, C. J.; Wall, F.; Avanzinelli, R.


    Carbonatite volcanism is typically associated both spatially and temporally with alkaline, ultramafic volcanism (Woolley & Church, 2005). Recent discoveries in Calatrava, Spain illustrate the activity of carbonatite in the source melts of leucitite volcanism. Melilitite pyroclastic lapilli tuffs also show a clear association with volcanic carbonate. Carbonatitic activity has been shown to initiate at depths greater than 100km (Humphreys et al., 2010) despite a maximum estimate of lithospheric thickness of 80km. The presence of aragonite and abundant mantle xenoliths in many deposits are clear indication of the rapid emplacement rates of such magmas. Carbonatitic activity in the source of the leucitite melts is indicated by carbonate inclusions within olivine xenocrysts and the presence of occasional carbonatite lenses. The composition of lead and strontium isotope ratios in the bulk rock, and spatially resolved analysis of carbonate from the groundmass and from inclusions demonstrates a genetic affinity between the inclusions and the related bulk rock composition. Lead and strontium isotopic analysis suggest that such melts do not represent the composition of convecting asthenospheric mantle. 87Sr/86Sr (0.7055-0.7068) values are higher than those of MORB and most OIB. Lead isotope ratios show a trend displaced to higher 207Pb/204Pb relative to MORB and OIB. Carbonate inclusions have less radiogenic lead values than the more radiogenic bulk rocks. Our data indicate that carbonatitic activity in the mantle is intrinsic in the generation of the leucitite lava. However, petrographic and isotopic evidence suggest a complex melt history. Olivine xenocrysts are not in equilibrium with the host leucitite, despite inclusions within olivine showing an isotopic affinity to the bulk rock. We suggest that in this example, alkaline magmatism was induced by the presence of CO2 in the mantle source. Isotopic evidence shows that the mantle producing such melts was not

  16. Vegetation dynamics and erosion resistance of sea dyke grassland

    Sprangers, J.T.C.M.


    In the Netherlands, in addition to the width and height of the dyke body itself, renewed measures for reconstruction and maintenance of dykes have stressed the importance to the safeguarding of the dyke, of the grass cover's protection of the clay-layer against erosion.


  17. Vegetation dynamics and erosion resistance of sea dyke grassland

    Sprangers, J.T.C.M.


    In the Netherlands, in addition to the width and height of the dyke body itself, renewed measures for reconstruction and maintenance of dykes have stressed the importance to the safeguarding of the dyke, of the grass cover's protection of the clay-layer against

  18. Vegetation dynamics and erosion resistance of sea dyke grassland

    Sprangers, H.


    In the Netherlands, in addition to the width and height of the dyke body itself, renewed measures for reconstruction and maintenance of dykes have stressed the importance to the safeguarding of the dyke, of the grass cover's protection of the clay-layer against erosion.From an inventory of different

  19. Dyke belt in North Western margin of Siberian platform

    Ryabov, Victor


    The Early Triassic dyke swarm belt is strengthening at about 500 km (50-60 km width) along the northern margin of Siberian platform. Its locations is limited from the north by rift structure of the Yenisei-Khatanga trough, and from the south by Kystyktah-Ayan-Ambardah uprise. From west to east dyke belt is crossing Norilsk, Kamensky and Maimecha-Kotuiskaya province. In this direction the composition of dykes changing from basic rthrough alkali-basic to alkali-ultramafic varieties. The sickness of dykes varies from 0,5-10m up to 90 m and length - from 5-15 m to 140 km. The orientation of the bulk of dykes coincides with the direction of the major structural and tectonic lineaments of the region. Dykes are often refer to the fault planes. The composition of dykes may vary along the stretches. The density of hundreds of basaltic dykes and small intrusions in the dyke swarms is not permanent and sometimes essentially uneven. They form a compact dyke swarms of dykes, stocks and sub layering bodies veins. In dyke package on Huor-Uyallah river here are 20 subparallel dykes of different chemical composition at a distance of 2 km Lack of the evidence of the dykes crossing allows to assume their formation during the same magmatic cycle. Dykes cross cut through the entire incision of basaltic plateau. They did not created the flow effusions and refer to the final stage trap magmatism. Ar/Ar age of the youngest dykes in the province Kamenska 238-247 Ma. the age of lamproite dyke in Norilsk province is 235 Ma. Dykes are represented by dolerites trachydolerites, syenites, minettes, lamprophyres (camptonite, spessartite, vosgesite), avgitites, melanephelinite, alnoites, limburgites alkaline picrites, meimechites. Their content vary widely: SiO2 - 35,7-62,6; TiO2- 0,4-7,5; Al2O3- 4,4-17,5; Fe2O3- 4,6-20,6; MnO- 0,08-0,44; MgO- 0,8-31,5; CaO- 0,7-15,4; Na2O- 0,01-6,5; K2O 0,8-5,3 wt.%; P2O5 0,1-1,2 wt.%. The h Bolsheavamskaya volcanic basin in Kamensky province is most abundant in

  20. Dyke Davidoff Masson Syndrome: A case report

    More Sumeet S, Jadhav Aravinash L, Garkal Shailendra M, Tewari Suresh C


    Full Text Available Dyke-Davidoff-Masson syndrome (DDMS is characterized by seizures, facial asymmetry, contralateral hemiplegia and mental retardation. The characteristic radiologic features are cerebral hemiatrophy with homolateral hypertrophy of the skull and sinuses. We report a case of DDMS in an 18years old girl who presented with a history of generalized tonic – clonic seizures, hemiparesis and hemiatrophy of right side.

  1. Insights into the late-stage differentiation processes of the Catalão I carbonatite complex in Brazil: New Sr-Nd and C-O isotopic data in minerals from niobium ores

    Oliveira, Ítalo L.; Brod, José A.; Cordeiro, Pedro F. O.; Dantas, Elton L.; Mancini, Luis H.


    The Late Cretaceous Catalão I carbonatite complex consists of ultramafic silicate rocks, phoscorites, nelsonites and carbonatites. The latest stages of the evolution of the complex are characterized by several nelsonite (magnetite-apatite rock) and carbonatite dykes, plugs and veins crosscutting earlier alkaline rocks. The interaction between the latter and late-stage carbonatites and/or carbo-hydrothermal fluids, converted the original dunites and bebedourites to metasomatic phlogopitites. Late-stage nelsonites (N1), pseudonelsonites (N2) and various types of dolomite carbonatites (DC) including norsethite-, magnesite- and/or monazite-bearing varieties show significant whole-rock Nd and Sr isotopic variations. To elucidate whether magmatic or metasomatic processes, or both, were responsible for these isotope variations we characterized the Nd and Sr isotope compositions of major mineral phases (i.e. apatite, dolomite, norsethite, pyrochlore and tetraferriphlogopite) in these late-stage rocks. Mineral isotope data recorded the same differences observed between N1 and N2 whole-rocks with N2 minerals showing more enriched isotopic signatures than minerals from N1. Sr isotopic disequilibrium among minerals from N2 pseudonelsonites and spatially related dolomite carbonatite pockets implies formation from batches of carbonate melts with distinct isotopic compositions. A detailed investigation of Nd and Sr isotopes from whole-rocks and minerals suggests that the most evolved rocks of the Catalão I complex probably derive from two different evolution paths. We propose that an earlier magmatic trend (path A) could be explained by several batches of immiscible and/or residual melts derived from carbonated-silicate parental magma (e.g. phlogopite picrite) contaminated with continental crust to a variable extent, in an AFCLI-like process. A second trend (path B) comprises highly variable 143Nd/144Ndi at nearly constant 87Sr/86Sri coupled with high δ18O in carbonates. This

  2. Magnetotelluric investigation of the Alnö alkaline and carbonatite ring complex, central Sweden

    Yan, Ping; Andersson, Magnus; Garcia Juanatey, Maria A.; Shan, Chunling; Malehmir, Alireza; Pedersen, Laust B.


    Alnö complex, 553-590 Ma, located in central Sweden, is one of the largest of few known alkaline and carbonatite ring intrusions in the world. The complex primarily consists of alkaline silicate rocks (ijolite, nepheline-syenite and pyroxenite) and a wide range of carbonatite dykes with different compositions (e.g., sövite). To better understand the intrusion mechanism(s) and the deeper structure of the intrusion, three high-resolution reflection seismic, gravity and magnetic profiles, crossing the main intrusion, were acquired in winter 2010. Together with these, petrophysical measurements on various rock samples have also been carried out. These data not only successfully showed the lateral extension of the intrusion at depth but also suggested a solidified saucer-shaped magma chamber at about 3 km depth that is associated with caldera-related ring-type fault systems. To further elucidate these interpretations, magnetotelluric (MT) data were acquired in summer 2013. The MT data were measured at 34 stations across the intrusion and designed so that a 3D conductivity model can be obtained. Most of the sites are located along the seismic profiles, while the rest is distributed over the intrusion area, to provide lateral and off-profile information. The time series were recorded with four broadband MT instruments simultaneously. The used sampling rates were 1000 Hz (two hours after midnight) and 20 Hz (a full day). The collected MT data are highly influenced by noise from cultural sources. Luckily, higher frequencies are less influenced providing a good coverage of the interest depth of about 5 km. Therefore, the data processing and analysis focused solely on the high frequency data. To decrease the effect of noise, the best quality site in one day was chosen for remote referencing the other three. Even if the sites were only 500 to 1000 m apart, better results were obtained, indicating very localized noise sources in the area. The strike analysis of the obtained

  3. Geochemistry and petrology of mafic Proterozoic and Permian dykes on Bornholm, Denmark:

    Holm, Paul Martin; Pedersen, Lise E.; Højsteeen, Birte


    ), 1220 Ma (narrow dykes), 950 Ma (Kaas and Listed dykes), and 300 Ma (NW-trending dykes), respectively.The largest dyke at Kelseaa (60 m wide) and some related dykes are primitive olivine tholeiites, one of which has N-type MORB geochemical features; all are crustally contaminated.The Kelseaa type magmas...

  4. Preliminary palaeomagnetic results from the Fen carbonatite complex, S. Norway

    Poorter, R.P.E.


    Samples from a hematite carbonate rock of the Eocambrian-Lower Cambrian Fen carbonatite-alkaline rock complex in southern Norway, yield a stable NRM with a direction after magnetic cleaning of D = 205°, I = −56° (N = 19, (k = 138, α95 = 3°). This corresponds with a palaeomagnetic pole position at

  5. Geochemistry of Monazite within Carbonatite Related REE Deposits

    Wei Chen


    Full Text Available Approximately >50% of global rare earth element (REE resources are hosted by carbonatite related deposits, of which monazite is one of the most important REE minerals. Monazite dominates more than 30 carbonatite-related REE deposits around the world, including currently exploited mineralization at Bayan Obo and Mount Weld. These deposits are widely distributed across all continents, except Antarctica. Though rare, monazite occurs as the primary mineral in carbonatite, and mostly presents as a secondary mineral that has a strong association with apatite. It can partially or completely replace thin or thick overgrowth apatite, depending on the availability of REE. Other mineral phases that usually crystallize together with monazite include barite, fluorite, xenotime, sulfide, and quartz in a carbonate matrix (e.g., dolomite, calcite. This review of monazite geochemistry within carbonatite-related REE deposits aims to provide information regarding the use of monazite as a geochemical indicator to track the formation history of the REE deposits and also supply additional information for the beneficiation of monazite. The chemical compositions of monazite are highly variable, and Ce-monazite is the dominant solid solution in carbonatite related deposits. Most monazite displays steep fractionation from La to Lu, absent of either Eu or Ce anomalies in the chondrite normalized REE plot. The other significant components are huttonite and cheratite. Some rare sulfur-bearing monazite is also identified with an SO3 content up to 4 wt %. A 147Sm/144Nd ratio with an average ~0.071 for monazite within carbonatite-related ores is similar to that of their host rocks (~0.065, and is the lowest among all types of REE deposits. Sm/Nd variation of monazite from a single complex reflects the differentiation stage of magma, which decreases from early to late. Based on the differences of Nd and Sr abundances, Nd isotopic composition for monazite can be used to track

  6. Chemical Compositions of Calcites in Carbonatites from Panxi Region Implications for Genesis of Carbonatites and Associated REE Deposits

    XU Cheng; HUANG Zhi-long


    @@ The Panxi region is important REE mineralization belt in China. Chemical compositions of calcites in carbon-atites from Daluxiang and Maoniuping REE deposits are analyzed by LA-ICPMS. At Maoniuping the reserve of REE2O3 is estimated to be more than 1.45 million tons.

  7. Fluorapatite in carbonatite-related phosphate deposits: the case of the Matongo carbonatite (Burundi)

    Decrée, Sophie; Boulvais, Philippe; Tack, Luc; André, Luc; Baele, Jean-Marc


    The Matongo carbonatite intrusive body in the Neoproterozoic Upper Ruvubu alkaline plutonic complex (URAPC) in Burundi is overlain by an economic phosphate ore deposit that is present as breccia lenses. The ore exhibits evidence of supergene enrichment but also preserves textures related to the concentration of fluorapatite in the carbonatitic system. Magmatic fluorapatite is abundant in the ore and commonly occurs as millimeter-sized aggregates. It is enriched in light rare earth elements (LREE), which is especially apparent in the final generation of magmatic fluorapatite (up to 1.32 wt% LREE2O3). After an episode of metasomatism (fenitization), which led to the formation of K-feldspar and albite, the fluorapatite-rich rocks were partly brecciated. Oxygen and carbon isotope compositions obtained on the calcite forming the breccia matrix (δ18O = 22.1 ‰ and δ13C = -1.5 ‰) are consistent with the involvement of a fluid resulting from the mixing of magmatic-derived fluids with a metamorphic fluid originating from the country rocks. In a subsequent postmagmatic event, the carbonates hosting fluorapatite were dissolved, leading to intense brecciation of the fluorapatite-rich rocks. Secondary carbonate-fluorapatite (less enriched in LREE with 0.07-0.24 wt% LREE2O3 but locally associated with monazite) and coeval siderite constitute the matrix of these breccias. Siderite has δ18O values between 25.4 and 27.7 ‰ and very low δ13C values (from -12.4 to -9.2 ‰), which are consistent with the contribution of organic-derived low δ13C carbon from groundwater. These signatures emphasize supergene alteration. Finally, the remaining voids were filled with a LREE-poor fibrous fluorapatite (0.01 wt% LREE2O3), forming hardened phosphorite, still under supergene conditions. Pyrochlore and vanadiferous magnetite are other minerals accumulated in the eluvial horizons. As a consequence of the supergene processes and fluorapatite accumulation, the phosphate ore, which

  8. Melting carbonated epidote eclogites: carbonatites from subducting slabs

    Poli, Stefano


    Current knowledge on the solidus temperature for carbonated eclogites suggests that carbonatitic liquids should not form from a subducted oceanic lithosphere at sub-arc depth. However, the oceanic crust includes a range of gabbroic rocks, altered on rifts and transforms, with large amounts of anorthite-rich plagioclase forming epidote on metamorphism. Epidote disappearance with pressure depends on the normative anorthite content of the bulk composition; we therefore expect that altered gabbros might display a much wider pressure range where epidote persists, potentially affecting the solidus relationships. A set of experimental data up to 4.6 GPa, and 1000 °C, including new syntheses on mafic eclogites with 36.8 % normative anorthite, is discussed to unravel the effect of variable bulk and volatile compositions in model eclogites, enriched in the normative anorthite component ( An 37 and An 45). Experiments are performed in piston cylinder and multianvil machines. Garnet, clinopyroxene, and coesite form in all syntheses. Lawsonite was found to persist at 3.7 GPa, 750 °C, with both dolomite and magnesite; at 3.8 GPa, 775-800 °C, fluid-saturated conditions, epidote coexists with kyanite, dolomite, and magnesite. The anhydrous assemblage garnet, omphacite, aragonite, and kyanite is found at 4.2 GPa, 850 °C. At 900 °C, a silicate glass of granitoid composition, a carbonatitic precipitate, and Na-carbonate are observed. Precipitates are interpreted as evidence of hydrous carbonatitic liquids at run conditions; these liquids produced are richer in Ca compared to experimental carbonatites from anhydrous experiments, consistently with the dramatic role of H2O in depressing the solidus temperature for CaCO3. The fluid-absent melting of the assemblage epidote + dolomite, enlarged in its pressure stability for An-rich gabbros, is expected to promote the generation of carbonatitic liquids. The subsolidus breakdown of epidote in the presence of carbonates at depths

  9. Geochemistry of Mesozoic carbonatite complexes in the southwestern part of Greenland

    Park, B.; Lee, J.; Lee, M.


    This is the results of geochemical analysis of carbonatite taken at the kimberlite and carbonatite complexes in Tikilusaag and Qaqarssuk located in the southwestern part of Greenland. These complexes have high grade of rare earth elements (REE), gold, olivine and diamond ore deposits. These kimberlite, lamprophyre and carbonatite are originated from complex carbonatitic and silicate magma. This kind of ultramafic alkaline complex is not common compared to other igneous bodies in the crust. Tikilusaag carbonatite complex in contains REE in calcite carbonatite. Carbonatite minerals are strontianite (SrCO3) and ancylite (SrCe(CO3)2(OH)H2O). Strontianite contains Ce and ancylite contains considerable amounts of La, Ce, Nd, respectively. Two minerals are the major components which have LREE in the complexes. Tikilussaaq carbonatite complex contain apatite which has maximum 200 micro meter in size and mostly euhedral. Most apatite crystals show compositional zoning under CL attached to SEM (JEOL, JSM-6610). This zoning reflects physiochemical condition of magma at the time of crystallization and the compositional difference of Ca, P, and F with the consideration of chemical composition of apatite. The apatite contain F instead of Cl, namely fluorine apatite. Compositional zoning reflect the difference of Ca and P according to CL image. Qaqarssuk carbonatite complex is consisted of several minerals containing Ba composition. Ba in calcite which is the major mineral of Ba carbonatite (Barytocalcite, CaBa(CO3)2) coexists with barite and Ba-Sr carbonatite. Fenitization near the complex is common process. Basic rocks formed during carbonatitization contain hornblendite predominantly, and high grade of fenitization produced albite-bearing granitic rocks in the area.

  10. Bases of the Mantle-Carbonatite Conception of Diamond Genesis

    Litvin, Yuriy; Spivak, Anna; Kuzyura, Anastasia


    In the mantle-carbonatite conception of diamond genesis, the results of physic-chemical experiments are coordinated with the data of analytic mineralogy of primary inclusions in natural diamonds. Generalization of the solutions of principal genetic problems constitutes the bases of the conception. The solutions are following: (1) it is grounded that diamond-parental melts of the upper mantle have peridotite/eclogite - carbonatite - carbon compositions, of the transition zone - (wadsleite↔ringwoodite) - majorite - stishovite - carbonatite - carbon compositions, and of the lower mantle - periclase/wustite - bridgmanite - Ca-perovskite -stishovite - carbonatite - carbon compositions; (2) a construction of generalized diagrams for the diamond-parental media, which reveal changeable compositions of the growth melts of diamonds and associated phases, their genetic relations to the mantle substance, and classification connections of the primary inclusions in natural diamonds; (3) experimental equilibrium phase diagrams of syngenesis of diamonds and primary inclusions, which characterize the nucleation and growth conditions of diamonds and a capture of paragenetic and xenogenetic minerals by the growing diamonds; (4) a determination of the phase diagrams of diamonds and inclusions syngenesis under the regime of fractional crystallization, which discover the regularities of ultrabasic-basic evolution and paragenesis transitions in the diamond-forming systems of the upper and lower mantle. The evidence of the physic-chemically united mode of diamond genesis at the mantle depths with different mineralogy is obtained. References. Litvin Yu.A. (2007). High-pressure mineralogy of diamond genesis. In: Advances in High-Pressure Mineralogy (edited by Eiji Ohtani), Geological Society of America Special paper 421, 83-103. Litvin Yu.A. (2012). Experimental study of physic-chemical conditions of natural diamond formation on an example of the eclogite-carbonatite

  11. Engineering geotextile tubes to be used in dyke construction

    ZHU Yuan-sheng


    Geotextile tube technology has been increasingly used in dykes. In this work reinforcement theory and circle method were employed to examine the allowable tensile limit of the geotextile tube and the stability factor of the slip surface of the dyke. The formulas to calculate the layer-to-layer spacing and size of geotextile tubes applied to double prism dykes were deduced. The application of these formulas was illustrated by several examples. The calculation results indicate that unequal spacing arrangement is more economical than equal spacing and the layer number of required geotextile tubes decreases with the increase of allowable tensile strength of the geotextile.

  12. Geochemical and mineralogical characteristics of the Yonghwa phoscorite-carbonatite complex, South Korea, and genetic implications

    Seo, Jieun; Choi, Seon-Gyu; Park, Jung-Woo; Whattam, Scott; Kim, Dong Woo; Ryu, In-Chang; Oh, Chang Whan


    The Yonghwa phoscorite-carbonatite complex occurs as an isolated individual body with an inclined pipe shape within the Precambrian Gyeonggi Massif, South Korea. The phoscorite consists mainly of olivine, apatite, magnetite, carbonates, amphibole, and phlogopite, and can be subdivided into two types, olivine-rich and apatite-rich. The carbonatite is composed of calcite, Mg-rich dolomite, Fe-rich dolomite, magnetite, apatite, and/or siderite. Intensive fenitization occurred along the boundary between the complex and the wall rocks of leucocratic banded gneiss and garnet-bearing metabasite. The paragenetic sequences of the phoscorite-carbonatite complex demonstrate that the early crystallization of silicate minerals was followed by the crystallization of carbonates as the carbonatitic melt cooled. Magnetite occurs within the complex, and the carbonatites have Fe contents that are higher than typical ferrocarbonatites, due to the high magnetite contents. The rare earth elements (REEs) in the phoscorites and carbonatites are weakly fractionated and show enrichments of LREEs and Nb relative to HREEs. Furthermore, the apatites reflect the fractionated trends of LREEs relative to HREEs. Phoscorite apatites are enriched in Sr and show substitutions between Ca and Sr. Mica chemistry reflects the evolutionary trend of Fe2 + and Mg2 + in the phoscorite-carbonatite melt without Al substitution. Micas exhibit high values of Mg# in the phoscorite-carbonatite complex, but lower values in fenites. Via thermodynamic analysis, the early stability fields of magnetite-pyrrhotite-graphite-carbonate assemblages indicate that the Yonghwa phoscorite and carbonatite crystallized under conditions of 600 °C, 2 kbar, and XCO2 = 0.2. Afterward, melts underwent an evolution to the late stability fields of magnetite-pyrite-pyrrhotite-ilmenite assemblages. The δ13C and δ18O isotopic compositions of carbonates in the Yonghwa phoscorite-carbonatite complex are - 8.2‰ to - 3.4‰ and 6.6 to 11

  13. Origin of unusual HREE-Mo-rich carbonatites in the Qinling orogen, China

    Song, Wenlei; Xu, Cheng; Smith, Martin P.; Kynicky, Jindrich; Huang, Kangjun; Wei, Chunwan; Zhou, Li; Shu, Qihai


    Carbonatites, usually occurring within intra-continental rift-related settings, have strong light rare earth element (LREE) enrichment; they rarely contain economic heavy REE (HREE). Here, we report the identification of Late Triassic HREE-Mo-rich carbonatites in the northernmost Qinling orogen. The rocks contain abundant primary HREE minerals and molybdenite. Calcite-hosted fluid inclusions, inferred to represent a magmatic-derived aqueous fluid phase, contain significant concentrations of Mo (~17 ppm), reinforcing the inference that these carbonatitic magmas had high Mo concentrations. By contrast, Late Triassic carbonatites in southernmost Qinling have economic LREE concentrations, but are depleted in HREE and Mo. Both of these carbonatite types have low δ26Mg values (-1.89 to -1.07‰), similar to sedimentary carbonates, suggesting a recycled sediment contribution for REE enrichment in their mantle sources. We propose that the carbonatites in the Qinling orogen were formed, at least in part, by the melting of a subducted carbonate-bearing slab, and that 10 Ma younger carbonatite magmas in the northernmost Qinling metasomatized the thickened eclogitic lower crust to produce high levels of HREE and Mo.

  14. Genesis of the Khaluta alkaline-basic Ba-Sr carbonatite complex (West Transbaikala, Russia)

    Doroshkevich, Anna G.; Ripp, German S.; Moore, Kathryn R.


    The Khaluta carbonatite complex comprizes fenites, alkaline syenites and shonkinites, and calcite and dolomite carbonatites. Textural and compositional criteria, melt inclusions, geochemical and isotopic data, and comparisons with relevant experimental systems show that the complex formed by liquid immiscibility of a carbonate-saturated parental silicate melt. Mineral and stable isotope geothermometers and melt inclusion measurements for the silicate rocks and carbonatite all give temperatures of crystallization of 915-1,000°C and 890-470°C, respectively. Melt inclusions containing sulphate minerals, and sulphate-rich minerals, most notably apatite and monazite, occur in all of the lithologies in the Khaluta complex. All lithologies, from fenites through shonkinites and syenites to calcite and dolomite carbonatites, and to hydrothermal mineralisation are further characterized by high Ba and Sr activity, as well as that of SO3 with formation of the sulphate minerals baryte, celestine and baryte-celestine. Thus, the characteristic features of the Khaluta parental melt were elevated concentrations of SO3, Ba and Sr. In addition to the presence of SO3, calculated fO2 for magnetites indicate a high oxygen fugacity and that Fe+3>Fe+2 in the Khaluta parental melt. Our findings suggest that the mantle source for Khaluta carbonatite and associated rocks, as well as for other carbonatites of the West Transbaikalia carbonatite province, were SO3-rich and characterized by high oxygen fugacity.

  15. Primary carbonatite melt from deeply subducted oceanic crust

    Walter, M.J.; Bulanova, G.P.; Armstrong, L.S.; Keshav, S.; Blundy, J.D.; Gudfinnesson, G.; Lord, O.T.; Lennie, A.R.; Clark, S.M.; Smith, C.B.; Gobbo, L.


    Partial melting in the Earth's mantle plays an important part in generating the geochemical and isotopic diversity observed in volcanic rocks at the surface. Identifying the composition of these primary melts in the mantle is crucial for establishing links between mantle geochemical 'reservoirs' and fundamental geodynamic processes. Mineral inclusions in natural diamonds have provided a unique window into such deep mantle processes. Here they provide exper8imental and geochemical evidence that silicate mineral inclusions in diamonds from Juina, Brazil, crystallized from primary and evolved carbonatite melts in the mantle transition zone and deep upper mantle. The incompatible trace element abundances calculated for a melt coexisting with a calcium-titanium-silicate perovskite inclusion indicate deep melting of carbonated oceanic crust, probably at transition-zone depths. Further to perovskite, calcic-majorite garnet inclusions record crystallization in the deep upper mantle from an evolved melt that closely resembles estimates of primitive carbonatite on the basis of volcanic rocks. Small-degree melts of subducted crust can be viewed as agents of chemical mass-transfer in the upper mantle and transition zone, leaving a chemical imprint of ocean crust that can possibly endure for billions of years.

  16. Geophysical Investigations of a Proterozoic Carbonatite Terrane, southeast Mojave Desert, California

    Denton, K. M.; Ponce, D. A.; Miller, D. M.; Peacock, J.; Miller, J. S.


    One of the world's largest rare-earth element-rich carbonatite deposits is located in the eastern Mojave Desert at Mountain Pass, California. The eastern Mojave Desert carbonatite terrane consists of a ~1.7 Ga gneiss and schist rocks that are host to a ~1.417 Ga (Premo, 2013) ultrapotassic intrusive suite (shonkinite, syenite, and granite) and a ~1.375 Ga (DeWitt, 1983) carbonatite deposit . Regional geophysical data indicate that this carbonatite terrane occurs within a north-northwest trending ~1-km wide bench in a gravity high and along the eastern edge of a prominent magnetic high in the eastern Clark Mountain Range. To improve our understanding of the geophysical and structural framework of the eastern Mojave carbonatite terrane, we collected over 2,300 gravity stations and over 640 physical rock property samples. Carbonatite rocks typically have distinct gravity, magnetic, and radioactive signatures because they are relatively dense, often contain magnetite, and are commonly enriched in thorium and/or uranium. Contrary to this trend, our results show that the carbonatite deposit is essentially nonmagnetic with an average susceptibility of 0.18 x 10-3 SI (n=31), and the ultrapotassic intrusive suite is very weakly magnetic with an average susceptibility of 2.0 x 10-3 SI (n=36). However, these rocks are found along a steep gradient of a prominent aeromagnetic anomaly. The lack of magnetic signature from the rocks of the eastern Mojave carbonatite terrane suggests alteration of magnetic minerals. This is corroborated by its location within a broader alteration zone and observed magnetic low. If so, such an alteration event occurred after emplacement of the carbonatite deposit, which likely remobilized rare earth elements in the surrounding rocks. Further, an alteration event is consistent with geology, high rare-earth element concentration, and unusual geochemistry of the carbonatite deposit. Temporal constraints (DeWitt, 1987; Premo, 2013) also suggest

  17. Local stresses, dyke arrest and surface deformation in volcanic edificesand rift zones

    L. S. Brenner


    Full Text Available Field studies indicate that nearly all eruptions in volcanic edifices and rift zones are supplied with magma through fractures (dykes that are opened by magmatic overpressure. While (inferred dyke injections are frequent during unrest periods, volcanic eruptions are, in comparison, infrequent, suggesting that most dykes become arrested at certain depths in the crust, in agreement with field studies. The frequency of dyke arrest can be partly explained by the numerical models presented here which indicate that volcanic edifices and rift zones consisting of rocks of contrasting mechanical properties, such as soft pyroclastic layers and stiff lava flows, commonly develop local stress fields that encourage dyke arrest. During unrest, surface deformation studies are routinely used to infer the geometries of arrested dykes, and some models (using homogeneous, isotropic half-spaces infer large grabens to be induced by such dykes. Our results, however, show that the dyke-tip tensile stresses are normally much greater than the induced surface stresses, making it difficult to explain how a dyke can induce surface stresses in excess of the tensile (or shear strength while the same strength is not exceeded at the (arrested dyke tip. Also, arrested dyke tips in eroded or active rift zones are normally not associated with dyke-induced grabens or normal faults, and some dykes arrested within a few metres of the surface do not generate faults or grabens. The numerical models show that abrupt changes in Young's moduli(stiffnesses, layers with relatively high dyke-normal compressive stresses (stress barriers, and weak horizontal contacts may make the dyke-induced surface tensile stresses too small for significant fault or graben formation to occur in rift zones or volcanic edifices. Also, these small surface stresses may have no simple relation to the dyke geometry or the depth to its tip. Thus, for a layered crust with weak contacts, straightforward

  18. The Daskop Granophyre Dyke: Inhomogeneous clast distribution and chemistry

    Kovaleva, Elizaveta; Huber, Matthew S.; Somers, Andrew; Bateman, Stuart


    The Vredefort Granophyre is present in the central basement of the Vredefort impact structure as a set of dykes up to 9 km long and up to 65 m wide and is considered to be the remnant of the impact melt sheet (e.g. French et al. 1989; French and Nielsen 1990). The dykes intruded into the floor of the structure's core during the crater modification and settling stages (e.g. Therriault et al. 1996). Granophyre is typically considered a well-homogenized and uniform melt (e.g., Nel 1927; Gibson and Reimold 2008). This study presents new insights into the chemical variety and inhomogeneous clast distribution of the Vredefort granophyre. The Granophyre dyke on the farm Daskop is located in the core of the impact structure and hosted by granitic gneiss of the Archean basement. The clast distribution was mapped in the eastern half of the dyke. Additionally, non-destructive geochemical methods (handheld µXRF and LIBS systems) were used to obtain chemical analysis of the dyke along strike. The map of clast distribution in the granophyre dyke reveals an inhomogeneous content of clasts, with a consistently higher concentration of clasts along the southern contact. This distribution suggests that either 1) the dyke orientation is non-vertical, allowing gravitational settling to affect the distribution of the clasts after the dyke intruded; or 2) that clasts were preferentially entrained along the southern margin of the dyke. Clast frequency also differs along strike. Many elongated clasts are oriented parallel to the dyke walls, indicating flow. We have also documented linear structures resembling flow channels. These structures are strictly parallel to the dyke walls and have a finer texture than the host granophyre. These may represent differentiation of the melt during crystallization. Chemical inhomogeneity of granophyre dyke has also been documented along strike. Such chemical variation may reflect local differences in the relative amounts of target rocks incorporated

  19. High Resolution Analysis of Dyke Tips and Segments, Using Drones

    Dering, G.; Micklethwaite, S.; Cruden, A. R.


    We analyse outstanding exposures of dykes from both coastal (Western Australia) and high altitude glacier-polished (Sierra Nevada, California) outcrops, representing intrusion at shallow upper-crustal and mid-crustal conditions respectively. We covered 10,000 m^2 of outcrop area sampling the ground at a scale of 3-5 mm per pixel. Using Structure-from-Motion photogrammetry from ground-based and UAV photographs lacking GPS camera positions (>500 images per study), we generated and calibrated a 3D geometry of dense point clouds by selectively using 25-30 ground control points measured by high precision GPS (40-90 mm error). Ground control points used in the photogrammetric model building process typically yielded a root mean square error (RMSE) of 5 cm. Half the ground control points were withheld from the model building process and when they were compared against the model they yielded RMSE values only 6-10% higher than the points used for georeferencing, suggesting good internal consistency of the dataset and accuracy relative to the reference frame, at least for the purposes of this study. The structural orientations of the dykes and associated fractures were then extracted digitally using the iterative Random Sample Consensus method (RANSAC) and least-squares plane fitting. Furthermore, fracture intensity relative to dykes was measured along a series of scanlines and the running average and variance calculated. All results were compared against field measurements. Results show fracture intensity increases toward the dykes in the shallow crustal examples (West Australia) but no such fractures exist around the mid-crustal (Californian) dykes. Despite this there is a remarkable uniformity of geometry, and by implication process, between the two dyke sets. In order to extract full value from the big visual data now available to us, the near-future requires dedicated research into software solutions for expert-driven, semi-automatic mapping of geology and structure.

  20. Dyke Foundation Classification%关于堤基的分段分类

    ZHANG; Jia-fa


    Main factors, which should be considered in the classification of dyke foundation, are discussed in this paper. Engineering conditions should be taken into accoun t when the levee safety is appraised based on engineering geologic appraisement and classificatio n. On the basis of safety appraisement, dyke foundation may be classified with regard of suitable r einforcement measures. Examples are presented to illustrate the instructive significance of dyke foundation cla ssification to dyke reinforcement design.

  1. Geochemistry and petrology of mafic Proterozoic and Permian dykes on Bornholm, Denmark:

    Holm, Paul Martin; Pedersen, Lise E.; Højsteeen, Birte


    More than 250 dykes cut the mid Proterozoic basement gneisses and granites of Bornholm. Most trend between NNW and NNE, whereas a few trend NE and NW. Field, geochemical and petrological evidence suggest that the dyke intrusions occurred as four distinct events at around 1326 Ma (Kelseaa dyke), 1...

  2. Temporal geoelectric behaviour of dyke aquifers in northern Deccan Volcanic Province, India

    Gautam Gupta; Vinit C Erram; Suyash Kumar


    Vertical electrical resistivity soundings (VES) were carried out over four major dykes of Nandurbar district in the northern Deccan Volcanic Province (DVP) of Maharashtra to investigate the subsurface geological conditions, with an aim of identifying zones with groundwater resource potential. Dykes can act as pathways or barrier to the groundwater flow depending upon the intensity of fracturing in the dyke rock. Whether the dykes act as water conduits or as barriers depends on their structure, location and orientation with respect to the groundwater flow. The Nandurbar district is known for occurrence of dykes and dyke swarms. A total of 33 dykes were demarcated in the study region and four major dykes (D4, D5, D6, and D7) from these were chosen for detailed VES studies. Data were acquired over these four dykes during pre-monsoon and post-monsoon periods to observe the seasonal variation in groundwater movement. These studies revealed changes in field characters, their attitudes, thickness and structure of the dykes. Longitudinal geoelectrical sections along these dykes demonstrated carrier as well as barrier stretches which identified potential aquifers up to depths of 25–30m below which hard and compact rock exists. These studies also indicated that dykes with sufficient width, length and favourable hydrogeological structure form potential aquifers for the occurrence and movement of groundwater in the study area.

  3. Investigation of Kpong carbonatite as a potential source for rare earth elements (REEs) using instrumental neutron activation analysis (INAA)

    Hayford, M.S.; Akiti, T.T.; Serfor-Armah, Y.; Dampare, S.B. [Ghana Univ., Accra (Ghana). School of Nuclear and Allied Sciences; Ghana Atomic Energy Commission (GAEC), Legon-Accra (Ghana). Nuclear Chemistry and Environmental Research Centre


    Instrumental neutron activation analysis (INAA) was used to investigate REEs in carbonatite from Kpong southeastern, Ghana. Total rare earth element (TREEs) obtain were in the range of 540 mg/kg to 705 mg/kg. The total number of rare earth elements (REEs) determined by INAA in the carbonatite rocks from Kpong were 11, namely; La, Ce, Nd, Sm, Eu, Tb, Dy, Ho, Tm, Yb, Lu. The INAA results from the carbonatite show a high enrichment of light rare earth elements (LREEs) deposits, marking the Kpong carbonatite as a potential REE source. (orig.)

  4. Wave overtopping erosion tests at Groningen sea dyke

    Akkerman, G.J.; van Gerven, K.A.J.; Schaap, H.A.; van der Meer, J.W.


    In the present report field erosion tests of the inner slope of a sea dyke in the province of Groningen (near Delfzijl) are described for the situation of severe wave overtopping. Three types of tests have been performed: tests at the present grass cover, tests at a reinforced grass cover and tests

  5. Contrasting petrogenesis of spatially related carbonatites from Samalpatti and Sevattur, Tamil Nadu, India

    Ackerman, Lukáš; Magna, Tomáš; Rapprich, Vladislav; Upadhyay, Dewashish; Krátký, Ondřej; Čejková, Bohuslava; Erban, Vojtěch; Kochergina, Yulia V.; Hrstka, Tomáš


    Two Neoproterozoic carbonatite suites of spatially related carbonatites and associated silicate alkaline rocks from Sevattur and Samalpatti, south India, have been investigated in terms of petrography, chemistry and radiogenic-stable isotopic compositions in order to provide further constraints on their genesis. The cumulative evidence indicates that the Sevattur suite is derived from an enriched mantle source without significant post-emplacement modifications through crustal contamination and hydrothermal overprint. The stable (C, O) isotopic compositions confirm mantle origin of Sevattur carbonatites with only a modest difference to Paleoproterozoic Hogenakal carbonatite, emplaced in the same tectonic setting. On the contrary, multiple processes have shaped the petrography, chemistry and isotopic systematics of the Samalpatti suite. These include pre-emplacement interaction with the ambient crustal materials with more pronounced signatures of such a process in silicocarbonatites. Calc-silicate marbles present in the Samalpatti area could represent a possible evolved end member due to the inability of common silicate rocks (pyroxenites, granites, diorites) to comply with radiogenic isotopic constraints. In addition, Samalpatti carbonatites show a range of C-O isotopic compositions, and δ13CV-PDB values between + 1.8 and + 4.1‰ found for a sub-suite of Samalpatti carbonatites belong to the highest values ever reported for magmatic carbonates. These heavy C-O isotopic signatures in Samalpatti carbonatites could be indicative of massive hydrothermal interaction with carbonated fluids. Unusual high-Cr silicocarbonatites, discovered at Samalpatti, seek their origin in the reaction of pyroxenites with enriched mantle-derived alkali-CO2-rich melts, as also evidenced by mantle-like O isotopic compositions. Field and petrographic observations as well as isotopic constraints must, however, be combined with the complex chemistry of incompatible trace elements as indicated

  6. Recycling of subducted crustal components into carbonatite melts revealed by boron isotopes

    Hulett, Samuel R. W.; Simonetti, Antonio; Rasbury, E. Troy; Hemming, N. Gary


    The global boron geochemical cycle is closely linked to recycling of geologic material via subduction processes that have occurred over billions of years of Earth’s history. The origin of carbonatites, unique melts derived from carbon-rich and carbonate-rich regions of the upper mantle, has been linked to a variety of mantle-related processes, including subduction and plume-lithosphere interaction. Here we present boron isotope (δ11B) compositions for carbonatites from locations worldwide that span a wide range of emplacement ages (between ~40 and ~2,600 Ma). Hence, they provide insight into the temporal evolution of their mantle sources for ~2.6 billion years of Earth’s history. Boron isotope values are highly variable and range between -8.6‰ and +5.5‰, with all of the young (-4.0‰), whereas most of the older carbonatite samples record lower B isotope values. Given the δ11B value for asthenospheric mantle of -7 +/- 1‰, the B isotope compositions for young carbonatites require the involvement of an enriched (crustal) component. Recycled crustal components may be sampled by carbonatite melts associated with mantle plume activity coincident with major tectonic events, and linked to past episodes of significant subduction associated with supercontinent formation.

  7. Dyke emplacement and propagation: a new laboratory approach

    Bakker, R.; Benson, P.; Vinciguerra, S.


    It is well known that magma ascends trough the crust by the process of dyking. During dyke movement crustal rocks, specifically the volcano's basement rocks, fracture due to the stress imposed by the ascending magma, thus providing conduits for magma transport. Dykes are frequently seen in the field and have been reproduced via numerical and analogue studies. However, a number of assumptions regarding rock mechanical behavior frequently has to be made as such data are very hard to directly measure at the pressure/temperature conditions of interest: high temperatures at relatively shallow depths. Such data are key to simulating the magma intrusion dynamics through the lithologies that underlie the volcanic edifice. To bridge this gap, we have performed a suite of rock deformation experiments in both compressive and tensile regimes, using a Paterson-type triaxial apparatus on representative lithologies present in the basement of Mt. Etna. In the compressive regime, we find that sedimentary rocks present at a depth of aproximately 2 km show a B/D transition at around 300 degC and significant weakening with temperatures exceeding 400 degC. Volcanic rocks (basalt) shows a significant change in deformation behavior only at temperatures exceeding 800 degC. Such a large contrast in mechanical properties could be favorable for dyke deflection or dyke arrest. However, in the tensile regime, it remains a significant technical challenge to precisely reproduce the conditions of dyking in the lab. As a starting point, we are now testing an analogue material to replace the magma to avoid such high temperatures, relying of maintaining similar temperature/viscosity ratios between magma/country rock in the laboratory and the field. We chose PMMA (a.k.a. plexiglass) for this task as it displays a large range in viscosities (log(visc)range = 10 - 1) with temperatures between 100 and 300 degC, making it an excellent analogue material. In addition PMMA solidifies after the sample cools

  8. Geochemistry of eastern North American CAMP diabase dykes

    Callegaro, S.; Marzoli, A.; Bertrand, H.; Reisberg, L. C.; Chiaradia, M.; Bellieni, G.


    The Piedmont area of the Appalachians and the coastal plains of eastern North America (ENA) were intruded between 202 and 195 Ma[1,2] by swarms of diabase (dolerite) dykes and a few sills of the Central Atlantic magmatic province (CAMP). Different trends are observed for the dykes, from NW (more frequent in the South), to N-S and NE, thus a radial pattern and a coeval emplacement driven by the bulging effect of a mantle plume were initially inferred[3]. Conversely, based on field data, an age progression can be defined from NW- to N- and NE-oriented dykes, supporting a diachronous northward rift-to-drift transition during Pangaea break-up. New geochemical data on 74 ENA dykes suggest a dominant lithospheric mantle source for these magmatic suite. A deep enriched mantle source is further discarded by the crystallization temperatures (ca.1350°C) calculated[4] for high-Fo (up to Fo89) olivines, which do not reflect very hot (i.e. mantle-plume) potential mantle temperatures. Incompatible trace element contents are fairly homogeneous and generally low, e.g. (La/Yb)Ch (0.54-2.39), typical of melts derived from a quite depleted shallow (spinel) mantle-source. However, isotopic compositions of ENA dykes display a considerable spread in initial isotopic signatures, do not show correlation with incompatible trace elements, and are independent of the orientation and age of the dykes, i.e. 87Sr/86Sr200Ma (0.7043-0.7088), ɛNd200Ma (-6.67-+2.42) and 206Pb/204Pb200Ma (17.46-18.61). Pb isotopic compositions plot above the NHRL, at positive Δ7/4 (10-17) and Δ8/4 (19-73), calling for an enriched ancient component in the mantle source. Unradiogenic 187Os/188Os200Ma ratios (0.127-0.144) argue for negligible amounts of crustal contamination and, coupled with the large range of Sr-Nd-Pb isotopic compositions, suggest generation from a strongly heterogeneous mantle source, probably metasomatized lithosphere. Lithospheric mantle underlying the Appalachian orogen may have undergone

  9. Crossed cerebro-cerebellar atrophy with Dyke Davidoff Masson syndrome.

    Algahtani, Hussein A; Aldarmahi, Ahmed A; Al-Rabia, Mohammed W; Young, G Bryan


    Dyke Davidoff Masson syndrome (DDMS) refers to atrophy or hypoplasia of one cerebral hemisphere following a prior fetal or childhood insult. It has characteristics of clinical and radiological changes. These changes include hemiparesis, seizures, facial-asymmetry, and mental retardation. We present a 25-year-old man with crossed cerebrocerebellar atrophy and DDMS. His seizures were well controlled using a combination of antiepileptic drugs.

  10. Effect of host-rock rheology on dyke shape, thickness and magma overpressure

    Vachon, Rémi; Hieronymus, Christoph F.


    The size and thickness of dykes is of fundamental importance for volcano dynamics because dykes are the primary path for magma transport, and because large numbers of dykes often comprise a major proportion of the volcanic edifice and of the underlying crust. Standard elastic models predict dyke geometry to be elliptic in cross-section for constant overpressure and uniform host-rock properties, whereas observations show that dyke thickness is typically more nearly constant with a sharp taper at the ends. Moreover, the predicted overpressures required to inflate dykes in a purely elastic medium are often significantly higher (>150 MPa and up to 2 GPa) than those estimated by other means (about 1-50 MPa). In this study, we use 2-D finite element models to test whether other host-rock rheologies lead to more realistic dyke shapes and overpressures. We examine three different rheologies, each of which is affected by the presence of the dyke itself: (1) elasticity with reduced moduli in regions of low pressure or tension; (2) elastoplasticity with plastic failure in the high-stress regions surrounding the dyke tips; (3) viscoelasticity with a viscosity decrease due to heating by the dyke. We use rheological parameters obtained from laboratory experiments whenever possible, and assume static conditions for the final dyke shape. We find that all three rheologies tend to make the dyke more rectangular relative to the elliptical dykes of the linearly elastic models. The change in shape is due to enhanced deformation in the high-stress zone surrounding the dyke tip. We also find that the overpressure required to inflate an initially thin dyke to a given thickness is reduced for all three rheologies. The greatest decrease in overpressure by a factor of about 0.1 is observed for the elastoplastic model, and for the viscoelastic model if the dyke intrudes into moderately pre-heated host-rock. We discuss our results with respect to dyke observations from Rum Island (Scotland

  11. The paleomagnetism and geological significance of Meso- proterozoic dyke swarms in the central North China Craton


    The Mesoproterozoic mafic dyke swarms are extensively distributedin the central North China Craton(NCC) including North Shanxi, Wutai and Lüliang areas, which are not deformed and metamorphic but high magnetic, so the dyke swarms become the mark to compare the high meta-morphic rock areas in magnetism. Based on the analysis of paleomagnetism of mafic dyke swarms in North Shanxi, Wutai and Lüliang areas, NCC inclined southward about 18° so that North Shanxi lifted up and rotated 10° left to Wutai area. The dyke swarms in Lüliang developed later than in North Shanxi and Wutai area. The NNW-trending and WNW-trending dyke swarms developed in Lüliang while the North China Plate moved northward consistently so that the paleomagnetism of dyke swarms in Lüliang is greatly different from North Shanxi and Wutai area.

  12. Geology and geochemistry of newly discovered Tertiary carbonatite occurrences near Villa Ahumada area, Basin and Range province, Chihuahua, northern Mexico

    Nandigam, Ravi Chenchu

    This study targets some newly discovered carbonatite occurrences located in the eastern Mexican Basin and Range province, a few kilometers to the east of Villa Ahumada, Chihuahua. The region containing these occurrences experienced compression related to subduction of the Farallon plate until about 32 Ma that was followed by Basin and Range extension. Geological mapping (1:5,000 scale), petrography, study of drill hole cuttings and satellite images, and major and trace element chemical analyses were utilized to understand the intrusive style of the carbonatites, their mineralogy and petrogenesis. The carbonatites, named Yuca, Mariana and El Indio, collectively intrude limestones, granitic intrusives and subduction-related tuffs and lavas mainly as a stock, breccias and dikes. The Yuca carbonatite was emplaced as a 900-m diameter stock, 500 x 350 m breccia body, numerous dikes and networks of fracture fillings. Crosscutting field relationships at Yuca suggest at least two stages of carbonatite emplacement. At Mariana, carbonatite was emplaced as a 750 x 350 m breccia. Four out of nine reverse circulation drill holes penetrated and bottomed in the breccia at an average depth of about 300 m At El Indio, carbonatite was emplaced as a 20 m diameter breccia pipe and a 1m thick sill. Major minerals present are calcite, Fe-rich calcite and hematite. Sporadic presence of fluorite is common. At Mariana, two generations of grossular-rich garnets associated with limestones and granite porphyry respectively are recognized. It is inferred that garnets in granite porphyry represent metasomatic alteration due to the emplacement of carbonatite breccia. Parental magmas of Yuca carbonatites have undergone differentiation under low fO2 conditions during which they were progressively enriched in iron. The carbonatite compositional types recognized based on major element data, in the sequence of least to most highly differentiated, are (1) magnesio-, (2) calcio- and (3

  13. Petrography and mineral chemistry of carbonatites and mica-rich rocks from the Araxá complex (Alto Paranaíba Province, Brazil



    Full Text Available The Araxá complex (16 km² comprises carbonatites forming a central core and a complex network of concentric and radial dykes as well as small veins; additionally, it includes mica-rich rocks, phoscorites and lamprophyres. Fenites also occur and are represented by Proterozoic quartzites and schists of the Araxá Group. The petrographic study of 130 borehole samples indicates that the complex is basically made up by two rock-types, carbonatites and mica-rich rocks, and subordinately by a third unit of hybrid composition. Carbonatites range chemically in composition, the most abundant type being magnesiocarbonatites. Dolomite and calcite correspond to the chief constituents, but other carbonate phases, including the Ce-group RE minerals, are also recognized. Phosphates and oxides are widespread accessories whereas silicate minerals consist of olivine, clinopyroxene, mica and amphibole. Mica-rich rocks are represented by abundant glimmeritic rocks and scarce cumulitic phlogopite-, olivine- and diopside-bearing pyroxenites. Hybrid rocks mainly contain phlogopite and tetraferriphlogopite as cumulus and intercumulus phases, respectively; carbonate minerals may also be found. Chemical data indicate that the carbonatites are strongly enriched in REE and have lower contents of Nb, Zr, V, Cr, Ni and Rb compared to the mica-rich rocks. The higher K, Nb and Zr contents of the latter rocks are believed to be related to metasomatic processes (glimmeritization of the pyroxenites. Similar REE patterns for carbonatites and mica-rich rocks seem to suggest that they are related to a single parental magma, possibly of ijolitic composition. Steep LREE/HREE fractionation and high sigmaREE content of some carbonatite samples would be explained by hydrothermal and supergenic processes.O complexo de Araxá (16 km² é constituído por carbonatitos na forma de um núcleo central e de complexa rede de diques concêntricos e radiais, além de pequenos veios

  14. Fractional crystallization of Si-undersaturated alkaline magmas leading to unmixing of carbonatites on Brava Island (Cape Verde) and a general model of carbonatite genesis in alkaline magma suites

    Weidendorfer, Daniel; Schmidt, Max W.; Mattsson, Hannes B.


    The carbonatites of Brava Island, Cape Verde hot spot, allow to investigate whether they represent small mantle melt fractions or form through extreme fractionation and/or liquid immiscibility from CO2-bearing silicate magmas. The intrusive carbonatites on Brava Island are part of a strongly silica-undersaturated pyroxenite, ijolite, nephelinite, nepheline syenite, combeite-foiditite, carbonatite series. The major and trace element composition of this suite is reproduced by a model fractionating olivine, clinopyroxene, perovskite, biotite, apatite, titanite, sodalite and FeTi oxides, all present as phenocrysts in the rocks corresponding to their fractionation interval. Fractionation of ~90 wt% crystals reproduces the observed geochemical trend from the least evolved ultramafic dikes (bulk X Mg = 0.64) to syenitic compositions. The modelled fractional crystallization leads to alkali enrichment, driving the melt into the carbonatite-silicate miscibility gap. An initial CO2 content of 4000 ppm is sufficient to saturate in CO2 at the point where the rock record suggests continuing unmixing carbonatites from nephelinites to nepheline syenites after 61 wt% fractionation. Such immiscibility is also manifested in carbonatite and silicate domains on a hand-specimen scale. Furthermore, almost identical primary clinopyroxene, biotite and carbonate compositions from carbonatites and nephelinites to nepheline syenites substantiate their conjugate character and our unmixing model. The modelled carbonatite compositions correspond to the natural ones except for their much higher alkali contents. The alkali-poor character of the carbonatites on Brava and elsewhere is likely a consequence of the release of alkali-rich CO2 + H2O fluids during final crystallization, which cause fenitization in adjacent rocks. We propose a general model for carbonatite generation during alkaline magmatism, where the fractionation of heavily Si-undersaturated, alkaline parent melts results in alkali and

  15. Ancient melt depletion overprinted by young carbonatitic metasomatism in the New Zealand lithospheric mantle

    Scott, James M.; Hodgkinson, A.; Palin, J.M.;


    removal of clinopyroxene. LREE-enriched, low-Ti/Eu and Al2O3 clinopyroxene and rare F-rich apatite reflect subsequent interaction between peridotite and carbonatite. The clearest metasomatic overprint occurs in the formerly depleted samples because there was little or no pre-existing clinopyroxene...

  16. Mineralogy of metamorphosed carbonatite of the Vesely occurrence, Northern Transbaikal region, Russia

    Lastochkin, E. I.; Ripp, G. S.; Doroshkevich, A. G.


    Metamorphism of carbonatite is exemplified in the Vesely occurrence. According to available data, the age of the carbonatite is 596 ± 3.5Ma, whereas metamorphism is dated at 550 ± 14 Ma. The rocks at the Vesely occurrence were metamorphosed under conditions of greenschist facies (epidote-muscovite-chlorite subfacies) under elevated pressure. Microthermometry of fluid inclusions in minerals indicates that the temperature of metamorphism is 377-450°C and the pressure estimated from phengite geobarometer is 6-8 kbar. The low-grade metamorphism led to the partial recrystallization of carbonates and apatite with removal of trace elements. This process resulted in a change of the oxygen isotopic composition of the studied minerals. Metamorphism was accompanied by formation of talc, phengite, chlorite, quartz, tremolite-actinolite, and anthophyllite, which are not typical of carbonatite. The data obtained show that the metamorphism exerted an effect on the mineralogical, isotopic, geochemical, and technological properties of the carbonatite. The effect of metamorphism should be taken into account in determination of the nature of ore mineralization and estimation of ore quality and perspective of the occurrence.

  17. Use of barium-strontium carbonatite for flux welding and surfacing of mining machines

    Kryukov, R. E.; Kozyrev, N. A.; Usoltsev, A. A.


    The results of application of barium-strontium carbonatite for modifying and refining iron-carbon alloys, used for welding and surfacing in ore mining and smelting industry, are generalized. The technology of manufacturing a flux additive containing 70 % of barium-strontium carbonatite and 30 % of liquid glass is proposed. Several compositions of welding fluxes based on silicomanganese slag were tested. The flux additive was introduced in an amount of 1, 3, 5 %. Technological features of welding with the application of the examined fluxes are determined. X-ray spectral analysis of the chemical composition of examined fluxes, slag crusts and weld metal was carried out, as well as metallographic investigations of welded joints. The principal possibility of applying barium-strontium carbonatite as a refining and gas-protective additive for welding fluxes is shown. The use of barium-strontium carbonatite reduces the contamination of the weld seam with nonmetallic inclusions: non-deforming silicates, spot oxides and brittle silicates, and increases the desulfurizing capacity of welding fluxes.

  18. Carbonatitic lavas in Catanda (Kwanza Sul, Angola): Mineralogical and geochemical constraints on the parental melt

    Campeny, Marc; Kamenetsky, Vadim S.; Melgarejo, Joan C.; Mangas, José; Manuel, José; Alfonso, Pura; Kamenetsky, Maya B.; Bambi, Aurora C. J. M.; Gonçalves, Antonio O.


    A set of small volcanic edifices with tuff ring and maar morphologies occur in the Catanda area, which is the only locality with extrusive carbonatites reported in Angola. Four outcrops of carbonatite lavas have been identified in this region and considering the mineralogical, textural and compositional features, we classify them as: silicocarbonatites (1), calciocarbonatites (2) and secondary calciocarbonatites produced by the alteration of primary natrocarbonatites (3). Even with their differences, we interpret these lava types as having been a single carbonatite suite related to the same parental magma. We have also estimated the composition of the parental magma from a study of melt inclusions hosted in magnetite microphenocrysts from all of these lavas. Melt inclusions revealed the presence of 13 different alkali-rich phases (e.g., nyerereite, shortite, halite and sylvite) that argues for an alkaline composition of the Catanda parental melts. Mineralogical, textural, compositional and isotopic features of some Catanda lavas are also similar to those described in altered natrocarbonatite localities worldwide such as Tinderet or Kerimasi, leading to our conclusion that the formation of some Catanda calciocarbonatite lavas was related to the occurrence of natrocarbonatite volcanism in this area. On the other hand, silicocarbonatite lavas, which are enriched in periclase, present very different mineralogical, compositional and isotopic features in comparison to the rest of Catanda lavas. We conclude that its formation was probably related to the decarbonation of primary dolomite bearing carbonatites.

  19. Apatite in carbonatitic rocks: Compositional variation, zoning, element partitioning and petrogenetic significance

    Chakhmouradian, Anton R.; Reguir, Ekaterina P.; Zaitsev, Anatoly N.; Couëslan, Christopher; Xu, Cheng; Kynický, Jindřich; Mumin, A. Hamid; Yang, Panseok


    Apatite-group phosphates are nearly ubiquitous in carbonatites, but our understanding of these minerals is inadequate, particularly in the areas of element partitioning and petrogenetic interpretation of their compositional variation among spatially associated rocks and within individual crystals. In the present work, the mode of occurrence, and major- and trace-element chemistry of apatite (sensu lato) from calcite and dolomite carbonatites, their associated cumulate rocks (including phoscorites) and hydrothermal parageneses were studied using a set of 80 samples from 50 localities worldwide. The majority of this set represents material for which no analytical data are available in the literature. Electron-microprobe and laser-ablation mass-spectrometry data ( 600 and 400 analyses, respectively), accompanied by back-scattered-electron and cathodoluminescence images and Raman spectra, were used to identify the key compositional characteristics and zoning patterns of carbonatitic apatite. These data are placed in the context of phosphorus geochemistry in carbonatitic systems and carbonatite evolution, and compared to the models proposed by previous workers. The documented variations in apatite morphology and zoning represent a detailed record of a wide range of evolutionary processes, both magmatic and fluid-driven. The majority of igneous apatite from the examined rocks is Cl-poor fluorapatite or F-rich hydroxylapatite (≥ 0.3 apfu F) with 0.2-2.7 wt.% SrO, 0-4.5 wt.% LREE2O3, 0-0.8 wt.% Na2O, and low levels of other cations accommodated in the Ca site (up to 1000 ppm Mn, 2300 ppm Fe, 200 ppm Ba, 150 ppm Pb, 700 ppm Th and 150 ppm U), none of which show meaningful correlation with the host-rock type. Silicate, (SO4)2 - and (VO4)3 - anions, substituting for (PO4)3 -, tend to occur in greater abundance in crystals from calcite carbonatites (up to 4.2 wt.% SiO2, 1.5 wt.% SO3 and 660 ppm V). Although (CO3)2 - groups are very likely present in some samples, Raman micro

  20. Regional geophysical expression of a carbonatite terrane in the eastern Mojave Desert, California

    Ponce, David A.; Denton, Kevin M.; Miller, David M.


    A world-class, rare earth element carbonatite deposit is located near Mountain Pass, in the eastern Mojave Desert of California and is hosted by Proterozoic rocks that extend along the eastern margins of the Clark Mountain Range, Mescal Range, and Ivanpah Mountains in a north-northwest trending fault-bounded block. This Proterozoic block is generally composed of a complex of 1.7 - 1.6 Ga gneisses and schists that are intruded by ~1.4 Ga carbonatite and ultrapotassic mafic dikes. In the latter suite, common intrusive rock types include shonkinite, syenite, and alkali granites that are associated with carbonatite dikes. Regional geophysical data reveal that the carbonatite deposit itself occurs along the northeast edge of a prominent magnetic high with an amplitude of 200 nanoteslas, which appears to be related to the surrounding Proterozoic block. More than 340 gravity stations and 155 physical property samples were collected to augment existing geophysical data to determine the geophysical and geologic setting of the eastern Mojave Desert carbonatite terrane. Physical properties of representative rock types in the area show that 23 samples of carbonatite ore have an average saturated bulk density of 2,866 with a range of 2,440 to 3,192 kg/m3 and a magnetic susceptibility of 0.22 with a range of 0.03 to 0.61x 10-3 SI units, 17 samples of syenite have an average saturated bulk density of 2,670 with a range of 2,555 to 2,788 kg/m3 and a magnetic susceptibility of 3.50 with a range of 0.19 to 11.46 x 10-3 SI units, 19 samples of shonkinite dike have an average saturated bulk density of 2,800 with a range of 2,603 to 3,000 kg/m3 and a magnetic susceptibility of 0.71 with a range of 0.00 to 4.44 x 10-3 SI units, and 28 samples of Proterozoic gneiss have an average saturated bulk density of 2,734 with a range of 2,574 to 3,086 kg/m3 and a magnetic susceptibility of 1.23 with a range of 0.01 to 7.48 x 10-3 SI units. In general, carbonatites have distinctive gravity


    Biswadev Basu


    Full Text Available ABSTRACT : Dyke – Davidoff – Masson Syndrome (DDMS, is a rare clinical condition characterized by clinical triad of seizures, contralateral spastic hemiplegia or hemiparesis, with or without mental retardation. Diagnosis requires presence of cerebral hemiatrophy with homolateral hypertrophy of the skull and sinuses on brain imaging. Here we report a case of DDMS in a 16 year old girl who presented with seizures and hemiparesis.MRI of her brain showed hemiatrophy involving the left cerebral hemisphere with enlargement of ipsilateral sinuses and ventricles

  2. Dyke Monitorin by the Means of Persistent Scattering Interferometry at the Coast of Northern Germany

    Seidel, M.; Marzahn, P.; Ludwig, R.


    40 percent of the world's population are presently living in coastal areas or along the main rivers. Taking into account that the vulnerability of these areas is increasing due to sea-level rise and coastal hazards such as storm surges or extreme rainfall events accompanied with floods, the importance of safety structures such as dykes is increasing as well. Hence, a spatial distributed dyke monitoring should be part of a sustainable adaptation strategy. Due to increasing amount of SAR-data from various satellites with high spatial and temporal coverage, the means of SAR-interferometry could be an essential tool to ensure this kind of required monitoring. Given this prospect, Persistent Scattering Interferometry (PSI) will be a very suitable monitoring technique for dyke structures to identify dyke movement with the accuracy of few millimetres. This procedure focuses on pixels that show a stable scattering behaviour in a sequence of multiple SAR-scenes. In opposition to ground-measurements, the spatial coverage of this technique provides comparable results for different parts of the dyke; furthermore weak segments with particular high movements could be identified in advance. This could prevent future dyke crevasses and help to reduce risks in high-populated areas. This paper attempts to describe the potential of the PSI technique for a spatial distributed dyke monitoring at the coast in northern Germany. 21 ERS-2 scenes and 16 Envisat ASAR scenes were analysed. Those Scenes cover an area of a sea shore dyke including a flood regulation barrage and results point out the potential for this technique to monitor dyke structures. Even though the observed dyke doesn't show any significant deformation rates, the two datasets show the same signal for the whole dyke.

  3. Fault-related carbonate breccia dykes in the La Chilca area, Eastern Precordillera, San Juan, Argentina

    Castro de Machuca, Brígida; Perucca, Laura P.


    Carbonate fault breccia dykes in the Cerro La Chilca area, Eastern Precordillera, west-central Argentina, provide clues on the probable mechanism of both fault movement and dyke injection. Breccia dykes intrude Upper Carboniferous sedimentary rocks and Triassic La Flecha Trachyte Formation. The timing of breccia dyke emplacement is constrained by cross cutting relationships with the uppermost Triassic unit and conformable contacts with the Early Miocene sedimentary rocks. This study supports a tectonic-hydrothermal origin for these breccia dykes; fragmentation and subsequent hydraulic injection of fluidized breccia are the more important processes in the breccia dyke development. Brecciation can be triggered by seismic activity which acts as a catalyst. The escape of fluidized material can be attributed to hydrostatic pressure and the direction of movement of the material establishes the direction of least pressure. Previous studies have shown that cross-strike structures have had an important role in the evolution of this Andean segment since at least Triassic times. These structures represent pre-existing crustal fabrics that could have controlled the emplacement of the dykes. The dykes, which are composed mostly of carbonate fault breccia, were injected upward along WNW fractures.

  4. REE mobility during the alteration of Carbonatite and their economic potential.

    Marien, Christian; Dijkstra, Arjan; Wilkins, Colin


    The supply risk of Rare Earth Elements is an unpredictable economic factor for the future application and development of modern technology for the EU. Therefore a better understanding of REE mobilisation during hydrothermal alteration of Carbonatites is essential for a safer supply of REE in general. The hydrothermal alteration of Carbonatite within the Fen Complex (Norway) forms a fine grained red hematized rock type, called Rødbergite, which is partially enriched in REE. The variation of REE within the Rødbergite is poorly understood and problematic for any future REE exploitation from Rødbergite. A genetic model of the formation of Rødbergite will provide more information about the economic potential of Rødbergite. The gradual transformation of carbonatite to Rødbergite is not easily observable due to sparse outcrop in the Fen Complex. A fresh road cut near the Bjørndallen farm (Fen Complex) provides a unique insight to the progressive hydrothermal alteration from carbonatite to Rødbergite and is therefore crucial for a genetic model of the formation of Rødbergite. 14 Samples were taken along the profile. The mineralogical, geochemical and textural characterization of the samples using the SEM as well as major-, trace- and isotopic elemental data revealed the breakdown of the primary minerals due to the infiltration of an oxidizing fluid along grain boundaries. The primary REE-minerals in unaltered Carbonatite are REE fluorocarbonates. With the increasing alteration to Rødbergite REE fluorocarbonates are progressively replaced by hematite. In contrast, monazite - a REE-phosphate - is the dominant REE mineral species in the Rødbergite. A transitional Rødbergite sample shows apatite aggregates with a strong preferential concentration of monazite along the rim of the apatite aggregates. This observation provides strong evidence for the solution of REE in the primary rock (carbonatite) by fluids and later precipitation of REE along phosphate bearing

  5. Segmented lateral dyke growth in a rifting event at Bárðarbunga volcanic system, Iceland.

    Sigmundsson, Freysteinn; Hooper, Andrew; Hreinsdóttir, Sigrún; Vogfjörd, Kristín S; Ófeigsson, Benedikt G; Heimisson, Elías Rafn; Dumont, Stéphanie; Parks, Michelle; Spaans, Karsten; Gudmundsson, Gunnar B; Drouin, Vincent; Árnadóttir, Thóra; Jónsdóttir, Kristín; Gudmundsson, Magnús T; Högnadóttir, Thórdís; Fridriksdóttir, Hildur María; Hensch, Martin; Einarsson, Páll; Magnússon, Eyjólfur; Samsonov, Sergey; Brandsdóttir, Bryndís; White, Robert S; Ágústsdóttir, Thorbjörg; Greenfield, Tim; Green, Robert G; Hjartardóttir, Ásta Rut; Pedersen, Rikke; Bennett, Richard A; Geirsson, Halldór; La Femina, Peter C; Björnsson, Helgi; Pálsson, Finnur; Sturkell, Erik; Bean, Christopher J; Möllhoff, Martin; Braiden, Aoife K; Eibl, Eva P S


    Crust at many divergent plate boundaries forms primarily by the injection of vertical sheet-like dykes, some tens of kilometres long. Previous models of rifting events indicate either lateral dyke growth away from a feeding source, with propagation rates decreasing as the dyke lengthens, or magma flowing vertically into dykes from an underlying source, with the role of topography on the evolution of lateral dykes not clear. Here we show how a recent segmented dyke intrusion in the Bárðarbunga volcanic system grew laterally for more than 45 kilometres at a variable rate, with topography influencing the direction of propagation. Barriers at the ends of each segment were overcome by the build-up of pressure in the dyke end; then a new segment formed and dyke lengthening temporarily peaked. The dyke evolution, which occurred primarily over 14 days, was revealed by propagating seismicity, ground deformation mapped by Global Positioning System (GPS), interferometric analysis of satellite radar images (InSAR), and graben formation. The strike of the dyke segments varies from an initially radial direction away from the Bárðarbunga caldera, towards alignment with that expected from regional stress at the distal end. A model minimizing the combined strain and gravitational potential energy explains the propagation path. Dyke opening and seismicity focused at the most distal segment at any given time, and were simultaneous with magma source deflation and slow collapse at the Bárðarbunga caldera, accompanied by a series of magnitude M > 5 earthquakes. Dyke growth was slowed down by an effusive fissure eruption near the end of the dyke. Lateral dyke growth with segment barrier breaking by pressure build-up in the dyke distal end explains how focused upwelling of magma under central volcanoes is effectively redistributed over long distances to create new upper crust at divergent plate boundaries.

  6. 40Ar-39Ar age of carbonatite-alkaline magmatism in Sung Valley, Maghalaya, India

    Jyotiranjan S Ray; Kanchan Pande


    40Ar-39Ar analyses of one alkali pyroxenite whole rock and two phlogopite separates of calcite carbonatites from the Sung Valley carbonatite-alkaline complex, which is believed to be a part of the Rajmahal-Bengal-Sylhet (RBS) ood basalt province, yielded indistinguishable plateau ages of 108.8 ± 2.0 Ma, 106:4 ± 1.3 Ma and 107.5 ± 1.4 Ma, respectively. The weighted mean of these ages, 107.2 ± 0.8 Ma, is the time of emplacement of this complex. This implies that Sung Valley complex and probably other such complexes in the Assam-Meghalaya Plateau postdate the main ood basalt event (i.e., the eruption of tholeiites) in the RBS province by ∼10 Ma.

  7. Paleomagnetism of the ~1.1 Ga Baraga-Marquette dykes (Michigan, USA)

    Piispa, E. J.; Foucher, M. S.; Chmielewski, J. A.; Smirnov, A. V.; Pesonen, L. J.


    We present new detailed paleomagnetic and rock magnetic results from ~50 dykes exposed in the Baraga-Marquette (BM) area of the Upper Peninsula of Michigan (USA). The dyke intrusion was associated with the development of the ~1.1 Ga North American Mid-Continent Rift (MCR) system. Most rocks representing the early stage of MCR are characterized by steep reversed directions of the characteristic remanent magnetization (ChRM), whereas the rocks from the main stage of MCR generally yield shallower normal polarity ChRM directions. Rock magnetic experiments show that the principal magnetic carrier in the BM dykes is single-domain to pseudosingle-domain magnetite or low-Ti titanomagnetite with minor occurrences of hematite, maghemite, or pyrrhotite in some dykes. The majority of BM dykes yielded steep reversed-polarity directions of ChRM indicating that they belong to the early stage of MCR development. The corresponding paleomagnetic pole plots close to the apex of the so called "Logan Loop", a segment of the Apparent Polar Wander Path (APWP) for the North American continent for ~1000-1200 Ma. Several BM dykes yielded steep normal-polarity ChRM directions, significantly different from the direction exhibited by the normally magnetized MCR sequences. This may indicate that these dykes are older than the reversed polarity dykes. In addition, a single mafic dyke from the Baraga basin with a recently published U/Pb age of 1120±4 Ma resulted in a shallow normal ChRM direction. The implications of our new paleomagnetic results for the North American APWP and the evolution of MCR will be discussed.

  8. Ultrasound-assisted extraction of rare-earth elements from carbonatite rocks.

    Diehl, Lisarb O; Gatiboni, Thais L; Mello, Paola A; Muller, Edson I; Duarte, Fabio A; Flores, Erico M M


    In view of the increasing demand for rare-earth elements (REE) in many areas of high technology, alternative methods for the extraction of these elements have been developed. In this work, a process based on the use of ultrasound for the extraction of REE from carbonatite (an igneous rock) is proposed to avoid the use of concentrated reagents, high temperature and excessive extraction time. In this pioneer work for REE extraction from carbonatite rocks in a preliminary investigation, ultrasonic baths, cup horn systems or ultrasound probes operating at different frequencies and power were evaluated. In addition, the power released to the extraction medium and the ultrasound amplitude were also investigated and the temperature and carbonatite mass/volume of extraction solution ratio were optimized to 70°C and 20mg/mL, respectively. Better extraction efficiencies (82%) were obtained employing an ultrasound probe operating at 20kHz for 15min, ultrasound amplitude of 40% (692Wdm(-3)) and using a diluted extraction solution (3% v/v HNO3+2% v/v HCl). It is important to mention that high extraction efficiency was obtained even using a diluted acid mixture and relatively low temperature in comparison to conventional extraction methods for REE. A comparison of results with those obtained by mechanical stirring (500rpm) using the same conditions (time, temperature and extraction solution) was carried out, showing that the use of ultrasound increased the extraction efficiency up to 35%. Therefore, the proposed ultrasound-assisted procedure can be considered as a suitable alternative for high efficiency extraction of REE from carbonatite rocks. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Carbonatitic and granitic melts produced under conditions of primary immiscibility during anatexis in the lower crust

    Ferrero, Silvio; Wunder, Bernd; Ziemann, Martin A.; Wälle, Markus; O'Brien, Patrick J.


    Carbonatites are peculiar magmatic rocks with mantle-related genesis, commonly interpreted as the products of melting of CO2-bearing peridotites, or resulting from the chemical evolution of mantle-derived magmas, either through extreme differentiation or secondary immiscibility. Here we report the first finding of anatectic carbonatites of crustal origin, preserved as calcite-rich polycrystalline inclusions in garnet from low-to-medium pressure migmatites of the Oberpfalz area, SW Bohemian Massif (Central Europe). These inclusions originally trapped a melt of calciocarbonatitic composition with a characteristic enrichment in Ba, Sr and LREE. This interpretation is supported by the results of a detailed microstructural and microchemical investigation, as well as re-melting experiments using a piston cylinder apparatus. Carbonatitic inclusions coexist in the same cluster with crystallized silicate melt inclusions (nanogranites) and COH fluid inclusions, suggesting conditions of primary immiscibility between two melts and a fluid during anatexis. The production of both carbonatitic and granitic melts during the same anatectic event requires a suitable heterogeneous protolith. This may be represented by a sedimentary sequence containing marble lenses of limited extension, similar to the one still visible in the adjacent central Moldanubian Zone. The presence of CO2-rich fluid inclusions suggests furthermore that high CO2 activity during anatexis may be required to stabilize a carbonate-rich melt in a silica-dominated system. This natural occurrence displays a remarkable similarity with experiments on carbonate-silicate melt immiscibility, where CO2 saturation is a condition commonly imposed. In conclusion, this study shows how the investigation of partial melting through melt inclusion studies may unveil unexpected processes whose evidence, while preserved in stiff minerals such as garnet, is completely obliterated in the rest of the rock due to metamorphic re

  10. Ultradepleted adcumulates from a late-stage mafic dyke of the Bayantsagaan layered intrusion, Mongolia

    Chistyakova, Sofya; Latypov, Rais


    It is commonly expected that late-stage dykes in mafic layered intrusions must be strongly enriched in all incompatible components that are concentrated in the evolved residual melt. Our recent study of one late-stage dyke from the Bayantsagaan layered intrusion (Mongolia) has revealed, however, that this is not always the case. This 11 cm thick dyke is composed of quite fresh, fully crystalline troctolite with no signs of chilling against host leucotroctolite. Texturally, both dyke and leucotroctolite are composed of medium-grained plagioclase-olivine-magnetite cumulate. The dyke is, however, finer-grained and more adcumulate than leucotroctolite as evident from a much less amount of intercumulus material mainly represented by interstitial amphibole (5 vol.% versus 10 vol.%). The dyke shows three distinctive geochemical features. Firstly, it is compositionally more evolved than leucotroctolite as indicated by notably lower real and normative An-content of plagioclase, whole-rock Mg-number and Cr and higher whole-rock TiO2. Secondly, despite of being more evolved, the dyke is notably depleted in all incompatible components (e.g. K2O, Y, REE). Their concentrations in the dyke are several times lower than in host leucotroctolite (e.g. 0.015 ppm versus 0.112 ppm for Dy). Thirdly, the dyke reveals internal reverse zonation with an inward increase in compatible MgO, TiO2 and normative An-content and a decrease in all incompatible components (e.g. REE). Such a distribution of incompatible components is indicative of an inward decrease in the amount of trapped melt, in other words, the dyke becomes inwards progressively more adcumulate. In layered intrusions, adcumulates are commonly attributed to the almost complete removal of interstitial liquid enriched in incompatible elements from cumulate pile by some primary cumulus (e.g. in situ growth) or post-cumulus processes (e.g. compaction, compositional convection, thermal migration). These processes are, however, not

  11. Looking for Asian butch-dykes: exploring filmic representations of East Asian butch-dykes in Donna Lee's Enter the Mullet.

    Lin, Hui-Ling


    Asian butch-dykes have been overlooked in analyses of Chinese cinema, studies that often concentrate on "feminized" transgender roles. This article examines cinematic representations of Asian butch-dykes through film analysis of Enter the Mullet (2004), a five-minute short, and in-depth interviews with the filmmaker, Donna Lee, a Chinese-Canadian in Vancouver. Lee's film is inspired by Enter the Dragon (1973), starring Bruce Lee, the most recognized icon of Asian masculinity. Combining with the mullet hairstyle, which is often associated with White working-class, the filmmaker introduces viewers to the hybrid masculinity of Asian butch-dykes. The article argues that Asian female masculinity can be a strategic means of destabilizing the hegemony of White-male-middle-class masculinity.

  12. Utility of natural generalised inverse technique in the interpretation of dyke structures

    Rao, M.M.M.; Murty, T.V.R.; Rao, P.R.; Lakshminarayana, S.; Subrahmanyam, A.S.; Murthy, K.S.R.

    Forward and Inverse methods of magnetic interpretation have been used to estimate the parameters of dyke like intrusion over the eastern continental shelf of India. In the forward problem, the tentative parameters of the causative source are assumed...

  13. The Ahmeyim Great Dyke of Mauritania: A newly dated Archaean intrusion

    Tait, J.; Straathof, G.; Söderlund, U.; Ernst, R. E.; Key, R.; Jowitt, S. M.; Lo, K.; Dahmada, M. E. M.; N'Diaye, O.


    A precise U-Pb baddeleyite age of 2733 ± 2 Ma has been obtained for the Ahmeyim Great Dyke of Mauritania that intruded into the Tasiast-Tijirit Terrane of the Reguibat Shield, NW Mauritania. This dyke is approximately 1500 m wide at the sampling area and extends for more than 150 km NNE/SSW. Major and trace element geochemistry of the dyke indicates that the magmas that formed this intrusive body were sub-alkaline, tholeiitic and boninitic, and the presence of a negative Nb anomaly indicates the involvement of subducted oceanic lithosphere during magma genesis, most likely an inherited signature from earlier subduction events and the Mesoarchaean collision of the Tasiast-Tijirit and Choum-Rag el Abiod Terranes. A palaeomagnetic study was also undertaken on samples collected from two different sections across the dyke. However, no within- or inter-site grouping of any palaeomagnetic directions could be identified, thus precluding any palaeographic interpretation. The Ahmeyim Great Dyke is interpreted to be part of the feeder system for a 2733 Ma Large Igneous Province (LIP); tholeiitic-komatiitic greenstone belts of this age are absent in the West African Craton (WAC) but are present on many other blocks. However, additional constraints are required to reliably link the Ahmeyim Great Dyke with any other such LIP-type greenstone belts in late Archaean supercontinent reconstructions. The magmas that formed the Ahmeyim Great Dyke were boninitic; this, combined with evidence of crustal contamination, the scale of the dyke and its potential link (as a feeder) to greenstone belts of tholeiitic-komatiitic affiliation within other crustal blocks suggests that it, and cogenetic magmatic units elsewhere, may be prospective for magmatic Ni-Cu-PGE sulphide exploration.

  14. Emplacement time of the Loe-Shilman carbonatite from NW Pakistan: Constraints from fission-track dating

    Khattak, N.U. [National Centre of Excellence in Geology, University of Peshawar (Pakistan)], E-mail:; Akram, M. [Physics Division, PINSTECH, P.O. Nilore, Islamabad (Pakistan); Khan, M.A. [National Centre of Excellence in Geology, University of Peshawar (Pakistan); Khan, H.A. [COMSATS Headquarters, 4th Floor, Shahrah-e-Jamhuriat, G-5/2 Islamabad 44000 (Pakistan)


    The Loe-Shilman carbonatite complex is situated in the extreme west of the Peshawar Plain Alkaline Igneous Province (PAIP), near the Pakistan-Afghanistan border. It comprises sill-form bodies emplaced along an E-W trending and N dipping fault zone in Paleozoic to Precambrian metasedimentary rocks of Khyber Agency. Fission-track dating studies on the apatite crystals using the external detector method and age standard approach (the {zeta} method) yielded an age of 30.0{+-}1.5Ma for the Loe-Shilman carbonatite. Close agreement between the previously determined radiometric ages from the same as well as the neighboring carbonatite complexes of the PAIP and the fission-track apatite age of this study indicates that the Loe-Shilman carbonatite was emplaced at relatively shallow crustal level and quickly cooled to low temperatures (<60{sup 0}C) required for the complete retention of fission tracks in apatite and that the fission-track age of this study is the emplacement age of the Loe-Shilman carbonatite.

  15. Trace element geochemistry of Amba Dongar carbonatite complex, India: Evidence for fractional crystallization and silicate-carbonate melt immiscibility

    Jyotiranjan S Ray; P N Shukla


    Carbonatites are believed to have crystallized either from mantle-derived primary carbonate magmas or from secondary melts derived from carbonated silicate magmas through liquid immiscibility or from residual melts of fractional crystallization of silicate magmas. Although the observed coexistence of carbonatites and alkaline silicate rocks in most complexes, their coeval emplacement in many, and overlapping initial 87Sr/86Sr and 143Nd/144Nd ratios are supportive of their cogenesis; there have been few efforts to devise a quantitative method to identify the magmatic processes. In the present study we have made an attempt to accomplish this by modeling the trace element contents of carbonatites and coeval alkaline silicate rocks of Amba Dongar complex, India. Trace element data suggest that the carbonatites and alkaline silicate rocks of this complex are products of fractional crystallization of two separate parental melts. Using the available silicate melt-carbonate melt partition coefficients for various trace elements, and the observed data from carbonatites, we have tried to simulate trace element distribution pattern for the parental silicate melt. The results of the modeling not only support the hypothesis of silicate-carbonate melt immiscibility for the evolution of Amba Dongar but also establish a procedure to test the above hypothesis in such complexes.

  16. Mangrove forest against dyke-break-induced tsunami on rapidly subsiding coasts

    Takagi, Hiroshi; Mikami, Takahito; Fujii, Daisuke; Esteban, Miguel; Kurobe, Shota


    Thin coastal dykes typically found in developing countries may suddenly collapse due to rapid land subsidence, material ageing, sea-level rise, high wave attack, earthquakes, landslides, or a collision with vessels. Such a failure could trigger dam-break tsunami-type flooding, or "dyke-break-induced tsunami", a possibility which has so far been overlooked in the field of coastal disaster science and management. To analyse the potential consequences of one such flooding event caused by a dyke failure, a hydrodynamic model was constructed based on the authors' field surveys of a vulnerable coastal location in Jakarta, Indonesia. In a 2 m land subsidence scenario - which is expected to take place in the study area after only about 10-20 years - the model results show that the floodwaters rapidly rise to a height of nearly 3 m, resembling the flooding pattern of earthquake-induced tsunamis. The depth-velocity product criterion suggests that many of the narrow pedestrian paths behind the dyke could experience strong flows, which are far greater than the safe limits that would allow pedestrian evacuation. A couple of alternative scenarios were also considered to investigate how such flood impacts could be mitigated by creating a mangrove belt in front of the dyke as an additional safety measure. The dyke-break-induced tsunamis, which in many areas are far more likely than regular earthquake tsunamis, cannot be overlooked and thus should be considered in disaster management and urban planning along the coasts of many developing countries.

  17. The late Paleoproterozoic extension event:aulacogens and dyke Swarms in the North China craton


    The extension structures and tectonic implication in the North China Craton (NCC) are discussed in this paper based on the mafic dyke swarms and geochronology, combining with the geochronology of aulacogens. The late Paleoproterozoic time is the important turning point in the Precambrian evolution of the NCC. The extension system (e. g. aulacogens and dyke swarms) is widespread in the NCC, which marks the carbonization of the NCC with the rigid characteristic similar to the modern plate. The paleostress field modeling suggests that the dyke swarms and aulacogens are arogenic extension marking the start of the supercontinent, not synorogenic and postorogenic extension. The mafic dyke swarms in the NCC mainly ranged from 1.83 to 1.77 Ga. The extension of the NCC is very limited brittle extension, the average extension ratio is only 0.35 % given by mafic dyke swarms extension calculation, so most of extension in the NCC is contributed by the aulacogens. The mafic dyke swarms are related with the aulacogens in the origin.

  18. Mafic dykes at the southwestern margin of Eastern Ghats belt: Evidence of rifting and collision

    S Bhattacharya; A K Chaudhary; W Teixeira


    The southwestern margin of the Eastern Ghats Belt characteristically exposes ma fic dykes intruding massif-type charnockites. Dykes of olivine basalt of alkaline composition have characteristic trace element signatures comparable with Ocean Island Basalt (OIB). Most importantly strong positive Nb anomaly and low values of Zr/Nb ratio are consistent with OIB source of the mafic dykes. K –Ar isotopic data indicate two cooling ages at 740 and 530 Ma. The Pan-African thermal event could be related to reactivation of major shear zones and represented by leuco-granite vein along minor shear bands. And 740 Ma cooling age may indicate the low grade metamorphic imprints, noted in some of the dykes. Although no intrusion age could be determined from the present dataset, it could be constrained by some age data of the host charnockite gneiss and Alkaline rocks of the adjacent Prakasam Province. Assuming an intrusion age of ∼1 .3 Ga, Sr –Nd isotopic composition of the dykes indicate that they preserved time-integrated LREE enrichment. In view of the chemical signatures of OIB source, the ma fic dykes could as well be related to continental rifting, around 1.3 Ga, which may have been initiated by intra-plate volcanism.

  19. Geology and Geochemistry of the Early Proterozoic Kortejärvi and Laivajoki Carbonatites, Central Fennoscandian Shield, Finland

    Nykänen, J.


    Full Text Available This paper provides for the first time extensive petrological, mineralogical and geochemical data on the early Proterozoic Kortejärvi and Laivajoki carbonatites, northern Finland, which form metamorphosed and highly strained bodies 2 and 4 km long within a Svecokarelian shear zone in central Fennoscandian Shield. They are not exposed, but have been penetrated by a couple of deep drill holes. In terms of modal mineralogy, both intrusions contain calcite carbonatite and dolomite-calcite carbonatite as their main rock types, but Kortejärvi also contains dolomite carbonatite and calcite-dolomite carbonatite, some glimmerite and olivine-magnetite rock and Laivajärvi tremolite-calcite carbonatite, tremolite-dolomite carbonatite, serpentine-talc-dolomite rock and glimmerite. The main country rock is an amphibolite which is not fenitized. No alkaline rocks have been detected in these intrusions. Calcite is most common mineral in both occurrences. Other carbonate minerals include dolomite with minor ankerite and occassional siderite. In addition to low-Ti phlogopite, tetraferriphlogopite is also encountered. Fresh olivine is rare, and its alteration products include titaniferous clinohumite. The amphiboles are mainly calcic amphiboles, including actinolite, tremolite and edenite. The only sodic-calcic amphibole is accessory richterite. Other essential minerals are Ti-poor magnetite with ilmenite exsolutions, fluorapatite (3.95-4.89 wt. % F, monazite, and allanite-(Ce. Geochemically, the Kortejärvi rocks are mostly magnesiocarbonatites, whereas those of Laivajärvi, due to their higher magnetite content, are ferrocarbonatites. Of the trace elements, Nb is much lower (8-30 ppm in proper carbonatites than the average for carbonatites and U and Th (<0.9 ppm and<2.4 pm, respectively lower than average. Sr is typical, but not high (1830-3480 ppm, and Ba is rather low (27-348 ppm. The REEs are hosted by allanite and monazite and their concentrations in the

  20. Emplacement of Amba Dongar Carbonatite-alkaline Complex at Cretaceous/Tertiary Boundary: Evidence from 40Ar-39Ar Chronology

    Jyotiranjan S Ray; Kanchan Pande; T R Venkatesan


    40Ar-39Ar analyses of three fresh alkaline rock samples and a phlogopite separate from a carbonatite from Amba Dongar carbonatite-alkaline complex of the Deccan Flood Basalt Province, India, yield indistinguishable precise plateau ages of 64.8 ± 0.6, 64.7 ± 0.5, 65.5 ± 0.8 and 65.3 ± 0.6 Ma, giving a mean plateau age of 65.0 ± 0.3 Ma, which is the age of emplacement of this complex. This age implies contemporaneity of Amba Dongar with several other carbonatite-alkaline activities of Chhota Udaipur subprovince and is consistent with their Reunion-Deccan plume origin hypothesis. The emplacement of these complexes at 65 Ma makes them very significant in the ongoing debate on the K/T extinctions owing to their capacity to rapidly inject a substantial amount of CO2 and SO2 into the atmosphere.

  1. Has dyke development in the Vietnamese Mekong Delta shifted flood hazard downstream?

    Van Khanh Triet, Nguyen; Viet Dung, Nguyen; Fujii, Hideto; Kummu, Matti; Merz, Bruno; Apel, Heiko


    In the Vietnamese part of the Mekong Delta (VMD) the areas with three rice crops per year have been expanded rapidly during the last 15 years. Paddy-rice cultivation during the flood season has been made possible by implementing high-dyke flood defenses and flood control structures. However, there are widespread claims that the high-dyke system has increased water levels in downstream areas. Our study aims at resolving this issue by attributing observed changes in flood characteristics to high-dyke construction and other possible causes. Maximum water levels and duration above the flood alarm level are analysed for gradual trends and step changes at different discharge gauges. Strong and robust increasing trends of peak water levels and duration downstream of the high-dyke areas are found with a step change in 2000/2001, i.e. immediately after the disastrous flood which initiated the high-dyke development. These changes are in contrast to the negative trends detected at stations upstream of the high-dyke areas. This spatially different behaviour of changes in flood characteristics seems to support the public claims. To separate the impact of the high-dyke development from the impact of the other drivers - i.e. changes in the flood hydrograph entering the Mekong Delta, and changes in the tidal dynamics - hydraulic model simulations of the two recent large flood events in 2000 and 2011 are performed. The hydraulic model is run for a set of scenarios whereas the different drivers are interchanged. The simulations reveal that for the central VMD an increase of 9-13 cm in flood peak and 15 days in duration can be attributed to high-dyke development. However, for this area the tidal dynamics have an even larger effect in the range of 19-32 cm. However, the relative contributions of the three drivers of change vary in space across the delta. In summary, our study confirms the claims that the high-dyke development has raised the flood hazard downstream. However, it is not

  2. Carbonatites of the World, Explored Deposits of Nb and REE - Database and Grade and Tonnage Models

    Berger, Vladimir I.; Singer, Donald A.; Orris, Greta J.


    This report is based on published tonnage and grade data on 58 Nb- and rare-earth-element (REE)-bearing carbonatite deposits that are mostly well explored and are partially mined or contain resources of these elements. The deposits represent only a part of the known 527 carbonatites around the world, but they are characterized by reliable quantitative data on ore tonnages and grades of niobium and REE. Grade and tonnage models are an important component of mineral resource assessments. Carbonatites present one of the main natural sources of niobium and rare-earth elements, the economic importance of which grows consistently. A purpose of this report is to update earlier publications. New information about known deposits, as well as data on new deposits published during the last decade, are incorporated in the present paper. The compiled database (appendix 1; linked to right) contains 60 explored Nb- and REE-bearing carbonatite deposits - resources of 55 of these deposits are taken from publications. In the present updated grade-tonnage model we have added 24 deposits comparing with the previous model of Singer (1998). Resources of most deposits are residuum ores in the upper part of carbonatite bodies. Mineral-deposit models are important in exploration planning and quantitative resource assessments for two reasons: (1) grades and tonnages among deposit types vary significantly, and (2) deposits of different types are present in distinct geologic settings that can be identified from geologic maps. Mineral-deposit models combine the diverse geoscience information on geology, mineral occurrences, geophysics, and geochemistry used in resource assessments and mineral exploration. Globally based deposit models allow recognition of important features and demonstrate how common different features are. Well-designed deposit models allow geologists to deduce possible mineral-deposit types in a given geologic environment, and the grade and tonnage models allow economists to

  3. Sedimentary dykes in the Oskarshamn-Vaestervik area. A study of the mechanism of formation

    Roeshoff, Kennert [BBK AB, Solna (Sweden); Cosgrove, John [Imperial College, London (United Kingdom). Dept. of Earth Sciences and Engineering


    This study of the sedimentary dykes from the Oskarshamn-Vaestervik area, near Aespoe and surrounding region, is aimed at understanding the mechanism of their formation. In particular it is important to establish whether or not they formed by the injection of high pressure fluidized sediments and if so what the likely effect of any future over pressured sediments will be on the stability of the fracture network in the basement rocks at Aespoe. This report is made up of a review of the literature on sedimentary dykes, a discussion of the various mechanical models for hydraulic fracturing and a description of the field and laboratory study carried out on the sedimentary dykes. The literature review indicates a remarkable consensus on the mode of formation of these structures based on their fabric (particularly layering generated in part by variation in clast size) and the composition of the infilling material. Two modes of origin have been recognised. These are the passive infilling of dykes where the dyke material has entered an open fracture under the influence of gravity, and active, i.e. forceful injection of a fluidized sediment under high pressure into a pre-existing fracture or into a fracture generated by the high pressure fluid. The discussion of the theory of fluid induced fracturing leads to the recognition of three systems which are the two end members and an intermediate form of a complete spectrum of materials ranging from unconsolidated and incohesive sediments, through cemented but porous rocks to crystalline rocks with no intrinsic porosity and whose only porosity relates to that imparted by the fracture network that the rock contains. The theory best suited to analyses this latter system is one based on fracture mechanics and is known as the theory of external hydraulic fracturing. From the point of view of the sedimentary dykes in the study area around the Aespoe Hard Rock Laboratory, where the dykes occur in the fractured granitic basement, this is

  4. A major light rare-earth element (LREE) resource in the Khanneshin carbonatite complex, southern Afghanistan

    Tucker, Robert D.; Belkin, Harvey E.; Schulz, Klaus J.; Peters, Stephen G.; Horton, Forrest; Buttleman, Kim; Scott, Emily R.


    The rapid rise in world demand for the rare-earth elements (REEs) has expanded the search for new REE resources. We document two types of light rare-earth element (LREE)-enriched rocks in the Khanneshin carbonatite complex of southern Afghanistan: type 1 concordant seams of khanneshite-(Ce), synchysite-(Ce), and parisite-(Ce) within banded barite-strontianite alvikite, and type 2 igneous dikes of coarse-grained carbonatite, enriched in fluorine or phosphorus, containing idiomorphic crystals of khanneshite-(Ce) or carbocernaite. Type 1 mineralized barite-strontianite alvikite averages 22.25 wt % BaO, 4.27 wt % SrO, and 3.25 wt % ∑ LREE2O3 (sum of La, Ce, Pr, and Nd oxides). Type 2 igneous dikes average 14.51 wt % BaO, 5.96 wt % SrO, and 3.77 wt % ∑ LREE2O3. A magmatic origin is clearly indicated for the type 2 LREE-enriched dikes, and type 1 LREE mineralization probably formed in the presence of LREE-rich hydrothermal fluid. Both types of LREE mineralization may be penecontemporaneous, having formed in a carbonate-rich magma in the marginal zone of the central vent, highly charged with volatile constituents (i.e., CO2, F, P2O5), and strongly enriched in Ba, Sr, and the LREE. Based on several assumptions, and employing simple geometry for the zone of LREE enrichment, we estimate that at least 1.29 Mt (million metric tonnes) of LREE2O3 is present in this part of the Khanneshin carbonatite complex.

  5. Carbonatite and alkaline intrusion-related rare earth element deposits–A deposit model

    Verplanck, Philip L.; Van Gosen, Bradley S.


    The rare earth elements are not as rare in nature as their name implies, but economic deposits with these elements are not common and few deposits have been large producers. In the past 25 years, demand for rare earth elements has increased dramatically because of their wide and diverse use in high-technology applications. Yet, presently the global production and supply of rare earth elements come from only a few sources. China produces more than 95 percent of the world's supply of rare earth elements. Because of China's decision to restrict exports of these elements, the price of rare earth elements has increased and industrial countries are concerned about supply shortages. As a result, understanding the distribution and origin of rare earth elements deposits, and identifying and quantifying our nation's rare earth elements resources have become priorities. Carbonatite and alkaline intrusive complexes, as well as their weathering products, are the primary sources of rare earth elements. The general mineral deposit model summarized here is part of an effort by the U.S. Geological Survey's Mineral Resources Program to update existing models and develop new descriptive mineral deposit models to supplement previously published models for use in mineral-resource and mineral-environmental assessments. Carbonatite and alkaline intrusion-related REE deposits are discussed together because of their spatial association, common enrichment in incompatible elements, and similarities in genesis. A wide variety of commodities have been exploited from carbonatites and alkaline igneous rocks, such as rare earth elements, niobium, phosphate, titanium, vermiculite, barite, fluorite, copper, calcite, and zirconium. Other enrichments include manganese, strontium, tantalum, thorium, vanadium, and uranium.

  6. Experimental and numerical investigation of the effect of basaltic dykes on transient saltwater intrusion

    Abdoulhalik, Antoifi; Ahmed, Ashraf; Hamill, Gerrard


    Heterogeneity in porous media is one of the major factors that control mixing zone and saltwater wedge dynamics. Basaltic dykes are natural geological structures that can significantly affect groundwater flow and solute transport in coastal aquifers. Few recent studies have investigated the effects of heterogeneity on the freshwater-saltwater mixing zone. However, most of these studies have focused on steady-state conditions. Furthermore, as per our knowledge no one has so far completed experiments to study the impact of basaltic dykes on transient saltwater intrusion. In this study, we have performed experiments in a laboratory-scale aquifer model to study saltwater intrusion process under different heterogeneous settings; a dyke was set at different locations and several values of thickness and permeability were tested. Using a variable-head groundwater system, a head difference was imposed across the porous media and images of the transient saltwater-wedge were recorded at thirty second intervals. The experimental data sets were simulated using the MODFLOW-family variable density flow code SEAWAT. The results show that under intruding-wedge conditions, the width of the mixing zone is almost two orders of magnitude larger in the presence of the dyke than it is in the homogeneous case, while it is more than ten times larger under receding-wedge conditions. A slight increase of the toe length was observed (around nine percent) in the presence of the dyke under intruding-wedge and receding-wedge conditions. When the permeability of the dyke is further reduced, it acts as an impervious barrier that almost prevents the progression of the saltwater wedge. Thus, saltwater is accumulated along the side boundary, and then forced to drain along the bottom boundary. The results highlight the significant effects of macroscopic variations in aquifer properties (such as volcanic dykes) in the temporal evolution of mixing zone dynamics (widening and narrowing) and the

  7. Toward a unified dynamic model for dykes and cone sheets in volcanic systems

    Galland, Olivier; Burchardt, Steffi; Hallot, Erwan; Mourgues, Régis; Bulois, Cédric


    Igneous sheet intrusions, such as dykes and cone sheets, represent various geometries of magma channels through the crust. In many volcanoes, they coexist as parts of complex plumbing systems and are likely fed by common sources. How they form is fundamental regarding volcanic hazards, but yet no dynamic model simulates and predicts satisfactorily the diversity of sheet intrusions observed in volcanic systems. Here we present scaled laboratory experiments that reproduced dyke and cone sheet intrusion geometries under controlled conditions. Combined to a parametric study, a dimensional analysis shows that two dimensionless numbers Π1 and Π2 govern the formation of these intrusions. Π1 is geometrical and describes the geometry of the magma source; Π2 is dynamical and compares the local viscous stresses in the flowing magma to the host-rock strength. Plotting our experiments against these two numbers results in a phase diagram evidencing a dyke and a cone-sheet field, separated by a sharp transition that fits a power law. This result shows that dykes and cone sheets correspond to two distinct physical regimes of magma emplacement in the Earth's crust. Cone sheets preferentially form when their source is shallow relative to their size, when the magma influx (or viscosity) is large, or when the host rock is weak. In addition, both dykes and cone sheets may form from the same source, the shift from one regime to the other being then controlled by magma dynamics, i.e. different values of Π2. We compare our phase diagram to geological data and show that the extrapolated empirical dyke-to-cone sheet transition predicts the occurrence of dykes and cone sheets in various natural volcanic settings. This study thus provides a unified dynamic model of sheet intrusions emplacement and captures fundamental mechanisms of magma transport in the Earth's crust.

  8. Carbonatite metasomatized peridotite xenoliths from southern Patagonia: implications for lithospheric processes and Neogene plateau magmatism

    Gorring, Matthew L.; Kay, Suzanne M.

    The mineral chemistry, major and trace element, and Sr-Nd isotopic composition of Cr-diopside, spinel peridotite xenoliths from the Estancia Lote 17 locality in southern Patagonia document a strong carbonatitic metasomatism of the backarc continental lithosphere. The Lote 17 peridotite xenolith suite consists of hydrous spinel lherzolite, wehrlite, and olivine websterite, and anhydrous harzburgite and lherzolite. Two-pyroxene thermometry indicates equilibration temperatures ranging from 870 to 1015°C and the lack of plagioclase or garnet suggests the xenoliths originated from between 40 and 60km depth. All of the xenoliths are LILE- and LREE-enriched, but have relatively low 87Sr/86Sr (0.70294 to 0.70342) and high ɛNd (+3.0 to +6.6), indicating recent trace element enrichment ( 25Ma, based on the low 87Sr/86Sr and high Rb concentrations of phlogopite separates) in the long-term, melt-depleted Patagonian lithosphere. Lote 17 peridotite xenoliths are divided into two basic groups. Group 1 xenoliths consist of fertile peridotites that contain hydrous phases (amphibole+/-phlogopite+/-apatite). Group 1 xenoliths are further subdivided into three groups (a, b, and c) based on distinctive textures and whole-rock chemistry. Group 1 xenolith mineralogy and chemistry are consistent with a complex metasomatic history involving variable extents of recent carbonatite metasomatism (high Ca/Al, Nb/La, Zr/Hf, low Ti/Eu) that has overprinted earlier metasomatic events. Group 2 xenoliths consist of infertile, anhydrous harzburgites and record cryptic metasomatism that is attributed to CO2-rich fluids liberated from Group 1 carbonatite metasomatic reactions. Extremely variable incompatible trace element ratios and depleted Sr-Nd isotopic compositions of Lote 17 peridotite xenoliths indicate that the continental lithosphere was neither the primary source nor an enriched lithospheric contaminant for Neogene Patagonian plateau lavas. Neogene plateau magmatism associated with formation

  9. The paleomagnetism and geological significance of Meso- proterozoic dyke swarms in the central North China Craton

    HOU; Guiting


    [1]Ma Xinghua, Zhang Zhengkun, Paleomagnetism and its application to plate tectonics, in The Basic Problems of Plate Tectonics (in Chinese), Beijing: Seismology Press, 1985, 119-142.[2]Zhang Wenzhi, Li Pu, The paleomagnetic characteristics of Sub-Sinian Erathem in Jixian of China, Bulletin of the Chinese Academy of Geological Science, Branch Bulletin of Geological Institute of Tianjin, 1980, 1(1): 111[3]Halls, H. C., Paleomagnetism, structure and longitudinal correlation of middle Precambrian dykes from northwestern Ontario and Minnesota, Can. J. Earth Sci., 1985, 23: 142.[4]Qian Xianglin, Chen Yaping, Late Precambrian mafic swarms of the north China Craton, in Mafic Dyke Swarms, Geological Association of Canada (eds. Halls, H. C., Fahrig, W. F.), 1987, Special Paper, 34: 385.[5]Chen Yaping, Qian Xianglin, The paleomagnetism study of Late Precambrian mafic dyke swarms in Lüliang inlier of Shanxi, Acta Scientiarum Naturalium Universitatis Pekinensis (in Chinese), 1987, 2: 87.[6]Ernst, R. E., Head, J. W., Parfitt, E. et al, Giant radiating dyke swarms on Earth and Venus, Earth-Science Reviews, 1995, 4: 229[7]Radhakrishns, T., Joseph. M., Proterozoic palaeomagnetism of the mafic dyke swarms is the high-grade region of southern India, Precambrian Research, 1996, 76: 31.[8]Li Jianghai, Qian Xianglin, Zhai Mingguo, The tectonic classification of granulite facies of North China and its Early Precambrian tectonic evolution, Scientia Geologica Sinica (in Chinese), 1997, 32: 254.[9]Hou Guiting, Zhang Chen, Qian Xianglin, The formation mechanism and tectonic stress field of Mesoproterozoic mafic dyke swarms in the North China Craton, Geological Review (in Chinese), 1998, 44(3): 309.[10]Li Jianghai, He Wenyuan, Qian Xianglin, Genetic mechanism and tectonic setting of Proterozoic mafic dyke swarm: its implication for paleoplate reconstruction, Geological Journal of China University (in Chinese), 1997, 3(3): 272.[11]Hou Guiting, Mu

  10. Thermal models of dyke intrusion during development of continent-ocean transition

    Daniels, K. A.; Bastow, I. D.; Keir, D.; Sparks, R. S. J.; Menand, T.


    A consensus has emerged in recent years from a variety of geoscientific disciplines that extension during continental rifting is achieved only partly by plate stretching: dyke intrusion also plays an important role. Magma intrusion can accommodate extension at lower yield stresses than are required to extend thick, strong, unmodified continental lithosphere mechanically, thereby aiding the breakup process. Dyke intrusion is also expected to heat and thereby weaken the plate, but the spatial extent of heating and the effect of different rates of magmatic extension on the timescales over which heating occurs are poorly understood. To address this issue, a numerical solution to the heat-flow equation is developed here to quantify the thermal effects of dyke intrusion on the continental crust during rifting. The thermal models are benchmarked against a priori constraints on crustal structure and dyke intrusion episodes in Ethiopia. Finite difference models demonstrate that magmatic extension rate exerts a first-order control on the crustal thermal structure. Once dyke intrusion supersedes faulting and stretching as the principal extensional mechanism the crust will heat and weaken rapidly (less than 1 Ma). In the Main Ethiopian Rift (MER), the majority of present-day extension is focused on ∼20 km-wide Quaternary-Recent axial magmatic segments that are mostly seismogenic to mid-crustal depths and show P-wave seismic velocities characteristic of heavily intruded continental crust. When reviewed in light of our models, these observations require that no more than half of the MER's extension since ∼2 Ma has been achieved by dyke intrusion. Magmatic heating and weakening of the crust would have rendered it aseismic if dyke intrusion accounted for the entire 6 mm/yr extension rate. In the older, faster extending (16 mm/yr) Red Sea rift (RSR) in Afar, dyke intrusion is expected to have had a more dramatic impact on crustal rheology. Accordingly, effective elastic plate

  11. Stable (C, O, S isotopes and whole-rock geochemistry of carbonatites from Alto Paranaíba Igneous Province, SE Brazil

    Caroline Siqueira Gomide

    Full Text Available ABSTRACT: The present work investigates the relationship between whole-rock geochemistry and stable isotope composition from carbonatites belonging to the Tapira, Araxá, Salitre, Serra Negra, Catalão I, and Catalão II alkaline-carbonatite complexes of the Alto Paranaiba Igneous Province (APIP, central Brazil and from the Jacupiranga Complex, of the Ponta Grossa Province, southeast Brazil. The APIP complexes are ultrapotassic, comprising bebedourites, phoscorites, nelsonites, and carbonatites, whereas Jacupiranga is a sodic complex composed of ijolite-series rocks, syenites, carbonatites, and alkaline gabbros. The geochemistry data allied to mineralogical constraints allowed us to classify the carbonatites into five groups, and to devise a chemical index (BaO/(BaO+SrO to gauge the magmatic evolution of the studied carbonatites.The APIP carbonatites evolve from apatite-rich calciocarbonatites toward Ba-, Sr-, and rare earth element (REE-rich magnesiocarbonatites. This evolution is mostly driven by apatite, phlogopite, dolomite, and calcite fractionation and consequent enrichment in monazite, norsethite, and strontianite. Stable isotope data show a wide diversity of petrogenetic processes in play at the APIP, relatively to the Jacupiranga Complex, which is interpreted as a result of the shallower intrusion levels of the APIP complexes. Such shallower emplacement, at low lithostatic pressure, allowed for a complex interplay of fractional crystallization, liquid immiscibility, degassing, and interaction with hydrothermal and carbohydrothermal systems.

  12. Natural occurrence and stability of pyrochlore in carbonatites, related hydrothermal systems, and weathering environments

    Lumpkin, G.R. [Australian Nuclear Science and Technology Organisation, Menai, New South Wales (Australia). Materials Div.; Mariano, A.N.


    Stoichiometric and non-stoichiometric (defect) pyrochlores crystallize during the magmatic and late magmatic-hydrothermal phases of carbonatite emplacement (T > 450--550 C, P < 2 kb). Defect pyrochlores can also form at low temperatures in laterite horizons during weathering. After crystallization, pyrochlore is subject to alteration by hydrothermal fluids (T {approximately} 550--200 C) and ground water. Alteration occurs primarily by ion exchange of low valence A-site cations together with O, F, and OH ions. The high valence cations Th and U are generally immobile; however, the authors have documented one example of hydrothermal alteration involving loss of U together with cation exchange at the B-site in samples from Mountain Pass, California. During laterite accumulation, the cation exchange rate of pyrochlore greatly exceeds the rate of matrix dissolution. The exceptional durability of pyrochlore in natural environments is related to the stability of the B-site framework cations. In carbonatites, defect pyrochlores may contain significant amounts of Si (up to 7.6 wt% SiO{sub 2}) which is negatively correlated with Nb.

  13. A link between geochemistry and geodynamics: carbonatites and kimberlites, Polar Siberia

    Rass, Irene


    Geophysical evidence indicates that the Moho surface beneath the northern Siberian Platform composes crests (or ranges) up to 14 km high above deeper areas and 50-80 to 150 km wide (Chernyshov and Bokaya, 1983). These ranges at the Moho likely mark ancient rift zones with a thinner crust. More than 70% kimberlites in structures surrounding the Anabar Shield occur along these Moho crests (Kravchenko et al., 1997; Rosen and Kostyuchenko, 1998). Carbonate-rich rocks that compose pipes, along with kimberlites, in kimberlite fields, were recognized as an individual type of carbonatite rocks: kimberlitic carbonatites (Lapin and Marshintsev, 1984). They abound in kimberlite fields of both Paleozoic and Mesozoic age southeast and east of the Anabar Shield. The liquidus temperatures of related kimberlites, determined based on their major-component chemistries, are 1429-1441оC and 1349-1518оC, respectively (Perchuk and Vaganov, 1980). Compared to classic carbonatites in ring complexes, kimberlitic carbonatites are characterized by the lowest relative concentrations of P and Sr, slightly lower REE, and high contents of Cr, Ti, and Zr (Rass, 1998). Mesozoic kimberlitic carbonatites exhibit a dependence of their geochemistry, position relative to the axial zones of the Moho crests, and the temperatures of the associated kimberlites, from the Kuoika to the Lower Kuonamka field: from trace elements between the silicate and carbonate components of the deep-sitting magmas. Their experimentally determined parameters are still scarce (Green, 1994) and obviously insufficient for any conclusions about the physicochemical conditions of the exsolution and/or melting of the parental magmas, so that any empirical dependences the identified in them provide information on the lateral heterogeneity of the mantle material in the northern Siberian Platform. References Chernyshov N.V. and Bokaya L.I., in: Structural Elements of the Earth's Crust and Their Evolution. Nauka, Novosibirsk, 1983

  14. Rethinking monogamy's nature: From the truth of non/monogamy to a dyke ethics of "antimonogamy".

    Willey, Angela


    Following Lynne Huffer's work on queer feminism, this abridged essay centers the figure of the lesbian in order to develop a dyke ethics that engenders nuanced thinking about both monogamy and embodiment. The essay reads Alison Bechdel's comic strip, Dykes to Watch Out For, to elaborate a "dyke ethics of anti-monogamy." Grounded in notions of friendship, community, and social justice, this ethics decenters the sexual dyad in a way that polyamory does not. It also insists upon a theoretical and ethical disposition of respect for the simultaneously political and embodied nature of desire. In so doing, it offers first a way of re-thinking the story of monogamy's nature as a naturecultural tale about mononormative desire and further places that desire in a field of relationality that renders its significance as a feature of humanness and an object of scientific inquiry strange.

  15. Experiment and Simulation of Turbulent Flow in Local Scour around a Spur Dyke

    Hao ZHANG; Hajime NAKAGAWA; Kenji KAWAIKE; Yasuyuki BABA


    The turbulent flow in the local scour hole around a single non-submerged spur dyke is investigated with both experimental and numerical methods.The experiments are conducted under clear-water scour regime with an impermeable spur dyke.The scour geometry and flow velocities are measured in details with a high-resolution laser displacement meter,electro-magnetic velocimetries and PIV (Particle image velocimetry).A 3D non-linear κ-ε model is developed to simulate the complex local flow field around the scour area.The numerical model is formulated using FVM (Finite volume method) on a collocated unstructured mesh,capable of resolving complex geometries and boundaries.It is found that the simulation results are reasonably consistent with those of the experimental measurements.Based on the study results,the nature of the flow structrue around a spur dyke with local scour hole is analyzed.

  16. 堤防加固设计中的若干技术问题%Problems about Design of Dyke Reinforcement

    ZHANG; Jia-fa


    The dyke experiences very high flood level more and more frequently. The timely issued " The Standard of Dyke Design" has played an important role in the design, measure fea sibility study and examination of dyke reinforcement. Safety appraisal is required before dyke rein forcement design. But, the conducted item is safety demonstration in the process of dyke reinforcement design at present. This paper suggests that at least 8 aspects should be considered in safety demo nstration. The effective water head is considered as the most important factor for dyke safety and reinfo rcement design. Seepage control measure design is an important part of dyke reinforcement design . Its correct train of thought is discussed in this paper. Some other factors for dyke reinforcement d esign are also pointed out.

  17. Controls on sill and dyke-sill hybrid geometry and propagation in the crust: The role of fracture toughness

    Kavanagh, J. L.; Rogers, B. D.; Boutelier, D.; Cruden, A. R.


    Analogue experiments using gelatine were carried out to investigate the role of the mechanical properties of rock layers and their bonded interfaces on the formation and propagation of magma-filled fractures in the crust. Water was injected at controlled flux through the base of a clear-Perspex tank into superposed and variably bonded layers of solidified gelatine. Experimental dykes and sills were formed, as well as dyke-sill hybrid structures where the ascending dyke crosses the interface between layers but also intrudes it to form a sill. Stress evolution in the gelatine was visualised using polarised light as the intrusions grew, and its evolving strain was measured using digital image correlation (DIC). During the formation of dyke-sill hybrids there are notable decreases in stress and strain near the dyke as sills form, which is attributed to a pressure decrease within the intrusive network. Additional fluid is extracted from the open dykes to help grow the sills, causing the dyke protrusion in the overlying layer to be almost completely drained. Scaling laws and the geometry of the propagating sill suggest sill growth into the interface was toughness-dominated rather than viscosity-dominated. We define KIc* as the fracture toughness of the interface between layers relative to the lower gelatine layer KIcInt / KIcG. Our results show that KIc* influences the type of intrusion formed (dyke, sill or hybrid), and the magnitude of KIcInt impacted the growth rate of the sills. KIcInt was determined during setup of the experiment by controlling the temperature of the upper layer Tm when it was poured into place, with Tm < 24 °C resulting in an interface with relatively low fracture toughness that is favourable for sill or dyke-sill hybrid formation. The experiments help to explain the dominance of dykes and sills in the rock record, compared to intermediate hybrid structures.

  18. Carbonatite magmatism of the southern Siberian Craton 1 Ga ago: Evidence for the beginning of breakup of Laurasia in the early Neoproterozoic

    Savelieva, V. B.; Danilova, Yu. V.; Bazarova, E. P.; Ivanov, A. V.; Kamenetsky, V. S.


    Apatite and biotite from dolomite‒ankerite and calcite‒dolomite carbonatite dikes emplaced into the Paleoproterozoic metamorphic rock complex in the southern part of the Siberian Craton are dated by the U-Pb (LA-ICP-MS) and 40Ar-39Ar methods, respectively. Proceeding from the lower intercept of discordia with concordia, the age of apatite from calcite‒dolomite carbonatite is estimated to be 972 ± 21 Ma and that for apatite from dolomite‒ankerite carbonatite, as 929 ± 37 Ma. Values derived from their upper intercept have no geological sense. The ages obtained for biotite by the 40Ar-39Ar method are 965 ± 9 and 975 ± 14 Ma. It means that the formation of carbonatites reflects the earliest phases of the Neoproterozoic stage in extension of the continental lithosphere.

  19. Dyke-path formation in relation to the eruptions of Eyjafjallajökull 2010 and Bardarbunga-Holuhraun 2014

    Gudmundsson, Agust


    Dykes are extension fractures and form when the magmatic overpressure is high enough to rupture (break) the host rock. Their formation is entirely analogous to that of many joints and human-made hydraulic fractures, such as are used to increase permeability in reservoirs. When generating their paths, dykes use existing weaknesses (e.g., cooling joints) in the host rock. The maximum depth of large tension fractures below the surface of a rift zone, however, is mostly less than a few hundred metres. If the fractures extend to greater depths, they must change into closed normal faults which are generally not used as magma paths. There are thus no large tension fractures or wide-open faults at great depths ready to be filled with magma to form a dyke. While magma flow in dykes, as in other fluid-driven fractures, is at any point in various directions dyke segmentation may indicate the overall large-scale flow direction. Thus, dykes composed of large-spaced disconnected segments in lateral sections are primarily formed in vertical magma flow at segmentation depth whereas those composed of large-spaced disconnected segments in vertical sections are primarily formed in lateral magma flow. The far-field displacement and stress fields of segmented dykes are similar to those generated by single, continuous dykes of similar dimensions, particularly when the distances between the nearby tips of the segments become small in comparison with segment lengths. Most dykes become arrested and never supply magma to eruptions. Feeder-dykes normally reach the surface only along parts of their lengths (strike-dimensions). The volumetric flow or effusion rate of magma through a feeder-dyke or volcanic fissure depends on the aperture (opening) of the dyke or fissure in the 3rd power. All these theoretical and observational results are here applied to the dyke emplacements associated with the eruptions of Eyjafjallajökull 2010 and Bardarbunga-Holuhraun 2014. The results make it possible to

  20. Evidence for the Multi-Stage Petrogenetic History of the Oka Carbonatite Complex (Québec, Canada) as Recorded by Perovskite and Apatite

    Wei Chen; Antonio Simonetti


    The Oka complex is amongst the youngest carbonatite occurrences in North America and is associated with the Monteregian Igneous Province (MIP; Québec, Canada). The complex consists of both carbonatite and undersaturated silicate rocks (e.g., ijolite, alnöite), and their relative emplacement history is uncertain. The aim of this study is to decipher the petrogenetic history of Oka via the compositional, isotopic and geochronological investigation of accessory minerals, perovskite and apatite, ...

  1. Compositional variation in apatite, phlogopite and other accessory minerals of the ultramafic Delitzsch complex, Germany: implication for cooling history of carbonatites

    Seifert, W.; Horst Kämpf; J. Wasternack;  ,


    A representative suite of samples from the ultramafic lamprophyre–carbonatite (UML–CR) complex of Delitzsch, Germany, shows significant variations in mineral composition and geothermobarometry. Petrographically distinct carbonatites of intrusive dolomitic and subvolcanic dolomitic and subvolcanic calcitic types clearly show marked compositional differences in such minerals as apatite, phlogopite and pyrochlore. Increasing concentrations are established for S, Cl, Si in apatite, and Ti, Al, Cr...

  2. A forced-gradient tracer test on the Hansrivier Dyke: Beaufort West ...


    Feb 16, 2011 ... ability. Furthermore, diffusion of a tracer into fractures and rock matrix has a universal ... Location map for the Beaufort West study area ... the ground surface in the Beaufort West region, particularly ... effects, these dykes have caused fracturing of adjacent rocks .... The volume of both the tracer and chase.

  3. Calcite and dolomite in intrusive carbonatites. II. Trace-element variations

    Chakhmouradian, Anton R.; Reguir, Ekaterina P.; Couëslan, Christopher; Yang, Panseok


    The composition of calcite and dolomite from several carbonatite complexes (including a large set of petrographically diverse samples from the Aley complex in Canada) was studied by electron-microprobe analysis and laser-ablation inductively-coupled-plasma mass-spectrometry to identify the extent of substitution of rare-earth and other trace elements in these minerals and the effects of different igneous and postmagmatic processes on their composition. Analysis of the newly acquired and published data shows that the contents of rare-earth elements (REE) and certain REE ratios in magmatic calcite and dolomite are controlled by crystal fractionation of fluorapatite, monazite and, possibly, other minerals. Enrichment in REE observed in some samples (up to ~2000 ppm in calcite) cannot be accounted for by coupled substitutions involving Na, P or As. At Aley, the REE abundances and chondrite-normalized (La/Yb)cn ratios in carbonates decrease with progressive fractionation. Sequestration of heavy REE from carbonatitic magma by calcic garnet may be responsible for a steeply sloping "exponential" pattern and lowered Ce/Ce* ratios of calcite from Magnet Cove (USA) and other localities. Alternatively, the low levels of Ce and Mn in these samples could result from preferential removal of these elements by Ce4+- and Mn3+-bearing minerals (such as cerianite and spinels) at increasing f(O2) in the magma. The distribution of large-ion lithophile elements (LILE = Sr, Ba and Pb) in rock-forming carbonates also shows trends indicative of crystal fractionation effects (e.g., concomitant depletion in Ba + Pb at Aley, or Sr + Ba at Kerimasi), although the phases responsible for these variations cannot be identified unambiguously at present. Overall, element ratios sensitive to the redox state of the magma and its complexing characteristics (Eu/Eu*, Ce/Ce* and Y/Ho) are least variable and in both primary calcite and dolomite, approach the average chondritic values. In consanguineous

  4. 3D magnetotelluric modelling of the Alnö alkaline and carbonatite ring complex, central Sweden

    Yan, Ping; Andersson, Magnus; Kalscheuer, Thomas; García Juanatey, María A.; Malehmir, Alireza; Shan, Chunling; Pedersen, Laust B.; Almqvist, Bjarne S. G.


    Thirty-four broadband magnetotelluric stations were deployed across the Alnö alkaline and carbonatite ring intrusion in central Sweden. The measurements were designed such that both 2D models along existing seismic profiles and a 3D model can be constructed. Alnö Island and surrounding areas are densely populated and industrialized and in order to reduce the effect of noise, the remote reference technique was utilized in time series processing. Strike and dimensionality analyses together with the induction arrows show that there is no homogeneous regional strike direction in this area. Therefore, only the determinant of the impedance tensor was used for 2D inversion whereas all elements of the impedance tensor were used for 3D inversion. Representative rock samples were collected from existing outcrops and their resistivities were measured in the laboratory to facilitate interpretation of the inversion models. The results from these measurements show that coarse-grained (sövite, white color) and fine-grained (dark color) carbonatites are the most conductive and resistive rock types, respectively. In accordance with the interpretation of the reflection seismic images, the 2D and 3D resistivity models depict the caldera-related ring-type fault system and updoming faulted and fractured systems as major 10-500 Ωm conductors, extending down to about 3 km depth. A central ~ 4000 Ωm resistive unit at about 3 km depth appears to correspond to a solidified fossil magma chamber as speculated from the reflection seismic data and earlier field geological studies.

  5. Dihedral angle of carbonatite melts in mantle residue near the upper mantle and transition zone

    Ghosh, S. K.; Rohrbach, A.; Schmidt, M. W.


    Carbonate melts are thought to be ideal metasomatic agents in the deep upper mantle (Green & Wallace, 1988) and these melts are low in viscosities (10-1-10-3 Pa·s) compared to primitive basalt (101-102 Pa·s), furthermore the ability to form an interconnected grain-edge melt network at low melt fractions (3 GPa (Dasgupta et al. 2006, Ghosh et al., 2009), dissolve a number of geochemically incompatible elements much better than silicate melts (Blundy and Dalton, 2000). Previous studies of carbonate melt dihedral angles in olivine-dominated matrices yielded 25-30oat 1-3 GPa, relatively independent of melt composition (Watson et al., 1990) and temperature (Hunter and McKenzie, 1989). Dihedral angles of carbonate melts in contact with deep mantle silicate phases (e.g. garnet, wadsleyite, and ringwoodite) which constitute more than 70 % of the deep upper mantle and transition zone have not been studied yet. We have performed multi-anvil experiments on carbonate-bearing peridotites with 5.0 wt% CO2 from 13.5 to 20 GPa 1550 oC to investigate the dihedral angle of magnesio-carbonatite melts in equilibrium with garnet, olivine (and its high-pressure polymorphs), and clinoenstatite. The dihedral angle of carbonate melts in the deep upper mantle and transition zone is ~30° for majorite garnet and olivine (and its polymorphs) dominated matrices. It does not change with increasing pressure in the range 13.5-20 GPa. Our results suggest that very low melt fractions of carbonatite melt forming in the deep upper mantle and transition zone are interconnected at melt fractions less than 0.01. Consistent with geophysical observations, this could possibly explain low velocity regions in the deep mantle and transition zone.

  6. Evidences for multiple remagnetization of Proterozoic dykes from Iguerda inlier (Anti-Atlas Belt, Southern Morocco)

    Neres, Marta; Silva, Pedro F.; Ikene, Moha; Martins, Sofia; Hafid, Ahmid; Mata, João; Almeida, Francisco; Youbi, Nasrrddine; Boumehdi, Ahmed


    Paleomagnetic data able to constrain the paleoposition of the West African Craton (WAC) during Paleo-Mesoproterozoic are absent, mainly due to gaps on the sedimentary record and intense remagnetizations. Dykes that intrude several Proterozoic inliers of WAC in the Anti-Atlas Belt (southern Morocco) have recently been subjected to geochronological studies, which revealed ages between Paleoproterozoic and early Neoproterozoic. Therefore, these dykes represent a window of opportunity for paleomagnetic studies aiming to infer about the paleoposition of WAC during Proterozoic. On this scope we conducted a paleomagnetic study on seven Proterozoic dykes of the Iguerda inlier. We determined the paleomagnetic directions and evaluated their meaning by rock magnetic and mineral analyses, complemented by petrographic observations. Results revealed that these rocks record the presence of a complex history of remagnetization events, mostly assigned to several Phanerozoic thermal/chemical events. In particular, we found components assigned to the late stages of Pan African orogeny (s.l.), to the Late Carboniferous Variscan orogeny, and to more recent events. The recognized remagnetization processes are related to widespread metamorphic events under greenschist facies followed by low-temperature oxidation, both responsible for the formation of new magnetic phases (magnetite and hematite). The primary (magmatic) thermo-remanent magnetization of the dykes was obliterated during these events through multiple thermal and chemical remagnetizations. For only one dyke the presence of primary magnetization is possible to infer, though not to confirm, and would place WAC at an equatorial position around 1750 Ma. The authors wish to acknowledge FCT (Portugal) - CNRST (Morocco) bilateral agreement for its major contribution without which this work wouldn't be possible. Publication supported by project FCT UID/GEO/50019/2013 - Instituto Dom Luiz.

  7. The antecryst compositional influence on Cretaceous alkaline lamprophyre dykes, SE Brazil

    Saulo Gobbo Menezes

    Full Text Available The question of whether the antecryst assemblage affects the bulk composition of lamprophyre dykes, and could be responsible for the compositional zonation between their centers and borders is addressed through a detailed study involving four monchiquite and camptonite dykes (basanites and tephrites representative of the Arco de Ponta Grossa and Serra do Mar alkaline provinces. In them, antecrysts are interpreted as early-crystallized minerals that are no longer in equilibrium with their host-liquid, albeit still linked to the same magmatic system. They represent recycled crystals of earlier stages of the magmatic system at depth. The antecryst microtextures, such as zoned clinopyroxene megacrysts (augite cores and titanaugite rims with partly corroded cores, olivine crystals with corroded rims surrounded by biotite coronas, chrome-spinel inclusions in clinopyroxene and olivine megacryst cores, and titanomagnetite crystals surrounded by biotite coronas, suggest chemical re-equilibrium with the matrix. The greatest antecryst cargo in these dykes is found in their centers. After subtracting the antecryst volume from the center analyses of each body, the calculated compositions are very similar to the border analyses. The mafic antecryst cargo of each occurrence proportionally leads to enrichment of MgO, FeO, TiO2, CaO, compatible trace elements (Cr, Ni and Co, and depletion of SiO2, K2O, Na2O, Al2O3 and incompatible trace elements (Ba, Sr and REE. The whole-rock geochemical analyses of each dyke represent the combination of accumulated crystals and melt. The compositional zonation of the studied dykes is associated with the antecryst cargo rather than different magmatic pulses.

  8. Dyke swarms and their role in the genesis of world-class gold deposits: Insights from the Jiaodong peninsula, China

    Li, Lin; Li, Sheng-Rong; Santosh, M.; Li, Qing; Gu, Yue; Lü, Wen-Jie; Zhang, Hua-Feng; Shen, Jun-Feng; Zhao, Guo-Chun


    Jiaodong peninsula, located at the southeastern margin of the North China Craton, is well known for its rich endowment of super-large gold deposits. This region is also characterized by hundreds of intermediate - mafic dykes that cluster into several dyke swarms. In this study, we present zircon U-Pb ages which show that the timing of dyke emplacement as ca. 120 Ma, which followed the crystallization of the (quartz-) diorite porphyry at ca. 130 Ma. These ages coincide with the peak ages reported for magmatism and metallogeny in the central North China Craton. The various ages (2450-2570 and 154 Ma) from the inherited zircon crystals in these rocks suggest that substantial lower to middle crustal basement rocks and Jurassic granitoids were involved during dyke emplacement. The dyke swarms, varying between alkaline and subalkaline, are compositionally low-Si low-Ti lamprophyre and low-Si high-Ti dolerite porphyry in the western of the Jiaodong peninsula, whereas those in the eastern part are composed of both high-Si low-Ti and low-Si high-Ti lamprophyres. These features imply multiple sources for the dykes from convective asthenospheric mantle to ancient enriched lithospheric mantle with magma generation at different depths involving mixture of slab-derived hydrous fluids. The source magmas of the dykes were hydrous and enriched in volatiles as well as ore components, and their evolution occurred under high oxygen fugacity conditions. The relatively rapid emplacement and cooling of the dyke systems enabled the migration of fluids into ore-controlling faults or fractures. We envisage that the dyke swarms played an important role in generating the world-class gold mineralization of Jiaodong.

  9. U-Pb baddeleyite ages for the Scourie dyke swarm, Scotland: evidence for two distinct intrusion events

    Heaman, L. M.; Tarney, J.


    PRECISE and accurate radiometric ages for continental mafic dyke swarms are a prerequisite for global correlation of mafic magmatic events, calibration of apparent polar-wander paths and deciphering mechanisms of dyke emplacement. Precambrian dyke swarms, such as the Scourie dyke swarm in north-west Scotland, are invaluable time-markers, so that a precise and accurate knowledge of their emplacement age is critical when unravelling the complex geological evolution of many terrains. Precise dating is often difficult, however, because magma interaction with country rock and subsequent metamorphic events can severely perturb some isotopic systems. Recent advances in U-Pb geochronology1-3 combined with the discovery that some mafic dykes contain trace amounts of uranium-bearing minerals such as baddeleyite (ZrO2) and/or zircon have made it possible to obtain U-Pb ages for these rocks with a precision typically on the order of 1-2 Myr4,5. Some of the first detailed U-Pb studies of Precambrian mafic dyke swarms5,6 have shown that large volumes of mafic magma, 100,000 km3, were emplaced into the continental crust in surprisingly short periods of time (<2 Myr). Here we report the results from a U-Pb study of three members of the Scourie dyke swarm, and find at least two periods of dyke emplacement at 2,418 and 1,992 Myr BP. We speculate on a potential global correlation of early Proterozoic mafic magmatism and hence on the origin of dyke swarms.

  10. ArcGIS studies and field relationships of Paleoproterozoic mafic dyke swarms from the south of Devarakonda area, Eastern Dharwar Craton, southern India: Implications for their relative ages

    Amiya K Samal; Rajesh K Srivastava; Lokesh K Sinha


    Google Earth Image and cross-cutting field relationships of distinct Paleoproterozoic mafic dykes from south of Devarakonda area in the Eastern Dharwar Craton has been studied to establish relative emplacement ages. The Devarakonda, covering an area of ∼700 km2, shows spectacular cross-cutting field relationships between different generations of mafic dykes, and is therefore selected for the present study. Although some recent radiometric age data are available for distinct Paleoproterozoic mafic dykes from the Eastern Dharwar Craton, there is no analogous age data available for the study area. Therefore, relative age relationships of distinct mafic dykes have been established for the study area using cross-cutting field relationships and GIS techniques, which shows slightly different picture than other parts of the Eastern Dharwar Craton. It is suggested that NE–SW trending mafic dykes are youngest in age (probably belong to ∼1.89 Ga dyke swarm), whereas NNW–SSE trending mafic dykes have oldest emplacement age. Further, the NNW–SSE mafic dykes are older to the other two identified mafic dyke swarms, i.e., WNW–ESE (∼2.18 Ga) and N–S trending (∼2.21 Ga) mafic dyke swarms, as dykes of these two swarms cross-cut a NNW–SSE dyke. It provides an evidence for existence of a new set of mafic dykes that is older to the ∼2.21 Ga and probably younger to the ∼2.37 Ga swarm. Present study also supports existence of two mafic dyke swarms having similar trend (ENE–WSW to NE–SW) but emplaced in two different ages (one is ∼2.37 Ga and other ∼1.89 Ga).

  11. Structure and tectonic setting of the SE Sardinia mafic dyke swarm. Insights for the stress state during magma emplacement in the upper crust

    Martinez-Poza, Ana Isabel; Druguet, Elena


    The SE Sardinia mafic dyke swarm intruded in Permian times into the Late Variscan granitoids of the Sàrrabus massif. In order to characterize the structure of the dyke swarm and to assess the stress state and tectonic regime at the time of dyking, we have performed a multi-methodological study which encompasses paleostress analysis using the orientation distribution of dykes, estimation of crustal extension from dyke thickness/spacing ratios and true dilation direction from the matching geometry of offsets. The mean orientation of the dyke swarm is ∼N150°, with secondary main trends orientated ∼N77° and ∼N10°. The fracture network (mostly joints) exhibits multiple orientations grouped in four or more sets, being the orientation and density patterns in granitoid and dykes significantly different. Some of the pre-existing joints were exploited by the dykes, while others were reactivated as faults during and after dyke intrusion. The paleostress analysis yielded σ1 sub-vertical, indicating that an extensional tectonic regime predominated in the area during the emplacement of the dyke swarm. σ3 was sub-horizontal, sub-parallel to the mean NE-SW dilation direction. The inferred relative stress magnitudes are characterized by a σ1 much larger than the other two principal stresses. In this context, intrusion of the dyke swarm occurred under low magma pressure conditions and preferentially into a pre-existing joint nerwork during a regional extensional event. The SE Sardinian dyke swarm has been compared with other contemporary mafic dykes of the western Mediterranean region, by attempting to restore the effects of the Neogene and eo-Alpine rotational events. The reconstruction gives a complex crustal-scale pattern in terms of dyke orientation, a fact that could be partly attributed to differential rotations associated with localized strike-slip movements that might have operated coevally with regional extension or transtension during Permian times.

  12. Preliminary analysis of thermal-infrared multispectral scanner data of the Iron Hill, Colorado carbonatite-alkalic rock complex

    Rowan, Lawrence C.; Watson, Kenneth; Miller, Susanne H.


    The Iron Hill carbonatite-alkalic igneous rock complex is in the Powderhorn mining district, approximately 40 km south-southwest of Gunnison, Colorado. The complex, which occupies about 30 sq km, was emplaced in metasedimentay and metavolcanic rocks during the later Precambrian or early Cambrian. The main rock types in the complex, from oldest to youngest, are fenite, pyroxenite, uncompahgrite, ijolite, nepheline syenite, and dolomitic carbonatite. The carbonatite is limonitic and forms an elliptially shaped 4 sq km stock. Calcitic and dolomitic carbonatite dikes are also numerous throughout the complex and in the pre-existing rocks. Pyroxenite is the most widespread rock type within the complex, but pyroxene is extensively altered to biotite, phlogopite, and vermiculite. Fenite, which formed through Na, K-metasomatism of the country rocks, typically contains more feldspar and less quartz than the equivalent unaltered country rocks. The other alkalic rock types are less widespread and less well exposed. Parts of the complex are covered by Oligocene ash-flow tuff and alluvial, colluvial, and glacial deposits. Sagebrush and grass cover is moderately dense to very dense at low to intermediate elevations; coniferous tree cover is dense at high elevations and on some north-facing slopes at lower elevations. A new algorithm was used to compute spectral emissivity ratios, independent of any emissivity assumptions. This algorithm has the advantage that any of the possible emissivity ratios can be computed and, thus, a large variety of composite ratio images can be constructed, which permits examination of various geologic hypotheses based on the spectral properties of the surface materials.

  13. Carbonatite associated with ultramafic diatremes in the Avon Volcanic District, Missouri, USA: Field, petrographic, and geochemical constraints

    Shavers, Ethan J.; Ghulam, Abduwasit; Encarnacion, John; Bridges, David L.; Luetkemeyer, P. Benjamin


    Here we report field, petrographic, and geochemical analyses of the southeast Missouri Avon Volcanic District intrusive rocks and present the first combined textural and geochemical evidence for the presence of a primary magmatic carbonatite phase among ultramafic dikes, pipes, and diatremes of olivine melilitite, alnöite, and calciocarbonatite. The δ13CVPDB values measured for primary calciocarbonatite as well as carbonates in olivine melilitite and alnöite rocks range from - 3.8‰ to - 8.2‰, which are within the typical range of mantle values and are distinct from values of the carbonate country rocks, 0.0‰ to - 1.3‰. The carbonate oxygen isotope compositions for the intrusive lithologies are in the range of 21.5‰ to 26.2‰ (VSMOW), consistent with post-emplacement low temperature hydrothermal alteration or kinetic fractionation effects associated with decompression and devolatilization. Metasomatized country rock and breccia-contaminated igneous lithologies have carbonate δ13CVPDB values gradational between primary carbonatite values and country rock values. Unaltered sedimentary dolomite breccia and mafic spheroids entrained by calciocarbonatite and the lack of microstratigraphic crystal growth typical of carbonate replacement, also exclude the possibility of hydrothermal replacement as the cause of the magmatic-textured carbonates. Rare earth element (REE) patterns for the alnöite, olivine melilitite, and carbonatite are similar to each other with strong light REE enrichment and heavy REE depletion relative to MORB. These patterns are distinct from those of country rock rhyolite and sedimentary carbonate. These data suggest that rocks of the Avon Volcanic District represent a single ultramafic-carbonatite intrusive complex possibly derived from a single mantle source.

  14. Trace element and isotopic composition of apatite in carbonatites from the Blue River area (British Columbia, Canada) and mineralogy of associated silicate rocks

    Mitchell, Roger; Chudy, Thomas; McFarlane, Christopher R. M.; Wu, Fu-Yuan


    Apatites from the Verity, Fir, Gum, Howard Creek and Felix carbonatites of the Blue River (British Columbia, Canada) area have been investigated with respect to their paragenesis, cathodoluminescence, trace element and Sr-Nd isotopic composition. Although all of the Blue River carbonatites were emplaced as sills prior to amphibolite grade metamorphism and have undergone deformation, in many instances magmatic textures and mineralogy are retained. Attempts to constrain the U-Pb age of the carbonatites by SIMS, TIMS and LA-ICP-MS studies of zircon and titanite were inconclusive as all samples investigated have experienced significant Pb loss during metamorphism. The carbonatites are associated with undersaturated calcite-titanite amphibole nepheline syenite only at Howard Creek although most contain clasts of disaggregated phoscorite-like rocks. Apatite from each intrusion is characterized by distinct, but wide ranges, in trace element composition. The Sr and Nd isotopic compositions define an array on a 87Sr/86Sr vs²Nd diagram at 350 Ma indicating derivation from depleted sub-lithospheric mantle. This array could reflect mixing of Sr and Nd derived from HIMU and EM1 mantle sources, and implies that depleted mantle underlies the Canadian Cordillera. Although individual occurrences of carbonatites in the Blue River region are mineralogically and geochemically similar they are not identical and thus cannot be considered as rocks formed from a single batch of parental magma at the same stage of magmatic evolution. However, a common origin is highly probable. The variations in the trace element content and isotopic composition of apatite from each occurrence suggest that each carbonatite represents a combination of derivation of the parental magma(s) from mineralogically and isotopically heterogeneous depleted mantle sources coupled with different stages of limited differentiation and mixing of these magmas. We do not consider these carbonatites as primary direct

  15. Radial patterns of bitumen dykes around Quaternary volcanoes, provinces of northern Neuquén and southernmost Mendoza, Argentina

    Cobbold, Peter R.; Ruffet, Gilles; Leith, Leslie; Loseth, Helge; Rodrigues, Nuno; Leanza, Hector A.; Zanella, Alain


    Where the Neuquén Basin of Argentina abuts the Andes, hundreds of veins of solid hydrocarbon (bitumen) are visible at the surface. Many of these veins became mines, especially in the last century. By consensus, the bitumen has resulted from maturation of organic-rich shales, especially the Vaca Muerta Fm of Late Jurassic age, but also the Agrio Fm of Early Cretaceous age. To account for their maturation, recent authors have invoked regional subsidence, whereas early geologists invoked magmatic activity. During 12 field seasons (since 1998), we have tracked down the bitumen localities, mapped the veins and host rocks, sampled them, studied their compositions, and dated some of them. In the provinces of northern Neuquén and southernmost Mendoza, the bitumen veins are mostly sub-vertical dykes. They tend to be straight and continuous, crosscutting regional structures and strata of all ages, from Jurassic to Palaeocene. Most of the localities lie within 70 km of Tromen volcano, although four are along the Rio Colorado fault zone and another two are at the base of Auca Mahuida volcano. On both volcanic edifices, lavas are of late Pliocene to Pleistocene age. Although regionally many of the bitumen dykes tend to track the current direction of maximum horizontal tectonic stress (ENE), others do not. However, most of the dykes radiate outward from the volcanoes, especially Tromen. Thicknesses of dykes tend to be greatest close to Tromen and where the host rocks are the most resistant to fracturing. Many of the dykes occur in the exhumed hanging walls of deep thrusts, especially at the foot of Tromen. Here the bitumen is in places of high grade (impsonite), whereas further out it tends to be of medium grade (grahamite). A few bitumen dykes contain fragments of Vaca Muerta shale, so that we infer forceful expulsion of source rock. At Curacó Mine, some shale fragments contain bedding-parallel veins of fibrous calcite (beef) and these contain some bitumen, which is

  16. Variscan potassic dyke magmatism of durbachitic affinity at the southern end of the Bohemian Massif (Lower Austria)

    Zeitlhofer, Helga; Grasemann, Bernhard; Petrakakis, Konstantin


    Dykes in the Strudengau area (SW Moldanubian Zone, Austria) can be mineralogically divided into lamprophyres (spessartites and kersantites) and felsic dykes (granite porphyries, granitic dykes and pegmatoid dykes). Geochemical analyses of 11 lamprophyres and 7 felsic dykes show evidence of fractional crystallization. The lamprophyres are characterized by metaluminous compositions, intermediate SiO2 contents and high amounts of MgO and K2O; these rocks have high Ba (800-3000 ppm) and Sr (250-1000 ppm) contents as well as an enrichment of large-ion lithophile elements over high field strength elements, typical for enriched mantle sources with variable modifications due to fractionation and crustal contamination. This geochemical signature has been reported from durbachites (biotite- and K feldspar-rich mela-syenites particularly characteristic of the Variscan orogen in Central Europe). For most major elements, calculated fractionation trends from crystallization experiments of durbachites give an excellent match with the data from the Strudengau dykes. This suggests that the lamprophyres and felsic dykes were both products of fractional crystallization and subsequent magma mixing of durbachitic and leucogranitic melts. Rb-Sr geochronological data on biotite from five undeformed kersantites and a locally deformed granite porphyry gave cooling ages of c. 334-318 Ma, indicating synchronous intrusion of the dykes with the nearby outcropping Weinsberger granite (part of the South Bohemian Batholith, c. 330-310 Ma). Oriented matrix biotite separated from the locally deformed granite porphyry gave an Rb-Sr age of c. 318 Ma, interpreted as a deformation age during extensional tectonics. We propose a large-scale extensional regime at c. 320 Ma in the Strudengau area, accompanied by plutonism of fractionated magmas of syncollisional mantle-derived sources, mixed with crustal components. This geodynamic setting is comparable to other areas in the Variscan belt documenting an

  17. Use of gravity drainage and quasi-homogenous dykes for containment of oil sands tailings

    Nichols, L.; Czajewski, K. [Terracon Geotechnique Ltd., Calgary, AB (Canada)


    Solutions to the disposal of byproducts from oil sands processing into tailings ponds in Alberta were examined. Gravity drainage of composite tailings (CT) was used as a mechanism to facilitate the consolidation of CT in critical areas of the containment ponds through the use of internal sand layers within the body of the deposit. Critical areas were defined as the areas around the perimeters of the containment ponds. The aim of the solution was to provide long-term stability to the disposal area through the creation of stiff deposits around the perimeter and through the facilitation of reclamation efforts on the surface. It was concluded that use of the quasi-homogenous dykes is the only commercially proven method of reducing the fine tailings inventory of the oil sands industry. It was concluded that the use of gravity drainage and quasi-homogenous dykes for oil sands containment structures will assist the industry in reducing its environmental footprint.

  18. Crystal chemistry of pyrochlore from the Mesozoic Panda Hill carbonatite deposit, western Tanzania

    Boniface, Nelson


    The Mesozoic Panda Hill carbonatite deposit in western Tanzania hosts pyrochlore, an ore and source of niobium. This study was conducted to establish the contents of radioactive elements (uranium and thorium) in pyrochlore along with the concentration of niobium in the ore. The pyrochlore is mainly hosted in sövite and is structurally controlled by NW-SE (SW dipping) or NE-SW (NW dipping) magmatic flow bands with dip angles of between 60° and 90°. Higher concentrations of pyrochlore are associated with magnetite, apatite and/or phlogopite rich flow bands. Electron microprobe analyses on single crystals of pyrochlore yield very low UO2 concentrations that range between 0 and 0.09 wt% (equivalent to 0 atoms per formula unit: a.p.f.u.) and ThO2 between 0.55 and 1.05 wt% (equivalent to 0.1 a.p.f.u.). The analyses reveal high concentrations of Nb2O5 (ranging between 57.13 and 65.50 wt%, equivalent to a.p.f.u. ranging between 1.33 and 1.43) and therefore the Panda Hill Nb-oxide is classified as pyrochlore sensu stricto. These data point to a non radioactive pyrochlore and a deposit rich in Nb at Panda Hill. The Panda Hill pyrochlore has low concentrations of REEs as displayed by La2O3 that range between 0.10 and 0.49 wt% (equivalent to a.p.f.u. ranging between 0 and 0.01) and Ce2O3 ranging between 0.86 and 1.80 wt% (equivalent to a.p.f.u. ranging between 0.02 and 0.03), Pr2O3 concentrations range between 0 and 0.23 wt% (equivalent to 0 a.p.f.u.), and Y2O3 is 0 wt% (equivalent to 0 a.p.f.u.). The abundance of the REEs in pyroclore at the Panda Hill Carbonatite deposit is of no economic significance.

  19. Dyking at EPR 16°N hypermagmatic ridge segment: Insights from near-seafloor magnetics

    Szitkar, Florent; Dyment, Jérôme; Le Saout, Morgane; Honsho, Chie; Gente, Pascal


    High-resolution, near-seafloor magnetic data have been acquired over the 16°N hypermagmatic segment of the East-Pacific Rise using an Autonomous Underwater Vehicle. This survey proves to be ideal to test the relative efficiency of various inversion methods applied to data acquired at a more or less constant altitude above the seafloor. Unlike other methods, a recently published Bayesian inversion preserves the short wavelengths and allows for the resolution of a high-resolution reduced-to-the-pole magnetic anomaly. This anomaly unveils the presence of several laterally adjacent dykes associated with individually separated Axial Summit Troughs. The observation of such anomalies, and therefore of shallow dykes, confirms the hypermagmatic character of the segment in a location where complex magma chambers have been imaged in seismic reflection studies. Variable intensity of the magnetic anomalies reflects the depth of the dyke swarms and, ultimately, the timing and style of eruptive events, helping to constrain the spreading axis evolution.

  20. Petrology of the prehistoric lavas and dyke of the Barren Island, Andaman Sea, Indian Ocean

    M A Alam; D Chandrasekharam; O Vaselli; B Capaccioni; P Manetti; P B Santo


    Although Barren Island (Andaman Sea, Indian Ocean) witnessed several volcanic eruptions during historic times, the eruptions that led to the formation of this volcanic island occurred mainly during prehistoric times. It is still active and currently in the fumarolic stage. Its volcanic evolution appears to be characterized by a constructive phase with the piling up of lava flows and scoria deposits and Strombolian activities, followed by a sudden collapse of the main cone. Deposits of a possible caldera-forming eruption were not recognized earlier. After a period of peri-calderic hydromagmatic activity, whose deposits presently mantle inner and outer caldera walls, a new phase of intracalderic Vulcanian activities took place. A prominent dyke in the SE inner side of the caldera wall was recognized. Petrographically the lava flows and dyke are similar but they differ in their chemical composition (viz., SiO2, MgO, Ni, Cr) significantly. Similarity in major, minor and trace element composition (viz., K/La, K/Nb, K/Rb, K/Ti ratios) of these rocks together with Chondrite normalized trace element (Rb, Ba, Sr, P, Zr, Ti and Nb) and REE (La, Ce, Nd and Y) patterns of the Barren Island prehistoric lava flows and dyke and low-K lavas of Sunda Arc indicates that Barren Island must have evolved from a source similar to that of Sunda Arc lavas during the Quaternary Period.

  1. Monitoring dyke injection and strain field evolution using shear-wave splitting.

    Kendall, J.-M.; Verdon, J. P.; Keir, D.; Baird, A.


    Magma storage and dyke injection in the shallow crust is a fundamental process in rifting and volcanic environments. The dyking will tend to align with directions of maximum compressive stress, and the associated aligned fracturing and melt migration provides a very effective means of generating seismic anisotropy. Observations of shear-wave splitting provide one of the most unambiguous indicators of such anisotropy. As such, shear-wave splitting can be used to monitor the evolving strain field in volcanic and rifting environments. Here we apply lessons learned from monitoring fracture propagation during the hydraulic stimulation of tight-gas reservoirs. In a number of experiments we observe spatial and temporal variations in shear-wave splitting magnitude and orientation. We invert shear-wave observations for fracture properties, including the tangential and normal compliance, the ratio of which is a good indicator of fluid flow and permeability. Frequency dependent affects can be also used to indicate the length scales of the causative cracks or fractures. We apply these insights to microseismic data recently acquired across the volcanically active Afar triple junction in Ethiopia. The pattern of S-wave splitting in Afar is best explained by anisotropy from deformation-related structures, with the dramatic change in splitting parameters into the rift axis from the increased density of dyke-induced faulting combined with a contribution from oriented melt pockets near volcanic centres. The results help in our understanding of the role of melt in strain accommodation in rifting and volcanic environments.

  2. Understanding and using technological affordances: a commentary on Conole and Dyke

    Tom Boyle


    Full Text Available The paper by Conole and Dyke sets the context by pointing to a number of problems that inhibit the widespread, effective use of Information and Communication Technologies (ICT to support learning. They argue that this situation highlights the need to explore a theoretical basis for the use of ICT to support learning. The central argument of the paper is that the notion of affordances can make a significant contribution to this endeavour. The paper aims to articulate the potential impact of these affordances primarily through the development of a taxonomy. It draws on social constructivist theory to help understand and articulate the impact of these affordances. The concept of affordances is potentially both rich and provocative. Conole and Dyke provide a refreshing and diverse look at the theoretical basis for the use of ICT to support learning. We have structured our commentary around six questions that are provided by Conole and Dyke in their Discussion section. Whilst examining these questions we highlight various issues raised by the paper, which we believe, need further consideration and clarification.

  3. Carbonatitic metasomatism in orogenic dunites from Lijiatun in the Sulu UHP terrane, eastern China

    Su, Bin; Chen, Yi; Guo, Shun; Chu, Zhu-Yin; Liu, Jing-Bo; Gao, Yi-Jie


    Among orogenic peridotites, dunites suffer the weakest crustal metasomatism at the slab-mantle interface and are the best lithology to trace the origins of orogenic peridotites and their initial geodynamic processes. Petrological and geochemical investigations of the Lijiatun dunites from the Sulu ultrahigh-pressure (UHP) terrane indicate a complex petrogenetic history involving melt extraction and multistage metasomatism (carbonatitic melt and slab-derived fluid). The Lijiatun dunites consist mainly of olivine (Fo = 92.0-92.6, Ca = 42-115 ppm), porphyroblastic orthopyroxene (En = 91.8-92.8), Cr-spinel (Cr# = 50.4-73.0, TiO2 continental subduction channel. These dunites then suffered weak metasomatism by slab-derived fluids, forming pargasitic amphibole after pyroxene. This work indicates that modification of the SCLM beneath the eastern margin of the NCC had already taken place before the Triassic continental subduction. Orogenic peridotites derived from such a lithospheric mantle wedge may be heterogeneously modified prior to their incorporation into the subduction channel, which would set up a barrier for investigation of the mass transfer from the subducted crust to the mantle wedge through orogenic peridotites.

  4. The campsite dykes: A window into the early post-solidification history of the Skaergaard Intrusion, East Greenland

    Holness, Marian B.; Richardson, Chris; Andersen, Jens C. Ø.


    The Skaergaard Intrusion of East Greenland is cut by several generations of dykes, the earliest of which is thought to have intruded shortly after solidification of the Skaergaard. Two ~ 6 m wide doleritic dykes from the earliest generation are exposed in the campsite area near Homestead Bay of the Skaergaard Peninsula. One of the dykes (the Campsite Dyke) locally contains abundant xenoliths of troctolitic cumulate. The other (the Plagioclase-phyric Dyke) contains abundant large plagioclase phenocrysts. Cross-cutting relationships between the two dykes are not exposed. The median clinopyroxene-plagioclase-plagioclase dihedral angle, Θcpp, in the Campsite Dyke is 88-89.5°, whereas that of the Plagioclase-phyric Dyke is 79°. Using an empirical relationship between Θcpp and the duration of crystallisation derived from dolerite sills, the observed Θcpp suggests that the Campsite Dyke is the older of the two, intruding the Skaergaard when it had cooled to 920-970 °C. The Plagioclase-phyric Dyke intruded later, once the Skaergaard had cooled below 670 °C. The troctolitic xenoliths divide into two separate groups. Type A xenoliths have microstructures similar to those of the Skaergaard Layered Series although mineral compositions are generally more primitive than those of the exposed cumulates - this type of xenolith is likely to have been derived from either deeper levels in the Skaergaard Intrusion or from a closely-related underlying magma chamber. One Type A xenolith has mineral compositions and Θcpp consistent with an origin in LZb of the Layered Series - this xenolith contains partially inverted pigeonite, suggesting that inversion of low-Ca pyroxene in the lower part of the Layered Series took place after the intrusion had completely solidified. Type B xenoliths are characterized by plagioclase containing large and abundant melt inclusions. Comparison with the microstructures of glassy crystalline nodules from Iceland points to a multi-stage cooling history

  5. Paleomagnetism of the Velez Rubio Dykes: Implications for transport directions in a collapsing orogen (Betic Cordillera, southern Spain)

    Platzman, E. S.; Platt, J. P.


    Palaeomagnetic and structural analysis of a suite of altered Neogene mafic dykes intruded into the Alpujarride allochthon in the Internal Zone of the Betic Cordillera demonstrate that between 32-62° clockwise vertical-axis rotation occurred after the major extensional event on the adjacent Malaguide Alpujarride. Anisotropy of magnetic susceptibility (AMS) measurements show that the dykes are virtually free of a penetrative magnetic fabric associated with this deformational event. Results of demagnetization experiments show that the remanence in many of the dykes is composed of one to three components. The lowest temperature component is usually in the direction of the present earth's magnetic field and is interpreted as a viscous overprint. The intermediate temperature component is carried by pyrrhotite and frequently has a direction identical to the high temperature remanence fraction. The high temperature component, which demagnetizes at the curie point of magnetite (575 °C), has an average declination of 242° and an inclination of -19°. Lack of a well-defined magnetic fabric coupled with a shallow inclination suggests that these dykes have rotated about a horizontal as well as a vertical axis. Rotation of approximately 57° about a horizontal NNE-trending axis, normal to the dykes, brings the inclination into statistical agreement with the expected inclination for the Oligocene. This rotation leaves the dykes in a near-vertical orientation, decreases the declination anomaly to 32° and brings the foliation in the surrounding schists approximately horizontal. We suggest that the regional foliation may have been sub-horizontal at the time of dyke emplacement, probably as a result of the phase of late-orogenic extension. The regional stretching lineation and hence transport direction associated with the extensional event was originally oriented NNE. sub-parallel to the finite extension directions obtained further to the west implying a large component of radial

  6. Dyke-sill relationships in Karoo dolerites as indicators of propagation and emplacement processes of mafic magmas in the shallow crust

    Coetzee, A.; Kisters, A. F. M.


    This paper describes the spatial and temporal relationships between Karoo-age (ca. 180 Ma) dolerite dykes and a regional-scale saucer-sill complex from the Secunda (coal mine) Complex in the northeastern parts of the Karoo Basin of South Africa. Unlike parallel dyke swarms of regional extensional settings, mafic dykes commonly show curved geometries and highly variable orientations, short strike extents and complex cross-cutting and intersecting relationships. Importantly, the dyke networks originate from the upper contacts of the first-order dolerite sill-saucer structure and are not the feeders of the saucer complex. Cross-cutting relationships indicate the largely contemporaneous formation of dykes and the inner sill and inclined sheets of the underlying saucer. Systematic dykes form a distinct boxwork-type pattern of two high-angle, interconnected dyke sets. The formation and orientation of this dyke set is interpreted to be related to the stretching of roof strata above elongated magma lobes that facilitated the propagation of the inner sill, similar to the ;cracked lid; model described for large saucer complexes in Antarctica. Dyke patterns generally reflect the saucer emplacement process and the associated deformation of wall rocks rather than far-field regional stresses.

  7. The discovery of the Neoarchean mafic dyke swarm in Hengshan and reinterpretation of the previous "Wutai greenstone belt"


    The structural mapping and section study indicate that the "greenstone belts" in the southern to central parts of Hengshan were intensively sheared and transposed mafic dyke swarm,which originally intruded into the Neoarchean grey gneiss and high-pressure granulite terrain(HPGT).The HPGT is characterized by flat-dipping structures,to the south it became steep and was cut by the Dianmen mafic dyke swarm.After high-pressure granulite-facies metamorphic event,the mafic dyke swarm occurred,and was associated with the extensional setting and reworked by the late strike-slip shearing.The zircon age dating proves that the Dianmen mafic dyke swarm was emplaced during the period between 2499±4 Ma and 2512±3 Ma,followed by late tectonothermal reworking.The Dianmen mafic dyke swarm further documents the extensional episode in the central to northern parts of North China Craton(NCC),providing the important constraint for the limit between Archean and Proterozoic and correlation between NCC and other cratonic blocks of the world.

  8. The discovery of the Neoarchean mafic dyke swarm in Hengshan and reinterpretation of the previous “Wutai greenstone belt”

    李江海; 张志强; 黄雄南


    The structural mapping and section study indicate thai the "greenstone belts" in the southern to central parts of Hengshan were intensively sheared and transposed mafic dyke swarm, which originally intruded into the Neoarchean grey gneiss and nigh-pressure granulite terrain (HPGT). The HPGT is characterized by flat-dipping structures, to the south it became steep and was cut by the Dianmen mafic dyke swarm. After high-pressure; granulite-facies metamorphic event, the mafic dyke swarm occurred, and was associated with the extensional setting and reworked by the late strike-slip shearing. The zircon age dating proves that the Dianmen mafic dyke swarm was emplaced during the period between 2499±4 Ma and 2512±3 Ma, followed by late tectonothermal reworking. The Dianmen mafic dyke swarm further documents the extensional episode in the central to northern parts of North China Craton (NCC), providing the important constraint for the limit between Archean and Proterozoic and correlation between NCC and other e

  9. Fault and dyke detectability in high resolution seismic surveys for coal: a view from numerical modelling*

    Zhou, Binzhong 13Hatherly, Peter


    Modern underground coal mining requires certainty about geological faults, dykes and other structural features. Faults with throws of even just a few metres can create safety issues and lead to costly delays in mine production. In this paper, we use numerical modelling in an ideal, noise-free environment with homogeneous layering to investigate the detectability of small faults by seismic reflection surveying. If the layering is horizontal, faults with throws of 1/8 of the wavelength should be detectable in a 2D survey. In a coal mining setting where the seismic velocity of the overburden ranges from 3000 m/s to 4000 m/s and the dominant seismic frequency is ~100 Hz, this corresponds to a fault with a throw of 4-5 m. However, if the layers are dipping or folded, the faults may be more difficult to detect, especially when their throws oppose the trend of the background structure. In the case of 3D seismic surveying we suggest that faults with throws as small as 1/16 of wavelength (2-2.5 m) can be detectable because of the benefits offered by computer-aided horizon identification and the improved spatial coherence in 3D seismic surveys. With dykes, we find that Berkhout's definition of the Fresnel zone is more consistent with actual experience. At a depth of 500 m, which is typically encountered in coal mining, and a 100 Hz dominant seismic frequency, dykes less than 8 m in width are undetectable, even after migration.

  10. Origin of carbonatites in the South Qinling orogen: Implications for crustal recycling and timing of collision between the South and North China Blocks

    Xu, Cheng; Chakhmouradian, Anton R.; Taylor, Rex N.; Kynicky, Jindrich; Li, Wenbo; Song, Wenlei; Fletcher, Ian R.


    Most studies of compositional heterogeneities in the mantle, related to recycling of crustal sediments or delaminated subcontinental lithosphere, come from oceanic setting basalts. In this work, we present direct geochronological and geochemical evidence for the incorporation of recycled crustal materials in collision-related carbonatites of the South Qinling orogenic belt (SQ), which merges with the Lesser Qinling orogen (LQ) to separate the South and North China Blocks. The SQ carbonatites occur mainly as stock associated with syenites. The data presented here show that zircon from the syenites yields an age of 766 ± 25 Ma, which differs significantly from the age of primary monazite from the carbonatites (233.6 ± 1.7 Ma). The syenites contain lower initial 87Sr/86Sr and higher εNd values. This indicates that the carbonatites do not have genetically related with the silicate rocks, and were directly derived from a primary carbonate magma generated in the mantle. The carbonatites show a Sr-Nd isotopic signature similar to that of the chondritic uniform reservoir (CHUR), and parallel Sm-Nd model ages (TCHUR) of 190-300 Ma. However, the rocks have extremely variable Pb isotopic values straddling between the HIMU and EM1 mantle end-members. Most carbon and oxygen isotopic compositions of the SQ carbonatites plot outside the field for primary igneous carbonates. Their δ13C shows higher value than a 'normal' mantle, which implies an incorporation of recycled inorganic carbon. The carbonatites were emplaced close to the Mianlue suture, and followed the closure of the Mianlue ocean and Triassic collision of the South and North China Blocks. However, direct melting of the subducted Mianlue oceanic crust characterized by high εNd and low (EM1-like) 206Pb/204Pb values cannot explain the CHUR-like Nd signature and the Pb isotopic trend toward HIMU in the SQ carbonatites. We conclude that their parental magma was derived from a source incorporating the Mianlue oceanic

  11. New U-Pb ages from dykes cross-cutting the Demirci metamorphics, NW Turkey: Implications for multiple orogenic events

    Sen, Fatih; Koral, Hayrettin; Peytcheva, Irena


    A high-grade metamorphic sequence in the Sünnice Mountains, Bolu, NW Turkey, is represented by migmatitic quartzo-feldspathic gneisses in amphibolite facies called the Demirci metamorphics/paragneisses, and a sequence of low-grade meta-volcanics containing meta-andesites with minor meta-rhyolites and meta-sedimentary rocks called the Yellice meta-volcanics. They are intruded by the Dirgine granite with an age of Upper Ediacaran (576-565 Ma) and are considered a part of the İstanbul-Zonguldak Tectonic Unit. The Demirci paragneisses are also intruded by a number of dykes in various directions, traditionally considered without radiometric dating to have been emplaced in a single magmatic phase in the Eocene related to post-collision regime of the Anatolide-Tauride platform. Mafic-intermediate-felsic dykes cross-cutting the Demirci paragneisses have been investigated in maps of 1/1000 scale, and their U-Pb zircon age, major-trace element and kinematic data have been obtained. The mafics dykes cross-cutting the Yellice meta-volcanics, equivalents of those in the Demirci paragneisses, occur in N400-500E orientations and have calc-alkaline basalt compositions with a subduction signature. The intermediate dykes occur in N650W, N800W orientations and have calc-alkaline basaltic andesite to andesitic compositions with a subduction signature. Some felsics occur in N150W and N800E orientations and have calc-alkaline dacitic compositions with a collisional tectonic setting. Other calc-alkaline granitic dykes occur in N750E orientation and calc-alkaline granitic compositions with a subduction signature. U-Pb LA-ICP-MS dating of zircons yield ages from 485.7±3.6 Ma (i.e. Cambro-Ordovician) for N800E trending dacite dykes; 443.0±5.4 Ma (i.e. Ordovician-Silurian) for N150W trending dacite dykes; 301.0±1.6 Ma (i.e. Upper Pennsylvanian-Carboniferous) for N650W trending basaltic andesite dykes; 268.2±2.4 Ma (i.e. Guadalupian-Permian) for N40-500E trending basalt dykes; 262.9±3

  12. Sedimentary Facies Models on Carbonatite in the Upper Shuaiba Member of Lower Cretaceous in Daleel Field, Oman

    Wang Feng; Jiang Zaixing; Zhou Liqing; Zhao Guoliang; Wang Lin; Zheng Ning; Xiang Shu'an


    The Upper Shuaiba Member (USH) is the main force pay bed in the Daleel field in northern Oman; 5 layers including A, B, C, D, and E were divided in profile, and layer D and layer E are the main beds. With the development of exploration in the Daieel oil field, studying the sedimentary systems about their inner composition and the collocation in dimension, and setting up the sedimentary models in the USH are becoming more and more necessary and important to meet the further exploration requirement. Based on the data of geology, seism, and paleo-biology, according to the analysis method on carbonatite depositional system, the litho-facies assemblage and sedimentary environment in the USH were studied. Intershoal low-lying sub-facies (where the water depth is 10-50 m) and shallow shoal sub-facies (where the water depth is not more than 10 m) were extinguished in the layer D, and storm deposit was found in layer E1, in which intershoal low-lying sub-facies also developed. The feature of the sedimentary sub-facies and the sedimentary condition were analyzed, and the sedimentary model was set up in the article: the carbonatite intershoal low-lying developed under the background of open land in shallow sea, where storm events usually occurred in the Lower Cretaceous in the area.

  13. EMI – young HIMU rock association at the Cape Verde Islands revisited: on the role of oceanic carbonatites

    Holm, Paul Martin; Kokfelt, Thomas Find; Dyhr, Charlotte Thorup

    .7031. Incompatible trace element ratios such as Ba/Nb, Ba/La, Th/Rb, La/Nb, La/Th of Fogo-EM1 are comparable to other EM1-type OIB, whereas SA young HIMU-rocks overlap with classical HIMU. The SN end-member has Ba/Nb=6-9, Ba/La=8-14, and La/Th=9-11 in the range of EM1 and HIMU, but has relatively lower Rb than even...... HIMU. Carbonatites are widespread throughout Cape Verde Islands but volumetrically minor and are low in Ti, K, and Rb. In several silicate rocks from all three islands low Ti/Eu is evidence for a carbonatite component and is accompanied by LREE enrichment, and relatively low K and Rb. Other rocks have...... and the rocks have mantle Ti/Eu. There is a strong correlation of Rb/La and Rb/Sr demonstrating that fluids are unlikely agents to explan this variation. Phlogopite control is also excluded due to decoupling of Rb and K from Ba. A possible explanation for the low K and Rb is dehydration of the mantle source...

  14. Geochemical characteristics of Mesoproterozoic metabasite dykes from the Chhotanagpur Gneissic Terrain, eastern India: Implications for their emplacement in a plate margin tectonic environment

    Rajesh K Srivastava; Anup K Sinha; Suresh Kumar


    A number of mafic intrusive bodies (mostly dykes) are exposed in the Chhotanagpur Gneissic Terrain (CGT). Most dykes trend in ENE–WSW to E–W following major structural trends of the region. These metabasite dykes show granoblastic to grano-nematoblastic textures and contain hornblende, plagioclase, chlorite, quartz and epidote which suggest their metamorphism under amphibolite grade P–T conditions. Although no radiometric age is available for the metabasite dykes, field relationships with host rock and available geochronology on granitoids suggest their emplacement during Mesoproterozoic. Geochemical characteristics of these dykes classify them as low-K tholeiite to medium-K calcalkaline type. At least two types of metabasite dykes are recognized on the basis of their HFSE contents; one group shows entirely calc-alkaline nature, whereas the other group has rocks of tholeiite-calc-alkaline series. High Mg#observed in a number of samples indicates their derivation from primary melt. Multielement spidergrams and rare-earth element patterns observed in these samples also corroborate their derivation from different magma batches. Trace element patterns observed for Nb–Ta, Hf–Zr, Sr and Y suggesting involvement of subduction related processes in the genesis of CGT metabasite dykes. Perceived geochemical characteristics suggest that metamorphism did not affect much on the chemistry of metabasites but source region, responsible for the generation of CGT metabasites, was possibly modified during subduction process. This study suggests that magma generated in a destructive plate setting fed the Mesoproterozoic mafic dykes of the CGT.

  15. Evidence for the Multi-Stage Petrogenetic History of the Oka Carbonatite Complex (Québec, Canada as Recorded by Perovskite and Apatite

    Wei Chen


    Full Text Available The Oka complex is amongst the youngest carbonatite occurrences in North America and is associated with the Monteregian Igneous Province (MIP; Québec, Canada. The complex consists of both carbonatite and undersaturated silicate rocks (e.g., ijolite, alnöite, and their relative emplacement history is uncertain. The aim of this study is to decipher the petrogenetic history of Oka via the compositional, isotopic and geochronological investigation of accessory minerals, perovskite and apatite, using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS. The new compositional data for individual perovskite and apatite grains from both carbonatite and associated alkaline silicate rocks are highly variable and indicative of open system behavior. In situ Sr and Nd isotopic compositions for these two minerals are also variable and support the involvement of several mantle sources. U-Pb ages for both perovskite and apatite define a bimodal distribution, and range between 113 and 135 Ma, which overlaps the range of ages reported previously for Oka and the entire MIP. The overall distribution of ages indicates that alnöite was intruded first, followed by okaite and carbonatite, whereas ijolite defines a bimodal emplacement history. The combined chemical, isotopic, and geochronological data is best explained by invoking the periodic generation of small volume, partial melts generated from heterogeneous mantle.

  16. Pesticides in soil and sediment of a dyke-protected area of the Red River Delta, Vietnam

    Braun, Gianna; Bläsing, Melanie; Kruse, Jens; Amelung, Wulf; Renaud, Fabrice; Sebesvari, Zita


    Coastal regions are densely populated but at the same time represent important agricultural areas for food production of the growing world population. To sustain high agricultural yields, in monocultures such as permanent rice systems, pesticides are used in high quantity and frequency. While earlier studies monitored the fate of pesticides in paddy rice systems, the overall fate of these compounds is altered nowadays due to the construction of dykes, which are needed in many delta regions to protect them from high tides, storm surges and salt water intrusion such as in the Red River Delta. The dyke system regulates the discharge and water exchange inside the diked area including irrigation channels for the paddy rice production. Local authorities observed increasing pollution towards the sea (highest pollution close to the dykes) and hypothesized that the dyke system would prevent water exchange and thus lead to an accumulation of pollutants within the diked area. Hence, the purpose of this study was to investigate the effect of dykes on pesticide pollution patterns in coastal delta regions of the Red River Delta. The study was conducted in the district Giao Thuy of the Red River Delta, Vietnam. This area is surrounded by a sea and river dyke; both have several inlet and outlet gates to control the water level in the irrigation channels. We determined the pesticide pollution pattern in a diked agricultural area, as well as along salinity gradients in and outside the diked areas. Samples were taken from rice fields and sediments from irrigation channels inside the diked area as well from saline aquaculture fields located outside the dyke. Pesticide analysis was conducted by accelerated solvent extraction (ASE), followed up by the clean-up process described by Laabs et al. (2007) and analyses using gas chromatography coupled with a mass selective detector (MSD). Preliminary results suggest that out of the 26 analysed compounds chlorpyrifos, propiconazole and

  17. Palaeomagnetism and geochronology of the Proterozoic dolerite dyke from southwest Greenland: indication of low palaeointensity*

    Miki, Masako; Taniguchi, Aya; Yokoyama, Masahiko; Gouzu, Chitaro; Hyodo, Hironobu; Uno, Koji; Zaman, Haider; Otofuji, Yo-ichiro


    Intensity of the geomagnetic field during the Archaean can potentially be used to study an evolution of the dynamo activity in the Earth's core. In order to investigate this issue, we present new palaeomagnetic and geochronological results from the dolerite dyke, which have been intruded into the Archaean Gneisses of Nuuk area, southwest Greenland. 40Ar/39Ar dating of the pyroxene grains from dolerite yield an age of 2585 +/- 21 Ma. The high temperature component, which has been recognized as a characteristic direction, is identified in 24 dolerite samples. Comparison of the palaeomagnetic directions from dolerite dykes with those from host gneisses suggests a primary origin for this component. Magnetic mineralogical and grain size investigations revealed a pseudo-single domain magnetite as a dominant career of magnetization. Thellier palaeointensity determinations of 14 dolerite specimens yield a mean field value of 13.9 +/- 2.5 μT. Strength of the virtual dipole moment (2.30 +/- 0.42 × 1022 Am2) obtained from this study is about one quarter of the present Earth's filed value. A simulation based numerical model of the Thellier experiments suggests that the presence of multidomain grains can play a role in enhancing the strength of palaeointensity. Even after taking in to account the effects of multidomain grains, an intensity value (13.9 μT) from this study suggests that the strength of geomagnetic field at about 2.6 Ga was much lower than that of the present time.

  18. Broad accommodation of rift-related extension recorded by dyke intrusion in Saudi Arabia

    Pallister, John S.


    The extensive harrat lava province of Arabia formed during the past 30 million years in response to Red Sea rifting and mantle upwelling. The area was regarded as seismically quiet, but between April and June 2009 a swarm of more than 30,000 earthquakes struck one of the lava fields in the province, Harrat Lunayyir, northwest Saudi Arabia. Concerned that larger damaging earthquakes might occur, the Saudi Arabian government evacuated 40,000 people from the region. Here we use geologic, geodetic and seismic data to show that the earthquake swarm resulted from magmatic dyke intrusion. We document a surface fault rupture that is 8 km long with 91 cm of offset. Surface deformation is best modelled by the shallow intrusion of a north-west trending dyke that is about 10 km long. Seismic waves generated during the earthquakes exhibit overlapping very low- and high-frequency components. We interpret the low frequencies to represent intrusion of magma and the high frequencies to represent fracturing of the crystalline basement rocks. Rather than extension being accommodated entirely by the central Red Sea rift axis, we suggest that the broad deformation observed in Harrat Lunayyir indicates that rift margins can remain as active sites of extension throughout rifting. Our analyses allowed us to forecast the likelihood of a future eruption or large earthquake in the region and informed the decisions made by the Saudi Arabian government to return the evacuees. © 2010 Macmillan Publishers Limited. All rights reserved.

  19. Broad accommodation of rift-related extension recorded by dyke intrusion in Saudi Arabia

    Pallister, J.S.; McCausland, W.A.; Jonsson, Sigurjon; Lu, Zhiming; Zahran, H.M.; El, Hadidy S.; Aburukbah, A.; Stewart, I.C.F.; Lundgren, P.R.; White, R.A.; Moufti, M.R.H.


    The extensive harrat lava province of Arabia formed during the past 30 million years in response to Red Sea rifting and mantle upwelling. The area was regarded as seismically quiet, but between April and June 2009 a swarm of more than 30,000 earthquakes struck one of the lava fields in the province, Harrat Lunayyir, northwest Saudi Arabia. Concerned that larger damaging earthquakes might occur, the Saudi Arabian government evacuated 40,000 people from the region. Here we use geologic, geodetic and seismic data to show that the earthquake swarm resulted from magmatic dyke intrusion. We document a surface fault rupture that is 8 km long with 91 cm of offset. Surface deformation is best modelled by the shallow intrusion of a north-west trending dyke that is about 10 km long. Seismic waves generated during the earthquakes exhibit overlapping very low- and high-frequency components. We interpret the low frequencies to represent intrusion of magma and the high frequencies to represent fracturing of the crystalline basement rocks. Rather than extension being accommodated entirely by the central Red Sea rift axis, we suggest that the broad deformation observed in Harrat Lunayyir indicates that rift margins can remain as active sites of extension throughout rifting. Our analyses allowed us to forecast the likelihood of a future eruption or large earthquake in the region and informed the decisions made by the Saudi Arabian government to return the evacuees.

  20. Broad accommodation of rift-related extension recorded by dyke intrusion in Saudi Arabia

    Pallister, John S.; McCausland, Wendy A.; Jónsson, Sigurjón; Lu, Zhong; Zahran, Hani M.; Hadidy, Salah El; Aburukbah, Abdallah; Stewart, Ian C. F.; Lundgren, Paul R.; White, Randal A.; Moufti, Mohammed R. H.


    The extensive harrat lava province of Arabia formed during the past 30 million years in response to Red Sea rifting and mantle upwelling. The area was regarded as seismically quiet, but between April and June 2009 a swarm of more than 30,000 earthquakes struck one of the lava fields in the province, Harrat Lunayyir, northwest Saudi Arabia. Concerned that larger damaging earthquakes might occur, the Saudi Arabian government evacuated 40,000 people from the region. Here we use geologic, geodetic and seismic data to show that the earthquake swarm resulted from magmatic dyke intrusion. We document a surface fault rupture that is 8km long with 91cm of offset. Surface deformation is best modelled by the shallow intrusion of a north-west trending dyke that is about 10km long. Seismic waves generated during the earthquakes exhibit overlapping very low- and high-frequency components. We interpret the low frequencies to represent intrusion of magma and the high frequencies to represent fracturing of the crystalline basement rocks. Rather than extension being accommodated entirely by the central Red Sea rift axis, we suggest that the broad deformation observed in Harrat Lunayyir indicates that rift margins can remain as active sites of extension throughout rifting. Our analyses allowed us to forecast the likelihood of a future eruption or large earthquake in the region and informed the decisions made by the Saudi Arabian government to return the evacuees.

  1. Palaeointensity and palaeodirection determinations of Paleoproterozoic dykes in the Kaapvaal Craton (South Africa)

    Shcherbakova, V. V.; Lubnina, N. V.; Shcherbakov, V. P.; Zhidkov, G. V.


    A combined palaeodirectional and palaeointensity study of a representative collection from the Bushveld Igneous Complex from 27 dolerite dykes from the 2.9, 2.7, and 1.8 Ga age swarms radiating SE, E and NE, respectively [Olsson et al., 2010] was carried out. Conventional progressive thermal or AF demagnetization was applied to all specimens. The palaeomagnetic directions have been calculated after thermal demagnetization. The ChRMs were isolated over the temperature interval 440-590 C and their intensities amount to 95% of total NRMs. Paleopole calculate from the primary high-temperature component, separated in the 2.9 Ga SE-dykes, is close to the paleopoles, obtained by Wingate (1998) and Strik et al. (2007) for 2.78 Ga volcanics. The paleopole calculated for the 2.7 Ga age E-trending dykes of the eastern region does not correspond to any of the previously obtained Archean-Paleoproterozoic paleopoles for the Kaapvaal Craton. The paleopole calculated for some NE-trending dykes of the Black Ridge swarm in the NE region is close to the 1.87 Ga pole of the Kaapvaal Craton obtained by Hanson et al. (2004). Palaeointensity determinations were carried out on rocks from ten dykes of different ages using Thellier-Coe method with the "check-points" procedure on specimens of 1 cm in edge length cut from either drilled cores or hand samples. Rock magnetic measurements were made on sister specimens. Curie temperatures and the thermal stability of magnetic minerals were estimated from thermomagnetic heating-cooling cycles to incrementally higher temperatures Ti with a Curie balance in an external magnetic field H = 0.45 T. To assess the magnetic hardness and mineralogy of samples, measurements of magnetic susceptibility and hysteresis loop parameters were performed. The domain structure (DS) was estimated also from the thermomagnetic criterion by evaluating the tails of pTRMs. Wilson's method of palaeointensity determination based on comparison of thermodemagnetization curves

  2. Precambrian crustal evolution and Cretaceous–Palaeogene faulting in West Greenland: Origin and evolution of the Kangâmiut mafic dyke swarm, West Greenland

    Lesher, Charkes E.


    Full Text Available The Kangâmiut dyke swarm in West Greenland intruded Archaean terrains at 2.04 Ga, and its northern portion was subsequently metamorphosed to granulite facies during the Nagssugtoqidian orogeny(c. 1.8 Ga. Mineral and whole-rock major and trace element compositions show that the parental magmas for the dyke swarm differentiated by the fractionation of olivine, clinopyroxene, plagioclase and late stage Fe-Ti oxides. Petrographical observations and the enrichment of K2O during differentiation argue that hornblende was not an important fractionating phase. Field observations suggest emplacement at crustal levels above the brittle–ductile transition, and clinopyroxene geothermobarometry constrains dyke emplacement depths to less than 10 km. Granulite facies metamorphism of the Kangâmiut dykes and their host rocks in the northern portion of the swarm requires subsequent burial to c. 30 km, related to roughly 20 km of crustal thickening between the time of dyke emplacement and peak metamorphism during the Nagssugtoqidian orogeny. Kangâmiut dykes are characterised by low Ba/La ratios (12 ±5, and high Nb/La ratios (0.8 ±0.2, compared to subduction relatedbasalts (Ba/La c. 25; Nb/La c. 0.35. These geochemical characteristics argue that the Kangâmiut dykes are not related to subduction processes. Forward modelling of rare-earth element data requires that primitive magmas for the Kangâmiut dykes originated from a moderately depleted mantle source with a mantle potential temperature of c. 1420°C. The inferred potential temperature is consistent with potential temperature estimates for ambient mantle at 2.0 Ga derived from secular cooling models and continental freeboard constraints. The geochemistry and petrology of the Kangâmiut dykes support a model that relates the dyke activity to passive rifting of the proposed Kenorland supercontinent rather than to mantle plume activity or subduction.

  3. Ordovician and Triassic mafic dykes in the Wudang terrane: Evidence for opening and closure of the South Qinling ocean basin, central China

    Nie, Hu; Wan, Xin; Zhang, He; He, Jian-Feng; Hou, Zhen-Hui; Siebel, Wolfgang; Chen, Fukun


    We report zircon ages and geochemical composition for mafic dykes that intruded Neoproterozoic volcanic-sedimentary sequences in the southern part of Wudang area, South Qinling. The results indicate that the dykes were emplaced during the Early Paleozoic (c. 460 Ma) and Early Mesozoic (c. 220 Ma). The dykes share similar major element composition, but have distinctive trace element pattern and Sr-Nd-Pb isotope distribution. Early Paleozoic mafic dykes are characterized by enrichment in LREEs, LILEs and HFSEs and EM II-type isotopic features. These geochemical features suggest derivation from an OIB-type mantle source that had undergone metasomatism during earlier subduction events. The Early Mesozoic mafic dykes can be subdivided into two distinct geochemical groups. Dykes of Group 1 are depleted in LREEs, LILEs and HFSEs and show depleted isotope compositions, indicating an origin by partial melting of asthenospheric mantle material. Dykes of Group 2 have high Rb-, Ba-, and K-contents and EM I-type isotopic features, suggesting input of lower crustal material to the magma source during Mesozoic subduction. We propose that the Early Paleozoic dykes are related to the opening of an oceanic basin separating South Qinling from the Yangtze Block, while the Early Mesozoic dykes were derived from partial melting of up-welling asthenosphere during the final amalgamation of these two blocks in the Early Mesozoic. A slab break-off model could explain not only the petrogenesis of the Mesozoic mafic dykes, but also the distinct geological features between the Dabie-Sulu and South Qinling orogens. We propose that slab break-off occurred at great depth in the Dabie-Sulu orogen and hence rare magmatism occurred. Whereas in South Qinling the break-off occurred at a shallow depth, the asthenospheric mantle material could rise further up into the overlying mantle where it experienced decompression and melting. As a consequence, crustal sections were heated up to produce extensive

  4. Creep of mafic dykes infiltrated by melt in the lower continental crust (Seiland Igneous Province, Norway)

    Degli Alessandrini, G.; Menegon, L.; Malaspina, N.; Dijkstra, A. H.; Anderson, M. W.


    A dry mafic dyke from a continental lower-crustal shear zone in the Seiland Igneous Province (northern Norway) experienced syn-kinematic melt-rock interaction. Viscous shearing occurred at T ≈ 800 °C, P ≈ 0.75-0.95 GPa and was coeval with infiltration of felsic melt from adjacent migmatitic metapelites. The dyke has a mylonitic microstructure where porphyroclasts of orthopyroxene, clinopyroxene and plagioclase are wrapped by a fine-grained (4-7 μm) polyphase mixture of clinopyroxene + orthopyroxene + plagioclase + quartz + ilmenite ± K-feldspar ± apatite. Microstructural observations and electron backscatter diffraction analysis indicate that the porphyroclasts deformed by a combination of dislocation glide and fracturing, with only a limited record of dislocation creep, recovery and dynamic recrystallization. We identified diffusion creep as the dominant deformation mechanism in the mixture based on the small grain size, phase mixing and weak crystallographic preferred orientation of all phases (interpreted as the result of oriented grain growth during viscous flow). The polyphase mixture did not form by dynamic recrystallization or by mechanical fragmentation of the porphyroclasts, but rather by melt-rock interaction. Thermodynamic models indicate that the syn-kinematic mineral assemblage results from the chemical interaction between a pristine mafic dyke and ca. 10 vol.% of felsic melt infiltrating from the adjacent partially molten metapelites. Extrapolation of laboratory-derived flow laws to natural conditions indicates that the formation of interconnected layers of fine-grained reaction products deforming by diffusion creep induces a dramatic weakening in the mafic granulites, with strain rates increasing up to 2-3 orders of magnitude. The reaction weakening effect is more efficient than the weakening associated with melt-assisted diffusion creep in the presence of up to 10 vol.% of infiltrated melt without formation of fine-grained reaction products

  5. Parental magma of the Skaergaard intrusion: constraints from melt inclusions in primitive troctolite blocks and FG-1 dykes

    Jakobsen, Jakob K.; Tegner, Christian; Brooks, C. Kent; Kent, Adam J. R.; Lesher, Charles E.; Nielsen, Troels F. D.; Wiedenbeck, Michael


    Troctolite blocks with compositions akin to the Hidden Zone are exposed in a tholeiitic dyke cutting across the Skaergaard intrusion, East Greenland. Plagioclase in these blocks contains finely crystallised melt inclusions that we have homogenised to constrain the parental magma to 47.4-49.0 wt.% SiO2, 13.4-14.9 wt.% Al2O3 and 10.7-14.1 wt.% FeOT. These compositions are lower in FeOT and higher in SiO2 than previous estimates and have distinct La/SmN and Dy/YbN ratios that link them to the lowermost volcanic succession (Milne Land Formation) of the regional East Greenland flood basalt province. New major- and trace element compositions for the FG-1 dyke swarm, previously taken to represent Skaergaard magmas, overlap with the entire range of the regional flood basalt succession and do not form a coherent suite of Skaergaard like melts. These dykes are therefore re-interpreted as feeder dykes throughout the main phase of flood basalt volcanism.

  6. Dyke-Davidoff-Masson syndrome: case report of fetal unilateral ventriculomegaly and hypoplastic left middle cerebral artery

    Piro, E.; Piccione, M.; Marrone, G; M. Giuffrè; Corsello, G


    Prenatal ultrasonographic detection of unilateral cerebral ventriculomegaly arises suspicion of pathological condition related to cerebrospinal fluid flow obstruction or cerebral parenchimal pathology. Dyke-Davidoff-Masson syndrome is a rare condition characterized by cerebral hemiatrophy, calvarial thickening, skull and facial asymmetry, contralateral hemiparesis, cognitive impairment and seizures. Congenital and acquired types are recognized and have been described, mainly in late childhood...

  7. Parental magma of the Skaergaard intrusion: constraints from melt inclusions in primitive troctolite blocks and FG-1 dykes

    Jakobsen, J.K.; Tegner, Christian; Brooks, Kent;


    Abstract Troctolite blocks with compositions akin to the Hidden Zone are exposed in a tholeiitic dyke cutting across the Skaergaard intrusion, East Greenland. Plagioclase in these blocks contains finely crystallised melt inclusions that we have homogenised to constrain the parental magma to 47...

  8. Mafic dyke swarms of the Bastar Craton, central India: geochemistry, Sr-Nd isotopes and tectonic implications

    Liao, Chien-Yi; Shellnutt, J. Gregory; Raghvan Hari, Kosiyathu; Viswakarma, Neeraj


    The Archean Bastar Craton of central India which is demarcated by Godivari rift in the west, Mahanadi rift in the east, Narmada-Son rift in the north and the Eastern Ghats Mobile Belt in the south was intruded by several generations of mafic dyke swarms during the Precambrian, with most of the dykes NW-SE to WNW-ESE trending. The dyke swarms can be subdivided into three main groups: the Meso-Neoarchean sub-alkaline mafic dykes (BD1), Neoarchean to Paleoproterozoic boninite-norite dykes (BN) and Paleoproterozoic sub-alkaline mafic dykes (BD2). In the present work, an attempt has been made to constrain the petrogenesis and tectonic implications of the dykes in the Bhanupratapur area of central Bastar Craton. Petrographically, the dykes are metabasites / metadolerites that experienced hydrothermal alteration, as most of the samples are moderately to highly altered. Primary minerals were replaced but still retain the original igneous texture (ophitic). The least-altered samples contain orthopyroxene, plagioclase, secondary amphibole, secondary quartz and some euhedral Fe-Ti oxides. The dykes can be classified into two groups according to major element data. Petrographically, the two groups cannot be clearly distinguished. Group 1 is sub-alkaline basalt (SiO2 = 51 wt%) with low magnesium (MgO = 4.6 to 7.2 wt%), low Mg-number (Mg# ≤ 53) and higher titanium (TiO2 ≥ 0.83 wt%). Group 2 is sub-alkaline basaltic andesite and has boninitic characteristics with higher silica (SiO2 = 51 to 56 wt%), higher magnesium (MgO = 5.9 to 19.1 wt%), higher Mg-number (Mg# = 50 to 79) and lower titanium (TiO2 ≤ 0.8 wt%). The chondrite-normalized REE patterns of Group 1 show variability in the light rare earth elements (La/SmN = 1.2 to 2.4). Group 2 exhibit light rare earth element enrichment (La/YbN = 2.2 to 10.4). The Sm-Nd isochron age of Group 1 is approximately 1.9 Ga, with the initial 87Sr/86Sr ratios range from 0.7029 to 0.7058 and ɛNd(t) values range from-0.9 to +1.8. Group 1

  9. Dyke-Davidoff-Masson Syndrome. An unusual cause of status epilepticus.

    Zawar, Ifrah; Khan, Ashfa A; Sultan, Tipu; Rathore, Ahsan W


    The Dyke-Davidoff-Masson Syndrome (DDMS) results from an insult to the growing brain in utero or early infancy, which lead to loss of neurons compromising the growth of the brain. Clinical presentation includes seizures, hemiparesis, facial asymmetry, and learning disability. Radiological findings include cerebral atrophy on one side. Here, we present a case with status epilepticus who had underlying DDMS. It is a rare syndrome and uncommon cause for status epilepticus. Infections of CNS, hypoxic ischemic encephalopathy, intracranial bleed, trauma, congenital vascular malformations are the common causes of this syndrome. Diagnosis is established after clinical history, examination, and MRI. Intractable seizures can be controlled with appropriate anticonvulsants. Subsequently, these children may require physiotherapy, speech therapy, and occupational therapy in addition to the anticonvulsant medication. Outcome is better if the seizures are controlled.

  10. Dyke propagation and tensile fracturing at high temperature and pressure, insights from experimental rock mechanics.

    Bakker, Richard; Benson, Philip; Vinciguerra, Sergio


    It is well known that magma ascends trough the crust by the process of dyking. To enable dyke emplacement, basement rocks typically fail in a mode 1 fracture, which acts as conduits for magma transport. An overpressure of the ascending magma will further open/widen the fracture and permit the fracture to propagate. In order to further understand the emplacement and arrest of dykes in the subsurface, analogue and numerical studies have been conducted. However, a number of assumptions regarding rock mechanical behaviour frequently has to be made as such data are very hard to directly measure at the pressure/temperature conditions of interest: high temperatures at relatively shallow depths. Such data are key to simulating the magma intrusion dynamics through the lithologies that underlie the volcanic edifice. Here we present a new laboratory setup, which allows us to investigate the tensile fracturing properties under both temperature and confining pressure, and the emplacement of molten material within the newly formed fracture. We have modified a traditional tri-axial test assembly setup to be able to use a Paterson type High Pressure, High Temperature deformation apparatus. Sample setup consists of cylindrical rock samples with a 22 mm diameter and a 8 mm bore at their centre, filled with a material chosen as such that it's in a liquid state at the experimental temperature and solid at room temperature to enable post-experiment analysis. The top and lower parts of the rock sample are fitted with plugs, sealing in the melt. The assembly is then placed between ceramic pistons to ensure there are no thermal gradients across the sample. The assembly is jacketed to ensure the confining medium (Ar) cannot enter the assembly. A piston is driven into the sample such that the inner conduit materials pressure is slowly increased. At some point a sufficient pressure difference between the inner and outer surfaces causes the sample to deform and fail in the tensile regime

  11. Adult Presentation of Dyke-Davidoff-Masson Syndrome: A Case Report

    Ujjawal Roy


    Full Text Available Dyke-Davidoff-Masson syndrome (DDMS is a rare disease which is clinically characterized by hemiparesis, seizures, facial asymmetry, and mental retardation. The classical radiological findings are cerebral hemiatrophy, calvarial thickening, and hyperpneumatization of the frontal sinuses. This disease is a rare entity, and it mainly presents in childhood. Adult presentation of DDMS is unusual and has been rarely reported in the medical literature. Key Messages: DDMS is a rare disease of childhood. However, it should be kept in mind as a diagnostic possibility in an adult who presents with a long duration of progressive hemiparesis with seizures and mental retardation. Cerebral hemiatrophy, calvarial thickening, and hyperpneumatization of the frontal sinuses are diagnostic for this illness on brain imaging.

  12. Shoshonitic and ultrapotassic post-collisional dykes from northern Karakorum (Sinkiang, China)

    Pognante, Ugo


    High-K calc-alkaline, shoshonitic and ultrapotassic post-collisional dykes of Neogene age have been found in the remote and little known region of northern Karakorum located around the Shaksgam valley, north of the K2-Gasherbrum range (China). The dykes derive from more or less comparable basic magma(s) and display rather unusual petrographic and geochemical characters with respect to the other K-rich rocks. The geochemical data are consistent with derivation of the basic magma(s) from small degrees of partial melting of garnet-lherzolites previously enriched in incompatible elements of crustal origin possibly during the subduction of the Indian plate beneath Karakorum. The spectrum of compositions reflects fractional crystallization governed by an early removal of clinopyroxene, phlogopite, plagioclase, garnet±amphibole followed by the precipitation of abundant alkali feldspar, amphibole±apatite±quartz. Additionally, assimilation of crustal rocks during magma ascent contributed to the unusual compositional characteristics and is suggested by the abundance of corroded quartz ( ± plagioclase) xenocrysts and by the occasional presence of granitic xenoliths. An apparent connection exists between magmatism and tectonism in the complex Karakorum Fault Zone (KFZ). It is suggested that, during the Neogene, the strike-slip KFZ and some adjacent post-metamorphic faults transiently behaved as extensional fault systems down to deep levels, triggering ascent and emplacement of the K-rich magma. The subsequent (re)activation of a compressive and transcurrent regime determined the rapid and recent uplift of the more primitive lamprophyres occurring in the plutonites and metamorphites of the upper Baltoro Glacier and K2-Gasherbrum range, relative to the more fractionated and contaminated lamprophyres injecting the shallower rocks of the Shaksgam valley area.

  13. Geochemistry and petrogenesis of early Cretaceous sub-alkaline mafic dykes from Swangkre-Rongmil, East Garo Hills, Shillong plateau, northeast India

    Rajesh K Srivastava; Anup K Sinha


    Numerous early Cretaceous mafic and alkaline dykes, mostly trending in N-S direction, are emplaced in the Archaean gneissic complex of the Shillong plateau, northeastern India. These dykes are spatially associated with the N-S trending deep-seated Nongchram fault and well exposed around the Swangkre-Rongmil region. The petrological and geochemical characteristics of mafic dykes from this area are presented. These mafic dykes show very sharp contact with the host rocks and do not show any signature of assimilation with them. Petrographically these mafic dykes vary from fine-grained basalt (samples from the dyke margin) to medium-grained dolerite (samples from the middle of the dyke) having very similar chemical compositions, which may be classified as basaltic-andesite/andesite. The geochemical characteristics of these mafic dykes suggest that these are genetically related to each other and probably derived from the same parental magma. Although, the high-field strength element (+rare-earth elements) compositions disallow the possibility of any crustal involvement in the genesis of these rocks, but Nb/La, La/Ta, and Ba/Ta ratios, and similarities of geochemical characteristics of present samples with the Elan Bank basalts and Rajmahal (Group II) mafic dyke samples, suggest minor contamination by assimilation with a small amount of upper crustal material. Chemistry, particularly REE, hints at an alkaline basaltic nature of melt. Trace element modelling suggests that the melt responsible for these mafic dykes had undergone extreme differentiation (∼50%) before its emplacement. The basaltic-andesite nature of these rocks may be attributed to this differentiation. Chemistry of these rocks also indicates ∼10–15% melting of the mantle source. The mafic dyke samples of the present investigation show very close geochemical similarities with the mafic rocks derived from the Kerguelen mantle plume. Perhaps the Swangkre-Rongmil mafic dykes are also derived

  14. Temporal correlation between dyke swarms and crustal extension in the middle Palaeozoic Vilyui rift basin, Siberian platform

    Polyansky, Oleg P.; Prokopiev, Andrei V.; Koroleva, Olga V.; Tomshin, Mikhail D.; Reverdatto, Vladimir V.; Selyatitsky, Alexander Yu.; Travin, Alexei V.; Vasiliev, Dmitry A.


    This paper presents results from new 40Ar/39Ar isotope dating of nine mafic dykes from three large dyke swarms (Vilyui-Markha, Kontai-Dzherba, and Chara-Sinsk) of the Yakutsk-Vilyui large igneous province (LIP), in addition to a reconstruction of the subsidence history of the middle Palaeozoic Vilyui paleorift basin (eastern Siberian platform). All previously published 40Ar/39Ar and U-Pb dates are summarized. Statistical analysis of the dyke ages reveals repeated magmatic events in the study area. Two major pulses of mafic magmatism are identified: one at the Frasnian-Famennian boundary, with a main peak at ca. 374.1 Ma, and another in the latest Devonian with a peak at ca. 363.4 Ma. The time of maximum intensity of dyke intrusion coincides (within uncertainty) with rapid subsidence in the Vilyui basin. The minimum total volume of middle Palaeozoic magmatism produced in the Yakutsk-Vilyui LIP is 100-215 K km3, which is much less than earlier estimates. Most of the mafic material within the Yakutsk-Vilyui LIP is related to the Vilyui basin and associated dyke swarms. Backstripping analysis of sedimentation in depressions of the Vilyui basin was carried out. Estimates were obtained for the spatial distribution of the stretching factor of the crust and mantle lithosphere, averaging 1.17 and 1.44, respectively. The amount of extension due to dyke intrusion is estimated to be 6%. Backstripping analysis of sedimentation in the Vilyui basin was used to assess the effect of both intraplate far-field forces and upwelling magma flows initiated by a mantle plume. A numerical thermomechanical model was developed to investigate the relations between two possible mechanisms by which the Vilyui rift was initiated: intraplate extension (passive rifting) and the ascent of a mantle magmatic diapir (active rifting). A model considering both of these mechanisms shows the contribution of the far-field extension forces and the effect of convective flows around the mantle plume, assuming

  15. Light rare earth element systematics as a tool for investigating the petrogenesis of phoscorite-carbonatite associations, as exemplified by the Phalaborwa Complex, South Africa

    Milani, Lorenzo; Bolhar, Robert; Frei, Dirk; Harlov, Daniel E.; Samuel, Vinod O.


    In-situ trace element analyses of fluorapatite, calcite, dolomite, olivine, and phlogopite have been undertaken on representative phoscorite and carbonatite rocks of the Palaeoproterozoic Phalaborwa Complex. Textural and compositional characterization reveals uniformity of fluorapatite and calcite among most of the intrusions, and seems to favor a common genetic origin for the phoscorite-carbonatite association. Representing major repositories for rare earth elements (REE), fluorapatite and calcite exhibit tightly correlated light REE (LREE) abundances, suggesting that partitioning of LREE into these rock forming minerals was principally controlled by simple igneous differentiation. However, light rare earth element distribution in apatite and calcite cannot be adequately explained by equilibrium and fractional crystallization and instead favors a complex crystallization history involving mixing of compositionally distinct magma batches, in agreement with previously reported mineral isotope variability that requires open-system behaviour.

  16. U-Pb ages, geochemistry, C-O-Nd-Sr-Hf isotopes and petrogenesis of the Catalão II carbonatitic complex (Alto Paranaíba Igneous Province, Brazil): implications for regional-scale heterogeneities in the Brazilian carbonatite associations

    Guarino, Vincenza; Wu, Fu-Yuan; Melluso, Leone; de Barros Gomes, Celso; Tassinari, Colombo Celso Gaeta; Ruberti, Excelso; Brilli, Mauro


    The Catalão II carbonatitic complex is part of the Alto Paranaíba Igneous Province (APIP), central Brazil, close to the Catalão I complex. Drill-hole sampling and detailed mineralogical and geochemical study point out the existence of ultramafic lamprophyres (phlogopite-picrites), calciocarbonatites, ferrocarbonatites, magnetitites, apatitites, phlogopitites and fenites, most of them of cumulitic origin. U-Pb data have constrained the age of Catalão I carbonatitic complex between 78 ± 1 and 81 ± 4 Ma. The initial strontium, neodymium and hafnium isotopic data of Catalão II (87Sr/86Sri = 0.70503-0.70599; ɛNdi = -6.8 to -4.7; 176Hf/177Hf = 0.28248-0.28249; ɛHfi = -10.33 to -10.8) are similar to the isotopic composition of the Catalão I complex and fall within the field of APIP kimberlites, kamafugites and phlogopite-picrites, indicating the provenance from an old lithospheric mantle source. Carbon isotopic data for Catalão II carbonatites (δ13C = -6.35 to -5.68 ‰) confirm the mantle origin of the carbon for these rocks. The origin of Catalão II cumulitic rocks is thought to be caused by differential settling of the heavy phases (magnetite, apatite, pyrochlore and sulphides) in a magma chamber repeatedly filled by carbonatitic/ferrocarbonatitic liquids ( s.l.). The Sr-Nd isotopic composition of the Catalão II rocks matches those of APIP rocks and is markedly different from the isotopic features of alkaline-carbonatitic complexes in the southernmost Brazil. The differences are also observed in the lithologies and the magmatic affinity of the igneous rocks found in the two areas, thus demonstrating the existence of regional-scale heterogeneity in the mantle sources underneath the Brazilian platform.

  17. In situ LA-ICP-MS and EPMA trace element characterization of Fe-Ti oxides from the phoscorite-carbonatite association at Phalaborwa, South Africa

    Milani, Lorenzo; Bolhar, Robert; Cawthorn, R. Grant; Frei, Dirk


    In situ laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and electron probe microanalysis (EPMA) are used to characterize magnetite and ilmenite of the phoscorite-carbonatite association at Phalaborwa. We trace the behavior of the compatible elements for two different generations of magnetite related to (1) a magmatic stage, with variable Ti-V content, which pre-dates the copper mineralization, and (2) a late hydrothermal, low-Ti, low-temperature event, mostly post-dating sulfide formation. Magnetite is shown to be a robust petrogenetic indicator; no influence on its chemical composition is detected from the intergrowth with the accompanying phases, including the interaction with coexisting sulfides. High spatial resolution EPMA characterize the tiny late-stage hydrothermal magnetite veins, as well as the ilmenite granular and lamellar exsolutions mostly developed in the magnetite from the phoscorite. By combining geochemical data with geothermo-oxybarometry calculations for magnetite-ilmenite pairs, we infer that the most primitive magnetite probably formed at oxygen fugacity above the nickel nickel oxide (NNO) buffer, revealing an evolutionary trend of decreasing temperature and oxygen fugacity. Geochemical similarity exists between magnetite from phoscorite and carbonatite, thus supporting a common mantle source for the phoscorite-carbonatite association.

  18. Magnetic resonance imaging depiction of acquired Dyke-Davidoff-Masson syndrome with crossed cerebro-cerebellar diaschisis: Report of two cases

    Ranjana Gupta


    Full Text Available Acquired Dyke-Davidoff-Masson syndrome, also known as hemispheric atrophy, is characterized by loss of volume of one cerebral hemisphere from an insult in early life. Crossed cerebellar diaschisis refers to dysfunction/atrophy of cerebellar hemisphere which is secondary to contralateral supratentorial insult. We describe magnetic resonance imaging findings in two cases of acquired Dyke-Davidoff-Masson syndrome with crossed cerebro-cerebellar diaschisis.

  19. Magnetic resonance imaging depiction of acquired Dyke-Davidoff-Masson syndrome with crossed cerebro-cerebellar diaschisis: Report of two cases.

    Gupta, Ranjana; Joshi, Sandeep; Mittal, Amit; Luthra, Ishita; Mittal, Puneet; Verma, Vibha


    Acquired Dyke-Davidoff-Masson syndrome, also known as hemispheric atrophy, is characterized by loss of volume of one cerebral hemisphere from an insult in early life. Crossed cerebellar diaschisis refers to dysfunction/atrophy of cerebellar hemisphere which is secondary to contralateral supratentorial insult. We describe magnetic resonance imaging findings in two cases of acquired Dyke-Davidoff-Masson syndrome with crossed cerebro-cerebellar diaschisis.

  20. Link between extension, dyking and subsidence as the reconstruction tool of intraplate rifting mechanism (backstripping data, modelling and geochronology)

    Polyansky, Oleg P.; Reverdatto, Vladimir V.; Babichev, Alexey V.


    Correlation between subsidence and extension-related magmatism is key in determining mechanism of intracratonic sedimentary basins formation. The total volume of basic sheet intrusions and volcanics within sedimentary rock mass characterizes indirectly the degree of depletion and thinning of the rifted mantle lithosphere. At present the documented features of real-world intracontinental basins show a wide range of parameters characterizing the duration and rate of subsidence, degree of extension/thinning of the lithosphere, age and extent of dyking. For creation of general model of continental rifting it is important to reconstruct an evolution of basins finished at the continental stage, not entered an oceanic spreading phase. One of examples of such structure is the Vilyui sedimentary basin in the eastern Siberian Platform which includes the massive emplacements (10**5 km3) of extrusive and intrusive rocks of the Vilyui large igneous province. We combine backstripping reconstructions of sedimentation and thermal regime during the subsidence with a numerical modelling based on the deformable solid mechanics. It is the first time that the evolution of sedimentation and subsidence which is nonuniform over the basin area has been analyzed for the Vilyui basin. The rift origin of the basin is proved. We estimate the spatial distribution of the parameters of crustal and mantle-lithosphere extension as well as expansion due to dike intrusions. According to the reconstructions, the type of subsidence curves for the sedimentary rocks of the basin depends on the tectonic regime of sedimentation in individual subbasins. The backstripping analysis revealed two stages of extension (sediments 4-5 km thick) and a foreland stage (sediments >2 km thick). With the two-layered lithosphere model, we concluded that the subcrustal layer underwent predominant extension (by a factor of 1.2-2.0 vs. 1.1-1.4 in the crust). In each section, dyke-related extension due to basic intrusion is

  1. Petrogenesis and tectonic implications of Upper Triassic appinite dykes in the East Kunlun orogenic belt, northern Tibetan Plateau

    Liu, Bin; Ma, Chang-Qian; Huang, Jian; Wang, Lian-Xun; Zhao, Shao-Qing; Yan, Rong; Sun, Yang; Xiong, Fu-Hao


    This paper presents geochronological, mineralogical, geochemical, and Sr-Nd isotopic data for recently identified Upper Triassic appinite dyke swarms in the East Kunlun orogenic belt (EKOB), northern Tibetan Plateau. Zircon U-Pb isotopic analyses using SHRIMP and LA-ICP-MS techniques yield 206Pb/238U ages of 226.1 ± 1.9 Ma and 226.4 ± 3.5 Ma, which can be interpreted as the crystallization ages of the appinite dykes. All the samples are characterized by high Al2O3 contents, enrichments in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) and strong depletions in Nb, Ta, Ti and P. These characteristics are comparable to those of subduction-related calc-alkaline high-Al basalts. Delayed plagioclase nucleation caused by relatively high-pressure conditions and high H2O contents is the most likely interpretation of the high Al contents. The geochemical and isotopic variations suggest that the appinite dykes were derived from partial melting of a mixed mantle source consisting of enriched lithospheric mantle and MORB-type asthenospheric mantle and had experienced some degree of crustal contamination during migration through continental crust. The appinite dykes are associated with previously documented, contemporaneous high-Ba-Sr and/or high-Sr/Y granites (225-223 Ma) derived from thickened mafic lower crust. These rocks provide important constraints on the compositional variations in the orogenic lithospheric mantle during the Late Triassic and provide evidence of a post-collisional environment associated with lithospheric delamination or slab break-off.

  2. Geochemistry of Metamafic Dykes from the Quanji Massif:Petrogenesis and Further Evidence for Oceanic Subduction, Late Paleoproterozoic, NW China

    Hassan Abdelslam Mustafa; Qinyan Wang; Nengsong Chen; Fanxi Liao; Min Sun; Meshaal Abdelgadir Salih


    A suite of ~1.84–1.92 Ga metamafic dykes within the paragneiss suite (khondalite) of the Quanji massif in NW China, has been chosen in this study for further understanding the tectonic evo-lution and possible links to the global Columbia supercontinent. Occurrence and field relations sug-gest that they were formed coevally with a previous studied ~1.83–1.85 Ga metamafic dyke swarms. Whole-rock major and trace elemental geochemistry suggests precursor magma of the amphibolites being generated from a volcanic arc-related tectonic setting rather than a back-arc environment where the metamafic dyke swarms were emplaced. The metamafic dykes show enrichment of LREE and strongly negative anomalies for Ta-Nb, Zr-Hf and Ti, have high SiO2 (49.3 wt.%–52.5 wt.%) but low MgO (6.40 wt.%–7.76 wt.%) contents and Mg# (Mg#=[100×(MgO/40.3)]/[MgO/40.3+FeO/71.8]) values (45.7–52.1), suggesting evolved precursor magma. The high values of La/Ta (22.2–42.8) and La/Nb (1.71–2.47), mildly negativeεNd(t) values (-2.51–0.15), with depleted mantle model ages (TDM) of 2.45–2.84 Ga, suggest that their precursor magmas were possibly derived from a subduction-related fluid metasomatized Archean sub-continental lithospheric mantle. This study provides further evi-dence for oceanic plate subduction prevailing before or around ~1.85 Ga, which confirms a prolonged subduction-accretion-collision history in the NW China which is possibly linked to the assembly of the Columbia supercontinent.

  3. The Cinder Lake Intrusive Complex, Knee Lake area, Central Manitoba: a Syenite- Carbonatite Association from a Neoarchean Continental Margin

    Chakhmouradian, A. R.; Böhm, C. O.; Kressall, R. D.; Lenton, P. G.


    The Cinder Lake intrusive complex is the only known occurrence of feldspathoid rocks in Manitoba. These rocks were initially mapped in the southeastern part of the Lake by Elbers (in Gilbert, 1985) and Lenton (1985), but have not been adequately studied. On the basis of new field, petrographic and geochemical evidence acquired in 2008, three discrete intrusive phases can be presently identified at Cinder Lake: fine-grained aegirine-nepheline syenite, fine-grained biotite-vishnevite syenite and syenitic pegmatite. There is also convincing mineralogical and geochemical evidence for the presence of unexposed clinopyroxenite and carbonatitic units genetically associated with the alkaline syenitic rocks. The evidence for the presence of unexposed carbonatite includes pervasive calcitization of the syenitic rocks, occurrence of rare-earth minerals (britholite, monazite and REE-rich apatite) in association with Sr-rich calcite in metasomatised pegmatite, and andradite veins crosscutting the syenites. The geochemistry of the Cinder Lake rocks is most consistent with the HFSE-depleted, potassic, high-Ba/La and high-Th/Nb signature of arc magmas (Edwards et al., 1994). In common with island-arc and continental-margin phonolites, the Cinder Lake syenites are potassic rocks with a chondritic Zr/Hf ratio, strong enrichment in Ba relative to La and Th relative to Nb. Uranium-lead dating of zircon crystals recovered from the biotite-vishnevite syenite yielded an age of 2705±2 Ma, interpreted as the timing of syenite emplacement. This value is close to the age of the incipient accretion of subprovinces in the northwestern Superior province at 2.70-2.71 Ga (Davis et al. 2005). Given this age relationship, the Cinder Lake complex is probably derived from magmas produced in a Neoarchean subduction zone underlying the North Caribou microcontinent. The regional geological setting of the complex (abundance of tonalite and granodiorite among the plutonic rocks and the predominance of

  4. Mineralogical and chemical character- istics of newer Dolerite Dyke around Keonjhar, Orissa: Implication for hydrothermal activity in subduction zone setting

    Piyali Sengupta; Arijit Ray; Sayantani Pramanik


    The newer dolerite dykes around Keonjhar within the Singbhum Granite occur in NE–SW, NW–SE and NNE–SSW trends. The mafic dykes of the present study exhibit several mineralogical changes like clouding of plagioclase feldspars, bastitisation of orthopyroxene, and development of fibrous amphibole (tremolite–actinolite) from clinopyroxene, which are all considered products of hydrothermal alterations. This alteration involves addition and subtraction of certain elements. Graphical analyses with alteration index and elemental abundances show that elements like Rb, Ba, Th, La and K have been added during the alteration process, whereas elements like Sc, Cr, Co, Ni, Si, Al, Fe, Mg and Ca have been removed. It is observed that in spite of such chemical alteration, correlation between major and trace elements, characteristic of petrogenetic process, is still preserved. This might reflect systematic alteration (addition or subtraction) of elements without disturbing the original element to element correlation. It has also been established by earlier workers that the evolution of newer dolerite had occurred in an arc-back arc setting which may also be true for newer dolerites of the present study. This is evident from plots of pyroxene composition and whole rock composition of newer dolerite samples in different tectonic discrimination diagrams using immobile elements. The newer dolerite dykes of the Keonjhar area may thus be considered to represent an example of hydrothermal activity on mafic rocks in an arc setting.

  5. Dyke-Davidoff-Masson syndrome: case report of fetal unilateral ventriculomegaly and hypoplastic left middle cerebral artery.

    Piro, Ettore; Piccione, Maria; Marrone, Gianluca; Giuffrè, Mario; Corsello, Giovanni


    Prenatal ultrasonographic detection of unilateral cerebral ventriculomegaly arises suspicion of pathological condition related to cerebrospinal fluid flow obstruction or cerebral parenchimal pathology. Dyke-Davidoff-Masson syndrome is a rare condition characterized by cerebral hemiatrophy, calvarial thickening, skull and facial asymmetry, contralateral hemiparesis, cognitive impairment and seizures. Congenital and acquired types are recognized and have been described, mainly in late childhood, adolescence and adult ages. We describe a female infant with prenatal diagnosis of unilateral left ventriculomegaly in which early brain MRI and contrast enhanced-MRI angiography, showed cerebral left hemiatrophy associated with reduced caliber of the left middle cerebral artery revealing the characteristic findings of the Dyke-Davidoff-Masson syndrome. Prenatal imaging, cerebral vascular anomaly responsible for the cerebral hemiatrophy and the early clinical evolution have never been described before in such a young child and complete the acquired clinical descriptions in older children. Differential diagnosis, genetic investigations, neurophysiologic assessments, short term clinical and developmental follow up are described. Dyke-Davidoff-Masson syndrome must be ruled out in differential diagnosis of fetal unilateral ventriculomegaly. Early clinical assessment, differential diagnosis and cerebral imaging including cerebral MRI angiography allow the clinicians to diagnose also in early infancy this rare condition.

  6. Quasi 2D hydrodynamic modelling of the flooded hinterland due to dyke breaching on the Elbe River

    S. Huang


    Full Text Available In flood modeling, many 1D and 2D combination and 2D models are used to simulate diversion of water from rivers through dyke breaches into the hinterland for extreme flood events. However, these models are too demanding in data requirements and computational resources which is an important consideration when uncertainty analysis using Monte Carlo techniques is used to complement the modeling exercise. The goal of this paper is to show the development of a quasi-2D modeling approach, which still calculates the dynamic wave in 1D but the discretisation of the computational units are in 2D, allowing a better spatial representation of the flow in the hinterland due to dyke breaching without a large additional expenditure on data pre-processing and computational time. A 2D representation of the flow and velocity fields is required to model sediment and micro-pollutant transport. The model DYNHYD (1D hydrodynamics from the WASP5 modeling package was used as a basis for the simulations. The model was extended to incorporate the quasi-2D approach and a Monte-Carlo Analysis was used to conduct a flood sensitivity analysis to determine the sensitivity of parameters and boundary conditions to the resulting water flow. An extreme flood event on the Elbe River, Germany, with a possible dyke breach area was used as a test case. The results show a good similarity with those obtained from another 1D/2D modeling study.

  7. New type of brittle deformations: two-axial turn structure of fractures in the Kovdor carbonatite intrusion (NW Russia)

    Zhirov, Dmitry


    The Earth's crust is known for a few types of structural fissuring and faults organization. First of all, this is an orthogonal or some kind of non-orthogonal fissuring network with a various number of systems. The hierarchic model is also popular since it stipulates a regular arrangement and collateral subordination of several ranks of elements relative to each other, and a general fault and/or shear zone. An axis-symmetric fissuring structure is developed in the central (ring)-type massifs and some other geological bodies. It is formed due to the progressive turn of adjoining fissure planes around the massif symmetry axis (mostly vertical) at a discrete angle (within 5-15° on the average depending on the scale and internal structural features). The investigation of the fault tectonics in the Kovdor carbonatite intrusion (NW Russia) has resulted in the identification of a new brittle deformations type. It is formed due to the simultaneous turn of fissure planes at discrete angles around two orthogonal guiding lines (axes), where one is represented by a vertical massif symmetry axis (L1), and the other axis (L2) lies horizontally in the fracture plane. Nonetheless, the rotation along the both axes is codirectional, i.e., when moving counterclockwise around the L1 axis, the L2 rotation is also counterclockwise. If we very tentatively consider a fissure as an ellipse, and take into account the whole assemblage of long and short axes, the overall picture of their spatial distribution generates a screw conoid or ordinary helicoid type structure. It will be shown as an S-shaped plane poles chain in the stereogram. A sequence of large scale fissures (longer than 100 meters), which are 25 to 100 meters apart from each other and regularly vary in strike and dip angle, is mapped in the open pit of the Kovdor apatite-magnetite deposit. The accuracy of positioning for each fissure is a few centimeters in measurement spots, with a deviation from its actual surface due to the

  8. Three Paleoproterozoic A-type granite intrusions and associated dykes from Kainuu, East Finland

    Hannu Huhma


    Full Text Available Mafic and felsic intrusive rocks aged 2.5–2.4 Ga have been observed over a large area in eastern and northern Finland, as well as in adjacent northwestern Russia. We describe three granite intrusions and associated dykes from Kainuu, Finland, that belong to this bimodal magmatic event. All these three granites show clear A2-type chemical affinities with high Y/Nb, HREE, Fe/Mg, Ga and Nb. Two of the intrusions, Rasinkylä and Pussisvaara, were dated at 2425±3 and 2427±3 Ma, respectively, using thermal ionisation mass spectrometry utilizing the chemical abrasion method (CA-TIMS. CA-TIMS ages are supported by single-grain age determinations obtained by using Laser Ablation Multicollector Inductively Coupled Plasma Mass Spectrometer (LA-MC-ICPMS. New data on the previously described Rasimäki granite from southern Kainuu is presented, including an age of 2389±5 Ma obtained with LA-MC-ICPMS. The variable magnetite content of the granites is proposed to reflect the differences in the oxidation state of the source, which in our interpretation is the local Archean lower crust. Partial melting and the emplacement of the granites occurred in an extensional environment. Heat for the partial melting was provided by mafic magmas under and intraplating the extended crust.

  9. Acute myeloblastic leukemia-associated Marfan syndrome and Davidoff-Dyke-Masson syndrome: a case report

    Ahmet Faik Öner


    Full Text Available We present herein a 23-year-old man with acute myeloblastic leukemia (AML associated with Davidoff-Dyke-Masson syndrome (DDMS and Marfan syndrome (MS. The diagnosis of DDMS was based on findings including left facial asymmetry, left hemiparesis, mental retardation, right cerebral hemiatrophy, dilatation of the ipsilateral lateral ventricle and calvarial thickening. The diagnosis of MS was based on clinical findings including tall stature, myopia, retinitis pigmentosa, blue scleras, scoliosis, pectus excavatum, arachnodactyly and low ratio of upper/lower body segment. The patient developed hepatosplenomegaly, gingival hypertrophy and pancytopenia. Peripheral blood film and bone marrow examination showed that most of nucleated cells were blasts; immunophenotype of those cells showed CD11+, CD13+, CD14+, CD33+ and HLA-DR+. These findings confirmed the diagnosis of AML (FAB-M5. After induction chemotherapy, remission was obtained. To the best of our knowledge, our case is the third report of AML in MS syndrome, while AML associated with DDMS and MS has not been previously reported in the literature.

  10. Can we see the distal dyke communicate with the caldera? Examples of temporal correlation analysis using seismicity from the Bárðarbunga volcano

    Jónsdóttir, Kristín; Jónasson, Kristján; Tumi Guðmundsson, Magnús; Hensch, Martin; Hooper, Andrew; Holohan, Eoghan; Sigmundsson, Freysteinn; Halldórsson, Sæmundur Ari; Vogfjörð, Kristín; Roberts, Matthew; Barsotti, Sara; Ófeigsson, Benedikt; Hjörleifsdóttir, Vala; Magnússon, Eyjólfur; Pálsson, Finnur; Parks, Michelle; Dumont, Stephanie; Einarsson, Páll; Guðmundsson, Gunnar


    The Bárðarbunga volcano is composed of a large oval caldera (7x11 km) and fissures extending tens of kilometers away from the caldera along the rift zone, which marks the divergent plate boundary across Iceland. On August 16th, 2014 an intense seismic swarm started below the Bárðarbunga caldera and in the two weeks that followed a dyke migrated some 47 km laterally in the uppermost 6-10 km of the crust along the rift. The dyke propagation terminated in lava fields just north of Vatnajökull glacier, where a major (1.5 km3) six months long eruption took place. Intense earthquake activity in the caldera started in the period August 21-24 with over 70 M5 earthquakes accompanying slow caldera collapse, as verified by various geodetic measurements. The subsidence is likely due to magma withdrawal from a reservoir at depth beneath the caldera. During a five months period, October-February, the seismic activity was separated by over 30 km in two clusters; one along the caldera rims (due to piecewise caldera subsidence) and the other at the far end of the dyke (as a result of small shear movements). Here we present statistical analysis comparing the temporal behaviour of seismicity recorded in the two clusters. By comparing the earthquake rate in the dyke in temporal bins before and after caldera subsidence earthquakes to the rate away from these bins (background rate), we show posing a statistical p-value test, that the number of dyke earthquakes was significantly higher (p earthquake (>M4.6) in the caldera. Increased dyke seismicity was also observed 0-3 hours following a large caldera earthquake. Elevated seismicity in the dyke before a large caldera earthquake may occur when a constriction in the dyke was reduced, followed by pressure drop in the chamber. Assuming that the large caldera earthquakes occurred when chamber pressure was lowest, the subsiding caldera piston may have caused temporary higher pressure in the dyke and thereby increased the likelihood of an

  11. Mineral Chemistry of Melanite from Calcitic Ijolite, the Oka Carbonatite Complex, Canada:Implications for Multi-Pulse Magma Mixing

    Wei Chen; Weiqi Zhang; Antonio Simonetti; Shaoyong Jiang


    Ti-rich garnet is found within calcitic ijolite from the Oka carbonatite complex in Can-ada, which is characterized by 58%–73% andradite component (2.12 wt.%–4.18 wt.% TiO2) and classi-fied as melanite. The garnet displays complex zoning and contains abundant high field strength ele-ments (HFSEs) and rare earth elements (REEs). Three groups (I, II, III) have been identified based on their petrographic nature. Compared to groups II and III, Group I garnet cores contain higher TiO2, MgO, HFSE, and REE and lower SiO2 abundances. The distinct chemical and petrographic signatures of the investigated garnets cannot be attributed to simple closed system crystallization, but they are consistent with the multi-pulse magma mixing. Combined with previously reported U-Pb ages for apa-tite from the calcitic ijolite, at least three stages of magma evolution and subsequent mixing have been involved in the generation of calcitic ijolite at Oka. The early-formed melt that generated Group I gar-net core was later mixed with at least two small-volume, more evolved melts. The intermediate stage melt formed the remaining garnet along with some pyroxene, calcite, nepheline, and apatite at 127±3.6 Ma. The youngest, most evolved melt generated the majority of pyroxene, calcite, nepheline, and apatite within the calcitic ijolite at 115±3.1 Ma.

  12. Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elements

    F. R. D. Andrade


    Full Text Available This paper presents results on the composition of Portland clinkers produced with non-conventional raw-materials and fuels, focusing on the distribution of selected trace elements. Clinkers produced with three different fuel compositions were sampled in an industrial plant, where all other parameters were kept unchanged. The fuels have chemical fingerprints, which are sulfur for petroleum coke and zinc for TDF (tire-derived fuel. Presence of carbonatite in the raw materials is indicated by high amounts of strontium and phosphorous. Electron microprobe data was used to determine occupation of structural site of both C3S and C2S, and the distribution of trace elements among clinker phases. Phosphorous occurs in similar proportions in C3S and C2S; while considering its modal abundance, C3S is its main reservoir in the clinker. Sulfur is preferentially partitioned toward C2S compared to C3S. Strontium substitutes for Ca2+ mainly in C2S and in non-silicatic phases, compared to C3S.

  13. Mineral chemistry of monazite-(Nd, xenotime-(Y, apatite, fluorite and zircon hosting in lamprophyre dyke in Abu Rusheid area, South Eastern Desert, Egypt

    Mohamed A. Ali


    Full Text Available The studied mineralized lamprophyre dyke in Abu Rusheid area is trending NNW-SSE, and occurs withinAbu Rusheid mineralized shear zone, measuring 0.2 - 1.0 m in width and 0.5 - 1.0 km in length. It was emplacedparallel with the Abu Rusheid shear zone. The dyke is mainly composed of plagioclases, amphiboles, mica (musco-vite and biotite, relics of pyroxenes with K-feldspars and quartz derived from surrounding country rocks asphenocrysts embedded in fine-grained groundmass. The lamprophyre dyke hosts REE-minerals monazite-(Nd,xenotime-(Y, and REE-bearing minerals apatite, fluorite, zircon-(Hf, rutile with inclusions of xenotime and ironoxides. The emplacement of lamprophyre dyke caused heating in the mineralized shear zone of Abu Rusheid area.The lamprophyre dyke was subsequently affected by hydrothermal alterations (e.g. chlorite-carbonate, muscovitization,fluoritization.The REE were remobilized from the mineralized shear zones by hydrothermal solutionsand re-precipitatedas REE-minerals xenotime-(Y and monazite-(Nd around flourapatite, fluorite, zircon andrutile. The solid solutions between monazite-(Nd and xenotime-(Y were formed as a product precipitation fromhydrothermal solutions. Also, the apatite mineral in the lamprophyre dyke was subjected to the heating duringthe emplacement, which lead to its alteration and breakdown with concominant precipitation of xenotime-(Yand monazite-(Nd. The chemistry of monazite-(Nd and xenotime-(Y obtained by scanning electron microscopy(SEM, and electron probe microanalysis (EPMA, showed that these minerals are enriched in U and Th. Themonazite-(Nd associated with fluorapatite in the studied dyke is poor in Th (0.02 ≤ Th ≤ 0.81 wt%, but usuallyrich in U (0.92 ≤ U ≤ 2.91 wt%, which indicates that monazite formed as a result of flourapatite metasomatism.

  14. Flood risk control of dams and dykes in middle reach of Huaihe River

    Zhen-kun MA


    Full Text Available Three stochastic mathematical models for calculation of the reservoir flood regulation process, river course flood release, and flood risk rate under flood control were established based on the theory of stochastic differential equations and features of flood control systems in the middle reach of the Huaihe River from Xixian to the Bengbu floodgate, comprehensively considering uncertain factors of hydrology, hydraulics, and engineering control. They were used to calculate the flood risk rate with flood regulation of five key reservoirs, including the Meishan, Xianghongdian, Nianyushan, Mozitan, and Foziling reservoirs in the middle reach of the Huaihe River under different flood frequencies, the flood risk rate with river course flood release under design and check floods for the trunk of the Huaihe River in conjunction with relevant flood storage areas, and the flood risk rate with operation of the Linhuaigang Project under design and check floods. The calculated results show that (1 the five reservoirs can withstand design floods, but the Xianghongdian and Foziling reservoirs will suffer overtopping accidents under check floods; (2 considering the service of flood storage areas under the design flood conditions of the Huaihe River, the mean flood risk rate with flood regulation of dykes and dams from Xixian to the Bengbu floodgate is about 0.2, and the trunk of the Huaihe River can generally withstand design floods; and (3 under a check flood with the flood return period of 1 000 years, the risk rate of overtopping accidents of the Linhuaigang Project is not larger than 0.15, indicating that it has a high flood regulation capacity. Through regulation and application of the flood control system of the Linhuigang Project, the Huaihe River Basin can withstand large floods, and the safety of the protected area can be ensured.

  15. Zirconolite, zircon and monazite-(Ce) U-Th-Pb age constraints on the emplacement, deformation and alteration history of the Cummins Range Carbonatite Complex, Halls Creek Orogen, Kimberley region, Western Australia

    Downes, Peter J.; Dunkley, Daniel J.; Fletcher, Ian R.; McNaughton, Neal J.; Rasmussen, Birger; Jaques, A. Lynton; Verrall, Michael; Sweetapple, Marcus T.


    In situ SHRIMP U-Pb dating of zirconolite in clinopyroxenite from the Cummins Range Carbonatite Complex, situated in the southern Halls Creek Orogen, Kimberley region, Western Australia, has provided a reliable 207Pb/206Pb age of emplacement of 1009 ± 16 Ma. Variably metamict and recrystallised zircons from co-magmatic carbonatites, including a megacryst ~1.5 cm long, gave a range of ages from ~1043-998 Ma, reflecting partial isotopic resetting during post-emplacement deformation and alteration. Monazite-(Ce) in a strongly foliated dolomite carbonatite produced U-Th-Pb dates ranging from ~900-590 Ma. Although the monazite-(Ce) data cannot give any definitive ages, they clearly reflect a long history of hydrothermal alteration/recrystallisation, over at least 300 million years. This is consistent with the apparent resetting of the Rb-Sr and K-Ar isotopic systems by a post-emplacement thermal event at ~900 Ma during the intracratonic Yampi Orogeny. The emplacement of the Cummins Range Carbonatite Complex probably resulted from the reactivation of a deep crustal structure within the Halls Creek Orogen during the amalgamation of Proterozoic Australia with Rodinia over the period ~1000-950 Ma. This may have allowed an alkaline carbonated silicate magma that was parental to the Cummins Range carbonatites, and generated by redox and/or decompression partial melting of the asthenospheric mantle, to ascend from the base of the continental lithosphere along the lithospheric discontinuity constituted by the southern edge of the Halls Creek Orogen. There is no evidence of a link between the emplacement of the Cummins Range Carbonatite Complex and mafic large igneous province magmatism indicative of mantle plume activity. Rather, patterns of Proterozoic alkaline magmatism in the Kimberley Craton may have been controlled by changing plate motions during the Nuna-Rodinia supercontinent cycles (~1200-800 Ma).

  16. Plume-derived rare gases in 380 Ma carbonatites from the Kola region (Russia) and the argon isotopic composition in the deep mantle

    Marty, Bernard; Tolstikhin, Igor; Kamensky, Igor L.; Nivin, Valentin; Balaganskaya, Elena; Zimmermann, Jean-Louis


    In an effort to document the source of the parental melts to carbonatites, we have measured rare gases in 380 Ma carbonatites and associated mineral assemblages from the Kola Peninsula, eastern part of the Baltic shield in Russia. These series were emplaced during widespread Devonian magmatism when several large ultrabasic-alkaline-carbonatite massifs were formed. 4He/ 3He ratios vary from 1×10 6 to 1×10 7 in the bulk He extracted by melting of samples from three localities, including the large Kovdor massif. A comparison of measured abundances of 3He and 4He with those expected from in-situ production revealed a large (up to 10 5 times) excess of 3He, implying a significant contribution from a mantle-derived 3He-bearing fluid. Crushing of these samples allowed extraction of fluids with 4He/ 3He ratios down to 38,000, lower than those of mid-ocean ridge basalts and in the range of 4He/ 3He observed in 3He-rich ocean island basalts (OIBs) related to mantle plumes. 20Ne/ 22Ne up to 12.1±0.2 are higher than the atmospheric value of 9.80, implying the occurrence of primordial (solar-type) neon in the carbonatite source. 20Ne/ 22Ne and 21Ne/ 22Ne ratios display a good correlation, with the regression line close to (slightly to the right of) the Loihi Seamount correlation. Extrapolation of the regression to solar 20Ne/ 22Ne of 13.8 gives a 21Ne/ 22Ne of 0.045 for the plume end-member, well below the mid-ocean ridge basalt (MORB) source (upper mantle) end-member of 0.07. The measured 40Ar/ 36Ar ratios up to 2790 correlate very well with the Ne isotopic ratios, and the best estimate of the 40Ar/ 36Ar ratio of the plume source is within 5000±1000. Although the 3He/ 22Ne ratio in the plume source appears to be comparable to the solar value within a factor of 2, the 22Ne/ 36Ar ratio, computed from Ne-Ar isotope correlation, is two orders of magnitude lower than the solar value. Such difference is unlikely to be due to magmatic fractionation since the observed 4He/ 40Ar

  17. Anisotropy of magnetic susceptibility in welded tuffs: application to a welded-tuff dyke in the tertiary Trans-Pecos Texas volcanic province, USA

    Wolff, John A.; Ellwood, Brooks B.; Sachs, Scott D.


    Consideration of published anisotropy of magnetic susceptibility (AMS) studies on welded ignimbrites suggests that AMS fabrics are controlled by groundmass microlites distributed within the existing tuff fabric, the sum result of directional fabrics imposed by primary flow lineation, welding, and (if relevant) rheomorphism. AMS is a more sensitive indicator of fabric elements within welded tuffs than conventional methods, and usually yields primary flow azimuth estimates. Detailed study of a single densely welded tuff sample demonstrates that the overall AMS fabric is insensitive to the relative abundances of fiamme, matrix and lithics within individual drilled cores. AMS determinations on a welded-tuff dyke occurring in a choked vent in the Trans-Pecos Texas volcanic field reveals a consistent fabric with a prolate element imbricated with respect to one wall of the dyke, while total magnetic susceptibility and density exhibit axially symmetric variations across the dyke width. The dyke is interpreted to have formed as a result of agglutination of the erupting mixture on a portion of the conduit wall as it failed and slid into the conduit, followed by residual squeezing between the failed block and in situ wallrock. Irrespective of the precise mechanism, widespread occurrence of both welded-tuff dykes and point-welded, aggregate pumices in pyroclastic deposits may imply that lining of conduit walls by agglutionation during explosive volcanic eruptions is a common process.

  18. Ultramafic lavas and pyroxene-spinifex high-Mg basaltic dykes from the Othris ophiolite complex, Greece

    Baziotis, Ioannis; Economou-Eliopoulos, Maria; Asimow, Paul


    This study aims to constrain the physico-chemical conditions and processes associated with the origin of ultramafic lavas of the Agrilia formation and high-Mg basaltic dykes in the Pournari area within the Othris ophiolite complex, a supra-subduction zone ophiolite of Mesozoic age (Paraskevopoulos & Economou, 1986; Barth et al., 2008). Hand-sample-scale spinifex texture is lacking from the ultramafic lavas and, despite whole-rock MgO contents greater than 31 wt.%, we infer an upper bound of 17 wt.% MgO for the erupted liquid, and thus identify these lavas as picrites containing accumulated olivine. We use textural and compositional criteria to divide the crystals within the Agrilia lavas between pre-eruptive and post-eruptive growth phases. The high-Mg basaltic dyke margins display a distinctive thin-section-scale micro-spinifex texture of skeletal and plumose Al- and Fe-rich clinopyroxene surrounded by large crystals of orthopyroxene. Normally zoned clinopyroxene in the Agrilia lavas and clinopyroxene of various textures (skeletal, needle- and dendritic-like) and sizes in the Pournari dykes display anomalous enrichment in Al2O3 and FeO* with decreasing MgO that require rapid, disequilibrium growth. Quantitative characteristics of the micro-spinifex pyroxene textures (Journal of Petrology 29, 305-331. Barth et al., 2008. Lithos, 100(1), 234-254. Faure et al., 2006. Journal of Petrology 47, 1591- 1610. Paraskevopoulos, G., Economou, M., 1986. Ofioliti 11 (3), 293 - 304. Roeder et al., 2001. The Canadian Mineralogist, 39(2), 397-416. Welsch et al., 2016. Contributions to Mineralogy and Petrology 171(1), 1-19.

  19. Application of generalized inverse for analysis of magnetic anomalies due to a dyke model - Some numerical experiments

    Rao, M.M.M.; Murty, T.V.R.; SuryaPrakash, S.; Chandramouli, P.; Murthy, K.S.R.

    by the computer from the field profile and their ratios or magnitudes are used to calculate the parameters by properly derived empirical relations. The characteristic distances to be measured are chosen, by trial and error, such that they or their ratios vary... of the dyke. For this, the anomalies ∆T(x i ) are digitized at distances measured from a convenient reference on the profile. When the distances are measured relative to the reference point, the anomaly equation is rewritten as ∆T(x i ) = C [cos Q ( θ A...

  20. Sentinel-1 TOPS interferometry for geophysical applications: Dyke intrusion imaged during 2014 Pico do Fogo eruption

    Gonzalez, Pablo J.; Marinkovic, Petar; Samsonov, Sergey; Hooper, Andrew; Larsen, Yngvar; Wright, Tim


    apply Sentinel-1 TOPS-InSAR to illuminate the deformation accompanying a recent volcanic eruption at Pico do Fogo volcano, Fogo (Cape Verde). The detected deformation is consistent with a shallow near-vertical dyke intrusion, which fed the fissure eruption. The modelling of the deformation interferograms do not seem affected largely by the variable LoS vector, in this case. The presented results prove the potential of Terrain observation by progressive scans (TOPS) interferometry for geophysical applications, in particular using ESA Sentinel-1 mission.

  1. The alkaline peralkaline granitic post-collisional Tin Zebane dyke swarm (Pan-African Tuareg shield, Algeria): prevalent mantle signature and late agpaitic differentiation

    Hadj-Kaddour, Zakia; Liégeois, Jean-Paul; Demaiffe, Daniel; Caby, Renaud


    The Tin Zebane dyke swarm was emplaced at the end of the Pan-African orogeny along a mega-shear zone separating two contrasting terranes of the Tuareg shield. It is located along the western boundary of the Archaean In Ouzzal rigid terrane, but inside the adjacent Tassendjanet terrane, strongly remobilized at the end of the Precambrian. The Tin Zebane swarm was emplaced during post-collisional sinistral movements along the shear zone at 592.2±5.8 Ma (19WR Rb-Sr isochron). It is a dyke-on-dyke system consisting of dykes and stocks of gabbros and dykes of metaluminous and peralkaline granites. All rock types have Sr and Nd isotopic initial ratios (Sr i=0.7028 and ɛNd=+6.2) typical of a depleted mantle source, similar to the prevalent mantle (PREMA) at that period. No crustal contamination occurred in the genesis of the Tin Zebane swarm. Even the samples showing evidence of fluid interaction (essentially alkali mobility) have the same isotopic signature. The peralkaline granites have peculiar geochemical characteristics that mimic subduction-related granites: this geochemical signature is interpreted in terms of extensive differentiation effects due to late cumulates comprising aegirine, zircon, titanite, allanite and possibly fergusonite, separated from the liquid in the swarm itself due to magmatic flow turbulence. The Tin Zebane dyke swarm is thus of paramount importance for constraining the differentiation of mantle products to generate highly evolved alkaline granites without continental crust participation, in a post-collisional setting.

  2. Syn-convergence extension in the southern Lhasa terrane: Evidence from late Cretaceous adakitic granodiorite and coeval gabbroic-dioritic dykes

    Ma, Xuxuan; Xu, Zhiqin; Meert, Joseph G.


    Late Cretaceous (∼100-80 Ma) magmatism in the Gangdese magmatic belt plays a pivotal role in understanding the evolutionary history and tectonic regime of the southern Lhasa terrane. The geodynamic process for the formation of the early Late Cretaceous magmatism has long been an issue of hot debates. Here, petrology, geochronology and geochemistry of early Late Cretaceous granodiorite and coeval gabbroic-dioritic dykes in the Caina region, southern Lhasa, were investigated in an effort to ascertain their petrogenesis, age of intrusion, magma mixing and tectonic setting. Zircon U-Pb dating of granodiorite yields 206Pb/238U ages of 85.8 ± 1.7 and 86.4 ± 1.1 Ma, whilst that of the E-W trending dykes yields ages of 82.7 ± 2.6 and 83.5 ± 3.5 Ma. Within error, the crystallization ages of the dykes and the granodiorite are indistinguishable. Field observations and mineralogical microstructures are suggestive of a magma mixing process during the formation of the dykes and the granodiorite. The granodiorite exhibits geochemical features that are in agreement with those of subduction-related high-SiO2 adakites. The granodiorite and dykes have relatively constant εNd(t) values of +2.2 to +4.9 and initial 87Sr/86Sr ratios (0.7045-0.7047). These similar characteristics are herein interpreted as an evolutionary series from the dykes to granodiorite, consistent with magma mixing process. Ti-in-zircon thermometer and Al-in-hornblende barometer indicate that the granodiorite and the dioritic dyke crystallized at temperatures of ca. 750 and 800 °C, depths of ca. 6-10 and 5-9 km, respectively. Taking into account the synchronous magmatic rocks in the Gangdese Belt and the coeval rifted basin within the Lhasa terrane, the granodiorite and dykes reveal an early Late Cretaceous syn-convergence extensional regime in the southern Lhasa terrane, triggered by slab rollback of the Neotethyan oceanic lithosphere.

  3. A 100 Ma bimodal composite dyke complex in the Jiamusi Block, NE China: An indication for lithospheric extension driven by Paleo-Pacific roll-back

    Sun, Ming-Dao; Chen, Han-Lin; Zhang, Feng-Qi; Wilde, Simon A.; Dong, Chuan-Wan; Yang, Shu-Feng


    A 125 m-wide bimodal composite dyke complex, consisting of rhyolite and dolerite dykes, was emplaced into Cretaceous volcanic strata of the Songmuhe Formation in the Jiamusi Block of NE China. The dolerite dykes are sub-vertical, strike north-south, and intruded into both the country rocks and rhyolite dykes soon after the latter solidified. SHRIMP zircon U-Pb dating shows that the rhyolite dykes were emplaced at 100 ± 2 Ma and the dolerite dykes were also most likely emplaced at 100 ± 2 Ma. The rhyolite is characterized by enrichment in large-ion lithophile elements (LILE) and light rare earth elements (LREE), and depletion in high-field strength elements (HFSE). It shows a significant negative Eu anomaly, and has ɛNd(t) values ranging from 0.49 to 1.66 and two groups of initial 87Sr/86Sr ratios at 0.7045 and 0.7061. The rhyolite displays the compositional signature of Peraluminous Ferroan Granitoid, indicating it was derived by either differentiation of basalt and/or low pressure partial melting of crust. The dolerite is also characterized by enrichment in LILE and LREE, and depletion in HFSE. It has a weak negative Eu anomaly and has ɛNd(t) = - 1.22 to + 3.26, and (87Sr/86Sr)i = 0.7057-0.7074. The dolerite originated from partial melting of lithospheric mantle which was affected by subducted oceanic crust, and experienced different amounts of crustal contamination. Such bimodal dyke complexes are an important indicator of crustal extension under the influence of mantle processes. Thus the dyke complex in the Jiamusi Block indicates mid-Cretaceous intra-plate extension in NE China related to the subduction of the paleo-Pacific plate along the eastern Eurasian continental margin. When compared with Mesozoic bimodal magmatism further to the west, our new data support a temporal eastward migration of magmatism over a distance > 1000 km from ~ 160 Ma to ~ 100 Ma. This was most likely associated with roll-back of the paleo-Pacific Plate and consequent upwelling of

  4. Study on Carbonate Limestone Dykes (Neptunian Dykes) of Upper Devonian in Nanbiancun, Guilin, Guangxi%广西桂林南边村上泥盆统沉积灰岩脉研究

    彭阳; 陆刚; 胡贵昂


    、亮晶胶结物、铁泥质等,与孔隙水混合形成粘稠的液化颗粒灰岩流,灌入这些张裂隙.二者裂隙成因均与台缘同沉积断层的构造—地震活动密切相关.即:同沉积断层发生时,在南边村剖面层45中产生刚性张裂隙,而其上覆地层的沉积物还处在弱固结的塑性状态,发生混合、颗粒化形成塑性液化颗粒流灌入下伏裂隙中.因此,南边村剖面层45中的沉积灰岩脉是软硬岩层对同沉积断层活动诱发地震的不同响应.而南边村剖面晚泥盆世所处的台缘靠近斜坡的古地理位置是其沉积灰岩脉的内部结构构造与众不同的原因.%Carbonate neptunian dykes occurred commonly in Late Palaeozoic carbonate plateform margins in Guilin and Northwestern Youjiang basin, Guangxi Autonomous Region. In the Nanbiancun International Devonian- Carboniferous (bed 55 ~ 56) Boundary (DCB) Parastratotype Section of Guilin of Guangxi, carbonate neptunian dykes are identified in Bed 45 (a liquefied grainstone vein) and Bed 50 (some fine crystal fiber calcite veins, as signal of tension structure background) and is considered far different from those in the Miaotou section of Guilin and Youjiang Basin. In the Miaotou section of Guilin and the Youjiang Basin, the infillings of neptunian dyke are afterwards normal sea water sediments, while in the Nanbiancun section of Guilin are simultaneous overlain liquefied soft-sediment-flow, shown as skeletals and non-skeletal grains ( with dark Fe-bearing clays, fine calcites and fine skeletals) mixture. The non-skeletal grains deformed and impinged each other with very few cements among them That means they are not normal sea water deposits. The skeletal grains are mainly brachiopod and crinoid stems crowded floating in non-skeletal grains. A single Brachiopods shell are folded as "U" shape and then cut into several continuous parts in situ. That means a slowly soft press surrounding and wholly flowing. The upper part of the

  5. Onset of seafloor spreading in the Iapetus Ocean at 608 Ma: precise age of the Sarek Dyke Swarm, northern Swedish Caledonides

    Svenningsen, Olaf


    that crystallization in the youngest dykes mimicked similar processes in gabbro plutons. Six zircon fractions, from the diorite pods including two single grains, were analysed geochronologically by the U–Pb thermal ionization mass spectrometry method. The data yield a linear array of points that are 0.4–0.8% normally...

  6. Dyke leakage localization and hydraulic permeability estimation through self-potential and hydro-acoustic measurements: Self-potential 'abacus' diagram for hydraulic permeability estimation and uncertainty computation

    Bolève, A.; Vandemeulebrouck, J.; Grangeon, J.


    In the present study, we propose the combination of two geophysical techniques, which we have applied to a dyke located in southeastern France that has a visible downstream flood area: the self-potential (SP) and hydro-acoustic methods. These methods are sensitive to two different types of signals: electric signals and water-soil pressure disturbances, respectively. The advantages of the SP technique lie in the high rate of data acquisition, which allows assessment of long dykes, and direct diagnosis in terms of leakage area delimitation and quantification. Coupled with punctual hydro-acoustic cartography, a leakage position can be precisely located, therefore allowing specific remediation decisions with regard to the results of the geophysical investigation. Here, the precise localization of leakage from an earth dyke has been identified using SP and hydro-acoustic signals, with the permeability of the preferential fluid flow area estimated by forward SP modeling. Moreover, we propose a general 'abacus' diagram for the estimation of hydraulic permeability of dyke leakage according to the magnitude of over water SP anomalies and the associated uncertainty.

  7. Integration of geotechnical and geophysical techniques for the characterization of a small earth-filled canal dyke and the localization of water leakage

    Bièvre, Grégory; Lacroix, Pascal; Oxarango, Laurent; Goutaland, David; Monnot, Guy; Fargier, Yannick


    This paper investigates the combined use of extensive geotechnical, hydrogeological and geophysical techniques to assess a small earth dyke with a permanent hydraulic head, namely a canal embankment. The experimental site was chosen because of known issues regarding internal erosion and piping phenomena. Two leakages were visually located following the emptying of the canal prior to remediation works. The results showed a good agreement between the geophysical imaging techniques (Electrical Resistivity Tomography, P- and SH-waves Tomography) and the geotechnical data to detect the depth to the bedrock and its lateral variations. It appeared that surface waves might not be fully adapted for dyke investigation because of the particular geometry of the studied dyke, non-respectful of the 1D assumption, and which induced depth and velocity discrepancies retrieved from Rayleigh and Love waves inversion. The use of these classical prospecting techniques however did not allow to directly locate the two leakages within the studied earth dyke. The analysis of ambient vibration time series with a modified beam-forming algorithm allowed to localize the most energetic water flow prior to remediation works. It was not possible to detect the leakage after remediation works, suggesting that they efficiently contributed to significantly reduce the water flow. The second leakage was not detected probably because of a non-turbulent water flow, generating few energetic vibrations.

  8. Ultrapotassic dykes in the Moldanubian Zone and their significance for understanding of the post-collisional mantle dynamics during Variscan orogeny in the Bohemian Massif

    Kubínová, Šárka; Faryad, Shah Wali; Verner, Kryštof; Schmitz, Mark; Holub, František


    We report mineral textures, geochemistry and age relations of two ultrapotassic dykes from a dyke swarm in the Western part of the Moldanubian Zone at contact to the Teplá-Barrandian Block. The dykes have orientation almost perpendicular to the NNE-SSW trending Central Bohemian plutonic complex and cross cut metamorphic foliation in basement gneisses and migmatites. Based on mineral compositions and geochemistry, the dykes show close relations to Mg-K syenite plutons in the Moldanubian Zone. The two dykes are vaugnerite and syenite in compositions and contain talc pseudomorphs after olivine within a fine-grained matrix that consists of K-feldspar, phlogopite with small amounts of clinopyroxene and accessory quartz, apatite, titanite and sulphides of Fe, Cu, Ni. The syenite porphyry dyke cross cuts the vaugnerite. It contains quartz phenocrysts and comparing to vaugnerite has lower modal content of talc pseudomorphs. The vaugnerite and syenite porphyry have high K2O (6 to 7 wt.%) and mg-number (0.66-0.74), but low CaO and Na2O contents. The vaugnerite is markedly rich in P2O5 (> 2 wt.%) and comparing to syenite porphyry has higher amount of mantle-incompatible elements (e.g. Rb, Cs, Ba, Pb, Th, U), V and Cr. ID-TIMS analyses on titanite in vaugnerite and on zircon in syenite porphyry yielded 338.59 ± 0.68 and 337.87 ± 0.21 Ma, respectively. Mineral and bulk rock chemistry of the dykes indicates that the source magma was formed by a low degree of partial melting of a highly anomalous domain in the upper mantle which subsequently fractionated and was contaminated with crustal material during its ascent. Formation of ultrapotassic magma is explained by transcurrent shear zones in the mantle lithosphere that occurred due to block rotation and post-collisional mantle dynamics initiated by slab break-off and asthenosphere upwelling into the Moldanubian accretionary complex during the Variscan Orogeny.

  9. Magmatism and metamorphism at the sheeted dyke-gabbro transition zone: new insight from beerbachite from ODP/IODP Hole 1256D and Oman ophiolite

    Python, Marie; Abily, Bénédicte; France, Lydéric


    During IODP Expedition 335, two-pyroxenes bearing granulites (beerbachites) were extensively recovered as drilling cuttings at the gabbro-sheeted dyke transition zone of ODP Hole 1256D (East Pacific Rise, 6°44.163'N, 91°56.061'W). This lithology results from high-temperature metamorphism of previously hydrothermally altered diabases, basalts and/or gabbros; the heat source likely stems from the melt lens located at the top of the magmatic chambers imaged along present-day fast-spreading ridges. This lithology, associated with gabbroic bodies, characterises the transition zone between the sheeted dyke complex and the uppermost gabbroic section and represents the interface between magmatic and hydrothermal convecting systems in an oceanic crust formed at fast-spreading ridges. Samples acquired during IODP Exp. 335 show a particularly high degree of recrystallisation and are characterised by the absence of hydrous phases like amphibole, suggesting very high-T metamorphism. The Beerbachites mineral chemical characteristics are rather homogeneous compared to gabbros or dolerite from the sheeted dyke but pyroxenes Mg#, Ti, Al and Cr contents as well as the anorthite content of plagioclase are closer to gabbro than dolerite. This similarity may be explained by two hypothesis: either beerbachites in Hole 1256D are metamorphosed gabbros, or they underwent a melt-rock reaction process with the gabbros parental magma and were re-equilibrated at high temperature until their mineral composition become similar to that of gabbros. The gabbro-sheeted dyke transition zone in the Oman ophiolite is also outlined by the presence of high grade metamorphic rocks. Fine grained granulites and amphibolites that may be derived from the transformation of altered sheeted dyke diabases are in direct contact with fresh gabbroic and troctolitic bodies which are themselves cross-cut by dolerite dykes. The observation of textures show that high-T recrystallisation occurred in the fine grained

  10. Palaeomagnetism of Precambrian dyke swarms in the North China Shield: The ˜1.8 Ga LIP event and crustal consolidation in late Palaeoproterozoic times

    Piper, John D. A.; Jiasheng, Zhang; Huang, Baochung; Roberts, Andrew P.


    The North China Shield (NCS) is cut by a laterally-extensive dyke swarm emplaced at 1.78-1.76 Ga when an extensional regime succeeded regional metamorphism and completion of cratonisation by ˜1.85 Ga. Palaeomagnetic study of these dykes and adjoining metamorphic country rocks identifies a dominant shallow axis comprising a contiguous population with NE to N declinations and rare opposite polarity. Dykes with NE shallow magnetic declination (A1, D/ I = 36/-1°) recognised from previous study and emplaced in granulite terranes in the north are displaced by more northerly declinations (A2, D/ I = 8/2°) in lower grade metamorphic terranes to the south. Contact tests indicate a primary cooling-related origin to these magnetisations although tests are in part ambiguous because magnetisations in the granulite basement are comparable. Petrologic and rock magnetic considerations imply that magnetisation of the dykes occurred during uplift from depths as deep as 20 km following the peak of metamorphism at ˜1.85 Ga. A temporal migration A2 → A1 is implied by the higher crustal level and earlier acquisition of the former, and the deeper source and later acquisition of the latter. A third population of dyke magnetisations (A3, D/ I = 18/43°) is distributed towards steeper inclinations and close to the Mesozoic-Recent palaeofield. These are either partial or complete overprints of A1-A2 magnetisations with greater degrees of alteration indicated by demagnetisation and thermomagenetic spectra, or are much younger dykes of Mesozoic-Tertiary age. A minority fourth (later Precambrian but presently undated) dual polarity population has a magnetisation (11 dykes, D/ I = 108/7°) with contact tests indicating a primary cooling-related origin. The ˜1.78-1.76 Ga time of emplacement of the dominant dyke swarms in this study is widely represented by contemporaneous igneous rocks in other major shields linked to major Large Igneous Province (LIP)-related events. The new definition of

  11. Impacts of dyke development in flood prone areas in the Vietnamese Mekong Delta to downstream flood hazard

    Khanh Triet Nguyen, Van; Dung Nguyen, Viet; Fujii, Hideto; Kummu, Matti; Merz, Bruno; Apel, Heiko


    The Vietnamese Mekong Delta (VMD) plays an important role in food security and socio-economic development of the country. Being a low-lying coastal region, the VMD is particularly susceptible to both riverine and tidal floods, which provide, on (the) one hand, the basis for the rich agricultural production and the livelihood of the people, but on the other hand pose a considerable hazard depending on the severity of the floods. But despite of potentially hazardous flood, the area remain active as a rice granary due to its nutrient-rich soils and sediment input, and dense waterways, canals and the long standing experience of the population living with floods. In response to both farmers' requests and governmental plans, the construction of flood protection infrastructure in the delta progressed rapidly in the last twenty years, notably at areas prone to deep flooding, i.e. the Plain of Reeds (PoR) and Long Xuyen Quadrangle (LXQ). Triple rice cropping becomes possible in farmlands enclosed by "full-dykes", i.e. dykes strong and high enough to prevent flooding of the flood plains for most of the floods. In these protected flood plains rice can be grown even during the peak flood period (September to November). However, little is known about the possibly (and already alleged) negative impacts of this fully flood protection measure to downstream areas. This study aims at quantifying how the flood regime in the lower part of the VMD (e.g. Can Tho, My Thuan, …) has been changed in the last 2 recent "big flood" events of 2000 and 2011 due to the construction of the full-dyke system in the upper part. First, an evaluation of 35 years of daily water level data was performed in order to detect trends at key gauging stations: Kratie: upper boundary of the Delta, Tan Chau and Chau Doc: areas with full-dyke construction, Can Tho and My Thuan: downstream. Results from the Mann-Kendall (MK) test show a decreasing trend of the annual maximum water level at 3 stations Kratie, Tan

  12. Parental magma of the Skaergaard intrusion: constraints from melt inclusions in primitive troctolite blocks and FG-1 dykes

    J. K. Jakobsen; C. Tegner; C. K. Brooks; A. J. R. Kent; C.-E. Lesher; T.F.D. Nielsen; Michael Wiedenbeck


    Troctolite blocks with compositions akin to the Hidden Zone are exposed in a tholeiitic dyke cutting across the Skaergaard intrusion, East Greenland. Plagioclase in these blocks contains finely crystallised melt inclusions that we have homogenised to constrain the parental magma to 47.4–49.0 wt.% SiO2, 13.4–14.9 wt.% Al2O3 and 10.7–14.1 wt.% FeOT. These compositions are lower in FeOT and higher in SiO2 than previous estimates and have distinct La/SmN and Dy/YbN ratios that link them to the lo...

  13. Petrogenesis of Mesoproterozoic lamproite dykes from the Garledinne (Banganapalle) cluster, south-western Cuddapah Basin, southern India

    Rao, N. V. Chalapathi; Atiullah; Kumar, Alok; Sahoo, Samarendra; Nanda, Purnendu; Chahong, Ngazimpi; Lehmann, B.; Rao, K. V. S.


    We report mineral chemistry and whole-rock major and trace-element geochemistry for a recent find of Mesoproterozoic (~1.4 Ga) lamproites from the Garledinne (Banganapalle) cluster, south-western part of the Paleo-Mesoproterozoic Cuddapah Basin, southern India. The Garledinne lamproites occur as WNW-ESE-trending dykes that have undergone varying degree of pervasive silicification and carbonate alteration. Nevertheless, their overall texture and relict mineralogy remain intact and provide important insights into the nature of their magmas. The lamproite dykes have porphyritic to weakly porphyritic textures comprising pseudomorphed olivine macrocrysts and microphenocrysts, titanian phlogopite microphenocrysts, spinel having a compositional range from chromite to rarely magnesiochromite, Sr-rich apatite and niobian rutile. The Garledinne and other Cuddapah Basin lamproites (Chelima and Zangamarajupalle) collectively lack sanidine, clinopyroxene, potassic richterite, and titanite and are thus mineralogically distinct from the nearby Mesoproterozoic lamproites (Krishna and Ramadugu) in the Eastern Dharwar Craton, southern India. The strong correlation between various major and trace elements coupled with high abundances of incompatible and compatible trace elements imply that alteration and crustal contamination have had a limited effect on the whole-rock geochemistry (apart from K2O and CaO) of the Garledinne lamproites and that olivine fractionation played an important role in their evolution. The Garledinne lamproites represent small-degree partial melts derived from a refractory (previously melt extracted) peridotitic mantle source that was subsequently metasomatised (enriched) by carbonate-rich fluids/melts within the garnet stability field. The involvement of multiple reservoirs (sub-continental lithospheric mantle and asthenosphere) has been inferred in their genesis. The emplacement of the Garledinne lamproites is linked to extensional events, across the various

  14. Isotopic and trace element geochemistry of alkalic-mafic-ultramafic-carbonatitic complexes and flood basalts in NE India: Origin in a heterogeneous Kerguelen plume

    Ghatak, Arundhuti; Basu, Asish R.


    The Archean East Indian cratonic margin was affected by the Kerguelen plume (KP) ˜117 Ma, causing flood-basalt eruptions of the Rajmahal-Bengal-Sylhet Traps (RBST). The RBST cover ˜one million km2 in and around the Bengal Basin as alkalic-ultrabasic intrusives in the west and Sikkim in the north, and Sylhet basalts and alkalic-carbonatitic-ultramafic complexes in the Shillong plateau - Mikir hills farther east of the Rajmahal-Bengal Traps. We provide new Nd-Sr-Pb-isotopic and trace element data on 21 unreported discrete lava flows of the Rajmahal Traps, 56 alkalic-carbonatitic-mafic-ultramafic rocks from four alkalic complexes, and three dikes from the Gondwana Bokaro coalfields, all belonging to the RBST. The data allow geochemical correlation of the RBST with some contemporaneous Kerguelen Plateau basalts and KP-related volcanics in the southern Indian Ocean. Specifically, the new data show similarity with previous data of Rajmahal group I-II basalts, Sylhet Traps, Bunbury basalts, and lavas from the southern Kerguelen Plateau, indicating a relatively primitive KP source, estimated as: ɛNd(I) = +2, 87Sr/86Sr(I) = 0.7046, with a nearly flat time-integrated rare earth element (REE) pattern. We model the origin of the uncontaminated RBST basalts by ˜18% batch melting with a 2× chondritic KP source in the spinel-peridotite stability depths of 60-70 km in the mantle. The new geochemical data similar to the Rajmahal group II basalts indicate a light REE enriched average source at ɛNd(I) = -5, 87Sr/86Sr(I) = 0.7069. Our geochemical modeling indicates these lavas assimilated granulites of the Eastern Ghats, reducing the thickness of the continental Indian lithosphere. Lack of an asthenospheric MORB component in the RBST province is indicated by various trace element ratios as well as the Nd-Sr isotopic ratios. Three alkalic complexes, Sung, Samchampi, and Barpung in NE India, and one in Sikkim to the north are of two groups: carbonatites, pyroxenites, lamproites

  15. Timing, mantle source and origin of mafic dykes within the gravity anomaly belt of the Taihang-Da Hinggan gravity lineament, central North China Craton

    Liu, Shen; Feng, Caixia; Feng, Guangying; Xu, Mengjing; Coulson, Ian M.; Guo, Xiaolei; Guo, Zhuang; Peng, Hao; Feng, Qiang


    Six mafic dyke swarms crop out in Hebei Province within the Taihang-Da Hinggan gravity lineament magmatic belt, China, and were sampled. Here, we present new zircon laser ablation-inductively coupled plasma-mass spectrometry U-Pb age, whole rock geochemical, and Sr-Nd-Pb-Hf isotopic data for the six areas where these mafic dykes occur. The mafic (dolerite) dykes formed between 131.6 ± 1.6 and 121.6 ± 1.1 Ma, and are enriched in the light rare earth elements (LREE), some of the large ion lithophile elements (LILE; e.g., Rb, Ba, and Sr) and Pb, and are depleted in Th, U, Nb and Ta; some samples are also depleted in Eu. The dykes have high initial 87Sr/86Sr ratios (0.7055-0.7057), negative εNd (t) values (-12.5 to -11.9), relatively constant Pb isotopic ratios ((206Pb/204Pb)i = 16.45-16.51, (207Pb/204Pb)i = 15.44-15.51, (208Pb/204Pb)i = 36.49-36.53), negative εHf (t) values (-18.2 to -15.1), and old Nd (TNdDM2; 2.17-2.47 Ga) and Hf (THfDM2; 2.28-2.33 Ga) model ages. These geochronological, geochemical, and isotopic data indicate that the dykes were derived from magmas generated by low to moderate degree partial melting (1.0%-10%) of an EM1-like garnet lherzolite mantle source; these magmas fractionated olivine, clinopyroxene, and hornblende prior to emplacement, and assimilated minimal amounts of crustal material. Several possible models have previously been proposed to explain the origin of Mesozoic magmatism in this region. However, here we propose a foundering model for these studied mafic dykes, involving the foundering of eclogite from thickened lower crust due to the collision between the Siberian Craton and the North China Craon.

  16. Petrogenesis and tectonic implications of the Neoproterozoic Datian mafic-ultramafic dykes in the Panzhihua area, western Yangtze Block, SW China

    Yang, Yi-Jin; Zhu, Wei-Guang; Bai, Zhong-Jie; Zhong, Hong; Ye, Xian-Tao; Fan, Hong-Peng


    Mafic-ultramafic dykes are important geological markers that can punctuate the onset of crustal extension during the breakup of a continent and provide valuable information on the mantle source. This study reports secondary ion mass spectroscopy zircon and baddeleyite U-Pb ages, elemental and Nd isotopic data for the Datian mafic-ultramafic dykes in the Panzhihua area, western Yangtze Block, SW China. Two kinds of rocks are confirmed: the picritic rock and the dolerite. Based on petrographic and geochemical features, the dolerite dykes are further subdivided into two groups: Group I mafic and Group II mafic dykes, which emplaced at 760 Ma (zircon U-Pb) and 800 Ma (zircon and baddeleyite U-Pb), respectively. All samples from the picritic rocks and the Group I mafic rocks show the features of high-Ti and alkaline basaltic magma in composition as well as "humped" trace element patterns, which are similar to those of typical alkaline basalts associated with continental rifts except for the slightly negative Nb-Ta anomalies. The Group II mafic rocks display the features of low-Ti and tholeiitic magma, moderately enriched in LILE and LREE, and characterized by distinctively negative Nb-Ta anomalies. The primary magmas of the picritic rocks and the Group I mafic rocks were generated from ca 25 % partial melting of an OIB-like, Nd isotopically depleted but incompatible elements relatively enriched mantle source within a garnet stable field. The Group II mafic rocks crystallized from crustal contaminated mafic magmas that were derived from a spinel-bearing sub-continental lithospheric mantle source, because of low ratios of La/Yb, Ti/Y and Sm/Yb. Geochemical features suggest that these groups of mafic-ultramafic dykes were formed in a continental rift setting, but derived from different mantle sources. In combination with other Neoproterozoic igneous rocks in the western margin of Yangtze Block, it is suggested that the Datian mafic-ultramafic dykes in the Panzhihua area

  17. Mineralogy and petrology of leucite ankaratrites with affinities to kamafugites and carbonatites from the Kayıköy area, Isparta, SW Anatolia, Turkey: Implications for the influences of carbonatite metasomatism into the parental mantle sources of silica-undersaturated potassic magmas

    Caran, Şemsettin


    In the Kayıköy area of Isparta-Gölcük district, Inner Isparta Angle, SW Anatolia, Turkey, a small volume of newly discovered K-rich mafic potassic magma was emplaced in the form of dome in the vicinity of graben structures under Pliocene (3.68 ± 0.5 Ma) extensional tectonics. Kayıköy leucite ankaratrites are made up of abundant diopside, barian phlogopite and leucite, and lesser olivine, that rarely contains Cr-spinel, nepheline and haüyne, with abundant magnetite. They have low SiO2 (44.00-46.04 wt.%) and Al2O3 (12.10-12.64 wt.%) with high K2O (4.00-4.42 wt.%), CaO (13.50-14.40 wt.%) and MgO (8.52-9.36 wt.%), with high Cr (397-547 ppm) and moderate Ni (57-74 ppm) contents. They represent the less evolved silica-undersaturated mafic potassic magmas within the Isparta-Gölcük volcanic province, and may be considered another parental source to the wide spectrum of the K-rich rocks. They are highly enriched in most of the incompatible elements (e.g., Ba, 2761 to > 10,000 ppm; Sr, 3700-4074 ppm; Th, 33.60-36.99 ppm; Zr, 274-321 ppm) with high LREEs, low HREEs and elevated LREEs/HREEs ratios [(La/Yb)N, 73-80] and are comparable with kamafugite and carbonatites. Trace element patterns have negative P, Ti and Nb-Ta anomalies in common with the Italian kamafugite province and lack of a Eu anomaly, in contrast to the negative Eu anomaly of the Italian province. Their Sr87/86-Nd143/144 (0.703877-0.512765) isotopic compositions, together with those of other potassic volcanics from the Inner Isparta Angle, coincide with the West Quinling (China) kamafugites with highly depleted mantle signatures, and young East African carbonatites. Olivine-Cr-spinel pairs, high Mg# (0.69-0.73) numbers and Cr values, and high incompatible and LREE contents in Kayıköy leucite ankaratritic magma are consistent with near-primary magmas equilibrated with enriched and heterogeneous (peridotitic/pyroxenitic) mantle sources. On the basis of (i) their geochemical signatures [low Ti

  18. Petrological and geochemical constraints on the origin of mafic dykes intruding the composite Kaçkar Pluton from the eastern Blacksea magmatic arc, NE Turkey

    Aydin, Faruk; Oguz, Simge; Baser, Rasim; Uysal, Ibrahim; Sen, Cüneyt; Karsli, Orhan; Kandemir, Raif


    Geological, petrographical and geochemical data of mafic dykes intruding the composite Kaçkar Pluton from the eastern Blacksea magmatic arc (EBMA), NE Turkey, provide new insights into the nature of the metasomatizing agents in subcontinental lithospheric mantle beneath the region during the late Mesozoic-early Tertiary. Mafic dykes from the Çaykara and Hayrat (Trabzon), and also Ikizdere (Rize) areas from the northern margin of the EBMA consist of basalts, dolerites, lamprophyres (basic member) and lesser basaltic andesites and trachyandesites (evolved member). All dykes have no deformation and metamorphism. The outcrops of these dykes vary, with thickness from 0.2 to 10 m. and visible length from 3 to 20 m. In general, the mafic dykes dip steeply and cut directly across the Kaçkar Pluton, and show NW- and NE-trending, roughly parallel to the orientations of the EBMA main faults. Most of the dyke samples display subaphyric to porphyritic texture with phenocrysts of plagioclase (up to 10%), clinopyroxene (5-20%), amphibole (5-15%), and some contain variable amount of biotite (5-20%), lesser quartz (1-2%), and minor euhedral zircon, apatite and Fe-Ti oxides. The basic members of the mafic dykes have SiO2 of 44.1-51.9%, MgO of 4.5-12.1%, and TiO2 >mostly 0.8% (up to 2.3%) with K2O+Na2O of 1.3-6.6% with mostly subalkaline character. They are relatively high in mg-number (0.45-0.73) and transition metals (V=171-376 ppm, Co=22-45 ppm, Ni=3-148 ppm, and Sc=21-49 ppm). The evolved members of the dykes exhibit relatively higher SiO2 (57.1-60.2%) and K2O+Na2O (5.6-9.0%), and lower MgO (2.2-5.9%) and TiO2 (0.5-0.8%) contents than those from the basic dykes. Also, these samples have slightly low mg-number (0.41-0.65) and transition metals (V=99-172 ppm, Co=9-22 ppm, Ni=1-43 ppm, and Sc=9-20 ppm). In the Harker diagrams, all samples of the mafic dykes form a continuous array, and exhibit similar geochemical characteristics. In general, SiO2 inversely correlates with MgO, Fe

  19. Contribution of the FUTUREVOLC project to the study of segmented lateral dyke growth in the 2014 rifting event at Bárðarbunga volcanic system, Iceland

    Sigmundsson, Freysteinn; Hooper, Andrew; Hreinsdóttir, Sigrún; Vogfjörd, Kristín S.; Ófeigsson, Benedikt; Rafn Heimisson, Elías; Dumont, Stéphanie; Parks, Michelle; Spaans, Karsten; Guðmundsson, Gunnar B.; Drouin, Vincent; Árnadóttir, Thóra; Jónsdóttir, Kristín; Gudmundsson, Magnús T.; Samsonov, Sergey; Brandsdóttir, Bryndís; White, Robert S.; Ágústsdóttir, Thorbjörg; Björnsson, Helgi; Bean, Christopher J.


    The FUTUREVOLC project (a 26-partner project funded by FP7 Environment Programme of the European Commission, addressing topic "Long-term monitoring experiment in geologically active regions of Europe prone to natural hazards: the Supersite concept) set aims to (i) establish an innovative volcano monitoring system and strategy, (ii) develop new methods for near real-time integration of multi-parametric datasets, (iii) apply a seamless transdisciplinary approach to further scientific understanding of magmatic processes, and (iv) to improve delivery, quality and timeliness of transdisciplinary information from monitoring scientists to civil protection. The project duration is 1 October 2012 - 31 March 2016. Unrest and volcanic activity since August 2014 at one of the focus areas of the project in Iceland, at the Bárðarbunga volcanic system, near the middle of the project duration, has offered unique opportunities for this project. On 16 August 2014 an intense seismic swarm started in Bárðarbunga, the beginning of a major volcano-tectonic rifting event forming over 45 km long dyke extending from the caldera to Holuhraun lava field outside the northern margin of Vatnajökull. A large basaltic, effusive fissure eruption began in Holuhraun on 31 August which had by January formed a lava field with a volume in excess of one cubic kilometre. We document how the FUTUREVOLC project has contributed to the study and response to the subsurface dyke formation, through increased seismic and geodetic coverage and joint interpreation of the data. The dyke intrusion in the Bárðarbunga volcanic system, grew laterally for over 45 km at a variable rate, with an influence of topography on the direction of propagation. Barriers at the ends of each segment were overcome by the build-up of pressure in the dyke end; then a new segment formed and dyke lengthening temporarily peaked. The dyke evolution, which occurred over 14 days, was revealed by propagating seismicity, ground

  20. Platinum-group element concentrations in pyrite from the Main Sulfide Zone of the Great Dyke of Zimbabwe

    Piña, R.; Gervilla, F.; Barnes, S.-J.; Oberthür, T.; Lunar, R.


    The Main Sulfide Zone (MSZ) of the Great Dyke of Zimbabwe hosts the world's second largest resource of platinum-group elements (PGE) after the Bushveld Complex in South Africa. The sulfide assemblage of the MSZ comprises pyrrhotite, pentlandite, chalcopyrite, and minor pyrite. Recently, several studies have observed in a number of Ni-Cu-PGE ore deposits that pyrite may host significant amounts of PGE, particularly Pt and Rh. In this study, we have determined PGE and other trace element contents in pyrite from the Hartley, Ngezi, Unki, and Mimosa mines of the Great Dyke by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Based on the textures and PGE contents, two types of pyrite can be differentiated. Py1 occurs as individual euhedral or subhedral grains or clusters of crystals mostly within chalcopyrite and pentlandite, in some cases in the form of symplectitic intergrowths, and is PGE rich (up to 99 ppm Pt and 61 ppm Rh; 1.7 to 47.1 ppm Ru, 0.1 to 7.8 ppm Os, and 1.2 to 20.2 ppm Ir). Py2 occurs as small individual euhedral or subhedral crystals within pyrrhotite, pentlandite, and less frequently within chalcopyrite and silicates and has low PGE contents (<0.11 ppm Pt, <0.34 ppm Rh, <2.5 ppm Ru, <0.37 ppm Ir, and <0.40 ppm Os). Py1 contains higher Os, Ir, Ru, Rh, and Pt contents than the associated pyrrhotite, pentlandite, and chalcopyrite, whereas Py2 has similar PGE contents as coexisting pyrrhotite and pentlandite. Based on the textural relationships, two different origins are attributed for each pyrite type. Py1 intergrowth with pentlandite and chalcopyrite is inferred to have formed by late, low temperature (<300 °C) decomposition of residual Ni-rich monosulfide solid solution, whereas Py2 is suggested to have formed by replacement of pyrrhotite and pentlandite caused by late magmatic/hydrothermal fluids.

  1. Late Archaean mantle metasomatism below eastern Indian craton: Evidence from trace elements, REE geochemistry and Sr-Nd-O isotope systematics of ultramafic dykes

    Abhijit Roy; A Sarkar; S Jeyakumar; S K Aggrawal; M Ebihara; H Satoh


    Trace, rare earth elements (REE), Rb-Sr, Sm-Nd and O isotope studies have been carried out on ultramafic (harzburgite and lherzolite) dykes belonging to the newer dolerite dyke swarms of eastern Indian craton. The dyke swarms were earlier considered to be the youngest mafic magmatic activity in this region having ages not older than middle to late Proterozoic. The study indicates that the ultramafic members of these swarms are in fact of late Archaean age (Rb-Sr isochron age 2613 ± 177 Ma, Sri ∼0.702 ± 0.004) which attests that out of all the cratonic blocks of India, eastern Indian craton experienced earliest stabilization event. Primitive mantle normalized trace element plots of these dykes display enrichment in large ion lithophile elements (LILE), pronounced Ba, Nb and Sr depletions but very high concentrations of Cr and Ni. Chondrite normalised REE plots exhibit light REE (LREE) enrichment with nearly flat heavy REE (HREE; ( HREE)N ∼ 2-3 times chondrite, (Gd/Yb)N∼1). The Nd(t) values vary from +1.23 to −3.27 whereas 18O values vary from +3.16‰ to +5.29‰ (average +3.97‰ ± 0.75‰) which is lighter than the average mantle value. Isotopic, trace and REE data together indicate that during 2.6 Ga the nearly primitive mantle below the eastern Indian Craton was metasomatised by the fluid (±silicate melt) coming out from the subducting early crust resulting in LILE and LREE enriched, Nb depleted, variable Nd, low Sri(0.702) and low 18O bearing EMI type mantle. Magmatic blobs of this metasomatised mantle were subsequently emplaced in deeper levels of the granitic crust which possibly originated due to the same thermal pulse.

  2. Gamma-ray and electrical resistivity measurements in soil with application of carbonatite and agricultural fertilizers in Distrito Federal; Radiacao gama e resistividade eletrica em solo com aplicacao de carbonatito e fertilizantes agricolas no Distrito Federal

    Nascimento, Carlos Tadeu Carvalho do; Gaspar, Jose Carlos; Pires, Augusto Cesar Bittencourt, E-mail:, E-mail:, E-mail: [Instituto de Geociencias, Universidade de Brasilia, DF (Brazil); Ferreira, Francisco Jose Fonseca, E-mail: [Departamento de Geologia, Universidade Federal do Parana, Curitiba, PR (Brazil); Andrade, Leide Rovenia Miranda de, E-mail: [Empresa Brasileira de Pesquisa Agropecuaria, Centro de Pesquisa Agropecuaria dos Cerrados, Planaltina, DF (Brazil)


    EMBRAPA (Empresa Brasileira de Pesquisa Agropecuaria) and Brasilia University developed a research project about the viability of carbonatite rock as agricultural fertilizer. As an initial experiment, several mixtures of carbonatite, limestone, phosphorous and potassium compounds were added as fertilizers in an oxisol area (red-latosol, according with Brazilian System of Soil Classification), in Distrito Federal, central Brazil. The experiment area was divided in 56 plots (4 x 7m) and each plot received a fertilizer mixture. The purpose of this work was to verify if the addition of fertilizer mixture to the soil modified its radiometric and resistivity properties and if it is possible to identify this change. Gamma-ray and electrical resistivity measurements were obtained in an experimental area and in a natural savannah type vegetation area. The results showed that the fertilizer addition modified soil natural properties causing a small increase in K, U, Th levels and decreasing ten times electrical resistivity. A low contrast of radiation was observed between plots, and then it was not possible to differentiate the several treatments in base of gamma-ray measurements. Electrical resistivity was efficient to identify three groups of plots related to mixtures characteristics, respectively with phosphorous, potassium and limestone / carbonatite predominance. (author)

  3. The Importance of Sampling Strategies on AMS Determination of Dykes II. Further Examples from the Kapaa Quarry, Koolau Volcano, Oahu, Hawaii

    Mendoza-Borunda, R.; Herrero-Bervera, E.; Canon-Tapia, E.


    Recent work has suggested the convenience of dyke sampling along several profiles parallel and perpendicular to its walls to increase the probability of determining a geologically significant magma flow direction using anisotropy of magnetic susceptibility (AMS) measurements. For this work, we have resampled in great detail some dykes from the Kapaa Quarry, Koolau Volcano in Oahu Hawaii, comparing the results of a more detailed sampling scheme with those obtained previously with a traditional sampling scheme. In addition to the AMS results we will show magnetic properties, including magnetic grain sizes, Curie points and AMS measured at two different frequencies on a new MFK1-FA Spinner Kappabridge. Our results thus far provide further empirical evidence supporting the occurrence of a definite cyclic fabric acquisition during the emplacement of at least some of the dykes. This cyclic behavior can be captured using the new sampling scheme, but might be easily overlooked if the simple, more traditional sampling scheme is used. Consequently, previous claims concerning the advantages of adopting a more complex sampling scheme are justified since this approach can serve to reduce the uncertainty in the interpretation of AMS results.

  4. Populations of Rice Grain Bug, Paraeuscosmetus pallicomis, (Hemiptera: Lygaeidae) in Weed-free Paddy Field, Weedy Paddy Field and Paddy Dykes.

    Abdullah, Tamrin; Nasruddin, Andi; Agus, Nurariaty


    Research on the populations of rice grain bug Paraeuscosmetus pallicomis Dallas (Hemiptera: Lygaeidae) in paddy field ecosystems was performed with the aim to determine the populations of rice grain bug in weed-free paddy field, weedy paddy field, and paddy dykes. Experiment was carried out in the village of Paccellekang in the district of Patallasang of Gowa Regency in South Sulawesi, Indonesia. Observations were performed during the milky grain stage (85 days after planting), the mature grain stage (105 days after planting), and one day after harvest (115 days after transplanting). Results showed that 85 days after the transplanting, the populations of rice grain bug was significantly higher in the weedy paddy field compared to weed-free field and paddy dykes with total numbers of 1.75, 3.53, and 0.31 insects per 2 hills, respectively. Similarly, 105 days after the transplanting, 2.53, 5.53, and 0.11 insects per hill, respectively. However, one day after the harvest (115 days after transplanting) the number of insects in weed-free field decreased, while in the dykes increased, and the weedy plot still had the highest number of insects per 2 hills. Our results suggested that weeds played an important role in regulating the bug population by providing alternative shelter and foods for the insect.

  5. Petrology, geochemistry of hornblende gabbro and associated dolerite dyke of Paharpur, Puruliya, West Bengal: Implication for petrogenetic process and tectonic setting

    Aditi Mandal; Arijit Ray; Mayukhee Debnath; Sankar Prasad Paul


    Paharpur gabbroic intrusive is an arcuate body running east–west paralleling the foliation of Chhotanagpur Granite Gneiss which acts as country rock. The main gabbroic body is intruded by a number of dolerite dykes running north–south. It is composed of clinopyroxene (Wo48En40Fs12–Wo51En40Fs09, mg no. 72–82), plagioclase (An52–An90), hornblende (magnesian hornblende to ferro-tschermackite), orthopyroxene (En76–En79) and ilmenite. Hornblende occurs as large poikilitic grain and constitutes around 60% of the rock. Both gabbro and associated dolerite dykes, show relatively primitive character (mg no. 65–73). Primitive mantle-normalized and MORB-normalized spider diagrams indicate enrichment in Rb, Ba, Th, La, Sr and depletion in Nb, Zr, Y, Ti and Nd. The LILE enrichment and Nb, Ti, Zr, Y depletion suggest arc like geochemical signature for the gabbroic and doleritic rocks of Paharpur. Flat to slightly LREE fractionated pattern and variable degree of REE enrichment is observed. An early stage fractionation of clinopyroxene, plagioclase, orthopyroxene, ilmenite and late stage reaction of cumulate pile and evolved melt/hydrous fluid is suggested for magmatic evolution of gabbro. Associated dolerite dykes, which are geochemically similar to the gabbro, have tholeiitic with boninitic character. The mineralogical and chemical compositions of intrusive rocks also have some similarity with mafic rocks of ophiolite complex of subduction zone.

  6. New constraints on the geochronology and Sm-Nd isotopic characteristics of Bas-Drâa mafic dykes, Anti-Atlas of Morocco

    El Bahat, Abdelhakim; Ikenne, Moha; Cousens, Brian; Söderlund, Ulf; Ernst, Richard; Klausen, Martin B.; Youbi, Nasrrddine


    The Precambrian inliers of the Anti-Atlas belt across the southern part of Morocco contain numerous mafic dyke and sill swarms, which are thought to represent the erosional remnants of Proterozoic Large Igneous Provinces (LIPs). As part of an extended research campaign to date and characterize these LIPs, two amphiboles from one dyke within the Bas-Drâa inlier (western Anti-Atlas) yielded consistent 40Ar-39Ar ages of 611 Ma ± 1.3; i.e., evidence of magmatic activity during the Ediacaran (635-542 Ma). Furthermore, Nd isotope ratios and model ages identifies four groups of dykes within the Bas-Drâa inlier, all of which were derived from a previously enriched mantle reservoir with very low 143Nd/144Nd ratios (0.51065-0.51170) and corresponding εNd(t) values (-16.44 to -2.45). Such low Nd-ratios arguably reflect either a contribution of crustal components, such as the Paleoproterozoïc schisto-granitic basement, or metasomatic modification of the sub-continental lithospheric mantle.

  7. The role of dyking and fault control in the rapid onset of eruption at Chaitén Volcano, Chile

    Wicks, C.; De La, Llera; Lara, L.E.; Lowenstern, J.


    Rhyolite is the most viscous of liquid magmas, so it was surprising that on 2 May 2008 at Chaitén Volcano, located in Chile’s southern Andean volcanic zone, rhyolitic magma migrated from more than 5 km depth in less than 4 hours and erupted explosively with only two days of detected precursory seismic activity. The last major rhyolite eruption before that at Chaitén was the largest volcanic eruption in the twentieth century, at Novarupta volcano, Alaska, in 1912. Because of the historically rare and explosive nature of rhyolite eruptions and because of the surprisingly short warning before the eruption of the Chaitén volcano, any information about the workings of the magmatic system at Chaitén, and rhyolitic systems in general, is important from both the scientific and hazard perspectives. Here we present surface deformation data related to the Chaitén eruption based on radar interferometry observations from the Japan Aerospace Exploration Agency (JAXA) DAICHI (ALOS) satellite. The data on this explosive rhyolite eruption indicate that the rapid ascent of rhyolite occurred through dyking and that melt segregation and magma storage were controlled by existing faults.

  8. The role of dyking and fault control in the rapid onset of eruption at Chaitén volcano, Chile.

    Wicks, Charles; de la Llera, Juan Carlos; Lara, Luis E; Lowenstern, Jacob


    Rhyolite is the most viscous of liquid magmas, so it was surprising that on 2 May 2008 at Chaitén Volcano, located in Chile's southern Andean volcanic zone, rhyolitic magma migrated from more than 5 km depth in less than 4 hours (ref. 1) and erupted explosively with only two days of detected precursory seismic activity. The last major rhyolite eruption before that at Chaitén was the largest volcanic eruption in the twentieth century, at Novarupta volcano, Alaska, in 1912. Because of the historically rare and explosive nature of rhyolite eruptions and because of the surprisingly short warning before the eruption of the Chaitén volcano, any information about the workings of the magmatic system at Chaitén, and rhyolitic systems in general, is important from both the scientific and hazard perspectives. Here we present surface deformation data related to the Chaitén eruption based on radar interferometry observations from the Japan Aerospace Exploration Agency (JAXA) DAICHI (ALOS) satellite. The data on this explosive rhyolite eruption indicate that the rapid ascent of rhyolite occurred through dyking and that melt segregation and magma storage were controlled by existing faults.

  9. 2D and 3D analyses of bubbles and minerals in an Etnean dyke: Insights on turbulence (non-laminar) and solidification during magma ascent

    Lanzafame, Gabriele; Iezzi, Gianluca; Mancini, Lucia; Lezzi, Federica; Mollo, Silvio; Ferlito, Carmelo


    Laminar and turbulent regimes during magma uprise through the plumbing systems of several volcanoes in the world are generally predicted by numerical models. In this work, we investigated a trachybasaltic aphyric 4.3 m thick dyke solidified at shallow depth (100-300 m below the pristine surface level) at Mount Etna (Italy). Two- and three-dimensional imaging analyses have been conducted on bubbles and minerals, in order to attest the non-laminar characteristic of the intruding magma. Seven samples along a cross profile from dyke rim (DK1) to core (DK7) have been analysed by means of i) 2D techniques such as high-resolution scanner, transmission optical microscope and scanning electron microscope imaging with back-scattered electrons and ii) a 3D technique as microfocus X-ray computed tomography. Despite limited changes in textures and compositions of plagioclase, clinopyroxene, titanomagnetite, and olvine, the amount, size and shape of bubbles change irregularly from dyke rim to core. Bubble and plagioclase contents show opposite saw-like trends due to the solidification from different portions of a H2O-rich magma and vice-versa. Along the cross profile of the dyke, bubbles with anisotropic shapes (average aspects 3:1) are randomly oriented in space, with strong variations in abundance, size and shape. These features could be attributed to transitional to turbulent, i.e. non-laminar, regimes (Reynolds number > 1000). Models to constrain the intrusive conditions of the dyke indicate that the crystal-free magma containing 1 wt.% H2O intruded and rapidly solidified at depth > 100-300 m, i.e. P > 10 MPa. The sudden and marked crystallization was favoured by the rapid volatile exsolution at very shallow level, coupled with the increase of viscosity and deceleration (a few meters per seconds) or even stop of the magma uprise. The retrieved results indicate that bubbles were frozen in, whereas crystals continued to grow under the effect of an increasing cooling rate from

  10. Evidence for metasomatic mantle carbonatitic magma extrusion in Mesoproterozoic ore-hosting dolomite rocks in the middle Kunyang rift, central Yunnan, China


    The Kunyang rift lying on the western margin of the Yangtze platform is a rare Precambrian Fe-Cu mineralization zone. Wuding- Lufeng basin that is an important part of the zone is located on the west edge in the middle of the rift. The most important ore-hosting rocks are Mesoproterozoic dolomite rocks in the basin controlled by a ring fracture system, which is a fundamental structure of the basin. Plenty of silicate minerals and acicular apatite, feldspar phenocrysts and small vesicular, flown line and flown plane structures, melt inclusion and high temperature fluid inclusion found in most ore-hosting dolomites suggest that this kind of rocks could not be sedimentary dolomite, marble or hydrothermal carbonate rocks. The Zr/Hf and Nb/Ta values of the rocks are identical with those of associated mantle-derived rocks, and vary widely. For the monomineral dolomite, δ18OSMOW‰=+5.99 to +18.4 and δ13CPDB‰=-3.01to+0.94, which fall within the range for all carbonatitic volcanic rocks of the world. As for the accessory minerals, the values of δ18OSMOW‰ of magnetite (=+3.47 to +5.99%0) are close to that of the mantle (<5.7%), and the δ34S‰ values of sulfides (-5.09 to+5.78, averaging+1.50) are close to that of meteorite. For all the ore-bearing dolomite rocks, εNd = +0.19 to +2.27, and the calculated Isr = 0.699143, while for the associated mantle-derived rocks, εNd = +3.18 to +3.72. All the data suggest that the mineral assemblage is not only igneous but also of metasomatic mantle origin. And the presence of acicular apatite indicates that the rocks were formed by magma rapidly cooling. And the phenocryst texture and vesicular, flown and ropy and pyroclastic structures suggest that the igneous rocks were extrusive. Therefore, the ore-bearing dolomite rocks are carbonatitic volcanic rocks. This conclusion implies that most iron and copper ore deposits hosted in the dolomite rocks should be of the carbonatitc type.

  11. Temporal distribution of mantle-derived potassic rocks and carbonatites linked to stabilization of mantle lithosphere and redox states during subduction

    Foley, S. F.


    Mantle-derived potassic igneous rocks and carbonatites first appear in the geological record in the late Archean, coinciding with major crust-forming events on most continents. The compositions of potassic rocks require sources including discrete ultramafic rocks with phlogopite and pyroxenes, whereas carbonatites and ultramafic lamprophyres (carbonate-rich potassic rocks) require oxidizing conditions in which carbonate is stable. The presence of these source rocks from this time is probably related to the stabilization of mantle lithosphere. If mantle lithosphere had not been stable for considerable periods of time, then melting would be restricted to peridotite, which is not a viable option for strongly potassic rocks. The phlogopite-rich source-rock assemblages that are necessary precursors for potassic melts could be introduced into the lithosphere by either subduction processes or by multiple stages of low-degree melting. Many modern examples involve subducted sedimentary material, which concentrates potassium by the stabilization of micas in subduction metamorphism. Subduction involves a great variety of redox states, but the bulk effect is the return of oxidized material from the surface into the mantle. However, we cannot apply uniformitarianism unthinkingly, because subduction processes at and before 2.7 Ga may have had different redox states. Before the Great Oxidation Event the distribution and abundances of geological formations such as banded iron formations, red beds, and uraninites indicate that geological reservoirs became gradually oxidized, preventing an earlier increase in atmospheric oxygen. This means that the function of the subduction process to oxidize the upper mantle by the return of oxidized rocks from the surface was much weaker in the early Earth. Early continental mantle lithosphere was, therefore, likely to accumulate carbon in reduced form, which would be more easily remobilized in melts through low-temperature redox melting much

  12. Fluids in the Siilinjärvi carbonatite complex, eastern Finland: Fluid inclusion evidence for the formation conditions of zircon and apatite

    Poutiainen, M.


    Full Text Available In the studied zircon and apatite crystals, data recorded two different compositional types of fluid inclusions: Type 1 H2O-CO2, low salinity inclusions (XCO2 = 0.42 to 0.87; XNaCl = 0.001 to 0.005 with bulk densities of 0.73 to 0.87 g/cm3, and Type 2 H2O moderate salinity (XNaCl = 0.03 to 0.06 inclusions with densities of 0.83 to 1.02 g/cm3. The Type 1 inclusions are not present in apatite. In zircon, the observed fluid inclusion types occur in separate domains: around (Type 1 and outside (Type 2 the apparent core. Fluid inclusions are further subdivided into pseudosecondary and secondary inclusions. Using a combination of SEM-EDS, optical characteristics and crushing-stage, various daughter and captive minerals were identified. The fluid inclusion data suggest that the pseudosecondary Type 1 and Type 2 inclusions in zircon and apatite were trapped during the pre-emplacement evolution of the carbonatite at mid-crustal conditions (P≥4 kbar, T≥625°C. The Type 1 fluid was depleted in CO2, during crystal fractionation and cooling leading to a fluid phase enriched in water and alkalies. Fenitization was obviously induced by these saline aqueous fluids. During emplacement of the carbonatite to the present level, zircon phenocrysts were intensively fractured, some Type 1 inclusions were re-equilibrated, and multiphase Type 2 inclusions were trapped. It is assumed that all these inclusions in zircon and the pseudosecondary Type 2 inclusions in apatite have a magmatic origin. In apatite, calcite inclusions occur side-by-side with the secondary Type 2 inclusions. These calcites co-existed with the aqueous fluid during fracturing and metamorphic re-crystallization of apatites. Probably, this metamorphic fluid also is responsible for the transport and deposition of at least some of the calcite at low temperatures (200-350°C.

  13. Mafic sill/dykes intruding into late Maastrichtian-early Paleocene calciclastic units, NE-Turkey: Petrographical and geochemical features of latest magmatic activity before collision in the eastern Sakarya zone

    Aydin, Faruk; Oǧuz, Simge; Karsli, Orhan; Kandemir, Raif; Şen, Cüneyt; Uysal, İbrahim


    We present here new petrographical, mineralogical and whole-rock geochemical data for mafic sill/dykes intruding into late Maastrichtian-early Paleocene calciclastic units in the Düzköy (Trabzon) and Cankurtaran (Artvin) areas (NE Turkey) of the eastern Sakarya zone (ESZ) in order to decipher the latest magmatic activity in the final stage of subduction-related magmatism of the ESZ. U-Pb zircon dating for the mafic sill/dykes in the region yielded ages varying from 83.6 to 78.5Ma (i.e. Early Campanian). Mafic sill/dykes consist of mostly basalts and lesser basaltic-andesites with komatiitic basalts. Most of the dyke samples display aphyric to porphyritic texture with phenocrysts of plagioclase (mostly replaced by calcite), clinopyroxene (partly uralized), olivine (almost serpentinized), and amphibole (partly chloritized). Based on the MgO, Nb and Zr contents with Nb/Y ratio, the mafic dykes from Düzköy area are mainly classified as two subgroups (basalts and basaltic andesites) while those of Cankurtaran can be divided into three different groups (low- and high-Nb normal basalts and komatitic basalts). Düzköy basaltic dykes have higher MgO (3.8-7.8%) and lower Nb (3-4ppm) and Zr (53-62ppm) contents with Nb/Y ratio (˜0.2) than those of Düzköy basaltic-andesitic dykes (MgO: ˜1.8%, Nb: 6-15ppm, Zr: 106-145ppm, Nb/Y: 0.3-0.6). On the other hand, Cankurtaran mafic sill/dykes have relatively high MgO contents (˜4-20%). These sill/dykes with 15-20% of MgO and group 1 and 4.0-4.4% for group 2), Nb (3-14ppm for group 1 and 19-21ppm for group 2), Zr (94-111ppm for group 1 and 125-140ppm for group 2) contents, and Nb/Y ratio (˜0.2-0.8 for group 1 and (˜1.0-1.2 for group 2). Although the studied mafic sill/dykes have generally subalkaline composition, they show a geochemical character changing from mostly tholeiitic to rarely calc-alkaline and show typical features of late Cretaceous subduction-related magmatic rocks as in the ESZ. On the chondrite-normalized REE

  14. Geochronologic and geochemical constraints of the petrogenesis of Permian mafic dykes in the Wuding area, SW China: Implications for Fe-Ti enrichment in mafic rocks in the ELIP

    Fan, Hong-Peng; Zhu, Wei-Guang; Bai, Zhong-Jie; Yang, Yi-Jin


    Mafic dykes are widely distributed and well preserved in the Wuding area, SW China. The dykes are composed of fine-grained diabases, which are further subdivided into two groups (Group I and Group II). The rocks from Group I have relatively higher MgO (4.95-6.16 wt%) and lower TiO2 (2.26-2.78 wt%) contents than those from the Group II rocks (MgO = 4.04-4.58 wt%; TiO2 = 4.09-4.55 wt%). Two baddeleyite ages of 264 ± 3 Ma and 256 ± 5 Ma from the Wuding dykes suggest that the ages of these dykes are similar to the plutonic bodies and the associated volcanic rocks of the Emeishan large igneous province (ELIP). The compositions and isotopic signatures of the dykes are also similar to those of the ELIP volcanic rocks, indicating derivation from the same magmatic event at 260 Ma. The primary melts of the Wuding dykes were originated by partial melting of a long-term depleted OIB-like mantle source. The Group I dykes were mainly formed by wallrock assimilation and fractional crystallization processes. The magmas parental to the Group II rocks were much more evolved than the magma parental to the Group I rocks and probably produced by wallrock assimilation and fractional crystallization of the parent magma of the Group I rocks. The increasing enrichment of Fe and Ti from the Group I to the Group II rocks were attributed to a fractional crystallization process which may be an epitome of enrichment of Fe and Ti in the Fe-Ti rich mafic intrusions of the ELIP.

  15. Subglacial volcanic activity above a lateral dyke path during the 2014-2015 Bárdarbunga-Holuhraun rifting episode, Iceland

    Reynolds, Hannah I.; Gudmundsson, Magnús T.; Högnadóttir, Thórdís; Magnússon, Eyjólfur; Pálsson, Finnur


    The rifting episode associated with the Bárdarbunga-Holuhraun eruption in 2014-2015 included the first observations of major dyke propagation under ice. Three shallow ice depressions (ice cauldrons) with volumes ranging from 1 to 18 million m3 formed in Dyngjujökull glacier above the 48-km-long lateral path of the magma, at 4, 7 and 12 km from the northern glacier edge. Aircraft-based radar altimetry profiling was used to map the evolution of the cauldrons and construct a time series of the heat transfer rates. Out of the three scenarios explored: (1) onset or increase of hydrothermal activity, (2) convection within vertical fissures filled with water overlying intruded magma and (3) subglacial eruptions, the last option emerges as the only plausible mechanism to explain the rapid heat transfer observed in a location far from known geothermal areas. The thermal signals at two of the cauldrons are consistent with effusive subglacial eruptions. The formation of the northernmost cauldron was more rapid, indicating faster heat transfer rates. Radio-echo sounding data indicate that in contrast to the other two cauldrons, an intrusion of eruptive products occurred into the glacier, reaching 50-60 m above bedrock with the increased magma-ice contact explaining the more rapid heat transfer. We propose that the 2-m widening associated with graben formation increased the groundwater storage capacity of the bedrock, creating space for the meltwater to be stored, explaining the absence of meltwater pulses draining from Dyngjujökull.

  16. Electrical resistivity tomography investigations along the planned dykes of the HPP Brežice water accumulation basin

    Gorazd Rajh


    Full Text Available Geophysical investigations were conducted using electrical resistivity tomography (ERT along planned dykes of the HPP Brežice water accumulation basin. The ERT profile is 7.3 km long and is located on the right riverbank of the Sava River on the Kr{ko-Brežice field (E Slovenia. A purpose of the investigations was to determine a boundary between semipermeable Miocene and permeable Plio-Quaternary (Pl-Q and Quaternary (Q sediments for the proper design of the jet grouting sealing curtain, which will prevent lateral outflow of water from the accumulation basin. In this paper we present processing of the section between 5100 and 6100 m of the profile line. In this section the measurement template was set to 25 depth levels, because a significant increase in a thickness of the Pl-Q sediments was expected. Modelling of the measured apparent electrical resistivity data was carried out with RES2DINV and RESIX 2DI inversion software. Different inversion parameters were used to create 15 geoelectrical models for each program, which were then compared and evaluated based on borehole data and on previous geological investigations of the area. With the final geoelectrical models it was possible to successfully determine areas of three expected stratigraphic members and limit an electrical resistivity range for each one of them. The boundary is well defined between Q and Pl-Q and also between Q and Miocene sediments with sharp contrast in electrical resistivity between them. A boundary between Pl-Q and Miocene sediments was not that obvious, but it was possible to determine its shape by the use of different inversion parameters. We propose a simplified geological cross section based on the interpreted geoelectrical models and borehole data.

  17. A synthesis of mineralization styles with an integrated genetic model of carbonatite-syenite-hosted REE deposits in the Cenozoic Mianning-Dechang REE metallogenic belt, the eastern Tibetan Plateau, southwestern China

    Liu, Yan; Hou, Zengqian


    The Cenozoic Mianning-Dechang (MD) rare earth element (REE) belt in eastern Tibet is an important source of light REE in southwest China. The belt is 270 km long and 15 km wide. The total REE resources are >3 Mt of light rare earth oxides (REO), including 3.17 Mt of REO at Maoniuping (average grade = 2.95 wt.%), 81,556 t at Dalucao (average grade = 5.21 wt.%), 0.1 Mt at Muluozhai (average grade = 3.97 wt.%), and 5764 t of REO at Lizhuang (average grade = 2.38 wt.%). Recent results from detailed geological surveys, and studies of petrographic features, ore-forming ages, ore forming conditions, and wallrock alteration are synthesized in this paper. REE mineralization within this belt is associated with carbonatite-syenite complexes, with syenites occurring as stocks intruded by carbonatitic sills or dikes. The mineralization is present as complex vein systems that contain veinlet, stringer, stockwork, and brecciated pipe type mineralization. Carbonatites in these carbonatite-related REE deposits (CARDs) are extremely rich in light REEs, Sr (>5000 ppm), and Ba (>1000 ppm), and have low Sr/Ba and high Ba/Th ratios, and radiogenic Sr-Nd isotopic compositions. These fertile magmas, which may lead to the formation of REE deposits, were generated by the partial melting of sub-continental lithospheric mantle (SCLM) that was metasomatized by REE- and CO2-rich fluids derived from subducted marine sediments. We suggest that this refertilization occurred along cratonic margins and, in particular, at a convergent margin where small-volume carbonatitic melts ascended along trans-lithospheric faults and transported REEs into the overlying crust, leading to the formation of the CARDs. The formation of fertile carbonatites requires a thick lithosphere and/or high pressures (>25 kbar), a metasomatized and enriched mantle source, and favorable pathways for magma to ascend into the overlying crust where REE-rich fluids exsolve from cooling magma. The optimal combination of these three

  18. Integrated Approach (Geophysics and Remote Sensing) to identify Water-bearing Dyke Swarms and Fractured Basement in the Sinai Peninsula, Egypt

    Mohamed, L.; Sultan, M.; Ahmed, M. E.; Sauck, W.; Abouelmagd, A. A.; Chouinard, K.


    An integrated approach utilizing Very Low Frequency (VLF) and magnetic field surveying and temporal remote sensing data including: (1) Advanced Space Borne Thermal Emission and Reflection (ASTER) data, (2) European Remote Sensing (ERS-1 and ERS-2) radar imagery, and (3) Tropical Rainfall Measuring Mission (TRMM) was used to delineate water-bearing sub-vertical shear zones within the basement complex of the Sinai Peninsula. The following steps were undertaken: (1) the shear zones and dyke swarms within the basement complex were delineated using false color ASTER band and band ratio images; (2) the spatial and temporal precipitation events over the basement complex were then identified from TRMM data, and (3) finally, observations extracted from temporal radar and thermal ASTER bands were used to identify the water-bearing shear zones and dyke swarms. A fracture or dyke was deemed to be water bearing if: (1) it witnessed a large increase in its reflectivity and emissivity compared to its surroundings following a precipitation event, and maintained such differences for periods ranging from days to months. Field observations and VLF investigations were then applied to test the validity of our satellite-based methodologies for locating targeted aquifer types and for refining the satellite-based selections. The VLF detects conductive water-saturated subvertical breccia zones in bedrock. Thirty two VLF transects were collected in September of 2011 and July of 2012 along with 10 magnetic profiles at the same VLF locations. Both VLF and magnetic transects were acquired along a traverse perpendicular to the dike orientations with station separations ranging from 10 to 25 m. The VLF receiver (T-VLF) measures the distortion of the normally horizontal electromagnetic flux lines by local electrical conductors. At each VLF station, and for each frequency used, the following were measured: the tilt of the electromagnetic field, from the horizontal (given in percentage), the

  19. MR and CT imaging in the Dyke-Davidoff-Masson syndrome: report of three cases and contribution to pathogenesis and differential diagnosis



    Full Text Available Cerebral hemiatrophy or Dyke-Davidoff-Masson syndrome is a condition characterized by seizures, facial asymmetry, contralateral hemiplegia or hemiparesis, and mental retardation. These findings are due to cerebral injury that may occur early in life or in utero. The radiological features are unilateral loss of cerebral volume and associated compensatory bone alterations in the calvarium, like thickening, hyperpneumatization of the paranasal sinuses and mastoid cells and elevation of the petrous ridge. The authors describe three cases. Classical findings of the syndrome are present in variable degrees according to the extent of the brain injury. Pathogenesis is commented.

  20. Analysis of the deconstruction of Dyke Marsh, George Washington Memorial Parkway, Virginia-Progression, geologic and manmade causes, and effective restoration scenarios

    Litwin, Ronald J.; Smoot, Joseph P.; Pavich, Milan J.; Markewich, Helaine W.; Oberg, Erik; Helwig, Ben; Steury, Brent; Santucci, Vincent L.; Durika, Nancy J.; Rybicki, Nancy B.; Engelhardt, Katharina M.; Sanders, Geoffrey; Verardo, Stacey; Elmore, Andrew J.; Gilmer, Joseph


    This report is a synthesis of the latest findings from an ongoing study of Dyke Marsh, an eroding freshwater tidal wetland that is scheduled for federal restoration. Its purpose is to provide an accurate and up-to-date temporal and geological framework for the marsh, of which most is new information (plus a compilation of historical and recent information), that is directly relevant to the restoration effort and also is relevant to short-term and long-term land management decisions regarding this natural resource.

  1. Determination of rare-earths and other trace elements in neo proterozoic-neo paleozoic dykes from Ceara state, Brazil, by neutron activation analysis

    Anjos, Rafael Martins dos; Figueiredo, Ana M.G., E-mail: rafael.anjos@usp.b, E-mail: anamaria@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro do Reator Nuclear de Pesquisas. Lab. de Analise por Ativacao com Neutrons; Cardoso, Gustavo Luan; Marques, Leila S., E-mail: leila@iag.usp.b [Universidade de Sao Paulo (IAG/USP), SP (Brazil). Inst. de Astronomia, Geofisica e Ciencias Atmosfericas


    Trace elements such as rare earths, U, Th, Ta, Ba and Hf can be very useful in petrogenetic studies of igneous and metamorphic rocks, giving information about the origin and evolution of magmas. Instrumental Neutron Activation Analysis (INAA) is an accurate and precise for trace element analysis in geological samples, and provides the information required for this kind of studies. In this study, rare earths and incompatible trace elements were determined by INAA in the geological reference materials GS-N and BE-N, to quality control, and for the investigation of acid dykes of neo proterozoic-neo paleozoic ages, which outcrop in the Medio Coreau and Ceara Central domains from the Borborema Province (Ceara State). The powdered samples (particle sizes less than 100 mesh), crushed by using a mechanical agate mortar grinder, were irradiated at the IEA-R1 nuclear reactor at IPEN-CNEN/SP, and the induced activity was measured by high resolution gamma-ray spectrometry. The accuracy and precision of the method were evaluated and preliminary results of dyke samples are presented. (author)

  2. Variations in the chemical composition of lamprophyllite-group minerals and the crystal structure of fluorine-rich barytolamprophyllite from new peralkaline dyke

    Akimenko, M. I.; Aksenov, S. M.; Sorokhtina, N. V.; Kogarko, L. N.; Kononkova, N. N.; Rastsvetaeva, R. K.; Rozenberg, K. A.


    The variations in the chemical composition of lamprophyllite-group minerals from a peralkaline dyke of the Mokhnatye Roga area (Kandalaksha region, Kola Peninsula), which are crystallized during the entire period of dyke formation and form several generations, have been investigated. The early generations differ in a steadily high fluorine content, while the later ones exhibit reduced amount of fluorine, impurity elements, and sodium, with a simultaneous increase in the potassium content. The crystal structure of fluorine- rich barytolamprophyllite (potentially a new representative of the lamprophyllite group, differing by the predominance of fluorine in the anion X site) has been analyzed by single crystal X-ray diffraction. This mineral is found to have a monoclinic unit cell with the following parameters: a = 19.5219(8) Å, b = 7.0915(2) Å, c = 5.3925(2) Å, β = 96.628(3)°, and sp. gr. C2/ m. The structure is refined to R = 5.73% in the anisotropic approximation of the atomic displacement parameters using 3668 I > 2σ( I). The idealized formula ( Z = 2) is (Ba,Sr)2[Na(Na,Fe)2(Ti,Mg)F2][Ti2(Si2O7)2O2].

  3. The peculiar case of Marosticano xenoliths: a cratonic mantle fragment affected by carbonatite metasomatism in the Veneto Volcanic Province (Northern Italy)

    Brombin, Valentina; Bonadiman, Costanza; Coltorti, Massimo; Florencia Fahnestock, M.; Bryce, Julia G.; Marzoli, Andrea


    the typical OSMA array (Arai, 1994b) is observed in typical on-craton mantle rocks (Downes et al., 2004). To corroborate the cratonic "flavour" of these peridotites, in-situ trace element analyses show that Marosticano clinopyroxene have modified their residual characteristics by interaction with deep metasomatic melt, which was able to strong enrich in U, Th, LILE (Rb-Ba) and LREE with respect to the restitic preserved HREE and HFSE (e.g. Nb, Ta, Zr and Hf) contents. The general clinopyroxene trace element distribution and elemental ratios ((La/Yb)N and Ti/Eu; Coltorti et al., 1999) are consistent with enrichment provided by a carbonatitic rather than a silicate metasomatizing agent. To characterize the chemical-physical frame of the MA mantle segment, peridotites equilibration temperatures and oxygen fugacities were also estimated and compared with those of the other VVP xenoliths. The latter comparison leads to i) Marosticano samples record relatively high oxidation conditions (as Mts. Lessini peridotites) in agreement with the range assigned to continental lithosphere (Foley et al., 2011) and ii) these T-fO2 values account for CO2 mole fractions dissolved in a potential metasomatic melt close to 1, further supporting the carbonatitic nature of the infiltrating melt. In this case it can be speculated that the usually low oxidizing conditions of the cratonic mantle have been augmented by the interaction with a carbonatitic melt or with a CO2-rich fluid released by the reaction with a peridotitic matrix. References Arai, S., 1994b. Compositional variation of olivine chromian spinel in Mg-rich magmas as a guide to their residual spinel peridotites. Journal of Volcanology and Geothermal Research 59, 279-293. Beccaluva L., Bianchini G., Bonadiman C., Coltorti M., Milani L., Salvini L., Siena F., Tassinari R. (2007). Intraplate lithospheric and sublithospheric components in the Adriatic domain: Nephelinite to tholeiite magma generation in the Paleogene Veneto Volcanic

  4. Estimated Flood-Inundation Mapping for the Upper Blue River, Indian Creek, and Dyke Branch in Kansas City, Missouri, 2006-08

    Kelly, Brian P.; Huizinga, Richard J.


    In the interest of improved public safety during flooding, the U.S. Geological Survey, in cooperation with the city of Kansas City, Missouri, completed a flood-inundation study of the Blue River in Kansas City, Missouri, from the U.S. Geological Survey streamflow gage at Kenneth Road to 63rd Street, of Indian Creek from the Kansas-Missouri border to its mouth, and of Dyke Branch from the Kansas-Missouri border to its mouth, to determine the estimated extent of flood inundation at selected flood stages on the Blue River, Indian Creek, and Dyke Branch. The results of this study spatially interpolate information provided by U.S. Geological Survey gages, Kansas City Automated Local Evaluation in Real Time gages, and the National Weather Service flood-peak prediction service that comprise the Blue River flood-alert system and are a valuable tool for public officials and residents to minimize flood deaths and damage in Kansas City. To provide public access to the information presented in this report, a World Wide Web site ( was created that displays the results of two-dimensional modeling between Hickman Mills Drive and 63rd Street, estimated flood-inundation maps for 13 flood stages, the latest gage heights, and National Weather Service stage forecasts for each forecast location within the study area. The results of a previous study of flood inundation on the Blue River from 63rd Street to the mouth also are available. In addition the full text of this report, all tables and maps are available for download ( Thirteen flood-inundation maps were produced at 2-foot intervals for water-surface elevations from 763.8 to 787.8 feet referenced to the Blue River at the 63rd Street Automated Local Evaluation in Real Time stream gage operated by the city of Kansas City, Missouri. Each map is associated with gages at Kenneth Road, Blue Ridge Boulevard, Kansas City (at Bannister Road), U.S. Highway 71

  5. Sr-Nd-Pb isotopes of the Early Paleozoic mafic-ultramafic dykes and basalts from South Qinling belt and their implications for mantle composition


    Late Early Paleozoic mafic-ultramafic dykes and volcanic rocks from the South Qinling belt are characterized by eNd( t ) = +3.28―+5.02, (87Sr/86Sr)i=0.70341―0.70555, (206Pb/204Pb)i = 17.256―18.993, (207Pb/204Pb)i= 15.505―15.642, (208Pb/204Pb)i=37.125―38.968, △8/4=21.18―774.43, △7/4=8.11―18.82. These charac- teristics suggest that they derived from a Middle Neoproterozoic mantle with isotopic compositions of mixed HIMU, EMII and minor EMI components. We interpret that these rocks were melting products of depleted mantle modified by subducted ancient oceanic crust and continental margin sediments along the northern margin of Yangtze block during Early Neoproterozoic.

  6. A Study of Sr, Nd and O Isotopes of the K-rich Melanocratic Dykes in the Late Mesozoic Gold Field in the Jiaodong Peninsula


    Geologic, petrographic and petrochemical studies of the lateMesozoic K-rich melanocratic dykes, including lamprophyres, andesite porphyrites and dacite-porphyry in the gold field system in the Jiaodong Peninsula, China, have shown that these dykes are characterized by rich potassium and alkali but poor titanium. They belong to an ultra-high potassic, shoshonitic and high potassic calc-alkaline rock series. The parental magma has relatively high initial strontium ratios ((87Sr/86Sr)i-0.70895-0.71140) and low (143Nd/144Nd)i ratios (varying from 0.51135 to 0.51231); and its δ18OsMow. whole rock values vary from +5.8‰ to +10.6‰ with a mean of +7.1‰. These features suggest that the source region of the magma is an enriched mantle wedge transformed from a continental lithosphere mantle which has experienced me tasomatism by mantle-derived fluids with H2O-dominated fluids that were provided during the underthrusting of an ocean crust. The initial magma was generated by low-degree partial melting of the enriched mantle in its mature stage in the back-arc spreading environment. The evolution of magmas is associated with two trends, i.e., fractional crystallization and mixing with or intensive contamination by palaeo-crust materials or metamorphic rocks. The former process is evident in the gold field system of quartz-vein type, whereas the latter is dominated in the gold field system of the altered-rock type. This conclusion is very important for more detailed study of petrogenesis and mineralization through the crust-mantle interaction (exchange) in the Mesozoic in this region.

  7. Petrology of continental tholeiitic magmas forming a 350-km-long Mesozoic dyke swarm in NE Brazil: Constraints of geochemical and isotopic data

    Ngonge, Emmanuel Donald; de Hollanda, Maria Helena Bezerra Maia; Archanjo, Carlos José; de Oliveira, Diógenes Custódio; Vasconcelos, Paulo Marcosde Paula; Muñoz, Patrício Rodrigo Montecinos


    The Ceará Mirim dyke swarm (northeastern Brazil) is composed of Cretaceous tholeiites with plagioclase, clinopyroxene (± olivine), Fe-Ti oxides and pigeonite in their groundmass. These tholeiites have been subdivided into three groups: high-Ti olivine tholeiites, evolved high-Ti tholeiites (TiO2 ≥ 1.5 wt.%; Ti/Y > 360), and low-Ti tholeiites (TiO2 ≤ 1.5 wt%; Ti/Y ≤ 360), with all exhibiting distinct degrees of enrichment in incompatible elements relative to Primitive Mantle. Negative Pb anomalies are found in all three groups, while Nb-Ta abundances similar to those of OIB-type magmas are found in the olivine tholeiites, with moderate to high depletions being observed, respectively, in the evolved high-Ti and low-Ti tholeiites. The low-Ti tholeiites exhibit some contamination with crustal (felsic) materials during ascent. The initial isotopic compositions of the olivine tholeiites show uniform and unradiogenic 87Sr/86Sr (~ 0.7035-0.7039) combined with (in part) radiogenic 143Nd/144Nd and 206Pb/204Pb (> 19.1) ratios, which together reveal a likely contribution of FOZO (FOcalZOne) component in their genesis. The other tholeiite groups show variable Sr-Nd ratios with relatively consistent 206Pb/204Pb ratios clustering towards an isotopically enriched mantle (EM1) component. Taken in conjunction with the Nb, this enriched signature reflects the involvement of a subduction-modified lithospheric mantle in the source of the evolved high-Ti and low-Ti tholeiites. Thus, we propose that FOZO and EMI components coexisted (including minor mixing with E-MORB magmas) and contributed in varying extents to the generation of the Ceará-Mirim dyke swarm primary melts, which segregated at 75 to 60 km in depth around the garnet-spinel facies transition zone. The mechanism that promoted melting was most likely non-plume related. We suggest that plate-boundary forces linked to the opening of the Atlantic Ocean promoted passive rifting and that the resulting asthenospheric

  8. The role of recycled oceanic crust in magmatism and metallogeny: Os-Sr-Nd isotopes, U-Pb geochronology and geochemistry of picritic dykes in the Panzhihua giant Fe-Ti oxide deposit, central Emeishan large igneous province, SW China

    Hou, Tong; Zhang, Zhaochong; Encarnacion, John; Santosh, M.; Sun, Yali


    The picritic dykes occurring within fine-grained gabbro in the marginal zone and in the surrounding Proterozoic wall-rock marbles of the Panzhihua Fe-Ti oxide deposit closely correspond in bulk composition with the nearby Panzhihua intrusion. These dykes offer important constraints on the nature of the mantle source of the Panzhihua ore-bearing intrusion and its possible link to the Emeishan plume. U-Pb zircon dating of the picritic dyke yields a crystallization age of 261.4 ± 4.6 Ma, coeval with the timing of the main Panzhihua gabbroic intrusion and Late Permian Emeishan flood basalts. The Panzhihua picritic dykes contain 37.63-43.41 wt% SiO2, 1.15-1.56 wt% TiO2, 11.43-13.25 wt% TFe2O3, and 20.96-28.87 wt% MgO. Primitive-mantle-normalized patterns of the rocks are comparable to those of ocean island basalt. The rocks define a relatively small range of Os isotopic compositions and a low Os signature of -0.13 to +2.76 for γOs (261 Ma). In combination with their Sr-Nd-Os isotopic compositions, we interpret that these rocks were derived from the Emeishan plume sources as well as the interactions of plume melts with the overlying lithosphere which had been extensively affected by eclogite-derived melts from the deep-subducted oceanic slab. Partial melting induced by an upwelling mantle plume that involved an eclogite or pyroxenite component in the lithospheric mantle could have produced the parental Fe-rich magma. Our study suggests that plume-lithosphere interaction might have played a key role in generating many world-class Fe-Ti oxide deposits clustered in the Panxi area.

  9. 沙尘在防沙堤附近沉积特性的数值模拟%Numerical Simulation on Sedimentation Characteristics of Sand Dust Around Sand Preventing Dyke

    王志强; 何艺峰; 黄晟敏; 李国申; 高鸿恩; 富宝锋


    为研究沙尘在防沙堤附近的沉积特点,基于FLUENT软件,采用标准K-ε湍流模型和DPM模型对沙尘在防沙堤附近的运动轨迹进行数值模拟.结果表明,沙尘的运动轨迹受自身粒径、风速及防沙堤迎风面坡度的综合影响,沙粒粒径越小,风速越大,防沙堤迎风面坡度越缓,沙粒越过防沙堤的能力越强;除风速较低时部分小粒径颗粒沉积在防沙堤后端外,其余情况下沙尘沉积主要发生在防沙堤前端.%To study the sedimentation characteristics of sand dust around sand preventing dyke, the particle tracks were simulated by the standard A' -e model and DPM model based on FLUENT software. The results show that particles moving tracks are affected by particles size, wind velocity and sand preventing dyke l/h ratio of windward side synthetically. The sand dust quantity passing sand preventing dyke increases with wind velocity and l/h, and decreases but the case is just converse with particle size. Customarily most sand dust accumulate in front of the sand preventing dyke, only a little fine particles accumulate in the leeward at lower wind speed.

  10. Investigation and Evaluation of Ecological Method in Sea Shore Dyke in Dapeng Peninsula of Shenzhen%深圳市大鹏半岛海堤生物安全防护现状调查与评价



    The location of sea shore dyke, type of coastline and vegetation, species of plants and its distribution were investigated. The importance of storm tide prevention, the importance of biodiversity conservation and the importance of existing biological forest shelter belts were evaluated The results showed that there are 15 locations in protecting sea shore dyke within the study area rating biological protection very importance, 5 for importance,4 for general. The importance of ecological method in protecting sea shore dyke also has been evaluated.%对深圳市大鹏半岛海堤分布、海岸类型、植被类型、植物种类及分布等进行详细调查.对防风暴潮重要性、生物多样性保护重要性和现有生物防护林带保护重要性3个方面进行评价.结果表明,研究区内有15处海堤生物防护重要性等级为极重要,5处为重要,4处为一般.对海堤生物安全防护的重要性进行综合评价.

  11. Using Different Grazing Practices for Increasing Plant Biodiversity in the Dykes and Embankments Along the Rhône River (Southern France)

    Moinardeau, Cannelle; Mesléard, François; Dutoit, Thierry


    Extensive grazing by domestic herbivores is a widespread management practice used since the 80s in many European agro-ecosystems such as semi-natural grasslands to maintain open habitats and to enhance biodiversity. Such grazing systems have principally been tested in cultural ecosystems of high nature value threatened by grazing abandonment. However, there have been few case studies of grazing management in very anthropized ecosystems, such as the new ecosystems created by urban or industrial conversions. In Southern France, the Rhône channeling for navigation and electricity production generated in the 1950s the construction of thousands of hectares of dams and dykes which were colonized naturally by diverse plant communities. Yet shrub encroachment and the consequent recourse to mechanical cutting to facilitate control and maintenance, raise the question of how best to maintain and manage these new habitats. Consequently, since 1999, different low-intensity grazing management systems using rustic breeds of cattle, horses and goats have been tested on a protected reserve of 1454 ha located in the lower part of the Rhône river. Extensive grazing, more than cutting or no management, positively modified vegetation heterogeneity (beta-diversity), the target open grassland species, but not plant species richness (alpha-diversity). However, the current monitoring shows that these benefits of grazing will be confirmed only if low-intensity grazing systems are sustained and if new adaptations can be also made, such as the use of mixed stocking and the establishment of multiyear contracts with breeders.

  12. Nevus vascularis mixtus (cutaneous vascular twin nevi) associated with intracranial vascular malformation of the Dyke-Davidoff-Masson type in two patients.

    Ruggieri, Martino; Milone, Pietro; Pavone, Piero; Falsaperla, Raffaele; Polizzi, Agata; Caltabiano, Rosario; Fichera, Marco; Gabriele, Anna Lia; Distefano, Angela; De Pasquale, Rocco; Salpietro, Vincenzo; Micali, Giuseppe; Pavone, Lorenzo


    The term twin spotting refers to phenotypes characterized by the spatial and temporal co-occurrence of two (or more) different nevi arranged in variable cutaneous patterns, and can be associated with extra-cutaneous anomalies. Several examples of twin spotting have been described in humans including nevus vascularis mixtus, cutis tricolor, lesions of overgrowth, and deficient growth in Proteus and Elattoproteus syndromes, epidermolytic hyperkeratosis of Brocq, and the so-called phacomatoses pigmentovascularis and pigmentokeratotica. We report on a 28-year-old man and a 15-year-old girl, who presented with a previously unrecognized association of paired cutaneous vascular nevi of the telangiectaticus and anemicus types (naevus vascularis mixtus) distributed in a mosaic pattern on the face (in both patients) and over the entire body (in the man) and a complex brain malformation (in both patients) consisting of cerebral hemiatrophy, hypoplasia of the cerebral vessels and homolateral hypertrophy of the skull and sinuses (known as Dyke-Davidoff-Masson malformation). Both patients had facial asymmetry and the young man had facial dysmorphism, seizures with EEG anomalies, hemiplegia, insulin-dependent diabetes mellitus (IDDM), autoimmune thyroiditis, a large hepatic cavernous vascular malformation, and left Legg-Calvé-Perthes disease (LCPD) [LCPD-like presentation]. Array-CGH analysis and mutation analysis of the RASA1 gene were normal in both patients.

  13. Age and origin of fluorapatite-rich dyke from Baranec Mt. (Tatra Mts., Western Carpathians: a key to understanding of the post-orogenic processes and element mobility

    Gawęda Aleksandra


    Full Text Available On the southeastern slope of the Baranec Mount in the Western Tatra Mountains (Slovakia an apatite-rich pegmatite-like segregation was found in the subvertical fault zone cutting metapelitic rocks. Two zones: felsic (F and mafic (M were found, differing in mineral assemblages and consequently in chemistry. Fluorapatite crystals yield a LA-ICP-MS U-Pb age of 328.6 ± 2.4 Ma. A temperature decrease from 634 °C to 454 °C at a pressure around 500 to 400 MPa with oxygen fugacity increasing during crystallization are the possible conditions for formation of the pegmatite-like segregation, while secondary alterations took place in the temperature range of 340 – 320 °C. The Sr-Nd isotope composition of both apatite and whole rock point toward a crustal origin of the dike in question, suggesting partial melting of (P, F, H2O-rich metasedimentary rocks during prolonged decompression of the Tatra Massif. The original partial melt (felsic component was mixed with an external (F, H2O-rich fluid, carrying Fe and Mg fluxed from more mafic metapelites and crystallizing as biotite and epidote in the mafic component of the dyke.

  14. Note: Modified π-type Butterworth-Van Dyke model for dual-mode Lamb-wave resonator with precise two-port Y-parameter characterizations

    Wang, Yong; Hong, Yan; Goh, Wang Ling; Mu, Xiaojing


    Dual-mode Lamb-wave resonator has become a powerful component for clock reference and sensing applications, enabling efficient compensations of temperature effects, concurrent measurements of multiple environmental parameters, etc. An equivalent circuit model for the dual-mode Lamb-wave resonator is indispensable as it provides a means as well as being an effective tool for evaluating device characteristics and to aid the designing of circuitry for the resonators. This could be the first time ever that an efficient equivalent-circuit model, i.e., modified π-type Butterworth-Van Dyke model for dual-mode Lamb-wave resonators is reported. Evaluated by experiments, this model attains noteworthy agreements on both the magnitudes and phases of Y11 and Y21 of the measurement results. Compared to literature, the proposed model is capable of modeling the dual resonances efficiently. Moreover, this work also proves more accurate when viewing the Y-parameters across a wide frequency range. The gained features of this model are most beneficial for the analysis of the dual-mode Lamb-wave resonator and also for the designing of circuits.

  15. Note: Modified π-type Butterworth-Van Dyke model for dual-mode Lamb-wave resonator with precise two-port Y-parameter characterizations.

    Wang, Yong; Hong, Yan; Goh, Wang Ling; Mu, Xiaojing


    Dual-mode Lamb-wave resonator has become a powerful component for clock reference and sensing applications, enabling efficient compensations of temperature effects, concurrent measurements of multiple environmental parameters, etc. An equivalent circuit model for the dual-mode Lamb-wave resonator is indispensable as it provides a means as well as being an effective tool for evaluating device characteristics and to aid the designing of circuitry for the resonators. This could be the first time ever that an efficient equivalent-circuit model, i.e., modified π-type Butterworth-Van Dyke model for dual-mode Lamb-wave resonators is reported. Evaluated by experiments, this model attains noteworthy agreements on both the magnitudes and phases of Y11 and Y21 of the measurement results. Compared to literature, the proposed model is capable of modeling the dual resonances efficiently. Moreover, this work also proves more accurate when viewing the Y-parameters across a wide frequency range. The gained features of this model are most beneficial for the analysis of the dual-mode Lamb-wave resonator and also for the designing of circuits.

  16. Rare gas isotopes and parent trace elements in ultrabasic-alkaline-carbonatite complexes, Kola Peninsula: identification of lower mantle plume component

    Tolstikhin, I. N.; Kamensky, I. L.; Marty, B.; Nivin, V. A.; Vetrin, V. R.; Balaganskaya, E. G.; Ikorsky, S. V.; Gannibal, M. A.; Weiss, D.; Verhulst, A.; Demaiffe, D.


    During the Devonian magmatism (370 Ma ago) ∼20 ultrabasic-alkaline-carbonatite complexes (UACC) were formed in the Kola Peninsula (north-east of the Baltic Shield). In order to understand mantle and crust sources and processes having set these complexes, rare gases were studied in ∼300 rocks and mineral separates from 9 UACC, and concentrations of parent Li, K, U, and Th were measured in ∼70 samples. 4He/3He ratios in He released by fusion vary from pure radiogenic values ∼108 down to 6 × 104. The cosmogenic and extraterrestrial sources as well as the radiogenic production are unable to account for the extremely high abundances of 3He, up to 4 × 10-9 cc/g, indicating a mantle-derived fluid in the Kola rocks. In some samples helium extracted by crushing shows quite low 4He/3He = 3 × 104, well below the mean ratio in mid ocean ridge basalts (MORB), (8.9 ± 1.0) × 104, indicating the contribution of 3He-rich plume component. Magnetites are principal carriers of this component. Trapped 3He is extracted from these minerals at high temperatures 1100°C to 1600°C which may correspond to decrepitation or annealing primary fluid inclusions, whereas radiogenic 4He is manly released at a temperature range of 500°C to 1200°C, probably corresponding to activation of 4He sites degraded by U, Th decay. Similar 4He/3He ratios were observed in Oligocene flood basalts from the Ethiopian plume. According to a paleo-plate-tectonic reconstruction, 450 Ma ago the Baltica (including the Kola Peninsula) continent drifted not far from the present-day site of that plume. It appears that both magmatic provinces could relate to one and the same deep-seated mantle source. The neon isotopic compositions confirm the occurrence of a plume component since, within a conventional 20Ne/22Ne versus 21Ne/22Ne diagram, the regression line for Kola samples is indistinguishable from those typical of plumes, such as Loihi (Hawaii). 20Ne/22Ne ratios (up to 12.1) correlate well with 40Ar/36Ar

  17. Relationship between magmatic carbonatite and copper mineralization in the Ruina copper ore field, central province of Zambia%赞比亚中央省瑞娜铜矿区碳酸岩及其与成矿的关系

    孙希文; 边千韬; 王作琦


    通过对赞比亚中央省瑞娜铜矿区钻孔岩芯的系统研究,作者认为该区的含矿围岩为典型的火成碳酸岩,详细的岩矿相学研究也揭示瑞娜铜矿为碳酸岩岩浆型铜矿床.岩浆发生液态不混溶作用,溶离出碱性硅酸盐熔体、金属硫化物熔体和挥发份(CO2、H2O、F、Cl、B、P等)等流体,岩浆所携带的碱质使接触带地层交代蚀变成霓长岩,挥发份以络合物的形式携带部分Cu、Au、Ag、Ga、Co、REE、Ni等金属元素在外接触带地层碎裂岩和内接触带处成矿.%Through the systematic observation of drill core samples collected from Ruina copper ore field in central province of Zambia,the authors conclude that the copper-bearing country rock is a typical carbonatite with magnetic origin.The detailed study of mineral assemblages and petrographical characteristics also indicate that the Ruina copper deposit is a magmatic carbonatite-type cooper mineralization.When the magma evolved into the immiscible stage,the alkali-containing silicate melt,sulfides melt and volatile components (including CO2,H2O,F,Cl,B,P)are dissolved.The alkali compositions accompanying the magma reacted with the contact host rock,then the fenite was formed; and the volatile components which contain mineralization elements such as Cu,Au,Ag,Ga,Co,REE and Ni in the form of chemical complex deposited in the fractures of host rocks within the outlier contact zone as well as inner contact zone.The result of this study will be useful and meaningful for mineral prospecting in this region.

  18. Interpretation of Source Parameters from Total Gradient of Gravity and Magnetic Anomalies Caused by Thin Dyke using Nonlinear Global Optimization Technique

    Biswas, A.


    A proficient way to deal with appraisal model parameters from total gradient of gravity and magnetic data in light of Very Fast Simulated Annealing (VFSA) has been exhibited. This is the first run through of applying VFSA in deciphering total gradient of potential field information with another detailing estimation brought on because of detached causative sources installed in the subsurface. The model parameters translated here are the amplitude coefficient (k), accurate origin of causative source (x0) depth (z0) and the shape factor (q). The outcome of VFSA improvement demonstrates that it can exceptionally decide all the model parameters when shape variable is fixed. The model parameters assessed by the present strategy, for the most part the shape and depth of the covered structures was observed to be in astounding concurrence with the genuine parameters. The technique has likewise the capability of dodging very uproarious information focuses and enhances the understanding results. Investigation of Histogram and cross-plot examination likewise proposes the translation inside the assessed ambiguity. Inversion of noise-free and noisy synthetic data information for single structures and field information shows the viability of the methodology. The procedure has been carefully and adequately connected to genuine field cases (Leona Anomaly, Senegal for gravity and Pima copper deposit, USA for magnetic) with the nearness of mineral bodies. The present technique can be to a great degree material for mineral investigation or ore bodies of dyke-like structure rooted in the shallow and more deep subsurface. The calculation time for the entire procedure is short.

  19. Precursors to dyke-fed eruptions at basaltic volcanoes: insights from patterns of volcano-tectonic seismicity at Kilauea volcano, Hawaii

    Bell, Andrew F.; Kilburn, Christopher R. J.


    To investigate the physical controls on volcano-tectonic (VT) precursors to eruptions and intrusions at basaltic volcanoes, we have analyzed the spatial and temporal patterns of VT earthquakes associated with 34 eruptions and 23 dyke intrusions that occurred between 1960 and 1983 at Kilauea, in Hawaii. Eighteen of the 57 magmatic events were preceded by an acceleration of the mean rate of VT earthquakes located close to the main shallow magma reservoir. Using a maximum-likelihood technique and the Bayesian Information Criterion for model preference, we demonstrate that an exponential acceleration is preferred over a power-law acceleration for all sequences. These sequences evolve over time-scales of weeks to months and are consistent with theoretical models for the approach to volcanic eruptions based on the growth of a population of fractures in response to an excess magma pressure. Among the remaining 40 magmatic events, we found a significant correlation between swarms of VT earthquakes located in the mobile south-flank of Kilauea and eruptions and intrusions. The behaviour of these swarms suggests that at least some of the magmatic events are triggered by transient episodes of elevated rates of aseismic flank movement, which could explain why many eruptions and intrusions are not preceded by longer-term precursory signals. In none of the 57 cases could a precursory sequence be used to distinguish between the approach to an eruption or an intrusion, so that, even when a precursory sequence is recognized, there remains an empirical chance of about 40% (24 intrusions from 57 magmatic events) of issuing a false alarm for an imminent eruption.

  20. Ductile-brittle deformation effects on crystal-chemistry and U-Pb ages of magmatic and metasomatic zircons from a dyke of the Finero Mafic Complex (Ivrea-Verbano Zone, Italian Alps)

    Langone, Antonio; Padrón-Navarta José, Alberto; Ji, Wei-Qiang; Zanetti, Alberto; Mazzucchelli, Maurizio; Tiepolo, Massimo; Giovanardi, Tommaso; Bonazzi, Mattia


    A detailed microstructural, geochemical and geochronological study was performed on zircon grains from plagioclase-rich dioritic dykes discordantly intruded within meta-diorites/gabbros forming the External Gabbro unit of the Finero Mafic Complex (Italian Alps). This unit is exposed as part of a near complete crustal section spanning from mantle rocks to upper crustal metasediments (Val Cannobina, Ivrea-Verbano Zone, Italy). The leucocratic dykes consist mainly of plagioclase (An18-24Ab79-82Or0.3-0.7) with subordinate amounts of biotite and spinel defining melanocratic layers. Zircon and corundum are common accessory phases. Both the dykes and the surrounding meta-diorites/gabbros show evidence of ductile deformation under amphibolite-facies conditions. Zircon grains/fragments (up to 2 mm in length) occur as porphyroclasts surrounded by fine-grained plagioclase within the leucocratic domains and may occur within the melanocratic layers completely or partially surrounded by biotite and spinels. Fractures are common within zircon, define networks and have associated displacements occasionally and/or they can be filled by secondary minerals. Cathodoluminescence (CL) images reveal that zircon grains from the leucocratic layers show relicts of primary magmatic (i.e. oscillatory and or sector) zoning generally related with the crystal shapes or crystallographic orientation, whereas those from the melanocratic domains do not. In both cases, zircon shows secondary CL features, i.e. mosaic-like textures, due to deformation. EBSD maps confirmed a profuse mosaic texture, resulting in an internal misorientation of ca. 10°, generally associated with fractures. Locally, zircon shows clear evidence of crystal-plastic deformation at the edges, with a gradual misorientations of up to 12°, suggesting an origin prior fragmentation. Trace elements and U-Pb analyses were carried out by LA-ICP-MS directly on petrographic thin sections. Such in situ investigations revealed a strong

  1. Experimental study of the apatite-carbonate-H2O system at P = 0.5 GPa and T = 1200°C: Efficiency of fluid transport in carbonatite

    Gorbachev, N. S.; Shapovalov, Yu. B.; Kostyuk, A. V.


    Partitioning of more than 35 elements between coexisting phases in the apatite (Apt)-carbonate (Carb)-H2O system was studied experimentally at P = 0.5 GPa and T = 1200°C for estimation of the efficiency of fluid transport during the formation of carbonatite in platform alkaline intrusions. The interphase partition coefficients of elements ( D) range from n × 10-2 to 100 and higher, which provides evidence for their effective fractionation in the system. The following elements were distinguished: (1) Apt-compatible (REE, Y, Th, Cu, and W), which are concentrated in apatite; (2) hydrophile (Na, K, Mg, Ba, S, Mn, Pb, U, W, and Re), which are preferably distributed into fluid or the carbonate melt. The high hydrophilicity of alkali metals controls the alkaline character of postmagmatic fluids and related metasomatic rocks, whereas the high D(Fl/Apt) and D(Fl/LCarb) for S, Zr, W, Re, and U show their high potential in relation to U-W-Re mineralization.

  2. Textural, mineralogical and stable isotope studies of hydrothermal alteration in the main sulfide zone of the Great Dyke, Zimbabwe and the precious metals zone of the Sonju Lake Intrusion, Minnesota, USA

    Li, C.; Ripley, E.M.; Oberthur, T.; Miller, J.D.; Joslin, G.D.


    Stratigraphic offsets in the peak concentrations of platinum-group elements (PGE) and base-metal sulfides in the main sulfide zone of the Great Dyke and the precious metals zone of the Sonju Lake Intrusion have, in part, been attributed to the interaction between magmatic PGE-bearing base-metal sulfide assemblages and hydrothermal fluids. In this paper, we provide mineralogical and textural evidence that indicates alteration of base-metal sulfides and mobilization of metals and S during hydrothermal alteration in both mineralized intrusions. Stable isotopic data suggest that the fluids involved in the alteration were of magmatic origin in the Great Dyke but that a meteoric water component was involved in the alteration of the Sonju Lake Intrusion. The strong spatial association of platinum-group minerals, principally Pt and Pd sulfides, arsenides, and tellurides, with base-metal sulfide assemblages in the main sulfide zone of the Great Dyke is consistent with residual enrichment of Pt and Pd during hydrothermal alteration. However, such an interpretation is more tenuous for the precious metals zone of the Sonju Lake Intrusion where important Pt and Pd arsenides and antimonides occur as inclusions within individual plagioclase crystals and within alteration assemblages that are free of base-metal sulfides. Our observations suggest that Pt and Pd tellurides, antimonides, and arsenides may form during both magmatic crystallization and subsolidus hydrothermal alteration. Experimental studies of magmatic crystallization and hydrothermal transport/deposition in systems involving arsenides, tellurides, antimonides, and base metal sulfides are needed to better understand the relative importance of magmatic and hydrothermal processes in controlling the distribution of PGE in mineralized layered intrusions of this type. ?? Springer-Verlag 2007.

  3. Design of the dam and south dyke at the Toulnustouc hydroelectric development project; Conception du barrage et de la digue sud de l'amenagement hydroelectrique de la Toulnustouc

    Beausejour, N.; Bouzaiene, H. [RSW Inc., Montreal, PQ (Canada); Hammamji, Y.; Bigras, A.; Bergeron, A. [Hydro-Quebec Equipment, Montreal, PQ (Canada)


    The Toulnustouc hydroelectric dam is located approximately 120 km north of Baie-Comeau, Quebec and has been in operation since 2005. New development involved expanding the existing Lac-Sainte-Anne reservoir by 22 km{sup 2} through the construction of a new 77 m high and 535 m long dam and a 46 m high and 400 m long south dyke. This paper described the geology of the area and presented details of the main dam, instrumentation and stability analysis. The main concrete face rockfill dam (CFRD) lies on a foundation of bedrock. This paper presented the predictions of the upstream face displacements and the internal movements that develop in the rockfill embankment during the construction phase and the reservoir filling. The materials for the embankment dam were assumed to be non-linear, stress dependent and stress history dependent. The prediction displacements of the upstream face were compared to the displacement measured by monitors installed on the concrete face during the filling of the reservoir. The south dyke was constructed in an effort to control and reduce water infiltration under the foundation and to raise the crest of the reservoir. The principal criteria used for the design of the south dyke and the CFRD was presented. These included design wave and freeboard; ice loading on the upstream slab; geometry of the fill; material types with layer thickness and compaction criteria; stress and deformation of the fill; stability of the slope in both static and seismic conditions; extruded curb as stabilization method of the upstream slope, concrete slab, plinth, parapet, perimeter joint and waterstops; foundation treatment; and, instrumentation. During reservoir filling, the measured deformations and seepage were found to be lower than expected. 7 refs., 1 tab., 3 figs.

  4. Controle da antracnose e qualidade de mangas (Mangifera indica L. cv. van dyke, após tratamento hidrotérmico e químico Anthracnose control and mango quality (Mangifera indica L. cv. van dyke after hydrothermal and chemical treatment

    Mário Sérgio Carvalho Dias


    Full Text Available A antracnose causa severos danos à casca da manga. Por isso, há a necessidade de se fazer o tratamento fitossanitário pós-colheita dos frutos, utilizando a imersão em calda de fungicidas, a qual, associada ao tratamento hidrotérmico, tem resultado em melhores benefícios. Com o presente trabalho objetivou-se estudar o controle da antracnose e qualidade pós-colheita de mangas (Mangifera indica L., cv. Van Dyke, após tratamento hidrotérmico associado ao químico mediante as análises física, físico-químicas, químicas e fitopatológica. As mangas, provenientes de pomar comercial do município de Janaúba - MG, da safra 2000, foram colhidas em estádio de maturação comercial. Após seleção de acordo com a uniformidade de cor, tamanho e ausência de injúrias mecânicas e fisiológicas, as mesmas foram transportadas em caixas plásticas para a EPAMIG - CTNM - Nova Porteirinha - MG, Laboratório de Pós-colheita de frutos, onde as amostras foram submetidas ao tratamento hidrotérmico (55°C por 5minutos e banho frio em soluções contendo os fungicidas Thiabendazole (Tecto 400 mL/100 L, Prochloraz (Sportak 110 mL/100 L e Imazalil (Magnate 200 mL/100 L. Após secagem ao ar, os frutos foram acondicionados em bandejas plásticas e armazenados à temperatura ambiente (25±2°C e UR 70%, por um período de 12 dias e avaliados quanto às características intrínsecas de qualidade a cada 4 dias. O experimento foi conduzido em delineamento inteiramente casualizado, com 8 tratamentos, 4 repetições e unidade experimental composta de 4 frutos. As variações de pH, sólidos solúveis totais, acidez total titulável e açúcares solúveis totais não comprometeram as características organolépticas de mangas cv. Van Dyke armazenadas sob temperatura ambiente (25±2°C e UR 70% até os 8 dias de armazenamento. A associação do tratamento hidrotérmico com o químico foi eficiente no controle da antracnose dos frutos por até 12 dias de

  5. Parasitic analysis and π-type Butterworth-Van Dyke model for complementary-metal-oxide-semiconductor Lamb wave resonator with accurate two-port Y-parameter characterizations.

    Wang, Yong; Goh, Wang Ling; Chai, Kevin T-C; Mu, Xiaojing; Hong, Yan; Kropelnicki, Piotr; Je, Minkyu


    The parasitic effects from electromechanical resonance, coupling, and substrate losses were collected to derive a new two-port equivalent-circuit model for Lamb wave resonators, especially for those fabricated on silicon technology. The proposed model is a hybrid π-type Butterworth-Van Dyke (PiBVD) model that accounts for the above mentioned parasitic effects which are commonly observed in Lamb-wave resonators. It is a combination of interdigital capacitor of both plate capacitance and fringe capacitance, interdigital resistance, Ohmic losses in substrate, and the acoustic motional behavior of typical Modified Butterworth-Van Dyke (MBVD) model. In the case studies presented in this paper using two-port Y-parameters, the PiBVD model fitted significantly better than the typical MBVD model, strengthening the capability on characterizing both magnitude and phase of either Y11 or Y21. The accurate modelling on two-port Y-parameters makes the PiBVD model beneficial in the characterization of Lamb-wave resonators, providing accurate simulation to Lamb-wave resonators and oscillators.

  6. Key technologies for design of sea dykes of Tlaozini 1st stage project in Jiangsu Province%江苏条子泥Ⅰ期匡围海堤设计关键技术

    徐亮; 吴彩娥; 陈茹


    根据江苏东台条子泥边滩海域的特性,结合施工的具体条件,从工程实际情况出发,因地制宜,对条子泥Ⅰ期匡围工程的海堤设计关键技术进行探讨.结果表明,海堤防护采取的防护措施合理,能满足工程质量、安全的要求,同时取得了良好的经济效益.%There' re a series of radial sand ridges in the near-shore shallow sea area of Jianggang Town in Dongtai City of Jiangsu Province. Tiaozini sand ridge is located in the center of the radial sandbar area and adjacent to the beach, whose northern land boundary is Iiangduo River estuary and the southern one is Xinchuan Port. According to the characteristics of Tiaozini sea area and combined with the specific construction conditions, the key technologies for the design of sea dykes of Tiaozini 1* stage project are discussed based on the actual situations and local conditions. The results indicate that the measures for protecting the sea dykes are rational, and they can meet the requirements of project quality and safety. Accordingly, good economic benefits are achieved.

  7. The Ediacaran volcanic rocks and associated mafic dykes of the Ouarzazate Group (Anti-Atlas, Morocco): Clinopyroxene composition, whole-rock geochemistry and Sr-Nd isotopes constraints from the Ouzellarh-Siroua salient (Tifnoute valley)

    Belkacim, Said; Gasquet, Dominique; Liégeois, Jean-Paul; Arai, Shoji; Gahlan, Hisham A.; Ahmed, Hassan; Ishida, Yoshito; Ikenne, Moha


    Belonging to the huge Ouarzazate volcanic Group that covered the whole Anti-Atlas during the late Ediacaran (580-545 Ma), the Tifnoute valley volcanic formations are mainly pyroclastic and show a large composition, from trachybasalt to rhyolite and are crosscut by dolerite dykes. The Tifnoute valley volcanic rocks are located within a rigid salient of the Anti-Atlas that gives them special extreme characteristics. Due to the heavy greenschist alteration that affects this volcanic group, we focused the more immobile elements, but as REE can also be affected, we used the composition of unaltered clinopyroxene crystals to determine the nature of these volcanic rocks. The clinopyroxene is an augite diopside in the basalt, an augite in the andesite and an augite-salite in the dolerite. Petrography of the Tifnoute mafic volcanic rocks and clinopyroxene compositions indicate the presence of two magmatic series: (i) older high-K calc-alkaline (alkali-calcic) andesite and basalt characterized by the early crystallization of Fe-Ti oxides and of the late fractionation of plagioclase, the modal proportion of the latter increasing from the basalt to the andesite and (ii) younger alkalic dolerite dykes. With clinopyroxene trace element compositions obtained using laser ablation ICP-MS, we calculated the composition of the melts in equilibrium with the pyroxenes. The volcanic rocks of the Tifnoute Valley have positive εNd570 (+1.7 to +5.0), low Sri (volcanic rocks emplaced in a Pan-African transtensive post-collisional environment that evolved towards the major rifting event that will give rise to the Rheic ocean, in a similar way to what occurred just after the Variscan orogeny during the Triassic period that evolved to the Tethys ocean opening.

  8. Petrogenesis of carbonic dykes within southern Tibetan Plateau, and climatic effects%藏南碳酸岩脉成因及其气候效应



    released back to atmosphere through hot springs. Most carbon had, however, transferred into deep interior of Tibetan Plateau along with subducted Indian crust. The biotite within the subducted slab underwent dehydration to form granitic magmas beneath south Tibetan Plateau. The metasomatic reactions between the granitic magmas and the subducted carbon-rich Siwalik formation took place to release high-temperature CO2-rich fluids beneath Tibetan Plateau, regarded as crustal-derived carbonic magmas in this study. The magmas/fluids intruded into south Tibetan upper crust to form carbonic dykes. The huge atmospheric CO2 has, therefore, been transformed into carbonic magmas within thickened crust of southern Tibetan Plateau during the collision between India and Asia. The carbon emitted by hot springs as well as volcanoes within Tibetan Plateau was originated from atmosphere. It is recycling carbon. The carbon emissions from Tibetan Plateau are slightly less than those sinked by Tibetan Plateau. Otherwise,the carbonic dykes,formed by consuming huge atmospheric CO2,never occurred within Tibetan Plateau. This clearly suggests that Himalayan Mountains and south Tibetan Plateau are a huge reservoir for atmospheric CO2, leading to global cooling during Cenozoic times. Moreover,the changing of atmospheric CO2 was mainly derived by Earth's tectonic activities, and not by mankind. Global changing is only a natural phenomenon, without any relationships carbon emissions of human.%始新世末期以来,全球大气CO2浓度持续下降,但长期以来不清楚为何这一时期全球大气CO2浓度下降,巨量的大气CO2赋存于何处.深入研究该问题有助于准确理解未来大气CO2浓度变化的趋势,特别是有助于进一步评估人类自身碳排放的后果.这一时期,小印度陆块持续与大亚洲陆块汇聚,导致了以喜马拉雅为代表的山脉群和青藏高原的形成.很早就有学者从地球表层碳循环的角度提出了“青藏高原的隆升

  9. Interaction between magmatic and tectonic stresses during dyke intrusion Interacción entre esfuerzos magmáticos y tectónicos durante la intrusión de diques

    Jorge Skarmeta


    Full Text Available Cataclastic and mylonitic rocks exposed in the southwestern part of the Peninsula de Mejillones, northern Chile, are intruded at high angles of the foliation by younger, steeply inclined (±70° basaltic dykes that resemble intrusive tension gashes with knife-edge contacts with the country rocks. These late dykes developed sigmoidaly-shaped, preferred orientation paths defined by oriented pyroxene phenocrysts that vary in size, aspect ratio, concentration and distribution across the width of an individual dyke. This banding has z and s asymmetries that indicate the sense of displacement of the country rock. The relative involvement of the coeval, internal and external stresses that caused the finite strains is estimated by using a partition analysis. The phenocryst location and size distribution are related to the internal magma flow velocity (u m stress component, whereas the sigmoid banding is linked to the external tectonic wall displacement velocity (±u. Dyke wall sliding with or against the magma flow induced the asymmetric shear strain distribution. The measured strain and displacements are analyzed using the deformation model of viscous laminar flow confined between two parallel plates moving parallel to each other with opposed motion. The shear stresses related to magma intrusion and frictional dyke-wall shear are quantified on the basis of magma flow displacements, cooling times and the temperature dependent viscosity of basalts in the linear rheology range. At the estimated depth where the intrusion and deformation occurred, the state of stress was close to being hydrostatic. This conclusion is in agreement with established models of active-collapsing volcanic centres, where bulk permeability is accommodated by means of a mesh of interconnected dykes and active faults. This interactivity tends to re-equilibrate, locally and transiently, any excess differential stress and redistributes excess magmatic pressures to create a uniform

  10. Influencia de la temperatura y el tiempo de almacenamiento en la conservación del fruto de mango (Manifera indica L. variedad Van Dyke Influence of temperature and storage time on quality of mango fruit (Mangifera indica l. variety Van Dyke

    Galvis Jesús A.


    Full Text Available Mangos (Mangifera índica L. Variedad Van Dyke en grado de madurez fisiológica, se almacenaron en tres temperaturas de refrigeración (12, 10 Y 7°C y H. R del 85 - 90%, por tiempos de 10, 20 y 30 días. Adicionalmente se almacenaron mangos a 18°C por 15 días, los cuales fueron tomados como testigo. Los mangos fueron cosechados de la finca Frutol, localizada
    en el municipio de El Espinal, departamento del Tolima.
    Temperatura media 29°C, altitud 431 m.s.n.m, humedad
    relativa del 70%, precipitación promedio anual 1368
    mm. Durante el almacenamiento se evaluaron características
    fisicas como porcentaje de pérdidas de peso, dureza del
    fruto y de la pulpa. Además se evaluaron algunos cambios
    químicos y bioquímicos como la variación de los °Brix, el pH, el porcentaje de acidez, el contenido de sacarosa, glucosa y fructosa y de ácidos (cítrico, málico, succínico y ascórbico. Finalmente se evaluaron los cambios de color de la corteza.
    Del estudio se concluyó que la mejor temperatura de
    almacenamiento fue 12°C, en la cual el fruto maduró
    hasta alcanzar la madurez organoléptica en el día 30, lo
    cual equivale al doble del tiempo de conservación respecto
    a los mangos almacenados a 18°C. El mango resultó ser sensible a las temperaturas de 10 y 7°C, la cual se caracterizó por la interrupción del proceso de maduración siendo más graves los daños por frío en la temperatura de 7°C. En la temperatura de 10°C, se presentó evolución de los cambios que caracterizan la maduración hasta el día 20, pero entre el día 21 y el día 30 los cambios fueron interrumpidos, lo que indica que los daños por frío se hicieron irreversibles a partir del día 21.Mangos variety Van Dyke harvested at physiologic maturity were stored at low temperatures (12, 10 and 7°C, 85% RH, for 10, 20 and 30 days. Control mangos were stored at 18°C by 15 days. The fruits were harvested in the Frutol

  11. Kampelite, Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O, a new very complex Ba-Sc phosphate mineral from the Kovdor phoscorite-carbonatite complex (Kola Peninsula, Russia)

    Yakovenchuk, Victor N.; Ivanyuk, Gregory Yu.; Pakhomovsky, Yakov A.; Panikorovskii, Taras L.; Britvin, Sergei N.; Krivovichev, Sergey V.; Shilovskikh, Vladimir V.; Bocharov, Vladimir N.


    Kampelite, Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O, is a new Ba-Sc phosphate from the Kovdor phoscorite-carbonatite complex (Kola Peninsula, Russia). It is orthorhombic, Pnma, a = 11.256(1), b = 8.512(1), c = 27.707(4) Å, V = 2654.6(3) Å3 and Z = 4 (from powder diffraction data) or a = 11.2261(9), b = 8.5039(6), c = 27.699(2) Å, V = 2644.3(3) Å3 (from single-crystal diffraction data). The mineral was found in a void within the calcite-magnetite phoscorite (enriched in hydroxylapatite and Sc-rich baddeleyite) inside the axial zone of the Kovdor phoscorite-carbonatite pipe. Kampelite forms radiated aggregates (up to 1.5 mm in diameter) of platy crystals grown on the surfaces of crystals of quintinite-2H in close association with pyrite, bobierrite and quintinite-3R. Kampelite is colourless, with a pearly lustre and a white streak. The cleavage is perfect on {001}, the fracture is smooth. Mohs hardness is about 1. In transmitted light, the mineral is colourless without pleochroism or dispersion. Kampelite is biaxial + (pseudouniaxial), α ≈ β = 1.607(2), γ = 1.612(2) (589 nm), and 2V calc = 0°. The calculated and measured densities are 3.28 and 3.07(3) g·cm-3, respectively. The mean chemical composition determined by electron microprobe is: MgO 4.79, Al2O3 0.45, P2O5 31.66, K2O 0.34, Sc2O3 16.17, Mn2O3 1.62, Fe2O3 1.38, SrO 3.44, and BaO 29.81 wt%. The H2O content estimated from the crystal-structure refinement is 7.12 wt%, giving a total of 96.51 wt%. The empirical formula calculated on the basis of P = 6 apfu (atoms per formula unit) is (Ba2.62Sr0.45K0.10Ca0.06)Σ3.23Mg1.60Mn0.28(Sc3.15Fe3+ 0.23Al0.12)Σ3.50(PO4)6(OH)2.61·4.01H2O. The simplified formula is Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O. The mineral easily dissolves in 10% cold HCl. The strongest X-ray powder-diffraction lines [listed as d in Å (I) (hkl)] are as follows: 15.80(100)(001), 13.86(45)(002), 3.184(18)(223), 3.129(19)(026), 2.756(16)(402), 2.688(24)(1010). The crystal structure of kampelite was refined to

  12. Primera edad U-Pb en circón usando LA-ICP-MS de un dique traquiandesítico emplazado en el granito tipo-A Los Árboles, Sierras Pampeanas Orientales First age U-Pb zircon LA-ICP-MS from trachyandesitic dyke emplaced in the A-type Los Árboles pluton, Eastern Sierras Pampeanas

    Juan A Dahlquist


    Full Text Available La edad de cristalización de diques subvolcánicos emplazados en plutones graníticos carboníferos, Sierras Pampeanas Orientales, permanece incierta. La primera edad U-Pb en circón usando LA-ICP-MS obtenida en un dique que intruye al plutón Los Árboles (sierra de Fiambalá, revela una edad de cristalización de 311 ± 3 Ma.The crystallization age of subvolcanic dykes emplaced in Carboniferous granitic plutons of the Sierras Pampeanas Orientales remains uncertain. The first age precise U-Pb zircon LA-ICP-MS obtained from a dyke emplaced in the Los Árboles pluton (Sierra de Fiambalá yield a crystallization age of 311 ± 3 Ma.

  13. U-Pb age of the Anuri dyke: paleoproterozoic potassic alkaline magmatism and implications for the Transamazonic orogeny in the Sao Francisco Craton;Idade U-Pb do dique sienitico Anuri, sul da Bahia: magmatismo alcalino-potassico paleoproterozoico e sua implicacao para a orogenia transamazonica no Craton do Sao Francisco

    Conceicao, Herbet; Rios, Debora Correia, E-mail: herbet@ufba.b, E-mail: debora@cpgg.ufba.b [Universidade Federal da Bahia (LPAPM/IGEO/UFBA), Salvador, BA (Brazil). Centro de Pesquisa em Geofisica e Geologia. Lab. de Petrologia Aplicada a Pesquisa Mineral; Rosa, Maria de Lourdes da Silva, E-mail: lourdes@cpgg.ufba.b [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil); Oberli, Felix, E-mail: oberli@erdw.ethz.c [Institute Isotopengeologie/Mineral, Zuerich (Switzerland)


    The Anuri Syenitic Dyke (72 km{sup 2}) is the south representative of a 1000 km N-S alignment of syenitic dykes which occur at the East Bahia. As the others bodies, Anuri is essentially composed of hypersolvus ultrapotassic syenites, which show the records of its differentiation by the presence of mafic-ultramafic apatite-rich cumulates. Its crystallization age of 2095- 4 Ma (U-Pb{sub zircao}) is quite similar with results obtained for the other syenitic dykes, which suggest that their intrusions occur almost at the same time, sincronically, after the Transamazonic Orogeny climax. The geochemical data reveal that Anuri syenites are Ba, Sr, P, LREE enriched and show negative anomalies of Ti and Nb, suggesting a mantelic source subduction related. The initial Sr ratio and {epsilon}{sub Nd} values confirms the presence of this anomalous mantle. These data suggest that at the end of Transamazonic Orogeny, at the Sao Francisco Craton, there were particular conditions which allow the generation of alkaline magmas through the melting of an EMI reservoir. (author)

  14. Determination of trace elements in Mesozoic dykes of the Serra do Mar by neutron activation; Determinacao de elementos tracos em diques mesozoicos da Serra do Mar por meio de ativacao com neutrons

    Vicentini, Caio M.; Marques, Leila S., E-mail:, E-mail: [Universidade de Sao Paulo (IAG/USP), Sao Paulo, SP (Brazil). Instituto de Astronomia, Geofisica e Ciencias Atmosfericas; Figueiredo, Ana Maria G., E-mail: [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)


    The analysis of trace elements such as rare earths, Th, U, Ta, Hf, Ba, Rb and Ba, is a very important tool for petrogenetic studies. In order to study these processes in dykes of Enxame Serra do Mar (Coast of Sao Paulo and Rio de Janeiro), belonging to the Parana Magmatic Province (PMP), one of the most significant provinces of continental basalts in the world, were perform analyzes by neutron activation in these dikes. The technique, employed in Centro de Reator de Pesquisa of the Instituto de Pesquisas Energeticas e Nucleares, provided concentrations of trace elements with accuracy levels of 10% and 9%, which are suitable for petrogenetic studies. Due to the low concentrations of the elements analyzed, the experimental routine sample preparation processes covered very careful to avoid contamination. The samples investigated can be divided into four groups: basic rocks (SiO{sub 2} <55%) with Ti / Y> 500; basic rocks with Ti / Y <500; intermediate rocks (55% 63%). Dikes of intermediate and acid composition only occur at the Sao Sebastiao Island and adjacent coastal region. The concentrations of major and minor elements, as well as the abundance patterns of rare earths and other incompatible elements of these more differentiated rocks, show significant similarities with the type of the volcanic Chapeco, suggesting similar genesis, in other worlds, including also processes of crustal contamination.

  15. Caracterizacion fisiológica del crecimiento y desarrollo del fruto de mango (mangifera indica l. variedad van dyke en el municipio de el Espinal

    Galvis Jose Antonio


    ="font-size: 12pt; font-family: "> 

    Se realizó el seguimiento de los cambios ocurridos durante el crecimiento y desarrollo del mango Variedad Van Dyke, desde la antesis hasta la madurez fisiológica: Diámetros longitudinal, transversal, el volumen, la gravedad específica, el peso fresco y seco, color de la corteza y de la pulpa y la Intensidad Respiratoria. El diseño experimental empleado fue completamente al azar.


    Se estableció que el tiempo que transcurre desde la antesis hasta alcanzar la madurez fisiológica es de 90 días. El crecimiento del fruto es de tipo Sigmoidal Simple. Se identificaron 3 etapas durante el crecimiento. El análisis de regresión permitió establecer modelos 1ineales para las características físicas.


    El fruto presentó alta intensidad respiratoria en los primeros días del crecimiento y fue disminuyendo hasta alcanzar valores mínimos al final de la etapa de crecimiento. Hubo una alta correlación inversa entre la I.R. y las variables físicas medidas.


  16. 唱凯堤决口应急封堵抢险施工技术与组织管理%Construction techniques and organizational management of emergency risk-elimination for closuring breaching of Changkai Dyke



    本文详细介绍了江西抚州市唱凯堤决口的概况、应急封堵抢险的设计方案和施工方案.针对应急抢险工程工期紧、施工条件差、社会关注度高等特点,采取了加大设备、人力等资源投入等强化施工措施,提出了抢险工程的设备及人力等资源投入应为平时施工的2~3倍,且必须一次到位的观点.介绍了提高现场组织指挥人员级别、明确任务目标、加强抢险过程中的统计分析、加强关键环节组织协调等组织管理措施.对类似工程施工和应急抢险工作有一定的参考作用.%Both the design scheme and construction scheme of the emergency risk-elimination for closuring the breaching of Changkai Dyke in Fuzhou of Jiangxi Province are described herein in detail During the emergency construction, the intensified construction measures such as increasing the inputs of equipment and labor resource, reinforcing the statistical analysis; strengthening the organization and coordination of the key-links during the construction, etc. Are adopted in accordance with the characteristics of limited construction period, poor construction condition and high concern from the society. Therefore, the emergency risk-elimination of this time has some references for the similar emergency construction concerned.

  17. Sm/Nd isotopic data for the Santana do Ipanema high-K mega dykes as evidence for Brasiliano decompression melting at the Pernambuco-Alagoas (PE-AL) Massif, Borborema province

    Silva Filho, A.F. da; Guimaraes, I.P.; Luna, E.B.A.; Valadares, D.S. [Pernambuco Univ., Recife, PE (Brazil). Dept. de Geologia


    This work deals with the Sm-Nd signatures of some mega dykes located close to the Northern limit of the batholith in the Santana do Ipanema plutonic complex (SIC), which comprises 6 intrusive suites. Their composition ranges from syenites to quartz syenites. They are mesocratic to leucocratic, usually equigranular but sometimes porphyritic. Their accessory mineralogy is comprised of sphene, opaque, amphibole, {+-} pyroxene, apatite, zircon, biotite, allanite and epidote. The main minerals are microcline, plagioclase and quartz. The SIC rocks are metaluminous and intermediate to acid, with Si O{sub 2} ranging from 55,6 wt% to 66.4 wt% and Ba ranging from 3889 ppm to 10253 pp,. The K{sub 2} O/Na{sub 2} O ratio ranges widely as well, from 0,59 to 2.07, making these rocks a quite heterogeneous suite. The diagram shows two patterns, one with troughs at Nb, Zr and Ti, while the other one shows troughs at Nb, Hf and Eu. The Zr data available show a wide range, from 133 ppm to 314 ppm, suggesting this suite was the result of different degrees of partial melting of a same enriched LIL protolith. Five isotope Sm-Nd data has been obtained for these rocks, yielding epsilon Nd (0.60 Ga) values which ranges from -9.3 to -3.6, and Tdm which ranges from 2.34 Ga to 1.26 Ga. The isotope data agree with the heterogeneous character showed by the trace elements 3 refs.

  18. Tectonic breccia of the Cabo Frio area, State of Rio de Janeiro, Brazil, intruded by Early Cretaceous mafic dyke: evidence of the Pan-African brittle tectonism? Brecha tectônica da área de Cabo Frio - RJ, intrudida por dique máfico do Eocretáceo: evidência do tectonismo rúptil do Pan-Africano?

    Akihisa Motoki


    Full Text Available This paper presents the field descriptions and microscopic observations of a tectonic breccia in the basement gneiss of the Cabo Frio and Arraial do Cabo areas, State of Rio de Janeiro, Brazil, and its intrusive contact with the Early Cretaceous mafic dyke. At the sea cliff close to the Ilha do Japonês, there is an excellent contact outcrop between them. The tectonic breccia zone is 10 to 20m wide and has N30ºE direction. The breccia clasts are angular and characterized by auto-brecciation texture, and composed of breccia with similar aspect of the host tectonic breccia. The matrix is firmly consolidated by hydrothermalism and following silicification. The mafic dyke is 7 to 10m wide and of N45ºE direction. Along the contact, the dyke chilled margin featured by fine-grained basalt and prismatic joints can be observed. At the Conchas Beach and Arraial do Cabo city, there are four outcrops demonstrating the mafic dyke intrusion into the consolidated tectonic breccias. These outcrops prove that the tectonic breccias are older than the Early Cretaceous tholeiitic dykes. The fault breccias could have been formed during the brittle-phase tectonism of the last stage of the Pan-African Orogeny by hydrothermalism without magmatic activities, namely tectonic hydrothermalism. The existence of the clasts constituent of the breccia that are composed of breccia suggests that the fault movement and following hydrothermalism occurred repeatedly.Esse trabalho apresenta as descrições de campo e observações petrográficas de uma brecha tectônica no embasamento gnáissico das áreas de Cabo Frio e Arraial do Cabo, RJ, e seu contato intrusivo com um dique máfico do Eocretáceo. Na proximidade da ilha do Japonês, ocorre um excelente afloramento de contato entre esses litotipos. A zona da brecha tectônica tem 10 a 20 m de largura e tem direção de N30ºE. Os clastos da brecha são angulosos e caracterizados pela textura de auto-brechação, sendo similares

  19. Experience with fermentation of grass and grass silage from extensively used grassland. Feasibility study on monofermentation of grass silage from contaminated sites - biomass from grasslands of the Elbe dyke foreland; Betriebserfahrungen mit der Vergaerung von Gras und Grassilagen von extensiv genutztem Gruenland. Machbarkeitsuntersuchung zur Monovergaerung von Grassilagen schadstoffkontaminierter Standorte am Beispiel der eingesetzten Biomasse von Gruenlandflaechen aus dem Deichvorland der Elbe

    Heuer, Hans-Juergen [Landwirtschaftskammer Niedersachsen, Bezirksstelle Uelzen (Germany)


    This feasibility study was concluded in 2011; monofermentation of grass silage from contaminated sites of the Elbe dyke foreland was investigated. It was found that a biogas operated in monofermentation of grass silage from extensively used grasslands is technically and economically feasible in batch operation. It was also shown that the fermentation residue can be used as agricultural fertilizer, provided that it is first turned in a compost turning unit and then worked into the soil. In view of the high pollutant concentration of the soils in the Elbe dyke foreland, the results of the project give the agricultural businesses in the Elbe valley grasslands an alternative use of the land. [German] Die Machbarkeitsuntersuchung zur Monovergaerung von Grassilagen schadstoffkontaminierter Standorte am Beispiel der eingesetzten Biomasse von Gruenlandflaechen aus dem Deichvorland der Elbe wurde Anfang Mai 2011 abgeschlossen. Im Ergebnis wurde herausgearbeitet, dass sich eine Biogaslage im Monovergaerungsverfahren mit ausschliesslich nur Grassilagen von extensiv gefuehrten Gruenlandflaechen technisch und wirtschaftlich in einer Batch-Anlage betreiben laesst. Auch wurde der Nachweis gefuehrt, dass die Biomasse aus dem Deichvorland der Elbe als Gaerrest auf das Gruenland im Deichvorland unter Beruecksichtigung von naturschutzfachlichen Vorgaben und nach den Vorgaben der guten fachlichen Praxis beim Duengen zurueckgefuehrt werden kann. Vor einer Aufbringung auf dem Gruenland sollte der feste Gaerrest jedoch mit einem Kompost-Umsetzer aufbereitet werden. Nach dem Ausstreuen auf dem Gruenland ist der Gaerrest mit einer Wiesenschleppe einzureiben. Vor dem Hintergrund der hohen Schadstoffbelastung der Boeden im Deichvorland der Elbe, tragen die im Projekt erarbeiteten Ergebnisse dazu bei, den landwirtschaftlichen Betriebsleitern in der Elbtalaue eine alternative Nutzung zur bisherigen Lebensmittelproduktion unterbreiten zu koennen.

  20. Diagnosis and Differential Diagnosis of the Dyke-Davidoff-Masson Syndrome by CT and MRI: Report of 3 Cases and Literature Review%戴克-大卫杜夫-梅森综合征CT、MRI诊断及鉴别诊断(附3例报告并文献复习)

    熊伟; 蒋秋燕; 欧波; 龙从杰


    Objective To discuss the clinical and imaging findings of Dyke-Davidoff-Masson syndrome(DDMS).Methods The clinical and imaging features of DDMS in 3 patients were analyzed retrospectively with literature review.Results 3 patients suffered from cerebral hemiatrophy with ipsilateral ventricular dilatation and displacement of the midline structures, 2 cases with encephalomalacia and porencephaly,one case with thalamus hypoplasia and lentiform nucleus hypoplasia were found.Unilateral calvarial thickening was seen in 3 cases.There were hyperpneumatization of paranasal sinuses in 2 cases,hypoplasia of the cranial fossa in 2 cases,hyperpneumatization of mastoid cells and elevation of the petrous ridge in one case.Conclusion DDMS displays relatively the typical imaging features,and it can be diagnosed correctly according to imaging findings in combination with clinical characters.%目的 探讨戴克-大卫杜夫-梅森综合征(Dyke-Davidoff-Masson syndrome,DDMS)的临床及影像学表现.方法 回顾性分析3例DDMS患者的临床及影像学资料并作文献复习.结果 3例均出现单侧大脑萎缩,同侧侧脑室扩大,中线结构向患侧偏移,1例出现脑软化及脑穿通畸形,1例出现丘脑及豆状核萎缩.3例出现患侧颅骨增厚,2例出现鼻窦过度发育,2例颅窝缩小,1例乳突窦增大及岩骨嵴抬升.结论 DDMS具有比较典型的影像学表现,结合临床表现影像学可以正确诊断.

  1. 基于MlKE11水动力模型的大洋河丹东有堤段行洪能力分析%Analysis on Flood Discharge Capacity of Dayang River Dandong Section with Dyke Based on MIKE11 Hydrodynamic Model



    河道现状行洪能力是河道所在地区防洪安全的核心,也是防汛主管管部门汛期指导防汛的重要依据。为分析大洋河丹东有堤段的行洪能力,采用水动力模型MIKE11计算、模拟河道及河网的一维洪水演进过程,准确判断其行洪能力,为保护沿岸居民防洪安全提供理论基础。%Flood discharge capacity of watercourse status is the core of flood control safety in the watercourse area, and is also as an important basis for flood prevention authorities directing the work of flood prevention during flood season. In order to analyze the flood discharge capacity of Dayang River Dandong section with dyke, we used hydrodynamic model MIKE11 to calculate and imitate one-di-mensional flood routing process of watercourse and river network, and estimated the flood discharge capacity correctly, providing the theoretical basis for preventing coastwise residents flood control safety.

  2. Design and construction of a rockfill spur dyke on the Rupert River (PK 85) under the Eastmain1-A/LaSarcelle/Rupert diversion project; Conception et construction d'un epi en enrochement sur la riviere Rupert (PK 85) dans le cadre du projet Eastmain-1-A/LaSarcell/derivation Rupert

    Pelletier, Pierre; Fecteau Sebastien, Thibodeau; Patrick [GENIVAR, Quebec, (Canada); Cote, Pierre; Grenon, Alain [Societe d' Energie de la Baie James, Montreal, (Canada)


    The Eastmain-1-A/Sarcelle plants and Rupert diversion project involved the partial diversion of the Rupert River in the direction of the La Grande complex. This diversion point on the Rupert River is located at the 314th kilometre, where a dam with a regulation works was constructed. A network of nine hydraulic works was designed and constructed to maintain the water levels in the slow flow section of the river to limit the environmental impact. A rockfill spur dyke was constructed at the 85th kilometre of the Rupert River, for control of the water levels over a distance of 10.8 kilometres. This paper presented the challenges facing the construction operation of this hydraulic work on the Rupert River. The design of this structure was first simulated by 2-D hydrodynamic models. A scale model built at the 1:40 scale was used to assess the stability of the temporary piers created for shelter during the construction process.

  3. Primary carbonatite melt from deeply subducted oceanic crust

    Walter, Michael J.; Bulanova, Galina; Armstrong, Lora S; Keshav, S; Blundy, Jon D; Gudfinnsson, G; Lord, Oliver T.; Lennie, A; Clark, SM; Smith, C; Gobbo, L


    Partial melting in the Earth’s mantle plays an important part in generating the geochemical and isotopic diversity observed in volcanic rocks at the surface. Identifying the composition of these primary melts in the mantle is crucial for establishing links between mantle geochemical ‘reservoirs’ and fundamental geodynamic processes. Mineral inclusions in natural diamonds have provided a unique window into such deep mantle processes. Here we provide experimental and geochemical evidence that s...

  4. The giant Bayan Obo REE-Nb-Fe deposit, China: Controversy and ore genesis

    Hong-Rui Fan


    Full Text Available Bayan Obo ore deposit is the largest rare-earth element (REE resource, and the second largest niobium (Nb resource in the world. Due to the complicated element/mineral compositions and involving several geological events, the REE enrichment mechanism and genesis of this giant deposit still remains intense debated. The deposit is hosted in the massive dolomite, and nearly one hundred carbonatite dykes occur in the vicinity of the deposit. The carbonatite dykes can be divided into three types from early to late: dolomite, co-existing dolomite-calcite and calcite type, corresponding to different evolutionary stages of carbonatite magmatism based on the REE and trace element data. The latter always has higher REE content. The origin of the ore-hosting dolomite at Bayan Obo has been addressed in various models, ranging from a normal sedimentary carbonate rocks to volcano-sedimentary sequence, and a large carbonatitic intrusion. More geochemical evidences show that the coarse-grained dolomite represents a Mesoproterozoic carbonatite pluton and the fine-grained dolomite resulted from the extensive REE mineralization and modification of the coarse-grained variety. The ore bodies, distributed along an E–W striking belt, occur as large lenses and underwent more intense fluoritization and fenitization. The first episode mineralization is characterized by disseminated mineralization in the dolomite. The second or main-episode is banded and/or massive mineralization, cut by the third episode consisting of aegirine-rich veins. Various dating methods gave different mineralization ages at Bayan Obo, resulting in long and hot debates. Compilation of available data suggests that the mineralization is rather variable with two peaks at ∼1400 and 440 Ma. The early mineralization peak closes in time to the intrusion of the carbonatite dykes. A significant thermal event at ca. 440 Ma resulted in the formation of late-stage veins with coarse crystals of REE

  5. 诸广花岗岩体南部油洞断裂带辉绿岩脉的Ar-Ar年龄及其地球化学特征%The Ar-Ar Age and Geochemical Characteristics of Diabase Dykes of the Youdong Fault Zone in South of Zhuguang Granite Pluton

    曹豪杰; 黄国龙; 许丽丽; 黄乐真; 王小冬; 吴建勇; 王春双


    The Ar-Ar age of diabase dykes in the Youdong fault zone is 110.6±2.0 Ma,indicating that diabase dykes were emplaced in late Yanshaninan.Diabase is rich in SiO2 (mean value 50.65%),Al2O3 (mean value 15.10%),CaO(mean value 10.48%),MgO(mean value 7.80%) and poor in TiO2 (mean value 1.13%),FeOt(mean value 9.90%),Na2O(mean value 2.28%),K2O (mean value 0.90%),and P2O5 (mean value 0.11%.In rare earth elements,it is rich in large-ion lithophile Rb,Th,Ba,K,and poor in Nb,Ta,Zr,Hf,P and Ti.Total rare earth is low,and bear the right-wing-type distribution patten eith obviously Eu deplation(δEu mean value 0.92).Its characteristic is similar with that of active continental margin basalt,and this phenomenon reflects that primitive magma came from relative enrichment of the lithospheric mantle,didn't come from original mantle.%油洞断裂带中辉绿岩脉的全岩Ar-Ar年龄为110.6±2.0 Ma,属于燕山晚期岩浆活动产物.辉绿岩具有较高的SiO2(平均为50.65%)、Al2O3(平均为15.10%)、CaO(平均为10.48%)、MgO(平均为7.80%)含量和较低的TiO2(平均为1.13%)、FeOt(平均为9.90%)、Na2 O(平均为2.28%)、K2O(平均为0.90%)、P2 O5(平均为0.11%)含量.在微量元素方面,大离子元素Rb、Th、Ba、K的富集明显,而Nb、Ta、Zr、Hf、P、Ti显示亏损.稀土元素总量低,轻稀土相对富集,分布模式略呈右倾型,Eu亏损弱(δEu平均为0.92).辉绿岩的上述元素地球化学特征非常相似于活动大陆边缘钙碱性玄武岩,反映原始岩浆来源于受太平洋板块俯冲产生的流体对上覆地幔楔交代改造形成的富集地幔源区.

  6. 赣抚大堤防洪保护区洪水风险图编制洪水分析方案设置研究%Study on setting flood analysis scheme for flood risk mapping of flood protection area of Ganfu Grand Dyke

    张秀平; 丁志雄


    编制洪水风险图是落实防汛工作从"控制洪水"向"洪水管理"转变和开展洪水风险管理的重要基础支撑,也是国内防洪减灾工作中重要的非工程类措施之一.洪水风险图编制是一个复杂的过程,涉及的基础资料较多,所需考虑的要素复杂,而洪水分析方案的设置是洪水风险图编制中至关重要的部分,关系到洪水风险图编制结果的实用性.本文以赣抚大堤防洪保护区为例,从洪水来源、洪水分析频率、洪水组合方式、可能溃口位置、溃口宽度、溃决时机等方面,并权衡实用性和易用性对设计方案优化组合,简述赣抚大堤洪水风险图编制过程中洪水分析方案的设置规则,为江西省及其他地区全面开展洪水风险图编制提供参考.%Flood risk mapping is an important foundation for the implementation of flood control work from flood control to flood management and provides an important foundation support for flood risk management.It is one of the improtant non-engineering measures for flood control and disaster relief in China.Flood risk mapping is a complicated process ,involving much basic informa-tion and the complex factors need to be considered.Flood analysis schemes are one of a vital part of the preparation of flood risk mapping,which is related to the practicality of flood risk mapping results.In this paper,we took flood protectition area of Ganfu Grand Dyke as an example,setting the rules for flood analysis schemes in the process of flood risk mapping of Ganfu Grand Dyke from these aspects ssuch as flood sources,flood analysis frequency,flood combinations,may breach position,breach wideth and out-burst opportunity and weighing the practicality and usability in order to optimize the analysis scheme are stated.It provides a refer-ence for this province and other areas to carry out a comprehensive flood risk mapping.

  7. Mineralogical evolution and REE mobility during crystallisation of ancylite-bearing ferrocarbonatite, Haast River, New Zealand

    Cooper, Alan F.; Collins, Alice K.; Palin, J. Michael; Spratt, John


    Ferrocarbonatites from the lamprophyric Alpine Dyke Swarm, south Westland, New Zealand are composed of dolomite-calcite-albite-hematite and contain interstitial patches dominated by calcite-ancylite-barite-monazite-thorite-albite-aeschynite-analcime, interpreted as modified late-stage segregations. The dominant carbonate in the ferrocarbonatite is a ferroan dolomite that contains vermicular and blocky patches of calcite and a more Fe-rich ankerite. The calcite is interpreted as the product of exsolution or the by-product, with dolomite and hematite, of the oxidation of primary ankerite during interaction with hydrothermal fluids. Late stage ancylite-rich segregations have elevated 87Sr/86Sr compositions relative to host carbonatite suggesting they have crystallised from fluids that have equilibrated with host schist, but with the REE derived from fractionation of ferrocarbonatite. Mineral veining indicates this stage of crystallisation post-dated the ankerite to dolomite replacement. The carbonatites, as inferred from mineral associations, textures and carbonate geothermometry, have a complex history of recrystallisation from late stage, low temperature carbo-hydrothermal fluids. All carbonatitic phases have convex-upward chondrite normalised REE patterns enriched in Nd, and are relatively depleted in lighter LREE and in HREE. Depletion in La and Ce is attributed to either complementary enrichment in felsic magmas during initial separation of carbonatite, or more likely, to subsequent preferentially enhanced mobility of La- and Ce-Cl- complexes in low-temperature aqueous fluids.

  8. Sources and mobility of carbonate melts beneath cratons, with implications for deep carbon cycling, metasomatism and rift initiation

    Tappe, Sebastian; Romer, Rolf L.; Stracke, Andreas; Steenfelt, Agnete; Smart, Katie A.; Muehlenbachs, Karlis; Torsvik, Trond H.


    Kimberlite and carbonatite magmas that intrude cratonic lithosphere are among the deepest probes of the terrestrial carbon cycle. Their co-existence on thick continental shields is commonly attributed to continuous partial melting sequences of carbonated peridotite at >150 km depths, possibly as deep as the mantle transition zone. At Tikiusaaq on the North Atlantic craton in West Greenland, approximately 160 Ma old ultrafresh kimberlite dykes and carbonatite sheets provide a rare opportunity to study the origin and evolution of carbonate-rich melts beneath cratons. Although their Sr-Nd-Hf-Pb-Li isotopic compositions suggest a common convecting upper mantle source that includes depleted and recycled oceanic crust components (e.g., negative ΔεHf coupled with > + 5 ‰ δ7Li), incompatible trace element modelling identifies only the kimberlites as near-primary low-degree partial melts (0.05-3%) of carbonated peridotite. In contrast, the trace element systematics of the carbonatites are difficult to reproduce by partial melting of carbonated peridotite, and the heavy carbon isotopic signatures (-3.6 to - 2.4 ‰ δ13C for carbonatites versus -5.7 to - 3.6 ‰ δ13C for kimberlites) require open-system fractionation at magmatic temperatures. Given that the oxidation state of Earth's mantle at >150 km depth is too reduced to enable larger volumes of 'pure' carbonate melt to migrate, it is reasonable to speculate that percolating near-solidus melts of carbonated peridotite must be silicate-dominated with only dilute carbonate contents, similar to the Tikiusaaq kimberlite compositions (e.g., 16-33 wt.% SiO2). This concept is supported by our findings from the North Atlantic craton where kimberlite and other deeply derived carbonated silicate melts, such as aillikites, exsolve their carbonate components within the shallow lithosphere en route to the Earth's surface, thereby producing carbonatite magmas. The relative abundances of trace elements of such highly

  9. Homosexuals, dykes and queers: political positions in the lesbian and gay movement

    Gerard Coll-Planas


    Full Text Available In this article I aim to explore conflicts among the variety of political projects in the lesbian and gay movement.I base the article on Alberto Mira’s (2004 proposed models for the expression of homosexuality: decadentist, homophile and camp. I discuss the main theoretical and political debates that arise from these models. Firstly, I ask whether life on the margins of mainstream social rules allows gays and lesbians to live a freer existence or merely means internalised homophobia (using Jean Genet’s and Michel Foucault’s approaches as examples. Secondly, I question whether the demand for “normality” entails the creation of new exclusions (following Judith Butler’s approach to normality: Finally, I consider whether camp culture reproduces and/or subverts gender rules (introducing a discussion between Sheila Jeffreys and Judith Butler’s positions. On the basis of this exploration of Mira's three cultural models, I develop a typology of political positions ('normalization of homosexuality', 'transformation' and 'queer', which I apply to the case study of the Catalan lesbian and gay movement.

  10. Homosexuals, dykes and queers: political positions in the lesbian and gay movement

    Coll-Planas, Gerard


    Full Text Available (English In this article I aim to explore conflicts among the variety of political projects in the lesbian and gay movement.I base the article on Alberto Mira’s (2004 proposed models for the expression of homosexuality: decadentist, homophile and camp. I discuss the main theoretical and political debates that arise from these models. Firstly, I ask whether life on the margins of mainstream social rules allows gays and lesbians to live a freer existence or merely means internalised homophobia (using Jean Genet’s and Michel Foucault’s approaches as examples. Secondly, I question whether the demand for “normality” entails the creation of new exclusions (following Judith Butler’s approach to normality: Finally, I consider whether camp culture reproduces and/or subverts gender rules (introducing a discussion between Sheila Jeffreys and Judith Butler’s positions. On the basis of this exploration of Mira's three cultural models, I develop a typology of political positions ('normalization of homosexuality', 'transformation' and 'queer', which I apply to the case study of the Catalan lesbian and gay movement.

  11. The flood, the channels, and the dykes : managing legal information a globalized and digital world

    Breuker, Joost; Casanovas, Pompeu; Klein, Michel C. A.; Francesconi, Enrico


    Information search and retrieval are part of daily routines of the legal profession. Lawyers, judges, prosecutors, and legal clerks usually access a number of electronic resources to browse, search, select, or update legal contents. Legal databases have currently become large digital libraries where the tasks related to information-seeking may sometimes be cumbersome. Adding semantics to support information search may provide significant results in terms of efficiency, efficacy, and user sati...

  12. Are eruptions from linear fissures and caldera ring dykes more likely to produce pyroclastic flows?

    Jessop, D. E.; Gilchrist, J.; Jellinek, A. M.; Roche, O.


    Turbulent volcanic jets are produced by highly-energetic explosive eruptions and may form buoyant plumes that rise many tens of kilometres into the atmosphere to form umbrella clouds or collapse to generate ground-hugging pyroclastic flows. Ash injected into the atmosphere can be transported for many hundreds of kilometres with the potential to affect climate, disrupt global air travel and cause respiratory health problems. Pyroclastic flows, by contrast, are potentially catastrophic to populations and infrastructure close to the volcano. Key to which of these two behaviours will occur is the extent to which the mechanical entrainment and mixing of ambient air into the jet by large (entraining) eddies forming the jet edge changes the density of the air-ash mixture: low entrainment rates lead to pyroclastic flows and high entrainment rates give rise to buoyant plumes. Recent experiments on particle-laden (multi-phase) volcanic jets from flared and straight-sided circular openings suggest that the likelihood for buoyant plumes will depend strongly on the shape and internal geometry of the vent region. This newly recognised sensitivity of the fate of volcanic jets to the structure of the vent is a consequence of a complex dynamic coupling between the jet and entrained solid particles, an effect that has generally been overlooked in previous studies. Building on this work, here we use an extensive series of experiments on multi-phase turbulent jets from analogue linear fissures and annular ring fractures to explore whether the restrictive vent geometry during cataclysmic caldera-forming (CCF) eruptions will ultimately lead a relatively greater frequency of pyroclastic flows than eruptions from circular vents on stratovolcanoes. Our results, understood through scaling analyses and a one-dimensional theoretical model, show that entrainment is enhanced where particle motions contribute angular momentum to entraining eddies. However, because the size of the entraining eddies scales approximately with vent width, the extent of entrainment is reduced as the vent width becomes small in comparison to its length. Consequently, our work shows that for specified mass eruption rates, the high length-to-width ratio vents typical of CCF events are more likely to produce pyroclastic flows. We suggest that the enigmatic trend in the geological record for the largest CCF eruptions to produce pyroclastic flows is an expected consequence of their being erupted through continuous or piece-wise continuous caldera ring fractures.

  13. Palaeointensity determinations on rocks from Palaeoproterozoic dykes from the Kaapvaal Craton (South Africa)

    Shcherbakova, V. V.; Shcherbakov, V. P.; Zhidkov, G. V.; Lubnina, N. V.


    Palaeointensity study of the Proterozoic-Archean volcanic rocks from the Kaapvaal Craton South Africa) are reported. Palaeomagnetic study of this collection was performed earlier by Olsson et al. Electron microscope observations, thermomagnetic and hysteresis measurements indicate the presence of single-domain and pseudo-single-domain (SD-PSD) magnetite grains as the main magnetic mineral. The samples demonstrated a very good stability to heating, the electron micrograph observations revealed magnetite-ilmenite exsolution structure. Palaeointensity determinations were obtained by Coe-modified Thellier procedure. A total 58 samples from 14 sites were studied but only seven samples from one site NL28 of the Early Proterozoic age of 1.9 Ga passed palaeointensity selection criteria. Reliable palaeointensity determinations were obtained by both Thellier and Wilson methods on 18 cubes (subsamples) from site NL28 yielding rather low mean virtual dipole moment (VDM) = (2.82 ± 0.12) ×1022 Am2 which is in agreement with the suggestion of existence of the `Proterozoic dipole low period'.

  14. Effect of dyke construction on water dynamics in the flooding savannahs of Venezuela

    Smith, J.K.; Chacon Moreno, E.J.; Jongman, R.H.G.; Wenting, P.F.M.; Loedeman, J.H.


    In the flooded savannahs water is the main factor determining the ecosystem and its change. During flooding, the level of water and the duration of flooding are highly dependent on the relative height position of the ecosystem unit. To understand the spatial processes in the ecosvstem one must know

  15. Literature survey on the advance detection of dykes in underground coal mine workings.

    Fourie, GA


    Full Text Available .A., Duff, B.M., Owen, T.E. & Spiegel, R.J. 1978. Geophysical hazard detection from the working face : phase one. Interim Technical Report. San Antonio Texas, USA. Southwest Research Institute April 1978. Treadway, J.A., Steeples, D.W. & Miller, R.... New Orleans, Louisiana, 4-6 November 1979. Abstracts in Geophysics, 45(4); 576 (April 1980). Dennen, R.S. & Stroud, W.P. 1991. Radar hazard detection in a coal structure. Mining Engineering, April 1991. Ellerbruch, D.A. & Adams, D.W. 1974...

  16. The East Greenland rifted volcanic margin

    C. Kent Brooks


    Full Text Available The Palaeogene North Atlantic Igneous Province is among the largest igneous provinces in the world and this review of the East Greenland sector includes large amounts of information amassed since previous reviews around 1990.The main area of igneous rocks extends from Kangerlussuaq (c. 67°N to Scoresby Sund (c. 70°N, where basalts extend over c. 65 000 km2, with a second area from Hold with Hope (c. 73°N to Shannon (c. 75°N. In addition, the Ocean Drilling Project penetrated basalt at five sites off South-East Greenland. Up to 7 km thickness of basaltic lavas have been stratigraphically and chemically described and their ages determined. A wide spectrum of intrusions are clustered around Kangerlussuaq, Kialeeq (c. 66°N and Mesters Vig (c. 72°N. Layered gabbros are numerous (e.g. the Skaergaard and Kap Edvard Holm intrusions, as are under- and oversaturated syenites, besides small amounts of nephelinite-derived products, such as the Gardiner complex (c. 69°N with carbonatites and silicate rocks rich in melilite, perovskite etc. Felsic extrusive rocks are sparse. A single, sanidine-bearing tuff found over an extensive area of the North Atlantic is thought to be sourced from the Gardiner complex.The province is famous for its coast-parallel dyke swarm, analogous to the sheeted dyke swarm of ophiolites, its associated coastal flexure, and many other dyke swarms, commonly related to central intrusive complexes as in Iceland. The dyke swarms provide time markers, tracers of magmatic evolution and evidence of extensional events. A set of dykes with harzburgite nodules gives unique insight into the Archaean subcontinental lithosphere.Radiometric dating indicates extrusion of huge volumes of basalt over a short time interval, but the overall life of the province was prolonged, beginning with basaltic magmas at c. 60 Ma and continuing to the quartz porphyry stock at Malmbjerg (c. 72°N at c. 26 Ma. Indeed, activity was renewed in the Miocene with

  17. ESI-VI10 Jost Van Dyke, U.K. Virgin Islands 2000 (Environmental Sensitivity Index Map)

    National Oceanic and Atmospheric Administration, Department of Commerce — Environmental Sensitivity Index (ESI) maps are an integral component in oil-spill contingency planning and assessment. They serve as a source of information in the...

  18. ESI-VI10 Jost Van Dyke, U.K. Virgin Islands 2000 (Environmental Sensitivity Index Map)

    National Oceanic and Atmospheric Administration, Department of Commerce — Environmental Sensitivity Index (ESI) maps are an integral component in oil-spill contingency planning and assessment. They serve as a source of information in the...

  19. Application of Ground Penetrating Radar Surveys and GPS Surveys for Monitoring the Condition of Levees and Dykes

    Tanajewski Dariusz


    Full Text Available This paper analyses the possibility of using integrated GPS (Global Positioning System surveys and ground penetrating radar surveys to precisely locate damages to levees, particularly due to the activity of small fossorial mammals. The technology of intercommunication between ground penetrating radar (GPR and an RTK (Real-Time Kinematic survey unit, and the method of data combination, are presented. The errors which may appear during the survey work are also characterized. The procedure for processing the data so that the final results have a spatial character and are ready to be implemented in digital maps and geographic information systems (GIS is also described.

  20. Application of Ground Penetrating Radar Surveys and GPS Surveys for Monitoring the Condition of Levees and Dykes

    Tanajewski, Dariusz; Bakuła, Mieczysław


    This paper analyses the possibility of using integrated GPS (Global Positioning System) surveys and ground penetrating radar surveys to precisely locate damages to levees, particularly due to the activity of small fossorial mammals. The technology of intercommunication between ground penetrating radar (GPR) and an RTK (Real-Time Kinematic) survey unit, and the method of data combination, are presented. The errors which may appear during the survey work are also characterized. The procedure for processing the data so that the final results have a spatial character and are ready to be implemented in digital maps and geographic information systems (GIS) is also described.

  1. 护砂保堤固我"长城"%Protect the Sand Protect the Dyke Make the "Great Wall" Durable



    @@ 84km长的盐场海堤宛如一条巨龙横卧在黄海海岸线上,它不仅为金桥盐业有限公司挡潮抵浪,同时也保护着赣榆、灌云、新浦、连云两县两区2 000km2、150万人口的生命财产安全.

  2. Dykes of standards supporting polders of data : The practices used in the Netherlands for making archaeological data available and accessible

    Gilissen, V.


    In the Netherlands, the archiving and publication of archaeological research data has led to the establishment of EDNA, the e-Depot for Dutch Archaeology, accommodated at DANS (Data Archiving and Networked Services) EDNA is a collaboration between DANS and

  3. Radiological Mapping of the Alkaline Intrusive Complex of Jombo, South Coastal Kenya by In-Situ Gamma-Ray Spectrometry

    Kaniu, Ian; Darby, Iain G.; Kalambuka Angeyo, Hudson


    Carbonatites and alkaline intrusive complexes are rich in a variety of mineral deposits such as rare earth elements (REEs), including Nb, Zr and Mn. These are often associated with U and Th bearing minerals, including monazite, samarskite and pyrochlore. Mining waste resulting from mineral processing activities can be highly radioactive and therefore poses a risk to human health and environment. The Jombo complex located in Kenya's south coastal region is potentially one of the richest sources of Nb and REEs in the world. It consists of the main intrusion at Jombo hill, three associated satellite intrusions at Mrima, Kiruku and Nguluku hills, and several dykes. The complex is highly heterogeneous with regard to its geological formation as it is characterized by alkaline igneous rocks and carbonatites which also influence its radio-ecological dynamics. In-situ gamma spectrometry offers a low-cost, rapid and spatially representative radioactivity estimate across a range of landscapes compared to conventional radiometric techniques. In this work, a wide ranging radiological survey was conducted in the Jombo complex as follow up on previous studies[1,2], to determine radiation exposure levels and source distributions, and perform radiological risk assessments. The in-situ measurements were carried out using a 2.0 l NaI(Tl) PGIS-2 portable detector from Pico Envirotec Inc integrated with GPS, deployed for ground (back-pack) and vehicular gamma-ray spectrometry. Preliminary results of radiological distribution and mapping will be presented. [1] Patel, J. P. (1991). Discovery and Innovation, 3(3): 31-35. [2] Kebwaro, J. M. et. al. (2011). J. Phys. Sci., 6(13): 3105-3110.

  4. Tectono-magmatic evolution of the younger Gardar southern rift, South Greenland

    Brian G.J. Upton


    Full Text Available The 1300–1140 Ma Gardar period in South Greenland involved continental rifting, sedimentation and alkaline magmatism. The latest magmatism was located along two parallel rift zones, Isortoq–Nunarsuit in the north and the Tuttutooq–Ilimmaasaq–Narsarsuaq zone in the south addressed here. The intrusive rocks crystallised at a depth of <4 km and are essentially undisturbed by later events. Magmatism in the southern zone began with the emplacement of two giant, ≤800 m wide dykes and involved intrusion of transitional olivine basaltic, high Al/Ca magmas crystallising to troctolitic gabbros. These relatively reduced magmas evolved through marked iron enrichment to alkaline salic differentiates. In the Older giant dyke complex, undersaturated augite syenites grade into sodalite foyaite. The larger, c. 1163 Ma Younger giant dyke complex (YGDC mainly consists of structureless troctolite with localised developments of layered cumulates. A layered pluton (Klokkenis considered to be coeval and presumably comagmatic with the YGDC. At the unconformitybetween the Ketilidian basement and Gardar rift deposits, the YGDC expanded into a gabbroic lopolith. Its magma may represent a sample from a great, underplated mafic magma reservoir, parental to all the salic alkaline rocks in the southern rift. The bulk of these are silica undersaturated; oversaturated differentiates are probably products of combined fractional crystallisation and crustalassimilation.A major dyke swarm 1–15 km broad was intruded during declining crustal extension, with decreasing dyke widths and increasing differentiation over time. Intersection of the dyke swarm and E–W-trending sinistral faults controlled the emplacement of at least three central complexes (Narssaq, South Qôroq and early Igdlerfigssalik. Three post-extensional complexes (Tugtutôq,Ilímaussaq and late Igdlerfigssalik along the former rift mark the end of magmatism at c. 1140 Ma. The latter two complexes have

  5. Seeking the mantle contribution for the formation of giant ore deposits: Contemporaneous alkaline lamproites and carbonatites in the Kalmakyr and Muruntau ore districts, Tienshan, Uzbekistan

    Seltmann, Reimar; Choulet, Flavien


    The decline in discoveries of ore deposits contrasted by the rising demand for e-tech metals requires the global mining industry to continuously seek innovation in exploration. Unravelling the source of metals is among the crucial questions in exploration targeting and geologists have often had to recourse to indirect determinations based on the nature of the magma conveying the metals. The relative contributions of mantle and crust in metallogenic processes and the origin of the magmas from either shallow or deep mantle are not fully understood in the current models of ore genesis. To help to resolve this dilemma, research must establish the link between anorogenic (within-plate) and orogenic processes by using a holistic approach featuring crustal processes, mantle dynamics and crust-mantle interactions that may contribute to the magma fertilization. To achieve this, our study focuses on indicators for the involvement of deep-mantle intrusions (lamproites, lamprophyres, etc.), which have the potential to encapsulate pristine samples of the mantle (xenoliths) during magma ascent [1,2]. The Tienshan belt hosting many giant ore deposits is quite exemplary for understanding mantle-crust interactions and identifying the nature of mantle contribution to ore systems. Sr-Nd-Hf-Pb isotope systematics on granitoids [3] showed a variation of crustal to mixed signatures, indicating involvement of both older crustal sources and mantle-derived material, but the mantle source is not clearly assessed. As objects for our case study in Uzbekistan we choose the Kalmakyr Cu-Au porphyry deposit (~ 315 Ma; Chatkal-Kurama continental arc of Middle Tienshan) and the Muruntau orogenic Au deposit (~290 Ma, Turkestan-Alai / Kyzylkum accretionary complex of South Tienshan) to investigate the impact of associated alkaline magmas on the ore-bearing intrusions and mineralization. Field observations and geochronological data shed light on the spatial and temporal relationships between the various geological objects involved in both giant mineral systems. Upper Carboniferous lamproitic pipes have been recognized around the Kalmakyr ore deposit [1]; diamond-bearing lamproites occur near the Muruntau ore deposit and are contemporaneous to the Murun granite [2]. Indicator minerals of deep crustal and mantle origin have been identified within xenoliths hosted by the ore-bearing intrusions and the dikes and pipes spatially and temporally associated to the giants. SEM and CT scanning observations allow for revealing the shape and internal texture of indicator minerals and their relations (inclusion, interstitial or bulk minerals). Microanalysis (EPMA and LA-ICPMS) of indicator minerals is used to estimate the physico-chemical conditions of their formation and track the mantle involvement in magma fertilization. Results permit clues on the mantle contribution in ore formation during the late collisional to post-collisional stages of the Tienshan, and, based on complementary comparisons with other ore systems, to refine exploration models. References: [1] Yusupov, R.G.; Stanley, C.J.; Welch, M.D.; Spratt, J.; Cressey, G.; Rumsey, M.S.; Seltmann, R.; Igamberdiev, E., 2009: Mavlyanovite, Mn5Si3: a new mineral species from a lamproite diatreme, Chatkal Ridge, Uzbekistan. Mineralogical Magazine 73, 43-50. [2] Golovko, A. V.; Divaev, F. K., 2010: Ore mineralisation of the Karashokho diatreme, western Uzbekistan. Applied Earth Science 119.2: 100. [3] Dolgopolova, A.; Seltmann, R.; Armstrong, R.; Belousova, E.; Pankhurst, R.; Konopelko, D.; Koneev, R., 2013: Sr-Nd-Hf-Pb Isotope Mapping of Tien Shan in Uzbekistan. Mineralogical Magazine 77.5: 1001.

  6. The Compositional Evolution of the Phyllosilicates in the Lateritic Profile of the Catalão I Ultramafic Alkaline-carbonatitic Complex (GO)

    Rogério Guitarrari Azzone; Excelso Ruberti


    The compositional evolution of the phyllosilicates in the lateritic profile of the Catalão I ultramafic alkaline-carbonatiticcomplex (GO) is proposed in this work based on petrographic and X-ray diffraction analysis, as well as, chemical compositionobtained by WDS electron microprobe. The micaceous minerals found in unweathered rocks are classified as phlogopites(with different parageneses) and tetraferriphlogopites (metasomatic products). In the levels of altered rocks and isalteriticsaproli...

  7. The Compositional Evolution of the Phyllosilicates in the Lateritic Profile of the Catalão I Ultramafic Alkaline-carbonatitic Complex (GO

    Rogério Guitarrari Azzone


    Full Text Available The compositional evolution of the phyllosilicates in the lateritic profile of the Catalão I ultramafic alkaline-carbonatiticcomplex (GO is proposed in this work based on petrographic and X-ray diffraction analysis, as well as, chemical compositionobtained by WDS electron microprobe. The micaceous minerals found in unweathered rocks are classified as phlogopites(with different parageneses and tetraferriphlogopites (metasomatic products. In the levels of altered rocks and isalteriticsaprolite, the phyllosilicates derived from micas are vermiculite and regular interstratified phlogopite-vermiculite (whichformation and characteristics are similar to hydrobiotite, characterizing a main vermiculitization process in this profile.Subordinately, in the upper portions and punctual areas of isalteritic saprolite, the alteration of the vermiculitized phlogopitegenerates smectitic products, which are characterized mainly by the occurrence of expansible regular interstratified mineraland even smectite. Kaolinite occurs on the top of the isalteritic saprolite and on the alloteritic level. The evolution sequenceof the phyllosilicates in the weathering profile of the Catalão I complex presents the following formation order: phlogopite,interstratified phlogopite-vermiculite, vermiculite, smectitic products (expansible interstratified minerals of local occurrence, smectite and kaolinite, of which, the last two are probably associated to supergene processes. This sequence is compatible with the most recent theories for the formation of clay minerals in soils. The main differences between the phlogopites and their products ofvermiculitic alteration are related to a significant decrease of K+ and oxidation of Fe2+, characteristic changes of the vermiculitizationprocess. In the specific case of vermiculites, the interlayer site is filled mainly by Mg2+. In addition to that, the presence of interstratified minerals (intermediate alteration products is a key indicator of relatively recent and low-altered weathering profiles.

  8. Combined Paleomagnetic And Petromagnetic Study Of Oligocene Dyke Swarms From Tecalitlan Area: Implications For Relative Motion Of Jalisco And Michoacan Blocks

    Aguilar Reyes, B.; Rosas Elguera, J.; Gogichaishvili, A.; Alva Valdivia, L.


    Results of detailed paleomagnetic studies from Tecalitlan area are reported. Sexteen sites (about 150 oriented samples) were collected including one Ar-Ar dated ignimbrite. Rock-magnetic experiments permitted identification of the magnetic carriers and assessment of the paleomagnetic stability. Continuous susceptibility measurements vs temperature, in most cases yield reasonably reversible curves with Curie points close to that of magnetite. Judging from the ratios of hysteresis parameters, all samples appear to fall in the pseudo- single domain grain-size region, probably indicating a mixture of multi-domain and a significant amount of single-domain grains. Reliable paleomagnetic directions were obtained for 14 sites. The mean inclination is in reasonably good agreement with the expected value, as derived from reference poles for the stable North America. Declination is significantly different from that expected which may suggests a counterclockwise tectonic rotation of 19°.

  9. Was the Devonian geomagnetic field dipolar or multipolar? Palaeointensity studies of Devonian igneous rocks from the Minusa Basin (Siberia) and the Kola Peninsula dykes, Russia

    Shcherbakova, V. V.; Biggin, A. J.; Veselovskiy, R. V.; Shatsillo, A. V.; Hawkins, L.; Shcherbakov, V. P.; Zhidkov, G. V.


    Defining variations in the behaviour of the geomagnetic field through geological time is critical to understanding the dynamics of Earth's core and its response to mantle convection and planetary evolution. Furthermore, the question of whether the axial dipole dominance of the recent palaeomagnetic field persists through the whole of Earth's history is fundamental to determining the reliability of palaeogeographic reconstructions and the efficacy of the magnetosphere in shielding Earth from solar wind radiation. Previous palaeomagnetic directional studies have suggested that the palaeofield had a complex configuration in the Devonian period (419-359 Ma). Here we present new palaeointensity determinations from rocks aged between 408 and 375 Ma from the Minusa Basin (southern Siberia), and the Kola Peninsula to investigate the strength of the field during this enigmatic period. Palaeointensity experiments were performed using the thermal Thellier, microwave Thellier, and Wilson methods on 165 specimens from 25 sites. Six out of eight successful sites from the Minusa Basin and all four successful sites from the Kola Peninsula produced extremely low palaeointensities (uniformitarian view of the palaeomagnetic field: field intensities of nearly an order of magnitude lower than Neogene values (except during relatively rare geomagnetic excursions and reversals) together with the widespread appearance of strange directions found in the Devonian suggest that the Earth's field during this time may have had a dominantly multipolar geometry. A persistent, low intensity multipolar magnetic field and associated diminished magnetosphere would increase the impact of solar particles on the Earth's magnetosphere, ionosphere and atmosphere with potential major implications for Earth's climate and biosphere.

  10. Data report: The effect of dyke reinforcement on benthic species in the Oosterschelde: T0 Cluster 2 and T1 Cluster 1

    Brink, van den A.M.; Hartog, E.


    In dit rapport zijn de data van de bodembewonende levensgemeenschappen beschreven voor locaties in de Oosterschelde voorafgaand aan oeververdedigingsactiviteiten (T0 Cluster 2) en locaties in de Oosterschelde in de periode na oeverversterkingen (T1 Cluster 1). Op de Cluster 1 locaties zijn de oevers

  11. The preliminary unit price analysis of the vertical seepage control for the dyke%垂直防渗单价初析

    杨国顺; 刘伟; 党爱琴



  12. The Chemistry of Niobium Mineralisation at Bayan Obo,Inner Mongolia, China: Constraints on the Hydrothermal Precipitation and Alteration of Nb-Minerals%The Chemistry of Niobium Mineralisation at Bayan Obo,Inner Mongolia,China:Constraints on the Hydrothermal Precipitation and Alteration of Nb-Minerals

    Martin SMITH; John SPRATT


    As well as world class Fe and REE resources the Bayan Obo mineral deposits also hosts significant niobium resources (estimated as 2.2 Mt Nb with an average grade of 0.13 wt% Nb).Niobium in this study is primarily hosted in aeschynite-(Ce) and (Nd),but with subsidiary amounts of pyrochlore,fergusonite-(Ce),fersmite and columbite.Here we report on the paragenetic and textural setting of aeschynite,pyrochlore and fergusonite in the main ore bodies and in a carbonatite dyke.Niobium in a carbonatite sample is hosted in a phase tentatively (due to significant Ca,Mn and Ti contents) identified as fergusonite-(Ce).Aeschynite occurs overgrowing foliation in banded ores,in fractures and vugs in aegirine-rich rocks and in calcite veins.The composition in all settings is similar,but some examples in banded ores develop significant zonation in Y,Th and the REE,inferred to relate to buffering of halogen acid species to low levels by dissolution and fluoritisation of calcite,and the preferential precipitation of LREE from solution due to lower mineral solubility products compared to the HREE.Although lower in total concentration the ratios of REE in pyrochlore are similar to those of aeschynite and suggest the same metal source.The crystallisation of pyroehlore probably relates to growth in paragenetic settings where carbonates had already been eliminated and hence the buffering of F-species activities in the hydrothermal fluid was reduced.Both aeschynite and pyrochlore show evidence of alteration.Primary alteration of aeschynite resulted in leaching of A-site cations (Ca,REE,Th) and Nh,addition of Fe,and ultimately replacement by Ba-Ti phases (baotite and bafertisite).Secondary,metamictisation enhanced,possibly supergene alteration of pyrochlore resulted in hydration,leaching of A-site cations leading to the development of lattice vacancies and increases in Si.The presence of hydrothermal Nb resources at Bayan Obo suggests there may be potential for further Nb discoveries in

  13. Origin of REE-rich ferrocarbonatites in southern Siberia (Russia): implications based on melt and fluid inclusions

    Prokopyev, Ilya R.; Borisenko, Alexander S.; Borovikov, Andrey A.; Pavlova, Galina G.


    Fe-rich carbonatites with a mineral assemblage of ankerite-calcite or siderite are widespread in southern Siberia, Russia. The siderite carbonatites are associated with F-Ba-Sr-REE mineralization and have a 40Ar/39Ar age of 117.2 ± 1.3 Ma. Melt and fluid inclusions suggest that the carbonatites formed from volatile-rich alkali- and chloride-bearing carbonate melts. Ankerite-calcite carbonatites formed from carbonatite melt at a temperature of more than 790 °C. The ferrocarbonatites (the second phase of carbonatite intrusion) formed from a sulfate-carbonate-chloride fluid phase (brine-melt) at >650 °C and ≥360 MPa. The brine-melt fluid phase had high concentrations of Fe and LREEs. A subsequent hydrothermal overprint contributed to the formation of economically important barite-Sr-fluorite-REE mineralization in polymict siderite breccia.

  14. Caracterização da parcela magnética de minério fosfático de carbonatito Characterization of the magnetic phase from carbonatitic phosphate ore

    Alysson A. Borges


    Full Text Available O rejeito magnético do Complexo Mineração de Tapira, Tapira - MG, onde se processa rocha fosfática, foi estudado. Suas principais características físicas, químicas e mineralógicas foram determinadas, assim como suas respostas a processos de concentração. A primeira etapa do trabalho envolveu análise granulométrica, análise química, difratometria de raios X, espectroscopia Mössbauer, microscopia ótica e microscopia eletrônica de varredura. Na segunda etapa, ensaios de separação magnética, flotação e lixiviação ácida foram realizados. O material sob estudo revelou-se composto essencialmente por magnetita, hematita (martita e ilmenita. A separação magnética resultou em recuperação metalúrgica de ferro acima de 96 %. Sabão sódico de ácido graxo vegetal (Hidrocol deu melhores resultados no processo de flotação, comparado ao desempenho de amina, quando empregados como coletores de silicatos e apatita, visando à depuração dos minerais portadores de ferro. A atrição preliminar ao condicionamento não influenciou sensivelmente a flotação. Os ensaios de lixiviação visaram a eliminação de fósforo, contaminante crítico nos minérios de ferro. O ácido acético extraiu 0,41 % do fósforo presente, enquanto o ácido clorídrico extraiu em torno de 73 % do fósforo. Estudos ulteriores de otimização de tais ensaios são recomendados, buscando o uso do material sob estudo em siderurgia.The characterization of the magnetic fraction of a tail from phosphate rock processing was done. Samples were from Tapira, in Minas Gerais, Brazil. The main physical, chemical and mineralogical properties, as well as this material response to separation processes were determined. The first part of this work encompasses the mineralogical characterization (determination of particle size distribution, X-ray diffraction, Mössbauer spectroscopy, optical microscopy and scanning electron microscopy. In the second part, concentration tests by magnetic separation, flotation and acid leaching were carried out. The iron-bearing material is composed predominantly of magnetite, hematite and ilmenite. Wet low intensity magnetic separation has reached iron recovery above 96 %. As far as flotation is concerned, fatty acid soap from vegetal oil (Hidrocol as a collector for silicates and apatite was better than amine. Attrition or scrubbing prior to conditioning seems not to affect flotation performance in this case. Acetic acid has extracted only 0.41 % of the phosphorus, and hydrochloric acid has depleted 73.05 % of the phosphorus in the samples under leaching.

  15. 安哥拉Bonga碳酸岩型铌矿床地质地球化学特征及成因%Geology, geochemistry and genesis of the Bonga carbonatite-type niobium deposit, Angola

    章永梅; 顾雪祥; 彭义伟; 郑硌; 张岩; 高海军; 董树义



  16. Hf isotope evidence for a hidden mantle reservoir

    Bizzarro, Martin; Simonetti, A.; Stevenson, R.K.


    High-precision Hf isotopic analyses and U-Pb ages of carbonatites and kimberlites from Greenland and eastern North America, including Earth's oldest known carbonatite (3 Ga), indicate derivation from an enriched mantle source. This previously unidentified mantle reservoir-marked by an unradiogeni...

  17. Tapiolite from the Koktokay No.3 Rare Metal Granitic Pegmatite Dyke, Altai, Xinjiang Autonomous Region%新疆阿尔泰可可托海3号伟晶岩脉重钽铁矿研究

    张爱铖; 王汝成; 胡欢



  18. Test and Analysis on Soil Characteristics for the South Main Dyke of Jingjiang River%荆南长江干堤土性试验研究及分析

    周小文; 何晓民; 龚壁卫


    In coordination of the construction of concealed work of levee project, the research on the soil quality of Jingnan levee in Hubei province was carried out through test. The results demonstrate: ① the Jingnan levee embankment is in bad quality, the compaction degree of most levee sections doesn't reach 92%; the average compressive coefficient of the levee backfilled soils is about 0.3 MPa; the seepage coefficients are 10\\+-5~10\\+-6 cm/s generally; the levee body was compacted unevenly; ② the soil layers of the levee foundation are distributed complicatedly and generally in low density; the void ratios of various soils are mostly in 0.7~1, indicating that the foundation soils are generally in loose state; ③ the pH value of levee body and foundation is 7.05~8.95, attributing to weak alkaline and not producing significant influence on liquid-plastic limit and shear strength of soils, the content of strongly soluble salt of levee foundation soils is 0.01%~0.52% and will not produce great influence on the mechanical behaviours of soils.

  19. Evolution of deformation and stress changes during the caldera collapse and dyking at Bárdarbunga, 2014-2015: Implication for triggering of seismicity at nearby Tungnafellsjökull volcano

    Parks, Michelle Maree; Heimisson, Elías Rafn; Sigmundsson, Freysteinn; Hooper, Andrew; Vogfjörd, Kristín S.; Árnadóttir, Thóra; Ófeigsson, Benedikt; Hreinsdóttir, Sigrún; Hjartardóttir, Ásta Rut; Einarsson, Páll; Gudmundsson, Magnús Tumi; Högnadóttir, Thórdis; Jónsdóttir, Kristín; Hensch, Martin; Bagnardi, Marco; Dumont, Stéphanie; Drouin, Vincent; Spaans, Karsten; Ólafsdóttir, Rósa


    Stress transfer associated with an earthquake, which may result in the seismic triggering of aftershocks (earthquake-earthquake interactions) and/or increased volcanic activity (earthquake-volcano interactions), is a well-documented phenomenon. However limited studies have been undertaken concerning volcanic triggering of activity at neighbouring volcanoes (volcano-volcano interactions). Here we present new deformation and stress modelling results utilising a wealth of diverse geodetic observations acquired during the 2014-2015 unrest and eruption within the Bárdarbunga volcanic system. These comprise a combination of InSAR, GPS, LiDAR, radar profiling and optical satellite measurements. We find a strong correlation between the locations of increased seismicity at nearby Tungnafellsjökull volcano and regions of increased tensile and Coulomb stress changes. Our results suggest that stress transfer during this major event has resulted in earthquake triggering at the neighbouring Tungnafellsjökull volcano by unclamping faults within the associated fissure swarm. This work has immediate application to volcano monitoring; to distinguish the difference between stress transfer and new intrusive activity.

  20. Geochemical Characteristics of the Late Paleozoic Diabase Dyke Swarms of Changmaohezi from Western Liaoning, Northeast China%辽西晚古生代长茂河子辉绿岩墙群的地球化学特征

    李伍平; 李献华


    根据全岩K-Ar年龄(287.5~243.6 Ma),辽西朝阳长茂河子辉绿岩墙群形成于晚古生代.这些辉绿岩分为低铁钛辉绿岩和高铁钛辉绿岩2种,以低铁钛辉绿岩为主.低铁钛辉绿岩以低TiO2(<2%)、FeOt(12.39%~15.33%)、V(227~335 μg/g)、Sc(24~36μg/g)含量和高的SiO2(45.61%~47.72%)、Al2O3(12.51%~16.71%)、MgO(6.66%~9.31%)、K2O(0.57%~2.39%)、Cr(107~177μg/g)和Ni(96~235 μg/g)含量,以及低Ti/Y(327~496)和Ti/Zr(69~114)比值为特征,类似于大陆拉斑玄武质岩石;高铁钛辉绿岩以高的TiO2(5%~6%)、FeOt(22.13%~22.16%)、V(850~859μg/g)、Sc(51~52μg/g)含量和低的SiO2(42.88%~44.90%)、Al2O3(11.53%~11.57%)、MgO(5.15%~5.29%,Mg#=0.32)、K2O(0.48%~0.51%)、Cr(<2 μg/g)和Ni(<30μg/g)含量及高的Ti/Y(1 046~1 106)、Ti/Zr(250~263)比值为特征,类似于Skaergaard侵入体.这些辉绿岩相对富集Rb、Th、U、Pb、Ti和轻稀土元素,而相对亏损Ba、Sr、P和Nb、Ta.εNd(t)(-6.43~-4.12)、εSr(t)(42.94~64.19)显示Sr-Nd同位素组成较为均匀,并反映它们源于富集岩石圈地幔.认为长茂河子辉绿岩形成于富集岩石圈地幔的部分熔融,经历了岩浆结晶分异与地壳混染作用.高铁钛辉绿岩和低高铁钛辉绿岩形成环境不同,前者形成于相对低氧逸度或相对封闭的结晶环境中.

  1. 关于堤防工程设计标准和超标准运用的讨论%Design standard and paranormal utilization of dyke projects

    张家发; 李青云



  2. 基于Monte-Carlo统计技术的堤防设计参数指标选值方法研究%Research on the Method for Selecting Design Parameters of Dyke Based on Monte-Carlo Statistic Technique

    李金都; 周志芳; 宋汉周; 张发明; 周益民



  3. A large scale investigation into changes in coal quality caused by dolerite dykes in Secunda, South Africa-implications for the use of proximate analysis on a working mine

    Bussio, John P.; Roberts, James R.


    The coalfields of South Africa contain numerous dolerite intrusions, which affected the quality of the surrounding coal through thermal processes, commonly believed to be controlled by the size of the magmatic body. Data gathered from a working coalfield in Secunda, South Africa, suggest that the relationship between intrusive sills and coal is complex and factors other than intrusion width must be considered in relation to the contact metamorphic effect. The study area contains multiple dolerite intrusions of Karoo age, of which three intrusions occur as sills intruded close to the main coal seam of the. A large database (>8000 boreholes) of coal quality data was used to investigate the presence or absence of a change in coal quality relative to dolerite proximity. Reduction in coal quality was defined using three proximate analysis values, namely the ash, volatile content and dry ash free volatile (DAFV) as defined in the coal industry. The resultant investigation showed no correlation between the position and thickness of the dolerites, and changes in coal quality as measured by proximate analysis. In the absence of a linear relationship between coal quality and dolerite proximity, two processes are proposed to explain the absence of the contact metamorphic effects expected from previous studies. Firstly dolerite emplacement dynamics may influence the size of the metamorphic aureole produced by an intrusion, invalidating intrusion size as a measure of thermal output. Secondly, hydrothermal fluids mobilised by the dolerite intrusions, either from the country rock or the intrusion itself may percolate through the coal and act as the metamorphic agent responsible for changing coal quality, by dissolving the volatile and semi-volatile components of the coal and transporting them to other locations. These two processes are sufficient to explain the lack of a clear "metamorphic effect" related to the dolerite intrusions. However, the perceived lack of a clear correlation between the coal quality parameters and the metamorphic effects associated with dolerite intrusion may also reflect the inadequacies of proximate analysis techniques in quantifying geological processes within the coal.

  4. Retraction notice to "Ca. 2.5 billion year old mafic dykes in western Shandong Province: Implications for hybridization between subducted continental crust and the North China Craton, China"

    Liu, Shen; Feng, Caixia; Zhai, Mingguo; Hu, Ruizhong; Gao, Shan; Lai, Shaocong; Zou, Haibo; Yan, Jun


    This article has been retracted: please see Elsevier Policy on Article Withdrawal. This article has been retracted at the request of the Editors-in-Chief. The article duplicates significant parts of a paper that had already appeared in, and was withdrawn from Precambrain Research (") One of the conditions of submission of a paper for publication is that authors declare explicitly that the paper is not under consideration for publication elsewhere. Re-use of any data should be appropriately cited. As such this article represents a severe abuse of the scientific publishing system. The scientific community takes a very strong view on this matter and apologies are offered to readers of the journal that this was not detected during the submission process.

  5. The quest to understand Pb loss in baddeleyite

    Davies, J.; Seydoux-Guillaume, A. M.; Heaman, L. M.; Schaltegger, U.


    Baddeleyite (ZrO2) is a trace phase dominantly found in mafic rocks that incorporates U into its crystal structure whilst rejecting Pb, similar to zircon. U-Pb geochronology using baddeleyite typically yields concordant or close to concordant results whereas untreated zircon from the same samples with similar U concentrations record large and variable degrees of discordance (Davies and Heaman, 2014). Baddeleyite therefore should be an ideal geochronometer in mafic rocks, however, high precision U-Pb analysis of baddeleyite often finds age dispersions greater than expected from simple cooling models (Bloch et al. 2014) suggesting that the ages of some or all of the crystals have experienced open system behaviour. Here we attempt to structurally, chemically and gechronologically characterize a suite of baddeleyite crystals from gabbroic sills, dolerite dykes, carbonatites and metamorphosed limestones with an age range of 2 Ga. We use TEM, Raman spectroscopy, elemental analysis, electron imaging and U-Pb geochronology to investigate open system behaviour in baddeleyite with the aim of determining how Pb is lost from baddeleyite crystals and how to identify it prior to U-Pb analysis. None of the crystals analysed show evidence for fluid alteration, mineral or fluid inclusions and all have very low trace element concentrations. The TEM analysis show the all of the baddeleyite crystals are fully crystalline and non-metamict. However, older crystals show evidence of lattice distortion probably related to Frenkel pairs similar to monazite (see Seydoux-Guillaume et al. 2002). Raman spectral analysis of the same crystals show band broadening, intensity loss and the appearance of new bands suggesting that the short range order of the crystals is significantly altered, and this disturbance correlates with alpha dose. Based on our exhaustive analysis of different baddeleyite crystals, we determine the most likely causes of open system behaviour, and also suggest the best ways

  6. Paraná-Etendeka lithosphere modeling according to GOCE observations and geophysical constraints: improvement of PERLA project

    Mariani, Patrizia; Braitenberg, Carla


    One of the challenges of the European Space Agency (ESA) is to improve knowledge of physical properties and geodynamic processes of the lithosphere and the Earth's deep interior, and their relationship to the Earth-surface changes. PERLA project is a part of the challenge of ESA's Living Planet program to investigate the Solid Earth, and in particular the lithosphere of the Paraná-Etendeka Large Igneous Province (LIP). At the present stage the study is focusing on the upper mantle, the source of the magma. The aim is to motivate the asymmetry of the shallow volcanic effusion of the Early Cretaceous tholeiitic magmatism, that in Paraná is wide, thick and represented by the basaltic layer of Serra Geral Formation, while in Etendeka it is rare and spanned. Viceversa the alkaline magmatism shows similar effusions along the region with dyke swarms and associated alkaline and alkaline-carbonatite complexes from Early Creataceous to Paleogene age. ESA's Living Planet program offers a suite of scientific satellites, the Earth Explorers, and in this context PERLA adopts the newest GOCE satellite mission products. The Marussi tensor field and especially its vertical component show a positive anomaly along the coastline sector of both the western and eastern Atlantic Ocean. Positive anomalies are also related to the deeper Moho under the northern part of Paraná basin, in South America (SAM) and the Etendeka continental part. Here we aim to define the detail of masses between crust and upper mantle by modeling the Marussi Tensor components and the invariants. The invariants are easier to understand because they are independent of the reference system. The forward model uses Tesseroids. The density model is compared with recent seismologic models, and is performed according to the results provided by the physical laws governing rock densities and seismic velocity of lithosphere in function of temperature and pressure combined with laboratory measurements of a great number of

  7. Structural and petrogenetical insights of the crustal plumbing system on Santorini Volcano, Greece

    Drymoni, Kyriaki; Browning, John; Gudmundsson, Agust


    Magma plumbing systems represent the magma transport and storage from the source in the mantle, through the crust, to the surface in a volcanic eruption. Characterising the different aspects of shallow crustal magma storage, the associated magma-crust interaction as well as the arrangement and chemistry of dykes and eruptive units are of key importance to help constrain the behaviour of individual volcanoes. Santorini is an active volcano that hosts a crustal magma plumbing system which has been disturbed by several caldera collapse episodes. To study this system, we have undertaken a field campaign at the northern part of the island. We have mapped, in detail, sections of the northern caldera wall with a specific interest in the dyke swarm, associated lavas and eruptive units which are partially cut by a series of historic caldera collapses. Preliminary results show that most of the studied dykes strike mostly N-S except 4 dykes which strike NW-SE. In contrast, the caldera strikes E-W in the northernmost section of Santorini. Dyke thickness ranges between 20 cm - 8m but the average thickness is 0.8 m. Most of the dykes studied are vertical to sub-vertical, only 5 dykes dip at angles less than 60 degrees. Compositionally the dykes range from basaltic to rhyolitic and their textures are glomeroporphyric to aphanitic. By coupling the field and geochemical data with numerical and analytical models we aim to 1) understand the distribution of stresses within the edifices, 2) to define and address the variables that contribute to dyke initiation, propagation and lead to a volcanic eruption, 3) group the different populations of dykes based on their composition, thickness and orientation, 4) find the different populations of eruptive units based on their lithology and composition and 5) discover the relationship (cross-cutting) between eruptive units and dykes, which help to constrain the timing of dyke propagation and the relative ages of the dykes.

  8. Mineralogy, morphology and crystal-chemistry of the monazite from Catalao 1 (Goias, Brazil); Mineralogia, morfologia e cristaloquimica da monazita de Catalao 1 (Goias, Brazil)

    Toledo, Maria Cristina Motta de; Oliveira, Sonia Maria Barros de; Ferrari, Viviane Carillo [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias]. E-mails:;; Fontan, Francois; Parseval, Philippe de [Universite Paul Sabatier, Toulouse (France). Lab. Mineralogie et Cristallographie]. E-mails:;


    The Catalao alkaline carbonatite complex hosts a number of mineral resources including monazite. This mineral is a common accessory phase in two lithological units: carbonatite and silexite. Textural evidence suggest that monazite replaced carbonates in the carbonatite and crystallized simultaneously with quartz in the silexite. Monazite was resistant to the strong laterization that affected the massif, except for the incipient transformation into gorceixite or cerianite. In both carbonatite and silexite, monazite occurs as a complex aggregate of sub-micrometric crystals, showing unusual morphological and chemical characteristics. It contains Ca, Sr, and Ba in the A-site, and shows a certain degree of hydration indicated by ATD and IV data. Structural formulae calculated on the basis of sum of cations=1 show a moderate ionic deficiency in the anionic site. Rietveld refinement indicated poor crystallinity. Notwithstanding these peculiar characteristics, cell dimensions are similar to those of standard monazite. (author)

  9. Mineral potential for incompatible element deposits hosted in pegmatites, alkaline rocks, and carbonatites in the Islamic Republic of Mauritania (phase V, deliverable 87): Chapter Q in Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II)

    Taylor, Cliff D.; Giles, Stuart A.


    Review of PRISM-I documents and the National inventory of mineral occurrences suggests that resources of U, Th, Nb, Ta, Be, rare earth elements (REEs) and fluorite are known in Mauritania and have been exploited in the past at the Bou Naga alkaline complex. Several different deposit types are indicated by the available data. Pegmatitic veins are recorded in several areas of the Archean and Paleoproterozoic portions of the Rgueïbat Shield and are prospective for resources of Li, Be, Nb, Ta, U, Th, and REEs. Over 150 beryl pegmatites are known in the Khnefissat and Inkebden areas of the Chami greenstone belt, and additional concentrations of pegmatites are known in the Guelb Nich Sud area of the Sebkhet Nich greenstone belt and in the northeastern part of the Amsaga Complex. Due to the small size of these deposits, they are unlikely to be economic unless additional value can be gained by processing contained minerals for their industrial uses.

  10. Carbonate-silicate melt immiscibility, REE mineralising fluids, and the evolution of the Lofdal Intrusive Suite, Namibia

    Bodeving, Sarah; Williams-Jones, Anthony E.; Swinden, Scott


    The Lofdal Intrusive Suite, Namibia, consists of calcio-carbonatite and silica-undersaturated alkaline intrusive rocks ranging in composition from phono-tephrite to phonolite (and nepheline syenite). The most primitive of these rocks is the phono-tephrite, which, on the basis of its Y/Ho and Nb/Ta ratios, is interpreted to have formed by partial melting of the mantle. Roughly linear trends in major and trace element contents from phono-tephrite to phonolite and nepheline syenite indicate that the latter two rock types evolved from the phono-tephrite by fractional crystallisation. The nepheline syenite, however, has a lower rare earth element (REE) content than the phonolite. The carbonatite has a primitive mantle-normalised REE profile roughly parallel to that of the silica-undersaturated alkaline igneous rocks, although the absolute REE concentrations are higher. Like the phono-tephrite, it also has a mantle Y/Ho ratio. However, the Nb/Ta and Zr/Hf ratios are significantly higher. Moreover, the carbonatite displays strong negative Ta, Zr and Hf anomalies on spidergrams, whereas the silicate rocks display positive anomalies for these elements. Significantly, this behaviour is predicted by the corresponding carbonatite-silicate melt partition coefficients, as is the behaviour of the REE. Based on these observations, we interpret the carbonatite to represent an immiscible liquid that exsolved from the phono-tephrite or possibly the phonolite melt. The result was a calcio-carbonatite that is enriched in the heavy REE (HREE) relative to most other carbonatites. Fluids released from the corresponding magma are interpreted to have been the source of the REE mineralisation that is currently the target of exploration.

  11. On-Board GPS Clock Monitoring for Signal Integrity


    Dyke, K. Kovach , J. Kraemer, J. Lavrakas, J. P. Fernow, J. Reese, and N. Attallah, 2003, “GPS Integrity Failure Modes and Effects Analysis,” in...California, USA (Institute of Navigation, Alexandria, Virginia), pp. 689-703. [9] K. Van Dyke, K. Kovach , J. Lavrakas, and B. Carroll, 2004

  12. Multicenter Clinical Trial of Keratin Biomaterial for Peripheral Nerve Regeneration


    hydrogel scaffolds. Tissue Eng Part A 2011:17(11-12):1499-505 Lin YC, Ram adan M, Van Dyke, M, Kokai LE, Philips BJ, Rubin JP, Marra KG. Keratin gel f...Ram adan M, Van Dyke, M, Kokai LE, Philips BJ, Rubin JP, Marra KG. Keratin gel f iller for peripheral nerve repair in a rodent sciatic nerve injury

  13. Thermal history from Pocos de Caldas alkaline massif, SP/MG , Brazil and dyke rich margins using apatite fission track analysis; Historia termica do macico alcalino de Pocos de Caldas (SP/MG) e adjacencias atraves da analise de datacao por tracos de fissao em apatitas

    Franco, Ana Olivia Barufi; Godoy, Daniel Francoso de [UNESP, Rio Claro, SP (Brazil). Pos-Graduacao em Geociencias. Dept. de Petrologia e Metalogenia]. E-mail:; Hackspacher, Peter Christian; Ribeiro, Luis Felipe Brandini [UNESP, Rio Claro, SP (Brazil). Dept. de Petrologia e Metalogenia; Guedes, Sandro [Universidade Estadual de Campinas, SP (Brazil). Instituto de Fisica Gleb Wataghin


    The South American Platform in southeastern Brazil records a long history of tectonic magmatic and uplift events, which resulted from the opening of the South Atlantic Ocean, Cretaceous reactivation and epirogeneic processes. Specific manifestations include the basic magmatism of the Serra Geral Formation of the Parana Basin and alkaline magmatism of Pocos de Caldas - Cabo Frio Lineament, as well as the uplift of the Serra da Mantiqueira and Serra do Mar mountain ranges. Thermo tectonic and geochronological studies using the K-Ar method and apatite fission track analysis in samples of the Pocos de Caldas alkaline massif show an initial evolution beginning 89 Ma related to a tectonic uplift, interpreted as related to the intrusion's doming. This was followed by an important episode of rapid cooling related to the formation of the massif. At the same time, the mountains that surround the massif record heating events in response to the alkaline intrusion, between 70 and 50 Ma. Periods of slow uplift, probably related to the South American Erosion Cycle (between 50 and 30 Ma) and Velhas Erosion Cycle (from 25 Ma), indicate a strong manifestation of denudation in this area. (author)

  14. Evidence of enriched mantle in the Archaean beneath eastern Indian Singhbhum Craton: constraints from geochemistry and Sr-Nd isotopic studies of mafic-ultramafic rocks from Bangriposi, Orissa, India

    Mouli Chakraborti, Tushar; Ray, Arijit; Deb, Gautam Kumar; Chakrabarti, Ramananda; Banerjee, Anupam


    interaction with an alkali-carbonatite melt. Enriched nature of the mantle region is also revealed in the highly negative ɛNd (T) values (-2.5 to -16.6), low initial 143Nd/144Nd (0.507895- 0.508615), and high but variable initial 87Sr/ 86Sr (0.7025- 0.7232). Calculated 147Sm/ 144Nd of the source region of the gabbroic rocks (0.1869; 5% less than CHUR) corroborate with enriched nature and the Fractionation Factor (α) of 1.05 corresponds with melting from a garnet bearing source region. Depleted mantle model age (TDM) calculations of the mafic-ultramafic rocks yield a span of 3.6- 5.6 Ga. Lack of Nb-Ta anomaly and complete absence of any field evidence of emplacement in a liquid state (Chilled margins, feeder dykes) in both cases precludes enrichment due to crustal contamination. Overall it can be stated that, these mafic-ultramafic rocks represent tectonic slices of ancient oceanic crust and enriched lithospheric mantle, together constituting a partly preserved ophiolite complex from eastern India.

  15. Closure of LG-1 reservoir across a sensitive clay terrace

    Schneeberger, C.E.; Levay, J.; Boncompain, B.


    The development of the LG-1 hydroelectric project requires the construction of a 2 km long dyke across a clay terrace. The nominal crest elevation of the dyke is 35 m and will confine the proposed LG-1 reservoir at elevation 32 m. Most of the dyke is of the freeboard type except for its northern extremity where the dyke reaches a height of 10.5 m. The sensitive nature of the soft clay foundation has called for several design features to assure the stability of the dyke along with both upstream and downstream bank stabilization work in order to avoid the occurence of potentially disastrous retrogressive slides. Such slides are typical of La Grande River clay banks and may reach 1-2 km in lateral extent. The paper describes the geotechnical conditions of the clay terrace and presents the most significant design criteria that were adopted.

  16. Melanite garnet-bearing nepheline syenite minor intrusion in Mawpyut ultramafic–mafic complex, Jaintia Hills, Meghalaya

    Monoj Maitra; J S David; S Bhaduri


    Mawpyut igneous suite in Jaintia Hills of Meghalaya plateau comprises differentiated suite of ultramafic–mafic rocks. The complex differs from other ultramafic–alkaline–carbonatite igneous emplacements of Shillong plateau and Mikir Hills like Jesra, Sung, Samchampi complexes, by the absence of alkaline–carbonatite rocks as major litho-units. Melanite garnet-bearing nepheline syenite, occurs as late phase minor intrusion in Mawpyut igneous complex, posseses alkaline character and shows inubiquitous relation with the host ultramafic–mafic rocks. On the other hand, this alkaline intrusive bodies of the Mawpyut igneous complex shows chemico-mineralogical resemblance with garnet-bearing nepheline syenite, ijolite litho-members of Jesra, Sung, Samchampi complexes of the region. It is interpreted that melanite garnet-bearing nepheline syenite intrusion in Mawpyut is contemporaneous with Jesra, Sung, Samchampi ultramafic–alkaline–carbonatite complexes and the host rocks of Mawpyut complex is an earlier magmatic activity possibly from a comparatively least enriched source.

  17. Artificial geochemical barriers for additional recovery of non-ferrous metals and reduction of ecological hazard from the mining industry waste.

    Chanturiya, Valentine; Masloboev, Vladimir; Makarov, Dmitriy; Mazukhina, Svetlana; Nesterov, Dmitriy; Men'shikov, Yuriy


    Laboratory tests and physical-chemical modeling have determined that mixtures of activated silica and carbonatite, serpophite and carbonatite show considerable promise for developing artificial geochemical barriers. The obtained average contents of nickel and copper deposited on geochemical barriers in the formed mining induced ores are acceptable for their subsequent cost efficient processing using either pyro- or hydrometallurgy methods. Some tests of geochemical barriers have been carried out, involving the use of polluted water in the impact zone of the "Kol'skaya GMK" JSC. A possibility of water purification from heavy metals down to the MAC level for fishery water bodies has been displayed.


    Sainov Mihail Petrovich


    Full Text Available The article has data on potential designs of overflow structures made of soil rather than concrete. The most reliable and cheap ones are dykes made of sandbags. This viewpoint is substantiated by the operation of peatland irrigation systems, constructed in the Moscow region in 2011 — 2012. The construction of overflow sandbag dykes must have slope/riverbed protection structures to withstand their erosion by open and filtration flows of the downstream. Designs of overflow dykes having their downstream sides protected by geosynthetic coats, which are patented by other hydraulic engineers, have proven unreliable.

  19. The geology of the Rio Grande region (Galicia, Spain)

    Insinger, H.F.


    The metamorphic rock sequence, ranging from micaschists to migmatites, and the intrusive rocks, granites and various dykes, of a coastal region of Galicia are described. A map and a general section give their distribution.

  20. The geology of the Rio Grande region (Galicia, Spain)

    Insinger, H.F.


    The metamorphic rock sequence, ranging from micaschists to migmatites, and the intrusive rocks, granites and various dykes, of a coastal region of Galicia are described. A map and a general section give their distribution.

  1. Estimation of divergence times for major lineages of galliform birds ...



    May 24, 2010 ... birds both for human society and for research (van Tuinen and Dyke, 2004). ... among some modern birds (Pereira and Baker, 2006a,. 2006b ..... Columbiformes and a dispersal-driven radiation in the Paleocene. Syst. Biol.

  2. When Is a Monopoly Not a Monopoly? A Reply to Tibor Machan

    Nicholas Dykes


    Full Text Available Accused by Tibor Machan of equivocation and psychologising in Machan’s 2008 book Anarchism/Minarchism, Nicholas Dykes rebuts both charges and suggests that, on the former charge, it is rather Professor Machan himself who equivocates.

  3. One of the Helium Liquifiers in the North Area


    Several Helium Liquifiers were installed in the North Area to cool superconducting magnets used in the experiments. At center top is M.Dykes, at bottom right J.Dozio. See CERN Annual Report 1979 p.82.

  4. 2-D Crustal thermal structure along Thuadara-Sindad DSS profile across Narmada-Son lineament, central India

    Rai, S N; Thiagarajan, S


    Central India is traversed by a WSW-ENE trending Narmada-Son lineament (NSL) which is characterized by the presence of numerous hot springs, feeder dykes for Deccan Traps and seismicity all along its length...

  5. A primary natrocarbonatitic association in the Deep Earth

    Kaminsky, Felix V.; Ryabchikov, Igor D.; Wirth, Richard


    In addition to ultramafic and mafic associations, a primary natrocarbonatitic association occurs in the lower mantle. To date, it was identified as inclusions in diamonds from the Juina area, Mato Grosso State, Brazil. It comprises almost 50 mineral species: carbonates, halides, fluorides, phosphates, sulfates, oxides, silicates, sulfides and native elements. In addition, volatiles are present in this association. Among oxides, coexisting periclase and wüstite were identified, pointing to the formation of the natrocarbonatitic association at a depth greater than 2000 km. Some iron-rich (Mg,Fe)O inclusions in diamond are attributed to the lowermost mantle. The initial lower-mantle carbonatitic melt formed as a result of low-fraction partial melting of carbon-containing lower-mantle material, rich in P, F, Cl and other volatile elements, at the core-mantle boundary. During ascent to the surface, the initial carbonatitic melt dissociated into two immiscible parts, a carbonate-silicate and a chloride-carbonate melt. The latter melt is parental to the natrocarbonatitic lower-mantle association. Diamonds with carbonatitic inclusions were formed in carbonatitic melts or high-density fluids.

  6. Precambrian crustal evolution and Cretaceous–Palaeogene faulting in West Greenland: Magnetic anomalies and metamorphic boundaries in the southern Nagssugtoqidian orogen, West Greenland

    Korstgård, John A.


    Full Text Available Within the southern Nagssugtoqidian orogen in West Greenland metamorphic terrains of both Archaean and Palaeoproterozoic ages occur with metamorphic grade varying from low amphibolites facies to granulite facies. The determination of the relative ages of the different metamorphic terrains is greatly aided by the intrusion of the 2 Ga Kangâmiut dyke swarm along a NNE trend. In Archaean areas dykes cross-cut gneiss structures, and the host gneisses are in amphibolite to granulite facies. Along Itilleq strong shearing in an E–W-oriented zone caused retrogression of surrounding gneisses to low amphibolite facies. Within this Itivdleq shear zone Kangâmiut dykes follow the E–W shear fabrics giving the impression that dykes were reoriented by the shearing. However, the dykes remain largely undeformed and unmetamorphosed, indicating that the shear zone was established prior to dyke emplacement and that the orientation of the dykes here was governed by the shear fabric. Metamorphism and deformation north of Itilleq involve both dykes and host gneisses, and the metamorphic grade is amphibolite facies increasing to granulite facies at the northern boundary of the southern Nagssugtoqidian orogen. Here a zone of strong deformation, the Ikertôq thrust zone, coincides roughly with the amphibolite–granulite facies transition. Total magnetic field intensity anomalies from aeromagnetic data coincide spectacularly with metamorphic boundaries and reflect changes in content of the magnetic minerals at facies transitions. Even the nature of facies transitions is apparent. Static metamorphic boundaries are gradual whereas dynamic boundaries along deformation zones are abrupt.

  7. Gravity and magnetic studies of the eastern Mojave Desert, California and Nevada

    Denton, Kevin M.; Ponce, David A.


    IntroductionFrom May 2011 to August 2014, the U.S. Geological Survey (USGS) collected gravity data at more than 2,300 stations and physical property measurements on more than 640 rock samples from outcrops in the eastern Mojave Desert, California and Nevada. Gravity, magnetic, and physical-property data are used to study and locate regional crustal structures as an aid to understanding the geologic framework related to mineral resources of the eastern Mojave Desert.The eastern Mojave Desert is host to a world-class rare earth element carbonatite deposit located at Mountain Pass, California. Carbonatites are typically defined as magmatic rocks with high modal abundances of primary carbonate minerals >50 weight percent and elevated abundances of rare earth elements (REEs) (Nelson and others, 1988; Woolley and Kempe, 1989). The “Sulphide Queen” carbonatite ore deposit is a composite, tabular body made up of sills and dikes of REE-bearing sovites and beforsites that occurs just south of the Clark Mountain Range along a north-northwest trending fault-bounded block that extends along the northeast edge of the Mescal Range and northwestern extent of Ivanpah Mountains. This early to middle Proterozoic block is composed of a 1.7 Ga metamorphic complex of gneiss and schist that underwent widespread metamorphism and associated plutonism during the Ivanpah orogeny (Miller and others, 2007). Subsequently, these rocks were intruded by a series of granitoids, which included the 1.4 Ga (DeWitt and others, 1987) ultrapotassic alkaline suite of intrusions that are spatially and temporally associated with hundreds of dikes, outcrops, and a carbonatite ore body. The relative age sequence of this intrusive suite of alkaline rocks from oldest to youngest includes shonkinite, mesosyenite, syenite, quartz syenite, potassic granite, carbonatite, and late shonkinite dikes (Olson and others, 1954; Wooden and Miller, 1990; Haxel, 2005; Miller and others, 2007).

  8. Communication between earthquake clusters separated by over 30 km supports simple volcano plumbing

    Jonsdottir, K.; Jonasson, K.; Gudmundsson, M. T.; Hensch, M.; Hooper, A. J.; Holohan, E. P.; Sigmundsson, F.; Halldorsson, S. A.; Hognadottir, T.; Magnússon, E.; Pálsson, F.; Walter, T. R.; Ofeigsson, B.; Parks, M.; Roberts, M. J.; Hjorleifsdottir, V.; Cesca, S.; Guðmundsson, G.; Hreinsdottir, S.; Jarosch, A. H.; Dumont, S.; Fridriksdóttir, H. M.; Barsotti, S.; Einarsson, P.


    The subglacial Bárðarbunga volcano is composed of a large oval caldera (7x11 km) and fissures extending tens of kilometers away from the caldera along the rift zone, which marks the divergent plate boundary across Iceland. On August 16th, 2014 an intense seismic swarm started below the Bárðarbunga caldera and in the two weeks that followed a dyke migrated some 47 km laterally in the uppermost 6-10 km of the crust along the rift. The dyke propagation terminated in lava fields just north of Vatnajökull glacier, where a major (1.5 km3) six months long eruption took place. Intense earthquake activity in the caldera started in the period August 21-24 with over 70 M5 earthquakes accompanying slow caldera collapse, as verified by various geodetic measurements. The subsidence is likely due to magma withdrawal from a reservoir at depth beneath the caldera. During a five months period, October-February, the seismic activity was separated by over 30 km in two clusters; one along the caldera rims (due to piecewise caldera subsidence) and the other at the far end of the dyke (as a result of small shear movements). Here we present statistical analysis comparing the temporal behaviour of seismicity recorded in the two clusters. By comparing the earthquake rate in the dyke in temporal bins before and after caldera subsidence earthquakes to the rate away from these bins (background rate), we show that the number of dyke earthquakes was significantly higher (p earthquake (>M4.6) in the caldera. Increased dyke seismicity was also observed 0-3 hours following a large caldera earthquake. Elevated seismicity in the dyke before a large caldera earthquake may occur when a constriction in the dyke was reduced, followed by pressure drop in the chamber. Assuming that the large caldera earthquakes occurred when chamber pressure was lowest, the subsiding caldera piston may have caused temporary higher pressure in the dyke and thereby increased the likelihood of an earthquake. Our results

  9. AfricaArray International Geophysics Field School: Applications of Near Surface Geophysics to challenges encountered in mine planning

    Webb, S. J.; Jones, M. Q.; Durrheim, R. J.; Nyblade, A.; Snyman, Q.


    Hard rock exploration and mining presents many opportunities for the effective use of near surface geophysics. For over 10 years the AfricaArray international geophysics field school has been hosted at a variety of mines in South Africa. While the main objective of the field school is practical training for the next generation of geophysicists, being hosted at a mine has allowed us to investigate applications of near surface geophysics in the early stages of mine planning and development as geophysics is often cheaper and faster than drilling. Several applications include: detailed delineation of dykes and stringer dykes, physical property measurements on drill core for modeling and marker horizons, determination of overburden thickness, locations of water and faults. Dolerite dykes are usually magnetic and are associated with loss of ground (i.e. where the dyke replaces the ore and thus reduces the amount of ore available) and safety/stability concerns. Thus the accurate mapping of dykes and narrow stringers that are associated with them are crucial to the safe planning of a mine. We have acquired several case studies where ground magnetic surveys have greatly improved on the resolution and detail of airborne magnetic surveys in regions of complicated dyke swarms. In many cases, thin stringer dykes of less than 5 cm have been detected. Physical property measurements of these dykes can be used to distinguish between different ages of dykes. It is important to accurately determine overburden thickness when planning an open pit mine as this directly affects the cost of development. Depending on the nature of the overburden, both refraction seismic and or DC resistivity can provide continuous profiling in the area of interest that fills in gaps between boreholes. DC resistivity is also effective for determining water associated with dykes and structures that may affect mine planning. The field school mainly addresses the training of a variety of students. The core

  10. The sub-volcanic system of El Hierro, Canary Islands

    Galindo, I.; Becerril, L.; Gudmundsson, A.


    The main volcanotectonic structures of El Hierro are three rift zones, trending northeast, west, and south. Most of the eruptions in El Hierro within these zones are basaltic fissure eruptions fed by subvertical dykes. The dykes appear as close to collinear or slightly offset segments, their surface expressions being clusters of cinder cones and eruptive vents. Three large landslides, referred to as El Golfo, El Julan, and Las Playas, have eroded the areas between rift axes and provide exposures that make it possible to provide a three-dimensional view of the uppermost part of the sub-volcanic system. Here we report the results of a structural study of the sub-volcanic system as obtained through the analysis of dykes and eruptive vents. The data obtained from surface outcrops have been combined with data from subsurface water galleries. More than 600 eruptive vents and 625 dykes have been studied in detail to characterise the subvolcanic system of the island. Using cinder-cone and other eruptive-vent alignments it has been possible to infer 115 eruptive fissures with lengths that range from 40 m to 2200 m. NE-SW trending volcanic fissures and dykes are common on the entire island and predominate in the northeast rift zone. The main strike of the dykes and fissures in the south and west rift zones are approximately NNW-SSE and E-W, respectively. However, in the west rift zone, eruptive fissures display a fan distribution with directions that range from N43°E to N124°E. Volcanic fissures within the El Golfo landslide valley trend parallel to the head scarp, except those that are close to the head of the valley, many of which are perpendicular to the scarp. Dykes show a radial distribution in the head scarp of the El Golfo landslide. Three feeder-dykes directly connected with their lava flows have been identified in El Hierro. Feeder dykes are difficult to observe in the field but provide important information when their lengths and thicknesses can be measured

  11. Paleo-Asian oceanic subduction-related modification of the lithospheric mantle under the North China Craton: Evidence from peridotite xenoliths in the Datong basalts

    Wang, Chengyuan; Liu, Yongsheng; Min, Ning; Zong, Keqing; Hu, Zhaochu; Gao, Shan


    In-situ major and trace elements and Sr isotopic compositions of peridotite xenoliths of the Datong Quaternary alkaline basalt were analyzed to evaluate the influences of the southward subduction of the Paleo-Asian oceanic plate (PAOP) on the lithospheric mantle transformation of the North China Craton (NCC). These peridotite xenoliths including spinel harzburgites and lherzolites were classified into three groups. The type 1 peridotites have the lowest temperatures (961-1007 °C). Clinopyroxenes in these peridotites exhibit LREE-depleted REE patterns and have the lowest 87Sr/86Sr ratios of 0.70243-0.70411. The type 2 and 3 peridotites show higher temperatures (1017-1022 °C). Clinopyroxenes in the type 2 peridotite have V-shaped REE patterns and relatively higher 87Sr/86Sr ratios of 0.70418-0.70465. Clinopyroxenes in the type 3 peridotite have concave-downward REE patterns and unusually high 87Sr/86Sr ratios of 0.70769-0.70929. Carbonatitic veinlets are found in the type 1 peridotites. They show steep LREE-enriched REE patterns with enrichment in LILE and depletion in HFSE, and have the highest 87Sr/86Sr ratios of 0.71145-0.71285. The mineral chemistries and modal calculations suggest that the protolith of these peridotites experienced a variable degree of partial melting. The type 2 and 3 peridotites sampled from deeper depth experienced latter cryptic carbonatitic metasomatism. The carbonatitic veinlets have generally consistent trace element patterns and Sr isotopic ratios with the calculated melts equilibrated with clinopyroxenes in the type 3 peridotite, which may represent the percolated carbonatitic melt quickly solidified in the relatively cold and shallow mantle. The remarkable negative Eu anomalies (0.37-0.61) and highly radiogenic Sr isotopic compositions of the calculated metasomatic agents preclude indicate melt derived from carbonated peridotite or carbonated eclogite but point to a crustal sedimentary origin. Considering the tectonic setting and

  12. Viscosity of carbonate-rich melts under different oxygen fugacity conditions

    Di Genova, Danilo; Hess, Kai-Uwe; Cimarelli, Corrado; Dingwell, Donald B.


    Viscosity is a fundamental property of many materials and its changes affects the fluid dynamics of natural system as well as industrial processes. The mobility of carbonatitic melts, which are carbonate-rich and very fluid melts, has attracted renewed interest in both earth science and industry. In fact, these melts are considered the main transport agent of carbon from the mantle to the crust and may be intimately linked to the generation of kimberlites. At the same time lithium, potassium and sodium carbonate are used as electrolytes in molten carbonate fuel cells which operate at high temperatures (~650° C) for the production of electricity without CO2 emissions. Accurate measurement of the transport property (i.e. viscosity) of carbonatitic melts is a priority in order to understand the carbonatite mobility and reaction rates. Additionally, obtaining accurate viscosity measurements of such low viscosity melts is however an experimental challenge due to volatility, very low torques and chemical melt instability in the viscometer. To overcome these limitations we have customized a Modular Compact Rheometer (MCR 502 from Anton Paar) ad hoc equipped with 2 narrow gap concentric-cylinder geometries of steel and Pt-Au. The rheometer is characterized by an air-bearing-supported synchronous motor with torque ranging between 0.01 μNm and 230 mNm (resolution of 0.1 nNm), achieving very low viscosity measurements in the order of mPa s, temperatures up to 1000° C and shear rates ranging between 1 and 100 sec-1. These experimental conditions well match the temperature-viscosity-shear rate window relevant for carbonate melts. Here we present the calibration of the rheometer and the results of a rheological characterization study on a series of very low viscous synthetic and natural carbonatitic melts at different oxygen fugacity (air and CO2 saturated atmosphere). Viscosity measurements on carbonate melts have been performed in the temperature range between ~650 and 1000

  13. Witnessing the birth of a new ocean? The first 6 years of the Dabbahu rifting episode, and other activity in Afar

    Wright, T.; Ayele, A.; Barnie, T.; Belachew, M.; Calais, E.; Field, L.; Hamling, I.; Hammond, J.; Keir, D.


    Intense earthquake activity and a small rhyolitic eruption in September 2005 heralded the onset of an unprecedented period of geological activity in the Afar Depression. The seismic activity accompanied dyke intrusion in the upper 10 km of crust along 60 km of the Dabbahu (northern Manda-Hararo) Magmatic Segment (DMS) of the Nubia-Arabia plate boundary, a nascent seafloor spreading centre. InSAR observations of the resulting deformation showed that the initial dyke was up to 8 m thick, with a total volume of 2-2.5 km3. Urgency funding from the UK Natural Environmental Research Council (NERC) and US National Science Foundation (NSF) enabled us to deploy a local array of seismometers in October 2005, continuous GPS instruments in January 2006, and to acquire a dense time series of satellite radar images. The medium-term viability of these instruments was secured with major follow-on funding from NSF and NERC; these projects supported the collection and analysis of additional unique data sets, including data from a broader array of seismic and GPS instruments, magneto-telluric transects of the rift, airborne LiDAR, petrological sampling and micro-gravity work. The combination of these data has allowed us to quantify the processes associated with crustal growth at divergent plate boundaries for the first time. Here, we present a broad overview of geological activity in the Afar depression in the hyperactive 21st century. Activity in the DMS began after September 2000, when Gabho volcano at the north of the segment began uplifting, as its magma chamber, ~3 km below the surface, was replenished. It is likely that the inflation at Gabho ultimately triggered the onset of the Dabbahu rifting episode. The rifting episode began with intense seismicity at the northern end of the DMS, before jumping to the Ado Ale Volcanic Complex at the segment centre. This initial dyking was fed from shallow (~3 km) chambers at Gabho and Dabbahu as well as a deeper (~10 km) source at Ado Ale

  14. Anatomy of a frozen axial melt lens from a fast-spreading paleo-ridge (Wadi Gideah, Oman ophiolite)

    Müller, T.; Koepke, J.; Garbe-Schönberg, C.-D.; Dietrich, M.; Bauer, U.; Wolff, P. E.


    At fast-spreading mid-ocean ridges, axial melt lenses (AMLs) sandwiched between the sheeted dyke section and the uppermost gabbros are assumed to be the major magma source of crust formation. Here, we present our results from a field study based on a single outcrop of a frozen AML in the Samail ophiolite in the Sultanate of Oman which presents a whole suite of different lithologies and complex cutting relationships: varitextured gabbro with relics of primitive poikilitic clinopyroxene is intruded by massive quartz diorites and tonalites bearing relics of assimilated sheeted dykes, which in turn are cut by trondhjemite dykes. The whole is cut by basaltic dykes with chilled margins. The geochemical evolutionary trend of the varitextured gabbros, including some of the quartz diorites and tonalites, can be best modelled by fractional crystallisation of an experimental MORB parental melt composition containing 0.4 to 0.8 wt.% H2O. Patchy varitextured gabbros containing domains of primitive poikilitic clinopyroxene and evolved granular networks represent the record of in situ crystallisation. Some quartz diorites, often with xenoliths of sheeted dykes and exceptionally high Al2O3 contents, show a bulk trace element pattern more in accord with melts generated by experimental partial melting of dyke material. Highly evolved, crosscutting trondhjemite dykes show characteristic trace element patterns implying a formation by partial melting of sheeted dykes under lower water activity which is indicated by relatively low Al2O3 contents. The late basaltic dykes with chilled margins crosscutting all other lithologies show a relatively depleted geochemical character with pronounced negative Nb-Ta anomalies implying a genetic relationship to the second phase of magmatic Oman paleo-ridge activity (V2). The field relationships in combination with the petrological/geochemical trends reveal multiple sequences of MORB-type magma cooling (resulting in fractional crystallisation) and re

  15. Effects of geological structures on groundwater flow and quality in hardrock regions of northern Tirunelveli district, southern India

    M Senthilkumar; R Arumugam; D Gnanasundar; D S C Thambi; E Sampath Kumar


    Geological and structural influences on groundwater flow and quality were evaluated in the present study in the hardrock regions of Tirunelveli District, southern India. Groundwater is a major source of freshwater in this region to cater to the requirements of domestic and agricultural activity, as there are no surface water resources. Geologically, the area is characterized by charnockites and garnetiferous biotite gneiss. Groundwater in this region is found to occur in the weathered portion under unconfined condition and in fractured/fissured portions under unconfined to semi-confined condition. Existence of deep-seated fractures are minimal. Lineaments/dykes play a major role in the occurrence and movement of groundwater in the region. Lineaments/dykes of the study area can be broadly divided into two types: north–south and west–east oriented structures. Analysis and field observations revealed that the north–south dykes act as a barrier of groundwater while the west–east oriented structures behave as a carrier of groundwater. Both quality and quantity of groundwater is different on the upstream and downstream sides of the dyke. Hence, it is conclusive that the west–east oriented dykes in this region are highly potential and act as a conduit for groundwater movement from recharge areas to the discharge area.




    Full Text Available In term of floods the current area of Hungary has extensively been endangered. Modelling of flood processes – mainly following the hydrological events in the riverbed – has recently been developed. As far as protection dykes provide protection of the inhabited and agricultural areas, the flood models can run with acceptable preciseness. However, when dykes cannot withstand against the increasing load and a dyke burst occurs, fast and efficient protection measures shall be taken in the protected areas. The dynamic 4D Flood model presented in this paper makes possible a fast modelling of dyke burst occurring in the protected side and spreading of water mass, based on real parameters. For this reason the features of protected area shall be recognised, for example topology of creeks, features of agricultural and inhabited areas, parameters of roads, railways, rainwater drainage, buildings, natural conditions (soil parameters, meteorological characteristics, etc.. The results satisfy the comprehensive demands of the Directorate General for Disaster Prevention of Borsod-Abaúj-Zemplén County. In case of dyke burst, the completed Flood Model can run the expected events of the next hour in a few minutes. This time is enough for the specialists to bring operative decisions to protect the inhabitants and avoid material losses.

  17. Forecasting magma-chamber rupture at Santorini volcano, Greece

    Browning, John; Drymoni, Kyriaki; Gudmundsson, Agust


    How much magma needs to be added to a shallow magma chamber to cause rupture, dyke injection, and a potential eruption? Models that yield reliable answers to this question are needed in order to facilitate eruption forecasting. Development of a long-lived shallow magma chamber requires periodic influx of magmas from a parental body at depth. This redistribution process does not necessarily cause an eruption but produces a net volume change that can be measured geodetically by inversion techniques. Using continuum-mechanics and fracture-mechanics principles, we calculate the amount of magma contained at shallow depth beneath Santorini volcano, Greece. We demonstrate through structural analysis of dykes exposed within the Santorini caldera, previously published data on the volume of recent eruptions, and geodetic measurements of the 2011-2012 unrest period, that the measured 0.02% increase in volume of Santorini’s shallow magma chamber was associated with magmatic excess pressure increase of around 1.1 MPa. This excess pressure was high enough to bring the chamber roof close to rupture and dyke injection. For volcanoes with known typical extrusion and intrusion (dyke) volumes, the new methodology presented here makes it possible to forecast the conditions for magma-chamber failure and dyke injection at any geodetically well-monitored volcano.

  18. Geochemical and geostatistical evaluation, Arkansas Canyon Planning Unit, Fremont and Custer Counties, Colorado

    Weiland, E.F.; Connors, R.A.; Robinson, M.L.; Lindemann, J.W.; Meyer, W.T.


    A mineral assessment of the Arkansas Canyon Planning Unit was undertaken by Barringer Resources Inc., under the terms of contract YA-553-CTO-100 with the Bureau of Land Management, Colorado State Office. The study was based on a geochemical-geostatistical survey in which 700 stream sediment samples were collected and analyzed for 25 elements. Geochemical results were interpreted by statistical processing which included factor, discriminant, multiple regression and characteristic analysis. The major deposit types evaluated were massive sulfide-base metal, sedimentary and magmatic uranium, thorium vein, magmatic segregation, and carbonatite related deposits. Results of the single element data and multivariate geostatistical analysis indicate that limited potential exists for base metal mineralization near the Horseshoe, El Plomo, and Green Mountain Mines. Thirty areas are considered to be anomalous with regard to one or more of the geochemical parameters evaluated during this study. The evaluation of carbonatite related mineralization was restricted due to the lack of geochemical data specific to this environment.

  19. Solid Inclusions in Au-nuggets, genesis and derivation from alkaline rocks of the Guli Massif, Northern Siberia

    Dvorani Sami N.


    Full Text Available A total of 112 Au-nuggets, collected from alluvial placer deposits of the Ingarinda River from the Guli massif, located in northem Siberia, Russia, were investigated. The Guli massif consists of a huge dunite-clinopyroxenite complex (the largest complex in the world, an alkaline to highly alkaline rock suite (melilite, nephelinite, ijolite enveloping the dunite and carbonatite intrusions, associated with disseminated schlieren type chromitite and Au-Ag, Pt placer deposits. The nuggets are characterized by various sizes and shapes and show chemical compositions Au, Au-Ag and AuCu, typical for a derivate of carbon-atites and/or ultramafic complexes. A great variety of oxide, silicate, REE-minerals, carbonate and sulphide inclusions have been detected in the nuggets, which are identical in mineralogy and chemical composition to mineral constituents of the alkaline to highly alkaline rock suite surrounding the Guli dunite core complex thus, considered as the source for Au-nuggets.

  20. REE Geochemistry of Fluorite from the Maoniuping REE Deposit, Sichuan Province, China: Implications for the Source of Ore-forming Fluids


    Fluorite is one of the main gangue minerals in the Maoniuping REE deposit, Sichuan Province, China. Fluorite with different colors occurs not only within various orebodies, but also in wallrocks of the orefield. Based on REE geochemistry, fluorite in the orefieid can be classified as the LREE-rich, LREE-flat and LREE-depleted types. The three types of fluorite formed at different stages from the same hydrothermal fluid source, with the LREE-rich fluorite forming at the relatively early stage, the LREE-flat fluorite in the middle, and the LREE-depleted fluorite at the latest stage. Various lines of evidence demonstrate that the variation of the REE contents of fluorite shows no relation to the color. The mineralization of the Maoniuping REE deposit is associated spatially and temporally with carbonatite-syenite magmatism and the ore-forming fluids are mainly derived from carbonatite and syenite melts.

  1. Subsolidus physical and chemical mixing of granite and gabbro during mylonitization, South Victoria Land, Antarctica

    Rachel Walcott, C.; Craw, Dave


    At Dromedary Massif, Southern Victoria Land, Antarctica, a suite of coarse-grained granite dykes cross-cuts a gabbro pluton which has been partially metamorphosed at amphibolite facies. During regional deformation, strain has been inhomogeneously distributed through the gabbro pluton and has been concentrated in granite dykes. In zones of relatively high strain, the granite dykes have developed a mylonitic fabric. A high strain gradient between granitic mylonite and metagabbroic host rock has induced isochemical mylonitization of the margin of the host. This grain size reduction allowed chemical diffusion between granitic and metagabbroic mylonites, resulting in a marginal zone of biotite-rich mylonite with intermediate composition. Biotite-rich mylonite decoupled from metagabbroic mylonite and flowed with granitic mylonite. Continued folding and transposition of granitic mylonite and biotite-rich mylonite has produced compositionally banded mylonite zones through thorough and irreversible mixing of the two lithologies.

  2. The basic and ultrabasic dikes from the coast region between the Sao Sebastiao and Ubatuba cities, Sao Paulo State, SP, Brazil; Os diques basicos e ultrabasicos da regiao costeira entre as cidades de Sao Sebastiao e Ubatuba, estado de Sao Paulo, SP, Brasil

    Garda, Gianna Maria


    The coastline between Sao Sebastiao and Ubatuba cities and the shores of Sao Sebastiao, Anchieta and Mar Virado islands (Sao Paulo State, Brazil) are crosscut by several small swarms and isolated dykes trending N55E. The main rock types range from basic to intermediate, but also a conspicuous variety of alkaline lamprophyres occur side by side with the main group. The thickness of the basic to intermediate dykes vary widely, from a few centimeters to several metres, while the lamprophyres are a few tens of centimeters thick. The objective of this thesis is the petrographic, mineralogic, petrochemical and isotopic characterization of the basic and ultrabasic dykes that occur between the Sao Sebastiao and Ubatuba cities (State of Sao Paulo), also including some occurrences from the Sao Sebastiao, Mar Virado and Anchieta islands and from the Bairro Alto region (Folha de Natividade da Serra). The petrogenetic model presented is based in the national and international bibliography. (author) 146 refs., 44 figs., 24 tabs.

  3. On a boundary layer problem related to the gas flow in shales

    Barenblatt, G. I.


    The development of gas deposits in shales has become a significant energy resource. Despite the already active exploitation of such deposits, a mathematical model for gas flow in shales does not exist. Such a model is crucial for optimizing the technology of gas recovery. In the present article, a boundary layer problem is formulated and investigated with respect to gas recovery from porous low-permeability inclusions in shales, which are the basic source of gas. Milton Van Dyke was a great master in the field of boundary layer problems. Dedicating this work to his memory, we want to express our belief that Van Dyke\\'s profound ideas and fundamental book Perturbation Methods in Fluid Mechanics (Parabolic Press, 1975) will live on-also in fields very far from the subjects for which they were originally invented. © 2013 US Government.

  4. Photograph of the Month


    For dykes, magma flow direction can be deciphered from various fabrics in the chilled margin (Correa-Gomez et al., 2001, JSG 23, 1415). This photograph represents part of a chilled margin of a appr. N- S trending dyke at Kharghar Hills, Mumbai, Maharashtra, India. The section is sub-vertical. The elongated grooves indicate flow of magma through a fault and the tapered grooves (arrows) connote the flow direction: towards the pointed end of the groove. The magma flowed towards the north in this case. Such fabrics of wall-magma interaction in the Deccan volcanic province prove that dykes injected along fault planes. 19° 2‧ 22.3″ N, 73° 3‧ 28.7″ E. Photograph Ayan Achyuta Misra, Mumbai, India.

  5. Comparing methods of estimating strength parameters for fissured clays at Seven Sisters Generating Station

    Dubois, D.P.; Yereniuk, V.A. [Manitoba Hydro, Winnipeg, MB (Canada)


    Some instabilities have been observed at several dyke locations at the Seven Sisters Generating Station, Manitoba since construction in the late 1940s. The foundations of the dykes are fissured plastic clays. Slope stabilizing methods have been proposed by a number of researchers since the late 1970s for estimating strength parameters for fissured plastic clays. This paper reports on four methods which were used for estimating Mohr-Coulomb strength parameters for stability analyses involving nine dyke locations where instability has been reported in the past. Correlation is established between the calculated safety factors and observed performance in an effort to determine the most appropriate method for this site. It was determined that the most appropriate method was that proposed by P.J. Rivard and Y.Lu in the late 1970s. 16 refs., 1 tab., 7 figs.

  6. The “eye of Africa” (Richat dome, Mauritania): An isolated Cretaceous alkaline-hydrothermal complex

    Matton, Guillaume; Jébrak, Michel


    The Richat dome is a spectacular circular structure located in the Mauritanian part of the Sahara Desert. The current erosion level of this igneous complex presents a wide variety of contrasting extrusive and intrusive rocks from shallow to deep source regions providing insight into the magmatic process at the origin of the complex. The Richat is the superposition of a bimodal tholeiitic suite crosscut by carbonatitic and kimberlitic magmatic rocks. The bimodal series is characterized by two concentric gabbroic ring dikes and two extrusive rhyolitic centers representing the remnant of two maar systems. Silica undersaturated magmas occur as carbonatite dikes, a kimberlite plug, and kimberlite sills extruded along the old regional anisotropies filling NNE-SSW dextral strike-slip faults and en-echelon tension gashes. An intense low-temperature hydrothermal event affected the Richat area. It is responsible, notably, for the karst-collapse central mega-breccia, the alteration of the rhyolites, the potassic alteration of the gabbros and the stable isotope enrichment in the carbonatites. A piston-like collapse is proposed to explain the contrast existing between the central and outer part of the Richat. Structural inheritance played an important role in the history of the Richat complex. Pre-existing anisotropies acted as a pathway for the ascent of asthenospheric and sub-continental melts and allowed the coexistence of alkaline and tholeiitic magmas within the same igneous complex.

  7. Petrography, geochemistry and geochronology of granite hosted rhyodacites associated with a disseminated pyrite mineralization (Arnolz, Southern Bohemian Massif, Austria)

    Göd, Richard; Kurzweil, Johannes; Klötzli, Urs


    The study focuses on a subvolcanic rhyodacite dyke intruding a fine grained biotite granite and paragneisses of the South Bohemian Massif, part of the Variscan Orogenic Belt in Central Europe. The subvertical dyke strikes NNE, displays a thickness of about 30 m and has been traced by boulder mapping for approximately 7 km. The rhyodacites have been affected by two hydrothermal fluids. An older one of oxidizing condition giving rise to a reddish to brownish type of rock (Type I) and a younger fluid of reducing condition causing a greenish variety (Type II). The hydrothermal alteration is associated with the formation of the clay minerals chlorite, sericite, kaolinite and smectite and a disseminated pyrite mineralization. Bulk chemistries of the rhyodacites emphasize the hydrothermal alterations to be isochemical with the exception of sulphur enriched up to a maximum of 0.6 wt%. Trace element composition of the rhyodacites points to a barren geochemical environment in terms of base and precious elements. Sulphur isotope investigations of pyrites from the rhyodacites and the hosting granites respectively yield d34S data ranging from +0.07 to -2.22 ‰, emphasizing a magmatic origin of the sulphur. Geochronological investigations yield in situ U/Pb zircon ages of 312 ± 4 Ma for the biotite granite and of 292 ± 4 Ma for the rhyodacitic dykes indicating a time gap of ≈ 20 Ma between these two intrusive events. A contemporaneous but geochemically specialized granitic intrusion associated with NW striking "felsitic" dykes occurs about 10 to 20 km to the NW of Arnolz. However, the rhyodacites around Arnolz differ significantly from these felsitic dykes in their geochemistry and alteration phenomena which points to a different magmatic source. This coincides with a change in the orientation of the dykes from a NW direction controlling the geochemically specialized intrusions in the NW to a dominating NNE direction mirrored by the studied rhyodacites at Arnolz.

  8. Petrography, geochemistry and geochronology of granite hosted rhyodacites associated with a disseminated pyrite mineralization (Arnolz, Southern Bohemian Massif, Austria)

    Göd, Richard; Kurzweil, Johannes; Klötzli, Urs


    The study focuses on a subvolcanic rhyodacite dyke intruding a fine grained biotite granite and paragneisses of the South Bohemian Massif, part of the Variscan Orogenic Belt in Central Europe. The subvertical dyke strikes NNE, displays a thickness of about 30 m and has been traced by boulder mapping for approximately 7 km. The rhyodacites have been affected by two hydrothermal fluids. An older one of oxidizing condition giving rise to a reddish to brownish type of rock (Type I) and a younger fluid of reducing condition causing a greenish variety (Type II). The hydrothermal alteration is associated with the formation of the clay minerals chlorite, sericite, kaolinite and smectite and a disseminated pyrite mineralization. Bulk chemistries of the rhyodacites emphasize the hydrothermal alterations to be isochemical with the exception of sulphur enriched up to a maximum of 0.6 wt%. Trace element composition of the rhyodacites points to a barren geochemical environment in terms of base and precious elements. Sulphur isotope investigations of pyrites from the rhyodacites and the hosting granites respectively yield d34S data ranging from +0.07 to -2.22 ‰, emphasizing a magmatic origin of the sulphur. Geochronological investigations yield in situ U/Pb zircon ages of 312 ± 4 Ma for the biotite granite and of 292 ± 4 Ma for the rhyodacitic dykes indicating a time gap of ≈ 20 Ma between these two intrusive events. A contemporaneous but geochemically specialized granitic intrusion associated with NW striking "felsitic" dykes occurs about 10 to 20 km to the NW of Arnolz. However, the rhyodacites around Arnolz differ significantly from these felsitic dykes in their geochemistry and alteration phenomena which points to a different magmatic source. This coincides with a change in the orientation of the dykes from a NW direction controlling the geochemically specialized intrusions in the NW to a dominating NNE direction mirrored by the studied rhyodacites at Arnolz.

  9. Geochronology and Hf Isotope Study of Pegmatite in the Xiaoqinling Area of NW China:Implication for Petrogenesis and Regional Metamorphism

    Haixiang Zhao; Shaoyong Jiang; Baozhang Dai; Liang Ma; Jianwei Li


    In this study, we carried out petrography, zircon U-Pb geochronology and Hf isotopic analyses on a granitic pegmatite dyke in the Xiaoqinling area in southern margin of the North China Craton (NCC). Our study suggests that the pegmatite dyke likely crystallized from a volatile-rich peg-matitic magma. Different from most other pegmatite elsewhere, zircon from this pegmatite dyke does not contain unusually high U and Th concentrations and suffered no evident radioactive damage, therefore we successfully obtained a zircon U-Pb dating using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), which yields an average 207Pb/206Pb age of 1 814±6 Ma, representing the intrusive age of the granitic pegmatite dyke. ZirconεHf(t) values are between-8.3 and-3.0, corresponding to Hf depleted mantle model ages from 2 649 to 2 991 Ma with an average of 2 881 Ma. These data indicate that this granitic pegmatite dyke may have been derived from partial melting of Meso-Neoarchean metamorphic rocks from the Xiaoqinling basement. Granitic pegmatite magma may have emplaced within the Taihua Group wall rocks during the last stage of the middle to high grade metamorphism. Furthermore, according to the petrographic observation, the 1.81 Ga pegmatite dyke and the 1 800–1 750 Ma Xiong’er Group rocks were not undergone middle to high grade meta-morphism, indicating 1.81 Ga as the termination of the latest regional metamorphism in the southern margin of the NCC.

  10. Magnetic interpretation of north Gebel El Shallul area, central Eastern Desert, Egypt

    Ahmed A. Khameis


    The interpretation of the basement tectonic map of the area indicated the presence of a set of unexposed subsurface basic dykes running generally in NNW–SSE direction controlling the courses of major wadis in the study area. This set of NNW–SSE basic dykes are dissected by a NE–SW fault system. These two sets of fault systems were found to be matched well with that obtained from the Landsat image and geological map. It was found that the pronounced NNW direction is a predominant structural trend controlling the structural framework of the area.

  11. Découverte d'un diatrème de kimberlite diamantifère à Séguéla en Côte-d'IvoireDiscovery of a diamond-bearing kimberlite diatreme at Séguéla in Ivory Coast

    Pouclet, André; Allialy, Marc; Daouda-Yao, Bertin; Esso, Botty


    The Séguéla area in Ivory Coast is known for its diamond-bearing field related to dykes of kimberlite and lamproite. These dykes, devoid of any deformation and metamorphism, crosscut the Birimian formations. Their N 170° orientation is controlled by the tectonized contact between the Archean and the Paleoproterozoic shields of the West-African craton. Discovery of a diatreme, with its pipe breccias and well-preserved maar sediments, below the present-day colluvia, attests for the probable recent geological age (Cretaceous?) of the kimberlitic activity. To cite this article: A. Pouclet et al., C. R. Geoscience 336 (2004).

  12. Investigation of Noise in Electronic Ultrasonic Systems

    Paulius Adomavičius


    Full Text Available Noise models in ultrasonic control system have been investigated. Ultrasonic system channel consist of exciting generator, ultrasonic transducer, amplitude limiter, amplifier, low band filter and A/D converter. The ultrasonic transducers have been described as Von Hippel model, Van Dyke model or improved Van Dyke model. Advantages and disadvantages of these models are discussed in this paper. Noise models of amplitude limiter and linear operational amplifier are presented. The summary results of calculated noise spectral density of ultrasonic system channel have been presented.Article in Lithuanian

  13. Interview with Alison Bechdel about her presentation of Fun Home in Paris and Tours

    Anne Crémieux


    Full Text Available “Self-portrait by Alison Bechdel,” Courtesy of the authorTransat: How has Fun Home’s reception been different in nature from the reactions to Dykes to Watch Out For? Alison Bechdel: Fun Home has had a very different reception than Dykes to Watch Out For. It’s a very different type of book. I don’t want to downplay DTWOF—I’m very proud of the series, and I think it’s been a worthy contribution to queer culture as well as to the comics genre. But Fun Home was a real creative leap for me. Creati...

  14. Geology, market and supply chain of niobium and tantalum—a review

    Mackay, Duncan A. R.; Simandl, George J.


    Tantalum (Ta) and niobium (Nb) are essential metals in modern society. Their use in corrosion prevention, micro-electronics, specialty alloys and high-strength low-alloy (HSLA) steel earns them a strategic designation in most industrialised countries. The Ta market is unstable due in part to historic influx of `conflict' columbite-tantalite concentrate, or "Coltan," that caused Ta mines in Australia and Canada to be placed on care and maintenance. More recently, the growing appetite of modern society for consumer goods made of `conflict-free' minerals or metals has put pressure on suppliers. Pegmatites, rare-element-enriched granites, related placer deposits and weathered crusts overlying carbonatite and peralkaline complexes account for the majority of Ta production. Several carbonatite-related deposits (e.g. Upper Fir and Crevier, Canada) are being considered for potential co-production of Ta and Nb. Pyrochlore (Nb-Ta), columbite-tantalite (Nb-Ta), wodginite (Ta, Nb and Sn) and microlite (Ta and Nb) are the main ore minerals. Approximately 40 % of Ta used in 2012 came from Ta mines, 30 % from recycling, 20 % from tin slag refining and 10 % from secondary mine concentrates. Due to rapid industrialisation and increased use of Nb in steel making in countries such as China and India, demand for Nb is rising. Weathered crusts overlying carbonatite complexes in Brazil and one hard rock carbonatite deposit in Canada account for about 92 and 7 % of Nb world mine production, respectively. Since the bulk of the production is geographically and politically restricted to a single country, security of supply is considered at risk. Other prospective resources of Nb, beside carbonatites and associated weathered crusts, are peralkaline complexes (e.g. Nechalacho; where Nb is considered as a potential co-product of REE and zirconium). Economically, significant deposits of Ta and Nb contain pyrochlore, columbite-tantalite, fersmite, loparite and strüverite. Assuming continued

  15. Volatile-rich Melts in the Earth's Upper Mantle (AGU Kuno Medal)

    Dasgupta, Rajdeep


    The onset of silicate magma generation in the Earth's upper mantle influences the thermal evolution of the planet, fluxes of key volatiles to the exosphere, and geochemical and geophysical properties of the mantle. Although carbonatitic fluid with variable water content could be stable ≤250 km beneath mid oceanic ridges [1-3], owing to the small fraction (oxygen fugacity of the mantle in the garnet peridotite field [2, 3], we suggest that on a global scale, carbonated silicate melt generation at ~250-180 km deep redox solidus, with destabilization of metal and majorite in the upwelling mantle, explains oceanic low-velocity zone and electrical conductivity structure of the mantle. In locally oxidized domains (i.e., higher than average Fe3+/Fetotal), deeper carbonated silicate melt may contribute to the X-discontinuity. Furthermore, the new experimental results along with the electrical conductivity of molten carbonated peridotite [8] and that of the oceanic upper mantle [6] suggest that if CO2-rich melt is the only possible agent to explain the high electrical conductivity of the asthenospheric mantle then the mantle at depth is CO2-rich but H2O-poor; higher H2O content in the mantle enhances melting, lowers the CO2 content and likely the conductivity of such melts. Finally, carbonated silicate melts restrict the stability of carbonatite in the Earth's deep oceanic upper mantle and the inventory of carbon, water, and other highly incompatible elements at ridges becomes controlled by flux of the former [7]. Although the stability of carbonatitic melt may be eliminated beneath oceanic ridges at all depths, beneath continents stability of carbonatitic melt is expected. Archean cratonic mantle (geotherms corresponding to surface heat flux of 40-50 mW m-2) crosses the carbonated peridotite solidus, at a depth of ~100-220 km [9]; thus considering the oxygen fugacity profile for cratons [3], carbonatitic melt is expected to be stable at 100-180 km depths, at a narrow

  16. Magnetic fabrics in characterization of magma emplacement and tectonic evolution of the Moyar Shear Zone, South India

    P. Pratheesh


    Full Text Available The Moyar Shear Zone (MSZ of the South Indian granulite terrain hosts a prominent syenite pluton (∼560 Ma and associated NW-SE to NE-SW trending mafic dyke swarm (∼65 Ma and 95 Ma. Preliminary magnetic fabric studies in the mafic dykes, using Anisotropy of Magnetic Susceptibly (AMS studies at low-field, indicate successive emplacement and variable magma flow direction. Magnetic lineation and foliation in these dykes are identical to the mesoscopic fabrics in MSZ mylonites, indicating shear zone guided emplacement. Spatial distribution of magnetic lineation in the dykes suggests a common conduit from which the source magma has been migrated. The magnetic foliation trajectories have a sigmoidal shape to the north of the pluton and curve into the MSZ suggesting dextral sense of shear. Identical fabric conditions for magnetic fabrics in the syenite pluton and measured field fabrics in mylonite indicate syntectonic emplacement along the Proterozoic crustal scale dextral shear zone with repeated reactivation history.

  17. Developing and using the field emitter as a high intensity electron source

    Charbonnier, Francis


    In the 1940's, Erwin Müller dominated field emission research. The 50's and 60's saw considerable growth in the number of scientists interested in field emission. While many made important contributions, three persons stood out who had different talents and interests. First and foremost: Erwin Müller, a very innovative, creative and skilled inventor and experimentalist. Second: Robert Gomer, equally adept at theory and experiment, with a unique mastery of fundamental physics concepts. Third: Walter Dyke, who was intrigued by the unique properties of field emission and resolved to develop field emission cathodes as high performance electron sources for a variety of electron beam devices. This paper summarizes Dyke's work at Linfield College, Linfield Research Institute and Field Emission Corporation from 1948 to 1972. However, while Dyke established a solid foundation for useful field emission cathodes and investigated several devices, particularly in microwaves, electron optics and flash radiography, he was unable to complete his work and produce commercial devices, except for flash radiography. Many groups have pursued this work in recent years, sometimes with great success. This paper briefly summarizes current work on field emission cathodes and device applications, as this puts Dyke's work in better perspective and adds to its significance.

  18. Homophobia in Secondary Schools: An Investigation of Teachers' Perceptions of Homophobia through a Collaborative Professional Development Program

    Jones, Joseph R.


    According to Gay Lesbian Straight Education Network, GLSEN, (2003), 84% of GLBT students experienced homophobic remarks or verbal harassment and of those, 91.5% reported hearing the word "faggot" or "dyke" on a regular basis, and over 60% felt unsafe in their schools because of their sexual orientation. More recently, several middle school…

  19. The Politics of Resilience in the Dutch ‘Room for the River’-project

    De Bruijn, J.A.; De Bruijne, M.L.C.; Ten Heuvelhof, E.F.


    An increased focus on the concept of resilience in flood protection has led to the development of a comprehensive flood protection strategy in the Netherlands which stresses the need to provide ‘Room for the River’ rather than building dykes. But how can a resilient solution in flood protection be

  20. Mangrove restoration in Vietnam: Key considerations and a practical guide

    Marchand, M.


    In Vietnam mangrove rehabilitation has a long history and gained momentum after the war that destroyed huge forested areas, especially in the Mekong Delta. In addition, in various places mangrove have been and still are being planted specifically as a way to protect shorelines and sea-dykes from wav

  1. 75 FR 77945 - Qualification of Drivers; Exemption Applications; Vision


    ...: Dr. Mary D. Gunnels, Director Medical Programs, 202-366-4001, U.S. Department of Transportation... Wesley A. Roberson Charles J. Dawber Darrell A. Harmon David M. Taylor Richard C. Dickinson Thomas W... is only allowed 2 moving citations: Wesley M. Creamer Gregory C. Simmons Christopher J. Van Dyke...

  2. Matriarchal village.

    Siegel, T S


    SUMMARY This story of a gypsy-dyke first experiencing polyamory is set in the 1970s in an Oregon college town, where radical feminists considered non-monogamy an important way to strengthen lesbian tribal bonds. Personal struggles with jealousy and community support for rejecting coupleism are captured in this piece.

  3. Editorial: The governance of adaptation to climate change as a multi-level, multi-sector and multi-actor challenge: a European comparative perspective

    Dewulf, A.R.P.J.


    There is increasing recognition of the need for society to adapt to the impacts of climate change, especially in the water sector. Adaptation to climatic impacts involves both infrastructural adjustments, such as reinforcing dykes or creating water storage capacity, and broader processes of societal

  4. Integrated interpretation of 3D seismic data to enhance the detection of the gold-bearing reef: Mponeng Gold mine, Witwatersrand Basin (South Africa)

    Manzi, M


    Full Text Available than 25 m but greater than 2-m throw were identified through horizon-based attribute analysis, while most dykes and sills with thickness less than 25 m were invisible. The detection of the lateral continuity of the Carbon Leader Reef reflector and its...

  5. A method for geometric modelling of magnetic anomalies: Two dimensional bodies

    Rao, T.C.S.

    for bodies of different shapes. A procedure has been evolved to compute the anomalies for all types of step and dyke models from a single formula by suitably reorienting the 'step model and by redefining its edges and the slope or dip angle. This method also...

  6. Shrimp-based livelihoods in mangrove silvo-aquaculture farming systems

    Bosma, R.H.; Nguyen, T.H.; Siahainenia, A.J.; Tran, H.T.P.; Tran, H.N.


    The paper reviews the following three types of mangrove-shrimp systems: (i) integrated with canals between platforms planted with mangrove; (ii) associated having larger areas of water and a large mangrove area; and (iii) separated, with a dyke separating ponds from forest. The variations in shrimp

  7. Social impacts of earthquakes caused by gas extraction in the Province of Groningen, The Netherlands

    van den Voort, Nick; Vanclay, Frank


    Gas extraction from the Groningen gasfield in the northern Netherlands has led to localized earthquakes which are projected to become more severe. The social impacts experienced by local residents include: damage to property; declining house prices; concerns about the chance of dykes breaking; feeli

  8. Drop floating on a granular raft

    Jambon-Puillet, Etienne; Protière, Suzie


    This paper is associated with a poster winner of a 2015 APS/DFD Milton van Dyke Award for work presented at the DFD Gallery of Fluid Motion. The original poster is available from the Gallery of Fluid Motion,

  9. Placement of Smart Grass reinforcement at test sections Groningen Sea dike

    van Gerven, K.A.J.; Akkerman, G.J.


    The present report deals with the application of a provisional Smart Grass Reinforcement (SGR) system in 2006 for full scale testing of increased overtopping at the Groningen sea dyke test section near Delfzijl, as envisaged in 2007. The SGR has been placed at two strips of 4 m wide: one primary str

  10. Biogeochemical constraints on the ecological rehabilitation of wetland vegetation in river floodplains

    Lamers, L.P.M.; Loeb, R.; Antheunisse, A.M.; Miletto, M.; Lucassen, E.C.H.E.T.; Boxman, A.W.; Smolders, A.J.P.; Roelofs, J.


    The European policy for river management during peak discharge periods is currently changing from exclusion strategies (reinforcement of dykes) to allowing a more natural situation by creating more floodplain space to reduce water levels during peak discharges. In addition, water retention and water

  11. The Politics of Resilience in the Dutch ‘Room for the River’-project

    De Bruijn, J.A.; De Bruijne, M.L.C.; Ten Heuvelhof, E.F.


    An increased focus on the concept of resilience in flood protection has led to the development of a comprehensive flood protection strategy in the Netherlands which stresses the need to provide ‘Room for the River’ rather than building dykes. But how can a resilient solution in flood protection be s

  12. National Reye's Syndrome Foundation

    ... Library eBooks & Apps Dick Van Dyke; NRSF Spokesperson Android Apps & eBooks The NRSF Blog School and Health Department ... Effort to Eradicate Reye's We've created an App for the Android phone and tablets all about Aspirin, from lists ...

  13. Beyond the Stars and Stripes

    Carter, Dale


    During the early 1970s the American song-writer, musician and producer Van Dyke Parks completed work on a series of albums exploring the musical contours of the circum-Caribbean region and, through them, broader patterns and issues in 20th century US-Caribbean relations. Focusing on the connectio...

  14. Beyond the Stars and Stripes

    Carter, Dale


    During the early 1970s the American song-writer, musician and producer Van Dyke Parks completed work on a series of albums exploring the musical contours of the circum-Caribbean region and, through them, broader patterns and issues in 20th century US-Caribbean relations. Focusing on the connectio...

  15. Complete preservation of ophiolite suite from south Andaman, India: A mineralchemical perspective

    Abhishek Saha; Avik Dhang; Jyotisankar Ray; Suvankar Chakraborty; David Moecher


    Field studies supplemented by petrographic analyses clearly reveal complete preservation of ophiolite suite from Port Blair (11° 39′ N: 92° 45′E) to Chiriyatapu (11° 30′ 24′′N: 92° 42′ 30′′E) stretch of South Andaman. The ophiolite suite reveals serpentinite at the base which is overlain unconformably by cumulate ultramafic–mafic members with discernible cumulus texture and igneous layering. Basaltic dykes are found to cut across the cumulate ultramafic–mafic members. The succession is capped by well exposed pillow basalts interlayered with arkosic sediments. Olivine from the basal serpentinite unit are highly magnesian (Fo80.1–86.2). All clinopyroxene analyses from cumulate pyroxenite, cumulate gabbro and basaltic dyke are discriminated to be `Quad’ and are uniformly restricted to the diopside field. Composition of plagioclase in different lithomembers is systematically varying from calcic to sodic endmembers progressively from cumulate pyroxenite to pillow basalt through cumulate gabbro and basaltic dyke. Plagioclase phenocrysts from basaltic dyke are found to be distinctly zoned (An60.7–An35.5) whereas groundmass plagioclase are relatively sodic (An33–An23.5). Deduced thermobarometric data from different lithomembers clearly correspond to the observed preservation of complete ophiolite suite.

  16. ContoExam: an ontology on context-aware examinations

    Brandt, P.; Basten, A.A.; Stuijk, S.


    Patient observations in health care, subjective surveys in social research or dyke sensor data in water management are all examples of measurements. Several ontologies already exist to express measurements, W3C's SSN ontology being a prominent example. However, these ontologies address quantities

  17. Volcano-tectonics of the Al Haruj Volcanic Province, Central Libya

    Elshaafi, Abdelsalam; Gudmundsson, Agust


    The Al Haruj intra-continental Volcanic Province (AHVP), located at the south-western margin of the Sirt Basin, hosts the most extensive and recent volcanic activity in Libya - which is considered typical for plate interiors. From north to south the AHVP is divided into two subprovinces, namely Al Haruj al Aswad and Al Haruj al Abiyad. The total area of the AHVP is around 42,000 km2. Despite the great size of the AHVP, its volcano-tectonic evolution and activity have received very little attention and are poorly documented and understood. Here we present new field data, and analytical and numerical results, on the volcano-tectonics of the AHVP. The length/thickness ratio of 47 dykes and volcanic fissures were measured to estimate magmatic overpressure at the time of eruption. The average dyke (length/thickness) ratio of 421 indicates magmatic overpressures during the associate fissure eruptions of 8-19 MPa (depending on host-rock elastic properties). Spatial distributions of 432 monogenetic eruptions sites/points (lava shields, pyroclastic cones) in the AHVP reveal two main clusters, one in the south and another in the north. Aligned eruptive vents show the dominating strike of volcanic fissures/feeder-dykes as WNW-ESE to NW-SE, coinciding with the orientation of one of main fracture/fault zones. Numerical modelling and field observations suggest that some feeder-dykes may have used steeply dipping normal-fault zones as part of their paths to the surface.

  18. Manma—Fluid Transition and the Genesis of Pegmatite Dike No.3,Altay,Xinjiang,Northwest China

    卢焕章; 王中刚; 等


    The physico-chemical conditions under which the pegmatite dyke No.3 was formed were discussed in the light of fluid-melt inclusion evidence.Our results lend support to the fractionation of hydrothermal solutions from magma,For the pegmatite dike No.3,the magmaderived hydrothermal solutions are dominated by NaCl+CO2+H2O.

  19. Partitions, Compartments and Portals: Cave Development in internally impounded karst masses.

    Osborne R. Armstrong L.


    Full Text Available Dykes and other vertical bodies can act as aquicludes within bodies of karst rock. These partitions separate isolated bodies of solublerock called compartments. Speleogenetically each compartment will behave as a small impounded-karst until the partition becomesbreached. Breaches through partitions, portals, allow water, air and biota including humans to pass between sections of caves thatwere originally isolated.

  20. The Vegetables Turned:

    Carter, Dale


    lyricist Van Dyke Parks, the incongruous, semantically complex figure of the vegetable came to illuminate aspects of psychedelic consciousness and - part by design, part by accident - the link between LSD and Anglo-American popular music. It threw light, too, on the scope and limits of changes...

  1. Uncovering the Cornfield

    Carter, Dale


    Observers agree that a pivotal factor in the abandonment of the Beach Boys’ Smile album in 1967 was the hostility shown by group members to some of Brian Wilson co-writer Van Dyke Parks’s lyrics. The latter still tend, however, to be cited more than they are analyzed. This reading of the song...

  2. Editorial: The governance of adaptation to climate change as a multi-level, multi-sector and multi-actor challenge: a European comparative perspective

    Dewulf, A.R.P.J.


    There is increasing recognition of the need for society to adapt to the impacts of climate change, especially in the water sector. Adaptation to climatic impacts involves both infrastructural adjustments, such as reinforcing dykes or creating water storage capacity, and broader processes of societal

  3. A review of reflection seismic investigations in three major metallogenic regions: The Kevitsa Ni–Cu–PGE district (Finland), Witwatersrand goldfields (South Africa), and the Bathurst Mining Camp (Canada)

    Malehmir, A


    Full Text Available long-standing controversy regarding the origin of the gold in the Basin. For example, it might be possible to show that dykes formed impermeable barriers, thereby falsifying the epigenetic hydrothermal models. 2D and 3D seismic data from the Brunswick...


    lent of monotherapy, which should generally be avoided at all costs. A variant of .... Van Dyke RB, Lee S, Johnson GM, et al. Reported adherence ... Richman D, Staszewski S. A Practical Guide to HIV Drug Resistance and its. Implications for ...

  5. ContoExam: an ontology on context-aware examinations

    Brandt, P.; Basten, A.A.; Stuijk, S.


    Patient observations in health care, subjective surveys in social research or dyke sensor data in water management are all examples of measurements. Several ontologies already exist to express measurements, W3C's SSN ontology being a prominent example. However, these ontologies address quantities an

  6. Evaluatie van het project `Fryske Diken' : evaluatie van de effecten van geïntensiveerd politietoezicht in het verkeer in Friesland in de periode februari-december 1998. In opdracht van het Directoraat-Generaal Rijkswaterstaat, Adviesdienst Verkeer en Vervoer AVV.

    Goldenbeld, C. Mathijssen, M.P.M. & Bunk, K.


    In February 1998, an ambitious project with intensified police surveillance began in the northern province of Friesland. It was called "Frisian Dykes". This report describes an evaluation study into the effects of intensified police surveillance on speeding, drunken driving, seat belt use, and the n

  7. Time-dependent behaviour of deep level tabular excavations in hard rock

    Malan, DF


    Full Text Available to the lateral extent of the orebody (Fig. 1). Although the reef is frequently dislocated by faults and dykes, the plane tabular nature of the orebody can persist for many square kilo- metres in some areas. Although the reef can be nearly horizontal in certain...

  8. Social impacts of earthquakes caused by gas extraction in the Province of Groningen, The Netherlands

    van den Voort, Nick; Vanclay, Frank


    Gas extraction from the Groningen gasfield in the northern Netherlands has led to localized earthquakes which are projected to become more severe. The social impacts experienced by local residents include: damage to property; declining house prices; concerns about the chance of dykes breaking; feeli

  9. Beyond the Stars and Stripes

    Carter, Dale


    During the early 1970s the American song-writer, musician and producer Van Dyke Parks completed work on a series of albums exploring the musical contours of the circum-Caribbean region and, through them, broader patterns and issues in 20th century US-Caribbean relations. Focusing on the connectio...

  10. Beyond the Stars and Stripes

    Carter, Dale


    During the early 1970s the American song-writer, musician and producer Van Dyke Parks completed work on a series of albums exploring the musical contours of the circum-Caribbean region and, through them, broader patterns and issues in 20th century US-Caribbean relations. Focusing on the connectio...

  11. The Vegetables Turned:

    Carter, Dale


    lyricist Van Dyke Parks, the incongruous, semantically complex figure of the vegetable came to illuminate aspects of psychedelic consciousness and - part by design, part by accident - the link between LSD and Anglo-American popular music. It threw light, too, on the scope and limits of changes...

  12. Natural variation in flowering time among populations of the annual crucifer Arabidopsis thaliana

    Hammad, I.; Van Tienderen, P.H.


    Genetic variation in flowering time was studied in four natural populations of Arabidopsis thaliana, using greenhouse experiments. Two populations from ruderal sites flowered early, two others from river dykes late. However, the late flowering plants flowered almost as early as the others after cold

  13. Evaluatie van het project `Fryske Diken' : evaluatie van de effecten van geïntensiveerd politietoezicht in het verkeer in Friesland in de periode februari-december 1998. In opdracht van het Directoraat-Generaal Rijkswaterstaat, Adviesdienst Verkeer en Vervoer AVV.

    Goldenbeld, C. Mathijssen, M.P.M. & Bunk, K.


    In February 1998, an ambitious project with intensified police surveillance began in the northern province of Friesland. It was called "Frisian Dykes". This report describes an evaluation study into the effects of intensified police surveillance on speeding, drunken driving, seat belt use, and the n

  14. Flood forecasting using artificial neural networks

    Varoonchotikul, P.


    Flood disasters continue to occur In many countries around the world and cause tremendous casualtles and properties damage. To mitigate the effects of floods, both structural and non-structural measures can be employed, such as dykes, channelisatlon, flood proofing of properties, land-use regulation

  15. Applying energy autonomous robots for dike inspection

    Dresscher, Douwe; Vries, de Theo J.A.; Stramigioli, Stefano


    This article presents an exploratory study of an energy-autonomous robot that can be deployed on the Dutch dykes. Based on theory in energy harvesting from sun and wind and the energy-cost of locomotion an analytic expression to determine the feasible daily operational time of such a vehicle is comp

  16. Synthetic Decapeptide Enhances Bacterial Clearance and Accelerates Healing in the Wounds of Restraint-Stressed Mice


    full thickness wounds were created, just below the shoulder blades , using a sterile 3.5 mm biopsy punch (Miltex Inc., York, PA). 2.4. Synthesis of... Runner , R.R., McPherson, J.C., Van Dyke, T.E., 2000. Pluronic polyol effects on human gingival fibroblast attachment and growth. J. Periodontol. 71 (5

  17. Chemistry, mineralogy and alteration intensity of hydrothermal altered Mt Unzen conduit rocks (Shimabara/Japan)

    Hess, Kai-Uwe; Yilmaz, Tim; Gilg, H. Albert; Janots, Emilie; Mayer, Klaus; Nakada, Setsuya; Dingwell, Donald


    Investigations were carried out on hydrothermally altered coherent dacitic dykes samples from (USDP-4) drill core at Mt Unzen stratovolcano (Shimabara/Japan). XRF, XRD, EMPA, C-O-isotope, hot-cathode CL and SEM analysis led to insights concerning chemistry, mineralogy, and intensity and type of alteration as well as the origin of carbonate-precipitating fluids. Additionally a textural characterization of the occurring replacement features in the volcanic conduit rocks was performed. The occurrence of the main secondary phases such as chlorite, pyrite, carbonates, and R1 (Reichweite parameter) illite-smectite and kaolinite group minerals indicate a weak to moderate propylitic to phyllic hydrothermal alteration. The dacitic samples of the dykes show different hydrothermal alteration features: (i) carbonate and chlorite pseudomorphs after hornblende as well as core and zonal textures due to replacement of plagioclase by R1 illite-smectite as well as kaolinite group minerals, (ii) colloform banded fracture fillings and fillings in dissolution vugs, and (iii) chlorite, R1 illite-smectite as well as kaolinite group minerals in the groundmass. Late chlorite veins crosscut precipitates of R1 illite-smectite as well as kaolinite group minerals. Carbonates in fractures and in pseudomorphs after hornblende comprise iron-rich dolomite solid solutions ("ankerite") and calcite. Isotopic values indicate a hydrothermal-magmatic origin for the carbonate formation. The chlorite-carbonate-pyrite index (CCPI) and the Ishikawa alteration index (AI), applied to the investigated samples show significant differences (CCPI=52.7-57.8; AI=36.1-40.6) indicating their different degree of alteration. According to Nakada et al., 2005, the C13 to C16 dykes represent the feeder dyke from the latest eruption (1991-1995) whereas C8 represents an earlier dyke feeder dyke from an older eruption. Weakest alteration, which was obtained in samples C16-1-5 and C13-2-5, correlates with the alteration

  18. Hydrothermal Alteration of the Mt Unzen Conduit (Shimabara/Japan)

    Yilmaz, T. I.; Mayer, K.; Hess, K. U.; Janots, E.; Gilg, H. A.; Dingwell, D. B.


    Investigations were carried out on hydrothermally altered coherent dacitic dykes samples from (USDP-4) drill core at Mt Unzen stratovolcano (Shimabara/Japan). XRF, XRD, EMPA, and C-O-isotope analysis led to insights concerning chemistry, mineralogy, and intensity of alteration as well as the origin of carbonate-precipitating fluids. Additionally a textural characterization of the occurring replacement features in the magma conduit zone was performed. The occurrence of the main secondary phases such as chlorite, pyrite, carbonates, and R1 (Reichweite parameter) illite-smectite indicate a weak to moderate propylitic to phyllic hydrothermal alteration. The dacitic samples of the dykes show different hydrothermal alteration features: (i) carbonate pseudomorphs after hornblende as well as core and zonal textures due to replacement of plagioclase by R1 illite-smectite, (ii) colloform banded fracture fillings and fillings in dissolution vugs, and (iii) chlorite and R1 illite-smectite in the groundmass. Carbonates in fractures comprise iron-rich dolomite solid solutions ("ankerite") and calcite. Isotopic values of d13Cvpdb = -4.59 ± 0.6‰ and d18Ovpdb = -21.73 ± 0.5‰ indicate a hydrothermal-magmatic origin for the carbonate formation. The chlorite-carbonate-pyrite index (CCPI) and the Ishikawa alteration index (AI), applied to the investigated samples show significant differences (CCPI=52.7-57.8; AI=36.1-40.6) indicating their different degree of alteration. According to Nakada et al., 2005, the C13 to C16 dykes represent the feeder dyke from the latest eruption (1991-1995) whereas C8 represents an earlier dyke feeder dyke from an older eruption. Weakest conduit alteration, which was obtained in samples C16-1-5 and C13-2-5, correlates with the alteration degree of the pristine dome rocks. Highest CCPI value was determined for sample C14-1-5 and the highest AI value was determined for sample C15-2-6. The degrees of alteration do not indicate highest alteration of the

  19. High-precision mapping of seismicity in the 2014 Bárdarbunga volcanic episode

    Vogfjörd, Kristín S.; Hensch, Martin; Gudmundsson, Gunnar B.; Jónsdóttir, Kristín


    The Bárdarbunga volcano and its associated fissure swarm in Iceland's Eastern volcanic zone is a highly active system with over 20 eruptions in the last 11 centuries. The location of this active volcano and much of the fissure swarm under several hundred metres thick ice gives rise to multiple hazards, including explosive, subglacial eruptions and associated subglacial floods (jökulhlaups), as well as fissure eruptions extruding large volumes of lava. After a decade of increasing seismic activity, volcanic unrest at Bárdarbunga suddenly escalated into a minor subglacial eruption on 16 August 2014. In the following weeks seismic activity soared and surface deformation of tens of cm were observed, caused by rifting and a dyke intrusion, which propagated 48 km northward from the central volcano (Sigmundsson et al., 2014). The dyke propagation stopped just outside the glacial margin and ended in a fissure eruption at Holuhraun at the end of August. At the time of writing the eruption is ongoing, having extruded a lava volume of over 1 km3 and released high rates of SO2 into the atmosphere. Over twenty thousand microearthquakes have been recorded. Initially most were in the dyke, but after the first two weeks the activity around the caldera rim increased and over 70 shallow earthquakes with MW > 5 have been located along the caldera rim accompanied by caldera subsidence. At the onset of the unrest on 16 August, the seismicity was located in the caldera and north of the caldera rim, but already in the first few hours the activity propagated out of the caldera to the SE. Still, the activity continued for a few days in the fissure swarm to the NE of the rim. High-precision earthquake locations in the propagating dyke have revealed its very detailed, planar rifting segments, with the events distributed over a 3-4 km depth range, and mostly between 6 and 9 km. These very planar event distributions are highly unusual in volcanic areas and strongly suggest rifting of

  20. A non-plume model for the Permian protracted (266-286 Ma) basaltic magmatism in the Beishan-Tianshan region, Xinjiang, Western China

    Xue, Sheng-Chao; Li, Chusi; Qin, Ke-Zhang; Tang, Dong-Mei


    The convenient mantle plume model for the Permian protracted mafic-ultramafic intrusions and mafic dykes (266-286 Ma) in the Beishan-Tianshan region, northern Xinjiang, western China can be rejected, because their temporal-spatial distribution does not show a hotspot track predicted by such model. New zircon U-Pb ages reveal that two small mafic dyke clusters (Podong, 280.5 ± 2 Ma; Luodong, 266.2 ± 3.2 Ma) that are separated by only ~ 20 km in the Pobei area, the southernmost part of the Beishan-Tianshan region, have a large age difference of ~ 18 Ma. The older mafic dykes are characterized by nearly flat mantle-normalized rare-earth-element patterns, pronounced negative Nb-Ta anomalies and positive εNd(t) values from 5.5 to 7.5, similar to the majority of the Permian mafic-ultramafic intrusions in the region. The younger mafic dykes are characterized by significant light rare-earth-element enrichments as well as pronounced negative Nb-Ta anomalies, plus lower εNd(t) (- 1.2 to 2.6) values and higher initial 87Sr/86Sr ratios than the older mafic dykes. The observed compositional variations can be explained by source mantle heterogeneity plus different degrees of crustal contamination. Overall, the Permian mafic-ultramafic rocks in the Beishan-Tianshan region are geochemically consistent with the products of basaltic magmatism induced by lithospheric delamination and asthenosphere upwelling in a convergent tectonic zone.

  1. Subaerial exposure and drowning processes in a carbonate platform during the Mesozoic Tethyan rifting: The case of the Jurassic succession of Western Sicily (central Mediterranean)

    Sulli, A.; Interbartolo, F.


    The Liassic carbonate platform succession outcropping at Monte Maranfusa (central Western Sicily) consists of a shallowing-upward sequence of peritidal carbonates, with Jurassic to Paleogene pelagic limestone and siliciclastic Tertiary covers above. The cyclic sequences of subtidal wackestones/packstones, intertidal microcrystalline carbonates with bird's-eye pores, and supratidal bioclastic grainstones are interbedded with dark layers of the following composition: 1) dark-gray, compact, and well-cemented limestone with blackish clasts, interpreted as calcretes (a type of carbonate soil) and 2) reddish calcite laminae, deformed by elongated cavities, filled with vadose silt, interpreted as paleokarst. This succession is crossed by almost vertical faults, of the Late Liassic to Miocene, which often coincides with neptunian dykes, filled by several generations of Toarcian-Early Miocene pelagic sediments. Another system of dykes, known as neptunian sills, filled by injected Upper Lias-Dogger pelagic sediments, lies parallel to the stratification. The parallel dykes were caused by the flexure of the platform during the Jurassic and presumably by a planar slip in the carbonate rocks, whereas neptunian dykes are caused by faulting episodes. Here, we present evidence that the dark layers in the Liassic succession of Monte Maranfusa, previously described by many authors only as parallel dykes, can actually be interpreted as a) neptunian sills, b) pedogenic calcretes, and c) paleospeleothems. Therefore, we found evidence of exposure/flooding intervals in the evolution of the carbonate platform during the Liassic, linked to different pulses in both the subsidence/tectonic activity and the sea-level oscillations. At the top, Fe-Mn crusts (hardgrounds) seal the carbonate platform succession, which is in turn overlain by condensed pelagic deposits, confirming its drowning during rifting processes.

  2. Utilising Geological Field Measurements and Historic Eruption Volumes to Estimate the Volume of Santorini's Magma Chamber

    Browning, J.; Drymoni, K.; Gudmundsson, A.


    An understanding of the amount of magma available to supply any given eruption is useful for determining the potential eruption magnitude and duration. Geodetic measurements and inversion techniques are often used to constrain volume changes within magma chambers, as well as constrain location and depth, but such models are incapable of calculating total magma storage. For example, during the 2012 unrest period at Santorini volcano, approximately 0.021 km3 of new magma entered a shallow chamber residing at around 4 km below the surface. This type of event is not unusual, and is in fact a necessary condition for the formation of a long-lived shallow chamber, of which Santorini must possess. The period of unrest ended without culminating in eruption, i.e the amount of magma which entered the chamber was insufficient to break the chamber and force magma further towards the surface. We combine previously published data on the volume of recent eruptions at Santorini together with geodetic measurements. Measurements of dykes within the caldera wall provide an estimate of the volume of magma transported during eruptions, assuming the dyke does not become arrested. When the combined volume of a dyke and eruption are known (Ve) they can be used to estimate using fracture mechanics principles and poro-elastic constraints the size of an underlying shallow magma chamber. We present field measurements of dykes within Santorini caldera and provide an analytical method to estimate the volume of magma contained underneath Santorini caldera. In addition we postulate the potential volume of magma required as input from deeper sources to switch the shallow magma chamber from an equilibrium setting to one where the pressure inside the chamber exceeds the surrounding host rocks tensile strength, a condition necessary to form a dyke and a possible eruption.

  3. Decoding micro-structural damage related to caldera collapse at Santorini Volcano

    Drymoni, Kyriaki; Browning, John; Gudmundsson, Agust; Mitchell, Thomas


    Deformation in damage zones, as micro fracture density, can be estimated at a given distance from a fault as a function of fault displacement, based on empirical relationships derived from detailed quantitative field studies of natural faults that cut through low porosity, crystalline rocks in strike-slip tectonic environments. For the first time, we attempt to apply the same method to study the characteristics of a damage zone generated by caldera collapse along a bounding circumferential ring-fault. We have undertaken a field campaign at Santorini Volcano, Greece, and mapped sections of a dyke swarm in the northern caldera wall. The dykes, associated lavas, and eruptive units are partially cut by a series of historic caldera collapses. The dykes represent elastic inclusions in an otherwise heterogeneous and complex edifice which makes up the Santorini Volcano. To study caldera-related damage we sampled dykes at varying distance from the inferred caldera fault. The collected samples were cut into several different orientations to map micro-fracture density and orientation with relation to the strike of the historic caldera faults. In addition, benchtop ultrasonic wave velocity measurements were made on all samples. Preliminary fracture analysis of plagioclase crystals and velocity data suggests relationship between proximity to the fault and micro-fracture density. We also find a mechanical anisotropy control which may relate to the orientation of fractures generated by historic caldera collapses on Santorini. An analysis of the anisotropy and micro-fractures may help to identify the mechanism of caldera faulting at Santorini (e.g. near-surface tension fractures and normal faulting or reverse faulting). In addition to our micro-structural study, we will investigate the presence of hydrothermal/chemical alteration within the inferred caldera damage zone. Our aim is to set up numerical models to investigate stress distribution within the dykes and host rock during

  4. Distribution of Platinum-Group Elements in Chromite Ores of the Sorkhband Ultramafic Complex, Kerman, Southeastern Iran

    Najafzadeh, Alireza; Arvin, Mohsen; Ahmadipour, Hamid; Pan, Yuanming


    The Ordovician Sorkhband ultramafic complex lies in southern Kerman Province of Iran. The wedge shape complex covers an area of more than 100 km2 and is divided into: lower part comprises of dunites, largest podiform chromitite deposits in Iran (Faryab mine), olivine clinopyroxenite dykes and massive's, wehrlite and olivine websterite dykes; and upper part comprises of clinopyroxene bearing harzburgites, with subordinate lenses and dykes of dunite, massive and dyke like olivine clinopyroxenite and minor orthopyroxenite dykes with no significant chromitite mineralization. Chromitite orebodies exhibit variable sizes and shapes, forming pods, lenses, bands, vein-like bodies and rich dissemination. Podiform chromitites in dunite form tabular to lenticular bodies although may occur also as pencil-like masses. The chromitites occur in four distinct textural modes. Massive, disseminated, banded and nodular chromitites are the most common textural types and commonly grade into one other. Massive chromitites have sharp contacts with the enclosing dunite whereas disseminated bodies grade outward into dunite and occasionally pass into interbanded chromitite and dunite. A detailed electron microprobe study reveals very high Cr#, Mg# and very low TiO2 contents for chromian spinels in chromitites. The Sorkhband chromitites contain up to 440 ppb total PGE, and display a systematic enrichment in IPGE relative to PPGE, with a steep negative slope in the PGE spidergrams and very low PPGE/IPGE ratios, a feature typical of ophiolitic podiform chromitites worldwide. The mineral chemistry data and PGE geochemistry of the chromitites indicates that the Sorkhband ultramafic complex was generated from an arc-related magma with boninitic affinity in a supra-subduction zone setting.

  5. Isotopic (Pb, Sr, Nd, C, O) evidence for plume-related sampling of an ancient, depleted mantle reservoir

    Chen, Wei; Simonetti, Antonio


    The exact mantle source for carbonatite melts remains highly controversial. Despite their predominant occurrence within continental (lithospheric) domains, the radiogenic isotope data from young (oceanic island basalts (OIBs). This feature suggests an intimate petrogenetic relationship with asthenospheric mantle. New Pb, Sr, C, and O isotopic data are reported here for constituent minerals from the Oka carbonatite complex, which is associated with the Cretaceous Monteregian Igneous Province (MIP), northeastern North America. The Pb isotope data define linear arrays in Pb-Pb isotope diagrams, with the corresponding Sr isotope ratios being highly variable (0.70314-0.70343); both these features are consistent with open system behavior involving at least three distinct mantle reservoirs. Compared to the isotope composition of known mantle sources for OIBs and carbonatite occurrences worldwide, the least radiogenic 207Pb/204Pb (14.96 ± 0.07) and 208Pb/204Pb (37.29 ± 0.15) isotopic compositions relative to their corresponding 206Pb/204Pb ratios (18.86 ± 0.08) reported here are distinct, and indicate the involvement of an ancient depleted mantle (ADM) source. The extremely unradiogenic Pb isotope compositions necessitate U/Pb fractionation early in Earth's history (prior to 4.0 Ga ago) and growth via a multi-stage Pb evolution model. The combined stable (C and O) and radiogenic isotopic compositions effectively rule out crustal/lithosphere contamination during the petrogenetic history of the Oka complex. Instead, the isotopic variations reported here most likely result from the mixing of discrete, small volume partial melts derived from a heterogeneous plume source characterized by a mixed HIMU-EM1-ADM signature.

  6. Key new pieces of the HIMU puzzle from olivines and diamond inclusions

    Weiss, Yaakov; Class, Cornelia; Goldstein, Steven L.; Hanyu, Takeshi


    Mantle melting, which leads to the formation of oceanic and continental crust, together with crust recycling through plate tectonics, are the primary processes that drive the chemical differentiation of the silicate Earth. The present-day mantle, as sampled by oceanic basalts, shows large chemical and isotopic variability bounded by a few end-member compositions. Among these, the HIMU end-member (having a high U/Pb ratio, μ) has been generally considered to represent subducted/recycled basaltic oceanic crust. However, this concept has been challenged by recent studies of the mantle source of HIMU magmas. For example, analyses of olivine phenocrysts in HIMU lavas indicate derivation from the partial melting of peridotite, rather than from the pyroxenitic remnants of recycled oceanic basalt. Here we report data that elucidate the source of these lavas: high-precision trace-element analyses of olivine phenocrysts point to peridotite that has been metasomatized by carbonatite fluids. Moreover, similarities in the trace-element patterns of carbonatitic melt inclusions in diamonds and HIMU lavas indicate that the metasomatism occurred in the subcontinental lithospheric mantle, fused to the base of the continental crust and isolated from mantle convection. Taking into account evidence from sulfur isotope data for Archean to early Proterozoic surface material in the deep HIMU mantle source, a multi-stage evolution is revealed for the HIMU end-member, spanning more than half of Earth’s history. Before entrainment in the convecting mantle, storage in a boundary layer, upwelling as a mantle plume and partial melting to become ocean island basalt, the HIMU source formed as Archean-early Proterozoic subduction-related carbonatite-metasomatized subcontinental lithospheric mantle.

  7. Deformation derived from GPS geodesy associated with Bárðarbunga 2014 rifting event in Iceland

    Ofeigsson, Benedikt Gunnar


    On August 16, 2014 an intense seismic swarm started below the eastern part of Bárðarbunga Caldera in the north-western corner of Vatnajökull ice-cap, Iceland, marking the onset of the first rifting event in Iceland since the Krafla fires (1975-1984). The migration of the seismicity was corroborated by ground deformation in areas outside the ice cap and on nunataks within the ice cap suggesting a lateral propagation of magma, from the Bárðabunga system. The sesimicity migrated out of the caldera forming a dyke with roughly three segments, changing direction each time until August 28 when the migration stopped around 10 km south of Askja Volcano, eventually leading to a short lived eruption in Holuhraun north of Dyngjujökull. A second fissure eruption started in Holuhraun on August 31 which is still ongoing at the time of this writing. In the months prior to the onset of the activity, subtle signs of inflation where observed on continuous GPS sites around the Bárðarbunga indicating a volume increase in the roots of the volcanic system. When the activity started on August 16, the deformation pattern indicated a simultaneous deflation centered within the caldera and a lateral growth of a dyke also reflected in the migration of seismicity along segments of variable strike. A maximum widening of 1.3 m occurred between stations on opposite sides of the dyke spaced 25 km apart. Significant movements where detected on GPS site more then 80 km away from the tip of dyke. Displacements indicated the fastest rate of widening at any time in the most distal segment of the dyke throughout its evolution. After the dyke stopped propagating, the inflation continued, decaying exponentialy with time. On September 4, five days into the second fissure eruption, the movements associated with the dyke where no longer significant. As the fissure eruption continues, a slowly decaying contraction is observed around the Bárðarbunga central volcano, both shown in the piston like

  8. The giant Kalgoorlie Gold Field revisited

    Noreen Mary Vielreicher; David Ian Groves; Neal Jesse McNaughton


    The Neoarchaean Kalgoorlie Gold Field contains the giant Golden Mile and world-class Mt Charlotte deposits, which have been the subject of much research for over 100 years. The Golden Mile deposit is a complex array of ductile to brittle vein and breccia lodes that are predominantly hosted in the highly-fractionated Golden Mile Dolerite sill. The Fimiston lodes comprise an array of narrow lodes that evolved broadly syn- to late-formation of the regional D2 NW-trending foliation. The lodes are charac-terized by pyrite veinlets and disseminations, quartz veinlets and breccias, and banded quartz-carbonate veins with sericite, carbonate, and pyrite-dominated alteration. Bonanza Green-Leader, or Oroya-style, lodes, with grades in excess of 1000 g/t Au, are similar to the Fimiston-style lodes, but are character-ized by abundant visible gold, native tellurium and more abundant telluride minerals within roscoelite-bearing alteration zones. The arguably structurally younger Mt Charlotte-style lodes are characterized by a pipe-shaped, coarse-grained quartz, carbonate and scheelite vein-stockwork with distinct vertically-zoned, carbonate-sericite-albite-pyrite ? pyrrhotite dominant alteration assemblages around veins within Unit 8 of the Golden Mile dolerite and porphyry dykes. The network of steep-and gently-dipping extension and shear fracture-fill veins are associated with NE-trending fault sets that cross cut the regional NW-trend. The deposit area is intruded by swarms of porphyry dykes, including syn-volcanic mafic dykes, early and volumetrically most significant c. 2.67 Ga feldspar-phyric porphyry dykes, as well as later c. 2.66‒2.65 Ga calc-alkaline hornblende-phyric dykes associated with younger c. 2.65‒2.64 Ga lamprophyre dykes. All post-volcanic dykes have similar orientations to the Fimiston lodes. The feldspar dykes are clearly overprinted by all styles of mineralization, although the relationship between hornblende-phyric and lamprophyre dykes and gold

  9. Synchronous alkaline and subalkaline magmatism during the late Neoproterozoic-early Paleozoic Ross orogeny, Antarctica: Insights into magmatic sources and processes within a continental arc

    Hagen-Peter, Graham; Cottle, John M.


    Extensive exposure of intrusive igneous rocks along the Ross orogen of Antarctica-an ancient accretionary orogen on the margin of East Gondwana-provides an exceptional opportunity to study continental arc magmatism. There is significant petrologic and geochemical variability in igneous rocks within a 500-km-long segment of the arc in southern Victoria Land. The conspicuous occurrence of carbonatite and alkaline silicate rocks (nepheline syenite, A-type granite, and alkaline mafic rocks) adjacent to large complexes of subalkaline granitoids is not adequately explained by traditional models for continental arc magmatism. Extensive geochemical analysis (> 100 samples) and zircon U-Pb geochronology (n = 70) confirms that alkaline and carbonatitic magmatism was partially contemporaneous with the emplacement of large subduction-related igneous complexes in adjacent areas. Major pulses of subalkaline magmatism were compositionally distinct and occurred at different times along the arc. Large bodies of subalkaline orthogneiss and granite (sensu lato) were emplaced over similar time intervals (ca. 25 Myr) to the north (ca. 515-492 Ma) and south (ca. 550-525 Ma) of the alkaline magmatic province, although the initiation of these major pulses of magmatism was offset by ca. 35 Myr. Alkaline and carbonatitic magmatism spanned at least ca. 550-509 Ma, overlapping with voluminous subalkaline magmatism in adjacent areas. The most primitive rocks from each area have similarly enriched trace element compositions, indicating some common characteristics of the magma sources along the arc. The samples from the older subalkaline complex have invariably low Sr/Y ratios (differentiation. The younger subalkaline complex and subalkaline rocks within the area of the alkaline province extend to higher Sr/Y ratios (up to 300), indicative of generation and differentiation at deeper levels. The significant spatial and temporal diversity in magmatism can be explained by a tectono-magmatic model

  10. GIS-based identification of areas with mineral resource potential for six selected deposit groups, Bureau of Land Management Central Yukon Planning Area, Alaska

    Jones, James V.; Karl, Susan M.; Labay, Keith A.; Shew, Nora B.; Granitto, Matthew; Hayes, Timothy S.; Mauk, Jeffrey L.; Schmidt, Jeanine M.; Todd, Erin; Wang, Bronwen; Werdon, Melanie B.; Yager, Douglas B.


    This study, covering the Bureau of Land Management (BLM) Central Yukon Planning Area (CYPA), Alaska, was prepared to aid BLM mineral resource management planning. Estimated mineral resource potential and certainty are mapped for six selected mineral deposit groups: (1) rare earth element (REE) deposits associated with peralkaline to carbonatitic intrusive igneous rocks, (2) placer and paleoplacer gold, (3) platinum group element (PGE) deposits associated with mafic and ultramafic intrusive igneous rocks, (4) carbonate-hosted copper deposits, (5) sandstone uranium deposits, and (6) tin-tungsten-molybdenum-fluorspar deposits associated with specialized granites. These six deposit groups include most of the strategic and critical elements of greatest interest in current exploration.

  11. 湖南某多金属矿田的成矿作用



    The multimetal mine described in this paper contains W, Mo, Bi, Sn, Be, Cu, Pb,Zn and etc. Deposits occur in Upper and Middle Devonian carbonatite rocks and exhibite apparent zonal arrangement around a small granite body with respect to the elements mentioned above. At least four periods of magmatic intrusion and mineralization are recognized within this distriet. A comagmatic origin is indicated for all the deposits by geological setting, mineral assemblages, the geochemistry of ore elements,isotopic compositions of lead and sulfur as well as fluid inclusion studies. Ore metals are derived chiefly from the granite while wall rocks cannot be excluded as a minor supplier.

  12. The Genetic Types of Baiyun Cave in Lincheng County of Hebei Province

    Yanping; SUN; Jian; WANG; Xiaoman; ZHANG; Qianhua; ZHENG; Huafang; HUANG


    Baiyun Karst Caverns in Lincheng County,Hebei Province,is a rare karst caverns in subhumid climate region of the north.It was developed in carbonatite strata,particularly in Zhangxia formation of the Middle Cambrain series.Erosion-corrosion landscape and chemical deposition landscape are abundant,They are various shapes,curtain drapery,cave flag,cave shield,stalactite,stalagmite,cave flowers,botryoid,soda straw are developed,especially heligmite,soda straw,cave flowers are the most characteristic.

  13. Formation of gold mineralization in ultramafic alkalic magmatic complexes

    Ryabchikov, I. D.; Kogarko, L. N.; Sazonov, A. M.; Kononkova, N. N.


    Study of mineral inclusions within alluvial gold particles of the Guli Complex (East Siberia) and findings of lode gold in rocks of the same intrusion have demonstrated that gold mineralization occurs in interstitions of both early high-magnesium rocks (dunite) and later alkalic and carbonatite rocks. In dunite the native gold occurs in association with Fe-Ni sulfides (monosulfide solid solution, pentlandite, and heazlewoodite). Formation of the gold-bearing alloys took place under a low oxygen potential over a broad range of temperatures: from those close to 600°C down to below 400°C.

  14. Remobilization in the cratonic lithosphere recorded in polycrystalline diamond

    Jacob; Viljoen; Grassineau; Jagoutz


    Polycrystalline diamonds (framesites) from the Venetia kimberlite in South Africa contain silicate minerals whose isotopic and trace element characteristics document remobilization of older carbon and silicate components to form the framesites shortly before kimberlite eruption. Chemical variations within the garnets correlate with carbon isotopes in the diamonds, indicating contemporaneous formation. Trace element, radiogenic, and stable isotope variations can be explained by the interaction of eclogites with a carbonatitic melt, derived by remobilization of material that had been stored for a considerable time in the lithosphere. These results indicate more recent formation of diamonds from older materials within the cratonic lithosphere.

  15. Geochemical evolution of lithospheric mantle underlying Intrasudetic Fault (SW Poland).

    Ćwiek, Mateusz; Matusiak-Małek, Magdalena; Puziewicz, Jacek; Ntaflos, Theodoros


    The Pilchowice basanite (SW Poland) forms volcanic plug located exactly on Intrasudetic Fault, which is one of the major tectonic lines in northern part of the Bohemian Massif. It originated during the formation of Variscan Orogen and marks the contact between two different crustal domains. The basanite is rhönite-bearing (Ladenberger et al., 2005. Min.Pol-Spec. Pap.) and contains small (JoP), which is in an opposition to modal content of clinopyroxene (0-4.1 vol.%). This suggests, that clinopyroxene is a "stealth" metasomatic phase (O'Reillly and Griffin, 2013, Springer). As trace element composition of clinopyroxene shows features typical for reaction with alkaline silicate melt (negative inflection at the most incompatible trace elements) and carbonatite (Ti, Zr, Hf anomalies), we suggest that majority of xenoliths were metasomatized by the an agent being a carbonatite-silicate melt or by CO2-bearing alkaline silicate melt. Xenolith where clinopyroxene shows constant enrichment in LREE may represent a part of mantle affected by pure carbonatitic metasomatism. Xenoliths with the lowest Fo content in olivine are probably cumulates of mafic silicate melt. Intergranular aggregates originated during reaction between primary phases and infiltrating, possibly mafic melt. The "glassy patch" might be a product of complete breakdown of amphibole in upper mantle conditions (Shaw, 2009, Lithos). However, presence of rhönite in host basanite suggests that some amphibole might have been broken also in lower pressures. Chemical composition of peridotites from Pilchowice resembles that recorded by group A mantle xenoliths from Krzeniów (Matusiak-Małek et al., 2014, JoP). In Pilchowice we have described the first xenolith affected by purely carbonatitic metasomatism. We also suggest that hydrous phases might have been present in upper mantle beneath this Pilchowice, which is believed to be nominally anhydrous (Puziewicz et al., 2015, IJES, DOI 10.1007/s00531

  16. The Effect of Composition and Pressure on the Structure of Carbonate-Silicate Melts Using in situ X-ray Diffuse Scattering

    Hummer, D. R.; Kavner, A.; Manning, C. E.


    Carbonatites are carbon-rich magmas that make up a crucial portion of the deep-Earth carbon cycle. During transport from the site of melting, reaction with surrounding mantle and crust can cause significant changes in their carbonate-silicate ratio. However, very little is known about the structure of carbonate-silicate liquids at the high pressures and temperatures where melts originate and metasomatism occurs. To examine how the melt structure of carbonate-silicate binary systems evolves as a function of pressure and composition, we performed in situ X-ray scattering experiments in the Paris-Edinburgh press at HPCAT (Advanced Photon Source). Mixtures from the CaCO3-CaSiO3 and CaCO3-Mg2SiO4 binary systems were used to simulate mantle carbonatites with differing Si:O ratio. Samples were loaded using the experimental setup of Yamada et al [1], and held at 1800 oC and a pressure of either 3 or 6 GPa while energy dispersive X-ray scattering spectra were recorded. Spectra were collected at nine different scattering angles to achieve coverage in reciprocal space up to q = 20 Å-1. Pair distribution functions for pure calcite confirm that carbonates form a simple ionic liquid, as found by previous investigators. [2,3] The silicate portion of carbonate-silicate melts, however, is extensively chain polymerized. This polymerization occurs even in melts containing Mg2SiO4, in which the solid is completely unpolymerized. However, analysis of Si-Si distances reveals that Mg2SiO4-bearing melts likely contain shorter, more distorted chains, while CaSiO3-bearing melts form extended chains with a Si-O-Si angles close to 180o. For silicate-rich mixtures in both systems, the extent of silica polymerization (as measured by the amount of scattering at the Si-Si pair distance of 3.3 Å) moderately increases with increasing carbonate content. Comparing pair distribution functions calculated from 3 and 6 GPa data reveal that pressure moderately increases the degree of polymerization of

  17. Global Carbon Cycle of the Precambrian Earth

    Wiewióra, Justyna

    The carbon isotopic composition of distinct Archaean geological records provides information about the global carbon cycle and emergence of life on early Earth. We utilized carbon isotopic records of Greenlandic carbonatites, diamonds, graphites, marbles, metacarbonates and ultramafic rocks...... to investigate carbon fluxes between Precambrian Earth’s mantle and crust and to trace the evolution of life in the Eoarchaean oceans. The world’s desire for diamonds gives us a unique opportunity to obtain insight into the nature of metasomatic fluids affecting the subcratonic lithospheric mantle (SCLM) beneath...

  18. Uraninite recrystallization and Pb loss in the Oklo and Bangombé natural fission reactors, Gabon

    Evins, Lena Z.; Jensen, Keld A.; Ewing, Rodney C.


    The Oklo and Bangombé natural fossil fission reactors formed ca. 2 Ga ago in the Franceville basin, Gabon. The response of uraninite in the natural reactors to different geological conditions has implications for the disposal of the UO 2 in spent nuclear fuel. Uraninite and galena from two reactor zones, RZ16 at Oklo and RZB at Bangombé, were studied to clarify the chronology and effect of alteration events on the reactor zones. In addition, ion microprobe U-Pb analysis of zircons from a dolerite dyke in the Oklo deposit were completed to better constrain the age of the dyke, and thereby testing the link between the dyke and an important alteration event in the reactor zones. The analyzed uraninite from RZ16 and RZB contains ca. 6 wt% PbO, indicating a substantial loss of radiogenic Pb. Transmission electron microscopy showed that microscopic uraninite grains in the reactor zones consist of mainly defect-free nanocrystalline to microcrystalline aggregates. However, the nanocrystalline regions have elevated Si contents and lower Pb contents than coarser uraninite crystallites. Single stage model ages of large, millimeter-sized galena grains at both RZ16 and RZB correlate well with the age of the Oklo dolerite dyke, 860 ± 39 Ma (2σ). Thus, the first major Pb loss from uraninite occurred at both Oklo and Bangombé during regional extension and the intrusion of a dyke swarm in the Franceville basin, ˜860-890 Ma ago. Uraninite Pb isotopes from RZ16 and RZB give lower ages of ca. 500 Ma. These ages agree with the "chemical" ages of the uraninite, and show that an ancient Pb loss occurred after the intrusion of the dolerite dykes. The presence of nanocrystallites in the reactor uraninite indicates internal recrystallization, which may have occurred around 500 Ma, resulting in the 6wt% PbO uraninite. It is suggested that leaching by fluid interaction triggered by the Pan-African orogeny was important during this second Pb-loss event. Thus, there are indications that

  19. SHRIMP dating of the Bangong Lake SSZ-type ophiolite:Constraints on the closure time of ocean in the Bangong Lake-Nujiang River, northwestern Tibet

    SHI RenDeng


    The Bangong Lake ophiolite is located in the westernmost part of the Bangong Lake-Nujiang River and massive lavas and mafic dykes with SSZ-type ophiolitic geochemical affinity formed at the end of a Wilson circle. The SHRIMP U-Pb ages of the co-magmatic zircon domains from one gabbroic dyke (Sample 01Y-155) range from 162.5±8.6 Ma to 177.1±1.4 Ma with an average of 167.0+1.4 Ma (n = 12,MSWD = 1.2), suggesting that the subduction of the Bangong Lake Neo-Tethyan Ocean started before the Middle Jurassic. It is inferred that the tectonic transform from spreading to subduction of the Neo-Tethyan Ocean began before the Middle Jurassic in the Bangong Lake area.

  20. Depth of origin of magma in eruptions.

    Becerril, Laura; Galindo, Ines; Gudmundsson, Agust; Morales, Jose Maria


    Many volcanic hazard factors--such as the likelihood and duration of an eruption, the eruption style, and the probability of its triggering large landslides or caldera collapses--relate to the depth of the magma source. Yet, the magma source depths are commonly poorly known, even in frequently erupting volcanoes such as Hekla in Iceland and Etna in Italy. Here we show how the length-thickness ratios of feeder dykes can be used to estimate the depth to the source magma chamber. Using this method, accurately measured volcanic fissures/feeder-dykes in El Hierro (Canary Islands) indicate a source depth of 11-15 km, which coincides with the main cloud of earthquake foci surrounding the magma chamber associated with the 2011-2012 eruption of El Hierro. The method can be used on widely available GPS and InSAR data to calculate the depths to the source magma chambers of active volcanoes worldwide.

  1. Heat or mass transfer from a sphere in Stokes flow at low Péclet number

    Bell, Christopher G.


    We consider the low Péclet number, Pe≪1, asymptotic solution for steady-state heat or mass transfer from a sphere immersed in Stokes flow with a Robin boundary condition on its surface, representing Newton cooling or a first-order chemical reaction. The application of Van Dyke\\'s rule up to terms of O(Pe3) shows that the O(Pe3logPe) terms in the expression for the average Nusselt/Sherwood number are twice those previously derived in the literature. Inclusion of the O(Pe3) terms is shown to increase the range of validity of the expansion. © 2012 Elsevier Ltd. All rights reserved.

  2. U-Pb SHRIMP data and geochemical characterization of granitoids intruded along the Coxixola shear zone, Provincia Borborema, NE Brazil

    Guimaraes, Ignez de Pinho; Silva Filho, Adejardo Francisco da; Silva, Francis M.J.V. da, E-mail: [Universidade Federal de Pernanmbuco (UFPE), Recife, PE (Brazil). Dept. de Geologia; Armstrong, Richard [Australian National University (Australia)


    A large volume of granitic magmatism associated with large scale shear zone and metamorphism under high-T amphibolite facies conditions characterize the Brasiliano Orogeny in the Borborema Province, NE Brazil. Granitoids from two plutons and later dykes intruded along the Coxixola shear zone show distinct crystallization ages and geochemical signature. The oldest granitoids (618 ± 5 Ma), Serra de Inacio Pereira Pluton are coeval with the peak of regional metamorphism and they were probably originated by melting of a paleoproterozoic source. The granitoids from the Serra do Marinho Pluton show crystallization age of 563 ± 4 Ma and geochemical signature of post-collisional A-type granites. The later dykes have crystallization age of 526 ± 7 Ma, geochemical signature of A-type granitoids. (author)

  3. Petrography and U-Pb Zircon Geochronology of Geological Units of the Mesa de Cocodite, Península de Paraguaná, Venezuela

    Mendi, D.; Baquero, M. L.; Oliveira, E. P.; Urbani, F.; Pinto, J.; Grande, S.; Valencia, V.


    Several continental crust units crop out in The Mesa de Cocodite, central Paraguaná Peninsula, Northwestern Venezuela, including a newly mapped quartz-feldspar gneiss that intruded the El Amparo Pluton, a major low-graded metamorphic unit of Permian age. It is unconformably overlying by Late Jurassic phyllites of the Pueblo Nuevo Formation. All these units are cross-cut by narrow dykes. This contribution focuses on the petrography and LA-ICP-MS U-Pb zircon dating of the igneous units, with the aim of constraining magmatism and its tectonic significance in the area. The quartz-feldspar gneiss consists of albite, bluish-smoked quartz, muscovite-chlorite, epidote and zircon. The enclosing El Amparo Pluton is typically a coarse-grained and thick-banded metagranodiorite, containing andesine, quartz, hornblende, epidote, K-feldspar, biotite, chlorite, titanite and zircon. The younger dykes consist of fine-grained, porphyritic hornblende diorites that contain numerous hornblende phenocrysts. The main minerals are andesine, hornblende, quartz, and chlorite. Accessory minerals include zircon, epidote and opaques. A felsic gneiss xenolith collected from the dykes contain quartz, K-feldspar, chlorite, epidote, albite and zircon. Zircon population in the quartz-feldspar gneiss displays a discordia trend, ranging in age from 1050-750 Ma but mostly around 950-900 Ma, which may represent a peak high-grade metamorphism in the area. The El Amparo Pluton provides a concordant Permian age (271.3±6.5 Ma), which is comparable with previous reported U-Pb ages in titanite. Because the porphyry dykes cross-cut all the units in the area, they should be post-Late Jurassic in Age; however, all dated zircons from the dykes are in the range of 1200-750 Ma. The absence of younger ages can be attributed to either formation during a relatively low temperature magmatic event, which generated very narrow younger zircon rims only and thus undetectable with the technique used, or a completely lack

  4. Concentrates and mantle xenocrysts from the Lao river Guinea and reconstructions of the mantle structure

    Afanasiev, Valentin; Ashchepkov, Igor; Nikolenko, Eeugeny


    The discovery of the kimberlite dykes in Quinea in the basin of the Lao river means finding of the new diamondiferous kimberlite field in the West Africa. It is locating 100 km SW from Bubudu and contains large dykes and placers in Lao river. The kimberlite concentrate and diamondiferous placers are containing pyropes, chromites, Ilmenites and Cr diosides and low Cr- pyroxenes. Two river placers in Lao and Bobeko and newly discovered dyke slightly differ in compositions of minerals. mainly in representatives of the minerals though their compositional trends are in general similar. The concentrates from and Druzhba pipe (Bunudu) contains mainly ilmenite and more are pyropes. Garnets from all localities are close and belong mainly to the lherzolite field to 10 wt%Cr2O3. But the dyke contains essential amount of harzburgitic garnets starting from 2 %wt Cr2O3 and they became prevailing from 6 wt %Cr2O3. There are also megacrystic low - Cr pyropes in dyke concentrate. Dyke is rich in peridotites and coarse grained garnet pyroxenite xenoliths which are ranging from the low Cr -to Cr -diopside type Chromites from Dyke are Ti - low but are often Al rich. While chromites from Bobeko and especially Lao placers define the Cr- rich trend from 60 to 40 wt%Cr2O3 and demonstrate the deviation to ulvospinel trends with increasing of Al2O3 . Cr - Diopsides clinopyroxenites trace the Fe- Ti-Na-Al enrichment trend. Ilmenites from three localities - define close trends splitting to the two intervals 60-40 wt% TiO2 and 33-27 TiO2 which are enriched in Cr2O3 to 5wt% reflecting the crystallization of megacrystalline association at the lithosphere base and Ilm metasomatic vein stockwark near the Moho in pre-eruption feeding system. The Dyke ilmenites are Mg rich and mainly are captured from the deep part of the mantle section. Babeko and Druzhba localities are similar variations of ilmenite trends. Some ilmenites from Lao and Druzhba are Mn - rich and are less in Cr possibly reflecting

  5. Reservoir stimulation techniques to minimize skin factor of Longwangmiao Fm gas reservoirs in the Sichuan Basin

    Guo Jianchun


    Full Text Available The Lower Cambrian Longwangmiao Fm carbonatite gas reservoirs in the Leshan-Longnüsi Paleouplift in the Sichuan Basin feature strong heterogeneity, well-developed fractures and caverns, and a high content of H2S, so these reservoirs are prone to reservoir damages caused by the invasion of drilling fluid or the improper well completion, so to minimize the reservoir skin factor is key to achieving high yield of oil and gas in this study area. Therefore, based on the geological characteristics of the Longwangmiao reservoirs, the binomial productivity equation was applied to demonstrate the possibility and scientificity of minimizing the skin factor. According to the current status of reservoir stimulation, the overall skin factors of reservoir damage caused by drilling fluid invasion, improper drilling and completion modes etc were analyzed, which shows there is still potential for skin factor reduction. Analysis of reservoir damage factors indicates that the main skin factor of Longwangmiao Fm reservoirs consists of that caused by drilling fluid and by improper completion modes. Along with the minimization of skin factor caused by drilling and improper completion, a fracture-network acidizing process to achieve “non-radial & network-fracture” plug-removal by making good use of natural fractures was proposed according to the characteristics of Longwangmiao Fm carbonatite reservoirs.

  6. A New Methodology for Open Pit Slope Design in Karst-Prone Ground Conditions Based on Integrated Stochastic-Limit Equilibrium Analysis

    Zhang, Ke; Cao, Ping; Ma, Guowei; Fan, Wenchen; Meng, Jingjing; Li, Kaihui


    Using the Chengmenshan Copper Mine as a case study, a new methodology for open pit slope design in karst-prone ground conditions is presented based on integrated stochastic-limit equilibrium analysis. The numerical modeling and optimization design procedure contain a collection of drill core data, karst cave stochastic model generation, SLIDE simulation and bisection method optimization. Borehole investigations are performed, and the statistical result shows that the length of the karst cave fits a negative exponential distribution model, but the length of carbonatite does not exactly follow any standard distribution. The inverse transform method and acceptance-rejection method are used to reproduce the length of the karst cave and carbonatite, respectively. A code for karst cave stochastic model generation, named KCSMG, is developed. The stability of the rock slope with the karst cave stochastic model is analyzed by combining the KCSMG code and the SLIDE program. This approach is then applied to study the effect of the karst cave on the stability of the open pit slope, and a procedure to optimize the open pit slope angle is presented.

  7. Phosphate occurrence and potential in the region of Afghanistan, including parts of China, Iran, Pakistan, Tajikistan, Turkmenistan, and Uzbekistan

    Orris, Greta J.; Dunlap, Pamela; Wallis, John; Wynn, Jeff


    As part of a larger study, the U.S. Geological Survey undertook a study to identify the potential for phosphate deposits in Afghanistan. As part of this study, a geographic information system was constructed containing a database of phosphate occurrences in Afghanistan and adjacent countries, and a database of potential host lithologies compiled from 1:1,000,000 scale maps. Within Afghanistan, a handful of known occurrences and reports indicate the presence of phosphate in Permian, Cretaceous, and Paleogene sediments and in carbonatite. With the exception of the Khanneshin carbonatite, very little is known about these occurrences. In the countries surrounding Afghanistan, economic phosphate is known to occur in Cambrian, Devonian, and Paleogene sediments and in Kiruna-type Fe-apatite deposits. Many of the host units may extend into Afghanistan or equivalent units may be present. Although the possibility of economic phosphate deposits exist for Afghanistan, the need for detailed exploration for phosphate, the remoteness of some locations, and the probability that a deposit would not be exposed at the surface mean that one or more deposits are not likely to be identified in the near future. Even if a phosphate-bearing deposit is identified in Afghanistan, it is not clear if the probable size, thickness, and grade ranges would allow economic development of the hypothesized resource.

  8. Development of Acidizing Techniques for Low-permeability Carbonate Reservoirs

    Liu Tongbin


    @@ Geological Background In accordance with gas reservoir occurrence, reserve type and trap type, the discovered and developed carbonate reservoirs in Sichuan Basin can be classified into the following three types: the first type is the layered porous gas reservoir (including porous and fractured porous gas reservoir), mainly distributed in East Sichuan area; the second is the block vug bottom water drive gas reservoir; the third is the irregular gas reservoir with fracture system, mainly distributed in the areas of South Sichuan and Southwest Sichuan. The reservoirs of these gas pools are mainly of carbonatite. The matrix porosity and permeability of carbonatite are very low, the porosity being below 1% - 3% and the permeability, 0.1×10-3-8× 10-3 μm2. Also the throat capillary resistance force is considerable with the mid-value width of the throat (γ50)of 0.1 - 4 μm, most below 2 μm. Owing to the low permeability and porosity as well as the serious heterogeneity of the reservoir, the productivi ty of gas wells changes greatly.

  9. Multi-threshold de-noising of electrical imaging logging data based on the wavelet packet transform

    Xie, Fang; Xiao, Chengwen; Liu, Ruilin; Zhang, Lili


    A key problem of effectiveness evaluation for fractured-vuggy carbonatite reservoir is how to accurately extract fracture and vug information from electrical imaging logging data. Drill bits quaked during drilling and resulted in rugged surfaces of borehole walls and thus conductivity fluctuations in electrical imaging logging data. The occurrence of the conductivity fluctuations (formation background noise) directly affects the fracture/vug information extraction and reservoir effectiveness evaluation. We present a multi-threshold de-noising method based on wavelet packet transform to eliminate the influence of rugged borehole walls. The noise is present as fluctuations in button-electrode conductivity curves and as pockmarked responses in electrical imaging logging static images. The noise has responses in various scales and frequency ranges and has low conductivity compared with fractures or vugs. Our de-noising method is to decompose the data into coefficients with wavelet packet transform on a quadratic spline basis, then shrink high-frequency wavelet packet coefficients in different resolutions with minimax threshold and hard-threshold function, and finally reconstruct the thresholded coefficients. We use electrical imaging logging data collected from fractured-vuggy Ordovician carbonatite reservoir in Tarim Basin to verify the validity of the multi-threshold de-noising method. Segmentation results and extracted parameters are shown as well to prove the effectiveness of the de-noising procedure.

  10. Thermochemistry and Reactivity of Metals Engaged in Chemiionization


    AFRL) Metal Oxide Space Cloud (MOSC) experiments have been conducted to test the efficiency of forming an artificial plasma cloud by this process...analysis methods have been extensively tested and further developed. 40-45 These studies demonstrate that a phase space theory (PST) approach in which...atmospheric tests. This result is also consistent with the original observations of both Fite and coworkers 65 and Dyke and coworkers 66 that the

  11. Courtright intrusive zone: Sierra National Forest, Fresno County, California.

    Bateman, P.C.; Kistler, R.W.; DeGraff, J.V.


    This is a field guide to a well-exposed area of plutonic and metamorphic rocks in the Sierra National Forest, Fresno County, California. The plutonic rocks, of which three major bodies are recognized, besides aplite and pegmatite dykes, range 103 to approx 90 m.y. in age. Points emphasized include cataclastic features within the plutonic rocks, schlieren and mafic inclusions. (M.A. 83M/0035).-A.P.

  12. Significado de fábricas magnéticas en rocas volcánicas cuaternarias de la Isla Decepción (Shetland del Sur, Antártida)

    Gil Imaz, Andrés; Gil Peña, Inmaculada; Galindo Zaldívar, Jesús; Rey Salgado, Jorge; Maestro González, Adolfo; Pueyo Anchuela, Óscar; Soto Marín, Ruth; Oliva Urcia, Belén; López Martínez, Jerónimo


    This work deals with the magnetic fabric (AMS technique) of different lithotypes related to quaternary volcanism of Deception Island (South Shetland Islands). The studied rocks include lava flows from basaltic to basaltic-andesitic composition, mafic dykes and several types of pyroclastic deposits. By combining the analysis of parametric aspects of the magnetic ellipsoids and their directional pattern, four types of magnetic fabrics have been recognized. Type I fabrics are related...

  13. The spontaneous imaginative life.

    Hetherington, J; Kivi, K L; Fisher, C; Merryfeather, L


    SUMMARY From an interweaving of the journal entries of four dykes involved in a polyamorous network, a picture of the day-to-day complexities of polyamory emerges. Relationship to family and community, jealousy, shame and acceptance of self are some of the issues dealt with in this narrative. The story unfolds in a rural community in British Columbia, Canada, where they all live. This piece is an excerpt from a longer, ongoing work.

  14. Diapiric ascent of silicic magma beneath the Bolivian Altiplano

    Del Potro, R.; M. Díez; Blundy, J.; Camacho, Antonio G.; Gottsmann, Joachim


    The vertical transport of large volumes of silicic magma, which drives volcanic eruptions and the long-term compositional evolution of the continental crust, is a highly debated problem. In recent years, dyking has been favored as the main ascent mechanism, but the structural connection between a distributed configuration of melt-filled pores in the source region and shallow magma reservoirs remains unsolved. In the Central Andes, inversion of a new high-resolution Bouguer anomaly data over t...

  15. Petrography and geochemical study of Nezam-Abad area, Southwest of Shazand, Arak

    Robabeh Jafari; Moosa Noghreeian; Mohammad Makizadeh


    Nezam-Abad area is located in southwest of Shazand (Arak) which is a part of Sanandaj-Sirjan zone. Major intrusive rocks of Nezam-Abad are quartz diorite and minor amount of granodiorite. Leucogranitic, pegmatite dykes and quartz-tourmaline veins were intruded the quartz diorite. Quartz diorites are mainly composed of plagioclase, hornblende, biotite, quartz and pyroxene as major minerals. Major minerals of leucogranite are microcline, orthoclase, albite, quartz, biotite and muscovite. Access...


    V. V. Chashchin; F. P. Mitrofanov


    The article provides data on the structure of the Paleoproterozoic intercontinental Imandra-Varzuga rifting structure (IVS) and compositions of intrusive formations typical of the early stage of the IVS development and associated mineral resources. IVS is located in the central part of the Kola region. Its length is about 350 km, and its width varies from 10 km at the flanks to 50 km in the central part. IVS contains an association of the sedimentary-volcanic, intrusive and dyke complexes. It...


    B.K Chand


    Full Text Available The impact of saline water inundation on freshwater aquaculture was evaluated through risk assessment tools. Fishponds in low-lying areas of Sagar and Basanti block are prone to saline water flooding. Respondents of Sagar block considered events like cyclone and coastal flooding as extreme risk; erratic monsoon, storm surge and land erosion as high risk; temperature rise, sea level rise, hot & extended summer and precipitation as medium risk. Likewise, in Basanti block the respondents rated cyclone as extreme risk; erratic monsoon, storm surge as high risk; temperature rise, hot & extended summer, land erosion, and precipitation as medium risk; coastal flooding and sea level rise as low risk. Fish farmers of Sagar block classified the consequences of saline water flooding like breach of pond embankment and mass mortality of fishes as extreme risk; escape of existing fish stock and diseases as high risk; entry of unwanted species, retardation of growth and deterioration of water quality as medium risk; and damage of pond environment as low risk. Farmers of Basanti block categorised breach of pond dyke, mass mortality of fishes and entry of unwanted species as extreme risk; escape of fish and diseases as high risk; retardation of growth as medium risk; deterioration of water quality and damage of pond environment as low risk. To reduce the threats against saline water ingression, farmers are taking some coping measures like increase in pond dyke height; repair and strengthening of dyke; plantation on dyke; dewatering and addition of fresh water; application of chemicals/ lime/ dung; addition of tree branches in pond for hide outs etc.

  18. The Aznalcollar (Spain) tailings pond failure of 1998 and the ecological disaster of Guadiamar river: causes, effects and lessons; La rotura de la balsa de residuos mineros de Aznalcollar (Espana) de 1998 y el desastre ecologico consecuente del rio Guadiamar: causas, efectos y lecciones

    Ayala-Carcedo, F. J.


    On 1998 a large tailings pond confined by a rock fill dyke in the Aznalcollar metallic mine near Sevilla, at the SW of Spain, failed with a big impact on public opinion due to potential environmental Impact on Donana National Park,a key natural space for birds migration between Europea and Africa. The accident is placed in a comparative way with others in the world, the causes of failure, its dynamics and the spill are analysed and also the actual ecological impacts related to the tailings and acid waters scattered by the Agrio and Guadiamar rivers. The lessons for future design and location of these type of deposits and water dams are also presented. The accident very quick, was caused by shear failure of the foundation formation, a miocene over consolidated marly clay, known as Guadalquivir blue marl, through a vertical point and a bedding plane, as a result of a progressive failure process under high pore pressure. Dynamic liquefaction of tailings due to sudden vertical movement towards the void created by the initial movement was a key factor to increase the outwards movement of the dyke, broken by the movement, and the tailings spill. The double dyke failure (main dyke and internal one) produced a tailings spill with solid and liquid flow. The dynamics of these flows is presented and also the combination of factors driving to failure. the problem posed by the successive human institutional failures, a necessary cause driving to no consideration of the possibility of the progressive failure in these formations, known from 1964, is also analysed. (Author) 67 refs.

  19. Video monitoring reveals pulsating vents and propagation path of fissure eruption during the March 2011 Pu'u 'Ō'ō eruption, Kilauea volcano

    Witt, Tanja; Walter, Thomas R.


    Lava fountains are a common eruptive feature of basaltic volcanoes. Many lava fountains result from fissure eruptions and are associated with the alignment of active vents and rising gas bubbles in the conduit. Visual reports suggest that lava fountain pulses may occur in chorus at adjacent vents. The mechanisms behind such a chorus of lava fountains and the underlying processes are, however, not fully understood. The March 2011 eruption at Pu'u 'Ō'ō (Kilauea volcano) was an exceptional fissure eruption that was well monitored and could be closely approached by field geologists. The fissure eruption occurred along groups of individual vents aligned above the feeding dyke. We investigate video data acquired during the early stages of the eruption to measure the height, width and velocity of the ejecta leaving eight vents. Using a Sobel edge-detection algorithm, the activity level of the lava fountains at the vents was determined, revealing a similarity in the eruption height and frequency. Based on this lava fountain time series, we estimate the direction and degree of correlation between the different vents. We find that the height and velocity of the eruptions display a small but systematic shift in time along the vents, indicating a lateral migration of lava fountaining at a rate of 11 m/s from W to E. This finding is in agreement with a propagation model of a pressure wave originating at the Kilauea volcano and propagating through the dyke at 10 m/s from W to E. Based on this approach from videos only 30 s long, we are able to obtain indirect constraints on the physical dyke parameters, with important implications for lateral magma flow processes at depth. This work shows that the recording and analysis of video data provide important constraints on the mechanisms of lava fountain pulses. Even though the video sequence is short, it allows for the confirmation of the magma propagation direction and a first-order estimation of the dyke dimensions.

  20. Ballistic Imaging of Liquid Breakup Processes in Dense Sprays


    link in CFD models is the description of the breakup process for the liquid fuel spray, especially primary breakup; the process by which a liquid...the near field of a hollow cone spray breaking up into sheets, ligaments and droplets. He doesn’t quote numbers, but it is likely that We is less...approaching 10) in the near field. The hollow cone image presented by Van Dyke was taken with a classical white light shadowgram arrangement. If the

  1. Groundwater resource evaluation of urban Bulawayo aquifer

    Rusinga, F


    Full Text Available mafic and ultramafic sills and dykes. Because of its prevalent mafic character which tends to promote deep weathering, the rock formation supports an aquifer with fairly good water storage capacity and permeability. Hydrogeophysical investigations... the secondary porosity of the formation to chemical weathering in contrast to the proposition of Weaver et al. (1992) that the secondary porosity in the well-field was due to fracturing. The proposition of Weaver et al. (1992) lends itself to widely...

  2. Petrogenesis and geodynamics of plagiogranites from Central Turkey (Ekecikdağ/Aksaray): new geochemical and isotopic data for generation in an arc basin system within the northern branch of Neotethys

    Köksal, Serhat; Toksoy-Köksal, Fatma; Göncüoglu, M. Cemal


    In the Late Cretaceous, throughout the closure of the Neotethys Ocean, ophiolitic rocks from the İzmir-Ankara-Erzincan ocean branch were overthrusted the northern margin of the Tauride-Anatolide Platform. The ophiolitic rocks in the Ekecikdaǧ (Aksaray/Central Turkey) region typify the oceanic crust of the İzmir-Ankara-Erzincan branch of Neotethys. The gabbros in the area are cut by copious plagiogranite dykes, and both rock units are intruded by mafic dykes. The plagiogranites are leucocratic, fine- to medium-grained calc-alkaline rocks characterized mainly by plagioclase and quartz, with minor amounts of biotite, hornblende and clinopyroxene, and accessory phases of zircon, titanite, apatite and opaque minerals. They are tonalite and trondhjemite in composition with high SiO2 (69.9-75.9 wt%) and exceptionally low K2O (<0.5 wt%) contents. The plagiogranites in common with gabbros and mafic dykes show high large-ion lithophile elements/high-field strength element ratios with depletion in Nb, Ti and light rare-earth elements with respect to N-MORB. The plagiogranites together with gabbros and mafic dykes show low initial 87Sr/86Sr ratios (0.70419-0.70647), high ƐNd(T) (6.0-7.5) values with 206Pb/204Pb (18.199-18.581), 207Pb/204Pb (15.571-15.639) and 208Pb/204Pb (38.292-38.605) ratios indicating a depleted mantle source modified with a subduction component. They show similar isotopic characteristics to the other supra-subduction zone (SSZ) ophiolites in the Eastern Mediterranean to East Anatolian-Lesser Caucasus and Iran regions. It is suggested that the Ekecikdaǧ plagiogranite was generated in a short time interval from a depleted mantle source in a SSZ/fore-arc basin setting, and its nature was further modified by a subduction component during intra-oceanic subduction.

  3. Integrated water resource and flood risk management: comparing the US and the EU

    Serra-Llobet Anna; Conrad Esther; Schaefer Kathleen


    Floods are the most important natural hazard in the EU and US, causing 700 deaths and at least €25 billion in insured economic losses in Europe since 1998, and causing nearly $10 billion annual average flood losses in the US. Flood control is commonly viewed as a matter of building dykes, dams, and other structures, but effective flood management within the perspective of Integrated Water Resource Management (IWRM) must address multiple components of the flood risk management cycle (Figure 1)...

  4. Características geológicas de los pórfiros dacíticos y su roca hospedante, quebrada del Peñasquito, Precordillera occidental de San Juan

    Gaido, María Fernanda


    Full Text Available Geological characteristics of the dacitic porphyries and their host rock, Quebrada del Peñasquito, western Precordillera of San Juan. At Peñasquito creek, in the sierra del Tontal (S 31º 40’ 44,5” - W69º 14’ 05”, western San Juan province, at an altitude of 2,953 m.s.n.m, a succession of dacitic dykes of unknown age are recognized, intruding subconcordantly sandstones of the Don Polo Formation of Ordovician age. The sandstones intruded by the dykes present short wavelength symmetrical folding (400 m. The dikes have attitudesof N0º/85ºO-N30º/75ºO, with thicknesses ranging between 3 and 25 m. Microscopically, they present a porfiric texture, composed of quartz, plagioclase, biotite and hematite. A deep alteration (oxidation confers a yellowish color to the dykes, easily visible by means of satellite imagery. There are numerous folded veins of quartz thataccompany the dikes, associated to anticline folds, fractures and shear zones, with sigmoid structures and cinematic indicators with dextral displacement indicators.The dikes may correspond to a Permian-Triasic or Miocene magmatism. The closest dacitic magmatism of Permian age has been recognized to the south of the area, in Pampa de los Pozos and Yalguaraz, with copper mineralization. However, Peñasquito´s dykes have a greater similarity with dacitic dikes described at Carrizal creek, 7 km to the north of the study area. For this reason are assigned to the Miocene magmatism recognized in the region.Exploratory studies are suggested to determine the presence of mineralization.

  5. A model to forecast magma chamber rupture

    Browning, John; Drymoni, Kyriaki; Gudmundsson, Agust


    An understanding of the amount of magma available to supply any given eruption is useful for determining the potential eruption magnitude and duration. Geodetic measurements and inversion techniques are often used to constrain volume changes within magma chambers, as well as constrain location and depth, but such models are incapable of calculating total magma storage. For example, during the 2012 unrest period at Santorini volcano, approximately 0.021 km3 of new magma entered a shallow chamber residing at around 4 km below the surface. This type of event is not unusual, and is in fact a necessary condition for the formation of a long-lived shallow chamber. The period of unrest ended without culminating in eruption, i.e the amount of magma which entered the chamber was insufficient to break the chamber and force magma further towards the surface. Using continuum-mechanics and fracture-mechanics principles, we present a model to calculate the amount of magma contained at shallow depth beneath active volcanoes. Here we discuss our model in the context of Santorini volcano, Greece. We demonstrate through structural analysis of dykes exposed within the Santorini caldera, previously published data on the volume of recent eruptions, and geodetic measurements of the 2011-2012 unrest period, that the measured 0.02% increase in volume of Santorini's shallow magma chamber was associated with magmatic excess pressure increase of around 1.1 MPa. This excess pressure was high enough to bring the chamber roof close to rupture and dyke injection. For volcanoes with known typical extrusion and intrusion (dyke) volumes, the new methodology presented here makes it possible to forecast the conditions for magma-chamber failure and dyke injection at any geodetically well-monitored volcano.

  6. Forecasting magma-chamber rupture at Santorini volcano, Greece

    John Browning; Kyriaki Drymoni; Agust Gudmundsson


    How much magma needs to be added to a shallow magma chamber to cause rupture, dyke injection, and a potential eruption? Models that yield reliable answers to this question are needed in order to facilitate eruption forecasting. Development of a long-lived shallow magma chamber requires periodic influx of magmas from a parental body at depth. This redistribution process does not necessarily cause an eruption but produces a net volume change that can be measured geodetically by inversion techni...

  7. The Manamedu Complex: Geochemical constraints on Neoproterozoic suprasubduction zone ophiolite formation within the Gondwana suture in southern India

    Yellappa, T.; Chetty, T. R. K.; Tsunogae, T.; Santosh, M.


    Ophiolites provide important clues on the role of subduction and have been widely investigated to reconstruct the history of development and closure of ocean basins in the geological past. The Manamedu Complex within the Palghat-Cauvery Suture Zone in southern India comprises metamorphosed equivalents of the following lithological units: (1) an ultramafic group comprising dominantly of pyroxenite and highly altered dunite, locally preserving cumulate textures; (2) a gabbroic suite consisting of gabbro, gabbro norite, and anorthosite; (3) sheeted mafic dykes of amphibolite to meta-andesite categories, (4) plagiogranite veins and pools; and (5) a thin layer of ferruginous cherts. Cr vs. Y, V vs. Cr, Ti vs. Zr, TiO 2-MnO-P 2O 5 and Fe 2O 3-Na 2O + K 2O-MgO plots of the gabbros and mafic dyke assemblages show that these are related to island arc tholeiite (IAT) group with tholeiitic to calcalkaline signatures. Chondrite normalized REE patterns of mafic dykes do not show any pronounced fractionation and display slight positive Eu anomalies. The normalized MORB plots of the mafic dykes show depletion of HFSE (negative Nb, Ti, Ta, Hf anomalies) and enrichment of LFSE (positive K, Ba, Rb, Th). The petrological and geochemical characteristics of the major lithological units in Manamedu Complex suggest that these rocks represent the remnants of an oceanic crust, developed from mantle-derived arc magmas probably within a suprasubduction zone tectonic setting. From the geological set up and our field observations, we infer that these rocks were obducted on to the continental margin with the closure of an ocean basin during the Neoproterozoic. The Manamedu Complex may represent the remnants of the Mozambique Ocean crust developed during Rodinia breakup and which was destroyed during the amalgamation of the Gondwana supercontinent in the Latest Neoproterozoic-Cambrian.

  8. Validation Test Report for WAVEWATCH III


    Organization ( WMO ) Global Telecommunication System (GTS) transmissions to validate the global WW3 and WAM models in wave spectra and wave height. However... WMO buoys NDBC buoys NDBC buoys Buoys, one oceanographic tower in Italy, France, Spain, mostly coastal Shallow-water and deep-water Waverider...research. WMO Bulletin 46(4): 317–324. Allard, R.A., J. Kaihatu, L.H. Hsu, and J.D. Dykes, (2002). The integrated ocean prediction system

  9. Graben-structure complexities at Mt. Laki, Iceland, investiged by camera drones and modeling

    Steinke, Bastian; Walter, Thomas R.; Mueller, Daniel; Witt, Tanja; Schoepa, Anne


    Fissure eruptions are often associated with formations of structural lineaments and a tectonic graben. Asymmetrical surface structures, formed by the fissure eruption of Laki volcano (Iceland) in 1783/84, are investigated for genesis and development in relation to loading and geometrical effects. The Laki craters, which form a NE-SW oriented row of about 140 vents over a distance of 25 km, are accompanied by asymmetrical ruptures close to the fissure. The graben forming ruptures show local complexities that are especially large at Mt. Laki. The dependence of the ruptures' form and orientation on dyke-geometry, loading effects and topography shall be studied here by using camera drones as central working method and stress modeling. Therefore, over 5000 photos, taken in several overflights with two camera drones over the top of Mt. Laki and on the northeastern/southwestern sides, were collected and converted into 3D-models using Structure from Motion (SfM). Afterwards, offset and orientation of the graben structures have been measured by profiles along and across the ruptures. The calculated trends of offset and distance to the vents provide a geometric constrain on the orientation and geometry of the underlying dyke. We compared this geometry of surface fractures to simulated fractures. In order to do so, the finite element method (FEM) was used to model stress and strain parameters close to a simulated dyke. Depth and dip of the dyke were systematically changed. The results of FEM are then compared to the photo results and provide an overall picture of the formation of the surface structures' local complexities at Mt. Laki and at other sites of the fissure eruption.

  10. Paleomagnetism of the Neoproterozoic Blekinge-Dalarna Dolerites in Western Sweden and Implications of the Sveconorwegian Loop(s)

    Gong, Z.; Evans, D. A.; Elming, S. A.


    Laurentia and Baltica are regarded to be juxtaposed at the core of the supercontinent Rodinia during Early Neoproterozoic. This contention is supported by the similar apparent polar wander paths (APWPs) of Laurentia and Baltica, known as the Grenville and the Sveconorwegian loops, respectively. Despite the debates of the age and shape of the Grenville loop, the Sveconorwegian loop has uncertainties as well. Paleomagnetic studies from Baltica show two distinct remanence directions at ca. 950 Ma: one is steep and upwards (A-type) and another is shallow and bipolar (B-type). The fidelity of B-type remanence is supported by the new key-pole from the 935 ± 5 Ma Blekinge-Dalarna dolerites (BDD) in western Sweden. But A-type remanence, less common, is also observed in the BDD dykes. Some studies attribute A-type remanence to remagnetization without clear evidence. If A-type remanence is primary, this would suggest a large APWP excursion of Baltica within a very short duration, analogous to the mid-Ediacaran situation of Laurentia that has been explained by different hypotheses such as true polar wander, unusual geomagnetic configuration or rapid plate motions. Therefore, we conducted a more detailed paleomagnetic study of the BDD dykes that cover an area of 10,000 km2. We propose a combined geochemical and magnetic fabric study to compare BDD dykes' signatures with published results to aid field identification. Thermal demagnetization is conducted and the fidelity of the remanence is examined by rigorous baked contact tests in different host rocks. Dykes with primary remanence will be radiometrically dated to constrain the age of the remanence. This study should have wide implications, in particular the configuration of Sveconorwegian loop(s) in Early Neoproterozoic time, the paleogeographic connection between Laurentia and Baltica in Rodinia, as well as the geodynamics in Earth's deep interior.

  11. Apport de la géophysique, de l'hydrogéochimie et de la modélisation du transfert en DMA : projet de réhabilitation de la mine abandonnée de Kettara (région de Marrakech, Maroc)


    The Kettara site (Morocco) is an abandoned pyrrhotite ore mine in a semi-arid environment. The site contains more than 3 million tons of mine waste that were deposited on the surface without concern for environmental consequences. Tailings were stockpiled in a pond, in a dyke, and in piles over an area of approximately 16 ha and have generated acid mine drainage (AMD) for more than 29 years. Investigation results show that the hydrochemistry of water samples is characterized by the relatively...

  12. Generation of Mesoscale Eddies in the Lee of the Hawaiian Islands


    at moderate Reynolds numbers, estimated in the range of 40-1000 [ Batchelor , 1967; van Dyke, 1982]. [9] For a stratified fluid in a rotating frame...An Introduction to Fluid Dynamics , 515 pp., Cambridge Univ. Press, Cambridge, U. K. Bidigarc, R. R., C. Bcnitcz-Nclson, C. L. Leonard, P. D. Quay, M...Florida, USA. 4Occan Dynamics and Prediction Branch, Naval Research Laboratory, Stcnnis Space Center, Mississippi, USA. Copyright 2011 by the

  13. A 100 km-long paleomagnetic traverse radial to the Sudbury Structure, Canada and its bearing on Proterozoic deformation and metamorphism of the surrounding basement

    Halls, Henry C.


    The 1850 Ma Sudbury Igneous Complex (SIC), considered to be a composite melt sheet of a major meteorite impact, has been deformed into an oval-shaped basin known as the Sudbury Structure. This paper explores to what extent this deformation has been communicated to the surrounding Archean basement around the northern margin of the SIC. Paleomagnetism of 2450 Ma Matachewan dykes and 1850 Ma impact breccia along a traverse, about 100 km-long and normal to strike of the contact between the SIC and the basement, suggests that the basement beneath the NW corner of the Sudbury Structure has been tilted to the SE within about 10 km of the contact. At this distance a possible fault separates the tilted region from one that shows no evidence of tilting. Petrographically the dykes out to a distance of about 50 km distant from the SIC are altered to upper greenschist facies of metamorphism with a fibrous amphibole replacing pyroxene and with loss of primary texture that characterizes less altered Matachewan dykes at distances greater than 50 km. The direction of magnetization found in the altered Matachewan dykes is an overprint which is probably associated with regional metamorphism related to orogenesis, or possibly with thermo-chemical alteration associated with SIC emplacement. The direction of the component is compatible with an age of about 1.8 to 1.9 Ga suggesting that the Penokean orogen is the most likely cause, if not the impact event. The paleomagnetism of the breccias, together with shatter cone orientation data, suggests that within 10 km of the SIC/basement contact, basement tilting to the southeast increases towards the SIC.

  14. Peridotites and mafic igneous rocks at the foot of the Galicia Margin: an oceanic or continental lithosphere? A discussion

    Korprobst, J.; Chazot, G.


    An ultramafic/mafic complex is exposed on the sea floor at the foot of the Galicia Margin (Spain and Portugal). It comprises various types of peridotites and pyroxenites, as well as amphibole-diorites, gabbros, dolerites and basalts. For chronological and structural reasons (gabbros were emplaced within peridotites before the continental break-up) this unit cannot be assigned to the Atlantic oceanic crust. The compilation of all available petrological and geochemical data suggests that peridotites are derived from the sub-continental lithospheric mantle, deeply transformed during Cretaceous rifting. Thus, websterite dykes extracted from the depleted MORB mantle reservoir (DMM), were emplaced early within the lithospheric harzburgites; subsequent boudinage and tectonic dispersion of these dykes in the peridotites, during deformation stages at the beginning of rifting, resulted in the formation of fertile but isotopically depleted lherzolites. Sterile but isotopically enriched websterites, would represent melting residues in the peridotites, after significant partial melting and melt extraction related to the thermal erosion of the lithosphere. The latter melts are probably the source of brown amphibole metasomatic crystallization in some peridotites, as well as of the emplacement of amphibole-diorite dykes. Melts directly extracted from the asthenosphere were emplaced as gabbro within the sub-continental mantle. Mixing these DMM melts together with the enriched melts extracted from the lithosphere, provided the intermediate isotopic melt-compositions - in between the DMM and Oceanic Islands Basalts reservoir - observed for the dolerites and basalts, none of which are characterized by a genuine N-MORB signature. An enriched lithospheric mantle, present prior to rifting of the Galicia margin, is in good agreement with data from the Messejana dyke (Portugal) and more generally, with those of all continental tholeiites of the Central Atlantic Magmatic Province (CAMP

  15. Quantitative volcanic susceptibility analysis of Lanzarote and Chinijo Islands based on kernel density estimation via a linear diffusion process

    Galindo, I.; Romero, M. C.; Sánchez, N.; Morales, J. M.


    Risk management stakeholders in high-populated volcanic islands should be provided with the latest high-quality volcanic information. We present here the first volcanic susceptibility map of Lanzarote and Chinijo Islands and their submarine flanks based on updated chronostratigraphical and volcano structural data, as well as on the geomorphological analysis of the bathymetric data of the submarine flanks. The role of the structural elements in the volcanic susceptibility analysis has been reviewed: vents have been considered since they indicate where previous eruptions took place; eruptive fissures provide information about the stress field as they are the superficial expression of the dyke conduit; eroded dykes have been discarded since they are single non-feeder dykes intruded in deep parts of Miocene-Pliocene volcanic edifices; main faults have been taken into account only in those cases where they could modified the superficial movement of magma. The application of kernel density estimation via a linear diffusion process for the volcanic susceptibility assessment has been applied successfully to Lanzarote and could be applied to other fissure volcanic fields worldwide since the results provide information about the probable area where an eruption could take place but also about the main direction of the probable volcanic fissures. PMID:27265878

  16. Magmatism in the brazilian sedimentary basins and the petroleum geology; Magmatismo nas bacias sedimentares brasileiras e sua influencia na geologia do petroleo

    Thomaz Filho, Antonio; Antonioli, Luzia [Universidade do Estado do Rio de Janeiro (UERJ), RJ (Brazil). Faculdade de Geologia]. E-mails:;; Mizusaki, Ana Maria Pimentel [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Inst. de Geociencias]. E-mail:


    In the recent years, the researches on the magmatic events that occurred in the Brazilian sedimentary basins had shown the importance of these episodes for the hydrocarbons exploration. The generation (heating), migration (structural and petrographic alterations), accumulation (basalt fractures) and migrations barriers (sills and dykes) of the hydrocarbons, produced for these rocks, are cited in the marginal and intra continental Brazilian basins. The magmatism produce the temperature increase in the sedimentary basin, around its intrusion, and this propitiate the maturation of the organic matter contained in the hydrocarbons generating rocks of the basin. At the same time, has been verified that the contacts dykes/sedimentary rocks can represent important ways for the hydrocarbons migrations. Recent studies have shown that the magmatism, in its extrusive manifestations, can be analyzed in view of the possibility of having acted as effective hydrocarbon seals and, in consequence, making possible the accumulation of hydrocarbons generated in the underlying sediments. The magmatism of predominantly basic to intermediary character is generated in the asthenosphere, that is, below the lithosphere. The dykes that had introduced in the basement of our sedimentary basins are good heat conductors and we can expect the geothermal gradients increase in the overlapped sedimentary deposits. The more detailed study of the magmatic processes in the Brazilian sedimentary basins must lead to new forms of hydrocarbons exploration in our sedimentary basins, also in those basins where the traditional exploration activities have not occasioned the waited expected successes. (author)

  17. Petrografía y geoquímica preliminar de los basaltos cretácicos de la sierra de Las Quijadas y cerrillada de Las Cabras, provincia de San Luis, Argentina

    Martínez Amancay N.


    Full Text Available Preliminary petrography and geochemistry of the Cretacic basalts of the Sierra de Las Quijadasand Cerrillada de Las Cabras, San Luis province, Argentina. We present preliminary results of the petrologyand geochemistry of Cretaceous basalts exposed in the anticlines of the sierra of Las Quijadas and cerrillada ofLas Cabras. In the mountainous western of San Luis crop out at least two depositional sequences which togetherexceed the 1500 m thick and consists mainly of clastic sedimentary sequences typical continental red beds belongingto the Giant Group and Lagarcito Formation. Within this group, recognizes two types of basalt events, representedby lava flows and dykes. The lava flows were described in the northeastern sector of the anticline, in a landscapeof gentle hills. The dykes were found on the western flank of the anticline, northern sector of that mountain.Basalt lava flows have porphyritic texture with phenocrystals show idiomorphic olivine with clinopyroxene,amphibole and plagioclase, while the basaltic dykes show olivine in porphyritic texture embedded in a plagioclasepaste without orientation, amphibole and apatite needles. The basalts of the cerrillada de Las Cabras presented asa volcanic breccia associated with basaltic bombs. They have phenocrystals of olivine and clinopyroxene in pastewith plagioclase oriented. The basalts are classified as alkali basalts and related to intraplate basalts. When analyzingrare earth elements chondrite normalized according to Nakamura’s design are observed with a steep negative slopefor the heavy rare earth elements, a design that is similar to that found in alkaline basalts from the Sierra Chica deCórdoba.

  18. Magnetic anomalies across Bastar craton and Pranhita–Godavari basin in south of central India

    I V Radhakrishna Murthy; S Bangaru Babu


    Aeromagnetic anomalies over Bastar craton and Pranhita –Godavari (P –G)basin in the south of central India could be attributed to NW –SE striking mafic intrusives in both the areas at variable depths.Such intrusions can be explained considering the collision of the Bastar and Dharwar cratons by the end of the Archaean and the development of tensile regimes that followed in the Paleoproterozoic,facilitating intrusions of mafic dykes into the continental crust.The P –G basin area,being a zone of crustal weakness along the contact of the Bastar and Dharwar cratons, also experienced extensional tectonics.The inferred remanent magnetization of these dykes dips upwards and it is such that the dykes are oriented towards the east of the magnetic north at the time of their formation compared to their present NW –SE strike.Assuming that there was no imprint of magnetization of a later date,it is concluded that the Indian plate was located in the southern hemisphere,either independently or as part of a supercontinent,for some span of time during Paleoproterozoic and was involved in complex path of movement and rotation subsequently. The paper presents a case study of the utility of aeromagnetic anomalies in qualitatively deducing the palaeopositions of the landmasses from the interpreted remanent magnetism of buried intrusive bodies.

  19. The architecture and shallow conduits of Laki-type pyroclastic cones: insights into a basaltic fissure eruption

    Reynolds, P.; Brown, R. J.; Thordarson, T.; Llewellin, E. W.


    Pyroclastic cones built along basaltic fissures provide important volcanological information, but it is often difficult to examine the early-erupted products due to burial by later products. Furthermore, it is rare to see the link between the feeder dyke and overlying cone fully exposed. In this study, we detail the architecture of a hybrid spatter cone, scoria half-cone and feeder dyke that has been dissected to below the pre-eruption surface by glacial floods. The cones were constructed during the 6-8 ka Rauðuborgir-Kvensöðul fissure eruption in North Iceland during Hawaiian- and Strombolian-style activities. Widening of their feeder dyke in the shallow sub-surface to produce an upward flaring morphology was accommodated by country rock removal and elastic host rock deformation. Ballistic calculations and stratigraphic relationships indicate that the scoria half-cone was constructed early in the eruption from the deposits of a lava fountain ~100 m high. A decline in fountain height and the generation of abundant welded deposits resulted in the formation of a nested spatter cone within the scoria half-cone. The cones are similar in structure and size to the hybrid scoria and spatter cones produced during the 15-km3 1783 Laki eruption and serve as a valuable window into the construction of pyroclastic edifices during basaltic fissure eruptions.

  20. Oklo. A review and critical evaluation of literature

    Zetterstroem, Lena [Swedish Museum of Natural History, Stockholm (Sweden). Lab. for Isotope Geology


    The Oklo natural fossil fission reactors in Gabon, Equatorial Africa, have been studied as a natural analogue for spent nuclear fuel in a geological environment. For these studies, it is important to know what has happened to these reactors since they formed. This review is focussed on existing geological and geochronological information concerning the Oklo reactors and the surrounding ore. A sequence of geological and geochemical events in the Oklo area, as described in the literature, is given. The data and the studies behind this established geochronology are discussed and evaluated. Of the regional geology, special attention is given to the dating of the Francevillian sediments, and the intrusion of a dolerite dyke swarm. The processes that led to the mineralisation at Oklo, the subsequent formation of the nuclear reactors and later migration of fission products are described. Further discussion concerns the studies of the dolerite dyke swarm, since this appears to be one of the most important events related to fission product migration. A close look at the data related to this event shows that further study of the age of the dolerite dykes, and their effect on the uraninite in the Oklo reactors, is needed.

  1. Nyamulagira’s magma plumbing system inferred from 15 years of InSAR

    Wauthier, Christelle; Cayol, Valerie; Poland, Michael; Kervyn, François; D'Oreye, Nicolas; Hooper, Andrew; Samsonov, Sergei; Tiampo, Kristy; Smets, Benoit; Pyle, D. M.; Mather, T.A.; Biggs, J.


    Nyamulagira, located in the east of the Democratic Republic of Congo on the western branch of the East African rift, is Africa’s most active volcano, with an average of one eruption every 3 years since 1938. Owing to the socio-economical context of that region, the volcano lacks ground-based geodetic measurements but has been monitored by interferometric synthetic aperture radar (InSAR) since 1996. A combination of 3D Mixed Boundary Element Method and inverse modelling, taking into account topography and source interactions, is used to interpret InSAR ground displacements associated with eruptive activity in 1996, 2002, 2004, 2006 and 2010. These eruptions can be fitted by models incorporating dyke intrusions, and some (namely the 2006 and 2010 eruptions) require a magma reservoir beneath the summit caldera. We investigate inter-eruptive deformation with a multi-temporal InSAR approach. We propose the following magma plumbing system at Nyamulagira by integrating numerical deformation models with other available data: a deep reservoir (c. 25 km depth) feeds a shallower reservoir (c. 4 km depth); proximal eruptions are fed from the shallow reservoir through dykes while distal eruptions can be fed directly from the deep reservoir. A dyke-like conduit is also present beneath the upper southeastern flank of Nyamulagira.

  2. Quantitative volcanic susceptibility analysis of Lanzarote and Chinijo Islands based on kernel density estimation via a linear diffusion process

    Galindo, I.; Romero, M. C.; Sánchez, N.; Morales, J. M.


    Risk management stakeholders in high-populated volcanic islands should be provided with the latest high-quality volcanic information. We present here the first volcanic susceptibility map of Lanzarote and Chinijo Islands and their submarine flanks based on updated chronostratigraphical and volcano structural data, as well as on the geomorphological analysis of the bathymetric data of the submarine flanks. The role of the structural elements in the volcanic susceptibility analysis has been reviewed: vents have been considered since they indicate where previous eruptions took place; eruptive fissures provide information about the stress field as they are the superficial expression of the dyke conduit; eroded dykes have been discarded since they are single non-feeder dykes intruded in deep parts of Miocene-Pliocene volcanic edifices; main faults have been taken into account only in those cases where they could modified the superficial movement of magma. The application of kernel density estimation via a linear diffusion process for the volcanic susceptibility assessment has been applied successfully to Lanzarote and could be applied to other fissure volcanic fields worldwide since the results provide information about the probable area where an eruption could take place but also about the main direction of the probable volcanic fissures.

  3. Constraints on the formation of geochemically variable plagiogranite intrusions in the Troodos Ophiolite, Cyprus

    Freund, Sarah; Haase, Karsten M.; Keith, Manuel; Beier, Christoph; Garbe-Schönberg, Dieter


    The geochemistry and petrology of tonalitic to trondhjemitic samples ( n = 85) from eight different plagiogranite intrusions at the gabbro/sheeted dyke transition of the Troodos Ophiolite were studied in order to determine their petrogenetic relationship to the mafic plutonic section and the lava pile. The plagiogranitic rocks have higher SiO2 contents than the majority of the glasses of the Troodos lava pile, but lie on a continuation of the chemical trends defined by the extrusive rocks, indicating that the shallow intrusions generally represent crystallised magmas. We define three different groups of plagiogranites in the Troodos Ophiolite based on different incompatible element contents and ratios. The first and most common plagiogranite group has geochemical similarities to the tholeiitic lavas forming the lavas and sheeted dyke complex in the Troodos crust, implying that these magmas formed at a spreading axis. The second plagiogranite group occurs in one intrusion that is chemically related to late-stage and off-axis boninitic lavas and dykes. One intrusion next to the Arakapas fault zone consists of incompatible element-enriched plagiogranites which are unrelated to any known mafic crustal rocks. The similarities of incompatible element ratios between plagiogranites, lavas and mafic plutonic rocks, the continuous chemical trends defined by plagiogranites and mafic rocks, as well as incompatible element modelling results, all suggest that shallow fractional crystallisation is the dominant process responsible for formation of the felsic magmas.

  4. Quantitative volcanic susceptibility analysis of Lanzarote and Chinijo Islands based on kernel density estimation via a linear diffusion process.

    Galindo, I; Romero, M C; Sánchez, N; Morales, J M


    Risk management stakeholders in high-populated volcanic islands should be provided with the latest high-quality volcanic information. We present here the first volcanic susceptibility map of Lanzarote and Chinijo Islands and their submarine flanks based on updated chronostratigraphical and volcano structural data, as well as on the geomorphological analysis of the bathymetric data of the submarine flanks. The role of the structural elements in the volcanic susceptibility analysis has been reviewed: vents have been considered since they indicate where previous eruptions took place; eruptive fissures provide information about the stress field as they are the superficial expression of the dyke conduit; eroded dykes have been discarded since they are single non-feeder dykes intruded in deep parts of Miocene-Pliocene volcanic edifices; main faults have been taken into account only in those cases where they could modified the superficial movement of magma. The application of kernel density estimation via a linear diffusion process for the volcanic susceptibility assessment has been applied successfully to Lanzarote and could be applied to other fissure volcanic fields worldwide since the results provide information about the probable area where an eruption could take place but also about the main direction of the probable volcanic fissures.

  5. Study of the deformation in Central Afar using InSAR NSBAS chain

    Deprez, A.; Doubre, C.; Grandin, R.; Saad, I.; Masson, F.; Socquet, A.


    The Afar Depression (East Africa) connects all three continental plates of Arabia, Somalia and Nubia plates. For over 20 Ma, the divergent motion of these plates has led to the formation of large normal faults building tall scarps between the high plateaus and the depression, and the development of large basins and an incipient seafloor spreading along a series of active volcano-tectonic rift segments within the depression. The space-time evolution of the active surface deformation over the whole Afar region remains uncertain. Previous tectonic and geodetic studies confirm that a large part of the current deformation is concentrated along these segments. However, the amount of extension accommodated by other non-volcanic basins and normal faulting remains unclear, despite significant micro-seismic activity. Due to the active volcanism, large transient displacements related to dyking sequence, notably in the Manda Hararo rift (2005-2010), increase the difficulty to characterize the deformation field over simple time and space scales. In this study, we attempt to obtain a complete inventory of the deformation within the whole Afar Depression and to understand the associated phenomena, which occurred in this singular tectonic environment. We study in particular, the behavior of the structures activated during the post-dyking stage of the rift segments. For this purpose, we conduct a careful processing of a large set of SAR ENVISAT images over the 2004-2010 period, we also use previous InSAR results and GPS data from permanent stations and from campaigns conducted in 1999, 2003, 2010, 2012 within a GPS network particularly dense along the Asal-Ghoubbet segment. In one hand, in the western part of Afar, the far-field response of the 2005-2010 dyke sequence appears to be the dominant surface motion on the mean velocity field. In an other hand, more eastward across the Asal-Ghoubbet rift, strong gradients of deformation are observed. The time series analysis of both In

  6. Insights on the injection mechanisms inferred from AMS fabrics of sand injectites in a turbiditic system, the exemple of Bevon area of the SE Basin (France).